The Northeast heating fuel market: Assessment and options

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

In response to a Presidential request, this study examines how the distillate fuel oil market (and related energy markets) in the Northeast behaved in the winter of 1999-2000, explains the role played by residential, commercial, industrial, and electricity generation sector consumers in distillate fuel oil markets and describes how that role is influenced by the structure of tie energy markets in the Northeast. In addition, this report explores the potential for nonresidential users to move away from distillate fuel oil and how this might impact future prices, and discusses conversion of distillate fuel oil users to other fuels over themore » next 5 years. Because the President's and Secretary's request focused on converting factories and other large-volume users of mostly high-sulfur distillate fuel oil to other fuels, transportation sector use of low-sulfur distillate fuel oil is not examined here.« less

Bio-Oil Deployment in the Home Heating Market

DOE Office of Scientific and Technical Information (OSTI.GOV)

Butcher, T. A.; Trojanowski, R.; Mante, O.

Distillate fuel oil is used in many stationary heating applications, predominantly in the Northeastern part of the United States. Total estimated non-transportation distillate use in 2014 was estimated to be 10.9 billion gallons. This study has focused on potentially displacing part of this petroleum use with biofuel derived from woody biomass. The fuel production route considered is pyrolysis which creates a liquid fuel high in oxygen, organic acids, and water. While this fuel can be used in stationary applications without significant further processing, to do so would require significant upgrades in current heating equipment. Alternatively this raw pyrolysis oil canmore » be upgraded through catalytic hydrogenation to produce a bio-oil with near-negligible oxygen, water, and acidity. The focus of this work has been exploration of such upgraded fuels. The quality of upgraded fuels is affected by process conditions and there is a cost /quality tradeoff.« less

New Catalyst Reduces Wasted Carbon in Biofuel Process, Lowers Cost

DOE Office of Scientific and Technical Information (OSTI.GOV)

Researchers at NREL recently developed a catalyst formulation that incorporates more hydrogen into the DME-to-high-octane gasoline process, resulting in a higher yield to gasoline-range products. Further, the researchers developed a secondary process that efficiently couples a portion of the gasoline-range product to yield jet/diesel fuels. The modified catalyst doubles the conversion rate of DME, which can be produced from biomass, to the high-octane gasoline product and significantly decreases the formation of wasted byproducts. For the distillate-range product, 80% of the mixture is in line with ASTM standards for use as a jet fuel blendstock. The increased productivity of high-octane gasolinemore » and the development of a value-added distillate blendstock process further improve the economic viability toward commercially implementing this renewable fuels process.« less

EFFICIENT RECOVERY OF BIOETHANOL USING NOVEL PERVAPORATION-DEPHLEGMATION PROCESS

EPA Science Inventory

Bioethanol is the most important liquid fuel made in the U.S. from domestically produced renewable resources. Traditional production of bioethanol involves batch fermation of biomass followed by ethanol recovery from the fermentation broths using distillation. The distillation st...

Application of the Advanced Distillation Curve Method to the Comparison of Diesel Fuel Oxygenates: 2,5,7,10-Tetraoxaundecane (TOU), 2,4,7,9-Tetraoxadecane (TOD), and Ethanol/Fatty Acid Methyl Ester (FAME) Mixtures.

PubMed

Burger, Jessica L; Lovestead, Tara M; LaFollette, Mark; Bruno, Thomas J

2017-08-17

Although they are amongst the most efficient engine types, compression-ignition engines have difficulties achieving acceptable particulate emission and NO x formation. Indeed, catalytic after-treatment of diesel exhaust has become common and current efforts to reformulate diesel fuels have concentrated on the incorporation of oxygenates into the fuel. One of the best ways to characterize changes to a fuel upon the addition of oxygenates is to examine the volatility of the fuel mixture. In this paper, we present the volatility, as measured by the advanced distillation curve method, of a prototype diesel fuel with novel diesel fuel oxygenates: 2,5,7,10-tetraoxaundecane (TOU), 2,4,7,9-tetraoxadecane (TOD), and ethanol/fatty acid methyl ester (FAME) mixtures. We present the results for the initial boiling behavior, the distillation curve temperatures, and track the oxygenates throughout the distillations. These diesel fuel blends have several interesting thermodynamic properties that have not been seen in our previous oxygenate studies. Ethanol reduces the temperatures observed early in the distillation (near ethanol's boiling temperature). After these early distillation points (once the ethanol has distilled out), B100 has the greatest impact on the remaining distillation curve and shifts the curve to higher temperatures than what is seen for diesel fuel/ethanol blends. In fact, for the 15% B100 mixture most of the distillation curve reaches temperatures higher than those seen diesel fuel alone. In addition, blends with TOU and TOD also exhibited uncommon characteristics. These additives are unusual because they distill over most the distillation curve (up to 70%). The effects of this can be seen both in histograms of oxygenate concentration in the distillate cuts and in the distillation curves. Our purpose for studying these oxygenate blends is consistent with our vision for replacing fit-for-purpose properties with fundamental properties to enable the development of equations of state that can describe the thermodynamic properties of complex mixtures, with specific attention paid to additives.

27 CFR 19.662 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use General § 19.662 Definitions. As used in this subpart, the following terms have the meanings indicated. Alcohol fuel plant. A... exclusively for fuel use. Bonded premises. The premises of an alcohol fuel plant where distilled spirits are...

27 CFR 19.662 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use General § 19.662 Definitions. As used in this subpart, the following terms have the meanings indicated. Alcohol fuel plant. A... exclusively for fuel use. Bonded premises. The premises of an alcohol fuel plant where distilled spirits are...

27 CFR 19.662 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-04-01

... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use General § 19.662 Definitions. As used in this subpart, the following terms have the meanings indicated. Alcohol fuel plant. A... exclusively for fuel use. Bonded premises. The premises of an alcohol fuel plant where distilled spirits are...

27 CFR 19.662 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use General § 19.662 Definitions. As used in this subpart, the following terms have the meanings indicated. Alcohol fuel plant. A... exclusively for fuel use. Bonded premises. The premises of an alcohol fuel plant where distilled spirits are...

Alcohol Fuel By-Product Utilization and Production.

ERIC Educational Resources Information Center

Boerboom, Jim

Ten lessons comprise this curriculum intended to assist vocational teachers in establishing and conducting an alcohol fuels workshop on engine modification and plant design. A glossary is provided first. The 10 lessons cover these topics: the alcohol fuel plant, feedstock preparation lab, distillation lab, fuel plant processes, plant design lab,…

Fate of virginiamycin through the fuel ethanol production process

USDA-ARS?s Scientific Manuscript database

Antibiotics are frequently used to prevent and treat bacterial contamination of commercial fuel ethanol fermentations, but there is concern that antibiotic residues may persist in the distillers grains coproducts. A study to evaluate the fate of virginiamycin during the ethanol production process wa...

Chemical composition of distillers grains, a review.

PubMed

Liu, KeShun

2011-03-09

In recent years, increasing demand for ethanol as a fuel additive and decreasing dependency on fossil fuels have resulted in a dramatic increase in the amount of grains used for ethanol production. Dry-grind is the major process, resulting in distillers dried grains with solubles (DDGS) as a major coproduct. Like fuel ethanol, DDGS has quickly become a global commodity. However, high compositional variation has been the main problem hindering its use as a feed ingredient. This review provides updated information on the chemical composition of distillers grains in terms of nutrient levels, changes during dry-grind processing, and causes for large variation. The occurrence in grain feedstock and the fate of mycotoxins during processing are also covered. During processing, starch is converted to glucose and then to ethanol and carbon dioxide. Most other components are relatively unchanged but concentrated in DDGS about 3-fold over the original feedstock. Mycotoxins, if present in the original feedstock, are also concentrated. Higher fold of increases in S, Na, and Ca are mostly due to exogenous addition during processing, whereas unusual changes in inorganic phosphorus (P) and phytate P indicate phytate hydrolysis by yeast phytase. Fermentation causes major changes, but other processing steps are also responsible. The causes for varying DDGS composition are multiple, including differences in feedstock species and composition, process methods and parameters, the amount of condensed solubles added to distiller wet grains, the effect of fermentation yeast, and analytical methodology. Most of them can be attributed to the complexity of the dry-grind process itself. It is hoped that information provided in this review will improve the understanding of the dry-grind process and aid in the development of strategies to control the compositional variation in DDGS.

Coal liquefaction process

DOEpatents

Wright, Charles H.

1986-01-01

A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

75 FR 21300 - North American Bioproducts Corp.; Filing of Food Additive Petition (Animal Use); Erythromycin...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-23

... antimicrobial processing aid in fuel- ethanol fermentations with respect to its consequent presence in by... aid in fuel- ethanol fermentations with respect to its consequent presence in by- product distiller...

Improvement studies on emission and combustion characteristics of DICI engine fuelled with colloidal emulsion of diesel distillate of plastic oil, TiO2 nanoparticles and water.

PubMed

Karisathan Sundararajan, Narayanan; Ammal, Anand Ramachandran Bhagavathi

2018-04-01

Experimentation was conducted on a single cylinder CI engine using processed colloidal emulsions of TiO 2 nanoparticle-water-diesel distillate of crude plastic diesel oil as test fuel. The test fuel was prepared with plastic diesel oil as the principal constituent by a novel blending technique with an aim to improve the working characteristics. The results obtained by the test fuel from the experiments were compared with that of commercial petro-diesel (CPD) fuel for same engine operating parameters. Plastic oil produced from high density polyethylene plastic waste by pyrolysis was subjected to fractional distillation for separating plastic diesel oil (PDO) that contains diesel range hydrocarbons. The blending process showed a little improvement in the field of fuel oil-water-nanometal oxide colloidal emulsion preparation due to the influence of surfactant in electrostatic stabilization, dielectric potential, and pH of the colloidal medium on the absolute value of zeta potential, a measure of colloidal stability. The engine tests with nano-emulsions of PDO showed an increase in ignition delay (23.43%), and decrease in EGT (6.05%), BSNO x (7.13%), and BSCO (28.96%) relative to PDO at rated load. Combustion curve profiles, percentage distribution of compounds, and physical and chemical properties of test fuels ascertains these results. The combustion acceleration at diffused combustion phase was evidenced in TiO 2 emulsion fuels under study.

Distillate Fuel Oil Assessment for Winter 1996-1997

EIA Publications

1997-01-01

This article describes findings of an analysis of the current low level of distillate stocks which are available to help meet the demand for heating fuel this winter, and presents a summary of the Energy Information Administration's distillate fuel oil outlook for the current heating season under two weather scenarios.

Distillers Dried Grains with Solubles (DDGS) – A Key to the Fuel Ethanol Industry

USDA-ARS?s Scientific Manuscript database

Corn-based ethanol in the U.S. has dramatically increased in recent years; so has the quantity of associated coproducts. Nonfermentable components are removed from the process as whole stillage, centrifuged to remove water – which is then evaporated to produce condensed distillers solubles (CDS), a...

Treating thin stillage or condensed distillers solubles with phytase for production of low phytate co-products

USDA-ARS?s Scientific Manuscript database

Fuel ethanol production from grains is mainly based on dry grind processing, during which phytate is concentrated about three fold in distillers dried grains with solubles (DDGS), a major co-product. For reducing phyate in DDGS, two industrial phytase preparations (Natuphos and Ronozyme) were used ...

Coal liquefaction process

DOEpatents

Wright, C.H.

1986-02-11

A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

Production of distillate fuels from biomass-derived polyoxygenates

DOEpatents

Kania, John; Blommel, Paul; Woods, Elizabeth; Dally, Brice; Lyman, Warren; Cortright, Randy

2017-03-14

The present invention provides methods, reactor systems and catalysts for converting biomass and biomass-derived feedstocks to C.sub.8+ hydrocarbons using heterogenous catalysts. The product stream may be separated and further processed for use in chemical applications, or as a neat fuel or a blending component in jet fuel and diesel fuel, or as heavy oils for lubricant and/or fuel oil applications.

Coal liquefaction process

DOEpatents

Skinner, Ronald W.; Tao, John C.; Znaimer, Samuel

1985-01-01

This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

Fuel oil and kerosene sales, 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-01-22

Despite the rise in petroleum products prices, a colder-than-normal winter in the latter part of 1989 spurred an increase in demand for distillate fuel oils. The shipping and electric utilities industries contributed to a significant rise in demand for both distillate and residual fuels oils in 1989. A total of 72.9 billion gallons of fuel oil and kerosene were sold to consumers in 1989, an increase of 3.0 percent over 1988 sales volumes. Of all fuel oil sold during 1989, distillate fuel oil accounted for 68.3 percent, which was an increase over 1988 when distillate fuel oil accounted for 67.2more » percent of all fuel oil products sold in the United States. Residual fuel oil's share of total fuel oil sold fell slightly to 29.9 percent from 30.7 percent in 1988. Kerosene followed with a 1.8 percent share, also falling from the previous year when it accounted for a 2.1 percent share of total fuel oil sold. 3 figs., 24 tabs.« less

27 CFR 19.739 - Authorized transfers to or from distilled spirits plants.

Code of Federal Regulations, 2011 CFR

2011-04-01

... coal, a proprietor of an alcohol fuel plant may receive spirits in bond from a distilled spirits plant qualified under subpart D of this part. A proprietor of an alcohol fuel plant may also transfer spirits in bond from the alcohol fuel plant to a distilled spirits plant qualified under subpart D of this part...

Liquefaction Of Coal With Surfactant And Disposable Catalyst

NASA Technical Reports Server (NTRS)

Hickey, Gregory S.; Sharma, Pramod K.

1996-01-01

Fuels derived from coal more competitive with petroleum products. Improved coal-liquefaction process exploits synergistic effects of disposable iron oxide catalyst and cheap anionic surfactant. Efficiency of conversion achieved in significantly higher than efficiencies obtained with addition of either surfactant or catalyst alone. No costly pretreatment necessary, and increase in conversion achieved under processing conditions milder than those used heretofore in liquefaction of coal. Quality of distillates obtained after liquefaction in process expected superior to distillates obtained after liquefaction by older techniques.

Synthesis and analysis of jet fuels from shale oil and coal syncrudes

NASA Technical Reports Server (NTRS)

Antoine, A. C.; Gallagher, J. P.

1976-01-01

The technical problems involved in converting a significant portion of a barrel of either a shale oil or coal syncrude into a suitable aviation turbine fuel were studied. TOSCO shale oil, H-Coal and COED coal syncrudes were the starting materials. They were processed by distillation and hydrocracking to produce two levels of yield (20 and 40 weight percent) of material having a distillation range of approximately 422 to 561 K (300 F to 550 F). The full distillation range 311 to 616 K (100 F to 650 F) materials were hydrotreated to meet two sets of specifications (20 and 40 volume percent aromatics, 13.5 and 12.75 weight percent H, 0.2 and 0.5 weight percent S, and 0.1 and 0.2 weight percent N). The hydrotreated materials were distilled to meet given end point and volatility requirements. The syntheses were carried out in laboratory and pilot plant equipment scaled to produce thirty-two 0.0757 cu m (2-gal)samples of jet fuel of varying defined specifications. Detailed analyses for physical and chemical properties were made on the crude starting materials and on the products.

40 CFR 80.598 - What are the designation requirements for refiners, importers, and distributors?

Code of Federal Regulations, 2010 CFR

2010-07-01

... (MVNRLM) diesel fuel. (B) Heating oil. (C) Jet fuel. (D) Kerosene. (E) No. 4 fuel. (F) Distillate fuel for... for use as kerosene or jet fuel (i.e., commonly referred to as dual use kerosene) may be designated as MVNRLM, kerosene, or jet fuel (as applicable). (viii) Beginning June 1, 2007, any distillate fuel with a...

40 CFR 80.598 - What are the designation requirements for refiners, importers, and distributors?

Code of Federal Regulations, 2013 CFR

2013-07-01

... (MVNRLM) diesel fuel. (B) Heating oil. (C) Jet fuel. (D) Kerosene. (E) No. 4 fuel. (F) Distillate fuel for... for use as kerosene or jet fuel (i.e., commonly referred to as dual use kerosene) may be designated as MVNRLM, kerosene, or jet fuel (as applicable). (viii) Beginning June 1, 2007, any distillate fuel with a...

40 CFR 80.598 - What are the designation requirements for refiners, importers, and distributors?

Code of Federal Regulations, 2012 CFR

2012-07-01

... (MVNRLM) diesel fuel. (B) Heating oil. (C) Jet fuel. (D) Kerosene. (E) No. 4 fuel. (F) Distillate fuel for... for use as kerosene or jet fuel (i.e., commonly referred to as dual use kerosene) may be designated as MVNRLM, kerosene, or jet fuel (as applicable). (viii) Beginning June 1, 2007, any distillate fuel with a...

40 CFR 80.598 - What are the designation requirements for refiners, importers, and distributors?

Code of Federal Regulations, 2014 CFR

2014-07-01

... (MVNRLM) diesel fuel. (B) Heating oil. (C) Jet fuel. (D) Kerosene. (E) No. 4 fuel. (F) Distillate fuel for... for use as kerosene or jet fuel (i.e., commonly referred to as dual use kerosene) may be designated as MVNRLM, kerosene, or jet fuel (as applicable). (viii) Beginning June 1, 2007, any distillate fuel with a...

40 CFR 80.598 - What are the designation requirements for refiners, importers, and distributors?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (MVNRLM) diesel fuel. (B) Heating oil. (C) Jet fuel. (D) Kerosene. (E) No. 4 fuel. (F) Distillate fuel for... for use as kerosene or jet fuel (i.e., commonly referred to as dual use kerosene) may be designated as MVNRLM, kerosene, or jet fuel (as applicable). (viii) Beginning June 1, 2007, any distillate fuel with a...

Recycling of waste engine oil for diesel production.

PubMed

Maceiras, R; Alfonsín, V; Morales, F J

2017-02-01

The aim of this work was to recycle waste engine oil until converting it into reusable product, diesel fuel. The waste oil was treated using pyrolytic distillation. The effect of two additives (sodium hydroxide and sodium carbonate) in the purification of the obtained fuel was also studied. Moreover, the influence of the number of distillations were analysed. Some thermal and physicochemical properties (density, viscosity, colour, turbidity, acidity value, distillation curves, cetane number, corrosiveness to Cu, water content, flash point and hydrocarbons) were determined to analyse the quality of the obtained fuel. The best results were obtained with 2% of sodium carbonate and two successive distillations. The obtained results showed that pyrolytic distillation of waste engine oil is an excellent way to produce diesel fuel to be used in engines. Copyright © 2016 Elsevier Ltd. All rights reserved.

49 CFR 172.336 - Identification numbers; special provisions.

Code of Federal Regulations, 2013 CFR

2013-10-01

... accordance with § 172.542(c). (3) On cargo tanks They contain only fuel oil The cargo tank is marked “Fuel... petroleum distillate fuel The identification number for the liquid petroleum distillate fuel having the lowest flash point is displayed. If the cargo tank also contains gasoline and alcohol fuel blends...

Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beverly L. Smith; Thomas J. Bruno

2007-09-15

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of eachmore » distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.« less

Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels

DOEpatents

Herling, Darrell R [Richland, WA; Aardahl, Chris L [Richland, WA; Rozmiarek, Robert T [Middleton, WI; Rappe, Kenneth G [Richland, WA; Wang, Yong [Richland, WA; Holladay, Jamelyn D [Kennewick, WA

2010-06-29

The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

DOEpatents

Herling, Darrell R [Richland, WA; Aardahl, Chris L [Richland, WA; Rozmiarek, Robert T [Middleton, WI; Rappe, Kenneth G [Richland, WA; Wang, Yong [Richland, WA; Holladay, Jamelyn D [Kennewick, WA

2008-10-14

The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

Distillation-based Droplet Modeling of Non-Ideal Oxygenated Gasoline Blends: Investigating the Role of Droplet Evaporation on PM Emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burke, Stephen C.; Ratcliff, Matthew; McCormick, Robert

In some studies, a relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from vehicles equipped with spark ignition engines. The fundamental cause of the PM increase seen for moderate ethanol concentrations is not well understood. Ethanol features a greater heat of vaporization (HOV) than gasoline and also influences vaporization by altering the liquid and vapor composition throughout the distillation process. A droplet vaporization model was developed to explore ethanol's effect on the evaporation of aromatic compounds known to be PM precursors. The evolving droplet composition is modeled as a distillation process, withmore » non-ideal interactions between oxygenates and hydrocarbons accounted for using UNIFAC group contribution theory. Predicted composition and distillation curves were validated by experiments. Detailed hydrocarbon analysis was applied to fuel samples and to distillate fractions, and used as input for the initial droplet composition. With composition calculated throughout the distillation, the changing HOV and other physical properties can be found using reference data. The droplet can thus be modeled in terms of energy transfer, which in turn provides the transient mass transfer, droplet temperature, and droplet diameter. Model predictions suggest that non-ideal vapor-liquid equilibrium along with an increase in HOV can alter the droplet composition evolution. Results predict that the presence of ethanol causes enrichment of the higher boiling fractions (T90+) in the aromatic components as well as lengthens the droplet lifetime. A simulation of the evaporation process in a transient environment as experienced within an engine cylinder predicts a decrease in mixing time of the heaviest fractions of the fuel prior to spark initiation, possibly explaining observations linking ethanol to PM.« less

Distillation-based Droplet Modeling of Non-Ideal Oxygenated Gasoline Blends: Investigating the Role of Droplet Evaporation on PM Emissions

DOE PAGES

Burke, Stephen C.; Ratcliff, Matthew; McCormick, Robert; ...

2017-03-28

In some studies, a relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from vehicles equipped with spark ignition engines. The fundamental cause of the PM increase seen for moderate ethanol concentrations is not well understood. Ethanol features a greater heat of vaporization (HOV) than gasoline and also influences vaporization by altering the liquid and vapor composition throughout the distillation process. A droplet vaporization model was developed to explore ethanol's effect on the evaporation of aromatic compounds known to be PM precursors. The evolving droplet composition is modeled as a distillation process, withmore » non-ideal interactions between oxygenates and hydrocarbons accounted for using UNIFAC group contribution theory. Predicted composition and distillation curves were validated by experiments. Detailed hydrocarbon analysis was applied to fuel samples and to distillate fractions, and used as input for the initial droplet composition. With composition calculated throughout the distillation, the changing HOV and other physical properties can be found using reference data. The droplet can thus be modeled in terms of energy transfer, which in turn provides the transient mass transfer, droplet temperature, and droplet diameter. Model predictions suggest that non-ideal vapor-liquid equilibrium along with an increase in HOV can alter the droplet composition evolution. Results predict that the presence of ethanol causes enrichment of the higher boiling fractions (T90+) in the aromatic components as well as lengthens the droplet lifetime. A simulation of the evaporation process in a transient environment as experienced within an engine cylinder predicts a decrease in mixing time of the heaviest fractions of the fuel prior to spark initiation, possibly explaining observations linking ethanol to PM.« less

27 CFR 19.907 - Meaning of terms.

Code of Federal Regulations, 2010 CFR

2010-04-01

... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Definitions § 19.907.... CFR. The Code of Federal Regulations. Fuel alcohol. Distilled spirits which have been rendered unfit... gas, or coal. This chapter. Title 27, Code of Federal Regulations, Chapter I [27 CFR Chapter I...

27 CFR 19.709 - Gauging.

Code of Federal Regulations, 2011 CFR

2011-04-01

... Gauging. (a) Gauging equipment and methods. A proprietor of an alcohol fuel plant must perform periodic gauges of the distilled spirits and fuel alcohol at the alcohol fuel plant. The procedures for the... following rules for the gauging of distilled spirits and fuel alcohol under this subpart also apply: (1) The...

Production of bio-fuel ethanol from distilled grain waste eluted from Chinese spirit making process.

PubMed

Tan, Li; Sun, Zhaoyong; Zhang, Wenxue; Tang, Yueqin; Morimura, Shigeru; Kida, Kenji

2014-10-01

Distilled grain waste eluted from Chinese spirit making is rich in carbohydrates, and could potentially serve as feedstock for the production of bio-fuel ethanol. Our study evaluated two types of saccharification methods that convert distilled grain waste to monosaccharides: enzymatic saccharification and concentrated H2SO4 saccharification. Results showed that enzymatic saccharification performed unsatisfactorily because of inefficient removal of lignin during pretreatment. Concentrated H2SO4 saccharification led to a total sugar recovery efficiency of 79.0 %, and to considerably higher sugar concentrations than enzymatic saccharification. The process of ethanol production from distilled grain waste based on concentrated H2SO4 saccharification was then studied. The process mainly consisted of concentrated H2SO4 saccharification, solid-liquid separation, decoloration, sugar-acid separation, oligosaccharide hydrolysis, and continuous ethanol fermentation. An improved simulated moving bed system was employed to separate sugars from acid after concentrated H2SO4 saccharification, by which 95.8 % of glucose and 85.8 % of xylose went into the sugar-rich fraction, while 83.3 % of H2SO4 went into the acid-rich fraction. A flocculating yeast strain, Saccharomyces cerevisiae KF-7, was used for continuous ethanol fermentation, which produced an ethanol yield of 91.9-98.9 %, based on glucose concentration.

27 CFR 19.729 - Withdrawal of fuel alcohol.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Withdrawal of fuel alcohol..., DEPARTMENT OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Rules for Use, Withdrawal, and Transfer of Spirits § 19.729 Withdrawal of fuel alcohol. (a) For each shipment or other...

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

DOEpatents

Knauss, Kevin G.; Copenhaver, Sally C.; Aines, Roger D.

2000-01-01

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Role of Volatility in the Development of JP-8 Surrogates for Diesel Engine Application

DTIC Science & Technology

2014-01-01

distillation curves of the surrogate fuels were calculated using the Aspen HYSYS [41] software package, and the Peng- Robinson model was chosen to...distillation curves for the surrogate fuels developed in this investigation, the accuracy of Aspen HYSYS software predictions were compared with...and SF3. The distillation curves calculated using Aspen HYSYS software for the five surrogate fuels of Table 1 are shown in Figure 7, along with the

Chemicals from coal. Interim report for USBM Synthoil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, B.C.

1977-10-01

This document contains the results of an investigation to determine the suitability of the USBM Synthoil Product as a petrochemical feedstock. A sample of the whole crude was distilled into two straight run fractions; 350 to 650/sup 0/F mid-distillate and 650/sup 0/F+ residue. Laboratory studies in metal reactors and computer and mathematical simulations were performed to provide overall material balance data for a conceptual plant. The mid-distillate was hydrocracked to produce naphtha which was further processed by hydrotreating and reforming. The reformate from the mid-distillate was then mathematically hydrodealkylated to convert it to a product slate consisting of methane, LPG's,more » benzene, and fuel, along with the total hydrogen consumed. The value of the products obtained per 100 pounds of mid-distillate was $6.89. The high aromatic yield obtained from the hydrocrackate naphtha makes this fraction very attractive as a petrochemical feedstock. Because the gas oil would be extremely difficult to process, it was not investigated.« less

Establishment and assessment of a novel cleaner production process of corn grain fuel ethanol.

PubMed

Wang, Ke; Zhang, Jianhua; Tang, Lei; Zhang, Hongjian; Zhang, Guiying; Yang, Xizhao; Liu, Pei; Mao, Zhonggui

2013-11-01

An integrated corn ethanol-methane fermentation system was proposed to solve the problem of stillage handling, where thin stillage was treated by anaerobic digestion and then reused to make mash for the following ethanol fermentation. This system was evaluated at laboratory and pilot scale. Anaerobic digestion of thin stillage ran steadily with total chemical oxygen demand removal efficiency of 98% at laboratory scale and 97% at pilot scale. Ethanol production was not influenced by recycling anaerobic digestion effluent at laboratory and pilot scale. Compared with dried distillers' grains with solubles produced in conventional process, dried distillers' grains in the proposed system exhibited higher quality because of increased protein concentration and decreased salts concentration. Energetic assessment indicated that application of this novel process enhanced the net energy balance ratio from 1.26 (conventional process) to 1.76. In conclusion, the proposed system possessed technical advantage over the conventional process for corn fuel ethanol production. Copyright © 2013 Elsevier Ltd. All rights reserved.

Pyroprocessing of Fast Flux Test Facility Nuclear Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

B.R. Westphal; G.L. Fredrickson; G.G. Galbreth

Used nuclear fuel from the Fast Flux Test Facility (FFTF) was recently transferred to the Idaho National Laboratory and processed by pyroprocessing in the Fuel Conditioning Facility. Approximately 213 kg of uranium from sodium-bonded metallic FFTF fuel was processed over a one year period with the equipment previously used for the processing of EBR-II used fuel. The peak burnup of the FFTF fuel ranged from 10 to 15 atom% for the 900+ chopped elements processed. Fifteen low-enriched uranium ingots were cast following the electrorefining and distillation operations to recover approximately 192 kg of uranium. A material balance on the primarymore » fuel constituents, uranium and zirconium, during the FFTF campaign will be presented along with a brief description of operating parameters. Recoverable uranium during the pyroprocessing of FFTF nuclear fuel was greater than 95% while the purity of the final electrorefined uranium products exceeded 99%.« less

Pyroprocessing of fast flux test facility nuclear fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westphal, B.R.; Wurth, L.A.; Fredrickson, G.L.

Used nuclear fuel from the Fast Flux Test Facility (FFTF) was recently transferred to the Idaho National Laboratory and processed by pyroprocessing in the Fuel Conditioning Facility. Approximately 213 kg of uranium from sodium-bonded metallic FFTF fuel was processed over a one year period with the equipment previously used for the processing of EBR-II used fuel. The peak burnup of the FFTF fuel ranged from 10 to 15 atom% for the 900+ chopped elements processed. Fifteen low-enriched uranium ingots were cast following the electrorefining and distillation operations to recover approximately 192 kg of uranium. A material balance on the primarymore » fuel constituents, uranium and zirconium, during the FFTF campaign will be presented along with a brief description of operating parameters. Recoverable uranium during the pyroprocessing of FFTF nuclear fuel was greater than 95% while the purity of the final electro-refined uranium products exceeded 99%. (authors)« less

Jet fuels from synthetic crudes

NASA Technical Reports Server (NTRS)

Antoine, A. C.; Gallagher, J. P.

1977-01-01

An investigation was conducted to determine the technical problems in the conversion of a significant portion of a barrel of either a shale oil or a coal synthetic crude oil into a suitable aviation turbine fuel. Three syncrudes were used, one from shale and two from coal, chosen as representative of typical crudes from future commercial production. The material was used to produce jet fuels of varying specifications by distillation, hydrotreating, and hydrocracking. Attention is given to process requirements, hydrotreating process conditions, the methods used to analyze the final products, the conditions for shale oil processing, and the coal liquid processing conditions. The results of the investigation show that jet fuels of defined specifications can be made from oil shale and coal syncrudes using readily available commercial processes.

Catalytic combustion of coal-derived liquids

NASA Technical Reports Server (NTRS)

Bulzan, D. L.; Tacina, R. R.

1981-01-01

A noble metal catalytic reactor was tested with three grades of SRC 2 coal derived liquids, naphtha, middle distillate, and a blend of three parts middle distillate to one part heavy distillate. A petroleum derived number 2 diesel fuel was also tested to provide a direct comparison. The catalytic reactor was tested at inlet temperatures from 600 to 800 K, reference velocities from 10 to 20 m/s, lean fuel air ratios, and a pressure of 3 x 10 to the 5th power Pa. Compared to the diesel, the naphtha gave slightly better combustion efficiency, the middle distillate was almost identical, and the middle heavy blend was slightly poorer. The coal derived liquid fuels contained from 0.58 to 0.95 percent nitrogen by weight. Conversion of fuel nitrogen to NOx was approximately 75 percent for all three grades of the coal derived liquids.

Effect of hydroprocessing severity on characteristics of jet fuel from OSCO 2 and Paraho distillates

NASA Technical Reports Server (NTRS)

Prok, G. M.; Flores, F. J.; Seng, G. T.

1981-01-01

Jet A boiling range fuels and broad-property research fuels were produced by hydroprocessing shale oil distillates, and their properties were measured to characterize the fuels. The distillates were the fraction of whole shale oil boiling below 343 C from TOSCO 2 and Paraho syncrudes. The TOSCO 2 was hydroprocessed at medium severity, and the Paraho was hydroprocessed at high, medium, and low severities. Fuels meeting Jet A requirements except for the freezing point were produced from the medium severity TOSCO 2 and the high severity Paraho. Target properties of a broad property research fuel were met by the medium severity TOSCO 2 and the high severity Paraho except for the freezing point and a high hydrogen content. Medium and low severity Paraho jet fuels did not meet thermal stability and freezing point requirements.

On-board generation of a highly volatile starting fuel to reduce automobile cold-start emissions.

PubMed

Ashford, Marcus D; Matthews, Ronald D

2006-09-15

The on-board distillation system (OBDS) was developed to extract, from gasoline, a high-volatility fuel for exclusive use during the starting and warm-up periods. The use of OBDS distillate fuel results in much improved mixture preparation, allowing combinations of air/fuel ratio and ignition timing that are not possible with gasoline, even with a fully warm engine. The volatility of the distillate is a function of the parent fuel volatility; however, the variability in distillate quality can be diminished via manipulation of the OBDS operating conditions. Thus, it is possible to develop aggressive starting calibrations that are relatively immune to variations in pump gasoline volatility. The key benefits provided bythe OBDS fuel relative to standard gasoline were found to be (1) improved mixture preparation allowing a 70% reduction of cranking fuel requirements, elimination of air-fuel mixture enrichment during the warm-up period, and significant extension of warm-up ignition timing retard; (2) a 57% decrease in catalyst light-off time, (3) emissions reductions over the FTP drive cycle of 81% for regulated hydrocarbons (NMOG); (4) emissions index (NMOG) approaching that of SULEV/PZEV vehicles; and (5) an apparent 1% increase in fuel economy over the FTP drive cycle.

Issues of Commonality. Volume II. Issue Analysis.

DTIC Science & Technology

1980-12-01

lubricating oil, and residual oil. 68 ° B Diesel fuel and kerosene make up what are known as the middle distillates. Jet fuels are blends from this...group of distillates which include some gasoline and some heavier oils. The range of hydrocarbons selected for this blending determines the "cut" of...the fuel. Wide-cut fuels are blended fram a wide range of hydrocarbons; narrow-cut fuels include only a small range of hydrocarbons from the

New co-products from grain-based fuel ethanol production and their drying performance

USDA-ARS?s Scientific Manuscript database

Fuel ethanol production in the U.S. and elsewhere is an important and growing industry. In the U.S, about 40% of annual corn production is now converted into fuel ethanol. During co-product recovery, condensed distillers solubles (CDS) has to be mixed with distillers wet grains before drying due to ...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2012 CFR

2012-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2014 CFR

2014-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2013 CFR

2013-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... burning that fuel. Similarly, when your total heat input is greater than 50 percent distillate oil and...

Investigations for the Recycle of Pyroprocessed Uranium

NASA Astrophysics Data System (ADS)

Westphal, B. R.; Price, J. C.; Chambers, E. E.; Patterson, M. N.

Given the renewed interest in uranium from the pyroprocessing of used nuclear fuel in a molten salt system, the two biggest hurdles for marketing the uranium are radiation levels and transuranic content. A radiation level as low as possible is desired so that handling operations can be performed directly with the uranium. The transuranic content of the uranium will affect the subsequent waste streams generated and, thus also should be minimized. Although the pyroprocessing technology was originally developed without regard to radiation and transuranic levels, adaptations to the process have been considered. Process conditions have been varied during the distillation and casting cycles of the process with increasing temperature showing the largest effect on the reduction of radiation levels. Transuranic levels can be reduced significantly by incorporating a pre-step in the salt distillation operation to remove a majority of the salt prior to distillation.

Impact of 50% Alcohol to Jet Blends on Aviation Turbine Fuel Filtration and Coalescence

DTIC Science & Technology

2014-06-20

Aviation and Distillate Fuel, Naval Shipboard 4. Energy Institute, July 2002. EI 1581 5th Edition Specifications and Qualification Procedures For... Distillate Fuel, Naval Shipboard 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 50.0 0 50 100 150 200 250 300 350 400 Se di m en t C on ce nt ra...2000 - Distillation Initial (°C) 10% Recovered (°C) 20% Recovered (°C) 50% Recovered (°C) 90 % Recovered (°C) End Point (°C) Residue (volume

Experimental Study of Fuel Heating at Low Temperatures in a Wing Tank Model, Volume 1

NASA Technical Reports Server (NTRS)

Stockemer, F. J.

1981-01-01

Scale model fuel heating systems for use with aviation hydrocarbon fuel at low temperatures were investigated. The effectiveness of the heating systems in providing flowability and pumpability at extreme low temperature when some freezing of the fuel would otherwise occur is evaluated. The test tank simulated a section of an outer wing tank, and was chilled on the upper and lower surfaces. Turbine engine lubricating oil was heated, and recirculating fuel transferred the heat. Fuels included: a commercial Jet A; an intermediate freeze point distillate; a higher freeze point distillate blended according to Experimental Referee Broadened Specification guidelines; and a higher freeze point paraffinic distillate used in a preceding investigation. Each fuel was chilled to selected temperature to evaluate unpumpable solid formation (holdup). Tests simulating extreme cold weather flight, without heating, provided baseline fuel holdup data. Heating and recirculating fuel increased bulk temperature significantly; it had a relatively small effect on temperature near the bottom of the tank. Methods which increased penetration of heated fuel into the lower boundary layer improved the capability for reducing holdup.

Comparison of Selected EIA-782 Data With Other Data Sources

EIA Publications

2012-01-01

This article compares annual average prices reported from the EIA-782 survey series for residential No. 2 distillate, on-highway diesel fuel, retail regular motor gasoline, refiner No. 2 fuel oil for resale, refiner No. 2 diesel fuel for resale, refiner regular motor gasoline for resale, and refiner kerosene-type jet fuel for resale with annual average prices reported by other sources. In terms of volume, it compares EIA-782C Prime Supplier annual volumes for motor gasoline (all grades), distillate fuel oil, kerosene-type jet fuel and residual fuel oil with annual volumes from other sources.

Conversion of Dimethyl Ether to Branched Hydrocarbons Over Cu/BEA: the Roles of Lewis Acidic and Metallic Sites in H2 Incorporation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hensley, Jesse E.; Schaidle, Joshua A.; Ruddy, Daniel A.

2017-04-26

Conversion of biomass to fuels remains as one of the most promising approach to support our energy needs. It has been previously shown that the gasification of non-edible cellulosic biomass can be used to derive fuels like methanol and dimethyl ether (DME). However, the use of methanol and DME is limited due to the fact that they have low energy densities, poor lubricity and lower viscosity when compared to long-chain hydrocarbons. Increasing the blending percentage can also lead to undesired amounts of oxygenated molecules in the transportation fuel infrastructure, which restrict their applicability as jet or diesel fuels. Consequently, themore » petroleum-derived hydrocarbons remain as the main constituent of the middle-distillate based fuels. One way to increase the share of biofuels in middle-distillates is to use methanol/DME as building blocks for producing renewable, energy-dense hydrocarbons. One way to achieve this is by catalytically converting the DME and methanol to light olefins, followed by oligomerization to higher molecular weight premium alkanes, which can directly be used as kerosene/diesel fuels. Here, we report the catalytic dimerization of biomass-derived deoxygenated olefins into transportation fuel-range hydrocarbons under liquid-phase stirred-batch conditions. Specifically, the effect of operating conditions, such as reaction temperature, solvent-type, reaction duration and olefin-structure, on the conversion, selectivity and kinetics of dimerization of triptene (2,3,3-trimethyl-1-butene) were investigated. Triptene, as previously reported, is one of the major products of DME-homologation reaction over a BEA zeolite4. We show that triptene can be converted to high quality middle-distillates using a commercially available ion-exchange acid resin, Amberlyst-35 (dry) by the process of catalytic dimerization.« less

Direct liquefaction Proof-of-Concept facility. Final technical progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Comolli, A.G.; Lee, L.K.; Pradhan, V.R.

