Sample records for dry zone stream

  1. Ash Tree Leaf Litter (Fraxinus excelsior L.) Breakdown in Two Different Biotopes and Streams

    NASA Astrophysics Data System (ADS)

    Fleituch, Tadeusz; Leichtfried, Maria

    2004-11-01

    Coarse (0.5 mm) and fine (0.1 mm) mesh size bag methodology was used for comparing the breakdown of ash tree leaves (Fraxinus excelsior L.) in two biotopes (dry - terrestrial and wet - overflown stream zones) in two low order streams (the Oberer Seebach (OSB), Lower Austria and the Brzezowka stream (BRZ), Beskidy Mountains, southern Poland). In total, 96 bags were exposed in autumn 2000. Ash-free dry mass (AFDM) ranged in dry zones of both streams from 94-62% (OSB) and 85-53% (BRZ) respectively. The decomposition process was faster in wet zones: 96-33% (OSB) and 56-11% (B) during the study period. Significant differences in ash breakdown and its chemical content between studied streams were found. Total organic carbon (TOC) and total nitrogen content (TN) of AFDM of litter showed increased differences with experiment duration between zones and between two bag types for both streams. The strongest increase of TOC and TN content (100% on average initial content) for bag types, zones, and streams was observed in the first two weeks of the experiment. These results confirm the importance of chemical compounds for microbiological processes (biofilms) in different ecosystem biotopes. (

  2. Reactivation of a cryptobiotic stream ecosystem in the McMurdo Dry Valleys, Antarctica: A long-term geomorphological experiment

    USGS Publications Warehouse

    McKnight, Diane M.; Tate, C.M.; Andrews, E.D.; Niyogi, D.K.; Cozzetto, K.; Welch, K.; Lyons, W.B.; Capone, D.G.

    2007-01-01

    The McMurdo Dry Valleys of Antarctica contain many glacial meltwater streams that flow for 6 to 12??weeks during the austral summer and link the glaciers to the lakes on the valley floors. Dry valley streams gain solutes longitudinally through weathering reactions and microbial processes occurring in the hyporheic zone. Some streams have thriving cyanobacterial mats. In streams with regular summer flow, the mats are freeze-dried through the winter and begin photosynthesizing with the onset of flow. To evaluate the longer term persistence of cyanobacterial mats, we diverted flow to an abandoned channel, which had not received substantial flow for approximately two decades. Monitoring of specific conductance showed that for the first 3??years after the diversion, the solute concentrations were greater in the reactivated channel than in most other dry valley streams. We observed that cyanobacterial mats became abundant in the reactivated channel within a week, indicating that the mats had been preserved in a cryptobiotic state in the channel. Over the next several years, these mats had high rates of productivity and nitrogen fixation compared to mats from other streams. Experiments in which mats from the reactivated channel and another stream were incubated in water from both of the streams indicated that the greater solute concentrations in the reactivated channel stimulated net primary productivity of mats from both streams. These stream-scale experimental results indicate that the cryptobiotic preservation of cyanobacterial mats in abandoned channels in the dry valleys allows for rapid response of these stream ecosystems to climatic and geomorphological change, similar to other arid zone stream ecosystems. ?? 2006 Elsevier B.V. All rights reserved.

  3. Baseline Characterization of Forested Headwater Stream Hydrology and Water Chemistry in Southwest Georgia

    Treesearch

    David G. Jones; William B. Summer; Masato Miwa; C. Rhett Jackson

    2004-01-01

    Stream hydrology and water quality in headwater streams are important components of ecosystem health. The Dry Creek Long-Term Watershed Study is designed to evaluate the effects of upland forestry operations and stream management zone (SMZ) thinning on stream hydrology, water quality, benthic macroinvertebrates, and other biologicindicators. The study also tests the...

  4. Determining long time-scale hyporheic zone flow paths in Antarctic streams

    USGS Publications Warehouse

    Gooseff, M.N.; McKnight, Diane M.; Runkel, R.L.; Vaughn, B.H.

    2003-01-01

    In the McMurdo Dry Valleys of Antarctica, glaciers are the source of meltwater during the austral summer, and the streams and adjacent hyporheic zones constitute the entire physical watershed; there are no hillslope processes in these systems. Hyporheic zones can extend several metres from each side of the stream, and are up to 70 cm deep, corresponding to a lateral cross-section as large as 12 m2, and water resides in the subsurface year around. In this study, we differentiate between the near-stream hyporheic zone, which can be characterized with stream tracer experiments, and the extended hyporheic zone, which has a longer time-scale of exchange. We sampled stream water from Green Creek and from the adjacent saturated alluvium for stable isotopes of D and 18O to assess the significance and extent of stream-water exchange between the streams and extended hyporheic zones over long time-scales (days to weeks). Our results show that water residing in the extended hyporheic zone is much more isotopically enriched (up to 11??? D and 2.2??? 18O) than stream water. This result suggests a long residence time within the extended hyporheic zone, during which fractionation has occured owing to summer evaporation and winter sublimation of hyporheic water. We found less enriched water in the extended hyporheic zone later in the flow season, suggesting that stream water may be exchanged into and out of this zone, on the time-scale of weeks to months. The transient storage model OTIS was used to characterize the exchange of stream water with the extended hyporheic zone. Model results yield exchange rates (??) generally an order magnitude lower (10-5 s-1) than those determined using stream-tracer techniques on the same stream. In light of previous studies in these streams, these results suggest that the hyporheic zones in Antarctic streams have near-stream zones of rapid stream-water exchange, where 'fast' biogeochemical reactions may influence water chemistry, and extended hyporheic zones, in which slower biogeochemical reaction rates may affect stream-water chemistry at longer time-scales. Copyright ?? 2003 John Wiley & Sons, Ltd.

  5. Streamflow losses along the Balcones Fault Zone, Nueces River basin, Texas

    USGS Publications Warehouse

    Land, L.F.; Boning, C.W.; Harmsen, Lynn; Reeves, R.D.

    1983-01-01

    Statistical evaluations of historical daily flow records for the streams that have gaging stations upstream and downstream from the recharge zone provided mathematical relationships that expressed downstream flow in terms of other significant parameters. For each stream, flow entering the recharge zone is most significant in defining downstream flow; for some streams, antecedent flows at the upstream site and ground-water levels are also significantly related to downstream flow. The analyses also determined the discharges required upstream from the recharge zone to sustain flow downstream from that zone. These discharges ranged from 355 cubic feet per second for the combined Frio and Dry Frio Rivers to 33 cubic feet per second for the Nueces River. The entire flows of lesser magnitude are generally lost to recharge to the aquifer.

  6. Dry creek long-term watershed study: assessment of immediate response of aquatic macroinvertebrates to watershed level harvesting and thinning of streamside management zones

    Treesearch

    M.W. Griswold; R.T. Winn; T.L. Crisman; W.R. White

    2006-01-01

    Streamside Management Zones (SMZs) are meant to protect riparian habitat and the stream ecosystem. Benthic macroinvertebrates are recognized bioindicators of water quality in streams, typically occupying multiple trophic levels in these systems and providing food for vertebrates. Thus, it is important to understand the effects of harvest within and adjacent to the SMZ...

  7. Recent (2008-10) water quality in the Barton Springs segment of the Edwards aquifer and its contributing zone, central Texas, with emphasis on factors affecting nutrients and bacteria

    USGS Publications Warehouse

    Mahler, Barbara J.; Musgrove, MaryLynn; Sample, Thomas L.; Wong, Corinne I.

    2011-01-01

    The Barton Springs zone, which comprises the Barton Springs segment of the Edwards aquifer and the watersheds to the west that contribute to its recharge, is in south-central Texas, an area with rapid growth in population and increasing amounts of land area affected by development. During November 2008-March 2010, an investigation of factors affecting the fate and transport of nutrients and bacteria in the Barton Springs zone was conducted by the U.S. Geological Survey (USGS), in cooperation with the Texas Commission on Environmental Quality. The primary objectives of the study were to characterize occurrence of nutrients and bacteria in the Barton Springs zone under a range of flow conditions; to improve understanding of the interaction between surface-water quality and groundwater quality; and to evaluate how factors such as streamflow variability and dilution affect the fate and transport of nutrients and bacteria in the Barton Springs zone. The USGS collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge and Buda), and the main orifice of Barton Springs in Austin, Texas. During the period of the study, during which the hydrologic conditions transitioned from exceptional drought to wetter than normal, water samples were collected routinely (every 3 to 4 weeks) from the streams, wells, and spring and, in response to storms, from the streams and spring. All samples were analyzed for major ions, nutrients, the bacterium Escherichia coli, and suspended sediment. During the dry period, the geochemistry of groundwater at the two wells and at Barton Springs was dominated by flow from the aquifer matrix and was relatively similar and unchanging at the three sites. At the onset of the wet period, when the streams began to flow, the geochemistry of groundwater samples from the Marbridge well and Barton Springs changed rapidly, and concentrations of most major ions and nutrients and densities of Escherichia coli became more similar to those of samples from the streams relative to concentrations and densities during the dry period. Geochemical modeling indicated that the proportion of Barton Springs discharge composed of stream recharge increased from about 0-8 percent during the dry period to about 80 percent during the wet period. The transition from exceptional drought to wetter-than-normal conditions resulted in a number of marked changes that highlight factors affecting the fate and transport of nutrients and bacteria and the strong influence of stream recharge on water quality in the Barton Springs segment of the Edwards aquifer and had a pronounced effect on the fate of nitrogen species. Organic nitrogen loaded to and stored in soils during the dry period was nitrified to nitrate when the soils were rewetted, resulting in elevated concentrations of nitrate plus nitrite in streams as these constituents were progressively leached during continued wet weather. Estimated mean monthly loads of organic nitrogen and nitrate plus nitrite in stream recharge and Barton Springs discharge, which were relatively low and constant during the dry period, increased during the wet period. Loads of organic nitrogen, on average, were about six times greater in stream recharge than in Barton Springs discharge, indicating that organic nitrogen likely was being converted to nitrate within the aquifer. Loads of total nitrogen (organic nitrogen plus ammonia and nitrate plus nitrite) in stream recharge (162 kilograms per day) and in Barton Springs discharge (157 kilograms per day) for the period of the investigation were not significantly different. Dilution was not an important factor affecting concentrations of nitrate plus nitrite in the streams or in Barton Springs during the period of this investigation: Concentrations of nitrate plus nitrite did not decrease in streams with increasing stream discharge, and nitrate plus nitrite concentrations measured at Barton

  8. Dry creek long-term watershed study: effects of timber harvest on hydrology and sediment export in headwater streams in Southwest Georgia

    Treesearch

    W.B. Summer; C. Rhett Jackson; D. Jones; M. Miwa

    2006-01-01

    Properly established streamside management zones (SMZs) reduce potential impacts of timber harvesting on stream hydro-period and sediment fluxes. Effects of upland silvicultural practices on stream hydrology and effects of partial harvesting within SMZs on water quality are not well documented. The objectives of this study are to determine the effects of these forest...

  9. Weathering reactions and hyporheic exchange controls on stream water chemistry in a glacial meltwater stream in the McMurdo Dry Valleys

    USGS Publications Warehouse

    Gooseff, Michael N.; McKnight, Diane M.; Lyons, W. Berry; Blum, Alex E.

    2002-01-01

    In the McMurdo Dry Valleys, Antarctica, dilute glacial meltwater flows down well‐established streambeds to closed basin lakes during the austral summer. During the 6–12 week flow season, a hyporheic zone develops in the saturated sediment adjacent to the streams. Longer Dry Valley streams have higher concentrations of major ions than shorter streams. The longitudinal increases in Si and K suggest that primary weathering contributes to the downstream solute increase. The hypothesis that weathering reactions in the hyporheic zone control stream chemistry was tested by modeling the downstream increase in solute concentration in von Guerard Stream in Taylor Valley. The average rates of solute supplied from these sources over the 5.2 km length of the stream were 6.1 × 10−9 mol Si L−1 m−1 and 3.7 × 10−9 mol K L−1 m−1, yielding annual dissolved Si loads of 0.02–1.30 mol Si m−2 of watershed land surface. Silicate minerals in streambed sediment were analyzed to determine the representative surface area of minerals in the hyporheic zone subject to primary weathering. Two strategies were evaluated to compute sediment surface area normalized weathering rates. The first applies a best linear fit to synoptic data in order to calculate a constant downstream solute concentration gradient, dC/dx (constant weathering rate contribution, CRC method); the second uses a transient storage model to simulate dC/dx, representing both hyporheic exchange and chemical weathering (hydrologic exchange, HE method). Geometric surface area normalized dissolution rates of the silicate minerals in the stream ranged from 0.6 × 10−12 mol Si m−2 s−1 to 4.5 × 10−12 mol Si m−2 s−1 and 0.4 × 10−12 mol K m−2 s−1to 1.9 × 10−12 mol K m−2 s−1. These values are an order of magnitude lower than geometric surface area normalized weathering rates determined in laboratory studies and are an order of magnitude greater than geometric surface area normalized weathering rates determined in a warmer, wetter setting in temperate basins, despite the cold temperatures, lack of precipitation and lack of organic material. These results suggest that the continuous saturation and rapid flushing of the sediment due to hyporheic exchange facilitates weathering in Dry Valley streams.

  10. Impact of stream geomorphology on greenhouse gas concentration in a New York mountain stream

    Treesearch

    Philippe Vidon; Satish Serchan

    2016-01-01

    As increased greenhouse gas concentrations (GHG: N2O, CO2, CH4) in our atmosphere remain a major concern, better quantifying GHG fluxes from natural systems is essential. In this study, we investigate GHG concentrations in saturated riparian sediments (dry, wet, mucky), streambed hyporheic zone...

  11. Hydroecological Connections: Hyporheic Zone Weathering of Silicate Minerals Controls Diatom Biodiversity in Microbial Mats in Glacial Meltwater Streams of the McMurdo Dry Valleys, Antarctica

    NASA Astrophysics Data System (ADS)

    McKnight, D. M.; Dyson, I.; Esposito, R. M.; Gooseff, M. N.; Lyons, W. B.; Welch, K. A.

    2015-12-01

    The McMurdo Dry Valleys of Antarctica is comprised of alpine and terminal glaciers, large expanses of patterned ground, and ice-covered lakes in the valley floors, which are linked by glacial meltwater streams that flow during the austral summer. As part of the McMurdo Dry Valleys Long-Term Ecological research project, we have observed stream ecosystem response to a sustained 18 year cool period with low flows, which has been recently interrupted by three "flood events" during sunny, warm summers. Many of these streams contain thriving microbial mats comprised of cyanobacteria and endemic diatoms, the most diverse group of eukaryotic organisms in the valleys. Of the 45 diatom taxa, some common taxa are heavily silicified, Hantzschia amphioxys f. muelleri, while others are only lightly silicified. By comparing diatom communities in streams which flow every summer with those in streams that only flow during flood events, we found that hydrologic flow regime acts as a strong environmental filter on diatom community composition. Following the first flood event in 2001/02, mat biomass was two-fold lower due to scouring and recovered over several years, with lesser declines following the subsequent floods. In the longer streams, the diatom community composition remained stable through the flood events, whereas in two of the shorter streams, Green and Bowles Creeks, the diatom community shifted after the first flood event to a greater abundance of lightly silicified taxa. Water quality monitoring and reactive transport modeling have shown that rapid weathering of silicate minerals in the hyporheic zone accounts for the downstream increases in Si concentration which are observed in the longer streams. One mechanism driving this greater abundance of lightly silicified diatoms in shorter streams could be the greater dilution of the Si supply from hyporheic weathering in shorter streams under high flows. Given that the stream diatom community is well preserved in the 40,000-year sediment record from the receiving lake, greater understanding of hydrologic and biogeochemical controls on diatom community composition provides insight into the evolution of the lakes and geologic history of the region.

  12. Inland diatoms from the McMurdo Dry Valleys and James Ross Island, Antarctica

    USGS Publications Warehouse

    Esposito, R.M.M.; Spaulding, S.A.; McKnight, Diane M.; Van De Vijver, B.; Kopalova, K.; Lubinski, D.; Hall, B.; Whittaker, T.

    2008-01-01

    Diatom taxa present in the inland streams and lakes of the McMurdo Dry Valleys and James Ross Island, Antarctica, are presented in this paper. A total of nine taxa are illustrated, with descriptions of four new species (Luticola austroatlantica sp. nov., Luticola dolia sp. nov., Luticola laeta sp. nov., Muelleria supra sp. nov.). In the perennially ice-covered lakes of the McMurdo Dry Valleys, diatoms are confined to benthic mats within the photic zone. In streams, diatoms are attached to benthic surfaces and within the microbial mat matrix. One species, L. austroatlantica, is found on James Ross Island, of the southern Atlantic archipelago, and the McMurdo Dry Valleys. The McMurdo Dry Valley populations are at the lower range of the size spectrum for the species. Streams flow for 6-10 weeks during the austral summer, when temperatures and solar radiation allow glacial ice to melt. The diatom flora of the region is characterized by species assemblages favored under harsh conditions, with naviculoid taxa as the dominant group and several major diatom groups conspicuously absent. ?? 2008 NRC.

  13. Denitrification in Agriculturally Impacted Streams: Seasonal Changes in Structure and Function of the Bacterial Community

    PubMed Central

    Manis, Erin; Royer, Todd V.; Johnson, Laura T.; Leff, Laura G.

    2014-01-01

    Denitrifiers remove fixed nitrogen from aquatic environments and hydrologic conditions are one potential driver of denitrification rate and denitrifier community composition. In this study, two agriculturally impacted streams in the Sugar Creek watershed in Indiana, USA with different hydrologic regimes were examined; one stream is seasonally ephemeral because of its source (tile drainage), whereas the other stream has permanent flow. Additionally, a simulated flooding experiment was performed on the riparian benches of the ephemeral stream during a dry period. Denitrification activity was assayed using the chloramphenicol amended acetylene block method and bacterial communities were examined based on quantitative PCR and terminal restriction length polymorphisms of the nitrous oxide reductase (nosZ) and 16S rRNA genes. In the stream channel, hydrology had a substantial impact on denitrification rates, likely by significantly lowering water potential in sediments. Clear patterns in denitrification rates were observed among pre-drying, dry, and post-drying dates; however, a less clear scenario was apparent when analyzing bacterial community structure suggesting that denitrifier community structure and denitrification rate were not strongly coupled. This implies that the nature of the response to short-term hydrologic changes was physiological rather than increases in abundance of denitrifiers or changes in composition of the denitrifier community. Flooding of riparian bench soils had a short-term, transient effect on denitrification rate. Our results imply that brief flooding of riparian zones is unlikely to contribute substantially to removal of nitrate (NO3 -) and that seasonal drying of stream channels has a negative impact on NO3 - removal, particularly because of the time lag required for denitrification to rebound. This time lag is presumably attributable to the time required for the denitrifiers to respond physiologically rather than a change in abundance or community composition. PMID:25171209

  14. Ecohydrological and subsurface controls on drought-induced contraction and disconnection of stream networks

    NASA Astrophysics Data System (ADS)

    Godsey, S.; Kirchner, J. W.; Whiting, J. A.

    2016-12-01

    Temporary headwater streams - both intermittent and ephemeral waterways - supply water to approximately 1/3 of the US population, and 60% of streams used for drinking water are temporary. Stream ecologists increasingly recognize that a gradient of processes across the drying continuum affect ecosystems at dynamic terrestrial-aquatic interfaces. Understanding the hydrological controls across that gradient of drying may improve management of these sensitive systems. One possible control on surface flows includes transpiration losses from either the riparian zone or the entire watershed. We mapped several stream networks under extreme low flow conditions brought on by severe drought in central Idaho and California in 2015. Compared to previous low-flow stream length estimates, the active drainage network had generally decreased by a very small amount across these sites, perhaps because stored water buffered the precipitation decrease, or because flowing channel heads are fixed by focused groundwater flow emerging at springs. We also examined the apparent sources of water for both riparian and hillslope trees using isotopic techniques. During drought conditions, we hypothesized that riparian trees - but not those far from flowing streams - would be sustained by streamflow recharging riparian aquifers, and thus would transpire water that was isotopically similar to streamflow because little soil water would remain available below the wilting point and stream water would be sustain those trees. We found a more complex pattern, but in most places stream water and water transpired by trees were isotopically distinct regardless of flow intermittency or tree location. We also found that hillslope trees outside of the riparian zone appeared to be using different waters from those used by riparian trees. Finally, we explore subsurface controls on network extent, showing that bedrock characteristics can influence network stability and contraction patterns.

  15. Ca isotopic geochemistry of an Antarctic aquatic system

    USGS Publications Warehouse

    Lyons, W. Berry; Bullen, Thomas D.; Welch, Kathleen A.

    2017-01-01

    The McMurdo Dry Valleys, Antarctica, are a polar desert ecosystem. The hydrologic system of the dry valleys is linked to climate with ephemeral streams that flow from glacial melt during the austral summer. Past climate variations have strongly influenced the closed-basin, chemically stratified lakes on the valley floor. Results of previous work point to important roles for both in-stream processes (e.g., mineral weathering, precipitation and dissolution of salts) and in-lake processes (e.g., mixing with paleo-seawater and calcite precipitation) in determining the geochemistry of these lakes. These processes have a significant influence on calcium (Ca) biogeochemistry in this aquatic ecosystem, and thus variations in Ca stable isotope compositions of the waters can aid in validating the importance of these processes. We have analyzed the Ca stable isotope compositions of streams and lakes in the McMurdo Dry Valleys. The results validate the important roles of weathering of aluminosilicate minerals and/or CaCO3 in the hyporheic zone of the streams, and mixing of lake surface water with paleo-seawater and precipitation of Ca-salts during cryo-concentration events to form the deep lake waters. The lakes in the McMurdo Dry Valleys evolved following different geochemical pathways, evidenced by their unique, nonsystematic Ca isotope signatures.

  16. Inorganic N and P dynamics of Antarctic glacial meltwater streams as controlled by hyporheic exchange and benthic autotrophic communities

    USGS Publications Warehouse

    McKnight, Diane M.; Runkel, R.L.; Tate, C.M.; Duff, J.H.; Moorhead, D.L.

    2004-01-01

    The McMurdo Dry Valleys of South Victoria Land, Antarctica, contain numerous glacial meltwater streams that drain into lakes on the valley floors. Many of the streams have abundant perennial mats of filamentous cyanobacteria. The algal mats grow during streamflow in the austral summer and are in a dormant freeze-dried state during the rest of the year. NO3 and soluble reactive P (SRP) concentrations were lower in streams with abundant algal mats than in streams with sparse algal mats. NO3 and SRP concentrations were higher in the hyporheic zone of a stream with abundant algal mats than in the stream itself. An experimental injection of LiCl, NaNO3, and K3PO4 was conducted in Green Creek, which has abundant algal mats. Substantial hyporheic exchange occurred. The NO3 and PO4 concentrations at 50 m below the injection were 55 ??M and 18 ??M, respectively, during the experiment. NO3 and PO4 concentrations were below the detection limit of 1 to 2 ??M at a site 497 m below the injection during the Cl tracer arrival, indicating a high capacity for nutrient uptake by algal communities. NO2 and NH4 were present at sites 226 and 327 m below the injection, indicating that, in addition to denitrification and algal uptake, dissimilatory NO3 reduction to NO2 and NH4 may be a NO3 sink during transport. Transport modelling with nutrient uptake represented as a 1st-order process yielded reach-scale parameters of 4.3 ?? 10-5 to 3.9 ?? 10-4/s and 1.4 ?? 10-4 to 3.8 ?? 10 -4/s for uptake of NO3 and PO4, respectively. The best match with the observed data was a model in which PO4 uptake occurred only in the main channel and NO3 uptake occurred in the main channel and in the hyporheic zone. Hyporheic NO3 uptake was 7 to 16% of the total uptake for the different stream reaches. These results demonstrate that nutrient flux to the lakes is controlled by hyporheic exchange and nutrient uptake by algal mats in dry valley streams. Streams without algal mats contribute more nutrients to the lakes than streams with algal mats.

  17. Spatial occupancy patterns and activity of arid rangeland cattle grazing small riparian pastures.

    PubMed

    Larson, Larry; Johnson, Douglas E; Wilson, Marie; Wilson, Kerry; Louhaichi, Mounir; Williams, John

    2017-03-01

    The spatial occupancy patterns and activity of cattle grazing three riparian pastures was investigated in northeastern Oregon using Global Positioning System (GPS) collars logging at 1-sec intervals. Cattle consistently selected plant communities as grazing areas that had forage in sufficient volume to meet their requirements and favored communities as resting areas that were dry and open. Cattle were stationary for more than 50% of the time in each pasture and consistently rested between dark and 04:00 hours. Interaction with stream channels was found to be 1-2% of total occupancy time and occurred on less than 10% of channel length. Cattle were indifferent or avoided channel areas relative to their area and, when in this zone, they spent most of their time moving not resting. Cattle did not prefer the stream bank zone and spent only 2% of their time in that zone. When occupied, the stream bank zone was used as a travel corridor to gain access to water or cross the channel to access other pasture areas. These results are in contrast with the general belief that cattle are a primary occupant of the stream bank/channel area; additional research is needed to define factors influencing cattle occupancy. © 2016 Japanese Society of Animal Science.

  18. Dry creek long-term watershed study: the effects of harvesting in streamside management zones and adjacent uplands of riparian corridors on avian communities in the Coastal Plain of Georgia

    Treesearch

    Merideth P. Grooms; J. Drew Lanham; T. Bently Wigley

    2006-01-01

    We evaluated the effects of Best Management Practices (BMPs) harvesting on avian communities associated with headwater streams in the Georgia Coastal Plain. Two watersheds served as references, with no timber harvesting, and two treatment watersheds were clearcut with retention of Streamside Management Zones (SMZs) according to Georgia BMPs for forestry. Bird...

  19. Using monitoring, LiDAR and MODFLOW to Estimate Hyporheic Fluxes for a Dynamic Large River Riparian Area

    EPA Science Inventory

    In unrevetted reaches, the Willamette River in northwest Oregon is a dynamic anastomosing system. Riparian zones are frequently divided into multiple islands during most of the wet winter season. The dividing stream channels are mostly absent during the dry summer season. This po...

  20. Capturing Hot Moments of Carbon Cycling in the Hyporheic Zone of an Intermittent Stream

    NASA Astrophysics Data System (ADS)

    Brandt, T.; Harjung, A.; Vieweg, M.; Butturini, A.; Schmidt, C.; Fleckenstein, J. H.; Sabater, F.

    2016-12-01

    Intermittent streams are increasingly recognized as a factor for underestimating potential CO2 emissions of aquatic ecosystems, because they are neglected during their dry phase. This can be partly attributed to poor understanding of dissolved organic matter (DOM) processing at highly reactive interfaces such as the hyporheic zone (HZ). Here, hydrological transitions drive rapid changes in the spatiotemporal distribution of dissolved oxygen (DO), thus creating hot moments of increased biogeochemical cycling. However, capturing these process-dynamics requires a continuous monitoring of hyporheic pore water at a sufficient temporal and spatial resolution. In order to investigate the transitions between the wet and dry phase, we used a combination of automated pore water sampling and in situ measurements. By combining conventional pumping approaches with recently developed technology we achieved a high resolution multi-scale, quasi continuous monitoring of relevant parameters of the carbon cycle. Our novel approach coupled continuous fluorescence DOM and infrared CO2 sensor measurements with spatially continuous vertical oxygen profiling in situ. A proof-of-concept application was established in a semi-pristine Mediterranean stream during the drying period in summer 2015. Previous sampling campaigns already identified the water level as a driver of DOM composition in the HZ. Once the surface flow switches to subsurface flow, the HZ becomes a sink for aromatic, high molecular weight compounds, while protein-like, autochthonous DOM gets released. Generally, we observed exponential increases in hyporheic CO2 from this point on, co-occurring with a sharp vertical DO gradient as a function of changing hydrological conditions.

  1. Hydrologic connectivity in the McMurdo Dry Valleys of Antarctica: System function and changes over two decades

    NASA Astrophysics Data System (ADS)

    Wlostowski, A. N.; Gooseff, M. N.; Bernzott, E. D.; McKnight, D. M.; Jaros, C.; Lyons, W.

    2013-12-01

    The McMurdo Dry Valleys of Antarctica is one of the coldest (average annual air temperature of -18°C) and driest (<10cm water equivalent of precip per year) places on earth. Despite the harsh climatic conditions of this landscape, a thriving microbial and invertebrate ecosystem exists, but is limited by the availability of liquid water. So, it is important to quantify temporal and spatial dynamics of hydrologic and ecological connections in the McMurdo Dry Valleys. Intermittent glacial meltwater streams connect glaciers to closed basin lakes and compose the most prominent hydrologic nexus in the valleys. This study uses of 20+ years of stream temperature, electrical conductivity (EC), and discharge data to enhance our quantitative understanding of the temporal dynamics of hydrologic connections along the glacier-stream-lake continuum. Annually, streamflow occurs for a relatively brief 10-12 week period of the austral summer. Longer streams are more prone to intermittent dry periods during the flow season, making for a harsher ecological environment than shorter streams. Diurnal streamflow variation occurs primarily as a result of changing solar postion relative to the source-glacier surfaces. Therfore, different streams predictably experience high flows and low flows at different times of the day. Electrical conductivity also exhibits diel variations, but the nature of EC-discharge relationships differs among streams throughout the valley. Longer streams have higher EC values and lower discharges than shorter streams, suggesting that hyporheic zones act as a significant solute source and hydrologic reservoir along longer streams. Water temperatures are consistently warmer in longer streams, relative to shorter streams, likely due to prolonged exposure to incident radiation with longer surface water residence times. Inter-annually, several shorter streams in the region show significant increases in Q10, Q30, Q50, Q70, Q90, and/or Q100 flows across the 20+ year record, indicating a long-term non-stationarity in hydrologic system dynamics. The tight coupling between surface waters and the glacier surface energy balance bring forth remarkably consistent hydrologic patterns on the daily and annual timescales, providing a model system for understanding fundamental hydro-ecological connectivity. We are beginning to understand long-term inter-annual changes in hydrologic connections in this thermodynamically sensitive landscape, with the aid of well-maintained long-term data sets.

  2. Reach-scale cation exchange controls on major ion chemistry of an Antarctic glacial meltwater stream

    USGS Publications Warehouse

    Gooseff, Michael N.; McKnight, Diane M.; Runkel, Robert L.

    2004-01-01

    McMurdo dry valleys of Antarctica represent the largest of the ice-free areas on the Antarctic continent, containing glaciers, meltwater streams, and closed basin lakes. Previous geochemical studies of dry valley streams and lakes have addressed chemical weathering reactions of hyporheic substrate and geochemical evolution of dry valley surface waters. We examine cation transport and exchange reactions during a stream tracer experiment in a dry valley glacial meltwater stream. The injection solution was composed of dissolved Li+, Na+, K+, and Cl-. Chloride behaved conservatively in this stream, but Li+, Na+, and K+ were reactive to varying degrees. Mass balance analysis indicates that relative to Cl-, Li+ and K+ were taken up in downstream transport and Na+ was released. Simulations of conservative and reactive (first-order uptake or generation) solute transport were made with the OTIS (one-dimensional solute transport with inflow and storage) model. Among the four experimental reaches of Green Creek, solute transport simulations reveal that Li+ was removed from stream water in all four reaches, K+ was released in two reaches, taken up in one reach, and Na+ was released in all four reaches. Hyporheic sediments appear to be variable with uptake of Li+ in two reaches, uptake of K+ in one reach, release of K+ in two reaches, and uptake of Na+ in one reach. Mass balances of the conservative and reactive simulations show that from 1.05 to 2.19 moles of Li+ was adsorbed per reach, but less than 0.3 moles of K+ and less than 0.9 moles of Na+ were released per reach. This suggests that either (1) exchange of another ion which was not analyzed in this experiment or (2) that both ion exchange and sorption control inorganic solute transport. The elevated cation concentrations introduced during the experiment are typical of initial flows in each flow season, which flush accumulated dry salts from the streambed. We propose that the bed sediments (which compose the hyporheic zone) modulate the flushing of these salts during initial flows each season, due to ion exchange and sorption reactions.

  3. Vegetation associations

    Treesearch

    W. F. Mueggler

    1985-01-01

    Aspen trees grow along moist stream bottoms as well as on dry ridges and southerly exposures, on talus slopes, and on shallow to deep soils of varied origins. Quaking aspen is one of the few plant species that can grow in all mountain vegetational zones from the alpine to the basal plain (Daubenmire 1943). As a consequence, aspen dominated communities are found...

  4. Recent (2008-10) concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone, south-central Texas, and their potential relation to urban development in the contributing zone

    USGS Publications Warehouse

    Mahler, Barbara J.; Musgrove, MaryLynn; Herrington, Chris; Sample, Thomas L.

    2011-01-01

    During 2008–10, the U.S. Geological Survey, in cooperation with the City of Austin, the City of Dripping Springs, the Barton Springs/Edwards Aquifer Conservation District, the Lower Colorado River Authority, Hays County, and Travis County, collected and analyzed water samples from five streams (Barton, Williamson, Slaughter, Bear, and Onion Creeks), two groundwater wells (Marbridge well [YD–58–50–704] and Buda well [LR–58–58–403]), and the main orifice of Barton Springs in Austin, Texas, with the objective of characterizing concentrations and isotopic compositions of nitrate and concentrations of wastewater compounds in the Barton Springs zone. The Barton Springs zone is in south-central Texas, an area undergoing rapid growth in population and in land area affected by development, with associated increases in wastewater generation. Over a period of 17 months, during which the hydrologic conditions transitioned from dry to wet, samples were collected routinely from the streams, wells, and spring and, in response to storms, from the streams and spring; some or all samples were analyzed for nitrate, nitrogen and oxygen isotopes of nitrate, and waste­water compounds. The median nitrate concentrations in routine samples from all sites were higher in samples collected during the wet period than in samples collected during the dry period, with the greatest difference for stream samples (0.05 milligram per liter during the dry period to 0.96 milligram per liter for the wet period). Nitrate concentrations in recent (2008–10) samples were elevated relative to concentrations in historical (1990–2008) samples from streams and from Barton Springs under medium- and high-flow conditions. Recent nitrate concentrations were higher than historical concentrations at the Marbridge well but the reverse was true at the Buda well. The elevated concentrations likely are related to the cessation of dry conditions coupled with increased nitrogen loading in the contributing watersheds. An isotopic composition of nitrate (delta nitrogen–15) greater than 8 per mil in many of the samples indicated there was a contribution of nitrate with a biogenic (human and or animal waste, or both) origin. Wastewater compounds measured in routine samples were detected infrequently (3 percent of cases), and concentrations were very low (less than the method reporting level in most cases). There was no correlation between nitrate concentrations and the frequency of detection of wastewater compounds, indicating that wastewater compounds might be undergoing removal during such processes as infiltration through soil. Three potential sources of biogenic nitrate to the contributing zone were considered: septic systems, land application of treated wastewater, and domesticated dogs and cats. During 2001–10, the estimated densities of septic systems and domesticated dogs and cats (number per acre) increased in the watersheds of all five creeks, and the rate of land application of treated wastewater (gallons per day per acre) increased in the watersheds of Barton, Bear, and Onion Creeks. Considering the timing and location of the increases in the three sources, septic systems were considered a likely source of increased nitrate to Bear Creek; land application of treated wastewater a likely source to Barton, Bear, and Onion Creeks; and domestic dogs and cats a potential source principally to Williamson Creek. The results of this investigation indicate that baseline water quality, in terms of nitrate, has shifted upward between 2001 and 2010, even without any direct discharges of treated wastewater to the creeks.

  5. Subsurface Controls on Stream Intermittency in a Semi-Arid Landscape

    NASA Astrophysics Data System (ADS)

    Dohman, J.; Godsey, S.; Thackray, G. D.; Hale, R. L.; Wright, K.; Martinez, D.

    2017-12-01

    Intermittent streams currently constitute 30% to greater than 50% of the global river network. In addition, the number of intermittent streams is expected to increase due to changes in land use and climate. These streams provide important ecosystem services, such as water for irrigation, increased biodiversity, and high rates of nutrient cycling. Many hydrological studies have focused on mapping current intermittent flow regimes or evaluating long-term flow records, but very few have investigated the underlying causes of stream intermittency. The disconnection and reconnection of surface flow reflects the capacity of the subsurface to accommodate flow, so characterizing subsurface flow is key to understanding stream drying. We assess how subsurface flow paths control local surface flows during low-flow periods, including intermittency. Water table dynamics were monitored in an intermittent reach of Gibson Jack Creek in southeastern Idaho. Four transects were delineated with a groundwater well located in the hillslope, riparian zone, and in the stream, for a total of 12 groundwater wells. The presence or absence of surface flow was determined by frequent visual observations as well as in situ loggers every 30m along the 200m study reach. The rate of surface water drying was measured in conjunction with temperature, precipitation, subsurface hydraulic conductivity, hillslope-riparian-stream connectivity and subsurface travel time. Initial results during an unusually wet year suggest different responses in reaches that were previously observed to occasionally cease flowing. Flows in the intermittent reaches had less coherent and lower amplitude diel variations during base flow periods than reaches that had never been observed to dry out. Our findings will help contribute to our understanding of mechanisms driving expansion and contraction cycles in intermittent streams, increase our ability to predict how land use and climate change will affect flow regimes, and improve management of our critical water resources.

  6. Spatial and Temporal Dynamics of Carbon Fluxes in Glacial Meltwater Streams, Antarctica

    NASA Astrophysics Data System (ADS)

    Torrens, C.; Lyons, W. B.; McKnight, D. M.; Welch, K. A.; Gooseff, M. N.

    2017-12-01

    In the McMurdo Dry Valleys [MDV], Antarctica, glacial meltwater streams are the primary biogeochemical connectors linking glaciers, soils and lakes. These streams control the supply of nutrients and carbon to their terminal lakes, yet little is known about the magnitude, timing or distribution of these fluxes. The McMurdo Long Term Ecological Research project [MCM LTER] has collected over 20 years of sample data on dissolved organic and inorganic carbon in Taylor Valley streamwater; this is the first spatial and temporal analysis of this data. MDV streams are characterized by strong diel pulses in streamflow, specific electrical conductance, and temperature. Unlike temperate stream systems, there is no terrestrial vegetation, lateral overland flow or deep groundwater connection in MDV streams. As a result, the organic carbon is autochthonous, originating from stream microbial mats. Inorganic carbon is primarily bicarbonate; its source is hyporheic zone weathering. The carbonate system is in atmospheric equilibrium, reflecting the wide and shallow stream channels. Preliminary data show that the DOC flux varies with streamflow and is greater on the rising limb of the diel flow pulse. This pattern is more distinct in longer streams. DIC data does not show the same pattern, although the response may be blurred by a lag in hyporheic response to flood pulses and the lack of time-series data for alkalinity. Stream flood pulse dynamics control carbon loading to MDV lakes. As the climate changes, so will the timing and magnitude of diel flood pulses. This is likely to increase carbon loading to the Dry Valley lakes, altering the ecosystem carbon balance. This study increases our understanding of past and current patterns of carbon fluxes from streams to lakes; understanding past patterns will improve predictions of future changes.

  7. Viscosity changes of riparian water controls diurnal fluctuations of stream-flow and DOC concentration

    NASA Astrophysics Data System (ADS)

    Schwab, Michael; Klaus, Julian; Pfister, Laurent; Weiler, Markus

    2015-04-01

    Diurnal fluctuations in stream-flow are commonly explained as being triggered by the daily evapotranspiration cycle in the riparian zone, leading to stream flow minima in the afternoon. While this trigger effect must necessarily be constrained by the extent of the growing season of vegetation, we here show evidence of daily stream flow maxima in the afternoon in a small headwater stream during the dormant season. We hypothesize that the afternoon maxima in stream flow are induced by viscosity changes of riparian water that is caused by diurnal temperature variations of the near surface groundwater in the riparian zone. The patterns were observed in the Weierbach headwater catchment in Luxembourg. The catchment is covering an area of 0.45 km2, is entirely covered by forest and is dominated by a schistous substratum. DOC concentration at the outlet of the catchment was measured with the field deployable UV-Vis spectrometer spectro::lyser (scan Messtechnik GmbH) with a high frequency of 15 minutes over several months. Discharge was measured with an ISCO 4120 Flow Logger. During the growing season, stream flow shows a frequently observed diurnal pattern with discharge minima in the afternoon. During the dormant season, a long dry period with daily air temperature amplitudes of around 10 ° C occurred in March and April 2014, with discharge maxima in the afternoon. The daily air temperature amplitude led to diurnal variations in the water temperature of the upper 10 cm of the riparian zone. Higher riparian water temperatures cause a decrease in water viscosity and according to the Hagen-Poiseuille equation, the volumetric flow rate is inversely proportional to viscosity. Based on the Hagen-Poiseuille equation and the viscosity changes of water, we calculated higher flow rates of near surface groundwater through the riparian zone into the stream in the afternoon which explains the stream flow maxima in the afternoon. With the start of the growing season, the viscosity induced diurnal effect is overlain by the stronger influence of evapotranspiration. Diurnal DOC fluctuations show daily maxima in the afternoon. While daily variations in DOC concentrations are often explained by faster in-stream biogeochemical processes during daylight, we here propose that the viscosity effect in the riparian zone could explain the afternoon peaks in DOC concentrations. Our records show that daily water temperature variations and therefore viscosity changes only occur in the near surface parts of the riparian zone, where the DOC concentrations are higher than in deeper parts of the riparian zone. We calculated, that the viscosity induced higher flow rates from the near surface parts of the riparian zone can explain the DOC concentration maxima in the afternoon. As the viscosity effect does not disappear during the growing season but is just smaller than the evapotranspiration effect, the DOC concentration pattern is not changing between the dormant and growing seasons. The different controls of diurnal fluctuations of stream-flow and water quality concentrations need to be carefully considered in order to better understand the different patterns in catchment hydrology.

  8. Ecotoxicology for risk assessment in arid zones: some key issues.

    PubMed

    Everts, J W

    1997-01-01

    In the hot arid zones of the world, ecotoxicological research is in statu nascendi. In these zones, the major sources of contamination by toxicants are: (1) plant protection and vector control in wet zones; (2) large-scale crop protection campaigns in dry and ephemeral wet zones; (3) refuse and obsolete pesticides in dry zones; and (4) mining. Economic development in many of these zones requires an adequate knowledge of certain basic principles, i.e., where extrapolating existing knowledge does not apply. The vulnerability of ecosystems to contaminants is closely related to water flow. In dry areas, species are susceptible to factors that interfere with the ecophysiological properties regulating water loss. Most hot arid areas are found at low latitudes where temperatures show striking extremes both in time and space. Living organisms are physiologically resistant and/or show adaptive behavior to these temperature extremes. Very little is known about the effects of toxicants on these key resistant and adaptive functions, although by extrapolation a few assumptions can be made. The effects of hyperthermia, for instance, can be aggravated by GSH depleting substances, and the temporary disabling effects characteristic of many pesticides may prove fatal under these circumstances. Most wet areas show a spatial concentration of both human activity and wildlife. In mesic zones, the contamination of water represents a health risk to both humans and other living organisms. The vast majority of aquatic communities are those inhabiting temporary pools and streams. Their populations are characterized by short reproductive cycles and/or long dormant stages. Toxicants affecting growth in these areas have been shown to have a deleterious effect. In a synthesis of existing knowledge the most prominent gaps are identified and priorities for further research are made.

  9. Constraints upon the Response of Fish and Crayfish to Environmental Flow Releases in a Regulated Headwater Stream Network

    PubMed Central

    Chester, Edwin T.; Matthews, Ty G.; Howson, Travis J.; Johnston, Kerrylyn; Mackie, Jonathon K.; Strachan, Scott R.; Robson, Belinda J.

    2014-01-01

    In dry climate zones, headwater streams are often regulated for water extraction causing intermittency in perennial streams and prolonged drying in intermittent streams. Regulation thereby reduces aquatic habitat downstream of weirs that also form barriers to migration by stream fauna. Environmental flow releases may restore streamflow in rivers, but are rarely applied to headwaters. We sampled fish and crayfish in four regulated headwater streams before and after the release of summer-autumn environmental flows, and in four nearby unregulated streams, to determine whether their abundances increased in response to flow releases. Historical data of fish and crayfish occurrence spanning a 30 year period was compared with contemporary data (electrofishing surveys, Victoria Range, Australia; summer 2008 to summer 2010) to assess the longer–term effects of regulation and drought. Although fish were recorded in regulated streams before 1996, they were not recorded in the present study upstream or downstream of weirs despite recent flow releases. Crayfish (Geocharax sp. nov. 1) remained in the regulated streams throughout the study, but did not become more abundant in response to flow releases. In contrast, native fish (Gadopsis marmoratus, Galaxias oliros, Galaxias maculatus) and crayfish remained present in unregulated streams, despite prolonged drought conditions during 2006–2010, and the assemblages of each of these streams remained essentially unchanged over the 30 year period. Flow release volumes may have been too small or have operated for an insufficient time to allow fish to recolonise regulated streams. Barriers to dispersal may also be preventing recolonisation. Indefinite continuation of annual flow releases, that prevent the unnatural cessation of flow caused by weirs, may eventually facilitate upstream movement of fish and crayfish in regulated channels; but other human–made dispersal barriers downstream need to be identified and ameliorated, to allow native fish to fulfil their life cycles in these headwater streams. PMID:24647407

  10. Stream Channel Stability.

    DTIC Science & Technology

    1981-04-01

    Cycles of wetting and drying are also t ,v itiue swelling and shrinkage of the soil. S 11ied blocks or peds of soil fabric ,,ks. id downslope soil creep ...hydrographs of water and sediment at the point in question. By feeding the output from the hydrology-transport model into the finite element model...the banks as undercut banks fail. Channel irregularities such as seepage zones, cattle crossings, overbank drainage, buried channels, organic deposits

  11. End of the trend: Cold desert ecosystem responses to climate variability

    NASA Astrophysics Data System (ADS)

    Gooseff, M. N.; Barrett, J. E.; Truhlar, A.; Adams, B.; Doran, P. T.; Fountain, A. G.; Lyons, W. B.; McKnight, D. M.; Priscu, J. C.; Takacs-Vesbach, C. D.; Virginia, R. A.; Wall, D. H.

    2013-12-01

    The McMurdo Dry Valleys (MDVs) of Antarctica represent a cold desert ecosystem defined by extensive soils (i.e., not ice-covered), glacier meltwater streams, and closed-basin, ice-covered lakes. Despite cold temperatures and very little precipitation, a vibrant ecosystem exists across these landscape units. Previous work in the MDVs documented significant responses of local aquatic and terrestrial ecosystems to a decadal cooling trend prior to 2000. However, an exceptionally high melt year occurred in 2002, influencing stream flow, lake dynamics and terrestrial ecosystems. Here we describe interannual variation in Dry Valley ecosystems, focusing on the contrasts in drivers of ecological responses pre- and post 2002, i.e., the flood year. In streams, ash-free dry mass (AFDM) and chlorophyll-a concentration in black Nostoc-dominated microbial mats were observed to decrease prior to 2002, and AFDM has been increasing since. Three MDV lakes were decreasing in volume and increasing in total chlorophyll-a mass in the photic zones prior to 2002 and have been increasing volume and decreasing total chlorophyll-a mass since. Soil nematode communities were decreasing in abundance prior to 2002, and show no significant trend since, but increased variability. Since 2002, the MDV ecosystem has ceased responding to only a decadal cooling trend and is responding to several high-flow years with new trajectories in some cases and changed interannual variability in others.

  12. AUTOMATIC RECORDING OF THE RADIOACTIVITY OF ZONES ELUTED FROM THE GAS- LIQUID CHROMATOGRAM

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    James, A.T.; Piper, E.A.

    1961-03-01

    A simple proportional flow counter for use with the gas chromatogram is described. which is operated at room temperature by burning all eluted material to CO/sub 2/ over heated copper oxide. The gas stream is dried. 5% CO/sub 2/ is injected and the mixture passed into the counter. Details are given of the necessary circuitry. Examples are provided of its use with long chain fatty acids. (auth)

  13. Shallow groundwater systems in a polar desert, McMurdo Dry Valleys, Antarctica

    NASA Astrophysics Data System (ADS)

    Gooseff, Michael N.; Barrett, John E.; Levy, Joseph S.

    2013-02-01

    The McMurdo Dry Valleys (MDVs), Antarctica, exist in a hyperarid polar desert, underlain by deep permafrost. With an annual mean air temperature of -18 °C, the MDVs receive <10 cm snow-water equivalent each year, collecting in leeward patches across the landscape. The landscape is dominated by expansive ice-free areas of exposed soils, mountain glaciers, permanently ice-covered lakes, and stream channels. An active layer of seasonally thawed soil and sediment extends to less than 1 m from the surface. Despite the cold and low precipitation, liquid water is generated on glaciers and in snow patches during the austral summer, infiltrating the active layer. Across the MDVs, groundwater is generally confined to shallow depths and often in unsaturated conditions. The current understanding and the biogeochemical/ecological significance of four types of shallow groundwater features in the MDVs are reviewed: local soil-moisture patches that result from snow-patch melt, water tracks, wetted margins of streams and lakes, and hyporheic zones of streams. In general, each of these features enhances the movement of solutes across the landscape and generates soil conditions suitable for microbial and invertebrate communities.

  14. Ecohydrological Consequences of Critical Zone Structure in the Franciscan Formation, Northern California Coast Ranges

    NASA Astrophysics Data System (ADS)

    Hahm, W. J.; Dietrich, W. E.; Dawson, T. E.; Lovill, S.; Rempe, D.

    2016-12-01

    Water availability regulates ecosystem function, particularly in seasonally dry climates where lack of moisture in the growing season acts as an ecological bottleneck. Water within hillslopes is extracted by plants during transpiration and also delivered to streams to support baseflow for riparian ecosystems and human use. How water is stored and then released from hillslopes is strongly influenced by the structure of the critical zone (CZ) that emerges from the complex interaction of lithology, climate, and tectonics. Here we show how contrasting CZ development has extreme ecohydrological consequences in the seasonally dry climate of the Northern California Coast Ranges. To explore how the CZ transmits and stores water, we studied hydrologic dynamics at two sites with similar climate across belts of the Franciscan Formation in the Eel River CZO. We monitored plant water use, precipitation inputs and stream runoff, groundwater and vadose zone moisture dynamics and documented near-surface hydraulic conductivity and runoff-generation processes. We investigated CZ structure via boreholes and geophysical methods. We find that CZ thickness determines the extent to which hillslopes `shed' or `store' wet season precipitation, and fundamentally controls the structure of plant communities and summer low-flows. In a climate where winter precipitation regularly exceeds 2000 mm, the thin CZ of the sheared argillite matrix Central belt rapidly fills, resulting in wet-season saturation overland flow that drives flashy winter runoff in channels that then quickly run dry in the early summer. The maximum unsaturated moisture storage of approximately 200 mm is sufficient to host an ecologically diverse yet sparsely forested oak savanna. In contrast, the thick CZ of the interbedded argillite and greywacke Coastal belt stores up to 600 mm of winter precipitation in the unsaturated zone and a seasonal groundwater system within fractured bedrock provides year-round flow to channels, supporting dense mixed coniferous-broadleaf evergreen forest and native resident salmonids. These findings underscore the importance of understanding how the structure of the CZ develops by directly pairing hillslope moisture storage and release to the composition and resilience of terrestrial and aquatic ecosystems.

  15. Effects of pulse and press drying disturbance on benthic stream communities

    USGS Publications Warehouse

    Lynch, Dustin T.; Magoulick, Daniel D.

    2016-01-01

    Natural disturbance is an integral component of most ecosystems and occurs in 3 different forms: pulse, press, and ramp. In lotic ecosystems, seasonal drought is a major form of disturbance, particularly in intermittent headwater streams, which often are reduced to pools that serve as refuges for biota. We used simulated intermittent stream pools to compare the effects of control, pulse, and press drying on growth and survival in 3 fish species (Lepomis megalotis, Campostoma anomalum, and Etheostoma spectabile) commonly found together in drought-prone streams in the Ozark Highlands, USA. We also compared effects on benthic community structure, including periphyton and chironomid density and sediment in deep (permanently watered) and shallow (intermittently dewatered) habitat. Only one species, L. megalotis, showed a significant reduction in length and mass growth in press drying compared with control treatments. Drying and type of drying had no effect on survival of any fish species. Drying and type of drying had strong overall effects on periphyton growth in shallow habitats, where ash-free dry mass decreased and the autotrophic index (the ratio of chlorophyll a to total biomass) increased significantly in drying relative to control and in press relative to pulse treatments. Drying negatively affected sediment accumulation in shallow habitat and chironomid density in deep habitat. Drying in intermittent streams has species-dependent effects on fish growth and benthic structure, and pulse and press drying differ in their effects on periphyton in these systems. These effects may have important consequences in seasonally drying streams as anthropogenic influence on stream drying increases.

  16. Dry Stream Reaches in Carbonate Terranes: Surface Indicators of Ground-Water Reservoirs

    USGS Publications Warehouse

    Brahana, J.V.; Hollyday, E.F.

    1988-01-01

    In areas where dry stream reaches occur, subsurface drainage successfully competes with surface drainage, and sheet-like dissolution openings have developed parallel to bedding creating the ground-water reservoir. Union Hollow in south-central Tennessee is the setting for a case study that illustrates the application of the dry stream reach technique. In this technique, dry stream reach identification is based on two types of readily acquired information: remotely sensed black and white infrared aerial photography; and surface reconnaissance of stream channel characteristics. Test drilling in Union Hollow subsequent to identification of the dry reach proved that a localized ground-water reservoir was present.

  17. Process for Nitrogen Oxide Waste Conversion to Fertilizer

    NASA Technical Reports Server (NTRS)

    Lueck, Dale E. (Inventor); Parrish, Clyde F. (Inventor)

    2003-01-01

    The present invention describes a process for converting vapor streams from sources containing at least one nitrogen-containing oxidizing agent therein to a liquid fertilizer composition comprising the steps of: a) directing a vapor stream containing at least one nitrogen-containing oxidizing agent to a first contact zone; b) contacting said vapor stream with water to form nitrogen oxide(s) from said at least one nitrogen-containing oxidizing agent; c) directing said acid(s) as a second stream to a second contact zone; d) exposing said second stream to hydrogen peroxide which is present within said second contact zone in a relative amount of at least 0.1% by weight of said second stream within said second contact zone to convert at least some of any nitrogen oxide species or ions other than in the nitrate form present within said second stream to nitrate ion; e) sampling said stream within said second contact zone to determine the relative amount of hydrogen peroxide within said second contact zone; f) adding hydrogen peroxide to said second contact zone when a level of hydrogen peroxide less than 0.1 % by weight in said second stream is determined by said sampling; g) adding a solution comprising potassium hydroxide to said second stream to maintain a pH between 6.0 and 11.0 within said second stream within said second contact zone to form a solution of potassium nitrate; and h) removing said solution of potassium nitrate from said second contact zone.

  18. Process and Equipment for Nitrogen Oxide Waste Conversion to Fertilizer

    NASA Technical Reports Server (NTRS)

    Lueck, Dale E. (Inventor); Parrish, Clyde F. (Inventor)

    2000-01-01

    The present invention describes a process for converting vapor streams from sources containing at least one nitrogen-containing oxidizing agent therein to a liquid fertilizer composition comprising the steps of: (1) directing a vapor stream containing at least nitrogen-containing oxidizing agent to a first contact zone; (2) contacting said vapor stream with water to form nitrogen oxide(s) from said at least one nitrogen- containing oxidizing agent; (3) directing said acid(s) as a second stream to a second contact zone; (4) exposing said second stream to hydrogen peroxide which is present within said second contact zone in a relative amount of at least 0.1% by weight of said second stream within said second contact zone to convert at least some of any nitrogen oxide species or ions other than in the nitrite form present within said second stream to nitrate ion; (5) sampling said stream within said second contact zone to determine the relative amount of hydrogen peroxide within said second contact zone; (6) adding hydrogen peroxide to said second contact zone when a level on hydrogen peroxide less than 0.1% by weight in said second stream is determined by said sampling; (7) adding a solution comprising potassium hydroxide to said second stream to maintain a pH between 6.0 and 11.0 within said second stream within said second contact zone to form a solution of potassium nitrate; and (8) removing sais solution of potassium nitrate from said second contact zone.

  19. Perennial flow through convergent hillslopes explains chemodynamic solute behavior in a shale headwater catchment

    NASA Astrophysics Data System (ADS)

    Herndon, E.; Steinhoefel, G.; Dere, A. L. D.; Sullivan, P. L.

    2017-12-01

    Streams experience changing hydrologic connectivity to heterogeneous water sources under different flow regimes. It remains unclear how seasonal flow paths link these different sources and regulate concentration-discharge behavior. Previous research at the Susquehanna Shale Hills Critical Zone Observatory (SSHCZO) in central Pennsylvania, USA identified chemostatic solutes (e.g., K, Mg, Na, Cl) whose concentrations varied little across a wide range of discharge values and chemodynamic solutes (e.g., Fe and Mn) whose concentrations decreased sharply with increasing stream discharge. To elucidate inputs to the stream when concentrations of chemodynamic solutes were high, we investigated stream water and shallow groundwater (< 4 m) chemistry at the SSHCZO in early autumn when discharge was negligible. The stream consisted of isolated puddles that were chemically variable along the length of the channel but similar to underlying shallow groundwater. Chemodynamic solute concentrations in the stream and groundwater were high in the upper catchment but decreased by an order of magnitude towards the outlet. In contrast, chemostatic solute concentrations varied little. Groundwater was minimally connected to the stream in an area of upwelling near the stream headwaters; however, the water table remained over a meter below the stream bed along the rest of the channel. We conclude that well water sampled from the upper catchment is young, shallow interflow that upwells to generate metal-rich stream headwaters during the dry season. High concentrations of chemodynamic solutes measured during low discharge occur when metal-rich headwaters are flushed to the catchment outlet during periodic rain events. Interflow during the dry season originates from water that infiltrates through organic-rich swales; thus, metals in the stream at low flow are ultimately derived from convergent hillslopes where biological processes have concentrated chemodynamic elements. We infer that chemodynamic solutes are diluted at high discharge due to increased flow through planar hillslopes and inputs from regional groundwater that rises to enter the stream. This study highlights how spatially heterogeneous biogeochemistry and seasonally variable flow paths regulate concentration-discharge behavior within catchments.

  20. The role of the hyporheic zone across stream networks

    Treesearch

    Steven M. Wondzell

    2011-01-01

    Many hyporheic papers state that the hyporheic zone is a critical component of stream ecosystems, and many of these papers focus on the biogeochemical effects of the hyporheic zone on stream solute loads. However, efforts to show such relationships have proven elusive, prompting several questions: Are the effects of the hyporheic zone on stream ecosystems so highly...

  1. A Fish-Based Index of Biotic Integrity for the Assessment of Streams Located in a Sugarcane-Dominated Landscape in Southeastern Brazil.

    PubMed

    dos Santos, Fernanda Bastos; Esteves, Katharina Eichbaum

    2015-08-01

    A multimetric, fish-based Index of Biotic Integrity (IBI) was developed and tested to assess the ecological status of streams with different riparian conditions in the Piracicaba River Basin. Nine streams with three categories of riparian zone preservation were selected: native forest (NF) with preserved forest, secondary forest (SF) with forest in an advanced state of regeneration and surrounded by sugarcane plantations, and sugarcane (SC) without riparian vegetation and surrounded by SC crops. A continuous scoring system was employed, and candidate metrics were tested for range, responsiveness, and redundancy, resulting in the selection of eight metrics to compose the index. The final IBI score was positively correlated with an Environmental Index both in the dry (Spearman's rho = 0.76; P = 0.01) and rainy seasons (Spearman's rho = 0.66; P = 0.04), suggesting that this IBI is a suitable tool for the assessment of the biological conditions of these streams. The highest IBI values were observed in the rainy season at the NF and SF sites, with significant differences between the NF and SC sites (Kruskal-Wallis test: P = 0.03). The results indicated some variability in the biological integrity at SF and SC sites, suggesting a relationship with the intensity of the management of this crop. Patterns were consistent with other studies that have shown the effects of agriculture on the environmental quality of streams, which indicate the importance of the riparian zone to the maintenance of ecosystem integrity and supports the use of the IBI for biological monitoring in similar regions.

  2. A Fish-Based Index of Biotic Integrity for the Assessment of Streams Located in a Sugarcane-Dominated Landscape in Southeastern Brazil

    NASA Astrophysics Data System (ADS)

    dos Santos, Fernanda Bastos; Esteves, Katharina Eichbaum

    2015-08-01

    A multimetric, fish-based Index of Biotic Integrity (IBI) was developed and tested to assess the ecological status of streams with different riparian conditions in the Piracicaba River Basin. Nine streams with three categories of riparian zone preservation were selected: native forest (NF) with preserved forest, secondary forest (SF) with forest in an advanced state of regeneration and surrounded by sugarcane plantations, and sugarcane (SC) without riparian vegetation and surrounded by SC crops. A continuous scoring system was employed, and candidate metrics were tested for range, responsiveness, and redundancy, resulting in the selection of eight metrics to compose the index. The final IBI score was positively correlated with an Environmental Index both in the dry (Spearman's rho = 0.76; P = 0.01) and rainy seasons (Spearman's rho = 0.66; P = 0.04), suggesting that this IBI is a suitable tool for the assessment of the biological conditions of these streams. The highest IBI values were observed in the rainy season at the NF and SF sites, with significant differences between the NF and SC sites (Kruskal-Wallis test: P = 0.03). The results indicated some variability in the biological integrity at SF and SC sites, suggesting a relationship with the intensity of the management of this crop. Patterns were consistent with other studies that have shown the effects of agriculture on the environmental quality of streams, which indicate the importance of the riparian zone to the maintenance of ecosystem integrity and supports the use of the IBI for biological monitoring in similar regions.

  3. In-stream biogeochemical processes of a temporary river.

    PubMed

    Tzoraki, Ourania; Nikolaidis, Nikolaos P; Amaxidis, Yorgos; Skoulikidis, Nikolaos Th

    2007-02-15

    A reach at the estuary of Krathis River in Greece was used to assess how in-stream processes alter its hydrologic and biogeochemical regime. Krathis River exhibited high annual flow variability and its transmission losses become significant, especially during the dry months. These transmission losses are enhanced in chemistry due to release of nutrients from river sediments. These fluxes are significant because they correspond to 11% of the dissolved inorganic nitrogen flux of the river. Release of nitrogen species was influenced by temperature, while release of phosphate was not because phosphate levels were below the equilibrium concentration. There is a significant amount of sediments with fine composition that create "hot spot" areas in the river reach. These sediments are mobilized during the first flush events in the fall carrying with them a significant load of nutrient and suspended matter to the coastal zone. The nutrient organic content of sediments was also significant and it was studied in terms of its mineralization capacity. The capacity for mineralization was influenced by soil moisture, exhibiting significant capacity even at moisture levels of 40%. Temporary rivers are sensitive ecosystems, vulnerable to climate changes. In-stream processes play a significant role in altering the hydrology and biogeochemistry of the water and its impacts to the coastal zone.

  4. Water resources of the Myakka River basin area, southwest Florida

    USGS Publications Warehouse

    Joyner, Boyd F.; Sutcliffe, Horace

    1976-01-01

    Ground water in the Myakka River basin area of southwest Floria is obtained from a water-table aquifer and from five zones in an artesian aquifer. Wells in the water-table aquifer yield generally less than 50 gpm and dissolved solids concentration is less than 500 mg/liter except in coastal areas and the peninsula southwest of the Myakka River estuary. Wells in the Venice area that tap zone 1 usually yield less than 30 gmp. The quality of water is good except in the peninsula area. Zone 2 is the most highly developed aquifer in the heavily populated coastal areas. Wells yield as much as 200 gpm. In most areas, water is of acceptable quality. Wells that tap zone 3 yield as much as 500 gmp. Fluoride concentration ranges from 1 to 3.5 mg/liter. Zone 4 yields as much as 1,500 gpm to large diameter wells. Except in the extreme northeastern part of the area water from zone 4 usually contains high concentrations of fluoride and sulfate. Zone 5 is the most productive aquifer in the area, but dissolved solids concentrations usually are too high for public supply except in the extreme northeast. Surface water derived from natural drainage is of good quality except for occasional high color in summer. Most of the streams in the Myakka River basin area have small drainage basins, are of short channel length, and do not yield high volumes of flow. During the dry season, streamflow is maintained by groundwater discharge, and, as a result, chloride, sulfate, and dissolved solids concentrations and the hardness of the water are above drinking water standards for some streams. (Woodard-USGS)

  5. [Effect of Seasonal Temperature Increasing on Nitrogen Mineralization in Soil of the Water Level Fluctuating Zone of Three Gorge Tributary During the Dry Period].

    PubMed

    Lin, Jun-jie; Zhang, Shuai; Liu, Dan; Zhou, Bin; Xiao, Xiao-jun; Ma, Hui-yan; Yu, Zhi-guo

    2016-02-15

    To reveal the effect of seasonal temperature increasing on nitrogen mineralization in soil of the water level fluctuating soil zone of three gorge reservoir areas in the Yangtze river tributary during the dry period, surface soils were collected from the water level fluctuating zone of Pengxi river crossing two hydrological sections, i.e., upstream and downstream and three water level altitudes, 155 m (low), 165 m (middle) and 175 m (high). We incubated the soil at 25 degrees C and 35 degrees C to determine the transformation rates of nitrogen in soil of Pengxi river basin during the dry period. The result showed that TN and NO3- -N contents in the soil of upstream section and higher (175 m) altitude of water level were higher than those in downstream and low (165 m) altitude of water level, whereas the pattern for NH4+ -N was different, with higher NH4+ -N contents in downstream and low water level. The inorganic nitrogen was dominated by NO3- -N, which accounted for up to 57.4%-84.7% of inorganic nitrogen. Generally, soil ammoniation, nitration and net N mineralization increased with the rising water level altitude and stream sections (P < 0.05). In summary, nitration and net N mineralization significantly increased with increasing temperature, (P < 0.05), while ammoniation showed no difference (P > 0.05).

  6. Simulated effects of ground-water pumpage on stream-aquifer flow in the vicinity of federally protected species of freshwater mussels in the lower Apalachicola-Chattahoochee-Flint River basin (Subarea 4), southeastern Alabama, northwestern Florida, and southwestern Georgia

    USGS Publications Warehouse

    Albertson, Phillip N.; Torak, Lynn J.

    2002-01-01

    Simulation results indicate that ground-water withdrawal in the lower Apalachicola-Chattahoochee-Flint River basin during times of drought could reduce stream-aquifer flow and cause specific stream reaches to go dry. Of the 37 reaches that were studied, 8 reaches ranked highly sensitive to pumpage, 13 reaches ranked medium, and 16 reaches ranked low. Of the eight reaches that ranked high, seven contain at least one federally protected mussel species. Small tributary streams such as Gum, Jones, Muckalee, Spring, and Cooleewahee Creeks would go dry at lower pumping rates than needed to dry up larger streams. Other streams that were ranked high may go dry depending on the amount of upstream flow entering the reach; this condition is indicated for some reaches on Spring Creek. A dry stream condition is of particular concern to water and wildlife managers because adequate streamflow is essential for mussel survival.

  7. Stream-subsurface nutrient dynamics in a groundwater-fed stream

    NASA Astrophysics Data System (ADS)

    Rezanezhad, F.; Niederkorn, A.; Parsons, C. T.; Van Cappellen, P.

    2015-12-01

    The stream-riparian-aquifer interface plays a major role in the regional flow of nutrients and contaminants due to a strong physical-chemical gradient that promotes the transformation, retention, elimination or release of biogenic elements. To better understand the effect of the near-stream zones on stream biogeochemistry, we conducted a field study on a groundwater-fed stream located in the rare Charitable Research Reserve, Cambridge, Ontario, Canada. This study focused on monitoring the spatial and temporal distributions of nutrient elements within the riparian and hyporheic zones of the stream. Several piezometer nests and a series of passive (diffusion) water samplers, known as peepers, were installed along longitudinal and lateral transects centered on the stream to obtain data on the groundwater chemistry. Groundwater upwelling along the stream resulted in distinctly different groundwater types and associated nitrate concentrations between small distances in the riparian zone (<4m). After the upstream source of the stream surface water, concentrations of nutrients (NO3-, NH4+, SO42- and carbon) did not significantly change before the downstream outlet. Although reduction of nitrate and sulphate were found in the riparian zone of the stream, this did not significantly influence the chemistry of the adjacent stream water. Also, minimal retention in the hyporheic zones limited reduction of reactive compounds (NO3- and SO42-) within the stream channel. The results showed that the dissolved organic carbon (DOC) and residence time of water in the hyporheic zone and in surface water limited denitrification.

  8. Rotary adsorbers for continuous bulk separations

    DOEpatents

    Baker, Frederick S [Oak Ridge, TN

    2011-11-08

    A rotary adsorber for continuous bulk separations is disclosed. The rotary adsorber includes an adsorption zone in fluid communication with an influent adsorption fluid stream, and a desorption zone in fluid communication with a desorption fluid stream. The fluid streams may be gas streams or liquid streams. The rotary adsorber includes one or more adsorption blocks including adsorbent structure(s). The adsorbent structure adsorbs the target species that is to be separated from the influent fluid stream. The apparatus includes a rotary wheel for moving each adsorption block through the adsorption zone and the desorption zone. A desorption circuit passes an electrical current through the adsorbent structure in the desorption zone to desorb the species from the adsorbent structure. The adsorbent structure may include porous activated carbon fibers aligned with their longitudinal axis essentially parallel to the flow direction of the desorption fluid stream. The adsorbent structure may be an inherently electrically-conductive honeycomb structure.

  9. Characterizing hyporheic exchange processes using high-frequency electrical conductivity-discharge relationships on subhourly to interannual timescales

    NASA Astrophysics Data System (ADS)

    Singley, Joel G.; Wlostowski, Adam N.; Bergstrom, Anna J.; Sokol, Eric R.; Torrens, Christa L.; Jaros, Chris; Wilson, Colleen E.; Hendrickson, Patrick J.; Gooseff, Michael N.

    2017-05-01

    Concentration-discharge (C-Q) relationships are often used to quantify source water contributions and biogeochemical processes occurring within catchments, especially during discrete hydrological events. Yet, the interpretation of C-Q hysteresis is often confounded by complexity of the critical zone, such as numerous source waters and hydrochemical nonstationarity. Consequently, researchers must often ignore important runoff pathways and geochemical sources/sinks, especially the hyporheic zone because it lacks a distinct hydrochemical signature. Such simplifications limit efforts to identify processes responsible for the transience of C-Q hysteresis over time. To address these limitations, we leverage the hydrologic simplicity and long-term, high-frequency Q and electrical conductivity (EC) data from streams in the McMurdo Dry Valleys, Antarctica. In this two end-member system, EC can serve as a proxy for the concentration of solutes derived from the hyporheic zone. We utilize a novel approach to decompose loops into subhysteretic EC-Q dynamics to identify individual mechanisms governing hysteresis across a wide range of timescales. We find that hydrologic and hydraulic processes govern EC response to diel and seasonal Q variability and that the effects of hyporheic mixing processes on C-Q transience differ in short and long streams. We also observe that variable hyporheic turnover rates govern EC-Q patterns at daily to interannual timescales. Last, subhysteretic analysis reveals a period of interannual freshening of glacial meltwater streams related to the effects of unsteady flow on hyporheic exchange. The subhysteretic analysis framework we introduce may be applied more broadly to constrain the processes controlling C-Q transience and advance understanding of catchment evolution.

  10. A Cultural Resource Survey of a Proposed Dry Detention Basin in Cape LaCroix Creek Watershed, Cape Girardeau County, Missouri. St. Louis District Cultural Resource Management Report Number 1

    DTIC Science & Technology

    1983-07-01

    bottomlands constituted the soil parent materials. Limestone bedrock outcrops are present only along portions of the stream beds. Three soils series are...friable and readily tilled (Festervand 1981:21). The other bottomland soil series , the Haymond, extends across the remainder of the alluvial zone within the...parcel. While similar to those of the Elsah series in many respects, Haymond silt loams have better drainage and higher natural fertility (Festervand

  11. Method for heating nongaseous carbonaceous material

    DOEpatents

    Lumpkin, Jr., Robert E.

    1978-01-01

    Nongaseous carbonaceous material is heated by a method comprising introducing tangentially a first stream containing a nongaseous carbonaceous material and carbon monoxide into a reaction zone; simultaneously and separately introducing a second stream containing oxygen into the reaction zone such that the oxygen enters the reaction zone away from the wall thereof and reacts with the first stream thereby producing a gaseous product and heating the nongaseous carbonaceous material; forming an outer spiralling vortex within the reaction zone to cause substantial separation of gases, including the gaseous product, from the nongaseous carbonaceous material; removing a third stream from the reaction zone containing the gaseous product which is substantially free of the nongaseous carbonaceous material before a major portion of the gaseous product can react with the nongaseous carbonaceous material; and removing a fourth stream containing the nongaseous carbonaceous material from the reaction zone.

  12. Multi-scale streambed topographic and discharge effects on hyporheic at the stream network scale in confined streams

    Treesearch

    Alessandra Marzadri; Daniele Tonina; James A. McKean; Matthew G. Tiedemann; Rohan M. Benjankar

    2014-01-01

    The hyporheic zone is the volume of the streambed sediment mostly saturated with stream water. It is the transitional zone between stream and shallow-ground waters and an important ecotone for benthic species, including macro-invertebrates, microorganisms, and some fish species that dwell in the hyporheic zone for parts of their lives. Most hyporheic analyses are...

  13. Evaluation of unsaturated zone water fluxes in heterogeneous alluvium at a Mojave Basin Site

    USGS Publications Warehouse

    Nimmo, John R.; Deason, Jeffrey A.; Izbicki, John A.; Martin, Peter

    2002-01-01

    Vertical and horizontal water fluxes in the unsaturated zone near intermittent streams critically affect ecosystems, water supply, and contaminant transport in arid and semiarid regions. The subsurface near the Oro Grande Wash is typical in having great textural diversity, pronounced layer contrasts, and extremely low hydraulic conductivities associated with nearly dry media. These features prevent a straightforward application of the Darcian method for recharge estimation, which has provided high‐quality flux estimates at simpler, wetter sites. We have augmented the basic Darcian method with theoretical developments such that a small number of core sample unsaturated hydraulic property measurements, combined with additional, easily obtained data (e.g., drillers' logs) can provide useful flux estimates and knowledge of two‐dimensional water behavior beneath the wash.

  14. Systems and methods for reactive distillation with recirculation of light components

    DOEpatents

    Stickney, Michael J [Nassau Bay, TX; Jones, Jr., Edward M.

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  15. Nitrate in groundwater and water sources used by riparian trees in an agricultural watershed: A chemical and isotopic investigation in southern Minnesota

    USGS Publications Warehouse

    Komor, Stephen C.; Magner, Joseph A.

    1996-01-01

    This study evaluates processes that affect nitrate concentrations in groundwater beneath riparian zones in an agricultural watershed. Nitrate pathways in the upper 2 m of groundwater were investigated beneath wooded and grass-shrub riparian zones next to cultivated fields. Because trees can be important components of the overall nitrate pathway in wooded riparian zones, water sources used by riparian trees and possible effects of trees on nitrate concentrations in groundwater were also investigated. Average nitrate concentrations in shallow groundwater beneath the cultivated fields were 5.5 mg/L upgradient of the wooded riparian zone and 3.5 mg/L upgradient of the grass-shrub zone. Shallow groundwater beneath the fields passed through the riparian zones and discharged into streams that had average nitrate concentrations of 8.5 mg/L (as N). Lateral variations of δD values in groundwater showed that mixing among different water sources occurred beneath the riparian zones. In the wooded riparian zone, nitrate concentrations in shallow groundwater were diluted by upwelling, nitrate-poor, deep groundwater. Upwelling deep groundwater contained ammonium with a δ15N of 5‰ that upon nitrification and mixing with nitrate in shallow groundwater caused nitrate δ15N values in shallow groundwater to decrease by as much as 19.5‰. Stream water penetrated laterally beneath the wooded riparian zone as far as 19 m from the stream's edge and beneath the grass-shrub zone as far as 27 m from the stream's edge. Nitrate concentrations in shallow groundwater immediately upgradient of where it mixed with stream water averaged 0.4 mg/L in the wooded riparian zone and 0.8 mg/L near the grass-shrub riparian zone. Nitrate concentrations increased toward the streams because of mixing with nitrate-rich stream water. Because nitrate concentrations were larger in stream water than shallow groundwater, concentrated nitrate in the streams cannot have come from shallow groundwater at these sites. Water sources of riparian trees were identified by comparing δD values of sap water, soil water, groundwater, and stream water. Soil water was the main water source for trees in the outer 4 to 6 m of one part of the wooded riparian zone and outer 10 m of another part. Groundwater was a significant water source for trees closer to the streams where the water table was less than about 2.1 to 2.7 m below the surface. No evidence was found in the nitrate concentration profiles that trees close to the streams that took up groundwater through their roots also took up nitrate from groundwater. The lack of such evidence is attributed to the nitrate concentration profiles being insufficiently sensitive indicators of nitrate removal by trees.

  16. Direct observations of rock moisture, a hidden component of the hydrologic cycle.

    PubMed

    Rempe, Daniella M; Dietrich, William E

    2018-03-13

    Recent theory and field observations suggest that a systematically varying weathering zone, that can be tens of meters thick, commonly develops in the bedrock underlying hillslopes. Weathering turns otherwise poorly conductive bedrock into a dynamic water storage reservoir. Infiltrating precipitation typically will pass through unsaturated weathered bedrock before reaching groundwater and running off to streams. This invisible and difficult to access unsaturated zone is virtually unexplored compared with the surface soil mantle. We have proposed the term "rock moisture" to describe the exchangeable water stored in the unsaturated zone in weathered bedrock, purposely choosing a term parallel to, but distinct from, soil moisture, because weathered bedrock is a distinctly different material that is distributed across landscapes independently of soil thickness. Here, we report a multiyear intensive campaign of quantifying rock moisture across a hillslope underlain by a thick weathered bedrock zone using repeat neutron probe measurements in a suite of boreholes. Rock moisture storage accumulates in the wet season, reaches a characteristic upper value, and rapidly passes any additional rainfall downward to groundwater. Hence, rock moisture storage mediates the initiation and magnitude of recharge and runoff. In the dry season, rock moisture storage is gradually depleted by trees for transpiration, leading to a common lower value at the end of the dry season. Up to 27% of the annual rainfall is seasonally stored as rock moisture. Significant rock moisture storage is likely common, and yet it is missing from hydrologic and land-surface models used to predict regional and global climate.

