Comparison of Single-Phase and Two-Phase Composite Thermal Barrier Coatings with Equal Total Rare-Earth Content

NASA Astrophysics Data System (ADS)

Rai, Amarendra K.; Schmitt, Michael P.; Dorfman, Mitchell R.; Zhu, Dongming; Wolfe, Douglas E.

2018-04-01

Rare-earth zirconates have been the focus of advanced thermal barrier coating research for nearly two decades; however, their lack of toughness prevents a wide-scale adoption due to lack of erosion and thermal cyclic durability. There are generally two methods of improving toughness: intrinsic modification of the coating chemistry and extrinsic modification of the coating structure. This study compares the efficacy of these two methods for a similar overall rare-earth content via the air plasma spray process. The extrinsically toughened coatings were comprised of a two-phase composite containing 30 wt.% Gd2Zr2O7 (GZO) combined with 70 wt.% of a tougher t' low-k material (ZrO2-2Y2O3-1Gd2O3-1Yb2O3; mol.%), while a single-phase fluorite with the overall rare-earth content equivalent to the two-phase composite (13 mol.% rare-earth) was utilized to explore intrinsically toughened concept. The coatings were then characterized via x-ray diffraction, energy-dispersive spectroscopy, and scanning electron microscopy, and their performance was evaluated via erosion, thermal conductivity, thermal annealing (500 h), and thermal cycling. It was shown that the extrinsic method provided an improved erosion and thermal conductivity response over the single phase, but at the expense of high-temperature stability and cyclic life.

Green pigments of the Pompeian artists' palette.

PubMed

Aliatis, Irene; Bersani, Danilo; Campani, Elisa; Casoli, Antonella; Lottici, Pier Paolo; Mantovan, Silvia; Marino, Iari-Gabriel; Ospitali, Francesca

2009-08-01

Green colored samples on wall paintings and green powder from a pigment pot found in Pompeii area are investigated by micro-Raman, FT-IR and, for one sample, SEM-EDX. To obtain the green color, green earths and malachite were used, together with mixture of Egyptian blue and yellow ochre. The mineralogical identification of the green earths has been attempted through the comparison of the vibrational features, discriminating between celadonite and glauconite spectra. Traces of a modern synthetic pigment containing copper phthalocyanine were found in a fresco fragment.

Green pigments of the Pompeian artists' palette

NASA Astrophysics Data System (ADS)

Aliatis, Irene; Bersani, Danilo; Campani, Elisa; Casoli, Antonella; Lottici, Pier Paolo; Mantovan, Silvia; Marino, Iari-Gabriel; Ospitali, Francesca

2009-08-01

Green colored samples on wall paintings and green powder from a pigment pot found in Pompeii area are investigated by micro-Raman, FT-IR and, for one sample, SEM-EDX. To obtain the green color, green earths and malachite were used, together with mixture of Egyptian blue and yellow ochre. The mineralogical identification of the green earths has been attempted through the comparison of the vibrational features, discriminating between celadonite and glauconite spectra. Traces of a modern synthetic pigment containing copper phthalocyanine were found in a fresco fragment.

Earth physics and phase transformations program: A concept and proposal

NASA Technical Reports Server (NTRS)

Bonavito, N. L.; Tanaka, T.

1971-01-01

A program to study the geophysical characteristics of the earth is presented as an integration of the different disciplines that constitute the earth sciences, through the foundation of a generalized geodynamic theory of earth physics. A program is considered for defining the physical constants of the earth's material which parametrize the hydrodynamic equation in the microscopic solid state behavior of the crystals of the lithosphere. In addition, in order to lay the foundation for a generalized theory in earth physics, specific research areas are considered, such as the nature of the kinetics of the phase transitions in mineral assemblages, the equilibrium thermodynamic properties of crystals which are major constituents of mineral assemblages, and the transport properties of pure crystals which are major constituents of mineral assemblages.

Effects of 3D Earth structure on W-phase CMT parameters

NASA Astrophysics Data System (ADS)

Morales, Catalina; Duputel, Zacharie; Rivera, Luis; Kanamori, Hiroo

2017-04-01

The source inversion of the W-phase has demonstrated a great potential to provide fast and reliable estimates of the centroid moment tensor (CMT) for moderate to large earthquakes. It has since been implemented in different operational environments (NEIC-USGS, PTWC, etc.) with the aim of providing rapid CMT solutions. These solutions are in particular useful for tsunami warning purposes. Computationally, W-phase waveforms are usually synthetized by summation of normal modes at long period (100 - 1000 s) for a spherical Earth model (e.g., PREM). Although the energy of these modes mainly stays in the mantle where lateral structural variations are relatively small, the impact of 3D heterogeneities on W-phase solutions have not yet been quantified. In this study, we investigate possible bias in W-phase source parameters due to unmodeled lateral structural heterogeneities. We generate a simulated dataset consisting of synthetic seismograms of large past earthquakes that accounts for the Earth's 3D structure. The W-phase algorithm is then used to invert the synthetic dataset for earthquake CMT parameters with and without added noise. Results show that the impact of 3D heterogeneities is generally larger for surface-waves than for W-phase waveforms. However, some discrepancies are noted between inverted W-phase parameters and target values. Particular attention is paid to the possible bias induced by the unmodeled 3D structure into the location of the W-phase centroid. Preliminary results indicate that the parameter that is most susceptible to 3D Earth structure seems to be the centroid depth.

Selectivity optimization in green chromatography by gradient stationary phase optimized selectivity liquid chromatography.

PubMed

Chen, Kai; Lynen, Frédéric; De Beer, Maarten; Hitzel, Laure; Ferguson, Paul; Hanna-Brown, Melissa; Sandra, Pat

2010-11-12

Stationary phase optimized selectivity liquid chromatography (SOSLC) is a promising technique to optimize the selectivity of a given separation by using a combination of different stationary phases. Previous work has shown that SOSLC offers excellent possibilities for method development, especially after the recent modification towards linear gradient SOSLC. The present work is aimed at developing and extending the SOSLC approach towards selectivity optimization and method development for green chromatography. Contrary to current LC practices, a green mobile phase (water/ethanol/formic acid) is hereby preselected and the composition of the stationary phase is optimized under a given gradient profile to obtain baseline resolution of all target solutes in the shortest possible analysis time. With the algorithm adapted to the high viscosity property of ethanol, the principle is illustrated with a fast, full baseline resolution for a randomly selected mixture composed of sulphonamides, xanthine alkaloids and steroids. Copyright © 2010 Elsevier B.V. All rights reserved.

High pressure phase transitions in the rare earth metal erbium to 151 GPa.

PubMed

Samudrala, Gopi K; Thomas, Sarah A; Montgomery, Jeffrey M; Vohra, Yogesh K

2011-08-10

High pressure x-ray diffraction studies have been performed on the heavy rare earth metal erbium (Er) in a diamond anvil cell at room temperature to a pressure of 151 GPa and Er has been compressed to 40% of its initial volume. The rare earth crystal structure sequence hcp → Sm type → dhcp → distorted fcc (hcp: hexagonal close packed; fcc: face centered cubic; dhcp: double hcp) is observed in Er below 58 GPa. We have carried out Rietveld refinement of crystal structures in the pressure range between 58 GPa and 151 GPa. We have examined various crystal structures that have been proposed for the distorted fcc (dfcc) phase and the post-dfcc phase in rare earth metals. We find that the hexagonal hR 24 structure is the best fit between 58 and 118 GPa. Above 118 GPa, a structural transformation from hR 24 phase to a monoclinic C 2/m phase is observed with a volume change of - 1.9%. We have also established a clear trend for the pressure at which a post-dfcc phase is formed in rare earth metals and show that there is a monotonic increase in this pressure with the filling of 4f shell.

High pressure phase transitions in the rare earth metal erbium to 151 GPa

NASA Astrophysics Data System (ADS)

Samudrala, Gopi K.; Thomas, Sarah A.; Montgomery, Jeffrey M.; Vohra, Yogesh K.

2011-08-01

High pressure x-ray diffraction studies have been performed on the heavy rare earth metal erbium (Er) in a diamond anvil cell at room temperature to a pressure of 151 GPa and Er has been compressed to 40% of its initial volume. The rare earth crystal structure sequence {hcp} \\to {Sm}~ {type} \\to {dhcp} \\to {distorted} fcc (hcp: hexagonal close packed; fcc: face centered cubic; dhcp: double hcp) is observed in Er below 58 GPa. We have carried out Rietveld refinement of crystal structures in the pressure range between 58 GPa and 151 GPa. We have examined various crystal structures that have been proposed for the distorted fcc (dfcc) phase and the post-dfcc phase in rare earth metals. We find that the hexagonal hR 24 structure is the best fit between 58 and 118 GPa. Above 118 GPa, a structural transformation from hR 24 phase to a monoclinic C 2/m phase is observed with a volume change of - 1.9%. We have also established a clear trend for the pressure at which a post-dfcc phase is formed in rare earth metals and show that there is a monotonic increase in this pressure with the filling of 4f shell.

Phase transitions in MgSiO3 post-perovskite in super-Earth mantles

NASA Astrophysics Data System (ADS)

Umemoto, Koichiro; Wentzcovitch, Renata M.; Wu, Shunqing; Ji, Min; Wang, Cai-Zhuang; Ho, Kai-Ming

2017-11-01

The highest pressure form of the major Earth-forming mantle silicate is MgSiO3 post-perovskite (PPv). Understanding the fate of PPv at TPa pressures is the first step for understanding the mineralogy of super-Earths-type exoplanets, arguably the most interesting for their similarities with Earth. Modeling their internal structure requires knowledge of stable mineral phases, their properties under compression, and major element abundances. Several studies of PPv under extreme pressures support the notion that a sequence of pressure induced dissociation transitions produce the elementary oxides SiO2 and MgO as the ultimate aggregation form at ∼3 TPa. However, none of these studies have addressed the problem of mantle composition, particularly major element abundances usually expressed in terms of three main variables, the Mg/Si and Fe/Si ratios and the Mg#, as in the Earth. Here we show that the critical compositional parameter, the Mg/Si ratio, whose value in the Earth's mantle is still debated, is a vital ingredient for modeling phase transitions and internal structure of super-Earth mantles. Specifically, we have identified new sequences of phase transformations, including new recombination reactions that depend decisively on this ratio. This is a new level of complexity that has not been previously addressed, but proves essential for modeling the nature and number of internal layers in these rocky mantles.

K-Band Phased Array Developed for Low- Earth-Orbit Satellite Communications

NASA Technical Reports Server (NTRS)

Anzic, Godfrey

1999-01-01

Future rapid deployment of low- and medium-Earth-orbit satellite constellations that will offer various narrow- to wide-band wireless communications services will require phased-array antennas that feature wide-angle and superagile electronic steering of one or more antenna beams. Antennas, which employ monolithic microwave integrated circuits (MMIC), are perfectly suited for this application. Under a cooperative agreement, an MMIC-based, K-band phased-array antenna is being developed with 50/50 cost sharing by the NASA Lewis Research Center and Raytheon Systems Company. The transmitting array, which will operate at 19 gigahertz (GHz), is a state-of-the-art design that features dual, independent, electronically steerable beam operation ( 42 ), a stand-alone thermal management, and a high-density tile architecture. This array can transmit 622 megabits per second (Mbps) in each beam from Earth orbit to small Earth terminals. The weight of the total array package is expected to be less than 8 lb. The tile integration technology (flip chip MMIC tile) chosen for this project represents a major advancement in phased-array engineering and holds much promise for reducing manufacturing costs.

Earth Observing Scanning Polarimeter (EOSP), phase B

NASA Technical Reports Server (NTRS)

1990-01-01

Evaluations performed during a Phase B study directed towards defining an optimal design for the Earth Observing Scanning Polarimeter (EOSP) instrument is summarized. An overview of the experiment approach is included which provides a summary of the scientific objectives, the background of the measurement approach, and the measurement method. In the instrumentation section, details of the design are discussed starting with the key instrument features required to accomplish the scientific objectives and a system characterization in terms of the Stokes vector/Mueller matrix formalism. This is followed by a detailing of the instrument design concept, the design of the individual elements of the system, the predicted performance, and a summary of appropriate instrument testing and calibration. The selected design makes use of key features of predecessor polarimeters and is fully compatible with the Earth Observing System spacecraft requirements.

The EPOS Implementation Phase: building thematic and integrated services for solid Earth sciences

NASA Astrophysics Data System (ADS)

Cocco, Massimo; Epos Consortium, the

2015-04-01

The European Plate Observing System (EPOS) has a scientific vision and approach aimed at creating a pan-European infrastructure for Earth sciences to support a safe and sustainable society. To follow this vision, the EPOS mission is integrating a suite of diverse and advanced Research Infrastructures (RIs) in Europe relying on new e-science opportunities to monitor and understand the dynamic and complex Earth system. To this goal, the EPOS Preparatory Phase has designed a long-term plan to facilitate integrated use of data and products as well as access to facilities from mainly distributed existing and new research infrastructures for solid Earth Science. EPOS will enable innovative multidisciplinary research for a better understanding of the Earth's physical processes that control earthquakes, volcanic eruptions, ground instability and tsunami as well as the processes driving tectonics and Earth surface dynamics. Through integration of data, models and facilities EPOS will allow the Earth Science community to make a step change in developing new concepts and tools for key answers to scientific and socio-economic questions concerning geo-hazards and geo-resources as well as Earth sciences applications to the environment and to human welfare. Since its conception EPOS has been built as "a single, Pan-European, sustainable and distributed infrastructure". EPOS is, indeed, the sole infrastructure for solid Earth Science in ESFRI and its pan-European dimension is demonstrated by the participation of 23 countries in its preparatory phase. EPOS is presently moving into its implementation phase further extending its pan-European dimension. The EPOS Implementation Phase project (EPOS IP) builds on the achievements of the successful EPOS preparatory phase project. The EPOS IP objectives are synergetic and coherent with the establishment of the new legal subject (the EPOS-ERIC in Italy). EPOS coordinates the existing and new solid Earth RIs within Europe and builds the

Complete phase diagram of rare-earth nickelates from first-principles

NASA Astrophysics Data System (ADS)

Varignon, Julien; Grisolia, Mathieu N.; Íñiguez, Jorge; Barthélémy, Agnès; Bibes, Manuel

2017-12-01

The structural, electronic and magnetic properties of AMO3 perovskite oxides, where M is a 3d transition metal, are highly sensitive to the geometry of the bonds between the metal-d and oxygen-p ions (through octahedra rotations and distortions) and to their level of covalence. This is particularly true in rare-earth nickelates RNiO3 that display a metal-insulator transition with complex spin orders tunable by the rare-earth size, and are on the border line between dominantly ionic (lighter elements) and covalent characters (heavier elements). Accordingly, computing their ground state is challenging and a complete theoretical description of their rich phase diagram is still missing. Here, using first-principles simulations, we successfully describe the electronic and magnetic experimental ground state of nickelates. We show that the insulating phase is characterized by a split of the electronic states of the two Ni sites (i.e., resembling low-spin 4+ and high-spin 2+) with a concomitant shift of the oxygen-2p orbitals toward the depleted Ni cations. Therefore, from the point of view of the charge, the two Ni sites appear nearly identical whereas they are in fact distinct. Performing such calculations for several nickelates, we built a theoretical phase diagram that reproduces all their key features, namely a systematic dependence of the metal-insulator transition with the rare-earth size and the crossover between a second to first order transition for R = Pr and Nd. Finally, our results hint at strategies to control the electronic and magnetic phases of perovskite oxides by fine tuning of the level of covalence.