1995-08-01

This report presents the results of work which included extensive modifications to HRI`s existing 3 ton per day Process Development Unit (PDU) and completion of the first PDU run. The 58-day Run 1 demonstrated scale-up of the Catalytic Two-Stage Liquefaction (CTSL Process) on Illinois No. 6 coal to produce distillate liquid products at a rate of up to 5 barrels per to of moisture-ash-free coal. The Kerr McGee Rose-SR unit from Wilsonville was redesigned and installed next to the US Filter installation to allow a comparison of the two solids removal systems. Also included was a new enclosed reactor tower,more » upgraded computer controls and a data acquisition system, an alternate power supply, a newly refurbished reactor, an in-line hydrotreater, interstage sampling system, coal handling unit, a new ebullating pump, load cells and improved controls and remodeled preheaters. Distillate liquid yields of 5 barrels/ton of moisture ash free coal were achieved. Coal slurry recycle rates were reduced from the 2--2.5 to 1 ratio demonstrated at Wilsonville to as low as 0.9 to 1. Coal feed rates were increased during the test by 50% while maintaining process performance at a marginally higher reactor severity. Sulfur in the coal was reduced from 4 wt% to ca. 0.02 wt% sulfur in the clean distillate fuel product. More than 3,500 gallons of distillate fuels were collected for evaluation and upgrading studies. The ROSE-SR Process was operated for the first time with a pentane solvent in a steady-state model. The energy rejection of the ash concentrate was consistently below prior data, being as low as 12%, allowing improved liquid yields and recovery.« less

75 FR 62545 - Ferm Solutions, Inc.; Filing of Food Additive Petition (Animal Use); Virginiamycin

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-12

... fermentations with respect to its consequent presence in by-product distiller grains used as an animal feed or... processing aid in fuel- ethanol fermentations with respect to its consequent presence in by- product...

76 FR 22904 - Ferm Solutions, Inc.; Filing of Food Additive Petition (Animal Use); Erythromycin Thiocyanate

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-25

...-ethanol fermentations with respect to its consequent presence in byproduct distiller grains used as an... thiocyanate as an antimicrobial processing aid in fuel-ethanol fermentations with respect to its [[Page 22905...

APPLICATION OF CAPILLARY SUPERCRITICAL FLUID CHROMATOGRAPHY TO THE ANALYSIS OF A MIDDLE DISTILLATE FUEL

EPA Science Inventory

The paper describes the application of capillary supercritical fluid chromatography (SFC) to the analysis of a middle distillate fuel. Small diameter (50 micrometer i.d.) fused silica capillary columns coated with crosslinked 50% phenyl polymethylsiloxane provided high separation...

Changes in Composition and Phosphorus Profile during Dry Grind Process of Corn into Ethanol and DDGS

USDA-ARS?s Scientific Manuscript database

Demand for alternatives to fossil fuels has resulted in a dramatic increase in ethanol production from corn. Dry grind method has been a major process, resulting in a large volume of dried distiller grains with solubles (DDGS) as a co-product. The process consists of grinding, cooking, liquefactio...

Oxygen-Induced Cracking Distillation of Oil in the Continuous Flow Tank Reactor

ERIC Educational Resources Information Center

Shvets, Valeriy F.; Kozlovskiy, Roman A.; Luganskiy, Artur I.; Gorbunov, Andrey V.; Suchkov, Yuriy P.; Ushin, Nikolay S.; Cherepanov, Alexandr A.

2016-01-01

The article analyses problems of processing black oil fuel and addresses the possibility of increasing the depth of oil refining by a new processing scheme. The study examines various methods of increasing the depth of oil refining reveals their inadequacies and highlights a need to introduce a new method of processing atmospheric and vacuum…

Fuel oil and kerosene sales 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-09-27

This publication contains the 1994 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the sixth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA)for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1994 edition marks the 11th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Distillate and residual fuel oil sales continued to move in opposite directions during 1994. Distillate salesmore » rose for the third year in a row, due to a growing economy. Residual fuel oil sales, on the other hand, declined for the sixth year in a row, due to competitive natural gas prices, and a warmer heating season than in 1993. Distillate fuel oil sales increased 4.4 percent while residual fuel oil sales declined 1.6 percent. Kerosene sales decreased 1.4 percent in 1994.« less

Off-design analysis of a gas turbine powerplant augmented by steam injection using various fuels

NASA Technical Reports Server (NTRS)

Stochl, R. J.

1980-01-01

Results are compared using coal derived low and intermediate heating valve fuel gases and a conventional distillate. The results indicate that steam injection provides substantial increases in both power and efficiency within the available compressor surge margin. The results also indicate that these performance gains are relatively insensitive as to the type of fuel. Also, in a cogeneration application, steam injection could provide some degree of flexibility by varying the split between power and process steam.

Northeast Heating Fuel Market The, Assessment and Options

EIA Publications

2000-01-01

In response to the President's request, this study examines how the distillate fuel oil market (and related energy markets) in the Northeast behaved in the winter of 1999-2000, explains the role played by residential, commercial, industrial, and electricity generation sector consumers in distillate fuel oil markets and describes how that role is influenced by the structure of the energy markets in the Northeast

27 CFR 19.1002 - Prohibited uses, transfers, and withdrawals.

Code of Federal Regulations, 2010 CFR

2010-04-01

... person shall withdraw, use, sell, or otherwise dispose of distilled spirits (including fuel alcohol... withdraws, uses, sells or otherwise disposes of distilled spirits (including fuel alcohol) produced under... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Prohibited uses, transfers...

ANALYTICAL PROCEDURES FOR CHARACTERIZING UNREGULATED EMISSIONS FROM VEHICLES USING MIDDLE-DISTILLATE FUELS

EPA Science Inventory

This research program was initiated with the objective of developing, codifying and testing a group of chemical analytical methods for measuring toxic compounds in the exhaust of distillate-fueled engines (i.e. diesel, gas turbine, Stirling, or Rankin cycle powerplants). It is a ...

Reactive Distillation for Esterification of Bio-based Organic Acids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.

2008-09-23

The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scalemore » has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.« less

Fractional Multistage Hydrothermal Liquefaction of Biomass and Catalytic Conversion into Hydrocarbons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cortright, Randy; Rozmiarek, Robert; Dally, Brice

2017-08-31

The objective of this project was to develop an improved multistage process for the hydrothermal liquefaction (HTL) of biomass to serve as a new front-end, deconstruction process ideally suited to feed Virent’s well-proven catalytic technology, which is already being scaled up. This process produced water soluble, partially de-oxygenated intermediates that are ideally suited for catalytic finishing to fungible distillate hydrocarbons. Through this project, Virent, with its partners, demonstrated the conversion of pine wood chips to drop-in hydrocarbon distillate fuels using a multi-stage fractional conversion system that is integrated with Virent’s BioForming® process. The majority of work was in the liquefactionmore » task and included temperature scoping, solvent optimization, and separations.« less

Sterilization of fermentation vessels by ethanol/water mixtures

DOEpatents

Wyman, Charles E.

1999-02-09

A method for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process.

Fuel Oil and Kerosene Sales

EIA Publications

2016-01-01

Provides information, illustrations and state-level statistical data on end-use sales of kerosene; No.1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off-highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses.

Energy data report: prices and margins of No. 2 distillate fuel oil. Monthly report, January 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whatley, A.

1982-03-22

Data are presented on the average prices and gross margins for the refining, reselling, and retailing sectors of the No. 2 distillate fuel oil market. Data are tabulated on prices and sales volumes of No. 2 fuel oil and No. 2 diesel fuel for residential, industrial/commercial, institutional/utility, other ultimate consumer sales, and nonultimate consumer sales. A brief discussion of the sampling and estimation procedures used in this report appears in the appendix.

Energy data report: prices and margins of No. 2 distillate fuel oil. Monthly report, October 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whatley, A.

1982-12-20

Data are presented on the average prices and gross margins for the refining, reselling, and retailing sectors of the No. 2 distillate fuel oil market. Data are tabulated on prices and sales volumes of No. 2 fuel oil and No. 2 diesel fuel for residential, industrial/commercial, institutional/utility, other ultimate consumer sales, and nonultimate consumer sales. A brief discussion of the sampling and estimation procedures used in this report appears in the appendix.

Energy data report: prices and margins of No. 2 distillate fuel oil. Monthly report, November 1982

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whatley, A.

1983-01-18

Data are presented on the average prices and gross margins for the refining, reselling, and retailing sectors of the No. 2 distillate fuel oil market. Data are tabulated on prices and sales volumes of No. 2 fuel oil and No. 2 diesel fuel for residential, industrial/commercial, institutional/utility, other ultimate consumer sales, and nonultimate consumer sales. A brief discussion of the sampling and estimation procedures used in this report appears in the appendix.

Energy data report: prices and margins of No. 2 distillate fuel oil. Monthly report, December 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whatley, A.

1982-02-22

Data are presented on the average prices and gross margins for the refining, reselling, and retailing sectors of the No. 2 distillate fuel oil market. Data are tabulated on prices and sales volumes of No. 2 fuel oil and No. 2 diesel fuel for residential, industrial/commercial, institutional/utility, other ultimate consumer sales, and nonultimate consumer sales. A brief discussion of the sampling and estimation procedures used in this report appears in the appendix.

27 CFR 19.672 - Types of plants.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Types of plants. 19.672... OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.672 Types of plants. There are three types of alcohol fuel plants: Small plants, medium plants...

27 CFR 19.672 - Types of plants.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Types of plants. 19.672... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.672 Types of plants. There are three types of alcohol fuel plants: Small plants, medium plants...

27 CFR 19.720 - Reports.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Reports. 19.720 Section 19... TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Reports § 19.720 Reports. Each proprietor of an alcohol fuel plant must submit to the appropriate TTB officer an annual report of operations...

27 CFR 19.720 - Reports.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Reports. 19.720 Section 19... TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Reports § 19.720 Reports. Each proprietor of an alcohol fuel plant must submit to the appropriate TTB officer an annual report of operations...

Recycle of valuable products from oily cold rolling mill sludge

NASA Astrophysics Data System (ADS)

Liu, Bo; Zhang, Shen-gen; Tian, Jian-jun; Pan, De-an; Liu, Yang; Volinsky, Alex A.

2013-10-01

Oily cold rolling mill (CRM) sludge contains lots of iron and alloying elements along with plenty of hazardous organic components, which makes it as an attractive secondary source and an environmental contaminant at the same time. The compound methods of "vacuum distillation + oxidizing roasting" and "vacuum distillation + hydrogen reduction" were employed for the recycle of oily cold rolling mill sludge. First, the sludge was dynamically vacuum distilled in a rotating furnace at 50 r/min and 600°C for 3 h, which removed almost hazardous organic components, obtaining 89.2wt% ferrous resultant. Then, high purity ferric oxide powders (99.2wt%) and reduced iron powders (98.9wt%) were obtained when the distillation residues were oxidized and reduced, respectively. The distillation oil can be used for fuel or chemical feedstock, and the distillation gases can be collected and reused as a fuel.

Energy Efficient Hybrid Vapor Stripping-Vapor Permeation Process for Ethanol Recovery ad Dehydration

EPA Science Inventory

Distillation combined with molecular sieve dehydration is the current state of the art for fuel grade ethanol production from fermentation broths. To improve the sustainability of bioethanol production, energy efficient separation alternatives are needed, particularly for lower f...

Direct Coal -to-Liquids (CTL) for Jet Fuel Using Biomass-Derived Solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chauhan, Satya P.; Garbark, Daniel B.; Taha, Rachid

Battelle has demonstrated a novel and potentially breakthrough technology for a direct coal-to-liquids (CTL) process for producing jet fuel using biomass-derived coal solvents (bio-solvents). The Battelle process offers a significant reduction in capital and operating costs and a substantial reduction in greenhouse gas (GHG) emissions, without requiring carbon capture and storage (CCS). The results of the project are the advancement of three steps of the hybrid coal/biomass-to-jet fuel process to the technology readiness level (TRL) of 5. The project objectives were achieved over two phases. In Phase 1, all three major process steps were explored and refined at bench-scale, including:more » (1) biomass conversion to high hydrogen-donor bio-solvent; (2) coal dissolution in biomass-derived bio-solvent, without requiring molecular H 2, to produce a synthetic crude (syncrude); and (3) two-stage catalytic hydrotreating/hydrogenation of syncrude to jet fuel and other distillates. In Phase 2, all three subsystems of the CTL process were scaled up to a pre-pilot scale, and an economic analysis was carried out. A total of over 40 bio-solvents were identified and prepared. The most unique attribute of Battelle’s bio-solvents is their ability to provide much-needed hydrogen to liquefy coal and thus increase its hydrogen content so much that the resulting syncrude is liquid at room temperature. Based on the laboratory-scale testing with bituminous coals from Ohio and West Virginia, a total of 12 novel bio-solvent met the goal of greater than 80% coal solubility, with 8 bio-solvents being as good as or better than a well-known but expensive hydrogen-donor solvent, tetralin. The Battelle CTL process was then scaled up to 1 ton/day (1TPD) at a pre-pilot facility operated in Morgantown, WV. These tests were conducted, in part, to produce enough material for syncrude-upgrading testing. To convert the Battelle-CTL syncrude into a form suitable as a blending stock for jet turbine fuel, a two-step catalytic upgrading process was developed at laboratory scale and then demonstrated at pre-pilot scale facility in Pittsburg, PA. Several drums of distillate products were produced, which were then distilled into unblended (neat) synthetic jet fuel and diesel products for a detailed characterization. Based on a detailed characterization of the synthetic jet fuel, a 20% synthetic, 80% commercial jet fuel blend was prepared, which met all specifications. An analysis of the synthetic diesel product showed that it has the promise of being a drop-in fuel as super-low (less than 15 ppm)-sulfur diesel fuel. A detailed economic analysis showed that the Battelle liquefaction process is economical at between 1000 metric tons/day (MT/day) and 2000 MT/day. The unit capital cost for Battelle CTL process for making jet fuel is 50K USD/daily bbl compared to 151K USD/daily bbl for indirect CTL, based on 2011 dollars. The jet-fuel selling cost at the refinery, including a 12% capital cost factor (which included profit), for the Battelle CTL process is 61USD/bbl (1.45 USD/gallon). This is competitive with crude oil price of 48 USD/bbl. At the same time, the GHG emissions of 3.56 MT CO 2/MT fuel were lower than the GHG emissions of 3.79 MT CO 2/MTfuel for petroleum-based fuels and 7.77 MT CO 2/MT fuel for indirect CTL. Thus, the use of bio-solvents completely eliminates the need for carbon capture in the case of Battelle CTL process. The superior economics and low GHG emissions for the Battelle CTL process has thus sparked worldwide interest and some potential commercialization opportunities are emerging.« less

Fuel oil and kerosene sales 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-08-01

The Fuel Oil and Kerosene Sales 1997 report provides information, illustrations and state-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. 24 tabs.

Tests of blending and correlation of distillate fuel properties

NASA Technical Reports Server (NTRS)

Erwin, J.; Bowden, J. N.

1982-01-01

The development of a fuel test matrix, results from tests of several blends of distillate aircraft fuels, and the use of correlations in formulation determination during a NASA-sponsored program to identify new aircraft fuels are described. The program was initiated in order to characterize fuel blends which are appropriate for different types of combustors in use and under development. The fuels were required to feature a specified range of properties. Attention is given to fuel volatility, hydrogen content, aromatic content, freezing point, kinematic viscosity, and naphthalene content. Paraffinic and naphtenic base stocks were employed, using alkyl benzene, naphthene benzenes, and naphthalenes to adjust the blend properties. Categories for the test fuels comprised source-controlled and composition controlled fuels. Test results and compositions of various fuels are provided.

The extraction and use of DDGS lipids for biodiesel production

USDA-ARS?s Scientific Manuscript database

The microbial fermentation process whereby fuel ethanol is produced does not destroy the acylglycerols resident in the fermentation feedstock. These lipids are contained in the thin stillage and Distillers Dried Grains with Solubles (DDGS) coproducts of fermentation. Recovery and conversion of the...

27 CFR 18.11 - Meaning of terms.

Code of Federal Regulations, 2013 CFR

2013-04-01

... under 27 CFR part 19, excluding alcohol fuel plants, for producing, warehousing, or processing distilled... unfermented mixture of juice, pulp, skins, and seeds prepared from fruit, berries, or grapes. High-proof..., exclusive of pulp, skins, or seeds. Person. An individual, trust, estate, partnership, association, company...

27 CFR 18.11 - Meaning of terms.

Code of Federal Regulations, 2014 CFR

2014-04-01

... under 27 CFR part 19, excluding alcohol fuel plants, for producing, warehousing, or processing distilled... unfermented mixture of juice, pulp, skins, and seeds prepared from fruit, berries, or grapes. High-proof..., exclusive of pulp, skins, or seeds. Person. An individual, trust, estate, partnership, association, company...

27 CFR 18.11 - Meaning of terms.

Code of Federal Regulations, 2010 CFR

2010-04-01

... under 27 CFR part 19, excluding alcohol fuel plants, for producing, warehousing, or processing distilled... unfermented mixture of juice, pulp, skins, and seeds prepared from fruit, berries, or grapes. High-proof..., exclusive of pulp, skins, or seeds. Person. An individual, trust, estate, partnership, association, company...

27 CFR 18.11 - Meaning of terms.

Code of Federal Regulations, 2011 CFR

2011-04-01

... under 27 CFR part 19, excluding alcohol fuel plants, for producing, warehousing, or processing distilled... unfermented mixture of juice, pulp, skins, and seeds prepared from fruit, berries, or grapes. High-proof..., exclusive of pulp, skins, or seeds. Person. An individual, trust, estate, partnership, association, company...

27 CFR 18.11 - Meaning of terms.

Code of Federal Regulations, 2012 CFR

2012-04-01

... under 27 CFR part 19, excluding alcohol fuel plants, for producing, warehousing, or processing distilled... unfermented mixture of juice, pulp, skins, and seeds prepared from fruit, berries, or grapes. High-proof..., exclusive of pulp, skins, or seeds. Person. An individual, trust, estate, partnership, association, company...

Sterilization of fermentation vessels by ethanol/water mixtures

DOEpatents

Wyman, C.E.

1999-02-09

A method is described for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process. 2 figs.

Design report small-scale fuel alcohol plant. Volume 2: Detailed construction information

NASA Astrophysics Data System (ADS)

1980-12-01

The objectives are to provide potential alcohol producers with a reference design and provide a complete, demonstrated design of a small scale fuel alcohol plant. The plant has the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention.

A reactive distillation process for the treatment of LiCl-KCl eutectic waste salt containing rare earth chlorides

NASA Astrophysics Data System (ADS)

Eun, H. C.; Choi, J. H.; Kim, N. Y.; Lee, T. K.; Han, S. Y.; Lee, K. R.; Park, H. S.; Ahn, D. H.

2016-11-01

The pyrochemical process, which recovers useful resources (U/TRU metals) from used nuclear fuel using an electrochemical method, generates LiCl-KCl eutectic waste salt containing radioactive rare earth chlorides (RECl3). It is necessary to develop a simple process for the treatment of LiCl-KCl eutectic waste salt in a hot-cell facility. For this reason, a reactive distillation process using a chemical agent was achieved as a method to separate rare earths from the LiCl-KCl waste salt. Before conducting the reactive distillation, thermodynamic equilibrium behaviors of the reactions between rare earth (Nd, La, Ce, Pr) chlorides and the chemical agent (K2CO3) were predicted using software. The addition of the chemical agent was determined to separate the rare earth chlorides into an oxide form using these equilibrium results. In the reactive distillation test, the rare earth chlorides in LiCl-KCl eutectic salt were decontaminated at a decontamination factor (DF) of more than 5000, and were mainly converted into oxide (Nd2O3, CeO2, La2O3, Pr2O3) or oxychloride (LaOCl, PrOCl) forms. The LiCl-KCl was purified into a form with a very low concentration (<1 ppm) for the rare earth chlorides.

Fate of virginiamycin through the fuel ethanol production process.

PubMed

Bischoff, Kenneth M; Zhang, Yanhong; Rich, Joseph O

2016-05-01

Antibiotics are frequently used to prevent and treat bacterial contamination of commercial fuel ethanol fermentations, but there is concern that antibiotic residues may persist in the distillers grains coproducts. A study to evaluate the fate of virginiamycin during the ethanol production process was conducted in the pilot plant facilities at the National Corn to Ethanol Research Center, Edwardsville, IL. Three 15,000-liter fermentor runs were performed: one with no antibiotic (F1), one dosed with 2 parts per million (ppm) of a commercial virginiamycin product (F2), and one dosed at 20 ppm of virginiamycin product (F3). Fermentor samples, distillers dried grains with solubles (DDGS), and process intermediates (whole stillage, thin stillage, syrup, and wet cake) were collected from each run and analyzed for virginiamycin M and virginiamycin S using a liquid chromatography-mass spectrometry method. Virginiamycin M was detected in all process intermediates of the F3 run. On a dry-weight basis, virginiamycin M concentrations decreased approximately 97 %, from 41 μg/g in the fermentor to 1.4 μg/g in the DDGS. Using a disc plate bioassay, antibiotic activity was detected in DDGS from both the F2 and F3 runs, with values of 0.69 μg virginiamycin equivalent/g sample and 8.9 μg/g, respectively. No antibiotic activity (<0.6 μg/g) was detected in any of the F1 samples or in the fermentor and process intermediate samples from the F2 run. These results demonstrate that low concentrations of biologically active antibiotic may persist in distillers grains coproducts produced from fermentations treated with virginiamycin.

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2014 CFR

2014-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

Thermogravimetric investigation of the co-combustion between the pyrolysis oil distillation residue and lignite.

PubMed

Li, Hao; Xia, Shuqian; Ma, Peisheng

2016-10-01

Co-combustion of lignite with distillation residue derived from rice straw pyrolysis oil was investigated by non-isothermal thermogravimetric analysis (TGA). The addition of distillation residue improved the reactivity and combustion efficiency of lignite, such as increasing the weight loss rate at peak temperature and decreasing the burnout temperature and the total burnout. With increasing distillation residue content in the blended fuels, the synergistic interactions between distillation residue and lignite firstly increased and then decreased during co-combustion stage. Results of XRF, FTIR, (13)C NMR and SEM analysis indicated that chemical structure, mineral components and morphology of samples have great influence on the synergistic interactions. The combustion mechanisms and kinetic parameters were calculated by the Coats Redfern model, suggesting that the lowest apparent activation energy (120.19kJ/mol) for the blended fuels was obtained by blending 60wt.% distillation residue during main co-combustion stage. Copyright © 2016 Elsevier Ltd. All rights reserved.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 2: Residual-fired nocogeneration process boiler

NASA Technical Reports Server (NTRS)

Knightly, W. F.

1980-01-01

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

NASA Technical Reports Server (NTRS)

Knightly, W. F.

1980-01-01

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuels consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section B

NASA Technical Reports Server (NTRS)

Knightly, W. F.

1980-01-01

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

Synthesis and analysis of jet fuel from shale oil and coal syncrudes

NASA Technical Reports Server (NTRS)

Gallagher, J. P.; Collins, T. A.; Nelson, T. J.; Pedersen, M. J.; Robison, M. G.; Wisinski, L. J.

1976-01-01

Thirty-two jet fuel samples of varying properties were produced from shale oil and coal syncrudes, and analyzed to assess their suitability for use. TOSCO II shale oil and H-COAL and COED syncrudes were used as starting materials. The processes used were among those commonly in use in petroleum processing-distillation, hydrogenation and catalytic hydrocracking. The processing conditions required to meet two levels of specifications regarding aromatic, hydrogen, sulfur and nitrogen contents at two yield levels were determined and found to be more demanding than normally required in petroleum processing. Analysis of the samples produced indicated that if the more stringent specifications of 13.5% hydrogen (min.) and 0.02% nitrogen (max.) were met, products similar in properties to conventional jet fuels were obtained. In general, shale oil was easier to process (catalyst deactivation was seen when processing coal syncrudes), consumed less hydrogen and yielded superior products. Based on these considerations, shale oil appears to be preferred to coal as a petroleum substitute for jet fuel production.

Measured and Predicted Vapor Liquid Equilibrium of Ethanol-Gasoline Fuels with Insight on the Influence of Azeotrope Interactions on Aromatic Species Enrichment and Particulate Matter Formation in Spark Ignition Engines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ratcliff, Matthew A; McCormick, Robert L; Burke, Stephen

A relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from direct injection spark ignition (DISI) vehicles. The fundamental cause of this observation is not well understood. One potential explanation is that increased evaporative cooling as a result of ethanol's high HOV may slow evaporation and prevent sufficient reactant mixing resulting in the combustion of localized fuel rich regions within the cylinder. In addition, it is well known that ethanol when blended in gasoline forms positive azeotropes which can alter the liquid/vapor composition during the vaporization process. In fact, it was shown recentlymore » through a numerical study that these interactions can retain the aromatic species within the liquid phase impeding the in-cylinder mixing of these compounds, which would accentuate PM formation upon combustion. To better understand the role of the azeotrope interactions on the vapor/liquid composition evolution of the fuel, distillations were performed using the Advanced Distillation Curve apparatus on carefully selected samples consisting of gasoline blended with ethanol and heavy aromatic and oxygenated compounds with varying vapor pressures, including cumene, p-cymene, 4-tertbutyl toluene, anisole, and 4-methyl anisole. Samples collected during the distillation indicate an enrichment of the heavy aromatic or oxygenated additive with an increase in initial ethanol concentration from E0 to E30. A recently developed distillation and droplet evaporation model is used to explore the influence of dilution effects versus azeotrope interactions on the aromatic species enrichment. The results suggest that HOV-cooling effects as well as aromatic species enrichment behaviors should be considered in future development of predictive indices to forecast the PM potential of fuels containing oxygenated compounds with comparatively high HOV.« less

Characterization of fast-pyrolysis bio-oil distillation residues and their potential applications

USDA-ARS?s Scientific Manuscript database

A typical petroleum refinery makes use of the vacuum gas oil by cracking the large molecular weight compounds into light fuel hydrocarbons. For various types of fast pyrolysis bio-oil, successful analogous methods for processing heavy fractions could expedite integration into a petroleum refinery fo...

40 CFR 1065.701 - General requirements for test fuels.

Code of Federal Regulations, 2010 CFR

2010-07-01

... procedure 1 Light distillate and light blends with residual ASTM D975-07b. Diesel Middle distillate ASTM D6985-04a. Biodiesel (B100) ASTM D6751-07b. Intermediate and residual fuel All See § 1065.705. Gasoline Motor vehicle gasoline ASTM D4814-07a. Minor oxygenated gasoline blends ASTM D4814-07a. Alcohol Ethanol...

Spray combustion modeling

NASA Technical Reports Server (NTRS)

Bellan, J.

1997-01-01

Concern over the future availability of high quality liquid fuels or use in furnaces and boilers prompted the U. S. Department of Energy (DOE) to consider alternate fuels as replacements for the high grade liquid fuels used in the 1970's and 1980's. Alternate fuels were defined to be combinations of a large percentage of viscous, low volatility fuels resulting from the low end of distillation mixed with a small percentage of relatively low viscosity, high volatility fuels yielded by the high end of distillation. The addition of high volatility fuels was meant to promote desirable characteristics to a fuel that would otherwise be difficult to atomize and burn and whose combustion would yield a high amount of pollutants. Several questions thus needed to be answered before alternate fuels became commercially viable. These questions were related to fuel atomization, evaporation, ignition, combustion and pollutant formation. This final report describes the results of the most significant studies on ignition and combustion of alternative fuels.

Process for converting cellulosic materials into fuels and chemicals

DOEpatents

Scott, Charles D.; Faison, Brendlyn D.; Davison, Brian H.; Woodward, Jonathan

1994-01-01

A process for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attritor and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system.

27 CFR 19.905 - Taxes.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Taxes. 19.905 Section 19.905 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use § 19.905 Taxes. Distilled spirits...

Subtask 3.9 - Direct Coal Liquefaction Process Development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aulich, Ted; Sharma, Ramesh

The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha middle distillate stream for upgrading and 2) a recycle stream was completed inmore » May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.« less

Fuels characterization studies. [jet fuels

NASA Technical Reports Server (NTRS)

Seng, G. T.; Antoine, A. C.; Flores, F. J.

1980-01-01

Current analytical techniques used in the characterization of broadened properties fuels are briefly described. Included are liquid chromatography, gas chromatography, and nuclear magnetic resonance spectroscopy. High performance liquid chromatographic ground-type methods development is being approached from several directions, including aromatic fraction standards development and the elimination of standards through removal or partial removal of the alkene and aromatic fractions or through the use of whole fuel refractive index values. More sensitive methods for alkene determinations using an ultraviolet-visible detector are also being pursued. Some of the more successful gas chromatographic physical property determinations for petroleum derived fuels are the distillation curve (simulated distillation), heat of combustion, hydrogen content, API gravity, viscosity, flash point, and (to a lesser extent) freezing point.

Refining and blending of aviation turbine fuels.

PubMed

White, R D

1999-02-01

Aviation turbine fuels (jet fuels) are similar to other petroleum products that have a boiling range of approximately 300F to 550F. Kerosene and No.1 grades of fuel oil, diesel fuel, and gas turbine oil share many similar physical and chemical properties with jet fuel. The similarity among these products should allow toxicology data on one material to be extrapolated to the others. Refineries in the USA manufacture jet fuel to meet industry standard specifications. Civilian aircraft primarily use Jet A or Jet A-1 fuel as defined by ASTM D 1655. Military aircraft use JP-5 or JP-8 fuel as defined by MIL-T-5624R or MIL-T-83133D respectively. The freezing point and flash point are the principle differences between the finished fuels. Common refinery processes that produce jet fuel include distillation, caustic treatment, hydrotreating, and hydrocracking. Each of these refining processes may be the final step to produce jet fuel. Sometimes blending of two or more of these refinery process streams are needed to produce jet fuel that meets the desired specifications. Chemical additives allowed for use in jet fuel are also defined in the product specifications. In many cases, the customer rather than the refinery will put additives into the fuel to meet their specific storage or flight condition requirements.

Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas – A Techno-Economic Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Yunhua; Jones, Susanne B.; Biddy, Mary J.

2012-08-01

This study reports the comparison of biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT) case, goal case, and conventional case, were compared in terms of performance and cost. The SOT case and goal case represent technology being developed at Pacific Northwest National Laboratory for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation (S2D process). The conventional case mirrors the two-step S2D process previously utilized and reported by Mobil using natural gas feedstock and consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. Analysis of the three cases revealedmore » that the goal case could indeed reduce fuel production cost over the conventional case, but that the SOT was still more expensive than the conventional. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield, single pass conversion efficiency, and reactor space velocity are the key factors driving the high cost for the SOT case.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eun, H.C.; Cho, Y.Z.; Choi, J.H.

A regeneration process of LiCl-KCl eutectic waste salt generated from the pyrochemical process of spent nuclear fuel has been studied. This regeneration process is composed of a chemical conversion process and a vacuum distillation process. Through the regeneration process, a high efficiency of renewable salt recovery can be obtained from the waste salt and rare earth nuclides in the waste salt can be separated as oxide or phosphate forms. Thus, the regeneration process can contribute greatly to a reduction of the waste volume and a creation of durable final waste forms. (authors)

Physical and chemical characterization of petroleum products by GC-MS.

PubMed

Mendez, A; Meneghini, R; Lubkowitz, J

2007-01-01

There is a need for reliable and fast means of monitoring refining, conversion, and upgrading processes aiming to increase the yield of light distillates, and thus, reducing the oil barrel bottoms. By simultaneously utilizing the FID and mass selective detectors while splitting the column effluent in a controlled way, it is possible to obtain identical gas chromatograms and total ion chromatograms from a single run. This means that besides the intensity vs. time graphs, the intensity vs. mass and boiling point can also be obtained. As a result, physical and chemical characterization can be performed in a simple and rapid manner. Experimental results on middle, heavy distillates, and crude oil fractions show clearly the effect of upgrading processes on the chemical composition and yields of diesel, jet fuels, and high vacuum gasoil fractions. The methodology is fully compliant with ASTM D-2887, D-7213, D-6352, and D7169 for simulated distillation and the previously mentioned mass spectrometry standards. The group type analysis correlated satisfactorily with high-performance liquid chromatography data.

FRACTIONAL DISTILLATION SEPARATION OF PLUTONIUM VALUES FROM LIGHT ELEMENT VALUES

DOEpatents

Cunningham, B.B.

1957-12-17

A process is described for removing light element impurities from plutonium. It has been found that plutonium contaminated with impurities may be purified by converting the plutonium to a halide and purifying the halide by a fractional distillation whereby impurities may be distilled from the plutonium halide. A particularly effective method includes the step of forming a lower halide such as the trior tetrahalide and distilling the halide under conditions such that no decomposition of the halide occurs. Molecular distillation methods are particularly suitable for this process. The apparatus may comprise an evaporation plate with means for heating it and a condenser surface with means for cooling it. The condenser surface is placed at a distance from the evaporating surface less than the mean free path of molecular travel of the material being distilled at the pressure and temperature used. The entire evaporating system is evacuated until the pressure is about 10/sup -4/ millimeters of mercury. A high temperuture method is presented for sealing porous materials such as carbon or graphite that may be used as a support or a moderator in a nuclear reactor. The carbon body is subjected to two surface heats simultaneously in an inert atmosphere; the surface to be sealed is heated to 1500 degrees centigrade; and another surface is heated to 300 degrees centigrade, whereupon the carbon vaporizes and flows to the cooler surface where it is deposited to seal that surface. This method may be used to seal a nuclear fuel in the carbon structure.

Process integration of crude oil distillation with technological and economic restrictions.

PubMed

Ulyev, Leonid; Vasiliev, Mikhail; Boldyryev, Stanislav

2018-09-15

The petrochemical industry is one of the most important industries in the world economy. In the largest oil-producing countries, more than half of GDP is generated by hydrocarbons production and refining. Reduction of oil prices and new environmental regulations are forcing petrochemical companies to improve their energy efficiency. Improvement of the energy efficiency of Crude oil distillation process at atmospheric vacuum distillation unit (AVDU) with a capacity of 3.3 million ton per year is considered in this paper. The amount of fuel spent for reprocessing of one ton of crude oil has been defined and it is 3.79 kg of natural gas. This paper shows the ways to achieve the objectives of retrofit in the context of administrative and technical restrictions. The retrofit goal was achieved by the retrofit of the heat exchange network, which allowed reducing gas consumption by 0.98 t/h (natural gas). The provided case studies show the pathway for efficient retrofit of crude oil distillation and most profitable ways for investment taking into account various administrative and technical constraints. The results of this work allow achieving reduction of energy consumption by 26%. Copyright © 2018 Elsevier Ltd. All rights reserved.

Literature survey of properties of synfuels derived from coal

NASA Technical Reports Server (NTRS)

Reynolds, T. W.; Niedzwiecki, R. W.; Clark, J. S.

1980-01-01

A literature survey of the properties of synfuels for ground-based gas turbine applications is presented. Four major concepts for converting coal into liquid fuels are described: solvent extraction, catalytic liquefaction, pyrolysis, and indirect liquefaction. Data on full range syncrudes, various distillate cuts, and upgraded products are presented for fuels derived from various processes, including H-coal, synthoil, solvent-refined coal, donor solvent, zinc chloride hydrocracking, co-steam, and flash pyrolysis. Some typical ranges of data for coal-derived low Btu gases are also presented.

Step enzymatic hydrolysis of sodium hydroxide-pretreated Chinese liquor distillers' grains for ethanol production.

PubMed

Liu, Yue-Hong; Wu, Zheng-Yun; Yang, Jian; Yuan, Yu-Ju; Zhang, Wen-Xue

2014-01-01

Distillers' grains are a co-product of ethanol production. In China, only a small portion of distillers' grains have been used to feed the livestock because the amount was so huge. Nowadays, it has been reported that the distillers' grains have the potential for fuel ethanol production because they are composed of lignocelluloses and residual starch. In order to effectively convert distillers' grains to fuel ethanol and other valuable production, sodium hydroxide pretreatment, step-by-step enzymatic hydrolysis, and simultaneous saccharification and fermentation (SSF) were investigated. The residual starch was first recycled from wet distillers' grains (WDG) with glucoamylase to obtain glucose-rich liquid. The total sugar concentration was 21.3 g/L, and 111.9% theoretical starch was hydrolyzed. Then the removed-starch dry distillers' grains (RDDG) were pretreated with NaOH under optimal conditions and the pretreated dry distillers' grains (PDDG) were used for xylanase hydrolysis. The xylose concentration was 19.4 g/L and 68.6% theoretical xylose was hydrolyzed. The cellulose-enriched dry distillers' grains (CDDG) obtained from xylanase hydrolysis were used in SSF for ethanol production. The ethanol concentration was 42.1 g/L and the ethanol productivity was 28.7 g/100 g CDDG. After the experiment, approximately 80.6% of the fermentable sugars in WDG was converted to ethanol.

Process for upgrading wax from Fischer-Tropsch synthesis

DOEpatents

Derr, Jr., W. Rodman; Garwood, William E.; Kuo, James C.; Leib, Tiberiu M.; Nace, Donald M.; Tabak, Samuel A.

1987-01-01

The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.

Methods to recover value-added co-products from dry grind processing of grains into fuel ethanol

USDA-ARS?s Scientific Manuscript database

Three methods were described to fractionate condensed distillers solubles (CDS) into several new co-products, including a protein-mineral fraction and a glycerol fraction by a chemical method; a protein fraction, an oil fraction and a glycerol-mineral fraction by a physical method; or a protein frac...

Fuel oil and kerosene sales 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-08-01

The Fuel Oil and Kerosene Sales 1996 report provides information, illustrations and State-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. The Petroleum Marketing Division, Office of Oil andmore » Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Fuel Oil and Kerosene Sales 1996. 24 tabs.« less

Fuel quality processing study, volume 1

NASA Astrophysics Data System (ADS)

Ohara, J. B.; Bela, A.; Jentz, N. E.; Syverson, H. T.; Klumpe, H. W.; Kessler, R. E.; Kotzot, H. T.; Loran, B. L.

1981-04-01

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

Fuel quality processing study, volume 1

NASA Technical Reports Server (NTRS)

Ohara, J. B.; Bela, A.; Jentz, N. E.; Syverson, H. T.; Klumpe, H. W.; Kessler, R. E.; Kotzot, H. T.; Loran, B. L.

1981-01-01

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

Weathering Patterns of Ignitable Liquids with the Advanced Distillation Curve Method

PubMed Central

Bruno, Thomas J; Allen, Samuel

2013-01-01

One can take advantage of the striking similarity of ignitable liquid vaporization (or weathering) patterns and the separation observed during distillation to predict the composition of residual compounds in fire debris. This is done with the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample fractions can be analyzed by any method that is appropriate. Analytical methods we have applied include gas chromatography (with flame ionization, mass spectrometric and sulfur chemiluminescence detection), thin layer chromatography, FTIR, Karl Fischer coulombic titrimetry, refractometry, corrosivity analysis, neutron activation analysis and cold neutron prompt gamma activation analysis. We have applied this method on product streams such as finished fuels (gasoline, diesel fuels, aviation fuels, rocket propellants), crude oils (including a crude oil made from swine manure) and waste oils streams (used automotive and transformer oils). In this paper, we present results on a variety of ignitable liquids that are not commodity fuels, chosen from the Ignitable Liquids Reference Collection (ILRC). These measurements are assembled into a preliminary database. From this selection, we discuss the significance and forensic application of the temperature data grid and the composition explicit data channel of the ADC. PMID:26401423

Weathering Patterns of Ignitable Liquids with the Advanced Distillation Curve Method.

PubMed

Bruno, Thomas J; Allen, Samuel

2013-01-01

One can take advantage of the striking similarity of ignitable liquid vaporization (or weathering) patterns and the separation observed during distillation to predict the composition of residual compounds in fire debris. This is done with the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample fractions can be analyzed by any method that is appropriate. Analytical methods we have applied include gas chromatography (with flame ionization, mass spectrometric and sulfur chemiluminescence detection), thin layer chromatography, FTIR, Karl Fischer coulombic titrimetry, refractometry, corrosivity analysis, neutron activation analysis and cold neutron prompt gamma activation analysis. We have applied this method on product streams such as finished fuels (gasoline, diesel fuels, aviation fuels, rocket propellants), crude oils (including a crude oil made from swine manure) and waste oils streams (used automotive and transformer oils). In this paper, we present results on a variety of ignitable liquids that are not commodity fuels, chosen from the Ignitable Liquids Reference Collection (ILRC). These measurements are assembled into a preliminary database. From this selection, we discuss the significance and forensic application of the temperature data grid and the composition explicit data channel of the ADC.

