Theoretical study on the dissociation energies, ionization potentials and electron affinities of three perfluoroalkyl iodides

NASA Astrophysics Data System (ADS)

Cheng, Li; Shen, Zuochun; Lu, Jianye; Gao, Huide; Lü, Zhiwei

2005-11-01

Dissociation energies, ionization potentials and electron affinities of three perfluoroalkyl iodides, CF 3I, C 2F 5I, and i-C 3F 7I are calculated accurately with B3LYP, MP n ( n = 2-4), QCISD, QCISD(T), CCSD, and CCSD(T) methods. Calculations are performed by using large-core correlation-consistent pseudopotential basis set (SDB-aug-cc-pVTZ) for iodine atom. In all energy calculations, the zero point vibration energy is corrected. And the basis set superposition error is corrected by counterpoise method in the calculation of dissociation energy. Theoretical results are compared with the experimental values.

ROPEC - ROtary PErcussive Coring Drill for Mars Sample Return

NASA Technical Reports Server (NTRS)

Chu, Philip; Spring, Justin; Zacny, Kris

2014-01-01

The ROtary Percussive Coring Drill is a light weight, flight-like, five-actuator drilling system prototype designed to acquire core material from rock targets for the purposes of Mars Sample Return. In addition to producing rock cores for sample caching, the ROPEC drill can be integrated with a number of end effectors to perform functions such as rock surface abrasion, dust and debris removal, powder and regolith acquisition, and viewing of potential cores prior to caching. The ROPEC drill and its suite of end effectors have been demonstrated with a five degree of freedom Robotic Arm mounted to a mobility system with a prototype sample cache and bit storage station.

Rolling-Tooth Core Breakoff and Retention Mechanism

NASA Technical Reports Server (NTRS)

Badescu, Mircea; Bickler, Donald B.; Sherrit, Stewart; Bar-Cohen, Yoseph; Bao, Xiaoqi; Hudson, Nicolas H.

2011-01-01

Sampling cores requires the controlled breakoff of the core at a known location with respect to the drill end. An additional problem is designing a mechanism that can be implemented at a small scale that is robust and versatile enough to be used for a variety of core samples. This design consists of a set of tubes (a drill tube and an inner tube) and a rolling element (rolling tooth). An additional tube can be used as a sample tube. The drill tube and the inner tube have longitudinal holes with the axes offset from the axis of each tube. The two eccentricities are equal. The inner tube fits inside the drill tube, and the sample tube fits inside the inner tube. While drilling, the two tubes are positioned relative to each other such that the sample tube is aligned with the drill tube axis and core. The drill tube includes teeth and flutes for cuttings removal. The inner tube includes, at the base, the rolling element implemented as a wheel on a shaft in an eccentric slot. An additional slot in the inner tube and a pin in the drill tube limit the relative motion of the two tubes. While drilling, the drill assembly rotates relative to the core and forces the rolling tooth to stay hidden in the slot along the inner tube wall. When the drilling depth has been reached, the drill bit assembly is rotated in the opposite direction, and the rolling tooth is engaged and penetrates into the core. Depending on the strength of the created core, the rolling tooth can score, lock the inner tube relative to the core, start the eccentric motion of the inner tube, and break the core. The tooth and the relative position of the two tubes can act as a core catcher or core-retention mechanism as well. The design was made to fit the core and hole parameters produced by an existing bit; the parts were fabricated and a series of demonstration tests were performed. This invention is potentially applicable to sample return and in situ missions to planets such as Mars and Venus, to moons such as Titan and Europa, and to comets. It is also applicable to terrestrial applications like forensic sampling and geological sampling in the field.

Drilling report and core logs for the 1981 drilling of Kilauea Iki lava lake, Kilauea volcano, Hawaii, with comparative notes on earlier (1967-1979) drilling experiences

DOE Office of Scientific and Technical Information (OSTI.GOV)

Helz, R.T.; Wright, T.L.

1983-01-01

The purpose is: (1) to describe the 1981 drilling of Kilauea Iki lava lake, (2) to present the logs for the drill core recovered during the 1981 drilling, and (3) to present a summary of some of the field observations made during the 1967, 1975, 1976 and 1979 drillings that are relevant to the crystallization history of Kilauea Iki lava lake. This report supplements logs for the 1967-1979 core presented in Helz et al. (1980). 21 references, 4 figures, 4 tables.

Drilling the Thuringian Syncline, Germany: core processing during the INFLUINS scientific deep drilling campaign

NASA Astrophysics Data System (ADS)

Abratis, Michael; Methe, Pascal; Aehnelt, Michaela; Kunkel, Cindy; Beyer, Daniel; Kukowski, Nina; Totsche, Kai Uwe

2014-05-01

Deep drilling of the central Thuringian Syncline was carried out in order to gather substantial knowledge of subsurface fluid dynamics and fluid rock interaction within a sedimentary basin. The final depth of the borehole was successfully reached at 1179 m, just a few meters above the Buntsandstein - Zechstein boundary. One of the aspects of the scientific drilling was obtaining sample material from different stratigraphic units for insights in genesis, rock properties and fluid-rock interactions. Parts of the section were cored whereas cuttings provide record of the remaining units. Coring was conducted in aquifers and their surrounding aquitards, i.e. parts of the Upper Muschelkalk (Trochitenkalk), the Middle Muschelkalk, the Upper Buntsandstein (Pelitrot and Salinarrot) and the Middle Buntsandstein. In advance and in cooperation with the GFZ Potsdam team "Scientific Drilling" core handling was discussed and a workflow was developed to ensure efficient and appropriate processing of the valuable core material and related data. Core curation including cleaning, fitting, marking, measuring, cutting, boxing, photographing and unrolled scanning using a DMT core scanner was carried out on the drilling site in Erfurt. Due care was exercised on samples for microbiological analyses. These delicate samples were immediately cut when leaving the core tube and stored within a cooling box at -78°C. Special software for data input was used developed by smartcube GmbH. Advantages of this drilling information system (DIS) are the compatibility with formats of international drilling projects from the IODP and ICDP drilling programs and thus options for exchanges with the international data bases. In a following step, the drill cores were brought to the national core repository of the BGR in Berlin Spandau where the cores were logged for their physical rock properties using a GeoTek multi sensor core logger (MSCL). After splitting the cores into a working and archive half, the cores were scanned for compositional variations using an XRF core scanner at the BGR lab and scan images of the slabbed surfaces were performed. The average core recovery rate was very high at nearly 100%. Altogether, we gained 533 m of excellent core material including sandstones, siltstones and claystones, carbonates, sulfates and chlorides. This provides valuable insight into the stratigraphic column of the Thuringian Syncline.

Rapid ice drilling with continual air transport of cuttings and cores: General concept

NASA Astrophysics Data System (ADS)

Wang, Rusheng; An, Liu; Cao, Pinlu; Chen, Baoyi; Sysoev, Mikhail; Fan, Dayou; Talalay, Pavel G.

2017-12-01

This article describes the investigation of the feasibility of rapid drilling in ice sheets and glaciers to depths of up to 600 m, with cuttings and cores continually transported by air reverse circulation. The method employs dual wall drill rods. The inner tubes provide a continuous pathway for the chips and cores from the drill bit face to the surface. To modify air reverse circulation drilling technology according to the conditions of a specific glacier, original cutter drill bits and air processing devices (air-cooled aftercoolers, air receivers, coalescing filters, desiccant dryers) should be used. The airflow velocity for conveying a 60-mm diameter and 200-mm long ice core should not be lower than 22.5 m/s, and the minimal airflow rate for continual chip and cores transport is 6.8 m3/min at 2.3-2.6 MPa. Drilling of a 600-m deep hole can be accomplished within 1.5 days in the case of 24 h drilling operations. However, to avoid sticking while drilling through ice, the drilling depth should to be limited to 540 m at a temperature of -20 °C and to 418 m at a temperature of -10 °C.

Results of NanTroSEIZE Expeditions Stages 1 & 2: Deep-sea Coring Operations on-board the Deep-sea Drilling Vessel Chikyu and Development of Coring Equipment for Stage 3

NASA Astrophysics Data System (ADS)

Shinmoto, Y.; Wada, K.; Miyazaki, E.; Sanada, Y.; Sawada, I.; Yamao, M.

2010-12-01

The Nankai-Trough Seismogenic Zone Experiment (NanTroSEIZE) has carried out several drilling expeditions in the Kumano Basin off the Kii-Peninsula of Japan with the deep-sea scientific drilling vessel Chikyu. Core sampling runs were carried out during the expeditions using an advanced multiple wireline coring system which can continuously core into sections of undersea formations. The core recovery rate with the Rotary Core Barrel (RCB) system was rather low as compared with other methods such as the Hydraulic Piston Coring System (HPCS) and Extended Shoe Coring System (ESCS). Drilling conditions such as hole collapse and sea conditions such as high ship-heave motions need to be analyzed along with differences in lithology, formation hardness, water depth and coring depth in order to develop coring tools, such as the core barrel or core bit, that will yield the highest core recovery and quality. The core bit is especially important in good recovery of high quality cores, however, the PDC cutters were severely damaged during the NanTroSEIZE Stages 1 & 2 expeditions due to severe drilling conditions. In the Stage 1 (riserless coring) the average core recovery was rather low at 38 % with the RCB and many difficulties such as borehole collapse, stick-slip and stuck pipe occurred, causing the damage of several of the PDC cutters. In Stage 2, a new design for the core bit was deployed and core recovery was improved at 67 % for the riserless system and 85 % with the riser. However, due to harsh drilling conditions, the PDC core bit and all of the PDC cutters were completely worn down. Another original core bit was also deployed, however, core recovery performance was low even for plate boundary core samples. This study aims to identify the influence of the RCB system specifically on the recovery rates at each of the holes drilled in the NanTroSEIZE coring expeditions. The drilling parameters such as weight-on-bit, torque, rotary speed and flow rate, etc., were analyzed and conditions such as formation, tools, and sea conditions which directly affect core recovery have been categorized. Also discussed will be the further development of such coring equipment as the core bit and core barrel for the NanTroSEIZE Stage 3 expeditions, which aim to reach a depth of 7000 m-below the sea floor into harder formations under extreme drilling conditions.

Publications - GMC 401 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 401 Publication Details Title: Core photographs, lithologic logs, drilling data, and borehole , 2012, Core photographs, lithologic logs, drilling data, and borehole inventory for the Caribou Dome publication sales page for information on ordering data on DVD. Keywords Core Drilling; Core Logs; Valdez

Design and testing of coring bits on drilling lunar rock simulant

NASA Astrophysics Data System (ADS)

Li, Peng; Jiang, Shengyuan; Tang, Dewei; Xu, Bo; Ma, Chao; Zhang, Hui; Qin, Hongwei; Deng, Zongquan

2017-02-01

Coring bits are widely utilized in the sampling of celestial bodies, and their drilling behaviors directly affect the sampling results and drilling security. This paper introduces a lunar regolith coring bit (LRCB), which is a key component of sampling tools for lunar rock breaking during the lunar soil sampling process. We establish the interaction model between the drill bit and rock at a small cutting depth, and the two main influential parameters (forward and outward rake angles) of LRCB on drilling loads are determined. We perform the parameter screening task of LRCB with the aim to minimize the weight on bit (WOB). We verify the drilling load performances of LRCB after optimization, and the higher penetrations per revolution (PPR) are, the larger drilling loads we gained. Besides, we perform lunar soil drilling simulations to estimate the efficiency on chip conveying and sample coring of LRCB. The results of the simulation and test are basically consistent on coring efficiency, and the chip removal efficiency of LRCB is slightly lower than HIT-H bit from simulation. This work proposes a method for the design of coring bits in subsequent extraterrestrial explorations.

Updated procedures for using drill cores and cuttings at the Lithologic Core Storage Library, Idaho National Laboratory, Idaho

USGS Publications Warehouse

Hodges, Mary K.V.; Davis, Linda C.; Bartholomay, Roy C.

2018-01-30

In 1990, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy Idaho Operations Office, established the Lithologic Core Storage Library at the Idaho National Laboratory (INL). The facility was established to consolidate, catalog, and permanently store nonradioactive drill cores and cuttings from subsurface investigations conducted at the INL, and to provide a location for researchers to examine, sample, and test these materials.The facility is open by appointment to researchers for examination, sampling, and testing of cores and cuttings. This report describes the facility and cores and cuttings stored at the facility. Descriptions of cores and cuttings include the corehole names, corehole locations, and depth intervals available.Most cores and cuttings stored at the facility were drilled at or near the INL, on the eastern Snake River Plain; however, two cores drilled on the western Snake River Plain are stored for comparative studies. Basalt, rhyolite, sedimentary interbeds, and surficial sediments compose most cores and cuttings, most of which are continuous from land surface to their total depth. The deepest continuously drilled core stored at the facility was drilled to 5,000 feet below land surface. This report describes procedures and researchers' responsibilities for access to the facility and for examination, sampling, and return of materials.

Scoring Dawg Core Breakoff and Retention Mechanism

NASA Technical Reports Server (NTRS)

Badescu, Mircea; Sherrit, Stewart; Bar-Cohen, Yoseph; Bao, Xiaoqi; Backes, Paul G.

2011-01-01

This novel core break-off and retention mechanism consists of a scoring dawg controlled by a set of two tubes (a drill tube and an inner tube). The drill tube and the inner tube have longitudinal concentric holes. The solution can be implemented in an eccentric tube configuration as well where the tubes have eccentric longitudinal holes. The inner tube presents at the bottom two control surfaces for controlling the orientation of the scoring dawg. The drill tube presents a sunk-in profile on the inside of the wall for housing the scoring dawg. The inner tube rotation relative to the drill tube actively controls the orientation of the scoring dawg and hence its penetration and retrieval from the core. The scoring dawg presents a shaft, two axially spaced arms, and a tooth. The two arms slide on the control surfaces of the inner tube. The tooth, when rotated, can penetrate or be extracted from the core. During drilling, the two tubes move together maintaining the scoring dawg completely outside the core. After the desired drilling depth has been reached the inner tube is rotated relative to the drill tube such that the tooth of the scoring dawg moves toward the central axis. By rotating the drill tube, the scoring dawg can score the core and so reduce its cross sectional area. The scoring dawg can also act as a stress concentrator for breaking the core in torsion or tension. After breaking the core, the scoring dawg can act as a core retention mechanism. For scoring, it requires the core to be attached to the rock. If the core is broken, the dawg can be used as a retention mechanism. The scoring dawg requires a hard-tip insert like tungsten carbide for scoring hard rocks. The relative rotation of the two tubes can be controlled manually or by an additional actuator. In the implemented design solution the bit rotation for scoring was in the same direction as the drilling. The device was tested for limestone cores and basalt cores. The torque required for breaking the 10-mm diameter limestone cores was 5 to 5.8 lb-in. (0.56 to 0.66 N-m).

Drilling systems for extraterrestrial subsurface exploration.

PubMed

Zacny, K; Bar-Cohen, Y; Brennan, M; Briggs, G; Cooper, G; Davis, K; Dolgin, B; Glaser, D; Glass, B; Gorevan, S; Guerrero, J; McKay, C; Paulsen, G; Stanley, S; Stoker, C

2008-06-01

Drilling consists of 2 processes: breaking the formation with a bit and removing the drilled cuttings. In rotary drilling, rotational speed and weight on bit are used to control drilling, and the optimization of these parameters can markedly improve drilling performance. Although fluids are used for cuttings removal in terrestrial drilling, most planetary drilling systems conduct dry drilling with an auger. Chip removal via water-ice sublimation (when excavating water-ice-bound formations at pressure below the triple point of water) and pneumatic systems are also possible. Pneumatic systems use the gas or vaporization products of a high-density liquid brought from Earth, gas provided by an in situ compressor, or combustion products of a monopropellant. Drill bits can be divided into coring bits, which excavate an annular shaped hole, and full-faced bits. While cylindrical cores are generally superior as scientific samples, and coring drills have better performance characteristics, full-faced bits are simpler systems because the handling of a core requires a very complex robotic mechanism. The greatest constraints to extraterrestrial drilling are (1) the extreme environmental conditions, such as temperature, dust, and pressure; (2) the light-time communications delay, which necessitates highly autonomous systems; and (3) the mission and science constraints, such as mass and power budgets and the types of drilled samples needed for scientific analysis. A classification scheme based on drilling depth is proposed. Each of the 4 depth categories (surface drills, 1-meter class drills, 10-meter class drills, and deep drills) has distinct technological profiles and scientific ramifications.

Theoretical spectroscopic characterization at low temperatures of detectable sulfur-organic compounds: Ethyl mercaptan and dimethyl sulfide

NASA Astrophysics Data System (ADS)

Senent, M. L.; Puzzarini, C.; Domínguez-Gómez, R.; Carvajal, M.; Hochlaf, M.

2014-03-01

Highly correlated ab initio methods are used for the spectroscopic characterization of ethyl mercaptan (CH3CH232SH, ETSH) and dimethyl sulfide (CH332SCH3, DMS), considering them on the vibrational ground and excited torsional states. Since both molecules show non-rigid properties, torsional energy barriers and splittings are provided. Equilibrium geometries and the corresponding rotational constants are calculated by means of a composite scheme based on CCSD(T) calculations that accounts for the extrapolation to the complete basis set limit and core-correlation effects. The ground and excited states rotational constants are then determined using vibrational corrections obtained from CCSD/cc-pVTZ force-field calculations, which are also employed to determine anharmonic frequencies for all vibrational modes. CCSD(T) and CCSD force fields are employed to predict quartic and sextic centrifugal-distortion constants, respectively. Equilibrium rotational constants are also calculated using CCSD(T)-F12. The full-dimensional anharmonic analysis does not predict displacements of the lowest torsional excited states due to Fermi resonances with the remaining vibrational modes. Thus, very accurate torsional transitions are calculated by solving variationally two-dimensional Hamiltonians depending on the CH3 and SH torsional coordinates of ethyl mercaptan or on the two methyl groups torsions of dimethyl-sulfide. For this purpose, vibrationally corrected potential energy surfaces are computed at the CCSD(T)/aug-cc-pVTZ level of theory. For ethyl mercaptan, calculations show large differences between the gauche (g) and trans (t) conformer spectral features. Interactions between rotating groups are responsible for the displacements of the g-bands with respect to the t-bands that cannot therefore be described with one-dimensional models. For DMS, the CCSD(T) potential energy surface has been semi-empirically adjusted to reproduce experimental data. New assignments are suggested for the methyl torsion bands of ETSH and a reassignment is proposed for the infrared bands of DMS (0 3 → 0 4 and 1 0 → 1 1). Our accurate spectroscopic data should be useful for the analysis of the microwave and far infrared spectra of ETSH and DMS recorded, at low temperatures, either in laboratory or in the interstellar medium.

Recent Developments and Adaptations in Diamond Wireline Core Drilling Technology

NASA Astrophysics Data System (ADS)

Thomas, D. M.; Nielson, D. L.; Howell, B. B.; Pardey, M.

2001-05-01

Scientific drilling using diamond wireline technology is presently undergoing a significant expansion and extension of activities that has allowed us to recover geologic samples that have heretofore been technically or financially unattainable. Under the direction and management of DOSECC, a high-capacity hybrid core drilling system was designed and fabricated for the Hawaii Scientific Drilling Project (HSDP) in 1998. This system, the DOSECC Hybrid Coring System (DHCS), has the capacity to recover H-sized core from depths of more than 6 km. In 1999, the DHCS completed the first phase of the HSDP to a depth of 3100 m at a substantially lower cost per foot than any previous scientific borehole to comparable depths and, in the process, established a new depth record for recovery of H-sized wireline core. This system has been offered for use in the Unzen Scientific Drilling Project, the Chicxulub (impact crater) Scientific Drilling Project, and the Geysers Deep Geothermal Reservoir Project. More recently, DOSECC has developed a smaller barge-mounted wireline core drilling system, the GLAD800, that is capable of recovering P-sized sediment core to depths of up to 800 m. The GLAD800 has been successfully deployed on Great Salt Lake and Bear Lake in Utah and is presently being mobilized to Lake Titicaca in South America for an extensive core recovery effort there. The coring capabilities of the GLAD800 system will be available to the global lakes drilling community for acquisition of sediment cores from many of the world's deep lakes for use in calibrating and refining global climate models. Presently under development by DOSECC is a heave-compensation system that will allow us to expand the capabilities of the moderate depth coring system to allow us to collect sediment and bottom core from the shallow marine environment. The design and capabilities of these coring systems will be presented along with a discussion of their potential applications for addressing a range of earth sciences questions.

The Final Phase of Drilling of the Hawaii Scientific Drilling Project

NASA Astrophysics Data System (ADS)

Stolper, E.; Depaolo, D.; Thomas, D.; Garcia, M.; Haskins, E.; Baker, M.

2008-12-01

The principal goal of the Hawaii Scientific Drilling Project (HSDP) was to core continuously deep into the flank of a Hawaiian volcano and to investigate the petrology, geochemisty, geochronology, magnetics, etc. of the recovered samples. Drilling in Hilo, on the island of Hawaii proceeded in three phases. A 1.06 km pilot hole was core-drilled in 1993; a second hole was core-drilled to 3,098 meters below sea level (mbsl) in 1999, then deepened in 2004-2007 to 3,509 mbsl. Although the final phase of drilling was at times technically challenging, core recovery was close to 100%. All rocks from the final phase of drilling were emplaced below sea level and are from the Mauna Kea volcano. On-site core logging identified 45 separate units (the 1999 phase of drilling yielded 345 units). Five lithologies were identified: pillows (~60%); pillow breccias (~10%); massive lavas (~12%); hyaloclastites (~17%); intrusives (~1%; these are mostly multiple thin (down to cm scale) fingers of magma with identical lithologies occurring over narrow depth intervals). The rocks are primarily tholeiitic, ranging from aphyric to highly olivine-phyric lavas (up to ~25% olivine phenocrysts), with considerable fresh glass and olivine; clays and zeolites are present throughout the core. Forty whole-rock samples were collected as a reference suite and sent to multiple investigators for study. Additionally, glass was collected at roughly 3 m intervals for electron microprobe analysis. Although continuous and consistent with the shallower rocks from the previous phase of coring, there are several noteworthy features of the deepest core: (1) Glasses from shallower portions of the core exhibited bimodal silica contents, a low SiO2 group (~48-50 wt.%) and a high SiO2 group (~50.5- 52 wt.%). Glasses from the last phase of drilling are essentially all in the high-silica group and are somewhat more evolved than the high-silica glasses from the shallower portion of the core (5.1-7.6 vs. 5.1-10.4 wt.% MgO). (2) The expected sequence of lithologies with depth in the core is subaerial lava flows, hyaloclastites (formed by debris flows carrying glass and lithic fragments from the shoreline down the submarine flanks of the volcano), and finally pillow lavas. This sequence was generally observed in the earlier phases of drilling, and it appeared that the deepest rocks from the 1999 phase of drilling were essentially all formed from pillow lavas (i.e., there were no more hyaloclastites). However, thick hyaloclastites reflecting long distance transport from the ancient shoreline reappear in the bottom ~100 m of the drill hole. Although it may be coincidence, pillow breccias occur in the shallower parts of the core from the final phase of drilling, but not in the deeper parts in which the hyaloclastites reappear. (3) Intrusive rocks make up a lower fraction (~1%) of samples from the final phase of coring than in the deeper parts of the section from the 1999 phase of drilling (3.8%). It had been suggested that intrusives might become more common the deeper the drilling, but this is not the case at depths down to 3.5 km. (4) There are three units classified as "massive" including one relatively thick (~40 m), featureless (no internal boundaries, no evidence of mixing or internal differentiation), moderately olivine-phyric basalt.

The first microbiological contamination assessment by deep-sea drilling and coring by the D/V Chikyu at the Iheya North hydrothermal field in the Mid-Okinawa Trough (IODP Expedition 331)

PubMed Central

Yanagawa, Katsunori; Nunoura, Takuro; McAllister, Sean M.; Hirai, Miho; Breuker, Anja; Brandt, Leah; House, Christopher H.; Moyer, Craig L.; Birrien, Jean-Louis; Aoike, Kan; Sunamura, Michinari; Urabe, Tetsuro; Mottl, Michael J.; Takai, Ken

2013-01-01

During the Integrated Ocean Drilling Program (IODP) Expedition 331 at the Iheya North hydrothermal system in the Mid-Okinawa Trough by the D/V Chikyu, we conducted microbiological contamination tests of the drilling and coring operations. The contamination from the drilling mud fluids was assessed using both perfluorocarbon tracers (PFT) and fluorescent microsphere beads. PFT infiltration was detected from the periphery of almost all whole round cores (WRCs). By contrast, fluorescent microspheres were not detected in hydrothermally active core samples, possibly due to thermal decomposition of the microspheres under high-temperature conditions. Microbial contamination from drilling mud fluids to the core interior subsamples was further characterized by molecular-based evaluation. The microbial 16S rRNA gene phylotype compositions in the drilling mud fluids were mainly composed of sequences of Beta- and Gammaproteobacteria, and Bacteroidetes and not archaeal sequences. The phylotypes that displayed more than 97% similarity to the sequences obtained from the drilling mud fluids were defined as possible contaminants in this study and were detected as minor components of the bacterial phylotype compositions in 13 of 37 core samples. The degree of microbiological contamination was consistent with that determined by the PFT and/or microsphere assessments. This study suggests a constructive approach for evaluation and eliminating microbial contamination during riser-less drilling and coring operations by the D/V Chikyu. PMID:24265628

The first microbiological contamination assessment by deep-sea drilling and coring by the D/V Chikyu at the Iheya North hydrothermal field in the Mid-Okinawa Trough (IODP Expedition 331).

PubMed

Yanagawa, Katsunori; Nunoura, Takuro; McAllister, Sean M; Hirai, Miho; Breuker, Anja; Brandt, Leah; House, Christopher H; Moyer, Craig L; Birrien, Jean-Louis; Aoike, Kan; Sunamura, Michinari; Urabe, Tetsuro; Mottl, Michael J; Takai, Ken

2013-01-01

During the Integrated Ocean Drilling Program (IODP) Expedition 331 at the Iheya North hydrothermal system in the Mid-Okinawa Trough by the D/V Chikyu, we conducted microbiological contamination tests of the drilling and coring operations. The contamination from the drilling mud fluids was assessed using both perfluorocarbon tracers (PFT) and fluorescent microsphere beads. PFT infiltration was detected from the periphery of almost all whole round cores (WRCs). By contrast, fluorescent microspheres were not detected in hydrothermally active core samples, possibly due to thermal decomposition of the microspheres under high-temperature conditions. Microbial contamination from drilling mud fluids to the core interior subsamples was further characterized by molecular-based evaluation. The microbial 16S rRNA gene phylotype compositions in the drilling mud fluids were mainly composed of sequences of Beta- and Gammaproteobacteria, and Bacteroidetes and not archaeal sequences. The phylotypes that displayed more than 97% similarity to the sequences obtained from the drilling mud fluids were defined as possible contaminants in this study and were detected as minor components of the bacterial phylotype compositions in 13 of 37 core samples. The degree of microbiological contamination was consistent with that determined by the PFT and/or microsphere assessments. This study suggests a constructive approach for evaluation and eliminating microbial contamination during riser-less drilling and coring operations by the D/V Chikyu.

Application of the CC(P;Q) Hierarchy of Coupled-Cluster Methods to the Beryllium Dimer.

PubMed

Magoulas, Ilias; Bauman, Nicholas P; Shen, Jun; Piecuch, Piotr

2018-02-08

The performance of coupled-cluster approaches with higher-than-doubly excited clusters, including the CCSD(T), CCSD(2) T , CR-CC(2,3), CCSD(TQ), and CR-CC(2,4) corrections to CCSD, the active-space CCSDt, CCSDtq, and CCSDTq methods, and the CC(t;3), CC(t,q;3), CC(t,q;3,4), and CC(q;4) corrections to CCSDt, CCSDtq, and CCSDTq resulting from the CC(P;Q) formalism, in reproducing the CCSDT and CCSDTQ potential energy curves and vibrational term values characterizing Be 2 in its electronic ground state is assessed. The correlation-consistent aug-cc-pVnZ and aug-cc-pCVnZ (n = T and Q) basis sets are employed. Among the CCSD-based corrections, the completely renormalized CR-CC(2,3) and CR-CC(2,4) approaches perform the best. The CC(t;3), CC(t,q;3), CC(t,q;3,4), and CC(q;4) methods, especially CC(t;3) and CC(q;4), outperform other employed approaches in reproducing the CCSDT and CCSDTQ data. Composite schemes combining the all-electron CCSDT calculations extrapolated to the complete basis set limit with the frozen-core CC(q;4) and CCSDTQ computations using the aug-cc-pVTZ basis to account for connected quadruple excitations reproduce the latest experimental vibrational spectrum of Be 2 to within 4-5 cm -1 , when the vibrational spacings are examined, with typical errors being below 1-2 cm -1 . The resulting binding energies and equilibrium bond lengths agree with their experimentally derived counterparts to within ∼10 cm -1 and 0.01 Å.

CT Scans of Cores Metadata, Barrow, Alaska 2015

DOE Data Explorer

Katie McKnight; Tim Kneafsey; Craig Ulrich

2015-03-11

Individual ice cores were collected from Barrow Environmental Observatory in Barrow, Alaska, throughout 2013 and 2014. Cores were drilled along different transects to sample polygonal features (i.e. the trough, center and rim of high, transitional and low center polygons). Most cores were drilled around 1 meter in depth and a few deep cores were drilled around 3 meters in depth. Three-dimensional images of the frozen cores were constructed using a medical X-ray computed tomography (CT) scanner. TIFF files can be uploaded to ImageJ (an open-source imaging software) to examine soil structure and densities within each core.

Logging-while-coring method and apparatus

DOEpatents

Goldberg, David S.; Myers, Gregory J.

2007-11-13

A method and apparatus for downhole coring while receiving logging-while-drilling tool data. The apparatus includes core collar and a retrievable core barrel. The retrievable core barrel receives core from a borehole which is sent to the surface for analysis via wireline and latching tool The core collar includes logging-while-drilling tools for the simultaneous measurement of formation properties during the core excavation process. Examples of logging-while-drilling tools include nuclear sensors, resistivity sensors, gamma ray sensors, and bit resistivity sensors. The disclosed method allows for precise core-log depth calibration and core orientation within a single borehole, and without at pipe trip, providing both time saving and unique scientific advantages.

Logging-while-coring method and apparatus

DOEpatents

Goldberg, David S.; Myers, Gregory J.

2007-01-30

A method and apparatus for downhole coring while receiving logging-while-drilling tool data. The apparatus includes core collar and a retrievable core barrel. The retrievable core barrel receives core from a borehole which is sent to the surface for analysis via wireline and latching tool The core collar includes logging-while-drilling tools for the simultaneous measurement of formation properties during the core excavation process. Examples of logging-while-drilling tools include nuclear sensors, resistivity sensors, gamma ray sensors, and bit resistivity sensors. The disclosed method allows for precise core-log depth calibration and core orientation within a single borehole, and without at pipe trip, providing both time saving and unique scientific advantages.

Can tephra be recognized in Hawaiian drill core, and if so, what can be learned about the explosivity of Hawaiian volcanoes?

NASA Astrophysics Data System (ADS)

Lautze, N. C.; Haskins, E.; Thomas, D. M.

2013-12-01

Nearly 6000 feet of drill core was recently recovered from the Pohakula Training Area (PTA) near the Saddle Road between Mauna Loa and Mauna Kea volcanoes on Hawaii Island. Drilling was funded by the US Army with an objective to find a potable water source; the rock core was logged and archived thanks to funding from the National Science Foundation. Within the first few hundred meters, alluvial outwash from the slopes of Mauna Kea is underlain by post-shield Mauna Kea lavas. Below this depth the core is predominantly pahoehoe and to a lesser extent a'a lavas expected to be from Mauna Kea's shield stage volcanism. During the logging effort, and throughout the core, a number of suspect-pyroclastic deposits were identified (largely based on particle texture). These deposits will be examined in more detail, with results presented here. An effort will be made to determine whether explosive deposits can, in fact, be unequivocally identified in drill core. Two anticipated challenges are differentiating between: scoria and 'clinker' (the latter associated with a'a lava flows), and primary volcanic ash, loess, and glacial sediments. Recognition of explosive deposits in the PTA drill core would lend insight into Mauna Kea's explosive history, and potentially that of other Big Island volcanoes as well. If the characteristics of tephra in Hawaiian drill core can be identified, core from the Hawaiian Scientific Drilling Project (HSDP) and Scientific Observation Holes (SOH-1,2,4) may also be examined.

Hydrothermal alteration in research drill hole Y-3, Lower Geyser Basin, Yellowstone National Park, Wyoming

USGS Publications Warehouse

Bargar, Keith E.; Beeson, Melvin H.

1985-01-01

Y-3, a U.S. Geological Survey research diamond-drill hole in Lower Geyser Basin, Yellowstone National Park, Wyoming, reached a depth of 156.7 m. The recovered drill core consists of 42.2 m of surficial (mostly glacial) sediments and two rhyolite flows (Nez Perce Creek flow and an older, unnamed rhyolite flow) of the Central Plateau Member of the Pleistocene Plateau Rhyolite. Hydrothermal alteration is fairly extensive in most of the drill core. The surficial deposits are largely cemented by silica and zeolite minerals; and the two rhyolite flows are, in part, bleached by thermal water that deposited numerous hydrothermal minerals in cavities and fractures. Hydrothermal minerals containing sodium as a dominant cation (analcime, clinoptilolite, mordenite, Na-smectite, and aegirine) are more abundant than calcium-bearing minerals (calcite, fluorite, Ca-smectite, and pectolite) in the sedimentary section of the drill core. In the volcanic section of drill core Y-3, calcium-rich minerals (dachiardite, laumontite, yugawaralite, calcite, fluorite, Ca-smectite, pectolite, and truscottite) are predominant over sodium-bearing minerals (aegirine, mordenite, and Na-smectite). Hydrothermal minerals that contain significant amounts of potassium (alunite and lepidolite in the sediments and illitesmectite in the rhyolite flows) are found in the two drill-core intervals. Drill core y:.3 also contains hydrothermal silica minerals (opal, [3-cristobalite, chalcedony, and quartz), other clay minerals (allophane, halloysite, kaolinite, and chlorite), gypsum, pyrite, and hematite. The dominance of calcium-bearing hydrothermal minerals in the lower rhyolitic section of the y:.3 drill core appears to be due to loss of calcium, along with potassium, during adiabatic cooling of an ascending boiling water.

Comparative evaluation of the indigenous microbial diversity vs. drilling fluid contaminants in the NEEM Greenland ice core.

PubMed

Miteva, Vanya; Burlingame, Caroline; Sowers, Todd; Brenchley, Jean

2014-08-01

Demonstrating that the detected microbial diversity in nonaseptically drilled deep ice cores is truly indigenous is challenging because of potential contamination with exogenous microbial cells. The NEEM Greenland ice core project provided a first-time opportunity to determine the origin and extent of contamination throughout drilling. We performed multiple parallel cultivation and culture-independent analyses of five decontaminated ice core samples from different depths (100-2051 m), the drilling fluid and its components Estisol and Coasol, and the drilling chips collected during drilling. We created a collection of diverse bacterial and fungal isolates (84 from the drilling fluid and its components, 45 from decontaminated ice, and 66 from drilling chips). Their categorization as contaminants or intrinsic glacial ice microorganisms was based on several criteria, including phylogenetic analyses, genomic fingerprinting, phenotypic characteristics, and presence in drilling fluid, chips, and/or ice. Firmicutes and fungi comprised the dominant group of contaminants among isolates and cloned rRNA genes. Conversely, most Proteobacteria and Actinobacteria originating from the ice were identified as intrinsic. This study provides a database of potential contaminants useful for future studies of NEEM cores and can contribute toward developing standardized protocols for contamination detection and ensuring the authenticity of the microbial diversity in deep glacial ice. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

Lunar deep drill apparatus

NASA Technical Reports Server (NTRS)

Harvey, Jill (Editor)

1989-01-01

A self contained, mobile drilling and coring system was designed to operate on the Lunar surface and be controlled remotely from earth. The system uses SKITTER (Spatial Kinematic Inertial Translatory Tripod Extremity Robot) as its foundation and produces Lunar core samples two meters long and fifty millimeters in diameter. The drill bit used for this is composed of 30 per carat diamonds in a sintered tungsten carbide matrix. To drill up to 50 m depths, the bit assembly will be attached to a drill string made from 2 m rods which will be carried in racks on SKITTER. Rotary power for drilling will be supplied by a Curvo-Synchronous motor. SKITTER is to support this system through a hexagonal shaped structure which will contain the drill motor and the power supply. A micro-coring drill will be used to remove a preliminary sample 5 mm in diameter and 20 mm long from the side of the core. This whole system is to be controlled from earth. This is carried out by a continuously monitoring PLC onboard the drill rig. A touch screen control console allows the operator on earth to monitor the progress of the operation and intervene if necessary.

Chemical stratigraphy of the Apollo 17 deep drill cores 70009-70007

NASA Technical Reports Server (NTRS)

Ehmann, W. D.; Ali, M. Z.

1977-01-01

A description is presented of an analysis of a total of 26 samples from three core segments (70009, 70008, 70007) of the Apollo 17 deep drill string. The deep drill string was taken about 700 m east of the Camelot Crater in the Taurus-Littrow region of the moon. Three core segments have been chemically characterized from the mainly coarse-grained upper portion of the deep drill string. The chemical data suggest that the entire 70007-70009 portion of the deep drill string examined was not deposited as a single unit, but was formed by several events sampling slightly different source materials which may have occurred over a relatively short period of time. According to the data from drill stem 70007, there were at least two phases of deposition. Core segment 70009 is probably derived from somewhat different source material than 70008. It seems to be a very well mixed material.

Neogene deformation in the West Antarctic Rift in the McMurdo Sound region from studies of the ANDRILL and Cape Roberts drill cores

NASA Astrophysics Data System (ADS)

Paulsen, T. S.; Wilson, T. J.; Jarrard, R. D.; Millan, C.; Saddler, D.; Läufer, A.; Pierdominici, S.

2010-12-01

Seismic studies indicate that the West Antarctic rift system records at least two distinct periods of Cenozoic rifting (Paleogene and Neogene) within the western Ross Sea. Natural fracture data from ANDRILL and Cape Roberts drill cores are revealing a picture of the geodynamic patterns associated with these rifting episodes. Kinematic indicators along faults recovered in drill cores document dominant normal faulting, although reverse and strike-slip faults are also present. Ongoing studies of mechanically twinned calcite in veins recovered in the drill cores yield predominantly vertical shortening strains with horizontal extension, consistent with a normal fault regime. In the Cape Roberts Project drill core, faults of inferred Oligocene age document a dominant NNE maximum horizontal stress associated with Paleogene rifting within the Victoria Land Basin. The NNE maximum horizontal stress at Cape Roberts is at an oblique angle to Transantarctic Mountain front, and consistent with previous interpretations invoking Cenozoic dextral transtensional shear along the boundary. In the ANDRILL SMS (AND-2A) drill core, faults and veins presumably associated with Neogene rifting document a dominant NNW to NE faulting of an expanded Lower Miocene section, although subsidiary WNW faulting is also present within the upper sections of oriented core. In the ANDRILL MIS (AND-1B) drill core, natural fractures are consistently present through the core below c. 450 mbsf, the estimated depth of the ‘B-clino’ seismic reflector. This is consistent with the presence of seismically-detectable faults below this horizon, which record the major faulting episode associated with Neogene rifting in the Terror Rift. Sedimentary intrusions and steep veins folded by compaction indicate that deformation occurred prior to complete lithification of the strata, suggesting that deformation was at least in part coeval with deposition. Faults and associated veins intersected in the AND-1B drill core also cut Pliocene and Pleistocene strata, suggesting that deformation has continued to the recent or may perhaps ongoing.

Report on drilling activities in the Thar Desert, Sindh Province, Pakistan

USGS Publications Warehouse

Thomas, Roger E.; Fassett, James E.; Warwick, Peter D.; Wardlaw, Bruce R.; Shah, Abas A.; Khan, Shafique Ahmed; Tagar, Mohammad A.; Memon, Abdul R.; Lashari, Ghulam S.; Khan, Zameer M.; Khan, Muhammad D.; Chandio, Altaf H.; Anwar, Mohammad; Nizamani, Mohammad A.; Ahmad, Mujeeb; Ur-Raman, Mehtab-

1994-01-01

Coal test drilling in the Thar Desert of southeast Pakistan was conducted as part of the Coal Exploration and Assessment Program (COALREAP) involving the United States Agency for International Development (USAID), the Geological Survey of Pakistan (GSP), and the U.S. Geological Survey. Drilling was performed in the Thar Desert, or Great Indian Desert, approximately 175 km northeast of Karachi. Twenty five exploration holes were drilled between January 1992 and May 1994. Drill core was described by geologists of the Pakistan Geological Survey and coal samples were analyzed in both the United States and Pakistan. U.S. Geological Survey geologists offered technical assistance, trained GSP personnel, and managed the drilling program according to an agreement with USAID under the Energy Planning and Development Project.Drilling was performed by the Geological Survey of Pakistan. During drilling, the first 50 m was rotary drilled and cuttings collected every 2 m for examination. Average depth for all coal beds is 214 m with a total average thickness of 10 m of coal per drill hole. Core was described, boxed, and stored at the Geological Survey of Pakistan core library at Sonda, near Hyderabad. Approximately 6,412 m of Paleocene to Eocene rock was drilled of which 3,990 m was cored and 1,113 m was rotary drilled.There was 1,309 m of core loss. Geophysical logging of each drill hole permitted detailed thicknesses of coal to be determined. Analysis of the coal indicated a rank of lignite B with an as-received heating value over 5,000 Btu.This report presents data collected at the drill sites and should be used inconjunction with the published interpretive report (Fassett and Durrani, 1994) and the USGS Open-File Report 94-167, which contains analysis of the coal samples. Tables provide quick reference to numeric data and results. Detailed index maps and specific data, for each drill hole are included. This report covers drill holes TP-5 to TP-31. Drill holes TP-16, 17, 21, 26, 27, and 29 were planned but not drilled due to time restraints and (or) a determination that those drill sites were not needed to effectively delineate the coal deposit. The basic data for drill holes TP-1 through TP-4 are included in SanFilipo and others, 1994 however, some data for these drill holes are included for consistency.

Mechanical Alteration And Contamination Issues In Automated Subsurface Sample Acquisition And Handling

NASA Astrophysics Data System (ADS)

Glass, B. J.; Cannon, H.; Bonaccorsi, R.; Zacny, K.

2006-12-01

The Drilling Automation for Mars Exploration (DAME) project's purpose is to develop and field-test drilling automation and robotics technologies for projected use in missions in the 2011-15 period. DAME includes control of the drilling hardware, and state estimation of both the hardware and the lithography being drilled and the state of the hole. A sister drill was constructed for the Mars Analog Río Tinto Experiment (MARTE) project and demonstrated automated core handling and string changeout in 2005 drilling tests at Rio Tinto, Spain. DAME focused instead on the problem of drill control while actively drilling while not getting stuck. Together, the DAME and MARTE projects demonstrate a fully automated robotic drilling capability, including hands-off drilling, adjustment to different strata and downhole conditions, recovery from drilling faults (binding, choking, etc.), drill string changeouts, core acquisition and removal, and sample handling and conveyance to in-situ instruments. The 2006 top-level goal of DAME drilling in-situ tests was to verify and demonstrate a capability for hands-off automated drilling, at an Arctic Mars-analog site. There were three sets of 2006 test goals, all of which were exceeded during the July 2006 field season. The first was to demonstrate the recognition, while drilling, of at least three of the six known major fault modes for the DAME planetary-prototype drill, and to employ the correct recovery or safing procedure in response. The second set of 2006 goals was to operate for three or more hours autonomously, hands-off. And the third 2006 goal was to exceed 3m depth into the frozen breccia and permafrost with the DAME drill (it had not gone further than 2.2m previously). Five of six faults were detected and corrected, there were 43 hours of hands-off drilling (including a 4 hour sequence with no human presence nearby), and 3.2m was the total depth. And ground truth drilling used small commercial drilling equipment in parallel in order to obtain cores and ice profiles at the drilling site. In the course of DAME drilling automation testing, the drilling-induced temperature gradients and their effects on encountered subsurface permafrost and ice layers were observed while drilling in frozen impact breccia at Haughton Crater. In repeated tests of robotic core removal processing and handling in the MARTE project, including field tests, cross-contamination issues arose between successive cores and samples, and procedures and metrics were developed for minimizing the cross-contamination. The MARTE core processing cross-contamination aspects were tested by analyzing a set of pristine samples (those stratigraphically known) vs. cuttings (loose clays) or artifacts from the robotic drilling (indurated clay layers). MARTE ground truth drilling, in parallel with the automated tests, provided control information on the discontinuity/continuity of the stratigraphic record (i.e., texture, color and structure of loose and consolidated materials).

Scientific Drilling of Impact Craters - Well Logging and Core Analyses Using Magnetic Methods (Invited)

NASA Astrophysics Data System (ADS)

Fucugauchi, J. U.; Perez-Cruz, L. L.; Velasco-Villarreal, M.

2013-12-01

Drilling projects of impact structures provide data on the structure and stratigraphy of target, impact and post-impact lithologies, providing insight on the impact dynamics and cratering. Studies have successfully included magnetic well logging and analyses in core and cuttings, directed to characterize the subsurface stratigraphy and structure at depth. There are 170-180 impact craters documented in the terrestrial record, which is a small proportion compared to expectations derived from what is observed on the Moon, Mars and other bodies of the solar system. Knowledge of the internal 3-D deep structure of craters, critical for understanding impacts and crater formation, can best be studied by geophysics and drilling. On Earth, few craters have yet been investigated by drilling. Craters have been drilled as part of industry surveys and/or academic projects, including notably Chicxulub, Sudbury, Ries, Vredefort, Manson and many other craters. As part of the Continental ICDP program, drilling projects have been conducted on the Chicxulub, Bosumtwi, Chesapeake, Ries and El gygytgyn craters. Inclusion of continuous core recovery expanded the range of paleomagnetic and rock magnetic applications, with direct core laboratory measurements, which are part of the tools available in the ocean and continental drilling programs. Drilling studies are here briefly reviewed, with emphasis on the Chicxulub crater formed by an asteroid impact 66 Ma ago at the Cretaceous/Paleogene boundary. Chicxulub crater has no surface expression, covered by a kilometer of Cenozoic sediments, thus making drilling an essential tool. As part of our studies we have drilled eleven wells with continuous core recovery. Magnetic susceptibility logging, magnetostratigraphic, rock magnetic and fabric studies have been carried out and results used for lateral correlation, dating, formation evaluation, azimuthal core orientation and physical property contrasts. Contributions of magnetic studies on impact age, cratering, target-impactite stratigraphy, ejecta, impact dynamics, hydrothermal alterations and post-impact processes are presented. The challenges and perspectives of drilling studies of impact craters are discussed.

Using DSDP/ODP/IODP core photographs and digital images in the classroom

NASA Astrophysics Data System (ADS)

Pereira, Hélder; Berenguer, Jean-Luc

2017-04-01

Since the late 1960's, several scientific ocean drilling programmes have been uncovering the history of the Earth hidden beneath the seafloor. The adventure began in 1968 with the Deep Sea Drilling Project (DSDP) and its special drill ship, the Glomar Challenger. The next stage was the Ocean Drilling Program (ODP) launched in 1985 with a new drill ship, the JOIDES Resolution. The exploration of the ocean seafloor continued, between 2003 and 2013, through the Integrated Ocean Drilling Program (IODP). During that time, in addition to the JOIDES Resolution, operated by the US, the scientists had at their service the Chikyu, operated by Japan, and Mission-Specific-Platforms, funded and implemented by the European Consortium for Ocean Research Drilling. Currently, scientific ocean drilling continues through the collaboration of scientists from 25 nations within the International Ocean Discovery Program (IODP). Over the last 50 years, the scientific ocean drilling expeditions conducted by these programmes have drilled and cored more than 3500 holes. The numerous sediment and rock samples recovered from the ocean floor have provided important insight on the active biological, chemical, and geological processes that have shaped the Earth over millions of years. During an expedition, once the 9.5-meter long cores arrive from the seafloor, the technicians label and cut them into 1.5-meter sections. Next, the shipboard scientists perform several analysis using non-destructive methods. Afterward, the technicians split the cores into two halves, the "working half", which scientists sample and use aboard the drilling platform, and the "archive half", which is kept in untouched condition after being visually described and photographed with a digital imaging system. The shipboard photographer also takes several close-up pictures of the archive-half core sections. This work presents some examples of how teachers can use DSDP/ODP/IODP core photographs and digital images, available through the Janus and LIMS online databases, to develop inquiry-based learning activities for secondary level students.

A new scientific drilling infrastructure in Sweden

NASA Astrophysics Data System (ADS)

Rosberg, J.-E.; Lorenz, H.

2012-04-01

A new scientific drilling infrastructure is currently under commissioning at Lund University in southern Sweden and is intended primarily for Swedish scientific drilling projects. However, it will be available to the scientific community and even industry when not occupied. The drill rig, a crawler mounted Atlas Copco CT20, was funded by the Swedish Research Council (VR) after an application by the Swedish scientific drilling community under the lead of Prof. Leif Bjelm, Lund University. As a national resource it is, together with support of the Swedish Deep Drilling Program (SDDP) and the Swedish membership in ICDP, part of VR's commitment to scientific drilling. The Atlas Copco CT20 is a top modern, versatile diamond wireline core-drilling rig which can handle P, H and N sizes. It can operate on very small drill sites (500-800 m2) and, thus, leaves a minimal environmental footprint. The crawler makes the rig ideal for operations in remote locations. A total of only 3-4 truckloads is necessary for mobilization of the basic drilling equipment. Main technical specifications are: Depth capacity coring, based on vertical water filled hole: P-size to around 1050 m, hole size 123 mm and core size 85 mm. H-size to around 1600 m, hole size 96 mm and core size 63 mm. N-size to around 2500 m, hole size 76 mm and core size 48 mm. Weight: Complete rig including crawler, wet - 23500 kg Dimensions in (length, width, height) transport position: 11560 x 2500 x 3750 mm. Available in-hole equipment: Complete core retrieval system for PQ, HQ and NQ-sizes, including PHD, HRQ (V-Wall) and NRQ (V-Wall) drill rods covering the maximum drilling depth for each size (see rig depth capacity above). Both dual and triple tube for HQ and NQ-sizes. Casing advancers (PW, HW, NW and BW). Casing PWT, HWT, NW and BW. Bits and reamers. Additional equipment: Mud cleaning and mixing system. MWD-system (Measurements While Drilling). Cementing equipment. Fishing tools (Bowen Spear). Blow Out Preventer (BOP). Deviation tools. Wireline packers. And more.

Agglutinates as recorders of regolith evolution - Application to the Apollo 17 drill core

NASA Technical Reports Server (NTRS)

Laul, J. C.; Smith, M. R.; Papike, J. J.; Simon, S. B.

1984-01-01

Chemical data are reported for agglutinates from 26 depth intervals of the Apollo 17 deep drill core, and the compositions of the agglutinates are compared with those of the soils in which they occur. The agglutinate sequence suggests a scenario in which several closely-spaced depositional events were involved in the formation of the drill core, rather than a continuous accumulation process.

Agglutinates as recorders of regolith evolution - Application to the Apollo 17 drill core

DOE Office of Scientific and Technical Information (OSTI.GOV)

Laul, J.C.; Smith, M.R.

1984-11-15

Chemical data are reported for agglutinates from 26 depth intervals of the Apollo 17 deep drill core, and the compositions of the agglutinates are compared with those of the soils in which they occur. The agglutinate sequence suggests a scenario in which several closely-spaced depositional events were involved in the formation of the drill core, rather than a continuous accumulation process.

Improved diamond coring bits developed for dry and chip-flush drilling

NASA Technical Reports Server (NTRS)

Decker, W. E.; Hampe, W. R.; Hampton, W. H.; Simon, A. B.

1971-01-01

Two rotary diamond bit designs, one operating with a chip-flushing fluid, the second including auger section to remove drilled chips, enhance usefulness of tool for exploratory and industrial core-drilling of hard, abrasive mineral deposits and structural masonry.

Results of core drilling for uranium-bearing lignites in the Bar H area, Slim Buttes, Harding County, South Dakota

USGS Publications Warehouse

Zeller, Howard D.

1953-01-01

Core drilling in the Car H area, Slim Buttes, Harding County, South Dakota, under a contract with the B. H. Mott Drilling Co., Huntington, West Virginia, was resumed June 12, 1952 after a 6-month recess during the winter and was completed July 18, 1952. The drilling was undertaken to obtain information on the distribution and extent of the uranium-bearing lignite beds along the southeast edge of the Bar H area. Eight holes totalling 885 feet were drilled and 52 feet of lignite core submitted for study and analysis. The report includes detailed lithographic descriptions of the lignite cores, Bureau of Mines coal analyses, and the results of 100 chemical analyses for uranium. The drilling showed that the thicker, more persistent lignite beds exposed in the northern part of the Bar H area were removed by erosion prior to the deposition of the overlaying White River formation in the south-eastern part of the area. The beds penetrated by drilling were not of sufficient thickness or uranium content to add to the previously known reserves.

Advantages and limitations of remotely operated sea floor drill rigs

NASA Astrophysics Data System (ADS)

Freudenthal, T.; Smith, D. J.; Wefer, G.

2009-04-01

A variety of research targets in marine sciences including the investigation of gas hydrates, slope stability, alteration of oceanic crust, ore formation and palaeoclimate can be addressed by shallow drilling. However, drill ships are mostly used for deep drillings, both because the effort of building up a drill string from a drill ship to the deep sea floor is tremendous and control on drill bit pressure from a movable platform and a vibrating drill string is poor especially in the upper hundred meters. During the last decade a variety of remotely operated drill rigs have been developed, that are deployed on the sea bed and operated from standard research vessels. These developments include the BMS (Bentic Multicoring System, developed by Williamson and Associates, operated by the Japanese Mining Agency), the PROD (Portable Remotely Operated Drill, developed and operated by Benthic Geotech), the Rockdrill 2 (developed and operated by the British geological Survey) and the MeBo (German abbreviation for sea floor drill rig, developed and operated by Marum, University of Bremen). These drill rigs reach drilling depths between 15 and 100 m. For shallow drillings remotely operated drill rigs are a cost effective alternative to the services of drill ships and have the major advantage that the drilling operations are performed from a stable platform independent of any ship movements due to waves, wind or currents. Sea floor drill rigs can be deployed both in shallow waters and the deep sea. A careful site survey is required before deploying the sea floor drill rig. Slope gradient, small scale topography and soil strength are important factors when planning the deployment. The choice of drill bits and core catcher depend on the expected geology. The required drill tools are stored on one or two magazines on the drill rig. The MeBo is the only remotely operated drill rig world wide that can use wire line coring technique. This method is much faster than conventional drilling. It has the advantage that the drill string stays in the drilled hole during the entire drilling process and prevents the drilled hole from collapsing while the inner core barrels comprising the drilled core sections are hooked up inside the drill string using a wire.

Ejector subassembly for dual wall air drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kolle, J.J.

1996-09-01

The dry drilling system developed for the Yucca Mountain Site Characterization Project incorporates a surface vacuum system to prevent drilling air and cuttings from contaminating the borehole wall during coring operations. As the drilling depth increases, however there is a potential for borehole contamination because of the limited volume of air which can be removed by the vacuum system. A feasibility analysis has shown that an ejector subassembly mounted in the drill string above the core barrel could significantly enhance the depth capacity of the dry drilling system. The ejector subassembly would use a portion of the air supplied tomore » the core bit to maintain a vacuum on the hole bottom. The results of a design study including performance testing of laboratory scale ejector simulator are presented here.« less

Recovery and Lithologic Analysis of Sediment from Hole UT-GOM2-1-H002, Green Canyon 955, Northern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Kinash, N.; Cook, A.; Sawyer, D.; Heber, R.

2017-12-01

In May 2017 the University of Texas led a drilling and pressure coring expedition in the northern Gulf of Mexico, UT-GOM2-01. The holes were located in Green Canyon Block 955, where the Gulf of Mexico Joint Industry Project Leg II identified an approximately 100m thick hydrate-filled course-grained levee unit in 2009. Two separate wells were drilled into this unit: Holes H002 and H005. In Hole H002, a cutting shoe drill bit was used to collect the pressure cores, and only 1 of the 8 cores collected was pressurized during recovery. The core recovery in Hole H002 was generally poor, about 34%, while the only pressurized core had 45% recovery. In Hole H005, a face bit was used during pressure coring where 13 cores were collected and 9 cores remained pressurized. Core recovery in Hole H005 was much higher, at about 75%. The type of bit was not the only difference between the holes, however. Drilling mud was used throughout the drilling and pressure coring of Hole H002, while only seawater was used during the first 80m of pressure cores collected in Hole H005. Herein we focus on lithologic analysis of Hole H002 with the goal of documenting and understanding core recovery in Hole H002 to compare with Hole H005. X-ray Computed Tomography (XCT) images were collected by Geotek on pressurized cores, mostly from Hole H005, and at Ohio State on unpressurized cores, mostly from Hole H002. The XCT images of unpressurized cores show minimal sedimentary structures and layering, unlike the XCT images acquired on the pressurized, hydrate-bearing cores. Only small sections of the unpressurized cores remained intact. The unpressurized cores appear to have two prominent facies: 1) silt that did not retain original sedimentary fabric and often was loose within the core barrel, and 2) dense mud sections with some sedimentary structures and layering present. On the XCT images, drilling mud appears to be concentrated on the sides of cores, but also appears in layers and fractures within intact core sections. On microscope images, the drilling mud also appears to saturate the pores in some silt intervals. Further analysis of the unpressurized cores is planned, including X-ray diffraction, grain size analysis and porosity measurements. These results will be compared to the pressurized cores to understand if further lithologic factors could have affected core recovery.

The Yucca Mountain Project prototype air-coring test, U12g tunnel, Nevada test site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ray, J.M.; Newsom, J.C.

1994-12-01

The Prototype Air-Coring Test was conducted at the Nevada Test Site (NTS) G-Tunnel facility to evaluate standard coring techniques, modified slightly for air circulation, for use in testing at a prospective nuclear waste repository at Yucca Mountain, Nevada. Air-coring technology allows sampling of subsurface lithology with minimal perturbation to ambient characteristic such as that required for exploratory holes near aquifers, environmental applications, and site characterization work. Two horizontal holes were cored, one 50 ft long and the other 150 ft long, in densely welded fractured tuff to simulate the difficult drilling conditions anticipated at Yucca Mountain. Drilling data from sevenmore » holes on three other prototype tests in nonwelded tuff were also collected for comparison. The test was used to establish preliminary standards of performance for drilling and dust collection equipment and to assess procedural efficiencies. The Longyear-38 drill achieved 97% recovery for HQ-size core (-2.5 in.), and the Atlas Copco dust collector (DCT-90) captured 1500 lb of fugitive dust in a mine environment with only minor modifications. Average hole production rates were 6-8 ft per 6-h shift in welded tuff and almost 20 ft per shift on deeper holes in nonwelded tuff. Lexan liners were successfully used to encapsulate core samples during the coring process and protect core properties effectively. The Prototype Air-Coring Test demonstrated that horizontal air coring in fractured welded tuff (to at least 150 ft) can be safely accomplished by proper selection, integration, and minor modification of standard drilling equipment, using appropriate procedures and engineering controls. The test also indicated that rig logistics, equipment, and methods need improvement before attempting a large-scale dry drilling program at Yucca Mountain.« less

A simple and inexpensive technique for assessing microbial contamination during drilling operations

NASA Astrophysics Data System (ADS)

Friese, André; Vuillemin, Aurèle; Kallmeyer, Jens; Wagner, Dirk

2016-04-01

Exploration of the Deep Biosphere relies on drilling, which inevitably causes infiltration of drilling fluids, containing allochthonous microbes from the surface, into the core. Therefore it is absolutely necessary to trace contamination of the sediment core in order to identify uncontaminated samples for microbiological investigations. Several techniques have been used in the past, including fluorescent dyes, perfluorocarbon tracers and fluorescent microspheres. Fluorescent dyes are inexpensive and easy to analyze on-site but are sensitive to light, pH and water chemistry. Furthermore, significant sorption to clays can decrease the fluorescence signal. Perfluorocarbon tracers are chemically inert hydrophobic compounds that can be detected with high sensitivity via gas chromatography, which might be a problem for on-site analysis. Samples have to be taken immediately after core retrieval as otherwise the volatile tracer will have diffused out of the core. Microsphere tracers are small (0.2 - 0.5 μm diameter) fluorescent plastic particles that are mixed into the drilling fluid. For analysis, these particles can be extracted from the sediment sample, transferred onto a filter and quantified via fluorescence microscopy. However, they are very expensive and therefore unsuitable for deep drilling operations that need large amounts of drilling fluids. Here, we present an inexpensive contamination control approach using fluorescent pigments initially used for coloring plastics. The price of this tracer is nearly three orders of magnitude lower than conventional microsphere tracers. Its suitability for large drilling campaigns was tested at the ICDP Deep Drilling at Lake Towuti, Sulawesi, Indonesia. The tracer was diluted 1:1000 in lake water, which was used as the drilling fluid. Additionally, a plastic bag filled with 20 mL of undiluted tracer was attached to the core catcher to increase the amount of particles in the liner fluid right at the core. After core retrieval, the core was cut and the liner fluid collected. From each whole round core (WRC) that was taken for microbiological and biogeochemical analyses, small samples of 1 cc were retrieved with sterile cutoff syringes from the rim, the center and an intermediate position. After dilution and homogenization in 9 mL MilliQ water, 10 μL of the sediment slurry was transferred onto a filter membrane and particles counted via fluorescence microscopy. Additionally, particles in the liner fluid were also quantified. This allows the quantification of the amount of drilling fluid that has entered the sediment sample during drilling. The minimum detectable volume of drilling fluid was in the order of single nanoliters per cc of sediment, which is in the range of established techniques. The presented method requires only a minimum of equipment and allows rapid determination of contamination in the sediment core and an easy to handle on-site analysis at low costs. The sensitivity is in the same range as perfluorocarbon and microsphere tracer applications. Thus, it offers an inexpensive but powerful technique for contamination assessment for future drilling campaigns.

26 CFR 1.617-1 - Exploration expenditures.

Code of Federal Regulations, 2012 CFR

2012-04-01

... commercial exploitation by the taxpayer. For example, core drilling expenditures paid or incurred by the... of this section. Expenditures paid or incurred in connection with core drilling to further delineate... meaning of this section. Also, expenditures for exploratory drilling from within a producing mine to...

26 CFR 1.617-1 - Exploration expenditures.

Code of Federal Regulations, 2011 CFR

2011-04-01

... commercial exploitation by the taxpayer. For example, core drilling expenditures paid or incurred by the... of this section. Expenditures paid or incurred in connection with core drilling to further delineate... meaning of this section. Also, expenditures for exploratory drilling from within a producing mine to...

26 CFR 1.617-1 - Exploration expenditures.

Code of Federal Regulations, 2010 CFR

2010-04-01

... commercial exploitation by the taxpayer. For example, core drilling expenditures paid or incurred by the... of this section. Expenditures paid or incurred in connection with core drilling to further delineate... meaning of this section. Also, expenditures for exploratory drilling from within a producing mine to...

26 CFR 1.617-1 - Exploration expenditures.

Code of Federal Regulations, 2014 CFR

2014-04-01

... commercial exploitation by the taxpayer. For example, core drilling expenditures paid or incurred by the... of this section. Expenditures paid or incurred in connection with core drilling to further delineate... meaning of this section. Also, expenditures for exploratory drilling from within a producing mine to...

26 CFR 1.617-1 - Exploration expenditures.

Code of Federal Regulations, 2013 CFR

2013-04-01

... commercial exploitation by the taxpayer. For example, core drilling expenditures paid or incurred by the... of this section. Expenditures paid or incurred in connection with core drilling to further delineate... meaning of this section. Also, expenditures for exploratory drilling from within a producing mine to...

Mud Gas Logging In A Deep Borehole: IODP Site C0002, Nankai Trough Accretionary Prism

NASA Astrophysics Data System (ADS)

Toczko, S.; Hammerschmidt, S.; Maeda, L.

2014-12-01

Mud logging, a tool in riser drilling, makes use of the essentially "closed-circuit" drilling mud flow between the drilling platform downhole to the bit and then back to the platform for analyses of gas from the formation in the drilling mud, cuttings from downhole, and a range of safety and operational parameters to monitor downhole drilling conditions. Scientific riser drilling, with coincident control over drilling mud, downhole pressure, and returning drilling mud analyses, has now been in use aboard the scientific riser drilling vessel Chikyu since 2009. International Ocean Discovery Program (IODP) Expedition 348, as part of the goal of reaching the plate boundary fault system near ~5000 mbsf, has now extended the deep riser hole (Hole C0002 N & P) to 3058.5 mbsf. The mud gas data discussed here are from two approximately parallel boreholes, one a kick-off from the other; 860-2329 mbsf (Hole C0002N) and 2163-3058 mbsf (Hole C0002P). An approximate overlap of 166 m between the holes allows for some slight depth comparison between the two holes. An additional 55 m overlap at the top of Hole C0002P exists where a 10-5/8-inch hole was cored, and then opened to 12-1/4-inch with logging while drilling (LWD) tools (Fig. 1). There are several fault zones revealed by LWD data, confirmed in one instance by coring. One of the defining formation characteristics of Holes C0002 N/P are the strongly dipping bedding planes, typically exceeding 60º. These fault zones and bedding planes can influence the methane/ethane concentrations found in the returning drilling mud. A focused comparison of free gas in drilling mud between one interval in Hole C0002 P, drilled first with a 10 5/8-inch coring bit and again with an 12 ¼-inch logging while drilling (LWD) bit is shown. Hole C0002N above this was cased all the way from the sea floor to the kick-off section. A fault interval (in pink) was identified from the recovered core section and from LWD resistivity and gamma. The plot of methane and ethane free gas (C1 and C2; ppmv) shows that the yield of free gas (primarily methane) was greater when the LWD bit returned to open the cored hole to a greater diameter. One possible explanation for this is the time delay between coring and LWD operations; approximately 3 days passed between the end of coring and the beginning of LWD (25-28 December 2013).

Application of drilling, coring, and sampling techniques to test holes and wells

USGS Publications Warehouse

Shuter, Eugene; Teasdale, Warren E.

1989-01-01

The purpose of this manual is to provide ground-water hydrologists with a working knowledge of the techniques of test drilling, auger drilling, coring and sampling, and the related drilling and sampling equipment. For the most part, the techniques discussed deal with drilling, sampling, and completion of test holes in unconsolidated sediments because a hydrologist is interested primarily in shallow-aquifer data in this type of lithology. Successful drilling and coring of these materials usually is difficult, and published research information on the subject is not readily available. The authors emphasize in-situ sampling of unconsolidated sediments to obtain virtually undisturbed samples. Particular attention is given to auger drilling and hydraulic-rotary methods of drilling because these are the principal means of test drilling performed by the U.S. Geological Survey during hydrologic studies. Techniques for sampling areas contaminated by solid or liquid waste are discussed. Basic concepts of well development and a detailed discussion of drilling muds, as related to hole conditioning, also are included in the report. The information contained in this manual is intended to help ground-water hydrologists obtain useful subsurface data and samples from their drilling programs.

Scientific drilling and the evolution of the earth system: climate, biota, biogeochemistry and extreme systems

NASA Astrophysics Data System (ADS)

Soreghan, G. S.; Cohen, A. S.

2013-11-01

A US National Science Foundation-funded workshop occurred 17-19 May 2013 at the University of Oklahoma to stimulate research using continental scientific drilling to explore earth's sedimentary, paleobiological and biogeochemical record. Participants submitted 3-page "pre-proposals" to highlight projects that envisioned using drill-core studies to address scientific issues in paleobiology, paleoclimatology, stratigraphy and biogeochemistry, and to identify locations where key questions can best be addressed. The workshop was also intended to encourage US scientists to take advantage of the exceptional capacity of unweathered, continuous core records to answer important questions in the history of earth's sedimentary, biogeochemical and paleobiologic systems. Introductory talks on drilling and coring methods, plus best practices in core handling and curation, opened the workshop to enable all to understand the opportunities and challenges presented by scientific drilling. Participants worked in thematic breakout sessions to consider questions to be addressed using drill cores related to glacial-interglacial and icehouse-greenhouse transitions, records of evolutionary events and extinctions, records of major biogeochemical events in the oceans, reorganization of earth's atmosphere, Lagerstätte and exceptional fossil biota, records of vegetation-landscape change, and special sampling requirements, contamination, and coring tool concerns for paleobiology, geochemistry, geochronology, and stratigraphy-sedimentology studies. Closing discussions at the workshop focused on the role drilling can play in studying overarching science questions about the evolution of the earth system. The key theme, holding the most impact in terms of societal relevance, is understanding how climate transitions have driven biotic change, and the role of pristine, stratigraphically continuous cores in advancing our understanding of this linkage. Scientific drilling, and particularly drilling applied to continental targets, provides unique opportunities to obtain continuous and unaltered material for increasingly sophisticated analyses, tapping the entire geologic record (extending through the Archean), and probing the full dynamic range of climate change and its impact on biotic history.

The Auto-Gopher Deep Drill

NASA Technical Reports Server (NTRS)

Badescu, Mircea

2014-01-01

Subsurface penetration by coring, drilling or abrading is of great importance for a large number of space and earth applications. An Ultrasonic/Sonic Drill/Corer (USDC) has been in development at JPL's Nondestructive Evaluation and Advanced Actuators (NDEAA) lab as an adaptable tool for many of these applications. The USDC uses a novel drive mechanism to transform the high frequency ultrasonic or sonic vibrations of the tip of a horn into a lower frequency sonic hammering of a drill bit through an intermediate free-flying mass. The USDC device idea has been implemented at various scales from handheld drills to large diameter coring devices. A series of computer programs that model the function and performance of the USDC device were developed and were later integrated into an automated modeling package. The USDC has also evolved from a purely hammering drill to a rotary hammer drill as the design requirements increased form small diameter shallow drilling to large diameter deep coring. A synthesis of the Auto-Gopher development is presented in this paper.

Drilling predation on molluscs in the northern Adriatic Sea: Spatial variability and temporal trends over the last millennia

NASA Astrophysics Data System (ADS)

Dengg, Markus; Wurzer, Sandra; Gallmetzer, Ivo; Haselmair, Alexandra; Zuschin, Martin

2016-04-01

Competition and predation are essential ecological factors influencing biodiversity. In a palaeontological context, the rate of predatory interactions between animal species is difficult to reconstruct because traces of predation are rarely incorporated into the fossil record. In the marine environment, the calcareous shells of molluscs, however, have good, long-time preservation potential, and predation in this group is often exerted by carnivorous gastropods that drill holes into mollusc shells. The prey's perforated shells remain in the sediment and can be used to study rates and intensities of predatory interactions in past marine molluscan communities. Differences in drilling frequencies along a sediment core not only reflect changes in local species richness and predation pressure, but may also mirror ecosystem changes through space and time. This makes the analysis of drilling predation an important tool when investigating the historical ecology of marine habitats. We used 1.5-m-long sediment cores from seven shelf locations spread throughout the northern Adriatic Sea basin to investigate regional and down-core variations in drilling frequencies. In total, about 54,000 bivalve and 40,000 gastropod shells were analysed to determine the following parameters: 1) overall drill frequency (DF), the proportion of shells drilled by predators; 2) edge drill frequency (EDF, only in bivalve shells), the proportion of shells with drilling traces at the shell edge; 3) multiple drill frequency (MDF), the percentage of individuals with more than one drill hole, 4) incomplete drill frequency (IDF), the percentage of shells unsuccessfully drilled; 5) prey effectiveness (PE), the proportion of individuals resisting the predator's attacks. Total drill frequency across all cores is 18% for bivalves and 13% for gastropods, but there are marked regional differences, with minima in the Po Delta (5%) and maxima in Panzano Bay (24%). Edge-drilled shells and multiple drill holes on single shells are very rare and occur on less than 1% of the investigated specimens. Also very low (< 1%) is the percentage of incomplete drill holes, except for the sampling location at the Brijuni Islands, Croatia (4%). Drilling frequencies show stronger differences between localities than along individual cores. Significant correlations exist between drilling intensities and prey species ecotype (especially for bivalves): commensals, parasitic and suspension-feeding species are more frequently drilled than other feeding types, as are infaunal species compared to species with epifaunal life habits. Despite the strong spatial variation in drilling intensities, the DF values of our samples are comparable to those typical for Cenozoic shelf environments.

Sea Bed Drilling Technology MARUM-MeBo: Overview on recent scientific drilling campaigns and technical developments

NASA Astrophysics Data System (ADS)

Freudenthal, Tim; Bergenthal, Markus; Bohrmann, Gerhard; Pape, Thomas; Kopf, Achim; Huhn-Frehers, Katrin; Gohl, Karsten; Wefer, Gerold

2017-04-01

The MARUM-MeBo (abbreviation for Meeresboden-Bohrgerät, the German expression for seafloor drill rig) is a robotic drilling system that is developed since 2004 at the MARUM Center for Marine Environmental Sciences at the University of Bremen in close cooperation with Bauer Maschinen GmbH and other industry partners. The MARUM-MeBo drill rigs can be deployed from multipurpose research vessel like, RV MARIA S. MERIAN, RV METEOR, RV SONNE and RV POLARSTERN and are used for getting long cores both in soft sediments as well as hard rocks in the deep sea. The first generation drill rig, the MARUM-MeBo70 is dedicated for a drilling depth of more than 70 m (Freudenthal and Wefer, 2013). Between 2005 and 2016 it was deployed on 17 research expeditions and drilled about 3 km into different types of geology including carbonate and crystalline rocks, gas hydrates, glacial tills, sands and gravel, glacial till and hemipelagic mud with an average recovery rate of about 70 %. We used the development and operational experiences of MARUM-MeBo70 for the development of a second generation drill rig MARUM-MeBo200. This drill rig is dedicated for conducting core drilling down to 200 m below sea floor. After successful sea trials in the North Sea in October 2014 the MeBo200 was used on a scientific expedition on the research vessel RV SONNE (SO247) in March/April 2016. During 12 deployments we drilled altogether 514 m in hemipelagic sediments with volcanic ashes as well as in muddy and sandy slide deposits off New Zealand. The average core recovery was about 54%. The maximum drilling depth was 105 m below sea floor. Developments for the MeBo drilling technology include the development of a pressure core barrel that was successfully deployed on two research expeditions so far. Bore hole logging adds to the coring capacity. Several autonomous logging probes have been developed in the last years for a deployment with MeBo in the logging while tripping mode - a sonic probe measuring in situ p-wave velocity being the latest development. Various bore hole monitoring systems where developed and deployed with the MeBo system. They allow for long-term monitoring of pressure variability within the sealed bore holes. References: Freudenthal, T and Wefer, G (2013) Drilling cores on the sea floor with the remote-controlled sea floor drilling rig MeBo. Geoscientific Instrumentation, Methods and Data Systems, 2(2). 329-337. doi:10.5194/gi-2-329-2013

The 2005 MARTE Robotic Drilling Experiment in Río Tinto, Spain: Objectives, Approach, and Results of a Simulated Mission to Search for Life in the Martian Subsurface

NASA Astrophysics Data System (ADS)

Stoker, Carol R.; Cannon, Howard N.; Dunagan, Stephen E.; Lemke, Lawrence G.; Glass, Brian J.; Miller, David; Gomez-Elvira, Javier; Davis, Kiel; Zavaleta, Jhony; Winterholler, Alois; Roman, Matt; Rodriguez-Manfredi, Jose Antonio; Bonaccorsi, Rosalba; Bell, Mary Sue; Brown, Adrian; Battler, Melissa; Chen, Bin; Cooper, George; Davidson, Mark; Fernández-Remolar, David; Gonzales-Pastor, Eduardo; Heldmann, Jennifer L.; Martínez-Frías, Jesus; Parro, Victor; Prieto-Ballesteros, Olga; Sutter, Brad; Schuerger, Andrew C.; Schutt, John; Rull, Fernando

2008-10-01

The Mars Astrobiology Research and Technology Experiment (MARTE) simulated a robotic drilling mission to search for subsurface life on Mars. The drill site was on Peña de Hierro near the headwaters of the Río Tinto river (southwest Spain), on a deposit that includes massive sulfides and their gossanized remains that resemble some iron and sulfur minerals found on Mars. The mission used a fluidless, 10-axis, autonomous coring drill mounted on a simulated lander. Cores were faced; then instruments collected color wide-angle context images, color microscopic images, visible near infrared point spectra, and (lower resolution) visible-near infrared hyperspectral images. Cores were then stored for further processing or ejected. A borehole inspection system collected panoramic imaging and Raman spectra of borehole walls. Life detection was performed on full cores with an adenosine triphosphate luciferin-luciferase bioluminescence assay and on crushed core sections with SOLID2, an antibody array-based instrument. Two remotely located science teams analyzed the remote sensing data and chose subsample locations. In 30 days of operation, the drill penetrated to 6 m and collected 21 cores. Biosignatures were detected in 12 of 15 samples analyzed by SOLID2. Science teams correctly interpreted the nature of the deposits drilled as compared to the ground truth. This experiment shows that drilling to search for subsurface life on Mars is technically feasible and scientifically rewarding.

The 2005 MARTE Robotic Drilling Experiment in Río Tinto, Spain: objectives, approach, and results of a simulated mission to search for life in the Martian subsurface.

PubMed

Stoker, Carol R; Cannon, Howard N; Dunagan, Stephen E; Lemke, Lawrence G; Glass, Brian J; Miller, David; Gomez-Elvira, Javier; Davis, Kiel; Zavaleta, Jhony; Winterholler, Alois; Roman, Matt; Rodriguez-Manfredi, Jose Antonio; Bonaccorsi, Rosalba; Bell, Mary Sue; Brown, Adrian; Battler, Melissa; Chen, Bin; Cooper, George; Davidson, Mark; Fernández-Remolar, David; Gonzales-Pastor, Eduardo; Heldmann, Jennifer L; Martínez-Frías, Jesus; Parro, Victor; Prieto-Ballesteros, Olga; Sutter, Brad; Schuerger, Andrew C; Schutt, John; Rull, Fernando

2008-10-01

The Mars Astrobiology Research and Technology Experiment (MARTE) simulated a robotic drilling mission to search for subsurface life on Mars. The drill site was on Peña de Hierro near the headwaters of the Río Tinto river (southwest Spain), on a deposit that includes massive sulfides and their gossanized remains that resemble some iron and sulfur minerals found on Mars. The mission used a fluidless, 10-axis, autonomous coring drill mounted on a simulated lander. Cores were faced; then instruments collected color wide-angle context images, color microscopic images, visible-near infrared point spectra, and (lower resolution) visible-near infrared hyperspectral images. Cores were then stored for further processing or ejected. A borehole inspection system collected panoramic imaging and Raman spectra of borehole walls. Life detection was performed on full cores with an adenosine triphosphate luciferin-luciferase bioluminescence assay and on crushed core sections with SOLID2, an antibody array-based instrument. Two remotely located science teams analyzed the remote sensing data and chose subsample locations. In 30 days of operation, the drill penetrated to 6 m and collected 21 cores. Biosignatures were detected in 12 of 15 samples analyzed by SOLID2. Science teams correctly interpreted the nature of the deposits drilled as compared to the ground truth. This experiment shows that drilling to search for subsurface life on Mars is technically feasible and scientifically rewarding.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whelan, J.A.

During the summer of 1975, the Department of Geology and Geophysics drilled nine drill thermal gradient/heat flow holes. Total footage drilled was 2125 feet. Seven holes were drilled with a Mayhew 1000 drill using various combinations of down the hole hammer drilling, rotary drilling, and NX diamond core drilling. Three of these were heat flow holes--one in the Mineral Range, one in the Tushar Range near Beaver, Utah, and one near Monroe, Utah. Two were alteration study holes in the Roosevelt KGRA and two were temperature gradient holes, in alluvium in the Roosevelt KGRA. The average depth of the holesmore » drilled with the Mayhew 1000 drill was 247 feet. Holes ranged from 135 feet to 492 feet. Cost per foot averaged $18.53. Two holes were core drilled with a Joy 12, BX-size drill. One was to 75 feet, in perlite. This hole was abandoned. The other was to 323 feet in granite.« less

Development of lunar drill to take core samples to 100-foot depths

NASA Technical Reports Server (NTRS)

1967-01-01

Lunar drill takes lunar surface cores to depths of 100 feet and is being developed to the samples at greater depths. The wireline drill system has been adapted to operate in the lunar environment by providing a sealed dc motor and solid metallic base lubricants.

Ultrasonic Drilling and Coring

NASA Technical Reports Server (NTRS)

Bar-Cohen, Yoseph

1998-01-01

A novel drilling and coring device, driven by a combination, of sonic and ultrasonic vibration, was developed. The device is applicable to soft and hard objects using low axial load and potentially operational under extreme conditions. The device has numerous potential planetary applications. Significant potential for commercialization in construction, demining, drilling and medical technologies.

Characterization of the HSiN HNSi system in its electronic ground state

NASA Astrophysics Data System (ADS)

Lind, Maria C.; Pickard, Frank C.; Ingels, Justin B.; Paul, Ankan; Yamaguchi, Yukio; Schaefer, Henry F.

2009-03-01

The electronic ground states (X˜Σ+1) of HSiN, HNSi, and the transition state connecting the two isomers were systematically studied using configuration interaction with single and double (CISD) excitations, coupled cluster with single and double (CCSD) excitations, CCSD with perturbative triple corrections [CCSD(T)], multireference complete active space self-consistent field (CASSCF), and internally contracted multireference configuration interaction (ICMRCI) methods. The correlation-consistent polarized valence (cc-pVXZ), augmented correlation-consistent polarized valence (aug-cc-pVXZ) (X=T,Q,5), correlation-consistent polarized core-valence (cc-pCVYZ), and augmented correlation-consistent polarized core-valence (aug-cc-pCVYZ) (Y=T,Q) basis sets were used. Via focal point analyses, we confirmed the HNSi isomer as the global minimum on the ground state HSiN HNSi zero-point vibrational energy corrected surface and is predicted to lie 64.7kcalmol-1 (22640cm-1, 2.81eV) below the HSiN isomer. The barrier height for the forward isomerization reaction (HSiN→HNSi) is predicted to be 9.7kcalmol-1, while the barrier height for the reverse process (HNSi→HSiN) is determined to be 74.4kcalmol-1. The dipole moments of the HSiN and HNSi isomers are predicted to be 4.36 and 0.26D, respectively. The theoretical vibrational isotopic shifts for the HSiN/DSiN and HNSi/DNSi isotopomers are in strong agreement with the available experimental values. The dissociation energy for HSiN [HSiN(X˜Σ+1)→H(S2)+SiN(XΣ+2)] is predicted to be D0=59.6kcalmol-1, whereas the dissociation energy for HNSi [HNSi(X˜Σ+1)→H(S2)+NSi(XΣ+2)] is predicted to be D0=125.0kcalmol-1 at the CCSD(T)/aug-cc-pCVQZ level of theory. Anharmonic vibrational frequencies computed using second order vibrational perturbation theory are in good agreement with available matrix isolation experimental data for both HSiN and HNSi isomers root mean squared derivation (RMSD=9cm-1).

A New Method of Stress Measurement Based upon Elastic Deformation of Core Sample with Stress Relief by Drilling

NASA Astrophysics Data System (ADS)

Ito, T.; Funato, A.; Tamagawa, T.; Tezuka, K.; Yabe, Y.; Abe, S.; Ishida, A.; Ogasawara, H.

2017-12-01

When rock is cored at depth by drilling, anisotropic expansion occurs with the relief of anisotropic rock stresses, resulting in a sinusoidal variation of core diameter with a period of 180 deg. in the core roll angle. The circumferential variation of core diameter is given theoretically as a function of rock stresses. These new findings can lead various ideas to estimate the rock stress from circumferential variation of core diameter measured after the core retrieving. In the simplest case when a single core sample is only available, the difference between the maximum and minimum components of rock stress in a plane perpendicular to the drilled hole can be estimated from the maximum and minimum core diameters (see the detail in, Funato and Ito, IJRMMS, 2017). The advantages of this method include, (i) much easier measurement operation than those in other in-situ or in-lab estimation methods, and (ii) applicability in high stress environment where stress measurements need pressure for packers or pumping system for the hydro-fracturing methods higher than their tolerance levels. We have successfully tested the method at deep seismogenic zones in South African gold mines, and we are going to apply it to boreholes collared at 3 km depth and intersecting a M5.5 rupture plane several hundred meters below the mine workings in the ICDP project of "Drilling into Seismogenic zones of M2.0 - M5.5 earthquakes in deep South African gold mines" (DSeis) (e.g., http://www.icdp-online.org/projects/world/africa/orkney-s-africa/details/). If several core samples with different orientation are available, all of three principal components of 3D rock stress can be estimated. To realize this, we should have several boreholes drilled in different directions in a rock mass where the stress field is considered to be uniform. It is commonly carried out to dill boreholes in different directions from a mine gallery. Even in a deep borehole drilled vertically from the ground surface, the downhole tool of rotary sidewall coring allows us to take core samples with different orientations at depths of interest from the sidewall of the vertically-drilled borehole. The theoretical relationship between the core expansion and rock stress has been verified through the examination of core samples prepared in laboratory experiments and retrieved field cores.