Deformation of phase D and Earth's deep water cycle

NASA Astrophysics Data System (ADS)

Walker, A.; Skelton, R.; Nowacki, A.

2016-12-01

The stability of dense hydrous magnesium silicates such as phase D in subducting slabs provide a potential path for hydrogen transport from the Earth's surface environment into the lower mantle. Recent analysis of source-side shear wave splitting for rays from deep earthquakes around slabs detected a signal of anisotropy that could be attributed to the deformation of phase D [Nowacki et al. 2015; Geochem. Geophys. Geosyst., 16, 764-784]. If this is the case these observations could provide an estimate of the hydrogen flux into the lower mantle at depths beyond shallow recycling through the volcanic arc. However, the processes leading to the deformation of phase D and the generation of seismic anisotropy are not well known and this is a barrier to progress. Here we present initial results of simulations designed to reveal how easily different dislocations move in phase D during deformation and lead to the generation of seismic anisotropy measured by shear wave splitting. In particular, we use atomic scale simulations to calculate the energies of generalised stacking faults in phase D, which are used to parameterise Peierls-Nabarro models of dislocation structures and Peierls stresses at pressures up to 60 GPa. We then use results from these calculations as parameters for models of texture development in polycrystalline aggregates during deformation using the visco-plastic self-consistent approach. In combination with measurement of the distribution of seismic anisotropy around subducting slabs, and an analysis of the strain pattern expected as slabs pass through the transition zone, these results could constrain an important part of Earth's deep water cycle.

High-pressure phase of brucite stable at Earth's mantle transition zone and lower mantle conditions.

PubMed

Hermann, Andreas; Mookherjee, Mainak

2016-12-06

We investigate the high-pressure phase diagram of the hydrous mineral brucite, Mg(OH) 2 , using structure search algorithms and ab initio simulations. We predict a high-pressure phase stable at pressure and temperature conditions found in cold subducting slabs in Earth's mantle transition zone and lower mantle. This prediction implies that brucite can play a much more important role in water transport and storage in Earth's interior than hitherto thought. The predicted high-pressure phase, stable in calculations between 20 and 35 GPa and up to 800 K, features MgO 6 octahedral units arranged in the anatase-TiO 2 structure. Our findings suggest that brucite will transform from a layered to a compact 3D network structure before eventual decomposition into periclase and ice. We show that the high-pressure phase has unique spectroscopic fingerprints that should allow for straightforward detection in experiments. The phase also has distinct elastic properties that might make its direct detection in the deep Earth possible with geophysical methods.

Accumulation of alkaline earth metals by the green macroalga Bryopsis maxima.

PubMed

Takahashi, Shigekazu; Aizawa, Kyoko; Nakamura, Saki; Nakayama, Katsumi; Fujisaki, Shingo; Watanabe, Soichiro; Satoh, Hiroyuki

2015-04-01

Twenty-five days after the disaster at the Fukushima Daiichi nuclear power plant in 2011, we collected samples of the green macroalga Bryopsis maxima from the Pacific coast of Japan. Bryopsis maxima is a unicellular, multinuclear, siphonous green macroalga. Radiation analysis revealed that B. maxima emitted remarkably high gamma radiation of (131)I, (134)Cs, (137)Cs, and (140)Ba as fission products of (235)U. Interestingly, B. maxima contained naturally occurring radionuclides derived from (226)Ra and (228)Ra. Analysis of element content revealed that B. maxima accumulates many ocean elements, especially high quantities of the alkaline earth metals Sr (15.9 g per dry-kg) and Ba (3.79 g per dry-kg), whereas Ca content (12.5 g per dry-kg) was lower than that of Sr and only 61 % of the mean content of 70 Japanese seaweed species. Time-course analysis determined the rate of radioactive (85)Sr incorporation into thalli to be approximately 0.13 g Sr per dry-kg of thallus per day. Subcellular fractionation of B. maxima cells showed that most of the (85)Sr was localized in the soluble fraction, predominantly in the vacuole or cytosol. Given that (85)Sr radioactivity was permeable through a dialysis membrane, the (85)Sr was considered to be a form of inorganic ion and/or bound with a small molecule. Precipitation analysis with sodium sulfate showed that more than 70% of the Sr did not precipitate as SrSO4, indicating that a proportion of the Sr may bind with small molecules in B. maxima.

Extraction and characterization of mixed phase KNO2-KNO3 nanocrystals derived from flat-leaf green spinach

NASA Astrophysics Data System (ADS)

Hazarika, S.; Mohanta, D.

2013-01-01

Naturally available green spinach, which is a rich source of potassium, was used as the key ingredient to extract mixed-phase ferroelectric crystals of nitrite and nitrate derivatives (KNO2 + KNO3). The KNO3 phase was found to be dominant for higher pH values, as revealed by the x-ray diffraction patterns. The characteristic optical absorption spectra exhibited intra-band π-π* electronic transitions, whereas Fourier transform infrared spectra exhibited characteristic N-O stretching vibrations. Differential scanning calorimetry revealed a broad endothermic peak at ˜121.8 °C, highlighting a transition from phase II to I via phase III of KNO3. Obtaining nanoscale ferroelectrics via the adoption of green synthesis is economically viable for large-scale production and possible application in ferroelectric elements/devices.

Ferromagnetic superconductors: A vortex phase in ternary rare-earth compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuper, C.G.; Revzen, M.; Ron, A.

1980-06-09

It is shown that the generalized Ginzburg-Landau free-energy functional of Blount and Varma admits self-consistent solutions with quantized-flux vortices, magnetized in a region about the cores. There is a temperature range where the new phase has a lower free energy than either the pure superconducting or ferromagnetic phases; it represents true coexistence of ferromagnetism and superconductivity. The main features of the specific heat and magnetic properties of some rare-earth ternary compounds can be explained qualitatively.

Internal loading of an inhomogeneous compressible Earth with phase boundaries

NASA Technical Reports Server (NTRS)

Defraigne, P.; Dehant, V.; Wahr, J. M.

1996-01-01

The geoid and the boundary topography caused by mass loads inside the earth were estimated. It is shown that the estimates are affected by compressibility, by a radially varying density distribution, and by the presence of phase boundaries with density discontinuities. The geoid predicted in the chemical boundary case is 30 to 40 percent smaller than that predicted in the phase case. The effects of compressibility and radially varying density are likely to be small. The inner core-outer core topography for loading inside the mantle and for loading inside the inner core were computed.

Phase stable rare earth garnets

DOEpatents

Kuntz, Joshua D.; Cherepy, Nerine J.; Roberts, Jeffery J.; Payne, Stephen A.

2013-06-11

A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

Earth - South America (first frame of Earth Spin Movie)

NASA Technical Reports Server (NTRS)

1990-01-01

This color image of the Earth was obtained by Galileo at about 6:10 a.m. Pacific Standard Time on Dec. 11, 1990, when the spacecraft was about 1.3 million miles from the planet during the first of two Earth flybys on its way to Jupiter. The color composite used images taken through the red, green and violet filters. South America is near the center of the picture, and the white, sunlit continent of Antarctica is below. Picturesque weather fronts are visible in the South Atlantic, lower right. This is the first frame of the Galileo Earth spin movie, a 500- frame time-lapse motion picture showing a 25-hour period of Earth's rotation and atmospheric dynamics.

Herbal Earth

NASA Image and Video Library

2017-12-08

Subtle vegetation changes are visible in this year-long visualization. Large-scale patterns vary with seasons, but the local variations in green are also sensitive precipitation, drought and fire. High values of Normalized Difference Vegetation Index, or NDVI, represent dense green functioning vegetation and low NDVI values represent sparse green vegetation or vegetation under stress from limiting conditions, such as drought. The visualization was created from a year’s worth of data from April 2012 to April 2013. The information was sent back to Earth from the Visible-Infrared Imager/Radiometer Suite (VIIRS) instrument aboard the Suomi National Polar-orbiting Partnership or Suomi NPP satellite, a partnership between NASA and the National Oceanic and Atmospheric Administration, or NOAA. Credit: NASA/NOAA To read more go to: www.nasa.gov/mission_pages/NPP/news/vegetation.html NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Separation of rare earths from transition metals by liquid-liquid extraction from a molten salt hydrate to an ionic liquid phase.

PubMed

Rout, Alok; Binnemans, Koen

2014-02-28

The solvent extraction of trivalent rare-earth ions and their separation from divalent transition metal ions using molten salt hydrates as the feed phase and an undiluted fluorine-free ionic liquid as the extracting phase were investigated in detail. The extractant was tricaprylmethylammonium nitrate, [A336][NO3], and the hydrated melt was calcium nitrate tetrahydrate, Ca(NO3)2·4H2O. The extraction behavior of rare-earth ions was studied for solutions of individual elements, as well as for mixtures of rare earths in the hydrated melt. The influence of different extraction parameters was investigated: the initial metal loading in the feed phase, percentage of water in the feed solution, equilibration time, and the type of hydrated melt. The extraction of rare earths from Ca(NO3)2·4H2O was compared with extraction from CaCl2·4H2O by [A336][Cl] (Aliquat 336). The nitrate system was found to be the better one. The extraction and separation of rare earths from the transition metals nickel, cobalt and zinc were also investigated. Remarkably high separation factors of rare-earth ions over transition metal ions were observed for extraction from Ca(NO3)2·4H2O by the [A336][NO3] extracting phase. Furthermore, rare-earth ions could be separated efficiently from transition metal ions, even in melts with very high concentrations of transition metal ions. Rare-earth oxides could be directly dissolved in the Ca(NO3)2·4H2O phase in the presence of small amounts of Al(NO3)3·9H2O or concentrated nitric acid. The efficiency of extraction after dissolving the rare-earth oxides in the hydrated nitrate melt was identical to extraction from solutions with rare-earth nitrates dissolved in the molten phase. The stripping of the rare-earth ions from the loaded ionic liquid phase and the reuse of the recycled ionic liquid were also investigated in detail.

Near equality of ion phase space densities at earth, Jupiter, and Saturn

NASA Technical Reports Server (NTRS)

Cheng, A. F.; Krimigis, S. M.; Armstrong, T. P.

1985-01-01

Energetic-ion phase-space density profiles are strikingly similar in the inner magnetospheres of earth, Jupiter, and Saturn for ions of first adiabatic invariant near 100 MeV/G and small mirror latitudes. Losses occur inside L approximately equal to 7 for Jupiter and Saturn and inside L approximately equal to 5 at earth. At these L values there exist steep plasma-density gradients at all three planets, associated with the Io plasma torus at Jupiter, the Rhea-Dione-Tethys torus at Saturn, and the plasmasphere at earth. Measurements of ion flux-tube contents at Jupiter and Saturn by the low-energy charged-particle experiment show that these are similar (for O ions at L = 5-9) to those at earth (for protons at L = 2-6). Furthermore, the thermal-ion flux-tube contents from Voyager plasma-science data at Jupiter and Saturn are also very nearly equal, and again similar to those at earth, differing by less than a factor of 3 at the respective L values. The near equality of energetic and thermal ion flux-tube contents at earth, Jupiter, and Saturn suggests the possibility of strong physical analogies in the interaction between plasma and energetic particles at the plasma tori/plasma sheets of Jupiter and Saturn and the plasmasphere of earth.

Stability of the body-centred-cubic phase of iron in the Earth's inner core.

PubMed

Belonoshko, Anatoly B; Ahuja, Rajeev; Johansson, Börje

2003-08-28

Iron is thought to be the main constituent of the Earth's core, and considerable efforts have therefore been made to understand its properties at high pressure and temperature. While these efforts have expanded our knowledge of the iron phase diagram, there remain some significant inconsistencies, the most notable being the difference between the 'low' and 'high' melting curves. Here we report the results of molecular dynamics simulations of iron based on embedded atom models fitted to the results of two implementations of density functional theory. We tested two model approximations and found that both point to the stability of the body-centred-cubic (b.c.c.) iron phase at high temperature and pressure. Our calculated melting curve is in agreement with the 'high' melting curve, but our calculated phase boundary between the hexagonal close packed (h.c.p.) and b.c.c. iron phases is in good agreement with the 'low' melting curve. We suggest that the h.c.p.-b.c.c. transition was previously misinterpreted as a melting transition, similar to the case of xenon, and that the b.c.c. phase of iron is the stable phase in the Earth's inner core.

Optical Temperature Sensor Based on Infrared Excited Green Upconversion Emission in Hexagonal Phase NaLuF4:Yb3+/Er3+ Nanorods.

