Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1990 to November 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kszos, L.A.

1994-03-01

On September 23, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Lab (ORNL) added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in identifying those effluents with the potential for adversely affecting instream fauna, assessing the ecological health of receiving streams, guiding plans for remediation, andmore » protecting human health. In September 1992, a renewed permit was issued which requires toxicity monitoring of continuous and intermittent outfalls on a quarterly basis. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities. This report includes ESD/ORNL activities occurring from December 1990 to November 1992.« less

Simplified MPN method for enumeration of soil naphthalene degraders using gaseous substrate.

PubMed

Wallenius, Kaisa; Lappi, Kaisa; Mikkonen, Anu; Wickström, Annika; Vaalama, Anu; Lehtinen, Taru; Suominen, Leena

2012-02-01

We describe a simplified microplate most-probable-number (MPN) procedure to quantify the bacterial naphthalene degrader population in soil samples. In this method, the sole substrate naphthalene is dosed passively via gaseous phase to liquid medium and the detection of growth is based on the automated measurement of turbidity using an absorbance reader. The performance of the new method was evaluated by comparison with a recently introduced method in which the substrate is dissolved in inert silicone oil and added individually to each well, and the results are scored visually using a respiration indicator dye. Oil-contaminated industrial soil showed slightly but significantly higher MPN estimate with our method than with the reference method. This suggests that gaseous naphthalene was dissolved in an adequate concentration to support the growth of naphthalene degraders without being too toxic. The dosing of substrate via gaseous phase notably reduced the work load and risk of contamination. The result scoring by absorbance measurement was objective and more reliable than measurement with indicator dye, and it also enabled further analysis of cultures. Several bacterial genera were identified by cloning and sequencing of 16S rRNA genes from the MPN wells incubated in the presence of gaseous naphthalene. In addition, the applicability of the simplified MPN method was demonstrated by a significant positive correlation between the level of oil contamination and the number of naphthalene degraders detected in soil.

Method of processing aluminous ores

DOEpatents

Loutfy, Raouf O.; Keller, Rudolf; Yao, Neng-Ping

1981-01-01

A method of producing aluminum chloride from aluminous materials containing compounds of iron, titanium and silicon comprising reacting the aluminous materials with carbon and a chlorine-containing gas at a temperature of about 900.degree. K. to form a gaseous mixture containing chlorides of aluminum, iron, titanium and silicon and oxides of carbon; cooling the gaseous mixture to a temperature of about 400.degree. K. or lower to condense the aluminum chlorides and iron chlorides while titanium chloride and silicon chloride remain in the gas phase to effect a separation thereof; heating the mixture of iron chlorides and aluminum chlorides to a temperature of about 800.degree. K. to form gaseous aluminum chlorides and iron chlorides; passing the heated gases into intimate contact with aluminum sulfide to precipitate solid iron sulfide and to form additional gaseous aluminum chlorides; and separating the gaseous aluminum chloride from the solid iron sulfide.

Apparatus and method for enhanced chemical processing in high pressure and atmospheric plasmas produced by high frequency electromagnetic waves

DOEpatents

Efthimion, Philip C.; Helfritch, Dennis J.

1989-11-28

An apparatus and method for creating high temperature plasmas for enhanced chemical processing of gaseous fluids, toxic chemicals, and the like, at a wide range of pressures, especially at atmospheric and high pressures includes an electro-magnetic resonator cavity, preferably a reentrant cavity, and a wave guiding structure which connects an electro-magnetic source to the cavity. The cavity includes an intake port and an exhaust port, each having apertures in the conductive walls of the cavity sufficient for the intake of the gaseous fluids and for the discharge of the processed gaseous fluids. The apertures are sufficiently small to prevent the leakage of the electro-magnetic radiation from the cavity. Gaseous fluid flowing from the direction of the electro-magnetic source through the guiding wave structure and into the cavity acts on the plasma to push it away from the guiding wave structure and the electro-magnetic source. The gaseous fluid flow confines the high temperature plasma inside the cavity and allows complete chemical processing of the gaseous fluids at a wide range of pressures.

Apparatus and process for the separation of gases using supersonic expansion and oblique wave compression

DOE Office of Scientific and Technical Information (OSTI.GOV)

VanOsdol, John G.

The disclosure provides an apparatus and method for gas separation through the supersonic expansion and subsequent deceleration of a gaseous stream. The gaseous constituent changes phase from the gaseous state by desublimation or condensation during the acceleration producing a collectible constituent, and an oblique shock diffuser decelerates the gaseous stream to a subsonic velocity while maintain the collectible constituent in the non-gaseous state. Following deceleration, the carrier gas and the collectible constituent at the subsonic velocity are separated by a separation means, such as a centrifugal, electrostatic, or impingement separator. In an embodiment, the gaseous stream issues from a combustionmore » process and is comprised of N.sub.2 and CO.sub.2.« less

Development of real-time monitors for gaseous formaldehyde. Final report, 1 December 1988-30 September 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kelly, T.J.; Barnes, R.H.

1990-11-01

Two new methods for real-time measurement of gaseous formaldehyde have been developed. One is a spectroscopic method based on direct fluorescence detection of gaseous formaldehyde following excitation with UV light. This method has been developed to the prototype stage by modifications of a commercial fluorescence SO2 detector to convert it to formaldehyde detection. The prototype spectroscopic formaldehyde monitor exhibits a detection limit of <30 ppbv, with a time response of about one minute. The second method is based on derivatization of formaldehyde in aqueous solution to form a fluorescent product. The detection of fluorescent product was made more sensitive bymore » using intense 254 nm light from a mercury lamp for excitation, thereby allowing use of a simple and efficient glass coil scrubber for collection of gaseous formaldehyde. The wet chemical formaldehyde monitor incorportating these improvements exhibits a detection limit for gaseous formaldehyde of 0.2 ppbv and for aqueous formaldehyde of 0.2 micromolar with time response of about one minute, following a lag time of 2 minutes. Both instruments were tested in the laboratory with gaseous formaldehyde standards, and the aqueous scrubbing/analysis method was field tested by continuous operation over a 10-day period in which outdoor and indoor air were sampled for alternate half-hour periods. A comparison of real-time (aqueous scrubbing/analysis) and integrated measurements, using dinitrophenylhydrazine (DNPH) impingers, showed close agreement between the real-time and DNPH data, even at concentrations as low as 1 ppbv.« less

On the accuracy of instantaneous gas exchange rates, energy expenditure and respiratory quotient calculations obtained from indirect whole room calorimetry.

PubMed

Gribok, Andrei; Hoyt, Reed; Buller, Mark; Rumpler, William

2013-06-01

This paper analyzes the accuracy of metabolic rate calculations performed in the whole room indirect calorimeter using the molar balance equations. The equations are treated from the point of view of cause-effect relationship where the gaseous exchange rates representing the unknown causes need to be inferred from a known, noisy effect-gaseous concentrations. Two methods of such inference are analyzed. The first method is based on the previously published regularized deconvolution of the molar balance equation and the second one, proposed in this paper, relies on regularized differentiation of gaseous concentrations. It is found that both methods produce similar results for the absolute values of metabolic variables and their accuracy. The uncertainty for O2 consumption rate is found to be 7% and for CO2 production--3.2%. The uncertainties in gaseous exchange rates do not depend on the absolute values of O2 consumption and CO2 production. In contrast, the absolute uncertainty in respiratory quotient is a function of the gaseous exchange rates and varies from 9.4% during the night to 2.3% during moderate exercise. The uncertainty in energy expenditure was found to be 5.9% and independent of the level of gaseous exchange. For both methods, closed form analytical formulas for confidence intervals are provided allowing quantification of uncertainty for four major metabolic variables in real world studies.

Charged particle mobility refrigerant analyzer

DOEpatents

Allman, S.L.; Chunghsuan Chen; Chen, F.C.

1993-02-02

A method for analyzing a gaseous electronegative species comprises the steps of providing an analysis chamber; providing an electric field of known potential within the analysis chamber; admitting into the analysis chamber a gaseous sample containing the gaseous electronegative species; providing a pulse of free electrons within the electric field so that the pulse of free electrons interacts with the gaseous electronegative species so that a swarm of electrically charged particles is produced within the electric field; and, measuring the mobility of the electrically charged particles within the electric field.

Charged particle mobility refrigerant analyzer

DOEpatents

Allman, Steve L.; Chen, Chung-Hsuan; Chen, Fang C.

1993-01-01

A method for analyzing a gaseous electronegative species comprises the steps of providing an analysis chamber; providing an electric field of known potential within the analysis chamber; admitting into the analysis chamber a gaseous sample containing the gaseous electronegative species; providing a pulse of free electrons within the electric field so that the pulse of free electrons interacts with the gaseous electronegative species so that a swarm of electrically charged particles is produced within the electric field; and, measuring the mobility of the electrically charged particles within the electric field.

Method and apparatus for producing laser radiation following two-photon excitation of a gaseous medium

DOEpatents

Bischel, William K. [Menlo Park, CA; Jacobs, Ralph R. [Livermore, CA; Prosnitz, Donald [Hamden, CT; Rhodes, Charles K. [Palo Alto, CA; Kelly, Patrick J. [Fort Lewis, WA

1979-02-20

Method and apparatus for producing laser radiation by two-photon optical pumping of an atomic or molecular gaseous medium and subsequent lasing action. A population inversion is created as a result of two-photon absorption of the gaseous species. Stark tuning is utilized, if necessary, in order to tune the two-photon transition into exact resonance. In particular, gaseous ammonia (NH.sub.3) or methyl fluoride (CH.sub.3 F) is optically pumped by a pair of CO.sub.2 lasers to create a population inversion resulting from simultaneous two-photon excitation of a high-lying vibrational state, and laser radiation is produced by stimulated emission of coherent radiation from the inverted level.

Method and apparatus for producing laser radiation following two-photon excitation of a gaseous medium

DOEpatents

Bischel, W.K.; Jacobs, R.R.; Prosnitz, D.P.; Rhodes, C.K.; Kelly, P.J.

1979-02-20

Method and apparatus are disclosed for producing laser radiation by two-photon optical pumping of an atomic or molecular gaseous medium and subsequent lasing action. A population inversion is created as a result of two-photon absorption of the gaseous species. Stark tuning is utilized, if necessary, in order to tune the two-photon transition into exact resonance. In particular, gaseous ammonia (NH[sub 3]) or methyl fluoride (CH[sub 3]F) is optically pumped by a pair of CO[sub 2] lasers to create a population inversion resulting from simultaneous two-photon excitation of a high-lying vibrational state, and laser radiation is produced by stimulated emission of coherent radiation from the inverted level. 3 figs.

Determination of efficiency of an aged HPGe detector for gaseous sources by self absorption correction and point source methods

NASA Astrophysics Data System (ADS)

Sarangapani, R.; Jose, M. T.; Srinivasan, T. K.; Venkatraman, B.

2017-07-01

Methods for the determination of efficiency of an aged high purity germanium (HPGe) detector for gaseous sources have been presented in the paper. X-ray radiography of the detector has been performed to get detector dimensions for computational purposes. The dead layer thickness of HPGe detector has been ascertained from experiments and Monte Carlo computations. Experimental work with standard point and liquid sources in several cylindrical geometries has been undertaken for obtaining energy dependant efficiency. Monte Carlo simulations have been performed for computing efficiencies for point, liquid and gaseous sources. Self absorption correction factors have been obtained using mathematical equations for volume sources and MCNP simulations. Self-absorption correction and point source methods have been used to estimate the efficiency for gaseous sources. The efficiencies determined from the present work have been used to estimate activity of cover gas sample of a fast reactor.

Production of heavy water

DOEpatents

Spencer, Larry S.; Brown, Sam W.; Phillips, Michael R.

2017-06-06

Disclosed are methods and apparatuses for producing heavy water. In one embodiment, a catalyst is treated with high purity air or a mixture of gaseous nitrogen and oxygen with gaseous deuterium all together flowing over the catalyst to produce the heavy water. In an alternate embodiment, the deuterium is combusted to form the heavy water. In an alternate embodiment, gaseous deuterium and gaseous oxygen is flowed into a fuel cell to produce the heavy water. In various embodiments, the deuterium may be produced by a thermal decomposition and distillation process that involves heating solid lithium deuteride to form liquid lithium deuteride and then extracting the gaseous deuterium from the liquid lithium deuteride.

Method of absorbing UF.sub.6 from gaseous mixtures in alkamine absorbents

DOEpatents

Lafferty, Robert H.; Smiley, Seymour H.; Radimer, Kenneth J.

1976-04-06

A method of recovering uranium hexafluoride from gaseous mixtures employing as an absorbent a liquid composition at least one of the components of which is chosen from the group consisting of ethanolamine, diethanolamine, and 3-methyl-3-amino-propane-diol-1,2.

METHOD OF OPERATING A NEUTRONIC REACTOR

DOEpatents

Turkevich, A.

1963-01-22

This patent relates to one step in a method of operating a neutronic reactor consisting of a slurry of fissionable material in heavy water. Deuterium gas is passed through the slurry to sweep gaseous fission products therefrom and the deuterium is then separated from the gaseous fission products. (AEC)

Comparative evaluation of methods for the determination of heat transfer coefficients of liquid and gaseous quenching media

NASA Astrophysics Data System (ADS)

Shevchenko, Svetlana Yu.; Melnik, Yury A.; Smirnov, Andrey E.; Htet, Wai Yan Min

2018-03-01

Temperature dependences of heat transfer coefficients of liquid and gaseous quenching media were determined using a gradient probe and prismatic probe of more simple design. The probes of two different designs were tested in the same conditions. Analysis of heat transfer coefficients showed good agreement between the data obtained. The tests were carried out with liquid and gaseous quenching media: water, polymer quenchant, quenching oil and high-pressure nitrogen. Methods of mathematical modeling of steel samples quenching show the adequacy of the results.

Method of measuring heat influx of a cryogenic transfer system

DOEpatents

Niemann, Ralph C.; Zelipsky, Steven A.; Rezmer, Ronald R.; Smelser, Peter

1981-01-01

A method is provided for measuring the heat influx of a cryogenic transfer system. A gaseous phase of the cryogen used during normal operation of the system is passed through the system. The gaseous cryogen at the inlet to the system is tempered to duplicate the normal operating temperature of the system inlet. The temperature and mass flow rate of the gaseous cryogen is measured at the outlet of the system, and the heat capacity of the cryogen is determined. The heat influx of the system is then determined from known thermodynamic relationships.

Method of preparing pure fluorine gas

DOEpatents

Asprey, Larned B.

1976-01-01

A simple, inexpensive system for purifying and storing pure fluorine is described. The method utilizes alkali metal-nickel fluorides to absorb tank fluorine by forming nickel complex salts and leaving the gaseous impurities which are pumped away. The complex nickel fluoride is then heated to evolve back pure gaseous fluorine.

Method and system for low-NO.sub.x dual-fuel combustion of liquid and/or gaseous fuels

DOEpatents

Gard, Vincent; Chojnacki, Dennis A; Rabovitser, Ioseph K

2014-12-02

A method and apparatus for combustion in which a pressurized preheated liquid fuel is atomized and a portion thereof flash vaporized, creating a mixture of fuel vapor and liquid droplets. The mixture is mixed with primary combustion oxidant, producing a fuel/primary oxidant mixture which is then injected into a primary combustion chamber in which the fuel/primary oxidant mixture is partially combusted, producing a secondary gaseous fuel containing hydrogen and carbon oxides. The secondary gaseous fuel is mixed with a secondary combustion oxidant and injected into the second combustion chamber wherein complete combustion of the secondary gaseous fuel is carried out. The resulting second stage flue gas containing very low amounts of NO.sub.x is then vented from the second combustion chamber.

Electron collisions—experiment, theory, and applications

NASA Astrophysics Data System (ADS)

Bartschat, Klaus

2018-07-01

Electron collisions with atoms, ions, and molecules have represented an important area of ‘applied quantum mechanics’ for more than a century. This Topical Review is the write-up of the Allis Prize Lecture given by the author at the 2016 meeting of the Division of Atomic, Molecular, and Optical Physics of the American Physical Society and the 2017 Gaseous Electronics Conference. In light of the enormous size of the field, the examples presented were selected in order to tell the story of how experimental and theoretical/numerical methods have developed over time, how fruitful collaborations between data producers (experimentalists and theorists) and data users have led to significant progress, and how the results of these studies, which were often designed for fundamental research in order to push both experiment and theory to new frontiers, continue to be highly sought after for modeling applications in a variety of fields. The impact of electron collision studies on other fields, such as photoinduced processes and quantum information, is also discussed.

Method of producing gaseous products using a downflow reactor

DOEpatents

Cortright, Randy D; Rozmiarek, Robert T; Hornemann, Charles C

2014-09-16

Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.

RELIABILITY STUDY OF THE U.S. EPA'S METHODS 101A - DETERMINATION OF PARTICULATE AND GASEOUS MERCURY EMISSIONS

EPA Science Inventory

EPA Method 101A applies to the determination of particulate and gaseous mercury missions from sewage sludge incinerators and other sources. oncern has been expressed hat ammonia or hydrogen chloride (HCl) when present in the emissions, interferes in the analytical processes and p...

Method of measuring heat influx of a cryogenic transfer system. [Patent application

DOEpatents

Niemann, R.C.; Zelipsky, S.A.; Rezmer, R.R.; Smelser, P.

1980-10-29

A method is provided for measuring the heat influx of a cryogenic transfer system. A gaseous phase of the cryogen used during normal operation of the system is passed through the system. The gaseous cryogen at the inlet to the system is tempered to duplicate the normal operating temperature of the system inlet. The temperature and mass flow rate of the gaseous cryogen is measured at the outlet of the system, and the heat capacity of the cryogen is determined. The heat influx of the system is then determined from known thermodynamic relationships.

The Gaseous Explosive Reaction : The Effect of Inert Gases

NASA Technical Reports Server (NTRS)

Stevens, F W

1928-01-01

Attention is called in this report to previous investigations of gaseous explosive reactions carried out under constant volume conditions, where the effect of inert gases on the thermodynamic equilibrium was determined. The advantage of constant pressure methods over those of constant volume as applied to studies of the gaseous explosive reaction is pointed out and the possibility of realizing for this purpose a constant pressure bomb mentioned. The application of constant pressure methods to the study of gaseous explosive reactions, made possible by the use of a constant pressure bomb, led to the discovery of an important kinetic relation connecting the rate of propagation of the zone of explosive reaction within the active gases, with the initial concentrations of those gases: s = K(sub 1)(A)(sup n1)(B)(sup n2)(C)(sup n3)------. By a method analogous to that followed in determining the effect of inert gases on the equilibrium constant K, the present paper records an attempt to determine their kinetic effect upon the expression given above.

Method for heating nongaseous carbonaceous material

DOEpatents

Lumpkin, Jr., Robert E.

1978-01-01

Nongaseous carbonaceous material is heated by a method comprising introducing tangentially a first stream containing a nongaseous carbonaceous material and carbon monoxide into a reaction zone; simultaneously and separately introducing a second stream containing oxygen into the reaction zone such that the oxygen enters the reaction zone away from the wall thereof and reacts with the first stream thereby producing a gaseous product and heating the nongaseous carbonaceous material; forming an outer spiralling vortex within the reaction zone to cause substantial separation of gases, including the gaseous product, from the nongaseous carbonaceous material; removing a third stream from the reaction zone containing the gaseous product which is substantially free of the nongaseous carbonaceous material before a major portion of the gaseous product can react with the nongaseous carbonaceous material; and removing a fourth stream containing the nongaseous carbonaceous material from the reaction zone.

Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

DOEpatents

Garrett, W. Ray

1997-01-01

A method and apparatus for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components.

Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

DOEpatents

Garrett, W.R.

1997-11-11

A method and apparatus are disclosed for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components. 9 figs.

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kszos, L.A.; Konetsky, B.K.; Peterson, M.J.

1997-06-01

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous diffusion Plant (PGDP). The PGDP BMP was conducted by the University of Kentucky Between 1987 and 1992 and by staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) from 1991 to present. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation ofmore » fish and other aquatic life, (2) characterize potential environmental impacts, and (3) document the effects of pollution abatement facilities on stream. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report focuses on ESD activities occurring from January 1996 to December 1996, although activities conducted outside this time period are included as appropriate.« less

Ionic liquid-functionalized mesoporous sorbents and their use in the capture of polluting gases

DOEpatents

Lee, Jong Suk; Koros, William J.; Bhuwania, Nitesh; Hillesheim, Patrick C.; Dai, Sheng

2016-01-12

A composite structure for capturing a gaseous electrophilic species, the composite structure comprising mesoporous refractory sorbent particles on which an ionic liquid is covalently attached, wherein said ionic liquid includes an accessible functional group that is capable of binding to said gaseous electrophilic species. In particular embodiments, the mesoporous sorbent particles are contained within refractory hollow fibers. Also described is a method for capturing a gaseous electrophilic species by use of the above-described composite structure, wherein the gaseous electrophilic species is contacted with the composite structure. In particular embodiments thereof, cooling water is passed through the refractory hollow fibers containing the IL-functionalized sorbent particles in order to facilitate capture of the gaseous electrophilic species, and then steam is passed through the refractory hollow fibers to facilitate release of the gaseous electrophilic species such that the composite structure can be re-used to capture additional gas.

Liquid and gaseous oxygen safety review, volume 1

NASA Technical Reports Server (NTRS)

Lapin, A.

1972-01-01

Materials used or contained in liquid and gaseous oxygen systems are analyzed for their compatibility; and areas of possible concern in oxygen systems are outlined. Design criteria, cleaning procedures, and quality control methods are covered in detail.

METHOD OF REMOVING RADIOACTIVE IODINE FROM GASES

DOEpatents

Silverman, L.

1962-01-23

A method of removing radioactive iodine from a gaseous medium is given in which the gaseous medium is adjusted to a temperature not exceeding 400 deg C and then passed over a copper fibrous pad having a coating of cupric sulfide deposited thereon. An ionic exchange on the pad results in the formation of cupric iodide and the release of sulfur. (AEC)

Gaseous fuel reactors for power systems

NASA Technical Reports Server (NTRS)

Kendall, J. S.; Rodgers, R. J.

1977-01-01

Gaseous-fuel nuclear reactors have significant advantages as energy sources for closed-cycle power systems. The advantages arise from the removal of temperature limits associated with conventional reactor fuel elements, the wide variety of methods of extracting energy from fissioning gases, and inherent low fissile and fission product in-core inventory due to continuous fuel reprocessing. Example power cycles and their general performance characteristics are discussed. Efficiencies of gaseous fuel reactor systems are shown to be high with resulting minimal environmental effects. A technical overview of the NASA-funded research program in gaseous fuel reactors is described and results of recent tests of uranium hexafluoride (UF6)-fueled critical assemblies are presented.

Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

DOEpatents

Pecharsky, Vitalij K.; Balema, Viktor P.

2004-08-10

The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

Parents of two-phase flow and theory of "gas-lift"

NASA Astrophysics Data System (ADS)

Zitek, Pavel; Valenta, Vaclav

2014-03-01

This paper gives a brief overview of types of two-phase flow. Subsequently, it deals with their mutual division and problems with accuracy boundaries among particular types. It also shows the case of water flow through a pipe with external heating and the gradual origination of all kinds of flow. We have met it in solution of safety condition of various stages in pressurized and boiling water reactors. In the MSR there is a problem in the solution of gas-lift using helium as a gas and its secondary usage for clearing of the fuel mixture from gaseous fission products. Theory of gas-lift is described.

LASER BIOLOGY AND MEDICINE: Application of tunable diode lasers for a highly sensitive analysis of gaseous biomarkers in exhaled air

NASA Astrophysics Data System (ADS)

Stepanov, E. V.; Milyaev, Varerii A.

2002-11-01

The application of tunable diode lasers for a highly sensitive analysis of gaseous biomarkers in exhaled air in biomedical diagnostics is discussed. The principle of operation and the design of a laser analyser for studying the composition of exhaled air are described. The results of detection of gaseous biomarkers in exhaled air, including clinical studies, which demonstrate the diagnostic possibilities of the method, are presented.

Analysis and evalaution in the production process and equipment area of the low-cost solar array project. [including modifying gaseous diffusion and using ion implantation

NASA Technical Reports Server (NTRS)

Goldman, H.; Wolf, M.

1979-01-01

The manufacturing methods for photovoltaic solar energy utilization are assessed. Economic and technical data on the current front junction formation processes of gaseous diffusion and ion implantation are presented. Future proposals, including modifying gaseous diffusion and using ion implantation, to decrease the cost of junction formation are studied. Technology developments in current processes and an economic evaluation of the processes are included.

Methods and systems for deacidizing gaseous mixtures

DOEpatents

Hu, Liang

2010-05-18

An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

Method of digital epitaxy by externally controlled closed-loop feedback

DOEpatents

Eres, D.; Sharp, J.W.

1994-07-19

A method and apparatus for digital epitaxy are disclosed. The apparatus includes a pulsed gas delivery assembly that supplies gaseous material to a substrate to form an adsorption layer of the gaseous material on the substrate. Structure is provided for measuring the isothermal desorption spectrum of the growth surface to monitor the active sites which are available for adsorption. The vacuum chamber housing the substrate facilitates evacuation of the gaseous material from the area adjacent the substrate following exposure. In use, digital epitaxy is achieved by exposing a substrate to a pulse of gaseous material to form an adsorption layer of the material on the substrate. The active sites on the substrate are monitored during the formation of the adsorption layer to determine if all the active sites have been filled. Once the active sites have been filled on the growth surface of the substrate, the pulse of gaseous material is terminated. The unreacted portion of the gas pulse is evacuated by continuous pumping. Subsequently, a second pulse is applied when availability of active sites is determined by studying the isothermal desorption spectrum. These steps are repeated until a thin film of sufficient thickness is produced. 4 figs.

Method of digital epilaxy by externally controlled closed-loop feedback

DOEpatents

Eres, Djula; Sharp, Jeffrey W.

1994-01-01

A method and apparatus for digital epitaxy. The apparatus includes a pulsed gas delivery assembly that supplies gaseous material to a substrate to form an adsorption layer of the gaseous material on the substrate. Structure is provided for measuring the isothermal desorption spectrum of the growth surface to monitor the active sites which are available for adsorption. The vacuum chamber housing the substrate facilitates evacuation of the gaseous material from the area adjacent the substrate following exposure. In use, digital epitaxy is achieved by exposing a substrate to a pulse of gaseous material to form an adsorption layer of the material on the substrate. The active sites on the substrate are monitored during the formation of the adsorption layer to determine if all the active sites have been filled. Once the active sites have been filled on the growth surface of the substrate, the pulse of gaseous material is terminated. The unreacted portion of the gas pulse is evacuated by continuous pumping. Subsequently, a second pulse is applied when availability of active sites is determined by studying the isothermal desorption spectrum. These steps are repeated until a thin film of sufficient thickness is produced.

Methods for deacidizing gaseous mixtures by phase enhanced absorption

DOEpatents

Hu, Liang

2012-11-27

An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

Deconstructing Calculation Methods, Part 4: Division

ERIC Educational Resources Information Center

Thompson, Ian

2008-01-01

In the final article of a series of four, the author deconstructs the primary national strategy's approach to written division. The approach to division is divided into five stages: (1) mental division using partition; (2) short division of TU / U; (3) "expanded" method for HTU / U; (4) short division of HTU / U; and (5) long division.…

Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

DOEpatents

Wilding, Bruce M; Turner, Terry D

2014-12-02

A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

Method for removing acid gases from a gaseous stream

DOEpatents

Gorin, Everett; Zielke, Clyde W.

1981-01-01

In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

GASEOUS DISPOSAL PROCESS

DOEpatents

Ryan, R.F.; Thomasson, F.R.; Hicks, J.H.

1963-01-22

A method is described of removing gaseous radioactive Xe and Kr from water containing O. The method consists in stripping the gases from the water stream by means of H flowing countercurrently to the stream. The gases are then heated in a deoxo bed to remove O. The carrier gas is next cooled and passed over a charcoal adsorbent bed maintained at a temperature of about --280 deg F to remove the Xe and Kr. (AEC)

Method for synthesizing ultrafine powder materials

DOEpatents

Buss, Richard J.; Ho, Pauline

1988-01-01

A method for synthesizing ultrafine powder materials, for example, ceramic and metal powders, comprises admitting gaseous reactants from which the powder material is to be formed into a vacuum reaction chamber maintained at a pressure less than atmospheric and at a temperature less than about 400.degree. K. (127.degree.C.). The gaseous reactants are directed through a glow discharge provided in the vacuum reaction chamber to form the ultrafine powder material.

Diffusion method of seperating gaseous mixtures

DOEpatents

Pontius, Rex B.

1976-01-01

A method of effecting a relatively large change in the relative concentrations of the components of a gaseous mixture by diffusion which comprises separating the mixture into heavier and lighter portions according to major fraction mass recycle procedure, further separating the heavier portions into still heavier subportions according to a major fraction mass recycle procedure, and further separating the lighter portions into still lighter subportions according to a major fraction equilibrium recycle procedure.

Catalyst systems and uses thereof

DOEpatents

Ozkan, Umit S [Worthington, OH; Holmgreen, Erik M [Columbus, OH; Yung, Matthew M [Columbus, OH

2012-07-24

A method of carbon monoxide (CO) removal comprises providing an oxidation catalyst comprising cobalt supported on an inorganic oxide. The method further comprises feeding a gaseous stream comprising CO, and oxygen (O.sub.2) to the catalyst system, and removing CO from the gaseous stream by oxidizing the CO to carbon dioxide (CO.sub.2) in the presence of the oxidation catalyst at a temperature between about 20 to about 200.degree. C.

Thermodynamic properties of gaseous cerium molybdates and tungstates studied by Knudsen effusion mass spectrometry.

PubMed

Shugurov, S M; Panin, A I; Lopatin, S I

2018-06-21

CeO 2 -WO 3 and CeO 2 -MoO 3 catalysts have shown excellent performance in the selective reduction of NO x by ammonia (NH 3 -selective catalytic reduction) over a wide temperature range. Strong interaction between CeO 2 and WO 3 or MoO 3 might be the dominant reason for the high activity of these mixed oxides. Studies of ceria-containing gaseous salts involve considerable experimental difficulties, since the transition of such salts to vapor requires high temperatures. To predict the possibility of the existence of gaseous associates formed by cerium and molybdenum (tungsten) oxides it is important to know their thermodynamic characteristics. Until the present investigation, gaseous cerium oxyacid salts were unknown. Knudsen effusion mass spectrometry was used to determine the partial pressures of vapor species and the equilibrium constants of gas-phase reactions, as well as the formation and atomization enthalpies of gaseous cerium molybdates and tungstates. CeO 2 was evaporated from molybdenum and tungsten effusion cells containing gold metal as a pressure standard. A theoretical study of gaseous cerium gaseous molybdates and tungstates was performed by several quantum chemical methods. In the temperature range 2050-2400 K, CeO, CeO 2 , XO 2 , XO 3 , CeWO 3 , CeXO 4 , CeXO 5 (X = Mo, W) and CeMo 2 O 7 were found to be the main vapor species over the CeO 2 - Mo (W) systems. On the basis of the equilibrium constants of the gaseous reactions, the standard formation enthalpies of gaseous CeWO 3 , CeXO 4 , CeXO 5 (X = Mo, W) and CeMo 2 O 7 at 298 K were determined. Energetically favorable structures of gaseous cerium salts were found and vibrational frequencies were evaluated in the harmonic approximation. The thermal stability of gaseous cerium oxyacid salts was confirmed by high-temperature mass spectrometry. Reaction enthalpies of the gaseous cerium molybdates and tungstates from gaseous cerium, molybdenum and tungsten oxides were evaluated theoretically and the obtained values are in reasonable agreement with the experimental one. This article is protected by copyright. All rights reserved.

40 CFR 63.2354 - What performance tests, design evaluations, and performance evaluations must I conduct?

Code of Federal Regulations, 2011 CFR

2011-07-01

... of Gaseous Organic Compounds by Direct Interface Gas Chromatography-Mass Spectrometry (incorporated... Method for Determination of Gaseous Organic Compounds by Direct Interface Gas Chromatography-Mass... Interface Gas Chromatography-Mass Spectrometry (incorporated by reference, see § 63.14),; or (B) For target...

ELECTROSTATIC PRECIPITATION AN AN ALTERNATIVE METHOD FOR /IN VITRO/ EXPOSURES TO MIXTURES OF GASES AND PARTICLES

EPA Science Inventory

There is an increasing interest in examining complex urban air pollution mixtures that include both particulate and gaseous components. Conventional methodologies are unable to expose lung cells in vitro simultaneously to both particulate and gaseous pollutants that are being for...

Conversion of organic solids to hydrocarbons

DOEpatents

Greenbaum, E.

1995-05-23

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

FIELD EVALUATION OF A METHOD FOR ESTIMATING GASEOUS FLUXES FROM AREA SOURCES USING OPEN-PATH FTIR

EPA Science Inventory

The paper gives preliminary results from a field evaluation of a new approach for quantifying gaseous fugitive emissions of area air pollution sources. The approach combines path-integrated concentration data acquired with any path-integrated optical remote sensing (PI-ORS) ...

FIELD EVALUATION OF A METHOD FOR ESTIMATING GASEOUS FLUXES FROM AREA SOURCES USING OPEN-PATH FOURIER TRANSFORM INFRARED

EPA Science Inventory

The paper describes preliminary results from a field experiment designed to evaluate a new approach to quantifying gaseous fugitive emissions from area air pollution sources. The new approach combines path-integrated concentration data acquired with any path-integrated optical re...

Conversion of organic solids to hydrocarbons

DOEpatents

Greenbaum, Elias

1995-01-01

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

High Order Accurate Algorithms for Shocks, Rapidly Changing Solutions and Multiscale Problems

DTIC Science & Technology

2014-11-13

for front propagation with obstacles, and homotopy method for steady states. Applications include high order simulations for 3D gaseous detonations ...obstacles, and homotopy method for steady states. Applications include high order simulations for 3D gaseous detonations , sound generation study via... detonation waves, Combustion and Flame, (02 2013): 0. doi: 10.1016/j.combustflame.2012.10.002 Yang Yang, Ishani Roy, Chi-Wang Shu, Li-Zhi Fang. THE

Method and apparatus for analyzing particle-containing gaseous suspensions

DOEpatents

Solomon, Peter R.; Carangelo, Robert M.; Best, Philip E.

1987-01-01

The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided.

Method and apparatus for analyzing particle-containing gaseous suspensions

DOEpatents

Solomon, P.R.; Carangelo, R.M.; Best, P.E.

1987-03-24

The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided. 51 figs.

Method of testing gas insulated systems for the presence of conducting particles utilizing a gas mixture of nitrogen and sulfur hexafluoride

DOEpatents

Wootton, Roy E.

1979-01-01

A method of testing a gas insulated system for the presence of conducting particles. The method includes inserting a gaseous mixture comprising about 98 volume percent nitrogen and about 2 volume percent sulfur hexafluoride into the gas insulated system at a pressure greater than 60 lb./sq. in. gauge, and then applying a test voltage to the system. If particles are present within the system, the gaseous mixture will break down, providing an indicator of the presence of the particles.

System and method for treatment of a medium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Surinder Prabhjot; Acharya, Harish Radhakrishna; Perry, Robert James

2017-05-23

A system and method for treatment of a medium is disclosed. The system includes a plurality of separator zones and a plurality of heat transfer zones. Each of the separator zone and the heat transfer zone among the plurality of separator zones and heat transfer zones respectively, are disposed alternatively in a flow duct. Further, each separator zone includes an injector device for injecting a sorbent into the corresponding separator zone. Within the corresponding separator zone, the injected sorbent is reacted with a gaseous medium flowing in the flow duct, so as to generate a reacted gaseous medium and amore » reacted sorbent. Further, each heat transfer zone exchanges heat between the reacted gaseous medium fed from the corresponding separator zone and a heat transfer medium.« less

Method of manufacturing aerogel composites

DOEpatents

Cao, W.; Hunt, A.J.

1999-03-09

Disclosed herewith is a process of forming an aerogel composite which comprises introducing a gaseous material into a formed aerogel monolith or powder, and causing decomposition of said gaseous material in said aerogel in amounts sufficient to cause deposition of the decomposition products of the gas on the surfaces of the pores of the said aerogel.

Method of manufacturing aerogel composites

DOEpatents

Cao, Wanqing; Hunt, Arlon Jason

1999-01-01

Disclosed herewith is a process of forming an aerogel composite which comprises introducing a gaseous material into a formed aerogel monolith or powder, and causing decomposition of said gaseous material in said aerogel in amounts sufficient to cause deposition of the decomposition products of the gas on the surfaces of the pores of the said aerogel.

Pilot-scale concept of real-time wind speed-matching wind tunnel for measurements of gaseous emissions

USDA-ARS?s Scientific Manuscript database

Comprehensive control of odors, hydrogen sulfide (H2S), ammonia (NH3) and odorous volatile organic compound (VOC) emissions associated with animal production is a critical need. Current methods utilizing wind tunnels and flux chambers for measurements of gaseous emissions from area sources such as f...

Use of residence time distribution for evaluation of gaseous pollutant volatilization from stored swine manure.

PubMed

Liao, C M

1997-01-01

A quantification analysis for evaluation of gaseous pollutant volatilization as a result of mass transfer from stored swine manure is presented from the viewpoint of residence time distribution. The method is based on evaluating the moments of concentration vs. time curves of both air and gaseous pollutants. The concept of moments of concentration histories is applicable to characterize the dispersal of the supplied air or gaseous pollutant in a ventilated system. The mean age or residence time of airflow can be calculated from an inverse system state matrix [B]-1 of a linear dynamic equation describing the dynamics of gaseous pollutant in a ventilated airspace. The sum elements in an arbitrary row i in matrix [B]-1 is equal to the mean age of airflow in airspace i. The mean age of gaseous pollutant in airspace i can be obtained from the area under the concentration profile divided by the equilibrium concentration reading in that space caused by gaseous pollutant sources. Matrix [B]-1 can also be represented in terms of the inverse local airflow rate matrix ([W]-1), transition probability matrix ([P]), and air volume matrix ([V]) as, [B]-1 = [W]-1[P][V]. Finally the mean age of airflow in a ventilated airspace can be interpreted by the physical characteristics of matrices [W] and [P]. The practical use of the concepts is also applied in a typical pig unit.

On the accuracy of instantaneous gas exchange rates, energy expenditure, and respiratory quotient calculations obtained in indirect whole room calorimetry

USDA-ARS?s Scientific Manuscript database

The molar balance equations of indirect calorimetry are treated from the point of view of cause-effect relationship where the gaseous exchange rates representing the unknown causes heed to be inferred from a known noisy effect – gaseous concentrations. Two methods of such inversion are analyzed. Th...

Method for silicon nitride precursor solids recovery

DOEpatents

Crosbie, Gary M.; Predmesky, Ronald L.; Nicholson, John M.

1992-12-15

Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

Spatially resolved thermal desorption/ionization coupled with mass spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jesse, Stephen; Van Berkel, Gary J; Ovchinnikova, Olga S

2013-02-26

A system and method for sub-micron analysis of a chemical composition of a specimen are described. The method includes providing a specimen for evaluation and a thermal desorption probe, thermally desorbing an analyte from a target site of said specimen using the thermally active tip to form a gaseous analyte, ionizing the gaseous analyte to form an ionized analyte, and analyzing a chemical composition of the ionized analyte. The thermally desorbing step can include heating said thermally active tip to above 200.degree. C., and positioning the target site and the thermally active tip such that the heating step forms themore » gaseous analyte. The thermal desorption probe can include a thermally active tip extending from a cantilever body and an apex of the thermally active tip can have a radius of 250 nm or less.« less

On-line measurement of gaseous iodine species during a PWR severe accident

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haykal, I.; Doizi, D.; Perrin, A.

A long-range remote sensing of severe accidents in nuclear power plants can be obtained by monitoring the online emission of volatile fission products such as xenon, krypton, caesium and iodine. The nuclear accident in Fukushima was ranked at level 7 of the International Nuclear Event Scale by the NISA (Nuclear and Industrial Safety Agency) according to the importance of the radionuclide release and the off-site impact. Among volatile fission products, iodine species are of high concern, since they can be released under aerosols as well as gaseous forms. Four years after the Fukushima accident, the aerosol/gaseous partition is still notmore » clear. Since the iodine gaseous forms are less efficiently trapped by the Filtered Containment Venting Systems than aerosol forms, it is of crucial importance to monitor them on-line during a nuclear accident, in order to improve the source term assessment in such a situation. Therefore, we propose to detect and quantify these iodine gaseous forms by the use of highly sensitive optical methods. (authors)« less

Aerogel composites and method of manufacture

DOEpatents

Cao, Wanqing; Hunt, Arlon Jason

1999-01-01

Disclosed herewith is a process of forming an aerogel composite which comprises introducing a gaseous material into a formed aerogel monolith or powder, and causing decomposition of said gaseous material in said aerogel in amounts sufficient to cause deposition of the decomposition products of the gas on the surfaces of the pores of the said aerogel. Also disclosed are the composites made by the process.

Quantum chemical approach for condensed-phase thermochemistry (IV): Solubility of gaseous molecules

NASA Astrophysics Data System (ADS)

Ishikawa, Atsushi; Kamata, Masahiro; Nakai, Hiromi

2016-07-01

The harmonic solvation model (HSM) was applied to the solvation of gaseous molecules and compared to a procedure based on the ideal gas model (IGM). Examination of 25 molecules showed that (i) the accuracy of ΔGsolv was similar for both methods, but the HSM shows advantages for calculating ΔHsolv and TΔSsolv; (ii) TΔSsolv contributes more than ΔHsolv to ΔGsolv in the HSM, i.e. the solvation of gaseous molecules is entropy-driven, which agrees well with experimental understanding (the IGM does not show this); (iii) the temperature dependence of Henry's law coefficient was correctly reproduced with the HSM.

Phosphonium-based ionic liquids and their use in the capture of polluting gases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Sheng; Wang, Congmin; Luo, Huimin

2017-06-06

An ionic liquid composition having the following chemical structural formula: ##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrocarbon groups containing at least 1 and up to 20 carbon atoms, and X.sup.- is a cyclic anion that possesses a negatively-charged group reactive with a gaseous electrophilic species, particularly carbon dioxide or sulfur dioxide. Methods for capturing a gaseous electrophilic species, such as CO.sub.2 or SO.sub.2, by contacting the gaseous electrophilic species with an ionic liquid according to Formula (1) are also described.

Turbulence coefficients and stability studies for the coaxial flow or dissimiliar fluids. [gaseous core nuclear reactors

NASA Technical Reports Server (NTRS)

Weinstein, H.; Lavan, Z.

1975-01-01

Analytical investigations of fluid dynamics problems of relevance to the gaseous core nuclear reactor program are presented. The vortex type flow which appears in the nuclear light bulb concept is analyzed along with the fluid flow in the fuel inlet region for the coaxial flow gaseous core nuclear reactor concept. The development of numerical methods for the solution of the Navier-Stokes equations for appropriate geometries is extended to the case of rotating flows and almost completes the gas core program requirements in this area. The investigations demonstrate that the conceptual design of the coaxial flow reactor needs further development.

Method of introducing additive into a reaction gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michelfelder, S.; Chughtai, M.Y.

