Compositional studies of Mare Moscoviense: New perspectives from Chandrayaan-1 VIS-NIR data
NASA Astrophysics Data System (ADS)
Bhatt, Megha; Wöhler, Christian; Dhingra, Deepak; Thangjam, Guneshwar; Rommel, Daniela; Mall, Urs; Bhardwaj, Anil; Grumpe, Arne
2018-03-01
Moscoviense is one of the prominent mare-filled basin on the lunar far side holding key insights about volcanic activity on the far side. Here, we present spectral and elemental maps of mare Moscoviense, using the Moon Mineralogy Mapper (M3) and Infrared Spectrometer-2 (SIR-2) data-sets. The different mare units are mapped based on their spectral properties analyzing both quantitatively (band center, band depth) and qualitatively (Integrated Band Depth composite images), and also using their elemental compositions. We find a total of five distinct spectral units from the basin floor based on the spectral properties. Our analysis suggests that the northern part which was mapped as Iltm unit (Imbrian low Ti, low Fe) by earlier researchers is actually a distinct unit, which is different in composition and age, named as Ivltm unit (Imbrian very low Ti and very low Fe). We obtain the absolute model age of 3.2 Ga with uncertainties of +0.2/ -0.5 Ga for the unit Ivltm. The newly identified basalt unit Ivltm is compositionally intermediate to the units Im and Iltm in FeO and TiO2 abundances. We find a total of five distinct spectral units from the basin floor based on the spectral properties. The units Im (Imbrian very low Ti) from southern and northern regions of the basin floor are spectrally distinct in terms of band center position and corresponding band depths but considered a single unit based on the elemental abundance analysis. The units Ivltm and Im are consistent with a high-Al basalt composition. Our detailed analysis of the entire Moscoviense basin indicates that the concentrations of orthopyroxene, olivine, and Mg-rich spinel, named as OOS rock family are widespread and dominant at the western and southern side of the middle ring of the basin with one isolated area found on the northern side of the peak ring.
NASA Astrophysics Data System (ADS)
Brunelli, D.; Levi, S. T.; Fragnoli, P.; Renzulli, A.; Santi, P.; Paganelli, E.; Martinelli, M. C.
2013-12-01
An integrated microchemical-petrographic approach is here proposed to discriminate the provenance of archaeological pottery artefacts from distinct production centres. Our study focuses on a statistically significant sampling ( n=186) of volcanic temper-bearing potteries representative of the manufacturing and dispersion among the islands of the Aeolian Archipelago during the Bronze Age. The widespread establishment of new settlements and the abundant recovery of Aeolian-made ceramic in southern Italy attest for the increased vitality of the Archipelago during the Capo Graziano culture (Early Bronze Age-Middle Bronze Age 2; 2300-1430 BC). Potteries from three of the main known ancient communities (Lipari, Filicudi and Stromboli) have been studied integrating old collections and newly excavated material. Volcanic tempers have been first investigated through multivariate analyses of relative abundances of mineral and rock clasts along with petrographic characters. In addition, we performed in-situ mineral chemistry microanalyses by Electron Microprobe and Laser Ablation—Inductively Coupled Plasma Mass Spectrometry to assess major and trace element composition of the most common mineral phases. Four Temper Compositional Reference Units have been recognised based on compositional trends. Two units (AI and AX) are unequivocally distinct by their peculiar trace element enrichment and petrographic composition; they mostly contain samples from the sites of Lipari and Stromboli, respectively. Units AIV and AVIII, restricted to the sites of Filicudi and Stromboli, show distinct petrographic characters but overlapped geochemical fingerprints.
NASA Astrophysics Data System (ADS)
Cahoon, E. B.; Streck, M. J.
2016-12-01
Mid-Miocene basaltic lavas and dikes are exposed in the area between the southern extent of the Picture Gorge Basalt (PGB) and the northern extent of Steens Basalt in a wide corridor of the Malheur National Forest, eastern Oregon. An approximate mid-Miocene age of sampled basaltic units is indicated by stratigraphic relationships to the 16 Ma Dinner Creek Tuff. Lavas provide an opportunity to extend and/or revise distribution areas of either CRBG unit and explore the petrologic transition between them. The PGB and the Steens Basalt largely represent geochemically distinct tholeiitic units of the CRBG; although each unit displays internal complexity. Lavas of PGB are relatively primitive (MgO 5-9 wt.%) while Steens Basalt ranges in MgO from >9 to 3 wt.% but both units are commonly coarsely porphyritic. Conversely, Steens Basalt compositions are on average more enriched in highly incompatible elements (e.g. Rb, Th) and relatively enriched in the lesser incompatible elements (e.g. Y, Yb) compared to the Picture Gorge basalts. These compositional signatures produce inclined and flat patterns on mantle-normalized incompatible trace element plots but with similar troughs and spikes, respectively. New compositional data from our study area indicate basaltic lavas can be assigned as PGB lava flows and dikes, and also to a compositional group chemically distinct between Steens Basalt and PGB. Distribution of lava flows with PGB composition extend this CRBG unit significantly south/southeast closing the exposure gap between PGB and Steens Basalt. We await data that match Steens Basalt compositions but basaltic lavas with petrographic features akin to Steens Basalt have been identified in the study area. Lavas of the transitional unit share characteristics with Upper Steens and Picture Gorge basalt types, but identify a new seemingly unique composition. This composition is slightly more depleted in the lesser incompatible elements (i.e. steeper pattern) on mantle normalized incompatible element diagrams, relatively enriched in Sr, and overall reflects more HFSE depletion than Upper Steens Basalt. Similar compositional patterns have also been observed among lavas of the Strawberry Volcanics located immediately east of our study area.
NASA Astrophysics Data System (ADS)
Baker, Matthew R.; Hollowed, Anne B.
2014-11-01
Characterizing spatial structure and delineating meaningful spatial boundaries have useful applications to understanding regional dynamics in marine systems, and are integral to ecosystem approaches to fisheries management. Physical structure and drivers combine with biological responses and interactions to organize marine systems in unique ways at multiple scales. We apply multivariate statistical methods to define spatially coherent ecological units or ecoregions in the eastern Bering Sea. We also illustrate a practical approach to integrate data on species distribution, habitat structure and physical forcing mechanisms to distinguish areas with distinct biogeography as one means to define management units in large marine ecosystems. We use random forests to quantify the relative importance of habitat and environmental variables to the distribution of individual species, and to quantify shifts in multispecies assemblages or community composition along environmental gradients. Threshold shifts in community composition are used to identify regions with distinct physical and biological attributes, and to evaluate the relative importance of predictor variables to determining regional boundaries. Depth, bottom temperature and frontal boundaries were dominant factors delineating distinct biological communities in this system, with a latitudinal divide at approximately 60°N. Our results indicate that distinct climatic periods will shift habitat gradients and that dynamic physical variables such as temperature and stratification are important to understanding temporal stability of ecoregion boundaries. We note distinct distribution patterns among functional guilds and also evidence for resource partitioning among individual species within each guild. By integrating physical and biological data to determine spatial patterns in community composition, we partition ecosystems along ecologically significant gradients. This may provide a basis for defining spatial management units or serve as a baseline index for analyses of structural shifts in the physical environment, species abundance and distribution, and community dynamics over time.
Quantification of Ethnic and Racial Residential Segregation: Analysis of 2015 U.S. Census Tracts
The presence and distribution of demographic enclaves, or places defined by distinctly different group compositions than surrounding places, are a well-studied occurrence in urban areas of the United States. With the changing composition of cities and surrounding suburban areas,...
Composition and Maturity of Apollo 16 Regolith Core 60013/14
NASA Technical Reports Server (NTRS)
Korotev, Randy T.; Morris, Richard V.
1993-01-01
Samples from every half-centimeter dissection interval of double drive tube 60013/14 (sections 60013 and 60014) were analyzed by magnetic techniques for Fe concentration and surface maturity parameter I(sub s)/ Fe(O), and by neutron activation for concentrations of 25 lithophile and siderophile elements. Core 60013/14 is one of three regolith cores taken in a triangular array 40-50 m apart on the Cayley plains during Apollo 16 mission to the Moon. The core can be divided into three zones based both on I(sub s)/FeO and composition. Unit A (0-44 cm depth) is compositionally similar to other soils from the surface of the central region of the site and is mature throughout, although maturity decreases with depth. Unit B (44-59 cm) is submature and compositionally more feldspathic than Unit A. Regions of lowest maturity in Unit B are characterized by lower Sm/Sc ratios than any soil obtained from the Cayley plains as a result of some unidentified lithologic component with low surface maturity. The component is probably some type of mafic anorthosite that does not occur in such high abundance in any of the other returned soils. Unit C (59-62 cm) is more mature than Unit B and compositionally equivalent to an 87: 13 mixture of soil such as that from Unit A and plagioclase such as found in ferroan anorthosite. Similar soils, but containing greater abundances of anorthosite (plagioclase), are found at depth in the other two cores of the array. These units of immature to submature soil enriched to varying degrees (compared to the mature surface soil) in ferroan anorthosite consisting of approx. 99% plagioclase are the only compositionally distinct subsurface similarities among the three cores. Each of the cores contains other units that are compositionally dissimilar to any soil unit in the other two cores. These compositionally distinct units probably derive from local subsurface blocks deposited by the event(s) that formed the Cayley plains. The ferroan anorthosite with approx. 99% plagioclase, however, must represent some subsurface lithology that is significant on the scale of tens of meters. The compositional uniformity of the surface soil (0-10 cm depth) over distances of kilometers reflects the large-scale uniformity of the plains deposits; the fine- structure reflects small-scale nonuniformity and the inefficiency of the impact-mixing process at depths as shallow as even one meter.
SPATIALLY RESOLVED SPECTROSCOPY OF EUROPA: THE DISTINCT SPECTRUM OF LARGE-SCALE CHAOS
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fischer, P. D.; Brown, M. E.; Hand, K. P., E-mail: pfischer@caltech.edu
2015-11-15
We present a comprehensive analysis of spatially resolved moderate spectral resolution near-infrared spectra obtained with the adaptive optics system at the Keck Observatory. We identify three compositionally distinct end member regions: the trailing hemisphere bullseye, the leading hemisphere upper latitudes, and a third component associated with leading hemisphere chaos units. We interpret the composition of the three end member regions to be dominated by irradiation products, water ice, and evaporite deposits or salt brines, respectively. The third component is associated with geological features and distinct from the geography of irradiation, suggesting an endogenous identity. Identifying the endogenous composition is ofmore » particular interest for revealing the subsurface composition. However, its spectrum is not consistent with linear mixtures of the salt minerals previously considered relevant to Europa. The spectrum of this component is distinguished by distorted hydration features rather than distinct spectral features, indicating hydrated minerals but making unique identification difficult. In particular, it lacks features common to hydrated sulfate minerals, challenging the traditional view of an endogenous salty component dominated by Mg-sulfates. Chloride evaporite deposits are one possible alternative.« less
Compositional structure of the asteroid belt.
Gradie, J; Tedesco, E
1982-06-25
The distribution of compositional types among the asteroids is found to vary systematically with heliocentric distance. Seven distinct peaks in the relative proportion of the compositional types E, R, S, M, F, C, P, and D are found from 1.8 to 5.2 astronomical units. The inferred composition of the asteroids in each semimajor axis region is consistent with the theory that the asteroids accreted from the solar nebula at or near their present locations.
NASA Astrophysics Data System (ADS)
Fischer, P. D.; Brown, M. E.; Trumbo, S. K.; Hand, K. P.
2017-01-01
We present spatially resolved spectroscopic observations of Europa’s surface at 3-4 μm obtained with the near-infrared spectrograph and adaptive optics system on the Keck II telescope. These are the highest quality spatially resolved reflectance spectra of Europa’s surface at 3-4 μm. The observations spatially resolve Europa’s large-scale compositional units at a resolution of several hundred kilometers. The spectra show distinct features and geographic variations associated with known compositional units; in particular, large-scale leading hemisphere chaos shows a characteristic longward shift in peak reflectance near 3.7 μm compared to icy regions. These observations complement previous spectra of large-scale chaos, and can aid efforts to identify the endogenous non-ice species.
NASA Astrophysics Data System (ADS)
Neal, C. R.; Kinman, W. S.
2003-12-01
The Ontong Java Plateau (OJP) is the world's largest LIP made up of 2 isotopically distinct lava types that comprise the Singgalo and Kwaimbaita formations (Tejada et al., 2002, J.Pet 43:449). Some Kwaimbaita basaltic flows contain plagioclase-rich cumulate xenoliths. As plagioclase is stable over a range of magmatic conditions, microanalysis of this phase allows the evolution of the parent magma(s) to be constrained (cf. Davidson & Tepley, 1997, Science 275:826). This crystal stratigraphy approach has been applied to cm-size plagioclase megacrysts from three basaltic units (5B, 6, and 7) recovered at ODP Leg 192 Site 1183. Core-to-rim trace element variations were quantified by LA-ICP-MS, major elements by EPMA, and compositional backscatter SEM imaging was used to investigate the subtle compositional zoning and textural features within the plagioclases. All 5 OJP megacrysts sampled show little core-to-rim anorthite variation (82 mol % An +/- 5%); An-rich plagioclase crystals are resistant to re-equilibration and are more likely to retain magmatic trace element signatures (Blundy & Wood, 1991, GCA 55:193). The Unit 7 (oldest) plagioclase contains a relatively Sr, Ga, REE, and Ti poor core bounded by a resorption surface and a relatively Sr, Ga, REE, and Ti rich zone suggesting this crystal was exposed to 2 compositionally distinct magmas. The Unit 6 plagioclase contains a relatively Sr, Ga, REE, and Ti poor core with increasing abundances toward the rim, consistent with evolution through fractional crystallization. This megacryst also contains a distinct resorption surface bounded by a core-like Sr, REE, and Ti poor zone. The three Unit 5B plagioclases display core-to-rim Sr and Ba increases with little core-to-rim REE and Ga variations. The uppermost Unit 5B crystal (youngest) exhibits a core-to-rim decrease in Ti, while the lower 2 crystals display the opposite relationship. We suggest the textural and trace element variations seen in OJP plagioclase megacrysts are again evidence of magma mixing. Reconstructed liquids suggest at least two distinct mixing end members: an enriched end member, similar to Singgalo-type lavas, and a depleted end member, similar to Kwaimbaita type lavas. As the Singgalo- and Kwaimbaita-type basalts are isotopically distinct (I(Sr) = 0.7041 and 0.7038, resp.), Sr isotope determinations of the different plagioclase zones through microdrilling is planned for the near future to test this hypothesis. If correct, it suggests that both the Kwaimbaita and Singgalo sources were active at the same time, which is in contrast to the stratigraphy determined by whole-rock compositions.
Constraints on the Compositions of Phobos and Deimos from Mineral Absorptions
NASA Technical Reports Server (NTRS)
Fraeman, A. A.; Murchie, S. L.; Arvidson, R. E.; Rivkin, A. S.; Morris, R. V.
2013-01-01
The compositions of Phobos and Deimos have remained controversial despite multiple Earth- and space-based observations acquired during the last 40 years. Phobos is composed of at least two spectral units that are both dark yet distinct at visible to near infrared wavelenghts; a spectrally red-sloped "red" unit covers most of the moon and a less red-sloped "blue" unit is present in the ejecta of the approximately 9-km diameter impact crater Stickney [1,2]. Deimos is similar spectrally to Phobos' "red" unit [2]. Here we report results from mapping mineral absorptions on Phobos and Deimos using visible/near infrared observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). We find evidence for an absorption feature at 0.65 m in the Phobos red unit and Deimos that is reproducible in observations from other instruments. The phase responsible is uncertain but may be a Fe-bearing phyllosilicate and/or graphite, consistent with the notion that Phobos and Deimos have compositions similar to CM carbonaceous chondrites [3].
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fischer, P. D.; Brown, M. E.; Trumbo, S. K.
2017-01-01
We present spatially resolved spectroscopic observations of Europa’s surface at 3–4 μ m obtained with the near-infrared spectrograph and adaptive optics system on the Keck II telescope. These are the highest quality spatially resolved reflectance spectra of Europa’s surface at 3–4 μ m. The observations spatially resolve Europa’s large-scale compositional units at a resolution of several hundred kilometers. The spectra show distinct features and geographic variations associated with known compositional units; in particular, large-scale leading hemisphere chaos shows a characteristic longward shift in peak reflectance near 3.7 μ m compared to icy regions. These observations complement previous spectra of large-scalemore » chaos, and can aid efforts to identify the endogenous non-ice species.« less
Compositions of modern dust and surface sediments in the Desert Southwest, United States
Reheis, M.C.; Budahn, J.R.; Lamothe, P.J.; Reynolds, R.L.
2009-01-01
Modern dusts across southwestern United States deserts are compositionally similar to dust-rich Av soil horizons (depths of 0-0.5 cm and 1-4 cm at 35 sites) for common crustal elements but distinctly different for some trace elements. Chemical compositions and magnetic properties of the soil samples are similar among sites relative to dust sources, geographic areas, and lithologic substrates. Exceptions are Li, U, and W, enriched in Owens Valley, California, and Mg and Sr, enriched in soils formed on calcareous fan gravel in southeast Nevada. The Av horizons are dominated by dust and reflect limited mixing with substrate sediments. Modern dust samples are also similar across the region, except that Owens Valley dusts are higher in Mg, Ba, and Li and dusts both there and at sites to the north on volcanic substrates are higher in Sb and W. Thus, dust and Av horizons consist of contributions from many different sources that are well mixed before deposition. Modern dusts contain significantly greater amounts of As, Cd, Cr, Cu, Ni, Pb, and Sb than do Av horizons, which record dust additions over hundreds to thousands of years. These results suggest that modern dust compositions are influenced by anthropogenic sources and emissions from Owens (dry) Lake after its artificial desiccation in 1926. Both modern dusts and Av horizons are enriched in As, Ba, Cu, Li, Sb, Th, U, and W relative to average crustal composition, which we interpret to indicate that the geologic sources of dust in the southwestern United States are geochemically distinctive.
NASA Technical Reports Server (NTRS)
Pieters, C.
1977-01-01
The types of basal to be found on the moon were identified using reflectance spectra from a variety of lunar mare surfaces and craters as well as geochemical interpretations of laboratory measurements of reflectance from lunar, terrestrial, and meteoritic samples. Findings indicate that major basaltic units are not represented in lunar sample collections. The existence of late stage high titanium basalts is confirmed. All maria contain lateral variations of compositionally heterogenous basalts; some are vertically inhomogenous with distinctly different subsurface composition. Some basalt types are spectrally gradational, suggesting minor variations in composition. Mineral components of unsampled units can be defined if spectra are obtained with sufficient spectral coverage (.3 to 2.5 micron m) and spatial resolution (approximating .5 km).
NASA Astrophysics Data System (ADS)
Moriarty, D. P.; Pieters, C. M.
2016-02-01
We reexamine the relationship between pyroxene composition and near-infrared absorption bands, integrating measurements of diverse natural and synthetic samples. We test an algorithm (PLC) involving a two-part linear continuum removal and parabolic fits to the 1 and 2 μm bands—a computationally simple approach which can easily be automated and applied to remote sensing data. Employing a suite of synthetic pure pyroxenes, the PLC technique is shown to derive similar band centers to the modified Gaussian model. PLC analyses are extended to natural pyroxene-bearing materials, including (1) bulk lunar basalts and pyroxene separates, (2) diverse lunar soils, and (3) HED meteorites. For natural pyroxenes, the relationship between composition and absorption band center differs from that of synthetic pyroxenes. These differences arise from complexities inherent in natural materials such as exsolution, zoning, mixing, and space weathering. For these reasons, band center measurements of natural pyroxene-bearing materials are compositionally nonunique and could represent three distinct scenarios (1) pyroxene with a narrow compositional range, (2) complexly zoned pyroxene grains, or (3) a mixture of multiple pyroxene (or nonpyroxene) components. Therefore, a universal quantitative relationship between band centers and pyroxene composition cannot be uniquely derived for natural pyroxene-bearing materials without additional geologic context. Nevertheless, useful relative relationships between composition and band center persist in most cases. These relationships are used to interpret M3 data from the Humboldtianum Basin. Four distinct compositional units are identified (1) Mare Humboldtianum basalts, (2) distinct outer basalts, (3) low-Ca pyroxene-bearing materials, and (4) feldspathic materials.
Meaning and Implications of Being Labelled a Predominantly White Institution
ERIC Educational Resources Information Center
Bourke, Brian
2016-01-01
Institutions of higher learning are regularly identified in scholarship and conversation by their racial composition, which generally reflects a distinction between predominantly white institutions (PWIs), and minority-serving institutions (MSIs). While PWI is not an official designation for any institution in the United Stated, six categories of…
Exposure of riverine waters to natural sunlight initiated alterations in stable carbon isotope ratios (delta C-13) of the associated dissolved organic carbon (DOC). Water samples were collected from two compositionally distinct coastal river systems in the southeastern United Sta...
Constraints on the Magnitude of Vertical and Lateral Mass Transport on the Moon
NASA Technical Reports Server (NTRS)
Mustard, John F.
1997-01-01
The role of vertical and lateral mass transport of crustal materials on the observed patterns of lunar surface composition, and the effects on our understanding of the geologic evolution of the planet, have been the subject of much debate in the lunar science community. The primary consensus that emerged from analyses of these processes in the 1970's and 1980's was that vertical and lateral mixing through impact gardening was a relatively inefficient process, and not likely to have contributed significantly to compositional units and variations on the Moon. The supporting evidence for this view is that unit boundaries (e.g. mare-highland contacts, contacts between mare color units) are still apparently quite distinct and sharp despite several aeons of impact activity, and cores from the Apollo landing sites did not show any evidence of widespread homogenization of the surface composition, nor distinct compositional gradients across geologic boundaries. In addition, modeling of vertical and lateral transport generally showed that the effects on composition should be confined to horizontal scales of about a kilometer and vertical scales of a meter. The problem with this consensus is that there is ample contradictory evidence. The fundamental discovery of Wood et al. (1970) was made possible by significant horizontal transport of highland material to the center of Mare Tranquillitatis. The continuous and discontinuous ejecta from the crater Copernicus has clearly influenced the surface composition of a large area of the lunar maria, while rays and ejecta from many highland craters are easily recognized in and around the nearside maria. Despite this contrary evidence, there have been few detailed studies to quantify the amount and rate of material redistribution through impact processes (a notable exception is reported in the paper by Pieters et al, 1985), largely because data adequate to critically analyze this process were lacking. However, the multispectral images acquired by the Galileo and Clementine missions now permit the investigation of this process.
Value Preferences Associated With Social Class, Sex, and Race
ERIC Educational Resources Information Center
Malpass, Roy S.; Symonds, John D.
1974-01-01
Preferences for 92 values were measured for 10 groups of black and white males and females of lower and middle class status in two geographically distinct settings in the United States. Factor analysis showed five shared value composites: (1) the good life, (2) pleasant working companions, (3) balance and adjustment; (4) artistic creativity, and…
Composite Calderas: The Long and Short of it
NASA Astrophysics Data System (ADS)
Gravley, D. M.; Hasegawa, T.; Nakagawa, M.; Wilson, C. J.
2006-12-01
Calderas formed in supereruptions are normally linked to a single magma body. However, caldera formation, regional tectonics, and multiple magma bodies may interact to form composite structures with complex geometries. The term composite caldera is often used without reference as to whether the `composite' is in time or space. Three examples of composite caldera styles from New Zealand and Japan show field, geophysical, geochemical and isotopic evidence to suggest that current models for the size, shape and evolution of calderas may be too simplistic. In our examples, multiple separate magma bodies distributed in either space or time, or both, may play a significant role in composite caldera formation. Multiple, clustered collapse events incremental in time: Akan caldera in Hokkaido appears to be a single, rectangular shaped caldera. However, the identification of 17 eruptive units spanning >1 Myr suggests that the caldera evolved incrementally over time and space. New gravity data shows that the caldera is actually a daisy-chain of 3 distinct collapse structures that can be correlated, using lithic componentry, to 3 major geochemical groups in the eruptive products. Multiple, clustered collapse events in a single eruption sequence: Shikotsu caldera in Hokkaido was originally thought to have formed following the eruption of a single large zoned magma chamber. However, the caldera-related deposits are characterized by several geochemically distinct pumice types that can not have been accommodated in a single magma system. Our studies suggest that the variations in pumice compositions are consistent with multiple distinct magma bodies feeding coeval eruptions from several vent sources within an area that collapsed to form a single caldera. Paired calderas with linking eruption-related regional faulting: Rotorua and Ohakuri calderas in New Zealand are 30 km apart and formed in close succession during a complex but virtually continuous eruption sequence at ca. 240 ka. The distinct calderas are joined in dumb-bell fashion by an intervening zone of eruption-related and immediately post-eruptive faulting and collapse.
Age Distribution of Lunar Impact-Melt Rocks in Apollo Drive-Tube 68001/2
NASA Technical Reports Server (NTRS)
Curran, N. M.; Bower, D. M.; Frasl, B.; Cohen, B. A.
2018-01-01
Apollo 16 double-drive tube 68001 /68002 provides impact and volcanic materials along a depth of approximately 60 cm in five compositional distinct units. 68001 /2 offers the potential to study distinct populations of impact melts with depth to understand how 'gardening' affects these samples. We will use unbiased major-element chemistry, mineralogy, and age to understand the impact history of Apollo 16 landing site. The study demonstrates the techniques that landed missions require to identify lithologies of interest (e.g., impact melts).
Is face distinctiveness gender based?
Baudouin, Jean-Yves; Gallay, Mathieu
2006-08-01
Two experiments were carried out to study the role of gender category in evaluations of face distinctiveness. In Experiment 1, participants had to evaluate the distinctiveness and the femininity-masculinity of real or artificial composite faces. The composite faces were created by blending either faces of the same gender (sexed composite faces, approximating the sexed prototypes) or faces of both genders (nonsexed composite faces, approximating the face prototype). The results show that the distinctiveness ratings decreased as the number of blended faces increased. Distinctiveness and gender ratings did not covary for real faces or sexed composite faces, but they did vary for nonsexed composite faces. In Experiment 2, participants were asked to state which of two composite faces, one sexed and one nonsexed, was more distinctive. Sexed composite faces were selected less often. The results are interpreted as indicating that distinctiveness is based on sexed prototypes. Implications for face recognition models are discussed. ((c) 2006 APA, all rights reserved).
Multispectral mapping of the lunar surface using groundbased telescopes
NASA Technical Reports Server (NTRS)
Mccord, T. B.; Pieters, C.; Feirberg, M. A.
1976-01-01
Images of the lunar surface were obtained at several wavelengths using a silicon vidicon imaging system and groundbased telescopes. These images were recorded and processed in digital form so that quantitative information is preserved. The photometric precision of the images is shown to be better than 1 percent. Ratio images calculated by dividing images obtained at two wavelengths (0.40/0.56 micrometer) and 0.95/0.56 micrometer are presented for about 50 percent of the lunar frontside. Spatial resolution is about 2 km at the sub-earth point. A complex of distinct units is evident in the images. Earlier work with the reflectance spectrum of lunar materials indicates that for the most part these units are compositionally distinct. Digital images of this precision are extremely useful to lunar geologists in disentangling the history of the lunar surface.
Robert T. Brooks
2003-01-01
Early-successional forests are ephemeral and distinct forest communities, maintained by disturbance and dominated by small-sized trees and shrubs. These structural and compositional conditions form a unique habitat that is preferred by many wildlife species. Various sources have indicated that there have been declines in early-successional forest area and in the...
Complex Processes from Dynamical Architectures with Time-Scale Hierarchy
Perdikis, Dionysios; Huys, Raoul; Jirsa, Viktor
2011-01-01
The idea that complex motor, perceptual, and cognitive behaviors are composed of smaller units, which are somehow brought into a meaningful relation, permeates the biological and life sciences. However, no principled framework defining the constituent elementary processes has been developed to this date. Consequently, functional configurations (or architectures) relating elementary processes and external influences are mostly piecemeal formulations suitable to particular instances only. Here, we develop a general dynamical framework for distinct functional architectures characterized by the time-scale separation of their constituents and evaluate their efficiency. Thereto, we build on the (phase) flow of a system, which prescribes the temporal evolution of its state variables. The phase flow topology allows for the unambiguous classification of qualitatively distinct processes, which we consider to represent the functional units or modes within the dynamical architecture. Using the example of a composite movement we illustrate how different architectures can be characterized by their degree of time scale separation between the internal elements of the architecture (i.e. the functional modes) and external interventions. We reveal a tradeoff of the interactions between internal and external influences, which offers a theoretical justification for the efficient composition of complex processes out of non-trivial elementary processes or functional modes. PMID:21347363
Bortolotto, Tissiana; Betancourt, Francisco; Krejci, Ivo
2016-12-01
This study evaluated the influence of curing devices on marginal adaptation of cavities restored with self-etching adhesive containing CQ and PPD initiators and hybrid composite. Twenty-four class V (3 groups, n=8) with margins located on enamel and dentin were restored with Clearfil S3 Bond and Clearfil APX PLT, light-cured with a monowave LED, multiwave LED and halogen light-curing unit (LCU). Marginal adaptation was evaluated with SEM before/after thermo-mechanical loading (TML). On enamel, significantly lower % continuous margins (74.5±12.6) were found in group cured by multiwave LED when compared to monowave LED (87.6±9.5) and halogen LCU (94.4±9.1). The presence of enamel and composite fractures was significantly higher in the group light-cured with multiwave LED, probably due to an increased materials' friability resulted from an improved degree of cure. The clinician should aware that due to a distinct activation of both initiators, marginal quality may be influenced on the long-term.
NASA Astrophysics Data System (ADS)
Heywood, L. J.; DeBari, S. M.; Schindlbeck, J. C.; Escobar-Burciaga, R. D.
2015-12-01
The Izu Bonin rear arc represents a unique laboratory to study the development of continental crust precursors at an intraoceanic subduction zone., Volcanic output in the Izu Bonin rear arc is compositionally distinct from the Izu Bonin main volcanic front, with med- to high-K and LREE-enrichment similar to the average composition of the continental crust. Drilling at IODP Expedition 350 Site U1437 in the Izu Bonin rear arc obtained volcaniclastic material that was deposited from at least 13.5 Ma to present. IODP Expedition 350 represents the first drilling mission in the Izu Bonin rear arc region. This study presents fresh glass and mineral compositions (obtained via EMP and LA-ICP-MS) from unaltered tephra layers in mud/mudstone (Lithostratigraphic Unit I) and lapillistone (Lithostratigraphic Unit II) <4.5 Ma to examine the geochemical signature of Izu Bonin rear arc magmas. Unit II samples are coarse-grained tephras that are mainly rhyolitic in composition (72.1-77.5 wt. % SiO2, 3.2-3.9 wt. % K2O and average Mg# 24) and LREE-enriched. These rear-arc rhyolites have an average La/Sm of 2.6 with flat HREEs, average Th/La of 0.15, and Zr/Y of 4.86. Rear-arc rhyolite trace element signature is distinct from felsic eruptive products from the Izu Bonin main volcanic front, which have lower La/Sm and Th/La as well as significantly lower incompatible element concentrations. Rear arc rhyolites have similar trace element ratios to rhyolites from the adjacent but younger backarc knolls and actively-extending rift regions, but the latter is typified by lower K2O, as well as a smaller degree of enrichment in incompatible elements. Given these unique characteristics, we explore models for felsic magma formation and intracrustal differentiation in the Izu Bonin rear arc.
1989-08-28
Voyager violet, green and ultraviolet images of Triton were map projected into cylindrical coordinates and combines to produce this false-color terrain map. Several compositionally distinct terrain and geologic features are portrayed. At center is a gray-blue unit referred to as 'cantaloupe' terrain because of its unusual topographic texture. The unit appears to predate other units to the left. Immediately adjacent to the cantaloupe terrain, is a smoother unit, represented by a reddish color, that has been dissected by a prominent fault system. This unit apparently overlies a much-higher-albedo material, seen farther left. A prominent angular albedo boundary separates relatively undisturbed smooth terrain from irregular patches which seem to emanate from circular, often bright-centered features. The parallel streaks may represent vented particulate materials blown in the same direction by winds in Triton's thin atmosphere.
Geomorphic Terrains and Evidence for Ancient Volcanism within Northeastern South Pole-Aitken Basin
NASA Technical Reports Server (NTRS)
Petro, Noah; Mest, Scott C.; Teich, Yaron
2010-01-01
The interior of the enigmatic South Pole-Aitken Basin has long been recognized as being compositionally distinct from its exterior. However, the source of the compositional anomaly has been subject to some debate. Is the source of the iron-enhancement due to lower-crustal/upper-mantle material being exposed at the surface, or was there some volume of ancient volcanism that covered portions of the basin interior? While several obvious mare basalt units are found within the basin and regions that appear to represent the original basin interior, there are several regions that appear to have an uncertain origin. Using a combination of Clementine and Lunar Orbiter images, several morphologic units are defined based on albedo, crater density, and surface roughness. An extensive unit of ancient mare basalt (cryptomare) is defined and, based on the number of superimposed craters, potentially represents the oldest volcanic materials within the basin. Thus, the overall iron-rich interior of the basin is not solely due to deeply derived crustal material, but is, in part due to the presence of ancient volcanic units.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smith, E.I.; Morikawa, S.A.; Martin, M.W.
1993-04-01
The Tuff of Bridge Spring (TBS) (15.19[+-]0.02 Ma; Gans, 1991) is a compositionally variable dacite to rhyolite ash-flow tuff that crops out over 1800 sq. km in the northern Colorado River extensional corridor. The TBS varies in composition from 59.5 to 74 wt. % SiO[sub 2] and typically contains phenocrysts of sanidine, plagioclase, biotite, clinopyroxene, [+-] sphene, [+-] apatite, [+-] zircon, and [+-] hornblende. The TBS is thickest and displays its greatest compositional range in the center of its area of exposure. The McCullough Range section contains at least three chemically distinct flow units that vary in composition from dacitemore » to rhyolite. The basal and uppermost units are normally zoned and the middle unit is reversely zoned. The complex chemical zonation and zoning reversals in the TBS indicate that it erupted from a magma chamber that was periodically injected by both mafic and felsic magmas. Sections at the edge of the exposure area are thin, contain only one or two chemically definable flow units and have a limited compositional range. To the west at Sheep Mountain, TBS is 2.9 m thick and ranges from 70.2--71.7 wt % SiO[sub 2]. To the east in the White Hills, TBS is 14 m thick and ranges from 59.5--65.3 wt % SiO[sub 2]. This chemical and field data indicate that although the TBS is regionally extensive, individual flow units are not. Isotopic data and chemistry suggest that all sections of the TBS are cogenetic. Comparisons of chemical, geochronological and isotopic data between the TBS and nearby coeval plutons indicate that the Aztec Wash (Eldorado Mts., Nevada) and Mt. Perkins (Black Mountain, Arizona) plutons are possible source for the TBS. Both plutons exhibit ample evidence of magma mixing and commingling, processes that may produce compositional zonation such as that observed in the TBS.« less
Geochemical Comparison of Four Cores from the Manson Impact Structure
NASA Technical Reports Server (NTRS)
Korotev, Randy L.; Rockow, Kaylynn M.; Jolliff, Bradley L.; Haskin, Larry A.; McCarville, Peter; Crossey, Laura J.
1996-01-01
Concentrations of 33 elements were determined in relatively unaltered, matrix-rich samples of impact breccia at approximately 3-m-depth intervals in the M-1 core from the Manson impact structure, Iowa. In addition, 46 matrix-rich samples from visibly altered regions of the M-7, M-8, and M-10 cores were studied, along with 42 small clasts from all four cores. Major element compositions were determined for a subset of impact breccias from the M-1 core, including matrix-rich impact-melt breccia. Major- and trace-element compositions were also determined for a suite of likely target rocks. In the M-1 core, different breccia units identified from lithologic examination of cores are compositionally distinct. There is a sharp compositional discontinuity at the boundary between the Keweenawan-shale-clast breccia and the underlying unit of impact-melt breccia (IMB) for most elements, suggesting minimal physical mixing between the two units during emplacement. Samples from the 40-m-thick IMB (M-1) are all similar to each other in composition, although there are slight increases in concentration with depth for those elements that have high concentrations in the underlying fragmental-matrix suevite breccia (SB) (e.g., Na, Ca, Fe, Sc), presumably as a result of greater clast proportions at the bottom margin of the unit of impact-melt breccia. The high degree of compositional similarity we observe in the impact-melt breccias supports the interpretation that the matrix of this unit represents impact melt. That our analyses show such compositional similarity results in part from our technique for sampling these breccias: for each sample we analyzed a few small fragments (total mass: approximately 200 mg) selected to be relatively free of large clasts and visible signs of alteration instead of subsamples of powders prepared from a large mass of breccia. The mean composition of the matrix-rich part of impact-melt breccia from the M-1 core can be modeled as a mixture of approximately 35% shale and siltstone (Proterozoic "Red Clastics"), 23% granite, 40% hornblende-biotite gneiss, and a small component (less than 2%) of mafic-dike rocks.
Hults, Chad P.; Wilson, Frederic H.; Donelick, Raymond A.; O'Sullivan, Paul B.
2013-01-01
The provenance of Jurassic to Cretaceous flysch along the northern boundary of the allochthonous Wrangellia composite terrane, exposed from the Lake Clark region of southwest Alaska to the Nutzotin Mountains in eastern Alaska, suggests that the flysch can be divided into two belts having different sources. On the north, the Kahiltna flysch and Kuskokwim Group overlie and were derived from the Farwell and Yukon-Tanana terranes, as well as smaller related terranes that were part of the paleo-Alaskan margin. Paleocurrent indicators for these two units suggest that they derived sediment from the north and west. Sandstones are predominantly lithic wacke that contain abundant quartz grains, lithic rock fragments, and detrital mica, which suggest that these rocks were derived from recycled orogen and arc sources. Conglomerates contain limestone clasts that have fossils matching terranes that made up the paleo-Alaskan margin. In contrast, flysch units on the south overlie and were derived from the Wrangellia composite terrane. Paleocurrent indicators for these units suggest that they derived sediment from the south. Sandstones are predominantly feldspathic wackes that contain abundant plagioclase grains and volcanic rock fragments, which suggest these rocks were derived from an arc. Clast compositions in conglomerate south of the boundary match rock types of the Wrangellia composite terrane. The distributions of detrital zircon ages also differentiate the flysch units. Flysch units on the north average 54% Mesozoic, 14% Paleozoic, and 32% Precambrian detrital zircons, reflecting derivation from the older Yukon-Tanana, Farewell, and other terranes that made up the paleo-Alaskan margin. In comparison, flysch units on the south average 94% Mesozoic, 1% Paleozoic, and 5% Precambrian zircons, which are consistent with derivation from the Mesozoic oceanic magmatic arc rocks in the Wrangellia composite terrane. In particular, the flysch units on the south contain a large proportion of zircons ranging from 135 to 175 Ma, corresponding to the age of the Chitina magmatic arc in the Wrangellia terrane and the plutons of the Peninsular terrane, which are part of the Wrangellia composite terrane. Flysch units on the north do not contain significant numbers of zircons in this age range. The flysch overlying the Wrangellia composite terrane apparently does not contain detritus derived from rocks of the paleo-Alaska margin, and the flysch overlying the paleo-Alaskan margin apparently does not contain detritus derived from the Wrangellia composite terrane. The provenance difference between the two belts helps to constrain the location of the northern boundary of the Wrangellia composite terrane. Geophysical models place a deep, through-going, crustal-scale suture zone in the area between the two flysch belts. The difference in the provenance of the two belts supports this interpretation. The youngest flysch is Late Cretaceous in age, and structural disruption of the flysch units is constrained to the Late Cretaceous, so it appears that the Wrangellia composite terrane was not near the paleo-Alaskan margin until the Late Cretaceous.
Miller, C.F.; Wooden, J.L.
1994-01-01
A compositionally expanded array of granitic (s.l.) magmas intruded the > 2 Ga crust of the Old Woman Mountains area between 160 and 70 Ma. These magmas were emplaced near the eastern (inland) edge of the Jurassic/Cretaceous arcs of western North America, in an area where magma flux, especially during the Jurassic, was considerably lower than to the west. The Jurassic intrusives and over half of the Cretaceous intrusives are predominantly metaluminous and variable in composition; a major Cretaceous suite comprises only peraluminous monzogranite. Only the Jurassic intrusions show clear evidence for the presence of mafic liquids. All units, including the most mafic rocks, reveal isotopic evidence for a significant crustal component. However, none of the Mesozoic intrusives matches in isotopic composition either average pre-intrusion crust or any major unit of the exposed crust. Elemental inconsistencies also preclude closed system derivation from exposed crust. Emplacement of these magmas, which doubled the volume of the mid- to upper crust, did not dramatically change its elemental composition. It did, however, affect its Nd and especially Sr isotopic composition and modify some of the distinctive aspects of the elemental chemistry. We propose that Jurassic magmatism was open-system, with a major influx of mantle-derived mafic magma interacting strongly with the ancient crust. Mesozoic crustal thickening may have led to closed-system crustal melting by the Late Cretaceous, but the deep crust had been profoundly modified by earlier Mesozoic hybridization so that crustal melts did not simply reflect the original crustal composition. The clear evidence for a crustal component in magmas of the Old Woman Mountains area may not indicate any fundamental differences from the processes at work elsewhere in this or other magmatic arcs where the role of pre-existing crust is less certain. Rather, a compositionally distinctive, very old crust may simply have yielded a more readily identifiable crustal fingerprint. The same processes that were involved here-mafic magma influx, hybridization, and remelting of hybridized crust-are likely to be typical of arc settings. ?? 1994.
Stith, David A.
1981-01-01
The chemical composition and stratigraphy of the Black River Group in southwestern Ohio were studied. Chemical analyses were done on two cores of the Black River from Adams and Brown Counties, Ohio. These studies show that substantial reserves of high-carbonate rock are present in the Black River at depths of less than 800 ft, in proximity to Cincinnati and the Ohio River. Stratigraphic studies show that the Black River Group has eight marker beds in its middle and upper portions and three distinct lithologic units in its lower portion; these marker beds and units are present throughout southwestern Ohio. The Black River Group correlates well with the High Bridge Group of Kentucky. Depositional environments of the Black River are similar to those of the High Bridge and to present-day tidal flats in the Bahamas.-Author
Single Sublattice Endotaxial Phase Separation Driven by Charge Frustration in a Complex Oxide
2013-01-01
Complex transition-metal oxides are important functional materials in areas such as energy and information storage. The cubic ABO3 perovskite is an archetypal example of this class, formed by the occupation of small octahedral B-sites within an AO3 network defined by larger A cations. We show that introduction of chemically mismatched octahedral cations into a cubic perovskite oxide parent phase modifies structure and composition beyond the unit cell length scale on the B sublattice alone. This affords an endotaxial nanocomposite of two cubic perovskite phases with distinct properties. These locally B-site cation-ordered and -disordered phases share a single AO3 network and have enhanced stability against the formation of a competing hexagonal structure over the single-phase parent. Synergic integration of the distinct properties of these phases by the coherent interfaces of the composite produces solid oxide fuel cell cathode performance superior to that expected from the component phases in isolation. PMID:23750709
NASA Astrophysics Data System (ADS)
Bergmanis, E. C.; Sinton, J. M.; Rubin, K. H.
2003-12-01
Major, trace element and U-series disequilibria data reveal both short- and long-term compositional heterogeneity in lavas from the southern EPR 17° 23'-17° 35'S. Major-element compositional variation in the ˜18km-long Aldo-Kihi flow (MgO 7.7-8.4 wt %) is consistent with shallow-level fractional crystallization. (230Th)/(238U) disequilibria for samples from the Aldo-Kihi flow cover a narrow range of 1.85+/-0.15. However, the range of Th/U ratios (2.61-2.84) and (226Ra)/(230Th) disequilibria (2.26-2.65) are very broad for a single eruptive unit and cannot be a result of shallow-level fractional crystallization of a single magma composition. MgO contents, Th/U ratios, and (226Ra)/(230Th) disequilibria for Aldo-Kihi samples all peak at ˜17° 30.6'S and generally are greater for samples south of 17° 30'S implying that more than one magmatic component has contributed to this lava flow. This along-axis compositional diversity is hard to reconcile with propagation of a dike originating from a small area, and suggests vertical eruption from a magma chamber that is compositionally zoned along-axis. Along this ˜22km-long section of the southern EPR, major, trace element and U-series disequilibria data indicate that at least six compositionally distinct lava types are present within 1km of the axis. (210Pb)/(226Ra) deficits of ˜5 % for the Aldo-Kihi lava and two other compositionally distinct units suggest they are substantially younger than ˜100 yrs. Although geologic relationships demonstrate that Aldo-Kihi is the youngest of these, the range of (210Pb)/(230Ra) disequilibria for the individual units overlap making relative age determinations impossible using that criteria alone. Regional trends in major-element data show that twenty-three other samples older than Aldo-Kihi contain >8.0 wt % MgO; all but two occur south of 17° 28.4'S suggesting that the location of hottest sub-axial magma is a long-lived feature of this region. The distribution of rock types in this area requires a complex history of mantle melting, recharge, cooling, and eruption that varies considerably over along-axis distances of ˜22 kilometers and between successive eruptions.
NASA Technical Reports Server (NTRS)
Morris, R. V.; Ming, D. W.; Gellert, R.; Vaniman, D. T.; Bish, D. L.; Blake, D. F.; Chipera, S. J.; Morrison, S. M.; Downs, R. T.; Rampe, E. B.;
2015-01-01
We have previously calculated the chemical compositions of the X-ray-diffraction (XRD) amorphous component of three solid samples (Rocknest (RN) soil, John Klein (JK) drill fines, and Cumberland (CB) drill fines) using major-element chemistry (APXS), volatile-element chemistry (SAM), and crystalline- phase mineralogy (CheMin) obtained by the Curiosity rover as a part of the ongoing Mars Science Laboratory mission in Gale Crater. According to CheMin analysis, the RN and the JK and CB samples are mineralogically distinct in that RN has no detectable clay minerals and both JK and CB have significant concentrations of high-Fe saponite. The chemical composition of the XRD amorphous component is the composition remaining after mathematical removal of the compositions of crystalline components, including phyllosilicates if present. Subsequent to, we have improved the unit cell parameters for Fe-forsterite, augite, and pigeonite, resulting in revised chemical compositions for the XRD-derived crystalline component (excluding clay minerals). We update here the calculated compositions of amorphous components using these revised mineral compositions.
Patterns of variation in diversity of the Mississippi river microbiome over 1,300 kilometers
Payne, Jason T.; Millar, Justin J.; Jackson, Colin R.
2017-01-01
We examined the downriver patterns of variation in taxonomic diversity of the Mississippi River bacterioplankton microbiome along 1,300 river kilometers, or approximately one third the total length of the river. The study section included portions of the Upper, Middle, and Lower Mississippi River, confluences with five tributaries draining distinct sub-basins, river cities, and extended stretches without major inputs to the Mississippi. The composition and proportional abundance of dominant bacterial phyla was distinct for free-living and particle-associated cells, and constant along the entire reach, except for a substantial but transient disturbance near the city of Memphis, Tennessee. At a finer scale of taxonomic resolution (operational taxonomic units, OTUs), however, there were notable patterns in downriver variation in bacterial community alpha diversity (richness within a site) and beta diversity (variation in composition among sites). There was a strong and steady increase downriver in alpha diversity of OTUs on suspended particles, suggesting an increase in particle niche heterogeneity, and/or particle colonization. Relatively large shifts in beta diversity of free-living and particle-associated communities occurred following major tributary confluences and transiently at Memphis, while in long stretches between these points diversity typically varied more gradually. We conclude that the Mississippi River possesses a bacterioplankton microbiome distinct in diversity from other large river microbiomes in the Mississippi River Basin, that at major river confluences or urban point sources its OTU diversity may shift abruptly and substantially, presumably by immigration of distinct external microbiomes, but that where environmental conditions are more stable along the downriver gradient, microbiome diversity tends to vary gradually, presumably by a process of successional change in community composition. PMID:28350888
Nord, G.L.
1980-01-01
Lunar and terrestrial orthopyroxenes (Mg,Fe,Ca)2Si2O6 contain varying abundances of coherent, Ca-enriched Guinier-Preston (G.P.) zones. G.P. zones 5-6 unit cells thick have been found in one lunar sample whereas all other examples (lunar and terrestrial) are only one unit-cell-thick. Electron diffraction maxima from the larger lunar G.P. zones indicate that d100=18.52 A?? whereas, d100=18.2 A?? for the host. This increase in the a direction corresponds to an increase in calcium content in the G.P. zones over that of the host of ???25 mol% Ca2Si2O6. Diffraction patterns of the hk0 net from an area containing G.P. zones show extra spots (h=2 n+1) not observed in the host orthopyroxene (Pbca), that violate the a-glide of the host. The G.P. zones, therefore, have space group Pbc21 if it is assumed that the c-glide of pyroxene is retained and the space group of the G.P. zone is a subgroup of Pbca. The loss of the a-glide in the G.P. zones results in 4 distinct silica chains and 4 distinct cation sites M1A, M1B, M2A, M2B; by symmetry, equivalent M2A or M2B sites are clustered together in only one-half of the unit cell. As one-fourth of the divalent cations in the G.P. zones are calcium, ordering of Ca on M2A or M2B would produce a zone 9 A?? thick extended parallel to (100) with the composition of Ca(Mg,Fe)Si2O6, but constrained by the host to the structure of orthopyroxene. This zone and the Ca-poor half-unit-cell then constitute an 18 A?? thick G.P. zone. Heating experiments of varying duration indicate that the zones become unstable with respect to the host orthopyroxene at ???950??C for Wo0.6 and ???1,050??C for Wo2.5. The zones are interpreted in terms of the pyroxene subsolidus as a metastable phase having either a solvus relationship with orthopyroxene or originating as a distinct phase. The size, distribution, composition and structure of G.P. zones may be an important indicator of the low-temperature thermal history of orthopyroxene. ?? 1980 Springer-Verlag.
Fierstein, J.; Wilson, C.J.N.
2005-01-01
The 1912 Valley of Ten Thousand Smokes (VTTS) ignimbrite was constructed from 9 compositionally distinct, sequentially emplaced packages, each with distinct proportions of rhyolite (R), dacite (D), and andesite (A) pumices that permit us to map package boundaries and flow paths from vent to distal extents. Changing pumice proportions and interbedding relationships link ignimbrite formation to coeval fall deposition during the first ???16 h (Episode I) of the eruption. Pumice compositional proportions in the ignimbrite were estimated by counts on ???100 lapilli at multiple levels in vertical sections wherever accessible and more widely over most of the ignimbrite surface in the VTTS. The initial, 100% rhyolite ignimbrite package (equivalent to regional fall Layer A and occupying ???3.5 h) was followed by packages with increasing proportions of andesite, then dacite, emplaced over ???12.5 h and equivalent to regional fall Layers B1-B3. Coeval fall deposits are locally intercalated with the ignimbrite and show parallel changes in R:D (rhyolite:dacite) proportions, but lack significant amounts of andesite. Andesite was thus dominantly a low-fountaining component in the eruption column and is preferentially represented in packages filling the VTTS north of the vent. The most extensive packages (3 and 4) occur in B1 and early B2 times where flow mobility and volume were optimized; earlier all-rhyolite flows (Package 1) were highly energetic but less voluminous, while later packages (5-9) were both less voluminous and emplaced at lower velocities. Package boundaries are expressed as one or more of the following: sharp color changes corresponding to compositional variations; persistent finer-grained basal parts of flow units; compaction swales filled by later packages; erosional channels cut by the flows that fill them; lobate accumulations of one package; and (mostly south of the vent) intercalated fall deposit layers. Clear flow-unit boundaries are best developed between ignimbrite of non-successive packages, indicating time breaks of tens of minutes to hours. Less well-defined stratification may represent rapidly emplaced successive flow units but often changes over short distances and indicates variations in localized depositional conditions. ?? 2005 Geological Society of America.
ChemCam Compositional Results from the Shaler Outcrop in Gale Crater, Mars (Invited)
NASA Astrophysics Data System (ADS)
Anderson, R. B.; Leveille, R. J.; Vaniman, D.; Williams, J.; Clegg, S. M.; Le Mouelic, S.; Wiens, R. C.; Edgar, L. A.; Newsom, H. E.; Clark, B. C.; Ollila, A.; Lewis, K. W.; Gupta, S.; Team, M.
2013-12-01
The Curiosity rover first visited the outcrop known as 'Shaler' on Sol 121 of the mission. The ~1 m thick outcrop is the 'type section' for the Shaler member, which forms the uppermost part of the Yellowknife Bay formation. The Shaler outcrop exhibits multiple well-exposed cross-bedded facies with typical grain sizes of 1-2 mm, most consistent with fluvial deposition. Initial results from the two Sol 121 observations of Shaler by the ChemCam instrument showed similar composition, with a mix of mafic silicates and feldspar grains. A strong correlation between iron and titanium indicates the possible presence of titanomagnetite or ilmenite. CaO shows an anticorrelation with the total of the measured major elements, suggesting that it may be related to a non-silicate phase such as a salt. The rover returned to the outcrop on Sols 309-324. Because of the rugged nature of the outcrop, much of the exposed rock was not reachable by the rover's robotic arm. However, the ChemCam instrument can collect elemental compositional information out to a range of ~7 m using laser-induced breakdown spectroscopy (LIBS), and can acquire high-resolution images at even greater range. ChemCam analyzed 29 locations using LIBS to determine chemical composition, and four additional locations were imaged with the Remote Micro Imager. The targets analyzed included both fine- and coarse-grained facies, as well as a distinct upper unit which appears darker and less red than other Shaler units in Mastcam images, and lacks the striking alternating resistant and recessive cross-bedding observed in lower Shaler. This upper unit occurs at an elevation similar to the rocks at 'Rocknest', and similar-looking rocks appear across the cratered surface to the south and east of Shaler. Several blocks apparently derived from this upper unit were analyzed by ChemCam to test the hypothesis that the unit is related to rocks observed at Rocknest. Work is ongoing to interpret the results of the ChemCam campaign at Shaler. This work includes localization of individual laser analysis points to relate fine-scaled texture and grain size to chemical compositions, analysis of detectable minor and trace elements, identification of compositional trends related to facies type, comparison with compositions of other stratigraphic units in Gale crater, and chemical classification based on terrestrial sedimentary geochemistry.
Granulite-facies rocks in the Whatley Mill gneiss, Pine Mountain basement massif, Eastern Alabama
DOE Office of Scientific and Technical Information (OSTI.GOV)
Daniell, N.; Salpas, P.A.
1993-03-01
The Pine Mountain basement massif is a granulite terrane exposed in a tectonic window through the Inner Piedmont of western Georgia and eastern Alabama. Investigations of the westernmost extent of the massif, the Whatley Mill Gneiss, have revealed four distinct lithologies: (1) an augen gneiss, the type lithology; (2) mylonite that develops in the shear zones cutting the unit; (3) a phaneritic rock showing weak to no foliation; (4) enclaves of biotite gneiss within the weakly-foliated rock. Additionally, the weakly-foliated rock comprises two distinct phases which are in sharp contact along curved and undulating boundaries: phase 1 is a coarser-grainedmore » rock; phase 2 is a finer-grained rock of the same mineralogy as phase 1 except it contains rare hypersthene. This first recorded observation of hypersthene unequivocally confirms the granulite-facies origin of the unit. Major and trace element compositions of the phase 1 rock are identical to those of the augen gneiss. The phase 2 rock, has a distinct composition with higher SiO[sub 2] and lower incompatible trace elements than the phase 1 rock. The enclaves display a range in major elements but higher incompatible elements than the other lithologies. Geochemical and petrologic relationships leads one to interpret: (1) the weakly-foliated rock retains many of its primary igneous features including its two phases and enclaves; (2) the two phases of the weakly-foliated rock arose as a result of injection of one magma (phase 2) into a cooler, crystal mush solidifying from another magma (phase 1); (3) the enclaves represent either autoliths of xenoliths; (4) the augen gneiss arose by isochemical deformation of the phase 1 rock.« less
Surface compositions in the Aristarchus Region: Implications for regional stratigraphy
NASA Technical Reports Server (NTRS)
Hawke, H. R.; Lucey, P. G.; Mccord, T. B.; Pieters, C. M.; Head, J. W.
1984-01-01
Near infrared reflectance spectra for the Aristachus region, obtained using the 2.2m UH telescope at the Mauna Kea Observatory, were reduced and analyzed. The spectra obtained for the central peak, southern floor, southwestern wall, eastern wall, and northwestern wall of Aristachus crater exhibit shallow continuum slopes, relatively strong feldspar bands, pyroxene bands stronger than those typically seen in the spectra of fresh higland features, and pyroxene band centers near l micrometer suggesting the dominance of Ca rich clinopyroxene. The spectrum of the south rim of Aristachus is quite distinct from those of other crater units. The position of Aristrchus on the plateau/mare boundary raises questions concerning compositional variations in crater ejects deposits.
Composition and maturity of the 60013/14 core
NASA Technical Reports Server (NTRS)
Korotev, Randy L.; Morris, Richard V.; Lauer, Howard V., Jr.
1993-01-01
The 60013/14 double drive tube (62 cm deep) is one of three regolith cores taken 35-40 m apart in a triangular array on the Cayley plains at station 10' (LM/ALSEP), Apollo 16. This trio, which includes double drive tube 60009/10 (59 cm deep) and deep drill core 60001-7 (220 cm), is the only such array of cores returned from the Moon. The top 45 cm of 60013/14 is mature, as is surface reference soil 60601 taken nearby. Maturity generally decreases with depth, with soil below 45 cm being submature. The zone of lowest maturity (34 is less than or equal to I(sub s)/FeO is less than 50) extends from 46 to 58 cm depth, and corresponds to the distinct region of light-colored soil observed during core processing. In the other two cores, most of the compositional variation results from mixing between fine-grained, mature soil with 10-11 micro-g/g Sc and coarse-grained ferroan anorthosite consisting of greater than 99% plagioclase with less than 0.5 micro-g/g Sc. This is most evident in 60009/10 which contains a high abundance of plagioclase at about 54 cm depth (minimum Sc: 3-4 micro-g/g); a similar zone occurs in 60001-7 at 17-22 cm (MPU-C), although it is not as rich in plagioclase (minimum Sc: 6-7 micro-g/g). Compositional variations are less in 60013/14 than in the other two cores (range: 7.9-10.0 micro-g/g Sc), but are generally consistent with the 'plagioclase dilution' effect seen in 60009/10, i.e., most 60013/14 samples plot along the mixing line of 60009/10. However, a plagioclase component is not the cause of the lower maturity and lighter color of the unit at 46-58 cm depth in 60013/14. Many of the samples in this zone have distinctly lower Sm/Sc ratios than typical LM-area soils and plot off the mixing trend defined by 60009/10. This requires a component with moderately high Sc, but low-Sm/Sc, such as feldspathic fragmental breccia (FFB) or granulitic breccia. A component of Descartes regolith, such as occurs at North Ray Crater (NRC) and which is rich in FFB, could account for the composition of these soils (i.e., a 3:1 mixture of 60601 and NRC soil). It seems unlikely that NRC ejecta would occur half a meter deep at the LM station, thus this low-Sm/Sc component may result from an older, local crater that penetrated the Cayley surface layer and excavated underlying Descartes material, as did North Ray Crater. There is no evidence for such a unit or component in the other two cores. Soil below the light-colored unit (58-62) cm has 'typical' Sm/Sc ratios, but the lowest absolute Sc concentrations, i.e., it is compositionally equivalent to a mixture of surface soil and plagioclase such as that in ferroan anorthosite. This is the only soil that might be related to the plagioclase-rich units in the other two cores. Except for the mature soil at the top of each core and, perhaps, the plagioclase-rich layers, there is little compositional evidence for any common unit among the three cores. Soil corresponding to the mare-glass-bearing unit (MPU-B) and regolith-breccia-bearing unit (MPU-A) of 60001-7 do not occur in 60013/14 or 60009/10.
Contrasted glass-whole rock compositions and phenocryst re-distribution, IPOD Sites 417 and 418
NASA Astrophysics Data System (ADS)
Staudigel, H.; Bryan, W. B.
1982-01-01
Major element composition ranges of closely associated basalt glass-whole rock pairs from individual small cooling units approach the total known range of basalt glass and whole rock compositions at IPOD sites 417 and 418. The whole rock samples fall into two groups: one is depleted in MgO and distinctly enriched in plagioclase but has lost some olivine and/or pyroxene relative to its corresponding glass; and the other is enriched in MgO and in phenocrysts of olivine and pyroxene as well as plagioclase compared to its corresponding glass. By analogy with observed phenocryst distributions in lava pillows, tubes, and dikes, and with some theoretical studies, we infer that bulk rock compositions are strongly affected by phenocryst redistribution due to gravity settling, flotation, and dynamic sorting after eruption, although specific models are not well constrained by the one-dimensional geometry of drill core. Compositional trends or groupings in whole rock data resulting from such late-stage processes should not be confused with more fundamental compositional effects produced in deep chambers or during partial melting.
South polar residual cap of Mars: Features, stratigraphy, and changes
NASA Astrophysics Data System (ADS)
Thomas, P. C.; Malin, M. C.; James, P. B.; Cantor, B. A.; Williams, R. M. E.; Gierasch, P.
2005-04-01
The south residual polar cap of Mars, rich in CO 2 ice, is compositionally distinct from the north residual cap which is dominantly H 2O ice. The south cap is also morphologically distinct, displaying a bewildering variety of depressions formed in thin layered deposits, which have been observed to change by scarp retreat over an interval of one Mars year (Malin et al., 2001, Science 294, 2146-2148). The climatically sensitive locale of the residual caps suggests that their behavior may help in the interpretation of recent fluctuations or repeatability of the Mars climate. We have used Mars Global Surveyor Mars Orbiter Camera (MOC) images obtained in three southern summers to map the variety of features in the south residual cap and to evaluate changes over two Mars years (Mars y). The images show that there are two distinct layered units which were deposited at different times separated by a period of degradation. The older unit, ˜10 m thick, has layers approximately 2 m thick. The younger unit has variable numbers of layers, each ˜1 m thick. The older unit is eroding by scarp retreat averaging 3.6 m/Mars y, a rate greater than the retreat of 2.2 m/Mars y observed for the younger unit. The rates of scarp retreat and sizes of the different types of depressions indicate that the history of the residual cap has been short periods of deposition interspersed with longer erosional periods. Erosion of the older unit probably occupied ˜100-150 Mars y. One layer may have been deposited after the Mariner 9 observations in 1972. Residual cap layers appear to differ from normal annual winter deposits by having a higher albedo and perhaps by having higher porosities. These properties might be produced by differences in the depositional meteorology that affect the fraction of high porosity snow included in the winter deposition.
Local unitary invariants for N-qubit pure states
NASA Astrophysics Data System (ADS)
Sharma, S. Shelly; Sharma, N. K.
2010-11-01
The concept of negativity font, a basic unit of multipartite entanglement, is introduced. Transformation properties of determinants of negativity fonts under local unitary (LU) transformations are exploited to obtain relevant N-qubit polynomial invariants and construct entanglement monotones from first principles. It is shown that entanglement monotones that detect the entanglement of specific parts of the composite system may be constructed to distinguish between states with distinct types of entanglement. The structural difference between entanglement monotones for an odd and even number of qubits is brought out.
Distinctiveness, use, and value of midwestern oak savannas and woodlands as avian habitats
Grundel, R.; Pavlovic, N.B.
2007-01-01
Oak savannas and woodlands historically covered millions of hectares in the midwestern United States but are rare today. We evaluated the ecological distinctiveness and conservation value of savannas and woodlands by examining bird distributions across a fire-maintained woody-vegetation gradient in northwest Indiana encompassing five habitats—open habitats with low canopy cover, savannas, woodlands, scrublands, and forests—during migration, breeding, and overwintering. Savannas and woodlands were significantly different in overall bird species composition from open and forest habitats but were often intermediate between open and forest in guild densities. Few bird species were consistently and highly concentrated in savannas or woodlands, and the Red-headed Woodpecker (Melanerpes erythrocephalus) was the only species significantly more abundant in savannas and woodlands than in open, scrub, and forest habitats. Fire frequency over a 15-year interval was a significant predictor of bird community composition and was positively related to species diversity, spring transient migrant density, and density of the most threatened species. Each habitat type had characteristics potentially important for avian conservation. Scrub had the highest density of transient migrants, which suggests it plays an important role as migration stopover habitat. More species were significantly concentrated in open or forest habitats than in the other habitats. Lack of species concentration and intermediate community composition suggested that birds experienced savannas and woodlands more as ecotones than as habitats distinct from forests or grasslands. However, this intermediate character can benefit conservation, as evidenced by savannas and woodlands having the highest density of the most threatened species along this woody-vegetation gradient.
Diesner, Susanne C.; Bergmayr, Cornelia; Pfitzner, Barbara; Assmann, Vera; Krishnamurthy, Durga; Starkl, Philipp; Endesfelder, David; Rothballer, Michael; Welzl, Gerhard; Rattei, Thomas; Eiwegger, Thomas; Szépfalusi, Zsolt; Fehrenbach, Heinz; Jensen-Jarolim, Erika; Hartmann, Anton
2017-01-01
In our mouse model, gastric acid-suppression is associated with antigen-specific IgE and anaphylaxis development. We repeatedly observed non-responder animals protected from food allergy. Here, we aimed to analyse reasons for this protection. Ten out of 64 mice, subjected to oral ovalbumin (OVA) immunizations under gastric acid-suppression, were non-responders without OVA-specific IgE or IgG1 elevation, indicating protection from allergy. In these non-responders, allergen challenges confirmed reduced antigen uptake and lack of anaphylactic symptoms, while in allergic mice high levels of mouse mast-cell protease-1 and a body temperature reduction, indicative for anaphylaxis, were determined. Upon OVA stimulation, significantly lower IL-4, IL-5, IL-10 and IL-13 levels were detected in non-responders, while IL-22 was significantly higher. Comparison of fecal microbiota revealed differences of bacterial communities on single bacterial Operational-Taxonomic-Unit level between the groups, indicating protection from food allergy being associated with a distinct microbiota composition in a non-responding phenotype in this mouse model. PMID:27789346
Composition formulas of binary eutectics
Ma, Y. P.; Dong, D. D.; Dong, C.; Luo, L. J.; Wang, Q.; Qiang, J. B.; Wang, Y. M.
2015-01-01
The present paper addresses the long-standing composition puzzle of eutectic points by introducing a new structural tool for the description of short-range-order structural unit, the cluster-plus-glue-atom model. In this model, any structure is dissociated into a 1st-neighbor cluster and a few glue atoms between the clusters, expressed by a cluster formula [cluster]gluex. This model is applied here to establish the structural model for eutectic liquids, assuming that a eutectic liquid consist of two subunits issued from the relevant eutectic phases, each being expressed by the cluster formula for ideal metallic glasses, i.e., [cluster](glue atom)1 or 3. A structural unit is then composed of two clusters from the relevant eutectic phases plus 2, 4, or 6 glue atoms. Such a dual cluster formulism is well validated in all boron-containing (except those located by the extreme phase diagram ends) and in some commonly-encountered binary eutectics, within accuracies below 1 at.%. The dual cluster formulas vary extensively and are rarely identical even for eutectics of close compositions. They are generally formed with two distinctly different cluster types, with special cluster matching rules such as cuboctahedron plus capped trigonal prism and rhombidodecahedron plus octahedral antiprism. PMID:26658618
NASA Astrophysics Data System (ADS)
Min, K.; Buckeridge, K. M.; Ziegler, S. E.; Edwards, K. A.; Bagchi, S.; Billings, S. A.
2016-12-01
The responses of heterotrophic microbial process rates to temperature in soils are often investigated in the short-term (hours to months), making it difficult to predict longer-term temperature responses. Here, we integrate the temperature sensitivity obtained from the Arrhenius model with the concepts of microbial resistance, resilience, and susceptibility to assess temporal dynamics of microbial temperature responses. We collected soils along a boreal forest climate gradient (long-term effect), and quantified exo-enzyme activities and CO2 respiration at 5, 15, and 25°C for 84 days (relatively short-term effect). Microbial process rates were examined at two levels (per g microbial biomass-C; and per g dry soil) along with community structure, to characterize driving mechanisms for temporal patterns (e.g., size of biomass, physiological plasticity, community composition). Although temperature sensitivity of exo-enzyme activities on a per g dry soil basis showed both resistance and resilience depending on the types of exo-enzyme, biomass -C-specific responses always exhibited resistance regardless of distinct community composition. Temperature sensitivity of CO2 respiration was constant across time and different communities at both units. This study advances our knowledge in two ways. First, resistant temperature sensitivity of exo-enzymes and respiration at biomass-C specific level across distinct communities and diverse timescales indicates a common relationship between microbial physiology and temperature at a fundamental level, a useful feature allowing microbial process models to be reasonably simplified. Second, different temporal responses of exo-enzymes depending on the unit selected provide a cautionary tale for those projecting future microbial behaviors, because interpretation of ecosystem process rates may vary with the unit of observation.
Characterization of Mineralogy Across Vesta
NASA Technical Reports Server (NTRS)
De Sanctis, M. C.; Ammannito, E.; Capria, M. T.; Capaccioni, F.; Carraro, F.; Fonte, S.; Frigeri, A.; Magni, G.; Marchi, S.; Palomba, E.;
2012-01-01
Dawn VIR spectra are characterized by pyroxene absorptions and no clear evidence for abundant other minerals are observed at the scale of the present measurements. Even though Vesta spectra are dominated by pyroxenes, spectral variation at regional and local scales are evident and distinct color units are identified. Although almost all of the surface materials exhibit spectra like those of howardites, some large units can be interpreted to be material richer in diogenite (based on pyroxenes band depths and band centers) and some others like eucrite-rich howardite units. VIR data strongly indicate that the south polar region (Rheasilvia) has its own spectral characteristics, indicating the presence of Mg-pyroxene-rich terrains (diogenite-like), while the equatorial areas have swallower band depths and average band centers at slightly longer wavelengths, consistent with more eucrite rich materials. Vesta surface shows considerable diversity at smaller scales (tens of km), in terms of spectral reflectance and emission, band depths and slopes. Many bright and dark spots are present on Vesta. Dark spots have low reflectance at visible wavelengths and are spectrally characterized by shallower 1 and 2 micron bands with respect the surrounding terrains. Bright materials have high reflectance and are often spectrally characterized by deep pyroxenes absorption bands. Vesta presents complex geology/topography and the mineral distribution is often correlated with geological and topographical structures. Ejecta from large craters have distinct spectral behaviors, and materials exposed in the craters show distinct spectra on floors and rims. VIR reveals the mineralogical variation of Vesta s crustal stratigraphy on local and global scales. Maps of spectral parameters show surface and subsurface unit compositions in their stratigraphic context. The hypothesis that Vesta is the HED parent body is consistent with, and strengthened by, the geologic and spectral context for pyroxene distribution provided by Dawn.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chen Yongqing, E-mail: ydonglai@mail.cgs.gov.cn; Zhao Pengda; Chen Jianguo
2001-03-15
A number of large and giant ore deposits have been discovered within the relatively small areas of lithospheric structure anomalies, including various boundary zones of tectonic plates. The regions have become the well-known intercontinental ore-forming belts, such as the circum-Pacific gold-copper, copper-molybdenum, and tungsten-tin metallogenic belts. These belts are typical geological anomalous areas. An investigation into the hydrothermal ore deposits in different regions in the former Soviet Union illustrated that the geologic structures of ore fields of almost all major commercial deposits have distinct features compared with the neighboring areas. These areas with distinct features are defined as geo-anomalies. Amore » geo-anomaly refers to such a geologic body or a combination of bodies that their composition, texture-structure, and genesis are significantly different from those of their surroundings. A geo-anomaly unit (GU) is an area containing distinct features that can be delineated with integrated ore-forming information using computer techniques on the basis of the geo-anomaly concept. Herein, the GU concept is illustrated by a case study of delineating the gold ore targets in the western Shandong uplift terrain, eastern China. It includes: (1) analyses of gold ore-forming factors; (2) compilation of normalized regional geochemical map and extraction of geochemical anomalies; (3) compilation of gravitational and aeromagnetic tectonic skeleton map and extraction of gravitational and aeromagnetic anomalies; (4) extraction of circular and linear anomalies from remote-sensing Landsat TM images; (5) establishment of a geo-anomaly conceptual model associated with known gold mineralization; (6) establishment of gold ore-forming favorability by computing techniques; and (7) delineation and assessment of ore-forming units. The units with high favorability are suggested as ore targets.« less
NASA Technical Reports Server (NTRS)
Korotev, Randy L.; Morris, Richard V.; Jolliff, Bradley L.; Schwarz, Carol
1997-01-01
Using FerroMagnetic Resonance (FMR) and Instrumental Neutron Activation Analysis (INAA), we have determined the maturity (surface exposure) parameter I(sub s)/FeO and concentrations of twenty- five chemical elements on samples taken every half centimeter down the 61-cm length of the 68001/2 regolith core (double drive tube) collected at station 8 on the Apollo 16 mission to the Moon. Contrary to premission expectations, no ejecta or other influence from South Ray crater is evident in the core, although a small inflection in the I(sub s)/FeO profile at 3 cm depth may be related the South Ray crater impact. Regolith maturity generally decreases with depth, as in several previously studied cores. We recognize five compositionally distinct units in the core, which we designate A through E, although all are similar in composition to each other and to other soils from the Cayley plains at the Apollo 16 site. Unit A (0-33 cm) is mature to submature throughout (I(sub s)/FeO: 89-34 units) and is indistinguishable in composition from surface soils collected at station 8. Unit B (33-37 cm) is enriched slightly in a component of anorthositic norite composition. Unit D (42-53 cm) is compositionally equivalent to 80 wt% Unit-A soil plus 20 wt% Apollo-16-type dimict breccia consisting of subequal parts anorthosite and impact-melt breccia. Compared to Unit A, Unit E (53-61 cm) contains a small proportion (up to 4%) of some component compositionally similar to Apollo 14 sample 14321. Unit C (37-42 cm) is unusual. For lithophile and siderophile elements, it is similar to Units A and D. However, I(sub s)/FeO is low throughout the unit (less than 30 units) and in a bluish-gray zone at 41 cm depth I(sub s)/FeO drops to 1.6 units, the lowest value that we have observed in several hundred Apollo 16 soil samples. Samples from the bluish-gray zone also have low Zn concentrations, less than 10 micro g/g, compared to 20-30 micro g/g for the rest of the core. Although both values are consistent with fragmented rock material that has received virtually no surface exposure, the abundance of agglutinates in the bluish-gray soil of Unit C is moderately high, typical of a submature soil that would ordinarily have I(sub s)/FeO - 30. We believe that the anomalously low values of I(sub s)/FeO and Zn concentration result because the soil was heated to -800-1000 'C, probably during an impact. This temperature range is sufficient to volatize the surface-correlated Zn and agglomerate the nanophase metal giving rise to the FMR signal but is not great enough to sinter the soil. Alternatively, the unusual soil interval may represent a disaggregated or incipient regolith breccia, although there is no significant difference in the texture or clast-matrix relationships between Unit C and adjacent units.
42 CFR 485.647 - Condition of participation: psychiatric and rehabilitation distinct part units.
Code of Federal Regulations, 2010 CFR
2010-10-01
... 42 Public Health 5 2010-10-01 2010-10-01 false Condition of participation: psychiatric and... Condition of participation: psychiatric and rehabilitation distinct part units. (a) Conditions. (1) If a CAH provides inpatient psychiatric services in a distinct part unit, the services furnished by the distinct...
Origin of Dark Material on VESTA from DAWN FC Data: Remnant Carbonaceous Chondrite Impators
NASA Technical Reports Server (NTRS)
Reddy, V.; LeCorre, L.; Nathues, A.; Mittlefehldt, David W.; Cloutis, E. A.; OBrien, D. P.; Durda, D. D.; Bottke, W. F.; Buczkowski, D.; Scully, J. E. C.;
2012-01-01
NASA's Dawn spacecraft entered orbit around asteroid (4) Vesta in July 2011 for a yearlong mapping orbit. The surface of Vesta as imaged by the Dawn Framing Camera (FC) revealed a surface that is unlike any asteroid we have visited so far with a spacecraft. Albedo and color variations on Vesta are the most diverse in the asteroid belt with a majority of these linked to distinct compositional units on the asteroid s surface. FC discovered dark material on Vesta. These low albedo surface features were first observed during Rotational Characterization 3 phase at a resolution of approx. 487 m/pixel. Here we explore the composition and possible meteoritical analogs for the dark material on Vesta.
Magma volumes and storage in the middle crust
NASA Astrophysics Data System (ADS)
Memeti, V.; Barnes, C. G.; Paterson, S. R.
2015-12-01
Quantifying magma volumes in magma plumbing systems is mostly done through geophysical means or based on volcanic eruptions. Detailed studies of plutons, however, are useful in revealing depths and evolving volumes of stored magmas over variable lifetimes of magma systems. Knowledge of the location, volume, and longevity of stored magma is critical for understanding where in the crust magmas attain their chemical signature, how these systems physically behave and how source, storage levels, and volcanoes are connected. Detailed field mapping, combined with single mineral geochemistry and geochronology of plutons, allow estimates of size and longevity of melt-interconnected magma batches that existed during the construction of magma storage sites. The Tuolumne intrusive complex (TIC) recorded a 10 myr magmatic history. Detailed maps of the major units in different parts of the TIC indicate overall smaller scale (cm- to <1 km) compositional variation in the oldest, outer Kuna Crest unit and mainly larger scale (>10 km) changes in the younger Half Dome and Cathedral Peak units. Mineral-scale trace element data from hornblende of granodiorites to gabbros from the Kuna Crest lobe show distinct hornblende compositions and zoning patterns. Mixed hornblende populations occur only at the transition to the main TIC. This compositional heterogeneity in the first 1-2 myr points to low volume magmatism resulting in smaller, discrete and not chemically interacting magma bodies. Trace element and Sr- and Pb-isotope data from growth zones of K-feldspar phenocrysts from the two younger granodiorites indicate complex mineral zoning, but general isotopic overlap, suggesting in-situ, inter-unit mixing and fractionation. This is supported by hybrid zones between units, mixing of zircon, hornblende, and K-feldspar populations and late leucogranites. Thus, magma body sizes increased later resulting in overall more homogeneous, but complexly mixing magma mushes that fractionated locally.
NASA Technical Reports Server (NTRS)
Tompkins, Stefanie; Pieters, Carle M.; Mustard, John F.; Pinet, Patrick; Chevrel, Serge D.
1994-01-01
Previous spectroscopic studies of the lunar crater Bullialdus, located in the Nubium Basin, indicated an unusual stratigraphy of two gabbroic layers overlying a noritic unit. The possible existence of a layered mafic pluton at Bullialdus was suggested. To investigate the geologic context with more detailed spatial information, charge-coupled device (CCD) images of Bullialdus were obtained using eight filters. A linear mixing model was used to investigate the fractional abundances of spectral end-members chosen from within the multispectral image. Since the reflectance properties of lunar materials over this wavelength range are sensitive to variations in composition and soil maturity, fractional abundance images were used to create a new geologic map of the crater. The spatial relationships of the surface materials confirm the previously inferred stratigraphy, and further reveal the central peaks to exhibit two distinct compositional units: noritic anorthosite and anorthositic norite. Three models for the origin of the observed stratigraphy are considered: Bullialdus has excavated stratigraphic units containing (1) early mare basalt overlying anorthositic-noritic crustal material, (2) part of a layered mafic pluton, and/or (3) part of an impact melt sheet formed by the Nubium Basin impact event.
NASA Astrophysics Data System (ADS)
Cawood, Adam J.; Bond, Clare E.
2018-01-01
Stratigraphic influence on structural style and strain distribution in deformed sedimentary sequences is well established, in models of 2D mechanical stratigraphy. In this study we attempt to refine existing models of stratigraphic-structure interaction by examining outcrop scale 3D variations in sedimentary architecture and the effects on subsequent deformation. At Monkstone Point, Pembrokeshire, SW Wales, digital mapping and virtual scanline data from a high resolution virtual outcrop have been combined with field observations, sedimentary logs and thin section analysis. Results show that significant variation in strain partitioning is controlled by changes, at a scale of tens of metres, in sedimentary architecture within Upper Carboniferous fluvio-deltaic deposits. Coupled vs uncoupled deformation of the sequence is defined by the composition and lateral continuity of mechanical units and unit interfaces. Where the sedimentary sequence is characterized by gradational changes in composition and grain size, we find that deformation structures are best characterized by patterns of distributed strain. In contrast, distinct compositional changes vertically and in laterally equivalent deposits results in highly partitioned deformation and strain. The mechanical stratigraphy of the study area is inherently 3D in nature, due to lateral and vertical compositional variability. Consideration should be given to 3D variations in mechanical stratigraphy, such as those outlined here, when predicting subsurface deformation in multi-layers.
Unifying concepts linking dissolved organic matter composition to persistence in aquatic ecosystems
Kellerman, Anne M.; Guillemette, François; Podgorski, David C.; Aiken, George R.; Butler, Kenna D.; Spencer, Robert G. M.
2018-01-01
The link between composition and reactivity of dissolved organic matter (DOM) is central to understanding the role aquatic systems play in the global carbon cycle; yet, unifying concepts driving molecular composition have yet to be established. We characterized 37 DOM isolates from diverse aquatic ecosystems, including their stable and radiocarbon isotopes (δ13C-dissolved organic carbon (DOC) and Δ14C-DOC), optical properties (absorbance and fluorescence), and molecular composition (ultrahigh resolution mass spectrometry). Isolates encompassed end-members of allochthonous and autochthonous DOM from sites across the United States, the Pacific Ocean, and Antarctic lakes. Modern Δ14C-DOC and optical properties reflecting increased aromaticity, such as carbon specific UV absorbance at 254 nm (SUVA254), were directly related to polyphenolic and polycyclic aromatic compounds, whereas enriched δ13C-DOC and optical properties reflecting autochthonous end-members were positively correlated to more aliphatic compounds. Furthermore, the two sets of autochthonous end-members (Pacific Ocean and Antarctic lakes) exhibited distinct molecular composition due to differences in extent of degradation. Across all sites and end-members studied, we find a consistent shift in composition with aging, highlighting the persistence of certain biomolecules concurrent with degradation time.
Jones, Aaron A.; Bennett, Philip C.