  17. Method for generating hydrogen for fuel cells

    DOEpatents

    Ahmed, Shabbir; Lee, Sheldon H. D.; Carter, John David; Krumpelt, Michael

    2004-03-30

    A method of producing a H.sub.2 rich gas stream includes supplying an O.sub.2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O.sub.2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent. The method still further includes contacting the cooled reformate stream with a catalyst that converts water and carbon monoxide to carbon dioxide and H.sub.2 in a water-gas-shift zone to produce a final reformate stream in the fuel processor.

  18. Fuel processor and method for generating hydrogen for fuel cells

    DOEpatents

    Ahmed, Shabbir [Naperville, IL; Lee, Sheldon H. D. [Willowbrook, IL; Carter, John David [Bolingbrook, IL; Krumpelt, Michael [Naperville, IL; Myers, Deborah J [Lisle, IL

    2009-07-21

    A method of producing a H.sub.2 rich gas stream includes supplying an O.sub.2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O.sub.2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent. The method still further includes contacting the cooled reformate stream with a catalyst that converts water and carbon monoxide to carbon dioxide and H.sub.2 in a water-gas-shift zone to produce a final reformate stream in the fuel processor.

  19. Characterizing multiple timescales of stream and storage zone interaction that affect solute fate and transport in streams

    USGS Publications Warehouse

    Choi, Jungyill; Harvey, Judson W.; Conklin, Martha H.

    2000-01-01

    The fate of contaminants in streams and rivers is affected by exchange and biogeochemical transformation in slowly moving or stagnant flow zones that interact with rapid flow in the main channel. In a typical stream, there are multiple types of slowly moving flow zones in which exchange and transformation occur, such as stagnant or recirculating surface water as well as subsurface hyporheic zones. However, most investigators use transport models with just a single storage zone in their modeling studies, which assumes that the effects of multiple storage zones can be lumped together. Our study addressed the following question: Can a single‐storage zone model reliably characterize the effects of physical retention and biogeochemical reactions in multiple storage zones? We extended an existing stream transport model with a single storage zone to include a second storage zone. With the extended model we generated 500 data sets representing transport of nonreactive and reactive solutes in stream systems that have two different types of storage zones with variable hydrologic conditions. The one storage zone model was tested by optimizing the lumped storage parameters to achieve a best fit for each of the generated data sets. Multiple storage processes were categorized as possessing I, additive; II, competitive; or III, dominant storage zone characteristics. The classification was based on the goodness of fit of generated data sets, the degree of similarity in mean retention time of the two storage zones, and the relative distributions of exchange flux and storage capacity between the two storage zones. For most cases (>90%) the one storage zone model described either the effect of the sum of multiple storage processes (category I) or the dominant storage process (category III). Failure of the one storage zone model occurred mainly for category II, that is, when one of the storage zones had a much longer mean retention time (ts ratio > 5.0) and when the dominance of storage capacity and exchange flux occurred in different storage zones. We also used the one storage zone model to estimate a “single” lumped rate constant representing the net removal of a solute by biogeochemical reactions in multiple storage zones. For most cases the lumped rate constant that was optimized by one storage zone modeling estimated the flux‐weighted rate constant for multiple storage zones. Our results explain how the relative hydrologic properties of multiple storage zones (retention time, storage capacity, exchange flux, and biogeochemical reaction rate constant) affect the reliability of lumped parameters determined by a one storage zone transport model. We conclude that stream transport models with a single storage compartment will in most cases reliably characterize the dominant physical processes of solute retention and biogeochemical reactions in streams with multiple storage zones.

  20. Identifying Stream/Aquifer Exchange by Temperature Gradient in a Guarani Aquifer System Outcrop Zone

    NASA Astrophysics Data System (ADS)

    Wendland, E.; Rosa, D. M. S.; Anache, J. A. A.; Lowry, C.; Lin, Y. F. F.

    2017-12-01

    Recharge of the Guarani Aquifer System (GAS) in South America is supposed to occur mainly in the outcrop zones, where the GAS appears as an unconfined aquifer (10% of the 1.2 Million km2 aquifer extension). Previous evaluations of recharge are based essentially on water balance estimates for the whole aquifer area or water table fluctuations in monitoring wells. To gain a more detailed understanding of the recharge mechanisms the present work aimed to study the stream aquifer interaction in a watershed (Ribeirão da Onça) at an outcrop zone. Two Parshall flumes were installed 1.3 km apart for discharge measurement in the stream. Along this distance an optic fiber cable was deployed to identify stretches with gaining and losing behavior. In order to estimate groundwater discharge in specific locations, 8 temperature sticks were set up along the stream reach to measure continuously the vertical temperature gradient. A temperature probe with 4 thermistors was also used to map the shallow streambed temperature gradient manually along the whole distance. The obtained results show a discharge difference of 250 m3/h between both flumes. Since the last significant rainfall (15 mm) in the watershed occurred 3 months ago, this value can be interpreted as the base flow contribution to the stream during the dry season. Given the temperature difference between groundwater ( 24oC) and surface water ( 17oC) the fiber-optic distributed temperature sensing (FO-DTS) allowed the identification of stretches with gaining behavior. Temperature gradients observed at the streambed varied between 0.67 and 14.33 oC/m. The study demonstrated that heat may be used as natural tracer even in tropical conditions, where the groundwater temperature is higher than the surface water temperature during the winter. The obtained results show that the discharge difference between both flumes can not be extrapolated without detailed analysis. Gaining and loosing stretches have to be identified on order to estimate total base flow contribution of the watershed. This result is important to correct the water balance of the system.

  1. Changes In Tree Species In Riparian Zones Of Urban Streams May Have Effects On Restoration And Storm Water Control Efforts

    EPA Science Inventory

    A riparian zone is the land and vegetation within and directly adjacent to surface water ecosystems, such as lakes and streams. The vegetation in riparian zones provides ecosystem services (such as reducing flooding and bank erosion and reducing levels of pollutants in streams) ...

  2. Bacterial production in the water column of small streams highly depends on terrestrial dissolved organic carbon

    NASA Astrophysics Data System (ADS)

    Graeber, Daniel; Poulsen, Jane R.; Rasmussen, Jes J.; Kronvang, Brian; Zak, Dominik; Kamjunke, Norbert

    2016-04-01

    In the recent years it has become clear that the largest part of the terrestrial dissolved organic carbon (DOC) pool is removed on the way from the land to the ocean. Yet it is still unclear, where in the freshwater systems terrestrial DOC is actually taken up, and for streams DOC uptake was assumed to happen mostly at the stream bottom (benthic zone). However, a recent monitoring study implies that water column but not benthic bacteria are strongly affected by the amount and composition of DOM entering streams from the terrestrial zone. We conducted an experiment to compare the reaction of the bacterial production and heterotrophic uptake in the water column and the benthic zone to a standardized source of terrestrial DOC (leaf leachate from Beech litter). In detail, we sampled gravel and water from eight streams with a gradient in stream size and land use. For each stream four different treatments were incubated at 16°C for three days and each stream: filtered stream water with gravel stones (representing benthic zone bacteria) or unfiltered stream water (representing water column bacteria), both either with (n = 5) or, without (n = 3) leaf leachate. We found that the bacterial uptake of leaf litter DOC was higher for the benthic zone likely due to the higher bacterial production compared to the water column. In contrast, the bacterial production per amount of leaf leachate DOC taken up was significantly higher for the bacteria in the water column than for those in the benthic zone. This clearly indicates a higher growth efficiency with the leaf leachate DOC for the bacteria in the water column than in the benthic zone. We found a high variability for the growth efficiency in the water column, which was best explained by a negative correlation of the DOC demand with stream width (R² = 0.86, linear correlation of log-transformed data). This was not the case for the benthic zone bacteria (R² = 0.02). This implies that water column bacteria in very small streams are more dependent on terrestrial DOC sources for their growth than those in larger streams. Based on this experiment and literature data we hypothesize that: I) The response of the bacterial production to terrestrial DOC in the water column is stronger than for the benthic zone and is decreasing with increasing stream size, likely due to the increase of autochthonous DOC production within the stream. II) Independent of stream size there is only a small reaction to terrestrial DOC for the bacterial production in the benthic zone, either due to internal DOC production or a stronger dependency on particulate organic carbon. We propose that this terrestrial DOC dependency concept is generally applicable, however, its potential underlying mechanisms and concept predictions need to be tested further for other stream and river ecosystems.

  3. Do storage dynamics in hydropedological units control hydrological connectivity? (Invited)

    NASA Astrophysics Data System (ADS)

    Tetzlaff, D.; Birkel, C.; Dick, J.; Geris, J.; Soulsby, C.

    2013-12-01

    In many northern landscapes, peat-dominated riparian wetlands often characterise the zone of connection between terrestrial drainage and the river network. In order to understand the relationship between connectivity and stream flow generation in a montane headwater catchment, we examined the storage dynamics and isotopic composition of soil water in major hydropedological units. These formed a classic catena sequence for northern catchments from free-draining podzols on steep upper hillslopes through to peaty gleysols in lower receiving slopes to deeper peats (Histosols) in the riparian zone. The peaty gleys and peats remained saturated throughout the year, whilst the podzols showed distinct wetting and drying cycles. In this climatic region, most precipitation events are less than 10mm in magnitude, storm runoff is mainly generated from the Histosols and Gleysols, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich surface horizons of the soils due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the strongly reflects that of the near surface waters in the riparian peats. Old 'pre-event' water generally accounts for >80% of flow, even in large events, mainly reflecting the displacement of water stored in the riparian peats and peaty gleys. These riparian areas appear to be the dominant zone where different catchment source waters mix; acting as an 'isostat' that regulates the isotopic composition of stream waters and integrates the Transit Time Distribution (TTD) for the catchment.

  4. Method for reacting nongaseous material with a gaseous reactant

    DOEpatents

    Lumpkin, Robert E.; Duraiswamy, Kandaswamy

    1979-03-27

    This invention relates to a new and novel method and apparatus for reacting nongaseous material with a gaseous reactant comprising introducing a first stream containing a nongaseous material into a reaction zone; simultaneously introducing a second stream containing a gaseous reactant into the reaction zone such that the gaseous reactant immediately contacts and reacts with the first stream thereby producing a gaseous product; forming a spiralling vortex within the reaction zone to cause substantial separation of gases, including the gaseous product, from the nongaseous material; forming and removing a third stream from the reaction zone containing the gaseous product which is substantially free of the nongaseous material before a major portion of the gaseous product can react with the nongaseous material; and forming and removing a fourth stream containing the nongaseous material from the reaction zone.

  5. Release of dissolved phosphorus from riparian wetlands: Evidence for complex interactions among hydroclimate variability, topography and soil properties.

    PubMed

    Gu, Sen; Gruau, Gérard; Dupas, Rémi; Rumpel, Cornélia; Crème, Alexandra; Fovet, Ophélie; Gascuel-Odoux, Chantal; Jeanneau, Laurent; Humbert, Guillaume; Petitjean, Patrice

    2017-11-15

    In agricultural landscapes, establishment of vegetated buffer zones in riparian wetlands (RWs) is promoted to decrease phosphorus (P) emissions because RWs can trap particulate P from upslope fields. However, long-term accumulation of P risks the release of dissolved P, since the unstable hydrological conditions in these zones may mobilize accumulated particulate P by transforming it into a mobile dissolved P species. This study evaluates how hydroclimate variability, topography and soil properties interact and influence this mobilization, using a three-year dataset of molybdate-reactive dissolved P (MRDP) and total dissolved P (TDP) concentrations in soil water from two RWs located in an agricultural catchment in western France (Kervidy-Naizin), along with stream P concentrations. Two main drivers of seasonal dissolved P release were identified: i) soil rewetting during water-table rise after dry periods and ii) reductive dissolution of soil Fe (hydr)oxides during prolonged water saturation periods. These mechanisms were shown to vary greatly in space (according to topography) and time (according to intra- and interannual hydroclimate variability). The concentration and speciation of the released dissolved P also varied spatially depending on soil chemistry and local topography. Comparison of sites revealed a similar correlation between soil P speciation (percentage of organic P ranging from 35-70%) and the concentration and speciation of the released P (MRDP from <0.10 to 0.40mgl -1 ; percentage of MRDP in TDP from 25-70%). These differences propagated to stream water, suggesting that the two RWs investigated were the main sources of dissolved P to streams. RWs can be critical areas due to their ability to biogeochemically transform the accumulated P in these zones into highly mobile and highly bioavailable dissolved P forms. Hydroclimate variability, local topography and soil chemistry must be considered to decrease the risk of remobilizing legacy soil P when establishing riparian buffer zones in agricultural landscapes. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. Using Isotopic Age of Water as a Constraint on Model Identification at a Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    Duffy, C.; Thomas, E.; Bhatt, G.; George, H.; Boyer, E. W.; Sullivan, P. L.

    2016-12-01

    This paper presents an ecohydrologic model constrained by comprehensive space and time observations of water and stable isotopes of oxygen and hydrogen for an upland catchment, the Susquehanna/Shale Hills Critical Zone Observatory (SSH_CZO). The paper first develops the theoretical basis for simulation of flow, isotope ratios and "age" as water moves through the canopy, to the unsaturated and saturated zones and finally to an intermittent stream. The model formulation demonstrates that the residence time and age of environmental tracers can be directly simulated without knowledge of the form of the underlying residence time distribution function and without the addition of any new physical parameters. The model is used to explore the observed rapid attenuation of event and seasonal isotopic ratios in precipitation over the depth of the soil zone and the impact of decreasing hydraulic conductivity with depth on the dynamics of streamflow and stream isotope ratios. The results suggest the importance of mobile macropore flow on recharge to groundwater during the non-growing cold-wet season. The soil matrix is also recharged during this season with a cold-season isotope signature. During the growing-dry season, root uptake and evaporation from the soil matrix along with a declining water table provides the main source of water for plants and determines the growing season signature. Flow path changes during storm events and transient overland flow is inferred by comparing the frequency distribution of groundwater and stream isotope histories with model results. Model uncertainty is evaluated for conditions of matrix-macropore partitioning and heterogeneous variations in conductivity with depth. The paper concludes by comparing the fully dynamical model with the simplified mixing model form in dynamic equilibrium. The comparison illustrates the importance of system memory on the time scales for flow and mixing processes and the limitations of the dynamic equilibrium assumption on estimated age and residence time.

  7. Changes in dissolved organic matter quality in a peatland and forest headwater stream as a function of seasonality and hydrologic conditions

    NASA Astrophysics Data System (ADS)

    Broder, Tanja; Knorr, Klaus-Holger; Biester, Harald

    2017-04-01

    Peatlands and peaty riparian zones are major sources of dissolved organic matter (DOM), but are poorly understood in terms of export dynamics and controls thereof. Thereby quality of DOM affects function and behavior of DOM in aquatic ecosystems, but DOM quality can also help to track DOM sources and their export dynamics under specific hydrologic preconditions. The objective of this study was to elucidate controls on temporal variability in DOM concentration and quality in stream water draining a bog and a forested peaty riparian zone, particularly considering drought and storm flow events. DOM quality was monitored using spectrofluorometric indices for aromaticity (SUVA254), apparent molecular size (SR) and precursor organic material (FI), as well as PARAFAC modeling of excitation emission matrices (EEMs). Indices for DOM quality exhibited major changes due to different hydrologic conditions, but patterns were also dependent on season. Stream water at the forested site with mineral, peaty soils generally exhibited higher variability in DOM concentrations and quality compared to the outflow of an ombrotrophic bog, where DOM was less susceptible to changes in hydrologic conditions. During snowmelt and spring events, near-surface protein-like DOM pools were exported. A microbial DOM fraction originating from groundwater and deep peat layers was increasing during drought, while a strongly microbially altered DOM fraction was also exported by discharge events with dry preconditions at the forested site. This might be due to accelerated microbial activity in the peaty riparian zone of the forested site under these preconditions. Our study demonstrated that DOM export dynamics are not only a passive mixing of different hydrological sources, but monitoring studies have to consider that DOM quality depends on hydrologic preconditions and season. Moreover, the forested peaty riparian zone generated the most variability in headwater DOM quantity and quality, as could be tracked by the used spectrofluorometric indices.

  8. Groundwater-surface water interaction in the riparian zone of an incised channel, Walnut Creek, Iowa

    USGS Publications Warehouse

    Schilling, K.E.; Li, Z.; Zhang, Y.-K.

    2006-01-01

    Riparian zones of many incised channels in agricultural regions are cropped to the channel edge leaving them unvegetated for large portions of the year. In this study we evaluated surface and groundwater interaction in the riparian zone of an incised stream during a spring high flow period using detailed stream stage and hydraulic head data from six wells, and water quality sampling to determine whether the riparian zone can be a source of nitrate pollution to streams. Study results indicated that bank storage of stream water from Walnut Creek during a large storm water runoff event was limited to a narrow 1.6 m zone immediately adjacent to the channel. Nitrate concentrations in riparian groundwater were highest near the incised stream where the unsaturated zone was thickest. Nitrate and dissolved oxygen concentrations and nitrate-chloride ratios increased during a spring recharge period then decreased in the latter portion of the study. We used MODFLOW and MT3DMS to evaluate dilution and denitrification processes that would contribute to decreasing nitrate concentrations in riparian groundwater over time. MT3DMS model simulations were improved with a denitrification rate of 0.02 1/d assigned to the floodplain sediments implying that denitrification plays an important role in reducing nitrate concentrations in groundwater. We conclude that riparian zones of incised channels can potentially be a source of nitrate to streams during spring recharge periods when the near-stream riparian zone is largely unvegetated. ?? 2005 Elsevier B.V. All rights reserved.

  9. Tracer-based characterization of hyporheic exchange and benthic biolayers in streams

    NASA Astrophysics Data System (ADS)

    Knapp, Julia L. A.; González-Pinzón, Ricardo; Drummond, Jennifer D.; Larsen, Laurel G.; Cirpka, Olaf A.; Harvey, Judson W.

    2017-02-01

    Shallow benthic biolayers at the top of the streambed are believed to be places of enhanced biogeochemical turnover within the hyporheic zone. They can be investigated by reactive stream tracer tests with tracer recordings in the streambed and in the stream channel. Common in-stream measurements of such reactive tracers cannot localize where the processing primarily takes place, whereas isolated vertical depth profiles of solutes within the hyporheic zone are usually not representative of the entire stream. We present results of a tracer test where we injected the conservative tracer bromide together with the reactive tracer resazurin into a third-order stream and combined the recording of in-stream breakthrough curves with multidepth sampling of the hyporheic zone at several locations. The transformation of resazurin was used as an indicator of metabolism, and high-reactivity zones were identified from depth profiles. The results from our subsurface analysis indicate that the potential for tracer transformation (i.e., the reaction rate constant) varied with depth in the hyporheic zone. This highlights the importance of the benthic biolayer, which we found to be on average 2 cm thick in this study, ranging from one third to one half of the full depth of the hyporheic zone. The reach-scale approach integrated the effects of processes along the reach length, isolating hyporheic processes relevant for whole-stream chemistry and estimating effective reaction rates.

  10. Tracer-based characterization of hyporheic exchange and benthic biolayers in streams

    USGS Publications Warehouse

    Knapp, Julia L.A.; González-Pinzón, Ricardo; Drummond, Jennifer D.; Larsen, Laurel G.; Cirpka, Olaf A.; Harvey, Judson W.

    2017-01-01

    Shallow benthic biolayers at the top of the streambed are believed to be places of enhanced biogeochemical turnover within the hyporheic zone. They can be investigated by reactive stream tracer tests with tracer recordings in the streambed and in the stream channel. Common in-stream measurements of such reactive tracers cannot localize where the processing primarily takes place, whereas isolated vertical depth profiles of solutes within the hyporheic zone are usually not representative of the entire stream. We present results of a tracer test where we injected the conservative tracer bromide together with the reactive tracer resazurin into a third-order stream and combined the recording of in-stream breakthrough curves with multidepth sampling of the hyporheic zone at several locations. The transformation of resazurin was used as an indicator of metabolism, and high-reactivity zones were identified from depth profiles. The results from our subsurface analysis indicate that the potential for tracer transformation (i.e., the reaction rate constant) varied with depth in the hyporheic zone. This highlights the importance of the benthic biolayer, which we found to be on average 2 cm thick in this study, ranging from one third to one half of the full depth of the hyporheic zone. The reach-scale approach integrated the effects of processes along the reach length, isolating hyporheic processes relevant for whole-stream chemistry and estimating effective reaction rates.

  11. Method for enhancing selectivity and recovery in the fractional flotation of particles in a flotation column

    DOEpatents

    Klunder, Edgar B [Bethel Park, PA

    2011-08-09

    The method relates to particle separation from a feed stream. The feed stream is injected directly into the froth zone of a vertical flotation column in the presence of a counter-current reflux stream. A froth breaker generates a reflux stream and a concentrate stream, and the reflux stream is injected into the froth zone to mix with the interstitial liquid between bubbles in the froth zone. Counter-current flow between the plurality of bubbles and the interstitial liquid facilitates the attachment of higher hydrophobicity particles to bubble surfaces as lower hydrophobicity particles detach. The height of the feed stream injection and the reflux ratio may be varied in order to optimize the concentrate or tailing stream recoveries desired based on existing operating conditions.

  12. [Research advances in macroinvertebrate ecology of the stream hyporheic zone].

    PubMed

    Zhang, Yue-Wei; Yuan, Xing-Zhong; Liu, Hong; Ren, Hai-Qing

    2014-11-01

    The stream hyporheic zone is an ecotone of surface water-ground water interactions, which is rich in biodiversity, and is an important component of stream ecosystem. The macroinvertebrates, which are at the top of food webs in the hyporheic zone to directly influence the matter and energy dynamics of the hyporheic zone, and are potential indicators of river ecological health to adjust the function of environment purification and ecological buffer. The macroinvertebrates in the hyporheic zone are divided into three categories: stygoxenes, stygophiles and stygobites. The key factors which influenced macroinvertebrates distribution in the hyporheic zone are physical size of interstitial spaces, interstitial current velocity, dissolved oxygen (DO), water temperature, available organic matter, hydraulic conductivity and hydraulic retention time. A suitable sampling method should be used for diverse research purposes in the special ecological interface. In the future, some necessary researches should focus on the life-history and life history strategy of the macroinvertebrates in the hyporheic zone, the quantitative analysis on the matter and energy dynamics in the ecological system of stream, the assessment systems of river ecological health based on the macroinvertebrates of the stream hyporheic zone, and the ecological significance of the hyporheic zone as a refuge for distribution and evolution of the macroinvertebrates.

  13. Method for estimating spatially variable seepage loss and hydraulic conductivity in intermittent and ephemeral streams

    USGS Publications Warehouse

    Niswonger, R.G.; Prudic, David E.; Fogg, G.E.; Stonestrom, David A.; Buckland, E.M.

    2008-01-01

    A method is presented for estimating seepage loss and streambed hydraulic conductivity along intermittent and ephemeral streams using streamflow front velocities in initially dry channels. The method uses the kinematic wave equation for routing streamflow in channels coupled to Philip's equation for infiltration. The coupled model considers variations in seepage loss both across and along the channel. Water redistribution in the unsaturated zone is also represented in the model. Sensitivity of the streamflow front velocity to parameters used for calculating seepage loss and for routing streamflow shows that the streambed hydraulic conductivity has the greatest sensitivity for moderate to large seepage loss rates. Channel roughness, geometry, and slope are most important for low seepage loss rates; however, streambed hydraulic conductivity is still important for values greater than 0.008 m/d. Two example applications are presented to demonstrate the utility of the method.

  14. Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes

    DOEpatents

    Nizamoff, Alan J.

    1980-01-01

    In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

  15. Refuge habitats for fishes during seasonal drying in an intermittent stream: movement, survival and abundance of three minnow species

    USGS Publications Warehouse

    Hodges, S.W.; Magoulick, Daniel D.

    2011-01-01

    Drought and summer drying can be important disturbance events in many small streams leading to intermittent or isolated habitats. We examined what habitats act as refuges for fishes during summer drying, hypothesizing that pools would act as refuge habitats. We predicted that during drying fish would show directional movement into pools from riffle habitats, survival rates would be greater in pools than in riffles, and fish abundance would increase in pool habitats. We examined movement, survival and abundance of three minnow species, bigeye shiner (Notropis boops), highland stoneroller (Campostoma spadiceum) and creek chub (Semotilus atromaculatus), during seasonal stream drying in an Ozark stream using a closed robust multi-strata mark-recapture sampling. Population parameters were estimated using plausible models within program MARK, where a priori models are ranked using Akaike's Information Criterion. Creek chub showed directional movement into pools and increased survival and abundance in pools during drying. Highland stonerollers showed strong directional movement into pools and abundance increased in pools during drying, but survival rates were not significantly greater in pools than riffles. Bigeye shiners showed high movement rates during drying, but the movement was non-directional, and survival rates were greater in riffles than pools. Therefore, creek chub supported our hypothesis and pools appear to act as refuge habitats for this species, whereas highland stonerollers partly supported the hypothesis and bigeye shiners did not support the pool refuge hypothesis. Refuge habitats during drying are species dependent. An urgent need exists to further understand refuge habitats in streams given projected changes in climate and continued alteration of hydrological regimes.

  16. A statistical method to predict flow permanence in dryland streams from time series of stream temperature

    USGS Publications Warehouse

    Arismendi, Ivan; Dunham, Jason B.; Heck, Michael; Schultz, Luke; Hockman-Wert, David

    2017-01-01

    Intermittent and ephemeral streams represent more than half of the length of the global river network. Dryland freshwater ecosystems are especially vulnerable to changes in human-related water uses as well as shifts in terrestrial climates. Yet, the description and quantification of patterns of flow permanence in these systems is challenging mostly due to difficulties in instrumentation. Here, we took advantage of existing stream temperature datasets in dryland streams in the northwest Great Basin desert, USA, to extract critical information on climate-sensitive patterns of flow permanence. We used a signal detection technique, Hidden Markov Models (HMMs), to extract information from daily time series of stream temperature to diagnose patterns of stream drying. Specifically, we applied HMMs to time series of daily standard deviation (SD) of stream temperature (i.e., dry stream channels typically display highly variable daily temperature records compared to wet stream channels) between April and August (2015–2016). We used information from paired stream and air temperature data loggers as well as co-located stream temperature data loggers with electrical resistors as confirmatory sources of the timing of stream drying. We expanded our approach to an entire stream network to illustrate the utility of the method to detect patterns of flow permanence over a broader spatial extent. We successfully identified and separated signals characteristic of wet and dry stream conditions and their shifts over time. Most of our study sites within the entire stream network exhibited a single state over the entire season (80%), but a portion of them showed one or more shifts among states (17%). We provide recommendations to use this approach based on a series of simple steps. Our findings illustrate a successful method that can be used to rigorously quantify flow permanence regimes in streams using existing records of stream temperature.

  17. The role of remediation, natural alkalinity sources and physical stream parameters in stream recovery.

    PubMed

    Kruse, Natalie A; DeRose, Lisa; Korenowsky, Rebekah; Bowman, Jennifer R; Lopez, Dina; Johnson, Kelly; Rankin, Edward

    2013-10-15

    Acid mine drainage (AMD) negatively impacts not only stream chemistry, but also aquatic biology. The ultimate goal of AMD treatment is restoration of the biological community, but that goal is rarely explicit in treatment system design. Hewett Fork in Raccoon Creek Watershed, Ohio, has been impacted by historic coal mining and has been treated with a calcium oxide doser in the headwaters of the watershed since 2004. All of the acidic inputs are isolated to a 1.5 km stretch of stream in the headwaters of the Hewett Fork watershed. The macroinvertebrate and fish communities have begun to recover and it is possible to distinguish three zones downstream of the doser: an impaired zone, a transition zone and a recovered zone. Alkalinity from both the doser and natural sources and physical stream parameters play a role in stream restoration. In Hewett Fork, natural alkaline additions downstream are higher than those from the doser. Both, alkaline additions and stream velocity drive sediment and metal deposition. Metal deposition occurs in several patterns; aluminum tends to deposit in regions of low stream velocity, while iron tends to deposit once sufficient alkalinity is added to the system downstream of mining inputs. The majority of metal deposition occurs upstream of the recovered zone. Both the physical stream parameters and natural alkalinity sources influence biological recovery in treated AMD streams and should be considered in remediation plans. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Pasture size effects on the ability of off-stream water or restricted stream access to alter the spatial/temporal distribution of grazing beef cows.

    PubMed

    Bisinger, J J; Russell, J R; Morrical, D G; Isenhart, T M

    2014-08-01

    For 2 grazing seasons, effects of pasture size, stream access, and off-stream water on cow distribution relative to a stream were evaluated in six 12.1-ha cool-season grass pastures. Two pasture sizes (small [4.0 ha] and large [12.1 ha]) with 3 management treatments (unrestricted stream access without off-stream water [U], unrestricted stream access with off-stream water [UW], and stream access restricted to a stabilized stream crossing [R]) were alternated between pasture sizes every 2 wk for 5 consecutive 4-wk intervals in each grazing season. Small and large pastures were stocked with 5 and 15 August-calving cows from mid May through mid October. At 10-min intervals, cow location was determined with Global Positioning System collars fitted on 2 to 3 cows in each pasture and identified when observed in the stream (0-10 m from the stream) or riparian (0-33 m from the stream) zones and ambient temperature was recorded with on-site weather stations. Over all intervals, cows were observed more (P ≤ 0.01) frequently in the stream and riparian zones of small than large pastures regardless of management treatment. Cows in R pastures had 24 and 8% less (P < 0.01) observations in the stream and riparian zones than U or UW pastures regardless of pasture size. Off-stream water had little effect on the presence of cows in or near pasture streams regardless of pasture size. In 2011, the probability of cow presence in the stream and riparian zones increased at greater (P < 0.04) rates as ambient temperature increased in U and UW pastures than in 2010. As ambient temperature increased, the probability of cow presence in the stream and riparian zones increased at greater (P < 0.01) rates in small than large pastures. Across pasture sizes, the probability of cow presence in the stream and riparian zone increased less (P < 0.01) with increasing ambient temperatures in R than U and UW pastures. Rates of increase in the probability of cow presence in shade (within 10 m of tree drip lines) in the total pasture with increasing temperatures did not differ between treatments. However, probability of cow presence in riparian shade increased at greater (P < 0.01) rates in small than large pastures. Pasture size was a major factor affecting congregation of cows in or near pasture streams with unrestricted access.

  19. Modeling the Impact of Stream Discharge Events on Riparian Solute Dynamics.

    PubMed

    Mahmood, Muhammad Nasir; Schmidt, Christian; Fleckenstein, Jan H; Trauth, Nico

    2018-03-22

    The biogeochemical composition of stream water and the surrounding riparian water is mainly defined by the exchange of water and solutes between the stream and the riparian zone. Short-term fluctuations in near stream hydraulic head gradients (e.g., during stream flow events) can significantly influence the extent and rate of exchange processes. In this study, we simulate exchanges between streams and their riparian zone driven by stream stage fluctuations during single stream discharge events of varying peak height and duration. Simulated results show that strong stream flow events can trigger solute mobilization in riparian soils and subsequent export to the stream. The timing and amount of solute export is linked to the shape of the discharge event. Higher peaks and increased durations significantly enhance solute export, however, peak height is found to be the dominant control for overall mass export. Mobilized solutes are transported to the stream in two stages (1) by return flow of stream water that was stored in the riparian zone during the event and (2) by vertical movement to the groundwater under gravity drainage from the unsaturated parts of the riparian zone, which lasts for significantly longer time (> 400 days) resulting in long tailing of bank outflows and solute mass outfluxes. We conclude that strong stream discharge events can mobilize and transport solutes from near stream riparian soils into the stream. The impact of short-term stream discharge variations on solute exchange may last for long times after the flow event. © 2018, National Ground Water Association.

  20. The influence of Critical Zone structure on runoff paths, seasonal water storage, and ecosystem composition

    NASA Astrophysics Data System (ADS)

    Hahm, W. J.; Dietrich, W. E.; Rempe, D.; Dralle, D.; Dawson, T. E.; Lovill, S.; Bryk, A.

    2017-12-01

    Understanding how subsurface water storage mediates water availability to ecosystems is crucial for elucidating linkages between water, energy, and carbon cycles from local to global scales. Earth's Critical Zone (the CZ, which extends from the top of the vegetation canopy downward to fresh bedrock) includes fractured and weathered rock layers that store and release water, thereby contributing to ecosystem water supplies, and yet are not typically represented in land-atmosphere models. To investigate CZ structural controls on water storage dynamics, we intensively studied field sites in a Mediterranean climate where winter rains arrive months before peak solar energy availability, resulting in strong summertime ecosystem reliance on stored subsurface water. Intra-hillslope and catchment-wide observations of CZ water storage capacity across a lithologic boundary in the Franciscan Formation of the Northern California Coast Ranges reveal large differences in the thickness of the CZ and water storage capacity that result in a stark contrast in plant community composition and stream behavior. Where the CZ is thick, rock moisture storage supports forest transpiration and slow groundwater release sustains baseflow and salmon populations. Where the CZ is thin, limited water storage is used by an oak savanna ecosystem, and streams run dry in summer due to negligible hillslope drainage. At both sites, wet season precipitation replenishes the dynamic storage deficit generated during the summer dry season, with excess winter rains exiting the watersheds via storm runoff as perched groundwater fracture flow at the thick-CZ site and saturation overland flow at the thin-CZ site. Annual replenishment of subsurface water storage even in severe drought years may lead to ecosystem resilience to climatic perturbations: during the 2011-2015 drought there was not widespread forest die-off in the study area.

  1. Dry Valley streams in Antarctica: Ecosystems waiting for water

    USGS Publications Warehouse

    McKnight, Diane M.; Niyogi, D.K.; Alger, A.S.; Bomblies, A.; Conovitz, P.A.; Tate, C.M.

    1999-01-01

    An axiom of ecology is: 'Where there is water, there is life.' In dry valley ecosystems of Antarctica, this axiom can be extended to: 'Where there has been and will be water, there is life.' Stream communities in the dry valleys can withstand desiccation on an annual basis and also for longer periods - as much as decades or even centuries. These intact ecosystems, consisting primarily of cyanobacteria and eukaryotic algae, spring back to life with the return of water. Soil organisms in the dry valleys also have remarkable survival capabilities (Virginia and Wall 1999), emerging from dormancy with the arrival of water. Streams in the dry valleys carry meltwater from a glacier or ice-field source to the lakes on the valley floors and generally flow for 4-10 weeks during the summer, depending on climatic conditions. Many of these streams contain abundant algal mats that are perennial in the sense that they are in a freeze-dried state during the winter and begin growing again within minutes of becoming wetted by the first flow of the season. The algal species present in the streams are mainly filamentous cyanobacteria (approximately 20 species of the genera Phormidium, Oscillatoria, and Nostoc), two green algal species of the genus Prasiola, and numerous diatom taxa that are characteristic of soil habitats and polar regions. Algal abundances are greatest in those streams in which periglacial processes, acting over periods of perhaps a century, have produced a stable stone pavement in the streambed. This habitat results in a less turbulent flow regime and limits sediment scour from the streambed. Because dry valley glaciers advance and retreat over periods of centuries and millennia and stream networks in the dry valleys evolve through sediment deposition and transport, some of the currently inactive stream channels may receive flow again in the future. Insights- into the process of algal persistence and reactivation will come from long-term experiments that study the effects of reintroducing water flow to channels in which flow has not occurred for decades or centuries. The present work of the McMurdo Dry Valleys LTER has led us to conclude that the legacy of past conditions constitutes a dominant influence on present-day ecosystem structure and function in the dry valleys (Moorhead et al. 1999). For example, Virginia-and Wall (1999) have found that soil nematodes are partly sustained by relict organic carbon from algae that grew during the high lake stands of 8000-10,000 years ago. Similarly, the growth of current algal populations in the lakes of the dry valleys is supported by diffusion of nutrients from relict nutrient pools in the deep bottom waters (Priscu et al. 1999). For the stream ecosystems, abundant algal mats are present in channels that have stable stone pavements, which formed through freeze-thaw cycles occurring over long periods, possibly hundreds of years. We hypothesize that these stone pavements are an important ecological legacy permitting the successful 'waiting for water' strategy. Similarly, the biodiversity of algal species that can survive the harsh conditions in the streams of the dry valleys may be stable for centuries or more, representing a second important ecological legacy.

  2. Geomorphic controls on hyporheic exchange flow in mountain streams.

    Treesearch

    T. Kasahara; S.M. Wondzell

    2003-01-01

    Hyporheic exchange flows were simulated using MODFLOW and MODPATH to estimate relative effects of channel morphologic features on the extent of the hyporheic zone, on hyporheic exchange flow, and on the residence time of stream water in the hyporheic zone. Four stream reaches were compared in order to examine the influence of stream size and channel constraint. Within...

  3. Acute toxicity of an acid mine drainage mixing zone to juvenile bluegill and largemouth bass

    USGS Publications Warehouse

    Henry, T.B.; Irwin, E.R.; Grizzle, J.M.; Wildhaber, M.L.; Brumbaugh, W.G.

    1999-01-01

    The toxicity of an acid mixing zone produced at the confluence of a stream that was contaminated by acid mine drainage (AMD) and a pH-neutral stream was investigated in toxicity tests with juvenile bluegill Lepomis macrochirus and largemouth bass Micropterus salmoides. Fish mortalities in instream cages located in the mixing zone, below the mixing zone, and upstream in both tributaries were compared to determine relative toxicity at each site. In all tests and for both species, significantly higher mortality was observed in the mixing zone than at any other location, including the acid stream, which had lower pH (2.9-4.3). The mixing zone was defined chemically by rapid precipitation of dissolved aluminum and iron, which arrived from the low-pH stream, and by the presence of white precipitates, which were attached to the substratum and which extended below the confluence. Possible seasonal changes in mixing zone toxicity were investigated by conducting field tests with bluegill in June, July, and August 1996 and in January 1997 and by conducting field tests with largemouth bass in April and May 1997. Toxicity was not significantly different at the extremes of temperature, pH, and metal concentration that occurred in June and July, as compared with January. Toxicity was significantly lower in August; however, elevated stream discharge during the August test may have disturbed mixing zone characteristics. High toxicity in AMD mixing zones may lower the survival of fishes in streams, reduce available habitat, and impede movements of migratory fish.

  4. Direct observations of rock moisture, a hidden component of the hydrologic cycle

    NASA Astrophysics Data System (ADS)

    Rempe, Daniella M.; Dietrich, William E.

    2018-03-01

    Recent theory and field observations suggest that a systematically varying weathering zone, that can be tens of meters thick, commonly develops in the bedrock underlying hillslopes. Weathering turns otherwise poorly conductive bedrock into a dynamic water storage reservoir. Infiltrating precipitation typically will pass through unsaturated weathered bedrock before reaching groundwater and running off to streams. This invisible and difficult to access unsaturated zone is virtually unexplored compared with the surface soil mantle. We have proposed the term “rock moisture” to describe the exchangeable water stored in the unsaturated zone in weathered bedrock, purposely choosing a term parallel to, but distinct from, soil moisture, because weathered bedrock is a distinctly different material that is distributed across landscapes independently of soil thickness. Here, we report a multiyear intensive campaign of quantifying rock moisture across a hillslope underlain by a thick weathered bedrock zone using repeat neutron probe measurements in a suite of boreholes. Rock moisture storage accumulates in the wet season, reaches a characteristic upper value, and rapidly passes any additional rainfall downward to groundwater. Hence, rock moisture storage mediates the initiation and magnitude of recharge and runoff. In the dry season, rock moisture storage is gradually depleted by trees for transpiration, leading to a common lower value at the end of the dry season. Up to 27% of the annual rainfall is seasonally stored as rock moisture. Significant rock moisture storage is likely common, and yet it is missing from hydrologic and land-surface models used to predict regional and global climate.

  5. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOEpatents

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  6. Hydrology and Nitrogen Biogeochemistry in the Hyporheic Zone of a Geomorphically Degraded Urban Stream

    EPA Science Inventory

    Few studies have investigated the relationship between hydrology and nitrogen biogeochemistry in hyporheic zones of degraded urban streams despite significant national efforts to restore such streams. We examined relationships between hydrology and biogeochemistry in Minebank Ru...

  7. Assessing the Use of Dry Wells as a Tool for Stormwater Management and Groundwater Recharge in Urban Areas

    NASA Astrophysics Data System (ADS)

    Edwards, E.; Harter, T.; Fogg, G. E.; Washburn, B.; Bryson, R.; Meirovitz, C.; Fawcett, J.; Kretsinger Grabert, V. J.; Bowles, C.; Carr, M.; Nelson, C.

    2014-12-01

    Dry wells are gravity-fed, excavated pits with perforated casings used to facilitate stormwater infiltration and groundwater recharge in areas comprised primarily of impermeable surfaces or low permeability soils. Stormwater runoff that would otherwise be routed to streams or drains in urban areas is used as a source of aquifer recharge. However, the potential for groundwater contamination caused by urban runoff bypassing surface soil filtration has prevented more widespread use of dry wells as a recharge mechanism. We present the results of a literature survey to assess the potential of dry wells for safe stormwater recharge. Dry wells have been inculpated in groundwater contamination events, although accusations were typically not backed by scientific data. In 1989 groundwater in Modesto, CA, was contaminated with tetrachloroethylene from a dry cleaning facility. The city had been using dry wells to manage stormwater for more than 50 years without detrimental impacts before the contamination. A USGS monitoring study proved that the contamination was from sewer system leakage, and did not involve the dry wells. Some areas of the country have used dry wells with positive results. The Underground Injection Control system (UICs) study in Portland, OR, has been active for ten years, and currently operates over 9,000 UICs. Initially, a ten foot separation distance was enforced between the seasonal high water table and the bottom perforation of the UIC; however, due to monitoring and modeling results that indicate the protectiveness of groundwater, this distance has been reduced to zero feet. Future work will include a comparative pilot study involving a residential and an industrial site in Elk Grove, CA. The study will use modeling tools to assess the recharge potential and groundwater protectiveness of dry wells. Both sites are outfitted with four monitoring wells each: an upgradient monitoring well, two downgradient monitoring wells, and a vadose zone monitoring well. The results of water quality sampling will determine the contaminants of interest, and a model of the fate and transport of these contaminants in the vadose zone will be coupled with hydraulic models to estimate the response of the hydrogeologic system to dry well recharge, with the goal of creating a tool that can be used to evaluate future dry well locations.

  8. Evaluation of the fate and transport of chlorinated ethenes in a complex groundwater system discharging to a stream in Wonju, Korea

    NASA Astrophysics Data System (ADS)

    Lee, Seong-Sun; Kaown, Dugin; Lee, Kang-Kun

    2015-11-01

    Chlorinated ethenes such as trichloroethylene (TCE) are common and persistent groundwater contaminants. If contaminated groundwater discharges to a stream, then stream water pollution near the contamination site also becomes a problem. In this respect, the fate and transport of chlorinated ethenes around a stream in an industrial complex were evaluated using the concentration of each component, and hydrogeochemical, microbial, and compound-specific carbon isotope data. Temporal and spatial monitoring reveal that a TCE plume originating from main and local source zones continues to be discharged to a stream. Groundwater geochemical data indicate that aerobic conditions prevail in the upgradient area of the studied aquifer, whereas conditions become anaerobic in the downgradient. The TCE molar fraction is high at the main and local source zones, ranging from 87.4 to 99.2% of the total volatile organic compounds (VOCs). An increasing trend in the molar fraction of cis-1, 2-Dichloroethene (cis-DCE) and vinyl chloride (VC) was observed in the downgradient zone of the study area. The enriched δ13C values of TCE and depleted values of cis-DCE in the stream zone, compared to those of the source zone, also suggest biodegradation of VOCs. Microbial community structures in monitoring wells adjacent to the stream zone in the downgradient area were analyzed using 16S rRNA gene-based pyrosequencing to identify the microorganisms responsible for biodegradation. This was attributed to the high relative abundance of dechlorinating bacteria in monitoring wells under anaerobic conditions farthest from the stream in the downgradient area. The multilateral approaches adopted in this study, combining hydrogeochemical and biomolecular methods with compound-specific analyses, indicate that contaminants around the stream were naturally attenuated by active anaerobic biotransformation processes.

  9. Refuge habitats for fishes during seasonal drying in an intermittent stream: Movement, survival and abundance of three minnow species

    USGS Publications Warehouse

    Hodges, S.W.; Magoulick, D.D.

    2011-01-01

    Drought and summer drying can be important disturbance events in many small streams leading to intermittent or isolated habitats. We examined what habitats act as refuges for fishes during summer drying, hypothesizing that pools would act as refuge habitats. We predicted that during drying fish would show directional movement into pools from riffle habitats, survival rates would be greater in pools than in riffles, and fish abundance would increase in pool habitats. We examined movement, survival and abundance of three minnow species, bigeye shiner (Notropis boops), highland stoneroller (Campostoma spadiceum) and creek chub (Semotilus atromaculatus), during seasonal stream drying in an Ozark stream using a closed robust multi-strata mark-recapture sampling. Population parameters were estimated using plausible models within program MARK, where a priori models are ranked using Akaike's Information Criterion. Creek chub showed directional movement into pools and increased survival and abundance in pools during drying. Highland stonerollers showed strong directional movement into pools and abundance increased in pools during drying, but survival rates were not significantly greater in pools than riffles. Bigeye shiners showed high movement rates during drying, but the movement was non-directional, and survival rates were greater in riffles than pools. Therefore, creek chub supported our hypothesis and pools appear to act as refuge habitats for this species, whereas highland stonerollers partly supported the hypothesis and bigeye shiners did not support the pool refuge hypothesis. Refuge habitats during drying are species dependent. An urgent need exists to further understand refuge habitats in streams given projected changes in climate and continued alteration of hydrological regimes. ?? 2011 Springer Basel AG (outside the USA).

  10. Dueling Mechanisms for Dry Zones around Frozen Droplets

    NASA Astrophysics Data System (ADS)

    Bisbano, Caitlin; Nath, Saurabh; Boreyko, Jonathan

    2016-11-01

    Ice acts as a local humidity sink, due to its depressed saturation pressure relative to that of supercooled water. Hygroscopic chemicals typically exhibit annular dry zones of inhibited condensation; however, dry zones do not tend to form around ice because of inter-droplet frost growth to nearby liquid droplets that have already condensed on the chilled surface. Here, we use a humidity chamber with an embedded Peltier stage to initially suppress the growth of condensation on a chilled surface containing a single frozen droplet, in order to characterize the dry zone around ice for the first time. The length of the dry zone was observed to vary by at least two orders of magnitude as a function of surface temperature, ambient humidity, and the size of the frozen droplet. The surface temperature and ambient humidity govern the magnitudes of the in-plane and out-of-plane gradients in vapor pressure, while the size of the frozen droplet effects the local thickness of the concentration boundary layer. We develop an analytical model that reveals two different types of dry zones are possible: one in which nucleation is inhibited and one where the net growth of condensate is inhibited. Finally, a phase map was developed to predict the parameter space in which nucleation dry zones versus flux dry zones are dominant.

  11. Southwest Region Threatened, Endangered, and At-Risk Species Workshop: Managing Within Highly Variable Environments Hydrology and Ecology of Intermittent Stream and Dry Wash Ecosystems

    EPA Science Inventory

    Ephemeral (dry washes) and intermittent streams make up approximately 59% of all streams in the U.S. (excluding Alaska), and over 81% in the arid and semi-arid Southwest (Arizona, New Mexico, Nevada, Utah, Colorado and California) according to the National Hydrography Dataset. T...

  12. Microbial responses to changes in flow status in temporary headwater streams: a cross-system comparison

    PubMed Central

    Febria, Catherine M.; Hosen, Jacob D.; Crump, Byron C.; Palmer, Margaret A.; Williams, D. Dudley

    2015-01-01

    Microbial communities are responsible for the bulk of biogeochemical processing in temporary headwater streams, yet there is still relatively little known about how community structure and function respond to periodic drying. Moreover, the ability to sample temporary habitats can be a logistical challenge due to the limited capability to measure and predict the timing, intensity and frequency of wet-dry events. Unsurprisingly, published datasets on microbial community structure and function are limited in scope and temporal resolution and vary widely in the molecular methods applied. We compared environmental and microbial community datasets for permanent and temporary tributaries of two different North American headwater stream systems: Speed River (Ontario, Canada) and Parkers Creek (Maryland, USA). We explored whether taxonomic diversity and community composition were altered as a result of flow permanence and compared community composition amongst streams using different 16S microbial community methods (i.e., T-RFLP and Illumina MiSeq). Contrary to our hypotheses, and irrespective of method, community composition did not respond strongly to drying. In both systems, community composition was related to site rather than drying condition. Additional network analysis on the Parkers Creek dataset indicated a shift in the central microbial relationships between temporary and permanent streams. In the permanent stream at Parkers Creek, associations of methanotrophic taxa were most dominant, whereas associations with taxa from the order Nitrospirales were more dominant in the temporary stream, particularly during dry conditions. We compared these results with existing published studies from around the world and found a wide range in community responses to drying. We conclude by proposing three hypotheses that may address contradictory results and, when tested across systems, may expand understanding of the responses of microbial communities in temporary streams to natural and human-induced fluctuations in flow-status and permanence. PMID:26089816

  13. Modeling hyporheic zone processes

    USGS Publications Warehouse

    Runkel, Robert L.; McKnight, Diane M.; Rajaram, Harihar

    2003-01-01

    Stream biogeochemistry is influenced by the physical and chemical processes that occur in the surrounding watershed. These processes include the mass loading of solutes from terrestrial and atmospheric sources, the physical transport of solutes within the watershed, and the transformation of solutes due to biogeochemical reactions. Research over the last two decades has identified the hyporheic zone as an important part of the stream system in which these processes occur. The hyporheic zone may be loosely defined as the porous areas of the stream bed and stream bank in which stream water mixes with shallow groundwater. Exchange of water and solutes between the stream proper and the hyporheic zone has many biogeochemical implications, due to differences in the chemical composition of surface and groundwater. For example, surface waters are typically oxidized environments with relatively high dissolved oxygen concentrations. In contrast, reducing conditions are often present in groundwater systems leading to low dissolved oxygen concentrations. Further, microbial oxidation of organic materials in groundwater leads to supersaturated concentrations of dissolved carbon dioxide relative to the atmosphere. Differences in surface and groundwater pH and temperature are also common. The hyporheic zone is therefore a mixing zone in which there are gradients in the concentrations of dissolved gasses, the concentrations of oxidized and reduced species, pH, and temperature. These gradients lead to biogeochemical reactions that ultimately affect stream water quality. Due to the complexity of these natural systems, modeling techniques are frequently employed to quantify process dynamics.

  14. Dicamptodon tenebrosus larvae within hyporheic zones of intermittent streams in California

    Treesearch

    David Feral; Michael A. Camann; Hartwell H. Welsh Jr.

    2005-01-01

    Lotic ecosystems are increasingly viewed as having three interactive spatial compartments, i.e., channel sediments, the hyporheic zone, and flood plains or riparian areas (Cummins et al. 1983; Ward 1989). The hyporheic zone is the sub-benthic habitat of interstitial spaces between substrate particles in the stream bed, and is the transition zone between surface flow...

  15. Dry method for recycling iodine-loaded silver zeolite

    DOEpatents

    Thomas, Thomas R.; Staples, Bruce A.; Murphy, Llewellyn P.

    1978-05-09

    Fission product iodine is removed from a waste gas stream and stored by passing the gas stream through a bed of silver-exchanged zeolite until the zeolite is loaded with iodine, passing dry hydrogen gas through the bed to remove the iodine and regenerate the bed, and passing the hydrogen stream containing the hydrogen iodide thus formed through a lead-exchanged zeolite which adsorbs the radioactive iodine from the gas stream and permanently storing the lead-exchanged zeolite loaded with radioactive iodine.

  16. Links between riparian landcover, instream environment and fish assemblages in headwater streams of south-eastern Brazil

    USGS Publications Warehouse

    Cruz, Bruna B.; Miranda, Leandro E.; Cetra, Mauricio

    2013-01-01

    We hypothesised and tested a hierarchical organisation model where riparian landcover would influence bank composition and light availability, which in turn would influence instream environments and control fish assemblages. The study was conducted during the dry season in 11 headwater tributaries of the Sorocaba River in the upper Paraná River Basin, south-eastern Brazil. We focused on seven environmental factors each represented by one or multiple environmental variables and seven fish functional traits each represented by two or more classes. Multivariate direct gradient analyses suggested that riparian zone landcover can be considered a higher level causal factor in a network of relations that control instream characteristics and fish assemblages. Our results provide a framework for a hierarchical conceptual model that identifies singular and collective influences of variables from different scales on each other and ultimately on different aspects related to stream fish functional composition. This conceptual model is focused on the relationships between riparian landcover and instream variables as causal factors on the organisation of stream fish assemblages. Our results can also be viewed as a model for headwater stream management in that landcover can be manipulated to influence factors such as bank composition, substrates and water quality, whereas fish assemblage composition can be used as indicators to monitor the success of such efforts.

  17. Effects of stream flow intermittency on riparian vegetation of a semiarid region river (San Pedro River, Arizona)

    USGS Publications Warehouse

    Stromberg, J.C.; Bagstad, K.J.; Leenhouts, J.M.; Lite, S.J.; Makings, E.

    2005-01-01

    The San Pedro River in the southwestern United States retains a natural flood regime and has several reaches with perennial stream flow and shallow ground water. However, much of the river flows intermittently. Urbanization-linked declines in regional ground-water levels have raised concerns over the future status of the riverine ecosystem in some parts of the river, while restoration-linked decreases in agricultural ground-water pumping are expected to increase stream flows in other parts. This study describes the response of the streamside herbaceous vegetation to changes in stream flow permanence. During the early summer dry season, streamside herbaceous cover and species richness declined continuously across spatial gradients of flow permanence, and composition shifted from hydric to mesic species at sites with more intermittent flow. Hydrologic threshold values were evident for one plant functional group: Schoenoplectus acutus, Juncus torreyi, and other hydric riparian plants declined sharply in cover with loss of perennial stream flow. In contrast, cover of mesic riparian perennials (including Cynodon dactylon, an introduced species) increased at sites with intermittent flow. Patterns of hydric and mesic riparian annuals varied by season: in the early summer dry season their cover declined continuously as flow became more intermittent, while in the late summer wet season their cover increased as the flow became more intermittent. Periodic drought at the intermittent sites may increase opportunities for establishment of these annuals during the monsoonal flood season. During the late summer flood season, stream flow was present at most sites, and fewer vegetation traits were correlated with flow permanence; cover and richness were correlated with other environmental factors including site elevation and substrate nitrate level and particle size. Although perennial-flow and intermittent-flow sites support different streamside plant communities, all of the plant functional groups are abundant at perennial-flow sites when viewing the ecosystem at broader spatial and temporal scales: mesic riparian perennials are common in the floodplain zone adjacent to the river channel and late-summer hydric and mesic annuals are periodically abundant after large floods. Copyright ?? 2005 John Wiley & Sons, Ltd.

  18. Seasonal variations in stream chemistry in a semi-arid montane headwater stream reveal changing hydrologic flowpaths

    NASA Astrophysics Data System (ADS)

    Anderson, S. P.; Mills, T. J.

    2016-12-01

    Water delivery drives weathering and streamflow in catchments. Deciphering the loci of weathering processes and the hydrology of hillslopes requires untangling these deeply entwined systems. Highly variable water delivery compounds the problem. In the Gordon Gulch catchment of Boulder Creek CZO, ephemeral snow, convective storms, and seasonal drought produce highly variable conditions that reveal changing flowpaths contributing to streamflow. We focus on two: groundwater and shallow flow paths. Both are well expressed in the stream during relatively brief periods each year. Baseflow conditions, when streamflow is primarily derived from groundwater, occurs during seasonal drought. Commonly, this is late summer, but it can occur earlier if there is little snow or spring precipitation. We identify baseflow by its chemical signature of low or no Si-Al colloids and DOC, and high concentration of rock-weathering derived dissolved Si, Na, Ca and alkalinity. These solutes increase in concentration downstream, suggesting either a greater proportion of groundwater inputs downstream, or longer deep flowpaths downstream. Shallow flow paths connect to the stream during high flow in periods of high soil moisture from snowmelt or rain. Although annual peak discharge occurs most years from snowmelt augmented by spring rain, convective rainstorms can also drive annual peak discharge. Chemical constituents associated with these shallow connected flowpaths are DOC and Si-Al colloids, which tend to be elevated during wetter conditions in the catchment. We infer that these are mobilized from shallow soil when high soil moisture increases connectivity of shallow soil with the stream channel. These constituents do not vary in concentration downstream. A question they pose is the extent of the zone of connectivity; it seems unlikely that shallow flow paths connected to the stream channel extend far beyond the riparian corridor. Several solutes are mobilized following seasonal drought. Cl and SO4 decline in concentration on both the rising and falling limbs of the annual discharge peak. Their concentrations rise during baseflow, and spike in fall and winter. We infer that these are delivered by dry deposition, and are flushed from shallow soils by wetting events after extended dry periods.

  19. Identifying spatial variability of groundwater discharge in a wetland stream using a distributed temperature sensor

    USGS Publications Warehouse

    Lowry, Christopher S.; Walker, John F.; Hunt, Randall J.; Anderson, Mary P.

    2007-01-01

    Discrete zones of groundwater discharge in a stream within a peat‐dominated wetland were identified on the basis of variations in streambed temperature using a distributed temperature sensor (DTS). The DTS gives measurements of the spatial (±1 m) and temporal (15 min) variation of streambed temperature over a much larger reach of stream (>800 m) than previous methods. Isolated temperature anomalies observed along the stream correspond to focused groundwater discharge zones likely caused by soil pipes within the peat. The DTS also recorded variations in the number of temperature anomalies, where higher numbers correlated well with a gaining reach identified by stream gauging. Focused zones of groundwater discharge showed essentially no change in position over successive measurement periods. Results suggest DTS measurements will complement other techniques (e.g., seepage meters and stream gauging) and help further improve our understanding of groundwater–surface water dynamics in wetland streams.

  20. 40 CFR 63.323 - Test methods and monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... air-perchloroethylene gas-vapor stream on the outlet side of the refrigerated condenser on a dry-to-dry machine, dryer, or reclaimer with a temperature sensor to determine if it is equal to or less than 7.2 °C (45 °F) before the end of the cool-down or drying cycle while the gas-vapor stream is flowing...

  1. 40 CFR 63.323 - Test methods and monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... air-perchloroethylene gas-vapor stream on the outlet side of the refrigerated condenser on a dry-to-dry machine, dryer, or reclaimer with a temperature sensor to determine if it is equal to or less than 7.2 °C (45 °F) before the end of the cool-down or drying cycle while the gas-vapor stream is flowing...

  2. A Hyporheic Mesocosm Experiment: Influence of Quantity and Quality of stream-source DOC on Rates of Hyporheic Metabolism

    NASA Astrophysics Data System (ADS)

    Serchan, S. P.; Wondzell, S. M.; Haggerty, R.; Pennington, R.; Feris, K. P.; Sanfilippo, A. R.; Reeder, W. J.; Tonina, D.

    2016-12-01

    Hyporheic zone biogeochemical processes can influence stream water chemistry. Some estimates show that 50-90% stream water CO2 is produced in the hyporheic zone through heterotrophic metabolism of organic matter, usually supplied from the stream as dissolved organic carbon (DOC). Preliminary results from our well network at the HJ Andrews WS1, indicate that dissolved inorganic carbon (DIC) is 1.5-2 times higher in the hyporheic zone than in stream water. Conversely, DOC (mg/L) is 1.5 times higher in stream water than in the hyporheic zone throughout the year. Overall, the hyporheic zone appears to be a net source of DIC. However, the increase in DIC along hyporheic flow paths is approximately 10-times greater than the loss of DOC, suggesting that metabolism of buried particulate organic carbon (POC) is a major source of organic carbon for microbial metabolism. However, we cannot completely rule out alternative sources of DIC, especially those originating in the overlying riparian soil, because hyporheic processes are difficult to isolate in well networks. To study hyporheic zone biogeochemical processes, particularly the transformation of organic carbon to inorganic carbon species, we designed and built six replicate 2-m long hyporheic mesocosms in which we are conducting DOC amendment experiments. We examine the role of DOC quality and quantity on hyporheic respiration by injecting labile (acetate) and refractory (fulvic acid) organic carbon and comparing rates of O2 consumption, DOC loss, and DIC gains against a control. We expect that stream source DOC is limiting in this small headwater stream, forcing hyporheic metabolism to rely on buried POC. However, the long burial time of POC suggests it is likely of low quality so that supplying labile DOC in stream water should shift hyporheic metabolism away from POC rather than increase the overall rate of metabolism. Future experiments will examine natural sources of DOC (stream periphyton, leaf, and soil humic horizon leachates), the breakdown of wood buried in the hyporheic zone, and the role of temperature and nutrients in controlling the rate at which buried POC is metabolized.

  3. High rates of organic carbon processing in the hyporheic zone of intermittent streams.

    PubMed

    Burrows, Ryan M; Rutlidge, Helen; Bond, Nick R; Eberhard, Stefan M; Auhl, Alexandra; Andersen, Martin S; Valdez, Dominic G; Kennard, Mark J

    2017-10-16

    Organic carbon cycling is a fundamental process that underpins energy transfer through the biosphere. However, little is known about the rates of particulate organic carbon processing in the hyporheic zone of intermittent streams, which is often the only wetted environment remaining when surface flows cease. We used leaf litter and cotton decomposition assays, as well as rates of microbial respiration, to quantify rates of organic carbon processing in surface and hyporheic environments of intermittent and perennial streams under a range of substrate saturation conditions. Leaf litter processing was 48% greater, and cotton processing 124% greater, in the hyporheic zone compared to surface environments when calculated over multiple substrate saturation conditions. Processing was also greater in more saturated surface environments (i.e. pools). Further, rates of microbial respiration on incubated substrates in the hyporheic zone were similar to, or greater than, rates in surface environments. Our results highlight that intermittent streams are important locations for particulate organic carbon processing and that the hyporheic zone sustains this fundamental process even without surface flow. Not accounting for carbon processing in the hyporheic zone of intermittent streams may lead to an underestimation of its local ecological significance and collective contribution to landscape carbon processes.

  4. Influence of riparian seepage zones on nitrate variability in two agricultural headwater streams

    USDA-ARS?s Scientific Manuscript database

    Riparian seepage zones are one of the primary pathways of groundwater transport to headwater streams. While seeps have been recognized for their contributions to streamflow, there is little information on how seeps affect stream water quality. The objective of this study was to examine the influence...

  5. Groundwater Recharge and Flow Regime revealed by multi-tracers approach in a headwater, North China Plain

    NASA Astrophysics Data System (ADS)

    Sakakibara, Koichi; Tsujimura, Maki; Song, Xianfang; Zhang, Jie

    2014-05-01

    Groundwater recharge is a crucial hydrological process for effective water management especially in arid/ semi-arid regions. However, the insufficient number of specific research regarding groundwater recharge process has been reported previously. Intensive field surveys were conducted during rainy season, mid dry season, and end of dry season, in order to clarify comprehensive groundwater recharge and flow regime of Wangkuai watershed in a headwater, which is a main recharge zone of North China Plain. The groundwater, spring, stream water and lake water were sampled, and inorganic solute constituents and stable isotopes of oxygen 18 and deuterium were determined on all water samples. Also the stream flow rate was observed. The solute ion concentrations and stable isotopic compositions show that the most water of this region can be characterized by Ca-HCO3 type and the main water source is precipitation which is affected by altitude effect of stable isotopes. In addition, the river and reservoir of the area seem to recharge the groundwater during rainy season, whereas interaction between surface water and groundwater does not become dominant gradually after the rainy season. The inversion analysis applied in Wangkuai watershed using simple mixing model represents an existing multi-flow systems which shows a distinctive tracer signal and flow rate. In summary, the groundwater recharged at different locations in the upper stream of Wangkuai reservoir flows downward to alluvial fan with a certain amount of mixing together, also the surface water recharges certainly the groundwater in alluvial plain in the rainy season.

  6. Removal of Woody Riparian Vegetation Substantially Altered a Stream Ecosystem in an Otherwise Undisturbed Grassland Watershed

    DOE PAGES

    Larson, Danelle M.; Dodds, Walter K.; Veach, Allison M.

    2018-04-23

    Riparian zones are key interfaces between stream and terrestrial ecosystems. Yet, we know of no whole-watershed experiments that cut only woody vegetation in the riparian zone in an otherwise intact watershed to isolate the role of riparian zones on stream ecology. We removed all of the woody riparian vegetation (from 10- and 30-m-wide buffers in headwaters and main channels, respectively) for 5 km of stream in a single watershed while leaving the remainder of the grassland watershed un-impacted. We assessed water chemistry changes 3 years before and 3 years after riparian wood removal and in two neighboring control watersheds withmore » a before–after, control-impact design and analysis. Riparian woody removal caused 10–100-fold increases in mean stream water nitrate concentrations and pulses of high nitrate for 3 years thereafter. Other nutrients and total suspended solids increased 2–25 times for the 3 years of post-removal. In-stream rates of gross primary production, ecosystem respiration, and net ecosystem production had large treatment effect sizes but also high variance among samples. Past studies of whole-watershed deforestations showed similar water quality responses to our riparian deforestation. Riparian zones of grassland streams are sensitive to disturbance and likely impart relatively greater influence on stream structure and function than the upslope of the watershed. Finally, our results further emphasize the role of riparian zones in biogeochemically linking aquatic and terrestrial habitats.« less

  7. Removal of Woody Riparian Vegetation Substantially Altered a Stream Ecosystem in an Otherwise Undisturbed Grassland Watershed

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Larson, Danelle M.; Dodds, Walter K.; Veach, Allison M.

    Riparian zones are key interfaces between stream and terrestrial ecosystems. Yet, we know of no whole-watershed experiments that cut only woody vegetation in the riparian zone in an otherwise intact watershed to isolate the role of riparian zones on stream ecology. We removed all of the woody riparian vegetation (from 10- and 30-m-wide buffers in headwaters and main channels, respectively) for 5 km of stream in a single watershed while leaving the remainder of the grassland watershed un-impacted. We assessed water chemistry changes 3 years before and 3 years after riparian wood removal and in two neighboring control watersheds withmore » a before–after, control-impact design and analysis. Riparian woody removal caused 10–100-fold increases in mean stream water nitrate concentrations and pulses of high nitrate for 3 years thereafter. Other nutrients and total suspended solids increased 2–25 times for the 3 years of post-removal. In-stream rates of gross primary production, ecosystem respiration, and net ecosystem production had large treatment effect sizes but also high variance among samples. Past studies of whole-watershed deforestations showed similar water quality responses to our riparian deforestation. Riparian zones of grassland streams are sensitive to disturbance and likely impart relatively greater influence on stream structure and function than the upslope of the watershed. Finally, our results further emphasize the role of riparian zones in biogeochemically linking aquatic and terrestrial habitats.« less

  8. Hyporheic zone denitrification: controls on effective reaction depth and contribution to whole-stream mass balance

    USGS Publications Warehouse

    Harvey, Judson W.; Böhlke, John Karl; Voytek, Mary A.; Scott, Durelle; Tobias, Craig R.

    2013-01-01

    Stream denitrification is thought to be enhanced by hyporheic transport but there is little direct evidence from the field. To demonstrate at a field site, we injected 15NO3−, Br (conservative tracer), and SF6 (gas exchange tracer) and compared measured whole-stream denitrification with in situ hyporheic denitrification in shallow and deeper flow paths of contrasting geomorphic units. Hyporheic denitrification accounted for between 1 and 200% of whole-stream denitrification. The reaction rate constant was positively related to hyporheic exchange rate (greater substrate delivery), concentrations of substrates DOC and nitrate, microbial denitrifier abundance (nirS), and measures of granular surface area and presence of anoxic microzones. The dimensionless product of the reaction rate constant and hyporheic residence time, λhzτhz define a Damköhler number, Daden-hz that was optimal in the subset of hyporheic flow paths where Daden-hz ≈ 1. Optimal conditions exclude inefficient deep pathways transport where substrates are used up and also exclude inefficient shallow pathways that require repeated hyporheic entries and exits to complete the reaction. The whole-stream reaction significance, Rs (dimensionless), was quantified by multiplying Daden-hz by the proportion of stream discharge passing through the hyporheic zone. Together these two dimensionless metrics, one flow-path scale and the other reach-scale, quantify the whole-stream significance of hyporheic denitrification. One consequence is that the effective zone of significant denitrification often differs from the full depth of the hyporheic zone, which is one reason why whole-stream denitrification rates have not previously been explained based on total hyporheic-zone metrics such as hyporheic-zone size or residence time.

  9. Influence of Gully Erosion Control on Amphibian and Reptile Communities within Riparian Zones of Channelized Streams

    USDA-ARS?s Scientific Manuscript database

    Riparian zones of streams in northwestern Mississippi have been impacted by agriculture, channelization, channel incision, and gully erosion. Riparian gully formation has resulted in the fragmentation of remnant riparian zones within agricultural watersheds. One widely used conservation practice for...

  10. Mercury and methylmercury dynamics in the hyporheic zone of an Oregon stream

    USGS Publications Warehouse

    Hinkle, Stephen R.; Bencala, Kenneth E.; Wentz, Dennis A.; Krabbenhoft, David P.

    2014-01-01

    The role of the hyporheic zone in mercury (Hg) cycling has received limited attention despite the biogeochemically active nature of this zone and, thus, its potential to influence Hg behavior in streams. An assessment of Hg geochemistry in the hyporheic zone of a coarse-grained island in the Coast Fork Willamette River in Oregon, USA, illustrates the spatially dynamic nature of this region of the stream channel for Hg mobilization and attenuation. Hyporheic flow through the island was evident from the water-table geometry and supported by hyporheic-zone chemistry distinct from that of the bounding groundwater system. Redox-indicator species changed abruptly along a transect through the hyporheic zone, indicating a biogeochemically reactive stream/hyporheic-zone continuum. Dissolved organic carbon (DOC), total Hg, and methylmercury (MeHg) concentrations increased in the upgradient portion of the hyporheic zone and decreased in the downgradient region. Total Hg (collected in 2002 and 2003) and MeHg (collected in 2003) were correlated with DOC in hyporheic-zone samples: r2=0.63 (total Hg-DOC, 2002), 0.73 (total Hg-DOC, 2003), and 0.94 (MeHg-DOC, 2003). Weaker Hg/DOC association in late summer 2002 than in early summer 2003 may reflect seasonal differences in DOC reactivity. Observed correlations between DOC and both total Hg and MeHg reflect the importance of DOC for Hg mobilization, transport, and fate in this hyporheic zone. Correlations with DOC provide a framework for conceptualizing and quantifying Hg and MeHg dynamics in this region of the stream channel, and provide a refined conceptual model of the role hyporheic zones may play in aquatic ecosystems.

  11. Effects and Non-effects of Stream Drying on Stonefly(Plecoptera) Assemblages in two Ouachita Mountains,AR, Catchments

    NASA Astrophysics Data System (ADS)

    Sheldon, A. L.; Warren, M. L.

    2005-05-01

    Streams integrate landscape change. To establish baseline conditions and predictive relationships in two experimental catchments, we collected adult stoneflies at 38 sites for a year. We used a stratified random sampling design and regular collections of adults, which are identifiable to species level, to ensure thorough coverage. We collected 43 species (1-27 per site). We characterized sites by two descriptors: stream size as drainage AREA, and DRY, a time-weighted average of absence of surface water in measured sections. Sites ranged from continuous surface flow to partial or total drying for months. Species composition (NMS ordination) was influenced strongly by DRY. Richness of species and genera were well described (R2>85%) by multiple regressions on AREA and DRY. However, species richness was related strongly to AREA (P<0.001) but independent of DRY (P>0.45). Generic richness, in contrast, was related significantly(P<0.001)to both descriptors but the negative effect of DRY was stronger. Seasonal drying is common in the Ouachita region and part of the fauna is resistant to drying. Our results have implications for diversity-stress relationships and taxonomic resolution in community ecology and monitoring.

  12. Water quality modeling based on landscape analysis: Importance of riparian hydrology

    Treesearch

    Thomas Grabs

    2010-01-01

    Several studies in high-latitude catchments have demonstrated the importance of near-stream riparian zones as hydrogeochemical hotspots with a substantial influence on stream chemistry. An adequate representation of the spatial variability of riparian-zone processes and characteristics is the key for modeling spatiotemporal variations of stream-water quality. This...

  13. Functional Process Zones Characterizing Aquatic Insect Communities in Streams of the Brazilian Cerrado.

    PubMed

    Godoy, B S; Simião-Ferreira, J; Lodi, S; Oliveira, L G

    2016-04-01

    Stream ecology studies see to understand ecological dynamics in lotic systems. The characterization of streams into Functional Process Zones (FPZ) has been currently debated in stream ecology because aquatic communities respond to functional processes of river segments. Therefore, we tested if different functional process zones have different number of genera and trophic structure using the aquatic insect community of Neotropical streams. We also assessed whether using physical and chemical variables may complement the approach of using FPZ to model communities of aquatic insects in Cerrado streams. This study was conducted in 101 streams or rivers from the central region of the state of Goiás, Brazil. We grouped the streams into six FPZ associated to size of the river system, presence of riparian forest, and riverbed heterogeneity. We used Bayesian models to compare number of genera and relative frequency of the feeding groups between FPZs. Streams classified in different FPZs had a different number of genera, and the largest and best preserved rivers had an average of four additional genera. Trophic structure exhibited low variability among FPZs, with little difference both in the number of genera and in abundance. Using functional process zones in Cerrado streams yielded good results for Ephemeroptera, Plecoptera, and Trichoptera communities. Thus, species distribution and community structure in the river basin account for functional processes and not necessarily for the position of the community along a longitudinal dimension of the lotic system.

  14. Numbers of fecal streptococci and Escherichia coli in fresh and dry cattle, horse, and sheep manure.

    PubMed

    Weaver, R W; Entry, J A; Graves, Alexandria

    2005-10-01

    Livestock are known contributors to stream pollution. Numbers of fecal streptococci and Escherichia coli in manure naturally deposited by livestock in the field are needed for activities related to bacterial source tracking and determining maximum daily bacterial loading of streams. We measured populations of fecal streptococci and E. coli in fresh and dry manure from cattle (Bos taurus L.), horses (Equus caballus L.), and sheep (Ovis aires L.) on farms in southern Idaho. Populations of indicator bacteria in dry manure were often as high as that in fresh manure from horse and sheep. There was a 2 log10 drop in the population of fecal coliform numbers in dry cattle manure from cattle in pastures but not from cattle in pens. Bacterial isolates used in source tracking should include isolates from both fresh and dry manure to better represent the bacterial source loading of streams.

  15. Estimating Locations of Perennial Streams in Idaho Using a Generalized Least-Squares Regression Model of 7-Day, 2-Year Low Flows

    USGS Publications Warehouse

    Wood, Molly S.; Rea, Alan; Skinner, Kenneth D.; Hortness, Jon E.

    2009-01-01

    Many State and Federal agencies use information regarding the locations of streams having intermittent or perennial flow when making management and regulatory decisions. For example, the application of some Idaho water quality standards depends on whether streams are intermittent. Idaho Administrative Code defines an intermittent stream as one having a 7-day, 2-year low flow (7Q2) less than 0.1 ft3/s. However, there is a general recognition that the cartographic representation of perennial/intermittent status of streams on U.S. Geological Survey (USGS) topographic maps is not as accurate or consistent as desirable from one map to another, which makes broad management and regulatory assessments difficult and inconsistent. To help resolve this problem, the USGS has developed a methodology for predicting the locations of perennial streams based on regional generalized least-squares (GLS) regression equations for Idaho streams for the 7Q2 low-flow statistic. Using these regression equations, the 7Q2 streamflow may be estimated for naturally flowing streams in most areas in Idaho. The use of these equations in conjunction with a geographic information system (GIS) technique known as weighted flow accumulation allows for an automated and continuous estimation of 7Q2 streamflow at all points along stream reaches. The USGS has developed a GIS-based map of the locations of streams in Idaho with perennial flow based on a 7Q2 of 0.1 ft3/s and a transition zone of plus or minus 1 standard error. Idaho State cooperators plan to use this information to make regulatory and water-quality management decisions. Originally, 7Q2 equations were developed for eight regions of similar hydrologic characteristics in the study area, using long-term data from 234 streamflow-gaging stations. Equations in five of the regions were revised based on spatial patterns observed in the initial perennial streams map and unrealistic behavior of the equations in extrapolation. The standard errors of prediction for the final equations ranged from a minimum of +75.0 to -42.9 percent in the central part of the study area to a maximum of +277 to -73.5 percent in the southern part of the study area. The equations are applicable only to unregulated, naturally-flowing streams and may produce unreliable results outside the range of explanatory variables used for equation development. Extrapolation outside the range of available data was necessary, however, to predict perennial flow initiation points and transition zones along stream reaches. The map of perennial streams was evaluated by comparing predicted stream classifications with four independent datasets, including field observations by other government agencies. Overall, 81 percent of the comparison data points agreed with the USGS perennial streams model. Regions with the highest number of disagreements had a high percentage of mountainous and forested area with potential mountain front recharge zones, and regions with the highest agreements had a high percentage of low gradient, low elevation area. As a whole, the USGS model predicted a higher number of perennial streams than predictions made with the independent datasets. Some disagreements were due to poor site location coordinates, timing of the comparison site visits during unusually wet or dry years, discrepancies in classification criteria, and variable ground water contributions to flow in some areas. The Idaho Department of Environmental Quality Beneficial Use Reconnaissance Program (BURP) dataset is considered the most representative dataset for comparison because it covered a range of climate conditions and the number of sites visited were consistent from year to year during the study period. Eighty-five percent of BURP comparison data points agreed with the USGS perennial streams model. Although site-specific flow data may be needed to correctly classify streams in some areas, this information rarely is available and is not always practical to o

  16. Evaluation of the fate and transport of chlorinated ethenes in a complex groundwater system discharging to a stream in Wonju, Korea.

