Direct AFM observation of an opening event of a DNA cuboid constructed via a prism structure.
Endo, Masayuki; Hidaka, Kumi; Sugiyama, Hiroshi
2011-04-07
A cuboid structure was constructed using a DNA origami design based on a square prism structure. The structure was characterized by atomic force microscopy (AFM) and dynamic light scattering. The real-time opening event of the cuboid was directly observed by high-speed AFM.
The epidemic spreading model and the direction of information flow in brain networks.
Meier, J; Zhou, X; Hillebrand, A; Tewarie, P; Stam, C J; Van Mieghem, P
2017-05-15
The interplay between structural connections and emerging information flow in the human brain remains an open research problem. A recent study observed global patterns of directional information flow in empirical data using the measure of transfer entropy. For higher frequency bands, the overall direction of information flow was from posterior to anterior regions whereas an anterior-to-posterior pattern was observed in lower frequency bands. In this study, we applied a simple Susceptible-Infected-Susceptible (SIS) epidemic spreading model on the human connectome with the aim to reveal the topological properties of the structural network that give rise to these global patterns. We found that direct structural connections induced higher transfer entropy between two brain regions and that transfer entropy decreased with increasing distance between nodes (in terms of hops in the structural network). Applying the SIS model, we were able to confirm the empirically observed opposite information flow patterns and posterior hubs in the structural network seem to play a dominant role in the network dynamics. For small time scales, when these hubs acted as strong receivers of information, the global pattern of information flow was in the posterior-to-anterior direction and in the opposite direction when they were strong senders. Our analysis suggests that these global patterns of directional information flow are the result of an unequal spatial distribution of the structural degree between posterior and anterior regions and their directions seem to be linked to different time scales of the spreading process. Copyright © 2017 Elsevier Inc. All rights reserved.
Acoustically Induced Vibration of Structures: Reverberant Vs. Direct Acoustic Testing
NASA Technical Reports Server (NTRS)
Kolaini, Ali R.; O'Connell, Michael R.; Tsoi, Wan B.
2009-01-01
Large reverberant chambers have been used for several decades in the aerospace industry to test larger structures such as solar arrays and reflectors to qualify and to detect faults in the design and fabrication of spacecraft and satellites. In the past decade some companies have begun using direct near field acoustic testing, employing speakers, for qualifying larger structures. A limited test data set obtained from recent acoustic tests of the same hardware exposed to both direct and reverberant acoustic field testing has indicated some differences in the resulting structural responses. In reverberant acoustic testing, higher vibration responses were observed at lower frequencies when compared with the direct acoustic testing. In the case of direct near field acoustic testing higher vibration responses appeared to occur at higher frequencies as well. In reverberant chamber testing and direct acoustic testing, standing acoustic modes of the reverberant chamber or the speakers and spacecraft parallel surfaces can strongly couple with the fundamental structural modes of the test hardware. In this paper data from recent acoustic testing of flight hardware, that yielded evidence of acoustic standing wave coupling with structural responses, are discussed in some detail. Convincing evidence of the acoustic standing wave/structural coupling phenomenon will be discussed, citing observations from acoustic testing of a simple aluminum plate. The implications of such acoustic coupling to testing of sensitive flight hardware will be discussed. The results discussed in this paper reveal issues with over or under testing of flight hardware that could pose unanticipated structural and flight qualification issues. Therefore, it is of paramount importance to understand the structural modal coupling with standing acoustic waves that has been observed in both methods of acoustic testing. This study will assist the community to choose an appropriate testing method and test setup in the planning stages.
Direct observation of the actin filament by tip-scan atomic force microscopy
Narita, Akihiro; Usukura, Eiji; Yagi, Akira; Tateyama, Kiyohiko; Akizuki, Shogo; Kikumoto, Mahito; Matsumoto, Tomoharu; Maéda, Yuichiro; Ito, Shuichi; Usukura, Jiro
2016-01-01
Actin filaments, the actin–myosin complex and the actin–tropomyosin complex were observed by a tip-scan atomic force microscope (AFM), which was recently developed by Olympus as the AFM part of a correlative microscope. This newly developed AFM uses cantilevers of similar size as stage-scan AFMs to improve substantially the spatial and temporal resolution. Such an approach has previously never been possible by a tip-scan system, in which a cantilever moves in the x, y and z directions. We evaluated the performance of this developed tip-scan AFM by observing the molecular structure of actin filaments and the actin–tropomyosin complex. In the image of the actin filament, the molecular interval of the actin subunits (∼5.5 nm) was clearly observed as stripes. From the shape of the stripes, the polarity of the actin filament was directly determined and the results were consistent with the polarity determined by myosin binding. In the image of the actin–tropomyosin complex, each tropomyosin molecule (∼2 nm in diameter) on the actin filament was directly observed without averaging images of different molecules. Each tropomyosin molecule on the actin filament has never been directly observed by AFM or electron microscopy. Thus, our developed tip-scan AFM offers significant potential in observing purified proteins and cellular structures at nanometer resolution. Current results represent an important step in the development of a new correlative microscope to observe nm-order structures at an acceptable frame rate (∼10 s/frame) by AFM at the position indicated by the fluorescent dye observed under a light microscope. PMID:27242058
NASA Astrophysics Data System (ADS)
Herique, A.; Ciarletti, V.
2015-10-01
Our knowledge of the internal structure of asteroids is, so far, indirect - relying entirely on inferences from remote sensing observations of the surface, and theoretical modeling. What are the bulk properties of the regolith and deep interior? And what are the physical processes that shape their internal structures? Direct measurements are needed to provide answers that will directly improve our ability to understand and model the mechanisms driving Near Earth Asteroids (NEA) for the benefit of science as well as for planetary defense or exploration. Radar tomography is the only technique to characterize internal structure from decimetric scale to global scale. This paper reviews the benefits of direct measurement of the asteroid interior. Then the radar concepts for both deep interior and shallow subsurface are presented and the radar payload proposed for the AIDA/AIM mission is outlined.
Deconstructing thermodynamic parameters of a coupled system from site-specific observables.
Chowdhury, Sandipan; Chanda, Baron
2010-11-02
Cooperative interactions mediate information transfer between structural domains of a protein molecule and are major determinants of protein function and modulation. The prevalent theories to understand the thermodynamic origins of cooperativity have been developed to reproduce the complex behavior of a global thermodynamic observable such as ligand binding or enzyme activity. However, in most cases the measurement of a single global observable cannot uniquely define all the terms that fully describe the energetics of the system. Here we establish a theoretical groundwork for analyzing protein thermodynamics using site-specific information. Our treatment involves extracting a site-specific parameter (defined as χ value) associated with a structural unit. We demonstrate that, under limiting conditions, the χ value is related to the direct interaction terms associated with the structural unit under observation and its intrinsic activation energy. We also introduce a site-specific interaction energy term (χ(diff)) that is a function of the direct interaction energy of that site with every other site in the system. When combined with site-directed mutagenesis and other molecular level perturbations, analyses of χ values of site-specific observables may provide valuable insights into protein thermodynamics and structure.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Urushihara, Daisuke; Asaka, Toru, E-mail: asaka.toru@nitech.ac.jp; Frontier Research Institute for Materials Science, Nagoya Institute of Technology, Nagoya 466-8555
We investigated the crystal structure and ferroelectric domains of Bi{sub 4}Ti{sub 3}O{sub 12} (BTO) by means of transmission electron microscopy (TEM) and single-crystal X-ray diffractometry. From the extinction rule, we determined that the space group in the ferroelectric phase of BTO is P1a1 rather than B2cb and B1a1 which have been proposed previously. We successfully refined the crystal structure based on the space group P1a1. The 180° and 90° ferroelectric domain structures were observed by the [001]-zone dark-field TEM imaging. In the 180° domain structure, we determined that one component of the polarization vector is parallel to the a-axis. Anmore » annular bright-field scanning transmission electron microscopy (ABF-STEM) was performed for the direct observation of the crystal structures. The ABF-STEM images displayed the contrasts with respect to every atomic position in spite of the highly distorted structure of BTO. We could evaluate the tilting and distortion of the [TiO{sub 6}] octahedra relatively. Therefore, we directly observed the ferroelectric displacements of Bi and Ti ions.« less
Imaging the Top of the Solar Corona and the Young Solar Wind
NASA Astrophysics Data System (ADS)
DeForest, C. E.; Matthaeus, W. H.; Viall, N. M.; Cranmer, S. R.
2016-12-01
We present the first direct visual evidence of the quasi-stationary breakup of solar coronal structure and the rise of turbulence in the young solar wind, directly in the future flight path of Solar Probe. Although the corona and, more recently, the solar wind have both been observed directly with Thomson scattered light, the transition from the corona to the solar wind has remained a mystery. The corona itself is highly structured by the magnetic field and the outflowing solar wind, giving rise to radial "striae" - which comprise the familiar streamers, pseudostreamers, and rays. These striae are not visible in wide-field heliospheric images, nor are they clearly delineated with in-situ measurements of the solar wind. Using careful photometric analysis of the images from STEREO/HI-1, we have, for the first time, directly observed the breakup of radial coronal structure and the rise of nearly-isotropic turbulent structure in the outflowing slow solar wind plasma between 10° (40 Rs) and 20° (80 Rs) from the Sun. These observations are important not only for their direct science value, but for predicting and understanding the conditions expected near SPP as it flies through - and beyond - this final frontier of the heliosphere, the outer limits of the solar corona.
Goch, Abraham M; Karia, Raj; Taormina, David; Kalet, Adina; Zuckerman, Joseph; Egol, Kenneth A; Phillips, Donna
2018-04-01
Evaluation of resident physicians' communications skills is a challenging task and is increasingly accomplished with standardized examinations. There exists a need to identify the effective, efficient methods for assessment of communications skills. We compared objective structured clinical examination (OSCE) and direct observation as approaches for assessing resident communications skills. We conducted a retrospective cohort analysis of orthopaedic surgery resident physicians at a single tertiary care academic institution, using the Institute for Healthcare Communication "4 Es" model for effective communication. Data were collected between 2011 and 2015. A total of 28 residents, each with OSCE and complete direct observation assessment checklists, were included in the analysis. Residents were included if they had 1 OSCE assessment and 2 or more complete direct observation assessments. There were 28 of a possible 59 residents (47%) included. A total of 89% (25 of 28) of residents passed the communications skills OSCE; only 54% (15 of 28) of residents passed the direct observation communications assessment. There was a positive, moderate correlation between OSCE and direct observation scores overall ( r = 0.415, P = .028). There was no agreement between OSCE and direct observation in categorizing residents into passing and failing scores (κ = 0.205, P = .16), after adjusting for chance agreement. Our results suggest that OSCE and direct observation tools provide different insights into resident communications skills (simulation of rare and challenging situations versus real-life daily encounters), and may provide useful perspectives on resident communications skills in different contexts.
Effect of Swirl on Turbulent Structures in Supersonic Jets
NASA Technical Reports Server (NTRS)
Rao, Ram Mohan; Lundgren, Thomas S.
1998-01-01
Direct Numerical Simulation (DNS) is used to study the mechanism of generation and evolution of turbulence structures in a temporally evolving supersonic swirling round jet and also to examine the resulting acoustic radiations. Fourier spectral expansions are used in the streamwise and azimuthal directions and a 1-D b-spline Galerkin representation is used in the radial direction. Spectral-like accuracy is achieved using this numerical scheme. Direct numerical simulations, using the b-spline spectral method, are carried out starting from mean flow initial conditions which are perturbed by the most unstable linear stability eigenfunctions. It is observed that the initial helical instability waves evolve into helical vortices which eventually breakdown into smaller scales of turbulence. 'Rib' structures similar to those seen in incompressible mixing layer flow of Rogers and Moserl are observed. The jet core breakdown stage exhibits increased acoustic radiations.
Direct Observations of ULF and Whistler-Mode Chorus Modulation of 500eV EDI Electrons by MMS
NASA Astrophysics Data System (ADS)
Paulson, K. W.; Argall, M. R.; Ahmadi, N.; Torbert, R. B.; Le Contel, O.; Ergun, R.; Khotyaintsev, Y. V.; Strangeway, R. J.; Magnes, W.; Russell, C. T.
2016-12-01
We present here direct observations of chorus-wave modulated field-aligned 500 eV electrons using the Electron Drift Instrument (EDI) on board the Magnetospheric Multiscale mission. These periods of wave activity were additionally observed to be modulated by Pc5-frequency magnetic perturbations, some of which have been identified as drifting mirror-mode structures. The spacecraft encountered these mirror-mode structures just inside of the duskside magnetopause. Using the high sampling rate provided by EDI in burst sampling mode, we are able to observe the individual count fluctuations of field-aligned electrons in this region up to 512 Hz. We use the multiple look directions of EDI to generate both pitch angle and gyrophase plots of the fluctuating counts. Our observations often show unidirectional flow of these modulated electrons along the background field, and in some cases demonstrate gyrophase bunching in the wave region.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rakhymzhanov, A. M.; Utegulov, Z. N., E-mail: zhutegulov@nu.edu.kz, E-mail: fytas@mpip-mainz.mpg.de; Optics Laboratory, National Laboratory Astana, Nazarbayev University, Astana 10000
2016-05-16
The phononic band diagram of a periodic square structure fabricated by femtosecond laser pulse-induced two photon polymerization is recorded by Brillouin light scattering (BLS) at hypersonic (GHz) frequencies and computed by finite element method. The theoretical calculations along the two main symmetry directions quantitatively capture the band diagrams of the air- and liquid-filled structure and moreover represent the BLS intensities. The theory helps identify the observed modes, reveals the origin of the observed bandgaps at the Brillouin zone boundaries, and unravels direction dependent effective medium behavior.
An observation of direct-gap electroluminescence in GaAs structures with Ge quantum wells
DOE Office of Scientific and Technical Information (OSTI.GOV)
Aleshkin, V. Ya.; Dikareva, N. V.; Dubinov, A. A., E-mail: sanya@ipm.sci-nnov.ru
2015-02-15
A light-emitting diode structure based on GaAs with eight narrow Ge quantum wells is grown by laser sputtering. An electroluminescence line polarized predominately in the plane parallel to the constituent layers of the structure is revealed. The line corresponds to the direct optical transitions in momentum space in the Ge quantum wells.
NASA Technical Reports Server (NTRS)
Farrugia, M. W.; Dunlop, M. W.; Geurts, F.; Balogh, A.; Southwood, D. J.; Bryant, D. A.; Neugebauer, M.
1990-01-01
Magnetic field structures in the solar wind, characterized by a variation of the field vectors within a plane inclined to the ecliptic ('Planar Magnetic Structures', PMSs), were reported recently (Nakagawa et al., 1989). These PMSs have the property that the plane of variation of the field also contains the nominal Parker spiral direction. An observation of a PMS where the direction of the line of intersection of the plane of field variation with the ecliptic plane makes a large (about 80 deg) angle to the Parker spiral direction is presented. Furthermore, the angular variables of the field (1) vary over a restricted range, and (2) are linearly related. The latter property is related to the former. Currently proposed models for the origin of PMS, inasmuch as they require field configurations which retain strict alignment with the Parker spiral direction from formation to observation, are probably incomplete.
NASA Astrophysics Data System (ADS)
Mishra, P.; Lohani, H.; Kundu, A. K.; Patel, R.; Solanki, G. K.; Menon, Krishnakumar S. R.; Sekhar, B. R.
2015-07-01
The valence band electronic structure of GeSe single crystals has been investigated using angle resolved photoemission spectroscopy (ARPES) and x-ray photoelectron spectroscopy. The experimentally observed bands from ARPES, match qualitatively with our LDA-based band structure calculations along the Γ-Z, Γ-Y and Γ-T symmetry directions. The valence band maximum occurs nearly midway along the Γ-Z direction, at a binding energy of -0.5 eV, substantiating the indirect band gap of GeSe. Non-dispersive features associated with surface states and indirect transitions have been observed. The difference in hybridization of Se and Ge 4p orbitals leads to the variation of dispersion along the three symmetry directions. The predominance of the Se 4pz orbitals, evidenced from theoretical calculations, may be the cause for highly dispersive bands along the Γ-T direction. Detailed electronic structure analysis reveals the significance of the cation-anion 4p orbitals hybridization in the valence band dispersion of IV-VI semiconductors. This is the first comprehensive report of the electronic structure of a GeSe single crystal using ARPES in conjugation with theoretical band structure analysis.
ERIC Educational Resources Information Center
Young, John Q.; Lieu, Sandra; O'Sullivan, Patricia; Tong, Lowell
2011-01-01
Objective: The authors developed and tested the feasibility and utility of a new direct-observation instrument to assess trainee performance of a medication management session. Methods: The Psychopharmacotherapy-Structured Clinical Observation (P-SCO) instrument was developed based on multiple sources of expertise and then implemented in 4…
In-plane isotropic magnetic and electrical properties of MnAs/InAs/GaAs (111) B hybrid structure
NASA Astrophysics Data System (ADS)
Islam, Md. Earul; Akabori, Masashi
2018-03-01
We characterized in-plane magnetic and electrical properties of MnAs/InAs/GaAs (111) B hybrid structure grown by molecular beam epitaxy (MBE). We observed isotropic easy magnetization in two crystallographic in-plane directions, [ 2 ̅ 110 ] and [ 0 1 ̅ 10 ] of hexagonal MnAs i.e. [ 1 ̅ 10 ] and [ 11 2 ̅ ] of cubic InAs. We also fabricated transmission line model (TLM) devices, and observed almost isotropic electrical properties in two crystallographic in-plane directions, [ 1 ̅ 10 ] and [ 11 2 ̅ ] of cubic InAs. Also we tried to fabricate and characterize lateral spin-valve (LSV) devices from the hybrid structure. We could roughly estimate the spin injection efficiency and the spin diffusion length at room temperature in [ 11 2 ̅ ] direction. We believe that the hybrid structures are helpful to design spintronic device with good flexibility in-plane.
Chirally directed formation of nanometer-scale proline clusters.
Myung, Sunnie; Fioroni, Marco; Julian, Ryan R; Koeniger, Stormy L; Baik, Mu-Hyun; Clemmer, David E
2006-08-23
Ion mobility measurements, combined with molecular mechanics simulations, are used to study enantiopure and racemic proline clusters formed by electrospray ionization. Broad distributions of cluster sizes and charge states are observed, ranging from clusters containing only a few proline units to clusters that contain more than 100 proline units (i.e., protonated clusters of the form [xPro + nH](n+) with x = 1 to >100 and n = 1-7). As the sizes of clusters increase, there is direct evidence for nanometer scale, chirally induced organization into specific structures. For n = 4 and 5, enantiopure clusters of approximately 50 to 100 prolines assemble into structures that are more elongated than the most compact structure that is observed from the racemic proline clusters. A molecular analogue, cis-4-hydroxy-proline, displays significantly different behavior, indicating that in addition to the rigidity of the side chain ring, intermolecular interactions are important in the formation of chirally directed clusters. This is the first case in which assemblies of chirally selective elongated structures are observed in this size range of amino acid clusters. Relationships between enantiopurity, cluster shape, and overall energetics are discussed.
NASA Astrophysics Data System (ADS)
Li, Shi-Yao; She, Zhen-Su; Chen, Jun
2017-11-01
A velocity-vorticity correlation structure (VVCS) analysis is applied to the direct numerical simulation (DNS) of compressible turbulent boundary layer (CTBL) at Mach numbers, Ma = 2.25 , 4.50 and 6.0 . It is shown that the VVCS analysis captures the geometry variation in the streamwise direction during the transition and in the wall-normal direction in the fully developed regime. Specifically, before transition, the VVCS captures the instability wave number, while in the transition region it displays a distinct scaling change of the dimensions. The fully developed turbulence regime is characterized by a nearly constant spatial extension of the VVCS. Particularly, after turbulence is well developed, a multi-layer structure in the wall normal direction is observed in the maximum correlation coefficient and in the length scales of the VVCS, as expected from a recent symmetry-based theory, the ensemble structure dynamics (SED). The most interesting outcome is an observed linear dependence of the length scale of the VVCS from y+ 50 to 200, which is a direct support to Townsend's attached-eddy theory. In conclusion, the VVCS analysis quantifies the geometrical characteristics of the coherent structures in turbulent compressible shear flows throughout the whole domain. Supported by NSFC (11172006, 11221062, 11452002) and by MOST (China) 973 project (2009CB724100).
How Noniridescent Colors Are Generated by Quasi-ordered Structures of Bird Feathers
DOE Office of Scientific and Technical Information (OSTI.GOV)
Noh, Heeso; Liew, Seng Fatt; Saranathan, Vinodkumar
2012-03-26
We investigate the mechanism of structural coloration by quasi-ordered nanostructures in bird feather barbs. Small-angle X-ray scattering (SAXS) data reveal the structures are isotropic and have short-range order on length scales comparable to optical wavelengths. We perform angle-resolved reflection and scattering spectrometry to fully characterize the colors under directional and omni-directional illumination of white light. Under directional lighting, the colors change with the angle between the directions of illumination and observation. The angular dispersion of the primary peaks in the scattering/reflection spectra can be well explained by constructive interference of light that is scattered only once in the quasi-ordered structures.more » Using the Fourier power spectra of structure from the SAXS data we calculate optical scattering spectra and explain why the light scattering peak is the highest in the backscattering direction. Under omni-directional lighting, colors from the quasi-ordered structures are invariant with the viewing angle. The non-iridescent coloration results from the isotropic nature of structures instead of strong backscattering.« less
75 FR 7931 - Airworthiness Directives; Airbus Model A380-841, -842, and -861 Airplanes
Federal Register 2010, 2011, 2012, 2013, 2014
2010-02-23
... addition, delamination has been observed within the monolithic Carbon Fibre Reinforced Plastic (CFRP... observed within the monolithic Carbon Fibre Reinforced Plastic (CFRP) structure around the pivot support... monolithic Carbon Fibre Reinforced Plastic (CFRP) structure around the pivot support-ring. This condition, if...
Harvey, Todd Alan; Bostwick, Kimberly S; Marschner, Steve
2013-09-06
Diverse plumages have evolved among birds through complex morphological modifications. We investigate how the interplay of light with surface and subsurface feather morphology determines the direction of light propagation, an understudied aspect of avian visual signalling. We hypothesize that milli-scale modifications of feathers produce anisotropic reflectance, the direction of which may be predicted by the orientation of the milli-scale structure. The subject of this study is the African Emerald Cuckoo, Chrysococcyx cupreus, noted for its shimmering green iridescent appearance. Using a spherical gantry, we measured the change in the directional reflectance across the feather surface and over a hemisphere of incident lighting directions. Using a microCT scanner, we also studied the morphology of the structural branches of the barb. We tracked the changes in the directional reflectance to the orientation of the structural branches as observed in the CT data. We conclude that (i) the far-field signal of the feather consists of multiple specular components, each associated with a different structural branch and (ii) the direction of each specular component is correlated to the orientation of the corresponding structure.
Harvey, Todd Alan; Bostwick, Kimberly S.; Marschner, Steve
2013-01-01
Diverse plumages have evolved among birds through complex morphological modifications. We investigate how the interplay of light with surface and subsurface feather morphology determines the direction of light propagation, an understudied aspect of avian visual signalling. We hypothesize that milli-scale modifications of feathers produce anisotropic reflectance, the direction of which may be predicted by the orientation of the milli-scale structure. The subject of this study is the African Emerald Cuckoo, Chrysococcyx cupreus, noted for its shimmering green iridescent appearance. Using a spherical gantry, we measured the change in the directional reflectance across the feather surface and over a hemisphere of incident lighting directions. Using a microCT scanner, we also studied the morphology of the structural branches of the barb. We tracked the changes in the directional reflectance to the orientation of the structural branches as observed in the CT data. We conclude that (i) the far-field signal of the feather consists of multiple specular components, each associated with a different structural branch and (ii) the direction of each specular component is correlated to the orientation of the corresponding structure. PMID:23825113
NASA Astrophysics Data System (ADS)
Franke, R.
2016-11-01
In many networks discovered in biology, medicine, neuroscience and other disciplines special properties like a certain degree distribution and hierarchical cluster structure (also called communities) can be observed as general organizing principles. Detecting the cluster structure of an unknown network promises to identify functional subdivisions, hierarchy and interactions on a mesoscale. It is not trivial choosing an appropriate detection algorithm because there are multiple network, cluster and algorithmic properties to be considered. Edges can be weighted and/or directed, clusters overlap or build a hierarchy in several ways. Algorithms differ not only in runtime, memory requirements but also in allowed network and cluster properties. They are based on a specific definition of what a cluster is, too. On the one hand, a comprehensive network creation model is needed to build a large variety of benchmark networks with different reasonable structures to compare algorithms. On the other hand, if a cluster structure is already known, it is desirable to separate effects of this structure from other network properties. This can be done with null model networks that mimic an observed cluster structure to improve statistics on other network features. A third important application is the general study of properties in networks with different cluster structures, possibly evolving over time. Currently there are good benchmark and creation models available. But what is left is a precise sandbox model to build hierarchical, overlapping and directed clusters for undirected or directed, binary or weighted complex random networks on basis of a sophisticated blueprint. This gap shall be closed by the model CHIMERA (Cluster Hierarchy Interconnection Model for Evaluation, Research and Analysis) which will be introduced and described here for the first time.
Anisotropic properties of periodically polarity-inverted zinc oxide structures
NASA Astrophysics Data System (ADS)
Park, J. S.; Minegishi, T.; Lee, J. W.; Hong, S. K.; Song, J. H.; Lee, J. Y.; Yoon, E.; Yao, T.
2010-06-01
We report on the anisotropic structural properties of periodically polarity-inverted (PPI) ZnO structures grown on patterned templates. The etching and growth rates along ⟨112¯0⟩ direction of ZnO structures are higher than those of ⟨101¯0⟩ direction of ZnO films. From the strain evaluation by Raman spectroscopy, compressive strains are observed in all PPI ZnO samples with different stripe pattern size and the smaller pattern size is more effective to residual stress relaxation. The detailed structures at transition region show relationship with the anisotropic crystal quality.
Developing Expertise: Using Video to Hone Teacher Candidates' Classroom Observation Skills
ERIC Educational Resources Information Center
Cuthrell, Kristen; Steadman, Sharilyn C.; Stapleton, Joy; Hodge, Elizabeth
2016-01-01
This article explores the impact of a video observation model developed for teacher candidates in an early experiences course. Video Grand Rounds (VGR) combines a structured observation protocol, videos, and directed debriefing to enhance teacher candidates' observations skills within nonstructured and field-based observations. A comparative…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Voylov, D. N.; Griffin, P. J.; Mercado, B.
In this detailed analysis of the static structure factor S(Q) in several glass-forming liquids we show that the temperature variations of the width of the main diffraction peak Q(T ) correlate with the fragility of these liquids. Our observation suggests a direct connection between rather subtle structural changes and sharp slowing down of structural relaxation in glass-forming liquids. We also show that this observation can be rationalized using the Adam-Gibbs approach, through a connection between temperature variations of structural correlation length, lc 2 /Q, and the size of cooperatively rearranging regions.
Direct Observation of Quark-Hadron Duality in the Free Neutron {ital F}{sub 2} Structure Function
Niculescu, I.; Niculescu, G.; Melnitchouk, W.; ...
2015-05-21
Using the recently published data from the BONuS(Barely Off-shell Nucleon Structure) experiment at Jefferson Lab, which utilized a spectator tagging technique to extract the inclusive electron-free neutron scattering cross section, we obtain the first direct observation of quark-hadron duality in the neutron F-2 structure function. The data are used to reconstruct the lowest few (N = 2, 4, and 6) moments of F-2 in the three prominent nucleon resonance regions, as well as the moments integrated over the entire resonance region. Comparison with moments computed from global parametrizations of parton distribution functions suggest that quark-hadron duality holds locally for themore » neutron in the second and third resonance regions down to Q(2) approximate to 1 GeV2, with violations possibly up to 20% observed in the first resonance region.« less
Truong, Quang Duc; Devaraju, Murukanahally Kempaiah; Tomai, Takaaki; Honma, Itaru
2013-10-23
LiCoPO4 cathode materials have been synthesized by a sol-gel route. X-ray diffraction analysis confirmed that LiCoPO4 was well-crystallized in an orthorhombic structure in the Pmna space group. From the high-resolution transmission electron microscopy (HR-TEM) image, the lattice fringes of {001} and {100} are well-resolved. The HR-TEM image and selected area electron diffraction pattern reveal the highly crystalline nature of LiCoPO4 having an ordered olivine structure. The atom-by-atom structure of LiCoPO4 olivine has been observed, for the first time, using high-angle annular dark-field (HAADF) and annual bright-field scanning transmission electron microscopy. We observed the bright contrast in Li columns in the HAADF images and strong contrast in the ABF images, directly indicating the antisite exchange defects in which Co atoms partly occupy the Li sites. The LiCoPO4 cathode materials delivered an initial discharge capacity of 117 mAh/g at a C/10 rate with moderate cyclic performance. The discharge profile of LiCoPO4 shows a plateau at 4.75 V, revealing its importance as a potentially high-voltage cathode. The direct visualization of atom-by-atom structure in this work represents important information for the understanding of the structure of the active cathode materials for Li-ion batteries.
IUE study of the very local interstellar medium. [Copernicus spacecraft
NASA Technical Reports Server (NTRS)
Henry, R. C.; Murthy, J.; Moos, H. W.; Landsman, W. B.; Linsky, J. L.; Vidal-Madjar, A.; Gry, C.
1986-01-01
The IUE and Copernicus results for the very local interstellar medium are compared. Despite its lower resolution, IUE produces results of comparable quality, giving important confirmation of Copernicus results on the density, temperature, turbulence, and deuterium-to-hydrogen ratio in the region within 10 pc of the Sun. The stars observed are in a very low-density quarter of the galaxy: multicomponent structure seen in other directions may not be present in the direction of most of the observed stars. The exceedingly low densities observed in certain directions encourages the idea that EUV studies of certain normal stars may be possible.
Large-scale structures in turbulent Couette flow
NASA Astrophysics Data System (ADS)
Kim, Jung Hoon; Lee, Jae Hwa
2016-11-01
Direct numerical simulation of fully developed turbulent Couette flow is performed with a large computational domain in the streamwise and spanwise directions (40 πh and 6 πh) to investigate streamwise-scale growth mechanism of the streamwise velocity fluctuating structures in the core region, where h is the channel half height. It is shown that long streamwise-scale structures (> 3 h) are highly energetic and they contribute to more than 80% of the turbulent kinetic energy and Reynolds shear stress, compared to previous studies in canonical Poiseuille flows. Instantaneous and statistical analysis show that negative-u' structures on the bottom wall in the Couette flow continuously grow in the streamwise direction due to mean shear, and they penetrate to the opposite moving wall. The geometric center of the log layer is observed in the centerline with a dominant outer peak in streamwise spectrum, and the maximum streamwise extent for structure is found in the centerline, similar to previous observation in turbulent Poiseuille flows at high Reynolds number. Further inspection of time-evolving instantaneous fields clearly exhibits that adjacent long structures combine to form a longer structure in the centerline. This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2014R1A1A2057031).
Spectral structure and stability studies on microstructure-fiber continuum
NASA Astrophysics Data System (ADS)
Gu, Xun; Kimmel, Mark; Zeek, Erik; Shreenath, Aparna P.; Trebino, Rick P.; Windeler, Robert S.
2003-07-01
Although previous direct measurements of the microstructure-fiber continuum have all showed a smooth and stable spectrum, our cross-correlation frequency-resolved optical gating (XFROG) full-intensity-and-phase characterization of the continuum pulse, utilizing sum-frequency-generation with a pre-characterized reference pulse and the angle-dithered-crystal technique, indicates that fine-scale spectral structure exists on a single-shot basis, contrary to previous observations. In particular, deep and fine oscillations are found in the retrieved spectrum, and the retrieved trace contains a "measles" pattern, whereas the measured trace and the independently-measured spectrum are rather smooth. The discrepancy is shown to be the result of unstable single-shot spectral structure. Although the XFROG measurement is not able to directly measure the single-shot fine structure in the trace, the redundancy of information in FROG traces enables the retrieval algorithm to correctly recognize the existence of the spectral fine structure, and restore the structure in the retrieved trace and spectrum. Numerical simulations have supported our hypothesis, and we directly observed the fine spectral structure in single-shot measurements of the continuum spectrum and the structure was seen to be highly unstable, the continuum spectrum appearing smooth only when many shots are averaged. Despite the structure and instability in the continuum spectrum, coherence experiments also reveal that the spectral phase is rather stable, being able to produce well-defined spectral fringes across the entire continuum bandwidth.
NASA Technical Reports Server (NTRS)
Steiner, B.; Kuriyama, M.; Dobbyn, R. C.; Laor, U.; Larson, D.; Brown, M.
1988-01-01
Novel, streak-like disruption features restricted to the plane of diffraction have recently been observed in images obtained by synchrotron radiation diffraction from undoped, semi-insulating gallium arsenide crystals. These features were identified as ensembles of very thin platelets or interfaces lying in (110) planes, and a structural model consisting of antiphase domain boundaries was proposed. We report here the other principal features observed in high resolution monochromatic synchrotron radiation diffraction images: (quasi) cellular structure; linear, very low-angle subgrain boundaries in (110) directions, and surface stripes in a (110) direction. In addition, we report systematic differences in the acceptance angle for images involving various diffraction vectors. When these observations are considered together, a unifying picture emerges. The presence of ensembles of thin (110) antiphase platelet regions or boundaries is generally consistent not only with the streak-like diffraction features but with the other features reported here as well. For the formation of such regions we propose two mechanisms, operating in parallel, that appear to be consistent with the various defect features observed by a variety of techniques.
NASA Technical Reports Server (NTRS)
Steiner, B.; Kuriyama, M.; Dobbyn, R. C.; Laor, U.; Larson, D.
1989-01-01
Novel, streak-like disruption features restricted to the plane of diffraction have recently been observed in images obtained by synchrotron radiation diffraction from undoped, semi-insulating gallium arsenide crystals. These features were identified as ensembles of very thin platelets or interfaces lying in (110) planes, and a structural model consisting of antiphase domain boundaries was proposed. We report here the other principal features observed in high resolution monochromatic synchrotron radiation diffraction images: (quasi) cellular structure; linear, very low-angle subgrain boundaries in (110) directions, and surface stripes in a (110) direction. In addition, we report systematic differences in the acceptance angle for images involving various diffraction vectors. When these observations are considered together, a unifying picture emerges. The presence of ensembles of thin (110) antiphase platelet regions or boundaries is generally consistent not only with the streak-like diffraction features but with the other features reported here as well. For the formation of such regions we propose two mechanisms, operating in parallel, that appear to be consistent with the various defect features observed by a variety of techniques.
Observation of Three-Dimensional Magnetic Reconnection in the Terrestrial Magnetotail
NASA Astrophysics Data System (ADS)
Zhou, Meng; Ashour-Abdalla, Maha; Deng, Xiaohua; Pang, Ye; Fu, Huishan; Walker, Raymond; Lapenta, Giovanni; Huang, Shiyong; Xu, Xiaojun; Tang, Rongxin
2017-09-01
Study of magnetic reconnection has been focused on two-dimensional geometry in the past decades, whereas three-dimensional structures and dynamics of reconnection X line are poorly understood. In this paper, we report Cluster multispacecraft observations of a three-dimensional magnetic reconnection X line with a weak guide field ( 25% of the upstream magnetic field) in the Earth's magnetotail. We find that the X line not only retreated tailward but also expanded across the tail following the electron flow direction with a maximum average speed of (0.04-0.15) VA,up, where VA,up is the upstream Alfvén speed, or (0.14-0.57) Vde, where Vde is the electron flow speed in the out-of-plane direction. An ion diffusion region was observed by two spacecraft that were separated about 10 ion inertial lengths along the out-of-plane direction; however, these two spacecraft observed distinct magnetic structures associated with reconnection: one spacecraft observed dipolarization fronts, while the other one observed flux ropes. This indicates that reconnection proceeds in drastically different ways in different segments along the X line only a few ion inertial lengths apart.
Direct Band Gap Wurtzite Gallium Phosphide Nanowires
2013-01-01
The main challenge for light-emitting diodes is to increase the efficiency in the green part of the spectrum. Gallium phosphide (GaP) with the normal cubic crystal structure has an indirect band gap, which severely limits the green emission efficiency. Band structure calculations have predicted a direct band gap for wurtzite GaP. Here, we report the fabrication of GaP nanowires with pure hexagonal crystal structure and demonstrate the direct nature of the band gap. We observe strong photoluminescence at a wavelength of 594 nm with short lifetime, typical for a direct band gap. Furthermore, by incorporation of aluminum or arsenic in the GaP nanowires, the emitted wavelength is tuned across an important range of the visible light spectrum (555–690 nm). This approach of crystal structure engineering enables new pathways to tailor materials properties enhancing the functionality. PMID:23464761
Observations of the magnetic field and plasma flow in Jupiter's magnetosheath
NASA Technical Reports Server (NTRS)
Lepping, R. P.; Burlaga, L. F.; Klein, L. W.; Jessen, J. M.; Goodrich, G. C.
1980-01-01
Large scale (many minutes to 10 hours) magnetic field structures consisting predominantly of nearly north-south field direction were discovered in Jupiter's magnetosheath from the data of Voyagers 1 and 2 and Pioneer 10 during their outbound encounter trajectories. The Voyager 2 data, and that of Voyager 1 to a lesser extent, show evidence of a quasi-period of 10 hours (and occasionally 5 hours) for these structures. The north-south components of the field and plasma velocity were strongly correlated in the outbound magnetosheath as observed by Voyagers 1 and 2, and the components orthogonal to the north-south direction showed weak correlations. For both Voyager encounters the sense (positive and negative) of the north-south correlations were directly related to the direction of the ecliptic plane component of the interplanetary magnetic field using the field and plasma measurements of the non-encountering spacecraft.
Taninaka, Atsushi; Yoshida, Shoji; Kanazawa, Ken; Hayaki, Eiko; Takeuchi, Osamu; Shigekawa, Hidemi
2016-06-16
Scanning tunneling microscopy/spectroscopy (STM/STS) was carried out to investigate the structures of Mn atoms deposited on a GaAs(110) surface at room temperature to directly observe the characteristics of interactions between Mn atoms in GaAs. Mn atoms were paired with a probability higher than the random distribution, indicating an attractive interaction between them. In fact, re-pairing of unpaired Mn atoms was observed during STS measurement. The pair initially had a new structure, which was transformed during STS measurement into one of those formed by atom manipulation at 4 K. Mn atoms in pairs and trimers were aligned in the <110> direction, which is theoretically predicted to produce a high Curie temperature.
Structure control of tungsten nanocontacts through pulsed-voltage application
NASA Astrophysics Data System (ADS)
Suzuki, Yasuchika; Kizuka, Tokushi
2018-05-01
The structural variation in tungsten nanocontacts (NCs) during a pulsed-voltage application was observed in situ by high-resolution transmission electron microscopy. The direction of electromigration in the NCs changed from the well-known direction to the opposite direction at a critical voltage of 0.9 V. Upon applying a higher pulsed voltage of 2.5 V, the NC structure changed to amorphous, with an average conductance density decreased to 82% of that of the crystalline NCs. We demonstrated that the external shape and texture of tungsten NCs can be controlled with an atomic precision through electromigration and amorphization by a pulsed-voltage application.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schuster, Patricia; Feng, Patrick; Brubaker, Erik
We report the scintillation anisotropy effect for proton recoil events has been investigated in five pure organic crystalline materials: anthracene, trans-stilbene, p-terphenyl, bibenzyl, and diphenylacetylene. These measurements include characterization of the scintillation response for one hemisphere of proton recoil directions in each crystal. In addition to standard measurements of the total light output and pulse shape at each angle, the prompt and delayed light anisotropies are analyzed, allowing for investigation of the singlet and triplet molecular excitation behaviors independently. This work provides new quantitative and qualitative observations that make progress toward understanding the physical mechanisms behind the scintillation anisotropy. Thesemore » measurements show that the relationship between the prompt and delayed light anisotropies is correlated with crystal structure, as it changes between the pi-stacked crystal structure materials (anthracene and p-terphenyl) and the herringbone crystal structure materials (stilbene, bibenzyl, and diphenylacetylene). The observations are consistent with a model in which there are preferred directions of kinetic processes for the molecular excitations. Finally, these processes and the impact of their directional dependencies on the scintillation anisotropy are discussed.« less
Schuster, Patricia; Feng, Patrick; Brubaker, Erik
2018-05-03
We report the scintillation anisotropy effect for proton recoil events has been investigated in five pure organic crystalline materials: anthracene, trans-stilbene, p-terphenyl, bibenzyl, and diphenylacetylene. These measurements include characterization of the scintillation response for one hemisphere of proton recoil directions in each crystal. In addition to standard measurements of the total light output and pulse shape at each angle, the prompt and delayed light anisotropies are analyzed, allowing for investigation of the singlet and triplet molecular excitation behaviors independently. This work provides new quantitative and qualitative observations that make progress toward understanding the physical mechanisms behind the scintillation anisotropy. Thesemore » measurements show that the relationship between the prompt and delayed light anisotropies is correlated with crystal structure, as it changes between the pi-stacked crystal structure materials (anthracene and p-terphenyl) and the herringbone crystal structure materials (stilbene, bibenzyl, and diphenylacetylene). The observations are consistent with a model in which there are preferred directions of kinetic processes for the molecular excitations. Finally, these processes and the impact of their directional dependencies on the scintillation anisotropy are discussed.« less
Han, Lu; Sakamoto, Yasuhiro; Che, Shunai; Terasaki, Osamu
2009-01-01
Silica mesoporous crystals were synthesized by using a gemini cationic surfactant (C(18-3-1)) as the directing agent, carboxyethylsilanetriol sodium salt as the co-structure directing agent (CSDA), and varying amounts of HCl. By using transmission electron microscopy (TEM) we observed 1) a structural change from the close-packed structures of spherical micelles--face-centered cubic (Fm3m) and hexagonal close-packed (P6(3)/mmc)--to Fd3m structures with an increase of HCl and 2) a few structural defects in the crystals with Fd3m symmetry. The structure of a crystal with Fd3m symmetry is described as one of the tetrahedrally close-packed (tcp) structures consisting of 5(12) and 5(12)6(4) polyhedra. The observed TEM images of the structural defects were explained well through use of simulated TEM images by introducing new 13-15 polyhedra comprising 5(12)6(2), 5(12)6(3), 4(1)5(10)6(2), 4(2)5(8)6(5), and 4(1)5(10)6(4), which have been observed in bubbles by Matzke. The mesostructural changes and defect formation are discussed in terms of the hardness of micelles composed of surfactant/CSDA/silica species that have formed through a change of the interaction between the surfactant and CSDA, which causes the micelles to change from a regime of close-packing to one of minimum-area packing.
Indications of a spatial variation of the fine structure constant.
Webb, J K; King, J A; Murphy, M T; Flambaum, V V; Carswell, R F; Bainbridge, M B
2011-11-04
We previously reported Keck telescope observations suggesting a smaller value of the fine structure constant α at high redshift. New Very Large Telescope (VLT) data, probing a different direction in the Universe, shows an inverse evolution; α increases at high redshift. Although the pattern could be due to as yet undetected systematic effects, with the systematics as presently understood the combined data set fits a spatial dipole, significant at the 4.2 σ level, in the direction right ascension 17.5 ± 0.9 h, declination -58 ± 9 deg. The independent VLT and Keck samples give consistent dipole directions and amplitudes, as do high and low redshift samples. A search for systematics, using observations duplicated at both telescopes, reveals none so far which emulate this result.
``Making the Molecular Movie'': First Frames
NASA Astrophysics Data System (ADS)
Miller, R. J. Dwayne
2011-03-01
Femtosecond Electron Diffraction has enabled atomic resolution to structural changes as they occur, essentially watching atoms move in real time--directly observe transition states. This experiment has been referred to as ``making the molecular movie'' and has been previously discussed in the context of a gedanken experiment. With the recent development of femtosecond electron pulses with sufficient number density to execute single shot structure determinations, this experiment has been finally realized. A new concept in electron pulse generation was developed based on a solution to the N-body electron propagation problem involving up to 10,000 interacting electrons that has led to a new generation of extremely bright electron pulsed sources that minimizes space charge broadening effects. Previously thought intractable problems of determining t=0 and fully characterizing electron pulses on the femtosecond time scale have now been solved through the use of the laser pondermotive potential to provide a time dependent scattering source. Synchronization of electron probe and laser excitation pulses is now possible with an accuracy of 10 femtoseconds to follow even the fastest nuclear motions. The camera for the ``molecular movie'' is well in hand based on high bunch charge electron sources. Several movies depicting atomic motions during passage through structural transitions will be shown. Atomic level views of the simplest possible structural transition, melting, will be presented for a number of systems in which both thermal and purely electronically driven atomic displacements can be correlated to the degree of directional bonding. Optical manipulation of charge distributions and effects on interatomic forces/bonding can be directly observed through the ensuing atomic motions. New phenomena involving strongly correlated electron systems will be presented in which an exceptionally cooperative phase transitions has been observed. The primitive origin of molecular cooperativity has also been discovered in recent studies of molecular crystals. These new developments will be discussed in the context of developing the necessary technology to directly observe the structure-function correlation in biomolecules--the fundamental molecular basis of biological systems.
Direct measurements on imaging riometer antenna array beam directivities
NASA Astrophysics Data System (ADS)
Wilson, A.; Nel, J. J.; Mathews, M. J.; Stoker, P. H.
2001-01-01
Spatial structures in enhanced ionization of the ionosphere are observed by absorption of cosmic radio waves. These structures are resolved by using theoretically derived imaging riometer antenna array directivities. These directivities are calculated from beam phasing of 64 crossed dipole elements of the 38.2-MHz antenna array at SANAE IV, Antarctica. In order to ensure that these derived directivities are representative of the actual viewing directions of the 64-beams, a radio transmitter was flown by helicopter across the antenna array. In this paper variations in the receiver signal strengths, recorded when flying across beam-viewing directions, are compared with the spatial and angular-dependent profiles of expected receiver output responses, derived theoretically from the directivities of the antenna array. A Global Positioning System (GPS) device on board the helicopter was used for positional recording. The derived and recorded profiles did coincide occasionally, but at other instances relative displacements and differences in magnitude of responses were observed. These displacements and differences could be attributed to degradation in position fixes imposed deliberately by selective availability on the GPS system. Excellent coincidence for a number of beam crossings proved that the viewing directions are accurate in all the beam directions, since the multi-dimensional Butler matrix produces 64 simultaneous beams.
Structural Analysis of Covariance and Correlation Matrices.
ERIC Educational Resources Information Center
Joreskog, Karl G.
1978-01-01
A general approach to analysis of covariance structures is considered, in which the variances and covariances or correlations of the observed variables are directly expressed in terms of the parameters of interest. The statistical problems of identification, estimation and testing of such covariance or correlation structures are discussed.…
Direct TEM observations of growth mechanisms of two-dimensional MoS2 flakes
Fei, Linfeng; Lei, Shuijin; Zhang, Wei-Bing; Lu, Wei; Lin, Ziyuan; Lam, Chi Hang; Chai, Yang; Wang, Yu
2016-01-01
A microscopic understanding of the growth mechanism of two-dimensional materials is of particular importance for controllable synthesis of functional nanostructures. Because of the lack of direct and insightful observations, how to control the orientation and the size of two-dimensional material grains is still under debate. Here we discern distinct formation stages for MoS2 flakes from the thermolysis of ammonium thiomolybdates using in situ transmission electron microscopy. In the initial stage (400 °C), vertically aligned MoS2 structures grow in a layer-by-layer mode. With the increasing temperature of up to 780 °C, the orientation of MoS2 structures becomes horizontal. When the growth temperature reaches 850 °C, the crystalline size of MoS2 increases by merging adjacent flakes. Our study shows direct observations of MoS2 growth as the temperature evolves, and sheds light on the controllable orientation and grain size of two-dimensional materials. PMID:27412892
Room temperature ferromagnetism in BiFe1-xMnxO3 thin film induced by spin-structure manipulation
NASA Astrophysics Data System (ADS)
Shigematsu, Kei; Asakura, Takeshi; Yamamoto, Hajime; Shimizu, Keisuke; Katsumata, Marin; Shimizu, Haruki; Sakai, Yuki; Hojo, Hajime; Mibu, Ko; Azuma, Masaki
2018-05-01
The evolution of crystal structure, spin structure, and macroscopic magnetization of manganese-substituted BiFeO3 (BiFe1-xMnxO3), a candidate for multiferroic materials, were investigated on bulk and epitaxial thin-film. Mn substitution for Fe induced collinear antiferromagnetic spin structure around room temperature by destabilizing the cycloidal spin modulation which prohibited the appearance of net magnetization generated by Dzyaloshinskii-Moriya interaction. For the bulk samples, however, no significant signal of ferromagnetism was observed because the direction of the ordered spins was close to parallel to the electric polarization so that spin-canting did not occur. On the contrary, BiFe1-xMnxO3 thin film on SrTiO3 (001) had a collinear spin structure with the spin direction perpendicular to the electric polarization at room temperature, where the appearance of spontaneous magnetization was expected. Indeed, ferromagnetic hysteresis behavior was observed for BiFe0.9Mn0.1O3 thin film.
Galactic Structure: A Constructivist Approach to Teaching Astronomy.
ERIC Educational Resources Information Center
Domenech, Antonio; Casasus, Elena
1991-01-01
An astrophysics course based on the constructivist approach to science teaching is described. The study of galactic structure is given as an example. Direct experiences and observations, representative-symbolic language, organized knowledge, and formal strategies are emphasized. (KR)
The universality of β-hairpin misfolding indicated by molecular dynamics simulations.
Shao, Qiang; Wang, Jinan; Shi, Jiye; Zhu, Weiliang
2013-10-28
Previous molecular dynamics simulations showed that besides the experimentally measured folded structures, several β-structured polypeptides could also have misfolded "out-of-register" structures. Through the enhanced sampling molecular dynamics simulations on a series of polypeptides using either implicit or explicit solvent model, the present study systematically investigated the universality of β-hairpin misfolding and its determinants. It was observed that the misfolding could take place for almost all polypeptides under study, especially in the presence of weak side chain hydrophobicity. Moreover, the observed misfolded structures for various polypeptides share the following common features: (1) the turn length in misfolded structure is one-residue shorter than that in folded structure; (2) the hydrophobic side chains on the two strands are pointed to the opposite directions instead of packing in the same direction to form hydrophobic core cluster in the folded structure; and (3) the misfolded structure is one-residue-shifted asymmetric β-hairpin structure. The detailed analysis suggested that the misfolding of β-hairpin is the result of the competition between the formation of the alterable turn configurations and the inter-strand hydrophobic interactions. These predictions are desired to be tested by experiments.
The universality of β-hairpin misfolding indicated by molecular dynamics simulations
NASA Astrophysics Data System (ADS)
Shao, Qiang; Wang, Jinan; Shi, Jiye; Zhu, Weiliang
2013-10-01
Previous molecular dynamics simulations showed that besides the experimentally measured folded structures, several β-structured polypeptides could also have misfolded "out-of-register" structures. Through the enhanced sampling molecular dynamics simulations on a series of polypeptides using either implicit or explicit solvent model, the present study systematically investigated the universality of β-hairpin misfolding and its determinants. It was observed that the misfolding could take place for almost all polypeptides under study, especially in the presence of weak side chain hydrophobicity. Moreover, the observed misfolded structures for various polypeptides share the following common features: (1) the turn length in misfolded structure is one-residue shorter than that in folded structure; (2) the hydrophobic side chains on the two strands are pointed to the opposite directions instead of packing in the same direction to form hydrophobic core cluster in the folded structure; and (3) the misfolded structure is one-residue-shifted asymmetric β-hairpin structure. The detailed analysis suggested that the misfolding of β-hairpin is the result of the competition between the formation of the alterable turn configurations and the inter-strand hydrophobic interactions. These predictions are desired to be tested by experiments.
Correlation of ICME Magnetic Fields at Radially Aligned Spacecraft
NASA Astrophysics Data System (ADS)
Good, S. W.; Forsyth, R. J.; Eastwood, J. P.; Möstl, C.
2018-03-01
The magnetic field structures of two interplanetary coronal mass ejections (ICMEs), each observed by a pair of spacecraft close to radial alignment, have been analysed. The ICMEs were observed in situ by MESSENGER and STEREO-B in November 2010 and November 2011, while the spacecraft were separated by more than 0.6 AU in heliocentric distance, less than 4° in heliographic longitude, and less than 7° in heliographic latitude. Both ICMEs took approximately two days to travel between the spacecraft. The ICME magnetic field profiles observed at MESSENGER have been mapped to the heliocentric distance of STEREO-B and compared directly to the profiles observed by STEREO-B. Figures that result from this mapping allow for easy qualitative assessment of similarity in the profiles. Macroscale features in the profiles that varied on timescales of one hour, and which corresponded to the underlying flux rope structure of the ICMEs, were well correlated in the solar east-west and north-south directed components, with Pearson's correlation coefficients of approximately 0.85 and 0.95, respectively; microscale features with timescales of one minute were uncorrelated. Overall correlation values in the profiles of one ICME were increased when an apparent change in the flux rope axis direction between the observing spacecraft was taken into account. The high degree of similarity seen in the magnetic field profiles may be interpreted in two ways. If the spacecraft sampled the same region of each ICME ( i.e. if the spacecraft angular separations are neglected), the similarity indicates that there was little evolution in the underlying structure of the sampled region during propagation. Alternatively, if the spacecraft observed different, nearby regions within the ICMEs, it indicates that there was spatial homogeneity across those different regions. The field structure similarity observed in these ICMEs points to the value of placing in situ space weather monitors well upstream of the Earth.
Fleming, Andrew P; McMahon, Robert J; King, Kevin M
2017-04-01
Structured observations of parent-child interactions are commonly used in research and clinical settings, but require additional empirical support. The current study examined the capacity of child-directed play, parent-directed play, and parent-directed chore interaction analogs to uniquely predict the development of conduct problems across a 6-year follow-up period. Parent-child observations were collected from 338 families from high-risk neighborhoods during the summer following the child's first-grade year. Participating children were 49.2 % female, 54.4 % white, and 45.6 % black, and had an average age of 7.52 years at the first assessment. Conduct problems were assessed via parent report and teacher report at five assessment points between first grade and seventh grade. Latent growth curve modeling was used to analyze predictors of conduct problem trajectory across this 6-year follow-up period. When race, sex, socioeconomic status, and maternal depressive symptoms were controlled, parental negative attention during child-directed play predicted higher levels of parent-reported conduct problems concurrently and after a 6-year follow-up period. Parental negative attention during child-directed play also predicted higher teacher-reported conduct problems 6 years later. Findings support the use of child-directed play and parent-directed chore analogs in predicting longitudinal development of conduct problems. The presence of parental negative attention during child-directed play appears to be an especially important predictor of greater conduct problems over time and across multiple domains. Additionally, the potential importance of task-incongruent behavior is proposed for further study.
Coronal electron stream and Langmuir wave detection inside a propagation channel at 4.3 AU
NASA Technical Reports Server (NTRS)
Buttighoffer, A.; Pick, M.; Roelof, E. C.; Hoang, S.; Mangeney, A.; Lanzerotti, L. J.; Forsyth, R. J.; Phillips, J. L.
1995-01-01
Observations of an energetic interplanetary electron event associated with the production of Langmuir waves, both of which are identified at 4.3 AU by instruments on the Ulysses spacecraft, are presented in this paper. This electron event propagates inside a well-defined magnetic structure. The existence of this structure is firmly established by joint particle and plasma observations made by Ulysses instruments. Its local estimated radial width is of the order of 2.3 x 10(exp 7) km (0.15 AU). The electron beam is associated with a type III burst observed from Earth at high frequencies and at low frequencies from Ulysses in association with Langmuir waves detected inside the structure. The consistency of local (Ulysses) and remote (Earth) observations in terms of temporal and geometrical considerations establishes that the structure is anchored in the solar corona near the solar active region responisble for the observed type III emission and gives an accurate determination of the injection time for the observed electron beam. Propagation analysis of the electron event is presented. In order to quantify the magnetic field properties, a variance analysis has been performed and is presented in this paper. The analysis establishes that inside the structure the amount of magnetic energy involved in the fluctuations is less than 4% of the total magnetic energy; the minimal variance direction is well defined and in coincidence with the direction of the mean magnetic field. This configuration may produce conditions favorable for scatter free streaming of energetic electrons and/or Langmuir wave production. The results presented show that the magnetic field might play a role in stabilizing the coronal-origin plasma structures and then preserving them to large, approximately 4 AU, distances in the heliosphere.
Direct observation of forward-scattering oscillations in the H+HD→H2+D reaction
NASA Astrophysics Data System (ADS)
Yuan, Daofu; Yu, Shengrui; Chen, Wentao; Sang, Jiwei; Luo, Chang; Wang, Tao; Xu, Xin; Casavecchia, Piergiorgio; Wang, Xingan; Sun, Zhigang; Zhang, Dong H.; Yang, Xueming
2018-06-01
Accurate measurements of product state-resolved angular distributions are central to fundamental studies of chemical reaction dynamics. Yet, fine quantum-mechanical structures in product angular distributions of a reactive scattering process, such as the fast oscillations in the forward-scattering direction, have never been observed experimentally and the nature of these oscillations has not been fully explored. Here we report the crossed-molecular-beam experimental observation of these fast forward-scattering oscillations in the product angular distribution of the benchmark chemical reaction, H + HD → H2 + D. Clear oscillatory structures are observed for the H2(v' = 0, j' = 1, 3) product states at a collision energy of 1.35 eV, in excellent agreement with the quantum-mechanical dynamics calculations. Our analysis reveals that the oscillatory forward-scattering components are mainly contributed by the total angular momentum J around 28. The partial waves and impact parameters responsible for the forward scatterings are also determined from these observed oscillations, providing crucial dynamics information on the transient reaction process.
Quasi-crystalline and disordered photonic structures fabricated using direct laser writing
NASA Astrophysics Data System (ADS)
Sinelnik, Artem D.; Pinegin, Konstantin V.; Bulashevich, Grigorii A.; Rybin, Mikhail V.; Limonov, Mikhail F.; Samusev, Kirill B.
2017-09-01
Direct laser writing is a rapid prototyping technology that has been utilized for the fabrication of micro- and nano-scale materials that have a perfect structure in most of the cases. In this study we exploit the direct laser writing to create several classes of non-periodic materials, such as quasi-crystalline lattices and three-dimensional (3D) objects with an orientation disorder in structural elements. Among quasi-crystalline lattices we consider Penrose tiling and Lévy-type photonic glasses. Images of the fabricated structures are obtained with a scanning electron microscope. In experiment we study the optical diffraction from 3D woodpile photonic structures with orientation disorder and analyze diffraction patters observed on a flat screen positioned behind the sample. With increasing of the disorder degree, we find an impressive transformation of the diffraction patterns from perfect Laue picture to a speckle pattern.
In-volume structuring of a bilayered polymer foil using direct laser interference patterning
NASA Astrophysics Data System (ADS)
Rößler, Florian; Günther, Katja; Lasagni, Andrés F.
2018-05-01
Periodic surface patterns can provide materials with special optical properties, which are usable in decorative or security applications. However, they can be sensitive to contact wear and thus their lifetime and functionality are limited. This study describes the use of direct laser interference patterning for structuring a multilayered polymer film at its interface creating periodic in-volume structures which are resistant to contact wear. The spatial period of the structures are varied in the range of 1.0 μm to 2.0 μm in order to produce decorative elements. The pattern formation at the interface is explained using cross sectional observations and a thermal simulation of the temperature evolution during the laser treatment at the interface. Both, the diffraction efficiency and direct transmission are characterized by light intensity measurements to describe the optical behavior of the produced periodic structures and a decorative application example is presented.
ERIC Educational Resources Information Center
Vancleef, Linda M. G.; Vlaeyen, Johan W. S.; Peters, Madelon L.
2009-01-01
Research has identified several anxiety and fear constructs that contribute directly or indirectly to the chronic course of pain. One way to gain insight into the frequently observed interrelations between these constructs may be by conceptualizing them within a hierarchical structure. In this structure, general and specific constructs are…
Transmission electron microscopy: direct observation of crystal structure in refractory ceramics.
Shaw, T M; Thomas, G
1978-11-10
Using high-resolution multibeam interference techniques in the transmission electron microscope, images have been obtained that make possible a real-space structure analysis of a beryllium-silicon-nitrogen compound. The results illustrate the usefulness of lattice imaging in the analysis of local crystal structure in these technologically promising ceramic materials.
Local Structure and Anisotropy in the Amorphous Precursor= to Ba-Hexaferrite Thin Films
NASA Astrophysics Data System (ADS)
Snyder, J. E.; Harris, V. G.; Koon, N. C.; Sui, X.; Kryder, M. H.
1996-03-01
Ba-hexaferrite thin-films for recording media applications are commonly fabricated by a two-step process: sputter-deposition of an amorphous precursor, followed by annealing to crystallize the BaFe_12O_19 phase. The magnetic anisotropy of the crystalline films can be either in-plane or perpendicular, depending on the sputtering process used in the first step. However, conventional characterization techniques (x-ray diffraction and TEM) have been unable to observe any structure in the amorphous precursor films. In this study, such films are investigated by PD-EXAFS (polarization-dependent extended x-ray absorption fine structure). An anisotropic local ordered structure is observed around both Fe and Ba atoms in the "amorphous" films. This anisotropic local structure appears to determine the orientation of the fast-growing basal plane directions during crystallization, and thus the directions of the c-axes and the magnetic anisotropy. Results suggest that the structure of the amorphous films consists of networks made up of units of Fe atoms surrounded by their O nearest neighbors, that are connected together. Ba atoms appear to fit into in-between spaces as network-modifiers.
Predicted electric-field-induced hexatic structure in an ionomer membrane
NASA Astrophysics Data System (ADS)
Allahyarov, Elshad; Taylor, Philip L.
2009-08-01
Coarse-grained molecular-dynamics simulations were used to study the morphological changes induced in a Nafion®-like ionomer by the imposition of a strong electric field. We observe the formation of structures aligned along the direction of the applied field. The polar head groups of the ionomer sidechains aggregate into clusters, which then form rodlike formations which assemble into a hexatic array aligned with the direction of the field. Occasionally these lines of sulfonates and protons form a helical structure. Upon removal of the electric field, the hexatic array of rodlike structures persists and has a lower calculated free energy than the original isotropic morphology.
Black Studies: A Key to the Future
ERIC Educational Resources Information Center
Johnson, Whittington B.; Nichols, Ted
1977-01-01
Concludes that black studies programs should develop an octopus-like academic structure which reaches out in several directions, simultaneously: initiating and illuminating, discerning and fostering, observing and directing, collecting and disseminating; all with one goal in view, exploring the black experience within a universal perspective.…
Structural Equation Models in a Redundancy Analysis Framework With Covariates.
Lovaglio, Pietro Giorgio; Vittadini, Giorgio
2014-01-01
A recent method to specify and fit structural equation modeling in the Redundancy Analysis framework based on so-called Extended Redundancy Analysis (ERA) has been proposed in the literature. In this approach, the relationships between the observed exogenous variables and the observed endogenous variables are moderated by the presence of unobservable composites, estimated as linear combinations of exogenous variables. However, in the presence of direct effects linking exogenous and endogenous variables, or concomitant indicators, the composite scores are estimated by ignoring the presence of the specified direct effects. To fit structural equation models, we propose a new specification and estimation method, called Generalized Redundancy Analysis (GRA), allowing us to specify and fit a variety of relationships among composites, endogenous variables, and external covariates. The proposed methodology extends the ERA method, using a more suitable specification and estimation algorithm, by allowing for covariates that affect endogenous indicators indirectly through the composites and/or directly. To illustrate the advantages of GRA over ERA we propose a simulation study of small samples. Moreover, we propose an application aimed at estimating the impact of formal human capital on the initial earnings of graduates of an Italian university, utilizing a structural model consistent with well-established economic theory.
Jenkinson, Paul M; Preston, Catherine
2017-02-01
In this study we adopted a psychometric approach to examine how the body is subjectively experienced in a mirror. One hundred and twenty-four healthy participants viewed their body for five minutes directly or via a mirror, and then completed a 20-item questionnaire designed to capture subjective experiences of the body. PCA revealed a two-component structure for both direct and mirror conditions, comprising body evaluations (and alienation) and unusual feelings and perceptions. The relationship between these components and pre-existing tendencies for appearance anxiety, body dysmorphic-type beliefs, dissociative symptomatology, self-objectification and delusion ideation further supported the similarity between direct and mirror conditions; however, the occurrence of strange experiences like those reported to occur during prolonged face viewing was not confirmed. These results suggest that, despite obvious differences in visual feedback, observing the body via a mirror (as an outside observer) is subjectively equivalent to observing the body directly (from our own viewpoint). Copyright © 2016 Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
Titov, O. A.; Lopez, Yu. R.
2018-03-01
We consider a method of reconstructing the structure delay of extended radio sources without constructing their radio images. The residuals derived after the adjustment of geodetic VLBI observations are used for this purpose. We show that the simplest model of a radio source consisting of two point components can be represented by four parameters (the angular separation of the components, the mutual orientation relative to the poleward direction, the flux-density ratio, and the spectral index difference) that are determined for each baseline of a multi-baseline VLBI network. The efficiency of this approach is demonstrated by estimating the coordinates of the radio source 0014+813 observed during the two-week CONT14 program organized by the International VLBI Service (IVS) in May 2014. Large systematic deviations have been detected in the residuals of the observations for the radio source 0014+813. The averaged characteristics of the radio structure of 0014+813 at a frequency of 8.4 GHz can be calculated from these deviations. Our modeling using four parameters has confirmed that the source consists of two components at an angular separation of 0.5 mas in the north-south direction. Using the structure delay when adjusting the CONT14 observations leads to a correction of the average declination estimate for the radio source 0014+813 by 0.070 mas.
Elemental and Microscopic Analysis of Naturally Occurring C-O-Si Hetero-Fullerene-Like Structures.
Hullavarad, Nilima V; Hullavarad, Shiva S; Fochesatto, Javier
2015-03-01
Carbon exhibits an ability to form a wide range of structures in nature. Under favorable conditions, carbon condenses to form hollow, spheroid fullerenes in an inert atmosphere. Using high resolution FESEM, we have concealed the existence of giant hetero-fullerene like structures in the natural form. Clear, distinct features of connected hexagons and pentagons were observed. Energy dispersive X-ray analysis depth-profile of natural fullerene structures indicates that Russian-doll-like configurations composed of C, 0, and Si rings exist in nature. The analysis is based on an outstanding molecular feature found in the size fraction of aerosols having diameters 150 nm to 1.0 µm. The fullerene like structures, which are ~ 150 nm in diameter, are observed in large numbers. To the best of our knowledge, this is the first direct detailed observation of natural fullerene-like structures. This article reports inadvertent observation of naturally occurring hetero-fullerene-like structures in the Arctic.
Correlation between temperature variations of static and dynamic properties in glass-forming liquids
Voylov, D. N.; Griffin, P. J.; Mercado, B.; ...
2016-12-29
In this detailed analysis of the static structure factor S(Q) in several glass-forming liquids we show that the temperature variations of the width of the main diffraction peak Q(T ) correlate with the fragility of these liquids. Our observation suggests a direct connection between rather subtle structural changes and sharp slowing down of structural relaxation in glass-forming liquids. We also show that this observation can be rationalized using the Adam-Gibbs approach, through a connection between temperature variations of structural correlation length, lc 2 /Q, and the size of cooperatively rearranging regions.
Yoo, Jongsoo; Yamada, Masaaki; Ji, Hantao; Myers, Clayton E
2013-05-24
The ion dynamics in a collisionless magnetic reconnection layer are studied in a laboratory plasma. The measured in-plane plasma potential profile, which is established by electrons accelerated around the electron diffusion region, shows a saddle-shaped structure that is wider and deeper towards the outflow direction. This potential structure ballistically accelerates ions near the separatrices toward the outflow direction. Ions are heated as they travel into the high-pressure downstream region.
NASA Astrophysics Data System (ADS)
Braun, Jean
1994-08-01
We have developed a three-dimensional finite element model to study wrench deformation of the crust regarded as an elasto-plastic material obeying Murrell's extension of Griffith's failure criterion. Numerical experiments using this model predict that the imposed basal wrenching is accommodated by an array of oblique Riedel-like shears and Y-shears (parallel to the direction of wrenching). The partitioning of deformation between the two types of structure depends on the width of the zone of imposed basal wrenching and the existence of a component of deformation in the x-direction (normal to the direction of wrenching). The Riedel shears are arranged in spiral-like structures that root into the basal wrench zone. In cross-section, the Riedel shears resemble wedge-shaped flower structures similar to those often observed in seismic cross-sections. The 'polarity' of the flower structures is positive (or palm-tree-like) in transpression experiments and negative (or tulip-like) in transtension experiments. The orientation of the Riedel shears throughout the crust obeys Mohr's hypothesis for incipient faulting combined with Murrell's failure criterion. The model also predicts plastic dilatancy inversely proportional to the square root of the confining pressure; this result agrees qualitatively with field observations and the results of sand-box experiments and quantitatively with direct measurement of dilatancy during high-pressure rock-deformation experiments.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sugimoto, Akira; Yamaguchi, Tetsuji; Iguchi, Ienari
1999-12-01
The Bitter decoration technique is one of the most powerful techniques to study the vortex structure of superconductor. The authors report the observation of vortex structure in a high {Tc} YBa{sub 2}Cu{sub 3}O{sub 7{minus}y} (YBCO) thin film by Bitter decoration method. The image of vortex structure was monitored by SEM, AFM and high resolution optical microscope. For magnetic field about 4--6mT, a vortex structure is seen. The vortex image varied with changing magnetic field. As compared with the vortex image of a Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+y} single crystal, the observed image appeared to be more randomly distributed.
A study of flame spread in engineered cardboard fuelbeds: Part I: Correlations and observations
Mark A. Finney; Jason Forthofer; Isaac C. Grenfell; Brittany A. Adam; Nelson K. Akafuah; Kozo Saito
2013-01-01
Wind tunnel laboratory fires spreading through laser-cut cardboard fuel beds were instrumented and analyzed for physical processes associated with spread. Flames in the span-wise direction appeared as a regular series of peaks-and-troughs that scaled directly with flame length. Flame structure in the stream-wise direction fluctuated with the forward advection of...
Role of interface states on electron transport in a-Si:H/nc-Si:H multilayer structures
NASA Astrophysics Data System (ADS)
Yadav, Asha; Kumari, Juhi; Agarwal, Pratima
2018-05-01
In this paper we report, I-V characteristic of a-Si:H/nc-Si:H multilayer structures in lateral as well as transverse direction. In lateral geometry, where the interfaces are parallel to the direction of electronic transport, residual photo conductivity (persistent photoconductivity) is observed after the light was turned off. On the other hand, in transverse geometry, where interfaces are along the direction of electronic transport, the space charge limited currents are affected and higher density of states is obtained. The PPC was more in the structures where numbers of such interface were more. These results have been understood in terms of the charge carriers trapped at the interface, which influence the electronic transport.
