Weld repair of directionally solidified articles

NASA Technical Reports Server (NTRS)

Smashey, Russell W. (Inventor); Snyder, John H. (Inventor); Borne, Bruce L. (Inventor)

2002-01-01

A directionally solidified nickel-base superalloy article has a defect therein extending parallel to the solidification direction. The article is repaired by removing any foreign matter present in the defect, and then heating the article to a repair temperature of from about 60 to about 98 percent of the solidus temperature of the base material in a chamber containing a protective gas that inhibits oxidation of the base material. The defect is filled with a filler metal while maintaining the article at the repair temperature. The filling is accomplished by providing a source of the filler metal of substantially the same composition as the base material of the directionally solidified article, and melting the filler metal into the defect progressively while moving the source of the filler metal relative to the article in a direction parallel to the solidification direction. Optionally, additional artificial heat extraction is accomplished in a heat-flow direction that is within about 45 degrees of the solidification direction, as the filler metal solidifies within the defect. The article may thereafter be heat treated.

Directional Solidification and Convection in Small Diameter Crucibles

NASA Technical Reports Server (NTRS)

Chen, J.; Sung, P. K.; Tewari, S. N.; Poirier, D. R.; DeGroh, H. C., III

2003-01-01

Pb-2.2 wt% Sb alloy was directionally solidified in 1, 2, 3 and 7 mm diameter crucibles. Pb-Sb alloy presents a solutally unstable case. Under plane-front conditions, the resulting macrosegregation along the solidified length indicates that convection persists even in the 1 mm diameter crucible. Al-2 wt% Cu alloy was directionally solidified because this alloy was expected to be stable with respect to convection. Nevertheless, the resulting macrosegregation pattern and the microstructure in solidified examples indicated the presence of convection. Simulations performed for both alloys show that convection persists for crucibles as small as 0.6 mm of diameter. For the solutally stable alloy, Al-2 wt% Cu, the simulations indicate that the convection arises from a lateral temperature gradient.

Simulating the Effect of Space Vehicle Environments on Directional Solidification of a Binary Alloy

NASA Technical Reports Server (NTRS)

Westra, D. G.; Heinrich, J. C.; Poirier, D. R.

2003-01-01

Space microgravity missions are designed to provide a microgravity environment for scientific experiments, but these missions cannot provide a perfect environment, due to vibrations caused by crew activity, on-board experiments, support systems (pumps, fans, etc.), periodic orbital maneuvers, and water dumps. Therefore, it is necessary to predict the impact of these vibrations on space experiments, prior to performing them. Simulations were conducted to study the effect of the vibrations on the directional solidification of a dendritic alloy. Finite element ca!cu!attie?ls were dme with a simd2titcr based on a continuum model of dendritic solidification, using the Fractional Step Method (FSM). The FSM splits the solution of the momentum equation into two steps: the viscous intermediate step, which does not enforce continuity; and the inviscid projection step, which calculates the pressure and enforces continuity. The FSM provides significant computational benefits for predicting flows in a directionally solidified alloy, compared to other methods presently employed, because of the efficiency gains in the uncoupled solution of velocity and pressure. finite differences, arises when the interdendritic liquid reaches the eutectic temperature and concentration. When a node reaches eutectic temperature, it is assumed that the solidification of the eutectic liquid continues at constant temperature until all the eutectic is solidified. With this approach, solidification is not achieved continuously across an element; rather, the element is not considered solidified until the eutectic isotherm overtakes the top nodes. For microgravity simulations, where the convection is driven by shrinkage, it introduces large variations in the fluid velocity. When the eutectic isotherm reaches a node, all the eutectic must be solidified in a short period, causing an abrupt increase in velocity. To overcome this difficulty, we employed a scheme to numerically predict a more accurate value for the rate of change of fraction of liquid as the liquid in an element solidifies. The new method enables us to contrast results of simulations in which the alloy is subjected to no gravity or a steady-state acceleration versus simulations when the alloy is subjected to vibration disturbances; therefore, the effect of vibration disturbances can be assessed more accurately. To assess the impact of these vibration-perturbations, transient accelerometer data from a space shuttle mission are used as inputs for the simulation model. These on-orbit acceleration data were obtained from the Microgravity Science Division at Glenn Research Center (GRC- MSD) and are applied to the buoyancy term of the momentum equation in a simulation of a Pb-5.8 wt. % Sb alloy that solidifies in a thermal gradient of 4000 K/m and a translation velocity of 3 p d s . Figure 2 shows the vertical velocity of a node that begins in the all-liquid region and subsequently solidifies; the vibrations are applied at 5000 seconds in this simulation. An important difficulty, common to all solidification models based on finite elements or 2 The magnitudes of the velocity oscillations that are vibration-induced are very small and acceptable. The biggest concern is whether the concentration of the liquid near the dendrite tips is distorted because of the vibration-induced perturbations. Results for this case show no concentration oscillations present in the all-liquid region.

Organic alloy systems suitable for the investigation of regular binary and ternary eutectic growth

NASA Astrophysics Data System (ADS)

Sturz, L.; Witusiewicz, V. T.; Hecht, U.; Rex, S.

2004-09-01

Transparent organic alloys showing a plastic crystal phase were investigated experimentally using differential scanning calorimetry and directional solidification with respect to find a suitable model system for regular ternary eutectic growth. The temperature, enthalpy and entropy of phase transitions have been determined for a number of pure substances. A distinction of substances with and without plastic crystal phases was made from their entropy of melting. Binary phase diagrams were determined for selected plastic crystal alloys with the aim to identify eutectic reactions. Examples for lamellar and rod-like eutectic solidification microstructures in binary systems are given. The system (D)Camphor-Neopentylglycol-Succinonitrile is identified as a system that exhibits, among others, univariant and a nonvariant eutectic reaction. The ternary eutectic alloy close to the nonvariant eutectic composition solidifies with a partially faceted solid-liquid interface. However, by adding a small amount of Amino-Methyl-Propanediol (AMPD), the temperature of the nonvariant eutectic reaction and of the solid state transformation from plastic to crystalline state are shifted such, that regular eutectic growth with three distinct nonfaceted phases is observed in univariant eutectic reaction for the first time. The ternary phase diagram and examples for eutectic microstructures in the ternary and the quaternary eutectic alloy are given.

Prediction of as-cast grain size of inoculated aluminum alloys melt solidified under non-isothermal conditions

NASA Astrophysics Data System (ADS)

Du, Qiang; Li, Yanjun

2015-06-01

In this paper, a multi-scale as-cast grain size prediction model is proposed to predict as-cast grain size of inoculated aluminum alloys melt solidified under non-isothermal condition, i.e., the existence of temperature gradient. Given melt composition, inoculation and heat extraction boundary conditions, the model is able to predict maximum nucleation undercooling, cooling curve, primary phase solidification path and final as-cast grain size of binary alloys. The proposed model has been applied to two Al-Mg alloys, and comparison with laboratory and industrial solidification experimental results have been carried out. The preliminary conclusion is that the proposed model is a promising suitable microscopic model used within the multi-scale casting simulation modelling framework.

Primary Dendrite Arm Spacings in Al-7Si Alloy Directionally Solidified on the International Space Station

NASA Technical Reports Server (NTRS)

Angart, Samuel; Lauer, Mark; Poirier, David; Tewari, Surendra; Rajamure, Ravi; Grugel, Richard

2015-01-01

Samples from directionally solidified Al- 7 wt. % Si have been analyzed for primary dendrite arm spacing (lambda) and radial macrosegregation. The alloy was directionally solidified (DS) aboard the ISS to determine the effect of mitigating convection on lambda and macrosegregation. Samples from terrestrial DS-experiments thermal histories are discussed for comparison. In some experiments, lambda was measured in microstructures that developed during the transition from one speed to another. To represent DS in the presence of no convection, the Hunt-Lu model was used to represent diffusion controlled growth under steady-state conditions. By sectioning cross-sections throughout the entire length of a solidified sample, lambda was measured and calculated using the model. During steady-state, there was reasonable agreement between the measured and calculated lambda's in the space-grown samples. In terrestrial samples, the differences between measured and calculated lambda's indicated that the dendritic growth was influenced by convection.

Evaluating Primary Dendrite Trunk Diameters in Directionally Solidified Al-Si Alloys

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Tewari, S. N.; Poirier, D. R.

2014-01-01

The primary dendrite trunk diameters of Al-Si alloys that were directionally solidified over a range of processing conditions have been measured. These data are analyzed with a model based primarily on an assessment of secondary dendrite arm dissolution in the mushy zone. Good fit with the experimental data is seen and it is suggested that the primary dendrite trunk diameter is a useful metric that correlates well with the actual solidification processing parameters. These results are placed in context with the limited results from the aluminium - 7 wt. % silicon samples directionally solidified aboard the International Space Station as part of the MICAST project.

Microstructural changes caused by thermal treatment and their effects on mechanical properties of a gamma/gamma prime - delta eutectic alloy

NASA Technical Reports Server (NTRS)

Tewari, S. N.; Dreshfield, R. L.

1976-01-01

Microstructural changes due to thermal treatments of a directionally solidified gamma/gamma'-delta eutectic alloy were investigated. Aging treatments of 8 to 48 hours and ranging from 750 to 1120 C were given to the alloy in both its as directionally solidified condition and after gamma' solutioning. Aging resulted in gamma' coarsening gamma precipitates in delta, and delta and gamma'' precipitates in delta. The tensile strength was increased about 12 percent at temperatures up to 900 C by a heat treatment. Times to rupture were essentially the same or greater than for as directionally solidified material. Tensile and rupture ductility in the growth direction of the alloy were reduced by the heat treatment.

Shear rupture of a directionally solidified eutectic gamma/gamma prime - alpha (Mo) alloy

NASA Technical Reports Server (NTRS)

Harf, F. H.

1978-01-01

Directionally solidified Mo alloys are evaluated to determine the shear rupture strength and to possibly improve it by microstructural and heat treatment variations. Bars of the alloy containing nominally 5.7% Al and 33.5% Mo by weight with balance Ni were directionally solidified at rates between 10 and 100 mm per hour in furnaces with thermal gradients at the liquid-solid interface of 250 or 100 C per cm. A limited number of longitudinal shear rupture tests were conducted at 760 C and 207 MPa in the as - solidified and in several heat treated conditions. It is shown that shear rupture failures are partly transgranular and that resistance to failure is prompted by good fiber alignment and a matrix structure consisting mainly of gamma prime. Well aligned as - solidified specimens sustained the shear stress for an average of 81 hours. A simulated coating heat treatment appeared to increase the transformation of gamma to gamma prime and raised the average shear life of aligned specimens to 111 hours. However, heat treatments at 1245 C and especially at 1190 C appeared to be detrimental by causing partial solutioning of the gamma prime, and reducing lives to 47 and 10 hours, respectively.

Directional solidification of Pb-Sn eutectic with vibration

NASA Technical Reports Server (NTRS)

Caram, Rubens; Banan, Mohsen; Wilcox, William R.

1991-01-01

Pb-Sn eutectic alloy was directionally solidified at 1.4 to 3.2 cm/hr with forced convection induced by axial vibration of the growth ampoule with a frequency of 10 to 40 Hz and an amplitude of 0.5 to 1.0 mm. To determine the exact growth rate, an interface demarcation technique was applied. The lamellar spacing was increased 10 to 40 percent in ingots solidified with vibration compared to those solidified without vibration. The average intensity of convection in the melt under axial vibration of the ampoule was estimated by comparing the experimental results with a theoretical model.

A Study of Production of Miscibility Gap Alloys with Controlled Structures

NASA Technical Reports Server (NTRS)

Parr, R. A.; Johnston, M. H.; Burka, J. A.; Davis, J. H.; Lee, J. A.

1983-01-01

Composite materials were directionally solidified using a new technique to align the constituents longitudinally along the length of the specimen. In some instances a tin coating was applied and diffused into the sample to form a high transition temperature superconducting phase. The superconducting properties were measured and compared with the properties obtained for powder composites and re-directionally solidified powder compacts. The samples which were compacted and redirectionally solidified showed the highest transition temperature and wildest transition range. This indicates that both steps, powder compaction and resolidification, determine the final superconducting properties of the material.

Slag processing system for direct coal-fired gas turbines

DOEpatents

Pillsbury, Paul W.

1990-01-01

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

Instabilities in rapid directional solidification under weak flow

NASA Astrophysics Data System (ADS)

Kowal, Katarzyna N.; Davis, Stephen H.; Voorhees, Peter W.

2017-12-01

We examine a rapidly solidifying binary alloy under directional solidification with nonequilibrium interfacial thermodynamics viz. the segregation coefficient and the liquidus slope are speed dependent and attachment-kinetic effects are present. Both of these effects alone give rise to (steady) cellular instabilities, mode S , and a pulsatile instability, mode P . We examine how weak imposed boundary-layer flow of magnitude |V | affects these instabilities. For small |V | , mode S becomes a traveling and the flow stabilizes (destabilizes) the interface for small (large) surface energies. For small |V | , mode P has a critical wave number that shifts from zero to nonzero giving spatial structure. The flow promotes this instability and the frequencies of the complex conjugate pairs each increase (decrease) with flow for large (small) wave numbers. These results are obtained by regular perturbation theory in powers of V far from the point where the neutral curves cross, but requires a modified expansion in powers of V1 /3 near the crossing. A uniform composite expansion is then obtained valid for all small |V | .

Directional solidification of Pb-Sn eutectics with vibration

NASA Technical Reports Server (NTRS)

Caram, Rubens; Banan, Mohsen; Wilcox, William R.

1991-01-01

Pb-Sn eutectic alloy was directionally solidified at 1.4 to 3.2 cm/hr with forced convection induced by axial vibration of the growth ampoule with a frequency of 10 to 40 Hz and an amplitude of 0.5 to 1.0 mm. To determine the exact growth rate, an interface demarcation technique was applied. The lamellar spacing was increased 10 to 40 percent in ingots solidified with vibration compared to those solidified without vibration. The number of grain boundaries was increased by vibration. The average intensity of convection in the melt under axial vibration of the ampoule was estimated by comparing the experimental results with a theoretical model.

Thermal fatigue resistance of NASA WAZ-20 alloy with three commercial coatings

NASA Technical Reports Server (NTRS)

Bizon, P. T.; Oldrieve, R. E.

1975-01-01

Screening tests using three commercial coatings (Jocoat, HI-15, and RT-1A) on the nickel-base alloy NASA WAZ-20 were performed by cyclic exposure in a Mach 1 burner facility. These tests showed Jocoated WAZ-20 to have the best cracking resistance. The thermal fatigue resistance of Jocoated WAZ-20 in both the random polycrystalline and directionally solidified polycrystalline forms relative to that of other superalloys was then evaluated in a fluidized-bed facility. This investigation showed that Jocoated random polycrystalline WAZ-20 ranked approximately in midrange in thermal fatigue life. The thermal fatigue life of directionally solidified Jocoated WAZ-20 was shorter than that of other directionally solidified alloys but still longer than that of all alloys in the random polycrystalline form.

Microstructure of directionally solidified Ti-Fe eutectic alloy with low interstitial and high mechanical strength

NASA Astrophysics Data System (ADS)

Contieri, R. J.; Lopes, E. S. N.; Taquire de La Cruz, M.; Costa, A. M.; Afonso, C. R. M.; Caram, R.

2011-10-01

The performance of Ti alloys can be considerably enhanced by combining Ti and other elements, causing an eutectic transformation and thereby producing composites in situ from the liquid phase. This paper reports on the processing and characterization of a directionally solidified Ti-Fe eutectic alloy. Directional solidification at different growth rates was carried out in a setup that employs a water-cooled copper crucible combined with a voltaic electric arc moving through the sample. The results obtained show that a regular fiber-like eutectic structure was produced and the interphase spacing was found to be a function of the growth rate. Mechanical properties were measured using compression, microindentation and nanoindentation tests to determine the Vickers hardness, compressive strength and elastic modulus. Directionally solidified eutectic samples presented high values of compressive strength in the range of 1844-3000 MPa and ductility between 21.6 and 25.2%.

Thermal effects in rapid directional solidification - Linear theory

NASA Technical Reports Server (NTRS)

Huntley, D. A.; Davis, S. H.

1993-01-01

We study the morphological instability of the planar solid/liquid interface for a unidirectionally-solidified dilute binary mixture. We use a model developed by Boettinger et al. (1985, 1986), Aziz (1982), and Jackson et al. (1980), which allows for nonequilibrium effects on the interface through velocity-dependent segregation and attachment kinetics. Two types of instabilities are found in the linear stability analysis: (1) a cellular instability, and (2) an oscillatory instability driven by disequilibrium effects. Merchant and Davis (1990) characterized these instabilities subject to the frozen-temperature approximation (FTA). The present work relaxes the FTA by including the effects of latent heat and the full temperature distribution. Thermal effects slightly postpone the onset of the cellular instability but dramatically postpone the onset of the oscillatory instability; however, the absolute-stability conditions, at which at high speed the cellular and oscillatory instabilities are suppressed, remain unchanged from the FTA.

Vertical solidification of dendritic binary alloys

NASA Technical Reports Server (NTRS)

Heinrich, J. C.; Felicelli, S.; Poirier, D. R.

1991-01-01

Three numerical techniques are employed to analyze the influence of thermosolutal convection on defect formation in directionally solidified (DS) alloys. The finite-element models are based on the Boussinesq approximation and include the plane-front model and two plane-front models incorporating special dendritic regions. In the second model the dendritic region has a time-independent volume fraction of liquid, and in the last model the dendritic region evolves as local conditions dictate. The finite-element models permit the description of nonlinear thermosolutal convection by treating the dendritic regions as porous media with variable porosities. The models are applied to lead-tin alloys including DS alloys, and severe segregation phenomena such as freckles and channels are found to develop in the DS alloys. The present calculations and the permeability functions selected are shown to predict behavior in the dendritic regions that qualitatively matches that observed experimentally.

Modeling Macrosegregation in Directionally Solidified Aluminum Alloys under Gravitational and Microgravitational Conditions.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lauer, Mark A.; Poirier, David R.; Erdmann, Robert G.

2014-09-01

This report covers the modeling of seven directionally solidified samples, five under normal gravitational conditions and two in microgravity. A model is presented to predict macrosegregation during the melting phases of samples solidified under microgravitational conditions. The results of this model are compared against two samples processed in microgravity and good agreement is found. A second model is presented that captures thermosolutal convection during directional solidification. Results for this model are compared across several experiments and quantitative comparisons are made between the model and the experimentally obtained radial macrosegregation profiles with good agreement being found. Changes in cross section weremore » present in some samples and micrographs of these are qualitatively compared with the results of the simulations. It is found that macrosegregation patterns can be affected by changing the mold material.« less

Directionally solidified eutectic gamma plus beta nickel-base superalloys

NASA Technical Reports Server (NTRS)

Jackson, M. R. (Inventor)

1977-01-01

A directionally solidified multivariant eutectic gamma + beta nickel-base superalloy casting having improved high temperature strength and oxidation resistance properties is provided. This comprises a two phase eutectic structure containing, on a weight percent basis, 5.0-15.0 tungsten, 8.5-14.5 aluminum, 0.0-35.0 cobalt and the balance being nickel. Embedded within the gamma phase nickel-base matrix are aligned eutectic beta phase (primarily (NiCo)Al reinforcing lamellae.

Alloy and structural optimization of a directionally solidified lamellar eutectic alloy

NASA Technical Reports Server (NTRS)

Sheffler, K. D.

1976-01-01

Mechanical property characterization tests of a directionally solidified Ni-20 percent Cb-2.5 percent Al-6 percent Cr cellular eutectic turbine blade alloy demonstrated excellent long time creep stability and indicated intermediate temperature transverse tensile ductility and shear strength to be somewhat low for turbine blade applications. Alloy and structural optimization significantly improves these off-axis properties with no loss of longitudinal creep strength or stability. The optimized alloy-structure combination is a carbon modified Ni-20.1 percent Cb-2.5 percent Al-6.0 percent Cr-0.06 percent C composition processed under conditions producing plane front solidification and a fully-lamellar microstructure. With current processing technology, this alloy exhibits a creep-rupture advantage of 39 C over the best available nickel base superalloy, directionally solidified MAR M200+ Hf. While improved by about 20 percent, shear strength of the optimized alloy remains well below typical superalloy values.

High Temperature Mechanical Behavior of MgAl2O4-YAG Eutectic Ceramic In Situ Composites by Float Zone Method

NASA Astrophysics Data System (ADS)

Abalı, Serkan

2017-09-01

The directionally solidified eutectic MgAl2O4-Y3Al5O12 crystal was prepared at a pressure of 0.4 MPa of ambient nitrogen gas by the high frequency induction heated floating zone furnace. In order to determine the high temperature characteristics, directionally solidified MgAl2O4-Y3Al5O12 eutectic phase has been analyzed with creep test, tensile strength, young modulus and fracture toughness at the various temperatures and the microstructural variations have been studied according to the analysis results. It has been seen that directionally solidified with zone melting MgAl2O4-YAG eutectic ceramic which has given the value of 168 MPa below 10-6/s strain rate at 1,700 °C temperature has revealed minimum stress.

Characterization of directionally solidified lead chloride

NASA Technical Reports Server (NTRS)

Singh, Narsingh Bahadur; Duval, W. M. B.; Rosenthal, B. N.

1988-01-01

A directionally solidified PbCl2 material was prepared and analyzed and subsequently used to grow single crystals. It was found that silicon, halogens, sulfur, magnesium, and phosphorus were the hardest impurities to remove by the single-pass directional freezing. Single crystals grown from the purified material displayed good scattering beam quality and showed no absorption peaks between 0.30 to 20 microns. Direct photographic observations of the solid-liquid interface at several G/V (denoting the temperature gradient and the translation velocity, respectively) ratio values showed that, as the G/V ratio decreased, the interface varied from a smooth convex surface to dendritic.

Primary Dendrite Array Morphology: Observations from Ground-based and Space Station Processed Samples

NASA Technical Reports Server (NTRS)

Tewari, Surendra; Rajamure, Ravi; Grugel, Richard; Erdmann, Robert; Poirier, David

2012-01-01

Influence of natural convection on primary dendrite array morphology during directional solidification is being investigated under a collaborative European Space Agency-NASA joint research program, "Microstructure Formation in Castings of Technical Alloys under Diffusive and Magnetically Controlled Convective Conditions (MICAST)". Two Aluminum-7 wt pct Silicon alloy samples, MICAST6 and MICAST7, were directionally solidified in microgravity on the International Space Station. Terrestrially grown dendritic monocrystal cylindrical samples were remelted and directionally solidified at 18 K/cm (MICAST6) and 28 K/cm (MICAST7). Directional solidification involved a growth speed step increase (MICAST6-from 5 to 50 micron/s) and a speed decrease (MICAST7-from 20 to 10 micron/s). Distribution and morphology of primary dendrites is currently being characterized in these samples, and also in samples solidified on earth under nominally similar thermal gradients and growth speeds. Primary dendrite spacing and trunk diameter measurements from this investigation will be presented.

Primary Dendrite Array: Observations from Ground-Based and Space Station Processed Samples

NASA Technical Reports Server (NTRS)

Tewari, Surendra N.; Grugel, Richard N.; Erdman, Robert G.; Poirier, David R.

2012-01-01

Influence of natural convection on primary dendrite array morphology during directional solidification is being investigated under a collaborative European Space Agency-NASA joint research program, Microstructure Formation in Castings of Technical Alloys under Diffusive and Magnetically Controlled Convective Conditions (MICAST). Two Aluminum-7 wt pct Silicon alloy samples, MICAST6 and MICAST7, were directionally solidified in microgravity on the International Space Station. Terrestrially grown dendritic monocrystal cylindrical samples were remelted and directionally solidified at 18 K per centimeter (MICAST6) and 28 K per centimeter (MICAST7). Directional solidification involved a growth speed step increase (MICAST6-from 5 to 50 millimeters per second) and a speed decrease (MICAST7-from 20 to 10 millimeters per second). Distribution and morphology of primary dendrites is currently being characterized in these samples, and also in samples solidified on earth under nominally similar thermal gradients and growth speeds. Primary dendrite spacing and trunk diameter measurements from this investigation will be presented.

The influence of interfacial energies and gravitational levels on the directionally solidified structures in hypermonotectic alloys

NASA Technical Reports Server (NTRS)

Andrews, J. B.; Curreri, P. A.; Sandlin, A. C.

1988-01-01

Various Cu-Pb-Al alloys were directionally solidified under 1-g conditions and alternating high-g/low-g conditions (achieved using NSAS's KC-135 aircraft) as a means of studying the influence of interfacial energies and gravitational levels on the resulting microstructures. Directional solidification of low Al content alloys was found to result in samples with coarser more irregular microstructures than in alloys with high Al contents under all the gravity conditions considered. Structures are correlated with interfacial energies, growth rates, and gravitational levels.

Numerical Simulations of Crystal Growth of an Alloy Under Microgravity Conditions

NASA Technical Reports Server (NTRS)

Simpson, James E.; deGroh, Henry C., III; Garimella, Suresh V.; Abbaschian, Reza

1999-01-01

The directional solidification of a dilute binary alloy (Bi-1.0 at.%Sn)is investigated. Results are obtained at a gravity level of I pg. Computations are performed in two dimensions with a fixed, non-uniform grid. The simulation involves a solution of the species concentration equation (modified to account for solute rejection at the interface) and energy equation (modified to account for phase-change) for both the solid and liquid phases, in addition to the constitutive equations for describing convective flow in the melt. The effects of conductive heat transfer in the ampoule and in a capillary tube in the sample are included. To gauge the effects of including this growth capillary tube in the apparatus, simulations both with and without the capillary tube are presented and compared. Fully transient simulations have been performed; no simplifying steady-state approximations are used, however, the influence of solute on the melting temperature at the interface is not included. Both thermal and solutal convective cells are seen to form. Convective velocities are significantly damped inside the capillary, causing less segregation due to convection. As solidification proceeds beyond the capillary tube, longitudinal segregation arises as a result of the change in cross-sectional area of solidifying material. The magnitudes of the velocities in this cell increase significantly once the solid/liquid front passes beyond the end of the capillary tube; this causes a corresponding increase in the level of radial solute segregation in the solidified material.

Large low-field magnetocaloric effect in directionally solidified Ni55Mn18+xGa27-x (x = 0, 1, 2) alloys

NASA Astrophysics Data System (ADS)

Li, Zhenzhuang; Li, Zongbin; Yang, Bo; Yang, Yiqiao; Zhang, Yudong; Esling, Claude; Zhao, Xiang; Zuo, Liang

2018-01-01

The magnetostructural transformation and magnetocaloric effect of directionally solidified polycrystalline Ni55Mn18+xGa27-x (x = 0, 1, 2) alloys were studied. It is shown the directionally solidified alloys form coarse columnar-shaped grains with strong 〈0 0 1〉A (the subscript A refers to austenite) preferred orientation along the solidification direction. Through Mn substitution for Ga, a coupled magnetostructural transformation was realized in Ni55Mn19Ga26 and Ni55Mn20Ga25 alloys. Large adiabatic temperature variation (ΔTad) of 1.47 K and 1.57 K under the low field change of 1.5 T were achieved in these two alloys, respectively. Such ΔTad values are obviously higher than that obtained from a single martensitic transformation and magnetic transition. The present results demonstrate that proper composition tuning to achieve magnetostructural transformation as well as increasing the grain size and preferential orientation degree through directional solidification could be an economical processing route to optimize magnetocaloric properties in polycrystalline Ni-Mn-Ga based alloys.

Particle Engulfment and Pushing by Solidifying Interfaces LMS Mission Results

NASA Technical Reports Server (NTRS)

Juretzko, Frank R.; Catalina, Adrian V.; Stefanescu, Doru M.; Dhindaw, Brij K.; Sen, Subhayu; Curreri, Peter A.; Mullins, Jennifer

1998-01-01

Results of the directional solidification experiments on Particle Engulfment and Pushing by Solidifying Interfaces (PEP) conducted on the space shuttle Columbia are reported. The experiment was manifested as part of The Life and Microgravity Science Mission. Two pure aluminum (99.999%) 9 mm cylindrical rods, loaded with about 2 vol.% 500 microns diameter zirconia particles were melted and directionally solidified in the microgravity (micro-g) environment of the shuttle. The particles were non-reactive with the matrices within the temperature range of interest. The experiments were conducted such as to insure a planar solid/liquid interface during solidification. Two different cartridge - crucible - sample designs were used: a spring-piston and expansion void. Both resulted in sound samples. Samples were evaluated post-flight for soundness by X-ray computer tomography (XCT).

Constitutive Modeling of Superalloy Single Crystals and Directionally Solidified Materials

NASA Technical Reports Server (NTRS)

Walker, K. P.; Jordan, E. H.

1985-01-01

A unified viscoplastic constitutive relation based on crystallographic slip theory was developed for the deformation analysis of nickel base face centered cubic superalloy single crystals at elevated temperature. The single crystal theory is embedded in a self consistent method to derive a constitutive relation for a directionally solidified material comprised of a polycrystalline aggregate of columnar cylindrical grains. One of the crystallographic axes of the cylindrical crystals points in the columnar direction while the remaining crystallographic axes are oriented at random in the basal plane perpendicular to the columnar direction. These constitutive formulations are coded in FORTRAN for use in nonlinear finite element and boundary element programs.

Pattern formation in triboelectrically charged binary packings

NASA Astrophysics Data System (ADS)

Schella, Andre; Vincent, Thomas; Herminghaus, Stephan; Schröter, Matthias

2015-11-01

Electrostatic self-assembly is an interesting route to aim at creating well-defined microstructures. In this spirit, we study the process of self-assembling for vertically shaken granular materials. Our system consists from 1 to 400 plastic beads of 3mm size made from Teflon and Nylon in 2D and 3D geometries. We find self-organization in four, five and sixfold order which is due to charging of the system via triboelectric effects between the grains. We observe that the binary system solidifies on a time scale of a few minutes. Image processing is used to extract the structural and dynamical properties of the assemblies. The mixture ratio is tuned from 1:5 to 5:1 and the humidity level is varied between 10% and 90% leading to various transitions between the morphologies.

Spatial distribution of structural defects in Cz-seeded directionally solidified silicon ingots: An etch pit study

NASA Astrophysics Data System (ADS)

Lantreibecq, A.; Legros, M.; Plassat, N.; Monchoux, J. P.; Pihan, E.

2018-02-01

The PV properties of wafers processed from Cz-seeded directionally solidified silicon ingots suffer from variable structural defects. In this study, we draw an overview on the types of structural defects encountered in the specific case of full 〈1 0 0〉 oriented growth. We found micro twins, background dislocations, and subgrains boundaries. We discuss the possible links between thermomechanical stresses and growth processes with spatial evolution of both background dislocation densities and subgrain boundaries length.

A Directionally Solidified Iron-chromium-aluminum-tantalum Carbide Eutectic Alloy

NASA Technical Reports Server (NTRS)

Harf, F. H.

1977-01-01

A eutectic alloy, Fe-13.6CR-3.7Al+9TaC, was directionally solidified in a high gradient furnace, producing a microstructure of alined TaC fibers in an oxidation resistant alpha-iron matrix. Tensile and stress rupture properties, thermal cycling resistance, and microstructures were evaluated. The alloy displays at 1000 C an ultimate tensile strength of 58 MPa and a 100-hour rupture life at a stress of 21 MPa. Thermal cycling to 1100 C induces faceting in the TaC fibers.

Large magnetoresistance in a directionally solidified Ni44.5Co5.1Mn37.1In13.3 magnetic shape memory alloy

NASA Astrophysics Data System (ADS)

Li, Zongbin; Hu, Wei; Chen, Fenghua; Zhang, Mingang; Li, Zhenzhuang; Yang, Bo; Zhao, Xiang; Zuo, Liang

2018-04-01

Polycrystalline Ni44.5Co5.1Mn37.1In13.3 alloy with coarse columnar-shaped grains and 〈0 0 1〉A preferred orientation was prepared by directional solidification. Due to the strong magnetostructural coupling, inverse martensitic transformation can be induced by the magnetic field, resulting in large negative magnetoresistance up to -58% under the field of 3 T. Such significant field controlled functional behaviors should be attributed to the coarse grains and strong preferred orientation in the directionally solidified alloy.

Effect of tensile mean stress on fatigue behavior of single-crystal and directionally solidified superalloys

NASA Technical Reports Server (NTRS)

Kalluri, Sreeramesh; Mcgaw, Michael A.

1990-01-01

Two nickel base superalloys, single crystal PWA 1480 and directionally solidified MAR-M 246 + Hf, were studied in view of the potential usage of the former and usage of the latter as blade materials for the turbomachinery of the space shuttle main engine. The baseline zero mean stress (ZMS) fatigue life (FL) behavior of these superalloys was established, and then the effect of tensile mean stress (TMS) on their FL behavior was characterized. At room temperature these superalloys have lower ductilities and higher strengths than most polycrystalline engineering alloys. The cycle stress-strain response was thus nominally elastic in most of the fatigue tests. Therefore, a stress range based FL prediction approach was used to characterize both the ZMS and TMS fatigue data. In the past, several researchers have developed methods to account for the detrimental effect of tensile mean stress on the FL for polycrystalline engineering alloys. However, the applicability of these methods to single crystal and directionally solidified superalloys has not been established. In this study, these methods were applied to characterize the TMS fatigue data of single crystal PWA 1480 and directionally solidified MAR-M 246 + Hf and were found to be unsatisfactory. Therefore, a method of accounting for the TMS effect on FL, that is based on a technique proposed by Heidmann and Manson was developed to characterize the TMS fatigue data of these superalloys. Details of this method and its relationship to the conventionally used mean stress methods in FL prediction are discussed.

Thermosolutal convection during dendritic solidification

NASA Technical Reports Server (NTRS)

Heinrich, J. C.; Nandapurkar, P.; Poirier, D. R.; Felicelli, S.

1989-01-01

This paper presents a mathematical model for directional solidification of a binary alloy including a dendritic region underlying an all-liquid region. It is assumed initially that there exists a nonconvecting state with planar isotherms and isoconcentrates solidifying at a constant velocity. The stability of this system has been analyzed and nonlinear calculations are performed that show the effect of convection in the solidification process when the system is unstable. Results of calculations for various cases defined by the initial temperature gradient at the dendrite tips and varying strength of the gravitational field are presented for systems involving lead-tin alloys. The results show that the systems are stable for a gravitational constant of 0.0001 g(0) and that convection can be suppressed by appropriate choice of the container's size for higher values of the gravitational constant. It is also concluded that for the lead-tin systems considered, convection in the mushy zone is not significant below the upper 20 percent of the dendritic zone, if al all.

The effect of thermal cycling on the structure and properties of a Co, Cr, Ni-TaC directionally solidified eutectic composite

NASA Technical Reports Server (NTRS)

Dunlevey, F. M.; Wallace, J. F.

1973-01-01

The effect of thermal cycling on the structure and properties of a cobalt, chromium, nickel, tantalum carbide directionally solidified eutectic composite is reported. It was determined that the stress rupture properties of the alloy were decreased by the thermal cycling. The loss in stress rupture properties varied with the number of cycles with the loss in properties after about 200 cycles being relatively high. The formation of serrations and the resulting changes in the mechanical properties of the material are discussed.

A quasi two-dimensional benchmark experiment for the solidification of a tin lead binary alloy

NASA Astrophysics Data System (ADS)

Wang, Xiao Dong; Petitpas, Patrick; Garnier, Christian; Paulin, Jean-Pierre; Fautrelle, Yves

2007-05-01

A horizontal solidification benchmark experiment with pure tin and a binary alloy of Sn-10 wt.%Pb is proposed. The experiment consists in solidifying a rectangular sample using two lateral heat exchangers which allow the application a controlled horizontal temperature difference. An array of fifty thermocouples placed on the lateral wall permits the determination of the instantaneous temperature distribution. The cases with the temperature gradient G=0, and the cooling rates equal to 0.02 and 0.04 K/s are studied. The time evolution of the interfacial total heat flux and the temperature field are recorded and analyzed. This allows us to evaluate heat transfer evolution due to natural convection, as well as its influence on the solidification macrostructure. To cite this article: X.D. Wang et al., C. R. Mecanique 335 (2007).

Acoustic emission from a solidifying aluminum-lithium alloy

NASA Technical Reports Server (NTRS)

Henkel, D. P.; Wood, J. D.

1992-01-01

Physical phenomena associated with the solidification of an AA2090 Al-Li alloy have been characterized by AE methods. Repeatable patterns of AE activity as a function of solidification time are recorded and explained for ultrahigh-purity (UHP) aluminum and an Al-4.7 wt pct Cu binary alloy, in addition to the AA2090 Al-Li alloy, by the complementary utilization of thermal, AE, and metallographic methods. One result shows that the solidification of UHP aluminum produces one discrete period of high AE activity as the last 10 percent of solid forms.

Directional Electrostatic Accretion Process Employing Acoustic Droplet Formation

NASA Technical Reports Server (NTRS)

Oeftering, Richard (Inventor)

1998-01-01

The present invention is directed to an apparatus for manufacturing a free standing solid metal part. In the present invention, metal droplets are ejected in a nozzleless fashion from a free surface pool of molten metal by applying focused acoustic radiation pressure. The acoustic radiation pressure is produced by high intensity acoustic tone bursts emitted from an acoustic source positioned at the bottom of the pool which directs the acoustic energy at the pool surface. The metal droplets are electrostatically charged so their trajectory can be controlled by electric fields that guide the droplets to predetermined points on a target. The droplets impinge upon the target and solidify with the target material. The accretion of the electrostatically directed solidified droplets forms the free standing metal part.

Use of rotation to suppress thermosolutal convection in directionally solidified binary alloys

NASA Technical Reports Server (NTRS)

Pearlstein, Arne J.

1994-01-01

Effects of rotation on onset of convection during plane-front directional solidification of Pb-Sn and the pseudobinary system mercury cadmium telluride (Hg(1-x)Cd(x)Te), and on dendritic solidification of Pb-Sn have been studied by means of linear stability analysis. Incorporating Coriolis and centrifugal accelerations into the momentum equation of Coriell et al., we find that under realistic processing conditions, a large degree of stabilization can be achieved using modest rotation rates for both Pb-Sn and mercury cadmium telluride. At a growth velocity of 5 micron/sec and nominal liquid-side temperature gradient of 200 K/cm in Pb-Sn, rotation at 500 rpm results in a hundredfold increase in the critical Sn concentration. Large increases in the maximum allowable growth velocity at fixed melt composition are also attainable with modest rotation rates. The effect is amplified under conditions of reduced gravitational acceleration. For Hg(1-x)Cd(x)Te, we have also studied the nonrotating case. The key differences are due to the existence of a composition range for Hg(1-x)Cd(x)Te in which the melt density has a local maximum as a function of temperature. When the melt solidifies by cooling from below, the liquid density may initially increase with distance above the interface, before ultimately decreasing as the melt temperature increases above the value at which the local density maximum occurs. In contrast to the Pb-Sn case where density depends monotonically on temperature and composition, for Hg(1-x)Cd(x)Te there exists a critical value of the growth velocity above which plane-front solidification is unstable for all bulk CdTe mole fractions. Again, rotation leads to significant inhibition of onset. We identify the predicted stabilization with the Taylor-Proudman mechanism by which rotation inhibits thermal convection in a single-component fluid heated from below. In a binary liquid undergoing solidification, rotation inhibits the onset of buoyancy-driven convection, and has no effect on the short-wavelength morphological instability. At large growth velocities, the plane-front interface between liquid and solid becomes unstable with respect to a morphological instability and solidification occurs dendritically, with a mushy zone of dendrites and interdendritic fluid separating the solid from the melt. For the Pb-Sn system, rotation substantially suppresses the onset of convection in the mushy zone and in the overlying liquid, holding open the promise that rotation can suppress freckling and other macrosegregation defects.

Effect of solidification parameters on mechanical properties of directionally solidified Al-Rich Al-Cu alloys

NASA Astrophysics Data System (ADS)

Çadırlı, Emin

2013-05-01

Al(100-x)-Cux alloys (x=3 wt%, 6 wt%, 15 wt%, 24 wt% and 33 wt%) were prepared using metals of 99.99% high purity in vacuum atmosphere. These alloys were directionally solidified under steady-state conditions by using a Bridgman-type directional solidification furnace. Solidification parameters (G, V and ), microstructure parameters (λ1, λ2 and λE) and mechanical properties (HV, σ) of the Al-Cu alloys were measured. Microstructure parameters were expressed as functions of solidification parameters by using a linear regression analysis. The dependency of HV, σ on the cooling rate, microstructure parameters and composition were determined. According to experimental results, the microhardness and ultimate tensile strength of the solidified samples was increased by increasing the cooling rate and Cu content, but decreased with increasing microstructure parameters. The microscopic fracture surfaces of the different samples were observed using scanning electron microscopy. Fractographic analysis of the tensile fracture surfaces showed that the type of fracture significantly changed from ductile to brittle depending on the composition.

Application of a Pore Fraction Hot Tearing Model to Directionally Solidified and Direct Chill Cast Aluminum Alloys

NASA Astrophysics Data System (ADS)

Dou, Ruifeng; Phillion, A. B.

2016-08-01

Hot tearing susceptibility is commonly assessed using a pressure drop equation in the mushy zone that includes the effects of both tensile deformation perpendicular to the thermal gradient as well as shrinkage feeding. In this study, a Pore Fraction hot tearing model, recently developed by Monroe and Beckermann (JOM 66:1439-1445, 2014), is extended to additionally include the effect of strain rate parallel to the thermal gradient. The deformation and shrinkage pore fractions are obtained on the basis of the dimensionless Niyama criterion and a scaling variable method. First, the model is applied to the binary Al-Cu system under conditions of directional solidification. It is shown that for the same Niyama criterion, a decrease in the cooling rate increases both the deformation and shrinkage pore fractions because of an increase in the time spent in the brittle temperature region. Second, the model is applied to the industrial aluminum alloy AA5182 as part of a finite element simulation of the Direct Chill (DC) casting process. It is shown that an increase in the casting speed during DC casting increases the deformation and shrinkage pore fractions, causing the maximum point of pore fraction to move towards the base of the casting. These results demonstrate that including the strain rate parallel to the thermal gradient significantly improves the predictive quality of hot tearing criteria based on the pressure drop equation.

Microstructure-property relationships in directionally solidified single crystal nickel-base superalloys

NASA Technical Reports Server (NTRS)

Mackay, R. A.; Nathal, M. V.

1986-01-01

Some of the microstructural features which influence the creep properties of directionally solidified and single crystal nickel-base superalloys are discussed. Gamma precipitate size and morphology, gamma-gamma lattice mismatch, phase instability, alloy composition, and processing variations are among the factors considered. Recent experimental results are reviewed and related to the operative deformation mechanisms and to the corresponding mechanical properties. Special emphasis is placed on the creep behavior of single crystal superalloys at high temperatures, where directional gamma coarsening is prominent, and at lower temperatures, where gamma coarsening rates are significantly reduced. It can be seen that very subtle changes in microstructural features can have profound effects on the subsequent properties of these materials.

Structure and creep rupture properties of directionally solidified eutectic gamma/gamma-prime-alpha alloy

NASA Technical Reports Server (NTRS)

Whittenberger, J. D.; Wirth, G.

1982-01-01

A simple ternary gamma/gamma-prime-alpha alloy of nominal composition (wt-%) Ni-32Mo-6Al has been directionally solidified at 17 mm/h and tested in creep rupture at 1073, 1173, and 1273 K. A uniform microstructure consisting of square-shaped Mo fibers in a gamma + gamma-prime matrix was found despite some variation in the molybdenum and aluminum concentrations along the growth direction. Although the steady-state creep rate is well described by the normal stress temperature equation, the stress exponent (12) and the activation energy (580 kJ/mol) are high. The rupture behavior is best characterized by the Larson-Miller parameter where the constant equals 20.

Experimental study of directionally solidified ferromagnetic shape memory alloy under multi-field coupling

NASA Astrophysics Data System (ADS)

Zhu, Yuping; Chen, Tao; Teng, Yao; Liu, Bingfei; Xue, Lijun

2016-11-01

Directionally solidified, polycrystalline Ni-Mn-Ga is studied in this paper. The polycrystalline Ni-Mn-Ga samples were cut at different angles to solidification direction. The magnetic field induced strain under constant stress and the temperature-induced strain under constant magnetic field during the loading-unloading cycle were measured. The experimental results show that the mechanical behavior during the loading-unloading cycle of the material is nonlinear and anisotropic. Based on the experimental results, the effects of multi-field coupling factors, such as stress, magnetic field, temperature and cutting angle on the mechanical behaviors were analyzed. Some useful conclusions were obtained, which will provide guidance for practical applications.

Directionally Solidified Aluminum - 7 wt% Silicon Alloys: Comparison of Earth and International Space Station Processed Samples

NASA Technical Reports Server (NTRS)

Grugel, Richard N,; Tewari, Surendra; Rajamure, R. S.; Erdman, Robert; Poirier, David

2012-01-01

Primary dendrite arm spacings of Al-7 wt% Si alloy directionally solidified in low gravity environment of space (MICAST-6 and MICAST-7: Thermal gradient approx. 19 to 26 K/cm, Growth speeds varying from 5 to 50 microns/s show good agreement with the Hunt-Lu model. Primary dendrite trunk diameters of the ISS processed samples show a good fit with a simple analytical model based on Kirkwood s approach, proposed here. Natural convection, a) decreases primary dendrite arm spacing. b) appears to increase primary dendrite trunk diameter.

Superconducting properties of Pb-Sn-In alloys directionally solidified aboard Skylab

NASA Technical Reports Server (NTRS)

Anderson, W. T., Jr.; Reger, J. L.

1975-01-01

Superconducting alloys of Pb-Sn-In were directionally solidified in the absence of gravity-induced convection and segregation by processing in a near weightless condition aboard Skylab. Lead-rich and tin-rich lamellar structures were obtained with both high and low G/R (temperature gradient/solidification rate) samples processed at 0-g and at 1-g in a ground-based laboratory. Thinner, higher density lamellae were found with the 0-g specimens. Magnetization curves at 4.2 K showed hysteresis effects with large areas under the curves indicating magnetic flux pinning by the normal state tin-rich phase.

Research on laser direct metal deposition

NASA Astrophysics Data System (ADS)

Zhang, Yongzhong; Shi, Likai

2003-03-01

Laser direct deposition of metallic parts is a new manufacturing technology, which combines with computer-aided design, laser cladding and rapid prototyping. Fully dense metallic parts can be directly obtained through melting the coaxially fed powders with a high-power laser in a layer-by-layer manner. The process characteristics, system composition as well as some research and advancement on laser direct deposition are presented here. The microstructure and properties observation of laser direct formed 663 copper alloy, 316L stainless steel and Rene'95 nickel super alloy samples indicate that, the as-deposited microstructure is similar to rapidly solidified materials, with homogenous composition and free of defects. Under certain conditions, directionally solidified microstructure can be obtained. The as-formed mechanical properties are equal to or exceed those for casting and wrought annealed materials. At the same time, some sample parts with complicate shape are presented for technology demonstration. The formed parts show good surface quality and dimensional accuracy.

Cold Heat Release Characteristics of Solidified Oil Droplet-Water Solution Latent Heat Emulsion by Air Bubbles

NASA Astrophysics Data System (ADS)

Inaba, Hideo; Morita, Shin-Ichi

The present work investigates the cold heat-release characteristics of the solidified oil droplets (tetradecane, C14H30, freezing point 278.9 K)/water solution emulsion as a latent heat-storage material having a low melting point. An air bubbles-emulsion direct-contact heat exchange method is selected for the cold heat-results from the solidified oil droplet-emulsion layer. This type of direct-contact method results in the high thermal efficiency. The diameter of air bubbles in the emulsion increases as compared with that in the pure water. The air bubbles blown from a nozzle show a strong mixing behavior during rising in the emulsion. The temperature effectiveness, the sensible heat release time and the latent heat release time have been measured as experimental parameters. The useful nondimensional emulsion level equations for these parameters have been derived in terms of the nondimensional emalsion level expressed the emulsion layer dimensions, Reynolds number for air flow, Stefan number and heat capacity ratio.

Effect of Convection Associated with Cross-section Change during Directional Solidification of Binary Alloys on Dendritic Array Morphology and Macrosegregation

NASA Astrophysics Data System (ADS)

Ghods, Masoud

This dissertation explores the role of different types of convection on macrosegregation and on dendritic array morphology of two aluminum alloys directionally solidified through cylindrical graphite molds having both cross-section decrease and increase. Al- 19 wt. % Cu and Al-7 wt. % Si alloys were directionally solidified at two growth speed of 10 and 29.1 mum s-1 and examined for longitudinal and radial macrosegregation, and for primary dendrite spacing and dendrite trunk diameter. Directional solidification of these alloys through constant cross-section showed clustering of primary dendrites and parabolic-shaped radial macrosegregation profile, indicative of "steepling convection" in the mushy-zone. The degree of radial macrosegregation increased with decreased growth speed. The Al- 19 wt. % Cu samples, grown under similar conditions as Al-7 wt. % Si, showed more radial macrosegregation because of more intense "stepling convection" caused by their one order of magnitude larger coefficient of solutal expansion. Positive macrosegregation right before, followed by negative macrosegregation right after an abrupt cross-section decrease (from 9.5 mm diameter to 3.2 mm diameter), were observed in both alloys; this is because of the combined effect of thermosolutal convection and area-change-driven shrinkage flow in the contraction region. The degree of macrosegregation was found to be higher in the Al- 19 wt. % Cu samples. Strong area-change-driven shrinkage flow changes the parabolic-shape radial macrosegregation in the larger diameter section before contraction to "S-shaped" profile. But in the smaller diameter section after the contraction very low degree of radial macrosegregation was found. The samples solidified through an abrupt cross-section increase (from 3.2 mm diameter to 9.5 mm diameter) showed negative macrosegregation right after the cross-section increase on the expansion platform. During the transition to steady-state after the expansion, radial macrosegregation profile in locations close to the expansion was found to be "S-shaped". This is attributed to the redistribution of solute-rich liquid ahead of the mushy-zone as it transitions from the narrow portion below into the large diameter portion above. Solutal remelting and fragmentation of dendrite branches, and floating of these fragmented pieces appear to be responsible for spurious grains formation in Al- 19 wt. % Cu samples after the cross-section expansion. New grain formation was not observed in Al-7 wt. % Si in similar locations; it is believed that this is due to the sinking of the fragmented dendrite branches in this alloy. Experimentally observed radial and axial macrosegregations agree well with the results obtained from the numerical simulations carried out by Dr. Mark Lauer and Prof. David R. Poirier at the University of Arizona. Trunk Diameter (TD) of dendritic array appears to respond more readily to the changing growth conditions as compared to the Nearest Neighbor Spacing (NNS) of primary dendrites.

Resistance of a directionally solidified gamma/gamma prime-delta eutectic alloy to recrystallization. [Ni-base alloy

NASA Technical Reports Server (NTRS)

Tewari, S. N.; Scheuermann, C. M.; Andrews, C. W.

1976-01-01

A lamellar nickel-base directionally-solidified eutectic gamma/gamma prime-delta alloy has potential as an advanced gas turbine blade material. The microstructural stability of this alloy was investigated. Specimens were plastically deformed by uniform compression or Brinell indentation, then annealed between 750 and 1120 C. Microstructural changes observed after annealing included gamma prime coarsening, pinch-off and spheroidization of delta lamellae, and appearance of an unidentified blocky phase in surface layers. All but the first of these was localized in severely deformed regions, suggesting that microstructural instability may not be a serious problem in the use of this alloy.

Resistance of a gamma/gamma prime - delta directionally solidified eutectic alloy to recrystallization

NASA Technical Reports Server (NTRS)

Tewari, S. N.; Scheuermann, C. M.; Andrews, C. W.

1975-01-01

The lamellar directionally solidified nickel-base eutectic alloy gamma/gamma prime-delta has potential as an advanced turbine blade material. The microstructural stability of this alloy was investigated. Specimens were plastically deformed by uniform compression or Brinell indentation, then annealed between 705 and 1120 C. Microstructural changes observed after annealing included gamma prime coarsening, pinch-off and spheroidization of delta lamellae, and the appearance of an unidentified blocky phase in surface layers. All but the first of these was localized in severely deformed regions, suggesting that microstructural instability is not a serious problem in the use of this alloy.

1300 K Compressive Properties of Directionally Solidified Ni-33Al-33Cr-1Mo

NASA Technical Reports Server (NTRS)

Whittenberger, J. Daniel; Raj, S. V.; Locci, Ivan E.

2000-01-01

The Ni-33Al-33Cr-1Mo eutectic has been directionally solidified by a modified Bridgeman technique at growth rates ranging from 7.6 to 508 mm/h to produce grain/cellular microstructures, containing alternating plates of NiAl and Cr alloyed with Mo. The grains had sharp boundaries for slower growth rates (< 12.7 mm/h), while faster growth rates (> 25.4 mm/h) lead to cells bounded by intercellular regions. Compressive testing at 1300 K indicated that alloys DS'ed at rates between 25.4 to 254 mm/h possessed the best strengths which exceed that for the as-cast alloy.

An Abnormal Increase of Fatigue Life with Dwell Time during Creep-Fatigue Deformation for Directionally Solidified Ni-Based Superalloy DZ445

NASA Astrophysics Data System (ADS)

Ding, Biao; Ren, Weili; Deng, Kang; Li, Haitao; Liang, Yongchun

2018-03-01

The paper investigated the creep-fatigue behavior for directionally solidified nickel-based superalloy DZ445 at 900 °C. It is found that the fatigue life shows an abnormal increase when the dwell time exceeds a critical value during creep-fatigue deformation. The area of hysteresis loop and fractograph explain the phenomenon quite well. The shortest life corresponds to the maximal area of hysteresis loop, i. e. the maximum energy to be consumed during the creep-fatigue cycle. The fractographic observation of failed samples further supports the abnormal behavior of fatigue life.

Development of low-cost directionally-solidified turbine blades

NASA Technical Reports Server (NTRS)

Hoppin, G. S., III; Fujii, M.; Sink, L. W.

1980-01-01

A low-cost directionally solidified (DS) casting of turbine blades of high stress rupture is discussed. The process uses an exothermically heated mold; a newly designed solid blade was cast for the high-pressure turbine of the TFE731-3 turbofan engine. Ni-based alloys Mar-M 247 and Mar-M 200 + Hf were used. The solid DS blade replaced a conventionally cast IN100 component; a 40% cost saving is expected, with a 2.4% reduction in the takeoff specific fuel consumption. The DS Mar-M 247 blade has been selected for production in the TFE731-3B-100, and advanced version of the TFE731-3.

Directional solidification of eutectic composites in space environment

NASA Technical Reports Server (NTRS)

Yue, A. S.

1972-01-01

The Ni-Ni3Ta eutectic and a nickel-base alloy containing 30 wt pct Ta were solidified unidirectionally in an electron beam floating zone melting apparatus. It was found that the volume fraction of the Ni3Ta phase in the Ni-Ni3Ta eutectic mixture was increased from 7.6 to 36 volume pct in agreement with the theory as predicted. Tensile properties of the randomly solidified and unidirectionally solidified Ni-Ni3Ta eutectic were determined as function of solidification rate and temperature. It was found that the ultimate tensile strength decreased as both the test temperature and solidification rate increased. An elongation of 40 pct was obtained for a nickelbase alloy containing 30 wt at room temperature. This unusually large elongation was attributed to the superplastic behavior of the alloy. The critical currents versus the external fields at 2.5, 3.0, 3.5 and 4.2 deg for the unidirectionally solidified Pb-Sn eutectic were measured. The values of critical fields at zero critical currents were obtained by extrapolation.

Effect of tensile mean stress on fatigue behavior of single-crystal and directionally solidified superalloys

NASA Technical Reports Server (NTRS)

Kalluri, Sreeramesh; Mcgaw, Michael A.

1992-01-01

Two nickel base superalloys, single crystal PWA 1480 and directionally solidified MAR-M 246 + Hf, were studied in view of the potential usage of the former and usage of the latter as blade materials for the turbomachinery of the Space Shuttle main engine. The baseline zero mean stress (ZMS) fatigue life (FL) behavior of these superalloys was established, and then the effect of tensile mean stress (TMS) on their FL behavior was characterized. A stress range based FL prediction approach was used to characterize both the ZMS and TMS fatigue data. In the past, several researchers have developed methods to account for the detrimental effect of tensile mean stress on the FL for polycrystalline engineering alloys. These methods were applied to characterize the TMS fatigue data of single crystal PWA 1480 and directionally solidified MAR-M 246 + Hf and were found to be unsatisfactory. Therefore, a method of accounting for the TMS effect on FL, that is based on a technique proposed by Heidmann and Manson was developed to characterize the TMS fatigue data of these superalloys. Details of this method and its relationship to the conventionally used mean stress methods in FL prediction are discussed.

Al and Mg Alloys for Aerospace Applications Using Rapid Solidification and Powder Metallurgy Processing.

DTIC Science & Technology

1986-11-14

5wt % Si was completely different from that of the alloy without silicon. The (X phase formed around the primary Mg2 Si crystals, and an irregular...content, and primary crystals in a binary Mg- 5wt % Si alloy did not exhibit this behavior. The surface of the rapidly solidified melt pools was rough and...Microhardness* of the laser treated alloys . Alloy As-cast Laser treated Mg- 5wt %Li 40.8 55.7 o, Mg- 5wt %Li- 5wt % Si 51.1 74.1 Mg-8wt%Li 42.8 71.2

Strain hardening and fracture behavior during tension of directionally solidified high-nitrogen austenitic steel

NASA Astrophysics Data System (ADS)

Maier, Galina; Astafurova, Elena; Melnikov, Eugene; Moskvina, Valentina; Galchenko, Nina

2017-12-01

The effect of grain orientation relative to tensile load on the strain hardening behavior and fracture mechanism of directionally solidified high-nitrogen steel Fe-20Cr-22Mn-1.5V-0.2C-0.6N (in wt %) was studied. The tensile samples oriented along the longitudinal direction of columnar grains demonstrated the improved mechanical properties compared to specimens with the transversal directions of columnar grains: the values of tensile strength and strain-to-fracture were as high as 1080 MPa and 22%, respectively, for tension along the columnar grains and 870 MPa and 11%, respectively, for the tension transversal to the columnar grains. The change in the grain orientation relative to the tensile load varies a fracture mode of the steel. The fraction of the transgranular fracture was higher in the samples with longitudinal directions of the columnar grains compared to the transversal ones.

Preparation of directionally solidified BaTi2O5-Ba6Ti17O40 eutectic by the floating zone method

NASA Astrophysics Data System (ADS)

Shiga, K.; Katsui, H.; Goto, T.

2017-02-01

The BaTi2O5-Ba6Ti17O40 eutectic (BaO-68.7 mol% TiO2) was directionally solidified by the floating zone (FZ) method and crystalline phases, microstructures and orientation were investigated. Ba6Ti17O40 with faceted rod-like shape was dispersed in the BaTi2O5 matrix. The growth directions of BaTi2O5 and Ba6Ti17O40 were parallel to the b and a axis, respectively, and the orientation relations were BaTi2O5 (010)//Ba6Ti17O40(60 2 ̅) and BaTi2O5 (001)//Ba6Ti17O40 (001).

Directionally Solidified NiAl-Based Alloys Studied for Improved Elevated-Temperature Strength and Room-Temperature Fracture Toughness

NASA Technical Reports Server (NTRS)

Whittenberger, J. Daniel; Raj, Sai V.; Locci, Ivan E.; Salem, Jonathan A.

2000-01-01

Efforts are underway to replace superalloys used in the hot sections of gas turbine engines with materials possessing better mechanical and physical properties. Alloys based on the intermetallic NiAl have demonstrated potential; however, they generally suffer from low fracture resistance (toughness) at room temperature and from poor strength at elevated temperatures. Directional solidification of NiAl alloyed with both Cr and Mo has yielded materials with useful toughness and elevated-temperature strength values. The intermetallic alloy NiAl has been proposed as an advanced material to extend the maximum operational temperature of gas turbine engines by several hundred degrees centigrade. This intermetallic alloy displays a lower density (approximately 30-percent less) and a higher thermal conductivity (4 to 8 times greater) than conventional superalloys as well as good high-temperature oxidation resistance. Unfortunately, unalloyed NiAl has poor elevated temperature strength (approximately 50 MPa at 1027 C) and low room-temperature fracture toughness (about 5 MPa). Directionally solidified NiAl eutectic alloys are known to possess a combination of high elevated-temperature strength and good room-temperature fracture toughness. Research has demonstrated that a NiAl matrix containing a uniform distribution of very thin Cr plates alloyed with Mo possessed both increased fracture toughness and elevated-temperature creep strength. Although attractive properties were obtained, these alloys were formed at low growth rates (greater than 19 mm/hr), which are considered to be economically unviable. Hence, an investigation was warranted of the strength and toughness behavior of NiAl-(Cr,Mo) directionally solidified at faster growth rates. If the mechanical properties did not deteriorate with increased growth rates, directional solidification could offer an economical means to produce NiAl-based alloys commercially for gas turbine engines. An investigation at the NASA Glenn Research Center at Lewis Field was undertaken to study the effect of the directional solidification growth rate on the microstructure, room temperature fracture toughness, and strength at 1027 C of a Ni-33Al-31Cr-3Mo eutectic alloy. The directionally solidified rates varied between 7.6 and 508 millimeters per hour Essentially fault-free, alternating (Cr, Mo)/NiAl lamellar plate microstructures (left photograph) were formed during growth at and below 12.7 mm/hr, whereas cellular microstructures (right photograph) with the (Cr, Mo) phase in a radial spokelike pattern were developed at faster growth rates. The compressive strength at 1027 C continuously increased with increasing growth rate and did not indicate a maxima as was reported for directionally solidified Ni-33Al-34Cr. Surprisingly, samples with the lamellar plate microstructure (left photograph) possessed a room-temperature fracture toughness of approximately 12 MPa(sup square root of m), whereas all the alloys with a cellular microstructure had a toughness of about 17 MPa(sup square root of m). These results are significant since they clearly demonstrate that Ni-33Al-31Cr-3Mo can be directionally solidified at much faster growth rates without any observable deterioration in its mechanical properties. Thus, the potential to produce strong, tough NiAl-based eutectics at commercially acceptable growth rates exists. Additional testing and alloy optimization studies are underway.

Controllable Thermal Rectification Realized in Binary Phase Change Composites

PubMed Central

Chen, Renjie; Cui, Yalong; Tian, He; Yao, Ruimin; Liu, Zhenpu; Shu, Yi; Li, Cheng; Yang, Yi; Ren, Tianling; Zhang, Gang; Zou, Ruqiang

2015-01-01

Phase transition is a natural phenomenon happened around our daily life, represented by the process from ice to water. While melting and solidifying at a certain temperature, a high heat of fusion is accompanied, classified as the latent heat. Phase change material (PCM) has been widely applied to store and release large amount of energy attributed to the distinctive thermal behavior. Here, with the help of nanoporous materials, we introduce a general strategy to achieve the binary eicosane/PEG4000 stuffed reduced graphene oxide aerogels, which has two ends with different melting points. It's successfully demonstrated this binary PCM composites exhibits thermal rectification characteristic. Partial phase transitions within porous networks instantaneously result in one end of the thermal conductivity saltation at a critical temperature, and therefore switch on or off the thermal rectification with the coefficient up to 1.23. This value can be further raised by adjusting the loading content of PCM. The uniqueness of this device lies in its performance as a normal thermal conductor at low temperature, only exhibiting rectification phenomenon when temperature is higher than a critical value. The stated technology has broad applications for thermal energy control in macroscopic scale such as energy-efficiency building or nanodevice thermal management. PMID:25748640

Controllable Thermal Rectification Realized in Binary Phase Change Composites

NASA Astrophysics Data System (ADS)

Chen, Renjie; Cui, Yalong; Tian, He; Yao, Ruimin; Liu, Zhenpu; Shu, Yi; Li, Cheng; Yang, Yi; Ren, Tianling; Zhang, Gang; Zou, Ruqiang

2015-03-01

Phase transition is a natural phenomenon happened around our daily life, represented by the process from ice to water. While melting and solidifying at a certain temperature, a high heat of fusion is accompanied, classified as the latent heat. Phase change material (PCM) has been widely applied to store and release large amount of energy attributed to the distinctive thermal behavior. Here, with the help of nanoporous materials, we introduce a general strategy to achieve the binary eicosane/PEG4000 stuffed reduced graphene oxide aerogels, which has two ends with different melting points. It's successfully demonstrated this binary PCM composites exhibits thermal rectification characteristic. Partial phase transitions within porous networks instantaneously result in one end of the thermal conductivity saltation at a critical temperature, and therefore switch on or off the thermal rectification with the coefficient up to 1.23. This value can be further raised by adjusting the loading content of PCM. The uniqueness of this device lies in its performance as a normal thermal conductor at low temperature, only exhibiting rectification phenomenon when temperature is higher than a critical value. The stated technology has broad applications for thermal energy control in macroscopic scale such as energy-efficiency building or nanodevice thermal management.

Growth kinetics of gamma-prime precipitates in a directionally solidified eutectic, gamma/gamma-prime-delta

NASA Technical Reports Server (NTRS)

Tewari, S. N.

1976-01-01

A directionally solidified eutectic alloy (DSEA), of those viewed as potential candidates for the next generation of aircraft gas turbine blade materials, is studied for the gamma-prime growth kinetics, in the system Ni-Nb-Cr-Al, specifically: Ni-20 w/o Nb-6 w/o Cr-2.5 w/o Al gamma/gamma-prime-delta DSEA. Heat treatment, polishing and etching, and preparation for electron micrography are described, and the size distribution of gamma-prime phase following various anneals is plotted, along with gamma-prime growth kinetics in this specific DSEA, and the cube of gamma-prime particle size vs anneal time. Activation energies and coarsening kinetics are studied.