    PubMed

    Lee, Seong-Sun; Kaown, Dugin; Lee, Kang-Kun

    2015-11-01

    Chlorinated ethenes such as trichloroethylene (TCE) are common and persistent groundwater contaminants. If contaminated groundwater discharges to a stream, then stream water pollution near the contamination site also becomes a problem. In this respect, the fate and transport of chlorinated ethenes around a stream in an industrial complex were evaluated using the concentration of each component, and hydrogeochemical, microbial, and compound-specific carbon isotope data. Temporal and spatial monitoring reveal that a TCE plume originating from main and local source zones continues to be discharged to a stream. Groundwater geochemical data indicate that aerobic conditions prevail in the upgradient area of the studied aquifer, whereas conditions become anaerobic in the downgradient. The TCE molar fraction is high at the main and local source zones, ranging from 87.4 to 99.2% of the total volatile organic compounds (VOCs). An increasing trend in the molar fraction of cis-1, 2-Dichloroethene (cis-DCE) and vinyl chloride (VC) was observed in the downgradient zone of the study area. The enriched δ(13)C values of TCE and depleted values of cis-DCE in the stream zone, compared to those of the source zone, also suggest biodegradation of VOCs. Microbial community structures in monitoring wells adjacent to the stream zone in the downgradient area were analyzed using 16S rRNA gene-based pyrosequencing to identify the microorganisms responsible for biodegradation. This was attributed to the high relative abundance of dechlorinating bacteria in monitoring wells under anaerobic conditions farthest from the stream in the downgradient area. The multilateral approaches adopted in this study, combining hydrogeochemical and biomolecular methods with compound-specific analyses, indicate that contaminants around the stream were naturally attenuated by active anaerobic biotransformation processes. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Influence of gully erosion control on amphibian and reptile communities within riparian zones of channelized streams

    USDA-ARS?s Scientific Manuscript database

    Riparian zones of streams in northern Mississippi have been impacted by agriculture, channelization, channel incision, and gully erosion. Gully erosion is the most severe form of erosion and has resulted in the fragmentation of remnant riparian zones within agricultural watersheds. One widely used c...

  18. Calculating terrain indices along streams: A new method for separating stream sides

    Treesearch

    T. J. Grabs; K. G. Jencso; B. L. McGlynn; J. Seibert

    2010-01-01

    There is increasing interest in assessing riparian zones and their hydrological and biogeochemical buffering capacity with indices derived from hydrologic landscape analysis of digital elevation data. Upslope contributing area is a common surrogate for lateral water flows and can be used to assess the variability of local water inflows to riparian zones and streams....

  19. Method of CO.sub.2 removal from a gasesous stream at reduced temperature

    DOEpatents

    Fisher, James C; Siriwardane, Ranjani V; Berry, David A; Richards, George A

    2014-11-18

    A method for the removal of H.sub.2O and CO.sub.2 from a gaseous stream comprising H.sub.2O and CO.sub.2, such as a flue gas. The method initially utilizes an H.sub.2O removal sorbent to remove some portion of the H.sub.2O, producing a dry gaseous stream and a wet H.sub.2O removal sorbent. The dry gaseous stream is subsequently contacted with a CO.sub.2 removal sorbent to remove some portion of the CO.sub.2, generating a dry CO.sub.2 reduced stream and a loaded CO.sub.2 removal sorbent. The loaded CO.sub.2 removal sorbent is subsequently heated to produce a heated CO.sub.2 stream. The wet H.sub.2O removal sorbent and the dry CO.sub.2 reduced stream are contacted in a first regeneration stage, generating a partially regenerated H.sub.2O removal sorbent, and the partially regenerated H.sub.2O removal sorbent and the heated CO.sub.2 stream are subsequently contacted in a second regeneration stage. The first and second stage regeneration typically act to retain an initial monolayer of moisture on the various removal sorbents and only remove moisture layers bound to the initial monolayer, allowing for relatively low temperature and pressure operation. Generally the applicable H.sub.2O sorption/desorption processes may be conducted at temperatures less than about 70.degree. C. and pressures less than 1.5 atmospheres, with certain operations conducted at temperatures less than about 50.degree. C.

  20. Flue gas desulfurization method and apparatus

    DOEpatents

    Madden, Deborah A.; Farthing, George A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  1. Flue gas desulfurization method and apparatus

    DOEpatents

    Madden, Deborah A.; Farthing, George A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  2. Understanding the effects of predictability, duration, and spatial pattern of drying on benthic invertebrate assemblages in two contrasting intermittent streams

    PubMed Central

    von Schiller, Daniel; Barberá, Gonzalo G.; Díaz, Angela M.; Arce, Maria Isabel; del Campo, Rubén; Tockner, Klement

    2018-01-01

    In the present study, we examined the effects of different drying conditions on the composition, structure and function of benthic invertebrate assemblages. We approached this objective by comparing invertebrate assemblages in perennial and intermittent sites along two intermittent Mediterranean streams with contrasting predictability, duration, and spatial patterns of drying: Fuirosos (high predictability, short duration, downstream drying pattern) and Rogativa (low predictability, long duration, patchy drying pattern). Specifically, we quantified the contribution of individual taxa to those differences, the degree of nestedness, and shifts in the composition, structure and function of benthic invertebrate assemblages along flow intermittence gradients. We observed greater effects of drying on the benthic invertebrate composition in Fuirosos than in Rogativa, resulting in a higher dissimilarity of assemblages between perennial and intermittent sites, as well as a lower degree of nestedness. Furthermore, a higher number of biotic metrics related to richness, abundance and biological traits were significantly different between perennial and intermittent sites in Fuirosos, despite a shorter dry period compared to Rogativa. At the same time, slightly different responses were detected during post-drying (autumn) than pre-drying (spring) conditions in this stream. In Rogativa, shifts in benthic invertebrate assemblages along increasing gradients of flow intermittence were found for three metrics (Ephemeroptera, Plecoptera and Trichoptera (EPT) and Odonata, Coleoptera and Heteroptera (OCH) abundances and aerial active dispersal. Furthermore, we demonstrated that combined gradients of dry period duration and distance to nearest perennial reach can generate complex, and different, responses of benthic invertebrate assemblages, depending on the flow intermittence metric. Our study advances the notion that special attention should be paid to the predictability, duration and spatial patterns of drying in intermittent streams in order to disentangle the effects of drying on benthic invertebrate assemblages, in particular in areas subject to high spatial heterogeneity and temporal variability in drying conditions. PMID:29590140

  3. Method of extracting iodine from liquid mixtures of iodine, water and hydrogen iodide

    DOEpatents

    Mysels, Karol J.

    1979-01-01

    The components of a liquid mixture consisting essentially of HI, water and at least about 50 w/o iodine are separated in a countercurrent extraction zone by treating with phosphoric acid containing at least about 90 w/o H.sub.3 PO.sub.4. The bottom stream from the extraction zone is substantially completely molten iodine, and the overhead stream contains water, HI, H.sub.3 PO.sub.4 and a small fraction of the amount of original iodine. When the water and HI are present in near-azeotropic proportions, there is particular advantage in feeding the overhead stream to an extractive distillation zone wherein it is treated with additional concentrated phosphoric acid to create an anhydrous HI vapor stream and bottoms which contain at least about 85 w/o H.sub.3 PO.sub.4. Concentration of these bottoms provides phosphoric acid infeed for both the countercurrent extraction zone and for the extractive distillation zone.

  4. Comparing Models and Methods for the Delineation of Stream Baseflow Contribution Areas

    NASA Astrophysics Data System (ADS)

    Chow, R.; Frind, M.; Frind, E. O.; Jones, J. P.; Sousa, M.; Rudolph, D. L.; Nowak, W.

    2016-12-01

    This study addresses the delineation of areas that contribute baseflow to a stream reach, also known as stream capture zones. Such areas can be delineated using standard well capture zone delineation methods, with three important differences: (1) natural gradients are smaller compared to those produced by supply wells and are therefore subject to greater numerical errors, (2) stream discharge varies seasonally, and (3) stream discharge varies spatially. This study focuses on model-related uncertainties due to parameter non-uniqueness, discretization schemes, and particle tracking algorithms. The methodology is applied to the Alder Creek watershed in southwestern Ontario. Four different model codes are compared: HydroGeoSphere, WATFLOW, MODFLOW, and FEFLOW. In addition, two delineation methods are compared: reverse particle tracking and reverse transport, where the latter considers local-scale parameter uncertainty by using a macrodispersion term to produce a capture probability plume. The results from this study indicate that different models can calibrate acceptably well to the same data and produce very similar distributions of hydraulic head, but can produce different capture zones. The stream capture zone is found to be highly sensitive to the particle tracking algorithm. It was also found that particle tracking by itself, if applied to complex systems such as the Alder Creek watershed, would require considerable subjective judgement in the delineation of stream capture zones. Reverse transport is an alternate approach that provides probability intervals for the baseflow contribution areas. In situations where the two approaches agree, the confidence in the delineation is reinforced.

  5. Riparian zone hydrology and biogeochemistry as a function of stream evolution stage in glaciated landscapes of the US Northeast

    NASA Astrophysics Data System (ADS)

    Rook, S. P.; Vidon, P.; Walter, M. T.

    2011-12-01

    The management of riparian buffer strips is often regarded as one of the most economical and sustainable methods of managing non-point source pollution and water quality. However, current riparian management often follows a 'one size fits all' design, which fails to recognize the complexity of the many biogeochemical processes that regulate pollutant transformation and retention in these systems. This study addresses two critical gaps in knowledge: (1) How carbon, nitrogen, phosphorous, and iron cycles interact with one another (rather than individually). (2) How stream channel geometry and evolution regulate these nutrient cycles and greenhouse gas (GHG) dynamics in the near stream zone. This project specifically explores the hydrological and biogeochemical functioning of riparian zones across a gradient of stream meander evolution stages, with the primary goal of understanding and predicting potential interactions between nutrient dynamics in these systems. Key research questions include: (1) How does stream meander curvature affect riparian zone hydrology? (2) How does stream meander curvature influence riparian zone biogeochemistry? (3) What relationships exist among N, P, Fe, and GHG dynamics? We instrumented three riparian sites near Ithaca, NY, with a dense network of wells, piezometers, and static chambers. These sites represent three riparian zones along three evolution stages of stream meanders: an inner meander, a straight stream section, and an outer bend of the stream with an oxbow lake formation. In spring through fall 2011, water samples and gas samples were collected at a tri-weekly bases at each of the three sites. Water samples were analyzed for oxidation-reduction potential, dissolved oxygen, temperature, FeII/FeIII, nutrients (NO3-, NH4+, PO43-) and dissolved organic carbon (DOC). GHG fluxes at the soil-atmosphere interface were measured for N2O, CO2, and CH4 gases. We predict that stream curvature will significantly affect groundwater flow direction in the riparian zones. Owing to more prolonged saturation, we expect that the oxbow setting will exhibit anoxic conditions, and associated biogeochemistry. Finally, we hypothesize clear relationships among N, P, Fe, and GHG dynamics. In areas of significant denitrification, we expect to see an increase in Fe reduction, PO43- release, N2O emission, and CH4 emission, and a decrease in CO2 emission. Quantifying these interactions will enhance our ability to model riparian biogeochemical processes, promote water quality, and comprehend to what extent the promotion of riparian zones for nitrate removal is done at the expense of air quality (with respect to GHG emissions) and/or water quality (with respect to P).

  6. The importance of the riparian zone and in-stream processes in nitrate attenuation in undisturbed and agricultural watersheds – a review of the scientific literature

    USGS Publications Warehouse

    Ranalli, Anthony J.; Macalady, Donald L.

    2010-01-01

    We reviewed published studies from primarily glaciated regions in the United States, Canada, and Europe of the (1) transport of nitrate from terrestrial ecosystems to aquatic ecosystems, (2) attenuation of nitrate in the riparian zone of undisturbed and agricultural watersheds, (3) processes contributing to nitrate attenuation in riparian zones, (4) variation in the attenuation of nitrate in the riparian zone, and (5) importance of in-stream and hyporheic processes for nitrate attenuation in the stream channel. Our objectives were to synthesize the results of these studies and suggest methodologies to (1) monitor regional trends in nitrate concentration in undisturbed 1st order watersheds and (2) reduce nitrate loads in streams draining agricultural watersheds. Our review reveals that undisturbed headwater watersheds have been shown to be very retentive of nitrogen, but the importance of biogeochemical and hydrological riparian zone processes in retaining nitrogen in these watersheds has not been demonstrated as it has for agricultural watersheds. An understanding of the role of the riparian zone in nitrate attenuation in undisturbed watersheds is crucial because these watersheds are increasingly subject to stressors, such as changes in land use and climate, wildfire, and increases in atmospheric nitrogen deposition. In general, understanding processes controlling the concentration and flux of nitrate is critical to identifying and mapping the vulnerability of watersheds to water quality changes due to a variety of stressors. In undisturbed and agricultural watersheds we propose that understanding the importance of riparian zone processes in 2nd order and larger watersheds is critical. Research is needed that addresses the relative importance of how the following sources of nitrate along any given stream reach might change as watersheds increase in size and with flow: (1) inputs upstream from the reach, (2) tributary inflow, (3) water derived from the riparian zone, (4) groundwater from outside the riparian zone (intermediate or regional sources), and (5) in-stream (hyporheic) processes.

  7. Stream structure at low flow: biogeochemical patterns in intermittent streams over space and time

    NASA Astrophysics Data System (ADS)

    MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

    2017-12-01

    Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry during a dry (2016) and a wet (2017) water year in southwest Idaho. We hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production, and that the heterogeneity of constituents within each stream would increase. We expected these patterns to differ in a high water year compared to a low water year due to algae scour. Finally, we expected that the spatial heterogeneity of biogeochemistry would decrease with time following fire. To test these hypotheses, in 2016 we collected surface water samples at 50 meter intervals from two intermittent headwater streams over 2,500 meter reaches in April, May, and June. One stream is burned and one remains unburned. In 2017, we collected surface water at the 50, 25 and 10 meter intervals from each stream once during low flow. 2016 results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. Between wet and dry water years, we observed a decrease in the spatial heterogeneity as measured by the standard deviation (SD) in conductivity at 50 meter intervals; the burned stream had a SD of 23.08 in 2016 and 11.40 in 2017 whereas the unburned stream had similar SDs. We conclude that the burned stream experienced more inter and intra-annual surface water change in chemistry patterns than did the unburned stream.

  8. Experimental design for estimating parameters of rate-limited mass transfer: Analysis of stream tracer studies

    USGS Publications Warehouse

    Wagner, Brian J.; Harvey, Judson W.

    1997-01-01

    Tracer experiments are valuable tools for analyzing the transport characteristics of streams and their interactions with shallow groundwater. The focus of this work is the design of tracer studies in high-gradient stream systems subject to advection, dispersion, groundwater inflow, and exchange between the active channel and zones in surface or subsurface water where flow is stagnant or slow moving. We present a methodology for (1) evaluating and comparing alternative stream tracer experiment designs and (2) identifying those combinations of stream transport properties that pose limitations to parameter estimation and therefore a challenge to tracer test design. The methodology uses the concept of global parameter uncertainty analysis, which couples solute transport simulation with parameter uncertainty analysis in a Monte Carlo framework. Two general conclusions resulted from this work. First, the solute injection and sampling strategy has an important effect on the reliability of transport parameter estimates. We found that constant injection with sampling through concentration rise, plateau, and fall provided considerably more reliable parameter estimates than a pulse injection across the spectrum of transport scenarios likely encountered in high-gradient streams. Second, for a given tracer test design, the uncertainties in mass transfer and storage-zone parameter estimates are strongly dependent on the experimental Damkohler number, DaI, which is a dimensionless combination of the rates of exchange between the stream and storage zones, the stream-water velocity, and the stream reach length of the experiment. Parameter uncertainties are lowest at DaI values on the order of 1.0. When DaI values are much less than 1.0 (owing to high velocity, long exchange timescale, and/or short reach length), parameter uncertainties are high because only a small amount of tracer interacts with storage zones in the reach. For the opposite conditions (DaI ≫ 1.0), solute exchange rates are fast relative to stream-water velocity and all solute is exchanged with the storage zone over the experimental reach. As DaI increases, tracer dispersion caused by hyporheic exchange eventually reaches an equilibrium condition and storage-zone exchange parameters become essentially nonidentifiable.

  9. Gill lesions and death of bluegill in an acid mine drainage mixing zone

    USGS Publications Warehouse

    Henry, T.B.; Irwin, E.R.; Grizzle, J.M.; Brumbaugh, W.G.; Wildhaber, M.L.

    2001-01-01

    The toxicity of an acid mine drainage (AMD) mixing zone was investigated by placing bluegill (Lepomis macrochirus) at the confluence of a stream contaminated by AMD and a stream having neutral pH. A mixing channel receiving water from both streams was assembled in the field, during July and October 1996, to determine the toxicity of freshly mixed and aged water (2.9–7.5 min). The AMD stream had elevated concentrations of Al and Fe, which precipitated upon mixing, and of Mn, which did not precipitate in the mixing zone. Fish exposed to freshly mixed water had higher mortality than fish exposed to water after aging. Precipitating Al, but not Fe, accumulated on the gills of bluegill, and accumulation was more rapid early during the mixing process than after aging. Fish exposed for 3.5 h to freshly mixed water had hypertrophy and hyperplasia of gill filament and lamellar epithelial cells. Similar lesions were observed after 6.0 h in fish exposed to water aged after mixing. Results demonstrated that Al was the predominant metal accumulating on the gills of fish in this AMD mixing zone, and that mixing zones can be more toxic than AMD streams in equilibrium.

  10. Method of aeration disinfecting and drying grain in bulk and pretreating seeds and a transverse blow silo grain dryer therefor

    DOEpatents

    Danchenko, Vitaliy G [Dnipropetrovsk, UA; Noyes, Ronald T [Stillwater, OK; Potapovych, Larysa P [Dnipropetrovsk, UA

    2012-02-28

    Aeration drying and disinfecting grain crops in bulk and pretreating seeds includes passing through a bulk of grain crops and seeds disinfecting and drying agents including an ozone and air mixture and surrounding air, subdividing the disinfecting and drying agents into a plurality of streams spaced from one another in a vertical direction, and passing the streams at different heights through levels located at corresponding heights of the bulk of grain crops and seeds transversely in a substantially horizontal direction.

  11. The Critical Zone: A Necessary Framework for Understanding Surface Earth Processes

    NASA Astrophysics Data System (ADS)

    Dietrich, W. E.

    2016-12-01

    One definition of the critical zone is: the thin veneer of Earth that extends from the top of the vegetation to the base of weathered bedrock. With this definition we can envision the critical zone as a distinct entity with a well-defined top and a fairly well-defined bottom that is distributed across terrestrial earth landscapes. It is a zone of co-evolving processes and, importantly, much of this zone is well below the soil mantle (and commonly more than 10 times thicker than the soil). Weathering advance into fresh bedrock creates a hydrologically-conductive skin that mediates runoff and solute chemistry, stores water used by vegetation, releases water as baseflow to streams, influences soil production and hillslope evolution, and feeds gasses to the atmosphere. Especially in seasonally dry environments, rock moisture in the critical zone, i.e. moisture that is exchangeable and potentially mobile in the matrix and fractures of the bedrock, can be a significant source of water to plants and is a previously unrecognized large component of the water budget that matters to climate models. First observations on the systematic variation of the critical zone across hillslopes have led to four distinct theories representing four distinct processes for what controls the depth to fresh bedrock (and thus the thickness of this zone across a hillslope). These theories are motivating geophysical surveys, deep drilling, and other actions to parameterize and explore the power of these models. Studies at the NSF-supported Critical Zone Observatories have taught us that the critical zone is an entity and that enduring field studies reveal key processes. A challenge we now face is how to include this emerging understanding of the critical zone into models of reactive transport, hydrologic processes and water supply, critical zone structure, landscape evolution, and climate.

  12. Methods and apparatuses for cutting, abrading, and drilling

    DOEpatents

    Bingham, Dennis N.; Swainston, Richard C.; Palmer, Gary L.; Ferguson, Russell L.

    2001-01-01

    Methods and apparatuses for treating a surface of a work piece are described. In one implementation, a laser delivery subsystem is configured to direct a laser beam toward a treatment zone on a work surface. A cryogenic material delivery subsystem is operably coupled with the laser delivery subsystem and is configured to direct a stream comprising cryogenic material toward the treatment zone. Both the laser beam and stream cooperate to treat material of the work surface within the treatment zone. In one aspect, a nozzle assembly provides the laser beam and stream of cryogenic material along a common flow axis. In another aspect, the laser beam and stream are provided along different axes.

  13. The trout fishery in Shenandoah National Park

    USGS Publications Warehouse

    Lennon, Robert E.

    1961-01-01

    Populations of brook trout in streams of Shenandoah National Park were reduced drastically early in the past decade by a succession of unusually severe droughts and floods. The drying of stream beds, predation, and scouring were principal factors in the loss of fish. The park was closed to fishing in 1954 and 1955 to protect survivors. The small numbers of survivors quickly repopulated the streams after drought conditions abated. The stocking of hatchery-reared fingerling trout in selected waters failed to augment the recovery of populations. Survival and growth of young, wild trout were especially good. Their redistribution through miles of previously dry streams was rapid. The park was opened again to fishing in 1956 under regulations which restrict the take but afford an increase in sporting opportunity. Two streams were placed under fishing-for-fun-only regulations in 1961.The welfare of the trout populations is dependent mostly on the weather cycle . Fish may be abundant in wet years but very scarc e in dry ones. Thus, the stream must be managed a s marginal for trout.

  14. Stream and riparian management for freshwater turtles.

    PubMed

    Bodie, J R

    2001-08-01

    The regulation and management of stream ecosystems worldwide have led to irreversible loss of wildlife species. Due to recent scrutiny of water policy and dam feasibility, there is an urgent need for fundamental research on the biotic integrity of streams and riparian zones. Although riverine turtles rely on stream and riparian zones to complete their life cycle, are vital producers and consumers, and are declining worldwide, they have received relatively little attention. I review the literature on the impacts of contemporary stream management on freshwater turtles. Specifically, I summarize and discuss 10 distinct practices that produce five potential biological repercussions. I then focus on the often-overlooked use of riparian zones by freshwater turtles, calculate a biologically determined riparian width, and offer recommendations for ecosystem management. Migration data were summarized on 10 species from eight US states and four countries. A riparian zone encompassing the majority of freshwater turtle migrations would need to span 150 m from the stream edge. Freshwater turtles primarily chose high, open sandy habitats to nest. Nests in North America contained eggs and hatchlings during April through September and often through the winter. In addition, freshwater turtles utilized diverse riparian habitats for feeding, nesting, and overwintering. Additional documentation of stream and riparian habitat use by turtles is needed.

  15. Concentration-discharge relationships in headwater streams of the Sierra Nevada, California

    NASA Astrophysics Data System (ADS)

    Hunsaker, Carolyn T.; Johnson, Dale W.

    2017-09-01

    We examined stream water concentration-discharge relationships for eight small, forest watersheds ranging in elevation from 1485 to 2465 m in the southern Sierra Nevada. These headwater streams revealed nearly chemostatic behavior by current definitions for K+, Ca2+, Mg2+, Na+, Cl-, and SO42- in most cases but not for NH4+, NO3-, or ortho-P. The latter ions were somewhat enriched during high flows. All ions studied showed a dilution process at lower flows (<50 L s-1) with the concentration-discharge relationship being more chemostatic at higher flows. While previous studies in the Sierra Nevada have reported peak concentrations of NH4+, NO3-, and SO42- during snowmelt, the headwater systems of the Kings River Experimental Watersheds experience peak concentrations of these ions during the fall rains after the dry summer. These forested watersheds span the rain-snow transition zone, are 49-228 ha in size, and have soils derived from granite. A statistically significant relationship between soils and stream water concentrations for ortho-P, Ca2+, and Na+ strongly suggests that soil chemistry has a major influence on stream water chemistry. Factors controlling stream water NH4+, NO3-, and SO42- concentrations are less clear, but one possible source of spikes in these ions during storm events is input from O-horizon runoff where high concentrations were measured. Overall, stream water concentration-discharge relationships for these Sierran watersheds are similar to those found in other watershed systems (nearly chemostatic); however, the dominant processes controlling these relationships are probably localized because of different watershed characteristics like soil chemistry, vegetation cover, hydrologic flow paths, and weather patterns.

  16. BET surface area distributions in polar stream sediments: Implications for silicate weathering in a cold-arid environment

    USGS Publications Warehouse

    Marra, Kristen R.; Elwood Madden, Megan E; Soreghan, Gerilyn S.; Hall, Brenda L

    2014-01-01

    BET surface area values are critical for quantifying the amount of potentially reactive sediments available for chemical weathering and ultimately, prediction of silicate weathering fluxes. BET surface area values of fine-grained (<62.5 μm) sediment from the hyporheic zone of polar glacial streams in the McMurdo Dry Valleys, Antarctica (Wright and Taylor Valleys) exhibit a wide range (2.5–70.6 m2/g) of surface area values. Samples from one (Delta Stream, Taylor Valley) of the four sampled stream transects exhibit high values (up to 70.6 m2/g), which greatly exceed surface area values from three temperate proglacial streams (0.3–12.1 m2/g). Only Clark stream in Wright Valley exhibits a robust trend with distance, wherein surface area systematically decreases (and particle size increases) in the mud fraction downstream, interpreted to reflect rapid dissolution processes in the weathering environment. The remaining transects exhibit a range in variability in surface area distributions along the length of the channel, likely related to variations in eolian input to exposed channel beds, adjacent snow drifts, and to glacier surfaces, where dust is trapped and subsequently liberated during summer melting. Additionally, variations in stream discharge rate, which mobilizes sediment in pulses and influences water:rock ratios, the origin and nature of the underlying drift material, and the contribution of organic acids may play significant roles in the production and mobilization of high-surface area sediment. This study highlights the presence of sediments with high surface area in cold-based glacier systems, which influences models of chemical denudation rates and the impact of glacial systems on the global carbon cycle.

  17. Method for production of magnesium

    DOEpatents

    Diaz, Alexander F.; Howard, Jack B.; Modestino, Anthony J.; Peters, William A.

    1998-01-01

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400.degree. C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products.

  18. Method for production of magnesium

    DOEpatents

    Diaz, A.F.; Howard, J.B.; Modestino, A.J.; Peters, W.A.

    1998-07-21

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400 C or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products. 12 figs.

  19. Macroinvertebrate assemblage recovery following a catastrophic flood and debris flows in an Appalachian mountain stream

    USGS Publications Warehouse

    Snyder, C.D.; Johnson, Z.B.

    2006-01-01

    In June 1995, heavy rains caused severe flooding and massive debris flows on the Staunton River, a 3rd-order stream in the Blue Ridge Mountains (Virginia, USA). Scouring caused the loss of the riparian zone and repositioned the stream channel of the lower 2.1 km of the stream. Between 1998 and 2001, we conducted seasonal macroinvertebrate surveys at sites on the Staunton River and on White Oak Canyon Run, a reference stream of similar size and geology that was relatively unaffected by the flood. Our study was designed to determine the extent to which flood-induced changes to the stream channel and riparian habitats caused long-term changes to macroinvertebrate community structure and composition. Sites within the impacted zone of the Staunton River supported diverse stable benthic macroinvertebrate assemblages 3 y after the flood despite dramatic and persistent changes in environmental factors known to be important controls on stream ecosystem function. However, significant differences in total macroinvertebrate density and trophic structure could be attributed to the flood. In autumn, densities of most feeding guilds, including shredders, were higher at impacted-zone sites than at all other sites, suggesting higher overall productivity in the impacted zone. Higher shredder density in the impacted zone was surprising in light of expected decreases in leaf-litter inputs because of removal of riparian forests. In contrast, in spring, we observed density differences in only one feeding guild, scrapers, which showed higher densities at impacted-zone sites than at all other sites. This result conformed to a priori expectations that reduced shading in the impacted zone would lead to increased light and higher instream primary production. We attribute the seasonal differences in trophic structure to the effects of increased temperatures on food quality and to the relationship between the timing of our sampling and the emergence patterns of important taxa. ?? 2006 by The North American Benthological Society.

  20. Oyster resource zones of the Barataria and Terrebonne estuaries of Louisiana

    USGS Publications Warehouse

    Melancon, E.; Soniat, T.; Cheramie, V.; Dugas, R.; Barras, J.; Lagarde, M.

    1998-01-01

    A 1:100,000 scale map delineating the subtidal oyster resource zones within the Barataria and Terrebonne estuaries was developed. Strategies to accomplish the task included interviews with Louisiana oystermen and state biologists to develop a draft map, field sampling to document oyster (Crassostrea virginica), Dermo (Perkinsus marinus), and oyster drill (Stramonita haemastoma) abundances, use of historical salinity data to aid in map verification, and public meetings to allow comment on a draft before final map preparation. Four oyster resource zones were delineated on the final map: a dry zone where subtidal oysters may be found when salinities increase, a wet zone where subtidal oysters may be found when salinities are suppressed, a wet-dry zone where subtidal oysters may be consistently found due to favorable salinities, and a high-salinity zone where natural oyster populations are predominantly found in intertidal and shallow waters. The dry zone is largely coincident with the brackish-marsh habitat, with some intermediate-type marsh. The wet-dry zone is found at the interface of the brackish and saline marshes, but extends further seaward than up-estuary. The wet zone and the high salinity zones are areas of mostly open water fringed by salt marshes. The dry zone encompasses 91,775 hectares, of which 48,788 hectares are water (53%). The wet zone encompasses 83,525 hectares, of which 66,958 hectares are water (80%). The wet-dry zone encompasses 171,893 hectares, of which 104,733 hectares are water (61%). The high salinity zone encompasses 125,705 hectares, of which 113,369 hectares are water (90%). There is a clear trend of increasing water habitat in the four zones over the past 30 years, and oysters are now cultivated on bottoms that were once marsh. The map should be useful in managing the effects upon oysters of freshwater diversions into the estuaries. It provides a pre-diversion record of the location of oyster resource zones and should prove helpful in the seaward relocation of oysters leases.

  1. Activities and Ecological Role of Adult Aquatic Insects in the Riparian Zone of Streams

    Treesearch

    John K. Jackson; Vincent H. Resh

    1989-01-01

    Most adult aquatic insects that emerge from streams live briefly in the nearby riparian zone. Adult activities, such as mating, dispersal, and feeding, influence their distribution in the terrestrial habitat. A study at Big Sulphur Creek, California, has shown that both numbers and biomass of adult aquatic insects are greatest in the near-stream vegetation; however,...

  2. Hydrogenation apparatus

    DOEpatents

    Friedman, Joseph [Encino, CA; Oberg, Carl L [Canoga Park, CA; Russell, Larry H [Agoura, CA

    1981-01-01

    Hydrogenation reaction apparatus comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1100.degree. to 1900.degree. C., while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products.

  3. Hydrogenation apparatus

    DOEpatents

    Friedman, J.; Oberg, C. L.; Russell, L. H.

    1981-06-23

    Hydrogenation reaction apparatus is described comprising a housing having walls which define a reaction zone and conduits for introducing streams of hydrogen and oxygen into the reaction zone, the oxygen being introduced into a central portion of the hydrogen stream to maintain a boundary layer of hydrogen along the walls of the reaction zone. A portion of the hydrogen and all of the oxygen react to produce a heated gas stream having a temperature within the range of from 1,100 to 1,900 C, while the boundary layer of hydrogen maintains the wall temperature at a substantially lower temperature. The heated gas stream is introduced into a hydrogenation reaction zone and provides the source of heat and hydrogen for a hydrogenation reaction. There also is provided means for quenching the products of the hydrogenation reaction. The present invention is particularly suitable for the hydrogenation of low-value solid carbonaceous materials to provide high yields of more valuable liquid and gaseous products. 2 figs.

  4. Modelling the fate of six common pharmaceuticals in a small stream: quantification of attenuation and retention in different stream-specific environments

    NASA Astrophysics Data System (ADS)

    Riml, Joakim; Wörman, Anders; Kunkel, Uwe; Radke, Michael

    2013-04-01

    Detection of pharmaceutical residues in streaming waters is common in urbanized areas. Although the occurrence and source of these micropollutants is known, their behavior in these aquatic ecosystems is still only partly understood. Specifically, quantitative information of biogeochemical processes in stream-specific environments where predominant reactions occur is often missing. In an attempt to address this knowledge gap, we performed simultaneous tracer tests in Säva Brook, Sweden, with bezafibrate, clofibric acid, diclofenac, ibuprofen, metoprolol and naproxen, as well as with the more inert solutes uranine and Rhodamine WT. The breakthrough curves at five successive sampling stations along a 16 km long stream reach were evaluated using a coupled physical-biogeochemical model framework containing surface water transport together with a representation of transient storage in slow/immobile zones of the stream. The multi-tracer experiment opens for decoupling of hydrological and biogeochemical contribution to the fate, and by linking impact and sensitivity analyses to relative significance of model parameters the most important processes for each contaminant were elucidated. Specifically for Säva Brook, the proposed methodology revealed that the pharmaceutical-contaminated stream water remained in the storage zones for times corresponding to 5-25% of the flow time of the stream. Furthermore, the results indicate a great variability in terms of predominant biogeochemical processes between the different contaminants. Rapid reactions occurring in the transient storage zone attenuated both ibuprofen and clofibric acid, and we conclude that a major degradation pathway for these contaminants was biodegradation in the hyporheic zone. In contrast, bezafibrate, metoprolol, and naproxen were mainly affected by sorption both in the storage zone and the main channel, while diclofenac displayed negligible effects of biogeochemical reactions.

  5. [Characteristics and Transport Patterns of Ammonia, Nitrites, Nitrates and Inorganic Nitrogen Flux at Epikarst Springs and a Subterranean Stream in Nanshan, Chongqing].

    PubMed

    Zhang, Yuan-zhu; He, Qiu-fang; Jiang, Yong-jun; Li, Yong

    2016-04-15

    In a karst groundwater system, it develops complex multiple flows because of its special geological structure and unique physical patterns of aquifers. In order to investigate the characteristics and transport patterns of ammonia, nitrite and nitrate in epikarst water and subterranean stream, the water samples were collected monthly in a fast-urbanizing karst region. The results showed distinctive characteristics of three forms of inorganic nitrogen. The concentration of inorganic nitrogen was stable in the epikarst water while it was fluctuant in the subterranean stream. Epikarst water was less affected by rainfall and sewage compared with subterranean stream. In epikarst water, the nitrate concentration was much higher than the ammonia concentration. Dissolved inorganic nitrogen, mainly from non-point source pollution related to agricultural activities, passed in and out of the epikarst water based on a series of physical; chemical and biological processes in the epikarst zone, such as ammonification, adsorption and nitrification. On the contrary, subterranean stream showed a result of NH₄⁺-N > NO₃⁻-N in dry seasons and NO₃⁻-N > NH₄⁺-N in rainy seasons. This can be due to the fact that sanitary and industrial sewage flowed into subterranean river through sinkholes, fissures and grikes in dry season. Dissolved inorganic nitrogen in subterranean river was mainly from the non-point source pollution in wet season. Non-point source pollutants entered into subterranean water by two transport ways, one by penetration along with vadose flow through fissures and grikes, and the other by conduit flow through sinkholes from the surface runoff, soil water flow and epikarst flow. The export flux of DIN was 56.05 kg · (hm² · a)⁻¹, and NH₄⁺-N and NO₃⁻-N accounted for 46.03% and 52.51%, respectively. The contributions of point-source pollution and non point-source pollution to the export flux of DIN were 25.08% and 74.92%, respectively, based on run-off division method.

  6. Flue gas desulfurization method and apparatus

    DOEpatents

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  7. Flue gas desulfurization method and apparatus

    DOEpatents

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  8. Dry season mean monthly flow and harmonic mean flow regression equations for selected ungaged basins in Arkansas

    USGS Publications Warehouse

    Breaker, Brian K.

    2015-01-01

    Equations for two regions were found to be statistically significant for developing regression equations for estimating harmonic mean flows at ungaged basins; thus, equations are applicable only to streams in those respective regions in Arkansas. Regression equations for dry season mean monthly flows are applicable only to streams located throughout Arkansas. All regression equations are applicable only to unaltered streams where flows were not significantly affected by regulation, diversion, or urbanization. The median number of years used for dry season mean monthly flow calculation was 43, and the median number of years used for harmonic mean flow calculations was 34 for region 1 and 43 for region 2.

  9. Effects of pasture management and off-stream water on temporal/spatial distribution of cattle and stream bank characteristics in cool-season grass pastures.

    PubMed

    Schwarte, K A; Russell, J R; Morrical, D G

    2011-10-01

    A 2-yr grazing experiment was conducted to assess the effects of grazing management on cattle distribution and pasture and stream bank characteristics. Six 12.1-ha cool-season grass pastures in central Iowa were allotted to 1 of 3 treatments: continuous stocking with unrestricted stream access (CSU), continuous stocking with stream access restricted to 4.9-m-wide stabilized crossings (CSR), or rotational stocking with stream access restricted to a riparian paddock (RP). Pastures were stocked with 15 fall-calving Angus cows (Bos taurus L.) from mid-May to mid-October for 153 d in 2008 and 2009. A global positioning system (GPS) collar recording cow position every 10 min was placed on at least 1 cow per pasture for 2 wk of each month from May through September. Off-stream water was provided to cattle in CSU and CSR treatments during the second of the 2 wk when GPS collars were on the cattle. A black globe temperature relative humidity index (BGTHI) was measured at 10-min intervals to match the time of the GPS measurements. Each month of the grazing season, forage characteristics (sward height, forage mass, and CP, IVDMD, and P concentrations) and bare and fecal-covered ground were measured. Stream bank erosion susceptibility was visually scored in May, August, and October (pre-, mid-, and post-stocking). Cattle in RP and CSR treatments spent less time (P < 0.10) within the stream zone (0 to 3 m from stream center) in June and August and in the streamside zone (0 to 33 m from stream zone) in May through August and May through September, respectively, than cattle in CSU pastures. However, off-stream water had no effect on cattle distribution. Compared with the CSU treatment, the CSR treatment reduced the probability (P < 0.10) that cattle were within the riparian zone (0 to 36 m from stream center) at BGTHI of 50 to 100. Bare ground was greater (P < 0.10) in pastures with the CSU than CSR and RP treatments in the stream and streamside zones in September and October and in July and September. Streams in pastures with the CSU treatment had less stable banks (P < 0.10) mid- and post-stocking than RP or CSR treatments. Results show that time spent by cattle near pasture streams can be reduced by RP or CSR treatments, thereby decreasing risks of sediment and nutrient loading of pasture streams even during periods of increased BGTHI.

  10. Structure and Function of Ephemeral Streams in the Arid and Semiarid Southwest: Implications for Conservation and Management

    DTIC Science & Technology

    2015-07-24

    stream flow, trade-offs were apparent between riparian plant biomass (high at wetter sites) and plant species diversity (high at dry sites with...iv) between wet and dry seasons? Technical Approach. A space-for-time substitution approach was followed in which changes across spatial water...For arthropods, pitfall traps were set during dry and wet seasons in channel, riparian and upland locations in canyon and piedmont reaches to

  11. Characterization of return flow pathways during flood irrigation

    NASA Astrophysics Data System (ADS)

    Claes, N.; Paige, G. B.; Parsekian, A.; Gordon, B. L.; Miller, S. N.

    2015-12-01

    With a decline in water resources available for private consumption and irrigation, the importance of sustainable water management practices is increasing. Local management decisions, based on models may affect the availability of water both locally and downstream, causing a ripple effect. It is therefore important that the models that these local management decisions are based on, accurately quantify local hydrological processes and the timescales at which they happen. We are focusing on return flow from flood irrigation, which can occur via different pathways back to the streams: overland flow, near-surface return flow and return flow via pathways below the vadose zone. The question addressed is how these different pathways each contribute to the total amount of return flow and the dynamics behind them. We used time-lapse ERT measurements in combination with an ensemble of ERT and seismic lines to answer this question via (1) capturing the process of gradual fragmentation of aqueous environments in the vadose zone during drying stages at field scale; (2) characterization of the formation of preferential flow paths from infiltrating wetting fronts during wetting cycles at field scale. The time-lapse ERT provides the possibility to capture the dynamic processes involved during the occurrence of finger flow or macro-pores when an intensive wetting period during flood irrigation occurs. It elucidates the dynamics of retention in the vadose zone during drying and wetting periods at field scale. This method provides thereby a link to upscale from laboratory experiments to field scale and watershed scale for finger flow and preferential flow paths and illustrates the hysteresis behavior at field scale.

  12. Delineating baseflow contribution areas for streams - A model and methods comparison

    NASA Astrophysics Data System (ADS)

    Chow, Reynold; Frind, Michael E.; Frind, Emil O.; Jones, Jon P.; Sousa, Marcelo R.; Rudolph, David L.; Molson, John W.; Nowak, Wolfgang

    2016-12-01

    This study addresses the delineation of areas that contribute baseflow to a stream reach, also known as stream capture zones. Such areas can be delineated using standard well capture zone delineation methods, with three important differences: (1) natural gradients are smaller compared to those produced by supply wells and are therefore subject to greater numerical errors, (2) stream discharge varies seasonally, and (3) stream discharge varies spatially. This study focuses on model-related uncertainties due to model characteristics, discretization schemes, delineation methods, and particle tracking algorithms. The methodology is applied to the Alder Creek watershed in southwestern Ontario. Four different model codes are compared: HydroGeoSphere, WATFLOW, MODFLOW, and FEFLOW. In addition, two delineation methods are compared: reverse particle tracking and reverse transport, where the latter considers local-scale parameter uncertainty by using a macrodispersion term to produce a capture probability plume. The results from this study indicate that different models can calibrate acceptably well to the same data and produce very similar distributions of hydraulic head, but can produce different capture zones. The stream capture zone is found to be highly sensitive to the particle tracking algorithm. It was also found that particle tracking by itself, if applied to complex systems such as the Alder Creek watershed, would require considerable subjective judgement in the delineation of stream capture zones. Reverse transport is an alternative and more reliable approach that provides probability intervals for the baseflow contribution areas, taking uncertainty into account. The two approaches can be used together to enhance the confidence in the final outcome.

  13. A perspective on stream-catchment connections

    USGS Publications Warehouse

    Bencala, Kenneth E.

    1993-01-01

    Ecological study of the hyporheic zone is leading to recognition of a need for additional hydrologic understanding. Some of this understanding can be obtained by viewing the hyporheic zone as a succession of isolated boxes adjacent to the stream. Further understanding, particularly relevant to catchment-scale ecology, may come from studies focussed on the fluid mechanics of the flow-path connections between streams and their catchments.

  14. Flat Branch monitoring project: stream water temperature and sediment responses to forest cutting in the riparian zone

    Treesearch

    Barton D. Clinton; James M. Vose; Dick L. Fowler

    2010-01-01

    Stream water protection during timber-harvesting activities is of primary interest to forest managers. In this study, we examine the potential impacts of riparian zone tree cutting on water temperature and total suspended solids. We monitored stream water temperature and total suspended solids before and after timber harvesting along a second-order tributary of the...

  15. Hyporheic zone influences on concentration-discharge relationships in a headwater sandstone stream

    NASA Astrophysics Data System (ADS)

    Hoagland, Beth; Russo, Tess A.; Gu, Xin; Hill, Lillian; Kaye, Jason; Forsythe, Brandon; Brantley, Susan L.

    2017-06-01

    Complex subsurface flow dynamics impact the storage, routing, and transport of water and solutes to streams in headwater catchments. Many of these hydrogeologic processes are indirectly reflected in observations of stream chemistry responses to rain events, also known as concentration-discharge (CQ) relations. Identifying the relative importance of subsurface flows to stream CQ relationships is often challenging in headwater environments due to spatial and temporal variability. Therefore, this study combines a diverse set of methods, including tracer injection tests, cation exchange experiments, geochemical analyses, and numerical modeling, to map groundwater-surface water interactions along a first-order, sandstone stream (Garner Run) in the Appalachian Mountains of central Pennsylvania. The primary flow paths to the stream include preferential flow through the unsaturated zone ("interflow"), flow discharging from a spring, and groundwater discharge. Garner Run stream inherits geochemical signatures from geochemical reactions occurring along each of these flow paths. In addition to end-member mixing effects on CQ, we find that the exchange of solutes, nutrients, and water between the hyporheic zone and the main stream channel is a relevant control on the chemistry of Garner Run. CQ relationships for Garner Run were compared to prior results from a nearby headwater catchment overlying shale bedrock (Shale Hills). At the sandstone site, solutes associated with organo-mineral associations in the hyporheic zone influence CQ, while CQ trends in the shale catchment are affected by preferential flow through hillslope swales. The difference in CQ trends document how the lithology and catchment hydrology control CQ relationships.

  16. Soil Microbial Community Contribution to Small Headwater Stream Metabolism.

    NASA Astrophysics Data System (ADS)

    Clapcott, J. E.; Gooderham, J. P.; Barmuta, L. A.; Davies, P. E.

    2005-05-01

    The temporal dynamics of sediment respiration were examined in seven small headwater streams in forested catchments in 2004. A strong seasonal response was observed with higher respiration rates in depositional zones than in gravel runs. The data were also examined in the context of proportional habitat distributions that highlighted the importance of high flow events in shaping whole stream metabolic budgets. This study specifically examines the question of terrestrial soil respiration contribution to whole stream metabolism by the controlled inundation of terrestrial soils. The experiment included six experimentally inundated terrestrial zones, six terrestrial controls, and six in-stream depositional zones. Sediment bacterial respiration was measured using 14C leucine incorporation and cotton strip bioassays were also employed to provide an indicative measure of sediment microbial activity. Despite high variability and exhibiting significantly lower bacterial activity than in-stream sediments, modelling using flow data and habitat mapping illustrated the important contribution of terrestrial soil respiration to the whole stream metabolic budgets of small headwater streams. In addition, microbial community composition examined using phospholipid fatty acid analysis clearly differentiated between terrestrial and aquatic communities. Freshly inundated terrestrial communities remained similar to un-inundated controls after 28 days.

  17. Spatial and temporal variation of denitrification in the riparian zone during the hydrological year

    NASA Astrophysics Data System (ADS)

    Trauth, Nico; Musolff, Andreas; Knöller, Kay; Fleckenstein, Jan H.

    2017-04-01

    In the riparian zone, where stream water mixes with groundwater, biogeochemical reactions and solute transformations occur which may enhance the self-cleaning mechanisms of aquatic ecosystems. The water exchange and solute transport through the riparian zone is controlled by hydraulic gradients between stream and groundwater and thus varies seasonally and during stream discharge events. In this study, we focus on transport, mixing and the distribution of nitrate in the riparian zone of a gravelly alluvial aquifer with the aim to quantify its denitrification potential during the hydrological year. For this purpose, 25 groundwater wells were drilled along a 2 km stream section of the Selke river, a third-order stream in Germany. From the stream and the wells, water samples were taken 4-weekly over a period of 2 years. Water samples were analyzed to field parameters, major ions, dissolved organic carbon, and N-O isotopes. Results show a strong influence of the stream on the adjacent groundwater, which varies both in time and space. In general, we can distinguish between two endmembers: a) the stream water with low chloride (<30 mg/L) and nitrate (<10 mg/L) concentrations and b) the groundwater in 100m distance to the stream with high chloride (>70 mg/L) and nitrate (>50 mg/L) concentrations. Based on conservatively transported chloride, the mixing of the endmembers can be determined in the riparian zone. Deviations in nitrate concentrations from this mixing model may indicate nitrate degradation by e.g. denitrification. By combining this chloride-nitrate-ratio method with dissolved oxygen data and the isotopic signature of the nitrate molecule, we are able to determine the timing and the location of high denitrification patterns in the riparian aquifer. Highest variability of denitrification occurs over the year in terms of seasonality (temperature-driven) and is temporally fueled by additional organic carbon supply during discharge events.

  18. Primary weathering rates, water transit times and concentration-discharge relations: A theoretical analysis for the critical zone

    NASA Astrophysics Data System (ADS)

    Ameli, Ali; Erlandsson, Martin; Beven, Keith; Creed, Irena; McDonnell, Jeffrey; Bishop, Kevin

    2017-04-01

    The permeability architecture of the critical zone exerts a major influence on the hydrogeochemistry of the critical zone. Water flowpath dynamics drive the spatio-temporal pattern of geochemical evolution and resulting streamflow concentration-discharge (C-Q) relation, but these flowpaths are complex and difficult to map quantitatively. Here, we couple a new integrated flow and particle tracking transport model with a general reversible Transition-State-Theory style dissolution rate-law to explore theoretically how C-Q relations and concentration in the critical zone respond to decline in saturated hydraulic conductivity (Ks) with soil depth. We do this for a range of flow rates and mineral reaction kinetics. Our results show that for minerals with a high ratio of equilibrium concentration to intrinsic weathering rate, vertical heterogeneity in Ks enhances the gradient of weathering-derived solute concentration in the critical zone and strengthens the inverse stream C-Q relation. As the ratio of equilibrium concentration to intrinsic weathering rate decreases, the spatial distribution of concentration in the critical zone becomes more uniform for a wide range of flow rates, and stream C-Q relation approaches chemostatic behaviour, regardless of the degree of vertical heterogeneity in Ks. These findings suggest that the transport-controlled mechanisms in the hillslope can lead to chemostatic C-Q relations in the stream while the hillslope surface reaction-controlled mechanisms are associated with an inverse stream C-Q relation. In addition, as the ratio of equilibrium concentration to intrinsic weathering rate decreases, the concentration in the critical zone and stream become less dependent on groundwater age (or transit time)

  19. Primary weathering rates, water transit times, and concentration-discharge relations: A theoretical analysis for the critical zone

    NASA Astrophysics Data System (ADS)

    Ameli, Ali A.; Beven, Keith; Erlandsson, Martin; Creed, Irena F.; McDonnell, Jeffrey J.; Bishop, Kevin

    2017-01-01

    The permeability architecture of the critical zone exerts a major influence on the hydrogeochemistry of the critical zone. Water flow path dynamics drive the spatiotemporal pattern of geochemical evolution and resulting streamflow concentration-discharge (C-Q) relation, but these flow paths are complex and difficult to map quantitatively. Here we couple a new integrated flow and particle tracking transport model with a general reversible Transition State Theory style dissolution rate law to explore theoretically how C-Q relations and concentration in the critical zone respond to decline in saturated hydraulic conductivity (Ks) with soil depth. We do this for a range of flow rates and mineral reaction kinetics. Our results show that for minerals with a high ratio of equilibrium concentration (Ceq) to intrinsic weathering rate (Rmax), vertical heterogeneity in Ks enhances the gradient of weathering-derived solute concentration in the critical zone and strengthens the inverse stream C-Q relation. As CeqRmax decreases, the spatial distribution of concentration in the critical zone becomes more uniform for a wide range of flow rates, and stream C-Q relation approaches chemostatic behavior, regardless of the degree of vertical heterogeneity in Ks. These findings suggest that the transport-controlled mechanisms in the hillslope can lead to chemostatic C-Q relations in the stream while the hillslope surface reaction-controlled mechanisms are associated with an inverse stream C-Q relation. In addition, as CeqRmax decreases, the concentration in the critical zone and stream become less dependent on groundwater age (or transit time).

  20. Modelling the influence of elevation and snow regime on winter stream temperature in the rain-on-snow zone

    NASA Astrophysics Data System (ADS)

    Leach, J.; Moore, D.

    2015-12-01

    Winter stream temperature of coastal mountain catchments influences fish growth and development. Transient snow cover and advection associated with lateral throughflow inputs are dominant controls on stream thermal regimes in these regions. Existing stream temperature models lack the ability to properly simulate these processes. Therefore, we developed and evaluated a conceptual-parametric catchment-scale stream temperature model that includes the role of transient snow cover and lateral advection associated with throughflow. The model provided reasonable estimates of observed stream temperature at three test catchments. We used the model to simulate winter stream temperature for virtual catchments located at different elevations within the rain-on-snow zone. The modelling exercise examined stream temperature response associated with interactions between elevation, snow regime, and changes in air temperature. Modelling results highlight that the sensitivity of winter stream temperature response to changes in climate may be dependent on catchment elevation and landscape position.

  1. Using FIA and GIS Data to Estimate Areas and Volumes of Potential Stream Management Zones and Road Beautifying Buffers

    Treesearch

    Michael Zasada; Chris J. Cieszewski; Roger C. Lowe; Jarek Zawadzki; Mike Clutter; Jacek P. Siry

    2005-01-01

    Georgia Stream Management Zones (SMZ) are voluntary and have an unknown extent and impact. We use FIA data, Landsat TM imagery, and GAP and other GIS data to estimate the acreages and volumes of these buffers. We use stream data classified into trout, perennial, and intermittent, combined with DEM files containing elevation values, to assess buffers with widths...

  2. Leaf-associated fungal diversity in acidified streams: insights from combining traditional and molecular approaches.

    PubMed

    Clivot, Hugues; Cornut, Julien; Chauvet, Eric; Elger, Arnaud; Poupin, Pascal; Guérold, François; Pagnout, Christophe

    2014-07-01

    We combined microscopic and molecular methods to investigate fungal assemblages on alder leaf litter exposed in the benthic and hyporheic zones of five streams across a gradient of increasing acidification for 4 weeks. The results showed that acidification and elevated Al concentrations strongly depressed sporulating aquatic hyphomycetes diversity in both zones of streams, while fungal diversity assessed by denaturing gradient gel electrophoresis (DGGE) appeared unaffected. Clone library analyses revealed that fungal communities on leaves were dominated by members of Ascomycetes and to a lesser extent by Basidiomycetes and Chytridiomycetes. An important contribution of terrestrial fungi was observed in both zones of the most acidified stream and in the hyporheic zone of the reference circumneutral stream. The highest leaf breakdown rate was observed in the circumneutral stream and occurred in the presence of both the highest diversity of sporulating aquatic hyphomycetes and the highest contribution to clone libraries of sequences affiliated with aquatic hyphomycetes. Both methods underline the major role played by aquatic hyphomycetes in leaf decomposition process. Our findings also bring out new highlights on the identity of leaf-associated fungal communities and their responses to anthropogenic alteration of running water ecosystems. © 2013 Society for Applied Microbiology and John Wiley & Sons Ltd.

  3. 40 CFR Figure 1 to Subpart G of... - Definitions of Terms Used in Wastewater Equations

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... wastewater, ppmw. CG=Concentration of TOC (minus methane and ethane) or total organic hazardous air pollutants, in vented gas stream, dry basis, ppmv. CGc=Concentration of TOC or organic hazardous air... flow rate of vented gas stream, dry standard, m3/min. QMG=Mass flowrate of TOC (minus methane and...

  4. The effect of seasonal drying on sulphate dynamics in streams across southeastern Canada and the northeastern USA

    Treesearch

    J.G. Kerr; M.C. Eimers; I.F. Creed; M.B. Adams; F. Beall; D. Burns; J.L. Campbell; S.F. Christopher; T.A. Clair; F. Courchesne; L. Duchesne; I. Fernandez; D. Houle; D.S. Jeffries; G.E. Likens; M.J. Mitchell; J. Shanley; H. Yao

    2012-01-01

    Within the southeast Canada and northeast USA region, a peak in sulphate (SO42-) concentration has been reported for some streams following periods of substantial catchment drying during the summer months (ON, Canada; VT, NH and NY, USA). However, it is currently unclear if a SO42-...

  5. Potential for real-time understanding of coupled hydrologic and biogeochemical processes in stream ecosystems: Future integration of telemetered data with process models for glacial meltwater streams

    NASA Astrophysics Data System (ADS)

    McKnight, Diane M.; Cozzetto, Karen; Cullis, James D. S.; Gooseff, Michael N.; Jaros, Christopher; Koch, Joshua C.; Lyons, W. Berry; Neupauer, Roseanna; Wlostowski, Adam

    2015-08-01

    While continuous monitoring of streamflow and temperature has been common for some time, there is great potential to expand continuous monitoring to include water quality parameters such as nutrients, turbidity, oxygen, and dissolved organic material. In many systems, distinguishing between watershed and stream ecosystem controls can be challenging. The usefulness of such monitoring can be enhanced by the application of quantitative models to interpret observed patterns in real time. Examples are discussed primarily from the glacial meltwater streams of the McMurdo Dry Valleys, Antarctica. Although the Dry Valley landscape is barren of plants, many streams harbor thriving cyanobacterial mats. Whereas a daily cycle of streamflow is controlled by the surface energy balance on the glaciers and the temporal pattern of solar exposure, the daily signal for biogeochemical processes controlling water quality is generated along the stream. These features result in an excellent outdoor laboratory for investigating fundamental ecosystem process and the development and validation of process-based models. As part of the McMurdo Dry Valleys Long-Term Ecological Research project, we have conducted field experiments and developed coupled biogeochemical transport models for the role of hyporheic exchange in controlling weathering reactions, microbial nitrogen cycling, and stream temperature regulation. We have adapted modeling approaches from sediment transport to understand mobilization of stream biomass with increasing flows. These models help to elucidate the role of in-stream processes in systems where watershed processes also contribute to observed patterns, and may serve as a test case for applying real-time stream ecosystem models.

  6. Distribution and accumulation of metals in tadpoles inhabiting the metalliferous streams of eastern Chalkidiki, northeast Greece.

    PubMed

    Kelepertzis, Efstratios; Argyraki, Ariadne; Valakos, Efstratios; Daftsis, Emmanouil

    2012-10-01

    The present study investigates the accumulation of heavy metals [copper (Cu), lead (Pb), zinc (Zn), magnesium (Mn), cadmium (Cd), nickel (Ni), and chromium (Cr)] in tadpoles inhabiting the metalliferous streams flowing within the Asprolakkas River basin (northeast Chalkidiki peninsula, Greece) and the effect of potentially harmful elements in stream water and sediment on the corresponding levels in their tissue. Animals were collected from six sampling sites influenced by a wide range of surface water and stream sediment trace element concentrations. The results of the chemical analyses showed that tadpoles accumulated significant levels of all of the examined metals. The range of whole-body mean measured concentrations were (in dry mass) as follows: Cu (46-182 mg/kg), Pb (103-4,490 mg/kg), Zn (494-11,460 mg/kg), Mn (1,620-13,310 mg/kg), Cd (1.2-82 mg/kg), Ni (57-163 mg/kg), and Cr (38-272 mg/kg). The mean concentrations of Pb, Zn, Mn, Ni, Cr, and Cd in Kokkinolakkas stream, which drains a currently active mining area, were the highest ever reported in tadpoles. Our results indicate that whole-body levels of Pb, Zn, Cu, and Cd increase with stream sediment concentrations and that these organisms tend to accumulate metals bound to Fe and Mn oxides. In addition, high dissolved concentrations and significant concentrations associated with more labile geochemical phases of sediments for specific metals were contributing factors determining whole-body levels. Given the observed bioconcentration factors, as well as the correlation with sediment concentrations, it is proposed that these organisms could be considered as bioindicators of environmental contamination and may be used for monitoring purposes within this metal-rich zone and, perhaps, within other rivers affected by metal mining.

  7. Shifts in the trophic base of intermittent stream food webs

    USGS Publications Warehouse

    Dekar, Matthew P.; Magoulick, Daniel D.; Huxel, G.R.

    2009-01-01

    Understanding spatial and temporal variation in the trophic base of stream food webs is critical for predicting population and community stability, and ecosystem function. We used stable isotope ratios (13C/12C, and 15N/14N) to characterize the trophic base of two streams in the Ozark Mountains of northwest Arkansas, U.S.A. We predicted that autochthonous resources would be more important during the spring and summer and allochthonous resources would be more important in the winter due to increased detritus inputs from the riparian zone during autumn leaf drop. We predicted that stream communities would demonstrate increased reliance on autochthonous resources at sites with larger watersheds and greater canopy openness. The study was conducted at three low-order sites in the Mulberry River Drainage (watershed area range: 81-232 km2) seasonally in 2006 and 2007. We used circular statistics to examine community-wide shifts in isotope space among fish and invertebrate consumers in relation to basal resources, including detritus and periphyton. Mixing models were used to quantify the relative contribution of autochthonous and allochthonous energy sources to individual invertebrate consumers. Significant isotopic shifts occurred but results varied by season and site indicating substantial variation in the trophic base of stream food webs. In terms of temporal variation, consumers shifted toward periphyton in the summer during periods of low discharge, but results varied during the interval between summer and winter. Our results did not demonstrate increased reliance on periphyton with increasing watershed area or canopy openness, and detritus was important at all the sites. In our study, riffle-pool geomorphology likely disrupted the expected spatial pattern and stream drying likely impacted the availability and distribution of basal resources.

  8. Single-droplet evaporation kinetics and particle formation in an acoustic levitator. Part 1: evaporation of water microdroplets assessed using boundary-layer and acoustic levitation theories.

    PubMed

    Schiffter, Heiko; Lee, Geoffrey

    2007-09-01

    The suitability of a single droplet drying acoustic levitator as a model for the spray drying of aqueous, pharmaceutically-relevant solutes used to produce protein-loaded particles has been examined. The acoustic levitator was initially evaluated by measuring the drying rates of droplets of pure water in dependence of drying-air temperature and flow rate. The measured drying rates were higher than those predicted by boundary layer theory because of the effects of primary acoustic streaming. Sherwood numbers of 2.6, 3.6, and 4.4 at drying-air temperatures of 25 degrees C, 40 degrees C, and 60 degrees C were determined, respectively. Acoustic levitation theory could predict the measured drying rates and Sherwood numbers only when a forced-convection drying-air stream was used to neuralize the retarding effect of secondary acoustic streaming on evaporation rate. At still higher drying-air flow rates, the Ranz-Marshall correlation accurately predicts Sherwood number, provided a stable droplet position in the standing acoustic wave is maintained. The measured Sherwood numbers and droplet Reynolds numbers show that experiments performed in the levitator in still air are taking place effectively under conditions of substantial forced convection. The similitude of these values to those occurring in spray dryers is fortuitous for the suitability of the acoustic levitator as a droplet evaporation model for spray drying. (c) 2007 Wiley-Liss, Inc. and the American Pharmacists Association.

  9. Role of monitoring in stream restoration

    EPA Science Inventory

    Hydrology and dissolved organic carbon availability dictate nitrate dynamics in urban streams. So to improve N uptake, restore streams to: • Slow down stream flow • Add organic carbon • Reconnect floodplain hydrology and riparian zones

  10. International Critical Zone Science: Opportunities to Build a Global Understanding of Land-Water Linkages

    NASA Astrophysics Data System (ADS)

    McDowell, W. H.

    2015-12-01

    Critical Zone science examines the structure and properties of the thin veneer that links surface properties to deep geology, at time scales of seconds to millennia. One of the fundamental premises of the US Critical Zone Observatories program is that CZOs should include some measurements made in common at all sites, as these common measurements will enable us to make stronger inferences about how the structure and function of the critical zone interact to drive key processes such as soil formation, stream flow generation, and nutrient export. Recent advances in real-time sensors provide new opportunities to address some fundamental questions about how hillslope soils and streams are linked. Data from the Luquillo Critical Zone Observatory in Puerto Rico, for example, document a previously undescribed transition, or flipping, of stream and soil biogeochemistry in a tropical rain forest. Under typical conditions, soil moisture is high and soil oxygen content is often low, especially at depth. Streams, in contrast, are typically near oxygen saturation. Under severe drought, however, oxygen increases dramatically in soil air and declines to values that are well below saturation in streams. This flipping in redox conditions suggests that despite the strong hydrologic connection between hillslope and stream, gas dynamics and potentially solute dynamics are decoupled along the flow path. The international CZO community has the opportunity to develop a suite of sensor arrays to document soil air, groundwater chemistry, and stream water chemistry. Progress towards realizing the potential of these international networks to develop coherent sensor programs will be addressed based on the current status of sensor deployments in CZO networks in the US, China, and Europe.

  11. Delineating baseflow contribution areas for streams - A model and methods comparison.

    PubMed

    Chow, Reynold; Frind, Michael E; Frind, Emil O; Jones, Jon P; Sousa, Marcelo R; Rudolph, David L; Molson, John W; Nowak, Wolfgang

    2016-12-01

    This study addresses the delineation of areas that contribute baseflow to a stream reach, also known as stream capture zones. Such areas can be delineated using standard well capture zone delineation methods, with three important differences: (1) natural gradients are smaller compared to those produced by supply wells and are therefore subject to greater numerical errors, (2) stream discharge varies seasonally, and (3) stream discharge varies spatially. This study focuses on model-related uncertainties due to model characteristics, discretization schemes, delineation methods, and particle tracking algorithms. The methodology is applied to the Alder Creek watershed in southwestern Ontario. Four different model codes are compared: HydroGeoSphere, WATFLOW, MODFLOW, and FEFLOW. In addition, two delineation methods are compared: reverse particle tracking and reverse transport, where the latter considers local-scale parameter uncertainty by using a macrodispersion term to produce a capture probability plume. The results from this study indicate that different models can calibrate acceptably well to the same data and produce very similar distributions of hydraulic head, but can produce different capture zones. The stream capture zone is found to be highly sensitive to the particle tracking algorithm. It was also found that particle tracking by itself, if applied to complex systems such as the Alder Creek watershed, would require considerable subjective judgement in the delineation of stream capture zones. Reverse transport is an alternative and more reliable approach that provides probability intervals for the baseflow contribution areas, taking uncertainty into account. The two approaches can be used together to enhance the confidence in the final outcome. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

  12. Green Infrastructure Benefits for Communities Managing Nitrate in their Drinking Water Sources

    EPA Science Inventory

    Nitrate in water moving through the “biologically active soil zone” of riparian zones, wetlands and streams may undergo denitrification. Therefore GI techniques such as conservation and restoration of riparian zones, wetlands and streams (daylighting) have the potential to remov...

  13. Environmental geochemistry at Red Mountain, an unmined volcanogenic massive sulphide deposit in the Bonnifield district, Alaska Range, east-central Alaska

    USGS Publications Warehouse

    Eppinger, R.G.; Briggs, P.H.; Dusel-Bacon, C.; Giles, S.A.; Gough, L.P.; Hammarstrom, J.M.; Hubbard, B.E.

    2007-01-01

    The unmined, pyrite-rich Red Mountain (Dry Creek) deposit displays a remarkable environmental footprint of natural acid generation, high metal and exceedingly high rate earth element (REE) concentrations in surface waters. The volcanogenic massive sulphide deposit exhibits well-constrained examples of acid-generating, metal-leaching, metal-precipitation and self-mitigation (via co-precipitation, dilution and neutralization) processes that occur in an undisturbed natural setting, a rare occurrence in North America. Oxidative dissolution of pyrite and associated secondary reactions under near-surface oxidizing conditions are the primary causes for the acid generation and metal leaching. The deposit is hosted in Devonian to Mississippian felsic metavolcanic rocks of the Mystic Creek Member of the Totatlanika Schist. Water samples with the lowest pH (many below 3.5), highest specific conductance (commonly >2500 ??S/cm) and highest major- and trace-element concentrations are from springs and streams within the quartz-sericite-pyrite alteration zone. Aluminum, Cd, Co, Cu, Fe, Mn, Ni, Pb, Y, Zn and, particularly, the REEs are found in high concentrations, ranging across four orders of magnitude. Waters collected upstream from the alteration zone have near-neutral pH, lower specific conductance (370 to 830 ??S/cm), lower metal concentrations and measurable alkalinities. Water samples collected downstream of the alteration zone have pH and metal concentrations intermediate between these two extremes. Stream sediments are anomalous in Zn, Pb, S, Fe, Cu, As, Co, Sb and Cd relative to local and regional background abundances. Red Mountain Creek and its tributaries do not, and probably never have, supported significant aquatic life. ?? 2007 AAG/ Geological Society of London.

  14. Time-Scales of Storm Flow Response in the Stream and Hyporheic Zone of a Small, Steep Forested Catchment - Contrasting the Potential Contributions from the Hillslope, Riparian-Hyporheic Zones, and the Stream Channel

    NASA Astrophysics Data System (ADS)

    Wondzell, S. M.; Corson-rikert, H.; Haggerty, R.

    2016-12-01

    Storm-flow responses of small catchments are widely studied to identify water sources and mechanisms routing water through catchments. These studies typically observe rapid responses to rainfall with peak concentrations of many chemical constituents occurring on rising leg of the hydrograph. To explain this, some conceptual models suggest that stream water early in storm periods is dominated by riparian water sources with hillslope water sources dominating later in the storm. We examined changes in both stream and hyporheic water chemistry during a small, autumn storm in a forested mountain catchment to test this conceptual model. Our study site was located in WS01 at the H.J. Andrews Experimental Forest, in Oregon, USA. The watershed has a narrow valley floor, always less than 15 m wide and occasionally interrupted by narrow, constrained bedrock sections. The valley floor has a longitudinal gradient of approximately 14%. Hyporheic water tends to flow parallel the valley axis and flow paths change little with changes in stream discharge, even during storm events. A well network is located in a 30-m reach near the bottom of the watershed. We sampled the stream, 9 hyporheic wells, and a hillslope well for DOC, DIC, Cl-, and NO3- during the storm. As expected, concentrations of DOC and NO3- increased rapidly on the rising leg of the hydrograph in both the stream and the hyporheic wells. However, the stream always had higher concentrations of DOC, and lower concentrations of NO3-, than did either the hillslope well or the hyporheic wells. These data suggest that the riparian/hyporheic zone is not a likely source of water influencing stream water chemistry on the rising leg of the hydrograph. These data agree with median travel time estimates of water flowing along hyporheic flow paths - it takes many 10s of hours for water to move from the riparian/hyporheic zone to the stream - a time scale that is far too slow to explain the rapid changes observed on the rising leg of the hydrograph. These data suggest that much of the early storm responses in stream chemistry may be generated by in-channel processes, or processes occurring in the shallow streambed with very short hyporheic residence times; the influence of the riparian zone, most of the hyporheic zone, or hillslopes must occur much later in the storm event.

  15. Spatial Heterogeneity of Stream Water Chemistry in the Elder Creek Catchment at the Eel River Critical Zone Observatory.

    NASA Astrophysics Data System (ADS)

    Thurnhoffer, B. M.; Lovill, S. M.; Nghiem, A.; Kim, H.; Bishop, J. K. B.

    2014-12-01

    How does stream chemistry vary with respect to discharge, flow distance, elevation, hill slope orientation, lithology, and vegetation on catchment scale? Is it possible to discern fast flowing seasonally recharged subsurface waters from long residence time waters contributing to base flow? To answer these questions, water samples were collected at ~80 locations distributed over the channel network of the (17 km2) Elder Creek catchment during surveys in May and August/September 2014. The site, located at the Angelo Coast Range Reserve near the headwaters of the South Fork of the Eel River in northern California, experiences a Mediterranean climate with warm dry summers and cold wet winters; this year (2014), our area has received less than 50% of expected precipitation and is experiencing an extreme drought. Our survey times correspond to the beginning of the dry season and late dry season, respectively. The subsurface lithology of the region almost uniform, being largely composed of argillite mudstone with intermittent areas underlain with sandstone. It is forested with Douglas fir, live and tan oaks, madrone and California bay laurel, which vary in abundance with hill-slope orientation. Due to drought, the Elder Catchment has recently experienced the effects of the nearby Lodge Lightening Complex Fire (first detection July 31 2014) and its effects may be differentiated through the continuous 1 - 3 day frequency sampling of Elder Creek water using the ISCO Gravity Filtration System (GFS; Kim et al. 2012, EST). All water samples are analyzed for dissolved major, minor, and trace solutes by Inductively Couple Plasma Mass Spectrometry and this report focuses on major solutes such as Na, K, Ca, Mg and Si; redox sensitive metals Fe and Mn; and Ba and Sr. Preliminary analysis of May 2014 data shows interesting patterns between tributaries, particularly differences between streams on north vs. south facing slopes. Concentrations of Ca, Mg, and Na decrease down slope in south facing tributaries, while they slightly increase downslope in north facing tributaries. Concentrations are relatively invariant in the Elder channel but Elder chemistry differs with respect to Na, Ca and Fe to the South Fork Eel River.

  16. Temperature Response of a Small Mountain Stream to Thunderstorm Cloud-Cover: Application of DTS Fiber-Optic Temperature Sensing

    NASA Astrophysics Data System (ADS)

    Thayer, D.; Klatt, A. L.; Miller, S. N.; Ohara, N.

    2014-12-01

    From a hydrologic point of view, the critical zone in alpine areas contains the first interaction of living systems with water which will flow to streams and rivers that sustain lowland biomes and human civilization. A key to understanding critical zone functions is understanding the flow of energy, and we can measure temperature as a way of looking at energy transfer between related systems. In this study we installed a Distributed Temperature Sensor (DTS) and fiber-optic cable in a zero-order stream at 9,000 ft in the Medicine Bow National Forest in southern Wyoming. We measured the temperature of the stream for 17 days from June 29 to July 16; the first 12 days were mostly sunny with occasional afternoon storms, and the last 5 experienced powerful, long-lasting storms for much of the day. The DTS measurements show a seasonal warming trend of both minimum and maximum stream temperature for the first 12 days, followed by a distinct cooling trend for the five days that experienced heavy storm activity. To gain insights into the timing and mechanisms of energy flow through the critical zone systems, we analyzed the timing of stream temperature change relative to solar short-wave radiation, and compared the stream temperature temporal response to the temporal response of soil temperature adjacent to the stream. Since convective thunderstorms are a dominant summer weather pattern in sub-alpine regions in the Rocky Mountains, this study gives us further insight into interactions of critical zone processes and weather in mountain ecosystems.

  17. The influence of stream thermal regimes and preferential flow paths on hyporheic exchange in a glacial meltwater stream

    USGS Publications Warehouse

    Cozzetto, Karen D.; Bencala, Kenneth E.; Gooseff, Michael N.; McKnight, Diane M.

    2013-01-01

    Given projected increases in stream temperatures attributable to global change, improved understanding of relationships between stream temperatures and hyporheic exchange would be useful. We conducted two conservative tracer injection experiments in a glacial meltwater stream, to evaluate the effects of hyporheic thermal gradients on exchange processes, including preferential flow paths (PFPs). The experiments were conducted on the same day, the first (a stream injection) during a cool, morning period and the second (dual stream and hyporheic injections) during a warm, afternoon period. In the morning, the hyporheic zone was thermally uniform at 4°C, whereas by the afternoon the upper 10 cm had warmed to 6–12°C and exhibited greater temperature heterogeneity. Solute transport modeling showed that hyporheic cross-sectional areas (As) at two downstream sites were two and seven times lower during the warm experiment. Exchange metrics indicated that the hyporheic zone had less influence on downstream solute transport during the warm, afternoon experiment. Calculated hyporheic depths were less than 5 cm, contrasting with tracer detection at 10 and 25 cm depths. The hyporheic tracer arrival at one downstream site was rapid, comparable to the in-stream tracer arrival, providing evidence for PFPs. We thus propose a conceptual view of the hyporheic zone in this reach as being dominated by discrete PFPs weaving through hydraulically isolated areas. One explanation for the simultaneous increase in temperature heterogeneity and As decrease in a warmer hyporheic zone may be a flow path preferentiality feedback mechanism resulting from a combination of temperature-related viscosity decreases and streambed heterogeneity.

  18. Chemical vapor deposition of epitaxial silicon

    DOEpatents

    Berkman, Samuel

    1984-01-01

    A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

  19. Quality of surface-water runoff in selected streams in the San Antonio segment of the Edwards aquifer recharge zone, Bexar County, Texas, 1997-2012

    USGS Publications Warehouse

    Opsahl, Stephen P.

    2012-01-01

    During 1997–2012, the U.S. Geological Survey, in cooperation with the San Antonio Water System, collected and analyzed water-quality constituents in surface-water runoff from five ephemeral stream sites near San Antonio in northern Bexar County, Texas. The data were collected to assess the quality of surface water that recharges the Edwards aquifer. Samples were collected from four stream basins that had small amounts of developed land at the onset of the study but were predicted to undergo substantial development over a period of several decades. Water-quality samples also were collected from a fifth stream basin located on land protected from development to provide reference data by representing undeveloped land cover. Water-quality data included pH, specific conductance, chemical oxygen demand, dissolved solids (filtered residue on evaporation in milligrams per liter, dried at 180 degrees Celsius), suspended solids, major ions, nutrients, trace metals, and pesticides. Trace metal concentration data were compared to the Texas Commission on Environmental Quality established surface water quality standards for human health protection (water and fish). Among all constituents in all samples for which criteria were available for comparison, only one sample had one constituent which exceeded the surface water criteria on one occasion. A single lead concentration (2.76 micrograms per liter) measured in a filtered water sample exceeded the surface water criteria of 1.15 micrograms per liter. The average number of pesticide detections per sample in stream basins undergoing development ranged from 1.8 to 6.0. In contrast, the average number of pesticide detections per sample in the reference stream basin was 0.6. Among all constituents examined in this study, pesticides, dissolved orthophosphate phosphorus, and dissolved total phosphorus demonstrated the largest differences between the four stream basins undergoing development and the reference stream basin with undeveloped land cover.