Hippocampal Replay Captures the Unique Topological Structure of a Novel Environment
Wu, Xiaojing
2014-01-01
Hippocampal place-cell replay has been proposed as a fundamental mechanism of learning and memory, which might support navigational learning and planning. An important hypothesis of relevance to these proposed functions is that the information encoded in replay should reflect the topological structure of experienced environments; that is, which places in the environment are connected with which others. Here we report several attributes of replay observed in rats exploring a novel forked environment that support the hypothesis. First, we observed that overlapping replays depicting divergent trajectories through the fork recruited the same population of cells with the same firing rates to represent the common portion of the trajectories. Second, replay tended to be directional and to flip the represented direction at the fork. Third, replay-associated sharp-wave–ripple events in the local field potential exhibited substructure that mapped onto the maze topology. Thus, the spatial complexity of our recording environment was accurately captured by replay: the underlying neuronal activities reflected the bifurcating shape, and both directionality and associated ripple structure reflected the segmentation of the maze. Finally, we observed that replays occurred rapidly after small numbers of experiences. Our results suggest that hippocampal replay captures learned information about environmental topology to support a role in navigation. PMID:24806672
Optical Imaging Observation of the Geospace from the International Space Station by ISS-IMAP
NASA Astrophysics Data System (ADS)
Saito, A.; Sakanoi, T.; Yoshikawa, I.; Yamazaki, A.; Hozumi, Y.; Perwitasari, S.; Otsuka, Y.; Yamamoto, M.
2017-12-01
Optical imaging observation of the mesosphere, thermosphere, ionosphere, and plasmasphere was carried out from the International Space Station (ISS) with ISS-IMAP (Ionosphere, Mesosphere, upper Atmosphere, and Plasmasphere mapping) mission instruments. ISS-IMAP instruments was installed on the Exposed Facility of Japanese Experiment Module of the ISS in August, 2012, and removed in August, 2015. They are two imagers, Visible-light and Infrared Spectrum Imager (VISI) and Extreme UltraViolet Imager (EUVI). VISI made imaging observations of the airglow and aurora in the nadir direction. It had two slits perpendicular to the trajectory of ISS, and the movement of ISS made the two-dimensional observation whose field-of-view width is 600km at 100km altitude. It covered the wave length range from 500nm to 900nm. The airglow of 730nm (OH, Alt. 85km), 762nm (O2, Alt. 95km), and 630nm (O, Alt. 250km) were mainly observed besides the other airglow, such as 589nm (Na) and 557 (O). EUVI made imaging observation of the resonant scattering from ions. It had two telescopes, and observed the resonant scattering of He+ in 30.4nm, and O+ in 83.4nm in the limb direction. VISI captured the airglow structures whose wavelength from 80km to 500km. The concentric wave structures were frequently observed in the mesosphere and lower thermosphere region. They are strong evidence of the vertical coupling between the lower atmosphere and the upper atmosphere by vertical propagation of the atmospheric gravity waves. The other airglow structures, such as mesospheric bores, were also detected by ISS-IMAP/VISI. The meso-scale structures in the ionosphere, such as plasma bubbles, and traveling ionospheric disturbances were also observed. EUVI revealed the longitudinal structures of He+ in the top side of the ionosphere. It was attributed to the neutral wind in the thermosphere. In the presentation, the outline and results of the ISS-IMAP's VISI and EUVI observations will be discussed.
NASA Technical Reports Server (NTRS)
Steiner, Bruce; Dobbyn, Ronald C.; Black, David; Burdette, Harold; Kuriyama, Masao; Fripp, Archibald; Simchik, Richard
1991-01-01
Irregularities in three crystals grown in space and in four terrestrial crystals grown under otherwise comparable conditions have been observed in high resolution diffraction imaging. The images provide important new clues to the nature and origins of irregularities in each crystal. For two of the materials, mercuric iodide and lead tin telluride, more than one phase (an array of non-diffracting inclusions) was observed in terrestrial samples; but the formation of these multiple phases appears to have been suppressed in directly comparable crystals grown in microgravity. The terrestrial seed crystal of triglycine sulfate displayed an unexpected layered structure, which propagated during directly comparable space growth. Terrestrial Bridgman regrowth of gallium arsenide revealed a mesoscopic structure substantially different from that of the original Czochralski material. A directly comparable crystal is to be grown shortly in space.
König, Jörg; Tschulik, Kristina; Büttner, Lars; Uhlemann, Margitta; Czarske, Jürgen
2013-03-19
To experimentally reveal the correlation between electrodeposited structure and electrolyte convection induced inside the concentration boundary layer, a highly inhomogeneous magnetic field, generated by a magnetized Fe-wire, has been applied to an electrochemical system. The influence of Lorentz and magnetic field gradient force to the local transport phenomena of copper ions has been studied using a novel two-component laser Doppler velocity profile sensor. With this sensor, the electrolyte convection within 500 μm of a horizontally aligned cathode is presented. The electrode-normal two-component velocity profiles below the electrodeposited structure show that electrolyte convection is induced and directed toward the rim of the Fe-wire. The measured deposited structure directly correlates to the observed boundary layer flow. As the local concentration of Cu(2+) ions is enhanced due to the induced convection, maximum deposit thicknesses can be found at the rim of the Fe-wire. Furthermore, a complex boundary layer flow structure was determined, indicating that electrolyte convection of second order is induced. Moreover, the Lorentz force-driven convection rapidly vanishes, while the electrolyte convection induced by the magnetic field gradient force is preserved much longer. The progress for research is the first direct experimental proof of the electrolyte convection inside the concentration boundary layer that correlates to the deposited structure and reveals that the magnetic field gradient force is responsible for the observed structuring effect.
`Fingerprint' Fine Structure in the Solar Decametric Radio Spectrum Solar Physics
NASA Astrophysics Data System (ADS)
Zlotnik, E. Y.; Zaitsev, V. V.; Melnik, V. N.; Konovalenko, A. A.; Dorovskyy, V. V.
2015-07-01
We study a unique fine structure in the dynamic spectrum of the solar radio emission discovered by the UTR-2 radio telescope (Kharkiv, Ukraine) in the frequency band of 20 - 30 MHz. The structure was observed against the background of a broadband type IV radio burst and consisted of parallel drifting narrow bands of enhanced emission and absorption on the background emission. The observed structure differs from the widely known zebra pattern at meter and decimeter wavelengths by the opposite directions of the frequency drift within a single stripe at a given time. We show that the observed properties can be understood in the framework of the radiation mechanism by virtue of the double plasma resonance effect in a nonuniform coronal magnetic trap. We propose a source model providing the observed frequency drift of the stripes.
ERIC Educational Resources Information Center
Pitner, Nancy J.; Russell, James S.
1986-01-01
This paper critically reviews administrator work activity studies which follow the research of Henry Mintzberg. It discusses directions for future research using qualitative and quantitative methods and discourages research that relies solely on Mintzberg's structure. (Author/JAZ)
Structure and Growth of the Leeward Kohala Field System: An Analysis with Directed Graphs
Dye, Thomas S.
2014-01-01
This study illustrates how the theory of directed graphs can be used to investigate the structure and growth of the leeward Kohala field system, a traditional Hawaiian archaeological site that presents an unparalleled opportunity to investigate relative chronology. The relative chronological relationships of agricultural walls and trails in two detailed study areas are represented as directed graphs and then investigated using graph theoretic concepts including cycle, level, and connectedness. The structural properties of the directed graphs reveal structure in the field system at several spatial scales. A process of deduction yields a history of construction in each detailed study area that is different than the history produced by an earlier investigation. These results indicate that it is now possible to study the structure and growth of the entire field system remnant using computer software implementations of graph theoretic concepts applied to observations of agricultural wall and trail intersections made on aerial imagery and/or during fieldwork. A relative chronology of field system development with a resolution of one generation is a possible result. PMID:25058167
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kaur, Manjit, E-mail: manjit@ipr.res.in; Bose, Sayak; Chattopadhyay, P. K.
2015-09-15
Observation of two well-separated dust vortices in an unmagnetized parallel plate DC glow discharge plasma is reported in this paper. A non-monotonic radial density profile, achieved by an especially designed cathode structure using a concentric metallic disk and ring of different radii, is observed to produce double dust tori between cathode and anode. PIV analysis of the still images of the double tori shows oppositely rotating dust structures between the central disk and the ring. Langmuir probe measurements of background plasma shows a non-uniform plasma density profile between the disk and the ring. Location and sense of rotation of themore » dust vortices coincides with the location and direction of the radial gradient in the ion drag force caused by the radial density gradient. The experimentally observed dust vorticity matches well with the calculated one using hydrodynamic formulations with shear in ion drag dominating over the dust charge gradient. These results corroborate that a radial gradient in the ion drag force directed towards cathode is the principal cause of dust rotation.« less
Uberuaga, Blas Pedro; Tang, Ming; Jiang, Chao; Valdez, James A.; Smith, Roger; Wang, Yongqiang; Sickafus, Kurt E.
2015-01-01
Understanding and predicting radiation damage evolution in complex materials is crucial for developing next-generation nuclear energy sources. Here, using a combination of ion beam irradiation, transmission electron microscopy and X-ray diffraction, we show that, contrary to the behaviour observed in pyrochlores, the amorphization resistance of spinel compounds correlates directly with the energy to disorder the structure. Using a combination of atomistic simulation techniques, we ascribe this behaviour to structural defects on the cation sublattice that are present in spinel but not in pyrochlore. Specifically, because of these structural defects, there are kinetic pathways for the relaxation of disorder in spinel that are absent in pyrochlore. This leads to a direct correlation between amorphization resistance and disordering energetics in spinel, the opposite of that observed in pyrochlores. These results provide new insight into the origins of amorphization resistance in complex oxides beyond fluorite derivatives. PMID:26510750
Uberuaga, Blas Pedro; Tang, Ming; Jiang, Chao; ...
2015-10-29
Understanding and predicting radiation damage evolution in complex materials is crucial for developing next-generation nuclear energy sources. Here, using a combination of ion beam irradiation, transmission electron microscopy and X-ray diffraction, we show that, contrary to the behaviour observed in pyrochlores, the amorphization resistance of spinel compounds correlates directly with the energy to disorder the structure. Using a combination of atomistic simulation techniques, we ascribe this behaviour to structural defects on the cation sublattice that are present in spinel but not in pyrochlore. Specifically, because of these structural defects, there are kinetic pathways for the relaxation of disorder in spinelmore » that are absent in pyrochlore. This leads to a direct correlation between amorphization resistance and disordering energetics in spinel, the opposite of that observed in pyrochlores. Furthermore, these results provide new insight into the origins of amorphization resistance in complex oxides beyond fluorite derivatives.« less
Solar Coronal Loop Dynamics Near the Null Point Above Active Region NOAA 2666
NASA Astrophysics Data System (ADS)
Filippov, B.
2018-06-01
We analyse observations of a saddle-like structure in the corona above the western limb of the Sun on 2017 July 18. The structure was clearly outlined by coronal loops with typical coronal temperature no more than 1 MK. The dynamics of loops showed convergence towards the centre of the saddle in the vertical direction and divergence in the horizontal direction. The event is a clear example of smooth coronal magnetic field reconnection. No heating manifestations in the reconnection region or magnetically connected areas were observed. Potential magnetic field calculations, which use as the boundary condition the SDO/HMI magnetogram taken on July 14, showed the presence of a null point at the height of 122 arcsec above the photosphere just at the centre of the saddle structure. The shape of field lines fits the fan-spine magnetic configuration above NOAA 2666.
Uberuaga, Blas Pedro; Tang, Ming; Jiang, Chao; Valdez, James A; Smith, Roger; Wang, Yongqiang; Sickafus, Kurt E
2015-10-29
Understanding and predicting radiation damage evolution in complex materials is crucial for developing next-generation nuclear energy sources. Here, using a combination of ion beam irradiation, transmission electron microscopy and X-ray diffraction, we show that, contrary to the behaviour observed in pyrochlores, the amorphization resistance of spinel compounds correlates directly with the energy to disorder the structure. Using a combination of atomistic simulation techniques, we ascribe this behaviour to structural defects on the cation sublattice that are present in spinel but not in pyrochlore. Specifically, because of these structural defects, there are kinetic pathways for the relaxation of disorder in spinel that are absent in pyrochlore. This leads to a direct correlation between amorphization resistance and disordering energetics in spinel, the opposite of that observed in pyrochlores. These results provide new insight into the origins of amorphization resistance in complex oxides beyond fluorite derivatives.
NASA Astrophysics Data System (ADS)
Matsushima, Shinichi; Kosaka, Hiroyuki; Kawase, Hiroshi
2017-07-01
As observational evidence of 3-D microtremor horizontal-to-vertical spectral ratios (MHVRs), previous studies have shown that a significant directional dependency is observed in and around Uji campus, Kyoto University, Japan. This directional dependence is considered to be the result of 2-D basin structure. In this study, we observed microtremors around a strong motion observation site of the Port and Harbor Research Institute in Onahama, Japan, and found that directional dependence of MHVRs exists in some parts of the area around the site. The directional dependence is more apparent and has a higher dominant frequency, at around 5 Hz, relative to those observed in Uji, at around 0.5 Hz. We defined a parameter γ, which we refer to as the "directionally dependent coefficient" to indicate the magnitude of difference between the two orthogonal components which implies the directional dependence of the MHVRs. We rotated the axes and calculated γ for each angle and searched for the orientation that gave the largest γ at a point. Points for which the axis with larger MHVR amplitude among the two axes is oriented in the NS direction are aligned in the NS direction, while points for which the axis with larger MHVR amplitude is oriented in the EW direction are aligned in the EW direction. The distribution of points with large γ formed a T-shaped distribution. We calculated the analytical and numerical MHVRs in order to simulate the observed MHVRs and succeeded in showing the existence of a narrow wedge. From these results, we conclude that a wedge-like lateral heterogeneity exists in the shallow subsurface of the studied area, parallel to the direction of the axis of the larger MHVR amplitude.
NASA Astrophysics Data System (ADS)
Takagi, R.; Okada, T.; Yoshida, K.; Townend, J.; Boese, C. M.; Baratin, L. M.; Chamberlain, C. J.; Savage, M. K.
2016-12-01
We estimate shear wave velocity anisotropy in shallow crust near the Alpine fault using seismic interferometry of borehole vertical arrays. We utilized four borehole observations: two sensors are deployed in two boreholes of the Deep Fault Drilling Project in the hanging wall side, and the other two sites are located in the footwall side. Surface sensors deployed just above each borehole are used to make vertical arrays. Crosscorrelating rotated horizontal seismograms observed by the borehole and surface sensors, we extracted polarized shear waves propagating from the bottom to the surface of each borehole. The extracted shear waves show polarization angle dependence of travel time, indicating shear wave anisotropy between the two sensors. In the hanging wall side, the estimated fast shear wave directions are parallel to the Alpine fault. Strong anisotropy of 20% is observed at the site within 100 m from the Alpine fault. The hanging wall consists of mylonite and schist characterized by fault parallel foliation. In addition, an acoustic borehole imaging reveals fractures parallel to the Alpine fault. The fault parallel anisotropy suggest structural anisotropy is predominant in the hanging wall, demonstrating consistency of geological and seismological observations. In the footwall side, on the other hand, the angle between the fast direction and the strike of the Alpine fault is 33-40 degrees. Since the footwall is composed of granitoid that may not have planar structure, stress induced anisotropy is possibly predominant. The direction of maximum horizontal stress (SHmax) estimated by focal mechanisms of regional earthquakes is 55 degrees of the Alpine fault. Possible interpretation of the difference between the fast direction and SHmax direction is depth rotation of stress field near the Alpine fault. Similar depth rotation of stress field is also observed in the SAFOD borehole at the San Andreas fault.
X-ray tomographic microscopy analysis of the dendrite orientation transition in Al-Zn
NASA Astrophysics Data System (ADS)
Friedli, Jonathan; Fife, Julie L.; Di Napoli, Paolo; Rappaz, Michel
2012-07-01
Recently, Gonzales and Rappaz [Met. Mat. Trans. A37:2797, 2006] showed the influence of an increasing zinc content on the growth directions of aluminum dendrites. langle100rangle and langle110rangle dendrites were observed below 25wt.% and above 55wt.% zinc, respectively, whereas textured seaweeds and langle320rangle dendrites were observed at intermediate compositions. Considering the complexity of these structures, it is necessary to first characterize them in further details and second, to model them using the phase field method. The so-called Dendrite Orientation Transition (DOT) was thus reinvestigated in quenched Bridgman solidification samples. The combination of X-ray tomographic microscopy and electron backscattered diffraction (EBSD) analysis on a whole range of compositions, from 5 to 90wt.% Zn, allowed insights with unprecedented details about texture, growth directions and mechanisms of the aforementioned structures. We show that seaweeds rather than dendrites are found at all intermediate compositions. Their growth was confirmed to be constrained within a (100) symmetry plane. However, new findings indicate that the observed macroscopic texture does not necessarily correspond to the actual growth directions of the microstructure. Further, it seems to operate by an alternating growth direction mechanism and could be linked to the competition between the langle100rangle and langle110rangle characters of regular dendrites observed at the limits of the DOT. These characters, as well as 3D seaweeds, are observed in phase-field simulations of equiaxed growth and directional solidification, respectively. This study emphasizes the importance of accurate experimental data to validate numerical models and details the progress that such combinations provide for the understanding of growth mechanisms.
Two-dimensional microsphere quasi-crystal: fabrication and properties
NASA Astrophysics Data System (ADS)
Noginova, Natalia E.; Venkateswarlu, Putcha; Kukhtarev, Nickolai V.; Sarkisov, Sergey S.; Noginov, Mikhail A.; Caulfield, H. John; Curley, Michael J.
1996-11-01
2D quasi-crystals were fabricated from polystyrene microspheres and characterized for their structural, diffraction, and non-linear optics properties. The quasi- crystals were produced with the method based on Langmuir- Blodgett thin film technique. Illuminating the crystal with the laser beam, we observed the diffraction pattern in the direction of the beam propagation and in the direction of the back scattering, similar to the x-ray Laue pattern observed in regular crystals with hexagonal structure. The absorption spectrum of the quasi-crystal demonstrated two series of regular maxima and minima, with the spacing inversely proportional to the microspheres diameter. Illumination of the dye-doped microspheres crystal with Q- switched radiation of Nd:YAG laser showed the enhancement of non-linear properties, in particular, second harmonic generation.
Colabello, Diane M; Sobalvarro, Elizabeth M; Sheckelton, John P; Neuefeind, Joerg C; McQueen, Tyrel M; Khalifah, Peter G
2017-11-06
Among oxide compounds with direct metal-metal bonding, the Y 5 Mo 2 O 12 (A 5 B 2 O 12 ) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2 O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal-metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal-metal bonding have integer oxidation states resulting from the lifting of orbital degeneracy typically induced by the metal-metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5 Mo 2 O 12 (Ln = La-Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2 O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1-2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5 Mo 2 O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. This represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.
Colabello, Diane M.; Sobalvarro, Elizabeth M.; Sheckelton, John P.; ...
2017-10-26
Among oxide compounds with direct metal–metal bonding, the Y 5Mo 2O 12 (A 5B 2O 12) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal–metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal–metal bonding have integer oxidation states resulting from the lifting of orbital degeneracymore » typically induced by the metal–metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5Mo 2O 12 (Ln = La–Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown in this paper that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1–2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5Mo 2O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. Finally, this represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Colabello, Diane M.; Sobalvarro, Elizabeth M.; Sheckelton, John P.
Among oxide compounds with direct metal–metal bonding, the Y 5Mo 2O 12 (A 5B 2O 12) structural family of compounds has a particularly intriguing low-dimensional structure due to the presence of bioctahedral B 2O 10 dimers arranged in one-dimensional edge-sharing chains along the direction of the metal–metal bonds. Furthermore, these compounds can have a local magnetic moment due to the noninteger oxidation state (+4.5) of the transition metal, in contrast to the conspicuous lack of a local moment that is commonly observed when oxide compounds with direct metal–metal bonding have integer oxidation states resulting from the lifting of orbital degeneracymore » typically induced by the metal–metal bonding. Although a monoclinic C2/m structure has been previously proposed for Ln 5Mo 2O 12 (Ln = La–Lu and Y) members of this family based on prior single crystal diffraction data, it is found that this structural model misses many important structural features. On the basis of synchrotron powder diffraction data, it is shown in this paper that the C2/m monoclinic unit cell represents a superstructure relative to a previously unrecognized orthorhombic Immm subcell and that the superstructure derives from the ordering of interchangeable Mo 2O 10 and LaO 6 building blocks. The superstructure for this reason is typically highly faulted, as evidenced by the increased breadth of superstructure diffraction peaks associated with a coherence length of 1–2 nm in the c* direction. Finally, it is shown that oxygen vacancies can occur when Ln = La, producing an oxygen deficient stoichiometry of La 5Mo 2O 11.55 and an approximately 10-fold reduction in the number of unpaired electrons due to the reduction of the average Mo valence from +4.5 to +4.05, a result confirmed by magnetic susceptibility measurements. Finally, this represents the first observation of oxygen vacancies in this family of compounds and provides an important means of continuously tuning the magnetic interactions within the one-dimensional octahedral chains of this system.« less
Information processing architecture of functionally defined clusters in the macaque cortex.
Shen, Kelly; Bezgin, Gleb; Hutchison, R Matthew; Gati, Joseph S; Menon, Ravi S; Everling, Stefan; McIntosh, Anthony R
2012-11-28
Computational and empirical neuroimaging studies have suggested that the anatomical connections between brain regions primarily constrain their functional interactions. Given that the large-scale organization of functional networks is determined by the temporal relationships between brain regions, the structural limitations may extend to the global characteristics of functional networks. Here, we explored the extent to which the functional network community structure is determined by the underlying anatomical architecture. We directly compared macaque (Macaca fascicularis) functional connectivity (FC) assessed using spontaneous blood oxygen level-dependent functional magnetic resonance imaging (BOLD-fMRI) to directed anatomical connectivity derived from macaque axonal tract tracing studies. Consistent with previous reports, FC increased with increasing strength of anatomical connection, and FC was also present between regions that had no direct anatomical connection. We observed moderate similarity between the FC of each region and its anatomical connectivity. Notably, anatomical connectivity patterns, as described by structural motifs, were different within and across functional modules: partitioning of the functional network was supported by dense bidirectional anatomical connections within clusters and unidirectional connections between clusters. Together, our data directly demonstrate that the FC patterns observed in resting-state BOLD-fMRI are dictated by the underlying neuroanatomical architecture. Importantly, we show how this architecture contributes to the global organizational principles of both functional specialization and integration.
Fukuda, Muneyuki; Tomimatsu, Satoshi; Nakamura, Kuniyasu; Koguchi, Masanari; Shichi, Hiroyasu; Umemura, Kaoru
2004-01-01
A new method to prepare micropillar specimens with a high aspect ratio that is suitable for three-dimensional scanning transmission electron microscopy (3D-STEM) was developed. The key features of the micropillar fabrication are: first, microsampling to extract a small piece including the structure of interest in an IC chip, and second, an ion-beam with an incident direction of 60 degrees to the pillar's axis that enables the parallel sidewalls of the pillar to be produced with a high aspect ratio. A memory-cell structure (length: 6 microm; width: 300 x 500 nm) was fabricated in the micropillar and observed from various directions with a 3D-STEM. A planiform capacitor covered with granular surfaces and a solid crossing gate and metal lines was successfully observed threedimensionally at a resolution of approximately 5 nm.
Microwave properties of Ni-based ferromagnetic inverse opals
NASA Astrophysics Data System (ADS)
Kostylev, M.; Stashkevich, A. A.; Roussigné, Y.; Grigoryeva, N. A.; Mistonov, A. A.; Menzel, D.; Sapoletova, N. A.; Napolskii, K. S.; Eliseev, A. A.; Lukashin, A. V.; Grigoriev, S. V.; Samarin, S. N.
2012-11-01
Investigations of microwave properties of Ni-based inverse ferromagnetic opal-like film with the [111] axis of the fcc structure along the normal direction to the film have been carried out in the 2-18 GHz frequency band. We observed multiple spin wave resonances for the magnetic field applied perpendicular to the film, i.e., along the [111] axis of this artificial crystal. For the field applied in the film plane, a broad band of microwave absorption is observed, which does not contain a fine structure. The field ranges of the responses observed are quite different for these two magnetization directions. This suggests a collective magnetic ground state or shape anisotropy and collective microwave dynamics for this foam-like material. This result is in agreement with SQUID measurements of hysteresis loops for the material. Two different models for this collective behavior are suggested that satisfactorily explain the major experimental results.
Measuring the topology of large-scale structure in the universe
NASA Technical Reports Server (NTRS)
Gott, J. Richard, III
1988-01-01
An algorithm for quantitatively measuring the topology of large-scale structure has now been applied to a large number of observational data sets. The present paper summarizes and provides an overview of some of these observational results. On scales significantly larger than the correlation length, larger than about 1200 km/s, the cluster and galaxy data are fully consistent with a sponge-like random phase topology. At a smoothing length of about 600 km/s, however, the observed genus curves show a small shift in the direction of a meatball topology. Cold dark matter (CDM) models show similar shifts at these scales but not generally as large as those seen in the data. Bubble models, with voids completely surrounded on all sides by wall of galaxies, show shifts in the opposite direction. The CDM model is overall the most successful in explaining the data.
Measuring the topology of large-scale structure in the universe
NASA Astrophysics Data System (ADS)
Gott, J. Richard, III
1988-11-01
An algorithm for quantitatively measuring the topology of large-scale structure has now been applied to a large number of observational data sets. The present paper summarizes and provides an overview of some of these observational results. On scales significantly larger than the correlation length, larger than about 1200 km/s, the cluster and galaxy data are fully consistent with a sponge-like random phase topology. At a smoothing length of about 600 km/s, however, the observed genus curves show a small shift in the direction of a meatball topology. Cold dark matter (CDM) models show similar shifts at these scales but not generally as large as those seen in the data. Bubble models, with voids completely surrounded on all sides by wall of galaxies, show shifts in the opposite direction. The CDM model is overall the most successful in explaining the data.
NASA Astrophysics Data System (ADS)
Budiman, A. S.; Nix, W. D.; Tamura, N.; Valek, B. C.; Gadre, K.; Maiz, J.; Spolenak, R.; Patel, J. R.
2006-06-01
Plastic deformation was observed in damascene Cu interconnect test structures during an in situ electromigration experiment and before the onset of visible microstructural damage (voiding, hillock formation). We show here, using a synchrotron technique of white beam x-ray microdiffraction, that the extent of this electromigration-induced plasticity is dependent on the linewidth. In wide lines, plastic deformation manifests itself as grain bending and the formation of subgrain structures, while only grain rotation is observed in the narrower lines. The deformation geometry leads us to conclude that dislocations introduced by plastic flow lie predominantly in the direction of electron flow and may provide additional easy paths for the transport of point defects. Since these findings occur long before any observable voids or hillocks are formed, they may have direct bearing on the final failure stages of electromigration.
Using directed information for influence discovery in interconnected dynamical systems
NASA Astrophysics Data System (ADS)
Rao, Arvind; Hero, Alfred O.; States, David J.; Engel, James Douglas
2008-08-01
Structure discovery in non-linear dynamical systems is an important and challenging problem that arises in various applications such as computational neuroscience, econometrics, and biological network discovery. Each of these systems have multiple interacting variables and the key problem is the inference of the underlying structure of the systems (which variables are connected to which others) based on the output observations (such as multiple time trajectories of the variables). Since such applications demand the inference of directed relationships among variables in these non-linear systems, current methods that have a linear assumption on structure or yield undirected variable dependencies are insufficient. Hence, in this work, we present a methodology for structure discovery using an information-theoretic metric called directed time information (DTI). Using both synthetic dynamical systems as well as true biological datasets (kidney development and T-cell data), we demonstrate the utility of DTI in such problems.
Saunders, Jeffrey A.
2014-01-01
Direction of self-motion during walking is indicated by multiple cues, including optic flow, nonvisual sensory cues, and motor prediction. I measured the reliability of perceived heading from visual and nonvisual cues during walking, and whether cues are weighted in an optimal manner. I used a heading alignment task to measure perceived heading during walking. Observers walked toward a target in a virtual environment with and without global optic flow. The target was simulated to be infinitely far away, so that it did not provide direct feedback about direction of self-motion. Variability in heading direction was low even without optic flow, with average RMS error of 2.4°. Global optic flow reduced variability to 1.9°–2.1°, depending on the structure of the environment. The small amount of variance reduction was consistent with optimal use of visual information. The relative contribution of visual and nonvisual information was also measured using cue conflict conditions. Optic flow specified a conflicting heading direction (±5°), and bias in walking direction was used to infer relative weighting. Visual feedback influenced heading direction by 16%–34% depending on scene structure, with more effect with dense motion parallax. The weighting of visual feedback was close to the predictions of an optimal integration model given the observed variability measures. PMID:24648194
Resolution of structural heterogeneity in dynamic crystallography
Ren, Zhong; Chan, Peter W. Y.; Moffat, Keith; Pai, Emil F.; Royer, William E.; Šrajer, Vukica; Yang, Xiaojing
2013-01-01
Dynamic behavior of proteins is critical to their function. X-ray crystallography, a powerful yet mostly static technique, faces inherent challenges in acquiring dynamic information despite decades of effort. Dynamic ‘structural changes’ are often indirectly inferred from ‘structural differences’ by comparing related static structures. In contrast, the direct observation of dynamic structural changes requires the initiation of a biochemical reaction or process in a crystal. Both the direct and the indirect approaches share a common challenge in analysis: how to interpret the structural heterogeneity intrinsic to all dynamic processes. This paper presents a real-space approach to this challenge, in which a suite of analytical methods and tools to identify and refine the mixed structural species present in multiple crystallographic data sets have been developed. These methods have been applied to representative scenarios in dynamic crystallography, and reveal structural information that is otherwise difficult to interpret or inaccessible using conventional methods. PMID:23695239
Resolution of structural heterogeneity in dynamic crystallography.
Ren, Zhong; Chan, Peter W Y; Moffat, Keith; Pai, Emil F; Royer, William E; Šrajer, Vukica; Yang, Xiaojing
2013-06-01
Dynamic behavior of proteins is critical to their function. X-ray crystallography, a powerful yet mostly static technique, faces inherent challenges in acquiring dynamic information despite decades of effort. Dynamic `structural changes' are often indirectly inferred from `structural differences' by comparing related static structures. In contrast, the direct observation of dynamic structural changes requires the initiation of a biochemical reaction or process in a crystal. Both the direct and the indirect approaches share a common challenge in analysis: how to interpret the structural heterogeneity intrinsic to all dynamic processes. This paper presents a real-space approach to this challenge, in which a suite of analytical methods and tools to identify and refine the mixed structural species present in multiple crystallographic data sets have been developed. These methods have been applied to representative scenarios in dynamic crystallography, and reveal structural information that is otherwise difficult to interpret or inaccessible using conventional methods.
NASA Technical Reports Server (NTRS)
Anderson, Kinsey A.
1991-01-01
The objective of this grant was to measure the spatial structure and directivity of the hard X-ray and low energy gamma-ray (100 keV-2 MeV) continuum sources in solar flares using stereoscopic observations made with spectrometers aboard the Pioneer Venus Orbiter (PVO) and Third International Sun Earth Explorer (ISEE-3) spacecraft. Since the hard X-ray emission is produced by energetic electrons through the bremsstrahlung process, the observed directivity can be directly related to the 'beaming' of electrons accelerated during the flare as they propagate from the acceleration region in the corona to the chromosphere/transition region. Some models (e.g., the thick-target model) predict that most of the impulsive hard X-ray/low energy gamma-ray source is located in the chromosphere, the effective height of the X-ray source above the photosphere increasing with the decrease in the photon energy. This can be verified by determining the height-dependence of the photon source through stereoscopic observations of those flares which are partially occulted from the view of one of the two spacecraft. Thus predictions about beaming of electrons as well as their spatial distributions could be tested through the analysis proposed under this grant.
NASA Astrophysics Data System (ADS)
Rodrigues, Jose Eduardo; Liu, Chan Chiang
1991-04-01
The geology of the westernmost part of Rio de Janeiro State (Brazil) is characterized by the conspicuous presence of the Alem Paraiba lineament, a large shear zone extending more than 200 km in N50-60E direction. Parts of Paraiba do Sul river and of the regional topography are strongly related to this geologic feature. Several other lineament directions complete the structural framework that can be seen on remote sensing products. According to well accepted theories of photointerpretation, LANDSAT images with low sun elevation angles should more clearly show those lineaments, because the shadow enhancement of the relief is greatest. Also, considering the high grade of relief conditionment by the Alem Paraiba lineament, it is expected that this structure could be clearly observed on LANDSAT images of all seasons. However, these hypotheses are not confirmed. The images with low sun elevation angles belong to the epoch (winter) in which the solar azimuths are nearly parallel to the regional structure, making its identification difficult. In summer, the images have high sun elevation angles but their solar azimuths, oblique to the regional structures, allow an adequate identification of the main structural trend.
A reduced adaptive observer for multivariable systems. [using reduced dynamic ordering
NASA Technical Reports Server (NTRS)
Carroll, R. L.; Lindorff, D. P.
1973-01-01
An adaptive observer for multivariable systems is presented for which the dynamic order of the observer is reduced, subject to mild restrictions. The observer structure depends directly upon the multivariable structure of the system rather than a transformation to a single-output system. The number of adaptive gains is at most the sum of the order of the system and the number of input parameters being adapted. Moreover, for the relatively frequent specific cases for which the number of required adaptive gains is less than the sum of system order and input parameters, the number of these gains is easily determined by inspection of the system structure. This adaptive observer possesses all the properties ascribed to the single-input single-output adpative observer. Like the other adaptive observers some restriction is required of the allowable system command input to guarantee convergence of the adaptive algorithm, but the restriction is more lenient than that required by the full-order multivariable observer. This reduced observer is not restricted to cycle systems.
P and S Velocity Structure in the Groningen Gas Reservoir From Noise Interferometry
NASA Astrophysics Data System (ADS)
Zhou, Wen; Paulssen, Hanneke
2017-12-01
Noise interferometry has proven to be a powerful tool to image seismic structure. In this study we used data from 10 geophones located in a borehole at ˜3 km depth within the Groningen gas reservoir in the Netherlands. The continuous data cross correlations show that noise predominantly comes in from above. The observed daily and weekly variations further indicate that the noise has an anthropogenic origin. The direct P wave emerges from the stacked vertical component cross correlations with frequencies up to 80 Hz and the direct S wave is retrieved from the horizontal components with frequencies up to 50 Hz. The measured intergeophone travel times were used to retrieve the P and S velocity structure along the borehole, and a good agreement was found with well log data. In addition, from the S wave polarizations, we determined azimuthal anisotropy with a fast direction of N65°W±18° and an estimated magnitude of (4±2)%. The fast polarization direction corresponds to the present direction of maximum horizontal stress measured at nearby boreholes but is also similar to the estimated paleostress direction.
Direct observation of forward-scattering oscillations in the H+HD→H2+D reaction.
Yuan, Daofu; Yu, Shengrui; Chen, Wentao; Sang, Jiwei; Luo, Chang; Wang, Tao; Xu, Xin; Casavecchia, Piergiorgio; Wang, Xingan; Sun, Zhigang; Zhang, Dong H; Yang, Xueming
2018-06-01
Accurate measurements of product state-resolved angular distributions are central to fundamental studies of chemical reaction dynamics. Yet, fine quantum-mechanical structures in product angular distributions of a reactive scattering process, such as the fast oscillations in the forward-scattering direction, have never been observed experimentally and the nature of these oscillations has not been fully explored. Here we report the crossed-molecular-beam experimental observation of these fast forward-scattering oscillations in the product angular distribution of the benchmark chemical reaction, H + HD → H 2 + D. Clear oscillatory structures are observed for the H 2 (v' = 0, j' = 1, 3) product states at a collision energy of 1.35 eV, in excellent agreement with the quantum-mechanical dynamics calculations. Our analysis reveals that the oscillatory forward-scattering components are mainly contributed by the total angular momentum J around 28. The partial waves and impact parameters responsible for the forward scatterings are also determined from these observed oscillations, providing crucial dynamics information on the transient reaction process.
The Spatially Resolved H(alpha)-Emitting Wind Structure of P Cygni
2010-06-01
using radio and optical interferometry, as well as direct imaging with adaptive optics (AO). Radio interferometric observations detect the nebula around...to structures in the nebula of P Cyg that are more than an order of magnitude smaller. Therefore, optical interferometry provides a unique window of
Hasselmo, Michael E.
2008-01-01
The spiking activity of hippocampal neurons during REM sleep exhibits temporally structured replay of spiking occurring during previously experienced trajectories (Louie and Wilson, 2001). Here, temporally structured replay of place cell activity during REM sleep is modeled in a large-scale network simulation of grid cells, place cells and head direction cells. During simulated waking behavior, the movement of the simulated rat drives activity of a population of head direction cells that updates the activity of a population of entorhinal grid cells. The population of grid cells drives the activity of place cells coding individual locations. Associations between location and movement direction are encoded by modification of excitatory synaptic connections from place cells to speed modulated head direction cells. During simulated REM sleep, the population of place cells coding an experienced location activates the head direction cells coding the associated movement direction. Spiking of head direction cells then causes frequency shifts within the population of entorhinal grid cells to update a phase representation of location. Spiking grid cells then activate new place cells that drive new head direction activity. In contrast to models that perform temporally compressed sequence retrieval similar to sharp wave activity, this model can simulate data on temporally structured replay of hippocampal place cell activity during REM sleep at time scales similar to those observed during waking. These mechanisms could be important for episodic memory of trajectories. PMID:18973557
NASA Astrophysics Data System (ADS)
Dove, P. M.; Davis, K. J.; De Yoreo, J. J.; Orme, C. A.
2001-12-01
Deciphering the complex strategies by which organisms produce nanocrystalline materials with exquisite morphologies is central to understanding biomineralizing systems. One control on the morphology of biogenic nanoparticles is the specific interactions of their surfaces with the organic functional groups provided by the organism and the various inorganic species present in the ambient environment. It is now possible to directly probe the microscopic structural controls on crystal morphology by making quantitative measurements of the dynamic processes occurring at the mineral-water interface. These observations can provide crucial information concerning the actual mechanisms of growth that is otherwise unobtainable through macroscopic techniques. Here we use in situ molecular-scale observations of step dynamics and growth hillock morphology to directly resolve roles of principal impurities in regulating calcite surface morphologies. We show that the interactions of certain inorganic as well as organic impurities with the calcite surface are dependent upon the molecular-scale structures of step-edges. These interactions can assume a primary role in directing crystal morphology. In calcite growth experiments containing magnesium, we show that growth hillock structures become modified owing to the preferential inhibition of step motion along directions approximately parallel to the [010]. Compositional analyses have shown that Mg incorporates at different levels into the two types of nonequivalent steps, which meet at the hillock corner parallel to [010]. A simple calculation of the strain caused by this difference indicates that we should expect a significant retardation at this corner, in agreement with the observed development of [010] steps. If the low-energy step-risers produced by these [010] steps is perpendicular to the c-axis as seems likely from crystallographic considerations, this effect provides a plausible mechanism for the elongated calcite crystal habits found in natural environments that contain magnesium. In a separate study, step-specific interactions are also found between chiral aspartate molecules and the calcite surface. The L and D- aspartate enantiomers exhibit structure preferences for the different types of step-risers on the calcite surface. These site-specific interactions result in the transfer of asymmetry from the organic molecule to the crystal surface through the formation of chiral growth hillocks and surface morphologies. These studies yield direct experimental insight into the molecular-scale structural controls on nanocrystal morphology in biomineralizing systems.
NASA Astrophysics Data System (ADS)
Innocenti, M. E.; Cazzola, E.; Mistry, R.; Eastwood, J. P.; Goldman, M. V.; Newman, D. L.; Markidis, S.; Lapenta, G.
2017-04-01
In Innocenti et al. (2015) we have observed and characterized for the first time Petschek-like switch-off slow shock/rotational discontinuity (SO-SS/RD) compound structures in a 2-D fully kinetic simulation of collisionless magnetic reconnection. Observing these structures in the solar wind or in the magnetotail would corroborate the possibility that Petschek exhausts develop in collisionless media as a result of single X point collisionless reconnection. Here we highlight their signatures in simulations with the aim of easing their identification in observations. The most notable signatures include a four-peaked ion current profile in the out-of-plane direction, associated ion distribution functions, increased electron and ion anisotropy downstream the SS, and increased electron agyrotropy downstream the RDs.
Brown bear response to elevated viewing structures at Brooks River, Alaska
DeBruyn, T.D.; Smith, T.S.; Proffitt, K.; Partridge, S.; Drummer, T.D.
2004-01-01
The increasing popularity of brown bear (Ursus arctos) viewing at Brooks River in Katmai National Park, Alaska has resulted in overcrowded facilities, increasing bear-human conflicts, displacement of bears from important habitats, and degradation of cultural resources. To partially address these issues, the National Park Service (NPS) constructed a 300-m-long elevated boardwalk with interconnected viewing platforms in August 2000. To determine what effects the new structures might have on individual bears, we observed bear movements and behaviors before and after construction. We used direct observations and motion-detection cameras to construct temporal-spatial profiles of bear activity. Although bear numbers were similar (59 bears in 2000 and 56 bears in 2001) and bear activity within the greater Brooks River area did not differ (P = 0.62, n = 29) between the 2 years of this study, trail crossings in the vicinity of the new structures decreased 78% (7,436 crossings in 2000 and 1,646 crossings in 2001; ??2 = 762, df = 14, P < 0.001). Bear temporal use of the boardwalk area changed such that when human use was highest, bear use was proportionally lower in the post- versus pre-construction phase (??2 = 34, df = 3, P < 0.005). Of 123 direct observations of bears approaching to pass beneath the structures, only 19.5% rerouted or avoided crossing under the structures. Bears' responses to the new structures were influenced by the behavior of visitors upon the structures. Potential management tools to minimize impacts of these structures on bears include enhanced public education regarding visitor conduct on the boardwalk, as well as visitor management and monitoring.
Self-organizing Large-scale Structures in Earth's Foreshock Waves
NASA Astrophysics Data System (ADS)
Ganse, U.; Pfau-Kempf, Y.; Turc, L.; Hoilijoki, S.; von Alfthan, S.; Vainio, R. O.; Palmroth, M.
2017-12-01
Earth's foreshock is populated by plasma waves in the ULF regime, assumed to be caused by wave instabilities of shock-reflected particle beams. While in-situ observation of these waves has provided plentiful data of their amplitudes, frequencies, obliquities and relation to local plasma conditions, global-scale structures are hard to grasp from observation data alone. The hybrid-Vlasov simulation system Vlasiator, designed for kinetic modeling of the Earth's magnetosphere, has been employed to study foreshock formation under radial and near-radial IMF conditions on global scales. Structures arising in the foreshock can be comprehensively studied and directly compared to observation results. Our modeling results show that foreshock waves present emergent large-scale structures, in which regions of waves with similar phase exist. At the interfaces of these regions ("spines") we observe high wave obliquity, higher beam densities and lower beam velocities than inside them. We characterize these apparently self-organizing structures through the interplay between wave- and beam properties and present the microphysical mechanisms involved in their creation.
Fisher, Zoë; Kovalevsky, Andrey Y; Mustyakimov, Marat; Silverman, David N; McKenna, Robert; Langan, Paul
2011-11-08
The neutron structure of wild-type human carbonic anhydrase II at pH 7.8 has been determined to 2.0 Å resolution. Detailed analysis and comparison to the previously determined structure at pH 10.0 show important differences in the protonation of key catalytic residues in the active site as well as a rearrangement of the H-bonded water network. For the first time, a completed H-bonded network stretching from the Zn-bound solvent to the proton shuttling residue, His64, has been directly observed.
Direct Observation of Dislocation Core Structures in CdTe/GaAs(001).
McGibbon, A J; Pennycook, S J; Angelo, J E
1995-07-28
A strategy is presented for determining sublattice polarity at defects in compound semiconductors. Core structures of 60-degree and Lomer dislocations in the CdTe/GaAs(001) system have been obtained by the application of maximum-entropy analysis to Z-contrast images (Z is atomic number) obtained in a 300-kilovolt scanning transmission electron microscope. Sixty-degree dislocations were observed to be of the glide type, whereas in the case of Lomer dislocations, both a symmetric (Hornstra-like) core and an unexpected asymmetric structure made up of a fourfold ring were seen.
Insights to primitive replication derived from structures of small oligonucleotides
NASA Technical Reports Server (NTRS)
Smith, G. K.; Fox, G. E.
1995-01-01
Available information on the structure of small oligonucleotides is surveyed. It is observed that even small oligomers typically exhibit defined structures over a wide range of pH and temperature. These structures rely on a plethora of non-standard base-base interactions in addition to the traditional Watson-Crick pairings. Stable duplexes, though typically antiparallel, can be parallel or staggered and perfect complementarity is not essential. These results imply that primitive template directed reactions do not require high fidelity. Hence, the extensive use of Watson-Crick complementarity in genes rather than being a direct consequence of the primitive condensation process, may instead reflect subsequent selection based on the advantage of accuracy in maintaining the primitive genetic machinery once it arose.
Control range: a controllability-based index for node significance in directed networks
NASA Astrophysics Data System (ADS)
Wang, Bingbo; Gao, Lin; Gao, Yong
2012-04-01
While a large number of methods for module detection have been developed for undirected networks, it is difficult to adapt them to handle directed networks due to the lack of consensus criteria for measuring the node significance in a directed network. In this paper, we propose a novel structural index, the control range, motivated by recent studies on the structural controllability of large-scale directed networks. The control range of a node quantifies the size of the subnetwork that the node can effectively control. A related index, called the control range similarity, is also introduced to measure the structural similarity between two nodes. When applying the index of control range to several real-world and synthetic directed networks, it is observed that the control range of the nodes is mainly influenced by the network's degree distribution and that nodes with a low degree may have a high control range. We use the index of control range similarity to detect and analyze functional modules in glossary networks and the enzyme-centric network of homo sapiens. Our results, as compared with other approaches to module detection such as modularity optimization algorithm, dynamic algorithm and clique percolation method, indicate that the proposed indices are effective and practical in depicting structural and modular characteristics of sparse directed networks.
Extracting Primordial Non-Gaussianity from Large Scale Structure in the Post-Planck Era
NASA Astrophysics Data System (ADS)
Dore, Olivier
Astronomical observations have become a unique tool to probe fundamental physics. Cosmology, in particular, emerged as a data-driven science whose phenomenological modeling has achieved great success: in the post-Planck era, key cosmological parameters are measured to percent precision. A single model reproduces a wealth of astronomical observations involving very distinct physical processes at different times. This success leads to fundamental physical questions. One of the most salient is the origin of the primordial perturbations that grew to form the large-scale structures we now observe. More and more cosmological observables point to inflationary physics as the origin of the structure observed in the universe. Inflationary physics predict the statistical properties of the primordial perturbations and it is thought to be slightly non-Gaussian. The detection of this small deviation from Gaussianity represents the next frontier in early Universe physics. To measure it would provide direct, unique and quantitative insights about the physics at play when the Universe was only a fraction of a second old, thus probing energies untouchable otherwise. En par with the well-known relic gravitational wave radiation -- the famous ``B-modes'' -- it is one the few probes of inflation. This departure from Gaussianity leads to very specific signature in the large scale clustering of galaxies. Observing large-scale structure, we can thus establish a direct connection with fundamental theories of the early universe. In the post-Planck era, large-scale structures are our most promising pathway to measuring this primordial signal. Current estimates suggests that the next generation of space or ground based large scale structure surveys (e.g. the ESA EUCLID or NASA WFIRST missions) might enable a detection of this signal. This potential huge payoff requires us to solidify the theoretical predictions supporting these measurements. Even if the exact signal we are looking for is of unknown amplitude, it is obvious that we must measure it as well as these ground breaking data set will permit. We propose to develop the supporting theoretical work to the point where the complete non-gaussianian signature can be extracted from these data sets. We will do so by developing three complementary directions: - We will develop the appropriate formalism to measure and model galaxy clustering on the largest scales. - We will study the impact of non-Gaussianity on higher-order statistics, the most promising statistics for our purpose.. - We will explicit the connection between these observables and the microphysics of a large class of inflation models, but also identify fundamental limitations to this interpretation.
Anisotropic piezoresistivity characteristics of aligned carbon nanotube-polymer nanocomposites
NASA Astrophysics Data System (ADS)
Sengezer, Engin C.; Seidel, Gary D.; Bodnar, Robert J.
2017-09-01
Dielectrophoresis under the application of AC electric fields is one of the primary fabrication techniques for obtaining aligned carbon nanotube (CNT)-polymer nanocomposites, and is used here to generate long range alignment of CNTs at the structural level. The degree of alignment of CNTs within this long range architecture is observed via polarized Raman spectroscopy so that its influence on the electrical conductivity and piezoresistive response in both the alignment and transverse to alignment directions can be assessed. Nanocomposite samples consisting of randomly oriented, well dispersed single-wall carbon nanotubes (SWCNTs) and of long range electric field aligned SWCNTs in a photopolymerizable monomer blend (urethane dimethacrylate and 1,6-hexanediol dimethacrylate) are quantitatively and qualitatively evaluated. Piezoresistive sensitivities in form of gauge factors were measured for randomly oriented, well dispersed specimens with 0.03, 0.1 and 0.5 wt% SWCNTs and compared with gauge factors in both the axial and transverse to SWCNT alignment directions for electric field aligned 0.03 wt% specimens under both quasi-static monotonic and cyclic tensile loading. Gauge factors in the axial direction were observed to be on the order of 2, while gauge factors in the transverse direction demonstrated a 5 fold increase with values on the order of 10 for aligned specimens. Based on Raman analysis, it is believed the higher sensitivity of the transverse direction is related to architectural evolution of misaligned bridging structures which connect alignment structures under load due to Poisson’s contraction.
Impact localization on composite structures using time difference and MUSIC approach
NASA Astrophysics Data System (ADS)
Zhong, Yongteng; Xiang, Jiawei
2017-05-01
1-D uniform linear array (ULA) has the shortcoming of the half-plane mirror effect, which does not allow discriminating between a target placed above the array and a target placed below the array. This paper presents time difference (TD) and multiple signal classification (MUSIC) based omni-directional impact localization on a large stiffened composite structure using improved linear array, which is able to perform omni-directional 360° localization. This array contains 2M+3 PZT sensors, where 2M+1 PZT sensors are arranged as a uniform linear array, and the other two PZT sensors are placed above and below the array. Firstly, the arrival times of impact signals observed by the other two sensors are determined using the wavelet transform. Compared with each other, the direction range of impact source can be decided in general, 0°to 180° or 180°to 360°. And then, two dimensional multiple signal classification (2D-MUSIC) based spatial spectrum formula using the uniform linear array is applied for impact localization by the general direction range. When the arrival times of impact signals observed by upper PZT is equal to that of lower PZT, the direction can be located in x axis (0°or 180°). And time difference based MUSIC method is present to locate impact position. To verify the proposed approach, the proposed approach is applied to a composite structure. The localization results are in good agreement with the actual impact occurring positions.
NASA Astrophysics Data System (ADS)
Uebayashi, Hirotoshi; Kawabe, Hidenori; Kamae, Katsuhiro
2012-05-01
Estimating the velocity structure of microseisms based on the horizontal-to-vertical spectral ratio (HVSR) is an extremely practical means of modelling the subsurface structure necessary for strong ground motion predictions. Thus, beyond the traditional framework of the 1-D velocity structure, the HVSR, derived from observation records of microseisms (microtremors with a frequency of about 1 Hz or lower originating from ocean waves) in areas where the sediment-bedrock interface has irregular topographies, was reproduced by finite differential method (FDM)-based simulation. This study was conducted for the Osaka sedimentary basin, the sediment-bedrock interface of which is three-dimensionally complicated and contains grabens, steps and ramps, because high-precision models for this basin have been constructed based on a wide range of existing exploration information. The HVSRs of two components (the east-west direction and the north-south direction to the vertical direction) derived from the FDM simulations were both well reproduced in terms of not only the peak frequency (HVfp) but also the spectral curves for a number of observation sites above the sediment-bedrock interface with complex geological features. These results suggest that with a sufficient number of observation sites for microtremors and highly accurate a priori information on geophysical constants in the sedimentary layer that spatially serves as the reference, the irregular-shaped sediment-bedrock interface may be estimated based on how well the HVSR curves and the HVfp agree between the observations and simulations. Furthermore, the FDM simulations confirmed observed phenomena such as the polarization of the amplitude of horizontal motions and broad or 'plateau-like' HVSR peaks of microseisms in grabens and step structures. It was determined that the HVfps in areas with these strong irregularities are higher than the peak frequency of Rayleigh wave ellipticity for the fundamental mode (RHVfp) based on the 1-D velocity structure. In addition, there was a difference of about 20 per cent at most between the HVfp derived from FDM simulations and the RHVfp in areas where the depth of the sediment-bedrock interface varies only slightly.
Motivation and Social Capital among prospective blood donors in three large blood centers in Brazil
Gonçalez, Thelma T.; Di Lorenzo Oliveira, Claudia; Carneiro-Proietti, Anna Barbara F.; Moreno, Elizabeth C.; Miranda, Carolina; Larsen, Nina; Wright, David; Leão, Silvana; Loureiro, Paula; de Almeida-Neto, Cesar; Lopes, Maria-Inês; Proietti, Fernando A.; Custer, Brian; Sabino, Ester
2012-01-01
Background Studies analyzing motivation factors that lead to blood donation have found altruism to be the primary motivation factor; however social capital has not been analyzed in this context. Our study examines the association between motivation factors (altruism, self-interest and response to direct appeal) and social capital (cognitive and structural) across three large blood centers in Brazil. Study Design and Methods We conducted a cross-sectional survey of 7,635 donor candidates from October 15 through November 20, 2009. Participants completed self-administered questionnaires on demographics, previous blood donation, HIV testing and knowledge, social capital and donor motivations. Enrollment was determined prior to the donor screening process. Results Among participants, 43.5% and 41.7% expressed high levels of altruism and response to direct appeal respectively, while only 26.9% expressed high levels of self-interest. More high self-interest was observed at Hemope-Recife (41.7%). Of participants, 37.4% expressed high levels of cognitive social capital while 19.2% expressed high levels of structural social capital. More high cognitive and structural social capital was observed at Hemope-Recife (47.3% and 21.3%, respectively). High cognitive social capital was associated with high levels of altruism, self-interest and response to direct appeal. Philanthropic and high social altruism was associated with high levels of altruism and response to direct appeal. Conclusion Cognitive and structural social capital and social altruism are associated with altruism and response to direct appeal, while only cognitive social capital is associated with self-interest. Designing marketing campaigns with these aspects in mind may help blood banks attract potential blood donors more efficiently. PMID:22998740
Motivation and social capital among prospective blood donors in three large blood centers in Brazil.
Gonçalez, Thelma T; Di Lorenzo Oliveira, Claudia; Carneiro-Proietti, Anna Barbara F; Moreno, Elizabeth C; Miranda, Carolina; Larsen, Nina; Wright, David; Leão, Silvana; Loureiro, Paula; de Almeida-Neto, Cesar; Lopes, Maria-Inês; Proietti, Fernando A; Custer, Brian; Sabino, Ester
2013-06-01
Studies analyzing motivation factors that lead to blood donation have found altruism to be the primary motivation factor; however, social capital has not been analyzed in this context. Our study examines the association between motivation factors (altruism, self-interest, and response to direct appeal) and social capital (cognitive and structural) across three large blood centers in Brazil. We conducted a cross-sectional survey of 7635 donor candidates from October 15 through November 20, 2009. Participants completed self-administered questionnaires on demographics, previous blood donation, human immunodeficiency virus testing and knowledge, social capital, and donor motivations. Enrollment was determined before the donor screening process. Among participants, 43.5 and 41.7% expressed high levels of altruism and response to direct appeal, respectively, while only 26.9% expressed high levels of self-interest. More high self-interest was observed at Hemope-Recife (41.7%). Of participants, 37.4% expressed high levels of cognitive social capital while 19.2% expressed high levels of structural social capital. More high cognitive and structural social capital was observed at Hemope-Recife (47.3 and 21.3%, respectively). High cognitive social capital was associated with high levels of altruism, self-interest, and response to direct appeal. Philanthropic and high social altruism were associated with high levels of altruism and response to direct appeal. Cognitive and structural social capital and social altruism are associated with altruism and response to direct appeal, while only cognitive social capital is associated with self-interest. Designing marketing campaigns with these aspects in mind may help blood banks attract potential blood donors more efficiently. © 2012 American Association of Blood Banks.
NASA Astrophysics Data System (ADS)
Yazdani, Ahmad; Hamreh, Sajad
2018-03-01
The electronic structure of the nanocrystallines and quasi-two-dimensional systems strongly impressed by the thermodynamic- behavior mainly due to excess of hidden surface free energy. Therefore, the stability of crystalline structure’s change could be related to band-offset of bond rupturing of atomic displacements. whereas for the electronic-structure of "Bi" it seams the competition of L.S and bond exchange should be effectively dominated. Besides all of the characters behave spatial like strong sensitive oxidation here it is supposed that strong correlated electronic structure in the absence of oxygen is resulted on direction of redistribution of surface chemical bond formation before any reconstructive structure. Where • The metallic direction of electronic structure “0 1 1” is changed to “1 1 1” semiconductor direction. • the effect of L.S is more evident on the local density of state while it is not observable around the fermi level. • Strong effect of spin-orbit interaction on splitting of the valance to nearly conduction band around the fermi level is more evident.
Proximity-induced superconductivity within the InAs/GaSb edge conducting state
NASA Astrophysics Data System (ADS)
Kononov, A.; Kostarev, V. A.; Semyagin, B. R.; Preobrazhenskii, V. V.; Putyato, M. A.; Emelyanov, E. A.; Deviatov, E. V.
2017-12-01
We experimentally investigate Andreev transport through the interface between an indium superconductor and the edge of the InAs/GaSb bilayer. To cover all possible regimes of the InAs/GaSb spectrum, we study samples with 10-nm-, 12-nm-, and 14-nm-thick InAs quantum wells. For the trivial case of a direct band insulator in 10 nm samples, differential resistance demonstrates standard Andreev reflection. For InAs/GaSb structures with band inversion (12 and 14 nm samples), we observe distinct low-energy structures, which we regard as direct evidence for the proximity-induced superconductivity within the current-carrying edge state. For 14 nm InAs well samples, we additionally observe mesoscopiclike resistance fluctuations, which are subjected to threshold suppression in low magnetic fields.
Miller, Thomas F.
2017-01-01
We present a coarse-grained simulation model that is capable of simulating the minute-timescale dynamics of protein translocation and membrane integration via the Sec translocon, while retaining sufficient chemical and structural detail to capture many of the sequence-specific interactions that drive these processes. The model includes accurate geometric representations of the ribosome and Sec translocon, obtained directly from experimental structures, and interactions parameterized from nearly 200 μs of residue-based coarse-grained molecular dynamics simulations. A protocol for mapping amino-acid sequences to coarse-grained beads enables the direct simulation of trajectories for the co-translational insertion of arbitrary polypeptide sequences into the Sec translocon. The model reproduces experimentally observed features of membrane protein integration, including the efficiency with which polypeptide domains integrate into the membrane, the variation in integration efficiency upon single amino-acid mutations, and the orientation of transmembrane domains. The central advantage of the model is that it connects sequence-level protein features to biological observables and timescales, enabling direct simulation for the mechanistic analysis of co-translational integration and for the engineering of membrane proteins with enhanced membrane integration efficiency. PMID:28328943
Self-interacting inelastic dark matter: a viable solution to the small scale structure problems
DOE Office of Scientific and Technical Information (OSTI.GOV)
Blennow, Mattias; Clementz, Stefan; Herrero-Garcia, Juan, E-mail: emb@kth.se, E-mail: scl@kth.se, E-mail: juan.herrero-garcia@adelaide.edu.au
2017-03-01
Self-interacting dark matter has been proposed as a solution to the small-scale structure problems, such as the observed flat cores in dwarf and low surface brightness galaxies. If scattering takes place through light mediators, the scattering cross section relevant to solve these problems may fall into the non-perturbative regime leading to a non-trivial velocity dependence, which allows compatibility with limits stemming from cluster-size objects. However, these models are strongly constrained by different observations, in particular from the requirements that the decay of the light mediator is sufficiently rapid (before Big Bang Nucleosynthesis) and from direct detection. A natural solution tomore » reconcile both requirements are inelastic endothermic interactions, such that scatterings in direct detection experiments are suppressed or even kinematically forbidden if the mass splitting between the two-states is sufficiently large. Using an exact solution when numerically solving the Schrödinger equation, we study such scenarios and find regions in the parameter space of dark matter and mediator masses, and the mass splitting of the states, where the small scale structure problems can be solved, the dark matter has the correct relic abundance and direct detection limits can be evaded.« less
Investigation of the moving structures in a coronal bright point
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ning, Zongjun; Guo, Yang, E-mail: ningzongjun@pmo.ac.cn
2014-10-10
We have explored the moving structures in a coronal bright point (CBP) observed by the Solar Dynamic Observatory Atmospheric Imaging Assembly (AIA) on 2011 March 5. This CBP event has a lifetime of ∼20 minutes and is bright with a curved shape along a magnetic loop connecting a pair of negative and positive fields. AIA imaging observations show that a lot of bright structures are moving intermittently along the loop legs toward the two footpoints from the CBP brightness core. Such moving bright structures are clearly seen at AIA 304 Å. In order to analyze their features, the CBP ismore » cut along the motion direction with a curved slit which is wide enough to cover the bulk of the CBP. After integrating the flux along the slit width, we get the spacetime slices at nine AIA wavelengths. The oblique streaks starting from the edge of the CBP brightness core are identified as moving bright structures, especially on the derivative images of the brightness spacetime slices. They seem to originate from the same position near the loop top. We find that these oblique streaks are bi-directional, simultaneous, symmetrical, and periodic. The average speed is about 380 km s{sup –1}, and the period is typically between 80 and 100 s. Nonlinear force-free field extrapolation shows the possibility that magnetic reconnection takes place during the CBP, and our findings indicate that these moving bright structures could be the observational outflows after magnetic reconnection in the CBP.« less
NASA Astrophysics Data System (ADS)
Imai, Hiroshi; Shima, Tomohiro; Sutoh, Kazuo; Walker, Matthew L.; Knight, Peter J.; Kon, Takahide; Burgess, Stan A.
2015-09-01
Cytoplasmic dynein is a dimeric AAA+ motor protein that performs critical roles in eukaryotic cells by moving along microtubules using ATP. Here using cryo-electron microscopy we directly observe the structure of Dictyostelium discoideum dynein dimers on microtubules at near-physiological ATP concentrations. They display remarkable flexibility at a hinge close to the microtubule binding domain (the stalkhead) producing a wide range of head positions. About half the molecules have the two heads separated from one another, with both leading and trailing motors attached to the microtubule. The other half have the two heads and stalks closely superposed in a front-to-back arrangement of the AAA+ rings, suggesting specific contact between the heads. All stalks point towards the microtubule minus end. Mean stalk angles depend on the separation between their stalkheads, which allows estimation of inter-head tension. These findings provide a structural framework for understanding dynein's directionality and unusual stepping behaviour.
Fine Structure of the Core of the Blazar OJ 287-I
NASA Astrophysics Data System (ADS)
Matveyenko, L. I.; Sivakon', S. S.
2017-12-01
The fine structure of the active region, the bulge, of the blazar OJ 287 has been investigated with a resolution of 20 μas (0.1 pc) at a wavelength of 7 mm, the epochs of 2007-2017. The structure and kinematics correspond to a vortex nature. The surrounding matter, the plasma, is transferred to the center along two arms from opposite directions. The emerging excess angular momentum is carried away along the rotation axis by bipolar outflows, rotating coaxial tubes, in a direction X ≈ -120° in the plane of the sky as it is accumulated. The central high-velocity bipolar outflow has a helical shape. The diameters of the low-velocity flows are ø1 ≈ 0.3 and ø2 ≈ 0.65 mas, or 1.4 and 3 pc, respectively. Ring currents whose tangential directions are observed as parallel chains of components are excited in the flow walls. The peak brightness temperature of the nozzle reaches Tb ≈ 1012-1013 K. A "disk" with a diameter ø ≈ 0.5 mas (≈2.2 pc) is observed by the absorption of synchrotron radiation. The disk is inclined to the plane of the sky at an angle of 60° in the jet direction. The fragments are seen from a distance of ˜0.2 mas outside the absorption zone. The jet sizes exceed considerably the counterjet ones. An enhanced supply of plasma from the northern arm gives rise to an independent vortex 0.2 mas away from the central one in the NW direction. As in the first case, the helical central bipolar outflow is surrounded by a low-velocity component ø ≈ 0.28 mas in diameter with built-in ring currents. The jet is ejected in the direction X = -50° in the plane of the sky. The jet orientation changes, X = -130° at a distance of 1 mas. A high activity of the central and two side nozzles spaced 0.22 mas apart in the direction X = -40° is occasionally observed simultaneously. The active region of the blazar is observed through an ionized medium, a screen, whose influence is significant even at a wavelength of 7 mm. The absorption and refraction of the transmitted emission in the screen affect the apparent brightness relative to the positions of the fragments.
Graham, Jonathan Pietarila; Mininni, Pablo D; Pouquet, Annick
2005-10-01
We present direct numerical simulations and Lagrangian averaged (also known as alpha model) simulations of forced and free decaying magnetohydrodynamic turbulence in two dimensions. The statistics of sign cancellations of the current at small scales is studied using both the cancellation exponent and the fractal dimension of the structures. The alpha model is found to have the same scaling behavior between positive and negative contributions as the direct numerical simulations. The alpha model is also able to reproduce the time evolution of these quantities in free decaying turbulence. At large Reynolds numbers, an independence of the cancellation exponent with the Reynolds numbers is observed.
ERIC Educational Resources Information Center
Good, Ron; And Others
1976-01-01
Studied classroom behaviors and conservation ability of elementary school science students taught by either Student-Structured Learning in Science (SSLS) or Teacher-Structured Learning in Science (TSLS). Reports on how behavior of conservers and nonconservers differs in SSLS and TSLS with respect to observing, following directions, and inventing…
The Social Organization of Participation Structures in Two Classrooms of Indian Students.
ERIC Educational Resources Information Center
Erickson, Frederick; Mohatt, Gerald
Participation structures in two classrooms of culturally similar children (Indian) taught by teachers with different cultural backgrounds (both experienced, one Indian, one non-Indian) were investigated in an Odawa reserve community in Northern Ontario, Canada. Data came from direct observation, videotaping in classrooms and in some children's…
Research on Short Duration Pulsed Radiation Sources.
correlate soft X-ray spots with the hard radiation in a 1 kJ plasma focus showed that field structures leading to the appearance of soft X-ray spots...are always present in this plasma focus . These field structures represent m = 0 plasma instabilities and do have a direct influence upon the observed neutron emission. (Author)
NASA Astrophysics Data System (ADS)
Shank, Joshua C.; Tellekamp, M. Brooks; Doolittle, W. Alan
2015-01-01
The theoretically suggested band structure of the novel p-type semiconductor lithium niobite (LiNbO2), the direct coupling of photons to ion motion, and optically induced band structure modifications are investigated by temperature dependent photoluminescence. LiNbO2 has previously been used as a memristor material but is shown here to be useful as a sensor owing to the electrical, optical, and chemical ease of lithium removal and insertion. Despite the high concentration of vacancies present in lithium niobite due to the intentional removal of lithium atoms, strong photoluminescence spectra are observed even at room temperature that experimentally confirm the suggested band structure implying transitions from a flat conduction band to a degenerate valence band. Removal of small amounts of lithium significantly modifies the photoluminescence spectra including additional larger than stoichiometric-band gap features. Sufficient removal of lithium results in the elimination of the photoluminescence response supporting the predicted transition from a direct to indirect band gap semiconductor. In addition, non-thermal coupling between the incident laser and lithium ions is observed and results in modulation of the electrical impedance.
Structure and Dynamics of Colliding Plasma Jets
Li, C.; Ryutov, D.; Hu, S.; ...
2013-12-01
Monoenergetic-proton radiographs of laser-generated, high-Mach-number plasma jets colliding at various angles shed light on the structures and dynamics of these collisions. The observations compare favorably with results from 2D hydrodynamic simulations of multistream plasma jets, and also with results from an analytic treatment of electron flow and magnetic field advection. In collisions of two noncollinear jets, the observed flow structure is similar to the analytic model’s prediction of a characteristic feature with a narrow structure pointing in one direction and a much thicker one pointing in the opposite direction. Spontaneous magnetic fields, largely azimuthal around the colliding jets and generatedmore » by the well-known ∇T e ×∇n e Biermann battery effect near the periphery of the laser spots, are demonstrated to be “frozen in” the plasma (due to high magnetic Reynolds number R M ~5×10⁴) and advected along the jet streamlines of the electron flow. These studies provide novel insight into the interactions and dynamics of colliding plasma jets.« less
Li, Xiangyang; Song, Baoan; Chen, Xi; Wang, Zhenchao; Zeng, Mengjiao; Yu, Dandan; Hu, Deyu; Chen, Zhuo; Jin, Linhong; Yang, Song; Yang, Caiguang; Chen, Baoen
2013-01-01
Background Crystal structures of the tobacco mosaic virus (TMV) coat protein (CP) in its helical and disk conformations have previously been determined at the atomic level. For the helical structure, interactions of proteins and nucleic acids in the main chains were clearly observed; however, the conformation of residues at the C-terminus was flexible and disordered. For the four-layer aggregate disk structure, interactions of the main chain residues could only be observed through water–mediated hydrogen bonding with protein residues. In this study, the effects of the C-terminal peptides on the interactions of TMV CP were investigated by crystal structure determination. Methodology/Principal Findings The crystal structure of a genetically engineered TMV CP was resolved at 3.06 Å. For the genetically engineered TMV CP, a six-histidine (His) tag was introduced at the N-terminus, and the C-terminal residues 155 to 158 were truncated (N-His-TMV CP19). Overall, N-His-TMV CP19 protein self-assembled into the four-layer aggregate form. The conformations of residues Gln36, Thr59, Asp115 and Arg134 were carefully analyzed in the high radius and low radius regions of N-His-TMV CP19, which were found to be significantly different from those observed previously for the helical and four-layer aggregate forms. In addition, the aggregation of the N-His-TMV CP19 layers was found to primarily be mediated through direct hydrogen-bonding. Notably, this engineered protein also can package RNA effectively and assemble into an infectious virus particle. Conclusion The terminal sequence of amino acids influences the conformation and interactions of the four-layer aggregate. Direct protein–protein interactions are observed in the major overlap region when residues Gly155 to Thr158 at the C-terminus are truncated. This engineered TMV CP is reassembled by direct protein–protein interaction and maintains the normal function of the four-layer aggregate of TMV CP in the presence of RNA. PMID:24223721
DOE Office of Scientific and Technical Information (OSTI.GOV)
Toprasertpong, Kasidit; Fujii, Hiromasa; Sugiyama, Masakazu
2015-07-27
In this study, we propose a carrier time-of-flight technique to evaluate the carrier transport time across a quantum structure in an active region of solar cells. By observing the time-resolved photoluminescence signal with a quantum-well probe inserted under the quantum structure at forward bias, the carrier transport time can be efficiently determined at room temperature. The averaged drift velocity shows linear dependence on the internal field, allowing us to estimate the quantum structure as a quasi-bulk material with low effective mobility containing the information of carrier dynamics. We show that this direct and real-time observation is more sensitive to carriermore » transport than other conventional techniques, providing better insights into microscopic carrier transport dynamics to overcome a device design difficulty.« less
Multiple film plane diagnostic for shocked lattice measurements (invited)
NASA Astrophysics Data System (ADS)
Kalantar, Daniel H.; Bringa, E.; Caturla, M.; Colvin, J.; Lorenz, K. T.; Kumar, M.; Stölken, J.; Allen, A. M.; Rosolankova, K.; Wark, J. S.; Meyers, M. A.; Schneider, M.; Boehly, T. R.