Directionally solidified eutectic alloy gamma-beta

NASA Technical Reports Server (NTRS)

Tewari, S. N.

1977-01-01

A pseudobinary eutectic alloy composition was determined by a previously developed bleed-out technique. The directionally solidified eutectic alloy with a composition of Ni-37.4Fe-10.0Cr-9.6Al (in wt%) had tensile strengths decreasing from 1,090 MPa at room temperature to 54 MPa at 1,100 C. The low density, excellent microstructural stability, and oxidation resistance of the alloy during thermal cycling suggest that it might have applicability as a gas turbine vane alloy while its relatively low high temperature strength precludes its use as a blade alloy. A zirconium addition increased the 750 C strength, and a tungsten addition was ineffective. The gamma=beta eutectic alloys appeared to obey a normal freezing relation.

High temperature oxidation resistant coatings for the directionally solidified Ni-Nb-Cr-Al eutectic superalloy

NASA Technical Reports Server (NTRS)

Strangman, T. E.; Ulion, N. E.; Felten, E. J.

1977-01-01

Protective coatings required for the Ni-Nb-Cr-Al directionally solidified eutectic superalloy were developed and evaluated on the basis of oxidation resistance, diffusional stability, thermal fatigue, and creep resistance. NiCrAlY+Pt and NiCrAlY physical vapor-deposition coating systems exhibited the best combination of properties. Burner-rig testing indicated that the useful life of a 127-micron-thick NiCrAlY+Pt coating exceeds 1000 h at 1366 K. Eutectic-alloy creep lives at 1311 K and a stress of 151.7 MN/sq m were greater for NiCrAlY+Pt-coated specimens than for uncoated specimens by a factor of two.

Effects of convection patterns on freckle formation of directionally solidified Nickel-based superalloy casting with abruptly varying cross-sections

NASA Astrophysics Data System (ADS)

Qin, Ling; Shen, Jun; Li, Qiudong; Shang, Zhao

2017-05-01

The effects of convection patterns on freckle formation of directionally solidified Nickel-based superalloy sample with abruptly varying cross-sections were investigated experimentally and numerically. The experimental results demonstrate that freckles were only observed at the bottom of larger cross-section. Numerical results indicate that this phenomenon should be attributed to the different convection patterns at front of solidification interface. As the withdrawal rate increased, the primary dendrites spacing has an obvious influence on freckle formation. A more in-depth investigation of the convection patterns can provide a better understanding of freckle formation and perhaps offer methods to minimize freckles in turbine blades.

The influence of processing parameters on microstructural development of low-weight-percent primary, pro-eutectic, dendritic alloys during directional solidification

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Kim, Shinwoo; Woodward, Tracey; Wang, T. G.

1992-01-01

Alloy compositions centering about Sn- 5 to 15 wt pct Al and Pb- 4 to 20 wt pct Cu have been directionally solidified as a function of growth rate and orientation with respect to earth's gravity vector. The effect of these processing variables on macrosegregation is presented, and the consequence of a structural transition from primary columnar to equiaxed dendritic growth is examined. Effects detrimental to microstructure and attributed to density variations are shown to be minimized by a novel processing technique. In view of the ground-based results, some considerations follow regarding what might be gained by solidifying these alloys in a microgravity environment.

Low-cost directionally-solidified turbine blades, volume 2. [TFE731-3 turbofan engine

NASA Technical Reports Server (NTRS)

Dennis, R. E.; Hoppin, G. S., III; Hurst, L. G.

1979-01-01

An endothermically heated technology was used to manufacture low cost, directionally solidified, uncooled nickel-alloy blades for the TFE731-3 turbofan engine. The MAR-M 247 and MER-M 100+Hf blades were finish processed through heat treatment, machining, and coating operations prior to 150 hour engine tests consisting of the following sequences: (1) 50 hours of simulated cruise cycling (high fatigue evaluation); (2) 50 hours at the maximum continuous power rating (stress rupture endurance (low cycle fatigue). None of the blades visually showed any detrimental effects from the test. This was verified by post test metallurgical evaluation. The specific fuel consumption was reduced by 2.4% with the uncooled blades.

Directionally solidified iron-base eutectic alloys

NASA Technical Reports Server (NTRS)

Tewari, S. N.

1976-01-01

Pseudobinary eutectic alloys with nominal compositions of Fe-25Ta-22Ni-10Cr and Fe-15.5Nb-14.5Ni-6.0Cr were directionally solidified at 0.5 centimeter per hour. Their microstructure consisted of the fcc, iron solid-solution, matrix phase reinforced by about 41-volume-percent, hcp, faceted Fe2Ta fibers and 41-volume-percent, hcp, Fe2Nb lamellae for the tantalum- and niobium-containing alloys, respectively. The microstructural stability under thermal cycling and the temperature dependence of tensile properties were investigated. These alloys showed low elevated-temperature strength and were not considered suitable for application in aircraft-gas-turbine blades although they may have applicability as vane materials.

Freckle Defect Formation near the Casting Interfaces of Directionally Solidified Superalloys

PubMed Central

Hong, Jianping; Ma, Dexin; Wang, Jun; Wang, Fu; Sun, Baode; Dong, Anping; Li, Fei; Bührig-Polaczek, Andreas

2016-01-01

Freckle defects usually appear on the surface of castings and industrial ingots during the directional solidification process and most of them are located near the interface between the shell mold and superalloys. Ceramic cores create more interfaces in the directionally solidified (DS) and single crystal (SX) hollow turbine blades. In order to investigate the location of freckle occurrence in superalloys, superalloy CM247 LC was directionally solidified in an industrial-sized Bridgman furnace. Instead of ceramic cores, Alumina tubes were used inside of the casting specimens. It was found that freckles occur not only on the casting external surfaces, but also appear near the internal interfaces between the ceramic core and superalloys. Meanwhile, the size, initial position, and area of freckle were investigated in various diameters of the specimens. The initial position of the freckle chain reduces when the diameter of the rods increase. Freckle area follows a linear relationship in various diameters and the average freckle fraction is 1.1% of cross sectional area of casting specimens. The flow of liquid metal near the interfaces was stronger than that in the interdendritic region in the mushy zone, and explained why freckle tends to occur on the outer or inner surfaces of castings. This new phenomenon suggests that freckles are more likely to occur on the outer or inner surfaces of the hollow turbine blades. PMID:28774050

Freckle Defect Formation near the Casting Interfaces of Directionally Solidified Superalloys.

PubMed

Hong, Jianping; Ma, Dexin; Wang, Jun; Wang, Fu; Sun, Baode; Dong, Anping; Li, Fei; Bührig-Polaczek, Andreas

2016-11-16

Freckle defects usually appear on the surface of castings and industrial ingots during the directional solidification process and most of them are located near the interface between the shell mold and superalloys. Ceramic cores create more interfaces in the directionally solidified (DS) and single crystal (SX) hollow turbine blades. In order to investigate the location of freckle occurrence in superalloys, superalloy CM247 LC was directionally solidified in an industrial-sized Bridgman furnace. Instead of ceramic cores, Alumina tubes were used inside of the casting specimens. It was found that freckles occur not only on the casting external surfaces, but also appear near the internal interfaces between the ceramic core and superalloys. Meanwhile, the size, initial position, and area of freckle were investigated in various diameters of the specimens. The initial position of the freckle chain reduces when the diameter of the rods increase. Freckle area follows a linear relationship in various diameters and the average freckle fraction is 1.1% of cross sectional area of casting specimens. The flow of liquid metal near the interfaces was stronger than that in the interdendritic region in the mushy zone, and explained why freckle tends to occur on the outer or inner surfaces of castings. This new phenomenon suggests that freckles are more likely to occur on the outer or inner surfaces of the hollow turbine blades.

Modeling the interaction of biological cells with a solidifying interface

NASA Astrophysics Data System (ADS)

Chang, Anthony; Dantzig, Jonathan A.; Darr, Brian T.; Hubel, Allison

2007-10-01

In this article, we develop a modified level set method for modeling the interaction of particles with a solidifying interface. The dynamic computation of the van der Waals and drag forces between the particles and the solidification front leads to a problem of multiple length scales, which we resolve using adaptive grid techniques. We present a variety of example problems to demonstrate the accuracy and utility of the method. We also use the model to interpret experimental results obtained using directional solidification in a cryomicroscope.

Segregation and microstructure evolution in chill cast and directionally solidified Ni-Mn-Sn metamagnetic shape memory alloys

NASA Astrophysics Data System (ADS)

Czaja, P.; Wierzbicka-Miernik, A.; Rogal, Ł.

2018-06-01

A multiphase solidification behaviour is confirmed for a range of Ni-rich and Ni-deficient Ni-Mn-Sn induction cast and directionally solidified (Bridgman) alloys. The composition variation is primarily linked to the changing Mn/Sn ratio, whereas the content of Ni remains largely stable. The partitioning coefficients for the Ni50Mn37Sn13 and Ni46Mn41.5Sn12.5 Bridgman alloys were obtained according to the Scheil equation based on the composition distribution along the longitudinal cross section of the ingots. Homogenization heat treatment performed for 72 h at 1220 K turned out sufficient for ensuring chemical uniformity on the macro- and microscale. It is owed to a limited segregation length scale due to slow cooling rates adopted for the directional solidification process.

Effects of Minor Alloying Additions on the Microstructure, Toughness, and Creep Strength of Directionally Solidified NiAl-31Cr-3Mo

NASA Technical Reports Server (NTRS)

Whittenberger, J. D.; Raj, S. V.; Locci, I. E.; Salem, J. A.

2001-01-01

A study of the effects of small (0.25 to 1.0 at%) fifth element additions to the structure and mechanical properties of directionally solidified (DS) NiAl-31Cr-3Mo has been undertaken. Essentially all the additions changed the as-DS'ed microstructure from lamellar eutectic grains to cells and, in some cases, introduced NiAl dendrites and/or third phases. In general the alloying additions did not improve strength or toughness over that possessed by the base composition; only Hf and, perhaps Ti, gave a minor increase in elevated temperature creep resistance. The lack of improvement in creep properties is probably due to inability to precipitation harden NiAl.

Microstructural Characterization of a Directionally-Solidified Ni-33 (at. %)Al-31Cr-3Mo Eutectic Alloy as a Function of Withdrawal Rate

NASA Technical Reports Server (NTRS)

Raj, S. V.; Locci, I. E.; Whittenberger, J. D.; Salem, J. A.

2000-01-01

The Ni-33 (at. %)Al-3lCr-3Mo eutectic alloy was directionally-solidified (DS) at different rates, V(sub I), varying between 2.5 to 508 mm/ h. Detailed qualitative and quantitative metallographic and chemical analyses were conducted on the directionally-solidified rods. The microstructures consisted of eutectic colonies with parallel lamellar NiAl/(Cr,Mo) plates for solidification rates at and below 12.7 mm/ h. Cellular eutectic microstructures were observed at higher solidification rates, where the plates exhibited a radial pattern. The microstructures were demonstrated to be fairly uniform throughout a 100 mm length of the DS zone by quantitative metallography. The average cell size, bar-d, decreased with increasing growth rate to a value of 125 microns at 508 mm/ h according to the relation bar-d (microns) approx. = 465 V(sup -0.22, sub I), where V(sub I) is in mm/ h. Both the average NiAl plate thickness, bar-Delta(sub NiAl), and the interlamellar spacing, bar-lambda, were observed to be constant for V(sub I) less than or = 50.8 mm/ h but decreased with increasing growth rate above this value as 0.93 bar-Delta(sub NiAl)(microns) = 61.2 V(sup -0.93, sub I) and bar-lambda (microns) = 47.7 V(sup -0.64, sub I), respectively. The present results are detailed on a microstructural map. Keywords Optical microscopy, microstructure, compounds intermetallic, directional solidification

Studies of the Influence of Beam Profile and Cooling Conditions on the Laser Deposition of a Directionally-Solidified Superalloy.

PubMed

Yang, Shuo; Du, Dong; Chang, Baohua

2018-02-04

In the laser deposition of single crystal and directionally-solidified superalloys, it is desired to form laser deposits with high volume fractions of columnar grains by suppressing the columnar-to-equiaxed transition efficiently. In this paper, the influence of beam profile (circular and square shapes) and cooling conditions (natural cooling and forced cooling) on the geometric morphology and microstructure of deposits were experimentally studied in the laser deposition of a directionally-solidified superalloy, IC10, and the mechanisms of influence were revealed through a numerical simulation of the thermal processes during laser deposition. The results show that wider and thinner deposits were obtained with the square laser beam than those with the circular laser beam, regardless of whether natural or forced cooling conditions was used. The heights and contact angles of deposits were notably increased due to the reduced substrate temperatures by the application of forced cooling for both laser beam profiles. Under natural cooling conditions, columnar grains formed epitaxially at both the center and the edges of the deposits with the square laser beam, but only at the center of the deposits with the circular laser beam; under forced cooling conditions, columnar grains formed at both the center and the edges of deposits regardless of the laser beam profile. The high ratios of thermal gradient and solidification velocity in the height direction of the deposits were favorable to forming deposits with higher volume fractions of columnar grains.

Studies of the Influence of Beam Profile and Cooling Conditions on the Laser Deposition of a Directionally-Solidified Superalloy

PubMed Central

Yang, Shuo; Du, Dong

2018-01-01

In the laser deposition of single crystal and directionally-solidified superalloys, it is desired to form laser deposits with high volume fractions of columnar grains by suppressing the columnar-to-equiaxed transition efficiently. In this paper, the influence of beam profile (circular and square shapes) and cooling conditions (natural cooling and forced cooling) on the geometric morphology and microstructure of deposits were experimentally studied in the laser deposition of a directionally-solidified superalloy, IC10, and the mechanisms of influence were revealed through a numerical simulation of the thermal processes during laser deposition. The results show that wider and thinner deposits were obtained with the square laser beam than those with the circular laser beam, regardless of whether natural or forced cooling conditions was used. The heights and contact angles of deposits were notably increased due to the reduced substrate temperatures by the application of forced cooling for both laser beam profiles. Under natural cooling conditions, columnar grains formed epitaxially at both the center and the edges of the deposits with the square laser beam, but only at the center of the deposits with the circular laser beam; under forced cooling conditions, columnar grains formed at both the center and the edges of deposits regardless of the laser beam profile. The high ratios of thermal gradient and solidification velocity in the height direction of the deposits were favorable to forming deposits with higher volume fractions of columnar grains. PMID:29401715

Investigation of the growth of directionally solidified eutectics with potential as electron emitters

NASA Technical Reports Server (NTRS)

Chapman, A. T.; Cochran, J. K.

1976-01-01

The construction of a solar furnace was completed and it was tested after a preliminary alignment of the heliostat mirrors. After final alignment, the solar furnace is used for directional solidification experiments designed to simulate space conditions.

Microstructure and property of directionally solidified Ni-Si hypereutectic alloy

NASA Astrophysics Data System (ADS)

Cui, Chunjuan; Tian, Lulu; Zhang, Jun; Yu, Shengnan; Liu, Lin; Fu, Hengzhi

2016-03-01

This paper investigates the influence of the solidification rate on the microstructure, solid/liquid interface, and micro-hardness of the directionally solidified Ni-Si hypereutectic alloy. Microstructure of the Ni-Si hypereutectic alloy is refined with the increase of the solidification rate. The Ni-Si hypereutectic composite is mainly composed of α-Ni matrix, Ni-Ni3Si eutectic phase, and metastable Ni31Si12 phase. The solid/liquid interface always keeps planar interface no matter how high the solidification rate is increased. This is proved by the calculation in terms of M-S interface stability criterion. Moreover, the Ni-Si hypereutectic composites present higher micro-hardness as compared with that of the pure Ni3Si compound. This is caused by the formation of the metastable Ni31Si12 phase and NiSi phase during the directional solidification process.

Influence of a magnetic field during directional solidification of MAR-M 246 + Hf superalloy

NASA Technical Reports Server (NTRS)

Andrews, J. Barry; Alter, Wendy; Schmidt, Dianne

1991-01-01

An area that has been almost totally overlooked in the optimization of properties in directionally solidified superalloys is the control of microstructural features through the application of a magnetic field during solidification. The influence of a magnetic field on the microstructural features of a nickel-base superalloys is investigated. Studies were performed on the dendritic MAR-M 246+Hf alloy, which was solidified under both a 5 K gauss magnetic field and under no-applied-field conditions. The possible influences of the magnetic field on the solidification process were observed by studying variations in microstructural features including volume fraction, surface area, number, and shape of the carbide particles. Stereological factors analyzed also included primary and secondary dendrite arm spacing and the volume fraction of the interdendritic eutectic constituent. Microprobe analysis was performed to determine the chemistry of the carbides, dendrites, and interdendritic constituents, and how it varied between field and no-field solidification samples. Experiments involving periodic application and removal of the magnetic field were also performed in order to permit a comparison with structural variations observed in a MAR-M 246+Hf alloy solidified during KC-135 high-g, low-g maneuvers.

Influence of convection on eutectic microstructure

NASA Technical Reports Server (NTRS)

Baskaran, V.; Eisa, G. F.; Wilcox, W. R.

1985-01-01

When the MnBi-Bi eutectic is directionally solidified, it forms fibers of MnBi in a matrix of bismuth. When the material solidified in space at rates of 30 and 50 cm/hr, the average fiber spacing lambda was about one half of the value obtained in cases in which the same material solidified on earth. Neither an altered temperature gradient nor a fluctuating freezing rate are apparently responsible for the change in lambda, and the possibility is studied that natural convection increases lambda on earth by perturbing the compositional field in the melt ahead of the growing solid. A theoretical analysis is conducted along with some experiments. On the basis of the theoretical results for lamellar growth, it is concluded that the spacing lambda increases with increasing stirring, especially at small freezing rates. The experiments indicate that at low growth rates the cross-sectional area of the MnBi blades increases with increased stirring and with decreased growth rate.

Solidification processing of monotectic alloy matrix composites

NASA Technical Reports Server (NTRS)

Frier, Nancy L.; Shiohara, Yuh; Russell, Kenneth C.

1989-01-01

Directionally solidified aluminum-indium alloys of the monotectic composition were found to form an in situ rod composite which obeys a lambda exp 2 R = constant relation. The experimental data shows good agreement with previously reported results. A theoretical boundary between cellular and dendritic growth conditions was derived and compared with experiments. The unique wetting characteristics of the monotectic alloys can be utilized to tailor the interface structure in metal matrix composites. Metal matrix composites with monotectic and hypermonotectic Al-In matrices were made by pressure infiltration, remelted and directionally solidified to observe the wetting characteristics of the alloys as well as the effect on structure of solidification in the constrained field of the fiber interstices. Models for monotectic growth are modified to take into account solidification in these constrained fields.

Evaluation of Primary Dendrite Arm Spacings from Aluminum-7wt% Silicon alloys Directionally Solidified aboard the International Space Station - Comparison with Theory

NASA Technical Reports Server (NTRS)

Angart, Samuel; Lauer, Mark; Poirier, David; Tewari, Surendra; Rajamure, Ravi; Grugel, Richard

2015-01-01

Aluminum – 7wt% silicon alloys were directionally solidified in the microgravity environment aboard the International Space Station as part of the “MIcrostructure Formation in CASTing of Technical Alloys under Diffusive and Magnetically Controlled Convective Conditions” (MICAST) European led program. Cross-sections of the sample during periods of steady-state growth were metallographically prepared from which the primary dendrite arm spacing (lambda 1) was measured. These spacings were found to be in reasonable agreement with the Hunt-Lu model which assumes a diffusion-controlled, convectionless, environment during controlled solidification. Deviation from the model was found and is attributed to gravity-independent thermocapillary convection where, over short distances, the liquid appears to have separated from the crucible wall.

Structure-property relationships in directionally solidified single crystal NiAl

NASA Technical Reports Server (NTRS)

Noebe, R. D.; Kim, J. T.; Gibala, R.

1987-01-01

The ordered intermetallic alloy NiAl is being considered as a potential high temperature structural material, but lack of ductility at ambient temperatures, especially in polycrystalline form, is presently a major obstacle in achieving this goal. Even general agreement of the intrinsic ductility that can be achieved in monocrystals is in dispute. In order to understand this problem, two directionally solidified ingots of NiAl which displayed known differences in ductility were characterized in sufficient detail to identify the corresponding microstructural differences. It was found that the type and size of casting defects, i.e., porosity, present in the material were the major factors in controlling ductility of NiAl single crystals and could explain the order of magnitude variance in fracture strains reported in the literature.

Numerical Simulation of Transport Phenomena for a Double-Layer Laser Powder Deposition of Single-Crystal Superalloy

NASA Astrophysics Data System (ADS)

Liu, Zhaoyang; Qi, Huan

2014-04-01

A turbine blade made of single-crystal superalloys has been commonly used in gas turbine and aero engines. As an effective repair technology, laser powder deposition has been implemented to restore the worn turbine blade tips with a near-net shape capability and highly controllable solidified microstructure. Successful blade repair technology for single-crystal alloys requires a continuous epitaxial grain growth in the same direction of the crystalline orientation of the substrate material to the newly deposited layers. This work presents a three-dimensional numerical model to simulate the transport phenomena for a multilayer coaxial laser powder deposition process. Nickel-based single-crystal superalloy Rene N5 powder is deposited on a directional solidified substrate made of nickel-based directional-solidified alloy GTD 111 to verify the simulation results. The effects of processing parameters including laser power, scanning speed, and powder feeding rate on the resultant temperature field, fluid velocity field, molten pool geometric sizes, and the successive layer remelting ratios are studied. Numerical simulation results show that the maximum temperature of molten pool increases over layers due to the reduced heat dissipation capacity of the deposited geometry, which results in an increased molten pool size and fluid flow velocity at the successive deposited layer. The deposited bead geometry agrees well between the simulation and the experimental results. A large part of the first deposition layer, up to 85 pct of bead height, can be remelted during the deposition of the second layer. The increase of scanning speed decreases the ratio of G/ V (temperature gradient/solidification velocity), leading to an increased height ratio of the misoriented grain near the top surface of the previous deposited layer. It is shown that the processing parameters used in the simulation and experiment can produce a remelting ratio R larger than the misoriented grain height ratio S, which enables remelting of all the misoriented grains and guarantees a continuous growth of the substrate directional-solidified crystalline orientation during the multilayer deposition of single-crystal alloys.

Effect of Microstructure on Creep in Directionally Solidified NiAl-31Cr-3Mo

NASA Technical Reports Server (NTRS)

Whittenberger, J. Daniel; Raj, S. V.; Locci, I. E.

2001-01-01

The 1200 to 1400 K slow strain rate characteristics of the directionally solidified (DS) eutectic Ni-33Al-31Cr-3 Mo have been determined as a function of growth rate. While differences in the light optical level microstructure were observed in alloys grown at rates ranging from 7.6 to 508 mm/h, compression testing indicated that all had essentially the same strength. The exception was Ni-33 Al-31Cr-3Mo DS at 25.4 mm/h which was slightly stronger than the other growth velocities; no microstructural reason could be found for this improvement. Comparison of the approximately 1300 K properties revealed that four different DS NiAl-34(Cr,Mo) alloys have a similar creep resistance which suggests that there is a common, but yet unknown, strengthening mechanism.

Evaluation of the MICAST #2-12 AI-7wt%Si Sample Directionally Solidified Aboard the International Space Station

NASA Technical Reports Server (NTRS)

Tewari, Surendra N.; Ghods, Masoud; Angart, Samuel G.; Lauer, Mark; Grugel, Richard N.; Poirier, David R.

2016-01-01

The US team of the European led "MIcrostructure Formation in CASTing of Technical Alloys under Diffusive and Magnetically Controlled Convective Conditions" (MICAST) program recently received a third Aluminum - 7wt% silicon alloy that was processed in the microgravity environment aboard the International Space Station. The sample, designated MICAST#2-12, was directionally solidified in the Solidification with Quench Furnace (SQF) at a constant rate of 40micometers/s through an imposed temperature gradient of 31K/cm. Procedures taken to evaluate the state of the sample prior to sectioning for metallographic analysis are reviewed and rational for measuring the microstructural constituents, in particular the primary dendrite arm spacing (Lambda (sub1)), is given. The data are presented, put in context with the earlier samples, and evaluated in view of a relevant theoretical model.

Cost/benefit studies of advanced materials technologies for future aircraft turbine engines: Materials for advanced turbine engines

NASA Technical Reports Server (NTRS)

Stearns, M.; Wilbers, L.

1982-01-01

Cost benefit studies were conducted on six advanced materials and processes technologies applicable to commercial engines planned for production in the 1985 to 1990 time frame. These technologies consisted of thermal barrier coatings for combustor and high pressure turbine airfoils, directionally solidified eutectic high pressure turbine blades, (both cast and fabricated), and mixers, tail cones, and piping made of titanium-aluminum alloys. A fabricated titanium fan blisk, an advanced turbine disk alloy with improved low cycle fatigue life, and a long-life high pressure turbine blade abrasive tip and ceramic shroud system were also analyzed. Technologies showing considerable promise as to benefits, low development costs, and high probability of success were thermal barrier coating, directionally solidified eutectic turbine blades, and abrasive-tip blades/ceramic-shroud turbine systems.

Effect of Microstructure on Creep in Directionally Solidified NiAl-31Cr-3Mo

NASA Technical Reports Server (NTRS)

Whittenberger, J. D.; Raj, S. V.; Locci, I. E.

2001-01-01

The 1200 to 1400 K slow strain rate characteristics of the directionally solidified (DS) eutectic Ni-33Al-31Cr-3 Mo have been determined as a function of growth rate. While differences in the light optical level microstructure were observed in alloys grown at rates ranging from 7.6 to 508 mm/h, compression testing indicated that all had essentially the same strength. The exception was Ni-33Al-31Cr-3Mo DS at 25.4 mm/h which was slightly stronger than the other growth velocities; no microstructural reason could be found for this improvement. Comparison of the approx. 1300 K properties revealed that four different DS NiAl-34(Cr,Mo) alloys have a similar creep resistance which suggests that there is a common, but yet unknown, strengthening mechanism.

Effect of swaging on the 1000 C compressive slow plastic flow characteristics of the directionally solidified eutectic alloy gamma/gamma prime-alpha

NASA Technical Reports Server (NTRS)

Whittenberger, J. D.; Wirth, G.

1983-01-01

Swaging between 750 and 1050 C has been investigated as a means to introduce work into the directionally solidified eutectic alloy gamma/gamma prime-alpha (Ni-32.3 wt percent Mo-6.3 wt percent Al) and increase the elevated temperature creep strength. The 1000 C slow plastic compressive flow stress-strain rate properties in air of as-grown, annealed, and worked nominally 10 and 25 percent materials have been determined. Swaging did not improve the slow plastic behavior. In fact large reductions tended to degrade the strength and produced a change in the deformation mechanism from uniform flow to one involving intense slip band formation. Comparison of 1000 C tensile and compressive strength-strain rate data reveals that deformation is independent of the stress state.

Differential Thermal Analysis of Hg(1-x)Mn(x)Te Alloys in the X=0 to 0.3 Range

NASA Technical Reports Server (NTRS)

Price, M. W.; Scripa, R. N.; Szofran, F. R.; Lehoczky, S. L.; Su, C-H

1998-01-01

Understanding the experimental conditions necessary for the development of radial and axial compositional homogeneity in directionally solidified Hg(0.89)Mn(0.11)Te(MMT) crystals has been difficult due to the lack of segregation coefficient data on the Hg(1-x)Mn(x)Te alloy system in the X = 0 to 0.3 composition range. Determining segregation coefficient data from the available Hg(1-x)Mn(x)Te alloy phase equilibria data is not practical due to discrepancies in the shape of the reported solidus and liquidus curves in the X = 0 to 0.3 range. To resolve these discrepancies and to obtain segregation coefficient data which can be used to understand homogeneity in directionally solidified MMT crystals, the solidus and liquidus temperatures of seven Hg(1-x)Mn(x)Te alloys in the X = 0 to 0.3 range were determined using differential thermal analysis (DTA). The Hg(1-x)Mn(x)Te phase diagram constructed for the X = 0 to 0.3 range of this alloy system from the DTA measurements clarifies the shape of the solidus and liquidus curves in this range. The segregation coefficient for the Hg(1-x)Mn(x)Te system was found to vary from 5 to 4.4 as the solidus composition increased from 0-30 atomic percent MnTe. This information will be useful in the analysis of axial and radial homogeneity of directionally solidified MMT crystals.

Printing low-melting-point alloy ink to directly make a solidified circuit or functional device with a heating pen

PubMed Central

Wang, Lei; Liu, Jing

2014-01-01

A new method to directly print out a solidified electronic circuit through low-melting-point metal ink is proposed. A functional pen with heating capability was fabricated. Several typical thermal properties of the alloy ink Bi35In48.6Sn16Zn0.4 were measured and evaluated. Owing to the specifically selected melting point of the ink, which is slightly higher than room temperature, various electronic devices, graphics or circuits can be manufactured in a short period of time and then rapidly solidified by cooling in the surrounding air. The liquid–solid phase change mechanism of the written lines was experimentally characterized using a scanning electron microscope. In order to determine the matching substrate, wettability between the metal ink Bi35In48.6Sn16Zn0.4 and several materials, including mica plate and silicone rubber, was investigated. The resistance–temperature curve of a printed resistor indicated its potential as a temperature control switch. Furthermore, the measured reflection coefficient of a printed double-diamond antenna accords well with the simulated result. With unique merits such as no pollution, no requirement for encapsulation and easy recycling, the present printing approach is an important supplement to current printed electronics and has enormous practical value in the future. PMID:25484611

Printing low-melting-point alloy ink to directly make a solidified circuit or functional device with a heating pen.

PubMed

Wang, Lei; Liu, Jing

2014-12-08

A new method to directly print out a solidified electronic circuit through low-melting-point metal ink is proposed. A functional pen with heating capability was fabricated. Several typical thermal properties of the alloy ink Bi 35 In 48.6 Sn 16 Zn 0.4 were measured and evaluated. Owing to the specifically selected melting point of the ink, which is slightly higher than room temperature, various electronic devices, graphics or circuits can be manufactured in a short period of time and then rapidly solidified by cooling in the surrounding air. The liquid-solid phase change mechanism of the written lines was experimentally characterized using a scanning electron microscope. In order to determine the matching substrate, wettability between the metal ink Bi 35 In 48.6 Sn 16 Zn 0.4 and several materials, including mica plate and silicone rubber, was investigated. The resistance-temperature curve of a printed resistor indicated its potential as a temperature control switch. Furthermore, the measured reflection coefficient of a printed double-diamond antenna accords well with the simulated result. With unique merits such as no pollution, no requirement for encapsulation and easy recycling, the present printing approach is an important supplement to current printed electronics and has enormous practical value in the future.

Effects of Undercooling and Cooling Rate on Peritectic Phase Crystallization Within Ni-Zr Alloy Melt

NASA Astrophysics Data System (ADS)

Lü, P.; Wang, H. P.

2018-04-01

The liquid Ni-16.75 at. pct Zr peritectic alloy was substantially undercooled and containerlessly solidified by an electromagnetic levitator and a drop tube. The dependence of the peritectic solidification mode on undercooling was established based on the results of the solidified microstructures, crystal growth velocity, as well as X-ray diffraction patterns. Below a critical undercooling of 124 K, the primary Ni7Zr2 phase preferentially nucleates and grows from the undercooled liquid, which is followed by a peritectic reaction of Ni7Zr2+L → Ni5Zr. The corresponding microstructure is composed of the Ni7Zr2 dendrites, peritectic Ni5Zr phase, and inter-dendritic eutectic. Nevertheless, once the liquid undercooling exceeds the critical undercooling, the peritectic Ni5Zr phase directly precipitates from this undercooled liquid. However, a negligible amount of residual Ni7Zr2 phase still appears in the microstructure, indicating that nucleation and growth of the Ni7Zr2 phase are not completely suppressed. The micromechanical property of the peritectic Ni5Zr phase in terms of the Vickers microhardness is enhanced, which is ascribed to the transition of the peritectic solidification mode. To suppress the formation of the primary phase completely, this alloy was also containerlessly solidified in free fall experiments. Typical peritectic solidified microstructure forms in large droplets, while only the peritectic Ni5Zr phase appears in smaller droplets, which gives an indication that the peritectic Ni5Zr phase directly precipitates from the undercooled liquid by completely suppressing the growth of the primary Ni7Zr2 phase and the peritectic reaction due to the combined effects of the large undercooling and high cooling rate.

Lamellar boundary alignment of DS-processed TiAl-W alloys by a solidification procedure

NASA Astrophysics Data System (ADS)

Jung, In-Soo; Oh, Myung-Hoon; Park, No-Jin; Kumar, K. Sharvan; Wee, Dang-Moon

2007-12-01

In this study, a β solidification procedure was used to align the lamellae in a Ti-47Al-2W (at.%) alloy parallel to the growth direction. The Bridgman technique and the floating zone process were used for directional solidification. The mechanical properties of the directionally solidified alloy were evaluated in tension at room temperature and at 800°C. At a growth rate of 30 mm/h (with the floating zone approach), the lamellae were well aligned parallel to the growth direction. The aligned lamellae yielded excellent room temperature tensile ductility. The tensile yield strength at 800°C was similar to that at room temperature. The orientation of the γ lamellar laths in the directionally solidified ingots, which were manufactured by means of a floating zone process, was identified with the aid of electron backscattered diffraction analysis. On the basis of this analysis, the preferred growth direction of the bcc-β dendrites that formed at high temperatures close to the melting point was inferred to be [001]β at a growth rate of 30 mm/h and [111]β at a growth rate of 90 mm/h.

Sub-mm Jet Properties of the X-Ray Binary Swift J1745-26

NASA Astrophysics Data System (ADS)

Tetarenko, A. J.; Sivakoff, G. R.; Miller-Jones, J. C. A.; Curran, P. A.; Russell, T. D.; Coulson, I. M.; Heinz, S.; Maitra, D.; Markoff, S. B.; Migliari, S.; Petitpas, G. R.; Rupen, M. P.; Rushton, A. P.; Russell, D. M.; Sarazin, C. L.

2015-05-01

We present the results of our observations of the early stages of the 2012-2013 outburst of the transient black hole X-ray binary (BHXRB), Swift J1745-26, with the Very Large Array, Submillimeter Array, and James Clerk Maxwell telescope (SCUBA-2). Our data mark the first multiple-band mm and sub-mm observations of a BHXRB. During our observations the system was in the hard accretion state producing a steady, compact jet. The unique combination of radio and mm/sub-mm data allows us to directly measure the spectral indices in and between the radio and mm/sub-mm regimes, including the first mm/sub-mm spectral index measured for a BHXRB. Spectral fitting revealed that both the mm (230 GHz) and sub-mm (350 GHz) measurements are consistent with extrapolations of an inverted power law from contemporaneous radio data (1-30 GHz). This indicates that, as standard jet models predict, a power law extending up to mm/sub-mm frequencies can adequately describe the spectrum, and suggests that the mechanism driving spectral inversion could be responsible for the high mm/sub-mm fluxes (compared to radio fluxes) observed in outbursting BHXRBs. While this power law is also consistent with contemporaneous optical data, the optical data could arise from either jet emission with a jet spectral break frequency of {{ν }break}≳ 1× {{10}14} Hz or the combination of jet emission with a lower jet spectral break frequency of {{ν }break}≳ 2× {{10}11} Hz and accretion disk emission. Our analysis solidifies the importance of the mm/sub-mm regime in bridging the crucial gap between radio and IR frequencies in the jet spectrum, and justifies the need to explore this regime further.

Assessment of phase constitution on the Al-rich region of rapidly solidified Al-Co-Fe-Cr alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolf, W., E-mail: witorw@gmail.com

The formation of quasicrystalline approximants in rapidly solidified Al-Co-Fe-Cr alloys was investigated. Alloys of atomic composition Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8}, Al{sub 77}Co{sub 11}Fe{sub 6}Cr{sub 6} and Al{sub 76}Co{sub 19}Fe{sub 4}Cr{sub 1} were produced using melt spinning and arc melting methods and their microstructural characterization was carried out by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Up to the present there is no consensus in the literature regarding the formation of quasicrystalline phase or quasicrystalline approximants in the Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8} alloy. This work presents, for the first time, a detailed structural characterization of selected alloysmore » in the Al-Co-Fe-Cr system close to the atomic composition Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8}. The results indicated the samples to be composed, mostly, by two intermetallic phases, which are quaternary extensions of Al{sub 5}Co{sub 2} and Al{sub 13}Co{sub 4} and are quasicrystalline approximants. Although the Al{sub 5}Co{sub 2} phase has already been reported in the Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8} alloy, the presence of the monoclinic Al{sub 13}Co{sub 4} is now identified for the first time in the as cast state. In the binary Al-Co system a quasicrystalline phase is known to form in a rapidly solidified alloy with composition close to the monoclinic and orthorhombic Al{sub 13}Co{sub 4} phases. This binary quasicrystalline phase presents an average valence electron per atom (e/a) between 1.7 and 1.9; thus, in addition to the Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8} alloy, the compositions Al{sub 77}Co{sub 11}Fe{sub 6}Cr{sub 6} and Al{sub 76}Co{sub 19}Fe{sub 4}Cr{sub 1} were chosen to be within the region of formation of the quaternary extension of the Al{sub 13}Co{sub 4} phase and also within the (e/a) of 1.7 to 1.9. However, no quasicrystalline phase is present in any of the studied alloys. The Al-Co-Fe-Cr system, around the compositions studied, is composed of quaternary extensions of Al-Co intermetallic phases, which present solubility of Fe and Cr at Co atomic sites. - Highlights: •The Al rich region of the AlCoFeCr system is studied concerning phase formation on rapidly solidified alloys. •The alloys were composed mostly by quaternary extensions of Al-Co intermetallic phases. •Al{sub 5}Co{sub 2} and Al{sub 13}Co{sub 4} were the major phases observed in the alloys and are approximants of a quasicrystalline phase. •No quasicrystalline phase was observed in the Al{sub 71}Co{sub 13}Fe{sub 8}Cr{sub 8} composition.« less

Metal Matrix Composites Directionally Solidified

NASA Astrophysics Data System (ADS)

Ares, Alicia Esther; Schvezov, Carlos Enrique

The present work is focus on studying the dendritic solidification of metal matrix composites, MMCs, (using zinc-aluminum, ZA, alloys as matrix and the addition of SiC and Al2O3 particles). The compounds were obtained by as-cast solidification, under continuous stirring and in a second stage were directionally solidified in order to obtain different dendritic growth (columnar, equiaxed and columnar-to-equiaxed transition (CET)). The results in MMCs were compared with those obtained in directional solidification of ZA alloys, primarily with regard to structural parameters. The size and evolution of microstructure, according to the size of the MMCs particles and the variation of the thermal parameters was analyzing. In general it was found that the size of the microstructure (secondary dendritic spacing) decreases with the increase of particles in the matrix. When cooling rate increases, particle size decreases, and a higher cooling rate causes finer and more homogeneous dendrites Also, the segregation which was found in the matrix of the composites was significantly less than in the case of ZA alloys.

Resistivity Distribution of Multicrystalline Silicon Ingot Grown by Directional Solidification

NASA Astrophysics Data System (ADS)

Sun, S. H.; Tan, Y.; Dong, W.; Zhang, H. X.; Zhang, J. S.

2012-06-01

The effects of impurities on the resistivity distribution and polarity of multicrystalline silicon ingot prepared by directional solidification were investigated in this article. The shape of the equivalence line of the resistivity in the vertical and cross sections was determined by the solid-liquid interface. Along the solidification height of silicon ingot, the conductive type changed from p-type in the lower part of the silicon ingot to n-type in the upper part of the silicon ingot. The resistivity in the vertical section of the silicon ingot initially increased along the height of the solidified part, and reached its maximum at the polarity transition position, then decreased rapidly along the height of solidified part and approached zero on the top of the ingot because of the accumulation of impurities. The variation of resistivity in the vertical section of the ingot has been proven to be deeply relevant to the distribution of Al, B, and P in the growth direction of solidification.

Partial melting of a Pb-Sn mushy layer due to heating from above, and implications for regional melting of Earth's directionally solidified inner core

NASA Astrophysics Data System (ADS)

Yu, James; Bergman, Michael I.; Huguet, Ludovic; Alboussiere, Thierry

2015-09-01

Superimposed on the radial solidification of Earth's inner core may be hemispherical and/or regional patches of melting at the inner-outer core boundary. Little work has been carried out on partial melting of a dendritic mushy layer due to heating from above. Here we study directional solidification, annealing, and partial melting from above of Pb-rich Sn alloy ingots. We find that partial melting from above results in convection in the mushy layer, with dense, melted Pb sinking and resolidifying at a lower height, yielding a different density profile than for those ingots that are just directionally solidified, irrespective of annealing. Partial melting from above causes a greater density deeper down and a corresponding steeper density decrease nearer the top. There is also a change in microstructure. These observations may be in accordance with inferences of east-west and perhaps smaller-scale variations in seismic properties near the top of the inner core.

Directional growth and characterization of Fe?Al?Nb eutectic alloys

NASA Astrophysics Data System (ADS)

Mota, M. A.; Coelho, A. A.; Bejarano, J. M. Z.; Gama, S.; Caram, R.

1999-03-01

The manufacturing of components for operation at high temperatures requires the use of metallic materials which can keep satisfactory mechanical and chemical properties, even at temperatures beyond 1000°C. An interesting alternative to solve such a problem is the use of directionally solidified eutectic alloys. A potentially promising system for the manufacture of structural materials, and so far not totally studied, is the eutectic based on the Fe-Al-Nb system, which involves the (FeAl) 2Nb phase and the FeAl solid solution. Eutectic samples from this system were directionally solidified in a vertical Bridgman crystal growth unit. The objective of the experiments was to determine the influence of the growth rate on the eutectic microstructure. The ingots obtained were investigated by using optical and electron scanning microscopy. At low growth rate, the eutectic microstructure remained regular, even though it showed several types of microstructure defects. As the growth rate was increased, a transition from lamellar to fibrous morphology was observed.

SPAR X Technical Report for Experiment 76-22 Directional Solidification of Magnetic Composites

NASA Technical Reports Server (NTRS)

Bethin, J.

1984-01-01

The effects of gravity on Bridgman-Stockbarger directional solidification of off-eutectic Bi/MnBi were studied in reduced gravity aboard the SPAR X flight and compared to normal-gravity investigations and previous eutectic Bi/MnBi SPAR flight experiments. The directional solidification of off-eutectic Bi/MnBi results in either a dendritic structure connected with local cooperative growth or a coupled low volume fraction faceted/non faceted aligned rod eutectic whose Mn macrosegregation, MnBi rod size, interrod spacing, and thermal and magnetic properties are sensitive functions of the solidification processing conditions. Two hypoeutectic and two hypereutectic samples were solidified during 605 sec of furnace travel, with an initial 265 sec low-gravity interval. Comparison Earth-gravity samples were solidified in the same furance assembly under identical processing conditions. Macrosegregation in the low-g samples was consistent with a metastable increase in Mn solubility in the Bi matrix, in partial agreement with previous Bi/MnBi SPAR findings of MnBi volume reduction.

Paleomagnetic evidence for dynamo activity driven by inward crystallisation of a metallic asteroid

NASA Astrophysics Data System (ADS)

Bryson, James F. J.; Weiss, Benjamin P.; Harrison, Richard J.; Herrero-Albillos, Julia; Kronast, Florian

2017-08-01

The direction in which a planetary core solidifies has fundamental implications for the feasibility and nature of dynamo generation. Although Earth's core is outwardly solidifying, the cores of certain smaller planetary bodies have been proposed to inwardly solidify due to their lower central pressures. However, there have been no unambiguous observations of inwardly solidified cores or the relationship between this solidification regime and planetary magnetic activity. To address this gap, we present the results of complimentary paleomagnetic techniques applied to the matrix metal and silicate inclusions within the IVA iron meteorites. This family of meteorites has been suggested to originate from a planetary core that had its overlaying silicate mantle removed by collisions during the early solar system. This process is thought to have produced a molten ball of metal that cooled rapidly and has been proposed to have inwardly solidified. Recent thermal evolution models of such a body predict that it should have generated an intense, multipolar and time-varying dynamo field. This field could have been recorded as a remanent magnetisation in the outer, cool layers of a solid crust on the IVA parent core. We find that the different components in the IVA iron meteorites display a range of paleomagnetic fidelities, depending crucially on the cooling rate of the meteorite. In particular, silicate inclusions in the quickly cooled São João Nepomuceno meteorite are poor paleomagnetic recorders. On the other hand, the matrix metal and some silicate subsamples from the relatively slowly cooled Steinbach meteorite are far better paleomagnetic recorders and provide evidence of an intense (≳100 μT) and directionally varying (exhibiting significant changes on a timescale ≲200 kyr) magnetic field. This is the first demonstration that some iron meteorites record ancient planetary magnetic fields. Furthermore, the observed field intensity, temporal variability and dynamo lifetime are consistent with thermal evolution models of the IVA parent core. Because the acquisition of remanent magnetisation by some IVA iron meteorites require that they cooled below their Curie temperature during the period of dynamo activity, the magnetisation carried by Steinbach also provides strong evidence favouring the inward solidification of its parent core.

Analysis of Radial Segregation in Directionally Solidified Hg(0.89)Mn(0.11)Te

NASA Technical Reports Server (NTRS)

Price, M. W.; Scripa, R. N.; Szofran, F. R.; Motakef, S.; Hanson, B.

2003-01-01

Bridgman growth experiments were performed on Hg(0.89)Mn(0.11)Te (MMT) to determine the extent of radial Manganese segregation during directional solidification. MMT crystals were directionally solidified at rates of 0.09 and 0.18 p d s and in axial thermal gradients of 83 and 68"C/cm. Wavelength Dispersive Spectroscopy (WDS) and Fourier Transform Infra-Red (FTIR) analytical techniques were used to determine the radial homogeneity in all boules and the deflection of the solid-liquid interface (SLI) in two boules that were rapidly quenched after 5 to 6 cm of directional solidification. For all growth runs, the measured radial coinpositional variations were on the order of 0.01 molar percent MnTe in the steady state region of growth. Comparison of the measured radial compositional results of the crystals to predicted values in the diffusion-limited regime indicate a strong influence of convection near the solid-liquid interface. This conclusion is supported by the weak influence of the translation rates and axial thermal gradients utilized in this study upon radial compositional homogeneity.

Thermosolutal convection during cellular arrayed growth of Pb-Sn alloys

NASA Technical Reports Server (NTRS)

Tewari, S. N.; Shah, Rajesh; Chopra, M. A.

1993-01-01

Thermosolutal convection caused by the solute build up ahead of the growing arrays of cells and dendrites results in macrosegregation along the length of the Pb-Sn alloy (10 to 58 wt pct Sn) specimens when they are directionally solidified in a positive thermal gradient (melt on top, solid below, and gravity pointing down). At a constant thermal gradient, the extent of macrosegregation increases with decreasing growth speed as the microstructure changes from dendritic, to cellular and to planar. An empirical parameter, effective partition coefficient, obtained from the dependence of the longitudinal macrosegregation on fraction distance solidified can be used to represent the extent of macrosegregation.

Analysis of Residual Acceleration Effects on Transport and Segregation During Directional Solidification of Tin-Bismuth in the MEPHISTO Furnace Facility

NASA Technical Reports Server (NTRS)

Alexander J. Iwan D. (Principal Investigator)

1996-01-01

The objective of this work is to approach the problem of determining the transport conditions (and effects of residual acceleration) during the plane-front directional solidification of a tin-bismuth alloy under low gravity conditions. The work involves using a combination of 2- and 3-D numerical models, scaling analyses, ID models and the results of ground-based and low-gravity experiments. The latter are to be conducted during the MEPHISTO experiment scheduled for USMP-3 in early 1996. The models will be used to predict the response of the transport conditions and consequent solute segregation in directionally solidifying tin-bismuth melt. Real-time Seebeck voltage variations across a Sn-Bi melt during directional solidification in MEPHISTO on USMP-1 show a distinct variation which can be correlated with thruster firings. The Seebeck voltage measurement is related to the response of the instantaneous average melt composition at the melt-solid interface. This allows a direct comparison of numerical simulations with the Seebeck signals obtained on USMP-1. The effects of such accelerations on composition for a directionally solidifying Sn-Bi alloy have been simulated numerically. USMP-1 acceleration data was used to assist in our choice of acceleration magnitude and orientation. The results show good agreement with experimental observations. The USMP-3 experiments took place earlier this year (February 22 through March 6). There were several differences between the USMP-3 experiments as compared to USMP-1. Firstly a more concentrated alloy was solidified and, secondly, Primary Reaction Control System thruster burns were requested at particular times during four separate growth runs. This allowed us to monitor the response Seebeck response under well-characterized growth conditions. In addition, we carried out simulations during the experiment in order to interpret the Seebeck signal. Preliminary results are described here.

Analysis and calculation of macrosegregation in a casting ingot, exhibits C and E

NASA Technical Reports Server (NTRS)

Poirier, D. R.; Maples, A. L.

1984-01-01

A computer model which describes the solidification of a binary metal alloy in an insulated rectangular mold with a temperature gradient is presented. A numerical technique, applicable to a broad class of moving boundary problems, was implemented therein. The solidification model described is used to calculate the macrosegregation within the solidified casting by coupling the equations for liquid flow in the solid/liquid or mushy zone with the energy equation for heat flow throughout the ingot and thermal convection in the bulk liquid portion. The rate of development of the solid can be automatically calculated by the model. Numerical analysis of such solidification parameters as enthalpy and boundary layer flow is displayed. On-line user interface and software documentation are presented.

The Rene 150 directionally solidified superalloy turbine blades, volume 1

NASA Technical Reports Server (NTRS)

Deboer, G. J.

1981-01-01

Turbine blade design and analysis, preliminary Rene 150 system refinement, coating adaptation and evaluation, final Rene 150 system refinement, component-test blade production and evaluation, engine-test blade production, and engine test are discussed.

Directionally solidified Eu doped CaF2/Li3AlF6 eutectic scintillator for neutron detection

NASA Astrophysics Data System (ADS)

Kamada, Kei; Hishinuma, Kousuke; Kurosawa, Shunsuke; Shoji, Yasuhiro; Pejchal, Jan; Ohashi, Yuji; Yokota, Yuui; Yoshikawa, Akira

2015-12-01

Eu doped CaF2/Li3AlF6 eutectics were grown by μ-PD method. The directionally solidified eutectic with well-aligned 600 nm diameter Eu:CaF2 scintillator fibers surrounded with Li3AlF6 was prepared. The grown eutectics showed an emission peak at 422 nm ascribed to Eu2+ 4f-5d transition from Eu:CaF2 scintillation fiber. Li concentration in the Eu:CaF2-Li3AlF6 eutectic is around 0.038 mol/cm3,which is two times higher than that of LiCaAlF6 single crystal (0.016 mol/cm3). The light yield of Eu:CaF2-Li3AlF6 eutectic was around 7000 ph/neutron. The decay time was about 550 ns (89%) and 1450 ns (11%).

Transparent metal model study of the use of a cellular growth front to form aligned monotectic composite materials

NASA Technical Reports Server (NTRS)

Kaukler, William F.

1988-01-01

The purpose of this work was to resolve a scientific controversy in the understanding of how second phase particles become aligned during unidirectional growth of a monotectic alloy. A second aspect was to make the first systematic observations of the solidification behavior of a monotectic alloy during cellular growth in-situ. This research provides the first systematic transparent model study of cellular solidification. An interface stability diagram was developed for the planar to cellular transition of the succinonitrile glycerol (SNG) system. A method was developed utilizing Fourier Transform Infrared Spectroscopy which allows quantitative compositional analysis of directionally solidified SNG along the growth axis. To determine the influence of cellular growth front on alignment for directionally solidified monotectic alloys, the planar and cellular growth morphology was observed in-situ for SNG between 8 and 17 percent glycerol and for a range of over two orders of magnitude G/R.

Effect of Growth Rate on Elevated Temperature Plastic Flow and Room Temperature Fracture Toughness of Directionally Solidified NiAl-31Cr-3Mo

NASA Technical Reports Server (NTRS)

Whittenberger, J. Daniel; Raj, S. V.; Locci, I. E.; Salem, J. A.

1999-01-01

The eutectic system Ni-33Al-31Cr-3Mo was directionally solidified at rates ranging from 7.6 to 508 mm/h. Samples were examined for microstructure and alloy chemistry, compression tested at 1200 and 1300 K, and subjected to room temperature fracture toughness measurements. Lamellar eutectic grains were formed at 12.7 mm/h; however cellular structures with a radial eutectic pattern developed at faster growth rates. Elevated temperature compression testing between 10(exp -4) to 10(exp -7)/s did not reveal an optimum growth condition, nor did any single growth condition result in a significant fracture toughness advantage. The mechanical behavior, taken together, suggests that Ni-33Al-31Cr-3Mo grown at rates from 25.4 to 254 mm/h will have nominally equivalent properties.

Longitudinal shear behavior of several oxide dispersion strengthened alloys

NASA Technical Reports Server (NTRS)

Glasgow, T. K.

1978-01-01

Two commercial oxide dispersion strengthened (ODS) alloys, MA-753 and MA-754, and three experimental ODS alloys, MA-757E, MA-755E, and MA-6000E, were tested in shear at 760 C. Comparisons were made with other turbine blade and vane alloys. All of the ODS alloys exhibited less shear strength than directionally solidified Mar-M 200 = Hf or then conventionally cast B-1900. The strongest ODS alloy tested, MA-755E, was comparable in both shear and tensile strength to the lamellar directionally solidified eutectic alloy gamma/gamma prime - delta. Substantial improvements in shear resistance were found for all alloys tested when the geometry of the specimen was changed from one generating a transverse tensile stress in the shear area to one generating a transverse compressive stress. Finally, 760 C shear strength as a fraction of tensile strength was found to increase linearly with the log of the transverse tensile ductility.

Progress in advanced high temperature materials technology

NASA Technical Reports Server (NTRS)

Freche, J. C.; Ault, G. M.

1976-01-01

Significant progress has recently been made in many high temperature material categories pertinent to such applications by the industrial community. These include metal matrix composites, superalloys, directionally solidified eutectics, coatings, and ceramics. Each of these material categories is reviewed and the current state-of-the-art identified, including some assessment, when appropriate, of progress, problems, and future directions.

The effect of tantalum on the structure/properties of two polycrystalline nickel-base superalloys: B-1900 + Hf MAR-M247. M.S. Thesis, Final Report

NASA Technical Reports Server (NTRS)

Janowski, G. M.

1985-01-01

The microstructure, phase compositions, and phase fractions were studied in conventionally cast B-1900 + Hf and both conventionally cast and directionally solidified MAR-M247 as a function of tantalum concentration. The hot tensile and creep rupture properties of the solutionized and aged MAR-M247-type alloys were also determined as a function of tantalum level. The effects of tantalum on the microstructure and phase compositions of B-1900 + Hf and MAR-M247 (conventionally cast and directionally solidified) were found to be very similar. The addition of tantalum to the as cast and heat treated alloys was shown to cause the partial replacement of the Hf in the MC carbides by Ta, although the degree of replacement was decreased by the solutionizing and aging heat treatment. The gamma prime and minor phase fractions (primarily MC type carbides) both increased approximately linearly with tantalum concentration. The gamma prime phase compositions were relatively insensitive to tantalum variations with the exception of the tantalum and/or hafnium levels. Bulk tantalum additions increased the tantalum, chromium, and cobalt levels of the gamma phase in both alloy series. The increase in the concentrations of the latter two elements in the gamma phase was a result of the decrease in the gamma phase fraction with increasing bulk tantalum concentration and constant gamma/gamma prime partitioning ratio. Tantalum additions increased the yield stress and ultimate tensile strength of the directionally solidified MAR-M247 type alloys and had no significant effect on ductility.

Use of Microgravity to Control the Microstructure of Eutectics

NASA Technical Reports Server (NTRS)

Wilcox, William R.; Regel, Liya L.; Smith, Reginald W.

1998-01-01

This grant began in June of 1996. Its long term goal is to be able to control the microstructure of directionally solidified eutectic alloys, through an improved understanding of the influence of convection. The primary objective of the present projects is to test hypotheses for the reported influence of microgravity on the microstructure of three fibrous eutectics (MnBi-Bi, InSb-NiSb, Al3Ni-Al). A secondary objective is to determine the influence of convection on the microstructure of other eutectic alloys. Two doctoral students and a masters student supported as a teaching assistant were recruited for this research. Techniques were developed for directional solidification of MnBi-Bi eutectics with periodic application of current pulses to produce an oscillatory freezing rate. Image analysis techniques were developed to obtain the variation in MnBi fiber spacing, which was found to be normally distributed. The mean and standard deviation of fiber spacing were obtained for several freezing conditions. Eighteen ampoules were prepared for use in the gradient freeze furnace QUELD developed at Queen's University for use in microgravity. Nine of these ampoules will be solidified soon at Queen's in a ground-based model. We hope to solidify the other nine in the QUELD that is mounted on the Canadian Microgravity Isolation Mount on MIR. Techniques are being developed for directional solidification of the Al-Si eutectic at different freezing rates, with and without application of accelerated crucible rotation to induce convection. For the first time, theoretical methods are being developed to analyze eutectic solidification with an oscillatory freezing rate. In a classical sharp-interface model, we found that an oscillatory freezing rate increases the deviation of the average interfacial composition from the eutectic, and increases the undercooling of the two phases by different amounts. This would be expected to change the volume fraction solidifying and the fiber spacing. Because of difficulties in tracking the freezing interfaces of the two solid phases, a phase-field model is also being developed. A paper demonstrating application of phase field methods to periodic structures has been submitted for publication.

Immiscible phase incorporation during directional solidification of hypermonotectics

NASA Technical Reports Server (NTRS)

Andrews, J. Barry; Merrick, Roger A.

1993-01-01

Solidification processes in immiscible samples were investigated by directly observing the events taking place at the solid-liquid interface during directional solidification. Visualization of these events was made possible through the use of a transparent metal analog system and a temperature gradient stage assembly fitted to an optical microscope. The immiscible transparent analog system utilized was the succinonitrile-glycerol system. This system has been shown to exhibit the same morphological transitions as observed in metallic alloys of monotectic composition. Both monotectic and hypermonotectic composition samples were directionally solidified in order to gain an improved understanding of the manner in which the excess hypermonotectic liquid is incorporated into the solidifying structure. The processing conditions utilized prevented sedimentation of the excess hypermonotectic liquid by directionally solidifying the samples in very thin (13 microns), horizontally oriented cells. High thermal gradient to growth rate ratios (G/R) were used in an effort to prevent constitutional supercooling and the subsequent formation of L(sub 2) droplets in advance of the solidification front during the growth of fibrous composite structures. Results demonstrated that hypermonotectic composites could be produced in samples up to two weight percent off of the monotectic composition by using a G/R ratio greater than or equal to 4.6 x 10(exp 4) C(s)/mm(sup 2) to avoid constitutional supercooling. For hypermonotectic samples processed with G/R ratios below 4.6 x 10(exp 4) C(s)/mm(sup 2), constitutional supercooling occurred and resulted in slight interfacial instability. For these samples, two methods of incorporation of the hypermonotectic liquid were observed and are reported. The correlation between the phase spacing, lambda, and the growth rate, R, was examined and was found to obey a relationship generally associated with a diffusion controlled coupled growth process. For samples with compositions ranging from the monotectic composition up to 2 percent off of the monotectic composition, data indicated that the square of the phase spacing (lambda) varied linearly with the inverse of the growth rate (R).

Numerical modeling of crystal growth in Bridgman device

NASA Astrophysics Data System (ADS)

Vompe, Dmitry Aleksandrovich

1997-12-01

The standard model for the growth of a crystal from a pure substance or diluted binary mixture contains transport equations for heat and phase change conditions at the solidification front. A numerical method is constructed for simulations of crystal growth in a vertical Bridgman device. The method is based on a boundary fitting technique in which melted and solidified regions are mapped onto a fixed rectangular logical domain. The Alternating Directions scheme (ADI) is used to treat the diffusive terms implicitly, with explicit methods are used for the remaining terms in the mapped temperature equations with variable coefficients. The nonlinear equation for the solid/liquid interface motion is solved by the modified Euler technique. Results obtained from the calculations have been used to study the influence of various boundary conditions imposed on the sidewalls and the top and bottom of the ampoule. Conditions are identified that lead to a steadily growing crystal and results are compared with an asymptotic one- dimensional model. Criteria based on ampoule length and boundary conditions being derived and compared with a previously developed one-dimensional model. Various cases have been considered to determine conditions for maintaining a nearly flat interface. It was found that the interface amplitude can be decreased by a factor of 100 (even 1,000) by optimizing temperature boundary conditions.

Secondary arm coarsening and microsegregation in superalloy PWA-1480 single crystals: Effect of low gravity

NASA Technical Reports Server (NTRS)

Vijayakumar, M.; Tewari, S. N.; Lee, J. E.; Curreri, P. A.

1990-01-01

Single crystal specimens of nickel base superalloy PWA-1480 were directionally solidified on ground and during low gravity (20 sec) and high gravity (90 sec) parabolic maneuver of KC-135 aircraft. Thermal profiles were measured during solidification by two in-situ thermocouples positioned along the sample length. The samples were quenched during either high or low gravity cycles so as to freeze the structures of the mushy zone developing under different gravity levels. Microsegregation was measured by examining the solutal profiles on several transverse cross-sections across primary dendrites along their length in the quenched mushy zone. Effect of gravity level on secondary arm coarsening kinetics and microsegregation have been investigated. The results indicate that there is no appreciable difference in the microsegregation and coarsening kinetics behavior in the specimens grown under high or low gravity. This suggests that short duration changes in gravity/levels (0.02 to 1.7 g) do not influence convection in the interdendritic region. Examination of the role of natural convection, in the melt near the primary dendrite tips, on secondary arm spacings requires low gravity periods longer than presently available on KC-135. Secondary arm coarsening kinetics show a reasonable fit with the predictions from a simple analytical model proposed by Kirkwood for a binary alloy.

Direct mechanical dispersion and in vitro culture of fusiform rust fungus single basidiospores

Treesearch

Alex M. Diner

1999-01-01

Single basidiospores of Cronartium quercuum f. sp. fusiforme were cast from telia suspended over a solidified nutritional medium affixed to an operating orbital shaker. Spores thus mechanically dispersed and isolated, germinated to develop single-genotype colonies.

The effect of growth rate on the compositional variations in directionally solidified Hg(1-x)CdsubxSe

NASA Technical Reports Server (NTRS)

Andrews, R. N.

1986-01-01

Several Hg1-xCdxSe crystals of composition x = 0.2 were grown in a bridgman-type directional solidification furnace at varying translation rates. The influence of growth rate on both the longitudinal and radial compositional uniformity for the crystals was determined using density measurements and infrared transmission-edge mapping.

Convection and macrosegregation in Al-19Cu alloy directionally solidified through an abrupt contraction in cross-section: A comparison with Al-7Si

NASA Astrophysics Data System (ADS)

Ghods, M.; Lauer, M.; Grugel, R. N.; Tewari, S. N.; Poirier, D. R.

2017-02-01

Hypoeutectic Al-19 wt. % Cu alloys were directionally solidified in cylindrical molds that featured an abrupt cross-section decrease 9.5 to 3.2 mm in diameter). Thermo-solutal convection and cross-section-change-induced shrinkage flow effects on macrosegregation were investigated. Dendrite clustering and extensive radial macrosegregation was seen, particularly in the larger cross-section before contraction. This alloy shows positive longitudinal macrosegregation near the contraction followed by negative macrosegregation right after it; the extent of macrosegregation, however, decreases with increasing growth speed. The degree of thermo-solutal convection was compared to another study investigating directional solidification of Al-7 wt. % Si [1] in order to study the effect of solutal expansion coefficient on macrosegregation. An interesting change of the radial macrosegregation profile, attributable to the area-change-induced-shrinkage flow, was observed very close to the contraction. A two-dimensional model accounting for both shrinkage and thermo-solutal convection was used to simulate solidification, the resulting steepling as well as axial and radial macrosegregation. The experimentally observed macrosegregation associated with the contraction during directional solidification was well predicted by the numerical simulations.

The effect of grain size and cement content on index properties of weakly solidified artificial sandstones

NASA Astrophysics Data System (ADS)

Atapour, Hadi; Mortazavi, Ali

2018-04-01

The effects of textural characteristics, especially grain size, on index properties of weakly solidified artificial sandstones are studied. For this purpose, a relatively large number of laboratory tests were carried out on artificial sandstones that were produced in the laboratory. The prepared samples represent fifteen sandstone types consisting of five different median grain sizes and three different cement contents. Indices rock properties including effective porosity, bulk density, point load strength index, and Schmidt hammer values (SHVs) were determined. Experimental results showed that the grain size has significant effects on index properties of weakly solidified sandstones. The porosity of samples is inversely related to the grain size and decreases linearly as grain size increases. While a direct relationship was observed between grain size and dry bulk density, as bulk density increased with increasing median grain size. Furthermore, it was observed that the point load strength index and SHV of samples increased as a result of grain size increase. These observations are indirectly related to the porosity decrease as a function of median grain size.

Use of direct washing of chemical dispense nozzle for defect control

NASA Astrophysics Data System (ADS)

Linnane, Michael; Mack, George; Longstaff, Christopher; Winter, Thomas

2006-03-01

Demands for continued defect reduction in 300mm IC manufacturing are driving process engineers to examine all aspects of the chemical apply process for improvement. Historically, the defect contribution from photoresist apply nozzles has been minimized through a carefully controlled process of "dummy dispenses" to keep the photoresist in the tip "fresh" and remove any solidified material, a preventive maintenance regime involving periodic cleaning or replacing of the nozzles, and reliance on a pool of solvent within the nozzle storage block to keep the photoresist from solidifying at the nozzle tip. The industry standard has worked well for the most part but has limitations in terms of cost effectiveness and absolute defect elimination. In this study, we investigate the direct washing of the chemical apply nozzle to reduce defects seen on the coated wafer. Data is presented on how the direct washing of the chemical dispense nozzle can be used to reduce coating related defects, reduce material costs from the reduction of "dummy dispense", and can reduce equipment downtime related to nozzle cleaning or replacement.