High performance liquid chromatographic hydrocarbon group-type analyses of mid-distillates employing fuel-derived fractions as standards

NASA Technical Reports Server (NTRS)

Seng, G. T.; Otterson, D. A.

1983-01-01

Two high performance liquid chromatographic (HPLC) methods have been developed for the determination of saturates, olefins and aromatics in petroleum and shale derived mid-distillate fuels. In one method the fuel to be analyzed is reacted with sulfuric acid, to remove a substantial portion of the aromatics, which provides a reacted fuel fraction for use in group type quantitation. The second involves the removal of a substantial portion of the saturates fraction from the HPLC system to permit the determination of olefin concentrations as low as 0.3 volume percent, and to improve the accuracy and precision of olefins determinations. Each method was evaluated using model compound mixtures and real fuel samples.

40 CFR 63.1561 - Am I subject to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... American Industry Classification (NAIC) code 32411, and used mainly for: (i) Producing transportation fuels (such as gasoline, diesel fuels, and jet fuels), heating fuels (such as kerosene, fuel gas distillate, and fuel oils), or lubricants; (ii) Separating petroleum; or (iii) Separating, cracking, reacting, or...

40 CFR 63.1561 - Am I subject to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... American Industry Classification (NAIC) code 32411, and used mainly for: (i) Producing transportation fuels (such as gasoline, diesel fuels, and jet fuels), heating fuels (such as kerosene, fuel gas distillate, and fuel oils), or lubricants; (ii) Separating petroleum; or (iii) Separating, cracking, reacting, or...

40 CFR 63.1561 - Am I subject to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... American Industry Classification (NAIC) code 32411, and used mainly for: (i) Producing transportation fuels (such as gasoline, diesel fuels, and jet fuels), heating fuels (such as kerosene, fuel gas distillate, and fuel oils), or lubricants; (ii) Separating petroleum; or (iii) Separating, cracking, reacting, or...

Process for converting cellulosic materials into fuels and chemicals

DOEpatents

Scott, C.D.; Faison, B.D.; Davison, B.H.; Woodward, J.

1994-09-20

A process is described for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attrition mill and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system. 1 fig.

Potential benefits of a ceramic thermal barrier coating on large power generation gas turbine

NASA Technical Reports Server (NTRS)

Clark, J. S.; Nainiger, J. J.

1977-01-01

Thermal barrier coating design option offers benefit in terms of reduced electricity costs when used in utility gas turbines. Options considered include: increased firing temperature, increased component life, reduced cooling air requirements, and increased corrosion resistance (resulting in increased tolerance for dirty fuels). Performance and cost data were obtained. Simple, recuperated and combined cycle applications were considered, and distillate and residual fuels were assumed. The results indicate that thermal barrier coatings could produce large electricity cost savings if these coatings permit turbine operation with residual fuels at distillate-rated firing temperatures. The results also show that increased turbine inlet temperature can result in substantial savings in fuel and capital costs.

Catalysts and process for liquid hydrocarbon fuel production

DOEpatents

White, Mark G.; Ranaweera, Samantha A.; Henry, William P.

2016-08-02

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality distillates, gasoline components, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel supported bimetallic ion complex catalyst for conversion, and provides methods of preparing such novel catalysts and use of the novel catalysts in the process and system of the invention.

Analysis and Environmental Fate of Air Force Distillate and High Density Fuels

DTIC Science & Technology

1981-10-01

728.1 128 0.8 Toluenc 751.3 92 0.6 XTHDCPD 1049.6 136 66.8 NTHDCPD 1079.2 136 1.5HNN 1509.6 186 20.1 JP-1O XTHDCPD 1050.3 136 96.8 ITHDCPD 1079.6 136 1,5...deionized water and the salts listed below. Blanks of both waters were routinely extracted and analyzed for possible 4.nterferences. MNN PXTX XTHDCPD ...through 13; complete data summaries for the distillate fuels may be found in Appendix C. All com- ponents of the high density fuels except XTHDCPD of

Problems Caused by Microbes and Treatment Strategies Downstream Petroleum Microbiology - An Industry Perspective

NASA Astrophysics Data System (ADS)

McFarlane, Elaine

In the mid 1800's it was discovered that crude oil could be extracted and exploited to produce energy. However, it was the invention of the first four-stroke internal combustion engine in 1876 that transformed the petroleum industry from a localised to a global business (Dell and Rand, 2004). Crude oil is made into useable products at the refinery via separation, conversion and treatment processes. Separation starts with distillation where the crude is evaporated and condensed into fractions based on their boiling ranges (Fig. 19.1). As well as carbon and hydrogen, the fractions consist of sulphur, nitrogen and oxygen (present in low concentrations) and metals like copper and iron (in trace amounts). After separation, heavy fractions are converted into lighter ones using intense heat, pressure and a catalyst to speed up chemical reactions. Molecules like sulphur can then be stripped out by heat treatment under pressure with hydrogen. Injection of refinery additives makes a finished fuel. For example, static dissipator is added to Automotive Gas Oil (AGO) to reduce the risk of spark and explosion during fuel movements; middle distillate flow improver to improve low temperature operability and lubricity improver to lubricate engine components. Finally, fuel quality measurements are made to ensure that the finished fuel meets the relevant specification.

Experimental Study on the Distillation Capacity of Alcohol-Gasoline Blends

NASA Astrophysics Data System (ADS)

Stan, C.; Andreescu, C.; Dobre, A.; Iozsa, D.

2017-10-01

The paper objective is to highlight the consequences of adding different alcohols in gasoline on the distillation characteristics of these blends. Changes of the distillation parameters (ti, t10, t50, t90, tf, E70, E100, E150) have been evaluated and, also, the evolution trends of the distillation curves for different alcohol added in mixture with the gasoline have been estimated. Several types of gasoline sold on the market and methanol, ethanol, i-propanol and butanol were used during the experiments and the corresponding distillation curves have been analyzed. The alcohol fraction in mixtures varied between 5 and 20%. Double blends with alcohol added in gasoline and triple blends with two alcohols added in gasoline were used. The comparison of the distillation curves of the mixtures was done with respect to that of pure gasoline. It was specified how the values of the distillation parameters, E70, E100 and E150, were set within the limits of EN 228. The distillation was made on 100 ml of fuel and the measurements were made on each 10 ml of fuel transformed into vapor state and then condensed. The influence of the alcohols present in these mixtures was manifested by the changes in the shape of the distillation curve. The butanol influence on the distillation temperatures was found lower than that of ethanol, because the physicochemical properties of the butanol are closer to those of gasoline. The molecules of alcohols actively interact with the fractions of gasolines, their combination leading to a conjugate effect and to a modifying the distillation parameters values. The variation of these parameters depends on the alcohol fraction in the mixture.

Changes in oil content, fatty acid composition, and functional lipid profiles during dry grind ethanol production from corn.

USDA-ARS?s Scientific Manuscript database

Demand for alternatives to fossil fuels has resulted in a dramatic increase in ethanol production from corn. The dry grind method has been the major process, resulting in a large volume of dried distiller grains with solubles (DDGS) as a co-product. This presentation reports our study to monitor ...

Process for upgrading wax from Fischer-Tropsch synthesis

DOEpatents

Derr, W.R. Jr.; Garwood, W.E.; Kuo, J.C.; Leib, T.M.; Nace, D.M.; Tabak, S.A.

1987-08-04

The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel. 2 figs.

Thermochemical Process Integration, Scale-Up, and Piloting | Bioenergy |

Science.gov Websites

; represented by spheres of hydrogen and carbon monoxide, then to "Gas Cleanup, Solids Removal, Reforming ; represented by a gasoline dispenser nozzle. A green arrow of "Fast Pyrolysis" and blue arrows for Distillation," and finally to "Fuels," represented by a gasoline dispenser nozzle Variety of

The development of the super-biodiesel production continuously from Sunan pecan oil through the process of reactive distillation

NASA Astrophysics Data System (ADS)

Yohana, Eflita; Yulianto, Moh. Endy; Ikhsan, Diyono; Nanta, Aditya Marga; Puspitasari, Ristiyanti

2016-06-01

In general, a vegetable oil-based biodiesel production commercially operates a batch process with high investments and operational costs. Thus, it is necessary to develop super-biodiesel production from sunan pecan oil continuously through the process of reactive distillation. There are four advantages of the reactive distillation process for the biodiesel production, as follows: (i) it incorporates the process of transesterification reaction, and product separation of residual reactants become one stage of the process, so it saves the investment and operation costs, (ii) it reduces the need for raw materials because the methanol needed corresponds to the stoichiometry, so it also reduces the operation costs, (iii) the holdup time in the column is relatively short (5±0,5 minutes) compared to the batch process (1-2 hours), so it will reduce the operational production costs, and (iv) it is able to shift the reaction equilibrium, because the products and reactants that do not react are instantly separated (based on Le Chatelier's principles) so the conversion will be increased. However, the very crucial problem is determining the design tools and process conditions in order to maximize the conversion of the transesterification reaction in both phases. Thus, the purpose of this research was to design a continuous reactive distillation process by using a recycled condensate to increase the productivity of the super-biodiesel from sunan pecan oil. The research was carried out in three stages including (i) designing and fabricating the reactive distillation equipment, (ii) testing the tool performance and the optimization of the biodiesel production, and (iii) biodiesel testing on the diesel engine. These three stages were needed in designing and scaling-up the process tools and the process operation commercially. The reactive distillation process tools were designed and manufactured with reference to the design system tower by Kitzer, et.al. (2008). The manufactured reactive distillation consisted of packing distillation columns equipped with a reboiler and condenser, with the prototype made of stainless steel material equipped with sigh glass. The filling column expands the contact of liquid-vapor phase so that the two reactants between methanol and oil would be converted into methyl ester and glycerol. The initial results of the study indicated that the relatively good condition is reached at the peak temperature and the base of the column of 62°C and 71°C with NaOH 2% of methanol weight as the catalyst at the feed ratio of methanol and the sunan pecan oil 4:1. The result of the performance test of the diesel engine indicated that the efficiency of the biodiesel fuel was achieved relatively good at 1.7% with 2500 rpm engine speed.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

NASA Technical Reports Server (NTRS)

Knightly, W. F.

1980-01-01

Various advanced energy conversion systems (ECS) are compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented for coal fired process boilers. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented.

40 CFR 1065.703 - Distillate diesel fuel.

Code of Federal Regulations, 2014 CFR

2014-07-01

... CONTROLS ENGINE-TESTING PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration... diesel fuel specified for use as a test fuel. See the standard-setting part to determine which grade to... grades are specified in the following table: Table 1 of § 1065.703—Test Fuel Specifications for...

40 CFR 94.108 - Test fuels.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Test fuels. 94.108 Section 94.108... EMISSIONS FROM MARINE COMPRESSION-IGNITION ENGINES Test Procedures § 94.108 Test fuels. (a) Distillate diesel test fuel. (1) The diesel fuels for testing Category 1 and Category 2 marine engines designed to...

40 CFR 1065.703 - Distillate diesel fuel.

Code of Federal Regulations, 2011 CFR

2011-07-01

... CONTROLS ENGINE-TESTING PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration... diesel fuel specified for use as a test fuel. See the standard-setting part to determine which grade to... inhibitor. (5) Pour depressant. (6) Dye. (7) Dispersant. (8) Biocide. Table 1 of § 1065.703—Test Fuel...

40 CFR 1065.703 - Distillate diesel fuel.

Code of Federal Regulations, 2013 CFR

2013-07-01

... CONTROLS ENGINE-TESTING PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration... diesel fuel specified for use as a test fuel. See the standard-setting part to determine which grade to... inhibitor. (5) Pour depressant. (6) Dye. (7) Dispersant. (8) Biocide. Table 1 of § 1065.703—Test Fuel...

40 CFR 94.108 - Test fuels.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Test fuels. 94.108 Section 94.108... EMISSIONS FROM MARINE COMPRESSION-IGNITION ENGINES Test Procedures § 94.108 Test fuels. (a) Distillate diesel test fuel. (1) The diesel fuels for testing Category 1 and Category 2 marine engines designed to...

40 CFR 1065.703 - Distillate diesel fuel.

Code of Federal Regulations, 2012 CFR

2012-07-01

... CONTROLS ENGINE-TESTING PROCEDURES Engine Fluids, Test Fuels, Analytical Gases and Other Calibration... diesel fuel specified for use as a test fuel. See the standard-setting part to determine which grade to... inhibitor. (5) Pour depressant. (6) Dye. (7) Dispersant. (8) Biocide. Table 1 of § 1065.703—Test Fuel...

40 CFR 94.108 - Test fuels.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Test fuels. 94.108 Section 94.108... EMISSIONS FROM MARINE COMPRESSION-IGNITION ENGINES Test Procedures § 94.108 Test fuels. (a) Distillate diesel test fuel. (1) The diesel fuels for testing Category 1 and Category 2 marine engines designed to...

16 CFR 317.2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-01-01

..., corporation, or other business entity. (e) Petroleum distillates means: (1) Jet fuels, including, but not limited to, all commercial and military specification jet fuels; and (2) Diesel fuels and fuel oils...) Wholesale means: (1) All purchases or sales of crude oil or jet fuel; and (2) All purchases or sales of...

16 CFR 317.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-01-01

..., corporation, or other business entity. (e) Petroleum distillates means: (1) Jet fuels, including, but not limited to, all commercial and military specification jet fuels; and (2) Diesel fuels and fuel oils...) Wholesale means: (1) All purchases or sales of crude oil or jet fuel; and (2) All purchases or sales of...

16 CFR 317.2 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-01-01

..., corporation, or other business entity. (e) Petroleum distillates means: (1) Jet fuels, including, but not limited to, all commercial and military specification jet fuels; and (2) Diesel fuels and fuel oils...) Wholesale means: (1) All purchases or sales of crude oil or jet fuel; and (2) All purchases or sales of...

16 CFR 317.2 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-01-01

..., corporation, or other business entity. (e) Petroleum distillates means: (1) Jet fuels, including, but not limited to, all commercial and military specification jet fuels; and (2) Diesel fuels and fuel oils...) Wholesale means: (1) All purchases or sales of crude oil or jet fuel; and (2) All purchases or sales of...

16 CFR 317.2 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-01-01

..., corporation, or other business entity. (e) Petroleum distillates means: (1) Jet fuels, including, but not limited to, all commercial and military specification jet fuels; and (2) Diesel fuels and fuel oils...) Wholesale means: (1) All purchases or sales of crude oil or jet fuel; and (2) All purchases or sales of...

Process Technology for Tunable Fischer Tropsch Synthesis Towards Middle Distillate Fuel Fractions

DTIC Science & Technology

2008-08-04

Catalyst Preparation (III) ● Incipient Wetness Used to impregnate Potassium Solution onto Iron (K / Fe atomic ratio = .02). Catalyst dried overnight at T...80oC then calcined for 1 hour at T = 350oC ● Incipient Wetness Used to impregnate Copper Solution onto Iron ( Cu / Fe atomic ratio = .01...Fischer Tropsch technologies that target the production of TP SBF through process, catalyst , and reactor improvements. Investigate Supercritical

40 CFR 94.108 - Test fuels.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) instead of or in addition to distillate diesel fuel (e.g., natural gas, methanol, or nondistillate diesel... Category 1 or Category 2 engines without exhaust aftertreatment obtained using a diesel fuel containing... Category 2 engines without exhaust aftertreatment obtained using diesel fuel containing less than 0.03...

40 CFR 94.108 - Test fuels.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) instead of or in addition to distillate diesel fuel (e.g., natural gas, methanol, or nondistillate diesel... Category 1 or Category 2 engines without exhaust aftertreatment obtained using a diesel fuel containing... Category 2 engines without exhaust aftertreatment obtained using diesel fuel containing less than 0.03...

40 CFR 60.17 - Incorporations by reference.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels, including Appendices X1 through... Specification for Diesel Fuel Oil, Biodiesel Blend (B6 to B20), including Appendices X1 through X3, (Approved...

Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oguejiofor, G.C.

Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phasemore » distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.« less

Refining and end use study of coal liquids I - pilot plant studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erwin, J.; Moulton, D.S.

1995-12-31

The Office of Fossil Energy, Pittsburgh Energy Technology Center is examining the ways in which coal liquids may best be integrated into the refinery of the 2000-2015 time frame and what performance and emission properties will prevail among the slate of fuels produced. The study consists of a Basic Program administered by Bechtel Group, Inc. to build a linear programming refinery model and provide processing and fuel properties data through subcontractors Southwest Research Institute, Amoco Oil R&D, and M.W. Kellogg Company. The model will be used in an Option 1 to devise a slate of test fuels meeting advanced specifications,more » which will be produced and tested for physical ASTM-type properties, engine performance, and vehicle emissions. Three coal liquids will be included: a direct liquid from bituminous coal, another from subbituminous, and a Fischer-Tropsch indirect liquefaction product. This paper reports the work to date on fractions of the first direct liquid including naphtha hydrotreating, heavy distillate hydrotreating, FCC of the heavy distillate hydrotreater products. Also reported are the first stages of work on the indirect liquefaction wax including feed preparation and FCC tests of blends with petroleum FCC feed.« less

Quality of Rapeseed Bio-Fuel Waste: Optical Properties

NASA Astrophysics Data System (ADS)

Sujak, Agnieszka; Muszyñski, Siemowit; Kachel-Jakubowska, Magdalena

2014-04-01

The objective of the presented work was to examine the optical properties of selected bio-fuel waste. Three independent optical methods: UV-Vis spectroscopy, infrared spectroscopy and chromametric measurements were applied to establish the possible quality control test for the obtained substances. The following by-products were tested: distilled glycerine, technical glycerine and matter organic non glycerine fraction from rapeseed oil bio-fuel production. The results show that analysis of UV-Vis spectra can give rapid information about the purity of distilled glycerine, while no direct information can be obtained concerning the concentration and kind of impurities. Transmission mode is more useful as compared to absorption, concerning the detection abilities of average UV-Vis spectrometers. Infrared spectroscopy can be used as a complementary method for determining impurities/admixtures in samples. Measurements of chroma give the quickest data to compare the colour of biofuel by-products obtained by different producers. The condition is, however, that the products are received through the same or similar chemical processes. The other important factor is application of well defined measuring background. All the discussed analyses are quick, cheap and non-destructive, and can help to compare the quality of products.

Reducing CO2 emissions and energy consumption of heat-integrated distillation systems.

PubMed

Gadalla, Mamdouh A; Olujic, Zarko; Jansens, Peter J; Jobson, Megan; Smith, Robin

2005-09-01

Distillation systems are energy and power intensive processes and contribute significantly to the greenhouse gases emissions (e.g. carbon dioxide). Reducing CO2 emissions is an absolute necessity and expensive challenge to the chemical process industries in orderto meetthe environmental targets as agreed in the Kyoto Protocol. A simple model for the calculation of CO2 emissions from heat-integrated distillation systems is introduced, considering typical process industry utility devices such as boilers, furnaces, and turbines. Furnaces and turbines consume large quantities of fuels to provide electricity and process heats. As a result, they produce considerable amounts of CO2 gas to the atmosphere. Boilers are necessary to supply steam for heating purposes; besides, they are also significant emissions contributors. The model is used in an optimization-based approach to optimize the process conditions of an existing crude oil atmospheric tower in order to reduce its CO2 emissions and energy demands. It is also applied to generate design options to reduce the emissions from a novel internally heat-integrated distillation column (HIDiC). A gas turbine can be integrated with these distillation systems for larger emissions reduction and further energy savings. Results show that existing crude oil installations can save up to 21% in energy and 22% in emissions, when the process conditions are optimized. Additionally, by integrating a gas turbine, the total emissions can be reduced further by 48%. Internal heat-integrated columns can be a good alternative to conventional heat pump and other energy intensive close boiling mixtures separations. Energy savings can reach up to 100% with respect to reboiler heat requirements. Emissions of these configurations are cut down by up to 83%, compared to conventional units, and by 36%, with respect to heat pump alternatives. Importantly, cost savings and more profit are gained in parallel to emissions minimization.

Simulation and Analysis of Isotope Separation System for Fusion Fuel Recovery System

NASA Astrophysics Data System (ADS)

Senevirathna, Bathiya; Gentile, Charles

2011-10-01

This paper presents results of a simulation of the Fuel Recovery System (FRS) for the Laser Inertial Fusion Engine (LIFE) reactor. The LIFE reaction will produce exhaust gases that will need to be recycled in the FRS along with xenon, the chamber's intervention gas. Solids and liquids will first be removed and then vapor traps are used to remove large gas molecules such as lead. The gas will be reacted with lithium at high temperatures to extract the hydrogen isotopes, protium, deuterium, and tritium in hydride form. The hydrogen isotopes will be recovered using a lithium blanket processing system already in place and this product will be sent to the Isotope Separation System (ISS). The ISS will be modeled in software to analyze its effectiveness. Aspen HYSYS was chosen for this purpose for its widespread use industrial gas processing systems. Reactants and corresponding chemical reactions had to be initialized in the software. The ISS primarily consists of four cryogenic distillation columns and these were modeled in HYSYS based on design requirements. Fractional compositions of the distillate and liquid products were analyzed and used to optimize the overall system.

40 CFR 49.125 - Rule for limiting the emissions of particulate matter.

Code of Federal Regulations, 2011 CFR

2011-07-01

... pollution sources? (1) Particulate matter emissions from a combustion source stack (except for wood-fired..., British thermal unit (Btu), coal, combustion source, distillate fuel oil, emission, fuel, fuel oil, gaseous fuel, heat input, incinerator, marine vessel, mobile sources, motor vehicle, nonroad engine...

27 CFR 19.990 - Redistillation of spirits or fuel alcohol received on the plant premises.

Code of Federal Regulations, 2010 CFR

2010-04-01

... or fuel alcohol received on the plant premises. 19.990 Section 19.990 Alcohol, Tobacco Products and... PLANTS Distilled Spirits For Fuel Use Redistillation § 19.990 Redistillation of spirits or fuel alcohol received on the plant premises. (a) Receipts for redistillation. Proprietors of alcohol fuel plants may...

40 CFR Table 3 to Subpart Ddddd of... - Work Practice Standards

Code of Federal Regulations, 2013 CFR

2013-07-01

...: natural gas, synthetic natural gas, propane, distillate oil, syngas, ultra-low sulfur diesel, fuel oil... start firing coal/solid fossil fuel, biomass/bio-based solids, heavy liquid fuel, or gas 2 (other) gases....While firing coal/solid fossil fuel, biomass/bio-based solids, heavy liquid fuel, or gas 2 (other) gases...

40 CFR Table 3 to Subpart Ddddd of... - Work Practice Standards

Code of Federal Regulations, 2014 CFR

2014-07-01

...: natural gas, synthetic natural gas, propane, distillate oil, syngas, ultra-low sulfur diesel, fuel oil... start firing coal/solid fossil fuel, biomass/bio-based solids, heavy liquid fuel, or gas 2 (other) gases....While firing coal/solid fossil fuel, biomass/bio-based solids, heavy liquid fuel, or gas 2 (other) gases...

Study on the Preparation Process and Influential Factors of Large Area Environment-friendly Molten Carbonate Fuel Cell Matrix

NASA Astrophysics Data System (ADS)

Zhang, Ruiyun; Xu, Shisen; Cheng, Jian; Wang, Hongjian; Ren, Yongqiang

2017-07-01

Low-cost and high-performance matrix materials used in mass production of molten carbonate fuel cell (MCFC) were prepared by automatic casting machine with α-LiAlO2 powder material synthesized by gel-solid method, and distilled water as solvent. The single cell was assembled for generating test, and the good performance of the matrix was verified. The paper analyzed the factors affecting aqueous tape casting matrix preparation, such as solvent content, dispersant content, milling time, blade height and casting machine running speed, providing a solid basis for the mass production of large area environment-friendly matrix used in molten carbonate fuel cell.

Proceedings of the 6. international conference on stability and handling of liquid fuels. Volume 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Giles, H.N.

Volume 2 of these proceedings contain 42 papers arranged under the following topical sections: Fuel blending and compatibility; Middle distillates; Microbiology; Alternative fuels; General topics (analytical methods, tank remediation, fuel additives, storage stability); and Poster presentations (analysis methods, oxidation kinetics, health problems).

27 CFR 19.986 - Record of dispositions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... Spirits § 19.986 Record of dispositions. (a) Fuel alcohol removed. For fuel alcohol removed from the plant... distilled spirits plant qualified under subpart G of this part or to another alcohol fuel plant, the...) Other dispositions. For spirits or fuel alcohol used or otherwise disposed of (e.g., lost, destroyed...

Distillation of granulated scrap tires in a pilot plant.

PubMed

López, Félix A; Centeno, Teresa A; Alguacil, Francisco José; Lobato, Belén

2011-06-15

This paper reports the pyrolytic treatment of granulated scrap tires (GST) in a pilot distillation unit at moderate temperature (550°C) and atmospheric pressure, to produce oil, char and gas products. Tire-derived oil is a complex mixture of organic C(5)-C(24) compounds, including a very large proportion of aromatic compounds. This oil has a high gross calorific value (∼ 43 MJ kg(-1)) and N and S contents of 0.4% and 0.6%, respectively, falling within the specifications of certain heating fuels. The distillation gas is composed of hydrocarbons; methane and n-butane are the most abundant, investing the distillation gas with a very high gross calorific value (∼ 68 MJ Nm(-3)). This gas is transformed into electric power by a co-generation turbine. The distillation char is mostly made of carbon but with significant inorganic impurities (∼ 12 wt%). The quality of the solid residue of the process is comparable to that of some commercial chars. The quantity of residual solids, and the qualities of the gas, liquid and solid fractions, are similar to those obtained by conventional pyrolytic treatments of waste tires. However, the simplicity of the proposed technology and its low investment costs make it a very attractive alternative. Copyright © 2011 Elsevier B.V. All rights reserved.

Effects of alternate fuels. Report No. 2. Analysis of basic refractories degraded by residual oil combustion products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei, G. C.; Tennery, V. J.

1978-02-01

Industrial conversion in the U.S. to alternate fuels from natural gas is presently under way and will accelerate rapidly as a result of gas curtailments and National policy considerations. Currently the prime alternate fuels are distillate and residual oils and coal. Conversion to residual oils or coal for high-temperature process heat applications is anticipated to result in accelerated refractory and insulation corrosion and degradation due to reactions between fuel impurities and the ceramic linings of high-temperature equipment. Understanding the nature of such reactions and identification of means for preventing or retarding them will be of considerable assistance to both refractorymore » manufacturers and users as well as a significant contribution to energy conservation.« less

Comparision on dynamic behavior of diesel spray and rapeseed oil spray in diesel engine

NASA Astrophysics Data System (ADS)

Sapit, Azwan; Azahari Razali, Mohd; Faisal Hushim, Mohd; Jaat, Norrizam; Nizam Mohammad, Akmal; Khalid, Amir

2017-04-01

Fuel-air mixing is important process in diesel combustion. It significantly affects the combustion and emission of diesel engine. Biomass fuel has high viscosity and high distillation temperature and may negatively affect the fuel-air mixing process. Thus, study on the spray development and atomization of this type of fuel is important. This study investigates the atomization characteristics and droplet dynamic behaviors of diesel engine spray fuelled by rapeseed oil (RO) and comparison to diesel fuel (GO). Optical observation of RO spray was carried out using shadowgraph photography technique. Single nano-spark photography technique was used to study the characteristics of the spray while dual nano-spark shadowgraph technique was used to study the spray droplet behavior. Using in-house image processing algorithm, the images were processed and the boundary condition of each spray was also studied. The results show that RO has very poor atomization due to the high viscosity nature of the fuel when compared to GO. This is in agreement with the results from spray droplet dynamic behavior studies that shows due to the high viscosity, the RO spray droplets are large in size and travel downward, with very little influence of entrainment effect due to its large kinematic energy.

27 CFR 19.967 - Additional security.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Additional security. 19.967 Section 19.967 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Construction...

Study of the effects of fuel composition and injection and combustion-system type and adjustment on exhaust emissions from light-duty diesels. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hare, C.T.

The project included measurement of emissions from four light-duty diesel automobiles operated on nine test fuels, and additional test work at non-standard (both advanced and retarded) injection timing using four of the nine fuels. The four test vehicles were a Mercedes 240D, Oldsmobile 5.7-liter, Peugeot 2.3-liter, and Volkswagen 1.6-liter, all 1982 models. Pre-identified fuel parameters intentionally varied among the test fuels included aromaticity, 10% distilled temperature, and 90% distilled temperature. Two steady-state test conditions (30 mph cruise and 56 BMEP/1700 rpm) were used. Visible smoke, dilute hydrocarbons, dilute CO/sub 2/, and dilute NO/sub x/ were measured continuously during all themore » tests, with key mode data tabulation for FTP (light-duty transient) cycles.« less

Unravelling the Chemical Complexity of Biomass Burning VOC Emissions via H3O+ ToF-CIMS: Separation of High- and Low-temperature Pyrolysis Products

NASA Astrophysics Data System (ADS)

Sekimoto, K.; Koss, A.; Gilman, J.; Selimovic, V.; Coggon, M.; Zarzana, K. J.; Yuan, B.; Lerner, B. M.; Brown, S. S.; Warneke, C.; Yokelson, R. J.; De Gouw, J. A.

2017-12-01

Biomass burning is a large source of volatile organic compounds (VOCs) and many other trace species to the atmosphere. These VOCs can act as precursors to formation of secondary pollutants such as ozone and fine particles, and some VOCs can also have direct effects on human and ecosystem health. Multiple different and complex processes take place in biomass burning, e.g., distillation, flaming, and smoldering combustion processes. In a given fire, most of these processes occur simultaneously, but the relative importance of each can change over the course of a fire. This gives rise to some of the variability in VOC emissions between different fires. To study gas-phase emissions from biomass burning, an H3O+ ToF-CIMS was deployed during the FIREX 2016 laboratory intensive at the US Forest Service Fire Sciences Laboratory in Missoula, Montana. This instrument has a fast time response and the measurements in stack burns show the varying gas-phase emissions as the mix of distillation, flaming, and smoldering varies. We used positive matrix factorization (PMF) to reduce and explain the observed chemical complexity in the gas phase. Despite the complexity and variability of emissions, we found that a solution including just two emission profiles explained on average 85% of the VOC emissions across 15 different fuel types including pines, firs, spruce, grass, shrubs, chaparrals, and wood wool. We identified the two profiles as resulting from high-temperature and low-temperature pyrolysis processes, and found that the profiles were remarkably similar (correlation coefficient r > 0.9) across nearly all the fuel types described above. Some of the remaining differences in VOC emission profiles between fuel types, and exceptions to the two-profile solution, can be explained by differences in the chemical composition of the fuels.

PROJECTIONS OF REGIONAL FUEL OIL AND NATURAL GAS PRICES

EPA Science Inventory

The report presents delivered regional oil and natural gas price forecasts for the industrial and electric utility sectors. Delivered energy price projections by Federal region through the year 2045 are provided for distillate fuel oil, residual fuel oil, and natural gas. Methodo...

A GUIDE TO FUEL PERFORMANCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

LITZKE,W.

2004-08-01

Heating oil, as its name implies, is intended for end use heating consumption as its primary application. But its identity in reference name and actual chemical properties may vary based on a number of factors. By name, heating oil is sometimes referred to as gas oil, diesel, No. 2 distillate (middle distillate), or light heating oil. Kerosene, also used as a burner fuel, is a No. 1 distillate. Due to the higher heat content and competitive price in most markets, No. 2 heating oil is primarily used in modern, pressure-atomized burners. Using No. 1 oil for heating has the advantagesmore » of better cold-flow properties, lower emissions, and better storage properties. Because it is not nearly as abundant in supply, it is often markedly more expensive than No. 2 heating oil. Given the advanced, low-firing rate burners in use today, the objective is for the fuel to be compatible and achieve combustion performance at the highest achievable efficiency of the heating systems--with minimal service requirements. Among the Oil heat industry's top priorities are improving reliability and reducing service costs associated with fuel performance. Poor fuel quality, fuel degradation, and contamination can cause burner shut-downs resulting in ''no-heat'' calls. Many of these unscheduled service calls are preventable with routine inspection of the fuel and the tank. This manual focuses on No. 2 heating oil--its performance, properties, sampling and testing. Its purpose is to provide the marketer, service manager and technician with the proper guidelines for inspecting the product, maintaining good fuel quality, and the best practices for proper storage. Up-to-date information is also provided on commercially available fuel additives, their appropriate use and limitations.« less

27 CFR 19.1001 - Consignee premises.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Consignee premises. 19.1001 Section 19.1001 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Uses, Withdrawals...

27 CFR 19.965 - Construction and equipment.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Construction and equipment. 19.965 Section 19.965 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Construction...

27 CFR 19.1006 - Other materials.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Other materials. 19.1006 Section 19.1006 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Materials for...

27 CFR 19.999 - Consignor premises.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Consignor premises. 19.999 Section 19.999 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Uses, Withdrawals and...

27 CFR 19.689 - Continuing partnerships.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Continuing partnerships. 19.689 Section 19.689 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Changes to Permit...

27 CFR 19.970 - Supervision of operations.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Supervision of operations..., DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Supervision § 19.970 Supervision of operations. The appropriate TTB officer may assign appropriate TTB officers to...

Fuel oil and kerosene sales, 1994 (for microcomputers). Data file

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1994-10-01

Annual petroleum marketing data are available on this diskette which contains statistics from the Fuel Oil and Kerosene Sales 1994 report. Included are annual sales data on petroleum volumes of kerosene, distillate fuel oil, and residual fuel oil by state. Annual historic data at the national level are provided in summary tables.

40 CFR 86.513 - Fuel and engine lubricant specifications.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Regulations for 1978 and Later New Motorcycles; Test Procedures § 86.513 Fuel and engine lubricant... of § 86.513—Gasoline Test Fuel Specifications Item Value Procedure 1 Distillation Range: 1. Initial... of § 86.513—Natural Gas Test Fuel Specifications Item Value 1 Methane, CH4 Minimum, 89.0 mole percent...

Cogeneration Technology Alternatives Study (CTAS). Volume 3: Industrial processes

NASA Technical Reports Server (NTRS)

Palmer, W. B.; Gerlaugh, H. E.; Priestley, R. R.

1980-01-01

Cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers is examined in terms of cost savings. The use of various advanced energy conversion systems are examined and compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the target energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules specified by NASA for determining performance and cost. Data and narrative descriptions of the industrial processes are given.

Development of a Fuel Lubricity Haze Test (FLHT) for Naval Applications

DTIC Science & Technology

2009-03-16

Protection Agency FLHT Fuel Lubricity Haze Tester FOA Fuel Oil Additive FSII Fuel System Icing Inhibitor (additive) FT Fisher Tropsch FY...Light Cycle Oil LSDF Low Sulfur Diesel Fuel MDFI Middle Distillate Flow Improver (additive) MIL-DTL Military Detail MSC Military Sealift...a chemical test for diesel fuel lubricity that included a base extraction, acidification, a back extraction, and analysis with gas chromatography

PRODUCTION OF PURIFIED URANIUM

DOEpatents

Burris, L. Jr.; Knighton, J.B.; Feder, H.M.

1960-01-26

A pyrometallurgical method for processing nuclear reactor fuel elements containing uranium and fission products and for reducing uranium compound; to metallic uranium is reported. If the material proccssed is essentially metallic uranium, it is dissolved in zinc, the sulution is cooled to crystallize UZn/sub 9/ , and the UZn/sub 9/ is distilled to obtain uranium free of fission products. If the material processed is a uranium compound, the sollvent is an alloy of zinc and magnesium and the remaining steps are the same.

Transportation Fuels Markets, Midwest and Rocky Mountain

EIA Publications

2017-01-01

A new study commissioned by the U.S. Energy Information Administration (EIA), finds that changes in North American energy markets over the past decade have strengthened the supply of transportation fuels including motor gasoline, distillates, and jet fuel in the Midwest and Rocky Mountain regions.

Conversion of microalgae to jet fuel: process design and simulation.

PubMed

Wang, Hui-Yuan; Bluck, David; Van Wie, Bernard J

2014-09-01

Microalgae's aquatic, non-edible, highly genetically modifiable nature and fast growth rate are considered ideal for biomass conversion to liquid fuels providing promise for future shortages in fossil fuels and for reducing greenhouse gas and pollutant emissions from combustion. We demonstrate adaptability of PRO/II software by simulating a microalgae photo-bio-reactor and thermolysis with fixed conversion isothermal reactors adding a heat exchanger for thermolysis. We model a cooling tower and gas floatation with zero-duty flash drums adding solids removal for floatation. Properties data are from PRO/II's thermodynamic data manager. Hydrotreating is analyzed within PRO/II's case study option, made subject to Jet B fuel constraints, and we determine an optimal 6.8% bioleum bypass ratio, 230°C hydrotreater temperature, and 20:1 bottoms to overhead distillation ratio. Process economic feasibility occurs if cheap CO2, H2O and nutrient resources are available, along with solar energy and energy from byproduct combustion, and hydrotreater H2 from product reforming. Copyright © 2014 Elsevier Ltd. All rights reserved.

27 CFR 19.747 - Other materials.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Other materials. 19.747... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Materials for Making Spirits Unfit for Beverage Use § 19.747 Other materials. If a proprietor wishes to use a material to...

27 CFR 19.917 - Powers of attorney.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Powers of attorney. 19.917 Section 19.917 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Permits § 19.917...

27 CFR 19.956 - Amount of bond.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Amount of bond. 19.956 Section 19.956 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Bonds § 19.956 Amount...

27 CFR 19.667 - Emergency variations from requirements.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Emergency variations from requirements. 19.667 Section 19.667 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use...

27 CFR 19.680 - Registration of stills.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Registration of stills. 19.680 Section 19.680 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit...

27 CFR 19.984 - Record of spirits received.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Record of spirits received. 19.984 Section 19.984 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Accounting for...

27 CFR 19.665 - Alternate methods or procedures.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Alternate methods or procedures. 19.665 Section 19.665 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use...

27 CFR 19.988 - Reports.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Reports. 19.988 Section 19.988 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Accounting for Spirits § 19.988...

27 CFR 19.901 - Scope of subpart.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Scope of subpart. 19.901 Section 19.901 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use § 19.901 Scope of...

27 CFR 19.904 - Emergency variations from requirements.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Emergency variations from requirements. 19.904 Section 19.904 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use § 19...

27 CFR 19.703 - Construction and equipment.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Construction and equipment. 19.703 Section 19.703 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Requirements for...

27 CFR 19.958 - Conditions of bond.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Conditions of bond. 19.958 Section 19.958 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Bonds § 19.958...

27 CFR 19.903 - Alternate methods or procedures.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Alternate methods or procedures. 19.903 Section 19.903 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use § 19...

27 CFR 19.747 - Other materials.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Other materials. 19.747... OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Materials for Making Spirits Unfit for Beverage Use § 19.747 Other materials. If a proprietor wishes to use a material to...

27 CFR 19.747 - Other materials.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Other materials. 19.747... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Materials for Making Spirits Unfit for Beverage Use § 19.747 Other materials. If a proprietor wishes to use a material to...

27 CFR 19.683 - Changes affecting permit applications.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Changes affecting permit applications. 19.683 Section 19.683 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use...

27 CFR 19.926 - Change in location.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Change in location. 19.926 Section 19.926 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Changes Affecting...

27 CFR 19.683 - Changes affecting permit applications.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Changes affecting permit applications. 19.683 Section 19.683 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use...

27 CFR 19.924 - Change in proprietorship.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Change in proprietorship. 19.924 Section 19.924 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Changes Affecting...

27 CFR 19.914 - Medium plants.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Medium plants. 19.914... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Permits § 19.914 Medium plants. Any person wishing to establish a medium plant shall make application for and obtain in...

27 CFR 19.915 - Large plants.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Large plants. 19.915... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Permits § 19.915 Large plants. Any person wishing to establish a large plant shall make application for and obtain an...

27 CFR 19.673 - Small plant permit applications.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Small plant permit... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.673 Small plant permit applications. (a) General. Any person wishing to establish a...

27 CFR 19.673 - Small plant permit applications.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Small plant permit... BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.673 Small plant permit applications. (a) General. Any person wishing to establish a...

27 CFR 19.676 - Large plant permit applications.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Large plant permit... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.676 Large plant permit applications. (a) General. Any person wishing to establish a...