2003-03-01
Laser-based shock experiments have been conducted in thin Si and Cu crystals at pressures above the Hugoniot elastic limit. In these experiments, static film and x-ray streak cameras recorded x rays diffracted from lattice planes both parallel and perpendicular to the shock direction. These data showed uniaxial compression of Si(100) along the shock direction and three-dimensional compression of Cu(100). In the case of the Si diffraction, there was a multiple wave structure observed, which may be due to a one-dimensional phase transition or a time variation in the shock pressure. A new film-based detector has been developed for these in situ dynamic diffraction experiments. This large-angle detector consists of three film cassettes that are positioned to record x rays diffracted from a shocked crystal anywhere within a full π steradian. It records x rays that are diffracted from multiple lattice planes both parallel and at oblique angles with respect to the shock direction. It is a time-integrating measurement, but time-resolved data may be recorded using a short duration laser pulse to create the diffraction source x rays. This new instrument has been fielded at the OMEGA and Janus lasers to study single-crystal materials shock compressed by direct laser irradiation. In these experiments, a multiple wave structure was observed on many different lattice planes in Si. These data provide information on the structure under compression.
Shibata, Naoya; Findlay, Scott D; Matsumoto, Takao; Kohno, Yuji; Seki, Takehito; Sánchez-Santolino, Gabriel; Ikuhara, Yuichi
2017-07-18
The functional properties of materials and devices are critically determined by the electromagnetic field structures formed inside them, especially at nanointerface and surface regions, because such structures are strongly associated with the dynamics of electrons, holes and ions. To understand the fundamental origin of many exotic properties in modern materials and devices, it is essential to directly characterize local electromagnetic field structures at such defect regions, even down to atomic dimensions. In recent years, rapid progress in the development of high-speed area detectors for aberration-corrected scanning transmission electron microscopy (STEM) with sub-angstrom spatial resolution has opened new possibilities to directly image such electromagnetic field structures at very high-resolution. In this Account, we give an overview of our recent development of differential phase contrast (DPC) microscopy for aberration-corrected STEM and its application to many materials problems. In recent years, we have developed segmented-type STEM detectors which divide the detector plane into 16 segments and enable simultaneous imaging of 16 STEM images which are sensitive to the positions and angles of transmitted/scattered electrons on the detector plane. These detectors also have atomic-resolution imaging capability. Using these segmented-type STEM detectors, we show DPC STEM imaging to be a very powerful tool for directly imaging local electromagnetic field structures in materials and devices in real space. For example, DPC STEM can clearly visualize the local electric field variation due to the abrupt potential change across a p-n junction in a GaAs semiconductor, which cannot be observed by normal in-focus bright-field or annular type dark-field STEM imaging modes. DPC STEM is also very effective for imaging magnetic field structures in magnetic materials, such as magnetic domains and skyrmions. Moreover, real-time imaging of electromagnetic field structures can now be realized through very fast data acquisition, processing, and reconstruction algorithms. If we use DPC STEM for atomic-resolution imaging using a sub-angstrom size electron probe, it has been shown that we can directly observe the atomic electric field inside atoms within crystals and even inside single atoms, the field between the atomic nucleus and the surrounding electron cloud, which possesses information about the atomic species, local chemical bonding and charge redistribution between bonded atoms. This possibility may open an alternative way for directly visualizing atoms and nanostructures, that is, seeing atoms as an entity of electromagnetic fields that reflect the intra- and interatomic electronic structures. In this Account, the current status of aberration-corrected DPC STEM is highlighted, along with some applications in real material and device studies.
Direct Interferometric Imaging with IOTA Interferometer: Morphology of the Water Shell around U Ori
NASA Astrophysics Data System (ADS)
Pluzhnik, Eugene; Ragland, S.; Le Coroller, H.; Cotton, W.; Danchi, W.; Traub, W.; Willson, L.
2007-12-01
Optical interferometric observations of Mira stars with adequate resolution using the 3-telescope Infrared Optical Telescope Array (IOTA) interferometer have shown detectable asymmetry in several Mira stars. Several mechanisms have been proposed to explain the observed asymmetry. In this paper, we present subsequent IOTA observations of a Mira star, namely, U Ori taken at 1.51, 1.64 and 1.78 μm in 2005. The reconstructed images based on a model independent algorithm are also presented. These images show asymmetric structures of the water shell that is similar to the structure of 22 GHz masers obtained by Vlemmings et al. in 2003. We explore the possibility of the detection of molecular shell rotation with a period of about 30 years by comparing our results with radio observations and discuss a possible geometric structure of the shell.
Preventing Data Ambiguity in Infectious Diseases with Four-Dimensional and Personalized Evaluations
Iandiorio, Michelle J.; Fair, Jeanne M.; Chatzipanagiotou, Stylianos; Ioannidis, Anastasios; Trikka-Graphakos, Eleftheria; Charalampaki, Nikoletta; Sereti, Christina; Tegos, George P.; Hoogesteijn, Almira L.; Rivas, Ariel L.
2016-01-01
Background Diagnostic errors can occur, in infectious diseases, when anti-microbial immune responses involve several temporal scales. When responses span from nanosecond to week and larger temporal scales, any pre-selected temporal scale is likely to miss some (faster or slower) responses. Hoping to prevent diagnostic errors, a pilot study was conducted to evaluate a four-dimensional (4D) method that captures the complexity and dynamics of infectious diseases. Methods Leukocyte-microbial-temporal data were explored in canine and human (bacterial and/or viral) infections, with: (i) a non-structured approach, which measures leukocytes or microbes in isolation; and (ii) a structured method that assesses numerous combinations of interacting variables. Four alternatives of the structured method were tested: (i) a noise-reduction oriented version, which generates a single (one data point-wide) line of observations; (ii) a version that measures complex, three-dimensional (3D) data interactions; (iii) a non-numerical version that displays temporal data directionality (arrows that connect pairs of consecutive observations); and (iv) a full 4D (single line-, complexity-, directionality-based) version. Results In all studies, the non-structured approach revealed non-interpretable (ambiguous) data: observations numerically similar expressed different biological conditions, such as recovery and lack of recovery from infections. Ambiguity was also found when the data were structured as single lines. In contrast, two or more data subsets were distinguished and ambiguity was avoided when the data were structured as complex, 3D, single lines and, in addition, temporal data directionality was determined. The 4D method detected, even within one day, changes in immune profiles that occurred after antibiotics were prescribed. Conclusions Infectious disease data may be ambiguous. Four-dimensional methods may prevent ambiguity, providing earlier, in vivo, dynamic, complex, and personalized information that facilitates both diagnostics and selection or evaluation of anti-microbial therapies. PMID:27411058
Molecular Dynamics Simulations and XAFS (MD-XAFS)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schenter, Gregory K.; Fulton, John L.
2017-01-20
MD-XAFS (Molecular Dynamics X-ray Adsorption Fine Structure) makes the connection between simulation techniques that generate an ensemble of molecular configurations and the direct signal observed from X-ray measurement.
Dark matter self-interactions and small scale structure
NASA Astrophysics Data System (ADS)
Tulin, Sean; Yu, Hai-Bo
2018-02-01
We review theories of dark matter (DM) beyond the collisionless paradigm, known as self-interacting dark matter (SIDM), and their observable implications for astrophysical structure in the Universe. Self-interactions are motivated, in part, due to the potential to explain long-standing (and more recent) small scale structure observations that are in tension with collisionless cold DM (CDM) predictions. Simple particle physics models for SIDM can provide a universal explanation for these observations across a wide range of mass scales spanning dwarf galaxies, low and high surface brightness spiral galaxies, and clusters of galaxies. At the same time, SIDM leaves intact the success of ΛCDM cosmology on large scales. This report covers the following topics: (1) small scale structure issues, including the core-cusp problem, the diversity problem for rotation curves, the missing satellites problem, and the too-big-to-fail problem, as well as recent progress in hydrodynamical simulations of galaxy formation; (2) N-body simulations for SIDM, including implications for density profiles, halo shapes, substructure, and the interplay between baryons and self-interactions; (3) semi-analytic Jeans-based methods that provide a complementary approach for connecting particle models with observations; (4) merging systems, such as cluster mergers (e.g., the Bullet Cluster) and minor infalls, along with recent simulation results for mergers; (5) particle physics models, including light mediator models and composite DM models; and (6) complementary probes for SIDM, including indirect and direct detection experiments, particle collider searches, and cosmological observations. We provide a summary and critical look for all current constraints on DM self-interactions and an outline for future directions.
Sub-nm 3D observation of human hair melanin by high-voltage STEM.
Imai, Takehito; Higuchi, Kimitaka; Yamamoto, Yuta; Arai, Shigeo; Nakano, Takashi; Tanaka, Nobuo
2016-04-01
The ultrastructure of melanin granules in human hair was studied using 1,000 kV high-voltage scanning transmission electron microscopy to successfully reconstruct three-dimensional images of the whole melanin granule. It was revealed that the melanin granule was composed of a membrane-like outer structure that included many spherical vesicles, and an inner matrix containing a sheet-like structure in the elongated direction of the melanin granule and a sheet-like arrays structure in the cross direction. The outer structure of the melanin granule was maintained even after exposure to hair-bleaching agents to decompose the melanin granule, suggesting that the outer structure was a highly robust structure and composition compared with the inner matrix . © The Author 2015. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.
NASA Astrophysics Data System (ADS)
Snyder, J. E.; Harris, V. G.; Koon, N. C.; Sui, X.; Kryder, M. H.
1996-10-01
Anisotropic local structure has been observed around both the Fe and Ba ions in the amorphous precursor to Ba-hexaferrite thin films, using polarization-dependent extended x-ray-absorption fine structure. This anisotropic local structure, consisting mainly of a network of Fe-O octahedra, determines the orientation of the fast-growing basal planes during crystallization, and thus the directions of the c axes and the resulting magnetic anisotropy.
Komatsu, Misako; Namikawa, Jun; Chao, Zenas C; Nagasaka, Yasuo; Fujii, Naotaka; Nakamura, Kiyohiko; Tani, Jun
2014-01-01
Many previous studies have proposed methods for quantifying neuronal interactions. However, these methods evaluated the interactions between recorded signals in an isolated network. In this study, we present a novel approach for estimating interactions between observed neuronal signals by theorizing that those signals are observed from only a part of the network that also includes unobserved structures. We propose a variant of the recurrent network model that consists of both observable and unobservable units. The observable units represent recorded neuronal activity, and the unobservable units are introduced to represent activity from unobserved structures in the network. The network structures are characterized by connective weights, i.e., the interaction intensities between individual units, which are estimated from recorded signals. We applied this model to multi-channel brain signals recorded from monkeys, and obtained robust network structures with physiological relevance. Furthermore, the network exhibited common features that portrayed cortical dynamics as inversely correlated interactions between excitatory and inhibitory populations of neurons, which are consistent with the previous view of cortical local circuits. Our results suggest that the novel concept of incorporating an unobserved structure into network estimations has theoretical advantages and could provide insights into brain dynamics beyond what can be directly observed. Copyright © 2014 Elsevier Ireland Ltd and the Japan Neuroscience Society. All rights reserved.
Narrow titanium oxide nanowires induced by femtosecond laser pulses on a titanium surface
NASA Astrophysics Data System (ADS)
Li, Hui; Li, Xian-Feng; Zhang, Cheng-Yun; Tie, Shao-Long; Lan, Sheng
2017-02-01
The evolution of the nanostructure induced on a titanium (Ti) surface with increasing irradiation pulse number by using a 400-nm femtosecond laser was examined by using scanning electron microscopy. High spatial frequency periodic structures of TiO2 parallel to the laser polarization were initially observed because of the laser-induced oxidation of the Ti surface and the larger efficacy factor of TiO2 in this direction. Periodically aligned TiO2 nanowires with featured width as small as 20 nm were obtained. With increasing pulse number, however, low spatial frequency periodic structures of Ti perpendicular to the laser polarization became dominant because Ti possesses a larger efficacy factor in this direction. The competition between the high- and low-spatial frequency periodic structures is in good agreement with the prediction of the efficacy factor theory and it should also be observed in the femtosecond laser ablation of other metals which are easily oxidized in air.
Observing the overall rocking motion of a protein in a crystal
NASA Astrophysics Data System (ADS)
Ma, Peixiang; Xue, Yi; Coquelle, Nicolas; Haller, Jens D.; Yuwen, Tairan; Ayala, Isabel; Mikhailovskii, Oleg; Willbold, Dieter; Colletier, Jacques-Philippe; Skrynnikov, Nikolai R.; Schanda, Paul
2015-10-01
The large majority of three-dimensional structures of biological macromolecules have been determined by X-ray diffraction of crystalline samples. High-resolution structure determination crucially depends on the homogeneity of the protein crystal. Overall `rocking' motion of molecules in the crystal is expected to influence diffraction quality, and such motion may therefore affect the process of solving crystal structures. Yet, so far overall molecular motion has not directly been observed in protein crystals, and the timescale of such dynamics remains unclear. Here we use solid-state NMR, X-ray diffraction methods and μs-long molecular dynamics simulations to directly characterize the rigid-body motion of a protein in different crystal forms. For ubiquitin crystals investigated in this study we determine the range of possible correlation times of rocking motion, 0.1-100 μs. The amplitude of rocking varies from one crystal form to another and is correlated with the resolution obtainable in X-ray diffraction experiments.
Studies by immune electron microscopy of hepatitis B surface antigen in PLC/PRF/5 cells.
Shibayama, T; Watanabe, T; Kojima, H; Yoshikawa, A; Watanabe, S; Kamimura, T; Suzuki, S; Ichida, F
1984-01-01
Electron microscopic studies of the morphology of hepatitis B surface antigen (HBsAg) produced by PLC/PRF/5 cells in vitro were carried out. Aggregates of 20-nm spherical particles in 3-day culture supernatants were observed by immune electron microscopy (IEM). Aggregates of tubular structures were found with IEM in the extracts of the cells. Tubular structures 18 to 22 nm in diameter were seen by electron microscopy (EM) in the cisternae of the endoplasmic reticulum in 2-3% of the cells. The tubular structures in the cytoplasm and extracts of PLC/PRF/5 cells resembled those observed in the hepatocytes of human carriers of hepatitis B virus (HBV). Intracellular localization of HBsAg in PLC/PRF/5 cells by direct peroxidase-conjugated antibody staining was observed on the tubular structures and the cisternal wall, which contained these structures. Rotation technique analysis indicated that the tubular structures were composed of 11 or 12 subunits.
In situ AFM imaging of apolipoprotein A-I directly derived from plasma HDL.
Gan, Chaoye; Wang, Zhexuan; Chen, Yong
2017-04-01
The major apolipoproteins of plasma lipoproteins play vital roles in the structural integrity and physiological functions of lipoproteins. More than ten structural models of apolipoprotein A-I (apoA-I), the major apolipoprotein of high-density lipoprotein (HDL), have been developed successively. In these models, apoA-I was supposed to organize in a ring-shaped form. To date, however, there is no direct evidence under physiological condition. Here, atomic force microscopy (AFM) was used to in situ visualize the organization of apoA-I, which was exposed via depletion of the lipid component of plasma HDL pre-immobilized on functionalized mica sheets. For the first time, the ring-shaped coarse structure and three detailed structures (crescent-shaped, gapped "O"-shaped, and parentheses-shaped structures, respectively) of apoA-I in plasma HDL, which have the ability of binding scavenger receptors, were directly observed and quantitatively measured by AFM. The three detailed structures probably represent the different extents to which the lipid component of HDL was depleted. Data on lipid depletion of HDL may provide clues to understand lipid insertion of HDL. These data provide important information for the understanding of the structure/maturation of plasma HDL. Moreover, they suggest a powerful method for directly visualizing the major apolipoproteins of plasma lipoproteins or the protein component of lipoprotein-like lipid-protein complexes. Copyright © 2017 Elsevier B.V. All rights reserved.
Parent-Child Mathematical Interactions: Examining Self-Report and Direct Observation
ERIC Educational Resources Information Center
Missall, Kristen N.; Hojnoski, Robin L.; Moreano, Ginna
2017-01-01
Variability in children's early-learning home environments points to the need to better understand specific mechanisms of early mathematical development. We used a sample of 66 parent-preschool child dyads to describe parent-reported mathematical activities in the home and observed parent-child mathematical activities in a semi-structured play…
Exploring small bodies in the outer solar system with stellar occultations
NASA Technical Reports Server (NTRS)
Elliot, Jim L.; Dunham, Edward W.; Olkin, C. B.
1995-01-01
Stellar occultation observations probe the atmospheric structure and extinction of outer solar system bodies with a spatial resolution of a few kilometers, and an airborne platform allows the observation of occultations by small bodies that are not visible from fixed telescopes. Results from occultations by Triton, Pluto, and Chiron observed with KAO are discussed, and future directions for this program are presented.
Magnetic discontinuities in magnetohydrodynamic turbulence and in the solar wind.
Zhdankin, Vladimir; Boldyrev, Stanislav; Mason, Joanne; Perez, Jean Carlos
2012-04-27
Recent measurements of solar wind turbulence report the presence of intermittent, exponentially distributed angular discontinuities in the magnetic field. In this Letter, we study whether such discontinuities can be produced by magnetohydrodynamic (MHD) turbulence. We detect the discontinuities by measuring the fluctuations of the magnetic field direction, Δθ, across fixed spatial increments Δx in direct numerical simulations of MHD turbulence with an imposed uniform guide field B(0). A large region of the probability density function (pdf) for Δθ is found to follow an exponential decay, proportional to exp(-Δθ/θ(*)), with characteristic angle θ(*)≈(14°)(b(rms)/B(0))(0.65) for a broad range of guide-field strengths. We find that discontinuities observed in the solar wind can be reproduced by MHD turbulence with reasonable ratios of b(rms)/B(0). We also observe an excess of small angular discontinuities when Δx becomes small, possibly indicating an increasing statistical significance of dissipation-scale structures. The structure of the pdf in this case closely resembles the two-population pdf seen in the solar wind. We thus propose that strong discontinuities are associated with inertial-range MHD turbulence, while weak discontinuities emerge from dissipation-range turbulence. In addition, we find that the structure functions of the magnetic field direction exhibit anomalous scaling exponents, which indicates the existence of intermittent structures.
A single spacecraft method to study the spatial profiles inside the magnetopause
NASA Astrophysics Data System (ADS)
Dorville, Nicolas; Belmont, Gerard; Rezeau, Laurence; Aunai, Nicolas; Retino, Alessandro
2013-04-01
Previous magnetopause observations have revealed that the tangential magnetic field often rotates over C-shaped hodograms during the boundary crossing. Using observations of magnetopause crossings by the ESA Cluster mission and a simulation developed at LPP by Nicolas Aunai, we developed a single spacecraft method using the temporal information on the magnetic field in such crossings, complemented by the ion data. We can so obtain a 1D spatial parameter to characterize the depth in the layer and study the structure of the magnetopause as a function of this parameter. This allows using one single spacecraft magnetic data, completed by ion data at large temporal scales, to study the spatial structure of the boundary, and access scales that the particle temporal measurements of the four spacecraft do not permit. To obtain the normal direction and position, we first initialize our computations thanks to the standard MVABC method. Then we use the magnetic field data in the current layer, and suppose it is 1D, rotating in the tangential plane along an ellipse, with an angle variation essentially linear in space, with small sinusoidal perturbations. Making the assumption that the normal velocity of ions is dominated by the motion of the boundary and that the internal structure of the magnetopause is stationary over the duration of a crossing, we can compute the best normal direction and parameters of the model with CIS velocity and FGM magnetic field data, and so derive the spatial position of the spacecraft in the boundary. This method, which has been tested on the simulation data, could be applied successfully on several magnetopause crossings observed by Cluster. It directly gives a thickness and a normal direction, and permits to establish spatial profiles of all the physical quantities inside the boundary. It can be used to better understand the internal structure of the boundary, its physical properties and behavior regarding the flux conservation equations. The obtained results are compared with the results of other methods.
Romanowicz, Barbara; Cao, Aimin; Godwal, Budhiram; ...
2016-01-06
Using an updated data set of ballistic PKIKP travel time data at antipodal distances, we test different models of anisotropy in the Earth's innermost inner core (IMIC) and obtain significantly better fits for a fast axis aligned with Earth's rotation axis, rather than a quasi-equatorial direction, as proposed recently. Reviewing recent results on the single crystal structure and elasticity of iron at core conditions, we find that an hcp structure with the fast c axis parallel to Earth's rotation is more likely but a body-centered cubic structure with the [111] axis aligned in that direction results in very similar predictionsmore » for seismic anisotropy. These models are therefore not distinguishable based on current seismological data. In addition, to match the seismological observations, the inferred strength of anisotropy in the IMIC (6–7%) implies almost perfect alignment of iron crystals, an intriguing, albeit unlikely situation, especially in the presence of heterogeneity, which calls for further studies. Fast axis of anisotropy in the central part of the inner core aligned with Earth's axis of rotation Lastly, the structure of iron in the inner core is most likely hcp, not bcc Not currently possible to distinguish between hcp and bcc structures from seismic observations« less
AFM Structural Characterization of Drinking Water Biofilm ...
Due to the complexity of mixed culture drinking water biofilm, direct visual observation under in situ conditions has been challenging. In this study, atomic force microscopy (AFM) revealed the three dimensional morphology and arrangement of drinking water relevant biofilm in air and aqueous solution. Operating parameters were optimized to improve imaging of structural details for a mature biofilm in liquid. By using a soft cantilever (0.03 N/m) and slow scan rate (0.5 Hz), biofilm and individual bacterial cell’s structural topography were resolved and continuously imaged in liquid without loss of spatial resolution or sample damage. The developed methodology will allow future in situ investigations to temporally monitor mixed culture drinking water biofilm structural changes during disinfection treatments. Due to the complexity of mixed culture drinking water biofilm, direct visual observation under in situ conditions has been challenging. In this study, atomic force microscopy (AFM) revealed the three dimensional morphology and arrangement of drinking water relevant biofilm in air and aqueous solution. Operating parameters were optimized to improve imaging of structural details for a mature biofilm in liquid. By using a soft cantilever (0.03 N/m) and slow scan rate (0.5 Hz), biofilm and individual bacterial cell’s structural topography were resolved and continuously imaged in liquid without loss of spatial resolution or sample damage. The developed methodo
Structural transition and enhanced phase transition properties of Se doped Ge2Sb2Te5 alloys
NASA Astrophysics Data System (ADS)
Vinod, E. M.; Ramesh, K.; Sangunni, K. S.
2015-01-01
Amorphous Ge2Sb2Te5 (GST) alloy, upon heating crystallize to a metastable NaCl structure around 150°C and then to a stable hexagonal structure at high temperatures (>=250°C). It has been generally understood that the phase change takes place between amorphous and the metastable NaCl structure and not between the amorphous and the stable hexagonal phase. In the present work, it is observed that the thermally evaporated (GST)1-xSex thin films (0 <= x <= 0.50) crystallize directly to the stable hexagonal structure for x >= 0.10, when annealed at temperatures >= 150°C. The intermediate NaCl structure has been observed only for x < 0.10. Chemically ordered network of GST is largely modified for x >= 0.10. Resistance, thermal stability and threshold voltage of the films are found to increase with the increase of Se. The contrast in electrical resistivity between the amorphous and crystalline phases is about 6 orders of magnitude. The increase in Se shifts the absorption edge to lower wavelength and the band gap widens from 0.63 to 1.05 eV. Higher resistance ratio, higher crystallization temperature, direct transition to the stable phase indicate that (GST)1-xSex films are better candidates for phase change memory applications.
The ambient stress field in the continental margin around the Korean Peninsula and Japanese islands
NASA Astrophysics Data System (ADS)
Lee, J.; Hong, T. K.; Chang, C.
2016-12-01
The ambient stress field is mainly influenced by regional tectonics. The stress field composition is crucial information for seismic hazard assessment. The Korean Peninsula, Japanese Islands and East Sea comprise the eastern margin of the Eurasian plate. The regions are surrounded by the Okhotsk, Pacific, and Philippine Sea plates. We investigate the regional stress field around the Korean Peninsula and Japanese islands using the focal mechanism solutions of regional earthquakes. Complex lateral and vertical variations of regional crustal stress fields are observed around a continental margin. The dominant compression directions are ENE-WSW around the Korean Peninsula and eastern China, E-W in the central East Sea and northern and southern Japan, NW-SE in the central Japan, and N-S around the northern Nankai trough. The horizontal compression directions are observed to be different by fault type, suggesting structure-dependent stress field distortion. The regional stress field change by depth and location, suggesting that the compression and tension stress may alternate in local region. The stress field and structures affect mutually, causing stress field distortion and reactivation of paleo-structures. These observation may be useful for understanding of local stress-field perturbation for seismic hazard mitigation of the region.
Park, Hyun Soon; Yu, Xiuzhen; Aizawa, Shinji; Tanigaki, Toshiaki; Akashi, Tetsuya; Takahashi, Yoshio; Matsuda, Tsuyoshi; Kanazawa, Naoya; Onose, Yoshinori; Shindo, Daisuke; Tonomura, Akira; Tokura, Yoshinori
2014-05-01
Skyrmions are nanoscale spin textures that are viewed as promising candidates as information carriers in future spintronic devices. Skyrmions have been observed using neutron scattering and microscopy techniques. Real-space imaging using electrons is a straightforward way to interpret spin configurations by detecting the phase shifts due to electromagnetic fields. Here, we report the first observation by electron holography of the magnetic flux and the three-dimensional spin configuration of a skyrmion lattice in Fe(0.5)Co(0.5)Si thin samples. The magnetic flux inside and outside a skyrmion was directly visualized and the handedness of the magnetic flux flow was found to be dependent on the direction of the applied magnetic field. The electron phase shifts φ in the helical and skyrmion phases were determined using samples with a stepped thickness t (from 55 nm to 510 nm), revealing a linear relationship (φ = 0.00173 t). The phase measurements were used to estimate the three-dimensional structures of both the helical and skyrmion phases, demonstrating that electron holography is a useful tool for studying complex magnetic structures and for three-dimensional, real-space mapping of magnetic fields.
NASA Astrophysics Data System (ADS)
Kang, Ming; Zhu, Weiren; Rukhlenko, Ivan D.
2017-12-01
The exceptional point (EP), which is one of the most important branch-type singularities exclusive to non-Hermitian systems, has been observed recently in various synthetic materials, giving rise to counterintuitive phenomena due to the nontrivial topology of the EP. Here, we present a direct experimental observation of the topological structure of the EPs via the angle-resolved transmission measurement of a hybridized metamaterial. Both eigenvalues and eigenvectors show branch-point singularities in the investigated biparametric space of frequency and incident angle. Importantly, the angle-resolved transmission coefficients provide all the information about the eigenvalues as well as the corresponding eigenvectors in the biparametric space, revealing the nontrivial topological structure of the EP, such as mode switching and the topological phase for a parameter loop encircling the EP. It is shown that the appearance of the EP in the scattering matrix is related directly to the perfect unidirectional transmission and the chirality of the EP corresponds to the maximum or minimum value of the asymmetric factor. Our investigation uncovers the capabilities of metamaterials for exploring the physics of EPs and their potential for having extreme optical properties, which provide potential applications in the spectral band ranging from microwaves to visible frequencies.
Robertson, Ann R R; Fernando, Bernard; Morrison, Zoe; Kalra, Dipak; Sheikh, Aziz
2015-03-27
Globally, diabetes mellitus presents a substantial and increasing burden to individuals, health care systems and society. Structuring and coding of information in the electronic health record underpin attempts to improve sharing and searching for information. Digital records for those with long-term conditions are expected to bring direct and secondary uses benefits, and potentially to support patient self-management. We sought to investigate if how and why records for adults with diabetes were structured and coded and to explore a range of UK stakeholders' perceptions of current practice in the National Health Service. We carried out a qualitative, theoretically informed case study of documenting health care information for diabetes in family practice and hospital settings in England, using semi-structured interviews, observations, systems demonstrations and documentary data. We conducted 22 interviews and four on-site observations. With respect to secondary uses - research, audit, public health and service planning - interviewees clearly articulated the benefits of highly structured and coded diabetes data and it was believed that benefits would expand through linkage to other datasets. Direct, more marginal, clinical benefits in terms of managing and monitoring diabetes and perhaps encouraging patient self-management were also reported. We observed marked differences in levels of record structuring and/or coding between family practices, where it was high, and the hospital. We found little evidence that structured and coded data were being exploited to improve information sharing between care settings. Using high levels of data structuring and coding in records for diabetes patients has the potential to be exploited more fully, and lessons might be learned from successful developments elsewhere in the UK. A first step would be for hospitals to attain levels of health information technology infrastructure and systems use commensurate with family practices.
NASA Astrophysics Data System (ADS)
Li, Kunkun; Yuan, Duanduan; Guo, Jiangang; Chen, Xiaolong
2018-04-01
We report the structure, antiferromagnetism, and superconductivity in C u1 -xL ixFeAs (0 ≤x ≤1.0 ) samples. A direct evolution from antiferromagnetism to superconductivity is observed as increasing doping level of Li. A phase diagram is constructed to show this evolution, which features no coexistence region between superconductivity and antiferromagnetism. This behavior shows that antiferromagnetic CuFeAs can be regarded as a parent compound to the observed superconductivity by equivalent doping, which is different from the cases with other FeAs-based superconductors. Structural analyses and first-principles calculations indicate that the anion height of F e2A s2 tetrahedral layer plays a crucial role on the physical properties. Moreover, the simple Fermi surface nesting picture adopted to explain the evolution from spin-density wave to superconductor in other FeAs-based superconductors might be not applicable to C u1 -xL ixFeAs .
Direct Investigation of Slow Correlated Dynamics in Proteins via Dipolar Interactions
Fenwick, R. Bryn; Schwieters, Charles D.; Vögeli, Beat
2016-01-01
The synchronization of native state motions as they transition between microstates influences catalysis kinetics, mediates allosteric interactions and reduces the conformational entropy of proteins. However, it has proven difficult to describe native microstates because they are usually minimally frustrated and may interconvert on the μs-ms time scale. Direct observation of concerted equilibrium fluctuations would therefore be an important tool for describing protein native states. Here we propose a strategy that relates NMR cross-correlated relaxation (CCR) rates between dipolar interactions to residual dipolar couplings (RDCs) of individual consecutive HN–N and Hα–Cα bonds, which act as a proxy for the peptide planes and the side chains respectively. Using Xplor-NIH ensemble structure calculations restrained with the RDC and CCR data we observe collective motions on time scales slower than nanoseconds in the backbone for GB3. To directly access the correlations from CCR we develop a structure-free data analysis. The resulting dynamic correlation map is consistent with the ensemble-restrained simulations and reveals a complex network. In general we find that the bond motions are on average slightly correlated, and that the local environment dominates many observations. Despite this, some patterns are typical over entire secondary structure elements. In the β-sheet, nearly all bonds are weakly correlated and there is an approximately binary alternation in correlation intensity corresponding to the solvent exposure/shielding alternation of the side chains. For α-helices there is also a weak correlation in the HN-N bonds and the degree of correlation involving Hα-Cα bonds is directly affected by side-chain fluctuations, while loops show complex and non-uniform behavior. PMID:27331619
Variation of directional reflectance factors with structural changes of a developing alfalfa canopy
NASA Technical Reports Server (NTRS)
Kirchner, J. A.; Kimes, D. S.; Mcmurtrey, J. E., III
1982-01-01
Directional reflectance factors of an alfalfa canopy were determined and related to canopy structure, agronomic variables, and irradiance conditions at four periods during a cutting cycle. Nadir and off-nadir reflectance factors decreased with increasing biomass in Thematic Mapper band 3(0.63-0.69 micrometer) and increased with increasing biomass in band 4(0.76-0.90 micrometer). The sensor view angle had less impact on perceived reflectance as the alfalfa progressed from an erectophile canopy of stems after harvest to a near planophile canopy of leaves at maturity. Studies of directional reflectance are needed for testing and upgrading vegetation canopy models and to aid in the complex interpretation problems presented by aircraft scanners and pointable satellites where illumination and viewing geometries may vary widely. Distinct changes in the patterns of radiance observed by a sensor as structural and biomass changes occur are keys to monitoring the growth and condition of crops.
Liu, Lifeng; Ding, Xiangdong; Li, Ju; Lookman, Turab; Sun, Jun
2014-02-21
Martensitic transformation usually creates hierarchical internal structures beyond mere change of the atomic crystal structure. Multi-stage nucleation is thus required, where nucleation (level-1) of the underlying atomic crystal lattice does not have to be immediately followed by the nucleation of higher-order superstructures (level-2 and above), such as polysynthetic laths. Using in situ transmission electron microscopy (TEM), we directly observe the nucleation of the level-2 superstructure in a Cu-Al-Ni single crystal under compression, with critical super-nuclei size L2c around 500 nm. When the sample size D decreases below L2c, the superelasticity behavior changes from a flat stress plateau to a continuously rising stress-strain curve. Such size dependence definitely would impact the application of shape memory alloys in miniaturized MEMS/NEMS devices.
The phantom leaf effect: a replication, part 1.
Hubacher, John
2015-02-01
To replicate the phantom leaf effect and demonstrate a possible means to directly observe properties of the biological field. Thirty percent to 60% of plant leaves were amputated, and the remaining leaf sections were photographed with corona discharge imaging. All leaves were cut before placement on film. A total of 137 leaves were used. Plant leaves of 14 different species. Ninety-six phantom leaf specimens were successfully obtained; 41 specimens did not yield the phantom leaf effect. A normally undetected phantom "structure," possibly evidence of the biological field, can persist in the area of an amputated leaf section, and corona discharge can occur from this invisible structure. This protocol may suggest a testable method to study properties of conductivity and other parameters through direct observation of the complete biological field in plant leaves, with broad implications for biology and physics.
Structure of the bulge of the galaxy NGC 4258
NASA Astrophysics Data System (ADS)
Matveyenko, L. I.; Demichev, V. A.
2017-09-01
The superfine structure of the bulge of the galaxy NGC 4258 has been investigated in H2O maser emission at the epochs on February 4, 2013, and November 29, 2013. The peak intensities of the spectral components reached F ≈ 5 Jy. The emission of the component at v = 476 km s-1 dominated at the beginning of this period; the second component at v = 487 km s-1 was observed at the end of the period. The structure is a chain of compact components up to 200 µas or 7mpc in extent. The velocity of the local standard of rest is v LSR = 482 km s-1. Two bright compact components with a separation between them Δ ρ ≈ 35 µas or 1.3 mpc and a pair of components spaced 13 µas apart, whose brightness reaches 30% of the peak value corresponding to a brightness temperature T b ≈ 1018 K, are located at the center. The sizes of the components are 2-3 µas. A splitting and a shift of the two pairs of components relative to each other by 8 µas or 0.3 mpc in the 45° direction are observed at the end of the period. The velocity gradient of the structure is dV/dρ = 224 km s-1 mas-1, suggesting a solid-body rotation with a period T ≈ 760 years. The compact components correspond to the tangential directions of the arm. Two parallel chains of components corresponding to the tangential directions of the walls of the bipolar outflow carrying away an excess angular momentum are ejected from the central part of the bulge, two sources. The outflow is oriented at an angle X ≈ 15° relative to the disk axis. The brightness of the outflow fragments does not exceed 1.5% of the peak value. The ejection of material from the central part in the northward direction at a level up to 0.2%, T b ≈ 1015 K, is observed at the epoch on February 4, 2013, at v = 478 km s-1. The core structure suggests a double system: parallel disks-vortices spaced 0.25 mpc apart.
NASA Astrophysics Data System (ADS)
Malyar, Ivan V.; Gorin, Dmitry A.; Stetsyura, Svetlana V.
2013-01-01
In this report we present the analysis of I-V curves for MIS-structures like silicon substrate / nanodimensional polyelectrolyte layer / metal probe (contact) which is promising for biosensors, microfluidic chips, different devices of molecular electronics, such as OLEDs, solar cells, where polyelectrolyte layers can be used to modify semiconductor surface. The research is directed to investigate the contact phenomena which influence the resulting signal of devices mentioned above. The comparison of I-V characteristics of such structures measured by scanning tunnel microscopy (contactless technique) and using contact areas deposited by thermal evaporation onto the organic layer (the contact one) was carried out. The photoassisted I-V measurements and complex analysis based on Simmons and Schottky models allow one to extract the potential barriers and to observe the changes of charge transport in MIS-structures under illumination and after polyelectrolyte adsorption. The direct correlation between the thickness of the deposited polyelectrolyte layer and both equilibrium tunnel barrier and Schottky barrier height was observed for hybrid structures with polyethylenimine. The possibility of control over the I-V curves of hybrid structure and the height of the potential barriers (for different charge transports) by illumination was confirmed. Based on experimental data and complex analysis the band diagrams were plotted which illustrate the changes of potential barriers for MIS-structures due to the polyelectrolyte adsorption and under the illumination.
NASA Astrophysics Data System (ADS)
Nyawako, Donald; Reynolds, Paul; Hudson, Emma
2016-04-01
Feedback control strategies are desirable for disturbance rejection of human-induced vibrations in civil engineering structures as human walking forces cannot easily be measured. In relation to human-induced vibration control studies, most past researches have focused on floors and footbridges and the widely used linear controller implemented in the trials has been the direct velocity feedback (DVF) scheme. With appropriate compensation to enhance its robustness, it has been shown to be effective at damping out the problematic modes of vibration of the structures in which the active vibration control systems have been implemented. The work presented here introduces a disturbance observer (DOB) that is used with an outer-loop DVF controller. Results of analytical studies presented in this work based on the dynamic properties of a walkway bridge structure demonstrate the potential of this approach for enhancing the vibration mitigation performance offered by a purely DVF controller. For example, estimates of controlled frequency response functions indicate improved attenuation of vibration around the dominant frequency of the walkway bridge structure as well as at higher resonant frequencies. Controlled responses from three synthesized walking excitation forces on a walkway bridge structure model show that the inclusion of the disturbance observer with an outer loop DVF has potential to improve on the vibration mitigation performance by about 3.5% at resonance and 6-10% off-resonance. These are realised with hard constraints being imposed on the low frequency actuator displacements.
NASA Astrophysics Data System (ADS)
Rouillard, A. P.; Lavraud, B.; Génot, V.; Bouchemit, M.; Dufourg, N.; Plotnikov, I.; Pinto, R. F.; Sanchez-Diaz, E.; Lavarra, M.; Penou, M.; Jacquey, C.; André, N.; Caussarieu, S.; Toniutti, J.-P.; Popescu, D.; Buchlin, E.; Caminade, S.; Alingery, P.; Davies, J. A.; Odstrcil, D.; Mays, L.
2017-11-01
The remoteness of the Sun and the harsh conditions prevailing in the solar corona have so far limited the observational data used in the study of solar physics to remote-sensing observations taken either from the ground or from space. In contrast, the 'solar wind laboratory' is directly measured in situ by a fleet of spacecraft measuring the properties of the plasma and magnetic fields at specific points in space. Since 2007, the solar-terrestrial relations observatory (STEREO) has been providing images of the solar wind that flows between the solar corona and spacecraft making in-situ measurements. This has allowed scientists to directly connect processes imaged near the Sun with the subsequent effects measured in the solar wind. This new capability prompted the development of a series of tools and techniques to track heliospheric structures through space. This article presents one of these tools, a web-based interface called the 'Propagation Tool' that offers an integrated research environment to study the evolution of coronal and solar wind structures, such as Coronal Mass Ejections (CMEs), Corotating Interaction Regions (CIRs) and Solar Energetic Particles (SEPs). These structures can be propagated from the Sun outwards to or alternatively inwards from planets and spacecraft situated in the inner and outer heliosphere. In this paper, we present the global architecture of the tool, discuss some of the assumptions made to simulate the evolution of the structures and show how the tool connects to different databases.
Nano-structured wild moth cocoon fibers as radiative cooling and waveguiding optical materials
NASA Astrophysics Data System (ADS)
Shi, Norman Nan; Tsai, Cheng-Chia; Bernard, Gary D.; Craig, Catherine; Yu, Nanfang
2017-09-01
The study shows that comet moth cocoon fibers exhibit radiative cooing properties with enhanced solar reflectivity and thermal emissivity. Nanostructured voids inside the cocoon fiber enables the cocoons to exhibit strong scattering in the visible and near-infrared. These structures also allow the fibers to exhibit strong shape birefringence and directional reflectivity. Optical waveguiding due to transverse Anderson localization is observed in these natural fibers, where the invariance and large concentration of the voids in the longitudinal direction allow the fiber to confine light in the transverse direction. To mimic the optical effects generated by these natural silk fibers, nanostructured voids are introduced into regenerated silk fibers through wet spinning to enhance reflectivity in the solar spectrum.
A comparison of in situ and airborne radar observations of ocean wave directionality
NASA Technical Reports Server (NTRS)
Jackson, F. C.; Walton, W. T.; Peng, C. Y.
1985-01-01
The directional spectrum of a fully arisen, about 3 m sea as measured by an experimental airborne radar, the NASA K(u)-band radar ocean wave spectrometer (ROWS), is compared to reference pitch-roll buoy data and to the classical SWOP (stereo wave observations project) spectrum for fully developed conditions. The ROWS spectrum, inferred indirectly from backscattered power measurements at 5-km altitude, is shown to be in excellent agreement with the buoy spectrum. Specifically, excellent agreement is found between the two nondirectional height spectra, and mean wave directions and directional spreads as functions of frequency. A comparison of the ROWS and SWOP spectra shows the two spectra to be very similar, in detailed shape as well as in terms of the gross spreading characteristics. Both spectra are seen to exhibit bimodal structures which accord with the Phillips' (1958) resonance mechanism. This observation is thus seen to support Phillips' contention that the SWOP modes were indeed resonance modes, not statistical artifacts.
NASA Astrophysics Data System (ADS)
LaComb, Ronald; Nadiarnykh, Oleg; Townsend, Sallie S.; Campagnola, Paul J.
2008-04-01
We present a heuristic treatment which relates SHG image intensities, signal directionality, and observed morphology to the physical structure of collagen and cellulose fibrillar tissues. The SHG creation model is based upon relaxed phase matching conditions which account for dispersion, randomness, and axial momentum contributions from the media, and includes a mathematical treatment which relates SHG conversion efficiency to fibril diameter and packing through the inclusion of potential intensity amplification resultant from quasi-phase matching (QPM). A direct consequence of this theory is that SHG in biological tissues is not strictly a coherent process, and that the forward directed SHG has a longer coherence length than the backward component, Through this treatment, we show that the emission directionality and also conversion efficiency do not arise solely from the fibril size but also depend on packing density and order of the inter-fibril structure. We demonstrate these principles in comparing the SHG response in normal and Osteogenesis Imperfecta (OI) skin. We show that the observed directionality and decreased relative intensity in the diseased state is consistent with phase matching conditions arising from the decreased fibril size and more random assembly. We further use this theory to explain the differences in morphology seen in forward and backward collected SHG in fibrillar tissues (e.g., collagenous and cellulosic). Specifically, we attribute segmented appearance to destructive interference between small fibrils separated by less than the coherence length. We suggest the approach based on relaxed phasematching conditions is general in predicting the SHG response in tissues and may be broadly applicable in interpreting the SHG contrast for diagnostic applications.
Controllability and observability analysis for vertex domination centrality in directed networks
NASA Astrophysics Data System (ADS)
Wang, Bingbo; Gao, Lin; Gao, Yong; Deng, Yue; Wang, Yu
2014-06-01
Topological centrality is a significant measure for characterising the relative importance of a node in a complex network. For directed networks that model dynamic processes, however, it is of more practical importance to quantify a vertex's ability to dominate (control or observe) the state of other vertices. In this paper, based on the determination of controllable and observable subspaces under the global minimum-cost condition, we introduce a novel direction-specific index, domination centrality, to assess the intervention capabilities of vertices in a directed network. Statistical studies demonstrate that the domination centrality is, to a great extent, encoded by the underlying network's degree distribution and that most network positions through which one can intervene in a system are vertices with high domination centrality rather than network hubs. To analyse the interaction and functional dependence between vertices when they are used to dominate a network, we define the domination similarity and detect significant functional modules in glossary and metabolic networks through clustering analysis. The experimental results provide strong evidence that our indices are effective and practical in accurately depicting the structure of directed networks.
Controllability and observability analysis for vertex domination centrality in directed networks
Wang, Bingbo; Gao, Lin; Gao, Yong; Deng, Yue; Wang, Yu
2014-01-01
Topological centrality is a significant measure for characterising the relative importance of a node in a complex network. For directed networks that model dynamic processes, however, it is of more practical importance to quantify a vertex's ability to dominate (control or observe) the state of other vertices. In this paper, based on the determination of controllable and observable subspaces under the global minimum-cost condition, we introduce a novel direction-specific index, domination centrality, to assess the intervention capabilities of vertices in a directed network. Statistical studies demonstrate that the domination centrality is, to a great extent, encoded by the underlying network's degree distribution and that most network positions through which one can intervene in a system are vertices with high domination centrality rather than network hubs. To analyse the interaction and functional dependence between vertices when they are used to dominate a network, we define the domination similarity and detect significant functional modules in glossary and metabolic networks through clustering analysis. The experimental results provide strong evidence that our indices are effective and practical in accurately depicting the structure of directed networks. PMID:24954137
Distributions of experimental protein structures on coarse-grained free energy landscapes
Liu, Jie; Jernigan, Robert L.
2015-01-01
Predicting conformational changes of proteins is needed in order to fully comprehend functional mechanisms. With the large number of available structures in sets of related proteins, it is now possible to directly visualize the clusters of conformations and their conformational transitions through the use of principal component analysis. The most striking observation about the distributions of the structures along the principal components is their highly non-uniform distributions. In this work, we use principal component analysis of experimental structures of 50 diverse proteins to extract the most important directions of their motions, sample structures along these directions, and estimate their free energy landscapes by combining knowledge-based potentials and entropy computed from elastic network models. When these resulting motions are visualized upon their coarse-grained free energy landscapes, the basis for conformational pathways becomes readily apparent. Using three well-studied proteins, T4 lysozyme, serum albumin, and sarco-endoplasmic reticular Ca2+ adenosine triphosphatase (SERCA), as examples, we show that such free energy landscapes of conformational changes provide meaningful insights into the functional dynamics and suggest transition pathways between different conformational states. As a further example, we also show that Monte Carlo simulations on the coarse-grained landscape of HIV-1 protease can directly yield pathways for force-driven conformational changes. PMID:26723638
Mosher, Jennifer J; Findlay, Robert H
2011-11-01
A correlative study was performed to determine if variation in streambed microbial community structure in low-order forested streams can be directly or indirectly linked to the chemical nature of the parental bedrock of the environments through which the streams flow. Total microbial and photosynthetic biomass (phospholipid phosphate [PLP] and chlorophyll a), community structure (phospholipid fatty acid analysis), and physical and chemical parameters were measured in six streams, three located in sandstone and three in limestone regions of the Bankhead National Forest in northern Alabama. Although stream water flowing through the two different bedrock types differed significantly in chemical composition, there were no significant differences in total microbial and photosynthetic biomass in the sediments. In contrast, sedimentary microbial community structure differed between the bedrock types and was significantly correlated with stream water ion concentrations. A pattern of seasonal variation in microbial community structure was also observed. Further statistical analysis indicated dissolved organic matter (DOM) quality, which was previously shown to be influenced by geological variation, correlated with variation in bacterial community structure. These results indicate that the geology of underlying bedrock influences benthic microbial communities directly via changes in water chemistry and also indirectly via stream water DOM quality.
Formation mechanism of self-assembled polarization-dependent periodic nanostructures in β-Ga2O3
NASA Astrophysics Data System (ADS)
Nakanishi, Y.; Shimotsuma, Y.; Sakakura, M.; Shimizu, M.; Miura, K.
2018-02-01
We have successfully observed self-assembled periodic nanostructures inside Si single crystal and GaP crystal, by the femtosecond double-pulse irradiation. These results experimentally indicate that the self-assembly of the periodic nanostructures inside semiconductors triggered by ultrashort pulses irradiation are possibly associated with a direct or an indirect band gap. More recently we have also empirically classified the photoinduced bulk nanogratings into the following three types: (1) structural deficiency, (2) compressed structure, (3) partial crystallization. We have still a big question about what material properties are involved in the bulk nanograting structure formation. In this study, to expand the selectivity of the material for bulk nanograting formation, we have employed β-Ga2O3 crystals (indirect bandgap Eg 4.8 eV) as a sample for femtosecond laser irradiation. The nanograting structure inside β-Ga2O3 crystal was aligned perpendicular to the laser polarization direction. Such phenomenon is similar to the nanograting in SiO2 glass (Eg 9 eV). Moreover, to clarify the band structure, we have also investigate the photoinduced structure in Sn doped β-Ga2O3 crystals, which exhibit direct bandgap according to the first principle calculation.
Harrison, Xavier A; York, Jennifer E; Young, Andrew J
2014-12-01
Sex-biased dispersal is pervasive and has diverse evolutionary implications, but the fundamental drivers of dispersal sex biases remain unresolved. This is due in part to limited diversity within taxonomic groups in the direction of dispersal sex biases, which leaves hypothesis testing critically dependent upon identifying rare reversals of taxonomic norms. Here, we use a combination of observational and genetic data to demonstrate a rare reversal of the avian sex bias in dispersal in the cooperatively breeding white-browed sparrow weaver (Plocepasser mahali). Direct observations revealed that (i) natal philopatry was rare, with both sexes typically dispersing locally to breed, and (ii), unusually for birds, males bred at significantly greater distances from their natal group than females. Population genetic analyses confirmed these patterns, as (i) corrected Assignment index (AIc), FST tests and isolation-by-distance metrics were all indicative of longer dispersal distances among males than females, and (ii) spatial autocorrelation analysis indicated stronger within-group genetic structure among females than males. Examining the spatial scale of extra-group mating highlighted that the resulting 'sperm dispersal' could have acted in concert with individual dispersal to generate these genetic patterns, but gamete dispersal alone cannot account entirely for the sex differences in genetic structure observed. That leading hypotheses for the evolution of dispersal sex biases cannot readily account for these sex-reversed patterns of dispersal in white-browed sparrow weavers highlights the continued need for attention to alternative explanations for this enigmatic phenomenon. We highlight the potential importance of sex differences in the distances over which dispersal opportunities can be detected. © 2014 The Authors. Molecular Ecology Published by John Wiley & Sons Ltd.
Theoretical prediction and direct observation of the 9R structure in Ag
NASA Astrophysics Data System (ADS)
Ernst, F.; Finnis, M. W.; Hofmann, D.; Muschik, T.; Schönberger, U.; Wolf, U.; Methfessel, M.
1992-07-01
Molecular-dynamics simulations of the Σ3<110>(211) twin boundary in Ag predict a thin (1 nm) boundary phase of the 9R (α-Sm) structure. High-resolution electron microscopy shows the presence of the predicted structure. We also calculate the energy ab initio for several hypothetical structures of Cu and Ag. Low energies of the 9R structure and other polytypes, low experimental stacking-fault energies, and the hcp-fcc energy difference are correlated and explained in terms of an effective nearest-neighbor Ising interaction.
NASA Astrophysics Data System (ADS)
Yasuda, K.; Tadokoro, K.; Ikuta, R.; Watanabe, T.; Nagai, S.; Sayanagi, K.
2013-12-01
Observation of seafloor crustal deformation is crucial for megathrust earthquake because most of the focal areas are located below seafloor. Seafloor crustal deformation can be observed GPS/Acoustic technique, and this technique has been carried out at subduction margins in Japan, e.g., Japan Trench, Suruga Trough, and Nankai Trough. At the present, the accuracy of seafloor positioning is one to several centimeters for each epoch. Velocity vectors at seafloor site are estimated through repeated observations. Co- and post- seismic slip distribution and interseismic deformation are estimated from results of seafloor geodetic measurement (e.g., Iinuma et al., 2012; Tadokoro et al., 2012). We repeatedly observed seafloor crustal deformations at two sites across the Suruga Trough from 2005 to investigate interplate locking condition at the focal area of the anticipated megathrust, Tokai, earthquake. We observed 12 and 16 times at an east site of the Suruga Trough (SNE) and at an west site of the Suruga Trough (SNW), respectively. We reinstalled seafloor benchmarks at both sites because of run out of batteries in 2012. We calculated and removed the bias between the old and new seafloor benchmarks. Furthermore, we evaluated two type of analysis. One is Fixed triangular configuration Analysis (FTA). When we determine the seafloor benchmark position, we fix the triangular configuration of seafloor units averaging all the measurements to improve trade-off relation between seafloor benchmark position and sound speed structure. Sound speed structure is assumed to be horizontal layered structure. The other one is Fixed Triangle and Gradient structure of sound speed structure (FTGA). We fixed triangular configuration same as FTA. Sound speed structure is assumed to have gradient structure. Comparing FTA with FTGA, the RMS of horizontal position analyzed through FTA is smaller than that through FTGA at SNE site. On the other hand, the RMS of horizontal position analyzed through FTA is larger than that through FTGA at SNW site. We estimated the displacement velocities with relative to the Amurian plate from the result of repeated observation. The estimated displacement velocity vectors at SNE and SNW are 42×8 mm/y to N94W direction and 46×13 mm/y to N77W direction, respectively. The directions are the same as those measured at the on-land GPS stations. The magnitudes of velocity vector indicate significant shortening by approximately 11 mm/y between SNW and on-land GPS stations at the western part of the Suruga Trough. We also calculated the theoretical surface deformation pattern to depict the interplate locking condition. These results show that the plate interface at the shallow zone of the northernmost Suruga trough is strongly locked.
Working Group on Ice Forces on Structures. A State-of-the-Art Report.
1980-06-01
observed in Soviet Design Codes, but the randomness of ice properties is not directly observed anywhere. 3.3 Contact system The mode of ice failure against...ups .............. o..........................90 2.133 Factors limiting ice ride-up ..................... o............91 2.134 Procedures for designing ...o................................110 3.3 Contact system .................................................. 115 3.4 Damping
González-Chávez, Ma Del Carmen A; Torres-Cruz, Terry J; Sánchez, Samantha Albarrán; Carrillo-González, Rogelio; Carrillo-López, Luis Manuel; Porras-Alfaro, Andrea
2018-02-01
Vanilla is an orchid of economic importance widely cultivated in tropical regions and native to Mexico. We sampled three species of Vanilla (V. planifolia, V. pompona, and V. insignis) in different crop systems. We studied the effect of crop system on the abundance, type of fungi, and quality of pelotons found in the roots using light and electron microscopy and direct sequencing of mycorrhizal structures. Fungi were identified directly from pelotons obtained from terrestrial roots of vanilla plants in the flowering stage. Root samples were collected from plants in crop systems located in the Totonacapan area in Mexico (states of Puebla and Veracruz). DNA was extracted directly from 40 pelotons and amplified using ITS rRNA sequencing. Peloton-like structures were observed, presenting a combination of active pelotons characterized by abundant hyphal coils and pelotons in various stages of degradation. The most active pelotons were observed in crop systems throughout living tutors (host tree) in comparison with roots collected from dead or artificial tutors. Fungi identified directly from pelotons included Scleroderma areolatum, a common ectomycorrhizal fungus that has not been reported as a mycorrhizal symbiont in orchids. Direct amplification of pelotons also yielded common plant pathogens, including Fusarium and Pyrenophora seminiperda, especially in those sites with low colonization rates, and where large numbers of degraded pelotons were observed. This research reports for the first time the potential colonization of Vanilla by Scleroderma, as a putative orchid mycorrhizal symbiont in four sites in Mexico and the influence of crop system on mycorrhizal colonization on this orchid.
Novel use of residue from direct coal liquefaction process
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jianli Yang; Zhaixia Wang; Zhenyu Liu
2009-09-15
Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modification ability is similar to that of Trinidad Lake Asphalt (TLA), a superior commercial modifier. Asphalts modified by two DCLRs meet the specifications of ASTM D5710 and BSI BS-3690 designated for the TLA-modified asphalts. The required addition amount for the DCLRs tested is less than thatmore » for TLA due possibly to the high content of asphaltene in DCLRs. Different compatibility was observed for the asphalts with the same penetration grade but from the different origin. Different components in the DCLR play different roles in the modification. Positive synergetic effects among the fractions were observed, which may due to the formation of the stable colloid structure. Unlike polymer-type modifier, the structure of asphalt-type modifier has a similarity with petroleum asphalts which favors the formation of a stable dispersed polar fluid (DPF) colloid structure and improves the performance of pavement asphalt. 12 refs., 1 fig., 6 tabs.« less
System/observer/controller identification toolbox
NASA Technical Reports Server (NTRS)
Juang, Jer-Nan; Horta, Lucas G.; Phan, Minh
1992-01-01
System Identification is the process of constructing a mathematical model from input and output data for a system under testing, and characterizing the system uncertainties and measurement noises. The mathematical model structure can take various forms depending upon the intended use. The SYSTEM/OBSERVER/CONTROLLER IDENTIFICATION TOOLBOX (SOCIT) is a collection of functions, written in MATLAB language and expressed in M-files, that implements a variety of modern system identification techniques. For an open loop system, the central features of the SOCIT are functions for identification of a system model and its corresponding forward and backward observers directly from input and output data. The system and observers are represented by a discrete model. The identified model and observers may be used for controller design of linear systems as well as identification of modal parameters such as dampings, frequencies, and mode shapes. For a closed-loop system, an observer and its corresponding controller gain directly from input and output data.
NASA Astrophysics Data System (ADS)
Stamopoulos, D.; Grapsa, E.; Manios, E.; Gogola, V.; Bakirtzi, N.
2012-12-01
Together with impaired production of erythropoietin and iron deficiency, the decreased lifespan of red blood cells (RBCs) is a main factor contributing to the chronic anaemia observed in haemodialysis (HD) patients. Atomic force microscopy is employed in this work to thoroughly survey the membrane of intact RBCs (iRBCs) of HD patients in comparison to those of healthy donors, aiming to obtain direct information on the structural status of RBCs that can be related to their decreased lifespan. We observed that the iRBC membrane of the HD patients is overpopulated with extended circular defects, termed ‘orifices’, that have typical dimension ranging between 0.2 and 1.0 μm. The ‘orifice’ index—that is, the mean population of ‘orifices’ per top membrane surface—exhibits a pronounced relative increase of order 54 ± 12% for the HD patients as compared to healthy donors. Interestingly, for the HD patients, the ‘orifice’ index, which relates to the structural status of the RBC membrane, correlates strongly with urea concentration, which is a basic index of the uraemic milieu. Thus, these results indicate that the uraemic milieu downgrades the structural status of the RBC membrane, possibly triggering biochemical processes that result in their premature elimination from the circulation. This process could decrease the lifespan of RBCs, as observed in HD patients.
Enhanced Emission of Quantum System in Si-Ge Nanolayer Structure.
Huang, Zhong-Mei; Huang, Wei-Qi; Dong, Tai-Ge; Wang, Gang; Wu, Xue-Ke
2016-12-01
It is very interesting that the enhanced peaks near 1150 and 1550 nm are observed in the photoluminescence (PL) spectra in the quantum system of Si-Ge nanolayer structure, which have the emission characteristics of a three-level system with quantum dots (QDs) pumping and emission of quasi-direct-gap band, in our experiment. In the preparing process of Si-Ge nanolayer structure by using a pulsed laser deposition method, it is discovered that the nanocrystals of Si and Ge grow in the (100) and (111) directions after annealing or electron beam irradiation. The enhanced PL peaks with multi-longitudinal-mode are measured at room temperature in the super-lattice of Si-Ge nanolayer quantum system on SOI.
Negative index effects from a homogeneous positive index prism
NASA Astrophysics Data System (ADS)
Marcus, Sherman W.; Epstein, Ariel
2017-12-01
Cellular structured negative index metamaterials in the form of a right triangular prism have often been tested by observing the refraction of a beam across the prism hypotenuse which is serrated in order to conform to the cell walls. We show that not only can this negative index effect be obtained from a homogeneous dielectric prism having a positive index of refraction, but in addition, for sampling at the walls of the cellular structure, the phase in the material has the illusory appearance of moving in a negative direction. Although many previous reports relied on refraction direction and phase velocity of prism structures to verify negative index design, our investigation indicates that to unambiguously demonstrate material negativity additional empirical evidence is required.
Convection flow structure in the central polar cap
NASA Astrophysics Data System (ADS)
Bristow, W. A.
2017-12-01
A previous study of spatially averaged flow velocity in the central polar cap [Bristow et al., 2015] observed under steady IMF conditions found that it was extremely rare for the average to exceed 850 m/s (less than 0.2 % of the time). Anecdotally, however it is not uncommon to observe line-of-sight velocities in excess of 100 m/s in the McMurdo radar field of view directly over the magnetic pole. This discrepancy motivated this study, which examines the conditions under which high-velocity flows are observed at latitudes greater than 80° magnetic latitude. It was found that highly structured flows are common in the central polar cap, which leads to the flow within regions to have significant deviation from the average. In addition, the high-speed flow regions are usually directed away from the earth-sun line. No specific set of driving conditions was identified to be associated with high-speed flows. The study did conclude that 1)Polar cap velocities are generally highly structured. 2)Flow patterns typically illustrate narrow channels, vortical flow regions, and propagating features. 3) Persistent waves are a regular occurrence. 3)Features are observed to propagate from day side to night side, and from night side to day side.. 4)Convection often exhibits significant difference between the two hemispheres. And 5)About 10% of the time the velocity somewhere in the cap exceeds 1 Km/s The presentation will conclude with a discussion of the physical reasons for the flow structure. Bristow, W. A., E. Amata, J. Spaleta, and M. F. Marcucci (2015), Observations of the relationship between ionospheric central polar cap and dayside throat convection velocities, and solar wind/IMF driving, J. Geophys. Res. Space Physics, 120, doi:10.1002/2015JA021199.
NASA Astrophysics Data System (ADS)
Ni, C. H.; Chen, Y. H.
2016-12-01
The pseudotachylyte generated from the fault sliding during an earthquake plays an important role in the geology. In general, the pseudotachylyte vein has a magnetic susceptibility which is higher than wall rocks attributed by the fine-grained magnetic minerals. In this study, the fault pseudotachylyte formed by frictional melting in quartzofeldspathic schist rocks from Alpine Fault, New Zealand, was investigated. The scanning electron microscopy (SEM) was used to obtain the morphology of magnetic minerals and magnetic force microscopy (MFM) was utilized to observe magnetic domain structures. We want to realize how the growth process of magnetic minerals affects magnetic structures and magnetic properties. It was observed exsoluted-titanomagnetite was especially around outer edge of pseudotachylyte. These titanomagnetite had a single domain (SD) and distributed paralleling to the direction of exsolution. In contrast, the magnetic minerals (magnetite) in the pseudotachylyte vein had two different magnetic structures: one is the detrital magnetite showed multiple domains (MD) without regular arrangement, which may be indicated the thermal remanent magnetization (TRM). One the other is neoformed fine-grained magnetite scattering in the matrix and showed SD to pseudo-single-domain (PSD) and their magnetic direction was perpendicular to the direction of pseudotachylyte veins, suggesting the chemical remanent magnetization (CRM). However, the macroscopic magnetic property, based on Day's plot, measured from superconducting quantum interference device (SQUID) was shown the sample belonged to MD structures. These results indicated that MFM is a more powerful and precise tool to figure out the magnetic structure. The related studies will be further investigated.
Future mission studies: Forecasting solar flux directly from its chaotic time series
NASA Technical Reports Server (NTRS)
Ashrafi, S.
1991-01-01
The mathematical structure of the programs written to construct a nonlinear predictive model to forecast solar flux directly from its time series without reference to any underlying solar physics is presented. This method and the programs are written so that one could apply the same technique to forecast other chaotic time series, such as geomagnetic data, attitude and orbit data, and even financial indexes and stock market data. Perhaps the most important application of this technique to flight dynamics is to model Goddard Trajectory Determination System (GTDS) output of residues between observed position of spacecraft and calculated position with no drag (drag flag = off). This would result in a new model of drag working directly from observed data.
Direct Observation of Spatiotemporal Dynamics of Short Electron Bunches in Storage Rings
NASA Astrophysics Data System (ADS)
Evain, C.; Roussel, E.; Le Parquier, M.; Szwaj, C.; Tordeux, M.-A.; Brubach, J.-B.; Manceron, L.; Roy, P.; Bielawski, S.
2017-02-01
In recent synchrotron radiation facilities, the use of short (picosecond) electron bunches is a powerful method for producing giant pulses of terahertz coherent synchrotron radiation. Here we report on the first direct observation of these pulse shapes with a few picoseconds resolution, and of their dynamics over a long time. We thus confirm in a very direct way the theories predicting an interplay between two physical processes. Below a critical bunch charge, we observe a train of identical THz pulses (a broadband Terahertz comb) stemming from the shortness of the electron bunches. Above this threshold, a large part of the emission is dominated by drifting structures, which appear through spontaneous self-organization. These challenging single-shot THz recordings are made possible by using a recently developed photonic time stretch detector with a high sensitivity. The experiment has been realized at the SOLEIL storage ring.
Resolving the Crab Nebula with Direct Hard X-Ray Imaging
NASA Technical Reports Server (NTRS)
Swartz, Douglas A.; Ramsey, Brian D.; Tennant, Allyn F.; Dietz, Kurtis L.; Apple, Jeff A.; Gaskin, Jessica A.; Weisskopf, Martin
2008-01-01
We report the first direct hard (25--60 keV) X-ray imaging observation of the Crab Nebula that resolves structure to approximately 0.25 pc. The observation was performed over a 1.4 hour period during a balloon flight from Ft. Sumner, NM, on 2007 May 27. The source was detected in the energy band above the atmospheric cutoff at approx.25 keV and below the mirror graze angle cutoff at approx.60 keV. The image shows elongation about 25 degrees E of N in the direction along the plane of the torus (and perpendicular to the jet axis) with a slight surface-brightness enhancement NE of the pulsar. The spectrum within a 1.7 arcminute radius region centered on the Crab pulsar can be fitted with a Gamma=2 power law absorbed by an atmospheric column consistent with the balloon altitude at the time of observation.
Photovoltaic switching mechanism in lateral structure hybrid perovskite solar cells
Yuan, Yongbo; Chae, Jungseok; Shao, Yuchuan; ...
2015-06-05
In this study, long range electromigration of methylammonium ions (MA +) in methyl ammonium lead tri-iodide (MAPbI 3) film is observed directly using the photothermal induced resonance technique. The electromigration of MA + leads to the formation of a lateral p-i-n structure, which is the origin of the switchable photovoltaic effect in MAPbI 3 perovskite devices.
Lattice relations and solidification of the complex regular eutectic (Cr,Fe)-(Cr,Fe)23C6
NASA Astrophysics Data System (ADS)
Lai, Hsuan-Han; Hsieh, Chih-Chun; Lin, Chi-Ming; Wu, Weite
2017-05-01
The eutectic (Cr,Fe)-(Cr,Fe)23C6 showed a triaxial fishbone structure and could be categorized as a "complex regular structure". In this study, the lattice relations of the fishbone (Cr,Fe)23C6 were examined and the solidification process was observed using a transmission electron microscope and a confocal laser scanning microscope. For one of the three fish bones in a eutectic cell, parallel (Cr,Fe)23C6 lamellas at one side of the spine had the same lattice direction, as did those in the (Cr,Fe) phase. The lattices of neighboring (Cr,Fe)23C6 and (Cr,Fe) phases were not coherent. Lamellar (Cr,Fe)23C6 on opposite sides of a spine had different lattice directions, and their lattice boundary was in the spine. By using the confocal laser scanning microscope, the solidification of lamellar eutectic structure could be observed. At the low cooling rate of 5 o C·min-1, parallel lamellas would grow thick blocks instead of thin plates. To obtain a thin lamellar eutectic structure, the cooling rate should be higher, like the rate in welding.
Yang, Xi; Han, Guoqiang; Cai, Hongmin; Song, Yan
2017-03-31
Revealing data with intrinsically diagonal block structures is particularly useful for analyzing groups of highly correlated variables. Earlier researches based on non-negative matrix factorization (NMF) have been shown to be effective in representing such data by decomposing the observed data into two factors, where one factor is considered to be the feature and the other the expansion loading from a linear algebra perspective. If the data are sampled from multiple independent subspaces, the loading factor would possess a diagonal structure under an ideal matrix decomposition. However, the standard NMF method and its variants have not been reported to exploit this type of data via direct estimation. To address this issue, a non-negative matrix factorization with multiple constraints model is proposed in this paper. The constraints include an sparsity norm on the feature matrix and a total variational norm on each column of the loading matrix. The proposed model is shown to be capable of efficiently recovering diagonal block structures hidden in observed samples. An efficient numerical algorithm using the alternating direction method of multipliers model is proposed for optimizing the new model. Compared with several benchmark models, the proposed method performs robustly and effectively for simulated and real biological data.
Loading mode dependent effective properties of octet-truss lattice structures using 3D-printing
NASA Astrophysics Data System (ADS)
Challapalli, Adithya
Cellular materials, often called lattice materials, are increasingly receiving attention for their ultralight structures with high specific strength, excellent impact absorption, acoustic insulation, heat dissipation media and compact heat exchangers. In alignment with emerging additive manufacturing (AM) technology, realization of the structural applications of the lattice materials appears to be becoming faster. Considering the direction dependent material properties of the products with AM, by directionally dependent printing resolution, effective moduli of lattice structures appear to be directionally dependent. In this paper, a constitutive model of a lattice structure, which is an octet-truss with a base material having an orthotropic material property considering AM is developed. In a case study, polyjet based 3D printing material having an orthotropic property with a 9% difference in the principal direction provides difference in the axial and shear moduli in the octet-truss by 2.3 and 4.6%. Experimental validation for the effective properties of a 3D printed octet-truss is done for uniaxial tension and compression test. The theoretical value based on the micro-buckling of truss member are used to estimate the failure strength. Modulus value appears a little overestimate compared with the experiment. Finite element (FE) simulations for uniaxial compression and tension of octettruss lattice materials are conducted. New effective properties for the octet-truss lattice structure are developed considering the observed behavior of the octet-truss structure under macroscopic compression and tension trough simulations.
THE SOURCE STRUCTURE OF 0642+449 DETECTED FROM THE CONT14 OBSERVATIONS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Xu, Ming H.; Wang, Guang L.; Heinkelmann, Robert
2016-11-01
The CONT14 campaign with state-of-the-art very long baseline interferometry (VLBI) data has observed the source 0642+449 with about 1000 observables each day during a continuous observing period of 15 days, providing tens of thousands of closure delays—the sum of the delays around a closed loop of baselines. The closure delay is independent of the instrumental and propagation delays and provides valuable additional information about the source structure. We demonstrate the use of this new “observable” for the determination of the structure in the radio source 0642+449. This source, as one of the defining sources in the second realization of themore » International Celestial Reference Frame, is found to have two point-like components with a relative position offset of −426 microarcseconds ( μ as) in R.A. and −66 μ as in decl. The two components are almost equally bright, with a flux-density ratio of 0.92. The standard deviation of closure delays for source 0642+449 was reduced from 139 to 90 ps by using this two-component model. Closure delays larger than 1 ns are found to be related to the source structure, demonstrating that structure effects for a source with this simple structure could be up to tens of nanoseconds. The method described in this paper does not rely on a priori source structure information, such as knowledge of source structure determined from direct (Fourier) imaging of the same observations or observations at other epochs. We anticipate our study to be a starting point for more effective determination of the structure effect in VLBI observations.« less
10 AU scale halo structure around DG Tauri
NASA Technical Reports Server (NTRS)
Chen, Wen P.; Howell, R. R.; Simon, M.; Benson, J. A.
1992-01-01
Lunar occultation observations of the active T Tauri star DG Tau show that in the infrared K band it has a core-halo structure: 20-25 percent of the flux comes from a region 10 AU in extent and the rest from an unresolved core smaller than an AU. These results are consistent with those reported by Leinert et al. from a separate observation. The results obtained here and those of Leinert et al., measuring the intensity distribution projected along directions spanning roughly 40 deg, indicate that the resolved structure is not highly elongated. The extended emission is interpreted as star light scattered by optically thin dust located in a halo surrounding the star.