2017-01-01
This study tests the hypothesis that surface composition influences microbial community structure and growth of biofilms. We used laboratory biofilm reactors (inoculated with a diverse subsurface community) to explore the phylogenetic and taxonomic variability in microbial communities as a function of surface type (carbonate, silicate, aluminosilicate), media pH, and carbon and phosphate availability. Using high-throughput pyrosequencing, we found that surface type significantly controlled ~70–90% of the variance in phylogenetic diversity regardless of environmental pressures. Consistent patterns also emerged in the taxonomy of specific guilds (sulfur-oxidizers/reducers, Gram-positives, acidophiles) due to variations in media chemistry. Media phosphate availability was a key property associated with variation in phylogeny and taxonomy of whole reactors and was negatively correlated with biofilm accumulation and α-diversity (species richness and evenness). However, mineral-bound phosphate limitations were correlated with less biofilm. Carbon added to the media was correlated with a significant increase in biofilm accumulation and overall α-diversity. Additionally, planktonic communities were phylogenetically distant from those in biofilms. All treatments harbored structurally (taxonomically and phylogenetically) distinct microbial communities. Selective advantages within each treatment encouraged growth and revealed the presence of hundreds of additional operational taxonomix units (OTU), representing distinct consortiums of microorganisms. Ultimately, these results provide evidence that mineral/rock composition significantly influences microbial community structure, diversity, membership, phylogenetic variability, and biofilm growth in subsurface communities. PMID:28400754
Hafnium Isotopic Variations in Central Atlantic Intraplate Volcanism
NASA Astrophysics Data System (ADS)
Geldmacher, J.; Hanan, B. B.; Hoernle, K.; Blichert-Toft, J.
2008-12-01
Although one of the geochemically best investigated volcanic regions on Earth, almost no Hf isotopic data have been published from the broad belt of intraplate seamounts and islands in the East Atlantic between 25° and 36° N. This study presents 176Hf/177Hf ratios from 61 representative samples from the Canary, Selvagen and Madeira Islands and nearby large seamounts, encompassing the full range of different evolutionary stages and geochemical endmembers. The majority of samples have mafic, mainly basaltic compositions with Mg-numbers within or near the range of magmas in equilibrium with mantle olivine (68-75). No correlation was found between Mg-number and 176Hf/177Hf ratios in the data set. In comparison to observed Nd isotope variations published for this volcanic province (6 ɛNd units), 176Hf/177Hf ratios span a larger range (14 ɛHf units). Samples from the Madeira archipelago have the most radiogenic compositions (176Hf/177Hfm= 0.283132-0.283335), widely overlapping the field for central Atlantic N-MORB. They form a relatively narrow, elongated trend (stretching over >6 ɛHf units) between a radiogenic MORB-like endmember and a composition located on the Nd-Hf mantle array. In contrast, all Canary Islands samples plot below the mantle array (176Hf/177Hfm = 0.282943-0.283067) and, despite being from an archipelago that stretches over a much larger geographic area, form a much denser cluster with less compositional variation (~4 ɛHf units). All samples from the seamounts NE of the Canaries, proposed to belong to the same Canary hotspot track (e.g. Geldmacher et al., 2001, JVGR 111; Geldmacher et al., 2005, EPSL 237), fall within the Hf isotopic range of this cluster. The cluster largely overlaps the composition of the proposed common mantle endmember 'C' (Hanan and Graham, 1996, Science 272) but spans a space between a more radiogenic (depleted) composition and a HIMU-type endmember. Although samples of Seine and Unicorn seamounts, attributed to the Madeira hotspot track, show less radiogenic Hf and Nd isotope ratios than Madeira, their isotopic compositions lie along an extension of the Madeira trend in plots of Hf versus Sr, Nd, Pb isotopes. The new Hf isotope ratios confirm the existence of at least two geochemically distinct volcanic provinces (Canary and Madeira) in the East Atlantic as previously proposed.
Diesner, Susanne C; Bergmayr, Cornelia; Pfitzner, Barbara; Assmann, Vera; Krishnamurthy, Durga; Starkl, Philipp; Endesfelder, David; Rothballer, Michael; Welzl, Gerhard; Rattei, Thomas; Eiwegger, Thomas; Szépfalusi, Zsolt; Fehrenbach, Heinz; Jensen-Jarolim, Erika; Hartmann, Anton; Pali-Schöll, Isabella; Untersmayr, Eva
2016-12-01
In our mouse model, gastric acid-suppression is associated with antigen-specific IgE and anaphylaxis development. We repeatedly observed non-responder animals protected from food allergy. Here, we aimed to analyse reasons for this protection. Ten out of 64 mice, subjected to oral ovalbumin (OVA) immunizations under gastric acid-suppression, were non-responders without OVA-specific IgE or IgG1 elevation, indicating protection from allergy. In these non-responders, allergen challenges confirmed reduced antigen uptake and lack of anaphylactic symptoms, while in allergic mice high levels of mouse mast-cell protease-1 and a body temperature reduction, indicative for anaphylaxis, were determined. Upon OVA stimulation, significantly lower IL-4, IL-5, IL-10 and IL-13 levels were detected in non-responders, while IL-22 was significantly higher. Comparison of fecal microbiota revealed differences of bacterial communities on single bacterial Operational-Taxonomic-Unit level between the groups, indicating protection from food allergy being associated with a distinct microbiota composition in a non-responding phenotype in this mouse model. Copyright © 2016 The Authors. Published by Elsevier Inc. All rights reserved.
Phase diagram and electrical behavior of silicon-rich iridium silicide compounds
NASA Technical Reports Server (NTRS)
Allevato, C. E.; Vining, Cronin B.
1992-01-01
The iridium-silicon phase diagram on the silicon-rich side was investigated by means of X-ray powder diffraction, density, differential thermal analysis, metalography, microprobe analysis, and electrical resistivity. Attempts were made to prepare eight previously reported silicon-rich iridium silicide compounds by arc melting and Bridgman-like growth. However, microprobe analysis identified only four distinct compositions: IrSi, Ir3Si4, Ir3Si5 and IrSi sub about 3. The existence of Ir4Si5 could not be confirmed in this study, even though the crystal structure has been previously reported. Differential thermal analysis (DTA) in conjunction with X-ray powder diffraction confirm polymorphism in IrSi sub about 3, determined to have orthorhombic and monoclinic unit cells in the high and low temperature forms. A eutectic composition alloy of 83 +/- 1 atomic percent silicon was observed between IrSi sub about 3 and silicon. Ir3Si4 exhibits distinct metallic behavior while Ir3Si5 is semiconducting. Both and IrSi and IrSi sub about 3 exhibit nearly temperature independent electrical resistivities on the order of 5-10 x 10 exp -6 ohms-m.
Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C
2014-01-01
We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. “pre-event” water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as “isostats,” not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Key Points Hillslope connectivity is controlled by small storage changes in soil units Different catchment source waters mix in large riparian wetland storage Isotopes show riparian wetlands set the catchment transit time distribution PMID:25506098
Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C
2014-02-01
We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. "pre-event" water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as "isostats," not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Hillslope connectivity is controlled by small storage changes in soil unitsDifferent catchment source waters mix in large riparian wetland storageIsotopes show riparian wetlands set the catchment transit time distribution.
Maizel, Andrew C; Remucal, Christina K
2017-10-01
There is a growing interest in water reuse and in recovery of nutrients from wastewater. Because many advanced treatment processes are designed to remove organic matter, a better understanding of the composition of dissolved organic matter (DOM) in wastewater is needed. To that end, we assessed DOM in the Nine Springs Wastewater Treatment Plant in Madison, Wisconsin by UV-visible spectroscopy and Fourier transform-ion cyclotron resonance mass spectrometry. Samples were collected from the influent and effluent of two different secondary treatment processes and their respective secondary clarifiers, the UV disinfection unit, and an Ostara treatment system, which produces struvite via chemical precipitation. The optical properties reveal that DOM throughout the plant is relatively aliphatic and is low in molecular weight compared to DOM in freshwater systems. Furthermore, the DOM is rich in heteroatoms (e.g., N, S, P, and Cl) and its molecular formulas are present in the lipid-, protein-, carbohydrate-, and lignin-like regions of van Krevelen diagrams. Secondary treatment produces DOM that is more aromatic and more complex, as shown by the loss of highly saturated formulas and the increase in the number of CHO, CHON, and CHOP formulas. The two secondary treatment processes produce DOM with distinct molecular compositions, while the secondary clarifiers and UV disinfection unit result in minimal changes in DOM composition. The Ostara process decreases the molecular weight of DOM, but does not otherwise alter its composition. The optical properties agree with trends in the molecular composition of DOM within the main treatment train of the Nine Springs plant. Copyright © 2017 Elsevier Ltd. All rights reserved.
Triton - False Color of Cantaloupe Terrain
1996-09-26
Voyager violet, green, and ultraviolet images of Triton were map projected into cylindrical coordinates and combined to produce this false color terrain map. Several compositionally distinct terrain and geologic features are portrayed. At center is a gray blue unit referred to as 'cantaloupe' terrain because of its unusual topographic texture. The unit appears to predate other units to the left. Immediately adjacent to the cantaloupe terrain, is a smoother unit, represented by a reddish color, that has been dissected by a prominent fault system. This unit apparently overlies a much higher albedo material, seen farther left. A prominent angular albedo boundary separates relatively undisturbed smooth terrain from irregular patches which have been derived from breakup of the same material. Also visible at the far left are diffuse, elongated streaks, which seem to emanate from circular, often bright centered features. The parallel streaks may represent vented particulate materials blown in the same direction by winds in Triton's thin atmosphere. The Voyager Mission was conducted by JPL for NASA's Office of Space Science and Applications. http://photojournal.jpl.nasa.gov/catalog/PIA00060
Jain, Bhawna; Singh, Bhupinder; Katare, Om Prakash; Vyas, Suresh Prashad
2010-06-01
The current study aimed to deliver minoxidil (2,4-diamino-6-piperidinopyrimidine 3-oxide; MXD), a potent hypertrichotic agent, into the pilosebaceous units, exploring the potential of the liposomal system. MXD-loaded liposomes of different compositions were prepared by a thin-film hydration technique and subsequently characterized for various vesicle-specific attributes (i.e., size, shape, lamellarity, and entrapment efficiency). Comparative analysis among these compositions was conducted with reference to their vesicle-specific parameters, drug deposition, and drug-delivery mechanism toward pilosebaceous units. The latter may bring about a distinct change in MXD therapy for various ailments related to pilosebaceous units, such as alopecia. The in vitro drug release, ex vivo skin permeation, and drug-retention behavior of the prepared formulation were evaluated by employing rat skin (normal as well as pilosebaceous free) and semipermeable membrane. The results revealed that the neutral liposomes (mean vesicle size, 3.83 +/- 0.18 microm) showed maximum drug deposition in the pilosebaceous units among all the other tested formulations. A quantitative estimation of pilosebaceous delivery revealed that the concentration of MXD in each pilosebaceous unit decreased in the following order: neutral liposomal formulation (5.8 x 10(3) to 7.25 x 10(3) microg) > positively charged liposomal formulation (4.7 x 10(3) to 5.87 x 10(3) microg) > negatively charged liposomal formulation (4.2 x 10(3) to 5.25 x 10(3) microg) > nonliposomal formulation (1.6 x 10(3) to 2.0 x 10(3) microg). Stability studies construed the need to store the liposomal formulation at lower temperatures. The results of the current work indicate that the neutral liposomes can deliver the drug molecules into pilosebaceous units more effectively than the other studied formulations.
Surface-compositional Properties of Lava Plains in Syria-Thaumasia Block, Mars
NASA Astrophysics Data System (ADS)
Huang, J.; Xiao, L.; Kraft, M. D.; Christensen, P. R.; Edwards, C. S.; Ruff, S. W.; Dohm, J.
2012-12-01
Mars has a long and complex volcanic history (Greeley and Spudis, 1981; Carr, 2006). Among abundant plain-style volcanism and various edifices, Tharsis bulge is a prominent and long-lasting (Werner, 2009) volcanic province. However, there is little report about compositional variations before and after Tharsis uplift. The Syria- Thaumasia block (STB) is a complex tectono-volcanic province related to the Tharsis bulge. Understanding its formation is critical to characterizing the early history and planetary evolution of Mars. The STB lies at the southern edge of Tharsis bulge. It consists of lava plains (Syria, Solis, Sinai and Thaumasia Plana) bounded by an arcuate region of higher topography (Thaumasia Highlands, Melas Dorsa and Coprates Rise) and Valles Marineris to the north. Previous work on surface thermophysical properties (Christensen, 1988; Jakosky et al., 2000; Putzig and Mellon, 2007) and visible/near infrared and thermal infrared remote sensing spectroscopic compositional analysis (Bandfield, 2000; Bibring et al., 2006; Rogers and Christensen, 2007) had been done only in a global scale, but regional study of both surface thermophysical properties and compositions for each of the distinct lava plains in STB is lacking. In this study, we characterize a variety of volcanic features, including lava tubes, channels and their relationships with wrinkle ridges within lava plains using THEMIS infrared data (100 m/pixel: Christensen et al., 2004), CTX data (6 m/pixel: Malin et al., 2007) and HiRISE data (25 cm/pixel: McEwen et al., 2007). We assessed the surface thermophysical properties and compositions of lava plains using TES data (Christensen et al., 2001). The geomorphic features imply the lava emplacement mechanisms, while their relationships indicate the chronologic relationships between Tharsis uplift and lava emplacement. The compositional results show variations within the lava plains (Table 1), while the thermophysical results show the compositional variations are due to different compositions of in place materials. The modeled high-calcium pyroxene and high-silica phases within Hsl unit are different from those of other units. The compositional variations may imply changes in magmatism (source and/or mechanism) before and after the uplift of Tharsis.Table 1. TES Derived modal mineralogy; a. Values are percent. b. Results of Hsl unit from Rogers and Christensen (2007)
NASA Technical Reports Server (NTRS)
Taranik, James V.; Noble, Donald C.; Hsu, Liang C.; Spatz, David M.
1987-01-01
LANDSAT Thematic Mapper imagery was evaluated over 3 Tertiary calderas in southern Nevada. Each volcanic center derived from a highly evolved silici magmatic system represented today by well exposed diverse lithologies. Distinctive imagery contrast between some of the late ash flows and earlier units follows from the high relative reflectance in longer wavelength bands (bands 5 and 7) of the former. Enhancement techniques provide color composite images which highlight some of the units in remarkable color contrast. Inasmuch as coatings on the tuffs are incompletely developed and apparently largely dependent spectrally on rock properties independent of petrochemistry, it is felt that the distinctive imagery characteristics are more a function of primary lithologic or petrochemical properties. Any given outcrop is backdrop for a variety of cover types, of which coatings, at various stages of maturity, are one. Petrographic and X-ray diffraction analysis of the outer air-interface zone of coatings reveal they are composed chiefly of amorphous compounds, probably with varying proportions of iron and manganese. Observations support an origin for some outer (air-interface) coating constituents exogenous to the underlying host.
Mapping of the Culann-Tohil region of Io from Galileo imaging data
Williams, D.A.; Schenk, P.M.; Moore, Johnnie N.; Keszthelyi, L.P.; Turtle, E.P.; Jaeger, W.L.; Radebaugh, J.; Milazzo, M.P.; Lopes, R.M.C.; Greeley, R.
2004-01-01
We have used Galileo spacecraft data to produce a geomorphologic map of the Culann-Tohil region of Io's antijovian hemisphere. This region includes a newly discovered shield volcano, Tsu??i Goab Tholus and a neighboring bright flow field, Tsu??i Goab Fluctus, the active Culann Patera and the enigmatic Tohil Mons-Radegast Patera-Tohil Patera complex. Analysis of Voyager global color and Galileo Solid-State Imaging (SSI) high-resolution, regional (50-330 m/pixel), and global color (1.4 km/pixel) images, along with available Galileo Near-Infrared Mapping Spectrometer (NIMS) data, suggests that 16 distinct geologic units can be defined and characterized in this region, including 5 types of diffuse deposits. Tsu??i Goab Fluctus is the center of a low-temperature hotspot detected by NIMS late during the Galileo mission, and could represent the best case for active effusive sulfur volcanism detected by Galileo. The Culann volcanic center has produced a range of explosive and effusive deposits, including an outer yellowish ring of enhanced sulfur dioxide (SO2), an inner red ring of SO2 with short-chain sulfur (S3-S4) contaminants, and two irregular green diffuse deposits (one in Tohil Patera) apparently produced by the interaction of dark, silicate lava flows with sulfurous contaminants ballistically-emplaced from Culann's eruption plume(s). Fresh and red-mantled dark lava flows west of the Culann vent can be contrasted with unusual red-brown flows east of the vent. These red-brown flows have a distinct color that is suggestive of a compositional difference, although whether this is due to surface alteration or distinct lava compositions cannot be determined. The main massif of Tohil Mons is covered with ridges and grooves, defining a unit of tectonically disrupted crustal materials. Tohil Mons also contains a younger unit of mottled crustal materials that were displaced by mass wasting processes. Neighboring Radegast Patera contains a NIMS hotspot and a young lava lake of dark silicate flows, whereas the southwest portion of Tohil Patera contains white flow-like units, perhaps consisting of 'ponds' of effusively emplaced SO2. From 0?? -15?? S the hummocky bright plains unit away from volcanic centers contains scarps, grooves, pits, graben, and channel-like features, some of which have been modified by erosion. Although the most active volcanic centers appear to be found in structural lows (as indicated by mapping of scarps), DEMs derived from stereo images show that, with the exception of Tohil Mons, there is less than 1 km of relief in the Culann-Tohil region. There is no discernable correlation between centers of active volcanism and topography. ?? 2003 Elsevier Inc. All rights reserved.
Origin of olivine at Copernicus
NASA Technical Reports Server (NTRS)
Pieters, C. M.; Wilhelms, D. E.
1985-01-01
The central peaks of Copernicus are among the few lunar areas where near-infrared telescopic reflectance spectra indicate extensive exposures of olivine. Other parts of Copernicus crater and ejecta, which were derived from highland units in the upper parts of the target site, contain only low-Ca pyroxene as a mafic mineral. The exposure of compositionally distinct layers including the presence of extensive olivine may result from penetration to an anomalously deep layer of the crust or to the lunar mantle. It is suggested that the Procellarum basin and the younger, superposed Insularum basin have provided access to these normally deep-seated crustal or mantle materials by thinning the upper crustal material early in lunar history. The occurrences of olivine in portions of the compositionally heterogeneous Aristarchus Region, in a related geologic setting, may be due to the same sequence of early events.
40Ar/39Ar geochronology and petrogenesis of the Table Mountain Shoshonite, Golden, Colorado, U.S.A.
Millikin, Alexie E. G.; Morgan, Leah; Noblett, Jeffery
2018-01-01
The Upper Cretaceous and Lower Paleogene Table Mountain Shoshonite lava flows and their proposed source, the Ralston Buttes intrusions, provide insight into the volcanic history of the Colorado Front Range. This study affirms the long-held hypothesis linking the extrusive Table Mountain lava flows and their intrusive equivalents at Ralston Buttes through major- and trace- element geochemistry. Systematic 40Ar/39Ar geochronology from all flows and intrusive units refines the eruptive history, improves precision on previously reported ages, and provides tighter constraints on the position of the K-Pg boundary in this location. Four flows are recognized on North and South Table mountains outside of Golden, Colorado. Flow 1 (66.5 ± 0.3 Ma, all ages reported with 2σ uncertainty) is the oldest, most compositionally distinct flow and is separated from younger flows by approximately 35 m of sedimentary deposits of the Denver Formation. Stratigraphically adjacent flows 2 (65.8 ± 0.2 Ma), 3 (65.5 ± 0.3 Ma), and 4 (65.9 ± 0.3 Ma) are compositionally indistinguishable. Lavas (referred to here as unit 5) that form three cone-shaped structures (shown by this study to be volcanic vents of a new unit 5) on top of North Table Mountain are compositionally similar to other units, but yield an age almost 20 m.y. younger (46.94 ± 0.15 Ma). Geochemistry and geochronology suggest that the rim phase of the Ralston plug (65.4 ± 0.2 Ma) is a reasonable source for flows 2, 3, and 4. All units are shoshonites—potassic basalts containing plagioclase, augite, olivine, and magnetite phenocrysts—and plot in the continental-arc field in tectonic discrimination diagrams. A continental-arc setting coupled with Late Cretaceous to early Paleogene ages suggest the high-K magmatism is associated with Laramide tectonism.
NASA Astrophysics Data System (ADS)
Hatfield, M.; Low, P. C.; Devlin, S.
2011-12-01
Thomas Jefferson's Poplar Forest estate near Lynchburg, VA is currently attempting to restore the property to its Jeffersonian condition. Subsequent modifications to the property following its sale by Jefferson's heirs included the removal of the original trees in order to facilitate agricultural activity. One key facet of the restoration involves determining the precise location of the sixty-four paper mulberry trees that Jefferson reportedly had transplanted in 1815 from his on-site nursery to near the main house. At Monticello, it is well-documented that Jefferson used contextually innovative fertilizing techniques, including the addition of gypsum and lime "to restore the exhaustion of a single crop from the soil." Whether he used these methods in the nursery at Poplar Forest to the degree that decades of subsequent leaching, weathering, and other disturbances would not erase remains historically and analytically unclear. Since the transplantation process requires that large amounts of soil be moved with the trees, small areas of compositionally distinct soils in the suspected planting area could be used to establish the exact location of each tree through differentiating between nursery and in situ soils. Through X-ray fluorescence spectroscopy (XRF) and intercoupled plasma optical emission spectroscopy (ICP-OES) geochemical analysis, the specific composition of soil can be determined. Preliminary analysis shows slight differences in phosphorus and sulfur between the nursery and in situ soil; however, the property lies on three different distinct geological units: actinolite schist and feldspathic metagreywacke units of the Alligator Back formation, and biotite gneiss of the Ashe Formation (biotite gneiss). The location of the nursery where the sixty-four paper mulberry trees were originally grown lies on the feldspathic metagreywacke unit; whereas the relocation site where Jefferson had them planted rests on the actinolite schist unit. Percursory study identifies significant differences in major elements such as silicon, aluminum, calcium, and manganese. Locating the presence of the nursery soil within the relocation site soil will allow staff archaeologists to replant the paper mulberry trees in order to reconstruct Jefferson's plantation.
Woodhouse, Jason Nicholas; Kinsela, Andrew Stephen; Collins, Richard Nicholas; Bowling, Lee Chester; Honeyman, Gordon L; Holliday, Jon K; Neilan, Brett Anthony
2016-01-01
The frequency of freshwater cyanobacterial blooms is at risk of increasing as a consequence of climate change and eutrophication of waterways. It is increasingly apparent that abiotic data are insufficient to explain variability within the cyanobacterial community, with biotic factors such as heterotrophic bacterioplankton, viruses and protists emerging as critical drivers. During the Australian summer of 2012–2013, a bloom that occurred in a shallow ephemeral lake over a 6-month period was comprised of 22 distinct cyanobacteria, including Microcystis, Dolichospermum, Oscillatoria and Sphaerospermopsis. Cyanobacterial cell densities, bacterial community composition and abiotic parameters were assessed over this period. Alpha-diversity indices and multivariate analysis were successful at differentiating three distinct bloom phases and the contribution of abiotic parameters to each. Network analysis, assessing correlations between biotic and abiotic variables, reproduced these phases and assessed the relative importance of both abiotic and biotic factors. Variables possessing elevated betweeness centrality included temperature, sodium and operational taxonomic units belonging to the phyla Verrucomicrobia, Planctomyces, Bacteroidetes and Actinobacteria. Species-specific associations between cyanobacteria and bacterioplankton, including the free-living Actinobacteria acI, Bacteroidetes, Betaproteobacteria and Verrucomicrobia, were also identified. We concluded that changes in the abundance and nature of freshwater cyanobacteria are associated with changes in the diversity and composition of lake bacterioplankton. Given this, an increase in the frequency of cyanobacteria blooms has the potential to alter nutrient cycling and contribute to long-term functional perturbation of freshwater systems. PMID:26636552
Xiong, Weili; Olm, Matthew R.; Thomas, Brian C.; Baker, Robyn; Firek, Brian; Morowitz, Michael J.; Hettich, Robert L.
2018-01-01
ABSTRACT During the first weeks of life, microbial colonization of the gut impacts human immune system maturation and other developmental processes. In premature infants, aberrant colonization has been implicated in the onset of necrotizing enterocolitis (NEC), a life-threatening intestinal disease. To study the premature infant gut colonization process, genome-resolved metagenomics was conducted on 343 fecal samples collected during the first 3 months of life from 35 premature infants housed in a neonatal intensive care unit, 14 of whom developed NEC, and metaproteomic measurements were made on 87 samples. Microbial community composition and proteomic profiles remained relatively stable on the time scale of a week, but the proteome was more variable. Although genetically similar organisms colonized many infants, most infants were colonized by distinct strains with metabolic profiles that could be distinguished using metaproteomics. Microbiome composition correlated with infant, antibiotics administration, and NEC diagnosis. Communities were found to cluster into seven primary types, and community type switched within infants, sometimes multiple times. Interestingly, some communities sampled from the same infant at subsequent time points clustered with those of other infants. In some cases, switches preceded onset of NEC; however, no species or community type could account for NEC across the majority of infants. In addition to a correlation of protein abundances with organism replication rates, we found that organism proteomes correlated with overall community composition. Thus, this genome-resolved proteomics study demonstrated that the contributions of individual organisms to microbiome development depend on microbial community context. PMID:29636439
Maintaining protein composition in cilia.
Stephen, Louise A; Elmaghloob, Yasmin; Ismail, Shehab
2017-12-20
The primary cilium is a sensory organelle that is vital in regulating several signalling pathways. Unlike most organelles cilia are open to the rest of the cell, not enclosed by membranes. The distinct protein composition is crucial to the function of cilia and many signalling proteins and receptors are specifically concentrated within distinct compartments. To maintain this composition, a mechanism is required to deliver proteins to the cilium whilst another must counter the entropic tendency of proteins to distribute throughout the cell. The combination of the two mechanisms should result in the concentration of ciliary proteins to the cilium. In this review we will look at different cellular mechanisms that play a role in maintaining the distinct composition of cilia, including regulation of ciliary access and trafficking of ciliary proteins to, from and within the cilium.
Volcano-ice interactions on Mars
NASA Technical Reports Server (NTRS)
Allen, C. C.
1979-01-01
Central volcanic eruptions beneath terrestrial glaciers have built steep-sided, flat-topped mountains composed of pillow lava, glassy tuff, capping flows, and cones of basalt. Subglacial fissure eruptions produced ridges of similar composition. In some places the products from a number of subglacial vents have combined to form widespread deposits. The morphologies of these subglacial volcanoes are distinctive enough to allow their recognition at the resolutions characteristic of Viking orbiter imagery. Analogs to terrestrial subglacial volcanoes have been identified on the northern plains and near the south polar cap of Mars. The polar feature provides probable evidence of volcanic eruptions beneath polar ice. A mixed unit of rock and ice is postulated to have overlain portions of the northern plains, with eruptions into this ground ice having produced mountains and ridges analogous to those in Iceland. Subsequent breakdown of this unit due to ice melting revealed the volcanic features. Estimated heights of these landforms indicate that the ice-rich unit once ranged from approximately 100 to 1200 m thick.
Budding, Karin E.
1982-01-01
The Joe Lott Tuff Member of the Mount Belknap Volcanics is the largest rhyolitic ash-flow tuff sheet in the Marysvale volcanic field. It was erupted 19 m.y. ago, shortly after the changeover from intermediate-composition calc-alkalic volcanism to bimodal basalt-rhyolite volcanism. Eruption of the tuff resulted in the formation of the Mount Belknap Caldera whose pyroclastic intracaldera stratigraphy parallels that in the outflow facies. The Joe Loft Tuff Member is a composite ash-flow sheet that changes laterally from a simple cooling unit near the source to four distinct cooling units toward the distal end. The lowest of these units is the largest and most widespread; it is 64 m thick and contains a basal vitrophyre. Eruption of the lower unit led to the initial collapse of the caldera. The lower unit is followed upward by a 43 m middle unit, a 26 m pink-colored unit which is separated by a prominent air- fall layer, and a 31 m upper unit. The Joe Loft Tuff Member is an alkali rhyolite with 75.85-77.31 wt. % silica and 8.06-9.32 wt. % K2O+Na2O; the agpaitic index (Na2O+ K2O/Al2O3) is .77-.98. The tuff contains about I% phenocrysts of quartz, sanidine, oligoclase, augite, apatite, zircon, sphene, biotite, and oxidized Fe-Ti oxides. The basal vitrophyre contains accessory allanite, chevkinite, and magnesiohastingsite. The main cooling units are chemically and mineralogically zoned indicating that the magma chamber restratified prior to each major eruption. Within each of the two thickest cooling units, the mineralogy changes systematically upwards; the Or content and relative volume of sanidine decreases and An content of plagioclase increases. The basal vitrophyre of the lower unit has a bulk composition that lies in the thermal trough near the minima of Or-Ab-Q at 1 kb PH2O. Microprobe analyses of feldspar and chemical modeling on experimental systems indicate that pre-eruption temperatures were near 750?C and that the temperature increased during the eruption of the cooling units. The chemical gradients in the apatite and whole-rock data in the Joe Loft Tuff Member and the consistent mineral assemblages throughout the ash-flow cannot be explained by crystal settling. The fractionation of the Joe Lott Tuff Member appears to closer fit the model of convection-driven thermogravitational diffusion.
NASA Astrophysics Data System (ADS)
Bergmanis, E. C.; Sinton, J. M.; Rubin, K. H.; Mahoney, J. J.; Bowles, J.; Gee, J. S.; Smith, M. C.
2004-12-01
Geologic observations, isotopic, major and trace element and U-series disequilibria data indicate that seven compositionally distinct lava types are present within 2 km of the fast-spreading ( ˜145 mm/yr) southern EPR between 17° 22'S and 17° 35'S. Geologic contacts observed during submersible dives indicate that these lava types are the products of at least four eruptions. These observations require a complex history of mantle melting, recharge, cooling, and eruption that varies considerably over along-axis distances of 24 kilometers and a timescale of several hundred years. The boundary of a young, ˜18km-long lava flow (Aldo-Kihi) is well constrained by submersible observations, three other geologic units are less well-defined. (210Pb)/(226Ra) deficits of ˜5 % and magnetic paleointensity measurements indistinguishable from present-day values suggest the Aldo-Kihi lava and two other compositionally distinct units are <100 yrs old. Major-element variation in the Aldo-Kihi flow (MgO 7.7-8.4 wt %) is consistent with shallow-level fractional crystallization. However, isotopic, trace element and U-series disequilibria data require along-axis mixing of two chemically distinct parental magmas. Pb and Sr isotopes, incompatible element concentrations, MgO contents, Th/U ratios, and (226Ra)/(230Th) disequilibria for Aldo-Kihi samples all peak near ˜17° 30.6'S, the lowest values occur near 17° 26.4'S. This spatial compositional diversity within a single eruption is difficult to reconcile with propagation of a dike originating from a small area, and suggests near-vertical eruption from a magma chamber that is compositionally zoned along-axis. MgO values for the most recent four lava types are lowest between 17° 24.6'S and 17° 27.9'S where the axial magma reservoir is shallowest; the highest MgO values occur south of 17° 30'S. These observations indicate that the processes controlling magma temperature have persisted through several cycles of eruption and recharge. Situated at the apex of a dome-shaped isotopic peak extending from 15.8° S to 20.7° S, samples from this 24 km-long area show isotopic variability (87Sr/86Sr: 0.70256-0.70282, ɛ Nd: +8.1 to +9.3, 206Pb/204Pb: 18.549-18.799) equal to 50 % of the entire range observed along the ˜1100 km-long EPR axis from 13° S to 23° S. These data extend the isotopic peak for axial lavas to values observed previously only in nearby off-axis seamounts and flow fields.
Crew Earth Observations (CEO) taken during Expedition 9
2004-06-18
ISS009-E-12441 (18 June 2004) --- Gebel (or Mount) Edmonstone is featured in this image photographed by an Expedition 9 crewmember on the International Space Station (ISS). Mount Edmonstone is a flat-topped mesa located near the Dahkla Oasis south of Cairo, Egypt. Gebel Edmonstone is a remnant of an eroding scarp that extends for over 200 kilometers (125 miles) east-southeast to west-northwest (visible in the upper left corner of this image). The flat caprock of both the scarp and Mount Edmonstone is chalky limestone underlain by fossil-bearing shale and fine-grained sedimentary rocks. This photograph has been stretched to enhance color variations in the various rock and soil units. The color variations reflect differences in composition (or weathering) of the various rock units. The limestone unit capping Gebel Edmonstone and the adjacent scarp ranges from white to gray in color, while the underlying fine-grained sedimentary layers are blue-gray. Hill slope pathways for sediment movement down slope are clearly visible as brown to tan streamers originating from Gebel Edmonstone. Barchan dune fields are also visible in this color-enhanced image, and are distinct due to their mineralogical composition. Evaporite deposits are bright white, while vegetated portions of the Oasis mostly agricultural fieldsare dark blue-black. This additional information obtained from image enhancement can be used for geologic mapping and investigation of surficial processes operating in the region.
Grundel, Ralph; Frohnapple, Krystal; Zaya, David N.; Glowacki, Gary A.; Weiskerger, Chelsea J.; Patterson, Tamatha A.; Pavlovic, Noel B.
2014-01-01
Distributional patterns across the United States of five avian community breeding-season characteristics—community biomass, richness, constituent species' vulnerability to extirpation, percentage of constituent species' global abundance present in the community (conservation index, CI), and the community's position along the ecological gradient underlying species composition (principal curve ordination score, PC)—were described, their covariation was analyzed, and projected effects of climate change on the characteristics and their covariation were modeled. Higher values of biomass, richness, and CI were generally preferred from a conservation perspective. However, higher values of these characteristics often did not coincide geographically; thus regions of the United States would differ in their value for conservation depending on which characteristic was chosen for setting conservation priorities. For instance, correlation patterns between characteristics differed among Landscape Conservation Cooperatives. Among the five characteristics, community richness and the ecological gradient underlying community composition (PC) had the highest correlations with longitude, with richness declining from east to west across the contiguous United States. The ecological gradient underlying composition exhibited a demarcation near the 100th meridian, separating the contiguous United States grossly into two similar-sized avian ecological provinces. The combined score (CS), a measure of species' threat of decline or extirpation, exhibited the strongest latitudinal pattern, declining from south to north. Over ∼75% of the lower United States, projected changes in June temperature and precipitation to year 2080 were associated with decreased averaged values of richness, biomass, and CI, implying decreased conservation value for birds. The two ecological provinces demarcated near the 100th meridian diverged from each other, with projected changes in June temperatures and precipitation from the year 2000 to 2080 suggesting increased ecological dissimilarity between the eastern and western halves of the lower United States with changing climate. Anticipated climate-related changes in the five characteristics by 2080 were more weakly correlated with latitude or longitude then the responses themselves, indicating less distinct geographic patterns of characteristic change than in the characteristics themselves. Climate changes projected for 2080 included geographic shifts in avian biomass, CS, and PC values, a moderate overall decline in CI, and general decline in species richness per site.
NASA Technical Reports Server (NTRS)
Bleamaster, Leslie F., III; Crown, David A.
2010-01-01
Geologic mapping studies at the 1:1M-scale are being used to assess geologic materials and processes that shape the highlands along the Arabia Terra dichotomy boundary. In particular, this mapping will provide a regional context and evaluate the distribution, stratigraphic position, and potential lateral continuity of compositionally distinct outcrops identified by spectral instruments currently in orbit (i.e., CRISM and OMEGA). Placing these landscapes, their material units, structural features, and unique compositional outcrops into spatial and temporal context with the remainder of the Arabia Terra dichotomy boundary may provide constraints on: 1) origin of the dichotomy boundary, 2) paleoenvironments and climate conditions, and 3) various fluvial-nival modification processes related to past and present volatile distribution and their putative reservoirs (aquifers, lakes and oceans, surface and ground ice) and the influences of nearby volcanic and tectonic features on hydrologic processes, including hydrothermal alteration, across the region.
Comparison of Membrane ATPases from Extreme Halophiles Isolated from Ancient Salt Deposits
NASA Technical Reports Server (NTRS)
Stan-Lotter, Helga; Sulzner, Michael; Egelseer, Eva; Norton, Cynthia F.; Hochstein, Lawrence I.
1993-01-01
Halophilic microorganisms were isolated from Triassic and Permian salt deposits. Two were rods and grew as red colonies; another was a coccus and produced pink colonies. The rods lysed in solutions that lacked added sodium chloride. Growth of all isolates was inhibited by aphidicolin and their bulk proteins were acidic as judged from isoelectric focusing. Therefore, these organisms were tentatively identified as extreme halophiles. Whole cell proteins patterns of the isolates following gel electrophoresis were distinct and differed from those of representative type strains of halophilic bacteria. The membrane ATPases from the rods were similar to the enzyme from Halobacterium saccharovorum with respect to sub unit composition. enzymatic properties and immunological cross-reaction, but differed slightly in amino acid composition. If the age of the microbial isolated is similar to that of the salt deposits, they can be considered repositories of molecular information of great evolutionary interest.
Starke, Verena; Kirshtein, Julie; Fogel, Marilyn L.; Steele, Andrew
2013-01-01
Environmental conditions shape community composition. Arctic thermal springs provide an opportunity to study how environmental gradients can impose strong selective pressures on microbial communities and provide a continuum of niche opportunities. We use microscopic and molecular methods to conduct a survey of microbial community composition at Troll Springs on Svalbard, Norway, in the high Arctic. Microorganisms there exist under a wide range of environmental conditions: in warm water as periphyton, in moist granular materials, and in cold, dry rock as endoliths. Troll Springs has two distinct ecosystems, aquatic and terrestrial, together in close proximity, with different underlying environmental factors shaping each microbial community. Periphyton are entrapped during precipitation of calcium carbonate from the spring's waters, providing microbial populations that serve as precursors for the development of endolithic communities. This process differs from most endolith colonization, in which the rock predates the communities that colonize it. Community composition is modulated as environmental conditions change within the springs. At Troll, the aquatic environments show a small number of dominant operational taxonomic units (OTUs) that are specific to each sample. The terrestrial environments show a more even distribution of OTUs common to multiple samples.
NASA Astrophysics Data System (ADS)
Herd, Christopher D. K.; Walton, Erin L.; Agee, Carl B.; Muttik, Nele; Ziegler, Karen; Shearer, Charles K.; Bell, Aaron S.; Santos, Alison R.; Burger, Paul V.; Simon, Justin I.; Tappa, Michael J.; McCubbin, Francis M.; Gattacceca, Jérôme; Lagroix, France; Sanborn, Matthew E.; Yin, Qing-Zhu; Cassata, William S.; Borg, Lars E.; Lindvall, Rachel E.; Kruijer, Thomas S.; Brennecka, Gregory A.; Kleine, Thorsten; Nishiizumi, Kunihiko; Caffee, Marc W.
2017-12-01
Northwest Africa (NWA) 8159 is an augite-rich shergottite, with a mineralogy dominated by Ca-, Fe-rich pyroxene, plagioclase, olivine, and magnetite. NWA 8159 crystallized from an evolved melt of basaltic composition under relatively rapid conditions of cooling, likely in a surface lava flow or shallow sill. Redox conditions experienced by the melt shifted from relatively oxidizing (with respect to known Martian lithologies, ∼QFM) on the liquidus to higher oxygen fugacity (∼QFM + 2) during crystallization of the groundmass, and under subsolidus conditions. This shift resulted in the production of orthopyroxene and magnetite replacing olivine phenocryst rims. NWA 8159 contains both crystalline and shock-amorphized plagioclase (An50-62), often observed within a single grain; based on known calibrations we bracket the peak shock pressure experienced by NWA 8159 to between 15 and 23 GPa. The bulk composition of NWA 8159 is depleted in LREE, as observed for Tissint and other depleted shergottites; however, NWA 8159 is distinct from all other martian lithologies in its bulk composition and oxygen fugacity. We obtain a Sm-Nd formation age of 2.37 ± 0.25 Ga for NWA 8159, which represents an interval in Mars geologic time which, until recently, was not represented in the other martian meteorite types. The bulk rock 147Sm/144Nd value of 0.37 ± 0.02 is consistent with it being derived directly from its source and the high initial ε143Nd value indicates this source was geochemically highly depleted. Cr, Nd, and W isotopic compositions further support a unique mantle source. While the rock shares similarities with the 2.4-Ga NWA 7635 meteorite, there are notable distinctions between the two meteorites that suggest differences in mantle source compositions and conditions of crystallization. Nevertheless, the two samples may be launch-paired. NWA 8159 expands the known basalt types, ages and mantle sources within the Mars sample suite to include a second igneous unit from the early Amazonian.
Geochemical evidence for diversity of dust sources in the southwestern United States
Reheis, M.C.; Budahn, J.R.; Lamothe, P.J.
2002-01-01
Several potential dust sources, including generic sources of sparsely vegetated alluvium, playa deposits, and anthropogenic emissions, as well as the area around Owens Lake, California, affect the composition of modern dust in the southwestern United States. A comparison of geochemical analyses of modern and old (a few thousand years) dust with samples of potential local sources suggests that dusts reflect four primary sources: (1) alluvial sediments (represented by Hf, K, Rb, Zr, and rare-earth elements, (2) playas, most of which produce calcareous dust (Sr, associated with Ca), (3) the area of Owens (dry) Lake, a human-induced playa (As, Ba, Li, Pb, Sb, and Sr), and (4) anthropogenic and/or volcanic emissions (As, Cr, Ni, and Sb). A comparison of dust and source samples with previous analyses shows that Owens (dry) Lake and mining wastes from the adjacent Cerro Gordo mining district are the primary sources of As, Ba, Li, and Pb in dusts from Owens Valley. Decreases in dust contents of As, Ba, and Sb with distance from Owens Valley suggest that dust from southern Owens Valley is being transported at least 400 km to the east. Samples of old dust that accumulated before European settlement are distinctly lower in As, Ba, and Sb abundances relative to modern dust, likely due to modern transport of dust from Owens Valley. Thus, southern Owens Valley appears to be an important, geochemically distinct, point source for regional dust in the southwestern United States. Copyright ?? 2002 Elsevier Science Ltd.
Genetic and Functional Diversity of Pseudomonas aeruginosa Lipopolysaccharide
Lam, Joseph S.; Taylor, Véronique L.; Islam, Salim T.; Hao, Youai; Kocíncová, Dana
2011-01-01
Lipopolysccharide (LPS) is an integral component of the Pseudomonas aeruginosa cell envelope, occupying the outer leaflet of the outer membrane in this Gram-negative opportunistic pathogen. It is important for bacterium–host interactions and has been shown to be a major virulence factor for this organism. Structurally, P. aeruginosa LPS is composed of three domains, namely, lipid A, core oligosaccharide, and the distal O antigen (O-Ag). Most P. aeruginosa strains produce two distinct forms of O-Ag, one a homopolymer of D-rhamnose that is a common polysaccharide antigen (CPA, formerly termed A band), and the other a heteropolymer of three to five distinct (and often unique dideoxy) sugars in its repeat units, known as O-specific antigen (OSA, formerly termed B band). Compositional differences in the O units among the OSA from different strains form the basis of the International Antigenic Typing Scheme for classification via serotyping of different strains of P. aeruginosa. The focus of this review is to provide state-of-the-art knowledge on the genetic and resultant functional diversity of LPS produced by P. aeruginosa. The underlying factors contributing to this diversity will be thoroughly discussed and presented in the context of its contributions to host–pathogen interactions and the control/prevention of infection. PMID:21687428
Yamanaka, Wataru; Takeshita, Toru; Shibata, Yukie; Matsuo, Kazuki; Eshima, Nobuoki; Yokoyama, Takeshi; Yamashita, Yoshihisa
2012-01-01
Supragingival plaque is permanently in contact with saliva. However, the extent to which the microbiota contributes to the salivary bacterial population remains unclear. We compared the compositional shift in the salivary bacterial population with that in supragingival plaque following periodontal therapy. Samples were collected from 19 patients with periodontitis before and after periodontal therapy (mean sample collection interval, 25.8 ± 2.6 months), and their bacterial composition was investigated using barcoded pyrosequencing analysis of the 16S rRNA gene. Phylogenetic community analysis using the UniFrac distance metric revealed that the overall bacterial community composition of saliva is distinct from that of supragingival plaque, both pre- and post-therapy. Temporal variation following therapy in the salivary bacterial population was significantly smaller than in the plaque microbiota, and the post-therapy saliva sample was significantly more similar to that pre-therapy from the same individual than to those from other subjects. Following periodontal therapy, microbial richness and biodiversity were significantly decreased in the plaque microbiota, but not in the salivary bacterial population. The operational taxonomic units whose relative abundances changed significantly after therapy were not common to the two microbiotae. These results reveal the compositional stability of salivary bacterial populations against shifts in the supragingival microbiota, suggesting that the effect of the supragingival plaque microbiota on salivary bacterial population composition is limited.
Water sorption-desorption in conifer cuticles: The role of lignin.
Reina, José J.; Domínguez, Eva; Heredia, Antonio
2001-07-01
Current information on the type and amount of biopolymers present in the epidermis of conifer species is still insufficient. This work presents the detailed morphology and chemical composition of Araucaria bidwillii cuticle after selective treatments to remove the different types of biopolymers. After removal of the waxes, cutin and polar hydrolyzable components, a lignin-like fraction, which makes up 25% of the initial cuticle weight, was identified by GC-MS and infrared spectroscopy. The isolated lignin is of G type, mainly formed by guaiacyl units. This composition indicates that the conifer cuticle investigated here has similar composition to other conifer-isolated cuticles. Water sorption and desorption by the isolated cuticle and the different cuticle fractions, including lignin, were studied. The analysis of the isotherms, following distinct physicochemical models, gave useful information on the structural and physiological role of the different biopolymers present in the cuticle. Lignin fraction showed both a high water sorption and capability of retaining it in comparision to other cuticle components. Hysteresis effect on water sorption-desorption cycle and water cluster formations has also been studied, and their physiological role discussed.
Li, Wei; Wang, Mengmeng; Pan, Haoqin; Burgaud, Gaëtan; Liang, Shengkang; Guo, Jiajia; Luo, Tian; Li, Zhaoxia; Zhang, Shoumei; Cai, Lei
2018-01-01
How ocean currents shape fungal transport, dispersal and more broadly fungal biogeography remains poorly understood. The East China Sea (ECS) is a complex and dynamic habitat with different water masses blending microbial communities. The internal transcribed spacer 2 region of fungal rDNA was analysed in water and sediment samples directly collected from the coastal (CWM), Kuroshio (KSWM), Taiwan warm (TWM) and the shelf mixed water mass (MWM), coupled with hydrographic properties measurements, to determine how ocean currents impact the fungal community composition. Almost 9k fungal operational taxonomic units (OTUs) spanning six phyla, 25 known classes, 102 orders and 694 genera were obtained. The typical terrestrial and freshwater fungal genus, Byssochlamys, was dominant in the CWM, while increasing abundance of a specific OTU affiliated with Aspergillus was revealed from coastal to open ocean water masses (TWM and KSWM). Compared with water samples, sediment harboured an increased diversity with distinct fungal communities. The proximity of the Yangtze and Qiantang estuaries homogenizes the surface water and sediment communities. A significant influence of ocean currents on community structure was found, which is believed to reduce proportionally the variation explained by environmental parameters at the scale of the total water masses. Dissolved oxygen and depth were identified as the major parameters structuring the fungal community. Our results indicate that passive fungal dispersal driven by ocean currents and river run-off, in conjunction with the distinct hydrographic conditions of individual water masses, shapes the fungal community composition and distribution pattern in the ECS. © 2017 John Wiley & Sons Ltd.
Operating health analysis of electric power systems
NASA Astrophysics Data System (ADS)
Fotuhi-Firuzabad, Mahmud
The required level of operating reserve to be maintained by an electric power system can be determined using both deterministic and probabilistic techniques. Despite the obvious disadvantages of deterministic approaches there is still considerable reluctance to apply probabilistic techniques due to the difficulty of interpreting a single numerical risk index and the lack of sufficient information provided by a single index. A practical way to overcome difficulties is to embed deterministic considerations in the probabilistic indices in order to monitor the system well-being. The system well-being can be designated as healthy, marginal and at risk. The concept of system well-being is examined and extended in this thesis to cover the overall area of operating reserve assessment. Operating reserve evaluation involves the two distinctly different aspects of unit commitment and the dispatch of the committed units. Unit commitment health analysis involves the determination of which unit should be committed to satisfy the operating criteria. The concepts developed for unit commitment health, margin and risk are extended in this thesis to evaluate the response well-being of a generating system. A procedure is presented to determine the optimum dispatch of the committed units to satisfy the response criteria. The impact on the response wellbeing being of variations in the margin time, required regulating margin and load forecast uncertainty are illustrated. The effects on the response well-being of rapid start units, interruptible loads and postponable outages are also illustrated. System well-being is, in general, greatly improved by interconnection with other power systems. The well-being concepts are extended to evaluate the spinning reserve requirements in interconnected systems. The interconnected system unit commitment problem is decomposed into two subproblems in which unit scheduling is performed in each isolated system followed by interconnected system evaluation. A procedure is illustrated to determine the well-being indices of the overall interconnected system. Under normal operating conditions, the system may also be able to carry a limited amount of interruptible load on top of its firm load without violating the operating criterion. An energy based approach is presented to determine the optimum interruptible load carrying capability in both the isolated and interconnected systems. Composite system spinning reserve assessment and composite system well-being are also examined in this research work. The impacts on the composite well-being of operating reserve considerations such as stand-by units, interruptible loads and the physical locations of these resources are illustrated. It is expected that the well-being framework and the concepts developed in this research work will prove extremely useful in the new competitive utility environment.
NASA Astrophysics Data System (ADS)
Dalton, J. B.; Prockter, L. M.; Shirley, J. H.; Phillips, C. B.; Kamp, L.
2011-12-01
Mannanan is a 22-km-diameter impact crater located at 3 N, 240 W on Europa's orbital trailing side. Detailed high resolution geologic mapping by Moore et al. (2001) revealed the likely presence of extensive deposits of impact melt materials largely filling the crater floor, together with surrounding continuous ejecta deposits that may have been excavated from Europa's interior. Terrains surrounding Mannanàn include some of Europa's visibly darkest surfaces, with extensive areas of chaos, traversed by the prominent structure of Belus Linea. The Mannannàn impact crater and its surrounding areas were imaged during the C3 orbital encounter of the Galileo Mission by the orbiter's Near-Infrared Mapping Spectrometer (NIMS). This NIMS observation (C3ENLINEA01A) has not been subjected to a detailed investigation until now, possibly due to the presence of moderate levels of radiation noise. A "despiked" version of this observation has been produced using methods described in Shirley et al. (2010). In addition, new geologic mapping precisely registered to the NIMS coverage of Manannàn and its surroundings allows the extraction of high-quality near-infrared spectra that are specific to individual geologic units and morphological features. We will present linear mixture modeling solutions for the compositions of several of Manannàn's key stratigraphic units, including the crater floor deposits and the adjacent chaos and linea materials. We will interpret these results in the context of ongoing investigations of the interplay of exogenic and endogenic influences on the surface composition of Europa. This work was performed at the Jet Propulsion Laboratory-California Institute of Technology, Johns Hopkins University-Applied Physics Laboratory, and the SETI Institute under a contract with NASA. Support by NASA's Outer Planets Research program is gratefully acknowledged. Moore, J. M. and 25 others 2001. Impact Features on Europa: Results of the Galileo Europa Mission (GEM), Icarus 151, 93-111. Shirley, J. H., J. B. Dalton III, L. M. Prockter, and L. W. Kamp 2010. Europa's ridged plains and smooth low albedo plains: Distinctive compositions and compositional gradients at the leading side-trailing side boundary, Icarus 210, 358-384, doi:10.1016/j.icarus.2010.06.018.
Mora-Ruiz, M Del R; Cifuentes, A; Font-Verdera, F; Pérez-Fernández, C; Farias, M E; González, B; Orfila, A; Rosselló-Móra, R
2018-03-01
Microorganisms are globally distributed but new evidence shows that the microbial structure of their communities can vary due to geographical location and environmental parameters. In this study, 50 samples including brines and sediments from Europe, Spanish-Atlantic and South America were analysed by applying the operational phylogenetic unit (OPU) approach in order to understand whether microbial community structures in hypersaline environments exhibited biogeographical patterns. The fine-tuned identification of approximately 1000 OPUs (almost equivalent to "species") using multivariate analysis revealed regionally distinct taxa compositions. This segregation was more diffuse at the genus level and pointed to a phylogenetic and metabolic redundancy at the higher taxa level, where their different species acquired distinct advantages related to the regional physicochemical idiosyncrasies. The presence of previously undescribed groups was also shown in these environments, such as Parcubacteria, or members of Nanohaloarchaeota in anaerobic hypersaline sediments. Finally, an important OPU overlap was observed between anoxic sediments and their overlaying brines, indicating versatile metabolism for the pelagic organisms. Copyright © 2017 Elsevier GmbH. All rights reserved.
Barth, A.P.; Wooden, J.L.
2006-01-01
Initiation of the Cordilleran magmatic arc in the southwestern United States is marked by intrusion of granitic plutons, predominantly composed of alkali-calcic Fe- and Sr-enriched quartz monzodiorite and monzonite, that intruded Paleoproterozoic basement and its Paleozoic cratonal-miogeoclinal cover. Three intrusive suites, recognized on the basis of differences in high field strength element and large ion lithophile element abundances, contain texturally complex but chronologically distinctive zircons. These zircons record heterogeneous but geochemically discrete mafic crustal magma sources, discrete Permo-Triassic intrusion ages, and a prolonged postemplacement thermal history within the long-lived Cordilleran arc, leading to episodic loss of radiogenic Pb. Distinctive lower crustal magma sources reflect lateral heterogeneity within the composite lithosphere of the Proterozoic craton. Limited interaction between derived magmas and middle and upper crustal rocks probably reflects the relatively cool thermal structure of the nascent Cordilleran continental margin magmatic arc. ?? 2006 by The University of Chicago. All rights reserved.
NASA Astrophysics Data System (ADS)
Long, Kai; Yuan, Philip F.; Xu, Shanqing; Xie, Yi Min
2018-04-01
Most studies on composites assume that the constituent phases have different values of stiffness. Little attention has been paid to the effect of constituent phases having distinct Poisson's ratios. This research focuses on a concurrent optimization method for simultaneously designing composite structures and materials with distinct Poisson's ratios. The proposed method aims to minimize the mean compliance of the macrostructure with a given mass of base materials. In contrast to the traditional interpolation of the stiffness matrix through numerical results, an interpolation scheme of the Young's modulus and Poisson's ratio using different parameters is adopted. The numerical results demonstrate that the Poisson effect plays a key role in reducing the mean compliance of the final design. An important contribution of the present study is that the proposed concurrent optimization method can automatically distribute base materials with distinct Poisson's ratios between the macrostructural and microstructural levels under a single constraint of the total mass.
33 CFR 90.3 - Pushing vessel and vessel being pushed: Composite unit.
Code of Federal Regulations, 2010 CFR
2010-07-01
... pushed: Composite unit. 90.3 Section 90.3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF... vessel being pushed: Composite unit. Rule 24(b) of the Inland Rules states that when a pushing vessel and a vessel being pushed ahead are rigidly connected in a composite unit, they are regarded as a power...
33 CFR 82.3 - Pushing vessel and vessel being pushed: Composite unit.
Code of Federal Regulations, 2010 CFR
2010-07-01
... pushed: Composite unit. 82.3 Section 82.3 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF... vessel being pushed: Composite unit. Rule 24(b) of the 72 COLREGS states that when a pushing vessel and a vessel being pushed ahead are rigidly connected in a composite unit, they are regarded as a power-driven...
Higher winding strings and confined monopoles in N=2 supersymmetric QCD
DOE Office of Scientific and Technical Information (OSTI.GOV)
Auzzi, R.; Bolognesi, S.; Shifman, M.
2010-04-15
We consider composite string solutions in N=2 SQCD with the gauge group U(N), the Fayet-Iliopoulos term {xi}{ne}0 and N (s)quark flavors. These bulk theories support non-Abelian strings and confined monopoles identified with kinks in the two-dimensional world-sheet theory. Similar and more complicated kinks (corresponding to composite confined monopoles) must exist in the world-sheet theories on composite strings. In a bid to detect them we analyze the Hanany-Tong (HT) model, focusing on a particular example of N=2. Unequal quark mass terms in the bulk theory result in the twisted masses in the N=(2,2) HT model. For spatially coinciding 2-strings, we findmore » three distinct minima of potential energy, corresponding to three different 2-strings. Then we find BPS-saturated kinks interpolating between each pair of vacua. Two kinks can be called elementary. They emanate one unit of the magnetic flux and have the same mass as the conventional 't Hooft-Polyakov monopole on the Coulomb branch of the bulk theory ({xi}=0). The third kink represents a composite bimonopole, with twice the minimal magnetic flux. Its mass is twice the mass of the elementary confined monopole. We find instantons in the HT model, and discuss quantum effects in composite strings at strong coupling. In addition, we study the renormalization group flow in this model.« less
NASA Astrophysics Data System (ADS)
Zambon, Francesca; Carli, Cristian; Galluzzi, Valentina; Capaccioni, Fabrizio; Filacchione, Gianrico; Giacomini, Lorenza; Massirioni, Matteo; Palumbo, Pasquale
2016-04-01
Mercury has been explored by two spatial missions. Mariner 10 acquired 45% of the surface during three Hermean flybys in 1974, giving a first close view of the planet. The recent MESSENGER mission globally mapped the planet and contributed to understand many unsolved issues about Mercury (Solomon et al., 2007). Nevertheless, even after MESSENGER, Mercury surface composition remains still unclear, and the correlation between morphology and compositional heterogeneity is not yet well understood. Thanks to the Mercury Dual Imaging System (MDIS), onboard MESSENGER, a global coverage of Mercury surface with variable spatial resolution has been done. MDIS is equipped with a Narrow Angle Camera (NAC), dedicated to the high-resolution study of the surface morphology and a Wide Angle Camera (WAC) with 12 filters useful to investigate the surface composition (Hawkins et al., 2007). Several works were focused on the different terrains present on Mercury, in particular, Denevi et al. (2013) observes that ~27% of Hermean surface is covered by volcanic origin smooth plains. These plains show differences in composition associated to spectral slope variation. High-reflectance red plains (HRP), with spectral slope greater than the average and low-reflectance blue plains (LBP), with spectral slope lesser than the average has been identified. This spectral variations could be correlated with different chemical composition. The X-Ray Spectrometer (XRS) data show that HRP-type areas are associated with a low-Fe basalt-like composition, while the LBP are also Fe poor but are rich in Mg/Si and Ca/Si and with lower Al/Si and are interpreted as more ultramafic (Nittler et al., 2011; Weider et al., 2012; Denevi at al., 2013, Weider et al., 2014). In these work we produce high resolution multicolor mosaic to found a possible link between morphology and composition. The spectral properties have been used to define the principal units of Mercury's surface or to characterize other globally distributed distinct spectral units. Therefore, integrating the spectral variability to a well defined morpho-stratigraphic (photo-interpreted) map will permit to improve the geologic map itself, defining sub-units, and associating spectral properties to analogue deposits. We are working to produce quadrangles color mosaics and high resolution color mosaics of smaller areas to define color products (common planetary geologic map) and obtain an "advanced" geologic map. The mapping process permits integration of different geological surface information to better understand the planet crust formation and evolution. Merging data from different instruments provides additional information about lithological composition, contributing to the construction of a more complete geological map (e.g., Giacomini et al., 2012). These work has been done in support of the BepiColombo Mission, which has an innovative Spectrometer and Imagers Integrated Observatory SYStem (SIMBIO-SYS). SIMBIO-SYS is composed by three instruments, the visible-near-infrared imaging spectrometer (VIHI), the high-resolution imager (HRIC) and the stereo imaging system (STC) which will be albe to improve the knowledge of Mercury surface form the geological and compositional point of view. This research was supported by the Italian Space Agency (ASI) within the SIMBIOSYS project (ASI-INAF agreement no. I/022/10/0)
Changing Understandings of "Public" and "Private" in Higher Education: The United Kingdom Case
ERIC Educational Resources Information Center
Tight, Malcolm
2006-01-01
Where does higher education in the United Kingdom sit today in terms of the public-private distinction, and what does that distinction mean in the higher education context? This article considers these questions and related issues, noting how the particular example of the United Kingdom compares with other systems internationally. Following a…
NASA Astrophysics Data System (ADS)
Thompson, L. M.; Yen, A.; Spray, J. G.; Johnson, J. R.; Fraeman, A. A.; Berger, J. A.; Gellert, R.; Boyd, N.; Desouza, E.; O'Connell-Cooper, C.; VanBommel, S.
2017-12-01
The >230 m thick Murray Formation is the lower-most unit of the Mount Sharp Group, and interpreted as primarily lacustrine. Representative mudstone, siltstone and fine sandstone targets, encountered above -4330 m elevation, trend to lower Si, Al, Ti, Cr and Ca, and higher Fe, Mn, Zn, P and Mg than the Murray below. Less common, distinctive, coarser grained sandstone lenses tend to exhibit slightly different compositions to the more typical Murray but, overall, show similar elemental trends with elevation, albeit exaggerated. This suggests that the variations observed with elevation in Al, Ti, Cr, K, Fe, Mn, Zn and P within both the coarser sandstones and finer grained Murray are the result of diagenetic and/or alteration processes rather than provenance or physical sedimentary processes such as sorting. This is supported by the chemistry of obvious diagenetic, dark grey nodules, and other potential diagenetic/alteration features within this section, which show variations in the same element concentrations (i.e., P, Mn, Fe, Zn, Mg, Ca and S), distinct from diagenetic features lower down in the stratigraphy, indicating mobility of these elements within this section and changing fluid chemistry. Trends in FeO/MnO generally mimic the presence of ferric absorption features observed in visible/near infrared passive spectra from the ChemCam instrument and from CRISM orbital data, which may be consistent with changes in redox conditions as we climb up section towards Vera Rubin Ridge (Hematite Ridge). Layer-parallel CaSO4 is also common, and not observed below -4330 m. This may represent syndepositional evaporite layers, or late bedding/laminae parallel veins emplaced after lithification, in conjunction with cross-cutting veins. The overall differences in composition between the sandstone targets and finer grained Murray are attributed to distinct provenances and/or sorting during transport. We will discuss the implications of the trends and composition of the Murray above -4330 m elevation and how this pertains to the history and evolution of the Murray Formation as a whole, climatic conditions during the formation of the Murray and the nature of Gale crater lake. Also, what do the trends imply about how circulating fluids have evolved within the Murray sediments and pH, redox, salinity conditions of these fluids?
Recovery of anhydrous hydrogen iodide
O'Keefe, Dennis R.; McCorkle, Jr., Kenneth H.; de Graaf, Johannes D.
1982-01-01
Relatively dry hydrogen iodide can be recovered from a mixture of HI, I.sub.2 and H.sub.2 O. After the composition of the mixture is adjusted so that the amounts of H.sub.2 O and I.sub.2 do not exceed certain maximum limits, subjection of the mixture to superatmospheric pressure in an amount equal to about the vapor pressure of HI at the temperature in question causes distinct liquid phases to appear. One of the liquid phases contains HI and not more than about 1 weight percent water. Often the adjustment in the composition will include the step of vaporization, and the distinct layers appear following the increase in pressure of the vapor mixture. Adjustment in the composition may also include the addition of an extraction agent, such as H.sub.3 PO.sub.4, and even though the adjusted composition mixture contains a significant amount of such an agent, the creation of the distinct liquid phases is not adversely affected.
Pragmatism and the Unlikely Influence of German Idealism on the Academy in the United States
ERIC Educational Resources Information Center
Ream, Todd C.
2007-01-01
In this article I argue that the subject-object distinction, operative in Continental Europe during the late-1700s and early-1800s, led to the religion-secular distinction in higher education in the United States. Many scholars believe the origins of the shifting nature of the religion-secular distinction resided with some form of influence that…
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-30
... than 51 acute care inpatient beds (excluding beds in a distinct psychiatric or rehabilitation unit of... services furnished in a psychiatric or rehabilitation unit that is a distinct part of the hospital, using...
Correlation of ash-flow tuffs.
Hildreth, W.; Mahood, G.
1985-01-01
Discrimination and correlation of ash-flow sheets is important in structurally complex, long-lived volcanic fields where such sheets provide the best keys to the regional stratigraphic framework. Three-dimensional complexities resulting from pulsatory eruptions, sectorial emplacement, mechanical sorting during outflow, thermal and compositional zoning of magmas, the physical zoning of cooling units, and structural and erosional disruption can make such correlation and discrimination difficult. When lithologic, magnetic, petrographic, chemical, and isotopic criteria for correlating ash-flow sheets are critically evaluated, many problems and pitfalls can be identified. Distinctive phenocrysts, pumice clasts, and lithic fragments are among the more reliable criteria, as are high-precision K-Ar ages and thermal remanent magnetization (TRM) directions in unaltered welded tuff. Chemical correlation methods should rely principally upon welded or nonwelded pumice blocks, not upon the ash-flow matrix, which is subject to fractionation, mixing, and contamination during emplacement. Compositional zoning of most large sheets requires that many samples be analyzed before phenocryst, glass or whole-rock chemical trends can be used confidently as correlation criteria.-Authors
Jung, Jee-Hyun; Lee, Eun-Hee; Choi, Kwang-Min; Yim, Un Hyuk; Ha, Sung Yong; An, Joon Geon; Kim, Moonkoo
2017-06-01
Crude oils from distinct geographical regions have distinct chemical compositions, and, as a result, their toxicity may be different. However, developmental toxicity of crude oils derived from different geographical regions has not been extensively characterized. In this study, flounder embryos were separately exposed to effluents contaminated by three crude oils including: Basrah Light (BLO), Pyrenees (PCO), and Sakhalin Vityaz (SVO), in addition to a processed fuel oil (MFO-380), to measure developmental toxicity and for gene expressions. Each oil possessed a distinct chemical composition. Edema defect was highest in embryos exposed to PCO and MFO-380 that both have a greater fraction of three-ring PAHs (33% and 22%, respectively) compared to BLO and SVO. Observed caudal fin defects were higher in embryos exposed to SVO and MFO-380, which are both dominated by naphthalenes (81% and 52%, respectively). CYP1A gene expressions were also highest in embryos exposed to SVO and MFO-380. Higher incidence of cardiotoxicity and lower nkx 2.5 expression were detected in embryos exposed to PCO. Unique gene expression profiles were observed in embryos exposed to crude oils with distinct compositions. This study demonstrates that crude oils of different geographical origins with different compositional characteristics induce developmental toxicity to different degrees. Copyright © 2017 Elsevier Inc. All rights reserved.
Herd, Christopher D. K.; Walton, Erin L.; Agee, Carl B.; ...
2017-09-01
Northwest Africa (NWA) 8159 is an augite-rich shergottite, with a mineralogy dominated by Ca-, Fe-rich pyroxene, plagioclase, olivine, and magnetite. NWA 8159 crystallized from an evolved melt of basaltic composition under relatively rapid conditions of cooling, likely in a surface lava flow or shallow sill. Redox conditions experienced by the melt shifted from relatively oxidizing (with respect to known Martian lithologies, ~QFM) on the liquidus to higher oxygen fugacity (~QFM + 2) during crystallization of the groundmass, and under subsolidus conditions. This shift resulted in the production of orthopyroxene and magnetite replacing olivine phenocryst rims. NWA 8159 contains both crystallinemore » and shock-amorphized plagioclase (An 50–62), often observed within a single grain; based on known calibrations we bracket the peak shock pressure experienced by NWA 8159 to between 15 and 23 GPa. The bulk composition of NWA 8159 is depleted in LREE, as observed for Tissint and other depleted shergottites; however, NWA 8159 is distinct from all other martian lithologies in its bulk composition and oxygen fugacity. Here, we obtain a Sm-Nd formation age of 2.37 ± 0.25 Ga for NWA 8159, which represents an interval in Mars geologic time which, until recently, was not represented in the other martian meteorite types. The bulk rock 147Sm/ 144Nd value of 0.37 ± 0.02 is consistent with it being derived directly from its source and the high initial ε 143Nd value indicates this source was geochemically highly depleted. Cr, Nd, and W isotopic compositions further support a unique mantle source. While the rock shares similarities with the 2.4-Ga NWA 7635 meteorite, there are notable distinctions between the two meteorites that suggest differences in mantle source compositions and conditions of crystallization. Nevertheless, the two samples may be launch-paired. Finally, NWA 8159 expands the known basalt types, ages and mantle sources within the Mars sample suite to include a second igneous unit from the early Amazonian.« less
Hybrid Composite Cryogenic Tank Structure
NASA Technical Reports Server (NTRS)
DeLay, Thomas
2011-01-01
A hybrid lightweight composite tank has been created using specially designed materials and manufacturing processes. The tank is produced by using a hybrid structure consisting of at least two reinforced composite material systems. The inner composite layer comprises a distinct fiber and resin matrix suitable for cryogenic use that is a braided-sleeve (and/or a filamentwound layer) aramid fiber preform that is placed on a removable mandrel (outfitted with metallic end fittings) and is infused (vacuum-assisted resin transfer molded) with a polyurethane resin matrix with a high ductility at low temperatures. This inner layer is allowed to cure and is encapsulated with a filamentwound outer composite layer of a distinct fiber resin system. Both inner and outer layer are in intimate contact, and can also be cured at the same time. The outer layer is a material that performs well for low temperature pressure vessels, and it can rely on the inner layer to act as a liner to contain the fluids. The outer layer can be a variety of materials, but the best embodiment may be the use of a continuous tow of carbon fiber (T-1000 carbon, or others), or other high-strength fibers combined with a high ductility epoxy resin matrix, or a polyurethane matrix, which performs well at low temperatures. After curing, the mandrel can be removed from the outer layer. While the hybrid structure is not limited to two particular materials, a preferred version of the tank has been demonstrated on an actual test tank article cycled at high pressures with liquid nitrogen and liquid hydrogen, and the best version is an inner layer of PBO (poly-pphenylenebenzobisoxazole) fibers with a polyurethane matrix and an outer layer of T-1000 carbon with a high elongation epoxy matrix suitable for cryogenic temperatures. A polyurethane matrix has also been used for the outer layer. The construction method is ideal because the fiber and resin of the inner layer has a high strain to failure at cryogenic temperatures, and will not crack or produce leaks. The outer layer serves as more of a high-performance structural unit for the inner layer, and can handle external environments.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Herd, Christopher D. K.; Walton, Erin L.; Agee, Carl B.
Northwest Africa (NWA) 8159 is an augite-rich shergottite, with a mineralogy dominated by Ca-, Fe-rich pyroxene, plagioclase, olivine, and magnetite. NWA 8159 crystallized from an evolved melt of basaltic composition under relatively rapid conditions of cooling, likely in a surface lava flow or shallow sill. Redox conditions experienced by the melt shifted from relatively oxidizing (with respect to known Martian lithologies, ~QFM) on the liquidus to higher oxygen fugacity (~QFM + 2) during crystallization of the groundmass, and under subsolidus conditions. This shift resulted in the production of orthopyroxene and magnetite replacing olivine phenocryst rims. NWA 8159 contains both crystallinemore » and shock-amorphized plagioclase (An 50–62), often observed within a single grain; based on known calibrations we bracket the peak shock pressure experienced by NWA 8159 to between 15 and 23 GPa. The bulk composition of NWA 8159 is depleted in LREE, as observed for Tissint and other depleted shergottites; however, NWA 8159 is distinct from all other martian lithologies in its bulk composition and oxygen fugacity. Here, we obtain a Sm-Nd formation age of 2.37 ± 0.25 Ga for NWA 8159, which represents an interval in Mars geologic time which, until recently, was not represented in the other martian meteorite types. The bulk rock 147Sm/ 144Nd value of 0.37 ± 0.02 is consistent with it being derived directly from its source and the high initial ε 143Nd value indicates this source was geochemically highly depleted. Cr, Nd, and W isotopic compositions further support a unique mantle source. While the rock shares similarities with the 2.4-Ga NWA 7635 meteorite, there are notable distinctions between the two meteorites that suggest differences in mantle source compositions and conditions of crystallization. Nevertheless, the two samples may be launch-paired. Finally, NWA 8159 expands the known basalt types, ages and mantle sources within the Mars sample suite to include a second igneous unit from the early Amazonian.« less
The Residual Polar Caps of Mars: Geological Differences and Possible Consequences
NASA Technical Reports Server (NTRS)
Thomas, P. C.; Sullivan, R.; Ingersoll, A. P.; Murray, B. C.; Danielson, G. E.; Herkenhoff, K. E.; Soderblom, L.; Malin, M. C.; Edgett, K. S.; James, P. B.
2000-01-01
The Martian polar regions have been known to have thick layered sequences (presumed to consist of silicates and ice), CO2 seasonal frost, and residual frosts that remain through the summer: H2O in the north, largely CO2 in the south. The relationship of the residual frosts to the underlying layered deposits could not be determined from Viking images. The Mars Orbiter Camera on Mars Global Surveyor has provided a 50-fold increase in resolution that shows more differences between the two poles. The north residual cap surface has rough topography of pits, cracks, and knobs, suggestive of ablational forms. This topography is less than a few meters in height, and grades in to surfaces exposing the layers underneath. In contrast, the south residual cap has distinctive collapse and possibly ablational topography emplaced in four or more layers, each approx. two meters thick. The top surface has polygonal depressions suggestive of thermal contraction cracks. The collapse and erosional forms include circular and cycloidal depressions, long sinuous troughs, and nearly parallel sets of troughs. The distinctive topography occurs throughout the residual cap area, but not outside it. Unconformities exposed in polar layers, or other layered materials, do not approximate the topography seen on the south residual cap. The coincidence of a distinct geologic feature, several layers modified by collapse, ablation, and mass movement with the residual cap indicates a distinct composition and/or climate compared to both the remainder of the south polar layered units and those in the north.
Human activities cause distinct dissolved organic matter composition across freshwater ecosystems.
Williams, Clayton J; Frost, Paul C; Morales-Williams, Ana M; Larson, James H; Richardson, William B; Chiandet, Aisha S; Xenopoulos, Marguerite A
2016-02-01
Dissolved organic matter (DOM) composition in freshwater ecosystems is influenced by the interactions among physical, chemical, and biological processes that are controlled, at one level, by watershed landscape, hydrology, and their connections. Against this environmental template, humans may strongly influence DOM composition. Yet, we lack a comprehensive understanding of DOM composition variation across freshwater ecosystems differentially affected by human activity. Using optical properties, we described DOM variation across five ecosystem groups of the Laurentian Great Lakes region: large lakes, Kawartha Lakes, Experimental Lakes Area, urban stormwater ponds, and rivers (n = 184 sites). We determined how between ecosystem variation in DOM composition related to watershed size, land use and cover, water quality measures (conductivity, dissolved organic carbon (DOC), nutrient concentration, chlorophyll a), and human population density. The five freshwater ecosystem groups had distinctive DOM composition from each other. These significant differences were not explained completely through differences in watershed size nor spatial autocorrelation. Instead, multivariate partial least squares regression showed that DOM composition was related to differences in human impact across freshwater ecosystems. In particular, urban/developed watersheds with higher human population densities had a unique DOM composition with a clear anthropogenic influence that was distinct from DOM composition in natural land cover and/or agricultural watersheds. This nonagricultural, human developed impact on aquatic DOM was most evident through increased levels of a microbial, humic-like parallel factor analysis component (C6). Lotic and lentic ecosystems with low human population densities had DOM compositions more typical of clear water to humic-rich freshwater ecosystems but C6 was only present at trace to background levels. Consequently, humans are strongly altering the quality of DOM in waters nearby or flowing through highly populated areas, which may alter carbon cycles in anthropogenically disturbed ecosystems at broad scales. © 2015 John Wiley & Sons Ltd.
Human activities cause distinct dissolved organic matter composition across freshwater ecosystems
Williams, Clayton J.; Frost, Paul C.; Morales-Williams, Ana M.; Larson, James H.; Richardson, William B.; Chiandet, Aisha S.; Xenopoulos, Marguerite A.
2016-01-01
Dissolved organic matter (DOM) composition in freshwater ecosystems is influenced by interactions between physical, chemical, and biological processes that are controlled, at one level, by watershed landscape, hydrology, and their connections. Against this environmental template, humans may strongly influence DOM composition. Yet, we lack a comprehensive understanding of DOM composition variation across freshwater ecosystems differentially affected by human activity. Using optical properties, we described DOM variation across five ecosystem groups of the Laurentian Great Lakes Region: large lakes, Kawartha Lakes, Experimental Lakes Area, urban stormwater ponds, and rivers (n = 184 sites). We determined how between ecosystem variation in DOM composition related to watershed size, land use and cover, water quality measures (conductivity, dissolved organic carbon (DOC), nutrient concentration, chlorophyll a), and human population density. The five freshwater ecosystem groups had distinctive DOM composition from each other. These significant differences were not explained completely through differences in watershed size nor spatial autocorrelation. Instead, multivariate partial least squares regression showed that DOM composition was related to differences in human impact across freshwater ecosystems. In particular, urban/developed watersheds with higher human population densities had a unique DOM composition with a clear anthropogenic influence that was distinct from DOM composition in natural land cover and/or agricultural watersheds. This nonagricultural, human developed impact on aquatic DOM was most evident through increased levels of a microbial, humic-like parallel factor analysis component (C6). Lotic and lentic ecosystems with low human population densities had DOM compositions more typical of clear water to humic-rich freshwater ecosystems but C6 was only present at trace to background levels. Consequently, humans are strongly altering the quality of DOM in waters nearby or flowing through highly populated areas, which may alter carbon cycles in anthropogenically disturbed ecosystems at broad scales.
Magnetic signature of the 22 June 1932 tsunami deposits (Jalisco, Mexican Pacific coast)
NASA Astrophysics Data System (ADS)
Bógalo, M. F.; Ramírez-Herrera, M.-T.; Goguitchaichvili, A.; Rey, D.; Mohamed, K. J.; Calvo-Rathert, M.; Corona, N.
2017-06-01
Recent studies have demonstrated that rock-magnetic analysis may provide additional information to distinguish and characterize extreme marine inundation events such as tsunamis. Rock-magnetic proxies reinforce and improve the environmental evidences supplied by other methods, adding some decisive clues for the interpretation of the origin and genesis of the sedimentary deposits. Here we report rock-magnetic, XRD, and SEM microscopy results obtained in the Palo Verde estuary (Colima Pacific coast, Mexico) in order to enhance the tools for identification and reconstruction of two tsunami-induced deposits. The sedimentary sequence includes two sand units, a tsunami deposit (PV1) associated with the 22 June 1932 tsunami and a deeper sandy layer (PV2) related to a possible paleotsunami that occurred around 1300 C.E. Both sandy units are topped by finer grained units. Magnetic properties exhibit a significant correlation with the stratigraphy. High susceptibility (χ) and high saturation isothermal remanence (SIRM) values typical of high concentrations of (titano)magnetite are a distinctive feature of the most recent sandy tsunamigenic unit PV1 and the overlaying soil. The lower sandy tsunamigenic unit PV2 shows significantly lower χ and SIRM values, indicating lower concentration of (titano)magnetite in this unit and the overlaying clayey-silt unit. The latter also shows a higher coercivity component associated with (titano)hematite. Magnetic grain-size differences are also observed between PV1 and PV2 suggesting differences in hydraulic conditions at the time of deposition. The bulk mineralogical composition and sediment texture of these units also support the hypothesis of different provenances for each tsunamigenic unit as inferred from magnetic properties.
A domain-specific design architecture for composite material design and aircraft part redesign
NASA Technical Reports Server (NTRS)
Punch, W. F., III; Keller, K. J.; Bond, W.; Sticklen, J.
1992-01-01
Advanced composites have been targeted as a 'leapfrog' technology that would provide a unique global competitive position for U.S. industry. Composites are unique in the requirements for an integrated approach to designing, manufacturing, and marketing of products developed utilizing the new materials of construction. Numerous studies extending across the entire economic spectrum of the United States from aerospace to military to durable goods have identified composites as a 'key' technology. In general there have been two approaches to composite construction: build models of a given composite materials, then determine characteristics of the material via numerical simulation and empirical testing; and experience-directed construction of fabrication plans for building composites with given properties. The first route sets a goal to capture basic understanding of a device (the composite) by use of a rigorous mathematical model; the second attempts to capture the expertise about the process of fabricating a composite (to date) at a surface level typically expressed in a rule based system. From an AI perspective, these two research lines are attacking distinctly different problems, and both tracks have current limitations. The mathematical modeling approach has yielded a wealth of data but a large number of simplifying assumptions are needed to make numerical simulation tractable. Likewise, although surface level expertise about how to build a particular composite may yield important results, recent trends in the KBS area are towards augmenting surface level problem solving with deeper level knowledge. Many of the relative advantages of composites, e.g., the strength:weight ratio, is most prominent when the entire component is designed as a unitary piece. The bottleneck in undertaking such unitary design lies in the difficulty of the re-design task. Designing the fabrication protocols for a complex-shaped, thick section composite are currently very difficult. It is in fact this difficulty that our research will address.
Grizzle, Raymond E; Ward, Krystin M; AlShihi, Rashid M S; Burt, John A
2016-04-30
Coral reefs of the United Arab Emirates were once extensive, but have declined dramatically in recent decades. Marine management and policy have been hampered by outdated and inaccurate habitat maps and habitat quality information. We combined existing recent datasets with our newly mapped coral habitats to provide a current assessment of nation-wide extent, and performed quantitative surveys of communities at 23 sites to assess coral cover and composition. Over 132 km(2) of coral habitat was mapped, averaging 28.6 ± 3.8% live coral cover at surveyed sites. In the Arabian Gulf low cover, low richness Porites dominated communities characterized western Abu Dhabi, while reefs northeast of Abu Dhabi city generally contained higher richness and cover, and were dominated by merulinids (formerly faviids). Distinct communities occur in the Sea of Oman, where cover and richness were low. We provide management recommendations to enhance conservation of vulnerable coral reefs in the UAE. Copyright © 2015 Elsevier Ltd. All rights reserved.