Bulk undercooling

NASA Technical Reports Server (NTRS)

Kattamis, T. Z.

1984-01-01

Bulk undercooling methods and procedures will first be reviewed. Measurement of various parameters which are necessary to understand the solidification mechanism during and after recalescence will be discussed. During recalescence of levitated, glass-encased large droplets (5 to 8 mm diam) high speed temperature sensing devices coupled with a rapid response oscilloscope are now being used at MIT to measure local thermal behavior in hypoeutectic and eutectic binary Ni-Sn alloys. Dendrite tip velocities were measured by various investigators using thermal sensors or high speed cinematography. The confirmation of the validity of solidification models of bulk-undercooled melts is made difficult by the fineness of the final microstructure, the ultra-rapid evolution of the solidifying system which makes measurements very awkward, and the continuous modification of the microstructure which formed during recalescence because of precipitation, remelting and rapid coarsening.

Evaluation of directionally solidified eutectic superalloys for turbine blade applications

NASA Technical Reports Server (NTRS)

Henry, M. E.; Jackson, M. R.; Walter, J. L.

1978-01-01

Alloys from the following systems were selected for property evaluation: (1) gamma/gamma-Mo (Ni-base, rods of Mo); (2) gamma-beta (Ni-base, lamellae or rods of (Ni, Fe/Co Al); and (3) gamma-gamma (Ni-base rods of Ni3Al gamma). The three alloys were subjected to longitudinal and transverse tensile and rupture tests from 750 C to 1100 C, longitudinal shear strength was measured at several temperatures, resistance to thermal cycling to 1150 C was determined, cyclic oxidation resistance was evaluated at 750 C and 1100 C, and each system was directionally solidified in an alumina shell mold turbine shape to evaluate mold/metal reactivity. The gamma/gamma Mo system has good rupture resistance, transverse properties and processability, and is a high potential system for turbine blades. The gamma-beta system has good physical properties and oxidation resistance, and is a potential system for turbine vanes. The gamma-gamma system has good high temperature rupture resistance and requires further exploratory research.

Radial macrosegregation and dendrite clustering in directionally solidified Al-7Si and Al-19Cu alloys

NASA Astrophysics Data System (ADS)

Ghods, M.; Johnson, L.; Lauer, M.; Grugel, R. N.; Tewari, S. N.; Poirier, D. R.

2016-05-01

Hypoeutectic Al-7 wt% Si and Al-19 wt% Cu alloys were directionally solidified upward in a Bridgman furnace through a range of constant growth speeds and thermal gradients. Though processing is thermo-solutally stable, flow initiated by gravity-independent advection at, slightly leading, central dendrites moves rejected solute out ahead and across the advancing interface. Here any lagging dendrites are further suppressed which promotes a curved solid-liquid interface and the eventual dendrite "clustering" seen in transverse sections (dendrite "steepling" in longitudinal orientations) as well as extensive radial macrosegregation. Both aluminum alloys showed considerable macrosegregation at the low growth speeds (10 and 30 μm s-1) but not at higher speed (72 μm s-1). Distribution of the fraction eutectic-constituent on transverse sections was determined in order to quantitatively describe radial macrosegregation. The convective mechanisms leading to dendrite-steepling were elucidated with numerical simulations, and their results compared with the experimental observations.

Effect of grain orientation and coating on thermal fatigue resistance of a directionally solidified superalloy (MAR-M 247)

NASA Technical Reports Server (NTRS)

Bizon, P. T.; Dreshfield, R. L.; Calfo, F. D.

1979-01-01

The effect of off-axis directionally solidified (DS) grain growth on thermal fatigue life of Mar-M 247 alloy was evaluated. Uncoated conventionally cast as well as DS wedge bars were cycled in a burner rig between 1070 C and room temperature. The longitudinal axis and leading edge of the specimen coincided. As the angle between the specimen longitudinal axis and growth axis increased, the thermal fatigue life decreased for both the uncoated and aluminide-coated bars. Life increases of about 50 cycles for the DS conditions were attributed to coating. The decrease in thermal fatigue life with increasing angle is primarily attributed to the increase in modulus of elasticity with increasing angle and not to the intersection of DS grain boundaries with the specimen leading edge. The thermal fatigue cracks were observed to be transgranular in the DS material. Limited tensile and stress-rupture properties of conventionally cast and off-axis DS Mar-M 247 alloy are also presented.

Microstructural Response of Directionally Solidified René 80 Superalloy to Gas-Tungsten Arc Welding

NASA Astrophysics Data System (ADS)

Sidhu, R. K.; Ojo, O. A.; Chaturvedi, M. C.

2009-01-01

The microstructural response of directionally solidified René 80 (DS René 80) superalloy to gas-tungsten-arc (GTA) welding was investigated. Rapid heating during welding resulted in a significant grain-boundary liquation of solid-state reaction product γ' precipitates, intergranular elemental segregation induced M5B3 borides, and secondary solidification constituents MC carbides and sulfocarbides, which were all present in the preweld heat-treated alloy. Liquation of these particles embrittled the grain boundaries in the heat-affected zone (HAZ) and caused microfissuring along the liquated grain boundaries. Nevertheless, contrary to the generally observed increase in HAZ cracking in superalloys with an increase in Ti and Al concentration, due to increase in the alloy’s hardness, significantly reduced cracking was observed in DS René 80 compared to the conventionally cast IN738 welded under the same conditions, despite its hardness being higher than that of IN738. This was related to the nature of base-metal grain- boundary intersections at the fusion-zone boundary in these materials.

On oscillatory microstructure during cellular growth of directionally solidified Sn–36at.%Ni peritectic alloy

PubMed Central

Peng, Peng; Li, Xinzhong; Li, Jiangong; Su, Yanqing; Guo, Jingjie

2016-01-01

An oscillatory microstructure has been observed during deep-cellular growth of directionally solidified Sn–36at.%Ni hyperperitectic alloy containing intermetallic compounds with narrow solubility range. This oscillatory microstructure with a dimension of tens of micrometers has been observed for the first time. The morphology of this wave-like oscillatory structure is similar to secondary dendrite arms, and can be observed only in some local positions of the sample. Through analysis such as successive sectioning of the sample, it can be concluded that this oscillatory microstructure is caused by oscillatory convection of the mushy zone during solidification. And the influence of convection on this oscillatory microstructure was characterized through comparison between experimental and calculations results on the wavelength. Besides, the change in morphology of this oscillatory microstructure has been proved to be caused by peritectic transformation during solidification. Furthermore, the melt concentration increases continuously during solidification of intermetallic compounds with narrow solubility range, which helps formation of this oscillatory microstructure. PMID:27066761

On oscillatory microstructure during cellular growth of directionally solidified Sn-36at.%Ni peritectic alloy.

PubMed

Peng, Peng; Li, Xinzhong; Li, Jiangong; Su, Yanqing; Guo, Jingjie

2016-04-12

An oscillatory microstructure has been observed during deep-cellular growth of directionally solidified Sn-36at.%Ni hyperperitectic alloy containing intermetallic compounds with narrow solubility range. This oscillatory microstructure with a dimension of tens of micrometers has been observed for the first time. The morphology of this wave-like oscillatory structure is similar to secondary dendrite arms, and can be observed only in some local positions of the sample. Through analysis such as successive sectioning of the sample, it can be concluded that this oscillatory microstructure is caused by oscillatory convection of the mushy zone during solidification. And the influence of convection on this oscillatory microstructure was characterized through comparison between experimental and calculations results on the wavelength. Besides, the change in morphology of this oscillatory microstructure has been proved to be caused by peritectic transformation during solidification. Furthermore, the melt concentration increases continuously during solidification of intermetallic compounds with narrow solubility range, which helps formation of this oscillatory microstructure.

Thermal fatigue and oxidation data of superalloys including directionally solidified eutectics

NASA Technical Reports Server (NTRS)

Hill, V. L.; Humphreys, V. E.

1977-01-01

Thermal fatigue and oxidation data were obtained on 61 specimens, representing 15 discrete alloy compositions or fabricating techniques and three coating systems. Conventionally fabricated alloys included V57, MM 200, Rene 77, Rene 125, MM 246, MM 509, IN-738, IN-792 + Hf, and MM 200 + Hf. The directionally solidified alloys were MM 200, MM 200 single crystal, MM 200 bicrystal, cellular gamma/gamma' - delta) and lamellar gamma/gamma' - delta. The coatings systems included NiCrAlY on IN-738, In-792 + Hf, MM 200 DS, MM 200 DS single crystal, and cellular gamma/gamma' - delta and NiCrAlY/Pt on lamellar gamma/gamma' - delta. Crack initiation survival rates were recorded for all alloys, with and without coatings. All uncoated alloys, except MM 509, exhibited significant oxidation weight loss in 75,000 to 15,000 cycles. MM 509 specimens had weight losses only slightly higher than coated specimens through 7,500 cycles. All coated specimens had low weight loss.

Effects of leachate concentration on the integrity of solidified clay liners.

PubMed

Xue, Qiang; Zhang, Qian

2014-03-01

This study aimed to evaluate the impact of landfill leachate concentration on the degradation behaviour of solidified clay liners and to propose a viable mechanism for the observed degradation. The results indicated that the unconfined compressive strength of the solidified clay decreased significantly, while the hydraulic conductivity increased with the leachate concentration. The large pore proportion in the solidified clay increased and the sum of medium and micro pore proportions decreased, demonstrating that the effect on the solidified clay was evident after the degradation caused by exposure to landfill leachate. The unconfined compressive strength of the solidified clay decreased with increasing leachate concentration as the leachate changed the compact structure of the solidified clay, which are prone to deformation and fracture. The hydraulic conductivity and the large pore proportion of the solidified clay increased with the increase in leachate concentration. In contrast, the sum of medium and micro pore proportions showed an opposite trend in relation to leachate concentration, because the leachate gradually caused the medium and micro pores to form larger pores. Notably, higher leachate concentrations resulted in a much more distinctive variation in pore proportions. The hydraulic conductivity of the solidified clay was closely related to the size, distribution, and connection of pores. The proportion of the large pores showed a positive correlation with the increase of hydraulic conductivity, while the sum of the proportions of medium and micro pores showed a negative correlation.

Directionally Solidified Eutectic Ceramics for Multifunctional Aerospace Applications

DTIC Science & Technology

2013-01-01

eutectic materials development through a new initiative entitled Boride Eutectic Project. These results first time organize and populate materials...property databases, and utilize an iterative feedback routine to constantly improve the design process of the boride eutectics LaB6-MeB2 (Me = Zr, Hf, Ti

The Nature of the Microstructure and Interface Boundary Formation in Directionally Solidified Ceramic Boride Composites

DTIC Science & Technology

2011-05-01

failure resistance, which results from their different microplasticity (microbrittleness) and relaxation ability. In order to evaluate the... microplasticity (microbrittleness) in the series of isomorphic hexaborides produced by zone melting we have plotted a number of statistical curves that show

Method for producing metallic microparticles

DOEpatents

Phillips, Jonathan; Perry, William L.; Kroenke, William J.

2004-06-29

Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

Directional solidification at ultra-high thermal gradient

NASA Technical Reports Server (NTRS)

Flemings, M. C.; Lee, D. S.; Neff, M. A.

1980-01-01

A high gradient controlled solidification (HGC) furnace was designed and operated at gradients up to 1800 C/cm to continuously produce aluminum alloys. Rubber '0' rings for the water cooling chamber were eliminated, while still maintaining water cooling directly onto the solidified metal. An HGC unit for high temperature ferrous alloys was also designed. Successful runs were made with cast iron, at thermal gradients up to 500 C/cm.

Advanced Gradient Heating Facility (AGHF)

NASA Technical Reports Server (NTRS)

1998-01-01

This section of the publication includes papers entitled: (1) Coupled growth in hypermonotectics; (2) Directional solidification of refined Al-4 wt.% Cu alloys; (3) Effects of convection on interface curvature during growth of concentrated ternary compounds; (4) Directional solidification of Al-1.5 wt.% Ni alloys; (5) Interactive response of advancing phase boundaries to particles; (6) INTeractive Response of Advancing Phase boundaries to Particles-INTRAPP; and (7) Particle engulfment and pushing by solidifying interfaces.

Columnar-to-Equiaxed Transition and Equiaxed Grain Alignment in Directionally Solidified Ni3Al Alloy Under an Axial Magnetic Field

NASA Astrophysics Data System (ADS)

Liu, Huan; Xuan, Weidong; Xie, Xinliang; Li, Chuanjun; Wang, Jiang; Yu, Jianbo; Li, Xi; Zhong, Yunbo; Ren, Zhongming

2017-09-01

The effect of an axial magnetic field on the solidification structure in directionally solidified Ni-21.5Al-0.4Zr-0.1B (at. pct) alloy was investigated. The experimental results indicated that the application of a high magnetic field caused the deformation of dendrites and the occurrence of columnar-to-equiaxed transition (CET). The magnetic field tended to orient the 〈001〉 crystal direction of the equiaxed grains along the magnetic field direction. The bulk solidification experiment under a high magnetic field showed that the crystal exhibited magnetic crystalline anisotropy. Further, the thermoelectric (TE) magnetic force and TE magnetic convention were analyzed by three-dimensional (3-D) numerical simulations. The results showed that the maximum value of TE magnetic force localized in the vicinity of the secondary dendrite arm root, which should be responsible for the dendrite break and CET. Based on the high-temperature creep mechanism, a simple model was proposed to describe the magnetic field intensity needed for CET: B ≥ kG^{ - 1.5} R^{1.25} . The model is in good agreement with the experiment results. The experimental results should be attributed to the combined action of TE magnetic effects and the magnetic moment.

Effect of a weak transverse magnetic field on the microstructure in directionally solidified peritectic alloys

PubMed Central

Li, Xi; Lu, Zhenyuan; Fautrelle, Yves; Gagnoud, Annie; Moreau, Rene; Ren, Zhongming

2016-01-01

Effect of a weak transverse magnetic field on the microstructures in directionally solidified Fe-Ni and Pb-Bi peritectic alloys has been investigated experimentally. The results indicate that the magnetic field can induce the formation of banded and island-like structures and refine the primary phase in peritectic alloys. The above results are enhanced with increasing magnetic field. Furthermore, electron probe micro analyzer (EPMA) analysis reveals that the magnetic field increases the Ni solute content on one side and enhances the solid solubility in the primary phase in the Fe-Ni alloy. The thermoelectric (TE) power difference at the liquid/solid interface of the Pb-Bi peritectic alloy is measured in situ, and the results show that a TE power difference exists at the liquid/solid interface. 3 D numerical simulations for the TE magnetic convection in the liquid are performed, and the results show that a unidirectional TE magnetic convection forms in the liquid near the liquid/solid interface during directional solidification under a transverse magnetic field and that the amplitude of the TE magnetic convection at different scales is different. The TE magnetic convections on the macroscopic interface and the cell/dendrite scales are responsible for the modification of microstructures during directional solidification under a magnetic field. PMID:27886265

Formation of an 18R long-period stacking ordered structure in rapidly solidified Mg{sub 88}Y{sub 8}Zn{sub 4} alloy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garcés, Gerardo, E-mail: ggarces@cenim.csic.es

The formation of the long-period stacking ordered structure (LPSO) in a Mg{sub 88}Y{sub 8}Zn{sub 4}(at%) ribbon produced by melt spinning was studied using high energy X-ray synchrotron radiation diffraction during in-situ isochronal heating and transmission electron microscopy. The microstructure of the rapidly solidified ribbons is characterised by fine magnesium grains with yttrium and zinc in solid solution and primary 18R LPSO-phase segregated at grain boundaries. Using differential scanning calorimetry, a strong exothermal peak was observed around 300 °C which was associated with the development of the 18R-type LPSO-phase in the magnesium grains. The apparent activation energy calculated using the Kissingermore » model was 125 KJmol{sup −1} and it is related to simultaneous diffusion of Y and Zn through magnesium basal plane. - Highlights: •The formation of the LPSO phase in rapidly solidified ribbons was studied. •The formation of the 18R LPSO starts at around 300 °C. •LPSO formation have to steps: Stacking faults along basal plane and then growth of 18R structure along the c direction.« less

Macrosegregation During Re-melting and Holding of Directionally Solidified Al-7 wt.% Si Alloy in Microgravity

NASA Astrophysics Data System (ADS)

Lauer, M.; Ghods, M.; Angart, S. G.; Grugel, R. N.; Tewari, S. N.; Poirier, D. R.

2017-08-01

As-cast aluminum-7 wt.% ailicon alloy sample rods were re-melted and directionally solidified on Earth which resulted in uniform dendritically aligned arrays. These arrays were then partially back-melted through an imposed, and constant, temperature gradient in the microgravity environment aboard the International Space Station. The mushy zones that developed in the seed crystals were held for different periods prior to initiating directional solidification. Upon return, examination of the initial mushy-zone regions exhibited significant macrosegregation in terms of a solute-depleted zone that increased as a function of the holding time. The silicon (solute) content in these regions was measured on prepared longitudinal sections by electron microprobe analysis as well as by determining the fraction eutectic on several transverse sections. The silicon content was found to increase up the temperature gradient resulting in significant silicon concentration immediately ahead of the mushy-zone tips. The measured macrosegregation agrees well with calculations from a mathematical model developed to simulate the re-melting and holding process. The results, due to processing in a microgravity environment where buoyancy and thermosolutal convection are minimized, serve as benchmark solidification data.

Effect of Multi-Scale Thermoelectric Magnetic Convection on Solidification Microstructure in Directionally Solidified Al-Si Alloys Under a Transverse Magnetic Field

NASA Astrophysics Data System (ADS)

Li, Xi; Du, Dafan; Gagnoud, Annie; Ren, Zhongming; Fautrelle, Yves; Moreau, Rene

2014-11-01

The influence of a transverse magnetic field ( B < 1 T) on the solidification structure in directionally solidified Al-Si alloys was investigated. Experimental results indicate that the magnetic field caused macrosegregation, dendrite refinement, and a decrease in the length of the mushy zone in both Al-7 wt pct Si alloy and Al-7 wt pct Si-1 wt pct Fe alloys. Moreover, the application of the magnetic field is capable of separating the Fe-rich intermetallic phases from Al-7 wt pct Si-1 wt pct Fe alloy. Thermoelectric magnetic convection (TEMC) was numerically simulated during the directional solidification of Al-Si alloys. The results reveal that the TEMC increases to a maximum () when the magnetic field reaches a critical magnetic field strength (), and then decreases as the magnetic field strength increases further. The TEMC exhibits the multi-scales effects: the and values are different at various scales, with decreasing and increasing as the scale decreases. The modification of the solidification structure under the magnetic field should be attributed to the TEMC on the sample and dendrite scales.

Application of solidifiers for oil spill containment: A review.

PubMed

Motta, Fernanda L; Stoyanov, Stanislav R; Soares, João B P

2018-03-01

The need for new and/or improvement of existing oil spill remediation measures has increased substantially amidst growing public concern with the increased transportation of unconventional crudes, such as diluted bitumen products. Solidifiers may be a very good spill response measure to contain and mitigate the effects of oil discharge incidents, as these interact with the oil to limit hydrocarbon release into air and water, prevent it from adhering onto sediment and debris, and could allow for oil recovery and reuse. Solidifiers change the physical state of the spilled oil from liquid to a coherent mass by chemical interactions between the spilled oil and the solidifier. Currently, the use of solidifiers is limited to small spills near shorelines. To extend their use to large-scale spill containment operations, it is necessary to understand the mechanism of solidifier action and to establish consistent criteria for evaluation of their effectiveness. The research effort to date has been focused mainly on gelators and cross-linking agents, with particularly impressive advancements in the areas of phase-selective polymeric and small-molecule gelators. Substantial research efforts are needed to improve solidifier performance and integrate solidifiers as part of spill response procedures, particularly for acute oil spills involving unconventional petroleum products. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

BinCat: a Catalog of Nearby Binary Stars with Tools for Calculating Light-Leakage for Direct Imaging Missions

NASA Astrophysics Data System (ADS)

Holte, Elias Peter; Sirbu, Dan; Belikov, Ruslan

2018-01-01

Binary stars have been largely left out of direct imaging surveys for exoplanets, specifically for earth-sized planets in their star's habitable zone. Utilizing new direct imaging techniques brings us closer to being able to detect earth-like exoplanets around binary stars. In preparation for the upcoming WFIRST mission and other direct imaging-capable missions (HabEx, LUVIOR) it is important to understand the expected science yield resulting from the implementation of these imaging techniques. BinCat is a catalog of binary systems within 30 parsecs to be used as a target list for future direct imaging missions. There is a non-static component along with BinCat that allows researchers to predict the expected light-leakage between a binary component and its off-axis companion (a value critical to the aforementioned techniques) at any epoch. This is accomplished by using orbital elements from the Sixth Orbital Catalog to model the orbits of the binaries. The software was validated against the historical data used to generate the orbital parameters. When orbital information is unknown or the binaries are purely optical the proper motion of the pair taken from the Washington Double Star catalog is integrated in time to estimate expected light-leakage.

Tidal disruption of inclined or eccentric binaries by massive black holes

NASA Astrophysics Data System (ADS)

Brown, Harriet; Kobayashi, Shiho; Rossi, Elena M.; Sari, Re'em

2018-07-01

Binary stars that are on close orbits around massive black holes (MBHs) such as Sgr A* in the centre of the Milky Way are liable to undergo tidal disruption and eject a hypervelocity star. We study the interaction between such an MBH and circular binaries for general binary orientations and penetration depths (i.e. binaries penetrate into the tidal radius around the BH). We show that for very deep penetrators, almost all binaries are disrupted when the binary rotation axis is roughly oriented towards the BH or it is in the opposite direction. The surviving chance becomes significant when the angle between the binary rotation axis and the BH direction is between 0.15π and 0.85π. The surviving chance is as high as ˜20 per cent when the binary rotation axis is perpendicular to the BH direction. However, for shallow penetrators, the highest disruption chance is found in such a perpendicular case, especially in the prograde case. This is because the dynamics of shallow penetrators is more sensitive to the relative orientation of the binary and orbital angular momenta. We provide numerical fits to the disruption probability and energy gain at the BH encounter as a function of the penetration depth. The latter can be simply rescaled in terms of binary masses, their initial separation, and the binary-to-BH mass ratio to evaluate the ejection velocity of a binary members in various systems. We also investigate the disruption of coplanar, eccentric binaries by an MBH. It is shown that for highly eccentric binaries retrograde orbits have a significantly increased disruption probability and ejection velocities compared to the circular binaries.

Tidal Disruption of Inclined or Eccentric Binaries by Massive Black Holes

NASA Astrophysics Data System (ADS)

Brown, Harriet; Kobayashi, Shiho; Rossi, Elena M.; Sari, Re'em

2018-04-01

Binary stars that are on close orbits around massive black holes (MBH) such as Sgr A* in the centre of the Milky Way are liable to undergo tidal disruption and eject a hypervelocity star. We study the interaction between such a MBH and circular binaries for general binary orientations and penetration depths (i.e. binaries penetrate into the tidal radius around the BH). We show that for very deep penetrators, almost all binaries are disrupted when the binary rotation axis is roughly oriented toward the BH or it is in the opposite direction. The surviving chance becomes significant when the angle between the binary rotation axis and the BH direction is between 0.15π and 0.85π. The surviving chance is as high as ˜20% when the binary rotation axis is perpendicular to the BH direction. However, for shallow penetrators, the highest disruption chance is found in such a perpendicular case, especially in the prograde case. This is because the dynamics of shallow penetrators is more sensitive to the relative orientation of the binary and orbital angular momenta. We provide numerical fits to the disruption probability and energy gain at the the BH encounter as a function of the penetration depth. The latter can be simply rescaled in terms of binary masses, their initial separation and the binary-to-BH mass ratio to evaluate the ejection velocity of a binary members in various systems. We also investigate the disruption of coplanar, eccentric binaries by a MBH. It is shown that for highly eccentric binaries retrograde orbits have a significantly increased disruption probability and ejection velocities compared to the circular binaries.

Characterization of Solidifiers used for Oil Spill Remediation

EPA Science Inventory

The physical characteristics and chemical composition of oil spill solidifiers were studied, and correlation of these properties with product effectiveness enabled determination of characteristics that are desirable in a good solidifier. The analyses revealed that the commercial...

Converting optical scanning holograms of real objects to binary Fourier holograms using an iterative direct binary search algorithm.

PubMed

Leportier, Thibault; Park, Min Chul; Kim, You Seok; Kim, Taegeun

2015-02-09

In this paper, we present a three-dimensional holographic imaging system. The proposed approach records a complex hologram of a real object using optical scanning holography, converts the complex form to binary data, and then reconstructs the recorded hologram using a spatial light modulator (SLM). The conversion from the recorded hologram to a binary hologram is achieved using a direct binary search algorithm. We present experimental results that verify the efficacy of our approach. To the best of our knowledge, this is the first time that a hologram of a real object has been reconstructed using a binary SLM.

The influence of gravity level during directional solidification of immiscible alloys

NASA Technical Reports Server (NTRS)

Andrews, J. B.; Schmale, A. L.; Sandlin, A. C.

1992-01-01

During directional solidification of immiscible (hypermonotectic) alloys it is theoretically possible to establish a stable macroscopically-planar solidification front, and thus avoid sedimentation. Unfortunately, convective instabilities often occur which interfere with the directional solidification process. In this paper, stability conditions are discussed and results presented from directional solidification studies carried out aboard NASA's KC-135 zero-g aircraft. Samples were directionally solidified while the effective gravity level was varied from approximately 0.01 g for 25 s to 1.8 g for 45 s. Dramatic variations in microstructure were observed with gravity level during solidification.

Discovery of a Thorne-Żytkow object candidate in the Small Magellanic Cloud

NASA Astrophysics Data System (ADS)

Levesque, Emily M.; Massey, Philip; Żytkow, Anna N.; Morrell, Nidia

2015-01-01

Thorne-Żytkow objects (TŻOs) are a theoretical class of star in which a compact neutron star is surrounded by a large, diffuse envelope. Supergiant TŻOs are predicted to be almost identical in appearance to red supergiants (RSGs), with their very red colors and cool temperatures placing them at the Hayashi limit on the H-R diagram. The only features that can be used at present to distinguish TŻOs from the general RSG population are the unusually strong heavy-element and lithium lines present in their spectra. These elements are the unique products of the stars fully convective envelope linking the photosphere with the extraordinarily hot burning region in the vicinity of the neutron star core. We have recently discovered a TŻO candidate in the Small Magellanic Cloud. It is the first star to display the distinctive chemical profile of anomalous element enhancements thought to be characteristic of TŻOs however, up-to-date models and additional observable predictions (including potential asteroseismological signatures) are required to solidify this discovery. The definitive detection of a TŻO would provide the first direct evidence for a completely new model of stellar interiors, a theoretically predicted fate for massive binary systems, and never-before-seen nucleosynthesis processes that would offer a new channel for heavy-element and lithium production in our universe.

Direct-Sequence Spread Spectrum System

DTIC Science & Technology

1990-06-01

by directly modulating a conventional narrowband frequency-modulated (FM) carrier by a high rate digital code. The direct modulation is binary phase ...specification of the DSSS system will not be developed. The results of the evaluation phase of this research will be compared against theoretical...spread spectrum is called binary phase -shift keying 19 (BPSK). BPSK is a modulation in which a binary Ŕ" represents a 0-degree relative phase

Optimizing the Hot-Corrosion Resistance-of-Novel gamma-Ni+gamma-prime-Ni3A1-Based Alloys and Coatings

DTIC Science & Technology

2006-07-01

TBC benefit Substrale limit 1 1 0 0 ---------- .- -.. . . . . . . --- I single crystal S1000 conventlonally cest allos . .- alloy. E directionally...usually heat treated or processed) forms. Developments in casting technologies made it possible to produce directionally-solidified and single - crystal ...advanced single - crystal superalloys with improved strength meant reductions in chromium and silicon contents. The scale growth and spallation rates can be

Comparative thermal fatigue resistances of twenty-six nickel and cobalt base alloys

NASA Technical Reports Server (NTRS)

Bizon, P. T.; Spera, D. A.

1975-01-01

Thermal fatigue resistances were determined from fluidized bed tests. Cycles to cracking differed by almost three orders of magnitude for these materials with directional solidification and surface protection of definite benefit. The alloy-coating combination with the highest thermal fatigue resistance was directionally solidified NASA TAZ-8A with an RT-XP coating. It oxidation resistance was excellent, showing almost no weight change after 15 000 fluidized bed cycles.

Development Of A Magnetic Directional-Solidification Furnace

NASA Technical Reports Server (NTRS)

Aldrich, Bill R.; Lehoczky, Sandor L.

1996-01-01

Report describes development of directional-solidification furnace in which axial magnetic field is imposed by surrounding ring permanent magnets and/or electromagnets and pole pieces. Furnace provides controlled axial temperature gradients in multiple zones, through which ampoule containing sample of material to be solidified is translated at controlled speed by low-vibration, lead-screw, stepping-motor-driven mechanism. Intended for use in low-gravity (spaceflight) experiments on melt growth of high-purity semiconductor crystals.

RECENT TRENDS IN THE EDUCATION OF THE GIFTED.

ERIC Educational Resources Information Center

TANNENBAUM, ABRAHAM J.

RECENT TRENDS IN EDUCATION OF THE GIFTED ARE PRESENTED. PROVISIONS FOR GIFTED STUDENTS ARE TO CONTINUE AND EXPAND, HOWEVER EMPHASIS SHOULD BE SHIFTED FROM MERELY PROMOTING THE NEEDS OF THE GIFTED TO SOLIDIFYING THE GAINS ALREADY MADE IN THIS DIRECTION. ENRICHMENT BRINGS NEW DISCIPLINES INTO THE CURRICULUM, AND NEW COURSES ARE DEVELOPED IN SUCH…

Formation of highly preferred orientation of β-Sn grains in solidified Cu/SnAgCu/Cu micro interconnects under temperature gradient effect

NASA Astrophysics Data System (ADS)

Zhao, N.; Zhong, Y.; Dong, W.; Huang, M. L.; Ma, H. T.; Wong, C. P.

2017-02-01

β-Sn grain orientation and configuration are becoming crucial factors to dominate the lifetime of solder interconnects in three-dimensional integrated circuit packaging. In this paper, we found that a temperature gradient during solidification significantly dominated the orientation and configuration of the final β-Sn grains in Cu/SnAgCu/Cu micro interconnects. Being different from the random orientations and growth fronts meeting or cyclic twin boundary forming near the center after homogeneous temperature bonding, the β-Sn grains solidified under a certain temperature gradient were observed to follow a highly preferred orientation with their c-axis departing from the direction of temperature gradient by about 45°-88°. Meanwhile, these preferred oriented β-Sn grains consisted of low angle grain boundary structures with misorientation in the range of 0°-15°. The mechanism was explained in terms of the anisotropy and directional growth of β-Sn grains. The results pave the way for grain orientation control in 3D packaging technology.

Characterization of Solidifiers used for Oil Spill Remediation ...

EPA Pesticide Factsheets

The physical characteristics and chemical composition of oil spill solidifiers were studied, and correlation of these properties with product effectiveness enabled determination of characteristics that are desirable in a good solidifier. The analyses revealed that the commercial products were primarily comprised of organic polymers and a few trace elements. A natural sorbent, which was composed entirely of plant based matter, was also evaluated, and it had the highest oil removal capacity, but it did not produce a solid mat-like final product. Generally, solidifiers with a carbonate group, pore size greater than 5 µm, and bulk densities lower than 0.3 g cm-3 were found to have better efficiency and produced a cohesive rubbery final product that facilitated removal compared to sorbents. The importance of bulk density and pore size in the performance of the solidifier suggest that the primary mechanism of action was likely physical sorption. In this study, we focused on characterizing the 12 solidifiers by using different analytical techniques.

Effects of Microalloying on the Microstructures and Mechanical Properties of Directionally Solidified Ni-33(at.%)Al-31Cr-3Mo Eutectic Alloys Investigated

NASA Technical Reports Server (NTRS)

Whittenberger, J. Daniel; Raj, Sai V.; Locci, Ivan E.; Salem, Jonathan A.

2002-01-01

Despite nickel aluminide (NiAl) alloys' attractive combination of oxidation and thermophysical properties, their development as replacements for superalloy airfoils in gas turbine engines has been largely limited by difficulties in developing alloys with an optimum combination of elevated-temperature creep resistance and room-temperature fracture toughness. Alternatively, research has focused on developing directionally solidified NiAl-based in situ eutectic composites composed of NiAl and (Cr,Mo) phases in order to obtain a desirable combination of properties a systematic investigation was undertaken at the NASA Glenn Research Center to examine the effects of small additions of 11 alloying elements (Co, Cu, Fe, Hf, Mn, Nb, Re, Si, Ta, Ti, and Zr) in amounts varying from 0.25 to 1.0 at.% on the elevated-temperature strength and room-temperature fracture toughness of directionally solidified Ni-33Al-31Cr-3Mo eutectic alloy. The alloys were grown at 12.7 mm/hr, where the unalloyed eutectic base alloy exhibited a planar eutectic microstructure. The different microstructures that formed because of these fifth-element additions are included in the table. The additions of these elements even in small amounts resulted in the formation of cellular microstructures, and in some cases, dendrites and third phases were observed. Most of these elemental additions did not improve either the elevated-temperature strength or the room-temperature fracture toughness over that of the base alloy. However, small improvements in the compression strength were observed between 1200 and 1400 K when 0.5 at.% Hf and 0.25 at.% Ti were added to the base alloy. The results of this study suggest that the microalloying of Ni-33Al-31Cr-3Mo will not significantly improve either its elevatedtemperature strength or its room-temperature fracture toughness. Thus, any improvements in these properties must be acquired by changing the processing conditions.

Controlled Directional Solidification of Aluminum - 7 wt Percent Silicon Alloys: Comparison Between Samples Processed on Earth and in the Microgravity Environment Aboard the International Space Station

NASA Technical Reports Server (NTRS)

Grugel, Richard N.; Tewari, Surendra N.; Erdman, Robert G.; Poirier, David R.

2012-01-01

An overview of the international "MIcrostructure Formation in CASTing of Technical Alloys" (MICAST) program is given. Directional solidification processing of metals and alloys is described, and why experiments conducted in the microgravity environment aboard the International Space Station (ISS) are expected to promote our understanding of this commercially relevant practice. Microstructural differences observed when comparing the aluminum - 7 wt% silicon alloys directionally solidified on Earth to those aboard the ISS are presented and discussed.

Development of high temperature fasteners using directionally solidified eutectic alloys

NASA Technical Reports Server (NTRS)

George, F. D.

1972-01-01

The suitability of the eutectics for high temperature fasteners was investigated. Material properties were determined as a function of temperature, and included shear parallel and perpendicular to the growth direction and torsion parallel to it. Techniques for fabricating typical fastener shapes included grinding, creep forming, and direct casting. Both lamellar Ni3Al-Ni3Nb and fibrous (Co,Cr,Al)-(Cr,Co)7C3 alloys showed promise as candidate materials for high temperature fastener applications. A brief evaluation of the performance of the best fabricated fastener design was made.

Directionally Solidified Multifunctional Ceramics

DTIC Science & Technology

2006-12-01

Vidrio , Vol. 44 [5] (2005) pp 347 - 352. 9. F. W. Dynys and A. Sayir, "Self Assemble Silicide Architectures by Directional Solidification," Journal...Sociedad Espanola de Ceramica y Vidrio , Vol. 43 [4] (2004) pp 753 - 758. 21. A. Sayir and F. S. Lowery, "Combustion-Resistance of Silicon-Based Ceramics...Espafiola de Cerdmica y Vidrio , Vol. 43 [3], 2004. ISSN-0366-3175-BSCVB9. 14 37. P. Berger, A. Sayir and M. H. Berger, "Nuclear Microprobe using Elastic

Transient and diffusion analysis of HgCdTe

NASA Technical Reports Server (NTRS)

Clayton, J. C.

1982-01-01

Solute redistribution during directional solidification of HgCdTe is addressed. Both one-dimensional and two-dimensional models for solute redistribution are treated and model results compared to experiment. The central problem studied is the cause of radial inhomogeneities found in directionally solidified HgCdTe. A large scale gravity-driven interface instability, termed shape instability, is postulated to be the cause of radial inhomogeneities. Recommendations for future work, along with appropriate computer programs, are included.

On-site low level radwaste storage facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knauss, C.H.; Gardner, D.A.

1993-12-31

This paper will explore several storage and processing technologies that are available for the safe storage of low-level waste, their advantages and their limitations such that potential users may be able to determine which technology may be most appropriate for their particular application. Also, a brief discussion will be included on available types of shipping and disposal containers and waste forms for use in those containers when ready for ultimate disposal. For the purposes of this paper, the waste streams considered will be restricted to nuclear power plant wastes. Wastes that will be discussed are powdered and bead resins formore » cooling and reactor water clean-up, filter cartridges, solidified waste oils, and Dry Active Wastes (DAW), which consist of contaminated clothing, tools, respirator filters, etc. On-site storage methods that will be analyzed include a storage facility constructed of individual temporary shielded waste containers on a hard surface; an on-site, self contained low level radwaste facility for resins and filters; and an on-site storage and volume reduction facility for resins and filters; and an on-site DAW. Simple, warehouse-type buildings and pre-engineered metal buildings will be discussed only to a limited degree since dose rate projections can be high due to their lack of adequate shielding for radiation protection. Waste processing alternatives that will be analyzed for resins include dewatering, solidifying in Portland cement, solidifying in bituminous material, and solidifying in a vinyl ester styrene matrix. The storage methods describes will be analyzed for their ability to shield the populace from the effects of direct transmission and skyshine radiation when storing the above mentioned materials, which have been properly processed for storage and have been placed in suitable storage containers.« less

Benard convection in binary mixtures with Soret effects and solidification

NASA Technical Reports Server (NTRS)

Zimmermann, G.; Mueller, U.; Davis, S. H.

1992-01-01

Benard convection was studied in a two-component liquid which displayed Soret effects (Soret, 1879; DeGroot and Mazur, 1969) and in which the temperatures of the horizontal boundaries spanned the solidification temperature of the mixture. A steady basic state was observed, in which the layer is partly liquid (near the lower, heated plate) and partly solid (near the upper, cooled plate) with the interface being planar, and in which all transport is by conduction and diffusion. Linear stability of the basic state was examined to determine how the presence of solid and the ability of the material to solidify or melt under disturbance affects the critical conditions from the onset of instability. The theoretical results obtained for cases when the phase change is absent and when the Soret effects are absent (but the phase change is present) are compared with an experiment using alcohol-water mixtures.

Evolution of double white dwarf binaries undergoing direct-impact accretion: Implications for gravitational wave astronomy

NASA Astrophysics Data System (ADS)

Kremer, Kyle; Breivik, Katelyn; Larson, Shane L.; Kalogera, Vassiliki

2017-01-01

For close double white dwarf binaries, the mass-transfer phenomenon known as direct-impact accretion (when the mass transfer stream impacts the accretor directly rather than forming a disc) may play a pivotal role in the long-term evolution of the systems. In this analysis, we explore the long-term evolution of white dwarf binaries accreting through direct-impact and explore implications of such systems to gravitational wave astronomy. We cover a broad range of parameter space which includes initial component masses and the strength of tidal coupling, and show that these systems, which lie firmly within the LISA frequency range, show strong negative chirps which can last as long as several million years. Detections of double white dwarf systems in the direct-impact phase by detectors such as LISA would provide astronomers with unique ways of probing the physics governing close compact object binaries.

Partially melted zone in aluminum welds

NASA Astrophysics Data System (ADS)

Huang, Chen-Che

The partially melted zone (PMZ) is a region immediately outside the weld metal where grain boundary (GB) liquation can occur and cause intergranular cracking. Aluminum alloys are known to be susceptible to liquation and liquation cracking. The PMZ of alloy 2219 (essentially Al-6.3Cu) was studied. Liquation is initiated eutectically. Solidification of the GB liquid was directional---upward and toward the weld as a result of the temperature gradients across the PMZ. The liquated material solidifies with severe segregation into a low-strength, low-ductility structure consisting of a solute-depleted ductile phase and a solute-rich brittle eutectic. In tensile testing the maximum load and displacement before failure were both far below those of the base metal. The GB eutectic fractured while the adjacent Cu-depleted a deformed readily under tension. The solidification mode of the grain boundary liquid was mostly planar. However, cellular solidification was also observed near the bottom of partial-penetration welds, where temperature gradients were lowest. The liquation mechanisms in wrought multicomponent aluminum alloys during welding were also studied. Three mechanisms were identified. They cover most, if not all, wrought aluminum alloys. Liquation cracking in the PMZ was investigated in full-penetration aluminum welds. Liquation cracking occurs because the solidifying PMZ is pulled by a solidifying and thus contracting weld metal that is stronger than the PMZ. Liquation cracking can occur if there is significant liquation in the PMZ, if there is no solidification cracking in the adjacent weld metal, and if the PMZ becomes lower in solid fraction (and hence strength) during its terminal solidification than the solidifying weld metal. Liquation cracking in the PMZ was also investigated in partial-penetration aluminum welds. The papillary (nipple) type penetration common in welding with spray transfer of the filler wire actually oscillates along the weld and promotes cracking regardless of the filler metal used. The fast-solidifying weld metal immediately behind the penetration tip contracts and pulls the PMZ near the tip and, regardless of the weld-metal composition, cracking can occur if PMZ liquation is significant.

Generalized spin filtering and an improved derivative-sign binary image method for the extraction of fringe skeletons

NASA Astrophysics Data System (ADS)

Yu, Qifeng; Liu, Xiaolin; Sun, Xiangyi

1998-07-01

Generalized spin filters, including several directional filters such as the directional median filter and the directional binary filter, are proposed for removal of the noise of fringe patterns and the extraction of fringe skeletons with the help of fringe-orientation maps (FOM s). The generalized spin filters can filter off noise on fringe patterns and binary fringe patterns efficiently, without distortion of fringe features. A quadrantal angle filter is developed to filter off the FOM. With these new filters, the derivative-sign binary image (DSBI) method for extraction of fringe skeletons is improved considerably. The improved DSBI method can extract high-density skeletons as well as common density skeletons.

Turbine blade processing

NASA Technical Reports Server (NTRS)

1975-01-01

Space processing of directionally solidified eutectic-alloy type turbine blades is envisioned as a simple remelt operations in which precast blades are remelted in a preformed mold. Process systems based on induction melting, continuous resistance furnaces, and batch resistance furnaces were evaluated. The batch resistance furnace type process using a multiblade mold is considered to offer the best possibility for turbine blade processing.

Parameters of Solidifying Mixtures Transporting at Underground Ore Mining

NASA Astrophysics Data System (ADS)

Golik, Vladimir; Dmitrak, Yury

2017-11-01

The article is devoted to the problem of providing mining enterprises with solidifying filling mixtures at underground mining. The results of analytical studies using the data of foreign and domestic practice of solidifying mixtures delivery to stopes are given. On the basis of experimental practice the parameters of transportation of solidifying filling mixtures are given with an increase in their quality due to the effect of vibration in the pipeline. The mechanism of the delivery process and the procedure for determining the parameters of the forced oscillations of the pipeline, the characteristics of the transporting processes, the rigidity of the elastic elements of pipeline section supports and the magnitude of vibrator' driving force are detailed. It is determined that the quality of solidifying filling mixtures can be increased due to the rational use of technical resources during the transportation of mixtures, and as a result the mixtures are characterized by a more even distribution of the aggregate. The algorithm for calculating the parameters of the pipe vibro-transport of solidifying filling mixtures can be in demand in the design of mineral deposits underground mining technology.

Directional solidification of Al2-Cu-Al and Al3-Ni-Al eutectics during TEXUS rocket flight

NASA Technical Reports Server (NTRS)

Favier, J. J.; Degoer, J.

1984-01-01

One lamellar eutectic sample and one fiber-like eutectic sample were solidified directionally during the TEXUS-6 rocket flight. The microstructures and the results of the thermal analysis, obtained from the temperatures recorded on the cartridge skin, are compared. No appreciable modifications of the regularity of the eutectic structures were observed by passing from 1 g to 0.0001 g in these experiments. No steady state growth conditions were achieved in these experiments.

Thermal-stress fatigue behavior of twenty-six superalloys

NASA Technical Reports Server (NTRS)

Bizon, P. T.; Spera, D. A.

1976-01-01

The comparative thermal-stress fatigue resistances of 26 nickeland cobalt-base alloys were determined by fluidized bed tests. Cycles to cracking differed by almost three orders of magnitude for these materials, with directional solidification and surface protection showing definite benefit. The alloy-coating combination with the highest thermal-stress fatigue resistance was directionally solidified NASA TAZ-8A with an RT-SP coating. Its oxidation resistance was also excellent, showing approximately a 1/2 percent weight loss after 14,000 fluidized bed cycles.

Microstructural characteristics of Hadfield steel solidified under high pressure

NASA Astrophysics Data System (ADS)

Zhang, Yuzi; Li, Yanguo; Han, Bo; Zhang, Fucheng; Qian, Lihe

2011-12-01

Samples of Hadfield steel, high manganese austenite steel with 13 wt% manganese and 1.2 wt% carbon, were solidified under a pressure of 6 GPa. The microstructures of the samples were analyzed by metallography and X-ray diffraction. The results indicate that the solidification microstructure of the Hadfield steel was remarkably refined under high pressure. Additionally, the carbide of M23C6 was obtained in the Hadfield steel solidified under high pressure was different from the carbide of M3C obtained by solidification under normal pressure. Furthermore, high pressure promoted the formation of orientational solidified microstructure of the Hadfield steel.

Convective fractionation: A mechanism to provide cryptic zoning (macrosegregation), layering, crescumulates, banded tuffs and explosive volcanism in igneous processes

NASA Astrophysics Data System (ADS)

Rice, Alan

1981-01-01

A large array of igneous and volcanic features has characteristics that are recognized in other disciplines as conclusive and direct evidence of convvection in stratified and/or solidifying melts; e.g., macroscopic segregation (cryptic variation, zoning in magma chambers), mineral layering (in mafic intrusives), crescumulates (fingering) in the vertical and horizontal, banding (in pyroclastics), 'rollover' with attendant flashing of volatiles (explosive volcanism), etc. Some quantitative and qualitative aspect of convection in solidifying and or stratified melts (e.g., mineral layer widths such as are observed inl the Skaergaards) are examined to show consistency with field evidence. Convective fractionation does not possess the physical implausibilities of gravitational segregation (crystal settling). Neither is the field evidence as ambiguous if interpreted in terms of convective fractionation (which can explain amongst other things heavier material overlying lighter). Convective fractionation may operate on larger scales in the interior of planets.

Gasification of carbonaceous solids

DOEpatents

Coates, Ralph L.

1976-10-26

A process and apparatus for converting coal and other carbonaceous solids to an intermediate heating value fuel gas or to a synthesis gas. A stream of entrained pulverized coal is fed into the combustion stage of a three-stage gasifier along with a mixture of oxygen and steam at selected pressure and temperature. The products of the combustion stage pass into the second or quench stage where they are partially cooled and further reacted with water and/or steam. Ash is solidified into small particles and the formation of soot is suppressed by water/steam injections in the quench stage. The design of the quench stage prevents slag from solidifying on the walls. The products from the quench stage pass directly into a heat recovery stage where the products pass through the tube, or tubes, of a single-pass, shell and tube heat exchanger and steam is generated on the shell side and utilized for steam feed requirements of the process.

Compact seaweed growth of peritectic phase on confined, flat properitectic dendrites

NASA Astrophysics Data System (ADS)

Ludwig, A.; Mogeritsch, J.

2016-12-01

Peritectic alloys form a variety of different solidification morphologies at low growth rates. An alloy with a concentration that corresponds to the hyper-peritectic limit should show a cellular/dendritic solidification of the peritectic phase for growth velocities above the corresponding constitutional undercooling limit. However, due to nucleation retardation of the peritectic phase we observed growth of properitectic dendrites before cellular growth of the peritectic could established. The transition happened via an overgrowth of dendrites with a thin layer of peritectic phase. The observations were made using a transparent, metal-like solidifying peritectic system that was solidified directionally in thin samples. In the gap between the flat dendrites and the tubing walls, the peritectic phase grew with a compact seaweed morphology, whereas in the interdendritic spacing it formed small-curved bumps. At same distance behind the tip region, more and more polycrystalline-like objects appeared at the elongated traces of the compact seaweed morphology.

Characterization of solidifiers used for oil spill remediation.

PubMed

Sundaravadivelu, Devi; Suidan, Makram T; Venosa, Albert D; Rosales, Pablo I

2016-02-01

The physical characteristics and chemical composition of oil spill solidifiers were studied, and correlation of these properties with product effectiveness enabled determination of characteristics that are desirable in a good solidifier. The analyses revealed that the commercial products were primarily comprised of organic polymers and a few trace elements. A natural sorbent, which was composed entirely of plant based matter, was also evaluated, and it had the highest oil removal capacity, but it did not produce a solid mat-like final product. Generally, solidifiers with a carbonate group, pore size greater than 5 μm, and bulk densities lower than 0.3 g cm(-3) were found to have better efficiency and produced a cohesive rubbery final product that facilitated removal compared to sorbents. The importance of bulk density and pore size in the performance of the solidifier suggest that the primary mechanism of action was likely physical sorption. Copyright © 2015 Elsevier Ltd. All rights reserved.

An experimental study on dynamic response for MICP strengthening liquefiable sands

NASA Astrophysics Data System (ADS)

Han, Zhiguang; Cheng, Xiaohui; Ma, Qiang

2016-12-01

The technology of bio-grouting is a new technique for soft ground improvement. Many researchers have carried out a large number of experiments and study on this topic. However, few studies have been carried out on the dynamic response of solidified sand samples, such reducing liquefaction in sand. To study this characteristic of microbial-strengthened liquefiable sandy foundation, a microorganism formula and grouting scheme is applied. After grouting, the solidified samples are tested via dynamic triaxial testing to examine the cyclic performance of solidified sand samples. The results indicate that the solidified sand samples with various strengths can be obtained to meet different engineering requirements, the use of bacteria solution and nutritive salt is reduced, and solidified time is shortened to 1-2 days. Most importantly, in the study of the dynamic response, it is found that the MICP grouting scheme is effective in improving liquefiable sand characteristic, such as liquefaction resistance.

Microgravity

NASA Image and Video Library

1991-09-01

The Advanced Automated Directional Solidification Furnace (AADSF) flew during the USMP-2 mission. During USMP-2, the AADSF was used to study the growth of mercury cadmium telluride crystals in microgravity by directional solidification, a process commonly used on earth to process metals and grow crystals. The furnace is tubular and has three independently controlled temperature zones. The sample travels from the hot zone of the furnace (1600 degrees F) where the material solidifies as it cools. The solidification region, known as the solid/liquid interface, moves from one end of the sample to the other at a controlled rate, thus the term directional solidification.

Large structural, thin-wall castings made of metals subject to hot tearing, and their fabrication

NASA Technical Reports Server (NTRS)

Smashey, Russell W. (Inventor)

2001-01-01

An article, such as a gas turbine engine mixer, is made by providing a mold structure defining a thin-walled, hollow article, and a base metal that is subject to hot tear cracking when cast in a generally equiaxed polycrystalline form, such as Rene' 108 and Mar-M247. The article is fabricated by introducing the molten base metal into the mold structure, and directionally solidifying the base metal in the mold structure to form a directionally oriented structure. The directionally oriented structure may be formed of a single grain or oriented multiple grains.

Cleaner Landfills

NASA Technical Reports Server (NTRS)

2000-01-01

Osmotek, Inc. developed the Direct Osmosis treatment system through SBIR funding from Ames Research Center. Using technology originally developed for flight aboard the Space Station, the company brought it to their commercial water purification treatment system, Direct Osmosis. This water purification system uses a direct osmosis process followed by a reverse osmosis treatment. Because the product extracts water from a waste product, Osmotek is marketing the unit for use in landfills. The system can treat leachate (toxic chemicals leached into a water source), by filtering the water and leaving behind the leahcate. The leachate then becomes solidified into substance that can not seep into water.

Parametric Study to Determine the Effect of Temperature on Oil Solidifier Performance and the Development of a New Empirical Correlation for Predicting Effectiveness

EPA Science Inventory

Temperature can play a significant role in the efficacy of solidifiers in removing oil slicks on water. We studied and quantified the effect of temperature on the performance of several solidifiers using 5 different types of oils under a newly developed testing protocol by conduc...

[Solidification of volatile oil with graphene oxide].

PubMed

Yan, Hong-Mei; Jia, Xiao-Bin; Zhang, Zhen-Hai; Sun, E; Xu, Yi-Hao

2015-02-01

To evaluate the properties of solidifying volatile oil with graphene oxide, clove oil and zedoary turmeric oil were solidified by graphene oxide. The amount of graphene oxide was optimized with the eugenol yield and curcumol yield as criteria. Curing powder was characterized by differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The effects of graphene oxide on dissolution in vitro and thermal stability of active components were studied. The optimum solidification ratio of graphene oxide to volatile oil was 1:1. Dissolution rate of active components had rare influence while their thermal stability improved after volatile oil was solidified. Solidifying herbal volatile oil with graphene oxide deserves further study.

Rapidly solidified metal coatings by peen plating

NASA Technical Reports Server (NTRS)

Chu, H. P.

1987-01-01

Specimens of 7075-T6 aluminum alloy were peen plated with rapidly solidified tin-lead and aluminum powders, and the cross-sections of the coated specimens were examined by light and electron microscopy. The properties of the peen plated specimens were also compared with those of shot peened specimens without any coating. It is found that peen plating with rapidly solidified metals improves the fatigue properties of the coated samples to a greater extent than shot peening alone. Specimens of 7075-T6 alloy peen plated with rapidly solidified tin-lead and aluminum exhibited better fatigue resistance than shot peened specimens in both air and salt water.

WORK FUNCTION CHARACTERIZATION OF DIRECTIONALLY SOLIDIFIED LAB6VB2 EUTECTIC (POSTPRINT)

DTIC Science & Technology

2017-05-10

Berkeley National Laboratory Marc Cahay University of Cincinnati Ali Sayir NASA Glenn Research Center 28 April 2017 Interim Report...Derkink, and Chen Gong - LBNL 4) Marc Cahay - University of Cincinnati 5) Ali Sayir - NASA Glenn Research Center 7. PERFORMING...Cincinnati, 2600 Clifton Ave. Cincinnati, Ohio, 45221-003 5) NASA Glenn Research Ctr, 21000 Brookpark Rd. Cleveland

Very High Cycle Fatigue Behavior of a Directionally Solidified Ni-Base Superalloy DZ4

PubMed Central

Nie, Baohua; Zhao, Zihua; Liu, Shu; Chen, Dongchu; Ouyang, Yongzhong; Hu, Zhudong; Fan, Touwen; Sun, Haibo

2018-01-01

The effect of casting pores on the very high cycle fatigue (VHCF) behavior of a directionally solidified (DS) Ni-base superalloy DZ4 is investigated. Casting and hot isostatic pressing (HIP) specimens were subjected to very high cycle fatigue loading in an ambient atmosphere. The results demonstrated that the continuously descending S-N curves were exhibited for both the casting and HIP specimens. Due to the elimination of the casting pores, the HIP samples had better fatigue properties than the casting samples. The subsurface crack initiated from the casting pore in the casting specimens at low stress amplitudes, whereas fatigue crack initiated from crystallographic facet decohesion for the HIP specimens. When considering the casting pores as initial cracks, there exists a critical stress intensity threshold ranged from 1.1 to 1.3 MPam, below which fatigue cracks may not initiate from the casting pores. Furthermore, the effect of the casting pores on the fatigue limit is estimated based on a modified El Haddad model, which is in good agreement with the experimental results. Fatigue life for both the casting and HIP specimens is well predicted using the Fatigue Indicator Parameter (FIP) model. PMID:29320429

Primary arm spacing in directionally solidified Pb-10 wt percent Sn alloys

NASA Technical Reports Server (NTRS)

Chopra, M. A.; Tewari, S. N.

1990-01-01

The dependence of primary arm spacings on growth speed was investigated for cellular and dendritic arrays in Pb-10 wt percent Sn samples directionally solidified under a constant positive thermal gradient in the melt. The gradient of constitutional supercooling was varied from almost zero (near the break-down of the planar liquid-solid interface at small growth speeds, cellular morphology) to near unity (large growth speeds, dendritic morphology). The spatial arrangements of cells and dendrites, as given by their coordination number, are not very different from each other. It appears that primary arm spacing maxima and the cell to dendrite transition are strongly influenced by the magnitude of the solute partition coefficient. The planar to cellular bifurcation is supercritical in Pb-Sn which has a high partition coefficient, as compared to the subcritical behavior reported in Al-Cu and succinonitrile-acetone, both of which have low partition coefficients. The primary arm spacing model due to Hunt agrees with the experimentally observed trend for the whole growth regime. There is a good quantitative agreement at higher gradients of supercooling. However, the model overpredicts the primary arm spacings at low gradients of constitutional supercooling.

46 CFR 153.1108 - Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose...

Code of Federal Regulations, 2014 CFR

2014-10-01

... 46 Shipping 5 2014-10-01 2014-10-01 false Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity exceeds 25 mPa sec at 20 °C: Categories A, B, and C... Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity...

46 CFR 153.1108 - Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose...

Code of Federal Regulations, 2012 CFR

2012-10-01

... 46 Shipping 5 2012-10-01 2012-10-01 false Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity exceeds 25 mPa sec at 20 °C: Categories A, B, and C... Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity...

46 CFR 153.1108 - Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose...

Code of Federal Regulations, 2013 CFR

2013-10-01

... 46 Shipping 5 2013-10-01 2013-10-01 false Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity exceeds 25 mPa sec at 20 °C: Categories A, B, and C... Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity...

46 CFR 153.1108 - Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose...

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 5 2011-10-01 2011-10-01 false Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity exceeds 25 mPa sec at 20 °C: Categories A, B, and C... Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity...

46 CFR 153.1108 - Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose...

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity exceeds 25 mPa sec at 20 °C: Categories A, B, and C... Heated prewash for solidifying NLS, high viscosity NLS and required prewashes of NLS whose viscosity...

Macrosegregation Due to Convection in Al-19Cu Alloy Directionally Solidified Through an Abrupt Expansion in Cross-Section: A Comparison with Al-7Si

NASA Astrophysics Data System (ADS)

Ghods, M.; Lauer, M.; Grugel, R. N.; Tewari, S. N.; Poirier, D. R.

2017-10-01

Hypoeutectic Al-19 wt.% Cu alloys were directionally solidified at two different growth speeds in cylindrical molds that featured an abrupt increase in cross-section, from 3.2 to 9.5 mm in diameter. The effects of thermosolutal convection and shrinkage flow induced by the cross-section change on macrosegregation were investigated. Dendrite clustering and extensive radial macrosegregation were seen, particularly in the larger cross-section after expansion. Negative longitudinal macrosegregation right after the cross-section increase was observed; the extent of macrosegregation, however, decreases with increasing growth speed. Both thermal and flow effects due to cross-section change were seen to influence the radial macrosegregation immediately before, and after the expansion. Radial macrosegregation pattern was found to be changing as the mushy zone enters the larger cross-section region above the cross-section change where the solidification is in its unsteady state. The effect of the solutal expansion coefficient on macrosegregation was studied by comparing the degree of thermosolutal convection in Al-19 wt.% Cu with a previous study in which we investigated Al-7 wt.% Si. A two-dimensional model accounting for both shrinkage and thermosolutal convection was used to simulate the resulting steepling, as well as the axial and radial macrosegregation. The experimentally observed macrosegregation associated with the expansion during directional solidification is well predicted by the numerical simulations.

A study of reduced chromium content in a nickel-base superalloy via element substitution and rapid solidification processing. Ph.D. ThesisFinal Report

NASA Technical Reports Server (NTRS)

Powers, William O.

1987-01-01

A study of reduced chromium content in a nickel base superalloy via element substitution and rapid solidification processing was performed. The two elements used as partial substitutes for chromium were Si and Zr. The microstructure of conventionally solidified materials was characterized using microscopy techniques. These alloys were rapidly solidified using the chill block melt spinning technique and the rapidly solidified microstructures were characterized using electron microscopy. The spinning technique and the rapidly solidified microstructures was assessed following heat treatments at 1033 and 1272 K. Rapidly solidified material of three alloys was reduced to particulate form and consolidated using hot isostatic pressing (HIP). The consolidated materials were also characterized using microscopy techniques. In order to evaluate the relative strengths of the consolidated alloys, compression tests were performed at room temperature and 1033 K on samples of as-HIPed and HIPed plus solution treated material. Yield strength, porosity, and oxidation resistance characteristics are given and compared.

Effect of cooling rate on magnetic domain structure and magnetic properties of Tb0.27Dy0.73Fe1.95 alloys solidified in high magnetic field

NASA Astrophysics Data System (ADS)

Liu, Tie; Dong, Meng; Gao, Pengfei; Xiao, Yubao; Yuan, Yi; Wang, Qiang

2018-05-01

In this work, Tb0.27Dy0.73Fe1.95 alloys were solidified in a high magnetic field of 4.4 T at various cooling rates. Changes in the magnetostriction, crystal orientation, magnetization, and magnetic domain of the solidified alloys were investigated. The application of the magnetic field can induce <111> orientation of (Tb, Dy)Fe2 phase. However, the effect of the magnetic field is strongly dependent on the cooling rate. The alloy solidified at 5 °C/min shows the highest magnetostriction, strongest <111> orientation, best contrast of light and dark in the domain image, and fastest magnetization, and followed in descending order by the alloys solidified at 1.5 °C/min and 60 °C/min. The change in the magnetostriction of the alloys can be attributed to the changes in crystal orientation and magnetic domain structure caused by both the magnetic field and cooling rate.

Aggregation-Induced Emission Luminogen-Based Direct Visualization of Concentration Gradient Inside an Evaporating Binary Sessile Droplet.

PubMed

Cai, Xin; Xie, Ni; Qiu, Zijie; Yang, Junxian; He, Minghao; Wong, Kam Sing; Tang, Ben Zhong; Qiu, Huihe

2017-08-30

In this study, the concentration gradient inside evaporating binary sessile droplets of 30, 50, and 60 vol % tetrahydrofuran (THF)/water mixtures was investigated. The 5 μL THF/water droplets were evaporated on a transparent hydrophobic substrate. This is the first demonstration of local concentration mapping within an evaporating binary droplet utilizing the aggregation-induced emission material. During the first two evaporation stages of the binary droplet, the local concentration can be directly visualized by the change of fluorescence emission intensity. Time-resolved average and local concentrations can be estimated by using the pre-established function of fluorescence intensity versus water volume fraction.

A Study on the Physical Properties and Interfacial Reactions with Cu Substrate of Rapidly Solidified Sn-3.5Ag Lead-Free Solder

NASA Astrophysics Data System (ADS)

Ma, Hai-Tao; Wang, Jie; Qu, Lin; Zhao, Ning; Kunwar, A.

2013-08-01

A rapidly solidified Sn-3.5Ag eutectic alloy produced by the melt-spinning technique was used as a sample in this research to investigate the microstructure, thermal properties, solder wettability, and inhibitory effect of Ag3Sn on Cu6Sn5 intermetallic compound (IMC). In addition, an as-cast Sn-3.5Ag solder was prepared as a reference. Rapidly solidified and as-cast Sn-3.5Ag alloys of the same size were soldered at 250°C for 1 s to observe their instant melting characteristics and for 3 s with different cooling methods to study the inhibitory effect of Ag3Sn on Cu6Sn5 IMC. Experimental techniques such as scanning electron microscopy, differential scanning calorimetry, and energy-dispersive spectrometry were used to observe and analyze the results of the study. It was found that rapidly solidified Sn-3.5Ag solder has more uniform microstructure, better wettability, and higher melting rate as compared with the as-cast material; Ag3Sn nanoparticles that formed in the rapidly solidified Sn-3.5Ag solder inhibited the growth of Cu6Sn5 IMC during aging significantly much strongly than in the as-cast material because their number in the rapidly solidified Sn-3.5Ag solder was greater than in the as-cast material with the same soldering process before aging. Among the various alternative lead-free solders, this study focused on comparison between rapidly solidified and as-cast solder alloys, with the former being observed to have better properties.

Solidification Using the Baffle in Sealed Ampoules

NASA Technical Reports Server (NTRS)

Ostrogorsky, A.; Marin, C.; Churilov, A.; Volz, M. P.; Bonner, W. A.; Spivey, R. A.; Smith, G.

2003-01-01

Solidification Using a Baffle in Sealed Ampoules (SUBSA) is the first investigation conducted in the Microgravity Science Glovebox (MSG) Facility at the International Space Station (ISS) Alpha. In July, August and September of 2002, 8 single crystals of InSb, doped with Te and Zn, were directionally solidified in microgravity. Ground based tests, related numerical modeling and images of the growth process obtained in microgravity are presented.

Dip-Coating Fabrication of Solar Cells

NASA Technical Reports Server (NTRS)

Koepke, B.; Suave, D.

1982-01-01

Inexpensive silicon solar cells made by simple dip technique. Cooling shoes direct flow of helium on graphite-coated ceramic substrate to solidify film of liquid silicon on graphite surface as substrate is withdrawn from molten silicon. After heaters control cooling of film and substrate to prevent cracking. Gas jets exit at points about 10 mm from substrate surfaces and 6 to 10 mm above melt surface.

Life Prediction of Turbine Blade Nickel Base Superalloy Single Crystals.