SCIENCE BRIEF: CONDITION ASSESSMENT OF COLLECTION SYSTEMS
To assess the condition of a collection system, data and information are gathered through observation, direct inspection, investigation, and indirect monitoring and reporting. An analysis of the data and information helps determine the structural, operational, and performance sta...
The three-dimensional genome organization of Drosophila melanogaster through data integration.
Li, Qingjiao; Tjong, Harianto; Li, Xiao; Gong, Ke; Zhou, Xianghong Jasmine; Chiolo, Irene; Alber, Frank
2017-07-31
Genome structures are dynamic and non-randomly organized in the nucleus of higher eukaryotes. To maximize the accuracy and coverage of three-dimensional genome structural models, it is important to integrate all available sources of experimental information about a genome's organization. It remains a major challenge to integrate such data from various complementary experimental methods. Here, we present an approach for data integration to determine a population of complete three-dimensional genome structures that are statistically consistent with data from both genome-wide chromosome conformation capture (Hi-C) and lamina-DamID experiments. Our structures resolve the genome at the resolution of topological domains, and reproduce simultaneously both sets of experimental data. Importantly, this data deconvolution framework allows for structural heterogeneity between cells, and hence accounts for the expected plasticity of genome structures. As a case study we choose Drosophila melanogaster embryonic cells, for which both data types are available. Our three-dimensional genome structures have strong predictive power for structural features not directly visible in the initial data sets, and reproduce experimental hallmarks of the D. melanogaster genome organization from independent and our own imaging experiments. Also they reveal a number of new insights about genome organization and its functional relevance, including the preferred locations of heterochromatic satellites of different chromosomes, and observations about homologous pairing that cannot be directly observed in the original Hi-C or lamina-DamID data. Our approach allows systematic integration of Hi-C and lamina-DamID data for complete three-dimensional genome structure calculation, while also explicitly considering genome structural variability.
Andersen, Olaf; Vesenjak, Matej; Fiedler, Thomas; Jehring, Ulrike; Krstulović-Opara, Lovre
2016-01-01
Rigid metallic fiber structures made from a variety of different metals and alloys have been investigated mainly with regard to their functional properties such as heat transfer, pressure drop, or filtration characteristics. With the recent advent of aluminum and magnesium-based fiber structures, the application of such structures in light-weight crash absorbers has become conceivable. The present paper therefore elucidates the mechanical behavior of rigid sintered fiber structures under quasi-static and dynamic loading. Special attention is paid to the strongly anisotropic properties observed for different directions of loading in relation to the main fiber orientation. Basically, the structures show an orthotropic behavior; however, a finite thickness of the fiber slabs results in moderate deviations from a purely orthotropic behavior. The morphology of the tested specimens is examined by computed tomography, and experimental results for different directions of loading as well as different relative densities are presented. Numerical calculations were carried out using real structural data derived from the computed tomography data. Depending on the direction of loading, the fiber structures show a distinctively different deformation behavior both experimentally and numerically. Based on these results, the prevalent modes of deformation are discussed and a first comparison with an established polymer foam and an assessment of the applicability of aluminum fiber structures in crash protection devices is attempted. PMID:28773522
Andersen, Olaf; Vesenjak, Matej; Fiedler, Thomas; Jehring, Ulrike; Krstulović-Opara, Lovre
2016-05-21
Rigid metallic fiber structures made from a variety of different metals and alloys have been investigated mainly with regard to their functional properties such as heat transfer, pressure drop, or filtration characteristics. With the recent advent of aluminum and magnesium-based fiber structures, the application of such structures in light-weight crash absorbers has become conceivable. The present paper therefore elucidates the mechanical behavior of rigid sintered fiber structures under quasi-static and dynamic loading. Special attention is paid to the strongly anisotropic properties observed for different directions of loading in relation to the main fiber orientation. Basically, the structures show an orthotropic behavior; however, a finite thickness of the fiber slabs results in moderate deviations from a purely orthotropic behavior. The morphology of the tested specimens is examined by computed tomography, and experimental results for different directions of loading as well as different relative densities are presented. Numerical calculations were carried out using real structural data derived from the computed tomography data. Depending on the direction of loading, the fiber structures show a distinctively different deformation behavior both experimentally and numerically. Based on these results, the prevalent modes of deformation are discussed and a first comparison with an established polymer foam and an assessment of the applicability of aluminum fiber structures in crash protection devices is attempted.
Hierarchical mesostructured titanium phosphonates with unusual uniform lines of macropores.
Ma, Tian-Yi; Lin, Xiu-Zhen; Zhang, Xue-Jun; Yuan, Zhong-Yong
2011-04-01
Organic-inorganic hybrid materials of mesostructured titanium phosphonates with unusual uniform lines of macropores were synthesized by using bis(hexamethylenetriamine) penta(methylenephosphonic acid) (BHMTPMP) as the coupling molecule, through a one-pot hydrothermal process without any surfactant assistance. A wormhole-like mesostructure and many uniform parallel lines of macropores divided by solid ridges in the same direction were confirmed by N(2) sorption, SEM and TEM observations. This novel macropore architecture has never been observed in other metal phosphonate materials, which may be directly related to the structure nature of BHMTPMP with extra long alkyl chains. The structural characterization of FT-IR and MAS NMR revealed the integrity of organic groups inside the hybrid framework. The hybrid materials were also used as adsorbents for heavy metal ions and CO(2), in order to clarify the impacts of the organic contents and organic types on the physicochemical properties of the synthesized hierarchical macro-/mesoporous phosphonate materials.
Direct observation of fast protein conformational switching.
Ishikawa, Haruto; Kwak, Kyungwon; Chung, Jean K; Kim, Seongheun; Fayer, Michael D
2008-06-24
Folded proteins can exist in multiple conformational substates. Each substate reflects a local minimum on the free-energy landscape with a distinct structure. By using ultrafast 2D-IR vibrational echo chemical-exchange spectroscopy, conformational switching between two well defined substates of a myoglobin mutant is observed on the approximately 50-ps time scale. The conformational dynamics are directly measured through the growth of cross peaks in the 2D-IR spectra of CO bound to the heme active site. The conformational switching involves motion of the distal histidine/E helix that changes the location of the imidazole side group of the histidine. The exchange between substates changes the frequency of the CO, which is detected by the time dependence of the 2D-IR vibrational echo spectrum. These results demonstrate that interconversion between protein conformational substates can occur on very fast time scales. The implications for larger structural changes that occur on much longer time scales are discussed.
Stress- and structure-controlled anisotropy in a region of complex faulting—Yuha Desert, California
Cochran, Elizabeth S.; Kroll, Kayla A.
2015-01-01
We examine shear velocity anisotropy in the Yuha Desert, California using aftershocks of the 2010 M7.2 El Mayor-Cucapah earthquake. The Yuha Desert is underlain by a complex network of right- and left-lateral conjugate faults, some of which experienced triggered slip during the El Mayor-Cucapah earthquake. An automated method that implements multiple measurement windows and a range of bandpass filters is used to estimate the fast direction (ϕ) and delay time (δt) of the split shear waves. We find an average ϕ oriented approximately north–south suggesting it is primarily controlled by the regional maximum compressive stress direction. However, the spatial variability in ϕ reveals that the fault structures that underlie the Yuha Desert also influence the measured splitting parameters. We infer that the northeast- and northwest-oriented ϕ reflect shear fabric subparallel to the conjugate fault structures. We do not observe a simple correlation between δt and hypocentral distance. Instead, the observed spatial variation in δt suggests that near-source variation in anisotropic strength may be equal to or more important than effects local to the station. No temporal variation in splitting parameters is observed during the 70-day period following the main shock. In this region of complex faulting, we observe a spatially variable pattern of anisotropy that is both stress- and structure-controlled. This study suggests that shear fabric can form even along short, discontinuous fault strands with minimal offset.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Aartsen, M. G.; Abraham, K.; Ackermann, M.
The IceCube Neutrino Observatory accumulated a total of 318 billion cosmic-ray-induced muon events between 2009 May and 2015 May. This data set was used for a detailed analysis of the sidereal anisotropy in the arrival directions of cosmic rays in the TeV to PeV energy range. The observed global sidereal anisotropy features large regions of relative excess and deficit, with amplitudes of the order of 10{sup 3} up to about 100 TeV. A decomposition of the arrival direction distribution into spherical harmonics shows that most of the power is contained in the low-multipole ( ℓ ≤ 4) moments. However, highermore » multipole components are found to be statistically significant down to an angular scale of less than 10°, approaching the angular resolution of the detector. Above 100 TeV, a change in the morphology of the arrival direction distribution is observed, and the anisotropy is characterized by a wide relative deficit whose amplitude increases with primary energy up to at least 5 PeV, the highest energies currently accessible to IceCube. No time dependence of the large- and small-scale structures is observed in the period of six years covered by this analysis. The high-statistics data set reveals more details of the properties of the anisotropy and is potentially able to shed light on the various physical processes that are responsible for the complex angular structure and energy evolution.« less
NASA Astrophysics Data System (ADS)
Aartsen, M. G.; Abraham, K.; Ackermann, M.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Ahrens, M.; Altmann, D.; Anderson, T.; Ansseau, I.; Anton, G.; Archinger, M.; Arguelles, C.; Arlen, T. C.; Auffenberg, J.; Bai, X.; Barwick, S. W.; Baum, V.; Bay, R.; Beatty, J. J.; Becker Tjus, J.; Becker, K.-H.; Beiser, E.; BenZvi, S.; Berghaus, P.; Berley, D.; Bernardini, E.; Bernhard, A.; Besson, D. Z.; Binder, G.; Bindig, D.; Bissok, M.; Blaufuss, E.; Blumenthal, J.; Boersma, D. J.; Bohm, C.; Börner, M.; Bos, F.; Bose, D.; Böser, S.; Botner, O.; Braun, J.; Brayeur, L.; Bretz, H.-P.; Buzinsky, N.; Casey, J.; Casier, M.; Cheung, E.; Chirkin, D.; Christov, A.; Clark, K.; Classen, L.; Coenders, S.; Collin, G. H.; Conrad, J. M.; Cowen, D. F.; Cruz Silva, A. H.; Daughhetee, J.; Davis, J. C.; Day, M.; de André, J. P. A. M.; De Clercq, C.; del Pino Rosendo, E.; Dembinski, H.; De Ridder, S.; Desiati, P.; de Vries, K. D.; de Wasseige, G.; de With, M.; DeYoung, T.; Díaz-Vélez, J. C.; di Lorenzo, V.; Dujmovic, H.; Dumm, J. P.; Dunkman, M.; Eberhardt, B.; Ehrhardt, T.; Eichmann, B.; Euler, S.; Evenson, P. A.; Fahey, S.; Fazely, A. R.; Feintzeig, J.; Felde, J.; Filimonov, K.; Finley, C.; Flis, S.; Fösig, C.-C.; Fuchs, T.; Gaisser, T. K.; Gaior, R.; Gallagher, J.; Gerhardt, L.; Ghorbani, K.; Gier, D.; Gladstone, L.; Glagla, M.; Glüsenkamp, T.; Goldschmidt, A.; Golup, G.; Gonzalez, J. G.; Góra, D.; Grant, D.; Griffith, Z.; Ha, C.; Haack, C.; Haj Ismail, A.; Hallgren, A.; Halzen, F.; Hansen, E.; Hansmann, B.; Hansmann, T.; Hanson, K.; Hebecker, D.; Heereman, D.; Helbing, K.; Hellauer, R.; Hickford, S.; Hignight, J.; Hill, G. C.; Hoffman, K. D.; Hoffmann, R.; Holzapfel, K.; Homeier, A.; Hoshina, K.; Huang, F.; Huber, M.; Huelsnitz, W.; Hulth, P. O.; Hultqvist, K.; In, S.; Ishihara, A.; Jacobi, E.; Japaridze, G. S.; Jeong, M.; Jero, K.; Jones, B. J. P.; Jurkovic, M.; Kappes, A.; Karg, T.; Karle, A.; Katz, U.; Kauer, M.; Keivani, A.; Kelley, J. L.; Kemp, J.; Kheirandish, A.; Kim, M.; Kintscher, T.; Kiryluk, J.; Klein, S. R.; Kohnen, G.; Koirala, R.; Kolanoski, H.; Konietz, R.; Köpke, L.; Kopper, C.; Kopper, S.; Koskinen, D. J.; Kowalski, M.; Krings, K.; Kroll, G.; Kroll, M.; Krückl, G.; Kunnen, J.; Kunwar, S.; Kurahashi, N.; Kuwabara, T.; Labare, M.; Lanfranchi, J. L.; Larson, M. J.; Lennarz, D.; Lesiak-Bzdak, M.; Leuermann, M.; Leuner, J.; Lu, L.; Lünemann, J.; Madsen, J.; Maggi, G.; Mahn, K. B. M.; Mandelartz, M.; Maruyama, R.; Mase, K.; Matis, H. S.; Maunu, R.; McNally, F.; Meagher, K.; Medici, M.; Meier, M.; Meli, A.; Menne, T.; Merino, G.; Meures, T.; Miarecki, S.; Middell, E.; Mohrmann, L.; Montaruli, T.; Morse, R.; Nahnhauer, R.; Naumann, U.; Neer, G.; Niederhausen, H.; Nowicki, S. C.; Nygren, D. R.; Obertacke Pollmann, A.; Olivas, A.; Omairat, A.; O'Murchadha, A.; Palczewski, T.; Pandya, H.; Pankova, D. V.; Paul, L.; Pepper, J. A.; Pérez de los Heros, C.; Pfendner, C.; Pieloth, D.; Pinat, E.; Posselt, J.; Price, P. B.; Przybylski, G. T.; Quinnan, M.; Raab, C.; Rädel, L.; Rameez, M.; Rawlins, K.; Reimann, R.; Relich, M.; Resconi, E.; Rhode, W.; Richman, M.; Richter, S.; Riedel, B.; Robertson, S.; Rongen, M.; Rott, C.; Ruhe, T.; Ryckbosch, D.; Sabbatini, L.; Sander, H.-G.; Sandrock, A.; Sandroos, J.; Sarkar, S.; Schatto, K.; Schimp, M.; Schlunder, P.; Schmidt, T.; Schoenen, S.; Schöneberg, S.; Schönwald, A.; Schumacher, L.; Seckel, D.; Seunarine, S.; Soldin, D.; Song, M.; Spiczak, G. M.; Spiering, C.; Stahlberg, M.; Stamatikos, M.; Stanev, T.; Stasik, A.; Steuer, A.; Stezelberger, T.; Stokstad, R. G.; Stössl, A.; Ström, R.; Strotjohann, N. L.; Sullivan, G. W.; Sutherland, M.; Taavola, H.; Taboada, I.; Tatar, J.; Ter-Antonyan, S.; Terliuk, A.; Tešić, G.; Tilav, S.; Toale, P. A.; Tobin, M. N.; Toscano, S.; Tosi, D.; Tselengidou, M.; Turcati, A.; Unger, E.; Usner, M.; Vallecorsa, S.; Vandenbroucke, J.; van Eijndhoven, N.; Vanheule, S.; van Santen, J.; Veenkamp, J.; Vehring, M.; Voge, M.; Vraeghe, M.; Walck, C.; Wallace, A.; Wallraff, M.; Wandkowsky, N.; Weaver, Ch.; Wendt, C.; Westerhoff, S.; Whelan, B. J.; Wiebe, K.; Wiebusch, C. H.; Wille, L.; Williams, D. R.; Wills, L.; Wissing, H.; Wolf, M.; Wood, T. R.; Woschnagg, K.; Xu, D. L.; Xu, X. W.; Xu, Y.; Yanez, J. P.; Yodh, G.; Yoshida, S.; Zoll, M.; IceCube Collaboration
2016-08-01
The IceCube Neutrino Observatory accumulated a total of 318 billion cosmic-ray-induced muon events between 2009 May and 2015 May. This data set was used for a detailed analysis of the sidereal anisotropy in the arrival directions of cosmic rays in the TeV to PeV energy range. The observed global sidereal anisotropy features large regions of relative excess and deficit, with amplitudes of the order of 10-3 up to about 100 TeV. A decomposition of the arrival direction distribution into spherical harmonics shows that most of the power is contained in the low-multipole (ℓ ≤ 4) moments. However, higher multipole components are found to be statistically significant down to an angular scale of less than 10°, approaching the angular resolution of the detector. Above 100 TeV, a change in the morphology of the arrival direction distribution is observed, and the anisotropy is characterized by a wide relative deficit whose amplitude increases with primary energy up to at least 5 PeV, the highest energies currently accessible to IceCube. No time dependence of the large- and small-scale structures is observed in the period of six years covered by this analysis. The high-statistics data set reveals more details of the properties of the anisotropy and is potentially able to shed light on the various physical processes that are responsible for the complex angular structure and energy evolution.
Directional x-ray dark-field imaging of strongly ordered systems
NASA Astrophysics Data System (ADS)
Jensen, Torben Haugaard; Bech, Martin; Zanette, Irene; Weitkamp, Timm; David, Christian; Deyhle, Hans; Rutishauser, Simon; Reznikova, Elena; Mohr, Jürgen; Feidenhans'L, Robert; Pfeiffer, Franz
2010-12-01
Recently a novel grating based x-ray imaging approach called directional x-ray dark-field imaging was introduced. Directional x-ray dark-field imaging yields information about the local texture of structures smaller than the pixel size of the imaging system. In this work we extend the theoretical description and data processing schemes for directional dark-field imaging to strongly scattering systems, which could not be described previously. We develop a simple scattering model to account for these recent observations and subsequently demonstrate the model using experimental data. The experimental data includes directional dark-field images of polypropylene fibers and a human tooth slice.
The Anisotropic Structure of South China Sea: Using OBS Data to Constrain Mantle Flow
NASA Astrophysics Data System (ADS)
Li, L.; Xue, M.; Yang, T.; Liu, C.; Hua, Q.; Xia, S.; Huang, H.; Le, B. M.; Huo, D.; Pan, M.
2015-12-01
The dynamic mechanism of the formation of South China Sea (SCS) has been debated for decades. The anisotropic structure can provide useful insight into the complex evolution of SCS by indicating its mantle flow direction and strength. In this study, we employ shear wave splitting methods on two half-year seismic data collected from 10 and 6 passive source Ocean Bottom Seismometers (OBS) respectively. These OBSs were deployed along both sides of the extinct ridge in the central basin of SCS by Tongji University in 2012 and 2013 respectively, which were then successfully recovered in 2013 and 2015 respectively. Through processing and inspecting the global and regional earthquakes (with local events being processing) of the 2012 dataset, measurements are made for 2 global events and 24 regional events at 5 OBSs using the tangential energy minimization, the smallest eigenvalue minimization, as well as the correlation methods. We also implement cluster analysis on the splitting results obtained for different time windows as well as filtered at different frequency bands. For teleseismic core phases like SKS and PKS, we find the fast polarization direction beneath the central basin is approximately NE-SW, nearly parallel to the extinct ridge in the central basin of SCS. Whereas for regional events, the splitting analysis on S, PS and ScS phases shows much more complicated fast directions as the ray path varies for different phases. The fast directions observed can be divided into three groups: (1) for the events from the Eurasia plate, a gradual rotation of the fast polarization direction from NNE-SSW to NEE-SWW along the path from the inner Eurasia plate to the central SCS is observed, implying the mantle flow is controlled by the India-Eurasia collision; (2) for the events located at the junction of Pacific plate and Philippine plate, the dominant fast direction is NW-SE, almost perpendicular to Ryukyu Trench as well as sub-parallel to the absolute direction of Philippine plate; (3) for the events occurred in the SE direction near the Philippine Fault zone, the observed NE-SW fast direction is sub-parallel to the subduction direction of the Philippine plate.
Nanoclusters of α-Fe naturally formed in twinned martensite after martensitic transformation
NASA Astrophysics Data System (ADS)
Liu, X.; Ping, D. H.; Xiang, H. P.; Lu, X.; Shen, J.
2018-05-01
Various Fe-C binary alloys with the carbon content from 0.05 to 2.0 (wt. %) have been prepared and water-quenched at austenitizing temperatures. The fine structure of the twinned martensite in the quenched samples has been investigated by means of transmission electron microscopy (TEM) in order to understand the initial products during the formation of the martensite structure. In the twinned structure (body-centered-cubic {112}⟨111⟩-type twin), TEM dark field observations have revealed that both matrix and twinned crystal regions are fully composed of ultra-fine particles (α-Fe nano-crystallites). The particles tend to have the same preferred direction (or texture) in the twinned martensite and the size is almost the same (1-2 nm). The ultra-fine particle structure has been commonly observed regardless of the carbon content; however, such a fine particle structure has been observed only in the martensite with the twinning structure. After in-situ TEM heating, recrystallization occurred and the fine particles merged into larger α-Fe grains; at the same time, the twinned relationship also disappeared.
Structural Brain Connectivity Constrains within-a-Day Variability of Direct Functional Connectivity
Park, Bumhee; Eo, Jinseok; Park, Hae-Jeong
2017-01-01
The idea that structural white matter connectivity constrains functional connectivity (interactions among brain regions) has widely been explored in studies of brain networks; studies have mostly focused on the “average” strength of functional connectivity. The question of how structural connectivity constrains the “variability” of functional connectivity remains unresolved. In this study, we investigated the variability of resting state functional connectivity that was acquired every 3 h within a single day from 12 participants (eight time sessions within a 24-h period, 165 scans per session). Three different types of functional connectivity (functional connectivity based on Pearson correlation, direct functional connectivity based on partial correlation, and the pseudo functional connectivity produced by their difference) were estimated from resting state functional magnetic resonance imaging data along with structural connectivity defined using fiber tractography of diffusion tensor imaging. Those types of functional connectivity were evaluated with regard to properties of structural connectivity (fiber streamline counts and lengths) and types of structural connectivity such as intra-/inter-hemispheric edges and topological edge types in the rich club organization. We observed that the structural connectivity constrained the variability of direct functional connectivity more than pseudo-functional connectivity and that the constraints depended strongly on structural connectivity types. The structural constraints were greater for intra-hemispheric and heterologous inter-hemispheric edges than homologous inter-hemispheric edges, and feeder and local edges than rich club edges in the rich club architecture. While each edge was highly variable, the multivariate patterns of edge involvement, especially the direct functional connectivity patterns among the rich club brain regions, showed low variability over time. This study suggests that structural connectivity not only constrains the strength of functional connectivity, but also the within-a-day variability of functional connectivity and connectivity patterns, particularly the direct functional connectivity among brain regions. PMID:28848416
NASA Astrophysics Data System (ADS)
Gao, Deheng; Mou, Yingping; Feng, Shiping
2018-02-01
The recent discovery of a direct link between the sharp peak in the electron quasiparticle scattering rate of cuprate superconductors and the well-known peak-dip-hump structure in the electron quasiparticle excitation spectrum is calling for an explanation. Within the framework of the kinetic-energy-driven superconducting mechanism, the complicated line-shape in the electron quasiparticle excitation spectrum of cuprate superconductors is investigated. It is shown that the interaction between electrons by the exchange of spin excitations generates a notable peak structure in the electron quasiparticle scattering rate around the antinodal and nodal regions. However, this peak structure disappears at the hot spots, which leads to that the striking peak-dip-hump structure is developed around the antinodal and nodal regions, and vanishes at the hot spots. The theory also confirms that the sharp peak observed in the electron quasiparticle scattering rate is directly responsible for the remarkable peak-dip-hump structure in the electron quasiparticle excitation spectrum of cuprate superconductors.
Natsuaki, Misaki N.; Leve, Leslie D.; Harold, Gordon T.; Neiderhiser, Jenae M.; Shaw, Daniel S.; Ganiban, Jody; Scaramella, Laura V.; Reiss, David
2013-01-01
This investigation examined the mutual influences between structured parenting and child social wariness during toddlerhood using a longitudinal adoption design. The sample consisted of 361 adoption-linked families, each including an adopted child, adoptive parents, and a birth mother. Heightened social wariness in children at age 18 months predicted reduced levels of observed structured parenting (i.e., less directive parenting with fewer commands and requests) in adoptive mothers at age 27 months. Adoptive fathers’ lower structured parenting at age 18 months predicted subsequent elevation in child social wariness. Birth mothers’ history of fear-related anxiety disorders was not associated with child social wariness. Findings highlight the role of dynamic family transactions in the development of social wariness during toddlerhood. PMID:23448430
NASA Astrophysics Data System (ADS)
Kohán, Balázs; Tyler, Jonathan; Jones, Matthew; Kern, Zoltán
2017-04-01
Water stable isotopes are important natural tracers in the hydrological cycle on global, regional and local scales. Daily precipitation water samples were collected from 70 sites over the British Isles on the 23rd, 24th, and 25th January, 2012 [1]. Samples were collected as part of a pilot study for the British Isotopes in Rainfall Project, a community engagement initiative, in collaboration with volunteer weather observers and the UK Met Office. Spatial correlation structure of daily precipitation stable oxygen isotope composition (δ18OP) has been explored by variogram analysis [2]. Since the variograms from the raw data suggested a pronounced trend, owing to the spatial trend discussed in the original study [1], a second order polynomial trend was removed from the raw δ18OP data and variograms were calculated on the residuals. Directional experimental semivariograms were calculated (steps: 10°, tolerance: 30°) and aggregated into variogram surface plots to explore the spatial dependence structure of daily δ18OP. Each daily data set produced distinct variogram plots. -A well expressed anisotropic structure can be seen for Jan 23. The lowest and highest variance was observed in the SW-NE and NNE-SSW direction, respectively. Meteorological observations showed that the majority of the atmospheric flow was SW on this day, so the direction of low variance seems to reflect this flow direction, while the maximum variance might reflect the moisture variance near the elongation of the frontal system. -A less characteristic but still expressed anisotropic structure was found for Jan 24 when a warm front passed the British Isles perpendicular to the east coast, leading to a characteristic east-west δ18OP gradient suggestive of progressive rainout. The low variance central zone has a 100 km radius which might correspond well to the width of the warm front zone. Although, the axis of minimum variance was similarly SW-NE, the zone of maximum variance was broader and practically perpendicular to it. In this case, however, directions of the axes appear misaligned with the flow direction. -We could not observe similar characteristic patterns in the last variogram calculated from the Jan 25 data set. These preliminary results suggest that variogram analysis is a promising approach to link δ18OP patterns to atmospheric processes. NKFIH: SNN118205/ARRS: N1-0054 References 1.Tyler, J. J., Jones, M., Arrowsmith, C., Allott, T., & Leng, M. J. (2016). Spatial patterns in the oxygen isotope composition of daily rainfall in the British Isles. Climate Dynamics 47:1971-1987 2.Webster, R. Oliver M.A. (2007) Geostatistics for Environmental Scientists. John Wiley & Sons, Chichester
Yamamoto, Kazuo; Iriyama, Yasutoshi; Hirayama, Tsukasa
2017-02-08
All-solid-state Li-ion batteries having incombustible solid electrolytes are promising energy storage devices because they have significant advantages in terms of safety, lifetime and energy density. Electrochemical reactions, namely, Li-ion insertion/extraction reactions, commonly occur around the nanometer-scale interfaces between the electrodes and solid electrolytes. Thus, transmission electron microscopy (TEM) is an appropriate technique to directly observe such reactions, providing important information for understanding the fundamental solid-state electrochemistry and improving battery performance. In this review, we introduce two types of TEM techniques for operando observations of battery reactions, spatially resolved electron energy-loss spectroscopy in a TEM mode for direct detection of the Li concentration profiles and electron holography for observing the electric potential changes due to Li-ion insertion/extraction reactions. We visually show how Li-ion insertion/extractions affect the crystal structures, electronic structures, and local electric potential during the charge-discharge processes in these batteries. © The Author 2016. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.
NASA Astrophysics Data System (ADS)
Worthington, L. L.; Christeson, G. L.; van Avendonk, H. J.; Gulick, S. P.
2009-12-01
We present results of a 2008 marine seismic reflection/refraction survey acquired as part of the St. Elias Erosion and Tectonics Project (STEEP), a multi-disciplinary NSF-Continental Dynamics project aimed at tectonic-climate interaction, structural evolution and geodynamics in the Chugach-St. Elias orogen. The Chugach-St.Elias orogen is the result of flat-slab subduction and collision of the Yakutat (YAK) microplate with North Amercian (NA) on the southern Alaska margin during the last ~10Ma. A fundamental goal of STEEP is to address controversy related to the deep crustal structure of the YAK block itself, describe its offshore structural relationships and constrain its buoyancy in order to understand the orogenic driver. Marine seismic reflection profiles acquired across the offshore YAK microplate provide the first regional images of the top of the subducting YAK basement. The basement reflector is observed near the seafloor at the Dangerous River Zone (DRZ) and is overlain by up to 12 km of sediments near Kayak Island, resulting in a basement dip of ~3° in the direction of subduction. The basement reflector also shallows near the shelf-edge adjacent to the Transition Fault, the YAK-Pacific boundary. These observations are indicative of an overall regional basement tilt towards the NA continent. Two coincident wide-angle refraction profiles constrain YAK crustal thickness between 30-35km, >20km thicker than normal oceanic crust, and lower crustal velocities potentially >7km/s. Crustal velocity and thickness are comparable to the Kerguelen oceanic plateau and the Siletz terrane. These results are the first direct observations in support of the oceanic plateau theory for the origin of the YAK microplate. Crustal velocity and structure are continuous across the DRZ on the YAK shelf, which is historically described as a vertical boundary between continental crust on the east and oceanic basement on the west. Instead, we observe a gradual shallowing of elevated crustal velocities associated with the aforementioned basement high near DRZ. Interestingly, observed Moho arrivals across the profile do not mimic the dipping trajectory of the basement reflector, indicating that the YAK slab may be slightly wedge-shaped, thinning in the direction of subduction. If true, the following implications for the YAK-NA collision must be considered: first, that uplift and deformation have intensified through time as thicker, more buoyant YAK crust attempts to subduct; second, migration of intense uplift from west to east across the orogen is partly controlled by underlying slab structure at depth.
Sun, Yintao; Wollenberg, Alexander L; O'Shea, Timothy Mark; Cui, Yanxiang; Zhou, Z Hong; Sofroniew, Michael V; Deming, Timothy J
2017-10-25
Synthetic diblock copolypeptides were designed to incorporate oppositely charged ionic segments that form β-sheet-structured hydrogel assemblies via polyion complexation when mixed in aqueous media. The observed chain conformation directed assembly was found to be required for efficient hydrogel formation and provided distinct and useful properties to these hydrogels, including self-healing after deformation, microporous architecture, and stability against dilution in aqueous media. While many promising self-assembled materials have been prepared using disordered or liquid coacervate polyion complex (PIC) assemblies, the use of ordered chain conformations in PIC assemblies to direct formation of new supramolecular morphologies is unprecedented. The promising attributes and unique features of the β-sheet-structured PIC hydrogels described here highlight the potential of harnessing conformational order derived from PIC assembly to create new supramolecular materials.
Anisotropic Ripple Deformation in Phosphorene.
Kou, Liangzhi; Ma, Yandong; Smith, Sean C; Chen, Changfeng
2015-05-07
Two-dimensional materials tend to become crumpled according to the Mermin-Wagner theorem, and the resulting ripple deformation may significantly influence electronic properties as observed in graphene and MoS2. Here, we unveil by first-principles calculations a new, highly anisotropic ripple pattern in phosphorene, a monolayer black phosphorus, where compression-induced ripple deformation occurs only along the zigzag direction in the strain range up to 10%, but not the armchair direction. This direction-selective ripple deformation mode in phosphorene stems from its puckered structure with coupled hinge-like bonding configurations and the resulting anisotropic Poisson ratio. We also construct an analytical model using classical elasticity theory for ripple deformation in phosphorene under arbitrary strain. The present results offer new insights into the mechanisms governing the structural and electronic properties of phosphorene crucial to its device applications.
Anisotropic expansion and amorphization of Ga2O3 irradiated with 946 MeV Au ions
NASA Astrophysics Data System (ADS)
Tracy, Cameron L.; Lang, Maik; Severin, Daniel; Bender, Markus; Trautmann, Christina; Ewing, Rodney C.
2016-05-01
The structural response of β-Ga2O3 to irradiation-induced electronic excitation was investigated. A polycrystalline pellet of this material was irradiated with 946 MeV Au ions and the resulting structural modifications were characterized using in situ X-ray diffraction analysis at various ion fluences, up to 1 × 1013 cm-2. Amorphization was induced, with the accumulation of the amorphous phase following a single-impact mechanism in which each ion produces an amorphous ion track along its path. Concurrent with this phase transformation, an increase in the unit cell volume of the material was observed and quantified using Rietveld refinement. This unit cell expansion increased as a function of ion fluence before saturating at 1.8%. This effect is attributed to the generation of defects in an ion track shell region surrounding the amorphous track cores. The unit cell parameter increase was highly anisotropic, with no observed expansion in the [0 1 0] direction. This may be due to the structure of β-Ga2O3, which exhibits empty channels of connected interstitial sites oriented in this direction.
Direct measurement of the low temperature spin state transitions in La1-xSrxCoO3 (0.05 < x < 0.3)
NASA Astrophysics Data System (ADS)
Gulec, A.; Klie, R. F.
2014-12-01
Sr-doped LaCoO3 has a complex magnetic phase diagram, which is believed to be directly correlated to changes in the crystal structure and ordering of the Co3+ spin states. In this work, we study the low temperature Co3+-ion spin state transitions in Sr-doped LaCoO3 around the critical doping concentration where a metal to insulator transition has been observed using electron energy-loss spectroscopy of the O K-edge combined with the Co L-edge fine structure. We measure the local spin state of the Co3+-ions and we demonstrate that the Co3+ spin-state transition only occurs in La0.95Sr0.05CoO3 single-crystal materials in the temperature range accessible by LN2 in-situ cooling, while no structural symmetry change is observed. The presence of this low-temperature spin-state transition in La1-xSrxCoO3 (x < 0.17) has been proposed as the origin of the percolative magnetic ordering in doped LaCoO3.
Lemaire, Arnaud; Rooke, Joanna Claire; Chen, Li-Hua; Su, Bao-Lian
2011-03-15
Hierarchically structured spongy meso-macroporous aluminosilicates with high tetrahedral aluminum content were synthesized from a mixture of single molecular alkoxide precursor, (sec-BuO)2-Al-O-Si(OEt)3, already containing Si-O-Al bonds, and a silica coreactant, tetramethoxysilane (TMOS). The spontaneous byproduct templated macroporous structure formation has been directly visualized using in situ high-resolution optical microscopy (OM), allowing the crucial observation of a microbubble dispersion which is directly correlated to the macrostructure observed by electronic microscopies (SEM and TEM). This discovery leads to a comparative study with meso-macroporous pure metal oxide and to a proposal of the formation mechanism of meso-macroporous aluminosilicates with 3D interconnectivity. The aluminosilicate phase/microbubbles emulsion is produced by a phase separation process occurring between the aluminosilicate nanoparticles and the liquid hydrolysis-condensation reaction byproducts (water, methanol, ethanol, and butanol). The use of alkoxysilane improves the heterocondensation rates between the highly reactive aluminum alkoxide part of the single precursor and added silica species but, above all, leads to the spontaneous generation of an unusual meso-macroporosity in alkaline media. The particles obtained at pH = 13.0 featured regular micrometer-sized macrospheres separated by very thin mesoporous walls and connected by submicrometric openings, providing a 3D interconnectivity. The slight increase in pH value to 13.5 induced significant modifications in morphology and textural properties due to the slower gelification process of the aluminosilicate phase, resulting in the formation of an aluminosilicate material constituted of 1-2 µm large independent hollow mesoporous spheres.
Structural geologic interpretations from radar imagery
Reeves, Robert G.
1969-01-01
Certain structural geologic features may be more readily recognized on sidelooking airborne radar (SLAR) images than on conventional aerial photographs, other remote sensor imagery, or by ground observations. SLAR systems look obliquely to one or both sides and their images resemble aerial photographs taken at low sun angle with the sun directly behind the camera. They differ from air photos in geometry, resolution, and information content. Radar operates at much lower frequencies than the human eye, camera, or infrared sensors, and thus "sees" differently. The lower frequency enables it to penetrate most clouds and some precipitation, haze, dust, and some vegetation. Radar provides its own illumination, which can be closely controlled in intensity and frequency. It is narrow band, or essentially monochromatic. Low relief and subdued features are accentuated when viewed from the proper direction. Runs over the same area in significantly different directions (more than 45° from each other), show that images taken in one direction may emphasize features that are not emphasized on those taken in the other direction; optimum direction is determined by those features which need to be emphasized for study purposes. Lineaments interpreted as faults stand out on radar imagery of central and western Nevada; folded sedimentary rocks cut by faults can be clearly seen on radar imagery of northern Alabama. In these areas, certain structural and stratigraphic features are more pronounced on radar images than on conventional photographs; thus radar imagery materially aids structural interpretation.
Horiuchi, Yoshihiro; Gnanadesikan, Vijay; Ohshima, Takashi; Masu, Hyuma; Katagiri, Kosuke; Sei, Yoshihisa; Yamaguchi, Kentaro; Shibasaki, Masakatsu
2005-09-05
The development of a direct catalytic asymmetric aldol-Tishchenko reaction and the nature of its catalyst are described. An aldol-Tishchenko reaction of various propiophenone derivatives with aromatic aldehydes was promoted by [LaLi3(binol)3] (LLB), and reactivity and enantioselectivity were dramatically enhanced by the addition of lithium trifluoromethanesulfonate (LiOTf). First, we observed a dynamic structural change of LLB by the addition of LiOTf using 13C NMR spectroscopy, electronspray ionization mass spectrometry (ESI-MS), and cold-spray ionization mass spectrometry (CSI-MS). X-ray crystallography revealed that the structure of the newly generated self-assembled complex was a binuclear [La2Li4(binaphthoxide)5] complex 6. A reverse structural change of complex 6 to LLB by the addition of one equivalent of Li2(binol) was also confirmed by ESI-MS and experimental results. The drastic concentration effects on the direct catalytic asymmetric aldol-Tishchenko reaction suggested that the addition of LiOTf to LLB generated an active oligomeric catalyst species.
Knudson, M D; Desjarlais, M P; Becker, A; Lemke, R W; Cochrane, K R; Savage, M E; Bliss, D E; Mattsson, T R; Redmer, R
2015-06-26
Eighty years ago, it was proposed that solid hydrogen would become metallic at sufficiently high density. Despite numerous investigations, this transition has not yet been experimentally observed. More recently, there has been much interest in the analog of this predicted metallic transition in the dense liquid, due to its relevance to planetary science. Here, we show direct observation of an abrupt insulator-to-metal transition in dense liquid deuterium. Experimental determination of the location of this transition provides a much-needed benchmark for theory and may constrain the region of hydrogen-helium immiscibility and the boundary-layer pressure in standard models of the internal structure of gas-giant planets. Copyright © 2015, American Association for the Advancement of Science.
Development of HRO interferometer at Kochi University of Technology
NASA Astrophysics Data System (ADS)
Yamamoto, Masa-Yuki; Horiuchi, Hirotaka; Okamoto, Goro; Hamaguchi, Haruko; Noguchi, Kazuya
2007-12-01
As a typical radio meteor observation method, the Ham-band Radio meteor Observation (HRO) has been spread to many amateur meteor observers in the world, resulting in worldwide continuous detection of each meteor echo at precise time of appearance in any weather condition as well as in daytime. However, direction finding of incoming electromagnetic waves by meteors is difficult to obtain by a usual HRO system. An application of HRO with interferometer technique was developed in 2004-2005 in Kochi University of Technology (KUT), Japan. Within a context of the forwardscattering radar method, an HRO interferometer (HRO-IF) with 3 antennas was developed. Detailed structure of the HRO-IF system at KUT as well as calibration experiments of establishing accurate direction determination are presented.
Crystal structure and partial Ising-like magnetic ordering of orthorhombic D y 2 Ti O 5
Shamblin, Jacob; Calder, Stuart; Dun, Zhiling; ...
2016-07-12
The structure and magnetic properties of orthorhombic Dy 2TiO 5 have been investigated using x-ray diffraction, neutron diffraction, and alternating current (ac)/direct current (dc) magnetic susceptibility measurements. In this paper, we report a continuous structural distortion below 100 K characterized by negative thermal expansion in the [0 1 0] direction. Neutron diffraction and magnetic susceptibility measurements revealed that two-dimensional (2D) magnetic ordering begins at 3.1 K, which is followed by a three-dimensional magnetic transition at 1.7 K. The magnetic structure has been solved through a representational analysis approach and can be indexed with the propagation vector k = [0 1/2more » 0]. The spin structure corresponds to a coplanar model of interwoven 2D “sheets” extending in the [0 1 0] direction. The local crystal field is different for each Dy 3+ ion (Dy1 and Dy2), one of which possesses strong uniaxial symmetry indicative of Ising-like magnetic ordering. In conclusion, consequently, two succeeding transitions under magnetic field are observed in the ac susceptibility, which are associated with flipping each Dy 3+ spin independently.« less
NASA Astrophysics Data System (ADS)
Bich Do, Danh; Lin, Jian Hung; Diep Lai, Ngoc; Kan, Hung-Chih; Hsu, Chia Chen
2011-08-01
We demonstrate the fabrication of a three-dimensional (3D) polymer quadratic nonlinear (χ(2)) grating structure. By performing layer-by-layer direct laser writing (DLW) and spin-coating approaches, desired photobleached grating patterns were embedded in the guest--host dispersed-red-1/poly(methylmethacrylate) (DR1/PMMA) active layers of an active-passive alternative multilayer structure through photobleaching of DR1 molecules. Polyvinyl-alcohol and SU8 thin films were deposited between DR1/PMMA layers serving as a passive layer to separate DR1/PMMA active layers. After applying the corona electric field poling to the multilayer structure, nonbleached DR1 molecules in the active layers formed polar distribution, and a 3D χ(2) grating structure was obtained. The χ(2) grating structures at different DR1/PMMA nonlinear layers were mapped by laser scanning second harmonic (SH) microscopy, and no cross talk was observed between SH images obtained from neighboring nonlinear layers. The layer-by-layer DLW technique is favorable to fabricating hierarchical 3D polymer nonlinear structures for optoelectronic applications with flexible structural design.
Do, Danh Bich; Lin, Jian Hung; Lai, Ngoc Diep; Kan, Hung-Chih; Hsu, Chia Chen
2011-08-10
We demonstrate the fabrication of a three-dimensional (3D) polymer quadratic nonlinear (χ(2)) grating structure. By performing layer-by-layer direct laser writing (DLW) and spin-coating approaches, desired photobleached grating patterns were embedded in the guest-host dispersed-red-1/poly(methylmethacrylate) (DR1/PMMA) active layers of an active-passive alternative multilayer structure through photobleaching of DR1 molecules. Polyvinyl-alcohol and SU8 thin films were deposited between DR1/PMMA layers serving as a passive layer to separate DR1/PMMA active layers. After applying the corona electric field poling to the multilayer structure, nonbleached DR1 molecules in the active layers formed polar distribution, and a 3D χ(2) grating structure was obtained. The χ(2) grating structures at different DR1/PMMA nonlinear layers were mapped by laser scanning second harmonic (SH) microscopy, and no cross talk was observed between SH images obtained from neighboring nonlinear layers. The layer-by-layer DLW technique is favorable to fabricating hierarchical 3D polymer nonlinear structures for optoelectronic applications with flexible structural design.
Dissipative structures, machines, and organisms: A perspective
NASA Astrophysics Data System (ADS)
Kondepudi, Dilip; Kay, Bruce; Dixon, James
2017-10-01
Self-organization in nonequilibrium systems resulting in the formation of dissipative structures has been studied in a variety of systems, most prominently in chemical systems. We present a study of a voltage-driven dissipative structure consisting of conducting beads immersed in a viscous medium of oil. In this simple system, we observed remarkably complex organism-like behavior. The dissipative structure consists of a tree structure that spontaneously forms and moves like a worm and exhibits many features characteristic of living organisms. The complex motion of the beads driven by the applied field, the dipole-dipole interaction between the beads, and the hydrodynamic flow of the viscous medium result in a time evolution of the tree structure towards states of lower resistance or higher dissipation and thus higher rates of entropy production. The resulting end-directed evolution manifests as the tree moving to locations seeking higher current, the current that sustains its structure and dynamics. The study of end-directed evolution in the dissipative structure gives us a means to distinguish the fundamental difference between machines and organisms and opens a path for the formulation of physics of organisms.
Observations of Lake-Breeze Events During the Toronto 2015 Pan-American Games
NASA Astrophysics Data System (ADS)
Mariani, Zen; Dehghan, Armin; Joe, Paul; Sills, David
2018-01-01
Enhanced meteorological observations were made during the 2015 Pan and Parapan American Games in Toronto in order to measure the vertical and horizontal structure of lake-breeze events. Two scanning Doppler lidars (one fixed and one mobile), a C-band radar, and a network including 53 surface meteorological stations (mesonet) provided pressure, temperature, humidity, and wind speed and direction measurements over Lake Ontario and urban areas. These observations captured the full evolution (prior, during, and after) of 27 lake-breeze events (73% of observation days) in order to characterize the convective and dynamic processes driving lake breezes at the local scale and mesoscale. The dominant signal of a passing lake-breeze front (LBF) was an increase in dew-point temperature of 2.3 ± 0.3°C, coinciding with a 180° shift in wind direction and a decrease in air temperature of 2.1 ± 0.2°C. Doppler lidar observations over the lake detected lake breezes 1 hour (on average) before detection by radar and mesonet. On days with the synoptic flow in the offshore direction, the lidars observed wedge-shaped LBFs with shallow depths, which inhibited the radar's ability to detect the lake breeze. The LBF's ground speed and inland penetration distance were found to be well-correlated (r = 0.78), with larger inland penetration distances occurring on days with non-opposing (non-offshore) synoptic flow. The observed enhanced vertical motion ({>} 1 m s^{-1}) at the LBF, observed by the lidar on 54% of lake-breeze days, was greater (at times {>} 2.5 m s^{-1}) than that observed in previous studies and longer-lasting over the lake than over land. The weaker and less pronounced lake-breeze structure over land is illustrated in two case studies highlighting the lifetime of the lake-breeze circulation and the impact of propagation distance on lake-breeze intensity.
Study of a Solar X-Ray Telescope
NASA Technical Reports Server (NTRS)
Golub, Leon
1997-01-01
The highly structured nature of the outer solar atmosphere seems to be intimately linked to the presence, at the solar surface, of magnetic fields that have been generated inside the Sun and have emerged to the surface. The corona is brightest (and also hottest) at just those locations where the magnetic field has emerged from inside the Sun. Dynamo theory predicts that strong magnetic fields will be generated deep in the solar interior and that bundles or 'ropes' of magnetic flux will float to the surface. When this happens, a magnetically bipolar region will become visible, extending above the surface in a three-dimensional structure. The field lines penetrate through the surface, showing two magnetic poles, and also exhibit a three-dimensional structure above the surface. The structure created by the field emergence is rooted in the (relatively) cool photosphere and extends through the chromosphere and transition region to the corona. Thus, the magnetic field creates a region, called an active region, which contains portions at temperatures from less than 10(exp 4) K to greater than 10(exp 6) K, and is therefore visible at wavelengths from the infrared through x-rays. The locations where the magnetic field leaves and reenters the visible surface are called the 'footpoints' of the coronal structures associated with the magnetic field. The magnetic fields themselves are not directly visible. However, the hot coronal plasma is, for the most part, constrained to follow the direction of the magnetic field lines in the atmosphere. Now, 100 years after the discovery of x-rays by Wilhelm Roentgen in 1896, we can routinely make observations of the solar corona from outside the Earth's atmosphere in this region of the electromagnetic spectrum. As shown by comparing x-ray images with magnetograms, the bright corona over these bipolar magnetic regions consists of closed structures that seem to follow the orientation of the magnetic field. Although we can see down to the photosphere at x-ray wavelengths when observing the disk of the Sun, this part of the solar atmosphere emits so little that far from the peak of its Planck curve it appears dark in x-ray images. This impression of hot plasma following the magnetic field direction is further strengthened by quantitative studies that calculate coronal magnetic field strength and direction based on photospheric measurements and compare them with the observed brightness and location of the x-ray emitting structures. Such comparisons make it clear that, for the most part, the hot plasma conforms to the geometry of the magnetic field and that the coronal brightness is strongly linked to the strength of the magnetic fields which have erupted to the solar surface from the interior. It is also the case that the larger-scale, fainter corona, as well as coronal holes, are strongly influenced by the large-scale solar magnetic field. We may get a small hint of the reason that the coronal plasma outlines the direction of B by examining the thermal conductivity of a hot plasma in the presence of a magnetic field. This quantity has enormously different values in the directions parallel and perpendicular to the field for a coronal temperature of 10(exp 6) K, a particle density of 10(exp 9)/cu cm and a magnetic field strength of 100 G, the conductivity along the field is approximately 13 orders of magnitude greater than that perpendicular to the field. It is therefore not surprising that a parcel of plasma which is locally heated would conduct that heat preferentially in the direction of the field. We also note that the thermal conductivity parallel to the magnetic field increases with temperature T, while the perpendicular conductivity decreases. To the extent that the loop aspect ratio, i.e., the ratio of loop length to loop width, is determined by the thermal conductivity, we would expect that higher temperature loops are longer and thinner than cooler ones. However, if the loop width becomes smaller than the spatial resolution of the observing instrument, this effect will not be directly observable. For organizational purposes, we provide a listing of some scientific objectives for a Solar-B x-ray telescope, arranged in terms of identifiable features in the corona.
Minami, Shintaro; Sawada, Kengo; Chikenji, George
2014-01-01
It has been known that topologically different proteins of the same class sometimes share the same spatial arrangement of secondary structure elements (SSEs). However, the frequency by which topologically different structures share the same spatial arrangement of SSEs is unclear. It is important to estimate this frequency because it provides both a deeper understanding of the geometry of protein folds and a valuable suggestion for predicting protein structures with novel folds. Here we clarified the frequency with which protein folds share the same SSE packing arrangement with other folds, the types of spatial arrangement of SSEs that are frequently observed across different folds, and the diversity of protein folds that share the same spatial arrangement of SSEs with a given fold, using a protein structure alignment program MICAN, which we have been developing. By performing comprehensive structural comparison of SCOP fold representatives, we found that approximately 80% of protein folds share the same spatial arrangement of SSEs with other folds. We also observed that many protein pairs that share the same spatial arrangement of SSEs belong to the different classes, often with an opposing N- to C-terminal direction of the polypeptide chain. The most frequently observed spatial arrangement of SSEs was the 2-layer α/β packing arrangement and it was dispersed among as many as 27% of SCOP fold representatives. These results suggest that the same spatial arrangements of SSEs are adopted by a wide variety of different folds and that the spatial arrangement of SSEs is highly robust against the N- to C-terminal direction of the polypeptide chain. PMID:25243952
What Do the Hitomi Observations Tell Us About the Turbulent Velocities in the Perseus Cluster?
NASA Astrophysics Data System (ADS)
ZuHone, John A.; Miller, Eric D.; Bulbul, Esra; Zhuravleva, Irina
2017-08-01
Recently, the Hitomi X-ray Observatory provided the first-ever direct measurements of Doppler line shifting and broadening from the hot plasma in clusters of galaxies via its observations of the Perseus Cluster. It has been reported that these observations demonstrate that the ICM in Perseus is "quiescent". It is indisputable that the velocities inferred from the measured line shifts and broadening are low, but what do these observations imply about the structure of the velocity field on scales smaller than the Hitomi PSF? We use hydrodynamic simulations of gas motions in a cool-core cluster in combination with synthetic Hitomi observations in order to compare the observed line-of-sight velocities to the 3D velocity structure of the ICM, and assess the impact of Hitomi's spatial resolution and the effects of varying the underlying ICM physics.
Direct Observation of Hot Jupiters and Other Faint Companions with the VLTI
NASA Astrophysics Data System (ADS)
Coudé du Foresto, Vincent
The existence of Jupiter-size planets very close to their parent stars (two examples of which are 51 Peg and τ Boo) creates a challenge for theories of planetary formation and structure. Only a direct measurement of their mass and luminosity (not accessible via the current radial velocity techniques) can help discriminate between the different models that have been proposed for this class of objects.
Collagen production of osteoblasts revealed by ultra-high voltage electron microscopy.
Hosaki-Takamiya, Rumiko; Hashimoto, Mana; Imai, Yuichi; Nishida, Tomoki; Yamada, Naoko; Mori, Hirotaro; Tanaka, Tomoyo; Kawanabe, Noriaki; Yamashiro, Takashi; Kamioka, Hiroshi
2016-09-01
In the bone, collagen fibrils form a lamellar structure called the "twisted plywood-like model." Because of this unique structure, bone can withstand various mechanical stresses. However, the formation of this structure has not been elucidated because of the difficulty of observing the collagen fibril production of the osteoblasts via currently available methods. This is because the formation occurs in the very limited space between the osteoblast layer and bone matrix. In this study, we used ultra-high-voltage electron microscopy (UHVEM) to observe collagen fibril production three-dimensionally. UHVEM has 3-MV acceleration voltage and enables us to use thicker sections. We observed collagen fibrils that were beneath the cell membrane of osteoblasts elongated to the outside of the cell. We also observed that osteoblasts produced collagen fibrils with polarity. By using AVIZO software, we observed collagen fibrils produced by osteoblasts along the contour of the osteoblasts toward the bone matrix area. Immediately after being released from the cell, the fibrils run randomly and sparsely. But as they recede from the osteoblast, the fibrils began to run parallel to the definite direction and became thick, and we observed a periodical stripe at that area. Furthermore, we also observed membrane structures wrapped around filamentous structures inside the osteoblasts. The filamentous structures had densities similar to the collagen fibrils and a columnar form and diameter. Our results suggested that collagen fibrils run parallel and thickly, which may be related to the lateral movement of the osteoblasts. UHVEM is a powerful tool for observing collagen fibril production.
High Strength and Ductility of Additively Manufactured 316L Stainless Steel Explained
NASA Astrophysics Data System (ADS)
Shamsujjoha, Md.; Agnew, Sean R.; Fitz-Gerald, James M.; Moore, William R.; Newman, Tabitha A.
2018-04-01
Structure-property relationships of an additively manufactured 316L stainless steel were explored. A scanning electron microscope and electron backscattered diffraction (EBSD) analysis revealed a fine cellular-dendritic (0.5 to 2 μm) substructure inside large irregularly shaped grains ( 100 μm). The cellular structure grows along the <100> crystallographic directions. However, texture analysis revealed that the main <100> texture component is inclined by 15 deg from the building direction. X-ray diffraction line profile analysis indicated a high dislocation density of 1 × 1015 m-2 in the as-built material, which correlates well with the observed EBSD microstructure and high-yield strength, via the traditional Taylor hardening equation. Significant variations in strain hardening behavior and ductility were observed for the horizontal (HB) and vertical (VB) built samples. Ductility of HB and VB samples measured 49 and 77 pct, respectively. The initial growth texture and subsequent texture evolution during tensile deformation are held responsible for the observed anisotropy. Notably, EBSD analysis of deformed samples showed deformation twins, which predominately form in the grains with <111> aligned parallel to the loading direction. The VB samples showed higher twinning activity, higher strain hardening rates at high strain, and therefore, higher ductility. Analysis of annealed samples revealed that the observed microstructures and properties are thermally stable, with only a moderate decrease in strength and very similar levels of ductility and anisotropy, compared with the as-built condition.
High Strength and Ductility of Additively Manufactured 316L Stainless Steel Explained
NASA Astrophysics Data System (ADS)
Shamsujjoha, Md.; Agnew, Sean R.; Fitz-Gerald, James M.; Moore, William R.; Newman, Tabitha A.
2018-07-01
Structure-property relationships of an additively manufactured 316L stainless steel were explored. A scanning electron microscope and electron backscattered diffraction (EBSD) analysis revealed a fine cellular-dendritic (0.5 to 2 μm) substructure inside large irregularly shaped grains ( 100 μm). The cellular structure grows along the <100> crystallographic directions. However, texture analysis revealed that the main <100> texture component is inclined by 15 deg from the building direction. X-ray diffraction line profile analysis indicated a high dislocation density of 1 × 1015 m-2 in the as-built material, which correlates well with the observed EBSD microstructure and high-yield strength, via the traditional Taylor hardening equation. Significant variations in strain hardening behavior and ductility were observed for the horizontal (HB) and vertical (VB) built samples. Ductility of HB and VB samples measured 49 and 77 pct, respectively. The initial growth texture and subsequent texture evolution during tensile deformation are held responsible for the observed anisotropy. Notably, EBSD analysis of deformed samples showed deformation twins, which predominately form in the grains with <111> aligned parallel to the loading direction. The VB samples showed higher twinning activity, higher strain hardening rates at high strain, and therefore, higher ductility. Analysis of annealed samples revealed that the observed microstructures and properties are thermally stable, with only a moderate decrease in strength and very similar levels of ductility and anisotropy, compared with the as-built condition.
NASA Technical Reports Server (NTRS)
Sunderland, P. B.; Axelbaum, Richard L.; Urban, D. L.
2000-01-01
We have examined the sooting behavior of spherical microgravity diffusion flames burning ethylene at atmospheric pressure in the NASA Glenn 2.2-second drop tower. In a novel application of microgravity, spherical flames allowed convection across the flame to be either from fuel to oxidizer or from oxidizer to fuel. Thus, microgravity flames are uniquely capable of allowing independent variation of convection direction across the flame and stoichiometric mixture fraction, Z(sub st). This allowed us to determine the dominant mechanism responsible for the phenomenon of permanently-blue diffusion flames -- flames that remain blue as strain rate approaches zero. Stoichiometric mixture fraction was varied by changing inert concentrations such that adiabatic flame temperature did not change. At low and high Z(sub st) nitrogen was supplied with the oxidizer and the fuel, respectively. For the present flames, structure (Z(sub st)) was found to have a profound effect on soot production. Soot-free conditions were observed at high Z(sub st) (Z(sub st) = 0.78) and sooting conditions were observed at low Z(sub st) (Z(sub st) = 0.064) regardless of the direction of convection. Convection direction was found to have a lesser impact on soot inception, with formation being suppressed when convection at the flame sheet was directed towards the oxidizer.
Structure of the Jovian Magnetodisk Current Sheet: Initial Galileo Observations
NASA Technical Reports Server (NTRS)
Russell, C. T.; Huddleston, D. E.; Khurana, K. K.; Kivelson, M. G.
2001-01-01
The ten-degree tilt of the Jovian magnetic dipole causes the magnetic equator to move back and forth across Jupiter's rotational equator and tile Galileo orbit that lies therein. Beyond about 24 Jovian radii, the equatorial current sheet thins and tile magnetic structure changes from quasi-dipolar into magnetodisk-like with two regions of nearly radial but antiparallel magnetic field separated by a strong current layer. The magnetic field at the center of the current sheet is very weak in this region. Herein we examine tile current sheet at radial distances from 24 55 Jovian radii. We find that the magnetic structure very much resembles tile structure seen at planetary magnetopause and tail current sheet crossings. Tile magnetic field variation is mainly linear with little rotation of the field direction, At times there is almost no small-scale structure present and the normal component of the magnetic field is almost constant through the current sheet. At other times there are strong small-scale structures present in both the southward and northward directions. This small-scale structure appears to grow with radial distance and may provide the seeds for tile explosive reconnection observed at even greater radial distances oil tile nightside. Beyond about 40 Jovian radii, the thin current sheet also appears to be almost constantly in oscillatory motion with periods of about 10 min. The amplitude of these oscillations also appears to grow with radial distance. The source of these fluctuations may be dynamical events in tile more distant magnetodisk.
Active black holes: Relevant plasma structures, regimes and processes involving all phase space
NASA Astrophysics Data System (ADS)
Coppi, Bruno
2011-03-01
The presented theory is motivated by the growing body of experimental information on the characteristics, connected with relevant spectral, time, and space resolutions, of the radiation emission from objects considered as rotating black holes. In the immediate surroundings of these objects, three plasma regions are identified: an innermost Buffer Region, an intermediate Three-regime Region, and a Structured Peripheral Region. In the last region, a Composite Disk Structure made of a sequence of plasma rings corresponding to the formation of closed magnetic surfaces is considered to be present and to allow intermittent accretion flows along the relevant separatrices. The nonlinear ``Master Equation'' describing composite disk structures is derived and solved in appropriate asymptotic limits. A ring configuration, depending on the state of the plasma at the microscopic level: (i) can be excluded from forming given the strongly nonthermal nature of the electron distribution (in momentum space) within the Three-regime Region allowing the onset of a spiral structure; the observed High Frequency Quasi Periodic Oscillations are associated with these tridimensional structures; (ii) may be allowed to propagate to the outer edge of the Buffer Region where successive rings carrying currents in opposite directions are ejected vertically (in opposite directions) and originate the observed jets; or (iii) penetrates in the Three-regime Region and is dissipated before reaching the outer edge of the Buffer Region. The absence of a coherent composite disk structure guiding accretion in the presence of a significant magnetic field background is suggested to characterize quiescent black holes.
NASA Astrophysics Data System (ADS)
Kataoka, Keisuke; Yasumoto, Tetsuaki; Manabe, Yousuke; Sato, Hiroyasu; Yamano, Akihito; Katagiri, Toshimasa
2013-01-01
An anisotropic tunnel microporous crystal was prepared. Active transportation of anthracene as a guest molecule in the anisotropic tunnels was observed. The direction of anthracene movement implies that the anisotropic tunnel did not work as a flap-check valve. The direction of the movement was consistent with that caused by a Brownian ratchet.An anisotropic tunnel microporous crystal was prepared. Active transportation of anthracene as a guest molecule in the anisotropic tunnels was observed. The direction of anthracene movement implies that the anisotropic tunnel did not work as a flap-check valve. The direction of the movement was consistent with that caused by a Brownian ratchet. Electronic supplementary information (ESI) available. CCDC reference numbers 837539 and 837540. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2nr30880k
Cosmic-ray anisotropy studies with IceCube
NASA Astrophysics Data System (ADS)
McNally, Frank
2014-03-01
The IceCube neutrino observatory detects tens of billions of energetic muons per year produced by cosmic-ray interactions with the atmosphere. The size of this sample has allowed IceCube to observe a significant anisotropy in arrival direction for cosmic rays with median energies between 20 and 400 TeV. This anisotropy is characterized by a large scale structure of per-mille amplitude accompanied by structures with smaller amplitudes and with typical angular sizes between 10° and 20°. IceTop, the surface component of IceCube, has observed a similar anisotropy in the arrival direction distribution of cosmic rays, extending the study to PeV energies. The better energy resolution of IceTop allows for additional studies of the anisotropy, for example a comparison of the energy spectrum in regions of a cosmic-ray excess or deficit to the rest of the sky. We present an update on the cosmic-ray anisotropy observed with IceCube and IceTop and the results of first studies of the energy spectrum at locations of cosmic-ray excess or deficit.
Attentional advantages in video-game experts are not related to perceptual tendencies.
Wong, Nicole H L; Chang, Dorita H F
2018-04-03
Previous studies have suggested that extensive action video gaming may enhance perceptual and attentional capacities. Here, we probed whether attentional differences between video-game experts and non-experts hold when attention is selectively directed at global or local structures. We measured performance on a modified attentional-blink task using hierarchically structured stimuli that consisted of global and local elements. Stimuli carried congruent or incongruent information. In two experiments, we asked observers to direct their attention globally (Experiment 1) or locally (Experiment 2). In each RSVP trial, observers were asked to identify the identity of an initial target (T1), and detect the presence or absence of a second target (T2). Experts showed a markedly attenuated attentional blink, as quantified by higher T2 detection sensitivity, relative to non-experts, in both global and local tasks. Notably, experts and non-experts were comparably affected by stimulus congruency. We speculate that the observed visuo-attentional advantage is unlikely to be related to mere differences perceptual tendencies (i.e., greater global precedence), which has been previously associated with diminished attentional blink.
Experimental verification of the rainbow trapping effect in adiabatic plasmonic gratings
Gan, Qiaoqiang; Gao, Yongkang; Wagner, Kyle; Vezenov, Dmitri; Ding, Yujie J.; Bartoli, Filbert J.
2011-01-01
We report the experimental observation of a trapped rainbow in adiabatically graded metallic gratings, designed to validate theoretical predictions for this unique plasmonic structure. One-dimensional graded nanogratings were fabricated and their surface dispersion properties tailored by varying the grating groove depth, whose dimensions were confirmed by atomic force microscopy. Tunable plasmonic bandgaps were observed experimentally, and direct optical measurements on graded grating structures show that light of different wavelengths in the 500–700-nm region is “trapped” at different positions along the grating, consistent with computer simulations, thus verifying the “rainbow” trapping effect. PMID:21402936
Dependence of the optical conductivity on the uniaxial and biaxial strains in black phosphorene
NASA Astrophysics Data System (ADS)
Yang, C. H.; Zhang, J. Y.; Wang, G. X.; Zhang, C.
2018-06-01
By using the Kubo formula, the optical conductivity of strained black phosphorene was studied. The anisotropic band dispersion gives rise to an orientation dependent optical conductivity. The energy gap can be tuned by the uniaxial and biaxial strains which can be observed from the interband optical conductivity polarized along the armchair (x ) direction. The preferential conducting direction is along the x direction. The dependence of the intraband optical conductivity along the zigzag (y ) direction on the Fermi energy and strain exhibits increasing or decreasing monotonously. However, along the x direction this dependence is complicated which originates from the carriers' inverse-direction movements obtained by two types of the nearest phosphorus atom interactions. The modification of the biaxial strain on the energy structure and optical-absorption property is more effective. The imaginary part of the total optical conductivity (Im σ ) can be negative around the threshold of the interband optical transition by modifying the chemical potential. Away from this frequency region, Im σ exhibits positive value. It can be used in the application of the surface plasmon propagations in multilayer dielectric structures.
Population-level mating patterns and fluctuating asymmetry in swordtail hybrids
NASA Astrophysics Data System (ADS)
Culumber, Zachary W.; Rosenthal, Gil G.
2013-08-01
Morphological symmetry is a correlate of fitness-related traits or even a direct target of mate choice in a variety of taxa. In these taxa, when females discriminate among potential mates, increased selection on males should reduce fluctuating asymmetry (FA). Hybrid populations of the swordtails Xiphophorus birchmanni and Xiphophorus malinche vary from panmictic (unstructured) to highly structured, in which reproductive isolation is maintained among hybrids and parental species. We predicted that FA in flanking vertical bars used in sexual signalling should be lower in structured populations, where non-random mating patterns are observed. FA in vertical bars was markedly lower in structured populations than in parental and unstructured hybrid populations. There was no difference in FA between parentals and hybrids, suggesting that hybridisation does not directly affect FA. Rather, variation in FA likely results from contrasting mating patterns in unstructured and structured populations.
Murphy, Lexa K; Murray, Caitlin B; Compas, Bruce E
2017-01-01
To review research on observed family communication in families with children with chronic illnesses compared with families with healthy, typically developing children, and to integrate findings utilizing a unifying family communication framework. Topical review of studies that have directly observed family communication in pediatric populations and included a typically developing comparison group. Initial findings from 14 studies with diverse approaches to quantifying observed family communication suggest that families with children with chronic illnesses may demonstrate lower levels of warm and structured communication and higher levels of hostile/intrusive and withdrawn communication compared with families with healthy, typically developing children. An integrative framework of family communication may be used in future studies that examine the occurrence, correlates, and mechanisms of family communication in pediatric populations.
Diffusion of phonons through (along and across) the ultrathin crystalline films
NASA Astrophysics Data System (ADS)
Šetrajčić, J. P.; Jaćimovski, S. K.; Vučenović, S. M.
2017-11-01
Instead of usual approach, applying displacement-displacement Green's functions, the momentum-momentum Green's functions will be used to calculate the diffusion tensor. With this type of Green's function we have calculated and analyzed dispersion law in film-structures. A small number of phonon energy levels along the direction of boundary surfaces joint of the film are discrete-ones and in this case standing waves could occur. This is consequence of quantum size effects. These Green's functions enter into Kubo's formula defining diffusion properties of the system and possible heat transfer direction through observed structures. Calculation of the diffusion tensor for phonons in film-structure requires solving of the system of difference equations. Boundary conditions are included into mentioned system through the Hamiltonian of the film-structure. It has been shown that the diagonal elements of the diffusion tensor express discrete behavior of the dispersion law of elementary excitations. More important result is-that they are temperature independent and that their values are much higher comparing with bulk structures. This result favors better heat conduction of the film, but in direction which is perpendicular to boundary film surface. In the same time this significantly favors appearance 2D superconducting surfaces inside the ultra-thin crystal structure, which are parallel to the boundary surface.
Structural peculiarities of the Quadrantid meteor shower
NASA Technical Reports Server (NTRS)
Isamutdinov, Sh. O.; Chebotarev, R. P.
1987-01-01
Systematic radio observations to investigate the Quadrantid meteor shower structure are regularly carried out. They have now been conducted annually in the period of its maximum activity, January 1 to 6, since 1966. The latest results of these investigations are presented, on the basis of 1981 to 1984 data obtained using new equipment with a limiting sensitivity of +7.7 sup m which make it possible to draw some conclusions on the Quadrantids shower structure both for transverse and lengthwise directions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Baghram, Shant; Abolhasani, Ali Akbar; Firouzjahi, Hassan
We study the predictions of anomalous inflationary models on the abundance of structures in large scale structure observations. The anomalous features encoded in primordial curvature perturbation power spectrum are (a): localized feature in momentum space, (b): hemispherical asymmetry and (c): statistical anisotropies. We present a model-independent expression relating the number density of structures to the changes in the matter density variance. Models with localized feature can alleviate the tension between observations and numerical simulations of cold dark matter structures on galactic scales as a possible solution to the missing satellite problem. In models with hemispherical asymmetry we show that themore » abundance of structures becomes asymmetric depending on the direction of observation to sky. In addition, we study the effects of scale-dependent dipole amplitude on the abundance of structures. Using the quasars data and adopting the power-law scaling k{sup n{sub A}-1} for the amplitude of dipole we find the upper bound n{sub A} < 0.6 for the spectral index of the dipole asymmetry. In all cases there is a critical mass scale M{sub c} in which for M M{sub c}) the enhancement in variance induced from anomalous feature decreases (increases) the abundance of dark matter structures in Universe.« less
Modifications to intermittent turbulent structures by sheared flow in LAPD
NASA Astrophysics Data System (ADS)
Rossi, Giovanni; Schaffner, David; Carter, Troy; Guice, Danny; Bengtson, Roger
2012-10-01
Turbulence in the edge of the Large Plasma Device is generally observed to be intermittent with the production of filamentary structures. Density-enhancement events (called ``blobs'') are localized to the region radially outside the edge of the cathode source while density-depletion events (called ``holes'') are localized to the region radially inward. A flow-shear layer is also observed to be localized to this same spatial region. Control over the edge flow and shear in LAPD is now possible using a biasable limiter. Edge intermittency is observed to be strongly affected by variations in the edge flow, with intermittency (as measured by skewness of the fluctuation amplitude PDF) increasing with edge flow (in either direction) and reaching a minimum when spontaneous edge flow is zeroed-out using biasing. This trend is counter to the observed changes in turbulent particle flux, which peaks at low flow/shear. Two-dimensional cross-conditional averaging confirms the blobs to be detached filamentary structures with a clear dipolar potential structure and a geometry also dependent on the magnitude of sheared flow. More detailed measurements are made to connect the occurrence of these blobs to observed flow-driven coherent modes and their contribution to radial particle flux.