PubMed

Li, Dongyu; Tian, Linlin; Huang, Zhen; Shao, Lexi; Quan, Jun; Wang, Yuxiao

2016-04-01

Hexagonal phase NaLuF4:Yb3+/Er3+ nanorods were synthesized hydrothermally. An analysis of the intense green upconversion emissions at 525 nm and 550 nm in hexagonal phase NaLuF4:Yb3/+Er3+ nanorods under excitation power density of 4.2 W/cm2 available from a diode laser emitting at 976 nm, have been undertaken. Fluorescence intensity ratio (FIR) variation of temperature-sensitive green upconversion emissions at 525 nm and 550 nm in this material was recorded in the physiological range from 295 to 343 K. The maximum sensitivity derived from the FIR technique of the green upconversion emissions is approximately 0.0044 K-1. Experimental results implied that hexagonal phase NaLuF4:Yb3/+Er3+ nanorods was a potential candidate for optical temperature sensor.

Inquiry-Based Science and Technology Enrichment Program: Green Earth Enhanced with Inquiry and Technology

NASA Astrophysics Data System (ADS)

Kim, Hanna

2011-12-01

This study investigated the effectiveness of a guided inquiry integrated with technology, in terms of female middle-school students' attitudes toward science/scientists and content knowledge regarding selective science concepts (e.g., Greenhouse Effect, Air/Water Quality, Alternative Energy, and Human Health). Thirty-five female students who were entering eighth grade attended an intensive, 1-week Inquiry-Based Science and Technology Enrichment Program which used a main theme, "Green Earth Enhanced with Inquiry and Technology." We used pre- and post-attitude surveys, pre- and post-science content knowledge tests, and selective interviews to collect data and measure changes in students' attitudes and content knowledge. The study results indicated that at the post-intervention measures, participants significantly improved their attitudes toward science and science-related careers and increased their content knowledge of selected science concepts ( p < .05).

Compositional and phase relations among rare earth element minerals

NASA Technical Reports Server (NTRS)

Burt, D. M.

1990-01-01

This paper discusses the compositional and phase relationships among minerals in which rare earth elements (REE) occur as essential constituents (e.g., bastnaesite, monazite, xenotime, aeschynite, allanite). Particular consideration is given to the vector representation of complex coupled substitutions in selected REE-bearing minerals and to the REE partitioning between minerals as related to the acid-base tendencies and mineral stabilities. It is shown that the treatment of coupled substitutions as vector quantities facilitates graphical representation of mineral composition spaces.

Phase conjugate Twyman-Green interferometer for testing spherical surfaces and lenses and for measuring refractive indices of liquids or solid transparent materials

NASA Technical Reports Server (NTRS)

Shukla, R. P.; Dokhanian, Mostafa; Venkateswarlu, Putcha; George, M. C.

1990-01-01

The present paper describes an application of a phase conjugate Twyman-Green interferometer using barium titanate as a self-pumping mirror for testing optical components like concave and convex spherical mirrors and lenses. The aberrations introduced by the beam splitter while testing concave or convex spherical mirrors of large aperture are automatically eliminated due to self-focussing property of the phase conjugate mirror. There is no necessity for a good spherical surface as a reference surface unlike in classical Twyman-Green interferometer or Williams interferometer. The phase conjugate Twyman Green interferometer with a divergent illumination can be used as a test plate for checking spherical surfaces. A nondestructive technique for measuring the refractive indices of a Fabry Perot etalon by using a phase conjugate interferometer is also suggested. The interferometer is found to be useful for measuring the refractive indices of liquids and solid transparent materials with an accuracy of the order of + or - 0.0004.

Green synthesis of a typical chiral stationary phase of cellulose-tris(3, 5-dimethylphenylcarbamate)

PubMed Central

2013-01-01

Background At present, the study on the homogeneous-phase derivatization of cellulose in ionic liquid is mainly focused on its acetylation. To the best of our knowledge, there has been no such report on the preparation of cellulose-tris(3,5-dimethylphenylcarbamate) (CDMPC) with ionic liquid 1-allyl-3-methyl-imidazolium chloride (AmimCl) so far. Results With ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl) as a reaction solvent, cellulose-tris(3,5-dimethylphenylcarbamate) (CDMPC) was synthesized by the reaction of 3,5-dimethylphenyl isocyanate and soluble microcrystalline cellulose in a homogeneous phase. The synthesized CDMPC was then coated onto the surfaces of aminopropyl silica gel to prepare a chiral stationary phase (CSP). The prepared CSP was successfully used in chiral separation of seven racemic pesticides by high performance liquid chromatography (HPLC). Good chiral separation was obtained using n-hexane and different modifiers as the mobile phases under the optimal percentage and column temperature, with the resolution of metalaxyl, diniconazole, flutriafol, paclobutrazol, hexaconazole, myclobutanil and hexythiazox of 1.73, 1.56, 1.26, 1.00, 1.18, 1.14 and 1.51, respectively. The experimental results suggested it was a good choice using a green solvent of AmimCl for cellulose functionalization. Conclusion CDMPC was successfully synthesized as the chiral selector by reacting 3, 5-dimethylphenyl isocyanate with dissolved microcrystalline cellulose in a green ionic liquid of AmimCl. PMID:23890199

Metabolic effects of green tea and of phases of weight loss.

PubMed

Diepvens, K; Kovacs, E M R; Vogels, N; Westerterp-Plantenga, M S

2006-01-30

The effect of ingestion of green tea (GT) extract along with a low-energy diet (LED) on health-related blood parameters, and the relationships among changes in metabolic parameters and phases of weight loss were assessed. A double-blind, placebo-controlled, parallel design was used. 46 female subjects (BMI 27.7+/-1.8 kg/m(2)) were fed in energy balance from days 1 to 3, followed by a LED with GT (n=23) or placebo (PLAC, n=23) from days 4 to 87. The LED-period consisted of a phase 1 of 4 weeks (days 4-32) followed by a phase 2 of 8 weeks (days 32-87). Body composition and fasting blood samples were determined on days 4, 32 and 87. No significant differences were observed between the blood parameters of the PLAC and GT group. In phase 1 compared to phase 2 the rate of weight loss was 0.09+/-0.05 kg/day vs. 0.03+/-0.03 kg/day (p<0.001); Fat free mass (FFM) was 21% of weight loss in phase 1 vs. 7% in phase 2 (ns). Surprisingly, favourable changes in free fatty acids, triacylglycerol, beta-hydroxybutyrate, glucose and total cholesterol in phase 1 were reversed in phase 2 (p<0.01). Taken together, GT supplementation during a LED had no effect on health-related blood parameters. Initial improvements in several blood measures at day 32 were reversed by day 87, despite continued weight loss. Modest weight loss improved HDL cholesterol and blood pressure.

Earth - South America First Frame of Earth Spin Movie

NASA Image and Video Library

1996-01-29

This color image of the Earth was obtained by NASA's Galileo at about 6:10 a.m. Pacific Standard Time on Dec. 11, 1990, when the spacecraft was about 1.3 million miles from the planet during the first of two Earth flybys on its way to Jupiter. The color composite used images taken through the red, green and violet filters. South America is near the center of the picture, and the white, sunlit continent of Antarctica is below. Picturesque weather fronts are visible in the South Atlantic, lower right. This is the first frame of the Galileo Earth spin movie, a 500- frame time-lapse motion picture showing a 25-hour period of Earth's rotation and atmospheric dynamics. A movie is availalble at http://photojournal.jpl.nasa.gov/catalog/PIA00114

Development of a passive phase separator for space and earth applications

PubMed Central

Wu, Xiongjun; Loraine, Greg; Hsiao, Chao-Tsung; Chahine, Georges L.

2018-01-01

The limited amount of liquids and gases that can be carried to space makes it imperative to recycle and reuse these fluids for extended human operations. During recycling processes gas and liquid phases are often intermixed. In the absence of gravity, separating gases from liquids is challenging due to the absence of buoyancy. This paper describes development of a passive phase separator that is capable of efficiently and reliably separating gas–liquid mixtures of both high and low void fractions in a wide range of flow rates that is applicable to for both space and earth applications. PMID:29628785

GreenView and GreenLand Applications Development on SEE-GRID Infrastructure

NASA Astrophysics Data System (ADS)

Mihon, Danut; Bacu, Victor; Gorgan, Dorian; Mészáros, Róbert; Gelybó, Györgyi; Stefanut, Teodor

2010-05-01

The GreenView and GreenLand applications [1] have been developed through the SEE-GRID-SCI (SEE-GRID eInfrastructure for regional eScience) FP7 project co-funded by the European Commission [2]. The development of environment applications is a challenge for Grid technologies and software development methodologies. This presentation exemplifies the development of the GreenView and GreenLand applications over the SEE-GRID infrastructure by the Grid Application Development Methodology [3]. Today's environmental applications are used in vary domains of Earth Science such as meteorology, ground and atmospheric pollution, ground metal detection or weather prediction. These applications run on satellite images (e.g. Landsat, MERIS, MODIS, etc.) and the accuracy of output results depends mostly of the quality of these images. The main drawback of such environmental applications regards the need of computation power and storage power (some images are almost 1GB in size), in order to process such a large data volume. Actually, almost applications requiring high computation resources have approached the migration onto the Grid infrastructure. This infrastructure offers the computing power by running the atomic application components on different Grid nodes in sequential or parallel mode. The middleware used between the Grid infrastructure and client applications is ESIP (Environment Oriented Satellite Image Processing Platform), which is based on gProcess platform [4]. In its current format, gProcess is used for launching new processes on the Grid nodes, but also for monitoring the execution status of these processes. This presentation highlights two case studies of Grid based environmental applications, GreenView and GreenLand [5]. GreenView is used in correlation with MODIS (Moderate Resolution Imaging Spectroradiometer) satellite images and meteorological datasets, in order to produce pseudo colored temperature and vegetation maps for different geographical CEE (Central

Green noise wall construction and evaluation.

DOT National Transportation Integrated Search

2011-09-01

This report details the research performed under Phase I of a research study titled Green Noise Wall Construction and Evaluation that looks into the feasibility of using green noise barriers as a noise mitigation option in Ohio. This phase incl...

Interaction of Environmental Moisture with Powdered Green Tea Formulations: Relationship between Catechin Stability and Moisture-Induced Phase Transformations

PubMed Central

Ortiz, Julieta; Kestur, Umesh S.; Taylor, Lynne S.; Mauer, Lisa J.

2009-01-01

This study investigated the effect of phase transformations of amorphous and deliquescent ingredients on catechin stability in green tea powder formulations. Blends of amorphous green tea and crystalline sucrose, citric acid, and/or ascorbic acid were analyzed by X-ray powder diffraction (XRPD), differential scanning calorimetry (DSC), dynamic water vapor sorption, water activity measurements, and high-performance liquid chromatography (HPLC) after storage for up to 12 weeks at 0–75% relative humidity (RH) and 22 °C. The glass transition temperature (Tg) of green tea was reduced to below room temperature (<22 °C) at 68% RH. Dissolution of deliquescent ingredients commenced at RH values below deliquescence points in blends with amorphous green tea, and these blends had greater water uptake than predicted by an additive model of individual ingredient moisture sorption. Catechin degradation was affected by Tg of green tea powder and both dissolution and deliquescence of citric and ascorbic acids. PMID:19489621

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K.

2008-07-01

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalizationmore » in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)« less

Earth Observation

NASA Image and Video Library

2014-09-01

Earth Observation taken during a night pass by the Expedition 40 crew aboard the International Space Station (ISS). Folder lists this as: New Zealand Aurora night pass. Docked Soyuz and Progress spacecraft are visible. On crewmember's Flickr page - The Moon, about to dive into a glowing ocean of green᥿9.

The cloud-phase feedback in the Super-parameterized Community Earth System Model

NASA Astrophysics Data System (ADS)

Burt, M. A.; Randall, D. A.

2016-12-01

Recent comparisons of observations and climate model simulations by I. Tan and colleagues have suggested that the Wegener-Bergeron-Findeisen (WBF) process tends to be too active in climate models, making too much cloud ice, and resulting in an exaggerated negative cloud-phase feedback on climate change. We explore the WBF process and its effect on shortwave cloud forcing in present-day and future climate simulations with the Community Earth System Model, and its super-parameterized counterpart. Results show that SP-CESM has much less cloud ice and a weaker cloud-phase feedback than CESM.

Preparation, characterization and application of Saussurea tridactyla Sch-Bip as green adsorbents for preconcentration of rare earth elements in environmental water samples

NASA Astrophysics Data System (ADS)

Zhang, Qiangying; He, Man; Chen, Beibei; Hu, Bin

2016-07-01

This paper deals with preparation, characterization and application of the Saussurea tridactyla Sch-Bip (STSB) as a new green adsorbent for separation of matrix elements and preconcentration of rare earth elements (REEs) in environmental water samples. The pretreated STSB adsorbent with 2 mol L- 1 NaOH is characterized with higher surface area and adsorption capacities in comparison with a raw STSB material. The new adsorbent was used for the development of on-line solid phase extraction (SPE) for the determination of REEs by radial viewing 27 MHz inductively coupled plasma optical emission spectrometry (ICP-OES). Various parameters affecting the adsorption/desorption procedure were optimized. The adsorption capacities for the STSB were found to be 62.2 (Y)-153 mg g- 1 (Tm). Under the optimized conditions, the limits of detection (LODs, 3σ) for REEs were in the range of 0.06 (Yb)-8.77 (Sm) ng mL- 1. The relative standard deviations (RSDs) for 7 replicate determinations of target REEs at low concentration level ranged from 2.4 (Yb) to 8.9 (Sm)%. The adsorption isotherm fitted Langmuir model and the adsorption kinetics fitted well with both Pseudo-first order and Pseudo-second order models. The predominant adsorption mechanism is ion exchange. The STSB pretreated with 2 mol L- 1 NaOH has been demonstrated to be low cost, green and environment friendly adsorbent, featuring with high adsorption capacity, wide pH range, and fast adsorption/desorption kinetics for target REEs with long lifetime. The proposed method was applied to the determination of REEs in East Lake, Yangtze River and rain water samples.

Single-Phase Rare-Earth Oxide/Aluminum Oxide Glasses

NASA Technical Reports Server (NTRS)

Weber, J. K. Richard; Abadie, John G.; Hixson, April D.; Nordine, Paul C.

2006-01-01

Glasses that comprise rare-earth oxides and aluminum oxide plus, optionally, lesser amounts of other oxides, have been invented. The other oxide(s) can include SiO2, B2O3, GeO2, and/or any of a variety of glass-forming oxides that have been used heretofore in making a variety of common and specialty glasses. The glasses of the invention can be manufactured in bulk single-phase forms to ensure near uniformity in optical and mechanical characteristics, as needed for such devices as optical amplifiers, lasers, and optical waveguides (including optical fibers). These glasses can also be formulated to have high indices of refraction, as needed in some of such devices.