27 CFR 19.912 - Small plants.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Small plants. 19.912... OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Permits § 19.912 Small plants. Persons wishing to establish a small plant shall apply for a permit as provided in this...

27 CFR 19.676 - Large plant permit applications.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Large plant permit... BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use Obtaining A Permit § 19.676 Large plant permit applications. (a) General. Any person wishing to establish a...

Methods to recover value-added coproducts from dry grind processing of grains into fuel ethanol.

PubMed

Liu, Keshun; Barrows, Frederic T

2013-07-31

Three methods are described to fractionate condensed distillers solubles (CDS) into several new coproducts, including a protein-mineral fraction and a glycerol fraction by a chemical method; a protein fraction, an oil fraction and a glycerol-mineral fraction by a physical method; or a protein fraction, an oil fraction, a mineral fraction, and a glycerol fraction by a physicochemical method. Processing factors (ethanol concentration and centrifuge force) were also investigated. Results show that the three methods separated CDS into different fractions, with each fraction enriched with one or more of the five components (protein, oil, ash, glycerol and other carbohydrates) and thus having different targeted end uses. Furthermore, because glycerol, a hygroscopic substance, was mostly shifted to the glycerol or glycerol-mineral fraction, the other fractions had much faster moisture reduction rates than CDS upon drying in a forced air oven at 60 °C. Thus, these methods could effectively solve the dewatering problem of CDS, allowing elimination of the current industrial practice of blending distiller wet grains with CDS for drying together and production of distiller dried grains as a standalone coproduct in addition to a few new fractions.

Bioethanol production from renewable sources as alternative valorization of waste of starting dates in south Algeria

NASA Astrophysics Data System (ADS)

Mehani, Insaf; Bouchekima, Bachir

2018-05-01

The necessary reduction and progressive consumption of fossil fuels, whose scarcity is inevitable, involves mobilizing a set of alternatives. Renewable energy, including bio energy is an alternative to the depletion of fossil fuels and a way to fight against the harmful effects of pollution that undergoes the environment. In Algeria, the conditioning units of dates generate significant quantities of waste arising from sorting deviations. This biomass, until then considered as a waste with high impact on the environment can be transformed into high value added product. It is possible to develop common dates of low commercial value, and put on the local and international market a new generation of products with high added values such as bio ethanol. Besides its use in chemical synthesis, bio ethanol can be blended with gasoline to produce a clean fuel while improving the octane. The objective of the present work is to study the feasibility and productivity of generating bio ethanol in laboratory from the transformation of common date using anaerobic fermentation and distillation processes. After an alcoholic fermentation of the substrate of the date using bakery yeast at 30°C for 72 h, the distilled and rectified date juice generated the highest ethanol 88° with acceptable productions.

Cogeneration Technology Alternatives Study (CTAS). Volume 5: Cogeneration systems results

NASA Technical Reports Server (NTRS)

Gerlaugh, H. E.; Hall, E. W.; Brown, D. H.; Priestley, R. R.; Knightly, W. F.

1980-01-01

The use of various advanced energy conversion systems is examined and compared with each other and with current technology systems for savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. The methodology and results of matching the cogeneration energy conversion systems to approximately 50 industrial processes are described. Results include fuel energy saved, levelized annual energy cost saved, return on investment, and operational factors relative to the noncogeneration base cases.

Protease digestion from wheat stillage within a dry grind ethanol facility.

PubMed

Bals, Bryan; Brehmer, Ben; Dale, Bruce; Sanders, Johan

2011-01-01

As the current starch based ethanol market increases at its rapid pace, finding new markets for the primary coproduct, distiller's grains, has gained considerable interest. One possibility is to isolate the protein-rich fraction for use as precursors to biochemicals and bioplastics, further decreasing fossil fuel consumption. This research focuses on enzymatic extraction of protein peptides from wheat heavy stillage using commercially available proteases. The energy saved due to this process ranged from ∼ 1.5 to 3.0 GJ/ton wheat stillage compared to fossil fuel-based chemicals. Using Protex 6L (Genencor), ∼ 57% of the protein in the stillage was soluble 24 h after protease addition at 0.1% w/w loading. Of these proteins, ∼ 32% were already soluble, indicating the importance of using wet heavy stillage as the feedstock rather than dried distiller's grains. Peptide size was less than 6 kDa. Further improvements in protein removal may be obtained through a fed batch addition of protease and improved protease cocktails. Copyright © 2011 American Institute of Chemical Engineers (AIChE).

Aviation spirit - past, present, and future

NASA Technical Reports Server (NTRS)

Dunstan, A E; Thole, F B

1923-01-01

The volatile fuel of the high-speed internal combustion engine has, in the past, consisted almost exclusively of the lighter distillates from crude petroleum. Alternative and supplementary fuels are discussed such as: tetraline, dekalin, alcohol, cyclo-hexenes.

Development of a test method for distillation of diesel-biodiesel-alcohols mixtures at reduced pressure

NASA Astrophysics Data System (ADS)

Niculescu, R.; Iosub, I.; Clenci, A.; Zaharia, C.; Iorga-Simăn, V.

2017-10-01

Increased environmental awareness and depletion of fossil petroleum resources are driving the automotive industry to seek out and use alternative fuels. For instance, the biofuel is a major renewable energy source to supplement declining fossil fuel resources. The addition of alcohols like methanol and ethanol is practical in biodiesel blends due to its miscibility with the pure biodiesel. Alcohols also improve physico-chemical properties of biodiesel blends, which lead to improved combustion efficiency. Proper volatility of fuels is critical to the operation of internal combustion engines with respect to both performance and emissions. Volatility may be characterised by various measurements, the most common of which are vapour pressure, distillation and the vapour/liquid ratio. The presence of ethanol or other oxygenates may affect these properties and, as a result, performance and emissions, as well. However, in the case of diesel-biodiesel-alcohols mixtures, the variance of component volatility makes difficult the analysis of the overall volatility. Thus, the paper presents an experimental method of distilling diesel-biodiesel-alcohols mixtures by adjusting the boiler pressure of an i-Fischer Dist equipment.

Pyrolytic product characteristics of biosludge from the wastewater treatment plant of a petrochemical industry.

PubMed

Lin, Kuo-Hsiung; Hsu, Hui-Tsung; Ko, Ya-Wen; Shieh, Zhu-Xin; Chiang, Hung-Lung

2009-11-15

Biosludge was produced from the wastewater treatment plant of a petrochemical industry. The element compositions of pyrolytic residues, CO, CO(2), NOx, SOx, total hydrocarbons and detailed volatile organic compounds of pyrolytic gas, and C, H, N, S content and compositions in biofuel were determined in this study. Generally, 75-80% water content in sludge cakes and about 65-70% weight of water vapor and volatile compounds were volatilized during the drying process. Propene, propane, 1-butene, n-butane, isobutene, toluene and benzene were the major volatile organic compounds (VOCs) of the pyrolytic gas, and the concentrations for most of the top 20 VOC species were greater than 5 ppm. C(5)-C(9) compounds contributed 60% by weight of biofuel; 4-hydroxy-4-methyl-2-pentanone was the highest species, accounting for 28-53% of biofuel at various pyrolytic temperatures. Based on the dried residues, there was 8.5-13% weight in pyrolytic residues, 62-82% weight in liquid products (water and crude oil) and 5.8-30% weight in the gas phase after pyrolytic processing at 500-800 degrees C. Finally, 1.5-2.5 wt% liquid fuel was produced after the distillation process. The pyrolytic residues could be reused, the pyrolytic liquid product could be used as a fuel after distillation, and the pyrolytic gas could be recycled in the pyrolytic process to achieve non-toxic discharge and reduce the cost of sludge disposal.

27 CFR 19.1000 - Reconsignment in transit.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Reconsignment in transit. 19.1000 Section 19.1000 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Uses, Withdrawals and Transfers § 19.1000...

27 CFR 19.674 - TTB action on small plant applications.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false TTB action on small plant applications. 19.674 Section 19.674 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits for Fuel Use...

Fuel/engine/airframe tradeoff study, phase 1

NASA Technical Reports Server (NTRS)

Peacock, A. T.

1980-01-01

The effects of broadening the specifications for JP-4 and JP-8 fueled on the performance and cost of all USAF aircraft presently using JP-4 as well as those expected to be introduced into the force structure by 1983 are investigated. Test results indicated that there was no impact on engine performance, turbine durability, and coking, however there was a small maintenance cost increase as a result of a small combustor life decrease. Using JP-4 as standard fuel will avoid the use of high demand middle distillate fuels and give producers flexibility. Extensive use of JP-8 in the United States will increase middle distillate demand and cause a slight increase in engine hot-section maintenance. It is also concluded that the maximum allowable freeze point of JP-4 or JP-8 cannot be increased without degrading system performance and safety as critical conditions are approached.

Distillate Fuel Trends: International Supply Variations and Alternate Fuel Properties

DTIC Science & Technology

2013-01-31

general trend toward a more uniform diesel around the world but the use of alternative fuels, such as biodiesel , has introduced additional variations...reduce sulfur; however, there are still areas with high sulfur, poor stability fuel. The primary source of alternate diesel fuel is Biodiesel , more...US FAME Fatty Acid Methyl Ester, aka Biodiesel FIA Fluorescent Indicator Adsorption FT SPK Fischer Tropsch derived Synthetic Paraffinic Kerosene

Comparative TEA for Indirect Liquefaction Pathways to Distillate-Range Fuels via Oxygenated Intermediates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tan, Eric; Snowden-Swan, Lesley J.; Talmadge, Michael

This paper presents a comparative techno-economic analysis of five conversion pathways from biomass to gasoline-, jet-, and diesel-range hydrocarbons via indirect liquefaction with specific focus on pathways utilizing oxygenated intermediates (derived either via thermochemical or biochemical conversion steps). The four emerging pathways of interest are compared with one conventional pathway (Fischer-Tropsch) for the production of the hydrocarbon blendstocks. The processing steps of the four emerging pathways include: biomass-to-syngas via indirect gasification, gas cleanup, conversion of syngas to alcohols/oxygenates, followed by conversion of alcohols/oxygenates to hydrocarbon blendstocks via dehydration, oligomerization, and hydrogenation. We show that the emerging pathways via oxygenated intermediatesmore » have the potential to be cost competitive with the conventional Fischer-Tropsch process. The evaluated pathways and the benchmark process generally exhibit similar fuel yields and carbon conversion efficiencies. The resulting minimum fuel selling prices are comparable to the benchmark at approximately $3.60 per gallon-gasoline equivalent, with potential for two new pathways to be more economically competitive. Additionally, the coproduct values can play an important role in the economics of the processes with oxygenated intermediates derived via syngas fermentation. Major cost drivers for the integrated processes are tied to achievable fuel yields and conversion efficiency of the intermediate steps, i.e., the production of oxygenates/alcohols from syngas and the conversion of oxygenates/alcohols to hydrocarbon fuels.« less

40 CFR 63.7575 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

.... Liquid fossil fuel means petroleum, distillate oil, residual oil and any form of liquid fuel derived from... primary purpose of recovering thermal energy in the form of steam or hot water. Waste heat boilers are... unit means a fossil fuel-fired combustion unit of more than 25 megawatts that serves a generator that...

40 CFR 63.7575 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

.... Liquid fossil fuel means petroleum, distillate oil, residual oil and any form of liquid fuel derived from... primary purpose of recovering thermal energy in the form of steam or hot water. Waste heat boilers are... unit means a fossil fuel-fired combustion unit of more than 25 megawatts that serves a generator that...

40 CFR 63.7575 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

.... Liquid fossil fuel means petroleum, distillate oil, residual oil and any form of liquid fuel derived from... primary purpose of recovering thermal energy in the form of steam or hot water. Waste heat boilers are... unit means a fossil fuel-fired combustion unit of more than 25 megawatts that serves a generator that...

27 CFR 19.734 - Consignor for in-bond shipments.

Code of Federal Regulations, 2011 CFR

2011-04-01

... Transfer of Spirits Between Alcohol Fuel Plants § 19.734 Consignor for in-bond shipments. A proprietor that ships distilled spirits in bond to another alcohol fuel plant is the “consignor” of the shipment. When... the alcohol fuel plant that will receive the spirits; and (5) The serial numbers of seals, locks, or...

Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags

USDA-ARS?s Scientific Manuscript database

Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture that consisted of saturated aliphatic paraffins (96.8%), aliphatic olefins (2.6%), and aromatics (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 182–2...

78 FR 37537 - CHS Inc., Federal Express Corporation, GROWMARK, Inc., HWRT Oil Company LLC, MFA Oil Company...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-21

... will no longer accept nominations for the transportation of jet fuel or distillates, violates the...., United Airlines, Inc., UPS Fuel Services, Inc. v. Enterprise TE Products Pipeline Company, LLC; Notice of... LLC; MFA Oil Company; Southwest Airline Co.; United Airlines, Inc.; and UPS Fuel Services, Inc...

18 CFR 281.304 - Computation of alternative fuel volume.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Computation of alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... not a diesel engine or turbine designed to use distillate fuels as the only substitute for natural gas...

18 CFR 281.304 - Computation of alternative fuel volume.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Computation of alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... not a diesel engine or turbine designed to use distillate fuels as the only substitute for natural gas...

18 CFR 281.304 - Computation of alternative fuel volume.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Computation of alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... not a diesel engine or turbine designed to use distillate fuels as the only substitute for natural gas...

18 CFR 281.304 - Computation of alternative fuel volume.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Computation of alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... not a diesel engine or turbine designed to use distillate fuels as the only substitute for natural gas...

18 CFR 281.304 - Computation of alternative fuel volume.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Computation of alternative fuel volume. 281.304 Section 281.304 Conservation of Power and Water Resources FEDERAL ENERGY... not a diesel engine or turbine designed to use distillate fuels as the only substitute for natural gas...

Airborne rotary separator study

NASA Astrophysics Data System (ADS)

Drnevich, R. F.; Nowobilski, J. J.

1992-12-01

Several air breathing propulsion concepts for future earth-to-orbit transport vehicles utilize air collection and enrichment, and subsequent storage of liquid oxygen for later use in the vehicle mission. Work performed during the 1960's established the feasibility of substantially reducing weight and volume of a distillation type air separator system by operating the distillation elements in high 'g' fields obtained by rotating the separator assembly. The purpose of this study was to evaluate various fuels and fuel combinations with the objective of minimizing the weight and increase the ready alert capability of the plane. Fuels will be used to provide energy as well as act as heat sinks for the on-board heat rejection system. Fuel energy was used to provide power for air separation as well as to produce refrigeration for liquefaction of oxygen enriched air, besides its primary purpose of vehicle propulsion. The heat generated in the cycle was rejected to the fuel and water which is also carried on board the vehicle.The fuels that were evaluated include JP4, methane, and hydrogen. Hydrogen served as a comparison to the JP4 and methane cases.

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids.

PubMed

Bruno, Thomas J; Ott, Lisa S; Lovestead, Tara M; Huber, Marcia L

2010-04-16

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The collected sample fractions can be analyzed by any method that is appropriate. The analytical methods we have applied include gas chromatography (with flame ionization, mass spectrometric and sulfur chemiluminescence detection), thin layer chromatography, FTIR, corrosivity analysis, neutron activation analysis and cold neutron prompt gamma activation analysis. By far, the most widely used analytical technique we have used with the ADC is gas chromatography. This has enabled us to study finished fuels (gasoline, diesel fuels, aviation fuels, rocket propellants), crude oils (including a crude oil made from swine manure) and waste oils streams (used automotive and transformer oils). In this special issue of the Journal of Chromatography, specifically dedicated to extraction technologies, we describe the essential features of the advanced distillation curve metrology as an analytical strategy for complex fluids. Published by Elsevier B.V.

Characteristics of bicyclic sesquiterpanes in crude oils and petroleum products.

PubMed

Yang, Chun; Wang, Zhendi; Hollebone, Bruce P; Brown, Carl E; Landriault, Mike

2009-05-15

This study presents a quantitative gas chromatography-mass spectrometry analysis of bicyclic sesquiterpanes (BSs) in numerous crude oils and refined petroleum products including light and mid-range distillate fuels, residual fuels, and lubricating oils collected from various sources. Ten commonly recognized bicyclic sesquiterpanes were determined in all the studied crude oils and diesel range fuels with principal dominance of BS3 (C(15)H(28)), BS5 (C(15)H(28)) and BS10 (C(16)H(30)), while they were generally not detected or in trace in light fuel oils like gasoline and kerosene and most lubricating oils. Laboratory distillation of crude oils demonstrated that sesquiterpanes were highly enriched in the medium distillation fractions of approximately 180 to 481 degrees C and were generally absent or very low in the light distillation fraction (boiling point to approximately 180 degrees C) and the heavy residual fraction (>481 degrees C). The effect of evaporative weathering on a series of diagnostic ratios of sesquiterpanes, n-alkanes, and biomarkers was evaluated with two suites of weathered oil samples. The change of abundance of sesquiterpanes was used to determine the extent of weathering of artificially evaporated crude oils and diesel. In addition to the pentacyclic biomarker C(29) and C(30) alphabeta-hopane, C(15) and C(16) sesquiterpanes might be alternative internal marker compounds to provide a direct way to estimate the depletion of oils, particularly diesels, in oil spill investigations. These findings may offer potential applications for both oil identification and oil-source correlation in cases where the tri- to pentacyclic biomarkers are absent due to refining or environmental weathering of oils.

Geographic Concentration of Oil Infrastructure: Issues and Options

DTIC Science & Technology

2007-03-24

their homes and plants , and destroy ports and refineries , thereby shattering the U.S. economy. The scope, scale, frequency and location of terrorist...for the above reasons. The corridor along the Mississippi River between Baton Rouge and New Orleans is home to six major refineries . These... refineries process more than 1.7 million barrels of oil per day to produce 775 thousand barrels of motor gasoline and 440 million barrels of distillate fuel

27 CFR 19.918 - Information already on file and supplemental information.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Information already on file and supplemental information. 19.918 Section 19.918 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX AND TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS DISTILLED SPIRITS PLANTS Distilled Spirits For Fuel Use Permits § 19.918...

40 CFR 80.46 - Measurement of reformulated gasoline fuel parameters.

Code of Federal Regulations, 2010 CFR

2010-07-01

...)−0.347 RVP kPa = (0.956 * X)−2.39 (d) Distillation. Distillation parameters must be determined using...)(3) of this section. (2) Beginning January 1, 2004, the sulfur content of butane must be determined... paragraph (a)(2) of this section: (i) ASTM standard method D 4468-85 (Reapproved 2000), “Standard Test...

Environmental assessment of used oil management methods.

PubMed

Boughton, Bob; Horvath, Arpad

2004-01-15

The 1 billion gal of used oil generated in the U.S. each year are managed in three primary ways: rerefined into base oil for reuse, distilled into marine diesel oil fuel, and marketed as untreated fuel oil. Management of used oil has local, regional and global impacts. Because of the globally distributed nature of fuel markets, used oil as fuel has localized and regional impacts in many areas. In this paper, the human health and environmental tradeoffs of the management options are quantified and characterized. The goal of this study was to assess and compare the environmental impacts and benefits of each management method in a product end-of-life scenario using a life-cycle assessment (LCA) approach. A life-cycle inventory showed that 800 mg of zinc and 30 mg of lead air emissions may result from the combustion of 1 L of used oil as fuel (50-100 times that of crude-derived fuel oils). As an example, up to 136 Mg of zinc and 5 Mg of lead air emissions may be generated from combustion of over 50 M gal of California-generated used oil each year. While occurring elsewhere, these levels are significant (of the same magnitude as reported total stationary source emissions in California). An impact assessment showed that heavy metals-related toxicity dominates the comparison of management methods. Zinc and lead emissions were the primary contributors to the terrestrial and human toxicity impact potentials that were calculated to be 150 and 5 times higher, respectively, for used oil combusted as fuel than for rerefining or distillation. Low profits and weak markets increasingly drive the used oil management method selection toward the untreated fuel oil market. Instead, both the rerefining and distillation methods and associated product markets should be strongly supported because they are environmentally preferable to the combustion of unprocessed used oil as fuel.

Modeling RP-1 Fuel Advanced Distillation Data using Comprehensive Two-Dimensional Gas Chromatography Coupled with Time-of-Flight Mass Spectrometry and Partial Least Squares Analysis

DTIC Science & Technology

2014-05-07

of a variety of complex liquid samples including, but not limited to, crude oil [12], gasoline [16], biodiesel fuel [17, 19], jet fuel [5, 10, 11...doi: 10.1021/ie302399v 19. Bruno TJ, Wolk A, Naydich A (2009) Stabilization of Biodiesel Fuel at Elevated Temperature with Hydrogen Donors

Sensitivities of Internal Combustion Automotive Engines to Variations in Fuel Properties

DOT National Transportation Integrated Search

1982-02-01

An assessment of the sensitivity of the automotive gasoline and diesel engines to variations in fuel properties has been made. The variables studied include H/C ratio, distillation range, aromatic content, ignition quality as determined by the octane...

The development of the new Eureka process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watari, R.; Shoji, Y.; Ishikawa, T.

1987-01-01

Fuji Oil and Chiyoda have jointly developed this new Eureka (ET-II) process. It utilizes the unique technology of the original Eureka process, such as the injection of superheated steam into the reaction atmosphere and the handling of pitch in a molten state. It also combines a cracking heater with a high conversion rate and a single flow type reactor. In comparison with the original Eureka process, the advantages offered by the ET-II process are: Lower capital investment; lower operating cost; higher yield of lighter distillates. The cracked oil products can also be processed in secondary upgrading processes and the pitchmore » can then be utilized as a form of pitch water slurry fuel.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dawson, F.N. Jr.

The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in themore » product mix, product quality, and economics.« less

Chevron: Refinery Identifies $4.4 Million in Annual Savings by Using Process Simulation Models to Perform Energy-Efficiency Assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2004-05-01

In an energy-efficiency study at its refinery near Salt Lake City, Utah, Chevron focused on light hydrocarbons processing. The company found it could recover hydrocarbons from its fuel gas system and sell them. By using process simulation models of special distillation columns and associated reboilers and condensers, Chevron could predict the performance of potential equipment configuration changes and process modifications. More than 25,000 MMBtu in natural gas could be saved annually if a debutanizer upgrade project and a new saturated gas plant project were completed. Together, these projects would save $4.4 million annually.

Dry halide method for separating the components of spent nuclear fuels

DOEpatents

Christian, Jerry Dale; Thomas, Thomas Russell; Kessinger, Glen F.

1998-01-01

The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission- and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200.degree. C. to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400.degree. C.; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164.degree. C. to 2.degree. C.; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic.

Dry halide method for separating the components of spent nuclear fuels

DOEpatents

Christian, J.D.; Thomas, T.R.; Kessinger, G.F.

1998-06-30

The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200 C to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400 C; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164 to 2 C; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic. 3 figs.

Survey of US fuel ethanol plants.

PubMed

Saunders, J A; Rosentrater, K A

2009-07-01

The ethanol industry is growing in response to increased consumer demands for fuel as well as the renewable fuel standard. Corn ethanol processing creates the following products: 1/3 ethanol, 1/3 distillers grains, and 1/3 carbon dioxide. As the production of ethanol increases so does the generation of its coproducts, and viable uses continually need to be developed. A survey was mailed to operational US ethanol plants to determine current practices. It inquired about processes, equipment used, end products, and desired future directions for coproducts. Results indicated that approximately one-third of plant managers surveyed expressed a willingness to alter current drying time and temperature if it could result in a higher quality coproduct. Other managers indicated hesitation, based on lack of economic incentives, potential cost and return, and capital required. Respondents also reported the desire to use their coproducts in some of the following products: fuels, extrusion, pellets, plastics, and human food applications. These results provide a snapshot of the industry, and indicate that operational changes to the current production of DDGS must be based upon the potential for positive economic returns.

Essential oils and distilled straws of lavender and lavandin: a review of current use and potential application in white biotechnology.

PubMed

Lesage-Meessen, Laurence; Bou, Marine; Sigoillot, Jean-Claude; Faulds, Craig B; Lomascolo, Anne

2015-04-01

The Lavandula genus, which includes lavender (Lavandula angustifolia) and lavandin (L. angustifolia × Lavandula latifolia), is cultivated worldwide for its essential oils, which find applications in perfumes, cosmetics, food processing and, more recently, in aromatherapy products. The chemical composition of lavender and lavandin essential oils, usually produced by steam distillation from the flowering stems, is characterized by the presence of terpenes (e.g. linalool and linalyl acetate) and terpenoids (e.g. 1,8-cineole), which are mainly responsible for their characteristic flavour and their biological and therapeutic properties. Lavender and lavandin distilled straws, the by-products of oil extraction, were traditionally used for soil replenishment or converted to a fuel source. They are mineral- and carbon-rich plant residues and, therefore, a cheap, readily available source of valuable substances of industrial interest, especially aroma and antioxidants (e.g. terpenoids, lactones and phenolic compounds including coumarin, herniarin, α-bisabolol, rosmarinic and chlorogenic acids). Accordingly, recent studies have emphasized the possible uses of lavender and lavandin straws in fermentative or enzymatic processes involving various microorganisms, especially filamentous fungi, for the production of antimicrobials, antioxidants and other bioproducts with pharmaceutical and cosmetic activities, opening up new challenging perspectives in white biotechnology applications.

Techno-economic analysis of extraction-based separation systems for acetone, butanol, and ethanol recovery and purification.

PubMed

Grisales Díaz, Víctor Hugo; Olivar Tost, Gerard

2017-01-01

Dual extraction, high-temperature extraction, mixture extraction, and oleyl alcohol extraction have been proposed in the literature for acetone, butanol, and ethanol (ABE) production. However, energy and economic evaluation under similar assumptions of extraction-based separation systems are necessary. Hence, the new process proposed in this work, direct steam distillation (DSD), for regeneration of high-boiling extractants was compared with several extraction-based separation systems. The evaluation was performed under similar assumptions through simulation in Aspen Plus V7.3 ® software. Two end distillation systems (number of non-ideal stages between 70 and 80) were studied. Heat integration and vacuum operation of some units were proposed reducing the energy requirements. Energy requirement of hybrid processes, substrate concentration of 200 g/l, was between 6.4 and 8.3 MJ-fuel/kg-ABE. The minimum energy requirements of extraction-based separation systems, feeding a water concentration in the substrate equivalent to extractant selectivity, and ideal assumptions were between 2.6 and 3.5 MJ-fuel/kg-ABE, respectively. The efficiencies of recovery systems for baseline case and ideal evaluation were 0.53-0.57 and 0.81-0.84, respectively. The main advantages of DSD were the operation of the regeneration column at atmospheric pressure, the utilization of low-pressure steam, and the low energy requirements of preheating. The in situ recovery processes, DSD, and mixture extraction with conventional regeneration were the approaches with the lowest energy requirements and total annualized costs.

40 CFR 86.307-82 - Fuel specifications.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.307-82..., research, minimum D2699 100 96 PB (organic), grams/U.S. gallon 1 1.4 0.00-0.05 Distillation Range: IBP, °F...

40 CFR 86.307-82 - Fuel specifications.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.307-82..., research, minimum D2699 100 96 PB (organic), grams/U.S. gallon 1 1.4 0.00-0.05 Distillation Range: IBP, °F...

40 CFR 86.307-82 - Fuel specifications.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.307-82..., research, minimum D2699 100 96 PB (organic), grams/U.S. gallon 1 1.4 0.00-0.05 Distillation Range: IBP, °F...

40 CFR 86.307-82 - Fuel specifications.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for New Gasoline-Fueled and Diesel-Fueled Heavy-Duty Engines; Gaseous Exhaust Test Procedures § 86.307-82..., research, minimum D2699 100 96 PB (organic), grams/U.S. gallon 1 1.4 0.00-0.05 Distillation Range: IBP, °F...

Short-Term Energy Outlook Model Documentation: Petroleum Products Supply Module

EIA Publications

2013-01-01

The Petroleum Products Supply Module of the Short-Term Energy Outlook (STEO) model provides forecasts of petroleum refinery inputs (crude oil, unfinished oils, pentanes plus, liquefied petroleum gas, motor gasoline blending components, and aviation gasoline blending components) and refinery outputs (motor gasoline, jet fuel, distillate fuel, residual fuel, liquefied petroleum gas, and other petroleum products).

Characterization of upgraded fast pyrolysis oak oil distillate fractions from sulfided and non-sulfided catalytic hydrotreating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Olarte, Mariefel V.; Padmaperuma, Asanga B.; Ferrell, Jack R.

Catalytic hydroprocessing of pyrolysis oils from biomass produces hydrocarbons that can be considered for liquid fuel production. This process requires removal of oxygen and cracking of the heavier molecular weight bio-oil constituents into smaller fragments at high temperatures and pressures under hydrogen. A comprehensive understanding of product oils is useful to optimize cost versus degree of deoxygenation. Additionally, a better understanding of the chemical composition of the distillate fractions can open up other uses of upgraded oils for potentially higher-value chemical streams. We present in this paper the characterization data for five well-defined distillate fractions of two hydroprocessed oils withmore » different oxygen levels: a low oxygen content (LOC, 1.8% O, wet basis) oil and a medium oxygen content (MOC, 6.4% O, wet basis) oil. Elemental analysis and 13C NMR results suggest that the distillate fractions become more aromatic/unsaturated as they become heavier. Our results also show that the use of sulfided catalysts directly affects the S content of the lightest distillate fraction. Carbonyl and carboxylic groups were found in the MOC light fractions, while phenols were present in the heavier fractions for both MOC and LOC. PIONA analysis of the light LOC fraction shows a predominance of paraffins with a minor amount of olefins. These results can be used to direct future research on refinery integration and production of value-added product from specific upgraded oil streams.« less

Low NOx Heavy Fuel Combustor Concept Program

NASA Technical Reports Server (NTRS)

Novick, A. S.; Troth, D. L.

1981-01-01

The development of the technology required to operate an industrial gas turbine combustion system on minimally processed, heavy petroleum or residual fuels having high levels of fuel-bound nitrogen (FBN) while producing acceptable levels of exhaust emissions is discussed. Three combustor concepts were designed and fabricated. Three fuels were supplied for the combustor test demonstrations: a typical middle distillate fuel, a heavy residual fuel, and a synthetic coal-derived fuel. The primary concept was an air staged, variable-geometry combustor designed to produce low emissions from fuels having high levels of FBN. This combustor used a long residence time, fuel-rich primary combustion zone followed by a quick-quench air mixer to rapidly dilute the fuel rich products for the fuel-lean final burnout of the fuel. This combustor, called the rich quench lean (RQL) combustor, was extensively tested using each fuel over the entire power range of the model 570 K engine. Also, a series of parameteric tests was conducted to determine the combustor's sensitivity to rich-zone equivalence ratio, lean-zone equivalence ratio, rich-zone residence time, and overall system pressure drop. Minimum nitrogen oxide emissions were measured at 50 to 55 ppmv at maximum continuous power for all three fuels. Smoke was less than a 10 SAE smoke number.

Deep Desulfurization of Extensively Hydrodesulfurized Middle Distillate Oil by Rhodococcus sp. Strain ECRD-1

PubMed Central

Grossman, M. J.; Lee, M. K.; Prince, R. C.; Minak-Bernero, V.; George, G. N.; Pickering, I. J.

2001-01-01

Dibenzothiophene (DBT), and in particular substituted DBTs, are resistant to hydrodesulfurization (HDS) and can persist in fuels even after aggressive HDS treatment. Treatment by Rhodococcus sp. strain ECRD-1 of a middle distillate oil whose sulfur content was virtually all substituted DBTs produced extensive desulfurization and a sulfur level of 56 ppm. PMID:11282654

Isolation of high purity americium metal via distillation

NASA Astrophysics Data System (ADS)

Squires, Leah N.; King, James A.; Fielding, Randall S.; Lessing, Paul

2018-03-01

Pure americium metal is a crucial component for the fabrication of transmutation fuels. Unfortunately, americium in pure metal form is not available; however, a number of mixed metals and mixed oxides that include americium are available. In this manuscript a method is described to obtain high purity americium metal from a mixture of americium and neptunium metals with lead impurity via distillation.

Modeling RP-1 fuel advanced distillation data using comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry and partial least squares analysis.

PubMed

Kehimkar, Benjamin; Parsons, Brendon A; Hoggard, Jamin C; Billingsley, Matthew C; Bruno, Thomas J; Synovec, Robert E

2015-01-01

Recent efforts in predicting rocket propulsion (RP-1) fuel performance through modeling put greater emphasis on obtaining detailed and accurate fuel properties, as well as elucidating the relationships between fuel compositions and their properties. Herein, we study multidimensional chromatographic data obtained by comprehensive two-dimensional gas chromatography combined with time-of-flight mass spectrometry (GC × GC-TOFMS) to analyze RP-1 fuels. For GC × GC separations, RTX-Wax (polar stationary phase) and RTX-1 (non-polar stationary phase) columns were implemented for the primary and secondary dimensions, respectively, to separate the chemical compound classes (alkanes, cycloalkanes, aromatics, etc.), providing a significant level of chemical compositional information. The GC × GC-TOFMS data were analyzed using partial least squares regression (PLS) chemometric analysis to model and predict advanced distillation curve (ADC) data for ten RP-1 fuels that were previously analyzed using the ADC method. The PLS modeling provides insight into the chemical species that impact the ADC data. The PLS modeling correlates compositional information found in the GC × GC-TOFMS chromatograms of each RP-1 fuel, and their respective ADC, and allows prediction of the ADC for each RP-1 fuel with good precision and accuracy. The root-mean-square error of calibration (RMSEC) ranged from 0.1 to 0.5 °C, and was typically below ∼0.2 °C, for the PLS calibration of the ADC modeling with GC × GC-TOFMS data, indicating a good fit of the model to the calibration data. Likewise, the predictive power of the overall method via PLS modeling was assessed using leave-one-out cross-validation (LOOCV) yielding root-mean-square error of cross-validation (RMSECV) ranging from 1.4 to 2.6 °C, and was typically below ∼2.0 °C, at each % distilled measurement point during the ADC analysis.

Laboratory Evaluation of Light Obscuration Particle Counters used to Establish use Limits for Aviation Fuel

DTIC Science & Technology

2015-12-01

markings are indicated, follow agency authorization procedures , e.g. RD/FRD, PROPIN, ITAR, etc. Include copyright information. 13. SUPPLEMENTARY...Contamination in Distillate Fuels (Visual Inspection Procedures ), as a final check of fuel to ensure aviation fuel is clear and bright before flight...Laboratories at the Detroit Arsenal. The online procedure for evaluating the light obscuration particle counters was modified from the concepts found

Thermo-chemical extraction of fuel oil from waste lubricating grease.

PubMed

Pilusa, Tsietsi Jefrey; Muzenda, Edison; Shukla, Mukul

2013-06-01

This study investigated the recovery of oil from waste grease through the process of thermal degradation in an aqueous solution of potassium hydroxide (KOH) followed by solvent extraction. Waste high temperature metal bearing grease was dissolved in a 15 w/w% KOH solution at 80°C while being agitated at 2000 rpm using a shear action agitator for a period of 15 min. Two distinct layers were observed after 8 min of settling time. The top layer being of dark brown oil and the bottom layer was a heterogeneous mixture. The two layers were separated by decantation. The bottom layer was cooled down to 45°C followed by slow addition of toluene (C7H8) while agitating at 1200 rpm for 15 min to prevent solids settling and minimise rapid volatilisation of the organic compounds in the mixture. Two distinct layers were also formed, the top homogeneous mixture of light brown oil-toluene mixture and the bottom sludge layer. The solvent was recovered from the oil for re-use by fractional distillation of the homogenous mixture. It was observed that 15 w/w% potassium hydroxide solution can chemically degrade the soap matrix in the grease and extract up to 49 w/w% of the fuel oil when subjected to high shear stress at a temperature of 80°C. The 26 w/w% extraction of oil in the remaining sludge was obtained by solvent extraction process with mass ratios of sludge to solvent of 2:1. Solvent recovery of 88% by mass was obtained via fractional distillation method. The combined extraction processes brought an overall oil yield of 75 w/w% from the waste grease. The fuel oil obtained from this process has similar properties to paraffin oil and can be blended with other oils as an alternative energy source. Copyright © 2013 Elsevier Ltd. All rights reserved.

Optimization and economic evaluation of industrial gas production and combined heat and power generation from gasification of corn stover and distillers grains.

PubMed

Kumar, Ajay; Demirel, Yasar; Jones, David D; Hanna, Milford A

2010-05-01

Thermochemical gasification is one of the most promising technologies for converting biomass into power, fuels and chemicals. The objectives of this study were to maximize the net energy efficiency for biomass gasification, and to estimate the cost of producing industrial gas and combined heat and power (CHP) at a feedrate of 2000kg/h. Aspen Plus-based model for gasification was combined with a CHP generation model, and optimized using corn stover and dried distillers grains with solubles (DDGS) as the biomass feedstocks. The cold gas efficiencies for gas production were 57% and 52%, respectively, for corn stover and DDGS. The selling price of gas was estimated to be $11.49 and $13.08/GJ, respectively, for corn stover and DDGS. For CHP generation, the electrical and net efficiencies were as high as 37% and 88%, respectively, for corn stover and 34% and 78%, respectively, for DDGS. The selling price of electricity was estimated to be $0.1351 and $0.1287/kWh for corn stover and DDGS, respectively. Overall, high net energy efficiencies for gas and CHP production from biomass gasification can be achieved with optimized processing conditions. However, the economical feasibility of these conversion processes will depend on the relative local prices of fossil fuels. Copyright 2009 Elsevier Ltd. All rights reserved.

Investigation of sources, properties and preparation of distillate test fuels

NASA Technical Reports Server (NTRS)

Bowden, J. N.; Erwin, J.

1983-01-01

Distillate test fuel blends were generated for prescribed variations in composition and physical properties. Fuels covering a wide range in properties and composition which would provide a matrix of fuels for possible use in future combustion research programs were identified. Except for tetralin the blending components were all from typical refinery streams. Property variation blends span a boiling range within 150 C to 335 C, freezing point -23 C to -43 C, aromatic content 20 to 50 volume percent, hydrogen content 11.8 to 14.2 mass percent, viscosity 4 and 11 cSt (-20 C), and naphthalenes 8 and 16 volume percent. Composition variation blends were made with two base stocks, one paraffinic and the other napthenic. To each base stock was added each of three aromatic type fuels (alkyl benzenes, tetralin, and naphthalenes) for assigned initial boiling point, final boiling point, and hydrogen content. The hydrogen content was 13.5 mass percent for the paraffinic base stock blends and 12.5 mass percent and 11.5 mass percent for the naphthenic base stock blends. Sample 5-gallon quantities of all blends were prepared and analyzed.

40 CFR 80.1101 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... fuel” includes cellulosic biomass ethanol, waste derived ethanol, biodiesel (mono-alkyl ester), non... the calendar year) does not exceed 75,000 barrels. (h) Biodiesel (mono-alkyl ester) means a motor... Specification for Biodiesel Fuel Blendstock (B100) for Middle Distillate Fuels.” ASTM D-6751-07 is incorporated...

40 CFR 80.1101 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... fuel” includes cellulosic biomass ethanol, waste derived ethanol, biodiesel (mono-alkyl ester), non... the calendar year) does not exceed 75,000 barrels. (h) Biodiesel (mono-alkyl ester) means a motor... Specification for Biodiesel Fuel Blendstock (B100) for Middle Distillate Fuels.” ASTM D-6751-07 is incorporated...

Overcoming bacterial contamination of fuel ethanol fermentations -- alterntives to antibiotics

USDA-ARS?s Scientific Manuscript database

Fuel ethanol fermentations are not performed under aseptic conditions and microbial contamination reduces yields and can lead to costly "stuck fermentations". Antibiotics are commonly used to combat contaminants, but these may persist in the distillers grains co-product. Among contaminants, it is kn...

30 CFR 208.2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... the period for which any royalty or net profit share is accrued or reserved to the United States... only be made if substantial amounts of royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel...

Characterizing Emissions from the Combustion of Biofuels

EPA Science Inventory

Emissions from two biofuels, a soy-based biodiesel and an animal-based biodiesel, were measured and compared to emissions from a distillate petroleum fuel oil. The three fuels were burned in a small fire tube boiler designed for use in institutional, commercial, and light industr...

SRC Residual fuel oils

DOEpatents

Tewari, Krishna C.; Foster, Edward P.