1984-04-03

A method of continuously introducing additive, which is conveyed by gaseous and/or liquid carriers, into a turbulent reaction gas flow in the combustion chamber of a steam generator having dry ash withdrawal for selective removal, in a dry manner, of environmentally harmful gaseous noxious materials, such as sulfur, chlorine, and chlorine compounds, which are contained in a hot reaction gas flow which results after a complete or incomplete flame combustion of solid, liquid, or gaseous fuels. Depending upon the additive introduced, heat is stored and/or used for decomposition reactions. The additive, is first introduced at one or more input locations,more » due to locally different pressure conditions in the combustion chamber, into one or more recirculation flows which are within the system and are closed. The additive is subsequently withdrawn from these recirculation flows and is introduced into the reaction gas flow.« less

Method and system for sensing and identifying foreign particles in a gaseous environment

NASA Technical Reports Server (NTRS)

Choi, Sang H. (Inventor); Park, Yeonjoon (Inventor)

2008-01-01

An optical method and system sense and identify a foreign particle in a gaseous environment. A light source generates light. An electrically-conductive sheet has an array of holes formed through the sheet. Each hole has a diameter that is less than one quarter of the light's wavelength. The sheet is positioned relative to the light source such that the light is incident on one face of the sheet. An optical detector is positioned adjacent the sheet's opposing face and is spaced apart therefrom such that a gaseous environment is adapted to be disposed there between. Alterations in the light pattern detected by the optical detector indicate the presence of a foreign particle in the holes or on the sheet, while a laser induced fluorescence (LIF) signature associated with the foreign particle indicates the identity of the foreign particle.

Modeling the Compression of Merged Compact Toroids by Multiple Plasma Jets

NASA Technical Reports Server (NTRS)

Thio, Y. C. Francis; Knapp, Charles E.; Kirkpatrick, Ron; Rodgers, Stephen L. (Technical Monitor)

2000-01-01

A fusion propulsion scheme has been proposed that makes use of the merging of a spherical distribution of plasma jets to dynamically form a gaseous liner. The gaseous liner is used to implode a magnetized target to produce the fusion reaction in a standoff manner. In this paper, the merging of the plasma jets to form the gaseous liner is investigated numerically. The Los Alamos SPHINX code, based on the smoothed particle hydrodynamics method is used to model the interaction of the jets. 2-D and 3-D simulations have been performed to study the characteristics of the resulting flow when these jets collide. The results show that the jets merge to form a plasma liner that converge radially which may be used to compress the central plasma to fusion conditions. Details of the computational model and the SPH numerical methods will be presented together with the numerical results.

Energy recovery system

DOEpatents

Moore, Albert S.; Verhoff, Francis H.

1980-01-01

The present invention is directed to an improved wet air oxidation system and method for reducing the chemical oxygen demand (COD) of waste water used from scrubbers of coal gasification plants, with this COD reduction being sufficient to effectively eliminate waste water as an environmental pollutant. The improvement of the present invention is provided by heating the air used in the oxidation process to a temperature substantially equal to the temperature in the oxidation reactor before compressing or pressurizing the air. The compression of the already hot air further heats the air which is then passed in heat exchange with gaseous products of the oxidation reaction for "superheating" the gaseous products prior to the use thereof in turbines as the driving fluid. The superheating of the gaseous products significantly minimizes condensation of gaseous products in the turbine so as to provide a substantially greater recovery of mechanical energy from the process than heretofore achieved.

Extruder system and method for treatment of a gaseous medium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Silvi, Norberto; Perry, Robert James; Singh, Surinder Prabhjot

A system for treatment of a gaseous medium, comprises an extruder having a barrel. The extruder further comprises a first inlet port, a second inlet port, and a plurality of outlet ports coupled to the barrel. The first inlet port is configured for feeding a lean sorbent, the second inlet port is configured for feeding a gaseous medium, and the plurality of outlet ports are configured for releasing a plurality of components removed from the gaseous medium. Further, the extruder comprises a plurality of helical elements coupled to a plurality of kneading elements, mounted on a shaft, and disposed withinmore » the barrel. The barrel and the plurality of helical and kneading elements together form an absorption unit and a desorption unit. The first and second inlet ports are formed in the absorption unit and the plurality of outlet ports are formed in the absorption and desorption units.« less

Regenerative process for removal of mercury and other heavy metals from gases containing H.sub.2 and/or CO

DOEpatents

Jadhav, Raja A [Naperville, IL

2009-07-07

A method for removal of mercury from a gaseous stream containing the mercury, hydrogen and/or CO, and hydrogen sulfide and/or carbonyl sulfide in which a dispersed Cu-containing sorbent is contacted with the gaseous stream at a temperature in the range of about 25.degree. C. to about 300.degree. C. until the sorbent is spent. The spent sorbent is contacted with a desorbing gaseous stream at a temperature equal to or higher than the temperature at which the mercury adsorption is carried out, producing a regenerated sorbent and an exhaust gas comprising released mercury. The released mercury in the exhaust gas is captured using a high-capacity sorbent, such as sulfur-impregnated activated carbon, at a temperature less than about 100.degree. C. The regenerated sorbent may then be used to capture additional mercury from the mercury-containing gaseous stream.

Method for the purification of noble gases, nitrogen and hydrogen

DOEpatents

Baker, J.D.; Meikrantz, D.H.; Tuggle, D.G.

1997-09-23

A method and apparatus are disclosed for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes. 15 figs.

Method for the purification of noble gases, nitrogen and hydrogen

DOEpatents

Baker, John D.; Meikrantz, David H.; Tuggle, Dale G.

1997-01-01

A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

Diffusion-based process for carbon dioxide uptake and isoprene emission in gaseous/aqueous two-phase photobioreactors by photosynthetic microorganisms.

PubMed

Bentley, Fiona K; Melis, Anastasios

2012-01-01

Photosynthesis for the generation of fuels and chemicals from cyanobacteria and microalgae offers the promise of a single host organism acting both as photocatalyst and processor, performing sunlight absorption and utilization, as well as CO(2) assimilation and conversion into product. However, there is a need to develop methods for generating, sequestering, and trapping such bio-products in an efficient and cost-effective manner that is suitable for industrial scale-up and exploitation. A sealed gaseous/aqueous two-phase photobioreactor was designed and applied for the photosynthetic generation of volatile isoprene (C(5)H(8)) hydrocarbons, which operates on the principle of spontaneous diffusion of CO(2) from the gaseous headspace into the microalgal or cyanobacterial-containing aqueous phase, followed by photosynthetic CO(2) assimilation and isoprene production by the transgenic microorganisms. Volatile isoprene hydrocarbons were emitted from the aqueous phase and were sequestered into the gaseous headspace. Periodic replacement (flushing) of the isoprene (C(5)H(8)) and oxygen (O(2)) content of the gaseous headspace with CO(2) allowed for the simultaneous harvesting of the photoproducts and replenishment of the CO(2) supply in the gaseous headspace. Reduction in practice of the gaseous/aqueous two-phase photobioreactor is offered in this work with a fed-batch and a semi-continuous culturing system using Synechocystis sp. PCC 6803 heterologously expressing the Pueraria montana (kudzu) isoprene synthase (IspS) gene. Constitutive isoprene production was observed over 192 h of experimentation, coupled with cyanobacterial biomass accumulation. The diffusion-based process in gaseous/aqueous two-phase photobioreactors has the potential to be applied to other high-value photosynthetically derived volatile molecules, emanating from a variety of photosynthetic microorganisms. Copyright © 2011 Wiley Periodicals, Inc.

Does rational selection of training and test sets improve the outcome of QSAR modeling?

PubMed

Martin, Todd M; Harten, Paul; Young, Douglas M; Muratov, Eugene N; Golbraikh, Alexander; Zhu, Hao; Tropsha, Alexander

2012-10-22

Prior to using a quantitative structure activity relationship (QSAR) model for external predictions, its predictive power should be established and validated. In the absence of a true external data set, the best way to validate the predictive ability of a model is to perform its statistical external validation. In statistical external validation, the overall data set is divided into training and test sets. Commonly, this splitting is performed using random division. Rational splitting methods can divide data sets into training and test sets in an intelligent fashion. The purpose of this study was to determine whether rational division methods lead to more predictive models compared to random division. A special data splitting procedure was used to facilitate the comparison between random and rational division methods. For each toxicity end point, the overall data set was divided into a modeling set (80% of the overall set) and an external evaluation set (20% of the overall set) using random division. The modeling set was then subdivided into a training set (80% of the modeling set) and a test set (20% of the modeling set) using rational division methods and by using random division. The Kennard-Stone, minimal test set dissimilarity, and sphere exclusion algorithms were used as the rational division methods. The hierarchical clustering, random forest, and k-nearest neighbor (kNN) methods were used to develop QSAR models based on the training sets. For kNN QSAR, multiple training and test sets were generated, and multiple QSAR models were built. The results of this study indicate that models based on rational division methods generate better statistical results for the test sets than models based on random division, but the predictive power of both types of models are comparable.

Development of a gas chromatography-mass spectrometry method for the determination of pesticides in gaseous and particulate phases in the atmosphere.

PubMed

Borrás, E; Sánchez, P; Muñoz, A; Tortajada-Genaro, L A

2011-08-05

A reliable multi-residue method for determining gaseous and particulate phase pesticides in atmospheric samples has been developed. This method, based on full scan gas chromatography-mass spectrometry (GC-MS), allowed the proper determination of sixteen relevant pesticides, in a wide range of concentrations and without the influence of interferences. The pesticides were benfluralin, bitertanol, buprofezin, chlorfenvinphos, chlorpyrifos, chlorpyrifos-methyl, ethalfluralin, fenthion, lindane, malathion, methidathion, propachlor, propanil, pyriproxifen, tebuconazol and trifluralin. Comparisons of two types of sampling filters (quartz and glass fibre) and four types of solid-phase cartridges (XAD-2, XAD-4, Florisil and Orbo-49P) showed that the most suitable supports were glass fibre filter for particulate pesticides and XAD-2 and XAD-4 cartridges for gaseous pesticides (>95% recovery). Evaluations of elution solvents for ultrasonic-assisted extraction demonstrated that isooctane is better than ethylacetate, dichloromethane, methanol or a mixture of acetone:hexane (1:1). Recovery assays and the standard addition method were performed to validate the proposed methodology. Moreover, large simulator chamber experiments allowed the best study of the gas-particle partitioning of pesticides for testing the sampling efficiency for the validation of an analytical multiresidue method for pesticides in air. Satisfactory analytical parameters were obtained, with a repeatability of 5±1%, a reproducibility of 13±3% and detection limits of 0.05-0.18 pg m(-3) for the particulate phase and 26-88 pg m(-3) for the gaseous phase. Finally, the methodology was successfully applied to rural and agricultural samples in the Mediterranean area. Copyright © 2011 Elsevier B.V. All rights reserved.

A multi-residue method for characterization of endocrine disruptors in gaseous and particulate phases of ambient air

NASA Astrophysics Data System (ADS)

Alliot, Fabrice; Moreau-Guigon, Elodie; Bourges, Catherine; Desportes, Annie; Teil, Marie-Jeanne; Blanchard, Martine; Chevreuil, Marc

2014-08-01

A number of semi-volatile compounds occur in indoor air most of them being considered as potent endocrine disruptors and thus, exerting a possible impact upon health. To assess their concentration levels in indoor air, we developed and validated a method for sampling and multi-residue analysis of 58 compounds including phthalates, polycyclic aromatic hydrocarbons (PAHs), polybromodiphenylethers (PBDEs), polychlorobiphenyls (PCBs), parabens, bisphenol A (BPA) and tetrabromobisphenol A (TBBPA) in gaseous and particulate phases of air. We validated each step of procedures from extraction until analysis. Matrice spiking were performed at extraction, fractionation and purification stages. The more volatile compounds were analyzed with a gas chromatography system coupled with a mass spectrometer (GC/MS) or with a tandem mass spectrometer (GC/MS/MS). The less volatile compounds were analyzed with a liquid chromatography system coupled with a tandem mass spectrometer (LC/MS/MS). Labeled internal standard method was used ensuring high quantification accuracy. The instrumental detection limits were under 1 pg for all compounds and therefore, a limit of quantification averaging 1 pg m-3 for the gaseous and the particulate phases and a volume of 150 m3, except for phthalates, phenol compounds and BDE-209. Satisfactory recoveries were found except for phenol compounds. That method was successfully applied to several indoor air samples (office, apartment and day nursery) and most of the targeted compounds were quantified, mainly occurring in the gaseous phase. The most abundant were phthalates (up to 918 ng m-3 in total air), followed by PCBs > parabens > BPA > PAHs > PBDEs.

Development of measures to improve technologies of energy recovery from gaseous wastes of oil shale processing

NASA Astrophysics Data System (ADS)

Tugov, A. N.; Ots, A.; Siirde, A.; Sidorkin, V. T.; Ryabov, G. A.

2016-06-01

Prospects of the use of oil shale are associated with its thermal processing for the production of liquid fuel, shale oil. Gaseous by-products, such as low-calorie generator gas with a calorific value up to 4.3MJ/m3 or semicoke gas with a calorific value up to 56.57 MJ/m3, are generated depending on the oil shale processing method. The main methods of energy recovery from these gases are either their cofiring with oil shale in power boilers or firing only under gaseous conditions in reconstructed or specially designed for this fuel boilers. The possible use of gaseous products of oil shale processing in gas-turbine or gas-piston units is also considered. Experiments on the cofiring of oil shale gas and its gaseous processing products have been carried out on boilers BKZ-75-39FSl in Kohtla-Järve and on the boiler TP-101 of the Estonian power plant. The test results have shown that, in the case of cofiring, the concentration of sulfur oxides in exhaust gases does not exceed the level of existing values in the case of oil shale firing. The low-temperature corrosion rate does not change as compared to the firing of only oil shale, and, therefore, operation conditions of boiler back-end surfaces do not worsen. When implementing measures to reduce the generation of NO x , especially of flue gas recirculation, it has been possible to reduce the emissions of nitrogen oxides in the whole boiler. The operation experience of the reconstructed boilers BKZ-75-39FSl after their transfer to the firing of only gaseous products of oil shale processing is summarized. Concentrations of nitrogen and sulfur oxides in the combustion products of semicoke and generator gases are measured. Technical solutions that made it possible to minimize the damage to air heater pipes associated with the low-temperature sulfur corrosion are proposed and implemented. The technological measures for burners of new boilers that made it possible to burn gaseous products of oil shale processing with low emissions of nitrogen oxides are developed.

[Correlation between gaseous exchange rate, body temperature, and mitochondrial protein content in the liver of mice].

PubMed

Muradian, Kh K; Utko, N O; Mozzhukhina, T H; Pishel', I M; Litoshenko, O Ia; Bezrukov, V V; Fraĭfel'd, V E

2002-01-01

Correlative and regressive relations between the gaseous exchange, thermoregulation and mitochondrial protein content were analyzed by two- and three-dimensional statistics in mice. It has been shown that the pair wise linear methods of analysis did not reveal any significant correlation between the parameters under exploration. However, it became evident at three-dimensional and non-linear plotting for which the coefficients of multivariable correlation reached and even exceeded 0.7-0.8. The calculations based on partial differentiation of the multivariable regression equations allow to conclude that at certain values of VO2, VCO2 and body temperature negative relations between the systems of gaseous exchange and thermoregulation become dominating.

METHOD FOR THE PREPARATION OF BINARY NITROGEN-FLUORINE COMPOUNDS

DOEpatents

Frazer, J.W.

1962-05-01

A process is given for preparing binary nitrogenfluorine compounds, in particular, tetrafluorohydrazine (N/sub 2/F/sub 4/) and difluorodiazine (N/sub 2/ F/sub 2/), The process comprises subjecting gaseous nitrogen trifluoride to the action of an alternating current electrical glow discharge in the presence of mercury vapors. By the action of the electrical discharge, the nitrogen trifluoride is converted into a gaseous product comprising a mixture of tetrafluorohydrazine, the isomers of difluorodiazine, and other impurities including nitrogen, nitrogen oxides, silicon tetrafiuoride, and unreacted nitrogen trifluoride. The gaseous products and impurities are passed into a trap maintained at about - 196 deg C to freeze out the desired products and impurities with the exception of nitregen gas which passes off from the trap and is discarded. Subsequently, the desired products and remaining impurities are warmed to the gaseous state and passed through a silica gel trap maintained at about - 55DEC, wherein the desired tetrafluorohydrazine and difluorodiazine products are retained while the remaining gaseous impurities pass therethrough. The desired products are volatilized from the silica gel trap by heating and then separated by gas chrounatography means into the respective tetrafluorohydrazine and difluorodiazine products. (A.e.C)

Apparatus for externally controlled closed-loop feedback digital epitaxy

DOEpatents

Eres, D.; Sharp, J.W.

1996-07-30

A method and apparatus for digital epitaxy are disclosed. The apparatus includes a pulsed gas delivery assembly that supplies gaseous material to a substrate to form an adsorption layer of the gaseous material on the substrate. Structure is provided for measuring the isothermal desorption spectrum of the growth surface to monitor the active sites which are available for adsorption. The vacuum chamber housing the substrate facilitates evacuation of the gaseous material from the area adjacent the substrate following exposure. In use, digital epitaxy is achieved by exposing a substrate to a pulse of gaseous material to form an adsorption layer of the material on the substrate. The active sites on the substrate are monitored during the formation of the adsorption layer to determine if all the active sites have been filled. Once the active sites have been filled on the growth surface of the substrate, the pulse of gaseous material is terminated. The unreacted portion of the gas pulse is evacuated by continuous pumping. Subsequently, a second pulse is applied when availability of active sites is determined by studying the isothermal desorption spectrum. These steps are repeated until a thin film of sufficient thickness is produced. 5 figs.

Apparatus for externally controlled closed-loop feedback digital epitaxy

DOEpatents

Eres, Djula; Sharp, Jeffrey W.

1996-01-01

A method and apparatus for digital epitaxy. The apparatus includes a pulsed gas delivery assembly that supplies gaseous material to a substrate to form an adsorption layer of the gaseous material on the substrate. Structure is provided for measuring the isothermal desorption spectrum of the growth surface to monitor the active sites which are available for adsorption. The vacuum chamber housing the substrate facilitates evacuation of the gaseous material from the area adjacent the substrate following exposure. In use, digital epitaxy is achieved by exposing a substrate to a pulse of gaseous material to form an adsorption layer of the material on the substrate. The active sites on the substrate are monitored during the formation of the adsorption layer to determine if all the active sites have been filled. Once the active sites have been filled on the growth surface of the substrate, the pulse of gaseous material is terminated. The unreacted portion of the gas pulse is evacuated by continuous pumping. Subsequently, a second pulse is applied when availability of active sites is determined by studying the isothermal desorption spectrum. These steps are repeated until a thin film of sufficient thickness is produced.

Computer program for calculation of complex chemical equilibrium compositions and applications. Supplement 1: Transport properties

NASA Technical Reports Server (NTRS)

Gordon, S.; Mcbride, B.; Zeleznik, F. J.

1984-01-01

An addition to the computer program of NASA SP-273 is given that permits transport property calculations for the gaseous phase. Approximate mixture formulas are used to obtain viscosity and frozen thermal conductivity. Reaction thermal conductivity is obtained by the same method as in NASA TN D-7056. Transport properties for 154 gaseous species were selected for use with the program.

Quasi-2D Unsteady Flow Procedure for Real Fluids

DTIC Science & Technology

2006-05-17

Reynolds number and the wall surface roughness . For the viscous flow examples presented below, the Churchill correlation7 was used to determine single...methods is discussed to aid in selection for specific applications. Results for the transient flows of gaseous nitrogen and water in a simple pipe ...gaseous nitrogen and water in a simple pipe network are presented to demonstrate the capability of the current techniques and the unsteady flow

Interactions of gaseous molecules with X-ray photons and photoelectrons in AP-XPS study of solid surface in gas phase.

PubMed

Tao, Franklin Feng; Nguyen, Luan

2018-04-18

Studies of the surface of a catalyst in the gas phase via photoelectron spectroscopy is an important approach to establish a correlation between the surface of a catalyst under reaction conditions or during catalysis and its corresponding catalytic performance. Unlike the well understood interactions between photoelectrons and the atomic layers of a surface in ultrahigh vacuum (UHV) and the well-developed method of quantitative analysis of a solid surface in UHV, a fundamental understanding of the interactions between X-ray photons and gaseous molecules and between photoelectrons and molecules of the gas phase in ambient pressure X-ray photoelectron spectroscopy (AP-XPS) is lacking. Through well designed experiments, here the impact of the interactions between photoelectrons and gaseous molecules and interactions between X-ray photons and gaseous molecules on the intensity of the collected photoelectrons have been explored. How the changes in photoelectron intensity resulting from these interactions influence measurement of the authentic atomic ratio of element M to A of a solid surface has been discussed herein, and methods to correct the measured nominal atomic ratio of two elements of a solid surface upon travelling through a gas phase to its authentic atomic ratio have been developed.

Tetracationic cyclophanes and their use in the sequestration of polyaromatic hydrocarbons by way of complexation

DOEpatents

Stoddart, J. Fraser; Barnes, Jonathan C.; Juri, Michal

2016-03-22

Novel tetracationic cyclophanes incorporating .pi.-electron poor organic compounds into their ring structures, as well as methods of making the cyclophanes, are provided. The cyclophanes are able to form electron donor-acceptor complexes with a variety of polyaromatic hydrocarbons (PAHs) ranging in size, shape, and electron density. Also provided are methods of using the cyclophanes in the sequestration of PAHs in liquid or gaseous samples, the separation of PAHs from liquid or gaseous samples, the detection of PAHs in liquid samples, and the exfoliation of graphene via pseudopolyrotaxane formation.

Method and Apparatus for Concentrating Vapors for Analysis

DOEpatents

Grate, Jay W.; Baldwin, David L.; Anheier, Jr., Norman C.

2008-10-07

An apparatus and method are disclosed for pre-concentrating gaseous vapors for analysis. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable. Vapors sorbed and concentrated within the bed of the apparatus can be thermally desorbed achieving at least partial separation of vapor mixtures. The apparatus is suitable, e.g., for preconcentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than for direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications.

Method for machining steel with diamond tools

DOEpatents

Casstevens, J.M.

1984-01-01

The present invention is directed to a method for machine optical quality finishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

Method for machining steel with diamond tools

DOEpatents

Casstevens, John M.

1986-01-01

The present invention is directed to a method for machining optical quality inishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

Enhancement of the Norfloxacin Antibiotic Activity by Gaseous Contact with the Essential Oil of Croton zehntneri

PubMed Central

Coutinho, HDM; Matias, EFF; Santos, KKA; Tintino, SR; Souza, CES; Guedes, GMM; Santos, FAD; Costa, JGM; Falcão-Silva, VS; Siqueira-Júnior, JP

2010-01-01

This is the first on the modulation of norfloxacin antibiotic activity by the volatile compounds of an essential oil. We report the chemical composition and antibiotic modifying activity of the essential oil extracted from the leaves of Croton zehntneri Pax et Hoffm (variety estragole), using the minimal inhibitory dose method and gaseous contact. The leaves of Croton zehntneri Pax et Hoffm (Euphorbiaceae) were subjected to hydrodistillation, and the essential oil extracted was examined with respect to the chemical composition, by gas chromatography-mass spectrometry (GC/MS), and to inhibitory activity of efflux pump by gaseous contact. The main component of the essential oil of C. zehntneri was estragole (76,8%). The gaseous components of the oil enhanced the inhibition zone of norfloxacin in 39,5%. This result shows that this oil influences the antibiotic activity of norfloxacin, possibly affecting the bacterial NorA efflux system, and may be used as an adjuvant in the antibiotic therapy of multidrug resistant pathogens. PMID:21264094

Two-tier tube-trailer pressure consolidation operation method for hydrogen refueling station cost reduction

DOE PAGES

Reddi, Krishna; Elgowainy, Amgad; Rustagi, Neha; ...

2018-01-10

An operation strategy known as two-tier “pressure consolidation” of delivered tube-trailers (or equivalent supply storage) has been developed to maximize the throughput at gaseous hydrogen refueling stations (HRSs) for fuel cell electric vehicles (FCEVs). The high capital costs of HRSs and the consequent high investment risk are deterring growth of the infrastructure needed to promote the deployment of FCEVs. Stations supplied by gaseous hydrogen will be necessary for FCEV deployment in both the near and long term. Here, the two-tier pressure consolidation method enhances gaseous HRSs in the following ways: (1) reduces the capital cost compared with conventional stations, asmore » well as those operating according to the original pressure consolidation approach described by Elgowainy et al. (2014) [1], (2) minimizes pressure cycling of HRS supply storage relative to the original pressure consolidation approach; and (3) increases use of the station’s supply storage (or delivered tube-trailers) while maintaining higher state-of-charge vehicle fills.« less

Two-tier tube-trailer pressure consolidation operation method for hydrogen refueling station cost reduction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reddi, Krishna; Elgowainy, Amgad; Rustagi, Neha

An operation strategy known as two-tier “pressure consolidation” of delivered tube-trailers (or equivalent supply storage) has been developed to maximize the throughput at gaseous hydrogen refueling stations (HRSs) for fuel cell electric vehicles (FCEVs). The high capital costs of HRSs and the consequent high investment risk are deterring growth of the infrastructure needed to promote the deployment of FCEVs. Stations supplied by gaseous hydrogen will be necessary for FCEV deployment in both the near and long term. Here, the two-tier pressure consolidation method enhances gaseous HRSs in the following ways: (1) reduces the capital cost compared with conventional stations, asmore » well as those operating according to the original pressure consolidation approach described by Elgowainy et al. (2014) [1], (2) minimizes pressure cycling of HRS supply storage relative to the original pressure consolidation approach; and (3) increases use of the station’s supply storage (or delivered tube-trailers) while maintaining higher state-of-charge vehicle fills.« less

Thermal discharges from Paducah Gaseous Diffusion Plant outfalls: Impacts on stream temperatures and fauna of Little Bayou and Big Bayou Creeks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roy, W.K.; Ryon, M.G.; Hinzman, R.L.

1996-03-01

The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the US Enrichment Corporationmore » (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7 C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.« less

Thermal Discharges from Paducah Gaseous Diffusion Plant Outfalls: Impacts on Stream Temperatures and Fauna of Little Bayou and Big Bayou Creeks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roy, W.K.

1999-01-01

The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the United States Enrichmentmore » Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.« less

2D spatiotemporal visualization system of expired gaseous ethanol after oral administration for real-time illustrated analysis of alcohol metabolism.

PubMed

Wang, Xin; Ando, Eri; Takahashi, Daishi; Arakawa, Takahiro; Kudo, Hiroyuki; Saito, Hirokazu; Mitsubayashi, Kohji

2010-08-15

A novel 2-dimensional spatiotemporal visualization system of expired gaseous ethanol after oral administration for real-time illustrated analysis of alcohol metabolism has been developed, which employed a low level light CCD camera to detect chemiluminescence (CL) generated by catalytic reactions of standard gaseous ethanol and expired gaseous ethanol after oral administration. First, the optimization of the substrates for visualization and the concentration of luminol solution for CL were investigated. The cotton mesh and 5.0 mmol L(-1) luminol solution were selected for further investigations and this system is useful for 0.1-20.0 mmol L(-1) of H(2)O(2) solution. Then, the effect of pH condition of Tris-HCl buffer solution was also evaluated with CL intensity and under the Tris-HCl buffer solution pH 10.1, a wide calibration range of standard gaseous ethanol (30-400 ppm) was obtained. Finally, expired air of 5 healthy volunteers after oral administration was measured at 15, 30, 45, 60, 75, 90, 105 and 120 min after oral administration, and this system showed a good sensitivity on expired gaseous ethanol for alcohol metabolism. The peaks of expired gaseous ethanol concentration appeared within 30 min after oral administration. During the 30 min after oral administration, the time variation profile based on mean values showed the absorption and distribution function, and the values onward showed the elimination function. The absorption and distribution of expired gaseous ethanol in 5 healthy volunteers following first-order absorption process were faster than the elimination process, which proves efficacious of this system for described alcohol metabolism in healthy volunteers. This system is expected to be used as a non-invasive method to detect VOCs as well as several other drugs in expired air for clinical purpose. Copyright 2010 Elsevier B.V. All rights reserved.

Dry-Enzyme Test For Gaseous Chemicals

NASA Technical Reports Server (NTRS)

Barzana, Eduardo; Karel, Marcus; Klibanov, Alexander

1990-01-01

Simple, dry-chemical test detects ethanol in human breath. Method of test also adapted to detection of such toxic chemicals as formaldehyde in airstreams. Used qualitatively to detect chemical compounds above present level; for example, ethanol above legal level for driving. Also used to indicate quantitatively concentrations of compounds. Involves dry enzyme and color indicator. Adapted to detect any gaseous compound transformed by enzymes to produce change evident to human eye or to instrument.

Carbon source/sink function of a subtropical, eutrophic lake determined from an overall mass balance and a gas exchange and carbon burial balance.

PubMed

Yang, Hong; Xing, Yangping; Xie, Ping; Ni, Leyi; Rong, Kewen

2008-02-01

Although studies on carbon burial in lake sediments have shown that lakes are disproportionately important carbon sinks, many studies on gaseous carbon exchange across the water-air interface have demonstrated that lakes are supersaturated with CO(2) and CH(4) causing a net release of CO(2) and CH(4) to the atmosphere. In order to more accurately estimate the net carbon source/sink function of lake ecosystems, a more comprehensive carbon budget is needed, especially for gaseous carbon exchange across the water-air interface. Using two methods, overall mass balance and gas exchange and carbon burial balance, we assessed the carbon source/sink function of Lake Donghu, a subtropical, eutrophic lake, from April 2003 to March 2004. With the overall mass balance calculations, total carbon input was 14 905 t, total carbon output was 4950 t, and net carbon budget was +9955 t, suggesting that Lake Donghu was a great carbon sink. For the gas exchange and carbon burial balance, gaseous carbon (CO(2) and CH(4)) emission across the water-air interface totaled 752 t while carbon burial in the lake sediment was 9477 t. The ratio of carbon emission into the atmosphere to carbon burial into the sediment was only 0.08. This low ratio indicates that Lake Donghu is a great carbon sink. Results showed good agreement between the two methods with both showing Lake Donghu to be a great carbon sink. This results from the high primary production of Lake Donghu, substantive allochthonous carbon inputs and intensive anthropogenic activity. Gaseous carbon emission accounted for about 15% of the total carbon output, indicating that the total output would be underestimated without including gaseous carbon exchange.

Laser-induced fluorescence method for on-line molecular isotopologues of iodine-127, iodine-129, iodine-131 detected in gaseous media using a tunable diode laser

NASA Astrophysics Data System (ADS)

Kireev, S. V.; Shnyrev, S. L.; Sobolevsky, I. V.

2016-06-01

The letter reports on the development of a laser-induced fluorescence method for on-line selective measurement of 127I2, 129I2, 131I2, 129I127I, 127I131I, 129I131I isotopologue concentrations in gaseous media. The method is based on the excitation of molecular iodine isotopologues’ fluorescence by tunable diode laser (632-637 nm) radiation at three or four wavelengths corresponding to the 127I2, 131I2, 129I127I, 129I131I absorption line centers. Boundary relations for concentrations of simultaneously measured iodine isotopologues is about 10-5-10-6.

An analysis of the symmetry issue in the ℓ-distribution method of gas radiation in non-uniform gaseous media

NASA Astrophysics Data System (ADS)

André, Frédéric

2017-03-01

The recently proposed ℓ-distribution/ICE (Iterative Copula Evaluation) method of gas radiation suffers from symmetry issues when applied in highly non-isothermal and non-homogeneous gaseous media. This problem is studied in a detailed theoretical way. The objective of the present paper is: 1/to provide a mathematical analysis of this problem of symmetry and, 2/to suggest a decisive factor, defined in terms of the ratio between the narrow band Planck and Rosseland mean absorption coefficients, to handle this issue. Comparisons of model predictions with reference LBL calculations show that the proposed criterion improves the accuracy of the intuitive ICE method for applications in highly non-uniform gases at high temperatures.

Devices and methods to detect and quantify trace gases

DOEpatents

Allendorf, Mark D.; Robinson, Alex

2016-05-03

Sensing devices based on a surface acoustic wave ("SAW") device coated with an absorbent crystalline or amorphous layer for detecting at least one chemical analyte in a gaseous carrier. Methods for detecting the presence of a chemical analyte in a gaseous carrier using such devices are also disclosed. The sensing devices and methods for their use may be configured for sensing chemical analytes selected from the group consisting of water vapor, carbon dioxide, methanol, ethanol, carbon monoxide, nitric oxide, nitrous oxide, organic amines, organic compounds containing NO.sub.2 groups, halogenated hydrocarbons, acetone, hexane, toluene, isopropanol, alcohols, alkanes, alkenes, benzene, functionalized aromatics, ammonia (NH.sub.3), phosgene (COCl.sub.2), sulfur mustard, nerve agents, sulfur dioxide, tetrahydrofuran (THF) and methyltertbutyl ether (MTBE) and combinations thereof.

Method and apparatus for physical separation of different sized nanostructures

DOEpatents

Roberts, Christopher B.; Saunders, Steven R.

2012-07-10

The present application provides apparatuses and methods for the size-selective fractionation of ligand-capped nanoparticles that utilizes the tunable thermophysical properties of gas-expanded liquids. The nanoparticle size separation processes are based on the controlled reduction of the solvent strength of an organic phase nanoparticle dispersion through increases in concentration of the antisolvent gas, such as CO.sub.2, via pressurization. The method of nanomaterial separation contains preparing a vessel having a solvent and dispersed nanoparticles, pressurizing the chamber with a gaseous antisolvent, and causing a first amount of the nanoparticles to precipitate, transporting the solution to a second vessel, pressurizing the second vessel with the gaseous antisolvent and causing further nanoparticles to separate from the solution.

Computed tomography measurement of gaseous fuel concentration by infrared laser light absorption

NASA Astrophysics Data System (ADS)

Kawazoe, Hiromitsu; Inagaki, Kazuhisa; Emi, Y.; Yoshino, Fumio

1997-11-01

A system to measure gaseous hydrocarbon distributions was devised, which is based on IR light absorption by C-H stretch mode of vibration and computed tomography method. It is called IR-CT method in the paper. Affection of laser light power fluctuation was diminished by monitoring source light intensity by the second IR light detector. Calibration test for methane fuel was carried out to convert spatial data of line absorption coefficient into quantitative methane concentration. This system was applied to three flow fields. The first is methane flow with lifted flame which is generated by a gourd-shaped fuel nozzle. Feasibility of the IR-CT method was confirmed through the measurement. The second application is combustion field with diffusion flame. Calibration to determine absorptivity was undertaken, and measured line absorption coefficient was converted spatial fuel concentration using corresponding temperature data. The last case is modeled in cylinder gas flow of internal combustion engine, where gaseous methane was led to the intake valve in steady flow state. The fuel gas flow simulates behavior of gaseous gasoline which is evaporated at intake valve tulip. Computed tomography measurement of inner flow is essentially difficult because of existence of surrounding wall. In this experiment, IR laser beam was led to planed portion by IR light fiber. It is found that fuel convection by airflow takes great part in air-fuel mixture formation and the developed IR-CT system to measure fuel concentration is useful to analyze air-fuel mixture formation process and to develop new combustors.

Measurement of atmospheric mercury species with manual sampling and analysis methods in a case study in Indiana

USGS Publications Warehouse

Risch, M.R.; Prestbo, E.M.; Hawkins, L.

2007-01-01

Ground-level concentrations of three atmospheric mercury species were measured using manual sampling and analysis to provide data for estimates of mercury dry deposition. Three monitoring stations were operated simultaneously during winter, spring, and summer 2004, adjacent to three mercury wet-deposition monitoring stations in northern, central, and southern Indiana. The monitoring locations differed in land-use setting and annual mercury-emissions level from nearby sources. A timer-controlled air-sampling system that contained a three-part sampling train was used to isolate reactive gaseous mercury, particulate-bound mercury, and elemental mercury. The sampling trains were exchanged every 6 days, and the mercury species were quantified in a laboratory. A quality-assurance study indicated the sampling trains could be held at least 120 h without a significant change in reactive gaseous or particulate-bound mercury concentrations. The manual sampling method was able to provide valid mercury concentrations in 90 to 95% of samples. Statistical differences in mercury concentrations were observed during the project. Concentrations of reactive gaseous and elemental mercury were higher in the daytime samples than in the nighttime samples. Concentrations of reactive gaseous mercury were higher in winter than in summer and were highest at the urban monitoring location. The results of this case study indicated manual sampling and analysis could be a reliable method for measurement of atmospheric mercury species and has the capability for supplying representative concentrations in an effective manner from a long-term deposition-monitoring network. ?? 2007 Springer Science+Business Media B.V.

Mixed species radioiodine air sampling readout and dose assessment system

DOEpatents

Distenfeld, Carl H.; Klemish, Jr., Joseph R.

1978-01-01

This invention provides a simple, reliable, inexpensive and portable means and method for determining the thyroid dose rate of mixed airborne species of solid and gaseous radioiodine without requiring highly skilled personnel, such as health physicists or electronics technicians. To this end, this invention provides a means and method for sampling a gas from a source of a mixed species of solid and gaseous radioiodine for collection of the mixed species and readout and assessment of the emissions therefrom by cylindrically, concentrically and annularly molding the respective species around a cylindrical passage for receiving a conventional probe-type Geiger-Mueller radiation detector.

Method and apparatus for concentrating vapors for analysis

DOEpatents

Grate, Jay W [West Richland, WA; Baldwin, David L [Kennewick, WA; Anheier, Jr., Norman C.

2012-06-05

A pre-concentration device and a method are disclosed for concentrating gaseous vapors for analysis. Vapors sorbed and concentrated within the bed of the pre-concentration device are thermally desorbed, achieving at least partial separation of the vapor mixtures. The pre-concentration device is suitable, e.g., for pre-concentration and sample injection, and provides greater resolution of peaks for vapors within vapor mixtures, yielding detection levels that are 10-10,000 times better than direct sampling and analysis systems. Features are particularly useful for continuous unattended monitoring applications. The invention finds application in conjunction with, e.g., analytical instruments where low detection limits for gaseous vapors are desirable.

A simple and highly sensitive colorimetric detection method for gaseous formaldehyde.

PubMed

Feng, Liang; Musto, Christopher J; Suslick, Kenneth S

2010-03-31

A colorimetric detection method using amine-functionalized polymer films doped with a pH indicator has been developed for the rapid, sensitive, and quantitative detection of gaseous formaldehyde at concentrations well below the immediately dangerous to life or health (IDLH) limit. In 1 min, visible color changes are easily observed, even down to the permissible exposure limit (PEL) at 750 ppb. The limit of detection is below 50 ppb (7% of the PEL) after 10 min of exposure. This sensor is essentially unaffected by changes in humidity or temperature (4 to 50 degrees C) and is not sensitive to common interferents.

Correlation and prediction of gaseous diffusion coefficients.

NASA Technical Reports Server (NTRS)

Marrero, T. R.; Mason, E. A.

1973-01-01

A new correlation method for binary gaseous diffusion coefficients from very low temperatures to 10,000 K is proposed based on an extended principle of corresponding states, and having greater range and accuracy than previous correlations. There are two correlation parameters that are related to other physical quantities and that are predictable in the absence of diffusion measurements. Quantum effects and composition dependence are included, but high-pressure effects are not. The results are directly applicable to multicomponent mixtures.

Lifetime prediction and reliability estimation methodology for Stirling-type pulse tube refrigerators by gaseous contamination accelerated degradation testing

NASA Astrophysics Data System (ADS)

Wan, Fubin; Tan, Yuanyuan; Jiang, Zhenhua; Chen, Xun; Wu, Yinong; Zhao, Peng

2017-12-01

Lifetime and reliability are the two performance parameters of premium importance for modern space Stirling-type pulse tube refrigerators (SPTRs), which are required to operate in excess of 10 years. Demonstration of these parameters provides a significant challenge. This paper proposes a lifetime prediction and reliability estimation method that utilizes accelerated degradation testing (ADT) for SPTRs related to gaseous contamination failure. The method was experimentally validated via three groups of gaseous contamination ADT. First, the performance degradation model based on mechanism of contamination failure and material outgassing characteristics of SPTRs was established. Next, a preliminary test was performed to determine whether the mechanism of contamination failure of the SPTRs during ADT is consistent with normal life testing. Subsequently, the experimental program of ADT was designed for SPTRs. Then, three groups of gaseous contamination ADT were performed at elevated ambient temperatures of 40 °C, 50 °C, and 60 °C, respectively and the estimated lifetimes of the SPTRs under normal condition were obtained through acceleration model (Arrhenius model). The results show good fitting of the degradation model with the experimental data. Finally, we obtained the reliability estimation of SPTRs through using the Weibull distribution. The proposed novel methodology enables us to take less than one year time to estimate the reliability of the SPTRs designed for more than 10 years.

Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

DOEpatents

Bennett, Ralph G.; Christian, Jerry D.; Grover, S. Blaine; Petti, David A.; Terry, William K.; Yoon, Woo Y.

1998-01-01

An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

DOEpatents

Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

1998-09-01

An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

Method for removing sulfur oxide from waste gases and recovering elemental sulfur

DOEpatents

Moore, Raymond H.

1977-01-01

A continuous catalytic fused salt extraction process is described for removing sulfur oxides from gaseous streams. The gaseous stream is contacted with a molten potassium sulfate salt mixture having a dissolved catalyst to oxidize sulfur dioxide to sulfur trioxide and molten potassium normal sulfate to solvate the sulfur trioxide to remove the sulfur trioxide from the gaseous stream. A portion of the sulfur trioxide loaded salt mixture is then dissociated to produce sulfur trioxide gas and thereby regenerate potassium normal sulfate. The evolved sulfur trioxide is reacted with hydrogen sulfide as in a Claus reactor to produce elemental sulfur. The process may be advantageously used to clean waste stack gas from industrial plants, such as copper smelters, where a supply of hydrogen sulfide is readily available.

System and process for upgrading hydrocarbons

DOEpatents

Bingham, Dennis N.; Klingler, Kerry M.; Smith, Joseph D.; Turner, Terry D.; Wilding, Bruce M.

2015-08-25

In one embodiment, a system for upgrading a hydrocarbon material may include a black wax upgrade subsystem and a molten salt gasification (MSG) subsystem. The black wax upgrade subsystem and the MSG subsystem may be located within a common pressure boundary, such as within a pressure vessel. Gaseous materials produced by the MSG subsystem may be used in the process carried out within the black wax upgrade subsystem. For example, hydrogen may pass through a gaseous transfer interface to interact with black wax feed material to hydrogenate such material during a cracking process. In one embodiment, the gaseous transfer interface may include one or more openings in a tube or conduit which is carrying the black wax material. A pressure differential may control the flow of hydrogen within the tube or conduit. Related methods are also disclosed.