Subsonic Ultra Green Aircraft Research Phase II: N+4 Advanced Concept Development

NASA Technical Reports Server (NTRS)

Bradley, Marty K.; Droney, Christopher K.

2012-01-01

This final report documents the work of the Boeing Subsonic Ultra Green Aircraft Research (SUGAR) team on Task 1 of the Phase II effort. The team consisted of Boeing Research and Technology, Boeing Commercial Airplanes, General Electric, and Georgia Tech. Using a quantitative workshop process, the following technologies, appropriate to aircraft operational in the N+4 2040 timeframe, were identified: Liquefied Natural Gas (LNG), Hydrogen, fuel cell hybrids, battery electric hybrids, Low Energy Nuclear (LENR), boundary layer ingestion propulsion (BLI), unducted fans and advanced propellers, and combinations. Technology development plans were developed.

A green separation strategy for neodymium (III) from cobalt (II) and nickel (II) using an ionic liquid-based aqueous two-phase system.

PubMed

Chen, Yuehua; Wang, Huiyong; Pei, Yuanchao; Wang, Jianji

2018-05-15

It is significant to develop sustainable strategies for the selective separation of rare earth from transition metals from fundamental and practical viewpoint. In this work, an environmentally friendly solvent extraction approach has been developed to selectively separate neodymium (III) from cobalt (II) and nickel (II) by using an ionic liquid-based aqueous two phase system (IL-ATPS). For this purpose, a hydrophilic ionic liquid (IL) tetrabutylphosphonate nitrate ([P 4444 ][NO 3 ]) was prepared and used for the formation of an ATPS with NaNO 3 . Binodal curves of the ATPSs have been determined for the design of extraction process. The extraction parameters such as contact time, aqueous phase pH, content of phase-formation components of NaNO 3 and the ionic liquid have been investigated systematically. It is shown that under optimal conditions, the extraction efficiency of neodymium (III) is as high as 99.7%, and neodymium (III) can be selectively separated from cobalt (II) and nickel (II) with a separation factor of 10 3 . After extraction, neodymium (III) can be stripped from the IL-rich phase by using dilute aqueous sodium oxalate, and the ILs can be quantitatively recovered and reused in the next extraction process. Since [P 4444 ][NO 3 ] works as one of the components of the ATPS and the extractant for the neodymium, no organic diluent, extra etractant and fluorinated ILs are used in the separation process. Thus, the strategy described here shows potential in green separation of neodymium from cobalt and nickel by using simple IL-based aqueous two-phase system. Copyright © 2018 Elsevier B.V. All rights reserved.

PSEUDO-BINARY SYSTEMS INVOLVING RARE EARTH LAVES PHASES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wernick, J.H.; Haszko, S.E.; Dorsi, D.

1962-06-01

The phase relations in a number of pseudo-binary systems involving rare earth Laves phases were determined. Complete series of cubic solid-solutions occur in the DyMn/sub 2/HoMn/sub 2/, HoMn/sub 2/-HoFe/sub 2/, DyMn/sub 2/-DyFe/ sub 2/, HoMn/sub 2/-HoAl/ sub 2/, TbMn/sub 2/TbAl/sub 2/, and DyMn/sub 2/-DyAl/ sub 2/ pseudobinary systems. Deviations from linearity in the lattice constants with composition occur in all these systems. Complete series of cubic solidsolutions also exist in the GdAl/sub 2/-ErAl/sub 2/, GdAl/sub 2/-PrAl/sub 2/ , GdAl/sub 2/-NdAl/sub 2/, GdAl/sub 2/-DyAl/sub 2/, TbAl/sub 2/-NdAl/sub 2/, and T bAl/sub 2/-DyAl/sub 2/ systems. For these systems, no deviation from linearitymore » occurs in the lattice constants. For the DyFe/sub 2/-DyAl/sub 2/ and DyCo/sub 2/- DyAl/sub 2/ systems, two new ternary phases, DyFeAl and DyCoAl, form and have the MgZn/sub 2/ structure. Their structures were determined from x-ray powder data only. The electronic state giving rise to the formation of these ternary phases is discussed qualitatively. For the DyMn/sub 2/TmMn/sub 2/ system, the range of composition in which the cubic MgCu/sub 2/ and hexagonal MgZn/sub 2/ structures exist are reported. No complete series of solid solutions or intermediate phases are formed in the DyNi/sub 2/-DyAl/sub 2/ system. (auth)« less

Crystal structure, equation of state, and elasticity of phase H (MgSiO4H2) at Earth's lower mantle pressures.

PubMed

Tsuchiya, Jun; Mookherjee, Mainak

2015-10-23

Dense hydrous magnesium silicate (DHMS) phases play a crucial role in transporting water in to the Earth's interior. A newly discovered DHMS, phase H (MgSiO4H2), is stable at Earth's lower mantle, i.e., at pressures greater than 30 GPa. Here we report the crystal structure and elasticity of phase H and its evolution upon compression. Using first principles simulations, we have explored the relative energetics of the candidate crystal structures with ordered and disordered configurations of magnesium and silicon atoms in the octahedral sites. At conditions relevant to Earth's lower mantle, it is likely that phase H is able to incorporate a significant amount of aluminum, which may enhance the thermodynamic stability of phase H. The sound wave velocities of phase H are ~2-4% smaller than those of isostructural δ-AlOOH. The shear wave impedance contrast due to the transformation of phase D to a mixture of phase H and stishovite at pressures relevant to the upper part of the lower mantle could partly explain the geophysical observations. The calculated elastic wave velocities and anisotropies indicate that phase H can be a source of significant seismic anisotropy in the lower mantle.

Green Chemistry Challenge: 2017 Academic Award

EPA Pesticide Factsheets

Green Chemistry Challenge 2017 award winner, Professor Schelter, developed a new, targeted approach for separating mixtures of rare earth metals obtained from consumer waste streams comprising mixtures of Nd/Dy and Eu/Y

Strain-induced modification of magnetic structure and new magnetic phases in rare-earth epitaxial films

NASA Astrophysics Data System (ADS)

Dufour, C.; Dumesnil, K.; Mangin, Ph

2006-07-01

Rare earths exhibit complex magnetic phase diagrams resulting from the competition between various contributions to the magnetic energy: exchange, anisotropy and magnetostriction. The epitaxy of a rare-earth film on a substrate induces (i) a clamping to the substrate and (ii) pseudomorphic strains. Both these effects are shown to lead to modifications of the magnetic properties in (0 0 1)Dy, (0 0 1)Tb and (1 1 0)Eu films. In Dy and Tb films, spectacular variations of the Curie temperature have been evidenced. Additionally, Tb films exhibit a new large wavelength magnetic modulation. In Eu films, one of the helical magnetic domains disappears at low temperature whereas the propagation vectors of the other helices are tilted. The link between structural and magnetic properties is underlined via magnetoelastic models. Moreover, molecular beam epitaxy permits the growth of Sm in a metastable dhcp phase. The magnetic structure of dhcp Sm has been elucidated for the first time. In this review, neutron scattering is shown to be a powerful technique to reveal the magnetic structures of rare-earth films.

Green chromatography separation of analytes of greatly differing properties using a polyethylene glycol stationary phase and a low-toxic water-based mobile phase.

PubMed

Šatínský, Dalibor; Brabcová, Ivana; Maroušková, Alena; Chocholouš, Petr; Solich, Petr

2013-07-01

A simple, rapid, and environmentally friendly HPLC method was developed and validated for the separation of four compounds (4-aminophenol, caffeine, paracetamol, and propyphenazone) with different chemical properties. A "green" mobile phase, employing water as the major eluent, was proposed and applied to the separation of analytes with different polarity on polyethylene glycol (PEG) stationary phase. The chromatography separation of all compounds and internal standard benzoic acid was performed using isocratic elution with a low-toxicity mobile phase consisting of 0.04% (v/v) triethylamine and water. HPLC separation was carried out using a PEG reversed-phase stationary phase Supelco Discovery HS PEG column (15 × 4 mm; particle size 3 μm) at a temperature of 30 °C and flow rate at 1.0 mL min(-1). The UV detector was set at 210 nm. In this study, a PEG stationary phase was shown to be suitable for the efficient isocratic separation of compounds that differ widely in hydrophobicity and acid-base properties, particularly 4-aminophenol (log P, 0.30), caffeine (log P, -0.25), and propyphenazone (log P, 2.27). A polar PEG stationary phase provided specific selectivity which allowed traditional chromatographic problems related to the separation of analytes with different polarities to be solved. The retention properties of the group of structurally similar substances (aromatic amines, phenolic compounds, and xanthine derivatives) were tested with different mobile phases. The proposed green chromatography method was successfully applied to the analysis of active substances and one degradation impurity (4-aminophenol) in commercial preparation. Under the optimum chromatographic conditions, standard calibration was carried out with good linearity correlation coefficients for all compounds in the range (0.99914-0.99997, n = 6) between the peak areas and concentration of compounds. Recovery of the sample preparation was in the range 100 ± 5% for all compounds

A Comprehensive Model of the Near-Earth Magnetic Field. Phase 3

NASA Technical Reports Server (NTRS)

Sabaka, Terence J.; Olsen, Nils; Langel, Robert A.

2000-01-01

The near-Earth magnetic field is due to sources in Earth's core, ionosphere, magnetosphere, lithosphere, and from coupling currents between ionosphere and magnetosphere and between hemispheres. Traditionally, the main field (low degree internal field) and magnetospheric field have been modeled simultaneously, and fields from other sources modeled separately. Such a scheme, however, can introduce spurious features. A new model, designated CMP3 (Comprehensive Model: Phase 3), has been derived from quiet-time Magsat and POGO satellite measurements and observatory hourly and annual means measurements as part of an effort to coestimate fields from all of these sources. This model represents a significant advancement in the treatment of the aforementioned field sources over previous attempts, and includes an accounting for main field influences on the magnetosphere, main field and solar activity influences on the ionosphere, seasonal influences on the coupling currents, a priori characterization of ionospheric and magnetospheric influence on Earth-induced fields, and an explicit parameterization and estimation of the lithospheric field. The result of this effort is a model whose fits to the data are generally superior to previous models and whose parameter states for the various constituent sources are very reasonable.

Sintered rare earth-iron Laves phase magnetostrictive alloy product and preparation thereof

DOEpatents

Malekzadeh, Manoochehr; Pickus, Milton R.

1979-01-01

A sintered rare earth-iron Laves phase magnetostrictive alloy product characterized by a grain oriented morphology. The grain oriented morphology is obtained by magnetically aligning powder particles of the magnetostrictive alloy prior to sintering. Specifically disclosed are grain oriented sintered compacts of Tb.sub.x Dy.sub.1-x Fe.sub.2 and their method of preparation. The present sintered products have enhanced magnetostrictive properties.

[Fe₃O₄-β-Cyclodextrin Polymer Nano Composites Solid-Phase Extraction-UV-Vis Spectrophotometry for Separation Analysis Malachite Green].

PubMed

Feng, Gang; Ping, Wen-hui; Zhu, Xia-shi

2016-02-01

In this paper, carboxymethyl-hydroxypropyl-β-cyclodextrin polymer modified magnetic particles Fe₃O₄ (CM-HP-β-CD- CP-MNPs) were prepared and applied to magnetic solid phase extraction of malachite green combined with UV-Visible spectrom- etry detection. The synthesized magnetic particles were characterized by element analysis, Fourier transform infrared spectra and transmission electron microscopy. Several variables affecting the extraction and desorption of malachite green such as pH, the amount of adsorbent, the type and volume of eluent, extraction and desorption time, and temperature were investigated. Under the optimum conditions, malachite green could be adsorbed by CM-HP-β-CDCP-MNPs (RE% = 92), and elution by C₂H₅OH (EE% = 90). the preconcentration factor of the proposed method was approximately 7.5, the CM-HP-β-CDCP-MNPs could be used repeatedly for 5 times and offered better recovery. The linear range and detection limit (DL) were found to be 0.08~8.00 µg · mL⁻¹ and 5.6 ng · mL⁻¹ respectively. This technique had been successfully applied to the determination of malachite green in real samples. The inclusion interaction of CM-HP--CDCP-MNPs with malachite green was studied through FTIR.

Proposal for extension of ORSA to include phasing in to prove successive encounters of an asteroid between Earth and Mars

NASA Astrophysics Data System (ADS)

Jolitz, Benjamin

Ben Jolitz 2/6/10 Proposal for extension of ORSA to include phasing in to prove successive encounters of an asteroid between Earth and Mars Phasing is the act of changing the phase angle between two sinusoidal functions. In the case of orbits, which are ellipses drawn by sinusoidal functions, phasing is the act of matching one orbit to another. Finding the phasing parameters of a captured asteroid, a non-Keplarian object, in a resonant bi-elliptic orbit and simulation thereof is rather difficult without specialized and esoteric applications. However, open source in the last ten years has made incredible advance-ments, and some projects originally designed for orbital reconstruction have been released to the public on an AS IS basis; one such project is ORSA -Orbital Reconstruction, Simulation, Analysis. ORSA, however, does not have methods for evaluating the relative changes to a phase angle of a bi-elliptic orbit in a recursive manner for successive encounters. For years, space shuttles and other celestial transport vessels have been faced with the difficulty of docking with the International Space Station, a task which involves matching the craft to the unique elliptical orbit of the ISS such that the shuttle will meet the ISS with the appropriate orbital parameters. However, calculation of such requires consideration of only the Earth and it's effect on rather small, man-made objects. In electrical engineering, the concept of a phase lock loop is used to match the frequency and phase of a controlled oscillator with a given set of input signals. In our test case, we wish compute the successive bi-elliptic half orbits of a captured asteroid that traverses between Earth and Mars using gravitational interactions with the intent of computing the relative phase angle between the desired half orbit and current orbit such that a timed encounter with Earth or Mars is possible. The goal of this proposal is to extend ORSA to maintain relative phase angle between bi

DNA Damage during G2 Phase Does Not Affect Cell Cycle Progression of the Green Alga Scenedesmus quadricauda

PubMed Central

Vítová, Milada; Bišová, Kateřina; Zachleder, Vilém

2011-01-01

DNA damage is a threat to genomic integrity in all living organisms. Plants and green algae are particularly susceptible to DNA damage especially that caused by UV light, due to their light dependency for photosynthesis. For survival of a plant, and other eukaryotic cells, it is essential for an organism to continuously check the integrity of its genetic material and, when damaged, to repair it immediately. Cells therefore utilize a DNA damage response pathway that is responsible for sensing, reacting to and repairing damaged DNA. We have studied the effect of 5-fluorodeoxyuridine, zeocin, caffeine and combinations of these on the cell cycle of the green alga Scenedesmus quadricauda. The cells delayed S phase and underwent a permanent G2 phase block if DNA metabolism was affected prior to S phase; the G2 phase block imposed by zeocin was partially abolished by caffeine. No cell cycle block was observed if the treatment with zeocin occurred in G2 phase and the cells divided normally. CDKA and CDKB kinases regulate mitosis in S. quadricauda; their kinase activities were inhibited by Wee1. CDKA, CDKB protein levels were stabilized in the presence of zeocin. In contrast, the protein level of Wee1 was unaffected by DNA perturbing treatments. Wee1 therefore does not appear to be involved in the DNA damage response in S. quadricauda. Our results imply a specific reaction to DNA damage in S. quadricauda, with no cell cycle arrest, after experiencing DNA damage during G2 phase. PMID:21603605

Tidal Amplitude Delta Factors and Phase Shifts for an Oceanic Earth

NASA Astrophysics Data System (ADS)

Spiridonov, E. A.