DTIC Science & Technology

1986-08-01

mechanical properties between single crystals and the DS version of Mar-M200. Soon it was recognized again through the mechanical property - structure ... property achievements demonstrated by screening and simulated engine tests. 1 Single crystals are the results of extensive investigation on the mechanical ...behavior, (especially fatigue and creep) of, and the structure - property correlations in the equiaxed and directionally solidified (DS) nickel-base

Field Emission Cold Cathode Devices Based on Eutectic Systems

DTIC Science & Technology

1981-07-01

8217RADC-TR-811-170 ’,Final Technical Report July 1981 FIELD EMISSION COLD CATHODE DEVICES BASED ON EUTECTIC SYSTEMS Fulmer Research Institute Ltd...and identify by block numrber) Field Emission Eutectic Systems Cold Cathode Rod Eutectics Electron Emitter Array Directionally Solidified Eutectics...Identify by block number) A survey has been made of the performance as field emission cold cathodes of selected refractory materials fabricated as

BUNDLE: A Novel Furnace for Performing Controlled Directional Solidification Experiments in a Microgravity Environment

NASA Technical Reports Server (NTRS)

Carrasquillo, Edgar J.; Griffin, Mark R.; Hammond, Monica S.; Johnson, Martin L.; Grugel, R. N.

2000-01-01

NASA Marshall Space Flight Center has developed a novel directional solidification furnace prototype for processing metals and alloys experiments in a microgravity environment. The BUNDLE (Bridgman Unidirectional Dendrite in Liquid Experiment) furnace is intended to accommodate the science requirements of Flight Definition Principle Investigators studying cellular/dendritic growth in aluminum and lead alloys at processing temperatures up to 1200 C. The furnace implements a number of innovative features to achieve high thermal gradients and quench rates in a low-power, light-weight design. These include a pyrolytic boron nitride/graphite composite heating element surrounded by layers of self-supporting refractory metal shielding, and a graphite fiber enhanced cold zone allowing high levels of heat extraction from the sample crucible. Novel to the BUNDLE design is an in-situ helium gas quench capability that ensures rapid freezing of the solidifying region (mushy zone) of the metal sample within the furnace without sample disturbance prior to quenching; this is a stringent requirement for subsequent analysis and understanding of microstructural development. The experiment hardware concept features multiple furnaces that may be "bundled" together so many samples, currently up to eight, can be processed at one time. The design of BUNDLE is flexible enough to be implemented on the Shuttle and Space Station in a number of locations (SpaceHab, Express Rack, MPESS, ISPR, etc). BUNDLE prototype furnaces have directionally solidified and quenched 1cm diameter lead - 5.8 weight percent antimony and aluminum - 4 weight percent copper alloys. Quenching of the mushy zone, as recorded by in-situ thermocouples, occurred on the order of 0.5 seconds or less, a rate within the PI's requirements. Subsequent metallographic examination revealed the solidified microstructure to be, as expected, unidirectional. Both the dendrite tips and the eutectic reaction were planar in nature indicating uniform axial heat flow. Delineation between the growing dendrites and eutectic structure with the "quenched-in" liquid was sharp, attesting to the efficacy of the helium quench. BUNDLE's conception, development, capability, and adaptability are presented (in view of Flight PI's needs and science requirements) through viewgraphs depicting actual hardware, generated thermal analysis, and micrographs prepared from BUNDLE processed, flight-like samples.

BUNDLE - A Novel Furnace for Performing Controlled Directional Solidification Experiments in a Microgravity Environment

NASA Technical Reports Server (NTRS)

Carrasquillo, Edgar J.; Griffin, Mark R.; Hammond, Monica S.; Johnson, Martin L.; Grugel, R. N.

2001-01-01

NASA Marshall Space Flight Center has developed a novel directional solidification furnace prototype for processing metals and alloys experiments in a microgravity environment. The BUNDLE (Bridgman Unidirectional Dendrite in Liquid Experiment) furnace is intended to accommodate the science requirements of Flight Definition Principle Investigators studying cellular/dendritic growth in aluminum and lead alloys at processing temperatures up to 1200 C. The furnace implements a number of innovative features to achieve high thermal gradients and quench rates in a low-power, light-weight design. These include a pyrolytic boron nitride/graphite composite heating element surrounded by layers of self-supporting refractory metal shielding, and a graphite fiber enhanced cold zone allowing high levels of heat extraction from the sample crucible. Novel to the BUNDLE design is an in-situ helium gas quench capability that ensures rapid freezing of the solidifying region (mushy zone) of the metal sample within the furnace without sample disturbance prior to quenching; this is a stringent requirement for subsequent analysis and understanding of microstructural development. The experiment hardware concept features multiple furnaces that may be "bundled" together so many samples, currently up to eight, can be processed at one time. The design of BUNDLE is flexible enough to be implemented on the Shuttle and Space Station in a number of locations (SpaceHab, Express Rack, MPESS, ISPR, etc). BUNDLE prototype furnaces have directionally solidified and quenched 1cm diameter lead - 5.8 weight percent antimony and aluminum - 4 weight percent copper alloys. Quenching of the mushy zone, as recorded by in-situ thermocouples, occurred on the order of 0.5 seconds or less, a rate within the PI's requirements. Subsequent metallographic examination revealed the solidified microstructure to be, as expected, unidirectional. Both the dendrite tips and the eutectic reaction were planar in nature indicating uniform axial heat flow. Delineation between the growing dendrites and eutectic structure with the "quenched-in" liquid was sharp, attesting to the efficacy of the helium quench. BUNDLE's conception, development, capability, and adaptability are presented (in view of Flight PI's needs and science requirements) through viewgraphs depicting actual hardware, generated thermal analysis, and micrographs prepared from BUNDLE processed, flight-like samples.

Primary Dendrite Arm Spacing and Trunk Diameter in Al-7-Weight-Percentage Si Alloy Directionally Solidified Aboard the International Space Station

NASA Technical Reports Server (NTRS)

Ghods, M.; Tewari, S. N.; Lauer, M.; Poirier, D. R.; Grugel, R. N.

2016-01-01

Under a NASA-ESA collaborative research project, three Al-7-weight-percentage Si samples (MICAST-6, MICAST-7 and MICAST 2-12) were directionally solidified aboard the International Space Station to determine the effect of mitigating convection on the primary dendrite array. The samples were approximately 25 centimeters in length with a diameter of 7.8 millimeter-diameter cylinders that were machined from [100] oriented terrestrially grown dendritic Al-7Si samples and inserted into alumina ampoules within the Sample Cartridge Assembly (SCA) inserts of the Low Gradient Furnace (LGF). The feed rods were partially remelted in space and directionally solidified to effect the [100] dendrite-orientation. MICAST-6 was grown at 5 microns per second for 3.75 centimeters and then at 50 microns per second for its remaining 11.2 centimeters of its length. MICAST-7 was grown at 20 microns per second for 8.5 centimeters and then at 10 microns per second for 9 centimeters of its remaining length. MICAST2-12 was grown at 40 microns per second for 11 centimeters. The thermal gradient at the liquidus temperature varied from 22 to 14 degrees Kelvin per centimeter during growth of MICAST-6, from 26 to 24 degrees Kelvin per centimeter for MICAST-7 and from 33 to 31 degrees Kelvin per centimeter for MICAST2-12. Microstructures on the transverse sections along the sample length were analyzed to determine nearest-neighbor spacing of the primary dendrite arms and trunk diameters of the primary dendrite-arrays. This was done along the lengths where steady-state growth prevailed and also during the transients associated with the speed-changes. The observed nearest-neighbor spacings during steady-state growth of the MICAST samples show a very good agreement with predictions from the Hunt-Lu primary spacing model for diffusion controlled growth. The observed primary dendrite trunk diameters during steady-state growth of these samples also agree with predictions from a coarsening-based model. The radial macrosegregation and "steepling" caused by thermosolutal convection during terrestrial growth of the Al-7Si was not observed in the space-grown MICAST samples.

[Solidification of magnolol phospholipid complex with polyvingypyrrolidone].

PubMed

Dai, Yun-Hao; Wang, Man; Ju, Jian-Ming; Zhang, Zhen-Hai

2016-06-01

In this study, magnolol phospholipid complex (MPC) was prepared and solidified with polyvingypyrrolidone (PVPP). The influence of PVPP on MPC's flowability, dissolution and oral bioavailability was investigated. The results of phase characterization using differential scanning calorimetry (DSC), infrared spectroscopy (IR), and scanning electron microscopy (SEM) showed that magnolol existed in solidified powder and MPC in an amorphous state. In flowability and dissolution experiments, solidified powder showed significant superiority. At the same time, it showed a higher oral bioavailability compared with MPC, with AUC0-∞ of 73.47 μg•h•mL⁻¹ vs. 63.48 μg•h•mL⁻¹. This process for solidifying powder with PVPP is simple and convenient. Copyright© by the Chinese Pharmaceutical Association.

Microgravity

NASA Image and Video Library

1992-03-12

The Advanced Automated Directional Solidification Furnace (AADSF) with the Experimental Apparatus Container (EAC) removed flew during the USMP-2 mission. During USMP-2, the AADSF was used to study the growth of mercury cadmium telluride crystals in microgravity by directional solidification, a process commonly used on earth to process metals and grow crystals. The furnace is tubular and has three independently controlled temperature zones . The sample travels from the hot zone of the furnace (1600 degrees F) where the material solidifies as it cools. The solidification region, known as the solid/liquid interface, moves from one end of the sample to the other at a controlled rate, thus the term directional solidification.

Preliminary science report on the directional solidification of hypereutectic cast iron during KC-135 low-G maneuvers

NASA Technical Reports Server (NTRS)

Curreri, P. A.; Stefanescu, D. M.; Hendrix, J. C.

1983-01-01

An ADSS-P directional solidification furnace was reconfigured for operation on the KC-135 low-g aircraft. The system offers many advantages over quench ingot methods for study of the effects of sedimentation and convection on alloy formation. The directional sodification furnace system was first flown during the September 1982 series of flights. The microstructure of the hypereutectic cast iron sample solidified on one of these flights suggests a low-g effect on graphite morphology. Further experiments are needed to ascertain that this effect is due to low-gravity and to deduce which of the possible mechanisms is responsible for it.

Particle Engulfment and Pushing by Solidifying Interfaces. Pt. 2; Micro-Gravity Experiments and Theoretical Analysis

NASA Technical Reports Server (NTRS)

Stefanescu, Doru M.; Juretzko, Frank R.; Dhindaw, Brij K.; Catalina, Adrian; Sen, Subhayu; Curreri, Peter A.

1998-01-01

Results of the directional solidification experiments on Particle Engulfment and Pushing by Solidifying Interfaces (PEP) conducted on the space shuttle Columbia during the Life and Microgravity Science Mission are reported. Two pure aluminum (99.999%) 9 mm cylindrical rods, loaded with about 2 vol.% 500 micrometers diameter zirconia particles were melted and resolidified in the microgravity (microg) environment of the shuttle. One sample was processed at step-wise increased solidification velocity, while the other at step-wise decreased velocity. It was found that a pushing-to-engulfment transition (PET) occurred in the velocity range of 0.5 to 1 micrometers. This is smaller than the ground PET velocity of 1.9 to 2.4 micrometers. This demonstrates that natural convection increases the critical velocity. A previously proposed analytical model for PEP was further developed. A major effort to identify and produce data for the surface energy of various interfaces required for calculation was undertaken. The predicted critical velocity for PET was of 0.775 micrometers/s.

Nanoscale microstructure effects on hydrogen behavior in rapidly solidified aluminum alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tashlykova-Bushkevich, Iya I.

2015-12-31

The present work summarizes recent progress in the investigation of nanoscale microstructure effects on hydrogen behavior in rapidly solidified aluminum alloys foils produced at exceptionally high cooling rates. We focus here on the potential of modification of hydrogen desorption kinetics in respect to weak and strong trapping sites that could serve as hydrogen sinks in Al materials. It is shown that it is important to elucidate the surface microstructure of the Al alloy foils at the submicrometer scale because rapidly solidified microstructural features affect hydrogen trapping at nanostructured defects. We discuss the profound influence of solute atoms on hydrogen−lattice defectmore » interactions in the alloys. with emphasis on role of vacancies in hydrogen evolution; both rapidly solidified pure Al and conventionally processed aluminum samples are considered.« less

Hierarchically-driven Approach for Quantifying Materials Uncertainty in Creep Deformation and Failure of Aerospace Materials

DTIC Science & Technology

2016-07-01

characteristics and to examine the sensitivity of using such techniques for evaluating microstructure. In addition to the GUI tool, a manual describing its use has... Evaluating Local Primary Dendrite Arm Spacing Characterization Techniques Using Synthetic Directionally Solidified Dendritic Microstructures, Metallurgical and...driven approach for quanti - fying materials uncertainty in creep deformation and failure of aerspace materials, Multi-scale Structural Mechanics and

Achieving Helicopter Modernization with Advanced Technology Turbine Engines

DTIC Science & Technology

1999-04-01

computer modeling of compressor and turbine aerody- digital engine control ( FADEC ) with manual backup. namics. Modern directionally solidified and single...controlled by a dual RAH.66A M channel FADEC , and features a very simple installation "" Improved Gross Weight and significantly reduced pilot...air separation efficiencies as an "advanced technology" engine. Technological meas- high as 97.5%. The FADEC improves acceleration, ures include but

Formation of equiaxed crystal structures in directionally solidified Al-Si alloys using Nb-based heterogeneous nuclei

PubMed Central

Bolzoni, Leandro; Xia, Mingxu; Babu, Nadendla Hari

2016-01-01

The design of chemical compositions containing potent nuclei for the enhancement of heterogeneous nucleation in aluminium, especially cast alloys such as Al-Si alloys, is a matter of importance in order to achieve homogeneous properties in castings with complex geometries. We identified that Al3Nb/NbB2 compounds are effective heterogeneous nuclei and are successfully produced in the form of Al-2Nb-xB (x = 0.5, 1 and 2) master alloys. Our study shows that the inoculation of Al-10Si braze alloy with these compounds effectively promotes the heterogeneous nucleation of primary α-Al crystals and reduces the undercooling needed for solidification to take place. Moreover, we present evidences that these Nb-based compounds prevent the growth of columnar crystals and permit to obtain, for the first time, fine and equiaxed crystals in directionally solidified Al-10Si braze alloy. As a consequence of the potent heterogeneous particles, the size of the α-Al crystals was found to be less dependent on the processing conditions, especially the thermal gradient. Finally, we also demonstrate that the enhanced nucleation leads to the refinement of secondary phases such as eutectic silicon and primary silicon particles. PMID:28008967

High temperature monotonic and cyclic deformation in a directionally solidified nickel-base superalloy

NASA Technical Reports Server (NTRS)

Huron, Eric S.

1986-01-01

Directionally solidified (DS) MAR-M246+Hf was tested in tension and fatigue, at temperatures from 20 C to 1093 C. Tests were performed on (001) oriented specimens at strain rates of 50 % and 0.5 % per minute. In tension, the yield strength was constant up to 704 C, above which the strength dropped off rapidly. A strong dependence of strength on strain rate was seen at the higher temperatures. The deformation mode was observed to change from heterogeneous to homogeneous with increasing temperature. Low Cycle Fatigue tests were done using a fully reversed waveform and total strain control. For a given plastic strain range, lives increased with increasing temperature. For a given temperature strain rate had a strong effect on life. At 704 C, decreasing strain rates decreased life, while at the higher temperatures, decreasing strain rates increased life, for a given plastic strain range. These results could be explained through considerations of the deformation modes and stress levels. At the higher temperatures, marked coarsening caused beneficial stress reductions, but oxidation limited the life. The longitudinal grain boundaries were found to influence slip behavior. The degree of secondary slip adjacent to the boundaries was found to be related to the degree of misorientation between the grains.

Detachment of secondary dendrite arm in a directionally solidified Sn-Ni peritectic alloy under deceleration growth condition

PubMed Central

Peng, Peng; Li, Xinzhong; Li, Jiangong; Su, Yanqing; Guo, Jingjie; Fu, Hengzhi

2016-01-01

In order to better understand the detachment mechanism of secondary dendrite arm during peritectic solidification, the detachment of secondary dendrite arm from the primary dendrite arms in directionally solidified Sn-36at.%Ni peritectic alloys is investigated at different deceleration rates. Extensive detachment of secondary dendrite arms from primary stem is observed below peritectic reaction temperature TP. And an analytical model is established to characterize the detachment process in terms of the secondary dendrite arm spacing λ2, the root radius of detached arms and the specific surface area (SV) of dendrites. It is found that the detachment mechanism is caused by not only curvature difference between the tips and roots of secondary branches, but also that between the thicker secondary branches and the thinner ones. Besides, this detachment process is significantly accelerated by the temperature gradient zone melting (TGZM) effect during peritectic solidification. It is demonstrated that the reaction constant (f) which is used to characterize the kinetics of peritectic reaction is crucial for the determination of the detachment process. The value of f not only changes with growth rate but also with solidification time at a given deceleration rate. In conclusion, these findings help the better understanding of the detachment mechanism. PMID:27270334

APS TBC performance on directionally-solidified superalloy substrates with HVOF NiCoCrAlYHfSi bond coatings

DOE PAGES

Lance, Michael J.; Unocic, Kinga A.; Haynes, James A.; ...

2015-09-04

Directionally-solidified (DS) superalloy components with advanced thermal barrier coatings (TBC) to lower the metal operating temperature have the potential to replace more expensive single crystal superalloys for large land-based turbines. In order to assess relative TBC performance, furnace cyclic testing was used with superalloys 1483, X4 and Hf-rich DS 247 substrates and high velocity oxygen fuel (HVOF)-NiCoCrAlYHfSi bond coatings at 1100 °C with 1-h cycles in air with 10% H 2O. With these coating and test conditions, there was no statistically-significant effect of substrate alloy on the average lifetime of the air plasma sprayed (APS) yttria-stabilized zirconia (YSZ) top coatingsmore » on small coupons. Using photo-stimulated luminescence piezospectroscopy maps at regular cycling intervals, the residual compressive stress in the α-Al 2O 3 scale underneath the YSZ top coating and on a bare bond coating was similar for all three substrates and delaminations occurred at roughly the same rate and frequency. As a result, x-ray fluorescence (XRF) measurements collected from the bare bond coating surface revealed higher Ti interdiffusion occurring with the 1483 substrate, which contained the highest Ti content.« less

Teaching Non-Recursive Binary Searching: Establishing a Conceptual Framework.

ERIC Educational Resources Information Center

Magel, E. Terry

1989-01-01

Discusses problems associated with teaching non-recursive binary searching in computer language classes, and describes a teacher-directed dialog based on dictionary use that helps students use their previous searching experiences to conceptualize the binary search process. Algorithmic development is discussed and appropriate classroom discussion…

Refinement of Promising Coating Compositions for Directionally Cast Eutectics

NASA Technical Reports Server (NTRS)

Strangman, T. E.; Felten, E. J.; Benden, R. S.

1976-01-01

The successful application of high creep strength, directionally solidified gamma/gamma prime-delta (Ni-19.7Cb-6Cr-2.5Al) eutectic superalloy turbine blades requires the development of suitable coatings for airfoil, root and internal blade surfaces. In order to improve coatings for the gamma/gamma prime-delta alloy, the current investigation had the goals of (1) refining promising coating compositions for directionally solidified eutectics, (2) evaluating the effects of coating/ substrate interactions on the mechanical properties of the alloy, and (3) evaluating diffusion aluminide coatings for internal surfaces. Burner rig cyclic oxidation, furnace cyclic hot corrosion, ductility, and thermal fatigue tests indicated that NiCrAlY+Pt(63 to 127 micron Ni-18Cr-12Al-0.3Y + 6 micron Pt) and NiCrAlY(63 to 127 micron Ni-18Cr-12Al-0.3Y) coatings are capable of protecting high temperature gas path surfaces of eutectic alloy airfoils. Burner rig (Mach 0.37) testing indicated that the useful coating life of the 127 micron thick coatings exceeded 1000 hours at 1366 K (2000 deg F). Isothermal fatigue and furnance hot corrosion tests indicated that 63 micron NiCrAlY, NiCrAlY + Pt and platinum modified diffusion aluminide (Pt + Al) coating systems are capable of protecting the relatively cooler surfaces of the blade root. Finally, a gas phase coating process was evaluated for diffusion aluminizing internal surfaces and cooling holes of air-cooled gamma/gamma prime-delta turbine blades.

Generation of binary holograms with a Kinect sensor for a high speed color holographic display

NASA Astrophysics Data System (ADS)

Leportier, Thibault; Park, Min-Chul; Yano, Sumio; Son, Jung-Young

2017-05-01

The Kinect sensor is a device that enables to capture a real scene with a camera and a depth sensor. A virtual model of the scene can then be obtained with a point cloud representation. A complex hologram can then be computed. However, complex data cannot be used directly because display devices cannot handle amplitude and phase modulation at the same time. Binary holograms are commonly used since they present several advantages. Among the methods that were proposed to convert holograms into a binary format, the direct-binary search (DBS) not only gives the best performance, it also offers the possibility to choose the display parameters of the binary hologram differently than the original complex hologram. Since wavelength and reconstruction distance can be modified, compensation of chromatic aberrations can be handled. In this study, we examine the potential of DBS for RGB holographic display.

OIL BOND®

EPA Pesticide Factsheets

Technical product bulletin: this miscellaneous oil spill control agent is a solidifier used in cleanups. It absorbs and solidifies hydrocarbon spills on freshwater and saltwater or land applications. Ring spill with booms or pillows before treatment.

Satellite radiance data assimilation for binary tropical cyclone cases over the western North Pacific

NASA Astrophysics Data System (ADS)

Choi, Yonghan; Cha, Dong-Hyun; Lee, Myong-In; Kim, Joowan; Jin, Chun-Sil; Park, Sang-Hun; Joh, Min-Su

2017-06-01

A total of three binary tropical cyclone (TC) cases over the Western North Pacific are selected to investigate the effects of satellite radiance data assimilation on analyses and forecasts of binary TCs. Two parallel cycling experiments with a 6 h interval are performed for each binary TC case, and the difference between the two experiments is whether satellite radiance observations are assimilated. Satellite radiance observations are assimilated using the Weather Research and Forecasting Data Assimilation (WRFDA)'s three-dimensional variational (3D-Var) system, which includes the observation operator, quality control procedures, and bias correction algorithm for radiance observations. On average, radiance assimilation results in slight improvements of environmental fields and track forecasts of binary TC cases, but the detailed effects vary with the case. When there is no direct interaction between binary TCs, radiance assimilation leads to better depictions of environmental fields, and finally it results in improved track forecasts. However, positive effects of radiance assimilation on track forecasts can be reduced when there exists a direct interaction between binary TCs and intensities/structures of binary TCs are not represented well. An initialization method (e.g., dynamic initialization) combined with radiance assimilation and/or more advanced DA techniques (e.g., hybrid method) can be considered to overcome these limitations.

Multi-stage flash degaser

DOEpatents

Rapier, P.M.

1980-06-26

A multi-stage flash degaser is incorporated in an energy conversion system having a direct-contact, binary-fluid heat exchanger to remove essentially all of the noncondensable gases from geothermal brine ahead of the direct-contact binary-fluid heat exchanger in order that the heat exchanger and a turbine and condenser of the system can operate at optimal efficiency.

Direct Exoplanet Detection with Binary Differential Imaging

NASA Astrophysics Data System (ADS)

Rodigas, Timothy J.; Weinberger, Alycia; Mamajek, Eric E.; Males, Jared R.; Close, Laird M.; Morzinski, Katie; Hinz, Philip M.; Kaib, Nathan

2015-10-01

Binaries are typically excluded from direct imaging exoplanet surveys. However, the recent findings of Kepler and radial velocity programs show that planets can and do form in binary systems. Here, we suggest that visual binaries offer unique advantages for direct imaging. We show that Binary Differential Imaging (BDI), whereby two stars are imaged simultaneously at the same wavelength within the isoplanatic patch at a high Strehl ratio, offers improved point spread function (PSF) subtraction that can result in increased sensitivity to planets close to each star. We demonstrate this by observing a young visual binary separated by 4″ with MagAO/Clio-2 at 3.9 μm, where the Strehl ratio is high, the isoplanatic patch is large, and giant planets are bright. Comparing BDI to angular differential imaging (ADI), we find that BDI’s 5σ contrast is ˜0.5 mag better than ADI’s within ˜1″ for the particular binary we observed. Because planets typically reside close to their host stars, BDI is a promising technique for discovering exoplanets in stellar systems that are often ignored. BDI is also 2-4× more efficient than ADI and classical reference PSF subtraction, since planets can be detected around both the target and PSF reference simultaneously. We are currently exploiting this technique in a new MagAO survey for giant planets in 140 young nearby visual binaries. BDI on a space-based telescope would not be limited by isoplanatism effects and would therefore be an even more powerful tool for imaging and discovering planets. This paper includes data obtained at the 6.5 m Magellan Telescopes located at Las Campanas Observatory, Chile.

Reactive polymer fused deposition manufacturing

DOEpatents

Kunc, Vlastimil; Rios, Orlando; Love, Lonnie J.; Duty, Chad E.; Johs, Alexander

2017-05-16

Methods and compositions for additive manufacturing that include reactive or thermosetting polymers, such as urethanes and epoxies. The polymers are melted, partially cross-linked prior to the depositing, deposited to form a component object, solidified, and fully cross-linked. These polymers form networks of chemical bonds that span the deposited layers. Application of a directional electromagnetic field can be applied to aromatic polymers after deposition to align the polymers for improved bonding between the deposited layers.

Detection of free liquid in containers of solidified radioactive waste

DOEpatents

Greenhalgh, Wilbur O.

1985-01-01

A method of nondestructively detecting the presence of free liquid within a sealed enclosure containing solidified waste by measuring the levels of waste at two diametrically opposite locations while slowly tilting the enclosure toward one of said locations. When the measured level remains constant at the other location, the measured level at said one location is noted and any measured difference of levels indicates the presence of liquid on the surface of the solidified waste. The absence of liquid in the enclosure is verified when the measured levels at both locations are equal.

A Study on Factors Affecting Strength of Solidified Peat through XRD and FESEM Analysis

NASA Astrophysics Data System (ADS)

Rahman, J. A.; Napia, A. M. A.; Nazri, M. A. A.; Mohamed, R. M. S. R.; Al-Geethi, A. S.

2018-04-01

Peat is soft soil that often causes multiple problems to construction. Peat has low shear strength and high deformation characteristics. Thus, peat soil needs to be stabilized or treated. Study on peat stabilization has been conducted for decades with various admixtures and mixing formulations. This project intends to provide an overview of the solidification of peat soil and the factors that affecting the strength of solidified peat soil. Three types of peats which are fabric, hemic and sapric were used in this study to understand the differences on the effect. The understanding of the factors affecting strength of solidified peat in this study is limited to XRD and FESEM analysis only. Peat samples were collected at Pontian, Johor and Parit Raja, Johor. Peat soil was solidified using fly ash, bottom ash and Portland cement with two mixing formulation following literature review. The solidified peat were cured for 7 days, 14 days, 28 days and 56 days. All samples were tested using Unconfined Compressive Strength Test (UCS), X-ray diffraction (XRD) and Field Emission Scanning Electron Microscope (FESEM). The compressive strength test of solidified peat had shown consistently increase of sheer strength, qu for Mixing 1 while decrease of its compressive strength value for Mixing 2. All samples were tested and compared for each curing days. Through XRD, it is found that all solidified peat are dominated with pargasite and richterite. The highest qu is Fabric Mixing 1(FM1) with the value of 105.94 kPa. This sample were proven contain pargasite. Samples with high qu were observed to be having fly ash and bottom ash bound together with the help of pargasite. Sample with decreasing strength showed less amount of pargasite in it. In can be concluded that XRD and FESEM findings are in line with UCS values.

Leaching of heavy metals from solidified waste using Portland cement and zeolite as a binder.

PubMed

Napia, Chuwit; Sinsiri, Theerawat; Jaturapitakkul, Chai; Chindaprasirt, Prinya

2012-07-01

This study investigated the properties of solidified waste using ordinary Portland cement (OPC) containing synthesized zeolite (SZ) and natural zeolite (NZ) as a binder. Natural and synthesized zeolites were used to partially replace the OPC at rates of 0%, 20%, and 40% by weight of the binder. Plating sludge was used as contaminated waste to replace the binder at rates of 40%, 50% and 60% by weight. A water to binder (w/b) ratio of 0.40 was used for all of the mixtures. The setting time and compressive strength of the solidified waste were investigated, while the leachability of the heavy metals was determined by TCLP. Additionally, XRD, XRF, and SEM were performed to investigate the fracture surface, while the pore size distribution was analyzed with MIP. The results indicated that the setting time of the binders marginally increased as the amount of SZ and NZ increased in the mix. The compressive strengths of the pastes containing 20 and 40wt.% of NZ were higher than those containing SZ. The compressive strengths at 28 days of the SZ solidified waste mixes were 1.2-31.1MPa and those of NZ solidified waste mixes were 26.0-62.4MPa as compared to 72.9MPa of the control mix at the same age. The quality of the solidified waste containing zeolites was better than that with OPC alone in terms of the effectiveness in reducing the leachability. The concentrations of heavy metals in the leachates were within the limits specified by the US EPA. SEM and MIP revealed that the replacement of Portland cement by zeolites increased the total porosity but decreased the average pore size and resulted in the better containment of heavy ions from the solidified waste. Copyright © 2012 Elsevier Ltd. All rights reserved.

Microstructural observations in rapidly-solidified and heat-treated Ni3Al-Cr alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carro, G.; Flanagan, W.F.

1992-08-01

The microstructural development following heat treatments of several rapidly-solidified Ni3Al-Cr and Ni3Al-Cr-B alloys is presented. Depending on composition, the as-solidified samples were either 100 percent gamma-prime phase - in the form of fine antiphase domains (APD) - or a mixture of gamma-prime (APDs) and beta phases. Upon annealing, the as-solidified microstructures transform to either APD-free gamma-prime or mixtures of gamma and gamma-prime phases. For those compositions where the quenched microstructures were 100 percent gamma-prime it was observed that APD coarsening followed conventional grain-growth kinetics, but when gamma phase precipitated on the APD boundaries the rate constant changed abruptly while themore » time exponent remained unaffected. It was also found that alloys containing critical amounts of chromium and boron are susceptible to precipitation of the boride Cr5B3. 14 refs.« less

Microstructural observations in rapidly-solidified and heat-treated Ni sub 3 Al-Cr alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carro, G.; Flanagan, W.F.

1992-01-01

In this paper , the microstructural development following heat treatments of several rapidly-solidified Ni{sub 3}Al-Cr and Ni{sub 3}Al-Cr-B alloys is presented. Depending on composition, the as-solidified samples were either 100% {gamma} phase-in the form of fine anti-phase domains (APD)-or a mixture of {gamma} (APDs) and {beta} phases. Upon annealing, the as-solidified microstructures transform to either APD-free {gamma}or mixtures of {gamma}and {gamma}{prime} phases. For those compositions where the quenched microstructures were 100{gamma}{prime} it was observed that APD coarsening followed conventional grain-growth kinetics, but when {gamma} phase precipitated on the APD boundaries the rate constant changed abruptly while the time exponent remainedmore » unaffected. It was also found that alloys containing critical amounts of chromium and boron are susceptible to precipitation of the boride Cr{sub 5}B{sub 3}.« less

Microstructural observations in rapidly-solidified and heat-treated Ni3Al-Cr alloys

NASA Technical Reports Server (NTRS)

Carro, G.; Flanagan, W. F.

1992-01-01

The microstructural development following heat treatments of several rapidly-solidified Ni3Al-Cr and Ni3Al-Cr-B alloys is presented. Depending on composition, the as-solidified samples were either 100 percent gamma-prime phase - in the form of fine antiphase domains (APD) - or a mixture of gamma-prime (APDs) and beta phases. Upon annealing, the as-solidified microstructures transform to either APD-free gamma-prime or mixtures of gamma and gamma-prime phases. For those compositions where the quenched microstructures were 100 percent gamma-prime it was observed that APD coarsening followed conventional grain-growth kinetics, but when gamma phase precipitated on the APD boundaries the rate constant changed abruptly while the time exponent remained unaffected. It was also found that alloys containing critical amounts of chromium and boron are susceptible to precipitation of the boride Cr5B3.

Radial Velocities of 41 Kepler Eclipsing Binaries

NASA Astrophysics Data System (ADS)

Matson, Rachel A.; Gies, Douglas R.; Guo, Zhao; Williams, Stephen J.

2017-12-01

Eclipsing binaries are vital for directly determining stellar parameters without reliance on models or scaling relations. Spectroscopically derived parameters of detached and semi-detached binaries allow us to determine component masses that can inform theories of stellar and binary evolution. Here we present moderate resolution ground-based spectra of stars in close binary systems with and without (detected) tertiary companions observed by NASA’s Kepler mission and analyzed for eclipse timing variations. We obtain radial velocities and spectroscopic orbits for five single-lined and 35 double-lined systems, and confirm one false positive eclipsing binary. For the double-lined spectroscopic binaries, we also determine individual component masses and examine the mass ratio {M}2/{M}1 distribution, which is dominated by binaries with like-mass pairs and semi-detached classical Algol systems that have undergone mass transfer. Finally, we constrain the mass of the tertiary component for five double-lined binaries with previously detected companions.

Microstructural Quantification of Rapidly Solidified Undercooled D2 Tool Steel

NASA Astrophysics Data System (ADS)

Valloton, J.; Herlach, D. M.; Henein, H.; Sediako, D.

2017-10-01

Rapid solidification of D2 tool steel is investigated experimentally using electromagnetic levitation (EML) under terrestrial and reduced gravity conditions and impulse atomization (IA), a drop tube type of apparatus. IA produces powders 300 to 1400 μm in size. This allows the investigation of a large range of cooling rates ( 100 to 10,000 K/s) with a single experiment. On the other hand, EML allows direct measurements of the thermal history, including primary and eutectic nucleation undercoolings, for samples 6 to 7 mm in diameter. The final microstructures at room temperature consist of retained supersaturated austenite surrounded by eutectic of austenite and M7C3 carbides. Rapid solidification effectively suppresses the formation of ferrite in IA, while a small amount of ferrite is detected in EML samples. High primary phase undercoolings and high cooling rates tend to refine the microstructure, which results in a better dispersion of the eutectic carbides. Evaluation of the cell spacing in EML and IA samples shows that the scale of the final microstructure is mainly governed by coarsening. Electron backscattered diffraction (EBSD) analysis of IA samples reveals that IA powders are polycrystalline, regardless of the solidification conditions. EBSD on EML samples reveals strong differences between the microstructure of droplets solidified on the ground and in microgravity conditions. While the former ones are polycrystalline with many different grains, the EML sample solidified in microgravity shows a strong texture with few much larger grains having twinning relationships. This indicates that fluid flow has a strong influence on grain refinement in this system.

Microstructural development and segregation effects in directionally solidified nickel-based superalloy PWA 1484

NASA Astrophysics Data System (ADS)

Li, Lichun

2002-09-01

These studies were performed to investigate the effects of thermal gradient (G) and growth velocity (V) on the microstructure development and solidification behavior of directionally solidified nickel-based superalloy PWA 1484. Directional solidification (DS) experiments were conducted using a Bridgman crystal growth facility. The solidification velocity ranged from 0.00005 to 0.01 cm/sec and thermal gradients ranged from 12 to 108°C/cm. The as-cast microstructures of DS samples were characterized by using conventional metallography; chemical composition and segregation of directionally solidified samples were analyzed with energy dispersive spectroscopy in SEM. A range of aligned solidification microstructures is exhibited by the alloy when examined as-cast at room temperature: dendrites, flanged cells, cells. The microstructure transitions from cellular to dendritic as the growth velocity increases. The experimental data for PWA1484 exhibits excellent agreement with the well-known exponential equation (lambda1 ∝ G -1/2V-1/4). However, the constant of proportionality is different depending upon the solidification microstructure: (1) dendritic growth with secondary arms leads to a marked dependence of lambda1 on G-1/2 V-1/4; (2) flanged cellular growth with no secondary arms leads to much lower dependence of lambda 1 on G-1/2V -1/4. The primary dendritic arm spacing results were also compared to recent theoretical models. The model of Hunt and Lu and the model of Ma and Sahm provided excellent agreement at medium to high thermal gradients and a wide range of solidification velocities. The anomalous behavior of lambda 1 with high growth velocity V at low G is analyzed based on the samples' microstructures. Off-axis heat flows were shown to cause radial non-uniformity in the dendrite arm spacing data for low thermal gradients and large withdrawal velocities. Various precipitates including gamma', (gamma ' + gamma) eutectic pool or divorced eutectic gamma ', and metal carbides were characterized. Processing conditions (growth velocity V and thermal gradient G) exert significant influence on both morphology and size of precipitates present. Freckle defects were observed on the surface of nickel-based superalloy MM247 cylindrical samples but not on the surface of cylindrical PWA 1484 samples. The Rayleigh number (Ra) that represents liquid instability at the interface was evaluated for MM247 and PWA 1484 in terms of a recently proposed theoretical equation. The effects of segregation, sloped solid/liquid interface and the morphology of dendritic/cellular trunks on the mushy zone convective flow and freckle formation are also discussed.

Application of Sorbents and Solidifiers for Oil Spills

EPA Pesticide Factsheets

This guide assists product manufacturers and members of the response community in distinguishing a sorbent from a solidifier for purposes of listing such products on the National Contingency Plan (NCP) Product Schedule and applying them in the field.

Finger Vein Recognition Based on Local Directional Code

PubMed Central

Meng, Xianjing; Yang, Gongping; Yin, Yilong; Xiao, Rongyang

2012-01-01

Finger vein patterns are considered as one of the most promising biometric authentication methods for its security and convenience. Most of the current available finger vein recognition methods utilize features from a segmented blood vessel network. As an improperly segmented network may degrade the recognition accuracy, binary pattern based methods are proposed, such as Local Binary Pattern (LBP), Local Derivative Pattern (LDP) and Local Line Binary Pattern (LLBP). However, the rich directional information hidden in the finger vein pattern has not been fully exploited by the existing local patterns. Inspired by the Webber Local Descriptor (WLD), this paper represents a new direction based local descriptor called Local Directional Code (LDC) and applies it to finger vein recognition. In LDC, the local gradient orientation information is coded as an octonary decimal number. Experimental results show that the proposed method using LDC achieves better performance than methods using LLBP. PMID:23202194

Finger vein recognition based on local directional code.

PubMed

Meng, Xianjing; Yang, Gongping; Yin, Yilong; Xiao, Rongyang

2012-11-05

Finger vein patterns are considered as one of the most promising biometric authentication methods for its security and convenience. Most of the current available finger vein recognition methods utilize features from a segmented blood vessel network. As an improperly segmented network may degrade the recognition accuracy, binary pattern based methods are proposed, such as Local Binary Pattern (LBP), Local Derivative Pattern (LDP) and Local Line Binary Pattern (LLBP). However, the rich directional information hidden in the finger vein pattern has not been fully exploited by the existing local patterns. Inspired by the Webber Local Descriptor (WLD), this paper represents a new direction based local descriptor called Local Directional Code (LDC) and applies it to finger vein recognition. In LDC, the local gradient orientation information is coded as an octonary decimal number. Experimental results show that the proposed method using LDC achieves better performance than methods using LLBP.

Multi-stage flash degaser

DOEpatents

Rapier, Pascal M.

1982-01-01

A multi-stage flash degaser (18) is incorporated in an energy conversion system (10) having a direct-contact, binary-fluid heat exchanger to remove essentially all of the noncondensable gases from geothermal brine ahead of the direct-contact binary-fluid heat exchanger (22) in order that the heat exchanger (22) and a turbine (48) and condenser (32) of the system (10) can operate at optimal efficiency.

Conditions Leading to Sudden Release of Magma Pressure

NASA Astrophysics Data System (ADS)

Damjanac, B.; Gaffney, E. S.

2005-12-01

Buildup of magmatic pressures in a volcanic system can arise from a variety of mechanisms. Numerical models of the response of volcanic structures to buildup of pressures in magma in dikes and conduits provide estimates of the pressures needed to reopen blocked volcanic vents. They also can bound the magnitude of sudden pressure drops in a dike or conduit due to such reopening. Three scenarios are considered: a dike that is sheared off by covolcanic normal faulting, a scoria cone over a conduit that is blocked by in-falling scoria and some length of solidified magma, and a lava flow whose feed has partially solidified due to an interruption of magma supply from below. For faulting, it is found that magma would be able to follow the fault to a new surface eruption. A small increase in magma pressure over that needed to maintain flow prior to faulting is required to open the new path, and the magma pressure needed to maintain flow is lower but still greater than for the original dike. The magma pressure needed to overcome the other types of blockages depends on the details of the blockage. For example, for a scoria cone, it depends on the depth of the slumped scoria and on the depth to which the magma has solidified in the conduit. In general, failure of the blockage is expected to occur by radial hydrofracture just below the blocked length of conduit at magma pressures of 10 MPa or less, resulting in radial dikes. However, this conclusion is based on the assumption that the fluid magma has direct access to the rock surrounding the conduit. If, on the other hand, there is a zone of solidified basalt, still hot enough to deform plastically, surrounding the molten magma in the conduit, this could prevent breakout of a hydrofracture and allow higher pressures to build up. In such cases, pressures could build high enough to deform the overlying strata (scoria cone or lava flow). Models of such deformations suggest the possibility of more violent eruptions resulting from sudden shear failure of a scoria cone with material accelerations near 100 m/s2.

Fundamental Concepts Relating Local Atomic Arrangements, Deformation, and Fracture of Intermetallic Alloys

DTIC Science & Technology

1993-06-01

Takahashi and H. Oikawa, J. Mater. Sci., 25 (1990) 629. 1 18. S.C. Huang and D.S. Shih, in Microstructure/Property Relationships in Titanium Aluminides and...driven development of directionally-solidified and single crystal superalloy turbine blades . Comparison of the deformation mechanism map for NiAI...1990) 35-44. 101. Bania, P.J. and Hall, J.A., in Titanium Science and Technology, Lutjering, G., Swicker, V., and Bunk, W. (eds.), Deutche

Segregation of Impurities in Directionally Solidified Silicon

NASA Technical Reports Server (NTRS)

Ravishankar, P. S.; Younghouse, L. B.

1984-01-01

Hall measurements and four-point probe resistivity measurements are used to determine the concentration profile of boron and iron in doped semi-conductor silicon ingots grown by the Bridgman technique. The concentration profiles are fitted to the normal segregation equation and the effective segregation coefficient, K sub eff, is calculated. The average value of K sub eff, is 0.803 for boron. For iron, K sub eff, is concentration dependent and is in the range 0.00008 to 0.00012.

Forging Oxide-Dispersion-Strengthened Superalloys

NASA Technical Reports Server (NTRS)

Harf, F. H.; Glasgow, T. K.; Moracz, D. J.; Austin, C. M.

1986-01-01

Cladding of mild steel prevents surface cracking when alloy contacts die. Continual need for improvements in properties of alloys capable of withstanding elevated temperatures. Accomplished by using oxide-dispersion-strengthed superalloys such as Inconel Alloy MA 6000. Elevated tensile properties of forged alloy equal those of hot-rolled MA 6000 bar. Stress-rupture properties somewhat lower than those of bar stock but, at 1,100 degrees C, exceed those of strongest commercial single crystal, directionally solidified and conventionally cast superalloys.

Solidification of radioactive waste resins using cement mixed with organic material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laili, Zalina, E-mail: liena@nm.gov.my; Waste and Environmental Technology Division, Malaysian Nuclear Agency; Yasir, Muhamad Samudi

2015-04-29

Solidification of radioactive waste resins using cement mixed with organic material i.e. biochar is described in this paper. Different percentage of biochar (0%, 5%, 8%, 11%, 14% and 18%) was investigated in this study. The characteristics such as compressive strength and leaching behavior were examined in order to evaluate the performance of solidified radioactive waste resins. The results showed that the amount of biochar affect the compressive strength of the solidified resins. Based on the data obtained for the leaching experiments performed, only one formulation showed the leached of Cs-134 from the solidified radioactive waste resins.

Temperature-dependent phase-specific deformation mechanisms in a directionally solidified NiAl-Cr(Mo) lamellar composite

DOE PAGES

Yu, Dunji; An, Ke; Chen, Xu; ...

2015-10-09

Phase-specific thermal expansion and mechanical deformation behaviors of a directionally solidified NiAl–Cr(Mo) lamellar in situ composite were investigated by using real-time in situ neutron diffraction during compression at elevated temperatures up to 800 °C. Tensile and compressive thermal residual stresses were found to exist in the NiAl phase and Crss (solid solution) phase, respectively. Then, based on the evolution of lattice spacings and phase stresses, the phase-specific deformation behavior was analyzed qualitatively and quantitatively. Moreover, estimates of phase stresses were derived by Hooke's law on the basis of a simple method for the determination of stress-free lattice spacing in inmore » situ composites. During compressive loading, the NiAl phase yields earlier than the Crss phase. The Crss phase carries much higher stress than the NiAl phase, and displays consistent strain hardening at all temperatures. The NiAl phase exhibits strain hardening at relatively low temperatures and softening at high temperatures. During unloading, the NiAl phase yields in tension whereas the Crss phase unloads elastically. Additionally, post-test microstructural observations show phase-through cracks at room temperature, micro cracks along phase interfaces at 600 °C and intact lamellae kinks at 800 °C, which is due to the increasing deformability of both phases as temperature rises.« less

Particle Engulfment and Pushing by Solidifying Interfaces: USMP-4 One Year Report

NASA Technical Reports Server (NTRS)

Stefanescu, D. M.; Juretzko, F. R.; Catalina, A. V.; Sen, S.; Curreri, P.; Schmitt, C.

1999-01-01

The experiment Particle Pushing and Engulfment by Solidifying Interfaces (PEP) was conducted during the USMP-4 (United States Microgravity Payload-4) mission on board the shuttle Columbia in November 1997. This experiment has its place within the framework of a long-term scientific effort to understand the physics of particle pushing. The first flight experiment of this kind was performed with a metal matrix composite on board STS-78 in the summer of 1996. The use of opaque matrices limits the evaluation to pre-and post-flight comparison of particle locations within the sample. By using transparent matrices the interaction of one or multiple particles with an advancing solid/liquid (SL) interface can be studied in-situ. If this observation can then directly be transmitted from the orbiter to the scientists by video down-link, a real-time execution of the experiment is possible in a micro-gravity environment. Part of this experiment was an extensive training of the payload specialists to perform the experiment in orbit. This was further enhanced by the availability of video down-link and direct communication with the astronauts. Even though the PEP experiment is aimed at understanding the interaction of a liquid/solid interface with insoluble particles and thus is fundamental in scope, the prospective applications are not. Possible applications range from improved metal matrix composites to understanding and preventing frost heaving affecting roads.

Pore Formation and Mobility Investigation (PPMI): Description and Initial Analysis of Experiments Conducted aboard the International Space Station

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Anilkumar, A. V.; Lee, C. P.

2003-01-01

Flow visualization experiments during the controlled directional melt back and re-solidification of succinonitrile (SCN) and SCN-water mixtures were conducted using the Pore Formation and Mobility Investigation (PFMI) apparatus in the glovebox facility (GBX) aboard the International Space Station. The study samples were initially 'cast' on earth under 450 millibar of nitrogen into 1 cm ID glass sample tubes approximately 30 cm in length, containing 6 in situ thermocouples. During the Space experiments, the processing parameters and flow visualization settings are remotely monitored and manipulated from the ground Telescience Center (TSC). The ground solidified sample is first subjected to a unidirectional melt back, generally at 10 microns per second, with a constant temperature gradient ahead of the melting interface. Bubbles of different sizes are seen to initiate at the melt interface and, upon release from the melting solid, translate at different speeds in the temperature field ahead of them before coming to rest. Over a period of time these bubbles dissolve into the melt. The gas-laden liquid is then directionally solidified in a controlled manner, generally starting at a rate of 1 micron /sec. Observation and preliminary analysis of bubble formation and mobility in pure SCN samples during melt back and the subsequent structure resulting during gas generation upon re-solidification are presented and discussed.

Pore Formation and Mobility Investigation (PFMI): Description and Initial Analysis of Experiments Conducted aboard the International Space Station

NASA Technical Reports Server (NTRS)

Grugel, R. N.; Anilkumar, A. V.; Lee, C. P.

2002-01-01

Flow visualization experiments during the controlled directional melt back and re-solidification of succinonitrile (SCN) and SCN-water mixtures were conducted using the Pore Formation and Mobility Investigation (PFMI) apparatus in the glovebox facility (GBX) aboard the International Space Station. The study samples were initially "cast" on earth under 450 millibar of nitrogen into 1 cm ID glass sample tubes approximately 30 cm in length, containing 6 in situ thermocouples. During the Space experiments, the processing parameters and flow visualization settings are remotely monitored and manipulated from the ground Telescience Center (TSC). The ground solidified sample is first subjected to a unidirectional melt back, generally at 10 microns per second, with a constant temperature gradient ahead of the melting interface. Bubbles of different sizes are seen to initiate at the melt interface and, upon release from the melting solid, translate at different speeds in the temperature field ahead of them before coming to rest. Over a period of time these bubbles dissolve into the melt. The gas-laden liquid is then directionally solidified in a controlled manner, generally starting at a rate of 1 micron /sec. Observation and preliminary analysis of bubble formation and mobility in pure SCN samples during melt back and the subsequent structure resulting during gas generation upon re-solidification are presented and discussed.

Effect of long-term thermal exposures on microstructures and mechanical properties of directionally solidified CM247LC alloy

NASA Astrophysics Data System (ADS)

Jeong, H. W.; Seo, S. M.; Choi, B. G.; Yoo, Y. S.; Ahn, Y. K.; Lee, J. H.

2013-09-01

A directionally solidified CM247LC alloy was exposed at 871 °C and 982 °C for 1000 h, 5000 h, and 10000 h under free stress in order to study the effect of microstructural degradation on the creep properties. None of the specimens exposed at temperatures up to 10000 h produced any kind of topologically close-packed phases because of the excellent phase stability of CM247LC alloy. The plate-like M6C carbide was formed only at exposure of 982 °C for 10000 h through a decomposition reaction between γ and MC. Moreover, an M23C6 carbide layer was observed between the M6C and the matrix. The exposure at 982°C for 5000 h and 10000 h had a spontaneous rafting of γ' under free stress, while the exposure at 871 °C for 1000 h, 5000 h, and 10000 h had a non-rafted structure. The spontaneous rafted structure resulted in a drastic decrease in creep life. A 3-dimensional morphology of γ' in the as-crept specimens, which were pre-exposed at 982 °C for 5000 h and 10000 h, had a non-rafted structure. This microstructural feature proves that the significant decrease in creep life of the specimen resulted from a loss of coherency between γ and γ'.

Comparison of Directionally Solidified Samples Solidified Terrestrially and Aboard the International Space Station

NASA Technical Reports Server (NTRS)

Angart, S.; Lauer, M.; Tewari, S. N.; Grugel, R. N.; Poirier, D. R.

2014-01-01

This article reports research that has been carried out under the aegis of NASA as part of a collaboration between ESA and NASA for solidification experiments on the International Space Station (ISS). The focus has been on the effect of convection on the microstructural evolution and macrosegregation in hypoeutectic Al-Si alloys during directional solidification (DS). Terrestrial DS-experiments have been carried out at Cleveland State University (CSU) and under microgravity on the International Space Station (ISS). The thermal processing-history of the experiments is well defined for both the terrestrially processed samples and the ISS-processed samples. As of this writing, two dendritic metrics was measured: primary dendrite arm spacings and primary dendrite trunk diameters. We have observed that these dendrite-metrics of two samples grown in the microgravity environment show good agreements with models based on diffusion controlled growth and diffusion controlled ripening, respectively. The gravity-driven convection (i.e., thermosolutal convection) in terrestrially grown samples has the effect of decreasing the primary dendrite arm spacings and causes macrosegregation. Dendrite trunk diameters also show differences between the earth- and space-grown samples. In order to process DS-samples aboard the ISS, the dendritic seed crystals were partially remelted in a stationary thermal gradient before the DS was carried out. Microstructural changes and macrosegregation effects during this period are described and have modeled.

Undercooling-Induced macrosegregation in directional solidification

NASA Astrophysics Data System (ADS)

de Groh, Henry C.

1994-11-01

The accepted primary mechanism for causing macrosegregation in directional solidification (DS) is thermal and solutal convection in the liquid. This article demonstrates the effects of under-cooling and nucleation on macrosegregation and shows that undercooling, in some cases, can be the cause of end-to-end macrosegregation. Alloy ingots of Pb-Sn were directionally solidified upward and downward, with and without undercooling. A thermal gradient of about 5.1 K/cm and a cooling rate of 7.7 K/h were used. Crucibles of borosilicate glass, stainless steel with Cu bottoms, and fused silica were used. High undercoolings were achieved in the glass crucibles, and very low undercoolings were achieved in the steel/Cu crucible. During under-cooling, large, coarse Pb dendrites were found to be present. Large amounts of macrosegregation developed in the undercooled eutectic and hypoeutectic alloys. This segre-gation was found to be due to the nucleation and growth of primary Pb-rich dendrites, continued coarsening of Pb dendrites during undercooling of the interdendritic liquid, Sn enrichment of the liquid, and dendritic fragmentation and settling during and after recalescence. Eutectic ingots that solidified with no undercooling had no macrosegregation, because both Pb and Sn phases were effectively nucleated at the start of solidification, thus initiating the growth of solid of eutectic composition. It is thus shown that undercooling and single-phase nucleation can cause significant macrosegregation by increasing the amount of solute rejected into the liquid and by the movement of unattached dendrites and dendrite fragments, and that macrosegregation in excess of what would be expected due to diffusion transport is not necessarily caused by convection in the liquid.

3-D Modeling of Directional Solidification of a Non-Dilute Alloy with Temperature and Concentration Fields Coupling via Materials Properties Dependence and via Double Diffusive Convection

NASA Technical Reports Server (NTRS)

Bune, Andris V.; Gillies, Donald C.; Lehoczky, Sandor L.

1998-01-01

Numerical simulation of the HgCdTe growth by the vertical Bridgman method was performed using FIDAP finite element code. Double-diffusive melt convection is analyzed, as the primary factor at controls inhomogeneity of the solidified material. Temperature and concentration fields in the model are also coupled via material properties, such as thermal and solutal expansion coefficients with the dependence on both temperature and concentration, and melting temperature evaluation from pseudobinary CdTe-HgTe phase diagram. Experimental measurements were used to obtain temperature boundary conditions. Parametric study of the melt convection dependence on the gravity conditions was undertaken. It was found, that the maximum convection velocity in the melt can be reduced under certain conditions. Optimal conditions to obtain a near flat solidified interface are discussed. The predicted interface shape is in agreement with one obtained experimentally by quenching. The results of 3-D calculations are compared with previous 2- D findings. A video film featuring 3-D melt convection will be presented.

Influence of convection on microstructure

NASA Technical Reports Server (NTRS)

Wilcox, William R.; Caram, Rubens; Mohanty, A. P.; Seth, Jayshree

1990-01-01

The mechanism responsible for the difference in microstructure caused by solidifying the MnBi-Bi eutectic in space is sought. The objectives for the three year period are as follows: (1) completion of the following theoretical analyses - determination of the influence of the Soret effect on the average solid composition versus distance of off-eutectic mixtures directionally solidified in the absence of convection, determination of the influence of convection on the microstructure of off-eutectic mixtures using a linear velocity profile in the adjacent melt, determination of the influence of volumetric changes during solidification on microconvection near the freezing interface and on microstructure, and determination of the influence of convection on microstructure when the MnBi fibers project out in front of the bismuth matrix; (2) search for patterns in the effect of microgravity on different eutectics (for example, eutectic composition, eutectic temperature, usual microstructure, densities of pure constituents, and density changes upon solidification); and (3) determination of the Soret coefficient and the diffusion coefficient for Mn-Bi melts near the eutectic composition, both through laboratory experiements to be performed here and from data from Shuttle experiments.

A Solid Case for Microgravity Processing

NASA Technical Reports Server (NTRS)

Grugel, Richard N.

2000-01-01

Solidification of metals, particularly alloys, is a complicated process. At some sufficiently high temperature, the components comprising an alloy fully mix, producing a single homogeneous liquid. Unfortunately, after this liquid is cast into a mold and allowed to freeze, the resulting solid is usually very inhomogeneous. In most cases the first solid to "freeze out" of the liquid has a composition very close to one of the pure metals. This initially solidifying metal usually comprises microscopic, pine-tree shaped components, collectively referred to as a dendritic array, whose distribution, alignment, and scale directly influence a materials strength and docility. During dendrite growth the adjacent liquid becomes enriched, and consequently, solidifies a much lower temperature and considerably later time. Thus, in the course of solidification, both the solid and the enriched liquid can have compositions (and local temperatures) significantly different from those of the bulk liquid. Different compositions and temperatures imply different densities that, in Earth's gravity, induce motion in the liquid. Such motion promotes formation of a casting that is denser at the bottom and lighter at the top. This condition known as macrosegregation, precludes optimized, uniform material properties.

A Three-Stage Mechanistic Model for Solidification Cracking During Welding of Steel

NASA Astrophysics Data System (ADS)

Aucott, L.; Huang, D.; Dong, H. B.; Wen, S. W.; Marsden, J.; Rack, A.; Cocks, A. C. F.

2018-03-01

A three-stage mechanistic model for solidification cracking during TIG welding of steel is proposed from in situ synchrotron X-ray imaging of solidification cracking and subsequent analysis of fracture surfaces. Stage 1—Nucleation of inter-granular hot cracks: cracks nucleate inter-granularly in sub-surface where maximum volumetric strain is localized and volume fraction of liquid is less than 0.1; the crack nuclei occur at solute-enriched liquid pockets which remain trapped in increasingly impermeable semi-solid skeleton. Stage 2—Coalescence of cracks via inter-granular fracture: as the applied strain increases, cracks coalesce through inter-granular fracture; the coalescence path is preferential to the direction of the heat source and propagates through the grain boundaries to solidifying dendrites. Stage 3—Propagation through inter-dendritic hot tearing: inter-dendritic hot tearing occurs along the boundaries between solidifying columnar dendrites with higher liquid fraction. It is recommended that future solidification cracking criterion shall be based on the application of multiphase mechanics and fracture mechanics to the failure of semi-solid materials.

Cryopreservation of in vitro-grown apical meristems of wasabi (Wasabia japonica) by vitrification and subsequent high plant regeneration.

PubMed

Matsumoto, T; Sakai, A; Yamada, K

1994-05-01

In vitro-grown apical meristems of wasabi (Wasabia japonica Matsumura) were successfully cryopreserved by vitrification. Excised apical meristems precultured on solidified M S medium containing 0.3M sucrose at 20°C for 1 day were loaded with a mixture of 2M glycerol and 0.4M sucrose for 20 min at 25°C. Cryoprotected meristems were then sufficiently dehydrated with a highly concentrated vitrification solution (designated PVS2) for 10 min at 25°C prior to a plunge into liquid nitrogen. After rapid warming, the meristems were expelled into 2 ml of 1.2M sucrose for 20 min and then plated on solidified culture medium. Successfully vitrified and warmed meristems remained green after plating, resumed growth within 3 days, and directly developed shoots within two weeks. The average rate of normal shoot formation amounted to about 80 to 90% in the cryopreserved meristems. This method was successfully applied to three other cultivars of wasabi. This vitrification procedure promises to become a routine method for cryopreserving meristems of wasabi.

Cost analysis of advanced turbine blade manufacturing processes

NASA Technical Reports Server (NTRS)

Barth, C. F.; Blake, D. E.; Stelson, T. S.

1977-01-01

A rigorous analysis was conducted to estimate relative manufacturing costs for high technology gas turbine blades prepared by three candidate materials process systems. The manufacturing costs for the same turbine blade configuration of directionally solidified eutectic alloy, an oxide dispersion strengthened superalloy, and a fiber reinforced superalloy were compared on a relative basis to the costs of the same blade currently in production utilizing the directional solidification process. An analytical process cost model was developed to quantitatively perform the cost comparisons. The impact of individual process yield factors on costs was also assessed as well as effects of process parameters, raw materials, labor rates and consumable items.

Superconductor fiber elongation with a heated injected gas

DOEpatents

Zeigler, D.D.; Conrad, B.L.; Gleixner, R.A.

1998-06-02

An improved method and apparatus for producing flexible fibers of superconducting material includes a crucible for containing a charge of the superconducting material. The material is melted in the crucible and falls in a stream through a bottom hole in the crucible. The stream falls through a protecting collar which maintains the stream at high temperatures. The stream is then supplied through a downwardly directed nozzle where it is subjected to a high velocity of a heated gas which breaks the melted superconducting material into ligaments which solidify into the flexible fibers. The fibers are collected by directing them against a collection filter. 10 figs.

Detachment of Tertiary Dendrite Arms during Controlled Directional Solidification in Aluminum - 7 wt Percent Silicon Alloys: Observations from Ground-based and Microgravity Processed Samples

NASA Technical Reports Server (NTRS)

Grugel, Richard N.; Erdman, Robert; Van Hoose, James R.; Tewari, Surendra; Poirier, David

2012-01-01

Electron Back Scattered Diffraction results from cross-sections of directionally solidified aluminum 7wt% silicon alloys unexpectedly revealed tertiary dendrite arms that were detached and mis-oriented from their parent arm. More surprisingly, the same phenomenon was observed in a sample similarly processed in the quiescent microgravity environment aboard the International Space Station (ISS) in support of the joint US-European MICAST investigation. The work presented here includes a brief introduction to MICAST and the directional solidification facilities, and their capabilities, available aboard the ISS. Results from the ground-based and microgravity processed samples are compared and possible mechanisms for the observed tertiary arm detachment are suggested.

Prediction of dendrite arm spacings in unsteady-and steady-state heat flow of unidirectionally solidified binary alloys

NASA Astrophysics Data System (ADS)

Bouchard, Dominique; Kirkaldy, John S.

1997-08-01

Various theoretical dendrite and cell spacing formulas have been tested against experimental data obtained in unsteady- and steady-state heat flow conditions. An iterative assessment strategy satisfactorily overcomes the circumstances that certain constitutive parameters are inadequately established and/or highly variable and that many of the data sets, in terms of gradients, velocities, and/or cooling rates, are unreliable. The accessed unsteady- and steady-state observations on near-terminal binary alloys for primary and secondary spacings were first examined within conventional power law representations, the deduced exponents and confidence limits for each alloy being tabularly recorded. Through this analysis, it became clear that to achieve predictive generality the many constitutive parameters must be included in a rational way, this being achievable only through extant or new theoretical formulations. However, in the case of primary spacings, all formulas, including our own, failed within the unsteady heat flow algorithm while performing adequately within their steady-state context. An earlier untested, heuristically derived steady-state formula after modification, λ _1 = 120 ( {{16X_0^{{1/2}} G_0 (\\varepsilon σ )T_M D}/{(1 - k)mΔ H G R}} )^{{1/2}} ultimately proved its utility in the unsteady regime, and so it is recommended for purposes of predictions for general terminal alloys. For secondary spacings, a Mullins and Sekerka type formula proved from the start to be adequate in both unsteady- and steady-state heat flows, and so it recommends itself in calibrated form, λ _2 = 12π ( {{4σ }/{X_0 (1 - k)^2 Δ H}( {D/R} )^2 } )^{{1/3}}

Beta-Tin Grain Formation in Aluminum-Modified Lead-Free Solder Alloys

NASA Astrophysics Data System (ADS)

Reeve, Kathlene N.; Handwerker, Carol A.

2018-01-01

The limited number of independent β-Sn grain orientations that typically form during solidification of Sn-based solders and the resulting large β-Sn grain size have major effects on overall solder performance and reliability. This study analyzes whether additions of Al to Sn-Cu and Sn-Cu-Ag alloys can be used to change the grain size, morphology, and twinning structures of atomized (as-solidified) and re-melted (reflowed) β-Sn dendrites as determined using scanning electron microscopy and electron backscatter diffraction for as-solidified and reflow cycled (20-250°C, 1-5 cycles) Sn-Cu-Al and Sn-Ag-Cu-Al drip atomized spheres (260 μm diameter). The resulting microstructures were compared to as-solidified and reflow cycled Sn-Ag-Cu spheres (450 μm diameter) as well as as-solidified Sn-Ag-Cu, Sn-Cu, and Sn-Ag microstructures from the literature. Previous literature observations reporting reductions in undercooling and β-Sn grain size with Al micro-alloying additions could not be correlated to the presence of the Cu9Al4 phase or Al solute. The as-solidified spheres displayed no change in β-Sn dendrite structure or grain size when compared to non-Al-modified alloys, and the reflow cycled spheres produced high undercoolings (22-64°C), indicating a lack of potent nucleation sites. The current findings highlighted the role of Ag in the formation of the interlaced twinning structure and demonstrated that with deliberate compositional choices, formation of the alloy's β-Sn grain structure (cyclical twinning versus interlaced twinning) could be influenced, in both the as-solidified and reflow cycled states, though still not producing the fine-grain sizes and multiple orientations desired for improved thermomechanical properties.

X-ray and optical crystallographic parameters investigations of high frequency induction melted Al-(alpha-Al(2)O(3)) alloys.