Paleomagnetic and Magnetostratigraphic Studies in Drilling Projects of Impact Craters - Recent Studies, Challenges and Perspectives

NASA Astrophysics Data System (ADS)

Fucugauchi, J. U.; Velasco-Villarreal, M.; Perez-Cruz, L. L.

2013-05-01

Paleomagnetic studies have long been successfully carried out in drilling projects, to characterize the borehole columns and to investigate the subsurface structure and stratigraphy. Magnetic susceptibility logging and magnetostratigraphic studies provide data for lateral correlation, formation evaluation, azimuthal core orientation, physical properties, etc., and are part of the tools available in the ocean and continental drilling programs. The inclusion of continuous core recovery in scientific drilling projects have greatly expanded the range of potential applications of paleomagnetic and rock magnetic studies, by allowing laboratory measurements on core samples. For this presentation, we concentrate on drilling studies of impact structures and their usefulness for documenting the structure, stratigraphy and physical properties at depth. There are about 170-180 impact craters documented in the terrestrial record, which is a small number compared to what is observed in the Moon, Mars, Venus and other bodies of the solar system. Of the terrestrial impact craters, only a few have been studied by drilling. Some craters have been drilled as part of industry exploration surveys and/or academic projects, including notably the Sudbury, Ries, Vredefort, Manson and many other craters. As part of the Continental ICDP program, drilling projects have been conducted on the Chicxulub, Bosumtwi, Chesapeake and El gygytgyn craters. Drilling of terrestrial craters has proved important in documenting the shallow stratigraphy and structure, providing insight on the cratering and impact dynamics. Questions include several that can only be addressed by retrieving core samples and laboratory analyses. Paleomagnetic, rock magnetic and fabric studies have been conducted in the various craters, which are here summarized with emphasis on the Chicxulub crater and Yucatan carbonate platform. Chicxulub is buried under a kilometer of younger sediments, making drilling an essential tool. Oil exploration included several boreholes, and additionally we have drilled 11 boreholes with continuous core recovery. Contributions and limitations of paleomagnetism for investigating the impact age, crater stratigraphy, cratering, ejecta emplacement, impact dynamics, hydrothermal system and post-impact processes are discussed.

Ultrasonic/Sonic Mechanisms for Drilling and Coring

NASA Technical Reports Server (NTRS)

Bar-Cohen, Yoseph; Sherrit, Stewart; Dolgin, Benjamin; Askin, Steve; Peterson, Thomas M.; Bell, Bill; Kroh, Jason; Pal, Dharmendra; Krahe, Ron; Du, Shu

2003-01-01

Two apparatuses now under development are intended to perform a variety of deep-drilling, coring, and sensing functions for subsurface exploration of rock and soil. These are modified versions of the apparatuses described in Ultrasonic/Sonic Drill/Corers With Integrated Sensors (NPO-20856), NASA Tech Briefs, Vol. 25, No. 1 (January 2001), page 38. In comparison with the drilling equipment traditionally used in such exploration, these apparatuses weigh less and consume less power. Moreover, unlike traditional drills and corers, these apparatuses function without need for large externally applied axial forces.

Development of the RANCOR Rotary-Percussive Coring System for Mars Sample Return

NASA Technical Reports Server (NTRS)

Paulsen, Gale; Indyk, Stephen; Zacny, Kris

2014-01-01

A RANCOR drill was designed to fit a Mars Exploration Rover (MER) class vehicle. The low mass of 3 kg was achieved by using the same actuator for three functions: rotation, percussions, and core break-off. Initial testing of the drill exposed an unexpected behavior of an off-the-shelf sprag clutch used to couple and decouple rotary-percussive function from the core break off function. Failure of the sprag was due to the vibration induced during percussive drilling. The sprag clutch would back drive in conditions where it was expected to hold position. Although this did not affect the performance of the drill, it nevertheless reduced the quality of the cores produced. Ultimately, the sprag clutch was replaced with a custom ratchet system that allowed for some angular displacement without advancing in either direction. Replacing the sprag with the ratchet improved the collected core quality. Also, premature failure of a 300-series stainless steel percussion spring was observed. The 300-series percussion spring was ultimately replaced with a music wire spring based on performances of previously designed rotary-percussive drill systems.

Results from Testing of Two Rotary Percussive Drilling Systems

NASA Technical Reports Server (NTRS)

Kriechbaum, Kristopher; Brown, Kyle; Cady, Ian; von der Heydt, Max; Klein, Kerry; Kulczycki, Eric; Okon, Avi

2010-01-01

The developmental test program for the MSL (Mars Science Laboratory) rotary percussive drill examined the e ect of various drill input parameters on the drill pene- tration rate. Some of the input parameters tested were drill angle with respect to gravity and percussive impact energy. The suite of rocks tested ranged from a high strength basalt to soft Kaolinite clay. We developed a hole start routine to reduce high sideloads from bit walk. The ongoing development test program for the IMSAH (Integrated Mars Sample Acquisition and Handling) rotary percussive corer uses many of the same rocks as the MSL suite. An additional performance parameter is core integrity. The MSL development test drill and the IMSAH test drill use similar hardware to provide rotation and percussion. However, the MSL test drill uses external stabilizers, while the IMSAH test drill does not have external stabilization. In addition the IMSAH drill is a core drill, while the MSL drill uses a solid powdering bit. Results from the testing of these two related drilling systems is examined.

Wireline Deep Drill for the Exploration of Icy Bodies

NASA Technical Reports Server (NTRS)

Paulsen, G.; Zacny, K.; Mellerowicz, B.; Craft, J.; Bar-Cohen, Y.; Beegle, L.; Sherrit, S.; Badescu, M.; Corsetti, F.; Ibarra, Y.

2013-01-01

One of the most pressing current questions in space science is whether life has ever arisen anywhere else in the universe. Water is a critical prerequisite for all life-as-we-know-it, thus the possible exploration targets for extraterrestrial life are bodies that have or had copious liquid: Mars, Europa, and Enceladus. Due to the oxidizing nature of Mars' surface, as well as subsurface liquid water reservoirs present on Europa and Enceladus, the search for evidence of existing life must likely focus on subsurface locations, at depths sufficient to support liquid water or retain biologic signatures. To address these questions, an Auto-Gopher sampler has been developed that is a wireline type drill. This drill is suspended on a tether and its motors and mechanisms are built into a tube that ends with a coring bit. The tether provides the mechanical connection to a rover/lander on a surface as well as power and data communication. Upon penetrating to a target depth, the drill is retracted from the borehole, the core is deposited into a sample transfer system, and the drill is lowered back into the hole. Wireline operation sidesteps one of the major drawbacks of traditional continuous drill string systems by obviating the need for multiple drill sections, which add significantly to the mass and the complexity of the system (i.e. penetration rate was 40 cm per hour). Drilling to 2 meter depth and recovering of cores every 10 cm took a total time of 15 hours (a single step of drilling 10 cm and retrieving the core was 45 minutes). Total energy to reach the 2 m depth was 500 Whr. The Weight on Bit was limited to less than 70 Newton. The core recovery was 100%.

Investigating the soil removal characteristics of flexible tube coring method for lunar exploration

NASA Astrophysics Data System (ADS)

Tang, Junyue; Quan, Qiquan; Jiang, Shengyuan; Liang, Jieneng; Lu, Xiangyong; Yuan, Fengpei

2018-02-01

Compared with other technical solutions, sampling the planetary soil and returning it back to Earth may be the most direct method to seek the evidence of extraterrestrial life. To keep sample's stratification for further analyzing, a novel sampling method called flexible tube coring has been adopted for China future lunar explorations. Given the uncertain physical properties of lunar regolith, proper drilling parameters should be adjusted immediately in piercing process. Otherwise, only a small amount of core could be sampled and overload drilling faults could occur correspondingly. Due to the fact that the removed soil is inevitably connected with the cored soil, soil removal characteristics may have a great influence on both drilling loads and coring results. To comprehend the soil removal characteristics, a non-contact measurement was proposed and verified to acquire the coring and removal results accurately. Herein, further more experiments in one homogenous lunar regolith simulant were conducted, revealing that there exists a sudden core failure during the sampling process and the final coring results are determined by the penetration per revolution index. Due to the core failure, both drilling loads and soil's removal states are also affected thereby.

Theoretical prediction of the ionization energies of the C4H7 radicals: 1-methylallyl, 2-methylallyl, cyclopropylmethyl, and cyclobutyl radicals.

PubMed

Lau, Kai-Chung; Zheng, Wenxu; Wong, Ning-Bew; Li, Wai-Kee

2007-10-21

The ionization energies (IEs) for the 1-methylallyl, 2-methylallyl, cyclopropylmethyl, and cyclobutyl radicals have been calculated by the wave function based ab initio CCSD(T)/CBS approach, which involves the approximation to the complete basis set (CBS) limit at the coupled cluster level with single and double excitations plus quasiperturbative triple excitation [CCSD(T)]. The zero-point vibrational energy correction, the core-valence electronic correction, and the scalar relativistic effect correction are included in these calculations. The present CCSD(T)/CBS results are then compared with the IEs determined in the photoelectron experiment by Schultz et al. [J. Am. Chem. Soc. 106, 7336 (1984)] The predicted IE value (7.881 eV) of 2-methylallyl radical is found to compare very favorably with the experimental value of 7.90+/-0.02 eV. Two ionization transitions for cis-1-methylallyl and trans-1-methylallyl radicals have been considered here. The comparison between the predicted IE values and the previous measurements shows that the photoelectron peak observed by Schultz et al. likely corresponds to the adiabatic ionization transition for the trans-1-methylallyl radical to form trans-1-methylallyl cation. Although a precise IE value for the cyclopropylmethyl radical has not been directly determined, the experimental value deduced indirectly using other known energetic data is found to be in good accord with the present CCSD(T)/CBS prediction. We expect that the Franck-Condon factor for ionization transition of c-C4H7-->bicyclobutonium is much less favorable than that for ionization transition of c-C4H7-->planar-C4H7+, and the observed IE in the previous photoelectron experiment is likely due to the ionization transition for c-C4H7-->planar-C4H7+. Based on our CCSD(T)/CBS prediction, the ionization transition of c-C4H7-->bicyclobutonium with an IE value around 6.92 eV should be taken as the adiabatic ionization transition for the cyclobutyl radical. The present study provides support for the conclusion that the CCSD(T)/CBS approach with high-level energetic corrections can be used to provide reliable IE predictions for C4 hydrocarbon radicals with an uncertainty of +/-22 meV. The CCSD(T)/CBS predictions to the heats of formation for the aforementioned radicals and cations are also presented.

30 CFR 784.22 - Geologic information.

Code of Federal Regulations, 2014 CFR

2014-07-01

... be collected and analyzed from test borings; drill cores; or fresh, unweathered, uncontaminated... not be removed, samples shall be collected and analyzed from test borings or drill cores to provide...

30 CFR 784.22 - Geologic information.

Code of Federal Regulations, 2013 CFR

2013-07-01

... be collected and analyzed from test borings; drill cores; or fresh, unweathered, uncontaminated... not be removed, samples shall be collected and analyzed from test borings or drill cores to provide...

Managing Geothermal Exploratory Drilling Risks Drilling Geothermal Exploration and Delineation Wells with Small-Footprint Highly Portable Diamond Core Drills

NASA Astrophysics Data System (ADS)

Tuttle, J.; Listi, R.; Combs, J.; Welch, V.; Reilly, S.

2012-12-01

Small hydraulic core rigs are highly portable (truck or scow-mounted), and have recently been used for geothermal exploration in areas such as Nevada, California, the Caribbean Islands, Central and South America and elsewhere. Drilling with slim diameter core rod below 7,000' is common, with continuous core recovery providing native-state geological information to aid in identifying the resource characteristics and boundaries; this is a highly cost-effective process. Benefits associated with this innovative exploration and delineation technology includes the following: Low initial Capital Equipment Cost and consumables costs Small Footprint, reducing location and road construction, and cleanup costs Supporting drill rod (10'/3meter) and tools are relatively low weight and easily shipped Speed of Mobilization and rig up Reduced requirements for support equipment (cranes, backhoes, personnel, etc) Small mud systems and cementing requirements Continuous, simplified coring capability Depth ratings comparable to that of large rotary rigs (up to ~10,000'+) Remote/small-location accessible (flown into remote areas or shipped in overseas containers) Can be scow or truck-mounted This technical presentation's primary goal is to share the technology of utilizing small, highly portable hydraulic coring rigs to provide exploratory drilling (and in some cases, production drilling) for geothermal projects. Significant cost and operational benefits are possible for the Geothermal Operator, especially for those who are pursuing projects in remote locations or countries, or in areas that are either inaccessible or in which a small footprint is required. John D. Tuttle Sinclair Well Products jtuttle@sinclairwp.com

Fluoroscopy-Guided Percutaneous Vertebral Body Biopsy Using a Novel Drill-Powered Device: Technical Case Series

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wallace, Adam N., E-mail: wallacea@mir.wustl.edu; Pacheco, Rafael A., E-mail: pachecor@mir.wustl.edu; Tomasian, Anderanik, E-mail: tomasiana@mir.wustl.edu

2016-02-15

BackgroundA novel coaxial biopsy system powered by a handheld drill has recently been introduced for percutaneous bone biopsy. This technical note describes our initial experience performing fluoroscopy-guided vertebral body biopsies with this system, compares the yield of drill-assisted biopsy specimens with those obtained using a manual technique, and assesses the histologic adequacy of specimens obtained with drill assistance.MethodsMedical records of all single-level, fluoroscopy-guided vertebral body biopsies were reviewed. Procedural complications were documented according to the Society of Interventional Radiology classification. The total length of bone core obtained from drill-assisted biopsies was compared with that of matched manual biopsies. Pathology reportsmore » were reviewed to determine the histologic adequacy of specimens obtained with drill assistance.ResultsTwenty eight drill-assisted percutaneous vertebral body biopsies met study inclusion criteria. No acute complications were reported. Of the 86 % (24/28) of patients with clinical follow-up, no delayed complications were reported (median follow-up, 28 weeks; range 5–115 weeks). The median total length of bone core obtained from drill-assisted biopsies was 28 mm (range 8–120 mm). This was longer than that obtained from manual biopsies (median, 20 mm; range 5–45 mm; P = 0.03). Crush artifact was present in 11 % (3/28) of drill-assisted biopsy specimens, which in one case (3.6 %; 1/28) precluded definitive diagnosis.ConclusionsA drill-assisted, coaxial biopsy system can be used to safely obtain vertebral body core specimens under fluoroscopic guidance. The higher bone core yield obtained with drill assistance may be offset by the presence of crush artifact.« less

A noniterative asymmetric triple excitation correction for the density-fitted coupled-cluster singles and doubles method: Preliminary applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bozkaya, Uğur, E-mail: ugrbzky@gmail.com

2016-04-14

An efficient implementation of the asymmetric triples correction for the coupled-cluster singles and doubles [ΛCCSD(T)] method [S. A. Kucharski and R. J. Bartlett, J. Chem. Phys. 108, 5243 (1998); T. D. Crawford and J. F. Stanton, Int. J. Quantum Chem. 70, 601 (1998)] with the density-fitting [DF-ΛCCSD(T)] approach is presented. The computational time for the DF-ΛCCSD(T) method is compared with that of ΛCCSD(T). Our results demonstrate that the DF-ΛCCSD(T) method provide substantially lower computational costs than ΛCCSD(T). Further application results show that the ΛCCSD(T) and DF-ΛCCSD(T) methods are very beneficial for the study of single bond breaking problems as wellmore » as noncovalent interactions and transition states. We conclude that ΛCCSD(T) and DF-ΛCCSD(T) are very promising for the study of challenging chemical systems, where the coupled-cluster singles and doubles with perturbative triples method fails.« less

The Chesapeake Bay Impact Crater: An Educational Investigation for Students into the Planetary Impact Process and its Environmental Consequences

NASA Technical Reports Server (NTRS)

Levine, Arlene S.

2008-01-01

Planetary impact craters are a common surface feature of many planetary bodies, including the Earth, the Moon, Mars, Mercury, Venus, and Jupiter s moons, Ganymede and Callisto. The NASA Langley Research Center in Hampton, VA, is located about 5 km inside the outer rim of the Chesapeake Bay Impact Crater. The Chesapeake Bay Impact Crater, with a diameter of 85 km is the sixth largest impact crater on our planet. The U.S. Geological Survey (USGS), in collaboration with the NASA Langley Research Center, the Virginia Department of Environmental Quality (VDEQ), the Hampton Roads Planning District Commission (HRPDC), and the Department of Geology of the College of William and Mary (WM) drilled into and through the crater at the NASA Langley Research Center and obtained a continuous core to a depth of 2075.9 ft (632.73 meters) from the Chesapeake Bay Impact Crater. At the NASA Langley location, the granite basement depth was at 2046 ft (623.87 meters). This collaborative drilling activity provided a unique educational opportunity and ongoing educational partnership between USGS, NASA Langley and the other collaborators. NASA Langley has a decade-long, ongoing educational partnership with the Colonial Coast Council of the Girl Scouts. The core drilling and on site analysis and cataloguing of the core segments provided a unique opportunity for the Girl Scouts to learn how geologists work in the field, their tools for scientific investigation and evaluation, how they perform geological analyses of the cores in an on-site tent and learn about the formation of impact craters and the impact of impacting bodies on the sub-surface, the surface, the oceans and atmosphere of the target body. This was accomplished with a two-part activity. Girl Scout day camps and local Girl Scout troops were invited to Langley Research Center Conference Center, where more than 300 Girl Scouts, their leaders and adult personnel were given briefings by scientists and educators from the USGS, NASA, VDEQ, HRPDC and WM on the principles of geology, the formation of impact craters, the consequences of the impacting body on the atmosphere, ocean, surface and sub-surface, the geological, chemical and biological analyses of the core and the cataloguing and storage of the core segments, etc. After the briefings, the Girl Scouts visited the drilling site where they inspected the core drilling rig, examined the core samples and discussed the drilling procedures, cores and interpretation of the cores with scientists and educators from the organizations conducting the core drilling. Demonstrations at the drilling site included demonstrations of impacting objects hitting multi-colored layered mud targets at different angles of entry. The multi-colored layers of mud were instructive in mapping out the distribution of impact-ejected material around the impact crater. The presentation will include a series of photographs of the Girl Scout participating in activities at the Chesapeake Bay Impact Crater drill site, including retrieving cores from the drilling rig, inspecting the core samples and participating in the impact-crater formation demonstrations.

High-level ab initio predictions for the ionization energies and heats of formation of five-membered-ring molecules: thiophene, furan, pyrrole, 1,3-cyclopentadiene, and borole, C4H4X/C4H4X+ (X = S, O, NH, CH2, and BH).

PubMed

Lo, Po-Kam; Lau, Kai-Chung

2011-02-10

The ionization energies (IEs) and heats of formation (ΔH°(f0)/ΔH°(f298)) for thiophene (C(4)H(4)S), furan (C(4)H(4)O), pyrrole (C(4)H(4)NH), 1,3-cyclopentadiene (C(4)H(4)CH(2)), and borole (C(4)H(4)BH) have been calculated by the wave function-based ab initio CCSD(T)/CBS approach, which involves the approximation to the complete basis set (CBS) limit at the coupled-cluster level with single and double excitations plus a quasi-perturbative triple excitation [CCSD(T)]. Where appropriate, the zero-point vibrational energy correction (ZPVE), the core-valence electronic correction (CV), and the scalar relativistic effect (SR) are included in these calculations. The respective CCSD(T)/CBS predictions for C(4)H(4)S, C(4)H(4)O, C(4)H(4)NH, and C(4)H(4)CH(2), being 8.888, 8.897, 8.222, and 8.582 eV, are in excellent agreement with the experimental values obtained from previous photoelectron and photoion measurements. The ΔH°(f0)/ΔH°(f298) values for the aforementioned molecules and their corresponding cations have also been predicted by the CCSD(T)/CBS method, and the results are compared with the available experimental data. The comparisons between the CCSD(T)/CBS predictions and the experimental values for C(4)H(4)S, C(4)H(4)O, C(4)H(4)NH, and C(4)H(4)CH(2) suggest that the CCSD(T)/CBS procedure is capable of predicting reliable IE values for five-membered-ring molecules with an uncertainty of ±13 meV. In view of the excellent agreements between the CCSD(T)/CBS predictions and the experimental values for C(4)H(4)S, C(4)H(4)O, C(4)H(4)NH, and C(4)H(4)CH(2), the similar CCSD(T)/CBS IE and ΔH°(f0)/ΔH°(f298) predictions for C(4)H(4)BH, whose thermochemical data are not readily available due to its reactive nature, should constitute a reliable data set. The CCSD(T)/CBS IE(C(4)H(4)BH) value is 8.868 eV, and ΔH°(f0)/ΔH°(f298) values for C(4)H(4)BH and C(4)H(4)BH(+) are 269.5/258.6 and 1125.1/1114.6 kJ/mol, respectively. The highest occupied molecular orbitals (HOMO) of C(4)H(4)S, C(4)H(4)O, C(4)H(4)NH, C(4)H(4)CH(2), and C(4)H(4)BH have also been studied by the natural bond orbital (NBO) method, and the extent of π-electron delocalization in these five-membered rings are discussed in correlation with their molecular structures and orbitals.

Contamination assessment in microbiological sampling of the Eyreville core, Chesapeake Bay impact structure

USGS Publications Warehouse

Gronstal, A.L.; Voytek, M.A.; Kirshtein, J.D.; Von der, Heyde; Lowit, M.D.; Cockell, C.S.

2009-01-01

Knowledge of the deep subsurface biosphere is limited due to difficulties in recovering materials. Deep drilling projects provide access to the subsurface; however, contamination introduced during drilling poses a major obstacle in obtaining clean samples. To monitor contamination during the 2005 International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) deep drilling of the Chesapeake Bay impact structure, four methods were utilized. Fluorescent microspheres were used to mimic the ability of contaminant cells to enter samples through fractures in the core material during retrieval. Drilling mud was infused with a chemical tracer (Halon 1211) in order to monitor penetration of mud into cores. Pore water from samples was examined using excitation-emission matrix (EEM) fl uorescence spectroscopy to characterize dissolved organic carbon (DOC) present at various depths. DOC signatures at depth were compared to signatures from drilling mud in order to identify potential contamination. Finally, microbial contaminants present in drilling mud were identified through 16S ribosomal deoxyribonucleic acid (rDNA) clone libraries and compared to species cultured from core samples. Together, these methods allowed us to categorize the recovered core samples according to the likelihood of contamination. Twenty-two of the 47 subcores that were retrieved were free of contamination by all the methods used and were subsequently used for microbiological culture and culture-independent analysis. Our approach provides a comprehensive assessment of both particulate and dissolved contaminants that could be applied to any environment with low biomass. ?? 2009 The Geological Society of America.

Contamination Control for Scientific Drilling Operations.

PubMed

Kallmeyer, J

2017-01-01

Drilling is an integral part of subsurface exploration. Because almost all drilling operations require the use of a drill fluid, contamination by infiltration of drill fluid into the recovered core material cannot be avoided. Because it is impossible to maintain sterile conditions during drilling the drill fluid will contain surface microbes and other contaminants. As contamination cannot be avoided, it has to be tracked to identify those parts of the drill core that were not infiltrated by the drill fluid. This is done by the addition of tracer compounds. A great variety of tracers is available, and the choice depends on many factors. This review will first explain the basic principles of drilling before presenting the most common tracers and discussing their strengths and weaknesses. The final part of this review presents a number of key questions that have to be addressed in order to find the right tracer for a particular drilling operation. Copyright © 2017 Elsevier Inc. All rights reserved.

Identifying past petroleum exploration related drill cutting releases and influences on the marine environment and benthic foraminiferal communities, Goliat Field, SW Barents Sea, Norway.

PubMed

Aagaard-Sørensen, Steffen; Junttila, Juho; Dijkstra, Noortje

2018-04-01

The present multiproxy investigation of marine sediment cores aims at: 1) Identifying dispersion of petroleum exploration related drill cutting releases within the Goliat Field, Barents Sea in 2006/07 and 2) Assessing past and present influence of drill cuttings on the marine environment. The cores were recovered 5, 30, 60, 125 and 250m from the drill site in the eastward downstream direction. Downstream dispersion of drill cuttings is evaluated by examining sediment grain size distribution and barium (Ba), heavy metal, total organic carbon and sulphur concentrations. Dispersion of drill cuttings was limited to <125m east from the drill site. Influence of drill cutting releases on the marine environment is assessed via microfaunal analysis of primarily calcareous benthic foraminifera. The findings suggest contemporaneous physical smothering at ≤30m from the drill site, with a natural fauna reestablishing after drilling cessation indicating no long-term effect of drill cutting releases. Copyright © 2017 Elsevier Ltd. All rights reserved.

The Hominin Sites and Paleolakes Drilling Project (HSPDP): Understanding the paleoenvironmental and paleoclimatic context of human origins through continental drilling

NASA Astrophysics Data System (ADS)

Cohen, Andrew S.; Campisano, Christopher; Asrat, Asfawossen; Arrowsmith, Ramon; Deino, Alan; Feibel, Craig; Hill, Andrew; Kingston, John; Lamb, Henry; Lowenstein, Tim; Olago, Daniel; Bernhart Owen, R.; Renaut, Robin; Schabitz, Frank; Trauth, Martin

2015-04-01

The influence of climate and environmental history on human evolution is an existential question that continues to be hotly debated, in part because of the paucity of high resolution records collected in close proximity to the key fossil and archaeological evidence. To address this issue and transform the scientific debate, the HSPDP was developed to collect lacustrine sediment drill cores from basins in Kenya and Ethiopia that collectively encompass critical time intervals and locations for Plio-Quaternary human evolution in East Africa. After a 17 month campaign, drilling was completed in November, 2014, with over 1750m of core collected from 11 boreholes from five areas (1930m total drilling length, avg. 91% recovery). The sites, from oldest to youngest, include 1) N. Awash, Ethiopia (~3.5-2.9Ma core interval); 2) Baringo-Tugen Hills, Kenya (~3.3-2.5Ma); 3) West Turkana, Kenya (~1.9-1.4Ma); L. Magadi, Kenya (0.8-0Ma) and the Chew Bahir Basin, Ethiopia (~0.5-0Ma). Initial core description (ICD) and sampling for geochronology, geochemistry and paleoecology studies had been completed by mid2014, with the two remaining sites (Magadi and Chew Bahir) scheduled for ICD work in early 2015. Whereas the primary scientific targets were the lacustrine deposits from the hominin-bearing basin depocenters, many intervals of paleosols (representative of low lake stands and probable arid periods) were also encountered in drill cores. Preliminary analyses of drill core sedimentology and geochemistry show both long-term lake level changes and cyclic variability in lake levels, both of which may be indicative of climatic forcing events of interest to paleoanthropologists. Authors of this abstract also include the entire HSPDP field team.

Modeling σ-Bond Activations by Nickel(0) Beyond Common Approximations: How Accurately Can We Describe Closed-Shell Oxidative Addition Reactions Mediated by Low-Valent Late 3d Transition Metal?

PubMed

Hu, Lianrui; Chen, Kejuan; Chen, Hui

2017-10-10

Accurate modelings of reactions involving 3d transition metals (TMs) are very challenging to both ab initio and DFT approaches. To gain more knowledge in this field, we herein explored typical σ-bond activations of H-H, C-H, C-Cl, and C-C bonds promoted by nickel(0), a low-valent late 3d TM. For the key parameters of activation energy (ΔE ‡ ) and reaction energy (ΔE R ) for these reactions, various issues related to the computational accuracy were systematically investigated. From the scrutiny of convergence issue with one-electron basis set, augmented (A) basis functions are found to be important, and the CCSD(T)/CBS level with complete basis set (CBS) limit extrapolation based on augmented double-ζ and triple-ζ basis pair (ADZ and ATZ), which produces deviations below 1 kcal/mol from the reference, is recommended for larger systems. As an alternative, the explicitly correlated F12 method can accelerate the basis set convergence further, especially after its CBS extrapolations. Thus, the CCSD(T)-F12/CBS(ADZ-ATZ) level with computational cost comparable to the conventional CCSD(T)/CBS(ADZ-ATZ) level, is found to reach the accuracy of the conventional CCSD(T)/A5Z level, which produces deviations below 0.5 kcal/mol from the reference, and is also highly recommendable. Scalar relativistic effects and 3s3p core-valence correlation are non-negligible for achieving chemical accuracy of around 1 kcal/mol. From the scrutiny of convergence issue with the N-electron basis set, in comparison with the reference CCSDTQ result, CCSD(T) is found to be able to calculate ΔE ‡ quite accurately, which is not true for the ΔE R calculations. Using highest-level CCSD(T) results of ΔE ‡ in this work as references, we tested 18 DFT methods and found that PBE0 and CAM-B3LYP are among the three best performing functionals, irrespective of DFT empirical dispersion correction. With empirical dispersion correction included, ωB97XD is also recommendable due to its improved performance.

Initial report on drilling into seismogenic zones of M2.0 - M5.5 earthquakes from deep South African gold mines (DSeis)

NASA Astrophysics Data System (ADS)

Ogasawara, Hiroshi; Durrheim, Raymond; Yabe, Yasuo; Ito, Takatoshi; van Aswegen, Gerrie; Grobbelaar, Michelle; Funato, Akio; Ishida, Akimasa; Ogasawara, Hiroyuki; Mngadi, Siyanda; Manzi, Musa; Ziegler, Martin; Ward, Tony; Moyer, Pamela; Boettcher, Margaret; Ellsworth, Bill; Liebenberg, Bennie; Wechsler, Neta; Onstott, Tullis; Berset, Nicolas

2017-04-01

The International Continental Scientific Drilling Program (ICDP) approved our proposal (Ogasawara et al., EGU 2016) to drill into and around seismogenic zones where critically stressed faults initiated ruptures at depth. The drilling targets include four ruptures equivalent to M2.0, 2.8, 3.5, and 5.5 that dynamically and quasi-statically evolved in 2.9 Ga hard rock in the Witwatersrand basin, South Africa. Major advantages of our drilling locations are the large quantity and high-quality of existing data from dense seismic arrays both on surface and near-field underground in three deep South African gold mines. Additionally, the great depths (1.0 to 3.3 km from surface) to collar holes reduce drilling costs significantly and enable a larger number of holes to be drilled. Flexibility in drilling direction will also allow us to minimize damage in borehole or drilled cores. With the ICDP funds, we will conduct full-core drilling of 16 holes with drilling ranges from 50 to 750 m to recover both materials and fractures in and around the seismogenic zones, followed by core and borehole logging. Additional in-hole monitoring at close proximity will be supported by co-mingled funds and will follow the ICDP drilling. Expected magnitudes of maximum shear stress are several tens of MPa. We have established an overcoring procedure to measure 3D-stress state for adverse underground working conditions so as not to interfere with mining operations. This procedure was optimized based on the Compact Conic-ended Borehole Overcoring (CCBO) technique (ISRM suggested; Sugawara and Obara, 1999). Funato and Ito (2016 IJRMMS) developed a diametrical core deformation analysis (DCDA) method to measure differential stress using only drilled core by assuming diametrical change with roll angles caused by elastic in-axisymmetrical expansion during drilling. A gold mine has already drilled a hole to intersect the hypocenter of a 2016 M3.5 earthquake and carried out the CCBO stress measurement in other holes at the M3.5 seismogenic zone. As we successfully conducted DCDA with the above-mentioned drilled core, we look forward to shedding light on spatial variations of stress in the seismogenic zones following our ICDP DSeis drilling. A M5.5 earthquake which took place near Orkney, South Africa on 5 August 2014, offers a special opportunity to compare seismically inverted spatio-temporal evolution of both the main rupture and the aftershock activity with the information directly probed by the ICDP DSeis project. Moyer et al. (2016 Seismol. Res. Lett. submitted) calls for comparing seismic source models as part of a workshop proposed to the Southern California Earthquake Center for Fall 2017. In addition, the upper edge of the M5.5 rupture is located hundreds of meters below the mining horizon, sufficiently away from anthropogenic activity. This allows geomicrobiologists to investigate deep microbiological activity fueled by H2 from seismic rupture to address questions about Earth's early life. Drilling machines are being rigged underground soon to kick off our ICDP DSeis drilling in early 2017.

Utilization of fluorescent microspheres and a green fluorescent protein-marked strain for assessment of microbiological contamination of permafrost and ground ice core samples from the Canadian High Arctic.

PubMed

Juck, D F; Whissell, G; Steven, B; Pollard, W; McKay, C P; Greer, C W; Whyte, L G

2005-02-01

Fluorescent microspheres were applied in a novel fashion during subsurface drilling of permafrost and ground ice in the Canadian High Arctic to monitor the exogenous microbiological contamination of core samples obtained during the drilling process. Prior to each drill run, a concentrated fluorescent microsphere (0.5-microm diameter) solution was applied to the interior surfaces of the drill bit, core catcher, and core tube and allowed to dry. Macroscopic examination in the field demonstrated reliable transfer of the microspheres to core samples, while detailed microscopic examination revealed penetration levels of less than 1 cm from the core exterior. To monitor for microbial contamination during downstream processing of the permafrost and ground ice cores, a Pseudomonas strain expressing the green fluorescent protein (GFP) was painted on the core exterior prior to processing. Contamination of the processed core interiors with the GFP-expressing strain was not detected by culturing the samples or by PCR to detect the gfp marker gene. These methodologies were quick, were easy to apply, and should help to monitor the exogenous microbiological contamination of pristine permafrost and ground ice samples for downstream culture-dependent and culture-independent microbial analyses.

Utilization of Fluorescent Microspheres and a Green Fluorescent Protein-Marked Strain for Assessment of Microbiological Contamination of Permafrost and Ground Ice Core Samples from the Canadian High Arctic

PubMed Central

Juck, D. F.; Whissell, G.; Steven, B.; Pollard, W.; McKay, C. P.; Greer, C. W.; Whyte, L. G.

2005-01-01

Fluorescent microspheres were applied in a novel fashion during subsurface drilling of permafrost and ground ice in the Canadian High Arctic to monitor the exogenous microbiological contamination of core samples obtained during the drilling process. Prior to each drill run, a concentrated fluorescent microsphere (0.5-μm diameter) solution was applied to the interior surfaces of the drill bit, core catcher, and core tube and allowed to dry. Macroscopic examination in the field demonstrated reliable transfer of the microspheres to core samples, while detailed microscopic examination revealed penetration levels of less than 1 cm from the core exterior. To monitor for microbial contamination during downstream processing of the permafrost and ground ice cores, a Pseudomonas strain expressing the green fluorescent protein (GFP) was painted on the core exterior prior to processing. Contamination of the processed core interiors with the GFP-expressing strain was not detected by culturing the samples or by PCR to detect the gfp marker gene. These methodologies were quick, were easy to apply, and should help to monitor the exogenous microbiological contamination of pristine permafrost and ground ice samples for downstream culture-dependent and culture-independent microbial analyses. PMID:15691963

Lake Eĺ gygytgyn Drilling under way: State of the operation and first results

NASA Astrophysics Data System (ADS)

Melles, M.; Brigham-Grette, J.; Minyuk, P.; Koeberl, C.; Scientific Party, EĺGygytgyn

2009-04-01

Lake Eĺgygytgyn, located in central Chukotka, NE Siberia, was formed 3.6 million years ago by a meteorite impact and has never been glaciated or desiccated. This makes Lake Eĺgygytgyn a unique target of an interdisciplinary, multi-national drilling campaign, which currently is carried out as part of the International Continental Drilling Program (ICDP). Drilling operations started in Nov./Dec. 2008, when a 142 m long sediment core was retrieved from the permafrost deposits in the western lake catchment by the local drilling company Chaun Mine Geological Company (CGE). The core penetrated coarse-grained, ice-rich alluvial sediments with variable contents of fine-grained material. It will be investigated for the environmental history, including potential lake-level changes, and the permafrost characteristics, in order to learn more about the influences of catchment changes on the lake sedimentation. Besides, the hole was permanently instrumented for future ground temperature monitoring as part of the Global Terrestrial Network for Permafrost (www.gtnp.org/index_e.html). The major drilling effort will commence in Febr. 2009, when two sites in the central part of Lake Eĺgygytgyn shall be drilled down to 630 m below the lake floor. Drilling will be carried out by DOSECC, using a new GLAD 800 system that will be operated from an enclosed platform on the lake ice. Drilling objectives include replicate overlapping cores from the up to 420 m thick lake sediment fill. The cores promise to yield the longest, most continuous record of climate change in the terrestrial Arctic, extending back one million years prior to the intensification of the Northern Hemisphere Glaciation at the Pliocene/Pleistocene boundary, thus offering unique insight into the climatic and environmental history of the Arctic and its comparison with records from lower latitude marine and terrestrial sites to better understand hemispheric and global climate change. Coring shall be continued up to 300 m into the underlying impact breccia and brecciated bedrock in order to additionally investigate the impact process and the response of the volcanic bedrock to the impact event. The field season will continue into May, when surface melting on the lake will push to start evacuation of the drill rig. In summer 2009, the cores will be flown by chartered cargo plane to St. Petersburg. Later they will be trucked to the University of Cologne, Germany, for sub-sampling starting in September by the international team and their students. The archive core halves will be shipped to the University of Minnesota LacCore Facility in the US for post-moratorium studies. This talk will provide an introduction into the drilling objectives, summarize the first conclusions that can be drawn from the field data, and outline the next steps towards multidisciplinary investigation of the core material by the international science team.

Study of sample drilling techniques for Mars sample return missions

NASA Technical Reports Server (NTRS)

Mitchell, D. C.; Harris, P. T.

1980-01-01

To demonstrate the feasibility of acquiring various surface samples for a Mars sample return mission the following tasks were performed: (1) design of a Mars rover-mounted drill system capable of acquiring crystalline rock cores; prediction of performance, mass, and power requirements for various size systems, and the generation of engineering drawings; (2) performance of simulated permafrost coring tests using a residual Apollo lunar surface drill, (3) design of a rock breaker system which can be used to produce small samples of rock chips from rocks which are too large to return to Earth, but too small to be cored with the Rover-mounted drill; (4)design of sample containers for the selected regolith cores, rock cores, and small particulate or rock samples; and (5) design of sample handling and transfer techniques which will be required through all phase of sample acquisition, processing, and stowage on-board the Earth return vehicle. A preliminary design of a light-weight Rover-mounted sampling scoop was also developed.

Operations Summary During Riserless Drilling to >7700 mbsl in the Japan Trench for IODP Expedition 343 & 343T: JFAST, and Discussion of the Relationship Between Drilling Parameters and Rock Damage.

NASA Astrophysics Data System (ADS)

Toy, V. G.; Maeda, L.; Toczko, S.; Eguchi, N.; Chester, F. M.; Mori, J. J.; Sawada, I.; Saruhashi, T.

2014-12-01

During IODP Expedition 343: The Japan Trench Fast Drilling Project (JFAST), two main boreholes were drilled from the D/V Chikyu in ~7000 m water depth. An uncored hole that penetrated to 850.5 meters below seafloor (mbsf) (total depth [TD] = 7740 meters below sea level [mbsl]) was documented using logging while drilling (LWD) tools. From an adjacent partially cored hole drilled to 844.5 mbsf (TD = 7734 mbsl) 21 cores were acquired that spanned the two main fault targets. The operations lasted 88 days. The drilling operation was very technically challenging. The drill string had to be withdrawn a number of times due to high seas, and technical issues; five holes were drilled (one abandoned after spud-in) and reoccupied in >6800 m water depth. A simple observatory was deployed in the wellhead installed during Exp 343 during the follow-up Exp 343T. In certain intervals during coring we mostly recovered loose, subrounded fine gravel clasts of the two major lithologies penetrated to those depths (silt and mudstones). We have performed particle shape and size analysis on these gravel aggregates. Particle shape variations apparent visually are not clearly quantified by conventional 'shape descriptors'. Variations in particle size distributions are apparent and we will discuss whether these relate to variations in drilling parameters.

Rapid Access Ice Drill: A New Tool for Exploration of the Deep Antarctic Ice Sheets and Subglacial Geology

NASA Astrophysics Data System (ADS)

Goodge, J. W.; Severinghaus, J. P.

2014-12-01

The Rapid Access Ice Drill (RAID) will penetrate the Antarctic ice sheets in order to core through deep ice, the glacial bed, and into bedrock below. This new technology will provide a critical first look at the interface between major ice caps and their subglacial geology. Currently in construction, RAID is a mobile drilling system capable of making several long boreholes in a single field season in Antarctica. RAID is interdisciplinary and will allow access to polar paleoclimate records in ice >1 Ma, direct observation at the base of the ice sheets, and recovery of rock cores from the ice-covered East Antarctic craton. RAID uses a diamond rock-coring system as in mineral exploration. Threaded drill-pipe with hardened metal bits will cut through ice using reverse circulation of Estisol for pressure-compensation, maintenance of temperature, and removal of ice cuttings. Near the bottom of the ice sheet, a wireline bottom-hole assembly will enable diamond coring of ice, the glacial bed, and bedrock below. Once complete, boreholes will be kept open with fluid, capped, and made available for future down-hole measurement of thermal gradient, heat flow, ice chronology, and ice deformation. RAID will also sample for extremophile microorganisms. RAID is designed to penetrate up to 3,300 meters of ice and take sample cores in less than 200 hours. This rapid performance will allow completion of a borehole in about 10 days before moving to the next drilling site. RAID is unique because it can provide fast borehole access through thick ice; take short ice cores for paleoclimate study; sample the glacial bed to determine ice-flow conditions; take cores of subglacial bedrock for age dating and crustal history; and create boreholes for use as an observatory in the ice sheets. Together, the rapid drilling capability and mobility of the drilling system, along with ice-penetrating imaging methods, will provide a unique 3D picture of the interior Antarctic ice sheets.

Arthroscopic-assisted core decompression of the humeral head.

PubMed

Dines, Joshua S; Strauss, Eric J; Fealy, Stephen; Craig, Edward V

2007-01-01

Humeral head osteonecrosis is a progressive disease that requires prompt diagnosis and treatment. Core decompression is a viable treatment option for early-stage cases. Most surgeons perform core decompression by arthroscopically visualizing the necrotic area of bone and using a cannulated drill to take a core. Several attempts are frequently needed to reach the proper location. In the hip multiple passes are associated with complications. We describe the use of an anterior cruciate ligament (ACL) tibial drill guide to precisely localize the area of necrotic bone. Diagnostic arthroscopy is performed to assess the areas of osteonecrosis. Core decompression is performed by use of an ACL tibial guide, brought in through the anterior or posterior portal to precisely localize the necrotic area in preparation for drilling. Under image intensification, Steinmann pins are advanced into the area of osteonecrosis. Once positioned, several 4-mm cores are made. We treated 3 patients with this technique, and all had immediate pain relief. The use of the ACL guide allows precise localization of the area of humeral head involvement and avoids multiple drillings into unaffected areas. Initial indications are that arthroscopic-assisted core decompression with an ACL guide is an effective alternative to previously used methods.

Magma-Hydrothermal Transition: Basalt Alteration at Supercritical Conditions in Drill Core from Reykjanes, Iceland, Iceland Deep Drilling Project.

NASA Astrophysics Data System (ADS)

Zierenberg, R. A.; Fowler, A. P.; Schiffman, P.; Fridleifsson, G. Ó.; Elders, W. A.

2017-12-01

The Iceland Deep Drilling Project well IDDP-2, drilled to 4,659 m in the Reykjanes geothermal system, the on-land extension of the Mid Atlantic Ridge, SW Iceland. Drill core was recovered, for the first time, from a seawater-recharged, basalt-hosted hydrothermal system at supercritical conditions. The well has not yet been allowed to heat to in situ conditions, but temperature and pressure of 426º C and 340 bar was measured at 4500 m depth prior to the final coring runs. Spot drill cores were recovered between drilling depths of 3648.00 m and 4657.58 m. Analysis of the core is on-going, but we present the following initial observations. The cored material comes from a basaltic sheeted dike complex in the brittle-ductile transition zone. Felsic (plagiogranite) segregation veins are present in minor amounts in dikes recovered below 4300 m. Most core is pervasively altered to hornblende + plagioclase, but shows only minor changes in major and minor element composition. The deepest samples record the transition from the magmatic regime to the presently active hydrothermal system. Diabase near dike margins has been locally recrystallized to granoblastic-textured orthopyroxene-clinopyroxe-plagioclase hornfels. High temperature hydrothermal alteration includes calcic plagioclase (up to An100) and aluminous hornblende (up to 11 Wt. % Al2O3) locally intergrown with hydrothermal biotite, clinopyroxene, orthopyroxene and/or olivine. Hydrothermal olivine is iron-rich (Mg # 59-64) compared to expected values for igneous olivine. Biotite phenocrysts in felsic segregation veins have higher Cl and Fe compared to hydrothermal biotites. Orthopyroxene-clinopyroxene pairs in partially altered quench dike margins give temperature of 955° to 1067° C. Orthopyroxene-clinopyroxene pairs from hornfels and hydrothermal veins and replacements give temperature ranging from 774° to 888° C. Downhole fluid sampling is planned following thermal equilibration of the drill hole. Previous work has suggested that the Reykjanes geothermal system has been active since the last glaciation, 10ka. No shallow melt bodies have been detected on the Reykjanes Peninsula suggesting that hydrothermal circulation typical of black smoker systems can be sustained with out a magmatic heat source.

The ethane + oxygen(,2) reaction mechanism: High-level ab initio characterizations

NASA Astrophysics Data System (ADS)

Rienstra-Kiracofe, Jonathan C.

The C2H˙5+O2 reaction, central to ethane oxidation and thus of fundamental importance to hydrocarbon combustion chemistry, has been examined in detail via highly sophisticated electronic structure methods. The geometries, energies, and harmonic vibrational frequencies of the reactants, transition states, intermediates, and products for the reaction of the ethyl radical (X~ 2A ') with O2 (X S-g3 , a 1Δg) have been investigated using the CCSD and CCSD(T) ab initio methods with basis sets ranging in quality from double-zeta plus polarization (DZP) to triple-zeta plus double polarization with f functions (TZ2Pf). Five mechanisms (M1-M5) involving the ground-state from the ethyl radical by O2 to give ethylene + HO˙2 with an overall 0 K activation energy, Ea(0 K) = +15.1 kcal mol-1 with CCSD(T)/TZ2Pf//CCSD(T)/TZ2P. (M2) Ethylperoxy β- hydrogen transfer with O-O bond rupture to yield oxirane + .OH Ea(0 K) = +5.3 kcal mol-1 with CCSD(T)/TZ2Pf//CCSD(T)/TZ2P. (M3) Ethylperoxy α- hydrogen transfer with O-O bond rupture to yield acetaldehyde + .OH Ea(0 K) = +11.5 kcal mol-1 with CCSD(T)/TZ2P//CCSD(T)/DZP. (M4) Ethylperoxy β- hydrogen transfer with C-O bond rupture to yield ethylene + HO˙2 ; Ea(0 K) = +5.3 kcal mol-1 with CCSD(T)/TZ2Pf//CCSD(T)/TZ2P, the C-O bond rupture barrier lying 1.2 kcal mol-1 above the O-O bond rupture barrier of M2 at the CCSD(T)/TZ2P//CCSD(T)/DZP level. (M5) Concerted elimination of HO˙2 from the ethylperoxy radical to give ethylene + HO˙2 ; Ea(0 K) = -0.9 kcal mol -1 with CCSD(T)/TZPf//CCSD(T)/TZ2P. We show that M5 is energetically preferred and is also the only mechanism consistent with experimental observations of a negative temperature coefficient. The reverse reaction (C2H 4 + HO˙2 --> .C2H4OOH) has a zero-point corrected barrier of 14.4 kcal mol-1 with CCSD(T)/TZ2P//CCSD(T)/DZP.

Drilling Regolith: Why Is It So Difficult?

NASA Astrophysics Data System (ADS)

Schmitt, H. H.

2017-10-01

The Apollo rotary percussive drill system penetrated the lunar regolith with reasonable efficiency; however, extraction of the drill core stem proved to be very difficult on all three missions. Retractable drill stem flutes may solve this problem.

Esmeralda Energy Company, Final Scientific Technical Report, January 2008. Emigrant Slimhole Drilling Project, DOE GRED III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deymonaz, John; Hulen, Jeffrey B.; Nash, Gregory D.

2008-01-22

The Emigrant Slimhole Drilling Project (ESDP) was a highly successful, phased resource evaluation program designed to evaluate the commercial geothermal potential of the eastern margin of the northern Fish Lake Valley pull-apart basin in west-central Nevada. The program involved three phases: (1) Resource evaluation; (2) Drilling and resource characterization; and (3) Resource testing and assessment. Efforts included detailed geologic mapping; 3-D modeling; compilation of a GIS database; and production of a conceptual geologic model followed by the successful drilling of the 2,938 foot deep 17-31 slimhole (core hole), which encountered commercial geothermal temperatures (327⁰ F) and exhibits an increasing, conductive,more » temperature gradient to total depth; completion of a short injection test; and compilation of a detailed geologic core log and revised geologic cross-sections. Results of the project greatly increased the understanding of the geologic model controlling the Emigrant geothermal resource. Information gained from the 17-31 core hole revealed the existence of commercial temperatures beneath the area in the Silver Peak Core Complex which is composed of formations that exhibit excellent reservoir characteristics. Knowledge gained from the ESDP may lead to the development of a new commercial geothermal field in Nevada. Completion of the 17-31 core hole also demonstrated the cost-effectiveness of deep core drilling as an exploration tool and the unequaled value of core in understanding the geology, mineralogy, evolutional history and structural aspects of a geothermal resource.« less

Defining Lithological Units by Cuttings, Core and Logging Data at Site C0009A in the Nankai Trough, Japan: IODP Expedition 319

NASA Astrophysics Data System (ADS)

Efimenko, N.; Schleicher, A. M.; Buchs, D. M.; Buret, C.; Kawabata, K.; Boutt, D. F.; Underwood, M.; Araki, E.; Byrne, T. B.; McNeill, L. C.; Saffer, D. M.; Eguchi, N. O.; Takahashi, K.; Toczko, S.; Scientists, E.

2009-12-01

The use of cuttings as an alternative or addition to core material is broadly debated in on-shore and off-shore drilling expeditions. Expedition 319 is the first IODP based Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) project using the riser-drilling method to collect cutting and core samples for scientific studies. One major scientific objective for this site was to characterise the lithology and deformation history of the Kumano forearc basin sediments and its underlying units through comparison of (i) cuttings, (ii) core, (iii) measurements while drilling, and (iv) wireline logging data. Cuttings were retrieved from each 5 m intervals from 703.9 to 1604 m, and cores were recovered from 1509.7 to 1593.9 m below sea floor. As core availability was limited, the study of cuttings was a crucial step in improving our understanding of their potential and limits for lithostratigraphical interpretations compared to core. Mineralogical and chemical analysis of cuttings and core, wireline logging data, and gamma ray data from MWD were available to define four lithostratigraphic units. These units are composed of mud and mudstone with coarser silty and sandy interbeds, and volcanic ash/tuff. Consistency between unit boundaries determined from cuttings and those determined from log data is good in terms of depth, with typical mismatches of less than 10m. Three significant problems affecting the preservation of cuttings were (1) mixing of cuttings as they travel from the drill face to the surface, (2) alteration of natural mineral and structure signatures, and (3) possible contamination from natural clay minerals with the polymer/bentonite drill mud. These difficulties can be overcome in part through the analysis of cuttings of similar sizes (1-4 mm), guided by the analyses of bulk cuttings. A more accurate quantitative characterisation of cuttings through the use of digital imaging might improve the description of lithofacies. Although the quality of cuttings is affected by caving and drilling mud contamination, our results clearly indicate that cuttings retrieval is a viable alternative to coring in ocean drilling. However, to improve the precision of lithostratigraphical observations and interpretations in critical intervals, the study of cores is needed.

Mineralogy of Gas Hydrate Bearing Sediment in Green Canyon Block 955 Northern Gulf of Mexico

NASA Astrophysics Data System (ADS)

Heber, R.; Kinash, N.; Cook, A.; Sawyer, D.; Sheets, J.; Johnson, J. E.

2017-12-01

Natural gas hydrates are of interest as a future hydrocarbon source, however, the formation and physical properties of such systems are not fully understood. In May 2017, the University of Texas drilled two holes in Green Canyon Block 955, northern Gulf of Mexico to collect pressurized core from a thick, 100 m accumulation of gas hydrate in a silt dominated submarine canyon levee system. The expedition, known as UT-GOM2-01, collected 21, 10-m pressure cores from Holes H002 and H005. Approximately half of the cores successfully pressurized and were fully recovered. Unsuccessful cores that did not pressurize generally had low core recovery. By analyzing the sediment composition in known gas hydrate reservoirs, we can construct a more detailed picture of how and why gas hydrates accumulate, as mineralogy can affect physical properties such as porosity and permeability as well as geophysical measurements such as resistivity. Using X-ray diffraction (XRD) on bulk sediment powders, we determined the bulk mineralogy of the samples. Moreover, we investigated drilling mud contamination using XRD and light optical analysis. In some cores, contamination was easily recognized visually as dense sludge between the core barrel and the recovered sediment core, however drilling mud is best observed both along the liner and interbedded within the sediment on X-ray computed tomography scans. To fully identify the presence and influence of drilling mud, we use XRD to analyze samples on cores collected both while drilling mud was used in hole and when only seawater was used in hole and consider the density anomalies observed on the XCT scans. The preliminary XRD light optical microscopy results show that the silt-dominated reservoir is primarily composed of quartz, with minor alkali feldspar, amphibole, muscovite, dolomite, and calcite. Samples from intervals with suspected drilling mud contamination show a similar composition, but with the addition of barite, a common component in drilling mud. Understanding why contamination occurs will improve the coring process and ensure maximum recovery in the future. The XRD data also show the presence of 7-angstrom clay minerals, most likely chlorite and serpentine, but more analysis is required in order to verify the identification and to establish relative abundances of each mineral.

Benthic foraminiferal responses to operational drill cutting discharge in the SW Barents Sea - a case study.

NASA Astrophysics Data System (ADS)

Aagaard-Sørensen, Steffen; Junttila, Juho; Dijkstra, Noortje

2016-04-01

Petroleum related exploration activities started in the Barents Sea 1980, reaching 97 exploration wells drilled per January 2013. The biggest operational discharge from drilling operations in the Barents Sea is the release of drill cuttings (crushed seabed and/or bedrock) and water based drilling muds including the commonly used weighing material barite (BaSO4). Barium (Ba), a constituent of barite, does not degrade and can be used to evaluate dispersion and accumulation of drill waste. The environmental impact associated with exploration drilling within the Goliat Field, SW Barents Sea in 2006 was evaluated via a multiproxy investigation of local sediments. The sediments were retrieved in November 2014 at ~350 meters water depth and coring sites were selected at distances of 5, 30, 60, 125 and 250 meters from the drill hole in the eastward downstream direction. The dispersion pattern of drill waste was estimated via measurements of sediment parameters including grain size distribution and water content in addition to heavy metal and total organic carbon contents. The environmental impact was evaluated via micro faunal analysis based on benthic foraminiferal (marine shell bearing protists) fauna composition and concentration changes. Observing the sediment parameters, most notably Ba levels, reveals that dispersion of drill waste was limited to <125 meters from the drill site with drill waste thicknesses decreasing downstream. The abruptness and quantity of drill waste sedimentation initially smothered the foraminiferal fauna at ≤ 30 meters from the drill site, while at a distance of 60 meters, the fauna seemingly survived and bioturbation persisted. Analysis of the live (Nov 2014) foraminiferal fauna reveals a natural species composition at all distances from the drill site within the top sediments (0-5 cm core depth). Furthermore, the fossil foraminiferal fauna composition found within post-impacted top sediment sections, particularly in the cores situated at 30 and 60 meters from the drill site, suggests that reestablishment of the foraminiferal fauna likely commenced shortly after cessation of drilling activity.

ICDP drilling in the Scandinavian Caledonides: the SDDP-COSC project

NASA Astrophysics Data System (ADS)

Lorenz, Henning; Juhlin, Christopher; Gee, David; Pascal, Christophe; Tsang, Chin-Fu; Pedersen, Karsten; Rosberg, Jan-Erik

2013-04-01

The Swedish Deep Drilling Program (SDDP) Collisional Orogeny in the Scandinavian Caledonides (COSC) project is a multidisciplinary investigation of the Scandian mountain belt. Cenozoic uplift of the Scandes has exposed a lower- to middle-crustal level section through this Himalaya-type orogen, providing unique opportunities to better understand not only the Caledonides, but also on-going orogeny and the earthquake-prone environments of modern mountains belts. COSC will also contribute to our knowledge of mountain belt hydrology, provide the first information about deep thermal gradients for paleoclimate modeling and potential geothermal energy resources, contribute new information about the deep biosphere, and improve our understanding of the Cenozoic uplift history of the Scandes. The drilling program targets the far-traveled (> 400 km) allochthons of the Scandinavian Caledonides and their emplacement across the Baltoscandian foreland basin onto the platform of continent Baltica. Two 2.5 km deep holes are planned. COSC-1, to be drilled in the summer of 2013, will target the high-grade metamorphic complex of the Seve Nappes (SNC) and its contact to underlying allochthons. COSC-2 will start in the lower thrust sheets, pass through the basal décollement and investigate the character of the deformation in the underlying basement. An international science team, including expertise on Himalaya-Tibet and other young orogens, is running the science program. New high-resolution reflection seismic data provide excellent images of the upper crust. Alternative interpretations of the reflectors' origin, particularly those in the basement, will be tested. The site of COSC-1 is based on a 3D geological model, constructed from surface geology, recent and vintage regional reflection seismic profiles, regional and local gravity data, and high-resolution aeromagnetics, acquired recently by the Geological Survey of Sweden. The drilling will be carried out utilising the new Swedish scientific drilling infrastructure, located at Lund University, an Atlas Copco CT20 diamond core-drilling rig, with versatile drilling equipment (see EGU2012-7379), providing the ideal platform for core-drilling to 2.5 km depths. Existing drilling, sampling and testing techniques (e.g. triple-tube core drilling for best core quality) will need to be adapted to highly variable lithologies and new techniques will be developed, as necessary. COSC-1 drilling operations and the directly related on-site investigations are financed by ICDP and the Swedish Research Council. All drill cores will be transferred to the core repository of the Geological Survey of Sweden, and a sampling party will be announced later this year. Researchers who want to participate in COSC and contribute their expertise are encouraged to inform us of their interests.

Drilling into Magma: Experiences at Kīlauea Iki Lava Lake, Hawaii

NASA Astrophysics Data System (ADS)

Helz, R. L.

2017-12-01

Several historic lava lakes (1959 Kīlauea Iki, 1963 Alae, and 1965 Makaopuhi) were drilled in the 20th century, and molten core recovered from them. Kīlauea Iki lava lake, the most extensively studied, was drilled in 1960-62, 1967, 1965, 1976, 1979, 1981 and 1988. A total of 1400 m feet of core was recovered, about 210 m of which was partially molten. The melt fraction varied from near zero to 40-45% by volume, with higher fractions in glassy ooze from below the crust/melt interface. Most of the 1960-1979 drill holes terminated in pre-existing melt-rich internal differentiates; the later (1981, 1988) drill holes were mostly stopped arbitrarily. When melt was reached and the string backed off to wireline the last interval of core, black glassy ooze immediately moved up the borehole. Repeated re-entry and ooze recovery never exhausted the melt-rich sources. The first deep hole that did not hit melt was KI79-1, which was stopped at 62.2 m after recovering 12 m of molten mush. Here the uncased drill hole backfilled not with black glassy ooze but with olivine-rich, partly crystalline mush. The first redrilled core (recovered between 50.8 and 53.9 m), which moved up over a period of 16 days after termination of the original hole, underwent extensive separation of melt from crystals as it flowed upward. After this interval was pulled, drilling resumed with the bottom of the hole at 52.9 m, and uniform olivine-rich mush was recovered from 52.9-54.25 m. Drilling resumed once more at 52.9 m and a further 3 m of ooze recovered. The bit reached a depth of 55.4 m when the core barrel was full, suggesting that the crystal-rich mush was rising into the core barrel spontaneously during drilling. The three cores recovered in reentering KI79-1 show the effect of unloading the confining pressure on mush layers, with melt moving toward the low-pressure area (the bottom of the hole) relative to crystals. All of the crystal-rich mushes are more melt-rich than the original core, with elevated TiO2, K2O and P2O5 levels at the same bulk MgO content. Grain-to-grain contacts were progressively eroded in the melt-inflated mushes, so that the mushes had no internal cohesion. Although their melt contents never reached 50% by volume, they were extremely mobile, rising into the drill hole in minutes rather than the days required for the initial backfilling of the hole.

Historical Isotopic Temperature Record from the Vostok Ice Core (420,000 years BP-present)

DOE Data Explorer

Petit, J. R. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Raynaud, D. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Lorius, C. [Laboratoire de Glaciogie et Geophysique de l'Environnement; Jouzel, J. [Laboratoire des Sciences du Climat et de l'Environnement; Delaygue, G. [Laboratoire des Sciences du Climat et de l'Environnement; Barkov, N. I. [Arctic and Antarctic Research Inst. (AARI), St. Petersburg (Russian Federation); Kotlyakov, V. M. [Institute of Geography, Russia

2000-01-01

Because isotopic fractions of the heavier oxygen-18 (18O) and deuterium (D) in snowfall are temperature-dependent and a strong spatial correlation exists between the annual mean temperature and the mean isotopic ratio (18O or δD) of precipitation, it is possible to derive ice-core climate records. The record presented by Jouzel et al. (1987) was the first ice core record to span a full glacial-interglacial cycle. That record was based on an ice core drilled at the Russian Vostok station in central east Antarctica. The 2083-m ice core was obtained during a series of drillings in the early 1970s and 1980s and was the result of collaboration between French and former-Soviet scientists. Drilling continued at Vostok and was completed in January 1998, reaching a depth of 3623 m, the deepest ice core ever recovered (Petit et al. 1997, 1999). The resulting core allows the ice core record of climate properties at Vostok to be extended to ~420 kyr BP.

Neogene and Quaternary geology of a stratigraphic test hole on Horn Island, Mississippi Sound

USGS Publications Warehouse

Gohn, Gregory S.; Brewster-Wingard, G. Lynn; Cronin, Thomas M.; Edwards, Lucy E.; Gibson, Thomas G.; Rubin, Meyer; Willard, Debra A.

1996-01-01

During April and May, 1991, the U.S. Geological Survey (USGS) drilled a 510-ft-deep, continuously cored, stratigraphic test hole on Horn Island, Mississippi Sound, as part of a field study of the Neogene and Quaternary geology of the Mississippi coastal area. The USGS drilled two new holes at the Horn Island site. The first hole was continuously cored to a depth of 510 ft; coring stopped at this depth due to mechanical problems. To facilitate geophysical logging, an unsampled second hole was drilled to a depth of 519 ft at the same location.

Structure and binding energy of the H2S dimer at the CCSD(T) complete basis set limit.

PubMed

Lemke, Kono H

2017-06-21

This study presents results for the binding energy and geometry of the H 2 S dimer which have been computed using Møller-Plesset perturbation theory (MP2, MP4) and coupled cluster (CCSD, CCSD(T)) calculations with basis sets up to aug-cc-pV5Z. Estimates of D e , E ZPE , D o , and dimer geometry have been obtained at each level of theory by taking advantage of the systematic convergence behavior toward the complete basis set (CBS) limit. The CBS limit binding energy values of D e are 1.91 (MP2), 1.75 (MP4), 1.41 (CCSD), and 1.69 kcal/mol (CCSD[T]). The most accurate values for the equilibrium S-S distance r SS (without counterpoise correction) are 4.080 (MP2/aug-cc-pV5Z), 4.131 (MP4/aug-cc-pVQZ), 4.225 (CCSD/aug-cc-pVQZ), and 4.146 Å (CCSD(T)/aug-cc-pVQZ). This study also evaluates the effect of counterpoise correction on the H 2 S dimer geometry and binding energy. As regards the structure of (H 2 S) 2 , MPn, CCSD, and CCSD(T) level values of r SS , obtained by performing geometry optimizations on the counterpoise-corrected potential energy surface, converge systematically to CBS limit values of 4.099 (MP2), 4.146 (MP4), 4.233 (CCSD), and 4.167 Å (CCSD(T)). The corresponding CBS limit values of the equilibrium binding energy D e are 1.88 (MP2), 1.76 (MP4), 1.41 (CCSD), and 1.69 kcal/mol (CCSD(T)), the latter in excellent agreement with the measured binding energy value of 1.68 ± 0.02 kcal/mol reported by Ciaffoni et al. [Appl. Phys. B 92, 627 (2008)]. Combining CBS electronic binding energies D e with E ZPE predicted by CCSD(T) vibrational second-order perturbation theory calculations yields D o = 1.08 kcal/mol, which is around 0.6 kcal/mol smaller than the measured value of 1.7 ± 0.3 kcal/mol. Overall, the results presented here demonstrate that the application of high level calculations, in particular CCSD(T), in combination with augmented correlation consistent basis sets provides valuable insight into the structure and energetics of the hydrogen sulfide dimer.

Structure and binding energy of the H2S dimer at the CCSD(T) complete basis set limit

NASA Astrophysics Data System (ADS)

Lemke, Kono H.

2017-06-01

This study presents results for the binding energy and geometry of the H2S dimer which have been computed using Møller-Plesset perturbation theory (MP2, MP4) and coupled cluster (CCSD, CCSD(T)) calculations with basis sets up to aug-cc-pV5Z. Estimates of De, EZPE, Do, and dimer geometry have been obtained at each level of theory by taking advantage of the systematic convergence behavior toward the complete basis set (CBS) limit. The CBS limit binding energy values of De are 1.91 (MP2), 1.75 (MP4), 1.41 (CCSD), and 1.69 kcal/mol (CCSD[T]). The most accurate values for the equilibrium S-S distance rSS (without counterpoise correction) are 4.080 (MP2/aug-cc-pV5Z), 4.131 (MP4/aug-cc-pVQZ), 4.225 (CCSD/aug-cc-pVQZ), and 4.146 Å (CCSD(T)/aug-cc-pVQZ). This study also evaluates the effect of counterpoise correction on the H2S dimer geometry and binding energy. As regards the structure of (H2S)2, MPn, CCSD, and CCSD(T) level values of rSS, obtained by performing geometry optimizations on the counterpoise-corrected potential energy surface, converge systematically to CBS limit values of 4.099 (MP2), 4.146 (MP4), 4.233 (CCSD), and 4.167 Å (CCSD(T)). The corresponding CBS limit values of the equilibrium binding energy De are 1.88 (MP2), 1.76 (MP4), 1.41 (CCSD), and 1.69 kcal/mol (CCSD(T)), the latter in excellent agreement with the measured binding energy value of 1.68 ± 0.02 kcal/mol reported by Ciaffoni et al. [Appl. Phys. B 92, 627 (2008)]. Combining CBS electronic binding energies De with EZPE predicted by CCSD(T) vibrational second-order perturbation theory calculations yields Do = 1.08 kcal/mol, which is around 0.6 kcal/mol smaller than the measured value of 1.7 ± 0.3 kcal/mol. Overall, the results presented here demonstrate that the application of high level calculations, in particular CCSD(T), in combination with augmented correlation consistent basis sets provides valuable insight into the structure and energetics of the hydrogen sulfide dimer.

The 1997 core drilling through Ordovician and Silurian strata at Röstånga, S. Sweden: preliminary stratigraphic assessment and regional comparison

USGS Publications Warehouse

Bergstrom, Stig M.; Huff, W.D.; Koren', T.; Larsson, K.; Ahlberg, P.; Kolata, Dennis R.

1999-01-01

A core drilling at Ro??sta??nga, the first such drilling ever undertaken in this classical Lower Paleozoic outcrop area in W-central Scania, penetrated an approximately 96 m thick succession of Lower Silurian-upper Middle Ordovician marine rocks. The drilling was stopped at a depth of 132.59 m in an interval of crushed rocks, probably a prominent fault zone, that proved impossible to drill through. The core contains a stratigraphical sequence from the basal Upper Llandoverian (Telychian Stage) to the upper Middle Ordovician (Harjuan Stage). The following units are recognized in descending stratigraphic order (approximate thickness in parenthesis): Kallholn Formation (35 m), Lindega??rd Mudstone (27 m), Fja??cka Shale (13 m), Mossen Formation (0.75 m), Skagen Formation (2.5 m), and Sularp Shale (19 m+). Except for the Skagen Formation, the drilled sequence consists of shales and mudstones with occasional thin limestone interbeds and is similar to coeval successions elsewhere in Scania. There are 11 K-bentonite beds in the Kallholn Formation, 2(3?) in the Lindega??rd Mudstone, 1 in the Mossen Formation, 7 in the Skagen Formation, and 33 in the Sularp Shale. The core serves as an excellent Lower Silurian-upper Middle Ordovician reference standard not only for the Ro??sta??nga area but also for southernmost Sweden in general because the cored sequence is the stratigraphically most complete one known anywhere in this region.

Application program of CRUST-1 10km continental scientific drilling rig in SK-2 scientific drilling well

NASA Astrophysics Data System (ADS)

Sun, Youhong; Gao, Ke; Yu, Ping; Liu, Baochang; Guo, Wei; Ma, Yinlong; Yang, Yang

2014-05-01

SK-2 Well is located in DaQing city,where is site of the largest oil field in China,Heilongjiang province, north-east of China.The objective of SK-2 well is to obtain full cores of cretaceous formation in Song Liao basin,and to build the time tunnel of Cretaceous greenhouse climate change,and to clarify the causes,processes and results of the formations of DaQing oil field. This will ensure to achieve our ultimate goals,to test the CRUST-1 drilling rig and improve China's deep scientific drilling technology,to form the scientific drilling technology,method and system with independent intellectual property rights,and to provide technical knowledge and information for China's ten kilometers super-deep scientific drilling technical resources.SK-2 Well is at 6400 meter depth, where the drilling inclination is 90 degree and the continuous coring length is 3535 meter that from 2865 to 6400 meter,the recovery rate of the core is greater or equal to 95 percent with 100 millimeters core diameter and 3.9 degree per 100 meter geothermal gradient.The CRUST-1 rig is designated with special drilling equipment for continental scientific drilling combined to the oil drilling equipment ability with advanced geological drilling technology which is highly automatic and intelligent. CRUST-1 drilling ability is 10000 meter with the maximum hook load 700 tons, the total power is 4610 Kilowatt.CRUST-1 will be integrated with a complete set of automation equipment,including big torque hydraulic top drive,high accuracy automatic drilling rod feeding system, suspended automatic drill string discharge device,hydraulic intelligent iron roughneck,and hydraulic automatic catwalk to fully meet the drilling process requirements of SK-2.Designed with advanced drilling technique for 260 degree in the bottom of SK-2 well and hard rock,including the drilling tools of high temperature hydraulic hammer,high temperature resistance and high strength aluminum drill pipe,high temperature preparation of mud treatment and high temperature resistant cementing materials, and bionic bits,that is coupling bionic PDC tooth bit and diamond-impregnated bit for hard rock.All parts of CRUST-1 were successfully assembled along with the derrick and base lift and transported about 3456 kilometers from manufacture,GuangHan city in southwest China's Sichuan province,to the well site of SK-2 in end of 2013.SK-2 will be finished during next 4 years.

Contamination Tracer Testing With Seabed Rock Drills: IODP Expedition 357

NASA Astrophysics Data System (ADS)

Orcutt, B.; Bergenthal, M.; Freudenthal, T.; Smith, D. J.; Lilley, M. D.; Schneiders, L.; Fruh-Green, G. L.

2016-12-01

IODP Expedition 357 utilized seabed rock drills for the first time in the history of the ocean drilling program, with the aim of collecting intact core of shallow mantle sequences from the Atlantis Massif to examine serpentinization processes and the deep biosphere. This new drilling approach required the development of a new system for delivering synthetic tracers during drilling to assess for possible sample contamination. Here, we describe this new tracer delivery system, assess the performance of the system during the expedition, provide an overview of the quality of the core samples collected for deep biosphere investigations based on tracer concentrations, and make recommendations for future applications of the system.

Contamination tracer testing with seabed drills: IODP Expedition 357

NASA Astrophysics Data System (ADS)

Orcutt, Beth N.; Bergenthal, Markus; Freudenthal, Tim; Smith, David; Lilley, Marvin D.; Schnieders, Luzie; Green, Sophie; Früh-Green, Gretchen L.

2017-11-01

IODP Expedition 357 utilized seabed drills for the first time in the history of the ocean drilling program, with the aim of collecting intact sequences of shallow mantle core from the Atlantis Massif to examine serpentinization processes and the deep biosphere. This novel drilling approach required the development of a new remote seafloor system for delivering synthetic tracers during drilling to assess for possible sample contamination. Here, we describe this new tracer delivery system, assess the performance of the system during the expedition, provide an overview of the quality of the core samples collected for deep biosphere investigations based on tracer concentrations, and make recommendations for future applications of the system.

Laboratory Equipment for Investigation of Coring Under Mars-like Conditions

NASA Astrophysics Data System (ADS)

Zacny, K.; Cooper, G.

2004-12-01

To develop a suitable drill bit and set of operating conditions for Mars sample coring applications, it is essential to make tests under conditions that match those of the mission. The goal of the laboratory test program was to determine the drilling performance of diamond-impregnated bits under simulated Martian conditions, particularly those of low pressure and low temperature in a carbon dioxide atmosphere. For this purpose, drilling tests were performed in a vacuum chamber kept at a pressure of 5 torr. Prior to drilling, a rock, soil or a clay sample was cooled down to minus 80 degrees Celsius (Zacny et al, 2004). Thus, all Martian conditions, except the low gravity were simulated in the controlled environment. Input drilling parameters of interest included the weight on bit and rotational speed. These two independent variables were controlled from a PC station. The dependent variables included the bit reaction torque, the depth of the bit inside the drilled hole and the temperatures at various positions inside the drilled sample, in the center of the core as it was being cut and at the bit itself. These were acquired every second by a data acquisition system. Additional information such as the rate of penetration and the drill power were calculated after the test was completed. The weight of the rock and the bit prior to and after the test were measured to aid in evaluating the bit performance. In addition, the water saturation of the rock was measured prior to the test. Finally, the bit was viewed under the Scanning Electron Microscope and the Stereo Optical Microscope. The extent of the bit wear and its salient features were captured photographically. The results revealed that drilling or coring under Martian conditions in a water saturated rock is different in many respects from drilling on Earth. This is mainly because the Martian atmospheric pressure is in the vicinity of the pressure at the triple point of water. Thus ice, heated by contact with the rotating bit, sublimed and released water vapor. The volumetric expansion of ice turning into a vapor was over 150 000 times. This continuously generated volume of gas effectively cleared the freeze-dried rock cuttings from the bottom of the hole. In addition, the subliming ice provided a powerful cooling effect that kept the bit cold and preserved the core in its original state. Keeping the rock core below freezing also reduced drastically the chances of cross contamination. To keep the bit cool in near vacuum conditions where convective cooling is poor, some intermittent stops would have to be made. Under virtually the same drilling conditions, coring under Martian low temperature and pressure conditions consumed only half the power while doubling the rate of penetration as compared to drilling under Earth atmospheric conditions. However, the rate of bit wear was much higher under Martian conditions (Zacny and Cooper, 2004) References Zacny, K. A., M. C. Quayle, and G. A. Cooper (2004), Laboratory drilling under Martian conditions yields unexpected results, J. Geophys. Res., 109, E07S16, doi:10.1029/2003JE002203. Zacny, K. A., and G. A. Cooper (2004), Investigation of diamond-impregnated drill bit wear while drilling under Earth and Mars conditions, J. Geophys. Res., 109, E07S10, doi:10.1029/2003JE002204. Acknowledgments The research supported by the NASA Astrobiology, Science and Technology Instrument Development (ASTID) program.

Coal test drilling for the DE-NA-Zin Bisti Area, San Juan County, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilson, R.W.; Jentgen, R.W.

1980-01-01

From October 1978 to June 1979, the US Geological Survey (USGS) drilled 51 test holes, and cored 9 holes, in the vicinity of the Bisti Trading Post in the southwestern part of the San Juan Basin, San Juan County, New Mexico. The drilling was done in response to expressions of interest received by the Bureau of Land Management concerning coal leasing and, in some places, badlands preservation. The object of the drilling was to determine the depth, thickness, extent, and quality of the coal in the Upper Cretaceous Fruitland Formation in northwest New Mexico. The holes were geophysically logged immediatelymore » after drilling. Resistivity spontaneous-potential, and natural gamma logs were run in all of the holes. A high-resolution density log was also run in all holes drilled before January 13, when a logging unit from the USGS in Albuquerque was available. After January 13, the holes were logged by a USGS unit from Casper, Wyoming that lacked density logging capabilities. At nine locations a second hole was drilled, about 20 ft from the first hole, down to selected coal-bearing intervals and the coal beds were cored. A detailed description of each of the cores is given on the page(s) following the logs for each hole. From these coal cores, 32 intervals were selected and submitted to the Department of Energy in Pittsburgh, Pennsylvania, for analysis.« less

Patient-specific core decompression surgery for early-stage ischemic necrosis of the femoral head

PubMed Central

Wang, Wei; Hu, Wei; Yang, Pei; Dang, Xiao Qian; Li, Xiao Hui; Wang, Kun Zheng

2017-01-01

Introduction Core decompression is an efficient treatment for early stage ischemic necrosis of the femoral head. In conventional procedures, the pre-operative X-ray only shows one plane of the ischemic area, which often results in inaccurate drilling. This paper introduces a new method that uses computer-assisted technology and rapid prototyping to enhance drilling accuracy during core decompression surgeries and presents a validation study of cadaveric tests. Methods Twelve cadaveric human femurs were used to simulate early-stage ischemic necrosis. The core decompression target at the anterolateral femoral head was simulated using an embedded glass ball (target). Three positioning Kirschner wires were drilled into the top and bottom of the large rotor. The specimen was then subjected to computed tomography (CT). A CT image of the specimen was imported into the Mimics software to construct a three-dimensional model including the target. The best core decompression channel was then designed using the 3D model. A navigational template for the specimen was designed using the Pro/E software and manufactured by rapid prototyping technology to guide the drilling channel. The specimen-specific navigation template was installed on the specimen using positioning Kirschner wires. Drilling was performed using a guide needle through the guiding hole on the templates. The distance between the end point of the guide needle and the target was measured to validate the patient-specific surgical accuracy. Results The average distance between the tip of the guide needle drilled through the guiding template and the target was 1.92±0.071 mm. Conclusions Core decompression using a computer-rapid prototyping template is a reliable and accurate technique that could provide a new method of precision decompression for early-stage ischemic necrosis. PMID:28464029

Patient-specific core decompression surgery for early-stage ischemic necrosis of the femoral head.

PubMed

Wang, Wei; Hu, Wei; Yang, Pei; Dang, Xiao Qian; Li, Xiao Hui; Wang, Kun Zheng

2017-01-01

Core decompression is an efficient treatment for early stage ischemic necrosis of the femoral head. In conventional procedures, the pre-operative X-ray only shows one plane of the ischemic area, which often results in inaccurate drilling. This paper introduces a new method that uses computer-assisted technology and rapid prototyping to enhance drilling accuracy during core decompression surgeries and presents a validation study of cadaveric tests. Twelve cadaveric human femurs were used to simulate early-stage ischemic necrosis. The core decompression target at the anterolateral femoral head was simulated using an embedded glass ball (target). Three positioning Kirschner wires were drilled into the top and bottom of the large rotor. The specimen was then subjected to computed tomography (CT). A CT image of the specimen was imported into the Mimics software to construct a three-dimensional model including the target. The best core decompression channel was then designed using the 3D model. A navigational template for the specimen was designed using the Pro/E software and manufactured by rapid prototyping technology to guide the drilling channel. The specimen-specific navigation template was installed on the specimen using positioning Kirschner wires. Drilling was performed using a guide needle through the guiding hole on the templates. The distance between the end point of the guide needle and the target was measured to validate the patient-specific surgical accuracy. The average distance between the tip of the guide needle drilled through the guiding template and the target was 1.92±0.071 mm. Core decompression using a computer-rapid prototyping template is a reliable and accurate technique that could provide a new method of precision decompression for early-stage ischemic necrosis.

A Simple and Inexpensive Technique for Assessing Microbial Contamination during Drilling Operations

NASA Astrophysics Data System (ADS)

Friese, A.; Kallmeyer, J.; Wagner, D.; Kitte, J. A.

2016-12-01

Exploration of the Deep Biosphere relies on drilling, which inevitably causes infiltration of drilling fluids, containing non-indigenous microbes from the surface, into the core. Therefore it is absolutely necessary to trace contamination of the sediment core in order to identify uncontaminated samples for microbiological investigations in drill core samples. To do this, usually a tracer is mixed into the drilling fluid. In past drilling operations a variety of tracers have been used including dyes, salts, dissolved gasses, and microspheres. The latter are microbe-sized fluorescent particles that can be detected with very high sensitivity. Each tracer has its specific strengths and weaknesses, for microspheres the main problem was the high price, which limited the use to spot checks or drilling operations that require only small amounts of drilling fluid. Here, we present a modified microsphere tracer approach, using an aqueous fluorescent pigment dispersion that has a similar concentration of fluorescent particles as previously used microsphere tracers. However, compared to previous microsphere tracers, the cost of the new tracer is four orders of magnitude lower, allowing for a much more liberal use even in large-scale operations. Its suitability for large drilling campaigns was successfully tested at the ICDP Deep Drilling at Lake Towuti, Sulawesi, Indonesia and at the ICDP Deep Drilling at Lake Chalco, Mexico. Contamination can be detected by fluorescence microscopy or by flow cytometry at a sensitivity that is in the range of established techniques. Quantification of the tracer thus only requires a minimum of equipment and by using a small portable cytometer, high-resolution data can be obtained directly on-site within minutes and with minimal effort. Therefore this approach offers an inexpensive but powerful alternative technique for contamination assessment for future drilling campaigns.

WETTABILITY AND PREDICTION OF OIL RECOVERY FROM RESERVOIRS DEVELOPED WITH MODERN DRILLING AND COMPLETION FLUIDS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jill S. Buckley; Norman R. Morrow

2006-01-01

The objectives of this project are: (1) to improve understanding of the wettability alteration of mixed-wet rocks that results from contact with the components of synthetic oil-based drilling and completion fluids formulated to meet the needs of arctic drilling; (2) to investigate cleaning methods to reverse the wettability alteration of mixed-wet cores caused by contact with these SBM components; and (3) to develop new approaches to restoration of wetting that will permit the use of cores drilled with SBM formulations for valid studies of reservoir properties.

A local framework for calculating coupled cluster singles and doubles excitation energies (LoFEx-CCSD)

DOE PAGES

Baudin, Pablo; Bykov, Dmytro; Liakh, Dmitry I.; ...

2017-02-22

Here, the recently developed Local Framework for calculating Excitation energies (LoFEx) is extended to the coupled cluster singles and doubles (CCSD) model. In the new scheme, a standard CCSD excitation energy calculation is carried out within a reduced excitation orbital space (XOS), which is composed of localised molecular orbitals and natural transition orbitals determined from time-dependent Hartree–Fock theory. The presented algorithm uses a series of reduced second-order approximate coupled cluster singles and doubles (CC2) calculations to optimise the XOS in a black-box manner. This ensures that the requested CCSD excitation energies have been determined to a predefined accuracy compared tomore » a conventional CCSD calculation. We present numerical LoFEx-CCSD results for a set of medium-sized organic molecules, which illustrate the black-box nature of the approach and the computational savings obtained for transitions that are local compared to the size of the molecule. In fact, for such local transitions, the LoFEx-CCSD scheme can be applied to molecular systems where a conventional CCSD implementation is intractable.« less

Antarctic Testing of the European Ultrasonic Planetary Core Drill (UPCD)

NASA Astrophysics Data System (ADS)

Timoney, R.; Worrall, K.; Li, X.; Firstbrook, D.; Harkness, P.

2018-04-01

An overview of a series of field testing in Antarctica where the Ultrasonic Planetary Core Drill (UPCD) architecture was tested. The UPCD system is the product an EC FP7 award to develop a Mars Sample Return architecture based around the ultrasonic technique.

Microbiology of the lower ocean crust - Preliminary results from IODP Expedition 360, Atlantis Bank

NASA Astrophysics Data System (ADS)

Sylvan, J. B.; Edgcomb, V. P.; Burgaud, G.; Klein, F.; Schubotz, F.; Expedition 360 Scientists, I.