Direct /TEM/ observation of the catalytic oxidation of amorphous carbon by Pd particles
NASA Technical Reports Server (NTRS)
Moorhead, R. D.; Poppa, H.; Heinemann, K.
1980-01-01
The catalytic oxidation of amorphous carbon substrates by Pd particles is observed by in situ transmission electron microscopy. Various modes of selective attack of the carbon substrate in the immediate neighborhood of Pd particles are observed, which can be correlated with different degrees of particle mobility. Using amorphous substrates we have been able to demonstrate that the particle-substrate interaction is influenced by the structure of the particle. This has not previously been noted.
MESSENGER Observation of Mercury's Magnetopause: Structure and Dynamics
NASA Technical Reports Server (NTRS)
Slavin, J. A.; Acuna, M. H.; Anderson, B. J.; Baker, D. N.; Benna, M.; Boardsen, S. A.; Gloeckler, G.; Gold, R. E.; Ho, G. C.; Korth, H.;
2008-01-01
MESSENGER'S 14 January 2008 encounter with Mercury has provided new observations of the magnetopause of this small magnetosphere, particularly concerning the effect of the direction of the interplanetary magnetic field (IMF) on the structure and dynamics of this boundary. The IMF was northward immediately prior to and following the passage of the MESSENGER spacecraft through Mercury's magnetosphere. However, several-minute episodes of southward IMF were observed in the magnetosheath during the inbound portion of the encounter. Evidence for reconnection at the dayside magnetopause in the form of well-developed flux transfer events (FTEs) was observed in the magnetosheath following some of these southward-B, intervals. The inbound magnetopause crossing seen in the magnetic field measurements is consistent with a transition from the magnetosheath into the plasma sheet. Immediately following MESSENGER'S entry into the magnetosphere, rotational perturbations in the magnetic field similar to those seen at the Earth in association with large-scale plasma sheet vortices driven by Kelvin-Helmholtz waves along the magnetotail boundary at the Earth were observed. The outbound magnetopause occurred during northward IMF B(sub z) and had the characteristics of a tangential discontinuity. These new observations by MESSENGER may be combined and compared with the magnetopause measurements collected by Mariner 10 to derive new understanding of the response of Mercury's magnetopause to IMF direction and its effect on the rate of solar wind energy and mass input to this small magnetosphere.
Observing Formation of Flux Rope by Tether-cutting Reconnection in the Sun
DOE Office of Scientific and Technical Information (OSTI.GOV)
Xue, Zhike; Yan, Xiaoli; Yang, Liheng
Tether-cutting reconnection is considered as one mechanism for the formation of a flux rope. It has been proposed for more than 30 years; however, so far, direct observations of it are very rare. In this Letter, we present observations of the formation of a flux rope via tether-cutting reconnection in NOAA AR 11967 on 2014 February 2 by combining observations with the New Vacuum Solar Telescope and the Solar Dynamic Observatory . The tether-cutting reconnection occurs between two sets of highly sheared magnetic arcades. Comprehensive observational evidence of the reconnection is as follows: changes of the connections between the arcades,more » brightenings at the reconnection site, hot outflows, formation of a flux rope, slow-rise motion of the flux rope, and flux cancelation. The outflows are along three directions from the reconnection site to the footpoints with the velocities from 24 ± 1 km s{sup −1} to 69 ± 5 km s{sup −1}. Additionally, it is found that the newly formed flux rope connects far footpoints and has a left-handed twisted structure with many fine threads and a concave-up-shape structure in the middle. All the observations are in agreement with the tether-cutting model and provide evidence that tether-cutting reconnection leads to the formation of the flux rope associated with flux shear flow and cancelation.« less
NASA Astrophysics Data System (ADS)
Ebert, R. W.; Allegrini, F.; Bagenal, F.; Bolton, S. J.; Chae, K.; Connerney, J. E. P.; Clark, G. B.; Gladstone, R.; Hue, V.; Kurth, W. S.; Levin, S.; Louarn, P.; Mauk, B.; McComas, D. J.; Paranicas, C.; Saur, J.; Reno, C.; Szalay, J. R.; Thomsen, M. F.; Valek, P. W.; Weidner, S.; Wilson, R. J.
2017-12-01
In addition to the main emissions in the north and south, Jupiter's auroral emissions also include polar, satellite-related, and other features. Here we present observations from Juno's Jovian Auroral Distributions Experiment (JADE) of 0.1 - 100 keV electrons in Jupiter's polar aurora region during the spacecraft's northern and southern polar passes bounding PJ1 (27 August 2016), PJ3 (11 December 11 2016), PJ4 (2 February 2017), PJ5 (27 March 2017), PJ6 (19 May 2017), and PJ7 (11 July 2017). Specifically, we focus on the spatial structure, energy and pitch angle distributions, and energy flux and spectra of these electrons. The observations reveal regions containing magnetic field aligned beams of bi-directional electrons having broad energy distributions interspersed between beams of upward electrons with narrow, peaked energy distributions, regions void of these electrons, and regions dominated by penetrating radiation, with penetrating radiation being most common. The electrons show evidence of acceleration via parallel electric fields (inverted-V structures) and via stochastic processes (bi-directional distributions). The inverted-V structures identified to date were observed from 1.4 - 2.9 RJ and had spatial scales of 100s to 1000s of kilometers along Juno's trajectory. The upward energy flux of the electron distributions was typically greater than the downward energy flux and their contribution to producing Jupiter's polar aurora emissions will be discussed.
About the role of the source terms on the spatial structure of the wave field in hurricanes
NASA Astrophysics Data System (ADS)
Osuna, P.; Esquivel-Trava, B.; Ocampo-Torres, F. J.
2012-04-01
A numerical experiment has been carried out in order to study the structure of the wave field during hurricane conditions. High resolution wind data for a hurricane were obtained by the use of a Holland type asymmetric model. The third generation wind-wave model SWAN has been used in this study. A reference framework for the structure of the wave field in hurricanes is obtained using the NDBC directional buoy database in the Caribbean Sea and the Gulf of Mexico. This observational reference is used to assess the ability of the model to reproduce the complexity of the wave field observed in hurricanes. It is found that the numerical results are in good agreement with the observed wave field in the hurricane: higher waves are in the right forward quadrant of the hurricane, where the spectral shape tends to become uni-modal. More complex spectral shapes are observed in the rear quadrants of the hurricane, where a tendency of the spectra to become multi-modal is observed. As pointed out by other authors, the wave field in the hurricane is dominated by swell propagating at significant angles to the local wind directions, except on a small region between the first and fourth quadrants. A deeper insight on the role of the physics that controls the evolution of the wave field is assessed by the analysis of the effect of the source terms computed by the wave model in the four quadrants of the hurricane. This is a contribution to the project CB-168173, funded by CONACYT.
A structural insight into mechanical strength of graphene-like carbon and carbon nitride networks
NASA Astrophysics Data System (ADS)
Rahaman, Obaidur; Mortazavi, Bohayra; Dianat, Arezoo; Cuniberti, Gianaurelio; Rabczuk, Timon
2017-02-01
Graphene, one of the strongest materials ever discovered, triggered the exploration of many 2D materials in the last decade. However, the successful synthesis of a stable nanomaterial requires a rudimentary understanding of the relationship between its structure and strength. In the present study, we investigate the mechanical properties of eight different carbon-based 2D nanomaterials by performing extensive density functional theory calculations. The considered structures were just recently either experimentally synthesized or theoretically predicted. The corresponding stress-strain curves and elastic moduli are reported. They can be useful in training force field parameters for large scale simulations. A comparative analysis of these results revealed a direct relationship between atomic density per area and elastic modulus. Furthermore, for the networks that have an armchair and a zigzag orientation, we observed that they were more stretchable in the zigzag direction than the armchair direction. A critical analysis of the angular distributions and radial distribution functions suggested that it could be due to the higher ability of the networks to suppress the elongations of the bonds in the zigzag direction by deforming the bond angles. The structural interpretations provided in this work not only improve the general understanding of a 2D material’s strength but also enables us to rationally design them for higher qualities.
Sand transportation and reverse patterns over leeward face of sand dune
NASA Astrophysics Data System (ADS)
Jiang, Hong; Dun, Hongchao; Tong, Ding; Huang, Ning
2017-04-01
Sand saltation has complex interactions with turbulent flow and dune form. Most models of wind-blown sand consider ideal circumstances such as steady wind velocity and a flat surface, and the bulk of data on wind flow and sand transport over an individual dune has focused mostly on the influence of dune shape or inter-dune space on the wind flow, neglecting the effect of morphology on sand saltation, particularly airflow and sand transportation over the leeward slope. Wind flow structures over the leeward slope of sand dunes have a fundamental influence on the organization of sand dunes. In order to understand sand dune dynamics, lee face airflow and sediment transportation should be paid more attention. Previous field observations could not measure turbulent flow structure well because of the limited observation points and the influence of experiment structure on wind field. In addition, the reverse sand particles over leeward face could not be collected by sand trap in field. Numerous field observations could not measure turbulent flow structure because of the limited observation points and the influence of experimental structures on the wind field. In addition, the reverse transport of sand particles over leeward face could not be collected by sand traps in field. Therefore, this paper aims to investigate the turbulent flow structure and sand transport pattern over the leeward slope. A numerical model of sand saltation over slope terrain is constructed, which also considers the coupling effects between air flow and sand particles. The large eddy simulation method is used to model turbulent flow. Sand transport is simulated by tracking the trajectory of each sand particle. The results show that terrain significantly alters the turbulent air flow structure and wind-blown sand movement, especially over the leeward slope. Here, mass flux increases initially and then decreases with height in the reversed flow region in the direction of wind flow, and the mass flux decreases with height in the reversed direction. The height of 0.5 H is the height of vortex core in the reversed flow region. The vortex core is a critical point in the flow region where few particles are transited. In the reversed region, the reversed mass flux of sand particles is 25% of the mass flux in the flow direction. This research may contribute to scientific understanding of the mechanisms of sand motion and wind flow over leeward of dune and it is likely to be significant in desertification control.
Fang, Jing; Nevin, Philip; Kairys, Visvaldas; Venclovas, Česlovas; Engen, John R; Beuning, Penny J
2014-04-08
The relationship between protein sequence, structure, and dynamics has been elusive. Here, we report a comprehensive analysis using an in-solution experimental approach to study how the conservation of tertiary structure correlates with protein dynamics. Hydrogen exchange measurements of eight processivity clamp proteins from different species revealed that, despite highly similar three-dimensional structures, clamp proteins display a wide range of dynamic behavior. Differences were apparent both for structurally similar domains within proteins and for corresponding domains of different proteins. Several of the clamps contained regions that underwent local unfolding with different half-lives. We also observed a conserved pattern of alternating dynamics of the α helices lining the inner pore of the clamps as well as a correlation between dynamics and the number of salt bridges in these α helices. Our observations reveal that tertiary structure and dynamics are not directly correlated and that primary structure plays an important role in dynamics. Copyright © 2014 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Bell, L. D.
1996-01-01
Ballistic-Electron-Emission Microscopy (BEEM) spectroscopy has been performed on Au/Si(111) structures as a function of Au thickness and temperature. At 77 K a direct signature of parallel momentum conservation at the Au/Si interface is observed in the BEEM spectra. The variation in spectral shape with both Au thickness and temperature places restrictions on allowable values of inelastic and elastic mean-free paths in the metal, and also requires the presence of multiple electron passes within the Au layer. An independent indication of multiple reflections is directly observed in the attenuation of BEEM current with Au thickness.
NASA Astrophysics Data System (ADS)
Sugioka, Koji; Hanada, Yasutaka; Midorikawa, Katsumi; Kawano, Hiroyuki; Ishikawa, Ikuko S.; Miyawaki, Atsushi
2011-12-01
We demonstrate to fabricate microfluidic chips integrated with some functional microcomponents such as optical attenuators and optical waveguides by femtosecond laser direct writing for understanding phenomena and functions of microorganisms. Femtosecond laser irradiation followed by annealing and wet etching in dilute hydrofluoric acid solution resulted in fabrication of three-dimensional microfludic structures embedded in a photosensitive glass. The embedded microfludic structures enabled us to easily and efficiently observe Phormidium gliding to the seedling root, which accelerates growth of the vegetable. In addition, integration of optical attenuators and optical waveguides into the microfluidic structures clarified the mechanism of the gliding movement of Phormidium. We termed such integrated microchips nanoaquariums, realizing the highly efficient and functional observation and analysis of various microorganisms.
Numerical investigation of separated nozzle flows
NASA Technical Reports Server (NTRS)
Chen, C. L.; Chakravarthy, S. R.; Hung, C. M.
1994-01-01
A numerical study of axisymmetric overexpanded nozzle is presented. The flow structure of the startup and throttle-down processes are examined. During the impulsive startup process, observed flow features include the Mach disk, separation shock, Mach stem, vortex core, contact surface, slip stream, initial shock front, and shocklet. Also the movement of the Mach disk is not monotonical in the downstream direction. For a range of pressure ratios, hysteresis phenomenon occurs; different solutions were obtained depending on different processes. Three types of flow structures were observed. The location of separation point and the lower end turning point of hysteresis are closely predicted. A high peak of pressure is associated with the nozzle flow reattachment. The reversed vortical structure and affects engine performance.
Phase transition studies of germanium to 1. 25 Mbar
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vohra, Y.K.; Brister, K.E.; Desgreniers, S.
1986-05-05
New phase transitions in Ge were observed by energy-dispersive x-ray diffraction techniques for pressures up to 125 GPa (1.25 Mbar) as follows: the ..beta..-Sn structure to the simple hexagonal (sh) phase at 75 +- 3 GPa and to the double hexagonal close-packed structure (dhcp) at 102 +- 5 GPa. These are the highest pressures for which a crystalline structure change has been directly observed in any material by x-ray diffraction. Total-energy pseudopotential calculations predict 84 +- 10 GPa for the ..beta..-Sn to sh phase transition and 105 +- 21 GPa for sh to hcp (not dhcp) transition. The role ofmore » 3d core electrons in increasing the transformation pressures in Ge, as compared to Si, is emphasized.« less
Sparse Bayesian Inference and the Temperature Structure of the Solar Corona
DOE Office of Scientific and Technical Information (OSTI.GOV)
Warren, Harry P.; Byers, Jeff M.; Crump, Nicholas A.
Measuring the temperature structure of the solar atmosphere is critical to understanding how it is heated to high temperatures. Unfortunately, the temperature of the upper atmosphere cannot be observed directly, but must be inferred from spectrally resolved observations of individual emission lines that span a wide range of temperatures. Such observations are “inverted” to determine the distribution of plasma temperatures along the line of sight. This inversion is ill posed and, in the absence of regularization, tends to produce wildly oscillatory solutions. We introduce the application of sparse Bayesian inference to the problem of inferring the temperature structure of themore » solar corona. Within a Bayesian framework a preference for solutions that utilize a minimum number of basis functions can be encoded into the prior and many ad hoc assumptions can be avoided. We demonstrate the efficacy of the Bayesian approach by considering a test library of 40 assumed temperature distributions.« less
A Springloaded Metal-Ligand Mesocate Allows Access to Trapped Intermediates of Self-Assembly.
Bogie, Paul M; Holloway, Lauren R; Lyon, Yana; Onishi, Nicole C; Beran, Gregory J O; Julian, Ryan R; Hooley, Richard J
2018-04-02
A strained, "springloaded" Fe 2 L 3 iminopyridine mesocate shows highly variable reactivity upon postassembly reaction with competitive diamines. The strained assembly is reactive toward transimination in minutes at ambient temperature and allows observation of kinetically trapped intermediates in the self-assembly pathway. When diamines are used that can only form less favored cage products upon full equilibration, trapped ML 3 fragments with pendant, "hanging" NH 2 groups are selectively formed instead. Slight variations in diamine structure have large effects on the product outcome: less rigid diamines convert the mesocate to more favored self-assembled cage complexes under mild conditions and allow observation of heterocomplex intermediates in the displacement pathway. The mesocate allows control of equilibrium processes and direction of product outcomes via small, iterative changes in added subcomponent structure and provides a method of accessing metal-ligand cage structures not normally observed in multicomponent Fe-iminopyridine self-assembly.
Molecular clouds and the large-scale structure of the galaxy
NASA Technical Reports Server (NTRS)
Thaddeus, Patrick; Stacy, J. Gregory
1990-01-01
The application of molecular radio astronomy to the study of the large-scale structure of the Galaxy is reviewed and the distribution and characteristic properties of the Galactic population of Giant Molecular Clouds (GMCs), derived primarily from analysis of the Columbia CO survey, and their relation to tracers of Population 1 and major spiral features are described. The properties of the local molecular interstellar gas are summarized. The CO observing programs currently underway with the Center for Astrophysics 1.2 m radio telescope are described, with an emphasis on projects relevant to future comparison with high-energy gamma-ray observations. Several areas are discussed in which high-energy gamma-ray observations by the EGRET (Energetic Gamma-Ray Experiment Telescope) experiment aboard the Gamma Ray Observatory will directly complement radio studies of the Milky Way, with the prospect of significant progress on fundamental issues related to the structure and content of the Galaxy.
Rybin, Mikhail V.; Samusev, Kirill B.; Lukashenko, Stanislav Yu.; Kivshar, Yuri S.; Limonov, Mikhail F.
2016-01-01
We study experimentally a fine structure of the optical Laue diffraction from two-dimensional periodic photonic lattices. The periodic photonic lattices with the C4v square symmetry, orthogonal C2v symmetry, and hexagonal C6v symmetry are composed of submicron dielectric elements fabricated by the direct laser writing technique. We observe surprisingly strong optical diffraction from a finite number of elements that provides an excellent tool to determine not only the symmetry but also exact number of particles in the finite-length structure and the sample shape. Using different samples with orthogonal C2v symmetry and varying the lattice spacing, we observe experimentally a transition between the regime of multi-order diffraction, being typical for photonic crystals to the regime where only the zero-order diffraction can be observed, being is a clear fingerprint of dielectric metasurfaces characterized by effective parameters. PMID:27491952
Probing the collimation of pristine post-AGB jets with STIS
NASA Astrophysics Data System (ADS)
Sanchez Contreras, Carmen
2009-07-01
The shaping of planetary and protoplanetary nebulae {PNe and PPNe} is probably the most exciting yet least understood problem in the late evolution of 1-8 solar mass stars. An increasing number of astronomers believe that fast jet-like winds ejected in the PPN phase are responsible for carving out the diverse shapes in the dense envelopes of the Asymptotic Giant Branch {AGB} stars. To date, the properties of these post-AGB jets have not been characterized and, indeed, their launching/collimation mechanism is still subject to controversial debate. This is due to the lack of the direct observations probing the spatio-kinematic structure of post-AGB winds in the stellar vicinity { 10e16cm}, which is only possible with HST+STIS. Recently, STIS observations have allowed us for the first time the DIRECT study of the structure and kinematics of the elusive post-AGB winds in one PPN, He3-1475 {Sanchez Contreras & Sahai 2001}. Those winds have been discovered through H-alpha blue-shifted absorption features in the inner 0.3"-0.7" of the nebula. These STIS observations have revealed an ultra-fast collimated outflow relatively unaffected by the interaction with the AGB wind that is totally hidden in ground-based spectroscopic observations and HST images. The discovery of the pristine ultra-fast { 2300km/s} jet in He3-1475 is the first observational confirmation of the presence of collimated outflows as close as 10e16cm from the central star. Most importantly, the spatio-kinematic structure of the ultra-fast jet clearly rules out hydrodynamical collimation alone and favors magnetic wind collimation. Therefore, STIS observations provide a unique method of probing the structure, kinematics, and collimation mechanism of the elusive post-AGB winds. We now propose similar observations for a sample of bipolar PPNe with ongoing post-AGB ejections in order to investigate the frequency of jets like those in He3-1475 in other PPNe and elucidate their nature and collimation mechanism. The observational characterization of these winds is indispensable for understanding this violent and important phase of post-AGB evolution.
On the spatial coherence of temperature within and above a vineyard under drainage conditions
NASA Astrophysics Data System (ADS)
Everard, K.; Giometto, M. G.; Christen, A.; Oldroyd, H. J.; Parlange, M. B.
2017-12-01
We show that turbulent exchange within vineyards under nighttime drainage conditions is controlled by large-scale coherent structures arising from a mixing-layer type instability at the canopy top, h. A combination of measurements and large-eddy simulations (LESs) are here used to characterize the onset and development of such structures as a function of the approaching wind angle over an organized canopy during drainage flows. Measurements were carried out over a west-facing 7° vineyard slope near Oliver, BC, Canada in the Okanagan Valley between July 5 and July 22, 2016. The vineyard canopy had an average height of h = 2.3 m, with parallel rows oriented in the local downslope direction (i.e. east-west). The set-up consisted of an array of five vertically arranged ultrasonic anemometers at z/h = 0.19, 0.39, 0.65, 1.02, and 2.06, and a 2-D grid of 40 fine-wire thermocouples arranged at the same heights as the ultrasonic anemometer array on 8 separate masts extending in the upslope direction at locations up to x/h = 13.91 from the flux tower. To complement observations, pressure-driven open-channel flow LESs are performed over a regular domain where vegetation is accounted for via a space dependent drag force. The drainage flow regime is emulated via a tuned pressure-gradient forcing, and different approaching wind angles are considered. Linear stability analyses show that the most unstable mode at the canopy top strongly depends on the approaching wind angle. Space-lagged correlations from measurements show that the lifetime of such eddies within the canopy also depends on the approaching wind direction, with longer lifetimes observed when wind angles are directed along the vine-rows. LESs are compared with measured quantities to ensure matching, and then used to investigate in detail the influence of the above-canopy wind vectors on eddy lifetimes. The impact of the observed coherent structures on momentum and heat exchange coefficients are also discussed.
Theodosis, D T; Poulain, D A
1984-01-01
Supraoptic nuclei of lactating rats present a particular anatomical organization that could serve to facilitate the synchronization of neuronal firing observed during suckling-induced reflex milk ejections. Although magnocellular neurones are usually separated by neuropil elements, particularly glial fibers, in lactating rats, numerous neurosecretory soma and dendritic profiles are in direct apposition, without glial interposition. Concomitantly, there is also a higher incidence of presynaptic terminals contacting two neurosecretory elements in the same plane of section ("double" synapses). In the present study, a quantitative ultrastructural analysis was used to trace the evolution of the structural reorganization of the nucleus at different stages of the reproductive cycle. The percentage of neurosecretory soma and dendritic profiles in direct apposition was low two weeks after the beginning of pregnancy, but the day prior to parturition, as during lactation, over 40% of all neurosecretory profiles were directly in contact and involved about 10% of the total neuronal surface membrane measured (a 5-fold increase over the corresponding frequencies recorded in virgin rats at oestrus). The contiguous neuronal membranes and associated intercellular space appeared unmodified, except for the presence of attachment plaques, that also increased in frequency at late gestation and lactation. The incidence of "double" synapses also increased by late gestation, so that at lactation, they bridged 8% of all the recorded neurosecretory somata and dendrites, (as compared to 1% in the virgin rats). Similar changes were observed during a first and second gestation and lactation. The incidence of direct appositions and "double" synapses then diminished gradually after weaning: 2 months after the end of lactation, the ultrastructure of the nucleus resembled that of virgin animals. These observations demonstrate a plasticity in the structural organization of the supraoptic nucleus that appears closely related to changing physiological states of the animal and that involves both neurone-glial relationships and the neurones' synaptic configuration.
Exotic phases of frustrated antiferromagnet LiCu2O2
NASA Astrophysics Data System (ADS)
Bush, A. A.; Büttgen, N.; Gippius, A. A.; Horvatić, M.; Jeong, M.; Kraetschmer, W.; Marchenko, V. I.; Sakhratov, Yu. A.; Svistov, L. E.
2018-02-01
7Li NMR spectra were measured in a magnetic field up to 17 T at temperatures 5-30 K on single crystalline LiCu2O2 . Earlier reported anomalies on magnetization curves correspond to magnetic field values where we observe changes of the NMR spectral shape. For the interpretation of the field and temperature evolutions of our NMR spectra, the magnetic structures were analyzed in the frame of the phenomenological theoretical approach of the Dzyaloshinskii-Landau theory. A set of possible planar and collinear structures was obtained. Most of these structures have an unusual configuration; they are characterized by a two-component order parameter and their magnetic moments vary harmonically not only in direction, but also in size. From the modeling of the observed spectra, a possible scenario of magnetic structure transformations is obtained.
NASA Astrophysics Data System (ADS)
Herique, A.; Ciarletti, V.; Plettemeier, D.; Grygorczuk, J.
2016-12-01
Our knowledge of the internal structure of asteroids entirely relies on inferences from remote sensing observations of the surface and theoretical modeling. Is the body a monolithic piece of rock or a rubble-pile, how high is the porosity? What is the typical size of the constituent blocs? Are these blocs homogeneous or heterogeneous? The body is covered by a regolith whose properties remain largely unknown in term of depth, size distribution and spatial variability. Is it resulting from fine particles re-accretion or from thermal fracturing? After several asteroid orbiting missions, theses crucial and yet basic questions remain open. Direct measurements of asteroid deep interior and regolith structure are needed to better understand the asteroid accretion and dynamical evolution and to provide answers that will directly improve our ability to understand the formation and evolution of the Near Earth Asteroids (NEA), that will allow us to model the mechanisms driving NEA deflection and other risk mitigation techniques. Radars operating at distance from a spacecraft are the only instruments capable of achieving this science objective of characterizing the internal structure and heterogeneity from submetric to global scale for the benefit of science as well as for planetary defense or exploration. The AIM mission will have two complementary radars on-board, operating at different frequencies in order to meet the objectives requirements. The deep interior structure tomography requires a low-frequency radar (LFR) in order to propagate throughout the complete body and characterize the deep interior: this LFR will be a direct heritage of the CONSERT radar designed for the Rosetta mission. Ihe characterization of the first ten meters of the subsurface with a metric resolution to identify layering and to reconnect surface measurements to internal structure will be achieved with a higher frequency radar (HFR). The design of HFR is based on the WISDOM radar developed for the ExoMars mission. Both radars are currently under phase AB1 funded by ESA. We will present the performances of both instruments on realistic environments and their operating modes.
NASA Astrophysics Data System (ADS)
Mohebi, M.; Jamasbi, N.; Liu, Jing
1996-11-01
We developed a computer model to understand the nonequilibrium structures induced in a magnetorheological (MR) fluid by rapidly applying an external magnetic field. MR fluids consist of particles suspended in a liquid where particles interact through dipole moments induced by the external magnetic field. We have simulated these induced structures in both directions, parallel and perpendicular to the field, in the limit of fastest response, by neglecting thermal motion and applying the field instantaneously. Our results show that the process of structure formation starts with particles forming chains aligned with the external field. The chains then coalesce to form columns and wall-like structures (``worms'' as viewed from the top). The complexity of this pattern is found to depend on the concentration of particles and the confinement of the cell in the direction of the external field. These results are consistent with experimental observations [G.A. Flores et al., in Proceedings of the Fifth International Conference on ER Fluids, MR Suspensions, and Associate Technology, University of Sheffield, Sheffield, 1995, edited by W. Bullough (World Scientific, Singapore, 1996), p. 140]. We have also used this model to study the interaction of two chains. The results of this study help in the understanding of the connection between the thickness of the sample and the increased complexity of the observed lateral pattern.
The impact of forest structure and light utilization on carbon cycling in tropical forests
NASA Astrophysics Data System (ADS)
Morton, D. C.; Longo, M.; Leitold, V.; Keller, M. M.
2015-12-01
Light competition is a fundamental organizing principle of forest ecosystems, and interactions between forest structure and light availability provide an important constraint on forest productivity. Tropical forests maintain a dense, multi-layered canopy, based in part on abundant diffuse light reaching the forest understory. Climate-driven changes in light availability, such as more direct illumination during drought conditions, therefore alter the potential productivity of forest ecosystems during such events. Here, we used multi-temporal airborne lidar data over a range of Amazon forest conditions to explore the influence of forest structure on gross primary productivity (GPP). Our analysis combined lidar-based observations of canopy illumination and turnover in the Ecosystem Demography model (ED, version 2.2). The ED model was updated to specifically account for regional differences in canopy and understory illumination using lidar-derived measures of canopy light environments. Model simulations considered the influence of forest structure on GPP over seasonal to decadal time scales, including feedbacks from differential productivity between illuminated and shaded canopy trees on mortality rates and forest composition. Finally, we constructed simple scenarios with varying diffuse and direct illumination to evaluate the potential for novel plant-climate interactions under scenarios of climate change. Collectively, the lidar observations and model simulations underscore the need to account for spatial heterogeneity in the vertical structure of tropical forests to constrain estimates of tropical forest productivity under current and future climate conditions.
Direct time-domain observation of attosecond final-state lifetimes in photoemission from solids
Tao, Z.; Chen, C.; Szilvasi, T.; ...
2016-06-01
Attosecond spectroscopic techniques have made it possible to measure differences in transport times for photoelectrons from localized core levels and delocalized valence bands in solids. Here, we report the application of attosecond pulse trains to directly and unambiguously measure the difference in lifetimes between photoelectrons born into free electron–like states and those excited into unoccupied excited states in the band structure of nickel (111). An enormous increase in lifetime of 212 ± 30 attoseconds occurs when the final state coincides with a short-lived excited state. Moreover, a strong dependence of this lifetime on emission angle is directly related to themore » final-state band dispersion as a function of electron transverse momentum. Our finding underscores the importance of the material band structure in determining photoelectron lifetimes and corresponding electron escape depths.« less
Anisotropic ripple deformation in phosphorene
Kou, Liangzhi; Ma, Yandong; Smith, Sean C.; ...
2015-04-07
Here, two-dimensional materials tend to become crumpled according to the Mermin-Wagner theorem, and the resulting ripple deformation may significantly influence electronic properties as observed in graphene and MoS 2. Here, we unveil by first-principles calculations a new, highly anisotropic ripple pattern in phosphorene, a monolayer black phosphorus, where compression-induced ripple deformation occurs only along the zigzag direction in the strain range up to 10%, but not the armchair direction. This direction-selective ripple deformation mode in phosphorene stems from its puckered structure with coupled hinge-like bonding configurations and the resulting anisotropic Poisson ratio. We also construct an analytical model using classicalmore » elasticity theory for ripple deformation in phosphorene under arbitrary strain. The present results offer new insights into the mechanisms governing the structural and electronic properties of phosphorene crucial to its device applications.« less
Anisotropic ripple deformation in phosphorene
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kou, Liangzhi; Ma, Yandong; Smith, Sean C.
Here, two-dimensional materials tend to become crumpled according to the Mermin-Wagner theorem, and the resulting ripple deformation may significantly influence electronic properties as observed in graphene and MoS 2. Here, we unveil by first-principles calculations a new, highly anisotropic ripple pattern in phosphorene, a monolayer black phosphorus, where compression-induced ripple deformation occurs only along the zigzag direction in the strain range up to 10%, but not the armchair direction. This direction-selective ripple deformation mode in phosphorene stems from its puckered structure with coupled hinge-like bonding configurations and the resulting anisotropic Poisson ratio. We also construct an analytical model using classicalmore » elasticity theory for ripple deformation in phosphorene under arbitrary strain. The present results offer new insights into the mechanisms governing the structural and electronic properties of phosphorene crucial to its device applications.« less
Plasmoids as magnetic flux ropes. [in geomagnetic tail
NASA Technical Reports Server (NTRS)
Moldwin, Mark B.; Hughes, W. J.
1991-01-01
A magnetic flux rope model is developed and used to determine whether the principal axis analysis (PAA) of magnetometer signatures from a single satellite pass is sufficient to obtain the magnetic topology of plasmoids. The model is also used to determine if plasmoid observations are best explained by the flux rope, closed loop, or large-amplitude wave picture. It was found that the principal axis directions is highly dependent on the satellite trajectory through the structure and, therefore, the PAA of magnetometer data from a single satellite pass is insufficient to differentiate between magnetic closed loop and flux rope models. Results also indicate that the flux rope model of plasmoid formation is well suited to unify the observations of various magnetic structures observed by ISEE 3.
Photoluminescence from narrow InAs-AlSb quantum wells
NASA Technical Reports Server (NTRS)
Brar, Berinder; Kroemer, Herbert; Ibbetson, James; English, John H.
1993-01-01
We report on photoluminescence spectra from narrow InAs-AlSb quantum wells. Strong, clearly resolved peaks for well widths from 2 to 8 monolayers were observed. Transmission electron micrographs show direct evidence for the structural quality of the quantum well structures. The transition energies of the narrowest wells suggest a strong influence of the AlSb X-barrier on the electronic states in the conduction band.
Dynamic unmagnetized plasma in the diamagnetic cavity around comet 67P/Churyumov-Gerasimenko
NASA Astrophysics Data System (ADS)
Hajra, Rajkumar; Henri, Pierre; Vallières, Xavier; Moré, Jerome; Gilet, Nicolas; Wattieaux, Gaetan; Goetz, Charlotte; Richter, Ingo; Tsurutani, Bruce T.; Gunell, Herbert; Nilsson, Hans; Eriksson, Anders I.; Nemeth, Zoltan; Burch, James L.; Rubin, Martin
2018-04-01
The Rosetta orbiter witnessed several hundred diamagnetic cavity crossings (unmagnetized regions) around comet 67P/Churyumov-Gerasimenko during its two year survey of the comet. The characteristics of the plasma environment inside these diamagnetic regions are studied using in situ measurements by the Rosetta Plasma Consortium instruments. Although the unmagnetized plasma density has been observed to exhibit little dynamics compared to the very dynamical magnetized cometary plasma, we detected several localized dynamic plasma structures inside those diamagnetic regions. These plasma structures are not related to the direct ionization of local cometary neutrals. The structures are found to be steepened, asymmetric plasma enhancements with typical rising-to-descending slope ratio of ˜2.8 (±1.9), skewness ˜0.43 (±0.36), mean duration of ˜2.7 (±0.9) min and relative density variation ΔN/N of ˜0.5 (±0.2), observed close to the electron exobase. Similar steepened plasma density enhancements were detected at the magnetized boundaries of the diamagnetic cavity as well as outside the diamagnetic region. The plausible scalelength and propagation direction of the structures are estimated from simple plasma dynamics considerations. It is suggested that they are large-scale unmagnetized plasma enhancements, transmitted from the very dynamical outer magnetized region to the inner magnetic field-free cavity region.
NASA Astrophysics Data System (ADS)
Yang, Ding-Shyue; He, Xing; Wu, Chengyi
Due to their large scattering cross sections with matter, electrons are suitable for contactless probing of solid-supported surface assemblies, especially in a reflection geometry. Direct visualization of assembly structures through electron diffraction further enables studies of ultrafast structural dynamics through the pump-probe scheme as well as discoveries of hidden phase changes in equilibrium that have been obscure in spectroscopic measurements. In this presentation, we report our first observation of unique two-stage transformations of interfacial methanol on smooth hydrophobic surfaces. The finding may reconcile the inconsistent previous reports of the crystallization temperature using various indirect methods. Dynamically, energy transfer across a solid-molecule interface following photoexcitation of the substrate is found to be highly dependent on the structure of interfacial methanol. If it is only 2-dimensionally ordered, as the film thickness increases, a prolonged time in the decrease of diffraction intensity is seen, signifying an inefficient vibrational coupling in the surface normal direction. Implications of the dynamics results and an outlook of interfacial studies using time-resolved and averaged electron diffraction will be discussed. We gratefully acknowledge the support from the R. A. Welch Foundation (Grant No. E-1860), the Donors of the American Chemical Society Petroleum Research Fund (ACS-PRF), and the University of Houston.
Development of structure in natural silk spinning and poly(vinyl alcohol) hydrogel formation
NASA Astrophysics Data System (ADS)
Willcox, Patricia Jeanene
This research involves the characterization of structure and structure formation in aqueous systems. Particularly, these studies investigate the effect of various processing variables on the structure formation that occurs upon conversion from aqueous solution to fiber or hydrogel. The two processes studied include natural silk fiber spinning and physical gelation of poly(vinyl alcohol), PVOH, in water. The techniques employed combine cryogenic technology for sample preparation and direct observation by transmission electron microscopy with electron diffraction, atomic force microscopy, optical rheometry, X-ray scattering and optical microscopy. In order to explore the full range of structure formation in natural silk spinning, studies are conducted in vivo and in vitro. In vivo structural investigations are accomplished through the cryogenic quenching and subsequent microtoming of live silk-spinning animals, Nephila clavipes (spider) and Bombyx mori (silkworm). Observations made using transmission electron microscopy, electron diffraction and atomic force microscopy indicate a cholesteric liquid crystalline mesophase of aqueous silk fibroin in both species. The mechanism of structure formation in solution is studied in vitro using optical rheometry on aqueous solutions made from regenerated Bombyx mori cocoon silk. Concentrated solutions exhibit birefringence under flow, with a wormlike conformation of the silk molecules in concentrated salt solution. Changes in salt concentration and pH of the aqueous silk solutions result in differing degrees of alignment and aggregation. These results suggest that structural control in the natural silk spinning process is accomplished by chemical manipulation of the electrostatic interactions and hydrogen bonding between chains. Application of cryogenic methods in transmission electron microscopy also provides a unique look at hydration-dependent structures in gels of poly(vinyl alcohol) produced by freeze-thaw processing. Morphologies ranging from circular pores to fibrillar networks are observed in gels formed from aqueous PVOH solutions subjected to cycles of freezing and thawing. These morphologies can be directly associated with the progressive nature of the mechanism of gelation as it proceeds from liquid-liquid phase separation to crystallization with increased cycling. A comparison of the structures produced by cycling and by aging suggests that there is a similarity in structural changes, but a superposition of the effects of cycling and aging is not possible.
Generalised Sandpile Dynamics on Artificial and Real-World Directed Networks
Zachariou, Nicky; Expert, Paul; Takayasu, Misako; Christensen, Kim
2015-01-01
The main finding of this paper is a novel avalanche-size exponent τ ≈ 1.87 when the generalised sandpile dynamics evolves on the real-world Japanese inter-firm network. The topology of this network is non-layered and directed, displaying the typical bow tie structure found in real-world directed networks, with cycles and triangles. We show that one can move from a strictly layered regular lattice to a more fluid structure of the inter-firm network in a few simple steps. Relaxing the regular lattice structure by introducing an interlayer distribution for the interactions, forces the scaling exponent of the avalanche-size probability density function τ out of the two-dimensional directed sandpile universality class τ = 4/3, into the mean field universality class τ = 3/2. Numerical investigation shows that these two classes are the only that exist on the directed sandpile, regardless of the underlying topology, as long as it is strictly layered. Randomly adding a small proportion of links connecting non adjacent layers in an otherwise layered network takes the system out of the mean field regime to produce non-trivial avalanche-size probability density function. Although these do not display proper scaling, they closely reproduce the behaviour observed on the Japanese inter-firm network. PMID:26606143
Generalised Sandpile Dynamics on Artificial and Real-World Directed Networks.
Zachariou, Nicky; Expert, Paul; Takayasu, Misako; Christensen, Kim
2015-01-01
The main finding of this paper is a novel avalanche-size exponent τ ≈ 1.87 when the generalised sandpile dynamics evolves on the real-world Japanese inter-firm network. The topology of this network is non-layered and directed, displaying the typical bow tie structure found in real-world directed networks, with cycles and triangles. We show that one can move from a strictly layered regular lattice to a more fluid structure of the inter-firm network in a few simple steps. Relaxing the regular lattice structure by introducing an interlayer distribution for the interactions, forces the scaling exponent of the avalanche-size probability density function τ out of the two-dimensional directed sandpile universality class τ = 4/3, into the mean field universality class τ = 3/2. Numerical investigation shows that these two classes are the only that exist on the directed sandpile, regardless of the underlying topology, as long as it is strictly layered. Randomly adding a small proportion of links connecting non adjacent layers in an otherwise layered network takes the system out of the mean field regime to produce non-trivial avalanche-size probability density function. Although these do not display proper scaling, they closely reproduce the behaviour observed on the Japanese inter-firm network.
Lidar observation of marine mixed layer
NASA Technical Reports Server (NTRS)
Yamagishi, Susumu; Yamanouchi, Hiroshi; Tsuchiya, Masayuki
1992-01-01
Marine mixed layer is known to play an important role in the transportation of pollution exiting ship funnels. The application of a diffusion model is critically dependent upon a reliable estimate of a lid. However, the processes that form lids are not well understood, though considerable progress toward marine boundary layer has been achieved. This report describes observations of the marine mixed layer from the course Ise-wan to Nii-jima with the intention of gaining a better understanding of their structure by a shipboard lidar. These observations were made in the summer of 1991. One interesting feature of the observations was that the multiple layers of aerosols, which is rarely numerically modeled, was encountered. No attempt is yet made to present a systematic analysis of all the data collected. Instead we focus on observations that seem to be directly relevant to the structure of the mixed layer.
AFM Structural Characterization of Drinking Water Biofilm under Physiological Conditions
Due to the complexity of mixed culture drinking water biofilm, direct visual observation under in situ conditions has been challenging. In this study, atomic force microscopy (AFM) revealed the three dimensional morphology and arrangement of drinking water relevant biofilm in air...
NASA Astrophysics Data System (ADS)
Chu, Xu; Weigand, Bernhard; Vaikuntanathan, Visakh
2018-06-01
Microscopic analysis of turbulence topology in a regular porous medium is presented with a series of direct numerical simulation. The regular porous media are comprised of square cylinders in a staggered array. Triply periodic boundary conditions enable efficient investigations in a representative elementary volume. Three flow patterns—channel with sudden contraction, impinging surface, and wake—are observed and studied quantitatively in contrast to the qualitative experimental studies reported in the literature. Among these, shear layers in the channel show the highest turbulence intensity due to a favorable pressure gradient and shed due to an adverse pressure gradient downstream. The turbulent energy budget indicates a strong production rate after the flow contraction and a strong dissipation on both shear and impinging walls. Energy spectra and pre-multiplied spectra detect large scale energetic structures in the shear layer and a breakup of scales in the impinging layer. However, these large scale structures break into less energetic small structures at high Reynolds number conditions. This suggests an absence of coherent structures in densely packed porous media at high Reynolds numbers. Anisotropy analysis with a barycentric map shows that the turbulence in porous media is highly isotropic in the macro-scale, which is not the case in the micro-scale. In the end, proper orthogonal decomposition is employed to distinguish the energy-conserving structures. The results support the pore scale prevalence hypothesis. However, energetic coherent structures are observed in the case with sparsely packed porous media.
Interactions between C and Cu atoms in single-layer graphene: direct observation and modelling.
Kano, Emi; Hashimoto, Ayako; Kaneko, Tomoaki; Tajima, Nobuo; Ohno, Takahisa; Takeguchi, Masaki
2016-01-07
Metal doping into the graphene lattice has been studied recently to develop novel nanoelectronic devices and to gain an understanding of the catalytic activities of metals in nanocarbon structures. Here we report the direct observation of interactions between Cu atoms and single-layer graphene by transmission electron microscopy. We document stable configurations of Cu atoms in the graphene sheet and unique transformations of graphene promoted by Cu atoms. First-principles calculations based on density functional theory reveal a reduction of energy barrier that caused rotation of C-C bonds near Cu atoms. We discuss two driving forces, electron irradiation and in situ heating, and conclude that the observed transformations were mainly promoted by electron irradiation. Our results suggest that individual Cu atoms can promote reconstruction of single-layer graphene.
NASA Astrophysics Data System (ADS)
Pischiutta, Marta; Cianfarra, Paola; Salvini, Francesco; Cara, Fabrizio; Vannoli, Paola
2018-03-01
Directional site effects observed at seismological stations on pronounced relief are analyzed. We investigate the ground motion properties calculating horizontal-to-vertical spectral ratios and horizontal polarization of both ambient vibrations and earthquake records using broadband seismograms of the Italian Seismic Network. We find that a subset of 47 stations with pronounced relief, results in a significant (>2) directional amplification of the horizontal component, with a well defined, site-specific direction of motion. However, the horizontal spectral response of sites is not uniform, varying from an isolated (resonant) frequency peak to a broadband amplification, interesting frequency bands as large as 1-10 Hz in many cases. Using the 47 selected stations, we have tried to establish a relation between directional amplification and topography geometry in a 2D-vision, when applicable, through a morphological analysis of the Digital Elevation Model using Geographic Information Systems. The procedure computes the parameters that characterize the geometry of topographic irregularities (size and slope), in combination with a principal component analysis that automatically yields the orientation of the elongated ridges. In seeking a relation between directional amplification and the surface morphology, we have found that it is impossible to fit the variety of observations with a resonant topography model as well as to identify common features in the ground motion behavior for stations with similar topography typologies. We conclude that, rather than the shape of the topography, local structural complexities and details of the near-surface structure must play a predominant role in controlling ground motion properties at sites with pronounced relief.
NASA Astrophysics Data System (ADS)
Pischiutta, Marta; Cianfarra, Paola; Salvini, Francesco; Cara, Fabrizio; Vannoli, Paola
2018-07-01
Directional site effects observed at seismological stations on pronounced relief are analysed. We investigate the ground motion properties calculating horizontal-to-vertical spectral ratios and horizontal polarization of both ambient vibrations and earthquake records using broad-band seismograms of the Italian seismic network. We find that a subset of 47 stations with pronounced relief results in a significant (>2) directional amplification of the horizontal component, with a well-defined, site-specific direction of motion. However, the horizontal spectral response of sites is not uniform, varying from an isolated (resonant) frequency peak to a broad-band amplification, interesting frequency bands as large as 1-10 Hz in many cases. Using 47 selected stations, we have tried to establish a relation between directional amplification and topography geometry in a 2-D vision, when applicable, through a morphological analysis of the digital elevation model using geographic information systems. The procedure computes the parameters that characterize the geometry of topographic irregularities (size and slope), in combination with a principal component analysis that automatically yields the orientation of the elongated ridges. In seeking a relation between directional amplification and the surface morphology, we have found that it is impossible to fit the variety of observations with a resonant topography model as well as to identify common features in the ground motion behaviour for stations with similar topography typologies. We conclude that, rather than the shape of the topography, local structural complexities and details of the near-surface structure must play a predominant role in controlling ground motion properties at sites with pronounced relief.
Feola, Andrew; Pal, Siladitya; Moalli, Pamela; Maiti, Spandan; Abramowitch, Steven
2014-01-01
Synthetic polypropylene meshes were designed to restore pelvic organ support for women suffering from pelvic organ prolapse; however, the FDA released two notifications regarding the potential complications associated with mesh implantation. Our aim was to characterize the structural properties of Restorelle and UltraPro subjected to uniaxial tension along perpendicular directions, and then model the tensile behavior of these meshes utilizing a co-rotational finite element model, with an imbedded linear or fiber-recruitment local stress-strain relationship. Both meshes exhibited highly nonlinear stress-strain behavior; Restorelle had no significant differences between the two perpendicular directions, while UltraPro had a 93% difference in the low (initial) stiffness (p=0.009) between loading directions. Our model predicted that early alignment of the mesh segments in the loading direction and subsequent stretching could explain the observed nonlinear tensile behavior. However, a nonlinear stress-strain response in the stretching regime, that may be inherent to the mesh segment, was required to better capture experimental results. Utilizing a nonlinear fiber recruitment model with two parameters A and B, we observed improved agreement between the simulations and the experimental results. An inverse analysis found A=120 MPa and B=1.75 for Restorelle (RMSE=0.36). This approach yielded A=30 MPa and B=3.5 for UltraPro along one direction (RMSE=0.652), while the perpendicular orientation resulted in A=130 MPa and B=4.75 (RMSE=4.36). From the uniaxial protocol, Restorelle was found to have little variance in structural properties along these two perpendicular directions; however, UltraPro was found to behave anisotropically. PMID:25011619
Guan, Zhe; Cao, Baobao; Yang, Yang; Jiang, Youfei; Li, Deyu; Xu, Terry T
2014-01-15
The physical properties of nanostructures strongly depend on their structures, and planar defects in particular could significantly affect the behavior of the nanowires. In this work, planar defects (twins or stacking faults) in boron carbide nanowires are extensively studied by transmission electron microscopy (TEM). Results show that these defects can easily be invisible, i.e., no presence of characteristic defect features like modulated contrast in high-resolution TEM images and streaks in diffraction patterns. The simplified reason of this invisibility is that the viewing direction during TEM examination is not parallel to the (001)-type planar defects. Due to the unique rhombohedral structure of boron carbide, planar defects are only distinctive when the viewing direction is along the axial or short diagonal directions ([100], [010], or 1¯10) within the (001) plane (in-zone condition). However, in most cases, these three characteristic directions are not parallel to the viewing direction when boron carbide nanowires are randomly dispersed on TEM grids. To identify fault orientations (transverse faults or axial faults) of those nanowires whose planar defects are not revealed by TEM, a new approach is developed based on the geometrical analysis between the projected preferred growth direction of a nanowire and specific diffraction spots from diffraction patterns recorded along the axial or short diagonal directions out of the (001) plane (off-zone condition). The approach greatly alleviates tedious TEM examination of the nanowire and helps to establish the reliable structure-property relations. Our study calls attention to researchers to be extremely careful when studying nanowires with potential planar defects by TEM. Understanding the true nature of planar defects is essential in tuning the properties of these nanostructures through manipulating their structures.
Ingham, Gerard; Fry, Jennifer; Morgan, Simon; Ward, Bernadette
2015-12-10
Workplace-based formative assessments using consultation observation are currently conducted during the Australian general practice training program. Assessment reliability is improved by using multiple assessment methods. The aim of this study was to explore experiences of general practice medical educator assessors and registrars (trainees) when adding random case analysis to direct observation (ARCADO) during formative workplace-based assessments. A sample of general practice medical educators and matched registrars were recruited. Following the ARCADO workplace assessment, semi-structured qualitative interviews were conducted. The data was analysed thematically. Ten registrars and eight medical educators participated. Four major themes emerged - formative versus summative assessment; strengths (acceptability, flexibility, time efficiency, complementarity and authenticity); weaknesses (reduced observation and integrity risks); and contextual factors (variation in assessment content, assessment timing, registrar-medical educator relationship, medical educator's approach and registrar ability). ARCADO is a well-accepted workplace-based formative assessment perceived by registrars and assessors to be valid and flexible. The use of ARCADO enabled complementary insights that would not have been achieved with direct observation alone. Whilst there are some contextual factors to be considered in its implementation, ARCADO appears to have utility as formative assessment and, subject to further evaluation, high-stakes assessment.
NASA Astrophysics Data System (ADS)
Anosova, Joanna P.
2017-06-01
On 14 Sept, 2015 The LIGO reported the first direct detection of gravitational waves and the first direct observation of a binary black hole. These observations demonstrate the existence of binary black holes in stellar systems predicted by Einstein in his general theory of relativity a century earlier.A lot of violent and complicated phenomena take place on different scales in the Universe. Many of them may be caused by multiple centers of gravitational attraction: planetary rings, accretion discs of various scales, peculiar structures of single galaxies and interacting galaxies. In this work, we show that various features of celestial objects can be understood by assuming the existence of two dominant centers of gravity in stellar systems.We study numerically the dynamical evolution of models with the central super-massive binary black holes and extended shells with numerous low-mass particles inside and around the orbits of binaries. These particles could be star clusters or gas and dust complexes. We consider several tens of thousands of initial conditions for the general three-body problem and compile them. We studied the dynamical evolution of all spherical shells together and separately. Our method permits us to study the individual trajectories of particles, their close double and triple approaches, and inspect the time-depending structures in the models. Multiple runs of the models allow us to classify the numerous strong triple interactions of the binary components with low-mass particles; frequently, the "gravitational slingshot" effect occurs in the center of systems. Such strong interactions of bodies are results in various structures with "dumb-bell" bars, close and open spirals, different types of flows, jets etc. These structures are often very similar the observed structures of galaxies.We found some combinations of the initial conditions and model parameters that produce at some time similar structures as that found in the galaxies Arp 5, 87, 214, 240, and NGC 4027, 6946. Our Figures show results of such comparison and the past and future evolution of our models.
Direct observation of multiple rotational stacking faults coexisting in freestanding bilayer MoS2.
Li, Zuocheng; Yan, Xingxu; Tang, Zhenkun; Huo, Ziyang; Li, Guoliang; Jiao, Liying; Liu, Li-Min; Zhang, Miao; Luo, Jun; Zhu, Jing
2017-08-16
Electronic properties of two-dimensional (2D) MoS 2 semiconductors can be modulated by introducing specific defects. One important type of defect in 2D layered materials is known as rotational stacking fault (RSF), but the coexistence of multiple RSFs with different rotational angles was not directly observed in freestanding 2D MoS 2 before. In this report, we demonstrate the coexistence of three RSFs with three different rotational angles in a freestanding bilayer MoS 2 sheet as directly observed using an aberration-corrected transmission electron microscope (TEM). Our analyses show that these RSFs originate from cracks and dislocations within the bilayer MoS 2 . First-principles calculations indicate that RSFs with different rotational angles change the electronic structures of bilayer MoS 2 and produce two new symmetries in their bandgaps and offset crystal momentums. Therefore, employing RSFs and their coexistence is a promising route in defect engineering of MoS 2 to fabricate suitable devices for electronics, optoelectronics, and energy conversion.
De Campeneere, S; Fiems, L O; De Boever, J L; Vanacker, J M; De Brabander, D L
2002-02-01
The critical roughage part (CRP) of 2 diet types was determined in a cross-over design with 6 double-muscled and 6 normally conformed Belgian Blue bulls fitted with rumen cannulae. The roughage:concentrate ratio was lowered weekly until signs of a lack of physical structure were observed. For diet 1, consisting of maize silage and concentrates, the initial proportion of maize silage was 25% of DM but it decreased weekly with 5% units of DM. For the second diet, consisting of wheat straw and concentrate, 12% straw (DM basis) was provided during the first week and thereafter the proportion of straw decreased weekly with 3% units of DM. Several directly observable parameters (rumen pH, feed intake, bloat, faecal consistency) were evaluated weekly for each bull. Apart from these direct indicators of acidosis, also other parameters, whose results were only available after the end of the trial, were determined (volatile fatty acid profile, lactic acid concentration, chewing time). The roughage part between the part fed when signs of a lack of physical structure was first observed and the part that was fed the week before, was considered as the CRP. Most animals showed no acute signs of clinical acidosis (directly observable parameters) and finished the trial on a 100% concentrate diet. However, in sacco rumen DM-degradabilities of maize silage, grass silage and wheat grain was depressed considerably when low roughage diets were fed. Based on all observed parameters, the mean CRP was calculated to be 14.7% for diet 1 and 8.1% for diet 2. The beef type (double-muscled or not) had no influence on the CRP.
Structural, optical and Carrier dynamics of self-assembled InGaN nanocolumns on Si(111)
NASA Astrophysics Data System (ADS)
Kumar, Praveen; Devi, Pooja; Soto Rodriguez, P. E. D.; Jain, Rishabh; Jaggi, Neena; Sinha, R. K.; Kumar, Mahesh
2018-05-01
We investigated the morphological, structural, optical, electrical and carrier relaxation dynamic changes on the self-assembled grown InGaN nanocolumns (NCs) directly on p-Si(111) substrate at two different substrate temperature, namely 580 °C (A) and 500 °C (B). The emission wavelength of comparably low temperature (LT) grown NCs was red-shifted from 3.2eV to 2.4eV. First observations on the charge carrier dynamics of these directly grown NCs show comparable broad excited state absorption (ESA) for LT gown NCs, which manifest bi-exponential decay due to the radiative defects generated during the coalescence of these NCs.
Solid iron-hydrogen alloys under high pressure by first principles
NASA Astrophysics Data System (ADS)
Umemoto, K.; Hirose, K.
2016-12-01
Hydrogen and iron are two of major constituents of the Earth and planetary interiors. The crystal structure of solid FeHx is one of the most fundamental information in order to understand properties of planetary cores. It is well known that FeH takes closed-packed structures: dhcp, hcp, and fcc. Recently, hydrogen-rich phases, FeH2 and FeH3, were experimentally synthesized [1]. Although a tetragonal structure of FeH2 was proposed, it could not explain experimental observations, energetic stability and compression curve. Here we propose a new crystal structure of FeH2. The symmetry of the new structure is completely identical to that in originally proposed one, but the hydrogen sublattice which cannot be directly determined by XRD experiments is different. It will be demonstrated by first principles that the new structure can be fully consistent with experimental observations. [1] C. M. Pépin, A. Dewaele, G. Geneste, P. Loubeyre, and M. Mezouar, Phys. Rev. Lett. 113, 265504 (2014).
Influence of hydrostatic pressure on the built-in electric field in ZnO/ZnMgO quantum wells
DOE Office of Scientific and Technical Information (OSTI.GOV)
Teisseyre, Henryk, E-mail: teiss@ifpan.edu.pl; Institute of High Pressure, Polish Academy of Sciences, Sokołowska 29/37, 01-142 Warsaw; Kaminska, Agata
We used high hydrostatic pressure to perform photoluminescence measurements on polar ZnO/ZnMgO quantum well structures. Our structure oriented along the c-direction (polar direction) was grown by plasma-assisted molecular beam epitaxy on a-plane sapphire. Due to the intrinsic electric field, which exists in polar wurtzite structure at ambient pressure, we observed a red shift of the emission related to the quantum-confined Stark effect. In the high hydrostatic pressure experiment, we observed a strong decrease of the quantum well pressure coefficients with increased thickness of the quantum wells. Generally, a narrower quantum well gave a higher pressure coefficient, closer to the band-gapmore » pressure coefficient of bulk material 20 meV/GPa for ZnO, while for wider quantum wells it is much lower. We observed a pressure coefficient of 19.4 meV/GPa for a 1.5 nm quantum well, while for an 8 nm quantum well the pressure coefficient was equal to 8.9 meV/GPa only. This is explained by taking into account the pressure-induced increase of the strain in our structure. The strain was calculated taking in to account that in-plane strain is not equal (due to fact that we used a-plane sapphire as a substrate) and the potential distribution in the structure was calculated self-consistently. The pressure induced increase of the built-in electric field is the same for all thicknesses of quantum wells, but becomes more pronounced for thicker quantum wells due to the quantum confined Stark effect lowering the pressure coefficients.« less
NASA Astrophysics Data System (ADS)
Mairota, Paola; Cafarelli, Barbara; Labadessa, Rocco; Lovergine, Francesco P.; Tarantino, Cristina; Nagendra, Harini; Didham, Raphael K.
2015-02-01
Modelling the empirical relationships between habitat quality and species distribution patterns is the first step to understanding human impacts on biodiversity. It is important to build on this understanding to develop a broader conceptual appreciation of the influence of surrounding landscape structure on local habitat quality, across multiple spatial scales. Traditional models which report that 'habitat amount' in the landscape is sufficient to explain patterns of biodiversity, irrespective of habitat configuration or spatial variation in habitat quality at edges, implicitly treat each unit of habitat as interchangeable and ignore the high degree of interdependence between spatial components of land-use change. Here, we test the contrasting hypothesis, that local habitat units are not interchangeable in their habitat attributes, but are instead dependent on variation in surrounding habitat structure at both patch- and landscape levels. As the statistical approaches needed to implement such hierarchical causal models are observation-intensive, we utilise very high resolution (VHR) Earth Observation (EO) images to rapidly generate fine-grained measures of habitat patch internal heterogeneities over large spatial extents. We use linear mixed-effects models to test whether these remotely-sensed proxies for habitat quality were influenced by surrounding patch or landscape structure. The results demonstrate the significant influence of surrounding patch and landscape context on local habitat quality. They further indicate that such an influence can be direct, when a landscape variable alone influences the habitat structure variable, and/or indirect when the landscape and patch attributes have a conjoined effect on the response variable. We conclude that a substantial degree of interaction among spatial configuration effects is likely to be the norm in determining the ecological consequences of habitat fragmentation, thus corroborating the notion of the spatial context dependence of habitat quality.
THE VERTICAL X-SHAPED STRUCTURE IN THE MILKY WAY: EVIDENCE FROM A SIMPLE BOXY BULGE MODEL
DOE Office of Scientific and Technical Information (OSTI.GOV)
Li Zhaoyu; Shen Juntai, E-mail: jshen@shao.ac.cn
2012-09-20
A vertical X-shaped structure in the Galactic bulge was recently reported. Here, we present evidence of a similar X-shaped structure in the Shen et al. 2010 bar/boxy bulge model that simultaneously matches the stellar kinematics successfully. The X-shaped structure is found in the central region of our bar/boxy bulge model and is qualitatively consistent with the observed one in many aspects. End-to-end separations of the X-shaped structure in the radial and vertical directions are roughly 3 kpc and 1.8 kpc, respectively. The X-shaped structure contains about 7% of light in the boxy bulge region, but it is significant enough tomore » be identified in observations. An X-shaped structure naturally arises in the formation of bar/boxy bulges and is mainly associated with orbits trapped around the vertically extended x{sub 1} family. Like the bar in our model, the X-shaped structure tilts away from the Sun-Galactic center line by 20 Degree-Sign . The X-shaped structure becomes increasingly symmetric about the disk plane, so the observed symmetry may indicate that it formed at least a few billion years ago. The existence of the vertical X-shaped structure suggests that the formation of the Milky Way bulge is shaped mainly by internal disk dynamical instabilities.« less
Andrew R. Meier; Mike R. Saunders
2014-01-01
Compositional and structural changes in response to silvicultural treatments in forest stands are well documented (e.g., Saunders and Wagner 2008), but the stochastic nature of natural disturbance events often precludes direct observation of their impacts on stand dynamics. Though the current dominance of oak-hickory forest types in the Central Hardwoods Forest region...
High-resolution electron microscopy and its applications.
Li, F H
1987-12-01
A review of research on high-resolution electron microscopy (HREM) carried out at the Institute of Physics, the Chinese Academy of Sciences, is presented. Apart from the direct observation of crystal and quasicrystal defects for some alloys, oxides, minerals, etc., and the structure determination for some minute crystals, an approximate image-contrast theory named pseudo-weak-phase object approximation (PWPOA), which shows the image contrast change with crystal thickness, is described. Within the framework of PWPOA, the image contrast of lithium ions in the crystal of R-Li2Ti3O7 has been observed. The usefulness of diffraction analysis techniques such as the direct method and Patterson method in HREM is discussed. Image deconvolution and resolution enhancement for weak-phase objects by use of the direct method are illustrated. In addition, preliminary results of image restoration for thick crystals are given.
ZnO-nanorods/graphene heterostructure: a direct electron transfer glucose biosensor
NASA Astrophysics Data System (ADS)
Zhao, Yu; Li, Wenbo; Pan, Lijia; Zhai, Dongyuan; Wang, Yu; Li, Lanlan; Cheng, Wen; Yin, Wei; Wang, Xinran; Xu, Jian-Bin; Shi, Yi
2016-08-01
ZnO-nanorods/graphene heterostructure was synthesized by hydrothermal growth of ZnO nanorods on chemically reduced graphene (CRG) film. The hybrid structure was demonstrated as a biosensor, where direct electron transfer between glucose oxidase (GOD) and electrode was observed. The charge transfer was attributed to the ZnO nanorod wiring between the redox center of GOD and electrode, and the ZnO/graphene heterostructure facilitated the transport of electrons on the hybride electrode. The glucose sensor based on the GOD-ZnO/CRG/Pt electrode had a high sensitivity of 17.64 μA mM-1, which is higher than most of the previously reported values for direct electron transfer based glucose biosensors. Moreover, this biosensor is linearly proportional to the concentration of glucose in the range of 0.2-1.6 mM. The study revealed that the band structure of electrode could affect the detection of direct electron transfer of GOD, which would be helpful for the design of the biosensor electrodes in the future.
NASA Astrophysics Data System (ADS)
Bakri, F. A.; Mashor, M. Y.; Sharun, S. M.; Bibi Sarpinah, S. N.; Abu Bakar, Z.
2016-10-01
This study proposes an adaptive fuzzy controller for attitude control system (ACS) of Innovative Satellite (InnoSAT) based on direct action type structure. In order to study new methods used in satellite attitude control, this paper presents three structures of controllers: Fuzzy PI, Fuzzy PD and conventional Fuzzy PID. The objective of this work is to compare the time response and tracking performance among the three different structures of controllers. The parameters of controller were tuned on-line by adjustment mechanism, which was an approach similar to a PID error that could minimize errors between actual and model reference output. This paper also presents a Model References Adaptive Control (MRAC) as a control scheme to control time varying systems where the performance specifications were given in terms of the reference model. All the controllers were tested using InnoSAT system under some operating conditions such as disturbance, varying gain, measurement noise and time delay. In conclusion, among all considered DA-type structures, AFPID controller was observed as the best structure since it outperformed other controllers in most conditions.
Davenport, Thaddeus M; Gorman, Jason; Joyce, M Gordon; Zhou, Tongqing; Soto, Cinque; Guttman, Miklos; Moquin, Stephanie; Yang, Yongping; Zhang, Baoshan; Doria-Rose, Nicole A; Hu, Shiu-Lok; Mascola, John R; Kwong, Peter D; Lee, Kelly K
2016-08-02
Antibody somatic hypermutation (SHM) and affinity maturation enhance antigen recognition by modifying antibody paratope structure to improve its complementarity with the target epitope. SHM-induced changes in paratope dynamics may also contribute to antibody maturation, but direct evidence of this is limited. Here, we examine two classes of HIV-1 broadly neutralizing antibodies (bNAbs) for SHM-induced changes in structure and dynamics, and delineate the effects of these changes on interactions with the HIV-1 envelope glycoprotein (Env). In combination with new and existing structures of unmutated and affinity matured antibody Fab fragments, we used hydrogen/deuterium exchange with mass spectrometry to directly measure Fab structural dynamics. Changes in antibody structure and dynamics were positioned to improve complementarity with Env, with changes in dynamics primarily observed at the paratope peripheries. We conclude that SHM optimizes paratope complementarity to conserved HIV-1 epitopes and restricts the mobility of paratope-peripheral residues to minimize clashes with variable features on HIV-1 Env. Copyright © 2016 Elsevier Ltd. All rights reserved.
Sicoli, Giuseppe; Mathis, Gérald; Aci-Sèche, Samia; Saint-Pierre, Christine; Boulard, Yves; Gasparutto, Didier; Gambarelli, Serge
2009-06-01
Double electron-electron resonance (DEER) was applied to determine nanometre spin-spin distances on DNA duplexes that contain selected structural alterations. The present approach to evaluate the structural features of DNA damages is thus related to the interspin distance changes, as well as to the flexibility of the overall structure deduced from the distance distribution. A set of site-directed nitroxide-labelled double-stranded DNA fragments containing defined lesions, namely an 8-oxoguanine, an abasic site or abasic site analogues, a nick, a gap and a bulge structure were prepared and then analysed by the DEER spectroscopic technique. New insights into the application of 4-pulse DEER sequence are also provided, in particular with respect to the spin probes' positions and the rigidity of selected systems. The lesion-induced conformational changes observed, which were supported by molecular dynamics studies, confirm the results obtained by other, more conventional, spectroscopic techniques. Thus, the experimental approaches described herein provide an efficient method for probing lesion-induced structural changes of nucleic acids.
Why P/OF should look for evidences of over-dense structures in solar flare hard X-ray sources
NASA Technical Reports Server (NTRS)
Neidig, D. F.; Kane, S. R.; Love, J. J.; Cliver, E. W.
1986-01-01
White-light and hard X-ray (HXR) observations of two white-light flares (WLFs) show that if the radiative losses in the optical continuum are powered by fast electrons directly heating the WLF source, then the column density constraints imposed by the finite range of the electrons requires that the WLF consist of an over-dense region in the chromosphere, with density exceeding 10 to the 14th power/cu cm. Thus, we recommend that P/OF search for evidences of over-dense structures in HXR images obtained simultaneously with optical observations of flares.
A discussion of the H-alpha filamentary nebulae and galactic structure in the Cygnus region
NASA Technical Reports Server (NTRS)
Matthews, T. A.; Simonson, S. C., III
1971-01-01
From observation of the galactic structure in Cygnus, the system of filamentary nebulae was found to lie at a distance of roughly 1.5 kpc, in the same region as about half the thermal radio sources in Cygnus X, the supernova remnant near gamma Cygni, and the association Cygnus OB2, in the direction of which the X-ray source Cygnus XR-3 is observed. The source of excitation was probably the pulse of radiation from a supernova explosion, as proposed in the case of Gum nebula. However continuing excitation by early stars in the region of Cygnus X cannot be excluded.
Wegleitner, Eric J.; Isermann, Daniel A.
2017-01-01
Many biologists use digital images for estimating ages of fish, but the use of images could lead to differences in age estimates and precision because image capture can produce changes in light and clarity compared to directly viewing structures through a microscope. We used sectioned sagittal otoliths from 132 Largemouth Bass Micropterus salmoides and sectioned dorsal spines and otoliths from 157 Walleyes Sander vitreus to determine whether age estimates and among‐reader precision were similar when annuli were enumerated directly through a microscope or from digital images. Agreement of ages between viewing methods for three readers were highest for Largemouth Bass otoliths (75–89% among readers), followed by Walleye otoliths (63–70%) and Walleye dorsal spines (47–64%). Most discrepancies (72–96%) were ±1 year, and differences were more prevalent for age‐5 and older fish. With few exceptions, mean ages estimated from digital images were similar to ages estimated via directly viewing the structures through the microscope, and among‐reader precision did not vary between viewing methods for each structure. However, the number of disagreements we observed suggests that biologists should assess potential differences in age structure that could arise if images of calcified structures are used in the age estimation process.
Rahman, Masudur; Neff, David; Green, Nathaniel; Norton, Michael L.
2016-01-01
Although there is a long history of the study of the interaction of DNA with carbon surfaces, limited information exists regarding the interaction of complex DNA-based nanostructures with the important material graphite, which is closely related to graphene. In view of the capacity of DNA to direct the assembly of proteins and optical and electronic nanoparticles, the potential for combining DNA-based materials with graphite, which is an ultra-flat, conductive carbon substrate, requires evaluation. A series of imaging studies utilizing Atomic Force Microscopy has been applied in order to provide a unified picture of this important interaction of structured DNA and graphite. For the test structure examined, we observe a rapid destabilization of the complex DNA origami structure, consistent with a strong interaction of single-stranded DNA with the carbon surface. This destabilizing interaction can be obscured by an intentional or unintentional primary intervening layer of single-stranded DNA. Because the interaction of origami with graphite is not completely dissociative, and because the frustrated, expanded structure is relatively stable over time in solution, it is demonstrated that organized structures of pairs of the model protein streptavidin can be produced on carbon surfaces using DNA origami as the directing material. PMID:28335324
Gulian, J M; Dalmasso, C; Millet, V; Unal, D; Charrel, M
1995-08-01
We compared data obtained with the Kodak Ektachem and Hitachi 717 Analysers and HPLC from 83 neonates under phototherapy. Total bilirubin values determined with the Kodak and Hitachi are in good agreement, but we observed a large discrepancy in the results for conjugated (Kodak) and direct (Hitachi) bilirubin. HPLC revealed that all the samples contained configurational isomers, while only 7.7% and 30.8% contained conjugated bilirubin and structural isomers, respectively. We developed a device for the specific and quantitative production of configurational or structural isomers, by irradiation with blue or green light. In vitro, total bilirubin values are coherent for the routine analysers in the presence of configurational or structural isomers. With configurational isomers, unconjugated bilirubin (Kodak) is lower than total bilirubin (Kodak), and conjugated bilirubin (Kodak) is always equal to zero, so the apparatus gives a false positive response for delta bilirubin. In contrast, the direct bilirubin (Hitachi) is constant. Furthermore, in the presence of structural isomers, unconjugated bilirubin (Kodak) is unexpectedly higher than total bilirubin (Kodak), conjugated bilirubin (Kodak) is proportional to the quantity of these isomers, and direct bilirubin (Hitachi) is constant. The contribution of photoisomers in bilirubin measurements is discussed.