Microevolution of Monophasic Salmonella Typhimurium during Epidemic, United Kingdom, 2005–2010
Petrovska, Liljana; Mather, Alison E.; AbuOun, Manal; Branchu, Priscilla; Harris, Simon R.; Connor, Thomas; Hopkins, K.L.; Underwood, A.; Lettini, Antonia A.; Page, Andrew; Bagnall, Mary; Wain, John; Parkhill, Julian; Dougan, Gordon; Davies, Robert
2016-01-01
Microevolution associated with emergence and expansion of new epidemic clones of bacterial pathogens holds the key to epidemiologic success. To determine microevolution associated with monophasic Salmonella Typhimurium during an epidemic, we performed comparative whole-genome sequencing and phylogenomic analysis of isolates from the United Kingdom and Italy during 2005–2012. These isolates formed a single clade distinct from recent monophasic epidemic clones previously described from North America and Spain. The UK monophasic epidemic clones showed a novel genomic island encoding resistance to heavy metals and a composite transposon encoding antimicrobial drug resistance genes not present in other Salmonella Typhimurium isolates, which may have contributed to epidemiologic success. A remarkable amount of genotypic variation accumulated during clonal expansion that occurred during the epidemic, including multiple independent acquisitions of a novel prophage carrying the sopE gene and multiple deletion events affecting the phase II flagellin locus. This high level of microevolution may affect antigenicity, pathogenicity, and transmission. PMID:26982594
Geology, tectonism and composition of the northwest Imbrium region
NASA Astrophysics Data System (ADS)
Wu, Yunzhao; Li, Lin; Luo, Xiaoxing; Lu, Yu; Chen, Yuan; Pieters, Carle M.; Basilevsky, Alexander T.; Head, James W.
2018-03-01
The objective of this study is to explore the regional geology of the northwest Imbrium region in which the Chang'E-3 (CE-3) landing site is located. CE-3 successfully landed on December 14, 2013 on the unsampled Eratosthenian basalts whose study is important for understanding the evolution of the Moon. New geologic and structural maps of the research area were produced through the integrated analysis of diverse datasets. The highlands surrounding Imbrium differ from typical Farside Highlands Terrain (FHT). The Iridum highland region (as well as the surrounding Imbrium region) exhibits elevated concentrations of Fe, and abundant local exposures of low-Ca pyroxene and olivine bearing lithologies. In this study these highlands are named as mafic highlands (MH). Our dating results using crater size-frequency distributions (CSFDs) show that the Iridum basin (hosting Sinus Iridum) was formed ∼3.8 Ga, shortly following the Imbrium basin formation and before the last large multiringed basin, Orientale. The Eratosthenian period of lunar basalt eruptions, which lasted longer than other stratigraphic units, is suggested to divide into the Lower Eratosthenian mare (LEm) and Upper Eratosthenian mare (UEm) units. This subdivision is based on whether lava fronts can be clearly seen or not and the age separating the units is 2.35 Ga. The mafic mineralogy of the mare basalts in Imbrium is characterized by abundant olivine in the Eratosthenian-aged basalts and average pyroxene compositions near pigeonite to sub-calcic augite in the Imbrian and Em1 units. The thickness of individual lava for UEm units is 8-11 m, indicative of high effusion rates. The thickness of the Em3 unit ranges from ∼17 m to ∼45 m with lesser thickness to the west and greater thickness in the interior and to the east. The estimated volume and average flux of the Eratosthenian-aged basalts are greater than previously thought. The presence of these youngest basalts in the Procellarum-KREEP terrain (PKT) is hypothesized to be a causal relationship, with the PKT terrain reducing the thickness of the lithosphere and permitting preferential dike emplacement and extrusion there. We speculate that high-Ti and olivine-rich composition in late stage basalts may be consistent with low Si and high Ti and low degrees of partial melting. Large numbers of sinuous rilles and small ridges are identified and mapped. Many young ridges were found inside Imbrium, suggesting a very extended period (at least as young as the last 50 Ma) of the Moon's tectonic activity. The distinct compositions of both highlands and mare basalts and extended tectonism emphasize how the Imbrium basin is an important area for understanding the Moon.
Geology of the Smythii and Marginis Region of the Moon: Using Integrated Remotely Sensed Data
NASA Technical Reports Server (NTRS)
Gillis, Jeffrey J.; Spudis, Paul D.
2000-01-01
We characterized the diverse and complex geology of the eastern limb region of the Moon using a trio of remote-sensing data sets: Clementine, Lunar Prospector, and Apollo. On the basis of Clementine-derived iron and titanium maps we classify the highlands into low-iron (3-6 wt % FeO) and high-iron (6-9 wt % FeO) units. The association of the latter with basalt deposits west of Smythii basin suggests that the highland chemical variation is the result of mixing between basalt and highland lithologies. Mare Smythii and Mare Marginis soils are compositionally similar, containing moderate iron (15-18 wt % FeO) and titanium (2.5-3.5 wt % TiO2). Smythii basin, in addition to the basalt deposits, contains an older, moderate-albedo plains unit. Our investigation reveals that the dark basin plains unit has a distinct albedo, chemistry, and surface texture and formed as a result of impact-mixing between highland and mare lithologies in approximately equal proportions. Clementine iron and maturity maps show that swirls along the northern margin of Mare Marginis have the same iron composition as the surrounding nonswirl material and indicate that the swirl material is bright because of its low agglutinate content. Gravity data for the eastern limb show high, positive Bouguer gravity anomalies for areas of thin basalt cover (e.g., Smythii basin and complex craters Joliot, Lomonosov, and Neper). We deduce that the uplift of dense mantle material is the primary (and mare basaltic fill the secondary) source for generating the concentration of mass beneath large craters and basins.
Eberts, Rebecca L.; Wissel, Bjorn; Simpson, Gavin L.; Crawford, Stephen S.; Stott, Wendylee; Hanner, Robert H.; Manzon, Richard G.; Wilson, Joanna Y.; Boreham, Douglas R.; Somers, Christopher M.
2017-01-01
Lake Whitefish Coregonus clupeaformis is the most commercially valuable species in Lake Huron. The fishery for this species has historically been managed based on 25 management units (17 in Canada, 8 in the USA). However, congruence between the contemporary population structure of Lake Whitefish and management units is poorly understood. We used stable isotopes of carbon (δ13C) and nitrogen (δ15N), food web markers that reflect patterns in resource use (i.e., prey, location, habitat), to assess the population structure of spawning-phase Lake Whitefish collected from 32 sites (1,474 fish) across Lake Huron. We found large isotopic variation among fish from different sites (ranges: δ13C = 10.2‰, δ15N = 5.5‰) and variable niche size and levels of overlap (standard ellipse area = 1.0–4.3‰2). Lake Huron contained spawning-phase fish from four major isotopic clusters largely defined by extensive variation in δ13C, and the isotopic composition of fish sampled was spatially structured both within and between lake basins. Based on cluster compositions, we identified six putative regional groups, some of which represented sites of high diversity (three to four clusters) and others with less (one to two clusters). Analysis of isotopic values from Lake Whitefish collected from summer feeding locations and baseline prey items showed similar isotopic variation and established spatial linkage between spawning-phase and summer fish. Our results show that summer feeding location contributes strongly to the isotopic structure we observed in spawning-phase fish. One of the regional groups we identified in northern Georgian Bay is highly distinct based on isotopic composition and possibly ecologically unique within Lake Huron. Our findings are congruent with several previous studies using different markers (genetics, mark–recapture), and we conclude that current management units are generally too small and numerous to reflect the population structure of Lake Whitefish in Lake Huron.
Engineering complex orthopaedic tissues via strategic biomimicry.
Qu, Dovina; Mosher, Christopher Z; Boushell, Margaret K; Lu, Helen H
2015-03-01
The primary current challenge in regenerative engineering resides in the simultaneous formation of more than one type of tissue, as well as their functional assembly into complex tissues or organ systems. Tissue-tissue synchrony is especially important in the musculoskeletal system, wherein overall organ function is enabled by the seamless integration of bone with soft tissues such as ligament, tendon, or cartilage, as well as the integration of muscle with tendon. Therefore, in lieu of a traditional single-tissue system (e.g., bone, ligament), composite tissue scaffold designs for the regeneration of functional connective tissue units (e.g., bone-ligament-bone) are being actively investigated. Closely related is the effort to re-establish tissue-tissue interfaces, which is essential for joining these tissue building blocks and facilitating host integration. Much of the research at the forefront of the field has centered on bioinspired stratified or gradient scaffold designs which aim to recapitulate the structural and compositional inhomogeneity inherent across distinct tissue regions. As such, given the complexity of these musculoskeletal tissue units, the key question is how to identify the most relevant parameters for recapitulating the native structure-function relationships in the scaffold design. Therefore, the focus of this review, in addition to presenting the state-of-the-art in complex scaffold design, is to explore how strategic biomimicry can be applied in engineering tissue connectivity. The objective of strategic biomimicry is to avoid over-engineering by establishing what needs to be learned from nature and defining the essential matrix characteristics that must be reproduced in scaffold design. Application of this engineering strategy for the regeneration of the most common musculoskeletal tissue units (e.g., bone-ligament-bone, muscle-tendon-bone, cartilage-bone) will be discussed in this review. It is anticipated that these exciting efforts will enable integrative and functional repair of soft tissue injuries, and moreover, lay the foundation for the development of composite tissue systems and ultimately, total limb or joint regeneration.
Engineering Complex Orthopaedic Tissues via Strategic Biomimicry
Qu, Dovina; Mosher, Christopher Z.; Boushell, Margaret K.; Lu, Helen H.
2014-01-01
The primary current challenge in regenerative engineering resides in the simultaneous formation of more than one type of tissue, as well as their functional assembly into complex tissues or organ systems. Tissue-tissue synchrony is especially important in the musculoskeletal system, whereby overall organ function is enabled by the seamless integration of bone with soft tissues such as ligament, tendon, or cartilage, as well as the integration of muscle with tendon. Therefore, in lieu of a traditional single-tissue system (e.g. bone, ligament), composite tissue scaffold designs for the regeneration of functional connective tissue units (e.g. bone-ligament-bone) are being actively investigated. Closely related is the effort to re-establish tissue-tissue interfaces, which is essential for joining these tissue building blocks and facilitating host integration. Much of the research at the forefront of the field has centered on bioinspired stratified or gradient scaffold designs which aim to recapitulate the structural and compositional inhomogeneity inherent across distinct tissue regions. As such, given the complexity of these musculoskeletal tissue units, the key question is how to identify the most relevant parameters for recapitulating the native structure-function relationships in the scaffold design. Therefore, the focus of this review, in addition to presenting the state-of-the-art in complex scaffold design, is to explore how strategic biomimicry can be applied in engineering tissue connectivity. The objective of strategic biomimicry is to avoid over-engineering by establishing what needs to be learned from nature and defining the essential matrix characteristics that must be reproduced in scaffold design. Application of this engineering strategy for the regeneration of the most common musculoskeletal tissue units (e.g. bone-ligament-bone, muscle-tendon-bone, cartilage-bone) will be discussed in this review. It is anticipated that these exciting efforts will enable integrative and functional repair of soft tissue injuries, and moreover, lay the foundation for the development of composite tissue systems and ultimately, total limb or joint regeneration. PMID:25465616
Micromechanics Fatigue Damage Analysis Modeling for Fabric Reinforced Ceramic Matrix Composites
NASA Technical Reports Server (NTRS)
Min, J. B.; Xue, D.; Shi, Y.
2013-01-01
A micromechanics analysis modeling method was developed to analyze the damage progression and fatigue failure of fabric reinforced composite structures, especially for the brittle ceramic matrix material composites. A repeating unit cell concept of fabric reinforced composites was used to represent the global composite structure. The thermal and mechanical properties of the repeating unit cell were considered as the same as those of the global composite structure. The three-phase micromechanics, the shear-lag, and the continuum fracture mechanics models were integrated with a statistical model in the repeating unit cell to predict the progressive damages and fatigue life of the composite structures. The global structure failure was defined as the loss of loading capability of the repeating unit cell, which depends on the stiffness reduction due to material slice failures and nonlinear material properties in the repeating unit cell. The present methodology is demonstrated with the analysis results evaluated through the experimental test performed with carbon fiber reinforced silicon carbide matrix plain weave composite specimens.
Isotopic imprints of mountaintop mining contaminants.
Vengosh, Avner; Lindberg, T Ty; Merola, Brittany R; Ruhl, Laura; Warner, Nathaniel R; White, Alissa; Dwyer, Gary S; Di Giulio, Richard T
2013-09-03
Mountaintop mining (MTM) is the primary procedure for surface coal exploration within the central Appalachian region of the eastern United States, and it is known to contaminate streams in local watersheds. In this study, we measured the chemical and isotopic compositions of water samples from MTM-impacted tributaries and streams in the Mud River watershed in West Virginia. We systematically document the isotopic compositions of three major constituents: sulfur isotopes in sulfate (δ(34)SSO4), carbon isotopes in dissolved inorganic carbon (δ(13)CDIC), and strontium isotopes ((87)Sr/(86)Sr). The data show that δ(34)SSO4, δ(13)CDIC, Sr/Ca, and (87)Sr/(86)Sr measured in saline- and selenium-rich MTM impacted tributaries are distinguishable from those of the surface water upstream of mining impacts. These tracers can therefore be used to delineate and quantify the impact of MTM in watersheds. High Sr/Ca and low (87)Sr/(86)Sr characterize tributaries that originated from active MTM areas, while tributaries from reclaimed MTM areas had low Sr/Ca and high (87)Sr/(86)Sr. Leaching experiments of rocks from the watershed show that pyrite oxidation and carbonate dissolution control the solute chemistry with distinct (87)Sr/(86)Sr ratios characterizing different rock sources. We propose that MTM operations that access the deeper Kanawha Formation generate residual mined rocks in valley fills from which effluents with distinctive (87)Sr/(86)Sr and Sr/Ca imprints affect the quality of the Appalachian watersheds.
Marshall, David C; Hill, Kathy B R
2017-05-31
A morphologically cryptic subspecies of Neotibicen similaris (Smith and Grossbeck) is described from forests of the Apalachicola region of the southeastern United States. Although the new form exhibits a highly distinctive male calling song, it hybridizes extensively where it meets populations of the nominate subspecies in parapatry, by which it is nearly surrounded. This is the first reported example of hybridization between North American nonperiodical cicadas. Acoustic and morphological characters are added to the original description of the nominate subspecies, and illustrations of complex hybrid song phenotypes are presented. The biogeography of N. similaris is discussed in light of historical changes in forest composition on the southeastern Coastal Plain.
Meteoric sphaerosiderite lines and their use for paleohydrology and paleoclimatology
Ludvigson, Greg A.; Gonzalez, Luis A.; Metzger, R.A.; Witzke, B.J.; Brenner, Richard L.; Murillo, A.P.; White, T.S.
1998-01-01
Sphaerosiderite, a morphologically distinct millimeter-scale spherulitic siderite (FeCO3), forms predominantly in wetland soils and sediments, and is common in the geologic record. Ancient sphaerosiderites are found in paleosol horizons within coal-bearing stratigraphic intervals and, like their modern counterparts, are interpreted as having formed in water-saturated environments. Here we report on sphaerosiderites from four different stratigraphic units, each of which has highly variable 13C and relatively stable 18O compositions. The unique isotopic trends are analogous to well-documented meteoric calcite lines, which we define here as meteoric sphaerosiderite lines. Meteoric sphaerosiderite lines provide a new means of constraining ground-water ??18O and thus allow evaluation of paleohydrology and paleoclimate in humid continental settings.
A primordial origin for the compositional similarity between the Earth and the Moon.
Mastrobuono-Battisti, Alessandra; Perets, Hagai B; Raymond, Sean N
2015-04-09
Most of the properties of the Earth-Moon system can be explained by a collision between a planetary embryo (giant impactor) and the growing Earth late in the accretion process. Simulations show that most of the material that eventually aggregates to form the Moon originates from the impactor. However, analysis of the terrestrial and lunar isotopic compositions show them to be highly similar. In contrast, the compositions of other Solar System bodies are significantly different from those of the Earth and Moon, suggesting that different Solar System bodies have distinct compositions. This challenges the giant impact scenario, because the Moon-forming impactor must then also be thought to have a composition different from that of the proto-Earth. Here we track the feeding zones of growing planets in a suite of simulations of planetary accretion, to measure the composition of Moon-forming impactors. We find that different planets formed in the same simulation have distinct compositions, but the compositions of giant impactors are statistically more similar to the planets they impact. A large fraction of planet-impactor pairs have almost identical compositions. Thus, the similarity in composition between the Earth and Moon could be a natural consequence of a late giant impact.
NASA Astrophysics Data System (ADS)
Cocherie, A.; Rossi, Ph.; Le Bel, L.
1984-10-01
Petrographic and structural observations on the calc-alkalic plutonism of western Corsica revealed the existence of several successively emplaced units associated with large basic bodies. The present mineralogical and geochemical study deals with the genesis, evolution and relationships of these different units. Basic plutonism is represented by three genetically linked types of rock: norites and troctolites with cumulate textures characterized by low REE contents and either no Eu anomaly or a positive Eu anomaly; gabbros with enriched LREE relatively to HREE patterns, probably close to an initial basaltic liquid; and diorites ranging up to charnockites which represent liquids evolved to varying degrees, mainly by fractional crystallization. Trace element data and studies on the evolution of pyroxene pairs demonstrate the consanguinity of these calc-alkaline basic rocks which are derived from a high alumina basaltic melt. The various granitoids (granodiorites, monzogranites and leucocratic monzogranites, i.e., adamellites) have distinct evolution trends as shown by the composition of their mafic minerals and by trace element distributions. They cannot be considered as being derivatives of the basic suite and they cannot be related by a common fractionation sequence. Rather, they represent distinctive batches of crustal anatexis. In addition, hybridization phenomena with the basic melt are noticed in granodiorites. The particular problem of the low La/Yb, Eu/Eu∗ and the high U, Th, Cs leucocratic monzogranites is discussed in detail. In addition to more conventional trace element diagrams, the simultaneous statistical treatment of all the geochemical data by correspondence factor analysis is shown to be a very use tool in distinguishing between the different units and to classify the elements according to their geochemical properties.
NASA Astrophysics Data System (ADS)
Tirsch, D.; Bishop, J. L.; Voigt, J. R. C.; Tornabene, L. L.; Erkeling, G.; Jaumann, R.
2018-11-01
We analyze the emplacement chronology and aqueous alteration history of distinctive mineral assemblages and related geomorphic units near Hashir and Bradbury impact craters located within the Libya Montes, which are part of the southern rim of the Isidis Basin on Mars. We derive our results from a spectro-morphological mapping project that combines spectral detections from CRISM near-infrared imagery with geomorphology and topography from HRSC, CTX, and HiRISE imagery. Through this combination of data sets, we were able to use the morphology associated with specific mineral detections to extrapolate the possible extent of the units hosting these compositions. We characterize multiple units consistent with formation through volcanic, impact, hydrothermal, lacustrine and evaporative processes. Altered pyroxene-bearing basement rocks are unconformably overlain by an olivine-rich unit, which is in turn covered by a pyroxene-bearing capping unit. Aqueously altered outcrops identified here include nontronite, saponite, beidellite, opal, and dolomite. The diversity of mineral assemblages suggests that the nature of aqueous alteration at Libya Montes varied in space and time. This mineralogy together with geologic features shows a transition from Noachian aged impact-induced hydrothermal alteration and the alteration of Noachian bedrock by neutral to slightly basic waters via Hesperian aged volcanic emplacements and evaporative processes in lacustrine environments followed by Amazonian resurfacing in the form of aeolian erosion.
Pahlevan, Ayob; Tabatabaei, Masumeh Hasani; Arami, Sakineh; Valizadeh, Sara
2016-01-01
Objectives: Different light curing units are used for polymerization of composite resins. The aim of this study was to evaluate the degree of conversion (DC) and temperature rise in hybrid and low shrinkage composite resins cured by LED and Argon Laser curing lights. Materials and Methods: DC was measured using FTIR spectroscopy. For measuring temperature rise, composite resin samples were placed in Teflon molds and cured from the top. The thermocouple under samples recorded the temperature rise. After initial radiation and specimens reaching the ambient temperature, reirradiation was done and temperature was recorded again. Both temperature rise and DC data submitted to one-way ANOVA and Tukey-HSD tests (5% significance). Results: The obtained results revealed that DC was not significantly different between the understudy composite resins or curing units. Low shrinkage composite resin showed a significantly higher temperature rise than hybrid composite resin. Argon laser caused the lowest temperature rise among the curing units. Conclusion: Energy density of light curing units was correlated with the DC. Type of composite resin and light curing unit had a significant effect on temperature rise due to polymerization and curing unit, respectively. PMID:27843507
Pahlevan, Ayob; Tabatabaei, Masumeh Hasani; Arami, Sakineh; Valizadeh, Sara
2016-01-01
Different light curing units are used for polymerization of composite resins. The aim of this study was to evaluate the degree of conversion (DC) and temperature rise in hybrid and low shrinkage composite resins cured by LED and Argon Laser curing lights. DC was measured using FTIR spectroscopy. For measuring temperature rise, composite resin samples were placed in Teflon molds and cured from the top. The thermocouple under samples recorded the temperature rise. After initial radiation and specimens reaching the ambient temperature, reirradiation was done and temperature was recorded again. Both temperature rise and DC data submitted to one-way ANOVA and Tukey-HSD tests (5% significance). The obtained results revealed that DC was not significantly different between the understudy composite resins or curing units. Low shrinkage composite resin showed a significantly higher temperature rise than hybrid composite resin. Argon laser caused the lowest temperature rise among the curing units. Energy density of light curing units was correlated with the DC. Type of composite resin and light curing unit had a significant effect on temperature rise due to polymerization and curing unit, respectively.
NASA Astrophysics Data System (ADS)
Edwards, C. S.; Ehlmann, B. L.
2013-12-01
The regional and local scale geology of the Nili Fossae region has been characterized in detail by a variety of investigators [e.g. Hamilton and Christensen, 2005; Mangold et al., 2007; Mustard et al., 2007; 2009; Ehlmann et al., 2008; 2009]. Several distinctive stratigraphic units record a number of unique environments and varied history of aqueous alteration, from the early Noachian to early Hesperian, including: 1) Fe/Mg smectite clay-bearing units commonly found in ancient Martian terrains, 2) a rocky carbonate- and olivine-bearing unit, 3) an Al clay-bearing unit, 4) a mafic cap unit of basaltic composition, and 5) olivine-bearing sands. In this work, we examined key locations with an emphasis on constraining the nature and geologic conditions responsible for the areally extensive Carbonate Plains, a >60 km by 80 km region of bedrock and sands east of the Nili Fossae. In order to accomplish this, it was first necessary to establish means of differentiating the five units above in a variety of datasets including the High Resolution Imaging Science Experiment (HiRISE), Context Imager (CTX), Compact Reconnaissance Imaging Spectrometer (CRISM), Thermal Emission Imaging System (THEMIS), and Thermal Emission Spectrometer (TES) data. We show TES and THEMIS compositional data can be directly related to CRISM compositional data where outcrops are large enough or geologic units are relatively homogenous within the instruments' measurement footprints. In addition to constraining the physical nature/thermal inertia (TI) of the materials in the scene (e.g. dust, sand, rock [Fergason et al., 2006]), THEMIS and TES data, when used in combination with morphologic data, provide valuable regional coverage where CRISM compositional data are not available. At TES scales the composition of the carbonate plains is consistent with an olivine-rich (~20% Fo60) basalt that has been altered to contain ~15% Mg-/Fe-carbonate. However, this carbonate abundance should be considered a minimum value, as the carbonate bearing rock exposures are significantly smaller than a single TES pixel. In co-located CRISM, THEMIS, and CTX data we observe an areal mixture of 2 components: 1) high TI (~600 J K-1 m-2 s-1/2) carbonate bearing, olivine-basalt bedrock and 2) low TI (~270 J K-1 m-2 s-1/2) carbonate-poor, olivine-basalt sands. By relating the TES spectral unmixing values to the areal fraction of carbonate rock exposures mapped using alternate datasets, the carbonate abundance of the only the bedrock component will be constrained. Furthermore, using Hapke modeling of CRISM spectra, we further constrain our abundance estimates of the unit. References: Ehlmann, B. L., et al. (2008), Science, 322(5909), 1828. Ehlmann, B. L., et al. (2009), J. Geophys. Res., 114, E00D08. Fergason, R. L., et al. (2006), J. Geophys. Res., 111, E12004. Hamilton, V. E. and P.R. Christensen (2005), Geology, 33(6), 433-436. Mangold, N., et al. (2007), J. Geophys. Res., 112, E08S04. Mustard, J. F., et al. (2007), J. Geophys. Res., 112, E08S03. Mustard, J. F., et al. (2009), J. Geophys. Res., 114, E00D12.
NASA Astrophysics Data System (ADS)
Alberti, A.; Alessandro, V.; Pieruccini, U.; Pranzini, E.
1993-10-01
Landsat TM data were used for lithological discrimination and mapping in the little-known, semiarid 900 km 2 area around Caraculo station and the middle course of the Rio Giraul (Namibe Province, SW Angola) following two main procedures. The first of these was based on visual evaluation of three-band composites, band-ratio composites and Principal Component Analysis. The second method relied on the extraction of spectral signatures, and their use to obtain automatic classifications. Satisfactory results were reached with the first procedure, thus allowing - with limited support of ground information — the draft of a lithological map, while the second method was not systematically efficient, even for confirmation of data acquired with the first procedure. Image interpretation suggests that an extensive but hithertoun differentiated metasedimentary complex consisting of a heterogeneous supracrustal sequence should be subdivided into at least two units. Field observations proved that one of these is marked by a notable frequency of marbles and the other is characterized by a widespread occurrence of amphibolitic bodies. Moreover, a belt of undetermined (thermally metamorphosed ?) metamorphic rocks is interposed between them. The distinction of so far unidentified units, though restricted to interpretation of processed Landsat TM data, has significant geological implications also in the regional context and will be helpful in guiding future work with conventional geological methods.
The XRD Amorphous Component in John Klein Drill Fines at Yellowknife Bay, Gale Crater, Mars
NASA Technical Reports Server (NTRS)
Morris, Richard V.; Ming,, Douglas W.; Blake, David; Vaniman, David; Bish, David L; Chipera, Steve; Downs, Robert; Morrison, Shaunna; Gellert, Ralf; Campbell, Iain;
2013-01-01
Drill fines of mudstone (targets John Klein and Cumberland) from the Sheepbed unit at Yel-lowknife Bay were analyzed by MSL payload elements including the Chemistry and Mineralogy (CheMin), APXS (Alpha Particle X-Ray Spectrometer), and Sample Analysis at Mars (SAM) instruments. CheMin XRD results show a variety of crystalline phases including feldspar, pyroxene, olivine, oxides, oxyhydroxides, sulfates, sulfides, a tri-octahedral smectite, and XRD amorphous material. The drill fines are distinctly different from corresponding analyses of the global soil (target Rocknest) in that the mudstone samples contained detectable phyllosilicate. Here we focus on John Klein and combine CheMin and APXS data to calculate the chemical composition and concentration of the amorphous component. The chemical composition of the amorphous plus smectite component for John Klein was calculated by subtracting the abundance-weighted chemical composition of the individual XRD crystalline components from the bulk composition of John Kline as measured by APXS. The chemical composition of individual crystalline components was determined either by stoichiometry (e.g., hematite and magnetite) or from their unit cell parameters (e.g., feldspar, olivine, and pyroxene). The chemical composition of the amorphous + smectite component (approx 71 wt.% of bulk sample) and bulk chemical composition are similar. In order to calculate the chemical composition of the amorphous component, a chemical composition for the tri-octahedral smectite must be assumed. We selected two tri-octahedral smectites with very different MgO/(FeO + Fe2O3) ratios (34 and 1.3 for SapCa1 and Griffithite, respectively). Relative to bulk sample, the concentration of amorphous and smectite components are 40 and 29 wt.% for SapCa1 and 33 and 36 wt.% for Griffithite. The amount of smectite was calculated by requiring the MgO concentration to be approx 0 wt.% in the amorphous component. Griffithite is the preferred smectite because the position of its 021 diffraction peak is similar to that reported for John Klein. In both cases, the amorphous component has low SiO2 and MgO and high FeO + Fe2O3, P2O5, and SO3 concentrations relative to bulk sample. The chemical composition of the bulk drill fines and XRD crystalline, smectite, and amorphous components implies alteration of an initially basaltic material under near neutral conditions (not acid sulfate), with the sulfate incorporated later as veins of CaSO4 injected into the mudstone.
Walker, B.A.; Miller, C.F.; Lowery, Claiborne L.; Wooden, J.L.; Miller, J.S.
2007-01-01
The Spirit Mountain batholith (SMB) is a ??? 250??km2 composite silicic intrusion located within the Colorado River Extensional Corridor in southernmost Nevada. Westward tilting of 40-50?? has exposed a cross-section from the roof through deep levels of the batholith. Piecemeal construction is indicated by zircon geochronology, field relations, and elemental geochemistry. Zircon U/Pb data (SHRIMP) demonstrates a ??? 2??million year (17.4-15.3??Ma) history for the SMB. Individual samples contain zircons with ages that span the lifetime of the batholith, suggesting recycling of extant zircon into new magma pulses. Field relations reveal several distinct intrusive episodes and suggest a common injection geometry of stacked horizontal sheets. The largest unit of the SMB is a gradational section (from roof downward) of high-silica leucogranite through coarse granite into foliated quartz monzonite. Solidification of this unit spans most of the history of the batholith. The 25??km ?? 2??km leucogranite was emplaced incrementally as subhorizontal sheets over most or all of the history of this section, suggesting repeated fractional crystallization and melt segregation events. The quartz monzonite and coarse granite are interpreted to be cumulate residuum of this fractionation. Age data from throughout this gradational unit show multiple zircon populations within individual samples. Subsequent distinct intrusions that cut this large unit, which include minor populations of zircons that record the ages of earlier events in construction of the batholith, preserve a sheeted, sill-on-sill geometry. We envision the SMB to have been a patchwork of melt-rich, melt-poor, and entirely solid zones throughout its active life. Preservation of intrusion geometries and contacts depended on the consistency of the host rock. Zircons recycled into new pulses of magma document remobilization of previously emplaced crystal mush, suggesting the mechanisms by which evidence for initial construction of the batholith became blurred. ?? 2007.
The temporal characteristics of humpback whale songs
NASA Astrophysics Data System (ADS)
Au, Whitlow W. L.; Lammers, Marc O.; Stimpert, Alison; Schotten, Michiel
2005-09-01
Songs sung by male humpback whales consist of distinct, pulsed sounds that are designated as units. Units are produced in some sequence to form a phrase, a repeated set of phrases forms a theme, and repeated themes form a song. A song can last from minutes to hours. The songs of eight humpback whales were recorded with a vertical array of five hydrophones spaced 7 m apart with the array located within 100 m of the whales. At least seven distinct units were identified aurally from this data set obtained during the 2002 winter humpback whale session in Hawaii. Four distinct recurring themes were found in the songs, and for each whale at least two themes were recorded. The average duration of each unit sampled and the silent interval following the unit were determined in order to describe the temporal characteristics of the songs. From the data the temporal consistency and cadence control of unit production by each humpback whale and between whales were determined. Understanding the temporal and spectral characteristics of units within songs and how these units vary between whales could ultimately help in the design of computer algorithms to automatically identify individual whales.
The Balmer basin - Regional geology and geochemistry of an ancient lunar impact basin
NASA Technical Reports Server (NTRS)
Maxwell, T. A.; Andre, C. G.
1982-01-01
Photogeologic, geochemical and geophysical information is cited to support the contention that an ancient multi-ringed basin exists in the east limb region of the moon, centered at 15 deg S and 70 deg E. The inner ring of the basin, with a diameter of 225 km, is composed of isolated rugged mountains of pre-Nectarian terra; the less distinct outer ring, whose diameter is approximately 450 km, is made up of irregular segments of surrounding large craters. It is noted that two units of light plains material occur in this area and that they are confined for the most part to the region within the proposed outer basin ring. According to orbital geochemical data, the younger unit (Imbrian age plains) consists of a mare basalt not unlike others of the nearside. This unit possesses high Mg/Al concentration ratios as determined from X-ray fluorescence data; it is also relatively high in Th and Fe when compared with the surrounding highlands. It is thought that the relatively high albedo of the Balmer plains may derive from either a reworking by numerous secondary craters from the surrounding impacts or a basaltic composition with higher albedo and lower Fe than the nearside maria.
Thoresen, Todd; Lenz, Martin; Gardel, Margaret L.
2013-01-01
Diverse myosin II isoforms regulate contractility of actomyosin bundles in disparate physiological processes by variations in both motor mechanochemistry and the extent to which motors are clustered into thick filaments. Although the role of mechanochemistry is well appreciated, the extent to which thick filament length regulates actomyosin contractility is unknown. Here, we study the contractility of minimal actomyosin bundles formed in vitro by mixtures of F-actin and thick filaments of nonmuscle, smooth, and skeletal muscle myosin isoforms with varied length. Diverse myosin II isoforms guide the self-organization of distinct contractile units within in vitro bundles with shortening rates similar to those of in vivo myofibrils and stress fibers. The tendency to form contractile units increases with the thick filament length, resulting in a bundle shortening rate proportional to the length of constituent myosin thick filament. We develop a model that describes our data, providing a framework in which to understand how diverse myosin II isoforms regulate the contractile behaviors of disordered actomyosin bundles found in muscle and nonmuscle cells. These experiments provide insight into physiological processes that use dynamic regulation of thick filament length, such as smooth muscle contraction. PMID:23442916
Strong-interaction-mediated critical coupling at two distinct frequencies.
Gupta, S Dutta
2007-06-01
I study a multilayered medium consisting of a metal-dielectric composite film, a spacer layer, and a dielectric Bragg reflector. I demonstrate a greater flexibility over the critical coupling phenomenon [Tischler et al., Opt. Lett. 31, 2045 (2006)], whereby nearly all the incident light energy is absorbed by the composite film through suppression of both transmission and reflection from the structure. For a larger volume fraction of the metal inclusions, strong light-matter coupling is shown to lead to almost total absorption at two distinct frequencies.
21 CFR 102.55 - Nonstandardized breaded composite shrimp units.
Code of Federal Regulations, 2010 CFR
2010-04-01
... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Nonstandardized breaded composite shrimp units. 102.55 Section 102.55 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN... for Specific Nonstandardized Foods § 102.55 Nonstandardized breaded composite shrimp units. (a) The...
21 CFR 165.110 - Bottled water.
Code of Federal Regulations, 2014 CFR
2014-04-01
.... (3) Physical quality. Bottled water shall, when a composite of analytical units of equal volume from.... 1 (4) Chemical quality. (i)(A) Bottled water shall, when a composite of analytical units of equal... bottled water, when a composite of analytical units of equal volume from a sample is examined by the...
Factors affecting marginal integrity of class II bulk-fill composite resin restorations
Savadi Oskoee, Siavash; Bahari, Mahmoud; Jafari Navimipour, Elmira; Ajami, Amir Ahmad; Ghiasvand, Negar; Savadi Oskoee, Ayda
2017-01-01
Background. Bulk-fill composite resins are a new type of resin-based composite resins, claimed to have the capacity to be placed in thick layers, up to 4 mm. This study was carried out to evaluate factors affecting gap formation in Cl II cavities restored using the bulk-fill technique. Methods. A total of 60 third molars were used in this study. Two Cl II cavities were prepared in each tooth, one on the mesial aspect 1 mm coronal to the CEJ and one on the distal aspect 1 mm apical to the CEJ. The teeth were divided into 4 groups: A: The cavities were restored using the bulk-fill technique with Filtek P90 composite resin and its adhesive system and light-cured with quartz tungsten halogen (QTH) light-curing unit. B: The cavities were restored similar to that in group A but light-cured with an LED light-curing unit. C: The cavities were restored using the bulk-fill technique with X-tra Fil composite resin and Clearfil SE Bond adhesive system and light-cured with a QTH curing unit. D: The cavities were restored similar to that in group C but light-cured with an LED light-curing unit. The gaps were examined under a stereomicroscope at ×60. Data were analyzed with General Linear Model test. In cases of statistical significance (P<0.05), post hoc Bonferroni test was used for further analyses. Results. The light-curing unit type had no effect on gap formation. However, the results were significant in relation to the composite resin type and margin location (P<0.001). The cumulative effects of light-curing unit*gingival margin and light-curing unit*composite resin type were not significant; however, the cumulative effect of composite rein type*gingival margin was significant (P=0.04) Conclusion. X-tra Fil composite exhibited smaller gaps compared with Filtek P90 composite with both light-curing units. Both composite resins exhibited smaller gaps at enamel margins. PMID:28748051
NASA Astrophysics Data System (ADS)
Bačík, Peter; Dikej, Jakub; Fridrichová, Jana; Miglierini, Marcel; Števko, Martin
2017-09-01
Tourmaline-supergroup minerals are common gangue minerals in Sb-hydrothermal veins on Betliar - Straková, Čučma - Gabriela and Rožňava - Peter-Pavol vein deposits in the Rožňava area, Slovakia. Tourmaline-supergroup minerals form relatively large prismatic to radial aggregates of parallel black to greyish-black crystals. Tourmaline-supergroup minerals from Betliar - Straková and Rožňava - Peter-Pavol are almost homogeneous with intermediate schorl-dravite composition. Čučma - Gabriela tourmaline have distinct zoning with massive core of the schorlitic-to-feruvitic shifting to schorlitic-to-dravitic composition, and dravitic to magnesio-foititic rim. The tourmaline composition is influenced by two main substitutions, namely Ca(Mg,Fe)Na-1Al-1 and X □AlNa-1(Mg,Fe)-1. Betliar - Straková and Rožňava - Peter-Pavol tourmaline-supergroup minerals exhibit only small extents of the X □AlNa-1(Mg,Fe)-1 substitution. This substitution shifts the composition to magnesio-foitite in Čučma - Gabriela tourmaline. The decrease of Al in the core of Čučma - Gabriela tourmaline crystals is caused by extensive Ca(Mg,Fe)Na-1Al-1 substitution. The unit-cell dimensions of all investigated tourmaline-supergroup minerals indicate an octahedral disorder with the Z (Fe3++Mg) proportion calculated from empirical equations varying between 0.85 and 0.87 apfu (atoms per formula unit). Based on Mössbauer spectra, the Z Fe3+ content varied between 0.25 apfu in Betliar - Straková tourmaline and 0.45 apfu in Čučma - Gabriela sample. Based on Fe/(Fe + Mg) ratio, Betliar - Straková tourmaline is slightly enriched in Fe compared to Rožňava - Peter-Pavol, suggesting the impact of the host-rock composition; first are grown in Fe-richer acidic metarhyolitic rocks, latter in metapelites. In Čučma - Gabriela, the variations in Fe/(Fe + Mg) are very likely reflecting the change in fluid composition. Magnesio-foitite is the product of second-stage crystallization forming rims and crack fills. The relatively low Fe3+/Fe2+ ratio suggests only minor proportion of meteoric fluids forming tourmaline.
Do storage dynamics in hydropedological units control hydrological connectivity? (Invited)
NASA Astrophysics Data System (ADS)
Tetzlaff, D.; Birkel, C.; Dick, J.; Geris, J.; Soulsby, C.
2013-12-01
In many northern landscapes, peat-dominated riparian wetlands often characterise the zone of connection between terrestrial drainage and the river network. In order to understand the relationship between connectivity and stream flow generation in a montane headwater catchment, we examined the storage dynamics and isotopic composition of soil water in major hydropedological units. These formed a classic catena sequence for northern catchments from free-draining podzols on steep upper hillslopes through to peaty gleysols in lower receiving slopes to deeper peats (Histosols) in the riparian zone. The peaty gleys and peats remained saturated throughout the year, whilst the podzols showed distinct wetting and drying cycles. In this climatic region, most precipitation events are less than 10mm in magnitude, storm runoff is mainly generated from the Histosols and Gleysols, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich surface horizons of the soils due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the strongly reflects that of the near surface waters in the riparian peats. Old 'pre-event' water generally accounts for >80% of flow, even in large events, mainly reflecting the displacement of water stored in the riparian peats and peaty gleys. These riparian areas appear to be the dominant zone where different catchment source waters mix; acting as an 'isostat' that regulates the isotopic composition of stream waters and integrates the Transit Time Distribution (TTD) for the catchment.
Speciated Chemical Composition of Biomass Burning Aerosol from Various Fuels during FIREX
NASA Astrophysics Data System (ADS)
Jen, C.; Hatch, L. E.; Kreisberg, N. M.; Selimovic, V.; Yokelson, R. J.; Barsanti, K.; Goldstein, A. H.
2017-12-01
Biomass burning is the largest global source of atmospheric primary carbonaceous aerosols and the second largest global source of non-methane organic compounds, including volatile and semi-volatile organic compounds that are now understood to be major contributors to secondary particle formation in the atmosphere. As wildfires in forested regions such as the western United States become larger and more frequent, understanding the chemical composition of biomass burning organic aerosol is needed to better predict their increasing impact on human health, air quality, and climate. This study presents emission profiles of chemically speciated intermediate and semi-volatile organic compounds present in biomass burning aerosol particles ≤1.0 μm. Biomass burning organic aerosol (BBOA) samples from a variety of fuel types and burning conditions were collected during the FIREX campaign at the USDA Fire Lab (Missoula, MT). Fuels were primarily selected from vegetation commonly found in the western United States, such as ponderosa pine, lodgepole pine, ceanothus, and chaparral. Collected BBOA was thermally desorbed from the filters and analyzed using online derivatization and 2-dimensional gas chromatography with an electron impact (70 eV) and vacuum ultra violet light (10.5 eV) high resolution time of flight mass spectrometer for compound identification. Emission profiles for specific compounds (e.g., levoglucosan) and families of compounds (e.g., sugars and methoxyphenols) show distinct variations between different fuel types, with major differences between fresh and partially decomposed fuels. Results also illustrate the variability in chemical species between burns conducted under similar conditions. Furthermore, chemical fingerprints, representing ratios of normalized emissions for key chemical compounds, were measured for specific fuels/conditions and could be used in future field studies to help identify contributions of various vegetation to total BBOA and in models to estimate the chemical composition of BBOA emissions.
Ajemian, Matthew J.; Jose, Philip D.; Froeschke, John T.; Wildhaber, Mark L.; Stunz, Gregory W.
2016-01-01
Although current assessments of shark population trends involve both fishery-independent and fishery-dependent data, the latter are generally limited to commercial landings that may neglect nearshore coastal habitats. Texas has supported the longest organized land-based recreational shark fishery in the United States, yet no studies have used this “non-traditional” data source to characterize the catch composition or trends in this multidecadal fishery. We analyzed catch records from two distinct periods straddling heavy commercial exploitation of sharks in the Gulf of Mexico (historical period = 1973–1986; modern period = 2008–2015) to highlight and make available the current status and historical trends in Texas’ land-based shark fishery. Catch records describing large coastal species (>1,800 mm stretched total length [STL]) were examined using multivariate techniques to assess catch seasonality and potential temporal shifts in species composition. These fishery-dependent data revealed consistent seasonality that was independent of the data set examined, although distinct shark assemblages were evident between the two periods. Similarity percentage analysis suggested decreased contributions of Lemon Shark Negaprion brevirostris over time and a general shift toward the dominance of Bull Shark Carcharhinus leucas and Blacktip Shark C. limbatus. Comparisons of mean STL for species captured in historical and modern periods further identified significant decreases for both Bull Sharks and Lemon Sharks. Size structure analysis showed a distinct paucity of landed individuals over 2,000 mm STL in recent years. Although inherent biases in reporting and potential gear-related inconsistencies undoubtedly influenced this fishery-dependent data set, the patterns in our findings documented potential declines in the size and occurrence of select large coastal shark species off Texas, consistent with declines reported in the Gulf of Mexico. Future management efforts should consider the use of non-traditional fishery-dependent data sources, such as land-based records, as data streams in stock assessments.
Earth science: Extraordinary world
NASA Astrophysics Data System (ADS)
Day, James M. D.
2016-09-01
The isotopic compositions of objects that formed early in the evolution of the Solar System have been found to be similar to Earth's composition -- overturning notions of our planet's chemical distinctiveness. See Letters p.394 & p.399
21 CFR 102.55 - Nonstandardized breaded composite shrimp units.
Code of Federal Regulations, 2011 CFR
2011-04-01
... 21 Food and Drugs 2 2011-04-01 2011-04-01 false Nonstandardized breaded composite shrimp units... for Specific Nonstandardized Foods § 102.55 Nonstandardized breaded composite shrimp units. (a) The... described by § 161.175(c)(6) of this chapter, except that the food is made from comminuted shrimp and is not...
NASA Astrophysics Data System (ADS)
Christiansen, E. H.; McCurry, M. O.; Champion, D. E.; Bolte, T.; Holtz, F.; Knott, T.; Branney, M. J.; Shervais, J. W.
2013-12-01
The rhyolites on the track of the Yellowstone hotspot are the classic examples of continental hotspot volcanism and the study of surface outcrops is maturing rapidly. However, in the central part of the track, where silicic volcanism is most voluminous, compositionally distinctive, and isotopically most anomalous, study of these large magma systems has been hindered because eruptive sources are buried. The 2 km Kimberly core helps fill that gap; it penetrates through surficial basalt, deep into the rhyolitic underpinnings on the southern margin of the province. The Kimberly core is dominated by thick sections of rhyolite lava and welded ignimbrite, with basalt-sediment intercalations between 241 m and 424 m depth. We tentatively interpret the core to include a thick intracaldera tuff. Our preliminary studies suggest that there are three major rhyolite units in the core. Rhyolite 3, the uppermost unit, is a nearly 130 m thick, low-silica rhyolite lava. Rhyolite 2 is the most highly evolved with ~75% silica and distinctively resorbed quartz. Rhyolite 1 is at least 1,340 m thick (the base was not cut by the core), has no apparent flow contacts or cooling breaks, and may represent a single, thick intracaldera ignimbrite. Paleomagnetic inclinations form a curious V-shaped profile, shallowing by about 18○ between 700 and 1700 m depth. We interpret this to be the result of slower cooling of the mid-part of the thick intracaldera ignimbrite. The lower unit is a low-silica rhyolite with high concentrations of Fe2O3 and TiO2--among the highest of any known ignimbrite on the SRP. It is chemically distinct from the upper units, very homogeneous, not vertically zoned, and lacks multiple populations of phenocrysts. It somewhat resembles the regionally extensive ~10 Ma outflow tuff of Wooden Shoe Butte. However, this is one of several large, petrologically similar ignimbrites as young as 8.6 Ma exposed in the Cassia Mountains south of the hole, so further work is needed. Like most rhyolites from the Snake River Plain, all 3 units have the characteristics of A-type rhyolites with high concentrations of alkalies, high Fe/Mg and TiO2/MgO ratios, as well as high concentrations Nb, Y, Zr and Ga. Initial analyses of plag, cpx, and qtz show that all three units are low δ18O rhyolites, like most from the Central Snake River Plain-- δ18O in feldspar ranges from 1‰ in Rhyolite 1 to 3‰ in Rhyolites 2 and 3. In the thick lower ignimbrite, whole-rock δ18O increases systematically from the base upward (0.5‰ to as much as 9‰ in the altered top and δD ranges from -140 to -180‰). Whole rock variations correlate with water content, apparently controlled by secondary clay. We suggest that these characteristics were largely imposed by their derivation from partial melting of basaltic sills and surrounding older crust. The low δ18O values reflect recycling of hydrothermally altered crustal rocks and indicate progressive incorporation of more hydrothermally altered material into the younger magmas. More work is needed to establish correlation with regional units, understand the emplacement of the rhyolites and their volcanic setting, and ascertain the origin of these distinctive low δ18O, A-type rhyolites.
NASA Technical Reports Server (NTRS)
Bleamaster, Leslie F., III; Crown, David A.
2008-01-01
Geologic mapping studies at the 1:1M-scale will be used to characterize geologic processes that have shaped the highlands along the Arabia Terra dichotomy boundary. In particular, this mapping will evaluate the distribution, stratigraphic position, and lateral continuity of compositionally distinct outcrops in Mawrth Vallis and Nili Fossae as identified by spectral instruments currently in orbit. Placing these landscapes, their material units, structural features, and unique compositional outcrops into spatial and temporal context with the remainder of the Arabia Terra dichotomy boundary will provide the ability to: 1) further test original dichotomy formation hypotheses, 2) constrain ancient paleoenvironments and climate conditions, and 3) evaluate various fluvial-nival modification processes related to past and present volatile distribution and their putative reservoirs (aquifers, lakes and oceans, surface and ground ice) and the influences of nearby volcanic and tectonic features on hydrologic processes in these regions. The result will be two 1:1M scale geologic maps of twelve MTM quadrangles (Mawrth Vallis - 20022, 20017, 20012, 25022, 25017, and 25012; and Nili Fossae - 20287, 20282, 25287, 25282, 30287, 30282).
Geologic Mapping along the Arabia Terra Dichotomy Boundary: Mawrth Vallis and Nili Fossae, Mars
NASA Technical Reports Server (NTRS)
Bleamaster, Leslie F., III; Crown, David A.
2009-01-01
Geologic mapping studies at the 1:1M-scale are being used to assess geologic materials and processes that shape the highlands along the Arabia Terra dichotomy boundary. In particular, this mapping will evaluate the distribution, stratigraphic position, and lateral continuity of compositionally distinct outcrops in Mawrth Vallis and Nili Fossae as identified by spectral instruments currently in orbit. Placing these landscapes, their material units, structural features, and unique compositional outcrops into spatial and temporal context with the remainder of the Arabia Terra dichotomy boundary may provide constraints on: 1) origin of the dichotomy boundary, 2) paleo-environments and climate conditions, and 3) various fluvial-nival modification processes related to past and present volatile distribution and their putative reservoirs (aquifers, lakes and oceans, surface and ground ice) and the influences of nearby volcanic and tectonic features on hydrologic processes in these regions. The results of this work will include two 1:1M scale geologic maps of twelve MTM quadrangles (Mawrth Vallis - 20022, 20017, 20012, 25022, 25017, and 25012; and Nili Fossae - 20287, 20282, 25287, 25282, 30287, 30282).
Origin of hybrid ferrolatite lavas from Magic Reservoir eruptive center, Snake River Plain, Idaho
NASA Astrophysics Data System (ADS)
Honjo, Norio; Leeman, William P.
1987-06-01
The mineralogy and geochemical characteristics of intermediate composition ferrolatites and related lavas from the Magic Reservoir eruptive center (central Snake River Plain) have been investigated to evaluate the origin and petrologic significance of these hybrid lavas. The ferrolatites are chemically uniform, but contain a disequilibrium phenocryst/xenocryst assemblage derived in part from mixed rhyolitic and basaltic magmas that are closely represented by extrusive units in the area. The hybrid lavas also contain xenoliths of Archean granulites and have high 87Sr/ 86Sr and low 143Nd/144Nd ratios, all of which suggest significant magma-crust interaction. Quantitative models including magma mixing, minor crystal fractionation, and crustal contamination very closely reproduce the observed compositions of these ferrolatites; closed system fractionation and (or) simple bulk contamination models are not as successful and can be ruled out. It appears that preexisting mafic and silicic magmas from distinct sources (e.g., mantle and crust) encounter one another in crustal-level magma chambers under conditions where intimate mixing may occur despite wide differences in the physical properties of these liquids.
Boyle, Diane K; Jayawardhana, Ananda; Burman, Mary E; Dunton, Nancy E; Staggs, Vincent S; Bergquist-Beringer, Sandra; Gajewski, Byron J
2016-11-01
Composite indices are single measures that combine the strengths of two or more individual measures and provide broader, easy-to-use measures for evaluation of provider performance and comparisons across units and hospitals to support quality improvement. The study objective was to develop a unit-level inpatient composite nursing care quality performance index-the Pressure Ulcer and Fall Rate Quality Composite Index. Two-phase measure development study. 5144 patient care units in 857 United States hospitals participating in the National Database of Nursing Quality Indictors ® during the year 2013. The Pressure Ulcer and Fall Rate Quality Composite Index was developed in two phases. In Phase 1 the formula was generated using a utility function and generalized penalty analysis. Experts with experience in healthcare quality measurement provided the point of indicator equivalence. In Phase 2 initial validity evidence was gathered based on hypothesized relationships between the Pressure Ulcer and Fall Rate Quality Composite Index and other variables using two-level (unit, hospital) hierarchical linear mixed modeling. The Pressure Ulcer and Fall Rate Quality Composite Index=100-PUR-FR, where PUR is pressure ulcer rate and FR is total fall rate. Higher scores indicate better quality. Bland-Altman plots demonstrated agreement between pairs of experts and provided evidence for inter-rater reliability of the formula. The validation process demonstrated that higher registered nurse skill mix, higher percent of registered nurses with a baccalaureate in nursing or higher degree, higher percent of registered nurses with national specialty certification, and lower percent of hours supplied by agency staff were significantly associated with higher Pressure Ulcer and Fall Rate Quality Composite Index scores. Higher percentages of unit patients at risk for a hospital-acquired pressure ulcer and higher unit rates of physical restraint use were not associated with higher Pressure Ulcer and Fall Rate Quality Composite Index scores. The Pressure Ulcer and Fall Rate Quality Composite Index is a step toward providing a more holistic perspective of unit level nursing quality than individual measures and may help nurses nursing administrators obtain a broader view of which patient care units are the higher and lower performers. Further study is needed to examine the usability of the Pressure Ulcer and Fall Rate Quality Composite Index. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.
Jayawardhana, Ananda; Burman, Mary E.; Dunton, Nancy E.; Staggs, Vincent S.; Bergquist-Beringer, Sandra; Gajewski, Byron J.
2016-01-01
Background Composite indices are single measures that combine the strengths of two or more individual measures and provide broader, easy-to-use measures for evaluation of provider performance and comparisons across units and hospitals to support quality improvement. Objective The study objective was to develop a unit-level inpatient composite nursing care quality performance index – the Pressure Ulcer and Fall Rate Quality Composite Index. Design Two-phase measure development study. Settings 5,144 patient care units in 857 United States hospitals participating in the National Database of Nursing Quality Indictors® during the year 2013. Methods The Pressure Ulcer and Fall Rate Quality Composite Index was developed in two phases. In Phase 1 the formula was generated using a utility function and generalized penalty analysis. Experts with experience in healthcare quality measurement provided the point of indicator equivalence. In Phase 2 initial validity evidence was gathered based on hypothesized relationships between the Pressure Ulcer and Fall Rate Quality Composite Index and other variables using two-level (unit, hospital) hierarchical linear mixed modeling. Results The Pressure Ulcer and Fall Rate Quality Composite Index = 100 − PUR − FR, where PUR is pressure ulcer rate and FR is total fall rate. Higher scores indicate better quality. Bland-Altman plots demonstrated agreement between pairs of experts and provided evidence for inter-rater reliability of the formula. The validation process demonstrated that higher registered nurse skill mix, higher percent of registered nurses with a baccalaureate in nursing or higher degree, higher percent of registered nurses with national specialty certification, and lower percent of hours supplied by agency staff were significantly associated with higher Pressure Ulcer and Fall Rate Quality Composite Index scores. Higher percentages of unit patients at risk for a hospital-acquired pressure ulcer and higher unit rates of physical restraint use were not associated with higher Pressure Ulcer and Fall Rate Quality Composite Index scores. Conclusions The Pressure Ulcer and Fall Rate Quality Composite Index is a step toward providing a more holistic perspective of unit level nursing quality than individual measures and may help nurses nursing administrators obtain a broader view of which patient care units are the higher and lower performers. Further study is needed to examine the usability of the Pressure Ulcer and Fall Rate Quality Composite Index. PMID:27607602
2016-09-01
investigated. The unitized composite consisted of a polymer matrix composite (PMC) co-cured with a ceramic matrix composite (CMC). The PMC portion...ply non- crimp 3D orthogonal weave composite consisting of a ceramic matrix reinforced with glass fibers. In order to assess the performance and...2.3 Ceramic Matrix Composites ...................................................................................5 2.4 2D vs 3D Reinforcement
Anthropogenic Litter in Urban Freshwater Ecosystems: Distribution and Microbial Interactions
Hoellein, Timothy; Rojas, Miguel; Pink, Adam; Gasior, Joseph; Kelly, John
2014-01-01
Accumulation of anthropogenic litter (i.e. garbage; AL) and its ecosystem effects in marine environments are well documented. Rivers receive AL from terrestrial habitats and represent a major source of AL to marine environments, but AL is rarely studied within freshwater ecosystems. Our objectives were to 1) quantify AL density in urban freshwaters, 2) compare AL abundance among freshwater, terrestrial, and marine ecosystems, and 3) characterize the activity and composition of AL biofilms in freshwater habitats. We quantified AL from the Chicago River and Chicago's Lake Michigan shoreline, and found that AL abundance in Chicago freshwater ecosystems was comparable to previously reported data for marine and terrestrial ecosystems, although AL density and composition differed among habitats. To assess microbial interactions with AL, we incubated AL and natural substrates in 3 freshwater ecosystems, quantified biofilm metabolism as gross primary production (GPP) and community respiration (CR), and characterized biofilm bacterial community composition via high-throughput sequencing of 16S rRNA genes. The main driver of biofilm community composition was incubation location (e.g., river vs pond), but there were some significant differences in biofilm composition and metabolism among substrates. For example, biofilms on organic substrates (cardboard and leaves) had lower GPP than hard substrates (glass, plastic, aluminum and tiles). In addition, bacterial communities on organic substrates were distinct in composition from those on hard substrates, with higher relative abundances of bacteria associated with cellulose decomposition. Finally, we used our results to develop a conceptual diagram designed to unite the study of AL in terrestrial and freshwater environments with the well-established field of marine debris research. We suggest this broad perspective will be useful for future studies which synthesize AL sources, ecosystem effects, and fate across multiple ecosystem types, and will benefit management and reduction of global AL accumulations. PMID:24955768
Anthropogenic litter in urban freshwater ecosystems: distribution and microbial interactions.
Hoellein, Timothy; Rojas, Miguel; Pink, Adam; Gasior, Joseph; Kelly, John
2014-01-01
Accumulation of anthropogenic litter (i.e. garbage; AL) and its ecosystem effects in marine environments are well documented. Rivers receive AL from terrestrial habitats and represent a major source of AL to marine environments, but AL is rarely studied within freshwater ecosystems. Our objectives were to 1) quantify AL density in urban freshwaters, 2) compare AL abundance among freshwater, terrestrial, and marine ecosystems, and 3) characterize the activity and composition of AL biofilms in freshwater habitats. We quantified AL from the Chicago River and Chicago's Lake Michigan shoreline, and found that AL abundance in Chicago freshwater ecosystems was comparable to previously reported data for marine and terrestrial ecosystems, although AL density and composition differed among habitats. To assess microbial interactions with AL, we incubated AL and natural substrates in 3 freshwater ecosystems, quantified biofilm metabolism as gross primary production (GPP) and community respiration (CR), and characterized biofilm bacterial community composition via high-throughput sequencing of 16S rRNA genes. The main driver of biofilm community composition was incubation location (e.g., river vs pond), but there were some significant differences in biofilm composition and metabolism among substrates. For example, biofilms on organic substrates (cardboard and leaves) had lower GPP than hard substrates (glass, plastic, aluminum and tiles). In addition, bacterial communities on organic substrates were distinct in composition from those on hard substrates, with higher relative abundances of bacteria associated with cellulose decomposition. Finally, we used our results to develop a conceptual diagram designed to unite the study of AL in terrestrial and freshwater environments with the well-established field of marine debris research. We suggest this broad perspective will be useful for future studies which synthesize AL sources, ecosystem effects, and fate across multiple ecosystem types, and will benefit management and reduction of global AL accumulations.
NASA Technical Reports Server (NTRS)
Rosner, D. E.; Nagarajan, R.
1985-01-01
Partial heterogeneous condensation phenomena in multicomponent reacting systems are analyzed taking into consideration the chemical element transport phenomena. It is demonstrated that the dew-point surface temperature in chemically reactive systems is not a purely thermodynamic quantity, but is influenced by the multicomponent diffusion and Soret-mass diffusion phenomena. Several distinct dew-points are shown to exist in such systems and, as a result of transport constraints, the 'sharp' locus between two chemically distinct condensates is systematically moved to a difference mainstream composition.
Choo, Jocelyn M; Kanno, Tokuwa; Zain, Nur Masirah Mohd; Leong, Lex E X; Abell, Guy C J; Keeble, Julie E; Bruce, Kenneth D; Mason, A James; Rogers, Geraint B
2017-01-01
The intestinal microbiome plays an essential role in regulating many aspects of host physiology, and its disruption through antibiotic exposure has been implicated in the development of a range of serious pathologies. The complex metabolic relationships that exist between members of the intestinal microbiota and the potential redundancy in functional pathways mean that an integrative analysis of changes in both structure and function are needed to understand the impact of antibiotic exposure. We used a combination of next-generation sequencing and nuclear magnetic resonance (NMR) metabolomics to characterize the effects of two clinically important antibiotic treatments, ciprofloxacin and vancomycin-imipenem, on the intestinal microbiomes of female C57BL/6 mice. This assessment was performed longitudinally and encompassed both antibiotic challenge and subsequent microbiome reestablishment. Both antibiotic treatments significantly altered the microbiota and metabolite compositions of fecal pellets during challenge and recovery. Spearman's correlation analysis of microbiota and NMR data revealed that, while some metabolites could be correlated with individual operational taxonomic units (OTUs), frequently multiple OTUs were associated with a significant change in a given metabolite. Furthermore, one metabolite, arginine, can be associated with increases/decreases in different sets of OTUs under differing conditions. Taken together, these findings indicate that reliance on shifts in one data set alone will generate an incomplete picture of the functional effect of antibiotic intervention. A full mechanistic understanding will require knowledge of the baseline microbiota composition, combined with both a comparison and an integration of microbiota, metabolomics, and phenotypic data. IMPORTANCE Despite the fundamental importance of antibiotic therapies to human health, their functional impact on the intestinal microbiome and its subsequent ability to recover are poorly understood. Much research in this area has focused on changes in microbiota composition, despite the interdependency and overlapping functions of many members of the microbial community. These relationships make prediction of the functional impact of microbiota-level changes difficult, while analyses based on the metabolome alone provide relatively little insight into the taxon-level changes that underpin changes in metabolite levels. Here, we used combined microbiota and metabolome profiling to characterize changes associated with clinically important antibiotic combinations with distinct effects on the gut. Correlation analysis of changes in the metabolome and microbiota indicate that a combined approach will be essential for a mechanistic understanding of the functional impact of distinct antibiotic classes.
NASA Astrophysics Data System (ADS)
Go, S. Y.; Kim, G. B.; Jeong, J. O.; Sohn, Y. K.
2017-03-01
The Songaksan tuff ring, Jeju Island, Korea, which erupted ca. 3.7 ka BP in a coastal setting, provides an unusual opportunity to study the processes of phreatomagmatic eruption and the formation of a diatreme because of the exceptionally well-preserved ejecta beds and well-known subsurface geology. The tuff sequence can be divided into four units (A to D), which have distinctly different accidental componentry (quartz-rich vs. quartz-poor), grain surface features (abraded and ash-coated vs. unabraded and uncoated), and chemical compositions of juvenile particles. The basal tephra bed of unit A, which probably erupted after the removal of the relatively hard shallow-level (<120 m deep) substrate by initial cratering, comprises only unabraded and uncoated grains and contains abundant relatively deep-derived (>120 m deep) accidental grains, suggesting that the early erupted tephra had not yet experienced recycling and pre-eruption mixing in the diatreme. On the other hand, the overlying tephra beds of units A, B, and D contain an abundance of abraded and ash-coated juvenile/accidental grains, suggesting that the tephra comprised significant proportions of "recycled" or "premixed" materials from previous eruptions or subsurface explosions, which participated in the explosion-driven mixing in the diatreme before eventual ejection from the diatreme. Unit C is unusual in that it comprises extremely rare accidental grains and ash-coated juvenile/accidental grains. We interpret that the supply of solid materials, either accidental or juvenile, to the diatreme was greatly reduced because of temporary stabilization of the diatreme and the reduction in magma flux to the diatreme. The diatreme is therefore envisaged to have been filled with a water-saturated slurry, in which particle abrasion and adhesion were inhibited. We also infer that the diatreme fill was temporarily removed by a powerful explosion before eruption of unit C on the basis of the near absence of the tephra grains from earlier eruptions throughout the tephra beds of unit C. The ratio of tachylite to sideromelane grains generally increases up-section of the tuff sequence with two abrupt drops across the tuff unit boundaries. These variations are coincident with the changes in the chemical composition of juvenile particles, suggesting an overall decrease in magma flux punctuated by brief increases in magma flux associated with the arrival of new magma batches. The textural and compositional variations of the Songaksan tuff ring suggest that there can be significant variability in diatreme processes even during a purely phreatomagmatic eruption of a tuff ring, including removal and renewal of the diatreme fill, and that there is still much room for further investigation of the diatreme processes from the ejecta beds in order to make the current diatreme model more robust.
SilMush: A procedure for modeling of the geochemical evolution of silicic magmas and granitic rocks
NASA Astrophysics Data System (ADS)
Hertogen, Jan; Mareels, Joyce
2016-07-01
A boundary layer crystallization modeling program is presented that specifically addresses the chemical fractionation in silicic magma systems and the solidification of plutonic bodies. The model is a Langmuir (1989) type approach and does not invoke crystal settling in high-viscosity silicic melts. The primary aim is to model a granitic rock as a congealed crystal-liquid mush, and to integrate major element and trace element modeling. The procedure allows for some exploratory investigation of the exsolution of H2O-fluids and of the fluid/melt partitioning of trace elements. The procedure is implemented as a collection of subroutines for the MS Excel spreadsheet environment and is coded in the Visual Basic for Applications (VBA) language. To increase the flexibility of the modeling, the procedure is based on discrete numeric process simulation rather than on solution of continuous differential equations. The program is applied to a study of the geochemical variation within and among three granitic units (Senones, Natzwiller, Kagenfels) from the Variscan Northern Vosges Massif, France. The three units cover the compositional range from monzogranite, over syenogranite to alkali-feldspar granite. An extensive set of new major element and trace element data is presented. Special attention is paid to the essential role of accessory minerals in the fractionation of the Rare Earth Elements. The crystallization model is able to reproduce the essential major and trace element variation trends in the data sets of the three separate granitic plutons. The Kagenfels alkali-feldspar leucogranite couples very limited variation in major element composition to a considerable and complex variation of trace elements. The modeling results can serve as a guide for the reconstruction of the emplacement sequence of petrographically distinct units. Although the modeling procedure essentially deals with geochemical fractionation within a single pluton, the modeling results bring up a number of questions about the petrogenetic relationships among parental magmas of nearly coeval granitic units emplaced in close proximity.
NASA Technical Reports Server (NTRS)
Loss, R. D.; Lugmair, G. W.; Davis, A. M.; Macpherson, G. J.
1994-01-01
The isotopic compositions of Mg, Ca, Ti, Cr, Zn, Sr, Ba, Nd, and Sm were measured in four relatively unaltered refractory inclusions from the Vigarano carbonaceous chondrite meteorite. Three of the inclusions (USNM 1623-2, 1623-3, and 1623-8) show similar Mg, Ca, Ti, and Cr isotopic compositions to those found in most inclusions in the Allende carbonaceous chondrite. This indicates that these Vigarano inclusions sampled the same isotopic reservoirs as the majority of the Allende inclusions that isotope signatures in the latter were not significantly modified by the secondary alteration that permeates most Allende inclusions. In contrast, inclusion 1623-5 has large deficits in Mg-26, Ca-48, and Ti-50 and small but distinct Cr-54, Zn-66, Sr-84, Ba-135, Ba-137, and Sm-144 anomalies. The magnitudes of these unusual anomalies in the refractory elements are within analytical uncertainty of those found in the Allende 'FUN" inclusion C1, yet 1623-5 has a very different bulk chemical composition from C1. The fact that 1623-5 and C1 have identical isotopic anomalies yet have significantly distinct major and trace element contents provide convincing evidence for the presence of isotopically distinct reservoirs in the early solar system.
NASA Astrophysics Data System (ADS)
Irwin, Rossman P.; Tanaka, Kenneth L.; Robbins, Stuart J.
2013-02-01
Most of the geomorphic changes on Mars occurred during the Noachian Period, when the rates of impact crater degradation and valley network incision were highest. Fluvial erosion around the Noachian/Hesperian transition is better constrained than the longer-term landscape evolution throughout the Noachian Period, when the highland intercrater geomorphic surfaces developed. We interpret highland resurfacing events and processes using a new global geologic map of Mars (at 1:20,000,000 scale), a crater data set that is complete down to 1 km in diameter, and Mars Orbiter Laser Altimeter topography. The Early Noachian highland (eNh) unit is nearly saturated with craters of 32-128 km diameter, the Middle Noachian highland (mNh) unit has a resurfacing age of ~4 Ga, and the Late Noachian highland unit (lNh) includes younger composite surfaces of basin fill and partially buried cratered terrain. These units have statistically distinct ages, and their distribution varies with elevation. The eNh unit is concentrated in the high-standing Hellas basin annulus and in highland terrain that was thinly mantled by basin ejecta near 180° longitude. The mNh unit includes most of Arabia Terra, the Argyre vicinity, highland plateau areas between eNh outcrops, and the Thaumasia range. The lNh unit mostly occurs within highland basins. Crater depth/diameter ratios do not vary strongly between the eNh and mNh units, although crater losses to Noachian resurfacing appear greater in lower lying areas. Noachian resurfacing was spatially non-uniform, long-lived, and gravity-driven, more consistent with arid-zone fluvial and aeolian erosion and volcanism than with air fall mantling or mass wasting.
Moss, C W; Wallace, P L; Hollis, D G; Weaver, R E
1988-03-01
We determined phenotypic characteristics, cellular fatty acid composition, and isoprenoid quinone content of representative strains of CDC groups EO-2, M-5, and M-6, Moraxella (Moraxella) species, Oligella urethralis, Acinetobacter species, and Psychrobacter immobilis. All organisms contained ubiquinone with eight isoprene units as the major isoprenolog, but distinct differences were observed in fatty acid composition. Twenty-eight of the original collection of CDC group EO-2 strains were further identified as P. immobilis, EO-2, or EO-3 by distinctive cellular fatty acid profiles, cellular morphology, and pigment production. The cellular fatty acid compositions of M-5 and M-6 were similar but were clearly different from those of other organisms. The genus Acinetobacter was differentiated from other organisms in the study by small amounts of 2-hydroxydodecanoic acid (2-OH-12:0), and P. immobilis was differentiated by small amounts of decanoic acid (10:0) and a branched-chain 17-carbon acid (i-17:0). All Moraxella species were distinguished by small amounts of decanoic acid (10:0) and the absence of i-17:0. M. bovis, M. nonliquefaciens, and some strains of M. lacunata formed a single fatty acid group, while M. osloensis, M. phenylpyruvica, M. atlantae, and other strains of M. lacunata (M. lacunata II) had species-specific fatty acid profiles. O. urethralis differed from Moraxella species by the presence of large amounts (49%) of cis-vaccenic acid (18:1 omega 7c), small amounts (1%) of 3-hydroxyhexadecanoate (3-OH-16:0), and the absence of 10:0 and 3-hydroxydodecanoate (3-OH-12:0). The combined use of chemical data and a small number of conventional tests permitted rapid identification and differentiation of these organisms from each other and from related organisms.
Moss, C W; Wallace, P L; Hollis, D G; Weaver, R E
1988-01-01
We determined phenotypic characteristics, cellular fatty acid composition, and isoprenoid quinone content of representative strains of CDC groups EO-2, M-5, and M-6, Moraxella (Moraxella) species, Oligella urethralis, Acinetobacter species, and Psychrobacter immobilis. All organisms contained ubiquinone with eight isoprene units as the major isoprenolog, but distinct differences were observed in fatty acid composition. Twenty-eight of the original collection of CDC group EO-2 strains were further identified as P. immobilis, EO-2, or EO-3 by distinctive cellular fatty acid profiles, cellular morphology, and pigment production. The cellular fatty acid compositions of M-5 and M-6 were similar but were clearly different from those of other organisms. The genus Acinetobacter was differentiated from other organisms in the study by small amounts of 2-hydroxydodecanoic acid (2-OH-12:0), and P. immobilis was differentiated by small amounts of decanoic acid (10:0) and a branched-chain 17-carbon acid (i-17:0). All Moraxella species were distinguished by small amounts of decanoic acid (10:0) and the absence of i-17:0. M. bovis, M. nonliquefaciens, and some strains of M. lacunata formed a single fatty acid group, while M. osloensis, M. phenylpyruvica, M. atlantae, and other strains of M. lacunata (M. lacunata II) had species-specific fatty acid profiles. O. urethralis differed from Moraxella species by the presence of large amounts (49%) of cis-vaccenic acid (18:1 omega 7c), small amounts (1%) of 3-hydroxyhexadecanoate (3-OH-16:0), and the absence of 10:0 and 3-hydroxydodecanoate (3-OH-12:0). The combined use of chemical data and a small number of conventional tests permitted rapid identification and differentiation of these organisms from each other and from related organisms. Images PMID:3356788
Coombs, D.S.; Alberti, A.; Armbruster, T.; Artioli, G.; Colella, C.; Galli, E.; Grice, Joel D.; Liebau, F.; Mandarino, J.A.; Minato, H.; Nickel, E.H.; Passaglia, E.; Peacor, D.R.; Quartieri, S.; Rinaldi, R.; Ross, M.; Sheppard, R.A.; Tillmanns, E.; Vezzalini, G.
1998-01-01
This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association Commission of New Minerals and Mineral Names. In a working definition of a zeolite mineral used for review, interrupted tetrahedral framework structures are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is allowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundance in atomic proportions. To name these, the appropriate chemical symbol is attached by a hyphen to the series name as a suffix except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely on Si:Al ratio except for heulandite (Si:Al < 4.0) and clinoptilolite (Si:Al ??? 4.0). Dehydration, partial hydration, and over-hydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of a zeolite. Newly recognized species in compositional series are as follows: brewsterite-Sr.-Ba: chabazite-Ca.-Na.-K; clinoptilolite-K, -Na, -Ca: dachiardite-Ca, -Na; erionite-K, -Ca: faujasite-Na, -Ca, -Na: paulingite-K. -Ca; phillipsite-Na, -Ca, -Ka; stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data. IZA structure-type symbols, space-group symmetry; unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, svetlozarite, and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.
NASA Technical Reports Server (NTRS)
Tosi, F.; Frigeri, A.; Combe, J.-Ph.; Zambon, F.; De Sanctis, M. C.; Ammannito, E.; Longobardo, A.; Hoffmann, M.; Nathues, A.; Garry, W. B.;
2015-01-01
Quadrangle Av-10 'Oppia' is one of five quadrangles that cover the equatorial region of asteroid (4) Vesta. This quadrangle is notable for the broad, spectrally distinct ejecta that extend south of the Oppia crater. These ejecta exhibit the steepest ('reddest') visible spectral slope observed across the asteroid and have distinct color properties as seen in multispectral composite images. Compared to previous works that focused on the composition and nature of unusual ('orange') ejecta found on Vesta, here we take into account a broader area that includes several features of interest, with an emphasis on mineralogy as inferred from data obtained by Dawn's Visible InfraRed mapping spectrometer (VIR). Our analysis shows that the older northern and northeastern part of Av-10 is dominated by howardite-like material, while the younger southwestern part, including Oppia and its ejecta blanket, has a markedly eucritic mineralogy. The association of the mineralogical information with the geologic and topographic contexts allows for the establishment of relationships between the age of the main formations observed in this quadrangle and their composition. A major point of interest in the Oppia quadrangle is the spectral signature of hydrous material seen at the local scale. This material can be mapped by using high-resolution VIR data, combined with multispectral image products from the Dawn Framing Camera (FC) so as to enable a clear correlation with specific geologic features. Hydrated mineral phases studied previously on Vesta generally correlate with low-albedo material delivered by carbonaceous asteroids. However, our analysis shows that the strongest OH signature in Av-10 is found in a unit west of Oppia, previously mapped as 'light mantle material' and showing moderate reflectance and a red visible slope. With the available data we cannot yet assess the presence of water in this material. However, we offer a possible explanation for its origin.
Thermally crosslinked polymeric compositions and methods of making the same
DOE Office of Scientific and Technical Information (OSTI.GOV)
Koros, William John; Kratochvil, Adam Michal
2014-03-04
The various embodiments of the present disclosure relate generally to thermally crosslinked polymeric compositions and methods of making thermally crosslinked polymeric compositions. An embodiment of the present invention comprises a composition comprising: a first polymer comprising a first repeat unit, the first repeat unit comprising a carboxyl group, wherein the first polymer crosslinks to a second polymer formed from a second repeat unit, and wherein the first polymer crosslinks to the second polymer without formation of an ester group.
Eichorst, Stephanie A.
2012-01-01
Many bacteria and fungi are known to degrade cellulose in culture, but their combined response to cellulose in different soils is unknown. Replicate soil microcosms amended with [13C]cellulose were used to identify bacterial and fungal communities responsive to cellulose in five geographically and edaphically different soils. The diversity and composition of the cellulose-responsive communities were assessed by DNA-stable isotope probing combined with Sanger sequencing of small-subunit and large-subunit rRNA genes for the bacterial and fungal communities, respectively. In each soil, the 13C-enriched, cellulose-responsive communities were of distinct composition compared to the original soil community or 12C-nonenriched communities. The composition of cellulose-responsive taxa, as identified by sequence operational taxonomic unit (OTU) similarity, differed in each soil. When OTUs were grouped at the bacterial order level, we found that members of the Burkholderiales, Caulobacteriales, Rhizobiales, Sphingobacteriales, Xanthomonadales, and the subdivision 1 Acidobacteria were prevalent in the 13C-enriched DNA in at least three of the soils. The cellulose-responsive fungi were identified as members of the Trichocladium, Chaetomium, Dactylaria, and Arthrobotrys genera, along with two novel Ascomycota clusters, unique to one soil. Although similarities were identified in higher-level taxa among some soils, the composition of cellulose-responsive bacteria and fungi was generally unique to a certain soil type, suggesting a strong potential influence of multiple edaphic factors in shaping the community. PMID:22287013
NASA Astrophysics Data System (ADS)
Roethe, T.; Bakke, J.; Støren, E.
2016-12-01
Here we present work in progress from Buarvatnet at the Folgefonn Peninsula, located on the west coast of Norway. Earlier work from Buarvatnet indicated several distinct spikes in the Silica count rates, detected by the ITRAX surface XRF-scanner. However, the process behind these distinct spikes was not understood. The arrival of high-resolution and innovative instruments at EARTHLAB, in particular the computed tomography (CT) scanner and grain Morphometer, have the potential to get a process-based understanding of these distinct layers and unravel the frequency and timing of such events. Multiple sediment cores were retrieved using a modified piston corer and a Uwitech corer from Buarvatnet. The sediments have been analysed using a multi-proxy approach and the analyses included magnetic properties, loss-on-ignition, dry bulk density, grain size/shape, geochemical analysis (XRF scanning) and CT-scanning. Accurate age-control will be achieved through 210Pb dating of the top-most sediments and 14C dating of terrestrial macrofossils. The lithostratigraphy of the 3.6 m long master sediment core from Buarvatnet is divided into three distinct units. The lower most unit ( 87 cm) is massive with fine-grained greyish sediments, most likely representing the deglaciation of the area. A 224 cm long unit is found above, characterised as dark brown gyttja with multiple thin layers (sub-mm to cm thick) of fine grained sediments. Also in this unit is two distinct sub-units showing a finer upwards sequence. At top, a gradual transition from dark brown gyttja to grey fine-grained sediments is found in the upper-most 19 cm of the sediment core. In total 16 distinct layers is found in the gyttja sequence, including the two sub-units, based on the lithostratigraphy and the prelimnary results from the magnetic, physical and geochemical properties. A preliminary hypothesis is that these distinct layers are due to outburst floods from a glacier-dammed lake upstream from Buarvatnet. In such a scenario, a bedrock threshold dams the meltwater from the retreating glacier and an outburst flood is triggered when the glacier calves or advances into the lake. Understanding the processes behind the multiple events is therefore important in order to highlight the potential hazards in rapid outburst floods in a warming world.
Brandstätter, Anita; Peterson, Christine T; Irwin, Jodi A; Mpoke, Solomon; Koech, Davy K; Parson, Walther; Parsons, Thomas J
2004-10-01
Large forensic mtDNA databases which adhere to strict guidelines for generation and maintenance, are not available for many populations outside of the United States and western Europe. We have established a high quality mtDNA control region sequence database for urban Nairobi as both a reference database for forensic investigations, and as a tool to examine the genetic variation of Kenyan sequences in the context of known African variation. The Nairobi sequences exhibited high variation and a low random match probability, indicating utility for forensic testing. Haplogroup identification and frequencies were compared with those reported from other published studies on African, or African-origin populations from Mozambique, Sierra Leone, and the United States, and suggest significant differences in the mtDNA compositions of the various populations. The quality of the sequence data in our study was investigated and supported using phylogenetic measures. Our data demonstrate the diversity and distinctiveness of African populations, and underline the importance of establishing additional forensic mtDNA databases of indigenous African populations.
Nanotechnology: toxicologic pathology.
Hubbs, Ann F; Sargent, Linda M; Porter, Dale W; Sager, Tina M; Chen, Bean T; Frazer, David G; Castranova, Vincent; Sriram, Krishnan; Nurkiewicz, Timothy R; Reynolds, Steven H; Battelli, Lori A; Schwegler-Berry, Diane; McKinney, Walter; Fluharty, Kara L; Mercer, Robert R
2013-02-01
Nanotechnology involves technology, science, and engineering in dimensions less than 100 nm. A virtually infinite number of potential nanoscale products can be produced from many different molecules and their combinations. The exponentially increasing number of nanoscale products will solve critical needs in engineering, science, and medicine. However, the virtually infinite number of potential nanotechnology products is a challenge for toxicologic pathologists. Because of their size, nanoparticulates can have therapeutic and toxic effects distinct from micron-sized particulates of the same composition. In the nanoscale, distinct intercellular and intracellular translocation pathways may provide a different distribution than that obtained by micron-sized particulates. Nanoparticulates interact with subcellular structures including microtubules, actin filaments, centrosomes, and chromatin; interactions that may be facilitated in the nanoscale. Features that distinguish nanoparticulates from fine particulates include increased surface area per unit mass and quantum effects. In addition, some nanotechnology products, including the fullerenes, have a novel and reactive surface. Augmented microscopic procedures including enhanced dark-field imaging, immunofluorescence, field-emission scanning electron microscopy, transmission electron microscopy, and confocal microscopy are useful when evaluating nanoparticulate toxicologic pathology. Thus, the pathology assessment is facilitated by understanding the unique features at the nanoscale and the tools that can assist in evaluating nanotoxicology studies.
Nanotechnology: Toxicologic Pathology
Hubbs, Ann F.; Sargent, Linda M.; Porter, Dale W.; Sager, Tina M.; Chen, Bean T.; Frazer, David G.; Castranova, Vincent; Sriram, Krishnan; Nurkiewicz, Timothy R.; Reynolds, Steven H.; Battelli, Lori A.; Schwegler-Berry, Diane; McKinney, Walter; Fluharty, Kara L.; Mercer, Robert R.