2016-12-01

International Ocean Discovery Program (IODP) Expedition 360 represents the first leg of a multi-phase drilling program, SloMo, aimed at investigating the nature of the lower crust and Moho at slow spreading ridges. The goal of Expedition 360 was to recover a representative transect of the lower oceanic crust formed at Atlantis Bank, an oceanic core complex on the SW Indian Ridge. We present here preliminary analysis of microbial communities sampled from Hole U1473A, drilled to 789.7 m below seafloor during Expedition 360. Sub-sampling of core sections was conducted in a newly designed plexiglass enclosure with positive air pressure and HEPA filtered air, providing a clean environment for microbiology sampling aboard the JOIDES Resolution. Adenosine triphosphoate, an indicator of microbial biomass, was quantified above detection in 23 of 66 samples analyzed. We measured exoenzyme activity for alkaline phosphatase (AP), leucine aminopeptidase and arginine aminopeptidase in 16 samples and found AP to be very low but above background for 14 of the samples, with highest activities measured between 10 and 70 m below seafloor (mbsf) and peaks again at 158 and 307 mbsf, while both peptidase enzymes were above detection for only one sample at 715 mbsf. Isolates of fungi obtained from core samples as well as analyses of lipid and DNA biomarkers, and Raman spectra for a few of our rock core samples provide initial insights into microbial communities in the lower oceanic crust. Finally, a new tracer of seawater and drilling mud contamination, perfluoromethyl decaline (PFMD), was tested for the first time and its performance compared with the commonly used tracer perfluoromethylcyclohexane (PMCH). PFMD was run during coring operations for ten samples and was routinely detected in the drilling fluids, usually detected on the outside of uncleaned cores, and rarely above detection on the cleaned outside of cores. It was below detection on the inside of cores, indicating penetration of drill fluids to the interior of whole round drill cores, where we collected our samples, is unlikely.

Praying Mantis Bending Core Breakoff and Retention Mechanism

NASA Technical Reports Server (NTRS)

Badescu, Mircea; Sherrit, Stewart; Bar-Cohen, Yoseph; Bao, Xiaoqi; Lindermann, Randel A.

2011-01-01

Sampling cores requires the controlled breakoff of the core at a known location with respect to the drill end. An additional problem is designing a mechanism that can be implemented at a small scale, yet is robust and versatile enough to be used for a variety of core samples. The new design consists of a set of tubes (a drill tube, an outer tube, and an inner tube) and means of sliding the inner and outer tubes axially relative to each other. Additionally, a sample tube can be housed inside the inner tube for storing the sample. The inner tube fits inside the outer tube, which fits inside the drill tube. The inner and outer tubes can move axially relative to each other. The inner tube presents two lamellae with two opposing grabbing teeth and one pushing tooth. The pushing tooth is offset axially from the grabbing teeth. The teeth can move radially and their motion is controlled by the outer tube. The outer tube presents two lamellae with radial extrusions to control the inner tube lamellae motion. In breaking the core, the mechanism creates two support points (the grabbing teeth and the bit tip) and one push point. The core is broken in bending. The grabbing teeth can also act as a core retention mechanism. The praying mantis that is disclosed herein is an active core breaking/retention mechanism that requires only one additional actuator other than the drilling actuator. It can break cores that are attached to the borehole bottom as

Accessing SAFOD data products: Downhole measurements, physical samples and long-term monitoring

NASA Astrophysics Data System (ADS)

Weiland, C.; Zoback, M.; Hickman, S. H.; Ellsworth, W. L.

2005-12-01

Many different types of data were collected during SAFOD Phases 1 and 2 (2004-2005) as part of the National Science Foundation's EarthScope program as well as from the SAFOD Pilot Hole, drilled in 2002 and funded by the International Continental Drilling Program (ICDP). Both SAFOD and the SAFOD Pilot Hole are being conducted as a close collaboration between NSF, the U.S. Geological Survey and the ICDP. SAFOD data products include cuttings, core and fluid samples; borehole geophysical measurements; and strain, tilt, and seismic recordings from the multilevel SAFOD borehole monitoring instruments. As with all elements of EarthScope, these data (and samples) are openly available to members of the scientific and educational communities. This paper presents the acquisition, storage and distribution plan for SAFOD data products. Washed and unwashed drill cuttings and mud samples were collected during Phases 1 and 2, along with three spot cores at depths of 1.5, 2.5, and 3.1 km. A total of 52 side-wall cores were also collected in the open-hole interval between 2.5 and 3.1 km depth. The primary coring effort will occur during Phase 3 (2007), when we will continuously core up to four, 250-m-long multilaterals directly within and adjacent to the San Andreas Fault Zone. Drill cuttings, core, and fluid samples from all three Phases of SAFOD drilling are being curated under carefully controlled conditions at the Integrated Ocean Drilling Program (IODP) Gulf Coast Repository in College Station, Texas. Photos of all physical samples and a downloadable sample request form are available on the ICDP website (http://www.icdp-online.de/sites/sanandreas/index/index.html). A suite of downhole geophysical measurements was conducted during the first two Phases of SAFOD drilling, as well as during drilling of the SAFOD Pilot Hole. These data include density, resistivity, porosity, seismic and borehole image logs and are also available via the ICDP website. The SAFOD monitoring program includes fiber-optic strain, tilt, seismic and fluid-pressure recording instruments. Seismic data from the Pilot Hole array are now available in SEED format from the Northern California Earthquake Data Center (http://quake.geo.berkeley.edu/safod/). The strain and tilt instruments are still undergoing testing and quality assurance, and these data will be available through the same web site as soon as possible. Lastly, two terabytes of unprocessed (SEG-2 format) data from a two-week deployment of an 80-level seismic array during April/May 2005 by Paulsson Geophysical Services, Inc. are now available via the IRIS data center (http://www.iris.edu/data/data.htm). Drilling parameters include real-time descriptions of drill cuttings mineralogy, drilling mud properties, and mechanical data related to the drilling process and are available via the ICDP web site. Current status reports on SAFOD drilling, borehole measurements, sampling, and monitoring instrumentation will continue to be available from the EarthScope web site (http://www.earthscope.org).

Physical-Property Measurements on Core samples from Drill-Holes DB-1 and DB-2, Blue Mountain Geothermal Prospect, North-Central Nevada

USGS Publications Warehouse

Ponce, David A.; Watt, Janet T.; Casteel, John; Logsdon, Grant

2009-01-01

From May to June 2008, the U.S. Geological Survey (USGS) collected and measured physical properties on 36 core samples from drill-hole Deep Blue No. 1 (DB-1) and 46 samples from drill-hole Deep Blue No. 2 (DB-2) along the west side of Blue Mountain about 40 km west of Winnemucca, Nev. These data were collected as part of an effort to determine the geophysical setting of the Blue Mountain geothermal prospect as an aid to understanding the geologic framework of geothermal systems throughout the Great Basin. The physical properties of these rocks and other rock types in the area create a distinguishable pattern of gravity and magnetic anomalies that can be used to infer their subsurface geologic structure. Drill-holes DB-1 and DB-2 were spudded in alluvium on the western flank of Blue Mountain in 2002 and 2004, respectively, and are about 1 km apart. Drill-hole DB-1 is at a ground elevation of 1,325 m and was drilled to a depth of 672 m and drill-hole DB-2 is at a ground elevation of 1,392 m and was drilled to a depth of 1522 m. Diameter of the core samples is 6.4 cm. These drill holes penetrate Jurassic and Triassic metasedimentary rocks predominantly consisting of argillite, mudstone, and sandstone; Tertiary diorite and gabbro; and younger Tertiary felsic dikes.

Long-term effects of core decompression by drilling. Demonstration of bone healing and vessel ingrowth in an animal study.

PubMed

Simank, H G; Graf, J; Kerber, A; Wiedmaier, S

1997-01-01

Avascular necrosis of the femoral head is associated with bone marrow hyperpression. Although core decompression by drilling is an accepted treatment regimen, until today no experimental results exist concerning the physiological effects of this procedure. Published clinical data are controversial. In an animal study marrow decompression was carried out by drilling of both hips in 18 healthy male sheep. In the right hip of each animal a resorbable stent was implanted in order to prolong the duration of core decompression. Over a time period of 24 weeks the effects were studied by measurement of the intraosseous pressure, by the plastination method and by morphological examination with light and electron microscopy. Bone drilling is a procedure of high short-time efficacy in decompressing the bone marrow. But decompression lasts only for a short time period. Three weeks postoperatively the drill channel is sealed by hematoma and fibrous tissue in both hips (with/without stent) and no significant decompressive effect is measured. Ingrowth of vessels along the drill channel is found in all hips after a time period of 3 weeks. These vessels originate from the periosteum as well as from the bone marrow and form temporary anastomoses between the periostal-diaphyseal-metaphyseal and the epiphyseal-physeal circulatory system. In conclusion, for the first time an anastomosis induced by drilling between both circulatory systems of bone is demonstrated and the importance of the periosteum is confirmed. The time of decreased core pressure induced by drilling is too short for substitution of a necrotic area and could be the explanation of the inferior clinical results of the procedure.

Core drill's bit is replaceable without withdrawal of drill stem - A concept

NASA Technical Reports Server (NTRS)

Rushing, F. C.; Simon, A. B.

1970-01-01

Drill bit is divided into several sectors. When collapsed, the outside diameter is forced down the drill stem, when it reaches bottom the sectors are forced outward and form a cutting bit. A dulled bit is retracted by reversal of this procedure.

MeBo70 Seabed Drilling on a Polar Continental Shelf: Operational Report and Lessons From Drilling in the Amundsen Sea Embayment of West Antarctica

NASA Astrophysics Data System (ADS)

Gohl, K.; Freudenthal, T.; Hillenbrand, C.-D.; Klages, J.; Larter, R.; Bickert, T.; Bohaty, S.; Ehrmann, W.; Esper, O.; Frederichs, T.; Gebhardt, C.; Küssner, K.; Kuhn, G.; Pälike, H.; Ronge, T.; Simões Pereira, P.; Smith, J.; Uenzelmann-Neben, G.; van de Flierdt, C.

2017-11-01

A multibarrel seabed drill rig was used for the first time to drill unconsolidated sediments and consolidated sedimentary rocks from an Antarctic shelf with core recoveries between 7% and 76%. We deployed the MARUM-MeBo70 drill device at nine drill sites in the Amundsen Sea Embayment. Three sites were located on the inner shelf of Pine Island Bay from which soft sediments, presumably deposited at high sedimentation rates in isolated small basins, were recovered from drill depths of up to 36 m below seafloor. Six sites were located on the middle shelf of the eastern and western embayment. Drilling at five of these sites recovered consolidated sediments and sedimentary rocks from dipping strata spanning ages from Cretaceous to Miocene. This report describes the initial coring results, the challenges posed by drifting icebergs and sea ice, and technical issues related to deployment of the MeBo70. We also present recommendations for similar future drilling campaigns on polar continental shelves.

A wireline piston core barrel for sampling cohesionless sand and gravel below the water table

USGS Publications Warehouse

Zapico, Michael M.; Vales, Samuel; Cherry, John A.

1987-01-01

A coring device has been developed to obtain long and minimally disturbed samples of saturated cohesionless sand and gravel. The coring device, which includes a wireline and piston, was developed specifically for use during hollow-stem auger drilling but it also offers possibilities for cable tool and rotary drilling. The core barrel consists of an inner liner made of inexpensive aluminum or plastic tubing, a piston for core recovery, and an exterior steel housing that protects the liner when the core barrel is driven into the aquifer. The core barrel, which is approximately 1.6m (5.6 feet) long, is advanced ahead of the lead auger by hammering at the surface on drill rods that are attached to the core barrel. After the sampler has been driven 1.5m (5 feet), the drill rods are detached and a wireline is used to hoist the core barrel, with the sample contained in the aluminum or plastic liner, to the surface. A vacuum developed by the piston during the coring operation provides good recovery of both the sediment and aquifer fluids contained in the sediment. In the field the sample tubes can be easily split along their length for on-site inspection or they can be capped with the pore water fluids inside and transported to the laboratory. The cores are 5cm (2 inches) in diameter by 1.5m (5 feet) long. Core acquisition to depths of 35m (115 feet), with a recovery greater than 90 percent, has become routine in University of Waterloo aquifer studies. A large diameter (12.7cm [5 inch]) version has also been used successfully. Nearly continuous sample sequences from sand and gravel aquifers have been obtained for studies of sedimentology, hydraulic conductivity, hydrogeochemistry and microbiology.

43 CFR 3485.1 - Reports.

Code of Federal Regulations, 2014 CFR

2014-10-01

... all drill hole logs and representative drill cores retained by the operator/lessee pursuant to § 3484... licensed lands. (2) Nature of exploration operations. (3) Number of holes drilled and/or other work performed during the year or report period. (4) Total footage drilled during the year or other period as...

A novel enzyme-based acidizing system: Matrix acidizing and drilling fluid damage removal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, R.E.; McKay, D.M.; Moses, V.

1995-12-31

A novel acidizing process is used to increase the permeability of carbonate rock cores in the laboratory and to remove drilling fluid damage from cores and wafers. Field results show the benefits of the technology as applied both to injector and producer wells.

Mineral and Lithology Mapping of Drill Core Pulps Using Visible and Infrared Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Taylor, G. R., E-mail: G.Taylor@unsw.edu.au

2000-12-15

A novel approach for using field spectrometry for determining both the mineralogy and the lithology of drill core pulps (powders) is developed and evaluated. The methodology is developed using material from a single drillhole through a mineralized sequence of rocks from central New South Wales. Mineral library spectra are used in linear unmixing routines to determine the mineral abundances in drill core pulps that represent between 1 m and 3 m of core. Comparison with X-Ray Diffraction (XRD) analyses shows that for most major constituents, spectrometry provides an estimate of quantitative mineralogy that is as reliable as that provided bymore » XRD. Confusion between the absorption features of calcite and those of chlorite causes the calcite contents determined by spectrometry to be unreliable. Convex geometry is used to recognize the spectra of those samples that are extreme and are representative of unique lithologies. Linear unmixing is used to determine the abundance of these lithologies in each drillhole sample and these abundances are used to interpret the geology of the drillhole. The interpreted geology agrees well with conventional drillhole logs of the visible geology and photographs of the split core. The methods developed provide a quick and cost-effective way of determining the lithology and alteration mineralogy of drill core pulps.« less

The 6-31B(d) basis set and the BMC-QCISD and BMC-CCSD multicoefficient correlation methods.

PubMed

Lynch, Benjamin J; Zhao, Yan; Truhlar, Donald G

2005-03-03

Three new multicoefficient correlation methods (MCCMs) called BMC-QCISD, BMC-CCSD, and BMC-CCSD-C are optimized against 274 data that include atomization energies, electron affinities, ionization potentials, and reaction barrier heights. A new basis set called 6-31B(d) is developed and used as part of the new methods. BMC-QCISD has mean unsigned errors in calculating atomization energies per bond and barrier heights of 0.49 and 0.80 kcal/mol, respectively. BMC-CCSD has mean unsigned errors of 0.42 and 0.71 kcal/mol for the same two quantities. BMC-CCSD-C is an equally effective variant of BMC-CCSD that employs Cartesian rather than spherical harmonic basis sets. The mean unsigned error of BMC-CCSD or BMC-CCSD-C for atomization energies, barrier heights, ionization potentials, and electron affinities is 22% lower than G3SX(MP2) at an order of magnitude less cost for gradients for molecules with 9-13 atoms, and it scales better (N6 vs N,7 where N is the number of atoms) when the size of the molecule is increased.

Computer Simulation To Assess The Feasibility Of Coring Magma

NASA Astrophysics Data System (ADS)

Su, J.; Eichelberger, J. C.

2017-12-01

Lava lakes on Kilauea Volcano, Hawaii have been successfully cored many times, often with nearly complete recovery and at temperatures exceeding 1100oC. Water exiting nozzles on the diamond core bit face quenches melt to glass just ahead of the advancing bit. The bit readily cuts a clean annulus and the core, fully quenched lava, passes smoothly into the core barrel. The core remains intact after recovery, even when there are comparable amounts of glass and crystals with different coefficients of thermal expansion. The unique resulting data reveal the rate and sequence of crystal growth in cooling basaltic lava and the continuous liquid line of descent as a function of temperature from basalt to rhyolite. Now that magma bodies, rather than lava pooled at the surface, have been penetrated by geothermal drilling, the question arises as to whether similar coring could be conducted at depth, providing fundamentally new insights into behavior of magma. This situation is considerably more complex because the coring would be conducted at depths exceeding 2 km and drilling fluid pressures of 20 MPa or more. Criteria that must be satisfied include: 1) melt is quenched ahead of the bit and the core itself must be quenched before it enters the barrel; 2) circulating drilling fluid must keep the temperature of the coring assembling cooled to within operational limits; 3) the drilling fluid column must nowhere exceed the local boiling point. A fluid flow simulation was conducted to estimate the process parameters necessary to maintain workable temperatures during the coring operation. SolidWorks Flow Simulation was used to estimate the effect of process parameters on the temperature distribution of the magma immediately surrounding the borehole and of drilling fluid within the bottom-hole assembly (BHA). A solid model of the BHA was created in SolidWorks to capture the flow behavior around the BHA components. Process parameters used in the model include the fluid properties and temperature of magma, coolant flow rate, rotation speed, and rate of penetration (ROP). The modeling results indicate that there are combinations of process parameters that will provide sufficient cooling to enable the desired coring process in magma.

Paleomagnetism of the Oman Ophiolite: New Results from Oman Drilling Project Cores

NASA Astrophysics Data System (ADS)

Horst, A. J.; Till, J. L.; Koornneef, L.; Usui, Y.; Kim, H.; Morris, A.

2017-12-01

The Oman Drilling Project drilled holes at four sites in a transect through the southern massifs of the Samail ophiolite, and recovered 1500 m of igneous and metamorphic rocks. We focus on three sites from the oceanic crustal section including lower layered gabbros (GT1A), the mid-crustal layered to foliated gabbro transition (GT2A), and the shallower transition from sheeted dikes to varitextured gabbros (GT3A). Detailed core descriptions, analyses, and paleomagnetic measurements, were made on D/V Chikyu from July to September 2017 to utilize the core laboratory facilities similar to IODP expeditions. Shipboard measurements included anisotropy of magnetic susceptibility (AMS) and alternating field and thermal demagnetization of 597 discrete samples. Sample demagnetization behavior is varied from each of the cores, with some revealing multiple components of magnetization, and others yielding nearly univectorial data. The interpretation of results from the lower crustal cores is complicated by the pervasive presence of secondary magnetite. In almost all samples, a stable component was resolved (interpreted as a characteristic remanent magnetization) after removal of a lower-coercivity or lower unblocking-temperature component. The inclinations of the stable components in the core reference frame are very consistent in Hole GT1A. However, a transition from negative to positive inclinations in GT2A suggests some structural complexity, possibly as a result of intense late faulting activity. Both abrupt and gradual transitions between multiple zones of negative and positive inclinations occur in Hole GT3A. Interpretation and direct comparison of remanence between drill sites is difficult as recovered core pieces currently remain azimuthally unoriented, and GT2A was drilled at a plunge of 60°, whereas GT1A and GT3A were both drilled vertically. Work is ongoing to use borehole imagery to reorient the core pieces and paleomagnetic data into a geographic in situ reference frame. We will present an overview of preliminary AMS and remanence data that will be used in the future to 1) document deformational histories, 2) characterize magmatic flow directions at different structural levels, and 3) identify the magnetic mineralogy of remanence carriers throughout the oceanic crustal section.

Determination of three-dimensional stress orientations in the Wenchuan earthquake Fault Scientific Drilling (WFSD) hole-1: A preliminary result by anelastic strain recovery measurements of core samples

NASA Astrophysics Data System (ADS)

Cui, J.; Lin, W.; Wang, L.; Tang, Z.; Sun, D.; Gao, L.; Wang, W.

2010-12-01

A great and destructive earthquake (Ms 8.0; Mw 7.9), Wunchuan earthquake struck on the Longmen Shan foreland trust zone in Sichuan province, China on 12 May 2008 (Xu et al., 2008; Episodes, Vol.31, pp.291-301). As a rapid response scientific drilling project, Wenchuan earthquake Fault Scientific Drilling (WFSD) started on 6 November 2008 shorter than a half of year from the date of earthquake main shock. The first pilot borehole (hole-1) has been drilled to the target depth (measured depth 1201 m MD, vertical depth 1179 m) at Hongkou, Dujianyan, Sichuan and passed through the main fault of the earthquake around 589 m MD. We are trying to determine three dimensional in-situ stress states in the WFSD boreholes by a core-based method, anelastic strain recovery (ASR) method (Lin et al., 2006; Tectonophysics, Vol4.26, pp.221-238). This method has been applied in several scientific drilling projects (TCDP: Lin et al., 2007; TAO, Vol.18, pp.379-393; NanTtoSEIZE: Byrne et al., 2009; GRL, Vol.36, L23310). These applications confirm the validity of using the ASR technique in determining in situ stresses by using drilled cores. We collected total 15 core samples in a depth range from 340 m MD to 1180 m MD, approximately for ASR measurements. Anelastic normal strains, measured every ten minutes in nine directions, including six independent directions, were used to calculate the anelastic strain tensors. The data of the ASR tests conducted at hole-1 is still undergoing analysis. As a tentative perspective, more than 10 core samples showed coherent strain recovery over one - two weeks. However, 2 or 3 core samples cannot be re-orientated to the global system. It means that we cannot rink the stress orientation determined by the core samples to geological structure. Unfortunately, a few core samples showed irregular strain recovery and were not analyzed further. The preliminary results of ASR tests at hole-1 show the stress orientations and stress regime changes a lot with the depth.

Single Piezo-Actuator Rotary-Hammering (SPaRH) Drill

NASA Technical Reports Server (NTRS)

Sherrit, Stewart (Inventor); Bao, Xiaoqi (Inventor); Badescu, Mircea (Inventor); Bar-Cohen, Yoseph (Inventor)

2014-01-01

A Single Piezo-Actuator Rotary-Hammering (SPaRH) Drill includes a horn actuator having high power piezoelectric materials and a flexure pre-stress to increase the actuators effectiveness. The drill is a low mass, low power, compact coring drill measuring 20-cm high by 7-cm diameter and having a total weight of 2 kg including drive electronics. Using an average power of 50-Watts, the drill basalt is expected to cut basalt at a rate of 0.2 cm/min down to depth of 10-cm and create cuttings and an intact core. The drill is expected to operate under different environments including Martian ambient (6 Torr and down to -50 degree C), and liquid nitrogen temperatures (77 K) and low pressure (<<1 Torr) to simulate lunar polar and Europa conditions. Materials expected to be sampled include Kaolinite, Saddleback Basalt, Limestone, Volcanic Breccia, Siltstone, ice, permafrost and layered rocks with different hardness.

Selected data fron continental scientific drilling core holes VC-1 and VC-2a, Valles Caldera, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Musgrave, J.A.; Goff, F.; Shevenell, L.

1989-02-01

This report presents geochemical and isotopic data on rocks and water and wellbore geophysical data from the Continental Scientific Drilling Program core holes VC-1 and VC-2a, Valles Caldera, New Mexico. These core holes were drilled as a portion of a broader program that seeks to answer fundamental questions about magma, water/rock interactions, ore deposits, and volcanology. The data in this report will assist the interpretation of the hydrothermal system in the Jemez Mountains and will stimulate further research in magmatic processes, hydrothermal alteration, ore deposits, hydrology, structural geology, and hydrothermal solution chemistry. 37 refs., 36 figs., 28 tabs.

Identification of sandstone core damage using scanning electron microscopy

NASA Astrophysics Data System (ADS)

Ismail, Abdul Razak; Jaafar, Mohd Zaidi; Sulaiman, Wan Rosli Wan; Ismail, Issham; Shiunn, Ng Yinn

2017-12-01

Particles and fluids invasion into the pore spaces causes serious damage to the formation, resulting reduction in petroleum production. In order to prevent permeability damage for a well effectively, the damage mechanisms should be identified. In this study, water-based drilling fluid was compared to oil-based drilling fluids based on microscopic observation. The cores were damaged by several drilling fluid systems. Scanning electron microscope (SEM) was used to observe the damage mechanism caused by the drilling fluids. Results showed that the ester based drilling fluid system caused the most serious damage followed by synthetic oil based system and KCI-polymer system. Fine solids and filtrate migration and emulsion blockage are believed to be the major mechanisms controlling the changes in flow properties for the sandstone samples.

Core drilling apparatus

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gusman, M.T.; Konstantinov, L.P.; Malkin, B.D.

1974-04-16

Mounted on the exterior of a nonrotatable core barrel is an end of a resilient tape, the other end of which extends inward into the barrel and is connected to a device for pulling the tape inward into the barrel. The apparatus also is provided with an arrangement which forms a sleeve from the tape as this is being pulled into the core barrel. During the coring operation, the tape is being pulled inward into the barrel and a sleeve is formed from the tape with the aid of the arrangement to encase and protect the core from disturbance. Themore » coring apparatus is intended for core drilling in soft, unconsolidated, and fractured formations. (3 claims)« less

Communication: An improved linear scaling perturbative triples correction for the domain based local pair-natural orbital based singles and doubles coupled cluster method [DLPNO-CCSD(T)].

PubMed

Guo, Yang; Riplinger, Christoph; Becker, Ute; Liakos, Dimitrios G; Minenkov, Yury; Cavallo, Luigi; Neese, Frank

2018-01-07

In this communication, an improved perturbative triples correction (T) algorithm for domain based local pair-natural orbital singles and doubles coupled cluster (DLPNO-CCSD) theory is reported. In our previous implementation, the semi-canonical approximation was used and linear scaling was achieved for both the DLPNO-CCSD and (T) parts of the calculation. In this work, we refer to this previous method as DLPNO-CCSD(T 0 ) to emphasize the semi-canonical approximation. It is well-established that the DLPNO-CCSD method can predict very accurate absolute and relative energies with respect to the parent canonical CCSD method. However, the (T 0 ) approximation may introduce significant errors in absolute energies as the triples correction grows up in magnitude. In the majority of cases, the relative energies from (T 0 ) are as accurate as the canonical (T) results of themselves. Unfortunately, in rare cases and in particular for small gap systems, the (T 0 ) approximation breaks down and relative energies show large deviations from the parent canonical CCSD(T) results. To address this problem, an iterative (T) algorithm based on the previous DLPNO-CCSD(T 0 ) algorithm has been implemented [abbreviated here as DLPNO-CCSD(T)]. Using triples natural orbitals to represent the virtual spaces for triples amplitudes, storage bottlenecks are avoided. Various carefully designed approximations ease the computational burden such that overall, the increase in the DLPNO-(T) calculation time over DLPNO-(T 0 ) only amounts to a factor of about two (depending on the basis set). Benchmark calculations for the GMTKN30 database show that compared to DLPNO-CCSD(T 0 ), the errors in absolute energies are greatly reduced and relative energies are moderately improved. The particularly problematic case of cumulene chains of increasing lengths is also successfully addressed by DLPNO-CCSD(T).

Communication: An improved linear scaling perturbative triples correction for the domain based local pair-natural orbital based singles and doubles coupled cluster method [DLPNO-CCSD(T)

NASA Astrophysics Data System (ADS)

Guo, Yang; Riplinger, Christoph; Becker, Ute; Liakos, Dimitrios G.; Minenkov, Yury; Cavallo, Luigi; Neese, Frank

2018-01-01

In this communication, an improved perturbative triples correction (T) algorithm for domain based local pair-natural orbital singles and doubles coupled cluster (DLPNO-CCSD) theory is reported. In our previous implementation, the semi-canonical approximation was used and linear scaling was achieved for both the DLPNO-CCSD and (T) parts of the calculation. In this work, we refer to this previous method as DLPNO-CCSD(T0) to emphasize the semi-canonical approximation. It is well-established that the DLPNO-CCSD method can predict very accurate absolute and relative energies with respect to the parent canonical CCSD method. However, the (T0) approximation may introduce significant errors in absolute energies as the triples correction grows up in magnitude. In the majority of cases, the relative energies from (T0) are as accurate as the canonical (T) results of themselves. Unfortunately, in rare cases and in particular for small gap systems, the (T0) approximation breaks down and relative energies show large deviations from the parent canonical CCSD(T) results. To address this problem, an iterative (T) algorithm based on the previous DLPNO-CCSD(T0) algorithm has been implemented [abbreviated here as DLPNO-CCSD(T)]. Using triples natural orbitals to represent the virtual spaces for triples amplitudes, storage bottlenecks are avoided. Various carefully designed approximations ease the computational burden such that overall, the increase in the DLPNO-(T) calculation time over DLPNO-(T0) only amounts to a factor of about two (depending on the basis set). Benchmark calculations for the GMTKN30 database show that compared to DLPNO-CCSD(T0), the errors in absolute energies are greatly reduced and relative energies are moderately improved. The particularly problematic case of cumulene chains of increasing lengths is also successfully addressed by DLPNO-CCSD(T).

An Early Pleistocene high-resolution paleoclimate reconstruction from the West Turkana (Kenya) HSPDP drill site

NASA Astrophysics Data System (ADS)

Stockhecke, Mona; Beck, Catherine; Brown, Erik T.; Cohen, Andrew; Deocampo, Daniel M.; Feibel, Craig S.; Pelletier, Jon D.; Rabideaux, Nathane M.; Sier, Mark

2016-04-01

The Hominin Sites and Paleolakes Drilling Project (HSPDP), and the related Olorgesailie Drilling Project (ODP), recovered ~2 km of drill core since 2012. At the HSPDP West Turkana Kaitio (WTK) site a 216 m-long core that covers the Early Pleistocene time window (1.3 to 1.87 Ma) during which hominids first expanded out of Africa and marine records document reorganization of tropical climate and the development of the strong Walker circulation. WTK carries particular interest for paleoclimate and paleoenvironmental reconstructions as it is located only 2.5 km from the location of one of the most complete hominin skeletons ever recovered (Nariokotome Boy). XRF core scanning data provide a means of evaluating records of past environmental conditions continuously and at high resolution. However, the record contains complex lithologies reflecting repeated episodes of inundation and desiccation along a dynamic lake margin. Here we present a methodological approach to address the highly variable lithostratigraphy of the East African records to establish comprehensive paleoclimate timeseries. The power spectrum of the presented hydroclimate record peaks at Milankovitch cycles, qualifying HSPDP drill cores from the Turkana Basin to be used as high-resolution Early Pleistocene paleoclimate archive. Comparing these data with marine climate reconstructions sheds light into athmospheric processes and continental climate dynamics.

Results of multiple drilling compared with those of conventional methods of core decompression.

PubMed

Song, Won Seok; Yoo, Jeong Joon; Kim, Young-Min; Kim, Hee Joong

2007-01-01

We performed multiple drilling as a femoral head-preserving procedure for osteonecrosis of the femoral head thinking the therapeutic effects of core decompression could be achieved by this simpler procedure than core decompression. We retrospectively reviewed 136 patients (163 hips) who had multiple drilling using 9/64-inch Steinmann pins for treatment of nontraumatic osteonecrosis of the femoral head. The mean followup for patients who did not require additional surgery (113 hips) was 87 months (range, 60-134 months). We defined failure as the need for additional surgery or a Harris hip score less than 75. After a minimum 5-year followup, 79% (31/39) of patients with Stage I disease and 77% (62/81) of patients with Stage II disease had no additional surgery. All (15/15) small lesions (<25% involvement) and 84% (37/44) of medium-sized lesions (25-50% involvement) were considered successful. Survival rates of patients with Ficat Stages I or II lesions were greater than survival rates for patients with Stage III lesions. Hips with a large necrotic area had poor results. We had one instance of subtrochanteric fracture through drill entry holes. Multiple drilling is straightforward with few complications and produces results comparable to results of other core decompression techniques.

Magnetostratigraphy of the Miocene sediments at Háj u Duchcova and Sokolov (West Bohemia)

NASA Astrophysics Data System (ADS)

Schnabl, Petr; Man, Otakar; Matys Grygar, Tomáš; Mach, Karel; Kdýr, Šimon; Čížková, Kristýna; Pruner, Petr; Martínek, Karel; Rojík, Petr

2017-04-01

Magnetostratigraphic investigation was conducted on the newly excavated drill core HD-50 and previously retreived drill cores DP-333-09 and JP-585-10. The new drill core HD-50 was sampled at the old coal mine 1.Máj near Háj u Duchcova in the Most Basin, while the DP-333-09 and JP-585-10 are from the benches of opencast coal mines Družba and Jiří in the Sokolov Basin. Both basins are parts of one segment of the European Cenozoic Rift System. The sediments in both basins are of Burdigalian age (lower Miocene). Their lithology mainly comprise fossil-free clays/silts above the main coal seam, with two phosphatic horizons with mineral crandalite in the Most Basin and several greigite layers in the Sokolov Basin. Anisotropy of magnetic susceptibility (AMS), alternate field demagnetization and remanent magnetization were measured in all samples. Unusually behaving samples with extremely high magnetic susceptibility (siderite), prolate anisotropy of AMS and samples with the angle of the main AMS axis exceeding 20 degrees was excluded from further evaluation. The sedimentation rate was computed by multivariate spectral analysis on data acquired by X-ray fluorescence. The spectral analysis was performed with our original software solution for identification of typical frequencies and their assignement to Milanković cycles.[1] The sedimentation rate (after compaction) was around 15 cm/ky for the drill core DP-333-09 and around 30 cm/ky for the core JP-585-10. The sediment succession above the coal seam at drill core DP-333-09 starts with 20 meters, in which the magnetic polarity could not be reconstructed (70 - 50 m), then there is a top part of reverse zone (50 - 49 m) and short normal subzone above it (49 - 48 m). Above that there is the second reverse zone (45 - 4 m). Two additional magnetozones above that could be found only in the drill core HD-50 from the Most Basin. The drill core JP-585-10 begins with 14 meters of disturbed zone (94 - 80 m), then 12 meters of normal polarity (69 - 80 m) was found. Above that, after a small gap of magnetically disturbed sediments, there are 60 meters of sediments with reverse polarity (62 - 2 m) with short normal excursion at the upper half (24 - 17 m). According to the detailed analysis of drill core HK591 (Matys Grygar et al. 2014), we suppose, that the succession begins in C5En (only JP-585-10), then C5Dr. Validity of subzone C5Dr.1n in the drills JP-585-10 and DP-333-09 is still under discussion. The zone C5Cr could be found only in the HD-50 core. In comparison of the interpreted polarities with ATNTS2012 the time span in the studied cores is approximately 17.5 to 17.9 Ma for DP-333-09, 17.8 to 18.1 for JP-585-[2]10 and 17.1 to 17.7 Ma for HD-50. Additional investigation should be done. The research was supported by Czech Science Foundation GAČR, project n. 16-00800S. Matys Grygar, T., Mach, K., Pruner, P., Schnabl, P., Laurin, J., Martinez, M., 2014. A lacustrine record of the early stage of the Miocene Climatic Optimum in Central Europe from the Most Basin, Ohře (Eger) Graben, Czech Republic, Geol. Mag. 151 (6), 1013-1033.

Geologic, geotechnical, and geophysical properties of core from the Acme Fire-Pit-1 drill hole, Sheridan County, Wyoming

USGS Publications Warehouse

Collins, Donley S.

1983-01-01

A preliminary core study from the Acme Fire-Pit-1 drill hole, Sheridan County, Wyoming, revealed that the upper portion of the core had been baked by a fire confined to the underlying Monarch coal bed. The baked (clinkered) sediment above the Monarch coal bed was determined to have higher point-load strength values (greater than 2 MPa) than the sediment under the burned coal

Tribological characterization of the drill pipe tool joints reconditioned by using welding technologies

NASA Astrophysics Data System (ADS)

Caltaru, M.; Badicioiu, M.; Ripeanu, R. G.; Dinita, A.; Minescu, M.; Laudacescu, E.

2018-01-01

Drill pipe is a seamless steel pipe with upset ends fitted with special threaded ends that are known as tool joints. During drilling operations, the wall thickness of the drill pipe and the outside diameter of the tool joints will be gradually reduced due to wear. The present research work investigate the possibility of reconditioning the drill pipe tool joints by hardbanding with a new metal-cored coppered flux cored wire, Cr-Mo alloyed, using the gas metal active welding process, taking into considerations two different hardbanding technologies, consisting in: hardbanding drill pipe tool joints after removing the old hardbanding material and surface reconstruction with a compensation material (case A), and hardbanding tool joint drill pipe, without removing the old hardbanding material (case B). The present paper brings forward the experimental researches regarding the tribological characterization of the reconditioned drill pipe tool joint by performing macroscopic analyses, metallographic analyses, Vickers hardness measurement, chemical composition measurement and wear tests conducted on ball on disk friction couples, in order to certify the quality of the hardbanding obtained by different technological approaches, to validate the optimum technology.

Origin of retrograde fluid in ultrahigh-pressure metamorphic rocks: Constraints from mineral hydrogen isotope and water content changes in eclogite gneiss transitions in the Sulu orogen

NASA Astrophysics Data System (ADS)

Chen, Ren-Xu; Zheng, Yong-Fei; Gong, Bing; Zhao, Zi-Fu; Gao, Tian-Shan; Chen, Bin; Wu, Yuan-Bao

2007-05-01

By taking advantage of having depth profiles between contrasting lithologies from core samples of the Chinese Continental Scientific Drilling (CCSD) project, a combined study was carried out to examine changes in mineral H isotope, total water and hydroxyl contents in garnet and omphacite across the contacts between ultrahigh-pressure (UHP) eclogite and gneiss in the Sulu orogen, east-central China. The samples of interest were from two continuous core segments from the CCSD main hole at depths of 734.21-737.16 and 929.67-932.86 m, respectively. The results show δD values of -116‰ to - 64‰ for garnet and -104‰ to -82‰ for omphacite, consistent with incorporation of meteoric water into protoliths of UHP metamorphic rocks by high-T alteration. Both equilibrium and disequilibrium H isotope fractionations were observed between garnet and omphacite, suggesting fluid-assisted H isotope exchange at local scales during amphibolite-facies retrogression. While bulk water analysis gave total H 2O concentrations of 522-1584 ppm for garnet and 1170-20745 ppm for omphacite, structural hydroxyl analysis yielded H 2O contents of 80-413 ppm for garnet and 228-412 ppm for omphacite. It appears that significant amounts of molecular H 2O are present in the minerals, pointing to enhanced capacity of water storage in the UHP eclogite minerals. Hydrogen isotope variations in the transition between eclogite and gneiss show correlations with variations in their water contents. Petrographically, the degree of retrograde metamorphism generally increases with decreasing distance from the eclogite-gneiss boundary. Thus, retrograde metamorphism results in mineral reactions and H isotope variation. Because hydroxyl solubility in nominally anhydrous minerals decreases with dropping pressure, significant amounts of water are expected to be released from the minerals during decompression exhumation. Decompression exsolution of structural hydroxyl from 1 m 3 volume of eclogite composed of only garnet and omphacite results in release of a quantitative estimate of 3.07-3.44 kg water that can form 140-156 kg amphibole during exhumation. Therefore, it is concluded that fluid for retrogression of the eclogites away from the eclogite-gneiss boundary was derived from the decompression exsolution of structural hydroxyl and molecular H 2O in nominally anhydrous minerals. For the eclogites adjacent to gneiss, in contrast, the retrograde metamorphism was principally caused by aqueous fluid from the gneiss which is relatively rich in water. Consequently, both the origin and availability of metamorphic fluid during exhumation of deeply subducted continental crust are deciphered by this combined study focusing on the transitions and the retrograde processes between the felsic and mafic UHP rocks.

30 CFR 550.297 - What information must a CID contain?

Code of Federal Regulations, 2014 CFR

2014-07-01

... drilled before your CID submittal that define the extent of the reservoirs. You must notify BOEM of any well that is drilled to total depth during the CID evaluation period and you may be required to update..., caliper curves) curves in an acceptable digital format; (4) Sidewall core/whole core and pressure-volume...

30 CFR 550.297 - What information must a CID contain?

Code of Federal Regulations, 2013 CFR

2013-07-01

... drilled before your CID submittal that define the extent of the reservoirs. You must notify BOEM of any well that is drilled to total depth during the CID evaluation period and you may be required to update..., caliper curves) curves in an acceptable digital format; (4) Sidewall core/whole core and pressure-volume...

30 CFR 550.297 - What information must a CID contain?

Code of Federal Regulations, 2012 CFR

2012-07-01

... drilled before your CID submittal that define the extent of the reservoirs. You must notify BOEM of any well that is drilled to total depth during the CID evaluation period and you may be required to update..., caliper curves) curves in an acceptable digital format; (4) Sidewall core/whole core and pressure-volume...

Characterizing the Weeks Island Salt Dome drilling of and seismic measurements from boreholes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sattler, A.R.; Harding, R.S.; Jacobson, R.D.

1996-10-01

A sinkhole 36 ft across, 30 ft deep was first observed in the alluvium over the Weeks Island Salt Dome (salt mine converted for oil storage by US Strategic Petroleum Reserve) May 1992. Four vertical, two slanted boreholes were drilled for diagnostics. Crosswell seismic data were generated; the velocity images suggest that the sinkhole collapse is complicated, not a simple vertical structure. The coring operation was moderately difficult; limited core was obtained through the alluvium, and the quality of the salt core from the first two vertical wells was poor. Core quality improved with better bit selection, mud, and drillingmore » method. The drilling fluid program provided fairly stable holes allowing open hole logs to be run. All holes were cemented successfully (although it took 3 attempts in one case).« less

Relevance of East African Drill Cores to Human Evolution: the Case of the Olorgesailie Drilling Project

NASA Astrophysics Data System (ADS)

Potts, R.

2016-12-01

Drill cores reaching the local basement of the East African Rift were obtained in 2012 south of the Olorgesailie Basin, Kenya, 20 km from excavations that document key benchmarks in the origin of Homo sapiens. Sediments totaling 216 m were obtained from two drilling locations representing the past 1 million years. The cores were acquired to build a detailed environmental record spatially associated with the transition from Acheulean to Middle Stone Age technology and extensive turnover in mammalian species. The project seeks precise tests of how climate dynamics and tectonic events were linked with these transitions. Core lithology (A.K. Behrensmeyer), geochronology (A. Deino), diatoms (R.B. Owen), phytoliths (R. Kinyanjui), geochemistry (N. Rabideaux, D. Deocampo), among other indicators, show evidence of strong environmental variability in agreement with predicted high-eccentricity modulation of climate during the evolutionary transitions. Increase in hominin mobility, elaboration of symbolic behavior, and concurrent turnover in mammalian species indicating heightened adaptability to unpredictable ecosystems, point to a direct link between the evolutionary transitions and the landscape dynamics reflected in the Olorgesailie drill cores. For paleoanthropologists and Earth scientists, any link between evolutionary transitions and environmental dynamics requires robust evolutionary datasets pertinent to how selection, extinction, population divergence, and other evolutionary processes were impacted by the dynamics uncovered in drill core studies. Fossil and archeological data offer a rich source of data and of robust environment-evolution explanations that must be integrated into efforts by Earth scientists who seek to examine high-resolution climate records of human evolution. Paleoanthropological examples will illustrate the opportunities that exist for connecting evolutionary benchmarks to the data obtained from drilled African muds. Project members: R. Potts, A.K. Behrensmeyer, E. Beverly, K. Brady, J. Bright, E. Brown, J. Clark, A. Cohen, A. Deino, P. deMenocal, D. Deocampo, R. Dommain, J.T. Faith, J. King, R. Kinyanjui, N. Levin, J. Moerman, V. Muiruri, A. Noren, R.B. Owen, N. Rabideaux, R. Renaut, S. Rucina, J. Russell, J. Scott, M. Stockhecke, K. Uno

Effect of Osteonecrosis Intervention Rod Versus Core Decompression Using Multiple Small Drill Holes on Early Stages of Necrosis of the Femoral Head: A Prospective Study on a Series of 60 Patients with a Minimum 1-Year-Follow-Up.

PubMed

Miao, Haixiong; Ye, Dongping; Liang, Weiguo; Yao, Yicun

2015-01-01

The conventional CD used 10 mm drill holes associated with a lack of structural support. Thus, alternative methods such as a tantalum implant, small drill holes, and biological treatment were developed to prevent deterioration of the joint. The treatment of CD by multiple 3.2 mm drill holes could reduce the femoral neck fracture and partial weight bearing was allowed. This study was aimed to evaluate the effect of osteonecrosis intervention rod versus core decompression using multiple small drill holes on early stages of necrosis of the femoral head. From January 2011 to January 2012, 60 patients undergoing surgery for osteonecrosis with core decompression were randomly assigned into 2 groups based on the type of core decompression used: (1) a total of 30 osteonecrosis patients (with 16 hips on Steinburg stageⅠ,20 hips on Steinburg stageⅡ) were treated with a porous tantalum rod insertion. The diameter of the drill hole for the intervention rod was 10mm.(2) a total of 30 osteonecrosis patients (with 14 hips on Steinburg stageⅠ,20 hips on Steinburg stageⅡ) were treated with core decompression using five drill holes on the lateral femur, the diameter of the hole was 3.2 mm. The average age of the patient was 32.6 years (20-45 years) and the average time of follow-up was 25.6 months (12- 28 months) in the rod implanted group. The average age of the patient was 35.2 years (22- 43 years) and the average time of follow-up was 26.3 months (12-28 months) in the small drill holes group. The average of surgical time was 40 min, and the mean volume of blood loss was 30 ml in both surgical groups. The average of Harris score was improved from 56.2 ± 7.1 preoperative to 80.2 ± 11.4 at the last follow-up in the rod implanted group (p < 0.05). The mean Harris score was improved from 53.8 ± 6.6 preoperative to 79.7 ± 13.2 at the last follow-up in the small drill holes group (p<0. 05). No significant difference was observed in Harris score between the two groups. At the last follow-up, 28 of 36 hips were at the same radiographic stages as pre-operation, and 8 deteriorated in the rod implanted group. 26 of 34 hips were at the same radiographic stage as pre-operation, and 8 deteriorated in the small drill holes group. No significant difference was observed in radiographic stage between the two groups. There was no favourable result on the outcome of a tantalum intervention implant compared to multiple small drill holes. CD via multiple small drill holes would allow similar postoperative load-bearing and seems to result in similar or even better clinical outcome without the prolonged implantation of an expensive tantalum implant. A tantalum rod intervention and core decompression using multiple small drill holes were effective on the stage I hips rather than stage II hips.

A current review of core decompression in the treatment of osteonecrosis of the femoral head.

PubMed

Pierce, Todd P; Jauregui, Julio J; Elmallah, Randa K; Lavernia, Carlos J; Mont, Michael A; Nace, James

2015-09-01

The review describes the following: (1) how traditional core decompression is performed, (2) adjunctive treatments, (3) multiple percutaneous drilling technique, and (4) the overall outcomes of these procedures. Core decompression has optimal outcomes when used in the earliest, precollapse disease stages. More recent studies have reported excellent outcomes with percutaneous drilling. Furthermore, adjunct treatment methods combining core decompression with growth factors, bone morphogenic proteins, stem cells, and bone grafting have demonstrated positive results; however, larger randomized trial is needed to evaluate their overall efficacy.

Variations in the depths of sulfate-methane transition zone (SMTZ) in UBGH2-6 drilling site in Ulleung Basin, East sea of Korea

NASA Astrophysics Data System (ADS)

Kim, Y.; Chun, J. H.; Bahk, J. J.; Ryu, B. J.; Um, I. K.

2016-12-01

The second Ulleung Basin Gas hydrate Drilling Expedition (UBGH2) was conducted in the Ulleung Basin, East Sea of Korea in 2010. Gas hydrates were observed in depth interval from 140 mbsf (meter below seafloor) to 160 mbsf in core sediment taken from UBGH2-6 drilling site, located in the north-western part of the basin (2,164 m water depth). To characterize the geochemical process for UBGH2-6 core sediments, pore fluid samples and headspace gas samples were extracted from core sediments and analyzed SO42- and CH4 concentrations. Based on SO42- and CH4 concentrations, sulfate-methane transition zone (SMTZ), where SO42- is depleted to zero and CH4 starts to increase was defined at a depth of approximately 6.50 mbsf in 2010. And in order to identify the variations in the depths of SMTZ at UBGH2-6 drilling site since 2010 (UBGH2), whole-round piston cores were collected from UBGH2-6 drilling site from 2013 to 2015. We analyzed SO42- and CH4 concentrations and identified the SMTZ for the last 3 years. The depths of SMTZ for the cores obtained from 2013, 2014 and 2015 are approximately 3.50 mbsf, 5.00 mbsf, and 5.00 mbsf respectively. The analysis results indicate that the SMTZ in 2013, 2014, and 2015 are shallower than the SMTZ of 2010.

Perturbative triples correction for local pair natural orbital based explicitly correlated CCSD(F12*) using Laplace transformation techniques.

PubMed

Schmitz, Gunnar; Hättig, Christof

2016-12-21

We present an implementation of pair natural orbital coupled cluster singles and doubles with perturbative triples, PNO-CCSD(T), which avoids the quasi-canonical triples approximation (T0) where couplings due to off-diagonal Fock matrix elements are neglected. A numerical Laplace transformation of the canonical expression for the perturbative (T) triples correction is used to avoid an I/O and storage bottleneck for the triples amplitudes. Results for a test set of reaction energies show that only very few Laplace grid points are needed to obtain converged energy differences and that PNO-CCSD(T) is a more robust approximation than PNO-CCSD(T0) with a reduced mean absolute deviation from canonical CCSD(T) results. We combine the PNO-based (T) triples correction with the explicitly correlated PNO-CCSD(F12*) method and investigate the use of specialized F12-PNOs in the conventional triples correction. We find that no significant additional errors are introduced and that PNO-CCSD(F12*)(T) can be applied in a black box manner.

Carbon X-ray absorption spectra of fluoroethenes and acetone: A study at the coupled cluster, density functional, and static-exchange levels of theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fransson, Thomas; Norman, Patrick; Coriani, Sonia

2013-03-28

Near carbon K-edge X-ray absorption fine structure spectra of a series of fluorine-substituted ethenes and acetone have been studied using coupled cluster and density functional theory (DFT) polarization propagator methods, as well as the static-exchange (STEX) approach. With the complex polarization propagator (CPP) implemented in coupled cluster theory, relaxation effects following the excitation of core electrons are accounted for in terms of electron correlation, enabling a systematic convergence of these effects with respect to electron excitations in the cluster operator. Coupled cluster results have been used as benchmarks for the assessment of propagator methods in DFT as well as themore » state-specific static-exchange approach. Calculations on ethene and 1,1-difluoroethene illustrate the possibility of using nonrelativistic coupled cluster singles and doubles (CCSD) with additional effects of electron correlation and relativity added as scalar shifts in energetics. It has been demonstrated that CPP spectra obtained with coupled cluster singles and approximate doubles (CC2), CCSD, and DFT (with a Coulomb attenuated exchange-correlation functional) yield excellent predictions of chemical shifts for vinylfluoride, 1,1-difluoroethene, trifluoroethene, as well as good spectral features for acetone in the case of CCSD and DFT. Following this, CPP-DFT is considered to be a viable option for the calculation of X-ray absorption spectra of larger {pi}-conjugated systems, and CC2 is deemed applicable for chemical shifts but not for studies of fine structure features. The CCSD method as well as the more approximate CC2 method are shown to yield spectral features relating to {pi}*-resonances in good agreement with experiment, not only for the aforementioned molecules but also for ethene, cis-1,2-difluoroethene, and tetrafluoroethene. The STEX approach is shown to underestimate {pi}*-peak separations due to spectral compressions, a characteristic which is inherent to this method.« less

Carbon X-ray absorption spectra of fluoroethenes and acetone: a study at the coupled cluster, density functional, and static-exchange levels of theory.

PubMed

Fransson, Thomas; Coriani, Sonia; Christiansen, Ove; Norman, Patrick

2013-03-28

Near carbon K-edge X-ray absorption fine structure spectra of a series of fluorine-substituted ethenes and acetone have been studied using coupled cluster and density functional theory (DFT) polarization propagator methods, as well as the static-exchange (STEX) approach. With the complex polarization propagator (CPP) implemented in coupled cluster theory, relaxation effects following the excitation of core electrons are accounted for in terms of electron correlation, enabling a systematic convergence of these effects with respect to electron excitations in the cluster operator. Coupled cluster results have been used as benchmarks for the assessment of propagator methods in DFT as well as the state-specific static-exchange approach. Calculations on ethene and 1,1-difluoroethene illustrate the possibility of using nonrelativistic coupled cluster singles and doubles (CCSD) with additional effects of electron correlation and relativity added as scalar shifts in energetics. It has been demonstrated that CPP spectra obtained with coupled cluster singles and approximate doubles (CC2), CCSD, and DFT (with a Coulomb attenuated exchange-correlation functional) yield excellent predictions of chemical shifts for vinylfluoride, 1,1-difluoroethene, trifluoroethene, as well as good spectral features for acetone in the case of CCSD and DFT. Following this, CPP-DFT is considered to be a viable option for the calculation of X-ray absorption spectra of larger π-conjugated systems, and CC2 is deemed applicable for chemical shifts but not for studies of fine structure features. The CCSD method as well as the more approximate CC2 method are shown to yield spectral features relating to π∗-resonances in good agreement with experiment, not only for the aforementioned molecules but also for ethene, cis-1,2-difluoroethene, and tetrafluoroethene. The STEX approach is shown to underestimate π∗-peak separations due to spectral compressions, a characteristic which is inherent to this method.

The dipole moment surface for hydrogen sulfide H2S

NASA Astrophysics Data System (ADS)

Azzam, Ala`a. A. A.; Lodi, Lorenzo; Yurchenko, Sergey N.; Tennyson, Jonathan

2015-08-01

In this work we perform a systematic ab initio study of the dipole moment surface (DMS) of H2S at various levels of theory and of its effect on the intensities of vibration-rotation transitions; H2S intensities are known from the experiment to display anomalies which have so far been difficult to reproduce by theoretical calculations. We use the transition intensities from the HITRAN database of 14 vibrational bands for our comparisons. The intensities of all fundamental bands show strong sensitivity to the ab initio method used for constructing the DMS while hot, overtone and combination bands up to 4000 cm-1 do not. The core-correlation and relativistic effects are found to be important for computed line intensities, for instance affecting the most intense fundamental band (ν2) by about 20%. Our recommended DMS, called ALYT2, is based on the CCSD(T)/aug-cc-pV(6+d)Z level of theory supplemented by a core-correlation/relativistic corrective surface obtained at the CCSD[T]/aug-cc-pCV5Z-DK level. The corresponding computed intensities agree significantly better (to within 10%) with experimental data taken directly from original papers. Worse agreement (differences of about 25%) is found for those HITRAN intensities obtained from fitted effective dipole models, suggesting the presence of underlying problems in those fits.

High-level ab initio potential energy surface and dynamics of the F- + CH3I SN2 and proton-transfer reactions.

PubMed

Olasz, Balázs; Szabó, István; Czakó, Gábor

2017-04-01

Bimolecular nucleophilic substitution (S N 2) and proton transfer are fundamental processes in chemistry and F - + CH 3 I is an important prototype of these reactions. Here we develop the first full-dimensional ab initio analytical potential energy surface (PES) for the F - + CH 3 I system using a permutationally invariant fit of high-level composite energies obtained with the combination of the explicitly-correlated CCSD(T)-F12b method, the aug-cc-pVTZ basis, core electron correlation effects, and a relativistic effective core potential for iodine. The PES accurately describes the S N 2 channel producing I - + CH 3 F via Walden-inversion, front-side attack, and double-inversion pathways as well as the proton-transfer channel leading to HF + CH 2 I - . The relative energies of the stationary points on the PES agree well with the new explicitly-correlated all-electron CCSD(T)-F12b/QZ-quality benchmark values. Quasiclassical trajectory computations on the PES show that the proton transfer becomes significant at high collision energies and double-inversion as well as front-side attack trajectories can occur. The computed broad angular distributions and hot internal energy distributions indicate the dominance of indirect mechanisms at lower collision energies, which is confirmed by analyzing the integration time and leaving group velocity distributions. Comparison with available crossed-beam experiments shows usually good agreement.

Exploration geothermal gradient drilling, Platanares, Honduras, Central America

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goff, S.J.; Laughlin, A.W.; Ruefenacht, H.D.

1988-01-01

This paper is a review and summary of the core drilling operations component of the Honduras Geothermal Resource Development Project at the Platanares geothermal prospect in Honduras, Central America. Three intermediate depth (428 to 679 m) coreholes are the first continuously cored geothermal exploration boreholes in Honduras. These coring operations are part of the Central America Energy Resource Project (CAERP) effort funded by the Agency for International Development (AID) and implemented by the Los Alamos National Laboratory (Los Alamos) in cooperation with the Empresa Nacional de Energia Electrica (ENEE) and the United States Geological Survey (USGS). This report emphasizes coringmore » operations with reference to the stratigraphy, thermal gradient, and flow test data of the boreholes. The primary objectives of this coring effort were (1) to obtain quantitative information on the temperature distribution as a function of depth, (2) to recover fluids associated with the geothermal reservoir, (3) to recover 75% or better core from the subsurface rock units, and (4) to drill into the subsurface rock as deeply as possible in order to get information on potential reservoir rocks, fracture density, permeabilities, and alteration histories of the rock units beneath the site. The three exploration coreholes drilled to depths of 650, 428 and 679 m, respectively, encountered several hot water entries. Coring operations and associated testing began in mid-October 1986 and were completed at the end of June 1987.« less

The Mattassee Lake Sites: Archeological Investigations Along the Lower Santee River in the Coastal Plain of South Carolina.

DTIC Science & Technology

1982-12-01

Limestones were is located in this area and appears to reflect penetrated in cores drilled south of Lake extensive, complex use. Some of the abori...lake margin (in the vicinity of the contrast, in all of the cores drilled by the 1979 excavations). The nature of aboriginal U.S. Army Corp of...to serve in (Table 31). While low, the tools occur in the prying or drilling functions it does not show dominant debitage levels. The tool types

Use of Nitrocarburizing for Strengthening Threaded Joints of Drill Pipes from Medium-Carbon Alloy Steels

NASA Astrophysics Data System (ADS)

Priymak, E. Yu.; Stepanchukova, A. V.; Yakovleva, I. L.; Tereshchenko, N. A.

2015-05-01

Nitrocarburizing is tested at the Drill Equipment Plant for reinforcing threaded joints of drill pipes for units with retrievable core receiver (RCR). The effect of the nitrocarburizing on the mechanical properties of steels of different alloying systems is considered. Steels for the production of threaded joints of drill pipes are recommended.

43 CFR 3207.12 - What work am I required to perform each year for BLM to continue the initial and additional...

Code of Federal Regulations, 2013 CFR

2013-10-01

...: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production or injection wells; (6) Reservoir... lease at the end of that year unless you qualify for a drilling extension under § 3207.13. (i) Every...

43 CFR 3207.12 - What work am I required to perform each year for BLM to continue the initial and additional...

Code of Federal Regulations, 2012 CFR

2012-10-01

...: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production or injection wells; (6) Reservoir... lease at the end of that year unless you qualify for a drilling extension under § 3207.13. (i) Every...

43 CFR 3207.12 - What work am I required to perform each year for BLM to continue the initial and additional...

Code of Federal Regulations, 2014 CFR

2014-10-01

...: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production or injection wells; (6) Reservoir... lease at the end of that year unless you qualify for a drilling extension under § 3207.13. (i) Every...

43 CFR 3207.12 - What work am I required to perform each year for BLM to continue the initial and additional...

Code of Federal Regulations, 2011 CFR

2011-10-01

...: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production or injection wells; (6) Reservoir... lease at the end of that year unless you qualify for a drilling extension under § 3207.13. (i) Every...

Molecular analysis of bacterial diversity in kerosene-based drilling fluid from the deep ice borehole at Vostok, East Antarctica.

PubMed

Alekhina, Irina A; Marie, Dominique; Petit, Jean Robert; Lukin, Valery V; Zubkov, Vladimir M; Bulat, Sergey A

2007-02-01

Decontamination of ice cores is a critical issue in phylogenetic studies of glacial ice and subglacial lakes. At the Vostok drill site, a total of 3650 m of ice core have now been obtained from the East Antarctic ice sheet. The ice core surface is coated with a hard-to-remove film of impure drilling fluid comprising a mixture of aliphatic and aromatic hydrocarbons and foranes. In the present study we used 16S rRNA gene sequencing to analyze the bacterial content of the Vostok drilling fluid sampled from four depths in the borehole. Six phylotypes were identified in three of four samples studied. The two dominant phylotypes recovered from the deepest (3400 and 3600 m) and comparatively warm (-10 degrees C and -6 degrees C, respectively) borehole horizons were from within the genus Sphingomonas, a well-known degrader of polyaromatic hydrocarbons. The remaining phylotypes encountered in all samples proved to be human- or soil-associated bacteria and were presumed to be drilling fluid contaminants of rare occurrence. The results obtained indicate the persistence of bacteria in extremely cold, hydrocarbon-rich environments. They show the potential for contamination of ice and subglacial water samples during lake exploration, and the need to develop a microbiological database of drilling fluid findings.

Surface drilling technologies for Mars

NASA Technical Reports Server (NTRS)

Blacic, J. D.; Rowley, J. C.; Cort, G. E.

1986-01-01

Rock drilling and coring conceptual designs for the surface activities associated with a manned Mars mission are proposed. Straightforward extensions of equipment and procedures used on Earth are envisioned for the sample coring and shallow high explosive shot holes needed for tunneling and seismic surveying. A novel rocket exhaust jet piercing method is proposed for very rapid drilling of shot holes required for explosive excavation of emergency radiation shelters. Summaries of estimated equipment masses and power requirements are provided, and the indicated rotary coring rigs are scaled from terrestrial equipment and use compressed CO2 from the Martian atmosphere for core bit cooling and cuttings removal. A mass of 120 kg and power of 3 kW(e) are estimated for a 10 m depth capability. A 100 m depth capacity core rig requires about 1150 kg and 32 km(e). The rocket exhaust jet equipment devised for shallow (3m) explosive emplacement shot holes requires no surface power beyond an electrical ignition system, and might have a 15 kg mass.

Petrology of deep drill hole, Kilauea Volcano

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grose, L.T.; Keller, G.V.

1976-12-01

The first deep drill hole (1262 m TD) at the summit of an active volcano (1102 m elev) was drilled in 1973 at Kilauea volcano, Hawaii with support from NSF and USGS. The hole is located within southern margin of Kilauea caldera in northern part of a 15 km/sup 2/ triangular block bounded by east rift zone, Koae fault zone, and southwest rift zone-a summit area relatively free of faults, rifts, and extrusions. Nearest eruptions are from fissures 1.2 km away which are active in 1974 and which do not trend toward the drill hole. Core recovery totals 47 mmore » from 29 core runs at rather evenly spaced intervals to total depth. Megascopic, thin-section, and X-ray examination reveals: (1) Recovered core is essentially vesicular, intergranular, nonporphyritic to porphyritic olivine basalt with minor olivine diabase, picrite diabase, and basalt, (2) Hyaloclastite and pillow basalt are absent, (3) Below water table (614 m elev) with increasing depth, vesicularity decreases, and density, crystallinity, competence, vesicle fill, and alteration irregularly increase, (4) Alteration first occurs at water table where calcite and silica partially fill vesticles and olivine is partially serpentinized, (5) At about 570 m elev massive serpentinization of olivine and deposition of montmorillonite-nontronite occur; at about 210 m elev truscottite and tobermorite occur in vesicles; at about 35 m elev mordenite occurs in vesicles, (6) Bottom-hole cores have complete filling of vesicles with silica, minor silica replacement, and complete alteration of olivine, and (7) Plagioclase is unaltered. Chemical analyses of bottom-hole cores are similar to those of modern summit lavas. Alteration and low porosity in bottom-hole cores plus abrupt temperature increase suggest the drill hole penetrated a self-sealed ''cap rock'' to a hydrothermal convection cell and possibly a magma body.« less

Hydrothermal mineralogy of core from geothermal drill holes at Newberry Volcano, Oregon

USGS Publications Warehouse

Bargar, Keith E.; Keith, Terry E.

1999-01-01

Hydrothermal mineralogy studies of specimens collected from nine geothermal drill holes suggest that, at the locations and depths drilled, past temperatures have been hottest (exceeding 300?C) near ring fractures on the south and west sides of Newberry Volcano.

43 CFR 3207.11 - What work am I required to perform during the first 10 years of my lease for BLM to grant the...

Code of Federal Regulations, 2014 CFR

2014-10-01

... geologic or reservoir information, such as: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production...

43 CFR 3207.11 - What work am I required to perform during the first 10 years of my lease for BLM to grant the...

Code of Federal Regulations, 2013 CFR

2013-10-01

... geologic or reservoir information, such as: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production...

43 CFR 3207.11 - What work am I required to perform during the first 10 years of my lease for BLM to grant the...

Code of Federal Regulations, 2012 CFR

2012-10-01

... geologic or reservoir information, such as: (1) Geologic investigation and analysis; (2) Drilling temperature gradient wells; (3) Core drilling; (4) Geochemical or geophysical surveys; (5) Drilling production...

Elastic anisotropy and borehole stress estimation in the Seve Nappe Complex from the COSC-1 well, Åre, Sweden.

NASA Astrophysics Data System (ADS)

Wenning, Quinn; Almquist, Bjarne; Ask, Maria; Schmitt, Douglas R.; Zappone, Alba

2015-04-01

The Caledonian orogeny, preserved in Scandinavia and Greenland, began with the closure of the Iapetus Ocean and culminated in the collision of Baltica and Laurentia cratons during the middle Paleozoic. The COSC scientific drilling project aims at understanding the crustal structure and composition of the Scandinavian Caledonides. The first well of the dual phase drilling program, completed in Summer of 2014, drilled through ~2.5 km of the Seve Nappe Complex near the town of Åre, Sweden. Newly acquired drill core and borehole logs provide fresh core material for physical rock property measurements and in-situ stress determination. This contribution presents preliminary data on compressional and shear wave ultrasonic velocities (Vp, Vs) determined from laboratory measurements on drill cores, together with in-situ stress orientation analysis using image logs from the first borehole of the Collisional Orogeny in the Scandinavian Caledonides project (COSC-1). An hydrostatically oil pressurized apparatus is used to test the ultrasonic Vp and Vs on three orthogonally cut samples of amphibolite, calcium bearing and felsic gneiss, meta-gabbro, and mylonitic schist from drill core. We measure directional anisotropy variability for each lithology using one sample cut perpendicular to the foliation and two additional plugs cut parallel to the foliation with one parallel to the lineation and the other perpendicular. Measurements are performed using the pulse transmission technique on samples subjected to hydrostatic pressure from 1-350 MPa at dry conditions. We present preliminary results relating Vp and Vs anisotropy to geologic units and degree of deformation. Additionally, we use acoustic borehole televiewer logs to estimate the horizontal stress orientation making use of well developed techniques for observed borehole breakouts (compressive failure) and drilling induced fractures (tensile failure). Preliminary observations show that very few drilling-induced tensile fractures are produced, and that borehole breakouts are episodic and suggests a NE-SW minimum horizontal stress direction

Depositional history of the Apollo 16 deep drill core

NASA Technical Reports Server (NTRS)

Gose, W. A.; Morris, R. V.

1977-01-01

Ferromagnetic resonance and magnetic hysteresis loop measurements were performed on 212 samples from the Apollo 16 deep drill core. The total iron content is generally uniform with a mean value of 5.7 plus or minus 0.9 wt%. The soils range in maturity from immature to mature. Two major contacts were observed. The contact at 13 cm depth represents a fossil surface whereas the contact at 190 cm depth has no time-stratigraphic significance. The data suggest that the core section below 13 cm depth was deposited in a single impact event and subjected to meteoritic gardening for about 450 m.y. However, our data do not preclude deposition by a series of closely spaced events. About 50 m.y. ago, the top 13 cm were added. Comparison with the Apollo 16 double drive tube 60009/60010 does not yield any evidence for a stratigraphic correlation with the deep drill core.

Stratigraphy and depositional history of the Apollo 17 drill core

NASA Technical Reports Server (NTRS)

Taylor, G. J.; Warner, R. D.; Keil, K.

1979-01-01

Lithologic abundances obtained from modal analyses of a continuous string of polished thin sections indicate that the Apollo 17 deep drill core can be divided into three main zones: An upper zone (0-19 cm depth) characterized by high abundances of agglutinates (30%) and a high ratio of mare to non-mare lithic fragments (less than 0.8); a coarse-grained layer (24-56 cm) rich in fragments of high-Ti mare basalts and mineral fragments derived from them, and poor in agglutinates (6%); and a lower zone (56-285 cm) characterized by variable but generally high agglutinate abundances (25%) and a low ratio of mare to nonmare lithic fragments (0.6). Using observations of the geology of the landing site, the principles of cratering dynamics, and the vast amount of data collected on the core, the following depositional history for the section of regolith sampled by the Apollo 17 drill core: was devised.

Inert gas stratigraphy of Apollo 15 drill core sections 15001 and 15003

NASA Technical Reports Server (NTRS)

Huebner, W.; Kirsten, T.; Heymann, D.

1973-01-01

Rare gase contents were studied in Apollo 15 drill core sections corresponding to 207 to 238 and 125 to 161-cm depths, with respect to layering of the core, turnover on a centimeter scale, and cosmic proton bombardment history. Trapped gas abundance was established in all samples, the mean grain size being a major factor influencing the absolute rare gas contents. Analysis of the results suggests that the regolith materials were exposed to galactic and solar cosmic rays long before their deposition.

Determination of the neutron activation profile of core drill samples by gamma-ray spectrometry.

PubMed

Gurau, D; Boden, S; Sima, O; Stanga, D

2018-04-01

This paper provides guidance for determining the neutron activation profile of core drill samples taken from the biological shield of nuclear reactors using gamma spectrometry measurements. Thus, it provides guidance for selecting a model of the right form to fit data and using least squares methods for model fitting. The activity profiles of two core samples taken from the biological shield of a nuclear reactor were determined. The effective activation depth and the total activity of core samples along with their uncertainties were computed by Monte Carlo simulation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Cybersonics: Tapping into Technology

NASA Technical Reports Server (NTRS)

2001-01-01

With the assistance of Small Business Innovation Research (SBIR) funding from NASA's Jet Propulsion Laboratory, Cybersonics, Inc., developed an ultrasonic drill with applications ranging from the medical industry to space exploration. The drill, which has the ability to take a core sample of the hardest granite or perform the most delicate diagnostic medical procedure, is a lightweight, ultrasonic device made to fit in the palm of the hand. Piezoelectric actuators, which have only two moving parts and no gears or motors, drive the components of the device, enabling it to operate in a wide range of temperatures. The most remarkable aspect of the drill is its ability to penetrate even the hardest rock with minimal force application. The ultrasonic device requires 20 to 30 times less force than standard rotating drills, allowing it to be safely guided by hand during operation. Also, the drill is operable at a level as low as three watts of power, where conventional drills require more than three times this level. Potential future applications for the ultrasonic drill include rock and soil sampling, medical procedures that involve core sampling or probing, landmine detection, building and construction, and space exploration. Cybersonics, Inc. developed an ultrasonic drill with applications ranging from the medical industry to space exploration.

A comparison of petrophysical data inputs for establishing time-depth relationships: a guide for future drilling expeditions

NASA Astrophysics Data System (ADS)

Boaga, J.; Sauermilch, I.; Mateo, Z. R. P.

2017-12-01

Time-depth relationships (TDR) are crucial in correlating drillhole and core information to seismic reflection profiles, for accurate resource estimation, scientific interpretation and to guide drilling operations. Conventional seismic time-depth domain conversion utilizes downhole sonic logs (DSI), calibrated using available checkshot data, which are local travel times from the surface to a particular depth. Scientific drilling programs (ODP and IODP) also measure P-wave velocity (PWL or C) on recovered core samples. Only three percent of all ODP and IODP sites record all three velocity measurements, however this information can be instructive as sometimes these data input show dissimilar TDR. These representative sites provide us with an opportunity to perform a comparative analysis highlighting the differences and similarities of TDRs derived from checkshot, downhole, and laboratory measurements. We then discuss the impact of lithology, stratigraphy, water column and other petrophysical properties in the predictive accuracy of TDR calculations, in an effort to provide guidance for future drilling and coring expeditions.

Determination of In-situ Rock Thermal Properties from Geophysical Log Data of SK-2 East Borehole, Continental Scientific Drilling Project of Songliao Basin, NE China

NASA Astrophysics Data System (ADS)

Zou, C.; Zhao, J.; Zhang, X.; Peng, C.; Zhang, S.

2017-12-01

Continental Scientific Drilling Project of Songliao Basin is a drilling project under the framework of ICDP. It aims at detecting Cretaceous environmental/climate changes and exploring potential resources near or beneath the base of the basin. The main hole, SK-2 East Borehole, has been drilled to penetrate through the Cretaceous formation. A variety of geophysical log data were collected from the borehole, which provide a great opportunity to analyze thermal properties of in-situ rock surrounding the borehole.The geothermal gradients were derived directly from temperature logs recorded 41 days after shut-in. The matrix and bulk thermal conductivity of rock were calculated with the geometric-mean model, in which mineral/rock contents and porosity were required as inputs (Fuchs et. al., 2014). Accurate mineral contents were available from the elemental capture spectroscopy logs and porosity data were derived from conventional logs (density, neutron and sonic). The heat production data were calculated by means of the concentrations of uranium, thorium and potassium determined from natural gamma-ray spectroscopy logs. Then, the heat flow was determined by using the values of geothermal gradients and thermal conductivity.The thermal parameters of in-situ rock over the depth interval of 0 4500m in the borehole were derived from geophysical logs. Statistically, the numerical ranges of thermal parameters are in good agreement with the measured values from both laboratory and field in this area. The results show that high geothermal gradient and heat flow exist over the whole Cretaceous formation, with anomalously high values in the Qingshankou formation (1372.0 1671.7m) and the Quantou formation (1671.7 2533.5m). It is meaningful for characterization of geothermal regime and exploration of geothermal resources in the basin. Acknowledgment: This work was supported by the "China Continental Scientific Drilling Program of Cretaceous Songliao Basin (CCSD-SK)" of China Geological Survey Projects (NO. 12120113017600).

Visible-Near Infrared Point Spectrometry of Drill Core Samples from Río Tinto, Spain: Results from the 2005 Mars Astrobiology Research and Technology Experiment (MARTE) Drilling Exercise

NASA Astrophysics Data System (ADS)

Sutter, Brad; Brown, Adrian J.; Stoker, Carol R.

2008-10-01

Sampling of subsurface rock may be required to detect evidence of past biological activity on Mars. The Mars Astrobiology Research and Technology Experiment (MARTE) utilized the Río Tinto region, Spain, as a Mars analog site to test dry drilling technologies specific to Mars that retrieve subsurface rock for biological analysis. This work examines the usefulness of visible-near infrared (VNIR) (450-1000 nm) point spectrometry to characterize ferric iron minerals in core material retrieved during a simulated Mars drilling mission. VNIR spectrometry can indicate the presence of aqueously precipitated ferric iron minerals and, thus, determine whether biological analysis of retrieved rock is warranted. Core spectra obtained during the mission with T1 (893-897 nm) and T2 (644-652 nm) features indicate goethite-dominated samples, while relatively lower wavelength T1 (832-880 nm) features indicate hematite. Hematite/goethite molar ratios varied from 0 to 1.4, and within the 880-898 nm range, T1 features were used to estimate hematite/goethite molar ratios. Post-mission X-ray analysis detected phyllosilicates, which indicates that examining beyond the VNIR (e.g., shortwave infrared, 1000-2500 nm) will enhance the detection of other minerals formed by aqueous processes. Despite the limited spectral range of VNIR point spectrometry utilized in the MARTE Mars drilling simulation project, ferric iron minerals could be identified in retrieved core material, and their distribution served to direct core subsampling for biological analysis.

Visible-near infrared point spectrometry of drill core samples from Río Tinto, Spain: results from the 2005 Mars Astrobiology Research and Technology Experiment (MARTE) drilling exercise.

PubMed

Sutter, Brad; Brown, Adrian J; Stoker, Carol R

2008-10-01

Sampling of subsurface rock may be required to detect evidence of past biological activity on Mars. The Mars Astrobiology Research and Technology Experiment (MARTE) utilized the Río Tinto region, Spain, as a Mars analog site to test dry drilling technologies specific to Mars that retrieve subsurface rock for biological analysis. This work examines the usefulness of visible-near infrared (VNIR) (450-1000 nm) point spectrometry to characterize ferric iron minerals in core material retrieved during a simulated Mars drilling mission. VNIR spectrometry can indicate the presence of aqueously precipitated ferric iron minerals and, thus, determine whether biological analysis of retrieved rock is warranted. Core spectra obtained during the mission with T1 (893-897 nm) and T2 (644-652 nm) features indicate goethite-dominated samples, while relatively lower wavelength T1 (832-880 nm) features indicate hematite. Hematite/goethite molar ratios varied from 0 to 1.4, and within the 880-898 nm range, T1 features were used to estimate hematite/goethite molar ratios. Post-mission X-ray analysis detected phyllosilicates, which indicates that examining beyond the VNIR (e.g., shortwave infrared, 1000-2500 nm) will enhance the detection of other minerals formed by aqueous processes. Despite the limited spectral range of VNIR point spectrometry utilized in the MARTE Mars drilling simulation project, ferric iron minerals could be identified in retrieved core material, and their distribution served to direct core subsampling for biological analysis.

Hawaii Scientific Drilling Project: Objectives, Successes, Surprises and Frustrations

NASA Astrophysics Data System (ADS)

Depaolo, D. J.; Stolper, E.; Thomas, D. M.

2008-12-01

The Hawaii Scientific Drilling Project (HSDP) is a long-running project undertaken with the objective of studying a mantle plume by drilling an extended sequence of lavas from a single Hawaiian volcano. The project originated with a proposal to NSF in late 1986 with the idea of drilling to the Moho under Hilo; the target depth was estimated at 12km, commensurate with the depth reached by the drilling program then being pursued by the USSR and that proposed in the U.S. for the southern Appalachians, and in line with the aspirations of the nascent DOSECC program. Subsequently, due to limitations in funding and reorganization of the drilling program into what later became the NSF Continental Dynamics Program, HSDP was re-scoped with the objective of drilling deeply enough (ca. 4.5km) to recover most of the eruptive history of a single volcano. The project first went to a pilot stage, which resulted in coring to a depth of 1.1km in late 1993. The pilot stage was relatively inexpensive (1M including science) and productive. Funding was then obtained from NSF and ICDP in 1995 (ca. 12M) with the objective of drilling to 4.5km. Drilling was originally planned for a five-year period, in two campaigns. The first campaign, in 1999, resulted in efficient coring to a depth of 3.1km over a period of 6 months; it used about 40 percent of the funds and was also highly productive. Deepening the hole below 3.1km turned out to be both difficult and expensive, although for interesting reasons. To facilitate deeper drilling the hole needed to be reamed to a larger diameter; but when this was done the well unexpectedly started to flow. We now know that there are several deep pressurized aquifers, with varying salt content, but these hydrological phenomena were totally unanticipated. A key finding, also unanticipated, is that cold seawater circulates through the volcanic pile in volumes sufficient to refrigerate the entire section below 700m depth to temperatures about 25 degrees below a normal geothermal gradient. In early 1999 when the first drilling campaign was organized, the price of oil was 10 USD (rigs and drilling crews were available and reasonably priced); in early 2003 when hole opening was being arranged, the price of oil was 30 USD, and for the coring campaigns in 2005 and 2007 it was 50 to 70 USD. For these reasons, and because trip times were longer and deeply buried pillow basalts more difficult to drill, the remainder of the project funds (and then some) were needed to deepen the hole from 3.1 to 3.5km. Nevertheless, the project obtained a nearly continuous, and virtually unweathered, core consisting of lava flows, hyaloclastite, minor intrusives and sediment from a 3260m section of the Mauna Kea volcano, covering an age range from 200 to over 600 ka. It also recovered a 250m and a 280m section of the Mauna Loa volcano. A wealth of geological, volcanological, petrological, geochemical, geomagnetic, geodynamic, hydrological, and geobiological data have come from the core and the well, and more are coming in. The unprecedented geochemical-petrological data sets are a major success, as is the fact that geochemists can work together, but the hoped-for detailed geochronology for the core has proven difficult to obtain.

Drill core major, trace and rare earth element anlayses from wells RN-17B and RN-30, Reykjanes, Iceland

DOE Data Explorer

Andrew Fowler

2015-04-01

Analytical results for X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) measurement of major, trace and rare earth elements in drill core from geothermal wells in Reykjanes, Iceland. Total Fe was analyzed as FeO, therefore is not included under the Fe2O3 column.

Preliminary data for northern Great Plains test well 1, quarter NE quarter Sec. 11, T.55N., R.77W., Sheridan County, Wyoming

USGS Publications Warehouse

Lobmeyer, D.H.; Anna, L.O.; Busby, J.F.

1982-01-01

This report documents the preliminary data obtained from Northern Great Plains test well 1 and describes the preliminary results and future testing plans. The intended audience includes hydrologists, local water users, drilling contractors, and water managers. The test well was drilled as part of the study to determine the water resource potential of the regional aquifer system in the Northern Great Plains, an area of about 250,000 sq mi. The well is 4,485 ft deep; nine cores were drilled totaling 182 ft; 157.42 ft of core were recovered. Sidewall cores were obtained from 24 horizons. Gamma and density scans of the cores were made, and selected parts were tested for density, porosity, and vertical and horizontal permeability. Eight zones were perforated and tested using conventional drill-stem tests and swabbing. Water samples were obtained from seven zones. No major potential sources of groundwater were penetrated by the test well. Estimated yields from selected zones range from about 240 gal/min with 400 ft of drawdown to about 5 gal/min flow at the surface. Dissolved-solids concentrations ranged from about 1,800 to 3,000 mg/l. (USGS)

Data Modeling, Development, Installation and Operation of the ACEX Offshore Drilling Information System for the Mission Specific Platform Expedition to the Lomonosov Ridge, Arctic Ocean.

NASA Astrophysics Data System (ADS)

Conze, R.; Krysiak, F.; Wallrabe-Adams, H.; Graham, C. C.

2004-12-01

During August/September 2004, the Arctic Coring Expedition (ACEX) was used to trial a new Offshore Drilling Information System (OffshoreDIS). ACEX was the first Mission Specific Platform (MSP) expedition of the Integrated Ocean Drilling Programme (IODP), funded by the European Consortium for Ocean Research Drilling (ECORD). The British Geological Survey in conjunction with the University of Bremen and the European Petrophysics Consortium were the ECORD Science Operator (ESO) for ACEX. IODP MSP expeditions have very similar data management requirements and operate in similar working environments to the lake drilling projects conducted by the International Continental Scientific Drilling Program (ICDP), for example, the GLAD800, which has very restricted space on board and operates in difficult conditions. Both organizations require data capture and management systems that are mobile, flexible and that can be deployed quickly on small- to medium-sized drilling platforms for the initial gathering of data, and that can also be deployed onshore in laboratories where the bulk of the scientific work is conducted. ESO, therefore, decided that an adapted version of the existing Drilling Information System (DIS) used by ICDP projects would satisfy its requirements. Based on the existing DIS, an OffshoreDIS has been developed for MSP expeditions. The underlying data model is compatible with IODP(JANUS), the Bremen Core Repository, WDC-MARE/PANGAEA and the LacCore in Minneapolis. According to the specific expedition platform configuration and on-board workflow requirements for the Arctic, this data model, data pumps and user interfaces were adapted for the ACEX-OffshoreDIS. On the drill ship Vidar Viking the cores were catalogued and petrophysically logged using a GeoTek Multi-Sensor Core Logger System, while further initial measurements, lithological descriptions and biostratigraphic investigations were undertaken on the Oden, which provided laboratory facilities for the expedition. Onboard samples were registered in a corresponding sample archive on both vessels. The ACEX-OffshoreDIS used a local area network covering the two ships of the three icebreaker fleet by wireless LAN between the ships and partly wired LAN on the ships. A DIS-server was installed on each ship. These were synchronized by database replication and linked to a total of 10 client systems and label printers across both ships. The ACEX-OffshoreDIS will also be used for the scientific measurement and analysis phase of the expedition during the post-field operations `shore-party' in November 2004 at the Bremen Core Repository (BCR). The data management system employed in the Arctic will be reconfigured and deployed at the BCR. In addition, an eXtended DIS (XDIS) Web interface will be available. This will allow controlled sample distribution (core curation, sub-sampling) as well as sharing of data (registration, upload and download) with other laboratories which will be undertaking additional sampling and analyses. The OffshoreDIS data management system will be of long-term benefit to both IODP and ICDP, being deployed in forthcoming MSP offshore projects, ICDP lake projects and joint IODP-ICDP projects such as the New Jersey Coastal Plain Drilling Project.