Mathematical Interaction Shaped by Communication, Epistemological Constraints and Enactivism
ERIC Educational Resources Information Center
Steinbring, Heinz
2015-01-01
On the surface, mathematical interaction often appears as an immediately transparent event that could be directly understood by careful observation. Theoretical considerations, however, clearly show that mathematical speaking and conversation in teaching-learning situations are highly complex social structures comprising many preconditions.…
El paradigma jerarquico de formacion de estructuras
NASA Astrophysics Data System (ADS)
Lambas, D. G.
This contribution aims at showing our current understanding of the hierarchical clustering scenario for structure formation, its main success in terms of agreement of theoretical predictions and observations, and the most direct tests that provide confidence on the validity of the paradigm. FULL TEXT IN SPANISH
NASA Technical Reports Server (NTRS)
Sondergaard, R.; Cantwell, B.; Mansour, N.
1997-01-01
Direct numerical simulations have been used to examine the effect of the initial disturbance field on the development of three-dimensionality and the transition to turbulence in the incompressible plane wake. The simulations were performed using a new numerical method for solving the time-dependent, three-dimensional, incompressible Navier-Stokes equations in flows with one infinite and two periodic directions. The method uses standard Fast Fourier Transforms and is applicable to cases where the vorticity field is compact in the infinite direction. Initial disturbances fields examined were combinations of two-dimensional waves and symmetric pairs of 60 deg oblique waves at the fundamental, subharmonic, and sub-subharmonic wavelengths. The results of these simulations indicate that the presence of 60 deg disturbances at the subharmonic streamwise wavelength results in the development of strong coherent three-dimensional structures. The resulting strong three-dimensional rate-of-strain triggers the growth of intense fine scale motions. Wakes initiated with 60 deg disturbances at the fundamental streamwise wavelength develop weak coherent streamwise structures, and do not develop significant fine scale motions, even at high Reynolds numbers. The wakes which develop strong three-dimensional structures exhibit growth rates on par with experimentally observed turbulent plane wakes. Wakes which develop only weak three-dimensional structures exhibit significantly lower late time growth rates. Preliminary studies of wakes initiated with an oblique fundamental and a two-dimensional subharmonic, which develop asymmetric coherent oblique structures at the subharmonic wavelength, indicate that significant fine scale motions only develop if the resulting oblique structures are above an angle of approximately 45 deg.
Rafiee Fanood, Mohammad M; Ganjitabar, Hassan; Garcia, Gustavo A; Nahon, Laurent; Turchini, Stefano; Powis, Ivan
2018-04-17
Photoionization of the chiral monoterpene limonene has been investigated using polarized synchrotron radiation between the adiabatic ionization threshold, 8.505 and 23.5 eV. A rich vibrational structure is seen in the threshold photoelectron spectrum and is interpreted using a variety of computational methods. The corresponding photoelectron circular dichroism-measured in the photoelectron angular distribution as a forward-backward asymmetry with respect to the photon direction-was found to be strongly dependent on the vibronic structure appearing in the photoelectron spectra, with the observed asymmetry even switching direction in between the major vibrational peaks. This effect can be ultimately attributed to the sensitivity of this dichroism to small phase shifts between adjacent partial waves of the outgoing photoelectron. These observations have implications for potential applications of this chiroptical technique, where the enantioselective analysis of monoterpene components is of particular interest. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Sharath Chandra, L. S.; Mondal, R.; Thamizhavel, A.; Dhar, S. K.; Roy, S. B.
2017-09-01
The temperature dependence of resistivity ρ(T) of a polycrystalline sample and a single crystal sample (current along the [0001] direction) of α - Titanium (Ti) at low temperatures is revisited to understand the electrical charge transport phenomena in this hexagonal closed pack metal. We show that the ρ(T) in single crystal Ti can be explained by considering the scattering of electrons due to electron-phonon, electron-electron, inter-band s-d and electron-impurity interactions, whereas the ρ(T) of polycrystalline Ti could not be explained by these interactions alone. We observed that the effects of the anisotropy of the hexagonal structure on the electronic band structure and the phonon dispersion need to be taken into account to explain ρ(T) of polycrystalline Ti. Two Debye temperatures corresponding to two different directions for the electron-phonon interactions and inter-band s-d scattering are needed to account the observed ρ(T) in polycrystalline Ti.
Xu, Rosalind J; Blasiak, Bartosz; Cho, Minhaeng; Layfield, Joshua P; Londergan, Casey H
2018-05-17
A quantitative connection between molecular dynamics simulations and vibrational spectroscopy of probe-labeled systems would enable direct translation of experimental data into structural and dynamical information. To constitute this connection, all-atom molecular dynamics (MD) simulations were performed for two SCN probe sites (solvent-exposed and buried) in a calmodulin-target peptide complex. Two frequency calculation approaches with substantial nonelectrostatic components, a quantum mechanics/molecular mechanics (QM/MM)-based technique and a solvatochromic fragment potential (SolEFP) approach, were used to simulate the infrared probe line shapes. While QM/MM results disagreed with experiment, SolEFP results matched experimental frequencies and line shapes and revealed the physical and dynamic bases for the observed spectroscopic behavior. The main determinant of the CN probe frequency is the exchange repulsion between the probe and its local structural neighbors, and there is a clear dynamic explanation for the relatively broad probe line shape observed at the "buried" probe site. This methodology should be widely applicable to vibrational probes in many environments.
Optical second harmonic generation from Pt nanowires with boomerang-like cross-sectional shapes
NASA Astrophysics Data System (ADS)
Ogata, Yoichi; Anh Tuan, Nguyen; Miyauchi, Yoshihiro; Mizutani, Goro
2011-08-01
We have fabricated Pt nanowires with boomerang-like cross-sectional shapes on the MgO(110) faceted template and observed their optical second-harmonic generation (SHG) response. In the TEM images the Pt nanowires on the MgO substrate had macroscopic C2v symmetry, however, their structure had microscopic imperfections. In the SHG response, as a function of the sample rotation angle around the substrate normal, we found contributions from the nonlinear susceptibility elements χ113, χ223, χ311, χ322, and χ333 originating from the broken symmetry in the 3; [110] direction of the MgO substrate. The indices 1 and 2 denote the [001] and [11¯0] directions, respectively. Under C2v symmetry no SHG is expected in the s-in/s-out polarization configuration, however, a finite SHG was observed in this polarization configuration. We suggest that the SHG in the forbidden configuration might originate from the imperfections in the nanowire structure.
The structure and nature of NGC 2017 IRS. 1: High-resolution radio continuum maps
NASA Technical Reports Server (NTRS)
Smith, Howard A.; Beck, Sara C.
1994-01-01
We have observed the star formation cluster NGC 2071 IRS 1, 2, and 3, with 0.14 sec spatial resolution at 2 cm. The strong source IRS 1 breaks up into a bright peak sitting on a narrow line emission extending over about 400 AU, with three much weaker peaks. This ridge, which has a p.a. = 100 deg, is not aligned with any of the other structures that have previously been seen around IRS 1: its orientation is about 55 deg from the CO outflow direction, and 35 deg from a hypothetical disk direction. The spectral and spatial results, combined with earlier radio and infrared observations, indicate that most likely the radio and infrared emission from the exciting source, IRS 1, is produced by a dense wind hidden by at least 100 visual magnitudes of extinction; the extended ridge of emission comes from an optically thin H II region with characteristic dimensions of approximately AU and which may result from a clumpy distribution of local gas and dust.
Integrated anode structure for passive direct methanol fuel cells with neat methanol operation
NASA Astrophysics Data System (ADS)
Wu, Huijuan; Zhang, Haifeng; Chen, Peng; Guo, Jing; Yuan, Ting; Zheng, Junwei; Yang, Hui
2014-02-01
A microporous titanium plate based integrated anode structure (Ti-IAS) suitable for passive direct methanol fuel cells (DMFCs) fueled with neat methanol is reported. This anode structure incorporates a porous titanium plate as a methanol mass transfer barrier and current collector, pervaporation film for passively vaporizing methanol, vaporous methanol cavity for evenly distributing fuel, and channels for carbon dioxide venting. With the effective control of methanol delivery rate, the Ti-IAS based DMFC allows the direct use of neat methanol as the fuel source. In the meantime, the required water for methanol-oxidation reaction at the anode can also be fully recovered from the cathode with the help of the highly hydrophobic microporous layer in the cathode. DMFCs incorporating this new anode structure exhibit a power density as high as 40 mW cm-2 and a high volumetric energy density of 489 Wh L-1 operating with neat methanol and at 25 °C. Importantly, no obvious performance degradation of the passive DMFC system is observed after more than 90 h of continuous operation. The experimental results reveal that the compact DMFC based on the Ti-IAS exhibits a substantial potential as power sources for portable applications.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Belopolski, Ilya; Xu, Su-Yang; Ishida, Yukiaki
2016-08-15
It has recently been proposed that electronic band structures in crystals can give rise to a previously overlooked type of Weyl fermion, which violates Lorentz invariance and, consequently, is forbidden in particle physics. It was further predicted that Mo x W 1 - x Te 2 may realize such a type-II Weyl fermion. Here, we first show theoretically that it is crucial to access the band structure above the Fermi level ε F to show a Weyl semimetal in Mo x W 1 - x Te 2 . Then, we study Mo x W 1 - x Te 2 bymore » pump-probe ARPES and we directly access the band structure > 0.2 eV above ε F in experiment. By comparing our results with ab initio calculations, we conclude that we directly observe the surface state containing the topological Fermi arc. We propose that a future study of Mo x W 1 - x Te 2 by pump-probe ARPES may directly pinpoint the Fermi arc. Our work sets the stage for the experimental discovery of the first type-II Weyl semimetal in Mo x W 1 - x Te 2 .« less
Transport properties of electrons in fractal magnetic-barrier structures
NASA Astrophysics Data System (ADS)
Sun, Lifeng; Fang, Chao; Guo, Yong
2010-09-01
Quantum transport properties in fractal magnetically modulated structures are studied by the transfer-matrix method. It is found that the transmission spectra depend sensitively not only on the incident energy and the direction of the wave vector but also on the stage of the fractal structures. Resonance splitting, enhancement, and position shift of the resonance peaks under different magnetic modulation are observed at four different fractal stages, and the relationship between the conductance in the fractal structure and magnetic modulation is also revealed. The results indicate the spectra of the transmission can be considered as fingerprints for the fractal structures, which show the subtle correspondence between magnetic structures and transport behaviors.
Yoder, Bruce L; Maze, Joshua T; Raghavachari, Krishnan; Jarrold, Caroline Chick
2005-03-01
The competitive structural isomers of the Mo(2)O(y) (-)Mo(2)O(y) (y=2, 3, and 4) clusters are investigated using a combination of anion photoelectron (PE) spectroscopy and density functional theory calculations. The PE spectrum and calculations for MoO(3) (-)MoO(3) are also presented to show the level of agreement to be expected between the spectra and calculations. For MoO(3) (-) and MoO(3), the calculations predict symmetric C(3v) structures, an adiabatic electron affinity of 3.34 eV, which is above the observed value 3.17(2) eV. However, there is good agreement between observed and calculated vibrational frequencies and band profiles. The PE spectra of Mo(2)O(2) (-) and Mo(2)O(3) (-) are broad and congested, with partially resolved vibrational structure on the lowest energy bands observed in the spectra. The electron affinities (EA(a)s) of the corresponding clusters are 2.24(2) and 2.33(7) eV, respectively. Based on the calculations, the most stable structure of Mo(2)O(2) (-) is Y shaped, with the two Mo atoms directly bonded. Assignment of the Mo(2)O(3) (-) spectrum is less definitive, but a O-Mo-O-Mo-O structure is more consistent with overall electronic structure observed in the spectrum. The PE spectrum of Mo(2)O(4) (-) shows cleanly resolved vibrational structure and electronic bands, and the EA of the corresponding Mo(2)O(4) is determined to be 2.13(4) eV. The structure most consistent with the observed spectrum has two oxygen bridge bonds between the Mo atoms.
NASA Astrophysics Data System (ADS)
Peer, Regina; Peer, Siegfried; Sander, Heike; Marsolek, Ingo; Koller, Wolfgang; Pappert, Dirk; Hierholzer, Johannes
2002-05-01
If new technology is introduced into medical practice it must prove to make a difference. However traditional approaches of outcome analysis failed to show a direct benefit of PACS on patient care and economical benefits are still in debate. A participatory process analysis was performed to compare workflow in a film based hospital and a PACS environment. This included direct observation of work processes, interview of involved staff, structural analysis and discussion of observations with staff members. After definition of common structures strong and weak workflow steps were evaluated. With a common workflow structure in both hospitals, benefits of PACS were revealed in workflow steps related to image reporting with simultaneous image access for ICU-physicians and radiologists, archiving of images as well as image and report distribution. However PACS alone is not able to cover the complete process of 'radiography for intensive care' from ordering of an image till provision of the final product equals image + report. Interference of electronic workflow with analogue process steps such as paper based ordering reduces the potential benefits of PACS. In this regard workflow modeling proved to be very helpful for the evaluation of complex work processes linking radiology and the ICU.
Observation of Bloch oscillations in complex PT-symmetric photonic lattices
Wimmer, Martin; Miri, Mohammed-Ali; Christodoulides, Demetrios; Peschel, Ulf
2015-01-01
Light propagation in periodic environments is often associated with a number of interesting and potentially useful processes. If a crystalline optical potential is also linearly ramped, light can undergo periodic Bloch oscillations, a direct outcome of localized Wannier-Stark states and their equidistant eigenvalue spectrum. Even though these effects have been extensively explored in conservative settings, this is by no means the case in non-Hermitian photonic lattices encompassing both amplification and attenuation. Quite recently, Bloch oscillations have been predicted in parity-time-symmetric structures involving gain and loss in a balanced fashion. While in a complex bulk medium, one intuitively expects that light will typically follow the path of highest amplification, in a periodic system this behavior can be substantially altered by the underlying band structure. Here, we report the first experimental observation of Bloch oscillations in parity-time-symmetric mesh lattices. We show that these revivals exhibit unusual properties like secondary emissions and resonant restoration of PT symmetry. In addition, we present a versatile method for reconstructing the real and imaginary components of the band structure by directly monitoring the light evolution during a cycle of these oscillations. PMID:26639941
In vitro fluorescence studies of transcription factor IIB-DNA interaction.
Górecki, Andrzej; Figiel, Małgorzata; Dziedzicka-Wasylewska, Marta
2015-01-01
General transcription factor TFIIB is one of the basal constituents of the preinitiation complex of eukaryotic RNA polymerase II, acting as a bridge between the preinitiation complex and the polymerase, and binding promoter DNA in an asymmetric manner, thereby defining the direction of the transcription. Methods of fluorescence spectroscopy together with circular dichroism spectroscopy were used to observe conformational changes in the structure of recombinant human TFIIB after binding to specific DNA sequence. To facilitate the exploration of the structural changes, several site-directed mutations have been introduced altering the fluorescence properties of the protein. Our observations showed that binding of specific DNA sequences changed the protein structure and dynamics, and TFIIB may exist in two conformational states, which can be described by a different microenvironment of W52. Fluorescence studies using both intrinsic and exogenous fluorophores showed that these changes significantly depended on the recognition sequence and concerned various regions of the protein, including those interacting with other transcription factors and RNA polymerase II. DNA binding can cause rearrangements in regions of proteins interacting with the polymerase in a manner dependent on the recognized sequences, and therefore, influence the gene expression.
Electronic Structure, Surface Doping, and Optical Response in Epitaxial WSe2 Thin Films.
Zhang, Yi; Ugeda, Miguel M; Jin, Chenhao; Shi, Su-Fei; Bradley, Aaron J; Martín-Recio, Ana; Ryu, Hyejin; Kim, Jonghwan; Tang, Shujie; Kim, Yeongkwan; Zhou, Bo; Hwang, Choongyu; Chen, Yulin; Wang, Feng; Crommie, Michael F; Hussain, Zahid; Shen, Zhi-Xun; Mo, Sung-Kwan
2016-04-13
High quality WSe2 films have been grown on bilayer graphene (BLG) with layer-by-layer control of thickness using molecular beam epitaxy. The combination of angle-resolved photoemission, scanning tunneling microscopy/spectroscopy, and optical absorption measurements reveal the atomic and electronic structures evolution and optical response of WSe2/BLG. We observe that a bilayer of WSe2 is a direct bandgap semiconductor, when integrated in a BLG-based heterostructure, thus shifting the direct-indirect band gap crossover to trilayer WSe2. In the monolayer limit, WSe2 shows a spin-splitting of 475 meV in the valence band at the K point, the largest value observed among all the MX2 (M = Mo, W; X = S, Se) materials. The exciton binding energy of monolayer-WSe2/BLG is found to be 0.21 eV, a value that is orders of magnitude larger than that of conventional three-dimensional semiconductors, yet small as compared to other two-dimensional transition metal dichalcogennides (TMDCs) semiconductors. Finally, our finding regarding the overall modification of the electronic structure by an alkali metal surface electron doping opens a route to further control the electronic properties of TMDCs.
NASA Astrophysics Data System (ADS)
Chevalier, S.; Lavielle, N.; Hatton, B. D.; Bazylak, A.
2017-06-01
In this first of a series of two papers, we report an in-depth analysis of the impact of the gas diffusion layer (GDL) structure on the polymer electrolyte membrane (PEM) fuel cell performance through the use of custom GDLs fabricated in-house. Hydrophobic electrospun nanofibrous gas diffusion layers (eGDLs) are fabricated with controlled fibre diameter and alignment. The eGDLs are rendered hydrophobic through direct surface functionalization, and this molecular grafting is achieved in the absence of structural alteration. The fibre diameter, chemical composition, and electrical conductivity of the eGDL are characterized, and the impact of eGDL structure on fuel cell performance is analysed. We observe that the eGDL facilitates higher fuel cell power densities compared to a commercial GDL (Toray TGP-H-60) at highly humidified operating conditions. The ohmic resistance of the fuel cell is found to significantly increase with increasing inter-fiber distance. It is also observed that the addition of a hydrophobic treatment enhances membrane hydration, and fibres perpendicularly aligned to the channel direction may enhance the contact area between the catalyst layer and the GDL.
Observation of Bloch oscillations in complex PT-symmetric photonic lattices
NASA Astrophysics Data System (ADS)
Wimmer, Martin; Miri, Mohammed-Ali; Christodoulides, Demetrios; Peschel, Ulf
2015-12-01
Light propagation in periodic environments is often associated with a number of interesting and potentially useful processes. If a crystalline optical potential is also linearly ramped, light can undergo periodic Bloch oscillations, a direct outcome of localized Wannier-Stark states and their equidistant eigenvalue spectrum. Even though these effects have been extensively explored in conservative settings, this is by no means the case in non-Hermitian photonic lattices encompassing both amplification and attenuation. Quite recently, Bloch oscillations have been predicted in parity-time-symmetric structures involving gain and loss in a balanced fashion. While in a complex bulk medium, one intuitively expects that light will typically follow the path of highest amplification, in a periodic system this behavior can be substantially altered by the underlying band structure. Here, we report the first experimental observation of Bloch oscillations in parity-time-symmetric mesh lattices. We show that these revivals exhibit unusual properties like secondary emissions and resonant restoration of PT symmetry. In addition, we present a versatile method for reconstructing the real and imaginary components of the band structure by directly monitoring the light evolution during a cycle of these oscillations.
Observations of CMEs and Models of the Eruptive Corona
NASA Technical Reports Server (NTRS)
Gopalswamy, Nat
2012-01-01
It is now realized that coronal mass ejections (CMEs) are the most energetic phenomenon in the heliosphere. Although early observations (in the 1970s and 19805) revealed most of the properties of CMEs, it is the extended and uniform data set from the Solar and Heliospheric Observatory (SOHO) mission that helped us consolidate our knowledge on CMEs. The Solar Terrestrial Relations Observatory (STEREO) mission has provided direct confirmation of the three-dimensional structure of CMEs. The broadside view provided by the STEREO coronagraphs helped us estimate the width of the halo CMEs and hence validate CME cone models. Current theoretical ideas on the internal structure of CMEs suggest that a flux rope is central to the CME structure, which has considerable observational support both from remote-sensing and in-situ observations. The flux-rope nature is also consistent with the post-eruption arcades with high-temperature plasma and the charge states observed within CMEs arriving at Earth. The quadrature observations also helped us understand the relation between the radial and expansion speeds of CMEs, which were only known from empirical relations in the past. This paper highlights some of these results obtained during solar cycle 23 and 24 and discusses implications for CME models.
Small-Scale Structure in Saturn's Rings
NASA Astrophysics Data System (ADS)
Rehnberg, Morgan
2017-08-01
The rings of Saturn are the largest and most complex in the Solar System. Decades of observation from ground- and space-based observatories and spacecraft missions have revealed the broad structure of the rings and the intricate interactions between the planet's moons and its rings. Stellar occultations observed by the Ultraviolet Imaging Spectrograph's High Speed Photometer onboard the Cassini spacecraft now enable the direct study of the small-scale structure that results from these interactions. In this dissertation, I present three distinct phenomena resulting from the small-scale physics of the rings. Many resonance locations with Saturn's external satellites lie within the main (A and B) rings. Two of these satellites, Janus and Epimetheus, have a unique co-orbital relationship and move radially to switch positions every 4.0 years. This motion also moves the resonance locations within the rings. As the spiral density waves created at these resonances interact, they launch an enormous solitary wave every eight years. I provide the first-ever observations of this never-predicted phenomenon and detail a possible formation mechanism. Previous studies have reported a population of kilometer-scale aggregates in Saturn's F ring, which likely form as a result of self-gravitation between ring particles in Saturn's Roche zone. I expand the known catalog of features in UVIS occultations and provide the first estimates of their density derived from comparisons with the A ring. These features are orders of magnitude less dense than previously believed, a fact which reconciles them with detections made by other means. Theory and indirect observations indicate that the smallest regular structures in the rings are wavelike aggregates called self-gravity wakes. Using the highest-resolution occulta- tions, I provide the first-ever direct detection of these features by identifying the gaps that represent the minima of the wakes. I demonstrate that the distribution of these gaps is con- sistent with the broad brightness asymmetries previously observed in the rings. Furthermore, the presence of spiral density waves affects the formation of self-gravity waves.
The structure of galactic HI in directions of low total column density
NASA Technical Reports Server (NTRS)
Lockman, F. J.; Jahoda, K.; Mccammon, D.
1985-01-01
A detailed 21 cm study of areas of that have the smallest known amount of HI in the northern sky was performed. These observations were corrected for stray radiation. The region of main interest, around alpha = 10(h)45(m), delta = 57 deg 20', has a minimium N(HI) of 4.5 x 10 to the 19th power/sq cm. Spectra taken at 21' resolution over a field 4 x 3 deg in this direction show up to four HI line components. Two, near 0 and -50 km/s, are ubiquitous. There is also a narrow component at -10 km/s attributable to a diffuse cloud covering half of the field, and scattered patches of HI at v -100 km/s. the low and intermediate velocity components have a broad line width and are so smoothly distributed across the region that it is unlikely that they contain significant unresolved angular structure. Eight other low column density directions were also observed. Their spectra typically have several components, but the total column density is always 7 x 10 to the 19th power/sq cm and changes smoothly along a 2 deg strip. Half of the directions show narrow lines arising from weak diffuse HI clouds that contain 0.5 to 3.0 x 10 to the 19th power/sq cm.
The Spatially Resolved H(alpha)-Emitting Wind Structure of P Cygni
2010-06-01
using radio and optical interferometry, as well as direct imaging with adaptive optics (AO). Radio interferometric observations detect the nebula around...to structures in the nebula of P Cyg that are more than an order of magnitude smaller. Therefore, optical interferometry provides a unique window of...resolved the outer Hα-emitting region of the extended envelope, but detected signatures of clumping. Although, the angular scales sampled with a 1.52 m
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lee, Seongmin; Verdine, Gregory L.; Harvard)
2010-01-14
Adenine DNA glycosylase catalyzes the glycolytic removal of adenine from the promutagenic A {center_dot} oxoG base pair in DNA. The general features of DNA recognition by an adenine DNA glycosylase, Bacillus stearothermophilus MutY, have previously been revealed via the X-ray structure of a catalytically inactive mutant protein bound to an A:oxoG-containing DNA duplex. Although the structure revealed the substrate adenine to be, as expected, extruded from the DNA helix and inserted into an extrahelical active site pocket on the enzyme, the substrate adenine engaged in no direct contacts with active site residues. This feature was paradoxical, because other glycosylases havemore » been observed to engage their substrates primarily through direct contacts. The lack of direct contacts in the case of MutY suggested that either MutY uses a distinctive logic for substrate recognition or that the X-ray structure had captured a noncatalytically competent state in lesion recognition. To gain further insight into this issue, we crystallized wild-type MutY bound to DNA containing a catalytically inactive analog of 2'-deoxyadenosine in which a single 2'-H atom was replaced by fluorine. The structure of this fluorinated lesion-recognition complex (FLRC) reveals the substrate adenine buried more deeply into the active site pocket than in the prior structure and now engaged in multiple direct hydrogen bonding and hydrophobic interactions. This structure appears to capture the catalytically competent state of adenine DNA glycosylases, and it suggests a catalytic mechanism for this class of enzymes, one in which general acid-catalyzed protonation of the nucleobase promotes glycosidic bond cleavage.« less
NASA Astrophysics Data System (ADS)
Abbasi, R.; Abdou, Y.; Abu-Zayyad, T.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Altmann, D.; Andeen, K.; Auffenberg, J.; Bai, X.; Baker, M.; Barwick, S. W.; Bay, R.; Bazo Alba, J. L.; Beattie, K.; Beatty, J. J.; Bechet, S.; Becker, J. K.; Becker, K.-H.; Benabderrahmane, M. L.; BenZvi, S.; Berdermann, J.; Berghaus, P.; Berley, D.; Bernardini, E.; Bertrand, D.; Besson, D. Z.; Bindig, D.; Bissok, M.; Blaufuss, E.; Blumenthal, J.; Boersma, D. J.; Bohm, C.; Bose, D.; Böser, S.; Botner, O.; Brown, A. M.; Buitink, S.; Caballero-Mora, K. S.; Carson, M.; Chirkin, D.; Christy, B.; Clem, J.; Clevermann, F.; Cohen, S.; Colnard, C.; Cowen, D. F.; D'Agostino, M. V.; Danninger, M.; Daughhetee, J.; Davis, J. C.; De Clercq, C.; Demirörs, L.; Denger, T.; Depaepe, O.; Descamps, F.; Desiati, P.; de Vries-Uiterweerd, G.; DeYoung, T.; Díaz-Vélez, J. C.; Dierckxsens, M.; Dreyer, J.; Dumm, J. P.; Ehrlich, R.; Eisch, J.; Ellsworth, R. W.; Engdegård, O.; Euler, S.; Evenson, P. A.; Fadiran, O.; Fazely, A. R.; Fedynitch, A.; Feintzeig, J.; Feusels, T.; Filimonov, K.; Finley, C.; Fischer-Wasels, T.; Foerster, M. M.; Fox, B. D.; Franckowiak, A.; Franke, R.; Gaisser, T. K.; Gallagher, J.; Gerhardt, L.; Gladstone, L.; Glüsenkamp, T.; Goldschmidt, A.; Goodman, J. A.; Gora, D.; Grant, D.; Griesel, T.; Groß, A.; Grullon, S.; Gurtner, M.; Ha, C.; Hajismail, A.; Hallgren, A.; Halzen, F.; Han, K.; Hanson, K.; Heinen, D.; Helbing, K.; Herquet, P.; Hickford, S.; Hill, G. C.; Hoffman, K. D.; Homeier, A.; Hoshina, K.; Hubert, D.; Huelsnitz, W.; Hülß, J.-P.; Hulth, P. O.; Hultqvist, K.; Hussain, S.; Ishihara, A.; Jacobsen, J.; Japaridze, G. S.; Johansson, H.; Joseph, J. M.; Kampert, K.-H.; Kappes, A.; Karg, T.; Karle, A.; Kenny, P.; Kiryluk, J.; Kislat, F.; Klein, S. R.; Köhne, J.-H.; Kohnen, G.; Kolanoski, H.; Köpke, L.; Kopper, S.; Koskinen, D. J.; Kowalski, M.; Kowarik, T.; Krasberg, M.; Krings, T.; Kroll, G.; Kurahashi, N.; Kuwabara, T.; Labare, M.; Lafebre, S.; Laihem, K.; Landsman, H.; Larson, M. J.; Lauer, R.; Lünemann, J.; Madajczyk, B.; Madsen, J.; Majumdar, P.; Marotta, A.; Maruyama, R.; Mase, K.; Matis, H. S.; Meagher, K.; Merck, M.; Mészáros, P.; Meures, T.; Middell, E.; Milke, N.; Miller, J.; Montaruli, T.; Morse, R.; Movit, S. M.; Nahnhauer, R.; Nam, J. W.; Naumann, U.; Nießen, P.; Nygren, D. R.; Odrowski, S.; Olivas, A.; Olivo, M.; O'Murchadha, A.; Ono, M.; Panknin, S.; Paul, L.; Pérez de los Heros, C.; Petrovic, J.; Piegsa, A.; Pieloth, D.; Porrata, R.; Posselt, J.; Price, C. C.; Price, P. B.; Przybylski, G. T.; Rawlins, K.; Redl, P.; Resconi, E.; Rhode, W.; Ribordy, M.; Rizzo, A.; Rodrigues, J. P.; Roth, P.; Rothmaier, F.; Rott, C.; Ruhe, T.; Rutledge, D.; Ruzybayev, B.; Ryckbosch, D.; Sander, H.-G.; Santander, M.; Sarkar, S.; Schatto, K.; Schmidt, T.; Schönwald, A.; Schukraft, A.; Schultes, A.; Schulz, O.; Schunck, M.; Seckel, D.; Semburg, B.; Seo, S. H.; Sestayo, Y.; Seunarine, S.; Silvestri, A.; Slipak, A.; Spiczak, G. M.; Spiering, C.; Stamatikos, M.; Stanev, T.; Stephens, G.; Stezelberger, T.; Stokstad, R. G.; Stössl, A.; Stoyanov, S.; Strahler, E. A.; Straszheim, T.; Stür, M.; Sullivan, G. W.; Swillens, Q.; Taavola, H.; Taboada, I.; Tamburro, A.; Tepe, A.; Ter-Antonyan, S.; Tilav, S.; Toale, P. A.; Toscano, S.; Tosi, D.; Turčan, D.; van Eijndhoven, N.; Vandenbroucke, J.; Van Overloop, A.; van Santen, J.; Vehring, M.; Voge, M.; Walck, C.; Waldenmaier, T.; Wallraff, M.; Walter, M.; Weaver, Ch.; Wendt, C.; Westerhoff, S.; Whitehorn, N.; Wiebe, K.; Wiebusch, C. H.; Williams, D. R.; Wischnewski, R.; Wissing, H.; Wolf, M.; Wood, T. R.; Woschnagg, K.; Xu, C.; Xu, X. W.; Yodh, G.; Yoshida, S.; Zarzhitsky, P.; Zoll, M.; IceCube Collaboration
2011-10-01
Between 2009 May and 2010 May, the IceCube neutrino detector at the South Pole recorded 32 billion muons generated in air showers produced by cosmic rays with a median energy of 20 TeV. With a data set of this size, it is possible to probe the southern sky for per-mil anisotropy on all angular scales in the arrival direction distribution of cosmic rays. Applying a power spectrum analysis to the relative intensity map of the cosmic ray flux in the southern hemisphere, we show that the arrival direction distribution is not isotropic, but shows significant structure on several angular scales. In addition to previously reported large-scale structure in the form of a strong dipole and quadrupole, the data show small-scale structure on scales between 15° and 30°. The skymap exhibits several localized regions of significant excess and deficit in cosmic ray intensity. The relative intensity of the smaller-scale structures is about a factor of five weaker than that of the dipole and quadrupole structure. The most significant structure, an excess localized at (right ascension α = 122fdg4 and declination δ = -47fdg4), extends over at least 20° in right ascension and has a post-trials significance of 5.3σ. The origin of this anisotropy is still unknown.
High-speed atomic force microscopy for observing protein molecules in dynamic action
NASA Astrophysics Data System (ADS)
Ando, T.
2017-02-01
Directly observing protein molecules in dynamic action at high spatiotemporal resolution has long been a holy grail for biological science. To materialize this long quested dream, I have been developing high-speed atomic force microscopy (HS-AFM) since 1993. Tremendous strides were recently accomplished in its high-speed and low-invasive performances. Consequently, various dynamic molecular actions, including bipedal walking of myosin V and rotary propagation of structural changes in F1-ATPase, were successfully captured on video. The visualized dynamic images not only provided irrefutable evidence for speculated actions of the protein molecules but also brought new discoveries inaccessible with other approaches, thus giving great mechanistic insights into how the molecules function. HS-AFM is now transforming "static" structural biology into dynamic structural bioscience.
Structural and critical current properties in Al-doped MgB 2
NASA Astrophysics Data System (ADS)
Zheng, D. N.; Xiang, J. Y.; Lang, P. L.; Li, J. Q.; Che, G. C.; Zhao, Z. W.; Wen, H. H.; Tian, H. Y.; Ni, Y. M.; Zhao, Z. X.
2004-08-01
A series of Al-doped Mg 1- xAl xB 2 samples have been fabricated and systematic study on structure and superconducting properties have been carried out for the samples. In addition to a structural transition observed by XRD, TEM micrographs showed the existence of a superstructure of double c-axis lattice constant along the direction perpendicular to the boron honeycomb sheet. In order to investigate the effect of Al doping on flux pinning and critical current properties in MgB 2, measurements on the superconducting transition temperature Tc, irreversible field Birr and critical current density Jc were performed too, for the samples with the doping levels lower than 0.15 in particular. These experimental observations were discussed in terms of Al doping induced changes in carrier concentration.
Dynamics of Coronal Structures Captured During the 2012 and 2013 Total Solar Eclipses
NASA Astrophysics Data System (ADS)
Alzate, N.; Habbal, S. R.; Druckmuller, M.
2017-12-01
White light eclipse images taken during total solar eclipses provide a very high dynamic range spanning tens of solar radii starting from the solar surface. They capture the instantaneous state of the corona, including dynamic events. We present observations of the 2012 November 13 and 2013 November 3 total solar eclipses, taken by Constantinos Emmanouilidis, in which we captured high latitude tethered prominences accompanied by CMEs, as well as several `atypical' large scale structures, spanning a few solar radii above the solar surface. By complementing the eclipse observations with co-temporaneous SDO/AIA, STEREO/EUVI and SOHO/LASCO observations, we show how the shape of the atypical structures outlines the shape of faint CME shock fronts, driven by flaring activities. The tethered prominences were imaged from their anchor at the solar surface out to several solar radii. The SDO/AIA 30.4, 17.1 and 19.3 nm emission clearly show how a direct link between the cool (104 - 105 K) filamentary emission from prominence material, and the filamentary structures emitting at coronal temperatures (> 106 K), is unmistakably present. The observed survival of these tethered systems out to the field of view of LASCO C3, establishes the likely origin of counter-streaming electrons associated with CMEs observed in interplanetary space (ICMEs). They also provide new insights for CME-initiation models associated with prominence eruptions. Our work highlights the uniqueness of eclipse observations in identifying the impact of transit events on large-scale coronal structures.
Hubble space telescope observations and geometric models of compact multipolar planetary nebulae
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hsia, Chih-Hao; Chau, Wayne; Zhang, Yong
2014-05-20
We report high angular resolution Hubble Space Telescope observations of 10 compact planetary nebulae (PNs). Many interesting internal structures, including multipolar lobes, arcs, two-dimensional rings, tori, and halos, are revealed for the first time. These results suggest that multipolar structures are common among PNs, and these structures develop early in their evolution. From three-dimensional geometric models, we have determined the intrinsic dimensions of the lobes. Assuming the lobes are the result of interactions between later-developed fast winds and previously ejected asymptotic giant branch winds, the geometric structures of these PNs suggest that there are multiple phases of fast winds separatedmore » by temporal variations and/or directional changes. A scenario of evolution from lobe-dominated to cavity-dominated stages is presented. The results reported here will provide serious constraints on any dynamical models of PNs.« less
Natsuaki, Misaki N; Leve, Leslie D; Harold, Gordon T; Neiderhiser, Jenae M; Shaw, Daniel S; Ganiban, Jody; Scaramella, Laura V; Reiss, David
2013-01-01
This investigation examined the mutual influences between structured parenting and child social wariness during toddlerhood using a longitudinal adoption design. The sample consisted of 361 adoption-linked families, each including an adopted child, adoptive parents, and a birth mother. Heightened social wariness in children at age 18 months predicted reduced levels of observed structured parenting (i.e., less directive parenting with fewer commands and requests) in adoptive mothers at age 27 months. Adoptive fathers' lower structured parenting at age 18 months predicted subsequent elevation in child social wariness. Birth mothers' history of fear-related anxiety disorders was not associated with child social wariness. Findings highlight the role of dynamic family transactions in the development of social wariness during toddlerhood. © 2013 The Authors. Child Development © 2013 Society for Research in Child Development, Inc.
Micro and sub-micron surface structuring of AZ31 by laser re-melting and dimpling
NASA Astrophysics Data System (ADS)
Furlan, Valentina; Demir, Ali Gökhan; Previtali, Barbara
2015-12-01
In this work, the use of ns-pulsed fibre laser for surface structuring of AZ31 Mg alloy is investigated. Surface re-melting was employed to change surface morphology, especially in terms of surface roughness. Dimpling by percussion microdrilling was investigated to control the hole geometry.. With surface remelting mono-directional and homogeneous surfaces were obtained with Fl<500 J/cm2. Above 500 J/cm2 particle generation was observed, which induced sub-micron structure growth with nano-fibrous features. Moreover, surface roughness could be controlled below the initial value and much higher. With dimpling, transformation from gentle to strong ablation was observed at F0=10.3 J/cm2. XRD analysis was employed to link oxide growth to the surface morphology. Tensile tests were carried out to assess the damage on the mechanical properties after surface structuring.
Topological defects in electric double layers of ionic liquids at carbon interfaces
Black, Jennifer M.; Okatan, Mahmut Baris; Feng, Guang; ...
2015-06-07
The structure and properties of the electrical double layer in ionic liquids is of interest in a wide range of areas including energy storage, catalysis, lubrication, and many more. Theories describing the electrical double layer for ionic liquids have been proposed, however a full molecular level description of the double layer is lacking. To date, studies have been predominantly focused on ion distributions normal to the surface, however the 3D nature of the electrical double layer in ionic liquids requires a full picture of the double layer structure not only normal to the surface, but also in plane. Here wemore » utilize 3D force mapping to probe the in plane structure of an ionic liquid at a graphite interface and report the direct observation of the structure and properties of topological defects. The observation of ion layering at structural defects such as step-edges, reinforced by molecular dynamics simulations, defines the spatial resolution of the method. Observation of defects allows for the establishment of the universality of ionic liquid behavior vs. separation from the carbon surface and to map internal defect structure. In conclusion, these studies offer a universal pathway for probing the internal structure of topological defects in soft condensed matter on the nanometer level in three dimensions.« less
The force-free configuration of flux ropes in geomagnetotail: Cluster observations
NASA Astrophysics Data System (ADS)
Yang, Y. Y.; Shen, C.; Zhang, Y. C.; Rong, Z. J.; Li, X.; Dunlop, M.; Ma, Y. H.; Liu, Z. X.; Carr, C. M.; Rème, H.
2014-08-01
Unambiguous knowledge of magnetic field structure and the electric current distribution is critical for understanding the origin, evolution, and related dynamic properties of magnetic flux ropes (MFRs). In this paper, a survey of 13 MFRs in the Earth's magnetotail are conducted by Cluster multipoint analysis, so that their force-free feature, i.e., the kind of magnetic field structure satisfying J × B = 0, can be probed directly. It is showed that the selected flux ropes with the bipolar signature of the south-north magnetic field component generally lie near the equatorial plane, as expected, and that the magnetic field gradient is rather weak near the axis center, where the curvature radius is large. The current density (up to several tens of nA/m2) reaches their maximum values as the center is approached. It is found that the stronger the current density, the smaller the angles between the magnetic field and current in MFRs. The direct observations show that only quasi force-free structure is observed, and it tends to appear in the low plasma beta regime (in agreement with the theoretic results). The quasi force-free region is generally found to be embedded in the central portion of the MFRs, where the current is approximately field aligned and proportional to the strength of core field. It is shown that ~60% of surveyed MFRs can be globally approximated as force free. The force-free factor α is found to be nonconstantly varied through the quasi force-free MFR, suggesting that the force-free structure is nonlinear.
Direct optical transitions at K- and H-point of Brillouin zone in bulk MoS2, MoSe2, WS2, and WSe2
NASA Astrophysics Data System (ADS)
Kopaczek, J.; Polak, M. P.; Scharoch, P.; Wu, K.; Chen, B.; Tongay, S.; Kudrawiec, R.
2016-06-01
Modulated reflectance (contactless electroreflectance (CER), photoreflectance (PR), and piezoreflectance (PzR)) has been applied to study direct optical transitions in bulk MoS2, MoSe2, WS2, and WSe2. In order to interpret optical transitions observed in CER, PR, and PzR spectra, the electronic band structure for the four crystals has been calculated from the first principles within the density functional theory for various points of Brillouin zone including K and H points. It is clearly shown that the electronic band structure at H point of Brillouin zone is very symmetric and similar to the electronic band structure at K point, and therefore, direct optical transitions at H point should be expected in modulated reflectance spectra besides the direct optical transitions at the K point of Brillouin zone. This prediction is confirmed by experimental studies of the electronic band structure of MoS2, MoSe2, WS2, and WSe2 crystals by CER, PR, and PzR spectroscopy, i.e., techniques which are very sensitive to critical points of Brillouin zone. For the four crystals besides the A transition at K point, an AH transition at H point has been observed in CER, PR, and PzR spectra a few tens of meV above the A transition. The spectral difference between A and AH transition has been found to be in a very good agreement with theoretical predictions. The second transition at the H point of Brillouin zone (BH transition) overlaps spectrally with the B transition at K point because of small energy differences in the valence (conduction) band positions at H and K points. Therefore, an extra resonance which could be related to the BH transition is not resolved in modulated reflectance spectra at room temperature for the four crystals.
Choudhury, Sharmistha Dutta; Badugu, Ramachandram; Ray, Krishanu; Lakowicz, Joseph R
2015-02-12
Metal-dielectric-metal (MDM) structures provide directional emission close to the surface normal, which offers opportunities for new design formats in fluorescence based applications. The directional emission arises due to near-field coupling of fluorophores with the optical modes present in the MDM substrate. Reflectivity simulations and dispersion diagrams provide a basic understanding of the mode profiles and the factors that affect the coupling efficiency and the spatial distribution of the coupled emission. This work reveals that the composition of the metal layers, the location of the dye in the MDM substrate and the dielectric thickness are important parameters that can be chosen to tune the color of the emission wavelength, the angle of observation, the angular divergence of the emission and the polarization of the emitted light. These features are valuable for displays and optical signage.
Choudhury, Sharmistha Dutta; Badugu, Ramachandram; Ray, Krishanu; Lakowicz, Joseph R.
2015-01-01
Metal-dielectric-metal (MDM) structures provide directional emission close to the surface normal, which offers opportunities for new design formats in fluorescence based applications. The directional emission arises due to near-field coupling of fluorophores with the optical modes present in the MDM substrate. Reflectivity simulations and dispersion diagrams provide a basic understanding of the mode profiles and the factors that affect the coupling efficiency and the spatial distribution of the coupled emission. This work reveals that the composition of the metal layers, the location of the dye in the MDM substrate and the dielectric thickness are important parameters that can be chosen to tune the color of the emission wavelength, the angle of observation, the angular divergence of the emission and the polarization of the emitted light. These features are valuable for displays and optical signage. PMID:25844110
Dynamics of wave packets in two-dimensional random systems with anisotropic disorder.
Samelsohn, Gregory; Gruzdev, Eugene
2008-09-01
A theoretical model is proposed to describe narrowband pulse dynamics in two-dimensional systems with arbitrary correlated disorder. In anisotropic systems with elongated cigarlike inhomogeneities, fast propagation is predicted in the direction across the structure where the wave is exponentially localized and tunneling of evanescent modes plays a dominant role in typical realizations. Along the structure, where the wave is channeled as in a waveguide, the motion of the wave energy is relatively slow. Numerical simulations performed for ultra-wide-band pulses show that even at the initial stage of wave evolution, the radiation diffuses predominantly in the direction along the major axis of the correlation ellipse. Spectral analysis of the results relates the long tail of the wave observed in the transverse direction to a number of frequency domain "lucky shots" associated with the long-living resonant modes localized inside the sample.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ma, Xiang; Zhang, Shuai; Jiao, Fang
Two-step nucleation pathways in which disordered, amorphous, or dense liquid states precede appearance of crystalline phases have been reported for a wide range of materials, but the dynamics of such pathways are poorly understood. Moreover, whether these pathways are general features of crystallizing systems or a consequence of system-specific structural details that select for direct vs two-step processes is unknown. Using atomic force microscopy to directly observe crystallization of sequence-defined polymers, we show that crystallization pathways are indeed sequence dependent. When a short hydrophobic region is added to a sequence that directly forms crystalline particles, crystallization instead follows a two-stepmore » pathway that begins with creation of disordered clusters of 10-20 molecules and is characterized by highly non-linear crystallization kinetics in which clusters transform into ordered structures that then enter the growth phase. The results shed new light on non-classical crystallization mechanisms and have implications for design of self-assembling polymer systems.« less
Dynamics of wave packets in two-dimensional random systems with anisotropic disorder
NASA Astrophysics Data System (ADS)
Samelsohn, Gregory; Gruzdev, Eugene
2008-09-01
A theoretical model is proposed to describe narrowband pulse dynamics in two-dimensional systems with arbitrary correlated disorder. In anisotropic systems with elongated cigarlike inhomogeneities, fast propagation is predicted in the direction across the structure where the wave is exponentially localized and tunneling of evanescent modes plays a dominant role in typical realizations. Along the structure, where the wave is channeled as in a waveguide, the motion of the wave energy is relatively slow. Numerical simulations performed for ultra-wide-band pulses show that even at the initial stage of wave evolution, the radiation diffuses predominantly in the direction along the major axis of the correlation ellipse. Spectral analysis of the results relates the long tail of the wave observed in the transverse direction to a number of frequency domain “lucky shots” associated with the long-living resonant modes localized inside the sample.
NASA Astrophysics Data System (ADS)
Ahmadi-Majlan, Kamyar; Chen, Tongjie; Lim, Zheng Hui; Conlin, Patrick; Hensley, Ricky; Chrysler, Matthew; Su, Dong; Chen, Hanghui; Kumah, Divine P.; Ngai, Joseph H.
2018-05-01
We present electrical and structural characterization of epitaxial LaTiO3/SrTiO3 heterostructures integrated directly on Si(100). By reducing the thicknesses of the heterostructures, an enhancement in carrier-carrier scattering is observed in the Fermi liquid behavior, followed by a metal to insulator transition in the electrical transport. The insulating behavior is described by activated transport, and its onset occurs near an occupation of 1 electron per Ti site within the SrTiO3, providing evidence for a Mott driven transition. We also discuss the role that structure and gradients in strain could play in enhancing the carrier density. The manipulation of Mott metal-insulator behavior in oxides grown directly on Si opens the pathway to harnessing strongly correlated phenomena in device technologies.
Ahmadi-Majlan, Kamyar; Chen, Tongjie; Lim, Zheng Hui; ...
2018-05-07
Here, we present electrical and structural characterization of epitaxial LaTiO 3/SrTiO 3 heterostructures integrated directly on Si(100). By reducing the thicknesses of the heterostructures, an enhancement in carrier-carrier scattering is observed in the Fermi liquid behavior, followed by a metal to insulator transition in the electrical transport. The insulating behavior is described by activated transport, and its onset occurs near 1 electron per Ti occupation within the SrTiO 3 well, providing evidence for a Mott driven transition. We also discuss the role that structure and gradients in strain could play in enhancing the carrier density. The manipulation of Mott metal-insulatormore » behavior in oxides grown directly on Si opens the pathway to harnessing strongly correlated phenomena in device technologies.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ahmadi-Majlan, Kamyar; Chen, Tongjie; Lim, Zheng Hui
Here, we present electrical and structural characterization of epitaxial LaTiO 3/SrTiO 3 heterostructures integrated directly on Si(100). By reducing the thicknesses of the heterostructures, an enhancement in carrier-carrier scattering is observed in the Fermi liquid behavior, followed by a metal to insulator transition in the electrical transport. The insulating behavior is described by activated transport, and its onset occurs near 1 electron per Ti occupation within the SrTiO 3 well, providing evidence for a Mott driven transition. We also discuss the role that structure and gradients in strain could play in enhancing the carrier density. The manipulation of Mott metal-insulatormore » behavior in oxides grown directly on Si opens the pathway to harnessing strongly correlated phenomena in device technologies.« less
First-principles study of direct and narrow band gap semiconducting β -CuGaO 2
Nguyen, Manh Cuong; Zhao, Xin; Wang, Cai-Zhuang; ...
2015-04-16
Semiconducting oxides have attracted much attention due to their great stability in air or water and the abundance of oxygen. Recent success in synthesizing a metastable phase of CuGaO 2 with direct narrow band gap opens up new applications of semiconducting oxides as absorber layer for photovoltaics. Using first-principles density functional theory calculations, we investigate the thermodynamic and mechanical stabilities as well as the structural and electronic properties of the β-CuGaO 2 phase. Our calculations show that the β-CuGaO 2 structure is dynamically and mechanically stable. The energy band gap is confirmed to be direct at the Γ point ofmore » Brillouin zone. In conclusion, the optical absorption occurs right at the band gap edge and the density of states near the valance band maximum is large, inducing an intense absorption of light as observed in experiment.« less
Distances, Kinematics, And Structure Of The Orion Complex
NASA Astrophysics Data System (ADS)
Kounkel, Marina; Hartmann, Lee
2018-01-01
I present an analysis of the structure and kinematics of the Orion Molecular Cloud Complex in an effort to better characterize the dynamical state of the closest region of ongoing massive star formation. I measured stellar parallax and proper motions with <5% uncertainty using radio VLBI observations of non-thermally-emitting sources located in various star forming regions within the Orion Complex. This includes the first direct distance measurements for sources that are located outside of the Orion Nebula. I identified a number of binary systems in the VLBI dataset and fitted their orbital motion, which allows for the direct measurement of the masses of the individual components. Additionally, I have identified several stars that have been ejected from the Orion Nebula due to strong gravitational interactions with the most massive members. I complemented the parallax and proper motion measurements with the observations of optical radial velocities of the stars toward the Orion Complex, probing the histories of both dynamic evolution and star formation in the region, providing a 6-dimensional model of the Complex. These observations can serve as a baseline for comparison of the upcoming results from the Gaia space telescope
NASA Astrophysics Data System (ADS)
Judson, Richard S.; Rabitz, Herschel
1987-04-01
The relationship between structure in the potential surface and classical mechanical observables is examined by means of functional sensitivity analysis. Functional sensitivities provide maps of the potential surface, highlighting those regions that play the greatest role in determining the behavior of observables. A set of differential equations for the sensitivities of the trajectory components are derived. These are then solved using a Green's function method. It is found that the sensitivities become singular at the trajectory turning points with the singularities going as η-3/2, with η being the distance from the nearest turning point. The sensitivities are zero outside of the energetically and dynamically allowed region of phase space. A second set of equations is derived from which the sensitivities of observables can be directly calculated. An adjoint Green's function technique is employed, providing an efficient method for numerically calculating these quantities. Sensitivity maps are presented for a simple collinear atom-diatom inelastic scattering problem and for two Henon-Heiles type Hamiltonians modeling intramolecular processes. It is found that the positions of the trajectory caustics in the bound state problem determine regions of the highest potential surface sensitivities. In the scattering problem (which is impulsive, so that ``sticky'' collisions did not occur), the positions of the turning points of the individual trajectory components determine the regions of high sensitivity. In both cases, these lines of singularities are superimposed on a rich background structure. Most interesting is the appearance of classical interference effects. The interference features in the sensitivity maps occur most noticeably where two or more lines of turning points cross. The important practical motivation for calculating the sensitivities derives from the fact that the potential is a function, implying that any direct attempt to understand how local potential regions affect the behavior of the observables by repeatedly and systematically altering the potential will be prohibitively expensive. The functional sensitivity method enables one to perform this analysis at a fraction of the computational labor required for the direct method.
NASA Astrophysics Data System (ADS)
Velusamy, T.
2010-07-01
The 1.9 THz [CII] observations provide a powerful probe of warm diffuse clouds, because they can observe them in emission and are useful as a tracer of their molecular H2 not directly traced by CO or other means. HIFI observations of [CII] provide a high resolution of 12 arcsec, better than that for single dish CO (> 30 arcsec) maps, and much better than HI (>30 arcsec). Thus with HIFI we have an opportunity probe the small scale structures in diffuse clouds in the inner Galaxy at distances > 3 kpc. To study the structure of diffuse ISM gas at small scales we propose HIFI maps of 1.9 THz (158 micron) [CII] line emission in a selection of 16 lines of sight (LOSs) towards the inner Galaxy, which are also being observed as part of the GOT C+ survey of [CII] in the Galactic plane. GOT C+ provides mainly single point spectra without any spatial data. Maps of [CII] will constrain better the cloud properties and models when combining [CII] and HI data. The proposed OTF X map will be along the longitude and latitude centered on 18 selected GOT C+ LOS over a length of 3 arcmin in each direction, which is adequate enough to provide sufficient spatial information on the small scale structures at larger distances (>3 kpc) and to characterize the CII filling factor in the larger beams of the ancillary (HI, CO, and CI data). The [CI] 609 & 370micron and the 12CO(7-6) (which lies within the CI band) are excellent diagnostics of the physical conditions of transition clouds and PDRs. We will use the ratio of the [CI] lines to constrain the kinetic temperature and volume density of the CII/CI/CO transition zones in molecular clouds using radiative transfer codes. We also propose OTF X maps in both the [CI] lines for all CII target LOSs. We anticipate fully resolved structural data in [CII] on at least 300 velocity resolved clouds along with their [CI] emissions. We request a total of 33.2 hrs of HIFI observing time.
NASA Astrophysics Data System (ADS)
Zhou, Yun; Li, Xiao-Hong; Wang, Jian-Feng; Zhou, Hao-Miao; Cao, Dan; Jiao, Zhi-Wei; Xu, Long; Li, Qi-Hao
2018-04-01
The direct and converse magnetoelectric hysteresis behavior for a tri-layered composite has been comparatively investigated and significant similarities have been observed. The results show that both the direct and converse magnetoelectric hysteresis is deeply affected by the bias magnetic field and test period. The test time hysteresis caused by a fast varying bias magnetic field can be reduced by prolonging the test period. The observed coercive field, remanence, and ratio of remanence of the direct and converse magnetoelectric effects with the test period obey an exponential decay law. A hysteretic nonlinear magnetoelectric theoretical model for the symmetrical tri-layered structure has been proposed based on a nonlinear constitutive model and pinning effect. The numerical calculation shows that the theoretical results are in good agreement with the experimental results. These findings not only provide insight into the examination and practical applications of magnetoelectric materials, but also propose a theoretical frame for studying the hysteretic characteristics of the magnetoelectric effect.
Comparative In Situ Measurements of Plasma Instabilities in the Equatorial and Auroral Electrojets
NASA Technical Reports Server (NTRS)
Pfaff, Robert F.
2008-01-01
This presentation provides a comparison of in situ measurements of plasma instabilities gathered by rocket-borne probes in the equatorial and auroral electrojets. Specifically, using detailed measurements of the DC electric fields, current density, and plasma number density within the unstable daytime equatorial electrojet from Brazil (Guara Campaign) and in the auroral electrojet from Sweden (ERRIS Campaign), we present comparative observations and general conclusions regarding the observed physical properties of Farley-Buneman two-stream waves and large scale, gradient drift waves. The two stream observations reveal coherent-like waves propagating near the E x B direction but at reduced speeds (nearer to the presumed acoustic velocity) with wavelengths of approximately 5-10m in both the equatorial and auroral electrojet, as measured using the spaced-receiver technique. The auroral electrojet data generally shows extensions to shorter wavelengths, in concert with the fact that these waves are driven harder. With respect to gradient-drift driven waves, observations of this instability are much more pronounced in the equatorial electrojet, given the more favorable geometry for growth provided by the vertical gradient and horizontal magnetic field lines. We present new analysis of Guara rocket observations of electric field and plasma density data that reveal considerable structuring in the middle and lower portion of the electrojet (90-105 km) where the ambient plasma density gradient is unstable. Although the electric field amplitudes are largest (approximately 10-15 mV/m) in the zonal direction, considerable structure (approximately 5-10 mV/m) is also observed in the vertical electric field component as well, implying that the dominant large scale waves involve significant vertical interaction and coupling within the narrow altitude range where they are observed. Furthermore, a detailed examination of the phase of the waveforms show that on some, but not all occasions, locally enhanced eastward fields are associated with locally enhanced upwards (polarization) electric fields. The measurements are discussed in terms of theories involving the non-linear evolution and structuring of plasma waves.
Nonequilibrium phase transitions in cuprates observed by ultrafast electron crystallography.
Gedik, Nuh; Yang, Ding-Shyue; Logvenov, Gennady; Bozovic, Ivan; Zewail, Ahmed H
2007-04-20
Nonequilibrium phase transitions, which are defined by the formation of macroscopic transient domains, are optically dark and cannot be observed through conventional temperature- or pressure-change studies. We have directly determined the structural dynamics of such a nonequilibrium phase transition in a cuprate superconductor. Ultrafast electron crystallography with the use of a tilted optical geometry technique afforded the necessary atomic-scale spatial and temporal resolutions. The observed transient behavior displays a notable "structural isosbestic" point and a threshold effect for the dependence of c-axis expansion (Deltac) on fluence (F), with Deltac/F = 0.02 angstrom/(millijoule per square centimeter). This threshold for photon doping occurs at approximately 0.12 photons per copper site, which is unexpectedly close to the density (per site) of chemically doped carriers needed to induce superconductivity.
Statistical survey of day-side magnetospheric current flow using Cluster observations: magnetopause
NASA Astrophysics Data System (ADS)
Liebert, Evelyn; Nabert, Christian; Perschke, Christopher; Fornaçon, Karl-Heinz; Glassmeier, Karl-Heinz
2017-05-01
We present a statistical survey of current structures observed by the Cluster spacecraft at high-latitude day-side magnetopause encounters in the close vicinity of the polar cusps. Making use of the curlometer technique and the fluxgate magnetometer data, we calculate the 3-D current densities and investigate the magnetopause current direction, location, and magnitude during varying solar wind conditions. We find that the orientation of the day-side current structures is in accordance with existing magnetopause current models. Based on the ambient plasma properties, we distinguish five different transition regions at the magnetopause surface and observe distinctive current properties for each region. Additionally, we find that the location of currents varies with respect to the onset of the changes in the plasma environment during magnetopause crossings.
Iridescence of a Marine Bacterium and Classification of Prokaryotic Structural Colors
Vukusic, Peter; Luke, Stephen
2012-01-01
Iridescence is a property of structural color that is occasionally encountered in higher eukaryotes but that has been poorly documented in the prokaryotic kingdom. In the present work, we describe a marine bacterium, identified as Cellulophaga lytica, isolated from the surface of an anemone, that exhibits bright green iridescent colonies under direct epi-illumination. This phenomenon has not previously been investigated in detail. In this study, color changes of C. lytica colonies were observed at various angles of direct illumination or observation. Its iridescent green appearance was dominant on various growth media. Red and violet colors were also discerned on colony edges. Remarkable C. lytica bacterial iridescence was revealed and characterized using high-resolution optical spectrometry. In addition to this, by culturing other bacterial strains to which various forms of faintly iridescent traits have previously been attributed, we identify four principal appearance characteristics of structural color in prokaryotes. A new general classification of bacterial iridescence is therefore proposed in this study. Furthermore, a specific separate class is described for iridescent C. lytica strains because they exhibit what is so far a unique intense glitter-like iridescence in reflection. C. lytica is the first prokaryote discovered to produce the same sort of intense iridescence under direct illumination as that associated with higher eukaryotes, like some insects and birds. Due to the nature of bacterial biology, cultivation, and ubiquity, this discovery may be of significant interest for both ecological and nanoscience endeavors. PMID:22267664
NASA Astrophysics Data System (ADS)
Moctezuma, R. E.; Arauz-Lara, J. L.; Donado, F.
2018-04-01
The structure of a two-dimensional magnetic granular system was determined by multifractal and Voronoi polygon analysis for a wide range of particle concentrations. Randomizing of the particle motions are produced by applying to the system a time-dependent sinusoidal magnetic field directed along the vertical direction. Both repulsive and attractive short-range interactions between the particles are induced. A direct observation of such system shows qualitatively that, as particle concentration increases, the structure evolves from being liquid-like at low particle concentrations to solid-like at high concentrations. We observe the formation of clusters which are small and weakly bonded and short-lived at low concentrations. Above a threshold particle concentration, clusters grow larger and are more strongly attached. In the system, one can distinguish the mobile particles from the immobile particles belonging to clusters, they can be considered separately as two different phases, a fluid and a solid. We determined the information entropy of the system as a whole and separately from each phase as particle concentration increases. The distribution of the Voronoi polygon areas are well fitted by a two-parameter gamma distribution and we have found that the regularity factor shows a notable change when pieces of the solid phase start to form. The methods we use here show that they can use even when the system is heterogeneous and they provide information when changes start.
On the mechanism of elasto-inertial turbulence.
Dubief, Yves; Terrapon, Vincent E; Soria, Julio
2013-11-01
Elasto-inertial turbulence (EIT) is a new state of turbulence found in inertial flows with polymer additives. The dynamics of turbulence generated and controlled by such additives is investigated from the perspective of the coupling between polymer dynamics and flow structures. Direct numerical simulations of channel flow with Reynolds numbers ranging from 1000 to 6000 (based on the bulk and the channel height) are used to study the formation and dynamics of elastic instabilities and their effects on the flow. The flow topology of EIT is found to differ significantly from Newtonian wall-turbulence. Structures identified by positive (rotational flow topology) and negative (extensional/compressional flow topology) second invariant Q a isosurfaces of the velocity gradient are cylindrical and aligned in the spanwise direction. Polymers are significantly stretched in sheet-like regions that extend in the streamwise direction with a small upward tilt. The Q a cylindrical structures emerge from the sheets of high polymer extension, in a mechanism of energy transfer from the fluctuations of the polymer stress work to the turbulent kinetic energy. At subcritical Reynolds numbers, EIT is observed at modest Weissenberg number ( Wi , ratio polymer relaxation time to viscous time scale). For supercritical Reynolds numbers, flows approach EIT at large Wi . EIT provides new insights on the nature of the asymptotic state of polymer drag reduction (maximum drag reduction), and explains the phenomenon of early turbulence, or onset of turbulence at lower Reynolds numbers than for Newtonian flows observed in some polymeric flows.
On the mechanism of elasto-inertial turbulence
NASA Astrophysics Data System (ADS)
Dubief, Yves; Terrapon, Vincent E.; Soria, Julio
2013-11-01
Elasto-inertial turbulence (EIT) is a new state of turbulence found in inertial flows with polymer additives. The dynamics of turbulence generated and controlled by such additives is investigated from the perspective of the coupling between polymer dynamics and flow structures. Direct numerical simulations of channel flow with Reynolds numbers ranging from 1000 to 6000 (based on the bulk and the channel height) are used to study the formation and dynamics of elastic instabilities and their effects on the flow. The flow topology of EIT is found to differ significantly from Newtonian wall-turbulence. Structures identified by positive (rotational flow topology) and negative (extensional/compressional flow topology) second invariant Qa isosurfaces of the velocity gradient are cylindrical and aligned in the spanwise direction. Polymers are significantly stretched in sheet-like regions that extend in the streamwise direction with a small upward tilt. The Qa cylindrical structures emerge from the sheets of high polymer extension, in a mechanism of energy transfer from the fluctuations of the polymer stress work to the turbulent kinetic energy. At subcritical Reynolds numbers, EIT is observed at modest Weissenberg number (Wi, ratio polymer relaxation time to viscous time scale). For supercritical Reynolds numbers, flows approach EIT at large Wi. EIT provides new insights on the nature of the asymptotic state of polymer drag reduction (maximum drag reduction), and explains the phenomenon of early turbulence, or onset of turbulence at lower Reynolds numbers than for Newtonian flows observed in some polymeric flows.
On the mechanism of elasto-inertial turbulence
Dubief, Yves; Terrapon, Vincent E.; Soria, Julio
2013-01-01
Elasto-inertial turbulence (EIT) is a new state of turbulence found in inertial flows with polymer additives. The dynamics of turbulence generated and controlled by such additives is investigated from the perspective of the coupling between polymer dynamics and flow structures. Direct numerical simulations of channel flow with Reynolds numbers ranging from 1000 to 6000 (based on the bulk and the channel height) are used to study the formation and dynamics of elastic instabilities and their effects on the flow. The flow topology of EIT is found to differ significantly from Newtonian wall-turbulence. Structures identified by positive (rotational flow topology) and negative (extensional/compressional flow topology) second invariant Qa isosurfaces of the velocity gradient are cylindrical and aligned in the spanwise direction. Polymers are significantly stretched in sheet-like regions that extend in the streamwise direction with a small upward tilt. The Qa cylindrical structures emerge from the sheets of high polymer extension, in a mechanism of energy transfer from the fluctuations of the polymer stress work to the turbulent kinetic energy. At subcritical Reynolds numbers, EIT is observed at modest Weissenberg number (Wi, ratio polymer relaxation time to viscous time scale). For supercritical Reynolds numbers, flows approach EIT at large Wi. EIT provides new insights on the nature of the asymptotic state of polymer drag reduction (maximum drag reduction), and explains the phenomenon of early turbulence, or onset of turbulence at lower Reynolds numbers than for Newtonian flows observed in some polymeric flows. PMID:24170968
Patterned Liquid Metal Contacts for Printed Carbon Nanotube Transistors.
Andrews, Joseph B; Mondal, Kunal; Neumann, Taylor V; Cardenas, Jorge A; Wang, Justin; Parekh, Dishit P; Lin, Yiliang; Ballentine, Peter; Dickey, Michael D; Franklin, Aaron D
2018-05-14
Flexible and stretchable electronics are poised to enable many applications that cannot be realized with traditional, rigid devices. One of the most promising options for low-cost stretchable transistors are printed carbon nanotubes (CNTs). However, a major limiting factor in stretchable CNT devices is the lack of a stable and versatile contact material that forms both the interconnects and contact electrodes. In this work, we introduce the use of eutectic gallium-indium (EGaIn) liquid metal for electrical contacts to printed CNT channels. We analyze thin-film transistors (TFTs) fabricated using two different liquid metal deposition techniques-vacuum-filling polydimethylsiloxane (PDMS) microchannel structures and direct-writing liquid metals on the CNTs. The highest performing CNT-TFT was realized using vacuum-filled microchannel deposition with an in situ annealing temperature of 150 °C. This device exhibited an on/off ratio of more than 10 4 and on-currents as high as 150 μA/mm-metrics that are on par with other printed CNT-TFTs. Additionally, we observed that at room temperature the contact resistances of the vacuum-filled microchannel structures were 50% lower than those of the direct-write structures, likely due to the poor adhesion between the materials observed during the direct-writing process. The insights gained in this study show that stretchable electronics can be realized using low-cost and solely solution processing techniques. Furthermore, we demonstrate methods that can be used to electrically characterize semiconducting materials as transistors without requiring elevated temperatures or cleanroom processes.
NASA Astrophysics Data System (ADS)
Prabowo, A. R.; Baek, S. J.; Lee, S. G.; Bae, D. M.; Sohn, J. M.
2018-01-01
Phenomena of impact loads on the marine structures has attracted attention to be predicted regarding its influences to structural damage. This part demands sustainable analysis and observation as tendency may vary from one to others since impact involves various scenario models and the structure itself experiences continuous development. Investigation of the damage extent can be conducted by observation on the energy behaviour during two entities involve in a contact. This study aimed to perform numerical investigation to predict structural damage by assessing absorbed strain energy represented by the internal energy during a series of ship collisions. The collision target in ship-ship interactions were determined on the single and double hulls part of a passenger ship. Tendency of the internal energy by the steel structures was summarized, and verification was presented by several crashworthiness criteria. It was found that steel structures applied by the material grades A and B produced different tendencies compared to the material grades D and E. Effect of the structural arrangement to structural responses in terms of strain and stress indicated that the single hull presented contour expansion mainly on the longitudinal directions.
Observational Evidence For The Comet-Like Heliosphere
NASA Astrophysics Data System (ADS)
Bzowski, M.; Czechowski, A.; Funsten, H. O.; Grygorczuk, J.; Heerikhuisen, J.; Kubiak, M. A.; Moebius, E.; McComas, D. J.; Schwadron, N.; Sokol, J. M.; Swaczyna, P.; Zirnstein, E.
2017-12-01
The shape of the heliosphere is a subject of ongoing debate. The traditional comet-like image has recently been challenged by ideas of croissant- or bubble-like forms. Here we seek to resolve this debate by confronting available observational evidence with global modeling. Several MHD models of a comet-like heliosphere were used to simulate the radius and center of the IBEX Ribbon to fit the direction and intensity of the interstellar magnetic field (ISMF). These models assumed the secondary ENA emission mechanism, which was recently strengthened due to direct measurement of the distance to the Ribbon source most likely just beyond the heliopause. The same mechanism explains the dependence of the Ribbon center position on energy due to the latitudinal structure of solar wind. The obtained ISMF vector agrees among these models and is consistent with the draped IMF measured by Voyager. Independently, we have shown by modeling that the Warm Breeze discovered by IBEX is naturally created in the outer heliosheath due to charge-exchange between interstellar He+ ions and He atoms. Now we simulate the Warm Breeze for various directions and intensities of the local IMF and we find that the simulation results are in best agreement with IBEX observations for the IMF vector obtained from the above-mentioned Ribbon analyses and Voyager measurements. These arguments, along with the co-planarity of the inflow directions of interstellar neutral H, He, O, and the Warm Breeze, directions of the Ribbon center and ISMF, as well as measurements of the plasma flow directions in the IHS by Voyager 2 indicate the existence of a common plane of approximate mirror symmetry of the heliosphere, defined by the directions of ISMF and the Sun's motion through the local interstellar medium. This suggests that the global structure of the outer heliosphere mostly results from the conditions in the local interstellar medium and the Sun's velocity. This evidence, obtained from very different spacecraft and measurement techniques, supports a homogeneous and consistent picture of the heliosphere with a comet-like shape and organized by the plane of approximate mirror symmetry.
The structure and mechanics of Moso bamboo material
Dixon, P. G.; Gibson, L. J.