2017-12-01

M.S. Molodenskiy's problem, which describes the state of an elastic self-gravitating compressible sphere, is generalized to the case of a biaxial hydrostatically equilibrium rotating elliptical inelastic shell. The system of sixth-order equations is supplemented with corrections due to the relative and Coriolis accelerations. The ordinary and load Love numbers of degree 2 are calculated with allowance for their latitude dependence and dissipation for different models of the Earth's structure (the AK135, IASP91, and PREM models). The problem is solved by Love's method. The theoretical amplitude delta factors and phase shifts of second-order tidal waves for an oceanic Earth are compared with their most recent empirical counterparts obtained by the GGP network superconducting gravimeters. In particular, it is shown that a good matching (up to the fourth decimal place) of the theoretical and observed amplitude factors of semidiurnal tides does not require the application of the nonhydrostatic theory.

Phased array feed design technology for Large Aperture Microwave Radiometer (LAMR) Earth observations

NASA Technical Reports Server (NTRS)

Schuman, H. K.

1992-01-01

An assessment of the potential and limitations of phased array antennas in space-based geophysical precision radiometry is described. Mathematical models exhibiting the dependence of system and scene temperatures and system sensitivity on phased array antenna parameters and components such as phase shifters and low noise amplifiers (LNA) are developed. Emphasis is given to minimum noise temperature designs wherein the LNA's are located at the array level, one per element or subarray. Two types of combiners are considered: array lenses (space feeds) and corporate networks. The result of a survey of suitable components and devices is described. The data obtained from that survey are used in conjunction with the mathematical models to yield an assessment of effective array antenna noise temperature for representative geostationary and low Earth orbit systems. Practical methods of calibrating a space-based, phased array radiometer are briefly addressed as well.

A Deeper Shade of Green

ERIC Educational Resources Information Center

Schachter, Ron

2009-01-01

For many schools, "Going Green" once meant turning out the lights after leaving the classroom, filling the recycle bins, and celebrating Earth Day. Not anymore. Although such activities remain staples of environmentally conscious school systems, that consciousness has exploded in an era of high energy prices, global warming threats, and…

Application of solid phase extraction procedures for rare earth elements determination in environmental samples.

PubMed

Pyrzynska, Krystyna; Kubiak, Anna; Wysocka, Irena

2016-07-01

Determination of rare earth elements in environmental samples requires often pre-concentration and separation step due to a low metal content and high concentration of the interfering matrix components. A solid phase extraction technique with different kind of solid sorbents offers a high enrichment factor, rapid phase separation and the possibility of its combination with various detection techniques used either in on-line or off-line mode. The recent developments in this area published over the last five years are presented and discussed in this paper. Copyright © 2016 Elsevier B.V. All rights reserved.

Intermittent nature of solar wind turbulence near the Earth's bow shock: phase coherence and non-Gaussianity.

PubMed

Koga, D; Chian, A C-L; Miranda, R A; Rempel, E L

2007-04-01

The link between phase coherence and non-Gaussian statistics is investigated using magnetic field data observed in the solar wind turbulence near the Earth's bow shock. The phase coherence index Cphi, which characterizes the degree of phase correlation (i.e., nonlinear wave-wave interactions) among scales, displays a behavior similar to kurtosis and reflects a departure from Gaussianity in the probability density functions of magnetic field fluctuations. This demonstrates that nonlinear interactions among scales are the origin of intermittency in the magnetic field turbulence.

Fabrication and secondary-phase crystallization of rare-earth disilicate-silicon nitride ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cinibulk, M.K.; Thomas, G.; Johnson, S.M.

1992-08-01

In this paper, the fabrication and intergranular-phase devitrification of silicon nitride densified with rare-earth (RE) oxide additives is investigated. The additions of the oxides of Sm, Gd, Dy, Er, and Yb, having high melting points and behaving similarly to Y[sub 2]O[sub 3], were compositionally controlled to tailor a microstructure with a crystalline secondary phase of RE[sub 2]Si[sub 2]O[sub 7]. The lanthanide oxides were found to be ass effective as Y[sub 2]O[sub 3] in densifying Si[sub 3]N[sub 4], resulting in identical microstructures and densities of 98-99% of theoretical density. The crystallization behavior of all six disilicates was similar, characterized by amore » limited nucleation and rapid growth mechanism resulting in large single crystals. Complete crystallization of the intergranular phase was obtained with the exception of a thin residual amorphous film which was observed at interfaces and believed to be rich in impurities, the cause of incomplete devitrification.« less

Mesoporous mixed-phase Ga{sub 2}O{sub 3}: Green synthesis and enhanced photocatalytic activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Jin; The Key Laboratory of Rare Earth Functional Materials and Applications, Zhoukou Normal University, Zhoukou 466001; Zhang, Gaoke, E-mail: gkzhang@whut.edu.cn

2015-08-15

Highlights: • Mixed-phase Ga{sub 2}O{sub 3} was synthesized by a facile and green method. • Mixed-phase Ga{sub 2}O{sub 3} exhibited good photocatalytic activity and stability. • The reactive species in the photocatalytic process were investigated. - Abstract: Mesoporous mixed-phase Ga{sub 2}O{sub 3} was synthesized by calcining the GaOOH precursor. The composition, crystal phase and microstructures of Ga{sub 2}O{sub 3} were characterized in detail. The phase composition of the as-prepared Ga{sub 2}O{sub 3} depended on the calcination temperature and the mixed-phase Ga{sub 2}O{sub 3} was obtained at 600–700 °C. As compared to the pure-phase α-Ga{sub 2}O{sub 3} and β-Ga{sub 2}O{sub 3},more » the mixed-phase Ga{sub 2}O{sub 3} exhibited an enhanced photocatalytic property for the degradation of metronidazole solution. The heterojunction in the mixed-phase Ga{sub 2}O{sub 3} was beneficial to the separation of photogenerated electrons and holes. Moreover, the mixed-phase Ga{sub 2}O{sub 3} possessed mesopore structure, which increased more reaction sites and was in favor of the contact of metronidazole molecules with reaction sites. The recycling experiments show that the mixed-phase Ga{sub 2}O{sub 3} has good stability and can be separated easily from the reaction system.« less

Earth and Its Moon, as Seen From Mars

NASA Image and Video Library

2017-01-06

This composite image of Earth and its moon, as seen from Mars, combines the best Earth image with the best moon image from four sets of images acquired on Nov. 20, 2016, by the High Resolution Imaging Science Experiment (HiRISE) camera on NASA's Mars Reconnaissance Orbiter. Each was separately processed prior to combining them so that the moon is bright enough to see. The moon is much darker than Earth and would barely be visible at the same brightness scale as Earth. The combined view retains the correct sizes and positions of the two bodies relative to each other. HiRISE takes images in three wavelength bands: infrared, red, and blue-green. These are displayed here as red, green, and blue, respectively. This is similar to Landsat images in which vegetation appears red. The reddish feature in the middle of the Earth image is Australia. Southeast Asia appears as the reddish area (due to vegetation) near the top; Antarctica is the bright blob at bottom-left. Other bright areas are clouds. These images were acquired for calibration of HiRISE data, since the spectral reflectance of the Moon's near side is very well known. When the component images were taken, Mars was about 127 million miles (205 million kilometers) from Earth. http://photojournal.jpl.nasa.gov/catalog/PIA21260

An Analysis of Green Propulsion Applied to NASA Missions

NASA Technical Reports Server (NTRS)

Cardiff, Eric H.; Mulkey, Henry W.; Baca, Caitlin E.

2014-01-01

The advantages of green propulsion for five mission classes are examined, including a Low Earth Orbit (LEO) mission (GPM), a Geosynchronous Earth Orbit (GEO) mission (SDO), a High Earth Orbit (HEO) mission (MMS), a lunar mission (LRO), and a planetary mission (MAVEN). The propellant mass benefits are considered for all five missions, as well as the effects on the tanks, propellant loading, thruster throughput, thermal considerations, and range requirements for both the AF-M315E and LMP-103S propellants.

Towards green loyalty: the influences of green perceived risk, green image, green trust and green satisfaction

NASA Astrophysics Data System (ADS)

Chrisjatmiko, K.

2018-01-01

The paper aims to present a comprehensive framework for the influences of green perceived risk, green image, green trust and green satisfaction to green loyalty. The paper also seeks to account explicitly for the differences in green perceived risk, green image, green trust, green satisfaction and green loyalty found among green products customers. Data were obtained from 155 green products customers. Structural equation modeling was used in order to test the proposed hypotheses. The findings show that green image, green trust and green satisfaction has positive effects to green loyalty. But green perceived risk has negative effects to green image, green trust and green satisfaction. However, green perceived risk, green image, green trust and green satisfaction also seems to be a good device to gain green products customers from competitors. The contributions of the paper are, firstly, a more complete framework of the influences of green perceived risk, green image, green trust and green satisfaction to green loyalty analyses simultaneously. Secondly, the study allows a direct comparison of the difference in green perceived risk, green image, green trust, green satisfaction and green loyalty between green products customers.

Development of the earth-moon system with implications for the geology of the early earth

NASA Technical Reports Server (NTRS)

Smith, J. V.

1976-01-01

Established facts regarding the basic features of the earth and the moon are reviewed, and some important problems involving the moon are discussed (extent of melting, time of crustal differentiation and nature of bombardment, bulk chemical composition, and nature and source of mare basins), with attention given to the various existing theories concerning these problems. Models of the development of the earth-moon system from the solar nebula are examined, with particular attention focused on those that use the concept of capture with disintegration. Impact processes in the early crust of the earth are briefly considered, with attention paid to Green's (1972) suggestion that Archaean greenstone belts may be the terrestrial equivalent of lunar maria.

STS-45 Earth observation of the Aurora Australis or Southern Lights

NASA Image and Video Library

1992-04-02

STS-45 Earth observation taken onboard Atlantis, Orbiter Vehicle (OV) 104, is of the Aurora Australis or Southern Lights. The green appearing auroral activity engulfs the thin blue line on the Earth's limb. Aurorae were observed and photographed throughout the STS-45 nine-day mission.

STS-45 Earth observation of the Aurora Australis or Southern Lights

NASA Technical Reports Server (NTRS)

1992-01-01

STS-45 Earth observation taken onboard Atlantis, Orbiter Vehicle (OV) 104, is of the Aurora Australis or Southern Lights. The green appearing auroral activity engulfs the thin blue line on the Earth's limb. Aurorae were observed and photographed throughout the STS-45 nine-day mission.

Efficient Rare-Earth-Based Coordination Polymers as Green Photocatalysts for the Synthesis of Imines at Room Temperature.

PubMed

Aguirre-Díaz, Lina M; Snejko, Natalia; Iglesias, Marta; Sánchez, Félix; Gutiérrez-Puebla, Enrique; Monge, M Ángeles

2018-06-18

Five new rare-earth coordination polymers (CPs) were designed in order to offer a remarkable platform that contains light-harvesting antennas and catalytic active centers to achieve solar-energy conversion as green alternatives in the synthesis of imines. These five new spirobifluorene-containing Ln-CPs, named [Er 3 (Hsfdc) 3 (sfdc) 3 (H 2 O)]· xH 2 O (RPF-30-Er), [Ln(Hsfdc)(sfdc)(EtOH)]·S (RPF-31-Ln, where Ln = La, Nd, and Sm and S = H 2 O or EtOH), and [Ho(Hsfdc)(sfdc)(H 2 O)] (RPF-32-Ho) (RPF = rare-earth polymeric framework and H 2 sfdc = 9,9'-spirobi[9 H-fluorene]-2,2'-dicarboxylic acid), have been solvothermally synthesized, and their structural features can be described as follows: (i) RPF-30-Er shows a 3D framework in which the inorganic trimers (secondary building units) are cross-linked by Hsfdc - and sfdc 2- linkers displaying a pcu topology. (ii) The isostructural RPF-31-Ln series of materials, together with RPF-32-Ho, exhibit a 1D network of chains growing along the a axis with a ribbon-of-rings topology type. The photocatalytic activity of the RPF- n materials was tested in the oxidative coupling of amines using molecular oxygen and air as oxidizing agents under warm light. Among the materials investigated, RPF-31-Nd was chosen to further investigate the approach in the selectivity of different amine derivates.

Recent developments and future trends in solid phase microextraction techniques towards green analytical chemistry.