  20. Trapping and exclusion zones in complex streaming patterns around a large assembly of microfluidic bubbles under ultrasound

    NASA Astrophysics Data System (ADS)

    Combriat, Thomas; Mekki-Berrada, Flore; Thibault, Pierre; Marmottant, Philippe

    2018-01-01

    Pulsating bubbles have proved to be a versatile tool for trapping and sorting particles. In this article, we investigate the different streaming patterns that can be obtained with a group of bubbles in a confined geometry under ultrasound. In the presence of an external flow strong enough to oppose the streaming velocities but not drag the trapped bubbles, we observe either the appearance of exclusion zones near the bubbles or asymmetric streaming patterns that we interpret as the superposition of a two-dimensional (2D) streaming function and of a potential flow. When studying a lattice of several bubbles, we show that the streaming pattern can be accurately predicted by superimposing the contributions of every pair of bubbles present in the lattice, thus allowing one to predict the sizes and the shapes of exclusion zones created by a group of bubbles under acoustic excitation. We suggest that such systems could be used to enhance mixing at a small scale or to catch and release chemical species initially trapped in vortices created around bubble pairs.

  1. Effects of extreme low flows on freshwater shrimps in a perennial tropical stream.

    Treesearch

    A.P. COVICH; T.A. CROWL; F.N. SCATENA

    2003-01-01

    1. Long-term data on rainfall suggests that perennial rainforest streams rarely are subject to drying of riffles or pools in the wet, non-seasonal Caribbean climate of Puerto Rico. Unusually low rainfall in 1994 caused some headwater riffles to dry out completely, resulting in isolated pools, reduced pool volumes and loss of access to microhabitats by benthic...

  2. Attempting to link hydro-morphology, transient storage and metabolism in streams: Insights from reactive tracer experiments

    NASA Astrophysics Data System (ADS)

    Kurz, Marie J.; Schmidt, Christian; Blaen, Phillip; Knapp, Julia L. A.; Drummond, Jennifer D.; Martí, Eugenia; Zarnetske, Jay P.; Ward, Adam S.; Krause, Stefan

    2016-04-01

    In-stream transient storage zones, including the hyporheic zone and vegetation beds, can be hotspots of biogeochemical processing in streams, enhancing ecosystem functions such as metabolism and nutrient uptake. The spatio-temporal dynamics and reactivity of these storage zones are influenced by multiple factors, including channel geomorphology, substrate composition and hydrology, and by anthropogenic modifications to flow regimes and nutrient loads. Tracer injections are a commonly employed method to evaluate solute transport and transient storage in streams; however, reactive tracers are needed to differentiate between metabolically active and inactive transient storage zones. The reactive stream tracer resazurin (Raz), a weakly fluorescent dye which irreversibly transforms to resorufin (Rru) under mildly reducing conditions, provides a proxy for aerobic respiration and an estimate of the metabolic activity associated with transient storage zones. Across a range of lotic ecosystems, we try to assess the influence of stream channel hydro-morphology, morphologic heterogeneity, and substrate type on reach (103 m) and sub-reach (102 m) scale transient storage, respiration, and nutrient uptake. To do so, we coupled injections of Raz and conservative tracers (uranine and/or salt) at each study site. The study sites included: vegetated mesocosms controlled for water depth; vegetated and un-vegetated sediment-filled mesocosms fed by waste-water effluent; a contrasting sand- vs. gravel-bedded lowland stream (Q = 0.08 m3/s); and a series of upland streams with varying size (Q = 0.1 - 1.5 m3/s) and prevalence of morphologic features. Continuous time-series of tracer concentrations were recorded using in-situ fluorometers and EC loggers. At the stream sites, time-series were recorded at multiple downstream locations in order to resolve sub-reach dynamics. Analyses yielded highly variable transport metrics and Raz-Rru transformation between study sites and between sub-reaches within stream sites. Higher Raz-Rru transformation rates were typically observed in smaller streams, in sub-reaches with higher prevalence of morphologic features known to promote hyporheic exchange, and in mesocosms with higher water depth, vegetation density and retention time. However, relationships between transformation rates and common metrics of transient storage were not consistent among study cases, indicating the existence of yet unrealized complexities in the relationships between water and solute transport and metabolism. Further insights were also gained related to the utility of Raz and improved tracer test practices.

  3. SHUTTLE IMAGING RADAR PROVIDES FRAMEWORK FOR SUBSURFACE GEOLOGIC EXPLORATION IN EGYPT AND SUDAN.

    USGS Publications Warehouse

    Breed, Carol S.; McCauley, John F.; Schaber, Gerald G.

    1984-01-01

    Shuttle Imaging Radar provides a pictorial framework to guide exploration for mineral resources (potential placers), groundwater sources, and prehistoric archaeological sites in the Western Desert of Egypt and Sudan. Documented penetration by the SIR-A signal of dry surficial sediment to depths of a meter or more revealed bedrock geologic features and networks of former stream valleys otherwise concealed beneath windblown sand, alluvium, and colluvial deposits. 'Radar units' mapped on SIR-A images according to relative brightness and degree of mottling correspond to subsurface geologic and topographic features identified in more than 50 test pits. Petrologic examination of pit samples confirms that a variety of depositional environments existed in this now hyper-arid region before it was mantled by windblown sand sheets and dunes. Wet sand was discovered in two buried valleys shown on the radar images and located in the field with the aid of co-registered maps and Landsat images, and a satellite navigation device. Buried valleys whose streams once traversed mineralized zones are potential sites of placers (gold, tin).

  4. Using Heat as a Tracer to Estimate Streambed Water Exchanges beneath the Losing Disconnected Stream

    NASA Astrophysics Data System (ADS)

    Chiu, Yung-Chia; Lee, Tsung-Yu; Hsu, Shao-Yu; Liao, Lin-Yan

    2017-04-01

    Streambed water exchanges is the movement of water from a river into the beneath sediments and then back into the river. This interaction between river and streambed is considered as a fundamental role in the functioning of riparian ecosystems. Chichiawan Watershed located in central Taiwan is the only habitat for the endangered species of formosan land-locked salmon and such dynamics of downwelling/upwelling flow within the streambed can affect the survival of salmon. In order to investigate the interaction between river and streambed, heat is used as an environmental tracer to determine the water exchanges within the streambed and estimate the hydraulic conductivity of sediments. The detailed hydrographs, thermographs, and vertical temperature profiles obtained along the Yusheng Creek, a tributary at the upstream of Chichiawan Creek, were presented and used to estimate the streambed water exchanges. Results showed that the Yusheng Creek along the monitoring section is a losing stream and its downwelling flux increases from up- to down-stream. Partial monitoring sections changed from perennial to intermittence when the consecutive dry days over a period of time increase significantly and an unsaturated zone between the creek and the groundwater existed. According to the measured temperature and water level data, the numerical model of VS2DH was used to quantify the vertical fluxes and hydraulic conductivities of streamed. The potential mechanisms causing the creek transited from perennial to intermittence and becoming a losing disconnected system need further study.

  5. Understanding the Mechanisms by Which a Perennial Arctic Stream Appears Intermittent

    NASA Astrophysics Data System (ADS)

    Betts, E.; Kane, D. L.

    2011-12-01

    Fish and wildlife species in the Arctic have developed life history strategies to deal with the extreme climate of the North. In the case of Arctic grayling, these strategies include long life, yearly spawning, and migration. In order to understand how such a species will be affected by a changing climate, we must determine how these adaptive strategies may be at odds with the changing Arctic landscape. Arctic grayling migrate to spawning grounds just after break up in the spring, then migrate to feeding sites in early summer, and finally in the fall migrate back to their overwintering sites. Low precipitation and high evapotranspiration rates early in the summer can lead to low water levels and a fragmentation of the hydrologic landscape. This fragmentation creates a barrier to fish migration. The Kuparuk River is a perennial stream originating in the foothills of the Brooks Range on the North Slope of Alaska. The basin is entirely underlain by permafrost which essentially cuts the system off from deep groundwater. Subsurface flow occurs in the active layer, that area above permafrost which undergoes seasonal thawing in the summer. Sections of the Kuparuk are intermittent in that during low flows in the system these reaches appear dry. Water reappears downstream of these dry reaches and it is believed that water continues to flow below the surface through the unfrozen thaw bulb beneath these reaches. These dry reaches act as summer barriers to fish migration within the Kuparuk River system. Previous research of this phenomenon sought to understand the location and timing of these "dry" events. This work found that these reaches appear dry anywhere from 2 days to 4 weeks at a time and average about 22 dry days a year. The timing of these dry events is fairly uniform throughout the summer. The three dry reaches in this study range from 1.5 miles in length to over 5 miles. The dry reaches in this study occur just upstream of aufeis fields. It has been shown previously that most aufeis fields on the North Slope are fed by deep groundwater springs. In this system however we know that this water is much younger and therefore likely from a much closer source. Specifically, it is the hypothesis of the author that the water feeding these aufeis fields is related to water being stored in unfrozen zones above the permafrost. This storage area represents an area of preferential flow which explains why flow runs completely subsurface during periods of low flow in the Kuparuk. The research presented here represents year two of the current project which has focused on understanding the mechanisms which drive these dry events in an effort to determine whether climate change will act to increase the instances of such events.

  6. Mineralogy of Antarctica Dry Valley Soils: Implications for Pedogenic Processes on Mars

    NASA Technical Reports Server (NTRS)

    Quinn, J. E.; Ming, D. W.; Morris, R. V.; Douglas, S.; Kounaves, S. P.; McKay, C. P.; Tamppari, L, K.; Smith, P. H.; Zent, A. P.; Archer, P. D., Jr.

    2010-01-01

    The Antarctic Dry Valleys (ADVs) located in the Transantarctic Mountains are the coldest and driest locations on Earth. The mean annual air temperature is -20 C or less and the ADVs receive 100mm or less of precipitation annually in the form of snow. The cold and dry climate in the ADVs is one of the best terrestrial analogs for the climatic conditions on Mars [2]. The soils in the ADVs have been categorized into three soil moisture zones: subxerous, xerous and ultraxerous. The subxerous zone is a coastal region in which soils have ice-cemented permafrost relatively close to the surface. Moisture is available in relatively large amounts and soil temperatures are above freezing throughout the soil profile (above ice permafrost) in summer months. The xerous zone, the most widespread of the three zones, is an inland region with a climate midway between the subxerous and ultraxerous. The soils from this zone have dry permafrost at moderate depths (30-75cm) but have sufficient water in the upper soil horizons to allow leaching of soluble materials. The ultraxerous zone is a high elevation zone, where both temperature and precipitation amounts are very low resulting in dry permafrost throughout the soil profile. The three moisture regime regions are similar to the three microclimatic zones (coastal thaw, inland mixed, stable upland) defined by Marchant and Head.

  7. Temporal Hyporheic Zone Response to Water Table Fluctuations.

    PubMed

    Malzone, Jonathan M; Anseeuw, Sierra K; Lowry, Christopher S; Allen-King, Richelle

    2016-03-01

    Expansion and contraction of the hyporheic zone due to temporal hydrologic changes between stream and riparian aquifer influence the biogeochemical cycling capacity of streams. Theoretical studies have quantified the control of groundwater discharge on the depth of the hyporheic zone; however, observations of temporal groundwater controls are limited. In this study, we develop the concept of groundwater-dominated differential hyporheic zone expansion to explain the temporal control of groundwater discharge on the hyporheic zone in a third-order stream reach flowing through glacially derived terrain typical of the Great Lakes region. We define groundwater-dominated differential expansion of the hyporheic zone as: differing rates and magnitudes of hyporheic zone expansion in response to seasonal vs. storm-related water table fluctuation. Specific conductance and vertical hydraulic gradient measurements were used to map changes in the hyporheic zone during seasonal water table decline and storm events. Planar and riffle beds were monitored in order to distinguish the cause of increasing hyporheic zone depth. Planar bed seasonal expansion of the hyporheic zone was of a greater magnitude and longer in duration (weeks to months) than storm event expansion (hours to days). In contrast, the hyporheic zone beneath the riffle bed exhibited minimal expansion in response to seasonal groundwater decline compared to storm related expansion. Results indicated that fluctuation in the riparian water table controlled seasonal expansion of the hyporheic zone along the planar bed. This groundwater induced hyporheic zone expansion could increase the potential for biogeochemical cycling and natural attenuation. © 2015, National Ground Water Association.

  8. Response of nutrients, biofilm, and benthic insects to salmon carcass addition.

    Treesearch

    Shannon M. Claeson; Judith L. Li; Jana E. Compton; Peter A. Bisson

    2006-01-01

    Salmon carcass addition to streams is expected to increase stream productivity at multiple trophic levels. This study examined stream nutrient (nitrogen, phosphorus, and carbon), epilithic biofilm (ash-free dry mass and chlorophyll a), leaf-litter decomposition, and macroinvertebrate (density and biomass) responses to carcass addition in three headwater streams of...

  9. RESPONSE OF NUTRIENTS, BIOFILM, AND BENTHIC INSECTS TO SALMON CARCASS ADDITION

    EPA Science Inventory

    Salmon carcass addition to streams is expected to increase stream productivity at multiple trophic levels. This study examined stream nutrient (nitrogen, phosphorus, and carbon), epilithic biofilm (ash-free dry mass and chlorophyll a), leaf-litter decomposition, and macroinverte...

  10. Evaluating the reliability of the stream tracer approach to characterize stream-subsurface water exchange

    USGS Publications Warehouse

    Harvey, Judson W.; Wagner, Brian J.; Bencala, Kenneth E.

    1996-01-01

    Stream water was locally recharged into shallow groundwater flow paths that returned to the stream (hyporheic exchange) in St. Kevin Gulch, a Rocky Mountain stream in Colorado contaminated by acid mine drainage. Two approaches were used to characterize hyporheic exchange: sub-reach-scale measurement of hydraulic heads and hydraulic conductivity to compute streambed fluxes (hydrometric approach) and reachscale modeling of in-stream solute tracer injections to determine characteristic length and timescales of exchange with storage zones (stream tracer approach). Subsurface data were the standard of comparison used to evaluate the reliability of the stream tracer approach to characterize hyporheic exchange. The reach-averaged hyporheic exchange flux (1.5 mL s−1 m−1), determined by hydrometric methods, was largest when stream base flow was low (10 L s−1); hyporheic exchange persisted when base flow was 10-fold higher, decreasing by approximately 30%. Reliability of the stream tracer approach to detect hyporheic exchange was assessed using first-order uncertainty analysis that considered model parameter sensitivity. The stream tracer approach did not reliably characterize hyporheic exchange at high base flow: the model was apparently more sensitive to exchange with surface water storage zones than with the hyporheic zone. At low base flow the stream tracer approach reliably characterized exchange between the stream and gravel streambed (timescale of hours) but was relatively insensitive to slower exchange with deeper alluvium (timescale of tens of hours) that was detected by subsurface measurements. The stream tracer approach was therefore not equally sensitive to all timescales of hyporheic exchange. We conclude that while the stream tracer approach is an efficient means to characterize surface-subsurface exchange, future studies will need to more routinely consider decreasing sensitivities of tracer methods at higher base flow and a potential bias toward characterizing only a fast component of hyporheic exchange. Stream tracer models with multiple rate constants to consider both fast exchange with streambed gravel and slower exchange with deeper alluvium appear to be warranted.

  11. Streamside Management Zones Affect Movement of Silvicultural Nitrogen and Phosphorus Fertilizers to Piedmont Streams

    Treesearch

    Joseph M. Secoges; Wallace M. Aust; John R. Seiler; C. Andrew Dolloff; William A. Lakel

    2013-01-01

    Forestry best management practices (BMP) recommendations for streamside management zones (SMZs) are based on limited data regarding SMZ width, partial harvests, and nutrient movements after forest fertilization. Agricultural fertilization is commonly linked to increased stream nutrients. However, less is known about effectiveness of SMZ options for controlling nutrient...

  12. Tracking tracer breakthrough in the hyporheic zone using time‐lapse DC resistivity, Crabby Creek, Pennsylvania

    USGS Publications Warehouse

    Nyquist, Jonathan E.; Toran, Laura; Fang, Allison C.; Ryan, Robert J.; Rosenberry, Donald O.

    2010-01-01

    Characterization of the hyporheic zone is of critical importance for understanding stream ecology, contaminant transport, and groundwater‐surface water interaction. A salt water tracer test was used to probe the hyporheic zone of a recently re‐engineered portion of Crabby Creek, a stream located near Philadelphia, PA. The tracer solution was tracked through a 13.5 meter segment of the stream using both a network of 25 wells sampled every 5–15 minutes and time‐lapse electrical resistivity tomographs collected every 11 minutes for six hours, with additional tomographs collected every 100 minutes for an additional 16 hours. The comparison of tracer monitoring methods is of keen interest because tracer tests are one of the few techniques available for characterizing this dynamic zone, and logistically it is far easier to collect resistivity tomographs than to install and monitor a dense network of wells. Our results show that resistivity monitoring captured the essential shape of the breakthrough curve and may indicate portions of the stream where the tracer lingered in the hyporheic zone. Time‐lapse resistivity measurements, however, represent time averages over the period required to collect a tomographic data set, and spatial averages over a volume larger than captured by a well sample. Smoothing by the resistivity data inversion algorithm further blurs the resulting tomograph; consequently resistivity monitoring underestimates the degree of fine‐scale heterogeneity in the hyporheic zone.

  13. Role of surface and subsurface processes in scaling N2O emissions along riverine networks

    PubMed Central

    Marzadri, Alessandra; Dee, Martha M.; Tonina, Daniele; Bellin, Alberto; Tank, Jennifer L.

    2017-01-01

    Riverine environments, such as streams and rivers, have been reported as sources of the potent greenhouse gas nitrous oxide (N2O) to the atmosphere mainly via microbially mediated denitrification. Our limited understanding of the relative roles of the near-surface streambed sediment (hyporheic zone), benthic, and water column zones in controlling N2O production precludes predictions of N2O emissions along riverine networks. Here, we analyze N2O emissions from streams and rivers worldwide of different sizes, morphology, land cover, biomes, and climatic conditions. We show that the primary source of N2O emissions varies with stream and river size and shifts from the hyporheic–benthic zone in headwater streams to the benthic–water column zone in rivers. This analysis reveals that N2O production is bounded between two N2O emission potentials: the upper N2O emission potential results from production within the benthic–hyporheic zone, and the lower N2O emission potential reflects the production within the benthic–water column zone. By understanding the scaling nature of N2O production along riverine networks, our framework facilitates predictions of riverine N2O emissions globally using widely accessible chemical and hydromorphological datasets and thus, quantifies the effect of human activity and natural processes on N2O production. PMID:28400514

  14. Destiny of earthward streaming plasma in the plasmasheet boundary layer

    NASA Technical Reports Server (NTRS)

    Green, J. L.; Horwitz, J. L.

    1986-01-01

    The dynamics of the earth's magnetotail have been investigated, and it has become clear that the plasmasheet boundary layer field lines map into the Region I Field-Aligned Currents (FAC) of the auroral zone. It is pointed out that the role of earthward streaming ions in the plasmasheet boundary layer may be of fundamental importance in the understanding of magnetotail dynamics, auroral zone physics, and especially for ionospheric-magnetospheric interactions. The present paper has the objective to evaluate propagation characteristics for the earthward streaming ions observed in the plasmasheet boundary layer. An investigation is conducted of the propagation characteristics of protons in the plasmasheet boundary layer using independent single particle dynamics, and conclusions are discussed. The density of earthward streaming ions found in the plasmasheet boundary layer should include the ring current as well as the auroral zone precipitaiton and inner plasmasheet regions of the magnetosphere.

  15. INVERTEBRATE ASSEMBLAGES FROM HEADWATER STREAMS WITH DIFFERENT FLOW PERMANENCE

    EPA Science Inventory

    Headwater streams are the most abundant and widespread of our nation's surface waters, yet few ecological assessments are specifically targeting these resources. Natural drying has a strong influence on the biological communities and can confound the use of traditional stream as...

  16. Stream Community Structure: An Analysis of Riparian Forest Buffer Restoration in the Chesapeake Bay Watershed

    NASA Astrophysics Data System (ADS)

    Orzetti, L. L.; Jones, R. C.

    2005-05-01

    Forested riparian buffer zones have been proposed as an important aid in curtailing upland sources of pollution before they reach stream surface waters, and enhancing habitat for stream organisms. Our objective was to test the efficacy of restored forest riparian buffers along streams in the Chesapeake Bay watershed by examining the stream macrobenthic community structure. To test our hypothesis, we collected riffle benthic and water samples, and performed habitat evaluations at 30 stream sites in the mid-Atlantic Piedmont, ranging in buffer age from 0 to greater than 50 years of age. Results showed that habitat, water quality, and benthic macroinvertebrate metrics improved with age of restored buffer. Habitat scores were driven mostly by instream substrate availability and width and age of riparian buffer zones. Water quality parameters varied within buffer age groups depending age of surrounding forest vegetation. Benthic invertebrate taxa richness, % EPT, % Plecoptera, % Ephemeroptera, and the FBI all improved with age of buffer zone. Instream habitat quality was the greatest driver of benthic macroinvertebrate community diversity and health, and appeared to plateau within 10-15 years of restoration with noticeable improvements occurring within 5-10 years post restoration.

  17. Method and system for the removal of oxides of nitrogen and sulfur from combustion processes

    DOEpatents

    Walsh, John V.

    1987-12-15

    A process for removing oxide contaminants from combustion gas, and employing a solid electrolyte reactor, includes: (a) flowing the combustion gas into a zone containing a solid electrolyte and applying a voltage and at elevated temperature to thereby separate oxygen via the solid electrolyte, (b) removing oxygen from that zone in a first stream and removing hot effluent gas from that zone in a second stream, the effluent gas containing contaminant, (c) and pre-heating the combustion gas flowing to that zone by passing it in heat exchange relation with the hot effluent gas.

  18. Physical Habitat and Energy Inputs Determine Freshwater Invertebrate Communities in Reference and Cranberry Farm Impacted Northeastern Coastal Zone Streams

    NASA Astrophysics Data System (ADS)

    Lander, D. M. P.; McCanty, S. T.; Dimino, T. F.; Christian, A. D.

    2016-02-01

    The River Continuum Concept (RCC) predicts stream biological communities based on dominant physical structures and energy inputs into streams and predicts how these features and corresponding communities change along the stream continuum. Verifying RCC expectations is important for creating valid points of comparison during stream ecosystem evaluation. These reference expectations are critical for restoration projects, such as the restoration of decommissioned cranberry bogs. Our research compares the physical habitat and freshwater invertebrate functional feeding groups (FWIFFG) of reference, active cranberry farming, and cranberry farm passive restoration sites in Northeastern Coastal Zone streams of Massachusetts to the specific RCC FWIFFG predictions. We characterized stream physical habitat using a semi-quantitative habitat characterization protocol and sampled freshwater invertebrates using the U.S. EPA standard 20-jab multi-habitat protocol. We expected that stream habitat would be most homogeneous at active farming stations, intermediate at restoration stations, and most heterogeneous at reference stations. Furthermore, we expected reference stream FWIFFG would be accurately predicted by the RCC and distributions at restoration and active sites would vary significantly. Habitat data was analyzed using a principle component analysis and results confirmed our predictions showing more homogeneous habitat for the active and reference stations, while showing a more heterogeneous habitat at the reference stations. The FWIFFG chi-squared analysis showed significant deviation from our specific RCC FWIFFG predictions. Because published FWIFFG distributions did not match our empirical values for a least disturbed Northeastern Coastal Zone headwater stream, using our data as a community structure template for current and future restoration projects is not recommend without further considerations.

  19. Utilizing Controlled Vibrations in a Microgravity Environment to Understand and Promote Microstructural Homogeneity During Floating-Zone Crystal Growth

    NASA Technical Reports Server (NTRS)

    Anilkumar, A. V.; Bhowmick, J.; Grugel, R. N.

    2001-01-01

    Our previous experiments with NaNO3 float-zones revealed that steady thermocapillary flow can be balanced/offset by the controlled surface streaming flow induced by end-wall vibration. In the current experiments we are examining the effects of streaming flow on steadying/stabilizing nonsteady thermocapillary flow in such zones. To this effect we have set up a controlled NaNO3 half-zone experiment, where the processing parameters, like zone dimensions and temperature gradients, can be easily varied to generate nonsteady thermocapillary flows. In the present paper we present preliminary results of our investigations into stabilizing such flows by employing endwall vibration.

  20. Utilizing Controlled Vibrations in a Microgravity Environment to Understand and Promote Microstructural Homogeneity During Float-Zone Crystal Growth

    NASA Technical Reports Server (NTRS)

    Anilkumar, A. V.; Bhowmick, J.; Grugel, R. N.a

    2000-01-01

    Our previous experiments with NaNO3 float-zones revealed that steady thermocapillary flow can be balanced/offset by the controlled surface streaming flow induced by end-wall vibration. In the current experiments we are examining the effects of streaming flow on steadying/stabilizing nonsteady thermocapillary flow in such zones. To this effect we have set up a controlled NaNO3 half-zone experiment, where the processing parameters, like zone dimensions and temperature gradients, can be easily varied to generate nonsteady thermocapillary flows. In the present paper we present preliminary results of our investigations into stabilizing such flows by employing end-wall vibration.

  1. Pulverized coal burner

    DOEpatents

    Sivy, J.L.; Rodgers, L.W.; Koslosy, J.V.; LaRue, A.D.; Kaufman, K.C.; Sarv, H.

    1998-11-03

    A burner is described having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO{sub x} burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO{sub x} back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing. 8 figs.

  2. Pulverized coal burner

    DOEpatents

    Sivy, Jennifer L.; Rodgers, Larry W.; Koslosy, John V.; LaRue, Albert D.; Kaufman, Keith C.; Sarv, Hamid

    1998-01-01

    A burner having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO.sub.x burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO.sub.x back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing.

  3. Legacy Nitrate Impacts on Groundwater and Streams

    NASA Astrophysics Data System (ADS)

    Tesoriero, A. J.; Juckem, P. F.; Miller, M. P.

    2017-12-01

    Decades of recharge of high-nitrate groundwater have created a legacy—a mass of high-nitrate groundwater—that has implications for future nitrate concentrations in groundwater and in streams. In the United States, inorganic nitrogen fertilizer applications to the land surface have increased ten-fold since 1950, resulting in sharp increases in nitrate concentrations in recharging groundwater, which pose a risk to deeper groundwater and streams. This study assesses the factors that control time lags and eventual concentrations of legacy nitrate in groundwater and streams. Results from the USGS National Water-Quality Assessment Project are presented which elucidate nitrate trends in recharging groundwater, delineate redox zones and assess groundwater and stream vulnerability to legacy nitrate sources on a regional scale. This study evaluated trends and transformations of agricultural chemicals based on groundwater age and water chemistry data along flow paths from recharge areas to streams at 20 study sites across the United States. Median nitrate recharge concentrations in these agricultural areas have increased markedly over the last 50 years, from 4 to 7.5 mg N/L. The effect that nitrate accumulation in shallow aquifers will have on drinking water quality and stream ecosystems is dependent on the redox zones encountered along flow paths and on the age distribution of nitrate discharging to supply wells and streams. Delineating redox zones on a regional scale is complicated by the spatial variability of reaction rates. To overcome this limitation, we applied logistic regression and machine learning techniques to predict the probability of a specific redox condition in groundwater in the Chesapeake Bay watershed and the Fox-Wolf-Peshtigo study area in Wisconsin. By relating redox-active constituent concentrations in groundwater samples to indicators of residence time and/or electron donor availability, we were able to delineate redox zones on a regional scale - an important indicator of groundwater vulnerability and the vulnerability of streams to legacy nitrate sources.

  4. The stream subsurface: nitrogen cycling and the cleansing function of hyporheic zones

    Treesearch

    Rhonda Mazza; Steve Wondzell; Jay Zarnetske

    2014-01-01

    Nitrogen is an element essential to plant growth and ecosystem productivity. Excess nitrogen, however, is a common water pollutant. It can lead to algal blooms that deplete the water's dissolved oxygen, creating "dead zones" devoid of fish and aquatic insects.Previous research showed that the subsurface area of a stream, known as the hyporheic...

  5. Dynamics of nitrate production and removal as a function of residence time in the hyporheic zone

    Treesearch

    Jay P. Zarnetske; Roy Haggerty; Steven M. Wondzell; Michelle A. Baker

    2011-01-01

    Biogeochemical reactions associated with stream nitrogen cycling, such as nitrification and denitrification, can be strongly controlled by water and solute residence times in the hyporheic zone (HZ). We used a whole-stream steady state 15N-Iabeled nitrate and conservative tracer addition to investigate the spatial and temporal physiochemical...

  6. Sediment trapping by streamside management zones of various widths after forest harvest and site preparation

    Treesearch

    William Lakel; Wallace Aust; M. Aust; Chad Bolding; C. Dolloff; Patrick Keyser; Robert Feldt

    2010-01-01

    Recommended widths for streamside management zones (SMZs) for sediment protection vary. The objectives of this study were to compare the effects of SMZ widths and thinning levels on sediment moving through SMZs. Four SMZ treatments were installed within 16 harvested watersheds where intermittent streams graded into small perennial streams. Sites were clearcut,...

  7. Response of herbaceous plant community diversity and composition to overstorey harvest within riparian management zones in Northern Hardwoods

    Treesearch

    Eric K. Zenner; Michelle A. Martin; Brian J. Palik; Jerilynn E. Peck; Charles R. Blinn

    2013-01-01

    Partial timber harvest within riparian management zones (RMZs) may permit active management of riparian forests while protecting stream ecosystems, but impacts on herbaceous communities are poorly understood. We compared herbaceous plant community abundance, diversity and composition in RMZs along small streams in northern Minnesota, USA, among four treatments before...

  8. Scrubbing of contaminants from contaminated air streams with aerogel materials with optional photocatalytic destruction

    DOEpatents

    Attia, Yosry A.

    2000-01-01

    Disclosed is a method for separating a vaporous or gaseous contaminant from an air stream contaminated therewith. This method includes the steps of: (a) passing said contaminated air into a contact zone in which is disposed an aerogel material capable of selecting adsorbing said contaminant from air and therein contacting said contaminated air with an aerogel material; and (b) withdrawing from said zone, air depleted of said contaminant. For present purposes, "contaminant" means a material not naturally occurring in ambient air and/or a material naturally occurring in air but present at a concentration above that found in ambient air. Thus, the present invention scrubs (or treats) air for the purpose of returning it to its ambient composition. Also disclosed herein is a process for the photocatalytic destruction of contaminants from an air stream wherein the contaminated air stream is passed into a control cell or contact zone in which is disposed a photocatalytic aerogel and exposing said aerogel to ultraviolet (UV) radiation for photocatalytically destroying the adsorbed contaminant, and withdrawing from said cell an exhaust air stream depleted in said contaminant.

  9. Groundwater-surface water interactions in a glacierized catchment and their influence on proglacial water supply

    NASA Astrophysics Data System (ADS)

    Gordon, R. P.; Lautz, L. K.; McKenzie, J. M.; Mark, B. G.

    2012-12-01

    The tropical glaciers of the Cordillera Blanca of Peru are retreating rapidly due to climate change, which threatens water resources for the quarter-million inhabitants of the upper Rio Santa river valley and many more downstream. Recent studies have shown that glacial melt supplies approximately half of dry season stream discharge in Cordillera Blanca valleys. The remainder of streamflow is supplied by groundwater stored in alpine meadows, moraines and talus slopes. In the future, when glacier loss has reduced the influence of melt water on streams, groundwater discharge will be the primary dry-season source of stream water for irrigation, municipalities, and hydropower in the Santa watershed. A better understanding of the dynamics of alpine groundwater, including sources and exchange fluxes, is therefore important for future planning in this region. Understanding these groundwater-surface water interactions is necessary for making accurate estimates of meltwater contributions to the hydrologic budget, and for our ability to make predictions about future water resources under deglaciating conditions. We combined measurements of groundwater-surface water exchange during the dry season with synoptic sampling of stream water and end-members in order to quantify the groundwater contributions to streamflow from an alpine meadow, debris fan, and moraine complex in a glacierized valley of the Cordillera Blanca. Using stream tracer-dilution techniques, we calculated channel water balances for 9 stream reaches of 100-200 m throughout the meadow and measured the discharge of glacial meltwater into debris fan and moraine units. We used vertical heat tracing to measure stream-groundwater exchange at 2-hour increments over 2 weeks in 13 stream locations in the meadow, debris fan, and moraine units. Channel water balance and heat tracing results show that, during the studied portion of the dry season, the stream loses water (2.5 l/s or ~25% of flow) to the subsurface in the upstream half of the meadow, and gains water (7 l/s or ~6% of flow) in the lower half. The debris fan adjacent to the meadow received 22 l/s of surficial melt water from a glacial lake but contributed ~100 l/s of streamflow to the meadow, mostly through springs at the fan-meadow interface. In contrast, the terminal moraine complex at the head of the meadow received 36 l/s of glacial lake discharge but only contributed 5 l/s of streamflow to the meadow; the remainder of stream discharge over the moraine was apparently lost to an underlying aquifer. Results show that gains and losses of stream water are unequally distributed across the landscape in the dry season, with the debris fan and meadow being net sources of streamflow, and the moraine a net sink. Almost all of the stream water exiting the catchment (115 l/s) spent some time in the subsurface, with approximately half originating as groundwater within the studied watershed.

  10. Seroepidemiology of Brucella abortus infection in bovids in Sri Lanka.

    PubMed

    Silva, I; Dangolla, A; Kulachelvy, K

    2000-07-03

    From 1992 to 1995, 0.15% (n=3916) of the bovids (cattle and buffalo) in Sri Lanka were sampled, using a multi-stage sampling procedure. Serum antibodies for Brucella abortus were detected using the indirect enzyme-linked immunosorbent assay (ELISA). The age, the agroecological zone and the management system practiced in the farms of the sampled bovids were studied as risk factors for seropositivity. The overall seroprevalence of brucellosis in cattle was 4.7% (n=3076) and 4.2% in buffaloes (n=840). Bovids that were over 3 years of age, from the dry zone (annual rainfall 20-35 in.), and reared under an extensive management system had higher odds of being seropositive. Bovids from the dry zone were at approximately six times higher odds of being seropositive even after controlling for the possible effects of age and management system. Approximately 75% of the seropositive males were from the dry zone. Most bovids (84%) from the dry zone in this study were reared under an extensive management system (free grazing) which allows unrestricted contact between animals. These factors may have contributed to the spread of brucellosis in bovids in the dry zone. This infection might be an important cause of abortion in bovids in Sri Lanka. However, there is also evidence of other causes for abortion, repeat breeding and retained placenta.

  11. Decoupling of stream and vegetation solutes during the late stages of weathering: insights from elemental and Mg isotope trends at the Luquillo Critical Zone Observatory, Puerto Rico

    NASA Astrophysics Data System (ADS)

    Chapela Lara, M.; Schuessler, J. A.; Buss, H. L.; McDowell, W. H.

    2017-12-01

    During the evolution of the critical zone, the predominant source of nutrients to the vegetation changes from bedrock weathering to atmospheric inputs and biological recycling. In parallel, the architecture of the critical zone changes with time, promoting a change in water flow regime from near-surface porous flow during early weathering stages to more complex flow regimes modulated by clay-rich regolith during the late stages of weathering. As a consequence of these two concurrent processes, we can expect the predominant sources and pathways of solutes to the streams to also change during critical zone evolution. If this is true, we would observe a decoupling between the solutes used by the vegetation and those that determine the composition of the streams during the late stages of weathering, represented by geomorphically stable tropical settings. To test these hypotheses, we are analyzing the elemental and Mg isotopic composition of regolith and streams at the humid tropical Luquillo Critical Zone Observatory. We aim to trace the relative contributions of the surficial, biologically mediated pathways and the deeper, weathering controlled nutrient pathways. We also investigate the role of lithology on the solute decoupling between the vegetation and the stream, by examining two similar headwater catchments draining two different bedrocks (andesitic volcaniclastic and granitic). Our preliminary elemental and Mg isotope results are consistent with atmospheric inputs in the upper 2 m of regolith in both lithologies and with bedrock weathering at depth. During a short storm event ( 6 h), a headwater stream draining volcaniclastic bedrock showed a large variation in Mg and δ26Mg, correlated with total suspended solids, while another similar headwater granitic stream showed a much narrower variation. A larger stream draining volcaniclastic bedrock showed changes in Mg concentration in response to rain during the same storm event, but did not change in δ26Mg, suggesting the surficial-deep decoupling of solutes we observe in regolith profiles and headwater catchments might be overwhelmed by storage effects at increasing water residence times.

  12. Tracking natural and anthropogenic origins of dissolved arsenic during surface and groundwater interaction in a post-closure mining context: Isotopic constraints.

    PubMed

    Khaska, Mahmoud; Le Gal La Salle, Corinne; Verdoux, Patrick; Boutin, René

    2015-01-01

    Arsenic contamination of stream waters and groundwater is a real issue in Au-As mine environments. At the Salsigne Au-As mine, southern France, arsenic contamination persists after closure and remediation of the site. In this study, natural and anthropogenic arsenic inputs in surface water and groundwater are identified based on (87)Sr/(86)Sr, and δ(18)O and δ(2)H isotopic composition of water. In the wet season, downstream of the remediated zone, the arsenic contents in stream water and alluvial aquifer groundwater are high, with values in the order of 36 μg/L and 40 μg/L respectively, while upstream natural background average concentrations are around 4 μg/L. Locally down-gradient of the reclaimed area, arsenic concentrations in stream water showed 2 peaks, one during an important rainy event (101 mm) in the wet season in May, and a longer one over the dry period, reaching 120 and 110 μg/L respectively. The temporal variations in arsenic content in stream water can be explained i) during the dry season, by release of arsenic stored in the alluvial sediments through increased contribution from base flow and decreased stream flow and ii) during major rainy events, by mobilization of arsenic associated with important surface runoff. The (87)Sr/(86)Sr ratios associated with increasing arsenic content in stream waters downstream of the reclaimed area are significantly lower than that of the natural Sr inherited from Variscan formations. These low (87)Sr/(86)Sr ratios are likely to be associated with the decontaminating water treatment processes, used in the past and still at present, where CaO, produced from marine limestone and therefore showing a low (87)Sr/(86)Sr ratios, is used to precipitate Ca3(AsO4)2. The low Sr isotope signatures will then impact on the Sr isotope ratio of (1) the Ca-arsenate stored in tailing dams, (2) effluent currently produced by water treatment process and (3) groundwater draining from the overall site. Furthermore, Δ(2)H shows that the low (87)Sr/(86)Sr ratio, arsenic rich water is characterized by an evaporated signature suggesting a potential influence of water impacted by evaporation during storage in decantation lagoons. This study shows the suitability of Sr and stable isotopes of water as tracers to differentiate natural and anthropogenic sources of arsenic release or other trace elements from mining context where CaO is used for water treatment. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Tracking natural and anthropogenic origins of dissolved arsenic during surface and groundwater interaction in a post-closure mining context: Isotopic constraints

    NASA Astrophysics Data System (ADS)

    Khaska, Mahmoud; Le Gal La Salle, Corinne; Verdoux, Patrick; Boutin, René

    2015-06-01

    Arsenic contamination of stream waters and groundwater is a real issue in Au-As mine environments. At the Salsigne Au-As mine, southern France, arsenic contamination persists after closure and remediation of the site. In this study, natural and anthropogenic arsenic inputs in surface water and groundwater are identified based on 87Sr/86Sr, and δ18O and δ2H isotopic composition of water. In the wet season, downstream of the remediated zone, the arsenic contents in stream water and alluvial aquifer groundwater are high, with values in the order of 36 μg/L and 40 μg/L respectively, while upstream natural background average concentrations are around 4 μg/L. Locally down-gradient of the reclaimed area, arsenic concentrations in stream water showed 2 peaks, one during an important rainy event (101 mm) in the wet season in May, and a longer one over the dry period, reaching 120 and 110 μg/L respectively. The temporal variations in arsenic content in stream water can be explained i) during the dry season, by release of arsenic stored in the alluvial sediments through increased contribution from base flow and decreased stream flow and ii) during major rainy events, by mobilization of arsenic associated with important surface runoff. The 87Sr/86Sr ratios associated with increasing arsenic content in stream waters downstream of the reclaimed area are significantly lower than that of the natural Sr inherited from Variscan formations. These low 87Sr/86Sr ratios are likely to be associated with the decontaminating water treatment processes, used in the past and still at present, where CaO, produced from marine limestone and therefore showing a low 87Sr/86Sr ratios, is used to precipitate Ca3(AsO4)2. The low Sr isotope signatures will then impact on the Sr isotope ratio of (1) the Ca-arsenate stored in tailing dams, (2) effluent currently produced by water treatment process and (3) groundwater draining from the overall site. Furthermore, Δ2H shows that the low 87Sr/86Sr ratio, arsenic rich water is characterized by an evaporated signature suggesting a potential influence of water impacted by evaporation during storage in decantation lagoons. This study shows the suitability of Sr and stable isotopes of water as tracers to differentiate natural and anthropogenic sources of arsenic release or other trace elements from mining context where CaO is used for water treatment.

  14. Landslide-induced iron mobilisation shapes benthic accumulation of nutrients, trace metals and REE fractionation in an oligotrophic alpine stream

    NASA Astrophysics Data System (ADS)

    Johnston, Scott G.; Rose, Andrew L.; Burton, Edward D.; Webster-Brown, Jenny

    2015-01-01

    Large alpine landslides that entrain substantial organic material below the water table and create suspended floodplains may have long-term consequences for the mobilisation of redox sensitive elements, such as Fe, into streamwaters. In turn, the cycling of iron in aquatic systems can influence the fate of nutrients, alter primary productivity, enhance accumulation of trace metals and induce fractionation of rare earth elements (REE). In this study we examine a reach of a pristine oligotrophic alpine stream bracketing a 30 year-old landslide and explore the consequences of landslide-induced Fe mobilisation for aqueous geochemistry and the composition of benthic stream cobble biofilm. Elevated Fe2+ and Mn in landslide zone stream waters reflect inputs of circumneutral groundwater from the landslide debris-zone floodplain. Geochemical characteristics are consistent with reductive dissolution being a primary mechanism of Fe2+ and Mn mobilisation. Stream cobble biofilm in the landslide zone is significantly (P < 0.01) enriched in poorly crystalline Fe(III) (∼10-400 times background) and Mn (∼15-150 times background) (1 M HCl extractable; Fe(III)Ab). While the landslide zone accounts for less than ∼9% of the total stream length, we estimate it is responsible for approximately 60-80% of the stream's benthic biofilm load of poorly crystalline Fe(III) and Mn. Biofilm Fe(III) precipitates are comprised mainly of ferrihydrite, lepidocrocite and an organic-Fe species, while precipitate samples collected proximal to hyporheic seeps contain abundant sheath structures characteristic of the neutrophilic Fe(II)-oxidising bacteria Leptothrix spp. Stream-cobble Fe(III)-rich biofilm is accumulating PO43- (∼3-30 times background) and behaving as a preferential substrate for photosynthetic periphyton, with benthic PO43-, chlorophyll a, organic carbonHCl and total N all significantly positively correlated with Fe(III)Ab and significantly elevated within the landslide zone (P < 0.01). P K-edge XANES indicates P is associated with both ferric and Ca-phosphate minerals, while SEM-EDX elemental mapping of Fe(III) precipitates reveal strong spatial associations between P, Ca and Fe. Cobble Fe(III)-rich biofilm is also sorbing and accumulating multiple trace metals and REE. Within the landslide zone there are significant (P < 0.01) enrichments (up to ∼10-100 times background) for most trace metals examined here and metals display significant positive linear correlations with Fe(III)Ab on a log transformed basis. Stream cobble biofilm also exhibits distinct REE fractionation along the flow path, with light REE (La, Ce, Nd, Pr) preferentially partitioning to the Fe(III) and Mn-rich biofilm within the landslide zone. Accumulation of PO43- and trace metals in this relatively environmentally labile form may have implications for their bioavailability and downstream transport, but further research is required to assess possible ecological consequences. This study demonstrates the potential for large alpine landslides to encourage reach-scale circumneutral Fe mobilisation in adjacent streams, thereby shaping multiple aspects of benthic stream geochemistry for many years after the landslide event itself.

  15. Probing Subsurface and Stream Particle Composition Through Optical Analysis at the Eel River Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    Nghiem, A.; Thurnhoffer, B. M.; Bishop, J. K. B.; Kim, H.

    2014-12-01

    Particles constitute a significant portion of the flux weathered material from continents to ocean basins but little is understood about their seasonal dynamics particularly in subsurface and headwater stream environments. At the Eel River Critical Zone Observatory, located near the headwaters of the South Fork Eel River in the Angelo Coast Range Reserve (Northern California), groundwater from weathered bedrock and stream waters are sampled at a frequency of one to three days from three wells (Well 1 down-slope, Well 3 mid-slope, Well 10 upper-slope) and Elder Creek. Approximately one thousand samples collected by automated ISCO Gravity Filtration System (GFS; Kim et al. 2012, EST) since 2011 have been filtered through 0.45 μm 25 mm diameter Supor filters. Filters imaged under controlled lighting are analyzed for red, green, and blue optical density (OD) to enable rapid assessment of sample loading and color as a prelude to and selection aid for more labor-intensive ICP-MS and Scanning Electron Microscopic analysis. For example, samples with lower red OD relative to green and blue may correspond to samples high in Mn/Fe oxides. Optical imaging of the loaded filters provides a time-series over three years and color anomalies in these filters along with chemical analysis of dissolved and particulate filtrate is used to establish a method for calibrating optical data to interpret chemical composition of water and particles. Results are interpreted within a framework of environmental data such as rainfall, stream discharge and turbidity, and water table depth measured at the heavily monitored forested hillslope. Data from the four locations range up to 0.6 OD units with a typical detection limit of better than 0.01 OD units. At Well 10, wet season filter samples exhibit highest particle loading (OD ~ 0.3) with values rapidly decreasing during the dry season (OD < D.L.) water table recession. At Well 1, particle loads instantaneously reflect intense rain events. Applied at a larger scale, this method - if proven - may be used to estimate basin level particulate flux with an estimation of chemical composition in a highly efficient manner.

  16. Response of crayfish to hyporheic water availability and excess sedimentation

    USGS Publications Warehouse

    Dyer, Joseph J.; Worthington, Thomas A.; Brewer, Shannon K.

    2015-01-01

    Crayfish in many headwater streams regularly cope with seasonal drought. However, it is unclear how landscape changes affect the long-term persistence of crayfish populations. We designed two laboratory experiments to investigate the acute effects of common landscape stressors on crayfish: water withdrawal and sedimentation. The first experiment tested the interaction among water withdrawals (four 24-h water reductions of 0, 15, 30, or 45 cm) and two substrate treatments (pebble and cobble) on the burrowing depth of crayfish. The second experiment evaluated the effects of excess fine sediment (three treatments of 0, 45, and 90% sediment) and substrate type (cobble and pebble) on crayfish burrowing depth. Crayfish were able to burrow deeper into the simulated hyporheic zone in cobble substrate when compared to pebble. Crayfish subjected to greater water withdrawals in the pebble treatment were not able to reach the simulated hyporheic zone. Excess fine sediment reduced the depth that crayfish burrowed, regardless of substrate type. Results from this study suggest excess fine sediment may reduce crayfish persistence, particularly when seeking refuge during prolonged dry conditions.

  17. An alternative regionalization scheme for defining nutrient criteria for rivers and streams

    USGS Publications Warehouse

    Robertson, Dale M.; Saad, David A.; Wieben, Ann M.

    2001-01-01

    The environmental nutrient zone approach can be applied to specific states or nutrient ecoregions and used to develop criteria as a function of stream type. This approach can also be applied on the basis of environmental characteristics of the watershed alone rather than the general environmental characteristics from the region in which the site is located. The environmental nutrient zone approach will enable states to refine the basic nutrient criteria established by the USEPA by developing attainable criteria given the environmental characteristics where the streams are located.

  18. Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

    USGS Publications Warehouse

    Harvey, Judson W.; Fuller, Christopher C.

    1998-01-01

    We determined the role of the hyporheic zone (the subsurface zone where stream water and shallow groundwater mix) in enhancing microbially mediated oxidation of dissolved manganese (to form manganese precipitates) in a drainage basin contaminated by copper mining. The fate of manganese is of overall importance to water quality in Pinal Creek Basin, Arizona, because manganese reactions affect the transport of trace metals. The basin-scale role of the hyporheic zone is difficult to quantify because stream-tracer studies do not always reliably characterize the cumulative effects of the hyporheic zone. This study determined cumulative effects of hyporheic reactions in Pinal Creek basin by characterizing manganese uptake at several spatial scales (stream-reach scale, hyporheic-flow-path scale, and sediment-grain scale). At the stream-reach scale a one-dimensional stream-transport model (including storage zones to represent hyporheic flow paths) was used to determine a reach-averaged time constant for manganese uptake in hyporheic zones, 1/λs, of 1.3 hours, which was somewhat faster but still similar to manganese uptake time constants that were measured directly in centimeter-scale hyporheic flow paths (1/λh= 2.6 hours), and in laboratory batch experiments using streambed sediment (1/λ = 2.7 hours). The modeled depths of subsurface storage zones (ds = 4–17 cm) and modeled residence times of water in storage zones (ts = 3–12 min) were both consistent with direct measurements in hyporheic flow paths (dh = 0–15 cm, th = 1–25 min). There was also good agreement between reach-scale modeling and direct measurements of the percentage removal of dissolved manganese in hyporheic flow paths (fs = 8.9%, andfh = 9.3%rpar;. Manganese uptake experiments in the laboratory using sediment from Pinal Creek demonstrated (through comparison of poisoned and unpoisoned treatments) that the manganese removal process was enhanced by microbially mediated oxidation. The cumulative effect of hyporheic exchange in Pinal Creek basin was to remove approximately 20% of the dissolved manganese flowing out of the drainage basin. Our results illustrate that the cumulative significance of reactive uptake in the hyporheic zone depends on the balance between chemical reaction rates, hyporheic porewater residence time, and turnover of streamflow through hyporheic flow paths. The similarity between the hyporheic reaction timescale (1/λs ≈ 1.3 hours), and the hyporheic porewater residence timescale (ts ≈ 8 min) ensured that there was adequate time for the reaction to progress. Furthermore, it was the similarity between the turnover length for stream water flow through hyporheic flow paths (Ls = stream velocity/storage-zone exchange coefficient ≈ 1.3 km) and the length of Pinal Creek (L ≈ 7 km), which ensured that all stream water passed through hyporheic flow paths several times. As a means to generalize our findings to other sites where similar types of hydrologic and chemical information are available, we suggest a cumulative significance index for hyporheic reactions, Rs = λstsL/Ls (dimensionless); higher values indicate a greater potential for hyporheic reactions to influence geochemical mass balance. Our experience in Pinal Creek basin suggests that values of Rs > 0.2 characterize systems where hyporheic reactions are likely to influence geochemical mass balance at the drainage-basin scale.

  19. Design of Remediation Actions for Nutrient Mitigation in the Hyporheic Zone

    NASA Astrophysics Data System (ADS)

    Morén, I.; Wörman, A.; Riml, J.

    2017-11-01

    Although hyporheic exchange has been shown to be of great importance for the overall water quality of streams, it is rarely considered quantitatively in stream remediation projects. A main driver of hyporheic exchange is the hydraulic head fluctuation along the streambed, which can be enhanced by modifications of the streambed topography. Here we present an analytical 2-D spectral subsurface flow model to estimate the hyporheic exchange associated with streambed topographies over a wide range of spatial scales; a model that was validated using tracer-test-results and measurements of hydraulic conductivity. Specifically, engineered steps in the stream were shown to induce a larger hyporheic exchange velocity and shorter hyporheic residence times compared to the observed topography in Tullstorps Brook, Sweden. Hyporheic properties were used to parameterize a longitudinal transport model that accounted for reactions in terms of first-order decay and instantaneous adsorption. Theoretical analyses of the mitigation effect for nitrate due to denitrification in the hyporheic zone show that there is a Damköhler number of the hyporheic zone, associated with several different stream geomorphologies, that optimizes nitrate mass removal on stream reach scale. This optimum can be limited by the available hydraulic head gradient given by the slope of the stream and the geological constraints of the streambed. The model illustrates the complex interactions between design strategies for nutrient mitigation, hyporheic flow patterns, and stream biogeochemistry and highlights the importance to diagnose a stream prior remediation, specifically to evaluate if remediation targets are transport or reaction controlled.

  20. Hyporheic Passive Flux Meters Reveal Inverse Vertical Zonation and High Seasonality of Nitrogen Processing in an Anthropogenically Modified Stream (Holtemme, Germany)

    NASA Astrophysics Data System (ADS)

    Kunz, Julia Vanessa; Annable, Michael D.; Rao, Suresh; Rode, Michael; Borchardt, Dietrich

    2017-12-01

    Transformation and retention of nitrogen and other biologically reactive solutes in the hyporheic zones of running water contribute to an essential ecosystem service. However, the synoptic impact of intense agricultural or urban land-uses, elevated nutrient loading, flow alterations, riparian clear-cutting, and channelization on the source-sink behavior of solutes in hyporheic zones remains largely uncharacterized and unquantified. Therefore, we studied nutrient dynamics in a hydromorphologically and chemically modified stream reach using a new monitoring approach allowing the simultaneous measurement of nutrient and water flux through a screened area in the subsurface of rivers (hyporheic passive flux meter, HPFM). With HPFMs we directly assessed time-integrated lateral hyporheic nitrate fluxes during early spring and midsummer covering different temperature and discharge regimes. Contrary to our expectations, higher stream discharge coincided with substantially lower hyporheic exchange rates. While in streams featuring a natural morphology, bed form induced exchange commonly increases with surface flow, the influence of groundwater level was dominant in this reach. Furthermore, in contrast to less impacted environments, where progressive substrate depletion with depths reduces metabolic rates in the subsurface, we identified not the upper, but the intermediate layer of the hyporheic zone as hot spot of nutrient turnover. Overall, the hyporheic zone at the study site functioned partly as nitrate source, partly as a sink. Neither of the commonly used determinants redox state and residence time could explain this source or sink function. Our results give clear evidence to carefully transfer the knowledge of hyporheic zone processes from "natural" systems to anthropologically modified streams.

  1. Effects of selenium on mallard duck reproduction and immune function

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Whiteley, P.L.; Yuill, T.M.; Fairbrother, A.

    Selenium from irrigation drain water and coal-fired power stations is a significant environmental contaminant in some regions of the USA. The objectives were to examine whether selenium-exposed waterfowl had altered immune function, disease resistance, or reproduction. Pairs of adult mallards were exposed for 95-99 days on streams with sodium selenite-treated water at 10 and 30 ppb, or on untreated streams. Selenium biomagnified through the food chain to the ducks. Disease resistance was decreased in ducklings hatched on the streams and challenged with duck hepatitis virus 1 (DHV1) when 15-days old. Liver selenium concentrations for these ducklings on the 10 andmore » 30 ppb streams was 3.6 and 7.6 ppm dry weight, respectively. Mortality of ducklings purchased when 7-days old, exposed to selenium for 14 days, and challenged when 22-days old was not affected. However, their selenium exposure was lower (liver selenium 4.1 ppm dry weight for the 30 ppb stream). Five parameters of immune function were measured in adult ducks. Phagocytosis of killed Pasteurella multocida by blood heterophils and monocytes, and blood monocyte concentrations were higher in adult males following 84 days exposure to 30 ppb selenium. Their liver selenium concentrations were 11.1 ppm dry weight after 95-99 days exposure.« less

  2. Flooding in ephemeral streams: incorporating transmission losses

    USDA-ARS?s Scientific Manuscript database

    Stream flow in semiarid lands commonly occurs as a form of flash floods in dry ephemeral stream beds. The goal of this research is to couple hydrological and hydraulic models treats channel transmission losses and test the methodology in the USDA-ARS Walnut Gulch Experimental Watershed (WGEW). For h...

  3. LAND USE AND LOTIC DIATOM ASSEMBLAGES: A MULTI-SPATIAL AND TEMPORAL ASSESSMENT

    EPA Science Inventory

    We assessed the effects of land-use at multiple spatial scales (e.g., catchment, stream network, and stream reach) on periphyton from 25 wadeable streams along a land-use gradient in the Willamette River Basin, Oregon, in a dry season. Additional water chemistry samples were col...

  4. Nitrogen biogeochemistry in urban wetlands and bioretention systems: The evolving roles of urban stormwater management practices (Invited)

    NASA Astrophysics Data System (ADS)

    Stander, E. K.; Borst, M.; Ehrenfeld, J. G.; O'Connor, T. P.; Rowe, A. A.

    2009-12-01

    Traditional stormwater management practices, designed and constructed to rapidly and efficiently route runoff away from established infrastructure, have resulted in the disruption of natural drainage patterns in urban landscapes. The modified in-stream flow incises urban streams and reduces regional groundwater recharge, thus altering hydrologic patterns and regimes in urban wetlands and riparian zones. Water table dynamics and in situ nitrogen cycling processes were quantified in 14 palustrine, forested wetlands and correlated with watershed-scale land cover metrics in urban northern New Jersey. Variability in nitrogen cycling process rates was, in some cases, explained by altered hydrological regimes. However, land cover and hydrologic characteristics did not always exhibit the predicted effects, as demonstrated by dry and/or flashy water tables in less developed watersheds and denitrification rates that did not always reflect hydrological conditions. Inorganic nitrogen inputs and outputs were characterized in throughfall and soil leachate in nine of the 14 wetlands. Atmospheric nitrogen deposition rates were higher in wetlands located in more impervious and densely populated urban sub-watersheds, but nitrate losses through leaching were generally low and did not correlate with landscape-level descriptors of urban intensity. Two wetlands did display net loss of nitrate, and the results of dual isotope analysis suggested the direct pass-through of atmospheric nitrate on four sampling dates in two sites; these findings point to decreased nitrate retention capacity in some urban wetlands. New stormwater management practices designed to mimic natural drainage patterns are currently being developed and implemented in existing urban watersheds and new developments. These practices, which include rain gardens, pervious pavement, and green roofs, are intended to reduce peak flows to urban streams and, in many cases, also provide water quality functions. Rain gardens in particular have a documented ability to remove heavy metals and phosphorus from urban stormwater runoff, but their coarse-textured, low organic matter content soils are less able to remove nitrate through denitrification. Research at the US Environmental Protection Agency explores the use of media carbon amendments and deep zones of saturation to facilitate denitrification by providing labile carbon and anoxic conditions in experimental rain garden mesocosms. Initial results highlight the importance of conducting bench-scale testing of bioretention media before installation in full-scale, working rain gardens, particularly when media characteristics have been modified to promote stressor removal. If these low impact development practices can increase groundwater recharge and reduce stream incision, natural hydrologic regimes may be restored to urban wetlands and riparian zones.

  5. Hydrogeology of a Danish Riparian Lowland: the Importance of Groundwater Upwelling on Nitrate Removal

    NASA Astrophysics Data System (ADS)

    Steiness, M.; van't Veen, S. G. W.; Jessen, S.; Engesgaard, P. K.

    2016-12-01

    Riparian zones are critical interfaces between streams and uplands with many of the characteristics for being key areas for nitrate removal. The hydrogeology is a controlling factor for the source, flow paths, magnitude of groundwater discharge to the stream, nitrate loading, and therefore the occurrence of "hot spots" with increased denitrification. A riparian lowland was investigated through field studies (geophysics, hydrogeology), water quality assessment, and flow and reactive transport modelling. One of the objectives was to understand the role of the landscape and hydrogeology on diffusive versus focused groundwater discharge and also nitrate removal. The investigated riparian zone is characterized by diffusive flow of groundwater to the stream from the northern bank (from a maize field) and groundwater upwelling in several places with overland flow to the stream from south (wetland area). Nitrate is effectively removed by pyrite oxidation (as shown by the reactive transport model high sulphate concentrations) on the northern side, whereas the groundwater-fed springs carry up to 74 mg/L nitrate. Groundwater flow modeling shows that upwelling may account for almost 25 % of the flow to the stream. Two other riparian zones were subsequently included and, on the catchment scale, the occurrence of diffusive and focused discharge is found to be common suggesting that riparian zones in this area are only partly effective in removing nitrate.

  6. Developing a novel approach to analyse the regimes of temporary streams and their controls on aquatic biota

    NASA Astrophysics Data System (ADS)

    Gallart, F.; Prat, N.; García-Roger, E. M.; Latron, J.; Rieradevall, M.; Llorens, P.; Barberá, G. G.; Brito, D.; de Girolamo, A. M.; Lo Porto, A.; Neves, R.; Nikolaidis, N. P.; Perrin, J. L.; Querner, E. P.; Quiñonero, J. M.; Tournoud, M. G.; Tzoraki, O.; Froebrich, J.

    2011-10-01

    Temporary streams are those water courses that undergo the recurrent cessation of flow or the complete drying of their channel. The biological communities in temporary stream reaches are strongly dependent on the temporal changes of the aquatic habitats determined by the hydrological conditions. The use of the aquatic fauna structural and functional characteristics to assess the ecological quality of a temporary stream reach can not therefore be made without taking into account the controls imposed by the hydrological regime. This paper develops some methods for analysing temporary streams' aquatic regimes, based on the definition of six aquatic states that summarize the sets of mesohabitats occurring on a given reach at a particular moment, depending on the hydrological conditions: flood, riffles, connected, pools, dry and arid. We used the water discharge records from gauging stations or simulations using rainfall-runoff models to infer the temporal patterns of occurrence of these states using the developed aquatic states frequency graph. The visual analysis of this graph is complemented by the development of two metrics based on the permanence of flow and the seasonal predictability of zero flow periods. Finally, a classification of the aquatic regimes of temporary streams in terms of their influence over the development of aquatic life is put forward, defining Permanent, Temporary-pools, Temporary-dry and Episodic regime types. All these methods were tested with data from eight temporary streams around the Mediterranean from MIRAGE project and its application was a precondition to assess the ecological quality of these streams using the current methods prescribed in the European Water Framework Directive for macroinvertebrate communities.

  7. Effectiveness of streamside management zones on water quality: pretreatment measurements

    Treesearch

    J.L. Boggs; G. Sun; S.G. McNulty; W. Swartley; E. Treasure

    2008-01-01

    The objective of this paired watershed study is to quantify the effects of upland forest harvesting and Streamside Management Zones (SMZs) on stream water quantity and quality in North Carolina. Four watersheds ranging from 12 to 28 hectares (i.e., two on Hill Forest and two on Umstead Research Farm) with perennial stream channels were gauged for flow monitoring and...

  8. Assessment of streamside management zones for conserving benthic macroinvertebrate communities following timber harvest in eastern Kentucky headwater catchments

    Treesearch

    Joshua Adkins; Christopher Barton; Scott Grubbs; Jeffrey Stringer; Randy Kolka

    2016-01-01

    Headwater streams generally comprise the majority of stream area in a watershed and can have a strong influence on downstream food webs. Our objective was to determine the effect of altering streamside management zone (SMZ) configurations on headwater aquatic insect communities. Timber harvests were implemented within six watersheds in eastern Kentucky. The SMZ...

  9. The transition from riparian to upland forest plant communities on headwater streams in the southern Sierra Nevada, California, United States

    Treesearch

    Christopher R. Dolanc; Carolyn T. Hunsaker

    2017-01-01

    Abstract. Fixed-width buffer zones on rivers and streams are designed to protect the diverse riparian community and its important function in the ecosystem. However, recent data suggest that riparian areas of some western forests have become more fire prone because of restrictions on fuel reduction treatments within buffer zones....

  10. Silvicultural management within streamside management zones of intermittent streams: effects on decomposition, productivity, nutrient cycling, and channel vegetation

    Treesearch

    R. Governo; B. G. Lockaby; Robert B. Rummer; C. Colson

    2004-01-01

    The purpose of this watershed study on three intermittent streams was to evaluate responses of riparian processes to three streamside management zone (SMZ) treatments; no harvest, clearcut, and partial hawest (50% basal area removal). Riparian response variables measured included litter$all, leaf litter decomposition, understory vegetation, soil temperature and water...

  11. Watershed scale assessment of the impact of forested riparian zones on stream water quality

    Treesearch

    J. A. Webber; K. W. J. Williard; M. R. Whiles; M. L. Stone; J. J. Zaczek; D. K. Davie

    2003-01-01

    Federal and state land management agencies have been promoting forest and grass riparian zones to combat non-point source nutrient and sediment pollution of our nations' waters. The majority of research examining the effectiveness of riparian buffers at reducing nutrient and sediment inputs to streams has been conducted at the field scale. This study took a...

  12. Coupled Spatio-Temporal Patterns of Solute Transport, Metabolism and Nutrient Uptake in Streams

    NASA Astrophysics Data System (ADS)

    Kurz, M. J.; Schmidt, C.

    2017-12-01

    Slower flow velocities and longer residence times within stream transient storage (TS) zones facilitate interaction between solutes and microbial communities, potentially increasing local rates of metabolic activity. Multiple factors, including channel morphology and substrate, variable hydrology, and seasonal changes in biological and physical parameters, result in changes in the solute transport dynamics and reactivity of TS zones over time and space. These changes would be expected to, in turn, influence rates of whole-stream ecosystem functions such as metabolism and nutrient uptake. However, the linkages between solute transport and ecosystem functioning within TS zones, and the contribution of TS zones to whole-stream functioning, are not always so straight forward. This may be due, in part, to methodological challenges. In this study we investigated the influence of stream channel hydro-morphology and substrate type on reach (103 m) and sub-reach (102 m) scale TS and ecosystem functioning. Patterns in solute transport, metabolism and nitrate uptake were tracked from April through October in two contrasting upland streams using several methods. The two streams, located in the Harz Mountains, Germany, are characterized by differing size (0.02 vs. 0.3 m3/s), dominant stream channel substrate (bedrock vs. alluvium) and sub-reach morphology (predominance of pools, riffles and glides). Solute transport parameters and respiration rates at the reach and sub-reach scale were estimated monthly from coupled pulse injections of the reactive tracer resazurin (Raz) and conservative tracers uranine and salt. Raz, a weakly fluorescent dye, irreversibly transforms to resorufin (Rru) under mildly reducing conditions, providing a proxy for aerobic respiration. Daily rates of primary productivity, respiration and nitrate retention at the reach scale were estimated using the diel cycles in dissolved oxygen and nitrate concentrations measured by in-situ sensors. Preliminary results indicate distinct differences in common metrics of TS and Raz transformation rates within and between the two streams. However, transformation rates and TS metrics are not well correlated, indicating complexities in the relationship between solute transport dynamics and metabolism in streams.

  13. Developing semi-analytical solution for multiple-zone transient storage model with spatially non-uniform storage

    NASA Astrophysics Data System (ADS)

    Deng, Baoqing; Si, Yinbing; Wang, Jia

    2017-12-01

    Transient storages may vary along the stream due to stream hydraulic conditions and the characteristics of storage. Analytical solutions of transient storage models in literature didn't cover the spatially non-uniform storage. A novel integral transform strategy is presented that simultaneously performs integral transforms to the concentrations in the stream and in storage zones by using the single set of eigenfunctions derived from the advection-diffusion equation of the stream. The semi-analytical solution of the multiple-zone transient storage model with the spatially non-uniform storage is obtained by applying the generalized integral transform technique to all partial differential equations in the multiple-zone transient storage model. The derived semi-analytical solution is validated against the field data in literature. Good agreement between the computed data and the field data is obtained. Some illustrative examples are formulated to demonstrate the applications of the present solution. It is shown that solute transport can be greatly affected by the variation of mass exchange coefficient and the ratio of cross-sectional areas. When the ratio of cross-sectional areas is big or the mass exchange coefficient is small, more reaches are recommended to calibrate the parameter.

  14. Effects of riparian buffer width on wood loading in headwater streams after repeated forest thinning

    Treesearch

    Julia I. Burton; Deanna H. Olson; Klaus J. Puettmann

    2016-01-01

    Forested riparian buffer zones are used in conjunction with upland forest management, in part, to provide for the recruitment for large wood to streams. Small headwater streams account for the majority of stream networks in many forested regions. Yet, our understanding of how riparian buffer width influences wood dynamics in headwater streams is relatively less...

  15. System and method for producing metallic iron

    DOEpatents

    Bleifuss, Rodney L; Englund, David J; Iwasaki, Iwao; Fosnacht, Donald R; Brandon, Mark M; True, Bradford G

    2013-09-17

    A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.

  16. Effects of upland disturbance and instream restoration on hydrodynamics and ammonium uptake in headwater streams

    USGS Publications Warehouse

    Roberts, B.J.; Mulholland, P.J.; Houser, J.N.

    2007-01-01

    Delivery of water, sediments, nutrients, and organic matter to stream ecosystems is strongly influenced by the catchment of the stream and can be altered greatly by upland soil and vegetation disturbance. At the Fort Benning Military Installation (near Columbus, Georgia), spatial variability in intensity of military training results in a wide range of intensities of upland disturbance in stream catchments. A set of 8 streams in catchments spanning this upland disturbance gradient was selected for investigation of the impact of disturbance intensity on hydrodynamics and nutrient uptake. The size of transient storage zones and rates of NH4+ uptake in all study streams were among the lowest reported in the literature. Upland disturbance did not appear to influence stream hydrodynamics strongly, but it caused significant decreases in instream nutrient uptake. In October 2003, coarse woody debris (CWD) was added to 1/2 of the study streams (spanning the disturbance gradient) in an attempt to increase hydrodynamic and structural complexity, with the goals of enhancing biotic habitat and increasing nutrient uptake rates. CWD additions had positive short-term (within 1 mo) effects on hydrodynamic complexity (water velocity decreased and transient storage zone cross-sectional area, relative size of the transient storage zone, fraction of the median travel time attributable to transient storage over a standardized length of 200 m, and the hydraulic retention factor increased) and nutrient uptake (NH4+ uptake rates increased). Our results suggest that water quality in streams with intense upland disturbances can be improved by enhancing instream biotic nutrient uptake capacity through measures such as restoring stream CWD. ?? 2007 by The North American Benthological Society.

  17. Metathesis process for preparing an alpha, omega-functionalized olefin

    DOEpatents

    Burdett, Kenneth A.; Mokhtarzadeh, Morteza; Timmers, Francis J.

    2010-10-12

    A cross-metathesis process for preparing an .alpha.,.omega.-functionalized olefin, such as methyl 9-decenoate, and an .alpha.-olefin having three or more carbon atoms, such as 1-decene. The process involves contacting in a first reaction zone an .alpha.-functionalized internal olefin, such as methyl oleate, and an .alpha.-olefinic monomer having three or more carbon atoms, such as 1-decene, with a first metathesis catalyst to prepare an effluent stream containing the .alpha.,.omega.-functionalized olefin, such as methyl 9-decenoate, an unfunctionalized internal olefin, such as 9-octadecene, unconverted reactant olefins, and optionally, an .alpha.,.omega.-difunctionalized internal olefinic dimer, such as dimethyl 9-octadecen-1,18-dioate; separating said effluent streams; then contacting in a second reaction zone the unfunctionalized internal olefin with ethylene in the presence of a second metathesis catalyst to obtain a second product effluent containing the .alpha.-olefinic monomer having three or more carbon atoms; and cycling a portion of the .alpha.-olefinic monomer stream(s) to the first zone.

  18. Assessment of Agroforestry Trees in Dry-land Savanna Supports Ecohydrologic Separation

    NASA Astrophysics Data System (ADS)

    Ceperley, Natalie; Mande, Theophile; Van de Giesen, Nick; Tyler, Scott; Parlange, Marc

    2016-04-01

    We use stable isotopes of water to demonstrate the ecohydrologic separation, or the plant controlled compartmentalization, of different water sources in a catchment in South Eastern Burkina Faso. We analyze water extracted from the groundwater, stream water, precipitation, perched aquifer, xylem water of agroforestry trees, and sub-canopy soil water over a 6 year period to explore how the separation affects different components of the system over time. The ratio between deuterium and O18 allows us to assess whether the water that plants use is the same as the water that recharges the aquifer and runs off in the stream. Water extracted from the tree at leaf out in February corresponded to deuterium and O18 concentrations of the groundwater, a drop from its dry season, enriched, levels which mimicked the soil water. Examination of the isotopic signature suggests that the size of tree plays an important role in duration and timing of this leaf-out as well as the degree of enrichment during the peak of the dry season. Dates of leaf out were confirmed by analyzing sub-canopy radiation and photographs. Water extracted from roots suggests that the trees are performing hydraulic redistribution, or lifting the ground water and 'sharing it' with the rooting zone soil during the dry season. The enriched level of xylem, in this case, is a product of water loss and enrichment along the travel path of the water from the roots to the tip of the branch, as evidenced by the variation according to size of tree. Vapor pressure deficit, sap flow, soil water, and soil moisture interactions support this picture of interacting controls, separate from hydrologic triggers on the water movement in the tree. A second round of sampling focused on the leaf out period by extracting and analyzing stem water from throughout the canopy during the leaf out. Simultaneous large eddy correlation revealed high levels of latent energy flux, even during the dry season. Our isotope analysis allowed us to conclude that tree level transpiration explains this discrepancy since it does not access the same reservoirs of water as the rest of the catchment. Most current land surface models do not differentiate between different reservoirs of water.

  19. Environmental conditions and biotic interactions influence ecosystem structure and function in a drying stream

    USGS Publications Warehouse

    Ludlam, J.P.; Magoulick, D.D.

    2010-01-01

    Benthic consumers influence stream ecosystem structure and function, but these interactions depend on environmental context. We experimentally quantified the effects of central stoneroller minnows (Campostoma anomalum (Rafinesque) and Meek's crayfish (Orconectes meeki meeki (Faxon)) on benthic communities using electric exclusion quadrats in Little Mulberry Creek before (June) and during (August) seasonal stream drying. Unglazed ceramic tiles were deployed in June and August to measure periphyton and invertebrate abundance, and leafpack decomposition and primary production were also measured in August. Relationships between stoneroller and crayfish density and the size of consumer effects were evaluated with multiple linear regression models. Average chlorophyll a abundance was greater on exposed than exclusion tiles in August, but not in June. Sediment dry mass, periphyton ash-free dry mass (AFDM), and chironomid densities on tiles did not differ among treatments in either period. Leaf packs decayed faster in exposed than exclusion treatments (kexposed = 0.038 ?? 0.013, kexclusion = 0.007 ?? 0.002), but consumer effects were stronger in some pools than others. Leafpack invertebrate biomass and abundance and tile primary productivity did not differ among treatments. Consumer effects on chlorophyll a were related to crayfish and stoneroller density, and effects on chironomid density were related to stoneroller density. These results contrast with a previous exclusion experiment in Little Mulberry Creek that demonstrated strong consumer effects. The influence of stream drying on consumer effects appears to have been reduced by strong spates, underscoring the importance of conducting multi-year studies to determine the magnitude of variability in ecological interactions. ?? US Government: USGS 2010.

  20. Integrated assessment of sources, chemical stressors and stream quality along a groundwater fed stream system

    NASA Astrophysics Data System (ADS)

    Løgstrup Bjerg, Poul; Sonne, Anne T.; Rønde, Vinni; McKnight, Ursula S.

    2016-04-01

    Streams are impacted by significant contamination at the catchment scale, as they are often locations of multiple chemical stressor inputs. The European Water Framework Directive requires EU member states to ensure good chemical and ecological status of surface water bodies by 2027. This requires monitoring of stream water quality, comparison with environmental quality standards (EQS) and assessment of ecological status. However, the achievement of good status of stream water also requires a strong focus on contaminant sources, pathways and links to stream water impacts, so source management and remedial measures can be implemented. Fate and impacts of different contaminant groups are governed by different processes and are dependent on the origin (geogenic, anthropogenic), source type (point or diffuse) and pathway of the contaminant. To address this issue, we identified contaminant sources and chemical stressors on a groundwater-fed stream to quantify the contaminant discharges, link the chemical impact and stream water quality and assess the main chemical risk drivers in the stream system potentially driving ecological impact. The study was conducted in the 8 m wide Grindsted stream (Denmark) along a 16 km stream stretch that is potentially impacted by two contaminated sites (Grindsted Factory site, Grindsted Landfill), fish farms, waste water discharges, and diffuse sources from agriculture and urban areas. Water samples from the stream and the hyporheic zone as well as bed sediment samples were collected during three campaigns in 2012 and 2014. Data for xenobiotic organic groundwater contaminants, pesticides, heavy metals, general water chemistry, physical conditions and stream flow were collected. The measured chemical concentrations were converted to toxic units (TU) based on the 48h acute toxicity tests with D. magna. The results show a substantial impact of the Grindsted Factory site at a specific stretch of the stream. The groundwater plume caused elevated concentrations of chlorinated ethenes, benzene and site specific pharmaceuticals in both the hyporheic zone and the stream water. Observed stream water vinyl chloride concentrations (up to 6 μg/L) are far above the Danish EQS (0.05 μg/L) for several km downstream of the discharge area. For heavy metals, comparison with EQS in stream water, the hyporheic zone and streambed showed concentrations around or above the threshold values for barium, copper, lead, nickel and zinc. The calculated TU was generally similar along the stream, but for arsenic and nickel higher values were observed where the groundwater plume discharges into the stream. Also, log TU sum values for organic contaminants were elevated in both the hyporheic zone and stream. Thus, the overall chemical stress in the main discharge area is much higher than upstream, while it gradually decreases downstream. In conclusion, this work clearly shows that groundwater contaminant plumes can impact stream water quality significantly in discharge areas, and extend far downstream. A surprisingly high impact of heavy metals with diffuse and/or biogenic origin on stream quality was identified. This work highlights the importance of a holistic assessment of stream water quality to identify and quantify the main contaminant sources and resulting chemical stream stressors leading to potential ecological impacts.

  1. Contrasting patterns of groundwater evapotranspiration in grass and tree dominated riparian zones of a temperate agricultural catchment

    NASA Astrophysics Data System (ADS)

    Satchithanantham, Sanjayan; Wilson, Henry F.; Glenn, Aaron J.