PubMed

Bourbia, A; Draissia, M; Bedboudi, H; Boulkhessaim, S; Debili, M Y

2010-01-01

This article deals with the microstructural strengthening mechanisms of aluminium by means of hard alpha-Al(2)O(3) alumina fine particles. A broad of understanding views covering materials preparations, elaboration process, characterization techniques and associated microstructural characteristic parameters measurements is given. In order to investigate the microstructural characteristic parameters and the mechanical strengthening mechanisms of pure aluminium by hard fine particles, a set of Al-(alpha-Al(2)O(3)) alloys samples were made under vacuum by high fusion temperature melting, the high frequency (HF) process, and rapidly solidified under ambient temperature from a mixture of cold-compacted high-pure fine Al and alpha-Al(2)O(3) powders. The as-solidified Al-(alpha-Al(2)O(3)) alloys were characterized by means of X-ray diffraction (XRD) analyses, optical microscopy observations and Vickers microhardness tests in both brut and heat-treated states. It was found that the as-solidified HF Al-(alpha-Al(2)O(3)) alloys with compositions below 4 wt.% (alpha-Al(2)O(3)) are single-phase microstructures of the solid solution FCC Al phase and over two-phase microstructures of the solid solution FCC Al and the Rhombohedral alpha-Al(2)O(3) phases. The optical micrographs reveal the presence of a grain size refinement in these alloys. Vickers microhardness of the as-solidified Al-(alpha-Al(2)O(3)) is increased by means of pure fine alpha-Al(2)O(3) alumina particles. These combined effects of strengthening and grain size refinement observed in the as-solidified Al-(alpha-Al(2)O(3)) alloys are essentially due to a strengthening of Al by the alpha-Al(2)O(3) alumina particles insertion in the (HF) melted and rapidly solidified alloys.

Clustering in complex directed networks

NASA Astrophysics Data System (ADS)

Fagiolo, Giorgio

2007-08-01

Many empirical networks display an inherent tendency to cluster, i.e., to form circles of connected nodes. This feature is typically measured by the clustering coefficient (CC). The CC, originally introduced for binary, undirected graphs, has been recently generalized to weighted, undirected networks. Here we extend the CC to the case of (binary and weighted) directed networks and we compute its expected value for random graphs. We distinguish between CCs that count all directed triangles in the graph (independently of the direction of their edges) and CCs that only consider particular types of directed triangles (e.g., cycles). The main concepts are illustrated by employing empirical data on world-trade flows.

Control of broadband optically generated ultrasound pulses using binary amplitude holograms.

PubMed

Brown, Michael D; Jaros, Jiri; Cox, Ben T; Treeby, Bradley E

2016-04-01

In this work, the use of binary amplitude holography is investigated as a mechanism to focus broadband acoustic pulses generated by high peak-power pulsed lasers. Two algorithms are described for the calculation of the binary holograms; one using ray-tracing, and one using an optimization based on direct binary search. It is shown using numerical simulations that when a binary amplitude hologram is excited by a train of laser pulses at its design frequency, the acoustic field can be focused at a pre-determined distribution of points, including single and multiple focal points, and line and square foci. The numerical results are validated by acoustic field measurements from binary amplitude holograms, excited by a high peak-power laser.

Bayesian performance metrics of binary sensors in homeland security applications

NASA Astrophysics Data System (ADS)

Jannson, Tomasz P.; Forrester, Thomas C.

2008-04-01

Bayesian performance metrics, based on such parameters, as: prior probability, probability of detection (or, accuracy), false alarm rate, and positive predictive value, characterizes the performance of binary sensors; i.e., sensors that have only binary response: true target/false target. Such binary sensors, very common in Homeland Security, produce an alarm that can be true, or false. They include: X-ray airport inspection, IED inspections, product quality control, cancer medical diagnosis, part of ATR, and many others. In this paper, we analyze direct and inverse conditional probabilities in the context of Bayesian inference and binary sensors, using X-ray luggage inspection statistical results as a guideline.

Phase-field simulations of velocity selection in rapidly solidified binary alloys

NASA Astrophysics Data System (ADS)

Fan, Jun; Greenwood, Michael; Haataja, Mikko; Provatas, Nikolas

2006-09-01

Time-dependent simulations of two-dimensional isothermal Ni-Cu dendrites are simulated using a phase-field model solved with a finite-difference adaptive mesh refinement technique. Dendrite tip velocity selection is examined and found to exhibit a transition between two markedly different regimes as undercooling is increased. At low undercooling, the dendrite tip growth rate is consistent with the kinetics of the classical Stefan problem, where the interface is assume to be in local equilibrium. At high undercooling, the growth velocity selected approaches a linear dependence on melt undercooling, consistent with the continuous growth kinetics of Aziz and with a one-dimensional steady-state phase-field asymptotic analysis of Ahmad [Phys. Rev. E 58, 3436 (1998)]. Our simulations are also consistent with other previously observed behaviors of dendritic growth as undercooling is increased. These include the transition of dendritic morphology to absolute stability and nonequilibrium solute partitioning. Our results show that phase-field models of solidification, which inherently contain a nonzero interface width, can be used to study the dynamics of complex solidification phenomena involving both equilibrium and nonequilibrium interface growth kinetics.

In situ gelable interpenetrating double network hydrogel formulated from binary components: thiolated chitosan and oxidized dextran.

PubMed

Zhang, Hanwei; Qadeer, Aisha; Chen, Weiliam

2011-05-09

In situ gelable interpenetrating double-network hydrogels composed of thiolated chitosan (Chitosan-NAC) and oxidized dextran (Odex), completely devoid of potentially cytotoxic small molecule cross-linkers and that do not require complex maneuvers or catalysis, have been formulated. The interpenetrating network structure is created by Schiff base formations and disulfide bond inter-cross-linkings through exploiting the disparity of their reaction times. Compared with the autogelable thiolated chitosan hydrogels that typically require a relatively long time span for gelation to occur, the Odex/Chitosan-NAC composition solidifies rapidly and forms a well-developed 3D network in a short time span. Compared with typical hydrogels derived from natural materials, the Odex/Chitosan-NAC hydrogels are mechanically strong and resist degradation. The cytotoxicity potential of the hydrogels was determined by an in vitro viability assay using fibroblast as a model cell, and the results reveal that the hydrogels are noncytotoxic. In parallel, in vivo results from subdermal implantation in mice models demonstrate that this hydrogel is not only highly resistant to degradation but also induces very mild tissue response.

In situ Gelable Interpenetrating Double Network Hydrogel Formulated from Binary Components: Thiolated Chitosan and Oxidized Dextran

PubMed Central

Zhang, Hanwei; Qadeer, Aisha; Chen, Weiliam

2011-01-01

In situ gelable interpenetrating double network hydrogels composed of thiolated chitosan (Chitosan-NAC) and oxidized dextran (Odex), completely devoid of potentially cytotoxic small molecule crosslinkers and do not require complex maneuvers or catalysis, have been formulated. The interpenetrating network structure is created by Schiff base formations and disulfide bond inter-crosslinkings through exploiting the disparity of their reaction times. Compare to the auto-gelable thiolated chitosan hydrogels that typically require a relatively long time span for gelation to occur, the Odex/Chitosan-NAC composition solidifies rapidly and forms a well-developed three-dimensional network in a short time span. Compare to typical hydrogels derived from natural materials, the Odex/Chitosan-NAC hydrogels are mechanically strong and resist degradation. The cytotoxicity potential of the hydrogels was determined by an in vitro viability assay using fibroblast as a model cell and the results reveal that the hydrogels are non-cytotoxic. In parallel, in vivo results from subdermal implantation in mice models demonstrate that this hydrogel is not only highly resistant to degradation but also induces very mild tissue response. PMID:21410248

Lean and Efficient Software: Whole-Program Optimization of Executables

DTIC Science & Technology

2015-09-30

libraries. Many levels of library interfaces—where some libraries are dynamically linked and some are provided in binary form only—significantly limit...software at build time. The opportunity: Our objective in this project is to substantially improve the performance, size, and robustness of binary ...executables by using static and dynamic binary program analysis techniques to perform whole-program optimization directly on compiled programs

Birth of millisecond pulsars in globular clusters

NASA Technical Reports Server (NTRS)

Grindlay, J. E.; Bailyn, C. D.

1988-01-01

It is argued here that accretion-induced collapse of white dwarfs in binaries can form millisecond pulsars directly without requiring a precursor low-mass X-ray binary stage. Ablation of the precollapse binary companion by the millisecond pulsar's radiation field, a process invoked to explain some of the characteristics of the recently discovered eclipsing millisecond pulsar, can then yield isolated neutron stars witout requiring an additional stellar encounter.

Getting Astrophysical Information from LISA Data

NASA Technical Reports Server (NTRS)

Stebbins, R. T.; Bender, P. L.; Folkner, W. M.

1997-01-01

Gravitational wave signals from a large number of astrophysical sources will be present in the LISA data. Information about as many sources as possible must be estimated from time series of strain measurements. Several types of signals are expected to be present: simple periodic signals from relatively stable binary systems, chirped signals from coalescing binary systems, complex waveforms from highly relativistic binary systems, stochastic backgrounds from galactic and extragalactic binary systems and possibly stochastic backgrounds from the early Universe. The orbital motion of the LISA antenna will modulate the phase and amplitude of all these signals, except the isotropic backgrounds and thereby give information on the directions of sources. Here we describe a candidate process for disentangling the gravitational wave signals and estimating the relevant astrophysical parameters from one year of LISA data. Nearly all of the sources will be identified by searching with templates based on source parameters and directions.

Binary Asteroids and Human Exploration Considerations

NASA Technical Reports Server (NTRS)

Abell, P. A.

2013-01-01

In 2009 the Augustine Commission identified near-Earth asteroids (NEAs) as high profile destinations for human exploration missions beyond the Earth-Moon system as part of the Flexible Path. Subsequently, the U.S. presidential administration directed NASA on April 15, 2010 to include NEAs as destinations for future human exploration with the goal of sending astronauts to a NEA in the mid to late 2020s. This directive became part of the official National Space Policy of the United States of America as of June 28, 2010. Current NASA plans to explore NEAs do not include binary systems. However, with a few in situ robotic precursor missions to binary NEAs, and increased confidence in human mission capabilities, the scientific and hazard mitigation benefits, along with the programmatic and operational benefits of a human venture beyond the Earth-Moon system, make a mission to a binary NEA using NASA's proposed exploration systems a compelling endeavor.

Investigation on microstructure characterization and property of rapidly solidified Mg-Zn-Ca-Ce-La alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou Tao, E-mail: tzhou1118@163.com; Chen Zhenhua, E-mail: chenzhenhua45@hotmail.com; Yang Mingbo, E-mail: yangmingbo@cqit.edu.cn

2012-01-15

Rapidly solidified (RS) Mg-Zn-Ca-Ce-La (wt.%) alloys have been produced via atomizing the alloy melt and subsequent splat-quenching on the water-cooled copper twin-rollers in the form of flakes. Microstructure characterization, phase compositions and thermal stability of the alloys have been systematically investigated. The results showed that with addition of RE (Ce and La) to the Mg-6Zn-5Ca alloy, the stable intermetallic compounds i.e. the Mg{sub x}Zn{sub y}RE{sub z} phase with a few Ca (about 3 at.%), shortened as the T Prime phase, were formed at the expense of the binary Mg-Zn and Ca{sub 2}Mg{sub 6}Zn{sub 3} phases, which was possibly beneficial tomore » the enhanced thermal stability of the alloy. In the Mg-6Zn-5Ca-3Ce-0.5La alloy, the composition of the T Prime phase in the grain interior was different from that at the grain boundaries, in which the segregation of the La elements was found, and the atomic percentage ratio of Zn to Ce in the T Prime phase within the grains was close to 2. Moreover, the stable Mg{sub 2}Ca phases were detected around the T Prime phases at the grain boundaries in the alloy. - Research Highlights: Black-Right-Pointing-Pointer The phase constitution of RS Mg-6Zn-5Ca alloy can be improved by RE additions. Black-Right-Pointing-Pointer In the Mg-Zn-Ca-Ce-La alloys, the Mg{sub x}Zn{sub y}RE{sub z} phase with a few Ca (T Prime phase) is formed. Black-Right-Pointing-Pointer The formation of the T Prime phase leads to the loss of the Mg-Zn and Ca{sub 2}Mg{sub 6}Zn{sub 3} phases. Black-Right-Pointing-Pointer The composition of the T Prime phase differs from the grain interior to the grain boundary.« less

Microgravity processing of particulate reinforced metal matrix composites

NASA Technical Reports Server (NTRS)

Morel, Donald E.; Stefanescu, Doru M.; Curreri, Peter A.

1989-01-01

The elimination of such gravity-related effects as buoyancy-driven sedimentation can yield more homogeneous microstructures in composite materials whose individual constituents have widely differing densities. A comparison of composite samples consisting of particulate ceramics in a nickel aluminide matrix solidified under gravity levels ranging from 0.01 to 1.8 G indicates that the G force normal to the growth direction plays a fundamental role in determining the distribution of the reinforcement in the matrix. Composites with extremely uniform microstructures can be produced by these methods.

Artificial Composites for High Temperature Applications; A Review (Composites Artificiels Destines a des Applications a Haute Temperature; Un Expose),

DTIC Science & Technology

1987-01-01

71 6 Propagation of the recrystallization front in W-wire activated by Ni and Fe in the temperature range 1473 to 1923 K...composites. 73 9 Comparitive creep data for W - 1%ThO2 /FeCrAIY and DS eutectics . 73 10 Three point flexural strength in argon versus temperature for...particularly directionally solidified eutectics . In these composites the fibrous reinforcing phase is usually in chemical equilibrium with the

Initial Transient in Zn-doped InSb Grown in Microgravity

NASA Technical Reports Server (NTRS)

Ostrogorsky, A G.; Marin, C.; Volz, M.; Duffar, T.

2009-01-01

Three Zn-doped InSb crystals were directionally solidified under microgravity conditions at the International Space Station (ISS) Alpha. The distribution of the Zn was measured using SIMS. A short diffusion-controlled transient, typical for systems with k greater than 1 was demonstrated. Static pressure of approximately 4000 N/m2 was imposed on the melt, to prevent bubble formation and dewetting. Still, partial de-wetting has occurred in one experiment, and apparently has disturbed the diffusive transport of Zn in the melt.

Netcast™ Shape Casting Technology: A Technological Breakthrough that Enhances the Cost Effectiveness of Aluminum Forgings

NASA Astrophysics Data System (ADS)

Anderson, Mark; Bruski, Richard; Groszkiewicz, Daniel; Wagstaff, Bob

A new Direct Chill (DC) casting process is introduced to semi-continuous casting where near net shaped ingots are solidified. This process is currently being used at Alcan Engineered Cast Products (ECP) facility in Jonquiere, Canada, sectioned, then forged at Alcoa Automotive, Kentucky Casting Center (KCC). Finished forgings are machined and assembled into the Ford D/EW98 platform as suspension components. A brief description of the process and the implications on the forging process are presented.

Microgravity

NASA Image and Video Library

1997-11-01

The purpose of the experiments for the Advanced Automated Directional Solidification Furnace (AADSF) is to determine how gravity-driven convection affects the composition and properties of alloys (mixtures of two or more materials, usually metal). During the USMP-4 mission, the AADSF will solidify crystals of lead tin telluride and mercury cadmium telluride, alloys of compound semiconductor materials used to make infrared detectors and lasers, as experiment samples. Although these materials are used for the same type application their properties and compositional uniformity are affected differently during the solidification process.

Advanced methods for preparation and characterization of infrared detector materials. [mercury cadmium telluride alloys

NASA Technical Reports Server (NTRS)

Lehoczky, S. L.; Szofran, F. R.

1981-01-01

Differential thermal analysis data were obtained on mercury cadmium telluride alloys in order to establish the liquidus temperatures for the various alloy compositions. Preliminary theoretical analyses was performed to establish the ternary phase equilibrium parameters for the metal rich region of the phase diagram. Liquid-solid equilibrium parameters were determined for the pseudobinary alloy system. Phase equilibrium was calculated and Hg(l-x) Cd(x) Te alloys were directionally solidified from pseudobinary melts. Electrical resistivity and Hall coefficient measurements were obtained.

High Temperature Monotonic and Cyclic Deformation in a Directionally Solidified Nickel-Base Superalloy.

DTIC Science & Technology

1986-05-01

was conducted in air, using a SATEC Systems computer-controlled servohydraulic testing machine. This machine uses a minicomputer (Digital PDP 11/34...overall test program) was run. This test was performed using a feature of the SATEC machine called combinatorial feedback, which allowed a user-defined...Rn) l/T + (in Es /A)/n (4.3) Q can be calculated from 0*: b Q=n (4.4) Creep data for DS MAR-M246, containing no Hafnium, from Reference 99 was used to

Analysis of a Rapidly Solidified High-Phosphorus Austenitic Steel Containing an Amorphous Phase.

DTIC Science & Technology

1981-12-01

electrodeposited nickel by a combination of Jet electro- polishing and ion-beam milling. Specimens were observed in a Vacuum Generators HB-5 scanning...the cell walls in these powders is one of suppressed crystal growth rather than nucleation , since the glass is formed in direct contact with the...Cohen, this Symposium. 5. T. F. Kelly, Ph.D. Thesis , MIT, February 1982. 6. C. V. Thompson, A. L. Greer, and A. J. Drehman, Proc. 4th Intl. Conf

Fiber-Reinforced Superalloys For Rocket Engines

NASA Technical Reports Server (NTRS)

Lewis, Jack R.; Yuen, Jim L.; Petrasek, Donald W.; Stephens, Joseph R.

1990-01-01

Report discusses experimental studies of fiber-reinforced superalloy (FRS) composite materials for use in turbine blades in rocket engines. Intended to withstand extreme conditions of high temperature, thermal shock, atmospheres containing hydrogen, high cycle fatigue loading, and thermal fatigue, which tax capabilities of even most-advanced current blade material - directionally-solidified, hafnium-modified MAR M-246 {MAR M-246 (Hf) (DS)}. FRS composites attractive combination of properties for use in turbopump blades of advanced rocket engines at temperatures from 870 to 1,100 degrees C.

Toward more intuitive brain-computer interfacing: classification of binary covert intentions using functional near-infrared spectroscopy

NASA Astrophysics Data System (ADS)

Hwang, Han-Jeong; Choi, Han; Kim, Jeong-Youn; Chang, Won-Du; Kim, Do-Won; Kim, Kiwoong; Jo, Sungho; Im, Chang-Hwan

2016-09-01

In traditional brain-computer interface (BCI) studies, binary communication systems have generally been implemented using two mental tasks arbitrarily assigned to "yes" or "no" intentions (e.g., mental arithmetic calculation for "yes"). A recent pilot study performed with one paralyzed patient showed the possibility of a more intuitive paradigm for binary BCI communications, in which the patient's internal yes/no intentions were directly decoded from functional near-infrared spectroscopy (fNIRS). We investigated whether such an "fNIRS-based direct intention decoding" paradigm can be reliably used for practical BCI communications. Eight healthy subjects participated in this study, and each participant was administered 70 disjunctive questions. Brain hemodynamic responses were recorded using a multichannel fNIRS device, while the participants were internally expressing "yes" or "no" intentions to each question. Different feature types, feature numbers, and time window sizes were tested to investigate optimal conditions for classifying the internal binary intentions. About 75% of the answers were correctly classified when the individual best feature set was employed (75.89% ±1.39 and 74.08% ±2.87 for oxygenated and deoxygenated hemoglobin responses, respectively), which was significantly higher than a random chance level (68.57% for p<0.001). The kurtosis feature showed the highest mean classification accuracy among all feature types. The grand-averaged hemodynamic responses showed that wide brain regions are associated with the processing of binary implicit intentions. Our experimental results demonstrated that direct decoding of internal binary intention has the potential to be used for implementing more intuitive and user-friendly communication systems for patients with motor disabilities.

Expanding the catalog of binary black-hole simulations: aligned-spin configurations

NASA Astrophysics Data System (ADS)

Chu, Tony; Pfeiffer, Harald; Scheel, Mark; Szilagyi, Bela; SXS Collaboration

2015-04-01

A major goal of numerical relativity is to model the inspiral and merger of binary black holes through sufficiently accurate and long simulations, to enable the successful detection of gravitational waves. However, covering the full parameter space of binary configurations is a computationally daunting task. The SXS Collaboration has made important progress in this direction recently, with a catalog of 174 publicly available binary black-hole simulations [black-holes.org/waveforms]. Nevertheless, the parameter-space coverage remains sparse, even for non-precessing binaries. In this talk, I will describe an addition to the SXS catalog to improve its coverage, consisting of 95 new simulations of aligned-spin binaries with moderate mass ratios and dimensionless spins as high as 0.9. Some applications of these new simulations will also be mentioned.

Binary optics: Trends and limitations

NASA Technical Reports Server (NTRS)

Farn, Michael W.; Veldkamp, Wilfrid B.

1993-01-01

We describe the current state of binary optics, addressing both the technology and the industry (i.e., marketplace). With respect to the technology, the two dominant aspects are optical design methods and fabrication capabilities, with the optical design problem being limited by human innovation in the search for new applications and the fabrication issue being limited by the availability of resources required to improve fabrication capabilities. With respect to the industry, the current marketplace does not favor binary optics as a separate product line and so we expect that companies whose primary purpose is the production of binary optics will not represent the bulk of binary optics production. Rather, binary optics' more natural role is as an enabling technology - a technology which will directly result in a competitive advantage in a company's other business areas - and so we expect that the majority of binary optics will be produced for internal use.

Angular momentum exchange in white dwarf binaries accreting through direct impact

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sepinsky, J. F.; Kalogera, V., E-mail: jeremy.sepinsky@scranton.edu, E-mail: vicky@northwestern.edu

We examine the exchange of angular momentum between the component spins and the orbit in semi-detached double white dwarf binaries undergoing mass transfer through direct impact of the transfer stream. We approximate the stream as a series of discrete massive particles ejected in the ballistic limit at the inner Lagrangian point of the donor toward the accretor. This work improves upon similar earlier studies in a number of ways. First, we self-consistently calculate the total angular momentum of the orbit at all times. This includes changes in the orbital angular momentum during the ballistic trajectory of the ejected mass, asmore » well as changes during the ejection/accretion due to the radial component of the particle's velocity. Second, we calculate the particle's ballistic trajectory for each system, which allows us to determine the precise position and velocity of the particle upon accretion. We can then include specific information about the radius of the accretor as well as the angle of impact. Finally, we ensure that the total angular momentum is conserved, which requires the donor star spin to vary self-consistently. With these improvements, we calculate the angular momentum change of the orbit and each binary component across the entire parameter space of direct impact double white dwarf binary systems. We find a significant decrease in the amount of angular momentum removed from the orbit during mass transfer, as well as cases where this process increases the angular momentum of the orbit at the expense of the spin angular momentum of the donor. We conclude that, unlike earlier claims in the literature, mass transfer through direct impact need not destabilize the binary and that the quantity and sign of the orbital angular momentum transfer depends on the binary properties, particularly the masses of the double white dwarf binary component stars. This stabilization may significantly impact the population synthesis calculations of the expected numbers of events/systems for which double white dwarfs may be a progenitor, e.g., Type Ia supernovae, Type.Ia supernovae, and AM CVn.« less

Dynamical evolution of young binaries and multiple systems

NASA Astrophysics Data System (ADS)

Reipurth, B.

Most stars, and perhaps all, are born in small multiple systems whose components interact, leading to chaotic dynamic behavior. Some components are ejected, either into distant orbits or into outright escapes, while the remaining components form temporary and eventually permanent binary systems. More than half of all such breakups of multiple systems occur during the protostellar phase, leading to the occasional ejection of protostars outside their nascent cloud cores. Such orphaned protostars are observed as wide companions to embedded protostars, and thus allow the direct study of protostellar objects. Dynamic interactions during early stellar evolution explain the shape and enormous width of the separation distribution function of binaries, from close spectroscopic binaries to the widest binaries.

Microstructures and properties of rapidly solidified alloys

NASA Technical Reports Server (NTRS)

Shechtman, D.; Horowitz, E.

1984-01-01

The microstructure and properties of rapidly solidified aluminum alloys were researched. The effects of powder and flake chemistry and morphology and alternative consolidation processing parameters are being conducted. Samples of the powders being utilized were obtained for comprehensive metallurgical characterization. Seven aluminum alloys in the form of thin foils were studied by a variety of techniques including optical metallography, scanning electron microscope, and transmission electron microscope. Details of the microstructural characteristics are presented along with a discussion of the solidification process. A better understanding of the microstructure of the rapidly solidified aluminum alloys prepared by a variety of techniques such as roller quenching, the vacuum atomized procedure, ultrasonically atomized in inert atmospheres, and atomized in flue gas was provided.

Crystal clear transparent lipstick formulation based on solidified oils.

PubMed

De Clermont-Gallerande, H; Chavardes, V; Zastrow, L

1999-12-01

We have developed a lipstick, the stick of which looks totally transparent. The base, coloured or not, may contain high concentration of actives or fragrances. The present study examines the process of determination of oils and solidifying agents. The selecting criterion include visible spectroscopic measurements to quantify transparency of the formulated product. We have also validated the stick hardness through drop point and breakage measurements. After several investigations, we selected a mixture of oils and solidifying agents. The oil network obtained has been characterized through optical microscopy, transmission electronic microscopy, X-ray diffraction and differential scanning calorimetry. We can show that the final product we obtained is amorphous and its solidity can be explained by chemical bonds formation.

Transverse tensile and stress rupture properties of gamma/gamma prime-delta directionally solidified eutectic

NASA Technical Reports Server (NTRS)

Gray, H. H.

1976-01-01

Tensile and stress rupture properties were determined primarily at 760 C for specimens oriented at various angles (0 deg, 10 deg, 45 deg, and 90 deg) from the solidification direction of bars and/or slabs of the Ni-20Cb-6Cr-2.5A (gamma/gamma prime-delta) eutectic. Threaded-head specimens yielded longer rupture lives with significantly less scatter than did tapered-head specimens. Miniature specimens are suitable for determining traverse tensile and rupture properties of 1.2 centimeter diameter bar stock. The 300 hour rupture stress at 760 C for specimens oriented at 10 deg from the solidification direction was reduced from 740 to 460 MPa, and to 230 MPa for material oriented at either 45 deg or 90 deg.

The growth of metastable peritectic compounds

NASA Technical Reports Server (NTRS)

Larson, D. J., Jr.

1984-01-01

The influence of gravitationally driven convection on the directional solidification of peritectic alloys was evaluated. The Pb-Bi peritectic was studied as a model solidification system. Analyses of directionally solidified Pb-Bi peritectic samples indicate that appreciable macrosegregation occurs due to thermosolutal convection and/or Soret diffusion. The macrosegregation results in sequantial change of phase and morphology as solidification progresses down the length of the sample. Banding was eliminated when furnace conditions were selected which resulted in a planar solidification interface. The directional solidification that occurs in the vicinity of the Pb-Bi peritectic isothermal was found to be isocompositional and to consist solely of the equilibrium terminal solid solution and peritectic phases on an extremely fine scale. Evidence was found to support the peritectic supercooling mechanism, but not the proposed peritectic superheat mechanism.

1974: the discovery of the first binary pulsar

NASA Astrophysics Data System (ADS)

Damour, Thibault

2015-06-01

The 1974 discovery, by Russell A Hulse and Joseph H Taylor, of the first binary pulsar, PSR B1913+16, opened up new possibilities for the study of relativistic gravity. PSR B1913+16, as well as several other binary pulsars, provided direct observational proof that gravity propagates at the velocity of light and has a quadrupolar structure. Binary pulsars also provided accurate tests of the strong-field regime of relativistic gravity. General relativity has passed all of the binary pulsar tests with flying colors. The discovery of binary pulsars also had very important consequences for astrophysics, leading to accurate measurement of neutron star masses, improved understanding of the possible evolution scenarios for the co-evolution of binary stars, and proof of the existence of binary neutron stars emitting gravitational waves for hundreds of millions of years, before coalescing in catastrophic events radiating intense gravitational wave signals, and probably also leading to important emissions of electromagnetic radiation and neutrinos. This article reviews the history of the discovery of the first binary pulsar, and describes both its immediate impact and its longer-term effect on theoretical and experimental studies of relativistic gravity.

Superconductor fiber elongation with a heated injected gas

DOEpatents

Zeigler, Douglas D.; Conrad, Barry L.; Gleixner, Richard A.

2001-01-16

An improved method and apparatus for producing flexible fibers (30) of superconducting material includes a crucible (12) for containing a charge of the superconducting material. The material is melted in the crucible (12) and falls in a stream (18) through a bottom hole (16) in the crucible (12). The stream (18) falls through a protecting collar (22) which maintains the stream (18) at high temperatures. The stream (18) is then supplied through a downwardly directed nozzle (26) where it is subjected to a high velocity of a heated gas (36') which breaks the melted superconducting material into ligaments which solidify into the flexible fibers (30). The fibers (30) are collected by directing them against a collection filter (32).

Superconductor fiber elongation with a heated injected gas

DOEpatents

Zeigler, Douglas D.; Conrad, Barry L.; Gleixner, Richard A.

1998-06-02

An improved method and apparatus for producing flexible fibers (30) of superconducting material includes a crucible (12) for containing a charge of the superconducting material. The material is melted in the crucible (12) and falls in a stream (18) through a bottom hole (16) in the crucible (12). The stream (18) falls through a protecting collar (22) which maintains the stream (18) at high temperatures. The stream (18) is then supplied through a downwardly directed nozzle (26) where it is subjected to a high velocity of a heated gas (36') which breaks the melted superconducting material into ligaments which solidify into the flexible fibers (30). The fibers (30) are collected by directing them against a collection filter (32).

Human Research Program: 2010 Annual Report

NASA Technical Reports Server (NTRS)

2010-01-01

2010 was a year of solid performance for the Human Research Program in spite of major changes in NASA's strategic direction for Human Spaceflight. Last year, the Program completed the final steps in solidifying the management foundation, and in 2010 we achieved exceptional performance from all elements of the research and technology portfolio. We transitioned from creating building blocks to full execution of the management tools for an applied research and technology program. As a team, we continue to deliver the answers and technologies that enable human exploration of space. While the Agency awaits strategic direction for human spaceflight, the Program is well positioned and critically important to helping the Agency achieve its goals.

A Laboratory Screening Study On The Use Of Solidifiers As A Response Tool To Remove Crude Oil Slicks On Seawater

EPA Science Inventory

The effectiveness of five solidifiers to remove Prudhoe Bay crude oil from artificial seawater in the laboratory was determined by ultraviolet-visible spectroscopy (UV-VIS) and gas chromatography/mass spectrometry (GC/MS). The performance of the solidifers was determined by US-V...

Prediction of chemical speciation in stabilized/solidified wastes using a general chemical equilibrium model. Part 1: Chemical representation of cementitious binders

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, J.Y.; Batchelor, B.

1999-03-01

Chemical equilibrium models are useful to evaluate stabilized/solidified waste. A general equilibrium model, SOLTEQ, a modified version of MINTEQA2 for S/S, was applied to predict the chemical speciations in the stabilized/solidified waste form. A method was developed to prepare SOLTEQ input data that can chemically represent various stabilized/solidified binders. Taylor`s empirical model was used to describe partitioning of alkali ions. As a result, SOLTEQ could represent chemical speciation in pure binder systems such as ordinary Portland cement and ordinary Portland cement + fly ash. Moreover, SOLTEQ could reasonably describe the effects on the chemical speciation due to variations in water-to-cement,more » fly ash contents, and hydration times of various binder systems. However, this application of SOLTEQ was not accurate in predicting concentrations of Ca, Si, and SO{sub 4} ions, due to uncertainties in the CSH solubility model and K{sub sp} values of cement hydrates at high pH values.« less

Magnetism-Structure Correlations during the epsilon ->tau Transformation in Rapidly-Solidified MnAl Nanostructured Alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jimenez-Villacorta, F; Marion, JL; Oldham, JT

2014-01-21

Magnetic and structural aspects of the annealing-induced transformation of rapidly-solidified Mn55Al45 ribbons from the as-quenched metastable antiferromagnetic (AF) epsilon-phase to the target ferromagnetic (FM) L1(0) tau-phase are investigated. The as-solidified material exhibits a majority hexagonal epsilon-MnAl phase revealing a large exchange bias shift below a magnetic blocking temperature T-B similar to 95 K (H-ex similar to 13 kOe at 10 K), ascribed to the presence of compositional fluctuations in this antiferromagnetic phase. Heat treatment at a relatively low annealing temperature T-anneal approximate to 568 K (295 degrees C) promotes the nucleation of the metastable L1(0) tau-MnAl phase at the expensemore » of the parent epsilon-phase, donating an increasingly hard ferromagnetic character. The onset of the epsilon ->tau transformation occurs at a temperature that is similar to 100 K lower than that reported in the literature, highlighting the benefits of applying rapid solidification for synthesis of the rapidly-solidified parent alloy.« less

Wide binaries in the direction of Andromeda

NASA Technical Reports Server (NTRS)

Bahcall, J. N.; Ratnatunga, K. U.; Jones, B. F.

1986-01-01

A statistically well-defined sample of candidate binary stars with separations that are expected to be mostly in the range 0.01-0.1 pc is presented. The 36 candidate pairs are all brighter than apparent visual magnitude 12; about half of the projected pairs are expected to be physically associated. After the candidates are studied spectroscopically and photometrically to establish which pairs are real binaries and to measure their physical characteristics, the sample can be used to help determine the dependence of number density on semimajor axis for wide binaries, a function that is of considerable theoretical interest.

Pozzolanic filtration/solidification of radionuclides in nuclear reactor cooling water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Englehardt, J.D.; Peng, C.

1995-12-31

Laboratory studies to investigate the feasibility of one- and two-step processes for precipitation/coprecipitating radionuclides from nuclear reactor cooling water, filtering with pozzolanic filter aid, and solidifying, are reported in this paper. In the one-step process, ferrocyanide salt and excess lime are added ahead of the filter, and the resulting filter cake solidifies by a pozzolanic reaction. The two-step process involves addition of solidifying agents subsequent to filtration. It was found that high surface area diatomaceous synthetic calcium silicate powders, sold commercially as functional fillers and carriers, adsorb nickel isotopes from solution at neutral and slightly basic pH. Addition of themore » silicates to cooling water allowed removal of the tested metal isotopes (nickel, iron, manganese, cobalt, and cesium) simultaneously at neutral to slightly basic pH. Lime to diatomite ratio was the most influential characteristic of composition on final strength tested, with higher lime ratios giving higher strength. Diatomaceous earth filter aids manufactured without sodium fluxes exhibited higher pozzolanic activity. Pozzolanic filter cake solidified with sodium silicate and a ratio of 0.45 parts lime to 1 part diatomite had compressive strength ranging from 470 to 595 psi at a 90% confidence level. Leachability indices of all tested metals in the solidified waste were acceptable. In light of the typical requirement of removing iron and desirability of control over process pH, a two-step process involving addition of Portland cement to the filter cake may be most generally applicable.« less

LavaSIM: the effect of heat transfer in 3D on lava flow characteristics (Invited)

NASA Astrophysics Data System (ADS)

Fujita, E.

2013-12-01

Characteristics of lava flow are governed by many parameters like lava viscosity, effusion rate, ground topography, etc. The accuracy and applicability of lava flow simulation code is evaluated whether the numerical simulation can reproduce these features quantitatively, which is important from both strategic and scientific points of views. Many lava flow simulation codes are so far proposed, and they are classified into two categories, i.e., the deterministic and the probabilistic models. LavaSIM is one of the former category models, and has a disadvantage of time consuming. But LavaSIM can solves the equations of continuity, motion, energy by step and has an advantage in the calculation of three-dimensional analysis with solid-liquid two phase flow, including the heat transfer between lava, solidified crust, air, water and ground, and three-dimensional convection in liquid lava. In other word, we can check the detailed structure of lava flow by LavaSIM. Therefore, this code can produce both channeled and fan-dispersive flows. The margin of the flow is solidified by cooling and these solidified crusts control the behavior of successive lava flow. In case of a channel flow, the solidified margin supports the stable central main flow and elongates the lava flow distance. The cross section of lava flow shows that the liquid lava flows between solidified crusts. As for the lava extrusion flow rate, LavaSIM can include the time function as well as the location of the vents. In some cases, some parts of the solidified wall may be broken by the pressure of successive flow and/or re-melting. These mechanisms could characterize complex features of the observed lava flows at many volcanoes in the world. To apply LavaSIM to the benchmark tests organized by V-hub is important to improve the lava flow evaluation technique.

The measurement of 129I for the cement and the paraffin solidified low and intermediate level wastes (LILWs), spent resin or evaporated bottom from the pressurized water reactor (PWR) nuclear power plants.

PubMed

Park, S D; Kim, J S; Han, S H; Ha, Y K; Song, K S; Jee, K Y

2009-09-01

In this paper a relatively simple and low cost analysis procedure to apply to a routine analysis of (129)I in low and intermediate level radioactive wastes (LILWs), cement and paraffin solidified evaporated bottom and spent resin, which are produced from nuclear power plants (NPPs), pressurized water reactors (PWR), is presented. The (129)I is separated from other nuclides in LILWs using an anion exchange adsorption and solvent extraction by controlling the oxidation and reduction state and is then precipitated as silver iodide for counting the beta activity with a low background gas proportional counter (GPC). The counting efficiency of GPC was varied from 4% to 8% and it was reversely proportional to the weight of AgI by a self absorption of the beta activity. Compared to a higher pH, the chemical recovery of iodide as AgI was lowered at pH 4. It was found that the chemical recovery of iodide for the cement powder showed a lower trend by increasing the cement powder weight, but it was not affected for the paraffin sample. In this experiment, the overall chemical recovery yield of the cement and paraffin solidified LILW samples and the average weight of them were 67+/-3% and 5.43+/-0.53 g, 70+/-7% and 10.40+/-1.60 g, respectively. And the minimum detectable activity (MDA) of (129)I for the cement and paraffin solidified LILW samples was calculated as 0.070 and 0.036 Bq/g, respectively. Among the analyzed cement solidified LILW samples, (129)I activity concentration of four samples was slightly higher than the MDA and their ranges were 0.076-0.114 Bq/g. Also of the analyzed paraffin solidified LILW samples, five samples contained a little higher (129)I activity concentration than the MDA and their ranges were 0.036-0.107 Bq/g.

Toward more intuitive brain-computer interfacing: classification of binary covert intentions using functional near-infrared spectroscopy.

PubMed

Hwang, Han-Jeong; Choi, Han; Kim, Jeong-Youn; Chang, Won-Du; Kim, Do-Won; Kim, Kiwoong; Jo, Sungho; Im, Chang-Hwan

2016-09-01

In traditional brain-computer interface (BCI) studies, binary communication systems have generally been implemented using two mental tasks arbitrarily assigned to “yes” or “no” intentions (e.g., mental arithmetic calculation for “yes”). A recent pilot study performed with one paralyzed patient showed the possibility of a more intuitive paradigm for binary BCI communications, in which the patient’s internal yes/no intentions were directly decoded from functional near-infrared spectroscopy (fNIRS). We investigated whether such an “fNIRS-based direct intention decoding” paradigm can be reliably used for practical BCI communications. Eight healthy subjects participated in this study, and each participant was administered 70 disjunctive questions. Brain hemodynamic responses were recorded using a multichannel fNIRS device, while the participants were internally expressing “yes” or “no” intentions to each question. Different feature types, feature numbers, and time window sizes were tested to investigate optimal conditions for classifying the internal binary intentions. About 75% of the answers were correctly classified when the individual best feature set was employed (75.89% ± 1.39 and 74.08% ± 2.87 for oxygenated and deoxygenated hemoglobin responses, respectively), which was significantly higher than a random chance level (68.57% for p < 0.001). The kurtosis feature showed the highest mean classification accuracy among all feature types. The grand-averaged hemodynamic responses showed that wide brain regions are associated with the processing of binary implicit intentions. Our experimental results demonstrated that direct decoding of internal binary intention has the potential to be used for implementing more intuitive and user-friendly communication systems for patients with motor disabilities.

Generation of binary holograms for deep scenes captured with a camera and a depth sensor

NASA Astrophysics Data System (ADS)

Leportier, Thibault; Park, Min-Chul

2017-01-01

This work presents binary hologram generation from images of a real object acquired from a Kinect sensor. Since hologram calculation from a point-cloud or polygon model presents a heavy computational burden, we adopted a depth-layer approach to generate the holograms. This method enables us to obtain holographic data of large scenes quickly. Our investigations focus on the performance of different methods, iterative and noniterative, to convert complex holograms into binary format. Comparisons were performed to examine the reconstruction of the binary holograms at different depths. We also propose to modify the direct binary search algorithm to take into account several reference image planes. Then, deep scenes featuring multiple planes of interest can be reconstructed with better efficiency.

R144: a very massive binary likely ejected from R136 through a binary-binary encounter

NASA Astrophysics Data System (ADS)

Oh, Seungkyung; Kroupa, Pavel; Banerjee, Sambaran

2014-02-01

R144 is a recently confirmed very massive, spectroscopic binary which appears isolated from the core of the massive young star cluster R136. The dynamical ejection hypothesis as an origin for its location is claimed improbable by Sana et al. due to its binary nature and high mass. We demonstrate here by means of direct N-body calculations that a very massive binary system can be readily dynamically ejected from an R136-like cluster, through a close encounter with a very massive system. One out of four N-body cluster models produces a dynamically ejected very massive binary system with a mass comparable to R144. The system has a system mass of ≈355 M⊙ and is located at 36.8 pc from the centre of its parent cluster, moving away from the cluster with a velocity of 57 km s-1 at 2 Myr as a result of a binary-binary interaction. This implies that R144 could have been ejected from R136 through a strong encounter with another massive binary or single star. In addition, we discuss all massive binaries and single stars which are ejected dynamically from their parent cluster in the N-body models.

Bayesian model-emulation of stochastic gravitational-wave spectra for probes of the final-parsec problem with pulsar-timing arrays

NASA Astrophysics Data System (ADS)

Taylor, Stephen R.; Simon, Joseph; Sampson, Laura

2017-01-01

The final parsec of supermassive black-hole binary evolution is subject to the complex interplay of stellar loss-cone scattering, circumbinary disk accretion, and gravitational-wave emission, with binary eccentricity affected by all of these. The strain spectrum of gravitational-waves in the pulsar-timing band thus encodes rich information about the binary population's response to these various environmental mechanisms. Current spectral models have heretofore followed basic analytic prescriptions, and attempt to investigate these final-parsec mechanisms in an indirect fashion. Here we describe a new technique to directly probe the environmental properties of supermassive black-hole binaries through "Bayesian model-emulation". We perform black-hole binary population synthesis simulations at a restricted set of environmental parameter combinations, compute the strain spectra from these, then train a Gaussian process to learn the shape of the spectrum at any point in parameter space. We describe this technique, demonstrate its efficacy with a program of simulated datasets, then illustrate its power by directly constraining final-parsec physics in a Bayesian analysis of the NANOGrav 5-year dataset. The technique is fast, flexible, and robust.

Bayesian model-emulation of stochastic gravitational-wave spectra for probes of the final-parsec problem with pulsar-timing arrays

NASA Astrophysics Data System (ADS)

Taylor, Stephen; Simon, Joseph; Sampson, Laura

2017-01-01

The final parsec of supermassive black-hole binary evolution is subject to the complex interplay of stellar loss-cone scattering, circumbinary disk accretion, and gravitational-wave emission, with binary eccentricity affected by all of these. The strain spectrum of gravitational-waves in the pulsar-timing band thus encodes rich information about the binary population's response to these various environmental mechanisms. Current spectral models have heretofore followed basic analytic prescriptions, and attempt to investigate these final-parsec mechanisms in an indirect fashion. Here we describe a new technique to directly probe the environmental properties of supermassive black-hole binaries through ``Bayesian model-emulation''. We perform black-hole binary population synthesis simulations at a restricted set of environmental parameter combinations, compute the strain spectra from these, then train a Gaussian process to learn the shape of spectrum at any point in parameter space. We describe this technique, demonstrate its efficacy with a program of simulated datasets, then illustrate its power by directly constraining final-parsec physics in a Bayesian analysis of the NANOGrav 5-year dataset. The technique is fast, flexible, and robust.

Microstructural characterization of high-carbon ferrochromium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lesko, A.; Navara, E.

1996-04-01

Light optical and scanning electron microscopy techniques were used for high-carbon ferrochromium microstructural analysis. Different microstructures were observed for industrially and laboratory-produced ferroalloys. Primary carbides of M{sub 7}C{sub 3} with chromium ferrite were found in the industrially produced, slowly solidified, and cooled ferroalloy, while primary M{sub 7}C{sub 3} carbides accompanied a eutectic mixture of M{sub 7}C{sub 3} carbides and chromium ferrite in the laboratory-melted and in the water-solidified and water-cooled materials. Different microstructural arrangements are directly related to the friability properties of this material, which characterizes its resistance to abrasion on handling and impact. In ferrochromium upgraded by carbon contentmore » reduction, the eutectic M{sub 7}C{sub 3} hexagonal carbides are partly replaced by M{sub 23}C{sub 6} dendritic carbides. The presence of dendritic carbides in the ferrochromium eutectic microstructure can be interpreted as a proof of a lower carbon content, raising the commercial value of the ferroalloy. The hexagonal M{sub 7}C{sub 3} carbides exhibited a central hollow along the longitudinal axis, and on metallographic samples they looked like screw nuts. A model of the solidification mechanism for such crystals is proposed.« less

Effects of additives on solidification of API separator sludge.

PubMed

Faschan, A; Tittlebaum, M; Cartledge, F; Eaton, H

1991-08-01

API separator sludge was solidified with various combinations of binders and absorbent soil additives. The binders utilized were Type I Portland Cement, Type C Flyash, and a 1:1 combination of the two. The soil additives used were bentonite, diatomite, Fuller's earth, and two brands of chemically altered bentonites, or organoclays. The effectiveness of the solidification materials was based on their effect on the physical and leaching characteristics of the sludge.It was determined the Portland cement and combination binders provided the sludge with adequate physical and strength characteristics. It was also determined the affinity of each additive for water had an important influence on the physical characteristics of the solidified sludge. The results of the leaching procedure indicated the binders alone reduced the leachability of organic constituents from the sludge by 1/5 to 1/10. It appeared the use of the additives with the binders may have further reduced the leachability of constituents from sludge, with the incorporation of the organoclay additives further reducing leachability by up to 1/2. Also, it appeared the absorbing capacity of the additives was directly related to their ability to reduce the leachability of organic constituents from the sludge.

Binary black hole mergers from globular clusters: Masses, merger rates, and the impact of stellar evolution

NASA Astrophysics Data System (ADS)

Rodriguez, Carl L.; Chatterjee, Sourav; Rasio, Frederic A.

2016-04-01

The recent discovery of GW150914, the binary black hole merger detected by Advanced LIGO, has the potential to revolutionize observational astrophysics. But to fully utilize this new window into the Universe, we must compare these new observations to detailed models of binary black hole formation throughout cosmic time. Expanding upon our previous work [C. L. Rodriguez, M. Morscher, B. Pattabiraman, S. Chatterjee, C.-J. Haster, and F. A. Rasio, Phys. Rev. Lett. 115, 051101 (2015).], we study merging binary black holes formed in globular clusters using our Monte Carlo approach to stellar dynamics. We have created a new set of 52 cluster models with different masses, metallicities, and radii to fully characterize the binary black hole merger rate. These models include all the relevant dynamical processes (such as two-body relaxation, strong encounters, and three-body binary formation) and agree well with detailed direct N -body simulations. In addition, we have enhanced our stellar evolution algorithms with updated metallicity-dependent stellar wind and supernova prescriptions, allowing us to compare our results directly to the most recent population synthesis predictions for merger rates from isolated binary evolution. We explore the relationship between a cluster's global properties and the population of binary black holes that it produces. In particular, we derive a numerically calibrated relationship between the merger times of ejected black hole binaries and a cluster's mass and radius. With our improved treatment of stellar evolution, we find that globular clusters can produce a significant population of massive black hole binaries that merge in the local Universe. We explore the masses and mass ratios of these binaries as a function of redshift, and find a merger rate of ˜5 Gpc-3yr-1 in the local Universe, with 80% of sources having total masses from 32 M⊙ to 64 M⊙. Under standard assumptions, approximately one out of every seven binary black hole mergers in the local Universe will have originated in a globular cluster, but we also explore the sensitivity of this result to different assumptions for binary stellar evolution. If black holes were born with significant natal kicks, comparable to those of neutron stars, then the merger rate of binary black holes from globular clusters would be comparable to that from the field, with approximately 1 /2 of mergers originating in clusters. Finally we point out that population synthesis results for the field may also be modified by dynamical interactions of binaries taking place in dense star clusters which, unlike globular clusters, dissolved before the present day.

Two distinct sequences of blue straggler stars in the globular cluster M 30.

PubMed

Ferraro, F R; Beccari, G; Dalessandro, E; Lanzoni, B; Sills, A; Rood, R T; Pecci, F Fusi; Karakas, A I; Miocchi, P; Bovinelli, S

2009-12-24

Stars in globular clusters are generally believed to have all formed at the same time, early in the Galaxy's history. 'Blue stragglers' are stars massive enough that they should have evolved into white dwarfs long ago. Two possible mechanisms have been proposed for their formation: mass transfer between binary companions and stellar mergers resulting from direct collisions between two stars. Recently the binary explanation was claimed to be dominant. Here we report that there are two distinct parallel sequences of blue stragglers in M 30. This globular cluster is thought to have undergone 'core collapse', during which both the collision rate and the mass transfer activity in binary systems would have been enhanced. We suggest that the two observed sequences are a consequence of cluster core collapse, with the bluer population arising from direct stellar collisions and the redder one arising from the evolution of close binaries that are probably still experiencing an active phase of mass transfer.

Effects of binary stellar populations on direct collapse black hole formation

NASA Astrophysics Data System (ADS)

Agarwal, Bhaskar; Cullen, Fergus; Khochfar, Sadegh; Klessen, Ralf S.; Glover, Simon C. O.; Johnson, Jarrett

2017-06-01

The critical Lyman-Werner (LW) flux required for direct collapse blackholes (DCBH) formation, or Jcrit, depends on the shape of the irradiating spectral energy distribution (SED). The SEDs employed thus far have been representative of realistic single stellar populations. We study the effect of binary stellar populations on the formation of DCBH, as a result of their contribution to the LW radiation field. Although binary populations with ages > 10 Myr yield a larger LW photon output, we find that the corresponding values of Jcrit can be up to 100 times higher than single stellar populations. We attribute this to the shape of the binary SEDs as they produce a sub-critical rate of H- photodetaching 0.76 eV photons as compared to single stellar populations, reaffirming the role that H- plays in DCBH formation. This further corroborates the idea that DCBH formation is better understood in terms of a critical region in the H2-H- photodestruction rate parameter space, rather than a single value of LW flux.

Directional solidification of Bi-Mn alloys using an applied magnetic field

NASA Technical Reports Server (NTRS)

Decarlo, J. L.; Pirich, R. G.

1987-01-01

Off-eutectic compositions of Bi-Mn were directionally solidified in applied transverse magnetic fields up to 3 kG, to determine the effects on thermal and solutal convection. Plane front directional solidification of eutectic and near-eutectic Bi-Mn results in a two-phase rodlike morphology consisting of ferromagnetic MnBi rods in a Bi solid solution matrix. Compositions of either side of the eutectic were studied in growth orientations vertically up and down. Temperature gradient was monitored during growth by means of an in-situ thermocouple. For Bi-rich compositions, the magnetic field appeared to increase mixing as determined from thermal, morphological, chemical, and magnetic analyses. For Mn-rich compositions, morphological and chemical analyses suggest some reduction in mixing due to application of the magnetic force. The capability for carrying out directional solidification of Bi-Mn in high longitudinal magnetic fields was established.

Functions and requirements document for interim store solidified high-level and transuranic waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith-Fewell, M.A., Westinghouse Hanford

1996-05-17

The functions, requirements, interfaces, and architectures contained within the Functions and Requirements (F{ampersand}R) Document are based on the information currently contained within the TWRS Functions and Requirements database. The database also documents the set of technically defensible functions and requirements associated with the solidified waste interim storage mission.The F{ampersand}R Document provides a snapshot in time of the technical baseline for the project. The F{ampersand}R document is the product of functional analysis, requirements allocation and architectural structure definition. The technical baseline described in this document is traceable to the TWRS function 4.2.4.1, Interim Store Solidified Waste, and its related requirements, architecture,more » and interfaces.« less

Ordinary portland cement based solidification of toxic wastes: The role of OPC reviewed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hills, C.D.; Sollars, C.J.; Perry, R.

1993-01-01

A mixed waste stream, which is commercially solidified, has been solidified in the laboratory using OPC and PFA (pulverized fly ash) in a variety of mix proportions. The solidified products have been subjected to calorimetric, physical and microstructural analysis. The heat of hydration for OPC/waste mixes showed that a progressive poisoning of normal hydration reactions occurred with increasing waste addition. Once poisoned OPC failed to act as a cement and was substituted by PFA and other products in this role. Strength development was found to be related to the heat of hydration; this suggests that conduction calorimetry could be usedmore » to determine the suitability of a particular waste for OPC based solidification.« less

Continuous method for manufacturing grain-oriented magnetostrictive bodies

DOEpatents

Gibson, Edwin D.; Verhoeven, John D.; Schmidt, Frederick A.; McMasters, O. Dale

1988-01-01

The invention comprises a continuous casting and crystallization method for manufacturing grain-oriented magnetostrictive bodies. A magnetostrictive alloy is melted in a crucible having a bottom outlet. The melt is discharged through the bottom of the crucible and deposited in an elongated mold. Heat is removed from the deposited melt through the lower end portion of the mold to progressively solidify the melt. The solid-liquid interface of the melt moves directionally upwardly from the bottom to the top of the mold, to produce the axial grain orientation.

Radioactive waste material disposal

DOEpatents

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1995-10-24

The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide. 3 figs.

Radioactive waste material disposal

DOEpatents

Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

1995-01-01

The invention is a process for direct conversion of solid radioactive waste, particularly spent nuclear fuel and its cladding, if any, into a solidified waste glass. A sacrificial metal oxide, dissolved in a glass bath, is used to oxidize elemental metal and any carbon values present in the waste as they are fed to the bath. Two different modes of operation are possible, depending on the sacrificial metal oxide employed. In the first mode, a regenerable sacrificial oxide, e.g., PbO, is employed, while the second mode features use of disposable oxides such as ferric oxide.

Growth and scintillation properties of Eu doped BaCl2/LiF eutectic scintillator

NASA Astrophysics Data System (ADS)

Kamada, Kei; Hishinuma, Kosuke; Kurosawa, Shunsuke; Yamaji, Akihiro; Shoji, Yasuhiro; Pejchal, Jan; Yokota, Yuui; Ohashi, Yuji; Yoshikawa, Akira

2015-12-01

Eu doped BaCl2/LiF eutectics were grown by the micro-pulling down method and their directionally solidified eutectic (DSE) system has been investigated. The grown eutectic showed main phases of cubic LiF and orthorhombic BaCl2. In these eutectics, the 399 nm emission of Eu2+ 4f5d was obtained. It shows the intrinsic decay time of about 410 ns. The light yield of the 1-mm-thick eutectic showed 7000 ph/5.5 MeV alpha-ray.

A thermodynamic prediction for microporosity formation in aluminum-rich Al-Cu alloys

NASA Technical Reports Server (NTRS)

Poirier, D. R.; Yeum, K.; Maples, A. L.

1987-01-01

A computer model is used to predict the formation and degree of microporosity in a directionally solidified Al-4.5 wt pct Cu alloy, considering the interplay between solidification shrinkage and gas porosity. Macrosegregation theory is used to determine the local pressure within the interdendritic liquid. Results show interdendritic porosity for initial hydrogen contents in the 0.03-1 ppm range, and none below contents of 0.03. An increase in either the thermal gradient or the solidification rate is show to decrease the amount of interdendritic porosity.

Containerless automated processing of intermetallic compounds and composites

NASA Technical Reports Server (NTRS)

Johnson, D. R.; Joslin, S. M.; Reviere, R. D.; Oliver, B. F.; Noebe, R. D.

1993-01-01

An automated containerless processing system has been developed to directionally solidify high temperature materials, intermetallic compounds, and intermetallic/metallic composites. The system incorporates a wide range of ultra-high purity chemical processing conditions. The utilization of image processing for automated control negates the need for temperature measurements for process control. The list of recent systems that have been processed includes Cr, Mo, Mn, Nb, Ni, Ti, V, and Zr containing aluminides. Possible uses of the system, process control approaches, and properties and structures of recently processed intermetallics are reviewed.

Printing of metallic 3D micro-objects by laser induced forward transfer.

PubMed

Zenou, Michael; Kotler, Zvi

2016-01-25

Digital printing of 3D metal micro-structures by laser induced forward transfer under ambient conditions is reviewed. Recent progress has allowed drop on demand transfer of molten, femto-liter, metal droplets with a high jetting directionality. Such small volume droplets solidify instantly, on a nanosecond time scale, as they touch the substrate. This fast solidification limits their lateral spreading and allows the fabrication of high aspect ratio and complex 3D metal structures. Several examples of micron-scale resolution metal objects printed using this method are presented and discussed.

Adolescent transition: Ordinary People (1980), Fly Away Home (1996), and (500) Days Of Summer (2009).

PubMed

Miller, Frederick C

2011-06-01

Five important transitional tasks of adolescent development are (i) taming the upsurge of desires and impulses, both sexual and aggressive, into constructive and creative directions; (ii) establishing independence from infantile family ties (while maintaining some involvement with the family of origin); (iii) reconciling self-preoccupations with social attachments; (iv) reworking identifications, especially sexual; and (v) establishing romantic attachments and solidifying ongoing stable love relationships. These tasks are illustrated with the help of three movies, namely Ordinary People, Fly Away Home, and (500) Days of Summer.

Proposed experiment to test fundamentally binary theories

NASA Astrophysics Data System (ADS)

Kleinmann, Matthias; Vértesi, Tamás; Cabello, Adán

2017-09-01

Fundamentally binary theories are nonsignaling theories in which measurements of many outcomes are constructed by selecting from binary measurements. They constitute a sensible alternative to quantum theory and have never been directly falsified by any experiment. Here we show that fundamentally binary theories are experimentally testable with current technology. For that, we identify a feasible Bell-type experiment on pairs of entangled qutrits. In addition, we prove that, for any n , quantum n -ary correlations are not fundamentally (n -1 ) -ary. For that, we introduce a family of inequalities that hold for fundamentally (n -1 ) -ary theories but are violated by quantum n -ary correlations.

Eclipsing binary stars in the era of massive surveys First results and future prospects

NASA Astrophysics Data System (ADS)

Papageorgiou, Athanasios; Catelan, Márcio; Ramos, Rodrigo Contreras; Drake, Andrew J.

2017-09-01

Our thinking about eclipsing binary stars has undergone a tremendous change in the last decade. Eclipsing binary stars are one of nature's best laboratories for determining the fundamental physical properties of stars and thus for testing the predictions of theoretical models. Some of the largest ongoing variable star surveys include the Catalina Real-time Transient Survey (CRTS) and the VISTA Variables in the Vía Láctea survey (VVV). They both contain a large amount of photometric data and plenty of information about eclipsing binaries that wait to be extracted and exploited. Here we briefly describe our efforts in this direction.

The Tarantula Massive Binary Monitoring. I. Observational campaign and OB-type spectroscopic binaries

NASA Astrophysics Data System (ADS)

Almeida, L. A.; Sana, H.; Taylor, W.; Barbá, R.; Bonanos, A. Z.; Crowther, P.; Damineli, A.; de Koter, A.; de Mink, S. E.; Evans, C. J.; Gieles, M.; Grin, N. J.; Hénault-Brunet, V.; Langer, N.; Lennon, D.; Lockwood, S.; Maíz Apellániz, J.; Moffat, A. F. J.; Neijssel, C.; Norman, C.; Ramírez-Agudelo, O. H.; Richardson, N. D.; Schootemeijer, A.; Shenar, T.; Soszyński, I.; Tramper, F.; Vink, J. S.

2017-02-01

Context. Massive binaries play a crucial role in the Universe. Knowing the distributions of their orbital parameters is important for a wide range of topics from stellar feedback to binary evolution channels and from the distribution of supernova types to gravitational wave progenitors, yet no direct measurements exist outside the Milky Way. Aims: The Tarantula Massive Binary Monitoring project was designed to help fill this gap by obtaining multi-epoch radial velocity (RV) monitoring of 102 massive binaries in the 30 Doradus region. Methods: In this paper we analyze 32 FLAMES/GIRAFFE observations of 93 O- and 7 B-type binaries. We performed a Fourier analysis and obtained orbital solutions for 82 systems: 51 single-lined (SB1) and 31 double-lined (SB2) spectroscopic binaries. Results: Overall, the binary fraction and orbital properties across the 30 Doradus region are found to be similar to existing Galactic samples. This indicates that within these domains environmental effects are of second order in shaping the properties of massive binary systems. A small difference is found in the distribution of orbital periods, which is slightly flatter (in log space) in 30 Doradus than in the Galaxy, although this may be compatible within error estimates and differences in the fitting methodology. Also, orbital periods in 30 Doradus can be as short as 1.1 d, somewhat shorter than seen in Galactic samples. Equal mass binaries (q> 0.95) in 30 Doradus are all found outside NGC 2070, the central association that surrounds R136a, the very young and massive cluster at 30 Doradus's core. Most of the differences, albeit small, are compatible with expectations from binary evolution. One outstanding exception, however, is the fact that earlier spectral types (O2-O7) tend to have shorter orbital periods than later spectral types (O9.2-O9.7). Conclusions: Our results point to a relative universality of the incidence rate of massive binaries and their orbital properties in the metallicity range from solar (Z⊙) to about half solar. This provides the first direct constraints on massive binary properties in massive star-forming galaxies at the Universe's peak of star formation at redshifts z 1 to 2 which are estimated to have Z 0.5 Z⊙. The log of observations and RV measurements for all targets are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/598/A84

Cement-based stabilization/solidification of oil refinery sludge: Leaching behavior of alkanes and PAHs.

PubMed

Karamalidis, Athanasios K; Voudrias, Evangelos A

2007-09-05

Stabilization/solidification is a process widely applied for the immobilization of inorganic constituents of hazardous wastes, especially for metals. Cement is usually one of the most common binders for that purpose. However, limited results have been presented on immobilization of hydrocarbons in cement-based stabilized/solidified petroleum solid waste. In this study, real oil refinery sludge samples were stabilized and solidified with various additions of I42.5 and II42.5 cement (Portland and blended cement, respectively) and subject to leaching. The target analytes were total petroleum hydrocarbons, alkanes and 16 polycyclic aromatic hydrocarbons of the EPA priority pollutant list. The experiments showed that the waste was confined in the cement matrix by macroencapsulation. The rapture of the cement structure led to the increase of leachability for most of the hydrocarbons. Leaching of n-alkanes from II42.5 cement-solidified samples was lower than that from I42.5 solidified samples. Leaching of alkanes in the range of n-C(10) to n-C(27) was lower than that of long chain alkanes (>n-C(27)), regardless the amount of cement addition. Generally, increasing the cement content in the solidified waste samples, increased individual alkane leachability. This indicated that cement addition resulted in destabilization of the waste. Addition of I42.5 cement favored immobilization of anthracene, benzo[a]anthracene, benzo[b]fluoroanthene, benzo[k]fluoroanthene, benzo[a]pyrene and dibenzo[a,h]anthracene. However, addition of II42.5 favored 5 out of 16, i.e., naphthalene, anthracene, benzo[b]fluoroanthene, benzo[k]fluoroanthene and dibenzo[a,h]anthracene.

Solidification/stabilization of fly ash from city refuse incinerator facility and heavy metal sludge with cement additives.

PubMed

Cerbo, Atlas Adonis V; Ballesteros, Florencio; Chen, Teng Chien; Lu, Ming-Chun

2017-01-01

Solidification and stabilization are well-known technologies used for treating hazardous waste. These technologies that use cementitious binder have been applied for decades as a final treatment procedure prior to the hazardous waste disposal. In the present work, hazardous waste like fly ash containing high concentrations of heavy metals such Zn (4715.56 mg/kg), Pb (1300.56 mg/kg), and Cu (534.72 mg/kg) and amounts of Ag, Cd, Co, Cr, Mn, and Ni was sampled from a city refuse incinerator facility. This fly ash was utilized in the solidification/stabilization of heavy metal sludge since fly ash has cement-like characteristics. Cement additives such as sodium sulfate, sodium carbonate, and ethylenediaminetetraacetic acid (EDTA) was incorporated to the solidified matrix in order to determine its effect on the solidification/stabilization performance. The solidified matrix was cured for 7, 14, 21, and 28 days prior for its physical and chemical characterizations. The results show that the solidified matrix containing 40% fly ash and 60% cement with heavy metal sludge was the formulation that has the highest fly ash content with a satisfactory strength. The solidified matrix was also able to immobilize the heavy metals both found in the fly ash and sludge based on the toxicity characteristic leaching procedure (TCLP) test. It also shows that the incorporation of sodium carbonate into the solidified matrix not only further improved the compressive strength from 0.36 MPa (without Na 2 CO 3 ) to 0.54 MPa (with Na 2 CO 3 ) but also increased its leaching resistance.

Parametric Study to Determine the Effect of Temperature on Oil Soldifier Performance and the Development of a new Empirical Correlation for Predicting Effectiveness

EPA Science Inventory

Temperature can play a significant role in the efficacy of solidifiers in removing oil slicks on water. We studied and quantified the effect of temperature on the performance of several solidifiers using 5 different types of oils under a newly developed testing protocol by condu...

Real-Time X-Ray Transmission Microscopy of Solidifying Al-In Alloys

NASA Technical Reports Server (NTRS)

Curreri, Peter A.; Kaukler, William F.

