Briquettes of rice husk, polyethylene terephthalate (PET), and dried leaves as implementation of wastes recycling

NASA Astrophysics Data System (ADS)

Hariyanto, Sucipto; Usman, Mohammad Nurdianfajar; Citrasari, Nita

2017-06-01

This research aim is to determine the best briquettes as implementation of wastes recycle based on scoring method, main component composition, compressive strength, caloric value, water content, vollatile content, and ash content, also the suitability with SNI 01-6235-2000. Main component that used are rice husk, 2mm and 6 mm PET, and dried leaves. Composition variation in this research are marked as K1, K2, K3, K4, and K5 with 2 mm PET plastic and K1, K2, K3, K4, and K5 with 6 mm PET plastic. The total weight of the briquettes is 100 g and divided into 90% main components and 10% tapioca as binder. The compressive strength, caloric value, water content, vollatile content, and ash content were tested according to ASTM D 5865-04, ASTM D 3173-03, ASTM D 3175-02, ASTM D 3174-02. The tested results were used to determine the best briquette by scoring method, and the chosen briquettes is K2 with 6 mm PET plastic. The composition is 70% rice husk, 20% 6 mm PET plastic, and 10% dried leaves with the compressive strength, caloric value, water content, vollatile content, and ash content value is 51,55 kg/cm2; 5123 kal/g; 3,049%; 31,823%, dan 12,869%. The suitable value that meet the criteria according to SNI 01-6235-2000 is compressive strength, caloric value, water content, and ash content.

Mass Spectrometric Determination of Uranium and Thorium in High Radiopurity Polymers Using Ultra Low Background Electroformed Copper Crucibles for Dry Ashing.

PubMed

Arnquist, Isaac J; Hoppe, Eric J; Bliss, Mary; Grate, Jay W

2017-03-07

A rapid new method for determining the U and Th mass concentrations in high radiopurity plastics is described, consisting of (1) dry ashing the plastic sample and tracers in low mass crucibles made of ultra low background electroformed copper (ULB EF-Cu) foil cut and folded into boats, (2) dissolving both the ash and the boat in acid, (3) performing a column separation to remove copper, and (4) determining the elements of interest by isotope dilution mass spectrometry. This method was demonstrated on both unfluorinated and fluorinated plastics, demonstrating high tracer recoveries and detection limits to pg/g (i.e., parts per trillion) levels or below, corresponding to μBq/kg of material. Samples of biomedical polyester (Max-Prene 955) and a fluoropolymer (polyvinylidene fluoride, PVDF) were analyzed in powder raw material forms as well as solids in the form of pellets or injection molded parts. The polyester powder contained 6 pg/g and 2 pg/g for 232 Th and 238 U, respectively. These levels correspond to 25 and 25 μBq/kg radioactivity, respectively. Determinations on samples of PVDF powder were typically below 1 pg/g for 232 Th and 2 pg/g for 238 U, corresponding to 4 and 25 μBq/kg radioactivity, respectively. The use of low mass ULB EF-Cu boats for dry ashing successfully overcame the problem of crucible-generated contaminants in the analysis; absolute detection limits, calculated as 3 × standard deviation of the process blanks, were typically 20-100 fg within a sample set. Complete dissolution of the ash and low mass boat provided high tracer recoveries and provides a convincing method to recover both the tracer and sample isotopes when full equilibration of tracer isotopes with sample isotopes is not possible prior to beginning chemical sample processing on solids.

Mass Spectrometric Determination of Uranium and Thorium in High Radiopurity Polymers Using Ultra Low Background Electroformed Copper Crucibles for Dry Ashing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arnquist, Isaac J.; Hoppe, Eric J.; Bliss, Mary

A rapid new method for determining the U and Th mass concentrations in high radiopurity plastics is described, consisting of 1) dry ashing the plastic sample and tracers in low mass crucibles made of ultra low background electroformed copper (ULB EF-Cu) foil cut and folded into boats, 2) dissolving both the ash and the boat in acid, 3) performing a column separation to remove copper, and 4) determining the elements of interest by isotope dilution mass spectrometry. This method was demonstrated on both unfluorinated and fluorinated plastics, demonstrating high tracer recoveries and detection limits to pg/g (i.e., parts per trillion)more » levels or below, corresponding to μBq/kg of material. Samples of biomedical polyester (Max-Prene® 955) and a fluoropolymer (polyvinylidene fluoride, PVDF) were analyzed in powder raw material forms as well as solids in the form of pellets or injection molded parts. The polyester powder contained 6 pg/g and 2 pg/g for Th and U respectively. These levels correspond to 25 and 25 μBq/kg radioactivity, respectively. Determinations on samples of PVDF powder were typically below 1 pg/g for Th and 2 pg/g for U, corresponding to 4 and 25 μBq/kg radioactivity, respectively. The use of low mass ULB EF-Cu boats for dry ashing successfully overcame the problem of crucible-generated contaminants in the analysis; absolute detection limits, calculated as 3 × standard deviation of the process blanks, were typically 20-100 fg within a sample set. Complete dissolution of the ash and low mass boat provided high tracer recoveries, and provides a convincing method to recover both the tracer and sample isotopes when full equilibration of tracer isotopes with sample isotopes is not possible prior to beginning chemical sample processing on solids.« less

Properties of Semi-dry Flue Gas Desulfurization Ash and Used for Phosphorus Removal

NASA Astrophysics Data System (ADS)

Yu, Y. P.; Fang, Y.; Chai, S. Y.; Zhuang, Z. Z.

2018-05-01

The composition of Semi-dry Flue Gas Desulfurization ash was as follows: CaSO3 · 0.5H2O and Ca(OH)2. Most of the particle size was about 8 µm particles were irregular and small, while the other part was rough and globular. CaSO3 strongly oxidized at about 466°C and Ca(OH)2 decomposed at ∼ 662°C. The maximum amount of phosphorus removal in Semi-dry Flue Gas Desulfurization ash was 79.898 mg/g.

Fertilizer from dried human urine added to ash and lime - a potential product from eco-sanitation system.

PubMed

Dutta, Shanta; Vinnerås, Björn

2016-09-01

This research explored the possibility of making fertilizer at a laboratory from source separated and untreated human urine added to ash and lime by drying at low temperatures. A mixture of ash and lime (1:1) was used as drying agent and human urine was applied as undiluted and fresh. Ash and lime were chosen as drying agents for maintaining a pH > 10 during the drying process, which should inhibit urea hydrolysis in urine, and thereby urea should be retained in the drying agent. The drying technique was developed and drying capacity of the system was quantified; three specific temperatures (20 °, 35 °, 60 °C) and two airflow rates (1 L/min and 5 L/min) were used in the experiment. A mass balance for nitrogen in the system was obtained. It was evident from the experiment that urea can be retained by maintaining a high pH (>10). Urine drying at 20 °C was not a feasible option, since rate of evaporation was very low. The highest retention of inflow nitrogen at 35 °C and 60 °C were 74% and 54%, respectively, in the produced fertilizer. Reduced evaporation rate, flooding of urine over drying agent, and blockage in airflow influenced nitrogen loss and concentration of nitrogen in the final product.

Volcanic ashfall accumulation and loading on gutters and pitched roofs from laboratory empirical experiments: Implications for risk assessment

NASA Astrophysics Data System (ADS)

Hampton, S. J.; Cole, J. W.; Wilson, G.; Wilson, T. M.; Broom, S.

2015-10-01

Volcanic ash load is dependent on the migration and accumulation of ash on roofing surfaces and guttering, of which limited research has been conducted. This study investigates this knowledge gap through the empirical experimental testing of volcanic ash on variably pitched metal sheet roofs with modern PVC gutter systems, highlighting the relative importance of accumulation, migration, remobilization, saturation, and subsequent load. A testing rig delivered ash onto variably pitched roofs (pitches 15°, 25°, 30°, 35°, and 45°) with two 45° tests involving a wet surface with subsequent ashfall, and the second of ashfall with periods of wetting, followed by wetting until failure. In testing, dry ash on a dry roof accumulates at pitches up to 35°, above this pitch the percentage of ash accumulating reduces with greater percentages infilling guttering and or lost to the ground. With the introduction of a wet roof surface at 45° pitch, adherence of dry ash greatly increases, increasing accumulated ash thickness as compared to dry tests from 8% to 38%. For testing involving periods of wetting at 45° roof pitch, accumulation percentages further increased to 50%. Ash migrating from the roof surface filled guttering more rapidly at greater pitches, which once full resulted in further migrating ash to spill over the front or back gutter lips. Collapse of guttering did not occur during testing, but deformation and bracket detachment did occur at loads > 1 kPa. This study provides data on load calculations on roofing and PVC guttering through the quantification and utilization of relationships between ash fate, pitch, and the influence of water, in the development of two scenarios for both roof and gutter. These two scenarios then enable the estimation of ash accumulation and thus the load and collapse thresholds for roof and gutter at different roof pitch, which could be adopted for volcanic risk modeling or risk management.

Wet-dry cycles effect on ash water repellency. A laboratory experiment.

NASA Astrophysics Data System (ADS)

Pereira, Paulo; Cerdà, Artemi; Oliva, Marc; Mataix, Jorge; Jordán, Antonio

2014-05-01

In the immediate period after the fire, the ash layer has a strong influence on soil hydrological processes, as runoff, infiltration and erosion. Ash is very dynamic in the space and time. Until the first rainfall periods, ash is (re)distributed by the wind. After it can cover the soil surface, infiltrate or transported to other areas by water transport (Pereira et al., 2013a, b). This will have strong implications on nutrient redistribution and vegetation recovery. Ash layer may affect soil water repellency in different ways, depending on fire severity, soil properties and vegetation. Ash produced at low temperatures after low-severity burning is usually hydrophobic (Bodi et al., 2011, 2012). Wet-dry cycles have implications on ash physical and chemical properties, changing their effects in space and time. The aim of this study is to analyse the effects of fire temperature and severity on ash water repellency. Pinus sylvestris needles were collected in a Lithuania forest in Dzukija National Park (53º 54' N and 24º 22' E), transported to laboratory and washed with deionized water to remove soil particles and other residues. Needle samples were dried during 24 hours and exposed to different temperatures: 200, 300, 400 and 500 ºC, during 2 hours. Ash colour was analysed according to the Munsell Soil Color charts. Ash was black (10 YR 2/1) at 200 ºC, very dark grey (10YR 3/1) at 300 ºC, gray (10YR 5/1) at 400 ºC and light gray (10YR 7/1) at 500 ºC. Ten samples of ash released after each treatment were placed in plastic dishes (50 mm in diameter) in an amount enough to form a 5 mm thick layer, and ash water repellency was measured according to the Water Drop Penetration Test. Later, ash was carefully wetted with 15 ml of deionized water and placed in an oven during 4 days (96 hours), as in Bodí et al. (2012). This procedure was repeated 5 times in order to observe the effects of wet-dry cycles in ash water repellency. The results showed significant differences among wet-dry cycles (Chi Sqr = 184.13 p <0.001) and among temperatures, immediately after treatments (Kruskal-Wallis test: H = 13.64, p<0.01) and after first wet-dry cycle (Kruskal-Wallis test: H =13.85 p<0.01). In the second (Kruskal-Wallis test: =5.80, p >0.05), third (Kruskal-Wallis test: H =3.07, p>0.05), fourth (Kruskal-Wallis test: H=0.75, p>0.05) and fifth (Kruskal-Wallis test: H =0.199, p<0.05) wet-dry cycles, ash water repellency did not show significant differences. After wetting, ash water repellency decreased substantially in the first cycle. These results suggest that wet-dry cycles have important impacts in the reduction of ash water repellency. Nevertheless, this reduction at least in the first cycle is different according to the temperature/severity. Black ash (200 ºC) water repellency was significantly higher than the other temperatures/severities. Further research will be carried out using burned soils and different species. References Bodi, M.B., Doerr, S., Cerda, A., Mataix-Solera, J. (2012) Hydrological effects of a layer of vegetation ash on underlying wettable and water repellent soil. Geoderma, 161, 14-23, 2011. DOI: 10.1016/j.geoderma.2012.01.006. Bodí, M.B., Mataix-Solera, J., Doerr, S.H., Cerdà, A. (2011). The wettability of ash from burned vegetation and its relationship to Mediterranean plant species type, burn severity and total organic carbon content. Geoderma 160, 599-607. DOI:10.1016/j.geoderma.2010.11.009. Pereira, P., Cerdà, A., Úbeda, X., Mataix-Solera, J. Arcenegui, V., Zavala, L. (2013a) Modelling the impacts of wildfire on ash thickness in a short-term period, Land Degradation and Development. DOI: 10.1002/ldr.2195. Pereira, P., Cerdà, A., Úbeda, X., Mataix-Solera, J., Jordan, A. Burguet, M. (2013b) Spatial models for monitoring the spatio-temporal evolution of ashes after fire - a case study of a burnt grassland in Lithuania, Solid Earth, 4, 153-165. DOI: 10.5194/se-4-153-2013.

Regeneratively cooled coal combustor/gasifier with integral dry ash removal

DOEpatents

Beaufrere, A.H.

1982-04-30

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.

2009-07-15

There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with flymore » ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.« less

Experimental study on durability improvement of fly ash concrete with durability improving admixture.

PubMed

Quan, Hong-zhu; Kasami, Hideo

2014-01-01

In order to improve the durability of fly ash concrete, a series of experimental studies are carried out, where durability improving admixture is used to reduce drying shrinkage and improve freezing-thawing resistance. The effects of durability improving admixture, air content, water-binder ratio, and fly ash replacement ratio on the performance of fly ash concrete are discussed in this paper. The results show that by using durability improving admixture in nonair-entraining fly ash concrete, the compressive strength of fly ash concrete can be improved by 10%-20%, and the drying shrinkage is reduced by 60%. Carbonation resistance of concrete is roughly proportional to water-cement ratio regardless of water-binder ratio and fly ash replacement ratio. For the specimens cured in air for 2 weeks, the freezing-thawing resistance is improved. In addition, by making use of durability improving admixture, it is easier to control the air content and make fly ash concrete into nonair-entraining one. The quality of fly ash concrete is thereby optimized.

The Quality and Food Safety of Dry Smoke Garfish (Hemirhamphus far) Product From Maluku

NASA Astrophysics Data System (ADS)

Marthina Tapotubun, Alfonsina; Reiuwpassa, Fredrik; Apituley, Yolanda M. T. N.; Nanlohy, Hellen; Matrutty, Theodora E. A. A.

2017-10-01

Dry garfish is product of smoked process of “ikan julung” (Hemirhamphus far) and slowly the product getting dry, stiff and its colour become gold yellow-brown. The aim of this study is to find out quality and food safety of dry smoked “julung” from Maluku. The sample of this study is taken from production Keffing village, East Seram Regency, Maluku. Parameters to be analyzed are degrees of protein, fat, water, ash, TPC, Escherichia coli, Salmonella, Vibrio and total Staphylococcus aureus used standard analysis method for proximate (AOAC. 2005), sensosy parameters (BSN.2009) and food safety (BSN. 2006). Spreadsheet Ms Excel (Microsoft Inc., USA) is used for data processing; data is being analyzed descriptively to be interpreted in the research report. Dry smoked “julung” Keffing village, Maluku meet the good quality and food safety, that are ingredient degrees of water content 12.43%, protein 61.55%, fat 12.58%, ash 9.3%, TPC [6,8] × 101 CFU, total Staphylococcus sp [1,7] × 102, total E.coli 6.4 APM/g. and negatively for Salmonella and Vibrio.

Drying Shrinkage of Mortar Incorporating High Volume Oil Palm Biomass Waste

NASA Astrophysics Data System (ADS)

Shukor Lim, Nor Hasanah Abdul; Samadi, Mostafa; Rahman Mohd. Sam, Abdul; Khalid, Nur Hafizah Abd; Nabilah Sarbini, Noor; Farhayu Ariffin, Nur; Warid Hussin, Mohd; Ismail, Mohammed A.

2018-03-01

This paper studies the drying shrinkage of mortar incorporating oil palm biomass waste including Palm Oil Fuel Ash, Oil Palm Kernel Shell and Oil Palm Fibre. Nano size of palm oil fuel ash was used up to 80 % as cement replacement by weight. The ash has been treated to improve the physical and chemical properties of mortar. The mass ratio of sand to blended ashes was 3:1. The test was carried out using 25 × 25 × 160 mm prism for drying shrinkage tests and 70 × 70 ×70 mm for compressive strength test. The results show that the shrinkage value of biomass mortar is reduced by 31% compared with OPC mortar thus, showing better performance in restraining deformation of the mortar while the compressive strength increased by 24% compared with OPC mortar at later age. The study gives a better understanding of how the biomass waste affect on mortar compressive strength and drying shrinkage behaviour. Overall, the oil palm biomass waste can be used to produce a better performance mortar at later age in terms of compressive strength and drying shrinkage.

Grain shape of basaltic ash populations: implications for fragmentation

NASA Astrophysics Data System (ADS)

Schmith, Johanne; Höskuldsson, Ármann; Holm, Paul Martin

2017-02-01

Here, we introduce a new quantitative method to produce grain shape data of bulk samples of volcanic ash, and we correlate the bulk average grain shape with magma fragmentation mechanisms. The method is based on automatic shape analysis of 2D projection ash grains in the size range 125-63 μm. Loose bulk samples from the deposits of six different basaltic eruptions were analyzed, and 20,000 shape measurements for each were obtained within 45 min using the Particle Insight™ dynamic shape analyzer (PIdsa). We used principal component analysis on a reference grain dataset to show that circularity, rectangularity, form factor, and elongation best discriminate between the grain shapes when combined. The grain population data show that the studied eruptive environments produce nearly the same range of grain shapes, although to different extents. Our new shape index (the regularity index (RI)) places an eruption on a spectrum between phreatomagmatic and dry magmatic fragmentation. Almost vesicle-free Surtseyan ash has an RI of 0.207 ± 0.002 (2σ), whereas vesiculated Hawaiian ash has an RI of 0.134 ± 0.001 (2σ). These two samples define the end-member RI, while two subglacial, one lacustrine, and another submarine ash sample show intermediate RIs of 0.168 ± 0.002 (2σ), 0.175 ± 0.002 (2σ), 0.187 ± 0.002 (2σ), and 0.191 ± 0.002 (2σ), respectively. The systematic change in RI between wet and dry eruptions suggests that the RI can be used to assess the relative roles of magmatic vs. phreatomagmatic fragmentation. We infer that both magmatic and phreatomagmatic fragmentation processes played a role in the subglacial eruptions.

FLY ASH RECYCLE IN DRY SCRUBBING

EPA Science Inventory

The paper describes the effects of fly ash recycle in dry scrubbing. (Previous workers have shown that the recycle of product solids improves the utilization of slaked lime--Ca(OH)2--for sulfur dioxide (SO2) removal by spray dryers with bag filters.) In laboratory-scale experimen...

Evaluation of beneficial use of wood-fired boiler ash on oat and bean growth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krejsl, J.A.; Scanlon, T.M.

An evaluation on the effects of pulp and paper mill combined boiler ashes on growth and nutrient uptake by oat (Avena sativa L., var. 501) and bean (Phaseolus vulgaris L., var. blue pole) was conducted in a greenhouse. Ash with a calcium carbonate equivalent of 29.1% and a pH of 12.1 was applied at the rates 30, 40, and 50 dry Mg ha{sup -1} to Chehalis silty clay loam (fine-silty, mixed, mesic Cumulic Ultic Haploxerolls), with pH 5.4. An agricultural dolomitic lime treatment of 7.4 Mg ha{sup -1} and a nonamended control were also included. Plants grown on ash-amended soilmore » had higher biomass compared to plants grown on lime and control treatments. Ash treatments 30, 40, and 50 dry Mg ha{sup -1} increased the bean (stems and leaves) dry matter (DM) yield over the control by 49, 57, and 64%, respectively. The lime treatment increased the bean DM yield by 31% compared with the control. The ash rate 30 dry Mg ha{sup -1}, equivalent to the recommended agronomic lime rate 7.4 Mg ha{sup -1}, increased oat (shoots) DM yields over the control by 45%, while the lime treatment increased biomass by 8% over control. The highest ash treatment, 50 Mg ha{sup -1}, produced the lowest oat biomass. The ash was as effective as dolomitic lime in raising soil pH. Ash-amended soils contained higher concentrations of P, S, and B for plant growth compared to lime and nonamended soils. Soil Zn, Fe, mn, and Cu concentrations decreased as ash application rates increased. Oat and bean plants grown in the ash-amended soil had increased concentrations of K, S, and B and decreased concentrations of Mn and Cu compared with plants grown in the nonamended control soil. Overall, oat and bean benefited from the increased nutrient availability and soil pH caused by the application of boiler ash. 20 refs., 6 tabs.« less

Geochemical field method for determination of nickel in plants

USGS Publications Warehouse

Reichen, L.E.

1951-01-01

The use of biogeochemical data in prospecting for nickel emphasizes the need for a simple, moderately accurate field method for the determination of nickel in plants. In order to follow leads provided by plants of unusual nickel content without loss of time, the plants should be analyzed and the results given to the field geologist promptly. The method reported in this paper was developed to meet this need. Speed is acquired by elimination of the customary drying and controlled ashing; the fresh vegetation is ashed in an open dish over a gasoline stove. The ash is put into solution with hydrochloric acid and the solution buffered. A chromograph is used to make a confined spot with an aliquot of the ash solution on dimethylglyoxime reagent paper. As little as 0.025% nickel in plant ash can be determined. With a simple modification, 0.003% can be detected. Data are given comparing the results obtained by an accepted laboratory procedure. Results by the field method are within 30% of the laboratory values. The field method for nickel in plants meets the requirements of biogeochemical prospecting with respect to accuracy, simplicity, speed, and ease of performance in the field. With experience, an analyst can make 30 determinations in an 8-hour work day in the field.

Regeneratively cooled coal combustor/gasifier with integral dry ash removal

DOEpatents

Beaufrere, Albert H.

1983-10-04

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

High gradient magnetic beneficiation of dry pulverized coal via upwardly directed recirculating fluidization

DOEpatents

Eissenberg, David M.; Liu, Yin-An

1980-01-01

This invention relates to an improved device and method for the high gradient magnetic beneficiation of dry pulverized coal, for the purpose of removing sulfur and ash from the coal whereby the product is a dry environmentally acceptable, low-sulfur fuel. The process involves upwardly directed recirculating air fluidization of selectively sized powdered coal in a separator having sections of increasing diameters in the direction of air flow, with magnetic field and flow rates chosen for optimum separations depending upon particulate size.

Procedural uncertainties of Proctor compaction tests applied on MSWI bottom ash.

PubMed

Izquierdo, Maria; Querol, Xavier; Vazquez, Enric

2011-02-28

MSWI bottom ash is a well-graded highly compactable material that can be used as a road material in unbound pavements. Achieving the compactness assumed in the design of the pavement is of primary concern to ensure long term structural stability. Regulations on road construction in a number of EU countries rely on standard tests originally developed for natural aggregates, which may not be appropriate to accurately assess MSWI bottom ash. This study is intended to assist in consistently assessing MSWI bottom ash compaction by means of the Proctor method. This test is routinely applied to address unbound road materials and suggests two methods. Compaction parameters show a marked procedural dependency due to the particle morphology and weak particle strength of ash. Re-compacting a single batch sample to determine Proctor curves is a common practise that turns out to overvalue optimum moisture contents and maximum dry densities. This could result in wet-side compactions not meeting stiffness requirements. Inaccurate moisture content measurements during testing may also induce erroneous determinations of compaction parameters. The role of a number of physical properties of MSWI bottom ash in compaction is also investigated. Copyright © 2011 Elsevier B.V. All rights reserved.

Experimental Study on Durability Improvement of Fly Ash Concrete with Durability Improving Admixture

PubMed Central

Quan, Hong-zhu; Kasami, Hideo

2014-01-01

In order to improve the durability of fly ash concrete, a series of experimental studies are carried out, where durability improving admixture is used to reduce drying shrinkage and improve freezing-thawing resistance. The effects of durability improving admixture, air content, water-binder ratio, and fly ash replacement ratio on the performance of fly ash concrete are discussed in this paper. The results show that by using durability improving admixture in nonair-entraining fly ash concrete, the compressive strength of fly ash concrete can be improved by 10%–20%, and the drying shrinkage is reduced by 60%. Carbonation resistance of concrete is roughly proportional to water-cement ratio regardless of water-binder ratio and fly ash replacement ratio. For the specimens cured in air for 2 weeks, the freezing-thawing resistance is improved. In addition, by making use of durability improving admixture, it is easier to control the air content and make fly ash concrete into nonair-entraining one. The quality of fly ash concrete is thereby optimized. PMID:25013870

Ion Beam Analyses Of Bark And Wood In Environmental Studies

NASA Astrophysics Data System (ADS)

Lill, J.-O.; Saarela, K.-E.; Harju, L.; Rajander, J.; Lindroos, A.; Heselius, S.-J.

2011-06-01

A large number of wood and bark samples have been analysed utilizing particle-induced X-ray emission (PIXE) and particle-induced gamma-ray emission (PIGE) techniques. Samples of common tree species like Scots Pine, Norway Spruce and birch were collected from a large number of sites in Southern and Southwestern Finland. Some of the samples were from a heavily polluted area in the vicinity of a copper-nickel smelter. The samples were dry ashed at 550 °C for the removal of the organic matrix in order to increase the analytical sensitivity of the method. The sensitivity was enhanced by a factor of 50 for wood and slightly less for bark. The ashed samples were pressed into pellets and irradiated as thick targets with a millimetre-sized proton beam. By including the ashing procedure in the method, the statistical dispersion due to elemental heterogeneities in wood material could be reduced. As a by-product, information about the elemental composition of ashes was obtained. By comparing the concentration of an element in bark ash to the concentration in wood ash of the same tree useful information from environmental point of view was obtained. The obtained ratio of the ashes was used to distinguish between elemental contributions from anthropogenic atmospheric sources and natural geochemical sources, like soil and bedrock.

Calcium, potassium, and sodium content of forest floor arthropods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reichle, D.E.; Shanks, M.H.; Crossley, D.A. Jr.

1969-01-01

Whole-body nutrient composition of calcium, potassium, and sodium is documented for 37 species of forest floor arthropods. Sodium concentrations averaging 4.6 mg Na/g ash-free dry weight, and potassium concentrations averaging 6.2 mg K/g ash-free dry weight were relatively consistent within and among major taxonomic categories. Calcium content varied from 0.3 to 509.8 mg Ca/g ash-free dry weight, with highest values associated with Diplopoda and related species possessing highly calcified exoskeletons. Within-species variation in chemical composition often exceeded seasonal fluctuations, although several species exhibited significant temporal changes in whole-body nutrient composition of calcium, potassium, and sodium. 9 references, 3 tables.

Biometric studies on the bivalves Astarte elliptica, A. borealis and A. montagui in Kiel Bay (Western Baltic Sea)

NASA Astrophysics Data System (ADS)

Schaefer, R.; Trutschler, K.; Rumohr, H.

1985-09-01

The three Astarte species were studied in June 1983 at two sites in Kiel Bay, “Süderfahrt” and “Schleimünde”, at 20 m depth. Shell length to live wet weight correlations are given for all three species; for A. elliptica also shell-free dry weight, shell dry weight, ash-free dry weight of the soft body and ash-free dry weight of the shell are recorded as functions of the shell length. In the logarithmic length/weight regression analysis the coefficients of slope for A. elliptica and A. borealis are 3. For A. montagui, that coefficient is significantly greater than 3. Weight conversion factors, calculated for A. elliptica, revealed a mean weight composition of 31.5 % water in the mantle cavity and tissue water, 64.5 % shell ash, 2.1 % organic content of shell, 1.7 % organic content of the soft body and 0.4 % ash of the soft body. An isometric growth of shell length and shell breadth is confirmed for A. borealis, while A. montagui exhibits positive allometric shell growth and changes its shape during life.

Natural weathering in dry disposed ash dump: Insight from chemical, mineralogical and geochemical analysis of fresh and unsaturated drilled cores.

PubMed

Akinyemi, S A; Akinlua, A; Gitari, W M; Khuse, N; Eze, P; Akinyeye, R O; Petrik, L F

2012-07-15

Some existing alternative applications of coal fly ash such as cement manufacturing; road construction; landfill; and concrete and waste stabilisation use fresh ash directly collected from coal-fired power generating stations. Thus, if the rate of usage continues, the demand for fresh ash for various applications will exceed supply and use of weathered dry disposed ash will become necessary alternative. As a result it's imperative to understand the chemistry and pH behaviour of some metals inherent in dry disposed fly ash. The bulk chemical composition as determined by XRF analysis showed that SiO2, Al2O3 and Fe2O3 were the major oxides in fresh ash and unsaturated weathered ashes. The unsaturated weathered ashes are relatively depleted in CaO, Fe2O3, TiO2, SiO2, Na2O and P2O5 due to dissolution and hydrolysis caused by chemical interaction with ingressing CO2 from the atmosphere and infiltrating rain water. Observed accumulations of Fe2O3, TiO2, CaO, K2O, Na2O and SO3 and Zn, Zr, Sr, Pb, Ni, Cr and Co in the lower layers indicate progressive downward movement through the ash dump though at a slow rate. The bulk mineralogy of unsaturated weathered dry disposed ash, as determined by XRD analysis, revealed quartz and mullite as the major crystalline phases; while anorthite, hematite, enstatite, lime, calcite, and mica were present as minor mineral phases. Pore water chemistry revealed a low concentration of readily soluble metals in unsaturated weathered ashes in comparison with fresh ash, which shows high leachability. This suggests that over time the precipitation of transient minor secondary mineral phases; such as calcite and mica might retard residual metal release from unsaturated weathered ash. Chloride and sulphate species of the water soluble extracts of weathered ash are at equilibrium with Na+ and K+; these demonstrate progressive leaching over time and become supersaturated at the base of unsaturated weathered ash. This suggests that the ash dump does not encapsulate the salt or act as a sustainable salt sink due to over time reduction in pore water pH. The leaching behaviours of Ca, Mg, Na+, K+, Se, Cr and Sr are controlled by the pH of the leachant in both fresh and unsaturated weathered ash. Other trace metals like As, Mo and Pb showed amphoteric behaviour with respect to the pH of the leachant. The precipitation of minor quantities of secondary mineral phases in the unsaturated weathered ash has significant effects on the acid susceptibility and leaching patterns of chemical species in comparison with fresh ash. The unsaturated weathered ash had lower buffering capacity at neutral pH (7.94-8.00) compared to fresh (unweathered) ash. This may be due to the initial high leaching/flushing of soluble basic buffering constituents from fly ash after disposal. The overall results of the acid susceptibility tests suggest that both fresh ash and unsaturated weathered ash would release a large percentage of their chemical species when in contact with slightly acidified rain. Proper management of ash dumps is therefore essential to safeguard the environmental risks of water percolation in different fly ashes behaviour. Copyright © 2012 Elsevier Ltd. All rights reserved.

Volcanic Ash Data Assimilation System for Atmospheric Transport Model

NASA Astrophysics Data System (ADS)

Ishii, K.; Shimbori, T.; Sato, E.; Tokumoto, T.; Hayashi, Y.; Hashimoto, A.

2017-12-01

The Japan Meteorological Agency (JMA) has two operations for volcanic ash forecasts, which are Volcanic Ash Fall Forecast (VAFF) and Volcanic Ash Advisory (VAA). In these operations, the forecasts are calculated by atmospheric transport models including the advection process, the turbulent diffusion process, the gravitational fall process and the deposition process (wet/dry). The initial distribution of volcanic ash in the models is the most important but uncertain factor. In operations, the model of Suzuki (1983) with many empirical assumptions is adopted to the initial distribution. This adversely affects the reconstruction of actual eruption plumes.We are developing a volcanic ash data assimilation system using weather radars and meteorological satellite observation, in order to improve the initial distribution of the atmospheric transport models. Our data assimilation system is based on the three-dimensional variational data assimilation method (3D-Var). Analysis variables are ash concentration and size distribution parameters which are mutually independent. The radar observation is expected to provide three-dimensional parameters such as ash concentration and parameters of ash particle size distribution. On the other hand, the satellite observation is anticipated to provide two-dimensional parameters of ash clouds such as mass loading, top height and particle effective radius. In this study, we estimate the thickness of ash clouds using vertical wind shear of JMA numerical weather prediction, and apply for the volcanic ash data assimilation system.

Hydraulic conductivity of fly ash-sewage sludge mixes for use in landfill cover liners.

PubMed

Herrmann, Inga; Svensson, Malin; Ecke, Holger; Kumpiene, Jurate; Maurice, Christian; Andreas, Lale; Lagerkvist, Anders

2009-08-01

Secondary materials could help meeting the increasing demand of landfill cover liner materials. In this study, the effect of compaction energy, water content, ash ratio, freezing, drying and biological activity on the hydraulic conductivity of two fly ash-sewage sludge mixes was investigated using a 2(7-1) fractional factorial design. The aim was to identify the factors that influence hydraulic conductivity, to quantify their effects and to assess how a sufficiently low hydraulic conductivity can be achieved. The factors compaction energy and drying, as well as the factor interactions material x ash ratio and ash ratio x compaction energy affected hydraulic conductivity significantly (alpha=0.05). Freezing on five freeze-thaw cycles did not affect hydraulic conductivity. Water content affected hydraulic conductivity only initially. The hydraulic conductivity data were modelled using multiple linear regression. The derived models were reliable as indicated by R(adjusted)(2) values between 0.75 and 0.86. Independent on the ash ratio and the material, hydraulic conductivity was predicted to be between 1.7 x 10(-11)m s(-1) and 8.9 x 10(-10)m s(-1) if the compaction energy was 2.4 J cm(-3), the ash ratio between 20% and 75% and drying did not occur. Thus, the investigated materials met the limit value for non-hazardous waste landfills of 10(-9)m s(-1).

Studies on mycorrhizal inoculation on dry matter yield and root colonization of some medicinal plants grown in stress and forest soils.

PubMed

Chandra, K K; Kumar, Neeraj; Chand, Gireesh

2010-11-01

Five medicinal plants viz. Abelmoschatus moschatus Linn., Clitoria tematea L., Plumbagozeylanica L., Psorolea corylifolia L. and Withania sominifera L. were grown in a polypot experiment in five soils representing coal mine soil, coppermine soil, fly ash, skeletal soil and forest soil with and without mycorrhizal inoculations in a completely randomized block design. Dry matter yield and mycorrhizal root colonization of plants varied both in uninoculated and inoculated conditions. The forest soil rendered highest dry matter due to higher yield of A. moschatus, P. zeylanica and P corylifolia while fly ash showed lowest dry matter without any inoculants. P. cematea were best in coalmine soil and W. sominifera in copper mine soil without mycorrhizal inoculation. The mycorrhiza was found to enhance the dry matter yield. This contributed minimum 0.19% to maximum up to 422.0% in different soils as compared to uninoculated plants. The mycorrhizal dependency was noticed maximum in plants grown in fly ash followed by coal mine soil, copper mine soil, skeletal soil and forest soil. The mycorrhizal response was increased maximum in W. sominifera due to survival in fly ash after inoculation followed by P corylifolia and P cematea. Percent root colonization in inoculated plant was increased minimum of 1.10 fold to maximum of 12.0 folds in comparison to un-inoculated plants . The native mycorrhiza fungi were also observed to colonize 4.0 to 32.0% roots in plants understudy. This study suggests that mycorrhizal inoculation increased the dry matter yield of medicinal plants in all soils under study. It also helps in survival of W. sominifera in fly ash.

Bone growth and calcium balance during simulated weightlessness in the rat

NASA Technical Reports Server (NTRS)

Roer, Robert D.; Dillaman, Richard M.

1990-01-01

Rats, age 28 days, experiencing tail suspension in modified metabolic cages for 1, 2, and 3 wk were compared with littermate controls. Food and water consumption, urinary and fecal Ca excretion, and serum Ca were measured; hearts, fore- and hindlimb bones, skulls, and mandibles were removed for determination of wet, dry, and ash weights and Ca concentration and for histological examination. Weight gain and Ca intake and excretion were the same for both groups; both displayed net Ca gain. Suspended rats had significantly lower wet, dry, and ash weights of femora and tibiae. Dry weights of the humeri and radii/ulnae were moderately higher, and the skull and mandible dry and ash weights were significantly higher in suspended than in control rats. Cortical thickness of the femur, but not humerus, was less in suspended rats. The data are consistent with the hypothesis that bone growth is influenced by the cardiovascular changes associated with tail suspension.

Faecal-wood biomass co-combustion and ash composition analysis.

PubMed

Somorin, Tosin Onabanjo; Kolios, Athanasios J; Parker, Alison; McAdam, Ewan; Williams, Leon; Tyrrel, Sean

2017-09-01

Fuel blending is a widely used approach in biomass combustion, particularly for feedstocks with low calorific value and high moisture content. In on-site sanitation technologies, fuel blending is proposed as a pre-treatment requirement to reduce moisture levels and improve the physiochemical properties of raw faeces prior to drying. This study investigates the co-combustion performance of wood dust: raw human faeces blends at varying air-to-fuel ratios in a bench-scale combustor test rig. It concludes with ash composition analyses and discusses their potential application and related problems. The study shows that a 50:50 wood dust (WD): raw human faeces (FC) can reduce moisture levels in raw human faeces by ∼40% prior to drying. The minimum acceptable blend for treating moist faeces without prior drying at a combustion air flow rate of 14-18 L/min is 30:70 WD: FC. For self-sustained ignition and flame propagation, the minimum combustion temperature required for conversion of the fuel to ash is ∼400 °C. The most abundant elements in faecal ash are potassium and calcium, while elements such as nickel, aluminium and iron are in trace quantities. This suggests the potential use of faecal ash as a soil conditioner, but increases the tendency for fly ash formation and sintering problems.

21 CFR 168.122 - Lactose.

Code of Federal Regulations, 2010 CFR

2010-04-01

.../m), calculated on a dry basis. (2) The sulfated ash content is not more than 0.3 percent, m/m... action to final action. (3) Sulfated ash content, section 31.014, “Ash of Sugars and Sirups,” Final Action, Sulfated Ash, 14th Ed. (1984), p. 575. (4) pH, section 14.022, “pH of Flour, Potentiometric...

21 CFR 168.122 - Lactose.

Code of Federal Regulations, 2011 CFR

2011-04-01

.../m), calculated on a dry basis. (2) The sulfated ash content is not more than 0.3 percent, m/m... action to final action. (3) Sulfated ash content, section 31.014, “Ash of Sugars and Sirups,” Final Action, Sulfated Ash, 14th Ed. (1984), p. 575. (4) pH, section 14.022, “pH of Flour, Potentiometric...

Environmental and economic life cycle assessment for sewage sludge treatment processes in Japan.

PubMed

Hong, Jinglan; Hong, Jingmin; Otaki, Masahiro; Jolliet, Olivier

2009-02-01

Life cycle assessment for sewage sludge treatment was carried out by estimating the environmental and economic impacts of the six alternative scenarios most often used in Japan: dewatering, composting, drying, incineration, incinerated ash melting and dewatered sludge melting, each with or without digestion. Three end-of-life treatments were also studied: landfilling, agricultural application and building material application. The results demonstrate that sewage sludge digestion can reduce the environmental load and cost through reduced dry matter volume. The global warming potential (GWP) generated from incineration and melting processes can be significantly reduced through the reuse of waste heat for electricity and/or heat generation. Equipment production in scenarios except dewatering has an important effect on GWP, whereas the contribution of construction is negligible. In addition, the results show that the dewatering scenario has the highest impact on land use and cost, the drying scenario has the highest impact on GWP and acidification, and the incinerated ash melting scenario has the highest impact on human toxicity due to re-emissions of heavy metals from incinerated ash in the melting unit process. On the contrary, the dewatering, composting and incineration scenarios generate the lowest impact on human toxicity, land use and acidification, respectively, and the incinerated ash melting scenario has the lowest impact on GWP and cost. Heavy metals released from atmospheric effluents generated the highest human toxicity impact, with the effect of dioxin emissions being significantly lower. This study proved that the dewatered sludge melting scenario is an environmentally optimal and economically affordable method.

The immersion freezing behavior of ash particles from wood and brown coal burning

NASA Astrophysics Data System (ADS)

Grawe, Sarah; Augustin-Bauditz, Stefanie; Hartmann, Susan; Hellner, Lisa; Pettersson, Jan B. C.; Prager, Andrea; Stratmann, Frank; Wex, Heike

2016-11-01

It is generally known that ash particles from coal combustion can trigger ice nucleation when they interact with water vapor and/or supercooled droplets. However, data on the ice nucleation of ash particles from different sources, including both anthropogenic and natural combustion processes, are still scarce. As fossil energy sources still fuel the largest proportion of electric power production worldwide, and biomass burning contributes significantly to the global aerosol loading, further data are needed to better assess the ice nucleating efficiency of ash particles. In the framework of this study, we found that ash particles from brown coal (i.e., lignite) burning are up to 2 orders of magnitude more ice active in the immersion mode below -32 °C than those from wood burning. Fly ash from a coal-fired power plant was shown to be the most efficient at nucleating ice. Furthermore, the influence of various particle generation methods on the freezing behavior was studied. For instance, particles were generated either by dispersion of dry sample material, or by atomization of ash-water suspensions, and then led into the Leipzig Aerosol Cloud Interaction Simulator (LACIS) where the immersion freezing behavior was examined. Whereas the immersion freezing behavior of ashes from wood burning was not affected by the particle generation method, it depended on the type of particle generation for ash from brown coal. It was also found that the common practice of treating prepared suspensions in an ultrasonic bath to avoid aggregation of particles led to an enhanced ice nucleation activity. The findings of this study suggest (a) that ash from brown coal burning may influence immersion freezing in clouds close to the source and (b) that the freezing behavior of ash particles may be altered by a change in sample preparation and/or particle generation.

Comparative Physicochemical Evaluation of Kharekhasak (Tribulus terrestris Linn.) Before and After Mudabbar Process

PubMed Central

Tauheed, Abdullah; Hamiduddin; Khanam, Salma; Ali, Mohd Akhtar; Zaigham, Mohammad

2017-01-01

Background and Objectives: Mudabbar/Tadbeere advia is referred to the processes performed on the drugs to detoxify, purify, and enhance therapeutic action and to reduce its doses before making the formulations in Unani medicine. It improves quality of drugs either by optimizing its desirable characteristics or minimizing the undesirable ones; it makes drug effective, safe, and specific. There is a need of comparative evaluation to understand its significance. Tadbeer of Kharekhasak (KK) khurd (Tribulus terrestris Linn. fruit) is described by Rabban Al-Tabari in Firdausul Hikmat, Akbar Arzani in Qarabadeene Qadri, etc., during the compounding of aphrodisiac formulations. Mudabbar Kharekhasak (MKK) used in Safoofe Kharekhasak mentioned in Al-Qarabadeene was evaluated in this work. Methods: Mudabbar/Tadbeer process was carried out by blending fresh KK. Juice with powdered dry KK and drying it under the sun. Juice used for process is thrice the weight of dry KK powder. The KK before and after the process was evaluated using physicochemical tests: powder characterization, extractive value, alcohol and water soluble matter, ash value, loss on drying (LOD) at 105°C, pH, high-performance thin layer chromatography (HPTLC) fingerprinting, and diosgenin content. Results: Powder characterizations were set in. Increase in successive and nonsuccessive extractive values in various solvents, water/alcohol-soluble content, total ash, acid-insoluble ash, water-soluble ash, and sulfated ash of MKK was noted in comparison with KK. Decrease in LOD at 105°C and pH of MKK powder was observed. HPTLC fingerprinting data were developed for the identification and evaluation. Quantification of diosgenin content increased to 432.1 g/g in MKK as compared to 144.5 g/g in KK, suggesting significant increase in saponin content. Conclusion: Data obtained clearly indicated changes in MKK validating the classical Mudabbar process, probably to enhance/modify the action of drug. Standards for crude and MKK were established for future reference. SUMMARY Mudabbar process on Tribulus terrestris Linn (KK) havebeen validated.Physicochemical data for Mudabbar and non mudabbar Kharekhasak (KK) powder have been set in.Diosgenin content was increased significantly in mudabbar KK. Abbreviations Used: KK: Kharekhasak, TT: Tribulus terrestris, MKK: mudabbar Kharekhasak, SK: Safoofe Kharekhasak, LOD: loss of weight on drying, HPTLC: High performance thin layer chromatography, BSS: British standard sieve, μl: microliter, SEM: Standard error of mean, nm: nanometer, g: gram. PMID:29263633

Immersion freezing induced by different kinds of coal fly ash: Comparing particle generation methods and measurement techniques

NASA Astrophysics Data System (ADS)

Grawe, Sarah; Augustin-Bauditz, Stefanie; Clemen, Hans-Christian; Eriksen-Hammer, Stine; Lubitz, Jasmin; Schneider, Johannes; Stratmann, Frank; Wex, Heike

2017-04-01

To date, a lot of effort has been put into the identification and characterization of atmospheric ice nucleating particles (INPs), which may influence both weather and climate. The majority of studies focuses on INPs from natural origin such as biological particles or mineral dust particles (Hoose and Möhler 2012, Murray et al. 2012). Combustion ashes, being possible sources of anthropogenic INPs, have rarely been investigated in the past. Ash particles may be emitted into the atmosphere either by the action of wind from ash deposits on the ground (bottom ash), or during the combustion process (fly ash). Two recent studies (Umo et al., 2015; Grawe et al., 2016) identified fly ash from coal combustion as the most efficient of the investigated samples (including also bottom ashes from wood and coal combustion). These results motivate the here presented study in which we investigated the immersion freezing behavior of four coal fly ash samples taken from the filters of different coal-fired power plants in Germany. A combination of two instruments was used to capture the temperature range from 0 °C to the homogeneous freezing limit at around -38 °C. Firstly, the new Leipzig Ice Nucleation Array (LINA) was used, where droplets from an ash-water suspension are pipetted onto a cooled plate. Secondly, we used the Leipzig Aerosol Cloud Interaction Simulator (LACIS; Hartmann et al., 2011), a laminar flow tube in which every droplet contains a single size-segregated ash particle. Here, it was possible to study the effect of different kinds of particle generation, i.e., atomization of an ash-water suspension, and aerosolization of dry ash material. The composition of the ash particles was investigated by means of single particle aerosol mass spectrometry and particles were sampled on filters for environmental scanning electron microscope analysis. Our measurements show that all four fly ash samples feature a similar immersion freezing behavior (ice fractions vary by a factor of 5 at most) when particles are generated via dry dispersion. Furthermore, we found that the ice nucleation ability of all samples is lowered significantly when changing from dry to wet particle generation. The aim of the study is to identify possible reasons for these observations. References: S. Grawe, S. Augustin-Bauditz, S. Hartmann, L. Hellner, J. B. C. Pettersson, A. Prager, F. Stratmann, and H. Wex, Atmos. Chem. Phys., 16, 13911-13928, 2016 S. Hartmann, D. Niedermeier, J. Voigtländer, T. Clauß, R. A. Shaw, H. Wex, A. Kiselev, and F. Stratmann, Atmos. Chem. Phys., 11, 1753-1767, 2011 C. Hoose and O. Möhler, Atmos. Chem. Phys., 12, 9817-9854, 2012 B. J. Murray, D. O'Sullivan, J. D. Atkinson, and M. E. Webb, Chem. Soc. Rev., 41, 6519-6554, 2012 N. S. Umo, B. J. Murray, M. T. Baeza-Romero, J. M. Jones, A. R. Lea-Langton, T. L. Malkin, D. O'Sullivan, L. Neve, J. M. C. Plane, and A. Williams, Atmos. Chem. Phys., 15, 5195-5210, 2015

Growth and elemental content of two tree species growing on abandoned coal fly ash basins. [Liquidambar styraciflua L. ; Platanus occidentalis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carlson, C.L.; Adriano, D.C.

Differences in aboveground tissue concentrations of trace elements were assessed for sweetgum (Liquidambar styraciflua L.) and sycamore (Plantanus occidentalis L.) growing on two abandoned coal fly ash basins and a control soil. The wet basin (pH = 5.58) had originally received precipitator ash in an ash-water slurry, while the dry basin (pH = 8.26) had received both precipitator and bottom ash in dry form. In general, trees from the wet basin exhibited elevated trace element concentrations in comparison to the controls, while the dry basin trees exhibited reduced concentrations. On eof the most striking differenced in elemental concentrations among themore » ash basin and control trees was observed for Mn, with the control trees exhibiting concentrations orders of magnitude greater than the ash basin trees. Differences in foliar trace element concentrations among the sites can generally be explained by differences in substrate trace element concentrations and/or substrate pH. While trees from the wet ash basin generally had the highest trace element concentrations, these trees also attained the greatest height and diameter growth, suggesting that the elevated trace element concentrations in the wet basin substrate are not limiting the establishment of these two species. The greater height and diameter growth of the wet basin trees is presumably a result of the greater water-holding capacity of the substrate on this site. Differences in growth and tissue concentrations between sweetgum and sycamore highlight the importance of using more than one species when assessing metal toxicity or deficiency on a given substrate.« less

Self-cementing properties of oil shale solid heat carrier retorting residue.

PubMed

Talviste, Peeter; Sedman, Annette; Mõtlep, Riho; Kirsimäe, Kalle

2013-06-01

Oil shale-type organic-rich sedimentary rocks can be pyrolysed to produce shale oil. The pyrolysis of oil shale using solid heat carrier (SHC) technology is accompanied by large amount of environmentally hazardous solid residue-black ash-which needs to be properly landfilled. Usage of oil shale is growing worldwide, and the employment of large SHC retorts increases the amount of black ash type of waste, but little is known about its physical and chemical properties. The objectives of this research were to study the composition and self-cementing properties of black ash by simulating different disposal strategies in order to find the most appropriate landfilling method. Three disposal methods were simulated in laboratory experiment: hydraulic disposal with and without grain size separation, and dry dumping of moist residue. Black ash exhibited good self-cementing properties with maximum compressive strength values of >6 MPa after 90 days. About 80% of strength was gained in 30 days. However, the coarse fraction (>125 µm) did not exhibit any cementation, thus the hydraulic disposal with grain size separation should be avoided. The study showed that self-cementing properties of black ash are governed by the hydration of secondary calcium silicates (e.g. belite), calcite and hydrocalumite.

Device and method for separating minerals, carbon and cement additives from fly ash

DOEpatents

Link, Thomas A.; Schoffstall, Micael R.; Soong, Yee

2004-01-27

A process for separating organic and inorganic particles from a dry mixture by sizing the particles into isolated fractions, contacting the sized particles to a charged substrate and subjecting the charged particles to an electric field to separate the particles.

Proximate and polyphenolic characterization of cranberry pomace.

PubMed

White, Brittany L; Howard, Luke R; Prior, Ronald L

2010-04-14

The proximate composition and identification and quantification of polyphenolic compounds in dried cranberry pomace were determined. Proximate analysis was conducted based on AOAC methods for moisture, protein, fat, dietary fiber, and ash. Other carbohydrates were determined by the difference method. Polyphenolic compounds were identified and quantified by HPLC-ESI-MS. The composition of dried cranberry pomace was 4.5% moisture, 2.2% protein, 12.0% fat, 65.5% insoluble fiber, 5.7% soluble fiber, 8.4% other carbohydrates, 1.1% ash, and 0.6% total polyphenolics. It contained six anthocyanins (111.5 mg/100 g of DW) including derivatives of cyanidin and peonidin. Thirteen flavonols were identified (358.4 mg/100 g of DW), and the aglycones myricetin (55.6 mg/100 g of DW) and quercetin (146.2 mg/100 g of DW) were the most prominent. Procyanidins with degrees of polymerization (DP) of 1-6 were identified (167.3 mg/100 g of DW), the most abundant being an A-type of DP2 (82.6 mg/100 g of DW).

Blackberry wines mineral and heavy metal content determination after dry ashing: multivariate data analysis as a tool for fruit wine quality control.

PubMed

Amidžić Klarić, Daniela; Klarić, Ilija; Mornar, Ana; Velić, Darko; Velić, Natalija

2015-08-01

This study brings out the data on the content of 21 mineral and heavy metal in 15 blackberry wines made of conventionally and organically grown blackberries. The objective of this study was to classify the blackberry wine samples based on their mineral composition and the applied cultivation method of the starting raw material by using chemometric analysis. The metal content of Croatian blackberry wine samples was determined by AAS after dry ashing. The comparison between an organic and conventional group of investigated blackberry wines showed statistically significant difference in concentrations of Si and Li, where the organic group contained higher concentrations of these compounds. According to multivariate data analysis, the model based on the original metal content data set finally included seven original variables (K, Fe, Mn, Cu, Ba, Cd and Cr) and gave a satisfactory separation of two applied cultivation methods of the starting raw material.

Enhancing the engineering properties of expansive soil using bagasse ash

NASA Astrophysics Data System (ADS)

Silmi Surjandari, Niken; Djarwanti, Noegroho; Umri Ukoi, Nafisah

2017-11-01

This paper deals with stabilization of expansive soil on a laboratory experimental basis. The aim of the research was to evaluate the enhancement of the engineering properties of expansive soil using bagasse ash. The soil is treated with bagasse ash by weight (0, 5, 10, 15, and 20%) based on dry mass. The performance of bagasse ash stabilized soil was evaluated using physical and strength performance tests, namely the plasticity index, standard Proctor compaction, and percentage swelling. An X-ray diffraction (XRD) test was conducted to evaluate the clay mineral, whereas an X-ray fluorescence (XRF) was to the chemical composition of bagasse ash. From the results, it was observed that the basic tests carried out proved some soil properties after the addition of bagasse ash. Furthermore, the plasticity index decreased from 53.18 to 47.70%. The maximum dry density of the specimen increased from 1.13 to 1.24 gr/cm3. The percentage swelling decreased from 5.48 to 3.29%. The outcomes of these tests demonstrate that stabilization of expansive soils using bagasse ash can improve the strength.

Development and freeze-thaw durability of high flyash-content concrete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sajadi, J.

1987-01-01

Objectives were to investigate the effects on concrete strength, drying shrinkage, freeze-thaw durability, and air-void system parameters of replacing various amounts of portland cement with different types of fly ash and to compare selected characteristics of such fly-ash concretes and fly-ash concretes containing a high-range water-reducing admixture to those of a control mixture. It was concluded that concrete mixtures with 90-day compressive strengths equal to the control could be produced when large amounts of cement were replaced by fly ash. In addition, when the high-range water-reducing admixtures was employed, very large amounts of cement could be replaced by fly ashmore » to yield mixtures whose compressive strengths were equal to or greater than the strengths of the control mix at all ages. The maximum amount of cement that could be replaced for equal-strength mixtures depended upon the nature of the fly ash. Drying shrinkage of plain fly-ash concretes and fly-ash concretes containing the high-range water-reducing admixture were similar to those of the control mix. The optimum fly-ash content in a concrete is comparable in strength and durability to a conventional (control) concrete was influenced by the chemical and physical characteristics of the fly ash.« less

Mechanical properties of geopolymer lightweight brick with styrofoam pellet

NASA Astrophysics Data System (ADS)

Abdullah, Mohd Mustafa Al Bakri; Tahir, Muhammad Faheem Mohd; Kadir, Aeslina Abdul; Hussin, Kamarudin; Samson, W. Saiful Iskandar W.

2017-09-01

The utilization of fly ash in brick as partial replacement of cement is gaining immense importance today, mainly on account of the improvement in the long-term durability of brick combined with ecological benefits. In this research, the lightweight brick was produced by using fly ash (class F) as a main material to replace Ordinary Portland Cement (OPC) in the composition of brick. Class F Fly Ash was mixed with an alkaline activator solution (a mixture of sodium silicate and NaOH), and styrofoam pellet was added to the geopolymer mixture to produce lightweight brick. The brick was prepared in two methods that is wet method and dry method due to different brick composition which is dry method for composition with sand and wet method for composition without sand. The bricks were cured in room temperature at 7 aging days. After 7 days, the compressive strength, water absorption, and density of the brick were investigated, where the optimum ratio for the best bricks has been determined from the lightweight density and has compressive strength more than minimum standard requirement. The best bricks are further produce for curing at 60°C in oven at 28 aging days. Those bricks also were characterized using optical microscope to measure the distribution of styrofoam in brick structure. From the result obtained, the brick that cured at 60°C in oven at 28 aging days has high strength compare to brick that cured in room temperature and at 7 day cured. The water absorption is decreasing as the curing temperature and aging days increased whereas density is increasing.

Effect of mixing geopolymer and peat on bearing capacity in Ogan Komering Ilir (OKI) by California bearing ratio (CBR) test

NASA Astrophysics Data System (ADS)

Raharja, Danang S.; Hadiwardoyo, Sigit P.; Rahayu, Wiwik; Zain, Nasuhi

2017-06-01

Geopolymer is binder material that consists of solid material and the activator solution. Geopolymer material has successfully replaced cement in the manufacture of concrete with aluminosilicate bonding system. Geopolymer concrete has properties similar to cement concrete with high compressive strength, low shrinkage value, relatively low creep value, as well as acid-resistant. Based on these, the addition of polymers in peat soils is expected to improve the bearing capacity of peat soils. A study on the influence of geopolymer addition in peat soils was done by comparing before and after the peat soil was mixed with geopolymer using CBR (California Bearing Ratio) test in unsoaked and soaked conditions. 10% mixture content of the peat dry was used, weighted with a variety of curing time 4 hours, 5 days, and 10 days. There were two methods of mixing: first, peat was mixed with fly ash geopolymer activators and mixed solution (waterglass, NaOH, water), and second, peat was mixed with fly ash and mixed geopolymer (waterglass, NaOH, water, fly ash). Changes were observed in specific gravity, dry density, acidity (pH), and the microscopic structure with Scanning Electron Microscope (SEM). Curing time did not significantly affect the CBR value. It even shows a tendency to decline with longer curing time. The first type mixture obtained CBR value of: 5.4% for 4 hours curing, 4.6% for 5 days curing and 3.6% for 10 days curing. The second type mixture obtained CBR value of: 6.1% for 4 hours curing, 5.2% for 5 days curing and 5.2% for 10 days curing. Furthermore, the specific gravity value, dry density, pH near neutral and swelling percentage increased. From both variants, the second type mixture shows better results than the first type mixture. The results of SEM (Scanning Electron Microscopy) show the structure of the peat which became denser with the fly ash particles filling the peat microporous. Also, the reaction of fly ash with geopolymer is indicated by the solid agglomerates that are larger than normal fly ash particle size.

Failure to phytosanitize ash firewood infested with emerald ash borer in a small dry kiln using ISPM-15 standards

Treesearch

P. Charles Goebel; Matthew S. Bumgardner; Daniel A. Herms; Andrew. Sabula

2010-01-01

Although current USDA-APHIS standards suggest that a core temperature of 71.1°C (160°F) for 75 min is needed to adequately sanitize emerald ash borer, Agrilus planipennis Fairmaire-infested firewood, it is unclear whether more moderate (and economical) treatment regimes will adequately eradicate emerald ash borer larvae and prepupae...

Properties of Fly Ash Blocks Made from Adobe Mould

NASA Astrophysics Data System (ADS)

Chokhani, Alankrit; Divakar, B. S.; Jawalgi, Archana S.; Renukadevi, M. V.; Jagadish, K. S.

2018-02-01

Fly ash being one of the industrial waste products poses a serious disposal problem. This paper presents an experimental study of utilization of fly ash to produce blocks with varying proportions and mix combinations. Composition of fly ash blocks mainly consist of fly ash and sand, with cementitious product as either cement, lime or both, such as fly ash-sand-cement, fly ash-sand-lime and fly ash-sand-cement-lime are used. Four different proportions for each of the mix combinations are experimented. Compressive strength, water absorption, Initial rate of absorption, and dry density of fly ash blocks are studied. The influence of partial and complete replacement of cement by lime is examined.

Properties of Fly Ash Blocks Made from Adobe Mould

NASA Astrophysics Data System (ADS)

Chokhani, Alankrit; Divakar, B. S.; Jawalgi, Archana S.; Renukadevi, M. V.; Jagadish, K. S.

2018-06-01

Fly ash being one of the industrial waste products poses a serious disposal problem. This paper presents an experimental study of utilization of fly ash to produce blocks with varying proportions and mix combinations. Composition of fly ash blocks mainly consist of fly ash and sand, with cementitious product as either cement, lime or both, such as fly ash-sand-cement, fly ash-sand-lime and fly ash-sand-cement-lime are used. Four different proportions for each of the mix combinations are experimented. Compressive strength, water absorption, Initial rate of absorption, and dry density of fly ash blocks are studied. The influence of partial and complete replacement of cement by lime is examined.

[Effects of stabilization treatment on migration and transformation of heavy metals in mineral waste residues].

PubMed

Zhao, Shu-Hua; Chen, Zhi-Liang; Zhang, Tai-Ping; Pan, Wei-Bin; Peng, Xiao-Chun; Che, Rong; Ou, Ying-Juan; Lei, Guo-Jian; Zhou, Ding

2014-04-01

Different forms of heavy metals in soil will produce different environmental effects, and will directly influence the toxicity, migration and bioavailability of heavy metals. This study used lime, fly ash, dried sludge, peanut shells as stabilizers in the treatment of heavy metals in mineral waste residues. Morphological analyses of heavy metal, leaching experiments, potted plant experiments were carried out to analyze the migration and transformation of heavy metals. The results showed that after adding stabilizers, the pH of the acidic mineral waste residues increased to more than neutral, and the organic matter content increased significantly. The main existing forms of As, Pb, and Zn in the mineral waste residues were the residual. The contents of exchangeable and organic matter-bound As decreased by 65.6% and 87.7% respectively after adding fly ash, dried sludge and peanut shells. Adding lime, fly ash and peanut shells promoted the transformation of As from the Fe-Mn oxide-bound to the carbonate-bound, and adding lime and fly ash promoted the transformation of Pb and Zn from the exchangeable, Fe-Mn oxide-bound, organic matter-bound to the residual. After the early stage of the stabilization treatment, the contents of As, Pb and Zn in the leachate had varying degrees of decline, and adding peanut shells could reduce the contents of As, Pb and Zn in the leachate further. Among them, the content of As decreased most significantly after treatment with fly ash, dried sludge and peanut shells, with a decline of 57.4%. After treatment with lime, fly ash and peanut shells, the content of Zn decreased most significantly, by 24.9%. The addition of stabilizers was advantageous to the germination and growth of plants. The combination of fly ash, dried sludge and peanut shell produced the best effect, and the Vetiveria zizanioides germination rate reached 76% in the treated wasted mineral residues.

Genetic parameters for body weight, carcass chemical composition and yield in a broiler-layer cross developed for QTL mapping

PubMed Central

Nunes, Beatriz do Nascimento; Ramos, Salvador Boccaletti; Savegnago, Rodrigo Pelicioni; Ledur, Mônica Corrêa; Nones, Kátia; Klein, Claudete Hara; Munari, Danísio Prado

2011-01-01

The objective of this study was to estimate genetic and phenotypic correlations of body weight at 6 weeks of age (BW6), as well as final carcass yield, and moisture, protein, fat and ash contents, using data from 3,422 F2 chickens originated from reciprocal cross between a broiler and a layer line. Variance components were estimated by the REML method, using animal models for evaluating random additive genetic and fixed contemporary group (sex, hatch and genetic group) effects. The heritability estimates (h2) for BW6, carcass yield and percentage of carcass moisture were 0.31 ± 0.07, 0.20 ± 0.05 and 0.33 ± 0.07, respectively. The h2 for the percentages of protein, fat and ash on a dry matter basis were 0.48 ± 0.09, 0.55 ± 0.10 and 0.36 ± 0.08, respectively. BW6 had a positive genetic correlation with fat percentage in the carcass, but a negative one with protein and ash contents. Carcass yield, thus, appears to have only low genetic association with carcass composition traits. The genetic correlations observed between traits, measured on a dry matter basis, indicated that selection for carcass protein content may favor higher ash content and a lower percentage of carcass fat. PMID:21931515

Inhibition of the de novo synthesis of PCDD/Fs on model fly ash by sludge drying gases.

PubMed

Chen, Tong; Zhan, Ming-Xiu; Lin, Xiao-Qing; Li, Xiao-Dong; Lu, Sheng-Yong; Yan, Jian-Hua; Buekens, Alfons; Cen, Ke-Fa

2014-11-01

Sludge drying gases (SDG), evolving from drying and mild thermal decomposition (<300°C) of raw sewage sludge contain NH3 and SO2 as well as other N- and S-compounds. All of these are potential PCDD/Fs suppressants. It is indeed observed that these SDG suppress 2,3,7,8-substitued PCDD/Fs formation on Model Fly Ash (MFA) with an efficiency up to 97.6% in wt. units and 96% in I-TEQ, respectively. This suppression is strong for (the bulk of) PCDD/Fs, adsorbed on the model fly ash; conversely, sludge drying gases enhance PCDD/Fs desorption from MFA. Moreover, TCDD/Fs are suppressed least, possibly following stepwise dechlorination of higher chlorinated PCDD/Fs. Characteristics, such as the type, origins and amount of sludge, its moisture-, nitrogen- and sulfur content and the nature of the thermal treatment applied are all expected to influence upon the suppression capabilities. In this study three types of dry sludge are tested and applied as suppressant in four different amounts or modes. The quality of the sludge drying gases is continuously monitored: the Gasmet results reveal that NH3 and SO2 are the most important components of SDG. The MFA reaction residue is scrutinized by Scanning Electron Microscope (SEM) and Energy Dispersive Spectrometer (EDS) analysis. A large number of particles attaching to the surface of model fly ash are observed by SEM. Moreover, EDS analysis reveals that part of the chlorine in MFA is carried away with the SDG and replaced by sulfur, so that eliminating chlorine may be part of the inhibition mechanism. However, further research is still needed to establish the optimum operating modes and to confirm the role of both inorganic and organic nitrogen and sulfur compounds in the suppression of PCDD/Fs formation on model fly ash. Copyright © 2014 Elsevier Ltd. All rights reserved.

Volcanic ash impacts on critical infrastructure

NASA Astrophysics Data System (ADS)

Wilson, Thomas M.; Stewart, Carol; Sword-Daniels, Victoria; Leonard, Graham S.; Johnston, David M.; Cole, Jim W.; Wardman, Johnny; Wilson, Grant; Barnard, Scott T.

2012-01-01

Volcanic eruptions can produce a wide range of hazards. Although phenomena such as pyroclastic flows and surges, sector collapses, lahars and ballistic blocks are the most destructive and dangerous, volcanic ash is by far the most widely distributed eruption product. Although ash falls rarely endanger human life directly, threats to public health and disruption to critical infrastructure services, aviation and primary production can lead to significant societal impacts. Even relatively small eruptions can cause widespread disruption, damage and economic loss. Volcanic eruptions are, in general, infrequent and somewhat exotic occurrences, and consequently in many parts of the world, the management of critical infrastructure during volcanic crises can be improved with greater knowledge of the likely impacts. This article presents an overview of volcanic ash impacts on critical infrastructure, other than aviation and fuel supply, illustrated by findings from impact assessment reconnaissance trips carried out to a wide range of locations worldwide by our international research group and local collaborators. ‘Critical infrastructure’ includes those assets, frequently taken for granted, which are essential for the functioning of a society and economy. Electricity networks are very vulnerable to disruption from volcanic ash falls. This is particularly the case when fine ash is erupted because it has a greater tendency to adhere to line and substation insulators, where it can cause flashover (unintended electrical discharge) which can in turn cause widespread and disruptive outages. Weather conditions are a major determinant of flashover risk. Dry ash is not conductive, and heavy rain will wash ash from insulators, but light rain/mist will mobilise readily-soluble salts on the surface of the ash grains and lower the ash layer’s resistivity. Wet ash is also heavier than dry ash, increasing the risk of line breakage or tower/pole collapse. Particular issues for water supply managers include: monitoring turbidity levels in raw water intakes, and if necessary increasing chlorination to compensate for higher turbidity; managing water demand; and communicating monitoring results with the public to allay fears of contamination. Ash can cause major damage to wastewater disposal systems. Ash deposited onto impervious surfaces such as roads and car parks is very easily washed into storm drains, where it can form intractable masses and lead to long-term flooding problems. It can also enter wastewater treatment plants (WWTPs), both through sewer lines and by direct fallout. Damage to modern WWTPs can run into millions of dollars. Ash falls reduce visibility creating hazards for ground transportation. Dry ash is also readily remobilised by vehicle traffic and wind, and dry and wet ash deposits will reduce traction on paved surfaces, including airport runways. Ash cleanup from road and airports is commonly necessary, but the large volumes make it logistically challenging. Vehicles are vulnerable to ash; it will clog filters and brake systems and abrade moving parts within engines. Lastly, modern telecommunications networks appear to be relatively resilient to volcanic ash fall. Signal attenuation and interference during ash falls has not been reported in eruptions over the past 20 years, with the exception of interference from ash plume-generated lightning. However, some telecommunications equipment is vulnerable to airborne ash, in particular heating, ventilation and air-conditioning (HVAC) systems which may become blocked from ash ingestion leading to overheating. This summary of volcanic ash impacts on critical infrastructure provides insight into the relative vulnerability of infrastructure under a range of different ashfall scenarios. Identifying and quantifying these impacts is an essential step in building resilience within these critical systems. We have attempted to consider interdependencies between sectors in a holistic way using systems thinking. As modern society becomes increasingly complex and interdependent this approach is likely to become increasingly necessary.

Properties of ceramics prepared using dry discharged waste to energy bottom ash dust.

PubMed

Bourtsalas, Athanasios; Vandeperre, Luc; Grimes, Sue; Themelis, Nicolas; Koralewska, Ralf; Cheeseman, Chris

2015-09-01

The fine dust of incinerator bottom ash generated from dry discharge systems can be transformed into an inert material suitable for the production of hard, dense ceramics. Processing involves the addition of glass, ball milling and calcining to remove volatile components from the incinerator bottom ash. This transforms the major crystalline phases present in fine incinerator bottom ash dust from quartz (SiO(2)), calcite (CaCO(3)), gehlenite (Ca(2)Al(2)SiO(7)) and hematite (Fe(2)O(3)), to the pyroxene group minerals diopside (CaMgSi(2)O(6)), clinoenstatite (MgSi(2)O(6)), wollastonite (CaSiO(3)) together with some albite (NaAlSi(3)O(8)) and andradite (Ca(3)Fe(2)Si(3)O(12)). Processed powders show minimal leaching and can be pressed and sintered to form dense (>2.5 g cm(-3)), hard ceramics that exhibit low firing shrinkage (<7%) and zero water absorption. The research demonstrates the potential to beneficially up-cycle the fine incinerator bottom ash dust from dry discharge technology into a raw material suitable for the production of ceramic tiles that have potential for use in a range of industrial applications. © The Author(s) 2015.

Failure to phytosanitize ash firewood infested with emerald ash borer in a small dry kiln using ISPM-15 standards.

PubMed

Goebel, P Charles; Bumgardner, Matthew S; Herms, Daniel A; Sabula, Andrew

2010-06-01

Although current USDA-APHIS standards suggest that a core temperature of 71.1 degrees C (160 degrees F) for 75 min is needed to adequately sanitize emerald ash borer, Agrilus planipennis Fairmaire-infested firewood, it is unclear whether more moderate (and economical) treatment regimes will adequately eradicate emerald ash borer larvae and prepupae from ash firewood. We constructed a small dry kiln in an effort to emulate the type of technology a small- to medium-sized firewood producer might use to examine whether treatments with lower temperature and time regimes successfully eliminate emerald ash borer from both spilt and roundwood firewood. Using white ash (Fraxinus americana L.) firewood collected from a stand with a heavy infestation of emerald ash borer in Delaware, OH, we treated the firewood using the following temperature and time regime: 46 degrees C (114.8 degrees F) for 30 min, 46 degrees C (114.8 degrees F) for 60 min, 56 degrees C (132.8 degrees F) for 30 min, and 56 degrees C (132.8 degrees F) for 60 min. Temperatures were recorded for the outer 2.54-cm (1-in.) of firewood. After treatment, all firewood was placed under mesh netting and emerald ash borer were allowed to develop and emerge under natural conditions. No treatments seemed to be successful at eliminating emerald ash borer larvae and perpupae as all treatments (including two nontreated controls) experienced some emerald ash borer emergence. However, the 56 degrees C (132.8 degrees F) treatments did result in considerably less emerald ash borer emergence than the 46 degrees C (114.8 degrees F) treatments. Further investigation is needed to determine whether longer exposure to the higher temperature (56 degrees C) will successfully sanitize emerald ash borer-infested firewood.

Standardization of spray-dried powder of Piper betle hot water extract

PubMed Central

Arawwawala, Liyanage Dona Ashanthi Menuka; Hewageegana, Horadugoda Gamage Sujatha Pushpakanthi; Arambewela, Lakshmi Sriyani Rajapaksha; Ariyawansa, Hettiarachchige Sami

2011-01-01

The leaves of Piper betle Linn. (Family: Piperaceae) possess several bioactivities and are used in the Traditional Medical systems of Sri Lanka. The present investigation was carried out to standardize the spray-dried powder of P. betle by (a) determination of physicochemical parameters, presence or absence of heavy metals, and microbial contamination; (b) screening for phytochemicals; and (c) development of High Pressure Liquid Chromatography (HPLC) fingerprint and densitogram. The percentages of moisture content, total ash, acid insoluble ash, water-soluble ash, and ethanol extractable matter of spray-dried powder of P. betle were 2.2-2.5, 6.8-7.0, 0.003-0.005, 4.1-4.3, and 15.8-16.2, respectively. The concentrations of all the tested heavy metals were below the WHO acceptable limits and bacterial species, such as Escherichia coli, Salmonella spp, Staphylococcus aureus, and Pseudomonas aeroginosa were not present in the P. betle spray-dried powder. Phenolic compounds, tannins, flavonoids steroids, and alkaloids were found to be present in the spray-dried powder of P. betle and HPLC fingerprint and densitogram clearly demonstrated the proportional differences of these chemical constituents. In conclusion, the results obtained from this study can be used to standardize the spray-dried powder of P. betle. PMID:21716924

Standardization of spray-dried powder of Piper betle hot water extract.

PubMed

Arawwawala, Liyanage Dona Ashanthi Menuka; Hewageegana, Horadugoda Gamage Sujatha Pushpakanthi; Arambewela, Lakshmi Sriyani Rajapaksha; Ariyawansa, Hettiarachchige Sami

2011-04-01

The leaves of Piper betle Linn. (Family: Piperaceae) possess several bioactivities and are used in the Traditional Medical systems of Sri Lanka. The present investigation was carried out to standardize the spray-dried powder of P. betle by (a) determination of physicochemical parameters, presence or absence of heavy metals, and microbial contamination; (b) screening for phytochemicals; and (c) development of High Pressure Liquid Chromatography (HPLC) fingerprint and densitogram. The percentages of moisture content, total ash, acid insoluble ash, water-soluble ash, and ethanol extractable matter of spray-dried powder of P. betle were 2.2-2.5, 6.8-7.0, 0.003-0.005, 4.1-4.3, and 15.8-16.2, respectively. The concentrations of all the tested heavy metals were below the WHO acceptable limits and bacterial species, such as Escherichia coli, Salmonella spp, Staphylococcus aureus, and Pseudomonas aeroginosa were not present in the P. betle spray-dried powder. Phenolic compounds, tannins, flavonoids steroids, and alkaloids were found to be present in the spray-dried powder of P. betle and HPLC fingerprint and densitogram clearly demonstrated the proportional differences of these chemical constituents. In conclusion, the results obtained from this study can be used to standardize the spray-dried powder of P. betle.