    2017-06-01

    Consumptive use of shallow groundwater by phreatophytic vegetation is a significant part of the water budget in many regions, particularly in riparian areas. The influence of vegetation type on groundwater level fluctuations and evapotranspiration has rarely been quantified for contrasting plant communities concurrently although it has implications for downstream water yield and quality. Hourly groundwater evapotranspiration (ETG) rates were estimated for grass and tree riparian vegetation in southwestern Manitoba, Canada using two modified White methods. Groundwater table depth was monitored in four 21 m transects of five 3 m deep monitoring wells in the riparian zone of a stream reach including tree (Acer negundo; boxelder) and grass (Bromus inermis; smooth brome) dominated segments. The average depths to the groundwater table from the surface were 1.4 m and 1 m for the tree and grass segments, respectively, over the two-year study. During rain free periods of the growing season ETG was estimated for a total of 70 days in 2014 and 79 days in 2015 when diurnal fluctuations were present in groundwater level. Diurnal groundwater level fluctuations were observed during dry periods under both segments, however, ETG was significantly higher (p < 0.001) under trees compared to grass cover in 2014 (a wet year with 72% higher than normal growing season precipitation) and 2015 (a drier year with 15% higher than normal growing season precipitation). The two methods used to estimate ETG produced similar daily and seasonal values for the two segments. In 2014, total ETG was approximately 50% (148 mm) and 100% (282-285 mm) of reference evapotranspiration (ETref, 281 mm) for the grass and tree segments, respectively. In 2015, total ETG was approximately 40% (106-127 mm) and 120% (369-374 mm) of ETref (307 mm) for the grass and tree segments, respectively. Results from the study show the tree dominated portions of the stream reach consumed approximately 2.4 ML ha-1 yr-1 more groundwater than a common forage grass. These findings have land management implications for regional water budgets during wet periods when flood mitigation is desirable and dry years when water scarcity is a concern.

  2. MODELING STREAM-AQUIFIER INTERACTIONS WITH LINEAR RESPONSE FUNCTIONS

    EPA Science Inventory

    The problem of stream-aquifer interactions is pertinent to conjunctive-use management of water resources and riparian zone hydrology. Closed form solutions are derived for stream-aquifer interactions in rates and volumes expressed as convolution integrals of impulse response and ...

  3. Novelty and its ecological implications to dry forest functioning and conservation

    Treesearch

    Ariel Lugo; Heather Erickson

    2017-01-01

    Tropical and subtropical dry forest life zones support forests with lower stature and species richness than do tropical and subtropical life zones with greater water availability. The number of naturalized species that can thrive and mix with native species to form novel forests in dry forest conditions in Puerto Rico and the US Virgin Islands is lower than in other...

  4. Standard for Ground Vehicle Mobility

    DTIC Science & Technology

    2005-02-01

    Zone Dry climates (2), humid mesothermal (3), See Appendix A humid microthermal (4), undifferentiated highland (6) Condition Dry, wet, snow See...represent the Dry, the Humid Mesothermal, and the Humid Microthermal climate zones, respectively. Scenarios ERDC-GSL was sponsored by WARSIM to...Coast D. Humid Microthermal Climates Humid Continental, Warm Summer, Humid Continental, Cool Summer, Sub-Arctic E. Polar Climates Tundra, Ice Caps F

  5. Development of stream-subsurface flow module in sub-daily simulation of Escherichia coli using SWAT

    NASA Astrophysics Data System (ADS)

    Kim, Minjeong; Boithias, Laurie; Cho, Kyung Hwa; Silvera, Norbert; Thammahacksa, Chanthamousone; Latsachack, Keooudone; Rochelle-Newall, Emma; Sengtaheuanghoung, Oloth; Pierret, Alain; Pachepsky, Yakov A.; Ribolzi, Olivier

    2017-04-01

    Water contaminated with pathogenic bacteria poses a large threat to public health, especially in the rural areas in the tropics where sanitation and drinking water facilities are often lacking. Several studies have used the Soil and Water Assessment Tool (SWAT) to predict the export of in-stream bacteria at a watershed-scale. However, SWAT is limited to in-stream processes, such as die-off, resuspension and, deposition; and it is usually implemented on a daily time step using the SCS Curve Number method, making it difficult to explore the dynamic fate and transport of bacteria during short but intense events such as flash floods in tropical humid montane headwaters. To address these issues, this study implemented SWAT on an hourly time step using the Green-Ampt infiltration method, and tested the effects of subsurface flow (LATQ+GWQ in SWAT) on bacterial dynamics. We applied the modified SWAT model to the 60-ha Houay Pano catchment in Northern Laos, using sub-daily rainfall and discharge measurements, electric conductivity-derived fractions of overland and subsurface flows, suspended sediments concentrations, and the number of fecal indicator organism Escherichia coli monitored at the catchment outlet from 2011 to 2013. We also took into account land use change by delineating the watershed with the 3-year composite land use map. The results show that low subsurface flow of less than 1 mm recovered the underestimation of E. coli numbers during the dry season, while high subsurface flow caused an overestimation during the wet season. We also found that it is more reasonable to apply the stream-subsurface flow interaction to simulate low in-stream bacteria counts. Using fecal bacteria to identify and understand the possible interactions between overland and subsurface flows may well also provide some insight into the fate of other bacteria, such as those involved in biogeochemical fluxes both in-stream and in the adjacent soils and hyporheic zones.

  6. Electron heating within interaction zones of simple high-speed solar wind streams

    NASA Technical Reports Server (NTRS)

    Feldman, W. C.; Asbridge, J. R.; Bame, S. J.; Gosling, J. T.; Lemons, D. S.

    1978-01-01

    In the present paper, electron heating within the high-speed portions of three simple stream-stream interaction zones is studied to further our understanding of the physics of heat flux regulation in interplanetary space. To this end, the thermal signals present in the compressions at the leading edges of the simple high-speed streams are analyzed, showing that the data are inconsistent with the Spitzer conductivity. Instead, a polynomial law is found to apply. Its implication concerning the mechanism of interplanetary heat conduction is discussed, and the results of applying this conductivity law to high-speed flows inside of 1 AU are studied. A self-consistent model of the radial evolution of electrons in the high-speed solar wind is proposed.

  7. Hydrology and Hyporheic Nitrogen Biogeochemistry in a Geomorphically Degraded Urban Stream

    EPA Science Inventory

    Few studies have investigated the relationship between hydrology and nitrogen biogeochemistry in hyporheic zones of degraded urban streams despite significant national efforts to restore such streams in attempts to improve the nutrient uptake functions in these ecosystems. We ex...

  8. Effect of deforestation on stream water chemistry in the Skrzyczne massif (the Beskid Śląski Mountains in southern Poland).

    PubMed

    Kosmowska, Amanda; Żelazny, Mirosław; Małek, Stanisław; Siwek, Joanna Paulina; Jelonkiewicz, Łukasz

    2016-10-15

    The purpose of the study was to identify the factors affecting stream water chemistry in the small mountain catchments deforested to varying degrees, from 98.7 to 14.1%, due to long-term acid deposition. Water samples were collected monthly in 2013 and 2014 from 17 streams flowing across three distinct elevation zones in the Skrzyczne massif (Poland): Upper, Middle and Lower Forest Zone. Chemical and physical analyses, including the pH, electrical conductivity (EC), total mineral content (Mt), water temperature, and the concentrations of Ca(2+), Mg(2+), Na(+), K(+), HCO3(-), SO4(2-), Cl(-), and NO3(-), were conducted. Based on Principal Component Analysis (PCA), the most important factor affecting water chemistry was human impact associated with changes in pH, SO4(2-) concentration, and the concentration of most of the main ions. The substantial acidity of the studied environment contributed to the exclusion of natural factors, associated with changes in discharge, from the list of major factors revealed by PCA. All of the streams were characterized by very low EC, Mt, and low concentrations of the main ions such as Ca(2+) and HCO3(-). This is the effect of continuous leaching of solutes from the soils by acidic precipitation. The lowest parameter values were measured for the streams situated in the Upper Forest Zone, which is associated with greater acid deposition at the higher elevations. In the streams located in the Upper Forest Zone, a higher percentage of SO4(2-) occurred than in the streams situated in the Middle and Lower Forest Zones. However, the largest share of SO4(2-) was measured in the most deforested catchment. The saturation of the studied deforested catchment with sulfur compounds is reflected by a positive correlation between SO4(2-) and discharge. Hence, a forest acts as a natural buffer that limits the level of acidity in the natural environment caused by acidic atmospheric deposition. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Riparian zone flowpath dynamics during snowmelt in a small headwater catchment

    NASA Astrophysics Data System (ADS)

    McGlynn, B. L.; McDonnell, J. J.; Shanley, J. B.; Kendall, C.

    1999-09-01

    The hydrology of the near-stream riparian zone in upland humid catchments is poorly understood. We examined the spatial and temporal aspects of riparian flowpaths during snowmelt in a headwater catchment within the Sleepers River catchment in northern Vermont. A transect of 15 piezometers was sampled for Ca, Si, DOC, other major cations, and δ18O. Daily piezometric head values reflected variations in the stream hydrograph induced by melt and rainfall. The riparian zone exhibited strong upward discharge gradients. An impeding layer was identified between the till and surficial organic soil. Water solute concentrations increased toward the stream throughout the melt. Ca concentrations increased with depth and DOC concentrations decreased with depth. The concentrations of Ca in all piezometers were lower during active snowmelt than during post-melt low flow. Ca data suggest snowmelt infiltration to depth; however, only upslope piezometers exhibited snowmelt infiltration and consequent low δ18O values,(while δ18O values varied less than 0.5‰ in the deep riparian piezometers throughout the study period. Ca and δ18O values in upslope piezometers during low streamflow were comparable to Ca and δ18O in riparian piezometers during high streamflow. The upland water Ca and δ18O may explain the deep riparian Ca dilution and consistent δ18O composition. The temporal pattern in Ca and δ18O indicate that upland water moves to the stream via a lateral displacement mechanism that is enhanced by the presence of distinct soil/textural layers. Snowmelt thus initiates the flux of pre-melt, low Ca upland water to depth in the riparian zone, but itself does not appear at depth in the riparian zone during spring melt. This is despite the coincident response of upland groundwater and stream discharge.

  10. DEVELOPMENT OF WATERSHED MANAGEMENT AND DECISION SUPPORT TOOLS FOR THE CANAAN VALLEY INSTITUTE (CVI) RIPARIAN ZONE AND STREAM RESTORATION

    EPA Science Inventory

    The USEPA Mid-Atlantic Highlands Streams Assessment (MAHA) report concluded that over 31% of stream miles in the Mid-Atlantic Highlands were in poor condition, and only 17% stream miles could be considered to be in good condition, based on their fish populations. Insect populatio...

  11. A Comparison of Vegetation Within and Outside Riparian Areas Bordering Ephemeral Streams in the Ouachita Mountains

    Treesearch

    David K. Radabaugh; Hal O. Liechty; James M. Guldin

    2004-01-01

    Abstract - Ephemeral streams frequently occur in shortleaf pine (Pinus echinata Mill.) hardwood stands that grow on the upper and mid-slopes of the Ouachita Mountains in Arkansas. Stream management zones are established around these ephemeral streams in the Ouachita National Forest to minimize impacts of adjacent forest management...

  12. MODELING PLUMES IN SMALL STREAMS

    EPA Science Inventory

    Pesticides accumulate on land surfaces from agricultural, commercial, and domestic application, and wash into streams and rivers during dry and wet weather. Flood water retention basins or structures often collect this contaminated runoff, providing intermediate storage and limit...

  13. Nutrient vectors and riparian nutrient processing in African semiarid savanna ecosystems

    USGS Publications Warehouse

    Jacobs, Shayne M.; Bechtold, J.S.; Biggs, Harry C.; Grimm, N. B.; McClain, M.E.; Naiman, R.J.; Perakis, Steven S.; Pinay, G.; Scholes, M.C.

    2007-01-01

    This review article describes vectors for nitrogen and phosphorus delivery to riparian zones in semiarid African savannas, the processing of nutrients in the riparian zone and the effect of disturbance on these processes. Semiarid savannas exhibit sharp seasonality, complex hillslope hydrology and high spatial heterogeneity, all of which ultimately impact nutrient fluxes between riparian, upland and aquatic environments. Our review shows that strong environmental drivers such as fire and herbivory enhance nitrogen, phosphorus and sediment transport to lower slope positions by shaping vegetative patterns. These vectors differ significantly from other arid and semiarid ecosystems, and from mesic ecosystems where the impact of fire and herbivory are less pronounced and less predictable. Also unique is the presence of sodic soils in certain hillslopes, which substantially alters hydrological flowpaths and may act as a trap where nitrogen is immobilized while sediment and phosphorus transport is enhanced. Nutrients and sediments are also deposited in the riparian zone during seasonal, intermittent floods while, during the dry season, subsurface movement of water from the stream into riparian soils and vegetation further enrich riparian zones with nutrients. As is found in mesic ecosystems, nutrients are immobilized in semiarid riparian corridors through microbial and plant uptake, whereas dissimilatory processes such as denitrification may be important where labile nitrogen and carbon are in adequate supply and physical conditions are suitablea??such as in seeps, wallows created by animals, ephemeral wetlands and stream edges. Interaction between temporal hydrologic connectivity and spatial heterogeneity are disrupted by disturbances such as large floods and extended droughts, which may convert certain riparian patches from sinks to sources for nitrogen and phosphorus. In the face of increasing anthropogenic pressure, the scientific challenges are to provide a basic understanding of riparian biogeochemistry in semiarid African savannas to adequately address the temporal and spatial impact of disturbances, and to apply this knowledge to better regional land and water management. An integrated, multidisciplinary approach applied in protected as well as human-disturbed ecosystems in southern Africa is essential for underpinning a strong environmental basis for sustainable human-related expansion.

  14. Spatio-temporal variability in the distribution of ground-dwelling riparian spiders and their potential role in water-to-land energy transfer along Hong Kong forest streams

    PubMed Central

    Yuen, Elaine Y.L.

    2015-01-01

    Terrestrial predators have been shown to aggregate along stream margins during periods when the emergence of adult aquatic insects is high. Such aggregation may be especially evident when terrestrial surroundings are relatively unproductive, and there are steep productivity gradients across riparia. In tropical forests, however, the productivity of inland terrestrial habitats may decrease the resource gradient across riparia, thus lessening any tendency of terrestrial predators to aggregate along stream margins. We elucidated the spatio-temporal variability in the distribution of ground-dwelling spiders and terrestrial arthropod prey within the riparia of two forest streams in tropical Hong Kong by sampling arthropods along transects at different distances from the streams during the wet and dry seasons. Environmental variables that may have influenced spider distributions were also measured. The vast majority of ground-dwelling predators along all transects at both sites were spiders. Of the three most abundant spiders captured along stream margins, Heteropoda venatoria (Sparassidae) and Draconarius spp. (Agelenidae) were terrestrially inclined and abundant during both seasons. Only Pardosa sumatrana (Lycosidae) showed some degree of aggregation at the stream banks, indicating a potential reliance on aquatic insect prey. Circumstantial evidence supports this notion, as P. sumatrana was virtually absent during the dry season when aquatic insect emergence was low. In general, forest-stream riparia in Hong Kong did not appear to be feeding hotspots for ground-dwelling predators. The lack of aggregation in ground-dwelling spiders in general may be attributed to the low rates of emergence of aquatic insects from the study streams compared to counterpart systems, as well as the potentially high availability of terrestrial insect prey in the surrounding forest. Heteropoda venatoria, the largest of the three spiders maintained a high biomass (up to 28 mg dry weight/m2) in stream riparia, exceeding the total standing stock of all other spiders by 2–80 times. The biomass and inland distribution of H. venatoria could make it a likely conduit for the stream-to-land transfer of energy. PMID:26246974

  15. Zone separator for multiple zone vessels

    DOEpatents

    Jones, John B.

    1983-02-01

    A solids-gas contact vessel, having two vertically disposed distinct reaction zones, includes a dynamic seal passing solids from an upper to a lower zone and maintaining a gas seal against the transfer of the separate treating gases from one zone to the other, and including a stream of sealing fluid at the seal.

  16. Biogeochemistry and Hydrology in Streams Impacted by Legacy Sediments and Urbanization: Implications for Stream Restoration

    EPA Science Inventory

    The groundwater–surface water interface, consisting of shallow groundwater adjacent to stream channels, is a hot spot for nitrogen removal processes, a storage zone for other solutes, and a target for restoration activities. Characterizing groundwater-surface water interac...

  17. Nitrogen dynamics at the groundwater-surface water interface of a degraded urban stream (journal)

    EPA Science Inventory

    Urbanization degrades stream ecosystems by altering hydrology and nutrient dynamics, yet relatively little effort has been devoted to understanding biogeochemistry of urban streams at the ground water-surface water interface. This zone may be especially important for nitrogen re...

  18. Relative Linkages of Stream Dissolved Oxygen with the Climatic, Hydrological, and Biogeochemical Drivers across the East Coast of U.S.A.

    NASA Astrophysics Data System (ADS)

    Abdul-Aziz, O. I.; Ahmed, S.

    2017-12-01

    Dissolved oxygen (DO) is a key indicator of stream water quality and ecosystem health. However, the temporal dynamics of stream DO is controlled by a multitude of interacting environmental drivers. The relative linkages of stream DO with the relevant environmental drivers were determined in this study across the U.S. East Coast by employing a systematic data analytics approach. The study analyzed temporal data for 51 water quality monitoring stations from USGS NWIS and EPA STORET databases. Principal component analysis and factor analysis, along with Pearson's correlation analysis, were applied to identify the interrelationships and unravel latent patterns among DO and the environmental drivers. Power law based partial least squares regression models with a bootstarp Monte-Carlo procedure (1000 iterations) were developed to reliably estimate the environmental linkages of DO by resolving multicollinearity. Based on the similarity of dominant drivers, the streams were categorized into three distinct environmental regimes. Stream DO in the northern part of temperate zone (e.g., northeast coast) had the strongest linkage with water temperature; suggesting an environmental regime with dominant climatic control. However, stream DO in the tropical zones (e.g., southeast Florida) was mostly driven by pH; indicating an environmental regime likely controlled by redox chemistry. Further, a transitional regime was found between the temperate and tropical zones, where stream DO was controlled by both water temperature and pH. The results suggested a strong effect of the climatic gradient (temperate to tropical) on stream DO along the East Coast. The identified environmental regimes and the regime-specific relative linkages provided new information on the dominant controls of coastal stream water quality dynamics. The findings would guide the planning and management of coastal stream water quality and ecosystem health across the U.S. East Coast and around the world.

  19. DARLA: Data Assimilation and Remote Sensing for Littoral Applications

    DTIC Science & Technology

    2011-09-30

    measurements from the Surf Zone Optics (SZO) experiment in September, 2011. Since optical reflectance saturates for surf zone bubble depths greater than...Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, Arlington VA 22202-4302. Respondents...pilot experiment at Duck, NC during the Surf Zone Optics DRI Experiment in September, 2010 and participated in planning of the upcoming RIVET DRI

  20. Biogeochemical patterns of intermittent streams over space and time as surface flows decrease

    NASA Astrophysics Data System (ADS)

    MacNeille, R. B.; Lohse, K. A.; Godsey, S.; McCorkle, E. P.; Parsons, S.; Baxter, C.

    2016-12-01

    Climate change in the western United States is projected to lead to earlier snowmelt, increasing fire risk and potentially transitioning perennial streams to intermittent ones. Differences between perennial and intermittent streams, especially the temporal and spatial patterns of carbon and nutrient dynamics during periods of drying, are understudied. We examined spatial and temporal patterns in surface water biogeochemistry in southwest Idaho and hypothesized that as streams dry, carbon concentrations would increase due to evapoconcentration and/or increased in-stream production. Furthermore, we expected that biogeochemical patterns of streams would become increasingly spatially heterogeneous with drying. Finally, we expected that these patterns would vary in response to fire. To test these hypotheses, we collected water samples every 50 meters from two intermittent streams, one burned and one unburned, in April, May and June, 2016 to determine surface water biogeochemistry. Results showed average concentrations of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC) increased 3-fold from April to June in the burned site compared to the unburned site where concentrations remained relatively constant. Interestingly, average concentrations of total nitrogen (TN) dropped substantially for the burned site over these three months, but only decreased slightly for the unburned site over the same time period. We also assessed changes in spatial correlation between the burned and unburned site: carbon concentrations were less spatially correlated at the unburned site than at the burned site. Scatterplot matrices of DIC values indicated that at a lag distance of 300 m in April and June, the unburned site had r-values of 0.7416 and 0.5975, respectively, while the burned site had r-values of 0.9468 and 0.8783, respectively. These initial findings support our hypotheses that carbon concentrations and spatial heterogeneity increased over time.

  1. Bacterial Community Composition and Extracellular Enzyme Activity in Temperate Streambed Sediment during Drying and Rewetting

    PubMed Central

    Pohlon, Elisabeth; Ochoa Fandino, Adriana; Marxsen, Jürgen

    2013-01-01

    Droughts are among the most important disturbance events for stream ecosystems; they not only affect stream hydrology but also the stream biota. Although desiccation of streams is common in Mediterranean regions, phases of dryness in headwaters have been observed more often and for longer periods in extended temperate regions, including Central Europe, reflecting global climate change and enhanced water withdrawal. The effects of desiccation and rewetting on the bacterial community composition and extracellular enzyme activity, a key process in the carbon flow of streams and rivers, were investigated in a typical Central European stream, the Breitenbach (Hesse, Germany). Wet streambed sediment is an important habitat in streams. It was sampled and exposed in the laboratory to different drying scenarios (fast, intermediate, slow) for 13 weeks, followed by rewetting of the sediment from the fast drying scenario via a sediment core perfusion technique for 2 weeks. Bacterial community structure was analyzed using CARD-FISH and TGGE, and extracellular enzyme activity was assessed using fluorogenic model substrates. During desiccation the bacterial community composition shifted toward composition in soil, exhibiting increasing proportions of Actinobacteria and Alphaproteobacteria and decreasing proportions of Bacteroidetes and Betaproteobacteria. Simultaneously the activities of extracellular enzymes decreased, most pronounced with aminopeptidases and less pronounced with enzymes involved in the degradation of polymeric carbohydrates. After rewetting, the general ecosystem functioning, with respect to extracellular enzyme activity, recovered after 10 to 14 days. However, the bacterial community composition had not yet achieved its original composition as in unaffected sediments within this time. Thus, whether the bacterial community eventually recovers completely after these events remains unknown. Perhaps this community undergoes permanent changes, especially after harsh desiccation, followed by loss of the specialized functions of specific groups of bacteria. PMID:24386188

  2. Effect of forest harvesting best management practices on coarse woody debris distribution in stream and riparian zones in three Appalachian watersheds

    Treesearch

    J. M. McClure; R. K. Kolka; A. White

    2004-01-01

    The distribution of coarse woody debris (CWD) was analyzed in three Appalachian watersheds in eastern Kentucky, eighteen years after harvest. The three watersheds included an unharvested control (Control), a second watershed with best management practices (BMPs) applied that included a 15.2 m unharvested zone near the stream (BMP watershed), and a third watershed that...

  3. A Bridge Too Far: Suppressing Frost Using an Out-of-Plane Dry Zone

    NASA Astrophysics Data System (ADS)

    Spohn, Corey; Ahmadi, Farzad; Nath, Saurabh; Boreyko, Jonathan

    2017-11-01

    It has recently been shown that ice can suppress the formation of any nearby condensation or frost on a substrate. However, these in-plane dry zones require the hygroscopic ice features to be placed on the same surface they are helping to keep dry, which makes it impossible to achieve complete anti-frosting. Here, we create an out-of-plane dry zone by holding two aluminum surfaces parallel to each other, where a uniform sheet of frost was grown on one surface to keep the other surface completely dry. The critical separation required to keep the test surface dry was found to be a function of the ambient supersaturation. We also show that inter-droplet ice bridging, now known to be a primary mechanism for in-plane frost growth, can be similarly extended to an out-of-plane configuration. We freeze a droplet on a hydrophobic surface and suspend a water droplet above it, such that an ice bridge grows toward the water droplet. More generally, these findings show that the recently discovered phenomena of dry zones and ice bridging can be extended to out-of-plane scenarios, which could lead to a better understanding of the behavior of mixed-phase systems. This work was supported by the National Science Foundation (CBET-1604272) and by the 3M Company (Non-Tenured Faculty Award).

  4. Catalytic distillation process

    DOEpatents

    Smith, Jr., Lawrence A.

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  5. Catalytic distillation process

    DOEpatents

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  6. Guidelines for collecting and processing samples of stream bed sediment for analysis of trace elements and organic contaminants for the National Water-Quality Assessment Program

    USGS Publications Warehouse

    Shelton, Larry R.; Capel, Paul D.

    1994-01-01

    A major component of the U.S. Geological Survey's National Water-Quality Assessment program is to assess the occurrence and distribution of trace elements and organic contaminants in streams. The first phase of the strategy for the assessment is to analyze samples of bed sediments from depositional zones. Fine-grained particles deposited in these zones are natural accumulators of trace elements and hydrophobic organic compounds. For the information to be comparable among studies in many different parts of the Nation, strategies for selecting stream sites and depositional zones are critical. Fine-grained surficial sediments are obtained from several depositional zones within a stream reach and composited to yield a sample representing average conditions. Sample collection and processing must be done consistently and by procedures specifically designed to separate the fine material into fractions that yield uncontaminated samples for trace-level analytes in the laboratory. Special coring samplers and other instruments made of Teflon are used for collection. Samples are processed through a 2.0-millimeter stainless-steel mesh sieve for organic contaminate analysis and a 63-micrometer nylon-cloth sieve for trace-element analysis. Quality assurance is maintained by strict collection and processing procedures, duplicate samplings, and a rigid cleaning procedure.

  7. Two-stage fixed-bed gasifier with selectable middle gas off-take point

    DOEpatents

    Strickland, Larry D.; Bissett, Larry A.

    1992-01-01

    A two-stage fixed bed coal gasifier wherein an annular region is in registry with a gasification zone underlying a devolatilization zone for extracting a side stream of high temperature substantially tar-free gas from the gasifier. A vertically displaceable skirt means is positioned within the gasifier to define the lower portion of the annular region so that vertical displacement of the skirt means positions the inlet into the annular region in a selected location within or in close proximity to the gasification zone for providing a positive control over the composition of the side stream gas.

  8. One-dimensional flow model of the river-hyporheic zone system

    NASA Astrophysics Data System (ADS)

    Pokrajac, D.

    2016-12-01

    The hyporheic zone is a shallow layer beneath natural streams that is characterized by intense exchange of water, nutrients, pollutants and thermal energy. Understanding these exchange processes is crucial for successful modelling of the river hydrodynamics and morphodynamics at various scales from the river corridor up to the river network scale (Cardenas, 2015). Existing simulation models of hyporheic exchange processes are either idealized models of the tracer movement through the river-hyporheic zone system (e.g. TSM, Bencala and Walters, 1983) or detailed models of turbulent flow in a stream, coupled with a conventional 2D Darcian groundwater model (e.g. Cardenas and Wilson, 2007). This paper presents an alternative approach which involves a simple 1-D simulation model of the hyporheic zone system based on the classical SWE equations coupled with the newly developed porous media analogue. This allows incorporating the effects of flow unsteadiness and non-Darcian parameterization od the drag term in the hyporheic zone model. The conceptual model of the stream-hyporheic zone system consists of a 1D model of the open channel flow in the river, coupled with a 1D model of the flow in the hyporheic zone via volume flux due to the difference in the water level in the river and the hyporheic zone. The interaction with the underlying groundwater aquifer is neglected, but coupling the present model with any conventional groundwater model is straightforward. The paper presents the derivation of the 1D flow equations for flow in the hyporheic zone, the details of the numerical scheme used for solving them and the model validation by comparison with published experimental data. References Bencala, K. E., and R. A. Walters (1983) "Simulation of solute transport in a mountain pool-and-riffle stream- a transient storage model", Water Resources Reseach 19(3): 718-724. Cardenas, M. B. (2015) "Hyporheic zone hydrologic science: A historical account of its emergence and a prospectus", Water Resources Research 51: 3601-3616 Cardenas, M. B., and J. L. Wilson (2007) "Dunes, turbulent eddies, and interfacial exchange with permeable sediments", Water Resour. Res. 43:W08412

  9. System and method for producing metallic iron

    DOEpatents

    Bleifuss, Rodney L [Grand Rapids, MN; Englund, David J [Bovey, MN; Iwasaki, Iwao [Grand Rapids, MN; Fosnacht, Donald R [Hermantown, MN; Brandon, Mark M [Charlotte, NC; True, Bradford G [Charlotte, NC

    2012-01-17

    A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

  10. Where does boreal stream DOC come from? - Quantifying the contribution from different landscape compartments using stable C isotope ratios.

    NASA Astrophysics Data System (ADS)

    Brink Bylund, J.; Bastviken, D.; Morth, C.; Laudon, H.; Giesler, R.; Buffam, I.

    2007-12-01

    Stable carbon isotope (δ13C) ratios are frequently used as a source tracer of e.g. organic matter (OM) produced in terrestrial versus aquatic environments. To our knowledge there has been no previous attempt to quantify the relative contribution of dissolved organic carbon (DOC) from various landscape compartments in catchments of different sizes. Here, we test to what extent δ13C values can be used also to quantify the relative contribution of DOC from wetlands/riparian zones along streams, and off stream forest habitats, respectively. We present data on spatial and temporal variability of DOC concentrations and δ13C-DOC values, during the year of 2005 in Krycklan catchment, a boreal stream network in northern Sweden. Ten stream sites, ranging from order 1 to 4, were monitored in sub catchments with different wetland coverage. Spatial variation of DOC concentration showed a weak but statistically significant relationship with wetland area, with higher concentration with increasing percent of wetland in the drainage area. During base flow the difference in δ13C-DOC values was significantly different between forest (-27.5‰) and wetland (-28.1‰). This spatial pattern disappears during spring peak flow when higher discharge flushing upper soil layer and the riparian zone on DOC in the catchments. A simple mixing model using DOC and δ13C-DOC showed that stream water DOC could be describe as a mixture of DOC coming from forest (deep) groundwater and wetland/riparian zone water. The result indicates that during spring peak flow almost all stream DOC (84-100%) is derived from wetlands and riparian zones. The wetland/riparian water dominates the stream DOC flux at all hydrological events, except for two sites, one forest dominated and one mixed catchment, where the forest groundwater dominated the DOC transport during base flow. Although the total wetland area in Krycklan catchment only represent 8.3%, it contributed, together with riparian zones, to as much as 83% of the yearly DOC transport. This study shows that there is a great potential in using stable carbon isotopes to quantify the relative contribution of DOC from various landscape compartments in catchments. Quantitative patterns are crucial for several reasons. It is for example necessary in predicting the response to global warming which will result in a changed hydrology and shifts in the relative area of the landscape compartments in boreal environments. KEY WORDS carbon isotopes; dissolved organic carbon; streams; boreal; landscape compartments; wetland; groundwater

  11. Small mammal habitat use within restored riparian habitats adjacent to channelized streams in Mississippi

    USDA-ARS?s Scientific Manuscript database

    Riparian zones of channelized agricultural streams in northwestern Mississippi typically consist of narrow vegetative corridors low in habitat diversity and lacking riparian wetlands. Land clearing practices and stream channelization has led to the development of gully erosion and further fragmenta...

  12. The importance of wood in headwater streams of the Oregon Coast Range

    USGS Publications Warehouse

    May, Christine; Gresswell, Robert E.; Erickson, Janet L.

    2004-01-01

    Although headwater streams comprise the majority of stream length in mountainous regions, little is known about their form and function in comparison to higher-order rivers. A better understanding of the role of headwater streams in routing water, wood, and sediment is needed to clarify the physical and biological connections among uplands, riparian zones, and downstream reaches.

  13. Defining perennial, intermittent and ephemeral channels in eastern Kentucky: application to forestry best management practices

    Treesearch

    J. R. Svec; R. K. Kolka; J. W. Stringer

    2003-01-01

    In Kentucky stream classification is used to determine which forestry best management practice (BMP) to apply in riparian zones. Kentucky defines stream classes as follows (Stringer and others 1998): a) perennial streams that hold water throughout the year, b) intermittent streams that hold water during wet portions of the year, and c) ephemeral channels that hold...

  14. Wet and Dry Atmospheric Mercury Deposition Accumulates in Watersheds of the Northeastern United States

    NASA Astrophysics Data System (ADS)

    Boyer, E. W.; Grant, C.; Grimm, J.; Drohan, P. J.; Bennett, J.; Lawler, D.

    2013-12-01

    Mercury emissions to the atmosphere from coal-fired power plants and other sources such as waste incineration can be deposited to landscapes in precipitation and in dry fallout. Some mercury reaches watersheds and streams, where it can accumulate in sediments and biota. Human exposure to mercury occurs primarily through fish consumption, and currently mercury fish eating advisories are in place for many of the streams and lakes in the state. Here, we explored mercury in air, soils, water, and biota. To quantify atmospheric mercury deposition, we measured both wet and dry mercury deposition at over 10 locations in Pennsylvania, from which we present variation in mercury deposition and initial assessments of factors affecting the patterns. Further, we simulated mercury deposition at unmonitored locations in Pennsylvania and the northeastern United States over space and time with a high-resolution modeling technique that reflects storm tracks and air flow patterns. To consider mercury accumulation in watersheds, we collected data on soil mercury concentrations in a set of soil samples, and collected baseline data on mercury in streams draining 35 forested watersheds across Pennsylvania, spanning gradients of atmospheric deposition, climate and geology. Mercury concentrations were measured in stream water under base-flow conditions, in streambed sediments, aquatic mosses, and in fish tissues from brook trout. Results indicate that wet and dry atmospheric deposition is a primary source of mercury that is accumulating in watersheds of Pennsylvania and the northeastern United States.

  15. The role of recharge zones, discharge zones, springs and tile drainage systems in peneplains of Central European highlands with regard to water quality generation processes

    NASA Astrophysics Data System (ADS)

    Doležal, František; Kvítek, Tomáš

    The hydrogeology, runoff generation and water quality generation in old peneplains of Central Europe built by acid crystalline rocks (such as the Bohemo-Moravian Highland) are described and interpreted in terms of a three-zone concept. The recharge zones are located on flat tops of hills and their soils are mostly permeable. It is mainly through them that the shallow groundwater-bearing formations are loaded with nitrate. The groundwater exfiltrates on the lower parts of slopes (in the so-called transient zone) and in narrow valleys (in the discharge zone), creating dispersed springs and waterlogged areas. In addition, the rapid and shallow flow of perched groundwater down the slope, which takes place during wet periods in the recharge zone and, mainly, in the transient zone, leaches the nitrate from the soil directly to the stream, without necessarily being in contact with the permanent groundwater table of the recharge and the transient zones. Discharge and water quality measurements in the Kopaninský tok experimental catchment (6.7 km 2) were analysed, using a combination of two runoff separation techniques (a digital filter and a simple conceptual model GROUND). Three runoff components were distinguished (direct runoff, interflow and baseflow). There is a weak but significant positive correlation between the stream nitrate concentration on the one hand and either the interflow or the baseflow on the other hand. There is also a weak but significant negative correlation between the stream nitrate concentration on the one hand and either the ratio of direct runoff to total stream flow or the logarithm of this ratio on the other hand, provided that the cases of zero direct runoff are disregarded. A simple mixing model was used to estimate the characteristic nitrate concentrations of individual runoff components. The interflow has the highest characteristic nitrate concentration and is probably the main stream water polluter with nitrate. The baseflow is identified as the likely second main polluter. The differences in water quality between a drainage outlet and a forest spring indicate the importance of a proper nitrogen management in the recharge zones. It is also concluded that the tile drainage and tillage of formerly waterlogged sites, mainly located in transient zones, reduce the opportunity for denitrification of both baseflow and interflow. The ploughed lands in the recharge zones represent an established basis for local agriculture and cannot be easily set aside. Many such lands have been declared as vulnerable to nitrate pollution in order to protect waters against impacts of risky agricultural practices. It is proposed that some waterlogged and drained sites in the transient and discharge zones are set aside rather than the flat ploughed lands on the hill tops. To increase the denitrification, tile drainage runoff from the transient and the discharge zones should be retarded.

  16. The Use of a Geographic Information System and Remote Sensing Technology for Monitoring Land Use and Soil Carbon Change in the Subtropical Dry Forest Life Zone of Puerto Rico

    NASA Technical Reports Server (NTRS)

    Velez-Rodriguez, Linda L. (Principal Investigator)

    1996-01-01

    Aerial photography, one of the first form of remote sensing technology, has long been an invaluable means to monitor activities and conditions at the Earth's surface. Geographic Information Systems or GIS is the use of computers in showing and manipulating spatial data. This report will present the use of geographic information systems and remote sensing technology for monitoring land use and soil carbon change in the subtropical dry forest life zone of Puerto Rico. This research included the south of Puerto Rico that belongs to the subtropical dry forest life zone. The Guanica Commonwealth Forest Biosphere Reserve and the Jobos Bay National Estuarine Research Reserve are studied in detail, because of their location in the subtropical dry forest life zone. Aerial photography, digital multispectral imagery, soil samples, soil survey maps, field inspections, and differential global positioning system (DGPS) observations were used.

  17. Agricultural adaptation to water scarcity in the Sri Lankan dry zone: A comparison of two water managment regimes

    NASA Astrophysics Data System (ADS)

    Burchfield, E. K.

    2014-12-01

    The island nation of Sri Lanka is divided into two agro-climatic zones: the southwestern wet zone and the northeastern dry zone. The dry zone is exposed to drought-like conditions for several months each year. Due to the sporadic nature of rainfall, dry zone livelihoods depend on the successful storage, capture, and distribution of water. Traditionally, water has been captured in rain-fed tanks and distributed through a system of dug canals. Recently, the Sri Lankan government has diverted the waters of the nation's largest river through a system of centrally managed reservoirs and canals and resettled farmers to cultivate this newly irrigated land. This study uses remotely sensed MODIS and LANDSAT imagery to compare vegetation health and cropping patterns in these distinct water management regimes under different conditions of water scarcity. Of particular interest are the socioeconomic, infrastructural, and institutional factors that affect cropping patterns, including field position, water storage capacity, and control of water resources. Results suggest that under known conditions of water scarcity, farmers cultivate other field crops in lieu of paddy. Cultivation changes depend to a large extent on the institutional distance between water users and water managers as well as the fragmentation of water resources within the system.

  18. REGIONAL PATTERNS AND LOCAL VARIABILITY OF DRY AND OCCULT DEPOSITION STRONGLY INFLUENCE SULFATE CONCENTRATIONS IN MAINE LAKES

    EPA Science Inventory

    There is great uncertainty and large cost in making dry deposition measurements. e present evidence based on wet deposition, evapotranspiration, S storage in lake sediments, and sulfate concentrations in lakes and streams in Nllaine that the dry deposition flux of sulfur to drain...

  19. The contribution of volunteer-based monitoring data to the assessment of harmful phytoplankton blooms in Brazilian urban streams.

    PubMed

    Cunha, Davi Gasparini Fernandes; Casali, Simone Pereira; de Falco, Patrícia Bortoletto; Thornhill, Ian; Loiselle, Steven Arthur

    2017-04-15

    Urban streams are vulnerable to a range of impacts, leading to the impairment of ecosystem services. However, studies on phytoplankton growth in tropical lotic systems are still limited. Citizen science approaches use trained volunteers to collect environmental data. We combined data on urban streams collected by volunteers with data obtained by professional scientists to identify potential drivers of phytoplankton community and determine thresholds for Cyanobacteria development. We combined datasets (n=117) on water quality and environmental observations in 64 Brazilian urban streams with paired data on phytoplankton. Sampling activities encompassed dry (July 2013 and July 2015) and warm (February and November 2014) seasons. Volunteers quantified phosphate (PO 4 3- ), nitrate (NO 3 - ) and turbidity in each stream using colorimetric and optical methods and recorded environmental conditions in the immediate surroundings of the sites through visual observations. We used non-parametric statistics to identify correlations among nutrients, turbidity and phytoplankton. We also looked for thresholds with respect to high Cyanobacteria abundance (>50,000cells/mL). The streams were characterized by relatively high nutrient concentrations (PO 4 3- : 0.11mg/L; NO 3 - : 2.6mg/L) and turbidity (49 NTU). Phytoplankton densities reached 189,000cells/mL, mainly potentially toxic Cyanobacteria species. Moderate but significant (p<0.05) correlations were observed between phytoplankton density and turbidity (ρ=0.338, Spearman) and PO 4 3- (ρ=0.292), but not with NO 3 - . Other important variables (river flow, temperature and light) were not assessed. Volunteers' observations covaried with phytoplankton density (p<0.05, Kruskal-Wallis), positively with increasing number of pollution sources and negatively with presence of vegetation in the riparian zone. Our results indicate that thresholds for PO 4 3- (0.11mg/L) can be used to separate systems with high Cyanobacteria density. The number of pollution sources provided a good indicator of waterbodies with potential cyanobacteria problems. Our findings reinforced the need for nutrient abatement and restoration of local streams and highlighted the benefits of volunteer-based monitoring to support decision-making. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Nitrogen transport and transformations in a coastal plain watershed: Influence of geomorphology on flow paths and residence times

    USGS Publications Warehouse

    Tesoriero, Anthony J.; Spruill, Timothy B.; Mew, H.E.; Farrell, Kathleen M.; Harden, Stephen L.

    2005-01-01

    Nitrogen transport and groundwater-surface water interactions were examined in a coastal plain watershed in the southeastern United States. Groundwater age dates, calculated using chlorofluorocarbon and tritium concentrations, along with concentrations of nitrogen species and other redox-active constituents, were used to evaluate the fate and transport of nitrate. Nitrate is stable only in recently recharged (<10 years) water found in the upper few meters of saturated thickness in the upland portion of a surficial aquifer. Groundwater with a residence time between 10 and 30 years typically has low nitrate and elevated excess N2 concentrations, indications that denitrification has reduced nitrate concentrations. Groundwater older than 30 years also has low nitrate concentrations but contains little or no excess N2, suggesting that this water did not contain elevated concentrations of nitrate along its flow path. Nitrate transport to streams varies between first- and third-order streams. Hydrologic, lithologic, and chemical data suggest that the surficial aquifer is the dominant source of flow and nitrate to a first-order stream. Iron-reducing conditions occur in groundwater samples from the bed and banks of the first-order stream, suggesting that direct groundwater discharge is denitrified prior to entering the stream. However, nitrogen from the surficial aquifer is transported directly to the stream via a tile drain that bypasses these reduced zones. In the alluvial valley of a third-order stream the erosion of a confining layer creates a much thicker unconfined alluvial aquifer with larger zones of nitrate stability. Age dating and chemical information (SiO 2, Na/K ratios) suggest that water in the alluvial aquifer is derived from short flow paths through the riparian zone and/or from adjacent streams during high-discharge periods. Copyright 2005 by the American Geophysical Union.

  1. Auxiliary reactor for a hydrocarbon reforming system

    DOEpatents

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Bentley, Jeffrey M.; Davis, Robert; Rumsey, Jennifer W.

    2006-01-17

    An auxiliary reactor for use with a reformer reactor having at least one reaction zone, and including a burner for burning fuel and creating a heated auxiliary reactor gas stream, and heat exchanger for transferring heat from auxiliary reactor gas stream and heat transfer medium, preferably two-phase water, to reformer reaction zone. Auxiliary reactor may include first cylindrical wall defining a chamber for burning fuel and creating a heated auxiliary reactor gas stream, the chamber having an inlet end, an outlet end, a second cylindrical wall surrounding first wall and a second annular chamber there between. The reactor being configured so heated auxiliary reactor gas flows out the outlet end and into and through second annular chamber and conduit which is disposed in second annular chamber, the conduit adapted to carry heat transfer medium and being connectable to reformer reaction zone for additional heat exchange.

  2. Simulation of climate-change effects on streamflow, lake water budgets, and stream temperature using GSFLOW and SNTEMP, Trout Lake Watershed, Wisconsin

    USGS Publications Warehouse

    Hunt, Randall J.; Walker, John F.; Selbig, William R.; Westenbroek, Stephen M.; Regan, R. Steve

    2013-01-01

    Although groundwater and surface water are considered a single resource, historically hydrologic simulations have not accounted for feedback loops between the groundwater system and other hydrologic processes. These feedbacks include timing and rates of evapotranspiration, surface runoff, soil-zone flow, and interactions with the groundwater system. Simulations that iteratively couple the surface-water and groundwater systems, however, are characterized by long run times and calibration challenges. In this study, calibrated, uncoupled transient surface-water and steady-state groundwater models were used to construct one coupled transient groundwater/surface-water model for the Trout Lake Watershed in north-central Wisconsin, USA. The computer code GSFLOW (Ground-water/Surface-water FLOW) was used to simulate the coupled hydrologic system; a surface-water model represented hydrologic processes in the atmosphere, at land surface, and within the soil-zone, and a groundwater-flow model represented the unsaturated zone, saturated zone, stream, and lake budgets. The coupled GSFLOW model was calibrated by using heads, streamflows, lake levels, actual evapotranspiration rates, solar radiation, and snowpack measurements collected during water years 1998–2007; calibration was performed by using advanced features present in the PEST parameter estimation software suite. Simulated streamflows from the calibrated GSFLOW model and other basin characteristics were used as input to the one-dimensional SNTEMP (Stream-Network TEMPerature) model to simulate daily stream temperature in selected tributaries in the watershed. The temperature model was calibrated to high-resolution stream temperature time-series data measured in 2002. The calibrated GSFLOW and SNTEMP models were then used to simulate effects of potential climate change for the period extending to the year 2100. An ensemble of climate models and emission scenarios was evaluated. Downscaled climate drivers for the period 2010–2100 showed increases in maximum and minimum temperature over the scenario period. Scenarios of future precipitation did not show a monotonic trend like temperature. Uncertainty in the climate drivers increased over time for both temperature and precipitation. Separate calibration of the uncoupled groundwater and surface-water models did not provide a representative initial parameter set for coupled model calibration. A sequentially linked calibration, in which the uncoupled models were linked by means of utility software, provided a starting parameter set suitable for coupled model calibration. Even with sequentially linked calibration, however, transmissivity of the lower part of the aquifer required further adjustment during coupled model calibration to attain reasonable parameter values for evaporation rates off a small seepage lake (a lake with no appreciable surface-water outlets) with a long history of study. The resulting coupled model was well calibrated to most types of observed time-series data used for calibration. Daily stream temperatures measured during 2002 were successfully simulated with SNTEMP; the model fit was acceptable for a range of groundwater inflow rates into the streams. Forecasts of potential climate change scenarios showed growing season length increasing by weeks, and both potential and actual evapotranspiration rates increasing appreciably, in response to increasing air temperature. Simulated actual evapotranspiration rates increased less than simulated potential evapotranspiration rates as a result of water limitation in the root zone during the summer high-evapotranspiration period. The hydrologic-system response to climate change was characterized by a reduction in the importance of the snow-melt pulse and an increase in the importance of fall and winter groundwater recharge. The less dynamic hydrologic regime is likely to result in drier soil conditions in rainfed wetlands and uplands, in contrast to less drying in groundwater-fed systems. Seepage lakes showed larger forecast stage declines related to climate change than did drainage lakes (lakes with outlet streams). Seepage lakes higher in the watershed (nearer to groundwater divides) had less groundwater inflow and thus had larger forecast declines in lake stage; however, ground-water inflow to seepage lakes in general tended to increase as a fraction of the lake budgets with lake-stage decline because inward hydraulic gradients increased. Drainage lakes were characterized by less simulated stage decline as reductions in outlet streamflow of set losses to other water flows. Net groundwater inflow tended to decrease in drainage lakes over the scenario period. Simulated stream temperatures increased appreciably with climate change. The estimated increase in annual average temperature ranged from approximately 1 to 2 degrees Celsius by 2100 in the stream characterized by a high groundwater inflow rate and 2 to 3 degrees Celsius in the stream with a lower rate. The climate drivers used for the climate-change scenarios had appreciable variation between the General Circulation Model and emission scenario selected; this uncertainty was reflected in hydrologic flow and temperature model results. Thus, as with all forecasts of this type, the results are best considered to approximate potential outcomes of climate change.

  3. Effects of urbanization on the distribution and abundance of amphibians and invasive species in southern California streams

    USGS Publications Warehouse

    Riley, S.P.D.; Busteed, G.T.; Kats, L.B.; Vandergon, T.L.; Lee, L.F.S.; Dagit, R.G.; Kerby, J.L.; Fisher, R.N.; Sauvajot, R.M.

    2005-01-01

    Urbanization negatively affects natural ecosystems in many ways, and aquatic systems in particular. Urbanization is also cited as one of the potential contributors to recent dramatic declines in amphibian populations. From 2000 to 2002 we determined the distribution and abundance of native amphibians and exotic predators and characterized stream habitat and invertebratecommunities in 35 streams in an urbanized landscape north of Los Angeles (U.S.A.). We measured watershed development as the percentage of area within each watershed occupied by urban land uses. Streams in more developed watersheds often had exotic crayfish (Procambarus clarkii) and fish, and had fewer native species such as California newts (Taricha torosa) and California treefrogs (Hyla cadaverina). These effects seemed particularly evident above 8% development, a result coincident with other urban stream studies that show negative impacts beginning at 10-15% urbanization. For Pacific treefrogs (H. regilla), the most widespread native amphibian, abundance was lower in the presence of exotic crayfish, although direct urbanization effects were not found. Benthic macroinvertebrate communities were also less diverse in urban streams, especially for sensitive species. Faunal community changes in urban streams may be related to changes in physical stream habitat, such as fewer pool and more run habitats and increased water depth and flow, leading to more permanent streams. Variation in stream permanence was particularly evident in 2002, a dry year when many natural streams were dry but urban streams were relatively unchanged. Urbanization has significantly altered stream habitat in this region and may enhance invasion by exotic species and negatively affect diversity and abundance of native amphibians. ??2005 Society for Conservation Biology.

  4. Comparison of Mercury Mass Loading in Streams to Wet and Dry Atmospheric Deposition in Watersheds of the Western US: Evidence for Non-Atmospheric Mercury Sources

    NASA Astrophysics Data System (ADS)

    Domagalski, J. L.; Majewski, M. S.; Alpers, C. N.; Eckley, C.

    2015-12-01

    Many streams in the western United States (US) are listed as impaired by mercury (Hg), and it is important to understand the magnitudes of the various sources in order to implement management strategies. Atmospheric deposition of Hg and can be a major source of aquatic contamination, along with mine wastes, and other sources. Prior studies in the eastern US have shown that streams deliver less than 50% of the atmospherically deposited Hg on an annual basis. In this study, we compared annual stream Hg loads for 20 watersheds in the western US to measured wet and modeled dry deposition. Land use varies from undisturbed to mixed (agricultural, urban, forested, mining). Data from the Mercury Deposition Network was used to estimate Hg input from precipitation. Dry deposition was not directly measured, but can be modeled using the Community Multi-scale Air Quality model. At an undeveloped watershed in the Rocky Mountains, the ratio of stream Hg load to atmospheric deposition was 0.2 during a year of average precipitation. In contrast, at the Carson River in Nevada, with known Hg contamination from historical silver mining with Hg amalgamation, stream export exceeded atmospheric deposition by a factor of 60, and at a small Sierran watershed with gold mining, the ratio was 70. Larger watersheds with mixed land uses, tend to have lower ratios of stream export relative to atmospheric deposition suggesting storage of Hg. The Sacramento River was the largest watershed for which Hg riverine loads were available with an average ratio of stream Hg export to atmospheric deposition of 0.10. Although Hg was used in upstream historical mining operations, the downstream river Hg load is partially mitigated by reservoirs, which trap sediment. This study represents the first compilation of riverine Hg loads in comparison to atmospheric deposition on a regional scale; the approach may be useful in assessing the relative importance of atmospheric and non-atmospheric Hg sources.

  5. The evaluation of evaporation by infrared thermography: A critical analysis of the measurements on the Crau test site. [France

    NASA Technical Reports Server (NTRS)

    Seguin, B.; Petit, V.; Devillard, R.; Reich, P.; Thouy, G. (Principal Investigator)

    1980-01-01

    Evapotranspiration was calculated for both the dry and irrigated zone by four methods which were compared with the energy balance method serving as a reference. Two methods did not involve the surface temperature. They are ETR(n) = R(n), liable to be valid under wet conditions and ET(eq) = (delta/delta + gamma) R(n) i.e, the first term of Penman's equation, adapted to moderately dry conditions. The methods using surface temperature were the combined energy balance aerodynamic approach and a simplified approach proposed by Jackson et al. Tests show the surface temperature methods give relatively satisfactory results both in the dry and wet zone, with a precision of 10% to 15% compared with the reference method. As was to be expected, ET(eq) gave satisfactory results only in the dry zone and ET(Rn) in the irrigated zone. Thermography increased the precision in the estimate of ET relative to the most suitable classical method by 5% to 8% and is equally suitable for both dry and wet conditions. The Jackson method does not require extensive ground measurements and the evaluation of the surface roughness.

  6. Using heat to characterize streambed water flux variability in four stream reaches

    USGS Publications Warehouse

    Essaid, H.I.; Zamora, C.M.; McCarthy, K.A.; Vogel, J.R.; Wilson, J.T.

    2008-01-01

    Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  7. Hydrological heterogeneity in agricultural riparian buffer strips

    NASA Astrophysics Data System (ADS)

    Hénault-Ethier, Louise; Larocque, Marie; Perron, Rachel; Wiseman, Natalie; Labrecque, Michel

    2017-03-01

    Riparian buffer strips (RBS) may protect surface water and groundwater in agricultural settings, although their effectiveness, observed in field-scale studies, may not extend to a watershed scale. Hydrologically-controlled leaching plots have often shown RBS to be effective at buffering nutrients and pesticides, but uncontrolled field studies have sometimes suggested limited effectiveness. The limited RBS effectiveness may be explained by the spatiotemporal hydrological heterogeneity near non-irrigated fields. This hypothesis was tested in conventional corn and soy fields in the St. Lawrence Lowlands of southern Quebec (Canada), where spring melt brings heavy and rapid runoff, while summer months are hot and dry. One field with a mineral soil (Saint-Roch-de-l'Achigan) and another with an organic-rich soil (Boisbriand) were equipped with passive runoff collectors, suction cup lysimeters, and piezometers placed before and after a 3 m-wide RBS, and monitored from 2011 to 2014. Soil topography of the RBS was mapped to a 1 cm vertical precision and a 50 cm sampling grid. On average, surface runoff intersects the RBS perpendicularly, but is subject to substantial local heterogeneity. Groundwater saturates the root zones, but flows little at the time of snowmelt. Groundwater flow is not consistently perpendicular to the RBS, and may reverse, flowing from stream to field under low water flow regimes with stream-aquifer connectivity, thus affecting RBS effectiveness calculations. Groundwater flow direction can be influenced by stratigraphy, local soil hydraulic properties, and historical modification of the agricultural stream beds. Understanding the spatiotemporal heterogeneity of surface and groundwater flows is essential to correctly assess the effectiveness of RBS in intercepting agro-chemical pollution. The implicit assumption that water flows across vegetated RBS, from the field to the stream, should always be verified.

  8. Vertebrate assemblages associated with headwater hydrology in western Oregon managed forests.

    Treesearch

    D.H. Olson; G. Weaver

    2007-01-01

    We characterized headwater stream habitats, fish, and amphibian fauna, in and along 106 headwater stream reaches at 12 study sites within managed forest stands 40 to 70 years old in western Oregon. Headwater stream types in our sample included perennial, spatially intermittent, and dry reaches. We captured 454 fish of three species groups and 1,796 amphibians of 12...

  9. Ecoregion and land-use influence invertebrate and detritus transport from headwater streams

    Treesearch

    Christopher A. Binckley; Mark S. Wipfli; R. Bruce Medhurst; Karl Polivka; Paul Hessburg; R. Brion Salter; Joshua Y. Kill

    2010-01-01

    We quantified the downstream transport of invertebrates, organic matter and inorganic sediment from 60 fishless headwater streams in the Wenatchee River Basin located on the eastern slope of the Cascade Range in Washington, U.S.A. Streams were classified into four groups (each n = 15) based on their position within two ecological subregions (wet and dry) and the extent...

  10. Exchanges across land-water-scape boundaries in urban systems: strategies for reducing nitrate pollution.

    PubMed

    Cadenasso, M L; Pickett, S T A; Groffman, P M; Band, L E; Brush, G S; Galvin, M F; Grove, J M; Hagar, G; Marshall, V; McGrath, B P; O'Neil-Dunne, J P M; Stack, W P; Troy, A R

    2008-01-01

    Conservation in urban areas typically focuses on biodiversity and large green spaces. However, opportunities exist throughout urban areas to enhance ecological functions. An important function of urban landscapes is retaining nitrogen thereby reducing nitrate pollution to streams and coastal waters. Control of nonpoint nitrate pollution in urban areas was originally based on the documented importance of riparian zones in agricultural and forested ecosystems. The watershed and boundary frameworks have been used to guide stream research and a riparian conservation strategy to reduce nitrate pollution in urban streams. But is stream restoration and riparian-zone conservation enough? Data from the Baltimore Ecosystem Study and other urban stream research indicate that urban riparian zones do not necessarily prevent nitrate from entering, nor remove nitrate from, streams. Based on this insight, policy makers in Baltimore extended the conservation strategy throughout larger watersheds, attempting to restore functions that no longer took place in riparian boundaries. Two urban revitalization projects are presented as examples aimed at reducing nitrate pollution to stormwater, streams, and the Chesapeake Bay. An adaptive cycle of ecological urban design synthesizes the insights from the watershed and boundary frameworks, from new data, and from the conservation concerns of agencies and local communities. This urban example of conservation based on ameliorating nitrate water pollution extends the initial watershed-boundary approach along three dimensions: 1) from riparian to urban land-water-scapes; 2) from discrete engineering solutions to ecological design approaches; and 3) from structural solutions to inclusion of individual, household, and institutional behavior.

  11. Effects of Climate on Co-evolution of Weathering Profiles and Hillscapes

    NASA Astrophysics Data System (ADS)

    Anderson, R. S.; Rajaram, H.; Anderson, S. P.

    2017-12-01

    Considerable debate revolves around the relative importance of rock type, tectonics, and climate in creating the architecture of the critical zone. It has recently been proposed that differences in the depths and patterns of weathering between landscapes in Colorado's Front Range and South Carolina's piedmont can be attributed to the state of stress in the rock imposed by the magnitude and orientation the regional stresses with respect to the ridgelines (St. Claire et al., 2016). We argue for the importance of the climate, and in particular, in temperate regions, the amount of recharge. We employ numerical models of hillslope evolution between bounding erosional channels, in which the degree of rock weathering governs the rate of transformation of rock to soil. As the water table drapes between the stream channels, fresh rock is brought into the weathering zone at a rate governed by the rate of incision of the channels. We track the chemical weathering of rock, represented by alteration of feldspar to clays, which in turn requires calculation of the concentration of reactive species in the water along hydrologic flow paths. We present results from analytic solutions to the flow field in which travel times can be efficiently assessed. Below the water table, flow paths are hyperbolic, taking on considerable lateral components as they veer toward the bounding channels that serve as drains to the hillslope. We find that if water is far from equilibrium with respect to weatherable minerals at the water table, as occurs in wet, slowly-eroding landscapes, deep weathering can occur well below the water table to levels approximating the base of the bounding channels. In dry climates, on the other hand, the weathering zone is limited to a shallow surface - parallel layer. These models capture the essence of the observed differences in depth to fresh rock in both wet and dry climates without appeal to the state of stress in the rock.

  12. Hyporheic invertebrate assemblages at reach scale in a Neotropical stream in Brazil.

    PubMed

    Mugnai, R; Messana, G; Di Lorenzo, T

    2015-11-01

    In the Neotropical Region, information concerning hyporheic communities is virtually non-existent. We carried out a sampling survey in the hyporheic zone of the Tijuca River, in the Tijuca National Park, located in the urban area of the city of Rio de Janeiro. Biological samples from the hyporheic zone were collected in three different stream reaches, in June 2012. The main objectives were: 1) to describe the structure of invertebrate assemblages in the hyporheic zone of a neotropical stream; 2) to apply a reach-scale approach in order to investigate spatial patterns of the hyporheic assemblages in relation to hydrology, depth and microhabitat typology. A total of 1460 individuals were collected and identified in 31 taxa belonging to Nematoda, Annelida, Crustacea, Hydrachnidia and Insecta. The class Insecta dominated the upper layer of the hyporheic zone. Copepods were the most abundant taxon among crustaceans and occurred mostly in the upwelling areas of the reaches. The results of this study represent one of the few contributions so far about hyporheic invertebrate assemblages of the Neotropical Region.

  13. Dynamics of Soil Water Evaporation during Soil Drying: Laboratory Experiment and Numerical Analysis

    PubMed Central

    Han, Jiangbo; Zhou, Zhifang

    2013-01-01

    Laboratory and numerical experiments were conducted to investigate the evolution of soil water evaporation during a continuous drying event. Simulated soil water contents and temperatures by the calibrated model well reproduced measured values at different depths. Results show that the evaporative drying process could be divided into three stages, beginning with a relatively high evaporation rate during stage 1, followed by a lower rate during transient stage and stage 2, and finally maintaining a very low and constant rate during stage 3. The condensation zone was located immediately below the evaporation zone in the profile. Both peaks of evaporation and condensation rate increased rapidly during stage 1 and transition stage, decreased during stage 2, and maintained constant during stage 3. The width of evaporation zone kept a continuous increase during stages 1 and 2 and maintained a nearly constant value of 0.68 cm during stage 3. When the evaporation zone totally moved into the subsurface, a dry surface layer (DSL) formed above the evaporation zone at the end of stage 2. The width of DSL also presented a continuous increase during stage 2 and kept a constant value of 0.71 cm during stage 3. PMID:24489492

  14. Dynamics of soil water evaporation during soil drying: laboratory experiment and numerical analysis.

    PubMed

    Han, Jiangbo; Zhou, Zhifang

    2013-01-01

    Laboratory and numerical experiments were conducted to investigate the evolution of soil water evaporation during a continuous drying event. Simulated soil water contents and temperatures by the calibrated model well reproduced measured values at different depths. Results show that the evaporative drying process could be divided into three stages, beginning with a relatively high evaporation rate during stage 1, followed by a lower rate during transient stage and stage 2, and finally maintaining a very low and constant rate during stage 3. The condensation zone was located immediately below the evaporation zone in the profile. Both peaks of evaporation and condensation rate increased rapidly during stage 1 and transition stage, decreased during stage 2, and maintained constant during stage 3. The width of evaporation zone kept a continuous increase during stages 1 and 2 and maintained a nearly constant value of 0.68 cm during stage 3. When the evaporation zone totally moved into the subsurface, a dry surface layer (DSL) formed above the evaporation zone at the end of stage 2. The width of DSL also presented a continuous increase during stage 2 and kept a constant value of 0.71 cm during stage 3.

  15. Preliminary study of the effects of headwater riparian reserves with upslope thinning on stream habitats and amphibians in western Oregon.

    Treesearch

    D.H. Olson; C. Rugger

    2007-01-01

    We conducted a preliminary examination of the responses of stream amphibians and instream habitat conditions to alternative riparian buffer zones with forest thinning upslope. Pre- and posttreatment surveys were carried out on 68 headwater stream reaches (including 23 unthinned reference reaches) at 11 sites in western Oregon. Streams were in managed conifer stands 40...

  16. Pasture BMP effectiveness using an HRU-based subarea approach in SWAT.

    PubMed

    Sheshukov, Aleksey Y; Douglas-Mankin, Kyle R; Sinnathamby, Sumathy; Daggupati, Prasad

    2016-01-15

    Many conservation programs have been established to motivate producers to adopt best management practices (BMP) to minimize pasture runoff and nutrient loads, but a process is needed to assess BMP effectiveness to help target implementation efforts. A study was conducted to develop and demonstrate a method to evaluate water-quality impacts and the effectiveness of two widely used BMPs on a livestock pasture: off-stream watering site and stream fencing. The Soil and Water Assessment Tool (SWAT) model was built for the Pottawatomie Creek Watershed in eastern Kansas, independently calibrated at the watershed outlet for streamflow and at a pasture site for nutrients and sediment runoff, and also employed to simulate pollutant loads in a synthetic pasture. The pasture was divided into several subareas including stream, riparian zone, and two grazing zones. Five scenarios applied to both a synthetic pasture and a whole watershed were simulated to assess various combinations of widely used pasture BMPs: (1) baseline conditions with an open stream access, (2) an off-stream watering site installed in individual subareas in the pasture, and (3) stream or riparian zone fencing with an off-stream watering site. Results indicated that pollutant loads increase with increasing stocking rates whereas off-stream watering site and/or stream fencing reduce time cattle spend in the stream and nutrient loads. These two BMPs lowered organic P and N loads by more than 59% and nitrate loads by 19%, but TSS and sediment-attached P loads remained practically unchanged. An effectiveness index (EI) quantified impacts from the various combinations of off-stream watering sites and fencing in all scenarios. Stream bank contribution to pollutant loads was not accounted in the methodology due to limitations of the SWAT model, but can be incorporated in the approach if an amount of bank soil loss is known for various stocking rates. The proposed methodology provides an adaptable framework for pasture BMP assessment and was utilized to represent a consistent, defensible process to quantify the effectiveness of BMP proposals in a BMP auction in eastern Kansas. Copyright © 2015 Elsevier Ltd. All rights reserved.

  17. Supported microporous ceramic membranes

    DOEpatents

    Webster, Elizabeth; Anderson, Marc

    1993-01-01

    A method for permformation of microporous ceramic membranes onto a porous support includes placing a colloidal suspension of metal or metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane useful for ultrafiltration, reverse osmosis, or molecular sieving having mean pore sizes less than 100 Angstroms.

  18. Metal oxide membranes for gas separation

    DOEpatents

    Anderson, Marc A.; Webster, Elizabeth T.; Xu, Qunyin

    1994-01-01

    A method for permformation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation.

  19. Supported microporous ceramic membranes

    DOEpatents

    Webster, E.; Anderson, M.

    1993-12-14

    A method for the formation of microporous ceramic membranes onto a porous support includes placing a colloidal suspension of metal or metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane useful for ultrafiltration, reverse osmosis, or molecular sieving having mean pore sizes less than 100 Angstroms. 4 figures.

  20. Metal oxide membranes for gas separation

    DOEpatents

    Anderson, M.A.; Webster, E.T.; Xu, Q.

    1994-08-30

    A method for formation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation. 4 figs.

  1. Engineered Hyporheic Zones as Novel Water Quality Best Management Practice: Flow and Contaminant Attenuation in Constructed Stream Experiments

    NASA Astrophysics Data System (ADS)

    Herzog, S.; McCray, J. E.; Higgins, C. P.

    2015-12-01

    The hyporheic zone is a hotspot for biogeochemical processing that can attenuate a variety of nonpoint source contaminants in streamwater. However, hyporheic zones in urban and agricultural streams are often degraded and poorly connected with surface water. In order to increase hyporheic exchange and improve water quality, we introduced engineered streambeds as a stormwater and restoration best management practice. Modifications to streambed hydraulic conductivity and reactivity are termed Biohydrochemical Enhancement structures for Streamwater Treatment (BEST). BEST are subsurface modules that utilize low- and high-permeability sediments to drive efficient hyporheic exchange, and reactive geomedia to increase reaction rates within the hyporheic zone. This work presents the first physical performance data of BEST modules at the pilot scale. BEST modules were installed in a constructed stream facility at the Colorado School of Mines in Golden, CO. This facility features two 15m artificial streams, which included an all sand control condition alongside the BEST test condition. Streams were continuously operated at a discharge of 1 L/s using recycled water. Time-lapse electrical resistivity surveys demonstrated that BEST modules provided substantially greater hyporheic exchange than the control condition. Water quality samples at the hyporheic and reach scales also revealed greater attenuation of nitrogen, coliforms, and select metals and trace organics by BEST modules relative to the control condition. These experimental results were also compared to previous numerical model simulations to evaluate model accuracy. Together, these results show that BEST may be an effective best management practice for improving streamwater quality in urban and agricultural settings.

  2. Estimation of river pollution index in a tidal stream using kriging analysis.

    PubMed

    Chen, Yen-Chang; Yeh, Hui-Chung; Wei, Chiang

    2012-08-29

    Tidal streams are complex watercourses that represent a transitional zone between riverine and marine systems; they occur where fresh and marine waters converge. Because tidal circulation processes cause substantial turbulence in these highly dynamic zones, tidal streams are the most productive of water bodies. Their rich biological diversity, combined with the convenience of land and water transports, provide sites for concentrated populations that evolve into large cities. Domestic wastewater is generally discharged directly into tidal streams in Taiwan, necessitating regular evaluation of the water quality of these streams. Given the complex flow dynamics of tidal streams, only a few models can effectively evaluate and identify pollution levels. This study evaluates the river pollution index (RPI) in tidal streams by using kriging analysis. This is a geostatistical method for interpolating random spatial variation to estimate linear grid points in two or three dimensions. A kriging-based method is developed to evaluate RPI in tidal streams, which is typically considered as 1D in hydraulic engineering. The proposed method efficiently evaluates RPI in tidal streams with the minimum amount of water quality data. Data of the Tanshui River downstream reach available from an estuarine area validate the accuracy and reliability of the proposed method. Results of this study demonstrate that this simple yet reliable method can effectively estimate RPI in tidal streams.

  3. Streamflow losses in the Black Hills of western South Dakota

    USGS Publications Warehouse

    Hortness, Jon E.; Driscoll, Daniel G.

    1998-01-01

    Losses occur in numerous streams that cross outcrops of various sedimentary rocks that are exposed around the periphery of the Black Hills of South Dakota. These streamflow losses are recognized as an important source of local recharge to regional bedrock aquifers. Most streams lose all of their flow up to some threshold rate. Streamflow is maintained through a loss zone when the threshold is exceeded. Streamflow records for 86 measurement sites are used to determine bedrock loss thresholds for 24 area streams, which have individual loss thresholds that range from negligible (no loss) to as much as 50 cubic feet per second. In addition, insights are provided regarding springflow that occurs in the immediate vicinity of selected loss zones. Most losses occur to outcrops of the Madison Limestone and Minnelusa Formation. Losses to the Deadwood Formation probably are minimal. Losses to the Minnekahta Limestone generally are small; however, they are difficult to quantify because of potential losses to extensive alluvial deposits that commonly are located near Minnekahta outcrops. Loss thresholds for each stream are shown to be relatively constant, without measurable effects from streamflow rates or duration of flow through the loss zones. Calculated losses for measurements made during high-flow conditions generally have larger variability than calculated losses for low-flow conditions; however, consistent relations between losses and streamflow have not been identified. Some of this variability results from the inability to account for tributary inflows and changes in storage. Calculated losses are shown to decrease, in some cases, during periods of extended flow through loss zones. Decreased 'net' losses, however, generally can be attributed to springflow (ground-water discharge) within a loss zone, which may occur during prolonged periods of wet climatic conditions. Losses to unsaturated alluvial deposits located adjacent to the stream channels are found to have significant effects on determination of bedrock losses. Large losses occur in filling initial storage in unsaturated alluvial deposits downstream from loss zones, when bedrock loss thresholds are first exceeded. Losses to alluvial deposits in the range of tens of cubic feet per second and alluvial storage capacities in the range of hundreds of acre-feet are documented. Significant changes in loss thresholds for Grace Coolidge Creek, Spring Creek, and Whitewood Creek are documented. Introduction of large quantities of fine-grained sediments into these stream channels may have affected loss thresholds for various periods of time.

  4. Enhanced effect of water vapor on complete oxidation of formaldehyde in air with ozone over MnOx catalysts at room temperature.

    PubMed

    Zhao, De-Zhi; Shi, Chuan; Li, Xiao-Song; Zhu, Ai-Min; Jang, Ben W-L

    2012-11-15

    At room temperature, the enhanced effect of water vapor on ozone catalytic oxidation (OZCO) of formaldehyde to CO2 over MnOx catalysts and the reaction stability was reported. In a dry air stream, only below 20% of formaldehyde could be oxidized into CO2 by O3. In humid air streams (RH≥55%), ∼100% of formaldehyde were oxidized into CO2 by O3 and the reaction stability was significantly enhanced. Meanwhile, in situ Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectra of OZCO of HCHO demonstrate that the amount of both monodentate and bidentate carbonate species on MnOx, in the dry stream, increased gradually with time on stream (TOS). However, in the humid stream, almost no accumulation of carbonate species on the catalysts was observed. To clarify the enhanced mechanism, formaldehyde surface reactions and CO2 adsorption/desorption on the fresh, O3 and O3+H2O treated MnOx catalysts were examined comparatively. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Determinants of tree water use across a floodplain in arid, subtropical northwest Australia

    NASA Astrophysics Data System (ADS)

    Grierson, Pauline; McLean, Elizabeth; Iles, Jordan; Skrzypek, Grzegorz; Brand, Melinda; O'Donnell, Alison; Siebers, Andre; Dogramaci, Shawan

    2017-04-01

    Riparian zones of ephemeral streams in hot arid regions are subject to unpredictable and generally short-lived flood periods. However, droughts tend to be longer and more severe than floods in their ecological impact as low water availability in surficial alluvium and on the floodplain results in hydrological stress. Resolving how riparian and floodplain vegetation respond to highly variable flow regimes remains a fundamental challenge for estimating water budgets in arid regions, particularly where water tables are subject to groundwater abstraction. Here, we investigated patterns of water use by a range of tree species (Eucalyptus camaldulensis, E. victrix, Acacia citrinoviridis, A. coriacea, Hakea lorea, Atalaya hemiglauca) across a floodplain in the Pilbara region of northwest Australia and assessed vegetation responsiveness to both temporal and spatial variation in water supply. We sought to disentangle the varying contributions of soil water, groundwater and surface water to tree water use to determine the ecological implications of changes in hydrologic connectivity resulting from both seasonal water deficits and anthropogenic management. Diurnal and seasonal dynamics of water use were assessed using sapflux measurements coupled with observations of changing source availability. Source utilization was examined using water stable isotope compositions of xylem, soil, rain, surface water and groundwater. Depending on distance from the stream channel and time since last rainfall, we found that small trees were primarily accessing shallow soil water of meteoric origin while larger eucalypts accessed water deeper in the profile (either stored soil water or groundwater), especially as surface soils dried out. However, tree species were highly variable in their diurnal patterns of water use,including some evidence of nocturnal sapflux in A. coriacea adjacent to streams. Sapflux rates also varied almost four-fold among species but generally declined with increasing depth to watertable i.e on to the floodplain. Ongoing studies are investigating how hyporheic zones expand and contract in response to episodic flows and vegetation water use in order to develop an integrated 3D hydrological/ecohydrological model to explore relationships between regional and local water tables, surface water flows, and evaporative and evapotranspiration fluxes. New insights into the biological, ecological and physical processes that control the flow of water between the biotic and abiotic compartments of ephemeral streams will be used to target specific aspects of flow regimes that are critical to maintaining riparian and floodplain ecosystems in dryland environments, particularly where streams are subject to altered hydrology.

  6. A New Dimensionless Number for Redox Conditions within the Hyporheic Zone: Morphological and Biogeochemical Controls

    NASA Astrophysics Data System (ADS)

    Marzadri, A.; Tonina, D.; Bellin, A.

    2012-12-01

    We introduce a new Damköhler number, Da, to quantify the biogeochemical status of the hyporheic zone and to upscale local hyporheic processes to reach scale. Da is defined as the ratio between the median hyporheic residence time, τup,50, which is a representative time scale of the hyporheic flow, and a representative time scale of biogeochemical reactions, which we define as the time τlim needed to consume dissolved oxygen to a prescribed threshold concentration below which reducing reactions are activated: Da = τup,50/τlim. This approach accounts for streambed topography and surface hydraulics via the hyporheic residence time and biogeochemical reaction via the time limit τlim. Da can readily evaluate the redox status of the hyporheic zone. Values of Da larger than 1 indicate prevailing anaerobic conditions, whereas values smaller than 1 prevailing aerobic conditions. This new Damköhler number can quantify the efficiency of hyporheic zone in transforming dissolved inorganic nitrogen species such as ammonium and nitrate, whose transformation depends on the redox condition of the hyporheic zone. We define a particular value of Da, Das, that indicates when the hyporheic zone is a source or a sink of nitrate. This index depends only on the relative abundance of ammonium and nitrate. The approach can be applied to any hyporheic zone of which the median hyporheic residence time is known. Application to streams with pool-riffle morphology shows that Da increases passing from small to large streams implying that the fraction of the hyporheic zone in anaerobic conditions increases with stream size.

  7. Denitrification in sediments from the hyporheic zone adjacent to a small forested stream

    USGS Publications Warehouse

    Duff, J.H.; Triska, F.J.

    1990-01-01

    Denitrifying potentials increased with increasing distance from the stream channel. Dissolved oxygen was 100% of the concentration expected in equilibrium with the atmosphere in water obtained from monitoring wells immediately adjacent to the stream but was as low as 7% of the expected value in water 11.4 m inland. Both nitrate and dissolved organic carbon decreased over summer in wells at the base of the alder-forested slope. A 48-h injection of nitrate-amended stream water into hyporheic water 8.4 m inland stimulated nitrous oxide production in the presence of acetylene. Nitrous oxide was generated as nitrate and acetylene were co-transported to a well 13 m down-gradient. Acetylene-block experiments coupled with the chemistry data suggest that denitrification can modify the chemistry of water during passage through the hyporheic zone. -from Authors

  8. The influence of stream bed geomorphology on chemical species within the hyporheic zone over time and space

    NASA Astrophysics Data System (ADS)

    Quick, A. M.; Reeder, W. J.; Farrell, T. B.; Benner, S. G.; Tonina, D.; Feris, K. P.

    2017-12-01

    The hyporheic zone is well established as an important zone of biogeochemical activity in streams and rivers. Multiple large scale flume experiments were carried out to mimic bedform-controlled hyporheic zones in small streams. The laboratory setting allowed for geochemical measurement resolution and replicates that would not be possible in a natural setting. Two flume experiments that consisted of three small streams with variable sizes of bedform dunes were carried out in which chemical species were measured in the surface water and along hyporheic flow lines in the subsurface. The species measured included dissolved oxygen, pH, alkalinity, major cations (Na+, Mg2+, Ca2+, K+, Si4+, Al3+), anions (NO3-, NO2-, SO42-, PO43-, Cl-), and many trace elements (As, Sr, Co, Ni, Cu, Zn, Pb, U, V). Observed spatial and temporal trends reflect microbiological processes, changing redox conditions, and chemical weathering. In general, microbial respiration causes DO to decrease with residence time, leading to aerobic and anaerobic zones that influence redox-sensitive species and pH gradients that influence mineral solubility. Most other species concentrations, including those of major cations and trace elements, increase with residence time and generally decrease over time elapsed during the experiment. The different dune morphologies dictate flow velocities in the hyporheic zone; for most species, steeper dunes with higher velocities had lower concentrations at the end of the experiment, indicating the role of dune shape in the weathering rates of minerals in hyporheic sediment and the concentrations of dissolved species entering the surface water over time. Many of the observed trends can be applied, at least qualitatively, to understanding how these species will behave in natural settings. This insight will contribute to the understanding of many of the applications of the hyporheic zone (e.g. bioremediation, habitat, greenhouse gas emissions, etc.).