Impact of the volume of gaseous phase in closed reactors on ANC results and modelling

NASA Astrophysics Data System (ADS)

Drapeau, Clémentine; Delolme, Cécile; Lassabatere, Laurent; Blanc, Denise

2016-04-01

The understanding of the geochemical behavior of polluted solid materials is often challenging and requires huge expenses of time and money. Nevertheless, given the increasing amounts of polluted solid materials and related risks for the environment, it is more and more crucial to understand the leaching of majors and trace metals elements from these matrices. In the designs of methods to quantify pollutant solubilization, the combination of experimental procedures with modeling approaches has recently gained attention. Among usual methods, some rely on the association of ANC and geochemical modeling. ANC experiments - Acid Neutralization Capacity - consists in adding known quantities of acid or base to a mixture of water and contaminated solid materials at a given liquid / solid ratio in closed reactors. Reactors are agitated for 48h and then pH, conductivity, redox potential, carbon, majors and heavy metal solubilized are quantified. However, in most cases, the amounts of matrix and water do not reach the total volume of reactors, leaving some space for air (gaseous phase). Despite this fact, no clear indication is given in standard procedures about the effect of this gaseous phase. Even worse, the gaseous phase is never accounted for when exploiting or modeling ANC data. The gaseous phase may exchange CO2 with the solution, which may, in turn, impact both pH and element release. This study lies within the most general framework for the use of geochemical modeling for the prediction of ANC results for the case of pure phases to real phase assemblages. In this study, we focus on the effect of the gaseous phase on ANC experiments on different mineral phases through geochemical modeling. To do so, we use PHREEQC code to model the evolution of pH and element release (including majors and heavy metals) when several matrices are put in contact with acid or base. We model the following scenarios for the gaseous phase: no gas, contact with the atmosphere (open system) and real reactors conditions (semi-closed systems). The solid phases tested are pure phases (calcite, sulfides, etc.) and synthetic assemblages mimicking complex polluted matrices. The modeling clearly shows that the systems are sensitive to the opening to the atmosphere. If the open system and the system with no gas are entirely different, "real" reactors also differ significantly from the other systems. Apparently, the presence of the gaseous phase in reactors greatly impacts pH and element release. This parameter should be accounted for in ANC experimental procedures and modeling. In addition to this numerical study, experimental results, previously obtained for urban polluted sediments, are analyzed in lights of the findings of the numerical study. This step allows us to strengthen conclusions and to pinpoint at the necessity to account for the gaseous phase when performing and modeling ANC experiments.

A new concept for spatially divided Deep Reactive Ion Etching with ALD-based passivation

NASA Astrophysics Data System (ADS)

Roozeboom, F.; Kniknie, B.; Lankhorst, A. M.; Winands, G.; Knaapen, R.; Smets, M.; Poodt, P.; Dingemans, G.; Keuning, W.; Kessels, W. M. M.

2012-12-01

Conventional Deep Reactive Ion Etching (DRIE) is a plasma etch process with alternating half-cycles of 1) Si-etching with SF6 to form gaseous SiFx etch products, and 2) passivation with C4F8 that polymerizes as a protecting fluorocarbon deposit on the sidewalls and bottom of the etched features. In this work we report on a novel alternative and disruptive technology concept of Spatially-divided Deep Reactive Ion Etching, S-DRIE, where the process is converted from the time-divided into the spatially divided regime. The spatial division can be accomplished by inert gas bearing 'curtains' of heights down to ~20 μm. These curtains confine the reactive gases to individual (often linear) injection slots constructed in a gas injector head. By horizontally moving the substrate back and forth under the head one can realize the alternate exposures to the overall cycle. A second improvement in the spatially divided approach is the replacement of the CVD-based C4F8 passivation steps by ALD-based oxide (e.g. SiO2) deposition cycles. The method can have industrial potential in cost-effective creation of advanced 3D interconnects (TSVs), MEMS manufacturing and advanced patterning, e.g., in nanoscale transistor line edge roughness using Atomic Layer Etching.

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

DOEpatents

Ghate, Madhav R.; Yang, Ralph T.

1987-01-01

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Fast quench reactor method

DOEpatents

Detering, B.A.; Donaldson, A.D.; Fincke, J.R.; Kong, P.C.; Berry, R.A.

1999-08-10

A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a means of rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Metal halide reactants are injected into the reactor chamber. Reducing gas is added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream. 8 figs.

Photoionization microplasma sensor

NASA Astrophysics Data System (ADS)

Mustafaev, A. S.; Rastvorova, I. V.; Podenko, S. S.; Tsyganov, A. B.

2017-11-01

New developments in the physics of plasma are presented, specifically, research of completely new method of atoms’ and molecules’ detection in gaseous phase - collisional electron spectroscopy. As a result, the microplasma sensor for quality and quantity analysis of the gaseous mixture was created. It works in the discharge afterglow mode using He as a buffer gas. In addition, the modification of the sensor using resonance photon photoionization was developed. This consideration gives the opportunity for wide practical appliance as an individual gas analyzer for industrial and medical purposes.

Fast quench reactor method

DOEpatents

Detering, Brent A.; Donaldson, Alan D.; Fincke, James R.; Kong, Peter C.; Berry, Ray A.

1999-01-01

A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a means of rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Metal halide reactants are injected into the reactor chamber. Reducing gas is added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

Promoted nitrogen dissolution due to the addition of Li or Ca to Ga-Na melt; some effects of additives on the growth of GaN single crystals using the sodium flux method

NASA Astrophysics Data System (ADS)

Morishita, Masanori; Kawamura, Fumio; Kawahara, Minoru; Yoshimura, Masashi; Mori, Yusuke; Sasaki, Takatomo

2005-10-01

The effect of the addition of Li or Ca to Ga-Na melt on the promotion of nitrogen dissolution was examined quantitatively in the growth of GaN single crystals using the sodium flux method. The addition of Li or Ca to Ga-Na melt increased both the solubility of solid GaN and that of gaseous nitrogen against the solution. The increase in the solubility of gaseous nitrogen seems to be caused by additives having a high binding energy with nitrogen. We measured the solubility of GaN and that of gaseous nitrogen against Ga-Na, Ga-Na-Li and Ga-Na-Ca melt in this study. On the basis of these data, we clarified the relationship between the N/Ga ratio in the solution and the coloration of GaN crystals grown in each system, and between changes in the yield of GaN and the absolute value of supersaturation.

Systems and Methods of Laser Texturing of Material Surfaces and Their Applications

NASA Technical Reports Server (NTRS)

Gupta, Mool C. (Inventor); Nayak, Barada K. (Inventor)

2014-01-01

The surface of a material is textured and by exposing the surface to pulses from an ultrafast laser. The laser treatment causes pillars to form on the treated surface. These pillars provide for greater light absorption. Texturing and crystallization can be carried out as a single step process. The crystallization of the material provides for higher electric conductivity and changes in optical and electronic properties of the material. The method may be performed in vacuum or a gaseous environment. The gaseous environment may aid in texturing and/or modifying physical and chemical properties of the surfaces. This method may be used on various material surfaces, such as semiconductors, metals and their alloys, ceramics, polymers, glasses, composites, as well as crystalline, nanocrystalline, polycrystalline, microcrystalline, and amorphous phases.

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures

NASA Technical Reports Server (NTRS)

Sprinkle, Danny R.; Chaturvedi, Sushil K.; Kheireddine, Ali

1996-01-01

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen in the combustion products. This method involves using a controller which maintains the fuel (gas) volumetric flow rate at a level consistent with the desired oxygen concentration in the combustion products. The heat of combustion is determined form a known correlation with the fuel flow rate. An on-line computer accesses the fuel flow data and displays the heat of combustion measurement at desired time intervals. This technique appears to be especially applicable for measuring heats of combustion of hydrocarbon mixtures of unknown composition such as natural gas.

Apparatus and method for generating continuous wave 16. mu. m laser radiation using gaseous CF/sub 4/

DOEpatents

Telle, J.M.

1984-05-01

Apparatus and method for generating continuous wave 16 ..mu..m laser radiation using gaseous CF/sub 4/. Laser radiation at 16 ..mu..m has been observed in a cooled static cell containing low pressure CF/sub 4/ optically pumped by an approximately 3 W output power c-w CO/sub 2/ laser. The laser cavity employed was a multiple-pass off-axis-path two spherical mirror ring resonator. Unidirectional CF/sub 4/ laser output power at 615 cm/sup -1/ exceeded 2 mW. Computer calculations indicate that for modest pump powers of about 40 W, approximately 1 W of emitted laser radiation at 16 ..mu..m might be obtained.

Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4

DOEpatents

Telle, John M.

1986-01-01

Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4. Laser radiation at 16 .mu.m has been observed in a cooled static cell containing low pressure CF.sub.4 optically pumped by an approximately 3 W output power cw CO.sub.2 laser. The laser cavity employed was a multiple-pass off-axis-path two spherical mirror ring resonator. Unidirectional CF.sub.4 laser output power at 615 cm.sup.-1 exceeded 2 mW. Computer calculations indicate that for modest pump powers of about 40 W, approximately 1 W of emitted laser radiation at 16 .mu.m might be obtained.

The Effect of Gaseous Ozone in Infected Root Canal

PubMed Central

Ajeti, Nova Nexhmije; Pustina-Krasniqi, Teuta; Apostolska, Sonja

2018-01-01

OBJECTIVES: During the treatment of chronic apical periodontitis and pulp necrosis the main role is to irrigate the root canal. AIM: The aim of this in vivo study was to irrigate with 0.9% NaCl (Natrium Chloride), 2.5 % NaOCl (Sodium Hypochlorite Solution, Sigma Aldrich - Germany) and 2% CHX (Chlorhexidine Digluconate Solution, Sigma Aldrich - Spain) combined with Gaseous Ozone (Prozone WH, Austria). MATERIAL AND METHODS: This study was realised in the University Dentistry Clinical Centre of Kosovo (UDCCK), respectively in the Department of Endodontic and Dental Pathology, Dental Branch, Faculty of Medicine, Prishtina, Kosovo. The 40 subjects involved in this study belonged to both genders, in age between 15 -65 years. The sample selection was randomised. The retroalveolar radiography for each patient was taken in the suspected tooth. As a therapeutic plan the authors decided to disinfect the root canal with the irrigants, as follows: 2.5 % NaOCl, 2 % CHX and gaseous ozone. RESULTS: The statistical analyses were based on Kruskal - Vallis test, X - test, DF = 3, r < 0.01. In the isolated average number of the aerobe and anaerobe bacteria colonies, when gaseous ozone was used, there was the significant statistical difference. CONCLUSIONS: When gaseous ozone was combined with irrigants 0.9%, 2.5 % NaOCl and 2% CHX, it was concluded that the number of colonies of aerobic and anaerobic bacteria was reduced. PMID:29531611

Apparatus for silicon nitride precursor solids recovery

DOEpatents

Crosbie, Gary M.; Predmesky, Ronald L.; Nicholson, John M.

1995-04-04

Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

Final Report: Seismic Hazard Assessment at the PGDP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Zhinmeng

2007-06-01

Selecting a level of seismic hazard at the Paducah Gaseous Diffusion Plant for policy considerations and engineering design is not an easy task because it not only depends on seismic hazard, but also on seismic risk and other related environmental, social, and economic issues. Seismic hazard is the main focus. There is no question that there are seismic hazards at the Paducah Gaseous Diffusion Plant because of its proximity to several known seismic zones, particularly the New Madrid Seismic Zone. The issues in estimating seismic hazard are (1) the methods being used and (2) difficulty in characterizing the uncertainties ofmore » seismic sources, earthquake occurrence frequencies, and ground-motion attenuation relationships. This report summarizes how input data were derived, which methodologies were used, and what the hazard estimates at the Paducah Gaseous Diffusion Plant are.« less

Site Specific Metal Criteria Developed Using Kentucky Division of Water Procedures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kszos, L.A.; Phipps, T.L.

1999-10-09

Alternative limits for Cu, Ni, Pb, and Zn were developed for treated wastewater from four outfalls at a Gaseous Diffusion Plant. Guidance from the Kentucky Division of Water (KDOW) was used to (1) estimate the toxicity of the effluents using water fleas (Ceriodaphnia dubia) and fathead minnow (Pimephales promelas) larvae; (2) determine total recoverable and dissolved concentrations of Cu, Pb, Ni, and Zn ; (3) calculate ratios of dissolved metal (DM) to total recoverable metal (TRM); and (4) assess chemical characteristics of the effluents. Three effluent samples from each outfall were collected during each of six test periods; thus, amore » total of 18 samples from each outfall were evaluated for toxicity, DM and TRM. Subsamples were analyzed for alkalinity, hardness, pH, conductivity, and total suspended solids. Short-term (6 or 7 d), static renewal toxicity tests were conducted according to EPA methodology. Ceriodaphnia reproduction was reduced in one test of effluent from Outfall A , and effluent from Outfall B was acutely toxic to both test species during one test. However, the toxicity was not related to the metals present in the effluents. Of the 18 samples from each outfall, more than 65% of the metal concentrations were estimated quantities. With the exception of two total recoverable Cu values in Outfall C, all metal concentrations were below the permit limits and the federal water quality criteria. Ranges of TR for all outfalls were: Cd, ,0.1-0.4 {micro}g/L; Cr,1.07-3.93 {micro}g/L; Cu, 1.59-7.24 {micro}g/L; Pb, <0.1-3.20 {micro}g/L; Ni, 0.82-10.7 {micro}g/L, Zn, 4.75-67.3 {micro}g/L. DM:TRM ratios were developed for each outfall. The proportion of dissolved Cu in the effluents ranged from 67 to 82%; the proportion of dissolved Ni ranged from 84 to 91%; and the proportion of dissolved Zn ranged from 74 to 94%. The proportion of dissolved Pb in the effluents was considerably lower (37-51%). TRM and/or DM concentrations of Cu, Ni, Pb, or Zn differed significantly from outfall to outfall but the DM:TRM ratios for Cu, Ni, and Pb did not. Through the use of the KDOW method, the total recoverable metal measured in an effluent is adjusted by the proportion of dissolved metal present. The resulting alternative total recoverable metal concentration is reported in lieu of the measured total recoverable concentration for determining compliance with permit limits. For example, the monthly average permit limit for Pb in Outfall B (3 {micro}g/L) was exceeded at the Gaseous Diffusion Plant. Through the use of the KDOW method for calculating an alternative total recoverable metal concentration, 4.98 {micro}g Pb/L in Outfall B would be reported as 3.00 {micro}g/L, a difference of > 39%. Thus, the alternative, calculated total recoverable metal concentration provides the discharger with a ''cushion'' for meeting permit limits.« less

Visibility through the gaseous smoke in airborne remote sensing using a DSLR camera

NASA Astrophysics Data System (ADS)

Chabok, Mirahmad; Millington, Andrew; Hacker, Jorg M.; McGrath, Andrew J.

2016-08-01

Visibility and clarity of remotely sensed images acquired by consumer grade DSLR cameras, mounted on an unmanned aerial vehicle or a manned aircraft, are critical factors in obtaining accurate and detailed information from any area of interest. The presence of substantial haze, fog or gaseous smoke particles; caused, for example, by an active bushfire at the time of data capture, will dramatically reduce image visibility and quality. Although most modern hyperspectral imaging sensors are capable of capturing a large number of narrow range bands of the shortwave and thermal infrared spectral range, which have the potential to penetrate smoke and haze, the resulting images do not contain sufficient spatial detail to enable locating important objects or assist search and rescue or similar applications which require high resolution information. We introduce a new method for penetrating gaseous smoke without compromising spatial resolution using a single modified DSLR camera in conjunction with image processing techniques which effectively improves the visibility of objects in the captured images. This is achieved by modifying a DSLR camera and adding a custom optical filter to enable it to capture wavelengths from 480-1200nm (R, G and Near Infrared) instead of the standard RGB bands (400-700nm). With this modified camera mounted on an aircraft, images were acquired over an area polluted by gaseous smoke from an active bushfire. Processed data using our proposed method shows significant visibility improvements compared with other existing solutions.

Hydrogen isotope separation utilizing bulk getters

DOEpatents

Knize, R.J.; Cecchi, J.L.

1991-08-20

Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

Hydrogen isotope separation utilizing bulk getters

DOEpatents

Knize, Randall J.; Cecchi, Joseph L.

1991-01-01

Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

Hydrogen isotope separation utilizing bulk getters

DOEpatents

Knize, Randall J.; Cecchi, Joseph L.

1990-01-01

Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

Fire flood method for recovering petroleum from oil reservoirs of low permeability and temperature

DOEpatents

Kamath, Krishna

1984-08-14

The present invention is directed to a method of enhanced oil recovery by fire flooding petroleum reservoirs characterized by a temperature of less than the critical temperature of carbon dioxide, a pore pressure greater than the saturated vapor pressure of carbon dioxide at said temperature (87.7.degree. F. at 1070 psia), and a permeability in the range of about 20 to 100 millidarcies. The in situ combustion of petroleum in the reservoir is provided by injecting into the reservoir a combustion supporting medium consisting essentially of oxygen, ozone, or a combination thereof. The heat of combustion and the products of this combustion which consist essentially of gaseous carbon dioxide and water vapor sufficiently decrease the viscosity of oil adjacent to fire front to form an oil bank which moves through the reservoir towards a recovery well ahead of the fire front. The gaseous carbon dioxide and the water vapor are driven into the reservoir ahead of the fire front by pressure at the injection well. As the gaseous carbon dioxide cools to less than about 88.degree. F. it is converted to liquid which is dissolved in the oil bank for further increasing the mobility thereof. By using essentially pure oxygen, ozone, or a combination thereof as the combustion supporting medium in these reservoirs the permeability requirements of the reservoirs are significantly decreased since the liquid carbon dioxide requires substantially less voidage volume than that required for gaseous combustion products.

Method and apparatus of cryogenic cooling for high temperature superconductor devices

DOEpatents

Yuan, Xing; Mine, Susumu

2005-02-15

A method and apparatus for providing cryogenic cooling to HTS devices, in particular those that are used in high-voltage electric power applications. The method involves pressurizing liquid cryogen to above one atmospheric pressure to improve its dielectric strength, while sub-cooling the liquid cryogen to below its saturation temperature in order to improve the performance of the HTS components of the device. An apparatus utilizing such a cooling method consists of a vessel that contains a pressurized gaseous cryogen region and a sub-cooled liquid cryogen bath, a liquid cryogen heating coupled with a gaseous cryogen venting scheme to maintain the pressure of the cryogen to a value in a range that corresponds to optimum dielectric strength of the liquid cryogen, and a cooling system that maintains the liquid cryogen at a temperature below its boiling point to improve the performance of HTS materials used in the device.

Optical oscillator strengths of the valence-shell excitations of atoms and molecules determined by the dipole ( γ,γ) method

NASA Astrophysics Data System (ADS)

Xu, Long-Quan; Liu, Ya-Wei; Xu, Xin; Ni, Dong-Dong; Yang, Ke; Zhu, Lin-Fan

2017-07-01

The dipole (γ,γ) method, which is the inelastic X-ray scattering operated at a negligibly small momentum transfer, has been developed to determine the absolute optical oscillator strengths of the valence-shell excitations of atoms and molecules. This new method is free from the line saturation effect, and its Bethe-Born conversion factor varies much more slowly with the excitation energy than that of the dipole (e, e) method. Thus the dipole (γ,γ) method provides a reliable approach to obtain the benchmark optical oscillator strengths of the valence-shell excitations for gaseous atoms and molecules. In this paper, we give a review of the dipole (γ,γ) method and some recent measurements of absolute optical oscillator strengths of gaseous atoms and molecules. Contribution to the Topical Issue "Atomic and Molecular Data and their Applications", edited by Gordon W.F. Drake, Jung-Sik Yoon, Daiji Kato, Grzegorz Karwasz.

Development of one-step hollow fiber supported liquid phase sampling technique for occupational workplace air analysis using high performance liquid chromatography with ultra-violet detector.

PubMed

Yan, Cheing-Tong; Chien, Hai-Ying

2012-07-13

In this study, a simple and novel one-step hollow-fiber supported liquid-phase sampling (HF-LPS) technique was developed for enriched sampling of gaseous toxic species prior to chemical analysis for workplace air monitoring. A lab-made apparatus designed with a gaseous sample generator and a microdialysis sampling cavity (for HF-LPS) was utilized and evaluated to simulate gaseous contaminant air for occupational workplace analysis. Gaseous phenol was selected as the model toxic species. A polyethersulfone hollow fiber dialysis module filled with ethylene glycol in the shell-side was applied as the absorption solvent to collect phenol from a gas flow through the tube-side, based on the concentration distribution of phenol between the absorption solvent and the gas flow. After sampling, 20 μL of the extractant was analyzed by high performance liquid chromatography with ultraviolet detection (HPLC-UV). Factors that influence the generation of gaseous standards and the HF-LPS were studied thoroughly. Results indicated that at 25 °C the phenol (2000 μg/mL) standard solution injected at 15-μL/min can be vaporized into sampling cavity under nitrogen flow at 780 mL/min, to generate gaseous phenol with concentration approximate to twice the permissible exposure limit. Sampling at 37.3 mL/min for 30 min can meet the requirement of the workplace air monitoring. The phenol in air ranged between 0.7 and 10 cm³/m³ (shows excellent linearity) with recovery between 98.1 and 104.1%. The proposed method was identified as a one-step sampling for workplace monitoring with advantages of convenience, rapidity, sensitivity, and usage of less-toxic solvent. Copyright © 2012 Elsevier B.V. All rights reserved.

Characteristics and applications of small, portable gaseous air pollution monitors.

PubMed

McKercher, Grant R; Salmond, Jennifer A; Vanos, Jennifer K

2017-04-01

Traditional approaches for measuring air quality based on fixed measurements are inadequate for personal exposure monitoring. To combat this issue, the use of small, portable gas-sensing air pollution monitoring technologies is increasing, with researchers and individuals employing portable and mobile methods to obtain more spatially and temporally representative air pollution data. However, many commercially available options are built for various applications and based on different technologies, assumptions, and limitations. A review of the monitor characteristics of small, gaseous monitors is missing from current scientific literature. A state-of-the-art review of small, portable monitors that measure ambient gaseous outdoor pollutants was developed to address broad trends during the last 5-10 years, and to help future experimenters interested in studying gaseous air pollutants choose monitors appropriate for their application and sampling needs. Trends in small, portable gaseous air pollution monitor uses and technologies were first identified and discussed in a review of literature. Next, searches of online databases were performed for articles containing specific information related to performance, characteristics, and use of such monitors that measure one or more of three criteria gaseous air pollutants: ozone, nitrogen dioxide, and carbon monoxide. All data were summarized into reference tables for comparison between applications, physical features, sensing capabilities, and costs of the devices. Recent portable monitoring trends are strongly related to associated applications and audiences. Fundamental research requires monitors with the best individual performance, and thus the highest cost technology. Monitor networking favors real-time capabilities and moderate cost for greater reproduction. Citizen science and crowdsourcing applications allow for lower-cost components; however important strengths and limitations for each application must be addressed or acknowledged for the given use. Copyright © 2016 Elsevier Ltd. All rights reserved.

Fostering Remainder Understanding in Fraction Division

ERIC Educational Resources Information Center

Zembat, Ismail O.

2017-01-01

Most students can follow this simple procedure for division of fractions: "Ours is not to reason why, just invert and multiply." But how many really understand what division of fractions means--especially fraction division with respect to the meaning of the remainder. The purpose of this article is to provide an instructional method as a…

Multicarrier orthogonal spread-spectrum (MOSS) data communications

DOEpatents

Smith, Stephen F [London, TN; Dress, William B [Camas, WA

2008-01-01

Systems and methods are described for multicarrier orthogonal spread-spectrum (MOSS) data communication. A method includes individually spread-spectrum modulating at least two of a set of orthogonal frequency division multiplexed carriers, wherein the resulting individually spread-spectrum modulated at least two of a set of orthogonal frequency division multiplexed carriers are substantially mutually orthogonal with respect to both frequency division multiplexing and spread-spectrum modulation.

System and method for detecting gas

DOEpatents

Chow, Oscar Ken; Moulthrop, Lawrence Clinton; Dreier, Ken Wayne; Miller, Jacob Andrew

2010-03-16

A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

Gas Chromatic Mass Spectrometer

NASA Technical Reports Server (NTRS)

Wey, Chowen

1995-01-01

Gas chromatograph/mass spectrometer (GC/MS) used to measure and identify combustion species present in trace concentration. Advanced extractive diagnostic method measures to parts per billion (PPB), as well as differentiates between different types of hydrocarbons. Applicable for petrochemical, waste incinerator, diesel transporation, and electric utility companies in accurately monitoring types of hydrocarbon emissions generated by fuel combustion, in order to meet stricter environmental requirements. Other potential applications include manufacturing processes requiring precise detection of toxic gaseous chemicals, biomedical applications requiring precise identification of accumulative gaseous species, and gas utility operations requiring high-sensitivity leak detection.

Radiative interactions in transient energy transfer in gaseous systems

NASA Technical Reports Server (NTRS)

Tiwari, S. N.

1985-01-01

Analyses and numerical procedures are presented to investigate the radiative interactions in transient energy transfer processes in gaseous systems. The nongray radiative formulations are based on the wide-band model correlations for molecular absorption. Various relations for the radiative flux are developed; these are useful for different flow conditions and physical problems. Specific plans for obtaining extensive results for different cases are presented. The methods presented in this study can be extended easily to investigate the radiative interactions in realistic flows of hydrogen-air species in the scramjet engine.

Planar high density sodium battery

DOEpatents

Lemmon, John P.; Meinhardt, Kerry D.

2016-03-01

A method of making a molten sodium battery is disclosed. A first metallic interconnect frame having a first interconnect vent hole is provided. A second metallic interconnect frame having a second interconnect vent hole is also provided. An electrolyte plate having a cathode vent hole and an anode vent hole is interposed between the metallic interconnect frames. The metallic interconnect frames and the electrolyte plate are sealed thereby forming gaseous communication between an anode chamber through the anode vent hole and gaseous communication between a cathode chamber through the cathode vent hole.

Galvanic cell for processing of used nuclear fuel

DOEpatents

Garcia-Diaz, Brenda L.; Martinez-Rodriguez, Michael J.; Gray, Joshua R.; Olson, Luke C.

2017-02-07

A galvanic cell and methods of using the galvanic cell is described for the recovery of uranium from used nuclear fuel according to an electrofluorination process. The galvanic cell requires no input energy and can utilize relatively benign gaseous fluorinating agents. Uranium can be recovered from used nuclear fuel in the form of gaseous uranium compound such as uranium hexafluoride, which can then be converted to metallic uranium or UO.sub.2 and processed according to known methodology to form a useful product, e.g., fuel pellets for use in a commercial energy production system.

Electrochemical fluorination for processing of used nuclear fuel

DOEpatents

Garcia-Diaz, Brenda L.; Martinez-Rodriguez, Michael J.; Gray, Joshua R.; Olson, Luke C.

2016-07-05

A galvanic cell and methods of using the galvanic cell is described for the recovery of uranium from used nuclear fuel according to an electrofluorination process. The galvanic cell requires no input energy and can utilize relatively benign gaseous fluorinating agents. Uranium can be recovered from used nuclear fuel in the form of gaseous uranium compound such as uranium hexafluoride, which can then be converted to metallic uranium or UO.sub.2 and processed according to known methodology to form a useful product, e.g., fuel pellets for use in a commercial energy production system.

Device for sampling and enriching impurities in hydrogen comprising hydrogen-permeable membrane

DOEpatents

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon D. H.; Kumar, Romesh

2017-01-31

Provided herein are methods and devices to enrich trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentration of impurities so as to allow the detection of the impurities using commonly-available detection methods.

Methods of using viral replicase polynucleotides and polypeptides

DOEpatents

Gordon-Kamm, William J.; Lowe, Keith S.; Bailey, Matthew A.; Gregory, Carolyn A.; Hoerster, George J.; Larkins, Brian A.; Dilkes, Brian R.; Burnett, Ronald; Woo, Young Min

2007-12-18

The invention provides novel methods of using viral replicase polypeptides and polynucleotides. Included are methods for increasing transformation frequencies, increasing crop yield, providing a positive growth advantage, modulating cell division, transiently modulating cell division, and for providing a means of positive selection.

The Plasma Archipelago: Plasma Physics in the 1960s

NASA Astrophysics Data System (ADS)

Weisel, Gary J.

2017-09-01

With the foundation of the Division of Plasma Physics of the American Physical Society in April 1959, plasma physics was presented as the general study of ionized gases. This paper investigates the degree to which plasma physics, during its first decade, established a community of interrelated specialties, one that brought together work in gaseous electronics, astrophysics, controlled thermonuclear fusion, space science, and aerospace engineering. It finds that, in some regards, the plasma community was indeed greater than the sum of its parts and that its larger identity was sometimes glimpsed in inter-specialty work and studies of fundamental plasma behaviors. Nevertheless, the plasma specialties usually worked separately for two inter-related reasons: prejudices about what constituted "basic physics," both in the general physics community and within the plasma community itself; and a compartmentalized funding structure, in which each funding agency served different missions.

Enhancing mercury removal across air pollution control devices for coal-fired power plants by desulfurization wastewater evaporation.

PubMed

Bin, Hu; Yang, Yi; Cai, Liang; Yang, Linjun; Roszak, Szczepan

2017-10-09

Desulfurization wastewater evaporation technology is used to enhance the removal of gaseous mercury (Hg) in conventional air pollution control devices (APCDs) for coal-fired power plants. Studies have affirmed that gaseous Hg is oxidized and removed by selective catalytic reduction (SCR), an electrostatic precipitator (ESP) and wet flue gas desulfurization (WFGD) in a coal-fired thermal experiment platform with WFGD wastewater evaporation. Effects of desulfurization wastewater evaporation position, evaporation temperature and chlorine ion concentration on Hg oxidation were studied as well. The Hg 0 oxidation efficiency was increased ranging from 30% to 60%, and the gaseous Hg removal efficiency was 62.16% in APCDs when wastewater evaporated before SCR. However, the Hg 0 oxidation efficiency was 18.99% and the gaseous Hg removal efficiency was 40.19% in APCDs when wastewater evaporated before ESP. The results show that WFGD wastewater evaporation before SCR is beneficial to improve the efficiency of Hg oxidized and removed in APCDs. Because Hg 2+ can be easily removed in ACPDs and WFGD wastewater in power plants is enriched with chlorine ions, this method realizes WFGD wastewater zero discharge and simultaneously enhances Hg removal in APCDs.

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

DOEpatents

Ghate, M.R.; Yang, R.T.

1985-10-03

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

DOEpatents

Hobson, D.O.; Alexeff, I.; Sikka, V.K.

1987-08-10

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

DOEpatents

Hobson, David O.; Alexeff, Igor; Sikka, Vinod K.

1988-01-01

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream

DOEpatents

Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

2013-07-16

The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

Method and system for fiber optic determination of gas concentrations in liquid receptacles

NASA Technical Reports Server (NTRS)

Nguyen, Quang-Viet (Inventor)

2008-01-01

A system for determining gas compositions includes a probe, inserted into a source of gaseous material, the probe having a gas permeable sensor tip and being capable of sending and receiving light to and from the gaseous material, a sensor body, connected to the probe, situated outside of the source and a fiber bundle, connected to the sensor body and communicating light to and from the probe. The system also includes a laser source, connected to one portion of the fiber bundle and providing laser light to the fiber bundle and the probe a Raman spectrograph, connected to another portion of the fiber bundle, receiving light from the probe and filtering the received light into specific channels and a data processing unit, receiving and analyzing the received light in the specific channels and outputting concentration of specific gas species in the gaseous material based on the analyzed received light.

Sample Training Based Wildfire Segmentation by 2D Histogram θ-Division with Minimum Error

PubMed Central

Dong, Erqian; Sun, Mingui; Jia, Wenyan; Zhang, Dengyi; Yuan, Zhiyong

2013-01-01

A novel wildfire segmentation algorithm is proposed with the help of sample training based 2D histogram θ-division and minimum error. Based on minimum error principle and 2D color histogram, the θ-division methods were presented recently, but application of prior knowledge on them has not been explored. For the specific problem of wildfire segmentation, we collect sample images with manually labeled fire pixels. Then we define the probability function of error division to evaluate θ-division segmentations, and the optimal angle θ is determined by sample training. Performances in different color channels are compared, and the suitable channel is selected. To further improve the accuracy, the combination approach is presented with both θ-division and other segmentation methods such as GMM. Our approach is tested on real images, and the experiments prove its efficiency for wildfire segmentation. PMID:23878526

Comparative Investigation on the Heat Transfer Characteristics of Gaseous CO2 and Gaseous Water Flowing Through a Single Granite Fracture

NASA Astrophysics Data System (ADS)

He, Yuanyuan; Bai, Bing; Li, Xiaochun

2017-11-01

CO2 and water are two commonly employed heat transmission fluids in several fields. Their temperature and pressure determine their phase states, thus affecting the heat transfer performance of the water/CO2. The heat transfer characteristics of gaseous CO2 and gaseous water flowing through fractured hot dry rock still need a great deal of investigation, in order to understand and evaluate the heat extraction in enhanced geothermal systems. In this work, we develop a 2D numerical model to compare the heat transfer performance of gaseous CO2 and gaseous water flowing through a single fracture aperture of 0.2 mm in a φ 50 × 50 mm cylindrical granite sample with a confining temperature of 200°C under different inlet mass flow rates. Our results indicate that: (1) the final outlet temperatures of the fluid are very close to the outer surface temperature under low inlet mass flow rate, regardless of the sample length. (2) Both the temperature of the fluid (gaseous CO2/gaseous water) and inner surface temperature rise sharply at the inlet, and the inner surface temperature is always higher than the fluid temperature. However, their temperature difference becomes increasingly small. (3) Both the overall heat transfer coefficient (OHTC) and local heat transfer coefficient (LHTC) of gaseous CO2 and gaseous water increase with increasing inlet mass flow rates. (4) Both the OHTC and LHTC of gaseous CO2 are lower than those of gaseous water under the same conditions; therefore, the heat mining performance of gaseous water is superior to gaseous CO2 under high temperature and low pressure.

Development, evaluation and application of a modified micrometeorological gradient method for long-term estimation of gaseous dry deposition over forest canopies.

EPA Science Inventory

Small pollutant concentration gradients between levels above a plant canopy result in large uncertainties in estimated air–surface exchange fluxes when using existing micrometeorological gradient methods, including the aerodynamic gradient method (AGM) and the modified Bowen rati...

Experimental study of gaseous and particulate contaminants distribution in an aircraft cabin

NASA Astrophysics Data System (ADS)

Li, Fei; Liu, Junjie; Pei, Jingjing; Lin, Chao-Hsin; Chen, Qingyan

2014-03-01

The environment of the aircraft cabin greatly influences the comfort and health of passengers and crew members. Contaminant transport has a strong effect on disease spreading in the cabin environment. To obtain the complex cabin contaminant distribution fields accurately and completely, which is also essential to provide solid and precise data for computational fluid dynamics (CFD) model validation, this paper aimed to investigate and improve the method for simultaneous particle and gaseous contaminant fields measurement. The experiment was conducted in a functional MD-82 aircraft. Sulfur hexafluoride (SF6) was used as tracer gas, and Di-Ethyl-Hexyl-Sebacat (DEHS) was used as particulate contaminant. The whole measurement was completed in a part of the economy-class cabin without heating manikins or occupied with heating manikins. The experimental method, in terms of pollutant source setting, sampling points and schedule, was investigated. Statistical analysis showed that appropriately modified sampling grid was able to provide reasonable data. A small difference in the source locations can lead to a significant difference in cabin contaminant fields. And the relationship between gaseous and particulate pollutant transport was also discussed through tracking behavior analysis.

Montana Department of Transportation Guide to Public Involvement

DOT National Transportation Integrated Search

1996-01-01

This guide describes the various methods the Transportation Planning Division of the MDOT uses to involve the public in Division activities, and also includes a chart that provides the names of staff people responsible for various Division programs. ...

The gaseous enthalpy of formation of the ionic liquid 1-butyl-3-methylimidazolium dicyanamide from combustion calorimetry, vapor pressure measurements, and ab initio calculations.

PubMed

Emel'yanenko, Vladimir N; Verevkin, Sergey P; Heintz, Andreas

2007-04-04

Ionic liquids are attracting growing interest as alternatives to conventional molecular solvents. Experimental values of vapor pressure, enthalpy of vaporization, and enthalpy of formation of ionic liquids are the key thermodynamic quantities, which are required for the validation and development of the molecular modeling and ab initio methods toward this new class of solvents. In this work, the molar enthalpy of formation of the liquid 1-butyl-3-methylimidazolium dicyanamide, 206.2 +/- 2.5 kJ.mol-1, was measured by means of combustion calorimetry. The molar enthalpy of vaporization of 1-butyl-3-methylimidazolium dicyanamide, 157.2 +/- 1.1 kJ.mol-1, was obtained from the temperature dependence of the vapor pressure measured using the transpiration method. The latter method has been checked with measurements of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, where data are available from the effusion technique. The first experimental determination of the gaseous enthalpy of formation of the ionic liquid 1-butyl-3-methylimidazolium dicyanamide, 363.4 +/- 2.7 kJ.mol-1, from thermochemical measurements (combustion and transpiration) is presented. Ab initio calculations of the enthalpy of formation in the gaseous phase have been performed for 1-butyl-3-methylimidazolium dicyanamide using the G3MP2 theory. Excellent agreement with experimental results has been observed. The method developed opens a new way to obtain thermodynamic properties of ionic liquids which have not been available so far.

Lightning Talks 2015: Theoretical Division

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shlachter, Jack S.

2015-11-25

This document is a compilation of slides from a number of student presentations given to LANL Theoretical Division members. The subjects cover the range of activities of the Division, including plasma physics, environmental issues, materials research, bacterial resistance to antibiotics, and computational methods.

A Constant Pressure Bomb

NASA Technical Reports Server (NTRS)

Stevens, F W

1924-01-01

This report describes a new optical method of unusual simplicity and of good accuracy suitable to study the kinetics of gaseous reactions. The device is the complement of the spherical bomb of constant volume, and extends the applicability of the relationship, pv=rt for gaseous equilibrium conditions, to the use of both factors p and v. The method substitutes for the mechanical complications of a manometer placed at some distance from the seat of reaction the possibility of allowing the radiant effects of reaction to record themselves directly upon a sensitive film. It is possible the device may be of use in the study of the photoelectric effects of radiation. The method makes possible a greater precision in the measurement of normal flame velocities than was previously possible. An approximate analysis shows that the increase of pressure and density ahead of the flame is negligible until the velocity of the flame approaches that of sound.

Systems and methods for thermal imaging technique for measuring mixing of fluids

DOEpatents

Booten, Charles; Tomerlin, Jeff; Winkler, Jon

2016-06-14

Systems and methods for thermal imaging for measuring mixing of fluids are provided. In one embodiment, a method for measuring mixing of gaseous fluids using thermal imaging comprises: positioning a thermal test medium parallel to a direction gaseous fluid flow from an outlet vent of a momentum source, wherein when the source is operating, the fluid flows across a surface of the medium; obtaining an ambient temperature value from a baseline thermal image of the surface; obtaining at least one operational thermal image of the surface when the fluid is flowing from the outlet vent across the surface, wherein the fluid has a temperature different than the ambient temperature; and calculating at least one temperature-difference fraction associated with at least a first position on the surface based on a difference between temperature measurements obtained from the at least one operational thermal image and the ambient temperature value.

Methods for increasing the production of ethanol from microbial fermentation

DOEpatents

Gaddy, James L [Fayetteville, AR; Arora, Dinesh K [Fayetteville, AR; Ko, Ching-Whan [Fayetteville, AR; Phillips, John Randall [Fayetteville, AR; Basu, Rahul [Bethlehem, PA; Wikstrom, Carl V [Fayetteville, AR; Clausen, Edgar C [Fayetteville, AR

2007-10-23

A stable continuous method for producing ethanol from the anaerobic bacterial fermentation of a gaseous substrate containing at least one reducing gas involves culturing a fermentation bioreactor anaerobic, acetogenic bacteria in a liquid nutrient medium; supplying the gaseous substrate to the bioreactor; and manipulating the bacteria in the bioreactor by reducing the redox potential, or increasing the NAD(P)H TO NAD(P) ratio, in the fermentation broth after the bacteria achieves a steady state and stable cell concentration in the bioreactor. The free acetic acid concentration in the bioreactor is maintained at less than 5 g/L free acid. This method allows ethanol to be produced in the fermentation broth in the bioreactor at a productivity greater than 10 g/L per day. Both ethanol and acetate are produced in a ratio of ethanol to acetate ranging from 1:1 to 20:1.

High School Forum

ERIC Educational Resources Information Center

Herron, J. Dudley, Ed.

1975-01-01

Describes methods for teaching the mole concept, including analogous calculations involving household objects, and the use of a cardboard wheel showing the interrelationships between moles, molecular weight, and the gaseous molar volume. (MLH)

Method for providing real-time control of a gaseous propellant rocket propulsion system

NASA Technical Reports Server (NTRS)

Morris, Brian G. (Inventor)

1991-01-01

The new and improved methods and apparatus disclosed provide effective real-time management of a spacecraft rocket engine powered by gaseous propellants. Real-time measurements representative of the engine performance are compared with predetermined standards to selectively control the supply of propellants to the engine for optimizing its performance as well as efficiently managing the consumption of propellants. A priority system is provided for achieving effective real-time management of the propulsion system by first regulating the propellants to keep the engine operating at an efficient level and thereafter regulating the consumption ratio of the propellants. A lower priority level is provided to balance the consumption of the propellants so significant quantities of unexpended propellants will not be left over at the end of the scheduled mission of the engine.

Resonantly enhanced four-wave mixing

DOEpatents

Begley, Richard F.; Kurnit, Norman A.

1978-01-01

A method and apparatus for achieving large susceptibilities and long interaction lengths in the generation of new wavelengths in the infrared spectral region. A process of resonantly enhanced four-wave mixing is employed, utilizing existing laser sources, such as the CO.sub.2 laser, to irradiate a gaseous media. The gaseous media, comprising NH.sub.3, CH.sub.3 F, D.sub.2, HCl, HF, CO, and H.sub.2 or some combination thereof, are of particular interest since they are capable of providing high repetition rate operation at high flux densities where crystal damage problems become a limitation.

APPLYING OPEN-PATH OPTICAL SPECTROSCOPY TO HEAVY-DUTY DIESEL EMISSIONS

EPA Science Inventory

Non-dispersive infrared absorption has been used to measure gaseous emissions for both stationary and mobile sources. Fourier transform infrared spectroscopy has been used for stationary sources as both extractive and open-path methods. We have applied the open-path method for bo...

40 CFR 98.224 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy. (2) ASTM D6348-03 Standard Test Method for Determination of Gaseous Compounds by Extractive Direct Interface Fourier Transform...

40 CFR 98.224 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy. (2) ASTM D6348-03 Standard Test Method for Determination of Gaseous Compounds by Extractive Direct Interface Fourier Transform...

40 CFR 98.224 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy. (2) ASTM D6348-03 Standard Test Method for Determination of Gaseous Compounds by Extractive Direct Interface Fourier Transform...

40 CFR 98.224 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy. (2) ASTM D6348-03 Standard Test Method for Determination of Gaseous Compounds by Extractive Direct Interface Fourier Transform...

Petroleum.