PubMed

Spietelun, Agata; Marcinkowski, Łukasz; de la Guardia, Miguel; Namieśnik, Jacek

2013-12-20

Solid phase microextraction find increasing applications in the sample preparation step before chromatographic determination of analytes in samples with a complex composition. These techniques allow for integrating several operations, such as sample collection, extraction, analyte enrichment above the detection limit of a given measuring instrument and the isolation of analytes from sample matrix. In this work the information about novel methodological and instrumental solutions in relation to different variants of solid phase extraction techniques, solid-phase microextraction (SPME), stir bar sorptive extraction (SBSE) and magnetic solid phase extraction (MSPE) is presented, including practical applications of these techniques and a critical discussion about their advantages and disadvantages. The proposed solutions fulfill the requirements resulting from the concept of sustainable development, and specifically from the implementation of green chemistry principles in analytical laboratories. Therefore, particular attention was paid to the description of possible uses of novel, selective stationary phases in extraction techniques, inter alia, polymeric ionic liquids, carbon nanotubes, and silica- and carbon-based sorbents. The methodological solutions, together with properly matched sampling devices for collecting analytes from samples with varying matrix composition, enable us to reduce the number of errors during the sample preparation prior to chromatographic analysis as well as to limit the negative impact of this analytical step on the natural environment and the health of laboratory employees. Copyright © 2013 Elsevier B.V. All rights reserved.

Human-induced greening of the northern extratropical land surface

NASA Astrophysics Data System (ADS)

Mao, J.; Ribes, A.; Yan, B.; Shi, X.; Thornton, P. E.; Seferian, R.; Ciais, P.; Myneni, R. B.; Douville, H.; Piao, S.; Zhu, Z.; Dickinson, R. E.; Dai, Y. J.; Ricciuto, D. M.; Jin, M.; Hoffman, F. M.; Wang, B.; Huang, M.; Lian, X.

2016-12-01

Significant land greening in the northern extratropical latitudes (NEL) has been documented through satellite observations during the past three decades. This enhanced vegetation growth has broad implications for surface energy, water and carbon budgets, and ecosystem services across multiple scales. Discernible human impacts on the Earth's climate system have been revealed by using statistical frameworks of detection-attribution. These impacts, however, were not previously identified on the NEL greening signal, owing to the lack of long-term observational records, possible bias of satellite data, different algorithms used to calculate vegetation greenness, and the lack of suitable simulations from coupled Earth system models (ESMs). Here we have overcome these challenges to attribute recent changes in NEL vegetation activity. We used two 30-year-long remote-sensing-based leaf area index (LAI) data sets, simulations from 19 coupled ESMs with interactive vegetation, and a formal detection and attribution algorithm. Our findings reveal that the observed greening record is consistent with an assumption of anthropogenic forcings, where greenhouse gases play a dominant role, but is not consistent with simulations that include only natural forcings and internal climate variability. These results provide the first clear evidence of a discernible human fingerprint on physiological vegetation changes other than phenology and range shifts.

Human-induced greening of the northern extratropical land surface

NASA Astrophysics Data System (ADS)

Mao, Jiafu; Ribes, Aurélien; Yan, Binyan; Shi, Xiaoying; Thornton, Peter E.; Séférian, Roland; Ciais, Philippe; Myneni, Ranga B.; Douville, Hervé; Piao, Shilong; Zhu, Zaichun; Dickinson, Robert E.; Dai, Yongjiu; Ricciuto, Daniel M.; Jin, Mingzhou; Hoffman, Forrest M.; Wang, Bin; Huang, Mengtian; Lian, Xu

2016-10-01

Significant land greening in the northern extratropical latitudes (NEL) has been documented through satellite observations during the past three decades. This enhanced vegetation growth has broad implications for surface energy, water and carbon budgets, and ecosystem services across multiple scales. Discernible human impacts on the Earth's climate system have been revealed by using statistical frameworks of detection-attribution. These impacts, however, were not previously identified on the NEL greening signal, owing to the lack of long-term observational records, possible bias of satellite data, different algorithms used to calculate vegetation greenness, and the lack of suitable simulations from coupled Earth system models (ESMs). Here we have overcome these challenges to attribute recent changes in NEL vegetation activity. We used two 30-year-long remote-sensing-based leaf area index (LAI) data sets, simulations from 19 coupled ESMs with interactive vegetation, and a formal detection and attribution algorithm. Our findings reveal that the observed greening record is consistent with an assumption of anthropogenic forcings, where greenhouse gases play a dominant role, but is not consistent with simulations that include only natural forcings and internal climate variability. These results provide the first clear evidence of a discernible human fingerprint on physiological vegetation changes other than phenology and range shifts.

Crystallographic Stability of Metastable Phase Formed by Containerless Processing in REFeO3 (RE: Rare-Earth Element)

NASA Technical Reports Server (NTRS)

Kuribayashi, Kazuhiko; Kumar, M. S. Vijaya

2012-01-01

Undercooling a melt often facilitates a metastable phase to nucleate preferentially. Although the classical nucleation theory shows that the most critical factor for forming a metastable phase is the interface free energy, the crystallographic stability is also indispensable for the phase to be frozen at ambient temperature. In compound materials such as oxides, authors have suggested that the decisive factors for forming a critical nucleus are not only the free energy difference but also the difference of the entropy of fusion between stable and metastable phases. In the present study, using REFeO3 (RE: rare-earth element) as a model material, we investigate the formation of a metastable phase from undercooled melts with respect to the competitive nucleation and crystallographical stabilities of both phases.

Earth Observation from space taken during Mission STS-111 UF-2.

NASA Image and Video Library

2002-06-17

STS111-712-028 (5-19 June 2002) --- This photo featuring the San Francisco Bay area in California was photographed by one of the STS-111 crewmembers aboard the Space Shuttle Endeavour. The gray urban footprint of San Francisco, Oakland, San Jose, and the surrounding suburbs contrasts strongly with the brown and green vegetation in the hillsides. At the top and bottom of the picture the green, red and yellow pools are impoundments and salt evaporation ponds. The Gateway to Astronaut Photography of Earth (link to http://eol.jsc.nasa.gov/sseop/) provides searchable access to other photographs of Earth taken by astronauts.

Estimating regional wheat yield from the shape of decreasing curves of green area index temporal profiles retrieved from MODIS data

NASA Astrophysics Data System (ADS)

Kouadio, Louis; Duveiller, Grégory; Djaby, Bakary; El Jarroudi, Moussa; Defourny, Pierre; Tychon, Bernard

2012-08-01

Earth observation data, owing to their synoptic, timely and repetitive coverage, have been recognized as a valuable tool for crop monitoring at different levels. At the field level, the close correlation between green leaf area (GLA) during maturation and grain yield in wheat revealed that the onset and rate of senescence appeared to be important factors for determining wheat grain yield. Our study sought to explore a simple approach for wheat yield forecasting at the regional level, based on metrics derived from the senescence phase of the green area index (GAI) retrieved from remote sensing data. This study took advantage of recent methodological improvements in which imagery with high revisit frequency but coarse spatial resolution can be exploited to derive crop-specific GAI time series by selecting pixels whose ground-projected instantaneous field of view is dominated by the target crop: winter wheat. A logistic function was used to characterize the GAI senescence phase and derive the metrics of this phase. Four regression-based models involving these metrics (i.e., the maximum GAI value, the senescence rate and the thermal time taken to reach 50% of the green surface in the senescent phase) were related to official wheat yield data. The performances of such models at this regional scale showed that final yield could be estimated with an RMSE of 0.57 ton ha-1, representing about 7% as relative RMSE. Such an approach may be considered as a first yield estimate that could be performed in order to provide better integrated yield assessments in operational systems.

Plants and their microbial assistants: Nature's answer to Earth's environmental pollution problems

NASA Technical Reports Server (NTRS)

Wolverton, B. C.

1990-01-01

The utilization of higher plants and their associated microorganisms to solve environmental pollution problems on Earth and in future space applications is briefly reviewed. If man is sealed inside closed facilities, he becomes a polluter of the environment. It is also common knowledge to most people that man cannot survive on Earth without green photosynthesizing plants and microorganisms. Therefore, it is vitally important to have a better understanding of the interactions of man with plants and microorganisms. Biosphere 2 and other related studies presently being conducted or planned, hopefully, will supply data that will help save planet Earth from impending environmental disaster. The development of means to utilize both air and water pollution as a nutrient source for growing green plants is examined.

Towards the development of new phosphors with reduced content of rare earth elements: Structural and optical characterization of Ce:Tb: Al{sub 2}SiO{sub 5}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiriu, D.; Stagi, L.; Carbonaro, C.M.

2016-05-15

Highlights: • A new promising inert matrix as host of luminescent ions is proposed. • Al2SiO5 matrix is free from Rare earths (critical raw materials). • Doping the matrix with Ce and Tb we obtain an efficient green emitter. • Cerium acts as sensitizer for Terbium emission. - Abstract: A new promising inert matrix as host of luminescent ions is proposed. Al2SiO5 samples, doped with rare earths (Ce, Tb single doped and co-doped) are proposed as good prospect for the development of new UV–vis converter with reduced content of rare earths elements. Structural characterization by Raman, XRD spectroscopy and TEMmore » imaging reveals the sillimanite phase and nano sized dimension of the investigated powders. Optical characterization by steady time and time resolved emission spectroscopy for the single doped and co-doped samples allows to identify an efficient energy transfer from Ce to Tb ions under near UV excitation wavelength. The intense green emission observed in the Ce:Tb co-doped Al2SiO5 system suggests its potential application as efficient blue pumped green emitter phosphor to be exploited for white LED: to this purpose we tested the compound in combination with a red emitting doping ion recording for Ce:Tb:Cr:ASO system a correlated color temperature of 6720 K.« less

Galileo Earth approach navigation using connected-element interferometer phase-delay tracking

NASA Technical Reports Server (NTRS)

Thurman, S. W.

1990-01-01

The application of a Connected-Element Interferometer (CEI) to the navigation of the Galileo spacecraft during its encounter with Earth in December 1990 is investigated. A CEI tracking demonstration is planned for the week of November 11 through 18, 1990, from 27 days to 20 days prior to Earth encounter on December 8. During this period, the spacecraft will be tracked daily with Deep Space Network Stations 13 and 15 at Goldstone. The purpose of this work is twofold: first, to establish and define the navigation performance expected during the tracking demonstration and, second, to study, in a more general sense, the sensitivity of orbit demonstration results obtained with CEI to the data density within CEI tracking passes and to important system parameters, such as baseline orientation errors and the phase-delay measurement accuracy. Computer simulation results indicate that the use of CEI data, coupled with conventional range and Doppler data, may reduce the uncertainty in the declination of the spacecraft's incoming trajectory by 15 to 66 percent compared with the operational solution using range and Doppler data only. The level of improvement depends upon the quantity and quality of the CEI data.

Green roofs'retention performances in different climates

NASA Astrophysics Data System (ADS)

Viola, Francesco; Hellies, Matteo; Deidda, Roberto

2017-04-01

The ongoing process of global urbanization contributes to increasing stormwater runoff from impervious surfaces, threatening also water quality. Green roofs have been proved to be an innovative stormwater management tool to partially restore natural state, enhancing interception, infiltration and evapotranspiration fluxes. The amount of water that is retained within green roofs depends mainly on both soil properties and climate. The evaluation of the retained water is not trivial since it depends on the stochastic soil moisture dynamics. The aim of this work is to explore performances of green roofs, in terms of water retention, as a function of their depth considering different climate regimes. The role of climate in driving water retention has been mainly represented by rainfall and potential evapotranspiration dynamics, which are simulated by a simple conceptual weather generator at daily time scale. The model is able to describe seasonal (in-phase and counter-phase) and stationary behaviors of climatic forcings. Model parameters have been estimated on more than 20,000 historical time series retrieved worldwide. Exemplifying cases are discussed for five different climate scenarios, changing the amplitude and/or the phase of daily mean rainfall and evapotranspiration forcings. The first scenario represents stationary climates, in two other cases the daily mean rainfall or the potential evapotranspiration evolve sinusoidally. In the latter two cases, we simulated the in-phase or in counter-phase conditions. Stochastic forcings have been then used as an input to a simple conceptual hydrological model which simulate soil moisture dynamics, evapotranspiration fluxes, runoff and leakage from soil pack at daily time scale. For several combinations of annual rainfall and potential evapotranspiration, the analysis allowed assessing green roofs' retaining capabilities, at annual time scale. Provided abacus allows a first approximation of possible hydrological benefits

Earth Observatory Satellite (EOS) Definition Phase Report, Volume 1

NASA Technical Reports Server (NTRS)

1971-01-01

System definition studies were conducted of the Earth Observatory Satellite (EOS). The studies show that the concept of an Earth Observatory Satellite in a near-earth, sun-synchronous orbit would make a unique contribution to the goals of a coordinated program for acquisition of data for environmental research with applications to earth resource inventory and management. The technical details for the proposed development of sensors, spacecraft, and a ground data processing system are presented.

Deep-sea mud in the Pacific Ocean as a potential resource for rare-earth elements

NASA Astrophysics Data System (ADS)

Kato, Yasuhiro; Fujinaga, Koichiro; Nakamura, Kentaro; Takaya, Yutaro; Kitamura, Kenichi; Ohta, Junichiro; Toda, Ryuichi; Nakashima, Takuya; Iwamori, Hikaru

2011-08-01

World demand for rare-earth elements and the metal yttrium--which are crucial for novel electronic equipment and green-energy technologies--is increasing rapidly. Several types of seafloor sediment harbour high concentrations of these elements. However, seafloor sediments have not been regarded as a rare-earth element and yttrium resource, because data on the spatial distribution of these deposits are insufficient. Here, we report measurements of the elemental composition of over 2,000 seafloor sediments, sampled at depth intervals of around one metre, at 78 sites that cover a large part of the Pacific Ocean. We show that deep-sea mud contains high concentrations of rare-earth elements and yttrium at numerous sites throughout the eastern South and central North Pacific. We estimate that an area of just one square kilometre, surrounding one of the sampling sites, could provide one-fifth of the current annual world consumption of these elements. Uptake of rare-earth elements and yttrium by mineral phases such as hydrothermal iron-oxyhydroxides and phillipsite seems to be responsible for their high concentration. We show that rare-earth elements and yttrium are readily recovered from the mud by simple acid leaching, and suggest that deep-sea mud constitutes a highly promising huge resource for these elements.

Indocyanine green plasma disappearance rate during the anhepatic phase of orthotopic liver transplantation.