Characterizing and quantifying the shrinkage resistance of alkali-activated (cement-free) concrete and evaluating potential methods for reducing early-age cracking in pavements and bridges.

DOT National Transportation Integrated Search

2015-12-01

This report summarizes the findings of an experimental investigation into shrinkage, and the mitigation thereof, in alkali-activated : fly ash and slag binders and concrete. The early-age (chemical and autogenous) and later-age (drying and : carbonat...

Effects of digestion, chemical separation, and deposition on Po-210 quantitative analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seiner, Brienne N.; Morley, Shannon M.; Beacham, Tere A.

Polonium-210 is a radioactive isotope often used to study sedimentation processes, food chains, aerosol behavior, and atmospheric circulations related to environmental sciences. Materials for the analysis of Po-210 range from tobacco leaves or cotton fibers, to soils and sediments. The purpose of this work was to determine polonium losses from a variety of sample types (soil, cotton fiber, and air filter) due to digestion technique, chemical separation, and deposition method for alpha energy analysis. Results demonstrated that yields from a perchloric acid wet-ash were similar to that from a microwave digestion. Both were greater than the dry-ash procedure. The poloniummore » yield from the perchloric acid wet ash was 87 ± 5%, the microwave digestion had a yield of 100 ± 7%, and the dry ash had a yield of 38 ± 5%. The chemical separation of polonium by an anion exchange resin was used only on the soil samples due to the complex nature of this sample. The yield of Po-209 tracer after chemical separation and deposition for alpha analysis was 83 ± 7% for the soil samples. Spontaneous deposition yields for the cotton and air filters were 87 ± 4% and 92 ± 6%, respectively. Based on the overall process yields for each sample type the amount of Po-210 was quantified using alpha energy analysis. The soil contained 0.18 ± 0.08 Bq/g, the cotton swipe contained 0.7 mBq/g, and the air filter contained 0.04 ± 0.02 mBq/g. High and robust yields of polonium are possible using a suitable digestion, separation, and deposition method.« less

Salt shell fallout during the ash eruption at the Nakadake crater, Aso volcano, Japan: evidence of an underground hydrothermal system surrounding the erupting vent

NASA Astrophysics Data System (ADS)

Shinohara, Hiroshi; Geshi, Nobuo; Yokoo, Akihiko; Ohkura, Takahiro; Terada, Akihiko

2018-03-01

A hot and acid crater lake is located in the Nakadake crater, Aso volcano, Japan. The volume of water in the lake decreases with increasing activity, drying out prior to the magmatic eruptions. Salt-rich materials of various shapes were observed, falling from the volcanic plume during the active periods. In May 2011, salt flakes fell from the gas plume emitted from an intense fumarole when the acid crater lake was almost dry. The chemical composition of these salt flakes was similar to those of the salts formed by the drying of the crater lake waters, suggesting that they originated from the crater lake water. The salt flakes are likely formed by the drying up of the crater lake water droplets sprayed into the plume by the fumarolic gas jet. In late 2014, the crater lake dried completely, followed by the magmatic eruptions with continuous ash eruptions and intermittent Strombolian explosions. Spherical hollow salt shells were observed on several occasions during and shortly after the weak ash eruptions. The chemical composition of the salt shells was similar to the salts formed by the drying of the crater lake water. The hollow structure of the shells suggests that they were formed by the heating of hydrothermal solution droplets suspended by a mixed stream of gas and ash in the plume. The salt shells suggest the existence of a hydrothermal system beneath the crater floor, even during the course of magmatic eruptions. Instability of the magmatic-hydrothermal interface can cause phreatomagmatic explosions, which often occur at the end of the eruptive phase of this volcano.

21 CFR 184.1979a - Reduced lactose whey.

Code of Federal Regulations, 2013 CFR

2013-04-01

....199 (dry sample), entitled “Fat in Dried Milk (45)—Official Final Action.” (iii) Ash content, 11 to 27...—Official Final Action” under the heading “Dried Milk, Nonfat Dry Milk, and Malted Milk.” (iv) Lactose... section 16.192, entitled “Moisture (41)—Official Final Action” under the heading “Dried Milk, Nonfat Dry...

21 CFR 184.1979a - Reduced lactose whey.

Code of Federal Regulations, 2012 CFR

2012-04-01

....199 (dry sample), entitled “Fat in Dried Milk (45)—Official Final Action.” (iii) Ash content, 11 to 27...—Official Final Action” under the heading “Dried Milk, Nonfat Dry Milk, and Malted Milk.” (iv) Lactose... section 16.192, entitled “Moisture (41)—Official Final Action” under the heading “Dried Milk, Nonfat Dry...

Novel dry-desulfurization process using Ca(OH)2/fly ash sorbent in a circulating fluidized bed.

PubMed

Matsushima, Norihiko; Li, Yan; Nishioka, Masateru; Sadakata, Masayoshi; Qi, Haiying; Xu, Xuchang

2004-12-15

A dry-desulfurization process using Ca(OH)2/fly ash sorbent and a circulating fluidized bed (CFB) was developed. Its aim was to achieve high SO2 removal efficiency without humidification and production of CaSO4 as the main byproduct. The CaSO4 produced could be used to treat alkalized soil. An 83% SO2 removal rate was demonstrated, and a byproduct with a high CaSO4 content was produced through baghouse ash. These results indicated that this process could remove SO2 in flue gas with a high efficiency under dry conditions and simultaneously produce soil amendment. It was shown that NO and NO2 enhanced the SO2 removal rate markedly and that NO2 increased the amount of CaSO4 in the final product more than NO. These results confirmed that the significant effects of NO and NO2 on the SO2 removal rate were due to chain reactions that occurred under favorable conditions. The amount of baghouse ash produced increased as the reaction progressed, indicating that discharge of unreacted Ca(OH)2 from the reactor was suppressed. Hence, unreacted Ca(OH)2 had a long residence time in the CFB, resulting in a high SO2 removal rate. It was also found that 350 degrees C is the optimum reaction temperature for dry desulfurization in the range tested (320-380 degrees C).

21 CFR 168.120 - Glucose sirup.

Code of Federal Regulations, 2011 CFR

2011-04-01

... sulfated ash content is not more than 1.0 percent m/m (calculated on a dry basis), and the sulfur dioxide...(a). (3) Sulfated ash content, section 31.216. (4) Sulfur dioxide content, sections 20.106-20.111...

21 CFR 168.120 - Glucose sirup.

Code of Federal Regulations, 2010 CFR

2010-04-01

... sulfated ash content is not more than 1.0 percent m/m (calculated on a dry basis), and the sulfur dioxide...(a). (3) Sulfated ash content, section 31.216. (4) Sulfur dioxide content, sections 20.106-20.111...

Rainfall and wet and dry cycle's impact on ash thickness. A laboratory experiment

NASA Astrophysics Data System (ADS)

Pereira, Paulo; Keestra, Saskia; Peters, Piet; Cerdà, Artemi

2016-04-01

Ash is the most important and effective soil protection in the immediate period after the fire (Cerda and Doerr, 2008; Pereira et al., 2015a). This protection can last for days or weeks depending on the fire severity, topography of the burned area and post-fire meteorological conditions. In the initial period after the fire, ash is easily transported by wind. However after the first rainfalls, ash is eroded, or bind in soil surface (Pereira et al., 2013, 2015a). Ash thickness has implications on soil protection. The soil protection against the erosion and the ash capacity to retain water increases with the ash thickness (Bodi et al., 2014). Ash cover is very important after fire because store water and releases into soil a large amount of nutrients, fundamental to vegetation recuperation (Pereira et al., 2014). Despite the importance of ash thickness in post fire environments, little information is available about the effects of rainfall and wet and dry cycle's effects on ash thickness. This work aims to fill this gap. The objective of this study is to investigate the impacts of rainfall and wet and dry cycles in the ash thickness of two different under laboratory conditions. Litter from Oak (Quercus robur) and Spruce (Picea abis) were collected to and exposed during 2 hours to produce ash at 200 and 400 C. Subsequently a layer of 15 mm ash was spread on soil surface in small boxes (24x32 cm) and then subjected to rainfall simulation. Boxes were placed at a 17% of inclination and a rainfall intensity of 55 mm/h during 40 minutes was applied. After the rainfall simulation the plots were stored in an Oven at the temperature of 25 C during four days, in order to identify the effects of wet and dry cycles (Bodi et al., 2013). Ash thickness was measured after the first rainfall (AFR), before the second rainfall (BSR) - after the dry period of 4 days - and after the second rainfall (ASR). In each box a grid with 57 points was designed in order to analyse ash thickness AFR, BSR and ASR. The results showed that AFR, ash thickness was reduced by 7.97% (±18.13) and 32.02 % (±37.44) in the Oak ash produced at 200 C (Oak 200) and 400 C (Oak 400), respectively. The spruce ash layer produced at 200 (Spruce 200) decreased 7.26% (±15.11) and 13.11 % (±18.40) in the ash produced at 400 C (Spruce 400). Before the second rainfall we identified that Oak 200 ash layer reduced approximately 15.95 (±15.81) while Oak 400 decreased 47.98% (±28.97). Spruce 200 ash layer was reduced by 14.52 (±14.57) and Spruce 400 by 18.68 (±17.54). In the last rainfall experiment, it was observed that Oak 200 ash layer decreased 14.88 (±14.09) and Oak 400 ash layer 44.52 (±28.85). Spruce 200 ash layer reduced 13.10 (±14.76) and spruce 400 18.33 (±21.69). The spatial pattern (assessed with Moran's I index) of the ash later of Oak 200 and Oak 400 AFR was significantly clustered (p<0.001). The spatial pattern of Spruce 200 was random (p>0.05) and Spruce 400 significantly clustered (p<0.001). Before the second rainfall, the spatial pattern of Oak 200 and Oak 400 was significantly clustered at a p<0.05 and p<0.001. The same situation was identified in Spruce 200 and Spruce 400 (p<0.001). Finally, ASR, the spatial pattern observed in Oak 200 and Oak 400 was significantly clustered at a p<0.05 and p<0.001. This was also identified in Spruce 200 and Spruce 400. Overall, the thickness decrease was higher in the ash layers produced at high temperature. The differences were mainly observed in oak ash. The dry cycle did not have an important impact on ash thickness in both species as the second rainfall cycle. The results from the Moran's I analysis showed that after the rainfall experiment the ash was mainly concentrated in a specific part of the plot. In this case it was located in the bottom of the experimental plot. Acknowledgments The authors are thankful to the Soil Physics and Land Management Group from Wageningen University, The Netherlands for provide the infrastructure to develop this work, to the RECARE project (grant agreement n° 603498), and to the COST action ES1306: Connecting European Connectivity Research for funding a STSM at the Wageningen University. References Bodi, M., Martin, D.A., Santin, C., Balfour, V., Doerr, S.H., Pereira, P., Cerda, A., Mataix-Solera, J. (2014) Wildland fire ash: production, composition and eco-hydro-geomorphic effects. Earth-Science Reviews, 130, 103-127. Bodi, M.B., Doerr, S.H., Cerda, A., Mataix-Solera, J. (2013) Hydrological effects of a layer of vegetation ash on underlying wettable and water repellent soil. Geoderma, 191, 14-23. Cerdà, A., Doerr, S.H., 2008. The effect of ash and needle cover on surface runoff and erosion in the immediate post-fire period. Catena 74, 256-263. Pereira, P., Cerdà, A., Úbeda, X., Mataix-Solera, J., Jordan, A. Burguet, M. (2013) Spatial models for monitoring the spatio-temporal evolution of ashes after fire - a case study of a burnt grassland in Lithuania, Solid Earth, 4, 153-165. Pereira, P., Cerdà, A., Úbeda, X., Mataix-Solera, J. Arcenegui, V., Zavala, L. (2015) Modelling the impacts of wildfire on ash thickness in a short-term period, Land Degradation and Development, 26, 180-192. Pereira, P., Jordan, A., Cerda, A., Martin, D. 2015a. Editorial: The role of ash in fire-affected ecosystems, Catena, 135, 337 - 379. Pereira, P., Úbeda, X., Martin, D., Mataix-Solera, J., Cerdà, A., Burguet, M. (2014)Wildfire effects on extractable elements in ash from a Pinus pinaster forest in Portugal, Hydrological Processes, 28, 3681-3690

[Proximate analysis of straw by near infrared spectroscopy (NIRS)].

PubMed

Huang, Cai-jin; Han, Lu-jia; Liu, Xian; Yang, Zeng-ling

2009-04-01

Proximate analysis is one of the routine analysis procedures in utilization of straw for biomass energy use. The present paper studied the applicability of rapid proximate analysis of straw by near infrared spectroscopy (NIRS) technology, in which the authors constructed the first NIRS models to predict volatile matter and fixed carbon contents of straw. NIRS models were developed using Foss 6500 spectrometer with spectra in the range of 1,108-2,492 nm to predict the contents of moisture, ash, volatile matter and fixed carbon in the directly cut straw samples; to predict ash, volatile matter and fixed carbon in the dried milled straw samples. For the models based on directly cut straw samples, the determination coefficient of independent validation (R2v) and standard error of prediction (SEP) were 0.92% and 0.76% for moisture, 0.94% and 0.84% for ash, 0.88% and 0.82% for volatile matter, and 0.75% and 0.65% for fixed carbon, respectively. For the models based on dried milled straw samples, the determination coefficient of independent validation (R2v) and standard error of prediction (SEP) were 0.98% and 0.54% for ash, 0.95% and 0.57% for volatile matter, and 0.78% and 0.61% for fixed carbon, respectively. It was concluded that NIRS models can predict accurately as an alternative analysis method, therefore rapid and simultaneous analysis of multicomponents can be achieved by NIRS technology, decreasing the cost of proximate analysis for straw.

Ash Tree Leaf Litter (Fraxinus excelsior L.) Breakdown in Two Different Biotopes and Streams

NASA Astrophysics Data System (ADS)

Fleituch, Tadeusz; Leichtfried, Maria

2004-11-01

Coarse (0.5 mm) and fine (0.1 mm) mesh size bag methodology was used for comparing the breakdown of ash tree leaves (Fraxinus excelsior L.) in two biotopes (dry - terrestrial and wet - overflown stream zones) in two low order streams (the Oberer Seebach (OSB), Lower Austria and the Brzezowka stream (BRZ), Beskidy Mountains, southern Poland). In total, 96 bags were exposed in autumn 2000. Ash-free dry mass (AFDM) ranged in dry zones of both streams from 94-62% (OSB) and 85-53% (BRZ) respectively. The decomposition process was faster in wet zones: 96-33% (OSB) and 56-11% (B) during the study period. Significant differences in ash breakdown and its chemical content between studied streams were found. Total organic carbon (TOC) and total nitrogen content (TN) of AFDM of litter showed increased differences with experiment duration between zones and between two bag types for both streams. The strongest increase of TOC and TN content (100% on average initial content) for bag types, zones, and streams was observed in the first two weeks of the experiment. These results confirm the importance of chemical compounds for microbiological processes (biofilms) in different ecosystem biotopes. (

Process Simulation and Cost Analysis for Removing Inorganics from Wood Chips using Combined Mechanical and Chemical Preprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Hongqiang; Westover, Tyler L.; Cherry, Robert

Naturally occurring and introduced inorganic species (ash) in biomass feedstocks negatively impact thermochemical energy conversion processes such as pyrolysis, hydrothermal liquefaction, gasification and combustion to biopower. As such, it is desirable to better understand the cost:benefit ratios of various ash reduction processes. Here, a novel process simulation model was developed using AspenPlus to reduce the ash content of Loblolly logging residues using both air classification and a dilute-acid leaching process. For costing purposes, a throughput of 25 tons/hour was selected. At this scale, the process cost for a standalone air classification process was $3 per ton for a biomass feedstock.more » Ash reduction via dilute –acid leaching was simulated based on experimentally determined kinetics of ion diffusion at an acid concentration of 0.5% H2SO4 and temperature of 75°F. The total estimated processing cost for leaching at these conditions was approximately $14/ton of dry biomass. Sensitivity analysis of three parameters on mineral reduction in the leaching process revealed that increasing leaching temperature was not economically feasible, while it was viable to apply a longer retention time in leaching for higher ash removal or achieve a lower water content in final products with reasonable extra costs. In addition, scenarios combining air classification with leaching were examined. A whole process cost of approximately $16/ton of biomass at a biomass feedstock rate of 25 ton/hour considering a 9% of biomass classified as light fraction to be leached. The leaching operating costs constituted 75% of this amount, of which the heating costs of dryer was 44%. This suggests that the process costs would be substantially reduced if more efficient drying methods are applied in future.« less

Osteoporotic-like effects of cadmium on bone mineral density and content in aged ovariectomized beagles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sacco-Gibson, N.; Abrams, J.; Chaudhry, S.

1992-12-31

Our purpose was to evaluate the effects of ovariectomy in conjunction with cadmium (Cd) exposure on bone. Aged female beagles with {sup 45}Ca-labeled skeletons ovariectomized and exposed to Cd. Successive vertebral scans by dual photon absorptiometry monitored changes in bone mineral density (BMD) in each dog with time. Results showed that ovariectomy or Cd exposure alone caused significant decreases in BMD; ovariectomy with Cd exposure caused the greatest decrease. Ovariectomy alone did not decrease BMD in the distal end or mid-shaft of the tibia while BMD of the distal tibia decreased significantly due to Cd exposure alone. Combination treatment resultedmore » in significant decreases in BMD of both tibial regions. At necropsy, tibiae, humeri, lumbar vertebrae and ribs were obtained for biochemical analysis. No group-to-group differences in bone weights (wet, dry, ash), in ash/dry ratios, or in long bone and vertebral Ca/dry or Ca/ash ratios were observed. Significantly higher total {sup 45}Ca content and {sup 45}Ca/dry and {sup 45}Ca/ash ratios were observed in long bones and vertebrae of OV- and OV+ groups. In contrast, intact ribs showed significantly decreased Ca/dry and Ca/ash ratios compared to the SO-group. Quartered ribs demonstrated regional responses to specific treatment; decreases in total Ca content were greatest in the mid-rib region ({minus}36 to {minus}46%). Results suggest that in the aged female beagle, bone mineral loss associated with estrogen depletion is not only related to bone type (trabecular versus cortical) but also to bone Ca pools. Our results also suggest that a regional heterogeneity of bone plays a role in responsiveness to ovariectomy and Cd exposure. These aspects suggest that Cd is an exogenous factor affecting bone mineral loss independently of estrogen depletion. However, estrogen depletion primes bone for responsiveness to Cd-induced bone mineral loss.« less

21 CFR 168.111 - Dextrose monohydrate.

Code of Federal Regulations, 2010 CFR

2010-04-01

... than 99.5 percent m/m calculated on a dry basis. (2) The sulfated ash content is not more than 0.25...) Sulfated ash content, section 31.216. (4) Sulfur dioxide content, sections 20.106-20.111. [42 FR 14479, Mar...

21 CFR 168.111 - Dextrose monohydrate.

Code of Federal Regulations, 2011 CFR

2011-04-01

... than 99.5 percent m/m calculated on a dry basis. (2) The sulfated ash content is not more than 0.25...) Sulfated ash content, section 31.216. (4) Sulfur dioxide content, sections 20.106-20.111. [42 FR 14479, Mar...

Trends in domestic and international markets for ash logs and lumber

Treesearch

Dan Meyer

2010-01-01

While ash is a "minor" commercial hardwood species relative to oak, poplar, and maple, it still accounts for roughly 3 percent of all hardwood lumber produced, with an estimated kiln-dried value exceeding $150 million annually.

Measurement of Iron in Egg Yolk: An Instrumental Analysis Experiment Using Biochemical Principles

ERIC Educational Resources Information Center

Maloney, Kevin M.; Quiazon, Emmanuel M.; Indralingam, Ramee

2008-01-01

The generally accepted method to determine iron content in food is by acid digestion or dry ashing and subsequent flame atomic absorption spectrometry or inductively coupled plasma atomic emission spectrometry. We have developed an experiment that chemically extracts the iron from an egg yolk and quantifies it using UV-vis absorption…

Environmentally-friendly animal litter

DOEpatents

Boxley, Chett; McKelvie, Jessica

2012-08-28

An animal litter composition including geopolymerized ash particulates having a network of repeating aluminum-silicon units is described herein. Generally, the animal litter is made from a quantity of a pozzolanic ash mixed with a sufficient quantity of water and an alkaline activator to initiate a geopolymerization reaction that forms geopolymerized ash. After the geopolymerized ash is formed, it is dried, broken into particulates, and sieved to a desired size. These geopolymerized ash particulates are used to make a non-clumping or clumping animal litter. Odor control is accomplished with the addition of a urease inhibitor, pH buffer, an odor eliminating agent, and/or fragrance.

Environmentally-friendly animal litter

DOEpatents

Boxley, Chett; McKelvie, Jessica

2013-09-03

An animal litter composition that includes geopolymerized ash particulates having a network of repeating aluminum-silicon units is described herein. Generally, the animal litter is made from a quantity of a pozzolanic ash mixed with an alkaline activator to initiate a geopolymerization reaction that forms geopolymerized ash. This geopolymerization reaction may occur within a pelletizer. After the geopolymerized ash is formed, it may be dried and sieved to a desired size. These geopolymerized ash particulates may be used to make a non-clumping or clumping animal litter or other absorbing material. Aluminum sulfate, clinoptilolite, silica gel, sodium alginate and mineral oil may be added as additional ingredients.

Comparative Effect of Bio-waste Ashes on Strength Properties of Cement Mortar

NASA Astrophysics Data System (ADS)

Ajay, Goyal; Hattori, Kunio; Ogata, Hidehiko; Ashraf, Muhammad; Ahmed, Mohamed Anwar

Biomass fuels produce about 400 million tonnes of ashes as waste material. This paper discusses the pozzolanic character of bio-waste ashes obtained from dry tree leaves (AML), Korai grass (KRI) and Tifton grass (TFT). Ashes were obtained by control incineration of the wastes at 600°C for 5 hours and mortar specimens were prepared by substituting cement with 10, 20 and 30% ash. Strength development of ash-blended mortar specimens was evaluated by conducting destructive tests as well as non-destructive tests till 91 days. X-ray diffraction, scanning electron microscopic and thermo-gravimetric techniques were used to analyze the influence of ash substitution on strength properties of blended-mortar. Pozzolanic reactivity of AML- and KRI-ash was confirmed, but TFT-ash did not show enough reactivity. Overall results confirmed that up to 20% substitution of cement can be made with AML- or KRI-ash with strength approaching 90% of that of control.

Recovery of Technetium Adsorbed on Charcoal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Engelmann, Mark D.; Metz, Lori A.; Ballou, Nathan E.

2006-05-01

Two methods capable of near complete recovery of technetium adsorbed on charcoal are presented. The first involves liquid extraction of the technetium from the charcoal by hot 4M nitric acid. An average recovery of 98% (n=3) is obtained after three rounds of extraction. The second method involves dry ashing with air in a quartz combustion tube at 400-450 C. This method yields an average recovery of 96% (n=5). Other thermal methods were attempted, but resulted in reduced recovery and incomplete material balance

Causes of Variability in the Effects of Vegetative Ash on Post-Fire Runoff and Erosion

NASA Astrophysics Data System (ADS)

Balfour, V.; Woods, S.

2008-12-01

Vegetative ash formed during forest wildfires has varying effects on post-fire runoff and erosion. In some cases the ash layer reduces runoff and erosion by storing rainfall and by protecting the soil surface from surface sealing and rainsplash detachment. In other cases, the ash layer increases runoff and erosion by forming a surface crust, clogging soil pores, and providing a ready source of highly erodible fine material. Since only a handful of studies have measured the hydrogeomorphic effect of ash, it is unclear whether the observed variability in its effect reflects initial spatial variability in the ash properties due to factors such as fuel type and fire severity, or differences that develop over time due to compaction and erosion or exposure of the ash to rainfall and air. The goal of our research was to determine if the observed differences in the effect of ash on runoff and erosion are due to: 1) variability in initial ash hydrologic properties due to differences in combustion temperature and fuel type, or 2) variability in ash hydrologic properties caused by mineralogical phase changes that develop after the ash is exposed to water. We created ash in the laboratory using wood and needles of Lodgepole pine (Pinus contorta), Ponderosa pine (Pinus Ponderosa) and Douglas fir (Pseudotsuga menziesii) and at 100° C temperature increments from 300 to 900° C. A subsample of ash from each fuel type / temperature combination was saturated, left undisturbed for 24 hours and then oven dried at 104° C. Dry and wetted ash samples were characterized in terms of: structure (using a scanning electron microscope), carbon content, mineralogy (using X-ray diffraction), porosity, water retention properties and hydraulic conductivity. Ash produced at the higher combustion temperatures from all three fuel types contained lime (CaO), which on wetting was transformed to portlandite (Ca(OH)2) and calcite (CaCO3). This mineralogical transformation resulted in irreversible hardening and crusting of the ash, and hardened ash had a significantly lower hydraulic conductivity than unhardened ash. Ash produced by high severity fires may undergo this same hardening and crusting process after it is wetted by rainfall whereas ash produced by lower severity fires will not, and this may explain in part the contrasting hydrogeomorphic effects of ash that have been reported in the literature.

Curcuma longa L. leaves: Characterization (bioactive and antinutritional compounds) for use in human food in Brazil.

PubMed

Braga, Monick Cristina; Vieira, Ellen Caroline Silvério; de Oliveira, Tatianne Ferreira

2018-11-01

This study evaluated the physicochemical characterization of Curcuma longa L. leaves with respect to proximate composition, mineral content, the presence of antinutritional factors, content of bioactive compounds and antioxidant capacity, and color measurements of leaves in natura and leaves subjected to microwave drying, oven drying, and freeze-drying methods. The proximate composition showed appreciable levels of protein (39.5 g.100 g -1 ), carbohydrates (44.74 g.100 g -1 ), total fiber (34.47 g.100 g -1 ), soluble fiber (22.65 g.100 g -1 ), insoluble fiber (11.81 g.100 g -1 ), ash (13.81 g.100 g -1 ), and low lipid contents (2.47 g.100 g -1 ). No cyanogenic compounds were detected in both samples. Freeze-drying stood out as the method that led to the greatest reductions of the bioactive compounds (33.12-73.86%, dry basis) and antioxidant capacity when compared to the leaves in natura. Microwave drying was the preservation method that produced dry leaves with higher content of bioactive compounds and antioxidant capacity. Therefore, microwave drying produced dehydrated Curcuma longa L. leaves with the highest bioactive compounds and antioxidant activity. Copyright © 2018 Elsevier Ltd. All rights reserved.

Common relationships among proximate composition components in fishes

USGS Publications Warehouse

Hartman, K.J.; Margraf, F.J.

2008-01-01

Relationships between the various body proximate components and dry matter content were examined for five species of fishes, representing anadromous, marine and freshwater species: chum salmon Oncorhynchus keta, Chinook salmon Oncorhynchus tshawytscha, brook trout Salvelinus fontinalis, bluefish Pomatomus saltatrix and striped bass Morone saxatilis. The dry matter content or per cent dry mass of these fishes can be used to reliably predict the per cent composition of the other components. Therefore, with validation it is possible to estimate fat, protein and ash content of fishes from per cent dry mass information, reducing the need for costly and time-consuming laboratory proximate analysis. This approach coupled with new methods of non-lethal estimation of per cent dry mass, such as from bioelectrical impedance analysis, can provide non-destructive measurements of proximate composition of fishes. ?? 2008 The Authors.

Determination of iodine in bread and fish using the iodide ion-selective electrode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steiner, J.B.

The purpose of this study was to assess the potential for use of the ion-selective electrode (ISE) as a method for measuring the iodine content in bread and fish. Ashing methods, sample preparation and electrode responses were evaluated. The iodine values obtained using the iodide electrode were compared to iodine values obtained by the arsenic-cerium method (As-Ce). Ashing methods were used in preparing bread and haddock for iodine analysis by the ISE. The values were compared to unashed samples measured by the ISE. Electrode response to iodide was examined by varying the sample pH, measuring electrode equilibrium times, and comparingmore » direct measurement in ppm to iodide values obtained by the method of known addition. Oyster reference tissue with a known iodine concentration was used to determine rates of recovery. For the As-Ce procedure, an alkaline dry ash for two hour followed by colorimetric analysis at 320 nm was recommended. The study showed that the pre-treatment of bread and fish was necessary for ISE measurement. The iodine values obtained by the ISE in the analysis of oyster reference tissue, haddock and bread were not in agreement with their corresponding As-Ce values. Further work needs to be done to determine an ashing procedure that has minimal iodide loss an/or develop sample treatments that will improve the reliability and precision of iodine values obtained using the ion-selective electrode.« less

Effects of yeast, fermentation time, and preservation methods on tarhana.

PubMed

Gurbuz, Ozan; Gocmen, Duygu; Ozmen, Nese; Dagdelen, Fatih

2010-01-01

The physicochemical properties of tarhana soup produced with different dough treatments, fermentation times, and preservation methods were examined. Tarhana doughs were prepared with yogurt (control) or baker's yeast (Saccharomyces cerevisiae) and fermented for 3 days. Samples were taken at 24, 48, and 72 hr. Samples were then preserved via one of four methods: sun dried, dried in the shade, vacumn dried, and frozen. Frozen samples produced lower organic acid levels after 72 hr of fermentation in both control (0.68 g/100 g) and yeast (0.61 g/100 g) applications than samples that were dried (0.94 g/100 g control samples; 0.81 g/100 g samples with yeast). Increasing fermentation time resulted in a significant effect on the formation of organic acid in the tarhana (p < .01). At 72 hr of fermentation, total acidity increased 11%, 17%, and 23% for tarhana samples vacumn-dried, sun-dried, and dried in the shade, respectively. Preservation methods also affected the moisture, ash, crude protein, total acidity, pH, salt, fat, reducing sugar levels, and the sensory assestment of tarhana soup (p < .01). Sensory characteristics were not significantly affected by baker's yeast in any of the preservation methods used (p > .01). However, sensory scores for tarhana prepared from the samples dried in a sheltered area showed a reduction in color desireablilty as the fermentation time increased. The soup prepared from frozen tarhana (72 hr fermentation, with yeast) had the highest scores with respect to color, mouth feel, flavor, and overall acceptability. Vacuum-dried samples' scores in these areas were also high in comparison to the two other drying methods.

Dry sliding behavior of aluminum alloy 8011 with 12% fly ash composites

NASA Astrophysics Data System (ADS)

Magibalan, S.; Senthilkumar, P.; Palanivelu, R.; Senthilkumar, C.; Shivasankaran, N.; Prabu, M.

2018-05-01

This research focused on the fabrication of aluminum alloy 8011 with 12% fly ash (FA) composite (AA8011%–12% FA) using the stir casting method. A three-level central composite design experiment was developed using response surface methodology with various parameters such as load, time, and sliding velocity varied in the range of 5 to 15 N, 5 to 15 min, and 1.5 to 4.5 m.s‑1, respectively. Dry sliding wear tests were performed as per the experimental design using a pin on disc at room temperature. The obtained regression result indicated that the developed model performed well in relating the wear process parameters and predicted the wear behavior of the composite. The surface plot showed that the wear rate increases with increase in load, time, and sliding velocity. Hardness was evaluated by Vickers hardness testing machine. Moreover, the surface morphology of the worn-out composite was examined using a scanning electron microscope.

Methods to recover value-added coproducts from dry grind processing of grains into fuel ethanol.

PubMed

Liu, Keshun; Barrows, Frederic T

2013-07-31

Three methods are described to fractionate condensed distillers solubles (CDS) into several new coproducts, including a protein-mineral fraction and a glycerol fraction by a chemical method; a protein fraction, an oil fraction and a glycerol-mineral fraction by a physical method; or a protein fraction, an oil fraction, a mineral fraction, and a glycerol fraction by a physicochemical method. Processing factors (ethanol concentration and centrifuge force) were also investigated. Results show that the three methods separated CDS into different fractions, with each fraction enriched with one or more of the five components (protein, oil, ash, glycerol and other carbohydrates) and thus having different targeted end uses. Furthermore, because glycerol, a hygroscopic substance, was mostly shifted to the glycerol or glycerol-mineral fraction, the other fractions had much faster moisture reduction rates than CDS upon drying in a forced air oven at 60 °C. Thus, these methods could effectively solve the dewatering problem of CDS, allowing elimination of the current industrial practice of blending distiller wet grains with CDS for drying together and production of distiller dried grains as a standalone coproduct in addition to a few new fractions.

Hydrodesulfurization and hydrodenitrogenation catalysts obtained from coal mineral matter

DOEpatents

Liu, Kindtoken H. D.; Hamrin, Jr., Charles E.

1982-01-01

A hydrotreating catalyst is prepared from coal mineral matter obtained by low temperature ashing coals of relatively low bassanite content by the steps of: (a) depositing on the low temperature ash 0.25-3 grams of an iron or nickel salt in water per gram of ash and drying a resulting slurry; (b) crushing and sizing a resulting solid; and (c) heating the thus-sized solid powder in hydrogen.

Bench-scale performance testing and economic analyses of electrostatic dry coal cleaning. Final report, October 1980-July 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rich, S.R.

1987-02-01

The report gives results of preliminary performance evaluations and economic analyses of the Advanced Energy Dynamics (AED) electrostatic dry coal-cleaning process. Grab samples of coal-feed-product coals were obtained from 25 operating physical coal-cleaning (PCC) plants. These samples were analyzed for ash, sulfur, and energy content and splits of the original samples of feed run-of-mine coal were provided for bench-scale testing in an electrostatic separation apparatus. The process showed superior sulfur-removal performance at equivalent cost and energy-recovery levels. The ash-removal capability of the process was not evaluated completely: overall, ash-removal results indicated that the process did not perform as well asmore » the PCC plants.« less

Process for the encapsulation and stabilization of radioactive, hazardous and mixed wastes

DOEpatents

Colombo, Peter; Kalb, Paul D.; Heiser, III, John H.

1997-11-14

The present invention provides a method for encapsulating and stabilizing radioactive, hazardous and mixed wastes in a modified sulfur cement composition. The waste may be incinerator fly ash or bottom ash including radioactive contaminants, toxic metal salts and other wastes commonly found in refuse. The process may use glass fibers mixed into the composition to improve the tensile strength and a low concentration of anhydrous sodium sulfide to reduce toxic metal solubility. The present invention preferably includes a method for encapsulating radioactive, hazardous and mixed wastes by combining substantially anhydrous wastes, molten modified sulfur cement, preferably glass fibers, as well as anhydrous sodium sulfide or calcium hydroxide or sodium hydroxide in a heated double-planetary orbital mixer. The modified sulfur cement is preheated to about 135.degree..+-.5.degree. C., then the remaining substantially dry components are added and mixed to homogeneity. The homogeneous molten mixture is poured or extruded into a suitable mold. The mold is allowed to cool, while the mixture hardens, thereby immobilizing and encapsulating the contaminants present in the ash.

Interspecies differences and variability with time of protein precipitation activity of extractable tannins, crude protein, ash, and dry matter content of leaves from 13 species of Nepalese fodder trees.

PubMed

Wood, C D; Tiwari, B N; Plumb, V E; Powell, C J; Roberts, B T; Padmini Sirimane, V D; Rossiter, J T; Gill, M

1994-12-01

Dry matter, ash, crude protein, and protein precipitation activity (PPA) of 13 Nepalese tree fodder species were monitored in dried samples prepared monthly between November 1990 and May 1991, and additionally in November 1991, covering the season when they are particularly important as fodder. Monthly levels of dry matter, ash, and crude protein were fairly stable except when there was new leaf growth, although year to year differences in dry matter were found inBrassaiopsis hainla (Bh),Dendrocalamus strictus (Ds),Ficus roxburghii (Fr), andQuercus semecarpifolia (Qs). Tannin PPA fluctuated considerably inArtocarpus lakoocha (Al),Ficus glaberrima (Fg),F. nerrifolia (Fn), Fr,F. semicordata (Fs),Litsea polyantha (Lp), andPrunus cerasoides (Pc), and to a lesser extent in Bh,Castanopsis indica (Ci),C. tribuloides (Ct),Quercus lamellosa (Ql), and Qs. Similar fluctuations in PPA were observed in fresh leaf samples taken weekly. Ds did not have any detectable PPA. Trends in PPA fluctuation were generally similar for trees located at similar altitudes. Fr, Pc, Al, Fn, Ql, and Ci had falling PPAs before shedding leaves. Some of the fluctuations in Fr, Fs, Fg, Pc, and Lp were apparently due to changes in the extractability and quantity of condensed tannins. These fluctuations in PPA may affect the nutritive value of the fodders.

The study of the burning possibilities of solid combustibles in the determined conditions for complete usage of caloric [energy] and ashes resulted

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voina, N.I.; Barca, F.; Mogos, D.

1995-12-31

In modern combustors, 95--98% of the organic mass of a solid combustible is converted into caloric energy; 2--4% remain in the fly ash captured in electrofilters and hydraulically removed in most cases. The 2--4% unburned materials in fly ash, together with the water from being hydraulically transported, make it difficult for the use of the fly ash for metal extraction or as a binder in the materials industry. This work presents the research results of a study in which the burning process was modified to result in fly ash without carbon content and fly ash removal by dry capture. Laboratorymore » fluidized-bed combustion of lignite with and without addition of limestone for sulfur capture was used to generate ashes for further study. The ashes were studied for their use as binders and as a cement substitute.« less

Volcanic Ash fall Impact on Vegetation, Colima 2005

NASA Astrophysics Data System (ADS)

Garcia, M. G.; Martin, A.; Fonseca, R.; Nieto, A.; Radillo, R.; Armienta, M.

2007-05-01

An ash sampling network was established arround Colima Volcano in 2005. Ash fall was sampled on the North, Northeast, East, Southeast, South, Southwest and West of the volcano. Samples were analyzed for ash components, geochemistry and leachates. Ash fall ocurred on April (12), May (10, 23), June (2, 6, 9, 10, 12, 14), July (27), September (27), October (23) and November (24). Most of the ash is made of andesitic dome-lithics but shows diferences in crystal, juvenile material and lithic content. In May, some samples contained grey and dark pumice (scoria). Texture varies from phi >4 to phi 0. Leachate concentration were low: SO4 (7.33-54.19) Cl- (2.29-4.97) and F- (0.16-0.37). During 2005, Colima Volcano's ash fall rotted some of the guava and peach fruits and had a drying effect on spearment and epazote plants. Even these small ash amounts could have hindered sugar cane and agave growth.

Differential growth and yield by canola (Brassica napus L.) and wheat (Triticum aestivum L.) arising from alterations in chemical properties of sandy soils due to additions of fly ash.

PubMed

Yunusa, Isa A M; Manoharan, Veeragathipillai; Harris, Rob; Lawrie, Roy; Pal, Yash; Quiton, Jonathan T; Bell, Richard; Eamus, Derek

2013-03-30

There is a need for field trials on testing agronomic potential of coal fly ash to engender routine use of this technology. Two field trials were undertaken with alkaline and acidic fly ashes supplied at between 3 and 6 Mg ha⁻¹ to acidic soils and sown to wheat and canola at Richmond (Eastern Australia) and to wheat only at Merredin (Western Australia). Ash addition marginally (P< 0.10) raised the pH in the top soil layers at both sites. The exceptionally dry season at both sites constrained yields and thwarted any likelihood of gaining yield benefits from ash-induced improvements in soil conditions. Yield improvements due to ash addition were absent at Merredin and only marginal at Richmond, where no elevated accumulation of B, Mo, Se, P or S in either the straw or seeds of wheat was observed; canola increased accumulation of Mo and Se in its shoot with acidic fly ash, but it was well below phyto toxic levels. Simulations of wheat using APSIM at Richmond over a 100-year period (1909-2008) predicted yield increases in 52% of years with addition of ash at 3.0 Mg ha⁻¹ compared with 24% of years with addition of ash at 6.0 Mg ha⁻¹. The simulated yield increases did not exceed 40% over the control with addition of 6 Mg ha⁻¹ ash, but was between 40% and 50% with an addition rate of 3 Mg ha⁻¹. We found no evidence of phytotoxicity in either crop in this unusually dry year and there is still a need for further field assessment in years with favourable rainfall to enable development of clear recommendations on fly ash rates for optimum yield benefits. © 2012 Society of Chemical Industry.

Potassic zeolites from Brazilian coal ash for use as a fertilizer in agriculture.

PubMed

Flores, Camila Gomes; Schneider, Helena; Marcilio, Nilson Romeu; Ferret, Lizete; Oliveira, João Carlos Pinto

2017-12-01

Brazilian coal has an ash content ranging from 30 to 50% by weight. Consequently, its use in coal-fired thermoelectric for power production generates a lot of waste. The construction sector is the largest consumer of coal ash, but it cannot absorb the entire amount generated. Thus, other applications for coal ash should be studied in aim to optimize the use of this industrial waste. This research had as focus to synthesize potassic zeolite from of the coal ash into on potassium fertilizer for the grown wheat plant. In this work, it was used a subbituminous coal from Mina do Leão (RS, Brazil) presenting 48.7% ash content on a dry basis. Concerning the synthesis of potassic zeolite, it was adopted the conventional method of hydrothermal treatment with potassium hydroxide. A schedule of experiments was conducted in order to define the optimum condition of zeolite synthesis that was then used an alkaline solution of 5M KOH with a reaction time of 24h at 150°C. According to this procedure, it was obtained a zeolite with a single crystalline phase, identified through X-ray diffraction as Merlinoite. Subsequently, it was performed a set of tests using potassic zeolite asa fertilizer for plants in a greenhouse. The synthesized potassic zeolite showed a good potential for its use as fertilizer in agriculture. Copyright © 2017 Elsevier Ltd. All rights reserved.

Detoxification and generation of useful products from coal combustion wastes: Quarterly technical report, (October--December 1988)

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1988-01-01

This quarter, samples of dry fly ash, wet bottom ash, and desulfurization gypsum slurry were provided from an Ohio Edison power plant. Chemical analysis mineralogical examination, and an anion analysis were performed on the samples. 2 figs., 1 tab. (CBS)

Determination and prediction of digestible and metabolizable energy concentrations in byproduct feed ingredients fed to growing pigs

PubMed Central

Son, Ah Reum; Park, Chan Sol; Kim, Beob Gyun

2017-01-01

Objective An experiment was conducted to determine digestible energy (DE) and metabolizable energy (ME) of different byproduct feed ingredients fed to growing pigs, and to generate prediction equations for the DE and ME in feed ingredients. Methods Twelve barrows with an initial mean body weight of 31.8 kg were individually housed in metabolism crates that were equipped with a feeder and a nipple drinker. A 12×10 incomplete Latin square design was employed with 12 dietary treatments, 10 periods, and 12 animals. A basal diet was prepared to mainly contain the corn and soybean meal (SBM). Eleven additional diets were formulated to contain 30% of each test ingredient. All diets contained the same proportion of corn:SBM ratio at 4.14:1. The difference procedure was used to calculate the DE and ME in experimental ingredients. The in vitro dry matter disappearance for each test ingredient was determined. Results The DE and ME values in the SBM sources were greater (p<0.05) than those in other ingredients except high-protein distillers dried grains. However, DE and ME values in tapioca distillers dried grains (TDDG) were the lowest (p<0.05). The most suitable regression equations for the DE and ME concentrations (kcal/kg on the dry matter [DM] basis) in the test ingredients were: DE = 5,528–(156×ash)–(32.4×neutral detergent fiber [NDF]) with root mean square error = 232, R2 = 0.958, and p<0.001; ME = 5,243–(153 ash)–(30.7×NDF) with root mean square error = 277, R2 = 0.936, and p<0.001. All independent variables are in % on the DM basis. Conclusion The energy concentrations were greater in the SBM sources and were the least in the TDDG. The ash and NDF concentrations can be used to estimate the energy concentrations in the byproducts from oil-extraction and distillation processes. PMID:27857027

Effect of wear parameters on dry sliding behavior of Fly Ash/SiC particles reinforced AA 2024 hybrid composites

NASA Astrophysics Data System (ADS)

Bhaskar Kurapati, Vijaya; Kommineni, Ravindra

2017-09-01

In the present work AA 2024 alloy reinforced with mixtures of SiC and Fly Ash (FA) particles of 70 µm (5, 10 and 15 wt. %) are fabricated using the stir casting method. Both reinforcements are added in equal weight proportions. The wear test specimens are prepared from both the alloy and composite castings in the dimensions of Ф 4 mm and 30 mm lengths by the wire cut EDM process. The dry sliding wear properties of the prepared composites at room temperature are estimated by pin-on-disc wear testing equipment. The wear characteristics of the composites are studied by conducting the dry sliding wear test over loads of 0.5 Kgf, 1.0 Kgf, 1.5 Kgf, a track diameter of 60 mm and sliding times of 15 min, 30 min, 45min. The experimental results shows that the wear decreases with an increase in the weight percentage of FA and SiC particles in the matrix. Additionally wear increases with an increase in load and sliding time. Further, it is found that the wear resistance of the AA2024-Hybrid composites is higher than that of the AA2024 matrix.

Thermo-mechanical properties and microfabric of fly ash-stabilized gold tailings.

PubMed

Lee, Joon Kyu; Shang, Julie Q; Jeong, Sangseom

2014-07-15

This paper studies the changes in thermal conductivity, temperature, and unconfined compressive strength of gold tailings and fly ash mixtures during the curing period of 5 days. The microfabric of the cured mixtures was investigated with mercury intrusion porosimetry (MIP). The mixture samples were prepared at their maximum dry unit weight and optimum moisture content. Effect of adding fly ash to gold tailings (i.e., 0, 20, and 40% of the dry weight of tailings) was examined, and a comparison was made on samples prepared at the same fly ash content by replacing gold tailings with humic acid (i.e., gold tailings and humic acid ratios of 100:0, 90:10, and 80:20 by weight) or by varying pore fluid chemistry (i.e., water and salt solutions of 1M NaCl and CaCl2). The results show that the initial thermal conductivity of the samples is sensitive to the mixture proportion and a declination in the thermal conductivity is observed due to hydration of fly ash and evaporation. Inclusion of fly ash and salts into gold tailings improves the unconfined compressive strength but the presence of humic acid in samples leads to the decrease of the strength. MIP results reveal the pore structure changes associated with the packing states of the samples that reflect the influential factors considered. Copyright © 2014 Elsevier B.V. All rights reserved.

Utilization of open pit burned household waste ash--a feasibility study in Dhaka.

PubMed

Haque, Md Obaidul; Sharif, Ahmed

2014-05-01

Informal incineration or open pit burning of waste materials is a common practice in the peripheral area of Dhaka, one of the fastest growing mega-cities in the world. This study deals with the effect of open pit burned (i.e. open burned) household waste bottom ash on fired clay bricks. Between 0 to 50% (by weight) of open pit burned household waste bottom ash was mixed with clay to make bricks. The molded specimens were air-dried at room temperature for 24 h and then oven dried at 100 °C for another 24 h to remove the water. The raw bricks were fired in a muffle furnace to a designated temperature (800, 900 and 1000 °C, respectively). The firing behaviour (mechanical strength, water absorption and shrinkage) was determined. The microstructures, phase compositions and leachates were evaluated for bricks manufactured at different firing temperatures. These results demonstrate that open pit burned ash can be recycled in clay bricks. This study also presents physical observations of the incinerated ash particles and determination of the chemical compositions of the raw materials by wet analysis. Open pit burned ash can be introduced easily into bricks up to 20% wt. The concentrations of hazardous components in the leachates were below the standard threshold for inert waste category landfill and their environmental risk during their use-life step can be considered negligible.

Study on the effect of different concentration of Spirulina platensis paste added into dried noodle to its quality characteristics

NASA Astrophysics Data System (ADS)

Agustini, T. W.; Ma'ruf, W. F.; Widayat; Wibowo, B. A.; Hadiyanto

2017-02-01

High nutritional content of microalgae S. platensis is very good for human health especially for its protein and β-carotene. These compounds can be used for improving quality of food from nutritional point of view. This study was designed to observe the effect of different concentration of S. platensis paste to dried noodle quality based on physical, chemical and sensory perspectives. Material used in this study was S. platensis powder obtained from CV Neoalgae, Sukoharjo. The best treatment observed from preliminary study was then used for further study and compared to control treatment (without added S. platensis paste). The dried noodle resulted was then analyzed for elasticity, chemical (β-carotene, water, protein, ash, fat and carbohydrate) and sensory (hedonic). Parametric data obtained were analyzed using t-Test while non-parametric data was analyzed using Kruskal-Wallis followed by Multiple Comparison test. The study showed that dried noodle added with 9% S. platensis paste give significant effect (P<0.05) on elasticity; β-carotene, water, protein, ash, fat and carbohydrate and also sensory (hedonic). Dried noodle without added S. platensis paste has lower in β-carotene and protein compared to that of added S. platensis paste with the value of 0.06 mg/100 gr and 17.51 mg/100gr (β-carotene) and 8.88% and 38.6% (protein), respectively. Those, chemical composition of dried noodle added with S. platensis comply with Indonesian National Standard in term of protein, water, and ash content with sensory of 7.26 ≤ μ ≤ 7.63. Addition of S. platensis can significantly increase the nutritional of dried noodle especially protein (by 4 times) and β-carotene.

Potential use of fly ash to soil treatment in the Morava region

NASA Astrophysics Data System (ADS)

Bulíková, Lucia; Kresta, František; Rochovanský, Martin

2017-09-01

Soil treatment by binders is a standard technology and leads to optimal utilization of excavated soils in road constructions. Soil treatment is controlled in the Czech Republic by EN 14227-15 and Technical Requirement TP 94. Soil treatment using fly ash has not been performed in the Czech Republic, although there is a sufficient normative base. Fly ash produced by burning of hard coal in the Moravian region was tested as a potential binder. Fly ash samples were mixed with loess loams (CI). Tested siliceous fly ash of class F (ASTM C618) did not showed hydraulic properties but it showed positive effect on reducing maximum dry density of mixtures, increasing the IBI value (Immediate bearing index) and decreasing tendency to volume changes when the amount of fly ash was increased. The results of laboratory tests demonstrate the possibility of using fly ashes as a binder for soil treatment.

Measurement of technetium-99 in Marshall Islands soil samples by ICP-MS

PubMed

Tagami; Uchida; Hamilton; Robison

2000-07-01

Extraction techniques for recovery of technetium-99 (99Tc) for Inductively Coupled Plasma Mass Spectrometry (ICP-MS) measurements were evaluated using soil samples collected from the Marshall Islands. The results of three different extraction techniques were compared: (MI) acid leaching of Tc from ashed soil; (M2) acid leaching of Tc from raw dry soil; and (M3) Tc volatilization from ashed soil using a combustion apparatus. Total Tc recoveries varied considerably between the extraction techniques but each method yielded similar analytical results for 99Tc. Applications of these extraction techniques to a series of environmental samples and ICP-MS measurements have yielded first data on the 99Tc content of Marshall Islands soil samples contaminated with close-in radioactive fallout from nuclear weapons testing. The 99Tc activity concentration in the soil samples ranged between 0.1 and 1.1 mBq g(-1) dry weight (dw). The limit of detection for 99Tc by ICP-MS was 0.17 mBq per sample or 0.014 mBq g(-1) dw under standard operating conditions.

Biomass and Nutrient Distribution in 3-Year Old Green Ash and Swamp Chestnut Oak Grown in a Minor Stream Bottom

Treesearch

Harvey E. Kennedy; Bryce E. Schlaegel

1985-01-01

After three growing seasons, green ash had produced 7,342 pounds per acre of above-ground dry matter compared to 3,572 for oak. Of the total biomass, ash had 53% in the bole (wood plus bark), 22% in old branches, 21% in leaves and 4% in new growth; oak had 50%, 21%, 24%, and 5% in the same components. These proportions changed after leaf fall. Concentrations of N, P, K...

Proximate biochemical composition and caloric content calculated from elemental CHN analysis: a stoichiometric concept.

PubMed

Gnaiger, E; Bitterlich, G

1984-06-01

Carbohydrate, lipid, and protein compositions are stoichiometrically related to organic CHN (carbon, hydrogen, nitrogen) contents. Elemental CHN analyses of total biomass and ash, therefore, provide a basis for the calculation of proximate biochemical composition and bomb caloric value. The classical nitrogen to protein conversion factor (6.25) should be replaced by 5.8±0.13. A linear relation exists between the mass fraction of non-protein carbon and the carbohydrate and lipid content. Residual water in dry organic matter can be estimated with the additional information derived from hydrogen measurements.The stoichiometric CHN method and direct biochemical analysis agreed within 10% of ash-free dry biomass (for muscle, liver and fat tissue of silver carp; gut contents composed of detritus and algae; commercial fish food). The detrital material, however, had to be corrected for non-protein nitrogen.A linear relationship between bomb caloric value and organic carbon fractions was derived on the basis of thermodynamic and stoichiometric principles, in agreement with experimental data published for bacteria, algae, protozoa and invertebrates. The highly automatic stoichiometric CHN method for the separation of nutrient contents in biomass extends existing ecophysiological concepts for the construction of balanced carbon and nitrogen, as well as biochemical and energy budgets.

Distribution of heavy metals in vegetation surrounding the Blackstone River, USA: considerations regarding sediment contamination and long term metals transport in freshwater riverine ecosystems.

PubMed

Ozdilek, Hasan Goksel; Mathisen, Paul P; Pellegrino, Don

2007-04-01

The Blackstone River, a 74 km interstate stream located in South Central Massachusetts and Rhode Island (USA), has had a long history of problems due to high concentrations of metals such as copper and lead. The river has been subjected to metals load that include contributions from urban runoff, wastewater discharges, contaminated sediments, and also resuspension of contaminated sediments in the river-bed. All of these effects lead to elevated concentrations of metals such as lead, copper, zinc, chromium, cadmium and arsenic. Furthermore, the contaminated sediments located behind impoundments become especially important when higher flows cause resuspension of the previously deposited sediments and associated metals. While it is known that high metals concentrations in this river are found in the bottom sediments, the fate of the metals and impact on the ecosystem are not well known. This paper addresses the potential impacts that metals may have on vegetation and plant tissues in the vicinity of the river Plant tissues (primarily mosses), were collected from a number of sampling sites along a 14 km stretch of this river. At each site, samples were collected from multiple distances from the riverbank. Laboratory analyses made use of both wet digestion and dry ashing digestion methods, followed by analysis using an atomic absorption spectrophotometer. The wet and dry ashing digestion methods yielded similar results, although the results afforded by the dry ashing methods were slightly lower than the results obtained from the wet method. The results showed that the metals concentrations in vegetation (as determined from plant tissue analyses) were generally inversely related to the distance between the vegetation and the riverbank, with higher metals concentrations existing in plant tissues located close to the riverbank. In addition, it was found that the transport of metals concentrations to the terrestrial vegetation adjacent to this section of the Blackstone River was affected by the river morphology and flow characteristics (including velocity, flow rate and depth of flow, which can govern the potential for plant submergence, as well as the dynamics of flow and transport in the soil near the river). The analyses help to provide an improved understanding of metals transport and potential significance of metals contamination in a terrestrial ecosystem that is located adjacent to a river.

Characterization of Fly and Bottom Ashes Mixtures Treated using Sodium Lauryl Sulphate and Polyvinyl Alcohol

NASA Astrophysics Data System (ADS)

Robert, C. G.; Ayob, A.; Zaki, M. F. Muhammad; Razali, M. E.; Lew, E. V.; Hong, P. Y.

2018-03-01

Malaysia promotes coal as an option for solid fuel in electric power generation. Demanding of electricity needs, therefore, has led to increase the coal consumption and thus producing more coal waste products. The disposal of coal waste ashes has been a main concern to power generation station due to the need of disposal sites and operational costs. This study investigates the composition of fly ash (FA) and bottom ash (BA) mixtures with difference component percentage treated with sodium lauryl sulphate (SLS) and polyvinyl alcohol (PVA) at 1.5 and 2.5 wt% solutions and examined in terms of specific gravity, pH, maximum dry density properties, and its surface morphology. Although the chemical composition of the SLS and PVA treated fly and bottom ashes studied in this current work is not altered extensively, significant changes could be observed in its physicochemical properties. Chemically treated fly and bottom ashes mixtures with SLS and PVA at 1.5 wt% solution exhibited specific gravity of 1.97 to 2.92 and high pH values within range of 9.28 to 10.52. The mixture of BA:FA=0:1 ratio depicting high maximum dry density of 1.35 to 1.56 g/cm3 in both SLS and PVA solutions at 1.5 and 2.5 wt%. Scanning electron microscopy image shows distinct surface morphologies of SLS-treated fly and bottom ashes mixture that the particles are packed closely, strongly bonded similar to popcorn shape due to the effect of active silanol groups acted on coal ashes surface with the presence of Al-O/Si-O/other oxides. These findings suggest that higher level of chemical interaction between the fly and bottom ashes particles, significantly enhances pozzolanic reactions such as shear strength, plasticity, cementing properties, and thus other engineering properties.

Relationships between waste physicochemical properties, microbial activity and vegetation at coal ash and sludge disposal sites.

PubMed

Woch, Marcin W; Radwańska, Magdalena; Stanek, Małgorzata; Łopata, Barbara; Stefanowicz, Anna M

2018-06-11

The aim of the study was to assess the relationships between vegetation, physicochemical and microbial properties of substrate at coal ash and sludge disposal sites. The study was performed on 32 plots classified into 7 categories: dried ash sedimentation ponds, dominated by a grass Calamagrostis epigejos (AH-Ce), with the admixture of Pinus sylvestris (AH-CePs) or Robinia pseudoacacia (AH-CeRp), dry ash landfill dominated by Betula pendula and Pinus sylvestris (AD-BpPs) or Salix viminalis (AD-Sv) and coal sludge pond with drier parts dominated by Tussilago farfara (CS-Tf) and the wetter ones by Cyperus flavescens (CS-Cf). Ash sites were covered with soil layer imported as a part of technical reclamation. Ash had relatively high concentrations of some alkali and alkaline earth metals, Mn and pH, while coal sludge had high water and C, S, P and K contents. Concentrations of heavy metals were lower than allowable limits in all substrate types. Microbial biomass and, particularly, enzymatic activity in ash and sludge were generally low. The only exception were CS-Tf plots characterized by the highest microbial biomass, presumably due to large deposits of organic matter that became available for aerobic microbial biomass when water level fell. The properties of ash and sludge adversely affected microbial biomass and enzymatic activity as indicated by significant negative correlations between the content of alkali/alkaline earth metals, heavy metals, and macronutrients with enzymatic activity and/or microbial biomass, as well as positive correlations of these parameters with metabolic quotient (qCO 2 ). Plant species richness and cover were relatively high, which may be partly associated with alleviating influence of soil covering the ash. The effect of the admixture of R. pseudoacacia or P. sylvestris to stands dominated by C. epigejos was smaller than expected. The former species increased NNH 4 , NNO 3 and arylsulfatase activity, while the latter reduced activity of the enzyme. Copyright © 2018 Elsevier B.V. All rights reserved.

Comparative Physicochemical Evaluation of Kharekhasak (Tribulus terrestris Linn.) Before and After Mudabbar Process.

PubMed

Tauheed, Abdullah; Hamiduddin; Khanam, Salma; Ali, Mohd Akhtar; Zaigham, Mohammad

2017-01-01

Mudabbar/ Tadbeere advia is referred to the processes performed on the drugs to detoxify, purify, and enhance therapeutic action and to reduce its doses before making the formulations in Unani medicine. It improves quality of drugs either by optimizing its desirable characteristics or minimizing the undesirable ones; it makes drug effective, safe, and specific. There is a need of comparative evaluation to understand its significance. Tadbeer of Kharekhasak (KK) khurd ( Tribulus terrestris Linn. fruit) is described by Rabban Al-Tabari in Firdausul Hikmat, Akbar Arzani in Qarabadeene Qadri, etc., during the compounding of aphrodisiac formulations. Mudabbar Kharekhasak (MKK) used in Safoofe Kharekhasak mentioned in Al-Qarabadeene was evaluated in this work. Mudabbar/Tadbeer process was carried out by blending fresh KK. Juice with powdered dry KK and drying it under the sun. Juice used for process is thrice the weight of dry KK powder. The KK before and after the process was evaluated using physicochemical tests: powder characterization, extractive value, alcohol and water soluble matter, ash value, loss on drying (LOD) at 105°C, pH, high-performance thin layer chromatography (HPTLC) fingerprinting, and diosgenin content. Powder characterizations were set in. Increase in successive and nonsuccessive extractive values in various solvents, water/alcohol-soluble content, total ash, acid-insoluble ash, water-soluble ash, and sulfated ash of MKK was noted in comparison with KK. Decrease in LOD at 105°C and pH of MKK powder was observed. HPTLC fingerprinting data were developed for the identification and evaluation. Quantification of diosgenin content increased to 432.1 g/g in MKK as compared to 144.5 g/g in KK, suggesting significant increase in saponin content. Data obtained clearly indicated changes in MKK validating the classical Mudabbar process, probably to enhance/modify the action of drug. Standards for crude and MKK were established for future reference. Mudabbar process on Tribulus terrestris Linn (KK) havebeen validated.Physicochemical data for Mudabbar and non mudabbar Kharekhasak (KK) powder have been set in.Diosgenin content was increased significantly in mudabbar KK. Abbreviations Used: KK: Kharekhasak, TT: Tribulus terrestris , MKK: mudabbar Kharekhasak, SK: Safoofe Kharekhasak , LOD: loss of weight on drying, HPTLC: High performance thin layer chromatography, BSS: British standard sieve, μl: microliter, SEM: Standard error of mean, nm: nanometer, g: gram.

The Effect of Fly Ash on the Corrosion Behaviour of Galvanised Steel Rebarsin Concrete

NASA Astrophysics Data System (ADS)

Tittarelli, Francesca; Mobili, Alessandra; Bellezze, Tiziano

2017-08-01

The effect of fly ash on the corrosion behaviour of galvanised steel rebars in cracked concrete specimens exposed to wet-dry cycles in a chloride solution has been investigated. The obtained results show that the use of fly ash, replacing either cement or aggregate, always improves the corrosion behaviour of galvanised steel reinforcements. In particular, the addition of fly ash, even in the presence of concrete cracks, decreases the corrosion rate monitored in very porous concretes, as those with w/c = 0.80, to values comparable with those obtained in good quality concretes, as those with w/c = 0.45. Therefore, fly ash cancels the negative effect, at least from the corrosion point of view, of a great porosity of the cement matrix.

Experimental Study on Semi-Dry Flue Gas Desulfurization Ash Used in Steel Slag Composite Material

NASA Astrophysics Data System (ADS)

Lu, Lijun; Fang, Honghui

This article carried out the experimental study on using desulfurization ash in steel slag composite material. This was done by investigating the desulfurization ash content in formula one and formula two samples on the influence of setting time and strength of mortar. Through this study the following conclusions were reached for formula one: (1) a setting time of more than 10 hours is required, (2) a dosage of desulfurization ash of 1 2% is optimal, where flexural strength is reduced by 10% 23% and compressive strength reduced by 5.7% 16.4%. The conclusions of formula two were: (1) when the dosage of desulfurization ash is within 5%, the setting time is within 10 hours; (2) when the dosage of desulfurization ash is 1 2%, the flexural strength is increased by 5 7% and the compressive strength is reduced by 1 2%. The results show that the formula two is better.

Deashing macroalgae biomass by pulsed electric field treatment.

PubMed

Robin, Arthur; Sack, Martin; Israel, Alvaro; Frey, Wolfgang; Müller, Georg; Golberg, Alexander

2018-05-01

Among all biomass constituents, the ashes are major hurdles for biomass processing. Ashes currently have low market value and can make a non-negligible fraction of the biomass dry weight significantly impacting its further processing by degrading equipment, lowering process yield, inhibiting reactions and decreasing products qualities. However, most of the current treatments for deashing biomass are of poor efficiency or industrial relevance. This work is the first report on the use of Pulsed Electric Field (PEF) to enhance deashing of biomass from a high ash content green marine macroalga, Ulva sp., using hydraulic pressing. By inducing cell permeabilization of the fresh biomass, PEF was able to enhance the ash extraction from 18.4% (non-treated control) to 37.4% of the total ash content in average, significantly enhancing the extraction of five of the major ash elements (K, Mg, Na, P and S) compared to pressing alone. Copyright © 2018 Elsevier Ltd. All rights reserved.

Mineral content of the honey produced in Zulia state, Venezuela.

PubMed

Sulbarán de Ferrer, Betzabé; Ojeda de Rodríguez, Graciela; Peña, Jorge; Martínez, Janeth; Morán, María

2004-09-01

The mineral content of the honey produced in five zones of the Zulia state, Venezuela, during dry and rainy seasons was determined. The analyzed elements were: sodium, potassium (by emission spectroscopy), calcium, magnesium, copper, iron, manganese (by atomic absorption spectroscopy), phosphorus (phosphate ions, by colorimetric method), and ash content of raw honey samples directly collected from different beekeepers. The mean values for Na, K, Ca, Mg, Cu, Fe, Mn, and P were 353+84; 1774+138; 237+66; 52+24; 0.76+0.43; 13.5+10.23; 0.92+0.42 and 1642+323 mg/kg respectively. The mean ash content was 0.431+0.15%. Potassium was the most abundant of the elements determined. This results confirm that Zulian honey can be considered a good source of minerals.

The effect of nano-silica fertilizer concentration and rice hull ash doses on soybean (Glycine max (L.) Merrill) growth and yield

NASA Astrophysics Data System (ADS)

Suciaty, T.; Purnomo, D.; Sakya, A. T.; Supriyadi

2018-03-01

Agriculture is facing a number of challenges included limited water supply, low nutrient use efficiency, etc affected by climate change. Nano-silica is a product of nanotechnology, the frontier technologies to enhance crop productivity under climate change threats. The purpose of the research was to investigate the effects of nano silica concentration and rice hull ash on growth and yield of soybean. The experiment was conducted at Gagasari village, Cirebon, West Java from March until June 2017. The treatments were arranged by using factorial completely randomized block design with two factors. The first factor was a concentration of nano silica fertilizer consisted of four levels i.e., 0, 1.75, 2.5, and 3.75 ml.l‑1. The second factor was doses of rice hull ash consisted of four levels i.e., 0, 1, 2, and 3 ton.ha‑1. Each treatment combinations was repeated three times. The result showed that concentration of nano silica individually affected the number of leaves and number of branches, NAR and RGR, productive branches at 21, 30-45, and 35 daps, respectively. It also affected the seed dry weight plant‑1 and plot‑1. Meanwhile, doses of rice hull ash affected LAI, NAR, and RGR, 15-30, and 30-45 dap, respectively. Dry seed weight plot‑1 was also affected by doses of rice hull ash. There was an interaction effect between nano-silica concentration and doses of rice hull ash on number pods.plant‑1. Combinations of 2.5 ml.l‑1 nano-silica and 3 ton.ha‑1 of rice hull ash gave the highest number pods.plant‑1.

Novel incineration technology integrated with drying, pyrolysis, gasification, and combustion of MSW and ashes vitrification.

PubMed

Liu, Yangsheng; Liu, Yushan

2005-05-15

The conventional mass burn systems for municipal solid waste (MSW) emit large amount of acidic gases and dioxins as well as heavy metals due to the large excess air ratio. Additionally, the final process residues, bottom ash with potential leachability of heavy metals and fly ash with high level of heavy metals and dioxins, also constitute a major environmental problem. To deal with these issues more effectively, a novel MSW incineration technology was developed in this study. MSW drying, pyrolysis, gasification, incineration, and ash vitrification were achieved as a spectrum of combustion by the same equipment (primary chamber) in one step. In practice, the primary chamber of this technology actually acted as both gasifier for organic matter and vitrifying reactor for ashes, and the combustion process was mainly completed in the secondary chamber. Experiments were carried outto examine its characteristics in an industrial MSW incineration plant, located in Taiyuan, with a capability of 100 tons per day (TPD). Results showed that (1) the pyrolysis, gasification, and vitrification processes in the primary chamber presented good behaviors resulting in effluent gases with high contents of combustibles (e.g., CO and CH4) and bottom ash with a low loss-on-ignition (L.o.l), low leachability of heavy metals, and low toxicity of cyanide and fluoride. The vitrified bottom ash was benign to its environment and required no further processing for its potential applications. (2) Low stack emissions of dioxins (0.076 ng of TEQ m(-3)), heavy metals (ranging from 0.013 to 0.033 mg m(-3)), and other air pollutants were achieved. This new technology could effectively dispose Chinese MSW with a low calorific value and high water content; additionally, it also had a low capital and operating costs compared with the imported systems.

Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Q.S.; Chen, J.J.; Li, Y.C.

2008-02-15

Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months ofmore » plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.« less

An Evaluation of Coal Water Slurry Fuel Burners and Technology

DTIC Science & Technology

1992-11-01

treatment) processes, such as froth flotation , which reduce ash and pyritic sulphur content (4). Unlike pulverized coal, there is no need for expensive drying...physical beneficiation (froth flotation ) to reduce pyrite , biotechnological and other methods to remove more sulfur (especially the organic portion...of limited effectiveness since only some of the pyritic sulfur (about 40 to 60 percent of the total sulfur) is removed for some coals, since 90 to 95

The Effect of Alkaline Activator Ratio on the Compressive Strength of Fly Ash-Based Geopolymer Paste

NASA Astrophysics Data System (ADS)

Lăzărescu, A. V.; Szilagyi, H.; Baeră, C.; Ioani, A.

2017-06-01

Alkaline activation of fly ash is a particular procedure in which ash resulting from a power plant combined with a specific alkaline activator creates a solid material when dried at a certain temperature. In order to obtain desirable compressive strengths, the mix design of fly ash based geopolymer pastes should be explored comprehensively. To determine the preliminary compressive strength for fly ash based geopolymer paste using Romanian material source, various ratios of Na2SiO3 solution/ NaOH solution were produced, keeping the fly ash/alkaline activator ratio constant. All the mixes were then cured at 70 °C for 24 hours and tested at 2 and 7 days, respectively. The aim of this paper is to present the preliminary compressive strength results for producing fly ash based geopolymer paste using Romanian material sources, the effect of alkaline activators ratio on the compressive strength and studying the directions for future research.

Selenium in fly ash

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gutenmann, W.H.; Bache, C.A.; Youngs, W.D.

1976-03-05

Selenium, at concentrations exceeding 200 parts per million (ppM) (dry weight), has been found in white sweet clover voluntarily growing on beds of fly ash in central New York State. Guinea pigs fed such clover concentrated selenium in their tissues. The contents of the honey stomachs of bees foraging on this seleniferous clover contained negligible selenium. Mature vegetables cultured on 10 percent (by weight) fly ash-amended soil absorbed up to 1 ppM of selenium. Fly ashes from 21 states contained total selenium contents ranging from 1.2 to 16.5 ppM. Cabbage grown on soil containing 10 percent (by weight) of thesemore » fly ashes absorbed selenium (up to 3.7 ppM) in direct proportion (correlation coefficient r = .89) to the selenium concentration in the respective fly ash. Water, aquatic weeds, algae, dragonfly nymphs, polliwogs, and tissues of bullheads and muskrats from a fly ash-contaminated pond contained concentrations of selenium markedly elevated over those of controls.« less

Effect of different processing methods on antioxidant activity of underutilized legumes, Entada scandens seed kernel and Canavalia gladiata seeds.

PubMed

Sasipriya, Gopalakrishnan; Siddhuraju, Perumal

2012-08-01

The present study is proposed to determine the antioxidant activity of raw and processed samples of underutilized legumes, Entada scandens seed kernel and Canavalia gladiata seeds. The indigenous processing methods like dry heating, autoclaving and soaking followed by autoclaving in different solutions (plain water, ash, sugar and sodium bicarbonate) were adopted to seed samples. All other processing methods than dry heat showed significant reduction in phenolics (2.9-63%), tannins (26-100%) and flavonoids (14-67%). However, in processed samples of E. scandens, the hydroxyl radical scavenging activity and β-carotene bleaching inhibition activity were increased, whereas, 2,2-azinobis (3-ethyl benzothiazoline-6-sulfonic acid) diammonium salt (ABTS·(+)), ferric reducing antioxidant power (FRAP), metal chelating and superoxide anion scavenging activity were similar to unprocessed ones. In contrary, except dry heating in C. gladiata, all other processing methods significantly (P<0.05) reduced the 2,2'-diphenyl-1-picryl-hydrazyl (DPPH·) (20-35%), ABTS·(+) (22-75%), FRAP (34-74%), metal chelating (30-41%), superoxide anion radical scavenging (8-80%), hydroxyl radical scavenging (20-40%) and β-carotene bleaching inhibition activity (15-69%). In addition, the sample extracts of raw and dry heated samples protected DNA damage at 10 μg. All processing methods in E. scandens and dry heating in C. gladiata would be a suitable method for adopting in domestic or industrial processing. Copyright © 2012 Elsevier Ltd. All rights reserved.

Influence of Specific Surface of Lignite Fluidal Ashes on Rheological Properties of Sealing Slurries / Wpływ Powierzchni Właściwej Popiołów Fluidalnych z Węgla Brunatnego na Właściwości Reologiczne Zaczynów Uszczelniających

NASA Astrophysics Data System (ADS)

Stryczek, Stanisław; Wiśniowski, Rafał; Gonet, Andrzej; Złotkowski, Albert

2012-11-01

New generation fly ashes come from the combustion of coal in fluid-bed furnaces with simultaneous sulphur-removal from gases at ca. 850°C. Accordingly, all produced ashes basically differ in their physicochemical properties from the traditional silica ones. The aim of the laboratory analyses was determining the influence of specific surface and granular composition of fluidal ash on rheological properties of slurries used for sealing up the ground and rock mass media with hole injection methods, geoengineering works and cementing casing pipes in deep boreholes. Fluidal ash from the combustion of lignite contain active Puzzolan appearing in the form of dehydrated clayey minerals and active components activating the process of hydration ashes, i.e. CaO, anhydrite II and CaCO3. The ashes have a weak point, i.e. their high water diment, which the desired rheological properties related with the range of their propagation in the rock mass cannot not be acquired for injection works in the traditional sealing slurries technology. Increasing the water-to-mixture ratio should eliminate this feature of fluidal ashes. Laboratory analyses were performed for slurries based on metallurgical cement CEM III/A 32,5 having water-to-mixture ratios: 0.5; 0.6 ; 0.7 and 0.8; the fluidal ash concentration in the slurries was 30 wt.% (with respect to the mass of dry cement). Basing on the obtained results there were determined optimum recipes of sealing slurries in view of their rheological parameters which could be applied both in drilling technologies (cementing casing pipes, closing of boreholes, plugging) and in geoengineering works related with sealing up and reinforcing ground and rock mass media.