2015-01-01
Nanotechnology involves technology, science, and engineering in dimensions less than 100 nm. A virtually infinite number of potential nanoscale products can be produced from many different molecules and their combinations. The exponentially increasing number of nanoscale products will solve critical needs in engineering, science, and medicine. However, the virtually infinite number of potential nanotechnology products is a challenge for toxicologic pathologists. Because of their size, nanoparticulates can have therapeutic and toxic effects distinct from micron-sized particulates of the same composition. In the nanoscale, distinct intercellular and intracellular translocation pathways may provide a different distribution than that obtained by micron-sized particulates. Nanoparticulates interact with subcellular structures including microtubules, actin filaments, centrosomes, and chromatin; interactions that may be facilitated in the nanoscale. Features that distinguish nanoparticulates from fine particulates include increased surface area per unit mass and quantum effects. In addition, some nanotechnology products, including the fullerenes, have a novel and reactive surface. Augmented microscopic procedures including enhanced dark-field imaging, immunofluorescence, field-emission scanning electron microscopy, transmission electron microscopy, and confocal microscopy are useful when evaluating nanoparticulate toxicologic pathology. Thus, the pathology assessment is facilitated by understanding the unique features at the nanoscale and the tools that can assist in evaluating nanotoxicology studies. PMID:23389777
Thermoviscoplastic analysis of fibrous periodic composites using triangular subvolumes
NASA Technical Reports Server (NTRS)
Walker, Kevin P.; Freed, Alan D.; Jordan, Eric H.
1993-01-01
The nonlinear viscoplastic behavior of fibrous periodic composites is analyzed by discretizing the unit cell into triangular subvolumes. A set of these subvolumes can be configured by the analyst to construct a representation for the unit cell of a periodic composite. In each step of the loading history, the total strain increment at any point is governed by an integral equation which applies to the entire composite. A Fourier series approximation allows the incremental stresses and strains to be determined within a unit cell of the periodic lattice. The nonlinearity arising from the viscoplastic behavior of the constituent materials comprising the composite is treated as fictitious body force in the governing integral equation. Specific numerical examples showing the stress distributions in the unit cell of a fibrous tungsten/copper metal matrix composite under viscoplastic loading conditions are given. The stress distribution resulting in the unit cell when the composite material is subjected to an overall transverse stress loading history perpendicular to the fibers is found to be highly heterogeneous, and typical homogenization techniques based on treating the stress and strain distributions within the constituent phases as homogeneous result in large errors under inelastic loading conditions.
Thermoviscoplastic analysis of fibrous periodic composites by the use of triangular subvolumes
NASA Technical Reports Server (NTRS)
Walker, Kevin P.; Freed, Alan D.; Jordan, Eric H.
1994-01-01
The non-linear viscoplastic behavior of fibrous periodic composites is analyzed by discretizing the unit cell into triangular subvolumes. A set of these subvolumes can be configured by the analyst to construct a representation for the unit cell of a periodic composite. In each step of the loading history the total strain increment at any point is governed by an integral equation which applies to the entire composite. A Fourier series approximation allows the incremental stresses and strains to be determined within a unit cell of the periodic lattice. The non-linearity arising from the viscoplastic behavior of the constituent materials comprising the composite is treated as a fictitious body force in the governing integral equation. Specific numerical examples showing the stress distributions in the unit cell of a fibrous tungsten/copper metal-matrix composite under viscoplastic loading conditions are given. The stress distribution resulting in the unit cell when the composite material is subjected to an overall transverse stress loading history perpendicular to the fibers is found to be highly heterogeneous, and typical homogenization techniques based on treating the stress and strain distributions within the constituent phases as homogeneous result in large errors under inelastic loading conditions.
NASA Astrophysics Data System (ADS)
Canevet, David; Pérez Del Pino, Angel; Amabilino, David B.; Sallé, Marc
2011-07-01
An organogelator with two distinct π-functional units is able to incorporate carbon nanotubes into its mesh of fibres in the gel state. The morphology of the material derived from this nanocomposite after evaporation of the solvent is a complex mesh of fibres which is clearly different from the pure gelator. This feature indicates a role of the nanotubes in assisting the formation of a fibre structure in the gel thanks to their interaction with the pyrene units in the organogelator. The nanocomposite conducts electricity once the p-type gelator is doped with iodine vapour. The change in morphology caused by the carbon material increases the conductivity of the material compared with the purely organic conducting system. It is remarkable that this improvement in the physical property is caused by an extremely small proportion of the carbon material (only present at a ratio of 0.1% w/w). The practically unique properties of TTF unit allow measurements with both doped and undoped materials with conducting atomic force microscopy which have demonstrated that the carbon nanotubes are not directly responsible for the increased conductivity.An organogelator with two distinct π-functional units is able to incorporate carbon nanotubes into its mesh of fibres in the gel state. The morphology of the material derived from this nanocomposite after evaporation of the solvent is a complex mesh of fibres which is clearly different from the pure gelator. This feature indicates a role of the nanotubes in assisting the formation of a fibre structure in the gel thanks to their interaction with the pyrene units in the organogelator. The nanocomposite conducts electricity once the p-type gelator is doped with iodine vapour. The change in morphology caused by the carbon material increases the conductivity of the material compared with the purely organic conducting system. It is remarkable that this improvement in the physical property is caused by an extremely small proportion of the carbon material (only present at a ratio of 0.1% w/w). The practically unique properties of TTF unit allow measurements with both doped and undoped materials with conducting atomic force microscopy which have demonstrated that the carbon nanotubes are not directly responsible for the increased conductivity. Electronic supplementary information (ESI) available: Details concerning the preparation of 1-SWCNTs composite. See DOI: 10.1039/c1nr10235d
Huebner, Kyla D; O'Brien, Etienne J O; Heard, Bryan J; Chung, May; Achari, Yamini; Shrive, Nigel G; Frank, Cyril B
2012-01-01
The human anterior cruciate ligament (ACL) is a composite structure of two anatomically distinct bundles: an anteromedial (AM) and posterolateral (PL) bundles. Tendons are often used as autografts for surgical reconstruction of ACL following severe injury. However, despite successful surgical reconstruction, some people experience re-rupture and later development of osteoarthritis. Understanding the structure and molecular makeup of normal ACL is essential for its optimal replacement. Reportedly the two bundles display different tensions throughout joint motion and may be fundamentally different. This study assessed the similarities and differences in ultrastructure and molecular composition of the AM and PL bundles to test the hypothesis that the two bundles of the ACL develop unique characteristics with maturation. ACLs from nine mature and six immature sheep were compared. The bundles were examined for mRNA and protein levels of collagen types I, III, V, and VI, and two proteoglycans. The fibril diameter composition of the two bundles was examined with transmission electron microscopy. Maturation does alter the molecular and structural composition of the two bundles of ACL. Although the PL band appears to mature slower than the AM band, no significant differences were detected between the bundles in the mature animals. We thus reject our hypothesis that the two ACL bundles are distinct. The two anatomically distinct bundles of the sheep ACL can be considered as two parts of one structure at maturity and material that would result in a structure of similar functionality can be used to replace each ACL bundle in the sheep.
Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.; Repetski, John E.
1999-01-01
Deep-water facies, chiefly hemipelagic deposits and turbidites, of Cambrian through Devonian age are widely exposed in the Medfra and Mt. McKinley quadrangles. These strata include the upper part of the Telsitna Formation (Middle-Upper Ordovician) and the Paradise Fork Formation (Lower Silurian-Lower Devonian) in the Nixon Fork terrane, the East Fork Hills Formation (Upper Cambrian-Lower Devonian) in the East Fork subterrane of the Minchumina terrane, and the chert and argillite unit (Ordovician) and the argillite and quartzite unit (Silurian- Devonian? and possibly older) in the Telida subterrane of the Minchumina terrane.In the western part of the study area (Medfra quadrangle), both hemipelagic deposits and turbidites are largely calcareous and were derived from the Nixon Fork carbonate platform. East- ern exposures (Mt. McKinley quadrangle; eastern part of the Telida subterrane) contain much less carbonate; hemipelagic strata are mostly chert, and turbidites contain abundant rounded quartz and lesser plagioclase and potassium feldspar. Deep-water facies in the Medfra quadrangle correlate well with rocks of the Dillinger terrane exposed to the south (McGrath quadrangle), but coeval strata in the Mt. McKinley quadrangle are compositionally similar to rocks to the northeast (Livengood quadrangle). Petrographic data thus suggest that the Telida subterranes presently defined is an artificial construct made up of two distinct sequences of disparate provenance.Restoration of 90 and 150 km of dextral strike-slip on the Iditarod and Farewell faults, respectively, aligns the deep-water strata of the Minchumina and Dillinger terranes in a position east of the Nixon Fork carbonate platform. This restoration supports the interpretation that lower Paleozoic rocks in the Nixon Fork and Dillinger terranes, and in the western part of the Minchumina terrane (East Fork subterrane and western part of the Telida subterrane), formed along a single continental margin. Rocks in the eastern part of the Telida subterrane are compositionally distinct from those to the west and may have had a different origin and history.
John P. Gannon; Scott W. Bailey; Kevin J. McGuire
2014-01-01
A network of shallow groundwater wells in a headwater catchment at the Hubbard Brook Experimental Forest in New Hampshire, U.S. was used to investigate the hydrologic behavior of five distinct soil morphological units. The soil morphological units were hypothesized to be indicative of distinct water table regimes. Water table fluctuations in the wells were...
Compositional threshold for Nuclear Waste Glass Durability
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kruger, Albert A.; Farooqi, Rahmatullah; Hrma, Pavel R.
2013-04-24
Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.
Blaser, Martin J; Dominguez-Bello, Maria G; Contreras, Monica; Magris, Magda; Hidalgo, Glida; Estrada, Isidoro; Gao, Zhan; Clemente, Jose C; Costello, Elizabeth K; Knight, Rob
2013-01-01
The human skin harbors complex bacterial communities. Prior studies showing high inter-individual variation focused on subjects from developed countries. We therefore compared cutaneous bacterial communities of Amerindians in the Venezuelan Amazon with subjects in the United States. Forearm skin specimens were studied from healthy Amerindians in Platanillal village in Amazonas State, and from healthy persons in New York and Colorado. All skin sampling used similar swab/buffer techniques. Multiplexed V2-targeted 16S rRNA gene pyrosequencing yielded high quality sequences from 112 samples. The results show 20 phyla, with three (Proteobacteria, Firmicutes, Actinobacteria) predominating. US residents and Venezuelan Amerindians had significantly different forearm skin bacterial community compositions, with United States dominated by Propionibacterium. Among the Amerindians, there was a deep split based on bacterial community membership, with 30 and 42 samples, respectively, falling into each of the two groups, not associated with age, gender, or body mass index. One Amerindian group had diversity similar to the United States, but was dominated by Staphylococcus rather than Propionibacterium. The other Amerindian group was significantly more diverse and even than the US or the other Amerindian group, and featured a broad range of Proteobacteria. The results provide evidence that ethnicity, lifestyle and/or geography are associated with the structure of human cutaneous bacterial communities.
Thoresen, Todd; Lenz, Martin; Gardel, Margaret L
2013-02-05
Diverse myosin II isoforms regulate contractility of actomyosin bundles in disparate physiological processes by variations in both motor mechanochemistry and the extent to which motors are clustered into thick filaments. Although the role of mechanochemistry is well appreciated, the extent to which thick filament length regulates actomyosin contractility is unknown. Here, we study the contractility of minimal actomyosin bundles formed in vitro by mixtures of F-actin and thick filaments of nonmuscle, smooth, and skeletal muscle myosin isoforms with varied length. Diverse myosin II isoforms guide the self-organization of distinct contractile units within in vitro bundles with shortening rates similar to those of in vivo myofibrils and stress fibers. The tendency to form contractile units increases with the thick filament length, resulting in a bundle shortening rate proportional to the length of constituent myosin thick filament. We develop a model that describes our data, providing a framework in which to understand how diverse myosin II isoforms regulate the contractile behaviors of disordered actomyosin bundles found in muscle and nonmuscle cells. These experiments provide insight into physiological processes that use dynamic regulation of thick filament length, such as smooth muscle contraction. Copyright © 2013 Biophysical Society. Published by Elsevier Inc. All rights reserved.
NASA Astrophysics Data System (ADS)
da Costa, Marcondes Lima; Sousa, Daniel José Lima; Angélica, Rômulo Simões
The eastern region of the Amazon is home to the most important kaolin bauxite producing district in Brazil, referred to as the Paragominas-Capim kaolin bauxite district, which has a reserve of at least 1.0 billion tons of high-quality kaolin used in the paper coating industry. The kaolin deposits are closely related to sedimentary rocks of the Parnaíba basin and their lateritic cover. Two large deposits are already being mined: IRCC (Ipixuna) and PPSA (Paragominas). The geology of the IRCC mine is comprised of the kaolin-bearing lower unit (truncated mature laterite succession derived from the Ipixuna/Itapecuru formation) and the upper unit (immature lateritized Barreiras formation). The lower kaolin unit is characterized by a sandy facies at the bottom and a soft (ore) with flint facies at the top. It is formed by kaolinite, quartz, some iron oxi-hydroxides, mica and several accessories and heavy minerals. The <2 μm kaolinite crystallites only correspond to 41.3-58.3% of the soft kaolin, and large booklets of 15-300 μm are common. The degree of structure order of kaolinite decreases towards the flint kaolin. The chemical composition of the soft kaolin is similar to the theoretical chemical composition of kaolinite, with low iron content, and can be well correlated to most kaolin deposits in the region. The distribution pattern of chemical elements from sandy to flint kaolin (lower unit) suggests a lateritic evolution and erosive truncation. This is quite distinct from the upper unit, which has a mineralogical and chemical pathway relating it to a complete immature lateritic profile. The geological evolution of the IRCC kaolin is similar to that of other deposits in the eastern Amazon region, being comprised of: parent rocks formed in an estuarine marine and fluvio-laccustrine environment during the early Cretaceous; establishment of mature lateritization with the formation of kaolin in the Eocene; marine transgression and regression - (Pirabas and Barreiras formation) with kaolin profile erosion and forward movement of deferruginization and flintization during the Miocene after partial mangrove covering; and immature lateritization - partial kaolin ferruginization during the Pleistocene.
NASA Astrophysics Data System (ADS)
Niemi, N. A.; Chang, H.; Li, L.; Molnar, P. H.
2017-12-01
The Bukadaban Feng massif in northern Tibet forms the footwall of an east-west trending graben that is kinematically linked to the Kunlun fault. Extension across this graben accommodates left-lateral slip on the Kunlun fault, as evidenced by the 2001 Kunlun earthquake rupture. New geochronologic and thermochronologic data from Bukadaban Feng provide insight into the evolution of this normal fault system. The Bukadaban Feng massif is composed of two plutonic units, an eastern unit of dacitic composition and a western unit of rhyolitic composition. Sixty-five LA-ICP-MS zircon U-Pb age determinations on the rhyolitic unit reveal a range of ages from 873 - 6.3 Ma. CA-TIMS U-Pb zircon geochronology on the nine youngest of these zircons yields an emplacement age of 6.8 Ma. Twenty-seven LA-ICP-MS zircon U-Pb ages on the dacite range from 208 to 7.9 Ma. No coherent population of young zircons was observed, and CA-TIMS analysis was not performed. Zircon (U-Th)/He analysis on the dacite and rhyolite yield ages of 3.9 and 5.0 Ma, respectively, while apatite (U-Th-Sm)/He thermochronology on 5 samples collected from both units along the trace of the normal fault yield ages ranging from 1.4 - 2.6 Ma. The emplacement ages and compositions of plutonic rocks at Bukadaban Feng are consistent with the eruptive timing and geochemistry of silicic volcanic rocks in the graben (Zhang et al., 2012). Silicic magmatism is often associated with the onset of crustal extension, and the combination of plutonism and correlative silicic volcanism provides an indirect constraint on the initiation of this graben at 7 Ma. The distinct zircon (U-Pb) and (U-Th)/He ages indicates that the rocks presently exposed at Bukadaban Feng were emplaced at ambient temperatures in excess of 180°C. The zircon and apatite thermochronologic data require exhumation at rates of 1-2 mm/yr since the late Miocene. A 7 Ma initiation age for the Bukadaban Feng normal fault is consistent with both published estimates of total offset across the Kunlun fault ( 70 km; Kidd and Molnar, 1988) and recent fault slip rates ( 10 mm/yr; van der Woerd et al., 2002). To the extent that the onset of extension and strike-slip faulting can be related to the attainment of high topography, these new data imply that northernmost Tibet may have reached maximum elevations as recently as the late Miocene.
CellTrans: An R Package to Quantify Stochastic Cell State Transitions.
Buder, Thomas; Deutsch, Andreas; Seifert, Michael; Voss-Böhme, Anja
2017-01-01
Many normal and cancerous cell lines exhibit a stable composition of cells in distinct states which can, e.g., be defined on the basis of cell surface markers. There is evidence that such an equilibrium is associated with stochastic transitions between distinct states. Quantifying these transitions has the potential to better understand cell lineage compositions. We introduce CellTrans, an R package to quantify stochastic cell state transitions from cell state proportion data from fluorescence-activated cell sorting and flow cytometry experiments. The R package is based on a mathematical model in which cell state alterations occur due to stochastic transitions between distinct cell states whose rates only depend on the current state of a cell. CellTrans is an automated tool for estimating the underlying transition probabilities from appropriately prepared data. We point out potential analytical challenges in the quantification of these cell transitions and explain how CellTrans handles them. The applicability of CellTrans is demonstrated on publicly available data on the evolution of cell state compositions in cancer cell lines. We show that CellTrans can be used to (1) infer the transition probabilities between different cell states, (2) predict cell line compositions at a certain time, (3) predict equilibrium cell state compositions, and (4) estimate the time needed to reach this equilibrium. We provide an implementation of CellTrans in R, freely available via GitHub (https://github.com/tbuder/CellTrans).
Perceived demands during modern military operations.
Boermans, Sylvie M; Kamphuis, Wim; Kamhuis, Wim; Delahaij, Roos; Korteling, J E Hans; Euwema, Martin C
2013-07-01
Using a cross-sectional design, this study explored operational demands during the International Security Assistance Force for Afghanistan (2009-2010) across distinct military units. A total of 1,413 Dutch soldiers, nested within four types of units (i.e., combat, combat support, service support, and command support units) filled out a 23-item self-survey in which they were asked to evaluate the extent to which they experienced operational characteristics as demanding. Exploratory factor analysis identified six underlying dimensions of demands. Multivariate analysis of variance revealed that distinct units are characterized by their own unique constellation of perceived demands, even after controlling for previous deployment experience. Most notable findings were found when comparing combat units to other types of units. These insights can be used to better prepare different types of military units for deployment, and support them in the specific demands they face during deployment. Reprint & Copyright © 2013 Association of Military Surgeons of the U.S.
Jeffery, Alvin D; Mosier, Sammie; Baker, Allison; Korwek, Kimberly; Borum, Cindy; Englebright, Jane
2018-02-01
Hospital medical-surgical (M/S) nursing units are responsible for up to 28 million encounters annually, yet receive little attention from professional organizations and national initiatives targeted to improve quality and performance. We sought to develop a framework recognizing high-performing units within our large hospital system. This was a retrospective data analysis of M/S units throughout a 168-hospital system. Measures represented patient experience, employee engagement, staff scheduling, nursing-sensitive patient outcomes, professional practices, and clinical process measures. Four hundred ninety units from 129 hospitals contributed information to test the framework. A manual scoring system identified the top 5% and recognized them as a "Unit of Distinction." Secondary analyses with machine learning provided validation of the proposed framework. Similar to external recognition programs, this framework and process provide a holistic evaluation useful for meaningful recognition and lay the groundwork for benchmarking in improvement efforts.
NASA Astrophysics Data System (ADS)
Ahern, A.; Rogers, D.
2017-12-01
Better constraints on the physical properties (e.g. grain size, rock abundance, cohesion, porosity and amount of induration) of Martian surface materials can lead to greater understanding of outcrop origin (e.g. via sedimentary, effusive volcanic, pyroclastic processes). Many outcrop surfaces on Mars likely contain near-surface (<3 cm) vertical heterogeneity in physical properties due to thin sediment cover, induration, and physical weathering, that can obscure measurement of the bulk thermal conductivity of the outcrop materials just below. Fortunately, vertical heterogeneity within near-surface materials can result in unique, and possibly predictable, diurnal and seasonal temperature patterns. The KRC thermal model has been utilized in a number of previous studies to predict thermal inertia of surface materials on Mars. Here we use KRC to model surface temperatures from overlapping Mars Odyssey THEMIS surface temperature observations that span multiple seasons and local times, in order to constrain both the nature of vertical heterogeneity and the underlying outcrop thermal inertia for various spectrally distinctive outcrops on Mars. We utilize spectral observations from TES and CRISM to constrain the particle size of the uppermost surface. For this presentation, we will focus specifically on chloride-bearing units in Terra Sirenum and Meridiani Planum, as well as mafic and feldspathic bedrock locations with distinct spectral properties, yet uncertain origins, in Noachis Terra and Nili Fossae. We find that many of these surfaces exhibit variations in apparent thermal inertia with season and local time that are consistent with low thermal inertia materials overlying higher thermal inertia substrates. Work is ongoing to compare surface temperature measurements with modeled two-layer scenarios in order to constrain the top layer thickness and bottom layer thermal inertia. The information will be used to better interpret the origins of these distinctive outcrops.
NASA Technical Reports Server (NTRS)
Tapia, Moiez A.
1993-01-01
The study of a comparative analysis of distinct multiplex and fault-tolerant configurations for a PLC-based safety system from a reliability point of view is presented. It considers simplex, duplex and fault-tolerant triple redundancy configurations. The standby unit in case of a duplex configuration has a failure rate which is k times the failure rate of the standby unit, the value of k varying from 0 to 1. For distinct values of MTTR and MTTF of the main unit, MTBF and availability for these configurations are calculated. The effect of duplexing only the PLC module or only the sensors and the actuators module, on the MTBF of the configuration, is also presented. The results are summarized and merits and demerits of various configurations under distinct environments are discussed.
Indentation creep behaviors of amorphous Cu-based composite alloys
NASA Astrophysics Data System (ADS)
Song, Defeng; Ma, Xiangdong; Qian, Linfang
2018-04-01
This work reports the indentation creep behaviors of two Si2Zr3/amorphous Cu-based composite alloys utilizing nanoindentation technique. By analysis with Kelvin model, the retardation spectra of alloys at different positions, detached and attached regions to the intermetallics, were deduced. For the indentation of detached regions to Si2Zr3 intermetallics in both alloys, very similarity in creep displacement can be observed and retardation spectra show a distinct disparity in the second retardation peak. For the indentation of detached regions, the second retardation spectra also display distinct disparity. At both positions, the retardation spectra suggest that Si elements may lead to the relatively dense structure in the amorphous matrix and to form excessive Si2Zr3 intermetallics which may deteriorate the plastic deformation of current Cu-based composite alloys.
Holland, L.E.; Huston, M.L.
1985-01-01
The distribution patterns and food habits of young-of-the-year (YOY) fishes in a lentic area adjacent to the main channel of Pool 7 of the upper Mississippi River were studied. Habitats sampled grouped distinctly based on percent composition and abundance of YOY fishes with those having submergent vegetation dominated by a number of important sport species. In late spring, the grouping of stations depended on the presence or absence of newly transformed northern pike (Esox lucius). In early summer, stations did not differ as distinctly in composition, but in total abundance of young. Those stations with submergent vegetation had total catches which were more than double those elsewhere. By late summer, submergent and mixed vegetation stations formed a distinct assemblage influenced by the preponderance of three species of sunfishes. (DBO).
Marston, Chung K.; Jamieson, Frances; Cahoon, Fred; Lesiak, Gail; Golaz, Anne; Reeves, Mike; Popovic, Tanja
2001-01-01
Molecular characterization of 53 U.S. and Canadian Corynebacterium diphtheriae isolates by multilocus enzyme electrophoresis, ribotyping, and random amplified polymorphic DNA showed that strains with distinct molecular subtypes have persisted in the United States and Canada for at least 25 years. These strains are endemic rather than imported from countries with current endemic or epidemic diphtheria. PMID:11283092
USDA-ARS?s Scientific Manuscript database
The body of an animal encompasses a multitude of compositionally and functionally unique microbial environments, from the skin to the gastrointestinal system. Each of these systems harbor microbial communities that have adapted in order to cohabitate with their specific host resulting in a distinct...
Research Interests Dynamic biochemical composition of bioenergy-relevant biomass Coproduct development from lipid streams. Lieve Laurens's research interests in this realm are primarily focused on analytical selective, quantitative tradeoffs in biochemical composition of three strains of algae, grown in distinct
Emitter and absorber assembly for multiple self-dual operation and directional transparency
NASA Astrophysics Data System (ADS)
Kalozoumis, P. A.; Morfonios, C. V.; Kodaxis, G.; Diakonos, F. K.; Schmelcher, P.
2017-03-01
We demonstrate how to systematically design wave scattering systems with simultaneous coherent perfect absorbing and lasing operation at multiple and prescribed frequencies. The approach is based on the recursive assembly of non-Hermitian emitter and absorber units into self-dual emitter-absorber trimers at different composition levels, exploiting the simple structure of the corresponding transfer matrices. In particular, lifting the restriction to parity-time-symmetric setups enables the realization of emitter and absorber action at distinct frequencies and provides flexibility with respect to the choice of realistic parameters. We further show how the same assembled scatterers can be rearranged to produce unidirectional and bidirectional transparency at the selected frequencies. With the design procedure being generically applicable to wave scattering in single-channel settings, we demonstrate it with concrete examples of photonic multilayer setups.
Areally Extensive Surface Bedrock Exposures on Mars: Many Are Clastic Rocks, Not Lavas
NASA Astrophysics Data System (ADS)
Rogers, A. Deanne; Warner, Nicholas H.; Golombek, Matthew P.; Head, James W.; Cowart, Justin C.
2018-02-01
Areally extensive exposures of intact olivine/pyroxene-enriched rock, as well as feldspar-enriched rock, are found in isolated locations throughout the Martian highlands. The petrogenetic origin(s) of these rock units are not well understood, but some previous studies favored an effusive volcanic origin partly on the basis of distinctive composition and relatively high thermal inertia. Here we show that the regolith development, crater retention, and morphological characteristics for many of these "bedrock plains" are not consistent with competent lavas and reinterpret the high thermal inertia orbital signatures to represent friable materials that are more easily kept free of comminution products through eolian activity. Candidate origins include pyroclastic rocks, impact-generated materials, or detrital sedimentary rocks. Olivine/pyroxene enrichments in bedrock plains relative to surrounding materials could have potentially formed through deflation and preferential removal of plagioclase.
Code of Federal Regulations, 2010 CFR
2010-01-01
... FRESH FRUITS, VEGETABLES AND OTHER PRODUCTS 1,2 (INSPECTION, CERTIFICATION, AND STANDARDS) United States... indicated by distinct elongation of the growing point or distinct yellow or green color in the tip of the...
NASA Astrophysics Data System (ADS)
He, Y.; Billen, M. I.; Puckett, E. G.
2015-12-01
Flow in the Earth's mantle is driven by thermo-chemical convection in which the properties and geochemical signatures of rocks vary depending on their origin and composition. For example, tectonic plates are composed of compositionally-distinct layers of crust, residual lithosphere and fertile mantle, while in the lower-most mantle there are large compositionally distinct "piles" with thinner lenses of different material. Therefore, tracking of active or passive fields with distinct compositional, geochemical or rheologic properties is important for incorporating physical realism into mantle convection simulations, and for investigating the long term mixing properties of the mantle. The difficulty in numerically advecting fields arises because they are non-diffusive and have sharp boundaries, and therefore require different methods than usually used for temperature. Previous methods for tracking fields include the marker-chain, tracer particle, and field-correction (e.g., the Lenardic Filter) methods: each of these has different advantages or disadvantages, trading off computational speed with accuracy in tracking feature boundaries. Here we present a method for modeling active fields in mantle dynamics simulations using a new solver implemented in the deal.II package that underlies the ASPECT software. The new solver for the advection-diffusion equation uses a Local Discontinuous Galerkin (LDG) algorithm, which combines features of both finite element and finite volume methods, and is particularly suitable for problems with a dominant first-order term and discontinuities. Furthermore, we have applied a post-processing technique to insure that the solution satisfies a global maximum/minimum. One potential drawback for the LDG method is that the total number of degrees of freedom is larger than the finite element method. To demonstrate the capabilities of this new method we present results for two benchmarks used previously: a falling cube with distinct buoyancy and viscosity, and a Rayleigh-Taylor instability of a compositionally buoyant layer. To evaluate the trade-offs in computational speed and solution accuracy we present results for these same benchmarks using the two field tracking methods available in ASPECT: active tracer particles and the entropy viscosity method.
NASA Astrophysics Data System (ADS)
Needham, A. J.; Lindsay, J. M.; Smith, I. E. M.; Augustinus, P.; Shane, P. A.
2011-04-01
Rangitoto Volcano is the youngest and largest eruptive centre in the monogenetic intraplate Auckland Volcanic Field (AVF). The stratigraphy of Rangitoto pyroclastic deposits that have been preserved in swamps on nearby Motutapu Island and in Lake Pupuke on the mainland reveals that the volcano erupted twice; radiocarbon dating of 10 samples from the two tephra units in the swamps indicates eruption ages of 553 ± 7 and 504 ± 5 Cal years BP, for the lower and upper tephra layers, respectively. Geochemistry of the lava field and various scoria cones on Rangitoto Island itself reveals two distinct compositional groups: an alkaline olivine basalt group (that correlates geochemically with the lower tephra layer) and a group that is sub-alkaline and transitional to tholeiite (that correlates geochemically with the upper tephra layer). Based on this data, we infer that, following a phreatomagmatic vent-clearing phase, the early magmatic eruption of Rangitoto Volcano was Strombolian in character and produced an alkaline olivine basalt scoria cone and an associated thick ash deposit on nearby Motutapu Island. This was followed by a time gap of up to several decades, after which a second eruptive phase built the current summit scoria cone together with an encircling lava field. We suggest this later, sub-alkaline eruptive period was associated with the deposition of the thin upper tephra layer on Motutapu Island. The two suites of Rangitoto samples are chemically quite distinct, and each is associated with a distinct parental composition. Trace element modelling indicates the alkaline and sub-alkaline parental melts could have been derived by ~ 1 and 6 wt.% partial melting of an anhydrous garnet peridotite source at ~ 80 and 65 km depth, respectively. The compositional range within each suite is similar, and can be explained by mainly olivine together with minor clinopyroxene fractionation within a relatively simple conduit system in which mixing and mingling were not important. Significant olivine fractionation (< 25%) suggests that the magma may have spent some time in the upper conduit during ascent. This contrasts with a recently published model for the Crater Hill centre in the AVF, in which deep-seated fractionation of clinopyroxene followed by relatively rapid ascent to the surface has been invoked to explain the compositions seen there. The polycyclic nature of Rangitoto and in particular the reuse of the conduit system after a period of quiescence have implications for the concept of monogenetic volcanism. There are also implications for hazard assessment, such that when a future eruption occurs in the AVF, it will be necessary to consider the conduit a possible pathway for another eruption for up to several decades afterwards.
Bacterial diversity and composition in the fluid of pitcher plants of the genus Nepenthes.
Takeuchi, Yayoi; Chaffron, Samuel; Salcher, Michaela M; Shimizu-Inatsugi, Rie; Kobayashi, Masaki J; Diway, Bibian; von Mering, Christian; Pernthaler, Jakob; Shimizu, Kentaro K
2015-07-01
Pitchers are modified leaves used by carnivorous plants for trapping prey. Their fluids contain digestive enzymes from the plant and they harbor abundant microbes. In this study, the diversity of bacterial communities was assessed in Nepenthes pitcher fluids and the composition of the bacterial community was compared to that in other environments, including the phyllosphere of Arabidopsis, animal guts and another pitcher plant, Sarracenia. Diversity was measured by 454 pyrosequencing of 16S rRNA gene amplicons. A total of 232,823 sequences were obtained after chimera and singleton removal that clustered into 3260 distinct operational taxonomic units (OTUs) (3% dissimilarity), which were taxonomically distributed over 17 phyla, 25 classes, 45 orders, 100 families, and 195 genera. Pyrosequencing and fluorescence in situ hybridization yielded similar estimates of community composition. Most pitchers contained high proportions of unique OTUs, and only 22 OTUs (<0.6%) were shared by ≥14/16 samples, suggesting a unique bacterial assemblage in each pitcher at the OTU level. Diversity analysis at the class level revealed that the bacterial communities of both opened and unopened pitchers were most similar to that of Sarracenia and to that in the phyllosphere. Therefore, the bacterial community in pitchers may be formed by environmental filtering and/or by phyllosphere bacteria. Copyright © 2015 The Authors. Published by Elsevier GmbH.. All rights reserved.
Bacterial diversity and community composition from seasurface to subseafloor.
Walsh, Emily A; Kirkpatrick, John B; Rutherford, Scott D; Smith, David C; Sogin, Mitchell; D'Hondt, Steven
2016-04-01
We investigated compositional relationships between bacterial communities in the water column and those in deep-sea sediment at three environmentally distinct Pacific sites (two in the Equatorial Pacific and one in the North Pacific Gyre). Through pyrosequencing of the v4-v6 hypervariable regions of the 16S ribosomal RNA gene, we characterized 450,104 pyrotags representing 29,814 operational taxonomic units (OTUs, 97% similarity). Hierarchical clustering and non-metric multidimensional scaling partition the samples into four broad groups, regardless of geographic location: a photic-zone community, a subphotic community, a shallow sedimentary community and a subseafloor sedimentary community (⩾1.5 meters below seafloor). Abundance-weighted community compositions of water-column samples exhibit a similar trend with depth at all sites, with successive epipelagic, mesopelagic, bathypelagic and abyssopelagic communities. Taxonomic richness is generally highest in the water-column O2 minimum zone and lowest in the subseafloor sediment. OTUs represented by abundant tags in the subseafloor sediment are often present but represented by few tags in the water column, and represented by moderately abundant tags in the shallow sediment. In contrast, OTUs represented by abundant tags in the water are generally absent from the subseafloor sediment. These results are consistent with (i) dispersal of marine sedimentary bacteria via the ocean, and (ii) selection of the subseafloor sedimentary community from within the community present in shallow sediment.
NASA Astrophysics Data System (ADS)
Pillai, Shreeja; Reshi, Hilal Ahmad; Bagwaiya, Toshi; Banerjee, Alok; Shelke, Vilas
2017-09-01
Nanomaterials exhibit properties different from those of their bulk counterparts. The modified magnetic characteristics of manganite nanoparticles were exploited to improve magnetization in multiferroic BiFeO3 compound. We studied the composite of two morphologically and magnetically distinct compounds BiFeO3 (BFO) and La0.7Sr0.3MnO3 (LSMO). The microcrystalline BiFeO3 sample was prepared by solid state reaction method and the nanocrystalline La0.7Sr0.3MnO3 by sol-gel method. Composites with nominal compositions (1-x)BiFeO3-(x)La0.7Sr0.3MnO3 were prepared by modified solid state reaction method. The phase purity and crystal structures were checked by using X-ray diffraction. The formation of composites with phase separated BFO and LSMO was confirmed using Raman and Fourier Transform Infrared spectroscopy studies. The composite samples showed relatively high value of magnetization with finite coercivity. This improvement in magnetic behavior is ascribed to the coexistence of multiple magnetic orderings in composite samples. We scrutinized the possibility of oxygen vacancy or Fe mixed valency formation in the samples using X-ray photoelectron spectroscopy technique.
Chemical complexity and source of the White River Ash, Alaska and Yukon
Preece, S.J.; McGimsey, Robert G.; Westgate, J.A.; Pearce, N.J.G.; Hartmann, W.K.; Perkins, W.T.
2014-01-01
The White River Ash, a prominent stratigraphic marker bed in Alaska (USA) and Yukon (Canada), consists of multiple compositional units belonging to two geochemical groups. The compositional units are characterized using multiple criteria, with combined glass and ilmenite compositions being the best discriminators. Two compositional units compose the northern group (WRA-Na and WRA-Nb), and two units are present in the eastern group (WRA-Ea and the younger, WRA-Eb). In the proximal area, the ca. 1900 yr B.P. (Lerbekmo et al., 1975) WRA-Na displays reverse zoning in the glass phase and systematic changes in ilmenite composition and estimated oxygen fugacity from the base to the top of the unit. The eruption probably tapped different magma batches or bodies within the magma reservoir with limited mixing or mingling between them. The 1147 cal yr B.P. (calibrated years, approximately equivalent to calendric years) (Clague et al., 1995) WRA-Ea eruption is only weakly zoned, but pumices with different glass compositions are present, along with gray and white intermingled glass in individual pumice clasts, indicating the presence of multiple magmatic bodies or layers. All White River Ash products are high-silica adakites and are sourced from the Mount Churchill magmatic system.
Structure, age and origin of the bay-mouth shoal deposits, Chesapeake Bay, Virginia
Colman, Steven M.; Berquist, C.R.; Hobbs, C. H.
1988-01-01
The mouth of Chesapeake Bay contains a distinctive shoal complex and related deposits that result from the complex interaction of three different processes: (1) progradation of a barrier spit at the southern end of the Delmarva Peninsula, (2) strong, reversing tidal currents that transport and rework sediment brought to the bay mouth from the north, and (3) landward (bayward) net non-tidal circulation and sediment transport. Together, these processes play a major role in changing the configuration of the estuary and filling it with sediment. The deposits at the mouth of the bay hold keys both to the evolution of the bay during the Holocene transgression and to the history of previous generations of the bay. The deposit associated with the shoals at the mouth of the bay, the bay-mouth sand, is a distinct stratigraphic unit composed mostly of uniform, gray, fine sand. The position and internal structure of the unit shows that it is related to near-present sea level, and thus is less than a few thousand years old. The processes affecting the upper surface of the deposit and the patterns of erosion and deposition at this surface are complex, but the geometry and structure of the deposit indicate that it is a coherent unit that is prograding bayward and tending to fill the estuary. The source of the bay-mouth sand is primarily outside the bay in the nearshore zone of the Delmarva Peninsula and on the inner continental shelf. The internal structure of the deposit, its surface morphology, its heavy-mineral composition, bottom-current studies, comparative bathymetry, and sediment budgets all suggest that sand is brought to the bay mouth by southerly longshore drift along the Delmarva Peninsula and then swept into the bay. In addition to building the southward- and bayward-prograding bay-mouth sand, these processes result in sand deposition tens of kilometers into the bay. ?? 1988.
Spatio-Temporal Interdependence of Bacteria and Phytoplankton during a Baltic Sea Spring Bloom
Bunse, Carina; Bertos-Fortis, Mireia; Sassenhagen, Ingrid; Sildever, Sirje; Sjöqvist, Conny; Godhe, Anna; Gross, Susanna; Kremp, Anke; Lips, Inga; Lundholm, Nina; Rengefors, Karin; Sefbom, Josefin; Pinhassi, Jarone; Legrand, Catherine
2016-01-01
In temperate systems, phytoplankton spring blooms deplete inorganic nutrients and are major sources of organic matter for the microbial loop. In response to phytoplankton exudates and environmental factors, heterotrophic microbial communities are highly dynamic and change their abundance and composition both on spatial and temporal scales. Yet, most of our understanding about these processes comes from laboratory model organism studies, mesocosm experiments or single temporal transects. Spatial-temporal studies examining interactions of phytoplankton blooms and bacterioplankton community composition and function, though being highly informative, are scarce. In this study, pelagic microbial community dynamics (bacteria and phytoplankton) and environmental variables were monitored during a spring bloom across the Baltic Proper (two cruises between North Germany to Gulf of Finland). To test to what extent bacterioplankton community composition relates to the spring bloom, we used next generation amplicon sequencing of the 16S rRNA gene, phytoplankton diversity analysis based on microscopy counts and population genotyping of the dominating diatom Skeletonema marinoi. Several phytoplankton bloom related and environmental variables were identified to influence bacterial community composition. Members of Bacteroidetes and Alphaproteobacteria dominated the bacterial community composition but the bacterial groups showed no apparent correlation with direct bloom related variables. The less abundant bacterial phyla Actinobacteria, Planctomycetes, and Verrucomicrobia, on the other hand, were strongly associated with phytoplankton biomass, diatom:dinoflagellate ratio, and colored dissolved organic matter (cDOM). Many bacterial operational taxonomic units (OTUs) showed high niche specificities. For example, particular Bacteroidetes OTUs were associated with two distinct genetic clusters of S. marinoi. Our study revealed the complexity of interactions of bacterial taxa with inter- and intraspecific genetic variation in phytoplankton. Overall, our findings imply that biotic and abiotic factors during spring bloom influence bacterial community dynamics in a hierarchical manner. PMID:27148206
Mineralogic and compositional properties of Martian soil and dust: results from Mars Pathfinder
Bell, J.F.; McSween, H.Y.; Crisp, J.A.; Morris, R.V.; Murchie, S.L.; Bridges, N.T.; Johnson, J. R.; Britt, D.T.; Golombek, M.P.; Moore, H.J.; Ghosh, A.; Bishop, J.L.; Anderson, R.C.; Brückner, J.; Economou, T.; Greenwood, J.P.; Gunnlaugsson, H.P.; Hargraves, R.M.; Hviid, S.; Knudsen, J.M.; Madsen, M.B.; Reid, R.; Rieder, R.; Soderblom, L.
2000-01-01
Mars Pathfinder obtained multispectral, elemental, magnetic, and physical measurements of soil and dust at the Sagan Memorial Station during the course of its 83 sol mission. We describe initial results from these measurements, concentrating on multispectral and elemental data, and use these data, along with previous Viking, SNC meteorite, and telescopic results, to help constrain the origin and evolution of Martian soil and dust. We find that soils and dust can be divided into at least eight distinct spectral units, based on parameterization of Imager for Mars Pathfinder (IMP) 400 to 1000 nm multispectral images. The most distinctive spectral parameters for soils and dust are the reflectivity in the red, the red/blue reflectivity ratio, the near-IR spectral slope, and the strength of the 800 to 1000 nm absorption feature. Most of the Pathfinder spectra are consistent with the presence of poorly crystalline or nanophase ferric oxide(s), sometimes mixed with small but varying degrees of well-crystalline ferric and ferrous phases. Darker soil units appear to be coarser-grained, compacted, and/or mixed with a larger amount of dark ferrous materials relative to bright soils. Nanophase goethite, akaganeite, schwertmannite, and maghemite are leading candidates for the origin of the absorption centered near 900 nm in IMP spectra. The ferrous component in the soil cannot be well-constrained based on IMP data. Alpha proton X-ray spectrometer (APXS) measurements of six soil units show little variability within the landing site and show remarkable overall similarity to the average Viking-derived soil elemental composition. Differences exist between Viking and Pathfinder soils, however, including significantly higher S and Cl abundances and lower Si abundances in Viking soils and the lack of a correlation between Ti and Fe in Pathfinder soils. No significant linear correlations were observed between IMP spectral properties and APXS elemental chemistry. Attempts at constraining the mineralogy of soils and dust using normative calculations involving mixtures of smectites and silicate and oxide minerals did not yield physically acceptable solutions. We attempted to use the Pathfinder results to constrain a number of putative soil and dust formation scenarios, including palagonitization and acid-fog weathering. While the Pathfinder soils cannot be chemically linked to the Pathfinder rocks by palagonitization, this study and McSween et al. [1999] suggest that palagonitic alteration of a Martian basaltic rock, plus mixture with a minor component of locally derived andesitic rock fragments, could be consistent with the observed soil APXS and IMP properties.
Digital image processing based identification of nodes and internodes of chopped biomass stems
USDA-ARS?s Scientific Manuscript database
Chemical composition of biomass feedstock is an important parameter for optimizing the yield and economics of various bioconversion pathways. Although understandably, the chemical composition of biomass varies among species, varieties, and plant components, there is distinct variation even among ste...
NASA Technical Reports Server (NTRS)
Spudis, P. D.; Hawke, B. R.
1982-01-01
Chemical mixing model studies of lunar geochemical data for the central and Taurus-Littrow lunar highlands were performed utilizing pristine highland rock types as end member compositions. The central highlands show considerable diversity in composition; anorthosite is the principal rock type in the Apollo 16/Descartes region, while norite predominates in the highlands west of the landing site. This change in crustal composition is coincident with a major color boundary seen in earth-based multispectral data and probably represents the presence of distinct geochemical provinces within the central highlands. The Taurus-Littrow highlands are dominated by norite; anorthosite is far less abundant than in the central highlands. This suggests that the impact target for the Serenitatis basin was different than that of the Nectaris basin and further strengthens the hypothesis that the lunar highlands are petrologically heterogeneous on a regional basis. It is suggested that the lunar highlands should be viewed in terms of geochemical provinces that have undergone distinct and complex igneous and impact histories.
NASA Astrophysics Data System (ADS)
Yamashita, Youhei; Boyer, Joseph N.; Jaffé, Rudolf
2013-09-01
The coastal zone of the Florida Keys features the only living coral reef in the continental United States and as such represents a unique regional environmental resource. Anthropogenic pressures combined with climate disturbances such as hurricanes can affect the biogeochemistry of the region and threaten the health of this unique ecosystem. As such, water quality monitoring has historically been implemented in the Florida Keys, and six spatially distinct zones have been identified. In these studies however, dissolved organic matter (DOM) has only been studied as a quantitative parameter, and DOM composition can be a valuable biogeochemical parameter in assessing environmental change in coastal regions. Here we report the first data of its kind on the application of optical properties of DOM, in particular excitation emission matrix fluorescence with parallel factor analysis (EEM-PARAFAC), throughout these six Florida Keys regions in an attempt to assess spatial differences in DOM sources. Our data suggests that while DOM in the Florida Keys can be influenced by distant terrestrial environments such as the Everglades, spatial differences in DOM distribution were also controlled in part by local surface runoff/fringe mangroves, contributions from seasgrass communities, as well as the reefs and waters from the Florida Current. Application of principal component analysis (PCA) of the relative abundance of EEM-PARAFAC components allowed for a clear distinction between the sources of DOM (allochthonous vs. autochthonous), between different autochthonous sources and/or the diagenetic status of DOM, and further clarified contribution of terrestrial DOM in zones where levels of DOM were low in abundance. The combination between EEM-PARAFAC and PCA proved to be ideally suited to discern DOM composition and source differences in coastal zones with complex hydrology and multiple DOM sources.
Tracing subducted crustal materials in the mantle by using magnesium isotopes
NASA Astrophysics Data System (ADS)
Teng, F. Z.
2016-12-01
Recent studies show that some continental basalt, mantle-metasomatised peridotite and cratonic eclogite have heterogeneous Mg isotopic compositions. These isotopically distinct Mg isotopic compositions have been explained by the incorporation of subducted materials in their mantle sources though the detailed mechanisms are still not well understood. In particular, how Mg-poor crustal materials can modify Mg isotopic systematics of Mg-rich mantle is unknown. Subduction zones are the most efficient sites for crust and mantle interactions, hence should be where the most prominent Mg isotopic variation occurs. However, to date, little is known on Mg isotope systematics in the subduction factory. Here I first review and report new Mg isotopic data for arc lava, subarc peridotite and the subducted slab (marine sediment, altered basalt and abyssal peridotite), then use them to constrain the origins of mantle Mg isotopic heterogeneity and lay the foundation for using Mg isotopes as new tools for tracing crust-mantle interactions. The main conclusions are 1) fluid-rock interactions can modify Mg isotopic systematics of abyssal peridotites; 2) island arc lavas have non-MORB Mg isotopic compositions, reflecting distinct surbarc mantle Mg isotopic signature; 3) continental arcs have non-MORB Mg isotopic compositions, likely resulting from crustal contamination and 4) the isotopically heterogeneous continental basalts are mainly produced by mixing of isotopically distinct magmas instead of being partial melting products of metasomatised mantle peridotites.
21 CFR 165.110 - Bottled water.
Code of Federal Regulations, 2012 CFR
2012-04-01
..., when a composite of analytical units of equal volume from a sample is examined by the method described...)(A) Bottled water shall, when a composite of analytical units of equal volume from a sample is..., and Cosmetic Act, the Food and Drug Administration has determined that bottled water, when a composite...
Langford, Caitlin R; Johnson, David W; Cameron, Neil R
2015-05-01
Emulsion-templated highly porous polymers (polyHIPEs), containing distinct regions differing in composition, morphology, and/or properties, are prepared by the simultaneous polymerization of two high internal phase emulsions (HIPEs) contained within the same mould. The HIPEs are placed together in the mould and subjected to thiol-acrylate photopolymerization. The resulting polyHIPE material is found to contain two distinct semicircular regions, reflecting the composition of each HIPE. The original interface between the two emulsions becomes a copolymerized band between 100 and 300 μm wide, which is found to be mechanically robust. The separate polyHIPE layers are distinguished from one another by their differing average void diameter, chemical composition, and extent of contraction upon drying. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Complex network approach to classifying classical piano compositions
NASA Astrophysics Data System (ADS)
Xin, Chen; Zhang, Huishu; Huang, Jiping
2016-10-01
Complex network has been regarded as a useful tool handling systems with vague interactions. Hence, numerous applications have arised. In this paper we construct complex networks for 770 classical piano compositions of Mozart, Beethoven and Chopin based on musical note pitches and lengths. We find prominent distinctions among network edges of different composers. Some stylized facts can be explained by such parameters of network structures and topologies. Further, we propose two classification methods for music styles and genres according to the discovered distinctions. These methods are easy to implement and the results are sound. This work suggests that complex network could be a decent way to analyze the characteristics of musical notes, since it could provide a deep view into understanding of the relationships among notes in musical compositions and evidence for classification of different composers, styles and genres of music.
Microplastics alter composition of fungal communities in aquatic ecosystems.
Kettner, Marie Therese; Rojas-Jimenez, Keilor; Oberbeckmann, Sonja; Labrenz, Matthias; Grossart, Hans-Peter
2017-11-01
Despite increasing concerns about microplastic (MP) pollution in aquatic ecosystems, there is insufficient knowledge on how MP affect fungal communities. In this study, we explored the diversity and community composition of fungi attached to polyethylene (PE) and polystyrene (PS) particles incubated in different aquatic systems in north-east Germany: the Baltic Sea, the River Warnow and a wastewater treatment plant. Based on next generation 18S rRNA gene sequencing, 347 different operational taxonomic units assigned to 81 fungal taxa were identified on PE and PS. The MP-associated communities were distinct from fungal communities in the surrounding water and on the natural substrate wood. They also differed significantly among sampling locations, pointing towards a substrate and location specific fungal colonization. Members of Chytridiomycota, Cryptomycota and Ascomycota dominated the fungal assemblages, suggesting that both parasitic and saprophytic fungi thrive in MP biofilms. Thus, considering the worldwide increasing accumulation of plastic particles as well as the substantial vector potential of MP, especially these fungal taxa might benefit from MP pollution in the aquatic environment with yet unknown impacts on their worldwide distribution, as well as biodiversity and food web dynamics at large. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.
Foreign-born Peers and Academic Performance.
Conger, Dylan
2015-04-01
The academic performance of foreign-born youth in the United States is well studied, yet little is known about whether and how foreign-born students influence their classmates. In this article, I develop a set of expectations regarding the potential consequences of immigrant integration across schools, with a distinction between the effects of sharing schools with immigrants who are designated as English language learners (ELL) and those who are not. I then use administrative data on multiple cohorts of Florida public high school students to estimate the effect of immigrant shares on immigrant and native-born students' academic performance. The identification strategy pays careful attention to the selection problem by estimating the effect of foreign-born peers from deviations in the share foreign-born across cohorts of students attending the same school in different years. The assumption underlying this approach is that students choose schools based on the composition of the entire school, not on the composition of each entering cohort. The results of the analysis, which hold under several robustness checks, indicate that foreign-born peers (both those who are ELL and those who are non-ELL) have no effect on their high school classmates' academic performance.
Nature of the "Orange" Material on Vesta From Dawn
NASA Technical Reports Server (NTRS)
LeCorre, L.; Reddy, V.; Schmedemann, N.; Becker, K. J.; OBrien, D. P.; Yamashita, N.; Peplowski, P. N.; Prettyman, T. H.; Li, J.-Y.; Coultis, E. A.;
2014-01-01
From ground-based observations of Vesta, it is well-known that the vestan surface has a large variation in albedo. Analysis of images acquired by the Hubble Space Telescope allowed production of the first color maps of Vesta and showed a diverse surface in terms of reflectance. Thanks to images collected by the Dawn spacecraft at Vesta, it became obvious that these specific units observed previously can be linked to geological features. The presence of the darkest material mostly around impact craters and scattered in the Western hemisphere has been associated with carbonaceous chondrite contamination [4]; whereas the brightest materials are believed to result from exposure of unaltered material from the subsurface of Vesta (in fresh looking impact crater rims and in Rheasilvia's ejecta and rim remants). Here we focus on a distinct material characterized by a steep slope in the near-IR relative to all other kinds of materials found on Vesta. It was first detected when combining Dawn Framing Camera (FC) color images in Clementine false-color composites [5] during the Approach phase of the mission (100000 to 5200 km from Vesta). We investigate the mineralogical and elemental composition of this material and its relationship with the HEDs (Howardite-Eucrite- Diogenite group of meteorites).
NASA Astrophysics Data System (ADS)
Polo, L. A.; Janasi, V. A.; Giordano, D.; Lima, E. F.; Cañon-Tapia, E.; Roverato, M.
2018-04-01
Lava flows and dome complexes of silicic composition were identified in the Lower Cretaceous Paraná Magmatic Province (PMP) at Rio Grande do Sul state, southern Brazil. Detailed mapping and image analysis reveals significant volumes of effusive deposits aligned according to main lineaments, likely representing the fissural systems that fed the three Palmas-type silicic units. Different structures indicative of effusive emplacement (lava domes, lobated flows, sheet flows and autobreccias) are very common in the study area, and are probably also more abundant than previously thought in whole PMP silicic magmatism. In fact, effusive deposits seem predominant in the three distinct silicic units identified in the area, since no remnants of pyroclastic components have been identified. The vitreous dacites that make up the upper flows of the basaltic andesite to dacite Barros Cassal sequence are clearly effusive, as indicated by their occurrence as thin sheet flows. The much thicker early Caxias do Sul dacites occur mostly as lava flow lobes and pancake-like, of low to moderate viscosity, and lava domes. The younger, high SiO2 Santa Maria rhyolite unit shows unequivocal examples of effusive deposits at its lower portion, as lobated flows formed by vesicle-rich obsidian. In spite of higher viscosities relative to the previous units ( 106 Pa·s), it is probable that the very low H2O contents 1 wt% of these rhyolite melts, associated with high discharge rates, resulted in an effusive nature in most to this unit.
NASA Astrophysics Data System (ADS)
Clausen, B. L.; Martínez Ardila, A. M.; Morton, D. M.
2010-12-01
An extensive geochemical data set from the northern Peninsular Ranges Batholith (PRB) in southern California is compared and contrasted with the Arequipa segment of the Peruvian Coastal Batholith, including new granitoid samples recently collected near Ica (14°S, 76°W). The data include major and trace elements and Sr isotope ratios. This is part of an on-going study of subduction-related magmatism to refine a petrogenetic model of crust formation at plate boundaries, with a particular interest in the role of magma mixing. Research in the northern PRB suggests that continental crust is formed in several cycles: (1) mantle melting to give mafic volcanics and gabbroic intrusives, (2) basalt/gabbro melting to give felsic granitoids uncontaminated by continental crust and having low initial 87Sr/86Sr (Sri) values less than 0.704, and (3) crustal melting to give high Sri values greater than 0.704. Geochemical evidence was used to determine the extent of mixing between mafic and felsic magma that produced rocks of intermediate SiO2 composition. These differentiation cycles formed a west to east chronologic sequence and yielded granitoids of gabbro, tonalite, and granodiorite composition. Using principal component analysis on the northern PRB granitoids, the four factors affecting geochemical composition were categorized as differentiation, crustal contamination, depth of magma source, and conditions that yield a range from calcic to more alkaline granitoids. A similar major and trace element analysis is being done for a classic result of subduction in the Peruvian Coastal Batholith. The Peruvian samples recently collected include granitoids of the upper Cretaceous Coastal Batholith, as well as the associated volcanics of Cretaceous and Jurassic age. The Coastal Batholith samples include a range of granitoids from the early gabbros and from the four batholithic super-units (from west to east: Linga, Pampahuasi, Tiabaya, and Incahuasi) containing a combination of diorite, tonalite, monzonite, and granodiorite. In addition, samples were taken from the adjacent Precambrian basement and Paleozoic San Nicolas batholith in order to estimate the local geochemistry for continental crust contamination and to compare with published crustal averages. For this part of the Coastal Batholith, gabbroic plutons that formed during extension have little contamination from continental crust; the time-separated super-units form distinct assemblages; some of the super-units went through several differentiation cycles; parts of the Linga super-unit have low Sri ratios below 0.704; and magma mixing played an important role. The Coastal Batholith of western Peru (similar to the eastern PRB) has an intermediate calc-alkaline composition, in comparison to batholiths in Chile (similar to the western PRB) that are more calcic and those in eastern Peru (similar to the Sierra Nevadas) that are more alkaline.
USDA-ARS?s Scientific Manuscript database
Soil organic matter (SOM) contributes to soil processes and is found both in shallow and deep soil layers. Its activity can be affected by its chemical composition, yet knowledge is incomplete of how land use alters the structural composition of SOM throughout the profiles of different soil types. T...
Highly birefringent polymer microstructured optical fibers embedded in composite materials
NASA Astrophysics Data System (ADS)
Lesiak, P.; SzelÄ g, M.; Kuczkowski, M.; Domański, A. W.; Woliński, T. R.
2013-05-01
Composite structures are made from two or more constituent materials with significantly different physical or chemical properties and they remain separate and distinct in a macroscopic level within the finished structure. This feature allows for introducing highly birefringent polymer microstructured optical fibers into the composite material. These new fibers can consist of only two polymer materials (PMMA and PC) with similar value of the Young modulus as the composite material so any stresses induced in the composite material can be easily measured by the proposed embedded fiber optic sensors.
Mass coral bleaching causes biotic homogenization of reef fish assemblages.
Richardson, Laura E; Graham, Nicholas A J; Pratchett, Morgan S; Eurich, Jacob G; Hoey, Andrew S
2018-04-06
Global climate change is altering community composition across many ecosystems due to nonrandom species turnover, typically characterized by the loss of specialist species and increasing similarity of biological communities across spatial scales. As anthropogenic disturbances continue to alter species composition globally, there is a growing need to identify how species responses influence the establishment of distinct assemblages, such that management actions may be appropriately assigned. Here, we use trait-based analyses to compare temporal changes in five complementary indices of reef fish assemblage structure among six taxonomically distinct coral reef habitats exposed to a system-wide thermal stress event. Our results revealed increased taxonomic and functional similarity of previously distinct reef fish assemblages following mass coral bleaching, with changes characterized by subtle, but significant, shifts toward predominance of small-bodied, algal-farming habitat generalists. Furthermore, while the taxonomic or functional richness of fish assemblages did not change across all habitats, an increase in functional originality indicated an overall loss of functional redundancy. We also found that prebleaching coral composition better predicted changes in fish assemblage structure than the magnitude of coral loss. These results emphasize how measures of alpha diversity can mask important changes in the structure and functioning of ecosystems as assemblages reorganize. Our findings also highlight the role of coral species composition in structuring communities and influencing the diversity of responses of reef fishes to disturbance. As new coral species configurations emerge, their desirability will hinge upon the composition of associated species and their capacity to maintain key ecological processes in spite of ongoing disturbances. © 2018 John Wiley & Sons Ltd.
NASA Astrophysics Data System (ADS)
Clynne, M. A.
2011-12-01
Cinder Cone, in Lassen Volcanic National Park, has received considerable attention in the literature since its description by Harkness (1875) and Diller (1891) and has provoked considerable controversy concerning its age and eruptive history (e.g. Finch and Anderson, 1930; Finch, 1937). Geologic mapping of the composite cinder cone, an extensive tephra blanket, and 5 lava flows determined the eruptive sequence stratigraphy (Clynne and Muffler, 2010), and tree-ring chronology dated the eruption as 1666 C.E. (Sheppard et al., 2008). Tephra, divided into 3 units by Heiken (1978), accounts for 20% of the 0.36 km3 total volume of the eruption. The lava field consists of 5 block lava flows: Old Bench (OB), Painted Dunes (PD) 1 and 2, and Fantastic Lava Beds (FL) 1 and 2. Magnesian olivine containing inclusions of chromian spinel is the most abundant phenocryst, followed by plagioclase and sparse augite. Xenocrystic quartz is ubiquitous. Three types of inclusions are present: 1) sparse, mostly melted, inclusions of granitic rocks derived from Sierran basement, 2) abundant single crystals of quartz derived from granitic rocks and multicrystalline inclusions of metamorphic quartz from veins, and 3) rare magmatic enclaves of olivine basalt with quenched textures. The tephra and OB, PD, and FL lithologies are olivine basaltic andesite to andesite with subtle differences. Analyses of tephra from a measured section document the compositional evolution of Cinder Cone eruption. Unit 1 tephra contains 55.5% SiO2, 7.9% MgO, and 1.25% K2O. Initial unit 2 tephra contains 54.8% SiO2, 8.2% MgO, and 1.2% K2O. Unit 2 tephra becomes increasing more mafic up section to 53.8% SiO2, 9.0% MgO, and 1.0% K2O and then rapidly more felsic to 56.3% SiO2, 8.0% MgO, and 1.3% K2O. Initial unit 3 tephra contains 58.0% SiO2, 7.5% MgO, and 1.6% K2O but becomes more mafic to 55.0% SiO2, 7.5% MgO, and 1.2% K2O up section. The OB flow and the early PD 1 flow are equivalent in composition to the early unit 2 tephra, and the subsequent late PD 1 flow and PD 2 flows mimic late unit 2 tephra. FL 1 and 2 flows are compositionally equivalent to early and late unit 3 tephra, respectively. A mostly destroyed remnant cinder cone has unit 2 tephra composition, and Cinder Cone has unit 3 composition. The complex compositional variation at Cinder Cone, superficially a monogenetic volcano, is ascribed to the combined effects of fractional crystallization and assimilation and concurrent recharge of the system by a new mafic magma. Variation of the early magmas can be modeled by fractional crystallization and assimilation of granitic xenoliths. The reversal of compositional variation near the unit 2-3 boundary and subsequent decrease in SiO2 can be modeled by mixing with a new mafic magma having the composition of the quenched basaltic enclaves. Details of the mineral compositions are consistent with the stratigraphy and bulk compositional evolution.
NASA Astrophysics Data System (ADS)
Sinton, John; Bergmanis, Eric; Rubin, Ken; Batiza, Rodey; Gregg, Tracy K. P.; Grönvold, Karl; Macdonald, Ken C.; White, Scott M.
2002-06-01
Side-scan sonar, submersible observations and sampling of lava flows from the East Pacific Rise, 17°-19°S constrain the character and variability of submarine volcanic eruptions along mid-ocean ridges. Nine separate lava sequences were mapped using relative age and lithological contrasts among recovered samples. Axial lengths activated during eruptive episodes range from ~1 to >18 km; individual flow field areas vary from <1 to >19 km2. Estimated erupted volumes range from <1 to >200 × 106 m3. The largest unit is the chemically uniform Animal Farm lava near 18°37'S. The youngest lava is the Aldo-Kihi flow field, 17°24'-34'S, probably erupted in the early 1990s from a fissure system extending >18 km along axis. Near 18°33'S two distinct lava compositions with uniform sediment cover were recovered from lava that buries older faulted terrain. The boundary in lava composition coincides with a change in depth to the top of an axial magma lens seismic reflector, consistent with magmas from two separate reservoirs being erupted in the same event. Chemical compositions from throughout the area indicate that lavas with identical compositions can be emplaced in separate volcanic eruptions within individual segments. A comparison of our results to global data on submarine mid-ocean ridge eruptions suggests consistent dependencies of erupted volume, activated fissure lengths, and chemical heterogeneity with spreading rate, consistent with expected eruptive characteristics from ridges with contrasting thermal properties and magma reservoir depths.
31 CFR 601.4 - Use of paper; interest-bearing securities of the United States.
Code of Federal Regulations, 2010 CFR
2010-07-01
... PAPER FOR UNITED STATES CURRENCY AND OTHER SECURITIES § 601.4 Use of paper; interest-bearing securities of the United States. The existing distinctive papers shall be used for the printing of interest...
Multiscale mechanics of graphene oxide and graphene based composite films
NASA Astrophysics Data System (ADS)
Cao, Changhong
The mechanical behavior of graphene oxide is length scale dependent: orders of magnitude different between the bulk forms and monolayer counterparts. Understanding the underlying mechanisms plays a significant role in their versatile application. A systematic multiscale mechanical study from monolayer to multilayer, including the interactions between layers of GO, can provide fundamental support for material engineering. In this thesis, an experimental coupled with simulation approach was used to study the multiscale mechanics of graphene oxide (GO) and the methods developed for GO study are proved to be applicable also to mechanical study of graphene based composites. GO is a layered nanomaterial comprised of hierarchical units whose characteristic dimension lies between monolayer GO (0.7 nm - 1.2 nm) and bulk GO papers (≥ 1 mum). Mechanical behaviors of monolayer GO and GO nanosheets (10 nm- 100 nm) were comprehensively studied this work. Monolayer GO was measured to have an average strength of 24.7 GPa,, orders of magnitude higher than previously reported values for GO paper and approximately 50% of the 2D intrinsic strength of pristine graphene. The huge discrepancy between the strength of monolayer GO and that of bulk GO paper motivated the study of GO at the intermediate length scale (GO nanosheets). Experimental results showed that GO nanosheets possess high strength in the gigapascal range. Molecular Dynamic simulations showed that the transition in the failure behavior from interplanar fracture to intraplanar fracture was responsible for the huge strength discrepancy between nanometer scale GO and bulk GO papers. Additionally, the interfacial shear strength between GO layers was found to be a key contributing factor to the distinct mechanical behavior among hierarchical units of GO. The understanding of the multiscale mechanics of GO is transferrable in heterogeneous layered nanomaterials, such as graphene-metal oxide based anode materials in Li-ion batteries. The novel methods developed in this work to study GO multilayered structures were also applied to study the mechanics of graphene-TiO 2 composites. It was found that a critical thickness range of TiO2 deposition on graphene is required for the observed stiffness enhancement effect of graphene to influence the mechanical behavior of the composite.
NASA Astrophysics Data System (ADS)
Rudnick, R. L.; Liu, X.
2011-12-01
The continental crust has an "intermediate" bulk composition that is distinct from primary melts of peridotitic mantle (basalt or picrite). This mismatch between the "building blocks" and the "edifice" of the continental crust points to the operation of processes that preferentially remove mafic to ultramafic material from the continents. Such processes include lower crustal recycling (via density foundering or lower crustal subduction - e.g., relamination, Hacker et al., 2011, EPSL), generation of evolved melts via slab melting, and/or chemical weathering. Stable isotope systems document the influence of chemical weathering on the bulk crust composition: the oxygen isotope composition of the bulk crust is distinctly heavier than that of primary, mantle-derived melts (Simon and Lecuyer, 2005, G-cubed) and the Li isotopic composition of the bulk crust is distinctly lighter than that of mantle-derive melts (Teng et al., 2004, GCA; 2008, Chem. Geol.). Both signatures mark the imprint of chemical weathering on the bulk crust composition. Here, we use a simple mass balance model for lithium inputs and outputs from the continental crust to quantify the mass lost due to chemical weathering. We find that a minimum of 15%, a maximum of 60%, and a best estimate of ~40% of the original juvenile rock mass may have been lost via chemical weathering. The accumulated percentage of mass loss due to chemical weathering leads to an average global chemical weathering rate (CWR) of ~ 8×10^9 to 2×10^10 t/yr since 3.5 Ga, which is about an order of magnitude higher than the minimum estimates based on modern rivers (Gaillardet et al., 1999, Chem. Geol.). While we cannot constrain the exact portion of crustal mass loss via chemical weathering, given the uncertainties of the calculation, we can demonstrate that the weathering flux is non-zero. Therefore, chemical weathering must play a role in the evolution of the composition and mass of the continental crust.
Cope, Emily K; Goldberg, Andrew N; Pletcher, Steven D; Lynch, Susan V
2017-05-12
Chronic rhinosinusitis (CRS) is a heterogeneous disease characterized by persistent sinonasal inflammation and sinus microbiome dysbiosis. The basis of this heterogeneity is poorly understood. We sought to address the hypothesis that a limited number of compositionally distinct pathogenic bacterial microbiota exist in CRS patients and invoke discrete immune responses and clinical phenotypes in CRS patients. Sinus brushings from patients with CRS (n = 59) and healthy individuals (n = 10) collected during endoscopic sinus surgery were analyzed using 16S rRNA gene sequencing, predicted metagenomics, and RNA profiling of the mucosal immune response. We show that CRS patients cluster into distinct sub-groups (DSI-III), each defined by specific pattern of bacterial co-colonization (permutational multivariate analysis of variance (PERMANOVA); p = 0.001, r 2 = 0.318). Each sub-group was typically dominated by a pathogenic family: Streptococcaceae (DSI), Pseudomonadaceae (DSII), Corynebacteriaceae [DSIII(a)], or Staphylococcaceae [DSIII(b)]. Each pathogenic microbiota was predicted to be functionally distinct (PERMANOVA; p = 0.005, r 2 = 0.217) and encode uniquely enriched gene pathways including ansamycin biosynthesis (DSI), tryptophan metabolism (DSII), two-component response [DSIII(b)], and the PPAR-γ signaling pathway [DSIII(a)]. Each is also associated with significantly distinct host immune responses; DSI, II, and III(b) invoked a variety of pro-inflammatory, T H 1 responses, while DSIII(a), which exhibited significantly increased incidence of nasal polyps (Fisher's exact; p = 0.034, relative risk = 2.16), primarily induced IL-5 expression (Kruskal Wallis; q = 0.045). A large proportion of CRS patient heterogeneity may be explained by the composition of their sinus bacterial microbiota and related host immune response-features which may inform strategies for tailored therapy in this patient population.
Svensson, Erik; Jensen, Elsebeth Tvenstrup; Rasmussen, Erik Michael; Folkvardsen, Dorte Bek; Norman, Anders; Lillebaek, Troels
2017-03-01
Mycobacterium chimaera was present at high rates (>80%) in heater-cooler units (HCUs) from all 5 thoracic surgery departments in Denmark. Isolates were clonal to HCU-associated isolates from the United States (including some from patients) and United Kingdom. However, M. chimaera from 2 brands of HCU were genetically distinct.
ERIC Educational Resources Information Center
Wadlinger, Robert L.
1983-01-01
SI units come in two distinct types: fundamental (kilogram, meter) and descriptive (atom, molecule). Proper/improper uses of atom/molecule from historical cases are presented followed by a re-introduction of a light "wave (cycle)" unit and the clearly defined photon model which is deduced. Also examines omission of the fundamental unit "radon."…
Zhu, Junya; Li, Liping; Zhao, Hailei; Han, Guangshu; Wu, Albert W; Weingart, Saul N
2014-10-01
Existing patient safety climate instruments, most of which have been developed in the USA, may not accurately reflect the conditions in the healthcare systems of other countries. To develop and evaluate a patient safety climate instrument for healthcare workers in Chinese hospitals. Based on a review of existing instruments, expert panel review, focus groups and cognitive interviews, we developed items relevant to patient safety climate in Chinese hospitals. The draft instrument was distributed to 1700 hospital workers from 54 units in six hospitals in five Chinese cities between July and October 2011, and 1464 completed surveys were received. We performed exploratory and confirmatory factor analyses and estimated internal consistency reliability, within-unit agreement, between-unit variation, unit-mean reliability, correlation between multi-item composites, and association between the composites and two single items of perceived safety. The final instrument included 34 items organised into nine composites: institutional commitment to safety, unit management support for safety, organisational learning, safety system, adequacy of safety arrangements, error reporting, communication and peer support, teamwork and staffing. All composites had acceptable unit-mean reliabilities (≥0.74) and within-unit agreement (Rwg ≥0.71), and exhibited significant between-unit variation with intraclass correlation coefficients ranging from 9% to 21%. Internal consistency reliabilities ranged from 0.59 to 0.88 and were ≥0.70 for eight of the nine composites. Correlations between composites ranged from 0.27 to 0.73. All composites were positively and significantly associated with the two perceived safety items. The Chinese Hospital Survey on Patient Safety Climate demonstrates adequate dimensionality, reliability and validity. The integration of qualitative and quantitative methods is essential to produce an instrument that is culturally appropriate for Chinese hospitals. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.
[Response to US review rules on patent subject matter of traditional Chinese medicine compositions].
Liu, Pan; Cao, Ya-di; Gong, Rui-Juan; Liu, Wei
2018-02-01
The United States Patent and Trademark Office(USPTO) issued Interim Guidance on Patent Subject Matter Eligibility on December 16, 2014, bringing certain effects to the review rules on patent application of Chinese medicine compositions. Based on the Interim Guidance, cases analysis was used in this paper to analyze the patent subject matter issues of traditional Chinese medicine compositions in the United States. The researches have shown that the application documents should be properly written in the United States when the patent for Chinese medicine compositions is applied, which can improve the probability of authorization. Copyright© by the Chinese Pharmaceutical Association.
Cekic-Nagas, Isil; Egilmez, Ferhan; Ergun, Gulfem
2010-01-01
Objectives: The aim of this study was to compare the microhardness of five different resin composites at different irradiation distances (2 mm and 9 mm) by using three light curing units (quartz tungsten halogen, light emitting diodes and plasma arc). Methods: A total of 210 disc-shaped samples (2 mm height and 6 mm diameter) were prepared from different resin composites (Simile, Aelite Aesthetic Enamel, Clearfil AP-X, Grandio caps and Filtek Z250). Photoactivation was performed by using quartz tungsten halogen, light emitting diode and plasma arc curing units at two irradiation distances (2 mm and 9 mm). Then the samples (n=7/per group) were stored dry in dark at 37°C for 24 h. The Vickers hardness test was performed on the resin composite layer with a microhardness tester (Shimadzu HMV). Data were statistically analyzed using nonparametric Kruskal Wallis and Mann-Whitney U tests. Results: Statistical analysis revealed that the resin composite groups, the type of the light curing units and the irradiation distances have significant effects on the microhardness values (P<.05). Conclusions: Light curing unit and irradiation distance are important factors to be considered for obtaining adequate microhardness of different resin composite groups. PMID:20922164
Muffler, L.J.P.; Clynne, M.A.; Calvert, A.T.; Champion, D.E.
2011-01-01
The Poison Lake chain consists of small, monogenetic, calc-alkaline basaltic volcanoes located east of the Cascade arc axis, 30 km ENE of Lassen Peak in northeastern California. This chain consists of 39 distinguishable units in a 14-km-long and 2-kmwide zone trending NNW, parallel to nearby Quaternary normal faults. The 39 units fall into nine coherent groups based on stratigraphy, field characteristics, petrography, and major-element compositions. Petrographic differences among groups are expressed by different amounts and proportions of phenocrysts. MgO-SiO 2, K 2O-SiO 2, and TiO 2-SiO 2 variation diagrams illustrate clear differences in compatible and incompatible elements among the groups. Variation of K 2O/ TiO 2 and K 2O/P 2O 5 with MgO indicates that most of the basalts of the Poison Lake chain cannot be related by crystal fractionation at different pressures and that compositions have not been affected significantly by incorporation of low-degree silicic crustal melt or interaction with sialic crust. Limited traceelement and whole-rock isotopic data also suggest little if any incorporation of uppercrustal material, and that compositional variation among groups primarily reflects source compositional differences. Precise 40Ar/ 39Ar determinations show that the lavas were erupted between 100 and 110 ka. The migration of paleomagnetic remanent directions over 30?? suggests that the entire Poison Lake chain could represent three short-lived episodes of volcanism within a period as brief as 500 yr. The diverse geologic, petrographic, chemical, paleomagnetic, and age data indicate that each of the nine groups represents a small, discrete magma batch generated in the mantle and stored briefly in the lower crust. A NNW normal fault zone provided episodic conduits that allowed rapid ascent of these batches to the surface, where they erupted as distinct volcanic groups, each aligned along a segment of the Poison Lake chain. Compositional diversity of these primitive magmas argues against widespread, long-lived ponding of uniform basalt magma at the base of the crust in this region and against interaction with a zone of melting, assimilation, storage, and homogenization (MASH) in the lower crust. ?? 2011 Geological Society of America.
Beta-diversity of ectoparasites at two spatial scales: nested hierarchy, geography and habitat type.
Warburton, Elizabeth M; van der Mescht, Luther; Stanko, Michal; Vinarski, Maxim V; Korallo-Vinarskaya, Natalia P; Khokhlova, Irina S; Krasnov, Boris R
2017-06-01
Beta-diversity of biological communities can be decomposed into (a) dissimilarity of communities among units of finer scale within units of broader scale and (b) dissimilarity of communities among units of broader scale. We investigated compositional, phylogenetic/taxonomic and functional beta-diversity of compound communities of fleas and gamasid mites parasitic on small Palearctic mammals in a nested hierarchy at two spatial scales: (a) continental scale (across the Palearctic) and (b) regional scale (across sites within Slovakia). At each scale, we analyzed beta-diversity among smaller units within larger units and among larger units with partitioning based on either geography or ecology. We asked (a) whether compositional, phylogenetic/taxonomic and functional dissimilarities of flea and mite assemblages are scale dependent; (b) how geographical (partitioning of sites according to geographic position) or ecological (partitioning of sites according to habitat type) characteristics affect phylogenetic/taxonomic and functional components of dissimilarity of ectoparasite assemblages and (c) whether assemblages of fleas and gamasid mites differ in their degree of dissimilarity, all else being equal. We found that compositional, phylogenetic/taxonomic, or functional beta-diversity was greater on a continental rather than a regional scale. Compositional and phylogenetic/taxonomic components of beta-diversity were greater among larger units than among smaller units within larger units, whereas functional beta-diversity did not exhibit any consistent trend regarding site partitioning. Geographic partitioning resulted in higher values of beta-diversity of ectoparasites than ecological partitioning. Compositional and phylogenetic components of beta-diversity were higher in fleas than mites but the opposite was true for functional beta-diversity in some, but not all, traits.
Cultivating a Reflective Approach to Language Difference in Composition Pedagogy
ERIC Educational Resources Information Center
Bommarito, Daniel V.; Cooney, Emily
2016-01-01
This essay addresses the persistence of monolingual tendencies in composition pedagogy and the critical efforts needed to dissolve them. Approaching language difference from a distinctly pedagogical perspective, this essay draws on the authors' teaching experiences and reflective writing in an effort to theorize the reflective practices key to…
Assessing Zones of Low Radar Reflectivity Across the South Polar Cap of Mars
NASA Astrophysics Data System (ADS)
Putzig, N. E.; Smith, I. B.; Whitten, J. L.; Campbell, B. A.
2017-12-01
The Mars Reconnaissance Orbiter Shallow Radar (SHARAD) revealed near-surface zones of low radar reflectivity (reflection-free zones, RFZs) in many areas of Planum Australe (Phillips et al., 2011, Science 332). The most poleward, RFZ3, corresponds geographically to geologic unit AA3 (Tanaka et al., 2007, 7th Int'l Mars Conf. abs. 3276) that exhibits sublimation features. Geometric considerations demonstrated that RFZ3 consists of three distinct layers of CO2 ice, preserved from earlier periods of atmospheric collapse (Bierson et al., 2016, GRL 43). However, the nature of other RFZs at lower latitudes remains undetermined, with none of the SHARAD observations examined to date providing definitive geometric constraints on their composition. While CO2-ice composition has not been ruled out, these RFZs differ in important ways from RFZ3. Surface imagery in the vicinity of the outlying RFZs does not generally exhibit sublimation features similar to those seen in AA3, SHARAD reflectivity exhibits a lower contrast with surrounding materials relative to RFZ3, and there are no indications of distinct layering within the outlying RFZs as there are in RFZ3. In addition, climate modeling of atmospheric collapse episodes (Wood et al., 2016, LPSC abs. 3074) suggests that CO2 accumulation is highly concentrated at the highest latitudes. An alternative explanation for the outlying RFZs is that they consist of nearly pure water ice deposited during times when atmospheric dust was nearly absent. Such conditions may occur coeval with eras of CO2 accumulation at the higher latitudes. To test these possibilities, we are working to constrain the composition of the outlying RFZs, using the recently produced 3-D SHARAD data volume that encompasses the entire Martian south polar ice cap (Foss et al., 2017, The Leading Edge, 36). Work is ongoing, but we expect that the geometric corrections and improvements to the overall signal-to-noise ratio provided by the 3-D radar imaging processing may now allow us to distinguish between CO2 and H2O composition, perhaps by enhancing faint layering that extends below the outlying RFZs. First looks at data in Promethei Lingula show promise for applying this method to the RFZ found there, but a loss of vertical resolution in the 3D volume relative to the 2D single-orbit observations complicates the analysis.
NASA Astrophysics Data System (ADS)
Potter, Katherine E.; Shervais, John W.; Christiansen, Eric H.; Vetter, Scott K.
2018-02-01
Basalts erupted in the Snake River Plain of central Idaho and sampled in the Kimama drill core link eruptive processes to the construction of mafic intrusions over 5.5 Ma. Cyclic variations in basalt composition reveal temporal chemical heterogeneity related to fractional crystallization and the assimilation of previously-intruded mafic sills. A range of compositional types are identified within 1912 m of continuous drill core: Snake River olivine tholeiite (SROT), low K SROT, high Fe-Ti, and evolved and high K-Fe lavas similar to those erupted at Craters of the Moon National Monument. Detailed lithologic and geophysical logs document 432 flow units comprising 183 distinct lava flows and 78 flow groups. Each lava flow represents a single eruptive episode, while flow groups document chemically and temporally related flows that formed over extended periods of time. Temporal chemical variation demonstrates the importance of source heterogeneity and magma processing in basalt petrogenesis. Low-K SROT and high Fe-Ti basalts are genetically related to SROT as, respectively, hydrothermally-altered and fractionated daughters. Cyclic variations in the chemical composition of Kimama flow groups are apparent as 21 upward fractionation cycles, six recharge cycles, eight recharge-fractionation cycles, and five fractionation-recharge cycles. We propose that most Kimama basalt flows represent typical fractionation and recharge patterns, consistent with the repeated influx of primitive SROT parental magmas and extensive fractional crystallization coupled with varying degrees of assimilation of gabbroic to ferrodioritic sills at shallow to intermediate depths over short durations. Trace element models show that parental SROT basalts were generated by 5-10% partial melting of enriched mantle at shallow depths above the garnet-spinel lherzolite transition. The distinctive evolved and high K-Fe lavas are rare. Found at four depths, 319 m, 1045 m, 1078 m, and 1189 m, evolved and high K-Fe flows are compositionally unrelated to SROT magmas and represent highly fractionated basalt, probably accompanied by crustal assimilation. These evolved lavas may be sourced from the Craters of the Moon/Great Rift system to the northeast. The Kimama drill core is the longest record of geochemical variation in the central Snake River Plain and reinforces the concept of magma processing in a layered complex.