ERIC Educational Resources Information Center

McManus, T. R.; And Others

1989-01-01

This review of petroleum covers: crude oil; fuels, gaseous and liquid; lubricants, oils, and greases; asphalts, bitumens, tars, and pitches; hydrocarbons; physical properties; metals in oil; nonmetallic elements and heterocompounds; and analytical methods and apparatus. (MVL)

Effect of catalyst calcination temperature in the visible light photocatalytic oxidation of gaseous formaldehyde by multi-element doped titanium dioxide.

PubMed

de Luna, Mark Daniel G; Laciste, Maricris T; Tolosa, Nolan C; Lu, Ming-Chun

2018-03-20

The present study investigates the influence of calcination temperature on the properties and photoactivity of multi-element doped TiO 2 . The photocatalysts were prepared by incorporating silver (Ag), fluorine (F), nitrogen (N), and tungsten (W) into the TiO 2 structure via the sol-gel method. Spectroscopic techniques were used to elucidate the correlation between the structural and optical properties of the doped photocatalyst and its photoactivity. XRD results showed that the mean crystallite size increased for undoped photocatalysts and decreased for the doped photocatalysts when calcination was done at higher temperatures. UV-Vis spectra showed that the absorption cut-off wavelength shifted towards the visible light region for the as-synthesized photocatalysts and band gap narrowing was attributed to multi-element doping and calcination. FTIR spectra results showed the shifting of OH-bending absorption bands towards increasing wave numbers. The activity of the photocatalysts was evaluated in terms of gaseous formaldehyde removal under visible light irradiation. The highest photocatalytic removal of gaseous formaldehyde was found at 88%. The study confirms the effectiveness of multi-element doped TiO 2 to remove gaseous formaldehyde in air by visible light photocatalysis and the results have a lot of potential to extend the application to other organic air contaminants.

Process for exchanging hydrogen isotopes between gaseous hydrogen and water

DOEpatents

Hindin, Saul G.; Roberts, George W.

1980-08-12

A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

Fluoride and sulfur dioxide indoor pollution situation and control in coal-burning endemic area in Zhaotong, Yunnan, China

NASA Astrophysics Data System (ADS)

Liu, Yonglin; Luo, Kunli; Li, Ling; Shahid, Muhammad Zeeshaan

2013-10-01

The presented study aims to investigate the gaseous fluoride and sulfur dioxide (SO2) pollution level in the kitchen, traditional flue-curing barn and outdoor environment and to find economically feasible method to reduce fluorine and sulfur release. The gaseous fluoride and SO2 concentrations in air of outdoor environment, kitchen and traditional flue-curing barn were determined in 56 households in coal-burning endemic fluorosis areas of Zhaotong. Among these, 21 households in Yujiawan Village, Zhenxiong County, Zhaotong City were chosen for this experiment to reduce gaseous fluoride and SO2 concentration in traditional flue-curing barn air by using calcined dolomitic siliceous limestone (CDSL) instead of clay mixed with coal. The result showed that: (1) gaseous fluoride and SO2 concentration in the outdoor air in Mangbu Township area was 0.51 μg dm-2ṡday and <0.05 mg m-3, respectively and in Xiaolongdong Township was 2.7 μg dm-2 day and <0.05 mg m-3, respectively while in Zhaotong City these concentration were lower than the ambient air standard (3 μg dm-2ṡday and 0.5 mg m-3, respectively). (2) The indoor gaseous fluoride concentration (3.7 μg m-3) in air of kitchen with the improved coal stove was within the reference value (10 μg m-3); SO2 concentration (0.94 mg m-3) in kitchen air had decline, but its concentration was still higher than indoor air quality standard (0.5 mg m-3). (3) Average concentration of gaseous fluoride and SO2 in air of traditional flue-curing barn of Xiaolongdong Township was 7.2 μg m-3 and 6.8 mg m-3 respectively, and in Yujiawan village were 10.1 μg m-3 and 14.4 mg m-3, respectively. (4) After using the calcined dolomitic siliceous limestone instead of clay mixed with coal, gaseous fluoride and SO2 concentration in the traditional flue-curing barn air decreased of 45% and 91%, respectively. The gaseous fluoride and SO2 pollution in the traditional flue-curing barn is very serious. The corn and chili baked by open stoves in traditional flue-curing barn (baking room) was also seriously polluted by fluoride and sulfur. After using the calcined dolomitic siliceous limestone instead of clay mixed with coal, gaseous fluoride and SO2 concentration in the traditional flue-curing barn air have declined markedly. The way of adding calcined dolomitic siliceous limestone instead of clay as a binder for briquette-making is an economically feasible way to control the indoor pollution of fluorine and sulfur in coal-burning endemic in Zhaotong, Yunnan.

Method to Select Metropolitan Areas of Epidemiologic Interest for Enhanced Air Quality Monitoring

EPA Science Inventory

The U.S. Environmental Protection Agency’s current Speciation Trends Network (STN) covers most major U.S. metropolitan areas and a wide range of particulate matter (PM) constituents and gaseous co-pollutants. However, using filter-based methods, most PM constituents are measured ...

40 CFR 87.71 - Compliance with gaseous emission standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 87.71 Compliance with gaseous emission standards. Compliance with each gaseous emission standard by an aircraft engine shall be...

40 CFR 87.71 - Compliance with gaseous emission standards.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 87.71 Compliance with gaseous emission standards. Compliance with each gaseous emission standard by an aircraft engine shall be...

Hybrid charge division multiplexing method for silicon photomultiplier based PET detectors

NASA Astrophysics Data System (ADS)

Park, Haewook; Ko, Guen Bae; Lee, Jae Sung

2017-06-01

Silicon photomultiplier (SiPM) is widely utilized in various positron emission tomography (PET) detectors and systems. However, the individual recording of SiPM output signals is still challenging owing to the high granularity of the SiPM; thus, charge division multiplexing is commonly used in PET detectors. Resistive charge division method is well established for reducing the number of output channels in conventional multi-channel photosensors, but it degrades the timing performance of SiPM-based PET detectors by yielding a large resistor-capacitor (RC) constant. Capacitive charge division method, on the other hand, yields a small RC constant and provides a faster timing response than the resistive method, but it suffers from an output signal undershoot. Therefore, in this study, we propose a hybrid charge division method which can be implemented by cascading the parallel combination of a resistor and a capacitor throughout the multiplexing network. In order to compare the performance of the proposed method with the conventional methods, a 16-channel Hamamatsu SiPM (S11064-050P) was coupled with a 4  ×  4 LGSO crystal block (3  ×  3  ×  20 mm3) and a 9  ×  9 LYSO crystal block (1.2  ×  1.2  ×  10 mm3). In addition, we tested a time-over-threshold (TOT) readout using the digitized position signals to further demonstrate the feasibility of the time-based readout of multiplexed signals based on the proposed method. The results indicated that the proposed method exhibited good energy and timing performance, thus inheriting only the advantages of conventional resistive and capacitive methods. Moreover, the proposed method showed excellent pulse shape uniformity that does not depend on the position of the interacted crystal. Accordingly, we can conclude that the hybrid charge division method is useful for effectively reducing the number of output channels of the SiPM array.

Comparative study of glass tube and mist chamber sampling techniques for the analysis of gaseous carbonyl compounds

NASA Astrophysics Data System (ADS)

François, Stéphanie; Perraud, Véronique; Pflieger, Maryline; Monod, Anne; Wortham, Henri

In this work, glass tube and mist chamber sampling techniques using 2,4-dinitrophenylhydrazine as derivative agent for the analysis of gaseous carbonyl compounds are compared. Trapping efficiencies of formaldehyde, acetaldehyde, propionaldehyde, acetone, acrolein, glyoxal, crotonaldehyde, benzaldehyde, butyraldehyde and valeraldehyde are experimentally determined using a gas-phase generator. In addition to generalise our results to all atmospheric gaseous compounds and derivative agents, theoretical trapping efficiencies and enrichment factors are expressed taking into account mechanisms involved in the two kinds of traps. Theoretical and experimental results show that, as expected, the trapping efficiencies of the glass tube depend mainly on solubility of compounds. The results provide new information and better understanding of phenomena occurring in the mist chamber and the ability of this sampler to concentrate the samples. Hence, the mist chamber is the more convenient sampling method when the trapping is associated to a fast derivatisation of the compounds and the glass tube technique must be used to trap atmospheric compounds without simultaneous derivatisation.

High-pressure liquid chromatography with direct injection of gas sample.

PubMed

Astanin, Anton I; Baram, Grigory I

2017-06-09

The conventional method of using liquid chromatography to determine the composition of a gaseous mixture entails dissolving vapors in a suitable solvent, then obtaining a chromatograph of the resulting solution. We studied the direct introduction of a gaseous sample into a C18 reversed-phase column, followed by separation of the components by HPLC with UV detection. Since the chromatography was performed at high pressure, vapors readily dissolved in the eluent and the substances separated in the column as effectively as in liquid samples. Samples were injected into the column in two ways: a) through the valve without a flow stop; b) after stopping the flow and relieving all pressure. We showed that an injectable gas volume could reach 70% of column dead volume. When an injected gaseous sample volume was less than 10% of the column dead volume, the resulting peaks were symmetrical and the column efficiency was high. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of the KCl Denuder Method for Gaseous Oxidized Mercury using HgBr2 at an In-Service AMNet Site

NASA Astrophysics Data System (ADS)

McClure, Crystal

During the summer of 2013, we examined the performance of KCl-coated denuders for measuring gaseous oxidized mercury (GOM) by calibrating with a known source of GOM (i.e., HgBr2) at the North Birmingham SouthEastern Aerosol Research and Characterization (SEARCH) site. We found that KCl-coated denuders have near 95% collection efficiency for HgBr2 in zero air (i.e., air scrubbed of mercury and ozone). However, in ambient air, the efficiency of KCl-coated denuders in capturing HgBr2 dropped to 20-54%. We also found that absolute humidity and ozone each demonstrate a significant inverse correlation with HgBr2 recovery in ambient air. Subsequent laboratory tests with HgBr2 and the KCl-coated denuder show that ozone and absolute humidity cause the release of gaseous elemental Hg from the denuder and thus appear to explain the low recovery in ambient air. Based on these findings, we infer that the KCl denuder method underestimates atmospheric GOM concentrations. A calibration system is needed to accurately measure GOM. The system described in this paper for HgBr2 could be implemented with existing mercury speciation instrumentation and this would improve our knowledge of the response to one potentially important GOM compound.

Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

DOEpatents

Bennett, Ralph G.; Christian, Jerry D.; Kirkham, Robert J.; Tranter, Troy J.

1998-01-01

An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

Use of open-path FTIR and inverse dispersion technique to quantify gaseous nitrogen loss from an intensive vegetable production site

NASA Astrophysics Data System (ADS)

Bai, Mei; Suter, Helen; Lam, Shu Kee; Sun, Jianlei; Chen, Deli

2014-09-01

An open-path Fourier transform infrared (OP-FTIR) spectroscopic technique in combination with a backward Lagrangian stochastic (bLS) dispersion model (WindTrax) can be used to simultaneously measure gaseous emissions of N2O, NH3, CH4 and CO2. We assessed the capability of this technique for measuring NH3 and N2O emissions following the application of calcium nitrate (Ca(NO3)2), Nitrophoska (NPK) and chicken manure on a celery farm at Boneo, Victoria, during April and May 2013. We found that the OP-FTIR/WindTrax method was able to measure the diurnal variation in NH3 flux from the field site following application of chicken manure with measured emissions ranging from approximately 0.1-9.8 kg NH3-N ha-1 day-1. The OP-FTIR/WindTrax method also detected a diurnal variation in N2O flux of 1.5-6.2 kg N2O-N ha-1 day-1 and N2O flux increased in response to application of the Ca(NO3)2. We concluded that the OP-FTIR/WindTrax technique can quantify gaseous N loss from vegetable production systems.

Innovative Monitoring of Atmospheric Gaseous Hydrogen Fluoride

PubMed Central

Bonari, Alessandro; Pompilio, Ilenia; Monti, Alessandro; Arcangeli, Giulio

2016-01-01

Hydrogen fluoride (HF) is a basic raw material for a wide variety of industrial products, with a worldwide production capacity of more than three million metric tonnes. A novel method for determining particulate fluoride and gaseous hydrogen fluoride in air is presented herewith. Air was sampled using miniaturised 13 mm Swinnex two-stage filter holders in a medium-flow pumping system and through the absorption of particulate fluoride and HF vapours on cellulose ester filters uncoated or impregnated with sodium carbonate. Furthermore, filter desorption from the holders and the extraction of the pentafluorobenzyl ester derivative based on solid-phase microextraction were performed using an innovative robotic system installed on an xyz autosampler on-line with gas chromatography (GC)/mass spectrometry (MS). After generating atmospheres of a known concentration of gaseous HF, we evaluated the agreement between the results of our sampling method and those of the conventional preassembled 37 mm cassette (±8.10%; correlation coefficient: 0.90). In addition, precision (relative standard deviation for n = 10, 4.3%), sensitivity (0.2 μg/filter), and linearity (2.0–4000 μg/filter; correlation coefficient: 0.9913) were also evaluated. This procedure combines the efficiency of GC/MS systems with the high throughput (96 samples/day) and the quantitative accuracy of pentafluorobenzyl bromide on-sample derivatisation. PMID:27829835

49 CFR 538.8 - Gallon Equivalents for Gaseous Fuels.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 6 2011-10-01 2011-10-01 false Gallon Equivalents for Gaseous Fuels. 538.8... TRAFFIC SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION MANUFACTURING INCENTIVES FOR ALTERNATIVE FUEL VEHICLES § 538.8 Gallon Equivalents for Gaseous Fuels. The gallon equivalent of gaseous fuels, for purposes...

49 CFR 538.8 - Gallon Equivalents for Gaseous Fuels.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 6 2010-10-01 2010-10-01 false Gallon Equivalents for Gaseous Fuels. 538.8... TRAFFIC SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION MANUFACTURING INCENTIVES FOR ALTERNATIVE FUEL VEHICLES § 538.8 Gallon Equivalents for Gaseous Fuels. The gallon equivalent of gaseous fuels, for purposes...

Enhanced photocatalytic degradation of 2-propanol over macroporous GaN/ZnO solid solution prepared by a novel sol-gel method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Lizhong; Ouyang, Shuxin; Ren, Bofan

2015-10-01

Macroporous GaN/ZnO solid solution photocatalyst is synthesized through a novel sol-gel method under mild conditions. The performance of as-synthesized solid solution photocatalyst is evaluated for decomposition of gaseous 2-propanol (IPA). It is found that due to enhancement in both the adsorption to gaseous IPA and the absorbance to visible light, the porous GaN/ZnO solid solution exhibits a good photocatalytic performance for IPA decomposition. Moreover, the mechanism for photocatalytic degradation IPA over porous GaN/ZnO solid solution is also investigated in comparison with those for the two end materials ZnO and GaN. The trapping effects with different scavengers prove that both themore » photoexcited electrons and holes affect the IPA photodegradation process, simultaneously.« less

Preparation of B-trichloroborazine

NASA Technical Reports Server (NTRS)

Riccitiello, Salvatore R.; Hsu, Ming-Ta S.; Chen, Timothy S.

1987-01-01

The present invention relates to a method of preparing B-trichloroborazine. Generally, the method includes the combination of gaseous boron trichloride in an anhydrous aprotic organic solvent followed by addition of excess gaseous ammonia at ambient temperature or below. The reaction mixture is heated to about 100 to 140 C followed by cooling, removal of the solid ammonium chloride at ambient temperature, distillation of the solvent under vacuum if necessary at a temperature of up to about 112 C, and recovery of the B-trichloroborazine. Solvents include toluene, benzene, xylene, chlorinated hydrocarbons, chlorinated aromatic compounds, or mixtures thereof. Toluene is a preferred solvent. The process provides a convenient synthesis of a material which often decomposes on standing. B-trichloroborazine is useful in a number of chemical reactions, and particularly in the formation of high temperature inorganic polymers and polymer precursors.

46 CFR 131.815 - Alarm for fixed gaseous fire-extinguishing system.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 46 Shipping 4 2010-10-01 2010-10-01 false Alarm for fixed gaseous fire-extinguishing system. 131... VESSELS OPERATIONS Markings for Fire Equipment and Emergency Equipment § 131.815 Alarm for fixed gaseous fire-extinguishing system. Each alarm for a fixed gaseous fire-extinguishing system must be...

46 CFR 131.815 - Alarm for fixed gaseous fire-extinguishing system.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 46 Shipping 4 2011-10-01 2011-10-01 false Alarm for fixed gaseous fire-extinguishing system. 131... VESSELS OPERATIONS Markings for Fire Equipment and Emergency Equipment § 131.815 Alarm for fixed gaseous fire-extinguishing system. Each alarm for a fixed gaseous fire-extinguishing system must be...

Portsmouth Gaseous Diffusion Plant expansion: final environmental statement. Volume 2. Appendices. [Appendices only

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liverman, James L.

Volume 2 is comprised of appendices: Portsmouth Gaseous Diffusion Plant Existing Facilities; Ecology; Civic Involvement; Social Analysis; Population Projections; Toxicity of Air Pollutants to Biota at Portsmouth Gaseous Diffusion Plant; and Assessment of Noise Effects of an Add-On to the Portsmouth Gaseous Diffusion Plant. (LK)

77 FR 3255 - Notice of 229 Boundary Revision at the Paducah Gaseous Diffusion Plant

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-23

... DEPARTMENT OF ENERGY Notice of 229 Boundary Revision at the Paducah Gaseous Diffusion Plant AGENCY... areas, buildings, and other facilities of the Paducah Gaseous Diffusion Plant, located in McCracken... or upon this facility, installation, or real property of the Paducah Gaseous Diffusion Plant located...

High-Energy Propellant Rocket Firing at the Rocket Lab

NASA Image and Video Library

1955-01-21

A rocket using high-energy propellant is fired from the Rocket Laboratory at the National Advisory Committee for Aeronautics (NACA) Lewis Flight Propulsion Laboratory. The Rocket Lab was a collection of ten one-story cinderblock test cells located behind earthen barriers at the western edge of the campus. The rocket engines tested there were comparatively small, but the Lewis researchers were able to study different configurations, combustion performance, and injectors and nozzle design. The rockets were generally mounted horizontally and fired, as seen in this photograph of Test Cell No. 22. A group of fuels researchers at Lewis refocused their efforts after World War II in order to explore high energy propellants, combustion, and cooling. Research in these three areas began in 1945 and continued through the 1960s. The group of rocket researches was not elevated to a division branch until 1952. The early NACA Lewis work led to the development of liquid hydrogen as a viable propellant in the late 1950s. Following the 1949 reorganization of the research divisions, the rocket group began working with high-energy propellants such as diborane, pentaborane, and hydrogen. The lightweight fuels offered high levels of energy but were difficult to handle and required large tanks. In late 1954, Lewis researchers studied the combustion characteristics of gaseous hydrogen in a turbojet combustor. Despite poor mixing of the fuel and air, it was found that the hydrogen yielded more than a 90-percent efficiency. Liquid hydrogen became the focus of Lewis researchers for the next 15 years.

Method and apparatus for conversion of carbonaceous materials to liquid fuel

DOEpatents

Lux, Kenneth W.; Namazian, Mehdi; Kelly, John T.

2015-12-01

Embodiments of the invention relates to conversion of hydrocarbon material including but not limited to coal and biomass to a synthetic liquid transportation fuel. The invention includes the integration of a non-catalytic first reaction scheme, which converts carbonaceous materials into a solid product that includes char and ash and a gaseous product; a non-catalytic second reaction scheme, which converts a portion of the gaseous product from the first reaction scheme to light olefins and liquid byproducts; a traditional gas-cleanup operations; and the third reaction scheme to combine the olefins from the second reaction scheme to produce a targeted fuel like liquid transportation fuels.

NOx formation in combustion of gaseous fuel in ejection burner

NASA Astrophysics Data System (ADS)

Rimár, Miroslav; Kulikov, Andrii

2016-06-01

The aim of this work is to prepare model for researching of the formation in combustion of gaseous fuels. NOx formation is one of the main ecological problems nowadays as nitrogen oxides is one of main reasons of acid rains. The ANSYS model was designed according to the calculation to provide full combustion and good mixing of the fuel and air. The current model is appropriate to research NOx formation and the influence of the different principles of NOx reduction method. Applying of designed model should spare both time of calculations and research and also money as you do not need to measure the burner characteristics.

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and... Gaseous Exhaust Test Procedures § 91.414 Raw gaseous exhaust sampling and analytical system description... the component systems. (g) The following requirements must be incorporated in each system used for raw...

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and... OR BELOW 19 KILOWATTS Gaseous Exhaust Test Procedures § 90.414 Raw gaseous exhaust sampling and... between the muffler and the sample probe. The mixing chamber is an optional component of the raw gas...

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and... Gaseous Exhaust Test Procedures § 91.414 Raw gaseous exhaust sampling and analytical system description... the component systems. (g) The following requirements must be incorporated in each system used for raw...

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and... OR BELOW 19 KILOWATTS Gaseous Exhaust Test Procedures § 90.414 Raw gaseous exhaust sampling and... between the muffler and the sample probe. The mixing chamber is an optional component of the raw gas...

40 CFR 86.127-00 - Test procedures; overview.

Code of Federal Regulations, 2013 CFR

2013-07-01

... following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and gaseous- fueled... vehicles). (b) The FTP Otto-cycle exhaust emission test is designed to determine gaseous THC, CO, CO2, CH4... determine gaseous THC, NMHC, CO, CO2, CH4, and NOX emissions from gasoline-fueled or diesel-fueled vehicles...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2012 CFR

2012-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2013 CFR

2013-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-00 - Test procedures; overview.

Code of Federal Regulations, 2014 CFR

2014-07-01

... following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and gaseous- fueled... vehicles). (b) The FTP Otto-cycle exhaust emission test is designed to determine gaseous THC, CO, CO2, CH4... determine gaseous THC, NMHC, CO, CO2, CH4, and NOX emissions from gasoline-fueled or diesel-fueled vehicles...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2011 CFR

2011-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-00 - Test procedures; overview.

Code of Federal Regulations, 2012 CFR

2012-07-01

... following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and gaseous- fueled... vehicles). (b) The FTP Otto-cycle exhaust emission test is designed to determine gaseous THC, CO, CO2, CH4... determine gaseous THC, NMHC, CO, CO2, CH4, and NOX emissions from gasoline-fueled or diesel-fueled vehicles...

On Partial Fraction Decompositions by Repeated Polynomial Divisions

ERIC Educational Resources Information Center

Man, Yiu-Kwong

2017-01-01

We present a method for finding partial fraction decompositions of rational functions with linear or quadratic factors in the denominators by means of repeated polynomial divisions. This method does not involve differentiation or solving linear equations for obtaining the unknown partial fraction coefficients, which is very suitable for either…

40 CFR Appendix D to Part 61 - Methods for Estimating Radionuclide Emissions

Code of Federal Regulations, 2011 CFR

2011-07-01

... Table 1. Table 1—Adjustment to Emission Factors for Effluent Controls Controls Types of radionuclides... applicable to gaseous radionuclides; periodic testing is prudent to ensure high removal efficiency. Fabric...

40 CFR Appendix D to Part 61 - Methods for Estimating Radionuclide Emissions

Code of Federal Regulations, 2013 CFR

2013-07-01

... Table 1. Table 1—Adjustment to Emission Factors for Effluent Controls Controls Types of radionuclides... applicable to gaseous radionuclides; periodic testing is prudent to ensure high removal efficiency. Fabric...

Method for removing oxide contamination from silicon carbide powders

DOEpatents

Brynestad, J.; Bamberger, C.E.

1984-08-01

The described invention is directed to a method for removing oxide contamination in the form of oxygen-containing compounds such as SiO/sub 2/ and B/sub 2/O/sub 3/ from a charge of finely divided silicon carbide. The silicon carbide charge is contacted with a stream of hydrogen fluoride mixed with an inert gas carrier such as argon at a temperature in the range of about 200/sup 0/ to 650/sup 0/C. The oxides in the charge react with the heated hydrogen fluoride to form volatile gaseous fluorides such as SiF/sub 4/ and BF/sub 3/ which pass through the charge along with unreacted hydrogen fluoride and the carrier gas. Any residual gaseous reaction products and hydrogen fluoride remaining in the charge are removed by contacting the charge with the stream of inert gas which also cools the powder to room temperature. The removal of the oxygen contamination by practicing the present method provides silicon carbide powders with desirable pressing and sintering characteristics. 1 tab.

Research on Geographical Environment Unit Division Based on the Method of Natural Breaks (Jenks)

NASA Astrophysics Data System (ADS)

Chen, J.; Yang, S. T.; Li, H. W.; Zhang, B.; Lv, J. R.

2013-11-01

Zoning which is to divide the study area into different zones according to their geographical differences at the global, national or regional level, includes natural division, economic division, geographical zoning of departments, comprehensive zoning and so on. Zoning is of important practical significance, for example, knowing regional differences and characteristics, regional research and regional development planning, understanding the favorable and unfavorable conditions of the regional development etc. Geographical environment is arising from the geographical position linkages. Geographical environment unit division is also a type of zoning. The geographical environment indicators are deeply studied and summed up in the article, including the background, the associated and the potential. The background indicators are divided into four categories, such as the socio-economic, the political and military, the strategic resources and the ecological environment, which can be divided into more sub-indexes. While the sub-indexes can be integrated to comprehensive index system by weighted stacking method. The Jenks natural breaks classification method, also called the Jenks optimization method, is a data classification method designed to determine the best arrangement of values into different classes. This is done by seeking to minimize each class's average deviation from the class mean, while maximizing each class's deviation from the means of the other groups. In this paper, the experiment of Chinese surrounding geographical environment unit division has been done based on the natural breaks (jenks) method, the geographical environment index system and the weighted stacking method, taking South Asia as an example. The result indicates that natural breaks (jenks) method is of good adaptability and high accuracy on the geographical environment unit division. The geographical environment research was originated in the geopolitics and flourished in the geo-economics. The main representatives of the geopolitics are German geographer Friedrich Ratzel, British geographer Mackinder and American geographical politician Nicholas John Spykman etc. The main representative of the geo-economics is American geographical economist Edward Luttwak. China has the most neighboring countries in the world, and its geographical environment is extremely complex. With the continuous development of globalization, China's relations with neighboring countries have become more complex and more closely. So it is very meaningful to have depth research on geographical environment unit division of China.

40 CFR 63.7142 - What are the requirements for claiming area source status?

Code of Federal Regulations, 2013 CFR

2013-07-01

... test must be repeated. (v) The post-test analyte spike procedure of section 11.2.7 of ASTM Method D6735... (3) ASTM Method D6735-01, Standard Test Method for Measurement of Gaseous Chlorides and Fluorides...)(3)(i) through (vi) of this section are followed. (i) A test must include three or more runs in which...

40 CFR 63.7142 - What are the requirements for claiming area source status?

Code of Federal Regulations, 2011 CFR

2011-07-01

... test must be repeated. (v) The post-test analyte spike procedure of section 11.2.7 of ASTM Method D6735... (3) ASTM Method D6735-01, Standard Test Method for Measurement of Gaseous Chlorides and Fluorides...)(3)(i) through (vi) of this section are followed. (i) A test must include three or more runs in which...

40 CFR 63.7142 - What are the requirements for claiming area source status?

Code of Federal Regulations, 2012 CFR

2012-07-01

... test must be repeated. (v) The post-test analyte spike procedure of section 11.2.7 of ASTM Method D6735... (3) ASTM Method D6735-01, Standard Test Method for Measurement of Gaseous Chlorides and Fluorides...)(3)(i) through (vi) of this section are followed. (i) A test must include three or more runs in which...

40 CFR 63.7142 - What are the requirements for claiming area source status?

Code of Federal Regulations, 2010 CFR

2010-07-01

... test must be repeated. (v) The post-test analyte spike procedure of section 11.2.7 of ASTM Method D6735... (3) ASTM Method D6735-01, Standard Test Method for Measurement of Gaseous Chlorides and Fluorides...)(3)(i) through (vi) of this section are followed. (i) A test must include three or more runs in which...

40 CFR 63.7142 - What are the requirements for claiming area source status?

Code of Federal Regulations, 2014 CFR

2014-07-01

... test must be repeated. (v) The post-test analyte spike procedure of section 11.2.7 of ASTM Method D6735... (3) ASTM Method D6735-01, Standard Test Method for Measurement of Gaseous Chlorides and Fluorides...)(3)(i) through (vi) of this section are followed. (i) A test must include three or more runs in which...

Onsite Gaseous Centrifuge Enrichment Plant UF6 Cylinder Destructive Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong

2012-07-17

The IAEA safeguards approach for gaseous centrifuge enrichment plants (GCEPs) includes measurements of gross, partial, and bias defects in a statistical sampling plan. These safeguard methods consist principally of mass and enrichment nondestructive assay (NDA) verification. Destructive assay (DA) samples are collected from a limited number of cylinders for high precision offsite mass spectrometer analysis. DA is typically used to quantify bias defects in the GCEP material balance. Under current safeguards measures, the operator collects a DA sample from a sample tap following homogenization. The sample is collected in a small UF6 sample bottle, then sealed and shipped under IAEAmore » chain of custody to an offsite analytical laboratory. Current practice is expensive and resource intensive. We propose a new and novel approach for performing onsite gaseous UF6 DA analysis that provides rapid and accurate assessment of enrichment bias defects. DA samples are collected using a custom sampling device attached to a conventional sample tap. A few micrograms of gaseous UF6 is chemically adsorbed onto a sampling coupon in a matter of minutes. The collected DA sample is then analyzed onsite using Laser Ablation Absorption Ratio Spectrometry-Destructive Assay (LAARS-DA). DA results are determined in a matter of minutes at sufficient accuracy to support reliable bias defect conclusions, while greatly reducing DA sample volume, analysis time, and cost.« less

Visible-Light Upconversion Carbon Quantum Dots Decorated TiO2 for the Photodegradation of Flowing Gaseous Acetaldehyde

NASA Astrophysics Data System (ADS)

Hu, Yidan; Xie, Xiaofeng; Wang, Xiao; Wang, Yan; Zeng, Yi; Pui, David Y. H.; Sun, Jing

2018-05-01

Carbon-modified photocatalyst has attracted extensive attentions in the field of gaseous pollutant removal, mainly due to the improved adsorption properties and electronic transport of carbon matrix, such as carbon nanotubes, graphene, and fullerene, etc. In this work, carbon quantum dots (CQDs) were employed to enhance the photocatalytic performance of TiO2-based composites for flowing gaseous acetaldehyde removal. Besides the aforementioned advantages of carbon materials, the unique up-converted photoluminescence property of CQDs is capable of extending the optical absorption to visible-light range. Moreover, the electron spin resonance (ESR) results firstly verified a stable existence of Ti3+ defect in the CQDs/TiO2 composite, which is possibly induced by the electron migration from CQDs to TiO2. And the formed Ti3+ donor energy level in the band gap could further help with the visible-light harvesting. During the photodegradation experiments, with two-hour continuous flowing gaseous acetaldehyde injection (500 ppm, 20 sccm), the CQDs/TiO2 composite remained 99% removal efficiency under fluorescent lamp irradiation (λ > 380 nm). The optimized CQDs content was obtained as 3 wt%, and the underlying mechanism was further analyzed by temperature programmed desorption (TPD) methods. This work will push forward the air purification researches by providing new insights of CQDs sensitized photocatalyst.

Consumption of Sport-Related Dietary Supplements among NCAA Division 1 Female Student Athletes

ERIC Educational Resources Information Center

Housman, Jeff; Dorman, Steve; Pruitt, Buzz; Ranjita, Misra; Perko, Michael

2011-01-01

Objectives: To determine factors that influence sport-related dietary supplement consumption among NCAA Division 1 female student athletes and to estimate the plausibility of the theory of planned behavior (TPB) for predicting the use of sport-related dietary supplements among NCAA Division 1 female student athletes. Method: Self-report data were…

Results of Small-scale Solid Rocket Combustion Simulator testing at Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Goldberg, Benjamin E.; Cook, Jerry

1993-01-01

The Small-scale Solid Rocket Combustion Simulator (SSRCS) program was established at the Marshall Space Flight Center (MSFC), and used a government/industry team consisting of Hercules Aerospace Corporation, Aerotherm Corporation, United Technology Chemical Systems Division, Thiokol Corporation and MSFC personnel to study the feasibility of simulating the combustion species, temperatures and flow fields of a conventional solid rocket motor (SRM) with a versatile simulator system. The SSRCS design is based on hybrid rocket motor principles. The simulator uses a solid fuel and a gaseous oxidizer. Verification of the feasibility of a SSRCS system as a test bed was completed using flow field and system analyses, as well as empirical test data. A total of 27 hot firings of a subscale SSRCS motor were conducted at MSFC. Testing of the Small-scale SSRCS program was completed in October 1992. This paper, a compilation of reports from the above team members and additional analysis of the instrumentation results, will discuss the final results of the analyses and test programs.

Design and development of the Waukesha AT25GL series gas engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pohl, J.M.

1988-01-01

Waukesha Engine Division of Dresser Industries is developing a new family of gaseous fueled, spark ignited engines. Derived from the Waukesha/Silzer AT25 diesel engine family, the AT25GL series consists of three models - the 8L-AT25GL (in-line 8 cylinder), the 12V-AT25GL (vee 12 cylinder), and the 16V-AT25GL (vee 16 cylinder). Like its sister engine, the VHP-GL, the AT25GL utilizes lean combustion technology. As such, it is inherently fuel efficient and emits low levels of nitrogen oxides, carbon monoxide and unburnt hydrocarbons. Targeted for two primary markets, electric power generation and gas compression, the AT25GL is rated at 170 KW per cylindermore » at 1000 rpm and 154 KW per cylinder at 900 rpm. This paper outlines Waukesha's initial effort in this program - design and development of the 12V-AT25GL.« less

Bernard J. Wood Receives 2013 Harry H. Hess Medal: Citation

NASA Astrophysics Data System (ADS)

Hofmann, Albrecht W.

2014-01-01

As Harry Hess recognized over 50 years ago, mantle melting is the fundamental motor for planetary evolution and differentiation. Melting generates the major divisions of crust mantle and core. The distribution of chemical elements between solids, melts, and gaseous phases is fundamental to understanding these differentiation processes. Bernie Wood, together with Jon Blundy, has combined experimental petrology and physicochemical theory to revolutionize the understanding of the distribution of trace elements between melts and solids in the Earth. Knowledge of these distribution laws allows the reconstruction of the source compositions of the melts (deep in Earth's interior) from their abundances in volcanic rocks. Bernie's theoretical treatment relates the elastic strain of the lattice caused by the substitution of a trace element in a crystal to the ionic radius and charge of this element. This theory, and its experimental calibrations, brought order to a literature of badly scattered, rather chaotic experimental data that allowed no satisfactory quantitative modeling of melting processes in the mantle.

Method of depositing wide bandgap amorphous semiconductor materials

DOEpatents

Ellis, Jr., Frank B.; Delahoy, Alan E.

1987-09-29

A method of depositing wide bandgap p type amorphous semiconductor materials on a substrate without photosensitization by the decomposition of one or more higher order gaseous silanes in the presence of a p-type catalytic dopant at a temperature of about 200.degree. C. and a pressure in the range from about 1-50 Torr.

Maskless laser writing of microscopic metallic interconnects

DOEpatents

Maya, Leon

1995-01-01

A method of forming a metal pattern on a substrate. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern.

Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

DOEpatents

Luebke, David; Nulwala, Hunald; Tang, Chau

2014-12-09

A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

Corrosion protection for silver reflectors

DOEpatents

Arendt, Paul N.; Scott, Marion L.

1991-12-31

A method of protecting silver reflectors from damage caused by contact with gaseous substances which are often present in the atmosphere and a silver reflector which is so protected. The inventive method comprises at least partially coating a reflector with a metal oxide such as aluminum oxide to a thickness of 15 .ANG. or less.

Work management plan for data systems and analysis directorate

NASA Technical Reports Server (NTRS)

Nichols, L. R.

1979-01-01

A contract with the Data Systems and Analysis Directorate contains a specified level of resources related to a specific set of work in support of three divisions within the Data Systems and Analysis Directorate. The divisions are Institutional Data Systems Division, Ground Data Systems Division, and Mission Planning and Analysis Division. The Statement of work defines at a functional requirements level the type of support to be provided to the three divisions. The contract provides for further technical direction to the contractor through issuance of Job Orders. The Job order is the prime method of further defining the work to be done, allocating a portion of the total resources in the contract to the defined tasks, and further delegating technical responsibility.

Quantifying cell turnover using CFSE data.

PubMed

Ganusov, Vitaly V; Pilyugin, Sergei S; de Boer, Rob J; Murali-Krishna, Kaja; Ahmed, Rafi; Antia, Rustom

2005-03-01

The CFSE dye dilution assay is widely used to determine the number of divisions a given CFSE labelled cell has undergone in vitro and in vivo. In this paper, we consider how the data obtained with the use of CFSE (CFSE data) can be used to estimate the parameters determining cell division and death. For a homogeneous cell population (i.e., a population with the parameters for cell division and death being independent of time and the number of divisions cells have undergone), we consider a specific biologically based "Smith-Martin" model of cell turnover and analyze three different techniques for estimation of its parameters: direct fitting, indirect fitting and rescaling method. We find that using only CFSE data, the duration of the division phase (i.e., approximately the S+G2+M phase of the cell cycle) can be estimated with the use of either technique. In some cases, the average division or cell cycle time can be estimated using the direct fitting of the model solution to the data or by using the Gett-Hodgkin method [Gett A. and Hodgkin, P. 2000. A cellular calculus for signal integration by T cells. Nat. Immunol. 1:239-244]. Estimation of the death rates during commitment to division (i.e., approximately the G1 phase of the cell cycle) and during the division phase may not be feasible with the use of only CFSE data. We propose that measuring an additional parameter, the fraction of cells in division, may allow estimation of all model parameters including the death rates during different stages of the cell cycle.

Divisions of geologic time-major chronostratigraphic and geochronologic units

USGS Publications Warehouse

,

2010-01-01

Effective communication in the geosciences requires consistent uses of stratigraphic nomenclature, especially divisions of geologic time. A geologic time scale is composed of standard stratigraphic divisions based on rock sequences and is calibrated in years. Over the years, the development of new dating methods and the refinement of previous methods have stimulated revisions to geologic time scales. Advances in stratigraphy and geochronology require that any time scale be periodically updated. Therefore, Divisions of Geologic Time, which shows the major chronostratigraphic (position) and geochronologic (time) units, is intended to be a dynamic resource that will be modified to include accepted changes of unit names and boundary age estimates. This fact sheet is a modification of USGS Fact Sheet 2007-3015 by the U.S. Geological Survey Geologic Names Committee.

An algol program for dissimilarity analysis: a divisive-omnithetic clustering technique

USGS Publications Warehouse

Tipper, J.C.

1979-01-01

Clustering techniques are used properly to generate hypotheses about patterns in data. Of the hierarchical techniques, those which are divisive and omnithetic possess many theoretically optimal properties. One such method, dissimilarity analysis, is implemented here in ALGOL 60, and determined to be competitive computationally with most other methods. ?? 1979.

40 CFR 89.309 - Analyzers required for gaseous emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... condensation is acceptable. A water trap performing this function and meeting the specifications in § 89.308(b) is an acceptable method. Means other than condensation may be used only with prior approval from the...

40 CFR 89.309 - Analyzers required for gaseous emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... condensation is acceptable. A water trap performing this function and meeting the specifications in § 89.308(b) is an acceptable method. Means other than condensation may be used only with prior approval from the...

40 CFR 89.309 - Analyzers required for gaseous emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... condensation is acceptable. A water trap performing this function and meeting the specifications in § 89.308(b) is an acceptable method. Means other than condensation may be used only with prior approval from the...

Diamond Nucleation Using Polyethene

NASA Technical Reports Server (NTRS)

Morell, Gerardo (Inventor); Makarov, Vladimir (Inventor); Varshney, Deepak (Inventor); Weiner, Brad (Inventor)

2013-01-01

The invention presents a simple, non-destructive and non-abrasive method of diamond nucleation using polyethene. It particularly describes the nucleation of diamond on an electrically viable substrate surface using polyethene via chemical vapor deposition (CVD) technique in a gaseous environment.

Diamond nucleation using polyethene

DOEpatents

Morell, Gerardo; Makarov, Vladimir; Varshney, Deepak; Weiner, Brad

2013-07-23

The invention presents a simple, non-destructive and non-abrasive method of diamond nucleation using polyethene. It particularly describes the nucleation of diamond on an electrically viable substrate surface using polyethene via chemical vapor deposition (CVD) technique in a gaseous environment.

NMR measurements of gaseous sulfur hexafluoride (SF6) to probe the cross-linking of EPDM rubber.

PubMed

Terekhov, M; Neutzler, S; Aluas, M; Hoepfel, D; Oellrich, L R

2005-11-01

The effects of embedding gaseous SF6 into EPDM rubber were investigated using NMR methods. It was found that observed sorption and desorption processes follow the behavior of the dual mode sorption model. A strong correlation was found between EPDM cross-linking and transversal relaxation time of embedded SF6. EPDM samples with different cross-link densities, preliminarily determined by 1H transversal relaxation using the Gotlib model and Litvinov's method, were investigated using embedded SF6. The sensitivity of the 19F transversal relaxation rate of SF6 to the EPDM cross-link density variation was found to be at least 10 times higher than for 1H in the polymer chain. First experiments on probing the swelling effects in EPDM due to its contact with polar liquids have been performed. Copyright (c) 2005 John Wiley & Sons, Ltd.

Method and device for determining heats of combustion of gaseous hydrocarbons

NASA Technical Reports Server (NTRS)

Singh, Jag J. (Inventor); Sprinkle, Danny R. (Inventor); Puster, Richard L. (Inventor)

1988-01-01

A method and device is provided for a quick, accurate and on-line determination of heats of combustion of gaseous hydrocarbons. First, the amount of oxygen in the carrier air stream is sensed by an oxygen sensing system. Second, three individual volumetric flow rates of oxygen, carrier stream air, and hydrocrabon test gas are introduced into a burner. The hydrocarbon test gas is fed into the burner at a volumetric flow rate, n, measured by a flowmeter. Third, the amount of oxygen in the resulting combustion products is sensed by an oxygen sensing system. Fourth, the volumetric flow rate of oxygen is adjusted until the amount of oxygen in the combustion product equals the amount of oxygen previously sensed in the carrier air stream. This equalizing volumetric flow rate is m and is measured by a flowmeter. The heat of combustion of the hydrocrabon test gas is then determined from the ratio m/n.

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

DOEpatents

Heffel, James W [Lake Matthews, CA; Scott, Paul B [Northridge, CA; Park, Chan Seung [Yorba Linda, CA

2011-11-01

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

DOEpatents

Heffel, James W.; Scott, Paul B.

2003-09-02

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Container and method for absorbing and reducing hydrogen concentration

DOEpatents

Wicks, George G.; Lee, Myung W.; Heung, Leung K.