Computer-Controlled Microwave Drying of Potentially Difficult Organic and Inorganic Soils

DTIC Science & Technology

1990-12-01

materials, fly ash, gypsum rich soils, calcite rich soils, organic clay,, peat, and halloysite rich soils. Because specimen sizes too large to be...measurement Field monitoring equipment User’s manual 19. A3STRACT (Continued). materials, organic clay, fly ash, and calcite rich soils are demonstrated...39 Factors Influencing Dehydration ..................................... 42 PART X: STUDIES OF CALCITE

Influence of within year treatments and between year environmental differences on peach leaf ash and carbon isotopic discrimination responses

USDA-ARS?s Scientific Manuscript database

Plant ash content is related to water use efficiency (WUE) (dry matter accumulation per unit of transpiration) and Delta 13C in a range of C3 species. In breeding programs, the genetic x environment interaction is measured with multiple locations and multiple years of evaluation but the genetic x e...

Possibility of using waste tire rubber and fly ash with Portland cement as construction materials.

PubMed

Yilmaz, Arin; Degirmenci, Nurhayat

2009-05-01

The growing amount of waste rubber produced from used tires has resulted in an environmental problem. Recycling waste tires has been widely studied for the last 20 years in applications such as asphalt pavement, waterproofing systems and membrane liners. The aim of this study is to evaluate the feasibility of utilizing fly ash and rubber waste with Portland cement as a composite material for masonry applications. Class C fly ash and waste automobile tires in three different sizes were used with Portland cement. Compressive and flexural strength, dry unit weight and water absorption tests were performed on the composite specimens containing waste tire rubber. The compressive strength decreased by increasing the rubber content while increased by increasing the fly ash content for all curing periods. This trend is slightly influenced by particle size. For flexural strength, the specimens with waste tire rubber showed higher values than the control mix probably due to the effect of rubber fibers. The dry unit weight of all specimens decreased with increasing rubber content, which can be explained by the low specific gravity of rubber particles. Water absorption decreased slightly with the increase in rubber particles size. These composite materials containing 10% Portland cement, 70% and 60% fly ash and 20% and 30% tire rubber particles have sufficient strength for masonry applications.

Geochemistry of an abandoned landfill containing coal combustion waste: Implications for remediation

Treesearch

Christopher Barton; Linda Paddock; Christopher Romanek; John Seaman

2001-01-01

The 488-D Ash Basin (488-DAB) is an unlined, earthen landfill containing approximately one million tons of dry ash and coal reject material at the U.S. Department of Energy's Savannah River Site, SC. The pyritic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatened biota...

Metal attenuation processes in a landfill containing coal combustion waste: implications for remediation

Treesearch

Christopher Barton; Lindy Paddock; Christopher Romanek; Sally Maharaj; John Seaman

2005-01-01

The 488-D Ash Basin (488-DAB) is an unlined, earthen landfill containing approximately 1 million t of dry ash and coal reject material at the U.S. Department of Energy's Savannah River Site, South Carolina. The pyritic nature of the coal rejects has resulted in the formation of acidic drainage, which has contributed to groundwater deterioration and threatened...

Evaluation of concrete incorporating bottom ash as a natural aggregates replacement.

PubMed

Andrade, L B; Rocha, J C; Cheriaf, M

2007-01-01

A study on the incorporation of coal bottom ash from thermoelectric power stations as a substitute material for natural sand in the production of concrete is here presented. The normally coarse, fused, glassy texture of bottom ash makes it an ideal substitute for natural aggregates. The use of bottom ash in concrete presents several technical challenges: the physical and mineralogical characteristics of the bottom ash; the effect on water demand and the participation on cements hydratation. In the production of the concrete, substitutions in volume were used. Two different ways to employ bottom ash were used to make up the mix proportions: one considering the natural humidity present in the porous particles and the other not considering it, seeking to maintain the same strength. These considerations are fundamental given that the process of bottom ash extraction is carried out through moisture. Mechanical tests by compressive strength were performed and the elastic modulus was determined. An analysis of the influence of bottom ash in the formation of pores was carried out through tests for the water loss by air drying and water uptake by capillary absorption. The results show that the higher the bottom ash contents in the concrete, the worse the performance regarding moisture transport. However, for one bottom ash concrete type, the mechanical properties were maintained.

Nutrient content of young cassava leaves and assessment of their acceptance as a green vegetable in Nigeria.

PubMed

Awoyinka, A F; Abegunde, V O; Adewusi, S R

1995-01-01

Cassava (Manihot esculenta Crantz) leaves contained a high level of crude protein (29.3-32.4% dry weight) compared to a conventional vegetable, Amaranthus (19.6%). Ash was 4.6-6.4% in cassava leaf samples but 13.1% dry weight in Amaranthus. Dietary fibre was very high in all samples (26.9-39% dry weight) while HCN-potential was low (5.1-12.6 mg/100 g dry weight). Tannin was the highest in IITA red cassava leaves (29.7 mg/g) and the lowest in Amaranthus vegetable. In vitro digestibility was very low in oven dried samples (15.6-22.7%). Blanching increased protein content (except Amaranthus) and in vitro protein digestibility but decreased ash, minerals, dietary fibre and tannin, while HCN-potential was unchanged. Grinding reduced both HCN-potential and tannin by 84 and 71% respectively while oven drying only reduced the HCN content marginally. Preference studies showed that the highest percentage of respondents (25.3%) preferred Amaranthus vegetable, followed by Celosia (17.5%), Talinum (12.4%), garden egg (11.5%), with cassava leaves as the least (0.5%). Organoleptic evaluation rated cassava leaf soup inferior to Amaranthus in terms of appearance, colour and texture but equal in terms of taste and flavour and overall acceptability.

Proximate composition, total phenolic content, and antioxidant activity of seagrape (Caulerpa lentillifera).

PubMed

Nguyen, Van Tang; Ueng, Jinn-Pyng; Tsai, Guo-Jane

2011-09-01

The proximate composition of seagrape (Caulerpa lentillifera) from culture ponds in Penghu, Taiwan was analyzed. The phenolic content and the antioxidant activities including the 1,1-diphenyl-2-picryl-hydrazil (DPPH) radical scavenging activity, ferric ion-reducing activity, hydrogen peroxide scavenging activity, and ferrous ion chelating (FIC) activity of the ethanolic extracts of dry seagrape samples using 2 drying methods of freeze drying and thermal drying were compared with the ethanolic extract of Oolong tea as a reference. The contents (dry weight basis) of carbohydrate, crude protein, crude lipid, crude fiber, and ash of seagrape obtained from culture ponds in Taiwan were 64.00%, 9.26%, 1.57%, 2.97%, and 22.20%, respectively. The total phenolic content (1.30 mg gallic acid equivalent [GAE]/g dry weight) of the ethanolic extract of thermally dried seagrape was significantly lower (P < 0.05) than that (2.04 mg GAE/g dry weight) of freeze-dried seagrape, and both were significantly lower than that (13.58 mg GAE/g dry weight) of Oolong tea. At the same phenolic content, the antioxidant activities of freeze-dried seagrape were significantly higher (P < 0.05) than those of thermally dried seagrape. Compared with Oolong tea, seagrape, irrespective of drying method used, generally had strong hydrogen peroxide scavenging activity; but it was weak in DPPH radical scavenging activity, ferric ion-reducing activity, and FIC activity. The antioxidant activity of seagrape and Oolong tea was significantly influenced by their phenolic contents. The proximate composition, total phenolic content, and antioxidant activity of seagrape (Caulerpa lentillifera) in Taiwan were determined in this research to indicate nutritionally of this edible seaweed to human health, and compared these results to previous studies. © 2011 Institute of Food Technologists®

An evaluation of benthic macroinvertebrate biomass methodology : Part 1. Laboratory analytical methods.

PubMed

Mason, W T; Lewis, P A; Weber, C I

1983-03-01

Evaluation of analytical methods employed for wet weight (live or preserved samples) of benthic macroinvertebrates reveals that centrifugation at 140 x gravity for one minute yields constant biomass estimates. Less relative centrifugal force increases chance of incomplete removal of body moisture and results in weighing error, while greater force may rupture fragile macroinvertebrates, such as mayflies. Duration of specimen exposure in ethanol, formalin, and formol (formaling-ethanol combinations) causes significant body weight loss with within 48 hr formalin and formol cause less body weight loss than ethanol. However, as all preservatives tested cause body weight loss, preservation time of samples collected for comparative purposes should be treated uniformly. Dry weight estimates of macroinvertebrates are not significantly affected by kind of preservative or duration of exposure. Constant dry weights are attained by oven drying at 103 °C at a minimum of four hours or vacuum oven drying (15 inches of mercury pressure) at 103 °C for a minimum of one hour. Although requiring more time in preparation than oven drying and inalterably changing specimen body shape, freeze drying (10 microns pressure, -55 °C, 24 hr) provides constant dry weights and is advantageous for long term sample storage by minimizing curatorial attention. Constant ash-free dry weights of macroinvertebrate samples are attained by igniting samples at 500-550 °C for a minimum of one hour with slow cooling to room temperature in desiccators before weighing.

Leaching kinetics of As, Mo, and Se from acidic coal fly ash samples

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neupane, Ghanashyam; Donahoe, Rona J.; Bhattacharyya, Siddhartha

Annually, coal-fired electric power plants produce large volumes potentially hazardous coal combustion products (CCPs) including fly ash. Since majority of the coal fly ash and other CCPs deposited in dry land fills or wet lagoons, they pose risk of contamination to local environment and hydrogeology. In this study, we present results of leaching kinetics for As, Mo, and Se from three acidic fly ash samples. This study shows that the leachate concentrations of As, Mo, and Se increase over time. Three kinetics equations, pseudo-second order, Elovich, and power-function, are able to adequately describe the experimental leaching kinetics data. Experimental leachingmore » data and modeling results indicate that the rate limiting leaching of As, Mo, and Se is largely controlled by the dissolution of the fly ash particles. Furthermore, it is important to adopt effective containment/treatment schemes to avoid potential and persistent dispersion of trace elements from ash disposal facilities to surrounding environment for a long time.« less

Leaching kinetics of As, Mo, and Se from acidic coal fly ash samples

DOE PAGES

Neupane, Ghanashyam; Donahoe, Rona J.; Bhattacharyya, Siddhartha; ...

2017-07-03

Annually, coal-fired electric power plants produce large volumes potentially hazardous coal combustion products (CCPs) including fly ash. Since majority of the coal fly ash and other CCPs deposited in dry land fills or wet lagoons, they pose risk of contamination to local environment and hydrogeology. In this study, we present results of leaching kinetics for As, Mo, and Se from three acidic fly ash samples. This study shows that the leachate concentrations of As, Mo, and Se increase over time. Three kinetics equations, pseudo-second order, Elovich, and power-function, are able to adequately describe the experimental leaching kinetics data. Experimental leachingmore » data and modeling results indicate that the rate limiting leaching of As, Mo, and Se is largely controlled by the dissolution of the fly ash particles. Furthermore, it is important to adopt effective containment/treatment schemes to avoid potential and persistent dispersion of trace elements from ash disposal facilities to surrounding environment for a long time.« less

Effect of processing on the biochemical contents of Acanthus montanus (Nees) T. Anderson (Acanthaceae) leaves.

PubMed

Igwe, Andrew; Eleazu, Chinedum

2018-03-01

The effect of processing on the biochemical contents of Acanthus montanus leaves was investigated. The moisture, crude protein, lipid, fiber, ash, and total carbohydrate contents of the raw vegetable were 59.15, 1.85, 2.32, 3.76, 2.04, and 34.65 g/100 g, respectively. The saponin, alkaloid, tannin, flavonoid, phenol, and anthocyanin contents of the raw vegetable were 5.35, 4.04, 1.10, 3.53, 2.87, and 1.27 g/100 g, respectively, while it contained 2.65 mg/100 g calcium, 1.14 mg/100 g magnesium, 7.66 mg/100 g potassium, 350.75 μg/g vitamin A, 50.87 mg/100 g vitamin C, and 0.25% titratable acidity. There were significant reductions ( p  < .05) in the protein, lipid, fiber, ash, saponin, alkaloid, tannin, phenol, anthocyanin, calcium, magnesium, potassium, vitamin A, vitamin C, and titratable acidity of the boiled or boiled + sun-dried A. montanus leaves; significant elevation of the moisture contents but significant reduction of the total carbohydrate contents of the boiled; and significant reduction of the moisture contents of the boiled + sun-dried vegetable compared with the raw. There were significant increases ( p  < .05) in the total carbohydrate contents of the boiled + sun-dried leaves; significant reductions ( p  < .05) in the moisture, saponin, alkaloid, and vitamins A and C contents of the sun-dried vegetable; and no significant differences ( p  > .05) in the lipid, calcium, potassium, and ash, but significant increases ( p  < .05) in the protein, crude fiber, total carbohydrates, tannins, flavonoids, phenols, anthocyanin, magnesium, and titratable acidity of the sun-dried vegetable when compared with the raw. Sun drying alone either retained or enhanced the release of some important bioactive compounds in A. montanus leaves. Furthermore, the reduced moisture content of the sun-dried vegetable together with its increased titratable acidity will make the sun-dried vegetable uninhabitable for microorganisms, thereby increasing its shelf life.

21 CFR 573.750 - Pichia pastoris dried yeast.

Code of Federal Regulations, 2010 CFR

2010-04-01

... the following percent-by-weight specifications: (1) Crude protein, not less than 60 percent. (2) Crude fat, not less than 2 percent. (3) Crude fiber, not more than 2 percent. (4) Ash, not more than 13... pastoris dried yeast may be used in feed formulations of broiler chickens as a source of protein not to...

21 CFR 573.750 - Pichia pastoris dried yeast.

Code of Federal Regulations, 2011 CFR

2011-04-01

... the following percent-by-weight specifications: (1) Crude protein, not less than 60 percent. (2) Crude fat, not less than 2 percent. (3) Crude fiber, not more than 2 percent. (4) Ash, not more than 13... pastoris dried yeast may be used in feed formulations of broiler chickens as a source of protein not to...

21 CFR 573.750 - Pichia pastoris dried yeast.

Code of Federal Regulations, 2012 CFR

2012-04-01

... the following percent-by-weight specifications: (1) Crude protein, not less than 60 percent. (2) Crude fat, not less than 2 percent. (3) Crude fiber, not more than 2 percent. (4) Ash, not more than 13... pastoris dried yeast may be used in feed formulations of broiler chickens as a source of protein not to...

21 CFR 573.750 - Pichia pastoris dried yeast.

Code of Federal Regulations, 2014 CFR

2014-04-01

... the following percent-by-weight specifications: (1) Crude protein, not less than 60 percent. (2) Crude fat, not less than 2 percent. (3) Crude fiber, not more than 2 percent. (4) Ash, not more than 13... pastoris dried yeast may be used in feed formulations of broiler chickens as a source of protein not to...

21 CFR 573.750 - Pichia pastoris dried yeast.

Code of Federal Regulations, 2013 CFR

2013-04-01

... the following percent-by-weight specifications: (1) Crude protein, not less than 60 percent. (2) Crude fat, not less than 2 percent. (3) Crude fiber, not more than 2 percent. (4) Ash, not more than 13... pastoris dried yeast may be used in feed formulations of broiler chickens as a source of protein not to...

Ambient airborne solids concentrations including volcanic ash at Hanford, Washington sampling sites subsequent to the Mount St. Helens eruption

NASA Technical Reports Server (NTRS)

Sehmel, G. A.

1982-01-01

Airborne solids concentrations were measured on a near daily basis at two Hanford, Washington sites after the eruption of Mount St. Helens on May 18, 1980. These sites are about 211 km east of Mount St. Helens. Collected airborne solids included resuspended volcanic ash plus normal ambient solids. Average airborne solids concentrations were greater at the Hanford meteorological station sampling site which is 24 km northwest of the Horn Rapids dam sampling site. These increased concentrations reflect the sampling site proximity to greater ash fallout depths. Both sites are in low ash fallout areas although the Hanford meteorological station site is closer to the greater ash fallout areas. Airborne solids concentrations were decreased by rain, but airborne solids concentrations rapidly increased as surfaces dried. Airborne concentrations tended to become nearly the same at both sampling sites only for July 12 and 13.

Effect of Drying Temperature on the Chemical Properties and Diffusivity of belimbi (averrhoa belimbi)

NASA Astrophysics Data System (ADS)

Shahari, N.; Jamil, N.; Rasmani, K. A.; Nursabrina

2015-09-01

In recent years, many dried fruit products have been developed in response to a strong demand by the customer. This type of fruit has a different composition and hence different moisture diffusivity (D). During drying, Fick's Law of diffusion, which describes the movement of liquid water was used to calculate this diffusivity. However diffusivity has strong effects on the material drying characteristics and these must be determined. In this paper, Fick's Law of diffusion with different kinds of boundary conditions was solve using separation of variable (SOV). In order to get the value of D, results obtained using SOV will be compared with the results from the drying of belimbi at temperature of 40°C, 50°C and 60°C. Although the results show that variation in the values of diffusivity for different temperatures is relatively small, but the variation in the total time required for drying is significantly bigger: between 3-7 hours. Its shown that diffusivity is an important measurement and should be considered in the modeling of the drying process. The chemical properties of belimbi slices in terms of vitamin C, total ash and antioxidant activity with different air temperatures and pretreatment were also investigated. Higher drying temperatures gives less drying time, a lower vitamin C and antioxidant activity but a greater total of ash, whilst pre-treatment can increased vitamin C and antioxidant activity. The results show that pre-treatment and the drying temperature are important variables to improve mass and heat transfer, as well as the belimbi chemical properties.

Changes of the soil environment affected by fly ash dumping site of the electric power plant

NASA Astrophysics Data System (ADS)

Weber, Jerzy; Gwizdz, Marta; Jamroz, Elzbieta; Debicka, Magdalena; Kocowicz, Andrzej

2014-05-01

In this study the effect of fly ash dumping site of the electric power plant on the surrounding soil environment was investigated. The fly ash dumping site collect wastes form brown coal combustion of Belchatow electric power station, central Poland. The dumping site is surrounding by forest, where pine trees overgrow Podzols derived from loose quartz sands. The soil profiles under study were located at a distance of 50, 100, 400 and 500 m from the dumping site, while control profiles were located 8 km away from the landfill. In all horizons of soil profiles the mpain hysico-chemical and chemical properties were determined. The humic substances were extracted from ectohumus horizons by Shnitzer's method, purified using XAD resin and freeze-dried. The fulvic acids were passed through a cation exchange column and freeze-dried. Optical density, elemental composition and atomic ratios were determined in the humic and fulvic acids. Organic carbon by KMnO4 oxidation was also determined in the organic soil horizons. The fly ash from the landfill characterized by high salinity and strong alkaline reaction (pH=10), which contributed significantly to the changes of the pH values in soils horizons. The alkalization of soils adjacent to the landfill was found, which manifested in increasing of pH values in the upper soil horizons. The impact of the landfill was also noted in the changes of the soil morphology of Podzols analysed. As a result of the alkalization, Bhs horizons have been converted into a Bs horizons. Leaching of low molecular humus fraction - typical for podzolization - has been minimized as a result of pH changes caused by the impact of the landfill, and originally occurring humic substances in the Bhs horizon (present in the control profiles) have been probably transported out of the soil profile and then into the groundwater.

Recovery of Trace and Heavy Metals from Coal Combustion Residues for Reuse and Safe Disposal: A Review

NASA Astrophysics Data System (ADS)

Kumar, Ashvani; Samadder, Sukha Ranjan; Elumalai, Suresh Pandian

2016-09-01

The safe disposal of coal combustion residues (CCRs) will remain a major public issue as long as coal is used as a fuel for energy production. Both dry and wet disposal methods of CCRs create serious environmental problems. The dry disposal method creates air pollution initially, and the wet disposal method creates water pollution as a result of the presence of trace and heavy metals. These leached heavy metals from fly ash may become more hazardous when they form toxic compounds such as arsenic sulfite (As2S3) and lead nitrate (N2O6Pb). The available studies on trace and heavy metals present in CCRs cannot ensure environmentally safe utilization. In this work, a novel approach has been offered for the retrieval of trace and heavy metals from CCRs. If the proposed method becomes successful, then the recovered trace and heavy metals may become a resource and environmentally safe use of CCRs may be possible.

Gas generation at a municipal waste combustor ash monofill -- Franklin, New Hampshire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Musselman, C.N.; Straub, W.A.; Bidwell, J.N.

1997-12-31

The characterization of landfill gas generated at municipal solid waste landfills has received significant attention in recent years. Generation of landfill gas at municipal waste combustor ash monofills is generally assumed to be negligible and there is little, if any, published information available concerning the characteristics of gas generated at ash monofills. The lined residue landfill in Franklin, New Hampshire, USA has been accepting combined ash (bottom ash, fly ash, scrubber product from direct dry lime injection) from a 500 ton per day mass burn waste to energy facility in Concord, NH from 1989 through the present. In March, 1996,more » landfill operators noticed gaseous emissions from cleanout lines connected to the landfill`s primary leachate collection system beneath the landfilled residue. The landfill staff tested these emissions with a hand-held LEL meter, which tripped alarms for low O{sub 2} and explosiveness. Subsequently, a comprehensive program was completed to sample and analyze the gaseous emissions. Temperatures within the landfill mass were unexpectedly found to be as high as 156 F, higher than typical in an MSW landfill, presumably due to exothermic chemical reactions within the residue. Methane concentrations were found to be very low, and oxygen was present, although at depressed concentrations. Methanogenic bacterial activity does not appear to play a major role in gas generation in a residue landfill. Hydrogen gas was measured at significant concentrations. The hydrogen gas is postulated to be generated by reactions of elemental aluminum within the landfilled residue. These hydrogen generating aluminum reactions may be accelerated at elevated pH levels resulting from the presence of dry lime scrubber product. Volatile organic compounds were present in concentrations at the low end of concentrations generally reported for MSW landfills.« less

Application of microwave digestion to the analysis of peat

USGS Publications Warehouse

Papp, C.S.E.; Fischer, L.B.

1987-01-01

A microwave digestion technique for the dissolution of peat is described and compared with a dry ashing method and a nitric - perchloric - hydrofluoric acid wet digestion. Peat samples with different organic matter contents were used and Ca, Mg, Fe, AI, Na, K, Mn, Zn, Cu and Li were determined by atomic absoprtion spectrometry. The results obtained using the three dissolution techniques were in good agreement. The microwave method has the advantage of digesting the samples in less than 2 h and uses less acid than the conventional wet digestion method. Keeping the volume of the acid mixture as small as possible minimises contamination and leads to lower blank values.

To fractionate municipal solid waste incineration bottom ash: Key for utilisation?

PubMed

Sormunen, Laura Annika; Rantsi, Riina

2015-11-01

For the past decade, the Finnish waste sector has increasingly moved from the landfilling of municipal solid waste towards waste incineration. New challenges are faced with the growing amounts of municipal solid waste incineration bottom ash, which are mainly landfilled at the moment. Since this is not a sustainable or a profitable solution, finding different utilisation applications for the municipal solid waste incineration bottom ash is crucial. This study reports a comprehensive analysis of bottom ash properties from one waste incineration plant in Finland, which was first treated with a Dutch bottom ash recovery technique called advanced dry recovery. This novel process separates non-ferrous and ferrous metals from bottom ash, generating mineral fractions of different grain sizes (0-2 mm, 2-5 mm, 5-12 mm and 12-50 mm). The main aim of the study was to assess, whether the advanced bottom ash treatment technique, producing mineral fractions of different grain sizes and therefore properties, facilitates the utilisation of municipal solid waste incineration bottom ash in Finland. The results were encouraging; the bottom ash mineral fractions have favourable behaviour against the frost action, which is especially useful in the Finnish conditions. In addition, the leaching of most hazardous substances did not restrict the utilisation of bottom ash, especially for the larger fractions (>5 mm). Overall, this study has shown that the advanced bottom ash recovering technique can be one solution to increase the utilisation of bottom ash and furthermore decrease its landfilling in Finland. © The Author(s) 2015.

Potential of phosphorus recovery from sewage sludge and manure ash by thermochemical treatment.

PubMed

Havukainen, Jouni; Nguyen, Mai Thanh; Hermann, Ludwig; Horttanainen, Mika; Mikkilä, Mirja; Deviatkin, Ivan; Linnanen, Lassi

2016-03-01

All life forms require phosphorus (P), which has no substitute in food production. The risk of phosphorus loss from soil and limited P rock reserves has led to the development of recycling P from industrial residues. This study investigates the potential of phosphorus recovery from sewage sludge and manure ash by thermochemical treatment (ASH DEC) in Finland. An ASH DEC plant could receive 46-76 kt/a of sewage sludge ash to produce 51-85 kt/a of a P-rich product with a P2O5 content of 13-18%, while 320-750 kt/a of manure ash could be supplied to produce 350-830 kt/a of a P-rich product with a P content of 4-5%. The P2O5 potential in the total P-rich product from the ASH DEC process using sewage sludge and manure ash is estimated to be 25-47 kt/a, which is significantly more than the P fertilizer demand in Finland's agricultural industries. The energy efficiency of integrated incineration and the ASH DEC process is more dependent on the total solid content and the subsequent need for mechanical dewatering and thermal drying than on the energy required by the ASH DEC process. According to the results of this study, the treated sewage sludge and manure ash using the ASH DEC process represent significant potential phosphorus sources for P fertilizer production. Copyright © 2016 Elsevier Ltd. All rights reserved.

Impact of animal density on cattle nutrition in dry Mediterranean rangelands: a faecal near-IR spectroscopy-aided study.

PubMed

Landau, S Y; Dvash, L; Yehuda, Y; Muklada, H; Peleg, G; Henkin, Z; Voet, H; Ungar, E D

2018-02-01

In the context of determining the sustainable carrying capacity of dry-Mediterranean herbaceous rangelands, we examined the effect of animal density on cattle nutrition, which is fundamental to animal performance and welfare. The effects on dietary components of low (0.56 cows/ha; L) and high (1.11 cows/ha; H) animal densities were monitored for three consecutive years in grazing beef cows. In the dry season (summer and early autumn), cows had free access to N-rich poultry litter (PL) given as a dietary supplement. In each season, near-IR spectroscopy (NIRS) was used to predict the chemical composition of herbage samples (ash, NDF, CP, in vitro dry matter digestibility (IVDMD) and metabolizable energy (ME) content from IVDMD). Near-IR spectroscopy was applied also to faecal samples to determine the chemical composition of the diet selected by the animal, as well as the contents of ash, NDF and CP in the faeces themselves. A faecal-NIRS equation was applied to estimate the dietary proportion of PL. Seasonal categories were green, dry without PL supplementation and dry with it. We found no effects of animal density on nutrition during the green season but effects were apparent when cows consumed dry pasture. Ash content predicted by faecal NIRS was higher in the diet than in plant samples clipped from pasture, which infers that cows ingested soil. Dietary and faecal ash contents were higher (P<0.05) at the H, implying greater soil intake in these animals. During the dry period, dietary contents of ME were higher in L than in H (P<0.05). Poultry litter supplementation was associated with a marked increase (P<0.01) in dietary and faecal CP contents. Poultry litter represented 0.45 and 0.59 of the diet in treatments L and H, respectively (P<0.05). Consequently, treatment H had higher faecal protein (P<0.05). A tendency of higher dietary protein (P=0.08) and lower dietary NDF (P=0.10) in treatment H was probably related to greater PL ingestion. Given that high and sustained rates of poultry litter consumption are detrimental to animal health, the above results cast doubts on the long-term sustainability of the higher of the animal densities tested. Although it may be sustainable vis-à-vis the vegetation, treatment H may have exceeded the boundaries of what is acceptable for cow health. Chemical information revealed with NIRS can be used to evaluate whether animal densities are compatible with animal health and welfare standards and can play a role in determining the carrying capacity of Mediterranean rangelands.

Evaluation of techniques for sampling volatile arsenic on volcanoes

NASA Astrophysics Data System (ADS)

Arndt, Julia; Ilgen, Gunter; Planer-Friedrich, Britta

2017-02-01

Volatile arsenic (As) species, like arsine, mono-, di-, and trimethylarsine (AsH3, MeAsH2, Me2AsH, Me3As) are reported to be released from volcanoes but their determination is difficult because of low concentrations, low boiling points, and high reactivity, especially in the presence of volcanic gases like H2S and SO2. We tested needle trap devices (NTDs), cryotrapping, and Tedlar® bags for quantitative and species-preserving sampling. NTDs did not trap AsH3, MeAsH2, Me2AsH, did not release sorbed Me3As quantitatively, and lead to artifact formation of dimethylchloroarsine, which also questions the reliability of previous reports from solid phase micro extraction fibers using the same sorption materials. Cryotrapping in dry ice was insufficient to trap AsH3 and MeAsH2; Me2AsH and Me3As were only partially retained. Sampling in Tedlar® bags remained the best alternative. Stability of all four arsines was confirmed for dark storage at 5 °C for 19 days in a matrix of dry N2, 11 days in 20% O2, and 19 days in 3800 ppmv CO2 (> 80% recovery for all species), while in the presence of H2S, Me3As recovery was only 67% and in the presence of SO2, Me2AsH and Me3As recovery was 40 and 11%, respectively. Removing interfering reactive gases by a NaOH trap, we sampled natural volcanic emissions at fumaroles of Vulcano and Solfatara (Italy). Detected total arsine concentrations of 0.5-77 ng·m- 3 were 1-2 orders of magnitude higher than the calculated background. Inorganic arsine was the dominant species suggesting that secondary microbially catalyzed methylation is a process of minor importance in the fumarolic gases.

The role of sample preparation in interpretation of trace element concentration variability in moss bioindication studies

USGS Publications Warehouse

Migaszewski, Z.M.; Lamothe, P.J.; Crock, J.G.; Galuszka, A.; Dolegowska, S.

2011-01-01

Trace element concentrations in plant bioindicators are often determined to assess the quality of the environment. Instrumental methods used for trace element determination require digestion of samples. There are different methods of sample preparation for trace element analysis, and the selection of the best method should be fitted for the purpose of a study. Our hypothesis is that the method of sample preparation is important for interpretation of the results. Here we compare the results of 36 element determinations performed by ICP-MS on ashed and on acid-digested (HNO3, H2O2) samples of two moss species (Hylocomium splendens and Pleurozium schreberi) collected in Alaska and in south-central Poland. We found that dry ashing of the moss samples prior to analysis resulted in considerably lower detection limits of all the elements examined. We also show that this sample preparation technique facilitated the determination of interregional and interspecies differences in the chemistry of trace elements. Compared to the Polish mosses, the Alaskan mosses displayed more positive correlations of the major rock-forming elements with ash content, reflecting those elements' geogenic origin. Of the two moss species, P. schreberi from both Alaska and Poland was also highlighted by a larger number of positive element pair correlations. The cluster analysis suggests that the more uniform element distribution pattern of the Polish mosses primarily reflects regional air pollution sources. Our study has shown that the method of sample preparation is an important factor in statistical interpretation of the results of trace element determinations. ?? 2010 Springer-Verlag.

The composition of pigeon peas (Cajanus cajan (L.) Millsp.) grown in Botswana.

PubMed

Amarteifio, J O; Munthali, D C; Karikari, S K; Morake, T K

2002-01-01

This study investigated the composition of pigeon peas (Cajanus cajan), grown at Sebele, Botswana. The raw seeds of six varieties were analyzed for dry matter, crude fat, protein, fiber, and ash, using Association of Official Analytical Chemists procedures. Major minerals, Ca, K, P, Mg, Na and trace minerals, Cu, Fe and Zn were also assessed. The range of nutrient contents obtained were: dry matter 86.6-88.0%, crude protein 19.0-21.7%, crude fat 1.2-1.3%, crude fiber 9.8-13.0%, and ash 3.9-4.3%. Minerals ranges (mg/100 g dry matter) were: K 1845-1941, P 163-293, Ca 120-167, Mg 113-127, Na 11.3-12.0, Zn 7.2-8.2, Fe 2.5-4.7 and Cu 1.6-1.8. There were no significant differences in Na among the six varieties (p > 0.05). For the other components, varietal differences (p < 0.05) were observed. The values obtained for the dry matter, crude protein, fat, ash, Ca, Cu, Fe, and Mg were similar to those in pigeon peas grown elsewhere, while those for crude fiber and Zn were higher. In general, the composition of pigeon peas compared favorably with those of other legumes such as Bambara groundnut (Vigna subterranea). The levels of crude protein, crude fiber, K, Ca, P and Mg indicated that pigeon peas could be valuable in the diet of the people of Botswana. This crop would positively contribute protein in the diet and the diversification of agricultural produce.

Modeling the formation of the quench product in municipal solid waste incineration (MSWI) bottom ash.

PubMed

Inkaew, Kanawut; Saffarzadeh, Amirhomayoun; Shimaoka, Takayuki

2016-06-01

This study investigated changes in bottom ash morphology and mineralogy under lab-scale quenching conditions. The main purpose was to clarify the mechanisms behind the formation of the quench product/layer around bottom ash particles. In the experiments, the unquenched bottom ashes were heated to 300°C for 1h, and were quenched by warm water (65°C) with different simulated conditions. After having filtered and dried, the ashes were analyzed by a combination of methodologies namely, particle size distribution analysis, intact particle and thin-section observation, X-ray diffractometry, and scanning electron microscope with energy dispersive X-ray spectroscopy. The results indicated that after quenching, the morphology and mineralogy of the bottom ash changed significantly. The freshly quenched bottom ash was dominated by a quench product that was characterized by amorphous and microcrystalline calcium-silicate-hydrate (CSH) phases. This product also enclosed tiny minerals, glasses, ceramics, metals, and organic materials. The dominant mineral phases produced by quenching process and detected by XRD were calcite, Friedel's salt, hydrocalumite and portlandite. The formation of quench product was controlled by the fine fraction of the bottom ash (particle size <0.425mm). From the observations, a conceptual model of the ash-water reactions and formation of the quench product in the bottom ash was proposed. Copyright © 2016 Elsevier Ltd. All rights reserved.

Investigation on the fly ash thermal treatment on the performance of Lithium Ferriphosphate (LiFePO{sub 4}) battery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Febiolita, Bella; Khoirunnissak, Dewi; Purwanto, Agus, E-mail: aguspurw@gmail.com

Addition of the fly ash can be used to improve the capacity of LiFePO{sub 4} battery. Fly ash was added in Acethylene Black (AB) as 2% of the total weight of Acetylene Black (AB). The effects of temperature variation and fly ash characteristics were analyzed. Fly ash was prepared by heating at 50, 100, 150, and 250°C in muffle furnace for 5 hours and passed in 200 mesh screen prior to mixing it with other compounds. Lithium Ferriphospat (LiFePO{sub 4}), fly ash, Acethylene Black (AB), Polyvinylidene Fluoride (PVDF) as a binder and N-methyl-2-pyrrolidone (NMP) as a solvent were mixed tomore » be slurry. The slurry were coated, dried and hot pressed to make a cathode film. The performance of battery lithium was examined by eight channel battery analyzer. The composition of the fly ash was examined by X-ray fluorescence spectrometry (XRF) and Fourier Tansform Infrared Spectroscopy (FTIR). The excellent performance was shown in the fly ash addition which were treated by heating at 150°C. The capacity of fly ash added LiFePO{sub 4} battery is 94.373 mAh/g, which is higher than that of without fly ash addition, i.e. 67.998 mAh/g.« less

Method of introducing additive into a reaction gas flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Michelfelder, S.; Chughtai, M.Y.

1984-04-03

A method of continuously introducing additive, which is conveyed by gaseous and/or liquid carriers, into a turbulent reaction gas flow in the combustion chamber of a steam generator having dry ash withdrawal for selective removal, in a dry manner, of environmentally harmful gaseous noxious materials, such as sulfur, chlorine, and chlorine compounds, which are contained in a hot reaction gas flow which results after a complete or incomplete flame combustion of solid, liquid, or gaseous fuels. Depending upon the additive introduced, heat is stored and/or used for decomposition reactions. The additive, is first introduced at one or more input locations,more » due to locally different pressure conditions in the combustion chamber, into one or more recirculation flows which are within the system and are closed. The additive is subsequently withdrawn from these recirculation flows and is introduced into the reaction gas flow.« less

Ash reduction strategies in corn stover facilitated by anatomical and size fractionation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lacey, Jeffrey A.; Emerson, Rachel M.; Thompson, David N.

There is growing interest internationally to produce fuels from renewable biomass resources. Inorganic components of biomass feedstocks, referred to collectively as ash, damage equipment and decrease yields in thermal conversion processes, and decrease feedstock value for biochemical conversion processes. Decreasing the ash content of feedstocks improves conversion efficiency and lowers process costs. Because physiological ash is unevenly distributed in the plant, mechanical processes can be used to separate fractions of the plant based on ash content. This study focuses on the ash separation that can be achieved by separating corn stover by particle size and anatomical fraction. Baled corn stovermore » was hand-separated into anatomical fractions, ground to <19.1 mm, and size separated using six sieves ranging from 9.5 to 0.150 mm. Size fractions were analyzed for total ash content and ash composition. Particle size distributions observed for the anatomical fractions varied considerably. Cob particles were primarily 2.0 mm or greater, while most of the sheath and husk particles were 2.0 mm and smaller. Particles of leaves greater than 0.6 mm contained the greatest amount of total ash, ranging from approximately 8 to 13% dry weight of the total original material, while the fractions with particles smaller than 0.6 mm contained less than 2% of the total ash of the original material. As a result, based on the overall ash content and the elemental ash, specific anatomical and size fractions can be separated to optimize the feedstocks being delivered to biofuels conversion processes and minimize the need for more expensive ash reduction treatments.« less

Ash reduction strategies in corn stover facilitated by anatomical and size fractionation

DOE PAGES

Lacey, Jeffrey A.; Emerson, Rachel M.; Thompson, David N.; ...

2016-04-22

There is growing interest internationally to produce fuels from renewable biomass resources. Inorganic components of biomass feedstocks, referred to collectively as ash, damage equipment and decrease yields in thermal conversion processes, and decrease feedstock value for biochemical conversion processes. Decreasing the ash content of feedstocks improves conversion efficiency and lowers process costs. Because physiological ash is unevenly distributed in the plant, mechanical processes can be used to separate fractions of the plant based on ash content. This study focuses on the ash separation that can be achieved by separating corn stover by particle size and anatomical fraction. Baled corn stovermore » was hand-separated into anatomical fractions, ground to <19.1 mm, and size separated using six sieves ranging from 9.5 to 0.150 mm. Size fractions were analyzed for total ash content and ash composition. Particle size distributions observed for the anatomical fractions varied considerably. Cob particles were primarily 2.0 mm or greater, while most of the sheath and husk particles were 2.0 mm and smaller. Particles of leaves greater than 0.6 mm contained the greatest amount of total ash, ranging from approximately 8 to 13% dry weight of the total original material, while the fractions with particles smaller than 0.6 mm contained less than 2% of the total ash of the original material. As a result, based on the overall ash content and the elemental ash, specific anatomical and size fractions can be separated to optimize the feedstocks being delivered to biofuels conversion processes and minimize the need for more expensive ash reduction treatments.« less

Assessment of the exposure of islanders to ash from the Soufriere Hills volcano, Montserrat, British West Indies

PubMed Central

Searl, A; Nicholl, A; Baxter, P

2002-01-01

Background and Aims: The Soufriere Hills volcano, Montserrat, has been erupting since July 1995 and volcanic ash has fallen on the island throughout most of the eruption. The ash contains substantial quantities of respirable particles and unusually large amounts (15–20%) of the crystalline silica mineral, cristobalite. The purpose of the surveys described here, undertaken between December 1996 and April 2000, was to determine levels of personal exposure of islanders to volcanic ash and cristobalite in order to inform advice on the associated risks to health and the measures required to reduce exposure. Methods: Surveys of personal exposure to respirable dust and cristobalite were undertaken using cyclone samplers. In addition, direct reading instruments (DUSTTRAK) were used to monitor ambient air concentrations of PM10 at fixed sites and also to provide information about exposures to airborne particles associated with selected activities. Results: Environmental concentrations of airborne ash have been greatest in the areas where the most ash has been deposited and during dry weather. Individual exposure to airborne ash was related to occupation, with the highest exposures among gardeners, cleaners, roadworkers, and police at roadside checkpoints. During 1997 many of these individuals were exposed to concentrations of cristobalite that exceeded the ACGIH recommended occupational exposure limit. Since the population became confined to the north of the island in October 1997, even those in relatively dusty occupations have received exposures to cristobalite well below this limit. Conclusions: Most of the 4500 people who have remained on island since the eruption began have not been exposed to sufficiently high concentrations of airborne dust for long enough to be at risk of developing silicosis. However, more than a dozen individuals continued to experience frequent high occupational exposures to volcanic ash, some of whom may have had sufficient exposure to crystalline silica to be at risk of developing mild silicosis. If volcanic activity were to deposit further ash over the occupied areas of the island during the coming years, the risks of silicosis will become more substantial. PMID:12151608

Hydrothermal liquefaction of harvested high-ash low-lipid algal biomass from Dianchi Lake: effects of operational parameters and relations of products.

PubMed

Tian, Chunyan; Liu, Zhidan; Zhang, Yuanhui; Li, Baoming; Cao, Wei; Lu, Haifeng; Duan, Na; Zhang, Li; Zhang, Tingting

2015-05-01

Hydrothermal liquefaction (HTL) allows a direct conversion of algal biomass into biocrude oil, not only solving the environmental issues caused by the over-growing algae but also producing renewable energy. This study reports HTL of algae after separation from eutrophicated Dianchi Lake in China. Conversion efficiency was studied under different operational conditions via an orthogonal design, including holding temperature (HT) (260-340 °C), retention time (RT) (30-90 min) and total solid (TS) (10-20%). A highest biocrude oil yield (18.4%, dry ash-free basis, daf) was achieved at 300 °C, 60 min, and 20% (TS), due to the low contents of lipids (1.9%, daf) and proteins (24.8%, daf), and high contents of ash (41.6%, dry basis) and carbohydrates (71.8%, daf). Operational parameters significantly affected the biocrude yields, and chemical distribution of HTL products. The biocrude production also related to other HTL products, and involved chemical reactions, such as deoxygenation and/or denitrogenation. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of processing methods on the nutritional content of three traditional vegetables leaves: Amaranth, black nightshade and jute mallow.

PubMed

Traoré, Korotimi; Parkouda, Charles; Savadogo, Aly; Ba/Hama, Fatoumata; Kamga, Regine; Traoré, Yves

2017-11-01

The study assessed changes in nutritional content of some commonly consumed traditional vegetables subjected to postharvest processes. Amaranth ( Amaranthus cruentus L.), black nightshade ( Solanum scabrum Mill.) and jute mallow ( Corchorus olitorius L.) leaves used as vegetables were subjected to blanching, boiling and drying. The proximate composition and β-carotene content of fresh and processed leaves were determined. Amaranth, black nightshade and jute mallow leaves had 25.21%, 39.74% and 29.18% of protein, respectively. The β-carotene levels were 16.40, 25.25 and 27.74 mg/100 g for black nightshade amaranth and jute mallow leaves, respectively. The ash content was 10.57% for black nightshade, 12.40% for jute mallow and 16.33% for amaranth. Processing methods caused decreases of β-carotene and crude lipid content. Boiling for 30 min or more resulted in large loss of β-carotene. Drying under shade resulted in less loss of β-carotene than drying in cabinet at 50 and 60°C.

33 CFR 159.131 - Safety: Incinerating device.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) POLLUTION MARINE SANITATION DEVICES Design, Construction, and Testing § 159.131 Safety.... Unitized incineration devices must completely burn to a dry, inert ash, a simultaneous defecation and...

Separation and characterization of magnetic fractions from waste-to-energy bottom ash with an emphasis on the leachability of heavy metals.

PubMed

Wei, Yunmei; Mei, Xiaoxia; Shi, Dezhi; Liu, Guotao; Li, Li; Shimaoka, Takayuki

2017-06-01

Magnetic fractions were extracted from pulverized waste-to-energy (WTE) bottom ashes using a combined wet-dry extraction method. The resulting magnetic and non-magnetic fractions were subjected to compositional, mineralogical, and redox state analyses by X-ray diffraction (XRD), X-ray fluorescence, and X-ray photoelectron spectroscopy (XPS), respectively. The distribution and leaching toxicity of heavy metals were assessed to evaluate potential effects on the environment. Compositional analyses revealed that Fe accounted for 35% of the magnetic fraction of pulverized ashes, which was approximately seven times that of the raw ash. In addition to Fe, elemental Ni, Mn, and Cr were also significantly enriched in the magnetic fractions. The mineralogical analysis determined that Fe was primarily present as hematite and magnetite, and metallic iron was also identified in the magnetic fraction samples. The XPS analysis further proved the existence of zero-valence Fe. However, a significant amount of Fe remained in the non-magnetic fractions, which could partially be ascribed to the intergrowth structure of the various minerals. The elevated concentrations of toxicity characteristic leaching procedure (TCLP)-extracted Mn, Ni, Cr, Cu, Pb, and Zn were primarily ascribed to the lower buffering capability of the magnetic fractions, with the enrichment of Mn, Ni, and Cr in the magnetic fractions also contributing to this elevation.

Characterization of fly ash from low-sulfur and high-sulfur coal sources: Partitioning of carbon and trace elements with particle size

USGS Publications Warehouse

Hower, J.C.; Trimble, A.S.; Eble, C.F.; Palmer, C.A.; Kolker, A.

1999-01-01

Fly ash samples were collected in November and December of 1994, from generating units at a Kentucky power station using high- and low-sulfur feed coals. The samples are part of a two-year study of the coal and coal combustion byproducts from the power station. The ashes were wet screened at 100, 200, 325, and 500 mesh (150, 75, 42, and 25 ??m, respectively). The size fractions were then dried, weighed, split for petrographic and chemical analysis, and analyzed for ash yield and carbon content. The low-sulfur "heavy side" and "light side" ashes each have a similar size distribution in the November samples. In contrast, the December fly ashes showed the trend observed in later months, the light-side ash being finer (over 20 % more ash in the -500 mesh [-25 ??m] fraction) than the heavy-side ash. Carbon tended to be concentrated in the coarse fractions in the December samples. The dominance of the -325 mesh (-42 ??m) fractions in the overall size analysis implies, though, that carbon in the fine sizes may be an important consideration in the utilization of the fly ash. Element partitioning follows several patterns. Volatile elements, such as Zn and As, are enriched in the finer sizes, particularly in fly ashes collected at cooler, light-side electrostatic precipitator (ESP) temperatures. The latter trend is a function of precipitation at the cooler-ESP temperatures and of increasing concentration with the increased surface area of the finest fraction. Mercury concentrations are higher in high-carbon fly ashes, suggesting Hg adsorption on the fly ash carbon. Ni and Cr are associated, in part, with the spinel minerals in the fly ash. Copyright ?? 1999 Taylor & Francis.

Characterizations of Deposited Ash During Co-Firing of White Pine and Lignite in Fluidized Bed Combustor

NASA Astrophysics Data System (ADS)

Shao, Yuanyuan; Zhu, Jesse; Preto, Fernando; Tourigny, Guy; Wang, Jinsheng; Badour, Chadi; Li, Hanning; Xu, Chunbao Charles

Characterizations of ash deposits from co-firing/co-combusting of a woody biomass (i.e., white pine) and lignite coal were investigated in a fluidized-bed combustor using a custom designed air-cooled probe installed in the freeboard region of the reactor. Ash deposition behaviors on a heat transfer surface were comprehensively investigated and discussed under different conditions including fuel type, fuel blending ratios (20-80% biomass on a thermal basis), and moisture contents. For the combustion of 100% lignite, the compositions of the deposited ash were very similar to those of the fuel ash, while in the combustion of 100% white pine pellets or sawdust the deposited ash contained a much lower contents of CaO, SO3, K2O and P2O5 compared with the fuel ash, but the deposited ash was enriched with SiO2, Al2O3 and MgO. A small addition of white pine (20% on a heat input basis) to the coal led to the highest ash deposition rates likely due to the strong interaction of the CaO and MgO (from the biomass ash) with the alumina and silica (from the lignite ash) during the co-combustion process, evidenced by the detection of high concentrations of calcium/magnesium sulfates, aluminates and silicates in the ash deposits. Interestingly, co-firing of white pine pellets and lignite at a 50% blending ratio led to the lowest ash deposition rates. Ash deposition rates in combustion of fuels as received with a higher moisture content was found to be much lower than those of oven-dried fuels.

Heavy metals in MSW incineration fly ashes

NASA Astrophysics Data System (ADS)

Ferreira, C.; Ribeiro, A.; Ottosen, L.

2003-05-01

Incineration is a common solution for dealing with the increasing amount of municipal solid waste (MSW). During the process, the heavy metals initially present in the waste go through several transformations, ending up in combustion products, such as fly ash. This article deals with some issues related to the combustion of MSW and the formation of fly ash, especially in what concerns heavy metals. Treatment of the flue gas in air pollution control equipment plays an important role and the basic processes to accomplish this are explained. Fly ash from a semi-dry flue gas treatment system is characterized regarding its physical-chemical properties: pH, solubility, chemical composition, and leaching, amongst others. Results indicate a high alkalinity and the presence of large amounts of calcium, chlorides, sulfates, carbonates, sodium and potassium. Metal concentrations in fly ash are: 6,2g/kg for zinc, 2,4g/kg for lead, 1,7g/kg for iron, and 7,9g/kg for magnesium. Copper, manganese, chromium and cadmium are also present with 546, 338, 104 and 91mg/kg of fly ash, respectively. These results are extremely important in subsequent studies on the treatment of fly ash.

Influence of lactation and pregnancy + lactation on mechanical properties and mineral content of the rat femur.

PubMed

Peng, T C; Kusy, R P; Garner, S C; Hirsch, P F; De Blanco, M C

1987-06-01

The quality of bone was assessed from femurs of rats both during lactation and after pregnancy + lactation. Mechanical properties of stiffness, strength, toughness, and ductility were measured, along with standard measurements of dry weight, ash weight, and total bone mineral. No changes occurred during the first week of lactation. During the second and third weeks of lactation all bone parameters except ductility decreased significantly. These data are consistent with bone losing mineral in order to supplement the dietary calcium intake necessary for milk production. In other experiments, femurs were collected from nulliparous rats and from rats that had previously undergone 1-3 pregnancy + lactations. The largest changes in bone mineral and mechanical properties occurred after a single pregnancy + lactation period, although significant further decreases in stiffness and strength occurred after the second pregnancy + lactation. No additional losses occurred following the third pregnancy + lactation. Even 5 months after only one pregnancy + lactation period, the bone quality was still impaired as all bone properties were lower than in nulliparous controls. Because the changes, especially stiffness and strength, were relatively larger than the changes in dry and ash weights of bone, measurements of these mechanical properties provide a more sensitive method to evaluate the quality of bone.

Ultrafiltration of thin stillage from conventional and e-mill dry grind processes.

PubMed

Arora, Amit; Dien, Bruce S; Belyea, Ronald L; Wang, Ping; Singh, Vijay; Tumbleson, M E; Rausch, Kent D

2011-05-01

We used ultrafiltration (UF) to evaluate membrane filtration characteristics of thin stillage and determine solids and nutrient compositions of filtered streams. To obtain thin stillage, corn was fermented using laboratory methods. UF experiments were conducted in batch mode under constant temperature and flow rate conditions. Two regenerated cellulose membranes (10 and 100 kDa molecular weight cutoffs) were evaluated with the objective of retaining solids as well as maximizing permeate flux. Optimum pressures for 10 and 100 kDa membranes were 207 and 69 kPa, respectively. Total solids, ash, and neutral detergent fiber contents of input TS streams of dry grind and E-Mill processes were similar; however, fat and protein contents were different (p < 0.05). Retentate obtained from conventional thin stillage fractionation had higher mean total solids contents (27.6% to 27.8%) compared to E-Mill (22.2% to 23.4%). Total solids in retentate streams were found similar to those from commercial evaporators used in industry (25% to 35% total solids). Fat contents of retentate streams ranged from 16.3% to 17.5% for the conventional process. A 2% increment in fat concentration was observed in the E-Mill retentate stream. Thin stillage ash content was reduced 60% in retentate streams.

Investigations of ash fouling with cattle wastes as reburn fuel in a small-scale boiler burner under transient conditions.

PubMed

Oh, Hyukjin; Annamalai, Kalyan; Sweeten, John M

2008-04-01

Fouling behavior under reburn conditions was investigated with cattle wastes (termed as feedlot biomass [FB]) and coal as reburn fuels under a transient condition and short-time operation. A small-scale (30 kW or 100,000 Btu/hr) boiler burner research facility was used for the reburn experiments. The fuels considered for these experiments were natural gas (NG) for the ashless case, pure coal, pure FB, and blends of coal and FB. Two parameters that were used to characterize the ash "fouling" were (1) the overall heat-transfer coefficient (OHTC) when burning NG and solid fuels as reburn fuels, and (2) the combustible loss through ash deposited on the surfaces of heat exchanger tubes and the bottom ash in the ash port. A new methodology is presented for determining ash-fouling behavior under transient conditions. Results on the OHTCs for solid reburn fuels are compared with the OHTCs for NG. It was found that the growth of the layer of ash depositions over longer periods typically lowers OHTC, and the increased concentration of ash in gas phase promotes radiation in high-temperature zones during initial periods while decreasing the heat transfer in low-temperature zones. The ash analyses indicated that the bottom ash in the ash port contained a smaller percentage of combustibles with a higher FB percentage in the fuels, indicating better performance compared with coal because small particles in FB burn faster and the FB has higher volatile matter on a dry ash-free basis promoting more burn out.

Characteristics of civil aviation atmospheric hazards

NASA Technical Reports Server (NTRS)

Marshall, Robert E.; Montoya, J.; Richards, Mark A.; Galliano, J.

1994-01-01

Clear air turbulence, wake vortices, dry hail, and volcanic ash are hazards to civil aviation that have not been brought to the forefront of public attention by a catastrophic accident. However, these four hazards are responsible for major and minor injuries, emotional trauma, significant aircraft damage, and in route and terminal area inefficiency. Most injuries occur during clear air turbulence. There is significant aircraft damage for any volcanic ash encounter. Rolls induced by wake vortices occur near the ground. Dry hail often appears as an area of weak echo on the weather radar. This paper will present the meteorological, electromagnetic, and spatiotemporal characteristics of each hazard. A description of a typical aircraft encounter with each hazard will be given. Analyzed microwave and millimeter wave sensor systems to detect each hazard will be presented.

Discovering the desirable alleles contributing to the lignocellulosic biomass traits in saccharum germplasm collections for energy cane improvement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Todd, James; Comstock, Jack C.

Phenotyping Methods: The accessions (which includes 21 taxa and 1,177 accessions) in the World Collection of Sugarcane and Related Grasses (WCSRG) was evaluated for the following traits: arenchyma, internode length and diameter, pubescence, pith, Brix, stalk number and fiber. A core of 300 accessions that included each species in the World Collection was selected by using the Maximization Strategy in MStrat software. Results: The core had a higher diversity rating than random selections of 300 accessions. The Shannon–Weaver Diversity Index scores of the core and whole collection were similar indicating that the majority of the diversity was captured by themore » core collection. The ranges and medians between the core and WCSRG were similar; only two of the trait medians were not significant at P = 0.05 using the non-parametric Wilcoxon method and the coincidence rate (CR % = 96.2) was high (>80) indicating that extreme values were retained. Thus, the phenotypic diversity of these traits in the WCSRG was well represented by the core collection. Associations Methods: Genotypic and phenotypic data were collected for 1002 accessions of the WCSRG including 209 SSR markers. Association analysis was performed using both General Linear (GLM) and Maximum Likelihood (MLM) models. Different core collections with 300 accessions each were selected based on genotypic, phenotypic and combined data based on the Maximization Strategy in MStrat software. Results: A major portion of the genotyping involving SNPs is being conducted by Dr. Jianping Wang of the University of Florida under the DOE award DE-FG 02-11ER 65214 and the genotypic and phenotypic associations will be reported separately next year. In the current, study forty one and seventeen markers were found to be associated with traits using the GLM and MLM methods respectively including associations with arenchyma, internode length and diameter, pubescence, pith, and Sugar Cane Yellow Leaf Virus. The data indicates that each of the cores and the World Collection are similar to each other genotypically and phenotypically, but the core that was selected using only genotypic data was significantly different phenotypically. This indicates that there is not enough association between the genotypic and phenotypic diversity as to select using only genotypic diversity and get the full phenotypic diversity. Core Collection: Creation and Phenotyping Methods: To evaluate this germplasm for breeding purposes, a representative diversity panel selected from the WCSRG of approximately 300 accessions was planted at Canal Point, FL in three replications. These accessions were measured for stalk height and stalk number multiple times throughout the growing season and Brix and fresh biomass during harvest in 2013 and, stalk height, stalk number, stalk diameter, internode length, Brix and fresh and dry biomass was determined in the ratoon crop harvest in 2014. Results: In correlations of multiple measurements, there were higher correlations for early measurements of stalk number and stalk height with harvest traits like Brix and fresh weight. Hybrids had higher fresh mass and Brix while Saccharum spontaneum had higher stalk number and dry mass. The heritability of hybrid mass traits was lower in the ratoon crop. According to the principal component analysis, the diversity panel was divided into two groups. One group had accessions with high stalk number and high dry biomass like S. spontaneum and the other groups contained accessions with higher Brix and fresh biomass like S. officinarum. Mass traits correlated with each other as expected but hybrids had lower correlations between fresh and dry mass. Stalk number and the mass traits correlated with each other except in S. spontaneum and hybrids in the first ratoon. There were 110 accessions not significantly different in Brix from the commercial sugarcane checks including 10 S. spontaneum accessions. There were 27 dry and 6 fresh mass accessions significantly higher than the commercial sugarcane checks. Core Collection: Fiber analysis Methods: A biomass sample was taken from each accession then shredded and dried. Fiber analysis was then performed on each sample. The acetyl groups, acid insoluble lignin, acid soluble lignin, arabinan, glucan, holocellulose, total lignin, structural ash, and xylan were quantified on a % fiber basis and nonstructural ash on a % total basis. Results: There were significant, but not large differences between species for holocellulose, lignin, acetyl, acid soluble lignin, nonstructural ash, and glucan. For each trait, S. spontaneum had significantly more holocellulose, glucan, lignin, and nonstructural ash and less acetyl and acid soluble lignin than the other species. In all populations, glucan and was positively correlated with holocellulose were positively correlated and glucan and and holocellulose were negatively correlated with lignin. In hybrids, internode length correlated positively with holocellulose and nonstructural ash and negatively with lignin. The heritability estimates for each of the fiber component traits is low indicating that environment is an important factor in fiber composition. Principal component analysis indicated that a large amount of diversity exists within each of the species.« less

Distinguishing styles of explosive eruptions at Erebus, Redoubt and Taupo volcanoes using multivariate analysis of ash morphometrics

NASA Astrophysics Data System (ADS)

Avery, Meredith R.; Panter, Kurt S.; Gorsevski, Pece V.

2017-02-01

The style and dynamics of volcanic eruptions control the level and type of hazards posed for local populations and can have a temporary long-range impact on climate if eruptions are extremely energetic. The purpose of this study is to provide a statistical approach to ash morphometrics in order to provide a means by which to evaluate diverse eruption styles and mechanisms of fragmentation. The methodology presented can be applied to tephra deposits worldwide and may aid volcanic hazard mitigation by better defining a volcano's history of explosive behavior. Ash-sized grains were collected from tephra deposits on Mount Erebus, Antarctica (< 10 ka, phonolitic unit SC4), Mount Redoubt, Alaska (2009, andesitic events 2-4 & 9-18), and the Taupo volcano, New Zealand (1.8 ka, rhyolitic unit 3D). Coarse ash from each deposit was carefully hand-sieved to 1 mm diameter and display diverse morphologies that vary from grains that are moderately vesicular and more rectangular (blocky) to highly vesiculated (spongy) grains that vary from angular to sub-rounded. A total of 264 grains were imaged by scanning electron microscopy. Morphometric properties were determined using image processing software and then evaluated by several statistical methods. Discriminant analysis of all parameters was found to be the best at differentiating the tephra deposits and allowing for interpretation of eruptive styles in conjunction with field observations. A linear array of data forming a positive slope in factor space, which explains > 99% of the total data variance, is interpreted to represent a continuum between fragmentations involving water-magma interaction ("wet") to grains that were formed predominately by magmatic ("dry") fragmentation mechanisms. The Taupo Hatepe ash, which was deposited from a phreatoplinian eruption column, has the highest factor values in the array, which signifies, in part, more rectangular/blocky morphologies with smooth grain edges. Factor values for the 2009 Redoubt eruption (events 2-4) are nearly as high as Hatepe ash and based on this we suggest that it was produced, in part, by phreatomagmatic fragmentation. This is supported by field observations that document melting and eruption through glacial ice during the early phases of the 2009 activity. Redoubt ash grains from later stages of the same eruption (events 9-18) show a significant shift to lower values in factor space (more irregular/vesiculated grains) and are interpreted to be a consequence of 'dryer' conditions. Coarse ash data from Mount Erebus are completely separated from Taupo and Redoubt grains in factor space due primarily to the difference in mean gray value, which is a proxy for vesicle density and size. The vesicle characteristics (larger and deeper) are consistent with documented strombolian-style activity and the scatter in grain shape data support fragmentation by a mixture of wet and dry processes as has previously been proposed based on deposit characteristics and resemblance to tephra produced by current activity.

Size matters: relationships between body size and body mass of common coastal, aquatic invertebrates in the Baltic Sea

PubMed Central

Austin, Åsa; Bergström, Ulf; Donadi, Serena; Eriksson, Britas D.H.K.; Hansen, Joakim; Sundblad, Göran

2017-01-01

Background Organism biomass is one of the most important variables in ecological studies, making biomass estimations one of the most common laboratory tasks. Biomass of small macroinvertebrates is usually estimated as dry mass or ash-free dry mass (hereafter ‘DM’ vs. ‘AFDM’) per sample; a laborious and time consuming process, that often can be speeded up using easily measured and reliable proxy variables like body size or wet (fresh) mass. Another common way of estimating AFDM (one of the most accurate but also time-consuming estimates of biologically active tissue mass) is the use of AFDM/DM ratios as conversion factors. So far, however, these ratios typically ignore the possibility that the relative mass of biologically active vs. non-active support tissue (e.g., protective exoskeleton or shell)—and therefore, also AFDM/DM ratios—may change with body size, as previously shown for taxa like spiders, vertebrates and trees. Methods We collected aquatic, epibenthic macroinvertebrates (>1 mm) in 32 shallow bays along a 360 km stretch of the Swedish coast along the Baltic Sea; one of the largest brackish water bodies on Earth. We then estimated statistical relationships between the body size (length or height in mm), body dry mass and ash-free dry mass for 14 of the most common taxa; five gastropods, three bivalves, three crustaceans and three insect larvae. Finally, we statistically estimated the potential influence of body size on the AFDM/DM ratio per taxon. Results For most taxa, non-linear regression models describing the power relationship between body size and (i) DM and (ii) AFDM fit the data well (as indicated by low SE and high R2). Moreover, for more than half of the taxa studied (including the vast majority of the shelled molluscs), body size had a negative influence on organism AFDM/DM ratios. Discussion The good fit of the modelled power relationships suggests that the constants reported here can be used to quickly estimate organism dry- and ash-free dry mass based on body size, thereby freeing up considerable work resources. However, the considerable differences in constants between taxa emphasize the need for taxon-specific relationships, and the potential dangers associated with ignoring body size. The negative influence of body size on the AFDM/DM ratio found in a majority of the molluscs could be caused by increasingly thicker shells with organism age, and/or spawning-induced loss of biologically active tissue in adults. Consequently, future studies utilizing AFDM/DM (and presumably also AFDM/wet mass) ratios should carefully assess the potential influence of body size to ensure more reliable estimates of organism body mass. PMID:28149685

Particle interaction and rheological behavior of cement-based materials at micro- and macro-scales

NASA Astrophysics Data System (ADS)

Lomboy, Gilson Rescober

Rheology of cement based materials is controlled by the interactions at the particle level. The present study investigates the particle interactions and rheological properties of cement-based materials in the micro- and macro-scales. The cementitious materials studied are Portland cement (PC), fly ash (FA), ground granulated blast furnace slag (GGBFS) and densified silica fume (SF). At the micro-scale, aside from the forces on particles due to collisions, interactions of particles in a flowing system include the adhesion and friction. Adhesion is due to the attraction between materials and friction depends on the properties of the sliding surfaces. Atomic Force Microscopy (AFM) is used to measure the adhesion force and coefficient of friction. The adhesion force is measured by pull-off force measurements and is used to calculate Hamaker constants. The coefficient of friction is measured by increasing the deflection set-points on AFM probes with sliding particles, thereby increasing normal loads and friction force. AFM probes were commercial Si3N4 tips and cementitious particles attached to the tips of probe cantilevers. SF was not included in the micro-scale tests due to its limiting size when attaching it to the AFM probes. Other materials included in the tests were silica, calcite and mica, which were used for verification of the developed test method for the adhesion study. The AFM experiments were conducted in dry air and fluid environments at pH levels of 7, 8, 9, 11 and 13. The results in dry air indicate that the Hamaker constant of Class F FA can be similar to PC, but Class C FA can have a high Hamaker constant, also when in contact with other cementitious materials. The results in fluid environments showed low Hamaker constants for Class F fly ashes compared to PC and also showed high Hamaker constants for PC and Class C fly ash. The results for the friction test in dry air indicated that the coefficient of friction of PC is lower than fly ashes, which is attributed to the asperities present on the particle surface. At the macro-scale, flow of cementitious materials may be in its dry or wet state, during transport and handling or when it is used in concrete mixtures, respectively. Hence, the behavior of bulk cementitious materials in their dry state and wet form are studied. In the dry state, the compression, recompression and swell indices, and stiffness modulus of plain and blended cementitious materials are determined by confined uniaxial compression. The coefficients of friction of the bulk materials studied are determined by a direct shear test. The results indicate that shape of particles has a great influence on the compression and shear parameters. The indices for PC blends with FA do not change with FA replacement, while it increases with GGBFS replacement. Replacement with GGBFS slightly decreases coefficient of friction, while replacement with FA significantly decreases coefficient of friction. At low SF replacement, coefficient of friction decreases. In wet state, unary, binary, ternary and quaternary mixes with w/b of 0.35, 0.45 and 0.55 were tested for yield stress, viscosity and thixotropy. It is found that fly ash replacement lowers the rheological properties and replacement with GGBFS and SF increases rheological properties. The distinct element method (DEM) was employed to model particle interaction and bulk behavior. The AFM force curve measurement is simulated to validate the adhesion model in the DEM. The contact due to asperities was incorporated by considering the asperities as a percentage of the radius of the contacting particles. The results of the simulation matches the force-curve obtained from actual AFM experiments. The confined uniaxial compression test is simulated to verify the use of DEM to relate micro-scale properties to macros-scale behavior. The bulk stiffness from the physical experiments is matched in the DEM simulation. The particle stiffness and coefficient of friction are found to have a direct relation to bulk stiffness.

Micro-quantity tissue digestion for metal measurements by use of a microwave acid-digestion bomb.

PubMed

Nicholson, J R; Savory, M G; Savory, J; Wills, M R

1989-03-01

We describe a simple and convenient method for processing small amounts of tissue samples for trace-metal measurements by atomic absorption spectrometry, by use of a modified Parr microwave digestion bomb. Digestion proceeds rapidly (less than or equal to 90 s) in a sealed Teflon-lined vessel that eliminates contamination or loss from volatilization. Small quantities of tissue (5-100 mg dry weight) are digested in high-purity nitric acid, yielding concentrations of analyte that can be measured directly without further sample manipulation. We analyzed National Institute of Standards and Technology bovine liver Standard Reference Material to verify the accuracy of the technique. We assessed the applicability of the technique to analysis for aluminum in bone by comparison with a dry ashing procedure.

Chemical composition and some anti-nutrient content of raw and processed bitter vetch (Vicia ervilia) seed for use as feeding stuff in poultry diet.

PubMed

Sadeghi, Gh; Pourreza, J; Samei, A; Rahmani, H

2009-01-01

An experiment was conducted to determine chemical composition of raw and treated bitter vetch seed for use in poultry diets. Processing methods were: soaked in water for 12 h, then autoclaved and dried (SA); coarsely ground, soaked in water for 24 h, autoclaved and dried (GSA); coarsely ground, soaked in water for 47 h with exchange of water every 12 h, cooked and dried (GSC); coarsely ground, soaked in solution of 1% acetic acid for 24 h at 60 degrees C and dried (GAA). Raw bitter vetch seed was contained 94.52, 26.56, 0.4, 58.86, 3.38, 5.32, 12.28 and 14.20 percent DM, CP, EE, NFE, Ash, CF, ADF and NDF, respectively. Its GE, AME, AMEn, TME and TMEn values were 18.10, 13.15, 14.38, 14.10 and 14.69 MJ/kg, respectively. Results indicated that bitter vetch is a good source of Fe (340 ppm) and Cu (46.7 ppm). It s amino acid profile was suitable and methionine was the first limiting amino acid when compared with broiler and layer chicks requirements. Its canavanine and tannin content were 0.78 and 6.7 mg/kgDM, respectively. Processing methods improved CP and in some cases AMEn. All processing methods especially GSC resulted in a significant (P < 0.05) reduction in canavanine and tannin.

The normalised wildfire ash index (NWAI): a remote sensing approach for quantifying post-wildfire ash loads

NASA Astrophysics Data System (ADS)

Chris, Chafer; Doerr, Stefan; Santin, Cristina

2017-04-01

The impacts of wildfire ash, the powdery residue from fuel burning, on post-fire ecosystems are many and diverse. Ash is a source of nutrients and can help the recovery of vegetation. It can also contain substantial amounts of recalcitrant carbon and thus contribute to long-term carbon storage. In its initial state, the ash layer on the ground can protect the bare soil, mitigating post-fire water erosion by runoff. However, when the adsorbent capability of this layer is exceeded, ash can be transported into the hydrological network and be a major contributor to water contamination. Ash can also contribute to post-fire mass movements such as debris flows. The eco-hydro-geomorphic impacts of ash on post-fire ecosystems are therefore important, but remain poorly quantified. A fundamental step in that direction is the understanding of ash production and distribution at the landscape scale, which would allow incorporating ash as a key parameter into post-fire risk models. We have developed a new spectral index (NWAI) using Landsat imagery to model the spatial distribution of ash loads in the post-fire landscape. It was developed based on a severe wildfire that burnt 13,000 ha of dry eucalyptus forest near Sydney and has also been tested for a forested area burnt by the catastrophic 2009 Black Saturday fires near Melbourne. Although ecosystem and fire characteristics differed substantially between the Sydney and Melbourne fires, our NWAI index performs well. In this contribution we will discuss the (i) the principles of the NWAI and (ii) its potential for pollution risk forecasting.

Investigations of ash fouling with cattle wastes as reburn fuel in a small-scale boiler burner under transient conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hyukjin Oh; Kalyan Annamalai; John M. Sweeten

2008-04-15

Fouling behavior under reburn conditions was investigated with cattle wastes (termed as feedlot biomass, FB) and coal as reburn fuels under a transient condition and short-time operation. A small-scale (30 kW or 100,000 Btu/hr) boiler burner research facility was used for the reburn experiments. The fuels considered for these experiments were natural gas (NG) for the ashless case, pure coal, pure FB, and blends of coal and FB. Two parameters that were used to characterize the ash 'fouling' were (1) the overall heat-transfer coefficient (OHTC) when burning NG and solid fuels as reburn fuels, and (2) the combustible loss throughmore » ash deposited on the surfaces of heat exchanger tubes and the bottom ash in the ash port. A new methodology is presented for determining ash fouling behavior under transient conditions. Results on the OHTCs for solid reburn fuels are compared with the OHTCs for NG. It was found that the growth of the layer of ash depositions over longer periods typically lowers OHTC, and the increased concentration of ash in gas phase promotes radiation in high-temperature zones during initial periods while decreasing the heat transfer in low-temperature zones. The ash analyses indicated that the bottom ash in the ash port contained a smaller percentage of combustibles with a higher FB percentage in the fuels, indicating better performance compared with coal because small particles in FB burn faster and the FB has higher volatile matter on a dry ash-free basis promoting more burn out. 16 refs., 12 figs., 6 tabs.« less

High-volume use of self-cementing spray dry absorber material for structural applications

NASA Astrophysics Data System (ADS)

Riley, Charles E.

Spray dry absorber (SDA) material, or spray dryer ash, is a byproduct of energy generation by coal combustion and sulfur emissions controls. Like any resource, it ought to be used to its fullest potential offsetting as many of the negative environmental impacts of coal combustion as possible throughout its lifecycle. Its cementitious and pozzolanic properties suggest it be used to augment or replace another energy and emissions intensive product: Portland cement. There is excellent potential for spray dryer ash to be used beneficially in structural applications, which will offset CO2 emissions due to Portland cement production, divert landfill waste by further utilizing a plentiful coal combustion by-product, and create more durable and sustainable structures. The research into beneficial use applications for SDA material is relatively undeveloped and the material is highly underutilized. This dissertation explored a specific self-cementing spray dryer ash for use as a binder in structural materials. Strength and stiffness properties of hydrated spray dryer ash mortars were improved by chemical activation with Portland cement and reinforcement with polymer fibers from automobile tire recycling. Portland cement at additions of five percent of the cementitious material was found to function effectively as an activating agent for spray dryer ash and had a significant impact on the hardened properties. The recycled polymer fibers improved the ductility and toughness of the material in all cases and increased the compressive strength of weak matrix materials like the pure hydrated ash. The resulting hardened materials exhibited useful properties that were sufficient to suggest that they be used in structural applications such as concrete, masonry block, or as a hydraulic cement binder. While the long-term performance characteristics remain to be investigated, from an embodied-energy and carbon emissions standpoint the material investigated here is far superior to Portland cement.

Earth observations taken by the Expedition 14 crew

NASA Image and Video Library

2007-03-01

ISS014-E-15732 (1 March 2007) --- Salt ponds of Botswana are featured in this image photographed by an Expedition 14 crewmember on the International Space Station. This recent, detailed view shows the salt ponds of one of Africa's major producers of soda ash (sodium carbonate) and salt. Soda ash is used for glass making, in metallurgy, in the detergent industry, and in chemical manufacture. The image shows a small part of the great salt flats of central Botswana known as the Makgadikgadi Salt Pans. The soda ash and salt are both mainly exported (since 1989) to most countries in southern and central Africa. Brines from just beneath the pan floor are evaporated to produce the soda ash and salt -- a process for which the semiarid climate of Botswana is ideal. Red salt-loving algae in the ponds indicate that the salinity of the evaporating brines is medium to high. The salt pans of Botswana--a prominent visual photo target of interest for astronauts aboard the station--lie at the low point of a vast shallow continental basin. Rivers draining from as far away as central Angola - more than 1,000 kilometers away - supply water to the pans. According to scientists, during several wet climatic phases in the recent geological past the pans were permanently filled with water, for thousands of years, only to dry out when climates fluctuated to drier conditions. During dry phases water only reaches the pans underground. These are the brines that support the ash and salt industry. During wet phases when open water exists, beach ridges are constructed by wave action. One of these crosses the lower part of the view.