2014-01-01
Although bamboo has been used structurally for millennia, there is currently increasing interest in the development of renewable and sustainable structural bamboo products (SBPs). These SBPs are analogous to wood products such as plywood, oriented strand board and glue-laminated wood. In this study, the properties of natural Moso bamboo (Phyllostachys pubescens) are investigated to further enable the processing and design of SBPs. The radial and longitudinal density gradients in bamboo give rise to variations in the mechanical properties. Here, we measure the flexural properties of Moso bamboo in the axial direction, along with the compressive strengths in the axial and transverse directions. Based on the microstructural variations (observed with scanning electron microscopy) and extrapolated solid cell wall properties of bamboo, we develop models, which describe the experimental results well. Compared to common North American construction woods loaded along the axial direction, Moso bamboo is approximately as stiff and substantially stronger, in both flexure and compression but denser. This work contributes to critical knowledge surrounding the microstructure and mechanical properties of bamboo, which are vital to the engineering and design of sustainable SBPs. PMID:25056211
NASA Astrophysics Data System (ADS)
Ayarcı Kuruoğlu, Neslihan; Özdemir, Orhan; Bozkurt, Kutsal; Sundaram, Suresh; Salvestrini, Jean-Paul; Ougazzaden, Abdallah; Gaimard, Quentin; Belahsene, Sofiane; Merghem, Kamel; Ramdane, Abderrahim
2017-12-01
The electrical response of gallium nitride (GaN), produced through metal-organic chemical vapor deposition in a p-i-n structure was investigated through temperature-dependent current-voltage (I-V) and admittance measurement. The I-V curves showed double diode behavior together with several distinct regions in which trap-assisted tunnelling current has been identified at low and moderate forward/reverse direction and space charge limited current (SCLC) at large forward/reverse bias. The value of extracted energy (˜200 meV in forward and ˜70 meV in reverse direction) marked the tunnelling entity as electron and heavy hole in the present structure. These values were also obtained in space charge limited regime and considered as minority carriers which might originate the experimentally observed negative capacitance issue at low frequencies over the junction under both forward and reverse bias directions. Analytically derived expression for the admittance in the revised versions of SCLC model was also applied to explain the inductance effect, yielding good fits to the experimentally measured admittance data.
NASA Astrophysics Data System (ADS)
Paganelli, F.; Schubert, G.; Lopes, R. M. C.; Malaska, M.; Le Gall, A. A.; Kirk, R. L.
2016-12-01
The current SAR data coverage on Titan encompasses several areas in which multiple radar passes are present and overlapping, providing additional information to aid the interpretation of geological and structural features. We exploit the different combinations of look direction and variable incidence angle to examine Cassini Synthetic Aperture RADAR (SAR) data using the Principal Component Analysis (PCA) technique and high-resolution radiometry, as a tool to aid in the interpretation of geological and structural features. Look direction and variable incidence angle is of particular importance in the analysis of variance in the images, which aid in the perception and identification of geological and structural features, as extensively demonstrated in Earth and planetary examples. The PCA enhancement technique uses projected non-ortho-rectified SAR imagery in order to maintain the inherent differences in scattering and geometric properties due to the different look directions, while enhancing the geometry of surface features. The PC2 component provides a stereo view of the areas in which complex surface features and structural patterns can be enhanced and outlined. We focus on several areas of interest, in older and recently acquired flybys, in which evidence of geological and structural features can be enhanced and outlined in the PC1 and PC2 components. Results of this technique provide enhanced geometry and insights into the interpretation of the observed geological and structural features, thus allowing a better understanding towards the geology and tectonics on Titan.
The use of community pharmacies in North West England: an observational study.
Mackridge, Adam J; Stokes, Elizabeth C; Gray, Nicola J
2017-04-01
There are few studies of community pharmacy footfall and activity in the existing literature, especially by direct observation. To describe the characteristics of counter interactions between pharmacy staff and customers. Structured observation of all interactions between pharmacy staff and customers across the weekly opening hours of five pharmacies diverse in location and ownership. Three-quarters (76%) of observed interactions were associated with prescriptions, but a significant minority accessed cognitive services. Dispensing was the primary activity across the diverse range of pharmacies. Reasons for visits are diversifying into advice and services, particularly among younger users. © 2016 Royal Pharmaceutical Society.
Exploring dynamic events in the solar corona
NASA Astrophysics Data System (ADS)
Downs, Cooper James
With the advent of modern computational technology it is now becoming the norm to employ detailed 3D computer models as empirical tools that directly account for the inhomogeneous nature of the Sun-Heliosphere environment. The key advantage of this approach lies in the ability to compare model results directly to observational data and to use a successful comparison (or lack thereof) to glean information on the underlying physical processes. Using extreme ultraviolet waves (EUV waves) as the overarching scientific driver, we apply this observation modeling approach to study the complex dynamics of the magnetic and thermodynamic structures that are observed in the low solar corona. Representing a highly non-trivial effort, this work includes three main scientific thrusts: an initial modeling effort and two EUV wave case-studies. First we document the development of the new Low Corona (LC) model, a 3D time-dependent thermodynamic magnetohydrodynamic (MHD) model implemented within the Space Weather Modeling Framework (SWMF). Observation synthesis methods are integrated within the LC model, which provides the ability to compare model results directly to EUV imaging observations taken by spacecraft. The new model is then used to explore the dynamic interplay between magnetic structures and thermodynamic energy balance in the corona that is caused by coronal heating mechanisms. With the model development complete, we investigate the nature of EUV waves in detail through two case-studies. Starting with the 2008 March 25 event, we conduct a series of numerical simulations that independently vary fundamental parameters thought to govern the physical mechanisms behind EUV waves. Through the subsequent analysis of the 3D data and comparison to observations we find evidence for both wave and non-wave mechanisms contributing to the EUV wave signal. We conclude with a comprehensive observation and modeling analysis of the 2010 June 13 EUV wave event, which was observed by the recently launched Solar Dynamics Observatory. We use a high resolution simulation of the transient to unambiguously characterize the globally propagating front of EUV wave as a fast-mode magnetosonic wave, and use the rich set of observations to place the many other facets of the EUV transient within a unified scenario involving wave and non-wave components.
MMS Observations of a Hot Flow Anomaly in the Magnetosheath
NASA Astrophysics Data System (ADS)
Zhang, H.; Le, G.; Sibeck, D. G.
2017-12-01
Hot flow anomalies (HFAs) are events observed near planetary bow shocks that are characterized by greatly heated solar wind plasmas and substantial flow deflection. HFAs are universal phenomena that have been observed near the bow shock of Earth, Venus, Mars, and Saturn. The dynamic pressure inside HFAs is lower than the ambient solar wind due to the density depletion and flow deflection. The passage of HFAs will therefore result in local negative pressure impulses, which lead to a local sunward expansion of the magnetopause. NASA's MMS mission produce unprecedented high resolution data, which enable the observations of HFA structures in great details. We report MMS observations of an HFA in the post-noon magnetosheath which lasted 25 minutes. Sunward and dawnward plasma flow was observed in the core of the HFA, which is in the opposite direction of the plasma flow in the ambient magnetosheath. The plasma density in the HFA was about one order of magnitude lower than that in the ambient magnetosheath. Two magnetopause crossings were observed inside the HFA. Boundary normal analysis shows the normal direction of the magnetopause was along the GSE Y direction, indicating a strongly deformed magnetopause. The first in, first out crossing sequence of the magnetopause by multiple spacecraft also indicates that the two magnetopause crossings were due to a bulged-out magnetopause rather than the back and forth motion of the magnetopause.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Light, Samuel H.; Minasov, George; Shuvalova, Ludmilla
2012-04-18
Dehydroquinate dehydratase (DHQD) catalyzes the third step in the biosynthetic shikimate pathway. We present three crystal structures of the Salmonella enterica type I DHQD that address the functionality of a surface loop that is observed to close over the active site following substrate binding. Two wild-type structures with differing loop conformations and kinetic and structural studies of a mutant provide evidence of both direct and indirect mechanisms of involvement of the loop in substrate binding. In addition to allowing amino acid side chains to establish a direct interaction with the substrate, closure of the loop necessitates a conformational change ofmore » a key active site arginine, which in turn positions the substrate productively. The absence of DHQD in humans and its essentiality in many pathogenic bacteria make the enzyme a target for the development of nontoxic antimicrobials. The structures and ligand binding insights presented here may inform the design of novel type I DHQD inhibiting molecules.« less
Modification of planetary atmospheres by material from the rings
NASA Technical Reports Server (NTRS)
Atreya, S. K.
1984-01-01
The modification of the atmospheres and ionospheres of ringed planets by the injection of ionized and neutral material from the rings is discussed, on the basis of Pioneer and Voyager observations. It is shown that although no direct evidence exists for the injection of material from the rings into the atmosphere, such an interaction could account for the observed thermal structure and ionospheric properties of Jupiter, Saturn, Uranus, and the Jovian satellite Io.
NASA Astrophysics Data System (ADS)
Iyemori, Toshihiko; Nakanishi, Kunihito; Aoyama, Tadashi; Lühr, Hermann
2014-05-01
Acoustic gravity waves propagated to the ionosphere cause dynamo currents in the ionosphere. They divert along geomagnetic field lines of force to another hemisphere accompanying electric field and then flow in the ionosphere of another hemisphere by the electric field forming closed current circuits. The oscillating current circuits with the period of acoustic waves generate magnetic variations on the ground, and they are observed as long period geomagnetic pulsations. This effect has been detected during big earthquakes, strong typhoons, tornados etc. On a low-altitude satellite orbit, the spatial distribution (i.e., structure) of the current circuits along the satellite orbit should be detected as temporal magnetic oscillations, and the effect is confirmed by a CHAMP data analysis. On the spatial structure, in particular, in the longitudinal direction, it has been difficult to examine by a single satellite or from ground magnetic observations. The SWARM satellites will provide an unique opportunity to clarify the three dimensional structure of the field-aligned current circuits.
Atomic Resolution Study of the Interfacial Bonding at Si3N4/CeO2-δ Grain Boundaries
NASA Astrophysics Data System (ADS)
Klie, Robert F.; Walkosz, Weronika; Ogut, Serdar; Borisevich, A.; Becher, Paul F.; Pennycook, Steve J.; Idrobo, Juan C.
2008-03-01
Using a combination of atomic resolution Z-contrast imaging and electron energy-loss spectroscopy (EELS) in the scanning transmission electron microscope, we examine the atomic and electronic structures at the interface between Si3N4 (10 10) and CeO2-δ inter-granular film (IGF). Ce atoms are observed to segregate to the interface in a two-layer periodic arrangement, which is significantly different compared to the structure observed in a previous study. Our EELS experiments show that (i) oxygen is present at the interface in direct contact with the terminating Si3N4 open-ring structures, (ii) the Ce valence state changes from +3 to +4 in going from the interface into the IGF, and (iii) while the N concentration decreases away from the Si3N4 grains into the IGF, the Si concentration remains uniform across the whole width of the IGF. Possible reasons for these observed structural and electronic variations at the interface and their implications for future studies on Si3N4/rare-earth oxide interfaces are briefly discussed.
Servidio, S; Chasapis, A; Matthaeus, W H; Perrone, D; Valentini, F; Parashar, T N; Veltri, P; Gershman, D; Russell, C T; Giles, B; Fuselier, S A; Phan, T D; Burch, J
2017-11-17
Plasma turbulence is investigated using unprecedented high-resolution ion velocity distribution measurements by the Magnetospheric Multiscale mission (MMS) in the Earth's magnetosheath. This novel observation of a highly structured particle distribution suggests a cascadelike process in velocity space. Complex velocity space structure is investigated using a three-dimensional Hermite transform, revealing, for the first time in observational data, a power-law distribution of moments. In analogy to hydrodynamics, a Kolmogorov approach leads directly to a range of predictions for this phase-space transport. The scaling theory is found to be in agreement with observations. The combined use of state-of-the-art MMS data sets, novel implementation of a Hermite transform method, and scaling theory of the velocity cascade opens new pathways to the understanding of plasma turbulence and the crucial velocity space features that lead to dissipation in plasmas.
NASA Astrophysics Data System (ADS)
Sergienko, O. V.
2013-12-01
The direct observations of the basal conditions under continental-scale ice sheets are logistically impossible. A possible approach to estimate conditions at the ice - bed interface is from surface observations by means of inverse methods. The recent advances in remote and ground-based observations have allowed to acquire a wealth observations from Greenland and Antarctic ice sheets. Using high-resolution data sets of ice surface and bed elevations and surface velocities, inversions for basal conditions have been performed for several ice streams in Greenland and Antarctica. The inversion results reveal the wide-spread presence of rib-like spatial structures in basal shear. The analysis of the hydraulic potential distribution shows that these rib-like structures co-locate with highs of the gradient of hydraulic potential. This suggests that subglacial water plays a role in the development and evolution of the basal shear ribs.
On crystal versus fiber formation in dipeptide hydrogelator systems.
Houton, Kelly A; Morris, Kyle L; Chen, Lin; Schmidtmann, Marc; Jones, James T A; Serpell, Louise C; Lloyd, Gareth O; Adams, Dave J
2012-06-26
Naphthalene dipeptides have been shown to be useful low-molecular-weight gelators. Here we have used a library to explore the relationship between the dipeptide sequence and the hydrogelation efficiency. A number of the naphthalene dipeptides are crystallizable from water, enabling us to investigate the comparison between the gel/fiber phase and the crystal phase. We succeeded in crystallizing one example directly from the gel phase. Using X-ray crystallography, molecular modeling, and X-ray fiber diffraction, we show that the molecular packing of this crystal structure differs from the structure of the gel/fiber phase. Although the crystal structures may provide important insights into stabilizing interactions, our analysis indicates a rearrangement of structural packing within the fibers. These observations are consistent with the fibrillar interactions and interatomic separations promoting 1D assembly whereas in the crystals the peptides are aligned along multiple axes, allowing 3D growth. This observation has an impact on the use of crystal structures to determine supramolecular synthons for gelators.
Role of Structural Dynamics at the Receptor G Protein Interface for Signal Transduction.
Rose, Alexander S; Zachariae, Ulrich; Grubmüller, Helmut; Hofmann, Klaus Peter; Scheerer, Patrick; Hildebrand, Peter W
2015-01-01
GPCRs catalyze GDP/GTP exchange in the α-subunit of heterotrimeric G proteins (Gαßγ) through displacement of the Gα C-terminal α5 helix, which directly connects the interface of the active receptor (R*) to the nucleotide binding pocket of G. Hydrogen-deuterium exchange mass spectrometry and kinetic analysis of R* catalysed G protein activation have suggested that displacement of α5 starts from an intermediate GDP bound complex (R*•GGDP). To elucidate the structural basis of receptor-catalysed displacement of α5, we modelled the structure of R*•GGDP. A flexible docking protocol yielded an intermediate R*•GGDP complex, with a similar overall arrangement as in the X-ray structure of the nucleotide free complex (R*•Gempty), however with the α5 C-terminus (GαCT) forming different polar contacts with R*. Starting molecular dynamics simulations of GαCT bound to R* in the intermediate position, we observe a screw-like motion, which restores the specific interactions of α5 with R* in R*•Gempty. The observed rotation of α5 by 60° is in line with experimental data. Reformation of hydrogen bonds, water expulsion and formation of hydrophobic interactions are driving forces of the α5 displacement. We conclude that the identified interactions between R* and G protein define a structural framework in which the α5 displacement promotes direct transmission of the signal from R* to the GDP binding pocket.
NASA Astrophysics Data System (ADS)
Erak, Dalibor; Matenco, Liviu; Toljić, Marinko; Stojadinović, Uroš; Andriessen, Paul A. M.; Willingshofer, Ernst; Ducea, Mihai N.
2017-07-01
Reactivation of inherited nappe contacts is a common process in orogenic areas affected by back-arc extension. The amount of back-arc extension is often variable along the orogenic strike, owing to the evolution of arcuated mountain chains during stages of rapid slab retreat. This evolution creates low rates of extension near rotation poles, where kinematics and interplay with the pre-existing orogenic structure are less understood. The amount of Miocene extension recorded by the Pannonian Basin of Central Europe decreases SE-wards along the inherited Cretaceous - Paleogene contact between the Dinarides and Carpathian Mountains. Our study combines kinematic data obtained from field and micro-structural observations assisted with fission track thermochronological analysis and U-Pb zircon dating to demonstrate a complex poly-phase evolution in the key area of the Jastrebac Mountains of Serbia. A first event of Late Cretaceous exhumation was followed by latest Cretaceous - Eocene thrusting and magmatism related to a continental collision that sutured the accretionary wedge containing contractional trench turbidites. The suture zone was subsequently reactivated and exhumed by a newly observed Miocene extensional detachment that lasted longer in the Jastrebac Mountains when compared with similar structures situated elsewhere in the same structural position. Such extensional zones situated near the pole of extensional-driven rotation favour late stage truncations and migration of extension in a hanging-wall direction, while directions of tectonic transport show significant differences in short distances across the strike of major structures.
X-ray diffraction study of A- plane non-polar InN epilayer grown by MOCVD
NASA Astrophysics Data System (ADS)
Moret, Matthieu; Briot, Olivier; Gil, Bernard
2015-03-01
Strong polarisation-induced electric fields in C-plane oriented nitrides semiconductor layers reduce the performance of devices. Eliminating the polarization fields can be achieved by growing nitrides along non polar direction. We have grown non polar A-plane oriented InN on R-plane (1‾102) nitridated sapphire substrate by MOCVD. We have studied the structural anisotropy observed in these layers by analyzing High Resolution XRay Diffraction rocking curve (RC) experiments as a function of the in-plane beam orientation. A-plane InN epilayer have a unique epitaxial relationship on R-Plane sapphire and show a strong structural anisotropy. Full width at half maximum (FWHM) of the InN(11‾20) XRD RC values are contained between 44 and 81 Arcmin. FWHM is smaller when the diffraction occurs along the [0001] and the largest FWHM values, of the (11‾20) RC, are obtained when the diffraction occurs along the [1‾100] in-plane direction. Atomic Force Microscopy imaging revealed morphologies with well organized crystallites. The grains are structured along a unique crystallographic orientation of InN, leading to larger domains in this direction. This structural anisotropy can be, in first approximation, attributed to the difference in the domain sizes observed. XRD reciprocal space mappings (RSM) were performed in asymmetrical configuration on (13‾40) and (2‾202) diffraction plane. RSM are measured with a beam orientation corresponding to a maximal and a minimal width of the (11‾20) Rocking curves, respectively. A simple theoretical model is exposed to interpret the RSM. We concluded that the dominant contribution to the anisotropy is due to the scattering coherence length anisotropy present in our samples.
Alert-QSAR. Implications for Electrophilic Theory of Chemical Carcinogenesis
Putz, Mihai V.; Ionaşcu, Cosmin; Putz, Ana-Maria; Ostafe, Vasile
2011-01-01
Given the modeling and predictive abilities of quantitative structure activity relationships (QSARs) for genotoxic carcinogens or mutagens that directly affect DNA, the present research investigates structural alert (SA) intermediate-predicted correlations ASA of electrophilic molecular structures with observed carcinogenic potencies in rats (observed activity, A = Log[1/TD50], i.e., ASA=f(X1SA,X2SA,…)). The present method includes calculation of the recently developed residual correlation of the structural alert models, i.e., ARASA=f(A−ASA,X1SA,X2SA,…). We propose a specific electrophilic ligand-receptor mechanism that combines electronegativity with chemical hardness-associated frontier principles, equality of ligand-reagent electronegativities and ligand maximum chemical hardness for highly diverse toxic molecules against specific receptors in rats. The observed carcinogenic activity is influenced by the induced SA-mutagenic intermediate effect, alongside Hansch indices such as hydrophobicity (LogP), polarizability (POL) and total energy (Etot), which account for molecular membrane diffusion, ionic deformation, and stericity, respectively. A possible QSAR mechanistic interpretation of mutagenicity as the first step in genotoxic carcinogenesis development is discussed using the structural alert chemoinformation and in full accordance with the Organization for Economic Co-operation and Development QSAR guidance principles. PMID:21954348
Tectonic controlled submarine slidings and dewatering structures
NASA Astrophysics Data System (ADS)
Yamamoto, Y.; Hirono, T.; Takahashi, M.
2003-04-01
Geologic structures associated with mass movements processes such as slumping, sliding, and creeping can be the key to understanding the tectonic or geologic constraints in the time they were formed. Because they are sensitively reflected by the paleo-topography which must be associated with active tectonics. It must be very useful if the direction of paleo-slope instability is known easily in a wide area. We paid attentions to convolute lamination and flame structure which might be associated with dewatering and loading, respectively. Some recent researches report the possibility that well regulated flame structures might be formed in relation to paleo-slope instability. However, there is an alternative idea that they were reflection of heterogeneous loading associated with ripple marks on the sandy layers. This controversy has not been settled. Accordingly, to evaluate the reliability of the relationship between formation of such structures with well regulated arrays and paleo-slope instability, the Pliocene Chikura Group in the southern part of the Boso Peninsula, central Japan, was studied. The Chikura Group overlying the Miura Group, Miocene accretionary prism, is composed of trench-fill sediments in the lowermost and of trench-slope basin sediments in the upper. The Chikura Group was deposited on an east-west extended sedimentary basin during east-west trending folds and faults development. These indicate the direction of paleo-slope in the Chikura Group due north or south. Flame structures and convolute laminations were recognized over 60 sites in the Chikura Group. They have well-regulated planar arrays which extend almost east west, perpendicular to the direction of paleo-slope instability. Some examples of such structures and slump deposit were observed in the same outcrop. Vergence of these slump deposits were toward north or south, and ridges of flame structures and convolute laminations extend east-west. Experimental study of direct imaging of dewatering under shear stress regime by using X-ray CT and X-ray microscope shows similar arrays of dewatering paths. Water escapes through the foliation which might be a tension fracture caused by direct shear strain. The foliation has vertical trends to the applied shear stress and has high angle dippings with approximately 65 to 75 degrees to the direct shear plane. These field-based study and experiment indicate that well regulated flame structures and convolute laminations were formed by dewatering or mud liquidization by which water escapes through the tension fractures associated with shear stress corresponding to the paleo-slope instability. These structures are very important because we can identify easily the paleo-slope directions, direction of synsedimentary shear and also macro-scopic geologic constraints on tectonics around a study area.
Electronic band structure of ReS2 by high-resolution angle-resolved photoemission spectroscopy
NASA Astrophysics Data System (ADS)
Webb, James L.; Hart, Lewis S.; Wolverson, Daniel; Chen, Chaoyu; Avila, Jose; Asensio, Maria C.
2017-09-01
The rhenium-based transition metal dichalcogenides (TMDs) are atypical of the TMD family due to their highly anisotropic crystalline structure and are recognized as promising materials for two-dimensional heterostructure devices. The nature of the band gap (direct or indirect) for bulk, few-, and single-layer forms of ReS2 is of particular interest, due to its comparatively weak interplanar interaction. However, the degree of interlayer interaction and the question of whether a transition from indirect to direct gap is observed on reducing thickness (as in other TMDs) are controversial. We present a direct determination of the valence band structure of bulk ReS2 using high-resolution angle-resolved photoemission spectroscopy. We find a clear in-plane anisotropy due to the presence of chains of Re atoms, with a strongly directional effective mass which is larger in the direction orthogonal to the Re chains (2.2 me ) than along them (1.6 me ). An appreciable interplane interaction results in an experimentally measured difference of ≈100 -200 meV between the valence band maxima at the Z point (0,0,1/2 ) and the Γ point (0,0,0) of the three-dimensional Brillouin zone. This leads to a direct gap at Z and a close-lying but larger gap at Γ , implying that bulk ReS2 is marginally indirect. This may account for recent conflicting transport and photoluminescence measurements and the resulting uncertainty about the nature of the band gap in this material.
Multiscale geophysical imaging of the critical zone
Parsekian, Andy; Singha, Kamini; Minsley, Burke J.; Holbrook, W. Steven; Slater, Lee
2015-01-01
Details of Earth's shallow subsurface—a key component of the critical zone (CZ)—are largely obscured because making direct observations with sufficient density to capture natural characteristic spatial variability in physical properties is difficult. Yet this inaccessible region of the CZ is fundamental to processes that support ecosystems, society, and the environment. Geophysical methods provide a means for remotely examining CZ form and function over length scales that span centimeters to kilometers. Here we present a review highlighting the application of geophysical methods to CZ science research questions. In particular, we consider the application of geophysical methods to map the geometry of structural features such as regolith thickness, lithological boundaries, permafrost extent, snow thickness, or shallow root zones. Combined with knowledge of structure, we discuss how geophysical observations are used to understand CZ processes. Fluxes between snow, surface water, and groundwater affect weathering, groundwater resources, and chemical and nutrient exports to rivers. The exchange of gas between soil and the atmosphere have been studied using geophysical methods in wetland areas. Indirect geophysical methods are a natural and necessary complement to direct observations obtained by drilling or field mapping. Direct measurements should be used to calibrate geophysical estimates, which can then be used to extrapolate interpretations over larger areas or to monitor changing processes over time. Advances in geophysical instrumentation and computational approaches for integrating different types of data have great potential to fill gaps in our understanding of the shallow subsurface portion of the CZ and should be integrated where possible in future CZ research.
NASA Astrophysics Data System (ADS)
Keller, Nicholas A.; Migliori, Amy D.; Arya, Gaurav; Rao, Venigalla B.; Smith, Douglas E.
2013-09-01
Many double-stranded DNA viruses employ a molecular motor to package DNA into preformed capsid shells. Based on structures of phage T4 motor proteins determined by X-ray crystallography and cryo-electron microscopy, Rao, Rossmann and coworkers recently proposed a structural model for motor function. They proposed that DNA is ratcheted by a large conformational change driven by electrostatic interactions between charged residues at an interface between two globular domains of the motor protein. We have conducted experiments to test this model by studying the effect on packaging under applied load of site-directed changes altering these residues. We observe significant impairment of packaging activity including reductions in packaging rate, percent time packaging, and time active under high load. We show that these measured impairments correlate well with alterations in free energies associated with the conformational change predicted by molecular dynamics simulations.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cevallos, F. Alex; Stolze, Karoline; Cava, Robert J.
The single crystal growth, structure, and basic magnetic properties of ErMgGaO 4 are reported. The structure consists of triangular layers of magnetic ErO 6 octahedra separated by a double layer of randomly occupied non-magnetic (Ga,Mg)O 5 bipyramids. The Er atoms are positionally disordered. Magnetic measurements parallel and perpendicular to the c axis of a single crystal reveal dominantly antiferromagnetic interactions, with a small degree of magnetic anisotropy. A weighted average of the directional data suggests an antiferromagnetic Curie Weiss temperature of approximately -30 K. Below 10 K the temperature dependences of the inverse susceptibilities in the in-plane and perpendicular-to planemore » directions are parallel, indicative of an isotropic magnetic moment at low temperatures. In conclusion, no sign of magnetic ordering is observed above 1.8 K, suggesting that ErMgGaO 4 is a geometrically frustrated magnet.« less
Low field domain wall dynamics in artificial spin-ice basis structure
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kwon, J.; School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798; Goolaup, S.
2015-10-28
Artificial magnetic spin-ice nanostructures provide an ideal platform for the observation of magnetic monopoles. The formation of a magnetic monopole is governed by the motion of a magnetic charge carrier via the propagation of domain walls (DWs) in a lattice. To date, most experiments have been on the static visualization of DW propagation in the lattice. In this paper, we report on the low field dynamics of DW in a unit spin-ice structure measured by magnetoresistance changes. Our results show that reversible DW propagation can be initiated within the spin-ice basis. The initial magnetization configuration of the unit structure stronglymore » influences the direction of DW motion in the branches. Single or multiple domain wall nucleation can be induced in the respective branches of the unit spin ice by the direction of the applied field.« less
Structure and Dynamics of Dinucleosomes Assessed by Atomic Force Microscopy
Filenko, Nina A.; Palets, Dmytro B.; Lyubchenko, Yuri L.
2012-01-01
Dynamics of nucleosomes and their interactions are important for understanding the mechanism of chromatin assembly. Internucleosomal interaction is required for the formation of higher-order chromatin structures. Although H1 histone is critically involved in the process of chromatin assembly, direct internucleosomal interactions contribute to this process as well. To characterize the interactions of nucleosomes within the nucleosome array, we designed a dinucleosome and performed direct AFM imaging. The analysis of the AFM data showed dinucleosomes are very dynamic systems, enabling the nucleosomes to move in a broad range along the DNA template. Di-nucleosomes in close proximity were observed, but their populationmore » was low. The use of the zwitterionic detergent, CHAPS, increased the dynamic range of the di-nucleosome, facilitating the formation of tight di-nucleosomes. The role of CHAPS and similar natural products in chromatin structure and dynamics is also discussed.« less
Crystal Structure and Ferroelectric Properties of ε-Ga2O3 Films Grown on (0001)-Sapphire.
Mezzadri, Francesco; Calestani, Gianluca; Boschi, Francesco; Delmonte, Davide; Bosi, Matteo; Fornari, Roberto
2016-11-21
The crystal structure and ferroelectric properties of ε-Ga 2 O 3 deposited by low-temperature MOCVD on (0001)-sapphire were investigated by single-crystal X-ray diffraction and the dynamic hysteresis measurement technique. A thorough investigation of this relatively unknown polymorph of Ga 2 O 3 showed that it is composed of layers of both octahedrally and tetrahedrally coordinated Ga 3+ sites, which appear to be occupied with a 66% probability. The refinement of the crystal structure in the noncentrosymmetric space group P6 3 mc pointed out the presence of uncompensated electrical dipoles suggesting ferroelectric properties, which were finally demonstrated by independent measurements of the ferroelectric hysteresis. A clear epitaxial relation is observed with respect to the c-oriented sapphire substrate, with the Ga 2 O 3 [10-10] direction being parallel to the Al 2 O 3 direction [11-20], yielding a lattice mismatch of about 4.1%.
NASA Astrophysics Data System (ADS)
Megalini, Ludovico; Cabinian, Brian C.; Zhao, Hongwei; Oakley, Douglas C.; Bowers, John E.; Klamkin, Jonathan
2018-02-01
We employ a simple two-step growth technique to grow large-area 1550-nm laser structures by direct hetero-epitaxy of III-V compounds on patterned exact-oriented (001) silicon (Si) substrates by metal organic chemical vapor deposition. Densely-packed, highly uniform, flat and millimeter-long indium phosphide (InP) nanowires were grown from Si v-grooves separated by silicon dioxide (SiO2) stripes with various widths and pitches. Following removal of the SiO2 patterns, the InP nanowires were coalesced and, subsequently, 1550-nm laser structures were grown in a single overgrowth without performing any polishing for planarization. X-ray diffraction, photoluminescence, atomic force microscopy and transmission electron microscopy analyses were used to characterize the epitaxial material. PIN diodes were fabricated and diode-rectifying behavior was observed.
Identifying Few-Molecule Water Clusters with High Precision on Au(111) Surface.
Dong, Anning; Yan, Lei; Sun, Lihuan; Yan, Shichao; Shan, Xinyan; Guo, Yang; Meng, Sheng; Lu, Xinghua
2018-06-01
Revealing the nature of a hydrogen-bond network in water structures is one of the imperative objectives of science. With the use of a low-temperature scanning tunneling microscope, water clusters on a Au(111) surface were directly imaged with molecular resolution by a functionalized tip. The internal structures of the water clusters as well as the geometry variations with the increase of size were identified. In contrast to a buckled water hexamer predicted by previous theoretical calculations, our results present deterministic evidence for a flat configuration of water hexamers on Au(111), corroborated by density functional theory calculations with properly implemented van der Waals corrections. The consistency between the experimental observations and improved theoretical calculations not only renders the internal structures of absorbed water clusters unambiguously, but also directly manifests the crucial role of van der Waals interactions in constructing water-solid interfaces.
Cevallos, F. Alex; Stolze, Karoline; Cava, Robert J.
2018-03-23
The single crystal growth, structure, and basic magnetic properties of ErMgGaO 4 are reported. The structure consists of triangular layers of magnetic ErO 6 octahedra separated by a double layer of randomly occupied non-magnetic (Ga,Mg)O 5 bipyramids. The Er atoms are positionally disordered. Magnetic measurements parallel and perpendicular to the c axis of a single crystal reveal dominantly antiferromagnetic interactions, with a small degree of magnetic anisotropy. A weighted average of the directional data suggests an antiferromagnetic Curie Weiss temperature of approximately -30 K. Below 10 K the temperature dependences of the inverse susceptibilities in the in-plane and perpendicular-to planemore » directions are parallel, indicative of an isotropic magnetic moment at low temperatures. In conclusion, no sign of magnetic ordering is observed above 1.8 K, suggesting that ErMgGaO 4 is a geometrically frustrated magnet.« less
Directional solidification of Al2-Cu-Al and Al3-Ni-Al eutectics during TEXUS rocket flight
NASA Technical Reports Server (NTRS)
Favier, J. J.; Degoer, J.
1984-01-01
One lamellar eutectic sample and one fiber-like eutectic sample were solidified directionally during the TEXUS-6 rocket flight. The microstructures and the results of the thermal analysis, obtained from the temperatures recorded on the cartridge skin, are compared. No appreciable modifications of the regularity of the eutectic structures were observed by passing from 1 g to 0.0001 g in these experiments. No steady state growth conditions were achieved in these experiments.
NASA Astrophysics Data System (ADS)
Isaenkova, M.; Perlovich, Yu.; Fesenko, V.; Babich, Y.; Zaripova, M.; Krapivka, N.
2018-05-01
The paper presents the results of investigation of the regularities of the structure and texture formation during rolling of single crystals of Zr-25%Nb alloy differing in their initial orientations relative to the external principal directions in the rolled plate: normal (ND) and rolling directions (RD). The features of rolled single crystals with initial orientations of planes {001}, {011} or {111} parallel to the rolling plane and different crystallographic directions along RD are considered. A comparison of the peculiarities of plastic deformation in a polycrystalline alloy of the same composition is made. For the samples studied, a decrease in the lattice parameter of the β-phase has been recorded, the minimum of the parameter being observed for different degrees of deformation, varying from 20 to 50%. Observed decrease in the unit cell parameter can be connected with the precipitation of the α(α')-Zr phase from the deformed nonequilibrium β-phase of the Zr-25%Nb alloy, i.e. change in the composition of the solid solution. Distributions of the increase in the dimensions of the deformed single crystal along RD and the transverse direction (TD) with its deformation up to 30% in thickness, which indicate the anisotropy of the plasticity of single crystals during their rolling, are constructed on stereographic projection. It is shown, that the deformation of single crystals occurs practically without increasing of their dimensions in the <110> direction with a total thickness deformation of up to 30%. Direction <110> is characterized by maximum hardening (microhardness) with indentation along it, which causes low plasticity of deformed and annealed foils from Zr-25%Nb alloy at the stretching along and across RD, that is connected with the features of their crystallographic texture.
NASA Astrophysics Data System (ADS)
Gratadour, D.; Rouan, D.; Grosset, L.; Boccaletti, A.; Clénet, Y.
2015-09-01
Aims: One of the main observational challenges for investigating the central regions of active galactic nuclei (AGN) at short wavelengths, using high angular resolution, and high contrast observations, is to directly detect the circumnuclear optically thick material hiding the central core emission when viewed edge-on. The lack of direct evidence is limiting our understanding of AGN, and several scenarios have been proposed to cope for the diverse observed aspects of activity in a unified approach. Methods: Observations in the near-infrared spectral range have shown themselves to be powerful for providing essential hints to the characterisation of the unified model ingredients because of the reduced optical depth of the obscuring material. Moreover, it is possible to trace this material through light scattered from the central engine's closest environment, so that polarimetric observations are the ideal tool for distinguishing it from purely thermal and stellar emissions. Results: Here we show strong evidence that there is an extended nuclear torus at the center of NGC 1068 thanks to new adaptive-optics-assisted polarimetric observations in the near-infrared. The orientation of the polarization vectors proves that there is a structured hourglass-shaped bicone and a compact elongated (20 × 60 pc) nuclear structure perpendicular to the bicone axis. The linearly polarized emission in the bicone is dominated by a centro-symmetric pattern, but the central compact region shows a clear deviation from the latter with linear polarization aligned perpendicular to the bicone axis. Figure 2 is available in electronic form at http://www.aanda.orgData obtained with the SPHERE an instrument designed and built by a consortium consisting of IPAG (France), MPIA (Germany), LAM (France), LESIA (France), Laboratoire Lagrange (France), INAF - Osservatorio di Padova (Italy), Observatoire de Genève (Switzerland), ETH Zurich (Switzerland), NOVA (Netherlands), ONERA (France), and ASTRON (Netherlands) in collaboration with ESO.
Laser direct writing of thin-film copper structures as a modification of lithographic processes
NASA Astrophysics Data System (ADS)
Meyer, F.; Ostendorf, A.; Stute, U.
2007-04-01
This paper presents a flexible, mask-free and efficient technique for UV-laser micropatterning of photosensitive resist by laser direct writing (LDW). Photo resist spun on gold sputtered silicon wafers has been laser structured by a scanner guided 266nm DPSSL and electroplated. Ablation behaviour and optimum seed layer preparation in relation to parameters like pulse energy, scanning speed and number of scanned cycles and the electroplating results are discussed. The resulting adhesive strength was measured by a µ-sear device and the gold seed layer-plated copper interface investigated by SEM and EDX to explain correlation to identified bonding behaviour. Improved adhesive strength was observed with higher laser pulse energy and reduced number of cycle.
Dissipative soliton vortices and tropical cyclones
NASA Astrophysics Data System (ADS)
Chefranov, S. G.; Chefranov, A. G.
2017-10-01
We have obtained a new exact steady-state solution to the hydrodynamic equation for a viscous incompressible liquid, which is a generalization of the well-known Sullivan solution (1959), taking into account additionally the external (Eckman) friction and rotation of the system as a single whole. In contrast to the radial structure of a Sullivan vortex, different circulation directions of velocity field tangential component are possible in the new solution in the inner and outer cells. We have considered the correspondence of this solution to the radial vortex structure observed in tropical cyclones, where the precisely anticyclonic circulation always exists in the inner core (typhoon, hurricane eye), which is associated with descending vertical currents for the cyclonic direction of rotation (as well as ascending currents) outside this core.
Network model for thermal conductivities of unidirectional fiber-reinforced composites
NASA Astrophysics Data System (ADS)
Wang, Yang; Peng, Chaoyi; Zhang, Weihua
2014-12-01
An empirical network model has been developed to predict the in-plane thermal conductivities along arbitrary directions for unidirectional fiber-reinforced composites lamina. Measurements of thermal conductivities along different orientations were carried out. Good agreement was observed between values predicted by the network model and the experimental data; compared with the established analytical models, the newly proposed network model could give values with higher precision. Therefore, this network model is helpful to get a wider and more comprehensive understanding of heat transmission characteristics of fiber-reinforced composites and can be utilized as guidance to design and fabricate laminated composites with specific directional or specific locational thermal conductivities for structures that simultaneously perform mechanical and thermal functions, i.e. multifunctional structures (MFS).
Ma, Hao; Tian, Zhiting
2018-01-10
Tapered bottlebrush polymers have novel nanoscale polymer architecture. Using nonequilibrium molecular dynamics simulations, we showed that these polymers have the unique ability to generate thermal rectification in a single polymer molecule and offer an exceptional platform for unveiling different heat conduction regimes. In sharp contrast to all other reported asymmetric nanostructures, we observed that the heat current from the wide end to the narrow end (the forward direction) in tapered bottlebrush polymers is smaller than that in the opposite direction (the backward direction). We found that a more disordered to less disordered structural transition within tapered bottlebrush polymers is essential for generating nonlinearity in heat conduction for thermal rectification. Moreover, the thermal rectification ratio increased with device length, reaching as high as ∼70% with a device length of 28.5 nm. This large thermal rectification with strong length dependence uncovered an unprecedented phenomenon-diffusive thermal transport in the forward direction and ballistic thermal transport in the backward direction. This is the first observation of radically different transport mechanisms when heat flow direction changes in the same system. The fundamentally new knowledge gained from this study can guide exciting research into nanoscale organic thermal diodes.
Directional reflectance factor distributions of a cotton row crop
NASA Technical Reports Server (NTRS)
Kimes, D. S.; Newcomb, W. W.; Schutt, J. B.; Pinter, P. J., Jr.; Jackson, R. D.
1984-01-01
The directional reflectance factor distribution spanning the entire exitance hemisphere was measured for a cotton row crop (Gossypium barbadense L.) with 39 percent ground cover. Spectral directional radiances were taken in NOAA satellite 7 AVHRR bands 1 and 2 using a three-band radiometer with restricted 12 deg full angle field of view at half peak power points. Polar co-ordinate system plots of directional reflectance factor distributions and three-dimensional computer graphic plots of scattered flux were used to study the dynamics of the directional reflectance factor distribution as a function of spectral band, geometric structure of the scene, solar zenith and azimuth angles, and optical properties of the leaves and soil. The factor distribution of the incomplete row crops was highly polymodal relative to that for complete vegetation canopies. Besides the enhanced reflectance for the antisolar point, a reflectance minimum was observed towards the forwardscatter direction in the principle plane of the sun. Knowledge of the mechanics of the observed dynamics of the data may be used to provide rigorous validation for two- or three-dimensional radiative transfer models, and is important in interpreting aircraft and satellite data where the solar angle varies widely.
NASA Astrophysics Data System (ADS)
Mahler, Michael; Gaganidze, Ermile; Aktaa, Jarir
2018-04-01
The experimental observation of anisotropic fracture behaviour of round blank polycrystalline tungsten was simulated using finite element (FE) method in combination with cohesive zone model. Experiments in the past had shown that due to the anisotropic microstructure the fracture toughness varies by factor of about two for different orientations. The reason is the crack propagation direction, which is - in some orientations - not the typical crack propagation direction for mode I fracture. In some directions the crack is not growing perpendicular to the crack opening tensile load. Nevertheless, in the present paper, the microstructure is modelled by FE mesh including cohesive zone elements which mimic grain boundaries (GB). This is based on the assumption that GB's are the weakest links in the structure. The use of the correct parameters to describe the fracture process allows the description of the observed experimental orientation dependent fracture toughness.
Jiang, Shang-Da; Maganas, Dimitrios; Levesanos, Nikolaos; Ferentinos, Eleftherios; Haas, Sabrina; Thirunavukkuarasu, Komalavalli; Krzystek, J; Dressel, Martin; Bogani, Lapo; Neese, Frank; Kyritsis, Panayotis
2015-10-14
The high-spin (S = 1) tetrahedral Ni(II) complex [Ni{(i)Pr2P(Se)NP(Se)(i)Pr2}2] was investigated by magnetometry, spectroscopic, and quantum chemical methods. Angle-resolved magnetometry studies revealed the orientation of the magnetization principal axes. The very large zero-field splitting (zfs), D = 45.40(2) cm(-1), E = 1.91(2) cm(-1), of the complex was accurately determined by far-infrared magnetic spectroscopy, directly observing transitions between the spin sublevels of the triplet ground state. These are the largest zfs values ever determined--directly--for a high-spin Ni(II) complex. Ab initio calculations further probed the electronic structure of the system, elucidating the factors controlling the sign and magnitude of D. The latter is dominated by spin-orbit coupling contributions of the Ni ions, whereas the corresponding effects of the Se atoms are remarkably smaller.
Direct Observation of Twisted Surface skyrmions in Bulk Crystals
NASA Astrophysics Data System (ADS)
Zhang, S. L.; van der Laan, G.; Wang, W. W.; Haghighirad, A. A.; Hesjedal, T.
2018-06-01
Magnetic skyrmions in noncentrosymmetric helimagnets with Dn symmetry are Bloch-type magnetization swirls with a helicity angle of ±9 0 ° . At the surface of helimagnetic thin films below a critical thickness, a twisted skyrmion state with an arbitrary helicity angle has been proposed; however, its direct experimental observation has remained elusive. Here, we show that circularly polarized resonant elastic x-ray scattering is able to unambiguously measure the helicity angle of surface skyrmions, providing direct experimental evidence that a twisted skyrmion surface state also exists in bulk systems. The exact surface helicity angles of twisted skyrmions for both left- and right-handed chiral bulk Cu2 OSeO3 , in the single as well as in the multidomain skyrmion lattice state, are determined, revealing their detailed internal structure. Our findings suggest that a skyrmion surface reconstruction is a universal phenomenon, stemming from the breaking of translational symmetry at the interface.
Kinoshita, Shuichi; Yoshioka, Shinya; Kawagoe, Kenji
2002-01-01
Structural colour in the Morpho butterfly originates from submicron structure within a scale and, for over a century, its colour and reflectivity have been explained as interference of light due to the multilayer of cuticle and air. However, this model fails to explain the extraordinarily uniform colour of the wing with respect to the observation direction. We have performed microscopic, optical and theoretical investigations, and have found that the separate lamellar structure with irregular heights is extremely important. Using a simple model, we have shown that the combined action of interference and diffraction is essential for the structural colour of the Morpho butterfly. PMID:12137569
NASA Technical Reports Server (NTRS)
1976-01-01
The structure and direction of bow shock waves and the occurence of Pc 3, 4 micropulsations were investigated. An observational description is given of a quasi-parallel structure in a plasma parameter regime. The use of approximation to estimate the thickness of thin, nearly perpendicular bow shocks at supralaminar Mach numbers is discussed. The pattern of energies of backstreaming protons in the foreshock are predicted.
Molecular Beam Epitaxial Growth of GaAs on (631) Oriented Substrates
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cruz Hernandez, Esteban; Rojas Ramirez, Juan-Salvador; Contreras Hernandez, Rocio
2007-02-09
In this work, we report the study of the homoepitaxial growth of GaAs on (631) oriented substrates by molecular beam epitaxy (MBE). We observed the spontaneous formation of a high density of large scale features on the surface. The hilly like features are elongated towards the [-5, 9, 3] direction. We show the dependence of these structures with the growth conditions and we present the possibility of to create quantum wires structures on this surface.
Banerjee, Debasis; Wang, Hao; Plonka, Anna M; Emge, Thomas J; Parise, John B; Li, Jing
2016-08-08
Gate-opening is a unique and interesting phenomenon commonly observed in flexible porous frameworks, where the pore characteristics and/or crystal structures change in response to external stimuli such as adding or removing guest molecules. For gate-opening that is induced by gas adsorption, the pore-opening pressure often varies for different adsorbate molecules and, thus, can be applied to selectively separate a gas mixture. The detailed understanding of this phenomenon is of fundamental importance to the design of industrially applicable gas-selective sorbents, which remains under investigated due to the lack of direct structural evidence for such systems. We report a mechanistic study of gas-induced gate-opening process of a microporous metal-organic framework, [Mn(ina)2 ] (ina=isonicotinate) associated with commensurate adsorption, by a combination of several analytical techniques including single crystal X-ray diffraction, in situ powder X-ray diffraction coupled with differential scanning calorimetry (XRD-DSC), and gas adsorption-desorption methods. Our study reveals that the pronounced and reversible gate opening/closing phenomena observed in [Mn(ina)2 ] are coupled with a structural transition that involves rotation of the organic linker molecules as a result of interaction of the framework with adsorbed gas molecules including carbon dioxide and propane. The onset pressure to open the gate correlates with the extent of such interaction. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Reber, J. E.; Schmalholz, S. M.; Burg, J.-P.
2010-10-01
Two orthogonal sets of veins, both orthogonal to bedding, form chocolate tablet structures on the limbs of folded quartzwackes of Carboniferous turbidites in SW Portugal. Structural observations suggest that (1) mode 1 fractures transverse to the fold axes formed while fold amplitudes were small and limbs were under layer-subparallel compression and (2) mode 1 fractures parallel to the fold axes formed while fold amplitudes were large and limbs were brought to be under layer-subparallel tension. We performed two- and three-dimensional numerical simulations investigating the evolution of stress orientations during viscous folding to test whether and how these two successive sets of fractures were related to folding. We employed ellipses and ellipsoids for the visualization and quantification of the local stress field. The numerical simulations show a change in the orientation of the local σ1 direction by almost 90° with respect to the bedding plane in the fold limbs. The coeval σ3 direction rotates from parallel to the fold axis at low fold amplitudes to orthogonal to the fold axis at high fold amplitudes. The stress orientation changes faster in multilayers than in single-layers. The numerical simulations are consistent with observation and provide a mechanical interpretation for the formation of the chocolate tablet structures through consecutive sets of fractures on rotating limbs of folded competent layers.
Examining Student Research Choices and Processes in a Disintermediated Searching Environment
ERIC Educational Resources Information Center
Rempel, Hannah Gascho; Buck, Stefanie; Deitering, Anne-Marie
2013-01-01
Students today perform research in a disintermediated environment, which often allows them to struggle directly with the process of selecting research tools and choosing scholarly sources. The authors conducted a qualitative study with twenty students, using structured observations to ascertain the processes students use to select databases and…
Directly Observed Physical Activity Levels in Preschool Children
ERIC Educational Resources Information Center
Pate, Russell R.; McIver, Kerry; Dowda, Marsha; Brown, William H.; Addy, Cheryl
2008-01-01
Background: Millions of young children attend preschools and other structured child development programs, but little is known about their physical activity levels while in those settings. The purpose of this study was to describe the physical activity levels and demographic and school-related correlates of physical activity in children attending…
Using Models to Understand Sea Level Rise
ERIC Educational Resources Information Center
Barth-Cohen, Lauren; Medina, Edwing
2017-01-01
Important science phenomena--such as atomic structure, evolution, and climate change--are often hard to observe directly. That's why an important scientific practice is to use scientific models to represent one's current understanding of a system. Using models has been included as an essential science and engineering practice in the "Next…
Structurally compliant rocket engine combustion chamber: Experimental and analytical validation
NASA Technical Reports Server (NTRS)
Jankovsky, Robert S.; Arya, Vinod K.; Kazaroff, John M.; Halford, Gary R.
1994-01-01
A new, structurally compliant rocket engine combustion chamber design has been validated through analysis and experiment. Subscale, tubular channel chambers have been cyclically tested and analytically evaluated. Cyclic lives were determined to have a potential for 1000 percent increase over those of rectangular channel designs, the current state of the art. Greater structural compliance in the circumferential direction gave rise to lower thermal strains during hot firing, resulting in lower thermal strain ratcheting and longer predicted fatigue lives. Thermal, structural, and durability analyses of the combustion chamber design, involving cyclic temperatures, strains, and low-cycle fatigue lives, have corroborated the experimental observations.
Dopant distributions in n-MOSFET structure observed by atom probe tomography.
Inoue, K; Yano, F; Nishida, A; Takamizawa, H; Tsunomura, T; Nagai, Y; Hasegawa, M
2009-11-01
The dopant distributions in an n-type metal-oxide-semiconductor field effect transistor (MOSFET) structure were analyzed by atom probe tomography. The dopant distributions of As, P, and B atoms in a MOSFET structure (gate, gate oxide, channel, source/drain extension, and halo) were obtained. P atoms were segregated at the interface between the poly-Si gate and the gate oxide, and on the grain boundaries of the poly-Si gate, which had an elongated grain structure along the gate height direction. The concentration of B atoms was enriched near the edge of the source/drain extension where the As atoms were implanted.
Yang, Linglu; Yan, Bo; Reinhard, Björn M.
2009-01-01
The optical spectra of individual Ag-Au alloy hollow particles were correlated with the particles’ structures obtained by transmission electron microscopy (TEM). The TEM provided direct experimental access to the dimension of the cavity, thickness of the metal shell, and the interparticle distance of hollow particle dimers with high spatial resolution. The analysis of correlated spectral and structural information enabled the quantification of the influence of the core-shell structure on the resonance energy, plasmon lifetime, and plasmon coupling efficiency. Electron beam exposure during TEM inspection was observed to affect plasmon wavelength and lifetime, making optical inspection prior to structural characterization mandatory. PMID:19768108
NASA Astrophysics Data System (ADS)
Moskvin, A. S.; Panov, Yu. D.; Rybakov, F. N.; Borisov, A. B.
2017-11-01
We have used high-performance parallel computations by NVIDIA graphics cards applying the method of nonlinear conjugate gradients and Monte Carlo method to observe directly the developing ground state configuration of a two-dimensional hard-core boson system with decrease in temperature, and its evolution with deviation from a half-filling. This has allowed us to explore unconventional features of a charge order—superfluidity phase transition, specifically, formation of an irregular domain structure, emergence of a filamentary superfluid structure that condenses within of the charge-ordered phase domain antiphase boundaries, and formation and evolution of various topological structures.
Direct folding simulation of helical proteins using an effective polarizable bond force field.
Duan, Lili; Zhu, Tong; Ji, Changge; Zhang, Qinggang; Zhang, John Z H
2017-06-14
We report a direct folding study of seven helical proteins (, Trpcage, , C34, N36, , ) ranging from 17 to 53 amino acids through standard molecular dynamics simulations using a recently developed polarizable force field-Effective Polarizable Bond (EPB) method. The backbone RMSDs, radius of gyrations, native contacts and native helix content are in good agreement with the experimental results. Cluster analysis has also verified that these folded structures with the highest population are in good agreement with their corresponding native structures for these proteins. In addition, the free energy landscape of seven proteins in the two dimensional space comprised of RMSD and radius of gyration proved that these folded structures are indeed of the lowest energy conformations. However, when the corresponding simulations were performed using the standard (nonpolarizable) AMBER force fields, no stable folded structures were observed for these proteins. Comparison of the simulation results based on a polarizable EPB force field and a nonpolarizable AMBER force field clearly demonstrates the importance of polarization in the folding of stable helical structures.
Qin, Guangzhao; Yan, Qing-Bo; Qin, Zhenzhen; Yue, Sheng-Ying; Cui, Hui-Juan; Zheng, Qing-Rong; Su, Gang
2014-01-01
We systematically investigated the geometric, electronic and thermoelectric (TE) properties of bulk black phosphorus (BP) under strain. The hinge-like structure of BP brings unusual mechanical responses such as anisotropic Young's modulus and negative Poisson's ratio. A sensitive electronic structure of BP makes it transform among metal, direct and indirect semiconductors under strain. The maximal figure of merit ZT of BP is found to be 0.72 at 800 K that could be enhanced to 0.87 by exerting an appropriate strain, revealing BP could be a potential medium-high temperature TE material. Such strain-induced enhancements of TE performance are often observed to occur at the boundary of the direct-indirect band gap transition, which can be attributed to the increase of degeneracy of energy valleys at the transition point. By comparing the structure of BP with SnSe, a family of potential TE materials with hinge-like structure are suggested. This study not only exposes various novel properties of BP under strain, but also proposes effective strategies to seek for better TE materials. PMID:25374306
NASA Astrophysics Data System (ADS)
Soloviev, A.; Dean, C.; Lukas, R.; Donelan, M. A.; Terray, E. A.
2016-12-01
Surface-wave breaking is a powerful mechanism producing significant energy flux to small scale turbulence. Most of the turbulent energy produced by breaking waves dissipates within one significant wave height, while the turbulent diffusion layer extends to approximately ten significant wave heights. Notably, the near-surface shear may practically vanish within the wave-stirred layer due to small-scale turbulent mixing. The surface ocean temperature-salinity structure, circulation, and mass exchanges (including greenhouse gases and pollutants) substantially depend on turbulent mixing and non-local transport in the near-surface layer of the ocean. Spatially coherent organized motions have been recognized as an important part of non-local transport. Langmuir circulation (LC) and ramp-like structures are believed to vertically transfer an appreciable portion of the momentum, heat, gases, pollutants (e.g., oil), and other substances in the upper layer of the ocean. Free surface significantly complicates the analysis of turbulent exchanges at the air-sea interface and the coherent structures are not yet completely understood. In particular, there is growing observational evidence that in the case of developing seas when the wind direction may not coincide with the direction of the energy containing waves, the Langmuir lines are oriented in the wind rather than the wave direction. In addition, the vortex force due to Stokes drift in traditional models is altered in the breaking-wave-stirred layer. Another complication is that the ramp-like structures in the upper ocean turbulent boundary layer have axes perpendicular to the axes of LC. The ramp-like structures are not considered in the traditional model. We have developed a new model, which treats the LC and ramp-like structures in the near-surface layer of the ocean as a coupled system. Using computational fluid dynamics tools (LES), we have been able to reproduce both LC and ramp-like structures coexisting in space though intermittent in time. In the model, helicity isosurfaces appear to be tilted and, in general, coordinated with the tilted velocity isosurfaces produced by ramp-like structures. This is an indication of coupling between the LC and ramp-like structures. Remarkably, the new model is able to explain observations of LC under developing seas.
Magnetic Doppler imaging of 53 Camelopardalis in all four Stokes parameters
NASA Astrophysics Data System (ADS)
Kochukhov, O.; Bagnulo, S.; Wade, G. A.; Sangalli, L.; Piskunov, N.; Landstreet, J. D.; Petit, P.; Sigut, T. A. A.
2004-02-01
We present the first investigation of the structure of the stellar surface magnetic field using line profiles in all four Stokes parameters. We extract the information about the magnetic field geometry and abundance distributions of the chemically peculiar star 53 Cam by modelling time-series of high-resolution spectropolarimetric observations with the help of a new magnetic Doppler imaging code. This combination of the unique four Stokes parameter data and state-of-the-art magnetic imaging technique makes it possible to infer the stellar magnetic field topology directly from the rotational variability of the Stokes spectra. In the magnetic imaging of 53 Cam we discard the traditional multipolar assumptions about the structure of magnetic fields in Ap stars and explore the stellar magnetic topology without introducing any global a priori constraints on the field structure. The complex magnetic model of 53 Cam derived with our magnetic Doppler imaging method achieves a good fit to the observed intensity, circular and linear polarization profiles of strong magnetically sensitive Fe II spectral lines. Such an agreement between observations and model predictions was not possible with any earlier multipolar magnetic models, based on modelling Stokes I spectra and fitting surface averaged magnetic observables (e.g., longitudinal field, magnetic field modulus, etc.). Furthermore, we demonstrate that even the direct inversion of the four Stokes parameters of 53 Cam assuming a low-order multipolar magnetic geometry is incapable of achieving an adequate fit to our spectropolarimetric observations. Thus, as a main result of our investigation, we discover that the magnetic field topology of 53 Cam is considerably more complex than any low-order multipolar expansion, raising a general question about the validity of the multipolar assumption in the studies of magnetic field structures of Ap stars. In addition to the analysis of the magnetic field of 53 Cam, we reconstruct surface abundance distributions of Si, Ca, Ti, Fe and Nd. These abundance maps confirm results of the previous studies of 53 Cam, in particular dramatic antiphase variation of Ca and Ti abundances. Based on observations obtained with the Bernard Lyot telescope of the Pic du Midi Observatory and Isaac Newton Telescope of the La Palma Observatory.
A new look at the kinematics of the bulge from an N-body model
NASA Astrophysics Data System (ADS)
Gómez, A.; Di Matteo, P.; Stefanovitch, N.; Haywood, M.; Combes, F.; Katz, D.; Babusiaux, C.
2016-05-01
By using an N-body simulation of a bulge that was formed via a bar instability mechanism, we analyse the imprints of the initial (I.e. before bar formation) location of stars on the bulge kinematics, in particular on the heliocentric radial velocity distribution of bulge stars. Four different latitudes were considered: b = -4°, -6°, -8°, and -10°, along the bulge minor axis as well as outside it, at l = ± 5° and l = ± 10°. The bulge X-shaped structure comprises stars that formed in the disk at different locations. Stars formed in the outer disk, beyond the end of the bar, which are part of the boxy peanut-bulge structure may show peaks in the velocity distributions at positive and negative heliocentric radial velocities with high absolute values that can be larger than 100 km s-1, depending on the observed direction. In some cases the structure of the velocity field is more complex and several peaks are observed. Stars formed in the inner disk, the most numerous, contribute predominantly to the X-shaped structure and present different kinematic characteristics. They display a rather symmetric velocity distribution and a smaller fraction of high-velocity stars. The stellar stream motion, which is induced by the bar changes with the star initial position, can reach more than 40 km s-1 for stars that originated in the external disk, depending on the observed direction. Otherwise it is smaller than approximately 20 km s-1. In all cases, it decreases from b = -4° to -10°. Our results may enable us to interpret the cold high-velocity peak observed in the APOGEE commissioning data, as well as the excess of high-velocity stars in the near and far arms of the X-shaped structure at l = 0° and b = -6°. When compared with real data, the kinematic picture becomes more complex due to the possible presence in the observed samples of classical bulge and/or thick disk stars. Overall, our results point to the existence of complex patterns and structures in the bulge velocity fields, which are generated by the bar. This suggests that caution should be used when interpreting the bulge kinematics: the presence of substructures, peaks and clumps in the velocity fields is not necessarily a sign of past accretion events.
Davis, Laurel; Hanson, Sheila K.; Zamir, Osnat; Gewirtz, Abigail H.; DeGarmo, David S.
2015-01-01
Deployment separation and reunifications are salient contexts that directly impact effective family functioning and parenting for military fathers. Yet, we know very little about determinants of post-deployed father involvement and effective parenting. The present study examined hypothesized risk and protective factors of observed parenting for 282 post-deployed fathers who served in the Army National Guard/Reserves. Pre-intervention data were employed from fathers participating in the After Deployment, Adaptive Parenting Tools (ADAPT) randomized control trial. Parenting practices were obtained from direct observation of father-child interaction and included measures of problem solving, harsh discipline, positive involvement, encouragement, and monitoring. Risk factors included combat exposure, negative life events, months deployed, and PTSD symptoms. Protective factors included education, income, dyadic adjustment, and social support. Results of a structural equation model predicting an effective parenting construct indicated that months deployed, income, and father age were most related to observed parenting, explaining 16% of the variance. We are aware of no other study utilizing direct parent-child observations of father’s parenting skills following overseas deployment. Implications for practice and preventive intervention are discussed. PMID:26213794
Davis, Laurel; Hanson, Sheila K; Zamir, Osnat; Gewirtz, Abigail H; DeGarmo, David S
2015-08-01
Deployment separation and reunifications are salient contexts that directly impact effective family functioning and parenting for military fathers. Yet, we know very little about determinants of postdeployed father involvement and effective parenting. The present study examined hypothesized risk and protective factors of observed parenting for 282 postdeployed fathers who served in the National Guard/Reserves. Preintervention data were employed from fathers participating in the After Deployment, Adaptive Parenting Tools randomized control trial. Parenting practices were obtained from direct observation of father-child interaction and included measures of problem solving, harsh discipline, positive involvement, encouragement, and monitoring. Risk factors included combat exposure, negative life events, months deployed, and posttraumatic stress disorder symptoms. Protective factors included education, income, dyadic adjustment, and social support. Results of a structural equation model assessing risk and protective factors for an effective parenting construct indicated that months deployed, income, and father age were most related to observed parenting, explaining 16% of the variance. We are aware of no other study using direct parent-child observations of fathers' parenting skills following overseas deployment. Implications for practice and preventive intervention are discussed. (c) 2015 APA, all rights reserved).
Statistical Analysis of Acoustic Wave Power and Flows around Solar Active Regions
NASA Astrophysics Data System (ADS)
Rabello-Soares, M. Cristina; Bogart, Richard S.; Scherrer, Philip H.
2018-05-01
We analyze the effect of a sunspot in its quiet surroundings applying a helioseismic technique on almost three years of Helioseismic and Magnetic Imager (HMI) observations obtained during solar cycle 24 to further study the sunspot structure below the solar surface. The attenuation of acoustic waves with frequencies lower than 4.2 mHz depends more strongly on the wave direction at a distance of 6°–7° from the sunspot center. The amplification of higher frequency waves is highest 6° away from the active region and is largely independent of the wave’s direction. We observe a mean clockwise flow around active regions, the angular speed of which decreases exponentially with distance and has a coefficient close to ‑0.7 degree‑1. The observed horizontal flow in the direction of the nearby active region agrees with a large-scale circulation around the sunspot in the shape of cylindrical shell. The center of the shell seems to be centered around 7° from the sunspot center, where we observe an inflow close to the surface down to ∼2 Mm, followed by an outflow at deeper layers until at least 7 Mm.
Usukura, Eiji; Narita, Akihiro; Yagi, Akira; Ito, Shuichi; Usukura, Jiro
2016-01-01
An improved unroofing method enabled the cantilever of an atomic force microscope (AFM) to reach directly into a cell to visualize the intracellular cytoskeletal actin filaments, microtubules, clathrin coats, and caveolae in phosphate-buffered saline (PBS) at a higher resolution than conventional electron microscopy. All of the actin filaments clearly exhibited a short periodicity of approximately 5–6 nm, which was derived from globular actins linked to each other to form filaments, as well as a long helical periodicity. The polarity of the actin filaments appeared to be determined by the shape of the periodic striations. Microtubules were identified based on their thickness. Clathrin coats and caveolae were observed on the cytoplasmic surface of cell membranes. The area containing clathrin molecules and their terminal domains was directly visualized. Characteristic ridge structures located at the surface of the caveolae were observed at high resolution, similar to those observed with electron microscopy (EM). Overall, unroofing allowed intracellular AFM imaging in a liquid environment with a level of quality equivalent or superior to that of EM. Thus, AFMs are anticipated to provide cutting-edge findings in cell biology and histology. PMID:27273367
NASA Astrophysics Data System (ADS)
Smirnova, Tatiana; Andrianov, Andrey; Shishov, Vladimir
We present results obtained from analysis of our observations carried out on the space-ground interferometer RadioAstron at frequency of 324 MHz. Observations were conducted on 04.07.12 with a baseline projection of 60000 km. We used two ground telescopes: GBT and WSRT with the space radio telescope (SRT). Notable visibility amplitudes were detected at all baseline projections. We found that frequency structure of interstellar scintillation for pulsar B1919+21 is defined by angular refraction with refractive angle: θref ≈ 60 mas. Cosmic prism is located near to observer with a distance of about 10 pc. The scattering angle is resolved by cosmic interferometer and θsc is about 1 mas. The temporal structure of scintillation is mainly defined by interstellar plasma of extended media, but frequency structure - by extended media and prism influence. We detected also the influence of ionosphere on a phase variations of interferometer.
Selective colors reflection from stratified aragonite calcium carbonate plates of mollusk shells.
Lertvachirapaiboon, Chutiparn; Parnklang, Tewarak; Pienpinijtham, Prompong; Wongravee, Kanet; Thammacharoen, Chuchaat; Ekgasit, Sanong
2015-08-01
An interaction between the incident light and the structural architecture within the shell of Asian green mussel (Perna viridis) induces observable pearlescent colors. In this paper, we investigate the influence of the structural architecture on the expressed colors. After a removal of the organic binder, small flakes from crushed shells show vivid rainbow reflection under an optical microscope. An individual flake expresses vivid color under a bright-field illumination while become transparent under a dark-field illumination. The expressed colors of the aragonite flakes are directly associated with its structural architecture. The flakes with aragonite thickness of 256, 310, and 353 nm, respectively, appear blue, green, and red under an optical microscope. The spectral simulation corroborates the experimentally observed optical effects as the flakes with thicker aragonite layers selectively reflected color with longer wavelengths. Flakes with multiple aragonite thicknesses expressed multi-color as the upper aragonite layers allow reflected colors from the lower layers to be observed. Copyright © 2015 Elsevier Inc. All rights reserved.
An Evaluation of Cosmological Models from the Expansion and Growth of Structure Measurements
NASA Astrophysics Data System (ADS)
Zhai, Zhongxu; Blanton, Michael; Slosar, Anže; Tinker, Jeremy
2017-12-01
We compare a large suite of theoretical cosmological models to observational data from the cosmic microwave background, baryon acoustic oscillation measurements of expansion, Type Ia supernova measurements of expansion, redshift space distortion measurements of the growth of structure, and the local Hubble constant. Our theoretical models include parametrizations of dark energy as well as physical models of dark energy and modified gravity. We determine the constraints on the model parameters, incorporating the redshift space distortion data directly in the analysis. To determine whether models can be ruled out, we evaluate the p-value (the probability under the model of obtaining data as bad or worse than the observed data). In our comparison, we find the well-known tension of H 0 with the other data; no model resolves this tension successfully. Among the models we consider, the large-scale growth of structure data does not affect the modified gravity models as a category particularly differently from dark energy models; it matters for some modified gravity models but not others, and the same is true for dark energy models. We compute predicted observables for each model under current observational constraints, and identify models for which future observational constraints will be particularly informative.
Mira variables: An informal review
NASA Technical Reports Server (NTRS)
Wing, R. F.
1980-01-01
The structure of the Mira variables is discussed with particular emphasis on the extent of their observable atmospheres, the various methods for measuring the sizes of these atmospheres, and the manner in which the size changes through the cycle. The results obtained by direct, photometric and spectroscopic methods are compared, and the problems of interpretation are addressed. Also, a simple model for the atmospheric structure and motions of Miras based on recent observations of the doubling of infrared molecualr times is described. This model, consisting of two atmospheric layers plus a circumstellar shell, provides a physically plausible picture of the atmosphere which is consistent with the photometrically measured magnitude and temperature variations as well as the spectroscopic data.
NASA Astrophysics Data System (ADS)
Kalita, Patricia; Specht, Paul; Root, Seth; Sinclair, Nicholas; Schuman, Adam; White, Melanie; Cornelius, Andrew L.; Smith, Jesse; Sinogeikin, Stanislav
2017-12-01
We report real-time observations of a phase transition in the ionic solid CaF2 , a model A B2 structure in high-pressure physics. Synchrotron x-ray diffraction coupled with dynamic loading to 27.7 GPa, and separately with static compression, follows, in situ, the fluorite to cotunnite structural phase transition, both on nanosecond and on minute time scales. Using Rietveld refinement techniques, we examine the kinetics and hysteresis of the transition. Our results give insight into the kinetic time scale of the fluorite-cotunnite phase transition under shock compression, which is relevant to a number of isomorphic compounds.
Extended Magnetic Reconnection Across the Dayside Magnetopause
NASA Technical Reports Server (NTRS)
Dunlop, M. W.; Zhang, Q.-H.; Bogdanova, Y. V.; Lockwood, M.; Pu, Z.; Hasegawa, H.; Wang, J.; Taylor, M. G. G. T.; Berchem, J.; Lavraund, B.;
2011-01-01
The extent of where magnetic reconnection (MR), the dominant process responsible for energy and plasma transport into the magnetosphere, operates across Earth's dayside magnetopause has previously been only indirectly shown by observations. We report the first direct evidence of X-line structure resulting from the operation of MR at each of two widely separated locations along the tilted, subsolar line of maximum current on Earth's magnetopause, confirming the operation of MR at two or more sites across the extended region where MR is expected to occur. The evidence results from in-situ observations of the associated ion and electron plasma distributions, present within each magnetic X-line structure, taken by two spacecraft passing through the active MR regions simultaneously.
Far-infrared observations of the exciting stars of Herbig-Haro objects. III - Circumstellar disks
NASA Technical Reports Server (NTRS)
Cohen, M.; Harvey, P. M.; Schwartz, R. D.
1985-01-01
Far-infrared observations of the exciting stars of Herbig-Haro objects are presented that (1) show these stars to be of low luminosity; (2) indicate that it is not usual for these objects themselves to be visible at far-infrared wavelengths; and (3) demonstrate the existence of spatially resolved, physically large, potentially disklike structures. These latter structures are resolved perpendicular to the directions of flow from the stars, but not parallel to the flows. In addition to these general properties, two new HH-exciting stars were discovered by searching along the extrapolated proper motion vectors for these HHs; and the jetlike object 'DG Tau B' was also detected.
Structure of Boron Nitride Nanotubes: Tube Closing Vs. Chirality
NASA Technical Reports Server (NTRS)
Srivastava, Deepak; Menon, Madhu
1998-01-01
The structure of boron nitride nanotubes is investigated using a generalized tight-binding molecular dynamics method. It is shown that dynamic relaxation results in a wavelike or "rippled" surface in which the B atoms rotate inward and the N atoms move outward, reminiscent of the surface relaxation of the III-V semiconductors. More importantly, the three different morphologies of the tube closing with flat, conical and amorphous ends, as observed in experiments, are shown to be directly related to the tube chiralities. The abundance of flat end tubes observed in experiments is, thus, shown to be an indication of the greater stability of "zig-zag" BN tubes over the "arm-chair" tubes under experimental conditions.
Kalita, Patricia E.; Specht, Paul Elliot; Root, Seth; ...