2001-01-01

A method for absorbing hydrogen from an enclosed environment comprising providing a vessel; providing a hydrogen storage composition in communication with a vessel, the hydrogen storage composition further comprising a matrix defining a pore size which permits the passage of hydrogen gas while blocking the passage of gaseous poisons; placing a material within the vessel, the material evolving hydrogen gas; sealing the vessel; and absorbing the hydrogen gas released into the vessel by the hydrogen storage composition. A container for absorbing evolved hydrogen gas comprising: a vessel having an interior and adapted for receiving materials which release hydrogen gas; a hydrogen absorbing composition in communication with the interior, the composition defining a matrix surrounding a hydrogen absorber, the matrix permitting the passage of hydrogen gas while excluding gaseous poisons; wherein, when the vessel is sealed, hydrogen gas, which is released into the vessel interior, is absorbed by the hydrogen absorbing composition.

Enhanced methods for operating refueling station tube-trailers to reduce refueling cost

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elgowainy, Amgad; Reddi, Krishna

A method and apparatus are provided for operating a refueling station including source tube-trailers and at least one compressor to reduce refueling cost. The refueling station includes a gaseous fuel supply source including a plurality of tanks on a tube trailer coupled to a first control unit, and high pressure buffer storage having predefined capacity coupled to a second control unit and the first tanks by a pressure control valve and the first control unit, and at least one compressor. The refueling station is operated at different modes depending on a state of the refueling station at the beginning ofmore » each operational mode. The refueling system is assessed at the end of each operational mode to identify the state of the system and select a next mode of operation. The operational modes include consolidating hydrogen, or any gaseous fuel, within the tubes mounted on the trailer.« less

Simulation of gaseous diffusion in partially saturated porous media under variable gravity with lattice Boltzmann methods

NASA Technical Reports Server (NTRS)

Chau, Jessica Furrer; Or, Dani; Sukop, Michael C.; Steinberg, S. L. (Principal Investigator)

2005-01-01

Liquid distributions in unsaturated porous media under different gravitational accelerations and corresponding macroscopic gaseous diffusion coefficients were investigated to enhance understanding of plant growth conditions in microgravity. We used a single-component, multiphase lattice Boltzmann code to simulate liquid configurations in two-dimensional porous media at varying water contents for different gravity conditions and measured gas diffusion through the media using a multicomponent lattice Boltzmann code. The relative diffusion coefficients (D rel) for simulations with and without gravity as functions of air-filled porosity were in good agreement with measured data and established models. We found significant differences in liquid configuration in porous media, leading to reductions in D rel of up to 25% under zero gravity. The study highlights potential applications of the lattice Boltzmann method for rapid and cost-effective evaluation of alternative plant growth media designs under variable gravity.

Direct estimation of diffuse gaseous emissions from coal fires: current methods and future directions

USGS Publications Warehouse

Engle, Mark A.; Olea, Ricardo A.; O'Keefe, Jennifer M. K.; Hower, James C.; Geboy, Nicholas J.

2013-01-01

Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques. Overview of these methods for direct estimation of diffuse gas emissions from coal fires is presented in this paper. Here we take advantage of stochastic Gaussian simulation to interpolate CO2 fluxes measured using a dynamic closed chamber at the Ruth Mullins coal fire in Perry County, Kentucky. This approach allows for preparing a map of diffuse gas emissions, one of the two primary ways that gases emanate from coal fires, and establishing the reliability of the study both locally and for the entire fire. Future research directions include continuous and automated sampling to improve quantification of gaseous coal fire emissions.

Molecular separation method and apparatus

DOEpatents

Villa-Aleman, Eliel

1996-01-01

A method and apparatus for separating a gaseous mixture of chemically identical but physically different molecules based on their polarities. The gaseous mixture of molecules is introduced in discrete quantities into the proximal end of a porous glass molecular. The molecular sieve is exposed to microwaves to excite the molecules to a higher energy state from a lower energy state, those having a higher dipole moment being excited more than those with a lower energy state. The temperature of the sieve kept cold by a flow of liquid nitrogen through a cooling jacket so that the heat generated by the molecules colliding with the material is transferred away from the material. The molecules thus alternate between a higher energy state and a lower one, with the portion of molecules having the higher dipole moment favored over the others. The former portion can then be extracted separately from the distal end of the molecular sieve.

Molecular separation method and apparatus

DOEpatents

Villa-Aleman, E.

1996-04-09

A method and apparatus are disclosed for separating a gaseous mixture of chemically identical but physically different molecules based on their polarities. The gaseous mixture of molecules is introduced in discrete quantities into the proximal end of a porous glass molecular sieve. The molecular sieve is exposed to microwaves to excite the molecules to a higher energy state from a lower energy state, those having a higher dipole moment being excited more than those with a lower energy state. The temperature of the sieve kept cold by a flow of liquid nitrogen through a cooling jacket so that the heat generated by the molecules colliding with the material is transferred away from the material. The molecules thus alternate between a higher energy state and a lower one, with the portion of molecules having the higher dipole moment favored over the others. The former portion can then be extracted separately from the distal end of the molecular sieve. 2 figs.

Laminar and Turbulent Gaseous Diffusion Flames. Appendix C

NASA Technical Reports Server (NTRS)

Faeth, G. M.; Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

2001-01-01

Recent measurements and predictions of the properties of homogeneous (gaseous) laminar and turbulent non-premixed (diffusion) flames are discussed, emphasizing results from both ground- and space-based studies at microgravity conditions. Initial considerations show that effects of buoyancy not only complicate the interpretation of observations of diffusion flames but at times mislead when such results are applied to the non-buoyant diffusion flame conditions of greatest practical interest. This behavior motivates consideration of experiments where effects of buoyancy are minimized; therefore, methods of controlling the intrusion of buoyancy during observations of non-premixed flames are described, considering approaches suitable for both normal laboratory conditions as well as classical microgravity techniques. Studies of laminar flames at low-gravity and microgravity conditions are emphasized in view of the computational tractability of such flames for developing methods of predicting flame structure as well as the relevance of such flames to more practical turbulent flames by exploiting laminar flamelet concepts.

MANTECH project book

NASA Astrophysics Data System (ADS)

The effective integration of processes, systems, and procedures used in the production of aerospace systems using computer technology is managed by the Integration Technology Division (MTI). Under its auspices are the Information Management Branch, which is actively involved with information management, information sciences and integration, and the Implementation Branch, whose technology areas include computer integrated manufacturing, engineering design, operations research, and material handling and assembly. The Integration Technology Division combines design, manufacturing, and supportability functions within the same organization. The Processing and Fabrication Division manages programs to improve structural and nonstructural materials processing and fabrication. Within this division, the Metals Branch directs the manufacturing methods program for metals and metal matrix composites processing and fabrication. The Nonmetals Branch directs the manufacturing methods programs, which include all manufacturing processes for producing and utilizing propellants, plastics, resins, fibers, composites, fluid elastomers, ceramics, glasses, and coatings. The objective of the Industrial Base Analysis Division is to act as focal point for the USAF industrial base program for productivity, responsiveness, and preparedness planning.

Effects of Diode Laser, Gaseous Ozone, and Medical Dressings on Enterococcus faecalis Biofilms in the Root Canal Ex Vivo

PubMed Central

Vlassakidis, Alexander; Niepel, Mediha; Hoedke, Daniela; Schulze, Julia; Neumann, Konrad; Moter, Annette; Noetzel, Jörn

2017-01-01

The objective was to compare the antibacterial effects of adjunctive disinfection using diode laser and gaseous ozone compared to the medical dressings calcium hydroxide (Ca(OH)2) and chlorhexidine gel (CHX-Gel) on Enterococcus faecalis biofilms in human root canals ex vivo. Root canals of 180 human extracted teeth were infected by E. faecalis and divided into 3 main groups (G): G1, control; G2, instrumentation and irrigation using 0.9% NaCl; G3, instrumentation and irrigation using 1% NaOCl. In each main group, the following treatments were applied: gaseous ozone, diode laser, and medical dressings of Ca(OH)2 or CHX-Gel for 7 days (n = 15). Reduction of colony forming units (CFUs) inside the root canal of planktons and frequencies of adherent bacteria after treatment were calculated. Bacterial reduction was significantly affected by the irrigation protocol (p < 0.0005) and the disinfection method (p < 0.0005), and a significant interaction between both factors could be observed (p < 0.0005; ANOVA). In G3 (instrumentation using 1% NaOCl), no significant effect of disinfection methods could be demonstrated on planktonic bacteria (p = 0.062; ANOVA) and frequencies of adherent bacteria (p > 0.05; chi-square test). Instrumentation and irrigation using NaOCl combined with ozone or laser application resulted in comparable bacterial reduction on E. faecalis to the application of medical dressings. PMID:28567421

Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

DOEpatents

Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

1998-09-01

An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

Preparing for Exit from Sport: A Phenomenological Examination of the Pre-Transition Experiences of Division I Female Intercollegiate Athletes

ERIC Educational Resources Information Center

Archer, David Eric

2010-01-01

Scope and Method of Study: The purpose of this study was to discover the meanings female intercollegiate athletes ascribe to their experiences preceding exit from NCAA Division I competition. The study sample included five Division I female intercollegiate athletes. Four of these attended a large public research institution in the Southern Plains…

Mechanical design

NASA Technical Reports Server (NTRS)

1976-01-01

Design concepts for a 1000 mw thermal stationary power plant employing the UF6 fueled gas core breeder reactor are examined. Three design combinations-gaseous UF6 core with a solid matrix blanket, gaseous UF6 core with a liquid blanket, and gaseous UF6 core with a circulating blanket were considered. Results show the gaseous UF6 core with a circulating blanket was best suited to the power plant concept.

Method of CO.sub.2 removal from a gasesous stream at reduced temperature

DOEpatents

Fisher, James C; Siriwardane, Ranjani V; Berry, David A; Richards, George A

2014-11-18

A method for the removal of H.sub.2O and CO.sub.2 from a gaseous stream comprising H.sub.2O and CO.sub.2, such as a flue gas. The method initially utilizes an H.sub.2O removal sorbent to remove some portion of the H.sub.2O, producing a dry gaseous stream and a wet H.sub.2O removal sorbent. The dry gaseous stream is subsequently contacted with a CO.sub.2 removal sorbent to remove some portion of the CO.sub.2, generating a dry CO.sub.2 reduced stream and a loaded CO.sub.2 removal sorbent. The loaded CO.sub.2 removal sorbent is subsequently heated to produce a heated CO.sub.2 stream. The wet H.sub.2O removal sorbent and the dry CO.sub.2 reduced stream are contacted in a first regeneration stage, generating a partially regenerated H.sub.2O removal sorbent, and the partially regenerated H.sub.2O removal sorbent and the heated CO.sub.2 stream are subsequently contacted in a second regeneration stage. The first and second stage regeneration typically act to retain an initial monolayer of moisture on the various removal sorbents and only remove moisture layers bound to the initial monolayer, allowing for relatively low temperature and pressure operation. Generally the applicable H.sub.2O sorption/desorption processes may be conducted at temperatures less than about 70.degree. C. and pressures less than 1.5 atmospheres, with certain operations conducted at temperatures less than about 50.degree. C.

Application of Coal Thermal Treatment Technology for Oil-Free Firing of Boilers

NASA Astrophysics Data System (ADS)

Aliyarov, B.; Mergalimova, A.; Zhalmagambetova, U.

2018-04-01

The theoretical and practical introduction of this kind of firing boiler units in coal thermal power plants is considered in the article. The results of an experimental study of three types of coals are presented in order to obtain the required gaseous fuel. The aim of the study is to develop a new, economically and ecologically more acceptable method for firing boilers at thermal power plants, which is able to exclude the use of expensive and inconvenient fuel oil. The tasks of the experiment are to develop a technological scheme of kindling of boilers at thermal power plants, using as a type of ignition fuel volatile combustible substances released during the heating of coal, and to investigate three types of coal for the suitability of obtaining gaseous fuels, in sufficient volume and with the required heat of combustion. The research methods include the analysis of technical and scientific-methodological literature on the problem of the present study, the study of the experience of scientists of other countries, the full-scale experiment on the production of volatile combustible substances. During the full-scale experiment, the coal of 3 fields of Kazakhstan has been studied: Shubarkul, Maikuben and Saryadyr. The analysis has been performed and the choice of the most convenient technology for boiler kindling and maintenance of steady burning of the torch has been made according to the proposed method, as well as the corresponding technological scheme has been developed. As a result of the experiment, it can be stated that from coal in the process of its heating (without access to oxygen), it is possible to obtain a sufficient amount of combustible volatile substances. The released gaseous fuel has the necessary parameters and is quite capable of replacing an expensive fuel oil. The resulting gaseous fuel is quite convenient to use and environmentally cleaner. The piloting scheme developed as a result of the experiment can be introduced in pulverized-coal thermal power plants, as a result of which they become single-fuel.

Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

DOEpatents

Detering, Brent A.; Kong, Peter C.

2001-01-01

Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

DOEpatents

Young, J.E.; Jalan, V.M.

1982-07-07

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Apparatus and method for removing particulate deposits from high temperature filters

DOEpatents

Nakaishi, Curtis V.; Holcombe, Norman T.; Micheli, Paul L.

1992-01-01

A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

Stability of gas atomized reactive powders through multiple step in-situ passivation

DOEpatents

Anderson, Iver E.; Steinmetz, Andrew D.; Byrd, David J.

2017-05-16

A method for gas atomization of oxygen-reactive reactive metals and alloys wherein the atomized particles are exposed as they solidify and cool in a very short time to multiple gaseous reactive agents for the in-situ formation of a protective reaction film on the atomized particles. The present invention is especially useful for making highly pyrophoric reactive metal or alloy atomized powders, such as atomized magnesium and magnesium alloy powders. The gaseous reactive species (agents) are introduced into the atomization spray chamber at locations downstream of a gas atomizing nozzle as determined by the desired powder or particle temperature for the reactions and the desired thickness of the reaction film.

An estimate of the outgassing of space payloads, their internal pressures, contaminations and gaseous influences on the environment

NASA Technical Reports Server (NTRS)

Scialdone, J. J.

1985-01-01

Experimentally measured outgassing as a function of time is presented for 14 space systems including several spacecraft instruments, spacecraft, the shuttle bay, and a spent solid fuel motor. The weights, volumes, and some of the scientific functions of the instruments involved are indicated. The methods used to obtain the data are briefly described. General indications on how to use the data to obtain the internal pressure versus time for a payload, its self-contamination, the gaseous flow in its vicinity, the column densities in its field of view, and other environmental parameters which are dependent on the outgassing of a payload are provided.

Information system of quality assessment for liquid and gaseous medium production

NASA Astrophysics Data System (ADS)

Bobrov, V. N.; Us, N. A.; Davidov, I. S.

2018-05-01

A method and a technical solution for controlling the quality of production of liquid and gaseous media is proposed. It is also proposed to monitor harmful factors in production while ensuring safe working conditions. Initially, using the mathematical model of an ideal atmosphere, the projection to the horizontal surface of the observation trajectory is calculated. At the second stage, the horizontal projection of the observation trajectory in real conditions is measured. The quality of the medium is judged by the difference between the projections of observation trajectories. The technical result is presented in the form of a device allowing obtaining information about the quality of the medium under investigation.

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates

DOEpatents

Elliott, Guy R. B.; Barraclough, Bruce L.; Vanderborgh, Nicholas E.

1984-01-01

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

DOEpatents

Young, J.E.; Jalan, V.M.

1984-06-19

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

DOEpatents

Young, John E.; Jalan, Vinod M.

1984-01-01

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Method for combined removal of mercury and nitrogen oxides from off-gas streams

DOEpatents

Mendelsohn, Marshall H [Downers Grove, IL; Livengood, C David [Lockport, IL

2006-10-10

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Microbial production of epoxides

DOEpatents

Clark, Thomas R.; Roberto, Francisco F.

2003-06-10

A method for microbial production of epoxides and other oxygenated products is disclosed. The method uses a biocatalyst of methanotrophic bacteria cultured in a biphasic medium containing a major amount of a non-aqueous polar solvent. Regeneration of reducing equivalents is carried out by using endogenous hydrogenase activity together with supplied hydrogen gas. This method is especially effective with gaseous substrates and cofactors that result in liquid products.

Method for enriching a middle isotope using vibration-vibration pumping

DOEpatents

Rich, Joseph W.; Homicz, Gregory F.; Bergman, Richard C.

1989-01-01

Method for producing isotopically enriched material by vibration-vibration excitation of gaseous molecules wherein a middle mass isotope of an isotopic mixture including lighter and heavier mass isotopes preferentially populates a higher vibrational mode and chemically reacts to provide a product in which it is enriched. The method can be used for vibration-vibration enrichment of .sup.17 O in a CO reactant mixture.

40 CFR 63.4965 - How do I determine the add-on control device emission destruction or removal efficiency?

Code of Federal Regulations, 2010 CFR

2010-07-01

... an alternative to Method 3B, the manual method for measuring the oxygen, carbon dioxide, and carbon..., Instruments and Apparatus]” (incorporated by reference, see § 63.14). (4) Use Method 4 of appendix A to 40 CFR... total gaseous organic mass emissions as carbon at the inlet and outlet of the add-on control device...

40 CFR 63.3545 - How do I determine the add-on control device emission destruction or removal efficiency?

Code of Federal Regulations, 2010 CFR

2010-07-01

... an alternative to Method 3B the manual method for measuring the oxygen, carbon dioxide, and carbon..., Instruments and Apparatus]” (incorporated by reference, see § 63.14). (4) Use Method 4 of appendix A to 40 CFR... total gaseous organic mass emissions as carbon at the inlet and outlet of the add-on control device...

Sulfur tolerant hydrophobic ionic liquid solvent

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luebke, David; Nulwala, Hunaid; Kail, Brian

Exemplary embodiments relate to methods for removal of CO.sub.2 and other acid gases from gaseous fuels prior to combustion. Exemplary methods may be used for CO.sub.2 capture, H.sub.2 purification and natural gas sweetening. Exemplary methods use at least one ionic liquid that has excellent CO.sub.2 solubility, selectivity over hydrogen, low viscosity, and resistance to H.sub.2S.

Evaluation of an offline method for the analysis of atmospheric reactive gaseous mercury and particulate mercury

USGS Publications Warehouse

Rutter, A.P.; Hanford, K.L.; Zwers, J.T.; Perillo-Nicholas, A. L.; Schauer, J.J.; Olson, M.L.

2008-01-01

Reactive gaseous mercury (RGM) and particulate mercury (PHg) were collected in Milwaukee, WI, between April 2004 and May 2005, and in Riverside, CA, between July 25 and August 7, 2005 using sorbent and filter substrates. The substrates were analyzed for mercury by thermal desorption analysis (TDA) using a purpose-built instrument. Results from this offline-TDA method were compared with measurements using a real-time atmospheric mercury analyzer. RGM measurements made with the offline-TDA agreed well with a commercial real-time method. However, the offline TDA reported PHg concentrations 2.7 times higher than the real-time method, indicating evaporative losses might be occurring from the real-time instrument during sample collection. TDA combined with reactive mercury collection on filter and absorbent substrates was cheap, relatively easy to use, did not introduce biases due to a semicontinuous sample collection strategy, and had a dynamic range appropriate for use in rural and urban locations. The results of this study demonstrate that offline-TDA is a feasible method for collecting reactive mercury concentrations in a large network of filter-based samplers. Copyright 2008 Air & Waste Management Association.

Photothermal laser deflection, an innovative technique to measure particles in exhausts

NASA Astrophysics Data System (ADS)

Hess, Cecil F.

1993-10-01

Photothermal Laser Deflection (PLD) is an analytical technique to measure in real-time the mass concentration of particles and gaseous exhaust pollutants in a variety of combustion devices (e.g., gas turbine engines and rockets). PLD uses a pump laser to locally heat the particle or gaseous species, thus changing the refractive index of the surrounding gas to form a thermal lens. A probe laser beam travelling through the thermal lens is temporarily deflected, and the amount of deflection is proportional to the species mass concentration. The experiments and analyses conducted during phase 1 demonstrated the feasibility of PLD in measuring the mass concentration of both soot particles and NO2 at a repetition rate of 25 HZ. PLD response was linear at soot concentrations from 0.3 to 10 mg/cubic meters at NO2 concentrations from approximately 6 to 208 ppm. Strategies to measure lower concentrations have been defined and include focusing the probe beam onto the face of the bi-cell detector. The large dynamic range, fast acquisition rate, and ability to measure particulate and gaseous pollutants makes PLD superior to other available methods.

Neutronic reactor thermal shield

DOEpatents

Wende, Charles W. J.

1976-06-15

1. The method of operating a water-cooled neutronic reactor having a graphite moderator which comprises flowing a gaseous mixture of carbon dioxide and helium, in which the helium comprises 40-60 volume percent of the mixture, in contact with the graphite moderator.

Processes for Removal and Immobilization of 14C, 129I, and 85Kr

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strachan, Denis M.; Bryan, Samuel A.; Henager, Charles H.

2009-10-05

This is a white paper covering the results of a literature search and preliminary experiments on materials and methods to remove and immobilize gaseous radionuclided that come from the reprocessing of spent nuclear fuel.

Analytical capabilities and services of Lawrence Livermore Laboratory's General Chemistry Division. [Methods available at Lawrence Livermore

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gutmacher, R.; Crawford, R.

This comprehensive guide to the analytical capabilities of Lawrence Livermore Laboratory's General Chemistry Division describes each analytical method in terms of its principle, field of application, and qualitative and quantitative uses. Also described are the state and quantity of sample required for analysis, processing time, available instrumentation, and responsible personnel.

75 FR 61148 - Food and Drug Administration Modernization Act of 1997: Modifications to the List of Recognized...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-04

... Evaluation and testing within a risk management process 2-100 ASTM E1372-95 (2003) Standard Test Method...) Standard Title, Type of Test Method for Agar Diffusion Cell standard , Relevant Culture Screening for... Biological evaluation of medical devices - Office(s) and Part 3: Tests for genotoxicity, Division(s...

Maskless laser writing of microscopic metallic interconnects

DOEpatents

Maya, L.

1995-10-17

A method of forming a metal pattern on a substrate is disclosed. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern. 4 figs.

Method and apparatus for jet-assisted drilling or cutting

DOEpatents

Summers, David Archibold; Woelk, Klaus Hubert; Oglesby, Kenneth Doyle; Galecki, Grzegorz

2012-09-04

An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.

Method and apparatus for jet-assisted drilling or cutting

DOEpatents

Summers, David Archibold; Woelk, Klaus Hubert; Oglesby, Kenneth Doyle; Galecki, Grzegorz

2013-07-02

An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.

IMPINGER SOLUTIONS FOR THE EFFICIENT CAPTURE OF GASEOUS MERCURY SPECIES USING DIRECT INJECTION NEBULIZATION INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY (DIN-ICP/MS) ANALYSIS

EPA Science Inventory

Currently there are no EPA reference sampling mehtods that have been promulgated for measuring Hg from coal combustion sources. EPA Method 29 is most commonly applied. The ASTM Ontario Hydro Draft Method for measuring oxidized, elemental, particulate-bound and total Hg is now und...

Quantitative Infrared Spectroscopy in Challenging Environments: Applications to Passive Remote Sensing and Process Monitoring

DTIC Science & Technology

2012-12-01

IR remote sensing o ers a measurement method to detect gaseous species in the outdoor environment. Two major obstacles limit the application of this... method in quantitative analysis : (1) the e ect of both temperature and concentration on the measured spectral intensities and (2) the di culty and...crucial. In this research, particle swarm optimization, a population- based optimization method was applied. Digital ltering and wavelet processing methods

An Analysis of the Cost Efficiency of the Math-Science Division Instructional Personnel at Gulf Coast Community College.

ERIC Educational Resources Information Center

Etheridge, Sandra Y.

Prepared to provide a comprehensible and useable statement of the productivity of the members of the Math-Science Division at Gulf Coast Community College (GCCC), this report presents the methods and findings of a study of the income and expenditures related to each full- and part-time faculty member in the division. Following introductory…

Performance Evaluation of "Low-cost" Sensors for Measuring Gaseous and Particle Air Pollutants: Results from Two Years of Field and Laboratory Testing

NASA Astrophysics Data System (ADS)

Feenstra, B. J.; Polidori, A.; Tisopulos, L.; Papapostolou, V.; Zhang, H.; Pathmanabhan, J.

2016-12-01

In recent years great progress has been made in development of low-cost miniature air quality sensing technologies. Such low-cost sensors offer a prospect of providing a real-time spatially dense information on pollutants, however, the quality of the data produced by these sensors is so far untested. In an effort to inform the general public about the actual performance of commercially available low-cost air quality sensors, in June 2014 the South Coast Air Quality Management District (SCAQMD) has established the Air Quality Sensor Performance Evaluation Center (AQ-SPEC). This program performs a thorough characterization of low-cost sensors under ambient (in the field) and controlled (in the laboratory) conditions. During the field testing, air quality sensors are operated side-by-side with Federal Reference Methods and Federal Equivalent Methods (FRM and FEM, respectively), which are routinely used to measure the ambient concentration of gaseous or particle pollutants for regulatory purposes. Field testing is conducted at two of SCAQMD's existing air monitoring stations, one in Rubidoux and one near the I-710 freeway. Sensors that demonstrate an acceptable performance in the field are brought back to the lab where a "characterization chamber" is used to challenge these devices with known concentrations of different particle and gaseous pollutants under different temperature and relative humidity levels. Testing results for each sensor are then summarized in a technical report and, along with other relevant information, posted online on a dedicated website (www.aqmd.gov/aq-spec) to educate the public about the capabilities of commercially available sensors and their potential applications. During this presentation, the results from two years of field and laboratory testing will be presented. The major strengths and weaknesses of some of the most commonly available particle and gaseous sensors will be discussed.

TC-99 Decontaminant from heat treated gaseous diffusion membrane -Phase I, Part B

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oji, L.; Restivo, M.; Duignan, M.

2017-11-01

Uranium gaseous diffusion cascades represent a significant environmental challenge to dismantle, containerize and dispose as low-level radioactive waste. Baseline technologies rely on manual manipulations involving direct access to technetium-contaminated piping and materials. There is a potential to utilize novel decontamination technologies to remove the technetium and allow for on-site disposal of the very large uranium converters. Technetium entered these gaseous diffusion cascades as a hexafluoride complex in the same fashion as uranium. Technetium, as the isotope Tc-99, is an impurity that follows uranium in the first cycle of the Plutonium and Uranium Extraction (PUREX) process. The technetium speciation or exactmore » form in the gaseous diffusion cascades is not well defined. Several forms of Tc-99 compounds, mostly the fluorinated technetium compounds with varying degrees of volatility have been speculated by the scientific community to be present in these cascades. Therefore, there may be a possibility of using thermal or leaching desorption, which is independent of the technetium oxidation states, to perform an insitu removal of the technetium as a volatile species and trap the radionuclide on sorbent traps which could be disposed as low-level waste. Based on the positive results of the first part of this work1 the use of steam as a thermal decontamination agent was further explored with a second piece of used barrier material from a different location. This new series of tests included exposing more of the material surface to the flow of high temperature steam through the change in the reactor design, subjecting it to alternating periods of stream and vacuum, as well as determining if a lower temperature steam, i.e., 121°C (250°F) would be effective, too. Along with these methods, one other simpler method involving the leaching of the Tc-99 contaminated barrier material with a 1.0 M aqueous solution of ammonium carbonate, with and without sonication, was evaluated.« less

Reforming of fuel inside fuel cell generator

DOEpatents

Grimble, Ralph E.

1988-01-01

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Reforming of fuel inside fuel cell generator

DOEpatents

Grimble, R.E.

1988-03-08

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

Experimental Evaluation of a Subscale Gaseous Hydrogen/gaseous Oxygen Coaxial Rocket Injector

NASA Technical Reports Server (NTRS)

Smith, Timothy D.; Klem, Mark D.; Breisacher, Kevin J.; Farhangi, Shahram; Sutton, Robert

2002-01-01

The next generation reusable launch vehicle may utilize a Full-Flow Stage Combustion (FFSC) rocket engine cycle. One of the key technologies required is the development of an injector that uses gaseous oxygen and gaseous hydrogen as propellants. Gas-gas propellant injection provides an engine with increased stability margin over a range of throttle set points. This paper summarizes an injector design and testing effort that evaluated a coaxial rocket injector for use with gaseous oxygen and gaseous hydrogen propellants. A total of 19 hot-fire tests were conducted up to a chamber pressure of 1030 psia, over a range of 3.3 to 6.7 for injector element mixture ratio. Post-test condition of the hardware was also used to assess injector face cooling. Results show that high combustion performance levels could be achieved with gas-gas propellants and there were no problems with excessive face heating for the conditions tested.

Hydrogen, lithium, and lithium hydride production

DOEpatents

Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

2014-03-25

A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

Cryopumping of hydrogen in vacuum chambers is aided by catalytic oxidation of hydrogen

NASA Technical Reports Server (NTRS)

Childs, J. H.; Grobman, J.; Rayle, W.

1964-01-01

Vacuum test facilities are required for high speed cryopumping of gaseous hydrogen at low pressures. One method involves the catalytic oxidation of hydrogen and condensation of the resulting water on a liquid nitrogen-cooled surface.

Analysis of Whiskey by Dispersive Liquid-Liquid Microextraction Coupled with Gas Chromatography/Mass Spectrometry: An Upper Division Analytical Chemistry Experiment Guided by Green Chemistry

ERIC Educational Resources Information Center

Owens, Janel E.; Zimmerman, Laura B.; Gardner, Michael A.; Lowe, Luis E.

2016-01-01

Analysis of whiskey samples prepared by a green microextraction technique, dispersive liquid-liquid microextraction (DLLME), before analysis by a qualitative gas chromatography-mass spectrometry (GC/MS) method, is described as a laboratory experiment for an upper division instrumental methods of analysis laboratory course. Here, aroma compounds in…

Method of making a ceramic with preferential oxygen reactive layer

NASA Technical Reports Server (NTRS)

Wang, Hongyu (Inventor); Luthra, Krishan Lal (Inventor)

2003-01-01

A method of forming an article. The method comprises forming a silicon-based substrate that is oxidizable by reaction with an oxidant to form at least one gaseous product and applying an intermediate layer/coating onto the substrate, wherein the intermediate layer/coating is oxidizable to a nongaseous product by reaction with the oxidant in preference to reaction of the silicon-containing substrate with the oxidant.

Plating methods, a survey

NASA Technical Reports Server (NTRS)

Berkowitz, J. B.; Emerson, N. H.

1972-01-01

Results are presented of a comprehensive search of the literature available, much of which has been generated by the research centers of NASA and its contractors, on plating and coating methods and techniques. Methods covered included: (1) electroplating from aqueous solutions; (2) electroplating from nonaqueous solutions; (3) electroplating from fused-salt baths; (4) electroforming; (5) electroless plating, immersion plating, and mirroring; (6) electroplating from gaseous plasmas; and (7) anodized films and conversion coatings.

Gaseous iodine monitoring in Europe after the Fukushima accident

NASA Astrophysics Data System (ADS)

Masson, Olivier; de Vismes-Ott, Anne; Manificat, Guillaume; Gurriaran, Rodolfo; Debayle, Christophe

2014-05-01

After the Fukushima accident and following the worldwide dispersion of contaminated air masses, many monitoring networks have reported airborne levels of emitted radionuclides, namely and mainly cesium isotopes and iodine 131. Most of the values focused on the particulate fraction (i.e. radionuclide-labeled aerosols) and were dedicated to cesium 137, cesium 134 and iodine 131. Iodine-131 was also found under gaseous form that accounted for most part of the total (gaseous + particulate)I-131 throughout the world. This gaseous predominance was also noticed after the Chernobyl accident despite differences in the type of accident. This predominance is due to the high iodine volatility and also by a rather low transfer from the gaseous form to the particulate one by adsorption on ambient airborne particles. Paradoxically, the number of gaseous determinations was rather low compared to the magnitude of data related to the particulate form (around 10 percent). Routine monitoring of airborne radionuclides species have been extensively based on aerosol sampling for decades as this allows the long term characterization of trace levels of remnant anthropogenic radionuclides. Moreover the capability of gaseous sampler equipped with activated charcoal to allow the quantification of 131I gaseous at trace level is limited by the contact time required for the sorption of iodine on the sorbent and thus by the low acceptable flow rate (usually between 3 and 5 m3/h, exceptionally 12 m3/h). In this context and despite the fact that airborne level outside Japan were of no concern for public health, this contribute to the lack of information on the actual levels of gaseous iodine. Other incidents involving iodine determination in the air have been reported in Europe in 2011 and 2012 without any relation with the Fukushima accident. For the same reason as previously mentioned, mainly, if not only, the particulate form was reported whereas it can be supposed that the predominant form was gaseous. In order to cope with these limitations, some improvements can be done 1) to increase the number of iodine samplers, as engaged by IRSN, 2) to have a number of gaseous surveillance station operating on a routine basis, 3) to diminish the detection limit of the gaseous iodine.

Review of microfluidic cell culture devices for the control of gaseous microenvironments in vitro

NASA Astrophysics Data System (ADS)

Wu, H.-M.; Lee, T.-A.; Ko, P.-L.; Chiang, H.-J.; Peng, C.-C.; Tung, Y.-C.

2018-04-01

Gaseous microenvironments play important roles in various biological activities in vivo. However, it is challenging to precisely control gaseous microenvironments in vitro for cell culture due to the high diffusivity nature of gases. In recent years, microfluidics has paved the way for the development of new types of cell culture devices capable of manipulating cellular microenvironments, and provides a powerful tool for in vitro cell studies. This paper reviews recent developments of microfluidic cell culture devices for the control of gaseous microenvironments, and discusses the advantages and limitations of current devices. We conclude with suggestions for the future development of microfluidic cell culture devices for the control of gaseous microenvironments.

Hydrogen and Gaseous Fuel Safety and Toxicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee C. Cadwallader; J. Sephen Herring

2007-06-01

Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

Photoresist removal using gaseous sulfur trioxide cleaning technology

NASA Astrophysics Data System (ADS)

Del Puppo, Helene; Bocian, Paul B.; Waleh, Ahmad

1999-06-01

A novel cleaning method for removing photoresists and organic polymers from semiconductor wafers is described. This non-plasma method uses anhydrous sulfur trioxide gas in a two-step process, during which, the substrate is first exposed to SO3 vapor at relatively low temperatures and then is rinsed with de-ionized water. The process is radically different from conventional plasma-ashing methods in that the photoresist is not etched or removed during the exposure to SO3. Rather, the removal of the modified photoresist takes place during the subsequent DI-water rinse step. The SO3 process completely removes photoresist and polymer residues in many post-etch applications. Additional advantages of the process are absence of halogen gases and elimination of the need for other solvents and wet chemicals. The process also enjoys a very low cost of ownership and has minimal environmental impact. The SEM and SIMS surface analysis results are presented to show the effectiveness of gaseous SO3 process after polysilicon, metal an oxide etch applications. The effects of both chlorine- and fluorine-based plasma chemistries on resist removal are described.

Cytoplasmic removal, enucleation, and cell fusion of mouse oocytes.

PubMed

Kyogoku, Hirohisa; Yoshida, Shuhei; Kitajima, Tomoya S

2018-01-01

Meiotic divisions in females occur in fully grown oocytes that have a large cytoplasmic volume. The intracellular processes that are needed to accomplish meiotic divisions, such as spindle formation, chromosome segregation, and polar body extrusion, are controlled by the concerted actions of nuclear and cytoplasmic factors, which exhibit dynamic quantitative and spatiotemporal changes during meiotic maturation. Thus, distinguishing between meiotic controls that are mediated by cytoplasmic factors and those mediated by nuclear factors helps in the understanding of the mechanisms underlying meiotic divisions. Here, we describe a method to artificially modify the number of nuclei and the volume of the cytoplasm of mouse oocytes through cytoplasmic removal, enucleation, and cell fusion. The oocytes generated by this method are viable and undergo reproducible meiotic divisions exhibiting the effects of altered amounts of cytoplasmic and nuclear factors, which can be analyzed by various assays, such as live imaging microscopy. © 2018 Elsevier Inc. All rights reserved.

Sterilization of microorganisms by the supercritical carbon dioxide micro-bubble method.

PubMed

Ishikawa, H; Shimoda, M; Shiratsuchi, H; Osajima, Y

1995-10-01

Lactobacillus brevis and Saccharomyces cerevisiae were completely sterilized by the supercritical (SC) CO2 micro-bubble method. Gaseous (G) and liquid (LQ) CO2 were used in a similar manner to compare the sterilizing effect. Among the three treatments, the microorganisms were only effectively sterilized by the SC CO2 treatment at 25 MPa and 35 degrees C.

Method of preparing silicon from sodium fluosilicate

DOEpatents

Schmidt, Frederick A.; Rehbein, David; Chiotti, Premo

1984-01-01

A process for preparing high purity silicon metal from Na.sub.2 SiF.sub.6 (sodium fluosilicate). The sodium fluosilicate is heated to decomposition temperature to form NaF, which retains most of the impurities, and gaseous SiF.sub.4. The SiF.sub.4 is then reduced by the bomb reduction method using a reductant having a low packing density.

Chemical of the Month: Nitric Acid.

ERIC Educational Resources Information Center

Pannu, Sardul S.

1984-01-01

Presents background information on nitric acid including old names, history, occurrence, methods of preparation, uses, production, and price. Includes such chemical properties as decomposition; acidity, oxidation of metals and nonmetals; reactions with organic and inorganic compounds; gaseous fluorine; and nitrating properties. Also discusses bond…

Liquid and gaseous oxygen safety review

NASA Technical Reports Server (NTRS)

Lapin, A.

1973-01-01

Materials used in oxygen systems and allowable oxygen environments are specified for each material. Design criteria, cleaning procedures and quality control methods are covered. Guidelines for protection against hazards involved with production, transportation, storage and use of oxygen are presented. Study also lists extensive references.

Assessment of a new method for the analysis of decomposition gases of polymers by a combining thermogravimetric solid-phase extraction and thermal desorption gas chromatography mass spectrometry.

PubMed

Duemichen, E; Braun, U; Senz, R; Fabian, G; Sturm, H

2014-08-08

For analysis of the gaseous thermal decomposition products of polymers, the common techniques are thermogravimetry, combined with Fourier transformed infrared spectroscopy (TGA-FTIR) and mass spectrometry (TGA-MS). These methods offer a simple approach to the decomposition mechanism, especially for small decomposition molecules. Complex spectra of gaseous mixtures are very often hard to identify because of overlapping signals. In this paper a new method is described to adsorb the decomposition products during controlled conditions in TGA on solid-phase extraction (SPE) material: twisters. Subsequently the twisters were analysed with thermal desorption gas chromatography mass spectrometry (TDS-GC-MS), which allows the decomposition products to be separated and identified using an MS library. The thermoplastics polyamide 66 (PA 66) and polybutylene terephthalate (PBT) were used as example polymers. The influence of the sample mass and of the purge gas flow during the decomposition process was investigated in TGA. The advantages and limitations of the method were presented in comparison to the common analysis techniques, TGA-FTIR and TGA-MS. Copyright © 2014 Elsevier B.V. All rights reserved.

Nitrification inhibitors mitigated reactive gaseous nitrogen intensity in intensive vegetable soils from China.

PubMed

Fan, Changhua; Li, Bo; Xiong, Zhengqin

2018-01-15

Nitrification inhibitors, a promising tool for reducing nitrous oxide (N 2 O) losses and promoting nitrogen use efficiency by slowing nitrification, have gained extensive attention worldwide. However, there have been few attempts to explore the broad responses of multiple reactive gaseous nitrogen emissions of N 2 O, nitric oxide (NO) and ammonia (NH 3 ) and vegetable yield to nitrification inhibitor applications across intensive vegetable soils in China. A greenhouse pot experiment with five consecutive vegetable crops was performed to assess the efficacies of two nitrification inhibitors, namely, nitrapyrin and dicyandiamide on reactive gaseous nitrogen emissions, vegetable yield and reactive gaseous nitrogen intensity in four typical vegetable soils representing the intensive vegetable cropping systems across mainland China: an Acrisol from Hunan Province, an Anthrosol from Shanxi Province, a Cambisol from Shandong Province and a Phaeozem from Heilongjiang Province. The results showed soil type had significant influences on reactive gaseous nitrogen intensity, with reactive gaseous nitrogen emissions and yield mainly driven by soil factors: pH, nitrate, C:N ratio, cation exchange capacity and microbial biomass carbon. The highest reactive gaseous nitrogen emissions and reactive gaseous nitrogen intensity were in Acrisol while the highest vegetable yield occurred in Phaeozem. Nitrification inhibitor applications decreased N 2 O and NO emissions by 1.8-61.0% and 0.8-79.5%, respectively, but promoted NH 3 volatilization by 3.2-44.6% across all soils. Furthermore, significant positive correlations were observed between inhibited N 2 O+NO and stimulated NH 3 emissions with nitrification inhibitor additions across all soils, indicating that reduced nitrification posed the threat of NH 3 losses. Additionally, reactive gaseous nitrogen intensity was significantly reduced in the Anthrosol and Cambisol due to the reduced reactive gaseous nitrogen emissions and increased yield, respectively. Our findings highlight the benefits of nitrification inhibitors for integrating environment and agronomy in intensive vegetable ecosystems in China. Copyright © 2017. Published by Elsevier B.V.

The mechanisms of labor division from the perspective of individual optimization

NASA Astrophysics Data System (ADS)

Zhu, Lirong; Chen, Jiawei; Di, Zengru; Chen, Liujun; Liu, Yan; Stanley, H. Eugene

2017-12-01

Although the tools of complexity research have been applied to the phenomenon of labor division, its underlying mechanisms are still unclear. Researchers have used evolutionary models to study labor division in terms of global optimization, but focusing on individual optimization is a more realistic, real-world approach. We do this by first developing a multi-agent model that takes into account information-sharing and learning-by-doing and by using simulations to demonstrate the emergence of labor division. We then use a master equation method and find that the computational results are consistent with the results of the simulation. Finally we find that the core underlying mechanisms that cause labor division are learning-by-doing, information cost, and random fluctuation.

A mass spectrometric study of gaseous H4PO+3 and H2PO-3 ions

NASA Astrophysics Data System (ADS)

de Petris, Giulia; Occhiucci, Giorgio; Pepi, Federico

1994-09-01

H4PO+3 ions have been generated in a mass spectrometer by proton-transfer to H3PO3 from different Brønsted acids. The proton affinity of H3PO3 has been estimated by bracketing and kinetic methods to be 198.6 ± 2 kcal mol-1. Gaseous H4PO+3 ions have been structurally assessed by metastable ion kinetic energy (MIKE) and collisionally induced dissociation (CID) mass spectrometry leading to the detection of a single isomeric species. The chemistry of H2PO-3 is characterized by facile addition-elimination reactions leading to formation of polyanions. Species containing up to six P atoms have been detected.

LOW TEMPERATURE PROCESS FOR THE REMOVAL AND RECOVERY OF CHLORIDES AND NITRATES FROM AQUEOUS NITRATE SOLUTIONS

DOEpatents

Savolainen, J.E.