1997-01-01

Real-time observations of transparent analog materials have provided insight, yet the results of these observations are not necessarily representative of opaque metallic systems. In order to study the detailed dynamics of the solidification process, we develop the technologies needed for real-time X ray microscopy of solidifying metallic systems, which has not previously been feasible with the necessary resolution, speed, and contrast. In initial studies of Al-In monotectic alloys unidirectionally solidified in an X-ray transparent furnace, in situ records of the evolution of interface morphologies, interfacial solute accumulation, and formation of the monotectic droplets were obtained for the first time: A radiomicrograph of Al-30In grown during aircraft parabolic maneuvers is presented, showing the volumetric phase distribution in this specimen. The benefits of using X-ray microscopy for postsolidification metallography include ease of specimen preparation, increased sensitivity, and three-dimensional analysis of phase distribution. Imaging of the solute boundary layer revealed that the isoconcentration lines are not parallel (as is often assumed) to the growth interface. Striations in the solidified crystal did not accurately decorate the interface position and shape. The monotectic composition alloy under some conditions grew in an uncoupled manner.

Binary translation using peephole translation rules

DOEpatents

Bansal, Sorav; Aiken, Alex

2010-05-04

An efficient binary translator uses peephole translation rules to directly translate executable code from one instruction set to another. In a preferred embodiment, the translation rules are generated using superoptimization techniques that enable the translator to automatically learn translation rules for translating code from the source to target instruction set architecture.

Modeling Spatial Relationships within a Fuzzy Framework.

ERIC Educational Resources Information Center

Petry, Frederick E.; Cobb, Maria A.

1998-01-01

Presents a model for representing and storing binary topological and directional relationships between 2-dimensional objects that is used to provide a basis for fuzzy querying capabilities. A data structure called an abstract spatial graph (ASG) is defined for the binary relationships that maintains all necessary information regarding topology and…

Research on the compressive strength of basic magnesium salts and cyanide slag solidified body

NASA Astrophysics Data System (ADS)

Tu, Yubo; Han, Peiwei; Ye, Shufeng; Wei, Lianqi; Zhang, Xiaomeng; Fu, Guoyan; Yu, Bo

2018-02-01

The solidification of cyanide slag by using basic magnesium salts could reduce pollution and protect the environment. Experiments were carried out to investigate the effects of age, mixing amount of cyanide slag, water cement ratio and molar ratio of MgO to MgSO4 on the compressive strength of basic magnesium salts and cyanide slag solidified body in the present paper. It was found that compressive strength of solidified body increased with the increase of age, and decreased with the increase of mixing amount of cyanide slag and water cement ratio. The molar ratio of MgO to MgSO4 should be controlled in the range from 9 to 11 when the mixing amount of cyanide slag was larger than 80 mass%.

Method of casting articles of a bulk-solidifying amorphous alloy

DOEpatents

Lin, X.; Johnson, W.L.; Peker, A.

1998-08-25

A casting charge of a bulk-solidifying amorphous alloy is cast into a mold from a temperature greater than its crystallized melting temperature, and permitted to solidify to form an article. The oxygen content of the casting charge is limited to an operable level, as excessively high oxygen contents produce premature crystallization during the casting operation. During melting, the casting charge is preferably heated to a temperature above a threshold temperature to eliminate heterogeneous crystallization nucleation sites within the casting charge. The casting charge may be cast from above the threshold temperature, or it may be cooled to the casting temperature of more than the crystallized melting point but not more than the threshold temperature, optionally held at this temperature for a period of time, and thereafter cast. 8 figs.

Method of casting articles of a bulk-solidifying amorphous alloy

DOEpatents

Lin, Xianghong; Johnson, William L.; Peker, Atakan

1998-01-01

A casting charge of a bulk-solidifying amorphous alloy is cast into a mold from a temperature greater than its crystallized melting temperature, and permitted to solidify to form an article. The oxygen content of the casting charge is limited to an operable level, as excessively high oxygen contents produce premature crystallization during the casting operation. During melting, the casting charge is preferably heated to a temperature above a threshold temperature to eliminate heterogeneous crystallization nucleation sites within the casting charge. The casting charge may be cast from above the threshold temperature, or it may be cooled to the casting temperature of more than the crystallized melting point but not more than the threshold temperature, optionally held at this temperature for a period of time, and thereafter cast.

Determining accurate distances to nearby galaxies

NASA Astrophysics Data System (ADS)

Bonanos, Alceste Zoe

2005-11-01

Determining accurate distances to nearby or distant galaxies is a very simple conceptually, yet complicated in practice, task. Presently, distances to nearby galaxies are only known to an accuracy of 10-15%. The current anchor galaxy of the extragalactic distance scale is the Large Magellanic Cloud, which has large (10-15%) systematic uncertainties associated with it, because of its morphology, its non-uniform reddening and the unknown metallicity dependence of the Cepheid period-luminosity relation. This work aims to determine accurate distances to some nearby galaxies, and subsequently help reduce the error in the extragalactic distance scale and the Hubble constant H 0 . In particular, this work presents the first distance determination of the DIRECT Project to M33 with detached eclipsing binaries. DIRECT aims to obtain a new anchor galaxy for the extragalactic distance scale by measuring direct, accurate (to 5%) distances to two Local Group galaxies, M31 and M33, with detached eclipsing binaries. It involves a massive variability survey of these galaxies and subsequent photometric and spectroscopic follow-up of the detached binaries discovered. In this work, I also present a catalog of variable stars discovered in one of the DIRECT fields, M31Y, which includes 41 eclipsing binaries. Additionally, we derive the distance to the Draco Dwarf Spheroidal galaxy, with ~100 RR Lyrae found in our first CCD variability study of this galaxy. A "hybrid" method of discovering Cepheids with ground-based telescopes is described next. It involves applying the image subtraction technique on the images obtained from ground-based telescopes and then following them up with the Hubble Space Telescope to derive Cepheid period-luminosity distances. By re-analyzing ESO Very Large Telescope data on M83 (NGC 5236), we demonstrate that this method is much more powerful for detecting variability, especially in crowded fields. I finally present photometry for the Wolf-Rayet binary WR 20a, which confirmed that the system consists of two extremely massive stars and refined the values of the masses. It is the most massive binary known with an accurate mass determination.

Directional Solidification and Mechanical Properties of NiAl-NiAlTa Alloys

NASA Technical Reports Server (NTRS)

Johnson, D. R.; Chen, X. F.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

1995-01-01

Directional solidification of eutectic alloys is a promising technique for producing in-situ composite materials exhibiting a balance of properties. Consequently, the microstructure, creep strength and fracture toughness of directionally solidified NiAl-NiAlTa alloys were investigated. Directional solidification was performed by containerless processing techniques to minimize alloy contamination. The eutectic composition was found to be NiAl-15.5 at% Ta and well-aligned microstructures were produced at this composition. A near-eutectic alloy of NiAl-14.5Ta was also investigated. Directional solidification of the near-eutectic composition resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The off-eutectic alloy exhibited promising compressive creep strengths compared to other NiAl-based intermetallics, while preliminary testing indicated that the eutectic alloy was competitive with Ni-base single crystal superalloys. The room temperature toughness of these two-phase alloys was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa.

The True Ultracool Binary Fraction Using Spectral Binaries

NASA Astrophysics Data System (ADS)

Bardalez Gagliuffi, Daniella; Burgasser, Adam J.; Schmidt, Sarah J.; Gagné, Jonathan; Faherty, Jacqueline K.; Cruz, Kelle; Gelino, Chris

2018-01-01

Brown dwarfs bridge the gap between stars and giant planets. While the essential mechanisms governing their formation are not well constrained, binary statistics are a direct outcome of the formation process, and thus provide a means to test formation theories. Observational constraints on the brown dwarf binary fraction place it at 10 ‑ 20%, dominated by imaging studies (85% of systems) with the most common separation at 4 AU. This coincides with the resolution limit of state-of-the-art imaging techniques, suggesting that the binary fraction is underestimated. We have developed a separation-independent method to identify and characterize tightly-separated (< 5 AU) binary systems of brown dwarfs as spectral binaries by identifying traces of methane in the spectra of late-M and early-L dwarfs. Imaging follow-up of 17 spectral binaries yielded 3 (18%) resolved systems, corroborating the observed binary fraction, but 5 (29%) known binaries were missed, reinforcing the hypothesis that the short-separation systems are undercounted. In order to find the true binary fraction of brown dwarfs, we have compiled a volume-limited, spectroscopic sample of M7-L5 dwarfs and searched for T dwarf companions. In the 25 pc volume, 4 candidates were found, three of which are already confirmed, leading to a spectral binary fraction of 0.95 ± 0.50%, albeit for a specific combination of spectral types. To extract the true binary fraction and determine the biases of the spectral binary method, we have produced a binary population simulation based on different assumptions of the mass function, age distribution, evolutionary models and mass ratio distribution. Applying the correction fraction resulting from this method to the observed spectral binary fraction yields a true binary fraction of 27 ± 4%, which is roughly within 1σ of the binary fraction obtained from high resolution imaging studies, radial velocity and astrometric monitoring. This method can be extended to identify giant planet companions to young brown dwarfs.

Performance of two-layer thermal barrier systems on directionally solidified Ni-Al-Mo and comparative effects of alloy thermal expansion on system life

NASA Technical Reports Server (NTRS)

Stecura, S.

1980-01-01

A promising two-layer thermal barrier coating system (TBS), Ni-16.4Cr-5.1A1-0.15Y/ZrO2-6.1Y2O3 (all in weight percent), was identified for directionally solidified Ni-Al-Mo (gamma/gamma' alpha). In cyclic furnace tests at 1095 C this system on gamma/gamma' alpha was better than Ni-16. 4Cr-5.1Al-0.15Y/ZrO2-7.8Y2O3 by about 50 percent. In natural gas - oxygen torch rig tests at 1250 C the ZrO2-6.1Y2O3 coating was better than the ZrO2-7.8Y2O3 coating by 95 percent, on MAR-M509 substrates and by 60 percent on gamma/gamma' alpha substrates. Decreasing the coefficient of thermal expansion of the substrate material from 17-18x10 to the -6 power/C (MAR-M200 + Hf and MAR-M509) to 11x10 to the -6 power/C (gamma/gamma' alpha) also resulted in improved TBS life. For example, in natural gas - oxygen torch rig tests at 1250 C, the life of Ni-16.4Cr-5.1Al-0.15Y/ZrO26.1Y2O3 was about 30 percent better on gamma/gamma' alpha than on MAR-M509 substrates. Thus compositional changes in the bond and thermal barrier coatings were shown to have a greater effect on TBS life than does the coefficient of thermal expansion.

Directionally solidified composite systems under evaluation

NASA Technical Reports Server (NTRS)

Ashbrook, R. L.

1974-01-01

The directionally solidified eutectic in-situ composites being evaluated for use as turbine materials range from ductile-ductile systems, where both matrix and reinforcement are ductile, to brittle-brittle systems, where both phases are brittle. The alloys most likely to be used in gas turbine engines in the near term are the lamellar ductile-semi ductile alloys gamma prime-delta, Ni3Al-Ni3Nb and gamma/gamma prime-delta Ni,Cr,Cb,Al/Ni3Al-Ni3Nb and the fibrous ductile-brittle alloys M-MC CoTaC or NiTaC and M-M7C3(Co,Cr,Al)-(Cr,Co)7C3. The results of tests are given which indicate that gamma prime strengthened NiTaC alloys and a (Co,Cr,Al)7C3 have greater tensile strength than the strongest superalloys at temperatures up to about 600 C. The gamma prime-delta and gamma/gamma prime-delta alloys in the Ni,Al,Nb(Cr) systems have greater tensile strength than the superalloys at temperatures greater than 800 C. At low stresses fibrous carbide reinforced eutectic alloys have longer lives at high temperatures than the strongest superalloys. Lamellar delta, Ni3Nb reinforced eutectic alloys have longer lives at high temperatures than the strongest superalloys at all stresses. The experience currently being gained in designing with the brittle ceramics SiC and Si3N4 may eventually be applied to ceramic matrix eutectic in-situ composites. However, the refractory metal fiber reinforced brittle-ductile systems may find acceptance as turbine materials before the ceramic-ceramic brittle-brittle systems.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reeve, Kathlene N.; Holaday, John R.; Choquette, Stephanie M.

New electronics applications demanding enhanced performance and higher operating temperatures have led to continued research in the field of Pb-free solder designs and interconnect solutions. In this paper, recent advances in the microstructural design of Pb-free solders and interconnect systems were discussed by highlighting two topics: increasing β-Sn nucleation in Sn-based solders, and isothermally solidified interconnects using transient liquid phases. Issues in β-Sn nucleation in Sn-based solders were summarized in the context of Swenson’s 2007 review of the topic. Recent advancements in the areas of alloy composition manipulation, nucleating heterogeneities, and rapid solidification were discussed, and a proposal based onmore » a multi-faceted solidification approach involving the promotion of constitutional undercooling and nucleating heterogeneities was outlined for future research. The second half of the paper analyzed two different approaches to liquid phase diffusion bonding as a replacement for high-Pb solders, one based on the application of the pseudo-binary Cu-Ni-Sn ternary system, and the other on a proposed thermodynamic framework for identifying potential ternary alloys for liquid phase diffusion bonding. Furthermore, all of the concepts reviewed relied upon the fundamentals of thermodynamics, kinetics, and solidification, to which Jack Smith substantially contributed during his scientific career.« less

Microstructure and Interfacial Reactions During Vacuum Brazing of Stainless Steel to Titanium Using Ag-28 pct Cu Alloy

NASA Astrophysics Data System (ADS)

Laik, A.; Shirzadi, A. A.; Sharma, G.; Tewari, R.; Jayakumar, T.; Dey, G. K.

2015-02-01

Microstructural evolution and interfacial reactions during vacuum brazing of grade-2 Ti and 304L-type stainless steel (SS) using eutectic alloy Ag-28 wt pct Cu were investigated. A thin Ni-depleted zone of -Fe(Cr, Ni) solid solution formed on the SS-side of the braze zone (BZ). Cu from the braze alloy, in combination with the dissolved Fe and Ti from the base materials, formed a layer of ternary compound , adjacent to Ti in the BZ. In addition, four binary intermetallic compounds, CuTi, CuTi, CuTi and CuTi formed as parallel contiguous layers in the BZ. The unreacted Ag solidified as islands within the layers of CuTi and CuTi. Formation of an amorphous phase at certain locations in the BZ could be revealed. The -Ti(Cu) layer, formed due to diffusion of Cu into Ti-based material, transformed to an -Ti + CuTi eutectoid with lamellar morphology. Tensile test showed that the brazed joints had strength of 112 MPa and failed at the BZ. The possible sequence of events that led to the final microstructure and the mode of failure of these joints were delineated.

Macrosegregation Resulting from Directional Solidification Through an Abrupt Change in Cross-Sections

NASA Technical Reports Server (NTRS)

Lauer, M.; Poirier, D. R.; Ghods, M.; Tewari, S. N.; Grugel, R. N.

2017-01-01

Simulations of the directional solidification of two hypoeutectic alloys (Al-7Si alloy and Al-19Cu) and resulting macrosegregation patterns are presented. The casting geometries include abrupt changes in cross-section from a larger width of 9.5 mm to a narrower 3.2 mm width then through an expansion back to a width of 9.5 mm. The alloys were chosen as model alloys because they have similar solidification shrinkages, but the effect of Cu on changing the density of the liquid alloy is about an order of magnitude greater than that of Si. The simulations compare well with experimental castings that were directionally solidified in a graphite mold in a Bridgman furnace. In addition to the simulations of the directional solidification in graphite molds, some simulations were effected for solidification in an alumina mold. This study showed that the mold must be included in numerical simulations of directional solidification because of its effect on the temperature field and solidification. For the model alloys used for the study, the simulations clearly show the interaction of the convection field with the solidifying alloys to produce a macrosegregation pattern known as "steepling" in sections with a uniform width. Details of the complex convection- and segregation-patterns at both the contraction and expansion of the cross-sectional area are revealed by the computer simulations. The convection and solidification through the expansions suggest a possible mechanism for the formation of stray grains. The computer simulations and the experimental castings have been part of on-going ground-based research with the goal of providing necessary background for eventual experiments aboard the ISS. For casting practitioners, the results of the simulations demonstrate that computer simulations should be applied to reveal interactions between alloy solidification properties, solidification conditions, and mold geometries on macrosegregation. The simulations also presents the possibility of engineering the mold-material to avoid, or mitigate, the effects of thermosolutal convection and macrosegregation by selecting a mold material with suitable thermal properties, especially its thermal conductivity.

Wind-accelerated orbital evolution in binary systems with giant stars

NASA Astrophysics Data System (ADS)

Chen, Zhuo; Blackman, Eric G.; Nordhaus, Jason; Frank, Adam; Carroll-Nellenback, Jonathan

2018-01-01

Using 3D radiation-hydrodynamic simulations and analytic theory, we study the orbital evolution of asymptotic giant branch (AGB) binary systems for various initial orbital separations and mass ratios, and thus different initial accretion modes. The time evolution of binary separations and orbital periods are calculated directly from the averaged mass-loss rate, accretion rate and angular momentum loss rate. We separately consider spin-orbit synchronized and zero-spin AGB cases. We find that the angular momentum carried away by the mass loss together with the mass transfer can effectively shrink the orbit when accretion occurs via wind-Roche lobe overflow. In contrast, the larger fraction of mass lost in Bondi-Hoyle-Lyttleton accreting systems acts to enlarge the orbit. Synchronized binaries tend to experience stronger orbital period decay in close binaries. We also find that orbital period decay is faster when we account for the non-linear evolution of the accretion mode as the binary starts to tighten. This can increase the fraction of binaries that result in common envelope, luminous red novae, Type Ia supernovae and planetary nebulae with tight central binaries. The results also imply that planets in the habitable zone around white dwarfs are unlikely to be found.

The Eclipsing Central Stars of the Planetary Nebulae Lo 16 and PHR J1040-5417

NASA Astrophysics Data System (ADS)

Hillwig, Todd C.; Frew, David; Jones, David; Crispo, Danielle

2017-01-01

Binary central stars of planetary nebula are a valuable tool in understanding common envelope evolution. In these cases both the resulting close binary system and the expanding envelope (the planetary nebula) can be studied directly. In order to compare observed systems with common envelope evolution models we need to determine precise physical parameters of the binaries and the nebulae. Eclipsing central stars provide us with the best opportunity to determine high precision values for mass, radius, and temperature of the component stars in these close binaries. We present photometry and spectroscopy for two of these eclipsing systems; the central stars of Lo 16 and PHR 1040-5417. Using light curves and radial velocity curves along with binary modeling we provide physical parameters for the stars in both of these systems.

Classification of X-ray sources in the direction of M31

NASA Astrophysics Data System (ADS)

Vasilopoulos, G.; Hatzidimitriou, D.; Pietsch, W.

2012-01-01

M31 is our nearest spiral galaxy, at a distance of 780 kpc. Identification of X-ray sources in nearby galaxies is important for interpreting the properties of more distant ones, mainly because we can classify nearby sources using both X-ray and optical data, while more distant ones via X-rays alone. The XMM-Newton Large Project for M31 has produced an abundant sample of about 1900 X-ray sources in the direction of M31. Most of them remain elusive, giving us little signs of their origin. Our goal is to classify these sources using criteria based on properties of already identified ones. In particular we construct candidate lists of high mass X-ray binaries, low mass X-ray binaries, X-ray binaries correlated with globular clusters and AGN based on their X-ray emission and the properties of their optical counterparts, if any. Our main methodology consists of identifying particular loci of X-ray sources on X-ray hardness ratio diagrams and the color magnitude diagrams of their optical counterparts. Finally, we examined the X-ray luminosity function of the X-ray binaries populations.

Multi-messenger studies of compact binary mergers in the in the ngVLA era

NASA Astrophysics Data System (ADS)

Corsi, Alessandra

2018-01-01

We explore some of the scientific opportunities that the next generation Very Large Array (ngVLA) will open in the field of multi-messenger time-domain astronomy. We focus on compact binary mergers, golden astrophysical targets of ground-based gravitational wave (GW) detectors such as advanced LIGO. A decade from now, a large number of these mergers is likely to be discovered by a world-wide network of GW detectors. We discuss how a radio array with 10 times the sensitivity of the current Karl G. Jansky VLA and 10 times the resolution, would enable resolved radio continuum studies of binary merger hosts, probing regions of the galaxy undergoing star formation (which can be heavily obscured by dust and gas), AGN components, and mapping the offset distribution of the mergers with respect to the host galaxy light. For compact binary mergers containing at least one neutron star (NS), from which electromagnetic counterparts are expected to exist, we show how the ngVLA would enable direct size measurements of the relativistic merger ejecta and probe, for the first time directly, their dynamics.

Bondi-Hoyle-Lyttleton Accretion onto Binaries

NASA Astrophysics Data System (ADS)

Antoni, Andrea; MacLeod, Morgan; Ramírez-Ruiz, Enrico

2018-01-01

Binary stars are not rare. While only close binary stars will eventually interact with one another, even the widest binary systems interact with their gaseous surroundings. The rates of accretion and the gaseous drag forces arising in these interactions are the key to understanding how these systems evolve. This poster examines accretion flows around a binary system moving supersonically through a background gas. We perform three-dimensional hydrodynamic simulations of Bondi-Hoyle-Lyttleton accretion using the adaptive mesh refinement code FLASH. We simulate a range of values of semi-major axis of the orbit relative to the gravitational focusing impact parameter of the pair. On large scales, gas is gravitationally focused by the center-of-mass of the binary, leading to dynamical friction drag and to the accretion of mass and momentum. On smaller scales, the orbital motion imprints itself on the gas. Notably, the magnitude and direction of the forces acting on the binary inherit this orbital dependence. The long-term evolution of the binary is determined by the timescales for accretion, slow down of the center-of-mass, and decay of the orbit. We use our simulations to measure these timescales and to establish a hierarchy between them. In general, our simulations indicate that binaries moving through gaseous media will slow down before the orbit decays.

The fate of close encounters between binary stars and binary supermassive black holes

NASA Astrophysics Data System (ADS)

Wang, Yi-Han; Leigh, Nathan; Yuan, Ye-Fei; Perna, Rosalba

2018-04-01

The evolution of main-sequence binaries that reside in the Galactic Centre can be heavily influenced by the central supermassive black hole (SMBH). Due to these perturbative effects, the stellar binaries in dense environments are likely to experience mergers, collisions, or ejections through secular and/or non-secular interactions. More direct interactions with the central SMBH are thought to produce hypervelocity stars (HVSs) and tidal disruption events (TDEs). In this paper, we use N-body simulations to study the dynamics of stellar binaries orbiting a central SMBH primary with an outer SMBH secondary orbiting this inner triple. The effects of the secondary SMBH on the event rates of HVSs, TDEs, and stellar mergers are investigated, as a function of the SMBH-SMBH binary mass ratio. Our numerical experiments reveal that, relative to the isolated SMBH case, the TDE and HVS rates are enhanced for, respectively, the smallest and largest mass ratio SMBH-SMBH binaries. This suggests that the observed event rates of TDEs and HVSs have the potential to serve as a diagnostic of the mass ratio of a central SMBH-SMBH binary. The presence of a secondary SMBH also allows for the creation of hypervelocity binaries. Observations of these systems could thus constrain the presence of a secondary SMBH in the Galactic Centre.

Fast optimization of binary clusters using a novel dynamic lattice searching method.

PubMed

Wu, Xia; Cheng, Wen

2014-09-28

Global optimization of binary clusters has been a difficult task despite of much effort and many efficient methods. Directing toward two types of elements (i.e., homotop problem) in binary clusters, two classes of virtual dynamic lattices are constructed and a modified dynamic lattice searching (DLS) method, i.e., binary DLS (BDLS) method, is developed. However, it was found that the BDLS can only be utilized for the optimization of binary clusters with small sizes because homotop problem is hard to be solved without atomic exchange operation. Therefore, the iterated local search (ILS) method is adopted to solve homotop problem and an efficient method based on the BDLS method and ILS, named as BDLS-ILS, is presented for global optimization of binary clusters. In order to assess the efficiency of the proposed method, binary Lennard-Jones clusters with up to 100 atoms are investigated. Results show that the method is proved to be efficient. Furthermore, the BDLS-ILS method is also adopted to study the geometrical structures of (AuPd)79 clusters with DFT-fit parameters of Gupta potential.

Further studies on criteria for the onset of dynamical instability in general three-body systems

NASA Technical Reports Server (NTRS)

Pendleton, Y. J.; Black, D. C.

1983-01-01

Numerical experiments designed for the elucidation of the conditions under which self-gravitating, three-body systems become dynamically unstable are examined of the cases of four orbital configuration types: circular, prograde, and coplanar; circular, retrograde, and coplanar; circular, direct, and inclined; and eccentric, direct, and coplanar. Results indicate that orbital inclination does not significantly affect stability in 'outer planet' configurations, while the stability of 'inner planet' configurations, where the tertiary is in close orbit about one member of the binary, is markedly less affected, once the relative orbital inclination is greater than 50 deg. It is found that the onset of dynamical instability is only weakly dependent on the eccentricity of either the binary or tertiary orbit, as long as the mass of the tertiary is comparable to the reduced mass of the binary.

Design of near-field irregular diffractive optical elements by use of a multiresolution direct binary search method.

PubMed

Li, Jia-Han; Webb, Kevin J; Burke, Gerald J; White, Daniel A; Thompson, Charles A

2006-05-01

A multiresolution direct binary search iterative procedure is used to design small dielectric irregular diffractive optical elements that have subwavelength features and achieve near-field focusing below the diffraction limit. Designs with a single focus or with two foci, depending on wavelength or polarization, illustrate the possible functionalities available from the large number of degrees of freedom. These examples suggest that the concept of such elements may find applications in near-field lithography, wavelength-division multiplexing, spectral analysis, and polarization beam splitters.

Numerical simulation of freckle formation in directional solidification of binary alloys

NASA Technical Reports Server (NTRS)

Felicelli, Sergio D.; Heinrich, Juan C.; Poirier, David R.

1992-01-01

A mathematical model of solidification is presented which simulates the formation of segregation models known as 'freckles' during directional solidification of binary alloys. The growth of the two-phase or dendritic zone is calculated by solving the coupled equations of momentum, energy, and solute transport, as well as maintaining the thermodynamic constraints dictated by the phase diagram of the alloy. Calculations for lead-tin alloys show that the thermosolutal convection in the dendritic zone during solidification can produce heavily localized inhomogeneities in the composition of the final alloy.

Particle tracking experiments in match-index-refraction porous media.

PubMed

Lachhab, Ahmed; Zhang, You-Kuan; Muste, Marian V I

2008-01-01

A low-cost, noninvasive, three-dimensional (3D), particle tracking velocimetry system was designed and built to investigate particle movement in match-index-refraction porous media. Both a uniform load of the glass beads of the same diameter and a binary load of the glass beads of two diameters were used. The purpose of the experiments is to study the effect of the two loads on the trajectories, velocity distribution, and spreading of small physical particles. A total of 35 particles were released and tracked in the uniform load and 46 in the binary load. The 3D trajectory of each particle was recorded with two video camcorders and analyzed. It is found that the particle's velocity, trajectory, and spreading are very sensitive to its initial location and that the smaller pore size or heterogeneity in the binary load increases the particles' velocity and enhances their spreading as compared with the uniform load. The experiments also verified the previous finding that the distribution of the particle velocities are lognormal in the longitudinal direction and Gaussian in two transverse directions and that the particle spreading is much larger along the longitudinal direction than along the traverse directions.

Vitrification of radioactive contaminated soil by means of microwave energy

NASA Astrophysics Data System (ADS)

Yuan, Xun; Qing, Qi; Zhang, Shuai; Lu, Xirui

2017-03-01

Simulated radioactive contaminated soil was successfully vitrified by microwave sintering technology and the solidified body were systematically studied by Raman, XRD and SEM-EDX. The Raman results show that the solidified body transformed to amorphous structure better at higher temperature (1200 °C). The XRD results show that the metamictization has been significantly enhanced by the prolonged holding time at 1200 °C by microwave sintering, while by conventional sintering technology other crystal diffraction peaks, besides of silica at 2θ = 27.830°, still exist after being treated at 1200 °C for much longer time. The SEM-EDX discloses the micro-morphology of the sample and the uniform distribution of Nd element. All the results show that microwave technology performs vitrification better than the conventional sintering method in solidifying radioactive contaminated soil.

Galaxy Rotation and Rapid Supermassive Binary Coalescence

NASA Astrophysics Data System (ADS)

Holley-Bockelmann, Kelly; Khan, Fazeel Mahmood

2015-09-01

Galaxy mergers usher the supermassive black hole (SMBH) in each galaxy to the center of the potential, where they form an SMBH binary. The binary orbit shrinks by ejecting stars via three-body scattering, but ample work has shown that in spherical galaxy models, the binary separation stalls after ejecting all the stars in its loss cone—this is the well-known final parsec problem. However, it has been shown that SMBH binaries in non-spherical galactic nuclei harden at a nearly constant rate until reaching the gravitational wave regime. Here we use a suite of direct N-body simulations to follow SMBH binary evolution in both corotating and counterrotating flattened galaxy models. For N > 500 K, we find that the evolution of the SMBH binary is convergent and is independent of the particle number. Rotation in general increases the hardening rate of SMBH binaries even more effectively than galaxy geometry alone. SMBH binary hardening rates are similar for co- and counterrotating galaxies. In the corotating case, the center of mass of the SMBH binary settles into an orbit that is in corotation resonance with the background rotating model, and the coalescence time is roughly a few 100 Myr faster than a non-rotating flattened model. We find that counterrotation drives SMBHs to coalesce on a nearly radial orbit promptly after forming a hard binary. We discuss the implications for gravitational wave astronomy, hypervelocity star production, and the effect on the structure of the host galaxy.

GALAXY ROTATION AND RAPID SUPERMASSIVE BINARY COALESCENCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holley-Bockelmann, Kelly; Khan, Fazeel Mahmood, E-mail: k.holley@vanderbilt.edu

2015-09-10

Galaxy mergers usher the supermassive black hole (SMBH) in each galaxy to the center of the potential, where they form an SMBH binary. The binary orbit shrinks by ejecting stars via three-body scattering, but ample work has shown that in spherical galaxy models, the binary separation stalls after ejecting all the stars in its loss cone—this is the well-known final parsec problem. However, it has been shown that SMBH binaries in non-spherical galactic nuclei harden at a nearly constant rate until reaching the gravitational wave regime. Here we use a suite of direct N-body simulations to follow SMBH binary evolutionmore » in both corotating and counterrotating flattened galaxy models. For N > 500 K, we find that the evolution of the SMBH binary is convergent and is independent of the particle number. Rotation in general increases the hardening rate of SMBH binaries even more effectively than galaxy geometry alone. SMBH binary hardening rates are similar for co- and counterrotating galaxies. In the corotating case, the center of mass of the SMBH binary settles into an orbit that is in corotation resonance with the background rotating model, and the coalescence time is roughly a few 100 Myr faster than a non-rotating flattened model. We find that counterrotation drives SMBHs to coalesce on a nearly radial orbit promptly after forming a hard binary. We discuss the implications for gravitational wave astronomy, hypervelocity star production, and the effect on the structure of the host galaxy.« less

Experimental Studies of the Interaction Between a Parallel Shear Flow and a Directionally-Solidifying Front

NASA Technical Reports Server (NTRS)

Zhang, Meng; Maxworthy, Tony

1999-01-01

It has long been recognized that flow in the melt can have a profound influence on the dynamics of a solidifying interface and hence the quality of the solid material. In particular, flow affects the heat and mass transfer, and causes spatial and temporal variations in the flow and melt composition. This results in a crystal with nonuniform physical properties. Flow can be generated by buoyancy, expansion or contraction upon phase change, and thermo-soluto capillary effects. In general, these flows can not be avoided and can have an adverse effect on the stability of the crystal structures. This motivates crystal growth experiments in a microgravity environment, where buoyancy-driven convection is significantly suppressed. However, transient accelerations (g-jitter) caused by the acceleration of the spacecraft can affect the melt, while convection generated from the effects other than buoyancy remain important. Rather than bemoan the presence of convection as a source of interfacial instability, Hurle in the 1960s suggested that flow in the melt, either forced or natural convection, might be used to stabilize the interface. Delves considered the imposition of both a parabolic velocity profile and a Blasius boundary layer flow over the interface. He concluded that fast stirring could stabilize the interface to perturbations whose wave vector is in the direction of the fluid velocity. Forth and Wheeler considered the effect of the asymptotic suction boundary layer profile. They showed that the effect of the shear flow was to generate travelling waves parallel to the flow with a speed proportional to the Reynolds number. There have been few quantitative, experimental works reporting on the coupling effect of fluid flow and morphological instabilities. Huang studied plane Couette flow over cells and dendrites. It was found that this flow could greatly enhance the planar stability and even induce the cell-planar transition. A rotating impeller was buried inside the sample cell, driven by an outside rotating magnet, in order to generate the flow. However, it appears that this was not a well-controlled flow and may also have been unsteady. In the present experimental study, we want to study how a forced parallel shear flow in a Hele-Shaw cell interacts with the directionally solidifying crystal interface. The comparison of experimental data show that the parallel shear flow in a Hele-Shaw cell has a strong stabilizing effect on the planar interface by damping the existing initial perturbations. The flow also shows a stabilizing effect on the cellular interface by slightly reducing the exponential growth rate of cells. The left-right symmetry of cells is broken by the flow with cells tilting toward the incoming flow direction. The tilting angle increases with the velocity ratio. The experimental results are explained through the parallel flow effect on lateral solute transport. The phenomenon of cells tilting against the flow is consistent with the numerical result of Dantzig and Chao.

Applications Of Binary Image Analysis Techniques

NASA Astrophysics Data System (ADS)

Tropf, H.; Enderle, E.; Kammerer, H. P.

1983-10-01

After discussing the conditions where binary image analysis techniques can be used, three new applications of the fast binary image analysis system S.A.M. (Sensorsystem for Automation and Measurement) are reported: (1) The human view direction is measured at TV frame rate while the subject's head is free movable. (2) Industrial parts hanging on a moving conveyor are classified prior to spray painting by robot. (3) In automotive wheel assembly, the eccentricity of the wheel is minimized by turning the tyre relative to the rim in order to balance the eccentricity of the components.

Wide- and contact-binary formation in substructured young stellar clusters

NASA Astrophysics Data System (ADS)

Dorval, J.; Boily, C. M.; Moraux, E.; Roos, O.

2017-02-01

We explore with collisional gravitational N-body models the evolution of binary stars in initially fragmented and globally subvirial clusters of stars. Binaries are inserted in the (initially) clumpy configurations so as to match the observed distributions of the field-binary-stars' semimajor axes a and binary fraction versus primary mass. The dissolution rate of wide binaries is very high at the start of the simulations, and is much reduced once the clumps are eroded by the global infall. The transition between the two regimes is sharper as the number of stars N is increased, from N = 1.5 k up to 80 k. The fraction of dissolved binary stars increases only mildly with N, from ≈15 per cent to ≈25 per cent for the same range in N. We repeated the calculation for two initial system mean number densities of 6 per pc3 (low) and 400 per pc3 (high). We found that the longer free-fall time of the low-density runs allows for prolonged binary-binary interactions inside clumps and the formation of very tight (a ≈ 0.01 au) binaries by exchange collisions. This is an indication that the statistics of such compact binaries bear a direct link to their environment at birth. We also explore the formation of wide (a ≳ 5 × 104 au) binaries and find a low (≈0.01 per cent) fraction mildly bound to the central star cluster. The high-precision astrometric mission Gaia could identify them as outflowing shells or streams.

Landmine Detection by Scatter Radiation Radiography.

DTIC Science & Technology

1987-07-02

and sucrose. The explosive substitute is solidified Karo TMLih Corn Syrup . While this material is not sucrose, it has similar elemental composition and...photon interaction characteristics. Upon heating, a portion of the fructose contained in the syrup is converted to sucrose. A number of test batches...solidified Karo TMLight Corn Syrup are each subjected to the four spectra: 80, 100, 150, and 200 KVp, each filtered by 4.75 mm of beryllium inherent

3D CAFE modeling of grain structures: application to primary dendritic and secondary eutectic solidification

NASA Astrophysics Data System (ADS)

Carozzani, T.; Digonnet, H.; Gandin, Ch-A.

2012-01-01

A three-dimensional model is presented for the prediction of grain structures formed in casting. It is based on direct tracking of grain boundaries using a cellular automaton (CA) method. The model is fully coupled with a solution of the heat flow computed with a finite element (FE) method. Several unique capabilities are implemented including (i) the possibility to track the development of several types of grain structures, e.g. dendritic and eutectic grains, (ii) a coupling scheme that permits iterations between the FE method and the CA method, and (iii) tabulated enthalpy curves for the solid and liquid phases that offer the possibility to work with multicomponent alloys. The present CAFE model is also fully parallelized and runs on a cluster of computers. Demonstration is provided by direct comparison between simulated and recorded cooling curves for a directionally solidified aluminum-7 wt% silicon alloy.

Processing eutectics in space

NASA Technical Reports Server (NTRS)

Douglas, F. C.; Galasso, F. S.

1974-01-01

Experimental work is reported which was directed toward obtaining interface shape control while a numerical thermal analysis program was being made operational. An experimental system was developed in which the solid-liquid interface in a directionally solidified aluminum-nickel eutectic could be made either concave to the melt or convex to the melt. This experimental system provides control over the solid-liquid interface shape and can be used to study the effect of such control on the microstructure. The SINDA thermal analysis program, obtained from Marshall Space Flight Center, was used to evaluate experimental directional solidification systems for the aluminum-nickel and the aluminum-copper eutectics. This program was applied to a three-dimensional ingot, and was used to calculate the thermal profiles in axisymmetric heat flow. The results show that solid-liquid interface shape control can be attained with physically realizable thermal configurations and the magnitudes of the required thermal inputs were indicated.

The Trojan Horse method for nuclear astrophysics: Recent results for direct reactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumino, A.; Gulino, M.; Spitaleri, C.

2014-05-09

The Trojan Horse method is a powerful indirect technique to determine the astrophysical factor for binary rearrangement processes A+x→b+B at astrophysical energies by measuring the cross section for the Trojan Horse (TH) reaction A+a→B+b+s in quasi free kinematics. The Trojan Horse Method has been successfully applied to many reactions of astrophysical interest, both direct and resonant. In this paper, we will focus on direct sub-processes. The theory of the THM for direct binary reactions will be shortly presented based on a few-body approach that takes into account the off-energy-shell effects and initial and final state interactions. Examples of recent resultsmore » will be presented to demonstrate how THM works experimentally.« less

Shuttle Flight Experiment on USMP-4: In Situ Monitoring of Crystal Growth Using MEPHISTO

NASA Technical Reports Server (NTRS)

Abbaschian, Reza; deGroh, Henry C., III; Leonardi, E.; deVahlDavis, Graham; Coriell, Sam; Cambon, Gerard

2001-01-01

This reports on the MEPHISTO-4 experiment on the Space Shuttle Columbia, STS-87, November 19-December 5, 1997. Involved were NASA; the University of Florida at Gainesville; groups from France that developed and built the furnace; the National Institute of Standards and Technology; The University of New South Wales, Australia; and Purdue University. This was a solidification study in which three long rods of Bismuth- 1 at.% Tin were directionally solidified. The goals were to solidify in an environment free of natural convection; to determine the relationship among solidification growth velocity, growth mode, and temperature; and determine the diffusivity of Sn in Bi. The flight samples grew with a planar solid/liquid interface at velocities less than 3.4 gm/s, and cellular growth was present at velocities greater than 6.7 um/s; grain orientation influenced the planar to cellular transition. The temperature gradient in the liquid was 204 K/cm. The s/l interface was flat with slight concavity. Diffusion-dominated conditions were present during MEPHISTO-4. The Seebeck technique was used to determine the s/I interface temperature during growth, however, to date, analysis of the Seebeck results has not yielded a reliable measurement of the interface temperature. The partition coefficient for Bi alloyed with Sn was measured, k = 0.029.

Properties of WZ21 (%wt) alloy processed by a powder metallurgy route.

PubMed

Cabeza, Sandra; Garcés, Gerardo; Pérez, Pablo; Adeva, Paloma

2015-06-01

Microstructure, mechanical properties and corrosion behaviour of WZ21 (%wt) alloy prepared by a powder metallurgy route from rapidly solidified powders have been studied. Results were compared to those of the same alloy prepared through a conventional route of casting and extrusion. The microstructure of the extruded ingot consisted of α-Mg grains and Mg3Zn3Y2 (W-phase) and LPSO-phase particles located at grain boundaries. Moreover, stacking faults were also observed within α-Mg grains. The alloy processed by the powder metallurgy route exhibited a more homogeneous and finer microstructure, with a grain size of 2 μm. In this case W-phase and Mg24Y5 phase were identified, but not the LPSO-phase. The microstructural refinement induced by the use of rapidly solidified powders strengthened the alloy at room temperature and promoted superplasticity at higher strain rates. Corrosion behaviour in PBS medium evidenced certain physical barrier effect of the almost continuous arrangements of second phases aligned along the extrusion direction in conventionally processed WZ21 alloy, with a stable tendency around 7 mm/year. On the other hand, powder metallurgy processing promoted significant pitting corrosion, inducing accelerated corrosion rate during prolonged immersion times. Copyright © 2015 Elsevier Ltd. All rights reserved.

Ultrafast synchrotron X-ray imaging studies of microstructure fragmentation in solidification under ultrasound

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Bing; Tan, Dongyue; Lee, Tung Lik

Ultrasound processing of metal alloys is an environmental friendly and promising green technology for liquid metal degassing and microstructural refinement. However many fundamental issues in this field are still not fully understood, because of the difficulties in direct observation of the dynamic behaviours caused by ultrasound inside liquid metal and semisolid metals during the solidification processes. In this paper, we report a systematic study using the ultrafast synchrotron X-ray imaging (up to 271,554 frame per second) technique available at the Advanced Photon Source, USA and Diamond Light Source, UK to investigate the dynamic interactions between the ultrasonic bubbles/acoustic flow andmore » the solidifying phases in a Bi-8%Zn alloy. The experimental results were complimented by numerical modelling. The chaotic bubble implosion and dynamic bubble oscillations were revealed in-situ for the first time in liquid metal and semisolid metal. The fragmentation of the solidifying Zn phases and breaking up of the liquid-solid interface by ultrasonic bubbles and enhanced acoustic flow were clearly demonstrated and agreed very well with the theoretical calculations. The research provides unambiguous experimental evidence and robust theoretical interpretation in elucidating the dominant mechanisms of microstructure fragmentation and refinement in solidification under ultrasound.« less

Ultrafast synchrotron X-ray imaging studies of microstructure fragmentation in solidification under ultrasound

DOE PAGES

Wang, Bing; Tan, Dongyue; Lee, Tung Lik; ...

2017-11-03

Ultrasound processing of metal alloys is an environmental friendly and promising green technology for liquid metal degassing and microstructural refinement. However many fundamental issues in this field are still not fully understood, because of the difficulties in direct observation of the dynamic behaviours caused by ultrasound inside liquid metal and semisolid metals during the solidification processes. In this paper, we report a systematic study using the ultrafast synchrotron X-ray imaging (up to 271,554 frame per second) technique available at the Advanced Photon Source, USA and Diamond Light Source, UK to investigate the dynamic interactions between the ultrasonic bubbles/acoustic flow andmore » the solidifying phases in a Bi-8%Zn alloy. The experimental results were complimented by numerical modelling. The chaotic bubble implosion and dynamic bubble oscillations were revealed in-situ for the first time in liquid metal and semisolid metal. The fragmentation of the solidifying Zn phases and breaking up of the liquid-solid interface by ultrasonic bubbles and enhanced acoustic flow were clearly demonstrated and agreed very well with the theoretical calculations. The research provides unambiguous experimental evidence and robust theoretical interpretation in elucidating the dominant mechanisms of microstructure fragmentation and refinement in solidification under ultrasound.« less

Solidification rate influence on orientation and mechanical properties of MAR-M-246+Hf

NASA Technical Reports Server (NTRS)

Hamilton, D.

1983-01-01

The influence of solidification rates on the orientation and mechanical properties of MAR-M-246+Hf was studied. The preferred orientation was found to be (001) for single crystals, with all samples with 45 degrees of (001). Tensile tests were performed at room temperature. The anisotropy of directionally solidified MAR-M-246+Hf was demonstrated by gage section deformation. Dendrite arm spacing and crystal growth were found to depend on solidification rates and source material conditions. The greatest strength occurred at lower solidification rates. Some single crystals were grown by control of growth rates without seeding.

Nonlinear heat transfer and structural analyses of SSME turbine blades

NASA Technical Reports Server (NTRS)

Abdul-Aziz, A.; Kaufman, A.

1987-01-01

Three-dimensional nonlinear finite-element heat transfer and structural analyses were performed for the first stage high-pressure fuel turbopump blade of the space shuttle main engine (SSME). Directionally solidified (DS) MAR-M 246 material properties were considered for the analyses. Analytical conditions were based on a typical test stand engine cycle. Blade temperature and stress-strain histories were calculated using MARC finite-element computer code. The study was undertaken to assess the structural response of an SSME turbine blade and to gain greater understanding of blade damage mechanisms, convective cooling effects, and the thermal-mechanical effects.

CAFE simulation of columnar-to-equiaxed transition in Al-7wt%Si alloys directionally solidified under microgravity

NASA Astrophysics Data System (ADS)

Liu, D. R.; Mangelinck-Noël, N.; Gandin, Ch-A.; Zimmermann, G.; Sturz, L.; Nguyen Thi, H.; Billia, B.

2016-03-01

A two-dimensional multi-scale cellular automaton - finite element (CAFE) model is used to simulate grain structure evolution and microsegregation formation during solidification of refined Al-7wt%Si alloys under microgravity. The CAFE simulations are first qualitatively compared with the benchmark experimental data under microgravity. Qualitative agreement is obtained for the position of columnar to equiaxed transition (CET) and the CET transition mode (sharp or progressive). Further comparisons of the distributions of grain elongation factor and equivalent diameter are conducted and reveal a fair quantitative agreement.

MHD oxidant intermediate temperature ceramic heater study

NASA Technical Reports Server (NTRS)

Carlson, A. W.; Chait, I. L.; Saari, D. P.; Marksberry, C. L.

1981-01-01

The use of three types of directly fired ceramic heaters for preheating oxygen enriched air to an intermediate temperature of 1144K was investigated. The three types of ceramic heaters are: (1) a fixed bed, periodic flow ceramic brick regenerative heater; (2) a ceramic pebble regenerative heater. The heater design, performance and operating characteristics under conditions in which the particulate matter is not solidified are evaluated. A comparison and overall evaluation of the three types of ceramic heaters and temperature range determination at which the particulate matter in the MHD exhaust gas is estimated to be a dry powder are presented.

Nozzle for superconducting fiber production

DOEpatents

Righi, Jamal

1992-11-17

A nozzle apparatus for producing flexible fibers of superconducting material receives melted material from a crucible for containing a charge of the superconducting material. The material is melted in the crucible and falls in a stream through a bottom hole in the crucible. The stream falls through a protecting collar which maintains the stream at high temperatures. The stream is then supplied through the downwardly directed nozzle where it is subjected to a high velocity air flow which breaks the melted superconducting material into ligaments which solidify into the flexible fibers. The fibers are collected by blowing them against a porous cloth.

Low cycle fatigue properties of MAR-M-246 Hf in hydrogen. [a cast nickel-base alloy

NASA Technical Reports Server (NTRS)

Warren, J. R.

1979-01-01

The transverse, low cycle fatigue properties were determined for directionally solidified and single crystal samples of a cast nickel-base alloy proposed for use in space propulsion systems in pure or partial high pressure hydrogen environments at elevated temperatures. The test temperature was 760 C (1400F) and the pressure of the gaseous hydrogen was 34.5 MPa (5000 psig). Low cycle fatique life was established by strain controlled testing using smooth specimens and a servohydraulic closed-loop test machine modified with a high pressure environmental chamber. Results and conclusions are discussed.

Wear of Selected Oxide Ceramics and Coatings

NASA Technical Reports Server (NTRS)

Miyoshi, K.; Sayir, A.; Farmer, S. C.

2005-01-01

The use of oxide ceramics and coatings for moving mechanical components operating in high-temperature, oxidizing environments creates a need to define the tribological performance and durability of these materials. Results of research focusing on the wear behavior and properties of Al2O3/ZrO2 (Y2O3) eutectics and coatings under dry sliding conditions are discussed. The importance of microstructure and composition on wear properties of directionally solidified oxide eutectics is illustrated. Wear data of selected oxide-, nitride-, and carbide-based ceramics and coatings are given for temperatures up to 973K in air.

Phasor Analysis of Binary Diffraction Gratings with Different Fill Factors

ERIC Educational Resources Information Center

Martinez, Antonio; Sanchez-Lopez, Ma del Mar; Moreno, Ignacio

2007-01-01

In this work, we present a simple analysis of binary diffraction gratings with different slit widths relative to the grating period. The analysis is based on a simple phasor technique directly derived from the Huygens principle. By introducing a slit phasor and a grating phasor, the intensity of the diffracted orders and the grating's resolving…

The binary protein-protein interaction landscape of Escherichia coli

PubMed Central

Rajagopala, Seesandra V.; Vlasblom, James; Arnold, Roland; Franca-Koh, Jonathan; Pakala, Suman B.; Phanse, Sadhna; Ceol, Arnaud; Häuser, Roman; Siszler, Gabriella; Wuchty, Stefan; Emili, Andrew; Babu, Mohan; Aloy, Patrick; Pieper, Rembert; Uetz, Peter

2014-01-01

Efforts to map the Escherichia coli interactome have identified several hundred macromolecular complexes, but direct binary protein-protein interactions (PPIs) have not been surveyed on a large scale. Here we performed yeast two-hybrid screens of 3,305 baits against 3,606 preys (~70% of the E. coli proteome) in duplicate to generate a map of 2,234 interactions, approximately doubling the number of known binary PPIs in E. coli. Integration of binary PPIs and genetic interactions revealed functional dependencies among components involved in cellular processes, including envelope integrity, flagellum assembly and protein quality control. Many of the binary interactions that could be mapped within multi-protein complexes were informative regarding internal topology and indicated that interactions within complexes are significantly more conserved than those interactions connecting different complexes. This resource will be useful for inferring bacterial gene function and provides a draft reference of the basic physical wiring network of this evolutionarily significant model microbe. PMID:24561554

Hypervelocity stars from young stellar clusters in the Galactic Centre

NASA Astrophysics Data System (ADS)

Fragione, G.; Capuzzo-Dolcetta, R.; Kroupa, P.

2017-05-01

The enormous velocities of the so-called hypervelocity stars (HVSs) derive, likely, from close interactions with massive black holes, binary stars encounters or supernova explosions. In this paper, we investigate the origin of HVSs as consequence of the close interaction between the Milky Way central massive black hole and a passing-by young stellar cluster. We found that both single and binary HVSs may be generated in a burst-like event, as the cluster passes near the orbital pericentre. High-velocity stars will move close to the initial cluster orbital plane and in the direction of the cluster orbital motion at the pericentre. The binary fraction of these HVS jets depends on the primordial binary fraction in the young cluster. The level of initial mass segregation determines the value of the average mass of the ejected stars. Some binary stars will merge, continuing their travel across and out of the Galaxy as blue stragglers.

From Solidification Processing to Microstructure to Mechanical Properties: A Multi-scale X-ray Study of an Al-Cu Alloy Sample

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tourret, D.; Mertens, J. C. E.; Lieberman, E.

We follow an Al-12 at. pct Cu alloy sample from the liquid state to mechanical failure, using in situ X-ray radiography during directional solidification and tensile testing, as well as three-dimensional computed tomography of the microstructure before and after mechanical testing. The solidification processing stage is simulated with a multi-scale dendritic needle network model, and the micromechanical behavior of the solidified microstructure is simulated using voxelized tomography data and an elasto-viscoplastic fast Fourier transform model. This study demonstrates the feasibility of direct in situ monitoring of a metal alloy microstructure from the liquid processing stage up to its mechanical failure,more » supported by quantitative simulations of microstructure formation and its mechanical behavior.« less

Coatings for directional eutectics. [for corrosion and oxidation resistance

NASA Technical Reports Server (NTRS)

Felten, E. J.; Strangman, T. E.; Ulion, N. E.

1974-01-01

Eleven coating systems based on MCrAlY overlay and diffusion aluminide prototypes were evaluated to determine their capability for protecting the gamma/gamma prime-delta directionally solidified eutectic alloy (Ni-20Cb-6Cr-2.5Al) in gas turbine engine applications. Furnace oxidation and hot corrosion, Mach 0.37 burner-rig, tensile ductility, stress-rupture and thermomechanical fatigue tests were used to evaluate the coated gamma/gamma prime-delta alloy. The diffusion aluminide coatings provided adequate oxidation resistance at 1144 K (1600 F) but offered very limited protection in 114 K (1600 F) hot corrosion and 1366 K (2000 F) oxidation tests. A platinum modified NiCrAlY overlay coating exhibited excellent performance in oxidation testing and had no adverse effects upon the eutectic alloy.

From Solidification Processing to Microstructure to Mechanical Properties: A Multi-scale X-ray Study of an Al-Cu Alloy Sample

DOE PAGES

Tourret, D.; Mertens, J. C. E.; Lieberman, E.; ...

2017-09-13

We follow an Al-12 at. pct Cu alloy sample from the liquid state to mechanical failure, using in situ X-ray radiography during directional solidification and tensile testing, as well as three-dimensional computed tomography of the microstructure before and after mechanical testing. The solidification processing stage is simulated with a multi-scale dendritic needle network model, and the micromechanical behavior of the solidified microstructure is simulated using voxelized tomography data and an elasto-viscoplastic fast Fourier transform model. This study demonstrates the feasibility of direct in situ monitoring of a metal alloy microstructure from the liquid processing stage up to its mechanical failure,more » supported by quantitative simulations of microstructure formation and its mechanical behavior.« less

From Solidification Processing to Microstructure to Mechanical Properties: A Multi-scale X-ray Study of an Al-Cu Alloy Sample

NASA Astrophysics Data System (ADS)

Tourret, D.; Mertens, J. C. E.; Lieberman, E.; Imhoff, S. D.; Gibbs, J. W.; Henderson, K.; Fezzaa, K.; Deriy, A. L.; Sun, T.; Lebensohn, R. A.; Patterson, B. M.; Clarke, A. J.

2017-11-01

We follow an Al-12 at. pct Cu alloy sample from the liquid state to mechanical failure, using in situ X-ray radiography during directional solidification and tensile testing, as well as three-dimensional computed tomography of the microstructure before and after mechanical testing. The solidification processing stage is simulated with a multi-scale dendritic needle network model, and the micromechanical behavior of the solidified microstructure is simulated using voxelized tomography data and an elasto-viscoplastic fast Fourier transform model. This study demonstrates the feasibility of direct in situ monitoring of a metal alloy microstructure from the liquid processing stage up to its mechanical failure, supported by quantitative simulations of microstructure formation and its mechanical behavior.

The growth of metastable peritectic compounds

NASA Technical Reports Server (NTRS)

Larson, D. J., Jr.; Pirich, R. G.

1981-01-01

The influence of gravitationally driven thermosolutal convection on the directional solidification of peritectic alloys is considered as well as the relationships between the solidification processing conditions, and the microstructure, chemistry, and magnetic properties of such alloys. Analysis of directionally solidified Pb-Bi peritectic samples indicates that appreciable macrosegregation occurs due to thermosolutal convection and/or Soret diffusion. A peritectic solidification model which accounts for partial mixing in the liquid ahead of the planar solidification interface and describes macrosegregation has been developed. Two-phase dendritic and banded microstructures were grown in the Pb-Bi peritectic system, refined two-phase microstructures have were observed, and candidate formation mechanisms proposed. Material handling, containment, casting, microstructural and magnetic characterization techniques were developed for the Sm-Co system. Alloys produced with these procedures are homogeneous.

U.S. Materials Science on the International Space Station: Status and Plans

NASA Technical Reports Server (NTRS)

Chiaramonte, Francis P.; Kelton, Kenneth F.; Matson, Douglas M.; Poirier, David R.; Trivedi, Rohit K.; Su, Ching-Hua; Volz, Martin P.; Voorhees, Peter W.

2010-01-01

This viewgraph presentation reviews the current status and NASA plans for materials science on the International Space Station. The contents include: 1) Investigations Launched in 2009; 2) DECLIC in an EXPRESS rack; 3) Dynamical Selection of Three-Dimensional Interface Patterns in Directional Solidification (DSIP); 4) Materials Science Research Rack (MSRR); 5) Materials Science Laboratory; 6) Comparison of Structure and Segregation in Alloys Directionally Solidified in Terrestrial and Microgravity Environments (MICAST/CETSOL); 7) Coarsening in Solid Liquid Mixtures 2 Reflight (CSLM 2R); 8) Crystal Growth Investigations; 9) Levitator Investigations; 10) Quasi Crystalline Undercooled Alloys for Space Investigation (QUASI); 11) The Role of Convection and Growth Competition in Phase Selection in Microgravity (LODESTARS); 12) Planned Additional Investigations; 13) SETA; 14) METCOMP; and 15) Materials Science NRA.

Manufacturing Processes for Long-Life Gas Turbines

NASA Astrophysics Data System (ADS)

Hoppin, G. S.; Danesi, W. P.

1986-07-01

Dual-alloy turbine wheels produced by solid-state diffusion bonding of vacuum investment cast blade rings of one superalloy to preconsolidated powder metal hubs of a second superalloy have the long cyclic lives characteristic of wrought or powder superalloys combined with the high creep strength and net-shape blades characteristic of cast superalloys. A wide variety of superalloys and turbine configurations are compatible with this technology. Improved temperature capability turbine blades and vanes of the MAR-M 247 alloy made by directional solidification casting processes are now in volume production for Garrett gas turbines. Single-crystal alloys derivative to MAR-M 247 further extend the temperature capability of turbine blades and have been successfully engine tested. These blades are produced by a relatively simple modification of the processes used to manufacture directionally solidified blades.

Tailoring magnetostriction with various directions for directional solidification Fe82Ga15Al3 alloy by magnetic field heat treatment

NASA Astrophysics Data System (ADS)

Li, Xiaolong; Bao, Xiaoqian; Liu, Yangyang; Yu, Linhua; Li, Jiheng; Gao, Xuexu

2017-10-01

The magnetostriction of the Fe82Ga15Al3 alloy, along the length and width, can be tailored by applying a magnetic field heat treatment. In this work, the Fe82Ga15Al3 sheet was cut from the directional solidified Fe82Ga15Al3 alloy with the ⟨100⟩ preferred orientation and was annealed at 720 °C for 30 min under a magnetic field of 800 Oe along the length direction with a heating and cooling rate of 100 °C/min. The magnetostrictive properties along the length and width directions were modified to λ// = 7 ppm and λ⊥ = -210 ppm from λ// = 210 ppm and λ⊥ = -10 ppm for the initial sample prior to the magnetic field heat treatment. The cellular-like magnetic domain structure was composed of parallel 180° stripe domains and vertical 90° domains observed using a magnetic-force microscope. The change in magnetostriction along parallel and perpendicular directions was mainly resulted from the rotation of the magnetic domain units.

Highly dispersed Pt-Ni nanoparticles on nitrogen-doped carbon nanotubes for application in direct methanol fuel cells.

PubMed

Jiang, Shujuan; Ma, Yanwen; Tao, Haisheng; Jian, Guoqiang; Wang, Xizhang; Fan, Yining; Zhu, Jianmin; Hu, Zheng

2010-06-01

Binary Pt-Ni alloyed nanoparticles supported on nitrogen-doped carbon nanotubes (NCNTs) have been facilely constructed without pre-modification by making use of the active sites in NCNTs due to the N-participation. So-obtained binary Pt-Ni alloyed nanoparticles have been highly dispersed on the outer surface of the support with the size of about 3-4 nm. The electrochemical properties of the catalysts for methanol oxidation have been systematically evaluated. Binary Pt-Ni alloyed composites with molar ratio (Pt:Ni) of 3:2 and 3:1 present enhanced electrocatalytic activities and improved tolerance to CO poisoning as well as the similar stability, in comparison with the commercial Pt/C catalyst and the monometallic Pt/NCNTs catalysts. These results imply that so-constructed nanocomposite catalysts have the potential for applications in direct methanol fuel cells.

Oxygen vacancies promoted interfacial charge carrier transfer of CdS/ZnO heterostructure for photocatalytic hydrogen generation.

PubMed

Xie, Ying Peng; Yang, Yongqiang; Wang, Guosheng; Liu, Gang

2017-10-01

The solid-state Z-scheme trinary/binary heterostructures show the advantage of utilizing the high-energy photogenerated charge carriers in photocatalysis. However, the key factors controlling such Z-scheme in the binary heterostructures are still unclear. In this paper, we showed that oxygen vacancies could act as an interface electron transfer mediator to promote the direct Z-scheme charge transfer process in binary semiconductor heterostructures of CdS/ZnS. Increasing the concentration of surface oxygen vacancies of ZnO crystal can greatly enhance photocatalytic hydrogen generation of CdS/ZnO heterostructure. This was attributed to the strengthened direct Z-scheme charge transfer process in CdS/ZnO, as evidenced by steady-state/time-resolved photoluminescence spectroscopy and selective photodeposition of metal particles on the heterostructure. Copyright © 2017 Elsevier Inc. All rights reserved.

Coincidence probabilities for spacecraft gravitational wave experiments - Massive coalescing binaries

NASA Technical Reports Server (NTRS)

Tinto, Massimo; Armstrong, J. W.

1991-01-01

Massive coalescing binary systems are candidate sources of gravitational radiation in the millihertz frequency band accessible to spacecraft Doppler tracking experiments. This paper discusses signal processing and detection probability for waves from coalescing binaries in the regime where the signal frequency increases linearly with time, i.e., 'chirp' signals. Using known noise statistics, thresholds with given false alarm probabilities are established for one- and two-spacecraft experiments. Given the threshold, the detection probability is calculated as a function of gravitational wave amplitude for both one- and two-spacecraft experiments, assuming random polarization states and under various assumptions about wave directions. This allows quantitative statements about the detection efficiency of these experiments and the utility of coincidence experiments. In particular, coincidence probabilities for two-spacecraft experiments are insensitive to the angle between the directions to the two spacecraft, indicating that near-optical experiments can be done without constraints on spacecraft trajectories.

Learning Discriminative Binary Codes for Large-scale Cross-modal Retrieval.

PubMed

Xu, Xing; Shen, Fumin; Yang, Yang; Shen, Heng Tao; Li, Xuelong

2017-05-01

Hashing based methods have attracted considerable attention for efficient cross-modal retrieval on large-scale multimedia data. The core problem of cross-modal hashing is how to learn compact binary codes that construct the underlying correlations between heterogeneous features from different modalities. A majority of recent approaches aim at learning hash functions to preserve the pairwise similarities defined by given class labels. However, these methods fail to explicitly explore the discriminative property of class labels during hash function learning. In addition, they usually discard the discrete constraints imposed on the to-be-learned binary codes, and compromise to solve a relaxed problem with quantization to obtain the approximate binary solution. Therefore, the binary codes generated by these methods are suboptimal and less discriminative to different classes. To overcome these drawbacks, we propose a novel cross-modal hashing method, termed discrete cross-modal hashing (DCH), which directly learns discriminative binary codes while retaining the discrete constraints. Specifically, DCH learns modality-specific hash functions for generating unified binary codes, and these binary codes are viewed as representative features for discriminative classification with class labels. An effective discrete optimization algorithm is developed for DCH to jointly learn the modality-specific hash function and the unified binary codes. Extensive experiments on three benchmark data sets highlight the superiority of DCH under various cross-modal scenarios and show its state-of-the-art performance.

DISTINGUISHING COMPACT BINARY POPULATION SYNTHESIS MODELS USING GRAVITATIONAL WAVE OBSERVATIONS OF COALESCING BINARY BLACK HOLES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stevenson, Simon; Ohme, Frank; Fairhurst, Stephen, E-mail: simon.stevenson@ligo.org

2015-09-01

The coalescence of compact binaries containing neutron stars or black holes is one of the most promising signals for advanced ground-based laser interferometer gravitational-wave (GW) detectors, with the first direct detections expected over the next few years. The rate of binary coalescences and the distribution of component masses is highly uncertain, and population synthesis models predict a wide range of plausible values. Poorly constrained parameters in population synthesis models correspond to poorly understood astrophysics at various stages in the evolution of massive binary stars, the progenitors of binary neutron star and binary black hole systems. These include effects such asmore » supernova kick velocities, parameters governing the energetics of common envelope evolution and the strength of stellar winds. Observing multiple binary black hole systems through GWs will allow us to infer details of the astrophysical mechanisms that lead to their formation. Here we simulate GW observations from a series of population synthesis models including the effects of known selection biases, measurement errors and cosmology. We compare the predictions arising from different models and show that we will be able to distinguish between them with observations (or the lack of them) from the early runs of the advanced LIGO and Virgo detectors. This will allow us to narrow down the large parameter space for binary evolution models.« less

Evolutionary Pathways for Asteroid Satellites

NASA Astrophysics Data System (ADS)

Jacobson, Seth Andrew

2015-08-01

The YORP-induced rotational fission hypothesis is a proposed mechanism for the creation of small asteroid binaries, which make up approximately 1/6-th of the near-Earth asteroid and small Main Belt asteroid populations. The YORP effect is a radiative torque that rotationally accelerates asteroids on timescales of thousands to millions of years. As asteroids rotationally accelerate, centrifugal accelerations on material within the body can match gravitational accelerations holding that material in place. When this occurs, that material goes into orbit. Once in orbit that material coalesces into a companion that undergoes continued dynamical evolution.Observations with radar, photometric and direct imaging techniques reveal a diverse array of small asteroid satellites. These systems can be sorted into a number of morphologies according to size, multiplicity of members, dynamical orbit and spin states, and member shapes. For instance, singly synchronous binaries have short separation distances between the two members, rapidly rotating oblate primary members, and tidally locked prolate secondary members. Other confirmed binary morphologies include doubly synchronous, tight asynchronous and wide asynchronous binaries. Related to these binary morphologies are unbound paired asteroid systems and bi-lobate contact binaries.A critical test for the YORP-induced rotational fission hypothesis is whether the binary asteroids produced evolve to the observed binary and related systems. In this talk I will review how this evolution is believed to occur according to gravitational dynamics, mutual body tides and the binary YORP effect.