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alan Black; Arnis Judzis

2004-10-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rockmore » cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING'' for the period starting June 23, 2003 through September 30, 2004. TerraTek has reviewed applicable literature and documentation and has convened a project kick-off meeting with Industry Advisors in attendance. TerraTek has designed and planned Phase I bench scale experiments. Some difficulties in obtaining ultra-high speed motors for this feasibility work were encountered though they were sourced mid 2004. TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. Some improvements over early NASA experiments have been identified.« less

SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alan Black; Arnis Judzis

2004-10-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high (greater than 10,000 rpm) rotational speeds. The work includes a feasibility of concept research effort aimed at development and test results that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with rigs having a smaller footprint to be more mobile. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration rockmore » cutting with substantially lower inputs of energy and loads. The project draws on TerraTek results submitted to NASA's ''Drilling on Mars'' program. The objective of that program was to demonstrate miniaturization of a robust and mobile drilling system that expends small amounts of energy. TerraTek successfully tested ultrahigh speed ({approx}40,000 rpm) small kerf diamond coring. Adaptation to the oilfield will require innovative bit designs for full hole drilling or continuous coring and the eventual development of downhole ultra-high speed drives. For domestic operations involving hard rock and deep oil and gas plays, improvements in penetration rates is an opportunity to reduce well costs and make viable certain field developments. An estimate of North American hard rock drilling costs is in excess of $1,200 MM. Thus potential savings of $200 MM to $600 MM are possible if drilling rates are doubled [assuming bit life is reasonable]. The net result for operators is improved profit margin as well as an improved position on reserves. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''SMALLER FOOTPRINT DRILLING SYSTEM FOR DEEP AND HARD ROCK ENVIRONMENTS; FEASIBILITY OF ULTRA-HIGH SPEED DIAMOND DRILLING'' for the period starting June 23, 2003 through September 30, 2004. (1) TerraTek has reviewed applicable literature and documentation and has convened a project kick-off meeting with Industry Advisors in attendance. (2) TerraTek has designed and planned Phase I bench scale experiments. Some difficulties in obtaining ultra-high speed motors for this feasibility work were encountered though they were sourced mid 2004. (3) TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. Some improvements over early NASA experiments have been identified.« less

Petrophysical characterization of first ever drilled core samples from an active CO2 storage site, the German Ketzin Pilot Site - Comparison with long term experiments

NASA Astrophysics Data System (ADS)

Zemke, Kornelia; Liebscher, Axel

2014-05-01

Petrophysical properties like porosity and permeability are key parameters for a safe long-term storage of CO2 but also for the injection operation itself. These parameters may change during and/or after the CO2 injection due to geochemical reactions in the reservoir system that are triggered by the injected CO2. Here we present petrophysical data of first ever drilled cores from a newly drilled well at the active CO2 storage site - the Ketzin pilot site in the Federal State of Brandenburg, Germany. By comparison with pre-injection baseline data from core samples recovered prior to injection, the new samples provide the unique opportunity to evaluate the impact of CO2 on pore size related properties of reservoir and cap rocks at a real injection site under in-situ reservoir conditions. After injection of 61 000 tons CO2, an additional well was drilled and new rock cores were recovered. In total 100 core samples from the reservoir and the overlaying caprock were investigated by NMR relaxation. Permeability of 20 core samples was estimated by nitrogen and porosity by helium pycnometry. The determined data are comparable between pre-injection and post-injection core samples. The lower part of the reservoir sandstone is unaffected by the injected CO2. The upper part of the reservoir sandstone shows consistently slightly lower NMR porosity and permeability values in the post-injection samples when compared to the pre-injection data. This upper sandstone part is above the fluid level and CO2 present as a free gas phase and a possible residual gas saturation of the cores distorted the NMR results. The potash-containing drilling fluid can also influence these results: NMR investigation of twin samples from inner and outer parts of the cores show a reduced fraction of larger pores for the outer core samples together with lower porosities and T2 times. The drill mud penetration depth can be controlled by the added fluorescent tracer. Due to the heterogeneous character of the Stuttgart Formation it is difficult to estimate definite CO2 induced changes from petrophysical measurements. The observed changes are only minor. Several batch experiments on Ketzin samples drilled prior injection confirm the results from investigation of the in-situ rock cores. Core samples of the pre-injection wells were exposed to CO2 and brine in autoclaves over various time periods. Samples were characterized prior to and after the experiments by NMR and Mercury Injection Porosimetry (MIP). The results are consistent with the logging data and show only minor change. Unfortunately, also in these experiments observed mineralogical and petrophysical changes were within the natural heterogeneity of the Ketzin reservoir and precluded unequivocal conclusions. However, given the only minor differences between post-injection well and pre-injection well, it is reasonable to assume that the potential dissolution-precipitation processes appear to have no severe consequences on reservoir and cap rock integrity or on the injection behaviour. This is also in line with the continuously recorded injection operation parameter. These do not point to any changes in reservoir injectivity.|

A CCSD (T) investigation of carbonyl oxide and dioxirane. Equilibrium geometries, dipole moments, infrared spectra, heats of formation and isomerization energies

NASA Astrophysics Data System (ADS)

Cremer, Dieter; Gauss, Jürgen; Kraka, Elfi; Stanton, John F.; Bartlett, Rodney J.

1993-07-01

A CCSD and CCSD (T) investigation of carbonyl oxide ( 1) and its cyclic isomer dioxirane ( 2) has been carried out employing DZ + P and TZ + 2P basis sets. Calculated geometries, charge distributions, and dipole moments suggest that 1 possesses more zwitterionic character (CCSD (T) dipole moment 4 D) than has been predicted. 1 can be distinguished from 2 by its infrared spectrum as indicated by CCSD (T) frequencies, intensities, and isotopic shifts. The heats of formation Δ H0f (298) for 1 and 2 are 30.2 and 6.0 kcal/mol, respectively; the CCSD (T) barrier to isomerization from 1 to 2 is 19.2 kcal/mol. Decomposition of 1 and 2 can lead to CO, CO 2, H 2O, H 2 but not to free CH 2, O 2 or O. Both isomers should be powerful epoxidation agents in the presence of alkenes, but they should differ in their ability to form cyclopropanes with alkenes.

Coccolith and silicoflagellate stratigraphy, northern mid-Atlantic Ridge and Reykjanes Ridge, Deep Sea Drilling Project Leg 49

USGS Publications Warehouse

Bukry, David

1979-01-01

Leg 49 of the Deep Sea Drilling Project recovered 192 cores at eight drilling sites, 407 through 414 (Figure 1). Light-microscope techniques were used to study the cocoliths, silicoflagellates, and sponge spicules of 120 samples from these cores. The cocolith zonation of the samples follows Bukry (1975a), and is summarized in Figure 2. Silicoflagellate zonation, summarized in Figure 3, is explained in the text. Siliceous sponge spicules are common in many samples and are briefly discussed and illustrated. One new silicoflagellate, Distephanus sulcatus, from the Plicene of Site 407, is described.

Multiple Small Diameter Drillings Increase Femoral Neck Stability Compared with Single Large Diameter Femoral Head Core Decompression Technique for Avascular Necrosis of the Femoral Head.

PubMed

Brown, Philip J; Mannava, Sandeep; Seyler, Thorsten M; Plate, Johannes F; Van Sikes, Charles; Stitzel, Joel D; Lang, Jason E

2016-10-26

Femoral head core decompression is an efficacious joint-preserving procedure for treatment of early stage avascular necrosis. However, postoperative fractures have been described which may be related to the decompression technique used. Femoral head decompressions were performed on 12 matched human cadaveric femora comparing large 8mm single bore versus multiple 3mm small drilling techniques. Ultimate failure strength of the femora was tested using a servo-hydraulic material testing system. Ultimate load to failure was compared between the different decompression techniques using two paired ANCOVA linear regression models. Prior to biomechanical testing and after the intervention, volumetric bone mineral density was determined using quantitative computed tomography to account for variation between cadaveric samples and to assess the amount of bone disruption by the core decompression. Core decompression, using the small diameter bore and multiple drilling technique, withstood significantly greater load prior to failure compared with the single large bore technique after adjustment for bone mineral density (p< 0.05). The 8mm single bore technique removed a significantly larger volume of bone compared to the 3mm multiple drilling technique (p< 0.001). However, total fracture energy was similar between the two core decompression techniques. When considering core decompression for the treatment of early stage avascular necrosis, the multiple small bore technique removed less bone volume, thereby potentially leading to higher load to failure.

The Hominin Sites and Paleolakes Drilling Project: inferring the environmental context of human evolution from eastern African rift lake deposits

NASA Astrophysics Data System (ADS)

Cohen, A.; Campisano, C.; Arrowsmith, R.; Asrat, A.; Behrensmeyer, A. K.; Deino, A.; Feibel, C.; Hill, A.; Johnson, R.; Kingston, J.; Lamb, H.; Lowenstein, T.; Noren, A.; Olago, D.; Owen, R. B.; Potts, R.; Reed, K.; Renaut, R.; Schäbitz, F.; Tiercelin, J.-J.; Trauth, M. H.; Wynn, J.; Ivory, S.; Brady, K.; O'Grady, R.; Rodysill, J.; Githiri, J.; Russell, J.; Foerster, V.; Dommain, R.; Rucina, S.; Deocampo, D.; Russell, J.; Billingsley, A.; Beck, C.; Dorenbeck, G.; Dullo, L.; Feary, D.; Garello, D.; Gromig, R.; Johnson, T.; Junginger, A.; Karanja, M.; Kimburi, E.; Mbuthia, A.; McCartney, T.; McNulty, E.; Muiruri, V.; Nambiro, E.; Negash, E. W.; Njagi, D.; Wilson, J. N.; Rabideaux, N.; Raub, T.; Sier, M. J.; Smith, P.; Urban, J.; Warren, M.; Yadeta, M.; Yost, C.; Zinaye, B.

2016-02-01

The role that climate and environmental history may have played in influencing human evolution has been the focus of considerable interest and controversy among paleoanthropologists for decades. Prior attempts to understand the environmental history side of this equation have centered around the study of outcrop sediments and fossils adjacent to where fossil hominins (ancestors or close relatives of modern humans) are found, or from the study of deep sea drill cores. However, outcrop sediments are often highly weathered and thus are unsuitable for some types of paleoclimatic records, and deep sea core records come from long distances away from the actual fossil and stone tool remains. The Hominin Sites and Paleolakes Drilling Project (HSPDP) was developed to address these issues. The project has focused its efforts on the eastern African Rift Valley, where much of the evidence for early hominins has been recovered. We have collected about 2 km of sediment drill core from six basins in Kenya and Ethiopia, in lake deposits immediately adjacent to important fossil hominin and archaeological sites. Collectively these cores cover in time many of the key transitions and critical intervals in human evolutionary history over the last 4 Ma, such as the earliest stone tools, the origin of our own genus Homo, and the earliest anatomically modern Homo sapiens. Here we document the initial field, physical property, and core description results of the 2012-2014 HSPDP coring campaign.

Site 765: Sediment Lithostratigraphy

USGS Publications Warehouse

,

1990-01-01

A 935-m-thick succession of Quaternary through Lower Cretaceous sediments was recovered at Site 765 (Fig. 10). A single core of Quaternary sediment was obtained from Hole 765A; drilling terminated and a new hole was drilled in an attempt to establish the mud line. Quaternary through middle Miocene sediments were cored in Hole 765B down to a depth of 395.6 mbsf. Middle Miocene through Lower Cretaceous sediments were cored in Hole 765C, after washing the interval between 0 and 350.2 mbsf. Exact lithologic correlation of the basal cores from Hole 765B with the upper cores from Hole 765C is not possible because of poor recovery; hence, correlation is based solely on matching sub-bottom depths.

The PASADO core processing strategy — A proposed new protocol for sediment core treatment in multidisciplinary lake drilling projects

NASA Astrophysics Data System (ADS)

Ohlendorf, Christian; Gebhardt, Catalina; Hahn, Annette; Kliem, Pierre; Zolitschka, Bernd

2011-07-01

Using the ICDP (International Continental Scientific Drilling Program) deep lake drilling expedition no. 5022 as an example, we describe core processing and sampling procedures as well as new tools developed for subsampling. A manual core splitter is presented that is (1) mobile, (2) able to cut plastic core liners lengthwise without producing swarf of liner material and (3) consists of off-the-shelf components. In order to improve the sampling of sediment cores, a new device, the core sampling assembly (CSA), was developed that meets the following targets: (1) the partitioning of the sediment into discs of equal thickness is fast and precise, (2) disturbed sediment at the inner surface of the liner is discarded during this sampling process, (3) usage of the available sediment is optimised, (4) subsamples are volumetric and oriented, and (5) identical subsamples are taken. The CSA can be applied to D-shaped split sediment cores of any diameter and consists of a divider and a D-shaped scoop. The sampling plan applied for ICDP expedition 5022 is illustrated and may be used as a guideline for planning the efficient partitioning of sediment amongst different lake research groups involved in multidisciplinary projects. For every subsample, the use of quality flags is suggested (1) to document the sample condition, (2) to give a first sediment classification and (3) to guarantee a precise adjustment of logging and scanning data with data determined on individual samples. Based on this, we propose a protocol that might be applied across lake drilling projects in order to facilitate planning and documentation of sampling campaigns and to ensure a better comparability of results.

Towards a distributed infrastructure for research drilling in Europe

NASA Astrophysics Data System (ADS)

Mevel, C.; Gatliff, R.; Ludden, J.; Camoin, G.; Horsfield, B.; Kopf, A.

2012-04-01

The EC-funded project "Deep Sea and Sub-Seafloor Frontier" (DS3F) aims at developing seafloor and sub seafloor sampling strategies for enhanced understanding of deep-sea and sub seafloor processes by connecting marine research in life and geosciences, climate and environmental change, with socio-economic issues and policy building. DS3F has identified access to sub seafloor sampling and instrumentation as a key element of this approach. There is a strong expertise in Europe concerning direct access to the sub seafloor. Within the international program IODP (Integrated Ocean Drilling Program), ECORD (European Consortium for Ocean Research Drilling) has successfully developed the concept of mission specific platforms (MSPs), contracted on a project basis to drill in ice covered and shallow water areas. The ECORD Science Operator, lead by the British Geological Survey (BGS) has build a internationally recognized expertise in scientific ocean drilling, from coring in challenging environment, through down hole measurements and laboratory analysis to core curation and data management. MARUM, at the Bremen University in Germany, is one of the three IODP core repositories. Europe is also at the forefront of scientific seabed drills, with the MeBo developed by MARUM as well as the BGS seabed rocks drills. Europe also plays a important role in continental scientific drilling and the European component of ICDP (International Continental Scientific Drilling Program) is strengthening, with the recent addition of France and foreseen addition of UK. Oceanic and continental drilling have very similar scientific objectives. Moreover, they share not only common technologies, but also common data handling systems. To develop an integrated approach to technology development and usage, a move towards a a distributed infrastructure for research drilling in Europe has been initiated by these different groups. Built on existing research & operational groups across Europe, it will facilitate the sharing of technological and scientific expertise for the benefit of the science community. It will link with other relevant infrastructure initiatives such as EMSO (European Marine Seafloor Observatories). It will raise the profile of scientific drilling in Europe and hopefully lead to better funding opportunities.

New Era of Scientific Ocean Drilling

NASA Astrophysics Data System (ADS)

Eguchi, N.; Toczko, S.; Sanada, Y.; Igarashi, C.; Kubo, Y.; Maeda, L.; Sawada, I.; Takase, K.; Kyo, N.

2014-12-01

The D/V Chikyu, committed to scientific ocean drilling since 2007, has completed thirteen IODP expeditions, and Chikyu's enhanced drilling technology gives us the means to reach deep targets, enhanced well logging, deep water riserless drilling, and state of the art laboratory. Chikyu recovered core samples from 2466 meters below sea floor (mbsf) in IODP Exp. 337, and drilled to 3058.5 mbsf in IODP Exp. 348, but these are still not the limit of Chikyu's capability. As deep as these depths are, they are just halfway to the 5200 mbsf plate boundary target for the NanTroSEIZE deep riser borehole. There are several active IODP proposals in the pipeline. Each has scientific targets requiring several thousand meters of penetration below the sea floor. Riser technology is the only way to collect samples and data from that depth. Well logging has been enhanced with the adoption of riser drilling, especially for logging-while-drilling (LWD). LWD has several advantages over wireline logging, and provides more opportunities for continuous measurements even in unstable boreholes. Because of the larger diameter of riser pipes and enhanced borehole stability, Chikyu can use several state-of-the-art downhole tools, e.g. fracture tester, fluid sampling tool, wider borehole imaging, and the latest sonic tools. These new technologies and tools can potentially expand the envelope of scientific ocean drilling. Chikyu gives us access to ultra-deep water riserless drilling. IODP Exp. 343/343T investigating the March 2011 Tohoku Oki Earthquake, explored the toe of the landward slope of the Japan Trench. This expedition reached the plate boundary fault target at more than 800 mbsf in water depths over 6900 m for logging-while-drilling, coring, and observatory installation. This deep-water drilling capability also expands the scientific ocean drilling envelope and provides access to previously unreachable targets. On top of these operational capabilities, Chikyu's onboard laboratory is equipped with state-of-the-art instruments to analyze all science samples. X-ray CT creates non-destructive 3D images of core samples providing high resolution structural detail. The microbiology laboratory offers clean and contamination-free work environments required for microbiological samples.

Preliminary physical stratigraphy, biostratigraphy, and geophysical data of the USGS South Dover Bridge Core, Talbot County, Maryland

USGS Publications Warehouse

Alemán González, Wilma B.; Powars, David S.; Seefelt, Ellen L.; Edwards, Lucy E.; Self-Trail, Jean M.; Durand, Colleen T.; Schultz, Arthur P.; McLaughlin, Peter P.

2012-01-01

The South Dover Bridge (SDB) corehole was drilled in October 2007 in Talbot County, Maryland. The main purpose for drilling this corehole was to characterize the Upper Cretaceous and Paleogene lithostratigraphy and biostratigraphy of the aquifers and confining units of this region. The data obtained from this core also will be used as a guide to geologic mapping and to help interpret well data from the eastern part of the Washington East 1:100,000-scale map near the town of Easton, Md. Core drilling was conducted to a depth of 700 feet (ft). The Cretaceous section was not penetrated due to technical problems during drilling. This project was funded by the U.S. Geological Survey’s (USGS) Eastern Geology and Paleoclimate Science Center (EGPSC) as part of the Geology of the Atlantic Watersheds Project; this project was carried out in cooperation with the Maryland Geological Survey (MGS) through partnerships with the Aquifer Characterization Program of the USGS’s Maryland-Delaware-District of Columbia Water Science Center and the National Cooperative Geologic Mapping Program. The SDB corehole was drilled by the USGS drilling crew in the northeastern corner of the Trappe 7.5-minute quadrangle, near the type locality of the Boston Cliffs member of the Choptank Formation. Geophysical logs (gamma ray, single point resistance, and 16-inch and 64-inch normal resistivity) were run to a depth of 527.5 ft; the total depth of 700.0 ft could not be reached because of the collapse of the lower part of the hole. Of the 700.0 ft drilled, 531.8 ft of core were recovered, representing a 76 percent core recovery. The elevation of the top of the corehole is approximately 12 ft above mean sea level; its coordinates are lat 38°44′49.34″N. and long 76°00′25.09″W. (38.74704N., 76.00697W. in decimal degrees). A groundwater monitoring well was not installed at this site. The South Dover Bridge corehole was the first corehole that will be used to better understand the geology and hydrology of the Maryland Eastern Shore.

New roles of LWD and wireline logging in scientific ocean drilling

NASA Astrophysics Data System (ADS)

Sanada, Y.; Kido, Y. N.; Moe, K.; Aoike, K.

2014-12-01

D/V Chikyu implemented by CDEX/JAMSTEC joined IODP from 2007. Various LWD (Logging While Drilling) and wireline logging have been carried out in many expeditions and for various purposes. Significant features of logging in Chikyu expeditions are many use of LWD than wireline logging, and riser dirlling. riser selected specific tools for each scientific target, and 3) carried out various borehole experiments. LWD has been more popular than wireline logging in Chikyu expeditions, because its advantages match theirs science targets. The advantages are followings. 1) LWD has more opportunities for measurement in unstable borehole, such as in the series of Nankai trough drilling expeditions. 2) LWD realtime data allows us to make realtime interpretation and operational decision. Realtime interpretation was required to set obsevartory at the properposition. 3) LWD before coring allows us to make a strategy of spot coring.We can design coring intervals for our interest and core length to improve core recovery.Riser drilling brings us merits for logging. One is hole stability (good hole condition) and the other is the use of large diameter tools. Controled drilling mud in riser drilling system prevent mud invasion to formation and mitigates collapse of borehole wall. They reduce the risk of tool stack and improve data quality. Large diameter of riser pipe enhances variation of tool seizes. A couple of new tools were used for new measurement and improvement of the data quality. For example, SonicScanner (trademark of Schulumberger) successfully measured compressional and share velocity in very low velocities at the soft sediment, where it has been difficult to measure them with conventional DSI tool (Exp319). The stress and pore pressure in the borehole were measured with the wireline logging tool, (Schlumberger MDT). The single probe tool enable to measure temporal formation fluid pressure. The double packer tool enable to fracture test by sealing and pumping in the borehole. These in-situ measurement and stress experiment data are very important to understand physical properties and mechanism of fault zone (Exp319).Those new technologies and tools also expand the envelope of scientific ocean drilling.

The Search for Subsurface Life on Mars: Results from the MARTE Analog Drill Experiment in Rio Tinto, Spain

NASA Astrophysics Data System (ADS)

Stoker, C. R.; Lemke, L. G.; Cannon, H.; Glass, B.; Dunagan, S.; Zavaleta, J.; Miller, D.; Gomez-Elvira, J.

2006-03-01

The Mars Analog Research and Technology (MARTE) experiment has developed an automated drilling system on a simulated Mars lander platform including drilling, sample handling, core analysis and down-hole instruments relevant to searching for life in the Martian subsurface.

43 CFR 3150.0-5 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-10-01

... and trails and cross-country transit of vehicles over such lands. It does not include core drilling for subsurface geologic information or drilling for oil and gas; these activities shall be authorized only by the issuance of an oil and gas lease and the approval of an Application for a Permit to Drill...

43 CFR 3150.0-5 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-10-01

... and trails and cross-country transit of vehicles over such lands. It does not include core drilling for subsurface geologic information or drilling for oil and gas; these activities shall be authorized only by the issuance of an oil and gas lease and the approval of an Application for a Permit to Drill...

43 CFR 3150.0-5 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-10-01

... and trails and cross-country transit of vehicles over such lands. It does not include core drilling for subsurface geologic information or drilling for oil and gas; these activities shall be authorized only by the issuance of an oil and gas lease and the approval of an Application for a Permit to Drill...

40 CFR 146.14 - Information to be considered by the Director.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., logging procedures, deviation checks, and a drilling, testing, and coring program; and (16) A certificate... information listed below which are current and accurate in the file. For a newly drilled Class I well, the..., construction, date drilled, location, depth, record of plugging and/or completion, and any additional...

Rotary Percussive Auto-Gopher for Deep Drilling and Sampling

NASA Technical Reports Server (NTRS)

Bar-Cohen, Yoseph; Badescu, Mircea; Sherrit, Stewart

2009-01-01

The term "rotary percussive auto-gopher" denotes a proposed addition to a family of apparatuses, based on ultrasonic/ sonic drill corers (USDCs), that have been described in numerous previous NASA Tech Briefs articles. These apparatuses have been designed, variously, for boring into, and/or acquiring samples of, rock or other hard, brittle materials of geological interest. In the case of the rotary percussive autogopher, the emphasis would be on developing an apparatus capable of penetrating to, and acquiring samples at, depths that could otherwise be reached only by use of much longer, heavier, conventional drilling-and-sampling apparatuses. To recapitulate from the prior articles about USDCs: A USDC can be characterized as a lightweight, low-power jackhammer in which a piezoelectrically driven actuator generates ultrasonic vibrations and is coupled to a tool bit through a free mass. The bouncing of the free mass between the actuator horn and the drill bit converts the actuator ultrasonic vibrations into sonic hammering of the drill bit. The combination of ultrasonic and sonic vibrations gives rise to a hammering action (and a resulting chiseling action at the tip of the tool bit) that is more effective for drilling than is the microhammering action of ultrasonic vibrations alone. The hammering and chiseling actions are so effective that the size of the axial force needed to make the tool bit advance into soil, rock, or another material of interest is much smaller than in ordinary rotary drilling, ordinary hammering, or ordinary steady pushing. The predecessor of the rotary percussive auto-gopher is an apparatus, now denoted an ultrasonic/sonic gopher and previously denoted an ultrasonic gopher, described in "Ultrasonic/ Sonic Mechanism for Drilling and Coring" (NPO-30291), NASA Tech Briefs Vol. 27, No. 9 (September 2003), page 65. The ultrasonic/sonic gopher is intended for use mainly in acquiring cores. The name of the apparatus reflects the fact that, like a gopher, it periodically stops advancing at the end of the hole to bring excavated material (in this case, a core sample) to the surface, then re-enters the hole to resume the advance of the end of the hole. By use of a cable suspended from a reel on the surface, the gopher is lifted from the hole to remove a core sample, then lowered into the hole to resume the advance and acquire the next core sample.

Detachment Faulting, Serpentinization, Fluids and Life: Preliminary Results of IODP Expedition 357 (Atlantis Massif, MAR 30°N)

NASA Astrophysics Data System (ADS)

Fruh-Green, G. L.; Orcutt, B.; Green, S.; Cotterill, C.

2016-12-01

We present an overview of IODP Expedition 357, which successfully used two seabed rock drills to core 17 shallow holes at 9 sites across Atlantis Massif (Mid-Atlantic Ridge 30°N). A major goal of this expedition is to investigate serpentinization processes and microbial activity in the shallow subsurface of highly altered ultramafic and mafic sequences that have been uplifted to the seafloor along a major detachment fault zone. More than 57 m of core were recovered, with borehole penetration ranging from 1.3 to 16.4 meters below seafloor, and core recovery as high as 75% of total penetration. The cores show highly heterogeneous rock type, bulk rock chemistry and alteration that reflect multiple phases of magmatism and fluid-rock interaction within the detachment fault zone. In cores along an E-W transect of the southern wall, recovered mantle peridotites are locally intruded by gabbroic and doleritic dikes and veins. The proportion of mafic rocks are volumetrically less than the amount of mafic rocks recovered previously in the central dome at IODP Site U1309, suggesting a lower degree of melt infiltration into mantle peridotite at the ridge-transform intersection. New technologies were developed and successfully applied for the first time: (1) an in-situ sensor package and water sampling system on each seabed drill measured real-time variations in dissolved methane, oxygen, pH, oxidation reduction potential, temperature, and conductivity during drilling and took water samples after drilling; (2) a borehole plug system to seal the boreholes was successfully deployed at two sites to allow access for future sampling; and (3) delivery of chemical tracers into the drilling fluids for contamination testing. We will provide an overview of the drilling strategy and preliminary results of Expedition 357, and highlight the role of serpentinization in sustaining microbial communities in a region of active serpentinization and low temperature hydrothermal alteration.

Chew Bahir: A Key Site within the Hominin Sites and Paleolakes Drilling Project, towards a Half Million-Year Climate Record from Southern Ethiopia

NASA Astrophysics Data System (ADS)

Schaebitz, F.; Asrat, A.; Lamb, H. F.; Trauth, M. H.; Foerster, V. E.; Junginger, A.; Raub, T. D.; Gromig, R.; Viehberg, F. A.; Roberts, H. M.; Cohen, A.

2015-12-01

Chew Bahir, a saline mudflat today, is one of the five sites in East Africa, drilled within the framework of HSPDP (Hominin Site and Paleolakes Drilling Project). It is also one of the key sites of the Collaborative Research Centre (CRC-806) "Our way to Europe" aiming at the reconstruction of environmental conditions in the source region of modern man (H. sapiens). It is suggested that a changing environment could have triggered the mobility and dispersal of modern man. The oldest known fossils of anatomical modern humans (~195 ka BP) were found in the Omo basin, not more than 90km westwards of our drill site. The deposits in the tectonic basin of Chew Bahir in southern Ethiopia were cored in Nov. 2014 in two boreholes down to 280 m and 260 m below surface respectively. The overlapping long cores (drilled ~20 m apart from each other), were opened, scanned, described and sampled in low resolution in April 2015. The recovered sediments mostly contain green-greyish to light coloured and brown to reddish clays and silty clays, interbedded with some laminated mica-rich sand layers and occurrences of carbonate concretions and nodules, which decrease upcore. Here we will present a first set of results on the composite core, comprising mainly lithology and magnetic susceptibility (MS). Based on known sedimentation rates from pre-studies performed on short cores across the basin, we anticipate the deep drilled cores to cover at least 500 ka BP. Moreover, new insights into the role of post-depositional alteration, especially of clay minerals and zeolites, will be presented as a contribution to an improved understanding of formation processes. The results support the identification of wet and dry climate periods in the past. Those pronounced variations of moisture availability, are thought to have influenced the evolution and mobility of Homo sapiens sapiens.

Computational studies of metal-metal and metal-ligand interactions

NASA Technical Reports Server (NTRS)

Barnes, Leslie A.

1992-01-01

The geometric structure of Cr(CO)6 is optimized at the modified coupled-pair functional (MCPF), single and double excitation coupled-cluster (CCSD) and CCSD(T) levels of theory (including a perturbational estimate for connected triple excitations), and the force constants for the totally symmetric representation are determined. The geometry of Cr(CO)5 is partially optimized at the MCPF, CCSD and CCSD(T) levels of theory. Comparison with experimental data shows that the CCSD(T) method gives the best results for the structures and force constants, and that remaining errors are probably due to deficiencies in the one-particle basis sets used for CO. A detailed comparison of the properties of free CO is therefore given, at both the MCPF and CCSD/CCSD(T) levels of treatment, using a variety of basis sets. With very large one-particle basis sets, the SSCD(T) method gives excellent results for the bond distance, dipole moment and harmonic frequency of free CO. The total binding energies of Cr(CO)6 and Cr(CO)5 are also determined at the MCPF, CCSD and CCSD(T) levels of theory. The CCSD(T) method gives a much larger total binding energy than either the MCPF or CCSD methods. An analysis of the basis set superposition error (BSSE) at the MCPF level of treatment points out limitations in the one-particle basis used here and in a previous study. Calculations using larger basis sets reduced the BSSE, but the total binding energy of Cr(CO)6 is still significantly smaller than the experimental value, although the first CO bond dissociation energy of Cr(CO)6 is well described. An investigation of 3s3p correlation reveals only a small effect. The remaining discrepancy between the experimental and theoretical total binding energy of Cr(CO)6 is probably due to limitations in the one-particle basis, rather than limitations in the correlation treatment. In particular an additional d function and an f function on each C and O are needed to obtain quantitative results. This is underscored by the fact that even using a very large primitive se (1042 primitive functions contracted to 300 basis functions), the superposition error for the total binding energy of Cr(CO)6 is 22 kcal/mol at the MCPF level of treatment.

The remarkable chemical uniformity of Apollo 16 layered deep drill core section 60002

NASA Technical Reports Server (NTRS)

Nava, D. F.; Philpotts, J. A.; Lindstrom, M. M.; Schuhmann, P. J.; Lindstrom, D. J.

1976-01-01

Atomic absorption and colorimetric spectrophotometers were used to determine major- and minor-element abundances in 12 samples from layered section 60002 of the Apollo 16 deep drill core. It is suggested that gardening of a relatively thick local unit produced the layering in this section in such a manner that the proportions of materials of different compositions remained virtually unchanged.

New approaches to subglacial bedrock drilling technology

NASA Astrophysics Data System (ADS)

Talalay, Pavel; Sun, Youhong; Zhao, Yue; Xue, Jun; Chen, Chen; Markov, Alexey; Xu, Huiwen; Gong, Wenbin; Han, Wei; Zheng, Zhichuan; Cao, Pinlu; Wang, Rusheng; Zhang, Nan; Yu, Dahui; Fan, Xiaopeng; Hu, Zhengyi; Yang, Cheng; Han, Lili; Sysoev, Mikhail

2013-04-01

Drilling to bedrock of ice sheets and glaciers offers unique opportunities to research processes acting at the bed for paleo-climatic and paleo-environmental recording, basal sliding studies, subglacial geology and tectonics investigations, prospecting and exploration for minerals covered by ice. Retrieving bedrock samples under ice sheets and glaciers is a very difficult task. Drilling operations are complicated by extremely low temperature at the surface of, and within glaciers, and by glacier flow, the absence of roads and infrastructures, storms, winds, snowfalls, etc. In order to penetrate through the ice sheet or glacier up to the depth of at least 1000 m and to pierce the bedrock to the depth of several meters from ice - bedrock boundary the development activity already has been started in Polar Research Center at Jilin University, China. All drilling equipment (two 50-kW diesel generators, winch, control desk, fluid dumping station, etc.) is installed inside a movable sledge-mounted warm-keeping and wind-protecting drilling shelter that has dimensions of 8.8 ×2.8 × 3.0 m. Mast has two positions: horizontal for transportation and vertical working position (mast height is 12 m). Drilling shelter can be transported to the chosen site with crawler-tractor, aircraft or helicopter. In case of carriage by air the whole drilling shelter was designed to be disassembled into pieces "small" enough to ship by aircraft. Weight and sizes of each component has been minimized to lower the cost of transportation and to meet weight restrictions for transportation. Total weight of drilling equipment (without drilling fluid) is near 15 tons. Expected time of assembling and preparing for drilling is 2 weeks. If drilling shelter is transported with crawler-tractor (for example, in Antarctic traverses) all equipment is ready to start drilling immediately upon arrival to the site. To drill through ice and bedrock a new, modified version of the cable-suspended electromechanical ice core drill is designed and tested. The expected average daily production of ice drilling would be not less than 25 m/day. The lower part of the drill is adapted for coring bed-rock using special tooth diamond bit. Deep ice coring requires a drilling fluid in the borehole during operation in order to keep the hole open and to compensate the hydrostatic pressures acting to close it. At present there are no ideal low-temperature drilling fluids as all of them are environmental and health hazardous substances. The new approaches of subglacial bedrock drilling technology are connected with utilization of environmental friendly, low-toxic materials, e.g. low-molecular dimethyl siloxane oils or aliphatic synthetic ester of ESTISOL™ 140 type. They have suitable density-viscosity properties, and can be consider as a viable alternative for drilling in glaciers and subglacial bedrock.

Physical property data from the ICDP-USGS Eyreville cores A and B, Chesapeake Bay impact structure, Virginia, USA, acquired using a multisensor core logger

USGS Publications Warehouse

Pierce, H.A.; Murray, J.B.

2009-01-01

The International Continental Scientific Drilling Program (ICDP) and the U.S. Geological Survey (USGS) drilled three core holes to a composite depth of 1766 m within the moat of the Chesapeake Bay impact structure. Core recovery rates from the drilling were high (??90%), but problems with core hole collapse limited the geophysical downhole logging to natural-gamma and temperature logs. To supplement the downhole logs, ??5% of the Chesapeake Bay impact structure cores was processed through the USGS GeoTek multisensor core logger (MSCL) located in Menlo Park, California. The measured physical properties included core thickness (cm), density (g cm-3), P-wave velocity (m s-1), P-wave amplitude (%), magnetic susceptibility (cgs), and resistivity (ohm-m). Fractional porosity was a secondary calculated property. The MSCL data-sampling interval for all core sections was 1 cm longitudinally. Photos of each MSCL sampled core section were imbedded with the physical property data for direct comparison. These data have been used in seismic, geologic, thermal history, magnetic, and gravity models of the Chesapeake Bay impact structure. Each physical property curve has a unique signature when viewed over the full depth of the Chesapeake Bay impact structure core holes. Variations in the measured properties reflect differences in pre-impact target-rock lithologies and spatial variations in impact-related deformation during late-stage crater collapse and ocean resurge. ?? 2009 The Geological Society of America.

Empirical relations of rock properties of outcrop and core samples from the Northwest German Basin for geothermal drilling

NASA Astrophysics Data System (ADS)

Reyer, D.; Philipp, S. L.

2014-09-01

Information about geomechanical and physical rock properties, particularly uniaxial compressive strength (UCS), are needed for geomechanical model development and updating with logging-while-drilling methods to minimise costs and risks of the drilling process. The following parameters with importance at different stages of geothermal exploitation and drilling are presented for typical sedimentary and volcanic rocks of the Northwest German Basin (NWGB): physical (P wave velocities, porosity, and bulk and grain density) and geomechanical parameters (UCS, static Young's modulus, destruction work and indirect tensile strength both perpendicular and parallel to bedding) for 35 rock samples from quarries and 14 core samples of sandstones and carbonate rocks. With regression analyses (linear- and non-linear) empirical relations are developed to predict UCS values from all other parameters. Analyses focus on sedimentary rocks and were repeated separately for clastic rock samples or carbonate rock samples as well as for outcrop samples or core samples. Empirical relations have high statistical significance for Young's modulus, tensile strength and destruction work; for physical properties, there is a wider scatter of data and prediction of UCS is less precise. For most relations, properties of core samples plot within the scatter of outcrop samples and lie within the 90% prediction bands of developed regression functions. The results indicate the applicability of empirical relations that are based on outcrop data on questions related to drilling operations when the database contains a sufficient number of samples with varying rock properties. The presented equations may help to predict UCS values for sedimentary rocks at depth, and thus develop suitable geomechanical models for the adaptation of the drilling strategy on rock mechanical conditions in the NWGB.

How computational methods and relativistic effects influence the study of chemical reactions involving Ru-NO complexes?

PubMed

Orenha, Renato Pereira; Santiago, Régis Tadeu; Haiduke, Roberto Luiz Andrade; Galembeck, Sérgio Emanuel

2017-05-05

Two treatments of relativistic effects, namely effective core potentials (ECP) and all-electron scalar relativistic effects (DKH2), are used to obtain geometries and chemical reaction energies for a series of ruthenium complexes in B3LYP/def2-TZVP calculations. Specifically, the reaction energies of reduction (A-F), isomerization (G-I), and Cl - negative trans influence in relation to NH 3 (J-L) are considered. The ECP and DKH2 approaches provided geometric parameters close to experimental data and the same ordering for energy changes of reactions A-L. From geometries optimized with ECP, the electronic energies are also determined by means of the same ECP and basis set combined with the computational methods: MP2, M06, BP86, and its derivatives, so as B2PLYP, LC-wPBE, and CCSD(T) (reference method). For reactions A-I, B2PLYP provides the best agreement with CCSD(T) results. Additionally, B3LYP gave the smallest error for the energies of reactions J-L. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

The 1500m South Pole Ice Core: Recovering a 40 Ka Environmental Record

NASA Technical Reports Server (NTRS)

Casey, Kimberly Ann; Neumann, Thomas Allen; Fudge, T. J.; Neumann, T. A.; Steig, E. J.; Cavitte, M. G. P.; Blankenship, D. D.

2014-01-01

Supported by the US National Science Foundation, a new 1500 m, approximately 40 ka old ice core will be recovered from South Pole during the 2014/15 and 2015/16 austral summer seasons using the new US Intermediate Depth Drill. The combination of low temperatures, relatively high accumulation rates and low impurity concentrations at South Pole will yield detailed records of ice chemistry and trace atmospheric gases. The South Pole ice core will provide a climate history record of a unique area of the East Antarctic plateau that is partly influenced by weather systems that cross the West Antarctic ice sheet. The ice at South Pole flows at approximately 10m a(exp-1) and the South Pole ice-core site is a significant distance from an ice divide. Therefore, ice recovered at depth originated progressively farther upstream of the coring site. New ground-penetrating radar collected over the drill site location shows no anthropogenic influence over the past approximately 50 years or upper 15 m. Depth-age scale modeling results show consistent and plausible annual-layer thicknesses and accumulation rate histories, indicating that no significant stratigraphic disturbances exist in the upper 1500m near the ice-core drill site.

Integrated NMR Core and Log Investigations With Respect to ODP LEG 204

NASA Astrophysics Data System (ADS)

Arnold, J.; Pechnig, R.; Clauser, C.; Anferova, S.; Blümich, B.

2005-12-01

NMR techniques are widely used in the oil industry and are one of the most suitable methods to evaluate in-situ formation porosity and permeability. Recently, efforts are directed towards adapting NMR methods also to the Ocean Drilling Program (ODP) and the upcoming Integrated Ocean Drilling Program (IODP). We apply a newly developed light-weight, mobile NMR core scanner as a non-destructive instrument to determine routinely rock porosity and to estimate the pore size distribution. The NMR core scanner is used for transverse relaxation measurements on water-saturated core sections using a CPMG sequence with a short echo time. A regularized Laplace-transform analysis yields the distribution of transverse relaxation times T2. In homogeneous magnetic fields, T2 is proportional to the pore diameter of rocks. Hence, the T2 signal maps the pore-size distribution of the studied rock samples. For fully saturated samples the integral of the distribution curve and the CPMG echo amplitude extrapolated to zero echo time are proportional to porosity. Preliminary results show that the NMR core scanner is a suitable tool to determine rock porosity and to estimate pore size distribution of limestones and sandstones. Presently our investigations focus on Leg 204, where NMR Logging-While-Drilling (LWD) was performed for the first time in ODP. Leg 204 was drilled into Hydrate Ridge on the Cascadia accretionary margin, offshore Oregon. All drilling and logging operations were highly successful, providing excellent core, wireline, and LWD data from adjacent boreholes. Cores recovered during Leg 204 consist mainly of clay and claystone. As the NMR core scanner operates at frequencies higher than that of the well-logging sensor it has a shorter dead time. This advantage makes the NMR core scanner sensitive to signals with T2 values down to 0.1 ms as compared to 3 ms in NMR logging. Hence, we can study even rocks with small pores, such as the mudcores recovered during Leg 204. We present a comparison of data from core scanning and NMR logging. Future integration of conventional wireline data and electrical borehole wall images (RAB/FMS) will provide a detailed characterization of the sediments in terms of lithology, petrophysics and, fluid flow properties.

San Andreas fault zone drilling project: scientific objectives and technological challenges

USGS Publications Warehouse

Hickman, Stephen; Younker, Leland; Zobeck, Mark; Cooper, George; ,

1994-01-01

We are leading a new international initiative to conduct scientific drilling within the San Andreas fault zone at depths of up to 10 km. This project is motivated by the need to understand the physical and chemical processes operating within the fault zone and to answer fundamental questions about earthquake generation along major plate-boundary faults. Through an integrated program of coring, fluid sampling, in-situ and laboratory experimentation and long-term monitoring, we hope to provide fundamental constraints on the structure, composition, mechanical behavior and physical state of the San Andreas fault system at depths comparable to the nucleation zones of great earthquakes. The drilling, sampling and observational requirements needed to ensure the success of this project are stringent. These include: 1) drilling stable vertical holes to depths of about 9 km in fractured rock at temperatures of up to 300??C; 2) continuous coring of inclined holes branched off these vertical boreholes to intersect the fault at depths of 3, 6 and 9 km; 3) conducting sophisticated borehole geophysical measurements and fluid/rock sampling at high temperatures and pressures; and 4) instrumenting some or all of these inclined core holes for continuous monitoring of seismicity and a broad range of physical and chemical properties over periods of up to several decades. For all of these tasks, because of the overpressured clay-rich formations anticipated within the fault zone at depth, we expect to encounter difficult drilling, coring and hole-completion conditions in the regions of greatest scientific interest.

San Andreas fault zone drilling project: scientific objectives and technological challenges

USGS Publications Warehouse

Hickman, S.H.; Younker, L.W.; Zoback, M.D.

1995-01-01

We are leading a new international initiative to conduct scientific drilling within the San Andreas fault zone at depths of up to 10 km. This project is motivated by the need to understand the physical and chemical processes operating within the fault zone and to answer fundamental questions about earthquake generation along major plate-boundary faults. Through a comprehensive program of coring, fluid sampling, downhole measurements, laboratory experimentation, and long-term monitoring, we hope to obtain critical information on the structure, composition, mechanical behavior and physical state of the San Andreas fault system at depths comparable to the nucleation zones of great earthquakes. The drilling, sampling and observational requirements needed to ensure the success of this project are stringent. These include: 1) drilling stable vertical holes to depths of about 9 km in fractured rock at temperatures of up to 300°C; 2) continuous coring and completion of inclined holes branched off these vertical boreholes to intersect the fault at depths of 3, 6, and 9 km; 3) conducting sophisticated borehole geophysical measurements and fluid/rock sampling at high temperatures and pressures; and 4) instrumenting some or all of these inclined core holes for continuous monitoring of earthquake activity, fluid pressure, deformation and other parameters for periods of up to several decades. For all of these tasks, because of the overpressured clay-rich formations anticipated within the fault zone at depth, we expect to encounter difficult drilling, coring and hole-completion conditions in the region of greatest scientific interest.

The structure and energetics of Cr(CO)6 and Cr(CO)5

NASA Technical Reports Server (NTRS)

Barnes, Leslie A.; Liu, Bowen; Lindh, Roland

1992-01-01

The geometric structure of Cr(CO)6 is optimized at the modified coupled pair functional (MCPF), single and double excitation coupled-cluster (CCSD) and CCSD(T) levels of theory (including a perturbational estimate for connected triple excitations), and the force constants for the totally symmetric representation are determined. The geometry of Cr(CO)5 is partially optimized at the MCPF, CCSD, and CCSD(T) levels of theory. Comparison with experimental data shows that the CCSD(T) method gives the best results for the structures and force constants, and that remaining errors are probably due to deficiencies in the one-particle basis sets used for CO. The total binding energies of Cr(CO)6 and Cr(CO)5 are also determined at the MCPF, CCSD, and CCSD(T) levels of theory. The CCSD(T) method gives a much larger total binding energy than either the MCPF or CCSD methods. An analysis of the basis set superposition error (BSSE) at the MCPF level of treatment points out limitations in the one-particle basis used. Calculations using larger basis sets reduce the BSSE, but the total binding energy of Cr(CO)6 is still significantly smaller than the experimental value, although the first CO bond dissociation energy of Cr(CO)6 is well described. An investigation of 3s3p correlation reveals only a small effect. In the largest basis set, the total CO binding energy of Cr(CO)6 is estimated to be 140 kcal/mol at the CCSD(T) level of theory, or about 86 percent of the experimental value. The remaining discrepancy between the experimental and theoretical value is probably due to limitations in the one-particle basis, rather than limitations in the correlation treatment. In particular an additional d function and an f function on each C and O are needed to obtain quantitative results. This is underscored by the fact that even using a very large primitive set (1042 primitive functions contracted to 300 basis functions), the superposition error for the total binding energy of Cr(CO)6 is 22 kcal/mol at the MCPF level of treatment.

Sample Acquisition and Caching architecture for the Mars Sample Return mission

NASA Astrophysics Data System (ADS)

Zacny, K.; Chu, P.; Cohen, J.; Paulsen, G.; Craft, J.; Szwarc, T.

This paper presents a Mars Sample Return (MSR) Sample Acquisition and Caching (SAC) study developed for the three rover platforms: MER, MER+, and MSL. The study took into account 26 SAC requirements provided by the NASA Mars Exploration Program Office. For this SAC architecture, the reduction of mission risk was chosen by us as having greater priority than mass or volume. For this reason, we selected a “ One Bit per Core” approach. The enabling technology for this architecture is Honeybee Robotics' “ eccentric tubes” core breakoff approach. The breakoff approach allows the drill bits to be relatively small in diameter and in turn lightweight. Hence, the bits could be returned to Earth with the cores inside them with only a modest increase to the total returned mass, but a significant decrease in complexity. Having dedicated bits allows a reduction in the number of core transfer steps and actuators. It also alleviates the bit life problem, eliminates cross contamination, and aids in hermetic sealing. An added advantage is faster drilling time, lower power, lower energy, and lower Weight on Bit (which reduces Arm preload requirements). Drill bits are based on the BigTooth bit concept, which allows re-use of the same bit multiple times, if necessary. The proposed SAC consists of a 1) Rotary-Percussive Core Drill, 2) Bit Storage Carousel, 3) Cache, 4) Robotic Arm, and 5) Rock Abrasion and Brushing Bit (RABBit), which is deployed using the Drill. The system also includes PreView bits (for viewing of cores prior to caching) and Powder bits for acquisition of regolith or cuttings. The SAC total system mass is less than 22 kg for MER and MER+ size rovers and less than 32 kg for the MSL-size rover.

Listvenite logging on D/V CHIKYU: Hole BT1B, Oman Drilling Project

NASA Astrophysics Data System (ADS)

Kelemen, P. B.; Beinlich, A.; Morishita, T.; Greenberger, R. N.; Johnson, K. T. M.; Lafay, R.; Michibayashi, K.; Harris, M.; Phase I Science Party, T. O. D. P.

2017-12-01

Listvenite, quartz-carbonate altered ultramafic rock containing minor fuchsite (Cr-muscovite) forms by complete carbonation of peridotite and is thus an attractive objective for carbon mitigation studies. However, reaction controls and evolution of listvenite are still enigmatic. Here we present the first results of Phase 1 of the ICDP (International Continental Drilling Program) Oman Drilling Project and subsequent core logging using the analytical facilities on board the research vessel D/V CHIKYU. Hole BT1B contains 300 m of continuous drill core intersecting alluvium, listvenite-altered serpentinite, serpentinite, ophicarbonate and the underlying metamorphic sole of the Semail ophiolite, Oman. The drill core has been systematically investigated by visual core description, thin section petrography, X-ray fluorescence core logging, X-ray diffractometry, visible-shortwave infrared imaging spectroscopy and X-ray Computer Tomography. Our observations show that listvenite is highly variable in texture and color on the mm to m scale. Listvenite was visually categorized into 5 principal color groups: the dominant dark red (47 %), light red (19 %), orange (14 %), pale (2 %) and green (16 %). The presence of hematite/goethite results in dark reddish, red and orange hues. Light grey or pale colored listvenite lacks hematite and/or goethite veins and may represent the `true' listvenite. Green listvenite is characterized by the presence of cm-sized quartz-fuchsite intergrowths. Five zones of serpentinite, which vary in thickness between several tens of cm and 4 m, are intercalated within the massive listvenite of Hole BT1B. Gradational listvenite-serpentinite transition zones contain the ophicarbonate assemblage (magnesite + serpentine) and sometimes additional talc, representing intermediate carbonation reaction progress. Preservation of the former mesh texture and bastite after orthopyroxene in the listvenite suggest that the listvenite precursor had already been serpentinized prior to infiltration of the CO2-bearing alteration fluid.

Contamination Control of Freeze Shoe Coring System for Collection of Aquifer Sands

NASA Astrophysics Data System (ADS)

Homola, K.; van Geen, A.; Spivack, A. J.; Grzybowski, B.; Schlottenmier, D.

2017-12-01

We have developed and tested an original device, the freeze-shoe coring system, designed to recover undisturbed samples of water contained in sand-dominated aquifers. Aquifer sands are notoriously difficult to collect together with porewater from coincident depths, as high hydraulic permeability leads to water drainage and mixing during retrieval. Two existing corer designs were reconfigured to incorporate the freeze-shoe system; a Hydraulic Piston (HPC) and a Rotary (RC) Corer. Once deployed, liquid CO­2 contained in an interior tank is channeled to coils at the core head where it changes phase, rapidly cooling the deepest portion of the core. The resulting frozen core material impedes water loss during recovery. We conducted contamination tests to examine the integrity of cores retrieved during a March 2017 yard test deployment. Perfluorocarbon tracer (PFC) was added to the drill fluid and recovered cores were subsampled to capture the distribution of PFC throughout the core length and interior. Samples were collected from two HPC and one RC core and analyzed for PFC concentrations. The lowest porewater contamination, around 0.01% invasive fluid, occurs in the center of both HPC cores. The greatest contamination (up to 10%) occurs at the disturbed edges where core material contacts drill fluid. There was lower contamination in the core interior than top, bottom, and edges, as well as significantly lower contamination in HPC cores that those recovered with the RC. These results confirm that the freeze-shoe system, proposed for field test deployments in West Bengal, India, can successfully collect intact porewater and sediment material with minimal if any contamination from drill fluid.

Precision of computer-assisted core decompression drilling of the knee.

PubMed

Beckmann, J; Goetz, J; Bäthis, H; Kalteis, T; Grifka, J; Perlick, L

2006-06-01

Core decompression by exact drilling into the ischemic areas is the treatment of choice in early stages of osteonecrosis of the femoral condyle. Computer-aided surgery might enhance the precision of the drilling and lower the radiation exposure time of both staff and patients. The aim of this study was to evaluate the precision of the fluoroscopically based VectorVision-navigation system in an in vitro model. Thirty sawbones were prepared with a defect filled up with a radiopaque gypsum sphere mimicking the osteonecrosis. 20 sawbones were drilled by guidance of an intraoperative navigation system VectorVision (BrainLAB, Munich, Germany). Ten sawbones were drilled by fluoroscopic control only. A statistically significant difference with a mean distance of 0.58 mm in the navigated group and 0.98 mm in the control group regarding the distance to the desired mid-point of the lesion could be stated. Significant difference was further found in the number of drilling corrections as well as radiation time needed. The fluoroscopic-based VectorVision-navigation system shows a high feasibility and precision of computer-guided drilling with simultaneously reduction of radiation time and therefore could be integrated into clinical routine.

Femoral head necrosis: A finite element analysis of common and novel surgical techniques.

PubMed

Cilla, Myriam; Checa, Sara; Preininger, Bernd; Winkler, Tobias; Perka, Carsten; Duda, Georg N; Pumberger, Matthias

2017-10-01

Femoral head necrosis is a common cause of secondary osteoarthritis. At the early stages, treatment strategies are normally based on core decompression techniques, where the number, location and diameter of the drilling holes varies depending on the selected approach. The purpose of this study was to investigate the risk of femoral head, neck and subtrochanteric fracture following six different core decompression techniques. Five common and a newly proposed techniques were analyzed in respect to their biomechanical consequences using finite element analysis. The geometry of a femur was reconstructed from computed-tomography images. Thereafter, the drilling configurations were simulated. The strains in the intact and drilled femurs were determined under physiological, patient-specific, muscle and joint contact forces. The following results were observed: i) - an increase in collapse and fracture risk of the femur head by disease progression ii) - for a single hole approach at the subtrochanteric region, the fracture risk increases with the diameter iii) - the highest fracture risks occur for an 8mm single hole drilling at the subtrochanteric region and approaches with multiple drilling at various entry points iv) - the proposed novel approach resulted in the most physiological strains (closer to the experienced by the healthy bone). Our results suggest that all common core decompression methods have a significant impact on the biomechanical competence of the proximal femur and impact its mechanical potential. Fracture risk increases with drilling diameter and multiple drilling with smaller diameter. We recommend the anterior approach due to its reduced soft tissue trauma and its biomechanical performance. Copyright © 2017 Elsevier Ltd. All rights reserved.

An efficient and near linear scaling pair natural orbital based local coupled cluster method.

PubMed

Riplinger, Christoph; Neese, Frank

2013-01-21

In previous publications, it was shown that an efficient local coupled cluster method with single- and double excitations can be based on the concept of pair natural orbitals (PNOs) [F. Neese, A. Hansen, and D. G. Liakos, J. Chem. Phys. 131, 064103 (2009)]. The resulting local pair natural orbital-coupled-cluster single double (LPNO-CCSD) method has since been proven to be highly reliable and efficient. For large molecules, the number of amplitudes to be determined is reduced by a factor of 10(5)-10(6) relative to a canonical CCSD calculation on the same system with the same basis set. In the original method, the PNOs were expanded in the set of canonical virtual orbitals and single excitations were not truncated. This led to a number of fifth order scaling steps that eventually rendered the method computationally expensive for large molecules (e.g., >100 atoms). In the present work, these limitations are overcome by a complete redesign of the LPNO-CCSD method. The new method is based on the combination of the concepts of PNOs and projected atomic orbitals (PAOs). Thus, each PNO is expanded in a set of PAOs that in turn belong to a given electron pair specific domain. In this way, it is possible to fully exploit locality while maintaining the extremely high compactness of the original LPNO-CCSD wavefunction. No terms are dropped from the CCSD equations and domains are chosen conservatively. The correlation energy loss due to the domains remains below <0.05%, which implies typically 15-20 but occasionally up to 30 atoms per domain on average. The new method has been given the acronym DLPNO-CCSD ("domain based LPNO-CCSD"). The method is nearly linear scaling with respect to system size. The original LPNO-CCSD method had three adjustable truncation thresholds that were chosen conservatively and do not need to be changed for actual applications. In the present treatment, no additional truncation parameters have been introduced. Any additional truncation is performed on the basis of the three original thresholds. There are no real-space cutoffs. Single excitations are truncated using singles-specific natural orbitals. Pairs are prescreened according to a multipole expansion of a pair correlation energy estimate based on local orbital specific virtual orbitals (LOSVs). Like its LPNO-CCSD predecessor, the method is completely of black box character and does not require any user adjustments. It is shown here that DLPNO-CCSD is as accurate as LPNO-CCSD while leading to computational savings exceeding one order of magnitude for larger systems. The largest calculations reported here featured >8800 basis functions and >450 atoms. In all larger test calculations done so far, the LPNO-CCSD step took less time than the preceding Hartree-Fock calculation, provided no approximations have been introduced in the latter. Thus, based on the present development reliable CCSD calculations on large molecules with unprecedented efficiency and accuracy are realized.

Chemistry and petrology of size fractions of Apollo 17 deep drill core 70009-70006

NASA Technical Reports Server (NTRS)

Laul, J. C.; Vaniman, D. T.; Papike, J. J.; Simon, S.

1978-01-01

Instrumental neutron activation analysis was used to examine 34 major, minor and trace elements in 48 bulk soils and size fractions (90-1000 microns, 20-90 microns and less than 20 microns) of the Apollo 17 deep drill core sections 70009-70006 (upper 130 cm). Modal data were also obtained for the less than 20 micron size fraction. Preliminary results indicate that (1) the chemistry of the greater than 90 micron and 20-90 micron coarse fractions is identical but quite different from the less than 20 micron fine fraction; (2) the upper 50 cm of the drill core is highly enriched in mare material; (3) the dominant source of highland material is KREEPy instead of anorthositic; and (4) indigenous volatiles such as Zn are quite high in all size fractions.

Characteristics of crushed rocks observed in drilled cores in landslide bodies located in accretionary complexes

NASA Astrophysics Data System (ADS)

Wakizaka, Yasuhiko

2013-10-01

The recent development of high-quality boring, which uses foam surfactants, has made it possible to examine the detailed geological constitution and structure of landslide bodies. However, geological information related to landslides has not been obtained appropriately even from undisturbed high-quality drilled cores. Moreover, it has been difficult to distinguish between rocks crushed by landslide movement and the fault breccia in accretionary complexes. We examined the detailed geology of high-quality drilled cores of landslide bodies on the Shimanto Belt and the Chichibu Belt. The fault breccia near the landslide bodies was found to exhibit planar fabrics while the crushed breccias in the landslide bodies showed a random fabric. We discovered that classifying the degree of crushing and inspecting the planar fabrics of rocks are effective in the geological determination of landslide bodies.

Data for four geologic test holes in the Sacramento Valley, California

USGS Publications Warehouse

Berkstresser, C.F.; French, J.J.; Schaal, M.E.

1985-01-01

The report provides geological and geophysical data for four of seven test holes drilled as a part of the Central Valley Aquifer Project, which is part of the Regional Aquifer Systems Analysis. The holes were drilled with a rotary well drilling machine to depths of 900 feet in the southwestern part of the Sacramento Valley in Solano and Yolo Counties. Geologic data for each well include lithology, texture, color, character of the contact, sorting, rounding, and cementation, determined from cuttings, cores, and sidewall covers. Fifty cores, 3 feet long, were obtained from each hole, and from eight to fourteen sidewall cores were collected. Geophysical data include a dual-induction log, spherically focused log (SFL), compensated neutron-formation density log, gamma-ray log, and a caliper log. These data are presented in four tables and on four plates. (USGS)

Highly correlated configuration interaction calculations on water with large orbital bases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Almora-Díaz, César X., E-mail: xalmora@fisica.unam.mx

2014-05-14

A priori selected configuration interaction (SCI) with truncation energy error [C. F. Bunge, J. Chem. Phys. 125, 014107 (2006)] and CI by parts [C. F. Bunge and R. Carbó-Dorca, J. Chem. Phys. 125, 014108 (2006)] are used to approximate the total nonrelativistic electronic ground state energy of water at fixed experimental geometry with CI up to sextuple excitations. Correlation-consistent polarized core-valence basis sets (cc-pCVnZ) up to sextuple zeta and augmented correlation-consistent polarized core-valence basis sets (aug-cc-pCVnZ) up to quintuple zeta quality are employed. Truncation energy errors range between less than 1 μhartree, and 100 μhartree for the largest orbital set. Coupledmore » cluster CCSD and CCSD(T) calculations are also obtained for comparison. Our best upper bound, −76.4343 hartree, obtained by SCI with up to sextuple excitations with a cc-pCV6Z basis recovers more than 98.8% of the correlation energy of the system, and it is only about 3 kcal/mol above the “experimental” value. Despite that the present energy upper bounds are far below all previous ones, comparatively large dispersion errors in the determination of the extrapolated energies to the complete basis set do not allow to determine a reliable estimation of the full CI energy with an accuracy better than 0.6 mhartree (0.4 kcal/mol)« less

43 CFR 3484.1 - Performance standards for exploration and surface and underground mining.

Code of Federal Regulations, 2013 CFR

2013-10-01

... operator/lessee to retain representative samples of drill cores for 1 year. Confidentiality of such... prevention equipment when drilling on lands valuable or prospectively valuable for oil, gas, or geothermal resources. (3) All exploration drill holes must be capped with at least 5 feet of cement and plugged with a...

43 CFR 3484.1 - Performance standards for exploration and surface and underground mining.

Code of Federal Regulations, 2012 CFR

2012-10-01

... operator/lessee to retain representative samples of drill cores for 1 year. Confidentiality of such... prevention equipment when drilling on lands valuable or prospectively valuable for oil, gas, or geothermal resources. (3) All exploration drill holes must be capped with at least 5 feet of cement and plugged with a...

Core Across the San Andreas Fault at SAFOD - Photographs, Physical Properties Data, and Core-Handling Procedures

NASA Astrophysics Data System (ADS)

Kirschner, D. L.; Carpenter, B.; Keenan, T.; Sandusky, E.; Sone, H.; Ellsworth, B.; Hickman, S.; Weiland, C.; Zoback, M.

2007-12-01

Core samples were obtained that cross three faults of the San Andreas Fault Zone north of Parkfield, California, during the summer of 2007. The cored intervals were obtained by sidetracking off the SAFOD Main Hole that was rotary drilled across the San Andreas in 2005. The first cored interval targeted the pronounced lithologic boundary between the Salinian terrane and the Great Valley and Franciscan formations. Eleven meters of pebbly conglomerate (with minor amounts of fine sands and shale) were obtained from 3141 to 3152 m (measured depth, MD). The two conglomerate units are heavily fractured with many fractures having accommodated displacement. Within this cored interval, there is a ~1m zone with highly sheared, fine-grained material, possibly ultracataclasite in part. The second cored interval crosses a creeping segment of a fault that has been deforming the cemented casing of the adjacent Main Hole. This cored interval sampled the fault 100 m above a seismogenic patch of M2 repeating earthquakes. Thirteen meters of core were obtained across this fault from 3186 to 3199 m (MD). This fault, which is hosted primarily in siltstones and shales, contains a serpentinite body embedded in a highly sheared shale and serpentinite-bearing fault gouge unit. The third cored interval crosses a second creeping fault that has also been deforming the cemented casing of the Main Hole. This fault, which is the most rapidly shearing fault in the San Andreas fault zone based on casing deformation, contains multiple fine- grained clay-rich fault strands embedded in highly sheared shales and lesser deformed sandstones. Initial processing of the cores was carried out at the drill site. Each core came to the surface in 9 meter-long aluminum core barrels. These were cut into more manageable three-foot sections. The quarter-inch-thick aluminum liner of each section was cut and then split apart to reveal the 10 cm diameter cores. Depending on the fragility and porosity of the rock, the drilling fluid was removed either by washing with dilute calcium chloride brine (to approximately match the salinity of the formation fluids) or by gently scraping away drilling mud on the core surface. Once cleaned, each core section was photographed to very high resolution on a Geotek Multi- Sensor Core Logging (MSCL) system. This system was also used to determine the bulk density and magnetic susceptibility of each section. The 25 MB high-resolution photographs and the raw and processed physical properties data were then uploaded to the ICDP web server in Potsdam for public access (http://safod.icdp- online.org). The cores will be archived at the Gulf Coast Repository of the Integrated Ocean Drilling Program in College Station, TX. The MSCL photographs, physical property measurements, and other related data, such as geophysical logs, will be integrated using CoreWall, and will be on display at the meeting. All samples, data, and imagery are available to the science community.

Accurate prediction of bond dissociation energies of large n-alkanes using ONIOM-CCSD(T)/CBS methods

NASA Astrophysics Data System (ADS)

Wu, Junjun; Ning, Hongbo; Ma, Liuhao; Ren, Wei

2018-05-01

Accurate determination of the bond dissociation energies (BDEs) of large alkanes is desirable but practically impossible due to the expensive cost of high-level ab initio methods. We developed a two-layer ONIOM-CCSD(T)/CBS method which treats the high layer with CCSD(T) method and the low layer with DFT method, respectively. The accuracy of this method was validated by comparing the calculated BDEs of n-hexane with that obtained at the CCSD(T)-F12b/aug-cc-pVTZ level of theory. On this basis, the C-C BDEs of C6-C20 n-alkanes were calculated systematically using the ONIOM [CCSD(T)/CBS(D-T):M06-2x/6-311++G(d,p)] method, showing a good agreement with the data available in the literature.

Low cost estimation of the contribution of post-CCSD excitations to the total atomization energy using density functional theory calculations

NASA Astrophysics Data System (ADS)

Sánchez, H. R.; Pis Diez, R.

2016-04-01

Based on the Aλ diagnostic for multireference effects recently proposed [U.R. Fogueri, S. Kozuch, A. Karton, J.M. Martin, Theor. Chem. Acc. 132 (2013) 1], a simple method for improving total atomization energies and reaction energies calculated at the CCSD level of theory is proposed. The method requires a CCSD calculation and two additional density functional theory calculations for the molecule. Two sets containing 139 and 51 molecules are used as training and validation sets, respectively, for total atomization energies. An appreciable decrease in the mean absolute error from 7-10 kcal mol-1 for CCSD to about 2 kcal mol-1 for the present method is observed. The present method provides atomization energies and reaction energies that compare favorably with relatively recent scaled CCSD methods.

Ab initio calculations, structure, NBO and NCI analyses of Xsbnd H⋯π interactions

NASA Astrophysics Data System (ADS)

Wu, Qiyang; Su, He; Wang, Hongyan; Wang, Hui

2018-02-01

The performance of ab initio methods (MP2, DFT/B3LYP, random-phase approximation (RPA), CCSD(T) and QCISD(T)) in predicting interaction energy of Xsbnd H⋯π (Xsbnd H = HCCH, HCl, HF; π = C2H2, C2H4, C6H6) hydrogen complexes are assessed systematically. The CCSD(T)/CBS benchmarks of interaction energy are reported. It is found that RPA agrees well with CCSD(T)/CBS benchmarks and experimental results. CCSD(T) and QCISD(T) perform the best only when compared with CCSD(T)/CBS benchmarks, MP2 performs well only for experimental data. B3LYP provides the worst accuracy. Additionally, the equilibrium structure, interaction type of Xsbnd H⋯π hydrogen complexes are investigated by the natural bond orbital (NBO) and the non-covalent interaction index (NCI).

Accuracy study of computer-assisted drilling: the effect of bone density, drill bit characteristics, and use of a mechanical guide.

PubMed

Hüfner, T; Geerling, J; Oldag, G; Richter, M; Kfuri, M; Pohlemann, T; Krettek, C

2005-01-01

This study was designed to determine the clinical relevant accuracy of CT-based navigation for drilling. Experimental model. Laboratory. Twelve drills of varying lengths and diameters were tested with 2 different set-ups. Group 1 used free-hand navigated drilling technique with foam blocks equipped with titanium target points. Group 2 (control) used a newly developed 3-dimensional measurement device equipped with titanium target points with a fixed entry for the navigated drill to minimize bending forces. One examiner performed 690 navigated drillings using solely the monitor screen for control in both groups. The difference between the planned and the actual starting and target point (up to 150 mm distance) was measured (mm). Levene test and a nonpaired t test. Significance level was set as P < 0.05. The core accuracy of the navigation system measured with the 3-dimensional device was 0.5 mm. The mean distance from planned to actual entry points in group 1 was 1.3 (range, 0.6-3.4 mm). The mean distance between planned and actual target point was 3.4 (range, 1.7-5.8 mm). Free-hand navigated drilling showed an increased difference with increased length of the drill bits as well as with increased drilling channel for drill bits 2.5 and 3.2 mm and not for 3.5 and 4.5 mm (P < 0.05). The core accuracy of the navigation system is high. Compared with the navigated free-hand technique, the results suggest that drill bit deflection interferes directly with the precision. The precision is decreased when using small diameter and longer drill bits.

Deep-Time drilling in the Australian Archean: the Agouron Institute geobiological drilling project. (Invited)

NASA Astrophysics Data System (ADS)

Buick, R.

2010-12-01

The Agouron Institute has sponsored deep-time drilling across the South African Archean-Proterozoic boundary, investigating the rise of oxygen over an onshore-offshore environmental transect. It is now supporting a drilling program in the Australian Archean of the Pilbara Craton, addressing a similar theme but with the added goal of resolving controversy over the age and origin of hydrocarbon biomarker molecules in ancient kerogenous shales. As these have been claimed to provide evidence for the evolution of oxygenic photosynthesis long before the rise of atmospheric oxygen to persistently high levels during the ~2.3 Ga “Great Oxidation Event”, their syngenesis with their host shales is thus of critical importance for the interpretation of Earth’s early oxygenation history. During the first drilling season, 3 holes were drilled using techniques and equipment to minimize organic geochemical contamination (new drill-string components cleaned before drilling potentially biomarker-bearing rocks, pre-contamination of drilling fluid with a synthetic organic compound of similar geochemical characteristics to biomarkers, sterile cutting and storage of samples immediately upon retrieval from the core-barrel). The initial hole was a blank control for organic geochemistry, drilled into rocks too metamorphosed to retain biomarker molecules. These rocks, cherts, carbonates and pelites of the 3.52 Ga Coucal Formation, Coonterunah Group, have been metamorphosed to upper greenschist facies at temperatures near 500°C and so should have had any ancient soluble hydrocarbons destroyed. However, because they contain both carbonate and organic carbon, these rocks can instead provide isotopic information about the earliest evolution of biological metabolism as they possess residues of both the reactant and product sides of the carbon-fixation reaction. The second hole sampled an on-shore section of carbonates and kerogenous shales in the ~2.65 Ga Carawine Dolomite and Lewin Shale of the Hamersley Group near Yilgalong Creek. This location had been previously drilled by a mining company in the 1980’s and the core provided the highest biomarker yields of any Archean rocks thus far sampled. As it has been suggested that these biomarkers are non-indigenous contaminants, one possibility is that they were introduced into the drill-core at some time between drilling and sampling, so this hole tests that hypothesis. If biomarker concentrations and ratios differ significantly between the two adjacent holes with differing exposures to post-drilling contaminants, then clearly contamination has affected one or other of the cores. The third hole sampled an off-shore equivalent, through banded irons and kerogenous shales of the ~2.65 Ga Marra Mamba and Jeerinah Formations of the Hamersley Group near Cowcumba Creek. Another opportunity for contamination may arise during post-depositional but pre-drilling hydrocarbon migration, when biomarkers can potentially be introduced into previously barren rocks by younger oils, so this hole tests that possibility. As it was drilled through the same stratigraphic interval and structural domain as the second hole but in a different environment, biomarker ratios should be similar if contaminated but different if indigenous.

Maia Mapper: high definition XRF imaging in the lab

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryan, Chris G.; Kirkham, R.; Moorhead, G. F.

Here, Maia Mapper is a laboratory μXRF mapping system for efficient elemental imaging of drill core sections serving minerals research and industrial applications. It targets intermediate spatial scales, with imaging of up to ~80 M pixels over a 500×150 mm 2 sample area. It brings together (i) the Maia detector and imaging system, with its large solid-angle, event-mode operation, millisecond pixel transit times in fly-scan mode and real-time spectral deconvolution and imaging, (ii) the high brightness MetalJet D2 liquid metal micro-focus X-ray source from Excillum, and (iii) an efficient XOS polycapillary lens with a flux gain ~15,900 at 21 keVmore » into a ~32 μm focus, and (iv) a sample scanning stage engineered for standard drill-core sections. Count-rates up to ~3 M/s are observed on drill core samples with low dead-time up to ~1.5%. Automated scans are executed in sequence with display of deconvoluted element component images accumulated in real-time in the Maia detector. Application images on drill core and polished rock slabs illustrate Maia Mapper capabilities as part of the analytical workflow of the Advanced Resource Characterisation Facility, which spans spatial dimensions from ore deposit to atomic scales.« less

Maia Mapper: high definition XRF imaging in the lab

DOE PAGES

Ryan, Chris G.; Kirkham, R.; Moorhead, G. F.; ...

2018-03-13

Here, Maia Mapper is a laboratory μXRF mapping system for efficient elemental imaging of drill core sections serving minerals research and industrial applications. It targets intermediate spatial scales, with imaging of up to ~80 M pixels over a 500×150 mm 2 sample area. It brings together (i) the Maia detector and imaging system, with its large solid-angle, event-mode operation, millisecond pixel transit times in fly-scan mode and real-time spectral deconvolution and imaging, (ii) the high brightness MetalJet D2 liquid metal micro-focus X-ray source from Excillum, and (iii) an efficient XOS polycapillary lens with a flux gain ~15,900 at 21 keVmore » into a ~32 μm focus, and (iv) a sample scanning stage engineered for standard drill-core sections. Count-rates up to ~3 M/s are observed on drill core samples with low dead-time up to ~1.5%. Automated scans are executed in sequence with display of deconvoluted element component images accumulated in real-time in the Maia detector. Application images on drill core and polished rock slabs illustrate Maia Mapper capabilities as part of the analytical workflow of the Advanced Resource Characterisation Facility, which spans spatial dimensions from ore deposit to atomic scales.« less

Maia Mapper: high definition XRF imaging in the lab

NASA Astrophysics Data System (ADS)

Ryan, C. G.; Kirkham, R.; Moorhead, G. F.; Parry, D.; Jensen, M.; Faulks, A.; Hogan, S.; Dunn, P. A.; Dodanwela, R.; Fisher, L. A.; Pearce, M.; Siddons, D. P.; Kuczewski, A.; Lundström, U.; Trolliet, A.; Gao, N.

2018-03-01

Maia Mapper is a laboratory μXRF mapping system for efficient elemental imaging of drill core sections serving minerals research and industrial applications. It targets intermediate spatial scales, with imaging of up to ~80 M pixels over a 500×150 mm2 sample area. It brings together (i) the Maia detector and imaging system, with its large solid-angle, event-mode operation, millisecond pixel transit times in fly-scan mode and real-time spectral deconvolution and imaging, (ii) the high brightness MetalJet D2 liquid metal micro-focus X-ray source from Excillum, and (iii) an efficient XOS polycapillary lens with a flux gain ~15,900 at 21 keV into a ~32 μm focus, and (iv) a sample scanning stage engineered for standard drill-core sections. Count-rates up to ~3 M/s are observed on drill core samples with low dead-time up to ~1.5%. Automated scans are executed in sequence with display of deconvoluted element component images accumulated in real-time in the Maia detector. Application images on drill core and polished rock slabs illustrate Maia Mapper capabilities as part of the analytical workflow of the Advanced Resource Characterisation Facility, which spans spatial dimensions from ore deposit to atomic scales.

43 CFR 3141.2-2 - Exploration licenses.

Code of Federal Regulations, 2011 CFR

2011-10-01

... license to conduct core drilling and other exploration activities to collect geologic, environmental and... drilling for oil or gas will be allowed under an exploration license issued under this subpart. No specific...

43 CFR 3141.2-2 - Exploration licenses.

Code of Federal Regulations, 2013 CFR

2013-10-01

... license to conduct core drilling and other exploration activities to collect geologic, environmental and... drilling for oil or gas will be allowed under an exploration license issued under this subpart. No specific...

43 CFR 3141.2-2 - Exploration licenses.

Code of Federal Regulations, 2012 CFR

2012-10-01

... license to conduct core drilling and other exploration activities to collect geologic, environmental and... drilling for oil or gas will be allowed under an exploration license issued under this subpart. No specific...

43 CFR 3141.2-2 - Exploration licenses.

Code of Federal Regulations, 2014 CFR

2014-10-01

... license to conduct core drilling and other exploration activities to collect geologic, environmental and... drilling for oil or gas will be allowed under an exploration license issued under this subpart. No specific...

Publications - SR 59 | Alaska Division of Geological & Geophysical Surveys

Science.gov Websites

Peninsula; Alaska, State of; Antimony; Arsenic; Arsenopyrite; Barite; Base Metals; Big Delta; Bismuth Materials; Copper; Core Drilling; Council; Crushed Gravel; Crushed Rock; Delta Junction; Diamond Drilling

A core handling device for the Mars Sample Return Mission

NASA Technical Reports Server (NTRS)

Gwynne, Owen

1989-01-01

A core handling device for use on Mars is being designed. To provide a context for the design study, it was assumed that a Mars Rover/Sample Return (MRSR) Mission would have the following characteristics: a year or more in length; visits by the rover to 50 or more sites; 100 or more meter-long cores being drilled by the rover; and the capability of returning about 5 kg of Mars regolith to Earth. These characteristics lead to the belief that in order to bring back a variegated set of samples that can address the range of scientific objetives for a MRSR mission to Mars there needs to be considerable analysis done on board the rover. Furthermore, the discrepancy between the amount of sample gathered and the amount to be returned suggests that there needs to be some method of choosing the optimal set of samples. This type of analysis will require pristine material-unaltered by the drilling process. Since the core drill thermally and mechanically alters the outer diameter (about 10 pct) of the core sample, this outer area cannot be used. The primary function of the core handling device is to extract subsamples from the core and to position these subsamples, and the core itself if needed, with respect to the various analytical instruments that can be used to perform these analyses.

Anionic water pentamer and hexamer clusters: An extensive study of structures and energetics

NASA Astrophysics Data System (ADS)

Ünal, Aslı; Bozkaya, Uǧur

2018-03-01

An extensive study of structures and energetics for anionic pentamer and hexamer clusters is performed employing high level ab initio quantum chemical methods, such as the density-fitted orbital-optimized linearized coupled-cluster doubles (DF-OLCCD), coupled-cluster singles and doubles (CCSD), and coupled-cluster singles and doubles with perturbative triples [CCSD(T)] methods. In this study, sixteen anionic pentamer clusters and eighteen anionic hexamer clusters are reported. Relative, binding, and vertical detachment energies (VDE) are presented at the complete basis set limit (CBS), extrapolating energies of aug4-cc-pVTZ and aug4-cc-pVQZ custom basis sets. The largest VDE values obtained at the CCSD(T)/CBS level are 9.9 and 11.2 kcal mol-1 for pentamers and hexamers, respectively, which are in very good agreement with the experimental values of 9.5 and 11.1 kcal mol-1. Our binding energy results, at the CCSD(T)/CBS level, indicate strong bindings in anionic clusters due to hydrogen bond interactions. The average binding energy per water molecules is -5.0 and -5.3 kcal mol-1 for pentamers and hexamers, respectively. Furthermore, our results demonstrate that the DF-OLCCD method approaches to the CCSD(T) quality for anionic clusters. The inexpensive analytic gradients of DF-OLCCD compared to CCSD or CCSD(T) make it very attractive for high-accuracy studies.

Anionic water pentamer and hexamer clusters: An extensive study of structures and energetics.

PubMed

Ünal, Aslı; Bozkaya, Uğur

2018-03-28

An extensive study of structures and energetics for anionic pentamer and hexamer clusters is performed employing high level ab initio quantum chemical methods, such as the density-fitted orbital-optimized linearized coupled-cluster doubles (DF-OLCCD), coupled-cluster singles and doubles (CCSD), and coupled-cluster singles and doubles with perturbative triples [CCSD(T)] methods. In this study, sixteen anionic pentamer clusters and eighteen anionic hexamer clusters are reported. Relative, binding, and vertical detachment energies (VDE) are presented at the complete basis set limit (CBS), extrapolating energies of aug4-cc-pVTZ and aug4-cc-pVQZ custom basis sets. The largest VDE values obtained at the CCSD(T)/CBS level are 9.9 and 11.2 kcal mol -1 for pentamers and hexamers, respectively, which are in very good agreement with the experimental values of 9.5 and 11.1 kcal mol -1 . Our binding energy results, at the CCSD(T)/CBS level, indicate strong bindings in anionic clusters due to hydrogen bond interactions. The average binding energy per water molecules is -5.0 and -5.3 kcal mol -1 for pentamers and hexamers, respectively. Furthermore, our results demonstrate that the DF-OLCCD method approaches to the CCSD(T) quality for anionic clusters. The inexpensive analytic gradients of DF-OLCCD compared to CCSD or CCSD(T) make it very attractive for high-accuracy studies.

Descriptions and preliminary interpretations of cores recovered from the Manson Impact Structure (Iowa)

NASA Technical Reports Server (NTRS)

Anderson, R. R.; Witzke, B. J.; Hartung, J. B.; Shoemaker, E. M.; Roddy, D. J.

1993-01-01

A core drilling program initiated by the Iowa Geological Survey Bureau and U.S. Geological Survey in 1991 and 1992 collected 12 cores totalling over 1200 m from the Manson Impact Structure, a probable K-T boundary structure located in north-central Iowa. Cores were recovered from each of the major structural terranes, with 2 cores (M-3 and M-4) from the Terrace Terrane, 4 cores (M-2, M-2A, M-6, and M-9) from the Crater Moat, and 6 cores (M-1, M-5, M-7, M-8, M-10, and M-11) from the Central Peak. These supplemented 2 central peak cores (1-A and 2-A) drilled in 1953. The cores penetrated five major impact lithologies: (1) sedimentary clast breccia; (2) impact ejecta; (3) central peak crystallite rocks; (4) crystalline clast breccia with sandy matrix; and (5) crystallite clast breccia with a melt matrix. Descriptions and preliminary interpretations of these cores are presented.

Comet sample acquisition for ROSETTA lander mission

NASA Astrophysics Data System (ADS)

Marchesi, M.; Campaci, R.; Magnani, P.; Mugnuolo, R.; Nista, A.; Olivier, A.; Re, E.

2001-09-01

ROSETTA/Lander is being developed with a combined effort of European countries, coordinated by German institutes. The commitment for such a challenging probe will provide a unique opportunity for in-situ analysis of a comet nucleus. The payload for coring, sampling and investigations of comet materials is called SD2 (Sampling Drilling and Distribution). The paper presents the drill/sampler tool and the sample transfer trough modeling, design and testing phases. Expected drilling parameters are then compared with experimental data; limited torque consumption and axial thrust on the tool constraint the operation and determine the success of tests. Qualification campaign involved the structural part and related vibration test, the auger/bit parts and drilling test, and the coring mechanism with related sampling test. Mechanical check of specimen volume is also reported, with emphasis on the measurement procedure and on the mechanical unit. The drill tool and all parts of the transfer chain were tested in the hypothetical comet environment, charcterized by frozen material at extreme low temperature and high vacuum (-160°C, 10-3 Pa).