1963-01-29

A method is described for reducing the chloride content of a solution derived from the dissolution of a stainless steel clad nuclear fuel element with an aqua regia dissolution medium. The solutlon is adjusted to a nitric acid concentration in the range 5 to 10 M and is countercurrently contacted at room temperature with a gaseous oxide of nitrogen selected from NO, NO/sub 2/, N/sub 2/ O/sub 3/, and N/sub 2/O/sub 4/. Chlo ride is recovered from the contacted solution as nitrosyl chloride. After reduction of the chloride content, the solution is then contacted with gaseous NO to reduce the nitric acid molarity to a desired level. (AEC)

Preparation of ZnS@In2S3 Core@shell Composite for Enhanced Photocatalytic Degradation of Gaseous o-Dichlorobenzene under Visible Light.

PubMed

Liu, Baojun; Hu, Xia; Li, Xinyong; Li, Ying; Chen, Chang; Lam, Kwok-Ho

2017-11-27

In this study, novel ZnS@In 2 S 3 core@shell hollow nanospheres were fabricated by a facile refluxing method for the first time, and the formation mechanism of hollow structure with interior architecture was discussed based on ion-exchange Ostwald ripening. As the photocatalytic material for degradation of gaseous o-Dichlorobenzene (o-DCB), the as-synthesized core@shell hollow nanospheres were found to show significantly enhanced catalytic performance for effective separation of photo-generated charges. Moreover, the mechanisms of enhanced activity were elucidated by band alignment and unique configuration. Such photocatalyst would meet the demands for the control of persistent organic pollutant (POPs) in the atmospheric environment.

Monitoring Gaseous CO2 and Ethanol above Champagne Glasses: Flute versus Coupe, and the Role of Temperature

PubMed Central

Liger-Belair, Gérard; Bourget, Marielle; Pron, Hervé; Polidori, Guillaume; Cilindre, Clara

2012-01-01

In champagne tasting, gaseous CO2 and volatile organic compounds progressively invade the headspace above glasses, thus progressively modifying the chemical space perceived by the consumer. Simultaneous quantification of gaseous CO2 and ethanol was monitored through micro-gas chromatography (μGC), all along the first 15 minutes following pouring, depending on whether a volume of 100 mL of champagne was served into a flute or into a coupe. The concentration of gaseous CO2 was found to be significantly higher above the flute than above the coupe. Moreover, a recently developed gaseous CO2 visualization technique based on infrared imaging was performed, thus confirming this tendency. The influence of champagne temperature was also tested. As could have been expected, lowering the temperature of champagne was found to decrease ethanol vapor concentrations in the headspace of a glass. Nevertheless, and quite surprisingly, this temperature decrease had no impact on the level of gaseous CO2 found above the glass. Those results were discussed on the basis of a multiparameter model which describes fluxes of gaseous CO2 escaping the liquid phase into the form of bubbles. PMID:22347390

Monitoring gaseous CO2 and ethanol above champagne glasses: flute versus coupe, and the role of temperature.

PubMed

Liger-Belair, Gérard; Bourget, Marielle; Pron, Hervé; Polidori, Guillaume; Cilindre, Clara

2012-01-01

In champagne tasting, gaseous CO(2) and volatile organic compounds progressively invade the headspace above glasses, thus progressively modifying the chemical space perceived by the consumer. Simultaneous quantification of gaseous CO(2) and ethanol was monitored through micro-gas chromatography (μGC), all along the first 15 minutes following pouring, depending on whether a volume of 100 mL of champagne was served into a flute or into a coupe. The concentration of gaseous CO(2) was found to be significantly higher above the flute than above the coupe. Moreover, a recently developed gaseous CO(2) visualization technique based on infrared imaging was performed, thus confirming this tendency. The influence of champagne temperature was also tested. As could have been expected, lowering the temperature of champagne was found to decrease ethanol vapor concentrations in the headspace of a glass. Nevertheless, and quite surprisingly, this temperature decrease had no impact on the level of gaseous CO(2) found above the glass. Those results were discussed on the basis of a multiparameter model which describes fluxes of gaseous CO(2) escaping the liquid phase into the form of bubbles.

10 CFR 76.21 - Certificate required.

Code of Federal Regulations, 2014 CFR

2014-01-01

... REGULATORY COMMISSION (CONTINUED) CERTIFICATION OF GASEOUS DIFFUSION PLANTS General Provisions § 76.21 Certificate required. (a) The Corporation or its contractors may not operate the gaseous diffusion plants at..., use, or transfer radioactive material at the gaseous diffusion plants at Piketon, Ohio, and Paducah...

10 CFR 76.21 - Certificate required.

Code of Federal Regulations, 2010 CFR

2010-01-01

... REGULATORY COMMISSION (CONTINUED) CERTIFICATION OF GASEOUS DIFFUSION PLANTS General Provisions § 76.21 Certificate required. (a) The Corporation or its contractors may not operate the gaseous diffusion plants at..., use, or transfer radioactive material at the gaseous diffusion plants at Piketon, Ohio, and Paducah...

10 CFR 76.21 - Certificate required.

Code of Federal Regulations, 2013 CFR

2013-01-01

... REGULATORY COMMISSION (CONTINUED) CERTIFICATION OF GASEOUS DIFFUSION PLANTS General Provisions § 76.21 Certificate required. (a) The Corporation or its contractors may not operate the gaseous diffusion plants at..., use, or transfer radioactive material at the gaseous diffusion plants at Piketon, Ohio, and Paducah...

10 CFR 76.21 - Certificate required.

Code of Federal Regulations, 2012 CFR

2012-01-01

... REGULATORY COMMISSION (CONTINUED) CERTIFICATION OF GASEOUS DIFFUSION PLANTS General Provisions § 76.21 Certificate required. (a) The Corporation or its contractors may not operate the gaseous diffusion plants at..., use, or transfer radioactive material at the gaseous diffusion plants at Piketon, Ohio, and Paducah...

10 CFR 76.21 - Certificate required.

Code of Federal Regulations, 2011 CFR

2011-01-01

... REGULATORY COMMISSION (CONTINUED) CERTIFICATION OF GASEOUS DIFFUSION PLANTS General Provisions § 76.21 Certificate required. (a) The Corporation or its contractors may not operate the gaseous diffusion plants at..., use, or transfer radioactive material at the gaseous diffusion plants at Piketon, Ohio, and Paducah...

Removing gaseous NH3 using biochar as an adsorbent

USDA-ARS?s Scientific Manuscript database

Ammonia is a major fugitive gas emitted from livestock operations and fertilization production. This study tested the potential of various biochars in removing gaseous ammonia via adsorption processes. Gaseous ammonia adsorption capacities of various biochars made from two different feedstocks (wood...

Apparatus for removal of particulate matter from gas streams

DOEpatents

Smith, Peyton L.; Morse, John C.

2000-01-01

An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

Proceedings of the Annual Meeting of the Association for Education in Journalism and Mass Communication (83rd, Phoenix, Arizona, August 9-12, 2000). Communication Theory and Method Division.

ERIC Educational Resources Information Center

Association for Education in Journalism and Mass Communication.

The Communication Theory and Method Division section of the proceedings contains the following 16 papers: "Profiling TV Ratings Users: Content-Based Advisories and Their Adoption" (Robert Abelman and David Atkin); "It's All About the Information: Salience Effects on the Perceptions of News Exemplification" (Francesca R. Dillman…

The Mass and Absorption Columns of Galactic Gaseous Halos

NASA Astrophysics Data System (ADS)

Qu, Zhijie; Bregman, Joel N.

2018-03-01

The galactic gaseous halo is a gas reservoir for the interstellar medium in the galaxy disk, supplying materials for star formation. We developed a gaseous halo model connecting the galaxy disk and the gaseous halo by assuming that the star formation rate on the disk is balanced by the radiative cooling rate of the gaseous halo, including stellar feedback. In addition to a single-temperature gaseous halo in collisional ionization equilibrium, we also consider the photoionization effect and a steady-state cooling model. Photoionization is important for modifying the ion distribution in low-mass galaxies and in the outskirts of massive galaxies due to the low densities. The multiphase cooling model dominates the region within the cooling radius, where t cooling = t Hubble. Our model reproduces most of the observed high ionization state ions for a wide range of galaxy masses (i.e., O VI, O VII, Ne VIII, Mg X, and O VIII). We find that the O VI column density has a narrow range around ≈1014 cm‑2 for halo masses from M ⋆ ≈ 3 × 1010 M ⊙ to 6 × 1012 M ⊙, which is consistent with some but not all observational studies. For galaxies with halo masses ≲3 × 1011 M ⊙, photoionization produces most of the O VI, while for more massive galaxies, the O VI is from the medium that is cooling from higher temperatures. Fitting the Galactic (Milky-Way) O VII and O VIII suggests a gaseous halo model where the metallicity is ≈0.55 Z ⊙ and the gaseous halo has a maximum temperature of ≈1.9 × 106 K. This gaseous halo model does not close the census of baryonic material within R 200.

Seasonal variation of organochlorine pesticides in the gaseous phase and aerosols over the East China Sea

NASA Astrophysics Data System (ADS)

Ji, Tianyi; Lin, Tian; Wang, Fengwen; Li, Yuanyuan; Guo, Zhigang

2015-05-01

Eighty paired gaseous phase and PM2.5 (particulate matter < 2.5 μm in diameter) samples, covering four seasons from October 2011 to August 2012 were collected simultaneously from a remote island in the East China Sea (ECS). The samples were analyzed for organochlorine pesticides (OCPs) to determine their seasonal variation and potential sources over the coastal marine environment. The concentrations of individual OCPs in the PM2.5 samples were higher in winter and lower in summer, and the reverse trend was observed for the measured OCP compounds (except hexachlorocyclohexanes, HCHs) in the gaseous phase. Principal component analysis revealed one trend that contributed 40% to PM2.5-bound OCPs characterized by β-HCH, α-HCH, p,p‧-dichlorodiphenyldichloroethane (p,p‧-DDD), p,p‧-dichlorodiphenyldichloroethylene (p,p‧-DDE), and chlordanes; whereas two seasonal trends, represented by dichlorodiphenyltrichloroethanes (DDTs) or chlordanes and HCHs, were responsible for 38% and 23% of the gaseous OCPs, respectively. Continental outflow driven by the East Asian monsoon brought large quantities of particulate OCPs to the ECS, especially in winter. Possible fresh sources or net volatilization from the Yangtze River induced by both higher ambient temperature and higher discharge rates caused the higher gaseous DDT and chlordane levels observed in summer. However, the lower concentrations of gaseous HCHs observed in summer suggested that net volatilization had a relatively limited impact on gaseous HCHs due to the long-term prohibition of their use and their low residual levels in the catchment, whereas the elevated concentrations of gaseous HCHs in winter controlled by gas-particle partitioning, resulted from increased particulate HCHs producing a partial shift to gaseous HCHs over ECS.

A Method to Constrain the Size of the Protosolar Nebula

NASA Astrophysics Data System (ADS)

Kretke, K. A.; Levison, H. F.; Buie, M. W.; Morbidelli, A.

2012-04-01

Observations indicate that the gaseous circumstellar disks around young stars vary significantly in size, ranging from tens to thousands of AU. Models of planet formation depend critically upon the properties of these primordial disks, yet in general it is impossible to connect an existing planetary system with an observed disk. We present a method by which we can constrain the size of our own protosolar nebula using the properties of the small body reservoirs in the solar system. In standard planet formation theory, after Jupiter and Saturn formed they scattered a significant number of remnant planetesimals into highly eccentric orbits. In this paper, we show that if there had been a massive, extended protoplanetary disk at that time, then the disk would have excited Kozai oscillations in some of the scattered objects, driving them into high-inclination (i >~ 50°), low-eccentricity orbits (q >~ 30 AU). The dissipation of the gaseous disk would strand a subset of objects in these high-inclination orbits; orbits that are stable on Gyr timescales. To date, surveys have not detected any Kuiper-belt objects with orbits consistent with this dynamical mechanism. Using these non-detections by the Deep Ecliptic Survey and the Palomar Distant Solar System Survey we are able to rule out an extended gaseous protoplanetary disk (RD >~ 80 AU) in our solar system at the time of Jupiter's formation. Future deep all sky surveys such as the Large Synoptic Survey Telescope will allow us to further constrain the size of the protoplanetary disk.

Inhalation dose due to presence of 131I in air above septic tank system of an endocrinology hospital.

PubMed

Mietelski, J W; Grabowska, S; Nowak, T; Bogacz, J; Gaca, P; Bartyzel, M; Budzanowski, M

2005-01-01

We present here measurements of the 131I concentration for both: gaseous and aerosol fraction of 131I in the air above the septic tank containing wastes from medical application of this isotope. Aerosols were collected using air filters, whereas gaseous forms of iodine were trapped in KI impregnated charcoal double layer cartridge. Besides an active method (pumping of the air through system of filters) an attempt for using a passive method (charcoal traps) for monitoring of radio-iodine is described. For better characterisation of a site the external kerma was determined by means of G-M and TLD techniques as well as the activity kept in the septic tank was measured by gamma spectrometry. Results show that the activity of the aerosol fraction can be neglected compared to that of the gaseous fraction. He measured activity of air is low, on the level of 1 Bq m(-3), even during simulated failure of the ventilation system. Estimated inhalation dose for the serviceman of septic tanks is low ( approximately 10%) compared with external dose obtained by such person due to gamma radiation from the tank (on the level approximately 500 nSv h(-1)). Therefore, the concept of passive monitoring of the iodine in air was abandoned. Also estimated is the efficiency of 131I reduction by a charcoal filter of the ventilation system and 131I input to the environment by the ventilation chimney.

Radioisotopic Method for Measuring Cell Division Rates of Individual Species of Diatoms from Natural Populations †

PubMed Central

Rivkin, Richard B.

1986-01-01

Silicon is an essential element for diatom frustule synthesis and is usually taken up only by dividing cells. With 68Ge, a radioactive analog of Si, the cell cycle marker event of frustule formation was identified for individual species of diatom. The frequency of cells within a population undergoing this division event was estimated, and the cell division rate was calculated. In laboratory cultures, these rates of cell division and those calculated from changes in cell numbers were similar. By dual labeling with 68Ge(OH)4 and NaH14CO3, rates of cell division and photosynthesis were coincidently measured for diatoms both in laboratory cultures and when isolated from natural populations in estuarine, offshore, and polar environments. These techniques permit the coupling between photosynthesis and cell division to be examined in situ for individual species of diatom. PMID:16347039

40 CFR 92.123 - Test procedure; general requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... measurements of brake specific emissions and smoke opacity at each throttle position and of measurements of... at idle and dynamic brake, all measurements of gaseous, particulate and smoke emissions may be... is removed for gaseous and particulate sampling, measurements of gaseous, and particulate emissions...

Observation of increases in emission from modern vehicles over time in Hong Kong using remote sensing.

PubMed

Lau, Jason; Hung, W T; Cheung, C S

2012-04-01

In this study on-road gaseous emissions of vehicles are investigated using remote sensing measurements collected over three different periods. The results show that a high percentage of gaseous pollutants were emitted from a small percentage of vehicles. Liquified Petroleum Gas (LPG) vehicles generally have higher gaseous emissions compared to other vehicles, particularly among higher-emitting vehicles. Vehicles with high vehicle specific power (VSP) tend to have lower CO and HC emissions while petrol and LPG vehicles tend to have higher NO emissions when engine load is high. It can be observed that gaseous emission factors of petrol and LPG vehicles increase greatly within 2 years of being introduced to the vehicle fleet, suggesting that engine and catalyst performance deteriorate rapidly. It can be observed that LPG vehicles have higher levels of gaseous emissions than petrol vehicles, suggesting that proper maintenance of LPG vehicles is essential in reducing gaseous emissions from vehicles. Copyright © 2011 Elsevier Ltd. All rights reserved.

Procedures for making gaseous industrial waste safe

NASA Astrophysics Data System (ADS)

Matros, Yu Sh; Noskov, Aleksandr S.

1990-10-01

The application of various methods (adsorption, absorption, thermal afterburning, catalytic purification, and others) for the removal of sulphur and nitrogen oxides, toxic organic compounds, hydrogen sulphide, and carbon monoxide from industrial waste gases is described. Much attention is devoted to the catalytic procedure for making the gases safe using an energy collecting non-stationary method (reversible process). The advantages and limitations of various gas purification methods are considered. The bibliography includes 279 references.

40 CFR 63.703 - Standards.

Code of Federal Regulations, 2010 CFR

2010-07-01

... gaseous HAP emitted from each solvent storage tank, piece of mix preparation equipment, coating operation..., piece of mix preparation equipment, coating operation, waste handling device, and condenser vent in... of this method is sufficient to meet the requirements of paragraph (c)(1) or (2) of this section. (4...

Method and means for producing fluorocarbon finishes on fibrous structures

NASA Technical Reports Server (NTRS)

Toy, Madeline S. (Inventor); Stringham, Roger S. (Inventor); Fogg, Lawrence C. (Inventor)

1981-01-01

An improved process and apparatus is provided for imparting chemically bonded fluorocarbon finishes to textiles. In the process, the textiles are contacted with a gaseous mixture of fluoroolefins in an inert diluent gas in the presence of ultraviolet light under predetermined conditions.

Persufflation (or gaseous oxygen perfusion) as a method of organ preservation.

PubMed

Suszynski, Thomas M; Rizzari, Michael D; Scott, William E; Tempelman, Linda A; Taylor, Michael J; Papas, Klearchos K

2012-06-01

Improved preservation techniques have the potential to improve transplant outcomes by better maintaining donor organ quality and by making more organs available for allotransplantation. Persufflation, (PSF, gaseous oxygen perfusion) is potentially one such technique that has been studied for over a century in a variety of tissues, but has yet to gain wide acceptance for a number of reasons. A principal barrier is the perception that ex vivo PSF will cause in vivo embolization post-transplant. This review summarizes the extensive published work on heart, liver, kidney, small intestine and pancreas PSF, discusses the differences between anterograde and retrograde PSF, and between PSF and other conventional methods of organ preservation (static cold storage, hypothermic machine perfusion). Prospective implications of PSF within the broader field of organ transplantation, and in the specific application with pancreatic islet isolation and transplant are also discussed. Finally, key issues that need to be addressed before PSF becomes a more widely utilized preservation strategy are summarized and discussed. Copyright © 2012 Elsevier Inc. All rights reserved.

Persufflation (or Gaseous Oxygen Perfusion) as a Method of Organ Preservation

PubMed Central

Suszynski, Thomas M.; Rizzari, Michael D.; Scott, William E.; Tempelman, Linda A.; Taylor, Michael J.; Papas, Klearchos K.

2012-01-01

Improved preservation techniques have the potential to improve transplant outcomes by better maintaining donor organ quality and by making more organs available for allotransplantation. Persufflation, (PSF, gaseous oxygen perfusion) is potentially one such technique that has been studied for over a century in a variety of tissues, but has yet to gain wide acceptance for a number of reasons. A principal barrier is the perception that ex vivo PSF will cause in vivo embolization post-transplant. This review summarizes the extensive published work on heart, liver, kidney, small intestine and pancreas PSF, discusses the differences between anterograde and retrograde PSF and between PSF and other conventional methods of organ preservation (static cold storage, hypothermic machine perfusion). Prospective implications of PSF within the broader field of organ transplantation, and in the specific application with pancreatic islet isolation and transplant are also discussed. Finally, key issues that need to be addressed before PSF becomes a more widely utilized preservation strategy are summarized and discussed. PMID:22301419

Infrared imaging - A validation technique for computational fluid dynamics codes used in STOVL applications

NASA Technical Reports Server (NTRS)

Hardman, R. R.; Mahan, J. R.; Smith, M. H.; Gelhausen, P. A.; Van Dalsem, W. R.

1991-01-01

The need for a validation technique for computational fluid dynamics (CFD) codes in STOVL applications has led to research efforts to apply infrared thermal imaging techniques to visualize gaseous flow fields. Specifically, a heated, free-jet test facility was constructed. The gaseous flow field of the jet exhaust was characterized using an infrared imaging technique in the 2 to 5.6 micron wavelength band as well as conventional pitot tube and thermocouple methods. These infrared images are compared to computer-generated images using the equations of radiative exchange based on the temperature distribution in the jet exhaust measured with the thermocouple traverses. Temperature and velocity measurement techniques, infrared imaging, and the computer model of the infrared imaging technique are presented and discussed. From the study, it is concluded that infrared imaging techniques coupled with the radiative exchange equations applied to CFD models are a valid method to qualitatively verify CFD codes used in STOVL applications.

Detection, composition and treatment of volatile organic compounds from waste treatment plants.

PubMed

Font, Xavier; Artola, Adriana; Sánchez, Antoni

2011-01-01

Environmental policies at the European and global level support the diversion of wastes from landfills for their treatment in different facilities. Organic waste is mainly treated or valorized through composting, anaerobic digestion or a combination of both treatments. Thus, there are an increasing number of waste treatment plants using this type of biological treatment. During waste handling and biological decomposition steps a number of gaseous compounds are generated or removed from the organic matrix and emitted. Different families of Volatile Organic Compounds (VOC) can be found in these emissions. Many of these compounds are also sources of odor nuisance. In fact, odors are the main source of complaints and social impacts of any waste treatment plant. This work presents a summary of the main types of VOC emitted in organic waste treatment facilities and the methods used to detect and quantify these compounds, together with the treatment methods applied to gaseous emissions commonly used in composting and anaerobic digestion facilities.

Detection, Composition and Treatment of Volatile Organic Compounds from Waste Treatment Plants

PubMed Central

Font, Xavier; Artola, Adriana; Sánchez, Antoni

2011-01-01

Environmental policies at the European and global level support the diversion of wastes from landfills for their treatment in different facilities. Organic waste is mainly treated or valorized through composting, anaerobic digestion or a combination of both treatments. Thus, there are an increasing number of waste treatment plants using this type of biological treatment. During waste handling and biological decomposition steps a number of gaseous compounds are generated or removed from the organic matrix and emitted. Different families of Volatile Organic Compounds (VOC) can be found in these emissions. Many of these compounds are also sources of odor nuisance. In fact, odors are the main source of complaints and social impacts of any waste treatment plant. This work presents a summary of the main types of VOC emitted in organic waste treatment facilities and the methods used to detect and quantify these compounds, together with the treatment methods applied to gaseous emissions commonly used in composting and anaerobic digestion facilities. PMID:22163835

Single-crystalline nanogap electrodes: enhancing the nanowire-breakdown process with a gaseous environment.

PubMed

Suga, Hiroshi; Sumiya, Touru; Furuta, Shigeo; Ueki, Ryuichi; Miyazawa, Yosuke; Nishijima, Takuya; Fujita, Jun-ichi; Tsukagoshi, Kazuhito; Shimizu, Tetsuo; Naitoh, Yasuhisa

2012-10-24

A method for fabricating single-crystalline nanogaps on Si substrates was developed. Polycrystalline Pt nanowires on Si substrates were broken down by current flow under various gaseous environments. The crystal structure of the nanogap electrode was evaluated using scanning electron microscopy and transmission electron microscopy. Nanogap electrodes sandwiched between Pt-large-crystal-grains were obtained by the breakdown of the wire in an O(2) or H(2) atmosphere. These nanogap electrodes show intense spots in the electron diffraction pattern. The diffraction pattern corresponds to Pt (111), indicating that single-crystal grains are grown by the electrical wire breakdown process in an O(2) or H(2) atmosphere. The Pt wires that have (111)-texture and coherent boundaries can be considered ideal as interconnectors for single molecular electronics. The simple method for fabrication of a single-crystalline nanogap is one of the first steps toward standard nanogap electrodes for single molecular instruments and opens the door to future research on physical phenomena in nanospaces.

The effects of hydrogen proportion on the synthesis of carbon nanomaterials with gaseous detonation (deflagration) method

NASA Astrophysics Data System (ADS)

Zhao, Tiejun; Li, Xiaojie; Lee, John H. S.; Yan, Honghao

2018-02-01

Using ferrocene, H2 and O2, Carbon nanomaterials were prepared with gaseous detonation (deflagration) method. The effects of H2 on the phase and morphology of carbon nanomaterials were studied by various proportions of H2 in the reaction. The prepared samples were characterized by x-ray diffractometer, transmission electron microscope and Raman spectrometer. The results show that hydrogen proportion has a great influence on the phase and morphology of carbon nanomaterials. The high hydrogen proportion leads to much unreacted hydrogen, which could protect the iron atom from oxidation of carbon and dilute the reactants contributing to uniform particle size. In addition, the graphitization degree of multi-walled carbon nanotubes, observed in samples with high H2 proportion, is high enough to see the lattice fringes, but the degree of graphitization of whole sample is lower than which fabricated with low H2 proportion, and it may result from the low energy generation.

GREENHOUSE GASES (ATMOSPHERIC PROTECTION BRANCH, AIR POLLUTION PREVENTION AND CONTROL DIVISION, NRMRL)

EPA Science Inventory

Greenhouse gas (GHG) emissions are projected for various scenarios and the most appropriate approaches and technologies for mitigation are identified by NRMRL's Air Pollution Prevention and Control Division's Atmospheric Protection Branch (APB). These methods contribute to reduct...

40 CFR 91.415 - Raw gaseous sampling procedures.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous sampling procedures. 91.415 Section 91.415 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Raw gaseous sampling procedures. Fit all heated sampling lines with a heated filter to extract solid...

40 CFR 91.415 - Raw gaseous sampling procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous sampling procedures. 91.415 Section 91.415 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Raw gaseous sampling procedures. Fit all heated sampling lines with a heated filter to extract solid...

40 CFR 90.415 - Raw gaseous sampling procedures.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous sampling procedures. 90.415 Section 90.415 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Test Procedures § 90.415 Raw gaseous sampling procedures. Fit all heated sampling lines with a heated...

40 CFR 90.415 - Raw gaseous sampling procedures.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous sampling procedures. 90.415 Section 90.415 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Test Procedures § 90.415 Raw gaseous sampling procedures. Fit all heated sampling lines with a heated...

14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

Division by zero, pseudo-division by zero, Zhang dynamics method and Zhang-gradient method about control singularity conquering

NASA Astrophysics Data System (ADS)

Zhang, Yunong; Zhang, Yinyan; Chen, Dechao; Xiao, Zhengli; Yan, Xiaogang

2017-01-01

In this paper, the division-by-zero (DBO) problem in the field of nonlinear control, which is traditionally termed the control singularity problem (or specifically, controller singularity problem), is investigated by the Zhang dynamics (ZD) method and the Zhang-gradient (ZG) method. According to the impact of the DBO problem on the state variables of the controlled nonlinear system, the concepts of the pseudo-DBO problem and the true-DBO problem are proposed in this paper, which provide a new perspective for the researchers on the DBO problems as well as nonlinear control systems. Besides, the two classes of DBO problems are solved under the framework of the ZG method. Specific examples are shown and investigated in this paper to illustrate the two proposed concepts and the efficacy of the ZG method in conquering pseudo-DBO and true-DBO problems. The application of the ZG method to the tracking control of a two-wheeled mobile robot further substantiates the effectiveness of the ZG method. In addition, the ZG method is successfully applied to the tracking control of a pure-feedback nonlinear system.

Gas chromatography - Mass spectrometry analysis and antibacterial activity of Cinnamomum burmanii essential oil to Staphylococcus aureus and Escherichia coli by gaseous contact

NASA Astrophysics Data System (ADS)

Chairunnisa, Tamhid, Hady Anshory; Nugraha, Arde Toga

2017-03-01

Infectious diseases and antibiotic resistance becomes a problem that must be resolved. Plant based products are among the alternative agents examined in order to replace conventional antibiotics. Cinnamaldehyde is one of the compound in cinnamon oil that has antibacterial activity. But the other compounds in cinnamon oil has also the potential antibacterial activity. The purpose of this study to conduct GC-MS analysis of cinnamon oil and its antibacterial activity to Staphylococcus aureus and Escherichia coli by gaseous contact. Cinnamomum burmannii was distilled by water-steam distillation to obtain essential oil. Identification of compounds was analyzed by GC-MS. Antibacterial activity was observed by gaseous contact method in airtight boxes. The GC-MS analyzed showed that there are four major compounds of cinnamon oil, trans-cinnamaldehyde (56,10%), 1,8-cineole (16,53%), α-pinene (3,44%) and α -terpineol (3,05%). The Minimum Inhibitory Dose (MID) of cinnamon oil to E. coli and S. aureus was 12.5 µL/L and 6.26 µL/L respectively. Gas compounds of cinnamon oil has more effective to gram-positive bacteria than gram-negative bacteria.

Elemental mapping in a contemporary miniature by full-field X-ray fluorescence imaging with gaseous detector vs. scanning X-ray fluorescence imaging with polycapillary optics

NASA Astrophysics Data System (ADS)

Silva, A. L. M.; Cirino, S.; Carvalho, M. L.; Manso, M.; Pessanha, S.; Azevedo, C. D. R.; Carramate, L. F. N. D.; Santos, J. P.; Guerra, M.; Veloso, J. F. C. A.

2017-03-01

Energy dispersive X-ray imaging can be used in several research fields and industrial applications. Elemental mapping through energy dispersive X-ray imaging technique has become a promising method to obtain positional distribution of specific elements in a non-destructive way. To obtain the elemental distribution of a sample it is necessary to use instruments capable of providing a precise positioning together with a good energy resolution. Polycapillary beams together with silicon drift chamber detectors are used in several commercial systems and are considered state-of-the-art spectrometers, however they are usually very costly. A new concept of large energy dispersive X-ray imaging systems based on gaseous radiation detectors emerged in the last years enabling a promising 2D elemental detection at a very reduced price. The main goal of this work is to analyze a contemporary Indian miniature with both X-ray fluorescence imaging systems, the one based on a gaseous detector 2D-THCOBRA and the state-of-the-art spectrometer M4 Tornado, from Bruker. The performance of both systems is compared and evaluated in the context of the sample's analysis.

Apparatus and method for the acceleration of projectiles to hypervelocities

DOEpatents

Hertzberg, Abraham; Bruckner, Adam P.; Bogdanoff, David W.

1990-01-01

A projectile is initially accelerated to a supersonic velocity and then injected into a launch tube filled with a gaseous propellant. The projectile outer surface and launch tube inner surface form a ramjet having a diffuser, a combustion chamber and a nozzle. A catalytic coated flame holder projecting from the projectile ignites the gaseous propellant in the combustion chamber thereby accelerating the projectile in a subsonic combustion mode zone. The projectile then enters an overdriven detonation wave launch tube zone wherein further projectile acceleration is achieved by a formed, controlled overdriven detonation wave capable of igniting the gaseous propellant in the combustion chamber. Ultrahigh velocity projectile accelerations are achieved in a launch tube layered detonation zone having an inner sleeve filled with hydrogen gas. An explosive, which is disposed in the annular zone between the inner sleeve and the launch tube, explodes responsive to an impinging shock wave emanating from the diffuser of the accelerating projectile thereby forcing the inner sleeve inward and imparting an acceleration to the projectile. For applications wherein solid or liquid high explosives are employed, the explosion thereof forces the inner sleeve inward, forming a throat behind the projectile. This throat chokes flow behind, thereby imparting an acceleration to the projectile.

A method to generate the surface cell layer of the 3D virtual shoot apex from apical initials.

PubMed

Kucypera, Krzysztof; Lipowczan, Marcin; Piekarska-Stachowiak, Anna; Nakielski, Jerzy

2017-01-01

The development of cell pattern in the surface cell layer of the shoot apex can be investigated in vivo by use of a time-lapse confocal images, showing naked meristem in 3D in successive times. However, how this layer is originated from apical initials and develops as a result of growth and divisions of their descendants, remains unknown. This is an open area for computer modelling. A method to generate the surface cell layer is presented on the example of the 3D paraboloidal shoot apical dome. In the used model the layer originates from three apical initials that meet at the dome summit and develops through growth and cell divisions under the isotropic surface growth, defined by the growth tensor. The cells, which are described by polyhedrons, divide anticlinally with the smallest division plane that passes depending on the used mode through the cell center, or the point found randomly near this center. The formation of the surface cell pattern is described with the attention being paid to activity of the apical initials and fates of their descendants. The computer generated surface layer that included about 350 cells required about 1200 divisions of the apical initials and their derivatives. The derivatives were arranged into three more or less equal clonal sectors composed of cellular clones at different age. Each apical initial renewed itself 7-8 times to produce the sector. In the shape and location and the cellular clones the following divisions of the initial were manifested. The application of the random factor resulted in more realistic cell pattern in comparison to the pure mode. The cell divisions were analyzed statistically on the top view. When all of the division walls were considered, their angular distribution was uniform, whereas in the distribution that was limited to apical initials only, some preferences related to their arrangement at the dome summit were observed. The realistic surface cell pattern was obtained. The present method is a useful tool to generate surface cell layer, study activity of initial cells and their derivatives, and how cell expansion and division are coordinated during growth. We expect its further application to clarify the question of a number and permanence or impermanence of initial cells, and possible relationship between their shape and oriented divisions, both on the ground of the growth tensor approach.

Solar Metal Sulfate-Ammonia Based Thermochemical Water Splitting Cycle for Hydrogen Production

NASA Technical Reports Server (NTRS)

T-Raissi, Ali (Inventor); Muradov, Nazim (Inventor); Huang, Cunping (Inventor)

2014-01-01

Two classes of hybrid/thermochemical water splitting processes for the production of hydrogen and oxygen have been proposed based on (1) metal sulfate-ammonia cycles (2) metal pyrosulfate-ammonia cycles. Methods and systems for a metal sulfate MSO.sub.4--NH3 cycle for producing H2 and O2 from a closed system including feeding an aqueous (NH3)(4)SO3 solution into a photoctalytic reactor to oxidize the aqueous (NH3)(4)SO3 into aqueous (NH3)(2)SO4 and reduce water to hydrogen, mixing the resulting aqueous (NH3)(2)SO4 with metal oxide (e.g. ZnO) to form a slurry, heating the slurry of aqueous (NH4)(2)SO4 and ZnO(s) in the low temperature reactor to produce a gaseous mixture of NH3 and H2O and solid ZnSO4(s), heating solid ZnSO4 at a high temperature reactor to produce a gaseous mixture of SO2 and O2 and solid product ZnO, mixing the gaseous mixture of SO2 and O2 with an NH3 and H2O stream in an absorber to form aqueous (NH4)(2)SO3 solution and separate O2 for aqueous solution, recycling the resultant solution back to the photoreactor and sending ZnO to mix with aqueous (NH4)(2)SO4 solution to close the water splitting cycle wherein gaseous H2 and O2 are the only products output from the closed ZnSO4--NH3 cycle.

Gaseous Oxidized Mercury Flux from Substrates Associated with Industrial Scale Gold Mining in Nevada, USA

NASA Astrophysics Data System (ADS)

Miller, M. B.

2015-12-01

Gaseous elemental and oxidized mercury (Hg) fluxes were measured in a laboratory setting from substrate materials derived from industrial-scale open pit gold mining operations in Nevada, USA. Mercury is present in these substrates at a range of concentrations (10 - 40000 ng g-1), predominantly of local geogenic origin in association with the mineralized gold ores, but altered and redistributed to a varying degree by subsequent ore extraction and processing operations, including deposition of Hg recently emitted to the atmosphere from large point sources on the mines. Waste rock, heap leach, and tailings material usually comprise the most extensive and Hg emission relevant substrate surfaces. All three of these material types were collected from active Nevada mine sites in 2010 for previous research, and have since been stored undisturbed at the University of Nevada, Reno. Gaseous elemental Hg (GEM) flux was previously measured from these materials under a variety of conditions, and was re-measured in this study, using Teflon® flux chambers and Tekran® 2537A automated ambient air analyzers. GEM flux from dry undisturbed materials was comparable between the two measurement periods. Gaseous oxidized Hg (GOM) flux from these materials was quantified using an active filter sampling method that consisted of polysulfone cation-exchange membranes deployed in conjunction with the GEM flux apparatus. Initial measurements conducted within greenhouse laboratory space indicate that in dry conditions GOM is deposited to relatively low Hg cap and leach materials, but may be emitted from the much higher Hg concentration tailings material.

78 FR 30342 - United States Enrichment Corporation, Paducah Gaseous Diffusion Plant

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-22

... Corporation, Paducah Gaseous Diffusion Plant AGENCY: Nuclear Regulatory Commission. ACTION: Notice of... Compliance (CoC) for the Paducah Gaseous Diffusion Plant (PGDP). The existing CoC (No. GDP-1) authorizes... compliance for PGDP on November 26, 1996, and assumed regulatory oversight for the plant on March 3, 1997...

Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

DOEpatents

Cohen, M.R.; Gal, E.

1993-04-13

A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

RECTIFIED ABSORPTION METHOD FOR THE SEPARATION OF HYDROGEN ISOTOPES

DOEpatents

Hunt, C.D.; Hanson, D.N.

1961-10-17

A method is described for separating and recovering heavy hydrogen isotopes from gaseous mixtures by multiple stage cyclic absorption and rectification from an approximate solvent. In particular, it is useful for recovering such isoteoes from ammonia feedstock streams containing nitrogen solvent. Modifications of the process ranging from isobaric to isothermal are provided. Certain impurities are tolerated, giving advantages over conventional fractional distillation processes. (AEC)

Curing preceramic polymers by exposure to nitrogen dioxide

NASA Technical Reports Server (NTRS)

Rabe, James A. (Inventor); Lipowitz, Jonathan (Inventor); Lu, Paul P. (Inventor)

1991-01-01

A rapid method of infusibilizing (curing) preceramic polymers comprising treatment said polymers with gaseous nitrogen dioxide. The infusibilized polymers may be pyrolyzed to temperatures in excess of about 800.degree. C. to yield ceramic materials with low oxygen content and, thus, good thermal stability. The methods are especially useful for the production of ceramic fibers and, more specifically, to the on-line production of ceramic fibers.

Method for removing oxide contamination from titanium diboride powder

DOEpatents

Brynestad, J.; Bamberger, C.E.

A method for removing oxide contamination from titanium diboride powder involves the direct chemical treatment of TiB/sub 2/ powders with a gaseous boron halide, such as BCl/sub 3/, at temperatures in the range of 500 to 800/sup 0/C. The BCl/sub 3/ reacts with the oxides to form volatile species which are removed by the BCl/sub 3/ exit stream.

Method for removing oxide contamination from titanium diboride powder

DOEpatents

Brynestad, Jorulf; Bamberger, Carlos E.

1984-01-01

A method for removing oxide contamination from titanium diboride powder involves the direct chemical treatment of TiB.sub.2 powders with a gaseous boron halide, such as BCl.sub.3, at temperatures in the range of 500.degree.-800.degree. C. The BCl.sub.3 reacts with the oxides to form volatile species which are removed by the BCl.sub.3 exit stream.

Nanoparticle-based gas sensors and methods of using the same

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mickelson, William; Zettl, Alex

Gas sensors are provided. The gas sensors include a gas sensing element having metal oxide nanoparticles and a thin-film heating element. Systems that include the gas sensors, as well as methods of using the gas sensors, are also provided. Embodiments of the present disclosure find use in a variety of different applications, including detecting whether an analyte is present in a gaseous sample.

METHOD FOR TESTING COATINGS

DOEpatents

Johns, I.B.; Newton, A.S.

1958-09-01

A method is described for detecting pin hole imperfections in coatings on uranium-metal objects. Such coated objects are contacted with a heated atmosphere of gaseous hydrogen and imperfections present in the coatings will allow the uranlum to react with the hydrogen to form uranium hydride. Since uranium hydride is less dense than uranium metal it will swell, causing enlargement of the coating defeot and rendering it visible.

METHOD OF FORMING TANTALUM SILICIDE ON TANTALUM SURFACES

DOEpatents

Bowman, M.G.; Krikorian, N.H.

1961-10-01

A method is described for forming a non-corrosive silicide coating on tantalum. The coating is made through the heating of trirhenium silicides in contact with the tantalum object to approximately 1400 deg C at which temperature trirhenium silicide decomposes into rhenium and gaseous silicons. The silicon vapor reacts with the tantalum surface to form a tantalum silicide layer approximately 10 microns thick. (AEC)

Improved measurement of carbonaceous aerosol in Beijing, China: intercomparison of sampling and thermal-optical analysis methods

NASA Astrophysics Data System (ADS)

Cheng, Y.; He, K. B.; Duan, F. K.; Zheng, M.; Ma, Y. L.; Tan, J. H.; Du, Z. Y.

2010-06-01

The sampling artifacts (both positive and negative) and the influence of thermal-optical methods (both charring correction method and the peak inert mode temperature) on the split of organic carbon (OC) and elemental carbon (EC) were evaluated in Beijing. The positive sampling artifact constituted 10% and 23% of OC concentration determined by the bare quartz filter during winter and summer, respectively. For summer samples, the adsorbed gaseous organics were found to continuously evolve off the filter during the whole inert mode when analyzed by the IMPROVE-A temperature protocol. This may be due to the oxidation of the adsorbed organics during sampling (reaction artifact) which would increase their thermal stability. The backup quartz approach was evaluated by a denuder-based method for assessing the positive artifact. The quartz-quartz (QBQ) in series method was demonstrated to be reliable, since all of the OC collected by QBQ was from originally gaseous organics. Negative artifact that could be adsorbed by quartz filter was negligible. When the activated carbon impregnated glass fiber (CIG) filter was used as the denuded backup filter, the denuder efficiency for removing gaseous organics that could be adsorbed by the CIG filter was only about 30%. EC values were found to differ by a factor of about two depending on the charring correction method. Influence of the peak inert mode temperature was evaluated based on the summer samples. The EC value was found to continuously decrease with the peak inert mode temperature. Premature evolution of light absorbing carbon began when the peak inert mode temperature was increased from 580 to 650 °C; when further increased to 800 °C, the OC and EC split frequently occurred in the He mode, and the last OC peak was characterized by the overlapping of two separate peaks. The discrepancy between EC values defined by different temperature protocols was larger for Beijing carbonaceous aerosol compared with North America and Europe, perhaps due to the higher concentration of brown carbon in Beijing aerosol.

Antibacterial activity and antibiotic modulating potential of the essential oil obtained from Eugenia jambolana in association with led lights.

PubMed

Pereira, Nara L F; Aquino, Pedro E A; Júnior, José G A S; Cristo, Janyketchuly S; Vieira Filho, Marcos A; Moura, Flávio F; Ferreira, Najla M N; Silva, Maria K N; Nascimento, Eloiza M; Correia, Fabrina M A; Cunha, Francisco A B; Boligon, Aline A; Coutinho, Henrique D M; Ribeiro-Filho, Jaime; Matias, Edinardo F F; Guedes, Maria I F

2017-09-01

Bacterial resistance has risen as an important health problem with impact on the pharmaceutical industry because many antibiotics have become ineffective, which has affected their commercialization. The Brazilian biodiversity is marked by a vast variety of natural products with significant therapeutic potential, which could bring new perspectives in the treatment of infections caused by resistant microorganisms. The present study aimed to evaluate the antibacterial effect of the essential oil obtained from Eugenia jambolana (EjEO) using the method of microdilution method to determine the Minimum Inhibitory Concentration (MIC). The modulatory effect of this oil on antibiotic activity was determined using both the broth microdilution and gaseous contact methods. The antibacterial effect of the association of the gaseous contact and the use of a LED unit with red and blue lights was also determined. The chemical components of the EjEO were characterized by HPLC, which revealed the presence of α-pinene as a major constituent. The EjEO presented a MIC≥128μg/mL against S. aureus and ≥1024μg/mL against E. coli. The combination of the EjEO with antibiotics presented synergism against E. coli and antagonism against S. aureus. An antagonistic effect was obtained from the association of EjEO with amikacin and erythromycin by the method of gaseous contact. On the other hand, the association of EjEO with ciprofloxacin presented a synergistic effect against S. aureus and E. coli exposed to LED lights. A similar effect was observed in the association of the EjEO with norfloxacin presented synergism against S. aureus in the same conditions. In conclusion, our results demonstrated that the essential oil obtained from Eugenia jambolana interfere with the action of antibiotics against bacteria exposed to LED lights. Thus, further researches are required to elucidate the mechanisms underlying these effects, which could open new perspectives in the development of new antibacterial therapies. Copyright © 2017 Elsevier B.V. All rights reserved.