Binary statistics among population II stars

NASA Astrophysics Data System (ADS)

Zinnecker, H.; Köhler, R.; Jahreiß, H.

2004-08-01

Population II stars are old, metal-poor, Galactic halo stars with high proper motion. We have carried out a visual binary survey of 164 halo stars in the solar neighborhood (median distance 100 pc), using infrared speckle interferometry, adaptive optics, and wide field direct imaging. The sample is based on the lists of Population II stars of Carney et al. (1994) and Norris (1986), with reliable distances from HIPPARCOS measurements. At face value, we found 33 binaries, 6 triples, and 1 quadruple system. When we limit ourselves to K-band flux ratios larger than 0.1 (to avoid background contamination), the numbers drop to 9 binaries and 1 triple, corresponding to a binary frequency of 6 - 7 % above our angular resolution limit of about 0.1 arcsec. If we count all systems with K-band flux ratios greater than 0.01, we obtain 15 more binaries and 3 more triples, corresponding to a binary frequency for projected separations in excess of 10 AU of around 20 %. This is to be compared with the frequency of spectroscopic binaries (up to a period of 3000 days) of Population II stars of about 15 % (Latham et al. 2002). We also determined a semi-major axis distribution for our visual Population II binary and triple systems, which appears to be remarkably different from that of Population I stars. Second epoch-observations must help confirm the reality of our results.

Preparation, Characterization and Properties of Rapidly Solidified Alloys

DTIC Science & Technology

1986-10-01

Biancaniello Met. Trans. A (Accepted) 3. Microsegregation in Rapidly Solidified Ag-15 wt % Cu Alloys W.J. Boettinger, L.A. Bendersky, S.R. Coriell...the alloy , leaving the tntercrystalline liquid depleted in manganese. The 15 and 18 wt % Mn ribbons both show Al (Ill) peaks which are split...same composition. The thicker ribbons of 35 and 37 wt % Mn alloys were single-phase decagonal. The decagonal phase is recognizable by its highly faulted

Alkali metal/sulfur battery

DOEpatents

Anand, Joginder N.

1978-01-01

Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

Systems and Methods for Fabricating Objects Including Amorphous Metal Using Techniques Akin to Additive Manufacturing

NASA Technical Reports Server (NTRS)

Hofmann, Douglas (Inventor)

2017-01-01

Systems and methods in accordance with embodiments of the invention fabricate objects including amorphous metals using techniques akin to additive manufacturing. In one embodiment, a method of fabricating an object that includes an amorphous metal includes: applying a first layer of molten metallic alloy to a surface; cooling the first layer of molten metallic alloy such that it solidifies and thereby forms a first layer including amorphous metal; subsequently applying at least one layer of molten metallic alloy onto a layer including amorphous metal; cooling each subsequently applied layer of molten metallic alloy such that it solidifies and thereby forms a layer including amorphous metal prior to the application of any adjacent layer of molten metallic alloy; where the aggregate of the solidified layers including amorphous metal forms a desired shape in the object to be fabricated; and removing at least the first layer including amorphous metal from the surface.

Microstructures, Martensitic Transformation, and Mechanical Behavior of Rapidly Solidified Ti-Ni-Hf and Ti-Ni-Si Shape Memory Alloys

NASA Astrophysics Data System (ADS)

Han, X. L.; Song, K. K.; Zhang, L. M.; Xing, H.; Sarac, B.; Spieckermann, F.; Maity, T.; Mühlbacher, M.; Wang, L.; Kaban, I.; Eckert, J.

2018-03-01

In this work, the microstructure and mechanical properties of rapidly solidified Ti50- x/2Ni50- x/2Hf x ( x = 0, 2, 4, 6, 8, 10, and 12 at.%) and Ti50- y/2Ni50- y/2Si y ( y = 1, 2, 3, 5, 7, and 10 at.%) shape memory alloys (SMAs) were investigated. The sequence of the phase formation and transformations in dependence on the chemical composition is established. Rapidly solidified Ti-Ni-Hf or Ti-Ni-Si SMAs are found to show relatively high yield strength and large ductility for specific Hf or Si concentrations, which is due to the gradual disappearance of the phase transformation from austenite to twinned martensite and the predominance of the phase transformation from twinned martensite to detwinned martensite during deformation as well as to the refinement of dendrites and the precipitation of brittle intermetallic compounds.

Validation of the solidifying soil process using laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Lin, Zhao-Xiang; Liu, Lin-Mei; Liu, Lu-Wen

2016-09-01

Although an Ionic Soil Stabilizer (ISS) has been widely used in landslide control, it is desirable to effectively monitor the stabilization process. With the application of laser-induced breakdown spectroscopy (LIBS), the ion contents of K, Ca, Na, Mg, Al, and Si in the permeable fluid are detected after the solidified soil samples have been permeated. The processes of the Ca ion exchange are analyzed at pressures of 2 and 3 atm, and it was determined that the cation exchanged faster as the pressure increased. The Ca ion exchanges were monitored for different stabilizer mixtures, and it was found that a ratio of 1:200 of ISS to soil is most effective. The investigated plasticity and liquidity indexes also showed that the 1:200 ratio delivers the best performance. The research work indicates that it is possible to evaluate the engineering performances of soil solidified by ISS in real time and online by LIBS.

Method of making active magnetic refrigerant, colossal magnetostriction and giant magnetoresistive materials based on Gd-Si-Ge alloys

DOEpatents

Gschneidner, Jr., Karl A.; Pecharsky, Alexandra O.; Pecharsky, Vitalij K.

2003-07-08

Method of making an active magnetic refrigerant represented by Gd.sub.5 (Si.sub.x Ge.sub.1-x).sub.4 alloy for 0.ltoreq.x.ltoreq.1.0 comprising placing amounts of the commercially pure Gd, Si, and Ge charge components in a crucible, heating the charge contents under subambient pressure to a melting temperature of the alloy for a time sufficient to homogenize the alloy and oxidize carbon with oxygen present in the Gd charge component to reduce carbon, rapidly solidifying the alloy in the crucible, and heat treating the solidified alloy at a temperature below the melting temperature for a time effective to homogenize a microstructure of the solidified material, and then cooling sufficiently fast to prevent the eutectoid decomposition and improve magnetocaloric and/or the magnetostrictive and/or the magnetoresistive properties thereof.

Black hole binaries dynamically formed in globular clusters

NASA Astrophysics Data System (ADS)

Park, Dawoo; Kim, Chunglee; Lee, Hyung Mok; Bae, Yeong-Bok; Belczynski, Krzysztof

2017-08-01

We investigate properties of black hole (BH) binaries formed in globular clusters via dynamical processes, using directN-body simulations. We pay attention to effects of BH mass function on the total mass and mass ratio distributions of BH binaries ejected from clusters. First, we consider BH populations with two different masses in order to learn basic differences from models with single-mass BHs only. Secondly, we consider continuous BH mass functions adapted from recent studies on massive star evolution in a low metallicity environment, where globular clusters are formed. In this work, we consider only binaries that are formed by three-body processes and ignore stellar evolution and primordial binaries for simplicity. Our results imply that most BH binary mergers take place after they get ejected from the cluster. Also, mass ratios of dynamically formed binaries should be close to 1 or likely to be less than 2:1. Since the binary formation efficiency is larger for higher-mass BHs, it is likely that a BH mass function sampled by gravitational-wave observations would be weighed towards higher masses than the mass function of single BHs for a dynamically formed population. Applying conservative assumptions regarding globular cluster populations such as small BH mass fraction and no primordial binaries, the merger rate of BH binaries originated from globular clusters is estimated to be at least 6.5 yr-1 Gpc-3. Actual rate can be up to more than several times of our conservative estimate.

Critical mingling and universal correlations in model binary active liquids

NASA Astrophysics Data System (ADS)

Bain, Nicolas; Bartolo, Denis

2017-06-01

Ensembles of driven or motile bodies moving along opposite directions are generically reported to self-organize into strongly anisotropic lanes. Here, building on a minimal model of self-propelled bodies targeting opposite directions, we first evidence a critical phase transition between a mingled state and a phase-separated lane state specific to active particles. We then demonstrate that the mingled state displays algebraic structural correlations also found in driven binary mixtures. Finally, constructing a hydrodynamic theory, we single out the physical mechanisms responsible for these universal long-range correlations typical of ensembles of oppositely moving bodies.

Cost-Sensitive Local Binary Feature Learning for Facial Age Estimation.

PubMed

Lu, Jiwen; Liong, Venice Erin; Zhou, Jie

2015-12-01

In this paper, we propose a cost-sensitive local binary feature learning (CS-LBFL) method for facial age estimation. Unlike the conventional facial age estimation methods that employ hand-crafted descriptors or holistically learned descriptors for feature representation, our CS-LBFL method learns discriminative local features directly from raw pixels for face representation. Motivated by the fact that facial age estimation is a cost-sensitive computer vision problem and local binary features are more robust to illumination and expression variations than holistic features, we learn a series of hashing functions to project raw pixel values extracted from face patches into low-dimensional binary codes, where binary codes with similar chronological ages are projected as close as possible, and those with dissimilar chronological ages are projected as far as possible. Then, we pool and encode these local binary codes within each face image as a real-valued histogram feature for face representation. Moreover, we propose a cost-sensitive local binary multi-feature learning method to jointly learn multiple sets of hashing functions using face patches extracted from different scales to exploit complementary information. Our methods achieve competitive performance on four widely used face aging data sets.

Texture Classification by Texton: Statistical versus Binary

PubMed Central

Guo, Zhenhua; Zhang, Zhongcheng; Li, Xiu; Li, Qin; You, Jane

2014-01-01

Using statistical textons for texture classification has shown great success recently. The maximal response 8 (Statistical_MR8), image patch (Statistical_Joint) and locally invariant fractal (Statistical_Fractal) are typical statistical texton algorithms and state-of-the-art texture classification methods. However, there are two limitations when using these methods. First, it needs a training stage to build a texton library, thus the recognition accuracy will be highly depended on the training samples; second, during feature extraction, local feature is assigned to a texton by searching for the nearest texton in the whole library, which is time consuming when the library size is big and the dimension of feature is high. To address the above two issues, in this paper, three binary texton counterpart methods were proposed, Binary_MR8, Binary_Joint, and Binary_Fractal. These methods do not require any training step but encode local feature into binary representation directly. The experimental results on the CUReT, UIUC and KTH-TIPS databases show that binary texton could get sound results with fast feature extraction, especially when the image size is not big and the quality of image is not poor. PMID:24520346

Oscillation-Mark Formation and Liquid-Slag Consumption in Continuous Casting Mold

NASA Astrophysics Data System (ADS)

Yang, Jie; Meng, Xiangning; Wang, Ning; Zhu, Miaoyong

2017-04-01

Traditional understanding on the complex multiphysics phenomenon of the meniscus in the oscillating mold for continuously cast steel, including oscillation-mark formation and liquid-slag consumption, has never considered the shape influence of the flux channel between the mold wall and the solidifying shell surface. Based on the reciprocating oscillation of mold, this study was carried out to calculate theoretically the periodic pressure and the liquid-slag layer thickness in the flux channel for the upper and the lower meniscus that possess different shapes in combination with a transient equilibrium profile of the flux channel as well as the sinusoidal and the nonsinusoidal oscillation modes of mold. The effect of flux channel shape on the multiphysics phenomenon in the meniscus was determined by the physical oscillation simulation by using an experimental cold model mold. The results show that the shape difference between the upper and the lower meniscus leads to the opposite direction of pressure in the flux channel. The pressure in the opposite direction plays a respective role in oscillation-mark formation and liquid-slag consumption in an oscillation cycle of mold, and thus, it makes a new mechanism for explaining the multiphysics phenomenon in the meniscus. The oscillation mark is initially formed by the rapid increase of positive channel pressure in the upper meniscus, and most of the liquid slag is infiltrated into the flux channel by the negative channel pressure in the lower meniscus from the end of a positive strip time to the beginning of the next positive strip time, including the negative strip time in between. Furthermore, the physical characteristics of the lubrication behavior in the meniscus are summarized, including liquid-slag infiltration, solidifying shell deformation, and the thickness change of the liquid-slag layer.

Process gas solidification system

DOEpatents

Fort, William G. S.; Lee, Jr., William W.

1978-01-01

It has been the practice to (a) withdraw hot, liquid UF.sub.6 from various systems, (b) direct the UF.sub.6 into storage cylinders, and (c) transport the filled cylinders to another area where the UF.sub.6 is permitted to solidify by natural cooling. However, some hazard attends the movement of cylinders containing liquid UF.sub.6, which is dense, toxic, and corrosive. As illustrated in terms of one of its applications, the invention is directed to withdrawing hot liquid UF.sub.6 from a system including (a) a compressor for increasing the pressure and temperature of a stream of gaseous UF.sub.6 to above its triple point and (b) a condenser for liquefying the compressed gas. A network containing block valves and at least first and second portable storage cylinders is connected between the outlet of the condenser and the suction inlet of the compressor. After an increment of liquid UF.sub.6 from the condenser has been admitted to the first cylinder, the cylinder is connected to the suction of the compressor to flash off UF.sub.6 from the cylinder, thus gradually solidifying UF.sub.6 therein. While the first cylinder is being cooled in this manner, an increment of liquid UF.sub.6 from the condenser is transferred into the second cylinder. UF.sub.6 then is flashed from the second cylinder while another increment of liquid UF.sub.6 is being fed to the first. The operations are repeated until both cylinders are filled with solid UF.sub.6, after which they can be moved safely. As compared with the previous technique, this procedure is safer, faster, and more economical. The method also provides the additional advantage of removing volatile impurities from the UF.sub.6 while it is being cooled.

Microstructures in rapidly solidified Ni-Mo alloys

NASA Technical Reports Server (NTRS)

Jayaraman, N.; Tewari, S. N.; Hemker, K. J.; Glasgow, T. K.

1985-01-01

Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by Chill Block Melt Spinning in vacuum and were examined by optical metallography, X-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

Changes in solidified microstructures

NASA Technical Reports Server (NTRS)

Wallace, J. F.

1984-01-01

The properties and casting behavior of metals are significantly affected by their cast structure. This structure is optimized by producing columnar versus equiaxed grains and coarse versus fine grains by controlling solidification conditions. The transition from columnar to equiaxed grains is favored by: constitutional supercooling with effective nucleation of free dendrites; melting off and transport of dendrite tips and arms; mechanical vibration; falling down of free dendrites from a chilled top surface; and induced flow in the solidifying structure by oscillation of rotation.

Method of forming pointed structures

NASA Technical Reports Server (NTRS)

Pugel, Diane E. (Inventor)

2011-01-01

A method of forming an array of pointed structures comprises depositing a ferrofluid on a substrate, applying a magnetic field to the ferrofluid to generate an array of surface protrusions, and solidifying the surface protrusions to form the array of pointed structures. The pointed structures may have a tip radius ranging from approximately 10 nm to approximately 25 micron. Solidifying the surface protrusions may be carried out at a temperature ranging from approximately 10 degrees C. to approximately 30 degrees C.

Large Eddy Simulation of Transient Flow, Solidification, and Particle Transport Processes in Continuous-Casting Mold

NASA Astrophysics Data System (ADS)

Liu, Zhongqiu; Li, Linmin; Li, Baokuan; Jiang, Maofa

2014-07-01

The current study developed a coupled computational model to simulate the transient fluid flow, solidification, and particle transport processes in a slab continuous-casting mold. Transient flow of molten steel in the mold is calculated using the large eddy simulation. An enthalpy-porosity approach is used for the analysis of solidification processes. The transport of bubble and non-metallic inclusion inside the liquid pool is calculated using the Lagrangian approach based on the transient flow field. A criterion of particle entrapment in the solidified shell is developed using the user-defined functions of FLUENT software (ANSYS, Inc., Canonsburg, PA). The predicted results of this model are compared with the measurements of the ultrasonic testing of the rolled steel plates and the water model experiments. The transient asymmetrical flow pattern inside the liquid pool exhibits quite satisfactory agreement with the corresponding measurements. The predicted complex instantaneous velocity field is composed of various small recirculation zones and multiple vortices. The transport of particles inside the liquid pool and the entrapment of particles in the solidified shell are not symmetric. The Magnus force can reduce the entrapment ratio of particles in the solidified shell, especially for smaller particles, but the effect is not obvious. The Marangoni force can play an important role in controlling the motion of particles, which increases the entrapment ratio of particles in the solidified shell obviously.

A study on polypropylene encapsulation and solidification of textile sludge.

PubMed

Kumari, V Krishna; Kanmani, S

2011-10-01

The textile sludge is an inevitable solid waste from the textile wastewater process and is categorised under toxic substances by statutory authorities. In this study, an attempt has been made to encapsulate and solidify heavy metals and dyes present in textile sludge using polypropylene and Portland cement. Sludge samples (2 Nos.) were characterized for pH (8.5, 9.5), moisture content (1.5%, 1.96%) and chlorides (245mg/L, 425.4mg/L). Sludge samples were encapsulated into polypropylene with calcium carbonate (additive) and solidified with cement at four different proportions (20, 30, 40, 50%) of sludge. Encapsulated and solidified cubes were made and then tested for compressive strength. Maximum compressive strength of cubes (size, 7.06cm) containing sludge (50%) for encapsulation (16.72 N/mm2) and solidification (18.84 N/mm2) was more than that of standard M15 mortar cubes. The leachability of copper, nickel and chromium has been effectively reduced from 0.58 mg/L, 0.53 mg/L and 0.07 mg/L to 0.28mg/L, 0.26mg/L and BDL respectively in encapsulated products and to 0.24mg/L, BDL and BDL respectively in solidified products. This study has shown that the solidification process is slightly more effective than encapsulation process. Both the products were recommended for use in the construction of non-load bearing walls.

High-speed high-accuracy three-dimensional shape measurement using digital binary defocusing method versus sinusoidal method

NASA Astrophysics Data System (ADS)

Hyun, Jae-Sang; Li, Beiwen; Zhang, Song

2017-07-01

This paper presents our research findings on high-speed high-accuracy three-dimensional shape measurement using digital light processing (DLP) technologies. In particular, we compare two different sinusoidal fringe generation techniques using the DLP projection devices: direct projection of computer-generated 8-bit sinusoidal patterns (a.k.a., the sinusoidal method), and the creation of sinusoidal patterns by defocusing binary patterns (a.k.a., the binary defocusing method). This paper mainly examines their performance on high-accuracy measurement applications under precisely controlled settings. Two different projection systems were tested in this study: a commercially available inexpensive projector and the DLP development kit. Experimental results demonstrated that the binary defocusing method always outperforms the sinusoidal method if a sufficient number of phase-shifted fringe patterns can be used.

High-speed 3D imaging using digital binary defocusing method vs sinusoidal method

NASA Astrophysics Data System (ADS)

Zhang, Song; Hyun, Jae-Sang; Li, Beiwen

2017-02-01

This paper presents our research findings on high-speed 3D imaging using digital light processing (DLP) technologies. In particular, we compare two different sinusoidal fringe generation techniques using the DLP projection devices: direct projection of 8-bit computer generated sinusoidal patterns (a.k.a, the sinusoidal method), and the creation of sinusoidal patterns by defocusing binary patterns (a.k.a., the binary defocusing method). This paper mainly examines their performance on high-accuracy measurement applications under precisely controlled settings. Two different projection systems were tested in this study: the commercially available inexpensive projector, and the DLP development kit. Experimental results demonstrated that the binary defocusing method always outperforms the sinusoidal method if a sufficient number of phase-shifted fringe patterns can be used.

The first gravitational-wave burst GW150914, as predicted by the scenario machine

NASA Astrophysics Data System (ADS)

Lipunov, V. M.; Kornilov, V.; Gorbovskoy, E.; Tiurina, N.; Balanutsa, P.; Kuznetsov, A.

2017-02-01

The Advanced LIGO observatory recently reported (Abbott et al., 2016a) the first direct detection of gravitational waves predicted by Einstein (1916). The detection of this event was predicted in 1997 on the basis of the Scenario Machine population synthesis calculations (Lipunov et al., 1997b) Now we discuss the parameters of binary black holes and event rates predicted by different scenarios of binary evolution. We give a simple explanation of the big difference between detected black hole masses and the mean black hole masses observed in of X-ray Nova systems. The proximity of the masses of the components of GW150914 is in good agreement with the observed initial mass ratio distribution in massive binary systems, as is used in Scenario Machine calculations for massive binaries.

LONG-TERM STABLE EQUILIBRIA FOR SYNCHRONOUS BINARY ASTEROIDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jacobson, Seth A.; Scheeres, Daniel J.

Synchronous binary asteroids may exist in a long-term stable equilibrium, where the opposing torques from mutual body tides and the binary YORP (BYORP) effect cancel. Interior of this equilibrium, mutual body tides are stronger than the BYORP effect and the mutual orbit semimajor axis expands to the equilibrium; outside of the equilibrium, the BYORP effect dominates the evolution and the system semimajor axis will contract to the equilibrium. If the observed population of small (0.1-10 km diameter) synchronous binaries are in static configurations that are no longer evolving, then this would be confirmed by a null result in the observationalmore » tests for the BYORP effect. The confirmed existence of this equilibrium combined with a shape model of the secondary of the system enables the direct study of asteroid geophysics through the tidal theory. The observed synchronous asteroid population cannot exist in this equilibrium if described by the canonical 'monolithic' geophysical model. The 'rubble pile' geophysical model proposed by Goldreich and Sari is sufficient, however it predicts a tidal Love number directly proportional to the radius of the asteroid, while the best fit to the data predicts a tidal Love number inversely proportional to the radius. This deviation from the canonical and Goldreich and Sari models motivates future study of asteroid geophysics. Ongoing BYORP detection campaigns will determine whether these systems are in an equilibrium, and future determination of secondary shapes will allow direct determination of asteroid geophysical parameters.« less

Circumbinary habitability niches

NASA Astrophysics Data System (ADS)

Mason, Paul A.; Zuluaga, Jorge I.; Cuartas-Restrepo, Pablo A.; Clark, Joni M.

2015-07-01

Binaries could provide the best niches for life in the Galaxy. Although counterintuitive, this assertion follows directly from stellar tidal interaction theory and the evolution of lower mass stars. There is strong evidence that chromospheric activity of rapidly rotating young stars may be high enough to cause mass loss from atmospheres of potentially habitable planets. The removal of atmospheric water is most critical. Tidal breaking in binaries could help reduce magnetic dynamo action and thereby chromospheric activity in favour of life. We call this the Binary Habitability Mechanism (BHM) that we suggest allows for water retention at levels comparable to or better than the Earth. We discuss novel advantages that life may exploit, in these cases, and suggest that life may even thrive on some circumbinary planets. We find that while many binaries do not benefit from BHM, high-quality niches do exist for various combinations of stars between 0.55 and 1.0 solar masses. For a given pair of stellar masses, BHM operates only for certain combinations of period and eccentricity. Binaries having a solar-type primary seem to be quite well-suited niches having wide and distant habitable zones with plentiful water and sufficient light for photosynthetic life. We speculate that, as a direct result of BHM, conditions may be suitable for life on several planets and possibly even moons of giant planets orbiting some binaries. Lower mass combinations, while more restrictive in parameter space, provide niches lasting many billions of years and are rich suppliers of photosynthetic photons. We provide a publicly available web-site (http://bit.ly/BHM-calculator or http://bit.ly/BHM-calculator-mirror), which calculates the BHM effects presented in this paper.

Measurement of the Tidal Dissipation in Multiple Stars

NASA Astrophysics Data System (ADS)

Tokovinin, Andrei

2007-08-01

Considerable effort has been spent to date in measuring the period of tidal circularisation in close binaries as a function of age, in order to constrain the tidal dissipation theory. Here we evaluate a new, direct method of measuring the tidal dissipation by precise timings of periastron passages in a very eccentric binary. The example of the 41 Dra system is studied in some detail.

surrkick: Black-hole kicks from numerical-relativity surrogate models

NASA Astrophysics Data System (ADS)

Gerosa, Davide; Hébert, François; Stein, Leo C.

2018-04-01

surrkick quickly and reliably extract recoils imparted to generic, precessing, black hole binaries. It uses a numerical-relativity surrogate model to obtain the gravitational waveform given a set of binary parameters, and from this waveform directly integrates the gravitational-wave linear momentum flux. This entirely bypasses the need of fitting formulae which are typically used to model black-hole recoils in astrophysical contexts.

On The Validity of the Assumed PDF Method for Modeling Binary Mixing/Reaction of Evaporated Vapor in GAS/Liquid-Droplet Turbulent Shear Flow

NASA Technical Reports Server (NTRS)

Miller, R. S.; Bellan, J.

1997-01-01

An Investigation of the statistical description of binary mixing and/or reaction between a carrier gas and an evaporated vapor species in two-phase gas-liquid turbulent flows is perfomed through both theroetical analysis and comparisons with results from direct numerical simulations (DNS) of a two-phase mixing layer.

The COBAIN (COntact Binary Atmospheres with INterpolation) Code for Radiative Transfer

NASA Astrophysics Data System (ADS)

Kochoska, Angela; Prša, Andrej; Horvat, Martin

2018-01-01

Standard binary star modeling codes make use of pre-existing solutions of the radiative transfer equation in stellar atmospheres. The various model atmospheres available today are consistently computed for single stars, under different assumptions - plane-parallel or spherical atmosphere approximation, local thermodynamical equilibrium (LTE) or non-LTE (NLTE), etc. However, they are nonetheless being applied to contact binary atmospheres by populating the surface corresponding to each component separately and neglecting any mixing that would typically occur at the contact boundary. In addition, single stellar atmosphere models do not take into account irradiance from a companion star, which can pose a serious problem when modeling close binaries. 1D atmosphere models are also solved under the assumption of an atmosphere in hydrodynamical equilibrium, which is not necessarily the case for contact atmospheres, as the potentially different densities and temperatures can give rise to flows that play a key role in the heat and radiation transfer.To resolve the issue of erroneous modeling of contact binary atmospheres using single star atmosphere tables, we have developed a generalized radiative transfer code for computation of the normal emergent intensity of a stellar surface, given its geometry and internal structure. The code uses a regular mesh of equipotential surfaces in a discrete set of spherical coordinates, which are then used to interpolate the values of the structural quantites (density, temperature, opacity) in any given point inside the mesh. The radiaitive transfer equation is numerically integrated in a set of directions spanning the unit sphere around each point and iterated until the intensity values for all directions and all mesh points converge within a given tolerance. We have found that this approach, albeit computationally expensive, is the only one that can reproduce the intensity distribution of the non-symmetric contact binary atmosphere and can be used with any existing or new model of the structure of contact binaries. We present results on several test objects and future prospects of the implementation in state-of-the-art binary star modeling software.

High Resolution Imaging of Very Low Mass Spectral Binaries: Three Resolved Systems and Detection of Orbital Motion in an L/T Transition Binary

NASA Astrophysics Data System (ADS)

Bardalez Gagliuffi, Daniella C.; Gelino, Christopher R.; Burgasser, Adam J.

2015-11-01

We present high resolution Laser Guide Star Adaptive Optics imaging of 43 late-M, L and T dwarf systems with Keck/NIRC2. These include 17 spectral binary candidates, systems whose spectra suggest the presence of a T dwarf secondary. We resolve three systems: 2MASS J1341-3052, SDSS J1511+0607 and SDSS J2052-1609 the first two are resolved for the first time. All three have projected separations <8 AU and estimated periods of 14-80 years. We also report a preliminary orbit determination for SDSS J2052-1609 based on six epochs of resolved astrometry between 2005 and 2010. Among the 14 unresolved spectral binaries, 5 systems were confirmed binaries but remained unresolved, implying a minimum binary fraction of {47}-11+12% for this sample. Our inability to resolve most of the spectral binaries, including the confirmed binaries, supports the hypothesis that a large fraction of very low mass systems have relatively small separations and are missed with direct imaging. Some of the data presented herein were obtained at the W.M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W.M. Keck Foundation.

Three-dimensional modeling of radiative disks in binaries

NASA Astrophysics Data System (ADS)

Picogna, G.; Marzari, F.

2013-08-01

Context. Circumstellar disks in binaries are perturbed by the companion gravity causing significant alterations of the disk morphology. Spiral waves due to the companion tidal force also develop in the vertical direction and affect the disk temperature profile. These effects may significantly influence the process of planet formation. Aims: We perform 3D numerical simulations of disks in binaries with different initial dynamical configurations and physical parameters. Our goal is to investigate their evolution and their propensity to grow planets. Methods: We use an improved version of the SPH code VINE modified to better account for momentum and energy conservation via variable smoothing and softening length. The energy equation includes a flux-limited radiative transfer algorithm. The disk cooling is obtained with the use of "boundary particles" populating the outer surfaces of the disk and radiating to infinity. We model a system made of star/disk + star/disk where the secondary star (and relative disk) is less massive than the primary. Results: The numerical simulations performed for different values of binary separation and disk density show that trailing spiral shock waves develop when the stars approach their pericenter. Strong hydraulic jumps occur at the shock front, in particular for small separation binaries, creating breaking waves, and a consistent mass stream between the two disks. Both shock waves and mass transfer cause significant heating of the disk. At apocenter these perturbations are reduced and the disks are cooled down and less eccentric. Conclusions: The disk morphology is substantially affected by the companion perturbations, in particular in the vertical direction. The hydraulic jumps may slow down or even halt the dust coagulation process. The disk is significantly heated up by spiral waves and mass transfer, and the high gas temperature may prevent the ice condensation by moving the "snow line" outward. The disordered motion triggered by the spiral waves may, on the other hand, favor direct formation of large planetesimals from pebbles. The strength of the hydraulic jumps, disk heating, and mass exchange depends on the binary separation, and for larger semi-major axes, the tidal spiral pattern is substantially reduced. The environment then appears less hostile to planet formation.

Influence of dendrite network defects on channel segregate growth

NASA Technical Reports Server (NTRS)

Simpson, M.; Yerebakan, M.; Flemings, M. C.

1985-01-01

The solidifying ingot interdendritic flow analysis in which channel segregates are assumed to be produced by interdendritic fluid flow dissolving channels in the primary dendrite network is presently refined by examining the flow through a dendrite network possessing a small defect. Attention is given to the section of the mushy zone in a solidifying casting. Since defects such as that presently treated are unavoidable in a real casting, a more reliable indication may be furnished of the occurrence of channel segregates.

Improving ostomates' confidence with a discharge-solidifying agent.

PubMed

Slater, Rebecca

Not every person with a stoma will develop problems or even feel that he or she is unable to manage a stoma independently. However, for the individual who does experience problems and struggles to cope, the stoma nurse is pivotal in providing resources and product experience. He or she can enable the ostomate to adapt to the stoma and maintain their quality of life. This article provides an overview of a solidifying agent and case studies illustrating how it can be used to help patients achieve independence.

Cooling and solidification of heavy hydrocarbon liquid streams

DOEpatents

Antieri, Salvatore J.; Comolli, Alfred G.

1983-01-01

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

THE PROPERTIES OF HYPERVELOCITY STARS AND S-STARS ORIGINATING FROM AN ECCENTRIC DISK AROUND A SUPERMASSIVE BLACK HOLE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Šubr, Ladislav; Haas, Jaroslav, E-mail: subr@sirrah.troja.mff.cuni.cz, E-mail: haas@sirrah.troja.mff.cuni.cz

2016-09-01

Hypervelocity stars (HVSs), which are observed in the Galactic halo, are believed to be accelerated to large velocities by a process of tidal disruption of binary stars passing close to the supermassive black hole (SMBH) which resides in the center of the Galaxy. It is, however, still unclear where these relatively young stars were born and what dynamical process pushed them to nearly radial orbits around the SMBH. In this paper we investigate the possibility that the young binaries originated from a thin eccentric disk, similar to the one currently observed in the Galactic center. By means of direct Nmore » -body simulations, we follow the dynamical evolution of an initially thin and eccentric disk of stars with a 100% binary fraction orbiting around the SMBH. Such a configuration leads to Kozai–Lidov oscillations of orbital elements, bringing a considerable number of binaries to the close vicinity of the black hole. Subsequent tidal disruption of these binaries accelerates one of their components to velocities well above the escape velocity from the SMBH, while the second component becomes tightly bound to the SMBH. We describe the main kinematic properties of the escaping and tightly bound stars within our model, and compare them qualitatively to the properties of the observed HVSs and S-stars, respectively. The most prominent feature is strong anisotropy in the directions of the escaping stars, which is observed for Galactic HVSs but has not yet been explained.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohanty, Soumya D.; Nayak, Rajesh K.

The space based gravitational wave detector LISA (Laser Interferometer Space Antenna) is expected to observe a large population of Galactic white dwarf binaries whose collective signal is likely to dominate instrumental noise at observational frequencies in the range 10{sup -4} to 10{sup -3} Hz. The motion of LISA modulates the signal of each binary in both frequency and amplitude--the exact modulation depending on the source direction and frequency. Starting with the observed response of one LISA interferometer and assuming only Doppler modulation due to the orbital motion of LISA, we show how the distribution of the entire binary population inmore » frequency and sky position can be reconstructed using a tomographic approach. The method is linear and the reconstruction of a delta-function distribution, corresponding to an isolated binary, yields a point spread function (psf). An arbitrary distribution and its reconstruction are related via smoothing with this psf. Exploratory results are reported demonstrating the recovery of binary sources, in the presence of white Gaussian noise.« less

A HST Search to Constrain the Binary Fraction of Stripped-Envelope Supernovae

NASA Astrophysics Data System (ADS)

Fox, Ori

2018-01-01

Stripped-envelope supernovae (e.g., SNe IIb, Ib, and Ic) refer to a subset of core-collapse explosions with progenitors that have lost some fraction of their outer envelopes in pre-SN mass loss. Mounting evidence over the past decade suggests that the mass loss in a large fraction of these systems occurs due to binary interaction. An unbiased, statistically significant sample of companion-star characteristics (including deep upper limits) can constrain the binary fraction, having direct implications on the theoretical physics of both single star and binary evolution. To date, however, only two detections have been made: SNe 1993J and 2011dh. Over the past year, we have improved this sample with an HST WFC3/NUV survey for binary companions of three additional nearby stripped-envelope SNe: 2002ap, 2001ig, and 2010br. I will present a review of previous companion searches and results from our current HST survey, which include one detection and two meaningful upper limits.

Experimental observation of the influence of furnace temperature profile on convection and segregation in the vertical Bridgman crystal growth technique

NASA Technical Reports Server (NTRS)

Neugebauer, G. T.; Wilcox, W. R.

1990-01-01

Azulene-doped naphtalene was directionally solidified using the vertical Bridgman-Stockbarger technique. Doping homogeneity and convection are determined as a function of the temperature profile in the furnace and the freezing rate. Convective velocities are two orders of magnitude lower when the temperature increases with height. The cross sectional variation in azulene concentration tends to be asymmetric. Neither rotation of the ampoule nor deliberate introduction of thermal asymmetries during solidification had a significant influence on cross sectional variations in doping. It is predicted that slow directional solidification under microgravity conditions can produce greater inhomogeneities than on earth. Thus when low freezing rates are necessary in order to avoid constitutional supercooling, it may be necessary to combine microgravity and magnetic fields in order to achieve homogeneous crystals.

Hierarchical colorant-based direct binary search halftoning.

PubMed

He, Zhen

2010-07-01

Colorant-based direct binary search (CB-DBS) halftoning proposed in provides an image quality benchmark for dispersed-dot halftoning algorithms. The objective of this paper is to further push the image quality limit. An algorithm called hierarchical colorant-based direct binary search (HCB-DBS) is developed in this paper. By appropriately integrating yellow colorant into dot-overlapping and dot-positioning controls, it is demonstrated that HCB-DBS can achieve better halftone texture of both individual and joint dot-color planes, without compromising the dot distribution of more visible halftone of cyan and magenta colorants. The input color specification is first converted from colorant space to dot-color space with minimum brightness variation principle for full dot-overlapping control. The dot-colors are then split into groups based upon dot visibility. Hierarchical monochrome DBS halftoning is applied to make dot-positioning decision for each group, constrained on the already generated halftone of the groups with higher priority. And dot-coloring is decided recursively with joint monochrome DBS halftoning constrained on the related total dot distribution. Experiments show HCB-DBS improves halftone texture for both individual and joint dot-color planes. And it reduces the halftone graininess and free of color mottle artifacts, comparing to CB-DBS.

Tuning into Scorpius X-1: adapting a continuous gravitational-wave search for a known binary system

NASA Astrophysics Data System (ADS)

Meadors, Grant David; Goetz, Evan; Riles, Keith

2016-05-01

We describe how the TwoSpect data analysis method for continuous gravitational waves (GWs) has been tuned for directed sources such as the low-mass X-ray binary (LMXB), Scorpius X-1 (Sco X-1). A comparison of five search algorithms generated simulations of the orbital and GW parameters of Sco X-1. Whereas that comparison focused on relative performance, here the simulations help quantify the sensitivity enhancement and parameter estimation abilities of this directed method, derived from an all-sky search for unknown sources, using doubly Fourier-transformed data. Sensitivity is shown to be enhanced when the source sky location and period are known, because we can run a fully templated search, bypassing the all-sky hierarchical stage using an incoherent harmonic sum. The GW strain and frequency, as well as the projected semi-major axis of the binary system, are recovered and uncertainty estimated, for simulated signals that are detected. Upper limits for GW strain are set for undetected signals. Applications to future GW observatory data are discussed. Robust against spin-wandering and computationally tractable despite an unknown frequency, this directed search is an important new tool for finding gravitational signals from LMXBs.

Gravitational waves from rotating neutron stars and compact binary systems

NASA Astrophysics Data System (ADS)

Wade, Leslie E., IV

It is widely anticipated that the first direct detections of gravitational waves will be made by advanced gravitational-wave detectors, such as the two Laser Interferometer Gravitational-wave Observatories (LIGO) and the Virgo interferometer. In preparation for the advanced detector era, I have worked on both detection and post-detection efforts involving two gravitational wave sources: isolated rotating neutron stars (NSs) and compact binary coalescences (CBCs). My dissertation includes three main research projects: 1) a population synthesis study assessing the detectability of isolated NSs, 2) a CBC search for intermediate-mass black-hole binaries (IMBHBs), and 3) new methods for directly measuring the neutron-star (NS) equation of state (EOS). Direct detections of gravitational waves will enrich our current astrophysical knowledge. One such contribution will be through population synthesis of isolated NSs. My collaborators and I show that advanced gravitational-wave detectors can be used to constrain the properties of the Galactic NS population. Gravitational wave detections can also shine light on a currently mysterious astrophysical object: intermediate mass black holes. In developing the IMBHB search, we performed a mock data challenge where signals with total masses up to a few hundred solar masses were injected into recolored data from LIGO's sixth science run. Since this is the first time a matched filter search has been developed to search for IMBHBs, I discuss what was learned during the mock data challenge and how we plan to improve the search going forward. The final aspect of my dissertation focuses on important post-detection science. I present results for a new method of directly measuring the NS EOS. This is done by estimating the parameters of a 4-piece polytropic EOS model that matches theoretical EOS candidates to a few percent. We show that advanced detectors will be capable of measuring the NS radius to within a kilometer for stars with canonical masses. However, this can only be accomplished with binary NS waveform models that are accurate to the rich EOS physics that happens near merger. We show that the waveforms typically used to model binary NS systems result in unavoidable systematic error that can significantly bias the estimation of the NS EOS.

A New Orbit for the Eclipsing Binary V577 Oph

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jeffery, Elizabeth J.; Barnes, Thomas G. III; Montemayor, Thomas J.

Pulsating stars in eclipsing binary systems are unique objects for providing constraints on stellar models. To fully leverage the information available from the binary system, full orbital radial velocity curves must be obtained. We report 23 radial velocities for components of the eclipsing binary V577 Oph, whose primary star is a δ Sct variable. The velocities cover a nearly complete orbit and a time base of 20 years. We computed orbital elements for the binary and compared them to the ephemeris computed by Creevey et al. The comparison shows marginally different results. In particular, a change in the systemic velocitymore » by −2 km s{sup −1} is suggested by our results. We compare this systemic velocity difference to that expected due to reflex motion of the binary in response to the third body in the system. The systemic velocity difference is consistent with reflex motion, given our mass determination for the eclipsing binary and the orbital parameters determined by Volkov and Volkova for the three-body orbit. We see no evidence for the third body in our spectra, but we do see strong interstellar Na D lines that are consistent in strength with the direction and expected distance of V577 Oph.« less

Gene-specific cell labeling using MiMIC transposons

PubMed Central

Gnerer, Joshua P.; Venken, Koen J. T.; Dierick, Herman A.

2015-01-01

Binary expression systems such as GAL4/UAS, LexA/LexAop and QF/QUAS have greatly enhanced the power of Drosophila as a model organism by allowing spatio-temporal manipulation of gene function as well as cell and neural circuit function. Tissue-specific expression of these heterologous transcription factors relies on random transposon integration near enhancers or promoters that drive the binary transcription factor embedded in the transposon. Alternatively, gene-specific promoter elements are directly fused to the binary factor within the transposon followed by random or site-specific integration. However, such insertions do not consistently recapitulate endogenous expression. We used Minos-Mediated Integration Cassette (MiMIC) transposons to convert host loci into reliable gene-specific binary effectors. MiMIC transposons allow recombinase-mediated cassette exchange to modify the transposon content. We developed novel exchange cassettes to convert coding intronic MiMIC insertions into gene-specific binary factor protein-traps. In addition, we expanded the set of binary factor exchange cassettes available for non-coding intronic MiMIC insertions. We show that binary factor conversions of different insertions in the same locus have indistinguishable expression patterns, suggesting that they reliably reflect endogenous gene expression. We show the efficacy and broad applicability of these new tools by dissecting the cellular expression patterns of the Drosophila serotonin receptor gene family. PMID:25712101

Thermal-structural analyses of Space Shuttle Main Engine (SSME) hot section components

NASA Technical Reports Server (NTRS)

Abdul-Aziz, Ali; Thompson, Robert L.

1988-01-01

Three dimensional nonlinear finite element heat transfer and structural analyses were performed for the first stage high pressure fuel turbopump (HPFTP) blade of the space shuttle main engine (SSME). Directionally solidified (DS) MAR-M 246 and single crystal (SC) PWA-1480 material properties were used for the analyses. Analytical conditions were based on a typical test stand engine cycle. Blade temperature and stress strain histories were calculated by using the MARC finite element computer code. The structural response of an SSME turbine blade was assessed and a greater understanding of blade damage mechanisms, convective cooling effects, and thermal mechanical effects was gained.

Evaluation of an advanced directionally solidified gamma/gamma'-alpha Mo eutectic alloy

NASA Technical Reports Server (NTRS)

Henry, M. F.; Jackson, M. R.; Gigliotti, M. F. X.; Nelson, P. B.

1979-01-01

An attempt was made to improve on the properties of the candidate jet engine turbine blade material AG-60, a gamma/gamma prime-alpha Mo eutectic composite. Alloy 38 (AG-170) was evaluated in the greatest detail. This alloy, Ni-5.88 A1-29.74 Mo-1.65 V-1.2C Re (weight percent), represents an improvement beyond AG-60, based on mechanical testing of the transverse and/or longitudinal orientations over a range of temperatures in tension, shear, rupture, and rupture after thermal exposure. It is likely that other alloys in the study represent a similar improvement.

Medical waste treatment and decontamination system

DOEpatents

Wicks, George G.; Schulz, Rebecca L.; Clark, David E.

2001-01-01

The invention discloses a tandem microwave system consisting of a primary chamber in which hybrid microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional hybrid microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.

Effect of thermal cycling in a Mach 0.3 burner rig on properties and structure of directionally solidified gamma/gamma prime - delta eutectic

NASA Technical Reports Server (NTRS)

Gray, H. R.; Sanders, W. A.

1975-01-01

Tensile and stress rupture properties at 1040 C of a thermally cycled gamma/gamma prime - delta eutectic were essentially equivalent to the as-grown properties. Tensile strength and rupture life at 760 C appeared to decrease slightly by thermal cycling. Thermal cycling resulted in gamma prime coarsening and Widmanstatten delta precipitation in the gamma phase. An unidentified precipitate, presumably gamma prime, was observed within the delta phase. The eutectic alloy exhibited a high rate of oxidation-erosion weight loss during thermal cycling in the Mach 0.3 burner rig.

Effects of Hafnium Additions on the Solidification Behavior of Directionally Solidified Superalloys.

DTIC Science & Technology

1981-10-01

h t (3-1) : where R is the instantaneous rate and h is the transient height. This transient was computed ahead of time on an IBM 370 interactive...form of thermocouple EMF output vs. time, taken at various positions serve as input parameters for the TCTEMP deck for the IBM 370. In its present...iuDv oWIiCNA u 41 S~Q 0 01 0, 0 0 0 % 00 .0 C) 1 0o u- I 0 o0 N 0N Itp 0 0 oitoain3 iuOOJ~d aflOA oian WUOied awnlOA S 1241 - 5 .A - _ A A - S

Tandem microwave waste remediation and decontamination system

DOEpatents

Wicks, George G.; Clark, David E.; Schulz, Rebecca L.

1999-01-01

The invention discloses a tandem microwave system consisting of a primary chamber in which microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.

Design quadrilateral apertures in binary computer-generated holograms of large space bandwidth product.

PubMed

Wang, Jing; Sheng, Yunlong

2016-09-20

A new approach for designing the binary computer-generated hologram (CGH) of a very large number of pixels is proposed. Diffraction of the CGH apertures is computed by the analytical Abbe transform and by considering the aperture edges as the basic diffracting elements. The computation cost is independent of the CGH size. The arbitrary-shaped polygonal apertures in the CGH consist of quadrilateral apertures, which are designed by assigning the binary phases using the parallel genetic algorithm with a local search, followed by optimizing the locations of the co-vertices with a direct search. The design results in high performance with low image reconstruction error.

In-situ observation of switchable nanoscale topography for y-shaped binary brushes in fluids.

PubMed

Lin, Yen-Hsi; Teng, Jing; Zubarev, Eugene R; Shulha, Hennady; Tsukruk, Vladimir V

2005-03-01

Direct, in-fluid observation of the surface morphology and nanomechanical properties of the mixed brushes composed of Y-shaped binary molecules PS-PAA revealed nanoscale network-like surface topography formed by coexisting stretched soluble PAA arms and collapsed insoluble PS chains in water. Placement of Y-shaped brushes in different fluids resulted in dramatic reorganization ranging from soft repellent layer covered by swollen PS arms in toluene to an adhesive, mixed layer composed of coexisting swollen PAA and collapsed PS arms in water. These binary layers with the overall nanoscale thickness can serve as adaptive nanocoatings with stimuli-responsive properties.

Low Pt content direct methanol fuel cell anode catalyst: nanophase PtRuNiZr

NASA Technical Reports Server (NTRS)

Whitacre, Jay F. (Inventor); Narayanan, Sekharipuram R. (Inventor)

2010-01-01

A method for the preparation of a metallic material having catalytic activity that includes synthesizing a material composition comprising a metal content with a lower Pt content than a binary alloy containing Pt but that displays at least a comparable catalytic activity on a per mole Pt basis as the binary alloy containing Pt; and evaluating a representative sample of the material composition to ensure that the material composition displays a property of at least a comparable catalytic activity on a per mole Pt basis as a representative binary alloy containing Pt. Furthermore, metallic compositions are disclosed that possess substantial resistance to corrosive acids.

Method for treating materials for solidification

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Martin, Hollis L.

1995-01-01

A method for treating materials such as wastes for solidification to form a solid, substantially nonleachable product. Addition of reactive silica rather than ordinary silica to the material when bringing the initial molar ratio of its silica constituent to a desired ratio within a preselected range increases the solubility and retention of the materials in the solidified matrix. Materials include hazardous, radioactive, mixed, and heavy metal species. Amounts of other constituents of the material, in addition to its silica content are also added so that the molar ratio of each of these constituents is within the preselected ranges for the final solidified product. The mixture is then solidified by cement solidification or vitrification. The method can be used to treat a variety of wastes, including but not limited to spent filter aids from waste water treatment, waste sludges, combinations of spent filter aids and waste sludges, combinations of supernate and waste sludges, incinerator ash, incinerator offgas blowdown, combinations of incinerator ash and offgas blowdown, cementitious wastes and contaminated soils.

Dispersoid reinforced alloy powder and method of making

DOEpatents

Anderson, Iver E; Rieken, Joel

2013-12-10

A method of making dispersion-strengthened alloy particles involves melting an alloy having a corrosion and/or oxidation resistance-imparting alloying element, a dispersoid-forming element, and a matrix metal wherein the dispersoid-forming element exhibits a greater tendency to react with an introduced reactive species than does the alloying element and wherein one or more atomizing parameters is/are modified to controllably reduce the amount of the reactive species, such as oxygen, introduced into the atomized particles so as to reduce anneal times and improve reaction (conversion) to the desired strengthening dispersoids in the matrix. The atomized alloy particles are solidified as solidified alloy particles or as a solidified deposit of alloy particles. Bodies are made from the dispersion strengthened alloy particles, deposit thereof, exhibit enhanced fatigue and creep resistance and reduced wear as well as enhanced corrosion and/or oxidation resistance at high temperatures by virtue of the presence of the corrosion and/or oxidation resistance imparting alloying element in solid solution in the particle alloy matrix.

Advances in Pb-free solder microstructure control and interconnect design

DOE PAGES

Reeve, Kathlene N.; Holaday, John R.; Choquette, Stephanie M.; ...

2016-06-09

New electronics applications demanding enhanced performance and higher operating temperatures have led to continued research in the field of Pb-free solder designs and interconnect solutions. In this paper, recent advances in the microstructural design of Pb-free solders and interconnect systems were discussed by highlighting two topics: increasing β-Sn nucleation in Sn-based solders, and isothermally solidified interconnects using transient liquid phases. Issues in β-Sn nucleation in Sn-based solders were summarized in the context of Swenson’s 2007 review of the topic. Recent advancements in the areas of alloy composition manipulation, nucleating heterogeneities, and rapid solidification were discussed, and a proposal based onmore » a multi-faceted solidification approach involving the promotion of constitutional undercooling and nucleating heterogeneities was outlined for future research. The second half of the paper analyzed two different approaches to liquid phase diffusion bonding as a replacement for high-Pb solders, one based on the application of the pseudo-binary Cu-Ni-Sn ternary system, and the other on a proposed thermodynamic framework for identifying potential ternary alloys for liquid phase diffusion bonding. Furthermore, all of the concepts reviewed relied upon the fundamentals of thermodynamics, kinetics, and solidification, to which Jack Smith substantially contributed during his scientific career.« less

A Keplerian Disk around Orion SrCI, a ∼ 15 M ⊙ YSO

NASA Astrophysics Data System (ADS)

Ginsburg, Adam; Bally, John; Goddi, Ciriaco; Plambeck, Richard; Wright, Melvyn

2018-06-01

We report ALMA long-baseline observations of Orion Source I (SrcI), with a resolution 0.″03–0.″06 (12–24 au) at 1.3 and 3.2 mm. We detect both continuum and spectral line emission from SrcI’s disk. We also detect a central weakly resolved source that we interpret as a hot spot in the inner disk, which may indicate the presence of a binary system. The high angular resolution and sensitivity of these observations allows us to measure the outer envelope of the rotation curve of the H2O {5}5,0}{--}{6}4,3} line, which gives a mass M I ≈ 15 ± 2 {M}ȯ . We detected several other lines that more closely trace the disk, but were unable to identify their parent species. Using centroid-of-channel methods on these other lines, we infer a similar mass. These measurements solidify SrcI as a genuine high-mass protostar system and support the theory that SrcI and the Becklin-Neugebauer Object were ejected from the dynamical decay of a multiple-star system ∼500 years ago, an event that also launched the explosive molecular outflow in Orion.

DETECTION OF WHITE DWARF COMPANIONS TO BLUE STRAGGLERS IN THE OPEN CLUSTER NGC 188: DIRECT EVIDENCE FOR RECENT MASS TRANSFER

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gosnell, Natalie M.; Mathieu, Robert D.; Geller, Aaron M.

2014-03-01

Several possible formation pathways for blue straggler stars have been developed recently, but no one pathway has yet been observationally confirmed for a specific blue straggler. Here we report the first findings from a Hubble Space Telescope Advanced Camera for Surveys/Solar Blind Channel far-UV photometric program to search for white dwarf companions to blue straggler stars. We find three hot and young white dwarf companions to blue straggler stars in the 7 Gyr open cluster NGC 188, indicating that mass transfer in these systems ended less than 300 Myr ago. These companions are direct and secure observational evidence that these blue straggler starsmore » were formed through mass transfer in binary stars. Their existence in a well-studied cluster environment allows for observational constraints of both the current binary system and the progenitor binary system, mapping the entire mass transfer history.« less

Directional Solidification and Characterization of Hg(0.89) Mn(0.11)Te

NASA Technical Reports Server (NTRS)

Price, M. W.; Scripa, R. N.; Lehoczky. S. L.; Szofran, F. R.; Su, C.-H.

1998-01-01

Two boules of Hg(0.89)Mn(0.11)Te(MMT) were solidified using the vertical Bridgman-Stockbarger method. Translation rates of 0.09 and 0. 18 microns/s were used. The influence of growth rate on axial compositional homogeneity in the MMT boules was evaluated experimentally by conducting precision density measurements on radial slices taken from each boule. In addition, Plane Front Solidification theory and segregation coefficient (k) data for the Hg(1-x)Mn(x)Te system were used to fit theoretical composition profiles to the measured MMT axial composition profiles. The strong correlation between the measured and calculated MMT axial composition profiles indicates diffusion dominated axial solute redistribution in the boules under the applied growth conditions. The analysis of the MMT axial composition profiles by Plane Front Solidification theory allowed the calculation of the effective diffusion coefficient (D(eff) = 3.5 x l0(exp -5) sq cm/s). The k-values for the Hg(1-x)Mn(x)Te system and the D(sub eff) - value were then used to verify that both boules were solidified under conditions which did not exceed the Constitutional Supercooling Criteria under ideal conditions. Finally, a preliminary examination of the radial compositional variation in each MMT was made using Fourier Transform Infra-Red Spectroscopy (FTIR). The radial homogeneity in the MMT boules was found to be comparable for both translation rates.

Experimental study and thermodynamic modeling of the phase relation in the Fe-S-Si system with implications for the distribution of S and Si in a partially solidified core

NASA Astrophysics Data System (ADS)

Tao, R.; Fei, Y.

2017-12-01

Planetary cooling leads to solidification of any initially molten metallic core. Some terrestrial cores (e.g. Mercury) are formed and differentiated under relatively reduced conditions, and they are thought to be composed of Fe-S-Si. However, there are limited understanding of the phase relations in the Fe-S-Si system at high pressure and temperature. In this study, we conducted high-pressure experiments to investigate the phase relations in the Fe-S-Si system up to 25 GPa. Experimental results show that the liquidus and solidus in this study are slightly lower than those in the Fe-S binary system for the same S concentration in liquid at same pressure. The Fe3S, which is supposed to be the stable sub-solidus S-bearing phase in the Fe-S binary system above 17 GPa, is not observed in the Fe-S-Si system at 21 GPa. Almost all S prefers to partition into liquid, while the distribution of Si between solid and liquid depends on experimental P and T conditions. We obtained the partition coefficient log(KDSi) by fitting the experimental data as a function of P, T and S concentration in liquid. At a constant pressure, the log(KDSi) linearly decreases with 1/T(K). With increase of pressure, the slopes of linear correlation between log(KDSi) and 1/T(K) decreases, indicating that more Si partitions into solid at higher pressure. In order to interpolate and extrapolate the phase relations over a wide pressure and temperature range, we established a comprehensive thermodynamic model in the Fe-S-Si system. The results will be used to constrain the distribution of S and Si between solid inner core and liquid outer core for a range of planet sizes. A Si-rich solid inner core and a S-rich liquid outer core are suggested for an iron-rich core.

Micro and Macro Segregation in Alloys Solidifying with Equiaxed Morphology

NASA Technical Reports Server (NTRS)

Stefanescu, Doru M.; Curreri, Peter A.; Leon-Torres, Jose; Sen, Subhayu

1996-01-01

To understand macro segregation formation in Al-Cu alloys, experiments were run under terrestrial gravity (1g) and under low gravity during parabolic flights (10(exp -2) g). Alloys of two different compositions (2% and 5% Cu) were solidified at two different cooling rates. Systematic microscopic and SEM observations produced microstructural and segregation maps for all samples. These maps may be used as benchmark experiments for validation of microstructure evolution and segregation models. As expected, the macro segregation maps are very complex. When segregation was measured along the central axis of the sample, the highest macro segregation for samples solidified at 1g was obtained for the lowest cooling rate. This behavior is attributed to the longer time available for natural convection and shrinkage flow to affect solute redistribution. In samples solidified under low-g, the highest macro-segregation was obtained at the highest cooling rate. In general, low-gravity solidification resulted in less segregation. To explain the experimental findings, an analytical (Flemings-Nereo) and a numerical model were used. For the numerical model, the continuum formulation was employed to describe the macroscopic transports of mass, energy, and momentum, associated with the microscopic transport phenomena, for a two-phase system. The model proposed considers that liquid flow is driven by thermal and solutal buoyancy, and by solidification shrinkage. The Flemings-Nereo model explains well macro segregation in the initial stages of low-gravity segregation. The numerical model can describe the complex macro segregation pattern and the differences between low- and high-gravity solidification.

Experimental study on the foundation of soft soil solidification formula based on the Design - Expert software search

NASA Astrophysics Data System (ADS)

Qian, Chaojun; Li, Dahua; Zhang, xian; Zhou, Dongqing; Zhang, Baoliang

2017-08-01

Xuan city + 1100 kv search for converter station in Anhui province, in the process of foundation treatment, there is a cloth with a large number of lacustrine soft soil can not reach the need of engineering construction, so we want to cure the soft soil. By combining ratio of blast furnace slag (GGBS), gypsum, exciting agent CaO as a main curing agent for combination of reinforcing soft soil, the indoor unconfined compressive strength test, the influence factors on blast furnace slag, exciting agent and dosage of gypsum as impact factors, response value is 7 d and 28 d unconfined compressive strength of solidified soil, the experimental method is the Box - Behnken. The results show that the 7 d gypsum and the interaction of the blast furnace slag is obvious; 28 d exciting agent and gypsum interaction is obvious. By the analysis plaster, CaO, GGBSIn 7 d optimal proportion is 3.71%, 3.62%, 12.18%, the actual strength of the solidified soil age 1479.33 kPa; 28 d optimal proportion was 4.08%, 4.50%, 11.6%, the actual strength of the solidified soil age 2936.78 kPa. In the soil and the water curing effect of GGBS solidified soil, thereby GGBS this is a kind of new solidification material that can be used as the engineering foundation treatment of soft soil stabilizer has a certain value.

Binary Cepheids: Separations and Mass Ratios in 5 Solar Mass Binaries

DTIC Science & Technology

2013-10-01

astrometry, photometry , direct imaging), each with selection biases. However, Cepheids—cool, evolved stars of∼5M—are a special case because ultraviolet...detected velocity variability. In an imaging survey with the Hubble Space Telescope Wide Field Camera 3, we resolved three of the companions (those...1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and

Search for High-energy Neutrinos from Binary Neutron Star Merger GW170817 with ANTARES, IceCube, and the Pierre Auger Observatory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Albert, A.; André, M.; Anghinolfi, M.

The Advanced LIGO and Advanced Virgo observatories recently discovered gravitational waves from a binary neutron star inspiral. A short gamma-ray burst (GRB) that followed the merger of this binary was also recorded by the Fermi Gamma-ray Burst Monitor (Fermi-GBM), and the Anti-Coincidence Shield for the Spectrometer for the International Gamma-Ray Astrophysics Laboratory (INTEGRAL), indicating particle acceleration by the source. The precise location of the event was determined by optical detections of emission following the merger. We searched for high-energy neutrinos from the merger in the GeV–EeV energy range using the Antares, IceCube, and Pierre Auger Observatories. No neutrinos directionally coincidentmore » with the source were detected within ±500 s around the merger time. Additionally, no MeV neutrino burst signal was detected coincident with the merger. We further carried out an extended search in the direction of the source for high-energy neutrinos within the 14 day period following the merger, but found no evidence of emission. We used these results to probe dissipation mechanisms in relativistic outflows driven by the binary neutron star merger. The non-detection is consistent with model predictions of short GRBs observed at a large off-axis angle.« less

An efficient coding algorithm for the compression of ECG signals using the wavelet transform.

PubMed

Rajoub, Bashar A

2002-04-01

A wavelet-based electrocardiogram (ECG) data compression algorithm is proposed in this paper. The ECG signal is first preprocessed, the discrete wavelet transform (DWT) is then applied to the preprocessed signal. Preprocessing guarantees that the magnitudes of the wavelet coefficients be less than one, and reduces the reconstruction errors near both ends of the compressed signal. The DWT coefficients are divided into three groups, each group is thresholded using a threshold based on a desired energy packing efficiency. A binary significance map is then generated by scanning the wavelet decomposition coefficients and outputting a binary one if the scanned coefficient is significant, and a binary zero if it is insignificant. Compression is achieved by 1) using a variable length code based on run length encoding to compress the significance map and 2) using direct binary representation for representing the significant coefficients. The ability of the coding algorithm to compress ECG signals is investigated, the results were obtained by compressing and decompressing the test signals. The proposed algorithm is compared with direct-based and wavelet-based compression algorithms and showed superior performance. A compression ratio of 24:1 was achieved for MIT-BIH record 117 with a percent root mean square difference as low as 1.08%.

Search for High-energy Neutrinos from Binary Neutron Star Merger GW170817 with ANTARES, IceCube, and the Pierre Auger Observatory

DOE PAGES

Albert, A.; André, M.; Anghinolfi, M.; ...

2017-11-29

The Advanced LIGO and Advanced Virgo observatories recently discovered gravitational waves from a binary neutron star inspiral. A short gamma-ray burst (GRB) that followed the merger of this binary was also recorded by the Fermi Gamma-ray Burst Monitor (Fermi-GBM), and the Anti-Coincidence Shield for the Spectrometer for the International Gamma-Ray Astrophysics Laboratory (INTEGRAL), indicating particle acceleration by the source. The precise location of the event was determined by optical detections of emission following the merger. We searched for high-energy neutrinos from the merger in the GeV–EeV energy range using the Antares, IceCube, and Pierre Auger Observatories. No neutrinos directionally coincidentmore » with the source were detected within ±500 s around the merger time. Additionally, no MeV neutrino burst signal was detected coincident with the merger. We further carried out an extended search in the direction of the source for high-energy neutrinos within the 14 day period following the merger, but found no evidence of emission. We used these results to probe dissipation mechanisms in relativistic outflows driven by the binary neutron star merger. The non-detection is consistent with model predictions of short GRBs observed at a large off-axis angle.« less

Directed assembly of binary monolayers with a high protein affinity: infrared reflection absorption spectroscopy (IRRAS) and surface plasmon resonance (SPR).

PubMed

Du, Xuezhong; Wang, Yuchun

2007-03-08

Infrared reflection absorption spectroscopy (IRRAS) and surface plasmon resonance (SPR) techniques have been employed to investigate human serum albumin (HSA) binding to binary monolayers of zwitterionic dipalmitoylphosphatidylcholine (DPPC) and cationic dioctadecyldimethylammonium bromide (DOMA). At the air-water interface, the favorable electrostatic interaction between DPPC and DOMA leads to a dense chain packing. The tilt angle of the hydrocarbon chains decreases with increasing mole fraction of DOMA (X(DOMA)) in the monolayers at the surface pressure 30 mN/m: DPPC ( approximately 30 degrees ), X(DOMA) = 0.1 ( approximately 15 degrees ), and X(DOMA) = 0.3 ( approximately 0 degrees ). Negligible protein binding to the DPPC monolayer is observed in contrast to a significant binding to the binary monolayers. After HSA binding, the hydrocarbon chains at X(DOMA) = 0.1 undergo an increase in tilt angle from 15 degrees to 25 approximately 30 degrees , and the chains at X(DOMA) = 0.3 remain almost unchanged. The two components in the monolayers deliver through lateral reorganization, induced by the protein in the subphase, to form multiple interaction sites favorable for protein binding. The surfaces with a high protein affinity are created through the directed assembly of binary monolayers for use in biosensing.