Enhancing the Mechanical Toughness of Epoxy-Resin Composites Using Natural Silk Reinforcements
Yang, Kang; Wu, Sujun; Guan, Juan; ...
2017-09-20
Strong and tough epoxy composites are developed using a less-studied fibre reinforcement, that of natural silk. Two common but structurally distinct silks from the domestic B. mori/Bm and the wild A. pernyi/Ap silkworms are selected in fabric forms. We show that the toughening effects on silk-epoxy composites or SFRPs are dependent on the silk species and the volume fraction of silk. Both silks enhance the room-temperature tensile and flexural mechanical properties of the composite, whereas the more resilient Ap silk shows a more pronounced toughening effect and a lower critical reinforcement volume for the brittle-ductile transition. Specifically, our 60 vol.%more » Ap-SFRP displays a three-fold elevation in tensile and flexural strength, as compared to pure epoxy resin, with an order of magnitude higher breaking energy via a distinct, ductile failure mode. Importantly, the 60 vol.% Ap-SFRP remains ductile with 7% flexural elongation at lower temperatures (-50 °C). Under impact, these SFRPs show significantly improved energy absorption, and the 60 vol.% Ap-SFRP has an impact strength some eight times that of pure epoxy resin. Lastly, the findings demonstrate both marked toughening and strengthening effects for epoxy composites from natural silk reinforcements, which presents opportunities for mechanically superior and "green" structural composites.« less
Computer-composite mapping for geologists
van Driel, J.N.
1980-01-01
A computer program for overlaying maps has been tested and evaluated as a means for producing geologic derivative maps. Four maps of the Sugar House Quadrangle, Utah, were combined, using the Multi-Scale Data Analysis and Mapping Program, in a single composite map that shows the relative stability of the land surface during earthquakes. Computer-composite mapping can provide geologists with a powerful analytical tool and a flexible graphic display technique. Digitized map units can be shown singly, grouped with different units from the same map, or combined with units from other source maps to produce composite maps. The mapping program permits the user to assign various values to the map units and to specify symbology for the final map. Because of its flexible storage, easy manipulation, and capabilities of graphic output, the composite-mapping technique can readily be applied to mapping projects in sedimentary and crystalline terranes, as well as to maps showing mineral resource potential. ?? 1980 Springer-Verlag New York Inc.
Fictional Narrative as Speech Event.
ERIC Educational Resources Information Center
Myers, Miles A.
The issue addressed in this paper is the relationship between form in fictional prose and form in other uses of language, particularly those uses important in composition theory. Form in composition theory has traditionally had two ways of identifying units of analysis: (1) the sentence and semantic units, and (2) pragmatic and rhetorical units.…
NASA Technical Reports Server (NTRS)
Foye, R. L.
1993-01-01
This report concerns the prediction of the elastic moduli and the internal stresses within the unit cell of a fabric reinforced composite. In the proposed analysis no restrictions or assumptions are necessary concerning yarn or tow cross-sectional shapes or paths through the unit cell but the unit cell itself must be a right hexagonal parallelepiped. All the unit cell dimensions are assumed to be small with respect to the thickness of the composite structure that it models. The finite element analysis of a unit cell is usually complicated by the mesh generation problems and the non-standard, adjacent-cell boundary conditions. This analysis avoids these problems through the use of preprogrammed boundary conditions and replacement materials (or elements). With replacement elements it is not necessary to match all the constitutional material interfaces with finite element boundaries. Simple brick-shaped elements can be used to model the unit cell structure. The analysis predicts the elastic constants and the average stresses within each constituent material of each brick element. The application and results of this analysis are demonstrated through several example problems which include a number of composite microstructures.
A new species of Deltaspis Audinet-Serville (Coleoptera: Cerambycidae: Cerambycinae) from Mexico.
Eya, Bryan K
2017-03-27
As currently defined, the genus Deltaspis Audinet-Serville, 1834, contains 16 species ranging in distribution from the southwestern United States to eastern Mexico. However, the generic distinction between Deltaspis and its closely allied genera, such as Crossidius LeConte, 1851 and Muscidora Thomson, 1864, is in need of clarification. According to Audinet-Serville, Deltaspis is so named due to its distinctive triangular scutellum (i.e., Δετα, delta, ασπιζ écusson), which is actually a commonly shared character of all these genera. Members of the tribe Trachyderini Dupont (1836), which includes the above genera, also have mandibles with an emarginate-truncate apex with the edge chisel-like or bifid. This modification of mouthpart appears to be for consumption of pollen and/or petals from composite flowers visited by the adult beetles (Krenn et al., 2005; Beierl & Barchet-Beierl, 1999). Other genera from this tribe with this modification of mandibles from North America, and mostly from Mexico, include: Chemsakiella Monné, 2006, Giesbertia Chemsak & Linsley, 1984, Hoegea Bates, 1885, Neocrossidius Chemsak, 1959, Paroxoplus Chemsak, 1959, Plionoma Casey, 1912, Schizax LeConte, 1873, and Tylosis LeConte, 1850. The remainder of Trachyderini genera have unmodified or simple mandibles with apex acute.
USDA-ARS?s Scientific Manuscript database
To evaluate whether commonly employed chemical treatments remove structurally distinct fractions of soil organic matter (SOM), a Mollic Xerofluvent under agricultural use was subjected to three distinct oxidation treatments: potassium permanganate (KMnO4), sodium hypochlorite (NaOCl), and hydrogen p...
Guan, Connie Qun; Ye, Feifei; Wagner, Richard K.; Meng, Wanjin; Leong, Che Kan
2014-01-01
The goal of the present study was to test opposing views about four issues concerning predictors of individual differences in Chinese written composition: (a) Whether morphological awareness, syntactic processing, and working memory represent distinct and measureable constructs in Chinese or are just manifestations of general language ability; (b) whether they are important predictors of Chinese written composition, and if so, the relative magnitudes and independence of their predictive relations; (c) whether observed predictive relations are mediated by text comprehension; and (d) whether these relations vary or are developmentally invariant across three years of writing development. Based on analyses of the performance of students in grades 4 (n = 246), 5 (n = 242) and 6 (n = 261), the results supported morphological awareness, syntactic processing, and working memory as distinct yet correlated abilities that made independent contributions to predicting Chinese written composition, with working memory as the strongest predictor. However, predictive relations were mediated by text comprehension. The final model accounted for approximately 75 percent of the variance in Chinese written composition. The results were largely developmentally invariant across the three grades from which participants were drawn. PMID:25530630
Ebel, J D; Leroux, S J; Robertson, M J; Dempson, J B
2016-11-01
Body-element content was measured for three life stages of wild Atlantic salmon Salmo salar from three distinct Newfoundland populations as individuals crossed between freshwater and marine ecosystems. Life stage explained most of the variation in observed body-element concentration whereas river of capture explained very little variation. Element composition of downstream migrating post-spawn adults (i.e. kelts) and juvenile smolts were similar and the composition of these two life stages strongly differed from adults migrating upstream to spawn. Low variation within life stages and across populations suggests that S. salar may exert rheostatic control of their body-element composition. Additionally, observed differences in trace element concentration between adults and other life stages were probably driven by the high carbon concentration in adults because abundant elements, such as carbon, can strongly influence the observed concentrations of less abundant elements. Thus, understanding variation among individuals in trace elements composition requires the measurement of more abundant elements. Changes in element concentration with ontogeny have important consequences the role of fishes in ecosystem nutrient cycling and should receive further attention. © 2016 The Fisheries Society of the British Isles.
Carstens, Julienne L; Correa de Sampaio, Pedro; Yang, Dalu; Barua, Souptik; Wang, Huamin; Rao, Arvind; Allison, James P; LeBleu, Valerie S; Kalluri, Raghu
2017-04-27
The exact nature and dynamics of pancreatic ductal adenocarcinoma (PDAC) immune composition remains largely unknown. Desmoplasia is suggested to polarize PDAC immunity. Therefore, a comprehensive evaluation of the composition and distribution of desmoplastic elements and T-cell infiltration is necessary to delineate their roles. Here we develop a novel computational imaging technology for the simultaneous evaluation of eight distinct markers, allowing for spatial analysis of distinct populations within the same section. We report a heterogeneous population of infiltrating T lymphocytes. Spatial distribution of cytotoxic T cells in proximity to cancer cells correlates with increased overall patient survival. Collagen-I and αSMA + fibroblasts do not correlate with paucity in T-cell accumulation, suggesting that PDAC desmoplasia may not be a simple physical barrier. Further exploration of this technology may improve our understanding of how specific stromal composition could impact T-cell activity, with potential impact on the optimization of immune-modulatory therapies.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smith, G.P.
The diversity and abundance of native grasses and herbaceous species characteristic of the longleaf savanna were compared between remnant stands that were not previously under agriculture and recent old-fields.The objective of the study was to establish a baseline for future restoration objectives and to compare the degree of degradation associated with agriculture. In most cases even the natural stands have suffered degradation as a result of fire exclusion and as such are not representative of pristine conditions. Community classification and ordination procedures were implemented to array the communities. Three distinct sub-units were identified and associated with xeric, sub-xeric, and medicmore » types associated with texture and soil moisture. Between plantations and natural stands, the xeric group demonstrated the most similarity. The presence of a B horizon was the most important discriminate variable in both groups.« less
The geologic history of Margaritifer basin, Mars
Salvatore, M. R.; Kraft, M. D.; Edwards, Christopher; Christensen, P.R.
2016-01-01
In this study, we investigate the fluvial, sedimentary, and volcanic history of Margaritifer basin and the Uzboi-Ladon-Morava (ULM) outflow channel system. This network of valleys and basins spans more than 8000 km in length, linking the fluvially dissected southern highlands and Argyre Basin with the northern lowlands via Ares Vallis. Compositionally, thermophysically, and morphologically distinct geologic units are identified and are used to place critical relative stratigraphic constraints on the timing of geologic processes in Margaritifer basin. Our analyses show that fluvial activity was separated in time by significant episodes of geologic activity, including the widespread volcanic resurfacing of Margaritifer basin and the formation of chaos terrain. The most recent fluvial activity within Margaritifer basin appears to terminate at a region of chaos terrain, suggesting possible communication between surface and subsurface water reservoirs. We conclude with a discussion of the implications of these observations on our current knowledge of Martian hydrologic evolution in this important region.
The geologic history of Margaritifer basin, Mars
NASA Astrophysics Data System (ADS)
Salvatore, M. R.; Kraft, M. D.; Edwards, C. S.; Christensen, P. R.
2016-03-01
In this study, we investigate the fluvial, sedimentary, and volcanic history of Margaritifer basin and the Uzboi-Ladon-Morava outflow channel system. This network of valleys and basins spans more than 8000 km in length, linking the fluvially dissected southern highlands and Argyre basin with the northern lowlands via Ares Vallis. Compositionally, thermophysically, and morphologically distinct geologic units are identified and are used to place critical relative stratigraphic constraints on the timing of geologic processes in Margaritifer basin. Our analyses show that fluvial activity was separated in time by significant episodes of geologic activity, including the widespread volcanic resurfacing of Margaritifer basin and the formation of chaos terrain. The most recent fluvial activity within Margaritifer basin appears to terminate at a region of chaos terrain, suggesting possible communication between surface and subsurface water reservoirs. We conclude with a discussion of the implications of these observations on our current knowledge of Martian hydrologic evolution in this important region.
29 CFR 779.203 - Distinction between “enterprise,” “establishment,” and “employer.”
Code of Federal Regulations, 2010 CFR
2010-07-01
... Apply; Enterprise Coverage Enterprise; the Business Unit § 779.203 Distinction between “enterprise... employee. (See § 779.19.) The term establishment means a distinct physical place of business rather than an entire business or enterprise. (See § 779.23.) The term enterprise was not used in the Act prior to the...
NASA Astrophysics Data System (ADS)
Fontana, D.; Lugli, S.; Marchetti Dori, S.; Caputo, R.; Stefani, M.
2015-07-01
In May 2012 widespread sand blows formed along buried channels in the eastern sector of the Po Plain (Northern Italy) as a consequence of a series of seismic events with main shocks of Mw 6.1 and 5.9. At San Carlo (Ferrara) a trench dug a few week after the earthquakes exposed sand dikes cutting through an old Reno River channel-levee system that was diverted in the 18th century and was deposited starting from the 14th century (unit A). This sequence overlies a Holocene muddy floodplain deposits and contains scattered sandy channel deposits (unit B) and a Pleistocene channel sand unit (unit C). Sands with inverse and normal grading, concave layering and vertical lamination coexisting along the dikes suggest multiple rhythmic opening and closing of the fractures that were injected and filled by a slurry of sand during the compression pulses, and emptied during the extension phase. The pulse mechanism may have lasted for several minutes and formed well stratified sand volcanoes structures that formed at the top of the fractures. Sands from dikes and from the various units show well defined compositional fields from lithoarenitic to quartz-feldspar-rich compositions. Sands from the old Reno levee and channel fill (unit A) have abundant lithic fragments derived from the erosion of Apennine sedimentary carbonate and terrigenous successions. Composition of the sand filling the dikes show clear affinities with sand layers of the old Reno River channel (Unit A) and clearly differ from any sand from deeper Holocene and Pleistocene layers (Unit B and C), which are richer in quartz and feldspar and poorer in sedimentary lithic fragments. Sorting related to sediment flux variations did not apparently affect the sand composition across the sedimentary structures. Textural and compositional data indicate that the liquefaction processes originated from a relatively shallow source consisting of channel sands located within Unit A at 6.8.to 7.5 m depth.
NASA Technical Reports Server (NTRS)
Podwysocki, M. H.; Bender, L. U.; Falcone, N.; Jones, O. D.
1983-01-01
Some LANDSAT thematic mapper data collected over the eastern United States were analyzed for their whole scene geometric accuracy, band to band registration and radiometric accuracy. Band ratio images were created for a part of one scene in order to assess the capability of mapping geologic units with contrasting spectral properties. Systematic errors were found in the geometric accuracy of whole scenes, part of which were attributable to the film writing device used to record the images to film. Band to band registration showed that bands 1 through 4 were registered to within one pixel. Likewise, bands 5 and 7 also were registered to within one pixel. However, bands 5 and 7 were misregistered with bands 1 through 4 by 1 to 2 pixels. Band 6 was misregistered by 4 pixels to bands 1 through 4. Radiometric analysis indicated two kinds of banding, a modulo-16 stripping and an alternate light dark group of 16 scanlines. A color ratio composite image consisting of TM band ratios 3/4, 5/2, and 5/7 showed limonitic clay rich soils, limonitic clay poor soils, and nonlimonitic materials as distinctly different colors on the image.
Mahajan, Chhavi; Chadha, B S; Nain, Lata; Kaur, Amarjeet
2014-07-01
The aim of this work was to evaluate glycosyl hydrolases produced by diverse thermophilic fungal strains for saccharification of alkali and biologically (Trametes hirusita/Myrothecium roridum) treated Parthenium hysterophorus and rice straw. The compositional analysis of hydrolysates by HPLC showed distinct profiles of hexose, pentose and oligomeric sugars. Malbranchea cinnamomea was most efficient source of glycosyl hydrolases producing 283.8, 35.9, 129.6, 27,193, 4.66, 7.26(units/gds) of endoglucanase, cellobiohydrolase, β-glucosidase, xylanase, α-αrabinofuranosidase and β xylosidase, respectively. The saccharification of alkali and biologically treated carrot grass by culture extract of M. cinnamomea was further enhanced by supplementation of β-glucosidase produced by Aspergillus sp. mutant "O". The resultant hydrolysates containing glucose/xylose were fermented efficiently to ethanol by Saccharomyces cerevisiae owing to presence of xylose isomerase (0.8 units/gds) activity in culture extract of M. cinnamomea resulting in production of 16.5 and 15.0 g/l of ethanol from alkali treated rice straw and carrot grass, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.
NASA Technical Reports Server (NTRS)
Hennigan, Christopher J.; Sandholm, Scott; Kim, Saewung; Stickel, Robert E.; Huey, L. Gregory; Weber, Rodney J.
2006-01-01
Aircraft measurements of fine inorganic aerosol composition were made with a particle-into-liquid sampler coupled to dual ion chromatographs (PILS-IC) as part of the NASA INTEX-NA study. The sampling campaign, which lasted from 1 July to 14 August 2004, centered over the eastern United States and Canada and showed that sulfate was the dominant inorganic species measured. The highest sulfate concentrations were observed at altitudes below 2 km, and back trajectory analyses showed a distinct difference between air masses that had or had not intercepted the Ohio River valley (ORV) region. Air masses encountered below 2 km with a history over the ORV had sulfate concentrations that were higher by a factor of 3.2 and total sulfur (S) concentrations higher by 2.5. The study's highest sulfate concentrations were found in these air masses. The sulfur of the ORV air masses was also more processed with a mean sulfate to total sulfur molar ratio of 0.5 compared to 0.3 in non-ORV measurements. Results from a second, independent trajectory model agreed well with those from the primary analysis. These ORV-influenced air masses were encountered on multiple days and were widely spread across the eastern United States and western Atlantic region.
Bresler, Scott; Gaskell, Michael B
2015-01-01
Workplace violence in healthcare settings is a complex topic with many different environments in which aggression is sometimes expressed by patients toward those entrusted with providing their healthcare. The assessment of violence risk in a nursing home containing many patients with organic brain syndrome is quite distinct from assessment in forensic psychiatric units, inner city emergency rooms, or outpatient pain clinics. Three cases are presented that are composite summaries of actual assaults which took place across different hospital settings, all within an urban Midwestern city in the United States: (1) an emergency department; (2) a psychiatric emergency services (PES) center; (3) a short stay (typically 72 hours to 5 days) civil psychiatric inpatient unit. These case studies exemplify specific risk factors that violent patients have, depending upon the specific healthcare setting where the patient presents. Research is cited relevant to all three case studies and how one should assess their risk. Lastly, the complexity of this issue is highlighted by a brief discussion of the pitfalls entailed in profiling ``the dangerous patient.'' It is demonstrated that when violence is expressed by a patient toward a healthcare provider, it is usually a maladaptive response, one in which characteristics of that setting and behavior of those who work within it must be carefully considered when determining what factors precipitated the patient's violent act.
Trade-off between taxon diversity and functional diversity in European lake ecosystems.
Grossmann, Lars; Beisser, Daniela; Bock, Christina; Chatzinotas, Antonis; Jensen, Manfred; Preisfeld, Angelika; Psenner, Roland; Rahmann, Sven; Wodniok, Sabina; Boenigk, Jens
2016-12-01
Inferring ecosystem functioning and ecosystem services through inspections of the species inventory is a major aspect of ecological field studies. Ecosystem functions are often stable despite considerable species turnover. Using metatranscriptome analyses, we analyse a thus-far unparalleled freshwater data set which comprises 21 mainland European freshwater lakes from the Sierra Nevada (Spain) to the Carpathian Mountains (Romania) and from northern Germany to the Apennines (Italy) and covers an altitudinal range from 38 m above sea level (a.s.l) to 3110 m a.s.l. The dominant taxa were Chlorophyta and streptophytic algae, Ciliophora, Bacillariophyta and Chrysophyta. Metatranscriptomics provided insights into differences in community composition and into functional diversity via the relative share of taxa to the overall read abundance of distinct functional genes on the ecosystem level. The dominant metabolic pathways in terms of the fraction of expressed sequences in the cDNA libraries were affiliated with primary metabolism, specifically oxidative phosphorylation, photosynthesis and the TCA cycle. Our analyses indicate that community composition is a good first proxy for the analysis of ecosystem functions. However, differential gene regulation modifies the relative importance of taxa in distinct pathways. Whereas taxon composition varies considerably between lakes, the relative importance of distinct metabolic pathways is much more stable, indicating that ecosystem functioning is buffered against shifts in community composition through a functional redundancy of taxa. © 2016 The Authors. Molecular Ecology Published by John Wiley & Sons Ltd.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Carretta, E., E-mail: eugenio.carretta@oabo.inaf.it
2014-11-10
We present the homogeneous reanalysis of Mg and Al abundances from high resolution UVES/FLAMES spectra for 31 red giants in the globular cluster NGC 2808. We found a well defined Mg-Al anticorrelation reaching a regime of subsolar Mg abundance ratios, with a spread of about 1.4 dex in [Al/Fe]. The main result from the improved statistics of our sample is that the distribution of stars is not continuous along the anticorrelation because they are neatly clustered into three distinct clumps, each with different chemical compositions. One group (P) shows a primordial composition of field stars of similar metallicity, and the other twomore » (I and E) have increasing abundances of Al and decreasing abundances of Mg. The fraction of stars we found in the three components (P: 68%, I: 19%, E: 13%) is in excellent agreement with the ratios computed for the three distinct main sequences in NGC 2808: for the first time there is a clear correspondence between discrete photometric sequences of dwarfs and distinct groups of giants with homogeneous chemistry. The composition of the I group cannot be reproduced by mixing of matter with extreme processing in hot H-burning and gas with pristine, unprocessed composition, as also found in the recent analysis of three discrete groups in NGC 6752. This finding suggests that different classes of polluters were probably at work in NGC 2808 as well.« less
NASA Astrophysics Data System (ADS)
Ayda Ustaömer, Petek; Ustaömer, Timur; Gerdes, Axel; Robertson, Alastair H. F.; Zulauf, Gernold
2014-05-01
The Permo-Triassic Karakaya Complex is well explained by northward subduction of Palaeotethys but until now no corresponding magmatic arc has been identified in the region. With the aim of determining the compositions and ages of the source units, ten sandstone samples were collected from the mappably distinct Ortaoba, Hodul, Kendirli and Orhanlar Units. Zircon grains were extracted from these sandstones and >1300 were dated by the U-Pb method and subsequently analysed for the Lu-Hf isotopic compositions by LA-MC-ICPMS at Goethe University, Frankfurt. The U-Pb-Hf isotope systematics are indicative of two different sediment provenances. The first, represented by the Ortaoba, Hodul and Kendirli Units, is dominated by igneous rocks of Triassic (250-220 Ma), Early Carboniferous-Early Permian (290-340 Ma) and Early to Mid-Devonian (385-400 Ma) ages. The second provenance, represented by the Orhanlar Unit, is indicative of derivation from a peri-Gondwanan terrane. In case of the first provenance, the Devonian and Carboniferous source rocks exibit intermediate eHf(t) values (-11 to -3), consistent with the formation at a continental margin where juvenile mantle-derived magmas mixed with (recycled) old crust having Palaeoproterozoic Hf model ages. In contrast, the Triassic arc magma exhibits higher eHf(t) values (-6 to +6), consistent with the mixing of juvenile mantle-derived melts with (recycled) old crust perhaps somewhat rejuvanated during the Cadomian period. We have therefore identified a Triassic magmatic arc as predicted by the interpretation of the Karakaya Complex as an accretionary complex related to northward subduction (Carboniferous and Devonian granites are already well documented in NW Turkey). Possible explanations for the lack of any outcrop of the source magmatic arc are that it was later subducted or the Karakaya Complex was displaced laterally from its source arc (both post 220 Ma). Strike-slip displacement (driven by oblique subduction?) can also explain the presence of two different sandstone source areas as indicated by the combined U-Pb-Hf isotope and supporting petrographic data. This study was supported by TUBITAK, Project no: 111R015
ChemCam at Gale Crater: Highlights and Discoveries from Three Years of Chemical Measurements on Mars
NASA Astrophysics Data System (ADS)
Blaney, Diana L.; Wiens, Roger; Maurice, Sylvestre; Gasnault, Olivier; Anderson, Ryan; Bridges, John; Bridges, Nathan; Clegg, Samuel; Clark, Benton; Ehlmann, Bethany; Dyar, Melinda D.; Fisk, Martin; Francis, Raymond; Fabre, Cecile; Forni, Olivier; Frydenvang, Jens; Johnson, Jeffery; Lanza, Nina; Leveille, Richard; Lasue, Jeremie; Le Deit, Laetitia; Mangold, Nicholas; Melikechi, Noureddine; Nachon, Marion; Newsom, Horton; Payre, Valerie; Rapin, William; Sautter, Violane; Vaniman, David; Grotzinger, John; Vasavad, Ashwin; Crisp, Joy
2015-11-01
ChemCam has undertaken a detailed chemical investigation of the rocks and soils at Gale crater over the last three years with over six thousand separate geochemical measurements. Recent recalibration of the ChemCam data using a new library of >350 geochemical standards has enabled increased elemental accuracies over a wider compositional range. The increased accuracy combined with ChemCam’s small spot size allows for the chemistry of mineral end members including feldspars, high silica, oxide rich grains to be identified. ChemCam has observed both sedimentary and igneous compositions. Igneous compositions are generally present in conglomerates and in float rocks. Compositions show a wide range of igneous chemistry ranging from basaltic to feldspar rich assemblages.Sedimentary rocks have a wide range of compositions reflecting both differences in chemical source regions and in depositional and diagenetic histories. The “Sheepbed” mudstones cluster around Martian average crustal compositions. The “Kimberley” outcrop showed enhanced potassium reaching concentrations up to ~6 wt% K2O. More recent observations in the Murray Formation at the base of Mt. Sharp reveal mudstones that are lower in magnesium and higher in silica and aluminum than the more basaltic mudstones previously investigated. Extremely high silica (75-85 wt%) deposits have also been identified. The high silica observations were associated with increased TiO2, While the Murray mudstones are generally low in magnesium, local enhancements in magnesium have also been noted associated with resistant facies in the outcrop. Chemical trends also indicate that iron oxide phases may also be present as cements. Sandstone facies with a mafic composition are also present. Veins in the unit also show a wide range of compositions indicating fluid chemistries rich in calcium sulfate, fluorine, magnesium and iron were present. Vein chemistry could be the result of distinct fluids migrating through from a distance with a pre-established chemical signature, fluids locally evolved from water rock interactions, or both. Thus the chemical relationships between the Pahrump bedrock and the veins’ chemistry can be used to constrain the origin of the fluids.
Lipids as a principle for the identification of Archaebacteria
NASA Technical Reports Server (NTRS)
Tornabene, T. G.; Lloyd, R. E.; Holzer, G.; Oro, J.
1980-01-01
The 'Archaebacteria' consist of several distinct subgroups including methanogens, extreme halophiles and specific thermoacidophiles. These bacteria are distinct from other bacteria with respect to their characteristic RNA compositions, the absence of muramic acid in the cell walls and the predominance of nonsaponifable lipids. The lipid composition of the Archaebacteria consists of isoprenoid and hydroisoprenoid hydrocarbons and isopranyl glycerol ether lipids. The pathways for the biosynthesis of the lipid components are those shared by most microorganisms and demonstrate a close relationship; however, an independent line of descent is indicated by the formation of the isopranyl glycerol ether lipids. This discontinuity formulates a point for delineating the early stages of biological evolution and for dividing bacteria into two subgroups.
Microhardness of resin composites polymerized by plasma arc or conventional visible light curing.
Park, S Ho; Krejci, I; Lutz, F
2002-01-01
This study evaluated the effectiveness of the plasma arc curing (PAC) unit for composite curing. To compare its effectiveness with conventional quartz tungsten halogen (QTH) light curing units, the microhardness of two composites (Z100 and Tetric Ceram) that had been light cured by the PAC or QTH units, were compared according to the depth from the composite surface. In addition, linear polymerization shrinkage was compared using a custom-made linometer between composites which were light cured by PAC or QTH units. Measuring polymerization shrinkage for two resin composites (Z100 and Tetric Ceram) was performed after polymerization with either QTH or PAC units. In the case of curing with the PAC unit, the composite was light cured with Apollo 95E for two (Group 1), three (Group 2), six (Group 3) or 2 x 6 (Group 4) seconds. For light curing with the QTH unit, the composite was light cured for 60 seconds with Optilux 500 (Group 5). The linear polymerization shrinkage of composites was determined in the linometer. Two resin composites were used to measure microhardness. Two-mm thick samples were light cured for three seconds (Group 1), six seconds (Group 2) or 12 (2 x 6) seconds (Group 3) with Apollo 95E or they were conventionally light cured with Optilux 500 for 30 seconds (Group 4) or 60 seconds (Group 5). For 3 mm thick samples, the composites were light cured for six seconds (Group 1), 12 (2 x 6) seconds (Group 2) or 18 (3 x 6) seconds (Group 3) with Apollo 95E or they were conventionally light cured with Optilux 500 for 30 seconds (Group 4) or 60 seconds (Group 5). Twenty samples were assigned to each group. The microhardness of the upper and lower surfaces was measured with a Vickers hardness-measuring instrument under load. The difference in microhardness between the upper and lower surfaces in each group was analyzed by paired t-test. For the upper or lower surfaces, one-way ANOVA with Tukey was used. For Tetric Ceram, the amount of polymerization shrinkage was lower when cured with the Apollo 95E for two or three seconds than when cured for six and 12 (2 x 6) seconds, or for 60 seconds with Optilux 500 (p<0.05). For Z100, the amount of linear polymerization shrinkage was lower when cured with the Apollo 95E for two, three and six seconds than for 12 (2 x 6) seconds with Apollo 95E or for 60 seconds with the Optilux 500 (p<0.05). The results of the microhardness test indicated that there was no statistically significant difference in microhardness between groups for the upper surface. However, for the lower surface, when the composites were light cured with Apollo 95E for three seconds as recommended by the manufacturer, microhardness of the lower surface was usually lower than that of the upper surface and did not cure sufficiently. Conclusively, when compared with conventional QTH unit, the PAC unit, Apollo 95E did not properly cure the lower composite surface when the layer thickness exceeded 2 mm. In addition, three seconds of curing time, which the manufacturer recommended, was insufficient for optimal curing of composites.
Coombs, D.S.; Alberti, A.; Armbruster, T.; Artioli, G.; Colella, C.; Galli, E.; Grice, Joel D.; Liebau, F.; Mandarino, J.A.; Minato, H.; Nickel, E.H.; Passaglia, E.; Peacor, D.R.; Quartieri, S.; Rinaldi, R.; Ross, M.; Sheppard, R.A.; Tillmanns, E.; Vezzalini, G.
1998-01-01
This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association Commission on New Minerals and Mineral Names. In a working definition of a zeolite mineral used for this review, structures containing an interrupted containing an interrupted framework of tetrahedra are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is alloowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundant in atomic proportions. To name these, the appropriate chemical symbol is attached by a hyphen to the series name as a suffix, except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely in Si:Al ratio except for heulandite (Si:Al < 4.0) and clinoptilolite (Si:Al ??? 4.0). Dehydration, partial hydration and over-hydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of zeolite. Newly recognized species in compositional series are as follows: brewsterite-Sr, -Ba; chabazite-Ca, -Na, -K; clinoptilolite-K, -Na, -Ca; dechiardite-Ca, -Na; erionite-Na, -K, -Ca,; faujasite-Na, -Ca, -Mg; ferrierite-Mg, -K, -Na; gmelinite-Na, -Ca, -K; heulandite-Ca, -Na, -K, -Sr; levyne-Ca, -Na; paulingite-K, -Ca; phillipsite-Na, -Ca, -K stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data, IZA structure-type symbols, space-group symmetry, unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, svetlozarite and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.
Coombs, D.S.; Alberti, A.; Armbruster, T.; Artioli, G.; Colella, C.; Galli, E.; Grice, Joel D.; Liebau, F.; Mandarino, J.A.; Minato, H.; Nickel, E.H.; Passaglia, E.; Peacor, D.R.; Quartieri, S.; Rinaldi, R.; Ross, M.; Sheppard, R.A.; Tillmanns, E.; Vezzalini, G.
1997-01-01
This report embodies recommendations on zeolite nomenclature approved by the International Mineralogical Association, Commission on New Minerals and Mineral Names. In a working definition of a zeolite mineral used for this review, structures containing an interrupted framework of tetrahedra are accepted where other zeolitic properties prevail, and complete substitution by elements other than Si and Al is allowed. Separate species are recognized in topologically distinctive compositional series in which different extra-framework cations are the most abundant in atomic proportions. To name these, the appropriate chemicalsymbol is attached by a hyphen to the series name as a suffix, except for the names harmotome, pollucite and wairakite in the phillipsite and analcime series. Differences in space-group symmetry and in order-disorder relationships in zeolites having the same topologically distinctive framework do not in general provide adequate grounds for recognition of separate species. Zeolite species are not to be distinguished solely on the ratio Si:Al except for heulandite (Si:Al < 4.0) and clinoptilolite (Si:Al ??? 4.0). Dehydration, partial hydration, and overhydration are not sufficient grounds for the recognition of separate species of zeolites. Use of the term 'ideal formula' should be avoided in referring to a simplified or averaged formula of a zeolite. newly recognized species in compositional series are as follows: brewsterite-Sr, -Ba, chabazite-Ca, -Na, -K, clinoptilolite-K, -Na, -Ca, dachiardite-Ca, -Na, erionite-Na, erionite-Na, -K, -Ca, faujasite-Na, -Ca, -Mg, ferrierite-Mg, -K, -Na, gmelinite-Na, -Ca, -K, heulandite-Ca, -Na, -K, -Sr, levyne-Ca, -Na, paulingite-K, -Ca, phillipsite-Na, -Ca, -K, and stilbite-Ca, -Na. Key references, type locality, origin of name, chemical data, IZA structure-type symbols, space-group symmetry, unit-cell dimensions, and comments on structure are listed for 13 compositional series, 82 accepted zeolite mineral species, and three of doubtful status. Herschelite, leonhardite, dvetlozarite, and wellsite are discredited as mineral species names. Obsolete and discredited names are listed.
NASA Astrophysics Data System (ADS)
Harris, William M.; Brinkman, Kyle S.; Lin, Ye; Su, Dong; Cocco, Alex P.; Nakajo, Arata; Degostin, Matthew B.; Chen-Wiegart, Yu-Chen Karen; Wang, Jun; Chen, Fanglin; Chu, Yong S.; Chiu, Wilson K. S.
2014-04-01
The microstructure and connectivity of the ionic and electronic conductive phases in composite ceramic membranes are directly related to device performance. Transmission electron microscopy (TEM) including chemical mapping combined with X-ray nanotomography (XNT) have been used to characterize the composition and 3-D microstructure of a MIEC composite model system consisting of a Ce0.8Gd0.2O2 (GDC) oxygen ion conductive phase and a CoFe2O4 (CFO) electronic conductive phase. The microstructural data is discussed, including the composition and distribution of an emergent phase which takes the form of isolated and distinct regions. Performance implications are considered with regards to the design of new material systems which evolve under non-equilibrium operating conditions.The microstructure and connectivity of the ionic and electronic conductive phases in composite ceramic membranes are directly related to device performance. Transmission electron microscopy (TEM) including chemical mapping combined with X-ray nanotomography (XNT) have been used to characterize the composition and 3-D microstructure of a MIEC composite model system consisting of a Ce0.8Gd0.2O2 (GDC) oxygen ion conductive phase and a CoFe2O4 (CFO) electronic conductive phase. The microstructural data is discussed, including the composition and distribution of an emergent phase which takes the form of isolated and distinct regions. Performance implications are considered with regards to the design of new material systems which evolve under non-equilibrium operating conditions. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr06684c
NASA Technical Reports Server (NTRS)
Humphrey, W. Donald
1997-01-01
This report summarizes efforts expended in the development of an all-composite compressor case. Two pre-production units have been built, one utilizing V-CAP and one utilizing AFR-700B resin systems. Both units have been rig tested at elevated temperatures well above design limit loads. This report discusses the manufacturing processes, test results, and Finite Element Analysis performed. The V-CAP unit was funded by NASA-Lewis Research Center in 1994 under contract number NAS3- 27442 for Development of an All-Composite OMC Compressor Case. This contract was followed by an Air Force study in 1996 to build and identical unit using the AFR-700B resin system in place of the V-CAP system. The second compressor case was funded under U.S. Air Force contract F33615-93-D-5326, Advanced Materials for Aerospace Structures Special Studies (AMAS3), Delivery Order 0021 entitled "Advanced Polymeric Composite Materials and Structures Technology for Advanced High Temperature Gas Turbine Engines.' Initial studies using the V-CAP resin system were undertaken in 1993 under a NASA Lewis contract (NAS3-26829). A first prototype unit was developed in a joint program between Textron-Lycoming (now Allied Signal) and Brunswick (now Lincoln Composites). This unit included composite end closures using low density, high temperature molded end closures. The units was similar in size and shape to a titanium case currently used on the PT-21 0 engine and was funded as part of the integrated High Performance Turbine Engine Technology (EHPTET) initiative of DOD and NASA.
Particulate matter (PM) associated metals contribute to the adverse cardiopulmonary effects following exposure to air pollution. Here, we investigated how variation in the composition and size of ambient PM collected from two distinct regions in Mexico City relates to toxicity d...
Geographical ecology of dry forest tree communities in the West Indies
Janet Franklin; Riley Andrade; Mark L. Daniels; Patrick Fairbairn; Maria C. Fandino; Thomas W. Gillespie; Grizelle González; Otto Gonzalez; Daniel Imbert; Valerie Kapos; Daniel L. Kelly; Humfredo Marcano-Vega; Elvia J. Meléndez-Ackerman; Kurt P. McLaren; Morag A. McDonald; Julie Ripplinger; Julissa Rojas-Sandoval; Michael S. Ross; Jorge Ruiz; David W. Steadman; Edmund V. J. Tanner; Inge Terrill; Michel Vennetier
2018-01-01
Aim: Seasonally dry tropical forest (SDTF) of the Caribbean Islands (primarily West Indies) is floristically distinct from Neotropical SDTF in Central and South America. We evaluate whether tree species composition was associated with climatic gradients or geographical distance. Turnover (dissimilarity) in species composition of different islands or among more distant...
USDA-ARS?s Scientific Manuscript database
Fennel (Foeniculum vulgare Mill.) is cultivated for its seeds and foliage, which contain essential oil. We hypothesized that the collection of fennel seed oil at different time points during the distillation process may result in fennel oil with distinct composition and bioactivity. We collected ess...
If Maslow Created a Composition Course: A New Look at Motivation in the Classroom.
ERIC Educational Resources Information Center
Boone, Beth; Hill, Ada S.
The needs hierarchy developed by Abraham Maslow lends itself to the composition classroom. The hierarchy depicts five distinct need levels through which an individual travels: basic, safety/security, belonging/peer acceptance, ego/esteem, and self-actualization. From teacher observations and students' comments, need levels can be assessed and…
School Composition and Peer Effects in Distinctive Organizational Settings
ERIC Educational Resources Information Center
Marks, Helen M.
2002-01-01
This chapter reviews the research on school composition and peer effects from three comparative perspectives--Catholic and public schools, single-sex and coeducational schools, and small and large schools. Most of the research is sociological, focuses on high schools, and draws on national samples. The chapter seeks to discern cumulative trends in…
Investigation of early timber–concrete composite bridges in the United States
James P. Wacker; Alfredo Dias; Travis K. Hosteng
2017-01-01
The use of timberâconcrete composite (TCC) bridges in the United States dates back to circa 1925. Two different TCC systems were constructed during this early period. The first system included a longitudinal nail-laminated deck composite with a concrete deck top layer. The second system included sawn timber stringers supporting a concrete deck top layer. Records...
Palacios, G.; Hui, J.; Quan, P. L.; Kalkstein, A.; Honkavuori, K. S.; Bussetti, A. V.; Conlan, S.; Evans, J.; Chen, Y. P.; vanEngelsdorp, D.; Efrat, H.; Pettis, J.; Cox-Foster, D.; Holmes, E. C.; Briese, T.; Lipkin, W. I.
2008-01-01
Israel acute paralysis virus (IAPV) is associated with colony collapse disorder of honey bees. Nonetheless, its role in the pathogenesis of the disorder and its geographic distribution are unclear. Here, we report phylogenetic analysis of IAPV obtained from bees in the United States, Canada, Australia, and Israel and the establishment of diagnostic real-time PCR assays for IAPV detection. Our data indicate the existence of at least three distinct IAPV lineages, two of them circulating in the United States. Analysis of representatives from each proposed lineage suggested the possibility of recombination events and revealed differences in coding sequences that may have implications for virulence. PMID:18434396
NASA Astrophysics Data System (ADS)
Szymanski, D. W.; Patino, L. C.; Vogel, T. A.; Alvarado, G. E.
2002-12-01
Explaining the occurrence of high-silica arc magmatism in the absence of continental crust remains a fundamental problem in igneous petrology. Recent work in the southern portion of the Central American volcanic arc has expanded the database for the abundant high-silica ash-flow tuffs erupted on top of thick oceanic basement in Costa Rica and southern Nicaragua. Regional differences in geochemistry are observed in data from central and northern Costa Rica. In addition, local heterogeneities among units are demonstrated in plots of both major and trace elements. High-silica ash-flow tuffs in central Costa Rica include the Tiribi Tuff (~0.33 Ma) and Alto Palomo formation (~0.56 Ma). In northern Costa Rica, numerous large silicic ash-flow sheets are found in the Guanacaste province, ranging from late Miocene (<10 Ma) to Pleistocene (~0.6 Ma) in age. A frequency histogram of normalized silica content for all analyses to date from these units (n=222) produces a left-skewed curve with a mode occurring at approximately 70 wt.% SiO2. Samples from the northern region (n=107) demonstrate a tighter distribution of silica content (60.1-78.7 wt.% SiO2 with a median of 72.2 wt.% SiO2) compared to samples from the central region (n=115, 55.4-74.2 wt.% SiO2 with a median of 67.1 wt.% SiO2). The least evolved samples come from the Tiribi Formation in the Valle Central and are chemically distinct from rocks in the Guanacaste region. In both chemistry and geographical position, the Alto Palomo formation appears to represent a transition between tuffs in the Valle Central and those in Guanacaste. Incompatible trace element ratios for these units are nearly identical to regional trends observed in basaltic to andesitic lavas of the modern Costa Rican arc (e.g. Ba/Nb). The Papagayo sequence is an example of chemical variation within one vertical section. The sequence is a ~21 m section of well-exposed tuff that represents an essentially continuous sampling of an evolving magma body. Major-element analyses from a systematic vertical sampling of the section support a model of crystal fractionation, eruption, and mafic replenishment of the magma chamber. Samples range from 60.1 to 70.2 wt.% SiO2, with the most mafic sample occurring at the top of sequence as a visibly mafic-silicic mingled pumice. The Rio Liberia (~1.47 Ma) and Salitral (~1.3 Ma) formations in the Guanacaste region form a series of tuffs, related by the same inferred vent. Despite overlapping silica content, the units have distinct mineral compositions. The Salitral formation includes plagioclase- and amphibole-rich units that appear very similar in the field, while the Rio Liberia contains biotite. Chemically, the units are distinct, forming several separate trends in trace element plots. These heterogeneities most likely reflect differences in both source and/or processes of magma evolution.
Anatomy of a Natural Composite Material
1989-11-01
from the vitellaria of the liver fluke, Fasciola hepatica. Biochemistry 28, 6104-6110. 2. Waite, J.H., Hansen, D.C., & Little, K.T. (1989) The glue...certainly belong to distinct genera and inhabit distinct ecological niches. Adhesive protein sequences from two non-molluscan species, Fasciola hepatica...choros), Gd (Geukensia demissa), Fh ( Fasciola hepatica), Me (Mytilus edulis), Mg (Mytella guyanensis), Mms (Modiolus modiolus squamosus), Pc
Examining spectral variations in localized lunar dark mantle deposits
Jawin, Erica; Besse, Sebastien; Gaddis, Lisa R.; Sunshine, Jessica; Head, James W.; Mazrouei, Sara
2015-01-01
The localized lunar dark mantle deposits (DMDs) in Alphonsus, J. Herschel, and Oppenheimer craters were analyzed using visible-near-infrared spectroscopy data from the Moon Mineralogy Mapper. Spectra of these localized DMDs were analyzed for compositional and mineralogical variations within the deposits and were compared with nearby mare basalt units. Spectra of the three localized DMDs exhibited mafic absorption features indicating iron-rich compositions, although the DMDs were spectrally distinct from nearby mare basalts. All of the DMDs contained spectral signatures of glassy materials, suggesting the presence of volcanic glass in varying concentrations across the individual deposits. In addition, the albedo and spectral signatures were variable within the Alphonsus and Oppenheimer crater DMDs, suggesting variable deposit thickness and/or variations in the amount of mixing with the local substrate. Two previously unidentified localized DMDs were discovered to the northeast of Oppenheimer crater. The identification of high concentrations of volcanic glass in multiple localized DMDs in different locations suggests that the distribution of volcanic glass across the lunar surface is much more widespread than has been previously documented. The presence of volcanic glass implies an explosive, vulcanian eruption style for localized DMDs, as this allows volcanic glass to rapidly quench, inhibiting crystallization, compared to the larger hawaiian-style eruptions typical of regional DMD emplacement where black beads indicate a higher degree of crystallization. Improved understanding of the local and global distributions of volcanic glass in lunar DMDs will further constrain lunar degassing and compositional evolution throughout lunar volcanic history.
Environmental Composites for Bomb Cyclones of the Western North Atlantic in Reanalysis, 1948-2016.
NASA Astrophysics Data System (ADS)
Adams, R.; Sheridan, S. C.
2017-12-01
"Bomb" cyclones represent a small subset of mid-latitude cyclones characterized by rapid intensification and frequently are associated with extreme weather conditions along the eastern coast of North America. Like other extreme phenomena, bomb cyclone predictions are prone to error leading to inadequate or untimely hazard warnings. The rare nature of bomb cyclones and the uniqueness of their evolutions has made it difficult for researchers to make meaningful generalizations on bomb cyclone events. This paper describes bomb cyclone climatology for the western North Atlantic, using data from the NCEP-NCAR Reanalysis for 1948-2016, and uses a synoptic climatological analysis to relate these bombs to their associated atmospheric environments. A self-organizing map (SOM) of 300-hPa geopotential height tendency is created to partition the regional atmospheric environment. Thermodynamic fields are contrasted by each 300-hPa geopotential height tendency pattern for both bomb and non-bomb events in composite difference maps. The SOM patterns most significantly associated with western North Atlantic bomb cyclogenesis are characterized by both strongly and weakly negative height tendencies along the eastern United States. In both cases, these patterns exhibit strong meridional flow, a distinction marked by the weakening and breaking down of the polar vortex in the boreal Winter. The composite maps for each pattern show the mean differences in low-mid level ascent and near surface thermodynamics for bomb environments contrasted with non-bomb environments, resulting in diverse spatiotemporal distributions of bombs in the western North Atlantic.
Constraints on continental crustal mass loss via chemical weathering using lithium and its isotopes
NASA Astrophysics Data System (ADS)
Rudnick, R. L.; Liu, X. M.
2012-04-01
The continental crust has an "intermediate" bulk composition that is distinct from primary melts of peridotitic mantle (basalt or picrite). This mismatch between the "building blocks" and the "edifice" that is the continental crust points to the operation of processes that preferentially remove mafic to ultramafic material from the continents. Such processes include lower crustal recycling (via density foundering or lower crustal subduction - e.g., relamination, Hacker et al., 2011, EPSL), generation of evolved melts via slab melting, and/or chemical weathering. Stable isotope systems point to the influence of chemical weathering on the bulk crust composition: the oxygen isotope composition of the bulk crust is distinctly heavier than that of primary, mantle-derived melts (Simon and Lecuyer, 2005, G-cubed) and the Li isotopic composition of the bulk crust is distinctly lighter than that of mantle-derive melts (Teng et al., 2004, GCA; 2008, Chem. Geol.). Both signatures mark the imprint of chemical weathering on the bulk crust composition. Here, we use a simple mass balance model for lithium inputs and outputs from the continental crust to quantify the mass lost due to chemical weathering. We find that a minimum of 15%, a maximum of 60%, and a best estimate of ~40% of the original juvenile rock mass may have been lost via chemical weathering. The accumulated percentage of mass loss due to chemical weathering leads to an average global chemical weathering rate (CWR) of ~ 1×10^10 to 2×10^10 t/yr since 3.5 Ga, which is about an order of magnitude higher than the minimum estimates based on modern rivers (Gaillardet et al., 1999, Chem. Geol.). While we cannot constrain the exact portion of crustal mass loss via chemical weathering, given the uncertainties of the calculation, we can demonstrate that the weathering flux is non-zero. Therefore, chemical weathering must play a role in the evolution of the composition and mass of the continental crust.
Collin, E C; Kilcoyne, M; White, S J; Grad, S; Alini, M; Joshi, L; Pandit, A S
2016-03-11
In this study, on/off markers for intervertebral disc (IVD) and articular cartilage (AC) cells (chondrocytes) and distinct glycoprofiles of cell and tissue-types were identified from immaturity to maturity. Three and eleven month-old ovine IVD and AC tissues were histochemically profiled with a panel of lectins and antibodies. Relationships between tissue and cell types were analysed by hierarchical clustering. Chondroitin sulfate (CS) composition of annulus fibrosus (AF), nucleus pulposus (NP) and AC tissues was determined by HPLC analysis. Clear on/off cell type markers were identified, which enabled the discrimination of chondrocytes, AF and NP cells. AF and NP cells were distinguishable using MAA, SNA-I, SBA and WFA lectins, which bound to both NP cells and chondrocytes but not AF cells. Chondrocytes were distinguished from NP and AF cells with a specific binding of LTA and PNA lectins to chondrocytes. Each tissue showed a unique CS composition with a distinct switch in sulfation pattern in AF and NP tissues upon disc maturity while cartilage maintained the same sulfation pattern over time. In conclusion, distinct glycoprofiles for cell and tissue-types across age groups were identified in addition to altered CS composition and sulfation patterns for tissue types upon maturity.
de Menezes, Alexandre B; Prendergast-Miller, Miranda T; Richardson, Alan E; Toscas, Peter; Farrell, Mark; Macdonald, Lynne M; Baker, Geoff; Wark, Tim; Thrall, Peter H
2015-08-01
Network and multivariate statistical analyses were performed to determine interactions between bacterial and fungal community terminal restriction length polymorphisms as well as soil properties in paired woodland and pasture sites. Canonical correspondence analysis (CCA) revealed that shifts in woodland community composition correlated with soil dissolved organic carbon, while changes in pasture community composition correlated with moisture, nitrogen and phosphorus. Weighted correlation network analysis detected two distinct microbial modules per land use. Bacterial and fungal ribotypes did not group separately, rather all modules comprised of both bacterial and fungal ribotypes. Woodland modules had a similar fungal : bacterial ribotype ratio, while in the pasture, one module was fungal dominated. There was no correspondence between pasture and woodland modules in their ribotype composition. The modules had different relationships to soil variables, and these contrasts were not detected without the use of network analysis. This study demonstrated that fungi and bacteria, components of the soil microbial communities usually treated as separate functional groups as in a CCA approach, were co-correlated and formed distinct associations in these adjacent habitats. Understanding these distinct modular associations may shed more light on their niche space in the soil environment, and allow a more realistic description of soil microbial ecology and function. © 2014 Society for Applied Microbiology and John Wiley & Sons Ltd.
Forster, H.-J.; Davis, J.C.
2000-01-01
Variscan granites of the Erzgebirge region can be effectively classified into five genetically distinct major groups by canonical analysis of geochemical variables. The same classification procedure, when applied to small plutons in the Aue-Schwarzenberg granite zone (ASGZ), shows that all ASGZ granites have compositional affinities to low-F biotite or low-F two-mica granite groups. This suggests that the ASGZ granites were emplaced during the first, late-collisional stage of silicic magmatism in the region, which occurred between about 325 and 318 Ma. The numerous biotite granite bodies in the zone are geochemically distinct from both the neighboring Kirchberg granite pluton and the spatially displaced Niederbobritzsch biotite granite massif. Instead, these bodies seem to constitute a third sub-group within the low-F biotite granite class. The ASGZ biotite granites represent three or more genetically distinct bodies, thus highlighting the enormous compositional variability within this group of granites. Least evolved samples of two-mica granites from the ASGZ apparently reflect the assimilation of low-grade metamorphic country rocks during emplacement, altering the original composition of the melts by enhancing primary Al content. The same genesis is implied for the rare "cordierite granite" facies of the Bergen massif, the type pluton for the low-F two-mica granite group in the Erzgebirge.
Physical properties of Deucalionis, Eos, Xanthe-type units in the central equatorial region of Mars
NASA Technical Reports Server (NTRS)
Strickland, Edwin L., III
1992-01-01
Classification and mapping of surficial units in the central equatorial region of Mars (30 degrees N to 20 degrees S, 57 degrees E to 75 degrees W) using enhanced color images and Mars Consortium data, identified three distinct, high albedo, relatively red surficial units in regions with intermediate to high thermal inertias. These units have distinctive properties and morphologies, occur in different, well-defined areas, and show different seasonal and secular patterns of albedo change. Deucalionis units occupy the classical albedo area of Deucalionis Regio, south of Meridiani Sinus and Sabaeus Sinus, and adjacent areas. Eos forms a bright band that separates the dark, relatively blue Meridiani-type units that dominate the southern part of the study area from intermediate albedo, relatively red Oxia units common in the north. Xanthe forms moderately bright, relatively red, Type 1B crater-streaks and uniform sheet-deposits in and adjacent to parts of Chryse Planitia, including the Viking 1 landing site. Xanthe is always associated with Oxia deposits, and has significantly lower albedos than the Eos materials, which it can be confused with.
Lehnert, M; Laurer, H; Maier, B; Frank, J; Marzi, I; Steudel, W-I; Mautes, A
2007-01-01
Age dependent motor unit dedifferentiation is a key component of impaired muscle function in advanced age. Here, we tested the hypothesis that rat muscle histochemical profile during the lifespan of an individual has an age-specific pattern since comprehensive longitudinal studies of muscle differentiation after birth and dedifferentiation in advanced age are scarce. Our results show that extensor digitorum longus muscle (EDL) is comprised only of two fiber types after birth, type slow-oxidative (SO) and type SDH-intermediate (SDH-INT), the latter being indicative for the presence of polyneuronal innervation. In contrast to the constantly growing cross-sectional area of the muscle fibers, a dramatic decrease in SDH-INT proportion occurs between day 14 and 21 after birth resulting in a complete loss of fiber type SDH-INT at the age of 90 days (p<0.05). At the age of 270 days, the fiber type composition of rat EDL dedifferentiates as shown by the reappearance of the SDH-INT type with a further increase at the age of 540 days (p<0.05). These changes in histochemical fiber type spectra are brought about by fiber type conversion within the fast twich fibers. The findings of the present study provide further evidence that fiber type conversion is a basic mechanism leading to motor unit differentiation and dedifferentiation during ontogenesis. Fiber type conversion shows a distinct time specific pattern and is also characteristic for motor unit regeneration after peripheral nerve repair. Factors that influence fiber type conversion and thereby motor unit organization may provide a future therapeutic option to enhance the regenerative capacity of motor units.
Anthropometric profile and body composition of Irish adolescent rugby union players aged 16-18.
Delahunt, Eamonn; Byrne, Risteard B; Doolin, Rachel K; McInerney, Rory G; Ruddock, Ciaran T J; Green, Brian S
2013-12-01
The literature suggests that one of the key determinants of success at rugby union international competitions is the anthropometric profile of players. The Irish Rugby Football Union (IRFU) long-term player development (LTPD) model is a framework designed to guide the development of the tactical, physical, and psychological domains of sporting participation. In Ireland, the Train-to-Train stage of the IRFU model is a critical stage, whereby the next developmental progression would include the transition of players into professional academies. To date, no previously published studies have examined the anthropometric profile of Irish Schools' rugby union players at the Train-to-Train stage of the IRFU model. The anthropometric profile of 136 male adolescent rugby union players at the Train-to-Train stage of the IRFU model was assessed using total-body dual-energy x-ray absorptiometry. Significant differences in height, body mass, body fat percentage, fat mass, lean mass, and fat-free mass were observed between players assigned to the forward and back units, and for specific position categorizations within each unit. Direct logistic regression revealed that body mass was a statistically significant (p < 0.01) predictor of unit position classification, with an odds ratio of 2.35, indicating that the players with a higher body mass were twice as likely to be classified as forwards. The results of this study indicate that at the Train-to-Train stage of the IRFU model, forward and back units have distinctly different anthropometric profiles. Furthermore, anthropometric differentiation also exists within specific position categorizations within each of these playing units. Thus, anthropometric profiling should be carried out on a systematic and periodic basis, because this will allow for the evaluation of the effectiveness of the implementation strategies of the IRFU model on a national basis.
Lithologies of the basement complex (Devonian and older) in the National Petroleum Reserve - Alaska
Dumoulin, Julie A.; Houseknecht, David W.
2001-01-01
Rocks of the basement complex (Devonian and older) were encountered in at least 30 exploratory wells in the northern part of the NPRA. Fine-grained, variably deformed sedimentary rocks deposited in a slope or basinal setting predominate and include varicolored (mainly red and green) argillite in the Simpson area, dark argillite and chert near Barrow, and widespread gray argillite. Chitinozoans of Middle-Late Ordovician and Silurian age occur in the dark argillite and chert unit. Sponge spicules and radiolarians establish a Phanerozoic age for the varicolored and gray argillite units, both of which contain local interbeds of chert-rich sandstone and silt-stone. Conglomerate and sandstone, also chert-rich but interbedded with mudstone and coal and of Early-Middle Devonian age, occur in the Topagoruk area; these strata formed in a fluvial environment. At East Teshekpuk, granite of probable Devonian age was penetrated. Brecciated, quartz-veined rock of uncertain protolith that may be part of the basement complex was encountered in the Ikpikpuk well. Seismic data indicate that angular unconformities truncate all sedimentary units of the basement complex in NPRA. Rocks correlative in age and lithofacies with the dark argillite and chert unit occur in the subsurface near Prudhoe Bay. Other argillite units in NPRA have similarities to basement rocks in the subsurface adjacent to ANWR and the Ordovician-Silurian Iviagik Group at Cape Lisburne, but lack the interbedded limestones found in the ANWR strata, and are less metamorphosed than, and compositionally distinct from, the Iviagik. The Topagoruk conglomerate and the East Teshekpuk granite resemble the Ulungarat formation and the Okpilak batholith, respectively, in the northeastern Brooks Range.
Salisbury, M.J.; Bohrson, W.A.; Clynne, M.A.; Ramos, F.C.; Hoskin, P.
2008-01-01
Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge-magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0??5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0??1 and 0??5 mm) that have core An contents of 66-69, and microlites (long axis < 0??1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution-precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/ or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma bodies. ?? The Author 2008. Published by Oxford University Press. All rights reserved.
ERIC Educational Resources Information Center
College Entrance Examination Board, New York, NY. Commission on English.
Literature, language, and composition are integrated in this collection of 30 model teaching units for grades 9-12. The units are concerned with (1) the explication and comparison of novels by Hemingway, Wilder, Kipling, and Knowles, (2) short story techniques used by writers from Poe to Joyce, (3) poetic structure and themes as demonstrated in…
The Gills of Reef Fish Support a Distinct Microbiome Influenced by Host-Specific Factors.
Pratte, Zoe A; Besson, Marc; Hollman, Rebecca D; Stewart, Frank J
2018-05-01
Teleost fish represent the most diverse of the vertebrate groups and play important roles in food webs, as ecosystem engineers, and as vectors for microorganisms. However, the microbial ecology of fishes remains underexplored for most host taxa and for certain niches on the fish body. This is particularly true for the gills, the key sites of respiration and waste exchange in fishes. Here we provide a comprehensive analysis of the gill microbiome. We focus on ecologically diverse taxa from coral reefs around Moorea, sampling the gills and intestines of adults and juveniles representing 15 families. The gill microbiome composition differed significantly from that of the gut for both adults and juveniles, with fish-associated niches having lower alpha diversity values and higher beta diversity values than those for seawater, sediment, and alga-associated microbiomes. Of ∼45,000 operational taxonomic units (OTUs) detected across all samples, 11% and 13% were detected only in the gill and the intestine, respectively. OTUs most enriched in the gill included members of the gammaproteobacterial genus Shewanella and the family Endozoicimonaceae In adult fish, both gill and intestinal microbiomes varied significantly among host species grouped by diet category. Gill and intestinal microbiomes from the same individual were more similar to one another than to gill and intestinal microbiomes from different individuals. These results demonstrate that distinct body sites are jointly influenced by host-specific organizing factors operating at the level of the host individual. The results also identify taxonomic signatures unique to the gill and the intestine, confirming fish-associated niches as distinct reservoirs of marine microbial diversity. IMPORTANCE Fish breathe and excrete waste through their gills. The gills are also potential sites of pathogen invasion and colonization by other microbes. However, we know little about the microbial communities that live on the gill and the factors shaping their diversity. Focusing on ecologically distinct types of coral reef fish, we provide a comprehensive analysis of the fish gill microbiome. By comparison to microbiomes of the gut and the surrounding environment, we identify microbes unique to the gill niche. These microbes may be targets for further studies to determine the contribution of the microbiome to waste exchange or host immunity. We also show that despite exhibiting a unique taxonomic signature, the gill microbiome is influenced by factors that also influence the gut microbiome. These factors include the specific identity of the host individual. These results suggest basic principles describing how association with fishes structures the composition of microbial communities. Copyright © 2018 American Society for Microbiology.
Mixing and mingling in Iceland: The origin of a diverse suite of Tertiary lavas
NASA Astrophysics Data System (ADS)
Jordan, B. T.
2006-12-01
A sequence of intermediate and silicic volcanic units occurs within a stratigraphic package dominated by moderately evolved tholeiitic basalts in the mountains Laxardalsfjoll and Langadalsfjall in the southern Skagi Peninsula of north-central Iceland. This sequence consists of several minor rhyolite and dacite lavas directly overlain by a voluminous (>3 km3) litholigically diverse andesite to rhyolite lava flow Above this flow is a basaltic andesite to dacite lava, or lavas (mapping not complete), and the sequence is capped by an extensive rhyolite lava. Pyroclastic deposits, including one welded tuff, occur within the sequence. The sequence was erupted at 7.8 Ma, not long before the abandonment of the Skagi-Snaefellsnes rift zone in which it was erupted. The rhyolite lavas are generally aphyric. The lower rhyolites are of variable composition (71-75% SiO2) and the upper is a high-silica rhyolite (75-76% SiO2). The lower dacite and upper basaltic andesite to dacite lava(s) are aphyric and plot on a linear mixing trend between well defined end-members, a moderately evolved basalt and a high-silica rhyolite. The most anomalous unit is the andesite-rhyolite lava. It is lithologically heterogeneous with <<1% to 20% coarse (up to 3 cm) nearly equant plagioclase phenocrysts. Lithologies commonly vary across sharp borders within the flow, with domains of different lithologies being up to 10s of m in extent. The coarse plagioclase phenocrysts are calcic, up to An87 indicating an origin in basaltic magma. The whole rock composition varies from andesite (58% SiO2) to rhyolite (70% SiO2). Silica content is inversely correlated with phenocryst abundance, but can not be explained by phenocrysts alone. A wide range of mixing and mingling textures are observed at mesoscopic and microscopic scales. Major and trace element variations are quite distinct from the other mixed unit and indicate that the end members of mixing are a plagioclase-rich basalt and a range of silicic compositions from dacite to low-silica rhyolite. A candidate for the mafic end member of mixing is a plagioclase-ultraphyric basalt mapped in Vatnsdalsfjall (~10 km away). It has similar coarse equant plagioclase phenocrysts (up to 35%), with identical An-contents and distinctive patterns of inclusions. I propose that a dike that fed this lava also propagated at depth into a zoned dacite-rhyolite magma chamber, similar to the AD 1480 propagation of the Veidivotn fissure into the Torfajokull caldera. This triggered a large eruption from the zone of mingling/mixing, followed by a significant eruption from the evolved upper portion of the magma chamber. The diverse underlying small-volume rhyolites had been the normal products erupted from the zoned silicic magma chamber. The origin of the second, basaltic andesite to dacite, mixing trend is equivocal. The lavas constituting this trend occur immediately below and above the porphyritic lava suggesting that mixing between normal tholeiite and high-silica rhyolite magmas was ongoing in the upper part of the magma chamber at the time of the main eruption.
Halogen and LED light curing of composite: temperature increase and Knoop hardness.
Schneider, L F; Consani, S; Correr-Sobrinho, L; Correr, A B; Sinhoreti, M A
2006-03-01
This study assessed the Knoop hardness and temperature increase provided by three light curing units when using (1) the manufacturers' recommended times of photo-activation and (2) standardizing total energy density. One halogen--XL2500 (3M/ESPE)--and two light-emitting diode (LED) curing units--Freelight (3M/ESPE) and Ultrablue IS (DMC)--were used. A type-K thermocouple registered the temperature change produced by the composite photo-activation in a mold. Twenty-four hours after the photo-activation procedures, the composite specimens were submitted to a hardness test. Both temperature increase and hardness data were submitted to ANOVA and Tukey's test (5% significance). Using the first set of photo-activation conditions, the halogen unit produced a statistically higher temperature increase than did both LED units, and the Freelight LED resulted in a lower hardness than did the other curing units. When applying the second set of photo-activation conditions, the two LED units produced statistically greater temperature increase than did the halogen unit, whereas there were no statistical differences in hardness among the curing units.
NASA Astrophysics Data System (ADS)
Słodczyk, Elżbieta; Pietranik, Anna; Glynn, Sarah; Wiedenbeck, Michael; Breitkreuz, Christoph; Dhuime, Bruno
2018-02-01
The Polish Lowlands, located southwest of the Teisseyre-Tornquist Zone, within Trans-European Suture Zone, were affected by bimodal, but dominantly rhyolitic, magmatism during the Late Paleozoic. Thanks to the inherited zircon they contain, these rhyolitic rocks provide a direct source of information about the pre-Permian rocks underlying the Polish Lowland. This paper presents zircon U-Pb geochronology and Hf and O isotopic results from five drill core samples representing four rhyolites and one granite. Based on the ratio of inherited vs. autocrystic zircon, the rhyolites can be divided into two groups: northern rhyolites, where autocrystic zircon is more abundant and southern rhyolites, where inherited zircon dominates. We suggest that the magma sources and the processes responsible for generating high silica magmas differ between the northern and southern rhyolites. Isotopically distinct sources were available during formation of northern rhyolites, as the Hf and O isotopes in magmatic zircon differ between the two analysed localities of northern rhyolites. A mixing between magmas formed from Baltica-derived mudstone-siltstone sediments and Avalonian basement or mantle can explain the diversity between the zircon compositions from the northern localities Daszewo and Wysoka Kamieńska. Conversely, the southern rhyolites from our two localities contain zircon with similar compositions, and these units can be further correlated with results from the North East German Basin, suggesting uniform source rocks over this larger region. Based on the ages of inherited zircon and the isotopic composition of magmatic ones, we suggest that the dominant source of the southern rhyolites is Variscan foreland sediments mixed with Baltica/Avalonia-derived sediments.
The mineralogy, petrology, and composition of anomalous eucrite Emmaville
NASA Astrophysics Data System (ADS)
Barrett, T. J.; Mittlefehldt, D. W.; Greenwood, R. C.; Charlier, B. L. A.; Hammond, S. J.; Ross, D. K.; Anand, M.; Franchi, I. A.; Abernethy, F. A. J.; Grady, M. M.
2017-04-01
The Emmaville eucrite is a relatively poorly studied basaltic achondrite with an anomalous oxygen isotope signature. In this study, we report comprehensive mineralogical, petrographic, and geochemical data from Emmaville in order to understand its petrogenesis and relationship with the basaltic eucrites. Emmaville is an unusually fine-grained, hornfelsic-textured metabasalt with pervasive impact melt veins and mineral compositions similar to those of typical basaltic eucrites. The major and trace element bulk composition of Emmaville is also typical of a basaltic eucrite. Three separated individual lithologies were also analyzed for O isotopes; a dark gray fraction (E1), a shocked lithology (E2), and a lighter gray portion (E3). Fractions E1 and E2 shared similar O isotope compositions to the bulk sample (E-B), whereas the lighter gray portion (E3) is slightly elevated in Δ17O and significantly elevated in δ18O compared to bulk. No evidence for any exogenous material is observed in the thin sections, coupled with the striking compositional similarity to typical basaltic eucrites, appears to preclude a simple impact-mixing hypothesis. The O-isotopes of Emmaville are similar to those of Bunburra Rockhole, A-881394, and EET 92023, and thus distinct from the majority of the HEDs, despite having similarities in petrology, mineral, and bulk compositions. It would, therefore, seem plausible that all four of these samples are derived from a single HED-like parent body that is isotopically distinct from that of the HEDs (Vesta) but similar in composition.
Exploring the Impact of Changes in Group Composition on Trends in Specialization
ERIC Educational Resources Information Center
Armstrong, Todd A.
2008-01-01
Stander and colleagues, in 1989, noted that change in specialization may be caused by two distinct but potentially complementary processes: (a) a change in group composition, where change in specialization is the product of the attrition of offenders who vary systematically in their tendency to specialize; and (b) a change in the tendency to…
Superbubbles and Local Cosmic Rays
NASA Technical Reports Server (NTRS)
Streitmatter, Robert E.; Jones, Frank C.
2005-01-01
We consider the possibility that distinctive features of the local cosmic ray spectra and composition are influenced by the Solar system being embedded within the cavity of an ancient superbubble. Shifts in the measured cosmic ray composition between 10(exp 11) and 10(exp 20) eV as well as the "knee" and "second knee" may be understood in this picture.
School Regimes and Education Equity: Some Insights Based on PISA 2006
ERIC Educational Resources Information Center
Alegre, Miquel Angel; Ferrer, Gerard
2010-01-01
This paper aims to analyze the effects of certain characteristics of the educational systems on the social composition of schools. After accounting for significant effects of schools' social composition on student outcomes (this is confirmed on the basis of a multilevel analysis), we explore the impacts of distinct components of what we name…
NASA Technical Reports Server (NTRS)
Shearer, C. K.; Messenger, S.; Sharp, Z. D.; Burger, P. V.; Nguyen, N.; McCubbin, F. M.
2017-01-01
The style, magnitude, timing, and mixing components involved in the interaction between mantle derived Martian magmas and Martian crust have long been a point of debate. Understanding this process is fundamental to deciphering the composition of the Martian crust and its interaction with the atmosphere, the compositional diversity and oxygen fugacity variations in the Martian mantle, the bulk composition of Mars and the materials from which it accreted, and the noble gas composition of Mars and the Sun. Recent studies of the chlorine isotopic composition of Martian meteorites imply that although the variation in delta (sup 37) Cl is limited (total range of approximately14 per mille), there appears to be distinct signatures for the Martian crust and mantle. However, there are potential issues with this interpretation. New Cl isotope data from the SAM (Sample Analysis at Mars) instrument on the Mars Science Lab indicate a very wide range of Cl isotopic compositions on the Martian surface. Recent measurements by [10] duplicated the results of [7,8], but placed them within the context of SAM surface data. In addition, Martian meteorite Chassigny contains trapped noble gases with isotopic ratios similar to solar abundance, and has long been considered a pristine, mantle derived sample. However, previous studies of apatite in Chassigny indicate that crustal fluids have interacted with regions interstitial to the cumulus olivine. The initial Cl isotope measurements of apatite in Chassigny suggest an addition of crustal component to this lithology, apparently contradicting the rare gas data. Here, we examine the Cl isotopic composition of multiple generations and textures of apatite in Chassigny to extricate the crustal and mantle components in this meteorite and to reveal the style and timing of the addition of crustal components to mantle-derived magmas. These data reveal distinct Martian Cl sources whose signatures have their origins linked to both the early Solar System and the evolving Martian atmosphere.
NASA Astrophysics Data System (ADS)
Huyghe, Damien; Mouthereau, Frédéric; Sébilo, Mathieu; Vacherat, Arnaud; Ségalen, Loïc; Richard, Patricia; Biron, Philippe; Bariac, Thierry
2018-02-01
Understanding how orogenic topography controls the spatial distribution and isotopic composition of precipitation is critical for paleoaltitudinal reconstructions. Here, we determine the isotopic composition (δ18O and δD) of 82 small rivers and springs from small catchments in the Pyrenees. Calculation of the deuterium excess (d-excess) parameter allows the distinction of four distinct isotopic provinces with d-excess values of between 15 and 22‰ in the northwest, between 7 and 14‰ in the central northern Pyrenees and between 3 and 11‰ in the northeast. The southern Pyrenees have a homogenous d-excess signature ranging from 7 to 14‰. Our results show significant local moisture recycling and/or rain amount effect in the northwestern Pyrenees, and control by evaporation processes during rainfall events in the southern Pyrenees and for low elevated samples of the northeast of the range. Based on the distribution of d-excess values, we estimate contrasting isotope lapse rates of -2.9/-21.4‰/km (δ18O/δD) in the northwest, -2.7/-21.4‰/km (δ18O/δD) in the north central and -3.7/-31.7‰/km (δ18O/δD) in the northeastern Pyrenees. The southern Pyrenees show distinctly higher lapse rates of -9.5/-77.5‰/km (δ18O/δD), indicating that in this area the altitudinal effect in not the only parameter driving isotopic composition of rivers. Despite their relatively low topographic gradient, the Pyrenees exert a direct control on the isotopic composition of river waters, especially on their northern side. The variations in isotopic composition-elevation relationships documented along the strike of the range are interpreted to reflect an increasing continentality effect driven by wind trajectories parallel to the range, and mixing with Mediterranean air masses. Despite these effects, the measurable orographic effect on precipitation in the Pyrenees proves that the isotopic composition approach for reconstructing past topography is applicable to low-elevation orogens.
High-performance flexible hydrogen sensor made of WS2 nanosheet-Pd nanoparticle composite film
NASA Astrophysics Data System (ADS)
Kuru, Cihan; Choi, Duyoung; Kargar, Alireza; Liu, Chin Hung; Yavuz, Serdar; Choi, Chulmin; Jin, Sungho; Bandaru, Prabhakar R.
2016-05-01
We report a flexible hydrogen sensor, composed of WS2 nanosheet-Pd nanoparticle composite film, fabricated on a flexible polyimide substrate. The sensor offers the advantages of light-weight, mechanical durability, room temperature operation, and high sensitivity. The WS2-Pd composite film exhibits sensitivity (R 1/R 2, the ratio of the initial resistance to final resistance of the sensor) of 7.8 to 50 000 ppm hydrogen. Moreover, the WS2-Pd composite film distinctly outperforms the graphene-Pd composite, whose sensitivity is only 1.14. Furthermore, the ease of fabrication holds great potential for scalable and low-cost manufacturing of hydrogen sensors.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yang, Kang; Wu, Sujun; Guan, Juan
Strong and tough epoxy composites are developed using a less-studied fibre reinforcement, that of natural silk. Two common but structurally distinct silks from the domestic B. mori/Bm and the wild A. pernyi/Ap silkworms are selected in fabric forms. We show that the toughening effects on silk-epoxy composites or SFRPs are dependent on the silk species and the volume fraction of silk. Both silks enhance the room-temperature tensile and flexural mechanical properties of the composite, whereas the more resilient Ap silk shows a more pronounced toughening effect and a lower critical reinforcement volume for the brittle-ductile transition. Specifically, our 60 vol.%more » Ap-SFRP displays a three-fold elevation in tensile and flexural strength, as compared to pure epoxy resin, with an order of magnitude higher breaking energy via a distinct, ductile failure mode. Importantly, the 60 vol.% Ap-SFRP remains ductile with 7% flexural elongation at lower temperatures (-50 °C). Under impact, these SFRPs show significantly improved energy absorption, and the 60 vol.% Ap-SFRP has an impact strength some eight times that of pure epoxy resin. Lastly, the findings demonstrate both marked toughening and strengthening effects for epoxy composites from natural silk reinforcements, which presents opportunities for mechanically superior and "green" structural composites.« less
NASA Astrophysics Data System (ADS)
Fitzpatrick, Robert; Hauer, Cole; Kyrillos, Carl; McGorty, Ryan; Robertson-Anderson, Rae
Entangled polymers have complex viscoelastic properties that are tuned by polymer lengths and flexibilities. Entangled composites of distinct polymers offer added versatility and display nonlinear mechanics, serving as a platform for multifunctional materials. To determine the role of flexibility and length in polymer composites we use optical tweezers and confocal microscopy to measure mechanical and structural properties of co-entangled actin and DNA. Actin filaments have lengths of 5-20 μm, comparable to their persistence length, while DNA of similar lengths have hundreds of persistence lengths per chain. To characterize the nonlinear mechanics of actin-DNA composites, we optically drive a microsphere through the composite and measure the induced force during and following strain. We characterize viscoelasticity and relaxation timescales; and determine the dependence of these quantities on the actin:DNA ratio (0:1-1:0) and DNA length (4-100 μm). We use confocal microscopy to image distinctly labeled co-entangled actin and DNA and characterize network homogeneity and fluctuations. Initial results show actin and DNA are well-integrated and form structurally homogenous networks that exhibit stiffness and relaxation times that increase nonlinearly with increased actin. NSF Career Award (DMR-1254340), AFOSR Young Investigator Program Award (FA95550-12-1-0315), Scialog Collaborative Innovation Award funed by Research Corp. for Scientific Advancement (24192).
NASA Astrophysics Data System (ADS)
Cagno, S.; De Raedt, I.; Jeffries, T.; Janssens, K.
SEM-EDX and LA-ICP-MS analyses were performed on a set of early 17th century London glass fragments. The samples originate from two archaeological sites (Aldgate and Old Broad Street) where glass workshops were active in this period. The great majority of the samples are made of soda glass. Two distinct compositional groups are observed, each typical of one site of provenance. The samples originating from the Old Broad Street excavation feature a silica-soda-lime composition, with a moderate amount of potash. The samples from Aldgate are richer in potassium and feature higher amounts of trace elements such as Rb, Zr and Cu. The distinction between the two groups stems from different flux and silica sources used for glassmaking. A comparison with different European glass compositions of that time reveals no resemblance with genuine Venetian production, yet the composition of the Old Broad Street glass shows a close similarity to that of fragments produced `à la façon de Venise' in Antwerp at the end of the 16th century. This coincides with historical sources attesting the arrival of glassworkers from the Low Countries in England and suggests that a transfer of technology took place near the turn of the century.
Unit area control in California forests
William E. Hallin
1951-01-01
There is a definite distinction between the basic concept of unit area control and the specific techniques or treatments used for specific units. Unit area control as a term was first used in connection with a cutting trial in the sugar pine-fir type; consequently, many foresters think the term refers merely to the technique used in sugar pine management, This is not...
16 CFR 500.15 - Units of count, more than one ply.
Code of Federal Regulations, 2012 CFR
2012-01-01
... 16 Commercial Practices 1 2012-01-01 2012-01-01 false Units of count, more than one ply. 500.15... SECTION 4 OF THE FAIR PACKAGING AND LABELING ACT § 500.15 Units of count, more than one ply. If the commodity is in distinct usable units made up of one or more components or ply, the statement of net...
16 CFR 500.15 - Units of count, more than one ply.
Code of Federal Regulations, 2011 CFR
2011-01-01
... 16 Commercial Practices 1 2011-01-01 2011-01-01 false Units of count, more than one ply. 500.15... SECTION 4 OF THE FAIR PACKAGING AND LABELING ACT § 500.15 Units of count, more than one ply. If the commodity is in distinct usable units made up of one or more components or ply, the statement of net...
16 CFR 500.15 - Units of count, more than one ply.
Code of Federal Regulations, 2013 CFR
2013-01-01
... 16 Commercial Practices 1 2013-01-01 2013-01-01 false Units of count, more than one ply. 500.15... SECTION 4 OF THE FAIR PACKAGING AND LABELING ACT § 500.15 Units of count, more than one ply. If the commodity is in distinct usable units made up of one or more components or ply, the statement of net...
16 CFR 500.15 - Units of count, more than one ply.
Code of Federal Regulations, 2010 CFR
2010-01-01
... 16 Commercial Practices 1 2010-01-01 2010-01-01 false Units of count, more than one ply. 500.15... SECTION 4 OF THE FAIR PACKAGING AND LABELING ACT § 500.15 Units of count, more than one ply. If the commodity is in distinct usable units made up of one or more components or ply, the statement of net...
16 CFR 500.15 - Units of count, more than one ply.
Code of Federal Regulations, 2014 CFR
2014-01-01
... 16 Commercial Practices 1 2014-01-01 2014-01-01 false Units of count, more than one ply. 500.15... SECTION 4 OF THE FAIR PACKAGING AND LABELING ACT § 500.15 Units of count, more than one ply. If the commodity is in distinct usable units made up of one or more components or ply, the statement of net...
The Gaseous State. Independent Learning Project for Advanced Chemistry (ILPAC). Unit P1.
ERIC Educational Resources Information Center
Inner London Education Authority (England).
This unit on the gaseous state is one of 10 first year units produced by the Independent Learning Project for Advanced Chemistry (ILPAC). The unit consists of two levels. Level one deals with the distinctive characteristics of gases, then considers the gas laws, in particular the ideal gas equation and its applications. Level two concentrates on…
Automated extraction and classification of time-frequency contours in humpback vocalizations.
Ou, Hui; Au, Whitlow W L; Zurk, Lisa M; Lammers, Marc O
2013-01-01
A time-frequency contour extraction and classification algorithm was created to analyze humpback whale vocalizations. The algorithm automatically extracted contours of whale vocalization units by searching for gray-level discontinuities in the spectrogram images. The unit-to-unit similarity was quantified by cross-correlating the contour lines. A library of distinctive humpback units was then generated by applying an unsupervised, cluster-based learning algorithm. The purpose of this study was to provide a fast and automated feature selection tool to describe the vocal signatures of animal groups. This approach could benefit a variety of applications such as species description, identification, and evolution of song structures. The algorithm was tested on humpback whale song data recorded at various locations in Hawaii from 2002 to 2003. Results presented in this paper showed low probability of false alarm (0%-4%) under noisy environments with small boat vessels and snapping shrimp. The classification algorithm was tested on a controlled set of 30 units forming six unit types, and all the units were correctly classified. In a case study on humpback data collected in the Auau Chanel, Hawaii, in 2002, the algorithm extracted 951 units, which were classified into 12 distinctive types.