Automated cell tracking identifies mechanically oriented cell divisions during Drosophila axis elongation.

PubMed

Wang, Michael F Z; Hunter, Miranda V; Wang, Gang; McFaul, Christopher; Yip, Christopher M; Fernandez-Gonzalez, Rodrigo

2017-04-01

Embryos extend their anterior-posterior (AP) axis in a conserved process known as axis elongation. Drosophila axis elongation occurs in an epithelial monolayer, the germband, and is driven by cell intercalation, cell shape changes, and oriented cell divisions at the posterior germband. Anterior germband cells also divide during axis elongation. We developed image analysis and pattern-recognition methods to track dividing cells from confocal microscopy movies in a generally applicable approach. Mesectoderm cells, forming the ventral midline, divided parallel to the AP axis, while lateral cells displayed a uniform distribution of division orientations. Mesectoderm cells did not intercalate and sustained increased AP strain before cell division. After division, mesectoderm cell density increased along the AP axis, thus relieving strain. We used laser ablation to isolate mesectoderm cells from the influence of other tissues. Uncoupling the mesectoderm from intercalating cells did not affect cell division orientation. Conversely, separating the mesectoderm from the anterior and posterior poles of the embryo resulted in uniformly oriented divisions. Our data suggest that mesectoderm cells align their division angle to reduce strain caused by mechanical forces along the AP axis of the embryo. © 2017. Published by The Company of Biologists Ltd.

Realization of a new concept for visible frequency division: phase locking of harmonic and sum frequencies.

PubMed

Telle, H R; Meschede, D; Hänsch, T W

1990-05-15

We explore and demonstrate the feasibility of an optical-frequency-to-radio-frequency division method that is based on visible or near-infrared laser oscillators only. Comparing harmonic and sum frequencies, we generate the arithmetic average of two visible frequencies. Cascading n stages provides difference-frequency division by 2(n). For a demonstration we have phase locked the second harmonic and the sum frequency of two independent diode lasers.

Rapid phylogenetic dissection of prokaryotic community structure in tidal flat using pyrosequencing.

PubMed

Kim, Bong-Soo; Kim, Byung Kwon; Lee, Jae-Hak; Kim, Myungjin; Lim, Young Woon; Chun, Jongsik

2008-08-01

Dissection of prokaryotic community structure is prerequisite to understand their ecological roles. Various methods are available for such a purpose which amplification and sequencing of 16S rRNA genes gained its popularity. However, conventional methods based on Sanger sequencing technique require cloning process prior to sequencing, and are expensive and labor-intensive. We investigated prokaryotic community structure in tidal flat sediments, Korea, using pyrosequencing and a subsequent automated bioinformatic pipeline for the rapid and accurate taxonomic assignment of each amplicon. The combination of pyrosequencing and bioinformatic analysis showed that bacterial and archaeal communities were more diverse than previously reported in clone library studies. Pyrosequencing analysis revealed 21 bacterial divisions and 37 candidate divisions. Proteobacteria was the most abundant division in the bacterial community, of which Gamma-and Delta-Proteobacteria were the most abundant. Similarly, 4 archaeal divisions were found in tidal flat sediments. Euryarchaeota was the most abundant division in the archaeal sequences, which were further divided into 8 classes and 11 unclassified euryarchaeota groups. The system developed here provides a simple, in-depth and automated way of dissecting a prokaryotic community structure without extensive pretreatment such as cloning.

Radioactive-gas separation technique

NASA Technical Reports Server (NTRS)

Haney, R.; King, K. J.; Nellis, D. O.; Nisson, R. S.; Robling, P.; Womack, W.

1977-01-01

Cryogenic technique recovers gases inexpensively. Method uses differences in vapor pressures, melting points, and boiling points of components in gaseous mixture. Series of temperature and pressure variations converts gases independently to solid and liquid states, thereby simplifying separation. Apparatus uses readily available cryogen and does not require expensive refrigeration equipment.

Methods for sequestering carbon dioxide into alcohols via gasification fermentation

DOEpatents

Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

2013-11-26

The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

METHOD OF SEPARATING HYDROGEN ISOTOPES

DOEpatents

Salmon, O.N.

1958-12-01

The process of separating a gaseous mixture of hydrogen and tritium by contacting finely dlvided palladium with the mixture in order to adsorb the gases, then gradually heating the palladium and collecting the evolved fractlons, is described. The fraction first given off is richer in trltium than later fractions.

Solution of the symmetric eigenproblem AX=lambda BX by delayed division

NASA Technical Reports Server (NTRS)

Thurston, G. A.; Bains, N. J. C.

1986-01-01

Delayed division is an iterative method for solving the linear eigenvalue problem AX = lambda BX for a limited number of small eigenvalues and their corresponding eigenvectors. The distinctive feature of the method is the reduction of the problem to an approximate triangular form by systematically dropping quadratic terms in the eigenvalue lambda. The report describes the pivoting strategy in the reduction and the method for preserving symmetry in submatrices at each reduction step. Along with the approximate triangular reduction, the report extends some techniques used in the method of inverse subspace iteration. Examples are included for problems of varying complexity.

Method for implementation of recursive hierarchical segmentation on parallel computers

NASA Technical Reports Server (NTRS)

Tilton, James C. (Inventor)

2005-01-01

A method, computer readable storage, and apparatus for implementing a recursive hierarchical segmentation algorithm on a parallel computing platform. The method includes setting a bottom level of recursion that defines where a recursive division of an image into sections stops dividing, and setting an intermediate level of recursion where the recursive division changes from a parallel implementation into a serial implementation. The segmentation algorithm is implemented according to the set levels. The method can also include setting a convergence check level of recursion with which the first level of recursion communicates with when performing a convergence check.

Industrial Fuel Gas Demonstration Plant Program: environmental permit compliance plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bodamer, Jr., James W.; Bocchino, Robert M.

1979-11-01

This Environmental Permit Compliance Plan is intended to assist the Memphis Light, Gas and Water Division in acquiring the necessary environmental permits for their proposed Industrial Fuel Gas Demonstration Plant in a time frame consistent with the construction schedule. Permits included are those required for installation and/or operation of gaseous, liquid and solid waste sources and disposal areas. Only those permits presently established by final regulations are described. The compliance plan describes procedures for obtaining each permit from identified federal, state and local agencies. The information needed for the permit application is presented, and the stepwise procedure to follow whenmore » filing the permit application is described. Information given in this plan was obtained by reviewing applicable laws and regulations and from telephone conversations with agency personnel on the federal, state and local levels. This Plan also presents a recommended schedule for beginning the work necessary to obtain the required environmental permits in order to begin dredging operations in October, 1980 and construction of the plant in September, 1981. Activity for several key permits should begin as soon as possible.« less

Treatment of organic waste

DOEpatents

Grantham, LeRoy F.

1979-01-01

An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

Three-electrode low pressure discharge apparatus and method for uniform ionization of gaseous media

DOEpatents

McLellan, Edward J.

1983-01-01

Uniform, transverse electrical discharges are produced in gaseous media without the necessity of switching the main discharge voltage with an external device which carries the entire discharge current. A three-electrode low pressure discharge tube is charged across its anode (1) and cathode (2) to below breakdown voltage using a dc voltage source (3). An array of resistors (4) or capacitors can be made to discharge to the wire screen anode by means of a low energy high voltage pulse circuit (5) producing sufficient preionization in the region between the anode and cathode to initiate and control the main discharge. The invention has been demonstrated to be useful as a CO.sub.2 laser oscillator and pulse-smoother. It can be reliably operated in the sealed-off mode.

Simultaneous determination of gaseous and particulate carbonyls in air by coupling micellar electrokinetic capillary chromatography with molecular imprinting solid-phase extraction.

PubMed

Sun, Hui; Lai, Jia-Ping; Fung, Ying Sing

2014-09-05

A novel method coupling molecular imprinting solid-phase extraction (MISPE) and micellar electrokinetic capillary chromatography (MEKC) was developed to enable the hourly determination of low level of ambient carbonyls, and study their partition between gaseous phase and particulate phase. With 2,4-dinitroaniline (DNAN) as dummy imprinting template, the unreacted 2,4-Dinitrophenylhydrazine (DNPH) in sampling solution could be removed effectively using MISPE, and an average recovery of 97±5.3% (n=5) for the carbonyl-DNPH derivatives was achieved. Owing to the high enrichment due to sample clean-up, and the improvement of MEKC separation efficiency, many low abundant carbonyls could be detected by hourly in the field study. Copyright © 2014 Elsevier B.V. All rights reserved.

Method of producing thermally sprayed metallic coating

DOEpatents

Byrnes, Larry Edward [Rochester Hills, MI; Kramer, Martin Stephen [Clarkston, MI; Neiser, Richard A [Albuquerque, NM

2003-08-26

The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

Thermal synthesis apparatus

DOEpatents

Fincke, James R [Idaho Falls, ID; Detering, Brent A [Idaho Falls, ID

2009-08-18

An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

Core/shell structured Zn/ZnO nanoparticles synthesized by gaseous laser ablation with enhanced photocatalysis efficiency

NASA Astrophysics Data System (ADS)

Song, Lu; Wang, Yafei; Ma, Jing; Zhang, Qinghua; Shen, Zhijian

2018-06-01

Zinc oxide (ZnO) is a competitive candidate in semiconductor photocatalysts, only if the efficiency could be fully optimized especially by tailored nanostructures. Here we report a kind of core/shell structured Zn/ZnO nanoparticles with enhanced photocatalysis efficiency, which were synthesized by a highly-productive gaseous laser ablation method. The nanodroplets generated by laser ablation would be reduced to zinc in the protective atmosphere, and further be oxidized at surface to form a specific core/shell structured Zn/ZnO nanoparticles within seconds. Thanks to the formation of this Zn-ZnO Schottky junction, the photocatalysis degradation efficiency of such core/shell Zn/ZnO nanostructure is significantly improved owing to the enhanced visible light absorption and inhibited carrier recombination by introducing the metallic zinc.

40 CFR 86.137-90 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... filters to the weighing chamber for post-test conditioning, if applicable. (22) Disconnect the exhaust... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Dynamometer test run, gaseous and... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-90 Dynamometer test run, gaseous...

40 CFR 86.137-90 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... filters to the weighing chamber for post-test conditioning, if applicable. (22) Disconnect the exhaust... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Dynamometer test run, gaseous and... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-90 Dynamometer test run, gaseous...

40 CFR 86.137-90 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... filters to the weighing chamber for post-test conditioning, if applicable. (22) Disconnect the exhaust... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Dynamometer test run, gaseous and... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-90 Dynamometer test run, gaseous...

40 CFR 86.137-90 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... filters to the weighing chamber for post-test conditioning, if applicable. (22) Disconnect the exhaust... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Dynamometer test run, gaseous and... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-90 Dynamometer test run, gaseous...

40 CFR 86.137-94 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... filters to the weighing chamber for post-test conditioning, if applicable. (22) Disconnect the exhaust... 40 Protection of Environment 19 2014-07-01 2014-07-01 false Dynamometer test run, gaseous and... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-94 Dynamometer test run, gaseous...

10 CFR Appendix C to Part 110 - Illustrative List of Gaseous Diffusion Enrichment Plant Assemblies and Components Under NRC...

Code of Federal Regulations, 2011 CFR

2011-01-01

... welds with substantial amounts of repetition of layout. The equipment, components and piping systems are... fully fluorinated hydrocarbon polymers. 1. Assemblies and components especially designed or prepared for use in gaseous diffusion enrichment. 1.1 Gaseous Diffusion Barriers Especially designed or prepared...

10 CFR Appendix C to Part 110 - Illustrative List of Gaseous Diffusion Enrichment Plant Assemblies and Components Under NRC...

Code of Federal Regulations, 2012 CFR

2012-01-01

... welds with substantial amounts of repetition of layout. The equipment, components and piping systems are... fully fluorinated hydrocarbon polymers. 1. Assemblies and components especially designed or prepared for use in gaseous diffusion enrichment. 1.1 Gaseous Diffusion Barriers Especially designed or prepared...

10 CFR Appendix C to Part 110 - Illustrative List of Gaseous Diffusion Enrichment Plant Assemblies and Components Under NRC...

Code of Federal Regulations, 2014 CFR

2014-01-01

... welds with substantial amounts of repetition of layout. The equipment, components and piping systems are... fully fluorinated hydrocarbon polymers. 1. Assemblies and components especially designed or prepared for use in gaseous diffusion enrichment. 1.1 Gaseous Diffusion Barriers Especially designed or prepared...

10 CFR Appendix C to Part 110 - Illustrative List of Gaseous Diffusion Enrichment Plant Assemblies and Components Under NRC...

Code of Federal Regulations, 2013 CFR

2013-01-01

... welds with substantial amounts of repetition of layout. The equipment, components and piping systems are... fully fluorinated hydrocarbon polymers. 1. Assemblies and components especially designed or prepared for use in gaseous diffusion enrichment. 1.1 Gaseous Diffusion Barriers Especially designed or prepared...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and...-IGNITION ENGINES Exhaust Emission Test Procedures § 89.412 Raw gaseous exhaust sampling and analytical... must be incorporated in each system used for raw testing under this subpart. (1) [Reserved] (2) The...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and...-IGNITION ENGINES Exhaust Emission Test Procedures § 89.412 Raw gaseous exhaust sampling and analytical... must be incorporated in each system used for raw testing under this subpart. (1) [Reserved] (2) The...

40 CFR 86.137-96 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Dynamometer test run, gaseous and particulate emissions. 86.137-96 Section 86.137-96 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-96 Dynamometer test run, gaseous...

40 CFR 86.137-96 - Dynamometer test run, gaseous and particulate emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Dynamometer test run, gaseous and particulate emissions. 86.137-96 Section 86.137-96 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.137-96 Dynamometer test run, gaseous...

40 CFR 90.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the values recorded. The number of events that may occur between the pre- and post-checks is not.... (9) Neither the zero drift nor the span drift between the pre-analysis and post-analysis checks on... Gaseous Exhaust Test Procedures § 90.413 Exhaust sample procedure—gaseous components. (a) Automatic data...

40 CFR 90.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the values recorded. The number of events that may occur between the pre- and post-checks is not.... (9) Neither the zero drift nor the span drift between the pre-analysis and post-analysis checks on... Gaseous Exhaust Test Procedures § 90.413 Exhaust sample procedure—gaseous components. (a) Automatic data...

40 CFR 90.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2014 CFR

2014-07-01

... the values recorded. The number of events that may occur between the pre- and post-checks is not.... (9) Neither the zero drift nor the span drift between the pre-analysis and post-analysis checks on... Gaseous Exhaust Test Procedures § 90.413 Exhaust sample procedure—gaseous components. (a) Automatic data...

40 CFR 90.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2012 CFR

2012-07-01

... the values recorded. The number of events that may occur between the pre- and post-checks is not.... (9) Neither the zero drift nor the span drift between the pre-analysis and post-analysis checks on... Gaseous Exhaust Test Procedures § 90.413 Exhaust sample procedure—gaseous components. (a) Automatic data...

40 CFR 90.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the values recorded. The number of events that may occur between the pre- and post-checks is not.... (9) Neither the zero drift nor the span drift between the pre-analysis and post-analysis checks on... Gaseous Exhaust Test Procedures § 90.413 Exhaust sample procedure—gaseous components. (a) Automatic data...

The Gaseous Phase as a Probe of the Astrophysical Solid Phase Chemistry

NASA Astrophysics Data System (ADS)

Abou Mrad, Ninette; Duvernay, Fabrice; Isnard, Robin; Chiavassa, Thierry; Danger, Grégoire

2017-09-01

In support of space missions and spectroscopic observations, laboratory experiments on ice analogs enable a better understanding of organic matter formation and evolution in astrophysical environments. Herein, we report the monitoring of the gaseous phase of processed astrophysical ice analogs to determine if the gaseous phase can elucidate the chemical mechanisms and dominant reaction pathways occurring in the solid ice subjected to vacuum ultra-violet (VUV) irradiation at low temperature and subsequently warmed. Simple (CH3OH), binary (H2O:CH3OH, CH3OH:NH3), and ternary ice analogs (H2O:CH3OH:NH3) were VUV-processed and warmed. The evolution of volatile organic compounds in the gaseous phase shows a direct link between their relative abundances in the gaseous phase, and the radical and thermal chemistries modifying the initial ice composition. The correlation between the gaseous and solid phases may play a crucial role in deciphering the organic composition of astrophysical objects. As an example, possible solid compositions of the comet Lovejoy are suggested using the abundances of organics in its comae.

High-speed bioimaging with frequency-division-multiplexed fluorescence confocal microscopy

NASA Astrophysics Data System (ADS)

Mikami, Hideharu; Harmon, Jeffrey; Ozeki, Yasuyuki; Goda, Keisuke

2017-04-01

We present methods of fluorescence confocal microscopy that enable unprecedentedly high frame rate of > 10,000 fps. The methods are based on a frequency-division multiplexing technique, which was originally developed in the field of communication engineering. Specifically, we achieved a broad bandwidth ( 400 MHz) of detection signals using a dual- AOD method and overcame limitations in frame rate, due to a scanning device, by using a multi-line focusing method, resulting in a significant increase in frame rate. The methods have potential biomedical applications such as observation of sub-millisecond dynamics in biological tissues, in-vivo three-dimensional imaging, and fluorescence imaging flow cytometry.

AN OVERVIEW OF PATHOGEN RESEARCH IN THE MICROBIOLOGICAL AND CHEMICAL EXPOSURE ASSESSMENT RESEARCH DIVISION

EPA Science Inventory

The Microbiological and Chemical Exposure Assessment Research Division of the EPA Office of Research and Development's National Exposure Research Laboratory has a robust in-house research program aimed at developing better occurrence and exposure methods for waterborne pathogens....

Methods for geochemical analysis

USGS Publications Warehouse

Baedecker, Philip A.

1987-01-01

The laboratories for analytical chemistry within the Geologic Division of the U.S. Geological Survey are administered by the Office of Mineral Resources. The laboratory analysts provide analytical support to those programs of the Geologic Division that require chemical information and conduct basic research in analytical and geochemical areas vital to the furtherance of Division program goals. Laboratories for research and geochemical analysis are maintained at the three major centers in Reston, Virginia, Denver, Colorado, and Menlo Park, California. The Division has an expertise in a broad spectrum of analytical techniques, and the analytical research is designed to advance the state of the art of existing techniques and to develop new methods of analysis in response to special problems in geochemical analysis. The geochemical research and analytical results are applied to the solution of fundamental geochemical problems relating to the origin of mineral deposits and fossil fuels, as well as to studies relating to the distribution of elements in varied geologic systems, the mechanisms by which they are transported, and their impact on the environment.

Evaluation of selective control information detection scheme in orthogonal frequency division multiplexing-based radio-over-fiber and visible light communication links

NASA Astrophysics Data System (ADS)

Dalarmelina, Carlos A.; Adegbite, Saheed A.; Pereira, Esequiel da V.; Nunes, Reginaldo B.; Rocha, Helder R. O.; Segatto, Marcelo E. V.; Silva, Jair A. L.

2017-05-01

Block-level detection is required to decode what may be classified as selective control information (SCI) such as control format indicator in 4G-long-term evolution systems. Using optical orthogonal frequency division multiplexing over radio-over-fiber (RoF) links, we report the experimental evaluation of an SCI detection scheme based on a time-domain correlation (TDC) technique in comparison with the conventional maximum likelihood (ML) approach. When compared with the ML method, it is shown that the TDC method improves detection performance over both 20 and 40 km of standard single mode fiber (SSMF) links. We also report a performance analysis of the TDC scheme in noisy visible light communication channel models after propagation through 40 km of SSMF. Experimental and simulation results confirm that the TDC method is attractive for practical orthogonal frequency division multiplexing-based RoF and fiber-wireless systems. Unlike the ML method, another key benefit of the TDC is that it requires no channel estimation.

Rapid Deployment Logistics: Lebanon, 1958

DTIC Science & Technology

1984-10-01

planning. In case of a general conflict, the 1st Infantry Division and 82d Airborne Division would also join STRAC. 7 Wet ...was aware of the problem and had long been researching different methods of cargo handling. Roll-on and roll-off ships provided one solution. In 1954...battalion land.ng team, or b, combining both methods . Basically, the forces were to deter 3- stop hostilities between Israel and Arab E’tates, r2

Probabilistic model of nonlinear penalties due to collision-induced timing jitter for calculation of the bit error ratio in wavelength-division-multiplexed return-to-zero systems

NASA Astrophysics Data System (ADS)

Sinkin, Oleg V.; Grigoryan, Vladimir S.; Menyuk, Curtis R.

2006-12-01

We introduce a fully deterministic, computationally efficient method for characterizing the effect of nonlinearity in optical fiber transmission systems that utilize wavelength-division multiplexing and return-to-zero modulation. The method accurately accounts for bit-pattern-dependent nonlinear distortion due to collision-induced timing jitter and for amplifier noise. We apply this method to calculate the error probability as a function of channel spacing in a prototypical multichannel return-to-zero undersea system.

Biofuels and Bioproducts from Wet and Gaseous Waste Streams: Challenges and Opportunities

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

This report draws together activities related to wet and gaseous waste feedstocks into a single document. It enables an amplified focus on feedstocks in the relevant technology and potential markets category. Also, this report helps to inform and support ongoing wet and gaseous resource recovery activities in the Bioenergy Technologies Office (BETO) and in the broader federal space. Historically, the office has identified wet and gaseous waste feedstocks as potentially advantageous, but has not pursued them with a sustained focus. This document seeks to position these waste streams appropriately alongside more traditional feedstocks in BETO efforts.

STATEQ: a nonlinear least-squares code for obtaining Martin thermodynamic representations of fluids in the gaseous and dense gaseous regions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Milora, S. L.

1976-02-01

The use of the code NLIN (IBM Share Program No. 1428) to obtain empirical thermodynamic pressure-volume-temperature (P-V-T) relationships for substances in the gaseous and dense gaseous states is described. When sufficient experimental data exist, the code STATEQ will provide least-squares estimates for the 21 parameters of the Martin model. Another code, APPROX, is described which also obtains parameter estimates for the model by making use of the approximate generalized behavior of fluids. Use of the codes is illustrated in obtaining thermodynamic representations for isobutane. (auth)

40 CFR 98.254 - Monitoring and QA/QC requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) ASTM D1945-03 Standard Test Method for Analysis of Natural Gas by Gas Chromatography (incorporated by... by Gas Chromatography (incorporated by reference, see § 98.7). (4) GPA 2261-00 Analysis for Natural Gas and Similar Gaseous Mixtures by Gas Chromatography (incorporated by reference, see § 98.7). (5...

Method for converting asbestos to non-carcinogenic compounds

DOEpatents

Selby, Thomas W.

1996-01-01

Hazardous and carcinogenic asbestos waste characterized by a crystalline fibrous structure is transformed into non-carcinogenic, relatively nonhazardous, and non-crystalline solid compounds and gaseous compounds which have commercial utilization. The asbestos waste is so transformed by the complete fluorination of the crystalline fibrous silicate mineral defining the asbestos.

Method for converting asbestos to non-carcinogenic compounds

DOEpatents

Selby, T.W.

1996-08-06

Hazardous and carcinogenic asbestos waste characterized by a crystalline fibrous structure is transformed into non-carcinogenic, relatively nonhazardous, and non-crystalline solid compounds and gaseous compounds which have commercial utilization. The asbestos waste is so transformed by the complete fluorination of the crystalline fibrous silicate mineral defining the asbestos. 7 figs.

Laser Diagnostics for combustion temperature and species measurements

NASA Technical Reports Server (NTRS)

Eckbreth, Alan C.

1988-01-01

Laser optical diagnostic techniques for the measurement of combustion gaseous-phase temperatures and, or species concentrations are discussed. The techniques fall into two classes: incoherent (Rayleigh scattering, spontaneous Raman scattering, laser induced fluorescence spectroscopy) and coherent (coherent anti-Stokes Raman spectroscopy). The advantages, disadvantages and applicability of each method are outlined.

Nitrogen dioxide detection

DOEpatents

Sinha, Dipen N.; Agnew, Stephen F.; Christensen, William H.

1993-01-01

Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

PRODUCTION OF URANIUM TETRAFLUORIDE

DOEpatents

Shaw, W.E.; Spenceley, R.M.; Teetzel, F.M.

1959-08-01

A method is presented for producing uranium tetrafluoride from the gaseous hexafluoride by feeding the hexafluoride into a high temperature zone obtained by the recombination of molecularly dissociated hydrogen. The molal ratio of hydrogen to uranium hexnfluoride is preferably about 3 to 1. Uranium tetrafluoride is obtained in a finely divided, anhydrous state.

Ventilation of porous media

DOEpatents

Neeper, Donald A.

1994-01-01

Methods for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction.

Halogenation of cobalt dicarbollide

DOEpatents

Hurlburt, P.K.; Abney, K.D.; Kinkead, S.A.

1997-05-20

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.

40 CFR 90.416 - Intake air flow measurement specifications.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Intake air flow measurement... Gaseous Exhaust Test Procedures § 90.416 Intake air flow measurement specifications. (a) If used, the engine intake air flow measurement method used must have a range large enough to accurately measure the...

Halogenation of cobalt dicarbollide

DOEpatents

Hurlburt, Paul K.; Abney, Kent D.; Kinkead, Scott A.

1997-01-01

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10' positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron.

40 CFR 49.124 - Rule for limiting visible emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

...% opacity limit. (3) The visible emissions from an oil-fired boiler or solid fuel-fired boiler that..., fuel, fuel oil, fugitive dust, gaseous fuel, grate cleaning, marine vessel, mobile sources, motor..., PM10, PM2.5, reference method, refuse, Regional Administrator, residual fuel oil, smudge pot, solid...

40 CFR 49.124 - Rule for limiting visible emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

...% opacity limit. (3) The visible emissions from an oil-fired boiler or solid fuel-fired boiler that..., fuel, fuel oil, fugitive dust, gaseous fuel, grate cleaning, marine vessel, mobile sources, motor..., PM10, PM2.5, reference method, refuse, Regional Administrator, residual fuel oil, smudge pot, solid...

Cyclin D regulation of a sexually dimorphic asymmetric cell division

PubMed Central

Tilmann, Christopher; Kimble, Judith

2006-01-01

SUMMARY The C. elegans somatic gonadal precursor cell (SGP) divides asymmetrically to establish gonad-specific coordinates in both sexes. In addition, the SGP division is sexually dimorphic and initiates sex-specific programs of gonadogenesis. Wnt/MAPK signaling determines the gonadal axes, and the FKH-6 transcription factor specifies the male mode of SGP division. In this paper, we demonstrate that C. elegans cyclin D controls POP-1/TCF asymmetry in the SGP daughters as well as fkh-6 and rnr expression in the SGPs. Although cyclin D mutants have delayed SGP divisions, the cyclin D defects are not mimicked by other methods of retarding the SGP division. We find that EFL-1/E2F has an antagonistic effect on fkh-6 expression and gonadogenesis, which is relieved by cyclin D activity. We propose that cyclin D and other canonical regulators of the G1/S transition coordinate key regulators of axis formation and sex determination with cell cycle progression to achieve the sexually dimorphic SGP asymmetric division. PMID:16198291

Mentorship programs for faculty development in academic general pediatric divisions.

PubMed

Takagishi, Jennifer; Dabrow, Sharon

2011-01-01

Introduction. Mentoring relationships have been shown to support academicians in areas of research, work/life balance, and promotion. Methods. General pediatric division chiefs accessed an electronic survey asking about mentorship relationships, their ability to create a mentorship program, and resources needed. Results. Dyadic mentorship programs were available at 53% of divisions. Peer mentorship programs were available at 27% of divisions. Overall, 84% of chiefs believed that dyadic mentorship would benefit their faculty. 91% of chiefs believed that peer mentorship would benefit their faculty. Chiefs were interested in starting peer (57%) or dyadic (55%) mentorship programs. Few divisions had a peer mentorship program available, whereas 24% already had a dyadic program. 43% of chiefs felt that they had the tools to start a program. Many tools are needed to create a program. Discussion. General pediatric division chiefs acknowledge the benefits of mentoring relationships, and some have programs in place. Many need tools to create them. Pediatric societies could facilitate this critical area of professional development.

New Gas Polarographic Hydrogen Sensor

NASA Technical Reports Server (NTRS)

Dominguez, Jesus A.; Barile, Ron

2004-01-01

Polarography is the measurement of the current that flows in solution as a function of an applied voltage. The actual form of the observed polarographic current depends upon the manner in which the voltage is applied and on the characteristics of the working electrode. The new gas polarographic H2 sensor shows a current level increment with concentration of the gaseous H2 similar to those relating to metal ions in liquid electrolytes in well-known polarography. This phenomenon is caused by the fact that the diffusion of the gaseous H2 through a gas diffusion hole built in the sensor is a rate-determining step in the gaseous-hydrogen sensing mechanism. The diffusion hole artificially limits the diffusion of the gaseous H2 toward the electrode located at the sensor cavity. This gas polarographic H2 sensor. is actually an electrochemical-pumping cell since the gaseous H2 is in fact pumped via the electrochemical driving force generated between the electrodes. Gaseous H2 enters the diffusion hole and reaches the first electrode (anode) located in the sensor cavity to be transformed into an H+ ions or protons; H+ ions pass through the electrolyte and reach the second electrode (cathode) to be reformed to gaseous H2. Gas polarographic 02 sensors are commercially available; a gas polarographic 02 sensor was used to prove the feasibility of building a new gas polarographic H2 sensor.

H2 Detection via Polarography

NASA Technical Reports Server (NTRS)

Dominquez, Jesus; Barile, Ron

2006-01-01

Polarography is the measurement of the current that flows in solution as a function of an applied voltage. The actual form of the observed polarographic current depends upon the manner in which the voltage is applied and on the characteristics of the working electrode. The new gas polarographic H2 sensor shows a current level increment with concentration of the gaseous H2 similar to those relating to metal ions in liquid electrolytes in well-known polarography. This phenomenon is caused by the fact that the diffusion of the gaseous H2 through a gas diffusion hole built in the sensor is a rate-determining step in the gaseous-hydrogen sensing mechanism. The diffusion hole artificially limits the diffusion of the gaseous H2 toward the electrode located at the sensor cavity. This gas polarographic H2 sensor is actually an electrochemical-pumping cell since the gaseous H2 is in fact pumped via the electrochemical driving force generated between the electrodes. Gaseous H2 enters the diffusion hole and reaches the first electrode (anode) located in the sensor cavity to be transformed into an H ions or protons; H ions pass through the electrolyte and reach the second electrode (cathode) to be reformed to gaseous H2. Gas polarographic O2 sensors are commercially available; a gas polarographic O2 sensor was used to prove the feasibility of building a new gas polarographic H2 sensor.

Understanding the variation in the millimeter-wave emission of Venus

NASA Technical Reports Server (NTRS)

Fahd, Antoine K.; Steffes, Paul G.

1992-01-01

Recent observations of the millimeter-wave emission from Venus at 112 GHz (2.6 mm) have shown significant variations in the continuum flux emission that may be attributed to the variability in the abundances of absorbing constituents in the Venus atmosphere. Such constituents include gaseous H2SO4, SO2, and liquid sulfuric acid (cloud condensates). Recently, Fahd and Steffes have shown that the effects of liquid H, SO4, and gaseous SO2 cannot completely account for this measured variability in the millimeter-wave emission of Venus. Thus, it is necessary to study the effect of gaseous H2SO4 on the millimeter-wave emission of Venus. This requires knowledge of the millimeter-wavelength (MMW) opacity of gaseous H2SO4, which unfortunately has never been determined for Venus-like conditions. We have measured the opacity of gaseous H2SO4 in a CO2 atmosphere at 550, 570, and 590 K, at 1 and 2 atm total pressure, and at a frequency of 94.1 GHz. Our results, in addition to previous centimeter-wavelength results are used to verify a modeling formalism for calculating the expected opacity of this gaseous mixture at other frequencies. This formalism is incorporated into a radiative transfer model to study the effect of gaseous H2SO4 on the MMW emission of Venus.

Computed tomography findings of gaseous necrosis in epithelial ovarian cancer: a report of three cases.

PubMed

Cronin, Paul; Crosse, Barbara; Lane, Geoff; Spencer, John A

2002-01-01

Necrosis in pathologic specimens of ovarian cancer is well documented; however, computed tomography (CT) evidence of gaseous necrosis in the absence of fistulation with bowel has not yet been described. We report three cases of ovarian adenocarcinoma that on CT showed evidence of gross gaseous necrosis, mimicking a pelvic abscess.

DEPOSITION AND EMISSION OF GASEOUS MERCURY TO AND FROM LAKE MICHIGAN DURING THE LAKE MICHIGAN MASS BALANCE STUDY (JULY, 1994 - OCTOBER, 1995)

EPA Science Inventory

This paper presents measurements of dissolved gaseous mercury (DGM) concentrations in Lake Michigan and the application of a mechanistic approach to estimate deposition and emission fluxes of gaseous mercury (Hg2+ and Hg0) to and from Lake Michigan. Measurements of DGM concentr...

Surface Acoustic Wave Nebulisation Mass Spectrometry for the Fast and Highly Sensitive Characterisation of Synthetic Dyes in Textile Samples

NASA Astrophysics Data System (ADS)

Astefanei, Alina; van Bommel, Maarten; Corthals, Garry L.

2017-10-01

Surface acoustic wave nebulisation (SAWN) mass spectrometry (MS) is a method to generate gaseous ions compatible with direct MS of minute samples at femtomole sensitivity. To perform SAWN, acoustic waves are propagated through a LiNbO3 sampling chip, and are conducted to the liquid sample, which ultimately leads to the generation of a fine mist containing droplets of nanometre to micrometre diameter. Through fission and evaporation, the droplets undergo a phase change from liquid to gaseous analyte ions in a non-destructive manner. We have developed SAWN technology for the characterisation of organic colourants in textiles. It generates electrospray-ionisation-like ions in a non-destructive manner during ionisation, as can be observed by the unmodified chemical structure. The sample size is decreased by tenfold to 1000-fold when compared with currently used liquid chromatography-MS methods, with equal or better sensitivity. This work underscores SAWN-MS as an ideal tool for molecular analysis of art objects as it is non-destructive, is rapid, involves minimally invasive sampling and is more sensitive than current MS-based methods. [Figure not available: see fulltext.

Measurement of 131I activity in air indoor Polish nuclear medical hospital as a tool for an internal dose assessment.

PubMed

Brudecki, K; Szczodry, A; Mróz, T; Kowalska, A; Mietelski, J W

2018-03-01

This paper presents results of 131 I air activity measurements performed within nuclear medical hospitals as a tool for internal dose assessment. The study was conducted at a place of preparation and administration of 131 I ("hot room") and at a nurse station. 131 I activity measurements were performed for 5 and 4 consecutive working days, at the "hot room" and nurse station, respectively. Iodine from the air was collected by a mobile HVS-30 aerosol sampler combined with a gas sampler. Both the gaseous and aerosol fractions were measurement. The activities in the gaseous fraction ranged from (28 ± 1 Bq m -3 ) to (492 ± 4) Bq m -3 . At both sampling sites, the activity of the gaseous iodine fraction trapped on activated charcoal was significantly higher than that of the aerosol fraction captured on Petrianov filter cloth. Based on these results, an attempt has been made to estimate annual inhalation effective doses, which were found to range from 0.47 mSv (nurse female) to 1.3 mSv (technician male). The highest annual inhalation equivalent doses have been found for thyroid as 32, 27, 13, and 11 mSv, respectively, for technician male, technical female, nurse male, and nurse female. The method presented here allows to fill the gaps in internal doses measurements. Moreover, because method has been successful used for many years in radioactive contamination monitoring of air in cases of serious nuclear accidents, it should also be used in nuclear medicine.

A SCR Model Calibration Approach with Spatially Resolved Measurements and NH 3 Storage Distributions

DOE PAGES

Song, Xiaobo; Parker, Gordon G.; Johnson, John H.; ...

2014-11-27

The selective catalytic reduction (SCR) is a technology used for reducing NO x emissions in the heavy-duty diesel (HDD) engine exhaust. In this study, the spatially resolved capillary inlet infrared spectroscopy (Spaci-IR) technique was used to study the gas concentration and NH 3 storage distributions in a SCR catalyst, and to provide data for developing a SCR model to analyze the axial gaseous concentration and axial distributions of NH 3 storage. A two-site SCR model is described for simulating the reaction mechanisms. The model equations and a calculation method was developed using the Spaci-IR measurements to determine the NH 3more » storage capacity and the relationships between certain kinetic parameters of the model. Moreover, a calibration approach was then applied for tuning the kinetic parameters using the spatial gaseous measurements and calculated NH3 storage as a function of axial position instead of inlet and outlet gaseous concentrations of NO, NO 2, and NH 3. The equations and the approach for determining the NH 3 storage capacity of the catalyst and a method of dividing the NH 3 storage capacity between the two storage sites are presented. It was determined that the kinetic parameters of the adsorption and desorption reactions have to follow certain relationships for the model to simulate the experimental data. Finally, the modeling results served as a basis for developing full model calibrations to SCR lab reactor and engine data and state estimator development as described in the references (Song et al. 2013a, b; Surenahalli et al. 2013).« less

Semi-continuous detection of mercury in gases

DOEpatents

Granite, Evan J [Wexford, PA; Pennline, Henry W [Bethel Park, PA

2011-12-06

A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

Method of producing encapsulated thermonuclear fuel particles

DOEpatents

Smith, Warren H.; Taylor, William L.; Turner, Harold L.

1976-01-01

A method of producing a fuel particle is disclosed, which comprises forming hollow spheroids which have a mass number greater than 50, immersing said spheroids while under the presence of pressure and heat in a gaseous atmosphere containing an isotope, such as deuterium and tritium, so as to diffuse the gas into the spheroid and thereafter cooling said spheroids up to about 77.degree. Kelvin to about 4.degree. Kelvin.

Sanitizing radish seeds by simultaneous treatments with gaseous chlorine dioxide, high relative humidity, and mild heat.

PubMed

Bang, Jihyun; Choi, Moonhak; Son, Hyeri; Beuchat, Larry R; Kim, Yoonsook; Kim, Hoikyung; Ryu, Jee-Hoon

2016-11-21

Sanitizing radish seeds intended for edible sprout production was achieved by applying simultaneous treatments with gaseous chlorine dioxide (ClO 2 ), high relative humidity (RH, 100%), and mild heat (55°C). Gaseous ClO 2 was produced from aqueous ClO 2 (0.66ml) by mixing sulfuric acid (5% w/v) with sodium chlorite (10 mg/mL) in a sealed container (1.8L). Greater amounts of gaseous ClO 2 were measured at 23% RH (144ppm after 6h) than at 100% RH (66ppm after 6h); however, the lethal activity of gaseous ClO 2 against naturally occurring mesophilic aerobic bacteria (MAB) on radish seeds was significantly enhanced at 100% RH. For example, when exposed to gaseous ClO 2 at 23% RH, the number of MAB on radish seeds decreased from 3.7logCFU/g to 2.6logCFU/g after 6h. However, when exposed to gaseous ClO 2 at 100% RH for 6h, the MAB population decreased to 0.7logCFU/g after 6h. Gaseous ClO 2 was produced in higher amounts at 55°C than at 25°C, but decreased more rapidly over time at 55°C than at 25°C. The lethal activity of gaseous ClO 2 against MAB on radish seeds was greater at 55°C than at 25°C. When radish seeds were treated with gaseous ClO 2 (peak concentration: 195ppm) at 100% RH and 55°C, MAB were reduced to populations below the detectable level (<-0.7logCFU/g) within 2h without decreasing the seed germination rate (97.7%). The lethality of combined treatments against artificially inoculated Escherichia coli O157:H7 was also evaluated. When exposed to gaseous ClO 2 at 100% RH and 55°C for 6h, the initial number of E. coli O157:H7 (3.5logCFU/g) on radish seeds decreased to below the detection limit (0.7logCFU/g) by direct plating but it was not eliminated from seeds. The germination rate of radish seeds was not significantly (P>0.05) decreased after treatment for 6h. The information reported here will be useful when developing decontamination strategies for producing microbiologically safe radish seed sprouts. Copyright © 2016. Published by Elsevier B.V.

Investigation of the role of the calvin cycle and C1 metabolism during HCHO metabolism in gaseous HCHO-treated petunia under light and dark conditions using 13C-NMR.

PubMed

Sun, Huiqun; Zhang, Wei; Tang, Lijuan; Han, Shuang; Wang, Xinjia; Zhou, Shengen; Li, Kunzhi; Chen, Limei

2015-01-01

It has been shown that formaldehyde (HCHO) absorbed by plants can be assimilated through the Calvin cycle or C1 metabolism. Our previous study indicated that Petunia hybrida could effectively eliminate HCHO from HCHO-polluted air. To understand the roles of C1 metabolism and the Calvin cycle during HCHO metabolism and detoxification in petunia plants treated with gaseous H(13)CHO under light and dark conditions. Aseptically grown petunia plants were treated with gaseous H(13)CHO under dark and light conditions. The metabolites generated from HCHO detoxification in petunia were investigated using (13)C-NMR. [2-(13)C]glycine (Gly) was generated via C1 metabolism and [U-(13)C]glucose (Gluc) was produced through the Calvin cycle simultaneously in petunia treated with low-level gaseous H(13)CHO under light conditions. Generation of [2-(13)C]Gly decreased whereas [U-(13) C]Gluc and [U-(13)C]fructose (Fruc) production increased greatly under high-level gaseous H(13)CHO stress in the light. In contrast, [U-(13)C]Gluc and [U-(13)C] Fruc production decreased greatly and [2-(13)C]Gly generation increased significantly under low-level and high-level gaseous H(13)CHO stress in the dark. C1 metabolism and the Calvin cycle contributed differently to HCHO metabolism and detoxification in gaseous H(13CHO-treated petunia plants. As the level of gaseous HCHO increased, the role of C1 metabolism decreased and the role of the Calvin cycle increased under light conditions. However, opposite changes were observed in petunia plants under dark conditions. Copyright © 2015 John Wiley & Sons, Ltd.