Laguna Potrok Aike, Argentina: the first non-tropical environmental record in South America extending far beyond the Late-Glacial - a progress report

NASA Astrophysics Data System (ADS)

Zolitschka, B.; Anselmetti, F.; Ariztegui, D.; Corbella, H.; Francus, P.; Gebhardt, C.; Lücke, A.; Ohlendorf, C.; Schäbitz, F.; Pasado Science Team

2009-04-01

Within the framework of the ICDP-funded "Potrok Aike maar lake sediment archive drilling project" (PASADO) an international team of scientists carried out interdisciplinary research at the unique mid-Pleistocene (770 ka) maar lake of Laguna Potrok Aike in southern Patagonia (Province of Santa Cruz, Argentina). This lake is very sensitive to variations in southern hemispheric wind and pressure systems and thus holds a unique and continuous lacustrine record of climatic and ecological variability of global significance. Moreover, Southern Patagonia with its many active volcanoes is an ideal location to better understand the regional history of volcanism. These are two challenging geo-scientific themes that need to be tackled, especially as both of them have an increasing socio-economic relevance. Three months of drilling activities that finished last November 2008 were carried out by DOSECC from the drilling platform R/V "Kerry Kelts". More than 500 m of lacustrine sediments were recovered. This sedimentary archive will provide (1) new insights into the processes of regional back arc volcanism within the Pali Aike Volcanic Field itself as well as the more distant explosive volcanism of the Andean mountain chains; and, (2) high-resolution (decadal) quantitative climate and environmental reconstructions supported by multiple dating and stratigraphic correlations. Marine - ice core - terrestrial linkages will be emphasized as well as the incorporation of results from global climate modelling simulations for the last ca. 100 ka. The two drilled sites in the central deep basin of Laguna Potrok Aike have been selected based on four seismic surveys carried out between 2003 and 2005. Sediments were recovered at both drilled sites down to a subbottom depth of slightly more than 100 m using the GLAD800 drill rig with the hydraulic piston corer tool (HPC) at water depths varying between 95 and 100 m. The total core recovery is 94%. On-site core logging with the multi sensor core logger (MSCL) documents an excellent correlation between the four recovered holes drilled at Site 1 as well as with the three holes obtained from Site 2 which is located ca. 700 m south of Site 1. Additionally, a variety of sedimentological, physical and geochemical analyses were carried out on the core catcher samples in the field laboratory. Preliminary interpretation of all data that is available before core opening indicates that the record may go back in time as far as to the ending of oxygen isotope stage 5. Acknowledgements This research is supported by the International Continental Scientific Drilling Program (ICDP) in the framework of the "Potrok Aike Maar Lake Sediment Archive Drilling Project" (PASADO). Funding was provided by the ICDP, the German Science Foundation (DFG), the Swiss National Science Foundation (SNF), the Natural Sciences and Engineering Research Council of Canada (NSERC), the Swedish Vetenskapsradet (VR) and the University of Bremen.

A new near-linear scaling, efficient and accurate, open-shell domain-based local pair natural orbital coupled cluster singles and doubles theory.

PubMed

Saitow, Masaaki; Becker, Ute; Riplinger, Christoph; Valeev, Edward F; Neese, Frank

2017-04-28

The Coupled-Cluster expansion, truncated after single and double excitations (CCSD), provides accurate and reliable molecular electronic wave functions and energies for many molecular systems around their equilibrium geometries. However, the high computational cost, which is well-known to scale as O(N 6 ) with system size N, has limited its practical application to small systems consisting of not more than approximately 20-30 atoms. To overcome these limitations, low-order scaling approximations to CCSD have been intensively investigated over the past few years. In our previous work, we have shown that by combining the pair natural orbital (PNO) approach and the concept of orbital domains it is possible to achieve fully linear scaling CC implementations (DLPNO-CCSD and DLPNO-CCSD(T)) that recover around 99.9% of the total correlation energy [C. Riplinger et al., J. Chem. Phys. 144, 024109 (2016)]. The production level implementations of the DLPNO-CCSD and DLPNO-CCSD(T) methods were shown to be applicable to realistic systems composed of a few hundred atoms in a routine, black-box fashion on relatively modest hardware. In 2011, a reduced-scaling CCSD approach for high-spin open-shell unrestricted Hartree-Fock reference wave functions was proposed (UHF-LPNO-CCSD) [A. Hansen et al., J. Chem. Phys. 135, 214102 (2011)]. After a few years of experience with this method, a few shortcomings of UHF-LPNO-CCSD were noticed that required a redesign of the method, which is the subject of this paper. To this end, we employ the high-spin open-shell variant of the N-electron valence perturbation theory formalism to define the initial guess wave function, and consequently also the open-shell PNOs. The new PNO ansatz properly converges to the closed-shell limit since all truncations and approximations have been made in strict analogy to the closed-shell case. Furthermore, given the fact that the formalism uses a single set of orbitals, only a single PNO integral transformation is necessary, which offers large computational savings. We show that, with the default PNO truncation parameters, approximately 99.9% of the total CCSD correlation energy is recovered for open-shell species, which is comparable to the performance of the method for closed-shells. UHF-DLPNO-CCSD shows a linear scaling behavior for closed-shell systems, while linear to quadratic scaling is obtained for open-shell systems. The largest systems we have considered contain more than 500 atoms and feature more than 10 000 basis functions with a triple-ζ quality basis set.

A new near-linear scaling, efficient and accurate, open-shell domain-based local pair natural orbital coupled cluster singles and doubles theory

NASA Astrophysics Data System (ADS)

Saitow, Masaaki; Becker, Ute; Riplinger, Christoph; Valeev, Edward F.; Neese, Frank

2017-04-01

The Coupled-Cluster expansion, truncated after single and double excitations (CCSD), provides accurate and reliable molecular electronic wave functions and energies for many molecular systems around their equilibrium geometries. However, the high computational cost, which is well-known to scale as O(N6) with system size N, has limited its practical application to small systems consisting of not more than approximately 20-30 atoms. To overcome these limitations, low-order scaling approximations to CCSD have been intensively investigated over the past few years. In our previous work, we have shown that by combining the pair natural orbital (PNO) approach and the concept of orbital domains it is possible to achieve fully linear scaling CC implementations (DLPNO-CCSD and DLPNO-CCSD(T)) that recover around 99.9% of the total correlation energy [C. Riplinger et al., J. Chem. Phys. 144, 024109 (2016)]. The production level implementations of the DLPNO-CCSD and DLPNO-CCSD(T) methods were shown to be applicable to realistic systems composed of a few hundred atoms in a routine, black-box fashion on relatively modest hardware. In 2011, a reduced-scaling CCSD approach for high-spin open-shell unrestricted Hartree-Fock reference wave functions was proposed (UHF-LPNO-CCSD) [A. Hansen et al., J. Chem. Phys. 135, 214102 (2011)]. After a few years of experience with this method, a few shortcomings of UHF-LPNO-CCSD were noticed that required a redesign of the method, which is the subject of this paper. To this end, we employ the high-spin open-shell variant of the N-electron valence perturbation theory formalism to define the initial guess wave function, and consequently also the open-shell PNOs. The new PNO ansatz properly converges to the closed-shell limit since all truncations and approximations have been made in strict analogy to the closed-shell case. Furthermore, given the fact that the formalism uses a single set of orbitals, only a single PNO integral transformation is necessary, which offers large computational savings. We show that, with the default PNO truncation parameters, approximately 99.9% of the total CCSD correlation energy is recovered for open-shell species, which is comparable to the performance of the method for closed-shells. UHF-DLPNO-CCSD shows a linear scaling behavior for closed-shell systems, while linear to quadratic scaling is obtained for open-shell systems. The largest systems we have considered contain more than 500 atoms and feature more than 10 000 basis functions with a triple-ζ quality basis set.

A view on coupled cluster perturbation theory using a bivariational Lagrangian formulation.

PubMed

Kristensen, Kasper; Eriksen, Janus J; Matthews, Devin A; Olsen, Jeppe; Jørgensen, Poul

2016-02-14

We consider two distinct coupled cluster (CC) perturbation series that both expand the difference between the energies of the CCSD (CC with single and double excitations) and CCSDT (CC with single, double, and triple excitations) models in orders of the Møller-Plesset fluctuation potential. We initially introduce the E-CCSD(T-n) series, in which the CCSD amplitude equations are satisfied at the expansion point, and compare it to the recently developed CCSD(T-n) series [J. J. Eriksen et al., J. Chem. Phys. 140, 064108 (2014)], in which not only the CCSD amplitude, but also the CCSD multiplier equations are satisfied at the expansion point. The computational scaling is similar for the two series, and both are term-wise size extensive with a formal convergence towards the CCSDT target energy. However, the two series are different, and the CCSD(T-n) series is found to exhibit a more rapid convergence up through the series, which we trace back to the fact that more information at the expansion point is utilized than for the E-CCSD(T-n) series. The present analysis can be generalized to any perturbation expansion representing the difference between a parent CC model and a higher-level target CC model. In general, we demonstrate that, whenever the parent parameters depend upon the perturbation operator, a perturbation expansion of the CC energy (where only parent amplitudes are used) differs from a perturbation expansion of the CC Lagrangian (where both parent amplitudes and parent multipliers are used). For the latter case, the bivariational Lagrangian formulation becomes more than a convenient mathematical tool, since it facilitates a different and faster convergent perturbation series than the simpler energy-based expansion.

Recovery Efficiency Test Project: Phase 1, Activity report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Overbey, W.K. Jr.; Wilkins, D.W.; Keltch, B.

1988-04-01

This report is the second volume of the Recovery Efficiency Test Phase I Report of Activities. Volume 1 covered selection, well planning, drilling, coring, logging and completion operations. This volume reports on well testing activities, reclamation activities on the drilling site and access roads, and the results of physical and mechanical properties tests on the oriented core material obtained from a horizontal section of the well. 3 refs., 21 figs., 10 tabs.

Spent Fuel Test-Climax: core logging for site investigation and instrumentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilder, D.G.; Yow, J.L. Jr.; Thorpe, R.K.

1982-05-28

As an integral part of the Spent Fuel Test-Climax 5150 ft (1570 m) of granite core was obtained. This core was diamond drilled in various sizes, mainly 38-mm and 76-mm diameters. The core was teken with single tube core barrels and was unoriented. Techniques used to drill and log this core are discussed, as well as techniques to orient the core. Of the 5150 ft (1570 m) of core more than 3645 ft (1111 m) was retained and logged in some detail. As a result of the core logging, geologic discontinuities were identified, joint frequency and spacing characterized. Discontinuities identifiedmore » included several joint sets, shear zones and faults. Correlations based on coring along were generally found to be impossible, even for the more prominent features. The only feature properly correlated from the exploratory drilling was the fault system at the end of the facility, but it was not identified from the exploratory core as a fault. Identification of discontinuities was later helped by underground mapping that identified several different joint sets with different characteristics. It was found that joint frequency varied from 0.3 to 1.1 joint per foot of core for open fractures and from 0.3 to 3.3/ft for closed or healed fractures. Histograms of fracture spacing indicate that there is likely a random distribution of spacing superimposed upon uniformly spaced fractures. It was found that a low angle joint set had a persistent mean orientation. These joints were healed and had pervasive wall rock alteration which made identification of joints in this set possible. The recognition of a joint set with known attitude allowed orientation of much of the core. This orientation technique was found to be effective. 10 references, 25 figures, 4 tables.« less

Reconstruction of in-situ porosity and porewater compositions of low-permeability crystalline rocks: Magnitude of artefacts induced by drilling and sample recovery

NASA Astrophysics Data System (ADS)

Meier, D. B.; Waber, H. N.; Gimmi, T.; Eichinger, F.; Diamond, L. W.

2015-12-01

Geological site characterisation programmes typically rely on drill cores for direct information on subsurface rocks. However, porosity, transport properties and porewater composition measured on drill cores can deviate from in-situ values due to two main artefacts caused by drilling and sample recovery: (1) mechanical disruption that increases porosity and (2) contamination of the porewater by drilling fluid. We investigated the effect and magnitude of these perturbations on large drill core samples (12-20 cm long, 5 cm diameter) of high-grade, granitic gneisses obtained from 350 to 600 m depth in a borehole on Olkiluoto Island (SW Finland). The drilling fluid was traced with sodium-iodide. By combining out-diffusion experiments, gravimetry, UV-microscopy and iodide mass balance calculations, we successfully quantified the magnitudes of the artefacts: 2-6% increase in porosity relative to the bulk connected porosity and 0.9 to 8.9 vol.% contamination by drilling fluid. The spatial distribution of the drilling-induced perturbations was revealed by numerical simulations of 2D diffusion matched to the experimental data. This showed that the rims of the samples have a mechanically disrupted zone 0.04 to 0.22 cm wide, characterised by faster transport properties compared to the undisturbed centre (1.8 to 7.7 times higher pore diffusion coefficient). Chemical contamination was shown to affect an even wider zone in all samples, ranging from 0.15 to 0.60 cm, in which iodide enrichment was up to 180 mg/kgwater, compared to 0.5 mg/kgwater in the uncontaminated centre. For all samples in the present case study, it turned out that the magnitude of the artefacts caused by drilling and sample recovery is so small that no correction is required for their effects. Therefore, the standard laboratory measurements of porosity, transport properties and porewater composition can be taken as valid in-situ estimates. However, it is clear that the magnitudes strongly depend on site- and drilling-specific factors and therefore our results cannot be transferred simply to other locations. We recommend the approach presented in this study as a route to obtain reliable values in future drilling campaigns aimed at characterising in-situ bedrock properties.

Reconstruction of in-situ porosity and porewater compositions of low-permeability crystalline rocks: Magnitude of artefacts induced by drilling and sample recovery.

PubMed

Meier, D B; Waber, H N; Gimmi, T; Eichinger, F; Diamond, L W

2015-12-01

Geological site characterisation programmes typically rely on drill cores for direct information on subsurface rocks. However, porosity, transport properties and porewater composition measured on drill cores can deviate from in-situ values due to two main artefacts caused by drilling and sample recovery: (1) mechanical disruption that increases porosity and (2) contamination of the porewater by drilling fluid. We investigated the effect and magnitude of these perturbations on large drill core samples (12-20 cm long, 5 cm diameter) of high-grade, granitic gneisses obtained from 350 to 600 m depth in a borehole on Olkiluoto Island (SW Finland). The drilling fluid was traced with sodium-iodide. By combining out-diffusion experiments, gravimetry, UV-microscopy and iodide mass balance calculations, we successfully quantified the magnitudes of the artefacts: 2-6% increase in porosity relative to the bulk connected porosity and 0.9 to 8.9 vol.% contamination by drilling fluid. The spatial distribution of the drilling-induced perturbations was revealed by numerical simulations of 2D diffusion matched to the experimental data. This showed that the rims of the samples have a mechanically disrupted zone 0.04 to 0.22 cm wide, characterised by faster transport properties compared to the undisturbed centre (1.8 to 7.7 times higher pore diffusion coefficient). Chemical contamination was shown to affect an even wider zone in all samples, ranging from 0.15 to 0.60 cm, in which iodide enrichment was up to 180 mg/kg water, compared to 0.5 mg/kg water in the uncontaminated centre. For all samples in the present case study, it turned out that the magnitude of the artefacts caused by drilling and sample recovery is so small that no correction is required for their effects. Therefore, the standard laboratory measurements of porosity, transport properties and porewater composition can be taken as valid in-situ estimates. However, it is clear that the magnitudes strongly depend on site- and drilling-specific factors and therefore our results cannot be transferred simply to other locations. We recommend the approach presented in this study as a route to obtain reliable values in future drilling campaigns aimed at characterising in-situ bedrock properties. Copyright © 2015 Elsevier B.V. All rights reserved.

Ocean Drilling Program: Science Operator Site Index

Science.gov Websites

time estimator Long-Term Observatories and Legacy Holes (University of Miami site) Drilling Services systems Internet systems Help Desk Database services How to obtain ODP data Data types and examples Core

Supplemental materials for the ICDP-USGS Eyreville A, B, and C core holes, Chesapeake Bay impact structure: Core-box photographs, coring-run tables, and depth-conversion files

USGS Publications Warehouse

Durand, C.T.; Edwards, L.E.; Malinconico, M.L.; Powars, D.S.

2009-01-01

During 2005-2006, the International Continental Scientific Drilling Program and the U.S. Geological Survey drilled three continuous core holes into the Chesapeake Bay impact structure to a total depth of 1766.3 m. A collection of supplemental materials that presents a record of the core recovery and measurement data for the Eyreville cores is available on CD-ROM at the end of this volume and in the GSA Data Repository. The supplemental materials on the CD-ROM include digital photographs of each core box from the three core holes, tables of the three coring-run logs, as recorded on site, and a set of depth-conversion programs. In this chapter, the contents, purposes, and basic applications of the supplemental materials are briefly described. With this information, users can quickly decide if the materials will apply to their specific research needs. ?? 2009 The Geological Society of America.

Geminal-spanning orbitals make explicitly correlated reduced-scaling coupled-cluster methods robust, yet simple

NASA Astrophysics Data System (ADS)

Pavošević, Fabijan; Neese, Frank; Valeev, Edward F.

2014-08-01

We present a production implementation of reduced-scaling explicitly correlated (F12) coupled-cluster singles and doubles (CCSD) method based on pair-natural orbitals (PNOs). A key feature is the reformulation of the explicitly correlated terms using geminal-spanning orbitals that greatly reduce the truncation errors of the F12 contribution. For the standard S66 benchmark of weak intermolecular interactions, the cc-pVDZ-F12 PNO CCSD F12 interaction energies reproduce the complete basis set CCSD limit with mean absolute error <0.1 kcal/mol, and at a greatly reduced cost compared to the conventional CCSD F12.

Vergleich von hydraulischen und chemischen Sedimenteigenschaften aus Spül- und Kernbohrungen im Raum Peine (Norddeutschland)

NASA Astrophysics Data System (ADS)

Konrad, C.; Walther, W.; Reimann, T.; Rogge, A.; Stengel, P.; Well, R.

2008-03-01

Comparison of hydraulic and chemical properties of sediments from flush- and core drillings in the area of Peine (Germany). Because of financial constraints, investigations of nitrate metabolism are often based on disturbed borehole samples. It is arguable, however, whether disturbed samples are suitable for these types of investigations. Disadvantages of disturbed samples in comparison to undisturbed core samples are well known and include possible contamination of the sample by mud additives, destruction of the sediment formation and the insecurity concerning the correct depth allocation. In this study, boreholes were drilled at three locations to a maximum depth of 50 m. The extracted samples, as intact sediment cores and drill cuttings, were studied with regard to chemical and hydraulic parameters of the aquifer sediments. The results show: 1. hydraulic parameters are not affected by clay-based mud; 2. disturbed samples contain less fine grain material relative to the core samples, and the hydraulic conductivity can only be estimated from catch samples; 3. catch samples contain fewer reducing agents (sulphides, organic carbon) than core samples in hydraulically passive zones (defined as K < 10 6 m · s 1); 4. the results of analyses of disturbed and undisturbed core samples are in good agreement for hydraulically active zones (K ≥ 10 6 m · s 1).

Basic data from five core holes in the Raft River geothermal area, Cassia County, Idaho

USGS Publications Warehouse

Crosthwaite, E. G.

1976-01-01

meters) were completed in the area (Crosthwaite, 1974), and the Aerojet Nuclear Company, under the auspices of the U.S. Energy Research and Development Administration, was planning some deep drilling 4,000 to 6,000 feet (1,200 to 1,800 meters) (fig. 1). The purpose of the core drilling was to provide information to test geophysical interpretations of the subsurface structure and lithology and to provide hydrologic and geologic data on the shallow part of the geothermal system. Samples of the core were made available to several divisions and branches of the Geological Survey and to people and agencies outside the Survey. This report presents the basic data from the core holes that had been collected to September 1, 1975, and includes lithologic and geophysical well logs, chemical analyses of water (table 1), and laboratory analyses of cores (table 2) that were completed as of the above date. The data were collected by the Idaho District office, Hydrologic Laboratory, Borehole Geophysics Research Project, and Drilling, Sampling, and Testing Section, all of the Water Resources Division, and the Branch of Central Environmental Geology of the Geologic Divison.

43 CFR 3593.1 - Core or test hole cores, samples, cuttings.

Code of Federal Regulations, 2014 CFR

2014-10-01

.... (d) When drilling on lands with potential for encountering high pressure oil, gas or geothermal... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Core or test hole cores, samples, cuttings...) EXPLORATION AND MINING OPERATIONS Bore Holes and Samples § 3593.1 Core or test hole cores, samples, cuttings...

43 CFR 3593.1 - Core or test hole cores, samples, cuttings.

Code of Federal Regulations, 2012 CFR

2012-10-01

.... (d) When drilling on lands with potential for encountering high pressure oil, gas or geothermal... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Core or test hole cores, samples, cuttings...) EXPLORATION AND MINING OPERATIONS Bore Holes and Samples § 3593.1 Core or test hole cores, samples, cuttings...

43 CFR 3593.1 - Core or test hole cores, samples, cuttings.

Code of Federal Regulations, 2013 CFR

2013-10-01

.... (d) When drilling on lands with potential for encountering high pressure oil, gas or geothermal... 43 Public Lands: Interior 2 2013-10-01 2013-10-01 false Core or test hole cores, samples, cuttings...) EXPLORATION AND MINING OPERATIONS Bore Holes and Samples § 3593.1 Core or test hole cores, samples, cuttings...

43 CFR 3593.1 - Core or test hole cores, samples, cuttings.

Code of Federal Regulations, 2011 CFR

2011-10-01

.... (d) When drilling on lands with potential for encountering high pressure oil, gas or geothermal... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Core or test hole cores, samples, cuttings...) EXPLORATION AND MINING OPERATIONS Bore Holes and Samples § 3593.1 Core or test hole cores, samples, cuttings...

28. MODIFIED CHAIN SAW FOR CUTTING ROCK CORES; BRUNTON COMPASS ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

28. MODIFIED CHAIN SAW FOR CUTTING ROCK CORES; BRUNTON COMPASS STAND FOR DETERMINING CORE'S FIELD ORIENTATION; INSECTICIDE DISPENSER MODIFIED TO LUBRICATE CORE DRILLING PROCESS. - U.S. Geological Survey, Rock Magnetics Laboratory, 345 Middlefield Road, Menlo Park, San Mateo County, CA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eriksen, Janus J., E-mail: janusje@chem.au.dk; Jørgensen, Poul; Matthews, Devin A.

The accuracy at which total energies of open-shell atoms and organic radicals may be calculated is assessed for selected coupled cluster perturbative triples expansions, all of which augment the coupled cluster singles and doubles (CCSD) energy by a non-iterative correction for the effect of triple excitations. Namely, the second- through sixth-order models of the recently proposed CCSD(T–n) triples series [J. J. Eriksen et al., J. Chem. Phys. 140, 064108 (2014)] are compared to the acclaimed CCSD(T) model for both unrestricted as well as restricted open-shell Hartree-Fock (UHF/ROHF) reference determinants. By comparing UHF- and ROHF-based statistical results for a test setmore » of 18 modest-sized open-shell species with comparable RHF-based results, no behavioral differences are observed for the higher-order models of the CCSD(T–n) series in their correlated descriptions of closed- and open-shell species. In particular, we find that the convergence rate throughout the series towards the coupled cluster singles, doubles, and triples (CCSDT) solution is identical for the two cases. For the CCSD(T) model, on the other hand, not only its numerical consistency, but also its established, yet fortuitous cancellation of errors breaks down in the transition from closed- to open-shell systems. The higher-order CCSD(T–n) models (orders n > 3) thus offer a consistent and significant improvement in accuracy relative to CCSDT over the CCSD(T) model, equally for RHF, UHF, and ROHF reference determinants, albeit at an increased computational cost.« less

Core logs from five holes near Kramer, in the Mojave Desert, California

USGS Publications Warehouse

Benda, William K.; Erd, Richard C.; Smith, Ward C.

1958-01-01

In 1957, five test holes were drilled near Kramer, California, in =he western Mojave Desert. The drill sites are in topographic basins where gravimetric and geologic surveys indicated the presence, beneath alluvium, of a thick section of Quaternary and Tertiary sedimentary and volcanic rocks. Two holes which were deeper tests at sites drilled in 1954 cored only silts, sands and gravels: Four Corners test hole No. 1 was drilled in sec. 20, T. I0 N., R. 6 W., to a depth of 3,500 feet. Four Corners No. 2, in sec. 5, T. I0 N., R. 8 W., was drilled to 2,328 feet. Three holes which were drilled at new sites north of the intersection of U. S. Highways 395 and 466, locally known as Four Corners, encountered colemanite-bearing sediments. The locations and total depths of these holes are as follows: Four Corners No. 3, sec. T. 11 N., R. 6 W., depth 2,568 feet; Four Corners No. 4, near northern edge of sec. 30, T. ll N., R. 6 W., depth 3,500 feet; Four Corners No. 5, near southern edge of sec. 30, depth 1,604 feet. The sections of rocks encountered in these three holes are similar. In each, the colemanite is in fine-grained sediments that lie below sands and gravels, which are about 600 to 800 feet thick, and are underlain by sandstones and conglomerates. Colemanite is most abundant in the cores from Four Corners to hole No. 5, particularly in the 76 feet of core recovered between depths of 1,051 and 1,131 feet. Chemical analysis shows that in this section of core the average content of B203 is above 14 percent. In addition to colemanite, the cores contain sulfides of arsenic, an unusual iron sulfide, and zeolites. This mineralogy of the colemanite-bearing sediments north of Four Corners, together with the general lake bed lithology and the occurrence as a tilted section of beds below sands and gravels, supports correlation with the upper or marginal parts of the borate-bearin8 sediments at the Kramer borate mining district, which have similar features. There is, however, no evidence that any beds are exactly equivalent in age.

Phase 1 drilling operations at the Magma Energy Exploratory Well (LVF 51-20)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Finger, J.T.; Jacobson, R.D.

1990-12-01

This report describes the Phase 1 drilling operations for the Magma Energy Exploratory Well near Mammoth Lakes, California. An important part of the Department of Energy's Magma Energy Program, this well is designed to reach an ultimate depth of 20,000 feet or a bottomhole temperature of 500{degree}C, whichever comes first. There will be four drilling phases, at least a year apart, with scientific investigations in the borehole between the drilling intervals. Phase 1 of this project resulted in a 20 inch cased hole to 2558 feet, with 185 feet of coring beyond that. This document comprises a narrative of themore » daily activities, copies of the daily mud and lithologic reports, time breakdowns of rig activities, inventories of lost circulation materials, temperature logs of the cored hole, and a strip chart mud log. 2 figs.« less

Hawaiian lava flows in the third dimension: Identification and interpretation of pahoehoe and 'a'a distribution in the KP-1 and SOH-4 cores

NASA Astrophysics Data System (ADS)

Katz, Melissa G.; Cashman, Katharine V.

2003-02-01

Hawaiian lava flows are classified as pahoehoe or 'a'a by their surface morphology. As surface morphology reflects flow emplacement conditions, the surface distribution of morphologic flow types has been used to study the evolution and eruptive history of basaltic volcanoes. We extend this analysis to the third dimension by determining the distribution of flow types in two deep drill cores, the Scientific Observation Hole-4 (SOH-4) core, drilled near Kilauea's East Rift Zone (ERZ), and the pilot hole (Kahi Puka-1 (KP-1)) for the Hawaiian Scientific Drilling Project (HSDP), drilled through distal flows from Mauna Loa and Mauna Kea. Flows are classified using both internal structures and groundmass textures, with the latter useful when identification based on mesoscopic flow features (e.g., surface morphology and vesicle content and distribution) is ambiguous. We then examine the temporal distribution of pahoehoe and 'a'a flows in proximal (SOH-4) and distal (KP-1) settings. Sequence analysis shows that the two flow types are not randomly distributed in either core but instead are strongly clustered. The proximal SOH-4 core is dominated by thin pahoehoe flows (˜60% by volume), consistent with the common occurrence of surface-fed pahoehoe flows in near-vent settings. The distal KP-1 core has a high proportion of 'a'a (˜58% by volume), although the proportion of pahoehoe and 'a'a varies dramatically throughout the Mauna Kea sequence. Thick inflated pahoehoe flows dominate when the drill site was near sea level, consistent with the numerous inflated pahoehoe fields on the current coastal plains of Kilauea and Mauna Loa. 'A'a flows are abundant when the site was far above sea level. As slope increases from the coastal plains to Mauna Kea's flank, this correlation may reflect the combined effect of long transport distances and increased slopes on flow emplacement. These results demonstrate that flow type and thickness variations in cores provide valuable information about both vent location and local site environment. Observed variations in flow type within the KP-1 core raise interesting questions about feedback between volcano evolution and flow morphology and suggest that flow type is an important variable in models of volcano growth and related models for lava flow hazard assessment.

The Inception of the Colorado Plateau Coring Project: Filling the Triassic Geochronologic Gap and Providing a Continuous Record of Continental Environmental Change in Western Equatorial Pangea

NASA Astrophysics Data System (ADS)

Geissman, J. W.; Olsen, P. E.; Kent, D. V.; Irmis, R. B.; Gehrels, G. E.; Mundil, R.; Parker, W.; Bachmann, G. H.; Kurschner, W. M.; Sha, J.

2014-12-01

The Triassic Period was punctuated by two of the largest Phanerozoic mass-extinctions and witnessed the evolution of elements of the modern biota and the advent of the age of dinosaurs. A rich archive of biotic and environmental changes on land for the early Mesozoic is on the Colorado Plateau, which despite over 100 years of study still remains poorly calibrated in time and poorly registered to other global records. Over 15 years ago, a diverse team of scientists began to develop the concept of a multi-phase, long term Colorado Plateau Coring Project (CPCP). Planning involved two major meetings (DOSECC/NSFICDP supported in Fall, 2007, St. George, UT; and International Continental Drilling Program (ICDP) supported in Spring, 2009, Albuquerque, NM). The National Park Service embraced the concept of Phase One drilling at Petrified Forest National Park (PFNP) in northern Arizona, which exposes one of the most famous and best studied successions of the continental Triassic on Earth, and the Phase One target was decided. Most drilling operation costs were secured from ICDP in Summer, 2010. In late 2013, following more recent NSF support, the research team, utilizing Ruen Drilling Inc., drilled a continuous ~530 m core (60o plunge) through the entire section of Triassic strata (Chinle and Moenkopi fms.) in the north end and a ~240 m core (75o plunge) in lower Chinle and all Moenkopi strata at the south end of the PFNP. Our continuous sampling will place this record in a reliable quantitative and exportable time scale, as a reference section in which magnetostratigraphic, geochronologic, environmental, and paleontologic data are registered to a common thickness scale with unambiguous superposition using pristine samples. The cores are being scanned at the High Resolution X-ray Computed Tomography Facility at UT Austin. They will be transported to the LacCore National Lacustrine Core Facility at U Minnesota, where they will be split, imaged, and scanned for several properties, including XRF data. The core will then be transported to the Rutgers University for sampling. The planning team is contemplating Phase Two options (e.g., the Middle to Lower Triassic marine-influenced section west of the Colorado Plateau (St. George, Utah) area or the Upper Triassic to Lower Jurassic sequence in the Comb Ridge area (Bluff, Utah)).

Geologic implications of gas hydrates in the offshore of India: results of the National Gas Hydrate Program Expedition 01

USGS Publications Warehouse

Collett, Timothy S.; Boswell, Ray; Cochran, J.R.; Kumar, Pushpendra; Lall, Malcolm; Mazumdar, Aninda; Ramana, Mangipudi Venkata; Ramprasad, Tammisetti; Riedel, Michael; Sain, Kalachand; Sathe, Arun Vasant; Vishwanath, Krishna

2014-01-01

One of the specific objectives of this expedition was to test gas hydrate formation models and constrain model parameters, especially those that account for the formation of concentrated gas hydrate accumulations. The necessary data for characterizing the occurrence of in situ gas hydrate, such as interstitial water chlorinities, core-derived gas chemistry, physical and sedimentological properties, thermal images of the recovered cores, and downhole measured logging data (LWD and/or conventional wireline log data), were obtained from most of the drill sites established during NGHP-01. Almost all of the drill sites yielded evidence for the occurrence of gas hydrate; however, the inferred in situ concentration of gas hydrate varied substantially from site to site. For the most part, the interpretation of downhole logging data, core thermal images, interstitial water analyses, and pressure core images from the sites drilled during NGHP-01 indicate that the occurrence of concentrated gas hydrate is mostly associated with the presence of fractures in the sediments, and in some limited cases, by coarser grained (mostly sand-rich) sediments.

Analytical results from samples collected during coal-bed methane exploration drilling in Caldwell Parish, Louisiana

USGS Publications Warehouse

Warwick, Peter D.; Breland, F. Clayton; Hackley, Paul C.; Dulong, Frank T.; Nichols, Douglas J.; Karlsen, Alexander W.; Bustin, R. Marc; Barker, Charles E.; Willett, Jason C.; Trippi, Michael H.

2006-01-01

In 2001, and 2002, the U.S. Geological Survey (USGS) and the Louisiana Geological Survey (LGS), through a Cooperative Research and Development Agreement (CRADA) with Devon SFS Operating, Inc. (Devon), participated in an exploratory drilling and coring program for coal-bed methane in north-central Louisiana. The USGS and LGS collected 25 coal core and cuttings samples from two coal-bed methane test wells that were drilled in west-central Caldwell Parish, Louisiana. The purpose of this report is to provide the results of the analytical program conducted on the USGS/LGS samples. The data generated from this project are summarized in various topical sections that include: 1. molecular and isotopic data from coal gas samples; 2. results of low-temperature ashing and X-ray analysis; 3. palynological data; 4. down-hole temperature data; 5. detailed core descriptions and selected core photographs; 6. coal physical and chemical analytical data; 7. coal gas desorption results; 8. methane and carbon dioxide coal sorption data; 9. coal petrographic results; and 10. geophysical logs.

Fugitive methane leak detection using mid-infrared hollow-core photonic crystal fiber containing ultrafast laser drilled side-holes

NASA Astrophysics Data System (ADS)

Karp, Jason; Challener, William; Kasten, Matthias; Choudhury, Niloy; Palit, Sabarni; Pickrell, Gary; Homa, Daniel; Floyd, Adam; Cheng, Yujie; Yu, Fei; Knight, Jonathan

2016-05-01

The increase in domestic natural gas production has brought attention to the environmental impacts of persistent gas leakages. The desire to identify fugitive gas emission, specifically for methane, presents new sensing challenges within the production and distribution supply chain. A spectroscopic gas sensing solution would ideally combine a long optical path length for high sensitivity and distributed detection over large areas. Specialty micro-structured fiber with a hollow core can exhibit a relatively low attenuation at mid-infrared wavelengths where methane has strong absorption lines. Methane diffusion into the hollow core is enabled by machining side-holes along the fiber length through ultrafast laser drilling methods. The complete system provides hundreds of meters of optical path for routing along well pads and pipelines while being interrogated by a single laser and detector. This work will present transmission and methane detection capabilities of mid-infrared photonic crystal fibers. Side-hole drilling techniques for methane diffusion will be highlighted as a means to convert hollow-core fibers into applicable gas sensors.

Pods: a Powder Delivery System for Mars In-situ Organic, Mineralogic and Isotopic Analysis Instruments

NASA Technical Reports Server (NTRS)

Saha, C. P.; Bryson, C. E.; Sarrazin, P.; Blake, D. F.

2005-01-01

Many Mars in situ instruments require fine-grained high-fidelity samples of rocks or soil. Included are instruments for the determination of mineralogy as well as organic and isotopic chemistry. Powder can be obtained as a primary objective of a sample collection system (e.g., by collecting powder as a surface is abraded by a rotary abrasion tool (RAT)), or as a secondary objective (e.g, by collecting drill powder as a core is drilled). In the latter case, a properly designed system could be used to monitor drilling in real time as well as to deliver powder to analytical instruments which would perform complementary analyses to those later performed on the intact core. In addition, once a core or other sample is collected, a system that could transfer intelligently collected subsamples of power from the intact core to a suite of analytical instruments would be highly desirable. We have conceptualized, developed and tested a breadboard Powder Delivery System (PoDS) intended to satisfy the collection, processing and distribution requirements of powder samples for Mars in-situ mineralogic, organic and isotopic measurement instruments.

Paleomagnetic Reorientation of Structural Elements in Drill Cores: an example from Tolhuaca Geothermal Field

NASA Astrophysics Data System (ADS)

Perez-Flores, P.; Veloso, E. E.; Cembrano, J. M.; Sánchez, P.; Iriarte, S.; Lohmar, S.

2013-12-01

Reorientation of mesoscopic faults, veins and fractures recovered from drilling is critical to construct reliable structural models that can account for their architecture and deformation regime. However, oriented cores are expensive and time consuming to drill. Some techniques achieve reorientation by introducing tools into the borehole. Problems arise when boreholes are unstable or collapse. One alternative technique allowing reorientation is to obtain reliable paleomagnetic vectors to reorient each core piece after drilling. Here, we present stable and reliable remnant magnetic vectors calculated from the Tol-1 core to analyze the geometry of the fracture network and its relationship to regional tectonic. Tol-1 core is a vertical, 1073 m deep geothermal well, drilled at the Tolhuaca Geothermal Field in the Southern Volcanic Zone of the Andes by MRP Geothermal Chile Ltda (formerly GGE Chile SpA) in 2009. The core consists of basaltic/andesitic volcanic rocks with subordinate pyroclastic/volcaniclastic units, with probable Pleistocene age. Fault planes with slickenlines and mineral fiber kinematic indicators are common in the upper 700 m of the core. Calcite, quartz and calcite-quartz veins are recognized along of entire core, whereas epidote-quartz and calcite-epidote veins occur in the last 350 m, minor chlorite, anhydrite and clay-minerals are present. Orientations of structural features in the core were measured with a goniometer using the core's axis and a false north for each piece; hence, orientation data has a false strike but a real dip. To achieve total reorientation of the pieces, we collected 200 standard-size paleomagnetic specimens, ensuring that at least four of them were recovered from continuous pieces. Thermal (up to 700°C) and alternating field demagnetization (up to 90mT on steps of 2mT) methods were used to isolate a stable remnant magnetization (RM) vector, and each technique yielded similar results. RM vectors were recovered between 0 to 25mT, and between 0 to 625°C. The declination of RM vectors was used to bring pieces to a common anchor orientation calculated through the Geocentric Axial Dipole Model (GAD). The paleomagnetic technique proved to be reliable to reorient the Tol-1 core. Structural analyses along the core show N50-60E-striking preferential vein orientation. In addition, N40-50E- and N60-70W-striking preferential fault orientations were identified. Kinematic analysis of fault-slip data shows a N60E-striking bulk fault plane solution with normal strain regime. The veins and faults orientation show strain axes compatible with published regional stress field (σmax N238E).

New Capabilities and Future Downhole and Coring Tools for IODP

NASA Astrophysics Data System (ADS)

Skinner, A.

2001-05-01

The extremely successful Ocean Drilling Programme (ODP) set the scene for innovative technical solutions to meet scientific challenges. This scenario is set to expand when the Integrated Ocean Drilling Programme (IODP) comes on stream at the end of 2003. Firstly the programme will have access to two dedicated drilling vessels and additional `Fit to mission@ offshore drilling units. This will allow for a much wider base of scientific disciplinary objectives to be met by coring and geophysical logging. And in turn will require more and innovative techncial equipment to collect the data. Secondly there are a number of coring tool developments which can enhance and extend data collection and which are not currently being used within the ODP programme. This, coupled with the different operational capabilities within IODP poses a number of technical challenges to ensure that the new programme meets all of the anticipated scientific demands. Thridly, over the past few years and ongoing at an accelerated pace, there has been significant advances in remote geophysical logging of boreholes both during and after drilling. The full potential of this has yet to be released on the scientific community and is set to revolutionise the acquisition of data from scientific boreholes. All of these items are discussed in the context of meeting the scientific challenges of IODP by harnessing and developing present industry and (outwith ODP) scientific technologies for the new programme.

The Mojave Subsurface Bio-Geochemistry Explorer (MOSBE)

NASA Technical Reports Server (NTRS)

Guerrero, J.; Beegle, L.; Abbey, W.; Bhartia, R.; Kounaves, S.; Russell, M.; Towles, D.

2012-01-01

The MOSBE Team has developed a terrestrial field campaign to explore two subsurface biological habitats under the Mojave Desert. This field campaign will not only help us understand terrestrial desert biology, but also will develop methodologies and strategies for potential future Mars missions that would seek to explore the Martian subsurface. We have proposed to the ASTEP program to integrate a suite of field demonstrated instruments with a 20 m subsurface drill as a coherent unit, the Mojave Subsurface Bio-geochemistry Explorer. The ATK Space Modular Planetary Drill System (MPDS) requires no drilling fluid, which allows aseptic sampling, can penetrate lithic ground up to 20 meters of depth, and utilizes less than 100 Watts throughout the entire depth. The drill has been developed and demonstrated in field testing to a depth of 10 meters in Arizona, December 2002. In addition to caching a continuous core throughout the drilling depth, it also generates and caches cuttings and fines that are strata-graphically correlated with the core. As a core segment is brought to the surface, it will be analyzed for texture and structure by a color microscopic imager and for relevant chemistry and mineralogy with a UV fluorescence/Raman spectrometer. Organic and soluble ionic species will be identified through two instruments -- a microcapillary electrophoresis, and an ion trap mass spectrometer that have been developed under PIDDP, ASTID and MIDP funding.

Electrical Transmission Line Diametrical Retention Mechanism

DOEpatents

Hall, David R.; Hall, Jr., H. Tracy; Pixton, David; Dahlgren, Scott; Sneddon, Cameron; Briscoe, Michael; Fox, Joe

2006-01-03

The invention is a mechanism for retaining an electrical transmission line. In one embodiment of the invention it is a system for retaining an electrical transmission line within downhole components. The invention allows a transmission line to be attached to the internal diameter of drilling components that have a substantially uniform drilling diameter. In accordance with one aspect of the invention, the system includes a plurality of downhole components, such as sections of pipe in a drill string, drill collars, heavy weight drill pipe, and jars. The system also includes a coaxial cable running between the first and second end of a drill pipe, the coaxial cable having a conductive tube and a conductive core within it. The invention allows the electrical transmission line to withstand the tension and compression of drill pipe during routine drilling cycles.

Linking downhole logging data with geology and drilling /coring operations - Example from Chicxulub Expedition 364.

NASA Astrophysics Data System (ADS)

Lofi, Johanna; Smith, Dave; Delahunty, Chris; Le Ber, Erwan; Mellet, Claire; Brun, Laurent; Henry, Gilles; Paris, Jehanne

2017-04-01

Expedition 364 was a joint IODP/ICDP mission specific platform expedition to explore the Chicxulub impact crater buried below the Yucatán continental shelf. In April and May 2016, our Expedition drilled a single borehole at Site M0077A into the crater's peak ring. It allowed recovering 303 excellent quality cores from 505.7 to 1334.7 meters below sea floor and acquiring more than 5.8 km of high resolution open hole logs. Downhole logs are rapidly collected, continuous with depth, and measured in situ; these data are classically interpreted in terms of stratigraphy, lithology, porosity, fluid content, geochemical composition and structure of the formation drilled. Downhole logs also allow assessing borehole quality (eg. shape and trajectory), and can provide assistance for decision support during drilling operations. In this work, Expedition 364 downhole logs are used to improve our understanding of the drilling/coring operation history. Differentiating between natural geological features and borehole artifacts are also critical for data quality assessment. The set of downhole geophysical tools used during Expedition 364 was constrained by the scientific objectives, drilling/coring technique, hole conditions and temperature at the drill site. Wireline logging data were acquired with slimline tools in three logging phases at intervals 0-503, 506-699 and 700-1334 mbsf. Logs were recorded either with standalone logging tools or, for the first time in IODP, with stackable slimline tools. Log data included total gamma radiation, sonic velocity, acoustic and optical borehole images, resistivity, conductivity, magnetic susceptibility, caliper and borehole fluid parameters. The majority of measurements were performed in open borehole conditions. During the drilling operations some problems were encountered directly linked to the geology of the drilled formation. For example, two zones of mud circulation losses correlate in depth with the presence of karst cavities or open faults, as evidenced from borehole wall images. Both form conduits probably open at a large scale as suggested by associated anomalies in the borehole fluid temperature profiles. When coring the basement, pieces of metal trapped outside the drill bit apparently led to an increase of the borehole tilt as well as to an enlargement of the hole, although this later remained sub-circular. In the post impact carbonates, 6-7 m long apparent cyclic oscillations in the magnetic field coupled to a spiral shape trajectory of the same wavelength suggest drilling induced artifacts and formation re-magnetization. Acknowledgements: Expedition 364 was funded by IODP with co-funding from ICDP and implemented by ECORD, with contributions and logistical support from the Yucatán state government and Universidad Nacional Autónoma de México. Drilling Services were provided by DOSECC Exploration Services. The downhole logging program was coordinated by EPC, as part of ESO. Expedition 364 Scientists: S. Gulick, J.V. Morgan, E. Chenot, G. Christeson, P. Claeys, C. Cockell, M.J. L. Coolen, L. Ferrière, C. Gebhardt, K. Goto, H. Jones, D.A. Kring, J. Lofi, X. Long, C. Lowery, C. Mellett, R. Ocampo-Torres, L. Perez-Cruz, A. Pickersgill, M. Poelchau, A. Rae, C. Rasmussen, M. Rebolledo-Vieyra, U. Riller, H. Sato, J. Smit, S. Tikoo, N. Tomioka, M. Whalen, A. Wittmann, J. Urrutia-Fucugauchi, K.E. Yamaguchi, W. Zylberman.

Geologic investigation of Playa Lakes, Tonopah Test Range, Nevada : data report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rautman, Christopher Arthur

Subsurface geological investigations have been conducted at two large playa lakes at the Tonopah Test Range in central Nevada. These characterization activities were intended to provide basic stratigraphic-framework information regarding the lateral distribution of ''hard'' and ''soft'' sedimentary materials for use in defining suitable target regions for penetration testing. Both downhole geophysical measurements and macroscopic lithilogic descriptions were used as a surrogate for quantitative mechanical-strength properties, although some quantitative laboratory strength measurements were obtained as well. Both rotary (71) and core (19) holes on a systematic grid were drilled in the southern half of the Main Lake; drill hole spacingsmore » are 300 ft north-south and 500-ft east-west. The drilled region overlaps a previous cone-penetrometer survey that also addressed the distribution of hard and soft material. Holes were drilled to a depth of 40 ft and logged using both geologic examination and down-hole geophysical surveying. The data identify a large complex of very coarse-grained sediment (clasts up to 8 mm) with interbedded finer-grained sands, silts and clays, underlying a fairly uniform layer of silty clay 6 to 12 ft thick. Geophysical densities of the course-grained materials exceed 2.0 g/cm{sup 2}, and this petrophysical value appears to be a valid discriminator of hard vs. soft sediments in the subsurface. Thirty-four holes, including both core and rotary drilling, were drilled on a portion of the much larger Antelope Lake. A set of pre-drilling geophysical surveys, including time-domain electromagnetic methods, galvanic resistivity soundings, and terrain-conductivity surveying, was used to identify the gross distribution of conductive and resistive facies with respect to the present lake outline. Conductive areas were postulated to represent softer, clay-rich sediments with larger amounts of contained conductive ground water. Initial drilling, consisting of cored drill holes to 100-ft (33-m) depth, confirmed both the specific surface geophysical measurements and the more general geophysical model of the subsurface lake facies. Good agreement of conductive regions with drill holes containing little to no coarse-grained sediments was observed, and vice-versa. A second phase of grid drilling on approximately 300-ft (100-m) centers was targeted a delineating a region of sufficient size containing essentially no coarse-grained ''hard'' material. Such a region was identified in the southwestern portion of Antelope Lake.« less

Results of exploration at the Old Leyden coal mine, Jefferson County, Colorado

USGS Publications Warehouse

Gude, A.J.; McKeown, F.A.

1953-01-01

Six diamond core holes totaling 2, 201 feet were drilled by the. U, S. Bureau of Mines under contract to the U. S. Atomic Energy Commission at the Old Leyden coal mine, Jefferson County, Colo. The holes were spotted on the basis of geologic mapping by the U. S. Geological survey and were drilled to explore the lateral and downward extent of a uranium-bearing coal and the associated carnotite deposits in the adjacent sandstone° The data obtained from the diamond-core holes helped to explain the geology and structural control of the deposit. The uranium is most abundant in a coal bed that in places has been brecciated by shearing. and then altered to a hard, dense, and silicified rock. The uraniferous coal is in the nearly vertical beds of the Laramie formation of Upper Cretaceous age. Small lenticular bodies of uraniferous material, 50 feet long, 25 to 30 feet wide, and 2 to 4 feet thick, occur at intervals in the coal and silicified coal over a strike length of about 800 feet. These bodies contain 0.10 to 0.50 percent uranium. Data obtained from the drilling indicate a discontinuous radioactive zone between these higher-grade bodies; assays of samples from the cores range from 0.001 to 0.10 percent uranium. All drill holes were probed by Survey and A. E. C. logging equipment and showed anomalies where the core assayed more than 0.005 percent uranium. Material of ore grade--0.10 percent uranium--was found in one core; the rock in the other five holes was of lower grade. The presence of the radioactive zone in all holes suggests, however, that uranium is distributed irregularly in a southerly plunging deposit which is exposed in the adit, on the outcrop, and in other diamond-drill holes that were put down by the lessee.

Different equation-of-motion coupled cluster methods with different reference functions: The formyl radical

NASA Astrophysics Data System (ADS)

Kuś, Tomasz; Bartlett, Rodney J.

2008-09-01

The doublet and quartet excited states of the formyl radical have been studied by the equation-of-motion (EOM) coupled cluster (CC) method. The Sz spin-conserving singles and doubles (EOM-EE-CCSD) and singles, doubles, and triples (EOM-EE-CCSDT) approaches, as well as the spin-flipped singles and doubles (EOM-SF-CCSD) method have been applied, subject to unrestricted Hartree-Fock (HF), restricted open-shell HF, and quasirestricted HF references. The structural parameters, vertical and adiabatic excitation energies, and harmonic vibrational frequencies have been calculated. The issue of the reference function choice for the spin-flipped (SF) method and its impact on the results has been discussed using the experimental data and theoretical results available. The results show that if the appropriate reference function is chosen so that target states differ from the reference by only single excitations, then EOM-EE-CCSD and EOM-SF-CCSD methods give a very good description of the excited states. For the states that have a non-negligible contribution of the doubly excited configurations one is able to use the SF method with such a reference function, that in most cases the performance of the EOM-SF-CCSD method is better than that of the EOM-EE-CCSD approach.

Depth profiles of Mn-53 in lunar rocks and soils

NASA Technical Reports Server (NTRS)

Imamura, M.; Nishiizumi, K.; Honda, M.; Finkel, R. C.; Arnold, J. R.; Kohl, C. P.

1974-01-01

Results of measurements of cosmic-ray-produced Mn-53 taken down the length of the Apollo 16 deep drill core are presented. They indicate that the lunar regolith has been unmixed, on a meter scale, for the past 5 million years at the location of this core. The data are in agreement with earlier Mn-53 measurements on the Apollo 15 drill core. Mn-53 activity profiles in 14310, 12002, and 14321 are compared to each other; all three rocks have probably been on the lunar surface long enough to saturate their solar cosmic-ray-produced Mn-53 (half-life = 3.7 m.y.) activity.

Hawaii scientific drilling protect: Summary of preliminary results

USGS Publications Warehouse

DePaolo, D.; Stolper, E.; Thomas, D.; Albarede, F.; Chadwick, O.; Clague, D.; Feigenson, M.; Frey, F.; Garcia, M.; Hofmann, A.; Ingram, B.L.; Kennedy, B.M.; Kirschvink, J.; Kurz, M.; Laj, Carlo; Lockwood, J.; Ludwig, K.; McEvilly, T.; Moberly, R.; Moore, G.; Moore, J.; Morin, R.; Paillet, F.; Renne, P.; Rhodes, M.; Tatsumoto, M.; Taylor, H.; Walker, G.; Wilkins, R.

1996-01-01

Petrological, geochemical, geomagnetic, and volcanological characterization of the recovered core from a 1056-m-deep well into the flank of the Mauna Kea volcano in Hilo, Hawaii, and downhole logging and fluid sampling have provided a unique view of the evolution and internal structure of a major oceanic volcano unavailable from surface exposures. Core recovery was ~90%, yielding a time series of fresh, subaerial lavas extending back to ~400 ka. Results of this 1993 project provide a basis for a more ambitious project to core drill a well 4.5 km deep in a nearby location with the goal of recovering an extended, high-density stratigraphic sequence of lavas.

Planetary Drilling and Resources at the Moon and Mars

NASA Technical Reports Server (NTRS)

George, Jeffrey A.

2012-01-01

Drilling on the Moon and Mars is an important capability for both scientific and resource exploration. The unique requirements of spaceflight and planetary environments drive drills to different design approaches than established terrestrial technologies. A partnership between NASA and Baker Hughes Inc. developed a novel approach for a dry rotary coring wireline drill capable of acquiring continuous core samples at multi-meter depths for low power and mass. The 8.5 kg Bottom Hole Assembly operated at 100 We and without need for traditional drilling mud or pipe. The technology was field tested in the Canadian Arctic in sandstone, ice and frozen gumbo. Planetary resources could play an important role in future space exploration. Lunar regolith contains oxygen and metals, and water ice has recently been confirmed in a shadowed crater at the Moon.s south pole. Mars possesses a CO2 atmosphere, frozen water ice at the poles, and indications of subsurface aquifers. Such resources could provide water, oxygen and propellants that could greatly simplify the cost and complexity of exploration and survival. NASA/JSC/EP/JAG

Effect of verification cores on tip capacity of drilled shafts.

DOT National Transportation Integrated Search

2009-02-01

This research addressed two key issues: : 1) Will verification cores holes fill during concrete backfilling? If so, what are the mechanical properties of the : filling material? In dry conditions, verification core holes always completely fill with c...

Analytic energy gradients for the orbital-optimized third-order Møller-Plesset perturbation theory

NASA Astrophysics Data System (ADS)

Bozkaya, Uǧur

2013-09-01

Analytic energy gradients for the orbital-optimized third-order Møller-Plesset perturbation theory (OMP3) [U. Bozkaya, J. Chem. Phys. 135, 224103 (2011)], 10.1063/1.3665134 are presented. The OMP3 method is applied to problematic chemical systems with challenging electronic structures. The performance of the OMP3 method is compared with those of canonical second-order Møller-Plesset perturbation theory (MP2), third-order Møller-Plesset perturbation theory (MP3), coupled-cluster singles and doubles (CCSD), and coupled-cluster singles and doubles with perturbative triples [CCSD(T)] for investigating equilibrium geometries, vibrational frequencies, and open-shell reaction energies. For bond lengths, the performance of OMP3 is in between those of MP3 and CCSD. For harmonic vibrational frequencies, the OMP3 method significantly eliminates the singularities arising from the abnormal response contributions observed for MP3 in case of symmetry-breaking problems, and provides noticeably improved vibrational frequencies for open-shell molecules. For open-shell reaction energies, OMP3 exhibits a better performance than MP3 and CCSD as in case of barrier heights and radical stabilization energies. As discussed in previous studies, the OMP3 method is several times faster than CCSD in energy computations. Further, in analytic gradient computations for the CCSD method one needs to solve λ-amplitude equations, however for OMP3 one does not since λ _{ab}^{ij(1)} = t_{ij}^{ab(1)} and λ _{ab}^{ij(2)} = t_{ij}^{ab(2)}. Additionally, one needs to solve orbital Z-vector equations for CCSD, but for OMP3 orbital response contributions are zero owing to the stationary property of OMP3. Overall, for analytic gradient computations the OMP3 method is several times less expensive than CCSD (roughly ˜4-6 times). Considering the balance of computational cost and accuracy we conclude that the OMP3 method emerges as a very useful tool for the study of electronically challenging chemical systems.

Analytic energy gradients for the orbital-optimized third-order Møller-Plesset perturbation theory.

PubMed

Bozkaya, Uğur

2013-09-14

Analytic energy gradients for the orbital-optimized third-order Møller-Plesset perturbation theory (OMP3) [U. Bozkaya, J. Chem. Phys. 135, 224103 (2011)] are presented. The OMP3 method is applied to problematic chemical systems with challenging electronic structures. The performance of the OMP3 method is compared with those of canonical second-order Møller-Plesset perturbation theory (MP2), third-order Møller-Plesset perturbation theory (MP3), coupled-cluster singles and doubles (CCSD), and coupled-cluster singles and doubles with perturbative triples [CCSD(T)] for investigating equilibrium geometries, vibrational frequencies, and open-shell reaction energies. For bond lengths, the performance of OMP3 is in between those of MP3 and CCSD. For harmonic vibrational frequencies, the OMP3 method significantly eliminates the singularities arising from the abnormal response contributions observed for MP3 in case of symmetry-breaking problems, and provides noticeably improved vibrational frequencies for open-shell molecules. For open-shell reaction energies, OMP3 exhibits a better performance than MP3 and CCSD as in case of barrier heights and radical stabilization energies. As discussed in previous studies, the OMP3 method is several times faster than CCSD in energy computations. Further, in analytic gradient computations for the CCSD method one needs to solve λ-amplitude equations, however for OMP3 one does not since λ(ab)(ij(1))=t(ij)(ab(1)) and λ(ab)(ij(2))=t(ij)(ab(2)). Additionally, one needs to solve orbital Z-vector equations for CCSD, but for OMP3 orbital response contributions are zero owing to the stationary property of OMP3. Overall, for analytic gradient computations the OMP3 method is several times less expensive than CCSD (roughly ~4-6 times). Considering the balance of computational cost and accuracy we conclude that the OMP3 method emerges as a very useful tool for the study of electronically challenging chemical systems.

An Automated, Low Mass, Low Power Drill for Acquiring Subsurface Samples of Ground Ice for Astrobiology Studies on Earth and on Mars

NASA Technical Reports Server (NTRS)

Briggs, G. A.; McKay, C.; George, J.; Derkowski, G.; Cooper, G.; Zacny, K.; Baker, R. Fincher; Pollard, W.; Clifford, S.

2003-01-01

As a project that is part of NASA s Astrobiology Technology & Instrument Development Program (ASTID), we are developing a low mass (approx.20kg) drill that will be operated without drilling fluids and at very low power levels (approx.60 watts electrical) to access and retrieve samples from permafrost regions of Earth and Mars. The drill, designed and built as a joint effort by NASA JSC and Baker-Hughes International, takes the form of a down-hole unit attached to a cable so that it can, in principle, be scaled easily to reach significant depths. A parallel laboratory effort is being carried out at UC Berkeley to characterize the physics of dry drilling under martian conditions of pressure, temperature and atmospheric composition. Data from the UCB and JSC laboratory experiments are being used as input to a drill simulation program which is under development to provide autonomous control of the drill. The first Arctic field test of the unit is planned for May 2004. A field expedition to Eureka on Ellesmere Island in Spring 2003 provided an introduction for several team members to the practical aspects of drilling under Arctic conditions. The field effort was organized by Wayne Pollard of McGill University and Christopher McKay of NASA ARC. A conventional science drill provided by New Zealand colleagues was used to recover ground ice cores for analysis of their microbial content and also to develop techniques using tracers to track the depth of penetration of contamination from the core surface into the interior of the samples.

Biostratigraphic data for the Cretaceous marine sediments in the USGS-St. George no. 1 core (DOR-211), Dorchester County, South Carolina

USGS Publications Warehouse

Self-Trail, Jean M.; Gohn, Gregory S.

1997-01-01

The USGS-St. George corehole was drilled for the U.S. Geological Survey (USGS) by a commercial drilling company during 1982. The corehole is located within the Coastal Plain Province in northern Dorchester County, South Carolina, about three miles southeast of the town of St. George near the village of Byrd (fig. 1). Coordinates for the corehole are 33o09'25'N latitude and 80o31'18'W longitude; ground elevation at the site is +78 feet (Reid and others, 1986). The St. George corehole is designated as USGS drill hole DOR-211. The St. George corehole was drilled to a total depth of 2,067 ft. The hole was cored continuously with generally good recovery from 300 ft to its total depth. Spot cores were taken at selected intervals between the top of the hole and a depth of 300 ft (50-55 ft, 100-110 ft, 150-165 ft, 200-205 ft, and 250-255 ft); however, recovery was poor in most of these intervals. The St. George core currently is stored at the USGS National Center, Reston, VA (March, 1997). The St. George corehole bottomed in basalt of probable early Mesozoic age beneath an Upper Cretaceous and Cenozoic sedi-mentary section. Reid and others (1986) placed the top of basalt saprolite at 1,962 ft in the hole. Our examination of the geophysical logs and original core descriptions suggests that the top of the saprolite is higher in the hole, at about 1,939 ft. The Cretaceous-Tertiary boundary was placed at or near 550 ft in the core by Reid and others (1986) and by Habib and Miller (1989). In this report, we provide paleontologic data for marine sediments in the upper part of the Upper Cretaceous section in the St. George core. Biostratigraphic and paleoenvironmental data and interpretations based on the study of calcareous nannofossils and ostracodes from the Cretaceous section are discussed.

The top of the Olduvai subchron in a high-resolution magnetostratigraphy from the West Turkana core WTK13, Hominin Sites and Paleolakes Drilling Project (HSPDP)

NASA Astrophysics Data System (ADS)

Sier, Mark; Langereis, Cor; Dupont-Nivet, Guillaume; Feibel, Craig; Jordeens, Jose; van der Lubbe, Jeroen; Beck, Catherine; Olago, Daniel; Cohen, Andrew

2017-04-01

One of the major challenges in understanding the evolution of our own species is identifying the role climate change has played in the evolution of earlier hominin species. To clarify the influence of climate, we need long and continuous high-resolution paleoclimate records, preferably obtained from hominin-bearing sediments, that are well-dated by tephro- and magnetostratigraphy and other methods. This is hindered, however, by the fact that fossil-bearing sediments are often discontinuous, and subject to weathering, which may lead to oxidation and remagnetization. To obtain fresh, unweathered sediments, the Hominin Sites and Paleolakes Drilling Project (HSPDP) collected a 216- meter core (WTK13) in 2013 from deposits of Early Pleistocene paleolake Lorenyang in the western Turkana Basin (Kenya). Here, we present the magnetostratigraphy of the core. Rock magnetic analyses reveal the presence of iron sulphides carrying the remanent magnetizations. To recover polarity orientation from the near-equatorial WTK13 core drilled at 5°N, we developed and successfully applied two independent drill-core reorientation methods taking advantage of (1) the sedimentary fabric as expressed in the Anisotropy of Magnetic Susceptibility (AMS) and (2) the occurrence of a viscous component oriented in the present day field. The reoriented directions reveal a normal to reversed polarity reversal identified as the top of the Olduvai subchron. From this excellent record, we find no evidence for the 'Vrica subchron' previously reported in the area. We suggest that outcrop-based interpretations supporting the presence of the Vrica subchron have been affected by the oxidation of iron sulphides initially present in the sediments as evident in the core record, and by subsequent remagnetization. Based on our new high-resolution magnetostratigraphy and stratigraphic markers, we provide constraints for an initial age model of the WTK13 core. We discuss the implications of the observed geomagnetic record for human evolution studies.

Mars Technology Rover with Arm-Mounted Percussive Coring Tool, Microimager, and Sample-Handling Encapsulation Containerization Subsystem

NASA Technical Reports Server (NTRS)

Younse, Paulo J.; Dicicco, Matthew A.; Morgan, Albert R.

2012-01-01

A report describes the PLuto (programmable logic) Mars Technology Rover, a mid-sized FIDO (field integrated design and operations) class rover with six fully drivable and steerable cleated wheels, a rocker-bogey suspension, a pan-tilt mast with panorama and navigation stereo camera pairs, forward and rear stereo hazcam pairs, internal avionics with motor drivers and CPU, and a 5-degrees-of-freedom robotic arm. The technology rover was integrated with an arm-mounted percussive coring tool, microimager, and sample handling encapsulation containerization subsystem (SHEC). The turret of the arm contains a percussive coring drill and microimager. The SHEC sample caching system mounted to the rover body contains coring bits, sample tubes, and sample plugs. The coring activities performed in the field provide valuable data on drilling conditions for NASA tasks developing and studying coring technology. Caching of samples using the SHEC system provide insight to NASA tasks investigating techniques to store core samples in the future.

Subannual layer variability in Greenland firn cores

NASA Astrophysics Data System (ADS)

Kjær, Helle Astrid; Vallelonga, Paul; Vinther, Bo; Winstrup, Mai; Simonsen, Marius; Maffezzoli, Niccoló; Jensen, Camilla Marie

2017-04-01

Ice cores are used to infer information about the past and modern techniques allow for high resolution (< cm) continuous flow analysis (CFA) of the ice. Such analysis is often used to inform on annual layers to constrain dating of ice cores, but can also be extended to provide information on sub-annual deposition patterns. In this study we use available high resolution data from multiple shallow cores around Greenland to investigate the seasonality and trends in the most often continuously measured components sodium, insoluble dust, calcium, ammonium and conductivity (or acidity) from 1800 AD to today. We evaluate the similarities and differences between the records and discuss the causes from different sources and transport to deposition and post-deposition effects over differences in measurement set up. Further we add to the array of cores already published with measurements from the newly drilled ReCAP ice core from a coastal ice cap in eastern Greenland and from a shallow core drilled at the high accumulation site at the Greenland South Dome.

Seismic imaging and velocity structure around the JFAST drill site in the Japan Trench: low Vp, high Vp/ Vs in the transparent frontal prism

NASA Astrophysics Data System (ADS)

Nakamura, Yasuyuki; Kodaira, Shuichi; Cook, Becky J.; Jeppson, Tamara; Kasaya, Takafumi; Yamamoto, Yojiro; Hashimoto, Yoshitaka; Yamaguchi, Mika; Obana, Koichiro; Fujie, Gou

2014-12-01

Seismic image and velocity models were obtained from a newly conducted seismic survey around the Integrated Ocean Drilling Program (IODP) Japan Trench Fast Drilling Project (JFAST) drill site in the Japan Trench. Pre-stack depth migration (PSDM) analysis was applied to the multichannel seismic reflection data to produce an accurate depth seismic profile together with a P wave velocity model along a line that crosses the JFAST site location. The seismic profile images the subduction zone at a regional scale. The frontal prism where the drill site is located corresponds to a typically seismically transparent (or chaotic) zone with several landward-dipping semi-continuous reflections. The boundary between the Cretaceous backstop and the frontal prism is marked by a prominent landward-dipping reflection. The P wave velocity model derived from the PSDM analysis shows low velocity in the frontal prism and velocity reversal across the backstop interface. The PSDM velocity model around the drill site is similar to the P wave velocity model calculated from the ocean bottom seismograph (OBS) data and agrees with the P wave velocities measured from the core experiments. The average Vp/ Vs in the hanging wall sediments around the drill site, as derived from OBS data, is significantly larger than that obtained from core sample measurements.

Metastable Autoionizing States of Molecules and Radicals in Highly Energetic Environment

DTIC Science & Technology

2016-03-22

electronic states. The specific aims are to develop and calibrate complex-scaled equation-of-motion coupled cluster (cs-EOM- CC ) and CAP (complex...absorbing potential) augmented EOM- CC methods. We have implemented and benchmarked cs-EOM-CCSD and CAP- augmented EOM-CCSD methods for excitation energies...motion coupled cluster (cs-EOM- CC ) and CAP (complex absorbing potential) augmented EOM- CC methods. We have implemented and benchmarked cs-EOM-CCSD and

Drilling and Caching Architecture for the Mars2020 Mission

NASA Astrophysics Data System (ADS)

Zacny, K.

2013-12-01

We present a Sample Acquisition and Caching (SAC) architecture for the Mars2020 mission and detail how the architecture meets the sampling requirements described in the Mars2020 Science Definition Team (SDT) report. The architecture uses 'One Bit per Core' approach. Having dedicated bit for each rock core allows a reduction in the number of core transfer steps and actuators and this reduces overall mission risk. It also alleviates the bit life problem, eliminates cross contamination, and aids in hermetic sealing. An added advantage is faster drilling time, lower power, lower energy, and lower Weight on Bit (which reduces Arm preload requirements). To enable replacing of core samples, the drill bits are based on the BigTooth bit design. The BigTooth bit cuts a core diameter slightly smaller than the imaginary hole inscribed by the inner surfaces of the bits. Hence the rock core could be much easier ejected along the gravity vector. The architecture also has three additional types of bits that allow analysis of rocks. Rock Abrasion and Brushing Bit (RABBit) allows brushing and grinding of rocks in the same was as Rock Abrasion Tool does on MER. PreView bit allows viewing and analysis of rock core surfaces. Powder and Regolith Acquisition Bit (PRABit) captures regolith and rock powder either for in situ analysis or sample return. PRABit also allows sieving capabilities. The architecture can be viewed here: http://www.youtube.com/watch?v=_-hOO4-zDtE

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnis Judzis; Alan Black; Homer Robertson

2006-03-01

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energymore » and loads. The significance of the ultra-high rotary speed drilling system is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm--usually well below 5,000 rpm. This document details the progress to date on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 October 2004 through 30 September 2005. Additionally, research activity from 1 October 2005 through 28 February 2006 is included in this report: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance. (2) TerraTek designed and planned Phase I bench scale experiments. Some difficulties continue in obtaining ultra-high speed motors. Improvements have been made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs have been provided to vendors for production. A more consistent product is required to minimize the differences in bit performance. A test matrix for the final core bit testing program has been completed. (3) TerraTek is progressing through Task 3 ''Small-scale cutting performance tests''. (4) Significant testing has been performed on nine different rocks. (5) Bit balling has been observed on some rock and seems to be more pronounces at higher rotational speeds. (6) Preliminary analysis of data has been completed and indicates that decreased specific energy is required as the rotational speed increases (Task 4). This data analysis has been used to direct the efforts of the final testing for Phase I (Task 5). (7) Technology transfer (Task 6) has begun with technical presentations to the industry (see Judzis).« less

Publications - GMC 327 | Alaska Division of Geological & Geophysical

Science.gov Websites

drill holes of the Coal Creek tin property of the Talkeetna Mountains D-6 Quadrangle of the Alaska Range and assays of cores from 1980, 1981, and 1982 drill holes of the Coal Creek tin property of the

High-level ab initio calculations on HGeCl and the equilibrium geometry of the A1A'' state derived from Franck-Condon analysis of the single-vibronic-level emission spectra of HGeCl and DGeCl.

PubMed

Mok, Daniel K W; Chau, Foo-Tim; Lee, Edmond P F; Dyke, John M

2010-02-01

CCSD(T) and/or CASSCF/MRCI calculations have been carried out on the X(1)A' and A(1)A'' states of HGeCl. The fully relativistic effective core potential, ECP10MDF, and associated standard valence basis sets of up to the aug-cc-pV5Z quality were employed for Ge. Contributions from core correlation and extrapolation to the complete basis set limit were included in determining the computed equilibrium geometrical parameters and relative electronic energy of these two states of HGeCl. Based on the currently, most systematic CCSD(T) calculations performed in this study, the best theoretical geometrical parameters of the X(1)A' state are r(e)(HGe) = 1.580 +/- 0.001 A, theta(e) = 93.88 +/- 0.01 degrees and r(e)(GeCl) = 2.170 +/- 0.001 A. In addition, Franck-Condon factors including allowance for anharmonicity and Duschinsky rotation between these two states of HGeCl and DGeCl were calculated employing CCSD(T) and CASSCF/MRCI potential energy functions, and were used to simulate A(1)A'' --> X(1)A' SVL emission spectra of HGeCl and DGeCl. The iterative Franck-Condon analysis (IFCA) procedure was carried out to determine the equilibrium geometrical parameters of the A(1)A'' state of HGeCl by matching the simulated, and available experimental SVL emission spectra of HGeCl and DGeCl of Tackett et al., J Chem Phys 2006, 124, 124320, using the available, estimated experimental equilibrium (r(e)(z)) structure for the X(1)A' state, while varying the equilibrium geometrical parameters of the A(1)A'' state systematically. Employing the derived IFCA geometry of r(e)(HGe) = 1.590 A, r(e)(GeCl) = 2.155 A and theta(e)(HGeCl) = 112.7 degrees for the A(1)A'' state of HGeCl in the spectral simulation, the simulated absorption and SVL emission spectra of HGeCl and DGeCl agree very well with the available experimental LIF and SVL emission spectra, respectively. Copyright 2009 Wiley Periodicals, Inc.

F+ and F⁻ affinities of simple N(x)F(y) and O(x)F(y) compounds.

PubMed

Grant, Daniel J; Wang, Tsang-Hsiu; Vasiliu, Monica; Dixon, David A; Christe, Karl O

2011-03-07

Atomization energies at 0 K and heats of formation at 0 and 298 K are predicted for the neutral and ionic N(x)F(y) and O(x)F(y) systems using coupled cluster theory with single and double excitations and including a perturbative triples correction (CCSD(T)) method with correlation consistent basis sets extrapolated to the complete basis set (CBS) limit. To achieve near chemical accuracy (±1 kcal/mol), three corrections to the electronic energy were added to the frozen core CCSD(T)/CBS binding energies: corrections for core-valence, scalar relativistic, and first order atomic spin-orbit effects. Vibrational zero point energies were computed at the CCSD(T) level of theory where possible. The calculated heats of formation are in good agreement with the available experimental values, except for FOOF because of the neglect of higher order correlation corrections. The F(+) affinity in the N(x)F(y) series increases from N(2) to N(2)F(4) by 63 kcal/mol, while that in the O(2)F(y) series decreases by 18 kcal/mol from O(2) to O(2)F(2). Neither N(2) nor N(2)F(4) is predicted to bind F(-), and N(2)F(2) is a very weak Lewis acid with an F(-) affinity of about 10 kcal/mol for either the cis or trans isomer. The low F(-) affinities of the nitrogen fluorides explain why, in spite of the fact that many stable nitrogen fluoride cations are known, no nitrogen fluoride anions have been isolated so far. For example, the F(-) affinity of NF is predicted to be only 12.5 kcal/mol which explains the numerous experimental failures to prepare NF(2)(-) salts from the well-known strong acid HNF(2). The F(-) affinity of O(2) is predicted to have a small positive value and increases for O(2)F(2) by 23 kcal/mol, indicating that the O(2)F(3)(-) anion might be marginally stable at subambient temperatures. The calculated adiabatic ionization potentials and electron affinities are in good agreement with experiment considering that many of the experimental values are for vertical processes. © 2011 American Chemical Society

Orbital-optimized MP2.5 and its analytic gradients: Approaching CCSD(T) quality for noncovalent interactions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bozkaya, Uğur, E-mail: ugur.bozkaya@atauni.edu.tr; Center for Computational Molecular Science and Technology, School of Chemistry and Biochemistry, and School of Computational Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332; Sherrill, C. David

2014-11-28

Orbital-optimized MP2.5 [or simply “optimized MP2.5,” OMP2.5, for short] and its analytic energy gradients are presented. The cost of the presented method is as much as that of coupled-cluster singles and doubles (CCSD) [O(N{sup 6}) scaling] for energy computations. However, for analytic gradient computations the OMP2.5 method is only half as expensive as CCSD because there is no need to solve λ{sub 2}-amplitude equations for OMP2.5. The performance of the OMP2.5 method is compared with that of the standard second-order Møller–Plesset perturbation theory (MP2), MP2.5, CCSD, and coupled-cluster singles and doubles with perturbative triples (CCSD(T)) methods for equilibrium geometries, hydrogenmore » transfer reactions between radicals, and noncovalent interactions. For bond lengths of both closed and open-shell molecules, the OMP2.5 method improves upon MP2.5 and CCSD by 38%–43% and 31%–28%, respectively, with Dunning's cc-pCVQZ basis set. For complete basis set (CBS) predictions of hydrogen transfer reaction energies, the OMP2.5 method exhibits a substantially better performance than MP2.5, providing a mean absolute error of 1.1 kcal mol{sup −1}, which is more than 10 times lower than that of MP2.5 (11.8 kcal mol{sup −1}), and comparing to MP2 (14.6 kcal mol{sup −1}) there is a more than 12-fold reduction in errors. For noncovalent interaction energies (at CBS limits), the OMP2.5 method maintains the very good performance of MP2.5 for closed-shell systems, and for open-shell systems it significantly outperforms MP2.5 and CCSD, and approaches CCSD(T) quality. The MP2.5 errors decrease by a factor of 5 when the optimized orbitals are used for open-shell noncovalent interactions, and comparing to CCSD there is a more than 3-fold reduction in errors. Overall, the present application results indicate that the OMP2.5 method is very promising for open-shell noncovalent interactions and other chemical systems with difficult electronic structures.« less

Deep drilling in the Chesapeake Bay impact structure - An overview

USGS Publications Warehouse

Gohn, G.S.; Koeberl, C.; Miller, K.G.; Reimold, W.U.

2009-01-01

The late Eocene Chesapeake Bay impact structure lies buried at moderate depths below Chesapeake Bay and surrounding landmasses in southeastern Virginia, USA. Numerous characteristics made this impact structure an inviting target for scientific drilling, including the location of the impact on the Eocene continental shelf, its threelayer target structure, its large size (??85 km diameter), its status as the source of the North American tektite strewn field, its temporal association with other late Eocene terrestrial impacts, its documented effects on the regional groundwater system, and its previously unstudied effects on the deep microbial biosphere. The Chesapeake Bay Impact Structure Deep Drilling Project was designed to drill a deep, continuously cored test hole into the central part of the structure. A project workshop, funding proposals, and the acceptance of those proposals occurred during 2003-2005. Initial drilling funds were provided by the International Continental Scientific Drilling Program (ICDP) and the U.S. Geological Survey (USGS). Supplementary funds were provided by the National Aeronautics and Space Administration (NASA) Science Mission Directorate, ICDP, and USGS. Field operations were conducted at Eyreville Farm, Northampton County, Virginia, by Drilling, Observation, and Sampling of the Earth's Continental Crust (DOSECC) and the project staff during September-December 2005, resulting in two continuously cored, deep holes. The USGS and Rutgers University cored a shallow hole to 140 m in April-May 2006 to complete the recovered section from land surface to 1766 m depth. The recovered section consists of 1322 m of crater materials and 444 m of overlying postimpact Eocene to Pleistocene sediments. The crater section consists of, from base to top: basement-derived blocks of crystalline rocks (215 m); a section of suevite, impact melt rock, lithic impact breccia, and cataclasites (154 m); a thin interval of quartz sand and lithic blocks (26 m); a granite megablock (275 m); and sediment blocks and boulders, polymict, sediment-clast-dominated sedimentary breccias, and a thin upper section of stratified sediments (652 m). The cored postimpact sediments provide insight into the effects of a large continental-margin impact on subsequent coastal-plain sedimentation. This volume contains the first results of multidisciplinary studies of the Eyreville cores and related topics. The volume is divided into these sections: geologic column; borehole geophysical studies; regional geophysical studies; crystalline rocks, impactites, and impact models; sedimentary breccias; postimpact sediments; hydrologic and geothermal studies; and microbiologic studies. ?? 2009 The Geological Society of America.

Rigid and Flexible Pavement Aircraft Tie-Downs

DTIC Science & Technology

2010-05-01

Concrete Pier, Prior to PCC Placement Neenah anchors are equipped with two ½-in-diameter cored holes to allow insertion of a section of rebar through...facilitate this process, a Hilti drill was utilized to perform the concrete drilling process. The drill bit diameter exceeded the rebar diameter by...aggregate particles not become lodged against the rebar sections inside the dowel sleeves, impeding the flow of concrete and possibly creating air voids

Late Cenozoic Climate History of the Ross Embayment from the AND-1B Drill Hole: Culmination of Three Decades of Antarctic Margin Drilling

USGS Publications Warehouse

Naish, T.R.; Powell, R.D.; Barrett, P.J.; Levy, R.H.; Henrys, S.; Wilson, G.S.; Krissek, L.A.; Niessen, F.; Pompilio, M.; Ross, J.; Scherer, R.; Talarico, F.; Pyne, A.; ,

2007-01-01

Because of the paucity of exposed rock, the direct physical record of Antarctic Cenozoic glacial history has become known only recently and then largely from offshore shelf basins through seismic surveys and drilling. The number of holes on the continental shelf has been small and largely confined to three areas (McMurdo Sound, Prydz Bay, and Antarctic Peninsula), but even in McMurdo Sound, where Oligocene and early Miocene strata are well cored, the late Cenozoic is poorly known and dated. The latest Antarctic geological drilling program, ANDRILL, successfully cored a 1285-m-long record of climate history spanning the last 13 m.y. from subsea-floor sediment beneath the McMurdo Ice Shelf (MIS), using drilling systems specially developed for operating through ice shelves. The cores provide the most complete Antarctic record to date of ice-sheet and climate fluctuations for this period of Earth’s history. The >60 cycles of advance and retreat of the grounded ice margin preserved in the AND-1B record the evolution of the Antarctic ice sheet since a profound global cooling step in deep-sea oxygen isotope records ~14 m.y.a. A feature of particular interest is a ~90-m-thick interval of diatomite deposited during the warm Pliocene and representing an extended period (~200,000 years) of locally open water, high phytoplankton productivity, and retreat of the glaciers on land.

Nano-Scale Sample Acquisition Systems for Small Class Exploration Spacecraft

NASA Astrophysics Data System (ADS)

Paulsen, G.

2015-12-01

The paradigm for space exploration is changing. Large and expensive missions are very rare and the space community is turning to smaller, lighter, and less expensive missions that could still perform great exploration. These missions are also within reach of commercial companies such as the Google Lunar X Prize teams that develop small scale lunar missions. Recent commercial endeavors such as "Planet Labs inc." and Sky Box Imaging, inc. show that there are new benefits and business models associated with miniaturization of space hardware. The Nano-Scale Sample Acquisition System includes NanoDrill for capture of small rock cores and PlanetVac for capture of surface regolith. These two systems are part of the ongoing effort to develop "Micro Sampling" systems for deployment by the small spacecraft with limited payload capacities. The ideal applications include prospecting missions to the Moon and Asteroids. The MicroDrill is a rotary-percussive coring drill that captures cores 7 mm in diameter and up to 2 cm long. The drill weighs less than 1 kg and can capture a core from a 40 MPa strength rock within a few minutes, with less than 10 Watt power and less than 10 Newton of preload. The PlanetVac is a pneumatic based regolith acquisition system that can capture surface sample in touch-and-go maneuver. These sampling systems were integrated within the footpads of commercial quadcopter for testing. As such, they could also be used by geologists on Earth to explore difficult to get to locations.

Auto-Gopher: A Wire-Line Rotary-Hammer Ultrasonic Drill

NASA Technical Reports Server (NTRS)

Badescu, Mircea; Sherrit, Stewart; Bao, Xiaogi; Bar-Cohen, Yoseph; Chen, Beck

2011-01-01

Developing technologies that would enable NASA to sample rock, soil, and ice by coring, drilling or abrading at a significant depth is of great importance for a large number of in-situ exploration missions as well as for earth applications. Proven techniques to sample Mars subsurface will be critical for future NASA astrobiology missions that will search for records of past and present life on the planet, as well as, the search for water and other resources. A deep corer, called Auto-Gopher, is currently being developed as a joint effort of the JPL's NDEAA laboratory and Honeybee Robotics Corp. The Auto-Gopher is a wire-line rotary-hammer drill that combines rock breaking by hammering using an ultrasonic actuator and cuttings removal by rotating a fluted bit. The hammering mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) that has been developed as an adaptable tool for many of drilling and coring applications. The USDC uses an intermediate free-flying mass to transform the high frequency vibrations of the horn tip into a sonic hammering of a drill bit. The USDC concept was used in a previous task to develop an Ultrasonic/Sonic Ice Gopher. The lessons learned from testing the ice gopher were implemented into the design of the Auto-Gopher by inducing a rotary motion onto the fluted coring bit. A wire-line version of such a system would allow penetration of significant depth without a large increase in mass. A laboratory version of the corer was developed in the NDEAA lab to determine the design and drive parameters of the integrated system. The design configuration lab version of the design and fabrication and preliminary testing results are presented in this paper

A multi-level quantum mechanics and molecular mechanics study of SN2 reaction at nitrogen: NH2Cl + OH(-) in aqueous solution.

PubMed

Lv, Jing; Zhang, Jingxue; Wang, Dunyou

2016-02-17

We employed a multi-level quantum mechanics and molecular mechanics approach to study the reaction NH2Cl + OH(-) in aqueous solution. The multi-level quantum method (including the DFT method with both the B3LYP and M06-2X exchange-correlation functionals and the CCSD(T) method, and both methods with the aug-cc-pVDZ basis set) was used to treat the quantum reaction region in different stages of the calculation in order to obtain an accurate potential of mean force. The obtained free energy activation barriers at the DFT/MM level of theory yielded a big difference of 21.8 kcal mol(-1) with the B3LYP functional and 27.4 kcal mol(-1) with the M06-2X functional respectively. Nonetheless, the barrier heights become very close when shifted from DFT to CCSD(T): 22.4 kcal mol(-1) and 22.9 kcal mol(-1) at CCSD(T)(B3LYP)/MM and CCSD(T)(M06-2X)/MM levels of theory, respectively. The free reaction energy obtained using CCSD(T)(M06-2X)/MM shows an excellent agreement with the one calculated using the available gas-phase data. Aqueous solution plays a significant role in shaping the reaction profile. In total, the water solution contributes 13.3 kcal mol(-1) and 14.6 kcal mol(-1) to the free energy barrier heights at CCSD(T)(B3LYP)/MM and CCSD(T)(M06-2X)/MM respectively. The title reaction at nitrogen is a faster reaction than the corresponding reaction at carbon, CH3Cl + OH(-).

Long Valley Coring Project, Inyo County, California, 1998, preliminary stratigraphy and images of recovered core

USGS Publications Warehouse

Sackett, Penelope C.; McConnell, Vicki S.; Roach, Angela L.; Priest, Susan S.; Sass, John H.