1985-01-01

Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

Evaluation of grain distillers dried yeast as a fish meal substitute in practical-type diets of juvenile rainbow trout, Oncorhynchus mykiss

USDA-ARS?s Scientific Manuscript database

Grain distillers dried yeast (GDDY) is a single-cell protein obtained as a co-product during the production of fuel ethanol that may have potential as a protein replacement for rainbow trout. The goal of this study was to examine the suitability of GDDY as a replacement for fishmeal on a digestible ...

30 CFR 1208.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... lease during the period for which any royalty or net profit share is accrued or reserved to the United... royalty oil are turned back. Refined petroleum product means gasoline, kerosene, distillates (including Number 2 fuel oil), refined lubricating oils, or diesel fuel. Royalty oil means that amount of oil that...

Emissions from Ships with respect to Their Effects on Clouds.

NASA Astrophysics Data System (ADS)

Hobbs, Peter V.; Garrett, Timothy J.; Ferek, Ronald J.; Strader, Scott R.; Hegg, Dean A.; Frick, Glendon M.; Hoppel, William A.; Gasparovic, Richard F.; Russell, Lynn M.; Johnson, Douglas W.; O'Dowd, Colin; Durkee, Philip A.; Nielsen, Kurt E.; Innis, George

2000-08-01

Emissions of particles, gases, heat, and water vapor from ships are discussed with respect to their potential for changing the microstructure of marine stratiform clouds and producing the phenomenon known as `ship tracks.' Airborne measurements are used to derive emission factors of SO2 and NO from diesel-powered and steam turbine-powered ships, burning low-grade marine fuel oil (MFO); they were 15-89 and 2-25 g kg1 of fuel burned, respectively. By contrast a steam turbine-powered ship burning high-grade navy distillate fuel had an SO2 emission factor of 6 g kg1.Various types of ships, burning both MFO and navy distillate fuel, emitted from 4 × 1015 to 2 × 1016 total particles per kilogram of fuel burned (4 × 1015-1.5 × 1016 particles per second). However, diesel-powered ships burning MFO emitted particles with a larger mode radius (0.03-0.05 m) and larger maximum sizes than those powered by steam turbines burning navy distillate fuel (mode radius 0.02 m). Consequently, if the particles have similar chemical compositions, those emitted by diesel ships burning MFO will serve as cloud condensation nuclei (CCN) at lower supersaturations (and will therefore be more likely to produce ship tracks) than the particles emitted by steam turbine ships burning distillate fuel. Since steam turbine-powered ships fueled by MFO emit particles with a mode radius similar to that of diesel-powered ships fueled by MFO, it appears that, for given ambient conditions, the type of fuel burned by a ship is more important than the type of ship engine in determining whether or not a ship will produce a ship track. However, more measurements are needed to test this hypothesis.The particles emitted from ships appear to be primarily organics, possibly combined with sulfuric acid produced by gas-to-particle conversion of SO2. Comparison of model results with measurements in ship tracks suggests that the particles from ships contain only about 10% water-soluble materials. Measurements of the total particles entering marine stratiform clouds from diesel-powered ships fueled by MFO, and increases in droplet concentrations produced by these particles, show that only about 12% of the particles serve as CCN.The fluxes of heat and water vapor from ships are estimated to be 2-22 MW and 0.5-1.5 kg s1, respectively. These emissions rarely produced measurable temperature perturbations, and never produced detectable perturbations in water vapor, in the plumes from ships. Nuclear-powered ships, which emit heat but negligible particles, do not produce ship tracks. Therefore, it is concluded that heat and water vapor emissions do not play a significant role in ship track formation and that particle emissions, particularly from those burning low-grade fuel oil, are responsible for ship track formation. Subsequent papers in this special issue discuss and test these hypotheses.

Detailed Analysis of Criteria and Particle Emissions from a Very Large Crude Carrier Using a Novel ECA Fuel.

PubMed

Gysel, Nicholas R; Welch, William A; Johnson, Kent; Miller, Wayne; Cocker, David R

2017-02-07

Ocean going vessels (OGVs) operating within emission control areas (ECA) are required to use fuels with ≤0.1 wt % sulfur. Up to now only distillate fuels could meet the sulfur limits. Recently refiners created a novel low-sulfur heavy-fuel oil (LSHFO) meeting the sulfur limits so questions were posed whether nitric oxide (NO x ) and particulate matter (PM) emissions were the same for the two fuels. This project characterized criteria pollutants and undertook a detailed analysis of PM emissions from a very large crude oil carrier (VLCC) using a distillate ECA fuel (MGO) and novel LSHFO. Results showed emission factors of NO x were ∼5% higher with MGO than LSHFO. PM 2.5 emission factors were ∼3 times higher with LSHFO than MGO, while both were below values reported by Lloyds, U.S. EPA and CARB. A detailed analysis of PM revealed it was >90% organic carbon (OC) for both fuels. Elemental carbon (EC) and soot measured with an AVL microsoot sensor (MSS) reflected black carbon. PM size distributions showed unimodal peaks for both MGO (20-30 nm) and LSHFO (30-50 nm). Particle number (PN) emissions were 28% and 17% higher with the PPS-M compared to the SMPS for LSHFO and MGO, respectively.

Feasibility of Technologies to Produce Coal-Based Fuels with Equal or Lower Greenhouse Gas Emissions than Petroleum Fuels

DTIC Science & Technology

2014-12-22

the commercial viability of CTL fuels depends on coal being significantly cheaper than crude oil on an energy basis. Additionally, current...1990 1995 2000 2005 2010 2015 P ro d u ct S u p p li ed (M il li o n B a rr el s p er D a y ) Residual Fuel Oil Liquified Petroleum Gases Kerosene...Type Jet Fuel Finished Motor Gasoline Distillate Fuel Oil Aviation Gasoline 4 Independence and Security Act (EISA) of 2007 2 effectively prohibits

Harmonisation of microbial sampling and testing methods for distillate fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, G.C.; Hill, E.C.

1995-05-01

Increased incidence of microbial infection in distillate fuels has led to a demand for organisations such as the Institute of Petroleum to propose standards for microbiological quality, based on numbers of viable microbial colony forming units. Variations in quality requirements, and in the spoilage significance of contaminating microbes plus a tendency for temporal and spatial changes in the distribution of microbes, makes such standards difficult to implement. The problem is compounded by a diversity in the procedures employed for sampling and testing for microbial contamination and in the interpretation of the data obtained. The following paper reviews these problems andmore » describes the efforts of The Institute of Petroleum Microbiology Fuels Group to address these issues and in particular to bring about harmonisation of sampling and testing methods. The benefits and drawbacks of available test methods, both laboratory based and on-site, are discussed.« less

Extended duration orbiter study: CO2 removal and water recovery

NASA Technical Reports Server (NTRS)

Marshall, R. D.; Ellis, G. S.; Schubert, F. H.; Wynveen, R. A.

1979-01-01

Two electrochemical depolarized carbon dioxide concentrator subsystems were evaluated against baseline lithium hydroxide for (1) the baseline orbiter when expanded to accommodate a crew of seven (mission option one), (2) an extended duration orbiter with a power extension package to reduce fuel cell expendables (mission option two), and (3) an extended duration orbiter with a full capability power module to eliminate fuel cell expendables (mission option three). The electrochemical depolarized carbon dioxide concentrator was also compared to the solid amine regenerable carbon dioxide removal concept. Water recovery is not required for Mission Option One since sufficient water is generated by the fuel cells. The vapor compression distillation subsystem was evaluated for mission option two and three only. Weight savings attainable using the vapor compression distillation subsystem for water recovery versus on-board water storage were determined. Combined carbon dioxide removal and water recovery was evaluated to determine the effect on regenerable carbon dioxide removal subsystem selection.

Catalytic thermal cracking of postconsumer waste plastics to fuels. 2. Pilot-scale thermochemical conversion

USDA-ARS?s Scientific Manuscript database

Synthetic gasoline and diesel fuels were prepared via catalytic and noncatalytic pyrolysis of waste polyethylene and polypropylene plastics followed by distillation of plastic crude oils. Reaction conditions optimized using a 2 L batch reactor were applied to pilot-scale production of plastic crude ...

77 FR 34368 - Agency Information Collection Extension

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-11

... Gasoline Blending Components, All Other --Kerosene-Type Jet Fuel --Distillate Fuel Oil by Sulfur Category (15 ppm sulfur and under, Greater than 15 ppm to 500 ppm sulfur (inclusive), and Greater than 500 ppm sulfur) Eliminating Form EIA-801 and the proposed changes to Form EIA-805 will make weekly bulk terminal...

Synthetic Fuels and Biofuels: Questionable Replacements for Petroleum

DTIC Science & Technology

2008-12-31

Hardy, D.R. Biodiesels fuels: Use of Soy Oil as a Blending Stock for Middle Distillate Petroleum Fuels. Ind. Eng. Chem. Res. 2000, 39(10), 3945...BACKGROUND The world market supply of oil along with growing environmental concerns has led to an increase demand in production of biodiesel...which differs from the ASTM D975-06 specification for diesel fuel oils as shown in Table 1 [8,9], in addition to key property requirements that are

40 CFR 1065.703 - Distillate diesel fuel.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 1 Cetane Number 40-50 40-50 40-50 ASTM D613-05. Distillation range: Initial boiling point °C 171-204 171-204 171-204 ASTM D86-07a. 10 pct. point 204-238 204-238 204-238 50 pct. point 243-282 243-282 243...-37 ASTM D4052-96e01. Total sulfur, ultra low sulfur mg/kg 7-15 See 40 CFR 80.580. Total sulfur, low...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2010 CFR

2010-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you are...

40 CFR 60.4325 - What emission limits must I meet for NOX if my turbine burns both natural gas and distillate oil...

Code of Federal Regulations, 2011 CFR

2011-07-01

... NOX if my turbine burns both natural gas and distillate oil (or some other combination of fuels)? 60... Combustion Turbines Emission Limits § 60.4325 What emission limits must I meet for NOX if my turbine burns... percent natural gas, you must meet the corresponding limit for a natural gas-fired turbine when you are...

Merox catalyst innovation solves difficult kerosene treating problems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verachtert, T.A.; Salazar, J.R.; Staehle, B.E.

1985-03-01

The UOP* Merox* process has enjoyed more than 25 years of successful commercial application. It is applied to treatment of mercaptanrich hydrocarbon streams ranging from a light gas to liquids as heavy as 350/sup 0/C (650/sup 0/F) endpoint diesel fuel. Although Merox has been applied successfully to many kerosenes, there are kerosenes from certain crudes that could not be treated using the standard Merox system. Recent UOP Merox research has centered on the development of new catalysts. From this research, an improved catalyst system (Merox 10*) for kerosene treatment now makes the Merox process applicable to the sweetening of anymore » kerosene boiling range material from any crude oil source now in production. This Merox catalyst innovation also could replace the more expensive hydrotreating still being used by refiners for reducing the mercaptan content of distillates. This paper discusses the application of the Merox process to the treatment of higher boiling fuels, particularly kerosene and jet fuel; however, it should be understood that the treatment of illuminating kerosene, stove oil, diesel fuel, and light furnace oil is quite similar although generally less complicated. Comparative economics and commercial data are provided for the Merox 10 and conventional fixed bed Merox systems. The well established superior economics of Merox over an equivalent duty hydrotreater are presented.« less

Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

DOEpatents

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-09-23

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor

DOEpatents

Marker, Terry L.; Felix, Larry G.; Linck, Martin B.; Roberts, Michael J.

2016-12-06

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

Superoxide radical and UV irradiation in ultrasound assisted oxidative desulfurization (UAOD): A potential alternative for greener fuels

NASA Astrophysics Data System (ADS)

Chan, Ngo Yeung

This study is aimed at improving the current ultrasound assisted oxidative desulfurization (UAOD) process by utilizing superoxide radical as oxidant. Research was also conducted to investigate the feasibility of ultraviolet (UV) irradiation-assisted desulfurization. These modifications can enhance the process with the following achievements: (1) Meet the upcoming sulfur standards on various fuels including diesel fuel oils and residual oils; (2) More efficient oxidant with significantly lower consumption in accordance with stoichiometry; (3) Energy saving by 90%; (4) Greater selectivity in petroleum composition. Currently, the UAOD process and subsequent modifications developed in University of Southern California by Professor Yen's research group have demonstrated high desulfurization efficiencies towards various fuels with the application of 30% wt. hydrogen peroxide as oxidant. The UAOD process has demonstrated more than 50% desulfurization of refractory organic sulfur compounds with the use of Venturella type catalysts. Application of quaternary ammonium fluoride as phase transfer catalyst has significantly improved the desulfurization efficiency to 95%. Recent modifications incorporating ionic liquids have shown that the modified UAOD process can produce ultra-low sulfur, or near-zero sulfur diesels under mild conditions with 70°C and atmospheric pressure. Nevertheless, the UAOD process is considered not to be particularly efficient with respect to oxidant and energy consumption. Batch studies have demonstrated that the UAOD process requires 100 fold more oxidant than the stoichiometic requirement to achieve high desulfurization yield. The expected high costs of purchasing, shipping and storage of the oxidant would reduce the practicability of the process. The excess use of oxidant is not economically desirable, and it also causes environmental and safety issues. Post treatments would be necessary to stabilize the unspent oxidant residual to prevent the waste stream from becoming reactive or even explosive. High energy consumption is another drawback in the UAOD process. A typical 10 minutes ultrasonication applied in the UAOD process to achieve 95% desulfurization for 20g of diesel requires 450 kJ of energy, which is equivalent to approximately 50% of the energy that can be provided by the treated diesel. This great expenditure of energy is impractical for industries to adopt. In this study, modifications of the UAOD process, including the application of superoxide and selection of catalysts, were applied to lower the oxidant dosage and to improve the applicability towards heavy-distillates such as residual oil. The results demonstrated that the new system required 80% less oxidant as compared to previous generations of UAOD process without the loss of desulfurization efficiency. The new system demonstrated its suitability towards desulfurizing commercial mid-distillates including jet fuels, marine gas oil and sour diesel. This process also demonstrated a new method to desulfurize residual oil with high desulfurization yields. The new process development has been supported by Eco Energy Solutions Inc., Reno, Nevada and Intelligent Energy Inc., Long Beach, California. A feasibility study on UV assisted desulfurization by replacing ultrasound with UV irradiation was also conducted. The study demonstrated that the UV assisted desulfurization process consumes 90% less energy than the comparable process using ultrasonication. These process modifications demonstrated over 98% desulfurization efficiency on diesel oils and more than 75% on residual oils with significantly less oxidant and energy consumption. Also the feasibility to desulfurize commercial sour heavy oil was demonstrated. Based on the UAOD process and the commercialized modifications by Wan and Cheng, the feasible applications of superoxide and UV irradiation in the UAOD process could provide deep-desulfurization on various fuels with practical cost.

Effects of Varying CDS Levels and Drying and Cooling Temperatures on Flowability Properties of DDGS

USDA-ARS?s Scientific Manuscript database

Demand for alternative fuels and the need to reduce dependence on fossil fuels, have triggered the growth of corn-based ethanol production, and this is expected to rise in future years. Transportation of the co-product distillers dried grains with solubles (DDGS) from this industry occurs under vari...

Resolving Bacterial Contamination of Fuel Ethanol Fermentations with Beneficial Bacteria – an Alternative to Antibiotic Treatment

USDA-ARS?s Scientific Manuscript database

Fuel ethanol fermentations are not performed under aseptic conditions and microbial contamination reduces yields and can lead to costly “stuck fermentations.” Antibiotics are commonly used to combat contaminants, but these may persist in the distillers grains co-product. Among contaminants, it is kn...

Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

DOEpatents

Alford, J. Michael; Diener, Michael D.

2006-12-19

This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

Process simulation of modified dry grind ethanol plant with recycle of pretreated and enzymatically hydrolyzed distillers' grains.

PubMed

Kim, Youngmi; Mosier, Nathan; Ladisch, Michael R

2008-08-01

Distillers' grains (DG), a co-product of a dry grind ethanol process, is an excellent source of supplemental proteins in livestock feed. Studies have shown that, due to its high polymeric sugar contents and ease of hydrolysis, the distillers' grains have potential as an additional source of fermentable sugars for ethanol fermentation. The benefit of processing the distillers' grains to extract fermentable sugars lies in an increased ethanol yield without significant modification in the current dry grind technology. Three different potential configurations of process alternatives in which pretreated and hydrolyzed distillers' grains are recycled for an enhanced overall ethanol yield are proposed and discussed in this paper based on the liquid hot water (LHW) pretreatment of distillers' grains. Possible limitations of each proposed process are also discussed. This paper presents a compositional analysis of distillers' grains, as well as a simulation of the modified dry grind processes with recycle of distillers' grains. Simulated material balances for the modified dry grind processes are established based on the base case assumptions. These balances are compared to the conventional dry grind process in terms of ethanol yield, compositions of its co-products, and accumulation of fermentation inhibitors. Results show that 14% higher ethanol yield is achievable by processing and hydrolyzing the distillers' grains for additional fermentable sugars, as compared to the conventional dry grind process. Accumulation of fermentation by-products and inhibitory components in the proposed process is predicted to be 2-5 times higher than in the conventional dry grind process. The impact of fermentation inhibitors is reviewed and discussed. The final eDDGS (enhanced dried distillers' grains) from the modified processes has 30-40% greater protein content per mass than DDGS, and its potential as a value-added process is also analyzed. While the case studies used to illustrate the process simulation are based on LHW pretreated DG, the process simulation itself provides a framework for evaluation of the impact of other pretreatments.

Advanced Thermally Stable Coal-Based Jet Fuels

DTIC Science & Technology

2008-01-01

the refined chemical oil used previously is in full agreement with recomm fuendations provided by RAND. Rxploratory work was begun to evaluate the...possible production of nuclear graphite from the by-products of co-coking. This would allow use of distillation residua rather than decant oil as feed...isotropic, that also means that the coker feed could be a distillation residuum (resid) and is not required to be a decant oil . Thus we envision the

Method and apparatus for converting and removing organosulfur and other oxidizable compounds from distillate fuels, and compositions obtained thereby

DOEpatents

D'Alessandro, Robert N.; Tarabocchia, John; Jones, Jerald Andrew; Bonde, Steven E.; Leininger, Stefan

2010-10-26

The present disclosure is directed to a multi-stage system and a process utilizing said system with the design of reducing the sulfur-content in a liquid comprising hydrocarbons and organosulfur compounds. The process comprising at least one of the following states: (1) an oxidation stage; (2) an extraction state; (3) a raffinate washing stage; (4) a raffinate polishing stage; (5) a solvent recovery stage; (6) a solvent purification stage; and (7) a hydrocarbon recovery stage. The process for removing sulfur-containing hydrocarbons from gas oil, which comprises oxidizing gas oil comprising hydrocarbons and organosulfur compounds to obtain a product gas oil.

Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

2013-10-01

The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbentmore » development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.« less

Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

2013-09-01

The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbentmore » development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.« less

The use of modified tyre derived fuel for compression ignition engines.

PubMed

Pilusa, T J

2017-02-01

This study investigated physical and chemical modification of tyre-derived fuel oil (TDFO) obtained from pyrolysis of waste tyres and rubber products for application as an alternative fuel for compression ignition engines (CIE's). TDFO collected from a local waste tyre treatment facility was refined via a novel "oxidative gas-phase fractional distillation over 13× molecular sieves" to recover the light to medium fractions of the TDFO while oxidising and capturing some sulphur compounds in a gas phase. This was followed by desulphurization and chemical modification to improve cetane number, kinematic viscosity and fuel stability. The resulting fuel was tested in an ADE407T truck engine to compare its performance with petroleum diesel fuel. It was discovered that gas phase oxidative fractional distillation reduces the low boiling point sulphur compounds in TDFO such as mercaptans. Using petroleum diesel fuel as a reference, it was observed that the produced fuel has a lower cetane number, flash point and viscosity. On storage the fuel tends to form fibrous microstructures as a result of auto-oxidation of asphaltenes present in the fuel. Mixtures of alkyl nitrate, vinyl acetate, methacrylic anhydride, methyl-tert butyl ether, n-hexane and n-heptane were used to chemically modify the fuel in accordance with the minimum fuel specifications as per SANS 342. The engine performance tests results did not show any sign of engine ceasing or knocking effect. The power-torque trend was very consistent and compared well with petroleum diesel fuelled engine. The levels of total sulphur are still considerably high compared to other cleaner fuel alternatives derived from zero sulphur sources. Copyright © 2016. Published by Elsevier Ltd.

Dehydration of ethanol by facile synthesized glucose-based silica.

PubMed

Tang, Baokun; Bi, Wentao; Row, Kyung Ho

2013-02-01

Bioethanol is considered a potential liquid fuel that can be produced from biomass by fermentation and distillation. Although most of the water is removed by distillation, the purity of ethanol is limited to 95-96 % due to the formation of a low-boiling point, water-ethanol azeotrope. To improve the use of ethanol as a fuel, many methods, such as dehydration, have been proposed to avoid distillation and improve the energy efficiency of extraction. Glucose-based silica, as an adsorbent, was prepared using a simple method, and was proposed for the adsorption of water from water-ethanol mixtures. After adsorption using 0.4 g of adsorbent for 3 h, the initial water concentration of 20 % (water, v/v) was decreased to 10 % (water, v/v). For water concentrations less than 5 % (water, v/v), the adsorbent could concentrate ethanol to 99 % (ethanol, v/v). The Langmuir isotherms used to describe the adsorption of water on an adsorbent showed a correlation coefficient of 0.94. The separation factor of the adsorbent also decreased with decreasing concentration of water in solution.

Distributive Distillation Enabled by Microchannel Process Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arora, Ravi

The application of microchannel technology for distributive distillation was studied to achieve the Grand Challenge goals of 25% energy savings and 10% return on investment. In Task 1, a detailed study was conducted and two distillation systems were identified that would meet the Grand Challenge goals if the microchannel distillation technology was used. Material and heat balance calculations were performed to develop process flow sheet designs for the two distillation systems in Task 2. The process designs were focused on two methods of integrating the microchannel technology 1) Integrating microchannel distillation to an existing conventional column, 2) Microchannel distillation formore » new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel distillation units. However, it was found that a significant development work would be required to develop process parameters to use UAM for commercial distillation manufacturing. Two alternate manufacturing methods were explored. Both manufacturing approaches were experimentally tested to confirm their validity. The conceptual design of the microchannel distillation unit (Task 3) was combined with the manufacturing methods developed in Task 4 and flowsheet designs in Task 2 to estimate the cost of the microchannel distillation unit and this was compared to a conventional distillation column. The best results were for a methanol-water separation unit for the use in a biodiesel facility. For this application microchannel distillation was found to be more cost effective than conventional system and capable of meeting the DOE Grand Challenge performance requirements.« less

Method for co-processing waste rubber and carbonaceous material

DOEpatents

Farcasiu, Malvina; Smith, Charlene M.

1991-01-01

In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the depolymerization temperature of the rubber in the presence of a source of hydrogen. The depolymerized rubber acts as a liquefying solvent for the carbonaceous material while a beneficial catalytic effect is obtained from the carbon black released on depolymerization the reinforced rubber. The reaction is carried out at liquefaction conditions of 380.degree.-600.degree. C. and 70-280 atmospheres hydrogen pressure. The resulting liquid is separated from residual solids and further processed such as by distillation or solvent extraction to provide a carbonaceous liquid useful for fuels and other purposes.

Defense Energy Information System (DEIS): DEIS-80 Design System Specification. Revision A.

DTIC Science & Technology

1981-07-01

and consumption of petroleum products such as aviation gasoline, jet fuels, motor gasolines, distillate, and residual oil within DoD. DEIS I software...water, fuel oil , coal, solar/thermal power, and wind power. This subsystem also reports environmental data such as degree days during a reporting period...Petroleum Oil and Lubricants Officer, the Fuels Officer, the Supply Of- ficer, or the Engineering Officer on the base or facility consolidate in

Power Gas and Combined Cycles: Clean Power From Fossil Fuels

ERIC Educational Resources Information Center

Metz, William D.

1973-01-01

The combined-cycle system is currently regarded as a useful procedure for producing electricity. This system can burn natural gas and oil distillates in addition to coal. In the future when natural gas stocks will be low, coal may become an important fuel for such systems. Considerable effort must be made for research on coal gasification and…

40 CFR 63.11237 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... energy in the form of steam or hot water. Controlled flame combustion refers to a steady-state, or near... fossil fuel and no more than 15 percent biomass on an annual heat input basis. Commercial boiler means a... limited to, petroleum, distillate oil, residual oil, any form of liquid fuel derived from petroleum, used...

40 CFR 63.11237 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... energy in the form of steam or hot water. Controlled flame combustion refers to a steady-state, or near... fossil fuel and no more than 15 percent biomass on an annual heat input basis. Commercial boiler means a... limited to, petroleum, distillate oil, residual oil, any form of liquid fuel derived from petroleum, used...

40 CFR 80.582 - What are the sampling and testing methods for the fuel marker?

Code of Federal Regulations, 2013 CFR

2013-07-01

... marker content of distillate fuels and how will EPA qualify or decline to qualify a test method?—(1... developed by a Voluntary Consensus-Based Standards Body, such as the American Society for Testing and... this standard from the American Society for Testing and Materials, 100 Barr Harbor Dr., West...

40 CFR 80.582 - What are the sampling and testing methods for the fuel marker?

Code of Federal Regulations, 2012 CFR

2012-07-01

... marker content of distillate fuels and how will EPA qualify or decline to qualify a test method?—(1... developed by a Voluntary Consensus-Based Standards Body, such as the American Society for Testing and... this standard from the American Society for Testing and Materials, 100 Barr Harbor Dr., West...

40 CFR 80.582 - What are the sampling and testing methods for the fuel marker?

Code of Federal Regulations, 2014 CFR

2014-07-01

... marker content of distillate fuels and how will EPA qualify or decline to qualify a test method?—(1... developed by a Voluntary Consensus-Based Standards Body, such as the American Society for Testing and... this standard from the American Society for Testing and Materials, 100 Barr Harbor Dr., West...

Vapor compression distiller and membrane technology for water revitalization

NASA Technical Reports Server (NTRS)

Ashida, A.; Mitani, K.; Ebara, K.; Kurokawa, H.; Sawada, I.; Kashiwagi, H.; Tsuji, T.; Hayashi, S.; Otsubo, K.; Nitta, K.

1987-01-01

Water revitalization for a space station can consist of membrane filtration processes and a distillation process. Water recycling equipment using membrane filtration processes was manufactured for ground testing. It was assembled using commercially available components. Two systems for the distillation are studied: one is absorption type thermopervaporation cell and the other is a vapor compression distiller. Absorption type thermopervaporation, able to easily produce condensed water under zero gravity, was investigated experimentally and through simulated calculation. The vapor compression distiller was studied experimentally and it offers significant energy savings for evaporation of water.

Vapor compression distiller and membrane technology for water revitalization.

PubMed

Ashida, A; Mitani, K; Ebara, K; Kurokawa, H; Sawada, I; Kashiwagi, H; Tsuji, T; Hayashi, S; Otsubo, K; Nitta, K

1987-01-01

Water revitalization for a space station can consist of membrane filtration processes and a distillation process. Water recycling equipment using membrane filtration processes was manufactured for ground testing. It was assembled using commercially available components. Two systems for the distillation are studied; one is an absorption type thermopervaporation cell and the other is a vapor compression distiller. Absorption type thermopervaporation able to easily produce condensed water under zero gravity was investigated experimentally and through simulated calculation. The vapor compression distiller was studied experimentally and it offers significant energy savings for evaporation of water.

Rhamnolipid produced by Pseudomonas aeruginosa USM-AR2 facilitates crude oil distillation.

PubMed

Asshifa Md Noh, Nur; Al-Ashraf Abdullah, Amirul; Nasir Mohamad Ibrahim, Mohamad; Ramli Mohd Yahya, Ahmad

2012-01-01

A biosurfactant-producing and hydrocarbon-utilizing bacterium, Pseudomonas aeruginosa USM-AR2, was used to assist conventional distillation. Batch cultivation in a bioreactor gave a biomass of 9.4 g L(-1) and rhamnolipid concentration of 2.4 g L(-1) achieved after 72 h. Biosurfactant activity (rhamnolipid) was detected by the orcinol assay, emulsification index and drop collapse test. Pretreatment of crude oil TK-1 and AG-2 with a culture of P. aeruginosa USM-AR2 that contains rhamnolipid was proven to facilitate the distillation process by reducing the duration without reducing the quality of petroleum distillate. It showed a potential in reducing the duration of the distillation process, with at least 2- to 3-fold decreases in distillation time. This is supported by GC-MS analysis of the distillate where there was no difference between compounds detected in distillate obtained from treated or untreated crude oil. Calorimetric tests showed the calorie value of the distillate remained the same with or without treatment. These two factors confirmed that the quality of the distillate was not compromised and the incubation process by the microbial culture did not over-degrade the oil. The rhamnolipid produced by this culture was the main factor that enhanced the distillation performance, which is related to the emulsification of hydrocarbon chains in the crude oil. This biotreatment may play an important role to improve the existing conventional refinery and distillation process. Reducing the distillation times by pretreating the crude oil with a natural biosynthetic product translates to energy and cost savings in producing petroleum products.

Comprehensive Assessment of Composition and Thermochemical Variability by High Resolution GC/QToF-MS and the Advanced Distillation-Curve Method as a Basis of Comparison for Reference Fuel Development.

PubMed

Lovestead, Tara M; Burger, Jessica L; Schneider, Nico; Bruno, Thomas J

2016-12-15

Commercial and military aviation is faced with challenges that include high fuel costs, undesirable emissions, and supply chain insecurity that result from the reliance on petroleum-based feedstocks. The development of alternative gas turbine fuels from renewable resources will likely be part of addressing these issues. The United States has established a target for one billion gallons of renewable fuels to enter the supply chain by 2018. These alternative fuels will have to be very similar in properties, chemistry, and composition to existing fuels. To further this goal, the National Jet Fuel Combustion Program (a collaboration of multiple U.S. agencies under the auspices of the Federal Aviation Administration, FAA) is coordinating measurements on three reference gas turbine fuels to be used as a basis of comparison. These fuels are reference fuels with certain properties that are at the limits of experience. These fuels include a low viscosity, low flash point, high hydrogen content "best case" JP-8 (POSF 10264) fuel, a relatively high viscosity, high flash point, low hydrogen content "worst case" JP-5 (POSF 10259) fuel, and a Jet-A (POSF 10325) fuel with relatively average properties. A comprehensive speciation of these fuels is provided in this paper by use of high resolution gas chromatography/quadrupole time-of-flight - mass spectrometry (GC/QToF-MS), which affords unprecedented resolution and exact molecular formula capabilities. The volatility information as derived from the measurement of the advanced distillation curve temperatures, T k and T h , provides an approximation of the vapor liquid equilibrium and examination of the composition channels provides detailed insight into thermochemical data. A comprehensive understanding of the compositional and thermophysical data of gas turbine fuels is required not only for comparison but also for modeling of such complex mixtures, which will, in turn, aid in the development of new fuels with the goals of diversified feedstocks, decreased pollution, and increased efficiency.

Laboratory simulation studies of steady-state and potential catalytic effects in the ROPE{trademark} process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guffey, F.D.; Holper, P.A.

The Western Research Institute is currently developing a process for the recovery of distillable liquid products from alternate fossil fuel sources such as tar sand and oil shale. The processing concept is based on recycling a fraction of the produced oil back into the reactor with the raw resource. This concept is termed the recycle oil pyrolysis and extraction (ROPE{sup TM}) process. The conversion of the alternate resource to a liquid fuel is performed in two stages. The first recovery stage is performed at moderate temperatures (325--420{degrees}C [617--788{degrees}F]) in the presence of product oil recycle. The second stage is performedmore » at higher temperatures (450--540{degrees}C [842--1004{degrees}F]) in the absence of product oil. The experiments reported here were performed Asphalt Ridge tar sand in the all-glass laboratory simulation reactor to simulate (1) the recycling of SAE 50 weight oil in the recycle oil pyrolysis zone and (2) to evaluate the potential catalytic effects of the sand matrix.« less

Laboratory simulation studies of steady-state and potential catalytic effects in the ROPE trademark process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guffey, F.D.; Holper, P.A.

The Western Research Institute is currently developing a process for the recovery of distillable liquid products from alternate fossil fuel sources such as tar sand and oil shale. The processing concept is based on recycling a fraction of the produced oil back into the reactor with the raw resource. This concept is termed the recycle oil pyrolysis and extraction (ROPE{sup TM}) process. The conversion of the alternate resource to a liquid fuel is performed in two stages. The first recovery stage is performed at moderate temperatures (325--420{degrees}C (617--788{degrees}F)) in the presence of product oil recycle. The second stage is performedmore » at higher temperatures (450--540{degrees}C (842--1004{degrees}F)) in the absence of product oil. The experiments reported here were performed Asphalt Ridge tar sand in the all-glass laboratory simulation reactor to simulate (1) the recycling of SAE 50 weight oil in the recycle oil pyrolysis zone and (2) to evaluate the potential catalytic effects of the sand matrix.« less

The A-B-C of Desalting.

ERIC Educational Resources Information Center

Department of the Interior, Washington, DC. Office of Water Research and Technology.

This publication provides a simple explanation of how various processes convert sea or brackish water to fresh water. Included are descriptions of the membrane processes (reverse osmosis, electrodialysis, transport depletion, and piezodialysis); the distillation processes (multistage flash distillation, vertical tube distillation, multieffect…

Trends of jet fuel demand and properties

NASA Technical Reports Server (NTRS)

Friedman, R.

1984-01-01

Petroleum industry forecasts predict an increasing demand for jet fuels, a decrease in the gasoline-to-distillate (heavier fuel) demand ratio, and a greater influx of poorer quality petroleum in the next two to three decades. These projections are important for refinery product analyses. The forecasts have not been accurate, however, in predicting the recent, short term fluctuations in jet fuel and competing product demand. Changes in petroleum quality can be assessed, in part, by a review of jet fuel property inspections. Surveys covering the last 10 years show that average jet fuel freezing points, aromatic contents, and smoke points have trends toward their specification limits.

Tumorigenic Evaluation of Jet Fuels JP-TS and JP-7.

DTIC Science & Technology

1991-04-01

DTIC AL-TR-1991 0020 3 ELECTE0 AD-A252 012 JUN 2 6 1992• • TUMORIGENIC EVALUATION OF JET FUELS JP-TS AND JP-7 E. R. Kinkead C. L. Gaworski C. D...Evaluation of Jet Fuels JP-TS and JP-7. The research described in this report began in March 1981 and was completed in February 1991 under U.S. Air Force...of jet engines in military and commercial aircraft has led to the development of a number of petroleum distillate fuels with special properties. These

Composition of corn dry-grind ethanol by-products: DDGS, wet cake, and thin stillage.

PubMed

Kim, Youngmi; Mosier, Nathan S; Hendrickson, Rick; Ezeji, Thaddeus; Blaschek, Hans; Dien, Bruce; Cotta, Michael; Dale, Bruce; Ladisch, Michael R

2008-08-01

DDGS and wet distillers' grains are the major co-products of the dry grind ethanol facilities. As they are mainly used as animal feed, a typical compositional analysis of the DDGS and wet distillers' grains mainly focuses on defining the feedstock's nutritional characteristics. With an increasing demand for fuel ethanol, the DDGS and wet distillers' grains are viewed as a potential bridge feedstock for ethanol production from other cellulosic biomass. The introduction of DDGS or wet distillers' grains as an additional feed to the existing dry grind plants for increased ethanol yield requires a different approach to the compositional analysis of the material. Rather than focusing on its nutritional value, this new approach aims at determining more detailed chemical composition, especially on polymeric sugars such as cellulose, starch and xylan, which release fermentable sugars upon enzymatic hydrolysis. In this paper we present a detailed and complete compositional analysis procedure suggested for DDGS and wet distillers' grains, as well as the resulting compositions completed by three different research groups. Polymeric sugars, crude protein, crude oil and ash contents of DDGS and wet distillers' grains were accurately and reproducibly determined by the compositional analysis procedure described in this paper.

Lignocellulosic Biomass: A Sustainable Bioenergy Source for the Future.

PubMed

Fatma, Shabih; Hameed, Amir; Noman, Muhammad; Ahmed, Temoor; Shahid, Muhammad; Tariq, Mohsin; Sohail, Imran; Tabassum, Romana

2018-01-01

Increasing population and industrialization are continuously oppressing the existing energy resources and depleting the global fuel reservoirs. The elevated pollutions from the continuous consumption of non-renewable fossil fuels also seriously contaminating the surrounding environment. The use of alternate energy sources can be an environment-friendly solution to cope these challenges. Among the renewable energy sources biofuels (biomass-derived fuels) can serve as a better alternative to reduce the reliance on non-renewable fossil fuels. Bioethanol is one of the most widely consumed biofuels of today's world. The main objective of this review is to highlight the significance of lignocellulosic biomass as a potential source for the production of biofuels like bioethanol, biodiesel or biogas. We discuss the application of various methods for the bioconversion of lignocellulosic biomass to end products i.e. biofuels. The lignocellulosic biomass must be pretreated to disintegrate lignocellulosic complexes and to expose its chemical components for downstream processes. After pretreatment, the lignocellulosic biomass is then subjected to saccharification either via acidic or enzymatic hydrolysis. Thereafter, the monomeric sugars resulted from hydrolysis step are further processed into biofuel i.e. bioethanol, biodiesel or butanol etc. through the fermentation process. The fermented impure product is then purified through the distillation process to obtain pure biofuel. Renewable energy sources represent the potential fuel alternatives to overcome the global energy crises in a sustainable and eco-friendly manner. In future, biofuels may replenish the conventional non-renewable energy resources due to their renewability and several other advantages. Lignocellulosic biomass offers the most economical biomass to generate biofuels. However, extensive research is required for the commercial production of an efficient integrated biotransformation process for the production of lignocellulose mediated biofuels. Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.org.

A Study of Alternative Approaches to Produce Obscuring Smoke with JP-8 in Vehicle Engine Exhaust Smoke Systems (VEESS)

DTIC Science & Technology

1989-12-01

fuel. Full D 2887 distillation data are also shown in the Appendix. Fractionation ADparatus - The glass vacuum distillation apparatus used was from a...liter - 3-neck glass round bottom flask 2. 120 cm (4 ft), 50-mm diameter vacuum -jacketed column packed with No. 2918 Helipak coils 12 TABLE 3. ASTM D...swinging bucket for variable reflux ratios and an integral condenser, all of which are vacuum jacketed 4. Product receiver of 1-liter capacity, vacuum

Comparison of hecter fuel with export aviation gasoline

NASA Technical Reports Server (NTRS)

Dickinson, H C; Gage, V R; Sparrow, S W

1921-01-01

Among the fuels which will operate at compression ratios up to at least 8.0 without preignition or "pinking" is hecter fuel, whence a careful determination of its performance is of importance. For the test data presented in this report the hecter fuel used was a mixture of 30 per cent benzol and 70 per cent cyclohexane, having a low freezing point, and distilling from first drop to 90 per cent at nearly a constant temperature, about 20 degrees c. below the average distillation temperature ("mean volatility") of the x gasoline (export grade). The results of these experiments show that the power developed by hecter fuel is the same as that developed by export aviation gasoline at about 1,800 r.p.m. at all altitudes. At lower speeds differences in the power developed by the fuels become evident. Comparisons at ground level were omitted to avoid any possibility of damaging the engine by operating with open throttle on gasoline at so high a compression. The fuel consumption per unit power based on weight, not volume, averaged more than 10 per cent greater with hecter than with x gasoline. The thermal efficiency of the engine when using hecter is less than when using gasoline, particularly at higher speeds. A generalization of the difference for all altitudes and speeds being 8 per cent. A general deduction from these facts is that more hecter is exhausted unburnt. Hecter can withstand high compression pressures and temperature without preignition. (author)

Diesel Fuel Property Effects on In-Cylinder Liquid Penetration Length: Impact on Smoke Emissions and Equivalence Ratio Estimates at the Flame Lift-Off Length

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dumitrescu, Cosmin E.; Polonowski, Christopher J.; Fisher, Brian T.