What Is the Unit of Visual Attention? Object for Selection, but Boolean Map for Access
ERIC Educational Resources Information Center
Huang, Liqiang
2010-01-01
In the past 20 years, numerous theories and findings have suggested that the unit of visual attention is the object. In this study, I first clarify 2 different meanings of unit of visual attention, namely the unit of access in the sense of measurement and the unit of selection in the sense of division. In accordance with this distinction, I argue…
Dissociative effects of orthographic distinctiveness in pure and mixed lists: an item-order account.
McDaniel, Mark A; Cahill, Michael; Bugg, Julie M; Meadow, Nathaniel G
2011-10-01
We apply the item-order theory of list composition effects in free recall to the orthographic distinctiveness effect. The item-order account assumes that orthographically distinct items advantage item-specific encoding in both mixed and pure lists, but at the expense of exploiting relational information present in the list. Experiment 1 replicated the typical free recall advantage of orthographically distinct items in mixed lists and the elimination of that advantage in pure lists. Supporting the item-order account, recognition performances indicated that orthographically distinct items received greater item-specific encoding than did orthographically common items in mixed and pure lists (Experiments 1 and 2). Furthermore, order memory (input-output correspondence and sequential contiguity effects) was evident in recall of pure unstructured common lists, but not in recall of unstructured distinct lists (Experiment 1). These combined patterns, although not anticipated by prevailing views, are consistent with an item-order account.
NASA Astrophysics Data System (ADS)
Tweedley, J. R.; Warwick, R. M.; Potter, I. C.
2015-08-01
Because estuaries are naturally stressed, due to variations in salinity, organic loadings, sediment stability and oxygen concentrations over both spatial and temporal scales, it is difficult both to set baseline reference conditions and to distinguish between natural and anthropogenic environmental stresses. This contrasts with the situation in marine coastal and offshore locations. A very large benthic macroinvertebrate dataset and matching concentrations for seven toxic heavy metals (i.e. Cr, Ni, Cu, Zn, Cd, Hg and Pb), compiled over three years as part of the UK's National Marine Monitoring Programme (NMMP) for 27 subtidal sites in 16 estuaries and 34 coastal marine sites in the United Kingdom, have been analysed. The results demonstrate that species composition and most benthic biotic indicators (number of taxa, overall density, Shannon-Wiener diversity, Simpson's index and AZTI's Marine Biotic Index [AMBI]) for sites in estuarine and coastal areas were significantly different, reflecting natural differences between these two environments. Shannon-Wiener diversity and AMBI were not significantly correlated either with overall heavy metal contaminant loadings or with individual heavy metal concentrations ('normalized' as heavy metal/aluminium ratios) in estuaries. In contrast, average taxonomic distinctness (Δ+) and variation in taxonomic distinctness (Λ+) did not differ significantly between estuarine and coastal environments, i.e. they were unaffected by natural differences between these two environments, but both were significantly correlated with overall heavy metal concentrations. Furthermore, Δ+ was correlated significantly with the Cu, Zn, Cd, Hg and Pb concentrations and Λ+ was correlated significantly with the Cr, Ni, Cu, Cd and Hg concentrations. Thus, one or both of these two taxonomic distinctness indices are significantly correlated with the concentrations for each of these seven heavy metals. These taxonomic distinctness indices are therefore considered appropriate indicators of anthropogenic disturbance in estuaries, as they allow a regional reference condition to be set from which significant departures can then be determined.
NASA Astrophysics Data System (ADS)
Hochmuth, Katharina; Gohl, Karsten; Uenzelmann-Neben, Gabriele
2014-05-01
The Manihiki Plateau is a Large Igneous Province (LIP) located in the Central Pacific. It is assumed, that the formation of the Manihiki Plateau took place during the early Cretaceous in multiple volcanic stages as part of the "Super-LIP" Ontong-Java-Nui. The plateau consists of several sub-plateaus of which the Western Plateau und High Plateau are the largest. In addressing the plateau's magmatic evolutionary history, one of the key questions is whether all sub-plateaus experienced the same magmatic history or if distinct phases of igneous or tectonic processes led to its fragmentation. During the RV Sonne cruise SO-224 in 2012; we collected two deep crustal seismic refraction/wide-angle reflection lines, crossing the two main sub-plateaus. Modeling of P- and S-wave phases reveals the different crustal nature of both sub-plateaus. On the High Plateau, the 20 km thick crust is divided into four seismic units, interpreted to range from basaltic composition in the uppermost crust to peridotitic composition in the middle and lower crust. The Western Plateau on the other hand shows multiple rift structures and no indications of basalt flows. With a maximum of 17 km crustal thickness, the Western Plateau is also thinner than the High Plateau. The upper basement layers show relatively low P-wave velocities (3.0 - 5.0 km/s), which infers that on the Western Plateau these layers consist of volcanoclastic and carbonatic rocks rather than basaltic flow units. Later volcanic stages may be restricted to the High Plateau with a possible eastward trend in the center of volcanic activity. Extensive secondary volcanism does not seem to have occurred on the Western Plateau, and its later deformation is mainly caused by tectonic extension and rifting.
Geologic map of the east half of the Lime Hills 1:250,000-scale quadrangle, Alaska
Gamble, Bruce M.; Reed, Bruce L.; Richter, Donald H.; Lanphere, Marvin A.
2013-01-01
This map is compiled from geologic mapping conducted between 1985 and 1992 by the U.S. Geological Survey as part of the Alaska Mineral Resource Assessment Program. That mapping built upon previous USGS work (1963–1988) unraveling the magmatic history of the Alaska–Aleutian Range batholith. Quaternary unit contacts depicted on this map are derived largely from aerial-photograph interpretation. K-Ar ages made prior to this study have been recalculated using 1977 decay constants. The east half of the Lime Hills 1:250,000-scale quadrangle includes part of the Alaska–Aleutian Range batholith and several sequences of sedimentary rocks or mixed sedimentary and volcanic rocks. The Alaska–Aleutian Range batholith contains rocks that represent three major igneous episodes, (1) Early and Middle Jurassic, (2) Late Cretaceous and early Tertiary, and (3) middle Tertiary; only rocks from the latter two episodes are found in this map area. The map area is one of very steep and rugged terrain; elevations range from a little under 1,000 ft (305 m) to 9,828 ft (2,996 m). Foot traverses are generally restricted to lowermost elevations. Areas suitable for helicopter landings can be scarce at higher elevations. Most of the area was mapped from the air, supplemented by direct examination of rocks where possible. This restricted access greatly complicates understanding some of the more complex geologic units. For example, we know there are plutons whose compositions vary from gabbro to granodiorite, but we have little insight as to how these phases are distributed and what their relations might be to each other. It is also possible that some of what we have described as compositionally complex plutons might actually be several distinct intrusions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wu, C.H.; Sercu, B.; Van De Werhorst, L.C.
2010-03-01
Microbial communities in aquatic environments are spatially and temporally dynamic due to environmental fluctuations and varied external input sources. A large percentage of the urban watersheds in the United States are affected by fecal pollution, including human pathogens, thus warranting comprehensive monitoring. Using a high-density microarray (PhyloChip), we examined water column bacterial community DNA extracted from two connecting urban watersheds, elucidating variable and stable bacterial subpopulations over a 3-day period and community composition profiles that were distinct to fecal and non-fecal sources. Two approaches were used for indication of fecal influence. The first approach utilized similarity of 503 operational taxonomicmore » units (OTUs) common to all fecal samples analyzed in this study with the watershed samples as an index of fecal pollution. A majority of the 503 OTUs were found in the phyla Firmicutes, Proteobacteria, Bacteroidetes, and Actinobacteria. The second approach incorporated relative richness of 4 bacterial classes (Bacilli, Bacteroidetes, Clostridia and a-proteobacteria) found to have the highest variance in fecal and non-fecal samples. The ratio of these 4 classes (BBC:A) from the watershed samples demonstrated a trend where bacterial communities from gut and sewage sources had higher ratios than from sources not impacted by fecal material. This trend was also observed in the 124 bacterial communities from previously published and unpublished sequencing or PhyloChip- analyzed studies. This study provided a detailed characterization of bacterial community variability during dry weather across a 3-day period in two urban watersheds. The comparative analysis of watershed community composition resulted in alternative community-based indicators that could be useful for assessing ecosystem health.« less
Wu, Cindy H.; Sercu, Bram; Van De Werfhorst, Laurie C.; Wong, Jakk; DeSantis, Todd Z.; Brodie, Eoin L.; Hazen, Terry C.; Holden, Patricia A.; Andersen, Gary L.
2010-01-01
Background Microbial communities in aquatic environments are spatially and temporally dynamic due to environmental fluctuations and varied external input sources. A large percentage of the urban watersheds in the United States are affected by fecal pollution, including human pathogens, thus warranting comprehensive monitoring. Methodology/Principal Findings Using a high-density microarray (PhyloChip), we examined water column bacterial community DNA extracted from two connecting urban watersheds, elucidating variable and stable bacterial subpopulations over a 3-day period and community composition profiles that were distinct to fecal and non-fecal sources. Two approaches were used for indication of fecal influence. The first approach utilized similarity of 503 operational taxonomic units (OTUs) common to all fecal samples analyzed in this study with the watershed samples as an index of fecal pollution. A majority of the 503 OTUs were found in the phyla Firmicutes, Proteobacteria, Bacteroidetes, and Actinobacteria. The second approach incorporated relative richness of 4 bacterial classes (Bacilli, Bacteroidetes, Clostridia and α-proteobacteria) found to have the highest variance in fecal and non-fecal samples. The ratio of these 4 classes (BBC∶A) from the watershed samples demonstrated a trend where bacterial communities from gut and sewage sources had higher ratios than from sources not impacted by fecal material. This trend was also observed in the 124 bacterial communities from previously published and unpublished sequencing or PhyloChip- analyzed studies. Conclusions/Significance This study provided a detailed characterization of bacterial community variability during dry weather across a 3-day period in two urban watersheds. The comparative analysis of watershed community composition resulted in alternative community-based indicators that could be useful for assessing ecosystem health. PMID:20585654
Large variability of bathypelagic microbial eukaryotic communities across the world's oceans.
Pernice, Massimo C; Giner, Caterina R; Logares, Ramiro; Perera-Bel, Júlia; Acinas, Silvia G; Duarte, Carlos M; Gasol, Josep M; Massana, Ramon
2016-04-01
In this work, we study the diversity of bathypelagic microbial eukaryotes (0.8-20 μm) in the global ocean. Seawater samples from 3000 to 4000 m depth from 27 stations in the Atlantic, Pacific and Indian Oceans were analyzed by pyrosequencing the V4 region of the 18S ribosomal DNA. The relative abundance of the most abundant operational taxonomic units agreed with the results of a parallel metagenomic analysis, suggesting limited PCR biases in the tag approach. Although rarefaction curves for single stations were seldom saturated, the global analysis of all sequences together suggested an adequate recovery of bathypelagic diversity. Community composition presented a large variability among samples, which was poorly explained by linear geographic distance. In fact, the similarity between communities was better explained by water mass composition (26% of the variability) and the ratio in cell abundance between prokaryotes and microbial eukaryotes (21%). Deep diversity appeared dominated by four taxonomic groups (Collodaria, Chrysophytes, Basidiomycota and MALV-II) appearing in different proportions in each sample. Novel diversity amounted to 1% of the pyrotags and was lower than expected. Our study represents an essential step in the investigation of bathypelagic microbial eukaryotes, indicating dominating taxonomic groups and suggesting idiosyncratic assemblages in distinct oceanic regions.
Morphology and composition of the surface of Mars: Mars Odyssey THEMIS results.
Christensen, Philip R; Bandfield, Joshua L; Bell, James F; Gorelick, Noel; Hamilton, Victoria E; Ivanov, Anton; Jakosky, Bruce M; Kieffer, Hugh H; Lane, Melissa D; Malin, Michael C; McConnochie, Timothy; McEwen, Alfred S; McSween, Harry Y; Mehall, Greg L; Moersch, Jeffery E; Nealson, Kenneth H; Rice, James W; Richardson, Mark I; Ruff, Steven W; Smith, Michael D; Titus, Timothy N; Wyatt, Michael B
2003-06-27
The Thermal Emission Imaging System (THEMIS) on Mars Odyssey has produced infrared to visible wavelength images of the martian surface that show lithologically distinct layers with variable thickness, implying temporal changes in the processes or environments during or after their formation. Kilometer-scale exposures of bedrock are observed; elsewhere airfall dust completely mantles the surface over thousands of square kilometers. Mars has compositional variations at 100-meter scales, for example, an exposure of olivine-rich basalt in the walls of Ganges Chasma. Thermally distinct ejecta facies occur around some craters with variations associated with crater age. Polar observations have identified temporal patches of water frost in the north polar cap. No thermal signatures associated with endogenic heat sources have been identified.
Morphology and composition of the surface of Mars: Mars Odyssey THEMIS results
Christensen, P.R.; Bandfield, J.L.; Bell, J.F.; Gorelick, N.; Hamilton, V.E.; Ivanov, A.; Jakosky, B.M.; Kieffer, H.H.; Lane, M.D.; Malin, M.C.; McConnochie, T.; McEwen, A.S.; McSween, H.Y.; Mehall, G.L.; Moersch, J.E.; Nealson, K.H.; Rice, J. W.; Richardson, M.I.; Ruff, S.W.; Smith, M.D.; Titus, T.N.; Wyatt, M.B.
2003-01-01
The Thermal Emission Imaging System (THEMIS) on Mars Odyssey has produced infrared to visible wavelength images of the martian surface that show lithologically distinct layers with variable thickness, implying temporal changes in the processes or environments during or after their formation. Kilometer-scale exposures of bedrock are observed; elsewhere airfall dust completely mantles the surface over thousands of square kilometers. Mars has compositional variations at 100-meter scales, for example, an exposure of olivine-rich basalt in the walls of Ganges Chasma. Thermally distinct ejecta facies occur around some craters with variations associated with crater age. Polar observations have identified temporal patches of water frost in the north polar cap. No thermal signatures associated with endogenic heat sources have been identified.
Cost containment and mechanical ventilation in the United States.
Cohen, I L; Booth, F V
1994-08-01
In many ICUs, admission and discharge hinge on the need for intubation and ventilatory support. As few as 5% to 10% of ICU patients require prolonged mechanical ventilation, and this patient group consumes > or = 50% of ICU patient days and ICU resources. Prolonged ventilatory support and chronic ventilator dependency, both in the ICU and non-ICU settings, have a significant and growing impact on healthcare economics. In the United States, the need for prolonged mechanical ventilation is increasingly recognized as separate and distinct from the initial diagnosis and/or procedure that leads to hospitalization. This distinction has led to improved reimbursement under the prospective diagnosis-related group (DRG) system, and demands more precise accounting from healthcare providers responsible for these patients. Using both published and theoretical examples, mechanical ventilation in the United States is discussed, with a focus on cost containment. Included in the discussion are ventilator teams, standards of care, management protocols, stepdown units, rehabilitation units, and home care. The expanding role of total quality management (TQM) is also presented.
Internal stratigraphy of the South Polar Layered Deposits, Mars from SHARAD data
NASA Astrophysics Data System (ADS)
Whitten, J. L.; Campbell, B. A.
2017-12-01
The South Polar Layered Deposits (SPLD) are one of the largest deposits of water ice on Mars, composed of alternating layers of ice and dust. The accumulation of the layers is driven by orbital forcings (e.g., obliquity) and both the cadence and structure of these layers preserve a record of the past martian climate. Image of very limited exposed layering suggest several distinct sequences, demarcated by erosional hiatuses, with a gently domical shape. Here we use the Shallow Radar (SHARAD) sounder dataset to investigate the internal stratigraphy of the SPLD in order to further constrain the south polar climate record. We identify four distinct units based in part on their degree of vertical sharpness (focus) in the SHARAD data: (1) upper focused layer packets, (2) focused layer packets, (3) blurred layer packets, and (4) reflection free zones (RFZs). A diffuse echo pattern related to uncertain aspects of composition or layer roughness is termed fog. The upper focused layer packets are concentrated in the area between 270° to 90°E, close to the residual polar cap. The focused and blurred layer packets cover a large portion of the SPLD and are subdivided into two different units, those with an average reflecting-interface brightness and those with substantially brighter reflectors. The brighter radar reflectors have a coherent spatial distribution and only comprise a small portion of the entire unit. The diffuse echoes are separated into a fog that is present throughout the entire vertical column of the SPLD and a fog that begins at the surface and traverses only the uppermost layers. Depending on the geometry of individual SHARAD tracks, reflectors can be traced for hundreds of kilometers, but the fog obscures much of the internal layering, and is related to the focusing distortion that prevents individual reflectors from being traced across the entire SPLD. We identify a major deviation from a gently domical SPLD shape in a 200 km dome. Its presence suggests that the depositional history of the SPLD was more complicated than previously proposed. Differences in the distribution of the identified units further supports the dynamic and changing nature of the south polar climate. We also explore the distribution and radar characteristics of other ice-rich deposits in the south polar region of Mars.
NASA Astrophysics Data System (ADS)
O'Driscoll, B.; Hepworth, L. N.; Daly, J. S.; Gertisser, R.; Emeleus, C. H.
2017-12-01
The cumulate stratigraphy of layered intrusions offers a means of interrogating the replenishment and solidification histories of mafic magma chambers. Cumulates comprise cumulus minerals, which accumulate to form a silicate framework, and intercumulus minerals, which represent melt crystallised within the crystal mush. This fundamental textural distinction lies at the heart of cumulus theory and underpins some of the classic models of crystal-liquid differentiation that are based on layered intrusions. In order to shed further light on the importance of postcumulus processes in layered intrusions, and to demonstrate that crystal mushes may behave as open-systems during the crystallisation of cumulates, we investigated mineral-scale textural and geochemical heterogeneity in Unit 10 of the 60 Ma Rum layered intrusion. Numerous ( 1 mm thick) Cr-spinel seams occur throughout the 65 m Unit 10 peridotite stratigraphy. Unusually, intercumulus plagioclase and clinopyroxene crystals in the peridotite several centimetres above and below these seams exhibit complex optical and major element zoning. Sampling of individual intra-crystal zones in these phases was carried out using a New Wave Micromill, for analysis of their 87Sr/86Sr compositions to be measured on unspiked samples by TIMS. Both minerals reveal intra-crystalline isotopic heterogeneity. The maximum range (with 2σ uncertainties) of 87Sr/86Sr in the Unit 10 plagioclase is 0.704026±17-0.704591±8 and in clinopyroxene is 0.703533±23-0.704517±17. Within a single, oscillatory-zoned plagioclase, three discrete zones yield 87Sr/86Sr values of 0.704337±20, 0.704095±20 and 0.704052±11. A complex patchily-zoned clinopyroxene yields a 87Sr/86Sr range of 0.703533±23-0.703894±23. The new data demonstrate that multiple generations of isotopically distinct melts percolated through the Unit 10 crystal mush, suggesting solidification from cumulates that underwent repeated cycles of resorption and recrystallisation at the postcumulus stage. The cumulate products of layered intrusions may therefore form from magma addition within the crystal mush, and such a process might be especially relevant for precious metal enrichment, given the association between isotopic disequilibrium and the locations of Cr-spinel seams observed here.
Brennecka, Gregory A.; Borg, Lars E.; Wadhwa, Meenakshi
2013-01-01
The isotopic composition of our Solar System reflects the blending of materials derived from numerous past nucleosynthetic events, each characterized by a distinct isotopic signature. We show that the isotopic compositions of elements spanning a large mass range in the earliest formed solids in our Solar System, calcium–aluminum-rich inclusions (CAIs), are uniform, and yet distinct from the average Solar System composition. Relative to younger objects in the Solar System, CAIs contain positive r-process anomalies in isotopes A < 140 and negative r-process anomalies in isotopes A > 140. This fundamental difference in the isotopic character of CAIs around mass 140 necessitates (i) the existence of multiple sources for r-process nucleosynthesis and (ii) the injection of supernova material into a reservoir untapped by CAIs. A scenario of late supernova injection into the protoplanetary disk is consistent with formation of our Solar System in an active star-forming region of the galaxy. PMID:24101483
NASA Technical Reports Server (NTRS)
Frank, D.; Zolensky, Michael E.; Brearley, A.; Le, L.
2011-01-01
The CO 3.0 chondrite ALHA77307 is thought to be the least metamorphosed of all the CO chondrites [1]. As such, the fine-grained (<30 m) olivine found in its matrix is a valuable resource for investigating the CO formation environment since its compositions should be primary. In the CO matrix, we indeed find a wide range of major element compositions (Fa(0.5-71)). However, more importantly, we find that the olivines make up two compositionally distinct populations (Fa(0.5-5) and Fa(21-71)). Grains from both populations are found within an extremely close proximity and we see no obvious evidence of two distinct lithologies within our samples. Therefore, we conclude that the olivine grains found in the ALHA77307 matrix must have crystallized within two unique formation conditions and were later mixed at a very fine scale during the accretion epoch. Here, we propose a possible explanation based on Cr and Mn concentrations in the olivine.
Brennecka, Gregory A; Borg, Lars E; Wadhwa, Meenakshi
2013-10-22
The isotopic composition of our Solar System reflects the blending of materials derived from numerous past nucleosynthetic events, each characterized by a distinct isotopic signature. We show that the isotopic compositions of elements spanning a large mass range in the earliest formed solids in our Solar System, calcium-aluminum-rich inclusions (CAIs), are uniform, and yet distinct from the average Solar System composition. Relative to younger objects in the Solar System, CAIs contain positive r-process anomalies in isotopes A < 140 and negative r-process anomalies in isotopes A > 140. This fundamental difference in the isotopic character of CAIs around mass 140 necessitates (i) the existence of multiple sources for r-process nucleosynthesis and (ii) the injection of supernova material into a reservoir untapped by CAIs. A scenario of late supernova injection into the protoplanetary disk is consistent with formation of our Solar System in an active star-forming region of the galaxy.
Vogt, Carmen; Pernemalm, Maria; Kohonen, Pekka; Laurent, Sophie; Hultenby, Kjell; Vahter, Marie; Lehtiö, Janne; Toprak, Muhammet S.; Fadeel, Bengt
2015-01-01
Superparamagnetic iron oxide nanoparticles (SPIONs) have emerged as promising contrast agents for magnetic resonance imaging. The influence of different surface coatings on the biocompatibility of SPIONs has been addressed, but the potential impact of the so-called corona of adsorbed proteins on the surface of SPIONs on their biological behavior is less well studied. Here, we determined the composition of the plasma protein corona on silica-coated versus dextran-coated SPIONs using mass spectrometry-based proteomics approaches. Notably, gene ontology (GO) enrichment analysis and Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway analysis revealed distinct protein corona compositions for the two different SPIONs. Relaxivity of silica-coated SPIONs was modulated by the presence of a protein corona. Moreover, the viability of primary human monocyte-derived macrophages was influenced by the protein corona on silica-coated, but not dextran-coated SPIONs, and the protein corona promoted cellular uptake of silica-coated SPIONs, but did not affect internalization of dextran-coated SPIONs. PMID:26444829
Vogt, Carmen; Pernemalm, Maria; Kohonen, Pekka; Laurent, Sophie; Hultenby, Kjell; Vahter, Marie; Lehtiö, Janne; Toprak, Muhammet S; Fadeel, Bengt
2015-01-01
Superparamagnetic iron oxide nanoparticles (SPIONs) have emerged as promising contrast agents for magnetic resonance imaging. The influence of different surface coatings on the biocompatibility of SPIONs has been addressed, but the potential impact of the so-called corona of adsorbed proteins on the surface of SPIONs on their biological behavior is less well studied. Here, we determined the composition of the plasma protein corona on silica-coated versus dextran-coated SPIONs using mass spectrometry-based proteomics approaches. Notably, gene ontology (GO) enrichment analysis and Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway analysis revealed distinct protein corona compositions for the two different SPIONs. Relaxivity of silica-coated SPIONs was modulated by the presence of a protein corona. Moreover, the viability of primary human monocyte-derived macrophages was influenced by the protein corona on silica-coated, but not dextran-coated SPIONs, and the protein corona promoted cellular uptake of silica-coated SPIONs, but did not affect internalization of dextran-coated SPIONs.
Low, I A; Liu, R H; Legendre, M G; Piotrowski, E G; Furner, R L
1986-10-01
A gas chromatograph/quadrupole mass spectrometer system, operated in electron impact/selected ion monitoring mode, is used to determine the intensity ratio of the m/z 59 and the m/z 58 ions of the [C3H8N]+ fragment derived from methamphetamine samples synthesized with varying amounts of 13C-labeled methylamine. Crude products are introduced into the gas chromatograph without prior cleanup. The ratios measured were in excellent agreement with those calculated. A change in 0.25% use of 13C-methylamine is sufficient for product differentiation. The feasibility of using isotope labeling and subsequent mass spectrometric isotope ratio measurement as the basis of a compound tracing mechanism is discussed. Specifically, if methamphetamine samples manufactured from legal sources are asked to incorporate distinct 13C compositions, their sources can be traced when samples are diverted into illegal channels. Samples derived from illicit preparations can also be traced if the manufacturers of a precursor (methylamine in this case) incorporate distinct 13C compositions in their products.
Rickettsia parkeri rickettsiosis and its clinical distinction from Rocky Mountain spotted fever.
Paddock, Christopher D; Finley, Richard W; Wright, Cynthia S; Robinson, Howard N; Schrodt, Barbara J; Lane, Carole C; Ekenna, Okechukwu; Blass, Mitchell A; Tamminga, Cynthia L; Ohl, Christopher A; McLellan, Susan L F; Goddard, Jerome; Holman, Robert C; Openshaw, John J; Sumner, John W; Zaki, Sherif R; Eremeeva, Marina E
2008-11-01
Rickettsia parkeri rickettsiosis, a recently identified spotted fever transmitted by the Gulf Coast tick (Amblyomma maculatum), was first described in 2004. We summarize the clinical and epidemiological features of 12 patients in the United States with confirmed or probable disease attributable to R. parkeri and comment on distinctions between R. parkeri rickettsiosis and other United States rickettsioses. Clinical specimens from patients in the United States who reside within the range of A. maculatum for whom an eschar or vesicular rash was described were evaluated by > or =1 laboratory assays at the Centers for Disease Control and Prevention (Atlanta, GA) to identify probable or confirmed infection with R. parkeri. During 1998-2007, clinical samples from 12 patients with illnesses epidemiologically and clinically compatible with R. parkeri rickettsiosis were submitted for diagnostic evaluation. Using indirect immunofluorescence antibody assays, immunohistochemistry, polymerase chain reaction assays, and cell culture isolation, we identified 6 confirmed and 6 probable cases of infection with R. parkeri. The aggregate clinical characteristics of these patients revealed a disease similar to but less severe than classically described Rocky Mountain spotted fever. Closer attention to the distinct clinical features of the various spotted fever syndromes that exist in the United States and other countries of the Western hemisphere, coupled with more frequent use of specific confirmatory assays, may unveil several unique diseases that have been identified collectively as Rocky Mountain spotted fever during the past century. Accurate assessments of these distinct infections will ultimately provide a more valid description of the currently recognized distribution, incidence, and case-fatality rate of Rocky Mountain spotted fever.
Prediction of composites behavior undergoing an ATP process through data-mining
NASA Astrophysics Data System (ADS)
Martin, Clara Argerich; Collado, Angel Leon; Pinillo, Rubén Ibañez; Barasinski, Anaïs; Abisset-Chavanne, Emmanuelle; Chinesta, Francisco
2018-05-01
The need to characterize composite surfaces for distinct mechanical or physical processes leads to different manners of evaluate the state of the surface. During many manufacturing processes deformation occurs, thus hindering composite classification for fabrication processes. In this work we focus on the challenge of a priori identifying the surfaces' behavior in order to optimize manufacturing. We will propose and validate the curvature of the surface as a reliable parameter and we will develop a tool that allows the prediction of the surface behavior.
NASA Technical Reports Server (NTRS)
Manuel, O. K.; Srinivasan, B.; Hennecke, E. W.; Sinclair, D. E.
1972-01-01
The abundance and isotopic composition of helium, neon, argon, krypton, and xenon which were released by stepwise heating of lunar fines (15601.64) and (15271.65) were measured spectrometrically. The results of a composition of noble gases released from the lunar fines with noble gases in meteorites and in the earth are presented along with the isotopic composition of noble gases in lunar fines, in meteorites, and in the atmosphere. A study of two isotopically distinct components of trapped xenon in carbonaceous chondrites is also included.
Crystal-Chemical Analysis Martian Minerals in Gale Crater
NASA Technical Reports Server (NTRS)
Morrison, S. M.; Downs, R. T.; Blake, D. F.; Bish, D. L.; Ming, D. W.; Morris, R. V.; Yen, A. S.; Chipera, S. J.; Treiman, A. H.; Vaniman, D. T.;
2015-01-01
The CheMin instrument on the Mars Science Laboratory rover Curiosity performed X-ray diffraction analyses on scooped soil at Rocknest and on drilled rock fines at Yellowknife Bay (John Klein and Cumberland samples), The Kimberley (Windjana sample), and Pahrump (Confidence Hills sample) in Gale crater, Mars. Samples were analyzed with the Rietveld method to determine the unit-cell parameters and abundance of each observed crystalline phase. Unit-cell parameters were used to estimate compositions of the major crystalline phases using crystal-chemical techniques. These phases include olivine, plagioclase and clinopyroxene minerals. Comparison of the CheMin sample unit-cell parameters with those in the literature provides an estimate of the chemical compositions of the major crystalline phases. Preliminary unit-cell parameters, abundances and compositions of crystalline phases found in Rocknest and Yellowknife Bay samples were reported in. Further instrument calibration, development of 2D-to- 1D pattern conversion corrections, and refinement of corrected data allows presentation of improved compositions for the above samples.
Japan's electronic packaging technologies
NASA Technical Reports Server (NTRS)
Tummala, Rao R.; Pecht, Michael
1995-01-01
The JTEC panel found Japan to have significant leadership over the United States in the strategic area of electronic packaging. Many technologies and products once considered the 'heart and soul' of U.S. industry have been lost over the past decades to Japan and other Asian countries. The loss of consumer electronics technologies and products is the most notable of these losses, because electronics is the United States' largest employment sector and is critical for growth businesses in consumer products, computers, automobiles, aerospace, and telecommunications. In the past there was a distinction between consumer and industrial product technologies. While Japan concentrated on the consumer market, the United States dominated the industrial sector. No such distinction is anticipated in the future; the consumer-oriented technologies Japan has dominated are expected to characterize both domains. The future of U.S. competitiveness will, therefore, depend on the ability of the United States to rebuild its technological capabilities in the area of portable electronic packaging.
Damping behavior of nano-fibrous composites with viscous interface in anti-plane shear
NASA Astrophysics Data System (ADS)
Wang, Xu
2017-06-01
By using the composite cylinder assemblage model, we derive an explicit expression of the specific damping capacity of nano-fibrous composite with viscous interface when subjected to time-harmonic anti-plane shear loads. The fiber and the matrix are first endowed with separate and distinct Gurtin-Murdoch surface elasticities, and rate-dependent sliding occurs on the fiber-matrix interface. Our analysis indicates that the effective damping of the composite depends on five dimensionless parameters: the fiber volume fraction, the stiffness ratio, two parameters arising from surface elasticity and one parameter due to interface sliding.
The Cuban-American Counterpoint: Black Cubans in the United States.
ERIC Educational Resources Information Center
Dixon, Heriberto
The term "Hispanics" as currently used in the United States is a gross oversimplification of the reality of a highly heterogeneous people. Among the many important variables that divide and subdivide the Hispanic population into distinctive and significant subpopulations are race, language, time of arrival in the United States, national origin,…
Santos, Rubens M; Oliveira-Filho, Ary T; Eisenlohr, Pedro V; Queiroz, Luciano P; Cardoso, Domingos B O S; Rodal, Maria J N
2012-02-01
The tree species composition of seasonally dry tropical forests (SDTF) in north-eastern and central Brazil is analyzed to address the following hypotheses: (1) variations in species composition are related to both environment (climate and substrate) and spatial proximity; (2) SDTF floristic units may be recognized based on peculiar composition and environment; and (3) the Arboreal Caatinga, a deciduous forest occurring along the hinterland borders of the Caatinga Domain, is one of these units and its flora is more strongly related to the caatinga vegetation than to outlying forests. The study region is framed by the Brazilian coastline, 50th meridian west and 21st parallel south, including the Caatinga Domain and extensions into the Atlantic Forest and Cerrado Domains. Multivariate and geostatistic analyses were performed on a database containing 16,226 occurrence records of 1332 tree species in 187 georeferenced SDTF areas and respective environmental variables. Tree species composition varied significantly with both environmental variables and spatial proximity. Eight SDTF floristic units were recognized in the region, including the Arboreal Caatinga. In terms of species composition, its tree flora showed a stronger link with that of the Cerrado Dry Forest Enclaves. On the other hand, in terms of species frequency across sample areas, the links were stronger with two other units: Rock Outcrops Caatinga and Agreste and Brejo Dry Forests. There is a role for niche-based control of tree species composition across the SDTFs of the region determined primarily by the availability of ground water across time and secondarily by the amount of soil mineral nutrients. Spatial proximity also contributes significantly to the floristic cohesion of SDTF units suggesting a highly dispersal-limited tree flora. These units should be given the status of eco-regions to help driving the conservation policy regarding the protection of their biodiversity.
Santos, Rubens M; Oliveira-Filho, Ary T; Eisenlohr, Pedro V; Queiroz, Luciano P; Cardoso, Domingos B O S; Rodal, Maria J N
2012-01-01
The tree species composition of seasonally dry tropical forests (SDTF) in north-eastern and central Brazil is analyzed to address the following hypotheses: (1) variations in species composition are related to both environment (climate and substrate) and spatial proximity; (2) SDTF floristic units may be recognized based on peculiar composition and environment; and (3) the Arboreal Caatinga, a deciduous forest occurring along the hinterland borders of the Caatinga Domain, is one of these units and its flora is more strongly related to the caatinga vegetation than to outlying forests. The study region is framed by the Brazilian coastline, 50th meridian west and 21st parallel south, including the Caatinga Domain and extensions into the Atlantic Forest and Cerrado Domains. Multivariate and geostatistic analyses were performed on a database containing 16,226 occurrence records of 1332 tree species in 187 georeferenced SDTF areas and respective environmental variables. Tree species composition varied significantly with both environmental variables and spatial proximity. Eight SDTF floristic units were recognized in the region, including the Arboreal Caatinga. In terms of species composition, its tree flora showed a stronger link with that of the Cerrado Dry Forest Enclaves. On the other hand, in terms of species frequency across sample areas, the links were stronger with two other units: Rock Outcrops Caatinga and Agreste and Brejo Dry Forests. There is a role for niche-based control of tree species composition across the SDTFs of the region determined primarily by the availability of ground water across time and secondarily by the amount of soil mineral nutrients. Spatial proximity also contributes significantly to the floristic cohesion of SDTF units suggesting a highly dispersal-limited tree flora. These units should be given the status of eco-regions to help driving the conservation policy regarding the protection of their biodiversity. PMID:22423333
Micromechanical models for textile structural composites
NASA Technical Reports Server (NTRS)
Marrey, Ramesh V.; Sankar, Bhavani V.
1995-01-01
The objective is to develop micromechanical models for predicting the stiffness and strength properties of textile composite materials. Two models are presented to predict the homogeneous elastic constants and coefficients of thermal expansion of a textile composite. The first model is based on rigorous finite element analysis of the textile composite unit-cell. Periodic boundary conditions are enforced between opposite faces of the unit-cell to simulate deformations accurately. The second model implements the selective averaging method (SAM), which is based on a judicious combination of stiffness and compliance averaging. For thin textile composites, both models can predict the plate stiffness coefficients and plate thermal coefficients. The finite element procedure is extended to compute the thermal residual microstresses, and to estimate the initial failure envelope for textile composites.
Effects of model layer simplification using composite hydraulic properties
Sepúlveda, Nicasio; Kuniansky, Eve L.
2010-01-01
The effects of simplifying hydraulic property layering within an unconfined aquifer and the underlying confining unit were assessed. The hydraulic properties of lithologic units within the unconfined aquifer and confining unit were computed by analyzing the aquifer-test data using radial, axisymmetric two-dimensional (2D) flow. Time-varying recharge to the unconfined aquifer and pumping from the confined Upper Floridan aquifer (USA) were simulated using 3D flow. Conceptual flow models were developed by gradually reducing the number of lithologic units in the unconfined aquifer and confining unit by calculating composite hydraulic properties for the simplified lithologic units. Composite hydraulic properties were calculated using either thickness-weighted averages or inverse modeling using regression-based parameter estimation. No significant residuals were simulated when all lithologic units comprising the unconfined aquifer were simulated as one layer. The largest residuals occurred when the unconfined aquifer and confining unit were aggregated into a single layer (quasi-3D), with residuals over 100% for the leakage rates to the confined aquifer and the heads in the confining unit. Residuals increased with contrasts in vertical hydraulic conductivity between the unconfined aquifer and confining unit. Residuals increased when the constant-head boundary at the bottom of the Upper Floridan aquifer was replaced with a no-flow boundary.
Grundel, R.; Jean, R.P.; Frohnapple, K.J.; Glowacki, G.A.; Scott, P.E.; Pavlovic, N.B.
2010-01-01
Given bees' central effect on vegetation communities, it is important to understand how and why bee distributions vary across ecological gradients. We examined how plant community composition, plant diversity, nesting suitability, canopy cover, land use, and fire history affected bee distribution across an open-forest gradient in northwest Indiana, USA, a gradient similar to the historic Midwest United States landscape mosaic. When considered with the other predictors, plant community composition was not a significant predictor of bee community composition. Bee abundance was negatively related to canopy cover and positively to recent fire frequency, bee richness was positively related to plant richness and abundance of potential nesting resources, and bee community composition was significantly related to plant richness, soil characteristics potentially related to nesting suitability, and canopy cover. Thus, bee abundance was predicted by a different set of environmental characteristics than was bee species richness, and bee community composition was predicted, in large part, by a combination of the significant predictors of bee abundance and richness. Differences in bee community composition along the woody vegetation gradient were correlated with relative abundance of oligolectic, or diet specialist, bees. Because oligoleges were rarer than diet generalists and were associated with open habitats, their populations may be especially affected by degradation of open habitats. More habitat-specialist bees were documented for open and forest/scrub habitats than for savanna/woodland habitats, consistent with bees responding to habitats of intermediate woody vegetation density, such as savannas, as ecotones rather than as distinct habitat types. Similarity of bee community composition, similarity of bee abundance, and similarity of bee richness between sites were not significantly related to proximity of sites to each other. Nestedness analysis indicated that species composition in species-poor sites was not merely a subset of species composition at richer sites. The lack of significant proximity or nestedness effects suggests that factors at a small spatial scale strongly influence bees' use of sites. The findings indicate that patterns of plant diversity, nesting resource availability, recent fire, and habitat shading, present at the scale of a few hundred meters, are key determinants of bee community patterns in the mosaic open-savanna-forest landscape. ?? 2010 by the Ecological Society of America.
2013-01-01
Background Wheat and rice are important food crops with enormous biomass residues for biofuels. However, lignocellulosic recalcitrance becomes a crucial factor on biomass process. Plant cell walls greatly determine biomass recalcitrance, thus it is essential to identify their key factors on lignocellulose saccharification. Despite it has been reported about cell wall factors on biomass digestions, little is known in wheat and rice. In this study, we analyzed nine typical pairs of wheat and rice samples that exhibited distinct cell wall compositions, and identified three major factors of wall polymer features that affected biomass digestibility. Results Based on cell wall compositions, ten wheat accessions and three rice mutants were classified into three distinct groups each with three typical pairs. In terms of group I that displayed single wall polymer alternations in wheat, we found that three wall polymer levels (cellulose, hemicelluloses and lignin) each had a negative effect on biomass digestibility at similar rates under pretreatments of NaOH and H2SO4 with three concentrations. However, analysis of six pairs of wheat and rice samples in groups II and III that each exhibited a similar cell wall composition, indicated that three wall polymer levels were not the major factors on biomass saccharification. Furthermore, in-depth detection of the wall polymer features distinctive in rice mutants, demonstrated that biomass digestibility was remarkably affected either negatively by cellulose crystallinity (CrI) of raw biomass materials, or positively by both Ara substitution degree of non-KOH-extractable hemicelluloses (reverse Xyl/Ara) and p-coumaryl alcohol relative proportion of KOH-extractable lignin (H/G). Correlation analysis indicated that Ara substitution degree and H/G ratio negatively affected cellulose crystallinity for high biomass enzymatic digestion. It was also suggested to determine whether Ara and H monomer have an interlinking with cellulose chains in the future. Conclusions Using nine typical pairs of wheat and rice samples having distinct cell wall compositions and wide biomass saccharification, Ara substitution degree and monolignin H proportion have been revealed to be the dominant factors positively determining biomass digestibility upon various chemical pretreatments. The results demonstrated the potential of genetic modification of plant cell walls for high biomass saccharification in bioenergy crops. PMID:24341349
NASA Technical Reports Server (NTRS)
Boyce, Joseph (Technical Monitor); Mustard, John
2004-01-01
Reflectance spectroscopy has demonstrated that high albedo surfaces on Mars contain heavily altered materials with some component of hematite, poorly crystalline ferric oxides, and an undefined silicate matrix. The spectral properties of many low albedo regions indicate crystalline basalts containing both low and high calcium pyroxene, a mineralogy consistent with the basaltic SNC meteorites. The Thermal Emission Spectrometer (TES) experiment on the Mars Geochemical Surveyor has acquired critical new data relevant to surface composition and mineralogy, but in a wavelength region that is complementary to reflectance spectroscopy. The essence of the completed research was to analyze TES data in the context of reflectance data obtained by the French ISM imaging spectrometer experiment in 1989. This approach increased our understanding of the complementary nature of these wavelength regions for mineralogic determinations using actual observations of the martian surface. The research effort focused on three regions of scientific importance: Syrtis Major-Isidis Basin, Oxia Palus-Arabia, and Valles Marineris. In each region distinct spatial variations related to reflectance, and in derived mineralogic information and interpreted compositional units were analyzed. In addition, specific science questions related to the composition of volcanics and crustal evolution, soil compositions and pedogenic processes, and the relationship between pristine lithologies and weathering provided an overall science-driven framework for the work. The detailed work plan involved colocation of TES and ISM data, extraction of reflectance and emissivity spectra from areas of known reflectance variability, and quantitative analysis using factor analysis and statistical techniques to determine the degree of correspondence between these different wavelength regions. Identified coherent variations in TES spectroscopy were assessed against known atmospheric effects to validate that the variations are due to surface properties. With this new understanding of reflectance and emission spectroscopy, mineralogic interpretations were derived and applied to the science objectives of the three regions.
Stable isotope composition of waters in the Great Basin, United States 1. Air-mass trajectories
Friedman, I.; Harris, J.M.; Smith, G.I.; Johnson, C.A.
2002-01-01
Isentropic trajectories, calculated using the NOAA/Climate Monitoring and Diagnostics Laboratory's isentropic transport model, were used to determine air-parcel origins and the influence of air mass trajectories on the isotopic composition of precipitation events that occurred between October 1991 and September 1993 at Cedar City, Utah, and Winnemucca, Nevada. Examination of trajectories that trace the position of air parcels backward in time for 10 days indicated five distinct regions of water vapor origin: (1) Gulf of Alaska and North Pacific, (2) central Pacific, (3) tropical Pacific, (4) Gulf of Mexico, and (5) continental land mass. Deuterium (??D) and oxygen-18 (??18O) analyses were made of precipitation representing 99% of all Cedar City events. Similar analyses were made on precipitation representing 66% of the precipitation falling at Winnemucca during the same period. The average isotopic composition of precipitation derived from each water vapor source was determined. More than half of the precipitation that fell at both sites during the study period originated in the tropical Pacific and traveled northeast to the Great Basin; only a small proportion traversed the Sierra Nevada. The isotopic composition of precipitation is determined by air-mass origin and its track to the collection station, mechanism of droplet formation, reequilibration within clouds, and evaporation during its passage from cloud to ground. The Rayleigh distillation model can explain the changes in isotopic composition of precipitation as an air mass is cooled pseudo-adiabatically during uplift. However, the complicated processes that take place in the rapidly convecting environment of cumulonimbus and other clouds that are common in the Great Basin, especially in summer, require modification of this model because raindrops that form in the lower portion of those clouds undergo isotopic change as they are elevated to upper levels of the clouds from where they eventually drop to the ground.
Crystallisation sequence and magma evolution of the De Beers dyke (Kimberley, South Africa)
NASA Astrophysics Data System (ADS)
Soltys, Ashton; Giuliani, Andrea; Phillips, David
2018-06-01
We present petrographic and mineral chemical data for a suite of samples derived from the De Beers dyke, a contemporaneous, composite intrusion bordering the De Beers pipe (Kimberley, South Africa). Petrographic features and mineral compositions indicate the following stages in the evolution of this dyke: (1) production of antecrystic material by kimberlite-related metasomatism in the mantle (i.e., high Cr-Ti phlogopite); (2) entrainment of wall-rock material during ascent through the lithospheric mantle, including antecrysts; (3) early magmatic crystallisation of olivine (internal zones and subsequently rims), Cr-rich spinel, rutile, and magnesian ilmenite, probably on ascent to the surface; and (4) crystallisation of groundmass phases (i.e., olivine rinds, Fe-Ti-rich spinels, perovskite, apatite, monticellite, calcite micro-phenocrysts, kinoshitalite-phlogopite, barite, and baddeleyite) and the mesostasis (calcite, dolomite, and serpentine) on emplacement in the upper crust. Groundmass and mesostasis crystallisation likely forms a continuous sequence with deuteric/hydrothermal modification. The petrographic features, mineralogy, and mineral compositions of different units within the De Beers dyke are indistinguishable from one another, indicating a common petrogenesis. The compositions of antecrysts (i.e., high Cr-Ti phlogopite) and magmatic phases (e.g., olivine rims, magnesian ilmenite, and spinel) overlap those from the root zone intrusions of the main Kimberley pipes (i.e., Wesselton, De Beers, Bultfontein). However, the composition of these magmatic phases is distinct from those in `evolved' intrusions of the Kimberley cluster (e.g., Benfontein, Wesselton water tunnel sills). Although the effects of syn-emplacement flow processes are evident (e.g., alignment of phases parallel to contacts), there is no evidence that the De Beers dyke has undergone significant pre-emplacement crystal fractionation (e.g., olivine, spinel, ilmenite). This study demonstrates the requirement for detailed petrographic and mineral chemical studies to assess whether individual intrusions are in fact `evolved'; and that dykes are not necessarily produced by differentiated magmas.
NASA Astrophysics Data System (ADS)
Landwehr, J. M.; Coplen, T. B.; Qi, H.
2009-04-01
The composition of stable isotopes of hydrogen (^2H) and oxygen (^18O) in animal tissues, such as hair, nail, teeth and bone, has been used to trace migrations and geographic origin of individuals. Variations of these isotopic ratios in tissue are known to show significant correlations with the isotopic composition of ingested water, as well as with diet and other oxygen sources. Drinking water in natural ecosystems is defined by what is locally available for animal consumption, primarily surface waters such as streams, ponds, lakes, seeps, springs, etc. Tap water provides the drinking water in many human ecosystems. It may derive from local sources but can also draw on more diverse sources, such as large rivers with watersheds larger than those of local creeks, deep ground waters or even imported supplies, which may be isotopically distinct from local ecosystem supplies. Because of the potentially complex hydrologic pathways of water sources available in either animal or human ecosystems, the stable isotopic composition of these supplies may differ significantly from that of the (weighted average) local precipitation which is sometimes used to represent local water supplies. For example, water samples taken from three different taps in Washington, D.C., USA, on August 15, 2007, had measured ^2H and ^18O values of -41.7 per mill and -6.13 per mill, -41.7 per mill and -6.06 per mill, and -42.2 per mill and -6.22 per mill, respectively. A water sample taken on the same day from the Potomac River, which is the source of the D.C. water supply, had ^2H and ^18O values of -41.7 per mill and -6.06 per mill, respectively, consistent with that of the urban tap water. However, precipitation samples collected locally in Reston, Virginia, USA, had ^2H and ^18O values of -16.1 per mill and -3.13 per mill, respectively, for the week ending on August 15, 2007; -17.5 per mill and -3.40 per mill, respectively, for the month preceding August 15, 2007; and -13.6 per mill and -3.39 per mill, respectively, for the average values for the month of August over three years. The isotopic composition of local precipitation was significantly more positive than that for the concurrently available tap water and the river water from which it was drawn. Thus, in order to allow valid geographic inferences for forensic purposes, it is necessary to have available the measured isotopic composition of drinking waters or of their appropriate sources. We have now collected tap water samples concurrently at 345 sites throughout the United States and measured ^2H and ^18O during both summer (2007) and winter (2008) seasons. Since large rivers are frequently the source of urban water supplies, we compare this information with data published for rivers and streams throughout the United States (Coplen and Kendall, 2000). These data and analyses should inform the use of stable isotopes of water for forensic determinations.
History of the magmatic feeding system of the Campi Flegrei caldera (Italy)
NASA Astrophysics Data System (ADS)
Civetta, L.; Arienzo, I.; D'Antonio, M.; di Renzo, V.; di Vito, M. A.; Orsi, G.
2007-05-01
The definition of the magmatic feeding system of active volcanoes in terms of architecture, composition, crystallization time-scale, relationships between composition of the erupted magmas and structural position of the vents, and magma processes, is of paramount importance for volcanic hazards evaluation. Investigations aimed at defining the Campi Flegeri magmatic system, include detailed mineralogical, geochemical and isotopic analyses (Sr, Nd, Pb, Th,U). The magmatic feeding system of the Campi Flegrei caldera is characterized by deep and shallow magma reservoirs. In the deep reservoirs (20-10 km depth) mantle- derived magmas differentiated and were contaminated by continental crust. In the shallow reservoirs isotopically distinct magmas, further differentiated, contaminated, and mixed and mingled before eruptions. These processes generated isotopically distinct components, variably interacting with the different structural elements of the Campi Flegrei caldera through time. The relationships between the structural position of the eruption vents, during the last 15 ka of activity, and the isotopic composition of the magmas erupted at the Campi Flegrei caldera allow us to reconstruct the architecture of the magmatic feeding system and to infer the chemical and isotopic composition of the magma feeding a future eruption, according to vent position.
History of the Magmatic Feeding System of the Campi Flegrei Caldera
NASA Astrophysics Data System (ADS)
Orsi, G.; Civetta, L.; Arienzo, I.; D'Antonio, M.; di Renzo, V.; di Vito, M. A.
2007-12-01
The definition of the magmatic feeding system of active volcanoes, in terms of composition, time-scale of crystallization, relation between composition of the erupted magma and structural position of vents, magma chamber processes and architecture, is of extreme importance for the hazard evaluation. The studies that are carried out for the definition of the magmatic systems include detailed mineralogical, geochemical and isotopic analyses (Sr, Nd, Pb). The Campi Flegrei caldera magmatic structure is characterized by deep and shallow magma chambers. In the deep reservoir (20-10 km depth) mantle derived magmas differentiate and are contaminated with continental crust. In the shallow reservoirs isotopically distinct magmas further differentiate, mix and mingle before the eruptions. These processes generated isotopically distinct components that were variably involved along different structures of the Campi Flegrei caldera during time. At Campi Flegrei caldera the relation between the structural position of the eruptive vent, for the last 14 ka of activity, and the isotopic composition of the emitted magma allow us to reconstruct the architecture of the magmatic feeding system and to infer the chemical and isotopic composition, and the magma chamber location and processes, of the future eruption, according to the position of the vent
Fabrication and microstructures of functional gradient SiBCN–Nb composite by hot pressing
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sun, Min, E-mail: lcxsunmin@163.com; Fu, Ruoyu; Chen, Jun
2016-04-15
A functional gradient material with five layers composed of SiBCN ceramic and niobium (Nb) was prepared successfully by hot pressing. The phase composition, morphology features and microstructures were investigated in each layer of the gradient material. The Nb-containing compounds involving NbC, Nb{sub 6}C{sub 5}, Nb{sub 4}C{sub 3}, Nb{sub 5}Si{sub 3} and NbN increase with the volume fraction of Nb increasing in the sub-layer. They are randomly scattered (≤ 25 vol.% Nb), then strip-like, and finally distribute continuously (≥ 75 vol.% Nb). The size of BN(C) and SiC grains in Nb-containing layers is larger than in 100% SiBCN layer due tomore » the loss of the capsule-like structures. No distinct interfaces form in the transition regions indicating the gradual changes in phase composition and microstructures. - Highlights: • A functional gradient SiBCN–Nb material was prepared successfully by hot pressing. • Phase composition, morphology features and microstructures were investigated. • Thermodynamic calculation was used to aid in the phase analysis. • No distinct interfaces form typical of the functional gradient material.« less
NASA Astrophysics Data System (ADS)
Shearer, C. K.; Floss, C.
Ion microprobe trace-element studies of lunar cumulates [ferroan anorthosites (FAN), highlands Mg suite (HMS), and highlands alkali suite (HAS)] and volcanic glasses have provided an additional perspective in reconstructing lunar magmatism and early differentiation. Calculated melt compositions for the FANs indicate that a simple lunar magma ocean (LMO) model does not account for differences between FANs with highly magnesian mafic minerals and “typical” ferroan anorthosites. The HMS and HAS appear to have crystallized from magmas that had incompatible trace-element concentrations equal to or greater than KREEP. Partial melting of distinct, hybridized sources is consistent with these calculated melt compositions. However, the high-Mg silicates with relatively low Ni content that are observed in the HMS are suggestive of other possible processes (reduction, metal removal). The compositions of the picritic glasses indicate that they were produced by melting of hybrid cumulate sources produced by mixing of early and late LMO cumulates. The wide compositional range of near-primitive mare basalts indicates small degrees of localized melting preserved the signature of distinct mantle reservoirs. The relationship between ilmenite anomalies and 182W in the mare basalts suggests that the LMO crystallized over a short period of time.
The evolution of compositionally and functionally distinct actin filaments.
Gunning, Peter W; Ghoshdastider, Umesh; Whitaker, Shane; Popp, David; Robinson, Robert C
2015-06-01
The actin filament is astonishingly well conserved across a diverse set of eukaryotic species. It has essentially remained unchanged in the billion years that separate yeast, Arabidopsis and man. In contrast, bacterial actin-like proteins have diverged to the extreme, and many of them are not readily identified from sequence-based homology searches. Here, we present phylogenetic analyses that point to an evolutionary drive to diversify actin filament composition across kingdoms. Bacteria use a one-filament-one-function system to create distinct filament systems within a single cell. In contrast, eukaryotic actin is a universal force provider in a wide range of processes. In plants, there has been an expansion of the number of closely related actin genes, whereas in fungi and metazoa diversification in tropomyosins has increased the compositional variety in actin filament systems. Both mechanisms dictate the subset of actin-binding proteins that interact with each filament type, leading to specialization in function. In this Hypothesis, we thus propose that different mechanisms were selected in bacteria, plants and metazoa, which achieved actin filament compositional variation leading to the expansion of their functional diversity. © 2015. Published by The Company of Biologists Ltd.
Phylogeography and genetic ancestry of tigers (Panthera tigris).
Luo, Shu-Jin; Kim, Jae-Heup; Johnson, Warren E; van der Walt, Joelle; Martenson, Janice; Yuhki, Naoya; Miquelle, Dale G; Uphyrkina, Olga; Goodrich, John M; Quigley, Howard B; Tilson, Ronald; Brady, Gerald; Martelli, Paolo; Subramaniam, Vellayan; McDougal, Charles; Hean, Sun; Huang, Shi-Qiang; Pan, Wenshi; Karanth, Ullas K; Sunquist, Melvin; Smith, James L D; O'Brien, Stephen J
2004-12-01
Eight traditional subspecies of tiger (Panthera tigris),of which three recently became extinct, are commonly recognized on the basis of geographic isolation and morphological characteristics. To investigate the species' evolutionary history and to establish objective methods for subspecies recognition, voucher specimens of blood, skin, hair, and/or skin biopsies from 134 tigers with verified geographic origins or heritage across the whole distribution range were examined for three molecular markers: (1) 4.0 kb of mitochondrial DNA (mtDNA) sequence; (2) allele variation in the nuclear major histocompatibility complex class II DRB gene; and (3) composite nuclear microsatellite genotypes based on 30 loci. Relatively low genetic variation with mtDNA,DRB,and microsatellite loci was found, but significant population subdivision was nonetheless apparent among five living subspecies. In addition, a distinct partition of the Indochinese subspecies P. t. corbetti in to northern Indochinese and Malayan Peninsula populations was discovered. Population genetic structure would suggest recognition of six taxonomic units or subspecies: (1) Amur tiger P. t. altaica; (2) northern Indochinese tiger P. t. corbetti; (3) South China tiger P. t. amoyensis; (4) Malayan tiger P. t. jacksoni, named for the tiger conservationist Peter Jackson; (5) Sumatran tiger P. t. sumatrae; and (6) Bengal tiger P. t. tigris. The proposed South China tiger lineage is tentative due to limited sampling. The age of the most recent common ancestor for tiger mtDNA was estimated to be 72,000-108,000 y, relatively younger than some other Panthera species. A combination of population expansions, reduced gene flow, and genetic drift following the last genetic diminution, and the recent anthropogenic range contraction, have led to the distinct genetic partitions. These results provide an explicit basis for subspecies recognition and will lead to the improved management and conservation of these recently isolated but distinct geographic populations of tigers.
Feng, Lidan; Watanabe, Takumi; Wang, Yi; Kichise, Tomoyasu; Fukuchi, Takeshi; Chen, Guo-Qiang; Doi, Yoshiharu; Inoue, Yoshio
2002-01-01
The comonomer-unit compositional distributions have been investigated for bacterial poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) [P(3HB-co-3HH)] samples with 3HH unit content of 13.8, 18.0, 22.0, and 54.0 mol %. They were comonomer compositionally fractionated using chloroform/n-heptane mixed solvent at ambient temperature. The fractionation of P(3HB-co-18.0 mol %3HH) and P(3HB-co-22.0 mol % 3HH), which could not be carried out effectively at room temperature, were refractionated at 70 degrees C in the mixed solvent. Fractions with different 3HH unit content in a wide range (from 4.4 to 80.7 mol %) were obtained. By use of these fractions with narrow compositional distribution, the comonomer composition dependence of thermal properties was investigated by differential scanning calorimetry. The melting point (T(m)) and heat of fusion (DeltaH) decreased as the 3HH unit content increased in the range of low 3HH content (<40 mol %), while they increased as the 3HH unit content increased in the high 3HH content range (>70 mol %). The minimum T(m) and DeltaH values were found to exist at 3HH unit content of about 60 mol %. The glass transition temperature (T(g)) decreased linearly with the increase of 3HH unit content. The values of T(m), DeltaH, and T(g) of P(3HB-co-3HH)s were compared with those of poly(3-hydroxybutyrate-co-3-hydroxyvalerate), poly(3-hydroxybutyrate-co-3-hydroxypropionate), and poly(3-hydroxybutyrate-co-4-hydroxybutyrate), and the effects of comonomer types on the thermal properties were revealed.
The geological history of Northeast Syrtis Major, Mars
NASA Astrophysics Data System (ADS)
Bramble, Michael S.; Mustard, John F.; Salvatore, Mark R.
2017-09-01
As inferred from orbital spectroscopic data, Northeast Syrtis Major bears considerable mineral diversity that spans the Noachian-Hesperian boundary despite its small geographic area. In this study we use observations from the High Resolution Imaging Science Experiment, supplemented with Context Camera imagery, to characterize and map the lateral extent of geomorphic units in Northeast Syrtis Major, and constrain the geomorphic context of the orbital-identified mineral signatures. Using recent observations, we confirm previous mineralogy identified with the Compact Reconnaissance Imaging Spectrometer for Mars, and greatly extend the lateral extent of visible to near-infrared investigation utilizing the greater coverage. Analysis of Thermal Emission Imaging System observations reveals further physical properties and distribution of the geomorphic units. The stratigraphy, which spans the Noachian-Hesperian boundary, displays significant morphological heterogeneity at the decameter scale, but it is unifiable under five distinct geomorphic units. Our paired morphological and mineralogical analysis allows us to construct a detailed geological history of Northeast Syrtis Major. Several geological events that occurred in Northeast Syrtis Major-including the formation of the post-Isidis crust, the emplacement of an olivine-rich unit, the formation of sulfate minerals, and the emplacement of the Syrtis Major Volcanics-can be related to regional and global processes constraining the local chronology. Other mineralogical indicators, particularly the formation of Al-phyllosilicates, are difficult to place in the temporal sequence. They are observed in isolated patches on the post-Isidis crust, not as a distinct stratigraphic unit as observed elsewhere in Nili Fossae, suggesting their formation via isolated leaching or through alteration of initial compositional heterogeneities within the crust. Exposures of an olivine-rich unit are intermittently observed to form quasi-circular landforms, suggestive of emplacement in circular depressions, which may indicate a period of cratering between the formation of the Isidis basin and the deposition of the olivine-rich unit. We identify and discuss intriguing large linear features of the olivine-rich unit, reminiscent of dyke-fed volcanism, that have raised bounding ridges suggestive of contact metamorphism with the crust. We compile, review, and discuss many of the outstanding questions and running hypotheses relevant to our mapping area. A synthesis of our geomorphic mapping with recent literature reveals a well-defined geological history with extensive aqueous activity at Northeast Syrtis Major that is amassed in a stratigraphic sequence spanning a time likely greater than 250 million years of geological history. Our geomorphic and spectral analyses confirm that Northeast Syrtis Major exhibits considerable geomorphic and mineralogic diversity within a relatively small geographic area that is representative of the geologic processes occurring throughout the broader Nili Fossae region during the Noachian and Hesperian. Northeast Syrtis Major adds to this sequence by exposing the diverse environmental history of this region as observed through the presence of alteration minerals not present in this fidelity or proximity elsewhere in Nili Fossae.
Phan, Thai T.; Capo, Rosemary C; Stewart, Brian W.; Macpherson, Gwen; Rowan, Elisabeth L.; Hammack, Richard W.
2015-01-01
In Greene Co., southwest Pennsylvania, the Upper Devonian sandstone formation waters have δ7Li values of + 14.6 ± 1.2 (2SD, n = 25), and are distinct from Marcellus Shale formation waters which have δ7Li of + 10.0 ± 0.8 (2SD, n = 12). These two formation waters also maintain distinctive 87Sr/86Sr ratios suggesting hydrologic separation between these units. Applying temperature-dependent illitilization model to Marcellus Shale, we found that Li concentration in clay minerals increased with Li concentration in pore fluid during diagenetic illite-smectite transition. Samples from north central PA show a much smaller range in both δ7Li and 87Sr/86Sr than in southwest Pennsylvania. Spatial variations in Li and δ7Li values show that Marcellus formation waters are not homogeneous across the Appalachian Basin. Marcellus formation waters in the northeastern Pennsylvania portion of the basin show a much smaller range in both δ7Li and 87Sr/86Sr, suggesting long term, cross-formational fluid migration in this region. Assessing the impact of potential mixing of fresh water with deep formation water requires establishment of a geochemical and isotopic baseline in the shallow, fresh water aquifers, and site specific characterization of formation water, followed by long-term monitoring, particularly in regions of future shale gas development.
Meisel, Matthew K; Clifton, Allan D; MacKillop, James; Goodie, Adam S
2015-12-01
The current study applied egocentric social network analysis (SNA) to investigate the prevalence of addictive behavior and co-occurring substance use in college students' networks. Specifically, we examined individuals' perceptions of the frequency of network members' co-occurring addictive behavior and investigated whether co-occurring addictive behavior is spread evenly throughout networks or is more localized in clusters. We also examined differences in network composition between individuals with varying levels of alcohol use. The study utilized an egocentric SNA approach in which respondents ("egos") enumerated 30 of their closest friends, family members, co-workers, and significant others ("alters") and the relations among alters listed. Participants were 281 undergraduates at a large university in the Southeastern United States. Robust associations were observed among the frequencies of gambling, smoking, drinking, and using marijuana by network members. We also found that alters tended to cluster together into two distinct groups: one cluster moderate-to-high on co-occurring addictive behavior and the other low on co-occurring addictive behavior. Lastly, significant differences were present when examining egos' perceptions of alters' substance use between the networks of at-risk, light, and nondrinkers. These findings provide empirical evidence of distinct clustering of addictive behavior among young adults and suggest the promise of social network-based interventions for this cohort. Copyright © 2015. Published by Elsevier Ltd.
Geologic framework of the regional ground-water flow system in the Upper Deschutes Basin, Oregon
Lite, Kenneth E.; Gannett, Marshall W.
2002-12-10
Geologic units in the Deschutes Basin were divided into several distinct hydrogeologic units. In some instances the units correspond to existing stratigraphic divisions. In other instances, hydrogeologic units correspond to different facies within a single stratigraphic unit or formation. The hydrogeologic units include Quaternary sediment, deposits of the Cascade Range and Newberry Volcano, four zones within the Deschutes Formation and age-equivalent rocks that roughly correspond with depositional environments, and pre-Deschutes-age strata.
Bacterial Composition and Survival on Sahara Dust Particles Transported to the European Alps
Meola, Marco; Lazzaro, Anna; Zeyer, Josef
2015-01-01
Deposition of Sahara dust (SD) particles is a frequent phenomenon in Europe, but little is known about the viability and composition of the bacterial community transported with SD. The goal of this study was to characterize SD-associated bacteria transported to the European Alps, deposited and entrapped in snow. During two distinct events in February and May 2014, SD particles were deposited and promptly covered by falling snow, thus preserving them in distinct ochre layers within the snowpack. In June 2014, we collected samples at different depths from a snow profile at the Jungfraujoch (Swiss Alps; 3621 m a.s.l.). After filtration, we performed various microbiological and physicochemical analyses of the snow and dust particles therein that originated in Algeria. Our results show that bacteria survive and are metabolically active after the transport to the European Alps. Using high throughput sequencing, we observed distinct differences in bacterial community composition and structure in SD-layers as compared to clean snow layers. Sporulating bacteria were not enriched in the SD-layers; however, phyla with low abundance such as Gemmatimonadetes and Deinococcus-Thermus appeared to be specific bio-indicators for SD. Since many members of these phyla are known to be adapted to arid oligotrophic environments and UV radiation, they are well suited to survive the harsh conditions of long-range airborne transport. PMID:26733988
Continental-scale distributions of dust-associated bacteria and fungi
Barberán, Albert; Ladau, Joshua; Pollard, Katherine S.; Menninger, Holly L.; Dunn, Robert R.; Fierer, Noah
2015-01-01
It has been known for centuries that microorganisms are ubiquitous in the atmosphere, where they are capable of long-distance dispersal. Likewise, it is well-established that these airborne bacteria and fungi can have myriad effects on human health, as well as the health of plants and livestock. However, we have a limited understanding of how these airborne communities vary across different geographic regions or the factors that structure the geographic patterns of near-surface microbes across large spatial scales. We collected dust samples from the external surfaces of ∼1,200 households located across the United States to understand the continental-scale distributions of bacteria and fungi in the near-surface atmosphere. The microbial communities were highly variable in composition across the United States, but the geographic patterns could be explained by climatic and soil variables, with coastal regions of the United States sharing similar airborne microbial communities. Although people living in more urbanized areas were not found to be exposed to distinct outdoor air microbial communities compared with those living in more rural areas, our results do suggest that urbanization leads to homogenization of the airborne microbiota, with more urban communities exhibiting less continental-scale geographic variability than more rural areas. These results provide our first insight into the continental-scale distributions of airborne microbes, which is information that could be used to identify likely associations between microbial exposures in outdoor air and incidences of disease in crops, livestock, and humans. PMID:25902536
Dusel-Bacon, Cynthia; Aleinikoff, John N.; Premo, Wayne R.; Paradis, Suzanne; Lohr-Schmidt, Ilana; Gough, Larry P.; Day, Warren C.
2007-01-01
This paper summarizes the results of field and laboratory investigations, including whole-rock geochemistry and radiogenic isotopes, of outcrop and drill core samples from volcanogenic massive sulfide (VMS) deposits and associated metaigneous rocks in the Wood River area of the Bonnifield mining district, northern Alaska Range (see fig. 1 of Editors’ Preface and Overview). U-Pb zircon igneous crystallization ages from felsic rocks indicate a prolonged period of Late Devonian to Early Mississippian (373±3 to 357±4 million years before present, or Ma) magmatism. This magmatism occurred in a basinal setting along the ancient Pacific margin of North America. The siliceous and carbonaceous compositions of metasedimentary rocks, Precambrian model ages based on U-Pb dating of zircon and neodymium ages, and for some units, radiogenic neodymium isotopic compositions and whole-rock trace-element ratios similar to those of continental crust are evidence for this setting. Red Mountain (also known as Dry Creek) and WTF, two of the largest VMS deposits, are hosted in peralkaline metarhyolite of the Mystic Creek Member of the Totatlanika Schist. The Mystic Creek Member is distinctive in having high concentrations of high-field-strength elements (HFSE) and rare-earth elements (REE), indicative of formation in a within-plate (extensional) setting. Mystic Creek metarhyolite is associated with alkalic, within-plate basalt of the Chute Creek Member; neodymium isotopic data indicate an enriched mantle component for both members of this bimodal (rhyolite-basalt) suite. Anderson Mountain, the other significant VMS deposit, is hosted by the Wood River assemblage. Metaigneous rocks in the Wood River assemblage span a wide compositional range, including andesitic rocks, which are characteristic of arc volcanism. Our data suggest that the Mystic Creek Member likely formed in an extensional, back-arc basin that was associated with an outboard continental-margin volcanic arc that included rocks of the Wood River assemblage. We suggest that elevated HFSE and REE trace-element contents of metavolcanic rocks, whose major-element composition may have been altered, are an important prospecting tool for rocks of VMS deposit potential in east-central Alaska.
Xu, Zhenqiang; Yao, Maosheng
2013-05-01
Increasing evidences show that inhalation of indoor bioaerosols has caused numerous adverse health effects and diseases. However, the bioaerosol size distribution, composition, and concentration level, representing different inhalation risks, could vary with different living environments. The six-stage Andersen sampler is designed to simulate the sampling of different human lung regions. Here, the sampler was used in investigating the bioaerosol exposure in six different environments (student dorm, hospital, laboratory, hotel room, dining hall, and outdoor environment) in Beijing. During the sampling, the Andersen sampler was operated for 30 min for each sample, and three independent experiments were performed for each of the environments. The air samples collected onto each of the six stages of the sampler were incubated on agar plates directly at 26 °C, and the colony forming units (CFU) were manually counted and statistically corrected. In addition, the developed CFUs were washed off the agar plates and subjected to polymerase chain reaction (PCR)-denaturing gradient gel electrophoresis (DGGE) for diversity analysis. Results revealed that for most environments investigated, the culturable bacterial aerosol concentrations were higher than those of culturable fungal aerosols. The culturable bacterial and fungal aerosol fractions, concentration, size distribution, and diversity were shown to vary significantly with the sampling environments. PCR-DGGE analysis indicated that different environments had different culturable bacterial aerosol compositions as revealed by distinct gel band patterns. For most environments tested, larger (>3 μm) culturable bacterial aerosols with a skewed size distribution were shown to prevail, accounting for more than 60 %, while for culturable fungal aerosols with a normal size distribution, those 2.1-4.7 μm dominated, accounting for 20-40 %. Alternaria, Cladosporium, Chaetomium, and Aspergillus were found abundant in most environments studied here. Viable microbial load per unit of particulate matter was also shown to vary significantly with the sampling environments. The results from this study suggested that different environments even with similar levels of total microbial culturable aerosol concentrations could present different inhalation risks due to different bioaerosol particle size distribution and composition. This work fills literature gaps regarding bioaerosol size and composition-based exposure risks in different human dwellings in contrast to a vast body of total bioaerosol levels.
NASA Technical Reports Server (NTRS)
Walker, Kevin P.; Freed, Alan D.; Jordan, Eric H.
1993-01-01
Local stress and strain fields in the unit cell of an infinite, two-dimensional, periodic fibrous lattice have been determined by an integral equation approach. The effect of the fibres is assimilated to an infinite two-dimensional array of fictitious body forces in the matrix constituent phase of the unit cell. By subtracting a volume averaged strain polarization term from the integral equation we effectively embed a finite number of unit cells in a homogenized medium in which the overall stress and strain correspond to the volume averaged stress and strain of the constrained unit cell. This paper demonstrates that the zeroth term in the governing integral equation expansion, which embeds one unit cell in the homogenized medium, corresponds to the generalized self-consistent approximation. By comparing the zeroth term approximation with higher order approximations to the integral equation summation, both the accuracy of the generalized self-consistent composite model and the rate of convergence of the integral summation can be assessed. Two example composites are studied. For a tungsten/copper elastic fibrous composite the generalized self-consistent model is shown to provide accurate, effective, elastic moduli and local field representations. The local elastic transverse stress field within the representative volume element of the generalized self-consistent method is shown to be in error by much larger amounts for a composite with periodically distributed voids, but homogenization leads to a cancelling of errors, and the effective transverse Young's modulus of the voided composite is shown to be in error by only 23% at a void volume fraction of 75%.
Vital effects in coral skeletal composition display strict three-dimensional control
Meibom, A.; Yurimoto, H.; Cuif, J.-P.; Domart-Coulon, I.; Houlbreque, F.; Constantz, B.; Dauphin, Y.; Tambutte, E.; Tambutte, S.; Allemand, D.; Wooden, J.; Dunbar, R.
2006-01-01
Biological control over coral skeletal composition is poorly understood but critically important to paleoenvironmental reconstructions. We present microanalytical measurements of trace-element abundances as well as oxygen and carbon isotopic compositions of individual skeletal components in the zooxanthellate coral Colpophyllia sp. Our data show that centers of calcification (COC) have higher trace element concentrations and distinctly lighter isotopic compositions than the fibrous components of the skeleton. These observations necessitate that COC and the fibrous skeleton are precipitated by different mechanisms, which are controlled by specialized domains of the calicoblastic cell-layer. Biological processes control the composition of the skeleton even at the ultra-structure level. Copyright 2006 by the American Geophysical Union.
Forest composition change in the eastern United States
Songlin Fei; Peilin. Yang
2011-01-01
Forest ecosystems in the eastern United States are believed to be experiencing a species composition change, but most evidence is anecdotal or localized. We used U.S. Forest Service Forest Inventory and Analysis data to quantify the annual changes of three common genera: Acer (maple), carya (hickory), and Quercus...
Writing for the Whole Person: A Transpersonal Approach to Freshman Composition.
ERIC Educational Resources Information Center
Pellettiri, Leonard
This text, written for students and teachers of English Composition, incorporates writing instruction with concepts of transpersonal psychology in a holistic and cosmic approach to writing. The text comprises nine units, which include teaching materials, group and individual exercises, and writing assignments. Unit I presents techniques of…
Numerical Study on the Tensile Behavior of 3D Four Directional Cylindrical Braided Composite Shafts
NASA Astrophysics Data System (ADS)
Zhao, Guoqi; Wang, Jiayi; Hao, Wenfeng; Liu, Yinghua; Luo, Ying
2017-10-01
The tensile behavior of 3D four directional cylindrical braided composite shafts was analyzed with the numerical method. The unit cell models for the 3D four directional cylindrical braided composite shafts with various braiding angles were constructed with ABAQUS. Hashin's failure criterion was used to analyze the tensile strength and the damage evolution of the unit cells. The influence of the braiding angle on the tensile behavior of the 3D four directional cylindrical braided composite shafts was analyzed. The numerical results showed that the tensile strength along the braiding direction increased as the braiding angle decreased. These results should play an integral role in the design of braiding composites shafts.
NASA Technical Reports Server (NTRS)
Murthy, P. L. N.; Chamis, C. C.
1992-01-01
A generic unit cell model which includes a unique fiber substructuring concept is proposed for the development of micromechanics equations for continuous fiber reinforcement ceramic composites. The unit cell consists of three constituents: fiber, matrix, and an interphase. In the present approach, the unit cell is further subdivided into several slices and the equations of micromechanics are derived for each slice. These are subsequently integrated to obtain ply level properties. A stand alone computer code containing the micromechanics model as a module is currently being developed specifically for the analysis of ceramic matrix composites. Towards this development, equivalent ply property results for a SiC/Ti-15-3 composite with 0.5 fiber volume ratio are presented and compared with those obtained from customary micromechanics models to illustrate the concept. Also, comparisons with limited experimental data for the ceramic matrix composite, SiC/RBSN (Reaction Bonded Silicon Nitride) with a 0.3 fiber volume ratio are given to validate the concepts.
Beever, Erik
2003-01-01
Compared to other ungulates of North America, free-roaming horses (Equus caballus) possess a unique evolutionary history that has given rise to a distinct suite of behavioral, morphological, and physiological traits. Because of their unique combination of cecal digestion, an elongate head with flexible lips, and non-uniform use of the landscape, horses represent a unique disturbance agent in semi-arid ecosystems of the western United States. Consequently, it is inappropriate to assume that influences of horses on the structure, composition, function, and pattern of arid and semi-arid ecosystems will mirror influences of cattle or other artiodactyls. Although management areas for free-roaming horses occupy 18.6 million ha of land across western North America, we know relatively little about how western ecosystems and their components have responded to this uniquely managed ungulate. I draw on my research of horse habitats in the western Great Basin (U.S.A.) to examine predictions of horses' unique influence, and advocate for continued research to refine our understanding of synecological relationships among horses and diverse ecosystem components in arid and semi-arid regions.
McNicol, L A; De, S P; Kaper, J B; West, P A; Colwell, R R
1983-01-01
A total of 165 strains of vibrios isolated from clinical and environmental sources in the United States, India, and Bangladesh, 11 reference cultures, and 4 duplicated cultures were compared in a numerical taxonomic study using 83 unit characters. Similarity between strains was computed by using the simple matching coefficient and the Jaccard coefficient. Strains were clustered by unweighted average linkage and single linkage algorithms. All methods gave similar cluster compositions. The estimated probability of error in the study was obtained from a comparison of the results of duplicated strains and was within acceptable limits. A total of 174 of the 180 organisms studied were divided into eight major clusters. Two clusters were identified as Vibrio cholerae, one as Vibrio mimicus, one as Vibrio parahaemolyticus, three as Vibrio species, and one as Aeromonas hydrophila. The V. mimicus cluster could be further divided into two subclusters, and the major V. cholerae group could be split into seven minor subclusters. Phenotypic traits routinely used to identify clinical isolates of V. cholerae can be used to identify environmental V. cholerae isolates. No distinction was found between strains of V. cholerae isolated from regions endemic for cholera and strains from nonendemic regions. PMID:6874901
Lunar highlands volcanism implications from Luna 20 and Apollo 16
Wilshire, H.G.; Wilhelms, D.E.; Howard, K.A.
1974-01-01
Highlands materials sampled at the Apollo 16 and Luna 20 sites represent units of distinctive morphology that are widespread on the lunar nearside. Samples from the Apollo 16 site represent hilly and furrowed materials of the Descartes highlands and Cayley Formation. Materials were collected by Luna 20 from terrain resembling the Descartes terrain. Most photogeologic interpretations of these units favored volcanic origins, but the samples fail to support this interpretation. Luna 20 soil fragments are mainly glassy microbreccia with lithic inclusions of fine-grained hornfels; less than 3 percent of the fragments have textures of volcanic rocks, and most of these are likely crystalline products of impact melting. Apollo 16 soils formed on ejecta derived from a plutonic anorthosite-norite-troctolite suite. The similarity of Luna 20 soils indicates that these too formed as regolith on ejecta of anorthosite-norite-troctolitc composition. Interpretation of the samples from the two locations now suggests that hilly and furrowed terrains, previously thought to be of volcanic origin, are impact ejecta; in view of the plutonic nature of the source rocks and their extensive fusion and metamorphism, it is likely that the ejecta were derived from multiring basins. At one point, the Apollo 16 site, the Cayley Formation is composed of basin ejecta.
Ash-flow tuffs of the Galiuro Volcanics in the northern Galiuro Mountains, Pinal County, Arizona
Krieger, Medora Louise Hooper
1979-01-01
The upper Oligocene and lower Miocene Galiuro Volcanics in the northern part of the Galiuro Mountains contains two distinctive major ash-flow tuff sheets, the Holy Joe and Aravaipa Members. These major ash-flows illustrate many features of ash-flow geology not generally exposed so completely. The Holy Joe Member, composed of a series of densely welded flows of quartz latite composition that make up a simple cooling unit. is a rare example of a cooling unit that has a vitrophyre at the top as well as at the base. The upper vitrophyre does not represent a cooling break. The Aravaipa Member. a rhyolite, is completely exposed in Aravaipa and other canyons and on Table Mountain. Remarkable exposures along Whitewash Canyon exhibit the complete change from a typical stacked-up interior zonation of an ash flow to a non welded distal margin. Vertical and horizontal changes in welding, crystallization, specific gravity, and lithology are exposed. The ash flow can be divided into six lithologic zones. The Holy Joe and Aravaipa Members of the Galiuro Volcanics are so well exposed and so clearly show characteristic features of ash-flow tuffs that they could be a valuable teaching aid and a source of theses for geology students.
Blasi, Monica F.; Boitani, Luigi
2014-01-01
We investigated social structure and association patterns for a small population of Mediterranean bottlenose dolphins, Tursiops truncatus, inhabiting the Aeolian Archipelago (southern Italy). Specifically we evaluate the role of sex and age composition, residency patterns and interaction with trammel nets on this social organization. Association data for 23 regularly sighted individuals were obtained from summer photoidentification surveys collected from 2005–2012. Using a combined cluster and social network analysis approach, we found associations between dolphins were hierarchically structured, where two mixed-sex social units were subdivided into smaller temporarily dynamic groups. We found non-random and long-term preferred associations in the population; however, the degree of social cohesion, residence pattern and interaction with trammel nets differed considerably between the two social units. Six of eight females occurred in the more resident social unit-1; in addition, social unit-1 individuals had significantly stronger associations, higher preferred associates, lived in larger groups and occurred less frequently with trammel nets. Nine of eleven males were clustered in social unit-2 and five of these males, interacting with trammel nets, formed small groups and preferred associations. We propose that female and male groups associate in the study area during the breeding season and that some males choose to interact with reproductive females forming a distinct but interrelated social unit. Other males may be associating in a larger fission-fusion network, which consists of dolphins that appear to temporarily join the network from the coastal population. We cannot exclude that some males specialized in trammel net foraging, suggesting that this foraging technique may favor a solitary lifestyle. Large group sizes and high degree of social cohesion for females could be an indication of greater protection and more efficiency in detecting, deterring or repelling anthropogenic pressures. Most likely dolphins' social organization depends on a combination of socio-ecological, demographic and anthropogenic factors. PMID:25494331
Speaking from Otherness: A New Perspective on U.S. Diversity and Suggestions to Educational Equality
ERIC Educational Resources Information Center
Li, Nan
2005-01-01
For a Chinese educator residing in the United States, one distinctive characteristic of American culture is diversity. The United States is a nation comprised of diversity in race, ethnicity, religion, socioeconomic (SES) status, exceptionality, gender, age, and language. Diversity, on one hand, distinguishes the United States and contributes to…
No Ivies, Oxbridge, or Grandes Écoles: Constructing Distinctions in University Choice
ERIC Educational Resources Information Center
Baker, Jayne
2014-01-01
Although we know a great deal about college choice in nations such as the United States, we know considerably less about how college choice operates in settings lacking well-defined hierarchies between higher education institutions. In the United States, the United Kingdom, and France, students from high socio-economic status backgrounds are…
Federal Register 2010, 2011, 2012, 2013, 2014
2010-04-01
... unit is a block cluster, which consists of one or more geographically contiguous census blocks. As in... a number of distinct processes, ranging from forming block clusters, selecting the block clusters... sample of block clusters, while the E Sample is the census of housing units and enumerations in the same...