1999-01-01

Phase III of the Long Valley Exploratory Well, the Long Valley Coring Project, obtained continuous core between the depths of 7,180 and 9,831 ft (2,188 to 2,996 meters) during the summer of 1998. This report contains a compendium of information designed to facilitate post-drilling research focussed on the study of the core. Included are a preliminary stratigraphic column compiled primarily from field observations and a general description of well lithology for the Phase III drilling interval. Also included are high-resolution digital photographs of every core box (10 feet per box) as well as scanned images of pieces of recovered core. The user can easily move from the stratigraphic column to corresponding core box photographs for any depth. From there, compressed, "unrolled" images of the individual core pieces (core scans) can be accessed. Those interested in higher-resolution core scans can go to archive CD-ROMs stored at a number of locations specified herein. All core is stored at the USGS Core Research Center in Denver, Colorado where it is available to researchers following the protocol described in this report. Preliminary examination of core provided by this report and the archive CD-ROMs should assist researchers in narrowing their choices when requesting core splits.

Construction diagrams, geophysical logs, and lithologic descriptions for boreholes USGS 103, 105, 108, 131, 135, NRF-15, and NRF-16, Idaho National Laboratory, Idaho

USGS Publications Warehouse

Hodges, Mary K.V.; Orr, Stephanie M.; Potter, Katherine E.; LeMaitre, Tynan

2012-01-01

This report, prepared in cooperation with the U.S. Department of Energy, summarizes construction, geophysical, and lithologic data collected from about 4,509 feet of core from seven boreholes deepened or drilled by the U.S. Geological Survey (USGS), Idaho National Laboratory (INL) Project Office, from 2006 to 2009 at the INL. USGS 103, 105, 108, and 131 were deepened and cored from 759 to 1,307 feet, 800 to 1,409 feet, 760 to 1,218 feet, and 808 to 1,239 feet, respectively. Boreholes USGS 135, NRF-15, and NRF-16 were drilled and continuously cored from land surface to 1,198, 759, and 425 feet, respectively. Cores were photographed and digitally logged by using commercially available software. Borehole descriptions summarize location, completion date, and amount and type of core recovered.

Delivery of prazosin hydrochloride from osmotic pump system prepared by coating the core tablet with an indentation.

PubMed

Liu, Longxiao; Wang, Jinchao; Zhu, Suyan

2007-04-01

The preparation of an osmotic pump tablet was simplified by elimination of laser drilling using prazosin hydrochloride as the model drug. The osmotic pump system was obtained by coating the indented core tablet compressed by the punch with a needle. A multiple regression equation was achieved with the experimental data of core tablet formulations, and then the formulation was optimized. The influences of the indentation size of the core tablet, environmental media, and agitation rate on drug release profile were investigated. The optimal osmotic pump tablet was found to deliver prazosin hydrochloride at an approximately constant rate up to 24 hr, and independent on both release media and agitation rate. Indentation size of core tablet hardly affected drug release in the range of 0.80-1.15 mm. The method that is simplified by elimination of laser drilling may be promising for preparation of an osmotic pump tablet.

Non-iterative triple excitations in equation-of-motion coupled-cluster theory for electron attachment with applications to bound and temporary anions.

PubMed

Jagau, Thomas-C

2018-01-14

The impact of residual electron correlation beyond the equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) approximation on positions and widths of electronic resonances is investigated. To establish a method that accomplishes this task in an economical manner, several approaches proposed for the approximate treatment of triple excitations are reviewed with respect to their performance in the electron attachment (EA) variant of EOM-CC theory. The recently introduced EOM-CCSD(T)(a)* method [D. A. Matthews and J. F. Stanton, J. Chem. Phys. 145, 124102 (2016)], which includes non-iterative corrections to the reference and the target states, reliably reproduces vertical attachment energies from EOM-EA-CC calculations with single, double, and full triple excitations in contrast to schemes in which non-iterative corrections are applied only to the target states. Applications of EOM-EA-CCSD(T)(a)* augmented by a complex absorbing potential (CAP) to several temporary anions illustrate that shape resonances are well described by EOM-EA-CCSD, but that residual electron correlation often makes a non-negligible impact on their positions and widths. The positions of Feshbach resonances, on the other hand, are significantly improved when going from CAP-EOM-EA-CCSD to CAP-EOM-EA-CCSD(T)(a)*, but the correct energetic order of the relevant electronic states is still not achieved.

Non-iterative triple excitations in equation-of-motion coupled-cluster theory for electron attachment with applications to bound and temporary anions

NASA Astrophysics Data System (ADS)

Jagau, Thomas-C.

2018-01-01

The impact of residual electron correlation beyond the equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) approximation on positions and widths of electronic resonances is investigated. To establish a method that accomplishes this task in an economical manner, several approaches proposed for the approximate treatment of triple excitations are reviewed with respect to their performance in the electron attachment (EA) variant of EOM-CC theory. The recently introduced EOM-CCSD(T)(a)* method [D. A. Matthews and J. F. Stanton, J. Chem. Phys. 145, 124102 (2016)], which includes non-iterative corrections to the reference and the target states, reliably reproduces vertical attachment energies from EOM-EA-CC calculations with single, double, and full triple excitations in contrast to schemes in which non-iterative corrections are applied only to the target states. Applications of EOM-EA-CCSD(T)(a)* augmented by a complex absorbing potential (CAP) to several temporary anions illustrate that shape resonances are well described by EOM-EA-CCSD, but that residual electron correlation often makes a non-negligible impact on their positions and widths. The positions of Feshbach resonances, on the other hand, are significantly improved when going from CAP-EOM-EA-CCSD to CAP-EOM-EA-CCSD(T)(a)*, but the correct energetic order of the relevant electronic states is still not achieved.

High-quality heat flow determination from the crystalline basement of the south-east margin of North China Craton

NASA Astrophysics Data System (ADS)

Jiang, Guangzheng; Tang, Xiaoyin; Rao, Song; Gao, Peng; Zhang, Linyou; Zhao, Ping; Hu, Shengbiao

2016-03-01

Very few of heat flow data have come from the crystalline basement in the North China Craton but rather from boreholes in the sedimentary cover of oil-gas basins. Explorations for hot dry rock (HDR) geothermal resources and porphyry gold deposits in eastern China offer now valuable opportunities to study the terrestrial heat flow in the crystalline basement. In this study, we obtained continuous temperature logs from two boreholes (the LZ borehole with a depth of 3471 m and the DR borehole with a depth of 2179 m) located in the south-east margin of the North China Craton. The boreholes have experienced long shut-in times (442 days and 261 days for the LZ borehole and DR borehole, respectively); thus, it can be expected that the temperature conditions have re-equilibrated after drilling and drill-mud circulation. Rock thermal conductivity and radiogenic heat production were measured for 68 crystalline rock samples from these two boreholes. The measured heat-flow density was determined to be 71.8 ± 2.3 mW m-2 (for the LZ borehole) and 91.5 ± 1.2 mW m-2 (for the DR borehole). The heat flow for the LZ borehole is close to the value of 75 mW m-2 determined in the Chinese Continental Scientific Drilling main hole (CCSD MH), both being in the Sulu-Dabie orogenic belt and thus able to verify each other. The value for the DR borehole is higher than the above two values, which supports former high heat-flow values determined in the Bohai Bay Basin.

Primary sedimentary structures and the internal architecture of a Martian sand body in search of evidence for sand transport and deposition

NASA Technical Reports Server (NTRS)

Basu, Abhijit

1988-01-01

Lunar experiences show that unmanned sample return missions, despite limitations on sample size, can produce invaluable data to infer crustal processes, regolith processes, regolith-atmosphere/ionosphere interaction processes, etc. Drill cores provide a record of regolith evolution as well as a more complete sample of the regolith than small scoops and/or rakes. It is proposed that: (1) a hole be drilled in a sand body to obtain continuous oriented cores; a depth of about 10 m would be compatible with what we know of bed form hierarchy of terrestrial stream deposits; (2) two trenches, at right angles to each other and close to the drill-hole, be dug and the walls scraped lightly such that primary/internal sedimentary structures of the sand body become visible; (3) the walls of the trenches be made gravitationally stable by impregnation techniques; (4) acetate or other peels of a strip on each wall be taken; and (5) appropriately scaled photographs of the walls be taken at different sun-angles to ensure maximum ease of interpretation of sedimentary structures; and, to correlate these structural features with those in the core at different depth levels of the core.

Management of non-traumatic avascular necrosis of the femoral head-a comparative analysis of the outcome of multiple small diameter drilling and core decompression with fibular grafting.

PubMed

Mohanty, S P; Singh, K A; Kundangar, R; Shankar, V

2017-04-01

The purpose of this study was to compare the clinical and radiological outcomes of multiple small diameter drilling and core decompression with fibular strut grafting in the management of non-traumatic avascular necrosis (AVN) of the femoral head. Outcomes of patients with AVN treated by multiple small diameter drilling (group 1) were compared retrospectively with patients treated by core decompression and fibular grafting (group 2). Harris hip score (HHS) was used to assess the clinical status pre- and postoperatively. Modified Ficat and Arlet classification was used to assess the radiological stage pre- and postoperatively. Forty-six patients (68 hips) were included in this study. Group 1 consisted of 33 hips, and group 2 consisted of 35 hips. In stages I and IIB, there was no statistically significant difference in the final HHS between the two groups. However, in stages IIA and III, hips in group 2 had a better final HHS (P < 0.05). In terms of radiographic progression, there was no statistical difference between hips in stages I, IIA and stage IIB. However, in stage III, hips belonging to group 2 had better results (P < 0.05). Kaplan-Meier survivorship analysis showed better outcome in group 2 in stage III (P < 0.05). Hips with AVN in the precollapse stage can be salvaged by core decompression with or without fibular grafting. Multiple small diameter drilling is relatively simple and carries less morbidity and hence preferred in stages I and II. However, in stage III disease, core decompression with fibular strut grafting gives better results.

The ICDP Snake River Geothermal Drilling Project: preliminary overview of borehole geophysics

USGS Publications Warehouse

Schmitt, Douglas R.; Liberty, Lee M.; Kessler, James E.; Kuck, Jochem; Kofman, Randolph; Bishop, Ross; Shervais, John W.; Evans, James P.; Champion, Duane E.

2012-01-01

Hotspot: The Snake River Geothermal Drilling Project was undertaken to better understand the geothermal systems in three locations across the Snake River Plain with varying geological and hydrological structure. An extensive series of standard and specialized geophysical logs were obtained in each of the wells. Hydrogen-index neutron and γ-γ density logs employing active sources were deployed through the drill string, and although not fully calibrated for such a situation do provide semi-quantitative information related to the ‘stratigraphy’ of the basalt flows and on the existence of alteration minerals. Electrical resistivity logs highlight the existence of some fracture and mineralized zones. Magnetic susceptibility together with the vector magnetic field measurements display substantial variations that, in combination with laboratory measurements, may provide a tool for tracking magnetic field reversals along the borehole. Full waveform sonic logs highlight the variations in compressional and shear velocity along the borehole. These, together with the high resolution borehole seismic measurements display changes with depth that are not yet understood. The borehole seismic measurements indicate that seismic arrivals are obtained at depth in the formations and that strong seismic reflections are produced at lithological contacts seen in the corresponding core logging. Finally, oriented ultrasonic borehole televiewer images were obtained over most of the wells and these correlate well with the nearly 6 km of core obtained. This good image log to core correlations, particularly with regards to drilling induced breakouts and tensile borehole and core fractures will allow for confident estimates of stress directions and or placing constraints on stress magnitudes. Such correlations will be used to orient in core orientation giving information useful in hydrological assessments, paleomagnetic dating, and structural volcanology.

Coring Sample Acquisition Tool

NASA Technical Reports Server (NTRS)

Haddad, Nicolas E.; Murray, Saben D.; Walkemeyer, Phillip E.; Badescu, Mircea; Sherrit, Stewart; Bao, Xiaoqi; Kriechbaum, Kristopher L.; Richardson, Megan; Klein, Kerry J.

2012-01-01

A sample acquisition tool (SAT) has been developed that can be used autonomously to sample drill and capture rock cores. The tool is designed to accommodate core transfer using a sample tube to the IMSAH (integrated Mars sample acquisition and handling) SHEC (sample handling, encapsulation, and containerization) without ever touching the pristine core sample in the transfer process.

Microgravity Drill and Anchor System

NASA Technical Reports Server (NTRS)

Parness, Aaron; Frost, Matthew A.; King, Jonathan P.

2013-01-01

This work is a method to drill into a rock surface regardless of the gravitational field or orientation. The required weight-on-bit (WOB) is supplied by a self-contained anchoring mechanism. The system includes a rotary percussive coring drill, forming a complete sampling instrument usable by robot or human. This method of in situ sample acquisition using micro - spine anchoring technology enables several NASA mission concepts not currently possible with existing technology, including sampling from consolidated rock on asteroids, providing a bolt network for astronauts visiting a near-Earth asteroid, and sampling from the ceilings or vertical walls of lava tubes and cliff faces on Mars. One of the most fundamental parameters of drilling is the WOB; essentially, the load applied to the bit that allows it to cut, creating a reaction force normal to the surface. In every drilling application, there is a minimum WOB that must be maintained for the system to function properly. In microgravity (asteroids and comets), even a small WOB could not be supported conventionally by the weight of the robot or astronaut. An anchoring mechanism would be needed to resist the reactions, or the robot or astronaut would push themselves off the surface and into space. The ability of the system to anchor itself to a surface creates potential applications that reach beyond use in low gravity. The use of these anchoring mechanisms as end effectors on climbing robots has the potential of vastly expanding the scope of what is considered accessible terrain. Further, because the drill is supported by its own anchor rather than by a robotic arm, the workspace is not constrained by the reach of such an arm. Yet, if the drill is on a robotic arm, it has the benefit of not reflecting the forces of drilling back to the arm s joints. Combining the drill with the anchoring feet will create a highly mobile, highly stable, and highly reliable system. The drilling system s anchor uses hundreds of microspine toes that independently find holes and ledges on a rock to create an anchor. Once the system is anchored, a linear translation mechanism moves the drill axially into the surface while maintaining the proper WOB. The linear translation mechanism is composed of a ball screw and stepper motor that can translate a carriage with high precision and applied load. The carriage slides along rails using self-aligning linear bearings that correct any axial misalignment caused by bending and torsion. The carriage then compresses a series of springs that simultaneously transmit the load to the drill along the bit axis and act as a suspension that compensates for the vibration caused by percussive drilling. The drill is a compacted, modified version of an off-the-shelf rotary percussive drill, which uses a custom carbide-tipped coring bit. By using rotary percussive drilling, the drill time is greatly reduced. The percussive action fractures the rock debris, which is removed during rotation. The final result is a 0.75-in. (.1.9- cm) diameter hole and a preserved 0.5- in. (.1.3-cm) diameter rock core. This work extends microspine technology, making it applicable to astronaut missions to asteroids and a host of robotic sampling concepts. At the time of this reporting, it is the first instrument to be demonstrated using microspine anchors, and is the first self-contained drill/anchor system to be demonstrated that is capable of drilling in inverted configurations and would be capable of drilling in microgravity.

Ultrasonic rotary-hammer drill

NASA Technical Reports Server (NTRS)

Bar-Cohen, Yoseph (Inventor); Badescu, Mircea (Inventor); Sherrit, Stewart (Inventor); Kassab, Steve (Inventor); Bao, Xiaoqi (Inventor)

2010-01-01

A mechanism for drilling or coring by a combination of sonic hammering and rotation. The drill includes a hammering section with a set of preload weights mounted atop a hammering actuator and an axial passage through the hammering section. In addition, a rotary section includes a motor coupled to a drive shaft that traverses the axial passage through the hammering section. A drill bit is coupled to the drive shaft for drilling by a combination of sonic hammering and rotation. The drill bit includes a fluted shaft leading to a distal crown cutter with teeth. The bit penetrates sampled media by repeated hammering action. In addition, the bit is rotated. As it rotates the fluted bit carries powdered cuttings helically upward along the side of the bit to the surface.

The Oman Drilling Project

NASA Astrophysics Data System (ADS)

Matter, J.; Kelemen, P. B.; Teagle, D. A. H.

2014-12-01

With seed funds from the Sloan Foundation, the International Continental Drilling Program (ICDP) approved a proposal by 39 international proponents for scientific drilling in the Oman ophiolite. Via observations on core, geophysical logging, fluid sampling, hydrological measurements, and microbiological sampling in a series of boreholes, we will address long-standing, unresolved questions regarding melt and solid transport in the mantle beneath oceanic spreading ridges, igneous accretion of oceanic crust, mass transfer between the oceans and the crust via hydrothermal alteration, and recycling of volatile components in subduction zones. We will undertake frontier exploration of subsurface weathering processes in mantle peridotite, including natural mechanisms of carbon dioxide uptake from surface waters and the atmosphere, and the nature of the subsurface biosphere. Societally relevant aspects include involvement and training of university students, including numerous students from Sultan Qaboos University in Oman. Studies of natural mineral carbonation will contribute to design of engineered systems for geological carbon dioxide capture and storage. Studies of alteration will contribute to fundamental understanding of the mechanisms of reaction-driven cracking, which could enhance geothermal power generation and extraction of unconventional hydrocarbon resources. We hope to begin drilling in late 2015. Meanwhile, we are seeking an additional $2M to match the combined Sloan and ICDP funding from national and international funding agencies. Matching funds are needed for operational costs of drilling, geophysical logging, downhole fluid sampling, and core description. Information on becoming part of the named investigator pool is in Appendix 14 (page 70) of the ICDP proposal, available at https://www.ldeo.columbia.edu/gpg/projects/icdp-workshop-oman-drilling-project. This formal process should begin at about the time of the 2014 Fall AGU Meeting. Meanwhile, potential investigators who can help raise matching funds, e.g. for core description as part of petrological or structural studies or for drill site operations, are encouraged to contact the authors of this abstract.

Estimation and Control for Autonomous Coring from a Rover Manipulator

NASA Technical Reports Server (NTRS)

Hudson, Nicolas; Backes, Paul; DiCicco, Matt; Bajracharya, Max

2010-01-01

A system consisting of a set of estimators and autonomous behaviors has been developed which allows robust coring from a low-mass rover platform, while accommodating for moderate rover slip. A redundant set of sensors, including a force-torque sensor, visual odometry, and accelerometers are used to monitor discrete critical and operational modes, as well as to estimate continuous drill parameters during the coring process. A set of critical failure modes pertinent to shallow coring from a mobile platform is defined, and autonomous behaviors associated with each critical mode are used to maintain nominal coring conditions. Autonomous shallow coring is demonstrated from a low-mass rover using a rotary-percussive coring tool mounted on a 5 degree-of-freedom (DOF) arm. A new architecture of using an arm-stabilized, rotary percussive tool with the robotic arm used to provide the drill z-axis linear feed is validated. Particular attention to hole start using this architecture is addressed. An end-to-end coring sequence is demonstrated, where the rover autonomously detects and then recovers from a series of slip events that exceeded 9 cm total displacement.

25 CFR 226.22 - Prohibition of pollution.

Code of Federal Regulations, 2014 CFR

2014-04-01

... all times conduct their operations and drill, equip, operate, produce, plug and abandon all wells drilled for oil or gas, service wells or exploratory wells (including seismic, core and stratigraphic... LANDS FOR OIL AND GAS MINING Operations § 226.22 Prohibition of pollution. (a) All operators...

25 CFR 226.22 - Prohibition of pollution.

Code of Federal Regulations, 2013 CFR

2013-04-01

... all times conduct their operations and drill, equip, operate, produce, plug and abandon all wells drilled for oil or gas, service wells or exploratory wells (including seismic, core and stratigraphic... LANDS FOR OIL AND GAS MINING Operations § 226.22 Prohibition of pollution. (a) All operators...

25 CFR 226.22 - Prohibition of pollution.

Code of Federal Regulations, 2012 CFR

2012-04-01

... all times conduct their operations and drill, equip, operate, produce, plug and abandon all wells drilled for oil or gas, service wells or exploratory wells (including seismic, core and stratigraphic... LANDS FOR OIL AND GAS MINING Operations § 226.22 Prohibition of pollution. (a) All operators...

Gravity-Independent Mobility and Drilling on Natural Rock using Microspines

NASA Technical Reports Server (NTRS)

Parness, Aaron; Frost, Matthew; Thatte, Nitish; King, Jonathan P.

2012-01-01

To grip rocks on the surfaces of asteroids and comets, and to grip the cliff faces and lava tubes of Mars, a 250 mm diameter omni-directional anchor is presented that utilizes a hierarchical array of claws with suspension flexures, called microspines, to create fast, strong attachment. Prototypes have been demonstrated on vesicular basalt and a'a lava rock supporting forces in all directions away from the rock. Each anchor can support >160 N tangent, >150 N at 45?, and >180 N normal to the surface of the rock. A two-actuator selectively- compliant ankle interfaces these anchors to the Lemur IIB robot for climbing trials. A rotary percussive drill was also integrated into the anchor, demonstrating self-contained rock coring regardless of gravitational orientation. As a harder- than-zero-g proof of concept, 20mm diameter boreholes were drilled 83 mm deep in vesicular basalt samples, retaining a 12 mm diameter rock core in 3-6 pieces while in an inverted configuration, literally drilling into the ceiling.

The X40×10 Halogen Bonding Benchmark Revisited: Surprising Importance of (n-1)d Subvalence Correlation.

PubMed

Kesharwani, Manoj K; Manna, Debashree; Sylvetsky, Nitai; Martin, Jan M L

2018-03-01

We have re-evaluated the X40×10 benchmark for halogen bonding using conventional and explicitly correlated coupled cluster methods. For the aromatic dimers at small separation, improved CCSD(T)-MP2 "high-level corrections" (HLCs) cause substantial reductions in the dissociation energy. For the bromine and iodine species, (n-1)d subvalence correlation increases dissociation energies and turns out to be more important for noncovalent interactions than is generally realized; (n-1)sp subvalence correlation is much less important. The (n-1)d subvalence term is dominated by core-valence correlation; with the smaller cc-pVDZ-F12-PP and cc-pVTZ-F12-PP basis sets, basis set convergence for the core-core contribution becomes sufficiently erratic that it may compromise results overall. The two factors conspire to generate discrepancies of up to 0.9 kcal/mol (0.16 kcal/mol RMS) between the original X40×10 data and the present revision.

Preliminary study on rotary ultrasonic machining of CFRP/Ti stacks.

PubMed

Cong, W L; Pei, Z J; Treadwell, C

2014-08-01

Reported drilling methods for CFRP/Ti stacks include twist drilling, end milling, core grinding, and their derived methods. The literature does not have any report on drilling of CFRP/Ti stacks using rotary ultrasonic machining (RUM). This paper, for the first time, reports a study on drilling of CFRP/Ti stacks using RUM. It also compares results on drilling of CFRP/Ti stacks using RUM with reported results on drilling of CFRP/Ti stacks using other methods. When drilling CFRP/Ti stacks using RUM, cutting force, torque, and CFRP surface roughness were lower, hole size variation was smaller, CFRP groove depth was smaller, tool life was longer, and there was no obvious Ti exit burr and CFRP entrance delamination. Ti surface roughness when drilling of CFRP/Ti stacks using RUM was about the same as those when using other methods. Copyright © 2014 Elsevier B.V. All rights reserved.

Heterogeneous Shallow-Shelf Carbonate Buildups in the Paradox Basin, Utah and Colorado: Targets for Increased Oil Production and Reserves Using Horizontal Drilling Techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wray, Laura L.; Eby, David E.; Chidsey, Jr., Thomas C.

2002-07-24

This report covers research activities for the second half of the second project year (October 6, 2001, through April 5, 2002). This work includes description and analysis of cores, correlation of geophysical well logs, reservoir mapping, petrographic description of thin sections, cross plotting of permeability and porosity data, and development of horizontal drilling strategies for the Little Ute and Sleeping Ute fields in Montezuma County, Colorado. Geological characterization on a local scale focused on reservoir heterogeneity, quality, and lateral continuity, as well as possible compartmentalization, within these fields. This study utilizes representative core, geophysical logs, and thin sections to characterizemore » and grade each field's potential for drilling horizontal laterals from existing development wells.« less

Comparative study of two active faults in different stages of the earthquake cycle in central Japan -The Atera fault (with 1586 Tensho earthquake) and the Nojima fault (with 1995 Kobe earthquake)-

NASA Astrophysics Data System (ADS)

Matsuda, T.; Omura, K.; Ikeda, R.

2003-12-01

National Research Institute for Earth Science and Disaster Prevention (NIED) has been conducting _gFault zone drilling_h. Fault zone drilling is especially important in understanding the structure, composition, and physical properties of an active fault. In the Chubu district of central Japan, large active faults such as the Atotsugawa (with 1858 Hietsu earthquake) and the Atera (with 1586 Tensho earthquake) faults exist. After the occurrence of the 1995 Kobe earthquake, it has been widely recognized that direct measurements in fault zones by drilling. This time, we describe about the Atera fault and the Nojima fault. Because, these two faults are similar in geological situation (mostly composed of granitic rocks), so it is easy to do comparative study of drilling investigation. The features of the Atera fault, which have been dislocated by the 1586 Tensho earthquake, are as follows. Total length is about 70 km. That general trend is NW45 degree with a left-lateral strike slip. Slip rate is estimated as 3-5 m / 1000 years. Seismicity is very low at present and lithologies around the fault are basically granitic rocks and rhyolite. Six boreholes have been drilled from the depth of 400 m to 630 m. Four of these boreholes (Hatajiri, Fukuoka, Ueno and Kawaue) are located on a line crossing in a direction perpendicular to the Atera fault. In the Kawaue well, mostly fractured and alternating granitic rock continued from the surface to the bottom at 630 m. X-ray fluorescence analysis (XRF) is conducted to estimate the amount of major chemical elements using the glass bead method for core samples. The amounts of H20+ are about from 0.5 to 2.5 weight percent. This fractured zone is also characterized by the logging data such as low resistivity, low P-wave velocity, low density and high neutron porosity. The 1995 Kobe (Hyogo-ken Nanbu) earthquake occurred along the NE-SW-trending Rokko-Awaji fault system, and the Nojima fault appeared on the surface on Awaji Island when this rupture occurred. It is more than 10 km long with 1-2 m offset along the Nojima fault. About one year after the earthquake, NIED drilled a borehole (the Hirabayashi NIED borehole) and penetrated the Nojima fault. The Hirabayashi NIED borehole was drilled to a depth of 1838 m and recovered the drill core. The main types of rock intersected by the borehole are granodiorite and cataclastic fault rocks. Three fracture zones were recognized in cores at approximate depth of 1140 m, 1300 m and 1800 m. There is remarkable foliated blue-gray gouge at a depth of 1140 m. We investigate chemical compositions by XRF analysis in the fracture zone. The amounts of H20+ are about from 1.0 to 15.0 weight percent. We investigate mineral assemblage in both drilling cores by X-ray powder diffraction analysis. From the results, we can_ft recognize so difference between the two faults. But the amount of H2O+ is very different. In the Hirabayashi NIED core at a depth of 1140 m, there is about ten times as much as the average of the Kawaue core. This is probably due to the greater degree of wall-rock fracturing in the fracture zone. We suggest that this characteristic is associated with the fault activity at the time of the 1995 Kobe earthquake and the nature of fluid-rock interactions in the fracture zone.

Oil-shale data, cores, and samples collected by the U.S. geological survey through 1989

USGS Publications Warehouse

Dyni, John R.; Gay, Frances; Michalski, Thomas C.; ,

1990-01-01

The U.S. Geological Survey has acquired a large collection of geotechnical data, drill cores, and crushed samples of oil shale from the Eocene Green River Formation in Colorado, Wyoming, and Utah. The data include about 250,000 shale-oil analyses from about 600 core holes. Most of the data is from Colorado where the thickest and highest-grade oil shales of the Green River Formation are found in the Piceance Creek basin. Other data on file but not yet in the computer database include hundreds of lithologic core descriptions, geophysical well logs, and mineralogical and geochemical analyses. The shale-oil analyses are being prepared for release on floppy disks for use on microcomputers. About 173,000 lineal feet of drill core of oil shale and associated rocks, as well as 100,000 crushed samples of oil shale, are stored at the Core Research Center, U.S. Geological Survey, Lakewood, Colo. These materials are available to the public for research.

Core Research Center

USGS Publications Warehouse

Hicks, Joshua; Adrian, Betty

2009-01-01

The Core Research Center (CRC) of the U.S. Geological Survey (USGS), located at the Denver Federal Center in Lakewood, Colo., currently houses rock core from more than 8,500 boreholes representing about 1.7 million feet of rock core from 35 States and cuttings from 54,000 boreholes representing 238 million feet of drilling in 28 States. Although most of the boreholes are located in the Rocky Mountain region, the geologic and geographic diversity of samples have helped the CRC become one of the largest and most heavily used public core repositories in the United States. Many of the boreholes represented in the collection were drilled for energy and mineral exploration, and many of the cores and cuttings were donated to the CRC by private companies in these industries. Some cores and cuttings were collected by the USGS along with other government agencies. Approximately one-half of the cores are slabbed and photographed. More than 18,000 thin sections and a large volume of analytical data from the cores and cuttings are also accessible. A growing collection of digital images of the cores are also becoming available on the CRC Web site Internet http://geology.cr.usgs.gov/crc/.

Revision of the experimental electron affinity of BO

NASA Astrophysics Data System (ADS)

Rienstra, Jonathan C.; Schaefer, Henry F., III

1997-05-01

The experimental electron affinity of BO has proven questionable. We obtained the electron affinity of BO using the large aug-cc-pVQZ basis with SCF, CISD, CISD+Q, CCSD, and CCSD(T) methods and predict a value of 2.57 eV, or 0.55 eV smaller than the latest experimental value. The 2∑+ to 2Π excitation energy of BO has also been obtained with the CCSD(T) method and found to be 2.82 eV.

Recent scientific and operational achievements of D/V Chikyu

NASA Astrophysics Data System (ADS)

Taira, Asahiko; Toczko, Sean; Eguchi, Nobu; Kuramoto, Shin'ichi; Kubo, Yusuke; Azuma, Wataru

2014-12-01

The D/V Chikyu, a scientific drilling vessel, is equipped with industry-standard riser capabilities. Riser drilling technology enables remarkable drilling and downhole logging capabilities and provides unprecedented hole-stability, enabling the shipboard team to retrieve high-quality wire-line logging data as well as well-preserved core samples. The 11 March 2011 Tohoku Oki mega-earthquake and tsunami cost over 18,000 casualties in NE Japan. Chikyu, docked in the Port of Hachinohe, was damaged by the tsunami. By April 2012, the ship was back in operation; drilling the toe of the Japan Trench fault zone where topographic surveys suggested there was up to 50 m eastward motion, the largest earthquake rupture ever recorded. During Integrated Ocean Drilling Program (IODP) Expeditions 343 and 343 T, Chikyu drilled 850 m below sea floor (mbsf) in 6,900+ m water depth and recovered core samples of a highly brecciated shear zone composed of pelagic claystone. A subseafloor observatory looking for temperature signatures caused by the fault friction during the earthquake, was installed and later successfully recovered. The recovered temperature loggers recorded data from which the level of friction during the mega-earthquake slip could be determined. Following Exp. 343, Chikyu began IODP Exp. 337, a riser drilling expedition into the Shimokita coal beds off Hachinohe, to study the deep subsurface biosphere in sedimentary units including Paleogene-Neogene coal beds. New records in scientific ocean drilling were achieved in deepest penetration (drilling reached 2,466 mbsf) and sample recovery. Currently Chikyu is conducting deep riser drilling at the Nankai Trough in the final stage of the NanTroSEIZE campaign. During the years 2011 to 2013, including drilling in the Okinawa Hydrothermal System, Chikyu's operational and scientific achievements have demonstrated that the ship's capabilities are vital for opening new frontiers in earth and biological sciences.

Regolith irradiation stratigraphy at the Apollo 16 and 17 landing sites

NASA Technical Reports Server (NTRS)

Crozaz, G.

1978-01-01

Additional fossil track measurements in the Apollo 17 deep drill stem, as well as detailed track studies in section 3 of the Apollo 16 deep drill core are reported. Although the upper part of the Apollo 17 core seems to have accreted rapidly, no evidence for a rapid accretion of the lower part, as postulated by some authors, is found. Despite the apparent inhomogeneity of section 60003, its track record is unexpectedly homogeneous; all levels are heavily irradiated and emplacement of big slabs of material is not favored.

Continuous depth profile of mechanical properties in the Nankai accretionary prism based on drilling performance parameters

NASA Astrophysics Data System (ADS)

Hamada, Y.; Kitamura, M.; Yamada, Y.; Sanada, Y.; Moe, K.; Hirose, T.

2016-12-01

In-situ rock properties in/around seismogenic zone in an accretionary prism are key parameters to understand the development mechanisms of an accretionary prism, spatio-temporal variation of stress state, and so on. For the purpose of acquiring continuous-depth-profile of in-situ formation strength in an accretionary prism, here we propose the new method to evaluate the in-situ rock strength using drilling performance property. Drilling parameters are inevitably obtained by any drilling operation even in the non-coring intervals or at challenging environment where core recovery may be poor. The relationship between the rock properties and drilling parameters has been proposed by previous researches [e.g. Teale 1964]. We introduced the relationship theory of Teale [1964], and developed a converting method to estimate in-situ rock strength without depending on uncertain parameters such as weight on bit (WOB). Specifically, we first calculated equivalent specific toughness (EST) which represents gradient of the relationship between Torque energy and volume of penetration at arbitrary interval (in this study, five meters). Then the EST values were converted into strength using the drilling parameters-rock strengths correlation obtained by Karasawa et al. [2002]. This method was applied to eight drilling holes in the Site C0002 of IODP NanTroSEIZE in order to evaluate in-situ rock strength in shallow to deep accretionary prism. In the shallower part (0 - 300 mbsf), the calculated strength shows sharp increase up to 20 MPa. Then the strength has approximate constant value to 1500 mbsf without significant change even at unconformity around 1000 mbsf (boundary between forearc basin and accretionary prism). Below that depth, value of the strength gradually increases with depth up to 60 MPa at 3000 mbsf with variation between 10 and 80 MPa. Because the calculated strength is across approximately the same lithology, the increase trend can responds to the rock strength. This strength-depth curve correspond reasonably well with the strength data of core and cutting samples collected from hole C0002N and C0002P [Kitamura et al., 2016 AGU]. These results show the validity of the method evaluating in-situ strength from the drilling parameters.

Uncertainty analysis of depth predictions from seismic reflection data using Bayesian statistics

NASA Astrophysics Data System (ADS)

Michelioudakis, Dimitrios G.; Hobbs, Richard W.; Caiado, Camila C. S.

2018-06-01

Estimating the depths of target horizons from seismic reflection data is an important task in exploration geophysics. To constrain these depths we need a reliable and accurate velocity model. Here, we build an optimum 2-D seismic reflection data processing flow focused on pre-stack deghosting filters and velocity model building and apply Bayesian methods, including Gaussian process emulation and Bayesian History Matching, to estimate the uncertainties of the depths of key horizons near the Deep Sea Drilling Project (DSDP) borehole 258 (DSDP-258) located in the Mentelle Basin, southwest of Australia, and compare the results with the drilled core from that well. Following this strategy, the tie between the modelled and observed depths from DSDP-258 core was in accordance with the ±2σ posterior credibility intervals and predictions for depths to key horizons were made for the two new drill sites, adjacent to the existing borehole of the area. The probabilistic analysis allowed us to generate multiple realizations of pre-stack depth migrated images, these can be directly used to better constrain interpretation and identify potential risk at drill sites. The method will be applied to constrain the drilling targets for the upcoming International Ocean Discovery Program, leg 369.

40 CFR 146.70 - Information to be evaluated by the Director.

Code of Federal Regulations, 2010 CFR

2010-07-01

... zone. Such data shall include a description of each well's type, construction, date drilled, location... program, well materials specifications and their life expectancy, logging procedures, deviation checks, and a drilling, testing and coring program; and (17) A demonstration pursuant to part 144, subpart F...

Dead Sea deep cores: A window into past climate and seismicity

NASA Astrophysics Data System (ADS)

Stein, Mordechai; Ben-Avraham, Zvi; Goldstein, Steven L.

2011-12-01

The area surrounding the Dead Sea was the locus of humankind's migration out of Africa and thus has been the home of peoples since the Stone Age. For this reason, understanding the climate and tectonic history of the region provides valuable insight into archaeology and studies of human history and helps to gain a better picture of future climate and tectonic scenarios. The deposits at the bottom of the Dead Sea are a geological archive of the environmental conditions (e.g., rains, floods, dust storms, droughts) during ice ages and warm ages, as well as of seismic activity in this key region. An International Continental Scientific Drilling Program (ICDP) deep drilling project was performed in the Dead Sea between November 2010 and March 2011. The project was funded by the ICDP and agencies in Israel, Germany, Japan, Norway, Switzerland, and the United States. Drilling was conducted using the new Large Lake Drilling Facility (Figure 1), a barge with a drilling rig run by DOSECC, Inc. (Drilling, Observation and Sampling of the Earth's Continental Crust), a nonprofit corporation dedicated to advancing scientific drilling worldwide. The main purpose of the project was to recover a long, continuous core to provide a high resolution record of the paleoclimate, paleoenvironment, paleoseismicity, and paleomagnetism of the Dead Sea Basin. With this, scientists are beginning to piece together a record of the climate and seismic history of the Middle East during the past several hundred thousand years in millennial to decadal to annual time resolution.

The MARTE VNIR imaging spectrometer experiment: design and analysis.

PubMed

Brown, Adrian J; Sutter, Brad; Dunagan, Stephen

2008-10-01

We report on the design, operation, and data analysis methods employed on the VNIR imaging spectrometer instrument that was part of the Mars Astrobiology Research and Technology Experiment (MARTE). The imaging spectrometer is a hyperspectral scanning pushbroom device sensitive to VNIR wavelengths from 400-1000 nm. During the MARTE project, the spectrometer was deployed to the Río Tinto region of Spain. We analyzed subsets of three cores from Río Tinto using a new band modeling technique. We found most of the MARTE drill cores to contain predominantly goethite, though spatially coherent areas of hematite were identified in Core 23. We also distinguished non Fe-bearing minerals that were subsequently analyzed by X-ray diffraction (XRD) and found to be primarily muscovite. We present drill core maps that include spectra of goethite, hematite, and non Fe-bearing minerals.

The MARTE VNIR Imaging Spectrometer Experiment: Design and Analysis

NASA Astrophysics Data System (ADS)

Brown, Adrian J.; Sutter, Brad; Dunagan, Stephen

2008-10-01

We report on the design, operation, and data analysis methods employed on the VNIR imaging spectrometer instrument that was part of the Mars Astrobiology Research and Technology Experiment (MARTE). The imaging spectrometer is a hyperspectral scanning pushbroom device sensitive to VNIR wavelengths from 400-1000 nm. During the MARTE project, the spectrometer was deployed to the Río Tinto region of Spain. We analyzed subsets of three cores from Río Tinto using a new band modeling technique. We found most of the MARTE drill cores to contain predominantly goethite, though spatially coherent areas of hematite were identified in Core 23. We also distinguished non Fe-bearing minerals that were subsequently analyzed by X-ray diffraction (XRD) and found to be primarily muscovite. We present drill core maps that include spectra of goethite, hematite, and non Fe-bearing minerals.

Carbon chemistry of the Apollo 15 and 16 deep drill cores

NASA Technical Reports Server (NTRS)

Wszolek, P. C.; Burlingame, A. L.

1973-01-01

The carbon chemistry of the Apollo 15 and 16 deep drill cores is a function of the surface exposure plus the chemical and mineralogical composition of the individual samples. The depth profiles of carbide and methane yields in the Apollo 15 core show a general decline with depth and correlate with the solar wind noble gas content, percentage agglutinates, track densities, and metallic iron. All horizons examined were exposed for a considerable time on the lunar surface. The Apollo 16 core samples show that chemical and mineralogical composition plays an important role in determining the nature of carbide-like material present in the fines. The higher aluminum and calcium contents and lower iron contents of highlands material result in carbide-like material yielding less CD4 and more C2D2 (deuteroacetylene) upon DF acid dissolution.

Characterization and depositional and evolutionary history of the Apollo 17 deep drill core

NASA Technical Reports Server (NTRS)

Morris, R. V.; Lauer, H. V., Jr.; Gose, W. A.

1979-01-01

With a depth resolution of about 0.5 cm, the stratigraphy of the approximately 3 m Apollo 17 deep drill core by measurement of the total FeO concentration is characterized along with the FMR surface exposure (maturity) index Is/FeO, the metallic iron concentration Fe-vsm, and the FMR linewidth delta-H. For stratigraphic characterization, the first two parameters are the most important. Most of the core is characterized by a FeO concentration of approximately 15.5 wt. %; there is a more mafic zone in the upper approximately 75 cm where the maximum FeO concentration is approximately 18.5 wt. %, and a more felsic zone between approximately 225 and 260 cm where the minimum FeO concentration is approximately 14.0%. As indicated by Is/FeO, most of the soil in the core is submature to mature; the only immature zone is located between approximately 20 and 60 cm and is one of the most distinctive features in the core. A two stage model for the depositional and evolutionary history of the Apollo 17 deep drill core is proposed: (1) deposition by one event approximately 110 m.y. ago or deposition by a sequence of closely spaced events initating a maximum of approximately 200 m.y. ago and terminating approximately 110 m.y. ago, (2) in situ reworking (gardening) to a depth of approximately 26 cm in the period between approximately 110 m.y. ago and the present day.

Ice Core Investigations

ERIC Educational Resources Information Center

Krim, Jessica; Brody, Michael

2008-01-01

What can glaciers tell us about volcanoes and atmospheric conditions? How does this information relate to our understanding of climate change? Ice Core Investigations is an original and innovative activity that explores these types of questions. It brings together popular science issues such as research, climate change, ice core drilling, and air…

Scientific results from Gulf of Mexico Gas Hydrates Joint Industry Project Leg 1 drilling: Introduction and overview

USGS Publications Warehouse

Ruppel, C.; Boswell, R.; Jones, E.

2008-01-01

The Gulf of Mexico Gas Hydrates Joint Industry Project (JIP) is a consortium of production and service companies and some government agencies formed to address the challenges that gas hydrates pose for deepwater exploration and production. In partnership with the U.S. Department of Energy and with scientific assistance from the U.S. Geological Survey and academic partners, the JIP has focused on studies to assess hazards associated with drilling the fine-grained, hydrate-bearing sediments that dominate much of the shallow subseafloor in the deepwater (>500 m) Gulf of Mexico. In preparation for an initial drilling, logging, and coring program, the JIP sponsored a multi-year research effort that included: (a) the development of borehole stability models for hydrate-bearing sediments; (b) exhaustive laboratory measurements of the physical properties of hydrate-bearing sediments; (c) refinement of new techniques for processing industry-standard 3-D seismic data to constrain gas hydrate saturations; and (d) construction of instrumentation to measure the physical properties of sediment cores that had never been removed from in situ hydrostatic pressure conditions. Following review of potential drilling sites, the JIP launched a 35-day expedition in Spring 2005 to acquire well logs and sediment cores at sites in Atwater Valley lease blocks 13/14 and Keathley Canyon lease block 151 in the northern Gulf of Mexico minibasin province. The Keathley Canyon site has a bottom simulating reflection at ???392 m below the seafloor, while the Atwater Valley location is characterized by seafloor mounds with an underlying upwarped seismic reflection consistent with upward fluid migration and possible shoaling of the base of the gas hydrate stability (BGHS). No gas hydrate was recovered at the drill sites, but logging data, and to some extent cores, suggest the occurrence of gas hydrate in inferred coarser-grained beds and fractures, particularly between 220 and 330 m below the seafloor at the Keathley Canyon site. This paper provides an overview of the results of the initial phases of the JIP work and introduces the 15 papers that make up this special volume on the scientific results related to the 2005 logging and drilling expedition.

A ~600 kyr duration Early Pleistocene record from the West Turkana (Kenya) HSPDP drill site: elemental XRF variability to reconstruct climate change in Turkana Boy's backyard

NASA Astrophysics Data System (ADS)

Stockhecke, M.; Beck, C. C.; Brown, E. T.; Cohen, A.; Deino, A. L.; Feibel, C. S.; Sier, M.

2015-12-01

Outcrops in the Kenyan and Ethiopian rift valleys document repeated occurrences of freshwater lakes and wooded landscapes over the past 4 million years at locations that are currently seasonally-dry savanna. Studies of the rich fossil records, in combination with outcropping lacustrine sequences, led to major breakthroughs in our knowledge of driving factors in human evolution. However, study of continuous drill core from ancient lake basins provides a basis for to unravel East African climate dynamics in an unseen fashion. The Hominin Sites and Paleolakes Drilling Project (HSPDP), and the related Olorgesailie Drilling Project, recovered ~2 km of drill core since 2012. A major project goal is characterization of East African paleoclimate in order to evaluate its impact on hominin evolution. XRF core scanning data provide a means of evaluating records of past environmental conditions continuously and at high resolution. However, the HSPDP records contain complex lithologies reflecting repeated episodes of inundation and desiccation of the lake basins. Nevertheless, careful data evaluation based on detailed lithostratigraphy, which includes smear-slide microscopic analyses and X-radiographic images, allows disentanglement of complex signals and robust identification of continuous sequences for any cyclostratigraphic and statistical analysis. At the HSPDP Turkana Basin site a 175.6 m-long core the covers the Early Pleistocene time window during which hominids first expanded out of Africa and marine records document reorganization of tropical climate and the development of the strong Walker circulation. This drill site carries particular interest as it is located in only 2.5 km from the location of one of the most complete hominin skeletons ever recovered (Turkana Boy). Here we present a methodological approach to address the highly variable lithostratigraphy of the East African records to establish comprehensive and environmentally meaningful paleoclimate timeseries. In addition, the XRF record of the changing hydroclimate of the West Turkana Basin from 1.3 to 1.9 kyrs will be explored in relation to regional reconstructions and marine stratigraphies.

Late Quaternary Paleoclimatic History of Tropical South America From Drilling Lake Titicaca and the Salar de Uyuni

NASA Astrophysics Data System (ADS)

Baker, P. A.; Fritz, S. C.; Seltzer, G. O.; Rigsby, C. A.; Lowenstein, T. K.; Ku, R.

2003-12-01

Seven drill cores were recovered from Lake Titicaca during the NSF/ICDP/DOSECC drilling expedition of 2001. Sub-lake floor drilling depths ranged from 53 to 139 m; water depths ranged from 40 to 232 m; recoveries ranged from 75 to 112 percent. Our most detailed multi-proxy analyses to date have been done on Core 2B raised from the central basin of the lake from 232 m water depth, drilled to 139.26 m sub-lakefloor with 140.61 m of total sediment recovered (101 percent). A basal age of 200 Ka is estimated by linear extrapolation from radiocarbon measurements in the upper 25 m of core; Ar-Ar dating of interbedded ashes and U/Th dating of abiogenic aragonites are underway. The volume and lake level of Lake Titicaca have undergone large changes several times during the late Quaternary. Proxies for these water level changes (each of different fidelity) include the ratio of planktonic-to-benthic diatoms, sedimentary carbonate content, and stable isotopic content of organic carbon. The most recent of these changes, has been described previously from earlier piston cores. In the early and middle Holocene the lake fell below its outlet to 85 m below modern level, lake salinity increased several-fold, and the Salar de Uyuni, which receives overflow from Titicaca, dessicated. In contrast, Lake Titicaca was deep, fresh, and overflowing (southward to the Salar de Uyuni) throughout the last glacial maximum from prior to 25,000 BP to at least 15,000 BP. According to extrapolated ages, the penultimate major lowstand of Lake Titicaca occurred prior to 60,000 BP, when seismic evidence indicates that lake level was about 200 m lower than present. Near the end of this lowstand, the lake also became quite saline. There are at least three, and possibly more, older lowstands, each separated temporally by periods in which the lake freshened dramatically and overflowed. These results will be compared with results from previous drilling in the Salar de Uyuni.

Drilling Automation Demonstrations in Subsurface Exploration for Astrobiology

NASA Technical Reports Server (NTRS)

Glass, Brian; Cannon, H.; Lee, P.; Hanagud, S.; Davis, K.

2006-01-01

This project proposes to study subsurface permafrost microbial habitats at a relevant Arctic Mars-analog site (Haughton Crater, Devon Island, Canada) while developing and maturing the subsurface drilling and drilling automation technologies that will be required by post-2010 missions. It builds on earlier drilling technology projects to add permafrost and ice-drilling capabilities to 5m with a lightweight drill that will be automatically monitored and controlled in-situ. Frozen cores obtained with this drill under sterilized protocols will be used in testing three hypotheses pertaining to near-surface physical geology and ground H2O ice distribution, viewed as a habitat for microbial life in subsurface ice and ice-consolidated sediments. Automation technologies employed will demonstrate hands-off diagnostics and drill control, using novel vibrational dynamical analysis methods and model-based reasoning to monitor and identify drilling fault states before and during faults. Three field deployments, to a Mars-analog site with frozen impact crater fallback breccia, will support science goals, provide a rigorous test of drilling automation and lightweight permafrost drilling, and leverage past experience with the field site s particular logistics.

Upward extension of the Nankai accretionary prism megasplay fault into slope basin strata. Insights from drilling at IODP Expedition 338 Site C0022

NASA Astrophysics Data System (ADS)

Fabbri, O.; Oohashi, K.; Kanagawa, K.; Yamaguchi, A.

2013-12-01

Megasplay faults have been recognized on seismic reflection profiles across several convergent margins in the world. Understanding the behavior of these faults during large to very large inter-plate earthquakes is a major challenge in assessing strong-motion and tsunami hazards at or near subduction zones. One of the goals of the IODP NanTroSEIZE project is to drill across and to obtain data from the megasplay fault crossing the Nankai accretionary prism off Kii peninsula (Kumano transect), SW Japan. This fault is considered to have been activated during the 1944 Tonankai earthquake (Baba et al., 2006 ; Moore et al., 2007). Drilling and coring during IODP Expedition 316 (Expedition 316 Scientists, 2009) showed that the megasplay fault at 300 mbsf at Site C0004 consists in a 60 m thick package of fractured and brecciated rocks. Combined analysis of 3D reflection data in the vicinity of Site C0004 and core data from sites C0004 and C0008 (Strasser et al., 2009 ; Kimura et al., 2011) suggest that the lower boundary of the megasplay fault ceased activity at about 1.55 Ma while its upper boundary has remained active since about 1.95 Ma and probably 1.24 Ma. In order to determine whether the megasplay fault upper boundary crosscuts slope sediments or is sealed by them, drilling at IODP Site C0022 was carried out during Expedition 338. Two 420 m deep holes were drilled: C0022A (LWD) and C0022B (coring). At Hole C0022A, LWD resistivity images show that the 85-105.5 mbsf interval is fractured and extends above and below a ca. 1 m thick interval characterized by a low resistivity value at 100-101 mbsf. Structures observed in cores from Hole C0022B confirm LWD data. While gently dipping elsewhere, bedding in the 73-146 mbsf interval is steep, commonly exceeding 30°. This bedding dip increase may be a consequence of fault activity (folding ?). Though the low-resistivity interval at 100-101 mbsf could not be sampled at Hole C0022B (no recovery between 95.5 and 99.5 mbsf), cores immediately from above this interval show three ca. 2 cm thick zones of claystone characterized by a marked planar fabric bearing faint striations raking at about 90°. Preliminary biostratigraphic dating in Hole C0022B indicate age reversals at 80.5, 137.5 and 145.5 mbsf, suggesting reverse offset bringing older strata over younger strata. Drilling at IODP Site C0022 confirms that a branch of the megasplay fault previously cored at Expedition 316 Site C0004 extends upwards and southeastwards. The core zone of this branch lies at about 100 mbsf and is about 1 m thick. The presence of weakly foliated claystone suggests aseismic motion immediately above the core zone. The lack of samples from the core zone prevents to determine whether motion was aseismic or not.

Gas Hydrate Research Site Selection and Operational Research Plans

NASA Astrophysics Data System (ADS)

Collett, T. S.; Boswell, R. M.

2009-12-01

In recent years it has become generally accepted that gas hydrates represent a potential important future energy resource, a significant drilling and production hazard, a potential contributor to global climate change, and a controlling factor in seafloor stability and landslides. Research drilling and coring programs carried out by the Ocean Drilling Program (ODP), the Integrated Ocean Drilling Program (IODP), government agencies, and several consortia have contributed greatly to our understanding of the geologic controls on the occurrence of gas hydrates in marine and permafrost environments. For the most part, each of these field projects were built on the lessons learned from the projects that have gone before them. One of the most important factors contributing to the success of some of the more notable gas hydrate field projects has been the close alignment of project goals with the processes used to select the drill sites and to develop the project’s operational research plans. For example, IODP Expedition 311 used a transect approach to successfully constrain the overall occurrence of gas hydrate within the range of geologic environments within a marine accretionary complex. Earlier gas hydrate research drilling, including IODP Leg 164, were designed primarily to assess the occurrence and nature of marine gas hydrate systems, and relied largely on the presence of anomalous seismic features, including bottom-simulating reflectors and “blanking zones”. While these projects were extremely successful, expeditions today are being increasingly mounted with the primary goal of prospecting for potential gas hydrate production targets, and site selection processes designed to specifically seek out anomalously high-concentrations of gas hydrate are needed. This approach was best demonstrated in a recently completed energy resource focused project, the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II (GOM JIP Leg II), which featured the collection of a comprehensive set of logging-while-drilling (LWD) data through expected gas-hydrate-bearing sand reservoirs in seven wells at three sites in the Gulf of Mexico. The discovery of thick hydrate-bearing sands at two of the sites drilled in the Gulf Mexico validated the integrated geological and geophysical approach used in the pre-drill site selection process to identify gas hydrate reservoirs that may be conducive to energy production. The results of the GOM JIP Leg II LWD expedition are also being used to support the selection of sites for a future drilling, logging, and coring program. Operationally, recent drilling programs, such as ODP Leg 204, IODP Expedition 311, the Japanese Toaki-oki to Kumano-nada drilling leg, the Indian NGHP Expedition 01, and the South Korean Gas Hydrate Research and Development Organization Expedition 01 have demonstrated the great benefit of a multi-leg drilling approach, including the initial acquisition of LWD data that was used to then select sites for the drilling of complex core and wireline logging test holes. It is obvious that a fully integrated site selection approach and a “goal based” operational plan, possibly including numerous drill sites and drilling legs, are required considerations for any future gas hydrate research project.

Structure and energetics of Cr(CO)6 and Cr(CO)5

NASA Technical Reports Server (NTRS)

Barnes, Leslie A.; Liu, Bowen; Lindh, Roland

1993-01-01

The geometric structures and energetics of Cr(CO)6 and Cr(CO)5 are determined at the modified coupled-pair functional, single and double excitation coupled-cluster (CCSD), and CCSD(T) levels of theory. For Cr(CO)6, the structure and force constants for the totally symmetric representation are in good agreement with experimental data once basis set constants are taken into account. In the largest basis set at the CCSD(T) level of theory, the total binding energy of CR(CO)6 is estimated at around 140 kcal/mol, or about 86 percent of the experimental value. In contrast, the first bond energy of Cr(CO)6 is very well described at the CCSD(T) level of theory, with the best estimated value of 38 kcal/mol being within the experimental uncertainty.

Fractography applied to investigations of cores, outcrops, and fractured reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulander, B.

1995-11-01

Fractography focuses investigations on the topography of fracture surfaces. This topography is composed of fractographic features produced by changing stress magnitudes and directions along the advancing crack tip. Fractographic features commonly useful in core and outcrop analysis include the origin, twist hackle, inclusion hackle, and rib marks. These structures develop during brittle failure by Mode I loading at the crack tip and act together to form a hackle plume. Fractographic components throughout the plume record the dynamic history of fracture development. Components show, to the limit of visual scale, the principal stress directions, as well as relative stress magnitudes andmore » propagation velocities, that existed at the advancing fracture front. This information contributes to more meaningful conclusions in fracture investigations. In core studies, fractography aids identification of induced and natural fractures. Induced fractures and fractographic features show distinct geometry with that of the core and reflect the effects of the core boundary, in-situ stresses, drilling stresses, and rock anisotropies. Certain drilling- and coring-induced fractures possess orientations and fractographic features that suggest the direction of minimum in-situ stress and that this direction may change abruptly within the drilled volume of rock. Cored natural fractures generally originated away from the bit and possess fractographic features that bear no geometerical relationship to core parameters. Abrupt changes of natural fracture strike and development of twist hackle suggest locally complex paleostress distributions. A combined knowledge of in-situ stress and natural fracture trends is useful in predicting reservoir permeability. In outcrop, fractographic features, including abutting relationships between joints, more readily depict order of development, intrastratum distribution of fracturing stress, and size for joints in any set.« less

Neogene sea surface temperature reconstructions from the Southern McMurdo Sound and the McMurdo Ice Shelf (ANDRILL Program, Antarctica)

NASA Astrophysics Data System (ADS)

Sangiorgi, Francesca; Willmott, Veronica; Kim, Jung-Hyun; Schouten, Stefan; Brinkhuis, Henk; Sinninghe Damsté, Jaap S.; Florindo, Fabio; Harwood, David; Naish, Tim; Powell, Ross

2010-05-01

During the austral summers 2006 and 2007 the ANtarctic DRILLing Program (ANDRILL) drilled two cores, each recovering more than 1000m of sediment from below the McMurdo Ice-Shelf (MIS, AND-1B), and sea-ice in Southern McMurdo Sound (SMS, AND-2A), respectively, revealing new information about Neogene Antarctic cryosphere evolution. Core AND-1B was drilled in a more distal location than core AND-2A. With the aim of obtaining important information for the understanding of the history of Antarctic climate and environment during selected interval of the Neogene, we applied novel organic geochemistry proxies such as TEX86 (Tetra Ether IndeX of lipids with 86 carbon atoms) using a new calibration equation specifically developed for polar areas and based on 116 surface sediment samples collected from polar oceans (Kim et al., subm.), and BIT (Branched and Isoprenoid Tetraether), to derive absolute (sea surface) temperature values and to evaluate the relative contribution of soil organic matter versus marine organic matter, respectively. We will present the state-of-the-art of the methodology applied, discussing its advantages and limitations, and the results so far obtained from the analysis of 60 samples from core AND-2A covering the Miocene Climatic Optimum (and the Mid-late Miocene transition) and of 20 pilot samples from core AND-1B covering the late Pliocene.

Hydrogeologic data from a 2,000-foot deep core hole at Polk City, Green Swamp area, central Florida

USGS Publications Warehouse

Navoy, A.S.

1986-01-01

Two core holes were drilled to depths of 906 and 1,996 feet, respectively, within the Tertiary limestone (Floridan) aquifers, at Polk City, central Florida. Data from the two holes revealed that the bottom of the zone of vigorous groundwater circulation is confined by carbonate rocks at a depth of about 1,000 feet (863 feet below sea level). The zone of circulation is divided into two high-permeability zones. The dissolved solids of the water within the high-permeability zones is approximately 150 milligrams per liter. Within the carbonate rocks, the dissolved solids content of the water reaches about 2,000 milligrams per liter at the bottom of the core hole. Water levels in the core holes declined a total of about 16 feet as the hole was drilled; most of the head loss occurred at depths below 1,800 feet. The porosities of selected cores ranged from 1.6 to 45.3 percent; the hydraulic conductivities ranged from less than 0.000024 to 19.0786 feet per day in the horizontal direction and from less than 0.000024 to 2.99 feet per day in the vertical direction; and the ratio of vertical to horizontal permeability ranged from 0.03 to 1.98. Due to drilling problems, packer tests and geophysical logging could not be accomplished. (USGS)

High-resolution gamma ray attenuation density measurements on mining exploration drill cores, including cut cores

NASA Astrophysics Data System (ADS)

Ross, P.-S.; Bourke, A.

2017-01-01

Physical property measurements are increasingly important in mining exploration. For density determinations on rocks, one method applicable on exploration drill cores relies on gamma ray attenuation. This non-destructive method is ideal because each measurement takes only 10 s, making it suitable for high-resolution logging. However calibration has been problematic. In this paper we present new empirical, site-specific correction equations for whole NQ and BQ cores. The corrections force back the gamma densities to the "true" values established by the immersion method. For the NQ core caliber, the density range extends to high values (massive pyrite, 5 g/cm3) and the correction is thought to be very robust. We also present additional empirical correction factors for cut cores which take into account the missing material. These "cut core correction factors", which are not site-specific, were established by making gamma density measurements on truncated aluminum cylinders of various residual thicknesses. Finally we show two examples of application for the Abitibi Greenstone Belt in Canada. The gamma ray attenuation measurement system is part of a multi-sensor core logger which also determines magnetic susceptibility, geochemistry and mineralogy on rock cores, and performs line-scan imaging.

Development of Next-Generation Borehole Magnetometer and Its Potential Application in Constraining the Magnetic Declination of Oman Samail Ophiolite at ICDP Drill Sites

NASA Astrophysics Data System (ADS)

Lee, S. M.; Parq, J. H.; Kim, H.; Moe, K.; Lee, C. S.; Kanamatsu, T.; Kim, K. J.; Bahk, K. S.

2017-12-01

Determining the azimuthal orientation of core samples obtained from deep drilling is extremely difficult because the core itself could have rotated during drilling operations. Several indirect methods have been devised to address this issue, but have certain limitations. Thus it is still a challenge to determine the azimuthal orientation consistently over the entire length of the hole. Provided that the recovery rate is high and thus all the other magnetic properties such as magnetization intensity and inclination are measured from the recovered cores, one possible method for ascertaining magnetic declination information is to measure the magnetic field inside the empty borehole and invert for the best fitting declination. However, there are two major problems: one is that present-day borehole magnetometers are not precise enough to resolve changes in direction of magnetization, and the other is that in most rock drilling experiments the rate of recovery is low. To overcome the first major problem which is technical, scientists from Korea and Japan jointly conducted the development for the next-generation borehole magnetometer, namely 3GBM (3rd Generation Borehole Magnetometer). The borehole magnetometer which uses fiber-optic laser gyro promises to provide accurate information on not only the magnetic field itself but also the orientation of the instrument inside the borehole. Our goal is to deploy this borehole magnetometer in the ICDP Oman Drilling Project Phase 2 drilling experiment early 2018. The site may be suitable for the investigation because, as recent Phase 1 of the Oman Samail Ophiolite drilling has demonstrated, the recovery rate was very high. Also the post-drilling measurements onboard DV Chikyu have shown that much of the recovered samples has moderate magnetization intensity on the order of 0.1 and 1 A/m. Here, we present the results of numerical simulation of magnetic field inside the borehole using finite element method to show that magnetic declination may be obtained systematically from the top to the bottom of the holes. The results will help us to fine tune the magnetometer before the actual deployment. It will also be useful in interpreting the obtained results together with resistivity images from conventional wireline logging and post-drilling paleomagnetic lab measurements results.

Ocean Drilling Simulation Activity.

ERIC Educational Resources Information Center

Telese, James A.; Jordan, Kathy

The Ocean Drilling Project brings together scientists and governments from 20 countries to explore the earth's structure and history as it is revealed beneath the oceans' basins. Scientific expeditions examine rock and sediment cores obtained from the ocean floor to learn about the earth's basic processes. The series of activities in this…

Fluid inclusions and preliminary studies of hydrothermal alteration in core hole PLTG-1, Platanares geothermal area, Honduras

USGS Publications Warehouse

Bargar, K.E.

1991-01-01

The Platanares geothermal area in western Honduras consists of more than 100 hot springs that issue from numerous hot-spring groups along the banks or within the streambed of the Quebrada de Agua Caliente (brook of hot water). Evaluation of this geothermal area included drilling a 650-m deep PLTG-1 drill hole which penetrated a surface mantling of stream terrace deposits, about 550 m of Tertiary andesitic lava flows, and Cretaceous to lower Tertiary sedimentary rocks in the lower 90 m of the drill core. Fractures and cavities in the drill core are partly to completely filled by hydrothermal minerals that include quartz, kaolinite, mixed-layer illite-smectite, barite, fluorite, chlorite, calcite, laumontite, biotite, hematite, marcasite, pyrite, arsenopyrite, stibnite, and sphalerite; the most common open-space fillings are calcite and quartz. Biotite from 138.9-m depth, dated at 37.41 Ma by replicate 40Ar/39 Ar analyses using a continuous laser system, is the earliest hydrothermal mineral deposited in the PLTG-1 drill core. This mid-Tertiary age indicates that at least some of the hydrothermal alteration encountered in the PLTG-1 drill core occured in the distant past and is unrelated to the present geothermal system. Furthermore, homogenization temperatures (Th) and melting-point temperatures (Tm) for fluid inclusions in two of the later-formed hydrothermal minerals, calcite and barite, suggest that the temperatures and concentration of dissolved solids of the fluids present at the time these fluid inclusions formed were very different from the present temperatures and fluid chemistry measured in the drill hole. Liquid-rich secondary fluid inclusions in barite and caicite from drill hole PLTG-1 have Th values that range from about 20??C less than the present measured temperature curve at 590.1-m depth to as much as 90??C higher than the temperature curve at 46.75-m depth. Many of the barite Th measurements (ranging between 114?? and 265??C) plot above the reference surface boiling-point curve for pure water assuming hydrostatic conditions; however, the absence of evidence for boiling in the fluid inclusions indicates that at the time the minerals formed, the ground surface must have been at least 80 m higher than at present and underwent stream erosion to the current elevation. Near-surface mixed-layer illite-smectite is closely associated with barite and appears to have formed at about the same temperature range (about 120?? to 200??C) as the fluid-inclusion Th values for barite. Fluid-inclusion Th values for calcite range between about 136?? and 213??C. Several of the calcite Th values are significantly lower than the present measured temperature curve. The melting-point temperatures (Tm) of fluid-inclusion ice yield calculated salinities, ranging from near zero to as much as 5.4 wt. % NaCl equivalent, which suggest that much of the barite and calcite precipitated from fluids of significantly greater salinity than the present low salinity Platanares hot-spring water or water produced from the drill hole. ?? 1991.

Innovative hyperspectral imaging (HSI) based techniques applied to end-of-life concrete drill core characterization for optimal dismantling and materials recovery

NASA Astrophysics Data System (ADS)

Bonifazi, Giuseppe; Picone, Nicoletta; Serranti, Silvia

2015-02-01

The reduction of EOL concrete disposal in landfills, together with a lower exploitation of primary raw materials, generates a strong interest to develop, set-up and apply innovative technologies to maximize Construction and Demolition Waste (C&DW) conversion into useful secondary raw materials. Such a goal can be reached starting from a punctual in-situ efficient characterization of the objects to dismantle in order to develop demolition actions aimed to set up innovative mechanical-physical processes to recover the different materials and products to recycle. In this paper an innovative recycling-oriented characterization strategy based on HyperSpectral Imaging (HSI) is described in order to identify aggregates and mortar in drill core samples from end-of-life concrete. To reach this goal, concrete drill cores from a demolition site were systematically investigated by HSI in the short wave infrared field (1000-2500 nm). Results obtained by the adoption of the HSI approach showed as this technology can be successfully applied to analyze quality and characteristics of C&DW before dismantling and as final product to reutilise after demolition-milling-classification actions. The proposed technique and the related recognition logics, through the spectral signature detection of finite physical domains (i.e. concrete slice and/or particle) of different nature and composition, allows; i) to develop characterization procedures able to quantitatively assess end-of-life concrete compositional/textural characteristics and ii) to set up innovative sorting strategies to qualify the different materials constituting drill core samples.

Publications - GMC 391 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 391 Publication Details Title: Core descriptions, photographs and thin section photomicro , Inc., 2010, Core descriptions, photographs and thin section photomicro-graphs from the Humble Oil DDH DVD. Keywords Core Drilling; Thin Section Top of Page Department of Natural Resources, Division of

Why Drill Here? Teaching to Build Student Understanding of the Role Sediment Cores from Polar Regions play in Interpreting Climate Change

NASA Astrophysics Data System (ADS)

Pound, K. S.; St. John, K.; Krissek, L. A.; Jones, M. H.; Leckie, R. M.; Pyle, E. J.

2008-12-01

That the ocean basins provide a record of past global climate changes through their sediment cores is often a surprise or novel idea for students. Equally surprising to many students is the fact that current research is being undertaken in remote polar regions, even though sedimentary records already exist from the low and mid latitude regions. Students are often also perplexed about how decisions are made regarding the selection of drill sites in the polar regions. Using an inquiry-based approach we are developing a series of simple exercises that are scaffolded to build student understanding around the question "Why Drill Here?" The exercises are based on IODP Expedition 302 (ACEX) in the Arctic, and on the Antarctic Geological Drilling (ANDRILL) program, which are used as case studies. The "Why Drill Here?" question is addressed at multiple levels so students can formulate a scientific rationale behind selection of sites for seafloor drilling in the Arctic and Antarctic regions. Technological challenges and solutions to doing field-based science in polar regions are explored. Finally, a subset of research results are investigated and compared with the current scientific paradigm on Cenozoic climate evolution to demonstrate that science is an evolving process. These exercises can be adapted for use in a variety of Introductory Earth Science classes.

Subsurface sediment contamination during borehole drilling with an air-actuated down-hole hammer.

PubMed

Malard, Florian; Datry, Thibault; Gibert, Janine

2005-10-01

Drilling methods can severely alter physical, chemical, and biological properties of aquifers, thereby influencing the reliability of water samples collected from groundwater monitoring wells. Because of their fast drilling rate, air-actuated hammers are increasingly used for the installation of groundwater monitoring wells in unconsolidated sediments. However, oil entrained in the air stream to lubricate the hammer-actuating device can contaminate subsurface sediments. Concentrations of total hydrocarbons, heavy metals (Cu, Ni, Cr, Zn, Pb, and Cd), and nutrients (particulate organic carbon, nitrogen, and phosphorus) were measured in continuous sediment cores recovered during the completion of a 26-m deep borehole drilled with a down-hole hammer in glaciofluvial deposits. Total hydrocarbons, Cu, Ni, Cr and particulate organic carbon (POC) were all measured at concentrations far exceeding background levels in most sediment cores. Hydrocarbon concentration averaged 124 +/- 118 mg kg(-1) dry sediment (n = 78 samples) with peaks at depths of 8, 14, and 20 m below the soil surface (maximum concentration: 606 mg kg(-1)). The concentrations of hydrocarbons, Cu, Ni, Cr, and POC were positively correlated and exhibited a highly irregular vertical pattern, that probably reflected variations in air loss within glaciofluvial deposits during drilling. Because the penetration of contaminated air into the formation is unpreventable, the representativeness of groundwater samples collected may be questioned. It is concluded that air percussion drilling has strong limitations for well installation in groundwater quality monitoring surveys.

The determination of accurate dipole polarizabilities alpha and gamma for the noble gases

NASA Technical Reports Server (NTRS)

Rice, Julia E.; Taylor, Peter R.; Lee, Timothy J.; Almloef, Jan

1989-01-01

The static dipole polarizabilities alpha and gamma for the noble gases helium through xenon were determined using large flexible one-particle basis sets in conjunction with high-level treatments of electron correlation. The electron correlation methods include single and double excitation coupled-cluster theory (CCSD), an extension of CCSD that includes a perturbational estimate of connected triple excitations, CCSD(T), and second order perturbation theory (MP2). The computed alpha and gamma values are estimated to be accurate to within a few percent. Agreement with experimental data for the static hyperpolarizability gamma is good for neon and xenon, but for argon and krypton the differences are larger than the combined theoretical and experimental uncertainties. Based on our calculations, we suggest that the experimental value of gamma for argon is too low; adjusting this value would bring the experimental value of gamma for krypton into better agreement with our computed result. The MP2 values for the polarizabilities of neon, argon, krypton and zenon are in reasonabe agreement with the CCSD and CCSD(T) values, suggesting that this less expensive method may be useful in studies of polarizabilities for larger systems.

Concepts and Benefits of Lunar Core Drilling

NASA Technical Reports Server (NTRS)

McNamara, K. M.; Bogard, D. D.; Derkowski, B. J.; George, J. A.; Askew, R. S.; Lindsay, J. F.

2007-01-01

Understanding lunar material at depth is critical to nearly every aspect of NASA s Vision and Strategic Plan. As we consider sending human s back to the Moon for brief and extended periods, we will need to utilize lunar materials in construction, for resource extraction, and for radiation shielding and protection. In each case, we will be working with materials at some depth beneath the surface. Understanding the properties of that material is critical, thus the need for Lunar core drilling capability. Of course, the science benefit from returning core samples and operating down-hole autonomous experiments is a key element of Lunar missions as defined by NASA s Exploration Systems Architecture Study. Lunar missions will be targeted to answer specific questions concerning lunar science and re-sources.

Demonstrations of Gravity-Independent Mobility and Drilling on Natural Rock using Microspines

NASA Technical Reports Server (NTRS)

Parness, Aaron; Frost, Matthew; King, Jonathan P.; Thatte, Nitish

2012-01-01

The video presents microspine-based anchors be ing developed for gripping rocks on the surfaces of comets and asteroids, or for use on cliff faces and lava tubes on Mars. Two types of anchor prototypes are shown on supporting forces in all directions away from the rock; >160 N tangent, >150 N at 45?, and >180 N normal to the surface of the rock. A compliant robotic ankle with two active degrees of freedom interfaces these anchors to the Lemur IIB robot for future climbing trials. Finally, a rotary percussive drill is shown coring into rock regardless of gravitational orientation. As a harder- than-zero-g proof of concept, inverted drilling was performed creating 20mm diameter boreholes 83 mm deep in vesicular basalt samples while retaining 12 mm diameter rock cores in 3-6 pieces.

Miocene Antarctic ice dynamics in the Ross Embayment (Western Ross Sea, Antarctica): Insights from provenance analyses of sedimentary clasts in the AND-2A drill core

NASA Astrophysics Data System (ADS)

Cornamusini, Gianluca; Talarico, Franco M.

2016-11-01

A detailed study of gravel-size sedimentary clasts in the ANDRILL-2A (AND-2A) drill core reveals distinct changes in provenance and allows reconstructions to be produced of the paleo ice flow in the McMurdo Sound region (Ross Sea) from the Early Miocene to the Holocene. The sedimentary clasts in AND-2A are divided into seven distinct petrofacies. A comparison of these with potential source rocks from the Transantarctic Mountains and the coastal Southern Victoria Land suggests that the majority of the sedimentary clasts were derived from formations within the Devonian-Triassic Beacon Supergroup. The siliciclastic-carbonate petrofacies are similar to the fossiliferous erratics found in the Quaternary Moraine in the southern McMurdo Sound and were probably sourced from Eocene strata that are currently hidden beneath the Ross Ice Shelf. Intraformational clasts were almost certainly reworked from diamictite and mudstone sequences that were originally deposited proximal to the drill site. The distribution of sedimentary gravel clasts in AND-2A suggests that sedimentary sequences in the drill core were deposited under two main glacial scenarios: 1) a highly dynamic ice sheet that did not extend beyond the coastal margin and produced abundant debris-rich icebergs from outlet glaciers in the central Transantarctic Mountains and South Victoria Land; 2) and an ice sheet that extended well beyond the coastal margin and periodically advanced across the Ross Embayment. Glacial scenario 1 dominated the early to mid-Miocene (between ca. 1000 and 225 mbsf in AND-2A) and scenario 2 the early Miocene (between ca. 1138 and 1000 mbsf) and late Neogene to Holocene (above ca. 225 mbsf). This study augments previous research on the clast provenance and highlights the added value that sedimentary clasts offer in terms of reconstructing past glacial conditions from Antarctic drill core records.

A discontinuous melt sheet in the Manson impact structure

NASA Technical Reports Server (NTRS)

Izett, G. A.; Reynolds, R. L.; Rosenbaum, J. G.; Nishi, J. M.

1993-01-01

Petrologic studies of the core recovered from holes drilled in the Manson, Iowa, buried impact structure may unravel the thermal history of the crater-fill debris. We made a cursory examination of about 200 m of core recovered from the M-1 bore hole. The M-1 bore hole was the first of 12 holes drilled as part of a cooperative drilling program between the U.S. Geological Survey and the Iowa Geological Survey Bureau. The M-1 core hole is about 6 km northeast of the center of the impact structure, apparently on the flank of its central peak. We developed a working hypothesis that a 30-m-thick breccia unit within a 53-m-thick unit previously termed the 'crystalline clast breccia with glassy matrix' is part of a discontinuous melt sheet in the crater-fill impact debris. The 30-m-thick breccia unit reached temperatures sufficient to partially melt some small breccia clasts and convert the fine-grained breccia matrix into a silicate melt that cooled to a greenish-black, flinty, microcrystalline rock. The results of the investigation of this unit are presented.

High Resolution Mineral Mapping of the Oman Drilling Project Cores with Imaging Spectroscopy: Preliminary Results

NASA Astrophysics Data System (ADS)

Greenberger, R. N.; Ehlmann, B. L.; Kelemen, P. B.; Manning, C. E.; Teagle, D. A. H.; Harris, M.; Michibayashi, K.; Takazawa, E.

2017-12-01

The Oman Drilling Project provides an unprecedented opportunity to study the formation and alteration of oceanic crust and peridotite. Key to answering the main questions of the project are a characterization of the primary and secondary minerals present within the drill core and their spatial relationships. To that end, we used the Caltech imaging spectrometer system to scan the entire 1.5-km archive half of the core from all four gabbro and listvenite boreholes (GT1A, GT2A, GT3A, and BT1B) at 250 µm/pixel aboard the JAMSTEC Drilling Vessel Chikyu during the ChikyuOman core description campaign. The instrument measures the visible and shortwave infrared reflectance spectra of the rocks as a function of wavelength from 0.4 to 2.6 µm. This wavelength range is sensitive to many mineral groups, including hydrated minerals (phyllosilicates, zeolites, amorphous silica polytypes), carbonates, sulfates, and transition metals, most commonly iron-bearing mineralogies. To complete the measurements, the core was illuminated with a halogen light source and moved below the spectrometer at 1 cm/s by the Chikyu's Geotek track. Data are corrected and processed to reflectance using measurements of dark current and a spectralon calibration panel. The data provide a unique view of the mineralogy at high spatial resolution. Analysis of the images for complete downhole trends is ongoing. Thus far, a variety of minerals have been identified within their petrologic contexts, including but not limited to magnesite, dolomite, calcite, quartz (through an Si-OH absorption due to minor H2O), serpentine, chlorite, epidote, zeolites, mica (fuchsite), kaolinite, prehnite, gypsum, amphibole, and iron oxides. Further analysis will likely identify more minerals. Results include rapidly distinguishing the cations present within carbonate minerals and identifying minerals of volumetrically-low abundance within the matrix and veins of core samples. This technique, for example, accurately identifies mm-thick dolomite or calcite veins among dense sets of magnesite veins in the listvenite, indicating cross-cutting relationships that reflect changing alteration conditions with time. It also highlights key zones for sampling and additional analyses. Further data processing will provide mineralogical maps of the full 1.5 km of core.

Rescuing the Cahoon Mine drill cores: Opportunities for modern mapping of the ca. 1.7 Ga Freedom Formation in southern Wisconsin

NASA Astrophysics Data System (ADS)

Stanley, V.; Stewart, E.

2016-12-01

Rock cores collected during historic mineral exploration can provide invaluable data for modern analyses, but only if the samples are properly curated. The Cahoon Mine operated in Baraboo, WI during the 1910's and produced iron ore from the ca. 1.7 Ga Freedom Formation. The Freedom Formation is part of the well-known Baraboo-interval stratigraphy and is only present in the subsurface of Wisconsin (Weidman, 1904). Seventeen exploratory drill cores were rescued by Wisconsin Geological and Natural History Survey (WGNHS) from the original drying house at the mine site. The condition of the containers endangered the stratigraphic context of the collection; identifiers and depth markings were often obscured or lost. The individual core pieces were coated in residue and dust. Most of what is known about the Freedom Formation is from core logs and master's theses from the early 1900's (Leith, 1935; Schmidt, 1951). Ongoing subsurface mapping of the Baraboo-interval sediments and underlying basement of southern Wisconsin integrates new and existing subsurface and regional geophysical datasets. Mapping involves calibrating unique signals in regional aeromagnetic data to known lithology from drill core and cuttings. The Freedom Formation is especially important in this process as its iron-rich composition and regional continuity causes it to have a somewhat unique signal in regional aeromagnetic data. The Cahoon Mine cores in the WGNHS repository are the most extensive collection of physical samples from the Freedom Formation still in existence. We are in the process of curating the cores to facilitate their use in ongoing bedrock mapping. Today the cost and logistics of extensive sampling of this unit makes the existing core collection irreplaceable. We transferred the material to new containers, digitally recorded metadata, and created archival labels. As a result of this effort, the Cahoon Mine cores are now stored in a format that is physically and digitally accessible.

A second-order multi-reference perturbation method for molecular vibrations

NASA Astrophysics Data System (ADS)

Mizukami, Wataru; Tew, David P.

2013-11-01

We present a general multi-reference framework for treating strong correlation in vibrational structure theory, which we denote the vibrational active space self-consistent field (VASSCF) approach. Active configurations can be selected according to excitation level or the degrees of freedom involved, or both. We introduce a novel state-specific second-order multi-configurational perturbation correction that accounts for the remaining weak correlation between the vibrational modes. The resulting VASPT2 method is capable of accurately and efficiently treating strong correlation in the form of large anharmonic couplings, at the same time as correctly resolving resonances between states. These methods have been implemented in our new dynamics package DYNAMOL, which can currently treat up to four-body Hamiltonian coupling terms. We present a pilot application of the VASPT2 method to the trans isomer of formic acid. We have constructed a new analytic potential that reproduces frozen core CCSD(T)(F12*)/cc-pVDZ-F12 energies to within 0.25% RMSD over the energy range 0-15 000 cm-1. The computed VASPT2 fundamental transition energies are accurate to within 9 cm-1 RMSD from experimental values, which is close to the accuracy one can expect from a CCSD(T) potential energy surface.

Precision of computer-assisted core decompression drilling of the femoral head.

PubMed

Beckmann, J; Goetz, J; Baethis, H; Kalteis, T; Grifka, J; Perlick, L

2006-08-01

Osteonecrosis of the femoral head is a local destructive disease with progression into devastating stages. Left untreated it mostly leads to severe secondary osteoarthrosis and early endoprosthetic joint replacement. Core decompression by exact drilling into the ischemic areas can be performed in early stages according to Ficat or ARCO. Computer-aided surgery might enhance the precision of the drilling and lower the radiation exposure time of both staff and patients. The aim of this study was to evaluate the precision of the fluoroscopically based VectorVision navigation system in an in vitro model. Thirty sawbones were prepared with a defect filled up with a radiopaque gypsum sphere mimicking the osteonecrosis. Twenty sawbones were drilled by guidance of an intraoperative navigation system VectorVision (BrainLAB, Munich, Germany) and 10 sawbones by fluoroscopic control only. No gypsum sphere was missed. There was a statistically significant difference regarding the three-dimensional deviation (Euclidian norm) as well as maximum deviation in x-, y- or z-direction (maximum norm) to the desired mid-point of the lesion, with a mean of 0.51 and 0.4 mm in the navigated group and 1.1 and 0.88 mm in the control group, respectively. Furthermore, significant difference was found in the number of drilling corrections as well as the radiation time needed: no second drilling or correction of drilling direction was necessary in the navigated group compared to 1.4 in the control group. The radiation time needed was less than 1 s compared to 3.1 s, respectively. The fluoroscopy-based VectorVision navigation system shows a high feasibility of computer-guided drilling with a clear reduction of radiation exposure time and can therefore be integrated into clinical routine. The additional time needed is acceptable regarding the simultaneous reduction of radiation time.

Partially linearized external models to active-space coupled-cluster through connected hextuple excitations.

PubMed

Xu, Enhua; Ten-No, Seiichiro L

2018-06-05

Partially linearized external models to active-space coupled-cluster through hextuple excitations, for example, CC{SDtqph} L , CCSD{tqph} L , and CCSD{tqph} hyb, are implemented and compared with the full active-space CCSDtqph. The computational scaling of CCSDtqph coincides with that for the standard coupled-cluster singles and doubles (CCSD), yet with a much large prefactor. The approximate schemes to linearize the external excitations higher than doubles are significantly cheaper than the full CCSDtqph model. These models are applied to investigate the bond dissociation energies of diatomic molecules (HF, F 2 , CuH, and CuF), and the potential energy surfaces of the bond dissociation processes of HF, CuH, H 2 O, and C 2 H 4 . Among the approximate models, CCSD{tqph} hyb provides very accurate descriptions compared with CCSDtqph for all of the tested systems. © 2018 Wiley Periodicals, Inc. © 2018 Wiley Periodicals, Inc.

Future scientific drilling in the Arctic Ocean: Key objectives, areas, and strategies

NASA Astrophysics Data System (ADS)

Stein, R.; Coakley, B.; Mikkelsen, N.; O'Regan, M.; Ruppel, C.