Here in this study, elastic scattering was employed to investigate diesel fuel property effects on the liquid length (i.e., the maximum extent of in-cylinder liquid-phase fuel penetration) using select research fuels: an ultralow-sulfur #2 diesel emissions-certification fuel (CF) and four of the Coordinating Research Council (CRC) Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8). The experiments were performed in a single-cylinder heavy-duty optical compression-ignition engine under time-varying, noncombusting conditions to minimize the influence of chemical heat release on the liquid-length measurement. The FACE diesel fuel and CF liquid lengths under combusting conditions were also predicted using Siebers’ scaling law and pressure data from previous work using the same fuels at similar in-cylinder conditions. The objective was to observe if the liquid length under noncombusting or combusting conditions provides additional insights into the relationships among the main fuel properties (i.e., cetane number (CN), the 90 vol % distillation recovery temperature (T90), and aromatic content) and smoke emissions. Results suggest that liquid-length values are best correlated to fuel distillation characteristics measured with ASTM D2887 (simulated distillation method). This work also studied the relationship between liquid length and lift-off length, H (i.e., distance from the fuel-injector orifice exit to the position where the standing premixed autoignition zone stabilizes during mixing-controlled combustion). Two possible cases were identified based on the relative magnitudes of liquid length under combusting conditions (Lc) and H. The low-CN fuels are representative of the first case, L c < H, in which the fuel is always fully vaporized at H. The high-CN fuels are mostly representative of the second case, L c ≥ H, in which there is still liquid fuel at H. Lc ≥ H would suggest higher smoke emissions, but there is not enough evidence in this work to support a compounding effect of a longer liquid length on top of the aromatic-content effect on smoke emissions for fuels with similar CN, supporting previous findings in the literature that lift-off length plays a more important role than liquid-length on diesel combustion. At the same time, the experimental results suggest a decrease in the fuel-jet spreading angle, i.e., a decrease in the entrainment rate into the jet at and downstream of H, under combusting conditions, that is not accounted for in the model used to predict the values ofmore » $$\\phi$$(H). Lastly, as a result, L c may be of interest for accurate predictions of $$\\phi$$(H), especially for combustion strategies designed to lower in-cylinder soot by operating near or below the nonsooting $$\\phi$$(H)-value (i.e., $$\\phi$$(H) ≈ 2).« less

Diesel Fuel Property Effects on In-Cylinder Liquid Penetration Length: Impact on Smoke Emissions and Equivalence Ratio Estimates at the Flame Lift-Off Length

DOE PAGES

Dumitrescu, Cosmin E.; Polonowski, Christopher J.; Fisher, Brian T.; ...

2015-10-05

Here in this study, elastic scattering was employed to investigate diesel fuel property effects on the liquid length (i.e., the maximum extent of in-cylinder liquid-phase fuel penetration) using select research fuels: an ultralow-sulfur #2 diesel emissions-certification fuel (CF) and four of the Coordinating Research Council (CRC) Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8). The experiments were performed in a single-cylinder heavy-duty optical compression-ignition engine under time-varying, noncombusting conditions to minimize the influence of chemical heat release on the liquid-length measurement. The FACE diesel fuel and CF liquid lengths under combusting conditions were also predicted using Siebers’ scaling law and pressure data from previous work using the same fuels at similar in-cylinder conditions. The objective was to observe if the liquid length under noncombusting or combusting conditions provides additional insights into the relationships among the main fuel properties (i.e., cetane number (CN), the 90 vol % distillation recovery temperature (T90), and aromatic content) and smoke emissions. Results suggest that liquid-length values are best correlated to fuel distillation characteristics measured with ASTM D2887 (simulated distillation method). This work also studied the relationship between liquid length and lift-off length, H (i.e., distance from the fuel-injector orifice exit to the position where the standing premixed autoignition zone stabilizes during mixing-controlled combustion). Two possible cases were identified based on the relative magnitudes of liquid length under combusting conditions (Lc) and H. The low-CN fuels are representative of the first case, L c < H, in which the fuel is always fully vaporized at H. The high-CN fuels are mostly representative of the second case, L c ≥ H, in which there is still liquid fuel at H. Lc ≥ H would suggest higher smoke emissions, but there is not enough evidence in this work to support a compounding effect of a longer liquid length on top of the aromatic-content effect on smoke emissions for fuels with similar CN, supporting previous findings in the literature that lift-off length plays a more important role than liquid-length on diesel combustion. At the same time, the experimental results suggest a decrease in the fuel-jet spreading angle, i.e., a decrease in the entrainment rate into the jet at and downstream of H, under combusting conditions, that is not accounted for in the model used to predict the values ofmore » $$\\phi$$(H). Lastly, as a result, L c may be of interest for accurate predictions of $$\\phi$$(H), especially for combustion strategies designed to lower in-cylinder soot by operating near or below the nonsooting $$\\phi$$(H)-value (i.e., $$\\phi$$(H) ≈ 2).« less

Investigation of black and brown carbon multiple-wavelength-dependent light absorption from biomass and fossil fuel combustion source emissions

Treesearch

Michael R. Olson; Mercedes Victoria Garcia; Michael A. Robinson; Paul Van Rooy; Mark A. Dietenberger; Michael Bergin; James Jay Schauer

2015-01-01

Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption was measured from fuels including wood, agricultural biomass, coals, plant matter, and petroleum distillates in controlled combustion settings....

A comprehensive evaluation of the carcinogenic potential of middle distillate fuels.

PubMed

Nessel, C S

1999-02-01

Middle distillate fuels (MDFs), which include jet fuel, kerosene, and diesel fuel, are a class of hydrocarbons distilled from crude oil at approximately 350-700 degrees F (176-371 degrees C). Although MDFs generally do not contain appreciable levels of potentially carcinogenic polycyclic aromatic compounds (PACs), they have produced weak tumorigenic responses in mouse skin characterized by low tumor yield and long latency. Recent studies demonstrated that the tumorigenic effects of these MDFs were dependent upon chronic dermal irritation. In the absence of skin irritation, tumors did not develop. Mechanistic studies suggest that straight-run MDFs containing low levels of PACs cause skin tumors through a nongenotoxic mechanism. MDFs cause chronic skin irritation and injury with repeated application to the skin. They have been found to have little or no activity in the modified Ames mutagenicity assay, lack tumor initiating activity, and are active skin tumor promoters. It has been hypothesized that the tumorigenic response to MDFs results from the promotion of preexisting, spontaneously initiated cells. Two recent studies, a one-year tumor promotion study and a two-year skin painting study, evaluated the role of skin irritation on the tumorigenic activity of MDFs in mice. MDFs were applied in pure and diluted forms to assess the effect of equal weekly doses of irritating and nonirritating test materials. The tumorigenicity of straight-run MDFs correlated to the level of skin irritation. No significant increase in tumor incidence occurred under conditions that resulted in minimal skin irritation and injury. These studies indicate that the tumorigenic activity of MDFs containing low levels of PACs is secondary to chronic skin irritation. These materials should not present a carcinogenic hazard in the absence of prolonged skin irritation.

Evolution of Volatile Compounds during the Distillation of Cognac Spirit.

PubMed

Awad, Pierre; Athès, Violaine; Decloux, Martine Esteban; Ferrari, Gérald; Snakkers, Guillaume; Raguenaud, Patrick; Giampaoli, Pierre

2017-09-06

Cognac wine spirit has a complex composition in volatile compounds which contributes to its organoleptic profile. This work focused on the batch distillation process and, in particular, on volatile compounds specifically produced by chemical reactions during the distillation of Cognac wine spirit, traditionally conducted in two steps with charentais pot stills. The aim of this study was to characterize these volatile compounds formed during distillation. Sampling has been performed on the distillates and inside the boiler during a typical Cognac distillation. The analysis of these samples allowed us to perform a mass balance and to point out several types of volatile compounds whose quantities strongly increased during the distillation process. These compounds were distinguished by their chemical family. It has been found that the first distillation step was decisive for the formation of volatile compounds. Moreover, 2 esters, 3 aldehydes, 12 norisoprenoids, and 3 terpenes were shown to be generated during the process. These results suggest that some volatile compounds found in Cognac spirit are formed during distillation due to chemical reactions induced by high temperature. These findings give important indications to professional distillers in order to enhance the product's quality.

Multipartite nonlocality distillation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsu, Li-Yi; Wu, Keng-Shuo

2010-11-15

The stronger nonlocality than that allowed in quantum theory can provide an advantage in information processing and computation. Since quantum entanglement is distillable, can nonlocality be distilled in the nonsignalling condition? The answer is positive in the bipartite case. In this article the distillability of the multipartite nonlocality is investigated. We propose a distillation protocol solely exploiting xor operations on output bits. The probability-distribution vectors and matrix are introduced to tackle the correlators. It is shown that only the correlators with extreme values can survive the distillation process. As the main result, the amplified nonlocality cannot maximally violate any Bell-typemore » inequality. Accordingly, a distillability criterion in the postquantum region is proposed.« less

Catalytic partial oxidation reforming of hydrocarbon fuels.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmed, S.

1998-09-21

The polymer electrolyte fuel cell (PEFC) is the primary candidate as the power source for light-duty transportation systems. On-board conversion of fuels (reforming) to supply the required hydrogen has the potential to provide the driving range that is typical of today's automobiles. Petroleum-derived fuels, gasoline or some distillate similar to it, are attractive because of their existing production, distribution, and retailing infrastructure. The fuel may be either petroleum-derived or other alternative fuels such as methanol, ethanol, natural gas, etc. [1]. The ability to use a variety of fuels is also attractive for stationary distributed power generation [2], such as inmore » buildings, or for portable power in remote locations. Argonne National Laboratory has developed a catalytic reactor based on partial oxidation reforming that is suitable for use in light-duty vehicles powered by fuel cells. The reactor has shown the ability to convert a wide variety of fuels to a hydrogen-rich gas at less than 800 C, temperatures that are several hundreds of degrees lower than alternative noncatalytic processes. The fuel may be methanol, ethanol, natural gas, or petroleum-derived fuels that are blends of various hydrocarbons such as paraffins, olefins, aromatics, etc., as in gasoline. This paper will discuss the results obtained from a bench-scale (3-kWe) reactor., where the reforming of gasoline and natural gas generated a product gas that contained 38% and 42% hydrogen on a dry basis at the reformer exit, respectively.« less

Status of H-Coal commercial activities. [Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hicks, H.N. Jr.

1981-01-01

The H-Coal process is a development of Hydrocarbon Research, Inc. (HRI). It converts coal by catalytic hydrogenation to substitutes for petroleum ranging from a low sulfur fuel oil to an all distillate synthetic crude, the latter representing a potential source of raw material for the petrochemical industry. The process is a related application to HRI's H-Oil process which is used commercially for the desulfurization of residual oils from crude oil refining. A large scale pilot plant was constructed at Catlettsburg, Kentucky that is designed to process 200 to 600 TPD of coal. The paper includes an update on the keymore » activities associated with the Breckinridge Project: Pilot Plant H-Coal at Catlettsburg, Kentucky; commercial design activities in Houston; and permit and EIS activities for the Addison, Kentucky plant site.« less

Cogeneration Technology Alternatives Study (CTAS). Volume 4: Energy conversion systems

NASA Technical Reports Server (NTRS)

Brown, D. H.; Gerlaugh, H. E.; Priestley, R. R.

1980-01-01

Industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules specified by NASA for determining performance and cost. The advanced and commercially available cogeneration energy conversion systems studied in CTAS are fined together with their performance, capital costs, and the research and developments required to bring them to this level of performance.

Determination of solid mass fraction in partially frozen hydrocarbon fuels

NASA Technical Reports Server (NTRS)

Cotterell, E. M.; Mossadegh, R.; Bruce, A. J.; Moynihan, C. T.

1986-01-01

Filtration procedures alone are insufficient to determine the amounts of crystalline solid in a partially frozen hydrocarbon distillate fraction. This is due to the nature of the solidification process by which a large amount of liquid becomes entrapped within an interconnected crystalline structure. A technique has been developed to supplement filtration methods with an independent determination of the amount of liquid in the precipitate thereby revealing the actual value of mass percent crystalline solid, %S. A non-crystallizing dye is injected into the fuel and used as a tracer during the filtration. The relative concentrations of the dye in the filtrate and precipitate fractions is subsequently detected by a spectrophotometric comparison. The filtration apparatus was assembled so that the temperature of the sample is recorded immediately above the filter. Also, a second method of calculation has been established which allows significant reduction in test time while retaining acceptable accuracy of results. Data have been obtained for eight different kerosene range hydrocarbon fuels.

VAPOR PRESSURE ISOTOPE EFFECTS IN THE MEASUREMENT OF ENVIRONMENTAL TRITIUM SAMPLES.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuhne, W.

2012-12-03

Standard procedures for the measurement of tritium in water samples often require distillation of an appropriate sample aliquot. This distillation process may result in a fractionation of tritiated water and regular light water due to the vapor pressure isotope effect, introducing either a bias or an additional contribution to the total tritium measurement uncertainty. The magnitude of the vapor pressure isotope effect is characterized as functions of the amount of water distilled from the sample aliquot and the heat settings for the distillation process. The tritium concentration in the distillate is higher than the tritium concentration in the sample earlymore » in the distillation process, it then sharply decreases due to the vapor pressure isotope effect and becomes lower than the tritium concentration in the sample, until the high tritium concentration retained in the boiling flask is evaporated at the end of the process. At that time, the tritium concentration in the distillate again overestimates the sample tritium concentration. The vapor pressure isotope effect is more pronounced the slower the evaporation and distillation process is conducted; a lower heat setting during the evaporation of the sample results in a larger bias in the tritium measurement. The experimental setup used and the fact that the current study allowed for an investigation of the relative change in vapor pressure isotope effect in the course of the distillation process distinguish it from and extend previously published measurements. The separation factor as a quantitative measure of the vapor pressure isotope effect is found to assume values of 1.034 {+-} 0.033, 1.052 {+-} 0.025, and 1.066 {+-} 0.037, depending on the vigor of the boiling process during distillation of the sample. A lower heat setting in the experimental setup, and therefore a less vigorous boiling process, results in a larger value for the separation factor. For a tritium measurement in water samples, this implies that the tritium concentration could be underestimated by 3 - 6%.« less

Cogeneration Technology Alternatives Study (CTAS). Volume 1: Summary report

NASA Technical Reports Server (NTRS)

Gerlaugh, H. E.; Hall, E. W.; Brown, D. H.; Priestley, R. R.; Knightly, W. F.

1980-01-01

Large savings can be made in industry by cogenerating electric power and process heat in single energy conversion systems rather than separately in utility plants and in process boilers. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed-cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum-based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. An attempt was made to use consistent assumptions and a consistent set of ground rules for determining performance and cost in individual plants and on a national level. It was found that: (1) atmospheric and pressurized fluidized bed steam turbine systems were the most attractive of the direct coal-fired systems; and (2) open-cycle gas turbines with heat recovery steam generators and combined-cycles with NO(x) emission reduction and moderately increased firing temperatures were the most attractive of the coal-derived liquid-fired systems.

Outlook for alternative energy sources. [aviation fuels

NASA Technical Reports Server (NTRS)

Card, M. E.

1980-01-01

Predictions are made concerning the development of alternative energy sources in the light of the present national energy situation. Particular emphasis is given to the impact of alternative fuels development on aviation fuels. The future outlook for aircraft fuels is that for the near term, there possibly will be no major fuel changes, but minor specification changes may be possible if supplies decrease. In the midterm, a broad cut fuel may be used if current development efforts are successful. As synfuel production levels increase beyond the 1990's there may be some mixtures of petroleum-based and synfuel products with the possibility of some shale distillate and indirect coal liquefaction products near the year 2000.

The characteristics of bioethanol fuel made of vegetable raw materials

NASA Astrophysics Data System (ADS)

Muhaji; Sutjahjo, D. H.

2018-01-01

The aim of this research is to identify the most potential vegetable raw as the material to make a bioethanol fuel as the alternative energy for gasoline. This study used experimental method. The high-level bioethanol was obtained through the process of saccharification, fermentation and stratified distillation. ASTM standards were used as the method of testing the chemical element (D 5501, D 1744, D 1688, D 512, D 2622, D 381), and physical test (D 1613, D 240, D 1298-99, D 445, and D 93). The result of the analysis showed that from the seven bioethanols being studied there is one bioethanol from Saccharum of icinarum linn that has physical and chemical properties close to the standard of bioethanol. Meanwhile, the others only meet some of the physical and chemical properties of the standard bioethanol.

The addition of zeolite adsorbents and calcium oxide on purification of bioethanol from sugar palm (arenga pinnata merr)

NASA Astrophysics Data System (ADS)

Herlina, Netti; Siska Dewi Harahap, Ici

2018-03-01

Bioethanol (C2H5OH) is a biochemical liquid produced by microorganisms through fermentation process on sugar molecules from carbohydrates. Bioethanol is a fuel of vegetable oil that has similar properties to premium. With its main product of palm juice, Sugar palm (Arenga pinnata) is a potential source of sugar and carbohydrate for bioethanol production. Production of palm juice can reach up to 12-14 liters/tree/day with total sugar content in palm juice ranges from 12-15%. The purpose of this research was to produce highly-concentrated bioethanol from palm juice through fermentation proccess to subtitude fossil fuel. This study was conducted with three stages of treatment, namely: the fermentation of palm juice, distillation of bioethanol, and purification of bioethanol with the addition of adsorbent zeolite and calcium oxide.

Integrated process of distillation with side reactors for synthesis of organic acid esters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri

An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

Activated-charcoal filters: water treatment, pollution control, and industrial applications. January 1970-July 1988 (citations from the US Patent data base). Report for January 1970-July 1988

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bibliography contains citations of selected patents concerning activated-charcoal filters and their applications in water treatment, pollution control, and industrial processes. Filtering methods and equipment for air and water purification, industrial distillation and extraction, industrial leaching, and filtration of toxic gases and pollutants are described. Applications include drinking water purification, filtering beverages, production of polymer materials, solvent and metal recovery, swimming pool filtration, waste conversion, automobile fuel and exhaust systems, and footwear deodorizing. (Contains 129 citations fully indexed and including a title list.)

Techno-economics of integrating bioethanol production from spent sulfite liquor for reduction of greenhouse gas emissions from sulfite pulping mills.

PubMed

Petersen, Abdul M; Haigh, Kate; Görgens, Johann F

2014-01-01

Flow sheet options for integrating ethanol production from spent sulfite liquor (SSL) into the acid-based sulfite pulping process at the Sappi Saiccor mill (Umkomaas, South Africa) were investigated, including options for generation of thermal and electrical energy from onsite bio-wastes, such as bark. Processes were simulated with Aspen Plus® for mass- and energy-balances, followed by an estimation of the economic viability and environmental impacts. Various concentration levels of the total dissolved solids in magnesium oxide-based SSL, which currently fuels a recovery boiler, prior to fermentation was considered, together with return of the fermentation residues (distillation bottoms) to the recovery boiler after ethanol separation. The generation of renewable thermal and electrical energy from onsite bio-wastes were also included in the energy balance of the combined pulping-ethanol process, in order to partially replace coal consumption. The bio-energy supplementations included the combustion of bark for heat and electricity generation and the bio-digestion of the calcium oxide SSL to produce methane as additional energy source. Ethanol production from SSL at the highest substrate concentration was the most economically feasible when coal was used for process energy. However this solution did not provide any savings in greenhouse gas (GHG) emissions for the concentration-fermentation-distillation process. Maximizing the use of renewable energy sources to partially replace coal consumption yielded a satisfactory economic performance, with a minimum ethanol selling price of 0.83 US$/l , and a drastic reduction in the overall greenhouse gas emissions for the entire facility. High substrate concentrations and conventional distillation should be used when considering integrating ethanol production at sulfite pulping mills. Bio-wastes generated onsite should be utilized at their maximum potential for energy generation in order to maximize the GHG emissions reduction.

Mini-biomass electric generation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elliot, G.

1997-12-01

Awareness of the living standards achieved by others has resulted in a Russian population which is yearning for a higher standard of living. Such a situation demands access to affordable electricity in remote areas. Remote energy requirements creates the need to transport power or fossil fuels over long distances. Application of local renewable energy resources could eliminate the need for and costs of long distance power supply. Vast forest resources spread over most of Russia make biomass an ideal renewable energy candidate for many off-grid villages. The primary objective for this preliminary evaluation is to examine the economic feasibility ofmore » replacing distillate and gasoline fuels with local waste biomass as the primary fuel for village energy in outlying regions of Russia. Approximately 20 million people live in regions where Russia`s Unified Electric System grid does not penetrate. Most of these people are connected to smaller independent power grids, but approximately 8 million Russians live in off-grid villages and small towns served by stand-alone generation systems using either diesel fuel or gasoline. The off-grid villages depend on expensive distillate fuels and gasoline for combustion in small boilers and engines. These fuels are used for both electricity generation and district heating. Typically, diesel generator systems with a capacity of up to 1 MW serve a collective farm, settlement and their rural enterprises (there are an estimated 10,000 such systems in Russia). Smaller gasoline-fueled generator systems with capacities in the range of 0.5 - 5 kW serve smaller farms or rural enterprises (there are about 60,000 such systems in Russia).« less

Pilot-scale conversion of lime-treated wheat straw into bioethanol: quality assessment of bioethanol and valorization of side streams by anaerobic digestion and combustion

PubMed Central

Maas, Ronald HW; Bakker, Robert R; Boersma, Arjen R; Bisschops, Iemke; Pels, Jan R; de Jong, Ed; Weusthuis, Ruud A; Reith, Hans

2008-01-01

Introduction The limited availability of fossil fuel sources, worldwide rising energy demands and anticipated climate changes attributed to an increase of greenhouse gasses are important driving forces for finding alternative energy sources. One approach to meeting the increasing energy demands and reduction of greenhouse gas emissions is by large-scale substitution of petrochemically derived transport fuels by the use of carbon dioxide-neutral biofuels, such as ethanol derived from lignocellulosic material. Results This paper describes an integrated pilot-scale process where lime-treated wheat straw with a high dry-matter content (around 35% by weight) is converted to ethanol via simultaneous saccharification and fermentation by commercial hydrolytic enzymes and bakers' yeast (Saccharomyces cerevisiae). After 53 hours of incubation, an ethanol concentration of 21.4 g/liter was detected, corresponding to a 48% glucan-to-ethanol conversion of the theoretical maximum. The xylan fraction remained mostly in the soluble oligomeric form (52%) in the fermentation broth, probably due to the inability of this yeast to convert pentoses. A preliminary assessment of the distilled ethanol quality showed that it meets transportation ethanol fuel specifications. The distillation residue, which contained non-hydrolysable and non-fermentable (in)organic compounds, was divided into a liquid and solid fraction. The liquid fraction served as substrate for the production of biogas (methane), whereas the solid fraction functioned as fuel for thermal conversion (combustion), yielding thermal energy, which can be used for heat and power generation. Conclusion Based on the achieved experimental values, 16.7 kg of pretreated wheat straw could be converted to 1.7 kg of ethanol, 1.1 kg of methane, 4.1 kg of carbon dioxide, around 3.4 kg of compost and 6.6 kg of lignin-rich residue. The higher heating value of the lignin-rich residue was 13.4 MJ thermal energy per kilogram (dry basis). PMID:18699996

Production of Jet Fuels from Coal Derived Liquids. Volume 6. Preliminary Analysis of Upgrading Alternatives for the Great Plains Liquid By-Production Streams

DTIC Science & Technology

1988-09-01

be easily hydrogenated to produce highly naphthenic JP-4 blendstock, but the hydrogen consumption is very high, around 5,000 SCFB. Distillation...The naphtha stream is characterized by analyses shown in Table 4 and distillation results in Figure 7. Comparison of as-received and caustic ... Naphthenes , min. 70 it , max. 90 Reid Vapor Pressure,min. 2.0 f to it ,max. 3.0 Flash Point, OF, min. 100 122 Pour Point, OF, max. -72 -62 Gasoline

Land usage attributed to corn ethanol production in the United States: sensitivity to technological advances in corn grain yield, ethanol conversion, and co-product utilization.

PubMed

Mumm, Rita H; Goldsmith, Peter D; Rausch, Kent D; Stein, Hans H

2014-01-01

Although the system for producing yellow corn grain is well established in the US, its role among other biofeedstock alternatives to petroleum-based energy sources has to be balanced with its predominant purpose for food and feed as well as economics, land use, and environmental stewardship. We model land usage attributed to corn ethanol production in the US to evaluate the effects of anticipated technological change in corn grain production, ethanol processing, and livestock feeding through a multi-disciplinary approach. Seven scenarios are evaluated: four considering the impact of technological advances on corn grain production, two focused on improved efficiencies in ethanol processing, and one reflecting greater use of ethanol co-products (that is, distillers dried grains with solubles) in diets for dairy cattle, pigs, and poultry. For each scenario, land area attributed to corn ethanol production is estimated for three time horizons: 2011 (current), the time period at which the 15 billion gallon cap for corn ethanol as per the Renewable Fuel Standard is achieved, and 2026 (15 years out). Although 40.5% of corn grain was channeled to ethanol processing in 2011, only 25% of US corn acreage was attributable to ethanol when accounting for feed co-product utilization. By 2026, land area attributed to corn ethanol production is reduced to 11% to 19% depending on the corn grain yield level associated with the four corn production scenarios, considering oil replacement associated with the soybean meal substituted in livestock diets with distillers dried grains with solubles. Efficiencies in ethanol processing, although producing more ethanol per bushel of processed corn, result in less co-products and therefore less offset of corn acreage. Shifting the use of distillers dried grains with solubles in feed to dairy cattle, pigs, and poultry substantially reduces land area attributed to corn ethanol production. However, because distillers dried grains with solubles substitutes at a higher rate for soybean meal, oil replacement requirements intensify and positively feedback to elevate estimates of land usage. Accounting for anticipated technological changes in the corn ethanol system is important for understanding the associated land base ascribed, and may aid in calibrating parameters for land use models in biofuel life-cycle analyses.

Land usage attributed to corn ethanol production in the United States: sensitivity to technological advances in corn grain yield, ethanol conversion, and co-product utilization

PubMed Central

2014-01-01

Background Although the system for producing yellow corn grain is well established in the US, its role among other biofeedstock alternatives to petroleum-based energy sources has to be balanced with its predominant purpose for food and feed as well as economics, land use, and environmental stewardship. We model land usage attributed to corn ethanol production in the US to evaluate the effects of anticipated technological change in corn grain production, ethanol processing, and livestock feeding through a multi-disciplinary approach. Seven scenarios are evaluated: four considering the impact of technological advances on corn grain production, two focused on improved efficiencies in ethanol processing, and one reflecting greater use of ethanol co-products (that is, distillers dried grains with solubles) in diets for dairy cattle, pigs, and poultry. For each scenario, land area attributed to corn ethanol production is estimated for three time horizons: 2011 (current), the time period at which the 15 billion gallon cap for corn ethanol as per the Renewable Fuel Standard is achieved, and 2026 (15 years out). Results Although 40.5% of corn grain was channeled to ethanol processing in 2011, only 25% of US corn acreage was attributable to ethanol when accounting for feed co-product utilization. By 2026, land area attributed to corn ethanol production is reduced to 11% to 19% depending on the corn grain yield level associated with the four corn production scenarios, considering oil replacement associated with the soybean meal substituted in livestock diets with distillers dried grains with solubles. Efficiencies in ethanol processing, although producing more ethanol per bushel of processed corn, result in less co-products and therefore less offset of corn acreage. Shifting the use of distillers dried grains with solubles in feed to dairy cattle, pigs, and poultry substantially reduces land area attributed to corn ethanol production. However, because distillers dried grains with solubles substitutes at a higher rate for soybean meal, oil replacement requirements intensify and positively feedback to elevate estimates of land usage. Conclusions Accounting for anticipated technological changes in the corn ethanol system is important for understanding the associated land base ascribed, and may aid in calibrating parameters for land use models in biofuel life-cycle analyses. PMID:24725504

Comprehensive Assessment of Composition and Thermochemical Variability by High Resolution GC/QToF-MS and the Advanced Distillation-Curve Method as a Basis of Comparison for Reference Fuel Development*

PubMed Central

Lovestead, Tara M.; Burger, Jessica L.; Schneider, Nico; Bruno, Thomas J.

2018-01-01

Commercial and military aviation is faced with challenges that include high fuel costs, undesirable emissions, and supply chain insecurity that result from the reliance on petroleum-based feedstocks. The development of alternative gas turbine fuels from renewable resources will likely be part of addressing these issues. The United States has established a target for one billion gallons of renewable fuels to enter the supply chain by 2018. These alternative fuels will have to be very similar in properties, chemistry, and composition to existing fuels. To further this goal, the National Jet Fuel Combustion Program (a collaboration of multiple U.S. agencies under the auspices of the Federal Aviation Administration, FAA) is coordinating measurements on three reference gas turbine fuels to be used as a basis of comparison. These fuels are reference fuels with certain properties that are at the limits of experience. These fuels include a low viscosity, low flash point, high hydrogen content “best case” JP-8 (POSF 10264) fuel, a relatively high viscosity, high flash point, low hydrogen content “worst case” JP-5 (POSF 10259) fuel, and a Jet-A (POSF 10325) fuel with relatively average properties. A comprehensive speciation of these fuels is provided in this paper by use of high resolution gas chromatography/quadrupole time-of-flight – mass spectrometry (GC/QToF-MS), which affords unprecedented resolution and exact molecular formula capabilities. The volatility information as derived from the measurement of the advanced distillation curve temperatures, Tk and Th, provides an approximation of the vapor liquid equilibrium and examination of the composition channels provides detailed insight into thermochemical data. A comprehensive understanding of the compositional and thermophysical data of gas turbine fuels is required not only for comparison but also for modeling of such complex mixtures, which will, in turn, aid in the development of new fuels with the goals of diversified feedstocks, decreased pollution, and increased efficiency. PMID:29706688

Alaskan refiner raced against winter to relocate vacuum unit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gdula, L.M.; Wentworth, J.A.

In late November 1994, San Antonio-based Tesoro Petroleum Corp. and Litwin Engineers and Constructors Inc. completed the relocation and refurbishment of a $25 million vacuum unit at Tesoro`s 72,000 b/d Kenai refinery. The addition of the vacuum distillation unit is a critical component in Tesoro`s market-driven strategy to enhance operating profits by maximizing production of higher-margin products such as gasoline and jet fuel. With its new vacuum distillation unit, Tesoro has reduced production of lower-value residual fuel oil while recovering more lighter, high-value material. The paper discusses the economic and strategic merits of purchasing and relocating an existing vacuum unit,more » the project schedule, new equipment, dismantling and transport, installation, tie-ins and start-up, products, operating changes, corrosion concerns, off gas, steam generation, design changes, environmental issues, reporting requirements, and accomplishments.« less

Effects of sodium meta bisulfite on diffusion fermentation of fodder beets for fuel ethanol production. [Saccharomyces cerevisiae

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gibbons, W.R.; Westby, C.A.

1987-01-01

The authors designed and tested a new process for converting fodder beets to ethanol: continuous diffusion-fermentation. This process utilizes the simultaneous diffusion-fermentation concept of the EX-FERM design; however, it overcomes the material handling problems inherent in that system by utilizing a counterflow tubular auger system. This process also eliminates the need for roller mills or presses and dryers which are required for alcohol recovery from solid phase fermentation. The latter is the only other currently feasible procedure for producing distillably worthwhile amounts of ethanol from fodder beets, sweet sorghum, and other similar feedstocks. Results on the use of sodium metamore » bisulfite (SMB) for contamination control with fermenting fodder beet cubes are reported.« less

Refinery Outages

EIA Publications

2017-01-01

EIA's latest analysis of planned refinery outages during the first half of 2017 finds that such outages are not expected to cause a shortfall in the supply of petroleum products including gasoline, jet fuel, and distillate fuel, relative to expected demand, either nationally or within any U.S. region. This result occurs notwithstanding the current high level of U.S. gasoline demand, which in 2016 was as high as or higher than in any past year.

Comparison of fuel-cell and diesel integrated energy systems and a conventional system for a 500-unit apartment

NASA Technical Reports Server (NTRS)

Simons, S. N.; Maag, W. L.

1978-01-01

The electrical and thermal energy utilization efficiencies of a 500 unit apartment complex are analyzed and compared for each of three energy supply systems. Two on-site integrated energy systems, one powered by diesel engines and the other by phosphoric-acid fuel cells were compared with a conventional system which uses purchased electricity and on-site boilers for heating. All fuels consumed on-site are clean, synthetic fuels (distillate fuel oil or pipeline quality gas) derived from coal. Purchased electricity was generated from coal at a central station utility. The relative energy consumption and economics of the three systems are analyzed and compared.

Comparative Study of Alternative Fuel Icing Inhibitor Additive Properties & Chemical Analysis of Metal Speciation in Aviation Fuels

DTIC Science & Technology

2010-08-01

paraffins, olefins, cyclo-parafins ( naphthenes ), aromatics and a host of trace species. Petroleum distillates such as jet fuels are also a complex...LC method consisted of: Mobile Phase: 95% CH3OH + 0.1% (vol) Acetic Acid 5% De-Ionized H2O Injection Volume: 5 µL Needle Wash in Flush...Port for 20 seconds using mobile phase CH3OH + 0.1% (vol) Acetic- Acid Run Time: 10 minute Post Time: 1 minute Binary Pump SL Flow Rate: 0.3 ml/min

Distillation process using microchannel technology

DOEpatents

Tonkovich, Anna Lee [Dublin, OH; Simmons, Wayne W [Dublin, OH; Silva, Laura J [Dublin, OH; Qiu, Dongming [Carbondale, IL; Perry, Steven T [Galloway, OH; Yuschak, Thomas [Dublin, OH; Hickey, Thomas P [Dublin, OH; Arora, Ravi [Dublin, OH; Smith, Amanda [Galloway, OH; Litt, Robert Dwayne [Westerville, OH; Neagle, Paul [Westerville, OH

2009-11-03

The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

Synthesis of zeolite from rice husk ash waste of brick industries as hydrophobic adsorbent for fuel grade ethanol purification

NASA Astrophysics Data System (ADS)

Purnomo, A.; Alhanif, M.; Khotimah, C.; Zuhra, UA; Putri, BR; Kumoro, AC

2017-11-01

A lot of researchers have devoted on ethanol utilization as renewable energy to substitute petroleum based gasoline. When ethanol is being used as a new fuel candidate, it should have at least of 99.5% purity. Usually produced via sugar fermentation process, further purification of ethanol from other components in fermentation broth to obtain its fuel grade is a crucial step. The purpose of this research is to produce synthetic zeolite as hydrophobic adsorbent from rice husk ash for ethanol-water separation and to investigate the influence of weight, adsorption time and initial ethanol concentration on zeolite adsorption capacity. This research consisted of rice husk silica extraction, preparation of hydrophobic zeolite adsorbent, physical characterization using SEM, EDX and adsorption test for an ethanol-water solution. Zeolite with highest adsorption capacity was obtained with 15: 1 alumina silica composition. The best adsorption condition was achieved when 4-gram hydrophobic zeolite applied for adsorption of 100 mL of 10% (v/v) ethanol-water solution for 120 minutes, which resulted in ethanol with 98.93% (v/v) purity. The hydrophobic zeolite from rice husk ash is a potential candidate as an efficient adsorbent to purify raw ethanol into fuel grade ethanol. Implementation of this new adsorbent for ethanol production in commercial scale may reduce the energy consumption of that usually used for the distillation processes.

75 FR 14116 - Approval of Implementation Plans of Wisconsin: Nitrogen Oxides Reasonably Available Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-24

... Annealing Furnace. Asphalt Plants =>65 mmBtu/hr... Gaseous fuel, 0.15 lbs/mmBtu. Distillate oil, 0.20 lbs/mm... relations, Nitrogen oxides, Ozone, Particulate matter, Reporting and recordkeeping requirements, Sulfur...

Property Analysis of Ethanol− Natural Gasoline−BOB Blends to Make Flex Fuel

EPA Pesticide Factsheets

Ten natural gasolines were analyzed for a wide range of properties, including Reid vapor pressure (RVP), benzene, sulfur, distillation, stability, metals, and aromatic content, to determine their quality. Benzene and sulfur content were sufficiently low

Characterization of coal liquids derived from the H-coal process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holmes, S.A.; Woodward, P.W.; Sturm, G.P. Jr.

1976-11-01

Compositional data of coal liquid products derived from the H-Coal process were obtained. Two overhead products (one from the fuel oil mode of operation and the other from the syncrude mode of operation) were prepared by Hydrocarbon Research, Inc. from Illinois No. 6 coal. The compositional data of these products are tabulated, and characteristics of the materials are discussed. Separation and characterization methods, with slight modification, as developed by the Bureau of Mines-API Research Project 60 for characterizing heavy ends of petroleum, were successfully used in analyzing coal liquid distillates within the boiling range 200/sup 0/ to 540/sup 0/C. Distillatesmore » boiling below 200/sup 0/C were separated and analyzed using chromatographic and spectral techniques.« less

APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, R.; Pak, D.

2011-08-10

Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill frommore » the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.« less

Thermal Stability of Distillate Hydrocarbon Fuels. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Reddy, Kishenkumar Tadisina; Cernansky, Nicholas P.

1987-01-01

Thermal stability of fuels is expected to become a severe problem in the future due to the anticipated use of broadened specification and alternative fuels. Future fuels will have higher contents of heteroatomic species which are reactive constituents and are known to influence fuel degradation. To study the degradation chemistry of selected model fuels, n-dodecane and n-dodecane plus heteroatoms were aerated by bubbling air through the fuels amd stressed on a modified Jet Fuel Thermal Oxidation Tester facility operating at heater tube temperatures between 200 to 400 C. The resulting samples were fractionated to concentrate the soluble products and then analyzed using gas chromatographic and mass spectrometric techniques to quantify and identify the stable reaction intermediate and product specifically. Heteroatom addition showed that the major soluble products were always the same, with and without heteroatoms, but their distributions varied considerably.

Downstream process options for the ABE fermentation.

PubMed

Friedl, Anton

2016-05-01

Butanol is a very interesting substance both for the chemical industry and as a biofuel. The classical distillation process for the removal of butanol is far too energy demanding, at a factor of 220% of the energy content of butanol. Alternative separation processes studied are hybrid processes of gas-stripping, liquid-liquid extraction and pervaporation with distillation and a novel adsorption/drying/desorption hybrid process. Compared with the energy content of butanol, the resulting energy demand for butanol separation and concentration of optimized hybrid processes is 11%-22% for pervaporation/distillation and 11%-17% for liquid-liquid extraction/distillation. For a novel adsorption/drying/desorption process, the energy demand is 9.4%. But all downstream process options need further proof of industrial applicability. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Silicon production process evaluations

NASA Technical Reports Server (NTRS)

1981-01-01

Chemical engineering analysis of the HSC process (Hemlock Semiconductor Corporation) for producing silicon from dichlorosilane in a 1,000 MT/yr plant was continued. Progress and status for the chemical engineering analysis of the HSC process are reported for the primary process design engineering activities: base case conditions (85%), reaction chemistry (85%), process flow diagram (60%), material balance (60%), energy balance (30%), property data (30%), equipment design (20%) and major equipment list (10%). Engineering design of the initial distillation column (D-01, stripper column) in the process was initiated. The function of the distillation column is to remove volatile gases (such as hydrogen and nitrogen) which are dissolved in liquid chlorosilanes. Initial specifications and results for the distillation column design are reported including the variation of tray requirements (equilibrium stages) with reflux ratio for the distillation.

Advanced Distillation Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maddalena Fanelli; Ravi Arora; Annalee Tonkovich

2010-03-24

The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the projectmore » were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.« less

40 CFR 60.41b - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... produces both electric (or mechanical) and useful thermal energy from the same primary energy source. Coke.... Conventional technology means wet flue gas desulfurization (FGD) technology, dry FGD technology, atmospheric fluidized bed combustion technology, and oil hydrodesulfurization technology. Distillate oil means fuel oils...

40 CFR 79.33 - Motor vehicle diesel fuel.

Code of Federal Regulations, 2010 CFR

2010-07-01

... data may be for such shorter period. (1) Hydrocarbon composition (aromatic content, olefin content, saturate content), with the methods of analysis identified; (2) Polynuclear organic material content, sulfur content, and trace element content, with the methods of analysis identified; (3) Distillation...