Search for High-energy Neutrinos from Binary Neutron Star Merger GW170817 with ANTARES, IceCube, and the Pierre Auger Observatory

NASA Astrophysics Data System (ADS)

Albert, A.; André, M.; Anghinolfi, M.; Ardid, M.; Aubert, J.-J.; Aublin, J.; Avgitas, T.; Baret, B.; Barrios-Martí, J.; Basa, S.; Belhorma, B.; Bertin, V.; Biagi, S.; Bormuth, R.; Bourret, S.; Bouwhuis, M. C.; Brânzaş, H.; Bruijn, R.; Brunner, J.; Busto, J.; Capone, A.; Caramete, L.; Carr, J.; Celli, S.; Cherkaoui El Moursli, R.; Chiarusi, T.; Circella, M.; Coelho, J. A. B.; Coleiro, A.; Coniglione, R.; Costantini, H.; Coyle, P.; Creusot, A.; Díaz, A. F.; Deschamps, A.; De Bonis, G.; Distefano, C.; Di Palma, I.; Domi, A.; Donzaud, C.; Dornic, D.; Drouhin, D.; Eberl, T.; El Bojaddaini, I.; El Khayati, N.; Elsässer, D.; Enzenhöfer, A.; Ettahiri, A.; Fassi, F.; Felis, I.; Fusco, L. A.; Gay, P.; Giordano, V.; Glotin, H.; Grégoire, T.; Ruiz, R. Gracia; Graf, K.; Hallmann, S.; van Haren, H.; Heijboer, A. J.; Hello, Y.; Hernández-Rey, J. J.; Hößl, J.; Hofestädt, J.; Illuminati, G.; James, C. W.; de Jong, M.; Jongen, M.; Kadler, M.; Kalekin, O.; Katz, U.; Kießling, D.; Kouchner, A.; Kreter, M.; Kreykenbohm, I.; Kulikovskiy, V.; Lachaud, C.; Lahmann, R.; Lefèvre, D.; Leonora, E.; Lotze, M.; Loucatos, S.; Marcelin, M.; Margiotta, A.; Marinelli, A.; Martínez-Mora, J. A.; Mele, R.; Melis, K.; Michael, T.; Migliozzi, P.; Moussa, A.; Navas, S.; Nezri, E.; Organokov, M.; Păvălaş, G. E.; Pellegrino, C.; Perrina, C.; Piattelli, P.; Popa, V.; Pradier, T.; Quinn, L.; Racca, C.; Riccobene, G.; Sánchez-Losa, A.; Saldaña, M.; Salvadori, I.; Samtleben, D. F. E.; Sanguineti, M.; Sapienza, P.; Schüssler, F.; Sieger, C.; Spurio, M.; Stolarczyk, Th.; Taiuti, M.; Tayalati, Y.; Trovato, A.; Turpin, D.; Tönnis, C.; Vallage, B.; Van Elewyck, V.; Versari, F.; Vivolo, D.; Vizzoca, A.; Wilms, J.; Zornoza, J. D.; Zúñiga, J.; ANTARES Collaboration; Aartsen, M. G.; Ackermann, M.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Ahrens, M.; Samarai, I. Al; Altmann, D.; Andeen, K.; Anderson, T.; Ansseau, I.; Anton, G.; Argüelles, C.; Auffenberg, J.; Axani, S.; Bagherpour, H.; Bai, X.; Barron, J. P.; Barwick, S. W.; Baum, V.; Bay, R.; Beatty, J. J.; Becker Tjus, J.; Becker, K.-H.; BenZvi, S.; Berley, D.; Bernardini, E.; Besson, D. Z.; Binder, G.; Bindig, D.; Blaufuss, E.; Blot, S.; Bohm, C.; Börner, M.; Bos, F.; Bose, D.; Böser, S.; Botner, O.; Bourbeau, E.; Bourbeau, J.; Bradascio, F.; Braun, J.; Brayeur, L.; Brenzke, M.; Bretz, H.-P.; Bron, S.; Brostean-Kaiser, J.; Burgman, A.; Carver, T.; Casey, J.; Casier, M.; Cheung, E.; Chirkin, D.; Christov, A.; Clark, K.; Classen, L.; Coenders, S.; Collin, G. H.; Conrad, J. M.; Cowen, D. F.; Cross, R.; Day, M.; de André, J. P. A. M.; De Clercq, C.; DeLaunay, J. J.; Dembinski, H.; De Ridder, S.; Desiati, P.; de Vries, K. D.; de Wasseige, G.; de With, M.; DeYoung, T.; Díaz-Vélez, J. C.; di Lorenzo, V.; Dujmovic, H.; Dumm, J. 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T.; Raab, C.; Rädel, L.; Rameez, M.; Rawlins, K.; Rea, I. C.; Reimann, R.; Relethford, B.; Relich, M.; Resconi, E.; Rhode, W.; Richman, M.; Robertson, S.; Rongen, M.; Rott, C.; Ruhe, T.; Ryckbosch, D.; Rysewyk, D.; Sälzer, T.; Sanchez Herrera, S. E.; Sandrock, A.; Sandroos, J.; Santander, M.; Sarkar, S.; Sarkar, S.; Satalecka, K.; Schlunder, P.; Schmidt, T.; Schneider, A.; Schoenen, S.; Schöneberg, S.; Schumacher, L.; Seckel, D.; Seunarine, S.; Soedingrekso, J.; Soldin, D.; Song, M.; Spiczak, G. M.; Spiering, C.; Stachurska, J.; Stamatikos, M.; Stanev, T.; Stasik, A.; Stettner, J.; Steuer, A.; Stezelberger, T.; Stokstad, R. G.; Stößl, A.; Strotjohann, N. L.; Stuttard, T.; Sullivan, G. W.; Sutherland, M.; Taboada, I.; Tatar, J.; Tenholt, F.; Ter-Antonyan, S.; Terliuk, A.; Tešić, G.; Tilav, S.; Toale, P. A.; Tobin, M. N.; Toscano, S.; Tosi, D.; Tselengidou, M.; Tung, C. F.; Turcati, A.; Turley, C. F.; Ty, B.; Unger, E.; Usner, M.; Vandenbroucke, J.; Van Driessche, W.; van Eijndhoven, N.; Vanheule, S.; van Santen, J.; Vehring, M.; Vogel, E.; Vraeghe, M.; Walck, C.; Wallace, A.; Wallraff, M.; Wandler, F. D.; Wandkowsky, N.; Waza, A.; Weaver, C.; Weiss, M. J.; Wendt, C.; Werthebach, J.; Westerhoff, S.; Whelan, B. J.; Wiebe, K.; Wiebusch, C. H.; Wille, L.; Williams, D. R.; Wills, L.; Wolf, M.; Wood, J.; Wood, T. R.; Woolsey, E.; Woschnagg, K.; Xu, D. L.; Xu, X. W.; Xu, Y.; Yanez, J. P.; Yodh, G.; Yoshida, S.; Yuan, T.; Zoll, M.; IceCube Collaboration; Aab, A.; Abreu, P.; Aglietta, M.; Albuquerque, I. F. M.; Albury, J. M.; Allekotte, I.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Anastasi, G. A.; Anchordoqui, L.; Andrada, B.; Andringa, S.; Aramo, C.; Arsene, N.; Asorey, H.; Assis, P.; Avila, G.; Badescu, A. M.; Balaceanu, A.; Barbato, F.; Barreira Luz, R. J.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; Berat, C.; Bertaina, M. E.; Bertou, X.; Biermann, P. L.; Biteau, J.; Blaess, S. G.; Blanco, A.; Blazek, J.; Bleve, C.; Boháčová, M.; Bonifazi, C.; Borodai, N.; Botti, A. M.; Brack, J.; Brancus, I.; Bretz, T.; Bridgeman, A.; Briechle, F. L.; Buchholz, P.; Bueno, A.; Buitink, S.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, L.; Cancio, A.; Canfora, F.; Caruso, R.; Castellina, A.; Catalani, F.; Cataldi, G.; Cazon, L.; Chavez, A. G.; Chinellato, J. A.; Chudoba, J.; Clay, R. W.; Cobos Cerutti, A. C.; Colalillo, R.; Coleman, A.; Collica, L.; Coluccia, M. R.; Conceição, R.; Consolati, G.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Cronin, J.; D’Amico, S.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; Day, J. A.; de Almeida, R. M.; de Jong, S. J.; De Mauro, G.; de Mello Neto, J. R. T.; De Mitri, I.; de Oliveira, J.; de Souza, V.; Debatin, J.; Deligny, O.; Díaz Castro, M. L.; Diogo, F.; Dobrigkeit, C.; D’Olivo, J. C.; Dorosti, Q.; dos Anjos, R. C.; Dova, M. T.; Dundovic, A.; Ebr, J.; Engel, R.; Erdmann, M.; Erfani, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Falcke, H.; Farmer, J.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Feldbusch, F.; Fenu, F.; Fick, B.; Figueira, J. M.; Filipčič, A.; Freire, M. M.; Fujii, T.; Fuster, A.; Gaïor, R.; García, B.; Gaté, F.; Gemmeke, H.; Gherghel-Lascu, A.; Ghia, P. L.; Giaccari, U.; Giammarchi, M.; Giller, M.; Głas, D.; Glaser, C.; Golup, G.; Gómez Berisso, M.; Gómez Vitale, P. F.; González, N.; Gorgi, A.; Gottowik, M.; Grillo, A. F.; Grubb, T. D.; Guarino, F.; Guedes, G. P.; Halliday, R.; Hampel, M. R.; Hansen, P.; Harari, D.; Harrison, T. A.; Harvey, V. M.; Haungs, A.; Hebbeker, T.; Heck, D.; Heimann, P.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huege, T.; Hulsman, J.; Insolia, A.; Isar, P. G.; Jandt, I.; Johnsen, J. A.; Josebachuili, M.; Jurysek, J.; Kääpä, A.; Kampert, K. H.; Keilhauer, B.; Kemmerich, N.; Kemp, J.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Krause, R.; Krohm, N.; Kuempel, D.; Kukec Mezek, G.; Kunka, N.; Kuotb Awad, A.; Lago, B. L.; LaHurd, D.; Lang, R. G.; Lauscher, M.; Legumina, R.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; Lo Presti, D.; Lopes, L.; López, R.; López Casado, A.; Lorek, R.; Luce, Q.; Lucero, A.; Malacari, M.; Mallamaci, M.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Mariş, I. C.; Marsella, G.; Martello, D.; Martinez, H.; Martínez Bravo, O.; Masías Meza, J. J.; Mathes, H. J.; Mathys, S.; Matthews, J.; Matthiae, G.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melo, D.; Menshikov, A.; Merenda, K.-D.; Michal, S.; Micheletti, M. I.; Middendorf, L.; Miramonti, L.; Mitrica, B.; Mockler, D.; Mollerach, S.; Montanet, F.; Morello, C.; Morlino, G.; Mostafá, M.; Müller, A. L.; Müller, G.; Muller, M. A.; Müller, S.; Mussa, R.; Naranjo, I.; Nellen, L.; Nguyen, P. H.; Niculescu-Oglinzanu, M.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Novotny, V.; Nožka, L.; Núñez, L. A.; Oikonomou, F.; Olinto, A.; Palatka, M.; Pallotta, J.; Papenbreer, P.; Parente, G.; Parra, A.; Paul, T.; Pech, M.; Pedreira, F.; Pȩkala, J.; Pelayo, R.; Peña-Rodriguez, J.; Pereira, L. A. S.; Perlin, M.; Perrone, L.; Peters, C.; Petrera, S.; Phuntsok, J.; Pierog, T.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Poh, J.; Porowski, C.; Prado, R. R.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Ramos-Pollan, R.; Rautenberg, J.; Ravignani, D.; Ridky, J.; Riehn, F.; Risse, M.; Ristori, P.; Rizi, V.; Rodrigues de Carvalho, W.; Rodriguez Fernandez, G.; Rodriguez Rojo, J.; Roncoroni, M. J.; Roth, M.; Roulet, E.; Rovero, A. C.; Ruehl, P.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Saleh, A.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santos, E. 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V.; Aufmuth, P.; Aulbert, C.; AultONeal, K.; Austin, C.; Avila-Alvarez, A.; Babak, S.; Bacon, P.; Bader, M. K. M.; Bae, S.; Baker, P. T.; Baldaccini, F.; Ballardin, G.; Ballmer, S. W.; Banagiri, S.; Barayoga, J. C.; Barclay, S. E.; Barish, B. C.; Barker, D.; Barkett, K.; Barone, F.; Barr, B.; Barsotti, L.; Barsuglia, M.; Barta, D.; Bartlett, J.; Bartos, I.; Bassiri, R.; Basti, A.; Batch, J. C.; Bawaj, M.; Bayley, J. C.; Bazzan, M.; Bécsy, B.; Beer, C.; Bejger, M.; Belahcene, I.; Bell, A. S.; Berger, B. K.; Bergmann, G.; Bero, J. J.; Berry, C. P. L.; Bersanetti, D.; Bertolini, A.; Betzwieser, J.; Bhagwat, S.; Bhandare, R.; Bilenko, I. A.; Billingsley, G.; Billman, C. R.; Birch, J.; Birney, R.; Birnholtz, O.; Biscans, S.; Biscoveanu, S.; Bisht, A.; Bitossi, M.; Biwer, C.; Bizouard, M. A.; Blackburn, J. K.; Blackman, J.; Blair, C. D.; Blair, D. G.; Blair, R. M.; Bloemen, S.; Bock, O.; Bode, N.; Boer, M.; Bogaert, G.; Bohe, A.; Bondu, F.; Bonilla, E.; Bonnand, R.; Boom, B. A.; Bork, R.; Boschi, V.; Bose, S.; Bossie, K.; Bouffanais, Y.; Bozzi, A.; Bradaschia, C.; Brady, P. R.; Branchesi, M.; Brau, J. E.; Briant, T.; Brillet, A.; Brinkmann, M.; Brisson, V.; Brockill, P.; Broida, J. E.; Brooks, A. F.; Brown, D. A.; Brown, D. D.; Brunett, S.; Buchanan, C. C.; Buikema, A.; Bulik, T.; Bulten, H. J.; Buonanno, A.; Buskulic, D.; Buy, C.; Byer, R. L.; Cabero, M.; Cadonati, L.; Cagnoli, G.; Cahillane, C.; Calderón Bustillo, J.; Callister, T. A.; Calloni, E.; Camp, J. B.; Canepa, M.; Canizares, P.; Cannon, K. C.; Cao, H.; Cao, J.; Capano, C. D.; Capocasa, E.; Carbognani, F.; Caride, S.; Carney, M. F.; Casanueva Diaz, J.; Casentini, C.; Caudill, S.; Cavaglià, M.; Cavalier, F.; Cavalieri, R.; Cella, G.; Cepeda, C. B.; Cerdá-Durán, P.; Cerretani, G.; Cesarini, E.; Chamberlin, S. J.; Chan, M.; Chao, S.; Charlton, P.; Chase, E.; Chassande-Mottin, E.; Chatterjee, D.; Cheeseboro, B. D.; Chen, H. Y.; Chen, X.; Chen, Y.; Cheng, H.-P.; Chia, H.; Chincarini, A.; Chiummo, A.; Chmiel, T.; Cho, H. S.; Cho, M.; Chow, J. H.; Christensen, N.; Chu, Q.; Chua, A. J. K.; Chua, S.; Chung, A. K. W.; Chung, S.; Ciani, G.; Ciolfi, R.; Cirelli, C. E.; Cirone, A.; Clara, F.; Clark, J. A.; Clearwater, P.; Cleva, F.; Cocchieri, C.; Coccia, E.; Cohadon, P.-F.; Cohen, D.; Colla, A.; Collette, C. G.; Cominsky, L. R.; Constancio, M., Jr.; Conti, L.; Cooper, S. J.; Corban, P.; Corbitt, T. R.; Cordero-Carrión, I.; Corley, K. R.; Cornish, N.; Corsi, A.; Cortese, S.; Costa, C. A.; Coughlin, M. W.; Coughlin, S. B.; Coulon, J.-P.; Countryman, S. T.; Couvares, P.; Covas, P. B.; Cowan, E. E.; Coward, D. M.; Cowart, M. J.; Coyne, D. C.; Coyne, R.; Creighton, J. D. E.; Creighton, T. D.; Cripe, J.; Crowder, S. G.; Cullen, T. J.; Cumming, A.; Cunningham, L.; Cuoco, E.; Dal Canton, T.; Dálya, G.; Danilishin, S. L.; D’Antonio, S.; Danzmann, K.; Dasgupta, A.; Da Silva Costa, C. F.; Dattilo, V.; Dave, I.; Davier, M.; Davis, D.; Daw, E. J.; Day, B.; De, S.; DeBra, D.; Degallaix, J.; De Laurentis, M.; Deléglise, S.; Del Pozzo, W.; Demos, N.; Denker, T.; Dent, T.; De Pietri, R.; Dergachev, V.; De Rosa, R.; DeRosa, R. T.; De Rossi, C.; DeSalvo, R.; de Varona, O.; Devenson, J.; Dhurandhar, S.; Díaz, M. C.; Di Fiore, L.; Di Giovanni, M.; Di Girolamo, T.; Di Lieto, A.; Di Pace, S.; Di Palma, I.; Di Renzo, F.; Doctor, Z.; Dolique, V.; Donovan, F.; Dooley, K. L.; Doravari, S.; Dorrington, I.; Douglas, R.; Dovale Álvarez, M.; Downes, T. P.; Drago, M.; Dreissigacker, C.; Driggers, J. C.; Du, Z.; Ducrot, M.; Dupej, P.; Dwyer, S. E.; Edo, T. B.; Edwards, M. C.; Effler, A.; Eggenstein, H.-B.; Ehrens, P.; Eichholz, J.; Eikenberry, S. S.; Eisenstein, R. A.; Essick, R. C.; Estevez, D.; Etienne, Z. B.; Etzel, T.; Evans, M.; Evans, T. M.; Factourovich, M.; Fafone, V.; Fair, H.; Fairhurst, S.; Fan, X.; Farinon, S.; Farr, B.; Farr, W. M.; Fauchon-Jones, E. J.; Favata, M.; Fays, M.; Fee, C.; Fehrmann, H.; Feicht, J.; Fejer, M. M.; Fernandez-Galiana, A.; Ferrante, I.; Ferreira, E. C.; Ferrini, F.; Fidecaro, F.; Finstad, D.; Fiori, I.; Fiorucci, D.; Fishbach, M.; Fisher, R. P.; Fitz-Axen, M.; Flaminio, R.; Fletcher, M.; Fong, H.; Font, J. A.; Forsyth, P. W. F.; Forsyth, S. S.; Fournier, J.-D.; Frasca, S.; Frasconi, F.; Frei, Z.; Freise, A.; Frey, R.; Frey, V.; Fries, E. M.; Fritschel, P.; Frolov, V. V.; Fulda, P.; Fyffe, M.; Gabbard, H.; Gadre, B. U.; Gaebel, S. M.; Gair, J. R.; Gammaitoni, L.; Ganija, M. R.; Gaonkar, S. G.; Garcia-Quiros, C.; Garufi, F.; Gateley, B.; Gaudio, S.; Gaur, G.; Gayathri, V.; Gehrels, N.; Gemme, G.; Genin, E.; Gennai, A.; George, D.; George, J.; Gergely, L.; Germain, V.; Ghonge, S.; Ghosh, Abhirup; Ghosh, Archisman; Ghosh, S.; Giaime, J. A.; Giardina, K. D.; Giazotto, A.; Gill, K.; Glover, L.; Goetz, E.; Goetz, R.; Gomes, S.; Goncharov, B.; González, G.; Gonzalez Castro, J. M.; Gopakumar, A.; Gorodetsky, M. L.; Gossan, S. E.; Gosselin, M.; Gouaty, R.; Grado, A.; Graef, C.; Granata, M.; Grant, A.; Gras, S.; Gray, C.; Greco, G.; Green, A. C.; Gretarsson, E. M.; Groot, P.; Grote, H.; Grunewald, S.; Gruning, P.; Guidi, G. M.; Guo, X.; Gupta, A.; Gupta, M. K.; Gushwa, K. E.; Gustafson, E. K.; Gustafson, R.; Halim, O.; Hall, B. R.; Hall, E. D.; Hamilton, E. Z.; Hammond, G.; Haney, M.; Hanke, M. M.; Hanks, J.; Hanna, C.; Hannam, M. D.; Hannuksela, O. A.; Hanson, J.; Hardwick, T.; Harms, J.; Harry, G. M.; Harry, I. W.; Hart, M. J.; Haster, C.-J.; Haughian, K.; Healy, J.; Heidmann, A.; Heintze, M. C.; Heitmann, H.; Hello, P.; Hemming, G.; Hendry, M.; Heng, I. S.; Hennig, J.; Heptonstall, A. W.; Heurs, M.; Hild, S.; Hinderer, T.; Hoak, D.; Hofman, D.; Holt, K.; Holz, D. E.; Hopkins, P.; Horst, C.; Hough, J.; Houston, E. A.; Howell, E. J.; Hreibi, A.; Hu, Y. M.; Huerta, E. A.; Huet, D.; Hughey, B.; Husa, S.; Huttner, S. H.; Huynh-Dinh, T.; Indik, N.; Inta, R.; Intini, G.; Isa, H. N.; Isac, J.-M.; Isi, M.; Iyer, B. R.; Izumi, K.; Jacqmin, T.; Jani, K.; Jaranowski, P.; Jawahar, S.; Jiménez-Forteza, F.; Johnson, W. W.; Jones, D. I.; Jones, R.; Jonker, R. J. G.; Ju, L.; Junker, J.; Kalaghatgi, C. V.; Kalogera, V.; Kamai, B.; Kandhasamy, S.; Kang, G.; Kanner, J. B.; Kapadia, S. J.; Karki, S.; Karvinen, K. S.; Kasprzack, M.; Katolik, M.; Katsavounidis, E.; Katzman, W.; Kaufer, S.; Kawabe, K.; Kéfélian, F.; Keitel, D.; Kemball, A. J.; Kennedy, R.; Kent, C.; Key, J. S.; Khalili, F. Y.; Khan, I.; Khan, S.; Khan, Z.; Khazanov, E. A.; Kijbunchoo, N.; Kim, Chunglee; Kim, J. C.; Kim, K.; Kim, W.; Kim, W. S.; Kim, Y.-M.; Kimbrell, S. J.; King, E. J.; King, P. J.; Kinley-Hanlon, M.; Kirchhoff, R.; Kissel, J. S.; Kleybolte, L.; Klimenko, S.; Knowles, T. D.; Koch, P.; Koehlenbeck, S. M.; Koley, S.; Kondrashov, V.; Kontos, A.; Korobko, M.; Korth, W. Z.; Kowalska, I.; Kozak, D. B.; Krämer, C.; Kringel, V.; Krishnan, B.; Królak, A.; Kuehn, G.; Kumar, P.; Kumar, R.; Kumar, S.; Kuo, L.; Kutynia, A.; Kwang, S.; Lackey, B. D.; Lai, K. H.; Landry, M.; Lang, R. N.; Lange, J.; Lantz, B.; Lanza, R. K.; Lartaux-Vollard, A.; Lasky, P. D.; Laxen, M.; Lazzarini, A.; Lazzaro, C.; Leaci, P.; Leavey, S.; Lee, C. H.; Lee, H. K.; Lee, H. M.; Lee, H. W.; Lee, K.; Lehmann, J.; Lenon, A.; Leonardi, M.; Leroy, N.; Letendre, N.; Levin, Y.; Li, T. G. F.; Linker, S. D.; Littenberg, T. B.; Liu, J.; Lo, R. K. L.; Lockerbie, N. A.; London, L. T.; Lord, J. E.; Lorenzini, M.; Loriette, V.; Lormand, M.; Losurdo, G.; Lough, J. D.; Lousto, C. O.; Lovelace, G.; Lück, H.; Lumaca, D.; Lundgren, A. P.; Lynch, R.; Ma, Y.; Macas, R.; Macfoy, S.; Machenschalk, B.; MacInnis, M.; Macleod, D. M.; Magaña Hernandez, I.; Magaña-Sandoval, F.; Magaña Zertuche, L.; Magee, R. M.; Majorana, E.; Maksimovic, I.; Man, N.; Mandic, V.; Mangano, V.; Mansell, G. L.; Manske, M.; Mantovani, M.; Marchesoni, F.; Marion, F.; Márka, S.; Márka, Z.; Markakis, C.; Markosyan, A. S.; Markowitz, A.; Maros, E.; Marquina, A.; Martelli, F.; Martellini, L.; Martin, I. W.; Martin, R. M.; Martynov, D. V.; Mason, K.; Massera, E.; Masserot, A.; Massinger, T. J.; Masso-Reid, M.; Mastrogiovanni, S.; Matas, A.; Matichard, F.; Matone, L.; Mavalvala, N.; Mazumder, N.; McCarthy, R.; McClelland, D. E.; McCormick, S.; McCuller, L.; McGuire, S. C.; McIntyre, G.; McIver, J.; McManus, D. J.; McNeill, L.; McRae, T.; McWilliams, S. T.; Meacher, D.; Meadors, G. D.; Mehmet, M.; Meidam, J.; Mejuto-Villa, E.; Melatos, A.; Mendell, G.; Mercer, R. A.; Merilh, E. L.; Merzougui, M.; Meshkov, S.; Messenger, C.; Messick, C.; Metzdorff, R.; Meyers, P. M.; Miao, H.; Michel, C.; Middleton, H.; Mikhailov, E. E.; Milano, L.; Miller, A. L.; Miller, B. B.; Miller, J.; Millhouse, M.; Milovich-Goff, M. C.; Minazzoli, O.; Minenkov, Y.; Ming, J.; Mishra, C.; Mitra, S.; Mitrofanov, V. P.; Mitselmakher, G.; Mittleman, R.; Moffa, D.; Moggi, A.; Mogushi, K.; Mohan, M.; Mohapatra, S. R. P.; Montani, M.; Moore, C. J.; Moraru, D.; Moreno, G.; Morriss, S. R.; Mours, B.; Mow-Lowry, C. M.; Mueller, G.; Muir, A. W.; Mukherjee, Arunava; Mukherjee, D.; Mukherjee, S.; Mukund, N.; Mullavey, A.; Munch, J.; Muñiz, E. A.; Muratore, M.; Murray, P. G.; Napier, K.; Nardecchia, I.; Naticchioni, L.; Nayak, R. K.; Neilson, J.; Nelemans, G.; Nelson, T. J. N.; Nery, M.; Neunzert, A.; Nevin, L.; Newport, J. M.; Newton, G.; Ng, K. K. Y.; Nguyen, T. T.; Nichols, D.; Nielsen, A. B.; Nissanke, S.; Nitz, A.; Noack, A.; Nocera, F.; Nolting, D.; North, C.; Nuttall, L. K.; Oberling, J.; O’Dea, G. D.; Ogin, G. H.; Oh, J. J.; Oh, S. H.; Ohme, F.; Okada, M. A.; Oliver, M.; Oppermann, P.; Oram, Richard J.; O’Reilly, B.; Ormiston, R.; Ortega, L. F.; O’Shaughnessy, R.; Ossokine, S.; Ottaway, D. J.; Overmier, H.; Owen, B. J.; Pace, A. E.; Page, J.; Page, M. A.; Pai, A.; Pai, S. A.; Palamos, J. R.; Palashov, O.; Palomba, C.; Pal-Singh, A.; Pan, Howard; Pan, Huang-Wei; Pang, B.; Pang, P. T. H.; Pankow, C.; Pannarale, F.; Pant, B. C.; Paoletti, F.; Paoli, A.; Papa, M. A.; Parida, A.; Parker, W.; Pascucci, D.; Pasqualetti, A.; Passaquieti, R.; Passuello, D.; Patil, M.; Patricelli, B.; Pearlstone, B. L.; Pedraza, M.; Pedurand, R.; Pekowsky, L.; Pele, A.; Penn, S.; Perez, C. J.; Perreca, A.; Perri, L. M.; Pfeiffer, H. P.; Phelps, M.; Piccinni, O. J.; Pichot, M.; Piergiovanni, F.; Pierro, V.; Pillant, G.; Pinard, L.; Pinto, I. M.; Pirello, M.; Pitkin, M.; Poe, M.; Poggiani, R.; Popolizio, P.; Porter, E. K.; Post, A.; Powell, J.; Prasad, J.; Pratt, J. W. W.; Pratten, G.; Predoi, V.; Prestegard, T.; Prijatelj, M.; Principe, M.; Privitera, S.; Prodi, G. A.; Prokhorov, L. G.; Puncken, O.; Punturo, M.; Puppo, P.; Pürrer, M.; Qi, H.; Quetschke, V.; Quintero, E. A.; Quitzow-James, R.; Raab, F. J.; Rabeling, D. S.; Radkins, H.; Raffai, P.; Raja, S.; Rajan, C.; Rajbhandari, B.; Rakhmanov, M.; Ramirez, K. E.; Ramos-Buades, A.; Rapagnani, P.; Raymond, V.; Razzano, M.; Read, J.; Regimbau, T.; Rei, L.; Reid, S.; Reitze, D. H.; Ren, W.; Reyes, S. D.; Ricci, F.; Ricker, P. M.; Rieger, S.; Riles, K.; Rizzo, M.; Robertson, N. A.; Robie, R.; Robinet, F.; Rocchi, A.; Rolland, L.; Rollins, J. G.; Roma, V. J.; Romano, R.; Romel, C. L.; Romie, J. H.; Rosińska, D.; Ross, M. P.; Rowan, S.; Rüdiger, A.; Ruggi, P.; Rutins, G.; Ryan, K.; Sachdev, S.; Sadecki, T.; Sadeghian, L.; Sakellariadou, M.; Salconi, L.; Saleem, M.; Salemi, F.; Samajdar, A.; Sammut, L.; Sampson, L. M.; Sanchez, E. J.; Sanchez, L. E.; Sanchis-Gual, N.; Sandberg, V.; Sanders, J. R.; Sassolas, B.; Saulson, P. R.; Sauter, O.; Savage, R. L.; Sawadsky, A.; Schale, P.; Scheel, M.; Scheuer, J.; Schmidt, J.; Schmidt, P.; Schnabel, R.; Schofield, R. M. S.; Schönbeck, A.; Schreiber, E.; Schuette, D.; Schulte, B. W.; Schutz, B. F.; Schwalbe, S. G.; Scott, J.; Scott, S. M.; Seidel, E.; Sellers, D.; Sengupta, A. S.; Sentenac, D.; Sequino, V.; Sergeev, A.; Shaddock, D. A.; Shaffer, T. J.; Shah, A. A.; Shahriar, M. S.; Shaner, M. B.; Shao, L.; Shapiro, B.; Shawhan, P.; Sheperd, A.; Shoemaker, D. H.; Shoemaker, D. M.; Siellez, K.; Siemens, X.; Sieniawska, M.; Sigg, D.; Silva, A. D.; Singer, L. P.; Singh, A.; Singhal, A.; Sintes, A. M.; Slagmolen, B. J. J.; Smith, B.; Smith, J. R.; Smith, R. J. E.; Somala, S.; Son, E. J.; Sonnenberg, J. A.; Sorazu, B.; Sorrentino, F.; Souradeep, T.; Spencer, A. P.; Srivastava, A. K.; Staats, K.; Staley, A.; Steinke, M.; Steinlechner, J.; Steinlechner, S.; Steinmeyer, D.; Stevenson, S. P.; Stone, R.; Stops, D. J.; Strain, K. A.; Stratta, G.; Strigin, S. E.; Strunk, A.; Sturani, R.; Stuver, A. L.; Summerscales, T. Z.; Sun, L.; Sunil, S.; Suresh, J.; Sutton, P. J.; Swinkels, B. L.; Szczepańczyk, M. J.; Tacca, M.; Tait, S. C.; Talbot, C.; Talukder, D.; Tanner, D. B.; Tápai, M.; Taracchini, A.; Tasson, J. D.; Taylor, J. A.; Taylor, R.; Tewari, S. V.; Theeg, T.; Thies, F.; Thomas, E. G.; Thomas, M.; Thomas, P.; Thorne, K. A.; Thrane, E.; Tiwari, S.; Tiwari, V.; Tokmakov, K. V.; Toland, K.; Tonelli, M.; Tornasi, Z.; Torres-Forné, A.; Torrie, C. I.; Töyrä, D.; Travasso, F.; Traylor, G.; Trinastic, J.; Tringali, M. C.; Trozzo, L.; Tsang, K. W.; Tse, M.; Tso, R.; Tsukada, L.; Tsuna, D.; Tuyenbayev, D.; Ueno, K.; Ugolini, D.; Unnikrishnan, C. S.; Urban, A. L.; Usman, S. A.; Vahlbruch, H.; Vajente, G.; Valdes, G.; van Bakel, N.; van Beuzekom, M.; van den Brand, J. F. J.; Van Den Broeck, C.; Vander-Hyde, D. C.; van der Schaaf, L.; van Heijningen, J. V.; van Veggel, A. A.; Vardaro, M.; Varma, V.; Vass, S.; Vasúth, M.; Vecchio, A.; Vedovato, G.; Veitch, J.; Veitch, P. J.; Venkateswara, K.; Venugopalan, G.; Verkindt, D.; Vetrano, F.; Viceré, A.; Viets, A. D.; Vinciguerra, S.; Vine, D. J.; Vinet, J.-Y.; Vitale, S.; Vo, T.; Vocca, H.; Vorvick, C.; Vyatchanin, S. P.; Wade, A. R.; Wade, L. E.; Wade, M.; Walet, R.; Walker, M.; Wallace, L.; Walsh, S.; Wang, G.; Wang, H.; Wang, J. Z.; Wang, W. H.; Wang, Y. F.; Ward, R. L.; Warner, J.; Was, M.; Watchi, J.; Weaver, B.; Wei, L.-W.; Weinert, M.; Weinstein, A. J.; Weiss, R.; Wen, L.; Wessel, E. K.; Weßels, P.; Westerweck, J.; Westphal, T.; Wette, K.; Whelan, J. T.; Whiting, B. F.; Whittle, C.; Wilken, D.; Williams, D.; Williams, R. D.; Williamson, A. R.; Willis, J. L.; Willke, B.; Wimmer, M. H.; Winkler, W.; Wipf, C. C.; Wittel, H.; Woan, G.; Woehler, J.; Wofford, J.; Wong, K. W. K.; Worden, J.; Wright, J. L.; Wu, D. S.; Wysocki, D. M.; Xiao, S.; Yamamoto, H.; Yancey, C. C.; Yang, L.; Yap, M. J.; Yazback, M.; Yu, Hang; Yu, Haocun; Yvert, M.; Zadrożny, A.; Zanolin, M.; Zelenova, T.; Zendri, J.-P.; Zevin, M.; Zhang, L.; Zhang, M.; Zhang, T.; Zhang, Y.-H.; Zhao, C.; Zhou, M.; Zhou, Z.; Zhu, S. J.; Zhu, X. J.; Zucker, M. E.; Zweizig, J.; LIGO Scientific Collaboration; Virgo Collaboration

2017-12-01

The Advanced LIGO and Advanced Virgo observatories recently discovered gravitational waves from a binary neutron star inspiral. A short gamma-ray burst (GRB) that followed the merger of this binary was also recorded by the Fermi Gamma-ray Burst Monitor (Fermi-GBM), and the Anti-Coincidence Shield for the Spectrometer for the International Gamma-Ray Astrophysics Laboratory (INTEGRAL), indicating particle acceleration by the source. The precise location of the event was determined by optical detections of emission following the merger. We searched for high-energy neutrinos from the merger in the GeV–EeV energy range using the ANTARES, IceCube, and Pierre Auger Observatories. No neutrinos directionally coincident with the source were detected within ±500 s around the merger time. Additionally, no MeV neutrino burst signal was detected coincident with the merger. We further carried out an extended search in the direction of the source for high-energy neutrinos within the 14 day period following the merger, but found no evidence of emission. We used these results to probe dissipation mechanisms in relativistic outflows driven by the binary neutron star merger. The non-detection is consistent with model predictions of short GRBs observed at a large off-axis angle.

Binary versus non-binary information in real time series: empirical results and maximum-entropy matrix models

NASA Astrophysics Data System (ADS)

Almog, Assaf; Garlaschelli, Diego

2014-09-01

The dynamics of complex systems, from financial markets to the brain, can be monitored in terms of multiple time series of activity of the constituent units, such as stocks or neurons, respectively. While the main focus of time series analysis is on the magnitude of temporal increments, a significant piece of information is encoded into the binary projection (i.e. the sign) of such increments. In this paper we provide further evidence of this by showing strong nonlinear relations between binary and non-binary properties of financial time series. These relations are a novel quantification of the fact that extreme price increments occur more often when most stocks move in the same direction. We then introduce an information-theoretic approach to the analysis of the binary signature of single and multiple time series. Through the definition of maximum-entropy ensembles of binary matrices and their mapping to spin models in statistical physics, we quantify the information encoded into the simplest binary properties of real time series and identify the most informative property given a set of measurements. Our formalism is able to accurately replicate, and mathematically characterize, the observed binary/non-binary relations. We also obtain a phase diagram allowing us to identify, based only on the instantaneous aggregate return of a set of multiple time series, a regime where the so-called ‘market mode’ has an optimal interpretation in terms of collective (endogenous) effects, a regime where it is parsimoniously explained by pure noise, and a regime where it can be regarded as a combination of endogenous and exogenous factors. Our approach allows us to connect spin models, simple stochastic processes, and ensembles of time series inferred from partial information.

The Eclipsing Binary On-Line Atlas (EBOLA)

NASA Astrophysics Data System (ADS)

Bradstreet, D. H.; Steelman, D. P.; Sanders, S. J.; Hargis, J. R.

2004-05-01

In conjunction with the upcoming release of \\it Binary Maker 3.0, an extensive on-line database of eclipsing binaries is being made available. The purposes of the atlas are: \\begin {enumerate} Allow quick and easy access to information on published eclipsing binaries. Amass a consistent database of light and radial velocity curve solutions to aid in solving new systems. Provide invaluable querying capabilities on all of the parameters of the systems so that informative research can be quickly accomplished on a multitude of published results. Aid observers in establishing new observing programs based upon stars needing new light and/or radial velocity curves. Encourage workers to submit their published results so that others may have easy access to their work. Provide a vast but easily accessible storehouse of information on eclipsing binaries to accelerate the process of understanding analysis techniques and current work in the field. \\end {enumerate} The database will eventually consist of all published eclipsing binaries with light curve solutions. The following information and data will be supplied whenever available for each binary: original light curves in all bandpasses, original radial velocity observations, light curve parameters, RA and Dec, V-magnitudes, spectral types, color indices, periods, binary type, 3D representation of the system near quadrature, plots of the original light curves and synthetic models, plots of the radial velocity observations with theoretical models, and \\it Binary Maker 3.0 data files (parameter, light curve, radial velocity). The pertinent references for each star are also given with hyperlinks directly to the papers via the NASA Abstract website for downloading, if available. In addition the Atlas has extensive searching options so that workers can specifically search for binaries with specific characteristics. The website has more than 150 systems already uploaded. The URL for the site is http://ebola.eastern.edu/.

Performance Analysis of New Binary User Codes for DS-CDMA Communication

NASA Astrophysics Data System (ADS)

Usha, Kamle; Jaya Sankar, Kottareddygari

2016-03-01

This paper analyzes new binary spreading codes through correlation properties and also presents their performance over additive white Gaussian noise (AWGN) channel. The proposed codes are constructed using gray and inverse gray codes. In this paper, a n-bit gray code appended by its n-bit inverse gray code to construct the 2n-length binary user codes are discussed. Like Walsh codes, these binary user codes are available in sizes of power of two and additionally code sets of length 6 and their even multiples are also available. The simple construction technique and generation of code sets of different sizes are the salient features of the proposed codes. Walsh codes and gold codes are considered for comparison in this paper as these are popularly used for synchronous and asynchronous multi user communications respectively. In the current work the auto and cross correlation properties of the proposed codes are compared with those of Walsh codes and gold codes. Performance of the proposed binary user codes for both synchronous and asynchronous direct sequence CDMA communication over AWGN channel is also discussed in this paper. The proposed binary user codes are found to be suitable for both synchronous and asynchronous DS-CDMA communication.

Formation of the Wide Asynchronous Binary Asteroid Population

NASA Astrophysics Data System (ADS)

Jacobson, Seth A.; Scheeres, Daniel J.; McMahon, Jay

2014-01-01

We propose and analyze a new mechanism for the formation of the wide asynchronous binary population. These binary asteroids have wide semimajor axes relative to most near-Earth and main belt asteroid systems. Confirmed members have rapidly rotating primaries and satellites that are not tidally locked. Previously suggested formation mechanisms from impact ejecta, from planetary flybys, and directly from rotational fission events cannot satisfy all of the observations. The newly hypothesized mechanism works as follows: (1) these systems are formed from rotational fission, (2) their satellites are tidally locked, (3) their orbits are expanded by the binary Yarkovsky-O'Keefe-Radzievskii-Paddack (BYORP) effect, (4) their satellites desynchronize as a result of the adiabatic invariance between the libration of the secondary and the mutual orbit, and (5) the secondary avoids resynchronization because of the YORP effect. This seemingly complex chain of events is a natural pathway for binaries with satellites that have particular shapes, which define the BYORP effect torque that acts on the system. After detailing the theory, we analyze each of the wide asynchronous binary members and candidates to assess their most likely formation mechanism. Finally, we suggest possible future observations to check and constrain our hypothesis.

Forming the wide asynchronous binary asteroid population

NASA Astrophysics Data System (ADS)

Jacobson, S.; Scheeres, D.; McMahon, J.

2014-07-01

We propose and analyze a new mechanism for the formation of the wide asynchronous binary population. These binary asteroids have wide semi-major axes relative to most near-Earth-asteroid and main-belt-asteroid systems as shown in the attached table. Confirmed members have rapidly rotating primaries and satellites that are not tidally locked. Previously suggested formation mechanisms from impact ejecta, from planetary flybys, and directly from rotational-fission events cannot satisfy all of the observations. The newly hypothesized mechanism works as follows: (1) these systems are formed from rotational fission, (2) their satellites are tidally locked, (3) their orbits are expanded by the binary Yarkovsky-O'Keefe-Radzievskii-Paddack (BYORP) effect, (4) their satellites desynchronize as a result of the adiabatic invariance between the libration of the secondary and the mutual orbit, and (5) the secondary avoids resynchronization because of the YORP effect. This seemingly complex chain of events is a natural pathway for binaries with satellites that have particular shapes, which define the BYORP effect torque that acts on the system. After detailing the theory, we analyze each of the wide-asynchronous-binary members and candidates to assess their most likely formation mechanism. Finally, we suggest possible future observations to check and constrain our hypothesis.

Parameter Estimation for Compact Binaries with Ground-Based Gravitational-Wave Observations Using the LALInference

NASA Technical Reports Server (NTRS)

Veitch, J.; Raymond, V.; Farr, B.; Farr, W.; Graff, P.; Vitale, S.; Aylott, B.; Blackburn, K.; Christensen, N.; Coughlin, M.

2015-01-01

The Advanced LIGO and Advanced Virgo gravitational wave (GW) detectors will begin operation in the coming years, with compact binary coalescence events a likely source for the first detections. The gravitational waveforms emitted directly encode information about the sources, including the masses and spins of the compact objects. Recovering the physical parameters of the sources from the GW observations is a key analysis task. This work describes the LALInference software library for Bayesian parameter estimation of compact binary signals, which builds on several previous methods to provide a well-tested toolkit which has already been used for several studies. We show that our implementation is able to correctly recover the parameters of compact binary signals from simulated data from the advanced GW detectors. We demonstrate this with a detailed comparison on three compact binary systems: a binary neutron star (BNS), a neutron star - black hole binary (NSBH) and a binary black hole (BBH), where we show a cross-comparison of results obtained using three independent sampling algorithms. These systems were analysed with non-spinning, aligned spin and generic spin configurations respectively, showing that consistent results can be obtained even with the full 15-dimensional parameter space of the generic spin configurations. We also demonstrate statistically that the Bayesian credible intervals we recover correspond to frequentist confidence intervals under correct prior assumptions by analysing a set of 100 signals drawn from the prior. We discuss the computational cost of these algorithms, and describe the general and problem-specific sampling techniques we have used to improve the efficiency of sampling the compact binary coalescence (CBC) parameter space.

CytometryML binary data standards

NASA Astrophysics Data System (ADS)

Leif, Robert C.

2005-03-01

CytometryML is a proposed new Analytical Cytology (Cytomics) data standard, which is based on a common set of XML schemas for encoding flow cytometry and digital microscopy text based data types (metadata). CytometryML schemas reference both DICOM (Digital Imaging and Communications in Medicine) codes and FCS keywords. Flow Cytometry Standard (FCS) list-mode has been mapped to the DICOM Waveform Information Object. The separation of the large binary data objects (list mode and image data) from the XML description of the metadata permits the metadata to be directly displayed, analyzed, and reported with standard commercial software packages; the direct use of XML languages; and direct interfacing with clinical information systems. The separation of the binary data into its own files simplifies parsing because all extraneous header data has been eliminated. The storage of images as two-dimensional arrays without any extraneous data, such as in the Adobe Photoshop RAW format, facilitates the development by scientists of their own analysis and visualization software. Adobe Photoshop provided the display infrastructure and the translation facility to interconvert between the image data from commercial formats and RAW format. Similarly, the storage and parsing of list mode binary data type with a group of parameters that are specified at compilation time is straight forward. However when the user is permitted at run-time to select a subset of the parameters and/or specify results of mathematical manipulations, the development of special software was required. The use of CytometryML will permit investigators to be able to create their own interoperable data analysis software and to employ commercially available software to disseminate their data.

A Novel Fabrication Method of Bi₂Te₃-Based Thermoelectric Modules by Indium Electroplating and Thermocompression Bonding.

PubMed

Yoon, Jongchan; Bae, Sung Hwa; Sohn, Ho-Sang; Son, Injoon; Kim, Kyung Tae; Ju, Young-Wan

2018-09-01

In this study, we devised a method to bond thermoelectric elements directly to copper electrodes by plating indium with a relatively low melting point. A coating of indium, ~30 μm in thickness, was fabricated by electroplating the surface of a Bi2Te3-based thermoelectric element with a nickel diffusion barrier layer. They were then subjected to direct thermocompression bonding at 453 K on a hotplate for 10 min at a pressure of 1.1 kPa. Scanning electron microscopy images confirmed that a uniform bond was formed at the copper electrode/thermoelectric element interface, and the melted/solidified indium layer was defect free. Thus, the proposed novel method of fabricating a thermoelectric module by electroplating indium on the surface of the thermoelectric element and directly bonding with the copper electrode can be used to obtain a uniformly bonded interface even at a relatively low temperature without the use of solder pastes.

Fabrication of Rare-earth Aluminate (ReAlO3) Glass and Crystalline phases by Aerodynamic Levitation (ADL)

NASA Astrophysics Data System (ADS)

Basavalingu, B.; Yoda, Shinichi; Kumar, M. S. Vijaya

2012-07-01

Containerless processing by levitation technique has been extensively used for material science and engineering because it suppresses inhomogeneous nucleation from the container wall and helps to produce stable, metastable and glass phases. The containerless levitation technique is widely explored for material processing because of its technological and scientific advantages. Recently, research on bulk glass and glass-ceramics have attracted the attention of material scientists as they are considered as low cost optical materials of the future. In the present study, the formation of bulk spherical glass and crystalline ReAlO _{3}(Re=La-Lu,Y) phases has been investigated due to their unique features in terms of the solidification process from an undercooled melt, glass structure and optical properties. An Aerodynamic levitation (ADL) was used to undercool the melt well below the melting temperature. Sintered bits of ReAlO _{3} sample with a diameter of ~2.5 mm and mass of ~20-25 mg was levitated by an ADL and completely melted by a CO _{2} laser and then the droplet was cooled by turning off the CO _{2} laser and solidified. The surface temperature and solidification process of the levitated droplet was monitored using pyrometer and high speed video camera, respectively. Among the rare earth aluminum perovskites Lanthanum, Neodymium and samarium aluminum perovskites solidified as glass and others YAlO _{3} and Europium to Lutetium aluminum perovskites solidified as crystalline phases. The scanning electron microscopy (SEM) images of cross-sectioned samples, TG/DTA, Transmittance and Refractive Index studies were performed for both glass and crystalline phases. The results of the above studies revealed the formation of glass and crystalline phases directly from the undercooled melt. The glass transition temperature (Tg) gradually increased with increasing ionic radius of the rare-earth elements. The NdAlO _{3} glass phase showed a high refractive index of ~1.89, suggesting that containerless levitation is an elegant technique for fabrication of new glass and crystalline ceramics from an undercooled melt.

Detection of free liquid in containers of solidified radioactive waste

DOEpatents

Greenhalgh, W.O.

Nondestructive detection of the presence of free liquid within a sealed enclosure containing solidified waste is accomplished by measuring the levels of waste at two diametrically opposite locations while slowly tilting the enclosure toward one of said locations. When the measured level remains constant at the other location, the measured level at said one location is noted and any measured difference of levels indicates the presence of liquid on the surface of the solifified waste. The absence of liquid in the enclosure is verified when the measured levels at both locations are equal.

Factors affecting fixation of heavy metals in solidified/stabilized matrix: a review.

PubMed

Malviya, Rachana; Chaudhary, Rubina

2010-07-01

In this paper, an effort has been made to understand the factors, which affect fixation of heavy metals in solidified/stabilized matrix. Various aspects related to the solidification/stabilization of different heavy metals (Ar, Ba, Cu, Cr, Pb, Zn, Hg) are reviewed. A comparative study of different binders for the fixation of each metal has also been carried out to suggest the most suitable binder, pretreatment required for the metal. Valence, speciation, pH and other factors are also considered while reviewing metal retention capacity of different matrix.

Geometrical characterization of perlite-metal syntactic foam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borovinšek, Matej, E-mail: matej.borovinsek@um.si

This paper introduces an improved method for the detailed geometrical characterization of perlite-metal syntactic foam. This novel metallic foam is created by infiltrating a packed bed of expanded perlite particles with liquid aluminium alloy. The geometry of the solidified metal is thus defined by the perlite particle shape, size and morphology. The method is based on a segmented micro-computed tomography data and allows for automated determination of the distributions of pore size, sphericity, orientation and location. The pore (i.e. particle) size distribution and pore orientation is determined by a multi-criteria k-nearest neighbour algorithm for pore identification. The results indicate amore » weak density gradient parallel to the casting direction and a slight preference of particle orientation perpendicular to the casting direction. - Highlights: •A new method for identification of pores in porous materials was developed. •It was applied on perlite-metal syntactic foam samples. •A porosity decrease in the axial direction of the samples was determined. •Pore shape analysis showed a high percentage of spherical pores. •Orientation analysis showed that more pores are oriented in the radial direction.« less

Texturing of high T(sub c) superconducting polycrystalline fibers/wires by laser-driven directional solidification in an thermal gradient

NASA Technical Reports Server (NTRS)

Varshney, Usha; Eichelberger, B. Davis, III

1995-01-01

This paper summarizes the technique of laser-driven directional solidification in a controlled thermal gradient of yttria stabilized zirconia core coated Y-Ba-Cu-O materials to produce textured high T(sub c) superconducting polycrystalline fibers/wires with improved critical current densities in the extended range of magnetic fields at temperatures greater than 77 K. The approach involves laser heating to minimize phase segregation by heating very rapidly through the two-phase incongruent melt region to the single phase melt region and directionally solidifying in a controlled thermal gradient to achieve highly textured grains in the fiber axis direction. The technique offers a higher grain growth rate and a lower thermal budget compared with a conventional thermal gradient and is amenable as a continuous process for improving the J(sub c) of high T(sub c) superconducting polycrystalline fibers/wires. The technique has the advantage of suppressing weak-link behavior by orientation of crystals, formation of dense structures with enhanced connectivity, formation of fewer and cleaner grain boundaries, and minimization of phase segregation in the incongruent melt region.

Parameter estimation method that directly compares gravitational wave observations to numerical relativity

NASA Astrophysics Data System (ADS)

Lange, J.; O'Shaughnessy, R.; Boyle, M.; Calderón Bustillo, J.; Campanelli, M.; Chu, T.; Clark, J. A.; Demos, N.; Fong, H.; Healy, J.; Hemberger, D. A.; Hinder, I.; Jani, K.; Khamesra, B.; Kidder, L. E.; Kumar, P.; Laguna, P.; Lousto, C. O.; Lovelace, G.; Ossokine, S.; Pfeiffer, H.; Scheel, M. A.; Shoemaker, D. M.; Szilagyi, B.; Teukolsky, S.; Zlochower, Y.

2017-11-01

We present and assess a Bayesian method to interpret gravitational wave signals from binary black holes. Our method directly compares gravitational wave data to numerical relativity (NR) simulations. In this study, we present a detailed investigation of the systematic and statistical parameter estimation errors of this method. This procedure bypasses approximations used in semianalytical models for compact binary coalescence. In this work, we use the full posterior parameter distribution for only generic nonprecessing binaries, drawing inferences away from the set of NR simulations used, via interpolation of a single scalar quantity (the marginalized log likelihood, ln L ) evaluated by comparing data to nonprecessing binary black hole simulations. We also compare the data to generic simulations, and discuss the effectiveness of this procedure for generic sources. We specifically assess the impact of higher order modes, repeating our interpretation with both l ≤2 as well as l ≤3 harmonic modes. Using the l ≤3 higher modes, we gain more information from the signal and can better constrain the parameters of the gravitational wave signal. We assess and quantify several sources of systematic error that our procedure could introduce, including simulation resolution and duration; most are negligible. We show through examples that our method can recover the parameters for equal mass, zero spin, GW150914-like, and unequal mass, precessing spin sources. Our study of this new parameter estimation method demonstrates that we can quantify and understand the systematic and statistical error. This method allows us to use higher order modes from numerical relativity simulations to better constrain the black hole binary parameters.

Measuring the spin of black holes in binary systems using gravitational waves.

PubMed

Vitale, Salvatore; Lynch, Ryan; Veitch, John; Raymond, Vivien; Sturani, Riccardo

2014-06-27

Compact binary coalescences are the most promising sources of gravitational waves (GWs) for ground-based detectors. Binary systems containing one or two spinning black holes are particularly interesting due to spin-orbit (and eventual spin-spin) interactions and the opportunity of measuring spins directly through GW observations. In this Letter, we analyze simulated signals emitted by spinning binaries with several values of masses, spins, orientations, and signal-to-noise ratios, as detected by an advanced LIGO-Virgo network. We find that for moderate or high signal-to-noise ratio the spin magnitudes can be estimated with errors of a few percent (5%-30%) for neutron star-black hole (black hole-black hole) systems. Spins' tilt angle can be estimated with errors of 0.04 rad in the best cases, but typical values will be above 0.1 rad. Errors will be larger for signals barely above the threshold for detection. The difference in the azimuth angles of the spins, which may be used to check if spins are locked into resonant configurations, cannot be constrained. We observe that the best performances are obtained when the line of sight is perpendicular to the system's total angular momentum and that a sudden change of behavior occurs when a system is observed from angles such that the plane of the orbit can be seen both from above and below during the time the signal is in band. This study suggests that direct measurement of black hole spin by means of GWs can be as precise as what can be obtained from x-ray binaries.

Randomizing world trade. II. A weighted network analysis

NASA Astrophysics Data System (ADS)

Squartini, Tiziano; Fagiolo, Giorgio; Garlaschelli, Diego

2011-10-01

Based on the misleading expectation that weighted network properties always offer a more complete description than purely topological ones, current economic models of the International Trade Network (ITN) generally aim at explaining local weighted properties, not local binary ones. Here we complement our analysis of the binary projections of the ITN by considering its weighted representations. We show that, unlike the binary case, all possible weighted representations of the ITN (directed and undirected, aggregated and disaggregated) cannot be traced back to local country-specific properties, which are therefore of limited informativeness. Our two papers show that traditional macroeconomic approaches systematically fail to capture the key properties of the ITN. In the binary case, they do not focus on the degree sequence and hence cannot characterize or replicate higher-order properties. In the weighted case, they generally focus on the strength sequence, but the knowledge of the latter is not enough in order to understand or reproduce indirect effects.

Clustered-dot halftoning with direct binary search.

PubMed

Goyal, Puneet; Gupta, Madhur; Staelin, Carl; Fischer, Mani; Shacham, Omri; Allebach, Jan P

2013-02-01

In this paper, we present a new algorithm for aperiodic clustered-dot halftoning based on direct binary search (DBS). The DBS optimization framework has been modified for designing clustered-dot texture, by using filters with different sizes in the initialization and update steps of the algorithm. Following an intuitive explanation of how the clustered-dot texture results from this modified framework, we derive a closed-form cost metric which, when minimized, equivalently generates stochastic clustered-dot texture. An analysis of the cost metric and its influence on the texture quality is presented, which is followed by a modification to the cost metric to reduce computational cost and to make it more suitable for screen design.

Photometric Follow-up of Eclipsing Binary Candidates from KELT and Kepler

NASA Astrophysics Data System (ADS)

Garcia Soto, Aylin; Rodriguez, Joseph E.; Bieryla, Allyson; KELT survey

2018-01-01

Eclipsing binaries (EBs) are incredibly valuable, as they provide the opportunity to precisely measure fundamental stellar parameters without the need for stellar models. Therefore, we can use EBs to directly test stellar evolution models. Constraining the stellar properties of stars is important since they directly influence our understanding of any planets orbiting them. Using the Harvard University's Clay 0.4m telescope and Fred Lawrence Whipple Observatory’s 1.2m telescope on Mount Hopkins, Arizona, we conducted follow-up multi-band photometric observations of EB candidates from the Kilodegree Extremely Little Telescope (KELT) survey and the Kepler mission. We will present our follow-up observations and AstroImageJ analysis on these 5 EB systems.

Catalog of 174 Binary Black Hole Simulations for Gravitational Wave Astronomy

NASA Astrophysics Data System (ADS)

Mroué, Abdul H.; Scheel, Mark A.; Szilágyi, Béla; Pfeiffer, Harald P.; Boyle, Michael; Hemberger, Daniel A.; Kidder, Lawrence E.; Lovelace, Geoffrey; Ossokine, Serguei; Taylor, Nicholas W.; Zenginoğlu, Anıl; Buchman, Luisa T.; Chu, Tony; Foley, Evan; Giesler, Matthew; Owen, Robert; Teukolsky, Saul A.

2013-12-01

This Letter presents a publicly available catalog of 174 numerical binary black hole simulations following up to 35 orbits. The catalog includes 91 precessing binaries, mass ratios up to 8∶1, orbital eccentricities from a few percent to 10-5, black hole spins up to 98% of the theoretical maximum, and radiated energies up to 11.1% of the initial mass. We establish remarkably good agreement with post-Newtonian precession of orbital and spin directions for two new precessing simulations, and we discuss other applications of this catalog. Formidable challenges remain: e.g., precession complicates the connection of numerical and approximate analytical waveforms, and vast regions of the parameter space remain unexplored.

Catalog of 174 binary black hole simulations for gravitational wave astronomy.

PubMed

Mroué, Abdul H; Scheel, Mark A; Szilágyi, Béla; Pfeiffer, Harald P; Boyle, Michael; Hemberger, Daniel A; Kidder, Lawrence E; Lovelace, Geoffrey; Ossokine, Serguei; Taylor, Nicholas W; Zenginoğlu, Anıl; Buchman, Luisa T; Chu, Tony; Foley, Evan; Giesler, Matthew; Owen, Robert; Teukolsky, Saul A

2013-12-13

This Letter presents a publicly available catalog of 174 numerical binary black hole simulations following up to 35 orbits. The catalog includes 91 precessing binaries, mass ratios up to 8∶1, orbital eccentricities from a few percent to 10(-5), black hole spins up to 98% of the theoretical maximum, and radiated energies up to 11.1% of the initial mass. We establish remarkably good agreement with post-Newtonian precession of orbital and spin directions for two new precessing simulations, and we discuss other applications of this catalog. Formidable challenges remain: e.g., precession complicates the connection of numerical and approximate analytical waveforms, and vast regions of the parameter space remain unexplored.

Gene-specific cell labeling using MiMIC transposons.

PubMed

Gnerer, Joshua P; Venken, Koen J T; Dierick, Herman A

2015-04-30

Binary expression systems such as GAL4/UAS, LexA/LexAop and QF/QUAS have greatly enhanced the power of Drosophila as a model organism by allowing spatio-temporal manipulation of gene function as well as cell and neural circuit function. Tissue-specific expression of these heterologous transcription factors relies on random transposon integration near enhancers or promoters that drive the binary transcription factor embedded in the transposon. Alternatively, gene-specific promoter elements are directly fused to the binary factor within the transposon followed by random or site-specific integration. However, such insertions do not consistently recapitulate endogenous expression. We used Minos-Mediated Integration Cassette (MiMIC) transposons to convert host loci into reliable gene-specific binary effectors. MiMIC transposons allow recombinase-mediated cassette exchange to modify the transposon content. We developed novel exchange cassettes to convert coding intronic MiMIC insertions into gene-specific binary factor protein-traps. In addition, we expanded the set of binary factor exchange cassettes available for non-coding intronic MiMIC insertions. We show that binary factor conversions of different insertions in the same locus have indistinguishable expression patterns, suggesting that they reliably reflect endogenous gene expression. We show the efficacy and broad applicability of these new tools by dissecting the cellular expression patterns of the Drosophila serotonin receptor gene family. © The Author(s) 2015. Published by Oxford University Press on behalf of Nucleic Acids Research.

Very massive runaway stars from three-body encounters

NASA Astrophysics Data System (ADS)

Gvaramadze, Vasilii V.; Gualandris, Alessia

2011-01-01

Very massive stars preferentially reside in the cores of their parent clusters and form binary or multiple systems. We study the role of tight very massive binaries in the origin of the field population of very massive stars. We performed numerical simulations of dynamical encounters between single (massive) stars and a very massive binary with parameters similar to those of the most massive known Galactic binaries, WR 20a and NGC 3603-A1. We found that these three-body encounters could be responsible for the origin of high peculiar velocities (≥70 km s-1) observed for some very massive (≥60-70 M⊙) runaway stars in the Milky Way and the Large Magellanic Cloud (e.g. λ Cep, BD+43°3654, Sk -67°22, BI 237, 30 Dor 016), which can hardly be explained within the framework of the binary-supernova scenario. The production of high-velocity massive stars via three-body encounters is accompanied by the recoil of the binary in the opposite direction to the ejected star. We show that the relative position of the very massive binary R145 and the runaway early B-type star Sk-69°206 on the sky is consistent with the possibility that both objects were ejected from the central cluster, R136, of the star-forming region 30 Doradus via the same dynamical event - a three-body encounter.

Using binary statistics in Taurus-Auriga to distinguish between brown dwarf formation processes

NASA Astrophysics Data System (ADS)

Marks, M.; Martín, E. L.; Béjar, V. J. S.; Lodieu, N.; Kroupa, P.; Manjavacas, E.; Thies, I.; Rebolo López, R.; Velasco, S.

2017-08-01

Context. One of the key questions of the star formation problem is whether brown dwarfs (BDs) form in the manner of stars directly from the gravitational collapse of a molecular cloud core (star-like) or whether BDs and some very low-mass stars (VLMSs) constitute a separate population that forms alongside stars comparable to the population of planets, for example through circumstellar disk (peripheral) fragmentation. Aims: For young stars in Taurus-Auriga the binary fraction has been shown to be large with little dependence on primary mass above ≈ 0.2 M⊙, while for BDs the binary fraction is < 10%. Here we investigate a case in which BDs in Taurus formed dominantly, but not exclusively, through peripheral fragmentation, which naturally results in small binary fractions. The decline of the binary frequency in the transition region between star-like formation and peripheral formation is modelled. Methods: We employed a dynamical population synthesis model in which stellar binary formation is universal with a large binary fraction close to unity. Peripheral objects form separately in circumstellar disks with a distinctive initial mass function (IMF), their own orbital parameter distributions for binaries, and small binary fractions, according to observations and expectations from smoothed particle hydrodynamics (SPH) and grid-based computations. A small amount of dynamical processing of the stellar component was accounted for as appropriate for the low-density Taurus-Auriga embedded clusters. Results: The binary fraction declines strongly in the transition region between star-like and peripheral formation, exhibiting characteristic features. The location of these features and the steepness of this trend depend on the mass limits for star-like and peripheral formation. Such a trend might be unique to low density regions, such as Taurus, which host binary populations that are largely unprocessed dynamically in which the binary fraction is large for stars down to M-dwarfs and small for BDs. Conclusions: The existence of a strong decline in the binary fraction - primary mass diagram will become verifiable in future surveys on BD and VLMS binarity in the Taurus-Auriga star-forming region. The binary fraction - primary mass diagram is a diagnostic of the (non-)continuity of star formation along the mass scale, the separateness of the stellar and BD populations, and the dominant formation channel for BDs and BD binaries in regions of low stellar density hosting dynamically unprocessed populations.

Binary power multiplier for electromagnetic energy

DOEpatents

Farkas, Zoltan D.

1988-01-01

A technique for converting electromagnetic pulses to higher power amplitude and shorter duration, in binary multiples, splits an input pulse into two channels, and subjects the pulses in the two channels to a number of binary pulse compression operations. Each pulse compression operation entails combining the pulses in both input channels and selectively steering the combined power to one output channel during the leading half of the pulses and to the other output channel during the trailing half of the pulses, and then delaying the pulse in the first output channel by an amount equal to half the initial pulse duration. Apparatus for carrying out each of the binary multiplication operation preferably includes a four-port coupler (such as a 3 dB hybrid), which operates on power inputs at a pair of input ports by directing the combined power to either of a pair of output ports, depending on the relative phase of the inputs. Therefore, by appropriately phase coding the pulses prior to any of the pulse compression stages, the entire pulse compression (with associated binary power multiplication) can be carried out solely with passive elements.

Gamma-rays from the binary system containing PSR J2032+4127 during its periastron passage

NASA Astrophysics Data System (ADS)

Bednarek, Włodek; Banasiński, Piotr; Sitarek, Julian

2018-01-01

The energetic pulsar, PSR J2032+4127, has recently been discovered in the direction of the unidentified HEGRA TeV γ-ray source (TeV J2032+4130). It is proposed that this pulsar forms a binary system with the Be type star, MT91 213, expected to reach periastron late in 2017. We performed detailed calculations of the γ-ray emission produced close to the binary system’s periastron passage by applying a simple geometrical model. Electrons accelerated at the collision region of pulsar and stellar winds initiate anisotropic inverse Compton {e}+/- pair cascades by scattering soft radiation from the massive companion. The γ-ray spectra, from such a comptonization process, are compared with the measurements of the extended TeV γ-ray emission from the HEGRA TeV γ-ray source. We discuss conditions within the binary system, at the periastron passage of the pulsar, for which the γ-ray emission from the binary can overcome the extended, steady TeV γ-ray emission from the HEGRA TeV γ-ray source.