  9. Regional Groundwater Discharge Drives High Carbon Dioxide Emissions from a Lowland Tropical Rainforest Stream

    NASA Astrophysics Data System (ADS)

    Oviedo-Vargas, D.; Dierick, D.; Genereux, D. P.; Oberbauer, S. F.; Osburn, C. L.

    2015-12-01

    Field measurements of carbon (C) fluxes are fundamental for understanding global C cycling, and the C source/sink status of ecosystems. In the tropical rainforest at La Selva Biological Station in Costa Rica, old regional bedrock groundwater (gw) high in dissolved inorganic C discharges into some streams and wetlands with possible impacts on ecosystem C pools and fluxes. We investigated carbon dioxide (CO2) and methane (CH4) degassing from two streams at La Selva: the Arboleda, where ~1/3 of the streamflow is from regional gw, and the Taconazo, fed exclusively by much younger local gw recharged within the catchment. In two reaches (upper and lower) of the Arboleda and Taconazo streams, emissions were determined from tracer injections. In the lower Arboleda (the only reach receiving regional gw) CO2 fluxes (fCO2) averaged 5.5 mol C per m2 of stream surface per day, ~7.5x higher than the average (0.7 mol C m-2 d-1) from the stream reaches with no regional gw inflow (the Taconazo and upper Arboleda). The regional gw inflow had no measurable effect on CH4 emissions. To further understand the dynamics of enhanced CO2 degassing from the lower Arboleda, we examined spatiotemporal patterns in fCO2 using floating chambers. Both static and drifting chambers revealed high spatial heterogeneity in fCO2 at the scale of 5 to 30 m reaches. Temporal trends were highly localized; in two of three subreaches surveyed repeatedly, fCO2 increased with stream discharge and did not differ between wet and dry seasons, but the third subreach showed the opposite behavior. Results from static and drifting chambers deviated 31% and -36%, respectively, from tracer injection results. CO2 degassing from the Arboleda is a large C flux; when averaged over the watershed area it is similar in magnitude to the net ecosystem exchange measured by eddy covariance. Elevated CO2 emissions from the Arboleda stream are consistent with measurements of higher CO2 concentration in the air above the Arboleda stream, and low 14C in plants growing near the Arboleda weir, a zone of high stream gas exchange where geological CO2 low in 14C is degassed from the stream and taken up by riparian plants. The outcomes of this research contribute to the understanding of how catchment connections to underlying hydrogeological systems can affect terrestrial ecosystem C budgets.

  10. Breeding birds in riparian and upland dry forests of the Cascade Range

    Treesearch

    John F. Lehmkuhl; E. Dorsey Burger; Emily K. Drew; John P. Lindsey; Maryellen Haggard; Kent Z. Woodruff

    2007-01-01

    We quantified breeding bird abundance, diversity, and indicator species in riparian and upland dry forests along six third- to fourth-order streams on the east slope of the Cascade Range, Washington, USA. Upland mesic forest on southerly aspects was dominated by open ponderosa pine (Pinus ponderosa) and dry Douglas-fir (Pseudotsuga menziesii...

  11. SOIL ALUMINUM DISTRIBUTION IN THE NEAR-STREAM ZONE AT THE BEAR BROOK WATERSHED IN MAINE

    EPA Science Inventory

    Near-stream and upslope soil chemical properties were analyzed to infer linkages between soil and surface water chemistry at the Bear Brook Watershed in Maine [BBWM]. Organic and mineral soil samples were collected along six 20 m transects perpendicular to the stream and one 200 ...

  12. Linking nitrogen management, seep chemistry, and stream water quality in two agricultural headwater watersheds

    USDA-ARS?s Scientific Manuscript database

    Riparian seepage zones in headwater agricultural watersheds represent important sources of nitrate-nitrogen (NO3-N) to surface waters, often connecting N-rich groundwater systems to streams. In this study, we examined how NO3-N concentrations in seep and stream water were affected by NO3-N processin...

  13. Hyporheic exchange and fulvic acid redox reactions in an alpine stream/wetland ecosystem, Colorado front range

    USGS Publications Warehouse

    Miller, Matthew P.; McKnight, Diane M.; Cory, R.M.; Williams, Mark W.; Runkel, Robert L.

    2006-01-01

    The influence of hyporheic zone interactions on the redox state of fulvic acids and other redox active species was investigated in an alpine stream and adjacent wetland, which is a more reducing environment. A tracer injection experiment using bromide (Br-) was conducted in the stream system. Simulations with a transport model showed that rates of exchange between the stream and hyporheic zone were rapid (?? ??? 10-3 s -1). Parallel factor analysis of fluorescence spectra was used to quantify the redox state of dissolved fulvic acids. The rate coefficient for oxidation of reduced fulvic acids (?? = 6.5 ?? 10-3 s -1) in the stream indicates that electron-transfer reactions occur over short time scales. The rate coefficients for decay of ammonium (?? = 1.2 ?? 10-3 s-1) and production of nitrate (?? = -1.0 ?? 10-3 s-1) were opposite in sign but almost equal in magnitude. Our results suggest that fulvic acids are involved in rapid electron-transfer processes in and near the stream channel and may be important in determining ecological energy flow at the catchment scale. ?? 2006 American Chemical Society.

  14. Dynamics of Soil Water Evaporation during Soil Drying in the Presence of a Shallow Water Table: Laboratory Experiment and Numerical Analysis

    NASA Astrophysics Data System (ADS)

    Han, J.; Lin, J.; Liu, P.; Li, W.

    2017-12-01

    Evaporation from a porous medium plays a key role in hydrological, agricultural, environmental, and engineering applications. Laboratory and numerical experiments were conducted to investigate the evolution of soil water evaporation during a continuous drying event. Simulated soil water contents and temperatures by the calibrated model well reproduced measured values at different depths. Results show that the evaporative drying process could be divided into three stages, beginning with a relatively high evaporation rate during stage 1, followed by a lower rate during transient stage and stage 2, and finally maintaining a very low and constant rate during stage 3. The condensation zone was located immediately below the evaporation zone in the profile. Both peaks of evaporation and condensation rate increased rapidly during stage 1 and transition stage, decreased during stage 2, and maintained constant during stage 3. The width of evaporation zone kept a continuous increase during stages 1 and 2 and maintained a nearly constant value of 0.68 cm during stage 3. When the evaporation zone totally moved into the subsurface, a dry surface layer (DSL) formed above the evaporation zone at the end of stage 2. The width of DSL also presented a continuous increase during stage 2 and kept a constant value of 0.71 cm during stage 3. Although the magnitude of condensation zone was much smaller than that for the evaporation zone, the importance of the contribution of condensation zone to soil water dynamics should not be underestimated. Results from our experiment and numerical simulation show that this condensation process resulted in an unexpected and apparent water content increase in the middle of vadose zone profile.

  15. Transpiration Response and Growth in Pearl Millet Parental Lines and Hybrids Bred for Contrasting Rainfall Environments

    PubMed Central

    Medina, Susan; Gupta, S. K.; Vadez, Vincent

    2017-01-01

    Under conditions of high vapor pressure deficit (VPD) and soil drying, restricting transpiration is an important avenue to gain efficiency in water use. The question we raise in this article is whether breeding for agro-ecological environments that differ for the rainfall have selected for traits that control plant water use. These are measured in pearl millet materials bred for zones varying in rainfall (8 combinations of parent and F1-hybrids, 18 F1-hybrids and then 40 F1-hybrids). In all cases, we found an agro-ecological variation in the slope of the transpiration response to increasing VPD, and parental line variation in the transpiration response to soil drying within hybrids/parent combinations. The hybrids adapted to lower rainfall had higher transpiration response curves than those from the highest rainfall zones, but showed no variation in how transpiration responded to soil drying. The genotypes bred for lower rainfall zones showed lower leaf area, dry matter, thicker leaves, root development, and exudation, than the ones bred for high rainfall zone when grown in the low VPD environment of the greenhouse, but there was no difference in their root length neither on the root/shoot index in these genotypes. By contrast, when grown under high VPD conditions outdoors, the lower rainfall hybrids had the highest leaf, tiller, and biomass development. Finally, under soil drying the genotypes from the lower rainfall accumulated less biomass than the ones from higher rainfall zone, and so did the parental lines compared to the hybrids. These differences in the transpiration response and growth clearly showed that breeding for different agro-ecological zones also bred for different genotype strategies in relation to traits related to plant water use. Highlights: • Variation in transpiration response reflected breeding for agro-ecological zones • Different growth strategies depended on the environmental conditions • Different ideotypes reflected rainfall levels in specific agro-ecological zones PMID:29163578

  16. Transpiration Response and Growth in Pearl Millet Parental Lines and Hybrids Bred for Contrasting Rainfall Environments.

    PubMed

    Medina, Susan; Gupta, S K; Vadez, Vincent

    2017-01-01

    Under conditions of high vapor pressure deficit (VPD) and soil drying, restricting transpiration is an important avenue to gain efficiency in water use. The question we raise in this article is whether breeding for agro-ecological environments that differ for the rainfall have selected for traits that control plant water use. These are measured in pearl millet materials bred for zones varying in rainfall (8 combinations of parent and F 1 -hybrids, 18 F 1 -hybrids and then 40 F 1 -hybrids). In all cases, we found an agro-ecological variation in the slope of the transpiration response to increasing VPD, and parental line variation in the transpiration response to soil drying within hybrids/parent combinations. The hybrids adapted to lower rainfall had higher transpiration response curves than those from the highest rainfall zones, but showed no variation in how transpiration responded to soil drying. The genotypes bred for lower rainfall zones showed lower leaf area, dry matter, thicker leaves, root development, and exudation, than the ones bred for high rainfall zone when grown in the low VPD environment of the greenhouse, but there was no difference in their root length neither on the root/shoot index in these genotypes. By contrast, when grown under high VPD conditions outdoors, the lower rainfall hybrids had the highest leaf, tiller, and biomass development. Finally, under soil drying the genotypes from the lower rainfall accumulated less biomass than the ones from higher rainfall zone, and so did the parental lines compared to the hybrids. These differences in the transpiration response and growth clearly showed that breeding for different agro-ecological zones also bred for different genotype strategies in relation to traits related to plant water use. Highlights : • Variation in transpiration response reflected breeding for agro-ecological zones • Different growth strategies depended on the environmental conditions • Different ideotypes reflected rainfall levels in specific agro-ecological zones.

  17. Hillslope-riparian-stream connectivity and flow directions at the Panola Mountain Research Watershed

    NASA Astrophysics Data System (ADS)

    van Meerveld, Ilja; Seibert, Jan; Peters, Jake

    2015-04-01

    The question how water travels from rainfall to the stream network has engaged hydrologists for decades as it determines the streamflow response to rainfall and stream water quality. In order to obtain a better understanding of water's journey from the hillslope to the stream, and in particular the effects of rainfall amount, bedrock topography and variations in soil depth on hillslope subsurface flow pathways and hillslope-riparian zone-stream connectivity, we analyzed data from 26 groundwater wells in a hillslope-riparian study area in the Panola Mountain Research Watershed, Georgia, USA. The water levels in the riparian zone were sustained throughout the wet winter period, while the wells on the hillslope showed very peaky and short-lived responses. Perched groundwater on the hillslope either developed across almost the entire hillslope or not at all, suggesting that either the majority of the hillslope became connected to the stream or that no connection was established. There were clear differences in the timing of the groundwater responses, with water levels near the stream and on the upper hillslope rising earlier than on the lower hillslope and midslope. The midslope with deep soils played a critical role in the establishment of hillslope-stream connectivity. A sharp increase in water level was measured at the lower hillslope wells and in some riparian wells when connectivity between the hillslope and the riparian zone was established. Sustained streamflow (more than 0.5 mm/h for more than 12 h) occurred only when the hillslope was connected to the stream. The groundwater flow directions were highly variable across the midslope with deep soils: the flow directions followed the local bedrock topography when perched groundwater levels were low and the surface topography when groundwater levels were higher. The flow directions could even point in the general upslope direction but followed the local bedrock topography. This suggests that first the bedrock hollow filled but that once water levels were higher and saturation was more widespread, the flow directions followed the surface topography and were downslope. This competing influence of the surface and bedrock topography was not observed in the riparian zone, where the flow directions were either downslope or changed from a combined downslope and downstream direction towards a more downslope direction during events.

  18. Joule heating induced stream broadening in free-flow zone electrophoresis.

    PubMed

    Dutta, Debashis

    2018-03-01

    The use of an electric field in free-flow zone electrophoresis (FFZE) automatically leads to Joule heating yielding a higher temperature at the center of the separation chamber relative to that around the channel walls. For small amounts of heat generated, this thermal effect introduces a variation in the equilibrium position of the analyte molecules due to the dependence of liquid viscosity and analyte diffusivity on temperature leading to a modification in the position of the analyte stream as well as the zone width. In this article, an analytic theory is presented to quantitate such effects of Joule heating on FFZE assays in the limit of small temperature differentials across the channel gap yielding a closed form expression for the stream position and zone variance under equilibrium conditions. A method-of-moments approach is employed to develop this analytic theory, which is further validated with numerical solutions of the governing equations. Interestingly, the noted analyses predict that Joule heating can drift the location of the analyte stream either way of its equilibrium position realized in the absence of any temperature rise in the system, and also tends to reduce zone dispersion. The extent of these modifications, however, is governed by the electric field induced temperature rise and three Péclet numbers evaluated based on the axial pressure-driven flow, transverse electroosmotic and electrophoretic solute velocities in the separation chamber. Monte Carlo simulations of the FFZE system further establish a time and a length scale over which the results from the analytic theory are valid. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Near-term effects of repeated-thinning with riparian buffers on headwater stream vertebrates and habitats in Oregon, USA

    Treesearch

    Deanna H. Olson; Julia I. Burton

    2014-01-01

    We examined the effects of a second-thinning harvest with alternative riparian buffer management approaches on headwater stream habitats and associated vertebrates in western Oregon, USA. Our analyses showed that stream reaches were generally distinguished primarily by average width and depth, along with the percentage of the dry reach length, and secondarily, by the...

  20. Storage dynamics in hydropedological units control hillslope connectivity, runoff generation, and the evolution of catchment transit time distributions

    PubMed Central

    Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C

    2014-01-01

    We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. “pre-event” water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as “isostats,” not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Key Points Hillslope connectivity is controlled by small storage changes in soil units Different catchment source waters mix in large riparian wetland storage Isotopes show riparian wetlands set the catchment transit time distribution PMID:25506098

  1. Storage dynamics in hydropedological units control hillslope connectivity, runoff generation, and the evolution of catchment transit time distributions.

    PubMed

    Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C

    2014-02-01

    We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. "pre-event" water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as "isostats," not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Hillslope connectivity is controlled by small storage changes in soil unitsDifferent catchment source waters mix in large riparian wetland storageIsotopes show riparian wetlands set the catchment transit time distribution.

  2. CONTINUOUS PRECIPITATION METHOD FOR CONVERSION OF URANYL NITRATE TO URANIUM HEXAFLUORIDE

    DOEpatents

    Reinhart, G.M.; Collopy, T.J.

    1962-11-13

    A continuous precipitation process is given for converting a uranyl nitrate solution to uranium tetrafluoride. A stream of the uranyl nitrate solution and a stream of an aqueous ammonium hydroxide solution are continuously introduced into an agitated reaction zone maintained at a pH of 5.0 to 6.5. Flow rates are adjusted to provide a mean residence time of the resulting slurry in the reaction zone of at least 30 minutes. After a startup period of two hours the precipitate is recovered from the effluent stream by filtration and is converted to uranium tetrafluoride by reduction to uranium dioxide with hydrogen and reaction of the uranium dioxide with anhydrous hydrogen fluoride. (AEC)

  3. Cooling and solidification of heavy hydrocarbon liquid streams

    DOEpatents

    Antieri, Salvatore J.; Comolli, Alfred G.

    1983-01-01

    A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

  4. Entrainment Zone Characteristics and Entrainment Rates in Cloud-Topped Boundary Layers from DYCOMS-II

    DTIC Science & Technology

    2012-03-01

    water and ozone across the EIL. The scalar variables from this flight (not shown) suggest significant horizontal variation in the free- troposphere ...near the cloud top where mixing occurs between dry free- troposphere air and moist turbulent air. Although the concept of the entrainment zone is...mixing occurs between dry free- troposphere air and moist turbulent air. Although the concept of the entrainment zone is clear, defining the top and

  5. Combustion chamber and thermal vapor stream producing apparatus and method

    DOEpatents

    Sperry, John S.; Krajicek, Richard W.; Cradeur, Robert R.

    1978-01-01

    A new and improved method and apparatus for burning a hydrocarbon fuel for producing a high pressure thermal vapor stream comprising steam and combustion gases for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, wherein a high pressure combustion chamber having multiple refractory lined combustion zones of varying diameters is provided for burning a hydrocarbon fuel and pressurized air in predetermined ratios injected into the chamber for producing hot combustion gases essentially free of oxidizing components and solid carbonaceous particles. The combustion zones are formed by zones of increasing diameters up a final zone of decreasing diameter to provide expansion zones which cause turbulence through controlled thorough mixing of the air and fuel to facilitate complete combustion. The high pressure air and fuel is injected into the first of the multiple zones where ignition occurs with a portion of the air injected at or near the point of ignition to further provide turbulence and more complete combustion.

  6. Using Rising Limb Analysis to Estimate Uptake of Reactive Solutes in Advective and Transient Storage Sub-compartments of Stream Ecosystems

    NASA Astrophysics Data System (ADS)

    Thomas, S. A.; Valett, H.; Webster, J. R.; Mulholland, P. J.; Dahm, C. N.

    2001-12-01

    Identifying the locations and controls governing solute uptake is a recent area of focus in studies of stream biogeochemistry. We introduce a technique, rising limb analysis (RLA), to estimate areal nitrate uptake in the advective and transient storage (TS) zones of streams. RLA is an inverse approach that combines nutrient spiraling and transient storage modeling to calculate total uptake of reactive solutes and the fraction of uptake occurring within the advective sub-compartment of streams. The contribution of the transient storage zones to solute loss is determined by difference. Twelve-hour coinjections of conservative (Cl-) and reactive (15NO3) tracers were conducted seasonally in several headwater streams among which AS/A ranged from 0.01 - 2.0. TS characteristics were determined using an advection-dispersion model modified to include hydrologic exchange with a transient storage compartment. Whole-system uptake was determined by fitting the longitudinal pattern of NO3 to first-order, exponential decay model. Uptake in the advective sub-compartment was determined by collecting a temporal sequence of samples from a single location beginning with the arrival of the solute front and concluding with the onset of plateau conditions (i.e. the rising limb). Across the rising limb, 15NO3:Cl was regressed against the percentage of water that had resided in the transient storage zone (calculated from the TS modeling). The y-intercept thus provides an estimate of the plateau 15NO3:Cl ratio in the absence of NO3 uptake within the transient storage zone. Algebraic expressions were used to calculate the percentage of NO3 uptake occurring in the advective and transient storage sub-compartments. Application of RLA successfully estimated uptake coefficients for NO3 in the subsurface when the physical dimensions of that habitat were substantial (AS/A > 0.2) and when plateau conditions at the sampling location consisted of waters in which at least 25% had resided in the transient storage zone. In those cases, the TS zone accounted for 8 - 47 % of overall NO3 uptake and uptake rates within the subsurface ranged from 0.7 - 14.3 mg N m-2 d-1.

  7. Quantifying and Predicting Three-Dimensional Heterogeneity in Transient Storage Using Roving Profiling

    NASA Astrophysics Data System (ADS)

    Kaplan, D. A.; Reaver, N.; Hensley, R. T.; Cohen, M. J.

    2017-12-01

    Hydraulic transport is an important component of nutrient spiraling in streams. Quantifying conservative solute transport is a prerequisite for understanding the cycling and fate of reactive solutes, such as nutrients. Numerous studies have modeled solute transport within streams using the one-dimensional advection, dispersion and storage (ADS) equation calibrated to experimental data from tracer experiments. However, there are limitations to the information about in-stream transient storage that can be derived from calibrated ADS model parameters. Transient storage (TS) in the ADS model is most often modeled as a single process, and calibrated model parameters are "lumped" values that are the best-fit representation of multiple real-world TS processes. In this study, we developed a roving profiling method to assess and predict spatial heterogeneity of in-stream TS. We performed five tracer experiments on three spring-fed rivers in Florida (USA) using Rhodamine WT. During each tracer release, stationary fluorometers were deployed to measure breakthrough curves for multiple reaches within the river. Teams of roving samplers moved along the rivers measuring tracer concentrations at various locations and depths within the reaches. A Bayesian statistical method was used to calibrate the ADS model to the stationary breakthrough curves, resulting in probability distributions for both the advective and TS zone as a function of river distance and time. Rover samples were then assigned a probability of being from either the advective or TS zone by comparing measured concentrations to the probability distributions of concentrations in the ADS advective and TS zones. A regression model was used to predict the probability of any in-stream position being located within the advective versus TS zone based on spatiotemporal predictors (time, river position, depth, and distance from bank) and eco-geomorphological feature (eddies, woody debris, benthic depressions, and aquatic vegetation). Results confirm that TS is spatially variable as a function of spatiotemporal and eco-geomorphological features. A substantial number of samples with nearly equivalent chances of being from the advective or TS zones suggests that the distinction between zones is often poorly defined.

  8. The Effect of Carbon Dioxide (CO 2) Ice Cloud Condensation on the Habitable Zone

    NASA Astrophysics Data System (ADS)

    Lincowski, Andrew; Meadows, Victoria; Robinson, Tyler D.; Crisp, David

    2016-10-01

    The currently accepted outer limit of the habitable zone (OHZ) is defined by the "maximum greenhouse" limit, where Rayleigh scattering from additional CO2 gas overwhelms greenhouse warming. However, this long-standing definition neglects the radiative effects of CO2 clouds (Kopparapu, 2013); this omission was justified based on studies using the two-stream approximation, which found CO2 clouds to be highly likely to produce a net warming. However, recent comparisons of the radiative effect of CO2 clouds using both a two-stream and multi-stream radiative transfer model (Kitzmann et al, 2013; Kitzmann, 2016) found that the warming effect was reduced when the more sophisticated multi-stream models were used. In many cases CO2 clouds caused a cooling effect, meaning that their impact on climate could not be neglected when calculating the outer edge of the habitable zone. To better understand the impact of CO2 ice clouds on the OHZ, we have integrated CO2 cloud condensation into a versatile 1-D climate model for terrestrial planets (Robinson et al, 2012) that uses the validated multi-stream SMART radiative transfer code (Meadows & Crisp, 1996; Crisp, 1997) with a simple microphysical model. We present preliminary results on the habitable zone with self-consistent CO2 clouds for a range of atmospheric masses, compositions and host star spectra, and the subsequent effect on surface temperature. In particular, we evaluate the habitable zone for TRAPPIST-1d (Gillon et al, 2016) with a variety of atmospheric compositions and masses. We present reflectance and transit spectra of these cold terrestrial planets. We identify any consequences for the OHZ in general and TRAPPIST-1d in particular. This more comprehensive treatment of the OHZ could impact our understanding of the distribution of habitable planets in the universe, and provide better constraints for statistical target selection techniques, such as the habitability index (Barnes et al, 2015), for missions like JWST, WFIRST-AFTA and the LUVOIR mission concept.

  9. Gasification of black liquor

    DOEpatents

    Kohl, A.L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  10. Gasification of black liquor

    DOEpatents

    Kohl, Arthur L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  11. Estimation of stream depletion using values of capacitance

    NASA Astrophysics Data System (ADS)

    Baldenkov, Mikhail; Filimonova, Elena

    2014-05-01

    Compensation pumping is used to alleviate deficiencies in streamflow discharge during dry seasons. Short-term groundwater pumping can use aquifer storage instead of catchment-zone water until the drawdown reaches the edge of the stream. Stream-aquifer interactions are the key component of the hydrologic budgets and estimation of stream depletion has top-priority when evaluating the effectiveness of application of seasonal compensation pumping. Numerous analytical equations have been developed to assess the influence of groundwater pumping on nearby streams (C.V. Theis, R.E. Glover, C.G. Balmer, M.S. Hantush, C.T. Jenkins, B. Hunt, J. Bredehoeft, V.A. Zlotnik, E.L. Minkin, N.N. Lapshin, F.M. Bochever and other researchers). R.B. Wallace and Y. Darama obtained solution for cyclic conditions groundwater pumping. Numerical model approaches used in difficult hydrogeological conditions. It is offered to estimate stream depletion by seasonal pumping using values of capacitance (complex, dimensionless parameter of an aquifer system that defines the delayed effect on steamflow when there is groundwater pumping). Capacitance (C) is determined by the following equation: ( ) L* C = f( °---) , TS-Δt where S and T are the aquifer specific yield (or storage coefficient for a confined aquifer) and transmissivity, respectively; Δt is the pumping time inside one cycle, L* is the summarizing distance between the compensation well and stream edge; in some cases it can involve a function of the stream leakance and vertical leakance of the impermeable layer. Three typical hydraulic cases of compensation pumping were classified depending on their capacitance structure (i.e. the relationship between surface water and groundwater): (a) perfect hydraulic connection between the stream and aquifer; (b) imperfect hydraulic connection between the stream and aquifer; and (c) essentially imperfect hydraulic connection between the stream and the underlying confined aquifer. The form of capacitance was obtained for all three cases and is a function of aquifer hydraulic characteristics, pumping time and distance between the well and stream edge. The distance in the first and the second cases is the sum of the shortest distance between stream edge and the well and the stream leakance; in case; and in the third case, it is the sum of real distance, stream leakance and vertical leakance through the impermeable layer. A regression test between unit stream depletion (i.e. the ratio of stream reduction to pumping rate stream depletion and capacitance was performed, and power dependences were obtained in the form of Y = a + bC-0.5 The drained storage cannot be absolutely recovered by natural processes that cause 'residual' stream depletion (RSD) even in condition of perfect hydraulic connection between the stream and aquifer. The impact of various hydraulic characteristics and engineering factors on RSD was examined by numerical modeling. It was realized lack of correlation between capacitance and RSD, but exponential dependences between capacitance and the annual amplitudes of stream depletion (A) were obtained in the form of: A = 0.95 exp(- 0.776C ) Although this approach cannot assess stream-aquifer interactions to the same degree of accuracy as analytical equations of detail as a numerical model, it can provide forecast estimation with the level of primary available data.

  12. Polyelectrolyte flocculation of grain stillage for improved clarification and water recovery within bioethanol production facilities.

    PubMed

    Menkhaus, Todd J; Anderson, Jason; Lane, Samuel; Waddell, Evan

    2010-04-01

    Polyelectrolytes were investigated for flocculation of a corn whole stillage stream to improve solid-liquid clarification operations and reduce downstream utility requirements for evaporation and drying within a bioethanol process. Despite a negative zeta potential for the stillage solids, an anionic polyelectrolyte was found to provide the best flocculation. At the optimal dosage of 1.1mg polymer/g dry suspended solids, an anionic flocculant provided a clarified stream with only 0.15% w/w suspended solids (equivalent to a total dissolved solid to total suspended solid ratio greater than 40, and a viscosity reduction of 39% compared to an unflocculated "clarified" stream). The resulting solids cake had greater than 40% w/w solids, and more than 80% water recovery was found in the clarified stream. Addition of flocculant improved filtration flux by six fold and/or would allow for up to a 4-times higher flow rate if using a decanting centrifuge for clarification of corn stillage. Copyright 2009 Elsevier Ltd. All rights reserved.

  13. Ground water stratification and delivery of nitrate to an incised stream under varying flow conditions.

    PubMed

    Böhlke, J K; O'Connell, Michael E; Prestegaard, Karen L

    2007-01-01

    Ground water processes affecting seasonal variations of surface water nitrate concentrations were investigated in an incised first-order stream in an agricultural watershed with a riparian forest in the coastal plain of Maryland. Aquifer characteristics including sediment stratigraphy, geochemistry, and hydraulic properties were examined in combination with chemical and isotopic analyses of ground water, macropore discharge, and stream water. The ground water flow system exhibits vertical stratification of hydraulic properties and redox conditions, with sub-horizontal boundaries that extend beneath the field and adjacent riparian forest. Below the minimum water table position, ground water age gradients indicate low recharge rates (2-5 cm yr(-1)) and long residence times (years to decades), whereas the transient ground water wedge between the maximum and minimum water table positions has a relatively short residence time (months to years), partly because of an upward increase in hydraulic conductivity. Oxygen reduction and denitrification in recharging ground waters are coupled with pyrite oxidation near the minimum water table elevation in a mottled weathering zone in Tertiary marine glauconitic sediments. The incised stream had high nitrate concentrations during high flow conditions when much of the ground water was transmitted rapidly across the riparian zone in a shallow oxic aquifer wedge with abundant outflow macropores, and low nitrate concentrations during low flow conditions when the oxic wedge was smaller and stream discharge was dominated by upwelling from the deeper denitrified parts of the aquifer. Results from this and similar studies illustrate the importance of near-stream geomorphology and subsurface geology as controls of riparian zone function and delivery of nitrate to streams in agricultural watersheds.

  14. Ground water stratification and delivery of nitrate to an incised stream under varying flow conditions

    USGS Publications Warehouse

    Böhlke, J.K.; O'Connell, M. E.; Prestegaard, K.L.

    2007-01-01

    Ground water processes affecting seasonal variations of surface water nitrate concentrations were investigated in an incised first-order stream in an agricultural watershed with a riparian forest in the coastal plain of Maryland. Aquifer characteristics including sediment stratigraphy, geochemistry, and hydraulic properties were examined in combination with chemical and isotopic analyses of ground water, macropore discharge, and stream water. The ground water flow system exhibits vertical stratification of hydraulic properties and redox conditions, with sub-horizontal boundaries that extend beneath the field and adjacent riparian forest. Below the minimum water table position, ground water age gradients indicate low recharge rates (2-5 cm yr-1) and long residence times (years to decades), whereas the transient ground water wedge between the maximum and minimum water table positions has a relatively short residence time (months to years), partly because of an upward increase in hydraulic conductivity. Oxygen reduction and denitrification in recharging ground waters are coupled with pyrite oxidation near the minimum water table elevation in a mottled weathering zone in Tertiary marine glauconitic sediments. The incised stream had high nitrate concentrations during high flow conditions when much of the ground water was transmitted rapidly across the riparian zone in a shallow oxic aquifer wedge with abundant outflow macropores, and low nitrate concentrations during low flow conditions when the oxic wedge was smaller and stream discharge was dominated by upwelling from the deeper denitrified parts of the aquifer. Results from this and similar studies illustrate the importance of near-stream geomorphology and subsurface geology as controls of riparian zone function and delivery of nitrate to streams in agricultural watersheds. ?? ASA, CSSA, SSSA.

  15. Simulation of dynamic expansion, contraction, and connectivity in a mountain stream network

    NASA Astrophysics Data System (ADS)

    Ward, Adam S.; Schmadel, Noah M.; Wondzell, Steven M.

    2018-04-01

    Headwater stream networks expand and contract in response to changes in stream discharge. The changes in the extent of the stream network are also controlled by geologic or geomorphic setting - some reaches go dry even under relatively wet conditions, other reaches remain flowing under relatively dry conditions. While such patterns are well recognized, we currently lack tools to predict the extent of the stream network and the times and locations where the network is dry within large river networks. Here, we develop a perceptual model of the river corridor in a headwater mountainous catchment, translate this into a reduced-complexity mechanistic model, and implement the model to examine connectivity and network extent over an entire water year. Our model agreed reasonably well with our observations, showing that the extent and connectivity of the river network was most sensitive to hydrologic forcing under the lowest discharges (Qgauge < 1 L s-1), that at intermediate discharges (1 L s-1 < Qgauge < 10 L s-1) the extent of the network changed dramatically with changes in discharge, and that under wet conditions (Qgauge > 10 L s-1) the extent of the network was relatively insensitive to hydrologic forcing and was instead determined by the network topology. We do not expect that the specific thresholds observed in this study would be transferable to other catchments with different geology, topology, or hydrologic forcing. However, we expect that the general pattern should be robust: the dominant controls will shift from hydrologic forcing to geologic setting as discharge increases. Furthermore, our method is readily transferable as the model can be applied with minimal data requirements (a single stream gauge, a digital terrain model, and estimates of hydrogeologic properties) to estimate flow duration or connectivity along the river corridor in unstudied catchments. As the available information increases, the model could be better calibrated to match site-specific observations of network extent, locations of dry reaches, or solute break through curves as demonstrated in this study. Based on the low initial data requirements and ability to later tune the model to a specific site, we suggest example applications of this parsimonious model that may prove useful to both researchers and managers.

  16. Solute transport in streams of varying morphology inferred from a high resolution network of potentiometric wireless chloride sensors

    NASA Astrophysics Data System (ADS)

    Klaus, Julian; Smettem, Keith; Pfister, Laurent; Harris, Nick

    2017-04-01

    There is ongoing interest in understanding and quantifying the travel times and dispersion of solutes moving through stream environments, including the hyporheic zone and/or in-channel dead zones where retention affects biogeochemical cycling processes that are critical to stream ecosystem functioning. Modelling these transport and retention processes requires acquisition of tracer data from injection experiments where the concentrations are recorded downstream. Such experiments are often time consuming and costly, which may be the reason many modelling studies of chemical transport have tended to rely on relatively few well documented field case studies. This leads to the need of fast and cheap distributed sensor arrays that respond instantly and record chemical transport at points of interest on timescales of seconds at various locations in the stream environment. To tackle this challenge we present data from several tracer experiments carried out in the Attert river catchment in Luxembourg employing low-cost (in the order of a euro per sensor) potentiometric chloride sensors in a distributed array. We injected NaCl under various baseflow conditions in streams of different morphologies and observed solute transport at various distances and locations. This data is used to benchmark the sensors to data obtained from more expensive electrical conductivity meters. Furthermore, the data allowed spatial resolution of hydrodynamic mixing processes and identification of chemical 'dead zones' in the study reaches.

  17. Evaluating the fate of six common pharmaceuticals using a reactive transport model: insights from a stream tracer test.

    PubMed

    Riml, Joakim; Wörman, Anders; Kunkel, Uwe; Radke, Michael

    2013-08-01

    Quantitative information regarding the capacity of rivers to self-purify pharmaceutical residues is limited. To bridge this knowledge gap, we present a methodology for quantifying the governing processes affecting the fate of pharmaceuticals in streaming waters and, especially, to evaluate their relative significance for tracer observations. A tracer test in Säva Brook, Sweden was evaluated using a coupled physical-biogeochemical model framework containing surface water transport together with a representation of transient storage in slow/immobile zones of the stream, which are presumably important for the retention and attenuation of pharmaceuticals. To assess the key processes affecting the environmental fate of the compounds, we linked the uncertainty estimates of the reaction rate coefficients to the relative influence of transformation and sorption that occurred in different stream environments. The hydrological and biogeochemical contributions to the fate of the pharmaceuticals were decoupled, and the results indicate a moderate hydrological retention in the hyporheic zone as well as in the densely vegetated parts of the stream. Biogeochemical reactions in these transient storage zones further affected the fate of the pharmaceuticals, and we found that sorption was the key process for bezafibrate, metoprolol, and naproxen, while primary transformation was the most important process for clofibric acid and ibuprofen. Conversely, diclofenac was not affected by sorption or transformation. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Vitrification of waste with conitnuous filling and sequential melting

    DOEpatents

    Powell, James R.; Reich, Morris

    2001-09-04

    A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste. Then the heat is applied to a new lower zone above the melted waste and the process of adding, drying and melting the waste continues upward in the canister until the entire canister is filled and the entire contents are melted and maintained at the target temperature for the desired period. Cooling of the melted waste takes place incrementally from the bottom of the canister to the top, or across the entire canister surface area, forming a vitrified product.

  19. Heat waves and jet stream relations - nature of dry and wet shifts around the 2.8 kyr BP event in Central Europe

    NASA Astrophysics Data System (ADS)

    Slowinski, M. M.; Persoiu, A.; Slowinska, S.; Marcisz, K.; Ionita, M.; Lamentowicz, M.

    2017-12-01

    Solar insolation was the main driver of N Hemisphere storm tracks changes, with significant impacts on European climate variability during the Holocene. Consequently, the Homeric solar minimum, which occurred between 2,750 and 2,550 cal BP, was characterized by cooling and increase in wind strength and humidity in W Europe. In contrast, environmental reconstructions from Central and E Europe show that the climatic changes during this period were often more complex, with increased hydrological instability and a shift towards drier conditions. These contrasting conditions could be explained by the blocking in a stationary position of a high-pressure system above Central and E Europe as a result of the behavior of the jet stream. In order to understand how these changes in the behavior of the jet stream were acting in the past, we have analyzed a modern analogue to better understand the climatic map of Europe during the Homeric minimum of the 9th century BC. Thus, in summer 2015, a northward extending meander of the jet stream led to dry and hot conditions in C Europe, blocking the transport of Atlantic-sourced moisture eastwards and leading to increased precipitation in W Europe. Contrary, in 2013, the position of the high-pressure cells associated with the meandering of the jet-stream was located over W Russia and E Europe (both affected by heat waves resulting from meridional advection of dry/hot air), leading to more Rossby waves breaking over C Europe and delivering record amounts of precipitation. To test whether a similar mechanism could act on longer times scales, we have analyzed two high-resolution palaeoclimate datasets from E Europe (Rąbień peatbog, Poland and Scăriloara Ice Cave, Romania), located in areas with both N Atlantic and Mediterranean climatic influences. At the time of the Homeric Solar Minimum, warm climatic conditions dominated in SE Europe, with advection of warm and dry air from the Mediterranean. W Europe was rather wet around that time and these contrasting conditions could have been the result of blocking conditions over C Europe, induced by a solar-influenced strongly meandering jet-stream. Our recent monitoring observation and paleoclimate data support studies that presents link between arctic polar vortex, jet streams, sea-ice formation in the Arctic and climate variability in Europe.

  20. Excavation multiple up drafting tunnels in coastal mountains: A simple solution to resist against the severe drought in sub tropical zones

    NASA Astrophysics Data System (ADS)

    Daei, Mohammad Ali; Daei, Manizheh; Daei, Bijan

    2017-04-01

    At many sub tropical places in the globe, including the Persian Gulf in the south of Iran, there is continuously a tremendous amount of steam in the air, but it fails to transform to cloud because of the surrounding overheated lands. Reduction in precipitation in these regions has been extraordinary in recent years. The most probable reason is the global warming phenomena. Many dried forest remains, in these regions are referring to much more precipitations not long ago. All around the Persian Gulf, Oman Sea, Arab sea, and red sea there are enough steam to produce good precipitation nearly year round. The main missed requirement in this zone is the coldness. This fact can be well understand from a narrow green strip in Dhofar which is indebted to a cold oceanic stream that approaches to local shore during four months yearly. This natural cold stream helps a better condensation of water vapor and more precipitation but only in a narrow mountainous land. Based on this natural phenomenon, we hypothesize a different design to cool the water vapor with the same result. Prevention of close contact between the water vapors and hot lands by shooting the steam directly into the atmosphere may help to produce more cloud and rain. Making multiple vertical tunnels in mountains for upright conducting of humid air into the atmosphere can be a solution. Fortunately there are a few high mountain ranges alongside of the coastline in south part of Iran. So excavation of drafting tunnels in these mountains seems reasonable. These structures act passively, but for long term do their work without consuming energy, and making pollution. These earth tubes in some aspects resemble to Kariz, another innovative structure which invented by ancient Iranians, thousands of years ago in order to extract water from dry lands in deserts. Up drafting earth channels can be supposed as a wide vertical kariz which conduct water vapor into the atmosphere from the hot land near a warm sea, something like passive cooling towers in power plants. Many experiments and practices are indicating that these simple, cheap, and environmentally friendly structures can work continuously and effectively without an operator. We expect hundreds of these structures alongside the coastline in the south, will be able to change the local climate positively forever. Also upright earth tubes may have extra benefits if we choose the right points for drilling. Chasing escaping streams, finding precious minerals and stones, producing well ventilated area for recreation are among of the probable opportunities. Almost certainly, these by-products, in majority of cases will compensate the costs. Key words: up drafting tunnels, conducting water vapor, steam, cloud and rain production, hot lands. Global warming

  1. Quantification of mass loading to Strawberry Creek near the Gilt Edge mine, Lawrence County, South Dakota, June 2003

    USGS Publications Warehouse

    Kimball, Briant A.; Runkel, Robert L.; Walton-Day, Katherine; Williamson, Joyce E.

    2006-01-01

    Although remedial actions have taken place at the Gilt Edge mine in the Black Hills of South Dakota, questions remain about a possible hydrologic connection along shear zones between some of the pit lakes at the mine site and Strawberry Creek. Spatially detailed chemical sampling of stream and inflow sites occurred during low-flow conditions in June 2003 as part of a mass-loading study by the U.S. Geological Survey to investigate the possible connection of shear zones to the stream. Stream discharge was calculated by tracer dilution; discharge increased by 25.3 liters per second along the study reach, with 9.73 liters per second coming from three tributaries and the remaining increase coming from small springs and dispersed, subsurface inflow. Chemical differences among inflow samples were distinguished by cluster analysis and indicated that inflows ranged from those unaffected by interaction with mine wastes to those that could have been affected by drainage from pit lakes. Mass loading to the stream from several inflows resulted in distinct chemical changes in stream water along the study reach. Mass loading of the mine-related metals, including cadmium, copper, nickel, and zinc, principally occurred from the discharge from the Gilt Edge mine, and those metals were substantially attenuated downstream. Secondary loadings of metals occurred in the vicinity of the Oro Fino shaft and from two more inflows about 200 m downstream from there. These are both locations where shear zones intersect the stream and may indicate loading associatedwith these zones. Loading downstream from the Oro Fino shaft had a unique chemical character, high in base-metal concentrations, that could indicate an association with water in the pit lakes. The loading from these downstream sources, however, is small in comparison to that from the initial mine discharge and does not appear to have a substantial impact on Strawberry Creek.

  2. BEST Engineered Hyporheic Zones: Enhanced Hyporheic Exchange and Resazurin and Nitrate Cycling in Constructed Stream Experiments

    NASA Astrophysics Data System (ADS)

    Herzog, S.; McCray, J. E.; Higgins, C. P.

    2016-12-01

    The hyporheic zone is a hotspot for biogeochemical processing that can attenuate a variety of nonpoint source contaminants in streamwater. However, hyporheic zones in urban and agricultural streams are often degraded and poorly connected with surface water. To increase hyporheic exchange and improve water quality, we introduced engineered streambeds as a stormwater and restoration best management practice. Modifications to streambed hydraulic conductivity and reactivity are termed Biohydrochemical Enhancements for Streamwater Treatment (BEST). BEST are subsurface modules that utilize low-permeability sediments to drive efficient hyporheic exchange, and reactive geomedia to increase reaction rates within the hyporheic zone. This research utilized two artificial stream flumes at the Colorado School of Mines in Golden, CO. Each lined stream flume was 15m long, 0.3m wide, had 0.3m sediment depth, and was continuously dosed with recycled water at 0.25 L/s. One flume served as an all-sand control condition, the other featured BEST modules at 1m spacing with a mixture of 70/30 sand/woodchips (v/v). NaCl breakthrough curves were monitored and analyzed using STAMMT-L, a mobile-immobile exchange model, which showed greater hyporheic exchange and residence times in the BEST stream relative to the control. This result is even more apparent when the calibrated models are used to simulate longer stream reaches. Water quality samples at the reach scale also revealed greater attenuation of nitrate and transformation of the indicator compound resazurin into resorufin. Together these compounds demonstrate that BEST can attenuate contaminants that degrade under anaerobic and aerobic conditions, respectively. These experimental results were also compared to previous numerical simulations to evaluate model accuracy, and show reasonable agreement. Altogether, these results show that BEST may be an effective novel best management practice for improving streamwater quality in urban and agricultural settings.

  3. An analytic description of electrodynamic dispersion in free-flow zone electrophoresis.

    PubMed

    Dutta, Debashis

    2015-07-24

    The present work analyzes the electrodynamic dispersion of sample streams in a free-flow zone electrophoresis (FFZE) chamber resulting due to partial or complete blockage of electroosmotic flow (EOF) across the channel width by the sidewalls of the conduit. This blockage of EOF has been assumed to generate a pressure-driven backflow in the transverse direction for maintaining flow balance in the system. A parallel-plate based FFZE device with the analyte stream located far away from the channel side regions has been considered to simplify the current analysis. Applying a method-of-moments formulation, an analytic expression was derived for the variance of the sample zone at steady state as a function of its position in the separation chamber under these conditions. It has been shown that the increase in stream broadening due to the electrodynamic dispersion phenomenon is additive to the contributions from molecular diffusion and sample injection, and simply modifies the coefficient for the hydrodynamic dispersion term for a fixed lateral migration distance of the sample stream. Moreover, this dispersion mechanism can dominate the overall spatial variance of analyte zones when a significant fraction of the EOF is blocked by the channel sidewalls. The analysis also shows that analyte streams do not undergo any hydrodynamic broadening due to unwanted pressure-driven cross-flows in an FFZE chamber in the absence of a transverse electric field. The noted results have been validated using Monte Carlo simulations which further demonstrate that while the sample concentration profile at the channel outlet approaches a Gaussian distribution only in FFZE chambers substantially longer than the product of the axial pressure-driven velocity and the characteristic diffusion time in the system, the spatial variance of the exiting analyte stream is well described by the Taylor-Aris dispersion limit even in analysis ducts much shorter than this length scale. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Riparian control of stream-water chemistry: Implications for hydrochemical basin models

    USGS Publications Warehouse

    Hooper, R.P.; Aulenbach, Brent T.; Burns, Douglas A.; McDonnell, J.; Freer, J.; Kendall, C.; Beven, K.

    1998-01-01

    End-member mixing analysis has been used to determine the hydrological structure for basin hydrochemical models at several catchments. Implicit in this use is the assumption that controlling end members have been identified, and that these end members represent distinct landscape locations. At the Panola Mountain Research Watershed, the choice of controlling end members was supported when a large change in the calcium and sulphate concentration of one of the end members was reflected in the stream water. More extensive sampling of groundwater and soil water indicated, however, that the geographic extent of the contributing end members was limited to the riparian zone. Hillslope solutions were chemically distinct from the riparian solutions and did not appear to make a large contribution to streamflow. The dominant control of the riparian zone on stream-water chemistry suggests that hydrological flow paths cannot be inferred from stream-water chemical dynamics.

  5. Air-water ‘tornado’-type microwave plasmas applied for sugarcane biomass treatment

    NASA Astrophysics Data System (ADS)

    Bundaleska, N.; Tatarova, E.; Dias, F. M.; Lino da Silva, M.; Ferreira, C. M.; Amorim, J.

    2014-02-01

    The production of cellulosic ethanol from sugarcane biomass is an attractive alternative to the use of fossil fuels. Pretreatment is needed to separate the cellulosic material, which is packed with hemicellulose and lignin in cell wall of sugarcane biomass. A microwave ‘tornado’-type air-water plasma source operating at 2.45 GHz and atmospheric pressure has been applied for this purpose. Samples of dry and wet biomass (˜2 g) have been exposed to the late afterglow plasma stream. The experiments demonstrate that the air-water highly reactive plasma environment provides a number of long-lived active species able to destroy the cellulosic wrapping. Scanning electron microscopy has been applied to analyse the morphological changes occurring due to plasma treatment. The effluent gas streams have been analysed by Fourier-transform infrared spectroscopy (FT-IR). Optical emission spectroscopy and FT-IR have been applied to determine the gas temperature in the discharge and late afterglow plasma zones, respectively. The optimal range of the operational parameters is discussed along with the main active species involved in the treatment process. Synergistic effects can result from the action of singlet O2(a 1Δg) oxygen, NO2, nitrous acid HNO2 and OH hydroxyl radical.

  6. 40 CFR 63.322 - Standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-perchloroethylene gas-vapor stream contained within each dry cleaning machine through a refrigerated condenser or an... contained within each dry cleaning machine through a refrigerated condenser or an equivalent control device...' specifications and recommendations. (e) Each refrigerated condenser used for the purposes of complying with...

  7. 40 CFR 63.322 - Standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalent control device. (2) Route the air-perchloroethylene gas-vapor stream contained within each dry... contained within each dry cleaning machine through a refrigerated condenser or an equivalent control device... cleaning machine drum through a carbon adsorber or equivalent control device immediately before or as the...

  8. 40 CFR 63.322 - Standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... equivalent control device. (2) Route the air-perchloroethylene gas-vapor stream contained within each dry... contained within each dry cleaning machine through a refrigerated condenser or an equivalent control device... cleaning machine drum through a carbon adsorber or equivalent control device immediately before or as the...

  9. Human-water interactions in Myanmar's Dry Zone under climate change

    NASA Astrophysics Data System (ADS)

    Taft, Linda; Evers, Mariele

    2016-04-01

    Understanding human-water interactions is particularly essential in countries where the economy and the people's well-being and income strongly depend on the availability and quality of sufficient water resources. Such a strong dependency on water is existent in Myanmar's Dry Zone located in the central Ayeyarwady River basin. In this area, rainfall is associated with high heterogeneity across space and time. Precipitation amounts in the Dry Zone (500-1000 mm annually) are generally less compared to other regions in Myanmar (up to 4000-6000 mm). Following the Global Climate Risk Index, Myanmar is one of the countries which were most affected by extreme weather events between 1994 and 2013. Severe drought periods e.g in the years 1997-1998, 2010 and 2014 led to crop failures and water shortage in the Dry Zone, where more than 14 mio people predominantly practice agriculture. Due to the high variability of rainfalls, farming is only possible with irrigation, mainly conducted by canal systems from the rivers and groundwater withdrawal. Myanmar is recently facing big challenges which result from comprehensive political and economic reforms since 2011. These may also include increasing water use by new industrial zones and urbanization. However, not only policy and economy modify the need for water. Variability of river runoff and changes in seasonality are expected as a result of climate change. The overarching goal of the study is to understand and increase the knowledge on human-water-climate interactions and to elaborate possible future scenarios for Myanmar's Dry Zone. It is not well studied yet how current and future climate change and increasing human impact will influence the country's abundant water resources including groundwater. Therefore, the first step of this study is to identify the major drivers within the central Ayeyarwady River basin. We are in the process of collecting and analyzing data sets and information including hydrologic and eco-hydrologic (discharge, sediment load, river biology), climatic (precipitation, temperature, evaporation) and anthropologic (water use, water management, dam projects) aspects. We identified key study sites in the Dry Zone, in order to assess and study the interplays, dependencies and feedbacks within the human-water system. First results based on meteorological data sets and literature survey indicate, that the central Dry Zone is affected by increasing interannual rainfall variability. Additionally, human impacts in this region are increasing due to numerous pumping (both river and groundwater) activities which will possibly alter water availability, river ecology and hydraulic processes in the near future. At the current state, the main course of the Ayeyarwady River is still unregulated but several larger dam projects are in the planning phase in the central area which will also impact the rich river biodiversity as well as the society. Our research will contribute to understand human-water-climate interactions in Myanmar's central Dry Zone with possible transferability to other large river basins in Asia.

  10. Wet and dry atmospheric depositions of inorganic nitrogen during plant growing season in the coastal zone of Yellow River Delta.

    PubMed

    Yu, Junbao; Ning, Kai; Li, Yunzhao; Du, Siyao; Han, Guangxuan; Xing, Qinghui; Wu, Huifeng; Wang, Guangmei; Gao, Yongjun

    2014-01-01

    The ecological problems caused by dry and wet deposition of atmospheric nitrogen have been widespread concern in the world. In this study, wet and dry atmospheric depositions were monitored in plant growing season in the coastal zone of the Yellow River Delta (YRD) using automatic sampling equipment. The results showed that SO4 (2-) and Na(+) were the predominant anion and cation, respectively, in both wet and dry atmospheric depositions. The total atmospheric nitrogen deposition was ~2264.24 mg m(-2), in which dry atmospheric nitrogen deposition was about 32.02%. The highest values of dry and wet atmospheric nitrogen deposition appeared in May and August, respectively. In the studied area, NO3 (-)-N was the main nitrogen form in dry deposition, while the predominant nitrogen in wet atmospheric deposition was NH4 (+)-N with ~56.51% of total wet atmospheric nitrogen deposition. The average monthly attribution rate of atmospheric deposition of NO3 (-)-N and NH4 (+)-N was ~31.38% and ~20.50% for the contents of NO3 (-)-N and NH4 (+)-N in 0-10 cm soil layer, respectively, suggested that the atmospheric nitrogen was one of main sources for soil nitrogen in coastal zone of the YRD.

  11. Ultrafiltration of thin stillage from conventional and e-mill dry grind processes.

    PubMed

    Arora, Amit; Dien, Bruce S; Belyea, Ronald L; Wang, Ping; Singh, Vijay; Tumbleson, M E; Rausch, Kent D

    2011-05-01

    We used ultrafiltration (UF) to evaluate membrane filtration characteristics of thin stillage and determine solids and nutrient compositions of filtered streams. To obtain thin stillage, corn was fermented using laboratory methods. UF experiments were conducted in batch mode under constant temperature and flow rate conditions. Two regenerated cellulose membranes (10 and 100 kDa molecular weight cutoffs) were evaluated with the objective of retaining solids as well as maximizing permeate flux. Optimum pressures for 10 and 100 kDa membranes were 207 and 69 kPa, respectively. Total solids, ash, and neutral detergent fiber contents of input TS streams of dry grind and E-Mill processes were similar; however, fat and protein contents were different (p < 0.05). Retentate obtained from conventional thin stillage fractionation had higher mean total solids contents (27.6% to 27.8%) compared to E-Mill (22.2% to 23.4%). Total solids in retentate streams were found similar to those from commercial evaporators used in industry (25% to 35% total solids). Fat contents of retentate streams ranged from 16.3% to 17.5% for the conventional process. A 2% increment in fat concentration was observed in the E-Mill retentate stream. Thin stillage ash content was reduced 60% in retentate streams.

  12. The mass distribution of coarse particulate organic matter exported from an Alpine headwater stream

    NASA Astrophysics Data System (ADS)

    Turowski, J. M.; Badoux, A.; Bunte, K.; Rickli, C.; Federspiel, N.; Jochner, M.

    2013-09-01

    Coarse particulate organic matter (CPOM) particles span sizes from 1 mm, with a dry mass less than 1 mg, to large logs and entire trees, which can have a dry mass of several hundred kilograms. Pieces of different size and mass play different roles in stream environments, from being the prime source of energy in stream ecosystems to macroscopically determining channel morphology and local hydraulics. We show that a single scaling exponent can describe the mass distribution of CPOM heavier than 0.1 g transported in the Erlenbach, a steep mountain stream in the Swiss pre-Alps. This exponent takes an average value of -1.8, is independent of discharge and valid for particle masses spanning almost seven orders of magnitude. Similarly, the mass distribution of in-stream large woody debris (LWD) in several Swiss streams can be described by power law scaling distributions, with exponents varying between -1.8 and -2.0, if all in-stream LWD is considered, and between -1.3 and -1.8 for material locked in log jams. We found similar values for in-stream and transported material in the literature. We had expected that scaling exponents are determined by stream type, vegetation, climate, substrate properties, and the connectivity between channels and hillslopes. However, none of the descriptor variables tested here, including drainage area, channel bed slope and the percentage of forested area, show a strong control on exponent value. Together with a rating curve of CPOM transport rates with discharge, the scaling exponents can be used in the design of measuring strategies and in natural hazard mitigation.

  13. Sediment record of environmental change at Lake Lop Nur (Xinjiang, NW China) from 13.0 to 5.6 cal ka BP

    NASA Astrophysics Data System (ADS)

    Wang, Jingzhong; Jia, Hongjuan

    2017-09-01

    Lake Lop Nur is located in the eastern part of the Tarim Basin in Xinjiang, northwestern China. A 220-cm-long sediment core was collected from the center of the ear-shaped depression forming the basin and dated with AMS14C. Grain size, total organic matter (TOC), total nitrogen (TN), and TOC/TN (C/N) analyses were used to reconstruct climatic conditions from 13.0 to 5.6 cal ka BP. The results showed five main climatic stages. Zone I (13.0-11.3 cal ka BP) was a wet-dry environment, whereas Zone II (11.3-8.9 cal ka BP) consisted of a primarily wet environment. Zone III (8.9-7.7 cal ka BP) was subdivided into Zone IIIa (8.9-8.2 cal ka BP) that indicated lake constriction and dry climate, and Zone IIIb (8.2-7.7 cal ka BP) in which the proxies indicated wet conditions. In Zone IV (7.7-6.6 cal ka BP), the climate presented a bit wet conditions. In Zone V (6.6-5.6 cal ka BP), abundant glauberite is present in the sediment and silt dominates the lithology; these results indicate the lake shrank and the overall climate was dry. Abrupt environmental events were also identified, including six dry events at 11.0, 10.5, 9.3, 8.6, 8.2, and 7.6 cal ka BP and one flood event from 7.8 to 7.7 cal ka BP in the Early-Middle Holocene.

  14. Brook trout use of thermal refugia and foraging habitat influenced by brown trout

    USGS Publications Warehouse

    Hitt, Nathaniel P.; Snook, Erin; Massie, Danielle L.

    2017-01-01

    The distribution of native brook trout (Salvelinus fontinalis) in eastern North America is often limited by temperature and introduced brown trout (Salmo trutta), the relative importance of which is poorly understood but critical for conservation and restoration planning. We evaluated effects of brown trout on brook trout behavior and habitat use in experimental streams across increasing temperatures (14–23 °C) with simulated groundwater upwelling zones providing thermal refugia (6–9 °C below ambient temperatures). Allopatric and sympatric trout populations increased their use of upwelling zones as ambient temperatures increased, demonstrating the importance of groundwater as thermal refugia in warming streams. Allopatric brook trout showed greater movement rates and more even spatial distributions within streams than sympatric brook trout, suggesting interference competition by brown trout for access to forage habitats located outside thermal refugia. Our results indicate that removal of introduced brown trout may facilitate native brook trout expansion and population viability in downstream reaches depending in part on the spatial configuration of groundwater upwelling zones.

  15. Discharge of New Subglacial Lake on Whillians Ice Stream: Implication for Ice Stream Flow Dynamics.

    NASA Astrophysics Data System (ADS)

    Sergienko, O. V.; Fricker, H. A.; Bindschadler, R. A.; Vornberger, P. L.; Macayeal, D. R.

    2006-12-01

    One of the surprise discoveries made possible by the ICESat laser altimeter mission of 2004-2006 is the presence of a large subglacial lake below the grounding zone of Whillians Ice Stream (dubbed here `Lake Helen' after the discoverer, Helen Fricker). What is even more surprising is the fact that this lake discharged a substantial portion of its volume during the ICESat mission, and changes in lake volume and surface elevation of the ice stream are documented in exquisite detail [Fricker et al., in press]. The presence and apparent dynamism of large subglacial lakes in the grounding zone of a major ice stream raises questions about their effects on ice-stream dynamics. Being liquid and movable, water modifies basal friction spatially and temporally. Melting due to shear heating and geothermal flux reduces basal traction, making the ice stream move fast. However, when water collects in a depression to form a lake, it potentially deprives the surrounding bed of lubricating water, and additionally makes the ice surface flat, thereby locally decreasing the ice stream driving stress. We study the effect of formation and discharge of a subglacial lake at the mouth of and ice stream using a two dimensional, vertically integrated, ice-stream model. The model is forced by the basal friction, ice thickness and surface elevation. The basal friction is obtained by inversion of the ice surface velocity, ice thickness and surface elevation come from observations. To simulate the lake formation we introduce zero basal friction and "inflate" the basal elevation of the ice stream at the site of the lake. Sensitivity studies of the response of the surrounding ice stream and ice shelf flow are performed to delineate the influence of near-grounding-line subglacial water storage for ice streams in general.

  16. Extrapolating regional probability of drying of headwater streams using discrete observations and gauging networks

    NASA Astrophysics Data System (ADS)

    Beaufort, Aurélien; Lamouroux, Nicolas; Pella, Hervé; Datry, Thibault; Sauquet, Eric

    2018-05-01

    Headwater streams represent a substantial proportion of river systems and many of them have intermittent flows due to their upstream position in the network. These intermittent rivers and ephemeral streams have recently seen a marked increase in interest, especially to assess the impact of drying on aquatic ecosystems. The objective of this paper is to quantify how discrete (in space and time) field observations of flow intermittence help to extrapolate over time the daily probability of drying (defined at the regional scale). Two empirical models based on linear or logistic regressions have been developed to predict the daily probability of intermittence at the regional scale across France. Explanatory variables were derived from available daily discharge and groundwater-level data of a dense gauging/piezometer network, and models were calibrated using discrete series of field observations of flow intermittence. The robustness of the models was tested using an independent, dense regional dataset of intermittence observations and observations of the year 2017 excluded from the calibration. The resulting models were used to extrapolate the daily regional probability of drying in France: (i) over the period 2011-2017 to identify the regions most affected by flow intermittence; (ii) over the period 1989-2017, using a reduced input dataset, to analyse temporal variability of flow intermittence at the national level. The two empirical regression models performed equally well between 2011 and 2017. The accuracy of predictions depended on the number of continuous gauging/piezometer stations and intermittence observations available to calibrate the regressions. Regions with the highest performance were located in sedimentary plains, where the monitoring network was dense and where the regional probability of drying was the highest. Conversely, the worst performances were obtained in mountainous regions. Finally, temporal projections (1989-2016) suggested the highest probabilities of intermittence (> 35 %) in 1989-1991, 2003 and 2005. A high density of intermittence observations improved the information provided by gauging stations and piezometers to extrapolate the temporal variability of intermittent rivers and ephemeral streams.

  17. Escape tectonics and the extrusion of Alaska: Past, present, and future

    USGS Publications Warehouse

    Redfield, T.F.; Scholl, D. W.; Fitzgerald, P.G.; Beck, M.E.

    2007-01-01

    The North Pacific Rim is a tectonically active plate boundary zone parts of which may be characterized as a laterally moving orogenic stream. Crustal blocks are transported along large-magnitude strike-slip faults in western Canada and central Alaska toward the Aleutian-Bering Sea subduction zones. Throughout much of the Cenozoic, at and west of its Alaskan nexus, the North Pacific Rim orogenic Stream (NPRS) has undergone tectonic escape. During transport, relatively rigid blocks acquired paleomagnetic rotations and fault-juxtaposed boundaries while flowing differentially through the system, from their original point of accretion and entrainment toward the free face defined by the Aleutian-Bering Sea subduction zones. Built upon classical terrane tectonics, the NPRS model provides a new framework with which to view the mobilistic nature of the western North American plate boundary zone. ?? 2007 The Geological Society of America.

  18. Fluxes of carbon dioxide and methane from diverse aquatic environments in an agricultural landscape

    NASA Astrophysics Data System (ADS)

    Stanley, E. H.; Crawford, J. T.; Loken, L. C.; Casson, N. J.; Gubbins, N. J.; Oliver, S. K.

    2014-12-01

    The contribution of aquatic environments to landscape carbon cycling is particularly apparent in carbon- and water-rich regions. Such areas arguably represent an end member in terms of the relative significance of aquatic carbon cycling, while dry, carbon-poor zones are the likely opposing end member. Not surprisingly, most limnological attention has focused on these former regions, leaving open questions as to how aquatic systems in other locales influence larger-scale carbon dynamics. This includes human-dominated landscapes where agricultural and urban land uses can fundamentally alter carbon dynamics. Surveys of streams, ponds, and lakes in a southern Wisconsin landscape highlight three findings relevant to understanding the role of these aquatic systems in larger-scale carbon dynamics. First, streams and ponds had unexpectedly high summertime concentrations in and fluxes of CO2 and CH4. These values were approximately an order of magnitude greater than for less disturbed, forest and wetland-dominated landscapes in northern Wisconsin. Second, while mean C gas concentrations in lakes were lower than in streams and ponds, detailed spatial measurements demonstrate variability in surface water CO2 (43-1090 ppm pCO2) and CH4 (6-839 ppm pCH4) within a lake on a single day is similar to that observed among 25 streams included in our survey (260-6000 ppm pCO2; 50-600 ppm pCH4). This small-scale heterogeneity highlights a basic challenge for upscaling site-specific data collected at one or a few points to the whole lake and across lakes. Third, while agricultural and urban ecosystems are not necessarily carbon-rich environments, area-specific carbon storage in streams and ponds is substantial (up to 3000-5000 g C per m2). Further, carbon storage was strongly related to CH4 concentrations in streams, as C-rich sediments provided both an environment and substrate to fuel methanogenesis. The picture that emerges of C processing in aquatic environments throughout this human-dominated landscape is one of large C pools and fluxes and high spatial variability, suggesting that these land uses may be accelerating rates of aquatic C cycling and amplifying the role of these ecosystems in anthropogenic landscapes.

  19. Predicting changes in hydrologic retention in an evolving semi-arid alluvial stream

    USGS Publications Warehouse

    Harvey, J.W.; Conklin, M.H.; Koelsch, R.S.

    2003-01-01

    Hydrologic retention of solutes in hyporheic zones or other slowly moving waters of natural channels is thought to be a significant control on biogeochemical cycling and ecology of streams. To learn more about factors affecting hydrologic retention, we repeated stream-tracer injections for 5 years in a semi-arid alluvial stream (Pinal Creek, Ariz.) during a period when streamflow was decreasing, channel width increasing, and coverage of aquatic macrophytes expanding. Average stream velocity at Pinal Creek decreased from 0.8 to 0.2 m/s, average stream depth decreased from 0.09 to 0.04 m, and average channel width expanded from 3 to 13 m. Modeling of tracer experiments indicated that the hydrologic retention factor (Rh), a measure of the average time that solute spends in storage per unit length of downstream transport, increased from 0.02 to 8 s/m. At the same time the ratio of cross-sectional area of storage zones to main channel cross-sectional area (As/A) increased from 0.2 to 0.8 m2/m2, and average water residence time in storage zones (ts) increased from 5 to 24 min. Compared with published data from four other streams in the US, Pinal Creek experienced the greatest change in hydrologic retention for a given change in streamflow. The other streams differed from Pinal Creek in that they experienced a change in streamflow between tracer experiments without substantial geomorphic or vegetative adjustments. As a result, a regression of hydrologic retention on streamflow developed for the other streams underpredicted the measured increases in hydrologic retention at Pinal Creek. The increase in hydrologic retention at Pinal Creek was more accurately predicted when measurements of the Darcy-Weisbach friction factor were used (either alone or in addition to streamflow) as a predictor variable. We conclude that relatively simple measurements of channel friction are useful for predicting the response of hydrologic retention in streams to major adjustments in channel morphology as well as changes in streamflow. Published by Elsevier Ltd.

  20. Flume experiments elucidate relationships between stream morphology, hyporheic residence time, and nitrous oxide production

    NASA Astrophysics Data System (ADS)

    Quick, Annika; Farrell, Tiffany B.; Reeder, William Jeffrey; Feris, Kevin P.; Tonina, Daniele; Benner, Shawn G.

    2015-04-01

    The hyporheic zone is a potentially important producer of nitrous oxide, a powerful greenhouse gas. The location and magnitude of nitrous oxide generation within the hyporheic zone involves complex interactions between multiple nitrogen species, redox conditions, microbial communities, and hydraulics. To better understand nitrous oxide generation and emissions from streams, we conducted large-scale flume experiments in which we monitored pore waters along hyporheic flow paths within stream dune structures. Measurements of dissolved oxygen, ammonia, nitrate, nitrite, and dissolved nitrous oxide showed distinct spatial relationships reflecting redox changes along flow paths. Using residence times along a flow path, clear trends in oxygen conditions and nitrogen species were observed. Three dune sizes were modeled, resulting in a range of residence times, carbon reactivity levels and respiration rates. We found that the magnitude and location of nitrous oxide production in the hyporheic zone is related to nitrate loading, dune morphology, and residence time. Specifically, increasing exogenous nitrate levels in surface water to approximately 3 mg/L resulted in an increase in dissolved N2O concentrations greater than 500% (up to 10 µg/L N-N2O) in distinct zones of specific residence times. We also found, however, that dissolved N2O concentrations decreased to background levels further along the flow path due to either reduction of nitrous oxide to dinitrogen gas or degassing. The decrease in measurable N2O along a flow path strongly suggests an important relationship between dune morphology, residence time, and nitrous oxide emissions from within stream sediments. Relating streambed morphology and loading of nitrogen species allows for prediction of nitrous oxide production in the hyporheic zone of natural systems.

  1. Quantifying hyporheic exchange at high spatial resolution using natural temperature variations along a first-order stream

    NASA Astrophysics Data System (ADS)

    Westhoff, M. C.; Gooseff, M. N.; Bogaard, T. A.; Savenije, H. H. G.

    2011-10-01

    Hyporheic exchange is an important process that underpins stream ecosystem function, and there have been numerous ways to characterize and quantify exchange flow rates and hyporheic zone size. The most common approach, using conservative stream tracer experiments and 1-D solute transport modeling, results in oversimplified representations of the system. Here we present a new approach to quantify hyporheic exchange and the size of the hyporheic zone (HZ) using high-resolution temperature measurements and a coupled 1-D transient storage and energy balance model to simulate in-stream water temperatures. Distributed temperature sensing was used to observe in-stream water temperatures with a spatial and temporal resolution of 2 and 3 min, respectively. The hyporheic exchange coefficient (which describes the rate of exchange) and the volume of the HZ were determined to range between 0 and 2.7 × 10-3 s-1 and 0 and 0.032 m3 m-1, respectively, at a spatial resolution of 1-10 m, by simulating a time series of in-stream water temperatures along a 565 m long stretch of a small first-order stream in central Luxembourg. As opposed to conventional stream tracer tests, two advantages of this approach are that exchange parameters can be determined for any stream segment over which data have been collected and that the depth of the HZ can be estimated as well. Although the presented method was tested on a small stream, it has potential for any stream where rapid (in regard to time) temperature change of a few degrees can be obtained.

  2. Transport and transformation of soil-derived CO2, CH4 and DOC sustain CO2 supersaturation in small boreal streams.

    PubMed

    Rasilo, Terhi; Hutchins, Ryan H S; Ruiz-González, Clara; Del Giorgio, Paul A

    2017-02-01

    Streams are typically supersaturated in carbon dioxide (CO 2 ) and methane (CH 4 ), and are recognized as important components of regional carbon (C) emissions in northern landscapes. Whereas there is consensus that in most of the systems the CO 2 emitted by streams represents C fixed in the terrestrial ecosystem, the pathways delivering this C to streams are still not well understood. We assessed the contribution of direct soil CO 2 injection versus the oxidation of soil-derived dissolved organic C (DOC) and CH 4 in supporting CO 2 supersaturation in boreal streams in Québec. We measured the concentrations of CO 2 , CH 4 and DOC in 43 streams and adjacent soil waters during summer base-flow period. A mass balance approach revealed that all three pathways are significant, and that the mineralization of soil-derived DOC and CH 4 accounted for most of the estimated stream CO 2 emissions (average 75% and 10%, respectively), and that these estimated contributions did not change significantly between the studied low order (≤3) streams. Whereas some of these transformations take place in the channel proper, our results suggest that they mainly occur in the hyporheic zones of the streams. Our results further show that stream CH 4 emissions can be fully explained by soil CH 4 inputs. This study confirms that these boreal streams, and in particular their hyporheic zones, are extremely active processors of soil derived DOC and CH 4 , not just vents for soil produced CO 2 . Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Meet EPA Ecologist Paul Mayer, Ph.D.

    EPA Pesticide Factsheets

    EPA ecologist Paul Mayer, Ph.D. works in EPA's Groundwater and Ecosystem Restoration division where he studies riparian zones (the area along rivers and streams where the habitats are influenced by both the land and water) and stream restoration

  4. Continuous multi-component geophysical experiment on LUSI mud edifice: What can we learn from it?

    NASA Astrophysics Data System (ADS)

    Mauri, Guillaume; Husein, Alwi; Karyono, Karyono; Hadi, Soffian; Mazzini, Adriano; Collignon, Marine; Faubert, Maïté; Miller, Stephen A.; Lupi, Matteo

    2016-04-01

    The Lusi eruption is located in East Java, Indonesia, and is ongoing since May 29th, 2006. In the framework of joined international projects, several joint geophysical studies focussing on seismic monitoring, spatial investigation over the mud edifice and its surroundings are being conducted. Here we present freshly acquired data from a test site to investigate: (1) potential change in the natural electrical self-potential generation over time (2) potential change in gravity field associated to change in mass or volume, (3) if the geysering activity generates disruption on either the electrical or gravity field. We selected a location ˜200m to the NE of the active Lusi crater. The experiment site covers an area of 60m x 80m, crossing the boundaries between the soft and the solid walkable mud. The western edge of the study area was less than 100m away from the rim of the crater site. A self-potential array made of 6 Pb-PbCl2 electrodes was deployed over the site. The electrodes were positioned inside active seeps, on dry unaltered zones and close to the mud stream that flushes the water erupted from the crater site. All the electrodes were connected to a single Pb-PbCl2 electrode reference. A second array of 7 thermometers was installed positioning 5 of them next to SP electrodes, one to measure atmospheric temperature and another P/T probe to monitor the stream water. In addition a seismometer coupled with a HD video camera, a thermal camera and a gravimeter recorded on site for several days monitoring visual and seismic activity of the crater. The collected data allows us to 1) monitor and define the different geysering activities ongoing at the crater, 2) define the delay existing between the recorded seismicity and the visual observations, 3) verify if the crater activity triggers perturbations that are transmitted to e.g. the thousands of satellite seeps distributed in the 7 square kilometers zone inside the embankment; 4) how significant is the delay between the crater activity and the water streamed out.

  5. Novel Insights Linking Ecological Health to Biogeochemical Hotspots across the Groundwater-Surface Water Interface in Mixed Land Use Stream Systems

    NASA Astrophysics Data System (ADS)

    McKnight, U. S.; Sonne, A. T.; Rasmussen, J. J.; Rønde, V.; Traunspurger, W.; Höss, S.; Bjerg, P. L.

    2017-12-01

    Increasing modifications in land use and water management have resulted in multiple stressors impacting freshwater ecosystems globally. Chemicals with the potential to impact aquatic habitats are still often evaluated individually for their adverse effects on ecosystem health. This may lead to critical underestimations of the combined impact caused by interactions occurring between stressors not typically evaluated together, e.g. xenobiotic groundwater pollutants and trace metals. To address this issue, we identified sources and levels of chemical stressors along a 16-km groundwater-fed stream corridor (Grindsted, Denmark), representative for a mixed land use stream system. Potential pollution sources included two contaminated sites (factory, landfill), aquaculture, wastewater/industrial discharges, and diffuse sources from agriculture and urban areas. Ecological status was determined by monitoring meiobenthic and macrobenthic invertebrate communities.The stream was substantially impaired by both geogenic and anthropogenic sources of metals throughout the investigated corridor, with concentrations close to or above threshold values for barium, copper, lead, nickel and zinc in the stream water, hyporheic zone and streambed sediment. The groundwater plume from the factory site caused elevated concentrations of chlorinated ethenes, benzene and pharmaceuticals in both the hyporheic zone and stream, persisting for several km downstream. Impaired ecological conditions, represented by a lower abundance of meiobenthic individuals, were found in zones where the groundwater plume discharges to the stream. The effect was only pronounced in areas characterized by high xenobiotic organic concentrations and elevated dissolved iron and arsenic levels - linked to the dissolution of iron hydroxides caused by the degradation of xenobiotic compounds in the plume. The results thus provide ecological evidence for the interaction of organic and inorganic chemical stressors, which may provide a missing link enabling the reconnection of chemical and ecological findings. This study highlights the importance of stream-aquifer interfaces for ecosystem functioning in terms of biological habitat, and that multiple stressor systems need to be tackled from a holistic perspective.

  6. 40 CFR 60.698 - Reporting requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... § 60.696(c). (c) A report that summarizes all inspections when a water seal was dry or otherwise... 3-hour period of operation during which the average temperature of the gas stream in the combustion... the average temperature of the gas stream immediately before the catalyst bed of a catalytic...

  7. Estimating Fill-Spill Wetland Surface Connections in the Pipestem Creek, ND, Across Wet-Dry Conditions

    EPA Science Inventory

    Wetlands in the Prairie Pothole Region {PPR) can be connected via surface flows through a fill-spill mechanism, with some wetlands eventually spilling into stream/river systems. This wetland-to-wetland and wetland-to-stream connection of wetlands via fill-spill has high temporal ...

  8. Techniques of fisheries management: water quality assessment with stream insects

    Treesearch

    A. Dennis Lemly

    2000-01-01

    Nutrient enrichment of streams is a long-standing problem that continues to have substantial local and regional consequences. For example, water quality of streams in the southern Appalachian Mountains of the U.S. can be seriously degraded by organic nutrients leached from animal wastes if cattle or other livestock are allowed to graze in the riparian zone. Local...

  9. Hillslope hydrologic connectivity controls riparian groundwater turnover: Implications of catchment structure for riparian buffering and stream water sources

    Treesearch

    Kelsey G. Jencso; Brian L. McGlynn; Michael N. Gooseff; Kenneth E. Bencala; Steven M. Wondzell

    2010-01-01

    Hydrologic connectivity between catchment upland and near stream areas is essential for the transmission of water, solutes, and nutrients to streams. However, our current understanding of the role of riparian zones in mediating landscape hydrologic connectivity and the catchment scale export of water and solutes is limited. We tested the relationship between the...