PubMed

Bruegger, Lukas; Studer, Peter; Schmid, Stefan W; Pestel, Gunther; Reichen, Juerg; Seiler, Christian; Candinas, Daniel; Inderbitzin, Daniel

2008-01-01

Non-invasive pulse spectrophotometry to measure indocyanine green (ICG) elimination correlates well with the conventional invasive ICG clearance test. Nevertheless, the precision of this method remains unclear for any application, including small-for-size liver remnants. We therefore measured ICG plasma disappearance rate (PDR) during the anhepatic phase of orthotopic liver transplantation using pulse spectrophotometry. Measurements were done in 24 patients. The median PDR after exclusion of two outliers and two patients with inconstant signal was 1.55%/min (95% confidence interval [CI]=0.8-2.2). No correlation with patient age, gender, body mass, blood loss, administration of fresh frozen plasma, norepinephrine dose, postoperative albumin (serum), or difference in pre and post transplant body weight was detected. In conclusion, we found an ICG-PDR different from zero in the anhepatic phase, an overestimation that may arise in particular from a redistribution into the interstitial space. If ICG pulse spectrophotometry is used to measure functional hepatic reserve, the verified average difference from zero (1.55%/min) determined in our study needs to be taken into account.

Earth and Moon as viewed from Mars

NASA Technical Reports Server (NTRS)

2003-01-01

MGS MOC Release No. MOC2-368, 22 May 2003

[figure removed for brevity, see original site] Globe diagram illustrates the Earth's orientation as viewed from Mars (North and South America were in view).

Earth/Moon: This is the first image of Earth ever taken from another planet that actually shows our home as a planetary disk. Because Earth and the Moon are closer to the Sun than Mars, they exhibit phases, just as the Moon, Venus, and Mercury do when viewed from Earth. As seen from Mars by MGS on 8 May 2003 at 13:00 GMT (6:00 AM PDT), Earth and the Moon appeared in the evening sky. The MOC Earth/Moon image has been specially processed to allow both Earth (with an apparent magnitude of -2.5) and the much darker Moon (with an apparent magnitude of +0.9) to be visible together. The bright area at the top of the image of Earth is cloud cover over central and eastern North America. Below that, a darker area includes Central America and the Gulf of Mexico. The bright feature near the center-right of the crescent Earth consists of clouds over northern South America. The image also shows the Earth-facing hemisphere of the Moon, since the Moon was on the far side of Earth as viewed from Mars. The slightly lighter tone of the lower portion of the image of the Moon results from the large and conspicuous ray system associated with the crater Tycho.

A note about the coloring process: The MGS MOC high resolution camera only takes grayscale (black-and-white) images. To 'colorize' the image, a Mariner 10 Earth/Moon image taken in 1973 was used to color the MOC Earth and Moon picture. The procedure used was as follows: the Mariner 10 image was converted from 24-bit color to 8-bit color using a JPEG to GIF conversion program. The 8-bit color image was converted to 8-bit grayscale and an associated lookup table mapping each gray value of the image to a red-green-blue color triplet (RGB). Each color triplet was root-sum-squared (RSS), and sorted in increasing RSS

Lead-free/rare earth-free Green-light-emitting crystal based on organic-inorganic hybrid [(C10H16N)2][MnBr4] with high emissive quantum yields and large crystal size

NASA Astrophysics Data System (ADS)

Cai, Xing-Wei; Zhao, Yu-Yuan; Li, Hong; Huang, Cui-Ping; Zhou, Zhen

2018-06-01

With the flourishing development of emitting materials, tremendous technological progress has been accomplished. However, they still face great challenges in convenient economical environmental-friendly large-scale commercial production. Herein we designed this organic-inorganic hybrid lead-free compound, an emerging class of high-efficiency emitting materials, [(C10H16N)2][MnBr4] (1), which emits intense greenish photoluminescence with a high emissive quantum yields of 72.26%, was prepared through the convenient economical solution method. What's more, compared with rare earth fluorescent materials (especially green-emitting Tb), Mn material is rich in natural resources and low commercial cost, which would possess an increasingly predominant advantage in the preparation of luminescent materials. Additionally, the exceptional thermal stability as well as the low-cost/convenient preparation process makes crystal 1 with the large size of more than 1 cm to be an ideal technologically important green-emitting material and it would open up a new route towards the commercialization process of lead-free/rare earth-free hybrid emitting materials in display and sensing.

Electronic Structure Calculation of Permanent Magnets using the KKR Green's Function Method

NASA Astrophysics Data System (ADS)

Doi, Shotaro; Akai, Hisazumi

2014-03-01

Electronic structure and magnetic properties of permanent magnetic materials, especially Nd2Fe14B, are investigated theoretically using the KKR Green's function method. Important physical quantities in magnetism, such as magnetic moment, Curie temperature, and anisotropy constant, which are obtained from electronics structure calculations in both cases of atomic-sphere-approximation and full-potential treatment, are compared with past band structure calculations and experiments. The site preference of heavy rare-earth impurities are also evaluated through the calculation of formation energy with the use of coherent potential approximations. Further, the development of electronic structure calculation code using the screened KKR for large super-cells, which is aimed at studying the electronic structure of realistic microstructures (e.g. grain boundary phase), is introduced with some test calculations.

The quadruple squeeze: defining the safe operating space for freshwater use to achieve a triply green revolution in the anthropocene.

PubMed

Rockström, Johan; Karlberg, Louise

2010-05-01

Humanity has entered a new phase of sustainability challenges, the Anthropocene, in which human development has reached a scale where it affects vital planetary processes. Under the pressure from a quadruple squeeze-from population and development pressures, the anthropogenic climate crisis, the anthropogenic ecosystem crisis, and the risk of deleterious tipping points in the Earth system-the degrees of freedom for sustainable human exploitation of planet Earth are severely restrained. It is in this reality that a new green revolution in world food production needs to occur, to attain food security and human development over the coming decades. Global freshwater resources are, and will increasingly be, a fundamental limiting factor in feeding the world. Current water vulnerabilities in the regions in most need of large agricultural productivity improvements are projected to increase under the pressure from global environmental change. The sustainability challenge for world agriculture has to be set within the new global sustainability context. We present new proposed sustainability criteria for world agriculture, where world food production systems are transformed in order to allow humanity to stay within the safe operating space of planetary boundaries. In order to secure global resilience and thereby raise the chances of planet Earth to remain in the current desired state, conducive for human development on the long-term, these planetary boundaries need to be respected. This calls for a triply green revolution, which not only more than doubles food production in many regions of the world, but which also is environmentally sustainable, and invests in the untapped opportunities to use green water in rainfed agriculture as a key source of future productivity enhancement. To achieve such a global transformation of agriculture, there is a need for more innovative options for water interventions at the landscape scale, accounting for both green and blue water, as well

A Sun-Earth-Moon Activity to Develop Student Understanding of Lunar Phases and Frames of Reference

ERIC Educational Resources Information Center

Ashmann, Scott

2012-01-01

The Moon is an ever-present subject of observation, and it is a recurring topic in the science curriculum from kindergarten's basic observations through graduate courses' mathematical analyses of its orbit. How do students come to comprehend Earth's nearest neighbor? What is needed for them to understand the lunar phases and other phenomena and…

Source phase shift - A new phenomenon in wave propagation due to anelasticity. [in free oscillations of earth model

NASA Technical Reports Server (NTRS)

Buland, R.; Yuen, D. A.; Konstanty, K.; Widmer, R.

1985-01-01

The free oscillations of an anelastic earth model due to earthquakes were calculated directly by means of the correspondence principle from wave propagation theory. The formulation made it possible to find the source phase which is not predictable using first order perturbation theory. The predicted source phase was largest for toroidal modes with source components proportional to the radial strain scalar instead of the radial displacement scalar. The source phase increased in relation to the overtone number. In addition, large relative differences were found in the excitation modulus and the phase when the elastic excitation was small. The effect was sufficient to bias estimates of source properties and elastic structure.

'Laba' garlic processed by dense phase carbon dioxide: the relation between green colour generation and cellular structure, alliin consumption and alliinase activity.

PubMed

Tao, Dandan; Zhou, Bing; Zhang, Luyao; Hu, Xiaosong; Liao, Xiaojun; Zhang, Yan

2016-07-01

'Laba' garlic is usually processed by soaking garlic in vinegar for more than 1 week during winter. It is popular for its unique green colour and tasty flavour. Greening is desirable and required for this product as its characteristic. Dense phase carbon dioxide (DPCD) had a significant effect on the greening of intact garlic (Allium sativum L.) cloves. The relation between green colour generation and alliin consumption, alliinase activity and the cellular structure of garlic, respectively, were investigated in this work. The effects of treatment time, pressure and temperature of DPCD were also analysed and discussed. DPCD had a significant effect on the cellular structure of garlic cells. Garlic protoplast underwent greater morphological change after DPCD treatments at higher temperatures while the amount of precipitate increased with greater treatment time and temperature. Common trends on garlic greening and alliin consumption were observed except for DPCD treatment at 10 MPa and 65 °C. The alliinase activity decreased with increasing treatment time, pressure and temperature. It reached the lowest level at 13 MPa and 55 °C. The formation of the green colour was a comprehensive result of DPCD on changing cellular structure, alliin consumption and alliinase activity. DPCD treatment at 10 MPa and 55 °C was the optimum condition for the greening of 'Laba' garlic. This work further facilitated the application of DPCD in the industrial production of 'Laba' garlic. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Trojan Asteroid Shares Orbit with Earth Artist Animation

NASA Image and Video Library

2011-07-27

This artist concept illustrates the first known Earth Trojan asteroid, discovered by NEOWISE, the asteroid-hunting portion of NASA WISE mission. The asteroid is shown in gray and its extreme orbit is shown in green. Objects are not drawn to scale.

Two-Phase Dynamics Simulations of the Growth and Instability of Earth's Inner Core

NASA Astrophysics Data System (ADS)

Hernlund, J. W.; Jellinek, M.; Labrosse, S.

2008-12-01

When the center of Earth's core began to freeze from a homogeneous liquid 1-2 billion years ago, its constitution was very likely that of a mushy region. As this incipient inner core grew by further crystallization of the outer core, an increase in gravity force allowed for the solid grains to compress against one another, undergo viscous compaction, and begin to expel remnant fluid out of the inner core by percolation. Meanwhile, inside the inner core the residual fluid and solid remained in equilibrium, and any perturbations that resulted in upwelling of the deformable mush would also be accompanied by decompression melting. Upwelling and melting regions might then increase in liquid fraction, become less dense, and hence buoyant in a way that would propel them upward at a faster rate, setting up a runaway instability and partial Rayleigh-Taylor-like overturn of Earth's inner core. Structures inherited from this event possibly include the distinct innermost inner core posited by seismologists to exist at Earth's centermost 300-600 km. We use a new two-phase dynamics code to model this scenario in axi-symmetric geometry in order to understand whether and when such an instability occurred, what size the core will have been at the onset of instability, and the degree and style of deformation that would have accompanied this episode. We have found that the growth of instability competes with the rate of background melt percolation, such that the instability would only have occurred after the inner core reaches a critical size and expelled a certain amount of liquid from its interior. A linear stability analysis confirms that there is a critical Rayleigh number for the onset of instability at a given radius. The combined constraints show that the inner core is guaranteed to have undergone this kind of instability, at a time and strength governed solely by physical properties such as grain size, density differences between liquid and solid, and viscosities of the

The hyper-fluorescent transitional bands in ultra-late phase of indocyanine green angiography in chronic central serous chorioretinopathy.

PubMed

Hua, Rui; Yao, Kai; Xia, Fan; Li, Jun; Guo, Lei; Yang, Guoxing; Tao, Jun

2016-03-01

Chronic central serous chorioretinopathy (CSCR) is regarded as a type of severe diffuse retinal pigment epitheliopathy. There is an atrophic tract at level of retinal pigment epithelium (RPE) due to hyper-permeability of choroidal vessels, along with photoreceptor (PR) atrophy. Indocyanine green angiography (ICGA) is considered a gold standard for diagnosis. The purpose of this work is to investigate the hyper-fluorescent transitional bands (HFTB) between hypo-fluorescent and normal regions of the retina in the ultra-late phase of ICGA in CSCR. 26 chronic CSCR eyes and 12 relative normal eyes received spectral domain optical coherence tomography (SD-OCT), and ICGA at the 24th hour after indocyanine green (ICG) intravenous injection. In the ultra-late phase, images showed homogenous fluorescence in all normal eyes. On the contrary, geographical hypofluorescent lesions with atrophy of RPE was noted in 26 chronic CSCR eyes. Moreover, HFTB with intact RPE and disrupted PR was detected in 20 out of 26 chronic CSCR eyes (76.9%). The HFTB may indicate the early damage in chronic CSCR. Ultra-late ICGA can monitor not only metabolic status by endogenous melanin, but also membrane function in RPE by exogenous ICG molecule. © 2015 Wiley Periodicals, Inc.

Antioxidant effects of green tea

PubMed Central

FORESTER, SARAH C.; LAMBERT, JOSHUA D.

2013-01-01

Consumption of green tea (Camellia sinensis) may provide protection against chronic diseases, including cancer. Green tea polyphenols are believed to be responsible for this cancer preventive effect, and the antioxidant activity of the green tea polyphenols has been implicated as a potential mechanism. This hypothesis has been difficult to study in vivo due to metabolism of these compounds and poor understanding of the redox environment in vivo. Green tea polyphenols can be direct antioxidants by scavenging reactive oxygen species or chelating transition metals as has been demonstrated in vitro. Alternatively, they may act indirectly by up-regulating phase II antioxidant enzymes. Evidence of this latter effect has been observed in vivo, yet more work is required to determine under which conditions these mechanisms occur. Green tea polyphenols can also be potent pro-oxidants, both in vitro and in vivo, leading to the formation of hydrogen peroxide, the hydroxyl radical, and superoxide anion. The potential role of these pro-oxidant effects in the cancer preventive activity of green tea is not well understood. The evidence for not only the antioxidant, but also pro-oxidant, properties of green tea are discussed in the present review. PMID:21538850

Anisotropy of the Earth's inner inner core from autocorrelations of earthquake coda in China Regional Seismic Networks

NASA Astrophysics Data System (ADS)

Xia, H.; Song, X.; Wang, T.