2012-04-01

In spite of the critical role of the Arctic Ocean in climate evolution, our understanding of the short- and long-term paleoceanographic and paleoclimatic history through late Mesozoic-Cenozoic times, as well as its plate-tectonic evolution, remains behind that from the other world's oceans. This lack of knowledge is mainly caused by the major technological/logistic problems in reaching this permanently ice-covered region with normal research vessels and in retrieving long and undisturbed sediment cores. With the Arctic Coring Expedition - ACEX (or IODP Expedition 302), the first Mission Specific Platform (MSP) expedition within IODP, a new era in Arctic research began (Backman, Moran, Mayer, McInroy et al., 2006). ACEX proved that, with an intensive ice-management strategy, successful scientific drilling in the permanently ice-covered central Arctic Ocean is possible. ACEX is certainly a milestone in Arctic Ocean research, but - of course - further drilling activities are needed in this poorly studied ocean. Furthermore, despite the success of ACEX fundamental questions related to the long- and short-term climate history of the Arctic Ocean during Mesozoic-Cenozoic times remain unanswered. This is partly due to poor core recovery during ACEX and, especially, because of a major mid-Cenozoic hiatus in this single record. Since ACEX, a series of workshops were held to develop a scientific drilling strategy for investigating the tectonic and paleoceanographic history of the Arctic Ocean and its role in influencing the global climate system: - "Arctic Ocean History: From Speculation to Reality" (Bremerhaven/Germany, November 2008); - "Overcoming barriers to Arctic Ocean scientific drilling: the site survey challenge" (Copenhagen/Denmark, November 2011); - Circum-Arctic shelf/upper continental slope scientific drilling workshop on "Catching Climate Change in Progress" (San Francisco/USA, December 2011); - "Coordinated Scientific Drilling in the Beaufort Sea: Addressing Past, Present and Future Changes in Arctic Terrestrial and Marine Systems" (Kananaskis, Alberta/Canada, February 2012). During these workshops, key areas and key scientific themes as well as drilling and site-survey strategies were discussed. Major scientific themes for future Arctic drilling will include: - The Arctic Ocean during the transition from greenhouse to icehouse conditions and millennial scale climate changes; - Physical and chemical changes of the evolving Polar Ocean and Arctic gateways; - Impact of Pleistocene/Holocene warming and sea-level rise on upper continental slope and shelf gas hydrates and on shelf permafrost; - Land-ocean interactions; - Tectonic evolution and birth of the Arctic Ocean basin: Arctic ridges, sea floor spreading and global lithosphere processes. When thinking about future Arctic drilling, it should be clearly emphasized that for the precise planning of future Arctic Ocean drilling campaigns, including site selection, evaluation of proposed drill sites for safety and environmental protection, etc., comprehensive site survey data are needed first. This means that the development of a detailed site survey strategy is a major challenge for the coming years. Here, an overview of perspectives and plans for future Arctic Ocean drilling will be presented.

Deep Drilling and Sampling via the Wireline Auto-Gopher Driven by Piezoelectric Percussive Actuator and EM Rotary Motor

NASA Technical Reports Server (NTRS)

Bar-Cohen, Yoseph; Badescu, Mircea; Sherrit, Stewart; Zacny, Kris; Paulsen, Gale L; Beegle, Luther; Bao, Xiaoqi

2012-01-01

The ability to penetrate subsurfaces and perform sample acquisition at depths of meters is critical for future NASA in-situ exploration missions to bodies in the solar system, including Mars and Europa. A corer/sampler was developed with the goal of acquiring pristine samples by reaching depths on Mars beyond the oxidized and sterilized zone. To developed rotary-hammering coring drill, called Auto-Gopher, employs a piezoelectric actuated percussive mechanism for breaking formations and an electric motor rotates the bit to remove the powdered cuttings. This sampler is a wireline mechanism that is incorporated with an inchworm mechanism allowing thru cyclic coring and core removal to reach great depths. The penetration rate is being optimized by simultaneously activating the percussive and rotary motions of the Auto-Gopher. The percussive mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) mechanism that is driven by piezoelectric stack and that was demonstrated to require low axial preload. The Auto-Gopher has been produced taking into account the a lessons learned from the development of the Ultrasonic/Sonic Gopher that was designed as a percussive ice drill and was demonstrated in Antarctica in 2005 to reach about 2 meters deep. A field demonstration of the Auto-Gopher is currently being planned with objective of reaching as deep as 3 to 5 meters in tufa subsurface.

Remanent magnetization stratigraphy of lunar cores

NASA Technical Reports Server (NTRS)

Banerjee, S. K.; Gingrich, D.; Marvin, J. A.

1977-01-01

Depth dependent fluctuations have been observed in the natural remanent magnetizations (NRM) of drive cores and drill strings from Apollo 16 and 17 missions. Partial demagnetization of unstable secondary magnetizations and identification of characteristic error signals from a core which is known to have been recently disturbed allow us to identify and isolate the stable NRM stratigraphy in double drive core 60010/60009 and drill strings 60002-60004. The observed magnetization fluctuations persist after normalization to take into account depth dependent variations in the carriers of stable NRM. We tentatively ascribe the stable NRM stratigraphy to instantaneous records of past magnetic fields at the lunar surface and suggest that the stable NRM stratigraphy technique could develop as a new relative time-stratigraphic tool, to be used with other physical measurements such as relative intensity of ferromagnetic resonance and charged particle track density to study the evolution of the lunar regolith.

Mountain Home Well - Photos

DOE Data Explorer

Shervais, John

2012-01-11

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Mountain Home drill hole is located along the western plain and documents older basalts overlain by sediment. Data submitted by project collaborator Doug Schmitt, University of Alberta

Modern rather than Mesoarchaean oxidative weathering responsible for the heavy stable Cr isotopic signatures of the 2.95 Ga old Ijzermijn iron formation (South Africa)

NASA Astrophysics Data System (ADS)

Albut, Gülüm; Babechuk, Michael G.; Kleinhanns, Ilka C.; Benger, Manuela; Beukes, Nicolas J.; Steinhilber, Bernd; Smith, Albertus J. B.; Kruger, Stephanus J.; Schoenberg, Ronny

2018-05-01

Previously reported stable Cr isotopic fractionation in Archaean paleosols and iron formations (IFs) have been interpreted as a signature of oxidative weathering of Cr(III) to Cr(VI) in soils, and delivery of isotopically heavy Cr(VI) into the oceans. One of the oldest reported fingerprints of this process is isotopically heavy Cr preserved in the 2.95 Ga old Ijzermijn IF, Sinqeni Formation of the Mozaan Group (Pongola Supergroup), South Africa and could suggest that atmospheric free oxygen was present ca. 600 million years earlier than the Great Oxidation Event (GOE). However, fractionated stable Cr isotopic signatures have only been found to date in surface outcrop samples of the White Mfolozi Inlier exposed along the White Mfolozi River Gorge. In this study, the latter outcrop was resampled along with two drill cores of the Ijzermijn IF and a drill core of the Scotts Hill IF to represent multiple exposures of Mozaan Group IFs with different states of preservation. A detailed geochemical comparison on bulk samples of different units was undertaken using stable Cr isotopes coupled with trace and major elements. Outcrop iron-rich mudstones (Fe - lutites) show very low LOI [wt] %, and very low Fe(II)/Fetot ratios, and lower Ca and Mg relative to equivalent facies in drill cores, indicating the effects that oxidative recent surface weathering had on Fe/Mn-rich carbonate minerals of the IF. Overall rare earth element and yttrium (REE + Y) mixing models agree well with previous studies, confirming that they were minimally disturbed by weathering and are consistent with a high magnitude of continental solutes delivered in a near-shore depositional environment, with a minor contribution of hydrothermally derived fluids that upwelled into shallower depositional setting. Importantly, all drill core samples of this study revealed δ53/52Cr values within the igneous inventory, despite variable amounts of detrital Cr input that includes nearly detritus-free, chert/jasper-rich units. By contrast, a specific group of Fe-lutite samples near the base of White Mfolozi River outcrop bear fractionated Cr isotopic signatures with δ53/52Cr values up to 0.418‰. These outcrop samples also display unusually high U/Th ratios (max. 12.6) as well as enrichments of other elements (W, Tl, As, MREE) that far exceed that observed in correlative drill core units. These observations together with the lack of Cr isotopic fractionation in drill core samples lead us to propose that the heavy δ53/52Cr values of Fe-lutites from outcrop Ijzermijn IF samples reported here and in a previous study are the product of modern oxidative weathering rather than an indicator for Mesoarchaean oxidative weathering at ca. 2.95 Ga.

PRELIMINARY DRILLING IN THE POWDER RIVER BASIN, CONVERSE, CAMPBELL, AND JOHNSON COUNTRIES, WYOMING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Geslin, H.E.; Bromley, C.P.

1957-06-01

On July 16, 1953, a diamond core-drilling program was begun in the pumpkin Buttes area to secure geologic information. Drilling was terminated March 11, 1964, after 12 holes had been completed for a total of 5,813 feet. An investigational rotary noncore-drilling project was conducted from June l4, to September 17, 1954, in the southern part of the Powder River Basin, Campbell, Johnson, and Converse Counties, Wyoming. Drilling was done in the Pumpkin Buttes area and the Converse County area. A total of 52,267 feet was drilled and the average depth of hole was 75.3 feet. Forty-one anomalous areas in themore » Powder River Basin were drilled; of these, three in Converse County were found to contain possible commercial ore bodies. All of the drilling was done in the Wasatch formation of Eocene age except one locality, which was in the Fort Union formation of Paleocene age. (auth)« less

Fifty Years of Soviet and Russian Drilling Activity in Polar and Non-Polar Ice: A Chronological History

DTIC Science & Technology

2007-10-01

max 175 m) Thermo-electric point “Elektroigla ETI-1” Sukhanov et al., 1974 113 Thermal drill LKTBM-1 1973 50.7 Thermal Coring drill...Glacier (West Caucasus), #C3 IGAS, Moscow State University 20 m (?) Thermo-electric point Sukhanov et al., 1974 1970, 1971 Five holes with...total depth of 405 m (max 111 m) Thermo-electric point Elektroigla ETI-1 Sukhanov , 1973; Sukhanov et al., 1974 1972 A few holes with total

Five Hundred and Seventy Three Holes in the Bottom of the Sea-Some Results From Seven Years of Deep-Sea Drilling

ERIC Educational Resources Information Center

Davies, T. A.

1976-01-01

Described are the background, operation, and findings of the work of the deep sea drilling vessel Glomar Challenger, which has taken 8,638 core samples from 573 holes at 392 sites on the floor of the Earth's oceans. (SL)

The keto-enol equilibrium in substituted acetaldehydes: focal-point analysis and ab initio limit

NASA Astrophysics Data System (ADS)

Balabin, Roman M.

2011-10-01

High-level ab initio electronic structure calculations up to the CCSD(T) theory level, including extrapolations to the complete basis set (CBS) limit, resulted in high precision energetics of the tautomeric equilibrium in 2-substituted acetaldehydes (XH2C-CHO). The CCSD(T)/CBS relative energies of the tautomers were estimated using CCSD(T)/aug-cc-pVTZ, MP3/aug-cc-pVQZ, and MP2/aug-cc-pV5Z calculations with MP2/aug-cc-pVTZ geometries. The relative enol (XHC = CHOH) stabilities (ΔE e,CCSD(T)/CBS) were found to be 5.98 ± 0.17, -1.67 ± 0.82, 7.64 ± 0.21, 8.39 ± 0.31, 2.82 ± 0.52, 10.27 ± 0.39, 9.12 ± 0.18, 5.47 ± 0.53, 7.50 ± 0.43, 10.12 ± 0.51, 8.49 ± 0.33, and 6.19 ± 0.18 kcal mol-1 for X = BeH, BH2, CH3, Cl, CN, F, H, NC, NH2, OCH3, OH, and SH, respectively. Inconsistencies between the results of complex/composite energy computations methods Gn/CBS (G2, G3, CBS-4M, and CBS-QB3) and high-level ab initio methods (CCSD(T)/CBS and MP2/CBS) were found. DFT/aug-cc-pVTZ results with B3LYP, PBE0 (PBE1PBE), TPSS, and BMK density functionals were close to the CCSD(T)/CBS levels (MAD = 1.04 kcal mol-1).

Influence of Steel Reinforcement on In-Situ Stress Evaluation in Concrete Structures by the Core-Drilling Method

NASA Astrophysics Data System (ADS)

McGinnis, M. J.; Pessiki, S.

2006-03-01

The core-drilling method is an emerging technique for evaluating in-situ stress in a concrete structure. A small hole is drilled into the structure, and the deformations in the vicinity of the hole are measured and related via elasticity theory to the stress. The method is similar to the ASTM hole-drilling strain-gauge method excepting that displacements rather than strains are the measured quantities. The technique may be considered nondestructive since the ability of the structure to perform its function is unaffected, and the hole is easily repaired. Displacement measurements in the current work are performed using 3D digital image correlation and industrial photogrammetry. The current paper addresses perturbations in the method caused by steel reinforcement within the concrete. The reinforcement is significantly stiffer than the surrounding concrete, altering the expected displacement field. A numerical investigation performed indicates an under-prediction of stress by as much as 18 percent in a heavily reinforced structure, although the effect is significantly smaller for more common amounts of reinforcement.

Environmental health research recommendations from the Inter-Environmental Health Sciences Core Center Working Group on unconventional natural gas drilling operations.

PubMed

Penning, Trevor M; Breysse, Patrick N; Gray, Kathleen; Howarth, Marilyn; Yan, Beizhan

2014-11-01

Unconventional natural gas drilling operations (UNGDO) (which include hydraulic fracturing and horizontal drilling) supply an energy source that is potentially cleaner than liquid or solid fossil fuels and may provide a route to energy independence. However, significant concerns have arisen due to the lack of research on the public health impact of UNGDO. Environmental Health Sciences Core Centers (EHSCCs), funded by the National Institute of Environmental Health Sciences (NIEHS), formed a working group to review the literature on the potential public health impact of UNGDO and to make recommendations for needed research. The Inter-EHSCC Working Group concluded that a potential for water and air pollution exists that might endanger public health, and that the social fabric of communities could be impacted by the rapid emergence of drilling operations. The working group recommends research to inform how potential risks could be mitigated. Research on exposure and health outcomes related to UNGDO is urgently needed, and community engagement is essential in the design of such studies.

Enhanced oil recovery utilizing high-angle wells in the Frontier Formation, Badger Basin Field, Park County, Wyoming. Quarterly technical progress report, 1 October 1993--31 December 1993

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fortmann, R.G.

1994-01-14

The goals during this period included the following objectives from the Statement of Work: in Phase 2A, completion of Subtask 2.1.4 -- Interpret data, of Task 2.1 -- Acquire 3-D seismic data; and, in Phase 2B, completion of Subtask 2.2.1 -- Solicit bids and award, and initiation of Subtask 2.2.2 -- Acquire cores, of Task 2.2 -- Drill slant hole. Subtask 2.1.4 -- Interpret data: Interpretation of the 3- D seismic survey was completed on a Sun Sparcstation10 workstation (UNIX based), using Landmark Graphics latest version of Seisworks 3D software. Subtask 2.2.2 -- Acquire cores: Sierra had picked a locationmore » and prepared a drilling plan for the slant/horizontal wellbores. Sierra was ready to submit an Application for Permit to Drill. However, due to the fact that Sierra entered into an agreement to sell the Badger Basin property, the drilling phase was put on hold.« less

Influence of Steel Reinforcement on In-Situ Stress Evaluation in Concrete Structures by the Core-Drilling Method

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGinnis, M. J.; Pessiki, S.

2006-03-06

The core-drilling method is an emerging technique for evaluating in-situ stress in a concrete structure. A small hole is drilled into the structure, and the deformations in the vicinity of the hole are measured and related via elasticity theory to the stress. The method is similar to the ASTM hole-drilling strain-gauge method excepting that displacements rather than strains are the measured quantities. The technique may be considered nondestructive since the ability of the structure to perform its function is unaffected, and the hole is easily repaired. Displacement measurements in the current work are performed using 3D digital image correlation andmore » industrial photogrammetry. The current paper addresses perturbations in the method caused by steel reinforcement within the concrete. The reinforcement is significantly stiffer than the surrounding concrete, altering the expected displacement field. A numerical investigation performed indicates an under-prediction of stress by as much as 18 percent in a heavily reinforced structure, although the effect is significantly smaller for more common amounts of reinforcement.« less

Engineering report on drilling in the San Rafael Swell area, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, L.I.

1980-05-01

The San Rafael Swell drilling project was conducted by Bendix Field Engineering Corporation in support of the US Department of Energy National Uranium Resource Evaluation (NURE) program. This project consisted of 27 drill holes ranging in depth from 120.0 ft (36.5 m) to 3,700.0 ft (1,127.7 m). A total of 41,716 ft (12,715 m) was drilled, of which 3,099.8 ft (944.8 m) were cored. Geophysical logging was supplied by Century Geophysical Corporation and Bendix Field Engineering Corporation. The objective of the project was to test the uranium potential of the Triassic and Jurassic sandstone units and to investigate areas wheremore » industry was unlikely to drill in the near future. Drilling commenced September 24, 1978, and was finished on December 17, 1979.« less

New scientific ocean drilling depth record extends study of subseafloor life

NASA Astrophysics Data System (ADS)

Showstack, Randy

2012-09-01

The Japanese deep-sea drilling vessel Chikyu set a new depth record for scientific ocean drilling and core retrieval by reaching a depth of 2119.5 meters below the seafloor (mbsf) on 6 September. This is 8.5 meters deeper than the prior record, set 19 years ago. Three days later, on 9 September, Chikyu set another record by reaching a drilling depth of 2466 mbsf, the maximum depth that will be attempted during the current expedition. The 6 September record was set on day 44 of the Deep Coalbed Biosphere off Shimokita expedition, which is expedition 337 of the Integrated Ocean Drilling Program (IODP). It occurred at drilling site C0020 in the northwestern Pacific Ocean, approximately 80 kilometers northeast from Hachinohe, Japan. The expedition is scheduled to conclude on 30 September.

Seismic imaging for an ocean drilling site survey and its verification in the Izu rear arc

NASA Astrophysics Data System (ADS)

Yamashita, Mikiya; Takahashi, Narumi; Tamura, Yoshihiko; Miura, Seiichi; Kodaira, Shuichi

2018-01-01

To evaluate the crustal structure of a site proposed for International Ocean Discovery Program drilling, the Japan Agency for Marine-Earth Science and Technology carried out seismic surveys in the Izu rear arc between 2006 and 2008, using research vessels Kaiyo and Kairei. High-resolution dense grid surveys, consisting of three kinds of reflection surveys, generated clear seismic profiles, together with a seismic velocity image obtained from a seismic refraction survey. In this paper, we compare the seismic profiles with the geological column obtained from the drilling. Five volcaniclastic sedimentary units were identified in seismic reflection profiles above the 5 km/s and 6 km/s contours of P-wave velocity obtained from the velocity image from the seismic refraction survey. However, some of the unit boundaries interpreted from the seismic images were not recognised in the drilling core, highlighting the difficulties of geological target identification in volcanic regions from seismic images alone. The geological core derived from drilling consisted of seven lithological units (labelled I to VII). Units I to V were aged at 0-9 Ma, and units VI and VII, from 1320-1806.5 m below seafloor (mbsf) had ages from 9 to ~15 Ma. The strong heterogeneity of volcanic sediments beneath the drilling site U1437 was also identified from coherence, calculated using cross-spectral analysis between grid survey lines. Our results suggest that use of a dense grid configuration is important in site surveys for ocean drilling in volcanic rear-arc situations, in order to recognise heterogeneous crustal structure, such as sediments from different origins.

Cool Science Explains a Warming World: Using Ice Core Science to Bridge the Gap Between Researchers and the K-12 Classroom

NASA Astrophysics Data System (ADS)

Huffman, L. T.

2017-12-01

Changing ice has urgent implications for people around the world. The Ice Drilling Program Office (IDPO) provides scientific leadership and oversight of ice coring and drilling activities funded by the US National Science Foundation and also has goals to enhance education and communication of current research information. In a time when misinformation is rampant and climate change science is suspect, it is essential that students receive accurate scientific information and engage in learning activities that model complex ideas through engaging and age appropriate ways, while also learning to validate and recognize reliable sources. The IDPO Education and Outreach (EO) office works to create resources, activities and professional development that bridge the gap between ice core science research and educators and their students. Ice core science is on the cutting edge of new discoveries about climate change and understanding better the past to predict the future. Hands-on inquiry activities based on ice core data allow teachers to lead their students to new discoveries about climate secrets hidden deep in the ice. Capitalizing on the inherent interest in the extremes of the Polar Regions, IDPO materials engage students in activities aligned with NGSS standards. Ice drilling technologies make an ideal platform for intertwining engineering concepts and practices with science research to meet the SEP (Science and Engineering Practices) in the NGSS. This session will highlight how the IDPO EO office has built a community of ice core scientists willing to take part in education and outreach projects and events and share some of the resources available to K-12 educators. We will highlight some of the successes and lessons learned as we continually evolve our work toward more effective science education and communication highlighting ice core and climate change science.

Magneto- and litho-stratigraphic records of the Oligocene-Early Miocene climatic changes from deep drilling in the Linxia Basin, Northeast Tibetan Plateau

NASA Astrophysics Data System (ADS)

Wu, Fuli; Fang, Xiaomin; Meng, Qingquan; Zhao, Yan; Tang, Fenjun; Zhang, Tao; Zhang, Weilin; Zan, Jinbo

2017-11-01

The East Asian monsoon is generally regarded to have initiated at the transition from the Late Oligocene to the Early Miocene. However, little is known about this process because of a lack of continuous strata across the boundary between the Late Oligocene and the Early Miocene in Asia. Based on previous drilling (core HZ-1) in the Miocene sediments in the southern Linxia Basin in NW China, we drilled a new 620 m core (HZ-2) into the Late Oligocene strata and obtained 206 m of continuous new core. The detailed paleomagnetism of the new core reveals eleven pairs of normal and reversed polarity zones that can be readily correlated with chrons 6Bn-9n of the geomagnetic polarity time scale (GPTS), define an age interval of 21.6-26.5 Ma and indicate continuity from the Late Oligocene to Early Miocene. The core is characterized by the remarkable occurrence of brownish-red paleosols of luvic cambisols (brown to luvic drab soils) above reddish-brown floodplain siltstones and mudstones, which suggest that the East Asian monsoon likely began by 26.5 Ma. In contrast to the siltstone and mudstone of the Late Oligocene strata, the Miocene strata begin with a thick fine sandstone bed, which marks sudden increases in erosion and loading that most likely reflect a response to tectonic uplift. The hematite content and redness index records of the core further demonstrate that the monsoonal climate in the Late Oligocene to Early Miocene in this area was mainly controlled by global temperature trends and events.

Utilizing the International GeoSample Number Concept during ICDP Expedition COSC

NASA Astrophysics Data System (ADS)

Conze, Ronald; Lorenz, Henning; Ulbricht, Damian; Gorgas, Thomas; Elger, Kirsten

2016-04-01

The concept of the International GeoSample Number (IGSN) was introduced to uniquely identify and register geo-related sample material, and make it retrievable via electronic media (e.g., SESAR - http://www.geosamples.org/igsnabout). The general aim of the IGSN concept is to improve accessing stored sample material worldwide, enable the exact identification, its origin and provenance, and also the exact and complete citation of acquired samples throughout the literature. The ICDP expedition COSC (Collisional Orogeny in the Scandinavian Caledonides, http://cosc.icdp-online.org) prompted for the first time in ICDP's history to assign and register IGSNs during an ongoing drilling campaign. ICDP drilling expeditions are using commonly the Drilling Information System DIS (http://doi.org/10.2204/iodp.sd.4.07.2007) for the inventory of recovered sample material. During COSC IGSNs were assigned to every drill hole, core run, core section, and sample taken from core material. The original IGSN specification has been extended to achieve the required uniqueness of IGSNs with our offline-procedure. The ICDP name space indicator and the Expedition ID (5054) are forming an extended prefix (ICDP5054). For every type of sample material, an encoded sequence of characters follows. This sequence is derived from the DIS naming convention which is unique from the beginning. Thereby every ICDP expedition has an unlimited name space for IGSN assignments. This direct derivation of IGSNs from the DIS database context ensures the distinct parent-child hierarchy of the IGSNs among each other. In the case of COSC this method of inventory-keeping of all drill cores was done routinely using the ExpeditionDIS during field work and subsequent sampling party. After completing the field campaign, all sample material was transferred to the "Nationales Bohrkernlager" in Berlin-Spandau, Germany. Corresponding data was subsequently imported into the CurationDIS used at the aforementioned core storage facility. This CurationDIS assigns IGSNs on samples newly taken in the repository in the identical fashion as done in the field. Thereby, the parent-child linkage of the IGSNs is ensured consistently throughout the entire sampling process. The only difference between ExpeditionDIS and CurationDIS sample curation is using the name space ICDP and BGRB respectively as part of the corresponding ID string. To prepare the IGSN registry, a set of metadata is generated for every assigned IGSN using the DIS, which is then exported from the DIS into one common xml-file. The xml-file is based on the SESAR schema and a proposal of IGSN e.V. (http://schema.igsn.org). This systematics has been recently extended for drilling data to achieve additional information for future retrieval options. The two allocation agents GFZ Potsdam und PANGAEA are currently involved in the registry of IGSNs in the case of COSC drill campaigns. An example for the IGSN registration of the COSC-1 drill hole A (5054_1_A) is "ICDP5054EEW1001" and can be resolved using the URL http://hdl.handle.net/10273/ICDP5054EEW1001. Opening the landing page for the complete COSC core material for this particular hole showcases graphically a hierarchical tree entitled "Sample Family". An example of an IGSN citation associated with a COSC sample set is featured on an EGU-2016 poster presentation by Ulrich Harms, Johannes Hierold et al. (EGU2016-8646).

Ferromagnetic resonance and magnetic studies of cores 60009/60010 and 60003 - Compositional and surface-exposure stratigraphy. [of Apollo deep drill lunar samples

NASA Technical Reports Server (NTRS)

Morris, R. V.; Gose, W. A.

1976-01-01

Ferromagnetic resonance and static magnetic measurements were made on 131 samples from core 60009/60010 and on 40 samples from section 60003 of the Apollo 16 deep drill core. These studies provided depth profiles for composition, in terms of the concentration of FeO, and relative surface exposure age (or maturity), in terms of the values of the specific FMR intensity normalized to the FeO content. For core 60009/60010, the concentration of FeO ranged from about 1.6 wt.% to 5.8 wt.% with a mean value of 4.6 wt.% and the maturity ranged from immature to mature with most of the soils being submature. A systematic decrease in maturity from the lunar surface to a depth of about 12.5 cm was observed in core section 60010. For core section 60003, the concentration of FeO ranged from about 5.2 wt.% to 7.5 wt.% with a mean value of 6.4 wt.% and the maturity ranged from submature to mature with most of the soils being mature.

Scientific Drilling at Lake Tanganyika, Africa: A Transformative Record for Understanding Evolution in Isolation and the Biological History of the African Continent, University of Basel, 6-8 June 2016

NASA Astrophysics Data System (ADS)

Cohen, Andrew S.; Salzburger, Walter

2017-05-01

We report on the outcomes of a workshop held to discuss evolutionary biology, paleobiology and paleoecology questions that could be addressed by a scientific drilling project at Lake Tanganyika, the largest, deepest and oldest of the African Rift Valley lakes. Lake Tanganyika is of special significance to evolutionary biologists as it harbors one of the most spectacular endemic faunas of any lake on earth, with hundreds of unique species of fish, molluscs, crustaceans and other organisms that have evolved over the lake's long history. Most of these groups of organisms are known from fossils in short cores from the lake, raising the possibility that both body fossil and ancient DNA records might be recovered from long drill cores. The lake's sedimentary record could also provide a record of African terrestrial ecosystem history since the late Miocene. This 3-day workshop brought together biological and geological specialists on the lake and its surroundings to prioritize paleobiological, ecological and microbiological objectives that could ultimately be incorporated into an overall drilling plan for Lake Tanganyika and to consider how biological objectives can effectively be integrated into the paleoclimate and tectonics objectives of a Lake Tanganyika drilling project already considered in prior workshops.

Rapid and Quiet Drill

NASA Technical Reports Server (NTRS)

Sherrit, Stewart; Badescu, Mircea; Bar-Cohen, Yoseph; Chang, Zensheu; Bao, Xiaoqi

2007-01-01

This describes aspects of the rapid and quiet drill (RAQD), which is a prototype apparatus for drilling concrete or bricks. The design and basic principle of operation of the RAQD overlap, in several respects, with those of ultrasonic/ sonic drilling and coring apparatuses described in a number of previous NASA Tech Briefs articles. The main difference is that whereas the actuation scheme of the prior apparatuses is partly ultrasonic and partly sonic, the actuation scheme of the RAQD is purely ultrasonic. Hence, even though the RAQD generates considerable sound, it is characterized as quiet because most or all of the sound is above the frequency range of human hearing.

Electrical transmission line diametrical retainer

DOEpatents

Hall, David R.; Hall, Jr., H. Tracy; Pixton, David; Dahlgren, Scott; Sneddon, Cameron; Briscoe, Michael; Fox, Joe

2004-12-14

The invention is a mechanism for retaining an electrical transmission line. In one embodiment of the invention it is a system for retaining an electrical transmission line within down hole components. In accordance with one aspect of the invention, the system includes a plurality of downhole components, such as sections of pipe in a drill string. The system also includes a coaxial cable running between the first and second end of a drill pipe, the coaxial cable having a conductive tube and a conductive core within it. The invention allows the electrical transmission line to with stand the tension and compression of drill pipe during routine drilling cycles.

Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Coring operations, core sedimentology, and lithostratigraphy

USGS Publications Warehouse

Rose, K.; Boswell, R.; Collett, T.

2011-01-01

In February 2007, BP Exploration (Alaska), the U.S. Department of Energy, and the U.S. Geological Survey completed the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert well) in the Milne Point Unit on the Alaska North Slope. The program achieved its primary goals of validating the pre-drill estimates of gas hydrate occurrence and thickness based on 3-D seismic interpretations and wireline log correlations and collecting a comprehensive suite of logging, coring, and pressure testing data. The upper section of the Mount Elbert well was drilled through the base of ice-bearing permafrost to a casing point of 594??m (1950??ft), approximately 15??m (50??ft) above the top of the targeted reservoir interval. The lower portion of the well was continuously cored from 606??m (1987??ft) to 760??m (2494??ft) and drilled to a total depth of 914??m. Ice-bearing permafrost extends to a depth of roughly 536??m and the base of gas hydrate stability is interpreted to extend to a depth of 870??m. Coring through the targeted gas hydrate bearing reservoirs was completed using a wireline-retrievable system. The coring program achieved 85% recovery of 7.6??cm (3??in) diameter core through 154??m (504??ft) of the hole. An onsite team processed the cores, collecting and preserving approximately 250 sub-samples for analyses of pore water geochemistry, microbiology, gas chemistry, petrophysical analysis, and thermal and physical properties. Eleven samples were immediately transferred to either methane-charged pressure vessels or liquid nitrogen for future study of the preserved gas hydrate. Additional offsite sampling, analyses, and detailed description of the cores were also conducted. Based on this work, one lithostratigraphic unit with eight subunits was identified across the cored interval. Subunits II and Va comprise the majority of the reservoir facies and are dominantly very fine to fine, moderately sorted, quartz, feldspar, and lithic fragment-bearing to -rich sands. Lithostratigraphic and palynologic data indicate that this section is most likely early Eocene to late Paleocene in age. The examined units contain evidence for both marine and non-marine lithofacies, and indications that the depositional environment for the reservoir facies may have been shallower marine than originally interpreted based on pre-drill wireline log interpretations. There is also evidence of reduced salinity marine conditions during deposition that may be related to the paleo-climate and depositional conditions during the early Eocene. ?? 2010.

Publications - GMC 262 | Alaska Division of Geological & Geophysical

Science.gov Websites

DGGS GMC 262 Publication Details Title: Map location and geological logs of core for 7 1991 diamond Reference Cominco American Inc., 1996, Map location and geological logs of core for 7 1991 diamond drill

Preliminary Physical Stratigraphy and Geophysical Data From the USGS Dixon Core, Onslow County, North Carolina

USGS Publications Warehouse

Seefelt, Ellen L.; Gonzalez, Wilma Aleman B.; Self-Trail, Jean M.; Weems, Robert E.; Edwards, Lucy E.; Pierce, Herbert A.; Durand, Colleen T.

2009-01-01

In October through November 2006, scientists from the U. S. Geological Survey (USGS) Eastern Region Earth Surface Processes Team (EESPT) and the Raleigh (N.C.) Water Science Center (WSC), in cooperation with the North Carolina Geological Survey (NCGS) and the Onslow County Water and Sewer Authority (ONWASA), drilled a stratigraphic test hole and well in Onslow County, N.C. The Dixon corehole was cored on ONWASA water utility property north of the town of Dixon, N.C., in the Sneads Ferry 7.5-minute quadrangle at latitude 34deg33'35' N, longitude 77deg26'54' W (decimal degrees 34.559722 and -77.448333). The site elevation is 66.0 feet (ft) above mean sea level as determined using a Paulin precision altimeter. The corehole attained a total depth of 1,010 ft and was continuously cored by the USGS EESPT drilling crew. A groundwater monitoring well was installed in the screened interval between 234 and 254 ft below land surface. The section cored at this site includes Upper Cretaceous, Paleogene, and Neogene sediments. The Dixon core is stored at the NCGS Coastal Plain core storage facility in Raleigh. The Dixon corehole is the fourth and last in a series of planned North Carolina benchmark coreholes drilled by the USGS Coastal Carolina Project. These coreholes explore the physical stratigraphy, facies, and thickness of Cretaceous, Paleogene, and Neogene Coastal Plain sediments in North Carolina. Correlations of lithologies, facies, and sequence stratigraphy can be made with the Hope Plantation corehole, N.C., near Windsor in Bertie County (Weems and others, 2007); the Elizabethtown corehole, near Elizabethtown, N.C., in Bladen County (Self-Trail and others, 2004b); the Smith Elementary School corehole, near Cove City, N.C., in Craven County (Harris and Self-Trail, 2006; Crocetti, 2007); the Kure Beach corehole, near Wilmington, N.C., in New Hanover County (Self-Trail and others, 2004a); the Esso#1, Esso #2, Mobil #1, and Mobil #2 cores in Albermarle and Pamlico Sounds, N.C. (Zarra, 1989); and the Cape Fear River outcrops in Bladen County, N.C. (Farrell, 1998; Farrell and others, 2001). This report contains the lithostratigraphic summary recorded at the drill site, core photographs, geophysical data, and calcareous nannofossil biostratigraphic correlations.

Lower crustal section of the Oman Ophiolite drilled in Hole GT1A, ICDP Oman Drilling Project

NASA Astrophysics Data System (ADS)

Umino, S.; Kelemen, P. B.; Matter, J. M.; Coggon, J. A.; Takazawa, E.; Michibayashi, K.; Teagle, D. A. H.

2017-12-01

Hole GT1A (22° 53.535'N, 58° 30.904'E) was drilled by the Oman Drilling Project (OmDP) into GT1A of the Samail ophiolite, Oman. OmDP is an international collaboration supported by the International Continental Scientific Drilling Program, the Deep Carbon Observatory, NSF, IODP, JAMSTEC, and the European, Japanese, German and Swiss Science Foundations, with in-kind support in Oman from the Ministry of Regional Municipalities and Water Resources, Public Authority of Mining, Sultan Qaboos University, and the German University of Technology. Hole GT1A was diamond cored in 22 Jan to 08 Feb 2017 to a total depth of 403.05 m. The outer surfaces of the cores were imaged and described on site before being curated, boxed and shipped to the IODP drill ship Chikyu, where they underwent comprehensive visual and instrumental analysis. Hole GT1A drilled the lower crustal section in the southern Oman Ophiolite and recovered 401.52 m of total cores (99.6% recovery). The main lithology is dominated by olivine gabbro (65.9%), followed in abundance by olivine-bearing gabbro (21.5%) and olivine melagabbro (3.9%). Minor rock types are orthopyroxene-bearing olivine gabbro (2.4%), oxide-bearing olivine gabbro (1.5%), gabbro (1.1%), anorthositic gabbro (1%), troctolitic gabbro (0.8%); orthopyroxene-bearing gabbro (0.5%), gabbronorite (0.3%); and dunite (0.3%). These rocks are divided into Lithologic Unit I to VII at 26.62 m, 88.16 m, 104.72 m, 154.04 m, 215.22 m, 306.94 m in Chikyu Curated Depth in descending order; Unit I and II consist of medium-grained olivine gabbro with lower olivine abundance in Unit II. Unit III is medium-grained olivine melagabbros, marked by an increase in olivine. Unit IV is relatively homogenous medium-grained olivine gabbros with granular textures. Unit V is identified by the appearance of fine-grained gabbros, but the major rocktypes are medium grained olivine gabbros. Unit VI is medium-grained olivine gabbro, marked by appearance of orthopyroxene. Unit VII is of fine- to medium-grained olivine gabbros with less olivine.

Coring the Chesapeake Bay impact crater

USGS Publications Warehouse

Poag, C.W.

2004-01-01

In July 1983, the shipboard scientists of Deep Sea Drilling Project Leg 95 found an unexpected bonus in a core taken 150 kilometers east of Atlantic City, N.J. At Site 612, the scientists recovered a 10-centimeter-thick layer of late Eocene debris ejected from an impact about 36 million years ago. Microfossils and argon isotope ratios from the same layer reveal that the ejecta were part of a broad North American impact debris field, previously known primarily from the Gulf of Mexico and Caribbean Sea. Since that serendipitous beginning, years of seismic reflection profiling, gravity measurements and core drilling have confirmed the source of that strewn field - the Chesapeake Bay impact crater, the largest structure of its kind in the United States, and the sixth-largest impact crater on Earth.

The public's trust in scientific claims regarding offshore oil drilling.

PubMed

Carlisle, Juliet E; Feezell, Jessica T; Michaud, Kristy E H; Smith, Eric R A N; Smith, Leeanna

2010-09-01

Our study examines how individuals decide which scientific claims and experts to believe when faced with competing claims regarding a policy issue. Using an experiment in a public opinion survey, we test the source content and credibility hypotheses to assess how much confidence people have in reports about scientific studies of the safety of offshore oil drilling along the California coast. The results show that message content has a substantial impact. People tend to accept reports of scientific studies that support their values and prior beliefs, but not studies that contradict them. Previous studies have shown that core values influence message acceptance. We find that core values and prior beliefs have independent effects on message acceptance. We also find that the sources of the claims make little difference. Finally, the public leans toward believing reports that oil drilling is riskier than previously believed.

Subsurface Sample Acquisition and Transfer Systems (SSATS)

NASA Astrophysics Data System (ADS)

Rafeek, S.; Gorevan, S. P.; Kong, K. Y.

2001-01-01

In the exploration of planets and small bodies, scientists will need the services of a deep drilling and material handling system to not only obtain the samples necessary for analyses but also to precisely transfer and deposit those samples in in-situ instruments on board a landed craft or rover. The technology for such a deep sampling system as the SSATS is currently been developed by Honeybee Robotics through a PIDDP effort. The SSATS has its foundation in a one-meter prototype (SATM) drill that was developed under the New Millenium Program for ST4/Champollion. Additionally the SSATS includes relevant coring technology form a coring drill (Athena Mini-Corer) developed for the Mars Sample Return Mission. These highly developed technologies along with the current PIDDP effort, is combined to produce a sampling system that can acquire and transfer samples from various depths. Additional information is contained in the original extended abstract.

Communication: Acceleration of coupled cluster singles and doubles via orbital-weighted least-squares tensor hypercontraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parrish, Robert M.; Sherrill, C. David, E-mail: sherrill@gatech.edu; Hohenstein, Edward G.

2014-05-14

We apply orbital-weighted least-squares tensor hypercontraction decomposition of the electron repulsion integrals to accelerate the coupled cluster singles and doubles (CCSD) method. Using accurate and flexible low-rank factorizations of the electron repulsion integral tensor, we are able to reduce the scaling of the most vexing particle-particle ladder term in CCSD from O(N{sup 6}) to O(N{sup 5}), with remarkably low error. Combined with a T{sub 1}-transformed Hamiltonian, this leads to substantial practical accelerations against an optimized density-fitted CCSD implementation.

Variation of Accumulation Rates Over the Last Eight Centuries on the East Antarctic Plateau Derived from Volcanic Signals in Ice Cores

NASA Technical Reports Server (NTRS)

Anschuetz, H.; Sinisalo, A.; Isaksson, E.; McConnell, J. R.; Hamran, S.-E.; Bisiaux, M. M.; Pasteris, D.; Neumann, T. A.; Winther, J.-G.

2011-01-01

Volcanic signatures in ice-core records provide an excellent means to date the cores and obtain information about accumulation rates. From several ice cores it is thus possible to extract a spatio-temporal accumulation pattern. We show records of electrical conductivity and sulfur from firn cores from the Norwegian-USA scientific traverse during the International Polar Year 2007-2009 (IPY) through East Antarctica. Major volcanic eruptions are identified and used to assess century-scale accumulation changes. The largest changes seem to occur in the most recent decades with accumulation over the period 1963- 2007/08 being up to 25 % different from the long-term record. There is no clear overall trend, some sites show an increase in accumulation over the period 1963 to present while others show a decrease. Almost all of the sites above 3200 m above sea level (asl) suggest a decrease. These sites also show a significantly lower accumulation value than large-scale assessments both for the period 1963 to present and for the long-term mean at the respective drill sites. The spatial accumulation distribution is influenced mainly by elevation and distance to the ocean (continentality), as expected. Ground-penetrating radar data around the drill sites show a spatial variability within 10-20 % over several tens of kilometers, indicating that our drill sites are well representative for the area around them. Our results are important for large-scale assessments of Antarctic mass balance and model validation.

International Collaboration in Data Management for Scientific Ocean Drilling: Preserving Legacy Data While Implementing New Requirements.

NASA Astrophysics Data System (ADS)

Rack, F. R.

2005-12-01

The Integrated Ocean Drilling Program (IODP: 2003-2013 initial phase) is the successor to the Deep Sea Drilling Project (DSDP: 1968-1983) and the Ocean Drilling Program (ODP: 1985-2003). These earlier scientific drilling programs amassed collections of sediment and rock cores (over 300 kilometers stored in four repositories) and data organized in distributed databases and in print or electronic publications. International members of the IODP have established, through memoranda, the right to have access to: (1) all data, samples, scientific and technical results, all engineering plans, data or other information produced under contract to the program; and, (2) all data from geophysical and other site surveys performed in support of the program which are used for drilling planning. The challenge that faces the individual platform operators and management of IODP is to find the right balance and appropriate synergies among the needs, expectations and requirements of stakeholders. The evolving model for IODP database services consists of the management and integration of data collected onboard the various IODP platforms (including downhole logging and syn-cruise site survey information), legacy data from DSDP and ODP, data derived from post-cruise research and publications, and other IODP-relevant information types, to form a common, program-wide IODP information system (e.g., IODP Portal) which will be accessible to both researchers and the public. The JANUS relational database of ODP was introduced in 1997 and the bulk of ODP shipboard data has been migrated into this system, which is comprised of a relational data model consisting of over 450 tables. The JANUS database includes paleontological, lithostratigraphic, chemical, physical, sedimentological, and geophysical data from a global distribution of sites. For ODP Legs 100 through 210, and including IODP Expeditions 301 through 308, JANUS has been used to store data from 233,835 meters of core recovered, which are comprised of 38,039 cores, with 202,281 core sections stored in repositories, which have resulted in the taking of 2,299,180 samples for scientists and other users (http://iodp.tamu.edu/janusweb/general/dbtable.cgi). JANUS and other IODP databases are viewed as components of an evolving distributed network of databases, supported by metadata catalogs and middleware with XML workflows, that are intended to provide access to DSDP/ODP/IODP cores and sample-based data as well as other distributed geoscience data collections (e.g., CHRONOS, PetDB, SedDB). These data resources can be explored through the use of emerging data visualization environments, such as GeoWall, CoreWall (http://(www.evl.uic.edu/cavern/corewall), a multi-screen display for viewing cores and related data, GeoWall-2 and LambdaVision, a very-high resolution, networked environment for data exploration and visualization, and others. The U.S Implementing Organization (USIO) for the IODP, also known as the JOI Alliance, is a partnership between Joint Oceanographic Institutions (JOI), Texas A&M University, and Lamont-Doherty Earth Observatory of Columbia University. JOI is a consortium of 20 premier oceanographic research institutions that serves the U.S. scientific community by leading large-scale, global research programs in scientific ocean drilling and ocean observing. For more than 25 years, JOI has helped facilitate discovery and advance global understanding of the Earth and its oceans through excellence in program management.

Geohydrologic data from test hole USW UZ-7, Yucca Mountain area, Nye County, Nevada

USGS Publications Warehouse

Kume, Jack; Hammermeister, D.P.

1990-01-01

This report contains a description of the methods used in drilling and coring of the test-hole USW UZ-7, a description of the methods used in collecting, handling, and testing of test-hole samples; Lithologic information from the test hole; and water-content, water-potential, bulk-density, grain-density, porosity, and tritium data for the test hole. Test-hole USW UZ-7 was drilled and cored to a total depth of 62.94 m. The drilling was done using air as a drilling fluid to minimize disturbance to the water content of cores, drill-bit cuttings, and borehole wall-rock. Beginning at the land surface, the unsaturated-zone rock that was penetrated consisted of alluvium; welded and partially to nonwelded ash-flow tuff; bedded and reworked ash-fall tuff; nonwelded ash-flow tuff; and welded ash-flow tuff. Values of gravimetric water content and water potential of alluvium were intermediate between the extreme values in welded and nonwelded units of tuff. Gravimetric water content was largest in bedded and nonwelded ash-fall tuffs and was smallest in welded ash-flow tuff. Values of water potential were more negative in densely welded ash-flow tuffs and were less negative in bedded and nonwelded ash-fall tuffs. Bulk density was largest in densely welded ash-flow tuffs and smallest in nonwelded and bedded ash-fall tuffs. Grain density was uniform but was slightly larger in nonwelded and bedded ash-fall tuffs than in welded ash-flow tuffs. Porosity trends were opposite to bulk-density trends. Tritium content in alluvium was smallest near the alluvium-bedrock contact, markedly increased in the middle of the deposit, and decreased in the near-surface zone of the deposit. (Author 's abstract)

Shipboard Analytical Capabilities on the Renovated JOIDES Resolution, IODP Riserless Drilling Vessel

NASA Astrophysics Data System (ADS)

Blum, P.; Foster, P.; Houpt, D.; Bennight, C.; Brandt, L.; Cobine, T.; Crawford, W.; Fackler, D.; Fujine, K.; Hastedt, M.; Hornbacher, D.; Mateo, Z.; Moortgat, E.; Vasilyev, M.; Vasilyeva, Y.; Zeliadt, S.; Zhao, J.

2008-12-01

The JOIDES Resolution (JR) has conducted 121 scientific drilling expeditions during the Ocean Drilling Program (ODP) and the first phase of the Integrated Ocean Drilling Program (IODP) (1983-2006). The vessel and scientific systems have just completed an NSF-sponsored renovation (2005-2008). Shipboard analytical systems have been upgraded, within funding constraints imposed by market driven vessel conversion cost increases, to include: (1) enhanced shipboard analytical services including instruments and software for sampling and the capture of chemistry, physical properties, and geological data; (2) new data management capabilities built around a laboratory information management system (LIMS), digital asset management system, and web services; (3) operations data services with enhanced access to navigation and rig instrumentation data; and (4) a combination of commercial and home-made user applications for workflow- specific data extractions, generic and customized data reporting, and data visualization within a shipboard production environment. The instrumented data capture systems include a new set of core loggers for rapid and non-destructive acquisition of images and other physical properties data from drill cores. Line-scan imaging and natural gamma ray loggers capture data at unprecedented quality due to new and innovative designs. Many instruments used to characterize chemical compounds of rocks, sediments, and interstitial fluids were upgraded with the latest technology. The shipboard analytical environment features a new and innovative framework (DESCinfo) and application (DESClogik) for capturing descriptive and interpretive data from geological sub-domains such as sedimentology, petrology, paleontology, structural geology, stratigraphy, etc. This system fills a long-standing gap by providing a global database, controlled vocabularies and taxa name lists with version control, a highly configurable spreadsheet environment for data capture, and visualization of context data collected with the shipboard core loggers and other instruments.

IODP Expedition 335: Deep Sampling in ODP Hole 1256D

NASA Astrophysics Data System (ADS)

Teagle, D. A. H.; Ildefonse, B.; Blum, P.; IODP Expedition 335 Scientists, the

2012-04-01

Observations of the gabbroic layers of untectonized ocean crust are essential to test theoretical models of the accretion of new crust at mid-ocean ridges. Integrated Ocean Drilling Program (IODP) Expedition 335 ("Superfast Spreading Rate Crust 4") returned to Ocean Drilling Program (ODP) Hole 1256D with the intention of deepening this reference penetration of intact ocean crust a significant distance (~350 m) into cumulate gabbros. Three earlier cruises to Hole 1256D (ODP 206, IODP 309/312) have drilled through the sediments, lavas, and dikes and 100 m into a complex dike-gabbro transition zone. Operations on IODP Expedition 335 proved challenging throughout, with almost three weeks spent re-opening and securing unstable sections of the hole. When coring commenced, the comprehensive destruction of the coring bit required further remedial operations to remove junk and huge volumes of accumulated drill cuttings. Hole-cleaning operations using junk baskets were successful, and they recovered large irregular samples that document a hitherto unseen sequence of evolving geological conditions and the intimate coupling between temporally and spatially intercalated intrusive, hydrothermal, contact-metamorphic, partial melting, and retrogressive processes. Hole 1256D is now clean of junk, and it has been thoroughly cleared of the drill cuttings that hampered operations during this and previous expeditions. At the end of Expedition 335, we briefly resumed coring before undertaking cementing operations to secure problematic intervals. To ensure the greatest scientific return from the huge efforts to stabilize this primary ocean lithosphere reference site, it would be prudent to resume the deepening of Hole 1256D in the nearest possible future while it is open to full depth. doi:10.2204/iodp.sd.13.04.2011

The French initiative for scientific cores virtual curating : a user-oriented integrated approach

NASA Astrophysics Data System (ADS)

Pignol, Cécile; Godinho, Elodie; Galabertier, Bruno; Caillo, Arnaud; Bernardet, Karim; Augustin, Laurent; Crouzet, Christian; Billy, Isabelle; Teste, Gregory; Moreno, Eva; Tosello, Vanessa; Crosta, Xavier; Chappellaz, Jérome; Calzas, Michel; Rousseau, Denis-Didier; Arnaud, Fabien

2016-04-01

Managing scientific data is probably one the most challenging issue in modern science. The question is made even more sensitive with the need of preserving and managing high value fragile geological sam-ples: cores. Large international scientific programs, such as IODP or ICDP are leading an intense effort to solve this problem and propose detailed high standard work- and dataflows thorough core handling and curating. However most results derived from rather small-scale research programs in which data and sample management is generally managed only locally - when it is … The national excellence equipment program (Equipex) CLIMCOR aims at developing French facilities for coring and drilling investigations. It concerns indiscriminately ice, marine and continental samples. As part of this initiative, we initiated a reflexion about core curating and associated coring-data management. The aim of the project is to conserve all metadata from fieldwork in an integrated cyber-environment which will evolve toward laboratory-acquired data storage in a near future. In that aim, our demarche was conducted through an close relationship with field operators as well laboratory core curators in order to propose user-oriented solutions. The national core curating initiative currently proposes a single web portal in which all scientifics teams can store their field data. For legacy samples, this will requires the establishment of a dedicated core lists with associated metadata. For forthcoming samples, we propose a mobile application, under Android environment to capture technical and scientific metadata on the field. This application is linked with a unique coring tools library and is adapted to most coring devices (gravity, drilling, percussion, etc...) including multiple sections and holes coring operations. Those field data can be uploaded automatically to the national portal, but also referenced through international standards or persistent identifiers (IGSN, ORCID and INSPIRE) and displayed in international portals (currently, NOAA's IMLGS). In this paper, we present the architecture of the integrated system, future perspectives and the approach we adopted to reach our goals. We will also present in front of our poster, one of the three mobile applications, dedicated more particularly to the operations of continental drillings.

Direct Observation of Rhyolite Magma by Drilling: The Proposed Krafla Magma Drilling Project

NASA Astrophysics Data System (ADS)

Eichelberger, J. C.; Sigmundsson, F.; Papale, P.; Markusson, S.; Loughlin, S.

2014-12-01

Remarkably, drilling in Landsvirkjun Co.'s geothermal field in Krafla Caldera, Iceland has encountered rhyolite magma or hypersolidus rhyolite at 2.1-2.5 km depth in 3 wells distributed over 3.5 km2, including Iceland Deep Drilling Program's IDDP-1 (Mortensen, 2012). Krafla's most recent rifting and eruption (basalt) episode was 1975-1984; deformation since that time has been simple decay. Apparently rhyolite magma was either emplaced during that episode without itself erupting or quietly evolved in situ within 2-3 decades. Analysis of drill cuttings containing quenched melt from IDDP-1 yielded unprecedented petrologic data (Zierenberg et al, 2012). But interpreting active processes of heat and mass transfer requires knowing spatial variations in physical and chemical characteristics at the margin of the magma body, and that requires retrieving core - a not-inconceivable task. Core quenched in situ in melt up to 1150oC was recovered from Kilauea Iki lava lake, Hawaii by the Magma Energy Project >30 years ago. The site from which IDDP-1 was drilled, and perhaps IDDP-1 itself, may be available to attempt the first-ever coring of rhyolite magma, now proposed as the Krafla Magma Drilling Project (KMDP). KMDP would also include geophysical and geochemical experiments to measure the response of the magma/hydrothermal system to fluid injection and flow tests. Fundamental results will reveal the behavior of magma in the upper crust and coupling between magma and the hydrothermal system. Extreme, sustained thermal power output during flow tests of IDDP-1 suggests operation of a Kilauea-Iki-like freeze-fracture-flow boundary propagating into the magma and mining its latent heat of crystallization (Carrigan et al, EGU, 2014). Such an ultra-hot Enhanced Geothermal System (EGS) might be developable beneath this and other magma-heated conventional hydrothermal systems. Additionally, intra-caldera intrusions like Krafla's are believed to produce the unrest that is so troubling in populated calderas (e.g., Campi Flegrei, Italy). Experiments with the live system will aid in hazard assessment and eruption forecasting for this most difficult of volcano hazard problems. We will report on an International Continental Scientific Drilling Program (ICDP) workshop held to assess feasibility and to develop a plan for KMDP.

Superhot Drilling in Iceland, the Experience of the Iceland Deep Drilling Project.

NASA Astrophysics Data System (ADS)

Elders, W. A.; Friðleifsson, G. Ó.; Zierenberg, R. A.; Fowler, A. P.

2017-12-01

The Iceland Deep Drilling Project aims to improve geothermal economics by producing supercritical fluids (www.iddp.is). Supercritical wells could yield an order of magnitude more usable energy than that from conventional geothermal wells because of higher enthalpy and enhanced flow properties. In 2009, the IDDP-1 well failed to reach supercritical conditions in the Krafla caldera in NE Iceland, after encountering rhyolite magma at only 2.1 km depth. The completed geothermal well became the world's hottest and produced superheated steam with a wellhead temperature of 452°C and flow sufficient to generate 35 MWe. The IDDP next moved SW to the Reykjanes Peninsula, the landward extension of the Mid-Atlantic Ridge, where it is possible to study an analog of the roots of a black smoker. Reykjanes is unique among Icelandic geothermal systems in being recharged by seawater, which has a critical point of 406°C at 298 bars. Drilling began by deepening an existing 2.5 km deep production well to 3 km depth, and then angling it towards the main upflow zone of the system, for a total slant depth of 4,659 m. Total circulation losses were encountered below 3 km that could not be cured by lost circulation materials or by multiple cement jobs. Accordingly, drilling continued to total depth without return of drill cuttings. We attempted 13 core runs below 3 km depth, only half of which recovered core. The cores are basalts and dolerites with alteration ranging from lower greenschist facies to lower amphibolite facies, suggesting formation temperatures >450°C. After the end of drilling in January 2017, following only six days of heating, supercritical conditions (426°C at 340 bars) were measured in the well at a depth of 4.5 km. The well has not yet been allowed to equilibrate to full in situ temperature. A perforated liner was inserted to 4,570 m, depth to facilitate temperature cycling to enhance permeability at depth through thermal cracking. In 2018 this will be followed by a flow test and eventual production of the well. The project is co-funded by the DEEPEGS project (EU H2020), HS Orka (the field operator), Statoil, the IDDP consortium, and the ICDP. Planning is underway to drill IDDP-3 at Hellisheidi.

Modelling of Tc migration in an un-oxidized fractured drill core from Äspö, Sweden

NASA Astrophysics Data System (ADS)

Huber, F. M.; Totskiy, Y.; Montoya Garcia, V.; Enzmann, F.; Trumm, M.; Wenka, A.; Geckeis, H.; Schaefer, T.

2015-12-01

The radionuclide retention of redox sensitive radionuclides (e.g. Pu, Np, U, Tc) in crystalline host rock greatly depends on the rock matrix and the rock redox capacity. Preservation of drill cores concerning oxidation is therefore of paramount importance to reliably predict the near-natural radionuclide retention properties. Here, experimental results of HTO and Tc laboratory migration experiments in a naturally single fractured Äspö un-oxidized drill core are modelled using two different 2D models. Both models employ geometrical information obtained by μ-computed tomography (μCT) scanning of the drill core. The models differ in geometrical complexity meaning the first model (PPM-MD) consists of a simple parallel plate with a porous matrix adjacent to the fracture whereas the second model (MPM) uses the mid-plane of the 3D fracture only (no porous matrix). Simulation results show that for higher flow rates (Peclet number > 1), the MPM satisfactorily describes the HTO breakthrough curves (BTC) whereas the PPM-MD model nicely reproduces the HTO BTC for small Pe numbers (<1). These findings clearly highlight the influence of fracture geometry/flow field complexity on solute transport for Pe numbers > 1 and the dominating effect of matrix diffusion for Peclet numbers < 1. Retention of Tc is modelled using a simple Kd-approach in case of the PPM-MD and including 1st order sorptive reduction/desorption kinetics in case of the MPM. Batch determined sorptive reduction/desorption kinetic rates and Kd values for Tc on non-oxidized Äspö diorite are used in the model and compared to best fit values. By this approach, the transferability of kinetic data concerning sorptive reduction determined in static batch experiments to dynamic transport experiments is examined.

Open Core Data: Connecting scientific drilling data to scientists and community data resources

NASA Astrophysics Data System (ADS)

Fils, D.; Noren, A. J.; Lehnert, K.; Diver, P.

2016-12-01

Open Core Data (OCD) is an innovative, efficient, and scalable infrastructure for data generated by scientific drilling and coring to improve discoverability, accessibility, citability, and preservation of data from the oceans and continents. OCD is building on existing community data resources that manage, store, publish, and preserve scientific drilling data, filling a critical void that currently prevents linkages between these and other data systems and tools to realize the full potential of data generated through drilling and coring. We are developing this functionality through Linked Open Data (LOD) and semantic patterns that enable data access through the use of community ontologies such as GeoLink (geolink.org, an EarthCube Building Block), a collection of protocols, formats and vocabularies from a set of participating geoscience repositories. Common shared concepts of classes such as cruise, dataset, person and others allow easier resolution of common references through shared resource IDs. These graphs are then made available via SPARQL as well as incorporated into web pages following schema.org approaches. Additionally the W3C PROV vocabulary is under evaluation for use for documentation of provenance. Further, the application of persistent identifiers for samples (IGSNs); datasets, expeditions, and projects (DOIs); and people (ORCIDs), combined with LOD approaches, provides methods to resolve and incorporate metadata and datasets. Application Program Interfaces (APIs) complement these semantic approaches to the OCD data holdings. APIs are exposed following the Swagger guidelines (swagger.io) and will be evolved into the OpenAPI (openapis.org) approach. Currently APIs are in development for the NSF funded Flyover Country mobile geoscience app (fc.umn.edu), the Neotoma Paleoecology Database (neotomadb.org), Magnetics Information Consortium (MagIC; earthref.org/MagIC), and other community tools and data systems, as well as for internal OCD use.

Wellsite, laboratory, and mathematical techniques for determining sorbed gas content of coals and gas shales utilizing well cuttings

USGS Publications Warehouse

Newell, K.D.

2007-01-01

Drill cuttings can be used for desorption analyses but with more uncertainty than desorption analyses done with cores. Drill cuttings are not recommended to take the place of core, but in some circumstances, desorption work with cuttings can provide a timely and economic supplement to that of cores. The mixed lithologic nature of drill cuttings is primarily the source of uncertainty in their analysis for gas content, for it is unclear how to apportion the gas generated from both the coal and the dark-colored shale that is mixed in usually with the coal. In the Western Interior Basin Coal Basin in eastern Kansas (Pennsylvanian-age coals), dark-colored shales with normal (??? 100 API units) gamma-ray levels seem to give off minimal amounts of gas on the order of less than five standard cubic feet per ton (scf/ton). In some cuttings analyses this rule of thumb for gas content of the shale is adequate for inferring the gas content of coals, but shales with high-gamma-ray values (>150 API units) may yield several times this amount of gas. The uncertainty in desorption analysis of drill cuttings can be depicted graphically on a diagram identified as a "lithologic component sensitivity analysis diagram." Comparison of cuttings desorption results from nearby wells on this diagram, can sometimes yield an unique solution for the gas content of both a dark shale and coal mixed in a cuttings sample. A mathematical solution, based on equating the dry, ash-free gas-contents of the admixed coal and dark-colored shale, also yields results that are correlative to data from nearby cores. ?? 2007 International Association for Mathematical Geology.

Astrobiology Drilling Program of the NASA Astrobiology Institute

NASA Astrophysics Data System (ADS)

Runnegar, B.

2004-12-01

Access to unweathered and uncontaminated samples of the least altered, oldest, sedimentary rocks is essential for understanding the early history of life on Earth and the environments in which it may have existed. For this reason, the NASA Astrobiology Institute (NAI) has embarked on two international programs, a series of Field Workshops aimed at making the most important surface samples available to investigators, and the Astrobiology Drilling Program (ADP), which serves to provide access to fresh subsurface samples when the scientific objectives require them. The Astrobiology Drilling Program commenced in Western Australia in 2003 with the initiation of its first project, the Archean Biosphere Drilling Project (ABDP). Funding for the ABDP came mainly from the Japanese Government through Kagoshima University and from NASA through the NAI Team at Pennsylvania State University, but significant technical and logistic support was provided by the Geological of Western Australia and, to a lesser extent, by the University of Western Australia. Six diamond drill cores totalling 1.4 km were obtained from astrobiologically important successions in the 3.3-3.5 Ga-old Pilbara Craton of northern Western Australia. Drilling in 2004 also occurred in Western Australia. The Deep Time Drilling Project (DTDP), a spin-off from the NAI's Mission to Early Earth Focus Group, completed one long hole, aimed mainly at fossil biomolecules (biomarkers) and other geochemical indicators of early life. The DTDP and the ABDP also jointly drilled two other important holes 2004, one through the oldest known erosion surface (and possible soil profile). The other intersected well-preserved middle Archean sediments. These efforts parallel other drilling initiatives within the wider astrobiological community that are taking place in Western Australia, South Africa, Spain, and arctic Canada. The ADP is managed by the NAI through a Steering Committee appointed by the NAI Director. Samples of cores obtained through ADP projects are available to the whole community, following a one year embargo, upon application to project PIs and the ADP Steering Committee.

Reconstructing paleo-precipitation amounts using a terrestrial hydrologic model: Lake Titicaca and the Salar de Uyuni, Peru and Bolivia

NASA Astrophysics Data System (ADS)

Nunnery, J. A.; Baker, P. A.; Coe, M. T.; Fritz, S. C.

2010-12-01

The Peruvian/Bolivian Altiplano has provided many information-rich records bearing on the history of the South American summer monsoon (SASM), a large-scale circulation system that is responsible for much of the precipitation over the Amazon basin and the southern tropics and subtropics. Examples of these paleoclimate time series include long, drill core records from Lake Titicaca (extending back to ca. 400 Ka, Fritz et al., 2007), the long drill core record from Salar de Uyuni (> 250 Ka, Baker et al., 2001; Fritz et al., 2004), paleo-lake level records from the Salar de Uyuni (e.g. Bills et al., 2004; Placzek et al, 2006); drill core records from the Rio Desaguadero valley (Rigsby et al., 2003), and ice core records from Quelccaya, Illimani, and Sajama (Thompson et al., 2000; Ramirez et al., 2003). Several previous studies using energy and water balance models have been applied to these records in attempts to provide quantitative constraints on paleo-temperature and paleo-precipitation (e.g. Kessler, 1984; Hastenrath and Kutzbach, 1985; Cross et al, 2001; Rowe and Dunbar, 2004; Arnold, 2002; Blodgett et al., 1997). For example, Blodgett et al. concluded that high paleolake stands in the Bolivian Altiplano, dated at ca. 16,000 cal. Yr BP (Bills et al., 1994) required precipitation 20% higher than modern at temperatures 5°C colder than modern. However, their model did not take into account the major overflow from Lake Titicaca. Using the THMB hydrologic model, we show that overflow from Lake Titicaca is necessary to produce and sustain large lakes in the Salar de Uyuni basin. This hydrological connection (via the Rio Desaguadero) between the northern and southern Altiplano likely was only established about 60,000 years ago. Prior to that, there were no sustained, large and deep paleolakes on the southern Altiplano. Rather, drill core evidence indicates a very long sequence of shallow, hypersaline lakes and playas.

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnis Judzis; Homer Robertson; Alan Black

2006-06-22

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill ''faster and deeper'' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energymore » and loads. The significance of the ''ultra-high rotary speed drilling system'' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm-usually well below 5,000 rpm. This document details the progress at the end of Phase 1 on the program entitled ''Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling'' for the period starting 1 March 2006 and concluding 30 June 2006. (Note: Results from 1 September 2005 through 28 February 2006 were included in the previous report (see Judzis, Black, and Robertson)). Summarizing the accomplished during Phase 1: {lg_bullet} TerraTek reviewed applicable literature and documentation and convened a project kickoff meeting with Industry Advisors in attendance (see Black and Judzis). {lg_bullet} TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Some difficulties continued in obtaining ultra-high speed motors. Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more consistent product with consistent performance. A test matrix for the final core bit testing program was completed. {lg_bullet} TerraTek concluded Task 3 ''Small-scale cutting performance tests.'' {sm_bullet} Significant testing was performed on nine different rocks. {sm_bullet} Five rocks were used for the final testing. The final tests were based on statistical design of experiments. {sm_bullet} Two full-faced bits, a small diameter and a large diameter, were run in Berea sandstone. {lg_bullet} Analysis of data was completed and indicates that there is decreased specific energy as the rotational speed increases (Task 4). Data analysis from early trials was used to direct the efforts of the final testing for Phase I (Task 5). {lg_bullet} Technology transfer (Task 6) was accomplished with technical presentations to the industry (see Judzis, Boucher, McCammon, and Black).« less

Investigation of the electronic structure of Be2+He and Be+He, and static dipole polarisabilities of the helium atom

NASA Astrophysics Data System (ADS)

Dhiflaoui, J.; Bejaoui, M.; Farjallah, M.; Berriche, H.

2018-05-01

The potential energy and spectroscopic constants of the ground and many excited states of the Be+He van der Waals system have been investigated using a one-electron pseudo-potential approach, which is used to replace the effect of the Be2+ core and the electron-He interactions by effective potentials. Furthermore, the core-core interactions are incorporated. This permits the reduction of the number of active electrons of the Be+He van der Waals system to only one electron. Therefore, the potential energy of the ground state as well as the excited states is performed at the SCF level and considering the spin-orbit interaction. The core-core interaction for Be2+He ground state is included using accurate CCSD (T) calculations. Then, the spectroscopic properties of the Be+He electronic states are extracted and compared with the previous theoretical and experimental studies. This comparison has shown a very good agreement for the ground and the first excited states. Moreover, the transition dipole moment has been determined for a large and dense grid of internuclear distances including the spin orbit effect. In addition, a vibrational spacing analysis for the Be2+He and Be+He ground states is performed to extract the He atomic polarisability.

Summary of moderate depth lunar drill development program from its conception to 1 July 1972

NASA Technical Reports Server (NTRS)

1972-01-01

The results are summarized of a program aimed at the development of a lunar drill capable of taking lunar surface cores to depths of at least 100 feet. The technologies employed in the program are described along with the accomplishments and problems encountered. Recommendations are included for future concept improvements and developments.

Problematic p-benzyne: Orbital instabilities, biradical character, and broken symmetry

NASA Astrophysics Data System (ADS)

Crawford, T. Daniel; Kraka, Elfi; Stanton, John F.; Cremer, Dieter

2001-06-01

The equilibrium geometry, harmonic vibrational frequencies, and infrared transition intensities of p-benzyne were calculated at the MBPT(2), SDQ-MBPT(4), CCSD, and CCSD(T) levels of theory using different reference wave functions obtained from restricted and unrestricted Hartree-Fock (RHF and UHF), restricted Brueckner (RB) orbital, and Generalized Valence Bond (GVB) theory. RHF erroneously describes p-benzyne as a closed-shell singlet rather than a singlet biradical, which leads to orbital near-instabilities in connection with the mixing of orbital pairs b1u-ag (HOMO-LUMO), b2g-ag (HOMO-1-LUMO), and b1g-ag (HOMO-2-LUMO). Vibrational modes of the corresponding symmetries cause method-dependent anomalous increases (unreasonable force constants and infrared intensities) or decreases in the energy (breaking of the D2h symmetry of the molecular framework of p-benzyne). This basic failure of the RHF starting function is reduced by adding dynamic electron correlation. However RHF-MBPT(2), RHF-SDQ-MBPT(4), RHF-CCSD, RB-CCD, and RHF-CCSD(T) descriptions of p-benzyne are still unreliable as best documented by the properties of the b1u-, b2g-, and b1g-symmetrical vibrational modes. The first reliable spin-restricted description is provided when using Brueckner orbitals at the RB-CCD(T) level. GVB leads to exaggerated biradical character that is reduced at the GVB-MP2 level of theory. The best results are obtained with a UHF reference wave function, provided a sufficient account of dynamic electron correlation is included. At the UHF-CCSD level, the triplet contaminant is completely annihilated. UHF-CCSD(T) gives a reliable account of the infrared spectrum apart from a CCH bending vibrational mode, which is still in disagreement with experiment.

Accounting for the exact degeneracy and quasidegeneracy in the automerization of cyclobutadiene via multireference coupled-cluster methods.

PubMed

Li, Xiangzhu; Paldus, Josef

2009-09-21

The automerization of cyclobutadiene (CBD) is employed to test the performance of the reduced multireference (RMR) coupled-cluster (CC) method with singles and doubles (RMR CCSD) that employs a modest-size MR CISD wave function as an external source for the most important (primary) triples and quadruples in order to account for the nondynamic correlation effects in the presence of quasidegeneracy, as well as of its perturbatively corrected version accounting for the remaining (secondary) triples [RMR CCSD(T)]. The experimental results are compared with those obtained by the standard CCSD and CCSD(T) methods, by the state universal (SU) MR CCSD and its state selective or state specific (SS) version as formulated by Mukherjee et al. (SS MRCC or MkMRCC) and, wherever available, by the Brillouin-Wigner MRCC [MR BWCCSD(T)] method. Both restricted Hartree-Fock (RHF) and multiconfigurational self-consistent field (MCSCF) molecular orbitals are employed. For a smaller STO-3G basis set we also make a comparison with the exact full configuration interaction (FCI) results. Both fundamental vibrational energies-as obtained via the integral averaging method (IAM) that can handle anomalous potentials and automatically accounts for anharmonicity- and the CBD automerization barrier for the interconversion of the two rectangular structures are considered. It is shown that the RMR CCSD(T) potential has the smallest nonparallelism error relative to the FCI potential and the corresponding fundamental vibrational frequencies compare reasonably well with the experimental ones and are very close to those recently obtained by other authors. The effect of anharmonicity is assessed using the second-order perturbation theory (MP2). Finally, the invariance of the RMR CC methods with respect to orbital rotations is also examined.

Explicitly correlated coupled-cluster theory using cusp conditions. II. Treatment of connected triple excitations.

PubMed

Köhn, Andreas

2010-11-07

The coupled-cluster singles and doubles method augmented with single Slater-type correlation factors (CCSD-F12) determined by the cusp conditions (also denoted as SP ansatz) yields results close to the basis set limit with only small overhead compared to conventional CCSD. Quantitative calculations on many-electron systems, however, require to include the effect of connected triple excitations at least. In this contribution, the recently proposed [A. Köhn, J. Chem. Phys. 130, 131101 (2009)] extended SP ansatz and its application to the noniterative triples correction CCSD(T) is reviewed. The approach allows to include explicit correlation into connected triple excitations without introducing additional unknown parameters. The explicit expressions are presented and analyzed, and possible simplifications to arrive at a computationally efficient scheme are suggested. Numerical tests based on an implementation obtained by an automated approach are presented. Using a partial wave expansion for the neon atom, we can show that the proposed ansatz indeed leads to the expected (L(max)+1)(-7) convergence of the noniterative triples correction, where L(max) is the maximum angular momentum in the orbital expansion. Further results are reported for a test set of 29 molecules, employing Peterson's F12-optimized basis sets. We find that the customary approach of using the conventional noniterative triples correction on top of a CCSD-F12 calculation leads to significant basis set errors. This, however, is not always directly visible for total CCSD(T) energies due to fortuitous error compensation. The new approach offers a thoroughly explicitly correlated CCSD(T)-F12 method with improved basis set convergence of the triples contributions to both total and relative energies.

Overview of Hole GT2A: Drilling middle gabbro in Wadi Tayin massif, Oman ophiolite

NASA Astrophysics Data System (ADS)

Takazawa, E.; Kelemen, P. B.; Teagle, D. A. H.; Coggon, J. A.; Harris, M.; Matter, J. M.; Michibayashi, K.

2017-12-01

Hole GT2A (UTM: 40Q 655960.7E / 2529193.5N) was drilled by the Oman Drilling Project (OmDP) into Wadi Gideah of Wadi Tayin massif in the Samail ophiolite, Oman. OmDP is an international collaboration supported by the International Continental Scientific Drilling Program, the Deep Carbon Observatory, NSF, IODP, JAMSTEC, and the European, Japanese, German and Swiss Science Foundations, with in-kind support in Oman from the Ministry of Regional Municipalities and Water Resources, Public Authority of Mining, Sultan Qaboos University, and the German University of Technology. Hole GT2A was diamond cored in 25 Dec 2016 to 18 Jan 2017 to a total depth of 406.77 m. The outer surfaces of the cores were imaged and described on site before being curated, boxed and shipped to the IODP drill ship Chikyu, where they underwent comprehensive visual and instrumental analysis. 33 shipboard scientists were divided into six teams (Igneous, Alteration, Structural, Geochem, Physical Properties, Paleomag) to describe and analyze the cores. Hole GT2A drilled through the transition between foliated and layered gabbro. The transition zone occurs between 50 and 150 m curation corrected depth (CCD). The top 50 m of Hole GT2A is foliated gabbro whereas the bottom 250 m consists of layered gabbro. Brittle fracture is observed throughout the core. Intensity of alteration vein decreases from the top to the bottom of the hole. On the basis of changes in grain size and/or modal abundance and/or appearance/disappearance of igneous primary mineral(s) five lithological units are defined in Hole GT2A (Unit I to V). The uppermost part of Hole GT2A (Unit I) is dominated by fine-grained granular olivine gabbro intercalated with less dominant medium-grained granular olivine gabbro and rare coarse-grained varitextured gabbro. The lower part of the Hole (Units II, III and V) is dominated by medium-grained olivine gabbro, olivine melagabbro and olivine-bearing gabbro. Modally-graded rhythmic layering with olivine melagabbro and olivine-bearing gabbro is well conspicuous in the bottom part of Unit II. The Unit IV occurs between 284.25 m and 293.92 m CCD from the top of the hole and is characterized by orthopyroxene-bearing lithologies such as fine-grained gabbronorite and coarse-grained troctolite. Discrete orthopyroxene crystals occur in these lithologies.

Preliminary organic analyses of the DSDP /JOIDES/ cores - Legs V-IX.

NASA Technical Reports Server (NTRS)

Simoneit, B. R.; Burlingame, A. L.

1972-01-01

Descriptions of the methods used and results obtained in analyses of deep sea drilling cores. The analyses were performed in two phases (differing in degree of particularization) depending on the amount of core sample available. The results are presented in relation to the ages and to the fossil fauna and flora of the sediments.

Characterization of Vadose Zone Sediment: RCRA Borehole 299-E33-338 Located Near the B-BX-BY Waste Management Area

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lindenmeier, Clark W.; Serne, R. Jeffrey; Bjornstad, Bruce N.

2003-09-11

This report summarizes data collected from samples in borehole 299-E33-338 (C3391). Borehole 299-E33-338 was drilled for two purposes. One purpose was for installation of a RCRA ground-water monitoring well and the other was to characterize the in situ soils and background porewater chemistry near WMA B-BX-BY that have been largely uncontaminated by tank farm and crib and trench discharge operations. This borehole was drilled just outside the southeast fence line of the B tank farm. The borehole was drilled between July 23 and August 8, 2001 to a total depth of 80.05 m (275.75 ft) bgs using the cable-tool methodmore » (Horton 2002). The water table was contacted at 77.5 m (254.2 ft) bgs and the top of basalt at 82.6 m (271 ft) bgs. Samples to the top of basalt were collected via a drive barrel/splitspoon, before switching to a hard tool to drill 5 feet into the basalt. Nearly continuous core was obtained down to a depth of ~78.6 m (258 ft) bgs. Two hundred and two 2-ft long by 4-in diameter cores were retrieved, which accounts for ~75% the total length of the borehole. Each 2-ft splitspoon contained two 1-ft lexan-lined core segments. The lithology of this borehole was summarized onto a field geologist's log by a CH2M HILL Hanford Group, Inc. geologist (L. D. Walker); subsequently visual inspection of the cores was performed in the laboratory by K. A. Lindsey (Kennedy/Jenks), K. D. Reynolds (Duratek), and B. N. Bjornstad (Pacific Northwest National Laboratory), who also collected 24 samples for paleomagnetic analysis. Subsamples were taken from all 102 cores for moisture content (Table B.1). In addition, 21 core subsamples were collected from a depth of geological interest for mineralogical and geochemical analysis. Data from these samples allow for comparison of uncontaminated versus contaminated soils to better understand the contributions of tank wastes and other wastewaters on the vadose zone in and around WMA B-BX-BY.« less

Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

DOE Office of Scientific and Technical Information (OSTI.GOV)

TerraTek, A Schlumberger Company

2008-12-31

The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill 'faster and deeper' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energymore » and loads. The significance of the 'ultra-high rotary speed drilling system' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm - usually well below 5,000 rpm. This document provides the progress through two phases of the program entitled 'Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling' for the period starting 30 June 2003 and concluding 31 March 2009. The accomplishments of Phases 1 and 2 are summarized as follows: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance (see Black and Judzis); (2) TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more consistent product with consistent performance. A test matrix for the final core bit testing program was completed; (3) TerraTek concluded small-scale cutting performance tests; (4) Analysis of Phase 1 data indicated that there is decreased specific energy as the rotational speed increases; (5) Technology transfer, as part of Phase 1, was accomplished with technical presentations to the industry (see Judzis, Boucher, McCammon, and Black); (6) TerraTek prepared a design concept for the high speed drilling test stand, which was planned around the proposed high speed mud motor concept. Alternative drives for the test stand were explored; a high speed hydraulic motor concept was finally used; (7) The high speed system was modified to accommodate larger drill bits than originally planned; (8) Prototype mud turbine motors and the high speed test stand were used to drive the drill bits at high speed; (9) Three different rock types were used during the testing: Sierra White granite, Crab Orchard sandstone, and Colton sandstone. The drill bits used included diamond impregnated bits, a polycrystalline diamond compact (PDC) bit, a thermally stable PDC (TSP) bit, and a hybrid TSP and natural diamond bit; and (10) The drill bits were run at rotary speeds up to 5500 rpm and weight on bit (WOB) to 8000 lbf. During Phase 2, the ROP as measured in depth of cut per bit revolution generally increased with increased WOB. The performance was mixed with increased rotary speed, with the depth cut with the impregnated drill bit generally increasing and the TSP and hybrid TSP drill bits generally decreasing. The ROP in ft/hr generally increased with all bits with increased WOB and rotary speed. The mechanical specific energy generally improved (decreased) with increased WOB and was mixed with increased rotary speed.« less

Scientific Drilling in the Arctic Ocean: A challenge for the next decades

NASA Astrophysics Data System (ADS)

Stein, R.; Coakley, B.

2009-04-01

Although major progress in Arctic Ocean research has been made during the last decades, the knowledge of its short- and long-term paleoceanographic and paleoclimatic history as well as its plate-tectonic evolution is much behind that from the other world's oceans. That means - despite the importance of the Arctic in the climate system - the data base we have from this area is still very weak, and large parts of the climate history have not been recovered at all in sedimentary sections. This lack of knowledge is mainly caused by the major technological/ logistic problems in reaching this permanently ice-covered region with normal research vessels and in retrieving long and undisturbed sediment cores. With the successful completion of IODP Expedition 302 ("Arctic Coring Expedition" - ACEX), the first Mission Specific Platform (MSP) expedition within the Integrated Ocean Drilling Program - IODP, a new era in Arctic research has begun. For the first time, a scientific drilling in the permanently ice-covered Arctic Ocean was carried out, penetrating about 430 meters of Quaternary, Neogene, Paleogene and Campanian sediment on the crest of Lomonosov Ridge close to the North Pole. The success of ACEX has certainly opened the door for further scientific drilling in the Arctic Ocean, and will frame the next round of questions to be answered from new drill holes to be taken during the next decades. In order to discuss and plan the future of scientific drilling in the Arctic Ocean, an international workshop was held at the Alfred Wegener Institute (AWI) in Bremerhaven/Germany, (Nov 03-05, 2008; convenors: Bernard Coakley/University of Alaska Fairbanks and Ruediger Stein/AWI Bremerhaven). About 95 scientists from Europe, US, Canada, Russia, Japan, and Korea, and observers from oil companies participated in the workshop. Funding of the workshop was provided by the Consortium for Ocean Leadership (US), the European Science Foundation, the Arctic Ocean Sciences Board, and the Nansen Arctic Drilling Program as well as by sponsorships from British Petroleum, ConocoPhillips, ExxonMobil, Norwegian Petroleum Directorate, StatoilHydro, and Shell International. The major targets of the workshop were: (1) to bring together an international group of Arctic scientists, young scientists and ocean drilling scientists to learn and exchange ideas, experience and enthusiasm about the Arctic Ocean; (2) to develop a scientific drilling strategy to investigate the tectonic and paleoceanographic history of the Arctic Ocean and its role in influencing the global climate system; (3) to summarize the technical needs, opportunities, and limitations of drilling in the Arctic; (4) to define scientific and drilling targets for specific IODP-type campaigns in Arctic Ocean key areas to be finalized in the development of drilling proposals. Following overview presentations about the history of the Arctic Ocean, legacy of high-latitude ocean drilling, existing site-survey database, technical needs for high-latitude drilling, possibilities of collaboration with industry, and the process of developing ocean-drilling legs through IODP, the main part of the workshop was spent in thematic and regional break-out groups discussing the particular questions to be addressed by drilling and the particular targets for Arctic scientific drilling. Within the working groups, key scientific questions (related to the overall themes paleoceanography, tectonic evolution, petrology/geochemistry of basement, and gas hydrates) and strategies for reaching the overall goals were discussed and - as one of the main results - core groups for further developing drilling proposals were formed. Based on discussions at this workshop, approximately ten new pre-proposals are planned to be submitted to IODP for the April 01- 2009 deadline. We hope that the development of new scientific objectives through the pre-proposal process will help reshape plans for scientific ocean drilling beyond 2013 and direct the program north towards these critical priorities and advance exploration of the Arctic.

Coupled-cluster based approach for core-level states in condensed phase: Theory and application to different protonated forms of aqueous glycine

DOE PAGES

Sadybekov, Arman; Krylov, Anna I.