NASA Astrophysics Data System (ADS)
Kinsman-Costello, L. E.; Dick, G.; Sheik, C.; Burton, G. A.; Sheldon, N. D.
2015-12-01
Submerged groundwater seeps in Lake Huron establish ecosystems with distinctive geochemical conditions. In the Middle Island Sinkhole (MIS), a 23-m deep seep, groundwater seepage establishes low O2 (< 4 mg L-1), high sulfate (6 mM) conditions, in which a purple cyanobacteria-dominated mat thrives. The mat is capable of anoxygenic photosynthesis, oxygenic photosynthesis, and chemosynthesis. Within the top 3 cm of the mat-water interface, hydrogen sulfide concentrations increase to 1-7 mM. Little is known about the structure and function of microbes within organic-rich, high-sulfide sediments beneath the mat. Using pore water and sediment geochemical characterization along with microbial community analysis, we elucidated relationships between microbial community structure and ecosystem function along vertical gradients. In sediment pore waters, biologically reactive solutes (SO42-, NH4+, PO43-, and CH4) displayed steep vertical gradients, reflecting biological and geochemical functioning. In contrast, more conservative ions (Ca+2, Mg+2, Na+, and Cl-), did not change significantly with depth in MIS sediments, indicating groundwater influence in the sediment profile. MIS sediments contained more organic matter than typical Lake Huron sediments, and were generally higher in nutrients, metals, and sulfur (acid volatile sulfide). Using the Illumina MiSeq platform we detected 14,127 unique operational taxonomic units across sediment and surface mat samples. Microbial community composition in the MIS was distinctly different from non-groundwater affected areas at similar depth nearby in Lake Huron (ANOSIM, R= 0.74, p=0.002). MIS sediment communities were more diverse that MIS surface mat communities and changed with depth into sediments. MIS sediment community composition was related to several geochemical variables, including organic matter and multiple indicators of phosphorus availability. Elucidating the structure and function of microbial consortia in MIS, a highly unique and environmentally vulnerable ecosystem, provides a rare opportunity to understand relationships between microbial species and their environment and may provide insights into the evolution of life under ancient low-oxygen, high-sulfur conditions.
Menke, Sebastian; Wasimuddin; Meier, Matthias; Melzheimer, Jörg; Mfune, John K. E.; Heinrich, Sonja; Thalwitzer, Susanne; Wachter, Bettina; Sommer, Simone
2014-01-01
Recent gut microbiome studies in model organisms emphasize the effects of intrinsic and extrinsic factors on the variation of the bacterial composition and its impact on the overall health status of the host. Species occurring in the same habitat might share a similar microbiome, especially if they overlap in ecological and behavioral traits. So far, the natural variation in microbiomes of free-ranging wildlife species has not been thoroughly investigated. The few existing studies exploring microbiomes through 16S rRNA gene reads clustered sequencing reads into operational taxonomic units (OTUs) based on a similarity threshold (e.g., 97%). This approach, in combination with the low resolution of target databases, generally limits the level of taxonomic assignments to the genus level. However, distinguishing natural variation of microbiomes in healthy individuals from “abnormal” microbial compositions that affect host health requires knowledge of the “normal” microbial flora at a high taxonomic resolution. This gap can now be addressed using the recently published oligotyping approach, which can resolve closely related organisms into distinct oligotypes by utilizing subtle nucleotide variation. Here, we used Illumina MiSeq to sequence amplicons generated from the V4 region of the 16S rRNA gene to investigate the gut microbiome of two free-ranging sympatric Namibian carnivore species, the cheetah (Acinonyx jubatus) and the black-backed jackal (Canis mesomelas). Bacterial phyla with proportions >0.2% were identical for both species and included Firmicutes, Fusobacteria, Bacteroidetes, Proteobacteria and Actinobacteria. At a finer taxonomic resolution, black-backed jackals exhibited 69 bacterial taxa with proportions ≥0.1%, whereas cheetahs had only 42. Finally, oligotyping revealed that shared bacterial taxa consisted of distinct oligotype profiles. Thus, in contrast to 3% OTUs, oligotyping can detect fine-scale taxonomic differences between microbiomes. PMID:25352837
Brucite-driven CO2 uptake in serpentinized dunites (Ligurian Ophiolites, Montecastelli, Tuscany)
NASA Astrophysics Data System (ADS)
Boschi, Chiara; Dini, Andrea; Baneschi, Ilaria; Bedini, Federica; Perchiazzi, Natale; Cavallo, Andrea
2017-09-01
Understanding the mechanism of serpentinite weathering at low temperature - that involves carbonate formation - has become increasingly important because it represents an analog study for a cost-efficient carbon disposal strategy (i.e. carbon mineralization technology or mineral Carbon dioxide Capture and Storage, CCS). At Montecastelli (Tuscany, Italy), on-going spontaneous mineral CO2 sequestration is enhanced by brucite-rich serpentinized dunites. The dunites are embedded in brucite-free serpentinized harzburgites that belong to the ophiolitic Ligurian Units (Northern Apennine thrust-fold belt). Two main serpentinization events produced two distinct mineral assemblages in the reactive dunite bodies. The first assemblage consists of low-T pseudomorphic, mesh-textured serpentine, Fe-rich brucite (up to 20 mol.% Fe(OH)2) and minor magnetite. This was overprinted by a non-pseudomorphic, relatively high-T assemblage consisting of serpentine, Fe-poor brucite (ca. 4 mol% Fe(OH)2) and abundant magnetite. The harzburgite host rock developed a brucite-free paragenesis made of serpentine and magnetite. Present-day interaction of serpentinized dunites with slightly acidic and oxidizing meteoric water, enhances brucite dissolution and leads to precipitation of both Mg-Fe layered double hydroxides (coalingite-pyroaurite, LDHs) and hydrous Mg carbonates (hydromagnesite and nesquehonite). In contrast, the brucite-free serpentinized harzburgites are not affected by the carbonation process. In the serpentinized dunites, different carbonate minerals form depending on brucite composition (Fe-rich vs Fe-poor). Reactions in serpentinized dunites containing Fe-rich brucite produce a carbonate assemblage dominated by LDHs and minor amount of hydromagnesite. Serpentinites with a Fe-poor brucite assemblage contain large amounts of hydromagnesite and minor LDHs. Efficiency of CO2 mineral sequestration is different in the two cases owing to the distinct carbon content of LDHs (ca. 1.5 wt.%) and hydromagnesite (ca. 10 wt.%). Here, for the first time, we link the mineral composition of serpentinized ultramafic rocks to carbonate formation, concluding that Fe-poor brucite maximizes the mineral CCS efficiency.
Rheological characterization of composites using a vertical oscillation rheometer.
Lee, In Bog; Cho, Byeong Hoon; Son, Ho Hyun; Um, Chung Moon
2007-04-01
The purpose of this study was to investigate the viscoelastic properties related to the handling characteristics of composites. A custom-designed vertical oscillation rheometer (VOR) was used for the rheological measurements of composites. The VOR consists of three parts: (1) a measuring unit, (2) a deformation induction unit, and (3) a force-detecting unit. Two medium-viscous composites, Z100 and Z250, and two packable composites, P60 and SureFil, were tested. A dynamic oscillatory test was used to evaluate the storage modulus (E'), loss modulus (E''), and loss tangent (tan delta) of the composites as a function of frequency (omega) from 0.1 to 20Hz at 23 degrees C. The E' and E'' increased with increasing frequency and showed differences in magnitude among brands. The complex moduli E* of the composites at omega=2 Hz, normalized to that of Z100, were 2.16 (Z250), 4.80 (P60), and 25.21 (SureFil). The magnitudes and frequency characteristic of loss tangent differed significantly among brands. The relationship among the complex modulus E*, the phase angle delta, and the frequency omega was represented by the frequency domain phasor form E*(omega)e(idelta)=E*(omega) angledelta. The viscoelasticities of composites, which influence handling characteristics, are significantly different among brands. The VOR is a relatively simple device for the dynamic rheological measurement of dental composites. The loci of the frequency domain phasor plots in a complex plane are a valuable method of representing the viscoelastic properties of composites.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tivanski, A.V.; Hopkins, R.J.; Tyliszczak, T.
2007-06-21
Carbonaceous particles originating from biomass burning canaccount for a large fraction of organic aerosols in a local environment.Presently, their composition, physical and chemical properties, as wellas their environmental effects are largely unknown. Tar balls, a distincttype of highly spherical carbonaceous biomass burn particles, have beenobserved in a number of field campaigns. The Yosemite AerosolCharacterization Study that took place in summer 2002 occurred during anactive fire season in the western United States; tar balls collectedduring this field campaign are described in this article. Scanningtransmission X-ray microscopy and near-edge X-ray absorption finestructure spectroscopy are used to determine the shape, structure, andsize-dependent chemicalmore » composition of ~;150 individual sphericalparticles ranging in size from 0.15 to 1.2mu m.The elemental compositionof tar balls is ~;55 percent atomic carbon and ~;45 percent atomicoxygen. Oxygen is present primarily as carboxylic carbonyls andoxygen-substituted alkyl (O-alkyl-C) functional groups, followed bymoderate amounts of ketonic carbonyls. The observed chemical composition,density, and carbon functional groups are distinctly different from sootor black carbon and more closely resemble high molecular weight polymerichumic-like substances, which could account for their reported opticalproperties. A detailed examination of the carboxylic carbonyl andO-alkyl-C functional groups as a function of particle size reveals a thinoxygenated interface layer. The high oxygen content, as well as thepresence of water-soluble carboxylic carbonyl groups, could account forthe reported hygroscopic properties of tar balls. The presence of theoxygenated layer is attributed to atmospheric processing of biomass burnparticles.« less
Stratigraphy and Geochemistry of a Fond St. Jean Cinder Cone, Dominica
NASA Astrophysics Data System (ADS)
Isenburg, T.; Frey, H. M.; Waters, L. E.; Dunn, S.; Manon, M. R. F.
2017-12-01
Current geologic maps of Dominica generally classify the south-eastern portion of the island surrounding the Foundland stratovolcano as "mafic breccias and thin lava flows of Foundland center" (Smith et al. 2013). A detailed survey of the stratigraphy of a road cut at Fond St. Jean provides evidence for a mafic cinder cone on the flanks of Foundland. The 39 m thick stratigraphic sequence, dipping 60˚ north, includes a basal unit of scoria overlain by a meter of basaltic breccia and repeating layers of massive and rubbly flows, which range from 1 to 10 m in thickness. These flows transition into an additional, 2 m thick scoria deposit capped by a meter of massive basalt, which sits beneath another 3-4 m scoria deposit. Another layer of massive flow then transitions to three units of alternating air fall and ash lenses. Air fall units are 0.5 m in thickness but pinch and swell regularly, and ash lenses are roughly 10 cm thick. All units contain plagioclase + olivine + clinopyroxene + orthopyroxene + titanomagnetite. Though the phase assemblage is consistent between basaltic units, different crystal morphologies serve to define individual massive flows. Variations in the texture of materials deposited by the cinder cone provides evidence for cyclic explosive and effusive episodes. Massive samples at the bottom of the stratigraphic section contain abundant, large olivine and tabular, elongate plagioclase. Plagioclase compositions between individual stratigraphic units span a similar range in composition. Massive flows throughout the column contain similar, weakly zoned plagioclase cores (An84-94) with 10-30 µm sodic rims (An58-78; most rims are 68). Plagioclase microlites (long axes ≤100µm) span a wide range of compositions (An50-90). Three different air fall units contain plagioclase rims ranging in composition from An58-86 and cores ranging from An84-92, with the exception of a single core that has a composition of An61. Olivine in most units ranges in composition from Fo55-70. Spinels are ubiquitous throughout each of the units in the section and are consistently titanomagnetites. The potential genetic relationship between the cinder cone and Foundland is unclear, as the Foundland basalts are olivine-poor and contain amphibole, suggesting a wetter source magma for Foundland.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jaramillo, C.A.; Pardo-Trujillo, A.; Rueda, M.
A palynological study of the Cerrejon Formation was conducted in order to date the formation and understand the floristic composition and diversity of a Paleocene tropical site. The Cerrejon Formation outcrops in the Cerrejon Coal Mine, the largest open cast coal mine in the world. Two cores (725 m) were provided by Carbones del Cerrejon LLC for study. Two hundred samples were prepared for palynology, and at least 150 palynomorphs were counted per sample where possible. Several statistical techniques including rarefaction, species accumulation curves, detrended correspondence analysis, and Anosim were used to analyze the floristic composition and diversity of themore » palynofloras. Palynomorph assemblages indicate that the age of the Cerrejon Formation and the overlying Tabaco Formation is Middle to Late Paleocene (ca. 60-58 Ma). Major structural repetitions were not found in the Cerrejon Formation in the Cerrejon coal mine, and there is little floral variation throughout. The floral composition, diversity, and lithofacies do not change significantly. Lithofacies associations and floral composition indicate deposition fluctuating from an estuarine-influenced coastal plain at the base to a fluvial-influenced coastal plain at the top. There are, however, significant differences in the composition and diversity of coal and siliciclastic samples. Coal palynofloras have fewer morphospecies, and a distinct and more homogeneous floral assemblage compared to assemblages from the intervening sisliciclastic strata, suggesting that tropical swampy environments supported fewer plant species and had a distinct vegetation adapted to permanently wet environments.« less
Grosnaja ABCs: Magnesium isotope compositions
NASA Technical Reports Server (NTRS)
Goswami, J. N.; Srinivasan, G.; Ulyanov, A. A.
1993-01-01
Three CAI's from the Grosnaja CV3 chondrite were analyzed for their magnesium isotopic compositions by the ion microprobe. The selected CAI's represent three distinct types: GR4(compact Type A), GR7(Type B) and GR2(Type C). Petrographic studies indicate that all three Grosnaja inclusions were subjected to secondary alterations. The Type A CAI GR4 is primarily composed of melilite with spinel and pyroxene occurring as minor phases. The rim of the inclusion does not exhibit distinct layered structure and secondary alteration products (garnet, Fe-rich olivine and Na-rich plagioclase) are present in some localized areas near the rim region. The average major element compositions of different mineral phases in GR4 are given. Preliminary REE data suggest a depletion of HREE relative to LREE by about a factor of 3 without any clear indication of interelement fractionation. The CAI GR7 has textural and minerological characteristics similar to Type B inclusions. The REE data show a pattern that is similar to Group 6 with enrichment in Eu and Yb. In addition, a depletion of HREE compared to LREE is also evident in this object. Melilite composition shows a broad range of akermanite content (Ak(sub 15-55)). Detailed petrographic study is in progress. GR2 is a anorthite-rich Type C inclusion with large plagioclase laths intergrown with Ti-rich pyroxene. The average plagioclase composition is close to pure anorthite (An99).
NASA Astrophysics Data System (ADS)
Shaw, Cliff S. J.; Woodland, Alan B.
2012-03-01
The quaternary Rockeskyllerkopf Volcanic Complex (RVC) comprises three spatially and temporally distinct volcanic centers that can also be distinguished on the basis of their geochemical signatures. All the volcanic products in the complex are olivine basanites whose major and trace element compositions span almost the entire range defined for the West Eifel field as a whole. The RVC lavas have lower Al2O3, Na2O and Y contents and higher TiO2, CaO, K2O, Sc, V, Co, Rb, and Ba than the Tertiary lavas in nearby Hocheifel volcanic field. Within the complex, the oldest South East Lammersdorf Center (SEL) comprises primitive lavas with an average MgO content of ˜11 wt.% and LaN/YbN of 29 ± 2. The second center, Mäuseberg, has similar MgO to SEL but is distinct in its much higher LaN/YbN of 42 ± 2. The Rockeskyllerkopf Center, which was erupted after a break in activity, comprises lavas similar in composition to the SEL Center but with distinctly higher Al2O3 and lower MgO contents. Given the lack of evidence for significant fractionation or assimilation in the RVC lavas, we attribute the compositional variations within and between the centers of the RVC to be due to variations in the composition of the source region in combination with magma mixing. Our preferred model involves 1-5% partial melting of LREE-enriched mantle in the garnet stability field, likely within the thermal boundary layer at the base of the lithospheric mantle. These melts mixed to variable degrees with 2-4% partial melts of phlogopite-spinel peridotite formed at higher levels in the modally metasomatised lithospheric mantle.
Petrology of Anomalous Eucrites
NASA Technical Reports Server (NTRS)
Mittlefehldt, D. W.; Peng, Z. X.; Ross, D. K.
2015-01-01
Most mafic achondrites can be broadly categorized as being "eucritic", that is, they are composed of a ferroan low-Ca clinopyroxene, high-Ca plagioclase and a silica phase. They are petrologically distinct from angritic basalts, which are composed of high-Ca, Al-Ti-rich clinopyroxene, Carich olivine, nearly pure anorthite and kirschsteinite, or from what might be called brachinitic basalts, which are composed of ferroan orthopyroxene and high-Ca clinopyroxene, intermediate-Ca plagioclase and ferroan olivine. Because of their similar mineralogy and composition, eucrite-like mafic achondrites formed on compositionally similar asteroids under similar conditions of temperature, pressure and oxygen fugacity. Some of them have distinctive isotopic compositions and petrologic characteristics that demonstrate formation on asteroids different from the parent of the HED clan (e.g., Ibitira, Northwest Africa (NWA) 011). Others show smaller oxygen isotopic distinctions but are otherwise petrologically and compositionally indistinguishable from basaltic eucrites (e.g., Pasamonte, Pecora Escarpment (PCA) 91007). The degree of uniformity in delta O-17 of eucrites and diogenites is one piece of evidence considered to favor of a magma-ocean scenario for their petrogenesis. Given that the O isotopic differences separating Pasamonte and PCA 91007 from other eucrites are small, and that there is an absence of other distinguishing characteristics, a legitimate question is: Did the HED parent asteroid fail to homogenize via a magma-ocean stage, thus explaining outliers like Pasamonte? We are initiating a program of study of anomalous eucrite-like achondrites as one part of our effort to seek a resolution of this issue. Here we present preliminary petrologic information on Asuka (A-) 881394, Elephant Moraine (EET) 87520 and EET 87542. We will have studied several more by conference time.
Fleck, Robert J.; Greenwood, W.R.; Hadley, D.G.; Anderson, R.E.; Schmidt, D.L.
1980-01-01
Rubidium-strontium studies of Precambrian volcanic and plutonic rocks of the Arabian Shield document an early development of the Arabian craton between 900 and 680 m.y. (million years) ago. Geologic studies indicate an island-arc environment characterized by andesitic (dioritic) magmas, volcaniclastic sedimentation, rapid deposition, and contemporaneous deformation along north or northwest-trending axes. Magmatic trends show consistent variation in both composition and geographic location as a function of age. The oldest units belong to an assemblage of basaltic strata exposed in western Saudi Arabia that yield an age of 1165:!:110 m.y. The oldest andesitic strata studied yield an age of 912:!:76 m.y. The earliest plutonic units are diorite to trondhjemite batholiths that range from 800 to 9,00 m.y. in age and ,occur along the western and southern parts of Saudi Arabia. Younger plutonic units, 680 to 750 m.y. in age, range from quartz diorite to granodiodte and become more abundant in the central and northeastern parts of the Arabian Shield. Initial 'Sr/ 86 Sr ratios for both dioritic groups range from 0.7023 to 0.7030 and average 0.7027. The absence of sialic detritus in sedimentary units and the evidence for an island-arc environment suggest the early development of the Arabian craton at a convergent plate margin between plates of oceanic lithosphere. Active subduction apparently extended from at least 900 m.y. to about 680 m.y. Subsequent to this subduction-related magmatism and tectonism, called the Hijaz tectonic cycle, the Arabian craton was sutured to the late Precambrian African plate in a collisional event. This period of orogeny, represented in Arabia and eastern Africa by the Mozambiquian or Pan-African event, extended from some time before 650 m.y. to at least 540 m.y. and perhaps 520 m.y. B.P. Although the tectonic processes of subduction and continental collision during the 900+ to 500-m.y. period require similar directions of plate convergence, the differences in magmatic and tectonic. styles of Hijaz orogenesis from those of the Pan-African and the temporal break between them in much of the southern part of the Arabian Shield support division into at least two events. As defined by the ages of major plutonic units, the axis of magmatic and tectonic activity migrated eastward or northeastward during the Hijaz cycle, the predominantly dioritic plutonic rocks becoming younger and more siliceous to the east. Granodiorite to granite pl}.1tonism of the Pan-African event, however, shows no geographic bias, being distributed throughout the Arabian Shield. Although the Hijaz diorites and Pan-African granitic rocks exhibit strong contrasts in composition and age differences as great as 250 m.y. in the westernmost parts of the area, the two groups are less distinct compositionally and nearly the same age in the eastern part.
ARO - Terrestrial Research Program, Methodologies and Protocols for Characterization of Geomaterials
2015-05-14
of ice involves melting, digestion, and analysis using inductively coupled plasma – mass spectrometry (ICPMS). ICP-MS analysis established elemental...4] have distinct chemical compositions. Knowledge of the chemical composition of the mineral assemblage present in a rock is critical to...activation analysis (INAA), to inductively-coupled plasma analysis and mass spectrometry (ICP & ICP-MS), mass spectrometry (MS), and laser-ablation
Steinborn, A; Schmitt, E; Kisielewicz, A; Rechenberg, S; Seissler, N; Mahnke, K; Schaier, M; Zeier, M; Sohn, C
2012-01-01
Dysregulations concerning the composition and function of regulatory T cells (T(regs)) are assumed to be involved in the pathophysiology of complicated pregnancies. We used six-colour flow cytometric analysis to demonstrate that the total CD4(+) CD127(low+/-) CD25(+) forkhead box protein 3 (FoxP3)(+) T(reg) cell pool contains four distinct T(reg) subsets: DR(high+) CD45RA(-), DR(low+) CD45RA(-), DR(-) CD45RA(-) T(regs) and naive DR(-) CD45RA(+) T(regs). During the normal course of pregnancy, the most prominent changes in the composition of the total T(reg) cell pool were observed between the 10th and 20th weeks of gestation, with a clear decrease in the percentage of DR(high+) CD45RA(-) and DR(low+) CD45RA(-) T(regs) and a clear increase in the percentage of naive DR(-) CD45RA(+) T(regs). After that time, the composition of the total T(reg) cell pool did not change significantly. Its suppressive activity remained stable during normally progressing pregnancy, but decreased significantly at term. Compared to healthy pregnancies the composition of the total T(reg) cell pool changed in the way that its percentage of naive DR(-) CD45RA(+) T(regs) was reduced significantly in the presence of pre-eclampsia and in the presence of preterm labour necessitating preterm delivery (PL). Interestingly, its percentage of DR(high+) CD45RA(-) and DR(low+) CD45RA(-) T(regs) was increased significantly in pregnancies affected by pre-eclampsia, while PL was accompanied by a significantly increased percentage of DR(-) CD45RA(-) and DR(low+) CD45RA(-) T(regs). The suppressive activity of the total T(reg) cell pool was diminished in both patient collectives. Hence, our findings propose that pre-eclampsia and PL are characterized by homeostatic changes in the composition of the total T(reg) pool with distinct T(reg) subsets that were accompanied by a significant decrease of its suppressive activity. © 2011 The Authors. Clinical and Experimental Immunology © 2011 British Society for Immunology.
Dean, Walter E.; Arthur, Michael A.
2011-01-01
eg 1 of the 1988 R/V Knorr expeditions to the Black Sea recovered 90 gravity and box cores. The longest recovery by gravity cores was about 3 meters, with an average of about 2.5 meters, recovering all of the Holocene and upper Pleistocene sections in the Black Sea. During the latest Pleistocene glaciation, sea level dropped below the 35-meters-deep Bosporus outlet sill of the Black Sea. Therefore throughout most of its history the Black Sea was a lake, and most of its sediments are lacustrine. The oldest sediments recovered (older than 8,000 calendar years) consist of massive to coarsely banded lacustrine calcareous clay designated as lithologic Unit III, generally containing less than 1 percent organic carbon (OC). The base of overlying Unit II marks the first incursion of Mediterranean seawater into the Black Sea, and the onset of bottom-water anoxia about 7,900 calendar years. Unit II contains as much as 15 percent OC in cores from the deepest part of the Black Sea (2,200 meters). The calcium carbonate (CaCO3) remains of the coccolith Emiliania huxleyi form the distinctive white laminae of overlying Unit I. The composition of Unit III and Unit II sediments are quite different, reflecting different terrigenous clastic sources and increased contributions from hydrogenous and biogenic components in anoxic Unit II sapropel. In Unit II, positive covariance between OC and three trace elements commonly concentrated in OC-rich sediments where sulfate reduction has occurred (molybdenum, nickel, and vanadium) and a nutrient (phosphorus) suggest a large marine source for these elements although nickel and vanadium also have a large terrigenous clastic source. The marine sources may be biogenic or hydrogenous. A large biogenic source is also suggested for copper and cobalt. Because abundant pyrite forms in the water column and sediments of the Black Sea, we expected to find a large hydrogenous iron component, but a strong covariance of iron with aluminum suggests that the dominant source of iron is from terrigenous clastic material. Most elements in lacustrine Unit III sediments have a strong covariance with Al indicating a very dominant terrigenous source. In Unit II, some elements, especially nickel, molybdenum, vanadium, and zinc, do not correlate with aluminum and have concentrations well above terrigenous clastic material, indicating a marine source.
USDA-ARS?s Scientific Manuscript database
Phytophthora kernoviae has only been isolated from the United Kingdom (U.K.) and New Zealand. To understand what differences may exist between isolates from these two distinct geographical regions, virulence studies on three host plants and sporulation on host leaves were conducted on select isolat...
Multiple nuclear loci reveal the distinctiveness of the threatened, Neotropical Pinus chiapensis
John Syring; Rafael F. del Castillo; Richard Cronn; Aaron Liston
2007-01-01
Pinus chiapensis is a threatened species of pine from southern Mexico and Guatemala. It was first described as a disjunct variety of P. strobus from the eastern United States and Canada. Subsequent morphological work indicates that P. chinpensis is a distinct species, but this interpretation is controversial. To...
Hampton, B.A.; Ridgway, K.D.; O'Neill, J. M.; Gehrels, G.E.; Schmidt, J.; Blodgett, R.B.
2007-01-01
Mesozoic strata of the northwestern Talkeetna Mountains are located in a regional suture zone between the allochthonous Wrangellia composite terrane and the former Mesozoic continental margin of North America (i.e., the Yukon-Tanana terrane). New geologic mapping, measured stratigraphic sections, and provenance data define a distinct three-part stratigraphy for these strata. The lowermost unit is greater than 290 m thick and consists of Upper Triassic-Lower Jurassic mafic lavas, fossiliferous limestone, and a volcaniclastic unit that collectively we informally refer to as the Honolulu Pass formation. The uppermost 75 m of the Honolulu Pass formation represent a condensed stratigraphic interval that records limited sedimentation over a period of up to ca. 25 m.y. during Early Jurassic time. The contact between the Honolulu Pass formation and the overlying Upper Jurassic-Lower Cretaceous clastic marine strata of the Kahiltna assemblage represents a ca. 20 m.y. depositional hiatus that spans the Middle Jurassic and part of Late Jurassic time. The Kahiltna assemblage may to be up to 3000 m thick and contains detrital zircons that have a robust U-Pb peak probability age of 119.2 Ma (i.e., minimum crystallization age/maximum depositional age). These data suggest that the upper age of the Kahiltna assemblage may be a minimum of 10-15 m.y. younger than the previously reported upper age of Valanginian. Sandstone composition (Q-43% F-30% L-27%-Lv-71% Lm-18% Ls-11%) and U-Pb detrital zircon ages suggest that the Kahiltna assemblage received igneous detritus mainly from the active Chisana arc, remnant Chitina and Talkeetna arcs, and Permian-Triassic plutons (Alexander terrane) of the Wrangellia composite terrane. Other sources of detritus for the Kahiltna assemblage were Upper Triassic-Lower Jurassic plutons of the Taylor Mountains batholith and Devonian-Mississippian plutons; both of these source areas are part of the Yukon-Tanana terrane. The Kahiltna assemblage is overlain by previously unrecognized nonmarine strata informally referred to here as the Caribou Pass formation. This unit is at least 250 m thick and has been tentatively assigned an Albian-Cenomanian-to-younger age based on limited palynomorphs and fossil leaves. Sandstone composition (Q-65% F-9% L-26%-Lv-28% Lm-52% Ls-20%) from this unit suggests a quartz-rich metamorphic source terrane that we interpret as having been the Yukon-Tanana terrane. Collectively, provenance data indicate that there was a fundamental shift from mainly arc-related sediment derivation from sources located south of the study area during Jurassic-Early Cretaceous (Aptian) time (Kahiltna assemblage) to mainly continental margin-derived sediment from sources located north and east of the study area by Albian-Cenomanian time (Caribou Pass formation). We interpret the threepart stratigraphy defined for the northwestern Talkeetna Mountains to represent pre- (the Honolulu Pass formation), syn- (the Kahiltna assemblage), and post- (the Caribou Pass formation) collision of the Wrangellia composite terrane with the Mesozoic continental margin. A similar Mesozoic stratigraphy appears to exist in other parts of south-central and southwestern Alaska along the suture zone based on previous regional mapping studies. New geologic mapping utilizing the three-part stratigraphy interprets the northwestern Talkeetna Mountains as consisting of two northwest-verging thrust sheets. Our structural interpretation is that of more localized thrust-fault imbrication of the three-part stratigraphy in contrast to previous interpretations of nappe emplacement or terrane translation that require large-scale displacements. Copyright ?? 2007 The Geological Society of America.
NASA Astrophysics Data System (ADS)
Itaoka, Kanae; Kim, In-Tae; Yamabuki, Kazuhiro; Yoshimoto, Nobuko; Tsutsumi, Hiromori
2015-11-01
Room temperature rechargeable magnesium (Mg) batteries are constructed from Mg as a negative material, sulfur (S)-containing composite prepared from elemental sulfur and the bis(alkenyl) compound having a crown ether unit (BUMB18C6) or linear ether unit (UOEE) as a positive material and the simple electrolyte (0.7 mol dm-3 Mg[N(SO2CF3)2]2-triglyme (G3) solution). The reaction between molten S and the bis(alkenyl) compound (BUMB18C6 or UOEE) provides the sulfur-containing composite, S-BUMB18C6 or S-UOEE. Both of the sulfur-containing composites are electrochemically active in the Mg salt-based electrolyte, acetonitrile- or G3- Mg[N(SO2CF3)2]2 electrolyte. The first discharge capacity of the test cells with the sulfur-containing composite is 460 Ah kg-1 (per the weight of sulfur in the composite) with the S-BUMB18C6 electrode and 495 Ah kg-1 with the S-UOEE electrode. According to the continuous charge-discharge cycle tests (at 10th cycle), the discharge capacity of the test cell with the S-BUMB18C6 electrode (68.1 Ah kg-1) is higher than that with the S-UOEE electrode (0.18 Ah kg-1). The crown ether units in the S-BUMB18C6 composite may create ion-conducting paths in the cathode, prevent rise in the internal resistance of the cathode, and provide better cycle performance of the test cells with the S-BUMB18C6 composite electrode than that with the S-UOEE electrode.
Particle shape effects on the fracture of discontinuously-reinforced 6061-A1 matrix composites
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shi, N.; Song, S.G.; Gray, G.T., III
1996-05-01
Effects on fracture and ductility of a spherical and an angular particulate-reinforced 6061-Al composite containing 20(vol)% Al{sub 2}O{sub 3} were studied using SEM fractography and modeled using finite element method (FEM). The spherical particulate composite exhibited a slightly lower yield strength and work hardening rate but a considerably higher ductility than the angular counterpart. SEM fractography showed that during tensile deformation the spherical composite failed through void nucleation and linking in the matrix near the reinforcement/matrix interface, whereas the angular composite failed through particle fracture and matrix ligament rupture. FEM results indicate that the distinction between the failure modes formore » these two composites can be attributed to differences in development of internal stresses and strains within the composites due to particle shape.« less
FEM Analysis of Glass/Epoxy Composite Based Industrial Safety Helmet
NASA Astrophysics Data System (ADS)
Ram, Khushi; Bajpai, Pramendra Kumar
2017-08-01
Recently, the use of fiber reinforced polymer in every field of engineering (automobile, industry and aerospace) and medical has increased due to its distinctive mechanical properties. The fiber based polymer composites are more popular because these have high strength, light in weight, low cost and easily available. In the present work, the finite element analysis (FEA) of glass/epoxy composite based industrial safety helmet has been performed using solid-works simulation software. The modeling results show that glass fiber reinforced epoxy composite can be used as a material for fabrication of industrial safety helmet which has good mechanical properties than the existing helmet material.
Dynamic mechanical properties of a Ti-based metallic glass matrix composite
NASA Astrophysics Data System (ADS)
Li, Jinshan; Cui, Jing; Qiao, Jichao; Bai, Jie; Kou, Hongchao; Wang, Jun
2015-04-01
Dynamic mechanical behavior of a Ti50Zr20Nb12Cu5Be13 bulk metallic glass composite was investigated using mechanical spectroscopy in both temperature and frequency domains. Storage modulus G' and loss modulus G″ are determined by temperature, and three distinct regions corresponding to different states in the bulk metallic glass composite are characterized. Physical parameters, such as atomic mobility and correlation factor χ, are introduced to analyze dynamic mechanical behavior of the bulk metallic glass composite in the framework of quasi-point defects (QPD) model. The experimental results are in good agreement with the prediction of QPD model.
Dynamic mechanical properties of a Ti-based metallic glass matrix composite
DOE Office of Scientific and Technical Information (OSTI.GOV)
Li, Jinshan, E-mail: ljsh@nwpu.edu.cn; Cui, Jing; Bai, Jie
2015-04-21
Dynamic mechanical behavior of a Ti{sub 50}Zr{sub 20}Nb{sub 12}Cu{sub 5}Be{sub 13} bulk metallic glass composite was investigated using mechanical spectroscopy in both temperature and frequency domains. Storage modulus G′ and loss modulus G″ are determined by temperature, and three distinct regions corresponding to different states in the bulk metallic glass composite are characterized. Physical parameters, such as atomic mobility and correlation factor χ, are introduced to analyze dynamic mechanical behavior of the bulk metallic glass composite in the framework of quasi-point defects (QPD) model. The experimental results are in good agreement with the prediction of QPD model.
Cathedral Peak Granodiorite, Sierra Nevada Batholith, California: A Big, Mushy, Magma System?
NASA Astrophysics Data System (ADS)
Burgess, S. D.; Miller, J. S.; Matzel, J. P.
2006-12-01
The Cathedral Peak Granodiorite (Kcp) is the largest mapped unit of the >1200 km2 Tuolumne Batholith (TB), which is one of a belt of Cretaceous zoned intrusions within the Sierra Nevada Batholith. Previous workers [1,2] proposed that the zonation in the TB was mainly produced in-situ either by inward differentiation of a large mass of magma and/or large-scale magma mixing between compositionally distinct map units. Recent geochronology has shown that the entire TB was intruded over 8-9 Ma, leading to the hypothesis that it was constructed continuously over this time period by many small increments [3], with variations in chemical and isotopic composition attributed to processes in the melt source. This hypothesis is also supported by scatter in trace elements vs. longitude from the margins to inner TB and appreciable variability in Nd and Sr isotopic data between the mapped units of the TB [e.g., 4]. Thus attributing chemical variations between major intrusive units to simple closed system fractionation or binary magma mixing is precluded. New field, geochemical and geochronologic work along a 5 km transect from the porphyritic Half Dome Granodiorite (Khdp) margin to the innermost Kcp, and approximately perpendicular to the Kcp-Khdp contact shows that: (1) magmatic foliation is moderately- to steeply-dipping (>60°); (2) zircon ages at each end of the transect are indistinguishable; (3) bulk composition varies only modestly but trace elements show variable degrees of scatter with greatest scatter observed among feldspar-compatible and highly incompatible elements (Sr, Ba, Th); (5) ɛNd(t) is invariant (Sr(i) has small variation); (6) abundant field evidence for transport and mixing of melt and crystals is observed (multiple generations of steep planar, tube- like, and chaotically folded schlieren, rafts and monomineralic clusters of K-feldspar, irregular and mingled contacts between sheets of texturally variable granite and schlieren). The broad geochemical and isotopic data are consistent with bulk fractionation in the Cathedral Peak Granodiorite. However, the geochemical spatial variation (especially trace elements) and field evidence suggest that fractionation was highly disorganized and involved mixing and remobilization of crystal mush as it solidified, possibly triggered by new inputs of isotopically uniform magma (i.e., recharge from the magma source). These data and observations are consistent with construction of a large, and dynamic but mushy magmatic system within the last 1 Ma of the total 9 Ma TB intrusion interval. [1] Bateman, PC & Chappell BW (1979) Geol Soc Am Bull, Part I 90:465-482; [2] Reid, JB, Evans, OC & Fates DG (1983) Earth Planet Sci Letters, 66:243-261; [3] Coleman, DS, Gray, W & Glazner, AF (2004) Geology, 32:433-436; [4] Kistler, RW, Chappell, BW, Peck, DL & Bateman, PC (1986) Contrib Min Pet, 94:205-220;
Sedimentological characteristics of lake sediment of the Lake Jelonek (North Poland)
NASA Astrophysics Data System (ADS)
Kramkowski, Mateusz; Filbrandt-Czaja, Anna; Ott, Florian; Słowiński, Michał; Tjallingii, Rik; Błaszkiewicz, Mirosław; Brauer, Achim
2016-04-01
Lake Jelonek is located in Northern Poland (53°45'58N, 18°23'30E). The lake is surrounded by forest, covers an area of 19,9 ha and has a maximum depth of 13,8 m. In 2013 and 2014 three overlapping and parallel series of long sediment cores JEL14-A-(1445 cm), JEL14-B-(1430 cm), JEL14-C-(1435 cm) and seven short gravity cores JEL13 (K1-K7) have been recovered from the deepest part of the lake. A continuous composite profile JEL14 covering 1426 cm has been established by correlation based on 28 distinct macroscopic marker layers. The sediment sequence can be divided into 15 (I-XV) lithological units. These units comprise biochemical calcite varves, homogeneous calcite-rich gyttja, homogeneous organic-diatomaceous gyttja, and sandy layers. The chronology established so far is based on 14 AMS 14C dates from terrestrial plant remains and tephrochronology (Askja AD-1875) and covers the interval from the Younger Dryas to present times. Based on the chronology and sedimentological characteristics the composite profile has been correlated to a previous core from which a detailed pollen diagram had been established (Filbrandt-Czaja 2009). Here we present initial results from thin section analyses for two intervals from the new composite record JEL14, (I) the uppermost 0-256 cm and (II) the interval from 768-1296 cm. Intercalated between these two varved interval is a thick section (512 cm) of homogeneous organic-ditomaceous sediments. We present varve micro-facies data in combination with μ-XRF element scanning for comprehensive reconstruction of the sedimentation processes in Lake Jelonek. Preliminary varve counting reveals that the uppermost 256 cm varved sediments comprise ca 925 years (2008-1083 AD), while the lower floating varve interval covers the time period from 1850 - 10500 cal a BP. This study is a contribution to the Virtual Institute of Integrated Climate and Landscape Evolution Analysis -ICLEA- of the Helmholtz Association; grant number VH-VI-415. References: Filbrandt-Czaja, A. 2009: Studia nad historią szaty roślinnej i krajobrazu Borów Tucholskich. pp. Wydawnictwo Naukowe Uniwersytetu Mikołaja Kopernika.
NASA Astrophysics Data System (ADS)
Jamiyanaa, Khongor
Pultrusion processing is a technique to make highly aligned fiber reinforced polymer composites. Thermoset pultrusion is a mature process and well established, while thermoplastic pultrusion in still in its infancy. Thermoplastic pultrusion has not been well established because thermoplastic resins are difficult to process due to their high viscosity. However, thermoplastic resins offer distinct advantages that make thermoplastic pultrusion worth exploring. The present work centers on developing a method to design and validate a die for a thermoplastic pultrusion system. Analytical models and various software tools were used to design a pultrusion die. Experimental measurements have been made to validate the models. One-dimensional transient heat transfer analysis was used to calculate the time required for pre-impregnated E-Glass/Polypropylene tapes to melt and consolidate into profiled shapes. Creo Element/Pro 1.0 was used to design the die, while ANSYS Work Bench 14.0 was used to conduct heat transfer analysis to understand the temperature profile of the pultrusion apparatus. Additionally Star-CCM+ was used to create a three-dimensional fluid flow model to capture the molten polymer flow inside the pultrusion die. The fluid model was used to understand the temperature of the flow and the force required to pull the material at any given temperature and line speed. A complete pultrusion apparatus including the die, heating unit, cooling unit, and the frame has been designed and manufactured as guided by the models, and pultruded profiles have been successfully produced. The results show that the analytical model and the fluid model show excellent correlation. The predicted and measured pulling forces are in agreement and show that the pull force increases as the pull speed increases. Furthermore, process induced residual stress and its influence on dimensional instability, such as bending or bowing, on pultruded composites was analyzed. The study indicated that unbalanced layup can produce asymmetrical residual stress through the thickness and causes the part to bow. Furthermore, the residual stress through the thickness was mapped with excellent accuracy. A design of experiments around the processing parameters indicated that increase in pull speed or decrease in die temperature increased the residual stress within the part.
33 CFR 83.24 - Towing and pushing (Rule 24).
Code of Federal Regulations, 2010 CFR
2010-07-01
... it can best be seen. (b) Pushing vessel and pushed vessel rigidly connected in composite unit. When a pushing vessel and a vessel being pushed ahead are rigidly connected in a composite unit they shall be...). (e) Vessels being towed. A vessel or object other than those referred to in paragraph (g) of this...
48 CFR 52.227-1 - Authorization and Consent.
Code of Federal Regulations, 2011 CFR
2011-10-01
... United States patent— (1) Embodied in the structure or composition of any article the delivery of which... a government regulatory body, of any invention described in and covered by a United States patent (1) embodied in the structure or composition of any article the delivery of which is accepted by the Government...
48 CFR 52.227-1 - Authorization and Consent.
Code of Federal Regulations, 2010 CFR
2010-10-01
... United States patent— (1) Embodied in the structure or composition of any article the delivery of which... a government regulatory body, of any invention described in and covered by a United States patent (1) embodied in the structure or composition of any article the delivery of which is accepted by the Government...
Fragmentation of forest communities in the eastern United States
Kurt Riitters; John Coulston; James Wickham
2011-01-01
Forest fragmentation threatens the sustainability of forest communities in the eastern United States. Forest communities exhibiting either a low total area or low percentage of intact forest are subject to relatively higher risk of shifts in stand composition towards edge-adapted and invasive species. Such changes in stand composition could result in local extirpation...
Visual Representations in Second Graders' Information Book Compositions
ERIC Educational Resources Information Center
Coleman, Julianne M.; Bradley, Linda Golson; Donovan, Carol A.
2012-01-01
This paper describes the visuals second grade students included in their own information book compositions during a science unit on weather during which multimodal science trade books on the topic of weather were read aloud. First, the multimodal nature of the information books used in the unit are described. Second, the teacher's talk about…
NASA Astrophysics Data System (ADS)
Khim, B. K.; Kim, J. E.; Lee, J.; Ikehara, M.; Clift, P. D.; Pandey, D.; Kulhanek, D. K.; Science Party, E.
2016-12-01
The Arabian Sea is characterized by a large pool of denitrifying water at intermediate water depths, which plays an important role in the marine nitrogen cycle and resultant response to climate change. A growing body of research emphasizes strong linkage between denitrification strength in the Arabian Sea and climate change at both orbital and millennial timescales. Drilling by International Ocean Discovery Program Expedition 355 was conducted at Site U1456 in the Laxmi Basin, Eastern Arabian Sea, 475 km from the Indian coastline and 820 km south of the modern Indus River Delta. Four lithologic units are defined onboard at the Site U1456. A total of 282 samples were collected from a composite section of Unit I consisting of Holes U1456A and U1456C. Unit I is composed mostly of nannofossil ooze and/or foraminifer-rich nannofossil ooze with interbedded clay, silt, and sand layers. Oxygen isotope measurements of planktonic foraminifera (G. ruber and G. sacculifer), together with shipboard biostratigraphic and paleomagnetic data, constrain the age of Unit I to younger than about 1.2 Ma. The δ15Nbulk values fluctuate from 4.5‰ to 9.6‰ with a mean of 7.3(±0.95)‰. Higher δ15Nbulk values coincide with interglacial intervals whereas lower δ15Nbulk values correspond to glacial intervals, representing clear glacial-interglacial cyclicity. These variations demonstrate the distinct climatic linkage with the degree of denitrification at orbital timescales, in association with changes in hydrography and productivity. The relation between denitrification and monsoon intensity, previously reported for the continental margins of the Arabian Sea, is also recorded in the deep water sediments.
Fore arc tectonothermal evolution of the El Oro metamorphic province (Ecuador) during the Mesozoic
NASA Astrophysics Data System (ADS)
Riel, Nicolas; Martelat, Jean-Emmanuel; Guillot, Stéphane; Jaillard, Etienne; Monié, Patrick; Yuquilema, Jonatan; Duclaux, Guillaume; Mercier, Jonathan
2014-10-01
The El Oro metamorphic province of SW Ecuador is a composite massif made of juxtaposed terranes of both continental and oceanic affinity that has been located in a fore-arc position since Late Paleozoic times. Various geochemical, geochronological, and metamorphic studies have been undertaken on the El Oro metamorphic province, providing an understanding of the origin and age of the distinct units. However, the internal structures and geodynamic evolution of this area remain poorly understood. Our structural analysis and thermal modeling in the El Oro metamorphic province show that this fore-arc zone underwent four main geological events. (1) During Triassic times (230-225 Ma), the emplacement of the Piedras gabbroic unit at crustal-root level ( 9 kbar) triggered partial melting of the metasedimentary sequence under an E-W extensional regime at pressure-temperature conditions ranging from 4.5 to 8.5 kbar and from 650 to 900°C for the migmatitic unit. (2) At 226 Ma, the tectonic underplating of the Arenillas-Panupalí oceanic unit (9 kbar and 300°C) thermally sealed the fore-arc region. (3) Around the Jurassic-Cretaceous boundary, the shift from trench-normal to trench-parallel subduction triggered the exhumation and underplating of the high-pressure, oceanic Raspas Ophiolitic Complex (18 kbar and 600°C) beneath the El Oro Group (130-120 Ma). This was followed by the opening of a NE-SW pull-apart basin, which tilted the massif along an E-W subhorizontal axis (110 Ma). (4) In Late Cretaceous times, an N-S compressional event generated heterogeneous deformation due to the presence of the Cretaceous Celica volcanic arc, which acted as a buttress and predominantly affected the central and eastern part of the massif.
Molecular tandem repeat strategy for elucidating mechanical properties of high-strength proteins
Jung, Huihun; Pena-Francesch, Abdon; Saadat, Alham; Sebastian, Aswathy; Kim, Dong Hwan; Hamilton, Reginald F.; Albert, Istvan; Allen, Benjamin D.; Demirel, Melik C.
2016-01-01
Many globular and structural proteins have repetitions in their sequences or structures. However, a clear relationship between these repeats and their contribution to the mechanical properties remains elusive. We propose a new approach for the design and production of synthetic polypeptides that comprise one or more tandem copies of a single unit with distinct amorphous and ordered regions. Our designed sequences are based on a structural protein produced in squid suction cups that has a segmented copolymer structure with amorphous and crystalline domains. We produced segmented polypeptides with varying repeat number, while keeping the lengths and compositions of the amorphous and crystalline regions fixed. We showed that mechanical properties of these synthetic proteins could be tuned by modulating their molecular weights. Specifically, the toughness and extensibility of synthetic polypeptides increase as a function of the number of tandem repeats. This result suggests that the repetitions in native squid proteins could have a genetic advantage for increased toughness and flexibility. PMID:27222581
From Solute, Fluidic and Particulate Precursors to Complex Organizations of Matter.
Rao, Ashit; Cölfen, Helmut
2018-03-24
The organization of matter from its constitutive units recruits intermediate states with distinctive degrees of self-association and molecular order. Existing as clusters, droplets, gels as well as amorphous and crystalline nanoparticles, these precursor forms have fundamental contributions towards the composition and structure of inorganic and organic architectures. In this personal account, we show that the transitions from atoms, molecules or ionic species to superstructures of higher order are intertwined with the interfaces and interactions of precursor and intermediate states. Structural organizations distributed across different length scales are explained by the multistep nature of nucleation and crystallization, which can be guided towards functional hybrid materials by the strategic application of additives, templates and reaction environments. Thus, the non-classical pathways for material formation and growth offer conceptual frameworks for elucidating, inducing and directing fascinating material organizations of biogenic and synthetic origins. © 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Goldsmith, Dawn B.; Parsons, Rachel J.; Beyene, Damitu; Salamon, Peter
2015-01-01
Deep sequencing of the viral phoH gene, a host-derived auxiliary metabolic gene, was used to track viral diversity throughout the water column at the Bermuda Atlantic Time-series Study (BATS) site in the summer (September) and winter (March) of three years. Viral phoH sequences reveal differences in the viral communities throughout a depth profile and between seasons in the same year. Variation was also detected between the same seasons in subsequent years, though these differences were not as great as the summer/winter distinctions. Over 3,600 phoH operational taxonomic units (OTUs; 97% sequence identity) were identified. Despite high richness, most phoH sequences belong to a few large, common OTUs whereas the majority of the OTUs are small and rare. While many OTUs make sporadic appearances at just a few times or depths, a small number of OTUs dominate the community throughout the seasons, depths, and years. PMID:26157645
Pinto, M Alice; Rubink, William L; Coulson, Robert N; Patton, John C; Johnston, J Spencer
2004-05-01
The invasion of Africanized honeybees (Apis mellifera L.) in the Americas provides a window of opportunity to study the dynamics of secondary contact of subspecies of bees that evolved in allopatry in ecologically distinctive habitats of the Old World. We report here the results of an 11-year mitochondrial DNA survey of a feral honeybee population from southern United States (Texas). The mitochondrial haplotype (mitotype) frequencies changed radically during the 11-year study period. Prior to immigration of Africanized honeybees, the resident population was essentially of eastern and western European maternal ancestry. Three years after detection of the first Africanized swarm there was a mitotype turnover in the population from predominantly eastern European to predominantly A. m. scutellata (ancestor of Africanized honeybees). This remarkable change in the mitotype composition coincided with arrival of the parasitic mite Varroa destructor, which was likely responsible for severe losses experienced by colonies of European ancestry. From 1997 onward the population stabilized with most colonies of A. m. scutellata maternal origin.
Sigle, Steffen; Steblau, Nadja; Wohlleben, Wolfgang; Muth, Günther
2016-09-01
Cell wall glycopolymers (CWG) represent an important component of the Gram-positive cell envelope with many biological functions. The mycelial soil bacterium Streptomyces coelicolor A3(2) incorporates two distinct CWGs, polydiglycosylphosphate (PDP) and teichulosonic acid, into the cell wall of its vegetative mycelium but only little is known about their role in the complex life cycle of this microorganism. In this study we established assays to measure the total amount of CWGs in mycelial cell walls and spore walls, to quantify the individual CWGs and to determine the length of PDP. By applying these assays, we discovered that the relative amount of CWGs, especially of PDP, is reduced in spores compared to vegetative mycelium. Furthermore we found that PDP extracted from mycelial cell walls consisted of at least 19 repeating units, whereas spore walls contained substantially longer PDP polymers. Copyright © 2016 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Zhang, Xuekai; Lu, Gang; Sun, Meng; Mahankali, Madhu; Ma, Yanfei; Zhang, Mingming; Hua, Wangde; Hu, Yuting; Wang, Qingbing; Chen, Jinghuo; He, Gang; Qi, Xiangbing; Shen, Weijun; Liu, Peng; Chen, Gong
2018-05-01
New methods capable of effecting cyclization, and forming novel three-dimensional structures while maintaining favourable physicochemical properties are needed to facilitate the development of cyclic peptide-based drugs that can engage challenging biological targets, such as protein-protein interactions. Here, we report a highly efficient and generally applicable strategy for constructing new types of peptide macrocycles using palladium-catalysed intramolecular C(sp3)-H arylation reactions. Easily accessible linear peptide precursors of simple and versatile design can be selectively cyclized at the side chains of either aromatic or modified non-aromatic amino acid units to form various cyclophane-braced peptide cycles. This strategy provides a powerful tool to address the long-standing challenge of size- and composition-dependence in peptide macrocyclization, and generates novel peptide macrocycles with uniquely buttressed backbones and distinct loop-type three-dimensional structures. Preliminary cell proliferation screening of the pilot library revealed a potent lead compound with selective cytotoxicity toward proliferative Myc-dependent cancer cell lines.
Localized and Areally Extensive Alterations in Marathon Valley, Endeavour Crater Rim, Mars
NASA Technical Reports Server (NTRS)
Mittlefehldt, David W.; Gellert, Ralf; Van Bommel, Scott; Arvidson, Raymond E.; Clark, Benton C.; Cohen, Barbara A.; Farrand, William H.; Ming, Douglas W.; Schroeder, Christian; Yen, Albert S.;
2016-01-01
Mars Exploration Rover Opportunity is exploring the rim of 22 km diameter, Noachian-aged Endeavour crater. Marathon Valley cuts through the central region of the western rim providing a window into the local lower rim stratigraphic record. Spectra from the Compact Reconnaissance Imaging Spectrometer for Mars show evidence for the occurrence of Fe-Mg smectite in this valley, indicating areally extensive and distinct lithologic units and/or styles of aqueous alteration. The Alpha Particle X-ray Spectrometer has determined the compositions of 59 outcrop targets on untreated, brushed and abraded surfaces. Rocks in the Marathon Valley region are soft breccias composed of mm- to cm-sized darker clasts set in a lighter-toned, finegrained matrix. They are basaltic in non-volatile-element composition and compositionally similar to breccias investigated elsewhere on the rim. Alteration styles recorded in the rocks include: (1) Enrichments in Si, Al, Ti and Cr in more reddish-colored rock, consistent with leaching of more soluble cations and/or precipitation of Si +/- Al, Ti, Cr from fluids. Coprecipitation of Ge-rich phases with Si occurred in the western area only; high water:rock is indicated. Pancam multispectral observations indicate higher nanophase ferric oxide contents, but the rocks have lower Fe contents. The highly localized nature of the red zones indicate they cannot be the source of the widespread smectite signature observed from orbit. (2) Outcrops separated by approximately 65 m show common compositional changes between brushed and abraded (approximately 1 mm deep) targets: increases in S and Mg; decreases in Al, Cl and Ca. These changes are likely due to relatively recent, surface-related alteration of valley rocks and formation of surface coatings under low water:rock. (3) One target, from the center of a region of strong CRISM smectite signature, shows modest differences in composition (higher Si, K; lower Mn) compared to most Marathon Valley rocks, while another target approximately 40 cm away on the same outcrop does not; a change towards smectite bulk compositions is not observed. The smectite signature likely resulted from alteration under low water:rock such that primary minerals were partially altered to phyllosilicates, but wholesale leaching of cations by fluids did not occur.
Geochemical Mapping of 4 Vesta Begins
NASA Technical Reports Server (NTRS)
Prettyman, Thomas H.; Feldman, William C.; Forni, Olivier; Joy, Steven P.; Lawrence, David J.; LeCorre, Lucille; Mafi, Joseph N.; McCord, Thomas B.; McCoy, Timothy J.; McSween, Harry Y.;
2011-01-01
By December, the NASA Dawn spacecraft will have descended to a low altitude mapping orbit (LAMO), where the Gamma Ray and Neutron Detector (GRaND) will acquire global mapping data for up to four months. Measurements by GRaND will help answer elusive questions about how Vesta differentiated and the nature of processes that shaped Vesta s surface. The data will be analyzed to determine the abundances of Mg, Si, Fe, K, Th, and H at a spatial resolution of roughly 300 km full-width-at-half-maximum from a 465 km radius orbit. Thermal and fast neutron counting data will be analyzed to determine the neutron macroscopic absorption cross section and average atomic mass, providing constraints on additional elements, such as Ca and Al. GRaND will quantify the elemental composition of coarse spatial units identified by Dawn s Framing Camera (FC) and the Visible & Infrared Spectrometer (VIR). In addition, GRaND will map the mixing ratio of compositional end members selected from the howardite, eucrite and diogenite (HED) meteorites, determine the relative proportions of plagioclase and mafic minerals, and search for compositions that are absent or under-represented in the meteorite collection. While it is generally thought that Vesta s crust on a regional scale should be well-represented by linear mixing of HED whole-rock compositions, there are hints that Vesta may be more diverse than implied by this model. For example, the discovery of K-rich impact glasses in howardites suggests that K-rich rocks may be present on a portion of Vesta s surface, and the analysis of diogenites indicates considerable variability in the magmatic processes that formed them. The chemical composition of materials within Vesta s south polar structure may provide further clues to how it formed. An impact might have exposed mantle and lower crustal materials, which should have a distinctive compositional signature. We present the analysis of data acquired by GRaND from cruise through the descent to LAMO, including GRaND s sensitivity to different elements and geochemical processes.
USDA-ARS?s Scientific Manuscript database
A number of recent soil biota studies have deviated from the standard experimental approach of generating a distinct data value for each experimental unit (e.g. Yang et al., 2013; Gundale et al., 2014). Instead, these studies have mixed together soils from multiple experimental units (i.e. sites wi...
Aeolian Abrasion at the Curiosity Landing Site: Clues to the Role of Wind in Landscape Modification
NASA Astrophysics Data System (ADS)
Bridges, N. T.; Le Mouélic, S.; Hallet, B.; Newman, C. E.; Rice, M. S.; Blaney, D. L.; Calef, F. J.; Herkenhoff, K. E.; Langevin, Y.; Lewis, K. W.; Maurice, S.; Pinet, P. C.; Wiens, R. C.; de Pablo, M.; Renno, N. O.
2013-12-01
The broad scale geomorphology of Gale Crater reflects diverse aeolian processes, from airfall settling that likely deposited much of the upper and some of the lower units of Mt. Sharp, to evidence of extensive wind exhumation and removal of material exterior to the mound, to active dunes on the crater floor. The integrated effect of aeolian sand transport can also be examined on a much smaller scale by the study of ventifacts, rocks that have been abraded by windborne particles. A diversity of ventifacts are found along Curiosity's traverse through the upper 'hummocky' (HY) geomorphic unit and the lower Yellowknife Bay (YKB) sedimentary rocks. The textures are analogous to abrasion features found on Earth and include cm-scale facets, keels, elongated pits, grooves, flutes, and basal sills. High-resolution images from ChemCam's Remote Micro-Imager also show mm-scale lineations. Evidence of differential erosion is common, with HY conglomerates (e.g., Hottah, Link) and the YKB Sheepbed mudstone unit containing distinct wind tails in the lee of resistant pebbles, and bedding features within Rocknest 3, the YKB Shaler sandstone unit, and other layered rocks displaying prominent ridge-groove topography. ChemCam LIBS depth profile data so far show no strong evidence for chemical differences in the elemental composition between abraded and non-abraded surfaces (as determined from qualitative assessment), as might be expected if there were rock coatings or weathering rinds undergoing active abrasion. Preliminary measurements of ventifact texture and wind tail orientations indicate sandblasting in HY and YKB from predominantly southwesterly and northerly directions, respectively. Based on meso-scale models of current winds and REMS results, SW flow is uncommon whereas N winds are frequent. Compositional and textural information from the suite of MSL instruments indicate that HY rocks are dominated by various types of basalt (either as whole rocks or the resistant clasts in conglomerates), whereas YKB are basaltic clastic rocks, with the lower members impregnated with sulfate veins, and were easily drilled. The HY rocks are therefore likely more resistant to abrasion than those of YKB. Combined, these results indicate that ventifacts so far investigated by MSL record two wind regimes, one a long-term integrated record of rare, yet strong winds and the other more reflective of typical conditions.
An evolved axial melt lens in the Northern Ibra Valley, Southern Oman Ophiolite
NASA Astrophysics Data System (ADS)
Loocke, M. P.; Lissenberg, C. J.; MacLeod, C. J.
2014-12-01
The axial melt lens (AML) is a common feature lying at the base of the upper crust at fast-spreading mid-ocean ridges. It is thought to play a major role in the evolution of MORB and, potentially, accretion of the plutonic lower crust. In order to better understand the petrological processes that operate in AMLs we have examined the nature and variability of the horizon equivalent to the AML preserved in the Oman ophiolite. We present the results of a detailed investigation of a section east of Fahrah in the Ibra Valley. Here, a suite of 'varitextured' gabbros separates the sheeted dykes above from foliated gabbros below. It comprises 3 distinct units: an ophitic gabbro with pegmatitic patches (patchy gabbro; 70 m thick), overlain by a spotty gabbro (50 m), capped by a quartz-diorite (120 m). The sheeted dykes are observed to root in the quartz-diorite. Contacts between the plutonic units are gradational and subhorizontal. All of the units are isotropic. A total of 110 samples were collected for detailed petrographic and chemical analysis. With the exception of a small number of the diorites, all of the samples have a 'cumulate' component. Primary igneous amphibole is ubiquitous, present even as a minor phase in the foliated gabbros beneath, and indicating extensive differentiation and/or the presence of water in the primary liquid. France et al. (2014, Lithos) report patches of granoblastic material from this horizon in the Fahrah area, and suggest they represent the restites of partially melted pieces of the sheeted dykes. We did not, however, find any such granoblastic material, nor can the quartz-diorites represent partial melt; instead, preliminary geochemical modeling suggests that all of the units can be related by simple progressive fractional crystallization of an Oman axial ('V1' or 'Geotimes') melt. Along with the field relationships, as well as the basaltic andesite to dacite composition of the overlying sheeted dykes, this suggests that the AML was the locus of formation of the highly evolved melts. This contrasts with the more primitive AML and sheeted dyke complex documented in Wadi Abyad. From this we conclude that there is significant lateral variability in AML compositions along the Oman ridge axis.
Does the light source affect the repairability of composite resins?
Karaman, Emel; Gönülol, Nihan
2014-01-01
The aim of this study was to examine the effect of the light source on the microshear bond strength of different composite resins repaired with the same substrate. Thirty cylindrical specimens of each composite resin--Filtek Silorane, Filtek Z550 (3M ESPE), Gradia Direct Anterior (GC), and Aelite Posterior (BISCO)--were prepared and light-cured with a QTH light curing unit (LCU). The specimens were aged by thermal cycling and divided into three subgroups according to the light source used--QTH, LED, or PAC (n = 10). They were repaired with the same substrate and a Clearfil Repair Kit (Kuraray). The specimens were light-cured and aged for 1 week in distilled water at 37 °C. The microshear bond strength and failure modes were assessed. There was no significant difference in the microshear bond strength values among the composite resins, except for the Filtek Silorane group that showed significantly lower bond strength values when polymerized with the PAC unit compared to the QTH or LED unit. In conclusion, previously placed dimethacrylate-based composites can be repaired with different light sources; however, if the composite to be repaired is silorane-based, then using a QTH or LED device may be the best option.
Compositional structure of the asteroid belt
NASA Technical Reports Server (NTRS)
Gradie, J.; Tedesco, E.
1982-01-01
A variety of observations, mainly albedos derived from 10 and 20 micron radiometry and eight-filter broadband spectrophotometry, were used to show that the asteroid belt is highly structured in composition. The bias-corrected distribution from 1.8 to 5.2 A.U. of the previously defined compositional types C,S,E,R, and M, plus type D and the newly described types F and P, are reported on. In terms of the relative abundances of the types discussed, the asteroid belt appears to be composed of at least six major compositionally distinct regions. The inferred composition of the asteroids in each semimajor axis region is consistent with the theory that the asteroids accreted from the solar nebula at or near their present location.
NASA Astrophysics Data System (ADS)
Hao, Wenfeng; Liu, Ye; Huang, Xinrong; Liu, Yinghua; Zhu, Jianguo
2018-06-01
In this work, the elastic constants of 3D four directional cylindrical braided composite shafts were predicted using analytical and numerical methods. First, the motion rule of yarn carrier of 3D four directional cylindrical braided composite shafts was analyzed, and the horizontal projection of yarn motion trajectory was obtained. Then, the geometry models of unit-cells with different braiding angles and fiber volume contents were built up, and the meso-scale models of 3D cylindrical braided composite shafts were obtained. Finally, the effects of braiding angles and fiber volume contents on the elastic constants of 3D braided composite shafts were analyzed theoretically and numerically. These results play a crucial role in investigating the mechanical properties of 3D 4-directional braided composites shafts.
Bone mineral density and body composition of the United States Olympic women's field hockey team
Sparling, P. B.; Snow, T. K.; Rosskopf, L. B.; O'Donnell, E. M.; Freedson, P. S.; Byrnes, W. C.
1998-01-01
OBJECTIVE: To evaluate total bone mineral density (BMD) and body composition (% fat) in world class women field hockey players, members of the 1996 United States Olympic team. METHODS: Whole body BMD (g/cm2) and relative body fatness (% fat) were assessed by dual energy x ray absorptiometry using a Lunar DPX-L unit with software version 1.3z. Body composition was also estimated by hydrostatic weighing and the sum of seven skinfolds. Results: Mean (SD) BMD was 1.253 (0.048) g/cm2 which is 113.2 (4.0)% of age and weight adjusted norms. Estimates of body composition from the three methods were similar (statistically non- significant): 16.1 (4.4)% fat from dual energy x ray absorptiometry, 17.6 (3.2)% from hydrostatic weighing, and 16.9 (2.6)% from the sum of seven skinfolds. Mean fat free mass was approximately 50 kg. CONCLUSIONS: The mean whole body BMD value for members of the 1996 United States Olympic women's field hockey team is one of the highest reported for any women's sports team. Moreover, the mean fat free mass per unit height was quite high and % fat was low. In this group of world class sportswomen, low % fat was not associated with low BMD. PMID:9865404
Uniting Generations through Children's Story Books
ERIC Educational Resources Information Center
Chowdhary, Usha
2004-01-01
This study examined the role of children's story books in uniting generations. Thematic similarities and distinctions depicted in 101 children's story books on intergenerational linkages were examined. They utilized five categories: caring and sharing, fun with grandparents, depiction of multicultural families, relationship with non-relatives, and…
Distinct Habitats Select Particular Bacterial Communities in Mangrove Sediments.
Rocha, Lidianne L; Colares, Geórgia B; Nogueira, Vanessa L R; Paes, Fernanda A; Melo, Vânia M M
2016-01-01
We investigated the relationship among environmental variables, composition, and structure of bacterial communities in different habitats in a mangrove located nearby to an oil exploitation area, aiming to retrieve the natural pattern of bacterial communities in this ecosystem. The T-RFLP analysis showed a high diversity of bacterial populations and an increase in the bacterial richness from habitats closer to the sea and without vegetation (S1) to habitats covered by Avicennia schaueriana (S2) and Rhizophora mangle (S3). Environmental variables in S1 and S2 were more similar than in S3; however, when comparing the bacterial compositions, S2 and S3 shared more OTUs between them, suggesting that the presence of vegetation is an important factor in shaping these bacterial communities. In silico analyses of the fragments revealed a high diversity of the class Gammaproteobacteria in the 3 sites, although in general they presented quite different bacterial composition, which is probably shaped by the specificities of each habitat. This study shows that microhabitats inside of a mangrove ecosystem harbor diverse and distinct microbiota, reinforcing the need to conserve these ecosystems as a whole.
Distinct Habitats Select Particular Bacterial Communities in Mangrove Sediments
Rocha, Lidianne L.; Colares, Geórgia B.; Nogueira, Vanessa L. R.; Paes, Fernanda A.; Melo, Vânia M. M.
2016-01-01
We investigated the relationship among environmental variables, composition, and structure of bacterial communities in different habitats in a mangrove located nearby to an oil exploitation area, aiming to retrieve the natural pattern of bacterial communities in this ecosystem. The T-RFLP analysis showed a high diversity of bacterial populations and an increase in the bacterial richness from habitats closer to the sea and without vegetation (S1) to habitats covered by Avicennia schaueriana (S2) and Rhizophora mangle (S3). Environmental variables in S1 and S2 were more similar than in S3; however, when comparing the bacterial compositions, S2 and S3 shared more OTUs between them, suggesting that the presence of vegetation is an important factor in shaping these bacterial communities. In silico analyses of the fragments revealed a high diversity of the class Gammaproteobacteria in the 3 sites, although in general they presented quite different bacterial composition, which is probably shaped by the specificities of each habitat. This study shows that microhabitats inside of a mangrove ecosystem harbor diverse and distinct microbiota, reinforcing the need to conserve these ecosystems as a whole. PMID:26989418
NASA Astrophysics Data System (ADS)
Simoes Pereira, P.; van de Flierdt, T.; Hillenbrand, C. D.; Hemming, S. R.; Kuhn, G.
2017-12-01
The West Antarctic Ice Sheet (WAIS) plays a key role in the global climate system and its collapse could contribute up to 4.3 m of sea-level rise. Mass loss of this marine-based ice sheet is largely caused by ocean-driven melting of ice shelves. This is confimed by modern observational data which show significant glacier thinning and retreat of grounding lines, particularly in the Amundsen Sea area. We here apply an integrated approach to determine provenance of marine sediments, which enables us to trace erosion of different bedrock lithologies, ultimately tied to the location of the eroding ice through time. We present provenance analysis on detrital Holocene seafloor sediments from the Amundsen Sea Embayment as well as from two marine cores PS58/254 (69°19´S, 108°27´W) and PC493 (71°09´S, 119°57´W), located on the continental rise of the Amundsen Sea and covering glacial-interglacial cycles of the past 800 kyrs. We use strontium (Sr) and neodymium (Nd) isotopic compositions of fine terrigenous grains (<63μm), and 40Ar/39Ar ages on ice-rafted (>150μm) hornblende and biotite grains. Our Holocene mapping results reveal drainage pathways with distinct signatures in the eastern and western Amundsen Sea Embayment. The western embayment records a homogenous provenance signature, pointing to a local source area in the hinterland, while the eastern embayment shows a range of compositions indicating erosion of the eastern coastal margin and a distinct, but unexposed source lithology under Pine Island Glacier and/or its drainage basin. Systematic isotope variations are detected between glacial and interglacial stages in both downcore records. Core PS58/254 exhibits a radiogenic fingerprint throughout the Late Pleistocene and systematic glacial-interglacial fluctuations in the order of three ɛNd units. They correlate with physical properties of the sediments (i.e. magnetic susceptibility) and trend towards lower values during interglacials, notably during Marine Isotope Stage (MIS) 5 and MIS 7. Core PC493 exhibits similar radiogenic Nd isotope composition, but a slightly reduced magnitude of glacial-interglacial changes. Detailed analysis of our results will offer a framework for interpreting sediment records from the area, including those from a recent MeBo expedition (PS104) and upcoming IODP expedition 379.
NASA Astrophysics Data System (ADS)
Manalilkada Sasidharan, S.; Dash, P.; Singh, S.; Lu, Y.
2017-12-01
The objective of this research was to quantify the effects of photodegradation and biodegradation on the dissolved organic matter (DOM) concentration and composition in five distinct waterbodies with diverse types of watershed land use and land cover in the southeastern United States. The water bodies included an agricultural pond, a lake in a predominantly forested watershed, a man-made reservoir, an estuary, and a bay. Two sets of samples were prepared from these water bodies by dispensing filtered water samples to unfiltered samples in 10:1 ratio. The first set was kept in the sunlight during the day (12 hours), and colored dissolved organic matter (CDOM) absorption and fluorescence were measured periodically over a 30-day period for examining the effects of combined photo- and biodegradation. The second set of samples was kept in the dark for examining the effects of biodegradation alone, and CDOM absorption and fluorescence were measured at the same time as the sunlight-exposed samples. Subsequently, spectrometric results in tandem with multivariate statistical analysis were used to interpret the lability vs. composition of DOM. Parallel factor analysis (PARAFAC) revealed the presence of four DOM components (C1-C4). C1 and C4 were microbial tryptophan-like, labile lighter components, while C2 and C3 were terrestrial humic like or fulvic acid type, larger aromatic refractory components. The principal component analysis (PCA) also revealed two distinct groups of DOM - C1 and C4 vs. C2 and C3. The negative PC1 loadings of C2, C3, HIX, a254 and SUVA indicated humic-like or fulvic-like structurally complex refractory aromatic DOM originated from higher plants in forested areas. C1, C4, SR, FI and BI had positive PC1 loadings, which indicated structurally simpler labile DOM were derived from agricultural areas or microbial activity. There was a decrease in dissolved organic carbon (DOC) due to combined photo- and biodegradation, and transformation of components C2, C3 into components C1, C4 was at a much faster rate than only biodegradation. This observation suggests that the presence of sunlight facilitated the degradation of larger, recalcitrant, terrestrial humic-like compounds into smaller, labile microbial components.
Distinct Fibroblasts in the Papillary and Reticular Dermis: Implications for Wound Healing.
Woodley, David T
2017-01-01
Human skin wounds heal largely by reparative wound healing rather than regenerative wound healing. Human skin wounds heal with scarring and without pilosebaceous units or other appendages. Dermal fibroblasts come from 2 distinct lineages of cells that have distinct cell markers and, more importantly, distinct functional abilities. Human skin wound healing largely involves the dermal fibroblast lineage from the reticular dermis and not the papillary dermis. If scientists could find a way to stimulate the dermal fibroblast lineages from the papillary dermis in early wound healing, perhaps human skin wounds could heal without scarring and with skin appendages. Copyright © 2016 Elsevier Inc. All rights reserved.
2013-01-01
Background Amblyomma cajennense F. is one of the best known and studied ticks in the New World because of its very wide distribution, its economical importance as pest of domestic ungulates, and its association with a variety of animal and human pathogens. Recent observations, however, have challenged the taxonomic status of this tick and indicated that intraspecific cryptic speciation might be occurring. In the present study, we investigate the evolutionary and demographic history of this tick and examine its genetic structure based on the analyses of three mitochondrial (12SrDNA, d-loop, and COII) and one nuclear (ITS2) genes. Because A. cajennense is characterized by a typical trans-Amazonian distribution, lineage divergence dating is also performed to establish whether genetic diversity can be linked to dated vicariant events which shaped the topology of the Neotropics. Results Total evidence analyses of the concatenated mtDNA and nuclear + mtDNA datasets resulted in well-resolved and fully congruent reconstructions of the relationships within A. cajennense. The phylogenetic analyses consistently found A. cajennense to be monophyletic and to be separated into six genetic units defined by mutually exclusive haplotype compositions and habitat associations. Also, genetic divergence values showed that these lineages are as distinct from each other as recognized separate species of the same genus. The six clades are deeply split and node dating indicates that they started diverging in the middle-late Miocene. Conclusions Behavioral differences and the results of laboratory cross-breeding experiments had already indicated that A. cajennense might be a complex of distinct taxonomic units. The combined and congruent mitochondrial and nuclear genetic evidence from this study reveals that A. cajennense is an assembly of six distinct species which have evolved separately from each other since at least 13.2 million years ago (Mya) in the earliest and 3.3 Mya in the latest lineages. The temporal and spatial diversification modes of the six lineages overlap the phylogeographical history of other organisms with similar extant trans-Amazonian distributions and are consistent with the present prevailing hypothesis that Neotropical diversity often finds its origins in the Miocene, after the Andean uplift changed the topology and consequently the climate and ecology of the Neotropics. PMID:24320199
Rogers, A.D.; Fergason, R.L.
2011-01-01
The compositional, thermophysical and geologic characteristics of surface units in Iapygia and Tyrrhena Terra (60??E-100??E, 0??-30??S) provide new insights into the compositional stratigraphy of the region. Intercrater plains are dominated by two surface units. The older unit (unit 1) is deficient in olivine and more degraded and likely consists of a mixture of impact, volcanic and sedimentary materials. The younger unit (unit 2) is enriched in olivine, exhibits a resistant morphology and higher thermal inertia, and likely represents volcanic infilling of plains. Units 1 and 2 bear a strong resemblance to those previously mapped in Mare Serpentis, a section of highlands crust located northwest of Hellas Basin. Thus, the two major intercrater plains units are even more widespread than previously thought and therefore likely constitute important components of Mars' highland stratigraphy. Many craters in the region contain high thermal inertia deposits (unit 3) that are compositionally identical to unit 2. These may have formed via volcanic infilling or may represent sedimentary materials that have been eroded from crater walls and lithified. Less common units include olivine and/or pyroxene-rich massifs and crater central peaks. These are primarily found within Hellas Basin rim units and may represent mantle materials brought toward the surface during the Hellas impact. Putative chloride deposits are primarily associated with olivine-deficient surfaces (unit 1) that may be heavily degraded occurrences of unit 2. The observations raise a variety of questions related to Martian crustal evolution and alteration that may have more widespread implications outside the study region. Copyright ?? 2011 by the American Geophysical Union.
Rogers, A. Deanne; Fergason, Robin L.
2011-01-01
The compositional, thermophysical and geologic characteristics of surface units in Iapygia and Tyrrhena Terra (60°E-100°E, 0°-30°S) provide new insights into the compositional stratigraphy of the region. Intercrater plains are dominated by two surface units. The older unit (unit 1) is deficient in olivine and more degraded and likely consists of a mixture of impact, volcanic and sedimentary materials. The younger unit (unit 2) is enriched in olivine, exhibits a resistant morphology and higher thermal inertia, and likely represents volcanic infilling of plains. Units 1 and 2 bear a strong resemblance to those previously mapped in Mare Serpentis, a section of highlands crust located northwest of Hellas Basin. Thus, the two major intercrater plains units are even more widespread than previously thought and therefore likely constitute important components of Mars' highland stratigraphy. Many craters in the region contain high thermal inertia deposits (unit 3) that are compositionally identical to unit 2. These may have formed via volcanic infilling or may represent sedimentary materials that have been eroded from crater walls and lithified. Less common units include olivine and/or pyroxene-rich massifs and crater central peaks. These are primarily found within Hellas Basin rim units and may represent mantle materials brought toward the surface during the Hellas impact. Putative chloride deposits are primarily associated with olivine-deficient surfaces (unit 1) that may be heavily degraded occurrences of unit 2. The observations raise a variety of questions related to Martian crustal evolution and alteration that may have more widespread implications outside the study region.
Katz, B.G.; Bullen, T.D.
1996-01-01
The hydrochemical interaction between groundwater and lakewater influences the composition of water that percolates downward from the surficial aquifer system through the underlying intermediate confining unit and recharges the Upper Floridan aquifer along highlands in Florida. The 87Sr/86Sr ratio along with the stable isotopes, D, 18O, and 13C were used as tracers to study the interaction between groundwater, lakewater, and aquifer minerals near Lake Barco, a seepage lake in the mantled karst terrane of northern Florida. Upgradient from the lake, the 87Sr/86Sr ratio of groundwater decreases with depth (mean values of 0.71004, 0.70890, and 0.70852 for water from the surficial aquifer system, intermediate confining unit, and Upper Floridan aquifer, respectively), resulting from the interaction of dilute oxygenated recharge water with aquifer minerals that are less radiogenic with depth. The concentrations of Sr2+ generally increase with depth, and higher concentrations of Sr2+ in water from the Upper Floridan aquifer (20-35 ??g/L), relative to water from the surficial aquifer system and the intermediate confining unit, result from the dissolution of Sr-bearing calcite and dolomite in the Eocene limestone. Dissolution of calcite [??13C = -1.6 permil (???)] is also indicated by an enriched ??13CDIC (-8.8 to - 11.4???) in water from the Upper Floridan aquifer, relative to the overlying hydrogeologic units (??13CDIC < - 16???). Groundwater downgradient from Lake Barco was enriched in 18O and D relative to groundwater upgradient from the lake, indicating mixing of lakewater leakage and groundwater. Downgradient from the lake, the 87Sr/86Sr ratio of groundwater and aquifer material become less radiogenic and the Sr2+ concentrations generally increase with depth. However, Sr2+ concentrations are substantially less than in upgradient groundwaters at similar depths. The lower Sr2+ concentrations result from the influence of anoxic lakewater leakage on the mobility of Sr2+ from clays. Based on results from mass-balance modeling, it is probable that cation exchange plays the dominant role in controlling the 87Sr/86Sr ratio of groundwater, both upgradient and downgradient from Lake Barco. Even though groundwater from the three distinct hydrogeologic units displays considerable variability in Sr concentration and isotopic composition, the dominant processes associated with the mixing of lakewater leakage with groundwater, as well as the effects of mineral-water interaction, can be ascertained by integrating the use of stable and radiogenic isotopic measurements of groundwater, lakewater, and aquifer minerals.