  10. Probing the deep critical zone beneath the Luquillo Experimental Forest, Puerto Rico

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Buss, Heather; Brantley, S. L.; Scatena, Fred

    2013-01-01

    Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world s oceans, thereby exerting a primary control on global temperature via the well-known positive feedback between silicate weathering and CO2. In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g., soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed inmore » the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared to the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream.« less

  11. Probing the deep critical zone beneath the Luquillo Experimental Forest, Puerto Rico

    USGS Publications Warehouse

    Buss, Heather L.; Brantley, Susan L.; Scatena, Fred; Bazilevskaya, Katya; Blum, Alex E.; Schulz, Marjorie S.; Jiménez, Rafael; White, Arthur F.; Rother, G.; Cole, D.

    2013-01-01

    Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world's oceans, thereby exerting a primary control on global temperature via the well-known positive feedback between silicate weathering and CO2. In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g. soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared with the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream

  12. Spatial and Temporal Patterns of Dissolved Organic Matter Characteristics in the Upper Willamette River Basin, Oregon

    NASA Astrophysics Data System (ADS)

    Lee, B. S.; Lajtha, K.

    2014-12-01

    Dissolved organic matter (DOM) leaching through soil affects soil carbon sequestration and the carbon metabolism of receiving water bodies. Improving our understanding of the sources and fate of DOM at varying spatial and temporal patterns is crucial for land management decisions. However, little is known about how DOM sources change with land use types and seasonal flow patterns. In the Willamette River Basin (WRB), which is home to Oregon's major cities including Portland and Salem, forested headwaters transition to agricultural and urban land. The climate of WRB has a distinctive seasonal pattern with dry warm summers and wet winters driven by winter precipitation and snowmelt runoff between November and March. This study examined DOM fluorescence characteristic in stream water from 21 locations collected monthly and 16 locations collected seasonally to identify the sources and fate of DOM in the upper WRB in contrasting land uses. DOC and dissolved organic nitrogen concentrations increased as the flow rate increased during winter precipitation at all sites. This indicates that increased flow rate increased the connectivity between land and nearby water bodies. DOM fluorescent properties varied among land use types. During the first precipitation event after a long dry summer, a microbial DOM signature in agricultural areas increased along with nitrate concentrations. This may be because accumulated nutrients on land during the dry season flowed to nearby streams during the first rain event and promoted microbial growth in the streams. During the month of the highest flow rate in 2014, sampling sites near forest showed evidence of a greater terrestrial DOM signature compared to its signature during the dry season. This indicates fluorescent DOM characteristics in streams vary as the flow connectivity changes even within the same land type.

  13. A methodology for delineating planning-level channel migration zones.

    DOT National Transportation Integrated Search

    2014-07-01

    The Washington State administrative codes that implement the Shoreline Management Act (SMA) require communities to identify the general location of channel migration zones (CMZs), and regulate development within these areas on shoreline streams. Shor...

  14. Experimental manipulation of leaf litter colonization by aquatic invertebrates in a third order tropical stream.

    PubMed

    Uieda, V S; Carvalho, E M

    2015-05-01

    Through a manipulative experiment, the colonization of leaf litter by invertebrates was investigated in two sections of a tropical stream (spatial scale) that differed in function of the canopy cover, one with the presence (closed area) and another without riparian vegetation (open area), during one month of the dry and one of the wet season (temporal scale). The work aimed to verify differences related to four variables: season, canopy cover, leaf type and leaf condition. Litter bags containing arboreal and herbaceous leaves (leaf type variable), non-conditioned and preconditioned (leaf condition variable) were placed at the bottom of the stream in each area (canopy cover variable) and season (dry and wet), and removed after 13-day colonization. The analysis of the remaining litter dry mass per leaf bag emphasizes differences related mainly to seasonality, canopy cover and leaf type, although leaf condition was also important when combined with those three factors. Comparing the abundance of invertebrates per treatment, there was a tendency of high predominance of Chironomidae during the dry season and greater taxa diversity and evenness during the wet season, when the water flow increase could alter the availability of microhabitats for local fauna. Even though canopy cover alone was not a significant source of variation in the abundance of invertebrates, the results showed a tendency of a combined effect of canopy cover with seasonality and leaf condition.

  15. Environmental Assessment for the Blair Lakes Bombing Range Facility Improvements

    DTIC Science & Technology

    2006-03-01

    None of these sites would be impacted by range activities. In the event that historic or cultura l sites are discovered during range construction or...willow. These areas often contain seasonally persistent water bodies. Along stream courses (Willow and Dry Creek, and tributaries ) soils are...The only identified fish stream in the immediate facility area is an unnamed tributary of Clear Creek. The ADF&G has catalogued this stream as

  16. Explosion Amplitude Reduction due to Fractures in Water-Saturated and Dry Granite

    NASA Astrophysics Data System (ADS)

    Stroujkova, A. F.; Leidig, M.; Bonner, J. L.

    2013-12-01

    Empirical observations made at the Semipalatinsk Test Site suggest that nuclear tests in the fracture zones left by previous explosions ('repeat shots') show reduced seismic amplitudes compared to the nuclear tests in virgin rocks. Likely mechanisms for the amplitude reduction in the repeat shots include increased porosity and reduced strength and elastic moduli, leading to pore closing and frictional sliding. Presence of pore water significantly decreases rock compressibility and strength, thus affecting seismic amplitudes. A series of explosion experiments were conducted in order to define the physical mechanism responsible for the amplitude reduction and to quantify the degree of the amplitude reduction in fracture zones of previously detonated explosions. Explosions in water-saturated granite were conducted in central New Hampshire in 2011 and 2012. Additional explosions in dry granite were detonated in Barre, VT in 2013. The amplitude reduction is different between dry and water-saturated crystalline rocks. Significant reduction in seismic amplitudes (by a factor of 2-3) in water-saturated rocks was achieved only when the repeat shot was detonated in the extensive damage zone created by a significantly larger (by a factor of 5) explosion. In case where the first and the second explosions were similar in yield, the amplitude reduction was relatively modest (5-20%). In dry rocks the amplitude reduction reached a factor of 2 even in less extensive damage zones. In addition there are differences in frequency dependence of the spectral amplitude ratios between explosions in dry and water-saturated rocks. Thus the amplitude reduction is sensitive to the extent of the damage zone as well as the pore water content.

  17. Holding onto the Green Zone: A Youth Program for the Study and Stewardship of Community Riparian Areas. Action Guide

    ERIC Educational Resources Information Center

    US Department of the Interior, 2008

    2008-01-01

    Scientists call the land along the edges of a river, stream, or lake a riparian zone. In this guide, riparian zone will be called the Green Zone. Riparian zones make up only a small part of land in the United States. But they are very important. They protect water quality and quantity, supply food and shelter for fish and wildlife, and provide…

  18. Quantifying hyporheic exchange in a karst stream using 222Rn

    NASA Astrophysics Data System (ADS)

    Khadka, M. B.; Martin, J. B.; Kurz, M. J.

    2013-12-01

    The hyporheic zone is a critical interface between groundwater and river water environments and is characterized by steep biogeochemical gradients. Understanding how this interface affects solute transport, nutrient cycling and contaminant attenuation is essential for better water resource management of streams. However, this understanding is constrained due to difficulty associated with quantification of exchange of water through the hyporheic zone. We tested a radon (222Rn) method to estimate the hyporheic water residence time and exchange rate in the bottom sediment of the spring-fed Ichetucknee River, north-central Florida. The river, which flows over the top of the unconfined karstic Floridan Aquifer, is characterized by a broad bedrock channel partially in-filled with unconsolidated sediments. Radon (222Rn) activity in the pore waters of the channel sediments differs from the amount expected from sediment production and decay. Although most radon in streams originates from sources in bottom sediments, the Ichetucknee River water has 222Rn activities (251×5 PCi/L) that are nearly twice that of the pore water (128×15 PCi/L). The river water 222Rn activity is consistent with that of the source springs, suggesting the source of Rn in the river is from deep within the aquifer rather than bottom sediments and that the excess 222Rn in the pore water results from hyporheic exchange. Profiles of radon concentrations with depth through the sediments show that the mixing of stream water and pore water extends 35-45 cm below the sediment and water interface. Based on a model that integrates the excess radon with depth, we estimate the water exchange rate to be between 1.1 and 1.6 cm/day with an average value of 1.3×0.2 cm/day. Water that exchanges across the sediment-water interface pumps oxygen into the sediments, thereby enhancing organic carbon remineralization, as well as the production of NH4+ and PO43- and their fluxes from sediments to the stream. As opposed to conventional in-stream tracer injection method which estimates exchange between the stream and both the hyporheic zone and the surface transient storage zone, the 222Rn approach measures the water exchange between stream and hyporheic sediments only. Although the present method is tested on a spring-fed karst stream, it has potential for any freshwater system (e.g. wetland, lake) where distinct radon activity and production between surface water and underlying sediments occur.

  19. Freeze core sampling to validate time-lapse resistivity monitoring of the hyporheic zone.

    PubMed

    Toran, Laura; Hughes, Brian; Nyquist, Jonathan; Ryan, Robert

    2013-01-01

    A freeze core sampler was used to characterize hyporheic zone storage during a stream tracer test. The pore water from the frozen core showed tracer lingered in the hyporheic zone after the tracer had returned to background concentration in collocated well samples. These results confirmed evidence of lingering subsurface tracer seen in time-lapse electrical resistivity tomographs. The pore water exhibited brine exclusion (ion concentrations in ice lower than source water) in a sediment matrix, despite the fast freezing time. Although freeze core sampling provided qualitative evidence of lingering tracer, it proved difficult to quantify tracer concentration because the amount of brine exclusion during freezing could not be accurately determined. Nonetheless, the additional evidence for lingering tracer supports using time-lapse resistivity to detect regions of low fluid mobility within the hyporheic zone that can act as chemically reactive zones of importance in stream health. © 2012, The Author(s). GroundWater © 2012, National Ground Water Association.

  20. On the feeding zone of planetesimal formation by the streaming instability

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Chao-Chin; Johansen, Anders, E-mail: ccyang@astro.lu.se, E-mail: anders@astro.lu.se

    2014-09-10

    The streaming instability is a promising mechanism to overcome the barriers in direct dust growth and lead to the formation of planetesimals. Most previous studies of the streaming instability, however, were focused on a local region of a protoplanetary disk with a limited simulation domain such that only one filamentary concentration of solids has been observed. The characteristic separation between filaments is therefore not known. To address this, we conduct the largest-scale simulations of the streaming instability to date, with computational domains up to 1.6 gas scale heights both horizontally and vertically. The large dynamical range allows the effect ofmore » vertical gas stratification to become prominent. We observe more frequent merging and splitting of filaments in simulation boxes of high vertical extent. We find multiple filamentary concentrations of solids with an average separation of about 0.2 local gas scale heights, much higher than the most unstable wavelength from linear stability analysis. This measures the characteristic separation of planetesimal forming events driven by the streaming instability and thus the initial feeding zone of planetesimals.« less

  1. 76 FR 14279 - Safety Zone; Todd Pacific Shipyards Vessel Roll-Out, West Duwamish Waterway, Seattle, WA

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-16

    ... from entering or remaining in the safety zone unless authorized by the Captain of the Port or a... published. In addition, given the dangers involved with a large slow moving dry dock maneuvering close to... with a large slow moving dry dock maneuvering close to the shore, delaying the effective date of this...

  2. Need to Identify Parameters of Concrete in the Weakest Zone of the Industrial Floor

    NASA Astrophysics Data System (ADS)

    Stawiski, Bohdan; Radzik, Łukasz

    2017-10-01

    The ways in which industrial floors are exploited leads to the requirement for the highest strength of their upper zone. Physical phenomena occurring during the compaction and hardening of the concrete cause different strength distributions. In the top zone of industrial floors, the strength is significantly lower (over a dozen MPa) than the strength in the bottom zone (several dozen MPa). Standard tests of control samples do not detect this fact. Processes for the application and finishing of embedded mineral-aggregate hardeners (dry shakes) can be regarded as uncontrolled. The effects of the use of dry shakes are not evaluated. In combination with the phenomenon of bleeding, they often fail by delamination. This paper presents the results of industrial floor testing. The ultrasonic pulse velocity method with dry point contact transducers was used. The results show how upper layer strength was reduced, and how dry shakes application affected the strength of the floor. The strength distribution in hardened concrete, which delaminated from the rest of the floor was presented as well. The extension of compulsory control tests of concrete samples was proposed. In the authors’ opinion, particular attention should be paid to 3 centimetres of the upper layer.

  3. Membrane-Filtered Olive Mill Wastewater: Quality Assessment of the Dried Phenolic-Rich Fraction.

    PubMed

    Sedej, Ivana; Milczarek, Rebecca; Wang, Selina C; Sheng, Runqi; de Jesús Avena-Bustillos, Roberto; Dao, Lan; Takeoka, Gary

    2016-04-01

    A current trend in olive mill wastewater (OMWW) management is to not only decrease environmental pollution but also to extract and utilize valuable by-products. Therefore, the objectives of this study were to explore different techniques for drying a phenolic-rich membrane filtration fraction of OMWW and compare the techniques in terms of the dried product quality and feasibility of the process. The OMWW from 2 (3-phase and 2-phase) California mills was subjected to a 2-step membrane filtration process using a novel vibratory system. The reverse osmosis retentate (RO-R) is a phenolic-rich coproduct stream, and the reverse osmosis permeate is a near-pure water stream that could be recycled into the milling process. Spray-, freeze-, and infrared-drying were applied to obtain solid material from the RO-R. Drying of the RO-R was made possible only with addition of 10% maltodextrin as a carrier. The total soluble phenolics in dried RO-R were in the range 0.15 to 0.58 mg gallic acid equivalents/g of dry weight for 2-phase RO-R, and 1.38 to 2.17 mg gallic acid equivalents/g of dry weight for the 3-phase RO-R. Spray-dried RO-R from 3-phase OMWW showed remarkable antioxidant activity. Protocatechuic acid, tyrosol, vanillic acid, and p-coumaric acid were quantified in all dried RO-R, whereas 3-hydroxytyrosol was found in 3-phase dried RO-R. This combination of separation and drying technologies helps to add value and shelf-stability to an olive oil by-product and increase environmental sustainability of its production. © 2016 Institute of Food Technologists®

  4. Influence of land use on hyporheos in catchment of the Jarama River (central Spain)

    NASA Astrophysics Data System (ADS)

    Iepure, S.; Martínez-Hernández, V.; Herrera, S.; de Bustamante, I.; Rasines, R.

    2012-04-01

    The Water Framework Directive (2000) requires integrated assessment of water bodies based on water resources but also the evaluation of land-use catchment effect on chemical and ecological conditions of aquatic ecosystems. The hyporheic zone (HZ) supporting obligate subterranean species are particularly vulnerable in river ecosystems when environmental stress occurs at surface and require management strategies to protect both the stream catchment and the aquifer that feed the stream channel. The influence of catchment land-use in the Jarama basin (central Spain) on river geomorphology and hyporheic zone granulometry, chemical and biological variables inferred from crustacean community biodiversity (species richness, taxonomic distinctness) and ecology was assessed. The study was conducted in four streams from the Madrid metropolitan area under distinct local land-use and water resource protection: i) a preserved forested natural sites where critical river ecosystem processes were unaltered or less altered by human activities, and ii) different degree of anthropogenic impact sites from agriculture, urban industrial and mining activities. The river bed permeability reduction and the increase of low sediment size input associated with changes in geomorphology of the stream channels are greatly affected by land-use changes in the Jarama watershed. Water chemical parameters linked to land-use increase from the natural stream to the urban industrial and agricultural dominated catchment. Principal coordinate analysis (PCO) and multidimensional scaling (MDS) clearly discriminate the pristine sites from forested areas by those under anthropogenic stressors. In streams draining forested areas, groundwater discharge and regular exchange between groundwater and surface water occur due to relatively high permeability of the sediments. Consequently, forested land-use produce sites of high water quality and crustacean richness (both groundwater dwellers and surface-benthos species), as indicate the expected diversity pattern after the simulation procedure for taxonomic distinctness. Crustacean diversity (Shannon index) was greatest in less extensive agricultural land-use sites where riparian zone is slightly developed, while intensive agricultural activities cause a decline of water quality and therefore of crustacean richness. Intensively urban industrial land-use yield highly contaminated hyporheic water with heavy metals and VOC (i.e. toluene, benzene). Complementarily, the streams geomorphology and low rates of water flow favour the deposition of fine sediments that clog the interstices, generate a reverse dynamic of river channel and induce a reduction of groundwater discharge. In results, the hyporheic is unsuitable for hyporheos that are missing or harbour reduced populations of exclusively surface-water taxa. There are sites of intermediate biodiversity including hypogeans, located in natural regional parks thriving well-established riparian zone and relatively good water quality. The differences among sites in the Jarama basin indicate the impact that changes in land-use have upon the hyporheic ecology as shown the pattern of crustacean community distribution, diversity and ecological structure. We suggest that in rehabilitation processes of streams sectors require the understanding and recognition of the potential roles of the hyporheic zone and its biota in the whole stream ecosystem.

  5. Climate and hydrology of the last interglaciation (MIS 5) in Owens Basin, California: Isotopic and geochemical evidence from core OL-92

    USGS Publications Warehouse

    Li, H.-C.; Bischoff, J.L.; Ku, T.-L.; Zhu, Z.-Y.

    2004-01-01

    ??18O, ??13C, total organic carbon, total inorganic carbon, and acid-leachable Li, Mg and Sr concentrations on 443 samples from 32 to 83 m depth in Owens Lake core OL-92 were analyzed to study the climatic and hydrological conditions between 60 and 155 ka with a resolution of ???200 a. The multi-proxy data show that Owens Lake overflowed during wet/cold conditions of marine isotope stages (MIS) 4, 5b and 6, and was closed during the dry/warm conditions of MIS 5a, c and e. The lake partially overflowed during MIS 5d. Our age model places the MIS 4/5 boundary at ca 72.5 ka and the MIS 5/6 boundary (Termination II) at ca 140 ka, agreeing with the Devils Hole chronology. The diametrical precipitation intensities between the Great Basin (cold/wet) and eastern China (cold/dry) on Milankovitch time scales imply a climatic teleconnection across the Pacific. It also probably reflects the effect of high-latitude ice sheets on the southward shifts of both the summer monsoon frontal zone in eastern Asia and the polar jet stream in western North America during glacial periods. ?? 2003 Elsevier Ltd. All rights reserved.

  6. Sensitivity analysis of conservative and reactive stream transient storage models applied to field data from multiple-reach experiments

    USGS Publications Warehouse

    Gooseff, M.N.; Bencala, K.E.; Scott, D.T.; Runkel, R.L.; McKnight, Diane M.

    2005-01-01

    The transient storage model (TSM) has been widely used in studies of stream solute transport and fate, with an increasing emphasis on reactive solute transport. In this study we perform sensitivity analyses of a conservative TSM and two different reactive solute transport models (RSTM), one that includes first-order decay in the stream and the storage zone, and a second that considers sorption of a reactive solute on streambed sediments. Two previously analyzed data sets are examined with a focus on the reliability of these RSTMs in characterizing stream and storage zone solute reactions. Sensitivities of simulations to parameters within and among reaches, parameter coefficients of variation, and correlation coefficients are computed and analyzed. Our results indicate that (1) simulated values have the greatest sensitivity to parameters within the same reach, (2) simulated values are also sensitive to parameters in reaches immediately upstream and downstream (inter-reach sensitivity), (3) simulated values have decreasing sensitivity to parameters in reaches farther downstream, and (4) in-stream reactive solute data provide adequate data to resolve effective storage zone reaction parameters, given the model formulations. Simulations of reactive solutes are shown to be equally sensitive to transport parameters and effective reaction parameters of the model, evidence of the control of physical transport on reactive solute dynamics. Similar to conservative transport analysis, reactive solute simulations appear to be most sensitive to data collected during the rising and falling limb of the concentration breakthrough curve. ?? 2005 Elsevier Ltd. All rights reserved.

  7. Hydrologic flow paths control dissolved organic carbon fluxes and metabolism in an Alpine stream hyporheic zone

    NASA Astrophysics Data System (ADS)

    Battin, Tom J.

    1999-10-01

    The objective of the present paper was to link reach-scale streambed reactive uptake of dissolved organic carbon (DOC) and dissolved oxygen (DO) to subsurface flow paths in an alpine stream (Oberer Seebach (OSB)). The topography adjacent to the stream channel largely determined flow paths, with shallow hillslope groundwater flowing beneath the stream and entering the alluvial groundwater at the opposite bank. As computed from hydrometric data, OSB consistently lost stream water to groundwater with fluxes out of the stream averaging 943 ± 47 and 664 ± 45 L m-2 h-1 at low (Q < 600 L s-1) and high (Q > 600 L s-1) flow, respectively. Hydrometric segregation of streambed fluxes and physicochemical mixing analysis indicated that stream water was the major input component to the streambed with average contributions of 70-80% to the hyporheic zone (i.e., the subsurface zone where shallow groundwater and stream water mix). Surface water was also the major source of DOC with 0.512 ± 0.043 mg C m-2 h-1 to the streambed. The DOC flux from shallow riparian groundwater was lower (0.309 ± 0.071 mg C m-2 h-1) and peaked in autumn with 1.011 mg C m-2 h-1. I computed the relative proportion of downstream discharge through the streambed as the ratio of the downstream length (Ssw) a stream water parcel travels before entering the streambed to the downstream length (Shyp) a streambed water parcel travels before returning to the stream water. The relative streambed DOC retention efficiency, calculated as (input-output)/input of interstitial DOC, correlated with the proportion (Ssw/Shyp) of downstream discharge (r2 = 0.76, p = 0.006). Also, did the streambed metabolism (calculated as DO uptake from mass balance) decrease with low subsurface downstream routing, whereas elevated downstream discharge through the streambed stimulated DO uptake (r2 = 0.69, p = 0.019)? Despite the very short DOC turnover times (˜0.05 days, calculated as mean standing stock/annual input) within the streambed, the latter constitutes a net sink of DOC (˜14 mg C m-2 h-1). Along with high standing stocks of sediment associated particulate organic carbon, these results suggest microbial biofilms as the major retention and storage site of DOC in an alpine stream where large hydrologic exchange controls DOC fluxes.

  8. Documentation of the Streamflow-Routing (SFR2) Package to Include Unsaturated Flow Beneath Streams - A Modification to SFR1

    USGS Publications Warehouse

    Niswonger, Richard G.; Prudic, David E.

    2005-01-01

    Many streams in the United States, especially those in semiarid regions, have reaches that are hydraulically disconnected from underlying aquifers. Ground-water withdrawals have decreased water levels in valley aquifers beneath streams, increasing the occurrence of disconnected streams and aquifers. The U.S. Geological Survey modular ground-water model (MODFLOW-2000) can be used to model these interactions using the Streamflow-Routing (SFR1) Package. However, the approach does not consider unsaturated flow between streams and aquifers and may not give realistic results in areas with significantly deep unsaturated zones. This documentation describes a method for extending the capabilities of MODFLOW-2000 by incorporating the ability to simulate unsaturated flow beneath streams. A kinematic-wave approximation to Richards' equation was solved by the method of characteristics to simulate unsaturated flow beneath streams in SFR1. This new package, called SFR2, includes all the capabilities of SFR1 and is designed to be used with MODFLOW-2000. Unlike SFR1, seepage loss from the stream may be restricted by the hydraulic conductivity of the unsaturated zone. Unsaturated flow is simulated independently of saturated flow within each model cell corresponding to a stream reach whenever the water table (head in MODFLOW) is below the elevation of the streambed. The relation between unsaturated hydraulic conductivity and water content is defined by the Brooks-Corey function. Unsaturated flow variables specified in SFR2 include saturated and initial water contents; saturated vertical hydraulic conductivity; and the Brooks-Corey exponent. These variables are defined independently for each stream reach. Unsaturated flow in SFR2 was compared to the U.S. Geological Survey's Variably Saturated Two-Dimensional Flow and Transport (VS2DT) Model for two test simulations. For both test simulations, results of the two models were in good agreement with respect to the magnitude and downward progression of a wetting front through an unsaturated column. A third hypothetical simulation is presented that includes interaction between a stream and aquifer separated by an unsaturated zone. This simulation is included to demonstrate the utility of unsaturated flow in SFR2 with MODFLOW-2000. This report includes a description of the data input requirements for simulating unsaturated flow in SFR2.

  9. Restoring hydrological and biogeochemical ecosystem services in streams: how can science inform practice?

    NASA Astrophysics Data System (ADS)

    Lautz, L.; Gordon, R.; Daniluk, T.; Zimmer, M. A.; Endreny, T. A.; McGrath, K.

    2014-12-01

    Society is increasingly recognizing the value of stream ecosystem functions, as evidenced by the enormous economic investment being made in stream restoration across the United States. Stream restoration projects have a variety of goals, including improvement in water quality and in-stream habitat. Popular approaches to restoration (such as Natural Channel Design, or NCD) aim to move degraded streams along a trajectory toward a dynamic ecological endpoint that represents natural conditions. Project designs primarily focus on channel form and function, but stream-groundwater exchanges of water and solutes are not typically a design consideration, although a primary component of fully functioning stream ecosystems. Here, we synthesize results from field investigations of the impact of NCD stream restoration on stream-groundwater exchanges by (1) comparing restored sites to reference reaches, which serve as the basis for the restoration design, (2) characterizing multiple restored sites to determine universal characteristics of streams restored by NCD, and (3) monitoring a stream pre- and post- restoration. NCD restoration creates hot spots of rapid hyporheic exchange upstream of channel spanning structures, with water fluxes across the bed interface up to an order of magnitude higher than at pre-restoration or reference reaches. Elevated flux rates result in short hyporheic residence times, which are not sufficiently long to generate net changes in nutrient concentrations. Hot spots of biogeochemical transformations are instead located around secondary bedforms, such as pool-riffle sequences, where gross water exchange rates are more moderate. Reference reaches show greater evidence of groundwater discharge to the hyporheic zone relative to restored reaches, although observations before and after restoration suggest NCD can modify the spatial extent of groundwater discharge zones. Gross water exchange across the streambed interface along restored reaches is a small percentage of stream discharge, suggesting the primary impact of restoration on stream-groundwater exchange is promoting biochemical heterogeneity in the subsurface, rather than longitudinal net changes in stream solute concentrations. Results inform future design to achieve restoration goals.

  10. Modeled streamflow metrics on small, ungaged stream reaches in the Upper Colorado River Basin

    USGS Publications Warehouse

    Reynolds, Lindsay V.; Shafroth, Patrick B.

    2016-01-20

    Modeling streamflow is an important approach for understanding landscape-scale drivers of flow and estimating flows where there are no streamgage records. In this study conducted by the U.S. Geological Survey in cooperation with Colorado State University, the objectives were to model streamflow metrics on small, ungaged streams in the Upper Colorado River Basin and identify streams that are potentially threatened with becoming intermittent under drier climate conditions. The Upper Colorado River Basin is a region that is critical for water resources and also projected to experience large future climate shifts toward a drying climate. A random forest modeling approach was used to model the relationship between streamflow metrics and environmental variables. Flow metrics were then projected to ungaged reaches in the Upper Colorado River Basin using environmental variables for each stream, represented as raster cells, in the basin. Last, the projected random forest models of minimum flow coefficient of variation and specific mean daily flow were used to highlight streams that had greater than 61.84 percent minimum flow coefficient of variation and less than 0.096 specific mean daily flow and suggested that these streams will be most threatened to shift to intermittent flow regimes under drier climate conditions. Map projection products can help scientists, land managers, and policymakers understand current hydrology in the Upper Colorado River Basin and make informed decisions regarding water resources. With knowledge of which streams are likely to undergo significant drying in the future, managers and scientists can plan for stream-dependent ecosystems and human water users.

  11. Wet and Dry Atmospheric Depositions of Inorganic Nitrogen during Plant Growing Season in the Coastal Zone of Yellow River Delta

    PubMed Central

    Li, Yunzhao; Du, Siyao; Han, Guangxuan; Xing, Qinghui; Wu, Huifeng; Wang, Guangmei

    2014-01-01

    The ecological problems caused by dry and wet deposition of atmospheric nitrogen have been widespread concern in the world. In this study, wet and dry atmospheric depositions were monitored in plant growing season in the coastal zone of the Yellow River Delta (YRD) using automatic sampling equipment. The results showed that SO4 2− and Na+ were the predominant anion and cation, respectively, in both wet and dry atmospheric depositions. The total atmospheric nitrogen deposition was ~2264.24 mg m−2, in which dry atmospheric nitrogen deposition was about 32.02%. The highest values of dry and wet atmospheric nitrogen deposition appeared in May and August, respectively. In the studied area, NO3 −–N was the main nitrogen form in dry deposition, while the predominant nitrogen in wet atmospheric deposition was NH4 +–N with ~56.51% of total wet atmospheric nitrogen deposition. The average monthly attribution rate of atmospheric deposition of NO3 −–N and NH4 +–N was ~31.38% and ~20.50% for the contents of NO3 −–N and NH4 +–N in 0–10 cm soil layer, respectively, suggested that the atmospheric nitrogen was one of main sources for soil nitrogen in coastal zone of the YRD. PMID:24977238

  12. Effect of morphology and discharge on hyporheic exchange flows in two small streams in the Cascade Mountains of Oregon, USA.

    Treesearch

    Steven M. Wondzell

    2006-01-01

    Stream-tracer injections were used to examine the effect of channel morphology and changing stream discharge on hyporheic exchange flows. Direct observations were made from well networks to follow tracer movement through the hyporheic zone. The reach-integrated influence of hyporheic exchange was evaluated using the transient storage model (TSM) OTIS-P. Transient...

  13. Strong seepage of shallow groundwater shifts the timing of the annual thermal signals in stream water

    NASA Astrophysics Data System (ADS)

    Briggs, M. A.; Johnson, Z. C.; Snyder, C.; Hitt, N. P.; White, E. A.; Lane, J. W., Jr.; Nelms, D. L.

    2016-12-01

    Conventional wisdom indicates that while short-term (e.g. diurnal) thermal variance in streams may be attenuated by groundwater seepage, annual temperature swings will essentially track the local air temperature signal. However, the temperature of shallow (less than 5 m depth) groundwater from seepage zones may not be constant and near the local mean air temperature, but instead will fluctuate seasonally, and show a pronounced phase lag from the annual air signal. The degree of phase lag will be dependent on the rate of vertical fluid and heat exchange through shallow aquifer sediments. Gaining headwater streams might be expected to adopt similar phase lags to local seepage zones. We explore these dynamics through 9 mountain watersheds in Shenandoah National Park, VA, USA that harbor critical habitat for cold-water brook trout (Salvelinus fontinalis). Daily paired air and stream water temperature records were collected for up to 5 years at several stream locations along each watershed. Sinusoids fit to multiple-year data from more than 100 total locations indicate an average phase shift from air to surface water of approximately 10 d; this may primarily be due to strong conductive exchange with the rocky alluvial aquifer in generally incised and shaded channels. A subset of these transects (n=4) showed phase-lags greater than 20 d, coinciding with locations of particularly pronounced diurnal variance attenuation, indicating strong groundwater influence. Shallow bedrock, evaluated throughout the watersheds with passive seismic methods, restricts downward infiltration of precipitation in the mountain bedrock aquifers. Numerical 1D vertical aquifer models indicate similar phase lags in shallow groundwater at the bedrock contact to that observed in stream seepage zones. Therefore, contrary to conventional wisdom, shaded mountain streams with strong groundwater influence may adopt the annual thermal signature of the adjacent aquifer, shifting the stream thermal maxima timing from that predicted by air temperature. This research illustrates the utility of long-term paired air/stream thermal records, which further refine the evaluation of apparent groundwater influence to aquatic habitat.

  14. New streams and springs after the 2014 Mw6.0 South Napa earthquake.

    PubMed

    Wang, Chi-Yuen; Manga, Michael

    2015-07-09

    Many streams and springs, which were dry or nearly dry before the 2014 Mw6.0 South Napa earthquake, started to flow after the earthquake. A United States Geological Survey stream gauge also registered a coseismic increase in discharge. Public interest was heightened by a state of extreme drought in California. Since the new flows were not contaminated by pre-existing surface water, their composition allowed unambiguous identification of their origin. Following the earthquake we repeatedly surveyed the new flows, collecting data to test hypotheses about their origin. We show that the new flows originated from groundwater in nearby mountains released by the earthquake. The estimated total amount of new water is ∼ 10(6) m(3), about 1/40 of the annual water use in the Napa-Sonoma area. Our model also makes a testable prediction of a post-seismic decrease of seismic velocity in the shallow crust of the affected region.

  15. Assessing effects of water abstraction on fish assemblages in Mediterranean streams

    USGS Publications Warehouse

    Benejam, Lluis; Angermeier, Paul L.; Munne, Antoni; García-Berthou, Emili

    2010-01-01

    1. Water abstraction strongly affects streams in arid and semiarid ecosystems, particularly where there is a Mediterranean climate. Excessive abstraction reduces the availability of water for human uses downstream and impairs the capacity of streams to support native biota. 2. We investigated the flow regime and related variables in six river basins of the Iberian Peninsula and show that they have been strongly altered, with declining flows (autoregressive models) and groundwater levels during the 20th century. These streams had lower flows and more frequent droughts than predicted by the official hydrological model used in this region. Three of these rivers were sometimes dry, whereas there were predicted by the model to be permanently flowing. Meanwhile, there has been no decrease in annual precipitation. 3. We also investigated the fish assemblage of a stream in one of these river basins (Tordera) for 6 years and show that sites more affected by water abstraction display significant differences in four fish metrics (catch per unit effort, number of benthic species, number of intolerant species and proportional abundance of intolerant individuals) commonly used to assess the biotic condition of streams. 4. We discuss the utility of these metrics in assessing impacts of water abstraction and point out the need for detailed characterisation of the natural flow regime (and hence drought events) prior to the application of biotic indices in streams severely affected by water abstraction. In particular, in cases of artificially dry streams, it is more appropriate for regulatory agencies to assign index scores that reflect biotic degradation than to assign ‘missing’ scores, as is presently customary in assessments of Iberian streams.

  16. Modifying WEPP to improve streamflow simulation in a Pacific Northwest watershed

    Treesearch

    A. Srivastava; M. Dobre; J. Q. Wu; W. J. Elliot; E. A. Bruner; S. Dun; E. S. Brooks; I. S. Miller

    2013-01-01

    The assessment of water yield from hillslopes into streams is critical in managing water supply and aquatic habitat. Streamflow is typically composed of surface runoff, subsurface lateral flow, and groundwater baseflow; baseflow sustains the stream during the dry season. The Water Erosion Prediction Project (WEPP) model simulates surface runoff, subsurface lateral flow...

  17. THE ECOLOGICAL AND HYDROLOGICAL SIGNIFICANCE OF EPHEMERAL AND INTERMITTENT STREAMS IN THE ARID AND SEMI-ARID AMERICAN SOUTHWEST

    EPA Science Inventory

    This report represents a state-of-the-art synthesis of current knowledge of the ecology and hydrology of ephemeral (dry washes) and intermittent streams in the American Southwest, and may have important bearing on establishing nexus to traditional navigable waters (TNW) and defin...

  18. A field comparison of multiple techniques to quantify groundwater - surface-water interactions

    USGS Publications Warehouse

    González-Pinzón, Ricardo; Ward, Adam S; Hatch, Christine E; Wlostowski, Adam N; Singha, Kamini; Gooseff, Michael N.; Haggerty, Roy; Harvey, Judson; Cirpka, Olaf A; Brock, James T

    2015-01-01

    Groundwater–surface-water (GW-SW) interactions in streams are difficult to quantify because of heterogeneity in hydraulic and reactive processes across a range of spatial and temporal scales. The challenge of quantifying these interactions has led to the development of several techniques, from centimeter-scale probes to whole-system tracers, including chemical, thermal, and electrical methods. We co-applied conservative and smart reactive solute-tracer tests, measurement of hydraulic heads, distributed temperature sensing, vertical profiles of solute tracer and temperature in the stream bed, and electrical resistivity imaging in a 450-m reach of a 3rd-order stream. GW-SW interactions were not spatially expansive, but were high in flux through a shallow hyporheic zone surrounding the reach. NaCl and resazurin tracers suggested different surface–subsurface exchange patterns in the upper ⅔ and lower ⅓ of the reach. Subsurface sampling of tracers and vertical thermal profiles quantified relatively high fluxes through a 10- to 20-cm deep hyporheic zone with chemical reactivity of the resazurin tracer indicated at 3-, 6-, and 9-cm sampling depths. Monitoring of hydraulic gradients along transects with MINIPOINT streambed samplers starting ∼40 m from the stream indicated that groundwater discharge prevented development of a larger hyporheic zone, which progressively decreased from the stream thalweg toward the banks. Distributed temperature sensing did not detect extensive inflow of ground water to the stream, and electrical resistivity imaging showed limited large-scale hyporheic exchange. We recommend choosing technique(s) based on: 1) clear definition of the questions to be addressed (physical, biological, or chemical processes), 2) explicit identification of the spatial and temporal scales to be covered and those required to provide an appropriate context for interpretation, and 3) maximizing generation of mechanistic understanding and reducing costs of implementing multiple techniques through collaborative research.

  19. Zone heating for fluidized bed silane pyrolysis

    NASA Technical Reports Server (NTRS)

    Iya, Sridhar K. (Inventor)

    1987-01-01

    An improved heated fluidized bed reactor and method for the production of high purity polycrystalline silicon by silane pyrolysis wherein silicon seed particles are heated in an upper heating zone of the reactor and admixed with particles in a lower reaction zone, in which zone a silane-containing gas stream, having passed through a lower cooled gas distribution zone not conducive to silane pyrolysis, contacts the heated seed particles whereon the silane is heterogeneously reduced to silicon.

  20. Pneumatic conveyance apparatus and process

    DOEpatents

    Heckendorn, Frank M.; Matzolf, Athneal D.; Hera, Kevin R.

    2010-05-04

    A pneumatic nozzle capable of removing dry solid debris, liquids, and mixtures of solid and liquid waste is provided. The pneumatic nozzle uses a pressurized gas stream to push materials through the nozzle. The force of a pressurized gas stream provides a partial vacuum to allow material to be introduced into an opening of a nozzle via a slight suction force. Thereafter, individual particles and materials introduced into the pneumatic nozzle are pushed by a stream of pressurized gas through the nozzle.

  1. Influence of Didymosphenia geminata blooms on prey composition and associated diet and growth of Brown Trout

    USGS Publications Warehouse

    James, Daniel A.; Chipps, Steven R.

    2016-01-01

    We compared diet, stomach fullness, condition, and growth of Brown Trout Salmo trutta among streams with or without blooms of the benthic diatom Didymosphenia geminata in the Black Hills, South Dakota. In Rapid Creek, where D. geminata blooms covered ∼30% of the stream bottom, Brown Trout consumed fewer ephemeropterans (6–8% by weight) than individuals from two stream sections that have not had D. geminatablooms (Castle and Spearfish creeks; 13–39% by weight). In contrast, dipterans (primarily Chironomidae) represented a larger percentage of Brown Trout diets from Rapid Creek (D. geminata blooms present; 16–28% dry weight) compared with diets of trout from streams without D. geminata blooms (6–19% dry weight). Diets of small Brown Trout (100–199 mm TL) reflected the invertebrate species composition in benthic stream samples; in Rapid Creek, ephemeropterans were less abundant whereas dipterans were more abundant than in streams without D. geminata blooms. Stomach fullness and condition of Brown Trout from Rapid Creek were generally greater than those of Brown Trout from other populations. Linkages among invertebrate availability, diet composition, and condition of Brown Trout support the hypothesis that changes in invertebrate assemblages associated with D. geminata (i.e., more Chironomidae) could be contributing to high recruitment success for small Brown Trout in Rapid Creek.

  2. Does tree harvesting in riparian areas increase stream sedimentation and turbidity - world-wide experience relative to Australia.

    NASA Astrophysics Data System (ADS)

    Neary, D.; Smethurst, P.; Petrone, K.

    2009-04-01

    A typical improved-pasture property in the high-rainfall zone of Australia contains 0.5-2.0 km of waterways per 100 ha. Nationwide, some 25-30 million ha of improved pasture contains about 100,000 km of streams, of which about 75% are currently un-buffered and contributing to soil and water degradation. Farmers and natural resource managers are considering ways to enhance environmental outcomes at farm and catchment scales using stream-side buffers of trees and other perennial vegetation. Benefits of buffers include improved water quality, biodiversity, carbon sequestration and aesthetics. Lack of sound information and funding for establishing and managing buffer zones is hindering wide-scale adoption of this practice. Stream-side areas of farms are generally highly productive (wet and nutrient-rich) and contain a high biodiversity, but they are also high-risk zones for soil and water values and stock safety. Development of options based on a balance between environmental and economic outcomes would potentially promote wider adoption. Australian codes of forest practice currently discourage or prevent harvesting of trees in streamside buffers. These codes were developed exclusively for large-scale native forests and industrial-scale plantations, and were applicable to farm forestry as now required. In countries including USA and Germany trees in stream-side buffers are harvested using Best Management Practices. Trees may grow at a faster rate in riparian zones and provide a commercial return, but the impacts of tree establishment and harvesting on water yield and quality must be evaluated. However, there have been few designed experiments investigating this problem. Australia has recently initiated studies to explore the use of high-value timber species and associated vegetation in riparian zones to improve water quality, particularly suspended sediment. Preliminary information from the Yan Yan Gurt Catchment in Victoria indicate that forested riparian strips can retain 98% of the sediment entrained in runoff from agricultural sections of the catchment. This paper examines the science background from North American and European experiences relative to Australia, with particular emphasis on sediment relationships after tree harvesting using Best Management Practices.

  3. Anthropogenic Mercury Accumulation in Watersheds of the Northern Appalachian Mountains

    NASA Astrophysics Data System (ADS)

    Boyer, E. W.; Drohan, P. J.; Lawler, D.; Grimm, J.; Grant, C.; Eklof, K. J.; Bennett, J.; Naber, M. D.

    2014-12-01

    Atmospheric deposition of mercury (Hg) is a critical environmental stress that affects ecosystems and human health. Mercury emissions to the atmosphere from coal-fired power plants and other sources such as waste incineration can be deposited over large geographic areas to downwind landscapes in precipitation and in dry fallout. The northern Appalachian Mountains are downwind of major atmospheric mercury emissions sources. Some mercury reaches watersheds and streams, where it can accumulate in sediments and biota. Human exposure to mercury occurs primarily through fish consumption, and currently mercury fish eating advisories are in place for many of the streams and lakes in the region. Here, we explored mercury accumulation in forested landscapes - in air, soils, water, and biota. To quantify atmospheric mercury deposition, we measured both wet and dry mercury deposition at 10 forested locations, from which we present variation in mercury deposition and initial assessments of factors affecting the patterns. To quantify mercury accumulation in terrestrial environments, we measured soil mercury concentrations within and surrounding 12 vernal pools spanning various physiographic settings in the region. Given that vernal pools have large inputs of water via precipitation yet do not have any stream discharge outflow, they are likely spots within the forested landscape to accumulate pollutants that enter via wet atmospheric deposition. To quantify mercury accumulation in aquatic environments, we sampled mercury concentrations in streams draining 35 forested watersheds, spanning gradients of atmospheric deposition, climate and geology. Mercury concentrations were measured in stream water under base-flow conditions, in streambed sediments, aquatic mosses, and in fish tissues from brook trout. Results indicate that wet and dry atmospheric deposition is a primary source of mercury that is accumulating in watersheds of the Northern Appalachian Mountains.

  4. Effects of land use and seasonality on stream water quality in a small tropical catchment: The headwater of Córrego Água Limpa, São Paulo (Brazil).

    PubMed

    Rodrigues, Valdemir; Estrany, Joan; Ranzini, Mauricio; de Cicco, Valdir; Martín-Benito, José Mª Tarjuelo; Hedo, Javier; Lucas-Borja, Manuel E

    2018-05-01

    Stream water quality is controlled by the interaction of natural and anthropogenic factors over a range of temporal and spatial scales. Among these anthropogenic factors, land cover changes at catchment scale can affect stream water quality. This work aims to evaluate the influence of land use and seasonality on stream water quality in a representative tropical headwater catchment named as Córrego Água Limpa (Sao Paulo, Brasil), which is highly influenced by intensive agricultural activities and urban areas. Two systematic sampling approach campaigns were implemented with six sampling points along the stream of the headwater catchment to evaluate water quality during the rainy and dry seasons. Three replicates were collected at each sampling point in 2011. Electrical conductivity, nitrates, nitrites, sodium superoxide, Chemical Oxygen Demand (DQO), colour, turbidity, suspended solids, soluble solids and total solids were measured. Water quality parameters differed among sampling points, being lower at the headwater sampling point (0m above sea level), and then progressively higher until the last downstream sampling point (2500m above sea level). For the dry season, the mean discharge was 39.5ls -1 (from April to September) whereas 113.0ls -1 were averaged during the rainy season (from October to March). In addition, significant temporal and spatial differences were observed (P<0.05) for the fourteen parameters during the rainy and dry period. The study enhance significant relationships among land use and water quality and its temporal effect, showing seasonal differences between the land use and water quality connection, highlighting the importance of multiple spatial and temporal scales for understanding the impacts of human activities on catchment ecosystem services. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. DRI Technical Program: Emerging Dynamics of the Marginal Ice Zone Ice, Ocean and Atmosphere Interactions in the Arctic Marginal Ice Zone. Year 3 Annual Report

    DTIC Science & Technology

    2014-09-30

    Institution The Scottish Association for Marine Science tmaksym@whoi.edu Phil.Hwang@sams.ac.uk LONG-TERM GOALS This DRI TECHNICAL PROGRAM (Emerging...jpw28@bas.ac.uk tmaksym@whoi.edu Co-PRINCIPAL INVESTIGATOR: Byongjun (Phil) Hwang The Scottish Association for Marine Science Phil.Hwang@sams.ac.uk 2

  6. Long-Term Outcomes in Patients with Neovascular Age-Related Macular Degeneration Who Maintain Dry Macula after Three Monthly Ranibizumab Injections.

    PubMed

    Kim, Kyung Min; Kim, Jae Hui; Chang, Young Suk; Kim, Jong Woo; Kim, Chul Gu

    2018-01-01

    To evaluate long-term changes in visual acuity and retinal microstructure in patients with neovascular age-related macular degeneration (AMD) who had maintained dry macula after initial treatment. This retrospective observational study included 55 eyes that were diagnosed with neovascular AMD, were treated with three monthly ranibizumab injections, and maintained dry macula during a two-year follow-up. Best-corrected visual acuity (BCVA) at three months and at the final follow-up were compared, and the degree of visual improvement was compared between eyes with and without improvement of the ellipsoid zone. In addition, the incidence of improvement of the ellipsoid zone was compared between eyes with different extents of disruption. The mean follow-up period was 30.3 ± 4.1 months. BCVA at three months and at the final follow-up was 0.51 ± 0.46 and 0.45 ± 0.49 (P<0.001). Among 35 eyes that exhibited >200 μm of disruption of the ellipsoid zone, 15 (42.9%) showed improvement of the ellipsoid zone, and the improvement in BCVA was greater in these eyes than that in the remaining 20 eyes (P=0.021). A higher incidence of improvement of the ellipsoid zone was noted in eyes with 200 to 800 μm of disruption than in eyes with >800 μm of disruption (P<0.001). Long-term improvement in visual acuity was noted in eyes that had maintained dry macula after three ranibizumab injections. The status of the ellipsoid zone at three months was closely associated with visual improvement.

  7. An overview of dry-wet climate variability among monsoon-westerly regions and the monsoon northernmost marginal active zone in China

    NASA Astrophysics Data System (ADS)

    Qian, Weihong; Ding, Ting; Hu, Haoran; Lin, Xiang; Qin, Aimin

    2009-07-01

    Climate in mainland China can be divided into the monsoon region in the southeast and the westerly region in the northwest as well as the intercross zone, i.e., the monsoon northernmost marginal active zone that is oriented from Southwest China to the upper Yellow River, North China, and Northeast China. In the three regions, dry-wet climate changes are directly linked to the interaction of the southerly monsoon flow on the east side of the Tibetan Plateau and the westerly flow on the north side of the Plateau from the inter-annual to inter-decadal timescales. Some basic features of climate variability in the three regions for the last half century and the historical hundreds of years are reviewed in this paper. In the last half century, an increasing trend of summer precipitation associated with the enhancing westerly flow is found in the westerly region from Xinjiang to northern parts of North China and Northeast China. On the other hand, an increasing trend of summer precipitation along the Yangtze River and a decreasing trend of summer precipitation along the monsoon northernmost marginal active zone are associated with the weakening monsoon flow in East Asia. Historical documents are widely distributed in the monsoon region for hundreds of years and natural climate proxies are constructed in the non-monsoon region, while two types of climate proxies can be commonly found over the monsoon northernmost marginal active zone. In the monsoon region, dry-wet variation centers are altered among North China, the lower Yangtze River, and South China from one century to another. Dry or wet anomalies are firstly observed along the monsoon northernmost marginal active zone and shifted southward or southeastward to the Yangtze River valley and South China in about a 70-year timescale. Severe drought events are experienced along the monsoon northernmost marginal active zone during the last 5 centuries. Inter-decadal dry-wet variations are depicted by natural proxies for the last 4-5 centuries in several areas over the non-monsoon region. Some questions, such as the impact of global warming on dry-wet regime changes in China, complex interactions between the monsoon and westerly flows in Northeast China, and the integrated multi-proxy analysis throughout all of China, are proposed.

  8. Agricultural Intensification in the Amazon: Tracking Nitrogen Fertilizer from Soy-Maize Double Cropping to Streams

    NASA Astrophysics Data System (ADS)

    Cabrera, V. D.; Jankowski, K.; Neill, C.; Macedo, M.; Deegan, L.; Brando, P. M.; Nascimento, S.; Nascimento, E.; Rocha, S.; Coe, M. T.; Nunes, D.

    2015-12-01

    Globalization and the increasing demand for food create pressure to both expand and intensify agriculture. These changes have potentially large consequences for the solute concentrations and functioning of streams. In the Brazilian Amazon, crop agriculture expanded greatly during the last 20 years. More recently, farmers have intensified production on existing cropland by double cropping of soy and maize during the same year. Maize, a novel crop for the region, requires much higher applications of nitrogen (N) fertilizer than soybeans. To determine whether this novel land use and associated N addition influenced N concentrations in groundwater and stream water, we measured N concentrations in groundwater wells and streams from small headwater watersheds across three land uses (soy-maize, soy, and tropical forest) in the Upper Xingu Basin, a region of rapid cropland intensification in the southern Amazon. Each watershed contained six groundwater wells arranged in a transect reaching cropland field edge on either side of the stream. Total inorganic N concentrations were higher in wells adjacent to fields where double cropping occurred, while stream concentrations did not differ overall among land uses. This suggests the riparian zones are critical in the removal of N, but as the intensification of agriculture continues the ability of the riparian zone to prevent N from traveling to streams is unknown. Their protection is critical to the functioning of tropical watersheds.

  9. Do Riparian Buffers Protect Stream Invertebrate Communities in South American Atlantic Forest Agricultural Areas?

    PubMed

    Hunt, L; Marrochi, N; Bonetto, C; Liess, M; Buss, D F; Vieira da Silva, C; Chiu, M-C; Resh, V H

    2017-12-01

    We investigated the influence and relative importance of insecticides and other agricultural stressors in determining variability in invertebrate communities in small streams in intensive soy-production regions of Brazil and Paraguay. In Paraguay we sampled 17 sites on tributaries of the Pirapó River in the state of Itapúa and in Brazil we sampled 18 sites on tributaries of the San Francisco River in the state of Paraná. The riparian buffer zones generally contained native Atlantic forest remnants and/or introduced tree species at various stages of growth. In Brazil the stream buffer width was negatively correlated with sediment insecticide concentrations and buffer width was found to have moderate importance in mitigating effects on some sensitive taxa such as mayflies. However, in both regions insecticides had low relative importance in explaining variability in invertebrate communities, while various habitat parameters were more important. In Brazil, the percent coverage of soft depositional sediment in streams was the most important agriculture-related explanatory variable, and the overall stream-habitat score was the most important variable in Paraguay streams. Paraguay and Brazil both have laws requiring forested riparian buffers. The ample forested riparian buffer zones typical of streams in these regions are likely to have mitigated the effects of pesticides on stream invertebrate communities. This study provides evidence that riparian buffer regulations in the Atlantic Forest region are protecting stream ecosystems from pesticides and other agricultural stressors. Further studies are needed to determine the minimum buffer widths necessary to achieve optimal protection.

  10. Product-to-parent reversion processes: Stream-hyporheic spiraling increases ecosystem exposure and environmental persistence

    NASA Astrophysics Data System (ADS)

    Ward, A. S.; Cwiertny, D. M.; Kolodziej, E. P.

    2014-12-01

    The product-to-parent reversion of metabolites of trenbolone acetate (TBA), a steroidal growth promoter used widely in beef cattle production, was recently observed to occur in environmental waters. The rapid forward reaction is by direct photolysis (i.e., photohydration), with the much slower reversion reaction occurring via dehydration in the dark. The objective of this study is to quantify the potential effect of this newly discovered reversible process on TBA metabolite concentrations and total bioactivity exposure in fluvial systems. Here, we demonstrate increased persistence of TBA metabolites in the stream and hyporheic zone due to the reversion process, increasing chronic and acute exposure to these endocrine-active compounds along a stream. The perpetually dark hyporheic zone is a key location for reversion in the system, ultimately providing a source of the parent compound to the stream and increasing mean in-stream concentration of 17α-trenbolone (17α-TBOH) by 40% of the input concentration under representative fluvial conditions. As such, regulatory frameworks for compounds undergoing product-to-parent reversion will require new approaches for assessing total exposure to bioactive compounds. Further, we demonstrate generalized cases for prediction of exposure for species with product-to-parent reversion in stream-hyporheic systems.

  11. Hydrogeology and groundwater availability in Clarke County, Virginia

    USGS Publications Warehouse

    Nelms, David L.; Moberg, Roger M.

    2010-01-01

    The prolonged drought between 1999 and 2002 drew attention in Clarke County, Virginia, to the quantity and sustainability of its groundwater resources. The groundwater flow systems of the county are complex and are controlled by the extremely folded and faulted geology that underlies the county. A study was conducted between October 2002 and October 2008 by the U.S. Geological Survey, in cooperation with Clarke County, Virginia, to describe the hydrogeology and groundwater availability in the county and to establish a long-term water monitoring network. The study area encompasses approximately 177 square miles and includes the carbonate and siliciclastic rocks of the Great Valley section of the Valley and Ridge Physiographic Province and the metamorphic rocks of the Blue Ridge Physiographic Province (Blue Ridge). High-yielding wells generally tend to cluster along faults, within lineament zones, and in areas of tight folding throughout the county. Water-bearing zones are generally within 250 feet (ft) of land surface; however, median depths are slightly deeper for the hydrogeologic units of the Blue Ridge than for those of the Great Valley section of the county. Total water-level fluctuations between October 2002 and October 2008 ranged from 2.86 to 87.84 ft across the study area, with an average of 24.15 ft. Generally, water-level fluctuations were greatest near hydrologic divides, in isolated elevated areas, and in the Opequon Creek Basin. Seasonally, water-level highs occur in the early spring at the end of the major groundwater recharge period and lows occur in late autumn when evapotranspiration rates begin to decrease. An overall downward trend in water levels between 2003 and 2008, which closely follows a downward trend in annual precipitation over the same period, was observed in a majority of wells in the Great Valley and in some of the wells in the Blue Ridge. Water-level fluctuations in the Blue Ridge tend to follow current meteorological conditions, and seasonal highs and lows tend to shift in response to the current conditions. Springs generally are present along faults and fold axes, and discharges for the study period ranged from dry to 10 cubic feet per second. A similar downward trend in discharges correlates with the trend in water levels and is indicative of an aquifer system that, over time, drains to a base level controlled by springs and streams. Point discharge from springs can occur as the start of flows of streams and creeks, along banks, and as discrete discharge through streambeds in the Great Valley. For the most part, streams, creeks, and rivers in the Great Valley function as aqueducts. Springs in the Blue Ridge have relatively low discharge rates, have small drainage areas, and are susceptible to current meteorological conditions. Estimates of effective groundwater recharge from 2001 to 2007 ranged from 6.4 to 23.0 inches per year (in/yr) in the Dry Marsh Run and Spout Run Basins with averages of 11.6 and 11.9 in/yr, respectively. Base flow accounted for between 80 and 97 percent of mean streamflow and averaged about 90 percent in these basins. The high base-flow index values (percent of streamflow from base flow) in the Dry Marsh Run and Spout Run Basins indicate that groundwater is the dominant source of streamflow during both wet and drought conditions. Between 46 and 82 percent of the precipitation that fell on the Dry Marsh Run and Spout Run Basins from 2001 to 2007 was removed by evapotranspiration, and an average of approximately 30 percent of the precipitation reached the water table as effective recharge. The high permeability of the rocks and low relief in these basins are not conducive for runoff; therefore, on average, only about 3 to 4 percent of the precipitation becomes runoff. Groundwater flow systems in the county are extremely vulnerable to current climatic conditions. Successive years of below-average effective recharge cause declines in water levels, spring discha

  12. Instream Large Wood: Dentrification Hotspots With Low N2O Production

    EPA Science Inventory

    The maintenance and restoration of forested riparian cover is important for watershed nitrogen (N) cycling. Forested riparian zones provide woody debris to streams that may stimulate in-stream denitrification and nitrous oxide (N2O) production. We examined the effects of woody an...

  13. Biodiversity management approaches for stream-riparian areas: perspectives for Pacific Northwest headwater forests, microclimates, and amphibians.

    Treesearch

    D.H. Olson; P.D. Anderson; C.A. Frissell; H.H. Welsh; D.F. Bradford

    2007-01-01

    New science insights are redefining stream riparian zones, particularly relative to headwaters, microclimate conditions, and fauna such as amphibians. We synthesize data on these topics, and propose management approaches to target sensitive biota at reach to landscape scales.

  14. Woody Debris: Denitrification Hotspots and N2O Production in Fluvial Systems

    EPA Science Inventory

    The maintenance and restoration of forested riparian cover is important for watershed nitrogen (N) cycling. Forested riparian zones provide woody debris to streams that may stimulate in-stream denitrification and control nitrous oxide (N2O) production. We examined the effects of ...

  15. Influence of multi-scale hydrologic controls on river network connectivity and riparian function

    EPA Science Inventory

    The ecological functions of rivers and streams and their associated riparian zones are strongly influenced by surface and subsurface hydrologic routing of water within river basins and river networks. Hydrologic attributes of the riparian area for a given stream reach are typica...

  16. Natural and artificial radionuclides in the Suez Canal bottom sediments and stream water

    NASA Astrophysics Data System (ADS)

    El-Tahawy, M. S.; Farouk, M. A.; Ibrahiem, N. M.; El-Mongey, S. A. M.

    1994-07-01

    Concentration of natural and artificial radionuclides in Suez Canal bottom sediments and stream water have been measured using γ spectrometers based on a hyper-pure Ge detector. The activity concentrations of 238U series, 232Th series and 40K did not exceed 16.0, 15.5 and 500.0 Bq kg-1 dry weight for sediments. The activity concentration of 238U series and 40K did not exceed 0.6 and 18.0 Bq 1-1 for stream water.

  17. Drum bubbler tritium processing system

    DOEpatents

    Rule, Keith; Gettelfinger, Geoff; Kivler, Paul

    1999-01-01

    A method of separating tritium oxide from a gas stream containing tritium oxide. The gas stream containing tritium oxide is fed into a container of water having a head space above the water. Bubbling the gas stream containing tritium oxide through the container of water and removing gas from the container head space above the water. Thereafter, the gas from the head space is dried to remove water vapor from the gas, and the water vapor is recycled to the container of water.

  18. Assessing the chemical contamination dynamics in a mixed land use stream system.

    PubMed

    Sonne, Anne Th; McKnight, Ursula S; Rønde, Vinni; Bjerg, Poul L

    2017-11-15

    Traditionally, the monitoring of streams for chemical and ecological status has been limited to surface water concentrations, where the dominant focus has been on general water quality and the risk for eutrophication. Mixed land use stream systems, comprising urban areas and agricultural production, are challenging to assess with multiple chemical stressors impacting stream corridors. New approaches are urgently needed for identifying relevant sources, pathways and potential impacts for implementation of suitable source management and remedial measures. We developed a method for risk assessing chemical stressors in these systems and applied the approach to a 16-km groundwater-fed stream corridor (Grindsted, Denmark). Three methods were combined: (i) in-stream contaminant mass discharge for source quantification, (ii) Toxic Units and (iii) environmental standards. An evaluation of the chemical quality of all three stream compartments - stream water, hyporheic zone, streambed sediment - made it possible to link chemical stressors to their respective sources and obtain new knowledge about source composition and origin. Moreover, toxic unit estimation and comparison to environmental standards revealed the stream water quality was substantially impaired by both geogenic and diffuse anthropogenic sources of metals along the entire corridor, while the streambed was less impacted. Quantification of the contaminant mass discharge originating from a former pharmaceutical factory revealed that several 100 kgs of chlorinated ethenes and pharmaceutical compounds discharge into the stream every year. The strongly reduced redox conditions in the plume result in high concentrations of dissolved iron and additionally release arsenic, generating the complex contaminant mixture found in the narrow discharge zone. The fingerprint of the plume was observed in the stream several km downgradient, while nutrients, inorganics and pesticides played a minor role for the stream health. The results emphasize that future investigations should include multiple compounds and stream compartments, and highlight the need for holistic approaches when risk assessing these dynamic systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Experiments on Suppression of Thermocapillary Oscillations in Sodium Nitrate Floating Half-Zones by High-frequency End-wall Vibrations

    NASA Technical Reports Server (NTRS)

    Anilkumar, A.; Grugel, R. N.; Bhowmick, J.; Wang, T.

    2004-01-01

    Experiments to suppress thermocapillary oscillations using high-frequency vibrations were carried out in sodium nitrate floating half-zones. Such a half-zone is formed by melting one end of a vertically held sodium nitrate crystal rod in contact with a hot surface at the top. Thermocapillary convection occurs in the melt because of the temperature gradient at the free surface of the melt. In the experiments, when thermocapillary oscillations occurred, the bottom end of the crystal rod was vibrated at a high frequency to generate a streaming flow in a direction opposite to that of the thermocapillary convection. It is observed that, by generating a sufficiently strong streaming flow, the thermocapillary flow can be offset enough such that the associated thermocapillary oscillations can be quenched.

  20. Potential effects of roadside dry wells on groundwater quality on the Island of Hawai'i-Assessment using numerical groundwater models

    USGS Publications Warehouse

    Izuka, Scot K.

    2011-01-01

    Widespread use of dry wells to dispose of roadside runoff has raised concern about the potential effects on the quality of groundwater on the Island of Hawai‘i. This study used semi-generic numerical models of groundwater flow and contaminant transport to assess the potential effect of dry wells on groundwater quality on the Island of Hawai‘i. The semi-generic models are generalized numerical groundwater-flow and solute-transport models that have a range of aquifer properties and regional groundwater gradients that are characteristic for the island. Several semi-generic models were created to study the effect of dry wells in different hydrogeologic conditions, such as different unsaturated-zone thicknesses or different aquifer characteristics. Results indicate that mixing of contaminated water from the surface with contaminant-free water in the saturated aquifer immediately reduces the contaminant concentration. The amount the concentration is reduced depends on the hydraulic properties of the aquifer in a given area, the thickness of the unsaturated zone, and whether the infiltration is focused in a small area of a dry well or spread naturally over a larger area. Model simulations indicate that focusing infiltration of contaminated runoff through a dry well can substantially increase contaminant concentrations in the underlying saturated aquifer relative to infiltration under natural conditions. Simulated concentrations directly beneath a dry well were nearly 8 times higher than the simulated concentrations directly beneath a broad infiltration area representing the natural condition. Where dry wells are present, contaminant concentrations in the underlying saturated aquifer are lower when the unsaturated zone is thicker and higher when the unsaturated zone is thinner. Contaminant concentrations decline quickly as the contaminant plume migrates, with the regional groundwater flow, away from the dry well. The differences among concentrations resulting from the various unsaturated-zone thicknesses also diminish with distance from the dry well. At a horizontal distance of about 700 ft downgradient from the dry well, all simulated maximum concentrations were less than 1 percent of the concentration in the infiltration water; at about 0.5 mi downgradient from the dry well, all simulated concentrations were equal to or less than 0.1 percent. Actual concentrations may be even lower than indicated by the models because of processes such as decay and reaction that were not simulated. Hydrologic and geologic differences from one location to the next also affect contaminant concentrations—simulations using models with properties representative of aquifers in the Hilo area resulted in lower overall concentrations than models with properties representative of aquifers in the Kona area. Results from this study can be used to assess how contaminants entering a dry well may affect receiving waters in a variety of situations on the Island of Hawai‘i. Better assessment would be obtained by using results from models having the most similar conditions (such as climate, hydraulic properties, regional groundwater gradient) to the dry well in question. The results of this study can help determine which dry wells are likely to have the greatest effect on nearby receiving waters and where more specific data and analyses may be needed.

  1. Impact of debris dams on hyporheic interaction along a semi-arid stream

    NASA Astrophysics Data System (ADS)

    Lautz, Laura K.; Siegel, Donald I.; Bauer, Robert L.

    2006-01-01

    Hyporheic exchange increases the potential for solute retention in streams by slowing downstream transport and increasing solute contact with the substrate. Hyporheic exchange may be a major mechanism to remove nutrients in semi-arid watersheds, where livestock have damaged stream riparian zones and contributed nutrients to stream channels. Debris dams, such as beaver dams and anthropogenic log dams, may increase hyporheic interactions by slowing stream water velocity, increasing flow complexity and diverting water to the subsurface.Here, we report the results of chloride tracer injection experiments done to evaluate hyporheic interaction along a 320 m reach of Red Canyon Creek, a second order stream in the semi-arid Wind River Range of Wyoming. The study site is part of a rangeland watershed managed by The Nature Conservancy of Wyoming, and used as a hydrologic field site by the University of Missouri Branson Geologic Field Station. The creek reach we investigated has debris dams and tight meanders that hypothetically should enhance hyporheic interaction. Breakthrough curves of chloride measured during the field experiment were modelled with OTIS-P, a one-dimensional, surface-water, solute-transport model from which we extracted the storage exchange rate and cross-sectional area of the storage zone As for hyporheic exchange. Along gaining reaches of the stream reach, short-term hyporheic interactions associated with debris dams were comparable to those associated with severe meanders. In contrast, along the non-gaining reach, stream water was diverted to the subsurface by debris dams and captured by large-scale near-stream flow paths. Overall, hyporheic exchange rates along Red Canyon Creek during snowmelt recession equal or exceed exchange rates observed during baseflow at other streams.

  2. Solid aerosol generator

    DOEpatents

    Prescott, Donald S.; Schober, Robert K.; Beller, John

    1992-01-01

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates.

  3. Science You Can Use Bulletin: Our forests in the [water] balance

    Treesearch

    Megan Matonis; Charles Luce; Zack Holden; Penny Morgan; Emily Heyerdahl

    2013-01-01

    Climate change is not only causing temperatures to rise, it is also altering the amount and type of precipitation that falls across the western United States. Research shows a trend of increasingly dry "dry years," meaning droughts are becoming more severe and streams are flowing lower during these periods.

  4. IMPACTS OF MARINE AEROSOLS ON SURFACE WATER CHEMISTRY AT BEAR BROOK WATERSHED, MAINE USA

    EPA Science Inventory

    The East Bear catchment at Bear Brook Watershed, Maine receives moderate (for the eastern U.S.) amounts of Cl- in wet and dry deposition. In 1989, Cl- in precipitation ranged from 2 to 55 eq/L. Dry, occult, and wet deposition plus evapotranspiration resulted in stream Cl- averagi...

  5. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOEpatents

    Erickson, Donald C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

  6. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOEpatents

    Erickson, D.C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

  7. Method for removing undesired particles from gas streams

    DOEpatents

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  8. Method and apparatus for decreased undesired particle emissions in gas streams

    DOEpatents

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  9. Method and apparatus for decreased undesired particle emissions in gas streams

    DOEpatents

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Bustard, Cynthia Jean

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  10. Method for removing undesired particles from gas streams

    DOEpatents

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Hyatt, David E.; Bustard, Cynthia Jean; Sjostrom, Sharon

    1998-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  11. Riverside East Solar Energy Zone (SEZ) - California

    Science.gov Websites

    Los Mogotes East Nevada Amargosa Valley Dry Lake Dry Lake Valley North Gold Point Millers New Mexico Pavement Cultural Gravel Bench I 10 Wiley Well Road South Wiley Well Rest Stop Ford Dry Lake Get Adobe there are also dry lake beds, sandy areas, and dry washes with ironwood and other trees. Some areas are

  12. Effect of manure application on abundance of antibiotic resistance genes and their attenuation rates in soil: field-scale mass balance approach.

    PubMed

    Fahrenfeld, Nicole; Knowlton, Katharine; Krometis, Leigh Anne; Hession, W Cully; Xia, Kang; Lipscomb, Emily; Libuit, Kevin; Green, Breanna Lee; Pruden, Amy

    2014-01-01

    The development of models for understanding antibiotic resistance gene (ARG) persistence and transport is a critical next step toward informing mitigation strategies to prevent the spread of antibiotic resistance in the environment. A field study was performed that used a mass balance approach to gain insight into the transport and dissipation of ARGs following land application of manure. Soil from a small drainage plot including a manure application site, an unmanured control site, and an adjacent stream and buffer zone were sampled for ARGs and metals before and after application of dairy manure slurry and a dry stack mixture of equine, bovine, and ovine manure. Results of mass balance suggest growth of bacterial hosts containing ARGs and/or horizontal gene transfer immediately following slurry application with respect to ermF, sul1, and sul2 and following a lag (13 days) for dry-stack-amended soils. Generally no effects on tet(G), tet(O), or tet(W) soil concentrations were observed despite the presence of these genes in applied manure. Dissipation rates were fastest for ermF in slurry-treated soils (logarithmic decay coefficient of -3.5) and for sul1 and sul2 in dry-stack-amended soils (logarithmic decay coefficients of -0.54 and -0.48, respectively), and evidence for surface and subsurface transport was not observed. Results provide a mass balance approach for tracking ARG fate and insights to inform modeling and limiting the transport of manure-borne ARGs to neighboring surface water.

  13. Relating runoff generation mechanisms to concentration-discharge relationships in catchments with well-characterized Critical Zone structures and hydrologic dynamics

    NASA Astrophysics Data System (ADS)

    Hahm, W. J.; Wang, J.; Druhan, J. L.; Rempe, D.; Dietrich, W. E.

    2017-12-01

    Stream solute concentration-discharge (C-Q) relationships integrate catchment-scale hydrologic and geochemical processes, potentially yielding valuable information about runoff generation and weathering mechanisms. However, recent compilations have established that chemostasis—the condition where solute concentrations are invariant across large ranges of runoff—is observed in watersheds of diverse lithology, climate, and topography, suggesting an equifinality of the C-Q relationship independent of hydrologic process. Here we explore C-Q signals in contrasting catchments of the Eel River Critical Zone (CZ) Observatory in the Northern California Coast Ranges, where, unlike most watersheds where chemostasis has been observed, hillslope hydrologic processes are well characterized via years of intensive hydrologic monitoring. Our two catchments in the Franciscan Complex have radically different runoff generation mechanisms arising from differences in CZ structure: at Elder Creek (Coastal Belt), rain passes vertically as unsaturated flow through soil, saprolite, and a thick weathered rock zone before perching as groundwater on fresh bedrock and flowing laterally through fractures to generate streamflow, resulting in nearly chemostatic major cation behavior (power law C-Q slopes (B) ≈ 0 to -0.1). At Dry Creek (Central Belt), the thin (2 to 3 m) hydrologically active CZ completely saturates in most storm events, generating saturation overland flow across the landscape. New data from Dry Creek reveal log-log C-Q relationships for major cations that exhibit negative curvature, indicating a trend towards increasing dilution at higher flow rates and a possible C-Q signature of overland flow. High geomorphic channel drainage density (16.9 km/km2) results in short flow paths and, presumably, short water hillslope residence times at high runoff when overland flow dominates (> 50 mm d-1). Surprisingly, even at these high runoff rates, pure dilution does not occur (high runoff B ≈ -0.5), suggesting a role for extremely rapid cation exchange reactions and equilibration as water flows over and through the soil surface, and underscoring limitations on the ability to interpret hydrologic processes from C-Q behavior.

  14. Reactor for fluidized bed silane decomposition

    NASA Technical Reports Server (NTRS)

    Iya, Sridhar K. (Inventor)

    1989-01-01

    An improved heated fluidized bed reactor and method for the production of high purity polycrystalline silicon by silane pyrolysis wherein silicon seed particles are heated in an upper heating zone of the reactor and admixed with particles in a lower zone, in which zone a silane-containing gas stream, having passed through a lower cooled gas distribution zone not conducive to silane pyrolysis, contacts the heated seed particles whereon the silane is heterogeneously reduced to silicon.

  15. Stream bed temperature profiles as indicators of percolation characteristics beneath arroyos in the middle Rio Grande Basin, USA

    USGS Publications Warehouse

    Constantz, J.; Thomas, C.L.

    1997-01-01

    Stream bed temperature profiles were monitored continuously during water year 1990 and 1991 (WY90 and 91) in two New Mexico arroyos, similar in their meteorological features and dissimilar in their hydrological features. Stream bed temperature profiles between depths of 30 and 300 cm were examined to determine whether temporal changes in temperature profiles represent accurate indicators of the timing, depth and duration of percolation in each stream bed. These results were compared with stream flow, air temperature, and precipitation records for WY90 and 91, to evaluate the effect of changing surface conditions on temperature profiles. Temperature profiles indicate a persistently high thermal gradient with depth beneath Grantline Arroyo, except during a semi-annual thermal reversal in spring and autumn. This typifies the thermal response of dry sediments with low thermal conductivities. High thermal gradients were disrupted only during infrequent stream flows, followed by rapid re-establishment of high gradients. The stream bed temperature at 300 cm was unresponsive to individual precipitation or stream flow during WY90 and 91. This thermal pattern provides strong evidence that most seepage into Grantline Arroyo failed to percolate at a sufficient rate to reach 300 cm before being returned to the atmosphere. A distinctly different thermal pattern was recorded beneath Tijeras Arroyo. Low thermal gradients between 30 and 300 cm and large diurnal variations in temperature, suggest that stream flow created continuous, advection-dominated heat transport for over 300 days, annually. Beneath Tijeras Arroyo, low thermal gradients were interrupted only briefly during periodic, dry summer conditions. Comparisons of stream flow records for WY90 and 91 with stream bed temperature profiles indicate that independent analysis of thermal patterns provides accurate estimates of the timing, depth and duration of percolation beneath both arroyos. Stream flow loss estimates indicate that seepage rates were 15 times greater for Tijeras Arroyo than for Grantline Arroyo, which supports qualitative conclusions derived from analysis of stream bed temperature responses to surface conditions. ?? 1997 John Wiley & Sons, Ltd.

  16. System for drying and heating particulate coal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Offergeld, E.; Wischniewski, M.

    1978-04-04

    Wet particulate coal and a current of hot dry gas at superatmospheric pressure are introduced into a substantially closed drying chamber to contact the material with the gas while maintaining the drying chamber under superatmospheric pressure so that the material is dried by the gas. The dried material is withdrawn from the drying chamber and the gas is withdrawn from the drying chamber and itself mixed with a stream of hot dry gas produced by burning a combustible and a combustion-supporting gas. This mixture is then reintroduced into the drying chamber as the current of hot gas used to drymore » the coal. The burner is operated at superatmospheric pressure and is formed of a jet-pump type injector, and a diffusor is provided downstream of this injector in the circulation path.« less

  17. Total Mercury and Methylmercury in the Great Egg Harbor River Watershed, New Jersey, USA

    NASA Astrophysics Data System (ADS)

    Barringer, J. L.; Riskin, M. L.; Szabo, Z.; Fischer, J. M.; Reilly, P. A.; Rosman, R.; Bonin, J. L.; Heckathorn, H. A.

    2007-12-01

    Hydrologic and biogeochemical conditions are important factors in the transport and distribution of mercury (Hg) in New Jersey Coastal Plain watersheds that contain extensive freshwater wetlands and where Hg bioaccumulation is of concern. U.S. Geological Survey studies found Hg concentrations in top predator fish from the Great Egg Harbor River mainstem that ranged from 2.9 to 4.5 mg/kg (dry wt.) and exceeded 10 ng/L in the watershed's acidic streams. An ongoing study with the N.J. Department of Environmental Protection indicates that atmospheric deposition of Hg to the wetlands and streams may be augmented by substantial contributions of Hg from ground water. Although background levels of Hg in water from the underlying aquifer typically are less than 10 ng/L, concentrations in water from more than 600 domestic wells in southern New Jersey have been shown to exceed the drinking-water maximum contaminant level of 2,000 ng/L. Therefore, to determine ground-water inputs to the streams, samples of ground water discharging to the tributaries and mainstem as well as streamwater samples collected during various flow conditions were analyzed for total Hg and methylmercury (MeHg). Total Hg concentrations in ground water discharging to the tributaries and mainstem were low to moderate (0.29-22 ng/L) in relatively undeveloped areas (including wetlands), but higher (36 and 177 ng/L) in two urban/suburban areas where much of the Hg was in particulate form. In recent and ongoing studies, total Hg concentrations in unfiltered samples of surface water, except those for one suburban tributary, have ranged from 2.13 to 37.7 ng/L. Concentrations in the suburban tributary have ranged from 50 ng/L during a dry period to 250 ng/L during a wet period. Hg concentrations in samples from a wetlands-embedded reach of the mainstem varied markedly with flow. In addition to increases in concentrations of total Hg, UV absorbance and concentrations of dissolved organic carbon also increased with flow after rain events, whereas pH and concentrations of dissolved oxygen and nitrate decreased. These flow-related changes apparently result from inputs of water that has percolated through acidic, reducing wetlands soils. The biogeochemical environment of these soils, on the basis of hydrogen sulfide odors detected during piezometer placement, supports sulfate reduction and likely promotes methylation of Hg. MeHg concentrations were 0.48 ng/L after a rainfall in discharge from 0.8 m below the streambed at a mainstem wetlands site. Downstream, where the channel briefly emerges from wetlands, MeHg was detectable during a dry period only in the hyporheic-zone water from 0.15 m below the streambed and in ground water from a depth of 0.3 m (0.15 ng/L and 0.05 ng/L, respectively). MeHg was not detected in the ground-water samples from deeper points below the streambeds, but concentrations in surface water ranged from 0.17 to 2.88 ng/L. The concentration from a tributary surrounded by urban/suburban development was highest. MeHg concentrations in mainstem water did not always increase with streamflow; variations in antecedent hydrologic conditions in the wetlands may explain the unpredictable relation of concentration to flow. Overall, total Hg appears to be contributed to the streams by both ground water and atmospheric deposition, with methylation taking place at shallow levels in wetlands soils and stream sediments.