Pilot Plant Program for the AED Advanced Coal Cleaning System. Phase II. Interim final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-08-01

Advanced Energy Dynamics, Inc. (AED), has developed a proprietary coal cleaning process which employs a combination of ionization and electrostatic separation to remove both sulfur and ash from dry pulverized coal. The Ohio Department of Energy sponsored the first part of a program to evaluate, develop, and demonstrate the process in a continuous-flow pilot plant. Various coals used by Ohio electric utilities were characterized and classified, and sulfur reduction, ash reduction and Btu recovery were measured. Sulfur removal in various coals ranged from 33 to 68% (on a Btu basis). Ash removal ranged from 17 to 59% (on a Btumore » basis). Ash removal of particles greater than 53 microns ranged from 46 to 88%. Btu recovery ranged from 90 to 97%. These results, especially the large percentage removal of ash particles greater than 53 microns, suggest that the AED system can contribute materially to improved boiler performance and availability. The study indicated the following potential areas for commercial utilization of the AED process: installation between the pulverizer and boiler of conventional coal-fired power utilities; reclamation of fine coal refuse; dry coal cleaning to supplement, and, if necessary, to take the place of conventional coal cleaning; upgrading coal used in: (1) coal-oil mixtures, (2) gasification and liquefaction processes designed to handle pulverized coal; and (3) blast furnaces for making steel, as a fuel supplement to the coke. Partial cleaning of coking coal blends during preheating may also prove economically attractive. Numerous other industrial processes which use pulverized coal such as the production of activated carbon and direct reduction of iron ore may also benefit from the use of AED coal cleaning.« less

Elemental and thermo-chemical analysis of oil palm fronds for biomass energy conversion

NASA Astrophysics Data System (ADS)

Guangul, Fiseha Mekonnen; Sulaiman, Shaharin Anwar; Raghavan, Vijay R.

2012-06-01

Oil palm frond is the most abundant yet untapped biomass waste in Malaysia. This paper investigates the characteristics of raw oil palm fronds and its ash to evaluate its potential utilization as a biomass fuel for gasification process using single throat downdraft gasifier. The morphological nature, elemental content, proximate and ultimate analysis and calorific value were studied. Field emission scanning electron microscopy and x-ray fluorescence were used to investigate the surface morphology, elemental and mineralogical nature of oil palm frond and its ash. The results were compared with other agricultural and forestry biomass wastes. From proximate analysis volatile matter, fixed carbon and ash were found to be 83.5%, 15.2% and 1.3%, respectively on dry basis. From ultimate analysis result values of 44.58%, 4.53%, 0.71% and 0.07% for carbon, hydrogen, nitrogen and sulfur were found respectively on dry basis. Oxygen was determined by difference and found to be 48.81%. The proximate and ultimate analysis results indicate that oil palm frond is better than agricultural wastes and less than most forestry wastes to use as a feedstock in the gasification process in order to get a better quality of syngas. The amount of ash content in OPF was found to be much less than in agricultural wastes and higher than most forestry wastes. From x-ray fluorescence analysis CaO and K2O were found as the major oxides in oil palm fronds and rice husk ash with the amount of 28.46% and 15.71% respectively. The overall results of oil palm fronds were found to be satisfactory to use as a feedstock for the process of gasification.

Modification of dry grain processing for rice nutrition produced

NASA Astrophysics Data System (ADS)

Rahman, A. N. F.; Genisa, J.; Dirpan, A.; Badani, A. A.

2018-05-01

Rice is a staple food for people in Indonesia that provides high energy and nutrients of up to 360 calories per 100 g. Based on the research it was known that the nutrient content in rice will increased by soaking. This is suspected because the nutrient content in the aleurone layer adsorbed to the endosperm. The purpose of this research was to know the effect of dry grain immersion on the nutrition of rice produced. The method of this research was conducted through some stages: 1. Preparation of raw materials, 2. Grain immersion, 3. Grain drying, 4. Peeling chaff, 5. Testing the nutritional value of rice. The research was processed by using factorial randomized complete random design (RCRD) with three replications. The result showed that soaking the grain for 12 hours has the highest nutritional value increases compared to the control. Proximate test resulted from the best treatment were: protein content of 8.26%, ash content of 0.42% and thiamine content of 0.023%.

Production of thermal insulation blocks from bottom ash of fluidized bed combustion system.

PubMed

Mandal, A K; Sinha, O P

2017-08-01

The issues of disposal and environmental problems are increased by the generation of bottom ash from the thermal power plants day by day; hence, its recycling is required. The present study aimed to make thermal insulation blocks using as raw material bottom ash and iron ore slime as a binder and to characterize their engineering properties. Two different fineness values of bottom ash were considered with varying amounts of iron ore slime (0-10%) to make the blocks. Blocks were dried followed by firing at 1000, 1100 and 1200°C, respectively. Cold crushing strength, density and thermal conductivity of these fired blocks showed increasing behaviour with firing temperature, fineness of bottom ash and iron ore slime content. In contrast, a reverse trend was observed in the case of porosity. With increasing firing temperature, the formation of lower melting phases like iron silicate followed by iron aluminium silicate was observed, which imparts the strength inside the blocks. The coarser particles of bottom ash increase the interparticle spaces, which enhances the apparent porosity, resulting in higher thermal insulation property in the blocks. Blocks having better thermal insulation property could be possible to make effectively from coarse bottom ash by adding iron ore slime as a binder.

Flue gas desulfurization gypsum and fly ash

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-05-01

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned formore » all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.« less

Elemental analyses of pine bark and wood in an environmental study.

PubMed

Saarela, K-E; Harju, L; Rajander, J; Lill, J-O; Heselius, S-J; Lindroos, A; Mattsson, K

2005-05-01

Bark and wood samples were taken from the same individuals of Scots pine (Pinus sylvestris L.) from a polluted area close to a Cu-Ni smelter in Harjavalta and from some relatively unpolluted areas in western Finland. The samples were analysed by thick-target particle induced X-ray emission (PIXE) after preconcentration by dry ashing at 550 degrees C. The elemental contents of pine bark and wood were compared to study the impact of heavy metal pollution on pine trees. By comparison of the elemental contents in ashes of bark and wood, a normalisation was obtained. For the relatively clean areas, the ratios of the concentration in bark ash to the concentration in wood ash for different elements were close to 1. This means that the ashes of Scots Pine wood and bark have quite similar elemental composition. For the samples from the polluted area the mean concentration ratios for some heavy metals were elevated (13-28), reflecting the effect of direct atmospheric contamination. The metal contents in the ashes of pine bark and wood were also compared to recommendations for ashes to be recycled back to the forest environment. Bark from areas close to emission sources of heavy metal pollution should be considered with caution if aiming at recycling the ash. Burning of bark fuel of pine grown within 6 km of the Cu-Ni smelter is shown to generate ashes with high levels of Cu, Ni as well as Cd, As and Pb.

Bromine and Chlorine in Aerosols and Fly Ash when Co-Firing Solid Recovered Fuel, Spruce Bark and Paper Mill Sludge in a 80MWth BFB Boiler

NASA Astrophysics Data System (ADS)

Vainikka, P.; Silvennoinen, J.; Yrjas, P.; Frantsi, A.; Hietanen, L.; Hupa, M.; Taipale, R.

Aerosol and fly ash sampling was carried out at a 80MWth bubbling fluidised bed (BFB) boiler plant co-firing solid recovered fuel (SRF), spruce bark and paper mill wastewater sludge in two experimental conditions. The SRF-Bark ratio in the fuel mix was kept constant at 50%-50% on dry mass basis in both experiments but two sludge proportions were used: 15% and 4% on dry mass basis. Aerosol samples were collected from the superheater region of the boiler furnace and fly ash from the electrostatic precipitator (ESP). Na, K, Cl and S were found to be in mainly water soluble compounds in the aerosols sampled by means of a Dekati type Low Pressure Impactor (DLPI). Bromine was found in several weight percentages in aerosols and it was amongst the main elements in some of the samples collected. Bromine is assumed to mainly originate from flame retarded plastics and textiles in the SRF. According to the measurements, the fate of Br seems to be analogous to the other main halogen, Cl, and its conversion from fuel to aerosols was high, indicating a strong tendency to form bromine salts.

Effects of different treatments of fly ash and mining soil on growth and antioxidant protection of Indian wild rice.

PubMed

Bisoi, Sidhanta Sekhar; Mishra, Swati S; Barik, Jijnasa; Panda, Debabrata

2017-05-04

The aim of the present study was investigation of the effects of fly ash and mining soil on growth and antioxidant protection of two cultivars of Indian wild rice (Oryza nivara and Oryza rufipogon) for possible phytoremediation and restoration of metal-contaminated site. In this study, Indian wild rice showed significant changes in germination, growth, and biochemical parameters after exposure to different ratio of fly ash and mining soil with garden soil. There was significant reduction of germination, fresh weight, dry weight, leaf chlorophyll content, leaf area, Special Analysis Device Chlorophyll (SPAD) Index, proteins, and activities of antioxidant enzymes in both cultivars of the wild rice grown in 100% fly ash and mining soil compared to the plants grown in 100% garden soil. Results from this study showed that in both cultivars of wild rice, all growth and antioxidant parameters increased when grown in 50% fly ash and mining soil. Taken together, Indian wild rice has the capacity to tolerate 50% of fly ash and mining soil, and can be considered as a good candidate for possible phytoremediation of contaminated soils.

Impact of Collection Equipment on Ash Variability of Baled Corn Stover Biomass for Bioenergy

DOE Office of Scientific and Technical Information (OSTI.GOV)

William Smith; Jeffery Einerson; Kevin Kenney

2014-09-01

Cost-effective conversion of agricultural residues for renewable energy hinges not only on the material’s quality but also the biorefinery’s ability to reliably measure quality specifications. The ash content of biomass is one such specification, influencing pretreatment and disposal costs for the conversion facility and the overall value of a delivered lot of biomass. The biomass harvest process represents a primary pathway for accumulation of soil-derived ash within baled material. In this work, the influence of five collection techniques on the total ash content and variability of ash content within baled corn stover in southwest Kansas is discussed. The equipment testedmore » included a mower for cutting the corn stover stubble, a basket rake, wheel rake, or shred flail to gather the stover, and a mixed or uniform in-feed baler for final collection. The results showed mean ash content to range from 11.5 to 28.2 % depending on operational choice. Resulting impacts on feedstock costs for a biochemical conversion process range from $5.38 to $22.30 Mg-1 based on the loss of convertible dry matter and ash disposal costs. Collection techniques that minimized soil contact (shred flail or nonmowed stubble) were shown to prevent excessive ash contamination, whereas more aggressive techniques (mowing and use of a wheel rake) caused greater soil disturbance and entrainment within the final baled material. Material sampling and testing were shown to become more difficult as within-bale ash variability increased, creating uncertainty around feedstock quality and the associated costs of ash mitigation.« less

Evaluation of days of total collection and use of internal markers in nutritional trials with small ruminants.

PubMed

da Teixeira, Catarine S C; de Carvalho, Gleidson G P; Nicory, Isis C M; Santos, Aracele V; Dos Pina, Douglas S; de Júnior, José E F; de Araújo, Maria L G M L; de Rufino, Luana M A; Cirne, Luís G A; Pires, Aureliano J V

2018-04-01

Two experiments were conducted to evaluate the number of days required for total fecal collection and the viability of using the indigestible dry matter (iDM), indigestible neutral detergent fiber (iNDF), and indigestible acid detergent fiber (iADF) internal markers to determine the fecal excretion of dry matter (FEDM) and digestibility in nutritional trials with small ruminants. Eight sheep in the first experiment and eight goats in the second experiment were distributed into two 4 × 4 Latin square designs. There were no significant differences between days of total fecal collection for FEDM; digestibility of dry matter (DM), organic matter (OM), crude protein (CP), ether extract (EE), neutral detergent fiber corrected for ash and protein (NDFap), and non-fibrous carbohydrates corrected for ash and protein (NFCap); and total digestible nutrients (TDN) in both species. The results suggest that only 1 day of total collection is sufficient to obtain the FEDM and the digestibility of the nutritional components in sheep and goats. The markers are efficient in determining fecal production and digestibility in these animal species.

Atmospheric distribution and removal of volcanic ash after the eruption of Kasatochi volcano: A regional model study

NASA Astrophysics Data System (ADS)

Langmann, Baerbel; ZakšEk, Klemen; Hort, Matthias

2010-01-01

In August 2008, Kasatochi volcano on the Aleutian Islands erupted without much advance warning. Volcanic ash released during this eruption quickly settled out of the atmosphere, mainly into the NE Pacific Ocean. The amount of volcanic ash, as well as the ash fall area and volume into the NE Pacific Ocean, remains speculative, as only a limited number of measurements is available. We used a three-dimensional atmosphere/chemistry-aerosol model to determine the atmospheric distribution of SO2 and volcanic ash and its fallout after the eruption of Kasatochi volcano. In a first step, modeled atmospheric SO2 distributions are compared with satellite data, thereby evaluating the model capabilities to reasonably reproduce atmospheric transport patterns. For modeled volcanic ash mass a considerable reduction of the atmospheric content already occurred by 10 August, the second day after the eruption in accordance with satellite observations. Gravitational settling is the most efficient removal process for volcanic ash mass, exceeding dry and wet deposition by far. Assuming an ash volume of 0.3 km3 released during the eruption of Kasatochi volcano and a median ash particle diameter of 4 μm, the mass of volcanic ash removed at ground within the 0.1 mm isopach covers an area of 7.6 × 105 km2 over the NE Pacific Ocean and makes up 49% of the removed material out of the atmosphere. The amount of ash and that of iron attached to it is sufficient to explain measured seawater CO2 decrease at the ocean station Papa in August 2008 induced by iron fertilization and subsequent phytoplankton production.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kanna, V.; Olson, R.A.; Jennings, H.M.

The effects of drying on mortars containing Portland cement blended with fly ash or slag on the shrinkage, extent of surface cracking, pore size distribution as measured by mercury intrusion porosimetry, flexural strength, fracture toughness, and Young`s modulus are reported. Specimens were exposed to conditions of 100% relative humidity (RH), 50% RH, and/or oven-drying at 105 C. Drying coarsened the pore structure and increased the density of surface cracks, but surprisingly increased the flexural strength and the fracture toughness, and as anticipated lowered the Young`s modulus. This was regardless of the content of mineral admixture.

Process simulation and cost analysis for removing inorganics from wood chips using combined mechanical and chemical preprocessing

DOE PAGES

Hu, Hongqiang; Westover, Tyler L.; Cherry, Robert; ...

2016-10-03

Inorganic species (ash) in biomass feedstocks negatively impact thermochemical and biochemical energy conversion processes. In this work, a process simulation model is developed to model the reduction in ash content of loblolly logging residues using a combination of air classification and dilute-acid leaching. Various scenarios are considered, and it is found that costs associated with discarding high-ash material from air classification are substantial. The costs of material loss can be reduced by chemical leaching the high-ash fraction obtained from air classification. The optimal leaching condition is found to be approximately 0.1 wt% sulfuric acid at 24°C. In example scenarios, totalmore » process costs in the range of $10-12/dry tonnes of product are projected that result in a removal of 11, 66, 53 and 86% of organics, total ash (inorganics), alkaline earth metals and phosphorus (AAEMS+P), and silicon, respectively. Here, sensitivity analyses indicate that costs associated with loss of organic material during processing (yield losses), brine disposal, and labor have the greatest potential to impact the total processing cost.« less

Kivihiilivoimalan Sivutuotteiden Maarakennuskaeytoen Elinkaariarviointi

DOT National Transportation Integrated Search

1998-01-01

The goal of this project was to assess the environmental impact of using fly ash and flue gas desulphurization (FGD) residues (produced by pulverized coal-fired power plants which employ semi dry scrubbing technology) in earthworks. The use of fly as...

Identification of Chromium Resistant Bacteria from Dry Fly Ash Sample of Mejia MTPS Thermal Power Plant, West Bengal, India.

PubMed

Roychowdhury, Roopali; Mukherjee, Pritam; Roy, Madhumita

2016-02-01

Eight chromium resistant bacteria were isolated from a dry fly ash sample of DVC-MTPS thermal power plant located in Bankura, West Bengal, India. These isolates displayed different degrees of chromate reduction under aerobic conditions. According to 16S rDNA gene analysis, five of them were Staphylococcus, two were Bacillus and one was Micrococcus. The minimum inhibitory concentration towards chromium and the ability to reduce hexavalent chromium to trivalent chromium was highest in Staphylococcus haemolyticus strain HMR17. All the strains were resistant to multiple heavy metals (As, Cu, Cd, Co, Zn, Mn, Pb and Fe) and reduced toxic hexavalent chromium to relatively non toxic trivalent chromium even in the presence of these multiple heavy metals. All of them showed resistance to different antibiotics. In a soil microcosm study, S. haemolyticus strain HMR17 completely reduced 4 mM hexavalent chromium within 7 days of incubation.

Elaboration of new ceramic microfiltration membranes from mineral coal fly ash applied to waste water treatment.

PubMed

Jedidi, Ilyes; Saïdi, Sami; Khemakhem, Sabeur; Larbot, André; Elloumi-Ammar, Najwa; Fourati, Amine; Charfi, Aboulhassan; Salah, Abdelhamid Ben; Amar, Raja Ben

2009-12-15

This work aims to develop a new mineral porous tubular membrane based on mineral coal fly ash. Finely ground mineral coal powder was calcinated at 700 degrees C for about 3 h. The elaboration of the mesoporous layer was performed by the slip-casting method using a suspension made of the mixture of fly-ash powder, water and polyvinyl alcohol (PVA). The obtained membrane was submitted to a thermal treatment which consists in drying at room temperature for 24 h then a sintering at 800 degrees C. SEM photographs indicated that the membrane surface was homogeneous and did not present any macrodefects (cracks, etc...). The average pore diameter of the active layer was 0.25 microm and the thickness was around 20 microm. The membrane permeability was 475 l/h m(2) bar. This membrane was applied to the treatment of the dying effluents generated by the washing baths in the textile industry. The performances in term of permeate flux and efficiency were determined and compared to those obtained using a commercial alumina microfiltration membrane. Almost the same stabilised permeate flux was obtained (about 100 l h(-1)m(-2)). The quality of permeate was almost the same with the two membranes: the COD and color removal was 75% and 90% respectively.

Potential of activated sludge disintegration.

PubMed

Boehler, M; Siegrist, H

2006-01-01

The disposal of sewage sludge and the agricultural use of stabilised sludge are decreasing due to more stringent regulations in Europe. An increasing fraction of sewage sludge must therefore be dewatered, dried, incinerated and the ashes disposed of in landfills. These processes are cost-intensive and also lead to the loss of valuable phosphate resources incorporated in the sludge ash. The implementation of processes that could reduce excess sludge production and recycle phosphate is therefore recommended. Disintegration of biological sludge by mechanical, thermal and physical methods could significantly reduce excess sludge production, improve the settling properties of the sludge and reduce bulking and scumming. The solubilised COD could also improve denitrification if the treated sludge is recycled to the anoxic zone. However, disintegration partly inhibits and kills nitrifiers and could therefore shorten their effective solid retention time, thus reducing the safety of the nitrification. This paper discusses the potential of disintegration on sludge reduction, the operating stability of nitrification, the improvement of denitrification and also presents an energy and cost evaluation.

Method of burning lightly loaded coal-water slurries

DOEpatents

Krishna, C.R.

1984-07-27

In a preferred arrangement of the method of the invention, a lightly loaded coal-water slurry, containing in the range of approximately 40% to 52% + 2% by weight coal, is atomized to strip water from coal particles in the mixture. Primary combustor air is forced around the atomized spray in a combustion chamber of a combustor to swirl the air in a helical path through the combustion chamber. A flame is established within the combustion chamber to ignite the stripped coal particles, and flame temperature regulating means are provided for maintaining the flame temperature within a desired predetermined range of temperatures that is effective to produce dry, essentially slag-free ash from the combustion process.

Characterization of Eyjafjallajokull volcanic ash particles and a protocol for rapid risk assessment.

PubMed

Gislason, S R; Hassenkam, T; Nedel, S; Bovet, N; Eiriksdottir, E S; Alfredsson, H A; Hem, C P; Balogh, Z I; Dideriksen, K; Oskarsson, N; Sigfusson, B; Larsen, G; Stipp, S L S

2011-05-03

On April 14, 2010, when meltwaters from the Eyjafjallajökull glacier mixed with hot magma, an explosive eruption sent unusually fine-grained ash into the jet stream. It quickly dispersed over Europe. Previous airplane encounters with ash resulted in sandblasted windows and particles melted inside jet engines, causing them to fail. Therefore, air traffic was grounded for several days. Concerns also arose about health risks from fallout, because ash can transport acids as well as toxic compounds, such as fluoride, aluminum, and arsenic. Studies on ash are usually made on material collected far from the source, where it could have mixed with other atmospheric particles, or after exposure to water as rain or fog, which would alter surface composition. For this study, a unique set of dry ash samples was collected immediately after the explosive event and compared with fresh ash from a later, more typical eruption. Using nanotechniques, custom-designed for studying natural materials, we explored the physical and chemical nature of the ash to determine if fears about health and safety were justified and we developed a protocol that will serve for assessing risks during a future event. On single particles, we identified the composition of nanometer scale salt coatings and measured the mass of adsorbed salts with picogram resolution. The particles of explosive ash that reached Europe in the jet stream were especially sharp and abrasive over their entire size range, from submillimeter to tens of nanometers. Edges remained sharp even after a couple of weeks of abrasion in stirred water suspensions.

Characterization of Eyjafjallajökull volcanic ash particles and a protocol for rapid risk assessment

PubMed Central

Gislason, S. R.; Hassenkam, T.; Nedel, S.; Bovet, N.; Eiriksdottir, E. S.; Alfredsson, H. A.; Hem, C. P.; Balogh, Z. I.; Dideriksen, K.; Oskarsson, N.; Sigfusson, B.; Larsen, G.; Stipp, S. L. S.

2011-01-01

On April 14, 2010, when meltwaters from the Eyjafjallajökull glacier mixed with hot magma, an explosive eruption sent unusually fine-grained ash into the jet stream. It quickly dispersed over Europe. Previous airplane encounters with ash resulted in sandblasted windows and particles melted inside jet engines, causing them to fail. Therefore, air traffic was grounded for several days. Concerns also arose about health risks from fallout, because ash can transport acids as well as toxic compounds, such as fluoride, aluminum, and arsenic. Studies on ash are usually made on material collected far from the source, where it could have mixed with other atmospheric particles, or after exposure to water as rain or fog, which would alter surface composition. For this study, a unique set of dry ash samples was collected immediately after the explosive event and compared with fresh ash from a later, more typical eruption. Using nanotechniques, custom-designed for studying natural materials, we explored the physical and chemical nature of the ash to determine if fears about health and safety were justified and we developed a protocol that will serve for assessing risks during a future event. On single particles, we identified the composition of nanometer scale salt coatings and measured the mass of adsorbed salts with picogram resolution. The particles of explosive ash that reached Europe in the jet stream were especially sharp and abrasive over their entire size range, from submillimeter to tens of nanometers. Edges remained sharp even after a couple of weeks of abrasion in stirred water suspensions. PMID:21518890

Ash effects on the thermal conductivity of a mediterranean loam soil

NASA Astrophysics Data System (ADS)

Rubio, Carles; Pereira, Paulo; Ubeda, Xavier

2014-05-01

The purpose of this work is to explore the variability on the soil thermal conductivity for a burnt soil and assessing the effects of the ashes on the heat transfer when they were incorporated into the soil matrix. A set of 42 soil samples from the Montgrí massif experimental plot between surface and 5 cm depth was collected before and after the soil was burnt. A thermal characterization of the soil was carried out. For that a dry out curve was constructed, which presented the relationship between water content and thermal conductivity for both types of soil samples, burnt and non-burnt soil. The results shown changes in the heat pulse transfer, being more conductive the soil before to be burnt (0.378 W•m-1•C-1) than the soil after to be exposed to the fire (0.337 W•m-1•C-1). Indeed, on the whole of moisture scenarios the values of thermal conductivity decreased after soil was burnt. Another experimental concern was based on to observe the soil thermal behaviour when ash collected after fire was incorporated into the burnt soil matrix. In this case, soil thermal and soil hydrodynamic behaviour presented differences according to the type of ash. Soil mixed with fly ash showed higher thermal conductivity than soil mixed with bottom ash. To sum up; the soil thermal conductivity decreased when soil was burnt. On the other hand, soil thermal conductivity shown differences depending on the type of ash incorporated into the matrix. Fly ash transferred the heat pulse better than bottom ash.

Removal of chloride from MSWI fly ash.

PubMed

Chen, Wei-Sheng; Chang, Fang-Chih; Shen, Yun-Hwei; Tsai, Min-Shing; Ko, Chun-Han

2012-10-30

The high levels of alkali chloride and soluble metal salts present in MSWI fly ash is worth noting for their impact on the environment. In addition, the recycling or reuse of fly ash has become an issue because of limited landfill space. The chloride content in fly ash limits its application as basis for construction materials. Water-soluble chlorides such as potassium chloride (KCl), sodium chloride (NaCl), and calcium chloride hydrate (CaCl(2) · 2H(2)O) in fly ash are easily washed away. However, calcium chloride hydroxide (Ca(OH)Cl) might not be easy to leach away at room temperature. The roasting and washing-flushing processes were applied to remove chloride content in this study. Additionally, air and CO(2) were introduced into the washing process to neutralize the hazardous nature of chlorides. In comparison with the water flushing process, the roasting process is more efficient in reducing the process of solid-liquid separation and drying for the reuse of Cl-removed fly ash particles. In several roasting experiments, the removal of chloride content from fly ash at 1050°C for 3h showed the best results (83% chloride removal efficiency). At a solid to liquid ratio of 1:10 the water-flushing process can almost totally remove water-soluble chloride (97% chloride removal efficiency). Analyses of mineralogical change also prove the efficiency of the fly ash roasting and washing mechanisms for chloride removal. Copyright © 2012 Elsevier B.V. All rights reserved.

In vitro evaluation of pulmonary deposition of airborne volcanic ash

NASA Astrophysics Data System (ADS)

Lähde, Anna; Sæunn Gudmundsdottir, Sigurbjörg; Joutsensaari, Jorma; Tapper, Unto; Ruusunen, Jarno; Ihalainen, Mika; Karhunen, Tommi; Torvela, Tiina; Jokiniemi, Jorma; Järvinen, Kristiina; Gíslason, Sigurður Reynir; Briem, Haraldur; Gizurarson, Sveinbjörn

2013-05-01

There has been an increasing interest in the effects of volcanic eruption on the environment, climate, and health following two recent volcanic eruptions in Iceland. Although health issues are mainly focused on subjects living close to the eruption due to the high concentration of airborne ash and gasses in close vicinity to the volcanoes, the ash may also reach high altitude and get distributed thousands of kilometers away from the volcano. Ash particles used in the studies were collected at the Eyjafjallajökull and Grímsvötn eruption sites. The composition, size, density and morphology of the particles were analyzed and the effect of particle properties on the re-dispersion and lung deposition were studied. The aerodynamic size and morphology of the particles were consistent with field measurement results obtained during the eruptions. Due to their size and structure, the ash particles can be re-suspended and transported into the lungs. The total surface area of submicron ash particles deposited into the alveolar and tracheobronchial regions of the lungs were 3-9% and 1-2%, respectively. Although the main fraction of the surface area is deposited in the head airways region, a significant amount of particles can deposit into the alveolar and tracheobronchial regions. The results indicate that a substantial increase in the concentration of respirable airborne ash particles and associated health hazard can take place if the deposited ash particles are re-suspended under dry, windy conditions or by outdoor human activity.

[Comparative study on five pretreatment methods for ICP-OES determination of mineral elements in Rosa rugosa].

PubMed

Zhao, Ning; Yang, Bin; Duan, Yu-Cen; Lei, Ran

2011-08-01

Abstract Five different pretreatment methods, including dry ashing and microwave digestion with four acid systems (HNO3 + H2O2, HNO3 + H2O2 + HF, HNO3 + HClO4 and HNO3 + HClO4 + HF), were employed for digestion of the samples of Rosa rugosa. Nine major and trace elements were determined using ICP-OES method. The addition standard recovery rates indicate that, with the system of HNO3 + HClO4, better results can be obtained for most of the determined elements. With this method, except for Fe, the recovery rates are in the range of 95.4%-104.6%. For Fe, higher recovery rate (99%) was obtained with HNO3 + H2O2 + HF system.

Fly ash carbon passivation

DOE Office of Scientific and Technical Information (OSTI.GOV)

La Count, Robert B; Baltrus, John P; Kern, Douglas G

A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most ofmore » the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.« less

Probabilistic detection of volcanic ash using a Bayesian approach.

PubMed

Mackie, Shona; Watson, Matthew

2014-03-16

Airborne volcanic ash can pose a hazard to aviation, agriculture, and both human and animal health. It is therefore important that ash clouds are monitored both day and night, even when they travel far from their source. Infrared satellite data provide perhaps the only means of doing this, and since the hugely expensive ash crisis that followed the 2010 Eyjafjalljökull eruption, much research has been carried out into techniques for discriminating ash in such data and for deriving key properties. Such techniques are generally specific to data from particular sensors, and most approaches result in a binary classification of pixels into "ash" and "ash free" classes with no indication of the classification certainty for individual pixels. Furthermore, almost all operational methods rely on expert-set thresholds to determine what constitutes "ash" and can therefore be criticized for being subjective and dependent on expertise that may not remain with an institution. Very few existing methods exploit available contemporaneous atmospheric data to inform the detection, despite the sensitivity of most techniques to atmospheric parameters. The Bayesian method proposed here does exploit such data and gives a probabilistic, physically based classification. We provide an example of the method's implementation for a scene containing both land and sea observations, and a large area of desert dust (often misidentified as ash by other methods). The technique has already been successfully applied to other detection problems in remote sensing, and this work shows that it will be a useful and effective tool for ash detection. Presentation of a probabilistic volcanic ash detection schemeMethod for calculation of probability density function for ash observationsDemonstration of a remote sensing technique for monitoring volcanic ash hazards.

Thermochemical treatment of sewage sludge ash with sodium salt additives for phosphorus fertilizer production--Analysis of underlying chemical reactions.

PubMed

Stemann, Jan; Peplinski, Burkhard; Adam, Christian

2015-11-01

Stocks of high grade phosphate rock are becoming scarce, and there is growing concern about potentially harmful impurities in conventional phosphorus fertilizers. Sewage sludge ash is a promising secondary phosphorus source. However, to remove heavy metals and convert the phosphorus contained in sewage sludge ash into mineral phases available to plants, an after-treatment is required. Laboratory-scale calcination experiments of sewage sludge ash blended with sodium salts using dried sewage sludge as a reducing agent were carried out at 1000°C. Thus, the Ca3(PO4)2 or whitlockite component of raw sewage sludge ash, which is not readily plant available, was converted to CaNaPO4 (buchwaldite). Consequently, nearly complete phosphorus solubility in ammonium citrate (a well-established indicator for plant availability) was achieved. Moreover, it was shown that Na2CO3 may be replaced by moderately priced Na2SO4. However, molar ratios of Na/P>2 were required to achieve >80% phosphorus solubility. Such over-stoichiometric Na consumption is largely caused by side reactions with the SiO2 component of the sewage sludge ash - an explanation for which clear evidence is provided for the first time. Copyright © 2015 Elsevier Ltd. All rights reserved.

The role of fly-ash particulate material and oxide catalysts in stone degradation

NASA Astrophysics Data System (ADS)

Hutchinson, A. J.; Johnson, J. B.; Thompson, G. E.; Wood, G. C.; Sage, P. W.; Cooke, M. J.

Studies of fly-ash composition identified the presence of calcium and sulphur, indicating their potential role as sources of calcium sulphate. Residual acidity (particularly for oil fly ash) suggested the possibility of enhanced chemical reaction, and the presence of transition metals, probably as oxides, might accelerate the oxidation of SO 2 to SO 42-. Exposure tests in a laboratory-based rig simulating dry deposition on Portland and Monks Park limestone, either seeded or unseeded with fly-ash particulate material or transition metal oxide catalysts, were carried out using an SO 2-containing environment at 95% r.h. Enhanced sulphation of these seeded limestones due to the above factors was minimal; at high loadings of fly ash, there was even evidence of masking the limestone surface, reducing sulphation. However, pure CaCO 3 powder in the exposure rig showed increases in sulphation when seeded with metal oxide catalysts. Thus the limestones examined contained sufficient inherent catalysts for the oxidation of SO 2 to SO 42- to proceed at such a rate that external catalysts were superfluous. This implies that dissolution rate of SO 2 in moisture films controls the availability of species for reaction with these carbonate-based stones and that fly ash deposited from the atmosphere does not enhance the reaction.

Phosphorus leaching from soils amended with thermally gasified piggery waste ash.

PubMed

Kuligowski, Ksawery; Poulsen, Tjalfe Gorm

2009-09-01

In regions with intensive livestock farming, thermal treatment for local energy extraction from the manure and export of the P rich ash as a fertilizer has gained interest. One of the main risks associated with P fertilizers is eutrophication of water bodies. In this study P and K mobility in ash from anaerobically digested, thermally gasified (GA) and incinerated (IA) piggery waste has been tested using water loads ranging from 0.1 to 200 ml g(-1). Leaching of P from soil columns amended with GA was investigated for one P application rate (205 kg P ha(-1) corresponding to 91 mg P kg(-1) soil dry matter) as a function of precipitation rate (9.5 and 2.5 mm h(-1)), soil type (Jyndevad agricultural soil and sand), amount of time elapsed between ash amendment and onset of precipitation (0 and 5 weeks) and compared to leaching from soils amended with a commercial fertilizer (Na(2)HPO(4)). Water soluble P in GA and IA constituted 0.04% and 0.8% of total ash P. Ash amended soil released much less P (0.35% of total P applied in sand) than Na(2)HPO(4) (97% and 12% of total P applied in Jyndevad and sand, respectively).

Fabricaton of brick without burning process

NASA Astrophysics Data System (ADS)

Zultiniar; Fadli, A.; Yenti, S. R.; Drastinawati; Thariq, M. R. A.

2018-04-01

Brick is a material with many applications on building materials. The purpose of this research is to study the effect of fly ash addition and hardening time on mechanical properties of brick produced. Brick was formed by mixing cement, clay, water and fly ash with addition point was 0;0,3;0,6;0,9;1,2 kg weight. Brick was dried at room temperature for 7, 14 and 21 days. The result showed that compressive strength with addition 0,6 kg fly ash for 21 days was the the strongest where that’s value was 9,375 N/mm2. The highest porosity was get in on 21,34 % with 1,2 fly ash addition. The result of TCLP showed that for Pb, Cu, Cr content was still below the quality standards based on PP No.85 TH 1999 and still considered harmless. Leachate value for Pb of 3,10 mg/L, 1,213 mg/L for Cr and 4,374 mg/L for Cu.

Effect of partitioning the nonfiber carbohydrate fraction and neutral detergent fiber method on digestibility of carbohydrates by dairy cows.

PubMed

Tebbe, A W; Faulkner, M J; Weiss, W P

2017-08-01

Many nutrition models rely on summative equations to estimate feed and diet energy concentrations. These models partition feed into nutrient fractions and multiply the fractions by their estimated true digestibility, and the digestible mass provided by each fraction is then summed and converted to an energy value. Nonfiber carbohydrate (NFC) is used in many models. Although it behaves as a nutritionally uniform fraction, it is a heterogeneous mixture of components. To reduce the heterogeneity, we partitioned NFC into starch and residual organic matter (ROM), which is calculated as 100 - CP - LCFA - ash - starch - NDF, where crude protein (CP), long-chain fatty acids (LCFA), ash, starch, and neutral detergent fiber (NDF) are a percentage of DM. However, the true digestibility of ROM is unknown, and because NDF is contaminated with both ash and CP, those components are subtracted twice. The effect of ash and CP contamination of NDF on in vivo digestibility of NDF and ROM was evaluated using data from 2 total-collection digestibility experiments using lactating dairy cows. Digestibility of NDF was greater when it was corrected for ash and CP than without correction. Conversely, ROM apparent digestibility decreased when NDF was corrected for contamination. Although correcting for contamination statistically increased NDF digestibility, the effect was small; the average increase was 3.4%. The decrease in ROM digestibility was 7.4%. True digestibility of ROM is needed to incorporate ROM into summative equations. Data from multiple digestibility experiments (38 diets) using dairy cows were collated, and ROM concentrations were regressed on concentration of digestible ROM (ROM was calculated without adjusting for ash and CP contamination). The estimated true digestibility coefficient of ROM was 0.96 (SE = 0.021), and metabolic fecal ROM was 3.43 g/100 g of dry matter intake (SE = 0.30). Using a smaller data set (7 diets), estimated true digestibility of ROM when calculated using NDF corrected for ash and CP contamination was 0.87 (SE = 0.025), and metabolic fecal ROM was 3.76 g/100 g (SE = 0.60). Regardless of NDF method, ROM exhibited nutritional uniformity. The ROM fraction also had lower errors associated with the estimated true digestibility and its metabolic fecal fraction than did NFC. Therefore, ROM may result in more accurate estimates of available energy if integrated into models. Copyright © 2017 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Effect of aggregate structure on VOC gas adsorption onto volcanic ash soil.

PubMed

Hamamoto, Shoichiro; Seki, Katsutoshi; Miyazaki, Tsuyoshi

2009-07-15

The understanding of the gaseous adsorption process and the parameters of volatile organic compounds such as organic solvents or fuels onto soils is very important in the analysis of the transport or fate of these chemicals in soils. Batch adsorption experiments with six different treatments were conducted to determine the adsorption of isohexane, a gaseous aliphatic, onto volcanic ash soil (Tachikawa loam). The measured gas adsorption coefficient for samples of Tachikawa loam used in the first three treatments, Control, AD (aggregate destroyed), and AD-OMR (aggregate destroyed and organic matter removed), implied that the aggregate structure of volcanic ash soil as well as organic matter strongly enhanced gas adsorption under the dry condition, whereas under the wet condition, the aggregate structure played an important role in gas adsorption regardless of the insolubility of isohexane. In the gas adsorption experiments for the last three treatments, soils were sieved in different sizes of mesh and were separated into three different aggregate or particle size fractions (2.0-1.0mm, 1.0-0.5mm, and less than 0.5mm). Tachikawa loam with a larger size fraction showed higher gas adsorption coefficient, suggesting the higher contributions of macroaggregates to isohexane gas adsorption under dry and wet conditions.

Microstructure Evolution from X-CT Measurements for Concrete/mortar under Multi-actions of Composite Salts Dry-wet Cycles and Loading

NASA Astrophysics Data System (ADS)

Chen, Yanjuan; Gao, Jianming; Shen, Daman

2017-08-01

Inthis research, microstructure evolution forconcrete/mortar under multi-actions of composite salts dry-wet cycles and loading was investigated through X-CT measurements. The evolution process of pores and micro-cracking with the erosion time were tracked. Compared the different erosion actions, it was found that dry-wet cycles promoted the pores become connected gradually. Besides, the dry-wet cycles accelerated the damage seriously on interface area between concrete and aggregate, whistle, loading contributes to the cracking propagation toward the internal. Moreover, fly ash played a positive role in the increasing of the number of harmless holes again and contributed to the durability of concrete.

RESPONSE OF NUTRIENTS, BIOFILM, AND BENTHIC INSECTS TO SALMON CARCASS ADDITION

EPA Science Inventory

Salmon carcass addition to streams is expected to increase stream productivity at multiple trophic levels. This study examined stream nutrient (nitrogen, phosphorus, and carbon), epilithic biofilm (ash-free dry mass and chlorophyll a), leaf-litter decomposition, and macroinverte...

Metals removal from spent salts

DOEpatents

Hsu, Peter C.; Von Holtz, Erica H.; Hipple, David L.; Summers, Leslie J.; Brummond, William A.; Adamson, Martyn G.

2002-01-01

A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

Microscopic evaluation and physiochemical analysis of Dillenia indica leaf

PubMed Central

Kumar, S; Kumar, V; Prakash, Om

2011-01-01

Objective To study detail microscopic evaluation and physiochemical analysis of Dillenia indica (D. indica) leaf. Methods Fresh leaf sample and dried power of the leaf were studied macroscopically and microscopically. Preliminary phytochemical investigation of plant material was done. Other WHO recommended parameters for standardizations were also performed. Results The detail microscopy revealed the presence of anomocytic stomata, unicellular trichome, xylem fibres, calcium oxalate crystals, vascular bundles, etc. Leaf constants such as stomatal number, stomatal index, vein-islet number and veinlet termination numbers were also measured. Physiochemical parameters such as ash values, loss on drying, extractive values, percentage of foreign matters, swelling index, etc. were also determined. Preliminary phytochemical screening showed the presence of steroids, terpenoids, glycosides, fatty acids, flavonoids, phenolic compounds and carbohydrates. Conclusions The microscopic and physiochemical analysis of the D. indica leaf is useful in standardization for quality, purity and sample identification. PMID:23569789

Sulfate resistance of high calcium fly ash concrete

NASA Astrophysics Data System (ADS)

Dhole, Rajaram

Sulfate attack is one of the mechanisms which can cause deterioration of concrete. In general, Class C fly ash mixtures are reported to provide poor sulfate resistance. Fly ashes, mainly those belonging to the Class C, were tested as per the ASTM C 1012 procedure to evaluate chemical sulfate resistance. Overall the Class C fly ashes showed poor resistance in the sulfate environment. Different strategies were used in this research work to improve the sulfate resistance of Class C fly ash mixes. The study revealed that some of the strategies such as use of low W/CM (water to cementing materials by mass ratio), silica fume or ultra fine fly ash, high volumes of fly ash and, ternary or quaternary mixes with suitable supplementary cementing materials, can successfully improve the sulfate resistance of the Class C fly ash mixes. Combined sulfate attack, involving physical and chemical action, was studied using sodium sulfate and calcium sulfate solutions. The specimens were subjected to wetting-drying cycles and temperature changes. These conditions were found to accelerate the rate of degradation of concrete placed in a sodium sulfate environment. W/CM was found to be the main governing factor in providing sulfate resistance to mixes. Calcium sulfate did not reveal damage as a result of mainly physical action. Characterization of the selected fly ashes was undertaken by using SEM, XRD and the Rietveld analysis techniques, to determine the relation between the composition of fly ashes and resistance to sulfate attack. The chemical composition of glass represented on the ternary diagram was the main factor which had a significant influence on the sulfate resistance of fly ash mixtures. Mixes prepared with fly ashes containing significant amounts of vulnerable crystalline phases offered poor sulfate resistance. Comparatively, fly ash mixes containing inert crystalline phases such as quartz, mullite and hematite offered good sulfate resistance. The analysis of hydrated lime-fly ash pastes confirmed that fly ash mortar or concrete mixes forming more monosulfate than ettringite before exposure to sulfates would offer poor sulfate resistance and vice versa. During quantitative Rietveld analysis carried out for determining ettringite, monosulfate and gypsum formed in the fly ash pastes, it was observed that fly ash mixtures showing more ettringite after exposures to sulfates, give poor sulfate resistance. A good relationship between the amounts of ettringite formed and expansions of mortar specimens in the ASTM C 1012 test was found.

Determination of chemical properties in 'calçot' (Allium cepa L.) by near infrared spectroscopy and multivariate calibration.

PubMed

Sans, Silvia; Ferré, Joan; Boqué, Ricard; Sabaté, José; Casals, Joan; Simó, Joan

2018-10-01

'Calçots', the immature floral stems of second-year onion resprouts, are an economically important traditional crop in Catalonia (Spain). Classical approaches to evaluating the chemical properties of 'calçots' are time consuming and expensive; near-infrared spectroscopy (NIRS) may be faster and cheaper. We used NIRS to develop partial least square (PLS) models to predict dry matter, soluble solid content, titratable acidity, and ash content in cooked 'calçots'. To guarantee the robustness of the models, calibration samples were grown and analyzed in a first season (2014-15) and validation samples in a second season (2015-16). NIRS on puree spectra estimated dry matter and soluble solid content with excellent accuracy (R 2 pred  = 0.953, 0.985 and RPD = 4.571, 8.068, respectively). However, good estimation of titratable acidity and ash content required using ground dried puree spectra (R 2 pred  = 0.852, 0.820 and RPD = 2.590, 1.987, respectively). NIRS can be a helpful tool for 'calçots' breeding and quality control. Copyright © 2018 Elsevier Ltd. All rights reserved.

Reuse of thermosetting plastic waste for lightweight concrete.

PubMed

Panyakapo, Phaiboon; Panyakapo, Mallika

2008-01-01

This paper presents the utilization of thermosetting plastic as an admixture in the mix proportion of lightweight concrete. Since this type of plastic cannot be melted in the recycling process, its waste is expected to be more valuable by using as an admixture for the production of non-structural lightweight concrete. Experimental tests for the variation of mix proportion were carried out to determine the suitable proportion to achieve the required properties of lightweight concrete, which are: low dry density and acceptable compressive strength. The mix design in this research is the proportion of plastic, sand, water-cement ratio, aluminum powder, and lignite fly ash. The experimental results show that the plastic not only leads to a low dry density concrete, but also a low strength. It was found that the ratio of cement, sand, fly ash, and plastic equal to 1.0:0.8:0.3:0.9 is an appropriate mix proportion. The results of compressive strength and dry density are 4.14N/mm2 and 1395 kg/m3, respectively. This type of concrete meets most of the requirements for non-load-bearing lightweight concrete according to ASTM C129 Type II standard.

Enzyme activities and substrate degradation during white rot fungi growth on sugar-cane straw in a solid state fermentation.

PubMed

Ortega, G M; Martinez, E O; González, P C; Betancourt, D; Otero, M A

1993-03-01

Two strains of Pleurotus spp., grown in solid state fermentation on sugar-cane straw, degraded the dry matter by 50% after 60 days. The rate of substrate consumption and the dry weight of fruiting bodies decreased in consecutive flushings. Both strains vigorously attacked hemicellulose (80% of total degradation) and lignin (70%). Fruiting bodies were rich in protein and lipids, and had a low content of carbohydrates and ash.

Effects of species and season on chemical composition and ruminal crude protein and organic matter degradability of some multi-purpose tree species by West African dwarf rams.

PubMed

Arigbede, O M; Anele, U Y; Südekum, K-H; Hummel, J; Oni, A O; Olanite, J A; Isah, A O

2012-04-01

Seasonal chemical composition and ruminal organic matter (OM) and crude protein (CP) degradabilities were determined in four tropical multi-purpose tree species (MPTS) namely; Pterocarpus santalinoides, Grewia pubescens, Enterolobium cyclocarpum and Leucaena leucocephala. Three West African dwarf (WAD) rams fitted with permanent rumen cannula were used for the degradability trials. Foliage samples were collected four times to represent seasonal variations as follows: January--mid dry; April--late dry; July--mid rainy and October--late rainy seasons. Leaf samples were randomly collected from the trees for estimation of dry matter (DM) and chemical composition. Ruminal in sacco OM and CP degradabilities were estimated from residues in nylon bags. All samples had high CP (161-259 g/kg DM) and moderate fibre concentrations [neutral detergent fibre (without residual ash], 300-501 g/kg DM; acid detergent fibre (without residual ash), 225-409 g/kg DM and acid detergent lignin, 87-179 g/kg DM across seasons. Interaction effects of species and season on chemical composition were highly significant (p = 0.001) except for trypsin inhibitor (p = 0.614). The MPTS recorded more than 60% OM and CP degradability at 24 h, which implied that they were all highly degradable in the rumen. Their incorporation into ruminant feeding systems as dry season forage supplements is therefore recommended. © 2011 Blackwell Verlag GmbH.

Initial interlaboratory validation of an analytical method for the determination of lead in canned tuna to be used for monitoring and regulatory purposes.

PubMed

Santiago, E C; Bello, F B B

2003-06-01

The Association of Official Analytical Chemists (AOAC) Standard Method 972.23 (dry ashing and flame atomic absorption spectrophotometry (FAAS)), applied to the analysis of lead in tuna, was validated in three selected local laboratories to determine the acceptability of the method to both the Codex Alimentarius Commission (Codex) and the European Union (EU) Commission for monitoring lead in canned tuna. Initial validation showed that the standard AOAC method as performed in the three participating laboratories cannot satisfy the Codex/EU proposed criteria for the method detection limit for monitoring lead in fish at the present regulation level of 0.5 mg x kg(-1). Modification of the standard method by chelation/concentration of the digest solution before FAAS analysis showed that the modified method has the potential to meet Codex/EU criteria on sensitivity, accuracy and precision at the specified regulation level.

Characterisation of agroindustrial solid residues as biofuels and potential application in thermochemical processes.

PubMed

Virmond, Elaine; De Sena, Rennio F; Albrecht, Waldir; Althoff, Christine A; Moreira, Regina F P M; José, Humberto J

2012-10-01

In the present work, selected agroindustrial solid residues from Brazil - biosolids from meat processing wastewater treatment and mixture of sawdust with these biosolids; residues from apple and orange juice industries; sugarcane bagasse; açaí kernels (Euterpe oleracea) and rice husk - were characterised as solid fuels and an evaluation of their properties, including proximate and ultimate composition, energy content, thermal behaviour, composition and fusibility of the ashes was performed. The lower heating value of the biomasses ranged from 14.31 MJkg(-1) to 29.14 MJkg(-1), on a dry and ash free basis (daf), all presenting high volatile matter content, varying between 70.57 wt.% and 85.36 wt.% (daf) what improves the thermochemical conversion of the solids. The fouling and slagging tendency of the ashes was predicted based on the fuel ash composition and on the ash fusibility correlations proposed in the literature, which is important to the project and operation of biomass conversion systems. The potential for application of the Brazilian agroindustrial solid residues studied as alternative energy sources in thermochemical processes has been identified, especially concerning direct combustion for steam generation. Copyright © 2012 Elsevier Ltd. All rights reserved.

Valorization of MSWI bottom ash for biogas desulfurization: Influence of biogas water content.

PubMed

Fontseré Obis, Marta; Germain, Patrick; Troesch, Olivier; Spillemaecker, Michel; Benbelkacem, Hassen

2017-02-01

In this study an alternative valorization of Municipal Solid Waste Incineration (MSWI) Bottom Ash (BA) for H 2 S elimination from landfill biogas was evaluated. Emphasis was given to the influence of water content in biogas on H 2 S removal efficiency by BA. A small-scale pilot was developed and implemented in a landfill site located in France. A new biogas analyzer was used and allowed real-time continuous measurement of CH 4 , CO 2 , O 2 , H 2 S and H 2 O in raw and treated biogas. The H 2 S removal efficiency of bottom ash was evaluated for different inlet biogas humidities: from 4 to 24g water /m 3 . The biogas water content was found to greatly affect bottom ash efficiency regarding H 2 S removal. With humid inlet biogas the H 2 S removal was almost 3 times higher than with a dry inlet biogas. Best removal capacity obtained was 56gH 2 S/kgdryBA. A humid inlet biogas allows to conserve the bottom ash moisture content for a maximum H 2 S retention. Copyright © 2016 Elsevier Ltd. All rights reserved.

Azadirachtin: an effective systemic insecticide for control of Agrilus planipennis (Coleoptera: Buprestidae).

PubMed

McKenzie, Nicole; Helson, Blair; Thompson, Dean; Otis, Gard; McFarlane, John; Buscarini, Teresa; Meating, Joe

2010-06-01

The emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), an invasive pest discovered in North America in 2002, is now well established and threatens ash (Fraxinus spp.) trees throughout the continent. Experiments were conducted to 1) examine the efficacy of an alternative natural pesticide, azadirachtin, to control emerald ash borer, and 2) determine foliar uptake and dissipation patterns after systemic injections of azadirachtin into trunks of small (2.2 cm diameter at breast height [dbh]), uninfested green ash trees. We found no evidence of mortality of adult beetles. In contrast, fewer larvae completed their development at dose levels > or = 1.7 mg (AI)/cm dbh and development ceased beyond the second instar at dose levels > or = 13.6 mg (AI)/cm dbh. Substantial concentrations (11.2 microg/g dry mass [SD = 7.55]) of azadirachtin were present in leaves within 7 d of treatment. After rapid initial uptake, concentrations in leaves declined logarithmically during the 55 d after injection. A similar pattern was observed in a separate experiment that examined the uptake and translocation of azadirachtin in larger green ash trees (22 cm dbh) treated with 250 mg (AI) /cm dbh with the EcoJect injection system. In another experiment, recently infested plantation green ash trees treated with doses > or = 40 mg (AI)/cm dbh had significant reductions in adult emergence approximately 1 yr postinjection. Given the inhibition of larval development, reduction of adult emergence, and the occurrence of foliar residues at biologically active concentrations, we conclude that azadirachtin is effective in protecting ash trees from emerald ash borer.

Chemical and physical properties of dry flue gas desulfurization products.

PubMed

Kost, David A; Bigham, Jerry M; Stehouwer, Richard C; Beeghly, Joel H; Fowler, Randy; Traina, Samuel J; Wolfe, William E; Dick, Warren A

2005-01-01

Beneficial and environmentally safe recycling of flue gas desulfurization (FGD) products requires detailed knowledge of their chemical and physical properties. We analyzed 59 dry FGD samples collected from 13 locations representing four major FGD scrubbing technologies. The chemistry of all samples was dominated by Ca, S, Al, Fe, and Si and strong preferential partitioning into the acid insoluble residue (i.e., coal ash residue) was observed for Al, Ba, Be, Cr, Fe, Li, K, Pb, Si, and V. Sulfur, Ca, and Mg occurred primarily in water- or acid-soluble forms associated with the sorbents or scrubber reaction products. Deionized water leachates (American Society for Testing and Materials [ASTM] method) and dilute acetic acid leachates (toxicity characteristic leaching procedure [TCLP] method) had mean pH values of >11.2 and high mean concentrations of S primarily as SO(2-)4 and Ca. Concentrations of Ag, As, Ba, Cd, Cr, Hg, Pb, and Se (except for ASTM Se in two samples) were below drinking water standards in both ASTM and TCLP leachates. Total toxicity equivalents (TEQ) of dioxins, for two FGD products used for mine reclamation, were 0.48 and 0.53 ng kg(-1). This was similar to the background level of the mine spoil (0.57 ng kg(-1)). The FGD materials were mostly uniform in particle size. Specific surface area (m2 g(-1)) was related to particle size and varied from 1.3 for bed ash to 9.5 for spray dryer material. Many of the chemical and physical properties of these FGD samples were associated with the quality of the coal rather than the combustion and SO2 scrubbing processes used.

The impact of using chickpea flour and dried carp fish powder on pizza quality.

PubMed

El-Beltagi, Hossam S; El-Senousi, Naglaa A; Ali, Zeinab A; Omran, Azza A

2017-01-01

Pizza being the most popular food worldwide, quality and sensory appeal are important considerations during its modification effort. This study was aimed to evaluate the quality of pizza made using two different sources of proteins, chickpea (Cicer arietinum) flour and dried carp fish powder (Cyprinus carpio). Analysis indicated nutrients richness specificity of chickpea flour (higher fiber, energy, iron, zinc, linoleic acid and total nonessential amino acids) and dried carp fish powder (higher contents of protein, fats, ash, oleic acid and total essential amino acids) complementing wheat flour to enhance nutritional value of pizza. Total plate count and thiobarbituric acid were increased (P<0.05) in dried carp fish powder after 45 days of storage, but no Coliform were detected. Wheat flour was substituted with 5, 7.5 and 10% chickpea flour or dried carp fish powder and chemical, textural, sensory and storage evaluation parameters of in pizza were investigated. Dried carp fish powder increased (P<0.05) contents of protein, ash, fats, zinc and protein digestibility of pizza. Chickpea flour increased iron and zinc contents of the pizza. Water activity (aw) was decreased in fish powder and chickpea pizza. Pizza firmness and gumminess were significantly (p<0.05) increased at every level of protein source, but cohesiveness was decreased with 10% chickpea flour. Pizza chewiness was the same (P>0.05) across the levels of two protein sources. Springiness was decreased (P<0.05) with high level (10%) dried fish powder and low/intermediate level of chickpea flour. Chickpea and dried carp fish incorporation up to 7.50% in pizza at the expense of wheat flour had no effect (P>0.05) on all sensorial parameters except for odor values. The results could be useful in utilization of chickpea flour and carp fish powder in designing nutritious pizza for consumers.

The impact of using chickpea flour and dried carp fish powder on pizza quality

PubMed Central

El-Senousi, Naglaa A.; Ali, Zeinab A.; Omran, Azza A.

2017-01-01

Pizza being the most popular food worldwide, quality and sensory appeal are important considerations during its modification effort. This study was aimed to evaluate the quality of pizza made using two different sources of proteins, chickpea (Cicer arietinum) flour and dried carp fish powder (Cyprinus carpio). Analysis indicated nutrients richness specificity of chickpea flour (higher fiber, energy, iron, zinc, linoleic acid and total nonessential amino acids) and dried carp fish powder (higher contents of protein, fats, ash, oleic acid and total essential amino acids) complementing wheat flour to enhance nutritional value of pizza. Total plate count and thiobarbituric acid were increased (P<0.05) in dried carp fish powder after 45 days of storage, but no Coliform were detected. Wheat flour was substituted with 5, 7.5 and 10% chickpea flour or dried carp fish powder and chemical, textural, sensory and storage evaluation parameters of in pizza were investigated. Dried carp fish powder increased (P<0.05) contents of protein, ash, fats, zinc and protein digestibility of pizza. Chickpea flour increased iron and zinc contents of the pizza. Water activity (aw) was decreased in fish powder and chickpea pizza. Pizza firmness and gumminess were significantly (p<0.05) increased at every level of protein source, but cohesiveness was decreased with 10% chickpea flour. Pizza chewiness was the same (P>0.05) across the levels of two protein sources. Springiness was decreased (P<0.05) with high level (10%) dried fish powder and low/intermediate level of chickpea flour. Chickpea and dried carp fish incorporation up to 7.50% in pizza at the expense of wheat flour had no effect (P>0.05) on all sensorial parameters except for odor values. The results could be useful in utilization of chickpea flour and carp fish powder in designing nutritious pizza for consumers. PMID:28873098

Effects of Mechanically Deboned Chicken Meat (MDCM) and Collagen on the Quality Characteristics of Semi-dried Chicken Jerky

PubMed Central

Song, Dong-Heon; Choi, Ji-Hun; Choi, Yun-Sang; Kim, Hyun-Wook; Hwang, Ko-Eun; Kim, Yong-Jae; Ham, Youn-Kyung; Kim, Cheon-Jei

2014-01-01

This study was conducted to determine the effects of using mechanically deboned chicken meat (MDCM) and collagen on quality characteristics of semi-dried chicken jerky. In experiment I, semi-dried chicken jerky was prepared with the replacement of chicken breast with MDCM (0, 10, 20, and 30%). The pH value of the jerky formulated with only chicken breast was 5.94, while the replacement of chicken breast with MDCM significantly increased the pH (p<0.05). The protein content and shear force of the jerkies decreased with increasing amounts of MDCM, whereas the fat, ash content and processing yield showed the opposite tendency (p<0.05). Replacement with up to 10% MDCM had no adverse effects on the sensory characteristics of the semi-dried chicken jerky. In experiment II, four levels of pork collagen (0, 1, 2, and 3%) were added to the semi-dried chicken jerky formulated with 90% chicken breast and 10% MDCM. The addition of collagen increased the moisture content, but decreased the ash content of the jerkies produced (p<0.05). The processing yield of the jerkies increased with increasing added amounts of collagen (p<0.05). It was found that the jerkies formulated with 0-2% collagen had significantly higher overall acceptance score than those prepared with 3% collagen (p<0.05). In conclusion, MDCM and collagen could be useful ingredients to reduce the production cost and improve the processing yield of semi-dried chicken jerky. The optimal levels of MDCM and collagen which could be added without adverse effects on the sensory characteristics were up to 10% and 2%, respectively. PMID:26761667

Proximate composition and energy density of some North Pacific forage fishes

USGS Publications Warehouse

van Pelt, Thomas I.; Piatt, John F.; Lance, Brian K.; Roby, Daniel D.

1997-01-01

Mature pelagic forage fish species (capelin, sand lance, squid) had greater lipid concentrations than juvenile age-classes of large demersal and pelagic fish species (walleye pollock, Pacific cod, Atka mackerel, greenling, prowfish, rockfish, sablefish). Myctophids preyed on by puffins have at least twice as much lipid per gram compared to mature capelin, sand lance and squid, and an order of magnitude greater lipid concentrations than juvenile forage fish. Energy density of forage fishes was positively correlated with lipid content, and negatively correlated with water, ash-free lean dry mass (mostly protein), and ash contents.

Evaluation of coalbed gas potential of the Seelyville Coal Member, Indiana, USA

USGS Publications Warehouse

Drobniak, A.; Mastalerz, Maria; Rupp, J.; Eaton, N.

2004-01-01

The Seelyville Coal Member of the Linton Formation in Indiana potentially contains 0.03 trillion m3 (1.1 TCF) of coalbed gas. The gas content determined by canister desorption technique ranges from 0.5 to 5.7 cm3/g on dry ash free basis (15.4 to 182.2 scf/ton). The controls on gas content distribution are complex, and cannot be explained by the coal rank alone. Ash content and the lithology of the overlying strata, among other factors, may influence this distribution. ?? 2004 Elsevier B.V. All rights reserved.

Quantity, composition and water contamination potential of ash produced under different wildfire severities.

PubMed

Santín, Cristina; Doerr, Stefan H; Otero, Xosé L; Chafer, Chris J

2015-10-01

Wildfires frequently threaten water quality through the transfer of eroded ash and soil into rivers and reservoirs. The ability to anticipate risks for water resources from wildfires is fundamental for implementing effective fire preparedness plans and post-fire mitigation measures. Here we present a new approach that allows quantifying the amount and characteristics of ash generated under different wildfire severities and its respective water contamination potential. This approach is applied to a wildfire in an Australian dry sclerophyll eucalypt forest, but can be adapted for use in other environments. The Balmoral fire of October 2013 affected 12,694 ha of Sydney's forested water supply catchment. It produced substantial ash loads that increased with fire severity, with 6, 16 and 34 Mg ha(-1) found in areas affected by low, high and extreme fire severity, respectively. Ash bulk density was also positively related to fire severity. The increase with fire severity in the total load and bulk density of the ash generated is mainly attributed to a combination of associated increases in (i) total amount of fuel affected by fire and (ii) contribution of charred mineral soil to the ash layer. Total concentrations of pollutants and nutrients in ash were mostly unrelated to fire severity and relatively low compared to values reported for wildfire ash in other environments (e.g. 4.0-7.3mg As kg(-1); 2.3-4.1 B mg kg(-1); 136-154 P mg kg(-1)). Solubility of the elements analysed was also low, less than 10% of the total concentration for all elements except for B (6-14%) and Na (30-50%). This could be related to a partial loss of soluble components by leaching and/or wind erosion before the ash sampling (10 weeks after the fire and before major ash mobilisation by water erosion). Even with their relatively low concentrations of potential pollutants, the substantial total ash loads found here represent a water contamination risk if transported into the hydrological network during severe erosion events. For example, up to 4 Mg of ash-derived P could be delivered into a single water supply reservoir. Copyright © 2015 Elsevier Inc. All rights reserved.

Probabilistic detection of volcanic ash using a Bayesian approach

PubMed Central

Mackie, Shona; Watson, Matthew

2014-01-01

Airborne volcanic ash can pose a hazard to aviation, agriculture, and both human and animal health. It is therefore important that ash clouds are monitored both day and night, even when they travel far from their source. Infrared satellite data provide perhaps the only means of doing this, and since the hugely expensive ash crisis that followed the 2010 Eyjafjalljökull eruption, much research has been carried out into techniques for discriminating ash in such data and for deriving key properties. Such techniques are generally specific to data from particular sensors, and most approaches result in a binary classification of pixels into “ash” and “ash free” classes with no indication of the classification certainty for individual pixels. Furthermore, almost all operational methods rely on expert-set thresholds to determine what constitutes “ash” and can therefore be criticized for being subjective and dependent on expertise that may not remain with an institution. Very few existing methods exploit available contemporaneous atmospheric data to inform the detection, despite the sensitivity of most techniques to atmospheric parameters. The Bayesian method proposed here does exploit such data and gives a probabilistic, physically based classification. We provide an example of the method's implementation for a scene containing both land and sea observations, and a large area of desert dust (often misidentified as ash by other methods). The technique has already been successfully applied to other detection problems in remote sensing, and this work shows that it will be a useful and effective tool for ash detection. Key Points Presentation of a probabilistic volcanic ash detection scheme Method for calculation of probability density function for ash observations Demonstration of a remote sensing technique for monitoring volcanic ash hazards PMID:25844278

Linking hydraulic properties of fire-affected soils to infiltration and water repellency

USGS Publications Warehouse

Moody, John A.; David Kinner,; Xavier Úbeda,

2009-01-01

Heat from wildfires can produce a two-layer system composed of extremely dry soil covered by a layer of ash, which when subjected to rainfall, may produce extreme floods. To understand the soil physics controlling runoff for these initial conditions, we used a small, portable disk infiltrometer to measure two hydraulic properties: (1) near-saturated hydraulic conductivity, Kf and (2) sorptivity, S(θi), as a function of initial soil moisture content, θi, ranging from extremely dry conditions (θi < 0.02 cm3 cm−3) to near saturation. In the field and in the laboratory replicate measurements were made of ash, reference soils, soils unaffected by fire, and fire-affected soils. Each has a different degrees of water repellency that influences Kf and S(θi).Values of Kf ranged from 4.5 × 10−3 to 53 × 10−3 cm s−1 for ash; from 0.93 × 10−3 to 130 × 10−3 cm s−1 for reference soils; and from 0.86 × 10−3 to 3.0 × 10−3 cm s−1, for soil unaffected by fire, which had the lowest values of Kf. Measurements indicated that S(θi) could be represented by an empirical non-linear function of θi with a sorptivity maximum of 0.18–0.20 cm s−0.5, between 0.03 and 0.08 cm3 cm−3. This functional form differs from the monotonically decreasing non-linear functions often used to represent S(θi) for rainfall–runoff modeling. The sorptivity maximum may represent the combined effects of gravity, capillarity, and adsorption in a transitional domain corresponding to extremely dry soil, and moreover, it may explain the observed non-linear behavior, and the critical soil-moisture threshold of water repellent soils. Laboratory measurements of Kf and S(θi) are the first for ash and fire-affected soil, but additional measurements are needed of these hydraulic properties for in situ fire-affected soils. They provide insight into water repellency behavior and infiltration under extremely dry conditions. Most importantly, they indicate how existing rainfall–runoff models can be modified to accommodate a possible two-layer system in extremely dry conditions. These modified models can be used to predict floods from burned watersheds under these initial conditions.

Comparison of methods for the removal of organic carbon and extraction of chromium, iron and manganese from an estuarine sediment standard and sediment from the Calcasieu River estuary, Louisiana, U.S.A.

USGS Publications Warehouse

Simon, N.S.; Hatcher, S.A.; Demas, C.

1992-01-01

U.S. National Bureau of Standards (NBS) estuarine sediment 1646 from the Chesapeake Bay, Maryland, and surface sediment collected at two sites in the Calcasieu River estuary, Louisiana, were used to evaluate the dilute hydrochloric acid extraction of Cr, Fe and Mn from air-dried and freeze-dried samples that had been treated by one of three methods to remove organic carbon. The three methods for the oxidation and removal of organic carbon were: (1) 30% hydrogen peroxide; (2) 30% hydrogen peroxide plus 0.25 mM pyrophosphate; and (3) plasma oxidation (low-temperature ashing). There was no statistically significant difference at the 95% confidence level between air- and freeze-dried samples with respect to the percent of organic carbon removed by the three methods. Generally, there was no statistically significant difference at the 95% confidence level between air- and freeze-dried samples with respect to the concentration of Cr, Fe and Mn that was extracted, regardless of the extraction technique that was used. Hydrogen peroxide plus pyrophosphate removed the most organic carbon from sediment collected at the site in the Calcasieu River that was upstream from industrial outfalls. Plasma oxidation removed the most organic carbon from the sediment collected at a site in the Calcasieu River close to industrial outfalls and from the NBS estuarine sediment sample. Plasma oxidation merits further study as a treatment for removal of organic carbon. Operational parameters can be chosen to limit the plasma oxidation of pyrite which, unlike other Fe species, will not be dissolved by dilute hydrochloric acid. Preservation of pyrite allows the positive identification of Fe present as pyrite in sediments. ?? 1992.

Timing of Getter Material Addition in Cementitious Wasteforms

NASA Astrophysics Data System (ADS)

Lawter, A.; Qafoku, N. P.; Asmussen, M.; Neeway, J.; Smith, G. L.

2015-12-01

A cementitious waste form, Cast Stone, is being evaluated as a possible supplemental immobilization technology for the Hanford sites's low activity waste (LAW), which contains radioactive 99Tc and 129I, as part of the tank waste cleanup mission. Cast Stone is made of a dry blend 47% blast furnace slag, 45% fly ash, and 8% ordinary Portland cement, mixed with a low-activity waste (LAW). To improve the retention of Tc and/or I in Cast Stone, materials with a high affinity for Tc and/or I, termed "getters," can be added to provide a stable domain for the radionuclides of concern. Previous testing conducted with a variety of getters has identified Tin(II)-Apatite and Silver Exchanged Zeolite as promising candidates for Tc and I, respectively. Investigation into the sequence in which getters are added to Cast Stone was performed following two methods: 1) adding getters to the Cast Stone dry blend, and then mixing with liquid waste, and 2) adding getters to the liquid waste first, followed by addition of the Cast Stone dry blend. Cast Stone monolith samples were prepared with each method and leach tests, following EPA method 1315, were conducted in either distilled water or simulated vadose zone porewater for a period of up to 63 days. The leachate was analyzed for Tc, I, Na, NO3-, NO2- and Cr with ICP-MS, ICP-OES and ion chromatography and the results indicated that the Cast Stone with getter addition in the dry blend mix (method 1) has lower rates of Tc and I leaching. The mechanisms of radionuclide release from the Cast Stone were also investigated with a variety of solid phase characterization techniques of the monoliths before and after leaching, such as XRD, SEM/EDS, TEM/SAED and other spectroscopic techniques.

Effect of municipal solid waste incinerator types on characteristics of ashes from different air pollution control devices.

PubMed

Lu, Chien-Hsing; Chuang, Kui-Hao

2016-01-01

The purpose of this paper is to investigate the characteristics of fly and bottom ashes sampled from both fluidized bed (FB) and mass-burning (MB) municipal solid waste incinerators (MSWIs), respectively. Fly ashes from different locations at FB and MB MSWIs equipped with a cyclone, a semi-dry scrubber, and a bag filter as air pollution control devices were examined to provide the baseline information between physicochemical properties and leaching ability. Experimental results of leachability indicated that the bag filter fly ash (FB-FA(B)) from the FB incinerator meets Taiwan regulatory standards set through the toxicity characteristic leaching procedure. X-ray diffraction results revealed the presence of Cr5O12 and Pb2O3 in the cyclone fly ash (MB-FA(C)) and bag filter fly ash (MB-FA(B)), respectively, from the MB incinerator. To observe lead incorporation mechanism, mixture of simulate lead-laden waste with bed material were fired between 600 °C and 900 °C in a laboratory scale FB reactor. The results clearly demonstrate a substantial decrease in lead leaching ratio for products with an appropriate temperature. The concentration of Pb in the MB-FA(B) was 250 times that in the FB-FA(B), suggesting that incineration of MSW in FB is a good strategy for stabilizing hazardous metals.

DISPOSAL OF FLUE-GAS-CLEANING WASTES

EPA Science Inventory

The article describes current commercial and emerging technology for disposal of wastes from flue gas cleaning (FGC) systems for coal-fired power plants. Over 80 million metric tons/yr (dry) of coal ash and desulfurization solids are expected to be produced by the 1980's. Althoug...

Inclusion of geopolymers derivate from fly ash and pumice in reinforced concrete

NASA Astrophysics Data System (ADS)

Montaño, A. M.; González, C. P.; Castro, D.; Gualdron, G.; Atencio, R.

2017-12-01

This paper presents results of a research project related to the development of alkali-activated geopolymers, synthesized from alumina-silicate minerals (fly ash and pumice) which are added to concrete. Alkali sources used in geopolymer synthesis were sodium hydroxide and sodium silicate solution. New materials were structurally characterized by Infra-Red spectroscopy (IR) and X-Ray Diffraction (XRD). Concretes obtained after geopolymers addition as Portland cement substitutes at 10%, 20% and 30%, were mechanically analysed by compression resistance at 7, 14, 28 and 90 drying days. Results were referred to standard (concrete of Portland cement) allows to know cementitious characteristics of geopolymers are lower than those for standard, but it keeps growing at longer drying time than Portland cement. By Electrochemical Impedance Spectroscopy (EIS) it is found that this new material shows high electrical resistance and have been proved as a protection agent against corrosion in reinforced concrete exhibiting anticorrosive properties higher than those showed by the conventional concrete mixture.

Chemical, rheological and bread making characteristics of bran duster flours from roller flourmills.

PubMed

Sakhare, Suresh D; Indrani, D; Inamdar, Aashitosh A; Gaikwad, Shwetha B; Rao, G Venkateswara

2014-10-01

Bran dusters are used in the wheat flour milling process to increase flour extraction rate. Chemical, rheological and bread characteristics of bran duster flours (BDR1, BDR2, BDR3) and straight run flour (SRF) obtained from two commercial roller flour mills were analyzed. Important chemical characteristics such as ash, dry gluten content, sedimentation value, damaged starch and falling number of bran duster flours were determined. Rheological behavior was tested using farinograph and alveograph equipments. The results showed an increase in ash, dry gluten content and Zeleny's sedimentation value for bran duster flours compared to SRF. Rheological characteristics indicated higher farinograph dough development time and stability values for bran duster flours. Alveograph characteristics indicated higher extensibility and lower elasticity values for bran duster flours. Over all quality score of bread for BDR1 from A and B roller flour mills ranged from 73.4 to 74.7, BDR2 (79-81.8), BDR3 (69-70.4) as against SRF (85.4-86.3).

Comparative study of wet and dry torrefaction of corn stalk and the effect on biomass pyrolysis polygeneration.