NASA Astrophysics Data System (ADS)
Li, Qian; Zhao, Kui-Dong; Lai, Pan-Chen; Jiang, Shao-Yong; Chen, Wei
2018-01-01
The giant Yanbei tin ore deposit is the largest porphyry-type tin deposit in South China. The orebodies are hosted by the granite porphyry in the central part of the Yanbei volcanic basin in southern Jiangxi Province. The Yanbei volcanic-intrusive complex mainly consists of dacitic-rhyolitic volcanic rocks, granite, granite porphyry and diabase dikes. In previous papers, the granite porphyry was considered as subvolcanic rocks, which came from the same single magma chamber with the volcanic rocks. In this study, zircon U-Pb ages and Hf isotope data, as well as whole-rock geochemical and Sr-Nd isotopic compositions of different magmatic units in the Yanbei complex are reported. Geochronologic results show that various magmatic units have different formation ages. The dacite yielded a zircon U-Pb age of 143 ± 1 Ma, and the granite porphyry has the emplacement age of 138 ± 1 Ma. Diabase dikes which represented the final stage of magmatism, yielded a zircon U-Pb age of 128 ± 1 Ma. Distinctive whole rock Sr-Nd and zircon Hf isotopic compositions suggest that these magmatic units were derived from different magma sources. The volcanic rocks were mainly derived from the partial melting of Paleoproterozoic metasedimentary rocks without additions of mantle-derived magma. The granite porphyry has an A-type geochemical affinity, and was derived from remelting of Paleo-Mesoproterozoic crustal source with involvement of a subordinate mantle-derived magma. The granite porphyry is also a typical stanniferous granite with high F (4070-6090 ppm) and Sn (7-39 ppm) contents. It underwent strongly crystal fractionation of plagioclase, K-feldspar, and accessory minerals (like apatite, Fe-Ti oxides), which may contribute to the tin mineralization. The diabase was derived by partial melting of enriched lithospheric mantle which had been metasomatised by slab-derived fluids. The change of magmatic sources reflected an increasing extensional tectonic environment, perhaps induced by slab rollback of subducted paleo-Pacific plate.
ERIC Educational Resources Information Center
Goldburg, Maxine E.
2012-01-01
Learner-centered methodology like peer review is problematic in the pluralism of the ESL classroom when teaching academic English composition. A distinct complication is the form writing instruction should take given the interaction and variations between ESL students' L1 background, experiences, schema, and the meaning of academic literacy in…
REMOTE RAMAN SPECTROSCOPY OF VARIOUS MIXED AND COMPOSITE MINERAL PHASES AT 7.2 m DISTANCE
NASA Technical Reports Server (NTRS)
Sharma, S. K.; Misra, A. K.; Ismail, Syed; Singh, U. N.
2006-01-01
Remote Raman [e.g.,1-5] and micro-Raman spectroscopy [e.g., 6-10] are being evaluated on geological samples for their potential applications on Mars rover or lander. The Raman lines of minerals are sharp and distinct. The Raman finger-prints of minerals do not shift appreciably but remain distinct even in sub-micron grains and, therefore, can be used for mineral identification in fine-grained rocks [e.g., 4,7]. In this work we have evaluated the capability of a directly coupled remote Raman system (co-axial configuration) for distinguishing the mineralogy of multiple crystals in the exciting laser beam. We have measured the Raman spectra of minerals in the near vicinity of each other and excited with a laser beam (e.g. -quartz (Qz) and K-feldspar (Feld) plates, each 5 mm thick). The spectra of composite transparent mineral plates of 5 mm thickness of -quartz and gypsum over calcite crystal were measured with the composite samples perpendicular to the exciting laser beam. The measurements of remote Raman spectra of various bulk minerals, and mixed and composite minerals with our portable UH remote Raman system were carried out at the Langley Research Center in a fully illuminated laboratory.
MacLea, Kyle S.; Paul, Kacy R.; Ben-Musa, Zobaida; Waechter, Aubrey; Shattuck, Jenifer E.; Gruca, Margaret
2014-01-01
Multiple yeast prions have been identified that result from the structural conversion of proteins into a self-propagating amyloid form. Amyloid-based prion activity in yeast requires a series of discrete steps. First, the prion protein must form an amyloid nucleus that can recruit and structurally convert additional soluble proteins. Subsequently, maintenance of the prion during cell division requires fragmentation of these aggregates to create new heritable propagons. For the Saccharomyces cerevisiae prion protein Sup35, these different activities are encoded by different regions of the Sup35 prion domain. An N-terminal glutamine/asparagine-rich nucleation domain is required for nucleation and fiber growth, while an adjacent oligopeptide repeat domain is largely dispensable for prion nucleation and fiber growth but is required for chaperone-dependent prion maintenance. Although prion activity of glutamine/asparagine-rich proteins is predominantly determined by amino acid composition, the nucleation and oligopeptide repeat domains of Sup35 have distinct compositional requirements. Here, we quantitatively define these compositional requirements in vivo. We show that aromatic residues strongly promote both prion formation and chaperone-dependent prion maintenance. In contrast, nonaromatic hydrophobic residues strongly promote prion formation but inhibit prion propagation. These results provide insight into why some aggregation-prone proteins are unable to propagate as prions. PMID:25547291
ERIC Educational Resources Information Center
Woodward, Jerry
2016-01-01
This study examined how a child constructed a scheme (abbreviated QRE) for producing mathematical equivalence via operations on composite units between two multiplicative situations consisting of singletons and composite units. Within the context of a teaching experiment, the work of one child, Joe, was analyzed over the course of 14 teaching…
Different types of crude oil and refined product, of all different chemical compositions, have distinct physical properties. These properties affect the way oil spreads and breaks down, its hazard to marine and human life, and the likelihood of threat.
Nonlinearities in the Evolutional Distinctions Between El Niño and La Niña Types
NASA Astrophysics Data System (ADS)
Ashok, K.; Shamal, M.; Sahai, A. K.; Swapna, P.
2017-12-01
Using the HadISST, SODA reanalysis, and various other observed and reanalyzed data sets for the period 1950-2010, we explore nonlinearities in the subsurface evolutional distinctions between El Niño types and La Niña types from a few seasons before the onset. Cluster analysis carried out over both summer and winter suggests that while the warm-phased events of both types are distinguishable, several cold phased events are clustered together. Further, we apply a joint Self-Organizing Map (SOM) analysis using the monthly sea surface temperature anomaly (SSTA) and thermocline-depth anomalies in tropical Pacific (TP). Results reveal that the evolutionary paths of El Niño Modoki (EM) and El Niño (EL) are, broadly, different. Subsurface temperature composites of EL and EM show different onset characteristics. During an EL, warm anomaly in the west spreads eastward along the thermocline and reaches the surface in the east in March-May of year(0). During an EM, warm anomaly already exists in the central tropical Pacific and then reaches the surface in the east in September-November of year(0). Composited SSTAs during La Niña (LN) and La Niña Modoki (LM) are distinguishable only at 80% confidence level, but the composited subsurface temperature anomalies show differences in the location of the coldest anomaly as well as evolution at 90% confidence level. Thus, the El Niño flavor distinction is potentially predictable at longer leads.
Impact of inhomogeneity on SH-type wave propagation in an initially stressed composite structure
NASA Astrophysics Data System (ADS)
Saha, S.; Chattopadhyay, A.; Singh, A. K.
2018-02-01
The present analysis has been made on the influence of distinct form of inhomogeneity in a composite structure comprised of double superficial layers lying over a half-space, on the phase velocity of SH-type wave propagating through it. Propagation of SH-type wave in the said structure has been examined in four distinct cases of inhomogeneity viz. when inhomogeneity in double superficial layer is due to exponential variation in density only (Case I); when inhomogeneity in double superficial layers is due to exponential variation in rigidity only (Case II); when inhomogeneity in double superficial layer is due to exponential variation in rigidity, density and initial stress (Case III) and when inhomogeneity in double superficial layer is due to linear variation in rigidity, density and initial stress (Case IV). Closed-form expression of dispersion relation has been accomplished for all four aforementioned cases through extensive application of Debye asymptotic analysis. Deduced dispersion relations for all the cases are found in well-agreement to the classical Love-wave equation. Numerical computation has been carried out to graphically demonstrate the effect of inhomogeneity parameters, initial stress parameters as well as width ratio associated with double superficial layers in the composite structure for each of the four aforesaid cases on dispersion curve. Meticulous examination of distinct cases of inhomogeneity and initial stress in context of considered problem has been carried out with detailed analysis in a comparative approach.
Onuki, Yoshinori; Obata, Yasuko; Kawano, Kumi; Sano, Hiromu; Matsumoto, Reina; Hayashi, Yoshihiro; Takayama, Kozo
2016-02-01
The purpose of this study is to obtain a comprehensive relationship between membrane microdomain structures of liposomes and their cellular uptake efficiency. Model liposomes consisting of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC)/1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC)/cholesterol (Ch) were prepared with various lipid compositions. To detect distinct membrane microdomains in the liposomes, fluorescence-quenching assays were performed at temperatures ranging from 25 to 60 °C using 1,6-diphenyl-1,3,5-hexatriene-labeled liposomes and (2,2,6,6-tetramethylpiperidin-1-yl)oxyl. From the data analysis using the response surface method, we gained a better understanding of the conditions for forming distinct domains (Lo, Ld, and gel phase membranes) as a function of lipid composition. We further performed self-organizing maps (SOM) clustering to simplify the complicated behavior of the domain formation to obtain its essence. As a result, DPPC/DOPC/Ch liposomes in any lipid composition were integrated into five distinct clusters in terms of similarity of the domain structure. In addition, the findings from synchrotron small-angle X-ray scattering analysis offered further insight into the domain structures. As a last phase of this study, an in vitro cellular uptake study using HeLa cells was conducted using SOM clusters' liposomes with/without PEGylation. As a consequence of this study, higher cellular uptake was observed from liposomes having Ch-rich ordered domains.
Kang, Wen-Bin; He, Chuan; Liu, Zhen-Xing; Wang, Jun; Wang, Wei
2018-05-16
Previous studies based on bioinformatics showed that there is a sharp distinction of structural features and residue composition between the intrinsically disordered proteins and the folded proteins. What induces such a composition-related structural transition? How do various kinds of interactions work in such processes? In this work, we investigate these problems based on a survey on peptides randomly composed of charged residues (including glutamic acids and lysines) and the residues with different hydrophobicity, such as alanines, glycines, or phenylalanines. Based on simulations using all-atom model and replica-exchange Monte Carlo method, a coil-globule transition is observed for each peptide. The corresponding transition temperature is found to be dependent on the contents of the hydrophobic and charged residues. For several cases, when the mean hydrophobicity is larger than a certain threshold, the transition temperature is higher than the room temperature, and vise versa. These thresholds of hydrophobicity and net charge are quantitatively consistent with the border line observed from the study of bioinformatics. These results outline the basic physical reasons for the compositional distinction between the intrinsically disordered proteins and the folded proteins. Furthermore, the contributions of various interactions to the structural variation of peptides are analyzed based on the contact statistics and the charge-pattern dependence of the gyration radii of the peptides. Our observations imply that the hydrophobicity contributes essentially to such composition-related transitions. Thus, we achieve a better understanding on composition-structure relation of the natural proteins and the underlying physics.
A guide to structural factors for advanced composites used on spacecraft
NASA Technical Reports Server (NTRS)
Vanwagenen, Robert
1989-01-01
The use of composite materials in spacecraft systems is constantly increasing. Although the areas of composite design and fabrication are maturing, they remain distinct from the same activities performed using conventional materials and processes. This has led to some confusion regarding the precise meaning of the term 'factor of safety' as it applies to these structures. In addition, composite engineering introduces terms such as 'knock-down factors' to further modify material properties for design purposes. This guide is intended to clarify these terms as well as their use in the design of composite structures for spacecraft. It is particularly intended to be used by the engineering community not involved in the day-to-day composites design process. An attempt is also made to explain the wide range of factors of safety encountered in composite designs as well as their relationship to the 1.4 factor of safety conventionally applied to metallic structures.
Caste-specific differences in hindgut microbial communities of honey bees (Apis mellifera).
Kapheim, Karen M; Rao, Vikyath D; Yeoman, Carl J; Wilson, Brenda A; White, Bryan A; Goldenfeld, Nigel; Robinson, Gene E
2015-01-01
Host-symbiont dynamics are known to influence host phenotype, but their role in social behavior has yet to be investigated. Variation in life history across honey bee (Apis mellifera) castes may influence community composition of gut symbionts, which may in turn influence caste phenotypes. We investigated the relationship between host-symbiont dynamics and social behavior by characterizing the hindgut microbiome among distinct honey bee castes: queens, males and two types of workers, nurses and foragers. Despite a shared hive environment and mouth-to-mouth food transfer among nestmates, we detected separation among gut microbiomes of queens, workers, and males. Gut microbiomes of nurses and foragers were similar to previously characterized honey bee worker microbiomes and to each other, despite differences in diet, activity, and exposure to the external environment. Queen microbiomes were enriched for bacteria that may enhance metabolic conversion of energy from food to egg production. We propose that the two types of workers, which have the highest diversity of operational taxonomic units (OTUs) of bacteria, are central to the maintenance of the colony microbiome. Foragers may introduce new strains of bacteria to the colony from the environment and transfer them to nurses, who filter and distribute them to the rest of the colony. Our results support the idea that host-symbiont dynamics influence microbiome composition and, reciprocally, host social behavior.
Diversity and Biogeography of Bathyal and Abyssal Seafloor Bacteria
Bienhold, Christina; Zinger, Lucie; Boetius, Antje; Ramette, Alban
2016-01-01
The deep ocean floor covers more than 60% of the Earth’s surface, and hosts diverse bacterial communities with important functions in carbon and nutrient cycles. The identification of key bacterial members remains a challenge and their patterns of distribution in seafloor sediment yet remain poorly described. Previous studies were either regionally restricted or included few deep-sea sediments, and did not specifically test biogeographic patterns across the vast oligotrophic bathyal and abyssal seafloor. Here we define the composition of this deep seafloor microbiome by describing those bacterial operational taxonomic units (OTU) that are specifically associated with deep-sea surface sediments at water depths ranging from 1000–5300 m. We show that the microbiome of the surface seafloor is distinct from the subsurface seafloor. The cosmopolitan bacterial OTU were affiliated with the clades JTB255 (class Gammaproteobacteria, order Xanthomonadales) and OM1 (Actinobacteria, order Acidimicrobiales), comprising 21% and 7% of their respective clades, and about 1% of all sequences in the study. Overall, few sequence-abundant bacterial types were globally dispersed and displayed positive range-abundance relationships. Most bacterial populations were rare and exhibited a high degree of endemism, explaining the substantial differences in community composition observed over large spatial scales. Despite the relative physicochemical uniformity of deep-sea sediments, we identified indicators of productivity regimes, especially sediment organic matter content, as factors significantly associated with changes in bacterial community structure across the globe. PMID:26814838
NASA Technical Reports Server (NTRS)
Dymek, R. F.; Boak, J. L.; Gromet, L. P.
1983-01-01
Rare earth element (REE) data is given on a set of clastic metasediments from the 3800 Ma Isua Supracrustal belt, West Greenland. Each of two units from the same sedimentary sequence has a distinctive REE pattern, but the average of these rocks bears a very strong resemblance to the REE pattern for the North American Shale Composite (NASC), and departs considerably from previous estimates of REE patterns in Archaean sediments. The possibility that the source area for the Isua sediments resembled that of the NASC is regarded as highly unlikely. However, REE patterns like that in the NASC may be produced by sedimentary recycling of material yielding patterns such as are found at Isua. The results lead to the following tentative conclusions: (1) The REE patterns for Isua Seq. B MBG indicate the existence of crustal materials with fractionated REE and negative Eu anomalies at 3800 Ma, (2) The average Seq. B REE pattern resembles that of the North American Shale Composite (NASC), (3) If the Seq. B average is truly representative of its crustal sources, then this early crust could have been extensively differentiated. In this regard, a proper understanding of the NASC pattern, and its relationship to post-Archaean crustal REE reservoirs, is essential, (4) The Isua results may represent a local effect.
Du, Can; Geng, Zengchao; Wang, Qiang; Zhang, Tongtong; He, Wenxiang; Hou, Lin; Wang, Yueling
2017-09-01
Microbial communities in subsurface soil are specialized for their environment, which is distinct from that of the surface communities. However, little is known about the microbial communities (bacteria and fungi) that exist in the deeper soil horizons. Vertical changes in microbial alpha-diversity (Chao1 and Shannon indices) and community composition were investigated at four soil depths (0-10, 10-20, 20-40, and 40-60 cm) in a natural secondary forest of Betula albosinensis by high-throughput sequencing of the 16S and internal transcribed spacer rDNA regions. The numbers of operational taxonomic units (OTUs), and the Chao1 and Shannon indices decreased in the deeper soil layers. Each soil layer contained both mutual and specific OTUs. In the 40-60 cm soil layer, 175 and 235 specific bacterial and fungal OTUs were identified, respectively. Acidobacteria was the most dominant bacterial group in all four soil layers, but reached its maximum at 40-60 cm (62.88%). In particular, the 40-60 cm soil layer typically showed the highest abundance of the fungal genus Inocybe (47.46%). The Chao1 and Shannon indices were significantly correlated with the soil organic carbon content. Redundancy analysis indicated that the bacterial communities were closely correlated with soil organic carbon content (P = 0.001). Collectively, these results indicate that soil nutrients alter the microbial diversity and relative abundance and affect the microbial composition.
Teaching Linear Measurement Concepts. . .K to 6
ERIC Educational Resources Information Center
Norrie, A. L.
1974-01-01
Three distinct, but overlapping, stages in measurement are identified as intuitive thinking, logical thinking, and formal operations. Three types of representation are body units, non-standard, and standard units. Instructional sequences and activities are suggested for grades 1-3 and grades 4-6 based on these considerations. (LS)
Intercultural Communication Problems in Japanese Multinationals.
ERIC Educational Resources Information Center
Nishiyama, Kazuo
Many large Japanese-owned multinational corporations have established successful subsidiaries in the United States, but distinct ethnic and cultural differences have caused communication problems between Japanese managers and American laborers and business people. Many top executives of the Japanese subsidiaries are sent to the United States on a…
75 FR 75475 - Agency Information Collection Activities: Proposed Collection; Comment Request
Federal Register 2010, 2011, 2012, 2013, 2014
2010-12-03
... collection; Title of Information Collection: Psychiatric Unit Criteria Work Sheet and Supporting Regulations... section 1886(d)(1)(B) of the Social Security Act. That section excludes psychiatric hospitals... (children's hospitals), and psychiatric and rehabilitation units which are a distinct part of a hospital...
Developing Curriculum for Canadian Schools: What We Learned from the Atlantic Salmon
ERIC Educational Resources Information Center
Anderson, Gary J.; And Others
1977-01-01
The process of developing a distinctively Canadian junior high school curriculum unit integrating subject content of history, science, and geography around a common theme is discussed. The unit focuses on the life cycle and environment of the Atlantic Salmon, Salmo salar. (MJB)
NASA Astrophysics Data System (ADS)
Zhou, Ping; Barkhaus, Paul E.; Zhang, Xu; Zev Rymer, William
2011-10-01
This paper presents a novel application of the approximate entropy (ApEn) measurement for characterizing spontaneous motor unit activity of amyotrophic lateral sclerosis (ALS) patients. High-density surface electromyography (EMG) was used to record spontaneous motor unit activity bilaterally from the thenar muscles of nine ALS subjects. Three distinct patterns of spontaneous motor unit activity (sporadic spikes, tonic spikes and high-frequency repetitive spikes) were observed. For each pattern, complexity was characterized by calculating the ApEn values of the representative signal segments. A sliding window over each segment was also introduced to quantify the dynamic changes in complexity for the different spontaneous motor unit patterns. We found that the ApEn values for the sporadic spikes were the highest, while those of the high-frequency repetitive spikes were the lowest. There is a significant difference in mean ApEn values between two arbitrary groups of the three spontaneous motor unit patterns (P < 0.001). The dynamic ApEn curve from the sliding window analysis is capable of tracking variations in EMG activity, thus providing a vivid, distinctive description for different patterns of spontaneous motor unit action potentials in terms of their complexity. These findings expand the existing knowledge of spontaneous motor unit activity in ALS beyond what was previously obtained using conventional linear methods such as firing rate or inter-spike interval statistics.
ERIC Educational Resources Information Center
Aisenbrey, Silke; Evertsson, Marie; Grunow, Daniela
2009-01-01
This article focuses on three countries with distinct policies toward motherhood and work: Germany, Sweden and the United States. We analyze the length of mothers' time out of paid work after childbirth and the short-term career consequences for mothers. In the United States, we identify a career punishment even for short time-out periods; long…
du Bray, Edward A.; Pallister, John S.; Snee, Lawrence W.
2004-01-01
Middle Tertiary volcanic rocks of the central Chiricahua Mountains in southeast Arizona are the westernmost constituents of the Eocene-Oligocene Boot Heel volcanic field of southwestern New Mexico and southeastern Arizona. About two dozen volumetric ally and stratigraphically significant volcanic units are present in this area. These include large-volume, regionally distributed ash-flow tuffs and smaller volume, locally distributed lava flows. The most voluminous of these units is the Rhyolite Canyon Tuff, which erupted 26.9 million years ago from the Turkey Creek caldera in the central Chiricahua Mountains. The Rhyolite Canyon Tuff consists of 500-1,000 cubic kilometers of rhyolite that was erupted from a normally zoned reservoir. The tuff represents sequential eruptions, which became systematically less geochemically evolved with time, from progressively deeper levels of the source reservoir. Like the Rhyolite Canyon Tuff, other ashflow tuffs preserved in the central Chiricahua Mountains have equivalents in nearby, though isolated mountain ranges. However, correlation of these other tuffs, from range to range, has been hindered by stratigraphic discontinuity, structural complexity, and various lithologic similarities and ambiguities. New geochemical and geochronologic data presented here enable correlation of these units between their occurrences in the central Chiricahua Mountains and the remainder of the Boot Heel volcanic field. Volcanic rocks in the central Chiricahua Mountains are composed dominantly of weakly peraluminous, high-silica rhyolite welded tuff and rhyolite lavas of the high-potassium and shoshonitic series. Trace-element, and to a lesser extent, major-oxide abundances are distinct for most of the units studied. Geochemical and geochronologic data depict a time and spatial transgression from subduction to within-plate and extensional tectonic settings. Compositions of the lavas tend to be relatively homogeneous within particular units. In contrast, compositions of the ash-flow tuffs, including the Rhyolite Canyon Tuff, vary significantly owing to eruption from compositionally zoned reservoirs. Reservoir zonation is consistent with fractional crystallization of observed phenocryst phases and resulting residual liquid compositional evolution. Rhyolite lavas preserved in the moat of the Turkey Creek caldera depict compositional zonation that is the reverse of that expected of magma extraction from progressively deeper parts of a normally zoned reservoir. Presuming that the source reservoir was sequentially tapped from its top downward, development of reverse zonation in the rhyolite lava sequence may indicate that later erupted, more evolved magma contains systematically less wallrock contamination derived from the geochemically primitive margins of its incompletely mixed reservoir. New 40Ar/39Ar geochronology data indicate that the principal middle Tertiary volcanic rocks in the central Chiricahua Mountains were erupted between about 34.2 and 26.2 Ma, and that the 5.2 m.y. period between 33.3 and 28.1 Ma was amagmatic. The initial phase of eruptive activity in the central Chiricahua Mountains, between 34.2 and 33.3 Ma, was associated with a regional tectonic regime dominated by subduction along the west edge of North America. We infer that the magmatic hiatus, nearly simultaneous with a hiatus of similar duration in parts of the Boot Heel volcanic field east of the central Chiricahua Mountains, is related to a period of more rapid convergence and therefore shallower subduction that may have displaced subduction-related magmatic activity to a position east of the present-day Boot Heel volcanic field. The hiatus also coincides with a major plate tectonic reorganization along the west edge of North America that resulted in cessation of subduction and initiation of transform faulting along the San Andreas fault. The final period of magmatism in the central Chiricahua Mountains, between 28.1 and 23.2 Ma, ap
NASA Astrophysics Data System (ADS)
Quantin-Nataf, Cathy; Carter, John; Thollot, Patrick; Loizeau, Damien; Davis, Joel; Grindrod, Peter; lozach, Loic
2017-04-01
The ExoMars 2018 mission (ESA) has for scientific objectives to search for signs of past and present life on Mars, to investigate the water/geochemical environment as a function of depth in the shallow subsurface, to study to Martian atmospheric trace gases and to characterize the surface environment. The landing site has to be relevant with regard to these objectives while fitting the restrictive engineering constrains. From the scientific point of view, the site must be ancient, from the Early Mars period, for which many scientific evidences favor the existence of a water-related cycle. In this paper, we present the unique location called Oxia Planum, a wide clay bearing plain located between 16° and 19° North and -23° to -28° East proposed as landing site for Exomars 2020 mission. Oxia Planum is located between Ares Vallis and Marwth Vallis in a wide basin just at the outlet of Cogoon Vallis System, with elevations ranging from -2800 m down to -3100 m. The regional compositional mapping of Oxia planum has been achieved based on OMEGA data at 2.5 km/pix well as CRISM multispectral data at 200 m/pix. Mg/Fe phyllosilicates, identified and mapped based on their diagnostic absorptions at 1.4, 1.9 and 2.3 µm are exposed over about 80% of the ellipse surface. The entire unit with phyllosilicates signatures corresponds to a light-toned layered unit that is observed over a large range of elevations (from -2600 m to -3100m) suggesting that like in Marwth Vallis region, the layered and altered formation overlaps a pre-existing topography . The age returned from crater count on the clay rich formation is 3.9 Ga. At the top or embedded within the layered formation, several fluvial morphologies such as former valleys or inverted channels are observed. Also, at the top of the layered clay-rich formation, a deltaic deposit is observed suggesting sub-aqueous episodes postdating the altered layered formation. In terms of mineralogy, the putative delta fan shows layers enriched in hydrated silica. This delta fan implies a second and distinct period of alteration in Oxia Planum signed by a distinct mineralogy. In term of age, the delta has a too small surface to allow a confident age assignment from crater count. We can only state that the delta-fan is older than 3.5 Ga. Oxia Planum recorded at least two clearly distinct alteration environments and contexts: 1) the alteration of the Noachian layers and 2) the fluvio-deltaic system post-dating the Noachian clay rich unit. Deciphering the formation environments for such diverse altered rocks would fulfill the goals of the ExoMars Rover.
Acquisition of equipment for composite manufacturing laboratory.
DOT National Transportation Integrated Search
2009-12-01
An interdisciplinary team of faculty was formed to upgrade the Composite Manufacturing and Testing Facilities at Missouri S&T. The Metering Unit is useful to manufacture composite pultruded parts using two part polyurethane resin system. Prior to the...
Hierarchy of facies of pyroclastic flow deposits generated by Laacher See type eruptions
NASA Astrophysics Data System (ADS)
Freundt, A.; Schmincke, H.-U.
1985-04-01
The upper Quaternary pyroclastic flow deposits of Laacher See volcano show compositional and structural facies variations on four different scales: (1) eruptive units of pyroclastic flows, composed of many flow units; (2) depositional cycles of as many as five flow units; flow units containing (3) regional intraflow-unit facies; and (4) local intraflow-unit subfacies. These facies can be explained by successively overlapping processes beginning in the magma column and ending with final deposition. The pyroclastic flow deposits thus reflect major aspects of the eruptive history of Laacher See volcano: (a) drastic changes in eruptive mechanism due to increasing access of water to the magma chamber and (b) change in chemical composition and crystal and gas content as evacuation of a compositionally zoned magma column progressed. The four scales of facies result from four successive sets of processes: (1) differentiation in the magma column and external factors governing the mechanism of eruption; (2) temporal variations of factors inducing eruption column collapse; (3) physical conditions in the eruption column and the way in which its collapse proceeds; and (4) interplay of flow-inherent and morphology-induced transport mechanics.
Investigation of Micro-Scale Architectural Effects on Damage of Composites
NASA Technical Reports Server (NTRS)
Stier, Bertram; Bednarcyk, Brett A.; Simon, Jaan W.; Reese, Stefanie
2015-01-01
This paper presents a three-dimensional, energy based, anisotropic, stiffness reduction, progressive damage model for composite materials and composite material constituents. The model has been implemented as a user-defined constitutive model within the Abaqus finite element software package and applied to simulate the nonlinear behavior of a damaging epoxy matrix within a unidirectional composite material. Three different composite microstructures were considered as finite element repeating unit cells, with appropriate periodicity conditions applied at the boundaries. Results representing predicted transverse tensile, longitudinal shear, and transverse shear stress-strain curves are presented, along with plots of the local fields indicating the damage progression within the microstructure. It is demonstrated that the damage model functions appropriately at the matrix scale, enabling localization of the damage to simulate failure of the composite material. The influence of the repeating unit cell geometry and the effect of the directionality of the applied loading are investigated and discussed.
A comparative study of the fatty acid composition of prochloron lipids
NASA Technical Reports Server (NTRS)
Kenrick, J. R.; Deane, E. M.; Bishop, D. G.
1983-01-01
The chemical analysis of lipids of Prochloron isolated from several hosts is discussed. The object was to determine whether differences in lipid composition could be used to characterize organisms from different sources. Major lipid components are given. An analysis of fatty acid composition of individual lipids slowed a distinctive disstribution of fatty acids. While present results do not justify the use of fatty acid content in the taxonomy of Prochlon, the variations found in the lipids of cells from the same host harvested from different areas, or at different times in the same area, suggest that a study of the effects of temperature and light intensity on lipid composition would be rewarding.
Oxygen Isotopic Analyses of Water Extracted from the Martian Meteorite NWA 7034
NASA Astrophysics Data System (ADS)
Nunn, M.; Agee, C. B.; Thiemens, M. H.
2012-12-01
Introduction: The NWA 7034 meteorite has been identified as Martian, but it is distinct from the Shergottite-Nakhlite-Chassignite (SNC) grouping of meteorites in its petrology (it is the only known Martian basaltic breccia) and bulk silicate oxygen isotopic composition (Δ17O = 0.56 ± 0.06 ‰, where Δ17O = δ17O - 0.528 x δ18O, compared to the average SNC Δ17O ≈ 0.3 ‰) [e.g., 1-2]. We report here measurements of the oxygen isotopic composition of water extracted from NWA 7034 by stepwise heating. Methods: A piece (~1.2g) of NWA 7034 was pumped to vacuum until outgassing had stopped before heating to 50, 150, 320, 500, and 1000°C. The sample was maintained at each temperature step for at least one hour while collecting evolved volatiles in a liquid nitrogen cold trap. Water was selectively converted to molecular oxygen, the oxygen isotopic composition of which was then measured on a double collecting isotope ratio mass spectrometer. Results: Our stepwise heating experiments indicate NWA 7034 contains 3330ppm water, and this water has an average oxygen isotopic composition of Δ17O = 0.330 ± 0.011‰. The oxygen isotopic composition of water in NWA 7034 is unlike that of the silicates from which it is extracted (Δ17O = 0.56 ± 0.06 ‰) but is comparable to the average SNC silicate composition (Δ17O ≈ 0.3 ‰). However, there is no consensus on the oxygen isotopic composition of water in SNCs because aliquots of water extracted from different samples (separate pieces of a single meteorite or from different meteorites) have different oxygen isotopic compositions [3]. Furthermore, carbonates and sulfates extracted from SNCs also possess distinct oxygen isotopic compositions [4]. The variation in oxygen isotopic composition among these phases most likely results from the existence of isotopically distinct oxygen reservoirs on Mars that were not equilibrated. On Earth, interaction of ozone (O3) and carbon dioxide (CO2) leads to a mass independent oxygen isotopic composition of atmospheric CO2 [5]. This anomaly is transferred by exchange from CO2 to water and subsequently to secondary minerals. The much larger CO2 to water ratio on Mars could allow this process to introduce a measurable oxygen isotopic anomaly to sulfates, carbonates, and water. The magnitude and variability of this anomaly would depend on the formation mechanism of the species (particularly the source of oxygen), as is consistent with measurements to date of phases in SNCs. References: [1] Franchi, I.A., et al. (1999) MAPS 34, 657-661. [2] Rumble, D. and Irving, A.J. (2009) LPSC XXXX, #2293 [3] Karlsson, H.R., et al. (1992) Science 255, 1409-1411. [4] Farquhar, J. and Thiemens, M.H. (2000) J. Geophys. Res. 105, 11991-11997. [5] Yung, Y.L., et al. (1991) Geophys. Res. Lett. 18, 13-16.
Genetic loci simultaneously controlling lignin monomers and biomass digestibility of rice straw.
Hu, Zhen; Zhang, Guifen; Muhammad, Ali; Samad, Rana Abdul; Wang, Youmei; Walton, Jonathan D; He, Yuqing; Peng, Liangcai; Wang, Lingqiang
2018-02-26
Lignin content and composition are crucial factors affecting biomass digestibility. Exploring the genetic loci simultaneously affecting lignin-relevant traits and biomass digestibility is a precondition for lignin genetic manipulation towards energy crop breeding. In this study, a high-throughput platform was employed to assay the lignin content, lignin composition and biomass enzymatic digestibility of a rice recombinant inbred line population. Correlation analysis indicated that the absolute content of lignin monomers rather than lignin content had negative effects on biomass saccharification, whereas the relative content of p-hydroxyphenyl unit and the molar ratio of p-hydroxyphenyl unit to guaiacyl unit exhibited positive roles. Eight QTL clusters were identified and four of them affecting both lignin composition and biomass digestibility. The additive effects of clustered QTL revealed consistent relationships between lignin-relevant traits and biomass digestibility. Pyramiding rice lines containing the above four positive alleles for increasing biomass digestibility were selected and showed comparable lignin content, decreased syringyl or guaiacyl unit and increased molar percentage of p-hydroxyphenyl unit, the molar ratio of p-hydroxyphenyl unit to guaiacyl unit and sugar releases. More importantly, the lodging resistance and eating/cooking quality of pyramiding lines were not sacrificed, indicating the QTL information could be applied to select desirable energy rice lines.
24 CFR 983.259 - Overcrowded, under-occupied, and accessible units.
Code of Federal Regulations, 2010 CFR
2010-04-01
...-occupied, and accessible units. (a) Family occupancy of wrong-size or accessible unit. The PHA subsidy standards determine the appropriate unit size for the family size and composition. If the PHA determines that a family is occupying a: (1) Wrong-size unit, or (2) Unit with accessibility features that the...
Steven, Blaire; Kuske, Cheryl R; Gallegos-Graves, La Verne; Reed, Sasha C; Belnap, Jayne
2015-11-01
Biological soil crusts (biocrusts) colonize plant interspaces in many drylands and are critical to soil nutrient cycling. Multiple climate change and land use factors have been shown to detrimentally impact biocrusts on a macroscopic (i.e., visual) scale. However, the impact of these perturbations on the bacterial components of the biocrusts remains poorly understood. We employed multiple long-term field experiments to assess the impacts of chronic physical (foot trampling) and climatic changes (2°C soil warming, altered summer precipitation [wetting], and combined warming and wetting) on biocrust bacterial biomass, composition, and metabolic profile. The biocrust bacterial communities adopted distinct states based on the mechanism of disturbance. Chronic trampling decreased biomass and caused small community compositional changes. Soil warming had little effect on biocrust biomass or composition, while wetting resulted in an increase in the cyanobacterial biomass and altered bacterial composition. Warming combined with wetting dramatically altered bacterial composition and decreased Cyanobacteria abundance. Shotgun metagenomic sequencing identified four functional gene categories that differed in relative abundance among the manipulations, suggesting that climate and land use changes affected soil bacterial functional potential. This study illustrates that different types of biocrust disturbance damage biocrusts in macroscopically similar ways, but they differentially impact the resident soil bacterial communities, and the communities' functional profiles can differ depending on the disturbance type. Therefore, the nature of the perturbation and the microbial response are important considerations for management and restoration of drylands. Copyright © 2015, American Society for Microbiology. All Rights Reserved.
Steven, Blaire; Kuske, Cheryl R.; Gallegos-Graves, La Verne; Reed, Sasha C.; Belnap, Jayne
2015-01-01
Biological soil crusts (biocrusts) colonize plant interspaces in many drylands and are critical to soil nutrient cycling. Multiple climate change and land use factors have been shown to detrimentally impact biocrusts on a macroscopic (i.e., visual) scale. However, the impact of these perturbations on the bacterial components of the biocrusts remain poorly understood. We employed multiple long-term field experiments to assess the impacts of chronic physical (foot trampling) and climatic changes (2 °C soil warming, altered summer precipitation (wetting), and combined warming and wetting) on biocrust bacterial biomass, composition, and metabolic profile. The biocrust bacterial communities adopted distinct states based on the mechanism of disturbance. Chronic trampling decreased biomass and caused small community compositional change. Soil warming had little effect on biocrust biomass or composition, while wetting resulted in an increase in cyanobacterial biomass and altered bacterial composition. Warming combined with wetting dramatically altered bacterial composition and decreased cyanobacteria abundance. Shotgun metagenomic sequencing identified four functional gene categories that differed in relative abundance among the manipulations, suggesting that climate and land use changes affected soil bacterial functional potential. This study illustrates that different types of biocrust disturbance damage biocrusts in macroscopically similar ways, but they differentially impact the resident soil bacterial communities and the community functional profile can differ depending on the disturbance type. Therefore, the nature of the perturbation and the microbial response are important considerations for management and restoration of drylands.
Casewell, Nicholas R.; Wagstaff, Simon C.; Wüster, Wolfgang; Cook, Darren A. N.; Bolton, Fiona M. S.; King, Sarah I.; Pla, Davinia; Sanz, Libia; Calvete, Juan J.; Harrison, Robert A.
2014-01-01
Variation in venom composition is a ubiquitous phenomenon in snakes and occurs both interspecifically and intraspecifically. Venom variation can have severe outcomes for snakebite victims by rendering the specific antibodies found in antivenoms ineffective against heterologous toxins found in different venoms. The rapid evolutionary expansion of different toxin-encoding gene families in different snake lineages is widely perceived as the main cause of venom variation. However, this view is simplistic and disregards the understudied influence that processes acting on gene transcription and translation may have on the production of the venom proteome. Here, we assess the venom composition of six related viperid snakes and compare interspecific changes in the number of toxin genes, their transcription in the venom gland, and their translation into proteins secreted in venom. Our results reveal that multiple levels of regulation are responsible for generating variation in venom composition between related snake species. We demonstrate that differential levels of toxin transcription, translation, and their posttranslational modification have a substantial impact upon the resulting venom protein mixture. Notably, these processes act to varying extents on different toxin paralogs found in different snakes and are therefore likely to be as important as ancestral gene duplication events for generating compositionally distinct venom proteomes. Our results suggest that these processes may also contribute to altering the toxicity of snake venoms, and we demonstrate how this variability can undermine the treatment of a neglected tropical disease, snakebite. PMID:24927555
Casewell, Nicholas R; Wagstaff, Simon C; Wüster, Wolfgang; Cook, Darren A N; Bolton, Fiona M S; King, Sarah I; Pla, Davinia; Sanz, Libia; Calvete, Juan J; Harrison, Robert A
2014-06-24
Variation in venom composition is a ubiquitous phenomenon in snakes and occurs both interspecifically and intraspecifically. Venom variation can have severe outcomes for snakebite victims by rendering the specific antibodies found in antivenoms ineffective against heterologous toxins found in different venoms. The rapid evolutionary expansion of different toxin-encoding gene families in different snake lineages is widely perceived as the main cause of venom variation. However, this view is simplistic and disregards the understudied influence that processes acting on gene transcription and translation may have on the production of the venom proteome. Here, we assess the venom composition of six related viperid snakes and compare interspecific changes in the number of toxin genes, their transcription in the venom gland, and their translation into proteins secreted in venom. Our results reveal that multiple levels of regulation are responsible for generating variation in venom composition between related snake species. We demonstrate that differential levels of toxin transcription, translation, and their posttranslational modification have a substantial impact upon the resulting venom protein mixture. Notably, these processes act to varying extents on different toxin paralogs found in different snakes and are therefore likely to be as important as ancestral gene duplication events for generating compositionally distinct venom proteomes. Our results suggest that these processes may also contribute to altering the toxicity of snake venoms, and we demonstrate how this variability can undermine the treatment of a neglected tropical disease, snakebite.
Miranda, Melissa; Pino, Ana María; Fuenzalida, Karen; Rosen, Clifford J.; Seitz, Germán; Rodríguez, J. Pablo
2016-01-01
Bone marrow adipose tissue (BMAT) is associated with low bone mass, although the functional consequences for skeletal maintenance of increased BMAT are currently unclear. BMAT might have a role in systemic energy metabolism, and could be an energy source as well as an endocrine organ for neighboring bone cells, releasing cytokines, adipokines and free fatty acids into the bone marrow microenvironment. The aim of the present report was to compare the fatty acid composition in the bone marrow supernatant fluid (BMSF) and blood plasma of postmenopausal women women (65 to 80 years old). BMSF was obtained after spinning the aspirated bone marrow samples; donors were classified as control, osteopenic or osteoporotic after dual-energy X-ray absorptiometry. Total lipids from human bone marrow fluid and plasma were extracted, converted to the corresponding methyl esters, and finally analyzed by a gas chromatographer coupled with a mass spectrometer. Results showed that fatty acid composition in BMSF was dynamic and distinct from blood plasma, implying significance in the locally produced lipids. The fatty acid composition in the BMSF was enriched in saturated fatty acid and decreased in unsaturated fatty acids as compared to blood plasma, but this relationship switched in women who suffered a hip fracture. On the other hand, there was no relationship between BMSF and bone mineral density. In conclusion, lipid composition of BMSF is distinct from the circulatory compartment, most likely reflecting the energy needs of the marrow compartment. PMID:27416518
Mechanical and Thermal Properties of Dental Composites Cured with CAD/CAM Assisted Solid-State Laser
De Santis, Roberto; Gloria, Antonio; Maietta, Saverio; Martorelli, Massimo; De Luca, Alessandro; Spagnuolo, Gianrico; Riccitiello, Francesco; Rengo, Sandro
2018-01-01
Over the last three decades, it has been frequently reported that the properties of dental restorative composites cured with argon laser are similar or superior to those achieved with conventional halogen and light emitting diode (LED) curing units. Whereas laser curing is not dependent on the distance between the curing unit and the material, such distance represents a drawback for conventional curing units. However, a widespread clinical application of this kind of laser remains difficult due to cost, heavy weight, and bulky size. Recently, with regard to the radiation in the blue region of the spectrum, powerful solid-state lasers have been commercialized. In the current research, CAD (computer-aided design)/CAM (computer-aided manufacturing) assisted solid-state lasers were employed for curing of different dental restorative composites consisting of micro- and nanoparticle-reinforced materials based on acrylic resins. Commercial LED curing units were used as a control. Temperature rise during the photopolymerisation process and bending properties were measured. By providing similar light energy dose, no significant difference in temperature rise was observed when the two light sources provided similar intensity. In addition, after 7 days since curing, bending properties of composites cured with laser and LED were similar. The results suggested that this kind of laser would be suitable for curing dental composites, and the curing process does not suffer from the tip-to-tooth distance. PMID:29584683
NASA Astrophysics Data System (ADS)
Brossier, J. F.; Stephan, K.; Jaumann, R.; Le Mouelic, S.; Brown, R. H.
2015-12-01
Since the equatorial regions of Titan have been fully observed by the Visible and Infrared Mapping Spectrometer (VIMS) [1], the analysis of false-color composite allows distinguishing three mains units: bright, bluish and brownish units [2-4]. This distinction can be enhanced by using ratios of VIMS channels that allow emphasizing subtle difference of spectral behavior of the units, especially at short wavelengths (below 2 µm). The VIMS - bluish unit is mostly enriched in water-ice particles, which consist of particles exposition derived from the high standing water-ice substrate and deposited on the lowlands after fluvial/pluvial processes [5] and impact [6]. This spectral unit is mainly located at the frontier of the large bright plateaus, and hence considered as a transition zone to the VIMS - brownish unit corresponding to the Radar dune-fields [7]. Whereas these brownish dunes consist on atmospheric aerosols, named tholins [4] contaminated with particles of water ice. High resolution observations of VIMS (less than 1 km per pixel), show local transition zones between the bright material and the brownish dunes, suggesting weathering and erosional processes (e.g. Bohai Sinus and the Huygens Landing site). The reason of these spectral variations in this bluish unit might be due to physical properties variations related to erosional processes occurring on the bright plateaus [5,8], such as particles sizes and the degree of mixture with tholins. Our approach enables a better understanding of the distribution of the water-ice grains in terms of particles-size and mixtures with tholins at local and global scale. Reference: [1] Brown, R. H. et al. (2005) SSR. [2] Barnes, J. W. et al. (2007) Icarus, 186 (1). [3] Soderblom, L. A. et al. (2007) PSS, 55 (13). [4] Langhans, M. H. et al. (2011) PSS, 60. [5] Jaumann, R. et al. (2008) Icarus, 197. [6] Le Mouelic, S. et al. (2008) JGR, 113 (E04003). [7] Rodriguez, S. et al. (2013) Icarus. [8] Jaumann, R. et al. (2009) LPSC.
Areal Crater Density Analysis of Volcanic Smooth Plains: A New Approach to Distinguishing Age Units
NASA Astrophysics Data System (ADS)
Ostrach, L. R.; Robinson, M. S.
2013-12-01
It is well documented that the lunar maria were emplaced over an extended period of time [e.g., 1-3], and mare units exhibit significant color differences in multispectral data that are interpreted to correlate with distinct mineralogical compositions and ages [e.g., 3-7]. Areal crater density (ACD) analysis is used as a novel approach to identify resurfacing boundaries within Mare Imbrium as a test case for mercurian studies. Absolute model age dating and measures of ACD from crater counts on Lunar Reconnaissance Orbiter Wide Angle Camera (LRO WAC) mosaics reveal two spatially expansive, statistically separable units in Mare Imbrium. The older, spectrally red unit (~15-18 wt% FeO, ~2-5 wt% TiO2 [8]) in the east is ~3.3 Ga, and the younger, spectrally blue unit (~17-20 wt% FeO, ~7-10 wt% TiO2 [8]) in the west is ~2.2 Ga. ACD measurements show a regional boundary at the contact between these two regions. The geologic contact is confidently observed in ACD maps derived for regions with model age differences >300-500 million years and spatial extents >1 × 104 km2. The older, spectrally red unit exhibits higher ACD (>35000 craters with diameters ≥500 m per 106 km2) and the younger, spectrally blue unit has a lower ACD (<26000 craters with diameters ≥500 m per 106 km2); the absolute model ages and ACD results agree with other dating studies of this region [5, 9-12]. Thus, ACD measurements provide a reliable technique to distinguish relative ages among geologic units as well as a means to explore the statistical significance of published absolute model ages. Moreover, the ability to distinguish surface units of different ages from measures of crater frequencies in Mare Imbrium, when spectral information is not available or units do not exhibit spectral contrasts, shows that the ACD technique may be applied to other planetary bodies to search for age boundaries within contiguous smooth plains units. For example, multispectral differences within volcanic units (age and composition) are not observed on Mercury [e.g., 13-15], so the ACD method can be used to test hypotheses concerning timing of smooth plains emplacement [15]. [1] Hartmann W.K. et al. (1981) In: BVTP, 1049-1127. [2] Stöffler D. et al. (2006) Rev. Mineral. Geochem, 60, 519-596. [3] Hiesinger H. et al. (2011) Spec. Pap. - Geol. Soc. Am, 477, 1-51. [4] Pieters C.M. (1978) Proc. Lunar Plan. Sci. Conf, 9th, 2825-2849. [5] Hiesinger H. et al. (2000) J. Geophys. Res, 105, 29239-29275. [6] Staid M.I. and C.M. Pieters (2001) J. Geophys. Res, 106, 27887-27900. [7] Staid M.I. et al. (2011) J. Geophys. Res, 116, E00G10. [8] Lucey P.G. et al. (2000) J. Geophys. Res, 105, 20297-20306. [9] Schaber G.G. (1973) In: Apollo 17 PSR, NASA SP-330, 30-17 to 30-25. [10] Schaber G.G. et al. (1975) The Moon, 13, 395-423. [11] Boyce J.M. and A.L. Dial Jr. (1975) Proc. Lunar Sci. Conf, 6th, 2585-2595. [12] Bugiolacchi R. and J.E. Guest (2008) Icarus, 197, 1-18. [13] Robinson M.S. et al. (2008) Science, 321, 66-69. [14] Denevi B.W. et al. (2009) Science, 324, 613-618. [15] Denevi B.W. et al. (2013) J. Geophys. Res, 118, 1-17.
Employability Skills Development in the United Kingdom.
ERIC Educational Resources Information Center
Turner, Dave
For the last 15 years, a series of policy initiatives have advocated for development of employability skills by young and unemployed people in the United Kingdom. The call for these employability skills has been championed by these two distinct but related movements: the Key Skills Development Movement (KSDM) and the Enterprising Skills…
National Culture-Management Practices: United States and Saudi Arabia Contrasted.
ERIC Educational Resources Information Center
Hashmi, Mahmud S.
Successful conduct of business in Saudi Arabia requires attitudes and skills significantly different from those needed in the United States. Distinct societal differences can turn winning practices in one culture into failures in another. Despite Saudi Arabia's recent emergence as a wealthy marketplace, traditional values and a unique lifestyle…
Participation in International Large-Scale Assessments from a US Perspective
ERIC Educational Resources Information Center
Plisko, Valena White
2013-01-01
International large-scale assessments (ILSAs) play a distinct role in the United States' decentralized federal education system. Separate from national and state assessments, they offer an external, objective measure for the United States to assess student performance comparatively with other countries and over time. The US engagement in ILSAs…
Profiles of Acculturative Adjustment Patterns among Chinese International Students
ERIC Educational Resources Information Center
Wang, Kenneth T.; Heppner, Puncky Paul; Fu, Chu-Chun; Zhao, Ran; Li, Feihan; Chuang, Chih-Chun
2012-01-01
This is the first study to empirically identify distinct acculturative adjustment patterns of new international students over their first 3 semesters in the United States. The sample consisted of 507 Chinese international students studying in the United States. Using psychological distress as an indicator of acculturative adjustment, measured over…
Hydrology, geomorphology, and vegetation of Coastal Plain rivers in the southeastern United States
Cliff R. Hupp
2000-01-01
Rivers of the Coastal Plain of the southeastern United States are characteristically low-gradient meandering systems that develop broad floodplains subjected to frequent and prolonged flooding. These floodplains support a relatively unique forested wetland (Bottomland Hardwoods), which have received considerable ecological study, but distinctly less hydrogeomorphic...
NASA Astrophysics Data System (ADS)
Varatharajan, Indhu; Srivastava, Neeraj; Murty, Sripada V. S.
2014-07-01
A comparative assessment of the mineralogy of young basalts (∼1.2 Ga to ∼2.8 Ga) from the western nearside, Moscoviense basin, and the Orientale basin of the Moon has been made using Level 2 Moon Mineralogy Mapper (M3) data from the Chandrayaan-1 mission. Spectral data characteristics of the individual units have been generated from fresh small craters to minimize the complications due to space weathering. Representative spectra for individual units and the derived spectral parameters (band centers and integrated band depth ratio) have been used to study composition of these young basalts. A modified approach of Gaffey et al. (Gaffey, M.J., Cloutis, E.A., Kelley, M.S., Reed, K.L. [2002]. Mineralogy of asteroids. In: Asteroids III. The University of Arizona Press, Tucson, pp. 183-204) (for olivine-pyroxene mixtures) and the methodology of Adams (Adams, J.B. [1974]. J. Geophys. Res. 79, 4829-4836. http://dx.doi.org/10.1029/JB079i032p04829) (for interpreting pyroxene type) have been used to improve our understanding of the spectral behavior of these basalts. Most of the young basalts of Oceanus Procellarum are characterized by abundant olivines and they show complex volcanic history. Vast exposures of olivine concentrated units having higher abundance of olivine content than high-Ca pyroxenes are emplaced in the northern Oceanus Procellarum region. Mostly, they show distinct stratigraphic gradation with the immediately underlying units of relatively lower olivine content. The Moscoviense unit shows signatures of Fe-rich glasses along with clinopyroxenes. The basalts of Orientale basin are typically devoid of olivine and are rich in high-Ca pyroxene. Thus, mineralogy of these mare basalts which erupted during the late stage volcanism vary across the Moon’s surface; however, broader observations reveal apparently higher FeO content in the younger basalts of western nearside and Orientale region.
Dubois, Carl-Ardy; D'amour, Danielle; Tchouaket, Eric; Clarke, Sean; Rivard, Michèle; Blais, Régis
2013-04-01
To examine the associations of four distinct nursing care organizational models with patient safety outcomes. Cross-sectional correlational study. Using a standardized protocol, patients' records were screened retrospectively to detect occurrences of patient safety-related events. Binary logistic regression was used to assess the associations of those events with four nursing care organizational models. Twenty-two medical units in 11 hospitals in Quebec, Canada, were clustered into 4 nursing care organizational models: 2 professional models and 2 functional models. Two thousand six hundred and ninety-nine were patients hospitalized for at least 48 h on the selected units. Composite of six safety-related events widely-considered sensitive to nursing care: medication administration errors, falls, pneumonia, urinary tract infection, unjustified restraints and pressure ulcers. Events were ultimately sorted into two categories: events 'without major' consequences for patients and events 'with' consequences. After controlling for patient characteristics, patient risk of experiencing one or more events (of any severity) and of experiencing an event with consequences was significantly lower, by factors of 25-52%, in both professional models than in the functional models. Event rates for both functional models were statistically indistinguishable from each other. Data suggest that nursing care organizational models characterized by contrasting staffing, work environment and innovation characteristics may be associated with differential risk for hospitalized patients. The two professional models, which draw mainly on registered nurses (RNs) to deliver nursing services and reflect stronger support for nurses' professional practice, were associated with lower risks than are the two functional models.
Mukherjea, Arnab; Morgan, Patricia A.; Snowden, Lonnie R.; Ling, Pamela M.; Ivey, Susan L.
2011-01-01
OBJECTIVE To explore and understand key cultural contexts of tobacco use among South Asian communities in the United States. DESIGN Focus groups, with homogenous compositions of gender, generational status, and length of time in the United States, were conducted in two distinct South Asian ethnic enclaves. Focus group findings were triangulated with observational data regarding availability of culturally-specific tobacco from commercial ethnic outlets and cultural events. SUBJECTS Respondents included 88 men and women of South Asian descent, aged 18 to 65 years, immigrant and native born, representing diversity of religion, socioeconomic status, and region of origin, with use of at least one culturally-specific tobacco product in previous 24 months. RESULTS A large number of culturally-specific products are commonly used by community members. Knowledge of product-specific health risks was lacking or inaccurate. Many culturally-specific tobacco products were considered to have beneficial properties. South Asian tobacco items were used to preserve cultural traditions and express ethnic identity in a new dominant culture. The social and cultural value ascribed to use helped distinguish community members from mainstream society and from other minority populations. CONCLUSIONS Many cultural factors govern tobacco use among diverse global populations. Especially for migrants with a common regional origin, the role of ethnic identity may strongly influence culturally-specific tobacco patterns. Qualitative inquiry helps elucidate such culturally-framed behaviors in culturally-diverse populations. These cultural contexts should be integrated into research and practice. Understanding multidimensional factors influencing non-traditional tobacco use is key to ensuring that comprehensive tobacco control strategies address tobacco-related disparities. PMID:21708814
Spectroscopy of SU(4) composite Higgs theory with two distinct fermion representations
NASA Astrophysics Data System (ADS)
Ayyar, Venkitesh; DeGrand, Thomas; Golterman, Maarten; Hackett, Daniel C.; Jay, William I.; Neil, Ethan T.; Shamir, Yigal; Svetitsky, Benjamin
2018-04-01
We have simulated the SU(4) lattice gauge theory coupled to dynamical fermions in the fundamental and two-index antisymmetric (sextet) representations simultaneously. Such theories arise naturally in the context of composite Higgs models that include a partially composite top quark. We describe the low-lying meson spectrum of the theory and fit the pseudoscalar masses and decay constants to chiral perturbation theory. We infer as well the mass and decay constant of the Goldstone boson corresponding to the nonanomalous U(1) symmetry of the model. Our results are broadly consistent with large-Nc scaling and vector-meson dominance.
NASA Technical Reports Server (NTRS)
Vilas, F.; Smith, B. A.
1985-01-01
The surface compositions of outer-belt asteroids were used to obtain information about the origin of these asteroids. High-resolution CCD reflectance spectra of 21 asteroids, primarily P class, were examined for compositional information. Distinct slope changes are observed that suggest that these asteroids are the remnants of a compositional gradation of planetesimals in the outer solar system, which were retained selectively in location when other material was ejected from the solar system. Other data suggest that this gradation could extend through the orbits of Uranus and Neptune.
The Control and Treatment of Narcotics Use. Parole Decision Making.
ERIC Educational Resources Information Center
Glaser, Daniel; O'Leary, Vincent
After a brief discussion of the physiological effects of drugs on the human body, seven distinctive features of drug usage in the United States since the start of World War II are noted, and initiation into drug usage is described. The notion of a distinct personality type of addicts is not favored since terms used to characterize the type are not…
ERIC Educational Resources Information Center
Kinney, Kelly; Girshin, Thomas; Bowlin, Barrett
2013-01-01
This review essay examines recent texts by Nancy Welch and Tony Scott, both of which use embodied activism as a starting point for their inquiries. Taken together, these works point to a distinct shift in composition studies' turn toward the social, one that calls on workers both within and outside the academy to actively engage in grassroots…
Optimization of Nickel Nanocomposite for Large Strain Sensing Applications
2011-01-01
piezoresistive response of the material. As part of this study the effect of the addition of a second conductive filler particle of a distinct length scale...corresponding increase in the overall conductivity of the composite. The composite conductivity is increased about an order of magnitude for each additional ...strain at which the mean resis - Fig. 10. Schematic representation of how εerr was calculated from the range of the volume resistivity for a given strain
Measurement of Thunderstorm Cloud-Top Parameters Using High-Frequency Satellite Imagery
1978-01-01
short wave was present well to the south of this system approximately 2000 ka west of Baja California. Two distinct flow patterns were present, one...view can be observed in near real time whereas radar observations, although excellent for local purposes, involve substantial errors when composited...on a large scale. The time delay in such large scale compositing is critical when attempting to monitor convective cloud systems for a potential
Wang, Yaqiong; Ma, Hong
2015-09-01
Proteins often function as complexes, yet little is known about the evolution of dissimilar subunits of complexes. DNA-directed RNA polymerases (RNAPs) are multisubunit complexes, with distinct eukaryotic types for different classes of transcripts. In addition to Pol I-III, common in eukaryotes, plants have Pol IV and V for epigenetic regulation. Some RNAP subunits are specific to one type, whereas other subunits are shared by multiple types. We have conducted extensive phylogenetic and sequence analyses, and have placed RNAP gene duplication events in land plant history, thereby reconstructing the subunit compositions of the novel RNAPs during land plant evolution. We found that Pol IV/V have experienced step-wise duplication and diversification of various subunits, with increasingly distinctive subunit compositions. Also, lineage-specific duplications have further increased RNAP complexity with distinct copies in different plant families and varying divergence for subunits of different RNAPs. Further, the largest subunits of Pol IV/V probably originated from a gene fusion in the ancestral land plants. We propose a framework of plant RNAP evolution, providing an excellent model for protein complex evolution. © 2015 The Authors. New Phytologist © 2015 New Phytologist Trust.
Purification of an eight subunit RNA polymerase I complex in Trypanosoma brucei.
Nguyen, Tu N; Schimanski, Bernd; Zahn, André; Klumpp, Birgit; Günzl, Arthur
2006-09-01
Trypanosoma brucei harbors a unique multifunctional RNA polymerase (pol) I which transcribes, in addition to ribosomal RNA genes, the gene units encoding the major cell surface antigens variant surface glycoprotein and procyclin. In consequence, this RNA pol I is recruited to three structurally different types of promoters and sequestered to two distinct nuclear locations, namely the nucleolus and the expression site body. This versatility may require parasite-specific protein-protein interactions, subunits or subunit domains. Thus far, data mining of trypanosomatid genomes have revealed 13 potential RNA pol I subunits which include two paralogous sets of RPB5, RPB6, and RPB10. Here, we analyzed a cDNA library prepared from procyclic insect form T. brucei and found that all 13 candidate subunits are co-expressed. Moreover, we PTP-tagged the largest subunit TbRPA1, tandem affinity-purified the enzyme complex to homogeneity, and determined its subunit composition. In addition to the already known subunits RPA1, RPA2, RPC40, 1RPB5, and RPA12, the complex contained RPC19, RPB8, and 1RPB10. Finally, to evaluate the absence of RPB6 in our purifications, we used a combination of epitope-tagging and reciprocal coimmunoprecipitation to demonstrate that 1RPB6 but not 2RPB6 binds to RNA pol I albeit in an unstable manner. Collectively, our data strongly suggest that T. brucei RNA pol I binds a distinct set of the RPB5, RPB6, and RPB10 paralogs.
Naficy, Cameron; Sala, Anna; Keeling, Eric G; Graham, Jon; DeLuca, Thomas H
2010-10-01
Increased forest density resulting from decades of fire exclusion is often perceived as the leading cause of historically aberrant, severe, contemporary wildfires and insect outbreaks documented in some fire-prone forests of the western United States. Based on this notion, current U.S. forest policy directs managers to reduce stand density and restore historical conditions in fire-excluded forests to help minimize high-severity disturbances. Historical logging, however, has also caused widespread change in forest vegetation conditions, but its long-term effects on vegetation structure and composition have never been adequately quantified. We document that fire-excluded ponderosa pine forests of the northern Rocky Mountains logged prior to 1960 have much higher average stand density, greater homogeneity of stand structure, more standing dead trees and increased abundance of fire-intolerant trees than paired fire-excluded, unlogged counterparts. Notably, the magnitude of the interactive effect of fire exclusion and historical logging substantially exceeds the effects of fire exclusion alone. These differences suggest that historically logged sites are more prone to severe wildfires and insect outbreaks than unlogged, fire-excluded forests and should be considered a high priority for fuels reduction treatments. Furthermore, we propose that ponderosa pine forests with these distinct management histories likely require distinct restoration approaches. We also highlight potential long-term risks of mechanical stand manipulation in unlogged forests and emphasize the need for a long-term view of fuels management.
PERIODIC CLASSIFICATION AND THE PROUST LAW (in French)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rinck, E.; Feschotte, P.
1962-04-01
Progress realized in the knowledge of the solid state has permitted the identification of numerous crystalline phases whose composition was not defined in the meaning of the Proust law. Its rigorous validity has nevertheless served as a beginning for atomic theory; it continues to be utilized in the measurement of atomic weights and remains valid for the vast region of organic chemistry. The investigation of the limits of the validity of the Proust law leads to some peculiarities of the metallic state which are closely connected to the periodic classification of elements. A new arrangement of the periodic table, permittingmore » for the first time the integration of the rare earths and giving to hydrogen a very special place, takes into consideration a distinction between true metals and earth metals. This distinction is imposed by the fact that the Proust law, valid for compounds between metalloids and earth metals, is not always followed when these same metalloids unite with true metals. Finally. this law loses all significance in alloys between true metals. The exceptions to this rule are explained by the specialization of chemical properties which is shown when one passes from short periods to long periods, hydrogen and the metals with short period being considered as undifferentiated elements. The usage of a point of view borrowed from embryology permits, thus, the chemical and even the physical properties of these elements to be better connected. (tr-auth)« less
Yoshida, Takashi; Monk, Kevin J.; Katz, Donald B.
2013-01-01
The taste of foods, in particular the palatability of these tastes, exerts a powerful influence on our feeding choices. Although the lateral hypothalamus (LH) has long been known to regulate feeding behavior, taste processing in LH remains relatively understudied. Here, we examined single-unit LH responses in rats subjected to a battery of taste stimuli that differed in both chemical composition and palatability. Like neurons in cortex and amygdala, LH neurons produced a brief epoch of nonspecific responses followed by a protracted period of taste-specific firing. Unlike in cortex, however, where palatability-related information only appears 500 ms after the onset of taste-specific firing, taste specificity in LH was dominated by palatability-related firing, consistent with LH's role as a feeding center. Upon closer inspection, taste-specific LH neurons fell reliably into one of two subtypes: the first type showed a reliable affinity for palatable tastes, low spontaneous firing rates, phasic responses, and relatively narrow tuning; the second type showed strongest modulation to aversive tastes, high spontaneous firing rates, protracted responses, and broader tuning. Although neurons producing both types of responses were found within the same regions of LH, cross-correlation analyses suggest that they may participate in distinct functional networks. Our data shed light on the implementation of palatability processing both within LH and throughout the taste circuit, and may ultimately have implications for LH's role in the formation and maintenance of taste preferences and aversions. PMID:23719813
Li, Jennifer X; Yoshida, Takashi; Monk, Kevin J; Katz, Donald B
2013-05-29
The taste of foods, in particular the palatability of these tastes, exerts a powerful influence on our feeding choices. Although the lateral hypothalamus (LH) has long been known to regulate feeding behavior, taste processing in LH remains relatively understudied. Here, we examined single-unit LH responses in rats subjected to a battery of taste stimuli that differed in both chemical composition and palatability. Like neurons in cortex and amygdala, LH neurons produced a brief epoch of nonspecific responses followed by a protracted period of taste-specific firing. Unlike in cortex, however, where palatability-related information only appears 500 ms after the onset of taste-specific firing, taste specificity in LH was dominated by palatability-related firing, consistent with LH's role as a feeding center. Upon closer inspection, taste-specific LH neurons fell reliably into one of two subtypes: the first type showed a reliable affinity for palatable tastes, low spontaneous firing rates, phasic responses, and relatively narrow tuning; the second type showed strongest modulation to aversive tastes, high spontaneous firing rates, protracted responses, and broader tuning. Although neurons producing both types of responses were found within the same regions of LH, cross-correlation analyses suggest that they may participate in distinct functional networks. Our data shed light on the implementation of palatability processing both within LH and throughout the taste circuit, and may ultimately have implications for LH's role in the formation and maintenance of taste preferences and aversions.
Process for Making Carbon-Carbon Turbocharger Housing Unit for Intermittent Combustion Engines
NASA Technical Reports Server (NTRS)
Northam, G. Burton (Inventor); Ransone, Philip O. (Inventor); Rivers, H. Kevin (Inventor)
1999-01-01
An improved. lightweight, turbine housing unit for an intermittent combustion reciprocating internal combustion engine turbocharger is prepared from a lay-up or molding of carbon-carbon composite materials in a single-piece or two-piece process. When compared to conventional steel or cast iron, the use of carbon-carbon composite materials in a turbine housing unit reduces the overall weight of the engine and reduces the heat energy loss used in the turbo-charging process. This reduction in heat energy loss and weight reduction provides for more efficient engine operation.
Carbon-Carbon Turbocharger Housing Unit for Intermittent Combustion Engines
NASA Technical Reports Server (NTRS)
Northam, G. Burton (Inventor); Ransone, Philip O. (Inventor); Rivers, H. Kevin (Inventor)
1998-01-01
An improved, lightweight, turbine housing unit for an intermittent combustion reciprocating internal combustion engine turbocharger is prepared from a lay-up or molding of carbon-carbon composite materials in a single-piece or two-piece process. When compared to conventional steel or cast iron, the use of carbon-carbon composite materials in a turbine housing unit reduces the overall weight of the engine and reduces the heat energy loss used in the turbocharging process. This reduction in heat energy loss and weight reduction provides for more efficient engine operation.
Søgaard, K; Christensen, H; Fallentin, N; Mizuno, M; Quistorff, B; Sjøgaard, G
1998-10-01
Muscle activity was recorded from the flexor carpi radialis muscle during static and dynamic-concentric wrist flexion in six subjects, who had exhibited large differences in histochemically identified muscle fibre composition. Motor unit recruitment patterns were identified by sampling 310 motor units and counting firing rates in pulses per second (pps). During concentric wrist flexion at 30% of maximal exercise intensity the mean firing rate was 27 (SD 13) pps. This was around twice the value of 12 (SD 5) pps recorded during sustained static contraction at 30% of maximal voluntary contraction, despite a larger absolute force level during the static contraction. A similar pattern of higher firing rates during dynamic exercise was seen when concentric wrist flexion at 60% of maximal exercise intensity [30 (SD 14) pps] was compared with sustained static contraction at 60% of maximal voluntary contraction [19 (SD 8) pps]. The increase in dynamic exercise intensity was accomplished by recruitment of additional motor units rather than by increasing the firing rate as during static contractions. No difference in mean firing rates was found among subjects with different muscle fibre composition, who had previously exhibited marked differences in metabolic response during corresponding dynamic contractions. It was concluded that during submaximal dynamic contractions motor unit firing rate cannot be deduced from observations during static contractions and that muscle fibre composition may play a minor role.
Influence of light curing and sample thickness on microhardness of a composite resin
Aguiar, Flávio HB; Andrade, Kelly RM; Leite Lima, Débora AN; Ambrosano, Gláucia MB; Lovadino, José R
2009-01-01
The aim of this in vitro study was to evaluate the influence of light-curing units and different sample thicknesses on the microhardness of a composite resin. Composite resin specimens were randomly prepared and assigned to nine experimental groups (n = 5): considering three light-curing units (conventional quartz tungsten halogen [QTH]: 550 mW/cm2 – 20 s; high irradiance QTH: 1160 mW/cm2 – 10 s; and light-emitting diode [LED]: 360 mW/cm2 – 40 s) and three sample thicknesses (0.5 mm, 1 mm, and 2 mm). All samples were polymerized with the light tip 8 mm away from the specimen. Knoop microhardness was then measured on the top and bottom surfaces of each sample. The top surfaces, with some exceptions, were almost similar; however, in relation to the bottom surfaces, statistical differences were found between curing units and thicknesses. In all experimental groups, the 0.5-mm-thick increments showed microhardness values statistically higher than those observed for 1- and -2-mm increments. The conventional and LED units showed higher hardness mean values and were statistically different from the high irradiance unit. In all experimental groups, microhardness mean values obtained for the top surface were higher than those observed for the bottom surface. In conclusion, higher levels of irradiance or thinner increments would help improve hybrid composite resin polymerization. PMID:23674901
Small-Scale Spectral and Color Analysis of Ritchey Crater Impact Materials
NASA Astrophysics Data System (ADS)
Bray, Veronica; Chojnacki, Matthew; McEwen, Alfred; Heyd, Rodney
2014-11-01
Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) analysis of Ritchey crater on Mars has allowed identification of the minerals uplifted from depth within its central peak as well as the dominant spectral signature of the crater fill materials which surround it. However, the 18m/px resolution of CRISM prevents full analysis of the nature of small-scale dykes, mega breccia blocks and finer scale crater-fill units. We extend our existing CRISM-based compositional mapping of the Ritchey crater interior to sub-CRISM pixel scales with the use of High Resolution Imaging Science Experiment (HiRISE) Color Ratio Products (CRPs). These CRPs are then compared to CRISM images; correlation between color ratio and CRISM spectral signature for a large bedrock unit is defined and used to suggest similar composition for a smaller unit with the same color ratio. Megabreccia deposits, angular fragments of rock in excess of 1 meter in diameter within a finer grained matrix, are common at Ritchey. The dominant spectral signature from each megabreccia unit varies with location around Ritchey and appears to reflect the matrix composition (based on texture and albedo similarities to surrounding rocks) rather than clast composition. In cases where the breccia block size is large enough for CRISM analysis, many different mineral compositions are noted (low calcium pyroxene (LCP) olivine (OL), alteration products) depending on the location. All block compositions (as inferred from CRPs) are observed down to the limit of HiRISE resolution. We have found a variety of dyke compositions within our mapping area. Correlation between CRP color and CRISM spectra in this area suggest that large 10 m wide) dykes within LCP-bearing bedrock close to the crater center tend to have similar composition to the host rock. Smaller dykes running non-parallel to the larger dykes are inferred to be OL-rich suggesting multiple phases of dyke formation within the Ritchey crater and its bedrock.
Needham, Amy; Cantlon, Jessica F; Ormsbee Holley, Susan M
2006-12-01
The current research investigates infants' perception of a novel object from a category that is familiar to young infants: key rings. We ask whether experiences obtained outside the lab would allow young infants to parse the visible portions of a partly occluded key ring display into one single unit, presumably as a result of having categorized it as a key ring. This categorization was marked by infants' perception of the keys and ring as a single unit that should move together, despite their attribute differences. We showed infants a novel key ring display in which the keys and ring moved together as one rigid unit (Move-together event) or the ring moved but the keys remained stationary throughout the event (Move-apart event). Our results showed that 8.5-month-old infants perceived the keys and ring as connected despite their attribute differences, and that their perception of object unity was eliminated as the distinctive attributes of the key ring were removed. When all of the distinctive attributes of the key ring were removed, the 8.5-month-old infants perceived the display as two separate units, which is how younger infants (7-month-old) perceived the key ring display with all its distinctive attributes unaltered. These results suggest that on the basis of extensive experience with an object category, infants come to identify novel members of that category and expect them to possess the attributes typical of that category.
NASA Astrophysics Data System (ADS)
Mukherjee, R.; Venkatesh, A. S.; Fareeduddin, F.
2016-12-01
Bhukia is a unique gold prospect in terms of its host lithologies such as albitite and carbonates with respect to greenstone hosted Archean gold deposits from India. Tourmaline occurs along with apatite, magnetite, graphite, chalcopyrite and gold-sulfide association in Bhukia gold prospect preserve geochemical record of changing physico-chemical conditions during its growth. Tourmalinization is one of the distinct hydrothermal alterations present in the study area. Chemical composition of two varieties of tourmalines presents as significant amounts within albitite and carbonate rocks from Bhukia gold prospect. EPMA analysis of two varieties of tourmalines viz. 1) rounded to sub-rounded, euhedral, green colored tourmalines and 2) elongated, zoned, brown colored tourmalines unlocks their chemical compositions as well as variations from core to rim. In some albitite litho-units, tourmaline occurs as major constituents (>15%), present as layers, termed as tourmalinites. Al-Fe-Mg and Na/ (Na+Ca) vs Fe/ (Fe+Mg) suggests that tourmalines from the Bhukia gold prospect are Mg-rich dravite to Fe-rich schrol in composition. Tourmalines present within the albitite rocks show variations in iron and sodium content from core to rim whereas similarity exist from core to rim in case of carbonate rocks. Presence of albite confirms the role of Na-rich fluids during the formation of tourmalines. Tourmalines present in Bhukia gold prospect is mainly influenced by boron influx and the source may be boron bearing hydrothermal fluid or boron bearing minerals. Dewatering of original un-metamorphosed rock during progressive metamorphism may remove boron from the metasedimentary rocks. Due to the mobile nature of boron, it dispersed and mixed with hydrothermal fluids and alumina that is required for the formation of the tourmaline might have been leached from metasedimentary rocks present in Bhukia gold prospect. Presence of hydrothermal alterations such as tourmalinization and albitization along with Au-Cu-graphite-magnetite association suggest this deposit to be an IOCG (Iron oxide copper gold) type.
Magnesium isotope systematics in Martian meteorites
NASA Astrophysics Data System (ADS)
Magna, Tomáš; Hu, Yan; Teng, Fang-Zhen; Mezger, Klaus
2017-09-01
Magnesium isotope compositions are reported for a suite of Martian meteorites that span the range of petrological and geochemical types recognized to date for Mars, including crustal breccia Northwest Africa (NWA) 7034. The δ26Mg values (per mil units relative to DSM-3 reference material) range from -0.32 to -0.11‰; basaltic shergottites and nakhlites lie to the heavier end of the Mg isotope range whereas olivine-phyric, olivine-orthopyroxene-phyric and lherzolitic shergottites, and chassignites have slightly lighter Mg isotope compositions, attesting to modest correlation of Mg isotopes and petrology of the samples. Slightly heavier Mg isotope compositions found for surface-related materials (NWA 7034, black glass fraction of the Tissint shergottite fall; δ26Mg > -0.17‰) indicate measurable Mg isotope difference between the Martian mantle and crust but the true extent of Mg isotope fractionation for Martian surface materials remains unconstrained. The range of δ26Mg values from -0.19 to -0.11‰ in nakhlites is most likely due to accumulation of clinopyroxene during petrogenesis rather than garnet fractionation in the source or assimilation of surface material modified at low temperatures. The rather restricted range in Mg isotope compositions between spatially and temporally distinct mantle-derived samples supports the idea of inefficient/absent major tectonic cycles on Mars, which would include plate tectonics and large-scale recycling of isotopically fractionated surface materials back into the Martian mantle. The cumulative δ26Mg value of Martian samples, which are not influenced by late-stage alteration processes and/or crust-mantle interactions, is - 0.271 ± 0.040 ‰ (2SD) and is considered to reflect δ26Mg value of the Bulk Silicate Mars. This value is robust taking into account the range of lithologies involved in this estimate. It also attests to the lack of the Mg isotope variability reported for the inner Solar System bodies at current analytical precision, also noted for several other major elements.
Selective logging: does the imprint remain on tree structure and composition after 45 years?
Osazuwa-Peters, Oyomoare L; Chapman, Colin A; Zanne, Amy E
2015-01-01
Selective logging of tropical forests is increasing in extent and intensity. The duration over which impacts of selective logging persist, however, remains an unresolved question, particularly for African forests. Here, we investigate the extent to which a past selective logging event continues to leave its imprint on different components of an East African forest 45 years later. We inventoried 2358 stems ≥10 cm in diameter in 26 plots (200 m × 10 m) within a 5.2 ha area in Kibale National Park, Uganda, in logged and unlogged forest. In these surveys, we characterized the forest light environment, taxonomic composition, functional trait composition using three traits (wood density, maximum height and maximum diameter) and forest structure based on three measures (stem density, total basal area and total above-ground biomass). In comparison to unlogged forests, selectively logged forest plots in Kibale National Park on average had higher light levels, different structure characterized by lower stem density, lower total basal area and lower above-ground biomass, and a distinct taxonomic composition driven primarily by changes in the relative abundance of species. Conversely, selectively logged forest plots were like unlogged plots in functional composition, having similar community-weighted mean values for wood density, maximum height and maximum diameter. This similarity in functional composition irrespective of logging history may be due to functional recovery of logged forest or background changes in functional attributes of unlogged forest. Despite the passage of 45 years, the legacy of selective logging on the tree community in Kibale National Park is still evident, as indicated by distinct taxonomic and structural composition and reduced carbon storage in logged forest compared with unlogged forest. The effects of selective logging are exerted via influences on tree demography rather than functional trait composition.
Selective logging: does the imprint remain on tree structure and composition after 45 years?
Osazuwa-Peters, Oyomoare L.; Chapman, Colin A.; Zanne, Amy E.
2015-01-01
Selective logging of tropical forests is increasing in extent and intensity. The duration over which impacts of selective logging persist, however, remains an unresolved question, particularly for African forests. Here, we investigate the extent to which a past selective logging event continues to leave its imprint on different components of an East African forest 45 years later. We inventoried 2358 stems ≥10 cm in diameter in 26 plots (200 m × 10 m) within a 5.2 ha area in Kibale National Park, Uganda, in logged and unlogged forest. In these surveys, we characterized the forest light environment, taxonomic composition, functional trait composition using three traits (wood density, maximum height and maximum diameter) and forest structure based on three measures (stem density, total basal area and total above-ground biomass). In comparison to unlogged forests, selectively logged forest plots in Kibale National Park on average had higher light levels, different structure characterized by lower stem density, lower total basal area and lower above-ground biomass, and a distinct taxonomic composition driven primarily by changes in the relative abundance of species. Conversely, selectively logged forest plots were like unlogged plots in functional composition, having similar community-weighted mean values for wood density, maximum height and maximum diameter. This similarity in functional composition irrespective of logging history may be due to functional recovery of logged forest or background changes in functional attributes of unlogged forest. Despite the passage of 45 years, the legacy of selective logging on the tree community in Kibale National Park is still evident, as indicated by distinct taxonomic and structural composition and reduced carbon storage in logged forest compared with unlogged forest. The effects of selective logging are exerted via influences on tree demography rather than functional trait composition. PMID:27293697
du Bray, Edward A.; Holm-Denoma, Christopher S.; Lund, Karen; Premo, Wayne R.
2018-03-27
The conterminous United States hosts numerous volumetrically significant and geographically dispersed granitoid intrusions that range in age from 1.50 to 1.32 billion years before present (Ga). Although previously referred to as A-type granites, most are better described as ferroan granites. These granitoid intrusions are distributed in the northern and central Rocky Mountains, the Southwest, the northern midcontinent, and a swath largely buried beneath Phanerozoic cover across the Great Plains and into the southern midcontinent. These intrusions, with ages that are bimodally distributed between about 1.455–1.405 Ga and 1.405–1.320 Ga, are dispersed nonsystematically with respect to age across their spatial extents. Globally, although A-type or ferroan granites are genetically associated with rare-metal deposits, most U.S. 1.4 Ga granitoid intrusions do not contain significant deposits. Exceptions are the light rare-earth element deposit at Mountain Pass, California, and the iron oxide-apatite and iron oxide-copper-gold deposits in southeast Missouri.Most of the U.S. 1.4 Ga granitoid intrusions are composed of hornblende ± biotite or biotite ± muscovite monzogranite, commonly with prominent alkali feldspar megacrysts; however, modal compositions vary widely. These intrusions include six of the eight commonly identified subtypes of ferroan granite: alkali-calcic and calc-alkalic peraluminous subtypes; alkalic, alkali-calcic, and calc-alkalic metaluminous subtypes; and the alkalic peralkaline subtype. The U.S. 1.4 Ga granitoid intrusions also include variants of these subtypes that have weakly magnesian compositions. Extreme large-ion lithophile element enrichments typical of ferroan granites elsewhere are absent among these intrusions. Chondrite-normalized rare-earth element patterns for these intrusions have modest negative slopes and moderately developed negative europium anomalies. Their radiogenic isotopic compositions are consistent with mixing involving primitive, mantle-derived components and evolved, crust-derived components.Each compositional subtype can be ascribed to a relatively unique petrogenetic history. The numerically dominant ferroan, peraluminous granites probably represent low-degree, relatively high-pressure partial melting of preexisting, crust-derived, intermediate-composition granitoids. The moderately numerous, weakly magnesian, peraluminous granites probably reflect similar partial melting but at a higher degree and in a lower pressure environment. In contrast, the ferroan but metaluminous granites may be the result of extensive differentiation of tholeiitic basalt. Finally, the peralkaline igneous rocks at Mountain Pass have compositions potentially derived by differentiation of alkali basalt. The varying alkalic character of each subtype probably reflects polybaric petrogenesis and the corresponding effect of diverse mineral stabilities on ultimate melt compositions. Mantle-derived mafic magma and variably assimilated partial melts of mainly juvenile Paleoproterozoic crustal components are required to generate the relatively low initial strontium (87Sr/86Sr) and distinctive neodymium isotope compositions characteristic of the U.S. 1.4 Ga granitoid intrusions. The characteristics of these intrusions are consistent with crustal melting in an extensional/decompressional, intracratonic setting that was triggered by mantle upwelling and emplacement of tholeiitic basaltic magma at or near the base of the crust. Composite magmas, formed by mingling and mixing mantle components with partial melts of Paleoproterozoic crust, produced variably homogenized storage reservoirs that continued polybaric evolution as intrusions lodged at various crustal depths.