  18. Examining the role of dissolved organic nitrogen in stream ecosystems across biomes and Critical Zone gradients

    NASA Astrophysics Data System (ADS)

    Wymore, A.; Rodriguez-Cardona, B.; Coble, A. A.; Potter, J.; Lopez Lloreda, C.; Perez Rivera, K.; De Jesus Roman, A.; Bernal, S.; Martí Roca, E.; Kram, P.; Hruska, J.; Prokishkin, A. S.; McDowell, W. H.

    2016-12-01

    Watershed nitrogen exports are often dominated by dissolved organic nitrogen (DON); yet, little is known about the role ambient DON plays in ecosystems. As an organic nutrient, DON may serve as either an energy source or as a nutrient source. One hypothesized control on DON is nitrate (NO3-) availability. Here we examine the interaction of NO3- and DON in streams across temperate forests, tropical rainforests, and Mediterranean and taiga biomes. Experimental streams also drain contrasting Critical Zones which provide gradients of vegetation, soil type and lithology (e.g. volcaniclastic, granitic, ultramafic, Siberian Traps Flood Basalt) in which to explore how the architecture of the Critical Zone affects microbial biogeochemical reactions. Streams ranged in background dissolved organic carbon (DOC) concentration (1-50 mg C/L) and DOC: NO3- ratios (10-2000). We performed a series of ecosystem-scale NO3- additions in multiple streams within each environment and measured the change in DON concentration. Results demonstrate that there is considerable temporal and spatial variation across systems with DON both increasing and decreasing in response to NO3- addition. Ecologically this suggests that DON can serve as both a nutrient source and an energy source to aquatic microbial communities. In contrast, DOC concentrations rarely changed in response to NO3- additions suggesting that the N-rich fraction of the ambient dissolved organic matter pool is more bioreactive than the C-rich fraction. Contrasting responses of the DON and DOC pools indicate different mechanisms controlling their respective cycling. It is likely that DON plays a larger role in ecosystems than previously recognized.

  19. Geochemical evolution of the Critical Zone across variable time scales informs concentration-discharge relationships: Jemez River Basin Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    McIntosh, Jennifer C.; Schaumberg, Courtney; Perdrial, Julia; Harpold, Adrian; Vázquez-Ortega, Angélica; Rasmussen, Craig; Vinson, David; Zapata-Rios, Xavier; Brooks, Paul D.; Meixner, Thomas; Pelletier, Jon; Derry, Louis; Chorover, Jon

    2017-05-01

    This study investigates the influence of water, carbon, and energy fluxes on solute production and transport through the Jemez Critical Zone (CZ) and impacts on C-Q relationships over variable spatial and temporal scales. Chemical depletion-enrichment profiles of soils, combined with regolith thickness and groundwater data indicate the importance to stream hydrochemistry of incongruent dissolution of silicate minerals during deep bedrock weathering, which is primarily limited by water fluxes, in this highly fractured, young volcanic terrain. Under high flow conditions (e.g., spring snowmelt), wetting of soil and regolith surfaces and presence of organic acids promote mineral dissolution and provide a constant supply of base cations, Si, and DIC to soil water and groundwater. Mixing of waters from different hydrochemical reservoirs in the near stream environment during "wet" periods leads to the chemostatic behavior of DIC, base cations, and Si in stream flow. Metals transported by organic matter complexation (i.e., Ge, Al) and/or colloids (i.e., Al) during periods of soil saturation and lateral connectivity to the stream display a positive relationship with Q. Variable Si-Q relationships, under all but the highest flow conditions, can be explained by nonconservative transport and precipitation of clay minerals, which influences long versus short-term Si weathering fluxes. By combining measurements of the CZ obtained across different spatial and temporal scales, we were able to constrain weathering processes in different hydrological reservoirs that may be flushed to the stream during hydrologic events, thereby informing C-Q relationships.

  20. Partial root-zone drying and conventional deficit irrigation applied during the whole berry growth maintain yield and berry quality in 'Crimson Seedless' table grapes

    NASA Astrophysics Data System (ADS)

    Pérez-Pastor, Alejandro; Domingo, Rafael; De la Rosa, Jose M.°; Rosario Conesa Saura, M.°

    2016-04-01

    To compare the effects of partial root-zone drying and conventional deficit irrigation applied during post-veraison and the whole berry growth on water relations, yield and berry quality, one experiment was conducted in a commercial vineyard of 'Crimson Seedless' table grapes. Five irrigation treatments were imposed: (i) Control (CTL) irrigated to 110% of crop evapotranspiration (ETc), (ii) regulated deficit irrigation (RDI) irrigated at 50% of CTL during the non- critical period of post-verasion, (iii) continuous deficit irrigation (DIc), irrigated at 50% of CTL throughout the whole berry growing season, (iv) partial root-zone drying (PRD), irrigated similar to RDI, but alternating the irrigation applied in the dry side every 10-14 days; and (v) continuous partial root-zone drying (PRDc), irrigated as DIc but alternating the irrigation in the dry side every 10-14 days. RDI and PRD received 24% and 28% less water than CTL, respectively. These reductions were higher in DIc and PRDc (65% and 53%, respectively). Total yield was not affected by any DI strategy. Only significantly lower values were observed in the weight and height's berries in respect to CTL. However, the colour parameters evaluated increased in all DI treatments, being slightly higher in DIc and PRDc compared with RDI and PRD. In addition, total soluble solids (TSS) were significantly higher in DIc, compared to other irrigated counterparts. Our findings showed that the application of water deficit during the whole berry growth through the use of DIc and PRDc, can be considered for irrigation scheduling in 'Crimson Seedless' table grapes. Acknowledgements This work has been funded by the European Union LIFE+ project IRRIMAN (LIFE13 ENV/ES/000539).

  1. Assessing the ecological benefits and opportunity costs of alternative stream management zone widths for eastern hardwoods

    Treesearch

    Chris B. LeDoux; Ethel Wilkerson

    2008-01-01

    Leaving buffer zones adjacent to waterways can effectively reduce the water quality concerns associated with timber harvesting. However, riparian areas are also some of the most productive sites and can yield high quality wood. The amount of unharvested timber left in SMZs (Streamside Management Zones) can represent a substantial opportunity cost to landowners. In this...

  2. Assessing the ecological benefits and opportunity costs of alternative stream management zone widths

    Treesearch

    Chris B. LeDoux; Ethel Wilkerson

    2008-01-01

    Leaving buffer zones adjacent to waterways can effectively reduce the water quality concerns associated with timber harvesting. However, riparian areas are also some of the most productive sites and can yield high quality wood. The amount of unharvested timber left in SMZs (Streamside Management Zones) can represent a substantial opportunity cost to landowners. In this...

  3. Antarctic climate cooling and response of diatoms in glacial meltwater streams

    USGS Publications Warehouse

    Esposito, R.M.M.; Horn, S.L.; McKnight, Diane M.; Cox, M.J.; Grant, M.C.; Spaulding, S.A.; Doran, P.T.; Cozzetto, K.D.

    2006-01-01

    To understand biotic responses to an Antarctic cooling trend diatom samples from glacial meltwater streams in the McMurdo Dry Valleys, the largest ice-free area in Antarctica. Diatoms are abundant in these streams, and 24 of 40 species have only been found in the Antarctic. The percentage of these Antarctic diatom species increased with decreasing annual stream flow and increasing harshness of the stream habitat. The species diversity of assemblages reached a maximum when the Antarctic species accounted for 40-60% of relative diatom abundance. Decreased solar radiation and air-temperatures reduce annual stream flow, raising the dominance of these Antarctic species to levels above 60%. Thus, cooling favors the Antarctic species, and lowers diatom species diversity in this region. Copyright 2006 by the American Geophysical Union.

  4. Ecological functions of riparian zones in Oregon hydrological landscapes

    EPA Science Inventory

    The ecological functions of streams and associated riparian zones are strongly influenced by the hydrological attributes of watersheds and landscapes in which they occur. Oregon hydrologic landscape regions (HLRs) have been defined based on four types of GIS data: 1) climate, 2) ...

  5. Assessing water use and quality through youth participatory research in a rural Andean watershed.

    PubMed

    Roa García, C E; Brown, S

    2009-07-01

    Water availability, use and quality in a rural watershed of the Colombian Andes were investigated through participatory research involving local youth. Research included the quantification of disaggregated water use at the household level; comparison of water use with availability; monitoring water quality of streams, community water intakes and household faucets; and the determination of land use-water quality interactions. Youth were involved in all aspects of the research from design to implementation, dissemination of results and remediation options. Quantification of domestic and on-farm water use, and water availability indicated that water availability was sufficient during the study period, but that only an 8% decrease in dry season supply would result in shortages. Elevated conductivity levels in the headwaters were related to "natural" bank erosion, while downstream high conductivity and coliform levels were associated with discharges from livestock stalls and poorly maintained septic tanks in the stream buffer zone. Through the involvement of youth as co-investigators, the knowledge generated by the research was appropriated at the local level. Community workshops led by local youth promoted water conservation and water quality protection practices based on research, and resulted in broader community participation in water management. The approach involving youth in research stimulated improved management of both land and water resources, and could be applied in small rural watersheds in developed or developing countries.

  6. Dynamic river networks as the context for evaluating riparian influence on river basin solute export

    EPA Science Inventory

    Many studies have examined the influence of riparian areas on nitrogen as water drains from hillslopes and through riparian zones at the stream reach scale. Most of these studies have been conducted along relatively small streams. However, water quality concerns typically deal wi...

  7. The Effects of Spatial Resolution on Impervious Cover Classifications in Watersheds and Riparian Zones in Vermont

    EPA Science Inventory

    Impervious cover (roads, rooftops, etc.) is a known stressor on stream biota and habitat and is often used as an indicator for assessing the effects of urbanization on stream health. Understanding how spatial data resolution impacts estimates of impervious cover is important for ...

  8. Nutrient sampling slam: high resolution surface-water sampling in streams reveals patterns in groundwater chemistry and flow paths

    EPA Science Inventory

    The groundwater–surface water interface (GSWI), consisting of shallow groundwater adjacent to stream channels, is a hot spot for nitrogen removal processes, a storage zone for other solutes, and a target for restoration activities. Characterizing groundwater-surface water intera...

  9. NITRATE REMOVAL EFFECTIVENESS OF A RIPARIAN BUFFER ALONG A SMALL AGRICULTURAL STREAM IN WESTERN OREGON

    EPA Science Inventory

    We established two study sites with similar soils and hydrology but contrasting riparian vegetation along Lake Creek, an intermittent stream that drains perennial ryegrass fields in the Willamette Valley of western Oregon. One site had a non-cultivated riparian zone with a plant...

  10. Ground-Water Occurrence and Contribution to Streamflow, Northeast Maui, Hawaii

    USGS Publications Warehouse

    Gingerich, Stephen B.

    1999-01-01

    The study area lies on the northern flank of the East Maui Volcano (Haleakala) and covers about 129 square miles between the drainage basins of Maliko Gulch to the west and Makapipi Stream to the east. About 989 million gallons per day of rainfall and 176 million gallons per day of fog drip reaches the study area and about 529 million gallons per day enters the ground-water system as recharge. Average annual ground-water withdrawal from wells totals only about 3 million gallons per day; proposed (as of 1998) additional withdrawals total about 18 million gallons per day. Additionally, tunnels and ditches of an extensive irrigation network directly intercept at least 10 million gallons per day of ground water. The total amount of average annual streamflow in gaged stream subbasins upstream of 1,300 feet altitude is about 255 million gallons per day and the total amount of average annual base flow is about 62 million gallons per day. Six major surface-water diversion systems in the study area have diverted an average of 163 million gallons per day of streamflow (including nearly all base flow of diverted streams) for irrigation and domestic supply in central Maui during 1925-97. Fresh ground water is found in two main forms. West of Keanae Valley, ground-water flow appears to be dominated by a variably saturated system. A saturated zone in the uppermost rock unit, the Kula Volcanics, is separated from a freshwater lens near sea level by an unsaturated zone in the underlying Honomanu Basalt. East of Keanae Valley, the ground-water system appears to be fully saturated above sea level to altitudes greater than 2,000 feet. The total average annual streamflow of gaged streams west of Keanae Valley is about 140 million gallons per day at 1,200 feet to 1,300 feet altitude. It is not possible to estimate the total average annual streamflow at the coast. All of the base flow measured in the study area west of Keanae Valley represents ground-water discharge from the high-elevation saturated zone. Total average daily ground-water discharge from the high-elevation saturated zone upstream of 1,200 feet altitude is greater than 38 million gallons per day, all of which is eventually removed from the streams by surface-water diversion systems. Perennial streamflow has been measured at altitudes greater than 3,000 feet in several of the streams. Discharge from the high-elevation saturated zone is persistent even during periods of little rainfall. The total average annual streamflow of the gaged streams east of Keanae Valley is about 109 million gallons per day at about 1,300 feet altitude. It is not possible to estimate the total average annual streamflow at the coast nor at higher altitudes. All of the base flow measured east of Keanae Valley represents ground-water discharge from the vertically extensive freshwater-lens system. Total average daily ground-water discharge to gaged streams upstream of 1,200 feet altitude is about 27 million gallons per day. About 19 million gallons per day of ground water discharges through the Kula and Hana Volcanics between about 500 feet and 1,300 feet altitude in the gaged stream sub-basins. About 13 million gallons per day of this discharge is in Hanawi Stream. The total ground-water discharge above 500 feet altitude in this part of the study area is greater than 56 million gallons per day.

  11. Oxygen Carbon Dynamics within the Hyporheic Zone of a Headwater Stream

    NASA Astrophysics Data System (ADS)

    Pennington, R.; Haggerty, R.; Wondzell, S. M.; Serchan, S. P.; Reeder, W. J.; Tonina, D.

    2016-12-01

    Streams and rivers influence global carbon fluxes; on an aerial basis, they have disproportionately high export rates compared to land. Various mechanisms exist for the movement of terrestrially derived carbon to the stream network including transport of organic and inorganic carbon with groundwater and hillslope runoff. A secondary process that has received little attention is carbon dynamics of hyporheic flow along flow paths that pass beneath the vegetated riparian zone. Through use of high frequency monitoring of dissolved inorganic carbon and dissolved oxygen we find that the riparian zone is a net source of carbon throughout the year. Increases in DIC relative stream water are generally more than double decreases in O2 on a molar basis. Metabolic quotients of C to O2 are close to 1.0, therefore respiration of dissolved or particulate organic carbon along flow paths would result in an equal magnitude increase in inorganic carbon to decrease in O2. Diffusion from the high CO2 soil atmosphere into hyporheic water has been considered, however 2-D reactive transport modeling using PFLOTRAN indicates that soil diffusion processes are unlikely to produce observed increases in carbon and that alternative transport mechanisms including root respiration or diel water level fluctuations are necessary for mass balance. Results of the analysis will feed into a comprehensive distributed model of the system that explores carbon dynamics at the reach scale.

  12. Variation of organic matter quantity and quality in streams at Critical Zone Observatory watersheds

    USGS Publications Warehouse

    Miller, Matthew P.; Boyer, Elizabeth W.; McKnight, Diane M.; Brown, Michael G.; Gabor, Rachel S.; Hunsaker, Carolyn T.; Iavorivska , Lidiia; Inamdar, Shreeram; Kaplan, Louis A.; Johnson, Dale W.; Lin, Henry; McDowell, William H.; Perdrial, Julia N.

    2016-01-01

    The quantity and chemical composition of dissolved organic matter (DOM) in surface waters influence ecosystem processes and anthropogenic use of freshwater. However, despite the importance of understanding spatial and temporal patterns in DOM, measures of DOM quality are not routinely included as part of large-scale ecosystem monitoring programs and variations in analytical procedures can introduce artifacts. In this study, we used consistent sampling and analytical methods to meet the objective of defining variability in DOM quantity and quality and other measures of water quality in streamflow issuing from small forested watersheds located within five Critical Zone Observatory sites representing contrasting environmental conditions. Results show distinct separations among sites as a function of water quality constituents. Relationships among rates of atmospheric deposition, water quality conditions, and stream DOM quantity and quality are consistent with the notion that areas with relatively high rates of atmospheric nitrogen and sulfur deposition and high concentrations of divalent cations result in selective transport of DOM derived from microbial sources, including in-stream microbial phototrophs. We suggest that the critical zone as a whole strongly influences the origin, composition, and fate of DOM in streams. This study highlights the value of consistent DOM characterization methods included as part of long-term monitoring programs for improving our understanding of interactions among ecosystem processes as controls on DOM biogeochemistry.

  13. Liquid additives for particulate emissions control

    DOEpatents

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Hyatt, David E.; Bustard, Cynthia Jean; Sjostrom, Sharon

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  14. Influence of warm air-drying on enamel bond strength and surface free-energy of self-etch adhesives.

    PubMed

    Shiratsuchi, Koji; Tsujimoto, Akimasa; Takamizawa, Toshiki; Furuichi, Tetsuya; Tsubota, Keishi; Kurokawa, Hiroyasu; Miyazaki, Masashi

    2013-08-01

    We examined the effect of warm air-drying on the enamel bond strengths and the surface free-energy of three single-step self-etch adhesives. Bovine mandibular incisors were mounted in self-curing resin and then wet ground with #600 silicon carbide (SiC) paper. The adhesives were applied according to the instructions of the respective manufacturers and then dried in a stream of normal (23°C) or warm (37°C) air for 5, 10, and 20 s. After visible-light irradiation of the adhesives, resin composites were condensed into a mold and polymerized. Ten samples per test group were stored in distilled water at 37°C for 24 h and then the bond strengths were measured. The surface free-energies were determined by measuring the contact angles of three test liquids placed on the cured adhesives. The enamel bond strengths varied according to the air-drying time and ranged from 15.8 to 19.1 MPa. The trends for the bond strengths were different among the materials. The value of the γS⁺ component increased slightly when drying was performed with a stream of warm air, whereas that of the γS⁻ component decreased significantly. These data suggest that warm air-drying is essential to obtain adequate enamel bond strengths, although increasing the drying time did not significantly influence the bond strength. © 2013 Eur J Oral Sci.

  15. Characterisation of the hydrology of an estuarine wetland

    NASA Astrophysics Data System (ADS)

    Hughes, Catherine E.; Binning, Philip; Willgoose, Garry R.

    1998-11-01

    The intertidal zone of estuarine wetlands is characterised by a transition from a saline marine environment to a freshwater environment with increasing distance from tidal streams. An experimental site has been established in an area of mangrove and salt marsh wetland in the Hunter River estuary, Australia, to characterise and provide data for a model of intertidal zone hydrology. The experimental site is designed to monitor water fluxes at a small scale (36 m). A weather station and groundwater monitoring wells have been installed and hydraulic head and tidal levels are monitored over a 10-week period along a short one-dimensional transect covering the transition between the tidal and freshwater systems. Soil properties have been determined in the laboratory and the field. A two-dimensional finite element model of the site was developed using SEEP/W to analyse saturated and unsaturated pore water movement. Modification of the water retention function to model crab hole macropores was found necessary to reproduce the observed aquifer response. Groundwater response to tidal fluctuations was observed to be almost uniform beyond the intertidal zone, due to the presence of highly permeable subsurface sediments below the less permeable surface sediments. Over the 36 m transect, tidal forcing was found to generate incoming fluxes in the order of 0.22 m 3/day per metre width of creek bank during dry periods, partially balanced by evaporative fluxes of about 0.13 m 3/day per metre width. During heavy rainfall periods, rainfall fluxes were about 0.61 m 3/day per metre width, dominating the water balance. Evapotranspiration rates were greater for the salt marsh dominated intertidal zone than the non-tidal zone. Hypersalinity and salt encrustation observed show that evapotranspiration fluxes are very important during non-rainfall periods and are believed to significantly influence salt concentration both in the surface soil matrix and the underlying aquifer.

  16. Groundwater contaminants in the deep benthic zone of urban streams in Canada (Invited)

    NASA Astrophysics Data System (ADS)

    Roy, J. W.; Bickerton, G.

    2010-12-01

    There is little information available on the potential threat that groundwater containing land-based contaminants poses to aquatic ecosystems in urban environments. In this study, a rapid screening approach was applied at the stream reach-scale for eight urban streams (reaches from 100 to < 1000 m). The objective was to determine what types of groundwater contaminants could be detected in the deeper benthic zone of these streams, if any, to start to address questions of whether such contaminants are a concern and which types are the most problematic. The benthic community may be especially at risk since it may experience higher contaminant concentrations than the stream itself due to fewer losses from sorption, degradation and volatilization processes. For each stream, groundwater samples from below the stream bed (typically 25-75 cm) were collected using a drive-point mini-profiler at intervals of 10-15 m along the stream and were subsequently analysed for general chemistry and a wide range of common and emerging urban contaminants. For a few test streams with known contamination, the area of contamination was identified with this technique. In addition, previously unknown contaminants or areas of contamination were identified at all nine streams. Identified contaminants included benzene and other petroleum hydrocarbons, fuel oxygenates (e.g. MTBE), perchlorate, pesticides, artificial sweeteners, and various chlorinated solvent compounds. In addition, elevated levels of nitrate, phosphate, some heavy metals, including cadmium and arsenic, and elevated chloride (likely indicating road salt) were detected. Most streams had many different types of contaminants, often overlapping over small stretches, and together often covering substantial portions of the monitored reach. The findings provide support for this screening approach for delineating areas of potential ecological concern and identifying possible sources of groundwater contamination, for urban settings. They also suggest that the presence of multiple groundwater contaminants may be a more common threat to the benthic community of urban streams than currently perceived.

  17. The partitioning of copper among selected phases of geologic media of two porphyry copper districts, Puerto Rico

    USGS Publications Warehouse

    Learned, R.E.; Chao, T.T.; Sanzolone, R.F.

    1981-01-01

    In experiments designed to determine the manner in which copper is partitioned among selected phases that constitute geologic media, we have applied the five-step sequential extraction procedure of Chao and Theobald to the analysis of drill core, soils, and stream sediments of the Rio Vivi and Rio Tanama porphyry copper districts of Puerto Rico. The extraction procedure affords a convenient means of determining the trace-metal content of the following fractions: (1) Mn oxides and "reactive" Fe oxides; (2) "amorphous" Fe oxides; (3) "crystalline" Fe oxides; (4) sulfides and magnetite; and (5) silicates. An additional extraction between steps (1) and (2) was performed to determine organic-related copper in stream sediments. The experimental results indicate that apportionment of copper among phases constituting geologic media is a function of geochemical environment. Distinctive partitioning patterns were derived from the analysis of drill core from each of three geochemical zones: (a) the supergene zone of oxidation; (b) the supergene zone of enrichment; and (c) the hypogene zone; and similarly, from the analysis of; (d) soils on a weakly leached capping; (e) soils on a strongly leached capping; and (f) active stream sediment. The experimental results also show that geochemical contrasts (anomaly-to-background ratios) vary widely among the five fractions of each sampling medium investigated, and that at least one fraction of each medium provides substantially stronger contrast than does the bulk medium. Fraction (1) provides optimal contrast for stream sediments of the district; fraction (2) provides optimal contrast for soils on a weakly leached capping; fraction (3) provides optimal contrast for soils on a strongly leached capping. Selective extraction procedures appear to have important applications to the orientation and interpretive stages of geochemical exploration. Further investigation and testing of a similar nature are recommended. ?? 1981.

  18. Water balance modelling in a tropical watershed under deciduous forest (Mule Hole, India): Regolith matric storage buffers the groundwater recharge process

    NASA Astrophysics Data System (ADS)

    Ruiz, Laurent; Varma, Murari R. R.; Kumar, M. S. Mohan; Sekhar, M.; Maréchal, Jean-Christophe; Descloitres, Marc; Riotte, Jean; Kumar, Sat; Kumar, C.; Braun, Jean-Jacques

    2010-01-01

    SummaryAccurate estimations of water balance are needed in semi-arid and sub-humid tropical regions, where water resources are scarce compared to water demand. Evapotranspiration plays a major role in this context, and the difficulty to quantify it precisely leads to major uncertainties in the groundwater recharge assessment, especially in forested catchments. In this paper, we propose to assess the importance of deep unsaturated regolith and water uptake by deep tree roots on the groundwater recharge process by using a lumped conceptual model (COMFORT). The model is calibrated using a 5 year hydrological monitoring of an experimental watershed under dry deciduous forest in South India (Mule Hole watershed). The model was able to simulate the stream discharge as well as the contrasted behaviour of groundwater table along the hillslope. Water balance simulated for a 32 year climatic time series displayed a large year-to-year variability, with alternance of dry and wet phases with a time period of approximately 14 years. On an average, input by the rainfall was 1090 mm year -1 and the evapotranspiration was about 900 mm year -1 out of which 100 mm year -1 was uptake from the deep saprolite horizons. The stream flow was 100 mm year -1 while the groundwater underflow was 80 mm year -1. The simulation results suggest that (i) deciduous trees can uptake a significant amount of water from the deep regolith, (ii) this uptake, combined with the spatial variability of regolith depth, can account for the variable lag time between drainage events and groundwater rise observed for the different piezometers and (iii) water table response to recharge is buffered due to the long vertical travel time through the deep vadose zone, which constitutes a major water reservoir. This study stresses the importance of long term observations for the understanding of hydrological processes in tropical forested ecosystems.

  19. Linking Weathering, Rock Moisture Dynamics, Geochemistry, Runoff, Vegetation and Atmospheric Processes through the Critical Zone: Graduate Student led Research at the Eel River Critical Zone Observatory

    NASA Astrophysics Data System (ADS)

    Dietrich, W. E.

    2014-12-01

    In the Eel River Critical Zone Observatory lies Rivendell, a heavily-instrumented steep forested hillslope underlain by nearly vertically dipping argillite interbedded with sandstone. Under this convex hillslope lies "Zb", the transition to fresh bedrock, which varies from less than 6 m below the surface near the channel to 20 m at the divide. Rempe and Dietrich (2014, PNAS) show that the Zb profile can be predicted from the assumption that weathering occurs when drainage is induced in the uplifting fresh bedrock under hillslopes by lateral head gradients driven by channel incision at the hillslope boundary. Infiltrating winter precipitation is impeded at the lower conductivity boundary at Zb, generating perched groundwater that dynamically pulses water laterally to the channel, controlling stream runoff. Below the soil and above the water table lies an unsaturated zone through which all recharge to the perched groundwater (and thus all runoff to channels) occurs. It is this zone and the waters in them that profoundly affect critical zone processes. In our seasonally dry environment, the first rains penetrate past the soil and moisten the underlying weathered bedrock (Salve et al., 2012, WRR). It takes about 200 to 400 mm of cumulative rain, however, before the underlying groundwater rises significantly. Oshun et al (in review) show that by this cumulative rainfall the average of the wide-ranging isotopic signature of rain reaches a nearly constant average annual value. Consequently, the recharging perched groundwater shows only minor temporal isotopic variation. Kim et al, (2014, GCA) find that the winter high-flow groundwater chemistry is controlled by relatively fast-reacting cation exchange processes, likely occurring in transit in the unsaturated zone. Oshun also demonstrates that the Douglas fir rely on this rock moisture as a water source, while the broadleaf trees (oaks and madrone) use mostly soil moisture. Link et al (2014 WRR) show that Doug fir declines in transpiration rate significantly compared to the madrone during summer high water stress periods, with may induce feedbacks from the forest to atmospheric temperature and humidity. Collectively these studies spotlight the seasonally dynamic unsaturated zone in the weathered bedrock beneath the soil as key to understanding critical zone processes.

  20. 40 CFR 63.1257 - Test methods and compliance procedures.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the design minimum and average flame zone temperatures and combustion zone residence time; and shall... establish the design exhaust vent stream organic compound concentration level, adsorption cycle time, number... regeneration cycle, design carbon bed temperature after regeneration, design carbon bed regeneration time, and...

  1. 40 CFR 63.1257 - Test methods and compliance procedures.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the design minimum and average flame zone temperatures and combustion zone residence time; and shall... establish the design exhaust vent stream organic compound concentration level, adsorption cycle time, number... regeneration cycle, design carbon bed temperature after regeneration, design carbon bed regeneration time, and...

  2. Ecohydrologic separation of water between trees and streams in a Mediterranean climate

    Treesearch

    J. Renee Brooks; Holly R. Barnard; Rob Coulombe; Jeffrey J. McDonnell

    2010-01-01

    Here, we directly explore links between hydrology and transpiration at the small watershed scale in a seasonally dry climate. Our central questions were: to what extent do trees and streams return the same water pool to the hydrosphere and how does this vary spatially within a watershed? These questions are fundamental to testing watershed hydrology models and coupled...

  3. Catchment scale controls the temporal connection of transpiration and diel fluctuations in streamflow

    Treesearch

    C.B. Graham; H.R. Barnard; K.L. Kavanagh; J.P. McNamara

    2012-01-01

    Diel fluctuations can comprise a significant portion of summer discharge in small to medium catchments. The source of these signals and the manner in which they are propagated to stream gauging sites is poorly understood. In this work, we analysed stream discharge from 15 subcatchments in Dry Creek, Idaho, Reynolds Creek, Idaho, and HJ Andrews, Oregon. We identified...

  4. Reduced streamflow lowers dry-season growth of rainbow trout in a small stream

    Treesearch

    Bret C. Harvey; Rodney J. Nakamoto; Jason L. White

    2006-01-01

    A wide variety of resource management activities can affect surface discharge in small streams. Often, the effects of variation in streamflow on fish survival and growth can be difficult to estimate because of possible confounding with the effects of other variables, such as water temperature and fish density. We measured the effect of streamflow on survival and growth...

  5. Spatial variation in basic chemistry of streams draining a volcanic landscape on Costa Rica's Caribbean slope

    USGS Publications Warehouse

    Pringle, C.M.; Triska, F.J.; Browder, G.

    1990-01-01

    Spatial variability in selected chemical, physical and biological parameters was examined in waters draining relatively pristine tropical forests spanning elevations from 35 to 2600 meters above sea level in a volcanic landscape on Costa Rica's Caribbean slope. Waters were sampled within three different vegetative life zones and two transition zones. Water temperatures ranged from 24-25 ??C in streams draining lower elevations (35-250 m) in tropical wet forest, to 10 ??C in a crater lake at 2600 m in montane forest. Ambient phosphorus levels (60-300 ??g SRP L-1; 66-405 ??g TP L-1) were high at sites within six pristine drainages at elevations between 35-350 m, while other undisturbed streams within and above this range in elevation were low (typically <30.0 ??g SRP L-1). High ambient phosphorus levels within a given stream were not diagnostic of riparian swamp forest. Phosphorus levels (but not nitrate) were highly correlated with conductivity, Cl, Na, Ca, Mg and SO4. Results indicate two major stream types: 1) phosphorus-poor streams characterized by low levels of dissolved solids reflecting local weathering processes; and 2) phosphorus-rich streams characterized by relatively high Cl, SO4, Na, Mg, Ca and other dissolved solids, reflecting dissolution of basaltic rock at distant sources and/or input of volcanic brines. Phosphorus-poor streams were located within the entire elevation range, while phosphorus-rich streams were predominately located at the terminus of Pleistocene lava flows at low elevations. Results indicate that deep groundwater inputs, rich in phosphorus and other dissolved solids, surface from basaltic aquifers at breaks in landform along faults and/or where the foothills of the central mountain range merge with the coastal plain. ?? 1990 Kluwer Academic Publishers.

  6. Greenhouse Gas Dynamics in Streams and Riparian Floodplains located within Forested Landscapes of the US Northeast: Impact of Key Floodplain Geomorphic Features on Greenhouse Gas Production in a Forested Watershed in Northern New York State, USA.

    NASA Astrophysics Data System (ADS)

    Serchan, S. P.; Vidon, P.

    2015-12-01

    This study measured dissolved greenhouse gas (GHG) concentrations in interstitial water and stream across various "hotspots" in headwater catchments of Archer Creek watershed, New York, USA. Results indicated that stream water was hyper saturated with methane (CH4), and moderately saturated with carbon dioxide (CO2), and nitrous oxide (N2O). The values of dissolved CO2 (88.3 μmol/L), dissolved CH4 (1.2 μmol/L), and dissolved N2O (0.02 μmol/L) found in the stream were 5.8, 432, and 2.3 times in excess of atmospheric equilibrium, respectively. Results of dissolved GHG measured in interstitial water across various sites: riparian dry (RZ-Dry), riparian wet (RZ-Wet), riparian mucky (RZ-Mucky), pool with fine textured bed sediments (IS-fine-sedpool), pool with coarse textured bed sediments (IS-coarse-sed-pool), and riffles (Riffle) indicated high variations in the degree of saturation of all three GHG. RZ-Mucky, RZ-Wet, and IS-fine-sedpool sites were hotspots of CH4 and CO2 relative to other sites. RZ-Dry sites were hotspots of N2O. Multiple linear regression models indicated that dissolved oxygen (D.O.) and dissolved organic carbon (DOC) influenced dissolved CO2 and CH4 at most of the sites. Relationships between dissolved N2O and predictor variables were highly variable across all sites. Patterns of dissolved N2O in relatively oxic RZ-Dry sites (D.O. 5.3 mg/L) were positively correlated with nitrate (NO3) indicating nitrification as a dominant process in N2O production. In contrast, patterns of dissolved N2O were positively correlated with ammonium (NH4+) at RZ-Wet and RZ-Mucky sites where concentrations of D.O. were significantly lower compared to other sites.

  7. Effects of geomorphology, habitat, and spatial location on fish assemblages in a watershed in Ohio, USA.

    PubMed

    D'Ambrosio, Jessica L; Williams, Lance R; Witter, Jonathan D; Ward, Andy

    2009-01-01

    In this paper, we evaluate relationships between in-stream habitat, water chemistry, spatial distribution within a predominantly agricultural Midwestern watershed and geomorphic features and fish assemblage attributes and abundances. Our specific objectives were to: (1) identify and quantify key environmental variables at reach and system wide (watershed) scales; and (2) evaluate the relative influence of those environmental factors in structuring and explaining fish assemblage attributes at reach scales to help prioritize stream monitoring efforts and better incorporate all factors that influence aquatic biology in watershed management programs. The original combined data set consisted of 31 variables measured at 32 sites, which was reduced to 9 variables through correlation and linear regression analysis: stream order, percent wooded riparian zone, drainage area, in-stream cover quality, substrate quality, gradient, cross-sectional area, width of the flood prone area, and average substrate size. Canonical correspondence analysis (CCA) and variance partitioning were used to relate environmental variables to fish species abundance and assemblage attributes. Fish assemblages and abundances were explained best by stream size, gradient, substrate size and quality, and percent wooded riparian zone. Further data are needed to investigate why water chemistry variables had insignificant relationships with IBI scores. Results suggest that more quantifiable variables and consideration of spatial location of a stream reach within a watershed system should be standard data incorporated into stream monitoring programs to identify impairments that, while biologically limiting, are not fully captured or elucidated using current bioassessment methods.

  8. Drivers and Spatio-Temporal Extent of Hyporheic Patch Variation: Implications for Sampling

    PubMed Central

    Braun, Alexander; Auerswald, Karl; Geist, Juergen

    2012-01-01

    The hyporheic zone in stream ecosystems is a heterogeneous key habitat for species across many taxa. Consequently, it attracts high attention among freshwater scientists, but generally applicable guidelines on sampling strategies are lacking. Thus, the objective of this study was to develop and validate such sampling guidelines. Applying geostatistical analysis, we quantified the spatio-temporal variability of parameters, which characterize the physico-chemical substratum conditions in the hyporheic zone. We investigated eight stream reaches in six small streams that are typical for the majority of temperate areas. Data was collected on two occasions in six stream reaches (development data), and once in two additional reaches, after one year (validation data). In this study, the term spatial variability refers to patch contrast (patch to patch variance) and patch size (spatial extent of a patch). Patch contrast of hyporheic parameters (specific conductance, pH and dissolved oxygen) increased with macrophyte cover (r2 = 0.95, p<0.001), while patch size of hyporheic parameters decreased from 6 to 2 m with increasing sinuosity of the stream course (r2 = 0.91, p<0.001), irrespective of the time of year. Since the spatial variability of hyporheic parameters varied between stream reaches, our results suggest that sampling design should be adapted to suit specific stream reaches. The distance between sampling sites should be inversely related to the sinuosity, while the number of samples should be related to macrophyte cover. PMID:22860053

  9. Rock property measurements and analysis of selected igneous, sedimentary, and metamorphic rocks from worldwide localities

    USGS Publications Warehouse

    Johnson, Gordon R.

    1983-01-01

    Dry bulk density and grain density measurements were made on 182 samples of igneous, sedimentary, and metamorphic rocks from various world-wide localities. Total porosity values and both water-accessible and helium-accessible porosities were calculated from the density data. Magnetic susceptibility measurements were made on the solid samples and permeability and streaming potentials were concurrently measured on most samples. Dry bulk densities obtained using two methods of volume determination, namely direct measurement and Archlmedes principle, were nearly equivalent for most samples. Grain densities obtained on powdered samples were typically greater than grain densities obtained on solid samples, but differences were usually small. Sedimentary rocks had the highest percentage of occluded porosity per rock volume whereas metamorphic rocks had the highest percentage of occluded porosity per total porosity. There was no apparent direct relationship between permeability and streaming potential for most samples, although there were indications of such a relationship in the rock group consisting of granites, aplites, and syenites. Most rock types or groups of similar rock types of low permeability had, when averaged, comparable levels of streaming potential per unit of permeability. Three calcite samples had negative streaming potentials.

  10. Solid aerosol generator

    DOEpatents

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  11. Shrinking streamflows in the Redwood Region

    Treesearch

    Randy. D. Klein; Tasha McKee; Katrina Nystrom

    2017-01-01

    The ongoing, severe drought in the redwood ecosystem has many ramifications, including loss of summer rearing habitat for juvenile salmonids. Many ‘perennial’ streams now cease to flow during parts of the summer and fall, either drying up completely or disconnecting pools as riffles go dry, subjecting fish to increased predation, high water temperatures, and...

  12. Improved solid aerosol generator

    DOEpatents

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  13. Simultaneous treatment of SO2 containing stack gases and waste water

    NASA Technical Reports Server (NTRS)

    Poradek, J. C.; Collins, D. D. (Inventor)

    1978-01-01

    A process for simultaneously removing sulfur dioxide from stack gases and the like and purifying waste water such as derived from domestic sewage is described. A portion of the gas stream and a portion of the waste water, the latter containing dissolved iron and having an acidic pH, are contacted in a closed loop gas-liquid scrubbing zone to effect absorption of the sulfur dioxide into the waste water. A second portion of the gas stream and a second portion of the waste water are controlled in an open loop gas-liquid scrubbing zone. The second portion of the waste water contains a lesser amount of iron than the first portion of the waste water. Contacting in the openloop scrubbing zone is sufficient to acidify the waste water which is then treated to remove solids originally present.

  14. Buffer strip design for protecting water quality and fish habitat

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Belt, G.H.; O'Laughlin, J.

    1994-04-01

    Buffer strips are protective areas adjacent to streams or lakes. Among other functions, they protect water quality and fish habitat. A typical buffer strip is found in western Oregon, where they are called Riparian Management Areas (RMAs). The authors use the term buffer strip to include functional descriptions such as filter, stabilization, or leave strips, and administrative designations such as Idaho's Stream Protection Zone (SPZ), Washington's Riparian Management Zone (RMZ), and the USDA Forest Service's Streamside Management Zone (SMZ). They address water quality and fishery protective functions of buffer strips on forestlands, pointing out improvements in buffer strip design possiblemore » through research or administrative changes. Buffer strip design requirements found in some western Forest Practices Act (FPA) regulations are also compared and related to findings in the scientific literature.« less

  15. Evaluation of soil manipulation to prepare engineered earthen waste covers for revegetation

    DOE PAGES

    Waugh, W. Joseph; Benson, Craig H.; Albright, William H.; ...

    2015-10-21

    Seven ripping treatments designed to improve soil physical conditions for revegetation were compared on a test pad simulating an earthen cover for a waste disposal cell. The field test was part of study of methods to convert compacted-soil waste covers into evapotranspiration covers. The test pad consisted of a compacted layer of fine-textured soil simulating a barrier protection layer overlain by a gravelly sand bedding layer and a cobble armor layer. Treatments included combinations of soil-ripping implements (conventional shank [CS], wing-tipped shank [WTS], and parabolic oscillating shank with wings [POS]), ripping depths, and number of passes. Dimensions, dry density, moisturemore » content, and particle size distribution of disturbance zones were determined in two trenches excavated across rip rows. The goal was to create a root-zone dry density between 1.2 and 1.6 Mg m-3 and a seedbed soil texture ranging from clay loam to sandy loam with low rock content. All treatments created V-shaped disturbance zones as measured on trench faces. Disturbance zone size was most influenced by ripping depth. Winged implements created larger disturbance zones. All treatments lifted fines into the bedding layer, moved gravel and cobble down into the fine-textured protection layer, and thereby disrupted the capillary barrier at the interface. Changes in dry density within disturbance zones were comparable for the CS and WTS treatments but were highly variable among POS treatments. Water content increased in the bedding layer and decreased in the protection layer after ripping. The POS at 1.2-m depth and two passes created the largest zone with a low dry density (1.24 Mg m-3) and the most favorable seedbed soil texture (gravely silt loam). Furthermore, ripping also created large soil aggregates and voids in the protection layer that may produce preferential flow paths and reduce water storage capacity.« less

  16. Climate change poised to threaten hydrologic connectivity and endemic fishes in dryland streams

    PubMed Central

    Jaeger, Kristin L.; Olden, Julian D.; Pelland, Noel A.

    2014-01-01

    Protecting hydrologic connectivity of freshwater ecosystems is fundamental to ensuring species persistence, ecosystem integrity, and human well-being. More frequent and severe droughts associated with climate change are poised to significantly alter flow intermittence patterns and hydrologic connectivity in dryland streams of the American Southwest, with deleterious effects on highly endangered fishes. By integrating local-scale hydrologic modeling with emerging approaches in landscape ecology, we quantify fine-resolution, watershed-scale changes in habitat size, spacing, and connectance under forecasted climate change in the Verde River Basin, United States. Model simulations project annual zero-flow day frequency to increase by 27% by midcentury, with differential seasonal consequences on continuity (temporal continuity at discrete locations) and connectivity (spatial continuity within the network). A 17% increase in the frequency of stream drying events is expected throughout the network with associated increases in the duration of these events. Flowing portions of the river network will diminish between 8% and 20% in spring and early summer and become increasingly isolated by more frequent and longer stretches of dry channel fragments, thus limiting the opportunity for native fishes to access spawning habitats and seasonally available refuges. Model predictions suggest that midcentury and late century climate will reduce network-wide hydrologic connectivity for native fishes by 6–9% over the course of a year and up to 12–18% during spring spawning months. Our work quantifies climate-induced shifts in stream drying and connectivity across a large river network and demonstrates their implications for the persistence of a globally endemic fish fauna. PMID:25136090

  17. Climate change poised to threaten hydrologic connectivity and endemic fishes in dryland streams.

    PubMed

    Jaeger, Kristin L; Olden, Julian D; Pelland, Noel A

    2014-09-23

    Protecting hydrologic connectivity of freshwater ecosystems is fundamental to ensuring species persistence, ecosystem integrity, and human well-being. More frequent and severe droughts associated with climate change are poised to significantly alter flow intermittence patterns and hydrologic connectivity in dryland streams of the American Southwest, with deleterious effects on highly endangered fishes. By integrating local-scale hydrologic modeling with emerging approaches in landscape ecology, we quantify fine-resolution, watershed-scale changes in habitat size, spacing, and connectance under forecasted climate change in the Verde River Basin, United States. Model simulations project annual zero-flow day frequency to increase by 27% by midcentury, with differential seasonal consequences on continuity (temporal continuity at discrete locations) and connectivity (spatial continuity within the network). A 17% increase in the frequency of stream drying events is expected throughout the network with associated increases in the duration of these events. Flowing portions of the river network will diminish between 8% and 20% in spring and early summer and become increasingly isolated by more frequent and longer stretches of dry channel fragments, thus limiting the opportunity for native fishes to access spawning habitats and seasonally available refuges. Model predictions suggest that midcentury and late century climate will reduce network-wide hydrologic connectivity for native fishes by 6-9% over the course of a year and up to 12-18% during spring spawning months. Our work quantifies climate-induced shifts in stream drying and connectivity across a large river network and demonstrates their implications for the persistence of a globally endemic fish fauna.

  18. New streams and springs after the 2014 Mw6.0 South Napa earthquake

    PubMed Central

    Wang, Chi-Yuen; Manga, Michael

    2015-01-01

    Many streams and springs, which were dry or nearly dry before the 2014 Mw6.0 South Napa earthquake, started to flow after the earthquake. A United States Geological Survey stream gauge also registered a coseismic increase in discharge. Public interest was heightened by a state of extreme drought in California. Since the new flows were not contaminated by pre-existing surface water, their composition allowed unambiguous identification of their origin. Following the earthquake we repeatedly surveyed the new flows, collecting data to test hypotheses about their origin. We show that the new flows originated from groundwater in nearby mountains released by the earthquake. The estimated total amount of new water is ∼106 m3, about 1/40 of the annual water use in the Napa–Sonoma area. Our model also makes a testable prediction of a post-seismic decrease of seismic velocity in the shallow crust of the affected region. PMID:26158898

  19. RhoE deficiency alters postnatal subventricular zone development and the number of calbindin-expressing neurons in the olfactory bulb of mouse.

    PubMed

    Ballester-Lurbe, Begoña; González-Granero, Susana; Mocholí, Enric; Poch, Enric; García-Manzanares, María; Dierssen, Mara; Pérez-Roger, Ignacio; García-Verdugo, José M; Guasch, Rosa M; Terrado, José

    2015-11-01

    The subventricular zone represents an important reservoir of progenitor cells in the adult brain. Cells from the subventricular zone migrate along the rostral migratory stream and reach the olfactory bulb, where they originate different types of interneurons. In this work, we have analyzed the role of the small GTPase RhoE/Rnd3 in subventricular zone cell development using mice-lacking RhoE expression. Our results show that RhoE null mice display a remarkable postnatal broadening of the subventricular zone and caudal rostral migratory stream. This broadening was caused by an increase in progenitor proliferation, observed in the second postnatal week but not before, and by an altered migration of the cells, which appeared in disorganized cell arrangements that impaired the appropriate contact between cells in the rostral migratory stream. In addition, the thickness of the granule cell layer in the olfactory bulb was reduced, although the density of granule cells did not differ between wild-type and RhoE null mice. Finally, the lack of RhoE expression affected the olfactory glomeruli inducing a severe reduction of calbindin-expressing interneurons in the periglomerular layer. This was already evident in the newborns and even more pronounced 15 days later when RhoE null mice displayed 89% less cells than control mice. Our results indicate that RhoE has pleiotropic functions on subventricular cells because of its role in proliferation and tangential migration, affecting mainly the development of calbindin-expressing cells in the olfactory bulb.

  20. Evaluating hillslope and riparian contributions to dissolved nitrogen (N) export from a boreal forest catchment

    NASA Astrophysics Data System (ADS)

    Blackburn, M.; Ledesma, José L. J.; Näsholm, Torgny; Laudon, Hjalmar; Sponseller, Ryan A.

    2017-02-01

    Catchment science has long held that the chemistry of small streams reflects the landscapes they drain. However, understanding the contribution of different landscape units to stream chemistry remains a challenge which frequently limits our understanding of export dynamics. For limiting nutrients such as nitrogen (N), an implicit assumption is that the most spatially extensive landscape units (e.g., uplands) act as the primary sources to surface waters, while near-stream zones function more often as sinks. These assumptions, based largely on studies in high-gradient systems or in regions with elevated inputs of anthropogenic N, may not apply to low-gradient, nutrient-poor, and peat-rich catchments characteristic of many northern ecosystems. We quantified patterns of N mobilization along a hillslope transect in a northern boreal catchment to assess the extent to which organic matter-rich riparian soils regulate the flux of N to streams. Contrary to the prevailing view of riparian functioning, we found that near-stream, organic soils supported concentrations and fluxes of ammonium (NH4+) and dissolved organic nitrogen that were much higher than the contributing upslope forest soils. These results suggest that stream N chemistry is connected to N mobilization and mineralization within the riparian zone rather than the wider landscape. Results further suggest that water table fluctuation in near-surface riparian soils may promote elevated rates of net N mineralization in these landscapes.

  1. Water quality in riparian boreal forest: a multi-method approach to scale biogeochemical drivers from groundwater hotspots to catchment outlets.

    NASA Astrophysics Data System (ADS)

    Ploum, Stefan; Kuglerová, Lenka; Leach, Jason; Laudon, Hjalmar

    2017-04-01

    Stream chemistry in boreal regions is for a large degree defined by the riparian zone. Within the riparian zone, groundwater hotspots represent a very small area, but likely play a major role in controlling stream water quality. Hotspots have shown to be unique in their plant species richness, soil texture and biogeochemistry. Also in terms of stream metabolism, hotspots show different responses, either due to local biotic or abiotic conditions. Readily available hydrological mapping tools, combined with biogeochemical data (stream temperature and stable water isotopes) show that there is great potential in predicting groundwater hotspots using terrain-based approaches. However, the role of individual hotspots varies in time. Presumably their hydrological regime is highly dependent on landscape properties of the upstream area. To improve the predictability of hotspots in space and time, a mechanistic understanding is needed. We achieve this by a combined approach including a damming experiment, high resolution optic fiber stream temperature measurements (DTS), a dense groundwater well network, stream and groundwater trace element analysis, frost monitoring and infrared (IR) imagery. This field-based strategy sheds light on the underlying drivers of groundwater hotspots and links them to landscape characteristics. This allows to move away from highly monitored reaches, and evaluate the relation between upland landscape features and the temporal variability of groundwater exfiltration rates on a catchment scale.

  2. Land Cover and Hydrologic Variability in Residential Watersheds: Drivers of N Loss in Sacramento CA

    NASA Astrophysics Data System (ADS)

    McConaghie, J. B.; Zhou, W.; Cadenasso, M. L.

    2011-12-01

    A key aspect to understanding N loss from urban systems is the link between landscape heterogeneity and variability in non-point source (NPS) nitrogen (N) flux. Because water transports N across the landscape and into receiving streams as runoff, understanding how landscape heterogeneity influences water quantity and movement is also needed. High variability in N loss has been documented from urban systems. However, typical NPS studies characterize landscape heterogeneity by land use and only weakly explain variability in stream N. Focusing on land cover, rather than land use, may better explain observed variability in N loss because land cover elements may better indicate major drivers of N loss. Also, most studies have been conducted in temperate urban systems with stream flow year round. In semi-arid urban systems, storm flow accounts for the majority of stream discharges, and residential irrigation contributes significantly to flows in the dry season. To address how landscape heterogeneity affects variability in water quantity and quality in urban streams, we examined how land cover influences stream flows and N loss in residential streams of metropolitan Sacramento, CA. We analyzed fine-scale variation in land cover and stream N during base flow and storm events in 4 residential watersheds which differ substantially in land cover. We classified land cover using HERCULES (High Ecological Resolution Classification for Urban Landscapes and Environmental Systems) which was developed specifically for urban systems. HERCULES classifies high-resolution aerial photographs into 5 elements: buildings, pavement, herbaceous and woody vegetation, and bare soil. Streams were sampled for discharge, NO3, and Total N using auto samplers during storms in the 2010-2011 rainy season and monthly in the dry season. Partial correlation analysis and multivariate models describe the relationships between land cover elements, water retention, and stream N in these watersheds. We found an early season flush of N from streams during the first storms, and N levels diminished through progressive storms. Also, N concentrations were higher during the rainy season compared to the dry season. High proportion of impervious cover was associated with greater flow rates overall, while high proportion of herbaceous cover was associated with reduced flow rates during storms. The proportion of pavement in the watersheds, a commonly used indicator of urban intensity, did not strongly correlate with increased levels of stream N except during the flush, but did correlate with the magnitude and timing of flows during storms. However, high proportions of building cover, e.g. residential homes, did correlate with higher N fluxes. The use of fertilizers or enhanced N cycling through vegetation management near residential buildings is a possible source of increased N. Management to reduce aquatic enrichment of N from urban ecosystems may be best directed toward identifying N sources and sinks associated with specific land covers. Management must also account for seasonal dynamics, such as annual hydrologic patterns, which drive the loss of N.

  3. Corridors of migrating neurons in the human brain and their decline during infancy.

    PubMed

    Sanai, Nader; Nguyen, Thuhien; Ihrie, Rebecca A; Mirzadeh, Zaman; Tsai, Hui-Hsin; Wong, Michael; Gupta, Nalin; Berger, Mitchel S; Huang, Eric; Garcia-Verdugo, Jose-Manuel; Rowitch, David H; Alvarez-Buylla, Arturo

    2011-09-28

    The subventricular zone of many adult non-human mammals generates large numbers of new neurons destined for the olfactory bulb. Along the walls of the lateral ventricles, immature neuronal progeny migrate in tangentially oriented chains that coalesce into a rostral migratory stream (RMS) connecting the subventricular zone to the olfactory bulb. The adult human subventricular zone, in contrast, contains a hypocellular gap layer separating the ependymal lining from a periventricular ribbon of astrocytes. Some of these subventricular zone astrocytes can function as neural stem cells in vitro, but their function in vivo remains controversial. An initial report found few subventricular zone proliferating cells and rare migrating immature neurons in the RMS of adult humans. In contrast, a subsequent study indicated robust proliferation and migration in the human subventricular zone and RMS. Here we find that the infant human subventricular zone and RMS contain an extensive corridor of migrating immature neurons before 18 months of age but, contrary to previous reports, this germinal activity subsides in older children and is nearly extinct by adulthood. Surprisingly, during this limited window of neurogenesis, not all new neurons in the human subventricular zone are destined for the olfactory bulb--we describe a major migratory pathway that targets the prefrontal cortex in humans. Together, these findings reveal robust streams of tangentially migrating immature neurons in human early postnatal subventricular zone and cortex. These pathways represent potential targets of neurological injuries affecting neonates.

  4. Stream inflow and predation risk affect littoral habitat selection by benthic fish

    Treesearch

    Karl M. Polivka; Lisa M. Friedli; Elizabeth C. Green

    2013-01-01

    We examined small, fishless headwater streams to determine whether transport of macroinvertebrates into the littoral zone of an oligotrophic lake augmented food availability for Cottus asper, an abundant predatory fish in our study system. We sampled fish and macroinvertebrates during the recruitment and growth season of 2 years, either monthly (2004...

  5. Appendix C: GLEES Macroinvertebrates

    Treesearch

    B. C. Kondratieff

    1994-01-01

    This Appendix identifies macroinvertebrate species found in streams and lakes at GLEES during a preliminary qualitative survey conducted in the summer of 1988 by Dr. Boris Kondratieff. The littoral zones of each lake and each stream were sampled by hand-picking and with a triangle net. Insect voucher specimens are maintained in the Gillette Entomological Museum at...

  6. THE HYDRAULIC CHARACTERISTICS AND GEOCHEMISTRY OF HYPORHEIC AND PARAFLUVIAL ZONES IN ARCTIC TUNDRA STREAMS, NORTH SLOPE, ALASKA

    EPA Science Inventory

    Sodium bromide and Rhodamine WT were used as conservative tracers to examine the hydrologic characteristics of seven tundra streams in Arctic Alaska, during the summers of 1994-1996. Continuous tracer additions were conducted in seven rivers ranging from 1st to 5th order with sam...

  7. 78 FR 45871 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-30

    ... components: Hydrogeologic study; Surface water sampling study; Stream biological study; Air quality survey... components: Biological survey; Biota survey; Surface water and sediment characterization; Groundwater... impacted groundwater in three water bearing zones at the Site; the unconsolidated materials zone, the upper...

  8. 40 CFR 61.356 - Recordkeeping requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... also establish the design minimum and average temperature in the combustion zone and the combustion... temperatures, combustion zone residence time, and description of method and location where the vent stream is... control device are not operated as designed including all periods and the duration when: (i) Any valve car...

  9. Style and Rate of Late Pleistocene - Holocene Deformation of the Poukawa Fault Zone, Central Hawke's Bay, New Zealand

    NASA Astrophysics Data System (ADS)

    Basili, R.; Langridge, R. M.; Villamor, P.; Rieser, U.

    2008-12-01

    The Poukawa Fault Zone is one component of a complex system of contractional faulting in eastern North Island, New Zealand. It is located within the actively uplifting Hikurangi Margin where the Australian plate meets the Pacific plate at a convergence rate of over 40 mm/yr. The most destructive earthquake in New Zealand history, the 1931 Hawke's Bay earthquake of M 7.8, occurred just off the northern termination of the Poukawa Fault Zone. To the south and probably within the Poukawa Fault Zone, another strong earthquake struck near Waipukurau in 1863. We have characterized the contemporary style of faulting along the zone on the basis of an integrated analysis of a broad spectrum of data, including exploratory trenching; geomorphic data aided by 1m resolution digital orthophotos, a LIDAR-derived Terrain Model, and GPS-RTK surveys; stratigraphic and paleoseismic analysis; radiocarbon and OSL dating and tephra correlation. We have also made a detailed reconstruction of the terrace sequences formed where the Kaikora Stream crosses at a high angle to the Poukawa Fault Zone. These data show that the Poukawa Fault Zone is a contractional fault system formed by a series of NE-SW strands with style varying, from west to east, from high-angle east-dipping reverse to low-angle west-dipping thrusting. The geometry of the system suggests that these faults may merge at shallow depth into a single large structure capable of generating strong earthquakes similar to those that occurred in the past on nearby sections. All these faults variously displace the top of the Ohakean aggradation surface (12-15 ka) thereby generating scarps of several meters. The Kaikora Stream terrace sequences also testify to a series of uplift events associated with the late-Holocene growth of two of the eastern thrust faults. Two reaches of Kaikora Stream show evidence of uplifted and abandoned inset Holocene stream terraces found in association with a surface-rupture trace and an active fold. The four terraces in each case correspond in number with paeloearthquake events recognized in trenches nearby (Kelsey et al. 1998). Based on these relations the recurrence interval of surface faulting and folding is c. 3000-3700 yr. The abandonment of a low inset terrace capped by peat and Waimihia Tephra (c. 3400 yr BP) is consistent with this average recurrence. Based on the deformation of the dated Ohakean surface across the entire Poukawa Fault Zone, its reverse slip rate is c. 1-2 mm/yr.

  10. From soil water to surface water - how the riparian zone controls element transport from a boreal forest to a stream

    NASA Astrophysics Data System (ADS)

    Lidman, Fredrik; Boily, Åsa; Laudon, Hjalmar; Köhler, Stephan J.

    2017-06-01

    Boreal headwaters are often lined by strips of highly organic soils, which are the last terrestrial environment to leave an imprint on discharging groundwater before it enters a stream. Because these riparian soils are so different from the Podzol soils that dominate much of the boreal landscape, they are known to have a major impact on the biogeochemistry of important elements such as C, N, P and Fe and the transfer of these elements from terrestrial to aquatic ecosystems. For most elements, however, the role of the riparian zone has remained unclear, although it should be expected that the mobility of many elements is affected by changes in, for example, pH, redox potential and concentration of organic carbon as they are transported through the riparian zone. Therefore, soil water and groundwater was sampled at different depths along a 22 m hillslope transect in the Krycklan catchment in northern Sweden using soil lysimeters and analysed for a large number of major and trace elements (Al, As, B, Ba, Ca, Cd, Cl, Co, Cr, Cs, Cu, Fe, K, La, Li, Mg, Mn, Na, Ni, Pb, Rb, Se, Si, Sr, Th, Ti, U, V, Zn, Zr) and other parameters such as sulfate and total organic carbon (TOC). The results showed that the concentrations of most investigated elements increased substantially (up to 60 times) as the water flowed from the uphill mineral soils and into the riparian zone, largely as a result of higher TOC concentrations. The stream water concentrations of these elements were typically somewhat lower than in the riparian zone, but still considerably higher than in the uphill mineral soils, which suggests that riparian soils have a decisive impact on the water quality of boreal streams. The degree of enrichment in the riparian zone for different elements could be linked to the affinity for organic matter, indicating that the pattern with strongly elevated concentrations in riparian soils is typical for organophilic substances. One likely explanation is that the solubility of many organophilic elements increases as a result of the higher concentrations of TOC in the riparian zone. Elements with low or modest affinity for organic matter (e.g. Na, Cl, K, Mg and Ca) occurred in similar or lower concentrations in the riparian zone. Despite the elevated concentrations of many elements in riparian soil water and groundwater, no increase in the concentrations in biota could be observed (bilberry leaves and spruce shoots).

  11. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Levendis, Y.A.

    A study was conducted to determine the efficacy of carboxylic calcium and magnesium salts (e.g., calcium magnesium acetate or CMA, CaMg{sub 2}(CH{sub 2}COOH){sub 6}) for the simultaneous removal of SO{sub 2} and NO{sub x} in oxygen-lean atmospheres. Experiments were performed in a high-temperature furnace that simulated the post-flame environment of a coal-fired boiler by providing similar temperatures and partial pressures of SO{sub 2}, NO{sub x} CO{sub 2} and O{sub 2}. When injected into a hot environment, the salts calcined and formed highly porous {open_quotes}popcorn{close_quotes}-like cenospheres. Residual MgO and/or CaCO{sub 3} and CaO reacted heterogeneously with SO{sub 2} to form MgSO{submore » 4} and/or CaCO{sub 4}. The organic components - which can be manufactured from wastes such as sewage sludge - gasified and reduced NO{sub x }to N{sub 2} efficiently if the atmosphere was moderately fuel-rich. Dry-injected CMA particles at a Ca/S ratio of 2, residence time of 1 second and bulk equivalence ratio of 1.3 removed over 90% of SO{sub 2} and NO{sub x} at gas temperatures {>=} 950{degrees}C. When the furnace isothermal zone was {<=} 950{degrees}C, Ca was essentially inert in the furnace quenching zone, while Mg continued to sorb SO{sub 2} as the gas temperature cooled at a rate of -130{degrees}C/sec. Hence, the removal of SO{sub 2} by CMA could continue for nearly the entire residence time of emissions in the exhaust stream of a power plant. Additional research is needed to improve the efficiency and reduce the cost of the relatively expensive carboxylic acid salts as dual SO{sub 2}-NO{sub x} reduction agents. For example, wet injection of the salts could be combined with less expensive hydrocarbons such as lignite or even polymers such as poly(ethylene) that could be extracted from the municipal waste stream.« less

  12. Drum bubbler tritium processing system

    DOEpatents

    Rule, K.; Gettelfinger, G.; Kivler, P.

    1999-08-17

    A method is described for separating tritium oxide from a gas stream containing tritium oxide. The gas stream containing tritium oxide is fed into a container of water having a head space above the water. The tritium oxide is separated by bubbling the gas stream containing tritium oxide through the container of water and removing gas from the container head space above the water. Thereafter, the gas from the head space is dried to remove water vapor from the gas, and the water vapor is recycled to the container of water. 2 figs.

  13. Comparison of mercury mass loading in streams to atmospheric deposition in watersheds of Western North America: Evidence for non-atmospheric mercury sources.

    PubMed

    Domagalski, Joseph; Majewski, Michael S; Alpers, Charles N; Eckley, Chris S; Eagles-Smith, Collin A; Schenk, Liam; Wherry, Susan

    2016-10-15

    Annual stream loads of mercury (Hg) and inputs of wet and dry atmospheric Hg deposition to the landscape were investigated in watersheds of the Western United States and the Canadian-Alaskan Arctic. Mercury concentration and discharge data from flow gauging stations were used to compute annual mass loads with regression models. Measured wet and modeled dry deposition were compared to annual stream loads to compute ratios of Hg stream load to total Hg atmospheric deposition. Watershed land uses or cover included mining, undeveloped, urbanized, and mixed. Of 27 watersheds that were investigated, 15 had some degree of mining, either of Hg or precious metals (gold or silver), where Hg was used in the amalgamation process. Stream loads in excess of annual Hg atmospheric deposition (ratio>1) were observed in watersheds containing Hg mines and in relatively small and medium-sized watersheds with gold or silver mines, however, larger watersheds containing gold or silver mines, some of which also contain large dams that trap sediment, were sometimes associated with lower load ratios (<0.2). In the non-Arctic regions, watersheds with natural vegetation tended to have low ratios of stream load to Hg deposition (<0.1), whereas urbanized areas had higher ratios (0.34-1.0) because of impervious surfaces. This indicated that, in ecosystems with natural vegetation, Hg is retained in the soil and may be transported subsequently to streams as a result of erosion or in association with dissolved organic carbon. Arctic watersheds (Mackenzie and Yukon Rivers) had a relatively elevated ratio of stream load to atmospheric deposition (0.27 and 0.74), possibly because of melting glaciers or permafrost releasing previously stored Hg to the streams. Overall, our research highlights the important role of watershed characteristics in determining whether a landscape is a net source of Hg or a net sink of atmospheric Hg. Published by Elsevier B.V.

  14. Comparison of mercury mass loading in streams to atmospheric deposition in watersheds of Western North America: Evidence for non-atmospheric mercury sources

    USGS Publications Warehouse

    Domagalski, Joseph L.; Majewski, Michael S.; Alpers, Charles N.; Eckley, Chris S.; Eagles-Smith, Collin A.; Schenk, Liam N.; Wherry, Susan

    2016-01-01

    Annual stream loads of mercury (Hg) and inputs of wet and dry atmospheric Hg deposition to the landscape were investigated in watersheds of the Western United States and the Canadian-Alaskan Arctic. Mercury concentration and discharge data from flow gauging stations were used to compute annual mass loads with regression models. Measured wet and modeled dry deposition were compared to annual stream loads to compute ratios of Hg stream load to total Hg atmospheric deposition. Watershed land uses or cover included mining, undeveloped, urbanized, and mixed. Of 27 watersheds that were investigated, 15 had some degree of mining, either of Hg or precious metals (gold or silver), where Hg was used in the amalgamation process. Stream loads in excess of annual Hg atmospheric deposition (ratio > 1) were observed in watersheds containing Hg mines and in relatively small and medium-sized watersheds with gold or silver mines, however, larger watersheds containing gold or silver mines, some of which also contain large dams that trap sediment, were sometimes associated with lower load ratios (< 0.2). In the non-Arctic regions, watersheds with natural vegetation tended to have low ratios of stream load to Hg deposition (< 0.1), whereas urbanized areas had higher ratios (0.34–1.0) because of impervious surfaces. This indicated that, in ecosystems with natural vegetation, Hg is retained in the soil and may be transported subsequently to streams as a result of erosion or in association with dissolved organic carbon. Arctic watersheds (Mackenzie and Yukon Rivers) had a relatively elevated ratio of stream load to atmospheric deposition (0.27 and 0.74), possibly because of melting glaciers or permafrost releasing previously stored Hg to the streams. Overall, our research highlights the important role of watershed characteristics in determining whether a landscape is a net source of Hg or a net sink of atmospheric Hg.

  15. Effects of acid mine drainage on the stream ecosystem of the east fork of the Obey River, Tennessee

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nichols, L.E.; Bulow, F.L.

    1973-01-01

    The stream ecosystem of the east fork of the Obey River, Tennessee was studied from January through December 1970. Emphasis centered on water quality, macroinvertebrates, fish and aquatic flora affected by acid mine drainage. Two control stations were established within the study area, one located below the zone of pollution. A reservoir station was established to detect any neutralization occurring within Dale Hollow Reservoir below the confluence of the east fork and west fork. An area approximately 40 miles in length was found to be severely degraded by acid mine drainage. Limited macroinvertebrate populations existed within this region. Chironomus andmore » Sialis were the predominate benthic indicator organisms present in the polluted zone. Euglena mutabilis was the most abundant representative organism of the aquatic flora. This organism was found to be characteristic of acid mine pollution. Fish were recovered above and below, but not within, the zone of pollution. Fish recovered were characteristic of the type of habitat in which they were collected, being either typical stream or reservoir fish. A fish kill occurred in the east fork embayment of Dale Hollow on August 15, 1970 from acid mine drainage discharged upstream.« less

  16. Heat tracer methods

    USGS Publications Warehouse

    Healy, Richard W.; Scanlon, Bridget R.

    2010-01-01

    The flow of heat in the subsurface is closely linked to the movement of water (Ingebritsen et al., 2006). As such, heat has been used as a tracer in groundwater studies for more than 100 years (Anderson, 2005). As with chemical and isotopic tracers (Chapter 7), spatial or temporal trends in surface and subsurface temperatures can be used to infer rates of water movement. Temperature can be measured accurately, economically, at high frequencies, and without the need to obtain water samples, facts that make heat an attractive tracer. Temperature measurements made over space and time can be used to infer rates of recharge from a stream or other surface water body (Lapham, 1989; Stonestrom and Constantz, 2003); measurements can also be used to estimate rates of steady drainage through depth intervals within thick unsaturated zones (Constantz et al., 2003; Shan and Bodvarsson, 2004). Several thorough reviews of heat as a tracer in hydrologic studies have recently been published (Constantz et al., 2003; Stonestrom and Constantz, 2003; Anderson, 2005; Blasch et al., 2007; Constantz et al., 2008). This chapter summarizes heat-tracer approaches that have been used to estimate recharge.Some clarification in terminology is presented here to avoid confusion in descriptions of the various approaches that follow. Diffuse recharge is that which occurs more or less uniformly across large areas in response to precipitation, infiltration, and drainage through the unsaturated zone. Estimates of diffuse recharge determined using measured temperatures in the unsaturated zone are referred to as potential recharge because it is possible that not all of the water moving through the unsaturated zone will recharge the aquifer; some may be lost to the atmosphere by evaporation or plant transpiration. Estimated fluxes across confining units in the saturated zone are referred to as interaquifer flow (Chapter 1). Focused recharge is that which occurs directly from a point or line source, such as a stream, on land surface. Focused recharge may vary widely in space and time. If the water table intersects a stream channel, estimates of stream loss are called actual recharge, or just recharge. If the water table lies below the stream channel, estimates are referred to as potential recharge. For simplicity, all vertical water fluxes are referred to as drainage throughout this chapter. Whether the estimated quantity represents actual or potential recharge or drainage depends on the circumstances of each individual study.

  17. Regional scale groundwater modelling study for Ganga River basin

    NASA Astrophysics Data System (ADS)

    Maheswaran, R.; Khosa, R.; Gosain, A. K.; Lahari, S.; Sinha, S. K.; Chahar, B. R.; Dhanya, C. T.

    2016-10-01

    Subsurface movement of water within the alluvial formations of Ganga Basin System of North and East India, extending over an area of 1 million km2, was simulated using Visual MODFLOW based transient numerical model. The study incorporates historical groundwater developments as recorded by various concerned agencies and also accommodates the role of some of the major tributaries of River Ganga as geo-hydrological boundaries. Geo-stratigraphic structures, along with corresponding hydrological parameters,were obtained from Central Groundwater Board, India,and used in the study which was carried out over a time horizon of 4.5 years. The model parameters were fine tuned for calibration using Parameter Estimation (PEST) simulations. Analyses of the stream aquifer interaction using Zone Budget has allowed demarcation of the losing and gaining stretches along the main stem of River Ganga as well as some of its principal tributaries. From a management perspective,and entirely consistent with general understanding, it is seen that unabated long term groundwater extraction within the study basin has induced a sharp decrease in critical dry weather base flow contributions. In view of a surge in demand for dry season irrigation water for agriculture in the area, numerical models can be a useful tool to generate not only an understanding of the underlying groundwater system but also facilitate development of basin-wide detailed impact scenarios as inputs for management and policy action.

  18. Epidemiology and vectors of Dracunculus medinensis in northwest Burkina Faso, West Africa.

    PubMed

    Steib, K; Mayer, P

    1988-04-01

    The epidemiology of the guinea worm, Dracunculus medinensis, was studied in the dry savanna zone of West Africa. The monthly incidence data collected over a period of four years showed peak transmission occurring in June and July at the beginning of the rainy season. The different types of local water sources (i.e. wells, periodic streams, seasonal cattle waterings, natural ponds and man-made ponds) were examined for infected cyclopoid copepods. Small hand-dug ponds or water-holes situated in the fields proved to be the most important sites of transmission. While the domestic water supply is obtained from draw-wells in the villages throughout the year, the villagers take additional drinking water from these ponds during the planting season when farm activities require long stays in the fields. Four cyclopoid species were found for the first time acting as natural intermediate hosts of D. medinensis. Thermocyclops inopinus was the most frequently infected cyclopoid, and small man-made ponds are the preferred habitats of this species. Occurrence of T. inopinus is confined to the first half of the rainy season, coinciding with peak transmission. The epidemiology of dracunculiasis in dry and humid regions of West Africa is compared with regard to seasonality. The use of protective water filters proved to be the only adequate method for guinea worm control in the project area.

  19. Anthropogenic degradation of mountainous raised bogs. Case study of the Polish Carpathians

    NASA Astrophysics Data System (ADS)

    Lajczak, Adam

    2016-04-01

    Publications on the human impact on peat bogs pay a lot of attention to peat erosion, peat burning and changes in the physical and chemical properties of peat deposits that indicate pollution in the environment, but a more detailed analysis of current changes in the peat bog relief as a result of peat deposit extraction and drying is omitted. Compared to other areas of the world, the level of knowledge on anthropogenic changes in the relief of peat bogs in some areas of Poland may be considered advanced. This applies not only to peat bogs in northern Poland but also southern Poland, where peat bogs in the Carpathians and the Sudetes are also found. The best analyzed peat bogs in southern Poland are the raised bogs in the Orawsko-Nowotarska Basin (Western Carpathians) and in valleys in the Bieszczady Mts. (Eastern Carpathians). Both areas are impacted by deep precipitation shadow. The purpose of this paper is: (1) to assess the rate of shrinkage in the surface area of peat domes in the mentioned areas, (2) to describe the rate of growth in the surface area of older and younger post-peat areas, (3) to explain current changes in peat bogs morphology, (4) to explain changes in water retention in peat deposit, (5) to separate phases in peat bogs relief changes. With that in mind, the direction and rate of change of landforms typical of younger post-peat areas, such as peat extraction scarps, post-extraction hollows, drainage systems including ditches and regulated stream channels, were analyzed. A special emphasis was placed on the period of time when the restoration of such areas has taken place. The paper is based on an analysis of maps produced over the last 230 years as well as on aerial photographs taken since 1965 and on LiDAR data. Fieldwork included the geomorphological and hydrographic mapping of specified landforms within peat bogs using GPS methods. In period prior to human activity peat domes were larger than today and were surrounded by lagg fens and were drained by meandering streams. In period prior to the end of peat extraction and drying the amount of area lost by the peat dome and former wetland fringe can be identified in terms of older and younger post-peat areas. Stream channels in the general area have been regulated and drainage ditches dug. Partial or full peat extraction taking place primarily in the domes' fringe zone has produced major changes in peat bog relief and has substantially reduced peat bog water content. The increased density of drainage ditches in the area surrounding the remnants of peat domes has led to further drying of the peat bogs. An unintended consequence of stream regulation are shallower and wider channels that evolve into braided channels with a local tendency to aggradate material. The current stage of peat bogs development is their restoration which started when peat extraction had been halted in most peat bogs and drainage ditch maintenance had been abandoned.

  20. Lateral, vertical, and longitudinal connectivity of runoff source areas drive stream hydro-biogeochemical signals across a low relief drainage network

    NASA Astrophysics Data System (ADS)

    Zimmer, M. A.; McGlynn, B. L.

    2017-12-01

    Our understanding of the balance between longitudinal, lateral, and vertical expansion and contraction of reactive flowpaths and source areas in headwater catchments is limited. To address this, we utilized an ephemeral-to-perennial stream network in the Piedmont region of North Carolina, USA to gain new understanding about critical zone mechanisms that drive runoff generation and biogeochemical signals in both groundwater and stream water. Here, we used chemical and hydrometric data collected from zero through second order catchments to characterize spatial and temporal runoff and overland, shallow soil, and deep subsurface flow across characteristic landscape positions. Our results showed that the active stream network was driven by two superimposed runoff generation regimes that produced distinct hydro-biogeochemical signals at the catchment outlet. The baseflow runoff generation regime expanded and contracted the stream network seasonally through the rise and fall of the seasonal water table. Superimposed on this, event-activated source area contributions were driven by surficial and shallow subsurface flowpaths. The subsurface critical zone stratigraphy in this landscape coupled with the precipitation regime activated these shallow flowpaths frequently. This drove an increase in dissolved organic carbon (DOC) concentrations with increases in runoff across catchment scales. DOC-runoff relationship variability and spread was driven by the balance between runoff regimes as well as a seasonal depletion of DOC from shallow subsurface flowpath activation and annual replenishment from litterfall. From this, we suggest that the hydro-biogeochemical signals at larger catchment outlets can be driven by a balance of longitudinal, lateral, and vertical source area contributions, critical zone structure, and complex hydrological processes.

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