Stability of yttria-stabilized zirconia during pyroprocessing tests

NASA Astrophysics Data System (ADS)

Choi, Eun-Young; Lee, Jeong; Lee, Sung-Jai; Kim, Sung-Wook; Jeon, Sang-Chae; Cho, Soo Haeng; Oh, Seung Chul; Jeon, Min Ku; Lee, Sang Kwon; Kang, Hyun Woo; Hur, Jin-Mok

2016-07-01

In this study, the feasibility of yttria-stabilized zirconia (YSZ) was investigated for use as a ceramic material, which can be commonly used for both electrolytic reduction and electrorefining. First, the stability of YSZ in salts for electrolytic reduction and electrorefining was examined. Then, its stability was demonstrated by a series of pyroprocessing tests, such as electrolytic reduction, LiCl distillation, electrorefining, and LiClsbnd KCl distillation, using a single stainless steel wire mesh basket containing fuel and YSZ. A single basket was used by its transportation from one test to subsequent tests without the requirements for unloading.

Use of extractive distillation to produce concentrated nitric acid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

1981-04-01

Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCPmore » = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.« less

Activated charcoal filters: Water treatment, pollution control, and industrial applications. (Latest citations from the Patent Bibliographic database with exemplary claims. ) Published Search

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The bibliography contains citations of selected patents concerning activated charcoal filters and their applications in water treatment, pollution control, and industrial processes. Filtering methods and equipment for air and water purification, industrial distillation and extraction, industrial leaching, and filtration of toxic materials and contaminants are described. Applications include drinking water purification, filtering beverages, production of polymer materials, solvent and metal recovery, waste conversion, automotive fuel and exhaust systems, swimming pool filtration, tobacco smoke filters, kitchen ventilators, medical filtration treatment, and odor absorbing materials. (Contains 250 citations and includes a subject term index and title list.)

Production of heavy water

DOEpatents

Spencer, Larry S.; Brown, Sam W.; Phillips, Michael R.

2017-06-06

Disclosed are methods and apparatuses for producing heavy water. In one embodiment, a catalyst is treated with high purity air or a mixture of gaseous nitrogen and oxygen with gaseous deuterium all together flowing over the catalyst to produce the heavy water. In an alternate embodiment, the deuterium is combusted to form the heavy water. In an alternate embodiment, gaseous deuterium and gaseous oxygen is flowed into a fuel cell to produce the heavy water. In various embodiments, the deuterium may be produced by a thermal decomposition and distillation process that involves heating solid lithium deuteride to form liquid lithium deuteride and then extracting the gaseous deuterium from the liquid lithium deuteride.

Thermodynamics of reformulated automotive fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zudkevitch, D.; Murthy, A.K.S.; Gmehling, J.

1995-06-01

Two methods for predicting Reid vapor pressure (Rvp) and initial vapor emissions of reformulated gasoline blends that contain one or more oxygenated compounds show excellent agreement with experimental data. In the first method, method A, D-86 distillation data for gasoline blends are used for predicting Rvp from a simulation of the mini dry vapor pressure equivalent (Dvpe) experiment. The other method, method B, relies on analytical information (PIANO analyses) of the base gasoline and uses classical thermodynamics for simulating the same Rvp equivalent (Rvpe) mini experiment. Method B also predicts composition and other properties for the fuel`s initial vapor emission.more » Method B, although complex, is more useful in that is can predict properties of blends without a D-86 distillation. An important aspect of method B is its capability to predict composition of initial vapor emissions from gasoline blends. Thus, it offers a powerful tool to planners of gasoline blending. Method B uses theoretically sound formulas, rigorous thermodynamic routines and uses data and correlations of physical properties that are in the public domain. Results indicate that predictions made with both methods agree very well with experimental values of Dvpe. Computer simulation methods were programmed and tested.« less

Evaluation of ultraviolet spectrophotometry for simultaneous analysis of alkylbenzenes, alkylnaphthalenes, alkylanthracenes/phenanthrenes and total aromatics in mid-distillate fuels

NASA Technical Reports Server (NTRS)

Kim, W. S.; Seng, G. T.

1982-01-01

A rapid ultraviolet spectrophotometric method for the simultaneous determination of aromatics in middistillate fuels was developed and evaluated. In this method, alkylbenzenes, alkylnaphthalenes, alkylanthracenes/phenanthracenes and total aromatics were determined from ultraviolet spectra of the fuels. The accuracy and precision were determined using simulated standard fuels with known compositions. The total aromatics fraction accuracy was 5% for a Jet A type fuel and 0.6% for a broadened properties jet turbine type fuel. Precision, expressed as relative standard deviations, ranged from 2.9% for the alkylanthracenes/phenanthrenes to 15.3% for the alkylbenzenes. The accuracy, however, was less for actual fuel samples when compared to the results obtained by a mass spectrometric method. In addition, the ASTM D-1840 method for naphthalenes by ultraviolet spectroscopy was evaluated.

Development of efficient, integrated cellulosic biorefineries : LDRD final report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Teh, Kwee-Yan; Hecht, Ethan S.; Shaddix, Christopher R.

2010-09-01

Cellulosic ethanol, generated from lignocellulosic biomass sources such as grasses and trees, is a promising alternative to conventional starch- and sugar-based ethanol production in terms of potential production quantities, CO{sub 2} impact, and economic competitiveness. In addition, cellulosic ethanol can be generated (at least in principle) without competing with food production. However, approximately 1/3 of the lignocellulosic biomass material (including all of the lignin) cannot be converted to ethanol through biochemical means and must be extracted at some point in the biochemical process. In this project we gathered basic information on the prospects for utilizing this lignin residue material inmore » thermochemical conversion processes to improve the overall energy efficiency or liquid fuel production capacity of cellulosic biorefineries. Two existing pretreatment approaches, soaking in aqueous ammonia (SAA) and the Arkenol (strong sulfuric acid) process, were implemented at Sandia and used to generated suitable quantities of residue material from corn stover and eucalyptus feedstocks for subsequent thermochemical research. A third, novel technique, using ionic liquids (IL) was investigated by Sandia researchers at the Joint Bioenergy Institute (JBEI), but was not successful in isolating sufficient lignin residue. Additional residue material for thermochemical research was supplied from the dilute-acid simultaneous saccharification/fermentation (SSF) pilot-scale process at the National Renewable Energy Laboratory (NREL). The high-temperature volatiles yields of the different residues were measured, as were the char combustion reactivities. The residue chars showed slightly lower reactivity than raw biomass char, except for the SSF residue, which had substantially lower reactivity. Exergy analysis was applied to the NREL standard process design model for thermochemical ethanol production and from a prototypical dedicated biochemical process, with process data supplied by a recent report from the National Research Council (NRC). The thermochemical system analysis revealed that most of the system inefficiency is associated with the gasification process and subsequent tar reforming step. For the biochemical process, the steam generation from residue combustion, providing the requisite heating for the conventional pretreatment and alcohol distillation processes, was shown to dominate the exergy loss. An overall energy balance with different potential distillation energy requirements shows that as much as 30% of the biomass energy content may be available in the future as a feedstock for thermochemical production of liquid fuels.« less

Interlinked Test Results for Fusion Fuel Processing and Blanket Tritium Recovery Systems Using Cryogenic Molecular Sieve Bed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamanishi, Toshihiko; Hayashi, Takumi; Kawamura, Yoshinori

2005-07-15

A simulated fuel processing (cryogenic distillation columns and a palladium diffuser) and CMSB (cryogenic molecular sieve bed) systems were linked together, and were operated. The validity of the CMSB was discussed through this experiment as an integrated system for the recovery of blanket tritium. A gas stream of hydrogen isotopes and He was supplied to the CMSB as the He sweep gas in blanket of a fusion reactor. After the breakthrough of tritium was observed, regeneration of the CMSB was carried out by evacuating and heating. The hydrogen isotopes were finally recovered by the diffuser. At first, only He gasmore » was sent by the evacuating. The hydrogen isotopes gas was then rapidly released by the heating. The system worked well against the above drastic change of conditions. The amount of hydrogen isotopes gas finally recovered by the diffuser was in good agreement with that adsorbed by the CMSB. The dynamic behaviors (breakthrough and regeneration) of the system were explained well by a set of basic codes.« less

Recovery of actinides from actinide-aluminium alloys by chlorination: Part III - Chlorination with HCl(g)

NASA Astrophysics Data System (ADS)

Meier, Roland; Souček, Pavel; Walter, Olaf; Malmbeck, Rikard; Rodrigues, Alcide; Glatz, Jean-Paul; Fanghänel, Thomas

2018-01-01

Two steps of a pyrochemical route for the recovery of actinides from spent metallic nuclear fuel are being investigated at JRC-Karlsruhe. The first step consists in electrorefining the fuel in molten salt medium implying aluminium cathodes. The second step is a chlorination process for the separation of actinides (An) from An-Al alloys formed on the cathodes. The chlorination process, in turn, consists of three steps; the distillation of adhered salt (1), the chlorination of An-Al by HCl/Cl2 under formation of AlCl3 and An chlorides (2), and the subsequent sublimation of AlCl3 (3). In the present work UAl2, UAl3, NpAl2, and PuAl2 were chlorinated with HCl(g) in a temperature range between 300 and 400 °C forming UCl4, NpCl4 or PuCl3 as the major An containing phases, respectively. Thermodynamic calculations were carried out to support the experimental work. The results showed a high chlorination efficiency for all used starting materials and indicated that the sublimation step may not be necessary when using HCl(g).

Separation technologies for the recovery and dehydration of alcohols from fermentation broths

EPA Science Inventory

Multi-column distillation followed by molecular sieve adsorption is currently the standard method for producing fuel grade ethanol from dilute fermentation broths in modern corn-to-ethnol facilities. As the liquid biofuels industry transitions to lignocellulosic feedstocks, expan...

Utilization of corn residues for production of the polysaccharide schizophyllan

USDA-ARS?s Scientific Manuscript database

Abundant corn residues include fiber from wet milling operations and distillers' dried grains from dry grind ethanol plants. Biorefineries of the future will utilize such residues for the production of valuable bioproducts, particularly those traditionally produced from fossil fuels. Schizophyllan...

A study on emission characteristics of an EFI engine with ethanol blended gasoline fuels

NASA Astrophysics Data System (ADS)

He, Bang-Quan; Wang, Jian-Xin; Hao, Ji-Ming; Yan, Xiao-Guang; Xiao, Jian-Hua

The effect of ethanol blended gasoline fuels on emissions and catalyst conversion efficiencies was investigated in a spark ignition engine with an electronic fuel injection (EFI) system. The addition of ethanol to gasoline fuel enhances the octane number of the blended fuels and changes distillation temperature. Ethanol can decrease engine-out regulated emissions. The fuel containing 30% ethanol by volume can drastically reduce engine-out total hydrocarbon emissions (THC) at operating conditions and engine-out THC, CO and NO x emissions at idle speed, but unburned ethanol and acetaldehyde emissions increase. Pt/Rh based three-way catalysts are effective in reducing acetaldehyde emissions, but the conversion of unburned ethanol is low. Tailpipe emissions of THC, CO and NO x have close relation to engine-out emissions, catalyst conversion efficiency, engine's speed and load, air/fuel equivalence ratio. Moreover, the blended fuels can decrease brake specific energy consumption.

Production of sensory compounds by means of the yeast Dekkera bruxellensis in different nitrogen sources with the prospect of producing cachaça.

PubMed

Castro Parente, Denise; Vidal, Esteban Espinosa; Leite, Fernanda Cristina Bezerra; de Barros Pita, Will; de Morais, Marcos Antonio

2015-01-01

The distilled spirit made from sugar cane juice, also known as cachaça, is a traditional Brazilian beverage that in recent years has increased its market share among international distilled beverages. Several volatile compounds produced by yeast cells during the fermentation process are responsible for the unique taste and aroma of this drink. The yeast Dekkera bruxellensis has acquired increasing importance in the fermented beverage production, as the different metabolites produced by this yeast may be either beneficial or harmful to the end-product. Since D. bruxellensis is often found in the fermentation processes carried out in ethanol fuel distillation in Brazil, we employed this yeast to analyse the physiological profile and production of aromatic compounds and to examine whether it is feasible to regard it as a cachaça-producing microorganism. The assays were performed on a small scale and simulated the conditions for the production of handmade cachaça. The results showed that the presence of aromatic and branched-chain amino acids in the medium has a strong influence on the metabolism and production of flavours by D. bruxellensis. The assimilation of these alternative nitrogen sources led to different fermentation yields and the production of flavouring compounds. The influence of the nitrogen source on the metabolism of fusel alcohols and esters in D. bruxellensis highlights the need for further studies of the nitrogen requirements to obtain the desired level of sensory compounds in the fermentation. Our results suggest that D. bruxellensis has the potential to play a role in the production of cachaça. Copyright © 2014 John Wiley & Sons, Ltd.

Fouling-Resistant Membranes for Treating Concentrated Brines for Water Reuse in Advanced Energy Systems- Final Technical Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hendren, Zachary; Choi, Young Chul

The high total dissolved solids (TDS) levels in the wastewater quality generated from unconventional oil and gas development make the current state-of-the art approach to water treatment/disposal untenable. Our proposed membrane technology approach addresses the two major challenges associated with this water: 1) the membrane distillation process removes the high TDS content, which is often 8 times higher than that of seawater, and 2) our novel membrane coating prevents the formation of scale that would otherwise pose a significant operational hurdle. This is accomplished through next-generation electrically conductive membranes that mitigate fouling beyond what is currently possible, and allow formore » the flexibility to treat to the water to levels desirable for multiple reuse options, thus reducing fresh water withdrawal, all the way to direct disposal into the environment. The overall project objective was to demonstrate the efficacy of membrane distillation (MD) as a cost-savings technology to treat concentrated brines (such as, but not limited to, produced waters generated from fossil fuel extraction) that have high levels of TDS for beneficial water reuse in power production and other industrial operations as well as agricultural and municipal water uses. In addition, a novel fouling-resistant nanocomposite membrane was developed to reduce the need for chemicals to address membrane scaling due to the precipitation of divalent ions in high-TDS waters and improve overall MD performance via an electrically conductive membrane distillation process (ECMD). This anti-fouling membrane technology platform is based on incorporating carbon nanotubes (CNTs) into the surface layer of existing, commercially available MD membranes. The CNTs impart electrical conductivity to the membrane surface to prevent membrane scaling and fouling when an electrical potential is applied.« less

Alkylcyclohexanes in environmental geochemistry

USGS Publications Warehouse

Hostettler, F.D.; Kvenvolden, K.A.

2002-01-01

The n-alkylated cyclohexanes (CHs) are a homologous series of hydrocarbon compounds that are commonly present in crude oil and refinery products such as diesel fuel. These compounds exhibit specific distribution patterns for different fuel types, providing useful fingerprints for characterizing petroleum products, especially after degradation of n-alkanes has occurred. However, there are no published data to show how these compounds are altered in the environment after long-term spillage of petroleum products. This paper presents two case studies of oil spills that demonstrate the changing distribution patterns resulting from long-term anaerobic microbial degradation. These spills are the 1979 crude-oil spill in Bemidji, Minnesota, and a chronic diesel-fuel spillage from 1953-1991 at Mandan, North Dakota. The alkyl CHs in both spilled oil products are affected by similar biodegradative processes in which the compounds undergo a consistent pattern of loss from the high molecular weight end of the homolog distribution. Degradation results in a measurable increase in the concentrations of the homologs in the lower molecular weight range, a gradual lowering in carbon number of the homolog maximum, and a gradual decrease of the total homolog range from the high molecular weight end. This pattern is the opposite of low-end loss expected with weathering and aerobic biodegradation. The enhancement of the low molecular mass alkyl CH homologs, if not recognized as a degradative pathway of diesel fuel in an anaerobic environment, can potentially be misinterpreted in fuel-oil fingerprinting as deriving from lower distillation-range fuels or admixture of diesel with other fuels.

Life-cycle assessment of corn-based butanol as a potential transportation fuel.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, M.; Wang, M.; Liu, J.

2007-12-31

Butanol produced from bio-sources (such as corn) could have attractive properties as a transportation fuel. Production of butanol through a fermentation process called acetone-butanol-ethanol (ABE) has been the focus of increasing research and development efforts. Advances in ABE process development in recent years have led to drastic increases in ABE productivity and yields, making butanol production worthy of evaluation for use in motor vehicles. Consequently, chemical/fuel industries have announced their intention to produce butanol from bio-based materials. The purpose of this study is to estimate the potential life-cycle energy and emission effects associated with using bio-butanol as a transportation fuel.more » The study employs a well-to-wheels analysis tool--the Greenhouse Gases, Regulated Emissions and Energy Use in Transportation (GREET) model developed at Argonne National Laboratory--and the Aspen Plus{reg_sign} model developed by AspenTech. The study describes the butanol production from corn, including grain processing, fermentation, gas stripping, distillation, and adsorption for products separation. The Aspen{reg_sign} results that we obtained for the corn-to-butanol production process provide the basis for GREET modeling to estimate life-cycle energy use and greenhouse gas emissions. The GREET model was expanded to simulate the bio-butanol life cycle, from agricultural chemical production to butanol use in motor vehicles. We then compared the results for bio-butanol with those of conventional gasoline. We also analyzed the bio-acetone that is coproduced with bio-butanol as an alternative to petroleum-based acetone. Our study shows that, while the use of corn-based butanol achieves energy benefits and reduces greenhouse gas emissions, the results are affected by the methods used to treat the acetone that is co-produced in butanol plants.« less

Methodology for Formulating Diesel Surrogate Fuels with Accurate Compositional, Ignition-Quality, and Volatility Characteristics

DOE PAGES

Mueller, Charles J.; Cannella, William J.; Bruno, Thomas J.; ...

2012-05-22

In this study, a novel approach was developed to formulate surrogate fuels having characteristics that are representative of diesel fuels produced from real-world refinery streams. Because diesel fuels typically consist of hundreds of compounds, it is difficult to conclusively determine the effects of fuel composition on combustion properties. Surrogate fuels, being simpler representations of these practical fuels, are of interest because they can provide a better understanding of fundamental fuel-composition and property effects on combustion and emissions-formation processes in internal-combustion engines. In addition, the application of surrogate fuels in numerical simulations with accurate vaporization, mixing, and combustion models could revolutionizemore » future engine designs by enabling computational optimization for evolving real fuels. Dependable computational design would not only improve engine function, it would do so at significant cost savings relative to current optimization strategies that rely on physical testing of hardware prototypes. The approach in this study utilized the state-of-the-art techniques of 13C and 1H nuclear magnetic resonance spectroscopy and the advanced distillation curve to characterize fuel composition and volatility, respectively. The ignition quality was quantified by the derived cetane number. Two well-characterized, ultra-low-sulfur #2 diesel reference fuels produced from refinery streams were used as target fuels: a 2007 emissions certification fuel and a Coordinating Research Council (CRC) Fuels for Advanced Combustion Engines (FACE) diesel fuel. A surrogate was created for each target fuel by blending eight pure compounds. The known carbon bond types within the pure compounds, as well as models for the ignition qualities and volatilities of their mixtures, were used in a multiproperty regression algorithm to determine optimal surrogate formulations. The predicted and measured surrogate-fuel properties were quantitatively compared to the measured target-fuel properties, and good agreement was found.« less

Production and Purification of Bioethanol from Molasses and Cassava

NASA Astrophysics Data System (ADS)

Maryana, Roni; Wahono, Satriyo Krido

2009-09-01

This research aim to analysis bioethanol purification process. Bioethanol from cassava has been produced in previous research and the ethanol from molasses was taken from Bekonang region. The production of bioethanol from cassava was carried out through several processes such as homogenization, adding of α-amylase, β-amylase and yeast (Saccharomyces c). Two types of laboratory scale distillator have been used, the first type is 50 cm length and 4 cm diameter. The second type distillator is 30 cm length and 9 cm diameter. Both types have been used to distill bioethanol The initial concentration after the fermentation process is 15% for bioethanol from cassava and 20-30% ethanol from molasses. The results of first type distillator are 90% of bioethanol at 50° C and yield 2.5%; 70% of bioethanol at 60° C and yield 11.2%. 32% of bioethanol at 70° C and yield 42%. Meanwhile the second distillator results are 84% of bioethanol at 50° C with yield 12%; 51% of bioethanol at 60° C with yield 35.5%; 20% of bioethanol at 70° C with yield 78.8%; 16% of bioethanol at 80° C with yield 81.6%. The ethanol from molasses has been distillated once times in Bekonang after the fermentation process, the yield was about 20%. In this research first type distillator and the initial concentration is 20% has been used. The results are 95% of bioethanol at 75° C with yield 8%; 94% of bioethanol at 85° C with yield 13% when vacuum pump was used. And 94% of bioethanol at 90° C with yield 3.7% and 94% of bioethanol at 96° C with yield 10.27% without vacuum pump. The bioethanol purification use second type distillator more effective than first type distillator.

Microbial development in distillers wet grains produced during fuel ethanol production from corn (Zea mays).

PubMed

Lehman, R Michael; Rosentrater, Kurt A

2007-09-01

Distillers grains are coproduced with ethanol and carbon dioxide during the production of fuel ethanol from the dry milling and fermentation of corn grain, yet there is little basic microbiological information on these materials. We undertook a replicated field study of the microbiology of distillers wet grains (DWG) over a 9 day period following their production at an industrial fuel ethanol plant. Freshly produced DWG had a pH of about 4.4, a moisture content of about 53.5% (wet mass basis), and 4 x 10(5) total yeast cells/g dry mass, of which about 0.1% were viable. Total bacterial cells were initially below detection limits (ca. 10(6) cells/g dry mass) and then were estimated to be approximately 5 x 10(7) cells/g dry mass during the first 4 days following production. Culturable aerobic heterotrophic organisms (fungi plus bacteria) ranged between 10(4) and 10(5) CFU/g dry mass during the initial 4 day period, and lactic acid bacteria increased from 36 to 10(3) CFU/g dry mass over this same period. At 9 days, total viable bacteria and yeasts and (or) molds topped 10(8) CFU/g dry mass and lactic acid bacteria approached 10(6) CFU/g dry mass. Community phospholipid fatty acid analysis indicated a stable microbial community over the first 4 days of storage. Thirteen morphologically distinct isolates were recovered, of which 10 were yeasts and molds from 6 different genera, 2 were strains of the lactic-acid-producing Pediococcus pentosaceus and only one was an aerobic heterotrophic bacteria, Micrococcus luteus. The microbiology of DWG is fundamental to the assessment of spoilage, deleterious effects (e.g., toxins), or beneficial effects (e.g., probiotics) in its use as feed or in alternative applications.

Hydrocarbon bio-jet fuel from bioconversion of poplar biomass: life cycle assessment.

PubMed

Budsberg, Erik; Crawford, Jordan T; Morgan, Hannah; Chin, Wei Shan; Bura, Renata; Gustafson, Rick

2016-01-01

Bio-jet fuels compatible with current aviation infrastructure are needed as an alternative to petroleum-based jet fuel to lower greenhouse gas emissions and reduce dependence on fossil fuels. Cradle to grave life cycle analysis is used to investigate the global warming potential and fossil fuel use of converting poplar biomass to drop-in bio-jet fuel via a novel bioconversion platform. Unique to the biorefinery designs in this research is an acetogen fermentation step. Following dilute acid pretreatment and enzymatic hydrolysis, poplar biomass is fermented to acetic acid and then distilled, hydroprocessed, and oligomerized to jet fuel. Natural gas steam reforming and lignin gasification are proposed to meet hydrogen demands at the biorefineries. Separate well to wake simulations are performed using the hydrogen production processes to obtain life cycle data. Both biorefinery designs are assessed using natural gas and hog fuel to meet excess heat demands. Global warming potential of the natural gas steam reforming and lignin gasification bio-jet fuel scenarios range from CO2 equivalences of 60 to 66 and 32 to 73 g MJ(-1), respectively. Fossil fuel usage of the natural gas steam reforming and lignin gasification bio-jet fuel scenarios range from 0.78 to 0.84 and 0.71 to 1.0 MJ MJ(-1), respectively. Lower values for each impact category result from using hog fuel to meet excess heat/steam demands. Higher values result from using natural gas to meet the excess heat demands. Bio-jet fuels produced from the bioconversion of poplar biomass reduce the global warming potential and fossil fuel use compared with petroleum-based jet fuel. Production of hydrogen is identified as a major source of greenhouse gas emissions and fossil fuel use in both the natural gas steam reforming and lignin gasification bio-jet simulations. Using hog fuel instead of natural gas to meet heat demands can help lower the global warming potential and fossil fuel use at the biorefineries.

Multivariable model predictive control design of reactive distillation column for Dimethyl Ether production

NASA Astrophysics Data System (ADS)

Wahid, A.; Putra, I. G. E. P.

2018-03-01

Dimethyl ether (DME) as an alternative clean energy has attracted a growing attention in the recent years. DME production via reactive distillation has potential for capital cost and energy requirement savings. However, combination of reaction and distillation on a single column makes reactive distillation process a very complex multivariable system with high non-linearity of process and strong interaction between process variables. This study investigates a multivariable model predictive control (MPC) based on two-point temperature control strategy for the DME reactive distillation column to maintain the purities of both product streams. The process model is estimated by a first order plus dead time model. The DME and water purity is maintained by controlling a stage temperature in rectifying and stripping section, respectively. The result shows that the model predictive controller performed faster responses compared to conventional PI controller that are showed by the smaller ISE values. In addition, the MPC controller is able to handle the loop interactions well.

H-Coal process and plant design

DOEpatents

Kydd, Paul H.; Chervenak, Michael C.; DeVaux, George R.

1983-01-01

A process for converting coal and other hydrocarbonaceous materials into useful and more valuable liquid products. The process comprises: feeding coal and/or other hydrocarbonaceous materials with a hydrogen-containing gas into an ebullated catalyst bed reactor; passing the reaction products from the reactor to a hot separator where the vaporous and distillate products are separated from the residuals; introducing the vaporous and distillate products from the separator directly into a hydrotreater where they are further hydrogenated; passing the residuals from the separator successively through flash vessels at reduced pressures where distillates are flashed off and combined with the vaporous and distillate products to be hydrogenated; transferring the unseparated residuals to a solids concentrating and removal means to remove a substantial portion of solids therefrom and recycling the remaining residual oil to the reactor; and passing the hydrogenated vaporous and distillate products to an atmospheric fractionator where the combined products are fractionated into separate valuable liquid products. The hydrogen-containing gas is generated from sources within the process.

Recovery of polyphenols from rose oil distillation wastewater using adsorption resins--a pilot study.

PubMed

Rusanov, Krasimir; Garo, Eliane; Rusanova, Mila; Fertig, Orlando; Hamburger, Matthias; Atanassov, Ivan; Butterweck, Veronika

2014-11-01

The production of rose oil from rose flowers by water steam distillation leaves a water fraction of the distillate as main part of the waste. Therefore, the rose oil distillation wastewater represents a serious environmental problem due to the high content of polyphenols which are difficult to decompose and have to be considered as biopollutants when discarded into the drainage system and rivers. On the other hand, natural polyphenols are valuable compounds with useful properties as bioactive substances. Until now there is no established practice for processing of rose oil distillation wastewater and utilization of contained substances. Thus, it was the aim of this study to develop a strategy to separate this wastewater into a polyphenol depleted water fraction and a polyphenol enriched fraction which could be developed into innovative value-added products. In a first step, the phytochemical profile of rose oil distillation wastewater was determined. Its HPLC-PDA-MS analysis revealed the presence of flavan-3-ols, flavanones, flavonols and flavones. In a second step, the development of a stepwise concentration of rose oil distillation wastewater was performed. The concentration process includes a filtration process to eliminate suspended solids in the wastewater, followed by adsorption of the contained phenolic compounds onto adsorption resins (XAD and SP). Finally, desorption of the polyphenol fraction from the resin matrix was achieved using ethanol and/or aqueous ethanol. The result of the process was a wastewater low in soluble organic compounds and an enriched polyphenol fraction (RF20 SP-207). The profile of this fraction was similar to that of rose oil distillation wastewater and showed the presence of flavonols such as quercetin and kaempferol glycosides as major metabolites. These compounds were isolated from the enriched polyphenol fraction and their structures confirmed by NMR. In summary, a pilot medium scale system was developed using adsorption resins for the recovery of polyphenols from rose oil distillation wastewater suggesting an industrial scalability of the process. Georg Thieme Verlag KG Stuttgart · New York.

The Impact of Household Hazardous Wastes on Landfill Leachates.

DTIC Science & Technology

1988-05-01

Cleaners Wood/Metal Petroleum Cleaners/Polishers Distillates Petroleum Naptha Turpentine Isopropyl Alcohol Automotive Oil/Fuel Additives Xylene Products...the propensity to " clean house" makes projecting an annual rate of disposal a very difficult task. Also, mean amount of waste per participant

Membrane-based recovery and dehydration of alcohols from fermentation broths - of materials and modules

EPA Science Inventory

Distillation combined with molecular sieve dehydration is the current state of the art for fuel grade ethanol production from fermentation broths. As the liquid biofuels industry transitions to lignocellulosic feedstocks, expands the end product portfolio to include other alcoho...

Energy efficient recovery and dehydration of ethanol from fermentation broths by Membrane Assisted Vapor Stripping technology

EPA Science Inventory

Distillation combined with molecular sieve dehydration is the current state of the art for fuel grade ethanol production from fermentation broths. To improve the sustainability of bioethanol production, energy efficient separation alternatives are needed, particularly for lower ...

At a Glance - Growth of DDGS

USDA-ARS?s Scientific Manuscript database

NCARL is proud of its active partnerships among industry, academic, and extension specialists, and we continue to pursue improved uses and values for distillers grain. We aim to augment both the livestock industry as well as fuel ethanol manufacturers with our research programs. The importance of ...

Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stephen Bergin

2011-03-30

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfurmore » middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.« less

Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stephen Bergin

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfurmore » middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.« less

Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stephen Bergin

2011-03-30

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfurmore » middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.« less

Montana Integrated Carbon to Liquids (ICTL) Demonstration Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiato, Rocco A.; Sharma, Ramesh; Allen, Mark

Integrated carbon-to-liquids technology (ICTL) incorporates three basic processes for the conversion of a wide range of feedstocks to distillate liquid fuels: (1) Direct Microcatalytic Coal Liquefaction (MCL) is coupled with biomass liquefaction via (2) Catalytic Hydrodeoxygenation and Isomerization (CHI) of fatty acid methyl esters (FAME) or trigylceride fatty acids (TGFA) to produce liquid fuels, with process derived (3) CO 2 Capture and Utilization (CCU) via algae production and use in BioFertilizer for added terrestrial sequestration of CO 2, or as a feedstock for MCL and/or CHI. This novel approach enables synthetic fuels production while simultaneously meeting EISA 2007 Section 526more » targets, minimizing land use and water consumption, and providing cost competitive fuels at current day petroleum prices. ICTL was demonstrated with Montana Crow sub-bituminous coal in MCL pilot scale operations at the Energy and Environmental Research Center at the University of North Dakota (EERC), with related pilot scale CHI studies conducted at the University of Pittsburgh Applied Research Center (PARC). Coal-Biomass to Liquid (CBTL) Fuel samples were evaluated at the US Air Force Research Labs (AFRL) in Dayton and greenhouse tests of algae based BioFertilizer conducted at Montana State University (MSU). Econometric modeling studies were also conducted on the use of algae based BioFertilizer in a wheat-camelina crop rotation cycle. We find that the combined operation is not only able to help boost crop yields, but also to provide added crop yields and associated profits from TGFA (from crop production) for use an ICTL plant feedstock. This program demonstrated the overall viability of ICTL in pilot scale operations. Related work on the Life Cycle Assessment (LCA) of a Montana project indicated that CCU could be employed very effectively to reduce the overall carbon footprint of the MCL/CHI process. Plans are currently being made to conduct larger-scale process demonstration studies of the CHI process in combination with CCU to generate synthetic jet and diesel fuels from algae and algae fertilized crops. Site assessment and project prefeasibility studies are planned with a major EPC firm to determine the overall viability of ICTL technology commercialization with Crow coal resources in south central Montana.« less

Distilling entanglement with noisy operations

NASA Astrophysics Data System (ADS)

Chang, Jinho; Bae, Joonwoo; Kwon, Younghun

Entanglement distillation is a fundamental task in quantum information processing. It not only extracts entanglement out of corrupted systems but also leads to protecting systems of interest against intervention with environment. In this work, we consider a realistic scenario of entanglement distillation where noisy quantum operations are applied. In particular, the two-way distillation protocol that tolerates the highest error rate is considered. We show that among all types of noise there are only four equivalence classes according to the distillability condition. Since the four classes are connected by local unitary transformations, our results can be used to improve entanglement distillability in practice when entanglement distillation is performed in a realistic setting.

Two-stage coal liquefaction process

DOEpatents

Skinner, Ronald W.; Tao, John C.; Znaimer, Samuel

1985-01-01

An improved SRC-I two-stage coal liquefaction process which improves the product slate is provided. Substantially all of the net yield of 650.degree.-850.degree. F. heavy distillate from the LC-Finer is combined with the SRC process solvent, substantially all of the net 400.degree.-650.degree. F. middle distillate from the SRC section is combined with the hydrocracker solvent in the LC-Finer, and the initial boiling point of the SRC process solvent is increased sufficiently high to produce a net yield of 650.degree.-850.degree. F. heavy distillate of zero for the two-stage liquefaction process.

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

DOEpatents

Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

2001-01-01

A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.

Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel

DOEpatents

Herrmann, Steven Douglas

2014-05-27

Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

Extraction of essential oil from baby Java orange (Citrus sinensis) solid waste using water and steam distillation

NASA Astrophysics Data System (ADS)

Dewi, I. A.; Prastyo, A. M.; Wijana, S.

2018-03-01

Baby java orange (Citrus sinensis) is commonly consumed as juice. Processing of baby java orange leaves organic waste which consist of the mesocarp, exocarp, seed, and wall of the orange. Therefore, it is necessary to process baby java orange waste to be valuable products. The purpose of this study was to provide added value to unutilized baby java orange waste, and to find out the pretreatment of time-delay process that maximize the yield of essential oil produced. Essential oil processing can be done by water and steam distillation. The study used randomized block design with one factor namely distillation time-delay process by air drying consisted of 4 levels i.e. the distillation delay for 2, 4, 6, and 8 days. The best treatment was determined based on the yield. The best essential oil from baby java orange waste was obtained from the treatment of distillation delay-process of 8 days. This pretreatment generated yield value of 0.63% with moisture content of 24.21%. By estimating the price of essential oil showed that this effort not only reduced the bulky organic waste but also provided potential economical value.

Corrosion Inhibition in High Temperature Environment

DTIC Science & Technology

1993-06-28

levels of sodium , sulfur, and vanadium. Low quality 12 marine residual fuels, for example, may contain up to 0.2 weight 13 percent ash which contains...appreciable amounts of sodium , up to 5 14 weight percent sulfur and up to 0.06 weight percent or 600 ppm 15 vanadium. Low grades of marine distillate...fuels are allowed up to 16 0.05 weight percent ash which contains appreciable amounts of 17 sodium , up to 2 weight percent sulfur and up to 100 ppm

Fuel Conversion from Natural Gas to Distillate Fuel Oil - Chemplex

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

Literature Review of Cetane Number and Its Correlations.

DTIC Science & Technology

1987-05-01

comprising distillate and residual fuels, Zeelenberg , et al. (141 obtained a correlation between CCAI and ignition delay. B. Calculated Ignition...1: An Improved Cetane Number Predictor," SAE Paper 861519, (1986). 14. Zeelenberg , A. P., Fijn Van Draat, H. J., and Barker, H. L., "The Ignition

What drives petroleum product prices

EIA Publications

2017-01-01

This new section discusses the various factors that influence the prices of gasoline and distillate fuel oil—the two most-consumed petroleum products in the United States. Charts detailing prices, consumption, production, inventories, and trade for both petroleum products will be updated each month in the Short-Term Energy Outlook.

The Chemistry of Deposit Formation in Distillate Fuels,

DTIC Science & Technology

1986-01-01

identified as groups of multiple isomers of the alkylphenols , alkylnaphthols and alkylphenylphenols listed in Table VI. Ion chromatograms for isomers...matching was achieved. For example, Figure 8 shows the reconstructed ion chromatogram for m/z 136 (C3- alkylphenols ), which corresponds to peak cluster 13 in

18 CFR 281.302 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Applicability. 281.302 Section 281.302 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... than a diesel engine or turbine designed to use distillate fuels as the only alternative to natural gas...

18 CFR 281.302 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Applicability. 281.302 Section 281.302 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... than a diesel engine or turbine designed to use distillate fuels as the only alternative to natural gas...

18 CFR 281.302 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Applicability. 281.302 Section 281.302 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... than a diesel engine or turbine designed to use distillate fuels as the only alternative to natural gas...

18 CFR 281.302 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Applicability. 281.302 Section 281.302 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... than a diesel engine or turbine designed to use distillate fuels as the only alternative to natural gas...

18 CFR 281.302 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Applicability. 281.302 Section 281.302 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT... than a diesel engine or turbine designed to use distillate fuels as the only alternative to natural gas...

40 CFR 61.300 - Applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... under subpart FF of this part), gasoline, crude oil, natural gas liquids, petroleum distillates (e.g., fuel oil, diesel, or kerosene), or benzene-laden liquid from coke by-product recovery plants. (b) Any affected facility under paragraph (a) of this section which loads only liquid containing less than 70...

40 CFR 61.300 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... under subpart FF of this part), gasoline, crude oil, natural gas liquids, petroleum distillates (e.g., fuel oil, diesel, or kerosene), or benzene-laden liquid from coke by-product recovery plants. (b) Any affected facility under paragraph (a) of this section which loads only liquid containing less than 70...

40 CFR 61.300 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... under subpart FF of this part), gasoline, crude oil, natural gas liquids, petroleum distillates (e.g., fuel oil, diesel, or kerosene), or benzene-laden liquid from coke by-product recovery plants. (b) Any affected facility under paragraph (a) of this section which loads only liquid containing less than 70...

40 CFR 61.300 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... under subpart FF of this part), gasoline, crude oil, natural gas liquids, petroleum distillates (e.g., fuel oil, diesel, or kerosene), or benzene-laden liquid from coke by-product recovery plants. (b) Any affected facility under paragraph (a) of this section which loads only liquid containing less than 70...

40 CFR 61.300 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... under subpart FF of this part), gasoline, crude oil, natural gas liquids, petroleum distillates (e.g., fuel oil, diesel, or kerosene), or benzene-laden liquid from coke by-product recovery plants. (b) Any affected facility under paragraph (a) of this section which loads only liquid containing less than 70...

At a Glance – Pelleting of DDGS

USDA-ARS?s Scientific Manuscript database

NCARL is proud of its active partnership among industry, academic, and extension specialists, and we continue to pursue improved uses and values for distillers grain. We aim to augment both the livestock industry as well as fuel ethanol manufacturers with our research programs. Pelleting is one wa...

Floral aroma improvement of Muscat spirits by packed column distillation with variable internal reflux.

PubMed

Matias-Guiu, Pau; Rodríguez-Bencomo, Juan José; Orriols, Ignacio; Pérez-Correa, José Ricardo; López, Francisco

2016-12-15

The organoleptic quality of wine distillates depends on raw materials and the distillation process. Previous work has shown that rectification columns in batch distillation with fixed reflux rate are useful to obtain distillates or distillate fractions with enhanced organoleptic characteristics. This study explores variable reflux rate operating strategies to increase the levels of terpenic compounds in specific distillate fractions to emphasize its floral aroma. Based on chemical and sensory analyses, two distillate heart sub-fractions obtained with the best operating strategy found, were compared with a distillate obtained in a traditional alembic. Results have shown that a drastic reduction of the reflux rate at an early stage of the heart cut produced a distillate heart sub-fraction with a higher concentration of terpenic compounds and lower levels of negative aroma compounds. Therefore, this sub-fraction presented a much more noticeable floral aroma than the distillate obtained with a traditional alembic. Copyright © 2016 Elsevier Ltd. All rights reserved.

Recent trends in aviation turbine fuel properties

NASA Technical Reports Server (NTRS)

Friedman, R.

1982-01-01

Plots and tables, compiled from Department of Energy (and predecessor agency) inspection reports from 1969 to 1980, present ranges, averages, extremes, and trends for most of the 22 properties of Jet A aviation turbine fuel. In recent years, average values of aromatics content, mercaptan sulfur content, distillation temperature of 10 percent recovered, smoke point, and freezing point show small but recognizable trends toward their specification limits. About 80 percent of the fuel samples had at least one property near specification, defined as within a standard band about the specification limit. By far the most common near-specification properties were aromatics content, smoke point, and freezing point.