Injury and Disability: Identification and Reduction

DTIC Science & Technology

2009-09-01

Biomechanics Branch September 2009 Final Report for October 2005 to August 2009 DESTRUCTION NOTICE – Destroy by any method that will prevent...Division Biomechanics Branch Wright-Patterson AFB OH 45433 Approved for public release, distribution unlimited. NOTICE AND SIGNATURE PAGE...Chief Biomechanics Branch Biosciences and Protection Division Human Effectiveness Directorate 711 th

The Modelling of Reasoning and Justification Methods in the Teaching of Fraction Division at Year 4 Level in Vietnam

ERIC Educational Resources Information Center

Norton, Stephen; Thao, Do Thi Phurong; Duy, Mai The

2014-01-01

Stephen Norton, Do Thi Phurong Thao and Mai The Duy provide an interesting insight into the teaching of fraction division in Vietnam. The article highlights one of the many teaching strategies available to teachers for building fraction concepts.

Apparatus and method for constant flow oxidizing of organic materials

DOEpatents

Surma, Jeffrey E.; Nelson, Norvell; Steward, G. Anthony; Bryan, Garry H.

1999-01-01

The invention is a method and apparatus using high cerium concentration in the anolyte of an electrochemical cell to oxidize organic materials. The method and apparatus further use an ultrasonic mixer to enhance the oxidation rate of the organic material in the electrochemical cell. A reaction vessel provides an advantage of independent reaction temperature control and electrochemical cell temperature control. A separate or independent reaction vessel may be used without an ultrasonic mixer to oxidize gaseous phase organic materials.

Specialized physiological studies in support of manned space flight

NASA Technical Reports Server (NTRS)

Luft, U. C.

1973-01-01

The areas of physiological research reported include: (1) evaluation of the single-breath method for determining cardiac output, (2) optimum protocol for the assessment of cardio-pulmonary competence, (3) body fluids and electrolytes under conditions of single and combined stress, (4) re-evaluation of the open-circuit method for measuring metabolic rate with regard to the alleged metabolic production of gaseous nitrogen, and (5) the use of the forced-oscillation method to determine total respiratory conductance in healthy subjects and pulmonary patients.

Methods and compositions for removing carbon dioxide from a gaseous mixture

DOEpatents

Li, Jing; Wu, Haohan

2014-06-24

Provided is a method for adsorbing or separating carbon dioxide from a mixture of gases by passing the gas mixture through a porous three-dimensional polymeric coordination compound having a plurality of layers of two-dimensional arrays of repeating structural units, which results in a lower carbon dioxide content in the gas mixture. Thus, this invention provides useful compositions and methods for removal of greenhouse gases, in particular CO.sub.2, from industrial flue gases or from the atmosphere.

Methods for pretreating biomass

DOEpatents

Balan, Venkatesh; Dale, Bruce E; Chundawat, Shishir; Sousa, Leonardo

2017-05-09

A method for pretreating biomass is provided, which includes, in a reactor, allowing gaseous ammonia to condense on the biomass and react with water present in the biomass to produce pretreated biomass, wherein reactivity of polysaccharides in the biomass is increased during subsequent biological conversion as compared to the reactivity of polysaccharides in biomass which has not been pretreated. A method for pretreating biomass with a liquid ammonia and recovering the liquid ammonia is also provided. Related systems which include a biochemical or biofuel production facility are also disclosed.

Efficacy of Gaseous Ozone Application during Vacuum Cooling against Escherichia coli O157:H7 on Spinach Leaves as Influenced by Bacterium Population Size.

PubMed

Yesil, Mustafa; Kasler, David R; Huang, En; Yousef, Ahmed E

2017-07-01

Foodborne disease outbreaks associated with the consumption of fresh produce pose a threat to public health, decrease consumer confidence in minimally processed foods, and negatively impact the sales of these commodities. The aim of the study was to determine the influence of population size of inoculated pathogen on its inactivation by gaseous ozone treatment during vacuum cooling. Spinach leaves were spot inoculated with Escherichia coli O157:H7 at approximate initial populations of 10 8 , 10 7 , and 10 5 CFU/g. Inoculated leaves were vacuum cooled (28.5 inHg; 4°C) in a custom-made vessel and then were subjected to a gaseous ozone treatment under the following conditions: 1.5 g of ozone per kg of gas mixture, vessel pressure at 10 lb/in 2 gauge, 94 to 98% relative humidity, and 30 min of holding time at 9°C. Treatment of the leaves, having the aforementioned inocula, decreased E. coli populations by 0.2, 2.1, and 2.8 log CFU/g, respectively, compared with the inoculated untreated controls. Additionally, spinach leaves were inoculated at 1.4 × 10 3 CFU/g, which approximates natural contamination level, and the small populations remaining after ozone treatment were quantified using the most-probable-number (MPN) method. Vacuum and ozone sequential treatment decreased this E. coli O157:H7 population to <3 MPN/g (i.e., greater than 3-log reduction). Resulting log reductions were greater (P < 0.05) at the lower rather than the higher inoculum levels. In conclusion, treatment of spinach leaves with gaseous ozone is effective against pathogen loads comparable to those found in naturally contaminated fresh produce, but efficacy decreases as inoculum level increases.

Effects of Coarse Particulate Matter on Emergency Hospital Admissions for Respiratory Diseases: A Time-Series Analysis in Hong Kong

PubMed Central

Qiu, Hong; Tian, Linwei; Wang, Xiaorong; Tse, Lap Ah; Tam, Wilson; Wong, Tze Wai

2012-01-01

Background: Many epidemiological studies have linked daily counts of hospital admissions to particulate matter (PM) with an aerodynamic diameter ≤ 10 μm (PM10) and ≤ 2.5 μm (PM2.5), but relatively few have investigated the relationship of hospital admissions with coarse PM (PMc; 2.5–10 μm aerodynamic diameter). Objectives: We conducted this study to estimate the health effects of PMc on emergency hospital admissions for respiratory diseases in Hong Kong after controlling for PM2.5 and gaseous pollutants. Methods: We conducted a time-series analysis of associations between daily emergency hospital admissions for respiratory diseases in Hong Kong from January 2000 to December 2005 and daily PM2.5 and PMc concentrations. We estimated PMc concentrations by subtracting PM2.5 from PM10 measurements. We used generalized additive models to examine the relationship between PMc (single- and multiday lagged exposures) and hospital admissions adjusted for time trends, weather conditions, influenza outbreaks, PM2.5, and gaseous pollutants (nitrogen dioxide, sulfur dioxide, and ozone). Results: A 10.9-μg/m3 (interquartile range) increase in the 4-day moving average concentration of PMc was associated with a 1.94% (95% confidence interval: 1.24%, 2.64%) increase in emergency hospital admissions for respiratory diseases that was attenuated but still significant after controlling for PM2.5. Adjusting for gaseous pollutants and altering models assumptions had little influence on PMc effect estimates. Conclusion: PMc was associated with emergency hospital admissions for respiratory diseases in Hong Kong independent of PM2.5 and gaseous pollutants. Further research is needed to evaluate health effects of different components of PMc. PMID:22266709

Comparison of the effects of formaldehyde and gaseous ozone on HBV-contaminated hospital quilts

PubMed Central

Guo, Dan; Li, Ziqiong; Jia, Bei; Che, Xiaoqiong; Song, Tianshuang; Huang, Wenxiang

2015-01-01

Background: Besides being highly infectious, Hepatitis B virus (HBV) is a major cause of liver disease worldwide. In hospital settings, it is easy for the environment and quilts to be contaminated by HBV patient blood and body fluids. Therefore, HBV can be transmitted to other patients via contaminated environmental surfaces or quilts, resulting in an HBV nosocomial infection. Formaldehyde and ozone are commonly used disinfectants that may influence this infectious situation. Objective: To investigate the clinical effectiveness of formaldehyde and gaseous ozone for the terminal cleaning of hospital quilts contaminated by HBV. Methods: Thin cloth and thick cotton soaked with the serum from high HBV copy number patients were prepared and disinfected using formaldehyde fumigation and gaseous ozone at different times. The copy numbers of HBV DNA in the HBV-contaminated cloth and cotton samples were measured quantitatively with fluorescent quantitative polymerase chain reaction (PCR). Results: When gaseous ozone was used to disinfect HBV-contaminated quilts for 23 minutes (min), 36 min, 49 min, and 90 min, the HBV DNA copy number displayed no significant decrease compared with the copy number before disinfection (P > 0.05). In comparison, the copy number of the HBV DNA in the cloth group decreased significantly (P < 0.05) after formaldehyde fumigation disinfection for 1 hour (h), and there was no difference when longer times and increased concentrations were used. In the thick cotton group, there was also a significant decrease (P < 0.05) of the HBV DNA copy numbers, but the decrease was not as dramatic. In addition, in this group, the disinfection effect observed at 4 h was the strongest. Conclusions: The application of ozone to disinfect HBV-contaminated hospital quilts possibly has no effect, whereas, formaldehyde oxide fumigation effectively reduced HBV copy numbers. PMID:26770591

Chemical Composition, Modulatory Bacterial Resistance and Antimicrobial Activity of Essential Oil the Hyptis martiusii Benth by Direct and Gaseous Contact

PubMed Central

de Oliveira, Allan Demetrius Leite; Galvao Rodrigue, Fabiola Fernandes; Douglas Melo Coutinho, Henrique; da Costa, Jose Galberto Martins; de Menezes, Irwin Rose Alencar

2014-01-01

Background: Several studies have shown that species of the genus Hyptis, have promising antimicrobial and antifungal effects. Objectives: Identify of chemical constituents of essential oil from leaves of Hyptis martiusii and evaluate its effect against bacterial strains by direct and gaseous contact. Materials and Methods: Essential oil was extracted from leaves of Hyptis martiusii Benth using hydro-distillation, and its composition was determined using gas chromatography–mass spectrometry (GC-MS). Chemical analysis showed that there was a predominance of sesquiterpenes. The leaf essential oil was screened for its minimal inhibitory concentration and modulatory effect of aminoglycoside by the direct (MIC) and gaseous (MID) micro-dilution assays for various pathogenic microorganisms. The essential oil remarkably inhibited the growth of all of the tested bacteria (MIC < 512 μg/mL) except S. aureus (SA358) multidrug resistant (MRSA) by direct contact. Results: Twenty-four compounds representing 92.13% of the essential oil of leaves were characterized; δ -3-carene (6.88%), 1, 8-cineole (7.01%), trans-caryophyllene (9.21%), Cariophyllene oxide (7.47%) and bicyclogermacrene (10.61%) were found as the major components. Modulatory aminoglycoside effect, by direct contact, was showed antagonistic relationship with antimicrobial activity. The gaseous component of the oil inhibited the bacterial growth of all of the tested bacteria in 50% and 25% of oil concentration and demonstrated synergistic interactions can be attributed to the constituting the oil compounds. Conclusions: These results show that this oil influences the activity of the antibiotic and may be used as an adjuvant in the antibiotic therapy of respiratory tract bacterial pathogens. PMID:25237640

Reductant injection and mixing system

DOEpatents

Reeves, Matt; Henry, Cary A.; Ruth, Michael J.

2016-02-16

A gaseous reductant injection and mixing system is described herein. The system includes an injector for injecting a gaseous reductant into an exhaust gas stream, and a mixer attached to a surface of the injector. The injector includes a plurality of apertures through which the gaseous reductant is injected into an exhaust gas stream. The mixer includes a plurality of fluid deflecting elements.

Combination free electron and gaseous laser

DOEpatents

Brau, Charles A.; Rockwood, Stephen D.; Stein, William E.

1980-01-01

A multiple laser having one or more gaseous laser stages and one or more free electron stages. Each of the free electron laser stages is sequentially pumped by a microwave linear accelerator. Subsequently, the electron beam is directed through a gaseous laser, in the preferred embodiment, and in an alternative embodiment, through a microwave accelerator to lower the energy level of the electron beam to pump one or more gaseous lasers. The combination laser provides high pulse repetition frequencies, on the order of 1 kHz or greater, high power capability, high efficiency, and tunability in the synchronous production of multiple beams of coherent optical radiation.

Experimental and simulation study of a Gaseous oxygen/Gaseous hydrogen vortex cooling thrust chamber

NASA Astrophysics Data System (ADS)

Yu, Nanjia; Zhao, Bo; Li, Gongnan; Wang, Jue

2016-01-01

In this paper, RNG k-ε turbulence model and PDF non-premixed combustion model are used to simulate the influence of the diameter of the ring of hydrogen injectors and oxidizer-to-fuel ratio on the specific impulse of the vortex cooling thrust chamber. The simulation results and the experimental tests of a 2000 N Gaseous oxygen/Gaseous hydrogen vortex cooling thrust chamber reveal that the efficiency of the specific impulse improves significantly with increasing of the diameter of the ring of hydrogen injectors. Moreover, the optimum efficiency of the specific impulse is obtained when the oxidizer-to-fuel ratio is near the stoichiometric ratio.

Gaseous insulators for high voltage electrical equipment

DOEpatents

Christophorou, Loucas G.; James, David R.; Pace, Marshall O.; Pai, Robert Y.

1979-01-01

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Gaseous insulators for high voltage electrical equipment

DOEpatents

Christophorou, Loucas G.; James, David R.; Pace, Marshall O.; Pai, Robert Y.

1981-01-01

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

The Gaseous Phase as a Probe of the Astrophysical Solid Phase Chemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abou Mrad, Ninette; Duvernay, Fabrice; Isnard, Robin

2017-09-10

In support of space missions and spectroscopic observations, laboratory experiments on ice analogs enable a better understanding of organic matter formation and evolution in astrophysical environments. Herein, we report the monitoring of the gaseous phase of processed astrophysical ice analogs to determine if the gaseous phase can elucidate the chemical mechanisms and dominant reaction pathways occurring in the solid ice subjected to vacuum ultra-violet (VUV) irradiation at low temperature and subsequently warmed. Simple (CH{sub 3}OH), binary (H{sub 2}O:CH{sub 3}OH, CH{sub 3}OH:NH{sub 3}), and ternary ice analogs (H{sub 2}O:CH{sub 3}OH:NH{sub 3}) were VUV-processed and warmed. The evolution of volatile organic compoundsmore » in the gaseous phase shows a direct link between their relative abundances in the gaseous phase, and the radical and thermal chemistries modifying the initial ice composition. The correlation between the gaseous and solid phases may play a crucial role in deciphering the organic composition of astrophysical objects. As an example, possible solid compositions of the comet Lovejoy are suggested using the abundances of organics in its comae.« less

Seasonal trends in vegetation and atmospheric concentrations of PAHs and PBDEs near a sanitary landfill

NASA Astrophysics Data System (ADS)

St-Amand, Annick D.; Mayer, Paul M.; Blais, Jules M.

Spruce needle and atmospheric (gaseous and particulate-bound) concentrations were surveyed near a sanitary landfill from February 2004 to June 2005. The influence of several parameters such as temperature, relative humidity, wind speed and direction, as well as increased domestic heating during the winter was assessed. In general, polybrominated diphenyl ethers (PBDE) and polycyclic aromatic hydrocarbons (PAH) concentrations in spruce needles increased over time and decreased following snowmelt with a minimum coinciding with bud burst of deciduous trees. Atmospheric concentrations of PBDE and PAH, both particulate-bound and gaseous phase, were linked to daily weather events and thus showed more variability than those in spruce needles. Highest PAH concentrations were encountered during the winter, likely reflecting increased emission from heating homes. Pseudo Clausius-Clapeyron plots revealed higher PBDE gaseous concentrations with increasing temperature, but showed no correlation between PAH gaseous concentrations and temperature as this effect was obscured by seasonal emission patterns. Finally, air mass back trajectories and local wind directions revealed that particulate-bound PBDEs, along with both gaseous and particulate-bound PAHs were from local sources, whereas gaseous PBDEs were likely from distant sources.

Lymph Node Metastases and Prognosis in Left Upper Division Non-Small Cell Lung Cancers: The Impact of Interlobar Lymph Node Metastasis

PubMed Central

Kuroda, Hiroaki; Sakao, Yukinori; Mun, Mingyon; Uehara, Hirofumi; Nakao, Masayuki; Matsuura, Yousuke; Mizuno, Tetsuya; Sakakura, Noriaki; Motoi, Noriko; Ishikawa, Yuichi; Yatabe, Yasushi; Nakagawa, Ken; Okumura, Sakae

2015-01-01

Background Left upper division segmentectomy is one of the major pulmonary procedures; however, it is sometimes difficult to completely dissect interlobar lymph nodes. We attempted to clarify the prognostic importance of hilar and mediastinal nodes, especially of interlobar lymph nodes, in patients with primary non-small cell lung cancer (NSCLC) located in the left upper division. Methods We retrospectively studied patients with primary left upper lobe NSCLC undergoing surgical pulmonary resection (at least lobectomy) with radical lymphadenectomy. The representative evaluation of therapeutic value from the lymph node dissection was determined using Sasako’s method. This analysis was calculated by multiplying the frequency of metastasis to the station and the 5-year survival rate of the patients with metastasis to the station. Results We enrolled 417 patients (237 men, 180 women). Tumors were located in the lingular lobe and at the upper division of left upper lobe in 69 and 348 patients, respectively. The pathological nodal statuses were pN0 in 263 patients, pN1 in 70 patients, and pN2 in 84 patients. Lymph nodes #11 and #7 were significantly correlated with differences in node involvement in patients with left upper lobe NSCLC. Among those with left upper division NSCLC, the 5-year overall survival in pN1 was 31.5% for #10, 39.3% for #11, and 50.4% for #12U. The involvement of node #11 was 1.89-fold higher in the anterior segment than that in the apicoposterior segment. The therapeutic index of estimated benefit from lymph node dissection for #11 was 3.38, #4L was 1.93, and the aortopulmonary window was 4.86 in primary left upper division NSCLC. Conclusions Interlobar node involvement is not rare in left upper division NSCLC, occurring in >20% cases. Furthermore, dissection of interlobar nodes was found to be beneficial in patients with left upper division NSCLC. PMID:26247881

An a priori study of different tabulation methods for turbulent pulverised coal combustion

NASA Astrophysics Data System (ADS)

Luo, Yujuan; Wen, Xu; Wang, Haiou; Luo, Kun; Jin, Hanhui; Fan, Jianren

2018-05-01

In many practical pulverised coal combustion systems, different oxidiser streams exist, e.g. the primary- and secondary-air streams in the power plant boilers, which makes the modelling of these systems challenging. In this work, three tabulation methods for modelling pulverised coal combustion are evaluated through an a priori study. Pulverised coal flames stabilised in a three-dimensional turbulent counterflow, consisting of different oxidiser streams, are simulated with detailed chemistry first. Then, the thermo-chemical quantities calculated with different tabulation methods are compared to those from detailed chemistry solutions. The comparison shows that the conventional two-stream flamelet model with a fixed oxidiser temperature cannot predict the flame temperature correctly. The conventional two-stream flamelet model is then modified to set the oxidiser temperature equal to the fuel temperature, both of which are varied in the flamelets. By this means, the variations of oxidiser temperature can be considered. It is found that this modified tabulation method performs very well on prediction of the flame temperature. The third tabulation method is an extended three-stream flamelet model that was initially proposed for gaseous combustion. The results show that the reference gaseous temperature profile can be overall reproduced by the extended three-stream flamelet model. Interestingly, it is found that the predictions of major species mass fractions are not sensitive to the oxidiser temperature boundary conditions for the flamelet equations in the a priori analyses.

Method For Synthesizing Extremely High-Temperature Melting Materials

DOEpatents

Saboungi, Marie-Louise; Glorieux, Benoit

2005-11-22

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Method for synthesizing extremely high-temperature melting materials

DOEpatents

Saboungi, Marie-Louise; Glorieux, Benoit

2007-11-06

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Systems and methods of storing combustion waste products

DOEpatents

Chen, Shen-En; Wang, Peng; Miao, Xiexing; Feng, Qiyan; Zhu, Qianlin

2016-04-12

In one aspect, methods of storing one or more combustion waste products are described herein. Combustion waste products stored by a method described herein can include solid combustion waste products such as coal ash and/or gaseous combustion products such as carbon dioxide. In some embodiments, a method of storing carbon dioxide comprises providing a carbon dioxide storage medium comprising porous concrete having a macroporous and microporous pore structure and flowing carbon dioxide captured from a combustion flue gas source into the pore structure of the porous concrete.

Method for Synthesizing Extremeley High Temperature Melting Materials

DOEpatents

Saboungi, Marie-Louise and Glorieux, Benoit

2005-11-22

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

The microbial killing capacity of aqueous and gaseous ozone on different surfaces contaminated with dairy cattle manure

PubMed Central

Lowe, James

2018-01-01

A high reactivity and leaving no harmful residues make ozone an effective disinfectant for farm hygiene and biosecurity. Our objectives were therefore to (1) characterize the killing capacity of aqueous and gaseous ozone at different operational conditions on dairy cattle manure-based pathogens (MBP) contaminated different surfaces (plastic, metal, nylon, rubber, and wood); (2) determine the effect of microbial load on the killing capacity of aqueous ozone. In a crossover design, 14 strips of each material were randomly assigned into 3 groups, treatment (n = 6), positive-control (n = 6), and negative-control (n = 2). The strips were soaked in dairy cattle manure with an inoculum level of 107–108 for 60 minutes. The treatment strips were exposed to aqueous ozone of 2, 4, and 9 ppm and gaseous ozone of 1and 9 ppm for 2, 4, and 8 minutes exposure. 3M™ Petrifilm™ rapid aerobic count plate and plate reader were used for bacterial culture. On smooth surfaces, plastic and metal, aqueous ozone at 4 ppm reduced MBP to a safe level (≥5-log10) within 2 minutes (6.1 and 5.1-log10, respectively). However, gaseous ozone at 9 ppm for 4 minutes inactivated 3.3-log10 of MBP. Aqueous ozone of 9 ppm is sufficient to reduce MBP to a safe level, 6.0 and 5.4- log10, on nylon and rubber surfaces within 2 and 8 minutes, respectively. On complex surfaces, wood, both aqueous and gaseous ozone at up to 9 ppm were unable to reduce MBP to a safe level (3.6 and 0.8-log10, respectively). The bacterial load was a strong predictor for reduction in MBP (P<0.0001, R2 = 0.72). We conclude that aqueous ozone of 4 and 9 ppm for 2 minutes may provide an efficient method to reduce MBP to a safe level on smooth and moderately rough surfaces, respectively. However, ozone alone may not an adequate means of controlling MBP on complex surfaces. PMID:29758045

In Vitro Toxicity Screening Technique for Volatile Substances ...

EPA Pesticide Factsheets

In 2007 the National Research Council envisioned the need for inexpensive, high throughput, cell based toxicity testing methods relevant to human health. High Throughput Screening (HTS) in vitro screening approaches have addressed these problems by using robotics. However the challenge is that many of these chemicals are volatile and not amenable to HTS robotic liquid handling applications. We assembled an in vitro cell culture apparatus capable of screening volatile chemicals for toxicity with potential for miniaturization for high throughput. BEAS-2B lung cells were grown in an enclosed culture apparatus under air-liquid interface (ALI) conditions, and exposed to an array of xenobiotics in 5% CO2. Use of ALI conditions allows direct contact of cells with a gas xenobiotic, as well as release of endogenous gaseous molecules without interference by medium on the apical surface. To identify potential xenobiotic-induced perturbations in cell homeostasis, we monitored for alterations of endogenously-produced gaseous molecules in air directly above the cells, termed “headspace”. Alterations in specific endogenously-produced gaseous molecules (e.g., signaling molecules nitric oxide (NO) and carbon monoxide (CO) in headspace is indicative of xenobiotic-induced perturbations of specific cellular processes. Additionally, endogenously produced volatile organic compounds (VOCs) may be monitored in a nonspecific, discovery manner to determine whether cell processes are

Experimental investigation on the combustion characteristics of aluminum in air

NASA Astrophysics Data System (ADS)

Feng, Yunchao; Xia, Zhixun; Huang, Liya; Yan, Xiaoting

2016-12-01

With the aim of revealing the detailed process of aluminum combustion in air, this paper reports an experimental study on the combustion of aluminum droplets. In this work, the aluminum wires were exposed and heated by a CO2 laser to produce aluminum droplets, and then these droplets were ignited and burnt in air. The changing processes of aluminum wires, droplets and flames were directly recorded by a high-speed camera, which was equipped with a high magnification zoom lens. Meanwhile, the spectrum distribution of the flame was also registered by an optical spectrometer. Besides, burning residuals were collected and analyzed by the methods of Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometer (EDS). Experimental results show that, during combustion, the aluminum droplet is covered by a spherical vapor-phase flame, and the diameter of this flame is about 1.4 times of the droplet diameter, statistically. In the later stages of combustion, the molten aluminum and condensed oxide products can react to generate gaseous Al and Al2O spontaneously. Little holes are found on the surface of residuals, which are the transport channels of gaseous products, namely the gaseous Al and Al2O. The combustion residuals are consisted by lots of aluminum oxide particles with diameters less than 1 μm.

The effect of pre-treatments to the nickel limonite leaching using dissolved gaseous SO2-air

NASA Astrophysics Data System (ADS)

Wulandari, W.; Soerawidjaja, T. H.; Alifiani, D.; Rangga, D. A.

2018-01-01

Nickel limonite leaching has been subjected to a number of studies, one of the method is by using dissolved gaseous SO2-air. The selectivity of nickel over iron extracted from leaching using dissolved gaseous SO2-air is advantageous, however the nickel that can be recovered is limited. This paper studies pre-treatments that is applied to the nickel ore prior leaching in order to increase the recovery of dissolved nickel from nickel limonite ore. There two pre-treatments that were carried out in this research, roasting and alkali-roasting using Na2CO3. The extraction was carried out for 180 min with pH 2, 3, 4, and 5 and temperature 30, 55, and 80 °C. It is found that the highest yield is achieved at pH 2 and 80 °C with nickel recovery of 61.39%. At pH 2, for alkali-roasting pre-treatment, the nickel yield raised from 28.17% to 100% and for roasting pre-treatment the nickel yield increased from 20.42% to 61.39%. However, at pH 2, the nickel to iron selectivity decreased from 96272 to 534 for roasting pre-treatment and from 1.8 to 1 for alkali-roasting pre-treatment.

Gaseous Air Pollution and the Risk for Stroke Admissions: A Case-Crossover Study in Beijing, China.

PubMed

Huang, Fangfang; Luo, Yanxia; Tan, Peng; Xu, Qin; Tao, Lixin; Guo, Jin; Zhang, Feng; Xie, Xueqin; Guo, Xiuhua

2017-02-14

Background: Though increasing evidence supports association between gaseous air pollution and stroke, it remains unclear whether the effects differ in season, sex and age. The aim of this study was to examine the associations of gaseous air pollution with stroke admissions in Beijing, 2013-2014 in different subgroups. Methods: Case-crossover design and conditional logistic regression were used to perform the analyses. We examined the exposure-response relationship between air pollution and stroke. Stratified analyses were performed in different seasons, sex, and age groups. Results: There were 147,624 stroke admissions during the study period. In the whole study period, percent changes of stroke admissions were 0.82% (95% CI: 0.52% to 1.13%) and 0.73% (95% CI: 0.44% to 1.03%) per 10 μg/m³ increase in the same day conentration of nitrogen dioxide (NO₂) and sulfur dioxide (SO₂). The positive associations were higher in warm seasons and with patients >65 years ( p < 0.05). Contrary effects of carbon monoxide (CO) and ozone on stroke admissions were observed in different seasons. Conclusions: NO₂ and SO₂ were positively associated with stroke admissions, with stronger effects in warm seasons and with patients >65 years. The associations of CO and ozone with stroke admissions differed across seasons.

Atmospheric mercury (Hg) in the Adirondacks: Concentrations and sources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hyun-Deok Choi; Thomas M. Holsen; Philip K. Hopke

2008-08-15

Hourly averaged gaseous elemental Hg (GEM) concentrations and hourly integrated reactive gaseous Hg (RGM), and particulate Hg (HgP) concentrations in the ambient air were measured at Huntington Forest in the Adirondacks, New York from June 2006 to May 2007. The average concentrations of GEM, RGM, and HgP were 1.4 {+-} 0.4 ng m{sup -3}, 1.8 {+-} 2.2 pg m{sup -3}, and 3.2 {+-} 3.7 pg m{sup -3}, respectively. RGM represents <3.5% of total atmospheric Hg or total gaseous Hg (TGM: GEM + RGM) and HgP represents <3.0% of the total atmospheric Hg. The highest mean concentrations of GEM, RGM, andmore » HgP were measured during winter and summer whereas the lowest mean concentrations were measured during spring and fall. Significant diurnal patterns were apparent in warm seasons for all species whereas diurnal patterns were weak in cold seasons. RGM was better correlated with ozone concentration and temperature in both warm than the other species. Potential source contribution function (PSCF) analysis was applied to identify possible Hg sources. This method identified areas in Pennsylvania, West Virginia, Ohio, Kentucky, Texas, Indiana, and Missouri, which coincided well with sources reported in a 2002 U.S. mercury emissions inventory. 51 refs., 7 figs., 1 tab.« less

Numerical Simulation of Self-gravitational Instability of Isothermal Gaseous Slab Under High External Pressure

NASA Astrophysics Data System (ADS)

Miyaji, S.; Umekawa, M.; Matsumoto, R.; Yoshida, T.

1996-05-01

Gaseous slab is formed with shock waves from super novae, collision of interstellar clouds, etc. When the mass in the Jeans scale is more than Jeans mass, the slab fragments into many clumps by gravitational instability. But in high external pressure environment, even the slab which is stable against Jeans mode can fragment(Elmegreen and Elmegreen 1978).This phenomenon results from incompressible mode instability(Lubow and Pringle 1993). These works are by linear analysis. We study numerically this isothermal gaseous slab which is formed by high external pressure and whose thickness is much smaller than its scale height. We assume self-gravitational fluid, and use two dimensional flux split method. Our model size is taken about the scale of linear maximum growth rate wave length and its five times length, which is an example of much longer than the maximum growth rate wave length. When the incompressible mode instability takes place, it becomes clumps. Each mass of the clumps is less than the Jeans mass. Then the clumps approach each other by gravitational interaction to form bigger clumps. In the presentation we will show results of numerical simulation and discuss about the interaction of fragments on star formation or initial mass function.

The role of NaCl in flame chemistry, in the deposition process, and in its reactions with protective oxides as related to hot corrosion

NASA Technical Reports Server (NTRS)

Kohl, F. J.; Stearns, C. A.

1979-01-01

Sodium chloride is believed to be the primary source of turbine engine contamination that contributes to hot corrosion. The behavior of NaCl-containing aerosols ingested with turbine intake air is very complex; some of the NaCl may vaporize during combustion while some may remain as particulates. The NaCl can lead to Na2SO4 formation by several possible routes or it can contribute to corrosion directly. Hydrogen or oxygen atom reaction with NaCl(c) was shown to result in the release of Na(g). Gaseous NaCl in flames can be partially converted to gaseous Na2SO4 by homogeneous reactions. The remaining gaseous NaCl and other Na-containing molecules can act as sodium carriers for condensate deposition of Na2SO4 on cool surfaces. A frozen boundary layer theory was developed to predict the rates of deposition. The condensed phase NaCl can be converted directly to condensed Na2SO4 by reaction with sulfur oxides and O2. Reaction of gaseous NaCl with Cr2O3 results in the vapor phase transport of chromium by the formation of complex Cr-containing gaseous molecules. Similar gaseous complexes are formed with molybdenum. The presence of gaseous NaCl was shown to affect the oxidation kinetics of Ni-Cr alloys. It also causes changes in the surface morphology of Al2O3 scales formed on Al-containing alloys.

Gaseous pollutants from brick kiln industry decreased the growth, photosynthesis, and yield of wheat (Triticum aestivum L.).

PubMed

Adrees, Muhammad; Ibrahim, Muhammad; Shah, Aamir Mehmood; Abbas, Farhat; Saleem, Farhan; Rizwan, Muhammad; Hina, Saadia; Jabeen, Fariha; Ali, Shafaqat

2016-05-01

Gaseous pollutant emissions from brick kiln industries deteriorate the current state of ambient air quality in Pakistan and worldwide. These gaseous pollutants affect the health of plants and may decrease plant growth and yield. A field experiment that was conducted to monitor the concentration of gaseous pollutants emitted mainly from brick kilns in the ambient air and associated impacts on the growth and physiological attributes of the two wheat (Triticum spp.) cultivars. Plants were grown at three sites, including control (Ayub Agriculture Research Institute, AARI), low pollution (LP) site (Small Estate Industry), and high pollution (HP) site (Sidar Bypass), of Faisalabad, Pakistan. Monitoring of ambient air pollution at experimental sites was carried out using the state-of-art ambient air analyzers. Plants were harvested after 120 days of germination and were analyzed for different growth attributes. Results showed that the hourly average concentration of gaseous air pollutants CO, NO2, SO2, and PM10 at HP site were significantly higher than the LP and control sites. Similarly, gaseous pollutants decreased plant height, straw and grain yield, photosynthesis and increased physical injury, and metal concentrations in the grains. However, wheat response toward gaseous pollutants did not differ between cultivars (Galaxy and 8173) studied. Overall, the results indicated that brick kiln emissions could reduce the performance of wheat grown in the soils around kilns and confirm the adverse impacts of pollutants on the growth, yield, and quality of the wheat.

Is it necessary to use the entire root as a donor when transferring contralateral C7 nerve to repair median nerve?

PubMed

Gao, Kai-Ming; Lao, Jie; Guan, Wen-Jie; Hu, Jing-Jing

2018-01-01

If a partial contralateral C 7 nerve is transferred to a recipient injured nerve, results are not satisfactory. However, if an entire contralateral C 7 nerve is used to repair two nerves, both recipient nerves show good recovery. These findings seem contradictory, as the above two methods use the same donor nerve, only the cutting method of the contralateral C 7 nerve is different. To verify whether this can actually result in different repair effects, we divided rats with right total brachial plexus injury into three groups. In the entire root group, the entire contralateral C 7 root was transected and transferred to the median nerve of the affected limb. In the posterior division group, only the posterior division of the contralateral C 7 root was transected and transferred to the median nerve. In the entire root + posterior division group, the entire contralateral C 7 root was transected but only the posterior division was transferred to the median nerve. After neurectomy, the median nerve was repaired on the affected side in the three groups. At 8, 12, and 16 weeks postoperatively, electrophysiological examination showed that maximum amplitude, latency, muscle tetanic contraction force, and muscle fiber cross-sectional area of the flexor digitorum superficialis muscle were significantly better in the entire root and entire root + posterior division groups than in the posterior division group. No significant difference was found between the entire root and entire root + posterior division groups. Counts of myelinated axons in the median nerve were greater in the entire root group than in the entire root + posterior division group, which were greater than the posterior division group. We conclude that for the same recipient nerve, harvesting of the entire contralateral C 7 root achieved significantly better recovery than partial harvesting, even if only part of the entire root was used for transfer. This result indicates that the entire root should be used as a donor when transferring contralateral C 7 nerve.

Is it necessary to use the entire root as a donor when transferring contralateral C7 nerve to repair median nerve?

PubMed Central

Gao, Kai-ming; Lao, Jie; Guan, Wen-jie; Hu, Jing-jing

2018-01-01

If a partial contralateral C7 nerve is transferred to a recipient injured nerve, results are not satisfactory. However, if an entire contralateral C7 nerve is used to repair two nerves, both recipient nerves show good recovery. These findings seem contradictory, as the above two methods use the same donor nerve, only the cutting method of the contralateral C7 nerve is different. To verify whether this can actually result in different repair effects, we divided rats with right total brachial plexus injury into three groups. In the entire root group, the entire contralateral C7 root was transected and transferred to the median nerve of the affected limb. In the posterior division group, only the posterior division of the contralateral C7 root was transected and transferred to the median nerve. In the entire root + posterior division group, the entire contralateral C7 root was transected but only the posterior division was transferred to the median nerve. After neurectomy, the median nerve was repaired on the affected side in the three groups. At 8, 12, and 16 weeks postoperatively, electrophysiological examination showed that maximum amplitude, latency, muscle tetanic contraction force, and muscle fiber cross-sectional area of the flexor digitorum superficialis muscle were significantly better in the entire root and entire root + posterior division groups than in the posterior division group. No significant difference was found between the entire root and entire root + posterior division groups. Counts of myelinated axons in the median nerve were greater in the entire root group than in the entire root + posterior division group, which were greater than the posterior division group. We conclude that for the same recipient nerve, harvesting of the entire contralateral C7 root achieved significantly better recovery than partial harvesting, even if only part of the entire root was used for transfer. This result indicates that the entire root should be used as a donor when transferring contralateral C7 nerve. PMID:29451212

Three-electrode low pressure discharge apparatus and method for uniform ionization of gaseous media. [CO/sub 2/ laser oscillator and pulse smoother

DOEpatents

McLellan, E.J.

1980-10-17

Uniform, transverse electrical discharges are produced in gaseous media without the necessity of switching the main discharge voltage with an external device which carries the entire discharge current. A three-electrode low pressure discharge tube is charged across its anode and cathode to below breakdown voltage using a dc voltage source. An array of resistors or capacitors can be made to discharge to the wire screen anode by means of a low energy high voltage pulse circuit producing sufficient preionization in the region between the anode and cathode to initiate and control the main discharge. The invention has been demonstrated to be useful as a CO/sub 2/ laser oscillator and pulse-smoother. It can be reliably operated in the sealed-off mode.

Regenerable MgO promoted metal oxide oxygen carriers for chemical looping combustion

DOEpatents

Siriwardane, Ranjani V.; Miller, Duane D.

2014-08-19

The disclosure provides an oxygen carrier comprised of a plurality of metal oxide particles in contact with a plurality of MgO promoter particles. The MgO promoter particles increase the reaction rate and oxygen utilization of the metal oxide when contacting with a gaseous hydrocarbon at a temperature greater than about 725.degree. C. The promoted oxide solid is generally comprised of less than about 25 wt. % MgO, and may be prepared by physical mixing, incipient wetness impregnation, or other methods known in the art. The oxygen carrier exhibits a crystalline structure of the metal oxide and a crystalline structure of MgO under XRD crystallography, and retains these crystalline structures over subsequent redox cycles. In an embodiment, the metal oxide is Fe.sub.2O.sub.3, and the gaseous hydrocarbon is comprised of methane.

Apparatus for diffusion separation

DOEpatents

Nierenberg, William A.; Pontius, Rex B.

1976-08-10

1. The method of testing the separation efficiency of porous permeable membranes which comprises causing a stream of a gaseous mixture to flow into contact with one face of a finely porous permeable membrane under such conditions that a major fraction of the mixture diffuses through the membrane, maintaining a rectangular cross section of the gaseous stream so flowing past said membrane, continuously recirculating the gas that diffuses through said membrane and continuously withdrawing the gas that does not diffuse through said membrane and maintaining the volume of said recirculating gas constant by continuously introducing into said continuously recirculating gas stream a mass of gas equivalent to that which is continuously withdrawn from said gas stream and comparing the concentrations of the light component in the entering gas, the withdrawn gas and the recirculated gas in order to determine the efficiency of said membrane.

Cardiovascular preparticipation screening practices of college team physicians.

PubMed

Asplund, Chad A; Asif, Irfan M

2014-07-01

Determine the cardiovascular screening practices of college team physicians. Cross-sectional survey. Electronic mail with a link to a 9-item survey. American Medical Society for Sports Medicine college team physicians. Screening practices survey administered to college team physicians. Cardiovascular preparticipation screening practices including noninvasive cardiac screening (NICS) such as electrocardiogram (ECG) or echocardiogram. Two hundred twenty-four of 613 AMSSM members identifying themselves as college team physicians (36.5%) responded: National Collegiate Athletic Association Division I: 146, Division II: 41, Division III: 27, National Association of Intercollegiate Athletics: 8, and Junior College: 2. The majority (78%) of schools conducted the American Heart Association (AHA) 12-element history and physical examination. Division I institutions were more likely to add an ECG and/or echocardiogram (30%) to their preparticipation examination (PPE) compared with lower divisions (P < 0.0001). Those Division I schools using NICS were more likely to do so for all athletes (P < 0.001) or revenue generating sports (P < 0.001), whereas other institutions did so only for high-risk subgroups (P < 0.01). Lower division schools would consider adding ECG if it cost less (P = 0.01) or if there were more local expertise in athlete-specific interpretation standards (P = 0.04). Many National Collegiate Athletic Association Athletes Division I programs already use NICS to screen athletes, whereas a significant portion of lower division schools add ECG for athletes deemed high risk. Increased use of these modalities suggests limitations of traditional PPE screening methods. This is the first study to assess cardiac screening practices across all collegiate divisions and broadens our understanding of cardiac screening in high-level athletes.

A History of the Acoustics Division of the Naval Research Laboratory: The First Eight Decades 1923 - 2008

DTIC Science & Technology

2013-08-01

Superintendent” goes back to the early days of NRL in the 1920s and has been retained to the present, refer- ring to the director of each NRL research division...installation, energy for the final amplifiers was stored essentially in the fuel tank of a gas- turbine -driven generator. Signifi- cant research in the Sound...Division found a method for control of the gas turbine which permitted it to supply power in long pulses without damage to the turbine . Research on

A Course in Coal Science and Technology.

ERIC Educational Resources Information Center

Wheelock, T. D.

1978-01-01

This course introduces graduate students and advanced undergraduates to coal science and technology. Topics include: (1) the nature and occurrence of coal, (2) its chemical and physical characteristics, (3) methods of cleaning and preparing coal, and (4) processes for converting coal into clean solid, liquid, and gaseous fuels, as well as coke.…

40 CFR Appendix D to Part 61 - Methods for Estimating Radionuclide Emissions

Code of Federal Regulations, 2010 CFR

2010-07-01

... (iii) 10−6 for solids. If any nuclide is heated to a temperature of 100 degrees Celsius or more, boils at a temperature of 100 degrees Celsius or less, or is intentionally dispersed into the environment... Although venturis may remove gases, variability in gaseous removal efficiency dictates adjustment factor...

40 CFR 90.419 - Raw emission sampling calculations-gasoline fueled engines.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw emission sampling calculations... KILOWATTS Gaseous Exhaust Test Procedures § 90.419 Raw emission sampling calculations—gasoline fueled... selected as the basis for mass emission calculations using the raw gas method. ER03JY95.022 Where: WHC...

40 CFR 90.419 - Raw emission sampling calculations-gasoline fueled engines.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw emission sampling calculations... KILOWATTS Gaseous Exhaust Test Procedures § 90.419 Raw emission sampling calculations—gasoline fueled... selected as the basis for mass emission calculations using the raw gas method. ER03JY95.022 Where: WHC...

Spectroscopy-based thrust sensor for high-speed gaseous flows

NASA Technical Reports Server (NTRS)

Hanson, Ronald K. (Inventor)

1993-01-01

A system and method for non-intrusively obtaining the thrust value of combustion by-products of a jet engine is disclosed herein. The system includes laser elements for inducing absorption for use in determining the axial velocity and density of the jet flow stream and elements for calculating the thrust value therefrom.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The first part covers standards for gaseous fuels. The standard part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrographic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

Ventilation of porous media

DOEpatents

Neeper, D.A.

1994-02-22

Methods are presented for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction. 10 figures.

Measurement of particulate matter emission fluxes from a beef cattle feedlot using Flux-gradient technique

USDA-ARS?s Scientific Manuscript database

Data on air emissions from open-lot beef cattle feedlots are limited. This research was conducted to determine PM10 emission fluxes from a commercial beef cattle feedlot in Kansas using the flux-gradient technique, a widely-used micrometeorological method for gaseous emissions from open sources. V...