PubMed

Wang, Xianhua; Wu, Jing; Chen, Yingquan; Pattiya, Adisak; Yang, Haiping; Chen, Hanping

2018-06-01

Wet torrefaction (WT) possesses some advantages over dry torrefaction (DT). In this study, a comparative analysis of torrefied corn stalk from WT and DT was conducted along with an investigation of their pyrolysis properties under optimal conditions for biomass pyrolysis polygeneration. Compared with DT, WT removed 98% of the ash and retained twice the amount of hydrogen. The impacts of DT and WT on the biomass macromolecular structure was also found to be different using two-dimensional perturbation correlation infrared spectroscopy (2D-PCIS). WT preserved the active hydroxyl groups and rearranged the macromolecule structure to allow cellulose to be more ordered, while DT removed these active hydroxyl groups and formed inter-crosslinking structures in macromolecules. Correspondingly, the bio-char yield after WT was lower than DT but the bio-char quality was upgraded due to high ash removal. Furthermore, higher bio-oil yield, higher sugar content, and higher H 2 generation, were obtained after WT. Copyright © 2018 Elsevier Ltd. All rights reserved.

Probabilistic detection of volcanic ash using a Bayesian approach

NASA Astrophysics Data System (ADS)

Mackie, Shona; Watson, Matthew

2014-03-01

Airborne volcanic ash can pose a hazard to aviation, agriculture, and both human and animal health. It is therefore important that ash clouds are monitored both day and night, even when they travel far from their source. Infrared satellite data provide perhaps the only means of doing this, and since the hugely expensive ash crisis that followed the 2010 Eyjafjalljökull eruption, much research has been carried out into techniques for discriminating ash in such data and for deriving key properties. Such techniques are generally specific to data from particular sensors, and most approaches result in a binary classification of pixels into "ash" and "ash free" classes with no indication of the classification certainty for individual pixels. Furthermore, almost all operational methods rely on expert-set thresholds to determine what constitutes "ash" and can therefore be criticized for being subjective and dependent on expertise that may not remain with an institution. Very few existing methods exploit available contemporaneous atmospheric data to inform the detection, despite the sensitivity of most techniques to atmospheric parameters. The Bayesian method proposed here does exploit such data and gives a probabilistic, physically based classification. We provide an example of the method's implementation for a scene containing both land and sea observations, and a large area of desert dust (often misidentified as ash by other methods). The technique has already been successfully applied to other detection problems in remote sensing, and this work shows that it will be a useful and effective tool for ash detection.

Extraction of mineral elements from inedible wastes of biological components of a life-support system and their utilization for plant nutrition

NASA Astrophysics Data System (ADS)

Gribovskaya, I. V.; Gladchenko, I. A.; Zinenko, G. K.

Two methods of extracting mineral elements from otherwise deadlock products of a life-support system are presented. We describe first optimum conditions for recovering elements by water extraction from dry wastes of plants, biomass ash, and solid human wastes after passing them through the catalytic furnace; and, second, we describe acid extracts of biogenous elements by 1N and 2N HNO_3 from these products. Ways to use the extracts of elements in plant nutrition are considered in order to increase the extent to which the mineral loop of a life-support system can be closed.

Comparing Two Independent Satellite-Based Algorithms for Detecting and Tracking Ash Clouds by Using SEVIRI Sensor.

PubMed

Falconieri, Alfredo; Cooke, Michael C; Filizzola, Carolina; Marchese, Francesco; Pergola, Nicola; Tramutoli, Valerio

2018-01-27

The Eyjafjallajökull (Iceland) volcanic eruption of April-May 2010 caused unprecedented air-traffic disruption in Northern Europe, revealing some important weaknesses of current operational ash-monitoring and forecasting systems and encouraging the improvement of methods and procedures for supporting the activities of Volcanic Ash Advisory Centers (VAACs) better. In this work, we compare two established satellite-based algorithms for ash detection, namely RST ASH and the operational London VAAC method, both exploiting sensor data of the spinning enhanced visible and infrared imager (SEVIRI). We analyze similarities and differences in the identification of ash clouds during the different phases of the Eyjafjallajökull eruption. The work reveals, in some cases, a certain complementary behavior of the two techniques, whose combination might improve the identification of ash-affected areas in specific conditions. This is indicated by the quantitative comparison of the merged SEVIRI ash product, achieved integrating outputs of the RST ASH and London VAAC methods, with independent atmospheric infrared sounder (AIRS) DDA (dust-detection algorithm) observations.

Electrodialytic remediation of municipal solid waste incineration residues using different membranes.

PubMed

Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M

2017-02-01

In the present work, three different commercial membrane brands were used in an identical electrodialytic cell setup and operating conditions, in order to reduce the leaching of metals and salt anions of two types of municipal solid waste incineration residues: air pollution control residues of a semi-dry flue-gas cleaning system and fly ashes from a plant with wet flue-gas cleaning system. The results showed a general reduction of the leaching in both residues after ED remediation. For the following elements, the leaching was found to be different after ED treatment depending on the membrane used, with statistical significance: • Air pollution control residues of the semi-dry flue-gas cleaning system: Cr, Cu, Ni, Pb, Zn; • Fly ashes from a plant with wet flue-gas cleaning system: Al, Ba, Cu, Ni, Zn, Cl, SO 4 . Final leaching values for some elements and membranes, but not the majority, were below than those of certified coal fly ash (e.g. Al or Cr), a material which is commonly used in construction materials; at the same time, some of these values were reduced to below the Danish law thresholds on the use of contaminated soil in constructions. These results show the potential of ED as a technology to upgrade municipal solid waste incineration residues. Copyright © 2016 Elsevier Ltd. All rights reserved.

The Ash that Closed Europe's Airspace in 2010

NASA Astrophysics Data System (ADS)

Gislason, S. R.; Alfredsson, H.; Olsson, J.; Eiriksdottir, E.; Oskarsson, N.; Hassenkam, T.; Nedel, S.; Bovet, N.; Hem, C.; Balogh, Z.; Dideriksen, K.; Stipp, S. L.

2011-12-01

On 14 April 2010, when meltwater from the Eyjafjallajökull glacier mixed with hot magma, an explosive phreato-magmatic eruption sent unusually fine-grained ash into the jet stream. It quickly dispersed over Europe. Previous airplane encounters with ash had caused sand blasted windows and particles melted inside jet engines, causing them to fail. Therefore, air traffic was grounded for several days. Concerns also arose about health risks from fallout, because ash can transport acids as well as toxic compounds. Studies on ash are usually made on material collected far from the source, where it could have mixed with other atmospheric particles, or after exposure to water as rain or fog, which would alter surface composition. In this study, a unique set of dry ash samples was collected during the explosive eruption and compared with fresh ash with the same bulk composition from a later more typical magmatic event, when meltwater did not have access to the magma.[1] Up to 70 mass % of the phreato-magmatic ash particles, collected 60 km from the source, was <60 μm in diameter, 22% was <10 μm and 11% was ≤ 4.4 μm. The finest grain size was found in the centre of the "collapsed" plume. The magmatic ash was coarser and its surface area was an order of magnitude smaller than for the explosive ash. The relative concentration of surface salts down to 10 nm depth was significantly lower on the explosive ash than the magmatic ash, because less volatile compounds were available to condense on the surfaces when water and steam were present. Instead, they dissolved in the meltwater and were transported as solutes in the ensuing floodwaters. The surface salts dissolved rapidly when exposed to experimental and natural waters, releasing pollutants and nutrients. Some of the salts further enhanced bulk dissolution of the ash. The particles of phreato-magmatic ash that reached Europe in the jet stream were especially sharp and hard, therefore abrasive, over their entire size range, from submillimeter to tens of nanometers. Edges remained sharp, even after 2 weeks of abrasion in stirred water suspensions. From the composition of the particles, we could predict that they would soften and melt at the temperatures typical of a jet engine (1500 to 2000 °C). [1] Gislason S.R. et al. (2011), PNAS, 108, 7307-7312

Coal ash in Israel: Natural resource or environmental hazard

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheps, S.; Davidi, S.; Cohen, H.

1997-12-31

Coal combustion in Israeli power plants produces 1,000,000 tonnes of ash annually. Most of the ash (55%) is used as cement additive. Since the expansion of coal combustion is much faster than the development of cement production, large amounts of fly ash are expected to accumulate in the next decade. Thus the environmental problem may be exacerbated if other means of utilization (e. g. embankments and marine reclamation or utilization as a chemical reagent) will not be possible in the future. Unlike other countries overseas, coal ash is defined in Israel as hazardous material, thus any disposal or utilization schememore » requires a special permit. The main concern is that pollution from the ash will leach out and contaminate the proximal ground water. The authors have decided to check the leaching behavior of South-African and Colombian fly ashes (the most abundant in Israel) using the following methods: (a) the improved EPA-TCLP 1311 (used in the US); (b) the EU-CEN/TC292/WG2 (declared recently as the method in the European Community); and (c) the NVN2508 method. The first two methods are batch methods and the third a flow through column method. The main constituents of the ash are listed along with the trace elements found. It has been observed that no appreciable amount of most trace elements are dissolved from the ash except that of chromium which exceeds the drinking water limits. Furthermore most of the leached chromium is in the hexavalent form which is considered as carcinogenic. The effect of different parameters and the risk involved in leaching out of trace elements from the fly ash to the underground water aquifer will be discussed in detail.« less

Forty years of vegetation change on the Missouri River floodplain

USGS Publications Warehouse

Johnson, W. Carter; Dixon, Mark D.; Scott, Michael L.; Rabbe, Lisa; Larson, Gary; Volke, Malia; Werner, Brett

2012-01-01

Comparative inventories in 1969 and 1970 and in 2008 of vegetation from 30 forest stands downstream of Garrison Dam on the Missouri River in central North Dakota showed (a) a sharp decline in Cottonwood regeneration; (b) a strong compositional shift toward dominance by green ash; and (c) large increases in invasive understory species, such as smooth brome, reed canary grass, and Canada thistle. These changes, and others discovered during remeasurement, have been caused by a complex of factors, some related to damming (altered hydrologic and sediment regimes, delta formation, and associated wet-dry cycles) and some not (diseases and expansion of invasive plants). Dominance of green ash, however, may be short lived, given the likelihood that the emerald ash borer will arrive in the Dakotas in 5-10 years, with potentially devastating effects. The prospects for recovery of this valuable ecosystem, rich in ecosystem goods and services and in American history, are daunting.

Cadmium contamination of wood ash and fire-treated coniferous humus: Effect on soil respiration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fritze, H.; Kapanen, A.; Vanhala, P.

Atmospheric acidic deposition is known to affect soil fertility and in many countries, liming has been used to counteract anthropogenic soil acidification in coniferous forest soils. Other measures used to improve the acid neutralization capacity of forest soils are wood ash application and prescribed burning. In both cases, ash is deposited on the forest floor, resulting in a pH increase in the humus layer. Currently, application of forests with wood ash is under discussion in Finland, since the naturally occurring cadmium of forest trees is concentrated into the wood ash which then contains between 4 and 20 {mu} g{sup {minus}1}more » of dry matter. Microbes are essential for maintaining soil fertility and plant growth because they play a fundamental role in nutrient availability. Soil respiration rate, which is an indicator of the microbially-mediated nutrient turnover rate, is decreased by addition of cadmium to the soil environment. In this paper we report on the effects of cadmium addition on the soil respiration rate of forest humus having received wood ash or fire treatments. The underlying objectives of this study were: (i) to determine the cadmium level which decreases the soil respiration of a Vaccinium site type forest humus to half of its original value (EC{sub 50}), (ii) to estimate how the forest treatments influence the EC{sub 50}, and (iii) to discuss the effect of Cd addition provided by wood ash on the nutrient mineralization rate. 17 refs., 2 figs., 2 tabs.« less

Effect of bacterial inoculants on phytomining of metals from waste incineration bottom ash.

PubMed

Rosenkranz, Theresa; Kidd, Petra; Puschenreiter, Markus

2018-03-01

Waste incineration bottom ash is considered a secondary resource for valuable trace elements (TE), which is currently neglected in most European countries. Phytomining could potentially recover valuable TE from such waste materials but is still at an exploratory stage with many challenges. The use of bioaugmentation to improve plant growth and TE accumulation of metal-tolerant high biomass plants growing on waste incineration bottom ash was evaluated. Bacterial strains that were previously isolated from rhizosphere, roots and contaminated soil were selected according to their plant growth promoting characteristics and tolerance to the bottom ash substrate. Those selected bacterial strains were tested for their beneficial effects on Nicotiana tabacum and Salix smithiana with regards to phytomining. The rhizobacterial strain Rhodococcus erythropolis P30 enhanced the shoot dry weight of N. tabacum by on average 57% compared to the control plants. Several bacterial inoculants enhanced biomass production and the nutritional status of S. smithiana. Moreover, those bacterial strains previously described to enhance biomass production of N. tabacum and members of the Salicaceae on TE-contaminated soils, also enhanced biomass production of these species on bottom ash. However, bacterial inoculants could not enhance trace element accumulation in plants. Copyright © 2017 Elsevier Ltd. All rights reserved.

Significance of various soil amendments to borrow pit reclamation with loblolly pine and fescue

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berry, C.R.; Marx, D.H.

Loblolly pine seedlings with ectomycorrhizae formed by Pisolithus tinctorius (Pt) or naturally occurring Thelephora terrestris (Tt) were planted on a borrow pit in South Carolina in plots with no amendment; with fertilizer plus dolomitic limestone alone and with pine bark or bottom ash or bark and ash together; or with dried sewage sludge alone and with bark or ash or bark and ash together. All plots were subsoiled, disked, and seeded to fescue grass before planting pine seedlings. Naturally occurring Pt formed abundant ectomycorrhizae on all Tt seedlings by the end of the first season, precluding any specific ectomycorrhizal fungusmore » effect for the duration of the study. Sewage sludge alone or with bark or ash amendments dramatically improved pine seedling growth and grass biomass in comparison with other soil treatments. Mean seedling volume (D/sup 2/H) was 28 times greater and grass biomass was five times greater in the sludge plots than on nonsludge plots. Generally, soil amended with sludge contained more N, P, organic matter, and had a higher cation exchange capacity than soil of other treatments. Foliage of pine seedlings in sludge-amended soil also contained more N and less Ca than other seedlings. The significance of these results to reclamation of borrow pits is discussed.« less

Parameters Affecting the Mechanical Properties of Fly Ash-Based Geopolymer Binders – Experimental Results

NASA Astrophysics Data System (ADS)

Lăzărescu, A.; Szilagyi, H.; Ioani, A.; Baeră, C.

2018-06-01

As the demand for concrete and the needs to satisfy development of infrastructure facilities increase, it is essential to find alternatives to create environment-friendly concrete. The particular procedure of alkaline activation of fly ash - in which ash resulting from a power plant is combined with a specific alkaline activator in order to create a solid material, then dried at a certain temperature - opened new opportunities for this new material to get attention worldwide. In order to obtain a material with similar properties of ordinary Portland cement concrete and to obtain desirable compressive strengths, the parameters that affect this type of binders should be fully understood. The aim of this paper is to study the main parameters affecting the mechanical strength of the fly ash-based geopolymer paste and their interactions. Parameters such as molarity of sodium hydroxide (from 8M to 12M) and alkaline activators ratio (from 0,5 to 2,5) were analysed to observe how they affect the mechanical properties of the geopolymer paste. Experimental results show that the compressive strength of the fly ash-based geopolymer paste produced using Romanian local raw materials increases with the increase of the concentration of sodium hydroxide and higher ratios of Na2SiO3/NaOH solution.

Phosphorus bioavailability, true metabolizable energy, and amino acid digestibilities of high protein corn distillers dried grains and dehydrated corn germ.

PubMed

Kim, E J; Amezcua, C Martinez; Utterback, P L; Parsons, C M

2008-04-01

There is currently much ongoing research and interest for developing new processing technologies to produce corn distillers dried grains with solubles (DDGS). The current study evaluated a high protein (HP) distillers dried grains (DDG) and a dehydrated corn germ, which are products that can be produced by a modified dry milling process. Two chick experiments were conducted to determine the P bioavailability based on tibia ash. In addition, precision-fed rooster assays were conducted to determine TME(n) and amino acid digestibility. In the first chick assay, a P-deficient cornstarch-dextrose-soybean meal basal diet containing 0.10 to 0.13% nonphytate P was supplemented with 0.0, 0.05, and 0.10% P from KH(2)PO(4) or 7 and 14% conventional DDGS, HP DDG, and corn germ. In the second experiment, the P-deficient basal was supplemented with 7 and 14% conventional DDGS and 12.5 and 25% HP DDG. New Hampshire x Columbian female chicks were fed the experimental diets from 9 to 22 d posthatch, and bioavailability of P was estimated using the slope-ratio method where tibia ash was regressed on P intake. The total P content (90% DM basis) of the conventional DDGS, HP DDG, and corn germ were 0.76, 0.33, and 1.29%, respectively. Bioavailabilities of the P in conventional DDGS, HP DDG, and corn germ relative to KH(2)PO(4) were found to be 60, 56, and 25%, respectively. The TME(n) in conventional roosters was found to be significantly reduced for HP DDG and increased for the corn germ when compared with the conventional DDGS. The protein content (90% DM basis) of the HP DDG and corn germ was 33 and 14%, respectively, and the total lysine as a % of CP was approximately 2 times greater for the corn germ than for the HP DDG. Amino acid digestibilities in cecectomized roosters were consistently higher for the corn germ than for the HP DDG, which was similar to conventional DDGS.

Bioaccessibility and Speciation of Potential Toxicants in Some Geogenic Sources of Atmospheric Particulate Matter

NASA Astrophysics Data System (ADS)

Morman, S. A.; Wolf, R. E.; Plumlee, G.; Reynolds, R. L.

2008-12-01

The correlation of exposure to particulate matter (PM) and increased morbidity and mortality was established in the 1970's. Research focused on elucidating mechanisms of action (i.e. particle size, composition, and biodurability), has generally examined anthropogenic sources such as solid or liquid combustion byproducts of fossil fuels, byproducts from the smelting of metal ores, and commercial/industrial mineral dusts (asbestos, crystalline silica. metal dusts). While many studies exist on agricultural exposures to inorganic dust, far fewer have examined health issues related to particulate matter contributions from rural, non-agricultural dusts or other geogenic sources. Geogenic PM (produced by natural processes such as volcanic ash, volcanic fog (vog), dusts from dry lakes or glacial deposits, smoke and windborne ash from wildfires, and dusts containing various soil pathogens) and geoanthropogenic PM (produced from natural sources by processes that are modified or enhanced by human activities such as dusts from lakebeds dried by human removal of water, dusts produced from areas that have undergone desertification as a result of human practices etc.) are increasingly recognized as potential agents of toxicity and disease, via both environmental and occupational exposures. Surface sediment on some dry lake beds may contribute significant amounts of mineral dusts to the atmospheric load. For example, Owens Lake (a dry lake in southern California) has been a major source of PM10 (particulate matter less than 10 micrometers) dust in the United States. Dusts from dry and drying saline lakes may contain high concentrations of metals, such as arsenic, with known human health toxicity. Wildfires, consuming over nine million acres in 2007, also contribute significant amounts of particulate matter in addition to their other hazards. Designed to estimate the bioaccessibility of metals in soils, dusts and other environmental materials by measuring the reactivity of the materials in simulated body fluids (SBFs), physiologically based extraction tests (PBETs) are an inexpensive, acellular in vitro test. Bioaccessibility, defined as the fraction of a potential toxicant that becomes soluble in the SBF (e.g. gastric, intestinal, lung or lysosomal fluid), is an indication of the amounts of a potential toxicant that may be available for absorption through ingestion or inhalation. PBETs were conducted on artificially generated dust samples from playas in the Mojave Desert and soil and ash samples from recent California wildfires. Speciation, an important factor in assessing toxicity, was evaluated using high performance liquid chromatography (HPLC) separation with ICP-MS detection for arsenic and chromium.

Seasonal distribution of nutrients in plants of seven browse species in Louisiana

Treesearch

R.M. Blair; E.A. Epps

1969-01-01

Contents of dry matter, protein, ether extract, crude fiber, nitrogen-free extract, ash, calcium, and phosphorus were determined for 2 years in leaves, twig tips, and twig bases. Species studied were American beautyberry, sweetgum, blackgum, common greenbrier, yellow jessamine, loblolly pine, and common sweetleaf.

Combinations of pozzolans and ground, granulated blast-furnace slag for durable hydraulic cement concrete

DOT National Transportation Integrated Search

1999-08-01

Hydraulic cement concretes were produced using pozzolans and ground, granulated, blast-furnace slag to investigate the effect of these materials on durability. The pozzolans used were an ASTM C 618 Class F fly ash with a low lime content and a dry, d...

Aerosol properties and meteorological conditions in the city of Buenos Aires, Argentina, during the resuspension of volcanic ash from the Puyehue-Cordón Caulle eruption

NASA Astrophysics Data System (ADS)

Graciela Ulke, Ana; Torres Brizuela, Marcela M.; Raga, Graciela B.; Baumgardner, Darrel

2016-09-01

The eruption in June 2011 of the Puyehue-Cordón Caulle Volcanic Complex in Chile impacted air traffic around the Southern Hemisphere for several months after the initial ash emissions. The ash deposited in vast areas of the Patagonian Steppe was subjected to the strong wind conditions prevalent during the austral winter and spring experiencing resuspension over various regions of Argentina. In this study we analyze the meteorological conditions that led to the episode of volcanic ash resuspension which impacted the city of Buenos Aires and resulted in the closure of the two main airports in Buenos Aires area (Ezeiza and Aeroparque) on 16 October 2011. A relevant result is that resuspended material (volcanic ash plus dust) imprints a distinguishable feature within the atmospheric thermodynamic vertical profiles. The thermodynamic soundings show the signature of "pulses of drying" in layers associated with the presence of hygroscopic ash in the atmosphere that has already been reported in similar episodes after volcanic eruptions in other parts of the world. This particular footprint can be used to detect the probable existence of volcanic ash layers. This study also illustrates the utility of ceilometers to detect not only cloud base at airports but also volcanic ash plumes at the boundary layer and up to 7 km altitude. Aerosol properties measured in the city during the resuspension episode indicate the presence of enhanced concentrations of aerosol particles in the boundary layer along with spectral signatures in the measurements at the Buenos Aires AERONET site typical of ash plus dust advected towards the city. The mandatory aviation reports from the National Weather Service about airborne and deposited volcanic ash at the airport near the measurement site (Aeroparque) correlate in time with the enhanced concentrations. The presence of the resuspended material was detected by the CALIOP lidar overpassing the region. Since the dynamics of ash resuspension and recirculation are similar to the dynamics of dust storms, we use the HYSPLIT model with the dust storm module to simulate the episode that affected Buenos Aires. The results of the modeling agree qualitatively with satellite lidar measurements.

Tropical soils degraded by slash-and-burn cultivation can be recultivated when amended with ashes and compost.

PubMed

Gay-des-Combes, Justine Marie; Sanz Carrillo, Clara; Robroek, Bjorn Jozef Maria; Jassey, Vincent Eric Jules; Mills, Robert Thomas Edmund; Arif, Muhammad Saleem; Falquet, Leia; Frossard, Emmanuel; Buttler, Alexandre

2017-07-01

In many tropical regions, slash-and-burn agriculture is considered as a driver of deforestation; the forest is converted into agricultural land by cutting and burning the trees. However, the fields are abandoned after few years because of yield decrease and weed invasion. Consequently, new surfaces are regularly cleared from the primary forest. We propose a reclamation strategy for abandoned fields allowing and sustaining re-cultivation. In the dry region of south-western Madagascar, we tested, according to a split-plot design, an alternative selective slash-and-burn cultivation technique coupled with compost amendment on 30-year-old abandoned fields. Corn plants ( Zea mays L.) were grown on four different types of soil amendments: no amendment (control), compost, ashes (as in traditional slash-and-burn cultivation), and compost + ashes additions. Furthermore, two tree cover treatments were applied: 0% tree cover (as in traditional slash-and-burn cultivation) and 50% tree cover (selective slash-and-burn). Both corn growth and soil fertility parameters were monitored during the growing season 2015 up to final harvest. The amendment compost + ashes strongly increased corn yield, which was multiplied by 4-5 in comparison with ashes or compost alone, reaching 1.5 t/ha compared to 0.25 and 0.35 t/ha for ashes and compost, respectively. On control plots, yield was negligible as expected on these degraded soils. Structural equation modeling evidenced that compost and ashes were complementary fertilizing pathways promoting soil fertility through positive effects on soil moisture, pH, organic matter, and microbial activity. Concerning the tree cover treatment, yield was reduced on shaded plots (50% tree cover) compared to sunny plots (0% tree cover) for all soil amendments, except ashes. To conclude, our results provide empirical evidence on the potential of recultivating tropical degraded soils with compost and ashes. This would help mitigating deforestation of the primary forest by increasing lifespan of agricultural lands.

Glass-ceramic from mixtures of bottom ash and fly ash.

PubMed

Vu, Dinh Hieu; Wang, Kuen-Sheng; Chen, Jung-Hsing; Nam, Bui Xuan; Bac, Bui Hoang

2012-12-01

Along with the gradually increasing yield of the residues, appropriate management and treatment of the residues have become an urgent environmental protection problem. This work investigated the preparation of a glass-ceramic from a mixture of bottom ash and fly ash by petrurgic method. The nucleation and crystallization kinetics of the new glass-ceramic can be obtained by melting the mixture of 80% bottom ash and 20% fly ash at 950 °C, which was then cooled in the furnace for 1h. Major minerals forming in the glass-ceramics mainly are gehlenite (Ca(2)Al(2)SiO(7)) & akermanite (Ca(2)MgSiO(7)) and wollastonite (CaSiO(3)). In addition, regarding chemical/mechanical properties, the chemical resistance showing durability, and the leaching concentration of heavy metals confirmed the possibility of engineering and construction applications of the most superior glass-ceramic product. Finally, petrurgic method of a mixture of bottom ash and fly ash at 950 °C represents a simple, inexpensive, and energy saving method compared with the conventional heat treatment. Copyright © 2012 Elsevier Ltd. All rights reserved.

Using human urine as food for cyanobacteria in LSS

NASA Astrophysics Data System (ADS)

Kalacheva, Galina; Gribovskaya, Iliada; Kolmakova, Angela

In biological LSS: human, higher plants, algae, united by common cycle of matter, native human urine is the most problematic substance for using in inter-link exchange. It contains urea, ammonium compounds and up to 10 g/l of NaCl. Each of the mentioned components is toxic for growing higher plants. As for inferior plants, experiments showed that cyanobacteria of genus Spirulina platensis and similar genus Oscillatoria deflexa can grow at NaCl concentrations up to 20 g/l and NH4Cl concentrations up to 800 mg/l. These cyanobacteria can be used in LSS as a photosynthesizing link. Besides, S. platensis is edible for humans and fish. To use urine as food for algae, it is necessary to remove urea and organics. All previously used methods for urine treatment aimed at urea destruction: heating to 300oC, ultraviolet exposure, freezing, oxidation on reactor with hydrogen peroxide, had no effect. We used the following method of urine treatment: urine evaporation till dry residue, subsequent combustion in muffle furnace at 450-500oC and creation of ash water extract of the same volume as the initial urine. Comparison of standard Zarrouk's solution for S. platensis and O. deflexa with the water extract of urine ash showed that the concentrations of K, Ca, Mg, P, S were similar. Successful experiments were made with O. deflexa that were grown on nutrient solution made of the water extract of urine ash with 10 g/l of NaHCO3 and 2 g/l of NaNO3. The sources of intersystem production of HCO3 and NO3 were shown, and the biochemical composition of the investigated algae species, including mineral composition, protein, carbohydrate, amino acid, lipid and vitamin content were studied.

High performance of treated and washed MSWI bottom ash granulates as natural aggregate replacement within earth-moist concrete.

PubMed

Keulen, A; van Zomeren, A; Harpe, P; Aarnink, W; Simons, H A E; Brouwers, H J H

2016-03-01

Municipal solid waste incineration bottom ash was treated with specially designed dry and wet treatment processes, obtaining high quality bottom ash granulate fractions (BGF) suitable for up to 100% replacement of natural gravel in concrete. The wet treatment (using only water for separating and washing) significantly lowers the leaching of e.g. chloride and sulfate, heavy metals (antimony, molybdenum and copper) and dissolved organic carbon (DOC). Two potential bottom ash granulate fractions, both in compliance with the standard EN 12620 (aggregates for concrete), were added into earth-moist concrete mixtures. The fresh and hardened concrete physical performances (e.g. workability, strength and freeze-thaw) of high strength concrete mixtures were maintained or improved compared with the reference mixtures, even after replacing up to 100% of the initial natural gravel. Final element leaching of monolithic and crushed granular state BGF containing concretes, showed no differences with the gravel references. Leaching of all mixtures did not exceed the limit values set by the Dutch Soil Quality Degree. In addition, multiple-life-phase emission (pH static test) for the critical elements of input bottom ash, bottom ash granulate (BGF) and crushed BGF containing concrete were assessed. Simulation pH lowering or potential carbonation processes indicated that metal (antimony, barium, chrome and copper) and sulfate element leaching behavior are mainly pH dominated and controlled, although differ in mechanism and related mineral abundance. Copyright © 2016 Elsevier Ltd. All rights reserved.

1980 scrubber highlights: dry-process startups, dual-alkali progress highlight scrubber advances

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-06-01

A survey of electric utilities reports scrubbers on 13% of existing capacity and estimates 29% by 1990, but compliance with the New Source Performance Standards may raise the total even higher. Dry scrubbers at two Northern States Power installations show test performances that indicate sound design and report modest manpower requirements. Other utilities are ordering demonstration dry-scrubber units, although orders for wet scrubbers continue to do well. A new dual-alkali scrubber is performing well at three installations in terms of availability and sulfur-dioxide-removal efficiency. A full-scale utility dump site test will identify any hazardous materials in pollution control ash andmore » sludge wastes. (DCK)« less

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

DOEpatents

Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

1997-10-28

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

DOEpatents

Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

1997-01-01

The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

Methods to Improve Survival and Growth of Planted Alternative Species Seedlings in Black Ash Ecosystems Threatened by Emerald Ash Borer

Treesearch

Nicholas Bolton; Joseph Shannon; Joshua Davis; Matthew Grinsven; Nam Noh; Shon Schooler; Randall Kolka; Thomas Pypker; Joseph Wagenbrenner

2018-01-01

Emerald ash borer (EAB) continues to spread across North America, infesting native ash trees and changing the forested landscape. Black ash wetland forests are severely affected by EAB. As black ash wetland forests provide integral ecosystem services, alternative approaches to maintain forest cover on the landscape are needed. We implemented simulated EAB infestations...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lindberg, Daniel, E-mail: daniel.lindberg@abo.fi; Molin, Camilla, E-mail: camilla.molin@abo.fi; Hupa, Mikko, E-mail: mikko.hupa@abo.fi

Highlights: • We review the thermal treatment methods for ashes and residues from WtE plants. • We review the results from extensive laboratory work on vitrification, melting and vaporization of ash. • We analyze the results from the extensive patent literature on thermal treatment. • We review industrial concepts for thermal treatment of ash. - Abstract: Thermal treatment methods of bottom ash, fly ash and various types of APC (air pollution control) residues from waste-to-energy plants can be used to obtain environmentally stable material. The thermal treatment processes are meant to reduce the leachability of harmful residue constituents, destroy toxicmore » organic compounds, reduce residue volume, and produce material suitable for utilization. Fly ash and APC residues often have high levels of soluble salts, particularly chlorides, metals such as cadmium, lead, copper and zinc, and trace levels of organic pollutants such as dioxins and furans. Different thermal treatment methods can be used to either decompose or stabilize harmful elements and compounds in the ash, or separate them from the ash to get a material that can be safely stored or used as products or raw materials. In the present paper, thermal treatment methods, such as sintering, vitrification, and melting have been reviewed. In addition to a review of the scientific literature, a survey has been made of the extensive patent literature in the field.« less

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 1. Technical results. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue-gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

Environmental assessment of a wood-waste-fired industrial watertube boiler. Volume 2. Data supplement. Final report, March 1981-March 1984

DOE Office of Scientific and Technical Information (OSTI.GOV)

Castaldini, C.; Waterland, L.R.

1987-03-01

The two-volume report gives results from field tests of a wood-waste-fired industrial watertube boiler. Two series of tests were performed: one firing dry (11% moisture) wood waste, and the other firing green (34% moisture) wood waste. Emission measurements included: continuous monitoring of flue-gas emissions; source-assessment sampling system (SASS) sampling of the flue-gas with subsequent laboratory analysis of samples to give total flue-gas organics in two boiling-point ranges, compound category information within these ranges, specific quantitation of the semi-volatile organic priority pollutants, and flue gas concentrations of 73 trace elements; Method 5 sampling for particulate; controlled condensation system sampling for SO/submore » 2/ and SO/sub 3/; and grab sampling of boiler mechanical collector hopper ash for inorganic and organic composition determinations. Total organic emissions decreased from 60-135 mg/dscm firing dry wood to 2-65 mg/dscm firing green wood, in parallel with corresponding boiler CO emissions.« less

[Development of cough-relieving herbal teas].

PubMed

Puodziūniene, Gene; Janulis, Valdimaras; Milasius, Arvydas; Budnikas, Vytautas

2005-01-01

Cough-relieving medicinal herbs in tea are used from ancient times. Mucilage present in them or secretion produced under the influence of the active substances covers the oral and throat mucosa soothing its irritability and relieving dry, tiresome cough. It is known that the mixtures of medicinal herbs (Specias) have a complex influence on the human organism and the rational combination of medicinal herbs can improve their curative action and decrease the undesirable side effects. Having summarized the properties of those medicinal herbs we decided to create two formulations of cough-relieving herbal tea. The first formulation consists of marshmallow roots, liquorice roots and lime flowers, the second -- of marshmallow roots, Iceland moss and lime flowers. The methods for identification and assay of the active substances in the compounds were applied. The purity of the mixtures was regulated by limitation of the loss on drying, total ash, microbial contamination, contamination with radionuclides, heavy metals, pesticides and foreign matter. The expiry date of both cough-relieving herbal teas was approved to be 2 years.

Solid-liquid extraction of alkali metals and organic compounds by leaching of food industry residues.

PubMed

Yu, Chaowei; Zheng, Yi; Cheng, Yu-Shen; Jenkins, Bryan M; Zhang, Ruihong; VanderGheynst, Jean S

2010-06-01

Leaching was studied for its application in extracting inorganic and organic constituents from fresh fermented grape pomace, air-dried fermented grape pomace and air-dried sugar beet pulp. Samples of each feedstock were leached in water at ambient temperature for 30 or 120 min at dry solid-to-liquid ratios of 1/20 and 1/50 kg/L. Leaching removed 82% of sodium, 86% of potassium, and 76% of chlorine from sugar beet pulp, and reduced total ash concentration in air-dry fermented grape pomace from 8.2% to 2.9% of dry matter, 8.2% to 4.4% in fresh fermented grape pomace, and 12.5% to 5.4% in sugar beet pulp. Glycerol (7-11 mg/dry g), ethanol (131-158 mg/dry g), and acetic acid (24-31 mg/dry g) were also extracted from fermented grape pomace. These results indicate that leaching is a beneficial pretreatment step for improving the quality of food processing residues for thermochemical and biochemical conversion. (c) 2010 Elsevier Ltd. All rights reserved.

Study of morphology, chemical, and amino acid composition of red deer meat

PubMed Central

Okuskhanova, Eleonora; Assenova, Bahytkul; Rebezov, Maksim; Amirkhanov, Kumarbek; Yessimbekov, Zhanibek; Smolnikova, Farida; Nurgazezova, Almagul; Nurymkhan, Gulnur; Stuart, Marilyne

2017-01-01

Aim: The aim of this study was to evaluate red deer (maral) meat quality based on chemical composition, pH, water-binding capacity (WBC), and amino acid content. Materials and Methods: Maral meat surface morphology measurements were obtained by scanning electron microscopy. Active acidity (pH) was determined by potentiometry. Samples were analyzed for WBC by exudation of moisture to a filter paper by the application of pressure. Chemical composition (moisture, protein, fat, and ash fractions) was obtained by drying at 150°C and by extraction, using ethylic ether, and ashing at 500-600°C. The amino acid composition was obtained by liquid chromatography. Results: Maral meat, with a pH of 5.85 and an average moisture content of 76.82%, was found to be low in fat (2.26%). Its protein content was 18.71% while its ash content was 2.21%. The amino acid composition showed that lysine (9.85 g/100 g), threonine (5.38 g/100 g), and valine (5.84 g/100 g) predominated in maral meat, while phenylalanine (4.08 g/100 g), methionine (3.29 g/100 g), and tryptophan (0.94 g/100 g) were relatively low in maral meat compared to other meats. The average WBC was found to be 65.82% and WBC was found to inversely correlate with moisture content. Conclusion: Low-fat content, high mineral content, and balanced amino-acid composition qualify maral meat as a worthy dietary and functional food. PMID:28717313

Effects of a layer of vegetative ash layer on wettable and water repellent soil hydrology

NASA Astrophysics Data System (ADS)

Bodí, Merche B.; Doerr, Stefan H.; Cerdà, Artemi; Mataix-Solera, Jorge

2010-05-01

Following a wildfire, a layer of vegetative ash often covers the ground until it is dissolved or redistributed by wind and water erosion. Much of the existing literature suggests that the ash layer temporally reduces infiltration by clogging soil pores or by forming a surface crust (Mallik et al., 1984; Onda et al., 2008). However, an increasing number of field-based studies have found that, at least in the short term, ash increases infiltration by storing rainfall and protecting the underlying soil from sealing (Cerdà and Doerr, 2008; Woods and Balfour, 2008). On the other hand, after a fire the soil may have produced, enhanced or reduced its water repellency (Doerr et al., 2000). Very few studies have been taken into account the interaction of the ash and the repellent soil. The layer of ash may have similar role as a litter layer in delaying runoff and reducing erosion by storing water. In order to examine this interaction, it was been made a series of experiments using a laboratory rainfall simulation. It has been assessed the effects of an ash layer i) on a wettable and water repellent soil (WDPT > 7200s), ii) with different ash thicknesses (bare soil and 5 mm, 15 mm and 30 mm of ash), iii) preceding and following the first rain after a fire when the ground is still wetted and after being partially dried. Three replicates were done, being a total of 40 simulations. The ash used was collected from a Wildfire in Teruel (Spain) during summer of 2009. The simulations were conducted in metal boxes of 30x30 cm and filled with 3 cm of soil. The slope of the box was set at 10° (17%) and the intensity applied was 78-84 mm h-1during 40 minutes. The splash detachment was determined also using four splash cups. Overland flow and subsurface drainage was collected at 1-minute intervals and the former stored every 5 min to allow determination of sediment concentrations, yield and erosion rates. Each sample was examined at the end in terms of water repellency, infiltration pattern and ash incorporation into the soil. The results show that when ash covers the wettable soil, runoff occur for a short period of time in the middle of the event. It occurred latter on time but larger in quantity as the ash thickness increases (from 0% to 2% of runoff coefficient) and at the same time drainage is reduced (from 57 to 24%). This suggests that the ash layer became saturated and produce runoff until the water is able to drain into the soil. Oppositely, in water repellent soil as ash thickness increases both runoff is reduced (from 78% to 26%) and drainage is increased (from 0 to 16%). That fact indicates a modification in the hydraulic conductivity of the repellent soil due to the pressure of the ash layer. Splash and erosion rates are bigger in water repellent soils yet erosion rates never exceed 2.5 g m-2 h-1. The fact of wetting increases the runoff and drainage rates in wettable but reduce them in the water repellent soil. An irregular infiltration pattern is observed afterwards. After drying the soil, the increase in runoff indicates a crust formation. Moreover, in water repellent soils part of the repellency is reestablished. These findings demonstrate that the interaction of the soil-ash layer should be considered and better studied in the immediate hydrological response after wildfire due to its particular behavior. References Cerdà, A. and Doerr, S.H., 2008. The effect of ash and needle cover on surface runoff and erosion in the immediate post-fire period. Catena, 74: 256-263. Doerr, S.H., Shakesby, R.A. and Walsh, R.P.D., 2000. Soil Water repellency: Its causes, characteristics and hydro-geomorphological significance. Earth Science Reviews, 51: 33-65. Mallik, A.U., Gimingham, C.H. and Rahman, A.A., 1984. Ecological effects of heater burning. I. Water infiltration, moisture retention and porosity of surface soil. Journal of Ecology, 72: 767-776. Onda, Y., Dietrich, W.E. and Booker, F., 2008. Evolution of overland flow after a severe forest fire, Point Reyes, California. Catena, 72: 13-20. Woods, S.W. and Balfour, V., 2008. The effect of ash on runoff and erosion after a forest wildfire, Montana, U.S.A. International Journal of Wildland Fire, 17(5): 535-548.

[Development of throat clearing herbal teas].

PubMed

Puodziūniene, Gene; Janulis, Valdimaras; Milasius, Arvydas; Budnikas, Milasius

2004-01-01

Medicinal herbs in tea for throat clearing are used from ancient times. Taking into consideration the bronchial mucus secretion stimulating and antispasmodic, antimicrobial, antiphlogistic and stimulating effect on the ciliated epithelium two new formulations of throat clearing herbal tea were originated. The first formulation consists of liquorice roots, sweet fennel and thyme, and the second one consists of pine gemmae, thyme and elder flowers. The methods for identification and assay of the active substances of the components were adapted. The purity of the mixtures was regulated by the limitation of the loss on drying, total ash, microbial contamination, contamination with radionuclides, heavy metals, pesticides and foreign matter. Expiry date of both throat clearing herbal teas was confirmed to be 2 years.

Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent.

PubMed

Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh; Lee, Byeong-Kyu; Mitoma, Yoshiharu; Mallampati, Srinivasa Reddy

2015-10-15

This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO4 dispersion mixture immobilized 95-100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO4 was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO4 mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO4- associated crystalline complexes, and that immobile Ca/PO4 salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO4 as a simple, suitable and highly efficient material for the gentle immobilization of heavy metals in hazardous ASR thermal residue in dry condition. Copyright © 2015 Elsevier B.V. All rights reserved.

Generation of fine hydromagmatic ash by growth and disintegration of glassy rinds

USGS Publications Warehouse

Mastin, L.G.

2007-01-01

The deposits of mafic hydromagmatic eruptions are more fine grained and variable in vesicularity than dry magmatic deposits. Blocky, equant shapes of many hydromagmatic clasts also contrast with droplet, thread, and bubble wall morphology of dry magmatic fragments. Small (

Influence of animal age on body concentrations of minerals in Japanese quail (Coturnix japonica).

PubMed

Sales, J; Skřivan, M; Englmaierová, M

2014-12-01

Mathematical modelling of the relationships between mineral inputs and outputs would enable the prediction of mineral requirements of poultry under a wide range of conditions. To establish the feasibility of possible modelling of mineral requirements, the current study aimed to describe the individual mineral concentrations of whole bodies of quail over the life cycle from hatching to 70 days of age. Quail were reared indoors without any restrictions that could limit growth. Sampling of birds (n = 6-18) was carried out at 0, 3, 7, 14, 21, 35, 49 and 70 days after hatching. Freeze-dried samples of whole bodies (digestive contents removed) were analysed for ash, and macrominerals (calcium, magnesium, phosphorus, potassium, sodium) and microminerals (copper, iron, manganese, nickel, selenium, zinc). Ash concentration followed a curvilinear trend, with a maximum of 101.7 g/kg dry matter at 32.77 days. Individual mineral concentrations, expressed as a proportion of ash, were fluctuating over time, with the most prominent changes at 3 days and again at either 14 or 21 days. Dissimilar patterns in individual mineral concentrations resulted that ratios between minerals followed inconsistent patterns over time. Although mineral contents in absolute quantities can be described through modelling over the entire life cycle of the bird, it can be concluded that variable concentrations of individual minerals could complicate further model development. Journal of Animal Physiology and Animal Nutrition © 2014 Blackwell Verlag GmbH.

Effects of drying process on the physicochemical properties of nopal cladodes at different maturity stages.

PubMed

Contreras-Padilla, Margarita; Gutiérrez-Cortez, Elsa; Valderrama-Bravo, María Del Carmen; Rojas-Molina, Isela; Espinosa-Arbeláez, Diego Germán; Suárez-Vargas, Raúl; Rodríguez-García, Mario Enrique

2012-03-01

Chemical proximate analysis was done in order to determine the changes of nutritional characteristics of nopal powders from three different maturity stages 50, 100, and 150 days and obtained by three different drying processes: freeze dried, forced air oven, and tunnel. Results indicate that nopal powder obtained by the process of freeze dried retains higher contents of protein, soluble fiber, and fat than the other two processes. Also, freeze dried process had less effect on color hue variable. No changes were observed in insoluble fiber content, chroma and lightness with the three different drying processes. Furthermore, the soluble fibers decreased with the age of nopal while insoluble fibers and ash content shows an opposite trend. In addition, the luminosity and hue values did not show differences among the maturity stages studied. The high content of dietary fibers of nopal pad powder could to be an interesting source of these important components for human diets and also could be used in food, cosmetics and pharmaceutical industry.

Utilization of leaf litter as a potential feed source

USDA-ARS?s Scientific Manuscript database

Proximate analysis and In-situ nylon bag ruminal dry matter degradation of fall dropped Liriodendron tulipifera (tulip poplar) and Quercus alba (white oak) leaves were used to determine their potential use as a feed source for ruminant livestock animals. Ash content was 8.24 and 4.69 ...

40 CFR 60.1305 - May I conduct stack testing less often?

Code of Federal Regulations, 2010 CFR

2010-07-01

...: dioxins/furans, cadmium, lead, mercury, particulate matter, opacity, hydrogen chloride, and fugitive ash. (b) You can test less often for dioxins/furans emissions if you own or operate a municipal waste... levels of dioxins/furans emissions less than or equal to 7 nanograms per dry standard cubic meter (total...

Response of nutrients, biofilm, and benthic insects to salmon carcass addition.

Treesearch

Shannon M. Claeson; Judith L. Li; Jana E. Compton; Peter A. Bisson

2006-01-01

Salmon carcass addition to streams is expected to increase stream productivity at multiple trophic levels. This study examined stream nutrient (nitrogen, phosphorus, and carbon), epilithic biofilm (ash-free dry mass and chlorophyll a), leaf-litter decomposition, and macroinvertebrate (density and biomass) responses to carcass addition in three headwater streams of...

Development of Self-Consolidating High Strength Concrete Incorporating Treated Palm Oil Fuel Ash

PubMed Central

Alsubari, Belal; Shafigh, Payam; Jumaat, Mohd Zamin

2015-01-01

Palm oil fuel ash (POFA) has previously been used as a partial cement replacement in concrete. However, limited research has been undertaken to utilize POFA in high volume in concrete. This paper presents a study on the treatment and utilization of POFA in high volume of up to 50% by weight of cement in self-consolidating high strength concrete (SCHSC). POFA was treated via heat treatment to reduce the content of unburned carbon. Ordinary Portland cement was substituted with 0%, 10%, 20%, 30%, and 50% treated POFA in SCHSC. Tests have been conducted on the fresh properties, such as filling ability, passing ability and segregation resistance, as well as compressive strength, drying shrinkage and acid attack resistance to check the effect of high volume treated POFA on SCHSC. The results revealed that compared to the control concrete mix, the fresh properties, compressive strength, drying shrinkage, and resistance against acid attack have been significantly improved. Conclusively, treated POFA can be used in high volume as a cement replacement to produce SCHSC with an improvement in its properties.

Comparison of mass balance, energy consumption and cost of composting facilities for different types of organic waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang Huijun; Matsuto, Toshihiko, E-mail: matsuto@eng.hokudai.ac.jp

2011-03-15

Mass balance, energy consumption and cost are basic pieces of information necessary for selecting a waste management technology. In this study, composting facilities that treat different types of organic waste were studied by questionnaire survey and via a chemical analysis of material collected at the facilities. The mass balance was calculated on a dry weight basis because the moisture content of organic waste was very high. Even though the ratio of bulking material to total input varied in the range 0-65% on a dry basis, the carbon and ash content, carbon/nitrogen ratio, heavy metal content and inorganic nutrients in themore » compost were clearly influenced by the different characteristics of the input waste. The use of bulking material was not correlated with ash or elemental content in the compost. The operating costs were categorised into two groups. There was some economy of scale for wages and maintenance cost, but the costs for electricity and fuel were proportional to the amount of waste. Differences in operating costs can be explained by differences in the process characteristics.« less

Site Simulation of Solidified Peat: Lab Monitoring

NASA Astrophysics Data System (ADS)

Durahim, N. H. Ab; Rahman, J. Abd; Tajuddin, S. F. Mohd; Mohamed, R. M. S. R.; Al-Gheethi, A. A.; Kassim, A. H. Mohd

2018-04-01

In the present research, the solidified peat on site simulation is conducted to obtain soil leaching from soil column study. Few raw materials used in testing such as Ordinary Portland Cement (OPC), Fly ash (FA) and bottom ash (BA) which containing in solidified peat (SP), fertilizer (F), and rainwater (RW) are also admixed in soil column in order to assess their effects. This research was conducted in two conditions which dry and wet condition. Distilled water used to represent rainfall during flushing process while rainwater used to gain leaching during dry and wet condition. The first testing made after leaching process done was Moisture Content (MC). Secondly, Unconfined Compressive Strength (UCS) will be conducted on SP to know the ability of SP strength. These MC and UCS were made before and after SP were applied in soil column. Hence, the both results were compared to see the reliability occur on SP. All leachate samples were tested using Absorption Atomic Spectroscopy (AAS), Ion Chromatography (IC) and Inductively-Coupled Plasma Spectrophotometry (ICP-MS) testing to know the anion and cation present in it.

Removal of hazardous metals from MSW fly ash--an evaluation of ash leaching methods.

PubMed

Fedje, Karin Karlfeldt; Ekberg, Christian; Skarnemark, Gunnar; Steenari, Britt-Marie

2010-01-15

Incineration is a commonly applied management method for municipal solid waste (MSW). However, significant amounts of potentially hazardous metal species are present in the resulting ash, and these may be leached into the environment. A common idea for cleaning the ash is to use enhanced leaching with strong mineral acids. However, due to the alkalinity of the ash, large amounts of acid are needed and this is a drawback. Therefore, this work was undertaken in order to investigate some alternative leaching media (EDTA, ammonium nitrate, ammonium chloride and a number of organic acids) and to compare them with the usual mineral acids and water. All leaching methods gave a significant increase in ash specific surface area due to removal of soluble bulk (matrix) compounds, such as CaCO(3) and alkali metal chlorides. The use of mineral acids and EDTA mobilised many elements, especially Cu, Zn and Pb, whereas the organic acids generally were not very effective as leaching agents for metals. Leaching using NH(4)NO(3) was especially effective for the release of Cu. The results show that washing of MSW filter ash with alternative leaching agents is a possible way to remove hazardous metals from MSW fly ash.

Determination of metals in coal fly ashes using ultrasound-assisted digestion followed by inductively coupled plasma optical emission spectrometry.

PubMed

Pontes, Fernanda V M; Mendes, Bruna A de O; de Souza, Evelyn M F; Ferreira, Fernanda N; da Silva, Lílian I D; Carneiro, Manuel C; Monteiro, Maria I C; de Almeida, Marcelo D; Neto, Arnaldo A; Vaitsman, Delmo S

2010-02-05

A method for determination of Co, Cr, Cu, Fe, Mn, Ni, Ti, V and Zn in coal fly ash samples using ultrasound-assisted digestion followed by inductively coupled plasma optical emission spectrometry (ICP-OES) is proposed. The digestion procedure consisted in the sonication of the previously dried sample with hydrofluoric acid and aqua regia at 80 degrees C for 30 min, elimination of fluorides by heating until dryness for about 1h and dissolution of the residue with nitric acid solution. A classical digestion method, used as comparative method, consisted in the addition of HCl, HNO(3) and HF to 1 g of sample, and heating on a hot plate until dryness for about 6h. The proposed method presents several advantages: it requires lower amounts of sample and reagents, and it is faster. It is also advantageous when compared to the published methods, which also use ultrasound-assisted digestion procedure: lower detection limits for Co, Cu, Ni, V and Zn, and it does not require shaking during the digestion. The detection limits (microg g(-1)) for Co, Cr, Cu, Fe, Mn, Ni, Ti, V and Zn were 0.06, 0.37, 1.0, 25, 0.93, 0.45, 4.0, 1.7 and 4.3, respectively. The results were in good agreement with those obtained by the classical method and reference values. The exception was Cr, which presented low recoveries in classical and proposed methods (83 and 87%, respectively). Also, the concentration for Cu obtained by the proposed method was significantly different from the reference value, in spite of the good recovery (91+/-1%). Copyright 2009 Elsevier B.V. All rights reserved.

Comparison of H2S adsorption by two hydrogel composite (HBC) derived by Empty Fruit Bunch (EFB) biochar and Coal Fly Ash (CFA)

NASA Astrophysics Data System (ADS)

Meri, N. H.; Alias, A. B.; Talib, N.; Rashid, Z. A.; Ghani, W. A. W. A. K.

2018-03-01

This study are covered the adsorption performance of two adsorbent Empty Fruit Bunch Hydrogel Biochar Composite (EFB-HBC) and Coal Fly Ash Hydrogel Composite (CFA-HC) on hydrogen sulphide. The EFB biochar were produce by pyrolysed and heated from room temperature to 550˚C at 10˚C/min under the Nitrogen flow. Meanwhile, coal fly ash collected from a power plant located in Selangor, Malaysia. Both of the materials is a waste from different industries and became the precursor to our adsorbents. EFB biochar and coal fly ash has been synthesized to become hydrogel by polymerization process with acrylamide (AAm) as monomer, N,N’-methylene bisacry lamide (MBA) as cross linker and ammonium persulfate (APS) as initiator. In addition, because of the speciality of hydrogel itself, which is has high ability in storing water, the effect of H2O wetness on EFB-HBC and CFA-HC were investigate in adsorption of H2S. EFB-HBC gave a longest breakthrough time and highest adsorption capacity compared with CFA-HC in both condition (dry/wet). The result also indicated that, the increased the bed height, increased the adsorption capacity.

Use of recycled chunk rubber asphalt concrete (CRAC) on low volume roads and use of recycled crumb rubber modifier in asphalt pavements. Final report, June 1993-June 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hossain, M.; Funk, L.P.; Sadeq, M.A.

1995-06-01

The major objective of this project was to formulate a Chunk Rubber Asphalt Concrete (CRAC) mix for use on low volume roads. CRAC is a rubber modified asphalt concrete product produced by the `dry process` where rubber chunks of 1/2 inch size are used as aggregate in a cold mix with a type C fly ash. The second objective of this project was to develop guidelines concerning the use of rubber modified asphalt concrete hot mix to include: (1) Design methods for use of asphalt-rubber mix for new construction and overlay, (2) Mix design method for asphalt-rubber, and (3) Testmore » method for determining the amount of rubber in an asphalt-rubber concrete for quality control purposes.« less

Comparison of digestion methods for total elemental analysis of peat and separation of its organic and inorganic components

USGS Publications Warehouse

Papp, C.S.E.; Harms, T.F.

1985-01-01

In order to find the most efficient digestion method for the total elemental recovery in peat, ten samples were subjected to different techniques and analysed for Ca, Mg, Fe, AI, Na, K, Mn, P, Zn, Cu, Li, Cd, Co, Ni, Pb and Si using atomic-absorption spectrophotometry. The most satisfactory procedures were dry ashing followed by hydrofluoric acid treatment and wet digestion using a mixture of hot nitric, perchloric and hydrofluoric acids. The wet digestion offers the advantage of a single decomposition method for the determination of Ca, Mg, Fe, AI, K, Na, Mn, Cu, Li, Zn and P. An alkaline fusion technique was required for the determination of Si. Hydrogen peroxide was used to separate the peat into its organic and inorganic components, leading to the total recovery of the elements for both fractions.

Mercury and trace element distribution in density separates of a South African Highveld (#4) coal: Implications for mercury reduction and preparation of export coal

USGS Publications Warehouse

Kolker, Allan; Senior, Connie L.; van Alphen, Chris; Koenig, Alan E.; Geboy, Nicholas J.

2017-01-01

Eight density separates of Permian Highveld (#4) coal were investigated for partitioning of Hg and trace elements. The separates include float fractions obtained in heavy media having densities of 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, and 2.0 g/cm3, and the sink fraction for 2.0 g/cm3. Bulk analysis of the separates shows strong (R2 ≥ 0.80) positive correlations between pyritic sulfur and mercury, and between ash yield and both pyritic sulfur and mercury. Laser ablation (LA) ICP-MS analysis of individual pyrite grains in the separates confirms association of Hg and As with pyrite as indicated by bulk analysis. Other elements detected in pyrite by LA-ICP-MS include Mn, Co, Ni, Tl, and Pb. Results for the separates allow prediction of Hg, trace elements, and ash yields expected in specific South African coal products. These range from 0.06 ppm Hg and an ash yield of 11.5% ash for the export fraction to 0.47 ppm Hg and an ash yield of 60.9% for the discard (stone) fraction (dry basis). Results show pronounced differences expected between coal used for domestic power generation and coal which is exported.

Chemical composition, mineral content and amino acid and lipid profiles in bones from various fish species.

PubMed

Toppe, Jogeir; Albrektsen, Sissel; Hope, Britt; Aksnes, Anders

2007-03-01

The chemical composition, content of minerals and the profiles of amino acids and fatty acids were analyzed in fish bones from eight different species of fish. Fish bones varied significantly in chemical composition. The main difference was lipid content ranging from 23 g/kg in cod (Gadus morhua) to 509 g/kg in mackerel (Scomber scombrus). In general fatty fish species showed higher lipid levels in the bones compared to lean fish species. Similarly, lower levels of protein and ash were observed in bones from fatty fish species. Protein levels differed from 363 g/kg lipid free dry matter (dm) to 568 g/kg lipid free dm with a concomitant inverse difference in ash content. Ash to protein ratio differed from 0.78 to 1.71 with the lowest level in fish that naturally have highest swimming and physical activity. Saithe (Pollachius virens) and salmon (Salmo salar) were found to be significantly different in the levels of lipid, protein and ash, and ash/protein ratio in the bones. Only small differences were observed in the level of amino acids although species specific differences were observed. The levels of Ca and P in lipid free fish bones were about the same in all species analyzed. Fatty acid profile differed in relation to total lipid levels in the fish bones, but some minor differences between fish species were observed.

Method for solidification of radioactive and other hazardous waste

DOEpatents

Anshits, Alexander G.; Vereshchagina, Tatiana A.; Voskresenskaya, Elena N.; Kostin, Eduard M.; Pavlov, Vyacheslav F.; Revenko, Yurii A.; Tretyakov, Alexander A.; Sharonova, Olga M.; Aloy, Albert S.; Sapozhnikova, Natalia V.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

2002-01-01

Solidification of liquid radioactive waste, and other hazardous wastes, is accomplished by the method of the invention by incorporating the waste into a porous glass crystalline molded block. The porous block is first loaded with the liquid waste and then dehydrated and exposed to thermal treatment at 50-1,000.degree. C. The porous glass crystalline molded block consists of glass crystalline hollow microspheres separated from fly ash (cenospheres), resulting from incineration of fossil plant coals. In a preferred embodiment, the porous glass crystalline blocks are formed from perforated cenospheres of grain size -400+50, wherein the selected cenospheres are consolidated into the porous molded block with a binder, such as liquid silicate glass. The porous blocks are then subjected to repeated cycles of saturating with liquid waste, and drying, and after the last cycle the blocks are subjected to calcination to transform the dried salts to more stable oxides. Radioactive liquid waste can be further stabilized in the porous blocks by coating the internal surface of the block with metal oxides prior to adding the liquid waste, and by coating the outside of the block with a low-melting glass or a ceramic after the waste is loaded into the block.

A stepwise-cluster microbial biomass inference model in food waste composting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun Wei; Huang, Guo H., E-mail: huangg@iseis.or; Chinese Research Academy of Environmental Science, North China Electric Power University, Beijing 100012-102206

2009-12-15

A stepwise-cluster microbial biomass inference (SMI) model was developed through introducing stepwise-cluster analysis (SCA) into composting process modeling to tackle the nonlinear relationships among state variables and microbial activities. The essence of SCA is to form a classification tree based on a series of cutting or mergence processes according to given statistical criteria. Eight runs of designed experiments in bench-scale reactors in a laboratory were constructed to demonstrate the feasibility of the proposed method. The results indicated that SMI could help establish a statistical relationship between state variables and composting microbial characteristics, where discrete and nonlinear complexities exist. Significance levelsmore » of cutting/merging were provided such that the accuracies of the developed forecasting trees were controllable. Through an attempted definition of input effects on the output in SMI, the effects of the state variables on thermophilic bacteria were ranged in a descending order as: Time (day) > moisture content (%) > ash content (%, dry) > Lower Temperature (deg. C) > pH > NH{sub 4}{sup +}-N (mg/Kg, dry) > Total N (%, dry) > Total C (%, dry); the effects on mesophilic bacteria were ordered as: Time > Upper Temperature (deg. C) > Total N > moisture content > NH{sub 4}{sup +}-N > Total C > pH. This study made the first attempt in applying SCA to mapping the nonlinear and discrete relationships in composting processes.« less

Comparing Two Independent Satellite-Based Algorithms for Detecting and Tracking Ash Clouds by Using SEVIRI Sensor

PubMed Central

Cooke, Michael C.; Filizzola, Carolina

2018-01-01

The Eyjafjallajökull (Iceland) volcanic eruption of April–May 2010 caused unprecedented air-traffic disruption in Northern Europe, revealing some important weaknesses of current operational ash-monitoring and forecasting systems and encouraging the improvement of methods and procedures for supporting the activities of Volcanic Ash Advisory Centers (VAACs) better. In this work, we compare two established satellite-based algorithms for ash detection, namely RSTASH and the operational London VAAC method, both exploiting sensor data of the spinning enhanced visible and infrared imager (SEVIRI). We analyze similarities and differences in the identification of ash clouds during the different phases of the Eyjafjallajökull eruption. The work reveals, in some cases, a certain complementary behavior of the two techniques, whose combination might improve the identification of ash-affected areas in specific conditions. This is indicated by the quantitative comparison of the merged SEVIRI ash product, achieved integrating outputs of the RSTASH and London VAAC methods, with independent atmospheric infrared sounder (AIRS) DDA (dust-detection algorithm) observations. PMID:29382058

Geotechnical characterization of a Municipal Solid Waste Incineration Ash from a Michigan monofill.

PubMed

Zekkos, Dimitrios; Kabalan, Mohammad; Syal, Sita Marie; Hambright, Matt; Sahadewa, Andhika

2013-06-01

A field and laboratory geotechnical characterization study of a Municipal Solid Waste Incineration Ash disposed of at the Carleton Farms monofill in Michigan was performed. Field characterization consisted of field observations, collection of four bulk samples and performance of shear wave velocity measurements at two locations. Laboratory characterization consisted of basic geotechnical characterization, i.e., grain size distribution, Atterberg limits, specific gravity tests, compaction tests as well as moisture and organic content assessment followed by direct shear and triaxial shear testing. The test results of this investigation are compared to results in the literature. The grain size distribution of the samples was found to be very similar and consistent with the grain size distribution data available in the literature, but the compaction characteristics were found to vary significantly. Specific gravities were also lower than specific gravities of silicic soils. Shear strengths were higher than typically reported for sandy soils, even for MSWI ash specimens at a loose state. Strain rate was not found to impact the shear resistance. Significant differences in triaxial shear were observed between a dry and a saturated specimen not only in terms of peak shear resistance, but also in terms of stress-strain response. In situ shear wave velocities ranged from 500 to 800 m/s at a depth of about 8m, to 1100-1200 m/s at a depth of 50 m. These high shear wave velocities are consistent with field observations indicating the formation of cemented blocks of ash with time, but this "ageing" process in MSWI ash is still not well understood and additional research is needed. An improved understanding of the long-term behavior of MSWI ash, including the effects of moisture and ash chemical composition on the ageing process, as well as the leaching characteristics of the material, may promote unbound utilization of the ash in civil infrastructure. Copyright © 2013 Elsevier Ltd. All rights reserved.

Selenium bioaccumulation in fish exposed to coal ash at the Tennessee Valley Authority Kingston spill site.

PubMed

Mathews, Teresa J; Fortner, Allison M; Jett, R Trent; Morris, Jesse; Gable, Jennifer; Peterson, Mark J; Carriker, Neil

2014-10-01

In December 2008, 4.1 million cubic meters of coal ash were released into the Emory and Clinch Rivers by the Tennessee Valley Authority Kingston Fossil Plant. Coal ash contains several contaminants, including the bioaccumulative metalloid selenium (Se). Because Se is predominantly accumulated in aquatic organisms through dietary rather than aqueous exposure, tissue-based toxicity thresholds for Se are currently being considered. The proposed threshold concentrations range between 4 μg/g and 9 μg/g Se (dry wt.) in whole body fish, with a proposed fillet threshold of 11.8 μg/g. In the present study, the authors examined the spatial and temporal trends in Se bioaccumulation and examined the relationship between the Se content in fillets and in whole bodies of fish collected around the Kingston spill site to determine whether Se bioaccumulation was a significant concern at the ash spill site. Whereas Se concentrations in fish (whole bodies and fillets) were elevated at sampling locations affected by the Kingston ash spill relative to reference locations, concentrations do not appear to be above risk thresholds and have not been increasing over the 5-yr period since the spill. These findings are not only relevant to guiding the human health and ecological risk assessments at the Kingston ash spill site, but because of current national discussions on appropriate guidelines for Se in fish as well for the disposal of coal combustion wastes, the results are also relevant to the general understanding of Se bioaccumulation in contaminated water bodies. © 2014 SETAC.

Relationship between selenium body burdens and tissue concentrations in fish exposed to coal ash at the Tennessee Valley Authority Kingston spill site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mathews, Teresa J; Fortner, Allison M; Jett, Robert T

2014-01-01

In December 2008, 4.1 million m3 of coal ash were released into the Emory and Clinch Rivers by the Tennessee Valley Authority (TVA) Kingston Fossil Plant. Coal ash contains several contaminants, including the bioaccumulative metalloid selenium (Se). Because Se is predominantly accumulated in aquatic organisms through dietary, rather than aqueous exposure, tissue-based toxicity thresholds for Se are currently being considered. The proposed threshold concentrations range between 4-9 g/g Se (dry wt.) in whole body fish, with a proposed fillet threshold of 11.8 g/g. In the present study we examined the spatial and temporal trends in Se bioaccumulation and examined themore » relationship between the Se content in fillets and in whole bodies of fish collected around the Kingston spill site to determine whether Se bioaccumulation was a significant concern at the ash spill site. While Se concentrations in fish (whole bodies and fillets) were elevated at sampling locations affected by the Kingston ash spill relative to reference locations, concentrations do not appear to be above risk thresholds and have not been increasing over the five year period since the spill. Our results are not only relevant to guiding the human health and ecological risk assessments at the Kingston ash spill site, but because of current national discussions on appropriate guidelines for Se in fish as well for the disposal of coal combustion wastes, our results are also relevant to the general understanding of Se bioaccumulation in contaminated water bodies.« less

Perspective of Life Search in Martian Econiches

NASA Astrophysics Data System (ADS)

Demidov, N. E.

2017-05-01

Mars may be divided on five ecological niches according to presence and state of water: permanent polar caps, dry regolith, subpermafrost aquifers, cryopegs and ice containing regolith. Basic limiting factors for the search of life in this econiches are: absence of water (dry regolith), depth of burial (cryopegs and subpermafrost aquifers), age (ice containing permafrost and polar caps). High priority targets for the search of life on Mars are represented by permanently frozen deposits of young polar volcanoes and ash layers in polar caps. During volcanic eruptions microorganisms from subpermafrost aquifers could propagate to the surface and survive in permafrost or ice for million years, as it is known to happen on Earth. Possibility of specific lithic habitats in dry layer must also be taken into account.

Volcanic Ashes Intercalated with Cultural Vestiges at Archaeological Sites from the Piedmont to the Amazon, Ecuador

NASA Astrophysics Data System (ADS)

Valverde, Viviana; Mothes, Patricia; Andrade, Daniel

2014-05-01

A mineralogical analysis was done on 70 volcanic ashes; 9 corresponding to proximal samples of seven volcanoes: Cotopaxi (4500 yBP), Guagua Pichincha (3300 yBP, 1000 yBP and 1660 yAD), Cuicocha (3100 yBP), Pululahua (2400 yBP), Ninahuilca (2350 yBP and 4600 yBP) and 61 to distal ashes collected at eight archaeological sites in the Coastal, Sierra and Amazon regions of Ecuador. Cultural vestiges are from Pre-ceramic, Formative, Regional Development and Integration periods, with the exception of a site denominated Hacienda Malqui, which also has Inca vestiges. The sampling process was done in collaboration with various archaeologists in 2011-2013. The volcanic ashes were washed, dried and divided in order to obtain a representative fraction and their later analysis with binocular microscope. The microscope analysis allowed determination of the characteristics of each component of volcanic ash. These main elements are: pumice fragments, minerals, volcanic glass, lithics and exogenous material (non volcanic). The petrographic analysis of distal volcanic ash layers at each archaeological site was correlated by their components and characteristics with proximal volcanic ashes of source volcanoes. Some correlations permitted obtaining a relative age for the layers of distal volcanic ash in the archaeological sites. The petrographic analysis showed a correlation between the archaeological sites of Las Mercedes - Los Naranjos, Rumipamba and El Condado (located west of Quito) with the eruptive activity of Guagua Pichincha volcano (3300 yBP, 1000 yBP and 1660 yAD) and Pululahua volcano (2400 yBP). Also, a correlation with eruptive activity of Ninahuilca (2350 yBP), Cotopaxi (4500 yBP) and Quilotoa (800 yBP) volcanoes at Hda. Malqui (60 km west of Latacunga) was provided by mineralogy of the respective ashes expulsed by these volcanoes. The ash layers at Cuyuja (50 km east of Quito) are mostly superficial; they are associated with Quilotoa's 800 yBP plinian. Finally at the Huapula and Pablo VI sites (in the western Amazon region of Ecuador), the reworked ashes are predominantly of Sangay volcano (in permanent eruptive activity since 1628). Finally, the work shared between archaeologists and volcanologists allowed us to discover more deposits of volcanic ashes at archaeological sites. These layers sometimes have more than 30 cm thickness in distal regions, such as the thick ash layer left by Pululahua's 2400 yBP eruption, a fact which helps us to comprehend the impact of volcanoes on past cultures.

New-Generation Aluminum Composite with Bottom Ash Industrial Waste

NASA Astrophysics Data System (ADS)

Mandal, A. K.; Sinha, O. P.

2018-02-01

Industrial waste bottom ash (BA) from a pulverized coal combustion boiler containing hard wear-resistant particles was utilized in this study to form an aluminum composite through a liquid metallurgy route. Composites comprising 5 wt.% and 10 wt.% bottom ash were characterized for their physiochemical, microstructural, mechanical, as well as tribological properties, along with pure aluminum. Scanning electron microscopy (SEM) microstructure revealed uniform distribution of BA particles throughout the matrix of the composite, whereas x-ray diffraction (XRD) analysis confirmed presence of aluminosilicate phase. Addition of 10 wt.% BA improved the Brinell hardness number (BHN) from 13 to 19 and ultimate tensile strength (UTS) from 71 MPa to 87 MPa, whereas ductility was adversely reduced after 5% BA addition. Incorporation of BA particles resulted in reduced dry sliding wear rates examined up to 80 N load compared with aluminum. Hence, such composites having lower cost could be applied as significantly hard, wear-resistant materials in applications in the automotive industry.

Effects of pyrolysis temperature, time and leaf litter and powder coal ash addition on sludge-derived adsorbents for nitrogen oxide.

PubMed

Ren, Xiaoli; Liang, Baohong; Liu, Min; Xu, Xiaoyuan; Cui, Meihua

2012-12-01

The objective of this research was to seek a cost effective solution to prepare adsorbents for nitrogen oxide from surplus sludge. Leaf litter and powder coal ash were used as cheap and easily available additives. An adsorbent for nitrogen oxide was prepared by pyrolysis of dried sludge mixed with zinc chloride. Under optimum pyrolysis conditions of 375°C for 90 min and a zinc chloride content of 30%, the surface area of the adsorbent with leaf litter was 514.41 m(2)/g, the surface area of the adsorbent with powder coal ash was 432.34 m(2)/g, respectively, corresponding to an increase of 90.70% and 60.27% when compared to the adsorbent without the additives. The saturated adsorption quantity of the adsorbent with leaf litter reached 271 mg/g at 20°C. The results indicated that the sludge-derived adsorbent was quite promising for nitrogen oxide removal. Copyright © 2012 Elsevier Ltd. All rights reserved.

Use of Slag/Sugar Cane Bagasse Ash (SCBA) Blends in the Production of Alkali-Activated Materials

PubMed Central

Castaldelli, Vinícius N.; Akasaki, Jorge L.; Melges, José L.P.; Tashima, Mauro M.; Soriano, Lourdes; Borrachero, María V.; Monzó, José; Payá, Jordi

2013-01-01

Blast furnace slag (BFS)/sugar cane bagasse ash (SCBA) blends were assessed for the production of alkali-activated pastes and mortars. SCBA was collected from a lagoon in which wastes from a sugar cane industry were poured. After previous dry and grinding processes, SCBA was chemically characterized: it had a large percentage of organic matter (ca. 25%). Solutions of sodium hydroxide and sodium silicate were used as activating reagents. Different BFS/SCBA mixtures were studied, replacing part of the BFS by SCBA from 0 to 40% by weight. The mechanical strength of mortar was measured, obtaining values about 60 MPa of compressive strength for BFS/SCBA systems after 270 days of curing at 20 °C. Also, microstructural properties were assessed by means of SEM, TGA, XRD, pH, electrical conductivity, FTIR spectroscopy and MIP. Results showed a good stability of matrices developed by means of alkali-activation. It was demonstrated that sugar cane bagasse ash is an interesting source for preparing alkali-activated binders. PMID:28811425

New-Generation Aluminum Composite with Bottom Ash Industrial Waste

NASA Astrophysics Data System (ADS)

Mandal, A. K.; Sinha, O. P.

2018-06-01

Industrial waste bottom ash (BA) from a pulverized coal combustion boiler containing hard wear-resistant particles was utilized in this study to form an aluminum composite through a liquid metallurgy route. Composites comprising 5 wt.% and 10 wt.% bottom ash were characterized for their physiochemical, microstructural, mechanical, as well as tribological properties, along with pure aluminum. Scanning electron microscopy (SEM) microstructure revealed uniform distribution of BA particles throughout the matrix of the composite, whereas x-ray diffraction (XRD) analysis confirmed presence of aluminosilicate phase. Addition of 10 wt.% BA improved the Brinell hardness number (BHN) from 13 to 19 and ultimate tensile strength (UTS) from 71 MPa to 87 MPa, whereas ductility was adversely reduced after 5% BA addition. Incorporation of BA particles resulted in reduced dry sliding wear rates examined up to 80 N load compared with aluminum. Hence, such composites having lower cost could be applied as significantly hard, wear-resistant materials in applications in the automotive industry.