Design and implementation of a control structure for quality products in a crude oil atmospheric distillation column.

PubMed

Sotelo, David; Favela-Contreras, Antonio; Sotelo, Carlos; Jiménez, Guillermo; Gallegos-Canales, Luis

2017-11-01

In recent years, interest for petrochemical processes has been increasing, especially in refinement area. However, the high variability in the dynamic characteristics present in the atmospheric distillation column poses a challenge to obtain quality products. To improve distillates quality in spite of the changes in the input crude oil composition, this paper details a new design of a control strategy in a conventional crude oil distillation plant defined using formal interaction analysis tools. The process dynamic and its control are simulated on Aspen HYSYS ® dynamic environment under real operating conditions. The simulation results are compared against a typical control strategy commonly used in crude oil atmospheric distillation columns. Copyright © 2017 ISA. Published by Elsevier Ltd. All rights reserved.

Hydrogen Generator

NASA Technical Reports Server (NTRS)

1978-01-01

Another spinoff from spacecraft fuel cell technology is the portable hydrogen generator shown. Developed by General Electric Company, it is an aid to safer operation of systems that use hydrogen-for example, gas chromatographs, used in laboratory analysis of gases. or flame ionization detectors used as $ollution monitors. The generator eliminates the need for high-pressure hydrogen storage bottles, which can be a safety hazard, in laboratories, hospitals and industrial plants. The unit supplies high-purity hydrogen by means of an electrochemical process which separates the hydrogen and oxygen in distilled water. The oxygen is vented away and the hydrogen gas is stored within the unit for use as needed. GE's Aircraft Equipment Division is producing about 1,000 of the generators annually.

Activated charcoal filters: Water treatment, pollution control, and industrial applications. October 1970-October 1989 (Citations from the US Patent data base). Report for October 1970-October 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bibliography contains citations of selected patents concerning activated charcoal filters and their applications in water treatment, pollution control, and industrial processes. Filtering methods and equipment for air and water purification, industrial distillation and extraction, industrial leaching, and filtration of toxic materials and contaminants are described. Applications include drinking water purification, filtering beverages, production of polymer materials, solvent and metal recovery, waste conversion, automotive fuel and exhaust systems, swimming-pool filtration, tobacco-smoke filters, kitchen ventilators, medical filtration treatment, and odor-absorbing materials. (This updated bibliography contains 173 citations, 12 of which are new entries to the previous edition.)

Activated-charcoal filters: Water treatment, pollution control, and industrial applications. January 1970-August 1989 (Citations from the US Patent data base). Report for January 1970-August 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bibliography contains citations of selected patents concerning activated charcoal filters and their applications in water treatment, pollution control, and industrial processes. Filtering methods and equipment for air and water purification, industrial distillation and extraction, industrial leaching, and filtration of toxic materials and contaminants are described. Applications include drinking-water purification, filtering beverages, production of polymer materials, solvent and metal recovery, waste conversion, automotive fuel and exhaust systems, swimming-pool filtration, tobacco-smoke filters, kitchen ventilators, medical-filtration treatment, and odor absorbing materials. (This updated bibliography contains 161 citations, 32 of which are new entries to the previous edition.)

Costs of Pelleting to Enhance the Logistics of Distillers Grains Shipping

USDA-ARS?s Scientific Manuscript database

Biofuels, especially corn-based ethanol, can help meet some of the increasing demand for transportation fuels. Currently, the most heavily utilized substrate is corn grain, which is readily converted into ethanol at a relatively low cost compared to other biomass sources. The production of ethanol...

Detail of north side of Test Stand 'A' base, showing ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Detail of north side of Test Stand 'A' base, showing tanks for distilled water (left), fuel (center), and gaseous nitrogen (right). Other tanks present for tests were removed before this image was taken. - Jet Propulsion Laboratory Edwards Facility, Test Stand A, Edwards Air Force Base, Boron, Kern County, CA

Review of Physical and Chemical Methods for Characterization of Fuels

DTIC Science & Technology

1981-12-01

Reversed-phase chromatography REF Refractometry CAL Calorimetry POT Potentiometry CC Coordination chromatography MSB Mossbauer spectroscopy FS Flame...petroleum distillates ......... .... ........................ . .... A-2-63 Determination of the nitrogen content of shale oil furnace oil by refractometry ... refractometry ............................................ A-2-70 SAPONIFICATION NUMBER Saponification number of petroleum products.......................A-2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bruner, R.H.

Male and female Fischer-344 rats and female C57/BL6 mice were subjected to subchronic and chronic inhalation exposures to a variety of distillate and synthetic hydrocarbon fuels of military interest. In general, male rats exposed to all agents developed a dose-related nephropathy which was not observed in females, controls, or exposed mice. Kidney lesions consisted of greatly increased cytoplasmic hyaline droplets in proximal tubular epithelium, necrosis of proximal tubular cells, and intratubular plugs of necrotic cell debris at the junction of the outer and inner stripe of the outer medulla. Following exposure, males that were held for lifetime oncogenic evaluation exhibitedmore » abundant mineralized casts in medullary tubules, multifocal to diffuse papillary hyperplasia of pelvic urothelium, and accentuated tubular degeneration compatible with progressive nephrosis of old rats. Male rats exposed six hours/day, five days/week for one year to two synthetic hydrocarbon missile fuels had significant increases in renal cell tumors, whereas males exposed for 90 days continuously to various distillate fuels failed to develop increased kidney neoplasia following lifespan observation. The pathogenic mechanisms remain unclear, but it is proposed that kidney changes may be related to an inability of renal tubular cells to efficiently digest resorbed alpha 2u globulin - a special protein of male rats which is synthesized in the liver.« less

Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brinkman, D.W.; Whisman, M.L.

In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in whichmore » experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.« less

Quantum key distillation from Gaussian states by Gaussian operations.

PubMed

Navascués, M; Bae, J; Cirac, J I; Lewestein, M; Sanpera, A; Acín, A

2005-01-14

We study the secrecy properties of Gaussian states under Gaussian operations. Although such operations are useless for quantum distillation, we prove that it is possible to distill a secret key secure against any attack from sufficiently entangled Gaussian states with nonpositive partial transposition. Moreover, all such states allow for key distillation, when Eve is assumed to perform finite-size coherent attacks before the reconciliation process.

Renewable liquid fuels from catalytic reforming of biomass-derived oxygenated hydrocarbons

NASA Astrophysics Data System (ADS)

Barrett, Christopher J.

Diminishing fossil fuel reserves and growing concerns about global warming require the development of sustainable sources of energy. Fuels for use in the transportation sector must have specific physical properties that allow for efficient distribution, storage, and combustion; these requirements are currently fulfilled by petroleum-derived liquid fuels. The focus of this work has been the development of two new biofuels that have the potential to become widely used transportation fuels from carbohydrate intermediates. Our first biofuel has cetane numbers ranging from 63 to 97 and is comprised of C7 to C15 straight chain alkanes. These alkanes can be blended with diesel like fuels or with P-series biofuel. Production involves a solid base catalyzed aldol condensation with mixed Mg-Al-oxide between furfural or 5-hydroxymethylfurfural (HMF) and acetone, followed by hydrogenation over Pd/Al2O3, and finally hydrogenation/dehydration over Pt/SiO2-Al2O3. Water was the solvent for all process steps, except for the hydrogenation/dehydration stage where hexadecane was co-fed to spontaneously separate out all alkane products and eliminate the need for energy intensive distillation. A later optimization identified Pd/MgO-ZrO2 as a hydrothermally stable bifunctional catalyst to replace Pd/Al2O3 and the hydrothermally unstable Mg-Al-oxide catalysts along with optimizing process parameters, such as temperature and molar ratios of reactants to maximize yields to heavier alkanes. Our second biofuel involved creating an improved process to produce HMF through the acid-catalyzed dehydration of fructose in a biphasic reactor. Additionally, we developed a technique to further convert HMF into 2,5-dimethylfuran (DMF) by hydrogenolysis of C-O bonds over a copper-ruthenium catalyst. DMF has many properties that make it a superior blending agent to ethanol: it has a high research octane number at 119, a 40% higher energy density than ethanol, 20 K higher boiling point, and is insoluble in water unlike ethanol. Continued work identified the cause of copper catalyst deactivation in HMF hydrogenolysis to be coking, minimized coking through varying temperature, pressure, solvent, and catalyst process variables, and identified a suitable regeneration technique through reduction.

Techno-economic assessment of hybrid extraction and distillation processes for furfural production from lignocellulosic biomass.

PubMed

Nhien, Le Cao; Long, Nguyen Van Duc; Kim, Sangyong; Lee, Moonyong

2017-01-01

Lignocellulosic biomass is one of the most promising alternatives for replacing mineral resources to overcome global warming, which has become the most important environmental issue in recent years. Furfural was listed by the National Renewable Energy Laboratory as one of the top 30 potential chemicals arising from biomass. However, the current production of furfural is energy intensive and uses inefficient technology. Thus, a hybrid purification process that combines extraction and distillation to produce furfural from lignocellulosic biomass was considered and investigated in detail to improve the process efficiency. This effective hybrid process depends on the extracting solvent, which was selected based on a comprehensive procedure that ranged from solvent screening to complete process design. Various solvents were first evaluated in terms of their extraction ability. Then, the most promising solvents were selected to study the separation feasibility. Eventually, processes that used the three best solvents (toluene, benzene, and butyl chloride) were designed and optimized in detail using Aspen Plus. Sustainability analysis was performed to evaluate these processes in terms of their energy requirements, total annual costs (TAC), and carbon dioxide (CO 2 ) emissions. The results showed that butyl chloride was the most suitable solvent for the hybrid furfural process because it could save 44.7% of the TAC while reducing the CO 2 emissions by 45.5% compared to the toluene process. In comparison with the traditional purification process using distillation, this suggested hybrid extraction/distillation process can save up to 19.2% of the TAC and reduce 58.3% total annual CO 2 emissions. Furthermore, a sensitivity analysis of the feed composition and its effect on the performance of the proposed hybrid system was conducted. Butyl chloride was found to be the most suitable solvent for the hybrid extraction/distillation process of furfural production. The proposed hybrid sequence was more favorable than the traditional distillation process when the methanol fraction of the feed stream was <3% and more benefit could be obtained when that fraction decreased.

Development of a Nonlinear Soft-Sensor Using a GMDH Network for a Refinery Crude Distillation Tower

NASA Astrophysics Data System (ADS)

Fujii, Kenzo; Yamamoto, Toru

In atmospheric distillation processes, the stabilization of processes is required in order to optimize the crude-oil composition that corresponds to product market conditions. However, the process control systems sometimes fall into unstable states in the case where unexpected disturbances are introduced, and these unusual phenomena have had an undesirable affect on certain products. Furthermore, a useful chemical engineering model has not yet been established for these phenomena. This remains a serious problem in the atmospheric distillation process. This paper describes a new modeling scheme to predict unusual phenomena in the atmospheric distillation process using the GMDH (Group Method of Data Handling) network which is one type of network model. According to the GMDH network, the model structure can be determined systematically. However, the least squares method has been commonly utilized in determining weight coefficients (model parameters). Estimation accuracy is not entirely expected, because the sum of squared errors between the measured values and estimates is evaluated. Therefore, instead of evaluating the sum of squared errors, the sum of absolute value of errors is introduced and the Levenberg-Marquardt method is employed in order to determine model parameters. The effectiveness of the proposed method is evaluated by the foaming prediction in the crude oil switching operation in the atmospheric distillation process.

40 CFR 80.84 - Treatment of interface and transmix.

Code of Federal Regulations, 2010 CFR

2010-07-01

... processing facility means any refinery that produces TGP from transmix by distillation or other refining processes, but does not produce gasoline by processing crude oil. (5) Transmix processor means any person... Test Method for Distillation of Petroleum Products at Atmospheric Pressure”, which is incorporated by...

Membrane augmented distillation to separate solvents from water

DOEpatents

Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

2012-09-11

Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

Coal Technology Program progress report for April 1976

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

In the Hydrocarbonization Research program, two successful experiments were completed in the bench-scale hydrocarbonizer. A settling test at a lower temperature (390/sup 0/F) using 20 percent toluene in Solvent Refined Coal (SRC) Unfiltered Oil (UFO) produced a 30 percent clarified product in 2 hr. Characterization tests include distillation curves for Wilsonville's SRC-UFO and a particle size distribution of Pittsburg and Midway Coal Mining Company's (PAMCO) SRC-UFO. Studies of intermediate-temperature pyrolysis of large blocks have been maintained with char samples continuing to demonstrate pyrophoricity, even after heating to 700/sup 0/C. Simulated distillation analysis of tars produced by the last eight experimentsmore » are being compared with those performed at Laramie upon tars produced by the Hanna No. 2 experiment. In Coal-Fueled MIUS, stainless steel tubing to be used in one of the furnace tube bundles was ordered and the bid package for the furnace completed. Tests continued on the coal feed system and with the cold flow fluidized bed model. For the Synthoil process, flow diagrams, material balances, and utilities requirements were completed for the entire facility. For the Hydrocarbonization process, flowsheets were reviewed for compatibility; equipment lists were brought up to date; and utilities requirements were compiled from the individual flowsheets. The char recovery and storage subsystem flowsheet was completed. (auth)« less

40 CFR 60.665 - Reporting and recordkeeping requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Distillation Operations § 60.665 Reporting and recordkeeping requirements. (a) Each owner or operator subject... of recovery equipment or a distillation unit; (2) Any recalculation of the TRE index value performed... distillation process unit containing the affected facility. These must be reported as soon as possible after...

40 CFR 60.665 - Reporting and recordkeeping requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Distillation Operations § 60.665 Reporting and recordkeeping requirements. (a) Each owner or operator subject... of recovery equipment or a distillation unit; (2) Any recalculation of the TRE index value performed... distillation process unit containing the affected facility. These must be reported as soon as possible after...

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 6, October 1--December 31, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-31

The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coalmore » gasifiers. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology will be integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading. An off-site product testing program will be conducted to demonstrate the suitability of the methanol product as a transportation fuel and as a fuel for stationary applications for small modular electric power generators for distributed power.« less

40 CFR 63.680 - Applicability and designation of affected sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... for the treatment, recycling, or recovery of off-site material. Distillation means a process, either... equilibrium within the distillation unit. (ii) Fractionation process used for the treatment, recycling, or... process used for the treatment, recycling, or recovery of off-site material. Thin-film evaporation means a...

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

DOEpatents

Comolli, Alfred G.; Lee, Lap-Keung

2001-01-01

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Thermodynamic Investigation of the Reduction-Distillation Process for Rare Earth Metals Production

NASA Astrophysics Data System (ADS)

Judge, W. D.; Azimi, G.

2017-10-01

Owing to their high vapor pressure, the four rare earth metals samarium, europium, thulium, and ytterbium are produced by reduction-distillation whereby their oxides are reduced with metallic lanthanum in vacuo, and the produced metal is subsequently vaporized off. Here, we performed a thorough thermodynamic investigation to establish a fundamental understanding of the reduction-distillation process. Thermodynamic functions including vapor pressures, Gibbs free energies, and enthalpies of reaction were calculated and compared with available experimental data. Furthermore, the kinetics of the process was explored and theoretical evaporation rates were calculated from thermodynamic data. The thermodynamic model developed in this work can help optimize processing conditions to maximize the yield and improve the overall process.

Process for converting heavy oil deposited on coal to distillable oil in a low severity process

DOEpatents

Ignasiak, Teresa; Strausz, Otto; Ignasiak, Boleslaw; Janiak, Jerzy; Pawlak, Wanda; Szymocha, Kazimierz; Turak, Ali A.

1994-01-01

A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

Neuro-estimator based GMC control of a batch reactive distillation.

PubMed

Prakash, K J Jithin; Patle, Dipesh S; Jana, Amiya K

2011-07-01

In this paper, an artificial neural network (ANN)-based nonlinear control algorithm is proposed for a simulated batch reactive distillation (RD) column. In the homogeneously catalyzed reactive process, an esterification reaction takes place for the production of ethyl acetate. The fundamental model has been derived incorporating the reaction term in the model structure of the nonreactive distillation process. The process operation is simulated at the startup phase under total reflux conditions. The open-loop process dynamics is also addressed running the batch process at the production phase under partial reflux conditions. In this study, a neuro-estimator based generic model controller (GMC), which consists of an ANN-based state predictor and the GMC law, has been synthesized. Finally, this proposed control law has been tested on the representative batch reactive distillation comparing with a gain-scheduled proportional integral (GSPI) controller and with its ideal performance (ideal GMC). Copyright © 2011 ISA. Published by Elsevier Ltd. All rights reserved.

Experiments on water detritiation and cryogenic distillation at TLK; Impact on ITER fuel cycle subsystems interfaces

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cristescu, I.; Cristescu, I. R.; Doerr, L.

2008-07-15

The ITER Isotope Separation System (ISS) and Water Detritiation System (WDS) should be integrated in order to reduce potential chronic tritium emissions from the ISS. This is achieved by routing the top (protium) product from the ISS to a feed point near the bottom end of the WDS Liquid Phase Catalytic Exchange (LPCE) column. This provides an additional barrier against ISS emissions and should mitigate the memory effects due to process parameter fluctuations in the ISS. To support the research activities needed to characterize the performances of various components for WDS and ISS processes under various working conditions and configurationsmore » as needed for ITER design, an experimental facility called TRENTA representative of the ITER WDS and ISS protium separation column, has been commissioned and is in operation at TLK The experimental program on TRENTA facility is conducted to provide the necessary design data related to the relevant ITER operating modes. The operation availability and performances of ISS-WDS have impact on ITER fuel cycle subsystems with consequences on the design integration. The preliminary experimental data on TRENTA facility are presented. (authors)« less

Modeling of steam distillation mechanism during steam injection process using artificial intelligence.

PubMed

Daryasafar, Amin; Ahadi, Arash; Kharrat, Riyaz

2014-01-01

Steam distillation as one of the important mechanisms has a great role in oil recovery in thermal methods and so it is important to simulate this process experimentally and theoretically. In this work, the simulation of steam distillation is performed on sixteen sets of crude oil data found in the literature. Artificial intelligence (AI) tools such as artificial neural network (ANN) and also adaptive neurofuzzy interference system (ANFIS) are used in this study as effective methods to simulate the distillate recoveries of these sets of data. Thirteen sets of data were used to train the models and three sets were used to test the models. The developed models are highly compatible with respect to input oil properties and can predict the distillate yield with minimum entry. For showing the performance of the proposed models, simulation of steam distillation is also done using modified Peng-Robinson equation of state. Comparison between the calculated distillates by ANFIS and neural network models and also equation of state-based method indicates that the errors of the ANFIS model for training data and test data sets are lower than those of other methods.

Modeling of Steam Distillation Mechanism during Steam Injection Process Using Artificial Intelligence

PubMed Central

Ahadi, Arash; Kharrat, Riyaz

2014-01-01

Steam distillation as one of the important mechanisms has a great role in oil recovery in thermal methods and so it is important to simulate this process experimentally and theoretically. In this work, the simulation of steam distillation is performed on sixteen sets of crude oil data found in the literature. Artificial intelligence (AI) tools such as artificial neural network (ANN) and also adaptive neurofuzzy interference system (ANFIS) are used in this study as effective methods to simulate the distillate recoveries of these sets of data. Thirteen sets of data were used to train the models and three sets were used to test the models. The developed models are highly compatible with respect to input oil properties and can predict the distillate yield with minimum entry. For showing the performance of the proposed models, simulation of steam distillation is also done using modified Peng-Robinson equation of state. Comparison between the calculated distillates by ANFIS and neural network models and also equation of state-based method indicates that the errors of the ANFIS model for training data and test data sets are lower than those of other methods. PMID:24883365

Safe, acceptable anti-microbial strategies for distillate fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, E.C.

1995-05-01

Microbiological fouling, spoilage and corrosion have for years been considered as end-user problems but they have now become endemic up-stream affecting cargoes, tank farms and terminals. Trading agreements to share storage and distribution facilities impose the need to mutually agree antimicrobial strategies which satisfy all health, safety and environmental regulations wherever that fuel is distributed and used. Also agreed must be the infection levels at which antimicrobial action is initiated. Physical decontamination methods are described and the use of biocides discussed in relation to increasing regulatory restrictions.

Surface code implementation of block code state distillation.

PubMed

Fowler, Austin G; Devitt, Simon J; Jones, Cody

2013-01-01

State distillation is the process of taking a number of imperfect copies of a particular quantum state and producing fewer better copies. Until recently, the lowest overhead method of distilling states produced a single improved [formula: see text] state given 15 input copies. New block code state distillation methods can produce k improved [formula: see text] states given 3k + 8 input copies, potentially significantly reducing the overhead associated with state distillation. We construct an explicit surface code implementation of block code state distillation and quantitatively compare the overhead of this approach to the old. We find that, using the best available techniques, for parameters of practical interest, block code state distillation does not always lead to lower overhead, and, when it does, the overhead reduction is typically less than a factor of three.

Surface code implementation of block code state distillation

PubMed Central

Fowler, Austin G.; Devitt, Simon J.; Jones, Cody

2013-01-01

State distillation is the process of taking a number of imperfect copies of a particular quantum state and producing fewer better copies. Until recently, the lowest overhead method of distilling states produced a single improved |A〉 state given 15 input copies. New block code state distillation methods can produce k improved |A〉 states given 3k + 8 input copies, potentially significantly reducing the overhead associated with state distillation. We construct an explicit surface code implementation of block code state distillation and quantitatively compare the overhead of this approach to the old. We find that, using the best available techniques, for parameters of practical interest, block code state distillation does not always lead to lower overhead, and, when it does, the overhead reduction is typically less than a factor of three. PMID:23736868

7 CFR 160.12 - Standard designations for rosin.

Code of Federal Regulations, 2014 CFR

2014-01-01

... after the distillation of gum spirits of turpentine from the oleoresin (gum) obtained from living pine... distillation of the volatile oil from the oleoresin within or extracted from pine wood by any suitable process... of rosin remaining after the removal of the fatty acids from tall oil by fractional distillation, and...

7 CFR 160.12 - Standard designations for rosin.

Code of Federal Regulations, 2013 CFR

2013-01-01

... after the distillation of gum spirits of turpentine from the oleoresin (gum) obtained from living pine... distillation of the volatile oil from the oleoresin within or extracted from pine wood by any suitable process... of rosin remaining after the removal of the fatty acids from tall oil by fractional distillation, and...

7 CFR 160.12 - Standard designations for rosin.

Code of Federal Regulations, 2012 CFR

2012-01-01

... after the distillation of gum spirits of turpentine from the oleoresin (gum) obtained from living pine... distillation of the volatile oil from the oleoresin within or extracted from pine wood by any suitable process... of rosin remaining after the removal of the fatty acids from tall oil by fractional distillation, and...

Desorption Studies of DDGS under Varying CDS and Temperature Levels

USDA-ARS?s Scientific Manuscript database

Distillers dried grains with solubles (DDGS) often contains approximately 30-35% (db) protein and 10-12% (db) fat, and has been shown to be an excellent livestock feed. DDGS is produced from the fuel ethanol industry, which is located in the midwest US; there is a growing need to transport DDGS over...

27 CFR 19.687 - Changes in officers, directors, members, managers, or principal persons.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Changes in officers... PLANTS Distilled Spirits for Fuel Use Changes to Permit Information § 19.687 Changes in officers, directors, members, managers, or principal persons. If there is a change in the list of officers, directors...

Production of schizophyllan from distiller's dried grains with solubles by diverse strains of Schizophyllan commune

USDA-ARS?s Scientific Manuscript database

Eleven diverse strains of Schizophyllan commune, to our knowledge never before examined for production of the biopolymer schizophyllan, were grown in malt extract (ME) basal medium containing 1.0% (w/v) distiller’s dried grains with solubles (DDGS, an abundant coproduct of fuel ethanol production by...

Converting Municipal Waste into Automobile Fuel: Ethanol from Newspaper

ERIC Educational Resources Information Center

Mascal, Mark; Scown, Richard

2008-01-01

Waste newspaper is pulped with acid and its cellulose is hydrolyzed. The resulting glucose syrup is fermented with yeast and distilled to give ethanol. The experiment highlights the potential of applied chemistry to confront problems of economic importance, that is, the effective utilization of biomass to reduce dependence on non-renewable…

Distillation and Air Stripping Designs for the Lunar Surface

NASA Technical Reports Server (NTRS)

Boul, Peter J.; Lange, Kevin E.; Conger, Bruce; Anderson, Molly

2009-01-01

Air stripping and distillation are two different gravity-based methods, which may be applied to the purification of wastewater on the lunar base. These gravity-based solutions to water processing are robust physical separation techniques, which may be advantageous to many other techniques for their simplicity in design and operation. The two techniques can be used in conjunction with each other to obtain high purity water. The components and feed compositions for modeling waste water streams are presented in conjunction with the Aspen property system for traditional stage distillation models and air stripping models. While the individual components for each of the waste streams will vary naturally within certain bounds, an analog model for waste water processing is suggested based on typical concentration ranges for these components. Target purity levels for the for recycled water are determined for each individual component based on NASA s required maximum contaminant levels for potable water Distillation processes are modeled separately and in tandem with air stripping to demonstrate the potential effectiveness and utility of these methods in recycling wastewater on the Moon. Optimum parameters such as reflux ratio, feed stage location, and processing rates are determined with respect to the power consumption of the process. Multistage distillation is evaluated for components in wastewater to determine the minimum number of stages necessary for each of 65 components in humidity condensate and urine wastewater mixed streams. Components of the wastewater streams are ranked by Henry s Law Constant and the suitability of air stripping in the purification of wastewater in terms of component removal is evaluated. Scaling factors for distillation and air stripping columns are presented to account for the difference in the lunar gravitation environment. Commercially available distillation and air stripping units which are considered suitable for Exploration Life Support are presented. The advantages to the various designs are summarized with respect to water purity levels, power consumption, and processing rates.

Comparison of standard moisture loss-on-drying methods for the determination of moisture content of corn distillers dried grains with solubles.

PubMed

Ileleji, Klein E; Garcia, Arnoldo A; Kingsly, Ambrose R P; Clementson, Clairmont L

2010-01-01

This study quantified the variability among 14 standard moisture loss-on-drying (gravimetric) methods for determination of the moisture content of corn distillers dried grains with solubles (DDGS). The methods were compared with the Karl Fischer (KF) titration method to determine their percent variation from the KF method. Additionally, the thermo-balance method using a halogen moisture analyzer that is routinely used in fuel ethanol plants was included in the methods investigated. Moisture contents by the loss-on-drying methods were significantly different for DDGS samples from three fuel ethanol plants. The percent deviation of the moisture loss-on-drying methods decreased with decrease in drying temperature and, to a lesser extent, drying time. This was attributed to an overestimation of moisture content in DDGS due to the release of volatiles at high temperatures. Our findings indicate that the various methods that have been used for moisture determination by moisture loss-on-drying will not give identical results and therefore, caution should be exercised when selecting a moisture loss-on-drying method for DDGS.

27 CFR 24.248 - Processes authorized for the treatment of wine, juice, and distilling material.

Code of Federal Regulations, 2010 CFR

2010-04-01

... vinous character of the wine(2) None of the stripping solution may migrate into the wine. Reverse osmosis....2910. 1 This process must be done on distilled spirits plant premises. However, reverse osmosis, under...

27 CFR 24.248 - Processes authorized for the treatment of wine, juice, and distilling material.

Code of Federal Regulations, 2014 CFR

2014-04-01

... vinous character of the wine(2) None of the stripping solution may migrate into the wine. Reverse osmosis....2910. 1 This process must be done on distilled spirits plant premises. However, reverse osmosis, under...

27 CFR 24.248 - Processes authorized for the treatment of wine, juice, and distilling material.

Code of Federal Regulations, 2011 CFR

2011-04-01

... vinous character of the wine(2) None of the stripping solution may migrate into the wine. Reverse osmosis....2910. 1 This process must be done on distilled spirits plant premises. However, reverse osmosis, under...

Efficient ethanol recovery from fermentation broths with integrated distillation-membrane process

EPA Science Inventory

The energy demand of distillation-molecular sieve systems for ethanol recovery/dehydration can be significant, particularly for dilute solutions. An alternative process integrating vapor stripping (like a beer still) with vapor compression and a vapor permeation membrane separati...

Characteristics and combustion of future hydrocarbon fuels. [aircraft fuels

NASA Technical Reports Server (NTRS)

Rudey, R. A.; Grobman, J. S.

1978-01-01

As the world supply of petroleum crude oil is being depleted, the supply of high-quality crude oil is also dwindling. This dwindling supply is beginning to manifest itself in the form of crude oils containing higher percentages of aromatic compounds, sulphur, nitrogen, and trace constituents. The result of this trend is described and the change in important crude oil characteristics, as related to aircraft fuels, is discussed. As available petroleum is further depleted, the use of synthetic crude oils (those derived from coal and oil shale) may be required. The principal properties of these syncrudes and the fuels that can be derived from them are described. In addition to the changes in the supply of crude oil, increasing competition for middle-distillate fuels may require that specifications be broadened in future fuels. The impact that the resultant potential changes in fuel properties may have on combustion and thermal stability characteristics is illustrated and discussed in terms of ignition, soot formation, carbon deposition flame radiation, and emissions.

Characterization of upgraded fast pyrolysis oak oil distillate fractions from sulfided and non-sulfided catalytic hydrotreating

DOE PAGES

Olarte, Mariefel V.; Padmaperuma, Asanga B.; Ferrell, III, Jack R.; ...

2017-04-06

We consider catalytic hydroprocessing of pyrolysis oils from biomass which produces hydrocarbons for liquid fuel production. This process requires removal of oxygen and cracking of the heavier molecular weight bio-oil constituents into smaller fragments at high temperatures and pressures under hydrogen. Here, we present in this paper the characterization of a group of five distillate fractions from each of two types of hydroprocessed oils from oak pyrolysis oil: a low oxygen content (LOC, 1.8% O, wet basis) oil and a medium oxygen content (MOC, 6.4% O, wet basis) oil. The LOC oil was generated using a sulfided hydrotreating system consistingmore » of RuS/C and xMoS/Al 2O 3 while the MOC was produced using non-sulfided catalysts, Ru/C and Pd/C. Elemental analysis and 13C NMR (nuclear magnetic resonance) results suggest that the distillate fractions from both oils become more aromatic/unsaturated as they become heavier. Carbonyl and carboxylic groups were found in the MOC light fractions, while phenols were present in the heavier fractions for both MOC and LOC. Paraffin, iso-paraffin, olefin, naphthene, aromatic (PIONA) analysis of the light LOC fraction shows a predominance of paraffins with a minor amount of olefins. Sulfur analysis showed the comparative concentration of sulfur in the different fractions as well as the surprising similarity in content in some sulfided and non-sulfided fractions. Our results can be used to direct future research on refinery integration and production of value-added product from specific upgraded oil streams.« less

Characterization of upgraded fast pyrolysis oak oil distillate fractions from sulfided and non-sulfided catalytic hydrotreating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Olarte, Mariefel V.; Padmaperuma, Asanga B.; Ferrell, III, Jack R.

We consider catalytic hydroprocessing of pyrolysis oils from biomass which produces hydrocarbons for liquid fuel production. This process requires removal of oxygen and cracking of the heavier molecular weight bio-oil constituents into smaller fragments at high temperatures and pressures under hydrogen. Here, we present in this paper the characterization of a group of five distillate fractions from each of two types of hydroprocessed oils from oak pyrolysis oil: a low oxygen content (LOC, 1.8% O, wet basis) oil and a medium oxygen content (MOC, 6.4% O, wet basis) oil. The LOC oil was generated using a sulfided hydrotreating system consistingmore » of RuS/C and xMoS/Al 2O 3 while the MOC was produced using non-sulfided catalysts, Ru/C and Pd/C. Elemental analysis and 13C NMR (nuclear magnetic resonance) results suggest that the distillate fractions from both oils become more aromatic/unsaturated as they become heavier. Carbonyl and carboxylic groups were found in the MOC light fractions, while phenols were present in the heavier fractions for both MOC and LOC. Paraffin, iso-paraffin, olefin, naphthene, aromatic (PIONA) analysis of the light LOC fraction shows a predominance of paraffins with a minor amount of olefins. Sulfur analysis showed the comparative concentration of sulfur in the different fractions as well as the surprising similarity in content in some sulfided and non-sulfided fractions. Our results can be used to direct future research on refinery integration and production of value-added product from specific upgraded oil streams.« less

Using Mathematica to Teach Process Units: A Distillation Case Study

ERIC Educational Resources Information Center

Rasteiro, Maria G.; Bernardo, Fernando P.; Saraiva, Pedro M.

2005-01-01

The question addressed here is how to integrate computational tools, namely interactive general-purpose platforms, in the teaching of process units. Mathematica has been selected as a complementary tool to teach distillation processes, with the main objective of leading students to achieve a better understanding of the physical phenomena involved…

Dynamic Modeling of Process Technologies for Closed-Loop Water Recovery Systems

NASA Technical Reports Server (NTRS)

Allada, Rama Kumar; Lange, Kevin; Anderson, Molly

2011-01-01

Detailed chemical process simulations are a useful tool in designing and optimizing complex systems and architectures for human life support. Dynamic and steady-state models of these systems help contrast the interactions of various operating parameters and hardware designs, which become extremely useful in trade-study analyses. NASA s Exploration Life Support technology development project recently made use of such models to compliment a series of tests on different waste water distillation systems. This paper presents dynamic simulations of chemical process for primary processor technologies including: the Cascade Distillation System (CDS), the Vapor Compression Distillation (VCD) system, the Wiped-Film Rotating Disk (WFRD), and post-distillation water polishing processes such as the Volatiles Removal Assembly (VRA) that were developed using the Aspen Custom Modeler and Aspen Plus process simulation tools. The results expand upon previous work for water recovery technology models and emphasize dynamic process modeling and results. The paper discusses system design, modeling details, and model results for each technology and presents some comparisons between the model results and available test data. Following these initial comparisons, some general conclusions and forward work are discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herbrych, Jacek W.; Feiguin, Adrian E.; Dagotto, Elbio R.

Here, we present a time-dependent density-matrix renormalization group investigation of the quantum distillation process within the Fermi-Hubbard model on a quasi-one-dimensional ladder geometry. The term distillation refers to the dynamical, spatial separation of singlons and doublons in the sudden expansion of interacting particles in an optical lattice, i.e., the release of a cloud of atoms from a trapping potential. Remarkably, quantum distillation can lead to a contraction of the doublon cloud, resulting in an increased density of the doublons in the core region compared to the initial state. As a main result, we show that this phenomenon is not limitedmore » to chains that were previously studied. Interestingly, there are additional dynamical processes on the two-leg ladder such as density oscillations and self-trapping of defects that lead to a less efficient distillation process. An investigation of the time evolution starting from product states provides an explanation for this behavior. Initial product states are also considered since in optical lattice experiments, such states are often used as the initial setup. We propose configurations that lead to a fast and efficient quantum distillation.« less

Separation and Recycling of Spent Carbon Cathode Blocks in the Aluminum Industry by the Vacuum Distillation Process

NASA Astrophysics Data System (ADS)

Yaowu, Wang; Jianping, Peng; Yuezhong, Di

2018-04-01

Aluminum is the second most produced metal after iron. China is the top producer of primary aluminum with a production capacity of 41,000 kt and an output in 2016 of 32,000 kt. A large amount of spent carbon cathode block (SCCB) is produced after electrolytic pot failure. SCCB consists of carbon, fluorides, alkali metals, carbides, nitrides, cyanides, and oxides, and is considered to be a hazardous material because it contains significant concentrations of toxic and soluble cyanides and fluorides. There is no economical and efficient process for the treatment of SCCB and is most commonly disposed in landfill. In this study, the vacuum distillation process (VDP) has been used to separate and recycle SCCB. The results show that Na3AlF6, NaF, and sodium metal can be effectively separated from SCCB by VDP, and the distillation ratio is above 80% at a distillation temperature of 1200°C. The carbon content in the distilled SCCB is above 91% and the impurities are mainly CaF2 and Al2O3.

Avoid problems during distillation column startups

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sloley, A.W.

1996-07-01

The startup of a distillation column is the end product of the design process. Indeed, startup is the culmination of the theory and practice of designing the column to meet the process objectives. The author will direct most of this discussion towards column revamps due to their inherent complexity; however, the points apply equally to new columns, as well. The most important question that must be answered prior to a startup is how will the distillation system changes affect initial startup, process control of the system, and normal day-to-day operations? How will the operators run the system? Steady-state distillation-column simulationsmore » alone cannot provide an authoritative answer and, indeed, engineers` over-reliance on software too often has led them to ignore many practical aspects. Computer modeling, while an important engineering tool, is not reality. Distillation columns are real functioning pieces of equipment that require practical skills to successfully modify. They are not steady-state solutions that result from converged computer simulations. Early planning, coupled with thorough inspections and comprehensive reviews of instrumentation and procedures, can play a key role in assuring smooth startups.« less

Fuel property effects on low-speed pre-ignition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jatana, Gurneesh S.; Splitter, Derek A.; Kaul, Brian C.

This work explores the dependence of fuel distillation and flame speed on low-speed pre-ignition (LSPI). Findings are based on cylinder pressure analysis, as well as the number count, clustering, intensity, duration, and onset crank angle of LSPI events. Four fuels were used, with three of the fuels being blends with gasoline, and the fourth being neat gasoline. The blended fuels consisted of single molecules of different molecular types: a ketone (cyclopentanone), an alcohol (2-methyl-1-butanol), and an aromatic (ethylbenzene). All three pure molecules have RON values within ±2 and boiling points within ±5 °C. These fuels were blended with gasoline tomore » a 25% mass fraction and were used to run the engine at identical LSPI prone operating conditions. The findings highlight that fuels with similar boiling properties and octane numbers can exhibit similar LSPI number counts, but with vastly different LSPI magnitudes and intensities. Moreover, the results highlight fundamental fuel properties such as flame speed are critical to characterizing the LSPI propensity and behavior of the fuel.« less

Low NOx heavy fuel combustor concept program, phase 1

NASA Technical Reports Server (NTRS)

Cutrone, M. B.

1981-01-01

Combustion tests were completed with seven concepts, including three rich/lean concepts, three lean/lean concepts, and one catalytic combustor concept. Testing was conducted with ERBS petroleum distillate, petroleum residual, and SRC-II coal-derived liquid fuels over a range of operating conditions for the 12:1 pressure ratio General Electric MS7001E heavy-duty turbine. Blends of ERBS and SRC-II fuels were used to vary fuel properties over a wide range. In addition, pyridine was added to the ERBS and residual fuels to vary nitrogen level while holding other fuel properties constant. Test results indicate that low levels of NOx and fuel-bound nitrogen conversion can be achieved with the rich/lean combustor concepts for fuels with nitrogen contents up to 1.0% by weight. Multinozzle rich/lean Concept 2 demonstrated dry low Nox emissions within 10-15% of the EPA New Source Performance Standards goals for SRC-II fuel, with yields of approximately 15%, while meeting program goals for combustion efficiency, pressure drop, and exhaust gas temperature profile. Similar, if not superior, potential was demonstrated by Concept 3, which is a promising rich/lean combustor design.

Fuel property effects on low-speed pre-ignition

DOE PAGES

Jatana, Gurneesh S.; Splitter, Derek A.; Kaul, Brian C.; ...

2018-05-30

This work explores the dependence of fuel distillation and flame speed on low-speed pre-ignition (LSPI). Findings are based on cylinder pressure analysis, as well as the number count, clustering, intensity, duration, and onset crank angle of LSPI events. Four fuels were used, with three of the fuels being blends with gasoline, and the fourth being neat gasoline. The blended fuels consisted of single molecules of different molecular types: a ketone (cyclopentanone), an alcohol (2-methyl-1-butanol), and an aromatic (ethylbenzene). All three pure molecules have RON values within ±2 and boiling points within ±5 °C. These fuels were blended with gasoline tomore » a 25% mass fraction and were used to run the engine at identical LSPI prone operating conditions. The findings highlight that fuels with similar boiling properties and octane numbers can exhibit similar LSPI number counts, but with vastly different LSPI magnitudes and intensities. Moreover, the results highlight fundamental fuel properties such as flame speed are critical to characterizing the LSPI propensity and behavior of the fuel.« less