2017-12-21
Here, we report real-time observations of a phase transition in the ionic solid CaF 2, a model AB 2 structure in high-pressure physics. Synchrotron x-ray diffraction coupled with dynamic loading to 27.7 GPa, and separately with static compression, follows, in situ, the fluorite to cotunnite structural phase transition, both on nanosecond and on minute time scales. Using Rietveld refinement techniques, we examine the kinetics and hysteresis of the transition. Our results give insight into the kinetic time scale of the fluorite-cotunnite phase transition under shock compression, which is relevant to a number of isomorphic compounds.
Immiscible phase incorporation during directional solidification of hypermonotectics
NASA Technical Reports Server (NTRS)
Andrews, J. Barry; Merrick, Roger A.
1993-01-01
Solidification processes in immiscible samples were investigated by directly observing the events taking place at the solid-liquid interface during directional solidification. Visualization of these events was made possible through the use of a transparent metal analog system and a temperature gradient stage assembly fitted to an optical microscope. The immiscible transparent analog system utilized was the succinonitrile-glycerol system. This system has been shown to exhibit the same morphological transitions as observed in metallic alloys of monotectic composition. Both monotectic and hypermonotectic composition samples were directionally solidified in order to gain an improved understanding of the manner in which the excess hypermonotectic liquid is incorporated into the solidifying structure. The processing conditions utilized prevented sedimentation of the excess hypermonotectic liquid by directionally solidifying the samples in very thin (13 microns), horizontally oriented cells. High thermal gradient to growth rate ratios (G/R) were used in an effort to prevent constitutional supercooling and the subsequent formation of L(sub 2) droplets in advance of the solidification front during the growth of fibrous composite structures. Results demonstrated that hypermonotectic composites could be produced in samples up to two weight percent off of the monotectic composition by using a G/R ratio greater than or equal to 4.6 x 10(exp 4) C(s)/mm(sup 2) to avoid constitutional supercooling. For hypermonotectic samples processed with G/R ratios below 4.6 x 10(exp 4) C(s)/mm(sup 2), constitutional supercooling occurred and resulted in slight interfacial instability. For these samples, two methods of incorporation of the hypermonotectic liquid were observed and are reported. The correlation between the phase spacing, lambda, and the growth rate, R, was examined and was found to obey a relationship generally associated with a diffusion controlled coupled growth process. For samples with compositions ranging from the monotectic composition up to 2 percent off of the monotectic composition, data indicated that the square of the phase spacing (lambda) varied linearly with the inverse of the growth rate (R).
Lance, Amanda; Yang, Chih-Chao; Swamydas, Muthulekha; Dean, Delphine; Deitch, Sandy; Burg, Karen J L; Dréau, Didier
2016-01-01
The extracellular matrix (ECM) contributes to the generation and dynamic of normal breast tissue, in particular to the generation of polarized acinar and ductal structures. In vitro 3D culture conditions, including variations in the composition of the ECM, have been shown to directly influence the formation and organization of acinus-like and duct-like structures. Furthermore, the density of the ECM appears to also play a role in the normal mammary tissue and tumour formation. Here we show that the density of the ECM directly influences the number, organization and function of breast acini. Briefly, non-malignant human breast MCF10A cells were incubated in increasing densities of a Matrigel®-collagen I matrix. Elastic moduli near and distant to the acinus structures were measured by atomic force microscopy, and the number of acinus structures was determined. Immunochemistry was used to investigate the expression levels of E-cadherin, laminin, matrix metalloproteinase-14 and ß-casein in MCF10A cells. The modulus of the ECM was significantly increased near the acinus structures and the number of acinus structures decreased with the increase in Matrigel-collagen I density. As evaluated by the expression of laminin, the organization of the acinus structures present was altered as the density of the ECM increased. Increases in both E-cadherin and MMP14 expression by MCF10A cells as ECM density increased were also observed. In contrast, MCF10A cells expressed lower ß-casein levels as the ECM density increased. Taken together, these observations highlight the key role of ECM density in modulating the number, organization and function of breast acini. Copyright © 2013 John Wiley & Sons, Ltd.
NASA Astrophysics Data System (ADS)
Pyak, P. E.; Usachenko, V. I.
2018-03-01
The phenomenon of pronounced peak structure(s) of longitudinal momentum distributions as well as a spike-like structure of low-energy spectra of photoelectrons emitted from laser-irradiated Ar and Ne atoms in a single ionization process is theoretically studied in the tunneling and multiphoton regimes of ionization. The problem is addressed assuming only the direct above-threshold ionization (ATI) as a physical mechanism underlying the phenomenon under consideration (viz. solely contributing to observed photoelectron momentum distributions (PMD)) and using the Coulomb-Volkov (CV) ansatz within the frame of conventional strong-field approximation (SFA) applied in the length-gauge formulation. The developed CV-SFA approach also incorporates the density functional theory essentially exploited for numerical composition of initial (laser-free) atomic state(s) constructed from atomic orbitals of Gaussian type. Our presented CV-SFA based (and laser focal-volume averaged) calculation results proved to be well reproducing both the pronounced double-peak and/or ATI-like multi-peak structure(s) experimentally observed in longitudinal PMD under conditions of tunneling and/or multiphoton regime, respectively. In addition, our CV-SFA results presented for tunneling regime also suggest and remarkably reproduce a pronounced structure observed in relevant experiments as a ‘spike-like’ enhanced maximum arising in low-energy region (around the value of about 1 eV) of photoelectron spectra. The latter consistency allows to identify and interpret these results as the so-called low-energy structure (LES) since the phenomenon proved to appear as the most prominent if the influence of Coulomb potential on photoelectron continuum states is maximally taken into account under calculations (viz. if the parameter Z in CV’s functions is put equal to 1). Moreover, the calculated LES proved to correspond (viz., established as closely related) to the mentioned double-peak structure arising in the low-momentum region ({p}| | ≤slant | 0.2| a.u.) of longitudinal PMDs calculated under condition of the tunneling regime. Thus, the phenomena under consideration can be well understood and adequately interpreted beyond the terms and/or concepts of various different alternative strong-field approaches and models (such as e.g., extensively invoked and exploited nowadays though, more sophisticated SFA-based ‘rescattering’ mechanism) compared to which, the currently applied CV-SFA model (through the same underlying physical mechanism of solely direct ATI suggested) is additionally able to provide and reveal an intimate and transparent interrelation between the phenomena of LES and double-peak structure arising in PMDs observed in the tunneling regime.
Harm to Those Who Serve: Effects of Direct and Vicarious Customer-Initiated Workplace Aggression.
Dupré, Kathryne E; Dawe, Kimberly-Anne; Barling, Julian
2014-09-01
While there is a large body of research on the effects of being a direct target of workplace aggression, there is far less research on the vicarious experience of aggression at work, despite the fact that more people experience workplace aggression vicariously (i.e., observe it or hear about it) than they do directly. In this study, we develop and test a model of the effects of direct and vicarious exposure to aggression that is directed at employees by customers. Structural equation modeling provided support for the proposed model, in which direct and vicarious workplace aggression influences the perceived risk of future workplace aggression, which in turn affects organizational attachment (affective commitment and turnover intentions) and individual well-being (psychological and physical). Conceptual research and policy implications are discussed. © The Author(s) 2014.
NASA Astrophysics Data System (ADS)
Bender, H.; Ring, U.; Almqvist, B. S. G.; Glodny, J.; Grasemann, B.; Stephens, M. B.
2016-12-01
The recent COSC-1 drilling programme (Lorenz et al., 2015), discovery of microdiamonds (Majka et al., 2014) and discussion of extrusion-wedge tectonics (Grimmer et al., 2015) outline the importance of the Seve Nappe Complex (SNC) and its key role during the Caledonian orogeny. The kinematic evolution of the SNC is crucial for better understanding the entire mountain belt. Thorough structural mapping of the SNC and adjacent units was conducted in western and northern Jämtland, central Sweden. Complementary microstructural investigations strengthen the field observations and show consistent top-to-the-SE directed movement through all studied tectonic units. Amphibolite-facies deformation can be inferred from fabrics in the SNC, which are overprinted by greenschist-facies structures showing the same kinematics throughout the studied section of the nappe stack. These data indicate persistence of the same foreland-directed kinematics over a wide range of pressure-temperature conditions in space and time. Currently proposed models for exhuming high-grade metamorphic rocks in collisional orogens fail to explain these observations and highlight the need for discussing new tectonic concepts for the Scandinavian Caledonides. References: Grimmer et al., 2015, Geology 43 (4); Lorenz et al., 2015, Scientific Drilling 19; Majka et al. 2014, Geology 42 (12).
Laboratory studies in ultraviolet solar physics
NASA Technical Reports Server (NTRS)
Parkinson, W. H.; Kohl, J. L.; Gardner, L. D.; Raymond, J. C.; Smith, P. L.
1991-01-01
The research activity comprised the measurement of basic atomic processes and parameters which relate directly to the interpretation of solar ultraviolet observations and to the development of comprehensive models of the component structures of the solar atmosphere. The research was specifically directed towards providing the relevant atomic data needed to perform and to improve solar diagnostic techniques which probe active and quiet portions of the solar chromosphere, the transition zone, the inner corona, and the solar wind acceleration regions of the extended corona. The accuracy with which the physical conditions in these structures can be determined depends directly on the accuracy and completeness of the atomic and molecular data. These laboratory data are used to support the analysis programs of past and current solar observations (e.g., the Orbiting solar Observatories, the Solar Maximum Mission, the Skylab Apollo Telescope Mount, and the Naval Research Laboratory's rocket-borne High Resolution Telescope and Spectrograph). In addition, we attempted to anticipate the needs of future space-borne solar studies such as from the joint ESA/NASA Solar and Heliospheric Observatory (SOHO) spacecraft. Our laboratory activities stressed two categories of study: (1) the measurement of absolute rate coefficients for dielectronic recombination and electron impact excitation; and (2) the measurement of atomic transition probabilities for solar density diagnostics. A brief summary of the research activity is provided.
X-ray diffraction of solid tin to 1.2 TPa
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lazicki, A.; Rygg, J. R.; Coppari, F.
2015-08-12
In this study, we report direct in situ measurements of the crystal structure of tin between 0.12 and 1.2 TPa, the highest stress at which a crystal structure has ever been observed. Using angle-dispersive powder x-ray diffraction, we find that dynamically compressed Sn transforms to the body-centered-cubic (bcc) structure previously identified by ambient-temperature quasistatic-compression studies and by zero-kelvin density-functional theory predictions between 0.06 and 0.16 TPa. However, we observe no evidence for the hexagonal close-packed (hcp) phase found by those studies to be stable above 0.16 TPa. Instead, our results are consistent with bcc up to 1.2 TPa. We conjecturemore » that at high temperature bcc is stabilized relative to hcp due to differences in vibrational free energy.« less
Peptide structure: Its effect on penetration into human hair.
Silva, Carla J S M; Vasconcelos, Andreia; Cavaco-Paulo, Artur
2007-01-01
The influence of the peptide structure on its penetration inside hair was studied, together with the effect of hair bleaching (oxidation). For that reason, the outcome of positioning a charged sequence (KAKAK) either at the N or C terminal on hair penetration has been studied for peptides with 17 residues each. It was observed that the penetration of these peptides into hair was driven by electrostatic interactions, where the position of the charged group at the peptide structure was of major importance. The penetration was only achieved for damaged hair due to its higher negative charge at the membrane surface. It was also observed that the peptides were able to restore the original tensile strength of bleached hair. Consequently, the knowledge of hair surface properties is of extreme importance when designing peptides directed for hair treatment.
The vector structure of active magnetic fields
NASA Technical Reports Server (NTRS)
Parker, E. N.
1985-01-01
Observations are needed to show the form of the strains introduced into the fields above the surface of the Sun. The longitudinal component alone does not provide the basic information, so that it has been necessary in the past to use the filamentary structure observed in H sub alpha to supplement the longitudinal information. Vector measurements provide the additional essential information to determine the strains, with the filamentary structure available as a check for consistency. It is to be expected, then, that vector measurements will permit a direct mapping of the strains imposed on the magnetic fields of active regions. It will be interesting to study the relation of those strains to the emergence of magnetic flux, flares, eruptive prominences, etc. In particular we may hope to study the relaxation of the strains via the dynamical nonequilibrium.
Atomic resolution study of the interfacial bonding at Si3N4/CeO2-δ grain boundaries
NASA Astrophysics Data System (ADS)
Walkosz, W.; Klie, R. F.; Öǧüt, S.; Borisevich, A.; Becher, P. F.; Pennycook, S. J.; Idrobo, J. C.
2008-08-01
Using a combination of atomic-resolution Z-contrast imaging and electron energy-loss spectroscopy (EELS) in the scanning transmission electron microscope, we examine the atomic and electronic structures at the interface between Si3N4 (101¯0) and CeO2-d intergranular film (IGF). Ce atoms are observed to segregate to the interface in a two-layer periodic arrangement, which is significantly different from the structure observed in a previous study. Our EELS experiments show (i) oxygen in direct contact with the terminating Si3N4 open-ring structures, (ii) a change in the Ce valence from a nominal oxidation state of +3 to almost +4 moving from the interface into the IGF, and (iii) a uniform concentration of Si in the film.
Binocular vision in amblyopia: structure, suppression and plasticity.
Hess, Robert F; Thompson, Benjamin; Baker, Daniel H
2014-03-01
The amblyopic visual system was once considered to be structurally monocular. However, it now evident that the capacity for binocular vision is present in many observers with amblyopia. This has led to new techniques for quantifying suppression that have provided insights into the relationship between suppression and the monocular and binocular visual deficits experienced by amblyopes. Furthermore, new treatments are emerging that directly target suppressive interactions within the visual cortex and, on the basis of initial data, appear to improve both binocular and monocular visual function, even in adults with amblyopia. The aim of this review is to provide an overview of recent studies that have investigated the structure, measurement and treatment of binocular vision in observers with strabismic, anisometropic and mixed amblyopia. © 2014 The Authors Ophthalmic & Physiological Optics © 2014 The College of Optometrists.
NASA Astrophysics Data System (ADS)
Awe, Thomas
2017-10-01
Implosions on the Z Facility assemble high-energy-density plasmas for radiation effects and ICF experiments, but achievable stagnation pressures and temperatures are degraded by the Magneto-Rayleigh-Taylor (MRT) instability. While the beryllium liners (tubes) used in Magnetized Liner Inertial Fusion (MagLIF) experiments are astonishingly smooth (10 to 50 nm RMS roughness), they also contain distributed micron-scale resistive inclusions, and large MRT amplitudes are observed. Early in the implosion, an electrothermal instability (ETI) may provide a perturbation which greatly exceeds the initial surface roughness of the liner. Resistive inhomogeneities drive nonuniform current density and Joule heating, resulting in locally higher temperature, and thus still higher resistivity. Such unstable temperature and pressure growth produce density perturbations which seed MRT. For MagLIF liners, ETI seeding of MRT has been inferred by evaluating late-time MRT, but a direct observation of ETI is not made. ETI is directly observed on the surface of 1.0-mm-diameter solid Al rods pulsed to 1 MA in 100 ns via high resolution gated optical imaging (2 ns temporal and 3 micron spatial resolution). Aluminum 6061 alloy rods, with micron-scale resistive inclusions, consistently first demonstrate overheating from distinct, 10-micron-scale, sub-eV spots, which 5-10 ns later merge into azimuthally stretched elliptical spots and discrete strata (40-100 microns wide by 10 microns tall). Axial plasma filaments form shortly thereafter. Surface plasma can be suppressed for rods coated with dielectric, enabling extended study of the evolution of stratified ETI structures, and experimental inference of ETI growth rates. This fundamentally new and highly 3-dimensional dataset informs ETI physics, including when the ETI seed of MRT may be initiated.
Near-Infrared Polarimetric Imaging of Disks around Young Intermediate-mass Stars in SEEDS
NASA Astrophysics Data System (ADS)
Fukagawa, Misato; Hashimoto, Jun; Grady, C. A.; Momose, Munetake; Wisniewski, J. P.; Okamoto, Yoshiko; Muto, Takayuki; Kusakabe, Nobuhiko; Bonnefoy, Mickael; Kotani, Takayuki; Maruta, Yayoi; Tamura, Motohide; Seeds/Hiciao/Ao188 Collaboration,
2013-07-01
We present our recent results to directly image circumstellar disks around Herbig Fe/Ae/Be stars in scattered light with Subaru. Observations of such young disks are critically important to understand how disks evolve possibly under the mutual interaction with new-born planets. One of the observational approaches is direct imaging in scattered light, and the progress in this field since PPV can be found in the ability to prove inner regions of disks. This improvement largely owes to the technique of polarization differential imaging (PDI) which provides higher contrast by extracting scattered light from the disk while suppressing unpolarized stellar light. Strategic Exploration of Exoplanets and Disks with Subaru (SEEDS) is the project dedicated to exoplanet hunting and study of circumstellar disks by direct imaging. Since its beginning in 2009, thirteen Herbig Fe/Ae/Be stars have been observed primarily in H band (1.6 micron). The PDI method has been employed with adaptive optics, enabling us to look into the inner region as close as 0.2 arcsec (˜30 AU) in radius with the typical angular resolution of 0.06 arcsec (˜8 AU). As a result, the SEEDS imagery has newly uncovered rich structures such as spiral arms, inner holes, and gaps for (pre-)transitional disks while suggested the variably illuminated disks for primordial systems. The highlight is the discovery of two spiral arms each for SAO 206462 and MWC 758. The spiral feature has been uniquely found toward Herbig Fe/Aes so far, which might be due to their warmer disks producing arms loosely wound and more easily detected. The observed morphology can be interpreted by the density-wave model, and those disks are implied to harbor Jupiter-mass companions as the exciting sources of the spiral structures according to these models.
Ground Based Program for the Physical Analysis of Macromolecular Crystal Growth
NASA Technical Reports Server (NTRS)
Malkin, Alexander J.
1998-01-01
During the past year we have focused on application of in situ Atomic Force Microscopy (AFM) for studies of the growth mechanisms and kinetics of crystallization for different macromolecular systems. Mechanisms of macrostep formation and their decay, which are important in understanding of defect formation, were studied on the surfaces of thaumatin, catalase, canavalin and lysozyme crystals. Experiments revealed that step bunching on crystalline surfaces occurred either due to two- or three-dimensional nucleation on the terraces of vicinal slopes or as a result of uneven step generation by complex dislocation sources. No step bunching arising from interaction of individual steps in the course of the experiment was observed. The molecular structure of the growth steps for thaumatin and lipase crystals were deduced. It was further shown that growth step advance occurs by incorporation of single protein molecules. In singular directions growth steps move by one-dimensional nucleation on step edges followed by lateral growth. One-dimensional nuclei have different sizes, less then a single unit cell, varying for different directions of step movement. There is no roughness due to thermal fluctuations, and each protein molecule which incorporated into the step remained. Growth kinetics for catalase crystals was investigated over wide supersaturation ranges. Strong directional kinetic anisotropy in the tangential step growth rates in different directions was seen. The influence of impurities on growth kinetics and cessation of macromolecular crystals was studied. Thus, for catalase, in addition to pronounced impurity effects on the kinetics of crystallization, we were also able to directly observe adsorption of some impurities. At low supersaturation we repeatedly observed filaments which formed from impurity molecules sedimenting on the surfaces. Similar filaments were observed on the surfaces of thaumatin, canavalin and STMV crystals as well, but the frequency was low compared with catalase crystallization. Cessation of growth of xylanase and lysozyme crystals was also observed and appeared to be a consequence of the formation of dense impurity adsorption layers. Attachment: "An in situ AFM investigation of catalase crystallization", "Atomic force microscopy studies of living cells: visualization of motility, division, aggregation, transformation, and apoptosis", AFM studies on mechanisms of nucleation and growth of macromolecular crystals", and "In situ atomic force microscopy studies of surface morphology, growth kinetics, defect structure and dissolution in macromolecular crystallization".
Statistical Issues in Galaxy Cluster Cosmology
NASA Technical Reports Server (NTRS)
Mantz, Adam
2013-01-01
The number and growth of massive galaxy clusters are sensitive probes of cosmological structure formation. Surveys at various wavelengths can detect clusters to high redshift, but the fact that cluster mass is not directly observable complicates matters, requiring us to simultaneously constrain scaling relations of observable signals with mass. The problem can be cast as one of regression, in which the data set is truncated, the (cosmology-dependent) underlying population must be modeled, and strong, complex correlations between measurements often exist. Simulations of cosmological structure formation provide a robust prediction for the number of clusters in the Universe as a function of mass and redshift (the mass function), but they cannot reliably predict the observables used to detect clusters in sky surveys (e.g. X-ray luminosity). Consequently, observers must constrain observable-mass scaling relations using additional data, and use the scaling relation model in conjunction with the mass function to predict the number of clusters as a function of redshift and luminosity.
Biodegradation of Direct Blue 15 by free and immobilized Trametes versicolor.
Pazarlioglu, Nurdan Kasikara; Akkaya, Alper; Akdogan, Hatice Ardag; Gungor, Burcin
2010-07-01
To investigate biodegradability by Trametes versicolor, five structurally different direct azo-dyes--Direct Black 38, Direct Blue 15 (DB 15), Direct Orange 26, Direct Green 6, and Direct Yellow 12--were studied. The DB 15 was determined as the best biodegradable dye by this white-rot fungus. Laccase and manganese peroxidase activities were monitored with the biodegradation process; it was observed that laccase played an important role in the dye degradation, while manganese peroxidase activity could not be detected. Possible degradation products also were examined by gas chromatography-mass spectrometry, but no metabolite was detected after the degradation and/or decolorization process. To enhance performance of the fungi during the degradation, Trametes versicolor cells were immobilized in alginate beads. Then, DB 15 decolorization by immobilized Trametes versicolor was studied in a small-scale packed-bed reactor. The color removal efficiency in repeated batches was found to be 98 and 93% for 50 mg/L DB 15.
NASA Astrophysics Data System (ADS)
Daněk, J.; Klaiber, M.; Hatsagortsyan, K. Z.; Keitel, C. H.; Willenberg, B.; Maurer, J.; Mayer, B. W.; Phillips, C. R.; Gallmann, L.; Keller, U.
2018-06-01
We study strong-field ionization and rescattering beyond the long-wavelength limit of the dipole approximation with elliptically polarized mid-IR laser pulses. Full three-dimensional photoelectron momentum distributions (PMDs) measured with velocity map imaging and tomographic reconstruction revealed an unexpected sharp ridge structure in the polarization plane (2018 Phys. Rev. A 97 013404). This thin line-shaped ridge structure for low-energy photoelectrons is correlated with the ellipticity-dependent asymmetry of the PMD along the beam propagation direction. The peak of the projection of the PMD onto the beam propagation axis is shifted from negative to positive values when the sharp ridge fades away with increasing ellipticity. With classical trajectory Monte Carlo simulations and analytical analysis, we study the underlying physics of this feature. The underlying physics is based on the interplay between the lateral drift of the ionized electron, the laser magnetic field induced drift in the laser propagation direction, and Coulomb focusing. To apply our observations to emerging techniques relying on strong-field ionization processes, including time-resolved holography and molecular imaging, we present a detailed classical trajectory-based analysis of our observations. The analysis leads to the explanation of the fine structure of the ridge and its non-dipole behavior upon rescattering while introducing restrictions on the ellipticity. These restrictions as well as the ionization and recollision phases provide additional observables to gain information on the timing of the ionization and recollision process and non-dipole properties of the ionization process.
Metastable Structural Phases of Metals in Columns IVB to Vib, and Rows 4 TO 6 OF the Periodic Table
NASA Astrophysics Data System (ADS)
Nnolim, Neme; Tyson, Trevor
2002-03-01
Total energy calculations as a function of strain along the <001> direction have been carried out for the bcc metals V, Nb, Ta, Cr, Mo and W, and the hcp metals Ti, Zr and Hf, all in the block of the periodic table defined by columns IVB to VIB, and rows 4 to 6. Since strain along the <001> direction corresponds to variation of the c lattice constant with respect to the a lattice constant, the total energy per unit cell has being calculated as a function of the c/a ratio. The highly accurate FP-LAPW (Full Potential Linearized Augmented Plane Wave) band structure method in the DFT (Density Functional Theory) formalism has been used for the calculations. In all cases except for the hcp column IVB elements, Zr, Hf and Ti, a metastable state was predicted from the calculations. Electronic properties are computed for all structures and are correlated with electrical and mechanical properties of metastable phases that have been observed experimentally. Properties of metastable phases, which were predicted in this work but which as of yet have not been observed experimentally, have also been predicted. Special attention is paid to the phases of tantalum and calculated transport properties are used to show that the observed high resistivity of the beta phase of tantalum relative to the alpha bcc phase cannot be explained solely by simple tetragonal distortions of the bcc phase.
Ingrassia, Pier Luigi; Prato, Federico; Geddo, Alessandro; Colombo, Davide; Tengattini, Marco; Calligaro, Sara; La Mura, Fabrizio; Franc, Jeffrey Michael; Della Corte, Francesco
2010-11-01
Functional exercises represent an important link between disaster planning and disaster response. Although these exercises are widely performed, no standardized method exists for their evaluation. To describe a simple and objective method to assess medical performance during functional exercise events. An evaluation tool comprising three data fields (triage, clinical maneuvers, and radio usage), accompanied by direct anecdotal observational methods, was used to evaluate a large functional mass casualty incident exercise. Seventeen medical responders managed 112 victims of a simulated building explosion. Although 81% of the patients were assigned the appropriate triage codes, evacuation from the site did not follow in priority. Required maneuvers were performed correctly in 85.2% of airway maneuvers and 78.7% of breathing maneuvers, however, significant under-treatment occurred, possibly due to equipment shortages. Extensive use of radio communication was documented. In evaluating this tool, the structured markers were informative, but further information provided by direct observation was invaluable. A three-part tool (triage, medical maneuvers, and radio usage) can provide a method to evaluate functional mass casualty incident exercises, and is easily implemented. For the best results, it should be used in conjunction with direct observation. The evaluation tool has great potential as a reproducible and internationally recognized tool for evaluating disaster management exercises. Copyright © 2010 Elsevier Inc. All rights reserved.
Structure of the floating water bridge and water in an electric field
Skinner, Lawrie B.; Benmore, Chris J.; Shyam, Badri; Weber, J. K. R.; Parise, John B.
2012-01-01
The floating water bridge phenomenon is a freestanding rope-shaped connection of pure liquid water, formed under the influence of a high potential difference (approximately 15 kV). Several recent spectroscopic, optical, and neutron scattering studies have suggested that the origin of the bridge is associated with the formation of anisotropic chains of water molecules in the liquid. In this work, high energy X-ray diffraction experiments have been performed on a series of floating water bridges as a function of applied voltage, bridge length, and position within the bridge. The two-dimensional X-ray scattering data showed no direction-dependence, indicating that the bulk water molecules do not exhibit any significant preferred orientation along the electric field. The only structural changes observed were those due to heating, and these effects were found to be the same as for bulk water. These X-ray scattering measurements are supported by molecular dynamics (MD) simulations which were performed under electric fields of 106 V/m and 109 V/m. Directional structure factor calculations were made from these simulations parallel and perpendicular to the E-field. The 106 V/m model showed no significant directional-dependence (anisotropy) in the structure factors. The 109 V/m model however, contained molecules aligned by the E-field, and had significant structural anisotropy. PMID:23010930
Plant, Jennifer L; Corden, Mark; Mourad, Michelle; O'Brien, Bridget C; van Schaik, Sandrijn M
2013-05-01
Self-directed learning requires self-assessment of learning needs and performance, a complex process that requires collecting and interpreting data from various sources. Learners' approaches to self-assessment likely vary depending on the learner and the context. The aim of this study was to gain insight into how learners process external information and apply their interpretation of this information to their self-assessment and learning during a structured educational activity. The study combined quantitative performance data with qualitative interview data. Pediatric residents led video-recorded simulated resuscitations and rated their crisis resource management skills on a validated 6-item instrument. Three independent observers rated the videos using the same instrument. During semi-structured interviews, each resident reviewed the video, rerated performance, discussed the self-assessment process, and interpreted feedback and observer scores. Transcripts were analyzed for themes. Sixteen residents participated. Residents' self-assessed scores ranged widely but usually fell within two points of the observers. They almost universally lowered their scores when self-assessing after the video review. Five major themes emerged from qualitative analysis of their interviews: (1) residents found self-assessment important and useful in certain contexts and conditions; (2) residents varied in their self-directed learning behaviors after the simulated resuscitation; (3) quantitative observer assessment had limited usefulness; (4) video review was difficult but useful; and (5) residents focused on their weaknesses and felt a need for constructive feedback to enhance learning. The residents in our study almost uniformly embraced the importance of self-assessment for all medical professionals. Even though video review had a negative impact on their self-assessment scores and was perceived as painful, residents saw this as the most useful aspect of the study exercises residents. They were less accepting of the quantitative assessment by observers. Residents explained their tendency to focus on weaknesses as a way to create an incentive for learning, demonstrating that self-assessment is closely linked to self-directed learning. How learners can use video review and external assessment most effectively to guide their self-directed learning deserves further study.
NASA Astrophysics Data System (ADS)
Hui, F.; Qing, Z.; Gengen, Q.; Fagen, P.; Dawei, B.; Baotun, G.; Jingqi, L.; Changwang, L.; Xiaochang, L.; Meixing, H.; Bingrui, D.
2012-12-01
Being constituted by the Seberia, Northern China fossil plate and Pacific Plate, the tectonics of Northeast China are very complicated. In order to study the electrical structure in these areas, the project SinoProbe-01-04 'Experimental study of 'standard monitoring network' of continental EM parameters in Northeast China' have established a 4°×4°regional MT array covering the whole Northeast China(Fig. 1). To make sure that MT data observed on each standard point representatively, a cross profile with the standard point being center and eight auxiliary measuring points around has been designed in practical work, and the same direction of the physical measuring point should have 20 km space, the observation time should be more than 120 hours in standard point and more than 24 hours in each auxiliary station. Both broadband MT equipment (V5-2000) and long-period MT equipment (LEMI-417M) have been used together in standard point, then the ultra-wideband electromagnetic signals at 320HZ-1/10000Hz can be acquired by combining the field data observed by each equipment. Eleven MT standard network control point with total 99 physical measuring points have been finished in 2010, then those works were repeated again in 2011 to make sure observed result reliable. Based on the observed result, this article preliminary analysis the electrical structure of each major tectonic element in Northeast China, which including the regularity of distribution of regional electrical spindle, the distribution characteristics of vertical conductivity, development status of the low resistivity layer in the crust, and the depth of the high conductivity layer in upper mantle. It has been founded that the electrical features of the major tectonic element in Northeast China are different and appear electrical-heterogeneous in cross direction. Fig.1 MT array observed site
Hwang, Wang-Taek; Min, Misook; Jeong, Hyunhak; Kim, Dongku; Jang, Jingon; Yoo, Daekyung; Jang, Yeonsik; Kim, Jun-Woo; Yoon, Jiyoung; Chung, Seungjun; Yi, Gyu-Chul; Lee, Hyoyoung; Wang, Gunuk; Lee, Takhee
2016-11-25
We investigated the electrical characteristics and the charge transport mechanism of pentacene vertical hetero-structures with graphene electrodes. The devices are composed of vertical stacks of silicon, silicon dioxide, graphene, pentacene, and gold. These vertical heterojunctions exhibited distinct transport characteristics depending on the applied bias direction, which originates from different electrode contacts (graphene and gold contacts) to the pentacene layer. These asymmetric contacts cause a current rectification and current modulation induced by the gate field-dependent bias direction. We observed a change in the charge injection barrier during variable-temperature current-voltage characterization, and we also observed that two distinct charge transport channels (thermionic emission and Poole-Frenkel effect) worked in the junctions, which was dependent on the bias magnitude.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wang, Dong, E-mail: wang.dong.539@m.kyushu-u.ac.jp; Maekura, Takayuki; Kamezawa, Sho
We demonstrated direct band gap (DBG) electroluminescence (EL) at room temperature from n-type bulk germanium (Ge) using a fin type asymmetric lateral metal/Ge/metal structure with TiN/Ge and HfGe/Ge contacts, which was fabricated using a low temperature (<400 °C) process. Small electron and hole barrier heights were obtained for TiN/Ge and HfGe/Ge contacts, respectively. DBG EL spectrum peaked at 1.55 μm was clearly observed even at a small current density of 2.2 μA/μm. Superlinear increase in EL intensity was also observed with increasing current density, due to superlinear increase in population of elections in direct conduction band. The efficiency of hole injection was alsomore » clarified.« less
NASA Astrophysics Data System (ADS)
Xiong, Chao; Xu, Jiyao; Wu, Kun; Yuan, Wei
2018-02-01
The lower pair satellites of Swarm mission, flying side-by-side and separated by 1.4° in longitude (about 150 km), usually observed equatorial plasma depletions (EPDs) showing quite different structures, and sometime even only one satellite observed EPD. In this study, we provided 6-h continuous observations of EPDs on the night of 23-24 September 2014, from an all-sky imager located at Fuke (geographic:19.5°N,109.1°E), south of China. From the airglow images the EPDs were found with longitudinal extensions of about 50 km and all tilted from northwest to southeast direction. We further checked the in situ electron density simultaneously measured by the Swarm lower pair satellites and found the differences of Swarm in situ electron densities explained well by the longitudinally thin structure of EPDs observed from the all-sky imager. During later periods the bifurcation and merging were observed by the airglow images, and it was the first time to report both processes in the evolution of one EPD. The bifurcation was first observed at the higher-latitude part, and then observed at lower latitudes of EPD. The subbranches generated through bifurcation showed even thinner longitudinal extension of about 20-30 km, and later the subbranches started to merge with each other, forming a really complicated mesh of depleted regions.
X ray timing observations and gravitational physics
NASA Technical Reports Server (NTRS)
Michelson, Peter F.; Wood, Kent S.
1989-01-01
Photon-rich x ray observations on bright compact galactic sources will make it possible to detect many fast processes that may occur in these systems on millisecond and submillisecond timescales. Many of these processes are of direct relevance to gravitational physics because they arise in regions of strong gravity near neutron stars and black holes where the dynamical timescales for compact objects of stellar mass are milliseconds. To date, such observations have been limited by the detector area and telemetry rates available. However, instruments such as the proposed X ray Large Array (XLA) would achieve collecting areas of about 100 sq m. This instrument has been described elsewhere (Wood and Michelson 1988) and was the subject of a recent prephase A feasibility study at Marshall Space Flight Center. Observations with an XLA class instrument will directly impact five primary areas of astrophysics research: the attempt to detect gravitational radiation, the study of black holes, the physics of mass accretion onto compact objects, the structure of neutron stars and nuclear matter, and the characterization of dark matter in the universe. Those observations are discussed that are most directly relevant to gravitational physics: the search for millisecond x ray pulsars that are potential sources of continuous gravitational radiation; and the use of x ray timing observations to probe the physical conditions in extreme relativistic regions of space near black holes, both stellar-sized and supermassive.
Morrow, Benjamin M.; Cerreta, E. K.; McCabe, R. J.; ...
2015-05-14
In-situ straining was used to study deformation behavior of hexagonal close-packed (hcp) metals.Twinning and dislocation motion, both essential to plasticity in hcp materials, were observed.Typically, these processes are characterized post-mortem by examining remnant microstructural features after straining has occurred. By imposing deformation during imaging, direct observation of active deformation mechanisms is possible. This work focuses on straining of structural metals in a transmission electron microscope (TEM), and a recently developed technique that utilizes familiar procedures and equipment to increase ease of experiments. In-situ straining in a TEM presents several advantages over conventional post-mortem characterization, most notably time-resolution of deformation andmore » streamlined identification of active deformation mechanisms. Drawbacks to the technique and applicability to other studies are also addressed. In-situ straining is used to study twin boundary motion in hcp magnesium. A {101¯2} twin was observed during tensile and compressive loading. Twin-dislocation interactions are directly observed. Notably, dislocations are observed to remain mobile, even after multiple interactions with twin boundaries, a result which suggests that Basinki’s dislocation transformation mechanism by twinning is not present in hcp metals. The coupling of in-situ straining with traditional post-mortem characterization yields more detailed information about material behavior during deformation than either technique alone.« less
Atomic Scale Structure of (001) Hydrogen-Induced Platelets in Germanium
NASA Astrophysics Data System (ADS)
David, Marie-Laure; Pizzagalli, Laurent; Pailloux, Fréderic; Barbot, Jean François
2009-04-01
An accurate characterization of the structure of hydrogen-induced platelets is a prerequisite for investigating both hydrogen aggregation and formation of larger defects. On the basis of quantitative high resolution transmission electron microscopy experiments combined with extensive first principles calculations, we present a model for the atomic structure of (001) hydrogen-induced platelets in germanium. It involves broken Ge-Ge bonds in the [001] direction that are dihydride passivated, vacancies, and trapped H2 molecules, showing that the species involved in platelet formation depend on the habit plane. This model explains all previous experimental observations.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kohno, Hideo, E-mail: kohno.hideo@kochi-tech.ac.jp; Masuda, Yusuke
2015-05-11
When the direction of flattening of a carbon nanotube changes during growth mediated by a metal nanoparticle, a carbon nanotetrahedron is formed in the middle of the carbon nanoribbon. We report the bending properties of the carbon nanotetrahedron/nanoribbon structure using a micro-manipulator system in a transmission electron microscope. In many cases, bending occurs at an edge of the carbon nanotetrahedron. No significant change is observed in the tetrahedron's shape during bending, and the bending is reversible and repeatable. Our results show that the carbon nanotetrahedron/nanoribbon structure has good durability against mechanical bending.
Structural and magnetic properties of non-stoichiometric Fe1-xO thin films
NASA Astrophysics Data System (ADS)
Muhammed Shameem P., V.; Mekala, Laxman; Kumar, M. Senthil
2018-04-01
The Fe1-xO thin films of various iron deficiencies (x) have been grown at ambient temperature by reactive dc magnetron sputtering technique and their structural and magnetic properties are studied. The structural study shows that the films are polycrystalline. As the iron content (1-x) varies from 0.924 to 0.855 a clear consistent change in the preferential orientation of the grains from [111] to the [200] direction is observed. The magnetization measurements show the possible existence of small superparamagnetic defect clusters at 300 K and large spinel-type defect clusters below the Neel temperature.
The Optical Janus Effect: Asymmetric Structural Color Reflection Materials.
England, Grant T; Russell, Calvin; Shirman, Elijah; Kay, Theresa; Vogel, Nicolas; Aizenberg, Joanna
2017-08-01
Structurally colored materials are often used for their resistance to photobleaching and their complex viewing-direction-dependent optical properties. Frequently, absorption has been added to these types of materials in order to improve the color saturation by mitigating the effects of nonspecific scattering that is present in most samples due to imperfect manufacturing procedures. The combination of absorbing elements and structural coloration often yields emergent optical properties. Here, a new hybrid architecture is introduced that leads to an interesting, highly directional optical effect. By localizing absorption in a thin layer within a transparent, structurally colored multilayer material, an optical Janus effect is created, wherein the observed reflected color is different on one side of the sample than on the other. A systematic characterization of the optical properties of these structures as a function of their geometry and composition is performed. The experimental studies are coupled with a theoretical analysis that enables a precise, rational design of various optical Janus structures with highly controlled color, pattern, and fabrication approaches. These asymmetrically colored materials will open applications in art, architecture, semitransparent solar cells, and security features in anticounterfeiting materials. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Characteristics of Eutectic α(Cr,Fe)-(Cr,Fe)23C6 in the Eutectic Fe-Cr-C Hardfacing Alloy
NASA Astrophysics Data System (ADS)
Lai, Hsuan-Han; Hsieh, Chih-Chun; Lin, Chi-Ming; Wu, Weite
2017-01-01
A specific eutectic (Cr,Fe)-(Cr,Fe)23C6 structure had been previously reported in the research studies of Fe-Cr-C hardfacing alloys. In this study, a close observation and discussion of the eutectic (Cr,Fe)-(Cr,Fe)23C6 were conducted. The eutectic solidification occurred when the chromium content of the alloy exceeded 35 wt pct. The eutectic structure showed a triaxial radial fishbone structure which was the so called "complex regular structure." Lamellar costa plates showed local asymmetry at two sides of a spine. Individual costae were able to combine as one, and spines showed extra branches. Costae that were nearly parallel to the heat flow direction were longer than those that were vertical to the heat flow direction. The triaxial spines preferred to intersect at 120 deg, while the costae preferred to intersect the spine at 90 deg and 35.26 deg due to the lattice relationships. The solidified metal near the fusion boundary showed an irregular structure instead of a complex regular structure. The reason for the irregular morphology was the high growth rate near the fusion boundary.
Switching from visibility to invisibility via Fano resonances: theory and experiment.
Rybin, Mikhail V; Filonov, Dmitry S; Belov, Pavel A; Kivshar, Yuri S; Limonov, Mikhail F
2015-03-05
Subwavelength structures demonstrate many unusual optical properties which can be employed for engineering of a new generation of functional metadevices, as well as controlled scattering of light and invisibility cloaking. Here we demonstrate that the suppression of light scattering for any direction of observation can be achieved for a uniform dielectric object with high refractive index, in a sharp contrast to the cloaking with multilayered plasmonic structures suggested previously. Our finding is based on the novel physics of cascades of Fano resonances observed in the Mie scattering from a homogeneous dielectric rod. We observe this effect experimentally at microwaves by employing high temperature-dependent dielectric permittivity of a glass cylinder with heated water. Our results open a new avenue in analyzing the optical response of high-index dielectric nanoparticles and the physics of cloaking.
Understanding older adults' usage of community green spaces in Taipei, Taiwan.
Pleson, Eryn; Nieuwendyk, Laura M; Lee, Karen K; Chaddah, Anuradha; Nykiforuk, Candace I J; Schopflocher, Donald
2014-01-27
As the world's population ages, there is an increasing need for community environments to support physical activity and social connections for older adults. This exploratory study sought to better understand older adults' usage and perceptions of community green spaces in Taipei, Taiwan, through direct observations of seven green spaces and nineteen structured interviews. Descriptive statistics from observations using the System for Observing Play and Recreation in Communities (SOPARC) confirm that older adults use Taipei's parks extensively. Our analyses of interviews support the following recommendations for age-friendly active living initiatives for older adults: make green spaces accessible to older adults; organize a variety of structured activities that appeal to older adults particularly in the morning; equip green spaces for age-appropriate physical activity; and, promote the health advantages of green spaces to older adults.
Switching from Visibility to Invisibility via Fano Resonances: Theory and Experiment
Rybin, Mikhail V.; Filonov, Dmitry S.; Belov, Pavel A.; Kivshar, Yuri S.; Limonov, Mikhail F.
2015-01-01
Subwavelength structures demonstrate many unusual optical properties which can be employed for engineering of a new generation of functional metadevices, as well as controlled scattering of light and invisibility cloaking. Here we demonstrate that the suppression of light scattering for any direction of observation can be achieved for a uniform dielectric object with high refractive index, in a sharp contrast to the cloaking with multilayered plasmonic structures suggested previously. Our finding is based on the novel physics of cascades of Fano resonances observed in the Mie scattering from a homogeneous dielectric rod. We observe this effect experimentally at microwaves by employing high temperature-dependent dielectric permittivity of a glass cylinder with heated water. Our results open a new avenue in analyzing the optical response of high-index dielectric nanoparticles and the physics of cloaking. PMID:25739324
The topology of large-scale structure. VI - Slices of the universe
NASA Astrophysics Data System (ADS)
Park, Changbom; Gott, J. R., III; Melott, Adrian L.; Karachentsev, I. D.
1992-03-01
Results of an investigation of the topology of large-scale structure in two observed slices of the universe are presented. Both slices pass through the Coma cluster and their depths are 100 and 230/h Mpc. The present topology study shows that the largest void in the CfA slice is divided into two smaller voids by a statistically significant line of galaxies. The topology of toy models like the white noise and bubble models is shown to be inconsistent with that of the observed slices. A large N-body simulation was made of the biased cloud dark matter model and the slices are simulated by matching them in selection functions and boundary conditions. The genus curves for these simulated slices are spongelike and have a small shift in the direction of a meatball topology like those of observed slices.
The topology of large-scale structure. VI - Slices of the universe
NASA Technical Reports Server (NTRS)
Park, Changbom; Gott, J. R., III; Melott, Adrian L.; Karachentsev, I. D.
1992-01-01
Results of an investigation of the topology of large-scale structure in two observed slices of the universe are presented. Both slices pass through the Coma cluster and their depths are 100 and 230/h Mpc. The present topology study shows that the largest void in the CfA slice is divided into two smaller voids by a statistically significant line of galaxies. The topology of toy models like the white noise and bubble models is shown to be inconsistent with that of the observed slices. A large N-body simulation was made of the biased cloud dark matter model and the slices are simulated by matching them in selection functions and boundary conditions. The genus curves for these simulated slices are spongelike and have a small shift in the direction of a meatball topology like those of observed slices.
Blacher, Jan; Baker, Bruce L.; Kaladjian, Araksia
2012-01-01
This study examined the extent to which child syndromes and observation context related to mothers’ parenting behaviors. Longitudinal observations were conducted of parenting behavior across ages 3, 4, and 5 years during structured and unstructured activities. The 183 participants included mothers of children with autism spectrum disorders, cerebral palsy, Down syndrome, undifferentiated developmental delay, or typical cognitive development. Negative parenting behaviors were higher in structured activities and higher in mothers of children in all developmentally delayed groups. Positive parenting was higher in unstructured activities and especially high for mothers of children with Down syndrome. Despite differences found through direct observation of parenting children in different diagnostic groups, they are not as strong as syndrome-group differences found through more commonly used self-report questionnaires assessing domains like parenting stress. PMID:22829243
Understanding Older Adults’ Usage of Community Green Spaces in Taipei, Taiwan
Pleson, Eryn; Nieuwendyk, Laura M.; Lee, Karen K.; Chaddah, Anuradha; Nykiforuk, Candace I. J.; Schopflocher, Donald
2014-01-01
As the world’s population ages, there is an increasing need for community environments to support physical activity and social connections for older adults. This exploratory study sought to better understand older adults’ usage and perceptions of community green spaces in Taipei, Taiwan, through direct observations of seven green spaces and nineteen structured interviews. Descriptive statistics from observations using the System for Observing Play and Recreation in Communities (SOPARC) confirm that older adults use Taipei’s parks extensively. Our analyses of interviews support the following recommendations for age-friendly active living initiatives for older adults: make green spaces accessible to older adults; organize a variety of structured activities that appeal to older adults particularly in the morning; equip green spaces for age-appropriate physical activity; and, promote the health advantages of green spaces to older adults. PMID:24473116
Germanene on single-layer ZnSe substrate: novel electronic and optical properties.
Ye, H Y; Hu, F F; Tang, H Y; Yang, L W; Chen, X P; Wang, L G; Zhang, G Q
2018-06-01
In this work, the structural, electronic and optical properties of germanene and ZnSe substrate nanocomposites have been investigated using first-principles calculations. We found that the large direct-gap ZnSe semiconductors and zero-gap germanene form a typical orbital hybridization heterostructure with a strong binding energy, which shows a moderate direct band gap of 0.503 eV in the most stable pattern. Furthermore, the heterostructure undergoes semiconductor-to-metal band gap transition when subjected to external out-of-plane electric field. We also found that applying external strain and compressing the interlayer distance are two simple ways of tuning the electronic structure. An unexpected indirect-direct band gap transition is also observed in the AAII pattern via adjusting the interlayer distance. Quite interestingly, the calculated results exhibit that the germanene/ZnSe heterobilayer structure has perfect optical absorption in the solar spectrum as well as the infrared and UV light zones, which is superior to that of the individual ZnSe substrate and germanene. The staggered interfacial gap and tunability of the energy band structure via interlayer distance and external electric field and strain thus make the germanene/ZnSe heterostructure a promising candidate for field effect transistors (FETs) and nanoelectronic applications.
Pore Size Control in Aluminium Foam by Standardizing Bubble Rise Velocity and Melt Viscosity
NASA Astrophysics Data System (ADS)
Avinash, G.; Harika, V.; Sandeepika, Ch; Gupta, N.
2018-03-01
In recent years, aluminium foams have found use in a wide range of applications. The properties of these foams, as good structural strength with light weight have made them as a promising structural material for aerospace industry. Foaming techniques (direct and indirect) are used to produce these foams. Direct foaming involves blowing of gas to create gas bubbles in the melt whereas indirect foaming technique uses blowing agents as metallic hydrides, which create hydrogen bubbles. Porosity and its distribution in foams directly affect its properties. This demands for more theoretical studies, to control such cellular structure and hence properties. In present work, we have studied the effect of gas bubble rise velocity and melt viscosity, on pore size and its distribution in aluminium foam. A 15 PPI aluminium foam, prepared using indirect foaming technique having porosity ~86 % was used for study. In order to obtain metal foam, the bubble must not escape from the melt and should get entrapped during solidification. Our calculations suggest that bubble rise velocity and melt viscosity are responsible for vertical displacement of bubble in the melt. It is observed that melt viscosity opposes bubble rise velocity and help the bubbles to stay in the melt, resulting in porous structure.
Uranus' and Neptune's Clouds as Revealed by UKIRT/UIST Observations
NASA Astrophysics Data System (ADS)
Irwin, Patrick G. J.; Teanby, N. A.; Davis, G. R.
2009-09-01
In 2006, 2007 and 2008 observations of the near-infrared spectrum of Uranus were made with the UIST instrument of the UK Infrared Telescope, covering the period of Uranus’ Northern Spring Equinox. A significant change in the visible appearance of Uranus occurred during this time with the southern polar zone at 45°S fading, while a corresponding zone at 45°N began to form. In addition the visibility of the equatorial zone increased. The observed spectra were fitted using the NEMESIS optimal estimation retrieval model to determine the variation in the latitudinal and vertical cloud structure during this time. Retrievals were conducted using both the methane absorption coefficients used in our previous analyses and also a newly available revised set of methane coefficients and significant differences were seen, which will be reported. During the Uranus observations in 2007, corresponding observations were also made of Neptune's near-infrared spectrum, albeit with substantially less spatial resolution. The spectra were nevertheless sufficient to retrieve the gross variation in Neptune's latitudinal-vertical cloud structure using both sets of methane absorption coefficients. The retrieved vertical-latitudinal cloud structure on Uranus and Neptune, observed with identical instrument setups, are directly compared and the similarities and differences will be presented and discussed.
Nishiyama, Hidetoshi; Suga, Mitsuo; Ogura, Toshihiko; Maruyama, Yuusuke; Koizumi, Mitsuru; Mio, Kazuhiro; Kitamura, Shinichi; Sato, Chikara
2010-03-01
Direct observation of subcellular structures and their characterization is essential for understanding their physiological functions. To observe them in open environment, we have developed an inverted scanning electron microscope with a detachable, open-culture dish, capable of 8 nm resolution, and combined with a fluorescence microscope quasi-simultaneously observing the same area from the top. For scanning electron microscopy from the bottom, a silicon nitride film window in the base of the dish maintains a vacuum between electron gun and open sample dish while allowing electrons to pass through. Electrons are backscattered from the sample and captured by a detector under the dish. Cells cultured on the open dish can be externally manipulated under optical microscopy, fixed, and observed using scanning electron microscopy. Once fine structures have been revealed by scanning electron microscopy, their component proteins may be identified by comparison with separately prepared fluorescence-labeled optical microscopic images of the candidate proteins, with their heavy-metal-labeled or stained ASEM images. Furthermore, cell nuclei in a tissue block stained with platinum-blue were successfully observed without thin-sectioning, which suggests the applicability of this inverted scanning electron microscope to cancer diagnosis. This microscope visualizes mesoscopic-scale structures, and is also applicable to non-bioscience fields including polymer chemistry. (c) 2010 Elsevier Inc. All rights reserved.
Structural and optical properties of AgIn5S8
NASA Astrophysics Data System (ADS)
Rincón, Carlos A. Durante; Durán, Larissa T.; Medina, Josefa Estévez; Castro, Jaime A.; León, Máximo; Fermín, Jose R.
2017-12-01
Compounds of the chalcogenide family Ag-In-VI (VI = S, Se, Te) are interesting materials due to their stoichiometric stability and potential application in nonlinear optics and solar cells. A polycrystalline ingot of AgIn5S8, an ordered vacancy semiconductor, was prepared by direct fusion of the stoichiometric mixture of the elements in an evacuated quartz ampoule. The presence of a single phase with cubic structure was confirmed by X-ray powder diffraction at room temperature. The lattice parameter, a, was calculated, giving 10.821750 Å. Samples in evacuated quartz ampoules were used to perform Differential Thermal Analysis measurements, showing congruent melting at 1110∘C. Transmittance and reflectivity measurements were used to calculate the absorption coefficient α. From the plot of (αhν)2 versus hν, two direct transitions are observed at 1.25 eV and 1.88 eV. While the higher energy direct transition has been observed by other authors, the direct nature of the lower energy transition was confirmed from the fitting of the plot of the reflectivity versus 1/hν between 0.53 eV-1 (1.89 eV) and 0.55 eV-1 (1.82 eV), obtaining a value of 1.29 eV. The real refractive index n and the high-frequency dielectric constant 𝜀∞ were also obtained from the fit of the reflectivity, resulting to be 2.68 and 7.2, respectively.
Structural Heterogeneity of Doubly-Charged Peptide b-Ions
NASA Astrophysics Data System (ADS)
Li, Xiaojuan; Huang, Yiqun; O'Connor, Peter B.; Lin, Cheng
2011-02-01
Performing collisionally activated dissociation (CAD) and electron capture dissociation (ECD) in tandem has shown great promise in providing comprehensive sequence information that was otherwise unobtainable by using either fragmentation method alone or in duet. However, the general applicability of this MS3 approach in peptide sequencing may be undermined by the formation of non-direct sequence ions, as sometimes observed under CAD, particularly when multiple stages of CAD are involved. In this study, varied-sized doubly-charged b-ions from three tachykinin peptides were investigated by ECD. Sequence scrambling was observed in ECD of all b-ions from neurokinin A (HKTDSFVGLM-NH2), suggesting the presence of N- and C-termini linked macro-cyclic conformers. On the contrary, none of the b-ions from eledoisin (pEPSKDAFIGLM-NH2) produced non-direct sequence ions under ECD, as it does not contain a free N-terminal amino group. ECD of several b-ions from Substance P (RPKPQQFFGLM-NH2) showed series of cm-Lys fragment ions which suggested that the macro-cyclic structure may also be formed by connecting the C-terminal carbonyl group and the ɛ-amino group of the lysine side chain. Theoretical investigation of selected Substance P b-ions revealed several low energy conformers, including both linear oxazolones and macro-ring structures, in corroboration with the experimental observation. This study showed that a b-ion may exist as a mixture of several forms, with their propensities influenced by its N-terminus, length, and certain side-chain groups. Further, the presence of several macro-cyclic structures may result in erroneous sequence assignment when the combined CAD and ECD methods are used in peptide sequencing.
Structural Heterogeneity of Doubly-Charged Peptide b-Ions
Li, Xiaojuan; Huang, Yiqun; O’Connor, Peter B.; Lin, Cheng
2011-01-01
Performing collisionally activated dissociation (CAD) and electron capture dissociation (ECD) in tandem has shown great promise in providing comprehensive sequence information that was otherwise unobtainable by using either fragmentation method alone or in duet. However, the general applicability of this MS3 approach in peptide sequencing may be undermined by the formation of non-direct sequence ions, as sometimes observed under CAD, particularly when multiple stages of CAD are involved. In this study, varied-sized doubly-charged b-ions from three tachykinin peptides were investigated by ECD. Sequence scrambling was observed in ECD of all b-ions from neurokinin A (HKTDSFVGLM-NH2), suggesting the presence of N- and C-termini linked macro-cyclic conformers. On the contrary, none of the b-ions from eledoisin (pEPSKDAFIGLM-NH2) produced non-direct sequence ions under ECD, as it does not contain a free N-terminal amino group. ECD of several b-ions from Substance P (RPKPQQFFGLM-NH2) showed series of cm-Lys fragment ions which suggested that the macro-cyclic structure may also be formed by connecting the C-terminal carbonyl group and the ε-amino group of the lysine side chain. Theoretical investigation of selected Substance P b-ions revealed several low energy conformers, including both linear oxazolones and macro-ring structures, in corroboration with the experimental observation. This study showed that a b-ion may exist as a mixture of several forms, with their propensities influenced by its N-terminus, length, and certain side-chain groups. Further, the presence of several macro-cyclic structures may result in erroneous sequence assignment when the combined CAD and ECD methods are used in peptide sequencing. PMID:21472584
Spontaneous formation and dynamics of half-skyrmions in a chiral liquid-crystal film
NASA Astrophysics Data System (ADS)
Nych, Andriy; Fukuda, Jun-Ichi; Ognysta, Uliana; Žumer, Slobodan; Muševič, Igor
2017-12-01
Skyrmions are coreless vortex-like excitations emerging in diverse condensed-matter systems, and real-time observation of their dynamics is still challenging. Here we report the first direct optical observation of the spontaneous formation of half-skyrmions. In a thin film of a chiral liquid crystal, depending on experimental conditions including film thickness, they form a hexagonal lattice whose lattice constant is a few hundred nanometres, or appear as isolated entities with topological defects compensating their charge. These half-skyrmions exhibit intriguing dynamical behaviour driven by thermal fluctuations. Numerical calculations of real-space images successfully corroborate the experimental observations despite the challenge because of the characteristic scale of the structures close to the optical resolution limit. A thin film of a chiral liquid crystal thus offers an intriguing platform that facilitates a direct investigation of the dynamics of topological excitations such as half-skyrmions and their manipulation with optical techniques.
Ion Demagnetization in the Magnetopause Current Layer Observed by MMS
NASA Technical Reports Server (NTRS)
Wang, Shan; Chen, Li-Jen; Hesse, Michael; Gershman, Daniel J.; Dorelli, John; Giles, Barbara; Torbert, Roy B.; Pollock, Craig J.; Lavraud, Benoit; Strangeway, Robert;
2016-01-01
We report ion velocity distribution functions (VDfs) observed by Magnetospheric Multiscale Mission (MMS) and present evidence for demagnetized ion Speiser motion during magnetopause reconnection. The demagnetization is observed in the vicinity of the X llne, as well as near the current sheet midlplane about tens of ion skin depths (d(sub 1)) away from the X line. Close to the X line before the outflow is built up, the VDFs are elongated, and the elongated part of VDFs rotates from the out-of-plane current direction toward the outflow directions downstream from the X line. Farther downstream, demagnetized ions exhibit a characteristic half-ring structure in the VDFs, as a result of the mixture of ions that have experienced different amounts of cyclotron turning around the magnetic field normal to the current sheet. Signatures of acceleration by electric fields are more pronounced in the VDFs near the X line than downstream.
Identification of a localized core mode in a helicon plasma
NASA Astrophysics Data System (ADS)
Green, Daniel A.; Chakraborty Thakur, Saikat; Tynan, George R.; Light, Adam D.
2017-10-01
We present imaging measurements of a newly observed mode in the core of the Controlled Shear Decorrelation Experiment - Upgrade (CSDX-U). CSDX-U is a well-characterized linear machine producing dense plasmas relevant to the tokamak edge (Te 3 eV, ne 1013 /cc). Typical fluctuations are dominated by electron drift waves, with evidence for Kelvin-Helmholtz vortices appearing near the plasma edge. A new mode has been observed using high-speed imaging that appears at high magnetic field strengths and is confined to the inner third of the plasma column. A cross-spectral phase technique allows direct visualization of dominant spatial structures as a function of frequency. Experimental dispersion curve estimates are constructed from imaging data alone, and allow direct comparison of theoretical dispersion relations to the observed mode. We present preliminary identification of the mode based on its dispersion curve, and compare the results with electrostatic probe measurements.
Ion demagnetization in the magnetopause current layer observed by MMS
NASA Astrophysics Data System (ADS)
Wang, Shan; Chen, Li-Jen; Hesse, Michael; Gershman, Daniel J.; Dorelli, John; Giles, Barbara; Torbert, Roy B.; Pollock, Craig J.; Lavraud, Benoit; Strangeway, Robert; Ergun, Robert E.; Burch, Jim; Avanov, Levon; Moore, Thomas E.; Saito, Yoshifumi
2016-05-01
We report ion velocity distribution functions (VDFs) observed by Magnetospheric Multiscale Mission (MMS) and present evidence for demagnetized ion Speiser motion during magnetopause reconnection. The demagnetization is observed in the vicinity of the X line, as well as near the current sheet midplane about tens of ion skin depths (di) away from the X line. Close to the X line before the outflow is built up, the VDFs are elongated, and the elongated part of VDFs rotates from the out-of-plane current direction toward the outflow directions downstream from the X line. Farther downstream, demagnetized ions exhibit a characteristic half-ring structure in the VDFs, as a result of the mixture of ions that have experienced different amounts of cyclotron turning around the magnetic field normal to the current sheet. Signatures of acceleration by electric fields are more pronounced in the VDFs near the X line than downstream.
Preflare magnetic and velocity fields
NASA Technical Reports Server (NTRS)
Hagyard, M. J.; Gaizauskas, V.; Chapman, G. A.; Deloach, A. C.; Gary, G. A.; Jones, H. P.; Karpen, J. T.; Martres, M.-J.; Porter, J. G.; Schmeider, B.
1986-01-01
A characterization is given of the preflare magnetic field, using theoretical models of force free fields together with observed field structure to determine the general morphology. Direct observational evidence for sheared magnetic fields is presented. The role of this magnetic shear in the flare process is considered within the context of a MHD model that describes the buildup of magnetic energy, and the concept of a critical value of shear is explored. The related subject of electric currents in the preflare state is discussed next, with emphasis on new insights provided by direct calculations of the vertical electric current density from vector magnetograph data and on the role of these currents in producing preflare brightenings. Results from investigations concerning velocity fields in flaring active regions, describing observations and analyses of preflare ejecta, sheared velocities, and vortical motions near flaring sites are given. This is followed by a critical review of prevalent concepts concerning the association of flux emergence with flares
Dynamic fluctuation of proteins watched in real time
Ormos, Pál
2008-01-01
The dynamic nature of protein function is a fundamental concept in the physics of proteins. Although the basic general ideas are well accepted most experimental evidence has an indirect nature. The detailed characterization of the dynamics is necessary for the understanding in detail. The dynamic fluctuations thought crucial for the function span an extremely broad time, starting from the picosecond regime. Recently, a few new experimental techniques emerged that permit the observation of dynamical phenomena directly. Notably, pulsed infrared (IR) spectroscopy has been applied with great success to observe structural changes with picosecond time resolution. Using two-dimensional-IR vibrational echo chemical exchange spectroscopy Ishikawa and co-workers [Ishikawa et al. (2008), Proc. Natl. Acad. Sci. U.S.A. 101, 14402–14407] managed to observe the transition between well defined conformational substrates of carbonmonoxy myoglobin directly. This is an important step in improving our insight into the details of protein function. PMID:19436491
ZnO-nanorods/graphene heterostructure: a direct electron transfer glucose biosensor
Zhao, Yu; Li, Wenbo; Pan, Lijia; Zhai, Dongyuan; Wang, Yu; Li, Lanlan; Cheng, Wen; Yin, Wei; Wang, Xinran; Xu, Jian-Bin; Shi, Yi
2016-01-01
ZnO-nanorods/graphene heterostructure was synthesized by hydrothermal growth of ZnO nanorods on chemically reduced graphene (CRG) film. The hybrid structure was demonstrated as a biosensor, where direct electron transfer between glucose oxidase (GOD) and electrode was observed. The charge transfer was attributed to the ZnO nanorod wiring between the redox center of GOD and electrode, and the ZnO/graphene heterostructure facilitated the transport of electrons on the hybride electrode. The glucose sensor based on the GOD-ZnO/CRG/Pt electrode had a high sensitivity of 17.64 μA mM−1, which is higher than most of the previously reported values for direct electron transfer based glucose biosensors. Moreover, this biosensor is linearly proportional to the concentration of glucose in the range of 0.2–1.6 mM. The study revealed that the band structure of electrode could affect the detection of direct electron transfer of GOD, which would be helpful for the design of the biosensor electrodes in the future. PMID:27572675
Correlation of anisotropy and directional conduction in β-Li 3PS 4 fast Li + conductor
Chen, Yan; Cai, Lu; Liu, Zengcai; ...
2015-07-06
Our letter reports the correlation of anisotropy and directional conduction in the fast Li + conductor β-Li 3PS 4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligiblemore » thermal expansion was observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li + conduction channels with incomplete Li occupancy and a flexible connection of LiS 4 and PS 4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li + conductor.« less
Structure et cinématique des peridotites feldspathiques du Cap Bougaroun (Algérie)
NASA Astrophysics Data System (ADS)
Misseri, M.
The Bougaroun Cape ultramafic body (Algeria) is located in the internal zone of the Maghrebine range. This body is similar to the ultramafic bodies of the Betico-Rifan range. Peridotites are associated with kinzigites. Observed structures and deformations correspond to a horizontal asthenospheric flow direction along a vertical plane. This could have been produced in the asthenosphere below a north-south rift or an incipient ocean spreading centre. The opening age is uncertain, hercynian or alpine.
Facile synthesis and photo electrochemical performance of SnSe thin films
NASA Astrophysics Data System (ADS)
Pusawale, S. N.; Jadhav, P. S.; Lokhande, C. D.
2018-05-01
Orthorhombic structured SnSe thin films are synthesized via SILAR (successive ionic layer adsorption and reaction) method on glass substrates. The structural properties of thin films are characterized by x-ray diffraction, scanning electron microscopy studies from which nanoparticles with an elongated shape and hydrophilic behavior are observed. UV -VIS absorption spectroscopy study showed the maximum absorption in the visible region with a direct band gap of 1.55 eV. The photo electrochemical study showed p-type electrical conductivity.
Suzuki, Naoki; Hattori, Asaki; Hayashibe, Mitsuhiro; Suzuki, Shigeyuki; Otake, Yoshito
2003-01-01
We have developed an imaging system for free and quantitative observation of human locomotion in a time-spatial domain by way of real time imaging. The system is equipped with 60 computer controlled video cameras to film human locomotion from all angles simultaneously. Images are installed into the main graphic workstation and translated into a 2D image matrix. Observation of the subject from optional directions is able to be performed by selecting the view point from the optimum image sequence in this image matrix. This system also possesses a function to reconstruct 4D models of the subject's moving human body by using 60 images taken from all directions at one particular time. And this system also has the capability to visualize inner structures such as the skeletal or muscular systems of the subject by compositing computer graphics reconstructed from the MRI data set. We are planning to apply this imaging system to clinical observation in the area of orthopedics, rehabilitation and sports science.
Photocrystallographic observation of halide-bridged intermediates in halogen photoeliminations.
Powers, David C; Anderson, Bryce L; Hwang, Seung Jun; Powers, Tamara M; Pérez, Lisa M; Hall, Michael B; Zheng, Shao-Liang; Chen, Yu-Sheng; Nocera, Daniel G
2014-10-29
Polynuclear transition metal complexes, which frequently constitute the active sites of both biological and chemical catalysts, provide access to unique chemical transformations that are derived from metal-metal cooperation. Reductive elimination via ligand-bridged binuclear intermediates from bimetallic cores is one mechanism by which metals may cooperate during catalysis. We have established families of Rh2 complexes that participate in HX-splitting photocatalysis in which metal-metal cooperation is credited with the ability to achieve multielectron photochemical reactions in preference to single-electron transformations. Nanosecond-resolved transient absorption spectroscopy, steady-state photocrystallography, and computational modeling have allowed direct observation and characterization of Cl-bridged intermediates (intramolecular analogues of classical ligand-bridged intermediates in binuclear eliminations) in halogen elimination reactions. On the basis of these observations, a new class of Rh2 complexes, supported by CO ligands, has been prepared, allowing for the isolation and independent characterization of the proposed halide-bridged intermediates. Direct observation of halide-bridged structures establishes binuclear reductive elimination as a viable mechanism for photogenerating energetic bonds.
Using thermal phase curves to probe the climate of potentially habitable planets
NASA Astrophysics Data System (ADS)
Kataria, Tiffany
2018-01-01
Thermal phase-curve observations probe the variation in emitted flux of a planet with phase, or longitude. When conducted spectroscopically, they allow us to probe the two-dimensional temperature structure in both longitude and altitude, which directly relate to the planet’s circulation and chemistry. In the case of small, potentially habitable exoplanets, spectroscopic phase-curve observations can provide us with direct evidence that the planet is capable of sustaining liquid water from measurements of its brightness temperature, and allow us to distinguish between a ‘airless’ body and one that has an appreciable atmosphere. In this talk I will summarize efforts to characterize exoplanets smaller than Neptune with phase-curve observations and emission spectroscopy using the Spitzer and Hubble Space Telescopes. I will then discuss how these ‘lessons learned’ can be applied to future efforts to characterize potentially habitable planets with phase-curve observations using JWST and future facilities such as the Origins Space Telescope (OST).
ORIGIN OF THE COMPLEX RADIO STRUCTURE IN BAL QSO 1045+352
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kunert-Bajraszewska, Magdalena; Gawronski, Marcin P.; Janiuk, Agnieszka
2010-08-01
We present new, more sensitive, high-resolution radio observations of a compact broad absorption line (BAL) quasar, 1045+352, made with the EVN+MERLIN at 5 GHz. These observations allowed us to trace the connection between the arcsecond structure and the radio core of the quasar. The radio morphology of 1045+352 is dominated by a knotty jet showing several bends. We discuss possible scenarios that could explain such a complex morphology: galaxy merger, accretion disk instability, precession of the jet, and jet-cloud interactions. It is possible that we are witnessing an ongoing jet precession in this source due to internal instabilities within themore » jet flow; however, a dense environment detected in the submillimeter band and an outflowing material suggested by the X-ray absorption could strongly interact with the jet. It is difficult to establish the orientation between the jet axis and the observer in 1045+352 because of the complex structure. Nevertheless, taking into account the most recent inner radio structure, we conclude that the radio jet is oriented close to the line of sight, which can mean that the opening angle of the accretion disk wind can be large in this source. We also suggest that there is no direct correlation between the jet-observer orientation and the possibility of observing BALs.« less
Daboer, J C; Lar, L A; Afolaranmi, T O; Bupwatda, P W; Dani, N
2013-12-01
After the initial gains in Tuberculosis case detection and cure rates, progress became stunted by persisting constraints and challenges in the implementation of the Directly Observed Treatment Short course strategy. This prompted the Stop Tuberculosis partners in 2006 to adopt innovative approaches including the Public-Private Mix, to improve access to and quality of care. This paper assesses the level of Public-Private Mix in Tuberculosis control in Jos, Plateau State. This was a facility-based, cross sectional study where data from all consenting private health care facilities owned by medically trained personnel and private medical practitioners in Jos North and Jos South Local Government Areas was collected using structured questionnaires. Eight (47.1%) of all 17 facilities assessed gave anti Tuberculosis drugs on clinical suspicion of Tuberculosis, 5(29.4%) required Acid Fast Bacillus result and 3(17.6%) referred elsewhere for the Tuberculosis management. Only 6 facilities (35.3%) were microscopy, treatment centres, or both. Ten (58.8%) of the facilities had the Directly Observed Treatment Short course guidelines, but these could be sighted in only 5 (29.4%), while six (35.3%) had Tuberculosis record and referral forms. In 13 (76.5%) of the facilities, no local government Tuberculosis and Leprosy supervisors had ever visited them. Only 30 (57.7%) medical practitioners had access to the Directly Observed Treatment Short course. Thirty two (61.5%) respondents treated Tuberculosis according to the Directly Observed Treatment Short course strategy, but 19 (36.5%) still used the conventional method. Only 22(42.3%) practitioners had ever received any training on the Directly Observed Treatment Short course strategy. The level of Public-Private Mix in Tuberculosis control in Jos is low.