Extraction optimization and characterization of gelatine from fish dry skin of Spanish mackerel (Scomberromorus commersoni)

NASA Astrophysics Data System (ADS)

Kusumaningrum, I.; Pranoto, Y.; Hadiwiyoto, S.

2018-04-01

This work was to optimized gelatin extraction from dry skin of Spanish mackerel (Scomberromorus commersoni) using Response Surface Methodology (RSM). The aim of this study was to determine the optimal condition of temperature and time for extraction process and properties of the gelatin extracted from dry mackerel skin. The optimal condition for extraction was 59.71°C for 4.25 hours. Results showed that predicted yield by RSM was 13.69% and predicted gel strength was 291.93 Bloom, whereas the actual experiment for yield and gel strength were 13.03% and 291.33 Bloom, respectively. The gelatin extracted from dried skin were analyzed for their proximate composition, yield, gel strength, viscosity, color, and amino acid composition. The results of dried skin gelatin properties compared to the commercial gelatin. Gelatin extracted from the dried skin gave content lower moisture, ash and protein content but higher fat compared to commercial gelatin. This study also shows that the gelatin extracted from the dried skin gave higher gel strength and pH but the lower amino acid composition compared to commercial gelatin.

Quality Indexes and Feasibility Analysis of Traditional Dried Anchovy From Buru Island

NASA Astrophysics Data System (ADS)

Krisanta Enda Savitri, Imelda; Sormin, R. B. D.; Silaban, Bernita

2017-10-01

Dried anchovy is a prominent fishery product in Buru Island Maluku. It is produce traditionally in villages Batuboi and Siahoni at Kayeli bay. Drying process was done in open air under the sun directly during two days to produce dried anchovy with a prospective marketable. This preliminary research was aimed to investigated the quality indexes and business feasibility of dried anchovy produced by processor comunity. The quality index was found by laboratory analysis of sample dried anchovy referring to Indonesian National Standard. The data for feasibility analysis was found by interview and by using quesioner list. The average Quality indexes of dried anchovy as follows: Water 14.22 grams percent; Protein 55.68 grams percent; Fat 2.29 grams percent; Ash 9.02 grams percent; Total Bacteri (TPC) 3,5 × 102-; organoleptic value 7.79; E. coli, Salmonella and Mold were unidentified. Total cost of dried anchovy production is 37,050,720 Rupiahs/year with the income was 224,000,000 Rupiahs/year. Total profit is 217,824,880 Rupiahs/year and the Revenue Cost ratio was 6.05. Dried anchovy from Buru Island has a good quality and also has a good business feasibility.

Supply of avocado starch (Persea americana mill) as bioplastic material

NASA Astrophysics Data System (ADS)

Ginting, M. H. S.; Hasibuan, R.; Lubis, M.; Alanjani, F.; Winoto, F. A.; Siregar, R. C.

2018-02-01

The purpose of this study was to determine the effect of time precipitation of avocado slurry seed to yield of starch. Starch analysis included starch content, moisture content, amylose content, amylopectin content, ash content, protein content, fat content, Fourier transform infra red analysis and rapid visco analyzer. Supply of starch from avocado seeds was used by extraction method. Every one hundred grams of avocado slurry was precipitated by gravity with variations for 4 hours, 8 hours, 12 hours, 16 hours, 20 hours and 24 hours. The Starch yield was washed, and dried using oven at 70°C for 30 minutes. Starch yield was the highest as 24.20 gram at 24 hours. The result of starch characterization was 73.62%, water content 16.6%, amylose 0.07%, amylopectin 73.55%, ash content 0.23%, protein content 2.16%, fat content 1.09%. Rapid visco analyzer obtained at 91.33°C of gelatinization temperature. Scanning electron microscopy analyzes obtained 20 μm oval-shaped starch granules. Fourier Transform Infra Red analysis of starch obtained the peak spectrum of O-H group of alcohols, C-H alkanes and C-O ether.

Effects of cooking methods and temperatures on nutritional and quality characteristics of anchovy (Engraulis encrasicholus).

PubMed

Uran, Harun; Gokoglu, Nalan

2014-04-01

The aim of this study was to determine the nutritional and quality characteristics of anchovy after cooking. The fish were cooked by different methods (frying, baking and grilling) at two different temperatures (160 °C, 180 °C). Crude ash, crude protein and crude fat contents of cooked fish increased due to rise in dry matter contents. While cooking methods affected mineral content of anchovy, cooking temperature did not affect. The highest values of monounsaturated fatty acids were found in baked samples. Polyunsaturated fatty acids in baked samples were also high and similar in fried samples. Fried samples, which were the most preferred, lost its nutritional characteristics more than baked and grilled samples. Grilled and baked fish samples can be recommended for healthy consumption. However, grilled fish samples had hard texture due to more moisture loss than other methods. Therefore, it is concluded that baking is the best cooking method for anchovy.

Molecular recognition of emerald ash borer infestation using leaf spray mass spectrometry.

PubMed

Falcone, Caitlin E; Cooks, R Graham

2016-06-15

The introduction of the emerald ash borer (Agrilus planipennis) (EAB) from Asia to Michigan, USA, in the 1990s caused the widespread death of ash trees in two Canadian provinces and 24 US states. The three current methods for the detection of emerald ash borer infestation, visual surveys, tree girdling and artificial traps, can be unreliable, and there is clearly a need for a rapid, dependable technique for the detection of emerald ash borer infestation. Leaf spray, an ambient ionization method for mass spectrometry (MS), gives direct chemical information on a leaf sample by applying a high voltage to a naturally or artificially sharply pointed leaf piece causing ions to be generated directly from the leaf tip for MS analysis. Leaflets from 23 healthy and EAB-infested ash trees were analyzed by leaf spray mass spectrometry in an attempt to distinguish healthy and EAB-infested ash trees. In negative ion mode, healthy ash trees showed an increased abundance of ions m/z 455.5, 471.5 and 487.5, and ash trees infested with the EAB displayed an increased abundance of ions m/z 181 and 217. The identities of the chemical discriminators ursolic acid and oleanolic acid in healthy ash trees, and six-carbon sugar alcohols in infested ash trees, were determined by tandem mass spectrometry and confirmed with standards. This preliminary study suggests that leaf spray mass spectrometry of ash tree leaflets provides a potential tool for the early detection of ash tree infestation by the emerald ash borer. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Methods for studying emerald ash borer parasitoids in the field

Treesearch

Leah Bauer; Jian Duan; Juli Gould; Kristopher Abell; Deborah Miller; Jason Hansen; Roy. Van Driesche

2011-01-01

The emerald ash borer (EAB), Agrilus planipennis (Coleoptera: Buprestidae), is an invasive phloemfeeding beetle from Asia that attacks ash (Fraxinus spp.) trees. EAB was determined to be the cause of extensive ash tree mortality throughout southeast Michigan and nearby Ontario in 2002. For several years, regulatory agencies...

The 1963–65 eruption of Irazú volcano, Costa Rica (the period of March 1963 to October 1964)

USGS Publications Warehouse

Murata, K.J.; Dondoli, C.; Saenz, R.

1966-01-01

The ash section was about 2 meters thick, 800 meters downwind from the vent in June 1964. In the section, deposits of the rainy season could be distinguished by their well developed stratification from those of the dry season. A zone containing three persistent pumice horizons represents the climactic period of December 1963 to January 1964. The cloudburst of December 10, 1963 is recorded by a highly rilled surface, and the strong winds of the dry season of 1964 are indicated by a rippled lag deposit.

Size matters: relationships between body size and body mass of common coastal, aquatic invertebrates in the Baltic Sea.

PubMed

Eklöf, Johan; Austin, Åsa; Bergström, Ulf; Donadi, Serena; Eriksson, Britas D H K; Hansen, Joakim; Sundblad, Göran

2017-01-01

Organism biomass is one of the most important variables in ecological studies, making biomass estimations one of the most common laboratory tasks. Biomass of small macroinvertebrates is usually estimated as dry mass or ash-free dry mass (hereafter 'DM' vs. 'AFDM') per sample; a laborious and time consuming process, that often can be speeded up using easily measured and reliable proxy variables like body size or wet (fresh) mass. Another common way of estimating AFDM (one of the most accurate but also time-consuming estimates of biologically active tissue mass) is the use of AFDM/DM ratios as conversion factors. So far, however, these ratios typically ignore the possibility that the relative mass of biologically active vs. non-active support tissue (e.g., protective exoskeleton or shell)-and therefore, also AFDM/DM ratios-may change with body size, as previously shown for taxa like spiders, vertebrates and trees. We collected aquatic, epibenthic macroinvertebrates (>1 mm) in 32 shallow bays along a 360 km stretch of the Swedish coast along the Baltic Sea; one of the largest brackish water bodies on Earth. We then estimated statistical relationships between the body size (length or height in mm), body dry mass and ash-free dry mass for 14 of the most common taxa; five gastropods, three bivalves, three crustaceans and three insect larvae. Finally, we statistically estimated the potential influence of body size on the AFDM/DM ratio per taxon. For most taxa, non-linear regression models describing the power relationship between body size and (i) DM and (ii) AFDM fit the data well (as indicated by low SE and high R 2 ). Moreover, for more than half of the taxa studied (including the vast majority of the shelled molluscs), body size had a negative influence on organism AFDM/DM ratios. The good fit of the modelled power relationships suggests that the constants reported here can be used to quickly estimate organism dry- and ash-free dry mass based on body size, thereby freeing up considerable work resources. However, the considerable differences in constants between taxa emphasize the need for taxon-specific relationships, and the potential dangers associated with ignoring body size. The negative influence of body size on the AFDM/DM ratio found in a majority of the molluscs could be caused by increasingly thicker shells with organism age, and/or spawning-induced loss of biologically active tissue in adults. Consequently, future studies utilizing AFDM/DM (and presumably also AFDM/wet mass) ratios should carefully assess the potential influence of body size to ensure more reliable estimates of organism body mass.

Wisconsin's forest resources in 2001.

Treesearch

John S. Vissage; Gery J. Brand; Manfred E. Mielke

2003-01-01

Results of the 2001 annual inventory of Wisconsin show about 15.8 million acres of forest land, more than 21.6 billion cubic feet of live volume on forest land, and nearly 584 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and white pine blister rust...

Wisconsin's forest resources in 2002.

Treesearch

John S. Vissage; Gary J. Brand; Manfred E. Mielke

2004-01-01

Results of the 2002 annual inventory of Wisconsin show about 16.0 million acres of forest land, over 22.2 billion cubic feet of live volume on forest land, and nearly 598 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and white pine blister rust were...

Development of RNAi method for screening candidate genes to control emerald ash borer, Agrilus planipennis

USDA-ARS?s Scientific Manuscript database

Emerald ash borer (EAB), a serious invasive forest pest in the United States, has killed millions of North American ash trees and spread to 29 states since it was first detected in 2002 in southern Michigan. Development of a new control method that specifically targets the pest but has no adverse i...

Concentration of heavy metals in ash produced from Lithuanian forests

NASA Astrophysics Data System (ADS)

Baltrenaite, Edita; Pereira, Paulo; Butkus, Donatas; Úbeda, Xavier

2010-05-01

Wood ash contains important amounts of heavy metals. This quantity depends on burned specie, temperature of exposition and heat duration time. Due the high mineralization imposed by the temperatures, ash is used as lime product in agriculture and forests. Also, after a forest fire large quantities of ash are produced and distributed in soil surface. This mineralized organic matter can induce important environmental problems, including soil toxicity provoked by heavy metals leachates from ash. There is an extensive literature about heavy metals contents on ash in different species. However, it recently highlighted that the same species placed in different environments can respond diversely to same temperatures. This question is of major importance because temperature effects on severity can be a function of the plant communities instead of specie characteristics. These findings add a higher degree of complexity in the understanding of temperature effects on ash composition and consequent availability of heavy metals. The aim of this study is to compare the ash chemical heavy metal composition, Cobalt (Co), Chromium (Cr), Cooper (Cu), Silver (Ag), Lead (Pb), Nickel (Ni), Manganese (Mn) and Zinc (Zn), from Pinus sylvestris and Betula pendula, collected in key and representative areas of Lithuanian forests, located in southern, coastal and central part. Samples were collected from alive trees, taken to laboratory and air dried. Subsequently were crushed and submitted to muffle furnace at temperature of 550°C during two hours. The ash samples were digested and in a HNO3-HCl solution and then analysed with AAS. Comparisons between species and sites were performed with a Non-parametric one-way ANOVA‘s on rank transformed data followed by Tukey‘s HSD, significant at a p<0.05. Results showed significant difference between Co and Ag concentrations between Pinus sylvestris and Betula pendula. Also, significantly different concentrations of Pb, Cu, Ni and Mn were determined among investigated sites. No significant difference was found for Zn and Cr among investigated sites. Variation of metals between sites and stands can be explained by their age, flammability difference between plant communities and anthropogenic heavy metal load. These and other aspects will be discussed with more detail in the communication.

Experimental volcanic ash aggregation: Internal structuring of accretionary lapilli and the role of liquid bonding

NASA Astrophysics Data System (ADS)

Mueller, Sebastian B.; Kueppers, Ulrich; Ayris, Paul M.; Jacob, Michael; Dingwell, Donald B.

2016-01-01

Explosive volcanic eruptions can release vast quantities of pyroclastic material into Earth's atmosphere, including volcanic ash, particles with diameters less than two millimeters. Ash particles can cluster together to form aggregates, in some cases reaching up to several centimeters in size. Aggregation alters ash transport and settling behavior compared to un-aggregated particles, influencing ash distribution and deposit stratigraphy. Accretionary lapilli, the most commonly preserved type of aggregates within the geologic record, can exhibit complex internal stratigraphy. The processes involved in the formation and preservation of these aggregates remain poorly constrained quantitatively. In this study, we simulate the variable gas-particle flow conditions which may be encountered within eruption plumes and pyroclastic density currents via laboratory experiments using the ProCell Lab System® of Glatt Ingenieurtechnik GmbH. In this apparatus, solid particles are set into motion in a fluidized bed over a range of well-controlled boundary conditions (particle concentration, air flow rate, gas temperature, humidity, liquid composition). Experiments were conducted with soda-lime glass beads and natural volcanic ash particles under a range of experimental conditions. Both glass beads and volcanic ash exhibited the capacity for aggregation, but stable aggregates could only be produced when materials were coated with high but volcanically-relevant concentrations of NaCl. The growth and structure of aggregates was dependent on the initial granulometry, while the rate of aggregate formation increased exponentially with increasing relative humidity (12-45% RH), before overwetting promoted mud droplet formation. Notably, by use of a broad granulometry, we generated spherical, internally structured aggregates similar to some accretionary pellets found in volcanic deposits. Adaptation of a powder-technology model offers an explanation for the origin of natural accretionary pellets, suggesting them to be the result of a particular granulometry and fast-acting selective aggregation processes. For such aggregates to survive deposition and be preserved in the deposits of eruption plumes and pyroclastic density currents likely requires a significant pre-existing salt load on ash surfaces, and rapid aggregate drying prior to deposition or interaction with a more energetic environment. Our results carry clear benefits for future efforts to parameterize models of ash transport and deposition in the field.

Assessment of the exposure of islanders to ash from the Soufriere Hills volcano, Montserrat, British West Indies.

PubMed

Searl, A; Nicholl, A; Baxter, P J

2002-08-01

The Soufriere Hills volcano, Montserrat, has been erupting since July 1995 and volcanic ash has fallen on the island throughout most of the eruption. The ash contains substantial quantities of respirable particles and unusually large amounts (15-20%) of the crystalline silica mineral, cristobalite. The purpose of the surveys described here, undertaken between December 1996 and April 2000, was to determine levels of personal exposure of islanders to volcanic ash and cristobalite in order to inform advice on the associated risks to health and the measures required to reduce exposure. Surveys of personal exposure to respirable dust and cristobalite were undertaken using cyclone samplers. In addition, direct reading instruments (DUSTTRAK) were used to monitor ambient air concentrations of PM(10) at fixed sites and also to provide information about exposures to airborne particles associated with selected activities. Environmental concentrations of airborne ash have been greatest in the areas where the most ash has been deposited and during dry weather. Individual exposure to airborne ash was related to occupation, with the highest exposures among gardeners, cleaners, roadworkers, and police at roadside checkpoints. During 1997 many of these individuals were exposed to concentrations of cristobalite that exceeded the ACGIH recommended occupational exposure limit. Since the population became confined to the north of the island in October 1997, even those in relatively dusty occupations have received exposures to cristobalite well below this limit. Most of the 4500 people who have remained on island since the eruption began have not been exposed to sufficiently high concentrations of airborne dust for long enough to be at risk of developing silicosis. However, more than a dozen individuals continued to experience frequent high occupational exposures to volcanic ash, some of whom may have had sufficient exposure to crystalline silica to be at risk of developing mild silicosis. If volcanic activity were to deposit further ash over the occupied areas of the island during the coming years, the risks of silicosis will become more substantial.

Characterization of polycyclic aromatic hydrocarbons and metals in ashes released from a forest fire

NASA Astrophysics Data System (ADS)

Campos, I.; Abrantes, N.; Pereira, P.; Vale, C.; Ferreira, A.; Keizer, J. J.

2012-04-01

Wildfires have become a permanent source of environmental and societal concerns. Whilst the impacts of wildfire on hydrological and erosion processes are well documented, the stocks and export of polycyclic aromatic hydrocarbons (PAHs) and heavy metals have received considerably less research attention. The ashes produced by wildfires, which include polluting substances such as PAHs and metals, are subject to transport processes by wind and especially by overland flow and water infiltrating into the soil and possibly reaching ground water bodies. In the framework of the FIRECNUTS project, we are studying the stocks of PAHs and selected metals in recently burnt forest stands in north-central Portugal, and their subsequent export by overland flow. The present work, however, will focus on the stocks in the ashes, both immediately after wildfire and three months later. These ashes were collected at two burnt slopes with contrasting forest types, i.e. a eucalypt and a maritime pine stand, the two pre-dominant forest types in the study region. The sixteen PAHs identified by US EPA as priority contaminants were analysed by gas chromatograph, after extraction and column clean up. The contents of vanadium (V), chromium (Cr), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), cadmium (Cd) and lead (Pb) were analysed by inductively coupled plasma- mass spectrometry (ICP-MS), after an acid digestion, while mercury (Hg) was analysed by pyrolysis atomic absorption spectrometry with gold amalgamation. The total concentration of PAHs immediately after the wildfire ranged from 314 ng/g dry weight in the maritime pine stand to 597 ng/g dry weight in the eucalypt stand. Three months later, the total concentration has decreased with 33% in the pine stand but only half (16%) in the eucalypt stand. The composition the PAHs by ring size was dominated by three-rings PAHs. This was true for all samples. The concentrations of various metals differed for the two sampling occasions but not in straightforward manners. Some metals (Co, Ni, Cu, Zn, Cd, Pb and Hg) revealed higher contents immediately after the fire, whereas others (V, Cr and As) did three months later. The present results underline the importance of furthering the knowledge about contamination of soil and water by ashes from wildfires and the associated risks in terms of ecotoxicological effects, both in-situ and in downstream aquatic systems. Keywords: Polycyclic aromatic hydrocarbons (PAH); heavy metals; stocks; ash; wildfires

Physico-chemical characteristics of microwave-dried wheat distillers grain with solubles.

PubMed

Mosqueda, Maria Rosario P; Tabil, Lope G; Meda, Venkatesh

2013-01-01

Laboratory-prepared samples of wheat distillers grain with solubles with varying condensed distillers solubles (CDS) content were dried under varying microwave power, and microwave convection settings using a domestic microwave oven to examine their effect on the chemical, structural, color, flow, compression, thermal, and frictional properties of the product, which is dried distillers grain with solubles (DDGS). As CDS level increased, protein and ash content increased, while fat and fiber content decreased in wheat-based DDGS. Fat content was also markedly effected by the microwave oven drying conditions. While CDS level, microwave power or microwave convection setting, and/or their interactions significantly effected a number of physical properties; results indicated that CDS level had a stronger influence compared to the other factors. DDGS samples with high CDS levels were significantly denser, finer but more differentiated in size, less flowable, and less dispersible. These also produced denser and stronger pellets.

Detection of copper, lead, cadmium and iron in wine using electronic tongue sensor system.

PubMed

Simões da Costa, A M; Delgadillo, I; Rudnitskaya, A

2014-11-01

An array of 10 potentiometric chemical sensors has been applied to the detection of total Fe, Cu, Pb and Cd content in digested wine. As digestion of organic matter of wine is necessary prior to the trace metal detection using potentiometric sensors, sample preparation procedures have been optimized. Different variants of wet and microwave digestion and dry ashing, 14 conditions in total, have been tested. Decomposition of organic matter was assessed using Fourier transform mid-infrared spectroscopy and total phenolic content. Dry ashing was found to be the most effective method of wine digestion. Measurements with sensors in individual solutions of Fe(III), Cu(II), Pb(II) and Cd(II) prepared on different backgrounds have shown that their detection limits were below typical concentration levels of these metals in wines and, in the case of Cu, Pb and Cd below maximum allowed concentrations. Detection of Fe in digested wine samples was possible using discrete iron-sensitive sensors with chalcogenide glass membranes with RMSEP of 0.05 mmol L(-1) in the concentration range from 0.0786 to 0.472 mmol L(-1). Low concentration levels of Cu, Pb and Cd in wine and cross-sensitivity of respective sensors resulted in the non-linearity of their responses, requiring back-propagation neural network for the calibration. Calibration models have been calculated using measurements in the model mixed solutions containing all three metals and a set of digested wine sample. RMSEP values for Cu, Pb and Cd were 3.9, 39 and 1.2 μmol L(-1) in model solutions and 2, 150 and 1 μmol L(-1) in digested wine samples. Copyright © 2014 Elsevier B.V. All rights reserved.

Reference point indentation is insufficient for detecting alterations in traditional mechanical properties of bone under common experimental conditions.

PubMed

Krege, John B; Aref, Mohammad W; McNerny, Erin; Wallace, Joseph M; Organ, Jason M; Allen, Matthew R

2016-06-01

Reference point indentation (RPI) was developed as a novel method to assess mechanical properties of bone in vivo, yet it remains unclear what aspects of bone dictate changes/differences in RPI-based parameters. The main RPI parameter, indentation distance increase (IDI), has been proposed to be inversely related to the ability of bone to form/tolerate damage. The goal of this work was to explore the relationshipre-intervention RPI measurebetween RPI parameters and traditional mechanical properties under varying experimental conditions (drying and ashing bones to increase brittleness, demineralizing bones and soaking in raloxifene to decrease brittleness). Beams were machined from cadaveric bone, pre-tested with RPI, subjected to experimental manipulation, post-tested with RPI, and then subjected to four-point bending to failure. Drying and ashing significantly reduced RPI's IDI, as well as ultimate load (UL), and energy absorption measured from bending tests. Demineralization increased IDI with minimal change to bending properties. Ex vivo soaking in raloxifene had no effect on IDI but tended to enhance post-yield behavior at the structural level. These data challenge the paradigm of an inverse relationship between IDI and bone toughness, both through correlation analyses and in the individual experiments where divergent patterns of altered IDI and mechanical properties were noted. Based on these results, we conclude that RPI measurements alone, as compared to bending tests, are insufficient to reach conclusions regarding mechanical properties of bone. This proves problematic for the potential clinical use of RPI measurements in determining fracture risk for a single patient, as it is not currently clear that there is an IDI, or even a trend of IDI, that can determine clinically relevant changes in tissue properties that may contribute to whole bone fracture resistance. Copyright © 2016 Elsevier Inc. All rights reserved.

Reference point indentation is insufficient for detecting alterations in traditional mechanical properties of bone under common experimental conditions

PubMed Central

Krege, John B.; Aref, Mohammad W.; McNerny, Erin; Wallace, Joseph M.; Organ, Jason M.; Allen, Matthew R.

2016-01-01

Reference point indentation (RPI) was developed as a novel method to assess mechanical properties of bone in vivo, yet it remains unclear what aspects of bone dictate changes/differences in RPI-based parameters. The main RPI parameter, indentation distance increase (IDI), has been proposed to be inversely related to the ability of bone to form/tolerate damage. The goal of this work was to explore the relationship between RPI parameters and traditional mechanical properties under varying experimental conditions (drying and ashing bones to increase brittleness, demineralizing bones and soaking in raloxifene to decrease brittleness). Beams were machined from cadaveric bone, pre-tested with RPI, subjected to experimental manipulation, post-tested with RPI, and then subjected to four-point bending to failure. Drying and ashing significantly reduced RPI’s IDI, as well as ultimate load (UL), and energy absorption measured from bending tests. Demineralization increased IDI with minimal change to bending properties. Ex vivo soaking in raloxifene had no effect on IDI but tended to enhance post-yield behavior at the structural level. These data challenge the paradigm of an inverse relationship between IDI and bone toughness, both through correlation analyses and in the individual experiments where divergent patterns of altered IDI and mechanical properties were noted. Based on these results, we conclude that RPI measurements alone, as compared to bending tests, are insufficient to reach conclusions regarding mechanical properties of bone. This proves problematic for the potential clinical use of RPI measurements in determining fracture risk for a single patient, as it is not currently clear that there is an IDI, or even a trend of IDI, that can determine clinically relevant changes in tissue properties that may contribute to whole bone fracture resistance. PMID:27072518

A robust method to forecast volcanic ash clouds

USGS Publications Warehouse

Denlinger, Roger P.; Pavolonis, Mike; Sieglaff, Justin

2012-01-01

Ash clouds emanating from volcanic eruption columns often form trails of ash extending thousands of kilometers through the Earth's atmosphere, disrupting air traffic and posing a significant hazard to air travel. To mitigate such hazards, the community charged with reducing flight risk must accurately assess risk of ash ingestion for any flight path and provide robust forecasts of volcanic ash dispersal. In response to this need, a number of different transport models have been developed for this purpose and applied to recent eruptions, providing a means to assess uncertainty in forecasts. Here we provide a framework for optimal forecasts and their uncertainties given any model and any observational data. This involves random sampling of the probability distributions of input (source) parameters to a transport model and iteratively running the model with different inputs, each time assessing the predictions that the model makes about ash dispersal by direct comparison with satellite data. The results of these comparisons are embodied in a likelihood function whose maximum corresponds to the minimum misfit between model output and observations. Bayes theorem is then used to determine a normalized posterior probability distribution and from that a forecast of future uncertainty in ash dispersal. The nature of ash clouds in heterogeneous wind fields creates a strong maximum likelihood estimate in which most of the probability is localized to narrow ranges of model source parameters. This property is used here to accelerate probability assessment, producing a method to rapidly generate a prediction of future ash concentrations and their distribution based upon assimilation of satellite data as well as model and data uncertainties. Applying this method to the recent eruption of Eyjafjallajökull in Iceland, we show that the 3 and 6 h forecasts of ash cloud location probability encompassed the location of observed satellite-determined ash cloud loads, providing an efficient means to assess all of the hazards associated with these ash clouds.

Determination of cadmium in urine by extraction and flameless atomic-absorption spectrophotometry Comparison of urine from smokers and non-smokers of different sex and age.

PubMed

Jawaid, M; Lind, B; Elinder, C G

1983-07-01

A method is presented for determining cadmium in urine by nameless atomic-absorption spectrophotometry after extraction. The sample is dried, ashed in the presence of nitric acid, and then the residue is dissolved in hydrochloric acid. Cadmium is extracted as its tetrahexylammonium iodide complex into methyl isobutyl ketone. The organic phase is analysed for cadmium by atomic-absorption spectrophotometry with electrothermal atomization. The median urinary excretion of cadmium for smokers aged 50-64 has been found to be 0.7 and 0.75 mug l . for males and females respectively, the values for non-smokers being 0.25 and 0.4mug l .

Effects of sodium hydroxide (NaOH) solution concentration on fly ash-based lightweight geopolymer

NASA Astrophysics Data System (ADS)

Ibrahim, W. M. W.; Hussin, K.; Abdullah, M. M. A.; Kadir, A. A.; Deraman, L. M.

2017-09-01

In this study, the effects of NaOH concentration on properties of fly ash-based lightweight geopolymer were investigated. Lightweight geopolymer was produced using fly ash as source materials and synthetic foaming agents as air entraining agent. The alkaline solutions used in this study are combination of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) solution. Different molarities of NaOH solution (6M, 8M, 10M, 12M, and 14M) are taken for preparation of 50 x 50 x 50 mm cubes of lightweight geopolymer. The ratio of fly ash/alkaline solution, Na2SiO3/NaOH solution, foaming agent/water and foam/geopolymer paste were kept constant at 2.0, 2.5, 1:10 and 1:1 respectively. The samples were cured at 80°C for 24 hours and left at room temperature for tested at 7 days of ageing. Physical and mechanical properties such as density, water absorption, compressive strength and microstructure property were determined from the cube dried samples. The results show that the NaOH molarity had effects on the properties of lightweight geopolymer with the optimum NaOH molarity found is 12M due to the high strength of 15.6 MPa, lower water absorption (7.3%) and low density (1440 kg/m3). Microstructure analysis shows that the lightweight geopolymer contain some porous structure and unreacted fly ash particles remains.

Ability of natural attenuation and phytoremediation using maize (Zea mays L.) to decrease soil contents of polycyclic aromatic hydrocarbons (PAHs) derived from biomass fly ash in comparison with PAHs-spiked soil.

PubMed

Košnář, Zdeněk; Mercl, Filip; Tlustoš, Pavel

2018-05-30

A 120-day pot experiment was conducted to compare the ability of natural attenuation and phytoremediation approaches to remove polycyclic aromatic hydrocarbons (PAHs) from soil amended with PAHs-contaminated biomass fly ash. The PAH removal from ash-treated soil was compared with PAHs-spiked soil. The removal of 16 individual PAHs from soil ranged between 4.8% and 87.8% within the experiment. The natural attenuation approach led to a negligible total PAH removal. The phytoremediation was the most efficient approach for PAH removal, while the highest removal was observed in the case of ash-treated soil. The content of low molecular weight (LMW) PAHs and the total PAHs in this treatment significantly decreased (P <.05) over the whole experiment by 47.6% and 29.4%, respectively. The tested level of PAH soil contamination (~1600 µg PAH/kg soil dry weight) had no adverse effects on maize growth as well on the biomass yield. In addition, the PAHs were detected only in maize roots and their bioaccumulation factors were significantly lower than 1 suggesting negligible PAH uptake from soil by maize roots. The results showed that PAHs of ash origin were similarly susceptible to removal as spiked PAHs. The presence of maize significantly boosted the PAH removal from soil and its aboveground biomass did not represent any environmental risk. Copyright © 2018 Elsevier Inc. All rights reserved.

Dry matter losses and quality changes during short rotation coppice willow storage in chip or rod form.

PubMed

Whittaker, Carly; Yates, Nicola E; Powers, Stephen J; Misselbrook, Tom; Shield, Ian

2018-05-01

This study compares dry matter losses and quality changes during the storage of SRC willow as chips and as rods. A wood chip stack consisting of approximately 74 tonnes of fresh biomass, or 31 tonnes dry matter (DM) was built after harvesting in the spring. Three weeks later, four smaller stacks of rods with an average weight of 0.8 tonnes, or 0.4 tonnes DM were built. During the course of the experiment temperature recorders placed in the stacks found that the wood chip pile reached 60 °C within 10 days of construction, but the piles of rods remained mostly at ambient temperatures. Dry matter losses were calculated by using pre-weighed independent samples within the stacks and by weighing the whole stack before and after storage. After 6 months the wood chip stack showed a DM loss of between 19.8 and 22.6%, and mean losses of 23.1% were measured from the 17 independent samples. In comparison, the rod stacks showed an average stack DM loss of between 0 and 9%, and between 1.4% and 10.6% loss from the independent samples. Analysis of the stored material suggests that storing willow in small piles of rods produces a higher quality fuel in terms of lower moisture and ash content; however, it has a higher fine content compared to storage in chip form. Therefore, according to the two storage methods tested here, there may be a compromise between maximising the net dry matter yield from SRC willow and the final fine content of the fuel.

Impedance Spectroscopy Study of the Effect of Environmental Conditions on the Microstructure Development of Sustainable Fly Ash Cement Mortars.

PubMed

Ortega, José Marcos; Sánchez, Isidro; Climent, Miguel Ángel

2017-09-25

Today, the characterisation of the microstructure of cement-based materials using non-destructive techniques has become an important topic of study, and among them, the impedance spectroscopy has recently experienced great progress. In this research, mortars with two different contents of fly ash were exposed to four different constant temperature and relative humidity environments during a 180-day period. The evolution of their microstructure was studied using impedance spectroscopy, whose results were contrasted with mercury intrusion porosimetry. The hardening environment has an influence on the microstructure of fly ash cement mortars. On one hand, the impedance resistances R₁ and R₂ are more influenced by the drying of the materials than by microstructure development, so they are not suitable for following the evolution of the porous network under non-optimum conditions. On the other hand, the impedance spectroscopy capacitances C₁ and C₂ allow studying the microstructure development of fly ash cement mortars exposed to those conditions, and their results are in accordance with mercury intrusion porosimetry ones. Finally, it has been observed that the combined analysis of the abovementioned capacitances could be very useful for studying shrinkage processes in cement-based materials kept in low relative humidity environments.

Optimizing use of girdled ash trees for management of low-density emerald ash borer (Coleoptera: Buprestidae) populations

Treesearch

Nathan W. Siegert; Deborah G. McCullough; Therese M. Poland; Robert L. Heyd

2017-01-01

Effective survey methods to detect and monitor recently established, low-density infestations of emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), remain a high priority because they provide land managers and property owners with time to implement tactics to slow emerald ash borer population growth and the progression of...

Studies of fly ash using thermal analysis techniques

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Hanxu; Shen, Xiang-Zhong; Sisk, B.

1996-12-31

Improved thermoanalytical methods have been developed that are capable of quantitative identification of various components of fly ash from a laboratory-scale fluidized bed combustion system. The thermogravimetric procedure developed can determine quantities of H{sub 2}O, Ca(OH){sub 2}, CaCO{sub 3}, CaSO{sub 4} and carbonaceous matter in fly ash with accuracy comparable to more time-consuming ASTM methods. This procedure is a modification of the Mikhail-Turcotte methods that can accurately analyze bed ash, with higher accuracy regarding the greater amount of carbonaceous matter in fly ash. In addition, in conjunction with FTIR and SEM/EDS analysis, the reduction mechanism of CaSO{sub 4} as CaSO{submore » 4} + 4H{sub 2} = CaS + 4H{sub 2}O has been confirmed in this study. This mechanism is important in analyzing and evaluating sulfur capture in fluidized-bed combustion systems.« less

A Bayesian method to rank different model forecasts of the same volcanic ash cloud: Chapter 24

USGS Publications Warehouse

Denlinger, Roger P.; Webley, P.; Mastin, Larry G.; Schwaiger, Hans F.

2012-01-01

Volcanic eruptions often spew fine ash high into the atmosphere, where it is carried downwind, forming long ash clouds that disrupt air traffic and pose a hazard to air travel. To mitigate such hazards, the community studying ash hazards must assess risk of ash ingestion for any flight path and provide robust and accurate forecasts of volcanic ash dispersal. We provide a quantitative and objective method to evaluate the efficacy of ash dispersal estimates from different models, using Bayes theorem to assess the predictions that each model makes about ash dispersal. We incorporate model and measurement uncertainty and produce a posterior probability for model input parameters. The integral of the posterior over all possible combinations of model inputs determines the evidence for each model and is used to compare models. We compare two different types of transport models, an Eulerian model (Ash3d) and a Langrangian model (PUFF), as applied to the 2010 eruptions of Eyjafjallajökull volcano in Iceland. The evidence for each model benefits from common physical characteristics of ash dispersal from an eruption column and provides a measure of how well each model forecasts cloud transport. Given the complexity of the wind fields, we find that the differences between these models depend upon the differences in the way the models disperse ash into the wind from the source plume. With continued observation, the accuracy of the estimates made by each model increases, increasing the efficacy of each model’s ability to simulate ash dispersal.

Characterization of post-fire surface cover, soils, and burn severity at the Cerro Grande Fire, New Mexico, using hyperspectral and multispectral remote sensing

USGS Publications Warehouse

Kokaly, R.F.; Rockwell, B.W.; Haire, S.L.; King, T.V.V.

2007-01-01

Forest fires leave behind a changed ecosystem with a patchwork of surface cover that includes ash, charred organic matter, soils and soil minerals, and dead, damaged, and living vegetation. The distributions of these materials affect post-fire processes of erosion, nutrient cycling, and vegetation regrowth. We analyzed high spatial resolution (2.4??m pixel size) Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data collected over the Cerro Grande fire, to map post-fire surface cover into 10 classes, including ash, soil minerals, scorched conifer trees, and green vegetation. The Cerro Grande fire occurred near Los Alamos, New Mexico, in May 2000. The AVIRIS data were collected September 3, 2000. The surface cover map revealed complex patterns of ash, iron oxide minerals, and clay minerals in areas of complete combustion. Scorched conifer trees, which retained dry needles heated by the fire but not fully combusted by the flames, were found to cover much of the post-fire landscape. These scorched trees were found in narrow zones at the edges of completely burned areas. A surface cover map was also made using Landsat Enhanced Thematic Mapper plus (ETM+) data, collected September 5, 2000, and a maximum likelihood, supervised classification. When compared to AVIRIS, the Landsat classification grossly overestimated cover by dry conifer and ash classes and severely underestimated soil and green vegetation cover. In a comparison of AVIRIS surface cover to the Burned Area Emergency Rehabilitation (BAER) map of burn severity, the BAER high burn severity areas did not capture the variable patterns of post-fire surface cover by ash, soil, and scorched conifer trees seen in the AVIRIS map. The BAER map, derived from air photos, also did not capture the distribution of scorched trees that were observed in the AVIRIS map. Similarly, the moderate severity class of Landsat-derived burn severity maps generated from the differenced Normalized Burn Ratio (dNBR) calculation had low agreement with the AVIRIS classes of scorched conifer trees. Burn severity and surface cover images were found to contain complementary information, with the dNBR map presenting an image of degree of change caused by fire and the AVIRIS-derived map showing specific surface cover resulting from fire.

Wisconsin's forest resources in 2003

Treesearch

John S. Vissage; Gary J. Brand; J.E. Cummings-Carlson,

2005-01-01

Results of the 2003 annual inventory of Wisconsin show about 15.9 million acres of forest land, over 21.9 billion cubic feet of live volume on forest land, and nearly 591 million dry tons of all live aboveground tree biomass on timberland. Gypsy moth, forest tent caterpillar, twolined chestnut borer, bronze birch borer, ash yellows, and oak wilt were among the pests of...

Growth and Yields of 5-Year-Old Planted Hardwoods On Sharkey Clay Soil

Treesearch

Roger M. Krinard; Harvey E. Kennedy

1981-01-01

Yields of five hardwood species at age 5, planted at 10- by 10-foot spacing on Sharkey clay soil, were ranked cottonwood>sycamore>green ash>sweet-gum~Nuttall oak. By species, per acre volume of stemwood ranged from 29 to 446 cubic feet and total above-ground dry tree weight ranged from 1.08 to 7.68 tons.

21 CFR 184.1979b - Reduced minerals whey.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Reduced minerals whey. 184.1979b Section 184.1979b... GRAS § 184.1979b Reduced minerals whey. (a) Reduced minerals whey is the substance obtained by the removal of a portion of the minerals from whey. The dry product shall not contain more than 7 percent ash...

Spectral analysis of white ash response to emerald ash borer infestations

NASA Astrophysics Data System (ADS)

Calandra, Laura

The emerald ash borer (EAB) (Agrilus planipennis Fairmaire) is an invasive insect that has killed over 50 million ash trees in the US. The goal of this research was to establish a method to identify ash trees infested with EAB using remote sensing techniques at the leaf-level and tree crown level. First, a field-based study at the leaf-level used the range of spectral bands from the WorldView-2 sensor to determine if there was a significant difference between EAB-infested white ash (Fraxinus americana) and healthy leaves. Binary logistic regression models were developed using individual and combinations of wavelengths; the most successful model included 545 and 950 nm bands. The second half of this research employed imagery to identify healthy and EAB-infested trees, comparing pixel- and object-based methods by applying an unsupervised classification approach and a tree crown delineation algorithm, respectively. The pixel-based models attained the highest overall accuracies.

EU landfill waste acceptance criteria and EU Hazardous Waste Directive compliance testing of incinerated sewage sludge ash.

PubMed

Donatello, S; Tyrer, M; Cheeseman, C R

2010-01-01

A hazardous waste assessment has been completed on ash samples obtained from seven sewage sludge incinerators operating in the UK, using the methods recommended in the EU Hazardous Waste Directive. Using these methods, the assumed speciation of zinc (Zn) ultimately determines if the samples are hazardous due to ecotoxicity hazard. Leaching test results showed that two of the seven sewage sludge ash samples would require disposal in a hazardous waste landfill because they exceed EU landfill waste acceptance criteria for stabilised non-reactive hazardous waste cells for soluble selenium (Se). Because Zn cannot be proven to exist predominantly as a phosphate or oxide in the ashes, it is recommended they be considered as non-hazardous waste. However leaching test results demonstrate that these ashes cannot be considered as inert waste, and this has significant implications for the management, disposal and re-use of sewage sludge ash.

Bioprocessing of common beans in diets for tilapia: in vivo digestibility and antinutritional factors.

PubMed

Valdez-González, Francisco; Gutiérrez-Dorado, Roberto; Hernández-Llamas, Alfredo; García-Ulloa, Manuel; Sánchez-Magaña, Luís; Cuevas-Rodríguez, Breidy; Rodríguez-González, Hervey

2017-09-01

Bioprocessing of ingredients by solid-state fermentation is a low-cost technique for preparing diets. It is performed by adding microorganisms such as Rhizopus oligosporus to bean grains, achieving minimal degradation of nutrients and a significant improvement in digestibility. In particular, fermentation induces favorable changes in beans by reducing enzyme inhibitors, such as phytates and tannins. Fermentation significantly (P < 0.05) increased the protein content and digestibility of dry matter and protein compared with whole bean grains, and decreased the content of lipids, ash and phytic acid. Hardening did not have a significant (P > 0.05) effect on the chemical content of beans and digestibility of diets. The dehulled bean meal significantly (P < 0.05) increased protein and lipid content and digestibility of dry matter and protein of beans, and decreased fiber, ash and tannin content. The chemical content of beans and digestibility of ingredients compare favorably with those reported by other authors, indicating the benefits of fermentation and dehulling. We concluded that bean meal obtained from fermentation or dehulling represents a low-cost alternative for diets for tilapia. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Rice husk ash (RHA) as a partial cement replacement in modifying peat soil properties

NASA Astrophysics Data System (ADS)

Daud, Nik Norsyahariati Nik; Daud, Mohd Nazrin Mohd; Muhammed, Abubakar Sadiq

2018-02-01

This paper describes the effect of rice husk ash (RHA) and ordinary Portland cement (OPC) as a potential binder for modifying the properties of peat soil. The amounts RHA and OPC added to the peat soil sample, as percentage of the dry soil mass were in the range of 10-15% and 15%, respectively. Observations were made for the changes in the properties of the soil such as maximum dry density (MDD), optimum moisture content (OMC) and shear strength. Scanning Electron Micrograph-Energy Dispersive X-Ray (SEM-EDX) test were also conducted to observe the microstructure of treated and untreated peat soil. The results show that the modified soil of MDD and OMC values are increased due to the increment amount of binder material. Shear strength values of modified peat showing a good result by assuming that it is relative to the formation of major reaction products such as calcium silicate hydrate (C-S-H). The presence of C-S-H formation is indicated by the results produced from microstructural analysis of peat before and after modification process. This depicts the potential usage of RHA as a partial cement replacement in peat soil which is also improving its engineering properties.

Palaeoenvironmental reconstruction of Hüsamlar coal seam, SW Turkey

NASA Astrophysics Data System (ADS)

Büçkün, Zeynep; İnaner, Hülya; Oskay, Riza Görkem; Christanis, Kimon

2015-06-01

The Ören and Yatağan Basins in SW Turkey host several Miocene coal deposits currently under exploitation for power generation. The present study aims to provide insight into the palaeoenvironmental conditions, which controlled the formation of the Hüsamlar coal seam located in Ören Basin. The coal seam displays many sharp alternations of matrix lignite beds and inorganic, lacustrine sediment layers. The coal is a medium-to-high ash lignite (10.47-31.16 wt%, on dry basis) with high total sulphur content (up to 10 wt%, on dry, ash-free basis), which makes it prone to self-combustion. The maceral composition indicates that the peat-forming vegetation consisted of both arboreal and herbaceous plants, with the latter being predominant in the upper part of the seam. Mica and feldspars contribute to the low part of the seam; carbonates are dominant in the upper part, whereas quartz and pyrite are present along the entire coal profile. The sudden transitions of the telmatic to the lacustrine regime and reverse is attributed to tectonic movements that controlled water table levels in the palaeomire, which affected surface runoff and hence, clastic deposition.

Robust Immobilized Amine CO 2 Sorbent Pellets Utilizing a Poly(Chloroprene) Polymer Binder and Fly Ash Additive

DOE PAGES

Wilfong, Walter Christopher; Kail, Brian W.; Howard, Bret H.; ...

2016-08-04

Pelletization of ca. 50 wt % amine/silica carbon dioxide sorbents was achieved with the novel combination of fly ash (FA) as a strength additive and hydrophobic poly(chloroprene) (PC) as a binder. The PC content and overall synthesis procedure of these materials were optimized to produce pellets, labeled as FA/E100-S_(20/80)_12.2, with the highest ball-mill attrition resistance (<0.5 wt % by fines, 24 h) and maximum CO 2 capture capacity of 1.78 mmol CO 2 g -1. The strength of the pellets was attributed to hydrogen-bonding of the relatively homogeneous PC network with the interlocked FA and BIAS particles (DRIFTS, SEM-EDS). Themore » low degradation of 3–4 % in the pellet's CO 2 capture capacity under both dry TGA (7.5 h) and practical fixed-bed (6.5 h dry; 4.5 h humid,≈5 vol % H 2O) CO 2 adsorption–desorption conditions highlights the pellet's excellent cyclic stability. These robust pellet characteristics make PC/FA/sorbent materials promising for commercial scale, point-source CO 2 capture.« less

Physical and chemical properties of meat from scavenging chickens and helmeted guinea fowls in response to age and sex.

PubMed

Musundire, M T; Halimani, T E; Chimonyo, M

2017-08-01

1. The effects of age and sex on body weight, carcass traits, physical and chemical properties of breast muscle from chickens and helmeted guinea fowls managed under village free-range conditions were assessed in random samples of 48 guinea fowls and 48 chickens obtained from local markets. 2. Guinea fowls had higher body weight, hot carcass weight, cold dressed weight and breast weight than chickens. 3. Guinea fowls had more dry matter, protein and less fat than chickens. Ash content did not differ between guinea fowls and chickens. Protein and fat increased, whereas dry matter and ash decreased with age (P < 0.05) 4. Chicken meat was lighter, less red and more yellow than guinea fowl meat. Cooking loss was higher in guinea fowls, male and grower birds than chickens, females and adult birds, respectively. Shear force was affected by age, as mature birds had a higher value than growers. 5. Guinea fowl carcasses contained more meat that was leaner, higher in protein and redder compared with chicken meat. As age increased the meat increased in protein and fat content and shear force, whereas colour became darker, redder and yellower.

A six-year record of volcanic ash detection with Envisat MIPAS

NASA Astrophysics Data System (ADS)

Griessbach, S.; Hoffmann, L.; von Hobe, M.; Müller, R.; Spang, R.

2012-04-01

Volcanic ash particles have an impact on the Earth's radiation budget and pose a severe danger to air traffic. Therefore, the ability to detect and characterize volcanic ash layers on a global and altitude-dependent scale is essential. The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on-board ESA's Envisat is mainly used for measurements of vertical profiles of atmospheric trace gases. It is also very sensitive to cloud and aerosol particles. We developed a fast, simple, and reliable method to detect volcanic ash using MIPAS spectra. From calculations of volcanic ash and ice particle optical properties, such as extinction coefficients and single scattering albedos as well as simulated MIPAS radiance spectra, we derived two optimal micro windows at 10.5 and 12.1 μm to detect volcanic ash. The calculations were performed with the JUelich RApid Spectral Simulation Code (JURASSIC), which includes a scattering module. Our method applies two radiance thresholds to detect volcanic ash. The first one is derived from a statistical analysis of six years of measured MIPAS radiances in the selected spectral windows. This statistical threshold accounts only for pure volcanic ash detections. The second threshold is derived from simulations of MIPAS radiances with JURASSIC for a broad range of atmospheric conditions and tangent altitudes for volcanic ash and ice particles. The second threshold allows more volcanic ash detections, because it accounts also for mixtures of ice and volcanic ash particles within the instrument's field of view. With the new method major eruptions (from e.g. Chaiten, Okmok, Kasatochi, Sarychev, Eyafjallajökull, Merapi, Grimsvötn, Puyehue-Cordon Caulle, Nabro) as well as several smaller eruptions at mid-latitudes and in polar regions between 2006 - 2011 were clearly identified in the MIPAS data. Trajectory calculations using the Chemical Langangian Model of the Stratosphere (CLaMS) are used to locate a volcanic eruption for each detection. In a case study of the 2011 eruption of the Chilean volcano Puyehue-Cordon Caulle we show how the volcanic ash spreads over the complete southern hemisphere mid-latitudes, is diluted and descends slowly with time. Ash is detected up to two month after the first eruption.

Validation of a continuous flow method for the determination of soluble iron in atmospheric dust and volcanic ash.

PubMed

Simonella, Lucio E; Gaiero, Diego M; Palomeque, Miriam E

2014-10-01

Iron is an essential micronutrient for phytoplankton growth and is supplied to the remote areas of the ocean mainly through atmospheric dust/ash. The amount of soluble Fe in dust/ash is a major source of uncertainty in modeling-Fe dissolution and deposition to the surface ocean. Currently in the literature, there exist almost as many different methods to estimate fractional solubility as researchers in the field, making it difficult to compare results between research groups. Also, an important constraint to evaluate Fe solubility in atmospheric dust is the limited mass of sample which is usually only available in micrograms to milligrams amounts. A continuous flow (CF) method that can be run with low mass of sediments (<10mg) was tested against a standard method which require about 1g of sediments (BCR of the European Union). For validation of the CF experiment, we run both methods using South American surface sediment and deposited volcanic ash. Both materials tested are easy eroded by wind and are representative of atmospheric dust/ash exported from this region. The uncertainty of the CF method was obtained from seven replicates of one surface sediment sample, and shows very good reproducibility. The replication was conducted on different days in a span of two years and ranged between 8 and 22% (i.e., the uncertainty for the standard method was 6-19%). Compared to other standardized methods, the CF method allows studies of dissolution kinetic of metals and consumes less reagents and time (<3h). The method validated here is suggested to be used as a standardized method for Fe solubility studies on dust/ash. Copyright © 2014 Elsevier B.V. All rights reserved.

Alkali content of fly ash : measuring and testing strategies for compliance : [tech transfer summary].

DOT National Transportation Integrated Search

2015-04-01

This study investigated the test methods used to determine the : alkali content of fly ash. It also evaluated if high-alkali fly ash : exacerbates alkali-silica reaction in laboratory tests and field : concrete.

[Study on quality standards of decoction pieces of salt Alpinia].

PubMed

Li, Wenbing; Hu, Changjiang; Long, Lanyan; Huang, Qinwan; Xie, Xiuqiong

2010-12-01

To establish the quality criteria for decoction pieces of salt Alpinia. Decoction pieces of salt Alpinia were measured with moisture, total ash, acid-insoluble ash, water-extract and volatile oils according to the procedures recorded in the Chinese Pharmacopoeia 2010. The content of Nootkatone was determined by HPLC, and NaCl, by chloridion electrode method. We obtained results of total ash, acid-insoluble ash, water-extract and volatile oils of 10 batches of decoction pieces of salt Alpinia moisture; Meanwhile we set the HPLC and chloridion electrode method. This research established a fine quality standard for decoction pieces of salt Alpinia.

Evaluation of Agrilus planipennis (Coleoptera: Buprestidae) control provided by emamectin benzoate and two neonicotinoid insecticides, one and two seasons after treatment

Treesearch

Deborah G. McCullough; Therese M. Poland; Andrea C. Anulewicz; Phillip Lewis; David. Cappaert

2011-01-01

Effective methods are needed to protect ash trees (Fraxinus spp.) from emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), an invasive buprestid that has killed millions of North American ash (Fraxinus spp.) trees. We randomly assigned 175 ash trees (11.5-48.1 cm in diameter) in 25 blocks...

Classification and categorization of treatment methods for ash generated by municipal solid waste incineration: a case for the 2 greater metropolitan regions of Greece.

PubMed

Karagiannidis, A; Kontogianni, St; Logothetis, D

2013-02-01

The primary goal of managing MSW incineration residues is to avoid any impact on human health or the environment. Incineration residues consist of bottom ash, which is generally considered as rather harmless and fly ash which usually contains compounds which are potentially harmful for public health. Small quantities of ash (both bottom and fly) are produced currently in Greece, mainly from the healthcare waste incineration facility in Attica region. Once incineration plants for MSW (currently under planning) are constructed in Greece, the produced ash quantities will increase highly. Thus, it is necessary to organize, already at this stage, a roadmap towards disposal/recovery methods of these ash quantities expected. Certain methods, related to the treatment of the future generated ash which are more appropriate to be implemented in Greece are highlighted in the present paper. The performed analysis offers a waste management approach, having 2016 as a reference year for two different incineration rates; 30% and 100% of the remaining MSW after recycling process. The results focus on the two greater regions of Greece: Attica and Central Macedonia. The quantity of potential future ash generation ranges from 137 to 459 kt for Attica region and from 62 to 207 kt for central Macedonia region depending on the incineration rate applied. Three alternative scenarios for the treatment of each kind of ash are compiled and analysed. Metal recovery and reuse as an aggregate in concrete construction proved to be the most advantageous -in terms of economy-bottom ash management scenario. Concerning management of the fly ash, chemical treatment with phosphoric solution addition results to be the lowest total treatment cost and is considered as the most profitable solution. The proposed methodology constitutes a safe calculation model for operators of MSW incineration plants regardless of the region or country they are located in. Crown Copyright © 2012. Published by Elsevier Ltd. All rights reserved.

The potential of two Salix genotypes for radionuclide/heavy metal accumulation. A case study of Rovinari ash pit (Gorj District, Romania)

NASA Astrophysics Data System (ADS)

Hernea, Cornelia; Neţoiu, Constantin; Corneanu, Gabriel; Crăciun, Constantin; Corneanu, Mihaela; Cojocaru, Luminiţa; Rovena Lăcătuşu, Anca; Popescu, Ion

2014-05-01

Thermo Electric Power Plants (TEPP) produce a high amount of ash, that contains heavy metals and radionuclides. Ash is usually stored in ash-pits, in mixture with water and contains U235, Th 234 and their decay products, that are released from the coal matrix, during combustion, as well as heavy metals. Warm weather dried the ash and it can be spread by the wind in surrounded area. This paper presents the results of an experiment with two Salix genotypes, cultivated on an old closed ash-pit, nearby the Rovinari TEPP, in the middle Jiu valley (Gorj District, Romania), in order to evaluate its tolerance to heavy metals and radionuclides. Ash analysis revealed the presence of natural radionuclides, beloging from ash and coal dust, as well as of Cs 137, of Chernobil provenance. Radionuclides content over the normal limits for Romania were registered for Th 234, Pb210, U235 and Ra226. The heavy metals level in ash was over the normal limits, but under the alerts limits. In order to establish the woody plants tolerance to heavy metals and radionuclides, it is important to study the seedlings behavior. In this respect Salix alba and Salix viminalis whips and cuttings culture have been establish on Rovinari ash-pit. The observations made on survival and growth rate pointed out the superiority of Salix viminalis behaviour. After a period of three years Salix viminalis registered a 96% survival rate, while in Salix alba annual decreases, reaching to 14%. These results are supported by the radionuclides content in leaves and by the electron microscopy studies. In Salix alba the leaves parenchimatic cells present a low sinthesis activity. The exogenous particles are accumulated in parenchima cells vacuola, the chloroplasts are usually agranal, with few starch grains and mitocondria presents slightly dillated crista. The ultrastructural features of the mature leaf cells, evidenced the natural adaptation of Salix viminalins for development in an environment with a big amount of heavy metals and radionuclides, in comparison with Salix alba. In seedlings developed on ash waste dump, in leaf cells, the fine blocks of heterochromatin are dispersed in nucleus. The chloroplast with well developed grana and numerous plastoglobuls, are in active synthesis (being present 2 - 4 starch grains), some chloroplasts being transformed in amyloplast. In the mitochondria matrix, are present ferritin aggregates, with role in cell detoxification processes.

Pneumatic testing in 45-degree-inclined boreholes in ash-flow tuff near Superior, Arizona

USGS Publications Warehouse

LeCain, G.D.

1995-01-01

Matrix permeability values determined by single-hole pneumatic testing in nonfractured ash-flow tuff ranged from 5.1 to 20.3 * 1046 m2 (meters squared), depending on the gas-injection rate and analysis method used. Results from the single-hole tests showed several significant correlations between permeability and injection rate and between permeability and test order. Fracture permeability values determined by cross-hole pneumatic testing in fractured ash-flow tuff ranged from 0.81 to 3.49 * 1044 m2, depending on injection rate and analysis method used. Results from the cross-hole tests monitor intervals showed no significant correlation between permeability and injection rate; however, results from the injection interval showed a significant correlation between injection rate and permeability. Porosity estimates from the 'cross-hole testing range from 0.8 to 2.0 percent. The maximum temperature change associated with the pneumatic testing was 1.2'(2 measured in the injection interval during cross-hole testing. The maximum temperature change in the guard and monitor intervals was O.Ip C. The maximum error introduced into the permeability values due to temperature fluctuations is approximately 4 percent. Data from temperature monitoring in the borehole indicated a positive correlation between the temperature decrease in the injection interval during recovery testing and the gas-injection rate. The thermocouple psychrometers indicated that water vapor was condensing in the boreholes during testing. The psychrometers in the guard and monitor intervals detected the drier injected gas as an increase in the dry bulb reading. The relative humidity in the test intervals was always higher than the upper measurement limit of the psychrometers. Although the installation of the packer system may have altered the water balance of the borehole, the gas-injection testing resulted in minimal or no changes in the borehole relative humidity.

Geohydrologic data from test hole USW UZ-7, Yucca Mountain area, Nye County, Nevada

USGS Publications Warehouse

Kume, Jack; Hammermeister, D.P.

1990-01-01

This report contains a description of the methods used in drilling and coring of the test-hole USW UZ-7, a description of the methods used in collecting, handling, and testing of test-hole samples; Lithologic information from the test hole; and water-content, water-potential, bulk-density, grain-density, porosity, and tritium data for the test hole. Test-hole USW UZ-7 was drilled and cored to a total depth of 62.94 m. The drilling was done using air as a drilling fluid to minimize disturbance to the water content of cores, drill-bit cuttings, and borehole wall-rock. Beginning at the land surface, the unsaturated-zone rock that was penetrated consisted of alluvium; welded and partially to nonwelded ash-flow tuff; bedded and reworked ash-fall tuff; nonwelded ash-flow tuff; and welded ash-flow tuff. Values of gravimetric water content and water potential of alluvium were intermediate between the extreme values in welded and nonwelded units of tuff. Gravimetric water content was largest in bedded and nonwelded ash-fall tuffs and was smallest in welded ash-flow tuff. Values of water potential were more negative in densely welded ash-flow tuffs and were less negative in bedded and nonwelded ash-fall tuffs. Bulk density was largest in densely welded ash-flow tuffs and smallest in nonwelded and bedded ash-fall tuffs. Grain density was uniform but was slightly larger in nonwelded and bedded ash-fall tuffs than in welded ash-flow tuffs. Porosity trends were opposite to bulk-density trends. Tritium content in alluvium was smallest near the alluvium-bedrock contact, markedly increased in the middle of the deposit, and decreased in the near-surface zone of the deposit. (Author 's abstract)

Effects of fire on ash thickness in a Lithuanian grassland and short-term spatio-temporal changes

NASA Astrophysics Data System (ADS)

Pereira, P.; Cerdà, A.; Úbeda, X.; Mataix-Solera, J.; Martin, D.; Jordán, A.; Burguet, M.

2012-12-01

Ash thickness is a key variable in the protection of soil against erosion agents after planned and unplanned fires. Thicker ash provides better protection against raindrop impact and reduces the runoff response by retaining water and promoting water infiltration although little is known about the distribution and the evolution of the ash layer after the fires. Ash thickness measurements were conducted along two transects (flat and sloping areas) following a a grid experimental design. Both transects extended from the burned area into an adjacent unburned area. We analysed ash thickness evolution according to time and fire severity. In order to interpolate data with accuracy and identify the techniques with the least bias, several interpolation methods were tested in the grid plot. Overall, the fire had a low severity. The fire significantly reduced the ground cover, especially on sloping areas owing to the higher fire severity and/or less biomass previous to the fire. Ash thickness depends on fire severity and is thin where fire severity was higher and thicker in lower fire severity sites. The ash thickness decreased with time after the fire. Between 4 and 16 days after the fire, ash was transported by wind. The major reduction took place between 16 and 34 days after the fire as a result of rainfall, and was more efficient where fire severity was higher. Between 34 and 45 days after the fire no significant differences in ash thickness were identified among ash colours and only traces of the ash layer remained. The omni-directional experimental variograms shown that variable structure did not change importantly with the time, however, the most accurate interpolation methods were different highlighting the slight different patterns of ash thickness distribution with the time. The ash spatial variability increased with the time, particularly on the slope, as a result of water erosion.

Treated bottom ash medium and method of arsenic removal from drinking water

DOEpatents

Gadgil, Ashok

2009-06-09

A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

Comparing the use of sewage sludge ash and glass powder in cement mortars.

PubMed

Chen, Zhen; Poon, Chi Sun

2017-06-01

This study explored the suitability of using sewage sludge ash (SSA) and mixed-colored glass powder (MGP) as construction materials in cement mortars. Positive findings from this study may help promote the recycling of waste SSA and MGP in construction works. The results indicated that the SSA decreased while MGP improved the mortar workability. The SSA exhibited very low pozzolanic activity, but the cement mortar prepared with 20% SSA yielded strength values slightly superior to those of the glass mortars due to its water absorption ability. MGP can serve as a pozzolan and when 20% of cement was replaced by MGP, apparent compressive strength gains were found at later curing ages. The SSA could be used to mitigate ASR expansion while the MGP was superior in resisting drying shrinkage.

The Early Detection of the Emerald Ash Borer (eab) Using Multi-Source Remotely Sensed Data

NASA Astrophysics Data System (ADS)

Hu, B.; Naveed, F.; Tasneem, F.; Xing, C.

2018-04-01

The objectives of this study were to exploit the synergy of hyperspectral imagery, Light Detection And Ranging (LiDAR) and high spatial resolution data and their synergy in the early detection of the EAB (Emerald Ash Borer) presence in trees within urban areas and to develop a framework to combine information extracted from multiple data sources. To achieve these, an object-oriented framework was developed to combine information derived from available data sets to characterize ash trees. Within this framework, an advanced individual tree delineation method was developed to delineate individual trees using the combined high-spatial resolution worldview-3 imagery was used together with LiDAR data. Individual trees were then classified to ash and non-ash trees using spectral and spatial information. In order to characterize the health state of individual ash trees, leaves from ash trees with various health states were sampled and measured using a field spectrometer. Based on the field measurements, the best indices that sensitive to leaf chlorophyll content were selected. The developed framework and methods were tested using worldview-3, airborne LiDAR data over the Keele campus of York University Toronto Canada. Satisfactory results in terms of individual tree crown delineation, ash tree identification and characterization of the health state of individual ash trees. Quantitative evaluations is being carried out.

Weight, Volume, and Physical Properties of Major Hardwood Species in the Gulf and Atlantic Coastal Plains

Treesearch

Alexander Clark; Douglas R. Phillips; Douglas J. Frederick

1985-01-01

The weight, volume, and physical properties of trees 1 to 20 inches d.b.h. were determined for green ash, blackgum, red maple, sweetgum, water tupelo, yellow-poplar, hickory, laurel oak, water oak, and white oak in the Gulf and Atlantic Coastal Plains. Hard hardwood, soft hardwood, and individual species equations are presented for predicting green and dry weight...

Transpirational drying effects on energy and ash content from whole-tree chipping operations in a southern pine plantation

Treesearch

J. Cutshall; D. Greene; S. Baker; Dana Mitchell

2011-01-01

Newly announced North American bioenergy projects will likely increase the demand for woody biomass substantially over the next five to ten years. High harvesting and transportation costs for woody biomass from forests are commonly identified as key constraints to expanding this new industry and meeting expected wood fiber demand. In addition to a cost-competitive...

Digestion of high rate activated sludge coupled to biochar formation for soil improvement in the tropics.

PubMed

Nansubuga, Irene; Banadda, Noble; Ronsse, Frederik; Verstraete, Willy; Rabaey, Korneel

2015-09-15

High rate activated sludge (HRAS) is well-biodegradable sludge enabling energy neutrality of wastewater treatment plants via anaerobic digestion. However, even through successful digestion a notable residue still remains. Here we investigated whether this residue can be converted to biochar, for its use as a fertilizer or as a solid fuel, and assessed its characteristics and overall process efficiency. In a first phase, HRAS was anaerobicaly digested under mesophilic conditions at a sludge retention time of 20 days. HRAS digested well (57.9 ± 6.2% VS degradation) producing on average 0.23 ± 0.04 L CH4 per gram VS fed. The digestate particulates were partially air-dried to mimic conditions used in developing countries, and subsequently converted to biochar by fixed-bed slow pyrolysis at a residence time of 15 min and at highest heating temperatures (HHT) of 300 °C, 400 °C and 600 °C. Subsequently, the produced chars were characterized by proximate analysis, CHN-elemental analysis, pH in solution and bomb calorimetry for higher heating value. The yield and volatile matter decreased with increasing HHT while ash content and fixed carbon increased with increasing HHT. The produced biochar showed properties optimal towards soil amendment when produced at a temperature of 600 °C with values of 5.91 wt%, 23.75 wt%, 70.35% on dry basis (db) and 0.44 for volatile matter, fixed carbon, ash content and H/C ratio, respectively. With regard to its use for energy purposes, the biochar represented a lower calorific value than the dried HRAS digestate likely due to high ash content. Based on these findings, it can be concluded that anaerobic digestion of HRAS and its subsequent biochar formation at HHT of 600 °C represents an attractive route for sludge management in tropic settings like in Uganda, coupling carbon capture to energy generation, carbon sequestration and nutrient recovery. Copyright © 2015 Elsevier Ltd. All rights reserved.

Respiratory hazard assessment of combined exposure to complete gasoline exhaust and respirable volcanic ash in a multicellular human lung model at the air-liquid interface

USGS Publications Warehouse

Tomasek, Ines; Horwell, Claire J.; Bisig, Christoph; Damby, David; Comte, Pierre; Czerwinski, Jan; Petri-Fink, Alke; Clift, Martin J D; Drasler, Barbara; Rothen-Rutishauer, Barbara

2018-01-01

Communities resident in urban areas located near active volcanoes can experience volcanic ash exposures during, and following, an eruption, in addition to sustained exposures to high concentrations of anthropogenic air pollutants (e.g., vehicle exhaust emissions). Inhalation of anthropogenic pollution is known to cause the onset of, or exacerbate, respiratory and cardiovascular diseases. It is further postulated similar exposure to volcanic ash can also affect such disease states. Understanding of the impact of combined exposure of volcanic ash and anthropogenic pollution to human health, however, remains limited.The aim of this study was to assess the biological impact of combined exposure to respirable volcanic ash (from Soufrière Hills volcano (SHV), Montserrat and Chaitén volcano (ChV), Chile; representing different magmatic compositions and eruption styles) and freshly-generated complete exhaust from a gasoline vehicle. A multicellular human lung model (an epithelial cell-layer composed of A549 alveolar type II-like cells complemented with human blood monocyte-derived macrophages and dendritic cells cultured at the air-liquid interface) was exposed to diluted exhaust (1:10) continuously for 6 h, followed by immediate exposure to the ash as a dry powder (0.54 ± 0.19 μg/cm2 and 0.39 ± 0.09 μg/cm2 for SHV and ChV ash, respectively). After an 18 h incubation, cells were exposed again for 6 h to diluted exhaust, and a final 18 h incubation (at 37 °C and 5% CO2). Cell cultures were then assessed for cytotoxic, oxidative stress and (pro-)inflammatory responses.Results indicate that, at all tested (sub-lethal) concentrations, co-exposures with both ash samples induced no significant expression of genes associated with oxidative stress (HMOX1, NQO1) or production of (pro-)inflammatory markers (IL-1β, IL-8, TNF-α) at the gene and protein levels. In summary, considering the employed experimental conditions, combined exposure of volcanic ash and gasoline vehicle exhaust has a limited short-term biological impact to an advanced lung cell in vitro model.

Respiratory hazard assessment of combined exposure to complete gasoline exhaust and respirable volcanic ash in a multicellular human lung model at the air-liquid interface.

PubMed

Tomašek, Ines; Horwell, Claire J; Bisig, Christoph; Damby, David E; Comte, Pierre; Czerwinski, Jan; Petri-Fink, Alke; Clift, Martin J D; Drasler, Barbara; Rothen-Rutishauser, Barbara

2018-07-01

Communities resident in urban areas located near active volcanoes can experience volcanic ash exposures during, and following, an eruption, in addition to sustained exposures to high concentrations of anthropogenic air pollutants (e.g., vehicle exhaust emissions). Inhalation of anthropogenic pollution is known to cause the onset of, or exacerbate, respiratory and cardiovascular diseases. It is further postulated similar exposure to volcanic ash can also affect such disease states. Understanding of the impact of combined exposure of volcanic ash and anthropogenic pollution to human health, however, remains limited. The aim of this study was to assess the biological impact of combined exposure to respirable volcanic ash (from Soufrière Hills volcano (SHV), Montserrat and Chaitén volcano (ChV), Chile; representing different magmatic compositions and eruption styles) and freshly-generated complete exhaust from a gasoline vehicle. A multicellular human lung model (an epithelial cell-layer composed of A549 alveolar type II-like cells complemented with human blood monocyte-derived macrophages and dendritic cells cultured at the air-liquid interface) was exposed to diluted exhaust (1:10) continuously for 6 h, followed by immediate exposure to the ash as a dry powder (0.54 ± 0.19 μg/cm 2 and 0.39 ± 0.09 μg/cm 2 for SHV and ChV ash, respectively). After an 18 h incubation, cells were exposed again for 6 h to diluted exhaust, and a final 18 h incubation (at 37 °C and 5% CO 2 ). Cell cultures were then assessed for cytotoxic, oxidative stress and (pro-)inflammatory responses. Results indicate that, at all tested (sub-lethal) concentrations, co-exposures with both ash samples induced no significant expression of genes associated with oxidative stress (HMOX1, NQO1) or production of (pro-)inflammatory markers (IL-1β, IL-8, TNF-α) at the gene and protein levels. In summary, considering the employed experimental conditions, combined exposure of volcanic ash and gasoline vehicle exhaust has a limited short-term biological impact to an advanced lung cell in vitro model. Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.

Improving lithium-ion battery performances by adding fly ash from coal combustion on cathode film

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dyartanti, Endah Retno; Jumari, Arif, E-mail: arifjumari@yahoo.com; Nur, Adrian

A lithium battery is composed of anode, cathode and a separator. The performance of lithium battery is also influenced by the conductive material of cathode film. In this research, the use of fly ash from coal combustion as conductive enhancer for increasing the performances of lithium battery was investigated. Lithium iron phosphate (LiFePO{sub 4}) was used as the active material of cathode. The dry fly ash passed through 200 mesh screen, LiFePO{sub 4} and acethylene black (AB), polyvinylidene fluoride (PVDF) as a binder and N-methyl-2-pyrrolidone (NMP) as a solvent were mixed to form slurry. The slurry was then coated, driedmore » and hot pressed to obtain the cathode film. The ratio of fly ash and AB were varied at the values of 1%, 2%, 3%, 4% and 5% while the other components were at constant. The anode film was casted with certain thickness and composition. The performance of battery lithium was examined by Eight Channel Battery Analyzer, the composition of the cathode film was examined by XRD (X-Ray Diffraction), and the structure and morphology of the anode film was analyzed by SEM (Scanning Electron Microscope). The composition, structure and morphology of cathode film was only different when fly ash added was 4% of AB or more. The addition of 2% of AB on cathode film gave the best performance of 81.712 mAh/g on charging and 79.412 mAh/g on discharging.« less

Gaseous mercury from curing concretes that contain fly ash: laboratory measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Danold W. Golightly; Ping Sun; Chin-Min Cheng

2005-08-01

Total gaseous mercury in headspace air was measured for enclosed concretes dry curing at 40 C for intervals of 2, 28, and 56 days. Release of mercury was confirmed for ordinary Portland cement concrete (OPC) and three concretes in which class F fly ash from coal-combustion substituted for a fraction of the cement: (a) 33% fly ash (FA33), (b) 55% fly ash (FA55), and (c) 33% fly ash plus 0.5% mercury-loaded powdered activated carbon (HgPAC). Mean rates of mercury release (0.10-0.43 ng/day per kg of concrete) over the standard first 28 days of curing followed the order OPC {lt} FA33more » {approximately} FA55 {lt} HgPAC. The mercury flux from exposed surfaces of these concretes ranged from 1.9 {+-} 0.5 to 8.1 {+-} 2.0 ng/m{sup 2}/h, values similar to the average flux for multiple natural substrates in Nevada, 4.2 {+-} 1.4 ng/m{sup 2}/h, recently published by others. Air sampling extending for 28 days beyond the initial 28-day maturation for OPC, FA55, and HgPAC suggested that the average Hg release rate by OPC is constant over 56 days and that mercury release rates for FA55 and HgPAC may ultimately diminish to levels exhibited by OPC concrete. The release of mercury from all samples was less than 0.1% of total mercury content over the initial curing period, implying that nearly all of the mercury was retained in the concrete. 20 refs., 3 figs., 3 tabs.« less

Properties of Controlled Low Strength Material with Circulating Fluidized Bed Combustion Ash and Recycled Aggregates

PubMed Central

Weng, Tsai-Lung; Cheng, An; Chao, Sao-Jeng; Hsu, Hui-Mi

2018-01-01

This study aims to investigate the effect of adding circulating fluidized bed combustion (CFBC) ash, desulfurization slag, air-cooled blast-furnace slag and coal bottom ash to the controlled low-strength material (CLSM). Test methods include slump flow test, ball drop test, water soluble chloride ion content measurement, compressive strength and length change measurement. The results show that (1) the use of CFBC hydration ash with desulfurization slag of slump flow is the best, and the use of CFBC hydration ash with coal bottom ash and slump flow is the worst; (2) CFBC hydration ash with desulfurization slag and chloride ion content is the highest; (3) 24 h ball drop test (diameter ≤ 76 mm), and test results are 70 mm to 76 mm; (4) CFBC hydration ash with desulfurization slag and compression strength is the highest, with the coal bottom ash being the lowest; increase of CFBC hydration ash can reduce compressive strength; and (5) the water-quenched blast furnace slag and CFBC hydration ash would expand, which results in length changes of CLSM specimens. PMID:29724055

Proximate composition of poultry processing wastewater particulate matter from broiler slaughter plants.