2017-07-07

A theoretical approach for calculating core-level states in condensed phase is presented. The approach is based on equation-of-motion coupled-cluster theory (EOMCC) and effective fragment potential (EFP) method. By introducing an approximate treatment of double excitations in the EOM-CCSD (EOM-CC with single and double substitutions) ansatz, we address poor convergence issues that are encountered for the core-level states and significantly reduce computational costs. While the approximations introduce relatively large errors in the absolute values of transition energies, the errors are systematic. Consequently, chemical shifts, changes in ionization energies relative to reference systems, are reproduced reasonably well. By using different protonation formsmore » of solvated glycine as a benchmark system, we show that our protocol is capable of reproducing the experimental chemical shifts with a quantitative accuracy. The results demonstrate that chemical shifts are very sensitive to the solvent interactions and that explicit treatment of solvent, such as EFP, is essential for achieving quantitative accuracy.« less

Optimizing Tensor Contraction Expressions for Hybrid CPU-GPU Execution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ma, Wenjing; Krishnamoorthy, Sriram; Villa, Oreste

2013-03-01

Tensor contractions are generalized multidimensional matrix multiplication operations that widely occur in quantum chemistry. Efficient execution of tensor contractions on Graphics Processing Units (GPUs) requires several challenges to be addressed, including index permutation and small dimension-sizes reducing thread block utilization. Moreover, to apply the same optimizations to various expressions, we need a code generation tool. In this paper, we present our approach to automatically generate CUDA code to execute tensor contractions on GPUs, including management of data movement between CPU and GPU. To evaluate our tool, GPU-enabled code is generated for the most expensive contractions in CCSD(T), a key coupledmore » cluster method, and incorporated into NWChem, a popular computational chemistry suite. For this method, we demonstrate speedup over a factor of 8.4 using one GPU (instead of one core per node) and over 2.6 when utilizing the entire system using hybrid CPU+GPU solution with 2 GPUs and 5 cores (instead of 7 cores per node). Finally, we analyze the implementation behavior on future GPU systems.« less

Coupled-cluster based approach for core-level states in condensed phase: Theory and application to different protonated forms of aqueous glycine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sadybekov, Arman; Krylov, Anna I.

A theoretical approach for calculating core-level states in condensed phase is presented. The approach is based on equation-of-motion coupled-cluster theory (EOMCC) and effective fragment potential (EFP) method. By introducing an approximate treatment of double excitations in the EOM-CCSD (EOM-CC with single and double substitutions) ansatz, we address poor convergence issues that are encountered for the core-level states and significantly reduce computational costs. While the approximations introduce relatively large errors in the absolute values of transition energies, the errors are systematic. Consequently, chemical shifts, changes in ionization energies relative to reference systems, are reproduced reasonably well. By using different protonation formsmore » of solvated glycine as a benchmark system, we show that our protocol is capable of reproducing the experimental chemical shifts with a quantitative accuracy. The results demonstrate that chemical shifts are very sensitive to the solvent interactions and that explicit treatment of solvent, such as EFP, is essential for achieving quantitative accuracy.« less

A Lift-Off-Tolerant Magnetic Flux Leakage Testing Method for Drill Pipes at Wellhead.

PubMed

Wu, Jianbo; Fang, Hui; Li, Long; Wang, Jie; Huang, Xiaoming; Kang, Yihua; Sun, Yanhua; Tang, Chaoqing

2017-01-21

To meet the great needs for MFL (magnetic flux leakage) inspection of drill pipes at wellheads, a lift-off-tolerant MFL testing method is proposed and investigated in this paper. Firstly, a Helmholtz coil magnetization method and the whole MFL testing scheme are proposed. Then, based on the magnetic field focusing effect of ferrite cores, a lift-off-tolerant MFL sensor is developed and tested. It shows high sensitivity at a lift-off distance of 5.0 mm. Further, the follow-up high repeatability MFL probing system is designed and manufactured, which was embedded with the developed sensors. It can track the swing movement of drill pipes and allow the pipe ends to pass smoothly. Finally, the developed system is employed in a drilling field for drill pipe inspection. Test results show that the proposed method can fulfill the requirements for drill pipe inspection at wellheads, which is of great importance in drill pipe safety.

A Lift-Off-Tolerant Magnetic Flux Leakage Testing Method for Drill Pipes at Wellhead

PubMed Central

Wu, Jianbo; Fang, Hui; Li, Long; Wang, Jie; Huang, Xiaoming; Kang, Yihua; Sun, Yanhua; Tang, Chaoqing

2017-01-01

To meet the great needs for MFL (magnetic flux leakage) inspection of drill pipes at wellheads, a lift-off-tolerant MFL testing method is proposed and investigated in this paper. Firstly, a Helmholtz coil magnetization method and the whole MFL testing scheme are proposed. Then, based on the magnetic field focusing effect of ferrite cores, a lift-off-tolerant MFL sensor is developed and tested. It shows high sensitivity at a lift-off distance of 5.0 mm. Further, the follow-up high repeatability MFL probing system is designed and manufactured, which was embedded with the developed sensors. It can track the swing movement of drill pipes and allow the pipe ends to pass smoothly. Finally, the developed system is employed in a drilling field for drill pipe inspection. Test results show that the proposed method can fulfill the requirements for drill pipe inspection at wellheads, which is of great importance in drill pipe safety. PMID:28117721

The structure and energetics of the HCN → HNC transition state

NASA Astrophysics Data System (ADS)

Lee, Timothy J.; Rendell, Alistair P.

1991-03-01

The optimum geometries and quadratic force constants of HCN, HNC and the transition state connecting them have been determined at the single and double excitation coupled-cluster (CCSD) and CCSD(T) levels of theory. Energy differences were evaluated using the CCSD and CCSD(T) methods in conjunction with large atomic natural orbital basis sets containing g-type basis functions on the heavy atoms and f-type functions on hydrogen. The most reliable structure obtained for the transition state has bond distances of 1.194, 1.188 and 1.389 Å for rCN, rCH and rNH, respectively. Including a correction for zero-point vibrational energies, the transition state is predicted to be 44.6 ± 1.0 kcal/mol above the HCN isomer, while HNC is predicted to be 14.4 ± 1.0 kcal/mol above HCN. The latter value is in excellent agreement with the most recent experimental determination (14.8 ± 2.0 kcal/mol).

Rare gases and Ca, Sr, and Ba in Apollo 17 drill-core fines

NASA Technical Reports Server (NTRS)

Pepin, R. O.; Dragon, J. C.; Johnson, N. L.; Bates, A.; Coscio, M. R., Jr.; Murthy, V. R.

1975-01-01

Trapped gas isotopic compositions and spallation gas concentrations as functions of depth in the Apollo 17 drill core were determined from mass spectrometer studies by means of correlation techniques. The distribution of He, Ne, Ar, Kr, and Xe as well as Ca, Sr, and Ba was investigated, and rare-gas spallation and neutron capture profiles are compared with attention to proposed depositional models for the Taurus-Littrow regolith. The data exclude a sedimentation pattern similar to that found at the Apollo 15 site but are possibly compatible with long-term continuous accretion models or models of very recent rapid accumulation of regolith.

Kimberly Well - Photos

DOE Data Explorer

Shervais, John

2011-06-16

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Kimberly drill hole was selected to document continuous volcanism when analysed in conjunction with the Kimama and is located near the margin of the plain. Data submitted by project collaborator Doug Schmitt, University of Alberta

Mountain Home Well - Borehole Geophysics Database

DOE Data Explorer

Shervais, John

2012-11-11

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Mountain Home drill hole is located along the western plain and documents older basalts overlain by sediment. Data submitted by project collaborator Doug Schmitt, University of Alberta

Kimberly Well - Borehole Geophysics Database

DOE Data Explorer

Shervais, John

2011-07-04

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Kimberly drill hole was selected to document continuous volcanism when analysed in conjunction with the Kimama and is located near the margin of the plain. Data submitted by project collaborator Doug Schmitt, University of Alberta

Improvement of core drill methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gatz, J.L.

1975-07-01

This report documents results of a program to evaluate effectiveness of more or less conventional subsurface samplers in obtaining representative and undisturbed samples of noncohesive alluvial materials containing large quantities of gravels and cobbles. This is the first phase of a research program to improve core drill methods. Samplers evaluated consisted of the Lawrence Livermore Laboratory membrane sampler, 4-in. Denison sampler, 6-in. Dension sampler, 5-in. Modified Denison sampler, and 3-in. thinwall drive tube. Small representative samples were obtained with the Dension samplers; no undisturbed samples were obtained. The field work was accomplished in the Rhodes Canyon area, White Sands Misslemore » Range, New Mexico.« less

Seismic-reflection data on the eastern U.S. continental shelf acquired by M. V. L'OLONNOIS as part of the Atlantic Margin Coring Project (AMCOR) of the U.S. Geological Survey, July-September 1976

USGS Publications Warehouse

Robb, James M.

1980-01-01

In 1976 the U.S. Geological Survey undertook a program to sample the eastern United States Shelf for stratigraphic information by drilling a set of core holes. Results of this Atlantic Margin Coring Program (AMCOR) have been reported by Hathaway and others. Sites were chosen from seismic-reflection data and were reviewed by a safety panel to minimize the risk of penetrating any hydrocarbon accumulation which might lead to environmental contamination.The M-V-L'OLONNOIS, the service ship for the drilling operation, was fitted with seismic-reflection profiling equipment (listed below), to run seismic-reflection profiles before drilling began on each hole. This provided additional assurance that no closed structures would be penetrated and allowed minor adjustment with the site selection. A total of 491 km of high-resolution seismic profiles was collected on 22 sites.Equipment used (specifics for each site noted on records): Bolt Air Guns 1-40 cubic inch chambers EPC Recorder Teledyne Minisparker (last two sites) Navigation used two Internav 101 Loran-C receivers.

Data file: the 1976 Atlantic Margin Coring (AMCOR) Project of the U.S. Geological Survey

USGS Publications Warehouse

Poppe, Lawrence J.; Poppe, Lawrence J.

1981-01-01

In 1976, the U.S. Geological Survey conducted the Atlantic Margin Coring Project (AMCOR) to obtain information on stratigraphy, hydrology and water chemistry, mineral resources other than petroleum hydrocarbons, and geotechnical engineering properties at sites widely distributed along the Continental Shelf and Slope of the Eastern United States (Hathaway and others, 1976, 1979). This program's primary purpose was to investigate a broad variety of sediment properties, many of which had not been previously studied in this region. Previous studies of sediments recovered by core drilling in this region were usually limited to one or two aspects of the sediment properties (Hathaway and others, 1979, table 2). The AMCOR program was limited by two factors: water depth and penetration depth. Because the ship selected for the program, the Glomar Conception, lacked dynamic positioning capability, its anchoring capacity determined the maximum water depth in which drilling could take place. Although it was equipped to anchor in water 450 m deep and did so successfully at one site, we attmepted no drilling in water depths greater than 300 m. Strong Gulf Stream currents at the one attempted deep (443 m) site frustrated attempts to "spud in" to begin the hole.

Fischer Assays of Oil Shale Drill Cores and Rotary Cuttings from the Piceance Basin, Colorado - 2009 Update

USGS Publications Warehouse

Mercier, Tracey J.; Brownfield, Michael E.; Johnson, Ronald C.; Self, Jesse G.

1998-01-01

This CD-ROM includes updated files containing Fischer assays of samples of core holes and cuttings from exploration drill holes drilled in the Eocene Green River Formation in the Piceance Basin of northwestern Colorado. A database was compiled that includes more than 321,380 Fischer assays from 782 boreholes. Most of the oil yield data were analyzed by the former U.S. Bureau of Mines oil shale laboratory in Laramie, Wyoming, and some analyses were made by private laboratories. Location data for 1,042 core and rotary holes, oil and gas tests, as well as a few surface sections are listed in a spreadsheet and included in the CD-ROM. These assays are part of a larger collection of subsurface information held by the U.S. Geological Survey, including geophysical and lithologic logs, water data, and chemical and X-ray diffraction analyses having to do with the Green River oil shale deposits in Colorado, Wyoming, and Utah. Because of an increased interest in oil shale, this CD-ROM disc containing updated Fischer assay data for the Piceance Basin oil shale deposits in northwestern Colorado is being released to the public.

El'gygytgyn impact crater, Chukotka, Arctic Russia: Impact cratering aspects of the 2009 ICDP drilling project

NASA Astrophysics Data System (ADS)

Koeberl, Christian; Pittarello, Lidia; Reimold, Wolf Uwe; Raschke, Ulli; Brigham-Grette, Julie; Melles, Martin; Minyuk, Pavel

2013-07-01

The El'gygytgyn impact structure in Chukutka, Arctic Russia, is the only impact crater currently known on Earth that was formed in mostly acid volcanic rocks (mainly of rhyolitic, with some andesitic and dacitic, compositions). In addition, because of its depth, it has provided an excellent sediment trap that records paleoclimatic information for the 3.6 Myr since its formation. For these two main reasons, because of the importance for impact and paleoclimate research, El'gygytgyn was the subject of an International Continental Scientific Drilling Program (ICDP) drilling project in 2009. During this project, which, due to its logistical and financial challenges, took almost a decade to come to fruition, a total of 642.3 m of drill core was recovered at two sites, from four holes. The obtained material included sedimentary and impactite rocks. In terms of impactites, which were recovered from 316.08 to 517.30 m depth below lake bottom (mblb), three main parts of that core segment were identified: from 316 to 390 mblb polymict lithic impact breccia, mostly suevite, with volcanic and impact melt clasts that locally contain shocked minerals, in a fine-grained clastic matrix; from 385 to 423 mblb, a brecciated sequence of volcanic rocks including both felsic and mafic (basalt) members; and from 423 to 517 mblb, a greenish rhyodacitic ignimbrite (mostly monomict breccia). The uppermost impactite (316-328 mblb) contains lacustrine sediment mixed with impact-affected components. Over the whole length of the impactite core, the abundance of shock features decreases rapidly from the top to the bottom of the studied core section. The distinction between original volcanic melt fragments and those that formed later as the result of the impact event posed major problems in the study of these rocks. The sequence that contains fairly unambiguous evidence of impact melt (which is not very abundant anyway, usually less than a few volume%) is only about 75 m thick. The reason for this rather thin fallback impactite sequence may be the location of the drill core on an elevated part of the central uplift. A general lack of large coherent melt bodies is evident, similar to that found at the similarly sized Bosumtwi impact crater in Ghana that, however, was formed in a target composed of a thin layer of sediment above crystalline rocks.

El'gygytgyn impact crater, Chukotka, Arctic Russia: Impact cratering aspects of the 2009 ICDP drilling project.

PubMed

Koeberl, Christian; Pittarello, Lidia; Reimold, Wolf Uwe; Raschke, Ulli; Brigham-Grette, Julie; Melles, Martin; Minyuk, Pavel; Spray, John

2013-07-01

The El'gygytgyn impact structure in Chukutka, Arctic Russia, is the only impact crater currently known on Earth that was formed in mostly acid volcanic rocks (mainly of rhyolitic, with some andesitic and dacitic, compositions). In addition, because of its depth, it has provided an excellent sediment trap that records paleoclimatic information for the 3.6 Myr since its formation. For these two main reasons, because of the importance for impact and paleoclimate research, El'gygytgyn was the subject of an International Continental Scientific Drilling Program (ICDP) drilling project in 2009. During this project, which, due to its logistical and financial challenges, took almost a decade to come to fruition, a total of 642.3 m of drill core was recovered at two sites, from four holes. The obtained material included sedimentary and impactite rocks. In terms of impactites, which were recovered from 316.08 to 517.30 m depth below lake bottom (mblb), three main parts of that core segment were identified: from 316 to 390 mblb polymict lithic impact breccia, mostly suevite, with volcanic and impact melt clasts that locally contain shocked minerals, in a fine-grained clastic matrix; from 385 to 423 mblb, a brecciated sequence of volcanic rocks including both felsic and mafic (basalt) members; and from 423 to 517 mblb, a greenish rhyodacitic ignimbrite (mostly monomict breccia). The uppermost impactite (316-328 mblb) contains lacustrine sediment mixed with impact-affected components. Over the whole length of the impactite core, the abundance of shock features decreases rapidly from the top to the bottom of the studied core section. The distinction between original volcanic melt fragments and those that formed later as the result of the impact event posed major problems in the study of these rocks. The sequence that contains fairly unambiguous evidence of impact melt (which is not very abundant anyway, usually less than a few volume%) is only about 75 m thick. The reason for this rather thin fallback impactite sequence may be the location of the drill core on an elevated part of the central uplift. A general lack of large coherent melt bodies is evident, similar to that found at the similarly sized Bosumtwi impact crater in Ghana that, however, was formed in a target composed of a thin layer of sediment above crystalline rocks.

El'gygytgyn impact crater, Chukotka, Arctic Russia: Impact cratering aspects of the 2009 ICDP drilling project

PubMed Central

Koeberl, Christian; Pittarello, Lidia; Reimold, Wolf Uwe; Raschke, Ulli; Brigham-Grette, Julie; Melles, Martin; Minyuk, Pavel; Spray, John

2013-01-01

The El'gygytgyn impact structure in Chukutka, Arctic Russia, is the only impact crater currently known on Earth that was formed in mostly acid volcanic rocks (mainly of rhyolitic, with some andesitic and dacitic, compositions). In addition, because of its depth, it has provided an excellent sediment trap that records paleoclimatic information for the 3.6 Myr since its formation. For these two main reasons, because of the importance for impact and paleoclimate research, El'gygytgyn was the subject of an International Continental Scientific Drilling Program (ICDP) drilling project in 2009. During this project, which, due to its logistical and financial challenges, took almost a decade to come to fruition, a total of 642.3 m of drill core was recovered at two sites, from four holes. The obtained material included sedimentary and impactite rocks. In terms of impactites, which were recovered from 316.08 to 517.30 m depth below lake bottom (mblb), three main parts of that core segment were identified: from 316 to 390 mblb polymict lithic impact breccia, mostly suevite, with volcanic and impact melt clasts that locally contain shocked minerals, in a fine-grained clastic matrix; from 385 to 423 mblb, a brecciated sequence of volcanic rocks including both felsic and mafic (basalt) members; and from 423 to 517 mblb, a greenish rhyodacitic ignimbrite (mostly monomict breccia). The uppermost impactite (316–328 mblb) contains lacustrine sediment mixed with impact-affected components. Over the whole length of the impactite core, the abundance of shock features decreases rapidly from the top to the bottom of the studied core section. The distinction between original volcanic melt fragments and those that formed later as the result of the impact event posed major problems in the study of these rocks. The sequence that contains fairly unambiguous evidence of impact melt (which is not very abundant anyway, usually less than a few volume%) is only about 75 m thick. The reason for this rather thin fallback impactite sequence may be the location of the drill core on an elevated part of the central uplift. A general lack of large coherent melt bodies is evident, similar to that found at the similarly sized Bosumtwi impact crater in Ghana that, however, was formed in a target composed of a thin layer of sediment above crystalline rocks. PMID:26074719

Stability analysis of Hawaiian Island flanks using insight gained from strength testing of the HSDP core

NASA Astrophysics Data System (ADS)

Thompson, Nick; Watters, Robert J.; Schiffman, Peter

2008-04-01

Hawaiian Island flank failures are recognized as the largest landslide events on Earth, reaching volumes of several thousand cubic kilometers and lengths of over 200 km and occurring on an average of once every 100 000 years. The 3.1 km deep Hawaii Scientific Drilling Project (HSDP) enabled an investigation of the rock mass strength variations on the island of Hawaii [Schiffman, P., Watters, R.J., Thompson, N., Walton, A.W., 2006. Hyaloclastites and the slope stability of Hawaiian volcanoes: insights from the Hawaiian Scientific Drilling Project's 3-km drill core. Journal of Volcanology and Geothermal Research, 151 (1-3): 217-228]. This study builds on that of Schiffman et al. [Schiffman, P., Watters, R.J., Thompson, N., Walton, A.W., 2006. Hyaloclastites and the slope stability of Hawaiian volcanoes: Insights from the Hawaiian Scientific Drilling Project's 3-km drill core. Journal of Volcanology and Geothermal Research, 151 (1-3): 217-228] by considering more in-depth rock mass classification and strength testing methods of the HSDP core. Geotechnical core logging techniques combined with laboratory strength testing methods show that rock strength differences exist within the edifice. Comparing the rock strength parameters obtained from the various volcano lithologies identified weak zones, suggesting the possible location of future slip surfaces for large flank failures. Relatively weak rock layers were recognized within poorly consolidated hyaloclastite zones, with increases in strength based on degree of alteration. Subaerial and submarine basalt flows are found to be significantly stronger. With the aid of digital elevation models, cross-sections have been developed of key flank areas on the island of Hawaii. Limit equilibrium slope stability analyses are performed on each cross-section using various failure criteria for the rock mass strength calculations. Based on the stability analyses the majority of the slopes analyzed are considered stable. In cases where instability (i.e. failure) is predicted, decreased rock mass quality (strength) of the altered and highly poorly consolidated lithologies is found to have a significant influence. These lithologies are present throughout the Hawaiian Islands, representing potential failure surfaces for large flank collapses. Failure criterion input parameters are considered in sensitivity analyses as are the influences of certain external stability factors such as sea level variation and seismic loading.

Outokumpu Deep Drill Hole: Window to the Precambrian bedrock

NASA Astrophysics Data System (ADS)

Heinonen, Suvi; Kietäväinen, Riikka; Ahonen, Lasse; Kukkonen, Ilmo

2017-04-01

Outokumpu Deep Drill Hole is located in eastern Finland, at latitude 62°43'4'' N and longitude 29°3'43'' E. This 2516 m long and fully cored deep hole has been utilized as a geolaboratory open for researchers worldwide since it was drilled in 2004-2005. The 220 mm diameter drill hole is open without a casing (excluding the uppermost 40 m) and thus provides a direct access to in situ conditions to 2.5 km depth. There is a wide range of wire-line logs carried out by the drilling contractor and later by ICDP (International Continental Scientific Drilling Program) in several logging sessions for geothermal, hydrogeological and deep biosphere studies. Lithology, metamorphism, fluid inclusions, density, magnetic properties, seismic velocities and thermal properties of the drill core have been studied by several international groups. The hole has kept open since the end of drilling enabling future studies to be conducted in it. The drill hole is situated in the southwestern part of the Outokumpu historical mining district famous for its Cu-Co-Zn sulfide deposits. These sulfide deposits are hosted by 1.96 Ga old ophiolitic rock types, known as the Outokumpu assemblage, also penetrated by the deep drill hole at 1314-1515 m depth. Laboratory and in situ petrophysical measurements have provided valuable information about physical properties of the typical rocks of the area that can be utilized in the mineral exploration efforts. The drill site of Outokumpu was chosen based on strong reflectivity observed in the high resolution seismic profiles acquired earlier in the area. Outokumpu Deep Drill Hole revealed that these reflections originate from the acoustic impedance variations caused by the ore hosting Outokumpu assemblage. In 2006, surface seismic reflection and vertical seismic profiling (VSP) data were measured in the drill site, and these data show that not only is Outokumpu assemblage rocks reflective but also water bearing fracture at 965 m depth is observed as a strong reflector. This fracture, as well as other fractures penetrated by the drill hole, contains saline water and gases, mainly methane, nitrogen, hydrogen and helium. Salinity of water in the deeper part (>1000 m) of the drill hole has continuously increased since the drilling. Gas-rich water slowly seeps upward and bubble out at the water table. In total, five different water types have been discerned along the drill hole by geochemical and isotopic methods and residence times up to 58 Ma indicated by the accumulation of noble gases. Microbiological studies in the Outokumpu Deep Drill Hole show that not only do different fracture zones act as places for shift in groundwater chemistry but also in the microbial communities. After a decade of research, Outokumpu drill hole site is geologically well known and thus provides a good environment to test new tools developed for exploration, microbiological or hydrogeological purposes, for example. Geological Survey of Finland is open for new research collaboration projects related to the drill site.

Are the results of multiple drilling and alendronate for osteonecrosis of the femoral head better than those of multiple drilling? A pilot study.

PubMed

Kang, Pengde; Pei, Fuxing; Shen, Bin; Zhou, Zongke; Yang, Jing

2012-01-01

The treatment of osteonecrosis of the femoral head (ONFH) remains controversial. A recently proposed treatment is multiple drilling core decompression combined with systemic alendronate as a femoral head-preserving procedure for ONFH. However, it is not known whether alendronate enhances the risk of collapse. We wondered whether the combined procedure could delay or prevent progression of ONFH compared to multiple drilling alone. Patients with early-stage ONFH were randomly assigned to be treated with either multiple drilling combined with alendronate (47 patients, 67 hips) or multiple drilling alone (46 patients, 60 hips). We defined failure as the need for THA or a Harris score less than 70. The minimum follow-up was 48 months for the 77 patients completing the protocol. After a minimum 4-year follow-up, 91% (40/44) of patients with Stage II disease and 62% (8/13) of patients with Stage III disease had not required THA in alendronate group, compared to 79% (31/39) of patients with Stage II disease and 46% (6/13) of patients with Stage III disease had not required THA in control group (P=0.12, P=0.047, respectively). Small or medium and central lesions had a better successful rate in both groups. Risk factors did not seem to affect the clinical successful rate of this procedure. Multiple small-diameter drilling core decompression combined with systemic alendronate administration can reduce pain and delay progression of early-stage ONFH. Even in Ficat IIA and III hips, some benefit was obtained from this approach at least delay in the need for THA. Copyright © 2011. Published by Elsevier SAS.

Assessment of Orbital-Optimized Third-Order Møller-Plesset Perturbation Theory and Its Spin-Component and Spin-Opposite Scaled Variants for Thermochemistry and Kinetics.

PubMed

Soydaş, Emine; Bozkaya, Uğur

2013-03-12

An assessment of the OMP3 method and its spin-component and spin-scaled variants for thermochemistry and kinetics is presented. For reaction energies of closed-shell systems, the CCSD, SCS-MP3, and SCS-OMP3 methods show better performances than other considered methods, and no significant improvement is observed due to orbital optimization. For barrier heights, OMP3 and SCS-OMP3 provide the lowest mean absolute deviations. The MP3 method yields considerably higher errors, and the spin scaling approaches do not help to improve upon MP3, but worsen it. For radical stabilization energies, the CCSD, OMP3, and SCS-OMP3 methods exhibit noticeably better performances than MP3 and its variants. Our results demonstrate that if the reference wave function suffers from a spin-contamination, then the MP3 methods dramatically fail. On the other hand, the OMP3 method and its variants can tolerate the spin-contamination in the reference wave function. For overall evaluation, we conclude that OMP3 is quite helpful, especially in electronically challenged systems, such as free radicals or transition states where spin contamination dramatically deteriorates the quality of the canonical MP3 and SCS-MP3 methods. Both OMP3 and CCSD methods scale as n(6), where n is the number of basis functions. However, the OMP3 method generally converges in much fewer iterations than CCSD. In practice, OMP3 is several times faster than CCSD in energy computations. Further, the stationary properties of OMP3 make it much more favorable than CCSD in the evaluation of analytic derivatives. For OMP3, the analytic gradient computations are much less expensive than CCSD. For the frequency computation, both methods require the evaluation of the perturbed amplitudes and orbitals. However, in the OMP3 case there is still a significant computational time savings due to simplifications in the analytic Hessian expression owing to the stationary property of OMP3. Hence, the OMP3 method emerges as a very useful tool for computational quantum chemistry.

Sea Ice Properties and Processes. Proceedings of the W. F. Weeks Sea Ice Symposium Held In San Francisco, California on December 1988

DTIC Science & Technology

1990-02-01

in the sample by inserting a probe thermometer into a transverse hole that was prepared with a hand drill . Then a portion of the ice was cut into...WeddellSea duringJuly-September 1986. holes drilled had the ice surface at or below sea level The symbols show positions where ice cores were at the...flux argument cannot be Table 3. Frequency of drilled statistically confirmed from the observations. holes with negative ice free- board. Measurement

IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frank R. Rack; Peter Schultheiss; Melanie Holland

The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) follow-up logging of pressure cores containing hydrate-bearing sediment; and (2) opening of some of these cores to establish ground-truth understanding. The follow-up measurements made on pressure cores in storage are part of a hydrate geriatric study related to ODP Leg 204. These activities are described in detail in Appendices A and B of this report. Work also continued on developing plans for Phase 2 of this cooperative agreement based on evolving plans to schedule a scientific ocean drilling expedition to study marine methane hydratesmore » along the Cascadia margin, in the NE Pacific as part of the Integrated Ocean Drilling Program (IODP) using the R/V JOIDES Resolution.« less

Physical analysis of an Antarctic ice core-towards an integration of micro- and macrodynamics of polar ice.

PubMed

Weikusat, Ilka; Jansen, Daniela; Binder, Tobias; Eichler, Jan; Faria, Sérgio H; Wilhelms, Frank; Kipfstuhl, Sepp; Sheldon, Simon; Miller, Heinrich; Dahl-Jensen, Dorthe; Kleiner, Thomas

2017-02-13

Microstructures from deep ice cores reflect the dynamic conditions of the drill location as well as the thermodynamic history of the drill site and catchment area in great detail. Ice core parameters (crystal lattice-preferred orientation (LPO), grain size, grain shape), mesostructures (visual stratigraphy) as well as borehole deformation were measured in a deep ice core drilled at Kohnen Station, Dronning Maud Land (DML), Antarctica. These observations are used to characterize the local dynamic setting and its rheological as well as microstructural effects at the EDML ice core drilling site (European Project for Ice Coring in Antarctica in DML). The results suggest a division of the core into five distinct sections, interpreted as the effects of changing deformation boundary conditions from triaxial deformation with horizontal extension to bedrock-parallel shear. Region 1 (uppermost approx. 450 m depth) with still small macroscopic strain is dominated by compression of bubbles and strong strain and recrystallization localization. Region 2 (approx. 450-1700 m depth) shows a girdle-type LPO with the girdle plane being perpendicular to grain elongations, which indicates triaxial deformation with dominating horizontal extension. In this region (approx. 1000 m depth), the first subtle traces of shear deformation are observed in the shape-preferred orientation (SPO) by inclination of the grain elongation. Region 3 (approx. 1700-2030 m depth) represents a transitional regime between triaxial deformation and dominance of shear, which becomes apparent in the progression of the girdle to a single maximum LPO and increasing obliqueness of grain elongations. The fully developed single maximum LPO in region 4 (approx. 2030-2385 m depth) is an indicator of shear dominance. Region 5 (below approx. 2385 m depth) is marked by signs of strong shear, such as strong SPO values of grain elongation and strong kink folding of visual layers. The details of structural observations are compared with results from a numerical ice sheet model (PISM, isotropic) for comparison of strain rate trends predicted from the large-scale geometry of the ice sheet and borehole logging data. This comparison confirms the segmentation into these depth regions and in turn provides a wider view of the ice sheet.This article is part of the themed issue 'Microdynamics of ice'. © 2016 The Authors.

Physical analysis of an Antarctic ice core-towards an integration of micro- and macrodynamics of polar ice*

NASA Astrophysics Data System (ADS)

Weikusat, Ilka; Jansen, Daniela; Binder, Tobias; Eichler, Jan; Faria, Sérgio H.; Wilhelms, Frank; Kipfstuhl, Sepp; Sheldon, Simon; Miller, Heinrich; Dahl-Jensen, Dorthe; Kleiner, Thomas

2017-02-01

Microstructures from deep ice cores reflect the dynamic conditions of the drill location as well as the thermodynamic history of the drill site and catchment area in great detail. Ice core parameters (crystal lattice-preferred orientation (LPO), grain size, grain shape), mesostructures (visual stratigraphy) as well as borehole deformation were measured in a deep ice core drilled at Kohnen Station, Dronning Maud Land (DML), Antarctica. These observations are used to characterize the local dynamic setting and its rheological as well as microstructural effects at the EDML ice core drilling site (European Project for Ice Coring in Antarctica in DML). The results suggest a division of the core into five distinct sections, interpreted as the effects of changing deformation boundary conditions from triaxial deformation with horizontal extension to bedrock-parallel shear. Region 1 (uppermost approx. 450 m depth) with still small macroscopic strain is dominated by compression of bubbles and strong strain and recrystallization localization. Region 2 (approx. 450-1700 m depth) shows a girdle-type LPO with the girdle plane being perpendicular to grain elongations, which indicates triaxial deformation with dominating horizontal extension. In this region (approx. 1000 m depth), the first subtle traces of shear deformation are observed in the shape-preferred orientation (SPO) by inclination of the grain elongation. Region 3 (approx. 1700-2030 m depth) represents a transitional regime between triaxial deformation and dominance of shear, which becomes apparent in the progression of the girdle to a single maximum LPO and increasing obliqueness of grain elongations. The fully developed single maximum LPO in region 4 (approx. 2030-2385 m depth) is an indicator of shear dominance. Region 5 (below approx. 2385 m depth) is marked by signs of strong shear, such as strong SPO values of grain elongation and strong kink folding of visual layers. The details of structural observations are compared with results from a numerical ice sheet model (PISM, isotropic) for comparison of strain rate trends predicted from the large-scale geometry of the ice sheet and borehole logging data. This comparison confirms the segmentation into these depth regions and in turn provides a wider view of the ice sheet. This article is part of the themed issue 'Microdynamics of ice'.

Optimization of the linear-scaling local natural orbital CCSD(T) method: Redundancy-free triples correction using Laplace transform.

PubMed

Nagy, Péter R; Kállay, Mihály

2017-06-07

An improved algorithm is presented for the evaluation of the (T) correction as a part of our local natural orbital (LNO) coupled-cluster singles and doubles with perturbative triples [LNO-CCSD(T)] scheme [Z. Rolik et al., J. Chem. Phys. 139, 094105 (2013)]. The new algorithm is an order of magnitude faster than our previous one and removes the bottleneck related to the calculation of the (T) contribution. First, a numerical Laplace transformed expression for the (T) fragment energy is introduced, which requires on average 3 to 4 times fewer floating point operations with negligible compromise in accuracy eliminating the redundancy among the evaluated triples amplitudes. Second, an additional speedup factor of 3 is achieved by the optimization of our canonical (T) algorithm, which is also executed in the local case. These developments can also be integrated into canonical as well as alternative fragmentation-based local CCSD(T) approaches with minor modifications. As it is demonstrated by our benchmark calculations, the evaluation of the new Laplace transformed (T) correction can always be performed if the preceding CCSD iterations are feasible, and the new scheme enables the computation of LNO-CCSD(T) correlation energies with at least triple-zeta quality basis sets for realistic three-dimensional molecules with more than 600 atoms and 12 000 basis functions in a matter of days on a single processor.

Optimization of the linear-scaling local natural orbital CCSD(T) method: Redundancy-free triples correction using Laplace transform

PubMed Central

2017-01-01

An improved algorithm is presented for the evaluation of the (T) correction as a part of our local natural orbital (LNO) coupled-cluster singles and doubles with perturbative triples [LNO-CCSD(T)] scheme [Z. Rolik et al., J. Chem. Phys. 139, 094105 (2013)]. The new algorithm is an order of magnitude faster than our previous one and removes the bottleneck related to the calculation of the (T) contribution. First, a numerical Laplace transformed expression for the (T) fragment energy is introduced, which requires on average 3 to 4 times fewer floating point operations with negligible compromise in accuracy eliminating the redundancy among the evaluated triples amplitudes. Second, an additional speedup factor of 3 is achieved by the optimization of our canonical (T) algorithm, which is also executed in the local case. These developments can also be integrated into canonical as well as alternative fragmentation-based local CCSD(T) approaches with minor modifications. As it is demonstrated by our benchmark calculations, the evaluation of the new Laplace transformed (T) correction can always be performed if the preceding CCSD iterations are feasible, and the new scheme enables the computation of LNO-CCSD(T) correlation energies with at least triple-zeta quality basis sets for realistic three-dimensional molecules with more than 600 atoms and 12 000 basis functions in a matter of days on a single processor. PMID:28576082

Probing phenylalanine/adenine pi-stacking interactions in protein complexes with explicitly correlated and CCSD(T) computations.

PubMed

Copeland, Kari L; Anderson, Julie A; Farley, Adam R; Cox, James R; Tschumper, Gregory S

2008-11-13

To examine the effects of pi-stacking interactions between aromatic amino acid side chains and adenine bearing ligands in crystalline protein structures, 26 toluene/(N9-methyl)adenine model configurations have been constructed from protein/ligand crystal structures. Full geometry optimizations with the MP2 method cause the 26 crystal structures to collapse to six unique structures. The complete basis set (CBS) limit of the CCSD(T) interaction energies has been determined for all 32 structures by combining explicitly correlated MP2-R12 computations with a correction for higher-order correlation effects from CCSD(T) calculations. The CCSD(T) CBS limit interaction energies of the 26 crystal structures range from -3.19 to -6.77 kcal mol (-1) and average -5.01 kcal mol (-1). The CCSD(T) CBS limit interaction energies of the optimized complexes increase by roughly 1.5 kcal mol (-1) on average to -6.54 kcal mol (-1) (ranging from -5.93 to -7.05 kcal mol (-1)). Corrections for higher-order correlation effects are extremely important for both sets of structures and are responsible for the modest increase in the interaction energy after optimization. The MP2 method overbinds the crystal structures by 2.31 kcal mol (-1) on average compared to 4.50 kcal mol (-1) for the optimized structures.

Drilling side holes from a borehole

NASA Technical Reports Server (NTRS)

Collins, E. R., Jr.

1980-01-01

Machine takes long horizontal stratum samples from confines of 21 cm bore hole. Stacked interlocking half cylindrical shells mate to form rigid thrust tube. Drive shaft and core storage device is flexible and retractable. Entire machine fits in 10 meter length of steel tube. Machine could drill drainage or ventilation holes in coal mines, or provide important information for geological, oil, and geothermal surveys.

Drill cutting and core major, trace and rare earth element anlayses from wells RN-17B and RN-30, Reykjanes, Iceland

DOE Data Explorer

Andrew Fowler

2015-05-01

Analytical results for x-ray fluorescence (XRF) and Inductively Couple Plasma Mass Spectrometry (ICP-MS) measurement of major, trace and rare earth elements in drill cuttings from geothermal wells in Reykjanes, Iceland. Total Fe was analyzed as FeO, therefore is not included under the Fe2O3 column.

Uncertainty analysis of depth predictions from seismic reflection data using Bayesian statistics

NASA Astrophysics Data System (ADS)

Michelioudakis, Dimitrios G.; Hobbs, Richard W.; Caiado, Camila C. S.

2018-03-01

Estimating the depths of target horizons from seismic reflection data is an important task in exploration geophysics. To constrain these depths we need a reliable and accurate velocity model. Here, we build an optimum 2D seismic reflection data processing flow focused on pre - stack deghosting filters and velocity model building and apply Bayesian methods, including Gaussian process emulation and Bayesian History Matching (BHM), to estimate the uncertainties of the depths of key horizons near the borehole DSDP-258 located in the Mentelle Basin, south west of Australia, and compare the results with the drilled core from that well. Following this strategy, the tie between the modelled and observed depths from DSDP-258 core was in accordance with the ± 2σ posterior credibility intervals and predictions for depths to key horizons were made for the two new drill sites, adjacent the existing borehole of the area. The probabilistic analysis allowed us to generate multiple realizations of pre-stack depth migrated images, these can be directly used to better constrain interpretation and identify potential risk at drill sites. The method will be applied to constrain the drilling targets for the upcoming International Ocean Discovery Program (IODP), leg 369.

Results of coal bed methane drilling, Mylan Park, Monongalia County, West Virginia

USGS Publications Warehouse

Ruppert, Leslie F.; Fedorko, Nick; Warwick, Peter D.; Grady, William C.; Crangle, Robert D.; Britton, James Q.

2004-01-01

The Department of Energy National Energy Technology Laboratory funded drilling of a borehole (39.64378 deg E , -80.04376 deg N) to evaluate the potential for coal bed methane and carbon dioxide sequestration at Mylan Park, Monongalia County, West Virginia. The drilling commenced on September 23, 2002 and was completed on November 14, 2002. The 2,525 ft deep hole contained 1,483.41 ft of Pennsylvanian coal-bearing strata, 739.67 feet of Mississippian strata, and 301.93 ft. of Devonian strata. The drill site was located directly over abandoned Pittsburgh and Sewickley coal mines. Coal cores from remaining mine pillars were cut and retrieved for desorption from both mines. In addition, coals were cored and desorbed from the Pittsburgh Roof, Little Pittsburgh, Elk Lick, Brush Creek, Upper Kittanning, Middle Kittanning, Clarion, Upper Mercer, Lower Mercer, and Quakertown coal beds. All coals are Pennsylvanian in age and are high-volatile-A bituminous in rank. A total of 34.75 ft of coal was desorbed over a maximum period of 662 days, although most of the coal was desorbed for about 275 days. This report is provided in Adobe Acrobat format. Appendix 3 is provided in Excel format.

Continental drilling for paleoclimatic records: Recommendations from an international workshop

USGS Publications Warehouse

Colman, Steve M.

1995-01-01

The Workshop, entitled "Continental Drilling for Paleoclimate Records", was sponsored by the Past Global Changes (PAGES) Project, a core project of the International Geosphere-Biosphere Programme (IGBP) and by the GeoForschungsZentrum, Potsdam, Germany, in conjunction with the International Continental Drilling Programme (ICDP). The impetus for the meeting was the need for long continental paleoclimate records that will fill gaps left by the marine and ice-core records and provide information on time and spatial scales that are relevant to human activities. Further impetus came from a perceived need to balance the forecasts and reconstructions of climate models with information on actual behavior of the climate system on the continents. The meeting was organized by Steven M. Colman, Suzanne A.G. Leroy, and Jörg F.W. Negendank and was held at the GeoForschungsZentrum, Potsdam, Germany, June 30-July 2, 1995. Because the Workshop was primarily a working meeting, a relatively small number of participants were invited (Appendix 3). Leaders of the PAGES Pole-Equator-Pole (PEP) transects and existing large-lake drilling programs, along with a mixture of technical experts, were the primary group of attendees.

Finding Faults: Tohoku and other Active Megathrusts/Megasplays

NASA Astrophysics Data System (ADS)

Moore, J. C.; Conin, M.; Cook, B. J.; Kirkpatrick, J. D.; Remitti, F.; Chester, F.; Nakamura, Y.; Lin, W.; Saito, S.; Scientific Team, E.

2012-12-01

Current subduction-fault drilling procedure is to drill a logging hole, identify target faults, then core and instrument them. Seismic data may constrain faults but the additional resolution of borehole logs is necessary for efficient coring and instrumentation under difficult conditions and tight schedules. Thus, refining the methodology of identifying faults in logging data has become important, and thus comparison of log signatures of faults in different locations is worthwhile. At the C0019 (JFAST) drill site, the Tohoku megathrust was principally identified as a decollement where steep cylindrically-folded bedding abruptly flattens below the basal detachment. A similar structural contrast occurs across a megasplay fault in the NanTroSEIZE transect (Site C0004). At the Tohoku decollement, a high gamma-ray value from a pelagic clay layer, predicted as a likely decollement sediment type, strengthens the megathrust interpretation. The original identification of the pelagic clay as a decollement candidate was based on results of previous coring of an oceanic reference site. Negative density anomalies, often seen as low resistivity zones, identified a subsidiary fault in the deformed prism overlying the Tohoku megathrust. Elsewhere, at Barbados, Nankai (Moroto), and Costa Rica, negative density anomalies are associated with the decollement and other faults in hanging walls. Log-based density anomalies in fault zones provide a basis for recognizing in-situ fault zone dilation. At the Tohoku Site C0019, breakouts are present above but not below the megathrust. Changes in breakout orientation and width (stress magnitude) occur across megasplay faults at Sites C0004 and C0010 in the NantroSEIZE transect. Annular pressure anomalies are not apparent at the Tohoku megathrust, but are variably associated with faults and fracture zones drilled along the NanTroSEIZE transect. Overall, images of changes in structural features, negative density anomalies, and changes in breakout occurrence and orientation provide the most common log criteria for recognizing major thrust zones in ocean drilling holes at convergent margins. In the case of JFAST, identification of faults by logging was confirmed during subsequent coring activities, and logging data was critical for successful placement of the observatory down hole.

Melt in the impact breccias from the Eyreville drill cores, Chesapeake Bay impact structure, USA

NASA Astrophysics Data System (ADS)

Bartosova, Katerina; Hecht, Lutz; Koeberl, Christian; Libowitzky, Eugen; Reimold, Wolf Uwe

2011-03-01

The center of the 35.3 Ma Chesapeake Bay impact structure (85 km diameter) was drilled during 2005/2006 in an ICDP-0USGS drilling project. The Eyreville drill cores include polymict impact breccias and associated rocks (1397-01551 m depth). Tens of melt particles from these impactites were studied by optical and electron microscopy, electron microprobe, and microRaman spectroscopy, and classified into six groups: m1—clear or brownish melt, m2—brownish melt altered to phyllosilicates, m3—colorless silica melt, m4—melt with pyroxene and plagioclase crystallites, m5—dark brown melt, and m6—melt with globular texture. These melt types have partly overlapping major element abundances, and large compositional variations due to the presence of schlieren, poorly mixed melt phases, partly digested clasts, and variable crystallization and alteration. The different melt types also vary in their abundance with depth in the drill core. Based on the chemical data, mixing calculations were performed to determine possible precursors of these melt particles. The calculations suggest that most melt types formed mainly from the thick sedimentary section of the target sequence (mainly the Potomac Formation), but an additional crystalline basement (schist/gneiss) precursor is likely for the most abundant melt types m2 and m5. Sedimentary rocks with compositions similar to those of the melt particles are present among the Eyreville core samples. Therefore, sedimentary target rocks were the main precursor of the Eyreville melt particles. However, the composition of the melt particles is not only the result of the precursor composition but also the result of changes during melting and solidification, as well as postimpact alteration, which must also be considered. The variability of the melt particle compositions reflects the variety of target rocks and indicates that there was no uniform melt source. Original heterogeneities, resulting from melting of different target rocks, may be preserved in impactites of some large impact structures that formed in volatile-rich targets, because no large melt body exists, in which homogenization would have taken place.

Inclusion of orbital relaxation and correlation through the unitary group adapted open shell coupled cluster theory using non-relativistic and scalar relativistic Hamiltonians to study the core ionization potential of molecules containing light to medium-heavy elements

NASA Astrophysics Data System (ADS)

Sen, Sangita; Shee, Avijit; Mukherjee, Debashis

2018-02-01

The orbital relaxation attendant on ionization is particularly important for the core electron ionization potential (core IP) of molecules. The Unitary Group Adapted State Universal Coupled Cluster (UGA-SUMRCC) theory, recently formulated and implemented by Sen et al. [J. Chem. Phys. 137, 074104 (2012)], is very effective in capturing orbital relaxation accompanying ionization or excitation of both the core and the valence electrons [S. Sen et al., Mol. Phys. 111, 2625 (2013); A. Shee et al., J. Chem. Theory Comput. 9, 2573 (2013)] while preserving the spin-symmetry of the target states and using the neutral closed-shell spatial orbitals of the ground state. Our Ansatz invokes a normal-ordered exponential representation of spin-free cluster-operators. The orbital relaxation induced by a specific set of cluster operators in our Ansatz is good enough to eliminate the need for different sets of orbitals for the ground and the core-ionized states. We call the single configuration state function (CSF) limit of this theory the Unitary Group Adapted Open-Shell Coupled Cluster (UGA-OSCC) theory. The aim of this paper is to comprehensively explore the efficacy of our Ansatz to describe orbital relaxation, using both theoretical analysis and numerical performance. Whenever warranted, we also make appropriate comparisons with other coupled-cluster theories. A physically motivated truncation of the chains of spin-free T-operators is also made possible by the normal-ordering, and the operational resemblance to single reference coupled-cluster theory allows easy implementation. Our test case is the prediction of the 1s core IP of molecules containing a single light- to medium-heavy nucleus and thus, in addition to demonstrating the orbital relaxation, we have addressed the scalar relativistic effects on the accuracy of the IPs by using a hierarchy of spin-free Hamiltonians in conjunction with our theory. Additionally, the contribution of the spin-free component of the two-electron Gaunt term, not usually taken into consideration, has been estimated at the Self-Consistent Field (ΔSCF) level and is found to become increasingly important and eventually quite prominent for molecules with third period atoms and below. The accuracies of the IPs computed using UGA-OSCC are found to be of the same order as the Coupled Cluster Singles Doubles (ΔCCSD) values while being free from spin contamination. Since the UGA-OSCC uses a common set of orbitals for the ground state and the ion, it obviates the need of two N5 AO to MO transformation in contrast to the ΔCCSD method.

Inclusion of orbital relaxation and correlation through the unitary group adapted open shell coupled cluster theory using non-relativistic and scalar relativistic Hamiltonians to study the core ionization potential of molecules containing light to medium-heavy elements.

PubMed

Sen, Sangita; Shee, Avijit; Mukherjee, Debashis

2018-02-07

The orbital relaxation attendant on ionization is particularly important for the core electron ionization potential (core IP) of molecules. The Unitary Group Adapted State Universal Coupled Cluster (UGA-SUMRCC) theory, recently formulated and implemented by Sen et al. [J. Chem. Phys. 137, 074104 (2012)], is very effective in capturing orbital relaxation accompanying ionization or excitation of both the core and the valence electrons [S. Sen et al., Mol. Phys. 111, 2625 (2013); A. Shee et al., J. Chem. Theory Comput. 9, 2573 (2013)] while preserving the spin-symmetry of the target states and using the neutral closed-shell spatial orbitals of the ground state. Our Ansatz invokes a normal-ordered exponential representation of spin-free cluster-operators. The orbital relaxation induced by a specific set of cluster operators in our Ansatz is good enough to eliminate the need for different sets of orbitals for the ground and the core-ionized states. We call the single configuration state function (CSF) limit of this theory the Unitary Group Adapted Open-Shell Coupled Cluster (UGA-OSCC) theory. The aim of this paper is to comprehensively explore the efficacy of our Ansatz to describe orbital relaxation, using both theoretical analysis and numerical performance. Whenever warranted, we also make appropriate comparisons with other coupled-cluster theories. A physically motivated truncation of the chains of spin-free T-operators is also made possible by the normal-ordering, and the operational resemblance to single reference coupled-cluster theory allows easy implementation. Our test case is the prediction of the 1s core IP of molecules containing a single light- to medium-heavy nucleus and thus, in addition to demonstrating the orbital relaxation, we have addressed the scalar relativistic effects on the accuracy of the IPs by using a hierarchy of spin-free Hamiltonians in conjunction with our theory. Additionally, the contribution of the spin-free component of the two-electron Gaunt term, not usually taken into consideration, has been estimated at the Self-Consistent Field (ΔSCF) level and is found to become increasingly important and eventually quite prominent for molecules with third period atoms and below. The accuracies of the IPs computed using UGA-OSCC are found to be of the same order as the Coupled Cluster Singles Doubles (ΔCCSD) values while being free from spin contamination. Since the UGA-OSCC uses a common set of orbitals for the ground state and the ion, it obviates the need of two N 5 AO to MO transformation in contrast to the ΔCCSD method.

Hydrothermal Alteration of Open Fractures in Prospective Geothermal Drill Cores, Akutan Island, Alaska

NASA Astrophysics Data System (ADS)

Kent, T.

2011-12-01

The goal of this study is to constrain the most recent thermal alteration of two drill cores (HSB2/HSB4) from the Island of Akutan in the Aleutian Islands of Alaska. These cores are characterized by identifying mineralogy using x-ray diffraction spectra, energy dispersive spectroscopy with a scanning electron microscope and optical mineralogy. This is then compared with the coincident thermal data gathered on site in order to help constrain the most recent thermal activity of this dynamic resource. Using multiple temperature diagnostic minerals and their paragenesis, a relative thermal history is produced of expansive propylitic alteration. When combined with the wireline temperature gradients of the cores a model of downward migration emerges. Shallow occurrences of high temperature minerals that lie above the boiling point to depth curve indicate higher hydrostatic pressures in the past which can be attributed to a combination of glacial effects, including a significant amount of glacial erosion that is recognized due to a lack of significant clay cap to the geothermal resource.

PDC-bit performance under simulated borehole conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, E.E.; Azar, J.J.

1993-09-01

Laboratory drilling tests were used to investigate the effects of pressure on polycrystalline-diamond-compact (PDC) drill-bit performance. Catoosa shale core samples were drilled with PDC and roller-cone bits at up to 1,750-psi confining pressure. All tests were conducted in a controlled environment with a full-scale laboratory drilling system. Test results indicate, that under similar operating conditions, increases in confining pressure reduce PDC-bit performance as much as or more than conventional-rock-bit performance. Specific energy calculations indicate that a combination of rock strength, chip hold-down, and bit balling may have reduced performance. Quantifying the degree to which pressure reduces PDC-bit performance will helpmore » researchers interpret test results and improve bit designs and will help drilling engineers run PDC bits more effectively in the field.« less

Sub-Ocean Drilling

NASA Technical Reports Server (NTRS)

1981-01-01

The National Science Foundation (NSF) initialized a new phase of exploration last year, a 10 year effort jointly funded by NSF and several major oil companies, known as the Ocean Margin Drilling Program (OMDP). The OMDP requires a ship with capabilities beyond existing drill ships; it must drill in 13,000 feet of water to a depth 20,000 feet below the ocean floor. To meet requirements, NSF is considering the conversion of the government-owned mining ship Glomar Explorer to a deep ocean drilling and coring vessel. Feasibility study performed by Donhaiser Marine, Inc. analyzed the ship's characteristics for suitability and evaluated conversion requirement. DMI utilized COSMIC's Ship Motion and Sea Load Computer program to perform analysis which could not be accomplished by other means. If approved for conversion, Glomar Explorer is expected to begin operations as a drillship in 1984.

Stress induced near fault-zone breakout rotation: Two case studies in TCDP and JFAST

NASA Astrophysics Data System (ADS)

Wu, H. Y.; Brodsky, E. E.; Moe, K.; Kinoshita, M.

2014-12-01

Within the past decade, two successful rapid-response drilling projects have measured breakouts within the nearfault of a recently ruptured fault. Breakout observation is the direct way to detect the far and near filed stress orientation in drilling. Here we compare those data. In 2006, ICDP performed an inland drilling project to penetrate Chelungpu fault plane in central of Taiwan, which had recently slipped in 1999 Mw 7.6 Chi-Chi earthquake. This drilling project succeeded in full coring and collecting comprehensive logging data in the borehole. The resistivity images run by Formation Micro Imager (FMI) indicated that a breakout rotation in the vicinity of the fault (1111mbf). Leak-off tests on site constrained the magnitude of minimum horizontal principal stress. Here we use these data to determine the stress variation in the fault plane in our breakout dislocation model. Based on the amount of breakout azimuth, rotation and fault geometry, the stress drop can be estimated in this model. In 2012, IODP initiated a rapid drilling project after the 2011 Mw9.0 Tohoku earthquake in Japan Trench. Due to the deep-water depth, only a real-time resistivity image recorded by Logging While Drilling (LWD) and few core samples are recovered by this expedition. However, the breakout azimuth occurred near the plate boundary (820mbsf) represents the stress disturbance after the dramatic slip comparing to TCDP case. In this research, we are attempting to discuss the possible effect factors and reconstruct the geo-mechanical models to interpret the breakout distribution observed from logging data and the stress state after these huge earthquakes.

Benchmark ab Initio Characterization of the Complex Potential Energy Surfaces of the X- + NH2Y [X, Y = F, Cl, Br, I] Reactions.

PubMed

Hajdu, Bálint; Czakó, Gábor

2018-02-22

We report a comprehensive high-level explicitly correlated ab initio study on the X - + NH 2 Y [X,Y = F, Cl, Br, I] reactions characterizing the stationary points of the S N 2 (Y - + NH 2 X) and proton-transfer (HX + NHY - ) pathways as well as the reaction enthalpies of various endothermic additional product channels such as H - + NHXY, XY - + NH 2 , XY + NH 2 - , and XHY - + NH. Benchmark structures and harmonic vibrational frequencies are obtained at the CCSD(T)-F12b/aug-cc-pVTZ(-PP) level of theory, followed by CCSD(T)-F12b/aug-cc-pVnZ(-PP) [n = Q and 5] and core correlation energy computations. In the entrance and exit channels we find two equivalent hydrogen-bonded C 1 minima, X - ···HH'NY and X - ···H'HNY connected by a C s first-order saddle point, X - ···H 2 NY, as well as a halogen-bonded front-side complex, X - ···YNH 2 . S N 2 reactions can proceed via back-side attack Walden inversion and front-side attack retention pathways characterized by first-order saddle points, submerged [X-NH 2 -Y] - and high-energy [H 2 NXY] - , respectively. Product-like stationary points below the HX + NHY - asymptotes are involved in the proton-transfer processes.

An Accurate ab initio Quartic Force Field and Vibrational Frequencies for CH4 and Isotopomers

NASA Technical Reports Server (NTRS)

Lee, Timothy J.; Martin, Jan M. L.; Taylor, Peter R.

1995-01-01

A very accurate ab initio quartic force field for CH4 and its isotopomers is presented. The quartic force field was determined with the singles and doubles coupled-cluster procedure that includes a quasiperturbative estimate of the effects of connected triple excitations, CCSD(T), using the correlation consistent polarized valence triple zeta, cc-pVTZ, basis set. Improved quadratic force constants were evaluated with the correlation consistent polarized valence quadruple zeta, cc-pVQZ, basis set. Fundamental vibrational frequencies are determined using second-order perturbation theory anharmonic analyses. All fundamentals of CH4 and isotopomers for which accurate experimental values exist and for which there is not a large Fermi resonance, are predicted to within +/- 6 cm(exp -1). It is thus concluded that our predictions for the harmonic frequencies and the anharmonic constants are the most accurate estimates available. It is also shown that using cubic and quartic force constants determined with the correlation consistent polarized double zeta, cc-pVDZ, basis set in conjunction with the cc-pVQZ quadratic force constants and equilibrium geometry leads to accurate predictions for the fundamental vibrational frequencies of methane, suggesting that this approach may be a viable alternative for larger molecules. Using CCSD(T), core correlation is found to reduce the CH4 r(e), by 0.0015 A. Our best estimate for r, is 1.0862 +/- 0.0005 A.

Composite vibrational spectroscopy of the group 12 difluorides: ZnF2, CdF2, and HgF2.

PubMed

Solomonik, Victor G; Smirnov, Alexander N; Navarkin, Ilya S

2016-04-14

The vibrational spectra of group 12 difluorides, MF2 (M = Zn, Cd, Hg), were investigated via coupled cluster singles, doubles, and perturbative triples, CCSD(T), including core correlation, with a series of correlation consistent basis sets ranging in size from triple-zeta through quintuple-zeta quality, which were then extrapolated to the complete basis set (CBS) limit using a variety of extrapolation procedures. The explicitly correlated coupled cluster method, CCSD(T)-F12b, was employed as well. Although exhibiting quite different convergence behavior, the F12b method yielded the CBS limit estimates closely matching more computationally expensive conventional CBS extrapolations. The convergence with respect to basis set size was examined for the contributions entering into composite vibrational spectroscopy, including those from higher-order correlation accounted for through the CCSDT(Q) level of theory, second-order spin-orbit coupling effects assessed within four-component and two-component relativistic formalisms, and vibrational anharmonicity evaluated via a perturbative treatment. Overall, the composite results are in excellent agreement with available experimental values, except for the CdF2 bond-stretching frequencies compared to spectral assignments proposed in a matrix isolation infrared and Raman study of cadmium difluoride vapor species [Loewenschuss et al., J. Chem. Phys. 50, 2502 (1969); Givan and Loewenschuss, J. Chem. Phys. 72, 3809 (1980)]. These assignments are called into question in the light of the composite results.

Composite vibrational spectroscopy of the group 12 difluorides: ZnF2, CdF2, and HgF2

NASA Astrophysics Data System (ADS)

Solomonik, Victor G.; Smirnov, Alexander N.; Navarkin, Ilya S.

2016-04-01

The vibrational spectra of group 12 difluorides, MF2 (M = Zn, Cd, Hg), were investigated via coupled cluster singles, doubles, and perturbative triples, CCSD(T), including core correlation, with a series of correlation consistent basis sets ranging in size from triple-zeta through quintuple-zeta quality, which were then extrapolated to the complete basis set (CBS) limit using a variety of extrapolation procedures. The explicitly correlated coupled cluster method, CCSD(T)-F12b, was employed as well. Although exhibiting quite different convergence behavior, the F12b method yielded the CBS limit estimates closely matching more computationally expensive conventional CBS extrapolations. The convergence with respect to basis set size was examined for the contributions entering into composite vibrational spectroscopy, including those from higher-order correlation accounted for through the CCSDT(Q) level of theory, second-order spin-orbit coupling effects assessed within four-component and two-component relativistic formalisms, and vibrational anharmonicity evaluated via a perturbative treatment. Overall, the composite results are in excellent agreement with available experimental values, except for the CdF2 bond-stretching frequencies compared to spectral assignments proposed in a matrix isolation infrared and Raman study of cadmium difluoride vapor species [Loewenschuss et al., J. Chem. Phys. 50, 2502 (1969); Givan and Loewenschuss, J. Chem. Phys. 72, 3809 (1980)]. These assignments are called into question in the light of the composite results.

Arctic Ocean Paleoceanography and Future IODP Drilling

NASA Astrophysics Data System (ADS)

Stein, Ruediger

2015-04-01

Although the Arctic Ocean is a major player in the global climate/earth system, this region is one of the last major physiographic provinces on Earth where the short- and long-term geological history is still poorly known. This lack in knowledge is mainly due to the major technological/logistical problems in operating within the permanently ice-covered Arctic region which makes it difficult to retrieve long and undisturbed sediment cores. Prior to 2004, in the central Arctic Ocean piston and gravity coring was mainly restricted to obtaining near-surface sediments, i.e., only the upper 15 m could be sampled. Thus, all studies were restricted to the late Pliocene/Quaternary time interval, with a few exceptions. These include the four short cores obtained by gravity coring from drifting ice floes over the Alpha Ridge, where older pre-Neogene organic-carbon-rich muds and laminated biosiliceous oozes were sampled. Continuous central Arctic Ocean sedimentary records, allowing a development of chronologic sequences of climate and environmental change through Cenozoic times and a comparison with global climate records, however, were missing prior to the IODP Expedition 302 (Arctic Ocean Coring Expedition - ACEX), the first scientific drilling in the central Arctic Ocean. By studying the unique ACEX sequence, a large number of scientific discoveries that describe previously unknown Arctic paleoenvironments, were obtained during the last decade (for most recent review and references see Stein et al., 2014). While these results from ACEX were unprecedented, key questions related to the climate history of the Arctic Ocean remain unanswered, in part because of poor core recovery, and in part because of the possible presence of a major mid-Cenozoic hiatus or interval of starved sedimentation within the ACEX record. In order to fill this gap in knowledge, international, multidisciplinary expeditions and projects for scientific drilling/coring in the Arctic Ocean are needed. Key areas and approaches for drilling and recovering undisturbed and complete sedimentary sequences are depth transects across the major ocean ridge systems, such as the Lomonosov Ridge. These new detailed climate records spanning time intervals from the (late Cretaceous/)Paleogene Greenhouse world to the Neogene-Quaternary Icehouse world will give new insights into our understanding of the Arctic Ocean within the global climate system and provide an opportunity to test the performance of climate models used to predict future climate change. During the Polarstern Expedition PS87 in August-September 2014, new site survey data including detailed multibeam bathymetry, multi-channel seismic and Parasound profiling as well as geological coring, were obtained on Lomonosov Ridge (Stein, 2015), being the basis for a more precise planning and update for a future IODP drilling campaign. Reference: Stein, R. (Ed.), 2015. Cruise Report of Polarstern Expedition PS87-2014 (Arctic Ocean/Lomonosov Ridge). Reps. Pol. Mar. Res., in press. Stein, R. , Weller, P. , Backman, J. , Brinkhuis, H., Moran, K. , Pälike, H., 2014. Cenozoic Arctic Ocean Climate History: Some highlights from the IODP Arctic Coring Expedition (ACEX). Developments in Marine Geology 7, Elsevier Amsterdam/New York, pp. 259-293.

Fischer Assays of Oil-Shale Drill Cores and Rotary Cuttings from the Greater Green River Basin, Southwestern Wyoming

USGS Publications Warehouse

,

2008-01-01

Chapter 1 of this CD-ROM is a database of digitized Fischer (shale-oil) assays of cores and cuttings from boreholes drilled in the Eocene Green River oil shale deposits in southwestern Wyoming. Assays of samples from some surface sections are also included. Most of the Fischer assay analyses were made by the former U.S. Bureau of Mines (USBM) at its laboratory in Laramie, Wyoming. Other assays, made by institutional or private laboratories, were donated to the U.S. Geological Survey (USGS) and are included in this database as well as Adobe PDF-scanned images of some of the original laboratory assay reports and lithologic logs prepared by USBM geologists. The size of this database is 75.2 megabytes and includes information on 971 core holes and rotary-drilled boreholes and numerous surface sections. Most of these data were released previously by the USBM and the USGS through the National Technical Information Service but are no longer available from that agency. Fischer assays for boreholes in northeastern Utah and northwestern Colorado have been published by the USGS. Additional data include geophysical logs, groundwater data, chemical and X-ray diffraction analyses, and other data. These materials are available for inspection in the office of the USGS Central Energy Resources Team in Lakewood, Colorado. The digitized assays were checked with the original laboratory reports, but some errors likely remain. Other information, such as locations and elevations of core holes and oil and gas tests, were not thoroughly checked. However, owing to the current interest in oil-shale development, it was considered in the public interest to make this preliminary database available at this time. Chapter 2 of this CD-ROM presents oil-yield histograms of samples of cores and cuttings from exploration drill holes in the Eocene Green River Formation in the Great Divide, Green River, and Washakie Basins of southwestern Wyoming. A database was compiled that includes about 47,000 Fischer assays from 186 core holes and 240 rotary drill holes. Most of the oil yield data are from analyses performed by the former U.S. Bureau of Mines oil shale laboratory in Laramie, Wyoming, with some analyses made by private laboratories. Location data for 971 Wyoming oil-shale drill holes are listed in a spreadsheet that is included in the CD-ROM. These Wyoming Fischer assays and histograms are part of a much larger collection of oil-shale information, including geophysical and lithologic logs, water data, chemical and X-ray diffraction analyses on the Green River oil-shale deposits in Colorado, Utah, and Wyoming held by the U.S. Geological Survey. Because of an increased interest in oil shale, this CD-ROM containing Fischer assay data and oil-yield histograms for the Green River oil-shale deposits in southwestern Wyoming is being released to the public. Microsoft Excel spreadsheets included with Chapter 2 contain the Fischer assay data from the 426 holes and data on the company name and drill-hole name, and location. Histograms of the oil yields obtained from the Fischer assays are presented in both Grapher and PDF format. Fischer assay text data files are also included in the CD-ROM.

ICDP supported coring in IDDP-2 at Reykjanes - the DEEPEGS demonstrator in Iceland - Supercritical conditions reached below 4.6 km depth.

NASA Astrophysics Data System (ADS)

Ómar Friðleifsson, Guðmundur; Elders, Wilfred A.; Zierenberg, Robert; Steafánsson, Ari; Sigurðsson, Ómar; Gíslason, Þór; Weisenberger, Tobias B.; Harðarson, Björn S.; Mesfin, Kiflom G.

2017-04-01

The Iceland Deep Drilling Project (IDDP) is exploring the technical and economic feasibility of producing supercritical geothermal resources. The IDDP-2 well is located in the Reykjanes saline geothermal system in SW Iceland, on the landward extension of the Mid-Atlantic Ridge, where we are probing the analog of the root zone of a black smoker. In 2009, Phase 1 of the IDDP was unsuccessful in reaching supercritical conditions in the Krafla volcanic caldera in NE Iceland, when the IDDP-1 drill hole unexpectedly encountered 900°C rhyolite magma at only 2.1 km depth. The completed well produced superheated steam with a well head temperature of 453°C with an enthalpy and flow rate sufficient to generate 35 MWe. Drilling the IDDP-2 began by deepening an existing 2.5 km deep production well (RN-15) to 3 km depth, casing it to 2941m depth and drilling it to 4626m. Total circulation losses which were encountered below 3 km depth, could not be cured by LCM and multiple cement jobs. Accordingly, drilling continued "blind" to total depth, without return of drill cuttings. We attempted 12 core runs below 3 km depth, half of which recovered some core. The cores are basalts and dolerites with alteration ranging from upper greenschist facies to amphibolite facies, suggesting formation temperatures >450°C. After a final report from the on-site science team, expected mid-year 2017, detailed petrological, petrophysical, and geochemical analyses of cores will be undertaken by the IDDP science team and collaborators and published in a special issue of a main-stream scientific journal. The drilling of the IDDP-2 was funded by the field operator HS Orka, and by Statoil, and the IDDP industry consortium. The coring was funded by ICDP and the science program of the IDDP. Deepening the RN-15 began 11th August 2016, and was completed to 4626m, 17th December 2016. A perforated liner was inserted to 4,571m and the well subsequently logged for temperature, pressure and injectivity, after 6 days partial heating-up. The injectivity index proved to be 1.7 (kg/s)/bar. Supercritical conditions were measured at the bottom, 427°C at 340 bar pressure. The T-log showed the main permeable zones to be at around 3360m, 4200m, 4370m and 4550m depth. Estimates suggest that 30% of 40 L/s injected into the well are received by the three deepest feed zones. This can possibly be enhanced by massive soft stimulation, which is a part of the DEEPEGS plan to be executed later this year. The DEEPEGS project is a demonstration project, supported by the European Commission, Horizon 2020. The goal is to demonstrate the feasibility of enhanced geothermal systems (EGS) for delivering energy from renewable resources in Europe. It is a four-year project coordinated by HS Orka, Iceland, in cooperation with partners from Iceland, France, Germany, Italy, and Norway. The project will demonstrate advanced technologies in three types of geothermal reservoirs, (i) in high enthalpy resource beneath existing hydrothermal field at Reykjanes with temperature up to 550°C, and (ii) in two very deep hydrothermal reservoirs in France with temperatures up to 220°C.

The development of cold-water coral mounds along the Moroccan Atlantic and Mediterranean margins revealed by MeBo drillings

NASA Astrophysics Data System (ADS)

Hebbeln, Dierk; Wienberg, Claudia; Frank, Norbert

2015-04-01

Cold-water corals (CWC) mostly occur in intermediate water depths between 200 m and 1000 m and are capable of forming substantial seafloor structures, so-called coral carbonate mounds. These mounds can reach heights from a few meters up to >300 m and are composed of a mixture of CWC (and other shell) fragments and hemipelagic sediments, that both individually serve as distinct paleo-archives. IODP Leg 307 drilled through Challenger Mound at the Irish margin and revealed for the first time the full life history of a coral mound. However, although CWC occur almost worldwide, the 155 m long Challenger Mound record was for many years the only record from a coral mound exceeding 10 m in length. During expedition MSM36 with the German R/V MARIA S. MERIAN in spring 2014, several coral mounds along the Moroccan margin, both in the Atlantic Ocean and in the Mediterranean Sea, were drilled (actually: push-cored) by applying the Bremen Seafloor Drill Rig MeBo. The MeBo is a remotely controlled drilling system that is lowered from the vessel to the seafloor. Energy supply and video control are secured by an umbilical linking the MeBo to the vessel. The scientific foci of expedition MSM36 were to investigate (1) the long-term development of CWC mounds in both areas over the last several 100,000 years in relation to changes in the ambient environmental conditions in the respective intermediate waters, (2) the life time history of these mounds, and (3) the forcing factors for the initiation and decease of individual mounds. In both working areas, a total amount of 11 sites were successfully drilled with MeBo. Eight drillings were conducted at CWC mounds (on-mound sites) and 3 drillings in the direct vicinity of the mounds (off-mound sites) in order to obtain continuous paleoceanographic records. Drilling depths ranged between 17 m and 71 m with the latter corresponding to the maximum drilling depth of MeBo. The core recoveries varied between the sites and ranged between 47% and 96%. The coral-bearing on-mound cores were frozen and opened (i.e., cut lengthwise) with a stone saw to avoid a destruction of the original sediment texture with the embedded coral fragments. After opening, it became obvious that the quality of the MeBo cores is excellent and that it allows detailed post-cruise analyses at the MARUM laboratories in Bremen. By obtaining on-mound records reaching lengths of >70 m (focus #1), supplemented by the full penetration of three coral mounds (foci #2 and #3) and by a >45-m-long double drilling at an off-mound site located between numerous fossil and buried mounds (allowing to put their full life history into a wider paleoceanographic context; foci #1 to #3), the major technical goals of this MeBo expedition were fully accomplished. The critical factor in applying MeBo is the sea state as during deployment and recovery dynamic loads on the umbilical might reach critical limits. Although during expedition MSM36 several MeBo deployments were done by wind speeds of 6 Bft, the sea state especially in the Mediterranean Sea allowed MeBo operations without any restrictions. On the Atlantic side, a high swell, which actually exceeded the operational limit given for secured MeBo operations, could be overcome by reducing the payload (i.e. reducing the maximum drill depth). Hence, the operational window could be widened allowing for almost continuous MeBo operations also in this area.

Image registration based on subpixel localization and Cauchy-Schwarz divergence

NASA Astrophysics Data System (ADS)

Ge, Yongxin; Yang, Dan; Zhang, Xiaohong; Lu, Jiwen

2010-07-01

We define a new matching metric-corner Cauchy-Schwarz divergence (CCSD) and present a new approach based on the proposed CCSD and subpixel localization for image registration. First, we detect the corners in an image by a multiscale Harris operator and take them as initial interest points. And then, a subpixel localization technique is applied to determine the locations of the corners and eliminate the false and unstable corners. After that, CCSD is defined to obtain the initial matching corners. Finally, we use random sample consensus to robustly estimate the parameters based on the initial matching. The experimental results demonstrate that the proposed algorithm has a good performance in terms of both accuracy and efficiency.

Drilling the centre of the Thuringian Basin, Germany, to decipher potential interrelation between shallow and deep fluid systems

NASA Astrophysics Data System (ADS)

Kukowski, Nina; Totsche, Kai Uwe; Abratis, Michael; Habisreuther, Annett; Ward, Timothy; Influins Drilling-Team

2014-05-01

To shed light on the coupled dynamics of near surface and deep fluids in a sedimentary basin on various scales, ranging from the pore scale to the extent of an entire basin, is of paramount importance to understand the functioning of sedimentary basins fluid systems and therefore e.g. drinking water supply. It is also the fundamental goal of INFLUINS (INtegrated FLuid dynamics IN Sedimentary basins), a research initiative of several groups from Friedrich-Schiller University of Jena and their partners. This research association is focusing on the nearby Thuringian basin, a well confined, small intra-continental sedimentary basin in Germany, as a natural geo laboratory. In a multidisciplinary approach, embracing different fields of geophysics like seismic reflection profiling or airborne geomagnetics, structural geology, sedimentology, hydrogeology, hydrochemistry and hydrology, remote sensing, microbiology and mineralogy, among others, and including both, field-based, laboratory-based and computer-based research, an integral INFLUINS topic is the potential interaction of aquifers within the basin and at its rims. The Thuringian basin, which is composed of sedimentary rocks from the latest Paleozoic and mainly Triassic, is particularly suited to undertake such research as it is of relative small size, about 50 to 100 km, easily accessible, and quite well known from previous studies, and therefore also a perfect candidate for deep drilling. After the acquisition of 76 km seismic reflection data in spring 2011, to get as much relevant data as possible from a deep drilling at the cross point between two seismic profiles with a limited financial budget, an optimated core sampling and measuring strategy including partial coring, borehole geophysics and pump tests as well as a drill hole design, which enables for later continuation of drilling down to the basement, had been developed. Drilling Triassic rocks from Keuper to lower Buntsandstein was successfully realised down to a final depth of 1179 m from late June to mid-September 2013. Here, we give an introduction into the layout of INFLUINS deep drilling together with a summary of preliminary results, e.g. on the nature of the boundaries between Muschelkalk and Buntsandstein, and between upper and middle Buntsandstein, a complete core recovery of upper Buntsandstein saliniferous formations as well as unexpectedly low porosity and permeability of potential aquifers.

An IODP proposal to drill the Godzilla Megamullion as a step to Mohole

NASA Astrophysics Data System (ADS)

Ohara, Y.; Michibayashi, K.; Dick, H. J. B.; Snow, J. E.; Ono, S.

2017-12-01

The year 2017 represents the 60th anniversary of the "original" project Mohole, which was coined by Walter Munk in 1957. Although the project Mohole has not yet been realized, the hard-rock community is now striving hard to understand the upper mantle in a variety of ways. Firstly, the present-day project Mohole, M2M (Moho-to-Mantle) project, will move forward in this September, conducting multi-channel seismic profiling off Hawaii as a site survey. Oman Drilling Project has started last December, and the drilled cores are being described aboard D/V Chikyu from July, this year. Furthermore, the forearc M2M proposal to drill the Bonin Trench forearc mantle was submitted to IODP in April 2016. Being a part of these efforts, we are preparing an IODP proposal to drill the Godzilla Megamullion, the largest known oceanic core complex on the Earth, located in the Parece Vela Basin in the Philippine Sea. A significant fraction of the ocean floor is created in backarc basins, while there have been no single long core of backarc basin lower ocean crust, from which to understand the likely differences in magmatic evolution and crustal structure in this key setting. The opportunity to explore the formation of the backarc basin lower crust and upper mantle is, therefore, an important contribution to understanding the ocean basins. At the same time, a better understanding of the architecture of backarc basin lower crust and upper mantle will greatly aid in the interpretation of the results of ophiolite study, since much of our understanding of the architecture of oceanic lower crust and upper mantle comes from ophiolites, most of which are thought to have at least some arc and/or backarc component. The Godzilla Megamullion is unique in its huge size as well as its development in a backarc basin, a rare tectonic window to study backarc basin lithosphere. The Godzilla Megamullion is prepared for full drilling proposal, with complete bathymetric data, multiple bottom samplings, and multi-channel seismic profilings as well as P-wave velocity structures. We will propose substantial riserless drilling at Godzilla Megamullion that will provide an excellent opportunity to understand backarc basin lower crust and upper mantle. In this contribution, we will make use of this opportunity to share the general scheme of the proposal with the community.

Infrared Spectroscopy for Rapid Characterization of Drill Core and Cutting Mineralogy

NASA Astrophysics Data System (ADS)

Calvin, W. M.; Kratt, C.; Kruse, F. A.

2009-12-01

Water geochemistry can vary with depth and location within a geothermal reservoir, owing to natural factors such as changing rock type, gas content, fluid source and temperature. The interaction of these variable fluids with the host rock will cause well known changes in alteration mineral assemblages that are commonly factored into the exploration of hydrothermal systems for economic metals, but are less utilized with regard to mapping borehole geology for geothermal energy production. Chemistry of geothermal fluids and rock alteration products can impact production factors such as pipeline corrosion and scaling and early studies explored the use of both silica and chlorites as geothermometers. Infrared spectroscopy is particularly good at identifying a wide variety of alteration minerals, especially in discrimination among clay minerals, with no sample preparation. The technique has been extensively used in the remote identification of materials, but is not commonly used on drill core or chips. We have performed several promising pilot studies that suggest the power of the technique to sample continuously and provide mineral logs akin to geophysical ones. We have surveyed a variety of samples, including drill chip boards, boxed core, and drill cuttings from envelopes, sample bottles and chip trays. This work has demonstrated that core and drill chips can be rapidly surveyed, acquiring spectra every few to tens of cm of section, or the vertical resolution of the chip tray (typically 10 feet). Depending on the sample type we can acquire spectral data over thousands of feet depth at high vertical resolution in a fraction of the time that is needed for traditional analytical methods such as XRD or TEM with better accuracy than traditional geologic drill or chip logging that uses visual inspection alone. We have successfully identified layered silicates such as illite, kaolinite, montmorillonite chlorite and prehnite, zeolites, opal, calcite, jarosite and iron oxides and hydroxides in geothermal drill samples. We are currently developing automated analysis techniques to convert this detailed spectral logging data into high-vertical-resolution mineral depth profiles that can be linked to lithology, stratigraphy, fracture zones and potential for geothermal production. Also in development are metrics that would link mapped mineralogy to known geothermometers such as Na-K, Mg depletion, discrimination among illite, montmorillonite, and beidellite, and kaolinite crystallinity. Identification of amorphous and crystalline silica components (chalcedony, crystobalite and quartz) can also constrain silica geothermometry. The degree of alteration and some mineral types have been shown to be a proxy for host rock permeability, natural circulation, and the potential for reservoir sealing. Analysis of alteration intensity is also under way. We will present a synthesis of results to date.

Ages and stable-isotope compositions of secondary calcite and opal in drill cores from Tertiary volcanic rocks of the Yucca Mountain area, Nevada

USGS Publications Warehouse

Szabo, B. J.; Kyser, T.K.

1990-01-01

Stable-isotope compositions of fracture- and cavity-filling calcite from the unsaturated zone of three drill cores at Yucca Mountain Tertiary volcanic complex indicate that the water from which the minerals precipitated was probably meteoric in origin. A decrease in 18O in the calcite with depth is interpreted as being due to the increase in temperature in drill holes corresponding to an estimated average geothermal gradient of 34?? per kilometer. A few of the calcite samples and all of the opal samples yielded uranium-series ages older than 400 000 yr, although most of the calcite samples yielded ages between 26 000 and 310 000 yr. The stable-isotope and uranium-series dates from precipitated calcite and opal of this reconnaissance study suggest a complex history of fluid movement through the volcanic pile, and episodes of fracture filling predominantly from meteoric water during at least the past 400 000 yr. -Authors

Hydraulic and acoustic properties of the active Alpine Fault, New Zealand: Laboratory measurements on DFDP-1 drill core

NASA Astrophysics Data System (ADS)

Carpenter, B. M.; Kitajima, H.; Sutherland, R.; Townend, J.; Toy, V. G.; Saffer, D. M.

2014-03-01

We report on laboratory measurements of permeability and elastic wavespeed for a suite of samples obtained by drilling across the active Alpine Fault on the South Island of New Zealand, as part of the first phase of the Deep Fault Drilling Project (DFDP-1). We find that clay-rich cataclasite and principal slip zone (PSZ) samples exhibit low permeabilities (⩽10-18 m), and that the permeability of hanging-wall cataclasites increases (from c. 10-18 m to 10-15 m) with distance from the fault. Additionally, the PSZ exhibits a markedly lower P-wave velocity and Young's modulus relative to the wall rocks. Our laboratory data are in good agreement with in situ wireline logging measurements and are consistent with the identification of an alteration zone surrounding the PSZ defined by observations of core samples. The properties of this zone and the low permeability of the PSZ likely govern transient hydrologic processes during earthquake slip, including thermal pressurization and dilatancy strengthening.

Trace-element analyses of core samples from the 1967-1988 drillings of Kilauea Iki lava lake, Hawaii

USGS Publications Warehouse

Helz, Rosalind Tuthill

2012-01-01

This report presents previously unpublished analyses of trace elements in drill core samples from Kilauea Iki lava lake and from the 1959 eruption that fed the lava lake. The two types of data presented were obtained by instrumental neutron-activation analysis (INAA) and energy-dispersive X-ray fluorescence analysis (EDXRF). The analyses were performed in U.S. Geological Survey (USGS) laboratories from 1989 to 1994. This report contains 93 INAA analyses on 84 samples and 68 EDXRF analyses on 68 samples. The purpose of the study was to document trace-element variation during chemical differentiation, especially during the closed-system differentiation of Kilauea Iki lava lake.

Kimama Well - Borehole Geophysics Database

DOE Data Explorer

Shervais, John

2011-07-04

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Kimama drill site was set up to acquire a continuous record of basaltic volcanism along the central volcanic axis and to test the extent of geothermal resources beneath the Snake River aquifer. Data submitted by project collaborator Doug Schmitt, University of Alberta

Kimama Well - Photos

DOE Data Explorer

Shervais, John

2011-01-16

The Snake River Plain (SRP), Idaho, hosts potential geothermal resources due to elevated groundwater temperatures associated with the thermal anomaly Yellowstone-Snake River hotspot. Project HOTSPOT has coordinated international institutions and organizations to understand subsurface stratigraphy and assess geothermal potential. Over 5.9km of core were drilled from three boreholes within the SRP in an attempt to acquire continuous core documenting the volcanic and sedimentary record of the hotspot: (1) Kimama, (2) Kimberly, and (3) Mountain Home. The Kimama drill site was set up to acquire a continuous record of basaltic volcanism along the central volcanic axis and to test the extent of geothermal resources beneath the Snake River aquifer. Data submitted by project collaborator Doug Schmitt, University of Alberta

Condensed listing of surface boreholes at the Waste Isolation Pilot Plant Project through 31 December 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, L.R.; Aguilar, R.; Mercer, J.W.

This report contains a condensed listing of Waste Isolation Pilot Plant (WIPP) project surface boreholes drilled for the purpose of site selection and characterization through 31 December 1995. The US Department of Energy (DOE) sponsored the drilling activities, which were conducted primarily by Sandia National Laboratories. The listing provides physical attributes such as location (township, range, section, and state-plane coordinates), elevation, and total borehole depth, as well as the purpose for the borehole, drilling dates, and information about extracted cores. The report also presents the hole status (plugged, testing, monitoring, etc.) and includes salient findings and references. Maps with boreholemore » locations and times-of-drilling charts are included.« less