PubMed

Kiepper, B H; Merka, W C; Fletcher, D L

2008-08-01

An experiment was conducted to compare the proximate composition of particulate matter recovered from poultry processing wastewater (PPW) generated by broiler slaughter plants. Poultry processing wastewater is the cumulative wastewater stream generated during the processing of poultry following primary and secondary physical screening (typically to 500 mum) that removes gross offal. Composite samples of PPW from 3 broiler slaughter plants (southeast United States) were collected over 8 consecutive weeks. All 3 broiler slaughter plants process young chickens with an average live weight of 2.0 kg. At each plant, a single 72-L composite sample was collected using an automatic sampler programmed to collect 1 L of wastewater every 20 min for 24 h during one normal processing day each week. Each composite sample was thoroughly mixed, and 60 L was passed through a series of sieves (2.0 mm, 1.0 mm, 500 mum, and 53 mum). The amount of particulate solids collected on the 2.0 mm, 1.0 mm, and 500 mum sieves was insignificant. The solids recovered from the 53-mum sieve were subjected to proximate analysis to determine percent moisture, fat, protein, ash, and fiber. The average percentages of fat, protein, ash, and fiber for all samples on a dry-weight basis were 55.3, 27.1, 6.1, and 4.1, respectively. Fat made up over half of the dry-weight matter recovered, representing PPW particulate matter between 500 and 53 mum. Despite the variation in number of birds processed daily, further processing operations, and number and type of wastewater screens utilized, there were no significance differences in percentage of fat and fiber between the slaughter plants. There were significant differences in percent protein and ash between the slaughter plants.

Effect of dietary protein and lipid levels on growth, nutrient utilization and whole-body composition of blue gourami, Trichogaster trichopterus fingerlings.

PubMed

Mohanta, K N; Subramanian, S; Korikanthimath, V S

2013-02-01

Nine semi-purified diets were prepared with three levels each of protein (300, 350 and 400 g/kg) and lipid (60, 80 and 100 g/kg) and fed ad libitum to Trichogaster trichopterus fingerlings (0.61 ± 0.03 g) in triplicate groups (10 fish/replicate) for 90 days to determine optimum dietary protein and lipid levels. Twenty-seven flow-through fibre-reinforced plastic tanks (200 l capacity each with 100 l of water) were used for rearing the fish. The dietary protein, lipid and their interactions had significant effects (p < 0.05) on weight gain, feed conversion ratio, specific growth rate, nutrient retention and digestibility, but not on hepato- and viscerosomatic indexes (p > 0.05). Dietary protein and the interaction of protein with lipid had significant effect (p < 0.05) on whole-body dry matter, lipid and energy contents, but not on protein and ash contents (p > 0.05). But, the dietary lipid had significant (p < 0.05) effect on whole-body dry matter, protein, lipid and energy contents except the ash contents (p > 0.05). For each level of dietary protein, the increase in dietary lipid resulted significant increase (p < 0.05) in whole-body lipid contents without affecting the protein and ash contents (p > 0.05). Based on better growth and dietary performances, the optimum dietary protein and lipid levels of blue gourami fingerling are 350 and 80 g/kg diet respectively. © 2011 Blackwell Verlag GmbH.

Physicochemical properties of chitooligosaccharide prepared by using chitosanase from Stenotrophomonas maltophilia KPU 2123

NASA Astrophysics Data System (ADS)

Fawzya, Y. N.; Rahmawati, A.; Patantis, G.

2018-03-01

Study on the physicochemical properties of chitooligosaccharide (COS) prepared by hydrolysis of chitosan using chitosanase from Stenotrophomonas maltophilia KPU 2123 has been carried out. Hydrolysis process was conducted by reacting the soluble chitosan with 8 U·g-1 chitosan of chitosanase for 0; 8; 16 and 24 h incubation and stopped by addition of 0.25 M NaOH until reached pH 7. The COS was obtained as supernatant after being centrifugation. The liquid COS were then freeze-dried and analyzed their physicochemical properties, which comprised yield, viscosity, moisture and ash content, the degree of deacetylation (DD), as well as lead (Pb), arsenic (As) content and analyses of COS by Thin Layer Chromatography (TLC). The optimum hydrolysis time was found to be 16 h with the COS viscosity was 8.50 ± 0.87 cPs. The high COS yield was related to high ash content, i.e. 251.70 ± 77.97 % and 50.45 ± 3.19 % (db), respectively. There was lead (Pb) and arsenic (As) metals detected, i.e. 4.4 ppm and 0.1 ppm, respectively. However, they still met the requirement of Pb and As content in a commercial COS referred. Based on the COS properties, desalination process should be applied in the preparation of COS by enzymatic method.

Utilization of wild apricot kernel press cake for extraction of protein isolate.

PubMed

Sharma, P C; Tilakratne, B M K S; Gupta, Anil

2010-12-01

The kernels of apricot (Prunus armeniaca) stones are utilized for extraction of oil. The press cake left after extraction of oil was evaluated for preparation of protein isolate for its use in food supplementation. The apricot kernels contained 45-50% oil, 23.6-26.2% protein, 4.2% ash, 5.42% crude fibre, 8.2% carbohydrates and 90 mg HCN/100 g kernels, while press cake obtained after oil extraction contained 34.5% crude protein, which can be utilized for preparation of protein isolates. The method standardized for extraction of protein isolate broadly consisted of boiling the press cake with water in 1:20 (w/v) ratio for 1 h, raising pH to 8 and stirring for a few min followed by filtration, coagulation at pH 4 prior to sieving and pressing of coagulant for overnight and drying followed by grinding which resulted in extraction of about 71.3% of the protein contained in the press cake. The protein isolate contained 68.8% protein, 6.4% crude fat, 0.8% ash, 2.2% crude fibre and 12.7% carbohydrates. Thus the apricot kernel press cake can be utilized for preparation of protein isolate to improve the nutritional status of many food formulations.

Ultraviolet-ozone treatment reduces levels of disease-associated prion protein and prion infectivity

USGS Publications Warehouse

Johnson, C.J.; Gilbert, P.; McKenzie, D.; Pedersen, J.A.; Aiken, Judd M.

2009-01-01

Background. Transmissible spongiform encephalopathies (TSEs) are a group of fatal neurodegenerative diseases caused by novel infectious agents referred to as prions. Prions appear to be composed primarily, if not exclusively, of a misfolded isoform of the cellular prion protein. TSE infectivity is remarkably stable and can resist many aggressive decontamination procedures, increasing human, livestock and wildlife exposure to TSEs. Findings. We tested the hypothesis that UV-ozone treatment reduces levels of the pathogenic prion protein and inactivates the infectious agent. We found that UV-ozone treatment decreased the carbon and prion protein content in infected brain homogenate to levels undetectable by dry-ashing carbon analysis or immunoblotting, respectively. After 8 weeks of ashing, UV-ozone treatment reduced the infectious titer of treated material by a factor of at least 105. A small amount of infectivity, however, persisted despite UV-ozone treatment. When bound to either montmorillonite clay or quartz surfaces, PrPTSE was still susceptible to degradation by UV-ozone. Conclusion. Our findings strongly suggest that UV-ozone treatment can degrade pathogenic prion protein and inactivate prions, even when the agent is associated with surfaces. Using larger UV-ozone doses or combining UV-ozone treatment with other decontaminant methods may allow the sterilization of TSE-contaminated materials. ?? 2009 Aiken et al; licensee BioMed Central Ltd.

Why is Coal Ash of Concern and How to Assess Potential Impacts?

EPA Science Inventory

EPA's new test methods - the leaching environmental assessment framework (LEAF) are discussed including how they have been used to evaluate fly ash and scrubber residues. Work to evaluate high-volume encapsulated use of fly ash in cementitious material is also described.

Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

DOE PAGES

Morgan, Trevor James; Turn, Scott Q.; George, Anthe

2015-08-26

A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amountsmore » of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high concentration of alkali and alkali earth metals (totaling ~2.8 wt% relative to the dry feedstock) which are catalytic and increase cracking reactions during pyrolysis.« less

Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

PubMed Central

Morgan, Trevor James; Turn, Scott Q.; George, Anthe

2015-01-01

A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amounts of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. The reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high concentration of alkali and alkali earth metals (totaling ~2.8 wt% relative to the dry feedstock) which are catalytic and increase cracking reactions during pyrolysis. PMID:26308860

Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morgan, Trevor James; Turn, Scott Q.; George, Anthe

A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amountsmore » of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high concentration of alkali and alkali earth metals (totaling ~2.8 wt% relative to the dry feedstock) which are catalytic and increase cracking reactions during pyrolysis.« less

Non-noble metal based metallization systems

NASA Technical Reports Server (NTRS)

Garcia, A., III

1983-01-01

The results of efforts to produce a nonsilver metallization system for silicon photovoltaic cells are given. The system uses a metallization system based on molybdenum, tin, and titanium hydride. The initial work in this system was done using the MIDFILM process. The MIDFILM process attains a line resolution comparable to photoresist methods with a process related to screen printing. The surface to be processed is first coated with a thin layer of photopolymer material. Upon exposure to ultraviolet light through a suitable mask, the polymer in the non-pattern area crosslinks and becomes hard. The unexposed pattern areas remain tacky. The conductor material is then applied in the form of a dry mixture of metal which adheres to the tacky pattern area. The assemblage is then fired to ash the photopolymer and sinter the conductor powder.

Microwave-assisted digestion using nitric acid for heavy metals and sulfated ash testing in active pharmaceutical ingredients.

PubMed

Pluhácek, T; Hanzal, J; Hendrych, J; Milde, D

2016-04-01

The monitoring of inorganic impurities in active pharmaceutical ingredients plays a crucial role in the quality control of the pharmaceutical production. The heavy metals and residue on ignition/sulfated ash methods employing microwave-assisted digestion with concentrated nitric acid have been demonstrated as alternatives to inappropriate compendial methods recommended in United States Pharmacopoeia (USP) and European Pharmacopoeia (Ph. Eur.). The recoveries using the heavy metals method ranged between 89% and 122% for nearly all USP and Ph. Eur. restricted elements as well as the recoveries of sodium sulfate spikes were around 100% in all tested matrices. The proposed microwave-assisted digestion method allowed simultaneous decomposition of 15 different active pharmaceutical ingredients with sample weigh up to 1 g. The heavy metals and sulfated ash procedures were successfully applied to the determination of heavy metals and residue on ignition/sulfated ash content in mycophenolate mofetil, nicergoline and silymarin.

Microbial control of the emerald ash borer

Treesearch

Leah S. Bauer; Houping Liu; Deborah L. Miller

2004-01-01

In June 2002, emerald ash borer (EAB), Agrilus planipennis Fairmaire, a buprestid native to several Asian countries, was identified as the causative agent of ash (Fraxinus spp.) mortality in southeastern Michigan and southwestern Ontario. Currently, the only method known to control EAB is limited to identifying and destroying...

Juvenile magma recognition and eruptive dynamics inferred from the analysis of ash time series: The 2015 reawakening of Cotopaxi volcano

USGS Publications Warehouse

Gaunt, H. Elizabeth; Bernard, Benjamin; Hidalgo, Silvana; Proano, Antonio; Wright, Heather M.; Mothes, Patricia; Criollo, Evelyn; Kueppers, Ulrich

2016-01-01

Forecasting future activity and performing hazard assessments during the reactivation of volcanoes remain great challenges for the volcanological community. On August 14, 2015 Cotopaxi volcano erupted for the first time in 73 years after approximately four months of precursory activity, which included an increase in seismicity, gas emissions, and minor ground deformation. Here we discuss the use of near real-time petrological monitoring of ash samples as a complementary aid to geophysical monitoring, in order to infer eruption dynamics and evaluate possible future eruptive activity at Cotopaxi. Twenty ash samples were collected between August 14 and November 23, 2015 from a monitoring site on the west flank of the volcano. These samples contain a range of grain types that we classified as: hydrothermal/altered, lithic, juvenile, and free crystals. The relative proportions of theses grains evolved as the eruption progressed, with increasing amounts of juvenile material and a decrease in hydrothermally altered material. In samples from the initial explosion, juvenile grains are glassy, microlite-poor and contain hydrothermal minerals (opal and alunite). The rising magma came in contact with the hydrothermal system under confinement, causing hydro-magmatic explosions that cleared the upper part of the plumbing system. Subsequently, the magmatic column produced a thermal aureole in the conduit and dried out the hydrothermal system, allowing for dry eruptions. Magma ascent rates were low enough to allow for efficient outgassing and microlite growth. Constant supply of magma from below caused quasi-continuous disruption of the uppermost magma volume through a combination of shear-deformation and gas expansion. The combination of increasing crystallinity of juvenile grains, and high measured SO2 flux indicate decreasing integrated magma ascent rates and clearing of the hydrothermal system along transport pathways in a system open to gas loss. The near real-time monitoring of ash samples combined with traditional geophysical monitoring techniques during the reawakening of Cotopaxi allowed us to gain a much clearer understanding of events than when using traditional geophysical monitoring alone.

Carbon dioxide sequestration in municipal solid waste incinerator (MSWI) bottom ash.

PubMed

Rendek, Eva; Ducom, Gaëlle; Germain, Patrick

2006-01-16

During bottom ash weathering, carbonation under atmospheric conditions induces physico-chemical evolutions leading to the pacification of the material. Fresh bottom ash samples were subjected to an accelerated carbonation using pure CO2. The aim of this work was to quantify the volume of CO2 that could be sequestrated with a view to reduce greenhouse gas emissions and investigate the possibility of upgrading some specific properties of the material with accelerated carbonation. Carbonation was performed by putting 4mm-sieved samples in a CO2 chamber. The CO2 pressure and the humidity of the samples were varied to optimize the reaction parameters. Unsieved material was also tested. Calcite formation resulting from accelerated carbonation was investigated by thermogravimetry and differential scanning calorimetry (TG/DSC) and metal leaching tests were performed. The volume of sequestrated CO2 was on average 12.5L/kg dry matter (DM) for unsieved material and 24 L/kg DM for 4mm-sieved samples. An ash humidity of 15% appeared to give the best results. The reaction was drastically accelerated at high pressure but it did not increase the volume of sequestrated CO2. Accelerated carbonation, like the natural phenomenon, reduces the dangerous nature of the material. It decreases the pH from 11.8 to 8.2 and causes Pb, Cr and Cd leaching to decrease. This process could reduce incinerator CO2 emissions by 0.5-1%.

From fly ash waste slurry to functional adsorbent for valuable rare earth ion separation: An ingenious combination process involving modification, dewatering and grafting.

PubMed

Zhou, Qi; Luo, Tiantian; Yang, Heng; Liang, Cheng; Jing, Luru; Luo, Wenjun

2018-03-01

Acid extracting aluminum from fly ash would produce pestilent secondary fly ash slurry with strong acidity, high content of Cl - and residual Al 3+ that is difficult to be further used. In order to achieve the zero emission, a potential integrated treatment process for reutilization was proposed in this paper. By intelligent use of residual Al 3+ in sludge as catalyst, hydrophobic modification of solid particle was taken with fatty acid via a heterogeneous esterification at normal temperature. Due to the solvophobic force, moisture content of its filter cake was 36.46%, which reduced 11.14% compared with the unmodified one, hydrophobicity scale can achieve 100% with modifier accounting for only 0.8% of solid content and the Cl - concentrations decreased from 20 to 0.102 g/L in wash liquor, thus greatly saving water for washing and energy for drying. Subsequently, based on the appearance of hydrocarbon chains on particle surface, a high-efficiency ultraviolet-induced grafting polymerization was implemented to fabricate density polyacrylic acid decorated fly ash particles from the surface "CH" sites, the resultant composite was proved to efficiently separate valuable rare-earth Gd 3+ from wastewater with outstanding adsorption and regeneration performance, hence bringing high added-value utilization for these hazardous waste. Copyright © 2017 Elsevier Inc. All rights reserved.

Agglomeration of SRC residues. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Theodore, F.W.; Wasson, G.E.

1982-01-01

EPRI contracted with CCDC to agglomerate Kerr-McGee ash concentrate and determine whether the agglomerates could be used as a fixed-bed gasifier feed. Briquettes were produced from Kerr-McGee ash concentrate which met CCDC's strength criteria for handling as feed to a fixed-bed gasifier. In addition, when shock heated under conditions simulating gasifier conditions, strong coke was produced demonstrating that the briquettes will not disintegrate during the initial temperature shock when charged to the gasifier. The conclusion of this study is that briquettes produced from the Kerr-McGee ash concentrate studied could be considered as feed for a fixed-bed gasifier. The CO/sub 2/-carbonmore » reactivity of the briquettes had values between a typical eastern and western coal. In the case of a dry bottom gasifier where the reactivity is important, it is not clear-cut whether the ash concentrate briquettes would be an economical feed. A closer inspection by a gasifier manufacturer is needed to resolve this issue. Since higher gasification temperatures are used in a slagging gasifier, the reactivity question is eliminated and the briquettes should be considered as a feed. This study does not deal with the exact design of a gasifier since this is a function of the type used. The gasifier manufacturer should be considered in future work for their input on critical design considerations i.e. stirrer design, etc.« less

Mercury emission and speciation of coal-fired power plants in China

NASA Astrophysics Data System (ADS)

Wang, S. X.; Zhang, L.; Li, G. H.; Wu, Y.; Hao, J. M.; Pirrone, N.; Sprovieri, F.; Ancora, M. P.

2010-02-01

Comprehensive field measurements are needed to understand the mercury emissions from Chinese power plants and to improve the accuracy of emission inventories. Characterization of mercury emissions and their behavior were measured in six typical coal-fired power plants in China. During the tests, the flue gas was sampled simultaneously at inlet and outlet of Selective Catalytic Reduction (SCR), electrostatic precipitators (ESP), and flue gas desulfurization (FGD) using the Ontario Hydro Method (OHM). The pulverized coal, bottom ash, fly ash and gypsum were also sampled in the field. Mercury concentrations in coal burned in the measured power plants ranged from 17 to 385 μg/kg. The mercury mass balances for the six power plants varied from 87 to 116% of the input coal mercury for the whole system. The total mercury concentrations in the flue gas from boilers were at the range of 1.92-27.15 μg/m3, which were significantly related to the mercury contents in burned coal. The mercury speciation in flue gas right after the boiler is influenced by the contents of halogen, mercury, and ash in the burned coal. The average mercury removal efficiencies of ESP, ESP plus wet FGD, and ESP plus dry FGD-FF systems were 24%, 73% and 66%, respectively, which were similar to the average removal efficiencies of pollution control device systems in other countries such as US, Japan and South Korea. The SCR system oxidized 16% elemental mercury and reduced about 32% of total mercury. Elemental mercury, accounting for 66-94% of total mercury, was the dominant species emitted to the atmosphere. The mercury emission factor was also calculated for each power plant.

Mercury emission and speciation of coal-fired power plants in China

NASA Astrophysics Data System (ADS)

Wang, S.; Zhang, L.; Li, G.; Wu, Y.; Hao, J.; Pirrone, N.; Sprovieri, F.; Ancora, M. P.

2009-11-01

Comprehensive field measurements are needed to understand the mercury emissions from Chinese power plants and to improve the accuracy of emission inventories. Characterization of mercury emissions and their behavior were measured in six typical coal-fired power plants in China. During the tests, the flue gas was sampled simultaneously at inlet and outlet of selective catalyst reduction (SCR), electrostatic precipitators (ESP), and flue gas desulfurization (FGD) using the Ontario Hydro Method (OHM). The pulverized coal, bottom ash, fly ash and gypsum were also sampled in the field. Mercury concentrations in coal burned in the measured power plants ranged from 17 to 385 μg/kg. The mercury mass balances for the six power plants varied from 87 to 116% of the input coal mercury for the whole system. The total mercury concentrations in the flue gas from boilers were at the range of 1.92-27.15 μg/m3, which were significantly related to the mercury contents in burned coal. The mercury speciation in flue gas right after the boiler is influenced by the contents of halogen, mercury, and ash in the burned coal. The average mercury removal efficiencies of ESP, ESP plus wet FGD, and ESP plus dry FGD-FF systems were 24%, 73% and 66%, respectively, which were similar to the average removal efficiencies of pollution control device systems in other countries such as US, Japan and South Korea. The SCR system oxidized 16% elemental mercury and reduced about 32% of total mercury. Elemental mercury, accounting for 66-94% of total mercury, was the dominant species emitted to the atmosphere. The mercury emission factor was also calculated for each power plant.

Experimental study and simulation of phosphorus purification effects of bioretention systems on urban surface runoff

PubMed Central

Liang, Zheng; Li, Yajiao; Li, Peng; Jiang, Chunbo

2018-01-01

Excessive phosphorus (P) contributes to eutrophication by degrading water quality and limiting human use of water resources. Identifying economic and convenient methods to control soluble reactive phosphorus (SRP) pollution in urban runoff is the key point of rainwater management strategies. Through three series of different tests involving influencing factors, continuous operation and intermittent operation, this study explored the purification effects of bioretention tanks under different experimental conditions, it included nine intermittent tests, single field continuous test with three groups of different fillers (Fly ash mixed with sand, Blast furnace slag, and Soil), and eight intermittent tests with single filler (Blast furnace slag mixed with sand). Among the three filler combinations studied, the filler with fly ash mixed with sand achieved the best pollution reduction efficiency. The setting of the submerged zone exerted minimal influence on the P removal of the three filler combinations. An extension of the dry period slightly promoted the P purification effect. The combination of fly ash mixed with sand demonstrated a positive purification effect on SRP during short- or long-term simulated rainfall duration. Blast furnace slag also presented a positive purification effect in the short term, although its continuous purification effect on SRP was poor in the long term. The purification abilities of soil in the short and long terms were weak. Under intermittent operations across different seasons, SRP removal was unstable, and effluent concentration processes were different. The purification effect of the bioretention system on SRP was predicted through partial least squares regression (PLS) modeling analysis. The event mean concentration removal of SRP was positively related to the adsorption capacity of filler and rainfall interval time and negatively related to submerged zones, influent concentration and volume. PMID:29742120

Environmentally-mediated ash aggregate formation: example from Tungurahua volcano, Ecuador

NASA Astrophysics Data System (ADS)

Kueppers, Ulrich; Ayris, Paul M.; Bernard, Benjamin; Delmelle, Pierre; Douillet, Guilhem A.; Lavallée, Yan; Mueller, Sebastian B.; Dingwell, Donald B.; Dobson, Kate J.

2016-04-01

Volcanic ash is generated during explosive eruptions through an array of different processes; it can be produced in large quantities and can, in some circumstances, have the potential for far-reaching impacts beyond the flanks of the volcano. Aggregation of ash particles can significantly impact the dispersal within the atmosphere, and its subsequent deposition into terrestrial or aquatic environments. However, our understanding of the complex interplay of the boundary conditions which permit aggregation to occur remain incomplete. Tungurahua volcano, Ecuador, has been intermittently active since 1999. In August 2006, a series of pyroclastic density currents (PDC) were generated during a series of dry, Vulcanian explosions and travelled down the western and northern flanks of the volcano. In some locations, the related PDC deposits temporarily dammed the Chambo river, and the residual heat within those deposits produced vigorous steam plumes. During several field campaigns (2009-2015), we mapped, sampled, and analysed the related deposits. At the base of the Rea ravine, a large delta fan of PDC deposits had dammed the river over a length of several hundred metres. In several outcrops adjacent to the river and in small erosional gullies we found a peculiar stratigraphic layer (up to ten centimetres thick) at the top of the PDC deposits. As this layer is capped by a thin fall unit of coarse ash that we also find elsewhere at the top of the August 2006 deposits, the primary nature is without doubt. In this unit, we observed abundant ash aggregates up to eight millimetres in diameter within a poorly sorted, ash-depleted lapilli tuff, primarily comprised of rounded pumiceous and scoriaceous clasts of similar size. Leaching experiments have shown that these aggregates contain several hundred ppm of soluble sulphate and chloride salts. Recent laboratory experiments (Mueller et al. 2015) have suggested that in order for accretionary lapilli to be preserved within ash deposits likely requires a combination of sufficient humidity and a pre-existing soluble salt load on aggregating ash particles. We suggest that steam pluming from the dammed Chambo river, coupled with soluble salts emplaced by gas-ash interactions between ejection and deposition, provided a unique opportunity for the formation of accretionary lapilli with sufficient mechanical strength to survive deposition, accounting for their presence in a deposit otherwise absent of such aggregates. This possibility provides an important reminder of the role played by external environmental triggers in shaping the properties volcanic ash deposits.

Geochemical and analytical implications of extensive sulfur retention in ash from Indonesian peats

USGS Publications Warehouse

Kane, Jean S.; Neuzil, Sandra G.

1993-01-01

Sulfur is an analyte of considerable importance to the complete major element analysis of ash from low-sulfur, low-ash Indonesian peats. Most analytical schemes for major element peat- and coal-ash analyses, including the inductively coupled plasma atomic emission spectrometry method used in this work, do not permit measurement of sulfur in the ash. As a result, oxide totals cannot be used as a check on accuracy of analysis. Alternative quality control checks verify the accuracy of the cation analyses. Cation and sulfur correlations with percent ash yield suggest that silicon and titanium, and to a lesser extent, aluminum, generally originate as minerals, whereas magnesium and sulfur generally originate from organic matter. Cation correlations with oxide totals indicate that, for these Indonesian peats, magnesium dominates sulfur fixation during ashing because it is considerably more abundant in the ash than calcium, the next most important cation in sulfur fixation.

Characterization of typical heavy metals in pyrolysis MSWI fly ash.

PubMed

Xu, Tengtun; Wang, Li'ao; Zeng, Yunmin; Zhao, Xue; Wang, Lei; Zhan, Xinyuan; Li, Tong; Yang, Lu

2018-06-07

Thermal treatment methods are used extensively in the process of municipal solid waste incineration fly ash. However, the characterization of heavy metals during this process should be understood more clearly in order to control secondary pollution. In this paper, the content, speciation and leaching toxicity of mercury (Hg), plumbum (Pb), cadmium (Cd) and zinc (Zn) in fly ash treated under different temperatures and time were firstly analysed as pre-tests. Later, pilot-scale pyrolysis equipment was used to explore the concentration and speciation changes in the heavy metals of fly ash. Finally, the phase constitution and microstructure changes in fly ash were compared before and after pyrolysis using X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The results showed that (a) The appropriate processing temperature was between 400°C and 450°C, and the processing time should be 1 h. (b) The stability of heavy metals in fly ash increased after pyrolysis. (c) XRD and SEM results indicated that phase constitution changed a little, but the microstructure varied to a porous structure similar to that of a coral reef after pyrolysis. These results suggest that pyrolysis could be an effective method in controlling heavy metal pollution in fly ash.

Apparatus and method for direct measurement of coal ash sintering and fusion properties at elevated temperatures and pressures

DOEpatents

Khan, M. Rashid

1990-01-01

A high-pressure microdilatometer is provided for measuring the sintering and fusion properties of various coal ashes under the influence of elevated pressures and temperatures in various atmospheres. Electrical resistivity measurements across a sample of coal ash provide a measurement of the onset of the sintering and fusion of the ash particulates while the contraction of the sample during sintering is measured with a linear variable displacement transducer for detecting the initiation of sintering. These measurements of sintering in coal ash at different pressures provide a mechanism by which deleterious problems due to the sintering and fusion of ash in various combustion systems can be minimized or obviated.

Effects of pulse and press drying disturbance on benthic stream communities

USGS Publications Warehouse

Lynch, Dustin T.; Magoulick, Daniel D.

2016-01-01

Natural disturbance is an integral component of most ecosystems and occurs in 3 different forms: pulse, press, and ramp. In lotic ecosystems, seasonal drought is a major form of disturbance, particularly in intermittent headwater streams, which often are reduced to pools that serve as refuges for biota. We used simulated intermittent stream pools to compare the effects of control, pulse, and press drying on growth and survival in 3 fish species (Lepomis megalotis, Campostoma anomalum, and Etheostoma spectabile) commonly found together in drought-prone streams in the Ozark Highlands, USA. We also compared effects on benthic community structure, including periphyton and chironomid density and sediment in deep (permanently watered) and shallow (intermittently dewatered) habitat. Only one species, L. megalotis, showed a significant reduction in length and mass growth in press drying compared with control treatments. Drying and type of drying had no effect on survival of any fish species. Drying and type of drying had strong overall effects on periphyton growth in shallow habitats, where ash-free dry mass decreased and the autotrophic index (the ratio of chlorophyll a to total biomass) increased significantly in drying relative to control and in press relative to pulse treatments. Drying negatively affected sediment accumulation in shallow habitat and chironomid density in deep habitat. Drying in intermittent streams has species-dependent effects on fish growth and benthic structure, and pulse and press drying differ in their effects on periphyton in these systems. These effects may have important consequences in seasonally drying streams as anthropogenic influence on stream drying increases.

Recovery of aluminum and other metal values from fly ash

DOEpatents

McDowell, William J.; Seeley, Forest G.

1981-01-01

The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

Recovery of aluminum and other metal values from fly ash

DOEpatents

McDowell, W.J.; Seeley, F.G.

1979-11-01

The invention relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

Emerald ash borer modeling methods for future forest projections

Treesearch

Ryan D. Desantis; W. Keith Moser; Robert J. Jr. Hugett; Ruhong Li; David N. Wear; Patrick D. Miles

2012-01-01

The emerald ash borer (Agrilus planipennis Fairmaire; EAB) is a nonnative invasive insect that has caused considerable damage to ash (Fraxinus spp.) in North America. Unlike invasive organisms that can be mitigated, contained, controlled, or even eradicated, EAB continues to spread across North America. The loss of the North...

Dispersal of the emerald ash borer, Agrilus planipennis, in newly-colonized sites

Treesearch

Rodrigo J. Mercader; Andrew M. Siegert; Andrew M. Liebhold; Deborah G. McCullough

2009-01-01

Emerald ash borer Agrilus planipennis Fairmaire (Coleoptera: Buprestidae) is an invasive forest insect pest threatening more than 8 billion ash (Fraxinus spp.) trees in North America. Development of effective survey methods and strategies to slow the spread of A. planipennis requires an understanding of dispersal...

Evaluation of recovery and monitoring methods for parasitoids released against Emerald Ash Borer

USDA-ARS?s Scientific Manuscript database

The emerald ash borer (Agrilus planipennis Fairmaire, EAB) is an invasive insect pest, and the target of an extensive biological control campaign designed to mitigate EAB driven ash tree (Fraxinus spp.) mortality. Since 2007, environmental releases of three species of hymenopteran parasitoids of EA...

Advancing the Renewable Industry in Minnesota

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sparby, Michael; Doering, Alan; Timmerman, Denny

This report deals with seven topics: 1. "Utilizing Ash Wastes as a Nutrient Source for Corn": As forms of gasification and combustion grow in the area of renewable energy in Minnesota the question arises regarding the utilization/application of the ash co product produced from these processes. Currently there are four facilities in Minnesota producing an ash co product (three ethanol facilities and one combusting biomass to produce energy). These ash wastes are generated from using ethanol by-products as a fuel or heating source for fermentation. Other ash wastes from agricultural sources include turkey litter ash. When applied to agricultural fields,more » ash wastes can be a source of nutrients for agricultural crops. Chemical analyses of ash wastes vary, but 200 to 300 lb of P 2O 5 and K 2O per ton of ash is typical. The value of ash wastes as a fertilizer has increased because commercial fertilizer prices have increased significantly over the last few years. Specifically: Compaction/Agglomeration research- Research included development of an appropriate product for use in current delivery systems by densifying the ash into the form of pellets or briquettes which may reduce fertilizer input cost to farmers. The initiative addresses the use of phosphorus and potassium from co-firing or gasification processes as a fertilizer source. 2. "Use of Glycerol as a Corn Replacement in Calf Starter Diets": Glycerol is a sugar alcohol by-product of bio-diesel production. About 1 gallon of glycerin is produced for every 10 gallons of bio-diesel of which the glycerol content may vary between 63 and almost 100%. There is some uncertainty of the exact energy value of glycerol as an ingredient for animal feed but it has been successfully used as a replacement for corn up to 10% of the diet dry matter for lactating dairy cows. There is a lack of information on incorporating glycerol into diets for pre- and post weaned dairy heifer calves which has the potential to expand the market for this by product. Preliminary work at SROC indicates that there are no palatability problems using glycerol up to 6% of the mix in post weaning pellets for group fed dairy heifers. 3. "Intervention Strategies for Reduction of Food-borne Pathogens in Cattle Fed Ethanol Byproducts": Ethanol plants and cattle producers create a symbiotic relationship: The use of wet and dry distiller’s grains in beef cattle rations provides significant improvement in overall feedlot performance for many producers in Minnesota and the Upper Midwest. Distiller’s grain is the coproduct that remains following the distillation of ethanol. It may be dehydrated to produce dried distiller’s grain (DDG) which is then commonly used as livestock feed. The use of distiller’s grains in livestock rations has been the subject of numerous research projects over the past ten years. Recently published research data conducted at Kansas State University (K-State) has created controversy over the feeding of distiller’s grains in beef cattle rations. The research indicates that cattle fed distiller’s grain may have an increased probability of Escherichia coli O157 in their hindgut. Specifically: This research assessment was a two part project consisting of feeding trials conducted at the University of Minnesota and an intervention study conducted at Kansas State University. This report is the Kansas State University portion. This report is a task-level final technical report. 4. "Impact of Distillers' Grains and Glycerin on Cattle Fecal Shedding of Escherichia coli O157:H7" 5. "Study Assessing the Opportunities and Potential of Soybean Based Products and Technologies": Based on demand/market potential, economic feasibility, stage of development and strength of institutional support, Informa Economics, Inc. ("Informa") narrowed down a list of more than 100 emerging soybean products and to 8 of the most promising for soybean, considered to have the greatest potential to add significant value to Minnesota's soybean commodity production. However, as with the potential of any biobased product or technology, the development of these emerging soybean products and technologies will be heavily reliant on future market price environments (especially for petroleum) and government policies. This report identifies what the contractor believes are the top 8 products and technologies for soybeans at the time of publishing. 6. "Study Assessing the Opportunities and Potential of Corn-Based Products and Technologies": Based on demand/market potential, economic feasibility, stage of development and strength of institutional support, Informa Economics, Inc. ("Informa") narrowed down a list of more than 100 emerging corn products and technologies to 8 of the most promising for corn, considered to have the greatest potential to add significant value to Minnesota's corn commodity production. However, as with the potential of any biobased product or technology, the development of these emerging corn products and technologies will be heavily reliant on future market price environments (especially for petroleum) and government policies. This report identifies what the contractor believes are the top 8 products and technologies for corn at the time of publishing. 7. "Distributed Power Generation Technology (Roseau Gasification)."« less

Yield and Nutrient Removal by Whole-Tree Harvest of a Young Bottomland Hardwood Stand

Treesearch

John K. Francis

1984-01-01

The yield and nutrient withdrawal by whole-tree harvest of young bottomland hardwoods has heretofore been unknown. In this study of intensive harvest, samples of chipped whole trees and soil from 16 test plots were analyzed for nutrient content. Eighty-two percent of the stems and 59 percent of the dry weight were green ash. The balance was divided among a number of...

Sewage sludge conditioning with the application of ash from biomass-fired power plant

NASA Astrophysics Data System (ADS)

Wójcik, Marta; Stachowicz, Feliks; Masłoń, Adam

2018-02-01

During biomass combustion, there are formed combustion products. Available data indicates that only 29.1 % of biomass ashes were recycled in Poland in 2013. Chemical composition and sorptive properties of ashes enable their application in the sewage sludge treatment. This paper analyses the impact of ashes from biomass-combustion power plant on sewage sludge dewatering and higienisation. The results obtained in laboratory tests proved the possitive impact of biomass ashes on sewage sludge hydration reduction after dewatering and the increase of filtrate volume. After sludge conditioning with the use of biomass combustion by-products, the final moisture content decreased by approximatelly 10÷25 % in comparison with raw sewage sludge depending on the method of dewatering. The application of biomass combustion products in sewage sludge management could provide an alternative method of their utilization according to law and environmental requirements.

Fractionation of distillers dried grains with solubles (DDGS) by sieving and winnowing.

PubMed

Liu, KeShun

2009-12-01

Four commercial samples of distillers dried grains with solubles (DDGS) were sieved. All sieved fractions except for the pan fraction, constituting about 90% of original mass, were then winnowed with an air blast seed cleaner. Sieving was effective in producing fractions with varying composition. As the particle size decreased, protein and ash contents increased, and total carbohydrate (CHO) decreased. Winnowing sieved fractions was also effective in shifting composition, particularly for larger particle classes. Heavy sub-fractions were enriched in protein, oil and ash, while light sub-fractions were enriched for CHO. For protein, the combination of the two procedures resulted in a maximum 56.4% reduction in a fraction and maximum 60.2% increase in another fraction. As airflow velocity increased, light sub-fraction mass increased, while the compositional difference between the heavy and light sub-fractions decreased. Winnowing three times at a lower velocity was as effective as winnowing one time at a medium velocity. Winnowing the whole DDGS was much less effective than winnowing sieved fractions in changing composition, but sieving winnowed fractions was more effective than sieving whole DDGS. The two combination sequences gave comparable overall effects but sieving followed by winnowing is recommended because it requires less time. Regardless of combinational sequence, the second procedure was more effective in shifting composition than the first procedure.

Effect of soaking in water and rumen digeta solutions on metabolizable energy content and chemical composition of barley seeds for use in poultry diet.

PubMed

Tabatabee, S N; Sadeghi, G H; Tabeidian, S A

2007-03-15

An experiment was carried out to evaluate the effect of soaking in water and different rumen digesta solutions on nutritional value of dry barley seeds. Treatments were included distilled water as control and rumen digesta that diluted with distilled water to obtain 20, 40 and 60% digesta solutions. Solutions have added to 10 kg of barley seed samples to achieve final 30% moisture content. After 21 days the chemical composition and energy content of barley seed were determined. Gross energy of barley seeds did not affected by different experimental treatments. Use of 20% rumen digesta solution resulted to a significant (p<0.01) increase in AME and AMEn content of barley seeds. Barley seed that treated with 40% of rumen digesta solution had highest TME and TMEn content and its different from seeds that treated with 60 and 100% rumen digesta solutions was significant (p<0.05). The chemical composition such as dry matter, crud protein, crude fat, crud fiber, ash and NFE were found to be similar and there was no significant difference. However, soaking in rumen digesta solutions increased crud protein, ether extract, crude fiber and ash content of barley seeds numerically.

Sustainable sources of biomass for bioremediation of heavy metals in waste water derived from coal-fired power generation.

PubMed

Saunders, Richard J; Paul, Nicholas A; Hu, Yi; de Nys, Rocky

2012-01-01

Biosorption of heavy metals using dried algal biomass has been extensively described but rarely implemented. We contend this is because available algal biomass is a valuable product with a ready market. Therefore, we considered an alternative and practical approach to algal bioremediation in which algae were cultured directly in the waste water stream. We cultured three species of algae with and without nutrient addition in water that was contaminated with heavy metals from an Ash Dam associated with coal-fired power generation and tested metal uptake and bioremediation potential. All species achieved high concentrations of heavy metals (to 8% dry mass). Two key elements, V and As, reached concentrations in the biomass of 1543 mg.kg(-1) DW and 137 mg.kg(-1) DW. Growth rates were reduced by more than half in neat Ash Dam water than when nutrients were supplied in excess. Growth rate and bioconcentration were positively correlated for most elements, but some elements (e.g. Cd, Zn) were concentrated more when growth rates were lower, indicating the potential to tailor bioremediation depending on the pollutant. The cosmopolitan nature of the macroalgae studied, and their ability to grow and concentrate a suite of heavy metals from industrial wastes, highlights a clear benefit in the practical application of waste water bioremediation.

Durability of conventional concretes containing black rice husk ash.

PubMed

Chatveera, B; Lertwattanaruk, P

2011-01-01

In this study, black rice husk ash (BRHA) from a rice mill in Thailand was ground and used as a partial cement replacement. The durability of conventional concretes with high water-binder ratios was investigated including drying shrinkage, autogenous shrinkage, depth of carbonation, and weight loss of concretes exposed to hydrochloric (HCl) and sulfuric (H(2)SO(4)) acid attacks. Two different replacement percentages of cement by BRHA, 20% and 40%, and three different water-binder ratios (0.6, 0.7 and 0.8) were used. The ratios of paste volume to void content of the compacted aggregate (γ) were 1.2, 1.4, and 1.6. As a result, when increasing the percentage replacement of BRHA, the drying shrinkage and depth of carbonation reaction of concretes increased. However, the BRHA provides a positive effect on the autogenous shrinkage and weight loss of concretes exposed to hydrochloric and sulfuric acid attacks. In addition, the resistance to acid attack was directly varied with the (SiO(2) + Al(2)O(3) + Fe(2)O(3))/CaO ratio. Results show that ground BRHA can be applied as a pozzolanic material and also improve the durability of concrete. Copyright © 2010 Elsevier Ltd. All rights reserved.

Porosity of Self-Compacting Concrete (SCC) incorporating high volume fly ash

NASA Astrophysics Data System (ADS)

Kristiawan, S. A.; Sunarmasto; Murti, G. Y.

2017-02-01

Degradation of concrete could be triggered by the presence of aggressive agents from the environment into the body of concrete. The penetration of these agents is influenced by the pore characteristics of the concrete. Incorporating a pozzolanic material such as fly ash could modify the pore characteristic of the concrete. This research aims to investigate the influence of incorporating fly ash at high volume level on the porosity of Self-Compacting Concrete (SCC). Laboratory investigations were carried out following the ASTM C642 for measuring density and volume of permeable pores (voids) of the SCC with varying fly ash contents (50-70% by weight of total binder). In addition, a measurement of permeable voids by saturation method was carried out to obtain an additional volume of voids that could not be measured by the immersion and boiling method of ASTM C642. The results show that the influence of fly ash content on the porosity appears to be dependent on age of SCC. At age less than 56 d, fly ash tends to cause an increase of voids but at 90 d of age it reduces the pores. The additional pores that can be penetrated by vacuum saturation method counts about 50% of the total voids.

Elemental content of tissues and excreta of lambs, goats, and kids fed white sweet clover growing on fly ash

DOE Office of Scientific and Technical Information (OSTI.GOV)

Furr, A.K.; Parkinson, T.F.; Heffron, C.L.

White sweet clover found voluntarily growing on a deep bed of soft coal fly ash was found to contain high concentrations of a number of elements including selenium, bromine, and molybdenum, rubidium, strontium, and others. The clover was harvested and fed as 23.5% of a dry pelleted ration to lambs and pregnant goats for up to 173 days. High concentrations of selenium were found in 11 tissues, blood, goats' milk, and excreta of lambs, goats, and newborn kids. Molybdenum in liver, strontium in bone, and bromine and rubidium in animal tissues were also elevated over those in the corresponding tissuesmore » of animals fed an identical ration containing control clover grown on soil. No gross or histologic lesions were present in any of the animals.« less

Obtaining of granular fertilizers based on ashes from combustion of waste residues and ground bones using phosphorous solubilization by bacteria Bacillus megaterium.

PubMed

Rolewicz, M; Rusek, P; Borowik, K

2018-06-15

The article presents research results on obtaining phosphorus granulated fertilizers on the basis of microbiologically activated sewage sludge ashes, ground bones and dried blood from meat industry. Granulation tests were carried out using a laboratory pan granulator as well as on an experimental pilot plant. The aim of the studies was to select the proper composition of the mixture of raw materials and binding agents to obtain granulated fertilizers from waste materials such as MSSA and MBM and bacteria lyophilisate. Obtained fertilizer samples were subjected to physical tests (granulation tests etc.) and quality assessment. The tests confirmed that it was possible to produce granulated phosphate fertilizers using the Bacillus megaterium for solubilization of phosphorus in a simple process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Magnetic mapping of distribution of wood ash used for fertilization of forest soil.

PubMed

Petrovský, Eduard; Remeš, Jiří; Kapička, Aleš; Podrázský, Vilém; Grison, Hana; Borůvka, Luboš

2018-06-01

The effect of wood-ash fertilization on forest soils has been assessed mainly through geochemical methods (e.g., content of soil organic matter or nutrients). However, a simple and fast method of determining the distribution of the ash and the extent of affected soil is missing. In this study we present the use of magnetic susceptibility, which is controlled by Fe-oxides, in comparing the fertilized soil in the forest plantation of pine and oak with intact forest soil. Spatial and vertical distribution of magnetic susceptibility was measured in an oak and pine plantation next to stems of young plants, where wood ash was applied as fertilizer. Pattern of the susceptibility distribution was compared with that in non-fertilized part of the plantation as well as with a spot of intact natural forest soil nearby. Our results show that the wood-ash samples contain significant amount of ferrimagnetic magnetite with susceptibility higher than that of typical forest soil. Clear differences were observed between magnetic susceptibility of furrows and ridges. Moreover, the dispersed ash remains practically on the surface, does not penetrate to deeper layers. Finally, our data suggest significant differences in surface values between the pine and oak plants. Based on this study we may conclude that magnetic susceptibility may represent a simple and approximate method of assessing the extent of soil affected by wood-ash. Copyright © 2018 Elsevier B.V. All rights reserved.

Thermal treatment of solid residues from WtE units: a review.

PubMed

Lindberg, Daniel; Molin, Camilla; Hupa, Mikko

2015-03-01

Thermal treatment methods of bottom ash, fly ash and various types of APC (air pollution control) residues from waste-to-energy plants can be used to obtain environmentally stable material. The thermal treatment processes are meant to reduce the leachability of harmful residue constituents, destroy toxic organic compounds, reduce residue volume, and produce material suitable for utilization. Fly ash and APC residues often have high levels of soluble salts, particularly chlorides, metals such as cadmium, lead, copper and zinc, and trace levels of organic pollutants such as dioxins and furans. Different thermal treatment methods can be used to either decompose or stabilize harmful elements and compounds in the ash, or separate them from the ash to get a material that can be safely stored or used as products or raw materials. In the present paper, thermal treatment methods, such as sintering, vitrification, and melting have been reviewed. In addition to a review of the scientific literature, a survey has been made of the extensive patent literature in the field. Copyright © 2015 Elsevier Ltd. All rights reserved.

Investigation on by-products of bioenergy systems (anaerobic digestion and gasification) as potential crop nutrient using FTIR, XRD, SEM analysis and phyto-toxicity test.

PubMed

Kataki, Sampriti; Hazarika, Samarendra; Baruah, D C

2017-07-01

Success and acceptability of the bio energy conversion technology to a large extent depend upon management of the inevitable by-products generated during the conversion process. By-products can be considered favourable as organic fertilizer as they retain nutrients with varying composition depending upon input biomass. However, characteristics of these heterogeneous resources with respect to feedstock and processing conditions have to be assessed to state on their agricultural and environmental benefits. Therefore, 3 types of anaerobic digestion by-products (digestate) from surplus biomass viz. cow dung, Ipomoea carnea:cow dung (60:40 dry weight basis) and rice straw:green gram stover:cow dung (30:30:40 dry weight basis) and one gasification by-product (biochar) from rice husk are considered to understand the fertilizer prospects. Considering 3 potential application options, digestate from each feedstock option was further processed as separated solid, separated liquid and ash from solid digestates. Thus, a total of 10 by-products were investigated for understanding their prospects as fertilizer using Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive X ray Spectroscopy (EDX) and phyto-toxicity test to have a broad insight in terms of their organic, mineral, elemental composition, morphological feature and potential phyto-toxicity. In general, irrespective of origin of feedstock, solid digestate, ash digestate and char showed similarity in terms of composition of functional groups with some degree of variation in relative content as reflected by FTIR analysis. Dominance of organic functional groups in separated solid digestates compared to liquid fraction indicated the former as favourable organic amendments. Quartz was the prevalent mineral phase in all separated solid, ash digestate and rice husk char. Digestates in ash phase represent more concentrated plant nutrient source with higher content of K, Ca, P, Na and Mg than their respective solid phase. Application of ash digestates and char is likely to improve adsorptive capacity of soil for water and nutrient due to presence of relatively uniformly distributed porous particles. Liquid fraction of Ipomoea digestates exhibited inhibitory effect on seed germination of greengram (Vigna radiate) with significant reduction of germination index. Inhibitory effects of by-products were found to correlate negatively with their electrical conductivity and ammonia-nitrogen content. Understanding on spectroscopic, morphological and phytotoxic properties of different application options of bioenergy by-products would be useful for assessment of their appropriate use in agriculture. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evaluation of recovery and monitoring methods for parasitoids released against emerald ash borer

Treesearch

Michael S. Parisio; Juli R. Gould; John D. Vandenberg; Leah S. Bauer; Melissa K. Fierke

2017-01-01

Emerald ash borer (Agrilus planipennis Fairmaire, EAB) is an invasive forest pest and the target of an extensive biological control program designed to mitigate EAB-caused ash (Fraxinus spp.) mortality. Since 2007, hymenopteran parasitoids of EAB from northeastern Asia have been released as biological control agents in North...

Developmental patterns of jicama (Pachyrhizus erosus (L.) Urban) plant and the chemical constituents of roots grown in Sonora, Mexico.

PubMed

Fernandez, M V; Warid, W A; Loaiza, J M; Montiel, A

1997-01-01

The developmental pattern of jicama (Pachyrhizus erosus (L.) Urban) was studied by sampling plants aged 20 to 36 weeks at weekly intervals. There was an increase in all characteristics of foliage: fresh and dry weight, number of leaves per plant, main stem length, number of leaves, nodes and internodes of the main stem; and in all root characteristics: fresh and dry weight, diameter and length. The chemical analysis was determined for roots at different plant ages. The range values for dry matter were 16.19-22.28%, protein 1.11-1.62%, fat 0.553-0.867%, crude fiber 0.3048-0.3943%, and ash 0.669-1.089%. The chemical constituents fluctuated with age but without specific trends. These values are considered the first record of roots produced by plants grown in Mexico.

Method validation for simultaneous determination of chromium, molybdenum and selenium in infant formulas by ICP-OES and ICP-MS.

PubMed

Khan, Naeem; Jeong, In Seon; Hwang, In Min; Kim, Jae Sung; Choi, Sung Hwa; Nho, Eun Yeong; Choi, Ji Yeon; Kwak, Byung-Man; Ahn, Jang-Hyuk; Yoon, Taehyung; Kim, Kyong Su

2013-12-15

This study aimed to validate the analytical method for simultaneous determination of chromium (Cr), molybdenum (Mo), and selenium (Se) in infant formulas available in South Korea. Various digestion methods of dry-ashing, wet-digestion and microwave were evaluated for samples preparation and both inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS) were compared for analysis. The analytical techniques were validated by detection limits, precision, accuracy and recovery experiments. Results showed that wet-digestion and microwave methods were giving satisfactory results for sample preparation, while ICP-MS was found more sensitive and effective technique than ICP-OES. The recovery (%) of Se, Mo and Cr by ICP-OES were 40.9, 109.4 and 0, compared to 99.1, 98.7 and 98.4, respectively by ICP-MS. The contents of Cr, Mo and Se in infant formulas by ICP-MS were found in good nutritional values in accordance to nutrient standards for infant formulas CODEX values. Copyright © 2013 Elsevier Ltd. All rights reserved.

Simultaneous determination of V, Ni and Fe in fuel fly ash using solid sampling high resolution continuum source graphite furnace atomic absorption spectrometry.

PubMed

Cárdenas Valdivia, A; Vereda Alonso, E; López Guerrero, M M; Gonzalez-Rodriguez, J; Cano Pavón, J M; García de Torres, A

2018-03-01

A green and simple method has been proposed in this work for the simultaneous determination of V, Ni and Fe in fuel ash samples by solid sampling high resolution continuum source graphite furnace atomic absorption spectrometry (SS HR CS GFAAS). The application of fast programs in combination with direct solid sampling allows eliminating pretreatment steps, involving minimal manipulation of sample. Iridium treated platforms were applied throughout the present study, enabling the use of aqueous standards for calibration. Correlation coefficients for the calibration curves were typically better than 0.9931. The concentrations found in the fuel ash samples analysed ranged from 0.66% to 4.2% for V, 0.23-0.7% for Ni and 0.10-0.60% for Fe. Precision (%RSD) were 5.2%, 10.0% and 9.8% for V, Ni and Fe, respectively, obtained as the average of the %RSD of six replicates of each fuel ash sample. The optimum conditions established were applied to the determination of the target analytes in fuel ash samples. In order to test the accuracy and applicability of the proposed method in the analysis of samples, five ash samples from the combustion of fuel in power stations, were analysed. The method accuracy was evaluated by comparing the results obtained using the proposed method with the results obtained by ICP OES previous acid digestion. The results showed good agreement between them. The goal of this work has been to develop a fast and simple methodology that permits the use of aqueous standards for straightforward calibration and the simultaneous determination of V, Ni and Fe in fuel ash samples by direct SS HR CS GFAAS. Copyright © 2017 Elsevier B.V. All rights reserved.

Comparing grey water versus tap water and coal ash versus perlite on growth of two plant species on green roofs.

PubMed

Agra, Har'el; Solodar, Ariel; Bawab, Omar; Levy, Shay; Kadas, Gyongyver J; Blaustein, Leon; Greenbaum, Noam

2018-08-15

Green roofs provide important ecosystem services in urban areas. In Mediterranean and other semi-arid climate regions, most perennial plants on green roofs need to be irrigated during the dry season. However, the use of freshwater in such regions is scarce. Therefore, the possibility of using grey water should be examined. Coal ash, produced primarily from the burning of coal in power plants, constitutes an environmental contaminant that should be disposed. One option is to use ash as a growing substrate for plants. Here, we compare the effects of irrigating with grey- versus tap-water and using ash versus perlite as growing substrates in green roofs. The study was conducted in northern Israel in a Mediterranean climate. The design was full factorial with three factors: water-type (grey or tap-water)×substrate-type (coal ash vs perlite)×plant species (Phyla nodiflora, Convolvulus mauritanicus or no-plant). The development of plants and the quality of drainage water along the season, as well as quality of the used substrates were monitored. Both plant species developed well under all the experimental conditions with no effect of water type or substrate type. Under all treatments, both plant species enhanced electrical conductivity (EC) and chemical oxygen demand (COD) of the drainage water. In the summer, EC and COD reached levels that are unacceptable in water and are intended to be reused for irrigation. We conclude that irrigating with grey water and using coal ash as a growth substrate can both be implemented in green roofs. The drainage from tap water as well as from grey water can be further used for irrigating the roof, but for that, COD and EC levels must be lowered by adding a sufficient amount of tap water before reusing. Copyright © 2018 Elsevier B.V. All rights reserved.

Development of a video-based slurry sensor for on-line ash analysis. Fifth quarterly technical progress report, October 1, 1995--December 31, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adel, G.T.; Luttrell, G.H.

Automatic control of fine coal cleaning circuits has traditionally been limited by the lack of sensors for on-line ash analysis. Although several nuclear-based analyzers are available, none have seen widespread acceptance. This is largely due to the fact that nuclear sensors are expensive and tend to be influenced by changes in seam type and pyrite content. Recently, researchers at VPI&SU have developed an optical sensor for phosphate analysis. The sensor uses image processing technology to analyze video images of phosphate ore. It is currently being used by PCS Phosphate for off-line analysis of dry flotation concentrate. The primary advantages ofmore » optical sensors over nuclear sensors are that hey are significantly cheaper, are not subject to measurement variations due to changes in high atomic number materials, are inherently safer and require no special radiation permitting. The purpose of this work is to apply the knowledge gained in the development of an optical phosphate analyzer to the development of an on-line ash analyzer for fine coal slurries. During the past quarter, the current prototype of the on-line optical ash analyzer was subjected to extensive testing at the Middlefork coal preparation plant. Initial work focused on obtaining correlations between ash content and mean gray level, while developmental work on the more comprehensive neural network calibration approach continued. Test work to date shows a promising trend in the correlation between ash content and mean gray level. Unfortunately, data scatter remains significant. Recent tests seem to eliminate variations in percent solids, particle size distribution, measurement angle and light setting as causes for the data scatter; however, equipment warm-up time and number of images taken per measurement appear to have a significant impact on the gray-level values obtained. 8 figs., 8 tabs.« less

Thermal Shock-resistant Cement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sugama T.; Pyatina, T.; Gill, S.

2012-02-01

We studied the effectiveness of sodium silicate-activated Class F fly ash in improving the thermal shock resistance and in extending the onset of hydration of Secar #80 refractory cement. When the dry mix cement, consisting of Secar #80, Class F fly ash, and sodium silicate, came in contact with water, NaOH derived from the dissolution of sodium silicate preferentially reacted with Class F fly ash, rather than the #80, to dissociate silicate anions from Class F fly ash. Then, these dissociated silicate ions delayed significantly the hydration of #80 possessing a rapid setting behavior. We undertook a multiple heating -watermore » cooling quenching-cycle test to evaluate the cement’s resistance to thermal shock. In one cycle, we heated the 200 and #61616;C-autoclaved cement at 500 and #61616;C for 24 hours, and then the heated cement was rapidly immersed in water at 25 and #61616;C. This cycle was repeated five times. The phase composition of the autoclaved #80/Class F fly ash blend cements comprised four crystalline hydration products, boehmite, katoite, hydrogrossular, and hydroxysodalite, responsible for strengthening cement. After a test of 5-cycle heat-water quenching, we observed three crystalline phase-transformations in this autoclaved cement: boehmite and #61614; and #61543;-Al2O3, katoite and #61614; calcite, and hydroxysodalite and #61614; carbonated sodalite. Among those, the hydroxysodalite and #61614; carbonated sodalite transformation not only played a pivotal role in densifying the cementitious structure and in sustaining the original compressive strength developed after autoclaving, but also offered an improved resistance of the #80 cement to thermal shock. In contrast, autoclaved Class G well cement with and without Class F fly ash and quartz flour failed this cycle test, generating multiple cracks in the cement. The major reason for such impairment was the hydration of lime derived from the dehydroxylation of portlandite formed in the autoclaved cement, causing its volume to expand.« less

Quantification of geopolymers production by chemical methods- A short review

NASA Astrophysics Data System (ADS)

Siyal, Ahmer Ali; Azizli, Khairun Azizi; Ismail, Lukman; Man, Zakaria; Khan, Muhammad Irfan

2015-07-01

Inorganic polymers are the aluminosilicate materials possessing properties superior than ordinary Portland cement. In this review paper the chemical techniques used for determining degree of reaction of fly ash or the quantity of geopolymer material produced have been discussed. These methods determine the amount of product formed in percentages. The methods include HCl method, salicylic acid method, and picric acid method. These methods are not only used for fly ash but they are being used for determining the degree of reactions of metakaolin and other pozzolanic materials. The picric acid is an explosive material and its transportation in high concentration is dangerous. During its use in laboratory there is also the risk of fire associated with it. According to the microscopic analysis results the picric acid attack dissolves small amount of fine unreacted fly ash particles also. The salicylic acid is easily available but the residue from its treatment contains unreacted fly ash particles, hydration phases, and certain parts of unreacted OPC. The residue from HCl and salicylic acid attack contains MgO particles which is the part of the hydration product. The HCl method is mostly used due to simple process and lower standard deviation.

Fungal leaching of valuable metals from a power plant residual ash using Penicillium simplicissimum: Evaluation of thermal pretreatment and different bioleaching methods.

PubMed

Rasoulnia, P; Mousavi, S M; Rastegar, S O; Azargoshasb, H

2016-06-01

Each year a tremendous volume of V-Ni rich ashes is produced by fuel oil consuming power plants throughout the world. Recovery of precious metals existing in these ashes is very important from both economic and environmental aspects. The present research was aimed at investigating bioleaching potential of Penicillium simplicissimum for the recovery of metals from power plant residual ash (PPR ash) using different bioleaching methods such as one-step, two-step, and spent-medium bioleaching at 1% (w/v) pulp density. Furthermore, the effects of thermal pretreatment on leaching of V, Ni, and Fe, as major elements present in PPR ash, were studied. Thermal pretreatment at various temperatures removed the carbonaceous and volatile fraction of the ash and affected the fungal growth and metal leachability. The highest extraction yields of V and Ni were achieved for the original PPR ash, using spent-medium bioleaching in which nearly 100% of V and 40% of Ni were extracted. The maximum extraction yield of Fe (48.3%) was obtained for the pretreated PPR ash at 400°C by spent-medium bioleaching. In addition, the fungal growth in pure culture was investigated through measurement of produced organic acids via high performance liquid chromatography (HPLC). Chemical leaching experiments were performed, using commercial organic acids at the same concentrations as those produced under optimum condition of fungal growth (5237ppm citric, 3666ppm gluconic, 1287ppm oxalic and 188ppm malic acid). It was found that in comparison to chemical leaching, bioleaching improved V and Ni recovery up to 19% and 12%, respectively. Moreover, changes in physical and chemical properties as well as morphology of the samples utilizing appropriate analytical methods such as XRF, XRD, FTIR, and FE-SEM were comprehensively investigated. Copyright © 2016 Elsevier Ltd. All rights reserved.

Eruption processes and deposit characteristics at the monogenetic Mt. Gambier Volcanic Complex, SE Australia: implications for alternating magmatic and phreatomagmatic activity

NASA Astrophysics Data System (ADS)

van Otterloo, Jozua; Cas, Raymond A. F.; Sheard, Malcolm J.

2013-08-01

The ˜5 ka Mt. Gambier Volcanic Complex in the Newer Volcanics Province, Australia is an extremely complex monogenetic, volcanic system that preserves at least 14 eruption points aligned along a fissure system. The complex stratigraphy can be subdivided into six main facies that record alternations between magmatic and phreatomagmatic eruption styles in a random manner. The facies are (1) coherent to vesicular fragmental alkali basalt (effusive/Hawaiian spatter and lava flows); (2) massive scoriaceous fine lapilli with coarse ash (Strombolian fallout); (3) bedded scoriaceous fine lapilli tuff (violent Strombolian fallout); (4) thin-medium bedded, undulating very fine lapilli in coarse ash (dry phreatomagmatic surge-modified fallout); (5) palagonite-altered, cross-bedded, medium lapilli to fine ash (wet phreatomagmatic base surges); and (6) massive, palagonite-altered, very poorly sorted tuff breccia and lapilli tuff (phreato-Vulcanian pyroclastic flows). Since most deposits are lithified, to quantify the grain size distributions (GSDs), image analysis was performed. The facies are distinct based on their GSDs and the fine ash to coarse+fine ash ratios. These provide insights into the fragmentation intensities and water-magma interaction efficiencies for each facies. The eruption chronology indicates a random spatial and temporal sequence of occurrence of eruption styles, except for a "magmatic horizon" of effusive activity occurring at both ends of the volcanic complex simultaneously. The eruption foci are located along NW-SE trending lineaments, indicating that the complex was fed by multiple dykes following the subsurface structures related to the Tartwaup Fault System. Possible factors causing vent migration along these dykes and changes in eruption styles include differences in magma ascent rates, viscosity, crystallinity, degassing and magma discharge rate, as well as hydrological parameters.

Mineralogy, chemical composition, and microstructure of ferrospheres in fly ashes from coal combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yongchun Zhao; Junying Zhang; Junmin Sun

2006-08-15

Fourteen samples of coal and ferrospheres, which were recovered by dry magnetic separation from fly ashes, were collected from five power plants in China. The mineralogy, chemical composition, and microstructure of ferrospheres in fly ashes have been studied by optical microscopy, X-ray diffraction (XRD), Moessbauer spectroscopy, and field emission scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (FSEM-EDX). Iron in ferrospheres mainly occurs as Fe{sub 3}O{sub 4}, {alpha}Fe{sub 2}O{sub 3}, {gamma}Fe{sub 2}O{sub 3}, MgFe{sub 2}O{sub 4}, and Fe{sup 3+}-glass, ferrian spinel, and so on. On the basis of iron content, the ferrospheres in fly ashes are classified into four groups,more » namely ferrooxides, aluminosilicate-bearing ferrooxides, high-ferriferous aluminosilicates, and ferroaluminosilicates . Ferrooxides are derived from the oxidation of iron-bearing minerals, whereas aluminosilicate-bearing ferrooxides, high-ferriferous aluminosilicates, and ferroaluminosilicates are formed by the fusion of different proportions of inherent iron-bearing minerals and clay minerals. According to their microstructure, the ferrospheres in fly ashes are classified into seven groups, namely sheet ferrospheres, dendritic ferrospheres, granular ferrospheres, smooth ferrospheres, ferroplerospheres, porous ferrospheres, and molten drop ferrospheres. Sheet ferrospheres are derived from the oxidation of iron-bearing minerals immediately; smooth ferrospheres, molten drop ferrospheres, ferroplerospheres, and porous ferrospheres are the complex eutectic of inherent iron-bearing minerals and clay minerals; dendritic ferrospheres and granular ferrospheres are formed by the conglutination after the oxidation of iron-bearing minerals. Ferrooxides and aluminosilicate-bearing ferrooxides are important sources of the initial layer that occurs in deposits formed in coal-burning systems. 78 refs., 11 figs., 4 tabs.« less

Method of arsenic removal from water

DOEpatents

Gadgil, Ashok

2010-10-26

A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

Comparison of TOMS and AVHRR volcanic ash retrievals from the August 1992 eruption of Mt. Spurr

USGS Publications Warehouse

Krotkov, N.A.; Torres, O.; Seftor, C.; Krueger, A.J.; Kostinski, A.; Rose, William I.; Bluth, G.J.S.; Schneider, D.; Schaefer, S.J.

1999-01-01

On August 19, 1992, the Advanced Very High Resolution Radiometer (AVHRR) onboard NOAA-12 and NASA's Total Ozone Mapping Spectrometer (TOMS) onboard the Nimbus-7 satellite simultaneously detected and mapped the ash cloud from the eruption of Mt. Spurr, Alaska. The spatial extent and geometry of the cloud derived from the two datasets are in good agreement and both AVHRR split window IR (11-12??m brightness temperature difference) and the TOMS UV Aerosol Index (0.34-0.38??m ultraviolet backscattering and absorption) methods give the same range of total cloud ash mass. Redundant methods for determination of ash masses in drifting volcanic clouds offer many advantages for potential application to the mitigation of aircraft hazards.

Prediction of the Chloride Resistance of Concrete Modified with High Calcium Fly Ash Using Machine Learning

PubMed Central

Marks, Michał; Glinicki, Michał A.; Gibas, Karolina

2015-01-01

The aim of the study was to generate rules for the prediction of the chloride resistance of concrete modified with high calcium fly ash using machine learning methods. The rapid chloride permeability test, according to the Nordtest Method Build 492, was used for determining the chloride ions’ penetration in concrete containing high calcium fly ash (HCFA) for partial replacement of Portland cement. The results of the performed tests were used as the training set to generate rules describing the relation between material composition and the chloride resistance. Multiple methods for rule generation were applied and compared. The rules generated by algorithm J48 from the Weka workbench provided the means for adequate classification of plain concretes and concretes modified with high calcium fly ash as materials of good, acceptable or unacceptable resistance to chloride penetration. PMID:28793740

Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash.

PubMed

Kuboňová, L; Langová, Š; Nowak, B; Winter, F

2013-11-01

Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050°C and in a muffle oven at temperatures from 500 to 1200°C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel. Copyright © 2013 Elsevier Ltd. All rights reserved.

Improvement of the in vitro digestible iron and zinc content of okra (Hibiscus esculentus L.) sauce widely consumed in Sahelian Africa.

PubMed

Avallone, Sylvie; Bohuon, Philippe; Hemery, Youna; Treche, Serge

2007-03-01

The effects of the formulation (okra, fish, soumbala, extract of wood ash) and cooking time of okra sauce on total iron and zinc content and on their in vitro digestibility were evaluated following a Doehlert uniform shell design with 5 factors and 33 trials. Cooking time had no significant effect on in vitro digestible iron and zinc content, whereas formulation did. Each ingredient had a specific effect. Extract of wood ash, which is a source of soluble and digestible iron and zinc, is a good way of increasing the digestible mineral content of the dish. Okra, the main ingredient in this sauce, has a negative effect and should be added in moderate quantities (< 37.7% of the DM of the sauce). An optimization using the desirability function allows us to identify the optimal recipe that enabled the quantity of digestible iron to be doubled and the quantity of digestible zinc to be increased by one third. This recipe calls for a mixture of 37.7% okra, 26.3% dried fish, 18.5% soumbala, and 3.7% extract of wood ash cooked for 25 min.

Review: Application of coal bottom ash as aggregate replacement in highway embankment, acoustic absorbing wall and asphalt mixtures

NASA Astrophysics Data System (ADS)

Afiza Mohammed, Syakirah; Rehan Karim, Mohamed

2017-06-01

Worldwide annual production of coal bottom ash waste was increased in the last decade and is being dumped on landfill over the years. Its improper disposal has become an environmental concern and resulted in a waste of recoverable resources. There is a pressing and on-going need to develop new recycling methods for coal bottom ash. The utilization of coal bottom ash in highway engineering is one of the options to reduce the environmental problems related to the disposal of bottom ash. The present review describe the physical and chemical properties of coal bottom ash waste and its current application as highway embankment material, as acoustic absorbing material and as aggregate replacement in asphalt mixtures. The purpose of this review is to stimulate and promote the effective recycling of coal bottom ash in highway engineering industry.

Accuracy of DXA scanning of the thoracic spine: cadaveric studies comparing BMC, areal BMD and geometric estimates of volumetric BMD against ash weight and CT measures of bone volume.

PubMed

Sran, Meena M; Khan, Karim M; Keiver, Kathy; Chew, Jason B; McKay, Heather A; Oxland, Thomas R

2005-12-01

Biomechanical studies of the thoracic spine often scan cadaveric segments by dual energy X-ray absorptiometry (DXA) to obtain measures of bone mass. Only one study has reported the accuracy of lateral scans of thoracic vertebral bodies. The accuracy of DXA scans of thoracic spine segments and of anterior-posterior (AP) thoracic scans has not been investigated. We have examined the accuracy of AP and lateral thoracic DXA scans by comparison with ash weight, the gold-standard for measuring bone mineral content (BMC). We have also compared three methods of estimating volumetric bone mineral density (vBMD) with a novel standard-ash weight (g)/bone volume (cm3) as measured by computed tomography (CT). Twelve T5-T8 spine segments were scanned with DXA (AP and lateral) and CT. The T6 vertebrae were excised, the posterior elements removed and then the vertebral bodies were ashed in a muffle furnace. We proposed a new method of estimating vBMD and compared it with two previously published methods. BMC values from lateral DXA scans displayed the strongest correlation with ash weight (r=0.99) and were on average 12.8% higher (p<0.001). As expected, BMC (AP or lateral) was more strongly correlated with ash weight than areal bone mineral density (aBMD; AP: r=0.54, or lateral: r=0.71) or estimated vBMD. Estimates of vBMD with either of the three methods were strongly and similarly correlated with volumetric BMD calculated by dividing ash weight by CT-derived volume. These data suggest that readily available DXA scanning is an appropriate surrogate measure for thoracic spine bone mineral and that the lateral scan might be the scan method of choice.

Utilization of coal fly ash in solidification of liquid radioactive waste from research reactor.

PubMed

Osmanlioglu, Ahmet Erdal

2014-05-01

In this study, the potential utilization of fly ash was investigated as an additive in solidification process of radioactive waste sludge from research reactor. Coal formations include various percentages of natural radioactive elements; therefore, coal fly ash includes various levels of radioactivity. For this reason, fly ashes have to be evaluated for potential environmental implications in case of further usage in any construction material. But for use in solidification of radioactive sludge, the radiological effects of fly ash are in the range of radioactive waste management limits. The results show that fly ash has a strong fixing capacity for radioactive isotopes. Specimens with addition of 5-15% fly ash to concrete was observed to be sufficient to achieve the target compressive strength of 20 MPa required for near-surface disposal. An optimum mixture comprising 15% fly ash, 35% cement, and 50% radioactive waste sludge could provide the solidification required for long-term storage and disposal. The codisposal of radioactive fly ash with radioactive sludge by solidification decreases the usage of cement in solidification process. By this method, radioactive fly ash can become a valuable additive instead of industrial waste. This study supports the utilization of fly ash in industry and the solidification of radioactive waste in the nuclear industry.

High-performance self-compacting concrete with the use of coal burning waste

NASA Astrophysics Data System (ADS)

Bakhrakh, Anton; Solodov, Artyom; Naruts, Vitaly; Larsen, Oksana; Alimov, Lev; Voronin, Victor

2017-10-01

Today, thermal power plants are the main producers of energy in Russia. Most of thermal power plants use coal as fuel. The remaining waste of coal burning is ash, In Russia ash is usually kept at dumps. The amount of utilized ash is quite small, less than 13%. Meanwhile, each ash dump is a local ecological disaster. Ash dumps take a lot of place and destroy natural landscape. The use of fly ash in building materials can solve the problem of fly ash dumps in Russia. A lot of papers of scientists are devoted to the use of fly ash as filler in concrete. The main advantage of admixing fly ash in concrete is decrease of amount of used cement. This investigation was held to find out if it is possible to utilize fly ash by its use in high amounts in self-compacting concrete. During experiments three mixtures of SCC with different properties were obtained. The first one is experimental and shows the possibility of obtaining SCC with high compressive strength with 60% of fly ash from the mass of cement. Two other mixtures were optimized with the help of the math planning method to obtain high 7-day and 28-day high compressive strength.

Progression of ash canopy thinning and dieback outward from the initial infestation of emerald ash borer (Coleoptera: Buprestidae) in southeastern Michigan.

PubMed

Smitley, David; Davis, Terrance; Rebek, Eric

2008-10-01

Our objective was to characterize the rate at which ash (Fraxinus spp.) trees decline in areas adjacent to the leading edge of visible ash canopy thinning due to emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae). Trees in southeastern Michigan were surveyed from 2003 to 2006 for canopy thinning and dieback by comparing survey trees with a set of 11 standard photographs. Freeways stemming from Detroit in all directions were used as survey transects. Between 750 and 1,100 trees were surveyed each year. A rapid method of sampling populations of emerald ash borer was developed by counting emerald ash borer emergence holes with binoculars and then felling trees to validate binocular counts. Approximately 25% of the trees surveyed for canopy thinning in 2005 and 2006 also were sampled for emerald ash borer emergence holes using binoculars. Regression analysis indicates that 41-53% of the variation in ash canopy thinning can be explained by the number of emerald ash borer emergence holes per tree. Emerald ash borer emergence holes were found at every site where ash canopy thinning averaged > 40%. In 2003, ash canopy thinning averaged 40% at a distance of 19.3 km from the epicenter of the emerald ash borer infestation in Canton. By 2006, the point at which ash trees averaged 40% canopy thinning had increased to a distance of 51.2 km away from Canton. Therefore, the point at which ash trees averaged 40% canopy thinning, a state of decline clearly visible to the average person, moved outward at a rate of 10.6 km/yr during this period.

Control of emerald ash borer adults and larvae with insecticides

Treesearch

Deborah G. McCullough; David Cappaert; Therese Poland; David R. Smitley

2003-01-01

Virtually no information is available from Asia regarding the ability of insecticide products and application methods to protect ash trees from emerald ash borer. Many landscapers in the Core infestation in southeastern Michigan have promoted various treatments to their customers, but there has been no objective evaluation of these products. Insecticides may also be...

Modeling the effects of emerald ash borer on forest composition in the Midwest and Northeast United States

Treesearch

Ryan D. DeSantis; W. Keith Moser; Robert J. Huggett; Ruhong Li; David N. Wear; Patrick D. Miles

2013-01-01

The nonnative invasive emerald ash borer (Agrilus planipennis Fairmaire; EAB) has caused considerable damage to the ash (Fraxinus spp.) resource in North America. While there are methods to mitigate, contain, control, or even eradicate some nonnative invasive insects, EAB continues to spread across North America. Considering strong...

Developing rearing methods for Tetrastichus planipennisi (Hymenoptera: Eulophidae), a larval endoparasitoid of the emerald ash borer (Coleoptera: Buprestidae)

Treesearch

Jian J. Duan; Mike Ulyshen; Leah Bauer; Ivich Fraser

2011-01-01

Tetrastichus planipennisi Yong, a gregarious koinobiont endoparasitoid, is one of three hymenopteran parasitoids being released in the U.S. for biological control of the emerald ash borer (Agrilus planipennis Fairmair, EAB), an invasive beetle from Asia causing mortality of the ash trees (Fraxinus spp.) in North...

Determination of mechanical behavior of new biocomposites

NASA Astrophysics Data System (ADS)

Busuioceanu, Ioana Iuliana; Enǎchescu, Georgiana-Luminita; Baciu, Florin; Dinu, Gabriela; Ştefǎnescu, Mariana Florentina

2018-02-01

The paper includes the results of experimental research to find new biocomposite materials, consisting of a resin matrix reinforforced with natural fiber waste. The resin used was natural resin collected from coniferous forests in Romania and natural wastes were walnut shells, pine needles and green ash. Despite all the difficulties encountered, regarding the high viscosity of the obtained biocomposites, the sticky character, the high drying and strengthening times, some conclusions could be drawn.

Programmatic Environmental Assessment for Standard Targetry Replacement

DTIC Science & Technology

2006-04-01

Appalachian oak and pine-oak stands. Pine barrens with grassy savannas are found in dry sandy soils, with thick shrubs often growing beneath the... fir . In interior valleys, the coniferous forest is less dense than along the coast; and often contains deciduous trees, such as big-leaf maple...Oregon ash, and black cottonwood. There are prairies that support open stands of oaks, or are broken by groves of Douglas fir and other trees

Feasible experimental study on the utilization of a 300 MW CFB boiler desulfurizating bottom ash for construction applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lu, X.F.; Amano, R.S.

2006-12-15

CFB boiler ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. The disposal in landfills has been the most common means of handling ash in circulating fluidized bed boiler power plants. However for a 300 MW CFB boiler power plant, there will be 600,000 tons of ash discharged per year and will result in great volumes and disposal cost of ash byproduct. It was very necessary to solve the utilization of CFB ash and to decrease the disposal cost of CFB ash. The feasible experimental study results on the utilization of themore » bottom ashes of a 300 MW CFB boiler in Baima power plant in China were reported in this paper. The bottom ashes used for test came from the discharged bottom ashes in a 100 MW CFB boiler in which the anthracite and limestone designed for the 300 MW CFB project was burned. The results of this study showed that the bottom ash could be used for cementitious material, road concrete, and road base material. The masonry cements, road concrete with 30 MPa compressive strength and 4.0 MPa flexural strength, and the road base material used for base courses of the expressway, the main road and the minor lane were all prepared with milled CFB bottom ashes in the lab. The better methods of utilization of the bottom ashes were discussed in this paper.« less

Plume Detection and Plume Top Height Estimation using SLSTR

NASA Astrophysics Data System (ADS)

Virtanen, Timo H.; Kolmonen, Pekka; Sogacheva, Larisa; Rodriguez, Edith; Saponaro, Giulia; de Leeuw, Gerrit

2017-04-01

We present preliminary results on ash and desert dust plume detection and plume top height estimates based on satellite data from the Sea and Land Surface Temperature Radiometer (SLSTR) aboard Sentinel-3, launched in 2016. The methods are based on the previously developed AATSR Correlation Method (ACM) height estimation algorithm, which utilized the data of the preceding similar instrument, Advanced Along Track Scanning Radiometer (AATSR). The height estimate is based on the stereo-viewing capability of SLSTR, which allows to determine the parallax between the satellite's 55° backward and nadir views, and thus the corresponding height. The ash plume detection is based on the brightness temperature difference between between thermal infrared (TIR) channels centered at 11 and 12 μm, which show characteristic signals for both desert dust and ash plumes. The SLSTR instrument provides a unique combination of dual-view capability and a wavelength range from visible to thermal infrared, rendering it an ideal instrument for this work. Accurate information on the volcanic ash position is important for air traffic safety. The ACM algorithm can provide valuable data of both horizontal and vertical ash dispersion. These data may be useful for comparisons with other volcanic ash and desert dust retrieval methods and dispersion models. The current work is being carried out as part of the H2020 project EUNADICS-AV ("European Natural Disaster Coordination and Information System for Aviation"), which started in October 2016.

Thermal co-treatment of combustible hazardous waste and waste incineration fly ash in a rotary kiln.

PubMed

Huber, Florian; Blasenbauer, Dominik; Mallow, Ole; Lederer, Jakob; Winter, Franz; Fellner, Johann

2016-12-01

As current disposal practices for municipal solid waste incineration (MSWI) fly ash are either associated with significant costs or negative environmental impacts, an alternative treatment was investigated in a field scale experiment. Thereto, two rotary kilns were fed with hazardous waste, and moistened MSWI fly ash (water content of 23%) was added to the fuel of one kiln with a ratio of 169kg/Mg hazardous waste for 54h and 300kg/Mg hazardous waste for 48h while the other kiln was used as a reference. It was shown that the vast majority (>90%) of the inserted MSWI fly ash was transferred to the bottom ash of the rotary kiln. This bottom ash complied with the legal limits for non-hazardous waste landfills, thereby demonstrating the potential of the investigated method to transfer hazardous waste (MSWI fly ash) into non-hazardous waste (bottom ash). The results of a simple mixing test (MSWI fly ash and rotary kiln bottom ash have been mixed accordingly without thermal treatment) revealed that the observed transformation of hazardous MSWI fly ash into non-hazardous bottom ash during thermal co-treatment cannot be referred to dilution, as the mixture did not comply with legal limits for non-hazardous waste landfills. For the newly generated fly ash of the kiln, an increase in the concentration of Cd, K and Pb by 54%, 57% and 22%, respectively, was observed. In general, the operation of the rotary kiln was not impaired by the MSWI fly ash addition. Copyright © 2016 Elsevier Ltd. All rights reserved.

Pharmacognostic studies of the leaves and stem of Careya arborea Roxb.

PubMed Central

Gupta, Prakash Chandra; Sharma, Nisha; Rao, Ch V

2012-01-01

Objective To study detailed pharmacognostic profile of leaves and stem of Careya arborea (C. arborea) Roxb. (Lecthyidaceae), an important medicinal plant in the Indian system of medicine. Methods Leaf and stem samples of C. arborea were studied by macroscopical, microscopical, physicochemical, phytochemical, fluorescence analysis of powder of the plant and other methods for standardization recommended by WHO. Results Macroscopically, the leaves are simple, broadly obovate in shape, acuminate apex with crenate, dentate margin, petioles (0.1–1.8 cm) long. Microscopically, the leaf showed the presence of median large size vascular bundle covered with fibrous bundle sheath, arrangement of xylem in cup shape and presence of cortical vascular bundle, patches of sclerenchyma, phloem fibers in groups and brown pigment containing cells in stem are some of the diagnostic features noted from anatomical study. Powder microscopy of leaf revealed the presence of parenchyma cells, xylem with pitted vessels and epidermis with anisocytic stomata. The investigations also included leaf surface data; quantitative leaf microscopy and fluorescence analysis. Physiochemical parameters such as loss on drying, swelling index, extractive values and ash values were also determined and results showed that total ash of the stem bark was about two times higher than leaf and water soluble extractive value of leaf and stem bark was two times higher than alcohol soluble extractive value. Preliminary phytochemical screening showed the presence of triterpenoids, saponins, tannins and flavonoids. Conclusions The results of the study can serve as a valuable source of information and provide suitable standards for identification of this plant material in future investigations and applications. PMID:23569939

Proximate Composition and Nutritional Value of Three Macroalgae: Ascophyllum nodosum, Fucus vesiculosus and Bifurcaria bifurcata

PubMed Central

Agregán, Rubén; Munekata, Paulo E. S.; Carballo, Javier; Şahin, Selin; Lacomba, Ramón

2017-01-01

Proximate composition (moisture, protein, lipid and ash content) and nutritional value (fatty acid, amino acid and mineral profile) of three macroalgae (Ascophyllum nodosum, Fucus vesiculosus and Bifurcaria bifurcate) were studied. Chemical composition was significantly (p < 0.001) different among the three seaweeds. In this regard, the B. bifurcata presented the highest fat content (6.54% of dry matter); whereas, F. vesiculosus showed the highest protein level (12.99% dry matter). Regarding fatty acid content, the polyunsaturated fatty acids (PUFAs) were the most abundant followed by saturated fatty acids (SFAs) and monounsaturated fatty acids (MUFAs). On the other hand, the three seaweeds are a rich source of K (from 3781.35 to 9316.28 mg/100 g), Mn (from 8.28 to 1.96 mg/100 g), Na (from 1836.82 to 4575.71 mg/100 g) and Ca (from 984.73 to 1160.27 mg/100 g). Finally, the most abundant amino acid was glutamic acid (1874.47–1504.53 mg/100 dry matter), followed by aspartic acid (1677.01–800.84 mg/100 g dry matter) and alanine (985.40–655.73 mg/100 g dry matter). PMID:29140261

Quality assessment of dry noodles made from blend of mocaf flour, rice flour and corn flour

NASA Astrophysics Data System (ADS)

Afifah, N.; Ratnawati, L.

2017-12-01

Mocaf flour, rice flour, and corn flour in different concentrations were used to produce dry noodles. The aims of this study were to investigate physicochemical properties of the flours and the quality characteristics of dry noodles made from these flours. Dry noodles were prepared by gelatinization of blending flours followed by feeding the dough to extruder and drying overnight in room temperature. Flours were analyzed for chemical and pasting properties and noodle samples were evaluated for chemical, cooking, and texture properties. The results showed there were significant differences in protein content and elongation between noodles made from blending mocaf and rice flour with that of blending mocaf, rice, and corn flour. The moisture, ash, and protein content of noodle samples ranged from 10.98 to 14.18%, 1.23 to 1.39%, and 4.09 to 5.58%, respectively. Values of noodle cooking quality were ranging from 12.0 - 13.8 minutes, 10.6 to 14.3%, and 204 to 248%, respectively for cooking time, cooking loss, and cooking weight. The elongation, hardness, and adhesiveness of noodles ranged from 276 to 374%, 3,523 to 10,478 gf, and -81.99 to -52.49 g.sec.

Optimal boiler control through real-time monitoring of unburned carbon in fly ash by laser-induced breakdown spectroscopy.

PubMed

Kurihara, Miki; Ikeda, Koji; Izawa, Yoshinori; Deguchi, Yoshihiro; Tarui, Hitoshi

2003-10-20

A laser-induced breakdown spectroscopy (LIBS) technique has been applied for detection of unburned carbon in fly ash, and an automated LIBS unit has been developed and applied in a 1000-MW pulverized-coal-fired power plant for real-time measurement, specifically of unburned carbon in fly ash. Good agreement was found between measurement results from the LIBS method and those from the conventional method (Japanese Industrial Standard 8815), with a standard deviation of 0.27%. This result confirms that the measurement of unburned carbon in fly ash by use of LIBS is sufficiently accurate for boiler control. Measurements taken by this apparatus were also integrated into a boiler-control system with the objective of achieving optimal and stable combustion. By control of the rotating speed of a mill rotary separator relative to measured unburned-carbon content, it has been demonstrated that boiler control is possible in an optimized manner by use of the value of the unburned-carbon content of fly ash.

Characteristics of wood ash and influence on soil properties and nutrient uptake: an overview.

PubMed

Demeyer, A; Voundi Nkana, J C; Verloo, M G

2001-05-01

Wood industries and power plants generate enormous quantities of wood ash. Disposal in landfills has been for long a common method for removal. New regulations for conserving the environment have raised the costs of landfill disposal and added to the difficulties for acquiring new sites for disposal. Over a few decades a number of studies have been carried out on the utilization of wood ashes in agriculture and forestry as an alternative method for disposal. Because of their properties and their influence on soil chemistry the utilization of wood ashes is particularly suited for the fertility management of tropical acid soils and forest soils. This review principally focuses on ash from the wood industry and power plants and considers its physical, chemical and mineralogical characteristics, its effect on soil properties, on the availability of nutrient elements and on the growth and chemical composition of crops and trees, as well as its impact on the environment.

Laser-induced breakdown spectroscopy (LIBS) for rapid analysis of ash, potassium and magnesium in gluten free flours.

PubMed

Markiewicz-Keszycka, Maria; Casado-Gavalda, Maria P; Cama-Moncunill, Xavier; Cama-Moncunill, Raquel; Dixit, Yash; Cullen, Patrick J; Sullivan, Carl

2018-04-01

Gluten free (GF) diets are prone to mineral deficiency, thus effective monitoring of the elemental composition of GF products is important to ensure a balanced micronutrient diet. The objective of this study was to test the potential of laser-induced breakdown spectroscopy (LIBS) analysis combined with chemometrics for at-line monitoring of ash, potassium and magnesium content of GF flours: tapioca, potato, maize, buckwheat, brown rice and a GF flour mixture. Concentrations of ash, potassium and magnesium were determined with reference methods and LIBS. PCA analysis was performed and presented the potential for discrimination of the six GF flours. For the quantification analysis PLSR models were developed; R 2 cal were 0.99 for magnesium and potassium and 0.97 for ash. The study revealed that LIBS combined with chemometrics is a convenient method to quantify concentrations of ash, potassium and magnesium and present the potential to classify different types of flours. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evaluation and comparison of alternative designs for water/solid-waste processing systems for spacecraft

NASA Technical Reports Server (NTRS)

Spurlock, J. M.

1975-01-01

Promising candidate designs currently being considered for the management of spacecraft solid waste and waste-water materials were assessed. The candidate processes were: (1) the radioisotope thermal energy evaporation/incinerator process; (2) the dry incineration process; and (3) the wet oxidation process. The types of spacecraft waste materials that were included in the base-line computational input to the candidate systems were feces, urine residues, trash and waste-water concentrates. The performance characteristics and system requirements for each candidate process to handle this input and produce the specified acceptable output (i.e., potable water, a storable dry ash, and vapor phase products that can be handled by a spacecraft atmosphere control system) were estimated and compared. Recommendations are presented.

Comparison of alkaline industrial wastes for aqueous mineral carbon sequestration through a parallel reactivity study.

PubMed

Noack, Clinton W; Dzombak, David A; Nakles, David V; Hawthorne, Steven B; Heebink, Loreal V; Dando, Neal; Gershenzon, Michael; Ghosh, Rajat S

2014-10-01

Thirty-one alkaline industrial wastes from a wide range of industrial processes were acquired and screened for application in an aqueous carbon sequestration process. The wastes were evaluated for their potential to leach polyvalent cations and base species. Following mixing with a simple sodium bicarbonate solution, chemistries of the aqueous and solid phases were analyzed. Experimental results indicated that the most reactive materials were capable of sequestering between 77% and 93% of the available carbon under experimental conditions in four hours. These materials - cement kiln dust, spray dryer absorber ash, and circulating dry scrubber ash - are thus good candidates for detailed, process-oriented studies. Chemical equilibrium modeling indicated that amorphous calcium carbonate is likely responsible for the observed sequestration. High variability and low reactive fractions render many other materials less attractive for further pursuit without considering preprocessing or activation techniques. Copyright © 2014 Elsevier Ltd. All rights reserved.

Effect of a micro-copolymer addition on the thermal conductivity of fly ash mortars.

PubMed

Durán-Herrera, A; Campos-Dimas, J K; Valdez-Tamez, P L; Bentz, D P

2016-07-01

In this study, a copolymer composed of hollow spherical particles with an average particle size of 90 µm was evaluated as a lightweight aggregate in Portland cement-fly ash mortars to improve the thermal conductivity ( k ) of the composite. Mortars were produced for three different water/binder ratios by mass ( w/b ), 0.4, 0.5 and 0.6. Optimized proportions were obtained for a minimum target compressive strength of 35 kg f /cm 2 (3.4 MPa) according to the requirements of Mexican standards for non-structural masonry units. Thermal conductivity was determined for dry and saturated samples through the transient plane technique with average results of 0.16 W/(m·K) and 0.31 W/(m·K), respectively. These values represent an increment of 23 % and a reduction of 33 %, respectively, in comparison to an efficient Portland cement-based commercially available thermal insulator.

Effect of a micro-copolymer addition on the thermal conductivity of fly ash mortars

PubMed Central

Durán-Herrera, A.; Campos-Dimas, J. K.; Valdez-Tamez, P.L.; Bentz, D. P.

2015-01-01

In this study, a copolymer composed of hollow spherical particles with an average particle size of 90 µm was evaluated as a lightweight aggregate in Portland cement-fly ash mortars to improve the thermal conductivity (k) of the composite. Mortars were produced for three different water/binder ratios by mass (w/b), 0.4, 0.5 and 0.6. Optimized proportions were obtained for a minimum target compressive strength of 35 kgf/cm2 (3.4 MPa) according to the requirements of Mexican standards for non-structural masonry units. Thermal conductivity was determined for dry and saturated samples through the transient plane technique with average results of 0.16 W/(m·K) and 0.31 W/(m·K), respectively. These values represent an increment of 23 % and a reduction of 33 %, respectively, in comparison to an efficient Portland cement-based commercially available thermal insulator. PMID:27453717

Effects of climate on emerald ash borer mortality and the potential for ash survival in North America

Treesearch

Ryan D. DeSantis; W. Keith Moser; Dale D. Gormanson; Marshall G. Bartlett; Bradley Vermunt

2013-01-01

Non-native invasive insects such as the emerald ash borer (Agrilus planipennis Fairmaire; EAB) cause billions of dollars; worth of economic damage and unquantifiable but substantial ecological damage in North America each year. There are methods to mitigate, contain, control, or even eradicate some non-native invasive insects, but so far the spread...

Effects of trap type, placement and ash distribution on emerald ash borer captures in a low density site

Treesearch

Deborah G. McCullough; Nathan W. Siegert; Therese M. Poland; Steven J. Pierce; Su Zie Ahn

2011-01-01

Effective methods for early detection of newly established, low density emerald ash borer (Agrilus planipennis Fairmaire) infestations are critically needed in North America. We assessed adult A. planipennis captures on four types of traps in a 16-ha site in central Michigan. The site was divided into 16 blocks, each comprised of...

Impacts of coal fly ash on plant growth and accumulation of essential nutrients and trace elements by alfalfa (Medicago sativa) grown in a loessial soil.

PubMed

He, Honghua; Dong, Zhigang; Peng, Qi; Wang, Xia; Fan, Chenbin; Zhang, Xingchang

2017-07-15

Coal fly ash (CFA) is a problematic solid waste all over the world. One distinct beneficial reuse of CFA is its utilization in land application as a soil amendment. A pot experiment was carried out to assess the feasibility of using CFA to improve plant growth and increase the supply of plant-essential elements and selenium (Se) of a loessial soil for agricultural purpose. Plants of alfalfa (Medicago sativa) were grown in a loessial soil amended with different rates (5%, 10%, 20% and 40%) of CFA for two years and subjected to four successive cuttings. Dry mass of shoots and roots, concentrations of plant-essential elements and Se in plants were measured. Shoot dry mass and root dry mass were always significantly increased by 5%, 10% and 20% CFA treatments, and by 40% CFA treatment in all harvests except the first one. The CFA had a higher supply of exchangeable phosphorus (P), magnesium (Mg), copper (Cu), zinc (Zn), molybdenum (Mo), and Se than the loessial soil. Shoot P, calcium (Ca), Mg, Mo, boron (B), and Se concentrations were generally markedly increased, but shoot potassium (K), Cu, and Zn concentrations were generally reduced. The CFA can be a promising source of some essential elements and Se for plants grown in the loessial soil, and an application rate of not higher than 5% should be safe for agricultural purpose without causing plant toxicity symptoms in the studied loessial soil and similar soils. Field trials will be carried out to confirm the results of the pot experiment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Compost and Crude Humic Substances Produced from Selected Wastes and Their Effects on Zea mays L. Nutrient Uptake and Growth

PubMed Central

Palanivell, Perumal; Susilawati, Kasim; Ahmed, Osumanu Haruna; Majid, Nik Muhamad

2013-01-01

Production of agriculture and timber commodities leads generation of enormous quantity of wastes. Improper disposal of these agroindustrial wastes pollutes the environment. This problem could be reduced by adding value to them. Therefore, a study was carried out to analyse and compare the nutrients content of RS, RH, SD, and EFB of composts and crude humic substances; furthermore, their effect on growth, dry matter production, and nutrient uptake for Zea mays L., and selected soil chemical properties were evaluated. Standard procedures were used to analyze humic acids (HA), crude fulvic acids (CFA), crude humin (CH), soil, dry matter production and nutrient uptake. Sawdust and RS compost matured at 42 and 47 days, respectively, while RH and EFB composts were less matured at 49th day of composting. Rice straw compost had higher ash, N, P, CEC, HA, K, and Fe contents with lower organic matter, total organic carbon, and C/N and C/P ratios. The HA of sawdust compost showed higher carbon, carboxylic, K, and Ca contents compared to those of RS, RH, and EFB. Crude FA of RS compost showed highest pH, total K, Ca, Mg, and Na contents. Crude humin from RS compost had higher contents of ash, N, P, and CEC. Rice straw was superior in compost, CFA, and CH, while sawdust compost was superior in HA. Application of sawdust compost significantly increased maize plants' diameter, height, dry matter production, N, P, and cations uptake. It also reduced N, P, and K based chemical fertilizer use by 90%. Application of CH and the composts evaluated in this study could be used as an alternative for chemical fertilizers in maize cultivation. PMID:24319353

Chromium behavior during thermal treatment of MSW fly ash.

PubMed

Kirk, Donald W; Chan, Chris C Y; Marsh, Hilary

2002-02-14

Energy-from-waste incineration has been promoted as an environmentally responsible method for handling non-recyclable waste from households. Despite the benefits of energy production, elimination of organic residues and reduction of volume of waste to be landfilled, there is concern about fly ash disposal. Fly ash from an incinerator contains toxic species such as Pb, Zn, Cd and Cr which may leach into soil and ground water if landfilled. Thermal treatment of the fly ash from municipal solid waste has been tested and proposed as a treatment option for removal of metal species such as Pb, Cd and Zn, via thermal re-volatilization. However, Cr is an element that remains in the residue of the heat treated fly ash and appears to become more soluble. This Cr solubilization is of concern if it exceeds the regulatory limit for hazardous waste. Hence, this unexpected behavior of Cr was investigated. The initial work involved microscopic characterization of Cr in untreated and thermally-treated MSW fly ash. This was followed by determining leaching characteristics using standard protocol leaching tests and characterization leaching methods (sequential extraction). Finally, a mechanism explaining the increased solubilization was proposed and tested by reactions of synthetic chemicals.

Heavy Metal Contents and Physical Parameters of Aegiceras corniculatum, Brassica juncea, and Litchi chinensis Honeys from Bangladesh

PubMed Central

Sarker, Nandita; Chowdhury, Muhammed Alamgir Zaman; Fakhruddin, Abu Naieum Muhammad; Fardous, Zeenath; Moniruzzaman, Mohammed; Gan, Siew Hua

2015-01-01

The present study was undertaken to determine the heavy metal levels and the physicochemical parameters (pH, electrical conductivity (EC), and ash, moisture, and total sugar content) of honeys from Bangladesh. Three different floral honeys were investigated, namely, khalsi (Aegiceras corniculatum), mustard (Brassica juncea), and litchi (Litchi chinensis) honeys. The heavy metals in the honeys were determined by using a High Temperature Dry Oxidation method followed by Atomic Absorption Spectroscopy. The mean pH, EC, and ash, moisture, and total sugar contents of the investigated honeys were 3.6, 0.51 mS/cm, 0.18%, 18.83%, and 68.30%, respectively. Iron was the most abundant among all the investigated heavy metals, ranging from 13.51 to 15.44 mg/kg. The mean concentrations of Mn and Zn in the investigated honeys were 0.28 mg/kg and 2.99 mg/kg, respectively. Cd was below the detection limit, and lead was found in some honey samples, but their contents were below the recommended Maximum Acceptable Level. Cr was also found in all of the samples, but its concentration was within the limit. The physicochemical analysis of the honey samples yielded levels within the limits set by the international honey legislation, indicating that the honey samples were of good quality and had acceptable values for maturity, purity, and freshness. PMID:26618176

Heavy Metal Contents and Physical Parameters of Aegiceras corniculatum, Brassica juncea, and Litchi chinensis Honeys from Bangladesh.

PubMed

Sarker, Nandita; Chowdhury, Muhammed Alamgir Zaman; Fakhruddin, Abu Naieum Muhammad; Fardous, Zeenath; Moniruzzaman, Mohammed; Gan, Siew Hua

2015-01-01

The present study was undertaken to determine the heavy metal levels and the physicochemical parameters (pH, electrical conductivity (EC), and ash, moisture, and total sugar content) of honeys from Bangladesh. Three different floral honeys were investigated, namely, khalsi (Aegiceras corniculatum), mustard (Brassica juncea), and litchi (Litchi chinensis) honeys. The heavy metals in the honeys were determined by using a High Temperature Dry Oxidation method followed by Atomic Absorption Spectroscopy. The mean pH, EC, and ash, moisture, and total sugar contents of the investigated honeys were 3.6, 0.51 mS/cm, 0.18%, 18.83%, and 68.30%, respectively. Iron was the most abundant among all the investigated heavy metals, ranging from 13.51 to 15.44 mg/kg. The mean concentrations of Mn and Zn in the investigated honeys were 0.28 mg/kg and 2.99 mg/kg, respectively. Cd was below the detection limit, and lead was found in some honey samples, but their contents were below the recommended Maximum Acceptable Level. Cr was also found in all of the samples, but its concentration was within the limit. The physicochemical analysis of the honey samples yielded levels within the limits set by the international honey legislation, indicating that the honey samples were of good quality and had acceptable values for maturity, purity, and freshness.

[Preliminary processing, processing and usage of Dendrobii Caulis in history].

PubMed

Yang, Wen-yu; Tang, Sheng; Shi, Dong-jun; Chen, Xiang-gui; Li, Ming-yuan; Tang, Xian-fu; Yuan, Chang-jiang

2015-07-01

On account of the dense cuticles of the fresh stem and the light, hard and pliable texture of the dried stem, Dendrobii Caulis is difficult to dry or pulverize. So, it is very important to the ancient doctors that Dendrobii Caulis should be properly treated and applied to keep or evoke its medicinal effects. The current textual research results about the preliminary processing, processing and usage methods of Dendrobii Caulis showed that: (1) In history the clinical use of fresh or processed Dendrobii Caulis as teas and tinctures were very common. (2) Its roots and rhizomes would be removed before using. (3) Some ancillary approaches were applied to shorten drying times, such as rinsing with boiling mulberry-ash soup, washing or soaking with liquor, mixing with rice pulp and then basking, etc. (4) According to the ancients knowledge, the sufficient pulverization, by means of slicing, rasping, hitting or pestling techniques, was necessary for Dendrobii Caulis to take its effects. (5) The heat processing methods for Dendrobii Caulis included stir-baking, stir-frying, steaming, decocting and stewing techniques, usually with liquor as an auxiliary material. Among above mentioned, steaming by pretreating with liquor was most commonly used, and this scheme was colorfully drawn in Bu Yi Lei Gong Pao Zhi Bian Lan (Ming Dynasty, 1591 CE) ; moreover, decocting in advance or long-time simmering so as to prepare paste products were recommended in the Qing Dynasty. (6) Some different processing programs involving stir-baking with grit, air-tightly baking with ondol (Kangs), fumigating with sulfur, which appeared in modern times and brought attractive outward appearance of the drug, went against ancients original intentions of ensuring drug efficacy.

Phenologically informed re-ordering of Landsat to account for inter-annual variability: a method to map Ash trees (Fraxinus spp.) using remotely sensed imagery

NASA Astrophysics Data System (ADS)

Isaacson, B. N.; Singh, A.; Serbin, S. P.; Townsend, P. A.

2009-12-01

Rapid ecosystem invasion by the emerald ash borer (Agrilus planipennis Fairemaire) is forcing resource managers to make decisions regarding how best to manage the pest, but a detailed map of abundance of the host, ash trees of the genus Fraxinus, does not exist, frustrating fully informed management decisions. We have developed methods to map ash tree abundance across a broad spatial extent in Wisconsin using their unique phenology (late leaf-out, early leaf-fall) and the rich dataset of Landsat imagery that can be used to characterize ash senescence with respect to other deciduous species. However, across environmental gradients in Wisconsin, senescence can vary by days or even weeks such that leaf-drop within one species can temporally vary even within a single Landsat footprint. To address this issue, we used phenology products from NASA’s MODIS for North American Carbon Program (NACP) coupled with vegetation indices derived from a time series of Landsat imagery across multiple years to determine the phenological position of each Landsat pixel within a single idealized growing season. Pixels within Landsat images collected in different years were re-arranged in a phenologically-informed time series that described autumn senescence. This characterization of leaf-drop was then related to the abundance of ash trees, producing a spatially-generalizable model of moderate resolution capable of predicting ash abundance across the state using multiple Landsat scenes. Empirical models predicting ash abundance for two Landsat footprints in Wisconsin indicate model fits for ash abundance of R^2=0.65 in north-central WI, and R^2>0.70 in southeastern WI.

Salt-soda sinter process for recovering aluminum from fly ash

DOEpatents

McDowell, William J.; Seeley, Forest G.

1981-01-01

A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

Salt-soda sinter process for recovering aluminum from fly ash

DOEpatents

McDowell, W.J.; Seeley, F.G.

A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na/sub 2/CO/sub 3/ to a temperature in the range 700/sup 0/ to 900/sup 0/C for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acidsoluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

Environmentally friendly use of non-coal ashes in Sweden.

PubMed

Ribbing, C

2007-01-01

The Swedish Thermal Engineering Research Institute (Värmeforsk) initiated an applied research program "Environmentally friendly use of non-coal ashes", in 2002. The program aims at increasing knowledge on the by-products of energy production and their application. The goal of formulating technical and environmental guidelines and assessments is a major point of the program, which is supported by about forty authorities and private organisations. The programme has been divided into four areas: recycling of ashes to forests, geotechnical applications, use in landfilling, and environmental aspects and chemistry. Among all results obtained, the following progress is shown: *Evidence for the positive effects of spreading ashes on forest growth. *A proposal for environmental guidelines on the utilisation of ashes in construction. *A handbook for using non-coal fly ashes in unpaved roads. *Technical and environmental assessments of MSWI bottom ashes in road construction. *Development of the use of ashes with municipal wastewater sludge as a cover for landfills and mine tailings. *Use of ashes from bio-fuels in concrete and replacement of cement in stoop mining. *A method to classify those by-products from combustion that have mirror entries in the EWC as a hazardous or non-hazardous compound. The Ash Programme has also made it possible to increase knowledge on ashes as valuable materials, on quality assurance and on markets for recovered materials.

The leaching characteristics of selenium from coal fly ashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, T.; Wang, J.; Burken, J.G.

2007-11-15

The leaching characteristics of selenium from several bituminous and subbituminous coal fly ashes under different pH conditions were investigated using batch methods. Results indicated that pH had a significant effect on selenium leaching from bituminous coal ash. The minimum selenium leaching occurred in the pH range between 3 and 4, while the maximum selenium leaching occurred at pH 12. The release of selenium from subbituminous coal ashes was very low for the entire experimental pH range, possibly due to the high content of calcium which can form hydration or precipitation products as a sink for selenium. The adsorption results formore » different selenium species indicated that Se(VI) was hardly adsorbable on either bituminous coal ashes or subbitumminous coal ashes at any pH. However, Se(I) was highly adsorbed by bituminous coal ashes under acidic pH conditions and was mostly removed by subbitumminous coal ashes across the entire pH range. This result suggests that the majority of selenium released from the tested fly ashes was Se(IV). A speciation-based model was developed to simulate the adsorption of Se(IV) on bituminous coal fly ash, and the pH-independent adsorption constants of HSeO{sup 3-} and SeO{sub 3}{sup 2-} were determined. The modeling approach is useful for understanding and predicting the release process of selenium from fly ash.« less

The Pearlette family ash beds in the Great Plains: Finding their identities and their roots in the Yellowstone country

USGS Publications Warehouse

Wilcox, R.E.; Naeser, C.W.

1992-01-01

For many years the numerous deposits of so-called 'Pearlette volcanic ash' in the Great Plains region of the United States were considered to be the remnants of the same volcanic event, and were used as a time-stratigraphic marker of probable Middle Pleistocene age. Although a few early workers had suggested that more than one air-fall event might be represented among the Pearlette occurrences, it was not until the latter half of the present century, after identification of volcanic ash beds by detailed chemical and mineralogical methods had been developed, that it could be established that the 'Pearlette family' of volcanic ashes included three ash beds of subtly differing characteristics. Development of isotopic methods of age determination has established that the ages of the three are significantly different (2.09, 1.29, and 0.60 Ma). The area of distribution of the Pearlette family ash beds was found to include not only the Great Plains, but also to extend across the Rocky Mountain and the Basin and Range provinces to the Pacific Ocean. The search for the sources of these three similar appearing ash beds, facilitated greatly by information gained from concurrent mapping projects underway in areas of major Late Cenozoic volcanic activity in western United States, ultimately led to the sites of the caldera-forming eruptions in the Yellowstone National Park region. ?? 1992.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burgess, R.M.; Perron, M.M.; Friedman, C.L.

Approaches for cleaning up contaminated sediments range from dredging to in situ treatment. In this study, we discuss the effects of amending reference and contaminated sediments with coal fly ash to reduce the bioavailability and toxicity of a field sediment contaminated with polycyclic aromatic hydrocarbons (PAHs). Six fly ashes and a coconut charcoal were evaluated in 7-d whole sediment toxicity tests with a marine amphipod (Ampelisca abdita) and mysid (Americamysis bahia). Fly ashes with high carbon content and the coconut charcoal showed proficiency at reducing toxicity. Some of the fly ashes demonstrated toxicity in the reference treatments. It is suspectedmore » that some of this toxicity is related to the presence of ammonia associated with fly ashes as a result of postoxidation treatment to reduce nitrous oxide emissions. Relatively simple methods exist to remove ammonia from fly ash before use, and fly ashes with low ammonia content are available. Fly ashes were also shown to effectively reduce overlying water concentrations of several PAHs. No evidence was seen of the release of the metals cadmium, copper, nickel, or lead from the fly ashes. A preliminary 28-d polychaete bioaccumulation study with one of the high-carbon fly ashes and a reference sediment was also performed. Although preliminary, no evidence was seen of adverse effects to worm growth or lipid content or of accumulation of PAHs or mercury from exposure to the fly ash. These data show fly ashes with high carbon content could represent viable remedial materials for reducing the bioavailability of organic contaminants in sediments.« less

Determination of selected elements in whole coal and in coal ash from the eight argonne premium coal samples by atomic absorption spectrometry, atomic emission spectrometry, and ion-selective electrode

USGS Publications Warehouse

Doughten, M.W.; Gillison, J.R.

1990-01-01

Methods for the determination of 24 elements in whole coal and coal ash by inductively coupled argon plasma-atomic emission spectrometry, flame, graphite furnace, and cold vapor atomic absorption spectrometry, and by ion-selective electrode are described. Coal ashes were analyzed in triplicate to determine the precision of the methods. Results of the analyses of NBS Standard Reference Materials 1633, 1633a, 1632a, and 1635 are reported. Accuracy of the methods is determined by comparison of the analysis of standard reference materials to their certified values as well as other values in the literature.

Continuous air agglomeration method for high carbon fly ash beneficiation

DOEpatents

Gray, McMahon L.; Champagne, Kenneth J.; Finseth, Dennis H.

2000-01-01

The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

EVALUATION OF THE EFFECTS OF COAL FLY ASH AMENDMENTS ON THE TOXICITY OF A CONTAMINATED MARINE SEDIMENT

PubMed Central

Burgess, Robert M.; Perron, Monique M.; Friedman, Carey L.; Suuberg, Eric M.; Pennell, Kelly G.; Cantwell, Mark G.; Pelletier, Marguerite C.; Ho, Kay T.; Serbst, Jonathan R.; Ryba, Stephan A.

2013-01-01

Approaches for cleaning-up contaminated sediments range from dredging to in situ treatment. In the present report, we discuss the effects of amending reference and contaminated sediments with coal fly ash to reduce the bioavailability and toxicity of a field sediment contaminated with polycyclic aromatic hydrocarbons (PAHs). Six fly ashes and a coconut charcoal were evaluated in 7 d whole sediment toxicity tests with a marine amphipod (Ampelisca abdita) and mysid (Americamysis bahia). Fly ashes with high carbon content and the coconut charcoal showed proficiency at reducing toxicity. Some of the fly ashes demonstrated toxicity in the reference treatments. It is suspected that some of this toxicity is related to the presence of ammonia associated with fly ashes as a result of post-oxidation treatment to reduce nitrous oxides emissions. Relatively simple methods exist to remove ammonia from fly ash prior to use and fly ashes with low ammonia content are available. Fly ashes were also shown to effectively reduce overlying water concentrations of several PAHs. There was no evidence of the release of the metals cadmium, copper, nickel or lead from the fly ashes. A preliminary 28 d polychaete bioaccumulation study with one of the high carbon fly ashes and a reference sediment was also performed. Although preliminary, there was no evidence of adverse effects to worm growth or lipid content, or the accumulation of PAHs or mercury from exposure to the fly ash. These data show fly ashes with high carbon contents may represent viable remedial materials for reducing the bioavailability of organic contaminants in sediments. PMID:18717615

Photogrammetric retrieval of volcanic ash cloud top height from SEVIRI and MODIS

NASA Astrophysics Data System (ADS)

Zakšek, Klemen; Hort, Matthias; Zaletelj, Janez; Langmann, Bärbel

2013-04-01

Even if erupting in remote areas, volcanoes can have a significant impact on the modern society due to volcanic ash dispersion in the atmosphere. The ash does not affect merely air traffic - its transport in the atmosphere and its deposition on land and in the oceans may also significantly influence the climate through modifications of atmospheric CO2. The emphasis of this contribution is the retrieval of volcanic ash plume height (ACTH). ACTH is important information especially for air traffic but also to predict ash transport and to estimate the mass flux of the ejected material. ACTH is usually estimated from ground measurements, pilot reports, or satellite remote sensing. But ground based instruments are often not available at remote volcanoes and also the pilots reports are a matter of chance. Volcanic ash cloud top height (ACTH) can be monitored on the global level using satellite remote sensing. The most often used method compares brightness temperature of the cloud with the atmospheric temperature profile. Because of uncertainties of this method (unknown emissivity of the ash cloud, tropopause, etc.) we propose photogrammetric methods based on the parallax between data retrieved from geostationary (SEVIRI) and polar orbiting satellites (MODIS). The parallax is estimated using automatic image matching in three level image pyramids. The procedure works well if the data from both satellites are retrieved nearly simultaneously. MODIS does not retrieve the data at exactly the same time as SEVIRI. To compensate for advection we use two sequential SEVIRI images (one before and one after the MODIS retrieval) and interpolate the cloud position from SEVIRI data to the time of MODIS retrieval. ACTH is then estimated by intersection of corresponding lines-of-view from MODIS and interpolated SEVIRI data. The proposed method was tested using MODIS band 1 and SEVIRI HRV band for the case of the Eyjafjallajökull eruption in April 2010. The parallax between MODIS and SEVIRI data can reach over 30 km which implies ACTH of more than 12 km. The accuracy of ACTH was estimated to 0.6 km. The limitation of this procedure is that it has difficulties with automatic image matching if the ash cloud is not opaque.

The influence of using volcanic ash and lime ash as filler on compressive strength in self compacting concrete

NASA Astrophysics Data System (ADS)

Karolina, Rahmi; Panatap Simanjuntak, Murydrischy

2018-03-01

Self Compacting Concrete (SCC) is a technology which is developing today in which concrete solidifies by itself without using vibrator. Casting conventional concrete which has a lot of reinforcement bars sometimes finds difficulty in achieving optimal solidity. The method used to solve this problem is by using SCC technology. SCC was made by using filler, volcanic ash, and lime ash as the filling materials so that the concrete became more solid and hollow space could be filled up. The variation of using these two materials was 10%, 15%, 20%, and 25% of the cementitious mass and using 1% of superplasticizer from cementitious material. The supporting testing was done by using the test when the concrete was still fluid and when it was solid. Malleable concrete was tested by using EFNARC 2002 standard in slump flow test, v-funnel test, l-shaped box test, and j-ring test to obtain filling ability and passing ability. In this malleable lime concrete test, there was the decrease, compared with normal SCC concrete without adding volcanic ash and lime ash. Testing was also done in solid concrete in compressive strength, tensile strength, and concrete absorption. The result of the testing showed that the optimum tensile strength in Variation 1, without volcanic ash and lime ash – with 1% of superplasticizer was 39.556 MPa, the optimum tensile strength in Variation 1, without volcanic ash and lime ash- with 1% of super-plasticizer was 3.563 MPa, while the value of optimum absorption which occurred in Variation 5 (25% of volcanic ash + 25% of lime ash + 50% of cement + 1% of superplasticizer) was 1.313%. This was caused by the addition of volcanic ash and lime ash which had high water absorption.

Process Design and Economics for the Production of Algal Biomass: Algal Biomass Production in Open Pond Systems and Processing Through Dewatering for Downstream Conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, Ryan; Markham, Jennifer; Kinchin, Christopher

2016-02-17

This report describes in detail a set of aspirational design and process targets to better understand the realistic economic potential for the production of algal biomass for subsequent conversion to biofuels and/or coproducts, based on the use of open pond cultivation systems and a series of dewatering operations to concentrate the biomass up to 20 wt% solids (ash-free dry weight basis).

Sustainable Sources of Biomass for Bioremediation of Heavy Metals in Waste Water Derived from Coal-Fired Power Generation

PubMed Central

Saunders, Richard J.; Paul, Nicholas A.; Hu, Yi; de Nys, Rocky

2012-01-01

Biosorption of heavy metals using dried algal biomass has been extensively described but rarely implemented. We contend this is because available algal biomass is a valuable product with a ready market. Therefore, we considered an alternative and practical approach to algal bioremediation in which algae were cultured directly in the waste water stream. We cultured three species of algae with and without nutrient addition in water that was contaminated with heavy metals from an Ash Dam associated with coal-fired power generation and tested metal uptake and bioremediation potential. All species achieved high concentrations of heavy metals (to 8% dry mass). Two key elements, V and As, reached concentrations in the biomass of 1543 mg.kg−1 DW and 137 mg.kg−1 DW. Growth rates were reduced by more than half in neat Ash Dam water than when nutrients were supplied in excess. Growth rate and bioconcentration were positively correlated for most elements, but some elements (e.g. Cd, Zn) were concentrated more when growth rates were lower, indicating the potential to tailor bioremediation depending on the pollutant. The cosmopolitan nature of the macroalgae studied, and their ability to grow and concentrate a suite of heavy metals from industrial wastes, highlights a clear benefit in the practical application of waste water bioremediation. PMID:22590550

Effect of glyphosate acid on biochemical markers of periphyton exposed in outdoor mesocosms in the presence and absence of the mussel Limnoperna fortunei.

PubMed

Iummato, María Mercedes; Pizarro, Haydée; Cataldo, Daniel; Di Fiori, Eugenia; Dos Santos Afonso, María; Del Carmen Ríos de Molina, María; Juárez, Ángela Beatriz

2017-07-01

Glyphosate is currently the most widely used herbicide in agricultural production. It generally enters aquatic ecosystems through surface water runoff and aerial drift. We evaluated the effect of glyphosate acid on biochemical parameters of periphyton exposed to concentrations of 1, 3, and 6 mg/L in outdoor mesocosms in the presence and absence of the mussel Limnoperna fortunei. Periphyton ash-free dry weight, chlorophyll a content, carotene/chlorophyll a ratio, lipid peroxidation levels, and superoxide dismutase and catalase activities were determined at days 0, 1, 7, 14, and 26 of the experimental period. Ash-free dry weight was similar between control and glyphosate-treated periphyton in the absence of L. fortunei. The latter had significantly lower carotene to chlorophyll a ratios and enzyme activities, and higher lipid peroxidation levels and chlorophyll a content than the former. These results show an adverse effect of glyphosate on the metabolism of periphyton community organisms, possibly inducing oxidative stress. On the contrary, no differences were observed in any of these variables between control and glyphosate-treated periphyton in the presence of L. fortunei. Mussels probably attenuated the herbicide effects by contributing to glyphosate dissipation. The results also demonstrate that biochemical markers provide useful information that may warn of herbicide impact on periphyton communities. Environ Toxicol Chem 2017;36:1775-1784. © 2016 SETAC. © 2017 SETAC.

Real-Time Estimation of Volcanic ASH/SO2 Cloud Height from Combined Uv/ir Satellite Observations and Numerical Modeling

NASA Astrophysics Data System (ADS)

Vicente, Gilberto A.

An efficient iterative method has been developed to estimate the vertical profile of SO2 and ash clouds from volcanic eruptions by comparing near real-time satellite observations with numerical modeling outputs. The approach uses UV based SO2 concentration and IR based ash cloud images, the volcanic ash transport model PUFF and wind speed, height and directional information to find the best match between the simulated and the observed displays. The method is computationally fast and is being implemented for operational use at the NOAA Volcanic Ash Advisory Centers (VAACs) in Washington, DC, USA, to support the Federal Aviation Administration (FAA) effort to detect, track and measure volcanic ash cloud heights for air traffic safety and management. The presentation will show the methodology, results, statistical analysis and SO2 and Aerosol Index input products derived from the Ozone Monitoring Instrument (OMI) onboard the NASA EOS/Aura research satellite and from the Global Ozone Monitoring Experiment-2 (GOME-2) instrument in the MetOp-A. The volcanic ash products are derived from AVHRR instruments in the NOAA POES-16, 17, 18, 19 as well as MetOp-A. The presentation will also show how a VAAC volcanic ash analyst interacts with the system providing initial condition inputs such as location and time of the volcanic eruption, followed by the automatic real-time tracking of all the satellite data available, subsequent activation of the iterative approach and the data/product delivery process in numerical and graphical format for operational applications.

Microphysical Properties of Alaskan Volcanic Ash

NASA Astrophysics Data System (ADS)

Puthukkudy, A.; Espinosa, R.; Rocha Lima, A.; Remer, L.; Colarco, P. R.; Whelley, P.; Krotkov, N. A.; Young, K.; Dubovik, O.; Wallace, K.; Martins, J. V.

2017-12-01

Volcanic ash has the potential to cause a variety of severe problems for human health and the environment. Therefore, effective monitoring of the dispersion and fallout from volcanic ash clouds and characterization of the aerosol particle properties are essential. One way to acquire information from volcanic clouds is through satellite remote sensing: such images have greater coverage than ground-based observations and can present a "big picture" perspective. A challenge of remote sensing is that assumptions of certain properties of the target are often a pre-requisite for making accurate and quantitative retrievals. For example, detailed information about size distribution, sphericity, and optical properties of the constituent matter is needed or must be assumed. The same kind of information is also needed for atmospheric transport models to properly simulate the dispersion and fallout of volcanic ash. Presented here is a laboratory method to determine the microphysical and optical properties of volcanic ash samples collected from two Alaskan volcanoes with markedly different compositions. Our method uses a Polarized Imaging Nephelometer (PI-Neph) and a system that re-suspends the particles in an air flow. The PI-Neph measures angular light scattering and polarization of the re-suspended particles from 3o to 175o in scattering angle, with an angular resolution of 1o . Primary measurements include phase function and polarized phase function at three wavelengths (445nm, 532nm, and 661nm). Size distribution, sphericity, and complex refractive index are retrieved indirectly from the PI-Neph measurements using the GRASP (Generalized Retrieval of Aerosol and Surface Properties) inversion algorithm. We report the results of this method applied to samples from the Mt. Okmok (2008) and Mt. Katmai (1912) volcanic eruptions. To our knowledge, this is the first time direct measurements of phase matrix elements of ash from Mt. Okmok and Mt. Katmai have been reported. Retrieved microphysical properties show that Mt. Katmai ash is less absorbing than the Mt. Okmok ash in visible wavelengths. Phase function of these Alaskan volcanic ashes is smooth curve without any significant features. Phase function and polarized phase function measured do not exhibit strong spectral dependence in visible wavelengths.

Properties and Leachability of Self-Compacting Concrete Incorporated with Fly Ash and Bottom Ash

NASA Astrophysics Data System (ADS)

Kadir, Aeslina Abdul; Ikhmal Haqeem Hassan, Mohd; Jamaluddin, Norwati; Bakri Abdullah, Mohd Mustafa Al

2016-06-01

The process of combustion in coal-fired power plant generates ashes, namely fly ash and bottom ash. Besides, coal ash produced from coal combustion contains heavy metals within their compositions. These metals are toxic to the environment as well as to human health. Fortunately, treatment methods are available for these ashes, and the use of fly ash and bottom ash in the concrete mix is one of the few. Therefore, an experimental program was carried out to study the properties and determine the leachability of selfcompacting concrete incorporated with fly ash and bottom ash. For experimental study, self-compacting concrete was produced with fly ash as a replacement for Ordinary Portland Cement and bottom ash as a replacement for sand with the ratios of 10%, 20%, and 30% respectively. The fresh properties tests conducted were slump flow, t500, sieve segregation and J-ring. Meanwhile for the hardened properties, density, compressive strength and water absorption test were performed. The samples were then crushed to be extracted using Toxicity Characteristic Leaching Procedure and heavy metals content within the samples were identified accordingly using Atomic Absorption Spectrometry. The results demonstrated that both fresh and hardened properties were qualified to categorize as self-compacting concrete. Improvements in compressive strength were observed, and densities for all the samples were identified as a normal weight concrete with ranges between 2000 kg/m3 to 2600 kg/m3. Other than that, it was found that incorporation up to 30% of the ashes was safe as the leached heavy metals concentration did not exceed the regulatory levels, except for arsenic. In conclusion, this study will serve as a reference which suggests that fly ash and bottom ash are widely applicable in concrete technology, and its incorporation in self-compacting concrete constitutes a potential means of adding value to appropriate mix and design.

[Determination of trace metals in atmospheric dry deposition with a heavy matrix of PUF by inductively coupled plasma mass spectroscopy after microwave digestion].

PubMed

Pan, Yue-peng; Wang, Yue-si; Yang, Yong-jie; Wu, Dan; Xin, Jin-yuan; Fan, Wen-yan

2010-03-01

Interest in atmospheric dry deposition results mostly from concerns about the effects of the deposited trace elements entering waterbody, soil and vegetation as well as their subsequent health effects. A microwave assisted digestion method followed by inductively coupled plasma mass spectrometric (MAD-ICP/MS) analysis was developed to determine the concentrations of a large number of trace metals in atmospheric dry deposition samples with a heavy matrix of polyurethane foam (PUF). A combination of HNO3-H2O2-HF was used for digestion. The experimental protocol for the microwave assisted digestion was established using two different SRMs (GBW 07401, Soil and GBW 08401, Coal fly ash). Subsequently, blanks and limits of detection for total trace metal concentrations were determined for PUF filter which was used for dry deposition sampling. Finally, the optimized digestion method was applied to real world atmospheric dry deposition samples collected at 10 sites in Jingjinji area in winter from Dec. 2007 to Feb. 2008. The results showed that the area-averaged total mass fluxes ranged between 85 and 912 mg x (m2 x d)(-1), and fluxes of most elements were highest at Baoding and lowest at Xinglong. In addition, the elemental fluxes in urban areas of Beijing, Tianjin and Tangshan were measured to be higher than that in suburb and rural sites. The average fluxes of crust elements (A1, Fe, Mn, K, Na, Ca and Mg) were one to three orders of magnitude higher than anthropogenic elements (Cu, Pb, Cr, Ni, V, Zn and Ba), varying from 151 to 16034 microg x (m2 x d)(-1) versus 14 to 243 microg x (m2 x d)(-1). Zinc was the most abundant heavy metal and calcium the highest of the crust elements while the elements Mo, Co, Cd, As and Be deposited less or even could not be detected. The anthropogenic and crustal contributions were estimated by employing enrichment factors (EF) calculated relative to the average crustal composition. The EF values of all elements except Pb and Zn were below 10, suggesting that local soil and/or dust generally dominate in the dry deposition flux.

Furthering the investigation of eruption styles through quantitative shape analyses of volcanic ash particles

NASA Astrophysics Data System (ADS)

Nurfiani, D.; Bouvet de Maisonneuve, C.

2018-04-01

Volcanic ash morphology has been quantitatively investigated for various aims such as studying the settling velocity of ash for modelling purposes and understanding the fragmentation processes at the origin of explosive eruptions. In an attempt to investigate the usefulness of ash morphometry for monitoring purposes, we analyzed the shape of volcanic ash particles through a combination of (1) traditional shape descriptors such as solidity, convexity, axial ratio and form factor and (2) fractal analysis using the Euclidean Distance transform (EDT) method. We compare ash samples from the hydrothermal eruptions of Iwodake (Japan) in 2013, Tangkuban Perahu (Indonesia) in 2013 and Marapi (Sumatra, Indonesia) in 2015, the dome explosions of Merapi (Java, Indonesia) in 2013, the Vulcanian eruptions of Merapi in 2010 and Tavurvur (Rabaul, Papaua New Guinea) in 2014, and the Plinian eruption of Kelud (Indonesia) in 2014. Particle size and shape measurements were acquired from a Particle Size Analyzer with a microscope camera attached to the instrument. Clear differences between dense/blocky particles from hydrothermal or dome explosions and vesicular particles produced by the fragmentation of gas-bearing molten magma are well highlighted by conventional shape descriptors and the fractal method. In addition, subtle differences between dense/blocky particles produced by hydrothermal explosions, dome explosions, or quench granulation during phreatomagmatic eruptions can be evidenced with the fractal method. The combination of shape descriptors and fractal analysis is therefore potentially able to distinguish between juvenile and non-juvenile magma, which is of importance for eruption monitoring.

Effect of three different bariatric obesity surgery procedures on nutrient and energy digestibility using a swine experimental model.

PubMed

Gandarillas, Mónica; Hodgkinson, Suzanne Marie; Riveros, José Luis; Bas, Fernando

2015-09-01

Morbid obesity is a worldwide health concern that compromises life quality and health status of obese human subjects. Bariatric surgery for treating morbid obesity remains as one of the best alternatives to promote excess weight loss and to reduce co-morbidities. We have not found studies reporting nutrients and energy balance considering digestibility trials in humans following surgery. The purpose of this study was to determine protein, lipid, fiber, energy, calcium, and phosphorous digestibility in a swine model that underwent ileal transposition (IT), sleeve gastrectomy with ileal transposition (SGIT), Roux-en-Y gastric bypass (RYGBP), and with sham operated animals (SHAM). Thirty-two pigs were randomly assigned to four laparoscopic procedures: IT (n = 8), RYGBP (n = 8), SGIT (n = 8), and Sham-operated pigs (n = 8). From day 0 postsurgery to 130, pigs were weighed monthly to determine live weight and weight gain was calculated for each month postsurgery until day 130. Food intake in a metabolic weight basis was calculated by measuring ad libitum food intake at day 130. Swine were fitted into metabolic crates to determine digestibility coefficients of dry matter, protein, fat, fiber, ash, energy, calcium, and phosphorous from day 130. A one-way ANOVA and Student-Newman-Keuls were used to detect differences in weight, food intake, and digestibility coefficients. Digestibility values for dry matter, fiber, phosphorus, and energy showed no differences among groups (P > 0.05). However, significant differences (P ≤ 0.05) were encountered among groups for fat, protein, ash, and calcium digestibilities. The RYGBP procedure, when applied to the pig model, significantly reduced calcium, fat, and ash digestibility, which did not occur with SGIT or IT procedure, when compared with Sham-operated animals. © 2015 by the Society for Experimental Biology and Medicine.

Structure, properties, and surfactant adsorption behavior of fly ash carbon

NASA Astrophysics Data System (ADS)

Kulaots, Indrek

The objective of this research was to suggest methods by which certain problems associated with use of coal fly ash as a pozzolanic agent in concrete mixtures could be alleviated, guided by a better characterization of fly ash properties. A sample suite of eighty fly ashes was gathered from utilities across the world (mainly US-based) and included ashes from coals ranging in rank from bituminous to lignite. The widely used foam index test is used to characterize ashes with respect to their propensity to adsorb surfactants (called Air Entraining Admixtures or AEAs) used to impart freeze-thaw resistance to concrete. In ash-containing concrete mixtures, AEAs are adsorbed from the polar concrete-water solution onto non-polar unburned carbon surfaces in the ash. The AEA uptake by fly ashes only crudely correlates with the amount of carbon in the fly ash, because carbon surface area, accessibility and polarity all play a role in determining adsorption capacities. Fly ash carbon particle size distribution is also a key factor. Fine carbon particles in fly ash fractions of <106mum are responsible for about 90% of surfactant adsorption capacity. Surfactant adsorption on fly ash carbon is, in the foam index test, a dynamic process. The time of the test (typically <10 minutes) is not long enough to permit penetration of small porosity by the relatively large AEA molecules, and only the most readily available adsorption surface near the geometrical surface of the carbon particles is utilized. The nature of the foam index test was also examined, and it is recommended that a more standardized test procedure based upon pure reagents be adopted for examining the nature of fly ashes. Several possible reagents were identified. Room temperature fly ash ozonation is a powerful technique that allows increasing fly ash surface polarity in a relatively short time and thus is very effective for decreasing the AEA uptake capacity. Depending on the ozone input concentration, sample amount and contact time, surfactant uptake capacity decreases by a factor of two or more following reaction of only 0--1g O3/kg-ash, bringing many ashes into compliance with AEA uptake requirements.

Development of a sintering process for recycling oil shale fly ash and municipal solid waste incineration bottom ash into glass ceramic composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Zhikun; Zhang, Lei; Li, Aimin, E-mail: leeam@dlut.edu.cn

Highlights: • Glass ceramic composite is prepared from oil shale fly ash and MSWI bottom ash. • A novel method for the production of glass ceramic composite is presented. • It provides simple route and lower energy consumption in terms of recycling waste. • The vitrified slag can promote the sintering densification process of glass ceramic. • The performances of products decrease with the increase of oil shale fly ash content. - Abstract: Oil shale fly ash and municipal solid waste incineration bottom ash are industrial and municipal by-products that require further treatment before disposal to avoid polluting the environment.more » In the study, they were mixed and vitrified into the slag by the melt-quench process. The obtained vitrified slag was then mixed with various percentages of oil shale fly ash and converted into glass ceramic composites by the subsequent sintering process. Differential thermal analysis was used to study the thermal characteristics and determine the sintering temperatures. X-ray diffraction analysis was used to analyze the crystalline phase compositions. Sintering shrinkage, weight loss on ignition, density and compressive strength were tested to determine the optimum preparation condition and study the co-sintering mechanism of vitrified amorphous slag and oil shale fly ash. The results showed the product performances increased with the increase of sintering temperatures and the proportion of vitrified slag to oil shale fly ash. Glass ceramic composite (vitrified slag content of 80%, oil shale fly ash content of 20%, sintering temperature of 1000 °C and sintering time of 2 h) showed the properties of density of 1.92 ± 0.05 g/cm{sup 3}, weight loss on ignition of 6.14 ± 0.18%, sintering shrinkage of 22.06 ± 0.6% and compressive strength of 67 ± 14 MPa. The results indicated that it was a comparable waste-based material compared to previous researches. In particular, the energy consumption in the production process was reduced compared to conventional vitrification and sintering method. Chemical resistance and heavy metals leaching results of glass ceramic composites further confirmed the possibility of its engineering applications.« less

Emerald ash borer invasion of North America: history, biology, ecology, impacts, and management.

PubMed

Herms, Daniel A; McCullough, Deborah G

2014-01-01

Since its accidental introduction from Asia, emerald ash borer (EAB), Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), has killed millions of ash trees in North America. As it continues to spread, it could functionally extirpate ash with devastating economic and ecological impacts. Little was known about EAB when it was first discovered in North America in 2002, but substantial advances in understanding of EAB biology, ecology, and management have occurred since. Ash species indigenous to China are generally resistant to EAB and may eventually provide resistance genes for introgression into North American species. EAB is characterized by stratified dispersal resulting from natural and human-assisted spread, and substantial effort has been devoted to the development of survey methods. Early eradication efforts were abandoned largely because of the difficulty of detecting and delineating infestations. Current management is focused on biological control, insecticide protection of high-value trees, and integrated efforts to slow ash mortality.

Quantifying volcanic ash dispersal and impact of the Campanian Ignimbrite super-eruption

NASA Astrophysics Data System (ADS)

Costa, A.; Folch, A.; Macedonio, G.; Giaccio, B.; Isaia, R.; Smith, V. C.

2012-05-01

We apply a novel computational approach to assess, for the first time, volcanic ash dispersal during the Campanian Ignimbrite (Italy) super-eruption providing insights into eruption dynamics and the impact of this gigantic event. The method uses a 3D time-dependent computational ash dispersion model, a set of wind fields, and more than 100 thickness measurements of the CI tephra deposit. Results reveal that the CI eruption dispersed 250-300 km3 of ash over ˜3.7 million km2. The injection of such a large quantity of ash (and volatiles) into the atmosphere would have caused a volcanic winter during the Heinrich Event 4, the coldest and driest climatic episode of the Last Glacial period. Fluorine-bearing leachate from the volcanic ash and acid rain would have further affected food sources and severely impacted Late Middle-Early Upper Paleolithic groups in Southern and Eastern Europe.

Wetting and Spreading of Molten Volcanic Ash in Jet Engines.

PubMed

Song, Wenjia; Lavallée, Yan; Wadsworth, Fabian B; Hess, Kai-Uwe; Dingwell, Donald B

2017-04-20

A major hazard to jet engines posed by volcanic ash is linked to the wetting and spreading of molten ash droplets on engine component surfaces. Here, using the sessile drop method, we study the evolution of the wettability and spreading of volcanic ash. We employ rapid temperature changes up to 1040-1450 °C, to replicate the heating conditions experienced by volcanic ash entering an operating jet engine. In this scenario, samples densify as particles coalesce under surface tension until they form a large system-sized droplet (containing remnant gas bubbles and crystals), which subsequently spreads on the surface. The data exhibit a transition from a heterogeneous to a homogeneous wetting regime above 1315 °C as crystals in the drops are dissolved in the melt. We infer that both viscosity and microstructural evolution are key controls on the attainment of equilibrium in the wetting of molten volcanic ash droplets.

Photogrammetric Retrieval of Etna's Plume Height from SEVIRI and MODIS

NASA Astrophysics Data System (ADS)

Zaksek, K.; Ganci, G.; Hort, M. K.

2013-12-01

Even remote volcanoes can impact the modern society due to volcanic ash dispersion in the atmosphere. A lot of research is currently dedicated to minimizing the impact of volcanic ash on air traffic. But the ash transport in the atmosphere and its deposition on land and in the oceans may also significantly influence the climate through modifications of atmospheric CO2. The emphasis of this contribution is the retrieval of volcanic ash plume height. This is important information for air traffic, to predict ash transport and to estimate the mass flux of the ejected material. The best way to monitor volcanic ash cloud top height (ACTH) on the global level is using satellite remote sensing. The most commonly used method for satellite ACTH compares brightness temperature of the cloud with the atmospheric temperature profile. Because of well-known uncertainties of this method we propose photogrammetric methods based on the parallax between data retrieved from geostationary (SEVIRI, HRV band; 1000 m spatial resolution) and polar orbiting satellites (MODIS, band 1; 250 m spatial resolution). The procedure works well if the data from both satellites are retrieved nearly simultaneously butMODIS does not retrieve the data at exactly the same time as SEVIRI. To compensate for advection in the atmosphere we use two sequential SEVIRI images (one before and one after the MODIS retrieval) and interpolate the cloud position from SEVIRI data to the time of MODIS retrieval. ACTH is then estimated by intersection of corresponding lines-of-view from MODIS and interpolated SEVIRI data. The proposed method has already been tested for the case of the Eyjafjallajökull eruption in April 2010. This case study had almost perfect conditions as the plume was vast and stretching over a homogeneous background - ocean. Here we show results of ACTH estimation during lava fountaining activity of Mount Etna in years 2011-2013. This activity resulted in volcanic ash plumes that are much smaller than the plume observed at Eyjafjallajökull eruption. Challenges and problems occurring while applying the photogrammetric method to small and medium sized plumes will be discussed and solutions to those challenges will be shown.

Experimental study on the effect of calcination on the volcanic ash activity of diatomite

NASA Astrophysics Data System (ADS)

Xiao, Liguang; Pang, Bo

2017-09-01

The volcanic ash activity of diatomite was studied under the conditions of aerobic calcination and vacuum calcination by the combined water rate method, it was characterized by XRD, BET and SEM. The results showed that the volcanic ash activity of diatomite under vacuum conditions was higher than that of aerobic calcination, 600°C vacuum calcination 2h, the combined water rate of diatomite-Ca(OH)2-H2O system was increased from 6.24% to 71.43%, the volcanic ash activity reached the maximum value, the specific surface

Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jing Gu; Shiyong Wu; Youqing Wu

2008-11-15

In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivitymore » than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.« less

Spreading dynamic of viscous volcanic ash in stimulated jet engine conditions

NASA Astrophysics Data System (ADS)

song, wenjia; Lavallée, Yan; Hess, Kai-Uwe; Kueppers, Ulrich; Cimarelli, Corrado

2016-04-01

The ingestion of volcanic ash is widely recognised as a potentially fatal hazard for aircraft operation. The volcanic ash deposition process in a jet turbine is potentially complex. Volcanic ash in the air stream enters the inner liners of the combustors and partially or completely melts under the flames up to 2000 °C, at which point part of the ash deposits in the combustor fuel nozzle. Molten volcanic particles within high energy airflow escape the combustor to enter the turbine and impact the stationary (e.g., inlet nozzle guide vanes) and rotating airfoils (e.g., first stage high-pressure turbine blades) at high speed (up to Mach 1.25) in different directions, with the result that ash may stick, flow and remain liquid or solidify. Thus, the wetting behaviour of molten volcanic ash particle is fundamental to investigate impingement phenomena of ash droplet on the surface of real jet engine operation. The topic of wetting has received tremendous interest from both fundamental and applied points of view. However, due to the interdisciplinary gap between jet engine engineering and geology science, explicit investigation of wetting behaviour of volcanic ash at high temperature is in its infancy. We have taken a big step towards meeting this challenge. Here, we experimentally and theoretically investigate the wetting behaviour of viscous volcanic ash over a wide temperature range from 1100 to 1550 °C using an improved sessile-drop method. The results of our experiment demonstrate that temperature and viscosity play a critical role in determining the wetting possibility and governing the spreading kinetics of volcanic ash at high temperatures. Our systemic analysis of spreading of molten volcanic ash systems allows us to report on the fundamental differences between the mechanisms controlling spreading of organic liquids at room temperature and molten volcanic ash droplets.

Chemical and engineering properties of fired bricks containing 50 weight percent of class F fly ash

USGS Publications Warehouse

Chou, I.-Ming; Patel, V.; Laird, C.J.; Ho, K.K.

2001-01-01

The generation of fly ash during coal combustion represents a considerable solid waste disposal problem in the state of Illinois and nationwide. In fact, the majority of the three million tons of fly ash produced from burning Illinois bituminous coals is disposed of in landfills. The purpose of this study was to obtain a preliminary assessment of the technical feasibility of mitigating this solid waste problem by making fired bricks with the large volume of fly ash generated from burning Illinois coals. Test bricks were produced by the extrusion method with increasing amounts (20-50% by weight) of fly ash as a replacement for conventional raw materials. The chemical characteristics and engineering properties of the test bricks produced with and without 50 wt% of fly ash substitutions were analyzed and compared. The properties of the test bricks containing fly ash were at least comparable to, if not better than, those of standard test bricks made without fly ash and met the commercial specifications for fired bricks. The positive results of this study suggest that further study on test bricks with fly ash substitutions of greater than 50wt% is warranted. Successful results could have an important impact in reducing the waste disposal problem related to class F fly ash while providing the brick industry with a new low cost raw material. Copyright ?? 2001 Taylor & Francis.

An improved method for monitoring parasitism and establishment of Oobius agrili (Hymenoptera: Encyrtidae), an egg parasitoid introduced for biological control of the emerald ash borer (Coleoptera: Buprestidae) in North America

Treesearch

Jian J. Duan; Leah S. Bauer; Jason A. Hansen; Kristopher J. Abell; Roy Van Driesche

2012-01-01

Oobius agrili Zhang and Huang (Hymenoptera: Encyrtidae) is a solitary egg parasitoid that has been released in the United States since 2007 for biocontrol of the invasive emerald ash borer (EAB), Agrilus planipennis Fairmaire (Coleoptera: Buprestidae). Field and laboratory trials with ash logs infested with EAB eggs were conducted...

Proximate Composition, Amino Acid, Mineral, and Heavy Metal Content of Dried Laver

PubMed Central

Hwang, Eun-Sun; Ki, Kyung-Nam; Chung, Ha-Yull

2013-01-01

Laver, a red algae belonging to the genus Porphyra, is one of the most widely consumed edible seaweeds. The most popular commercial dried laver species, P. tenera and P. haitanensis, were collected from Korea and China, respectively, and evaluated for proximate composition, amino acids, minerals, trace heavy metals, and color. The moisture and ash contents of P. tenera and P. haitanensis ranged from 3.66~6.74% and 8.78~9.07%, respectively; crude lipid and protein contents were 1.96~2.25% and 32.16~36.88%, respectively. Dried lavers were found to be a good source of amino acids, such as asparagine, isoleucine, leucine, and taurine, and γ-aminobutyric acid. K, Ca, Mg, Na, P, I, Fe, and Se minerals were selected for analysis. A clear regional variation existed in the amino acid, mineral, and trace metal contents of lavers. Regular consumption of lavers may have heath benefits because they are relatively low in fat and high in protein, and contain functional amino acids and minerals. PMID:24471123

Proximate composition, amino Acid, mineral, and heavy metal content of dried laver.

PubMed

Hwang, Eun-Sun; Ki, Kyung-Nam; Chung, Ha-Yull

2013-06-01

Laver, a red algae belonging to the genus Porphyra, is one of the most widely consumed edible seaweeds. The most popular commercial dried laver species, P. tenera and P. haitanensis, were collected from Korea and China, respectively, and evaluated for proximate composition, amino acids, minerals, trace heavy metals, and color. The moisture and ash contents of P. tenera and P. haitanensis ranged from 3.66~6.74% and 8.78~9.07%, respectively; crude lipid and protein contents were 1.96~2.25% and 32.16~36.88%, respectively. Dried lavers were found to be a good source of amino acids, such as asparagine, isoleucine, leucine, and taurine, and γ-aminobutyric acid. K, Ca, Mg, Na, P, I, Fe, and Se minerals were selected for analysis. A clear regional variation existed in the amino acid, mineral, and trace metal contents of lavers. Regular consumption of lavers may have heath benefits because they are relatively low in fat and high in protein, and contain functional amino acids and minerals.

Nutritional and functional characterization of barley flaxseed based functional dry soup mix.

PubMed

Kaur, Sumeet; Das, Madhusweta

2015-09-01

Barley flaxseed based functional dry soup mix (BFSM) was developed from whole barely flour (46.296%), roasted flaxseed powder (23.148%) and the seasoning (30.555%) comprising several flavoring compounds and anticaking agent, using simple processing technique. Developed BFSM was nutritious. On dry matter basis it contained: protein (14.31%), carbohydrate excluding crude fiber (54.70%), fat (8.70%), ash (17.45%) and crude fiber (4.84%). It was low glycemic soup, free of antinutritional risk and had calorific value of 319.77 kcal/100 g (wet or sample basis, sb) estimated from its composition. 100 g (sb) of BFSM contained 4.36 g β-glucans and 8.08 g total lipid of which 25.6% was ω-3 fatty acids. Different extracts of BFSM revealed the presence of total phenols (0.57-1.86 mg gallic acid equivalent/g, sb) with antioxidants equivalence of DPPH (20.69-39.07%) and FRAP (120-331 μm Fe (II)/g, sb).

Adding worms during composting of organic waste with red mud and fly ash reduces CO2 emissions and increases plant available nutrient contents.

PubMed

Barthod, J; Rumpel, C; Calabi-Floody, M; Mora, M-L; Bolan, N S; Dignac, M-F

2018-09-15

Alkaline industrial wastes such as red mud and fly ash are produced in large quantities. They may be recycled as bulking agent during composting and vermicomposting, converting organic waste into soil amendments or plant growth media. The aim of this study was to assess the microbial parameters, greenhouse gas emissions and nutrient availability during composting and vermicomposting of household waste with red mud and fly ash 15% (dry weight). CO 2 , CH 4 and N 2 O emissions were monitored during 6 months in controlled laboratory conditions and microbial biomass and phospholipid acids, N and P availability were analysed in the end-products. Higher CO 2 emissions were observed during vermicomposting compared to composting. These emissions were decreased by red mud addition, while fly ash had no effect. Nitrate (NO 3 -N) content of the end-products were more affected by worms than by alkaline materials, while higher ammonium (NH 4 -N) contents were recorded for composts than vermicomposts. Red mud vermicompost showed higher soluble P proportion than red mud compost, suggesting that worm presence can counterbalance P adsorption to the inorganic matrix. Final composts produced with red mud showed no harmful heavy metal concentrations. Adding worms during composting thus improved the product nutrient availability and did not increase metal toxicity. From a practical point of view, this study suggests that for carbon stabilisation and end-product quality, the addition of red mud during composting should be accompanied by worm addition to counterbalance negative effects on nutrient availability. Copyright © 2018. Published by Elsevier Ltd.