2014-12-01

The Earth's inner core possesses strong cylindrical anisotropy with the fast symmetry axis parallel to the rotation axis. However, recent study has suggested that the inner part of the inner core has a fast symmetry axis near the equator with a different form of anisotropy from the outer part (Wang et al., this session). To confirm the observation, we use data from dense seismic arrays of the China Regional Seismic Networks. We perform autocorrelation (ACC) of the coda after major earthquakes (Mw>=7.0) at each station and then stack the ACCs at each cluster of stations. The PKIKP2 and PKIIKP2 phases (round-trip phase from the Earth's surface reflections) can be clearly extracted from the stacked empirical Green's functions. We observe systematic variation of the differential times between PKIKP2 and PKIIKP2 phases, which are sensitive to the bulk anisotropy of the inner core. The differential times show large variations with both latitudes and longitudes, even though our ray paths are not polar (with our stations at mid-range latitudes of about 20 to 45 degrees). The observations cannot be explained by an averaged anisotropy model with the fast axis along the rotation axis. The pattern appears consistent with an inner inner core that has a fast axis near the equator.

Geostationary earth climate sensor: Scientific utility and feasibility, phase A

NASA Technical Reports Server (NTRS)

Campbell, G. Garrett; Vonderharr, T. H.; Evert, T.; Kidder, Stanley Q.; Purdom, James F. W.

1991-01-01

The possibility of accurate broad band radiation budget measurements from a GEO platform will provide a unique opportunity for viewing radiation processes in the atmosphere-ocean system. The CSU/TRW team has prepared a Phase 1 instrument design study demonstrating that measurements of radiation budget are practical from geosynchronous orbit with proven technology. This instrument concept is the Geostationary Earth Climate Sensor (GECS). A range of resolutions down to 20 km at the top of the atmosphere are possible, depending upon the scientific goals of the experiment. These tradeoffs of resolution and measurement repeat cycles are examined for scientific utility. The design of a flexible instrument is shown to be possible to meet the two goals: long-term, systematic monitoring of the diurnal cycles of radiation budget; and high time and space resolution studies of regional radiation features.

Interaction of green tea polyphenols with dairy matrices in a simulated gastrointestinal environment.

PubMed

Lamothe, Sophie; Azimy, Naheed; Bazinet, Laurent; Couillard, Charles; Britten, Michel

2014-10-01

The consumption of polyphenols in green tea has been associated with beneficial health effects. Although polyphenols are unstable in the intestinal environment, they may be protected by interactions with dairy proteins during digestion. The objectives of this study were to evaluate the effect of a green tea extract on the digestibility of different dairy matrices and to monitor the antioxidant activity of these matrices with or without the green tea extract during digestion in a simulated gastrointestinal environment. Milk, yogurt and cheese with similar fat-to-protein ratios were subjected to simulated digestion. Matrix degradation, protein and fat hydrolysis, polyphenol concentration and radical scavenging activity were analyzed during gastric and intestinal digestion phases. Cheese was the matrix most resistant to protein and fat digestion. The addition of the green tea extract significantly decreased proteolysis in the gastric phase but had no effect in the intestinal phase. The kinetics of fatty acid release was reduced by the presence of the green tea extract. Transition from the gastric phase to the intestinal phase induced a 50% decrease in the antioxidant activity of the control (tea extract dispersed in water) due to the degradation of polyphenols. The presence of dairy matrices significantly improved polyphenol stability in the intestinal phase and increased the antioxidant activity by 29% (cheese) to 42% (milk) compared to the control. These results suggest that simultaneous consumption of green tea and dairy products helps to maintain the integrity and antioxidant activity of polyphenols during digestion.

Development of the self-learning machine for creating models of microprocessor of single-phase earth fault protection devices in networks with isolated neutral voltage above 1000 V

NASA Astrophysics Data System (ADS)

Utegulov, B. B.; Utegulov, A. B.; Meiramova, S.

2018-02-01

The paper proposes the development of a self-learning machine for creating models of microprocessor-based single-phase ground fault protection devices in networks with an isolated neutral voltage higher than 1000 V. Development of a self-learning machine for creating models of microprocessor-based single-phase earth fault protection devices in networks with an isolated neutral voltage higher than 1000 V. allows to effectively implement mathematical models of automatic change of protection settings. Single-phase earth fault protection devices.

Optical thermometry through infrared excited green upconversion in monoclinic phase Gd2(MoO4)3:Yb3+/Er3+ phosphor

NASA Astrophysics Data System (ADS)

Xu, Weijiang; Li, Dongyu; Hao, Haoyue; Song, Yinglin; Wang, Yuxiao; Zhang, Xueru

2018-04-01

Monoclinic phase Gd2(MoO4)3: Yb3+/Er3+ phosphor is synthesized via a simple sol-gel method. The XRD result reveals that the phosphor possesses monoclinic structure with space group C2/c(15). Under the excitation of a 980 nm laser, its emission spectra shows remarkably intense green and negligible red emissions, which are all two-photon process. By investigating effect of temperature on green emission of the sample, the competition between the thermal agitation and non-radiative relaxation of 2H11/2 level can be found, which is verified by the measurement of lifetime. In addition, the sensitivity of optical thermometry is studied based on the fluorescence intensity ratio technique through infrared excited green upconversion. The maximum sensitivity is found to be about 0.02574 K-1 at 510.2 K, suggesting that the phosphor can be used as an excellent material for optical temperature sensing.

Earth Science

NASA Image and Video Library

1994-09-02

This image depicts a full view of the Earth, taken by the Geostationary Operational Environment Satellite (GOES-8). The red and green charnels represent visible data, while the blue channel represents inverted 11 micron infrared data. The north and south poles were not actually observed by GOES-8. To produce this image, poles were taken from a GOES-7 image. Owned and operated by the National Oceanic and Atmospheric Administration (NOAA), GOES satellites provide the kind of continuous monitoring necessary for intensive data analysis. They circle the Earth in a geosynchronous orbit, which means they orbit the equatorial plane of the Earth at a speed matching the Earth's rotation. This allows them to hover continuously over one position on the surface. The geosynchronous plane is about 35,800 km (22,300 miles) above the Earth, high enough to allow the satellites a full-disc view of the Earth. Because they stay above a fixed spot on the surface, they provide a constant vigil for the atmospheric triggers for severe weather conditions such as tornadoes, flash floods, hail storms, and hurricanes. When these conditions develop, the GOES satellites are able to monitor storm development and track their movements. NASA manages the design and launch of the spacecraft. NASA launched the first GOES for NOAA in 1975 and followed it with another in 1977. Currently, the United States is operating GOES-8, positioned at 75 west longitude and the equator, and GOES-10, which is positioned at 135 west longitude and the equator. (GOES-9, which malfunctioned in 1998, is being stored in orbit as an emergency backup should either GOES-8 or GOES-10 fail. GOES-11 was launched on May 3, 2000 and GOES-12 on July 23, 2001. Both are being stored in orbit as a fully functioning replacement for GOES-8 or GOES-10 on failure.

Earth observation taken by the Expedition 46 crew

NASA Image and Video Library

2016-01-20

ISS046e015697 (01/20/2016) --- NASA astronaut Scott Kelly took this majestic image of the Earth at night highlighting the green and red hues of an Aurora. He tweeted this message along with the image: “The dance of #aurora. #YearInSpace"

Geoantineutrino spectrum and slow nuclear burning on the boundary of the liquid and solid phases of the Earth's core

NASA Astrophysics Data System (ADS)

Rusov, V. D.; Pavlovich, V. N.; Vaschenko, V. N.; Tarasov, V. A.; Zelentsova, T. N.; Bolshakov, V. N.; Litvinov, D. A.; Kosenko, S. I.; Byegunova, O. A.

2007-09-01

We give an alternative description of the data produced in the KamLAND experiment. Assuming the existence of a natural nuclear reactor on the boundary of the liquid and solid phases of the Earth's core, a geoantineutrino spectrum is obtained. This assumption is based on the experimental results of V. Anisichkin and his collaborators on the interaction of uranium dioxide and uranium carbide with iron-nickel and silica-alumina melts at high pressure (5-10 GPa) and temperature (1600-2200°C), which led to the proposal of the existence of an actinide shell in the Earth's core. We describe the operating mechanism of this reactor as solitary waves of nuclear burning in 238U and/or 232Th medium, in particular, as neutron fission progressive waves of Feoktistov and/or Teller et al. type. Next, we propose a simplified model for the accumulation and burn-up kinetics in Feoktistov's U-Pu fuel cycle. We also apply this model for numerical simulations of neutron fission wave in a two-phase UO2/Fe medium on the surface of the Earth's solid core. The proposed georeactor model offers a mechanism for the generation of 3He. The 3He/4He distribution in the Earth's interior is calculated, which in turn can be used as a natural quantitative criterion of the georeactor thermal power. Finally, we give a tentative estimation of the geoantineutrino intensity and spectrum on the Earth's surface. For this purpose we use the O'Nions et al. geochemical model of mantle differentiation and crust growth complemented by a nuclear energy source (georeactor with power of 30 TW).

Determination of adulteration of malachite green in green pea and some prepared foodstuffs by micellar liquid chromatography.

PubMed

Ashok, Vipin; Agrawal, Nitasha; Durgbanshi, Abhilasha; Esteve-Romero, Josep; Bose, Devasish

2014-01-01

A simple, fast, and robust micellar LC method was developed for the separation and identification of the nonpermitted color malachite green in green pea and some ready-to-eat foodstuffs. Malachite green (4-[(4-dimethylaminophenyl) phenyl-methyl]-N,N-dimethylaniline) is a hazardous dye that is used to treat fungal and protozoan infections in fish and is a common adulterant (coloring agent) in green pea and other green vegetables because of its green color. In the present work, malachite green was determined in various foodstuffs using a direct injection technique on an RP C18 column with isocratic elution. The optimum mobile phase consisted of 0.15 M sodium dodecyl sulfate (SDS), 6% pentanol buffered at pH 5. Detection was carried out at 620 nm. Malachite green was eluted in 9.2 min without any interference caused by endogenous compounds. Linearities (r > 0.9999), intraday and interday precision (RSD less than 1.00%) in micellar media, and robustness were studied for method validation. LOD and LOQ were 0.10 and 0.25 ppm, respectively. The simplicity of the developed method makes it useful for routine analysis in the area of food QC.

Solar System Portrait - Earth as Pale Blue Dot

NASA Image and Video Library

1996-09-12

This narrow-angle color image of the Earth, dubbed Pale Blue Dot, is a part of the first ever 'portrait' of the solar system taken by NASA’s Voyager 1. The spacecraft acquired a total of 60 frames for a mosaic of the solar system from a distance of more than 4 billion miles from Earth and about 32 degrees above the ecliptic. From Voyager's great distance Earth is a mere point of light, less than the size of a picture element even in the narrow-angle camera. Earth was a crescent only 0.12 pixel in size. Coincidentally, Earth lies right in the center of one of the scattered light rays resulting from taking the image so close to the sun. This blown-up image of the Earth was taken through three color filters -- violet, blue and green -- and recombined to produce the color image. The background features in the image are artifacts resulting from the magnification. http://photojournal.jpl.nasa.gov/catalog/PIA00452

Mineralogical modeling of the anisotropic inner core based on the phase relations and elasticity of iron and iron alloys under the Earth's core condition

NASA Astrophysics Data System (ADS)

Kuwayama, Y.; Tsuchiya, T.; Ohishi, Y.

2011-12-01

The inner-core and the outer-core, which make up the center of the Earth, are thought to be composed predominantly of a solid and liquid iron alloying with 5 to 15 % nickel, respectively. Determination of the physical properties of iron alloy at extremely high pressures found in the deep Earth's core (>300 GPa) is a fundamental issue for understanding the thermal and dynamical state of the Earth's core. According to seismological observations, it is widely accepted that the Earth's inner-core is elastically anisotropic; the compressional wave in the inner-core propagates 3~4 % faster along its rotational axis than in the equatorial direction. A number of models on core dynamics have been proposed to explain the origin of the inner-core anisotropy, but all of them are based on the idea of the crystal preferred orientation of iron. The phase relation of iron at high pressures has been extensively studied using LH-DACs. At relatively low temperatures, around room temperature, the phase relations are already well established; a low pressure phase with a bcc structure transforms into an hcp structure above ~10 GPa and it persists above 300 GPa. In contrast, the phase relations of iron at high temperatures are highly controversial. Some experiments assigned different crystal structures including orthorhombic, dhcp, fcc, and bcc as candidate stable crystal structures, whereas others suggested that the hcp structure remains stable at high temperatures. Despite considerable attention on these new phases, there is, however, no experimental reproducibility. The lack of plausible data is mainly because of the substantial difficulties associated with high-temperature experiments at multimegabar pressures. In order to overcome these difficulties, we have developed experimental techniques using a laser-heated diamond-anvil cell for the past decade and succeeded in obtaining excellent quality data under extremely high-pressure and high-temperature conditions. In order to

Ionization energies and electron affinities from a random-phase-approximation many-body Green's-function method including exchange interactions

NASA Astrophysics Data System (ADS)

Heßelmann, Andreas

2017-06-01

A many-body Green's-function method employing an infinite order summation of ring and exchange-ring contributions to the self-energy is presented. The individual correlation and relaxation contributions to the quasiparticle energies are calculated using an iterative scheme which utilizes density fitting of the particle-hole, particle-particle and hole-hole densities. It is shown that the ionization energies and electron affinities of this approach agree better with highly accurate coupled-cluster singles and doubles with perturbative triples energy difference results than those obtained with second-order Green's-function approaches. An analysis of the correlation and relaxation terms of the self-energy for the direct- and exchange-random-phase-approximation (RPA) Green's-function methods shows that the inclusion of exchange interactions leads to a reduction of the two contributions in magnitude. These differences, however, strongly cancel each other when summing the individual terms to the quasiparticle energies. Due to this, the direct- and exchange-RPA methods perform similarly for the description of ionization energies (IPs) and electron affinities (EAs). The coupled-cluster reference IPs and EAs, if corrected to the adiabatic energy differences between the neutral and charged molecules, were shown to be in very good agreement with experimental measurements.

Earth storable bimodal engine, phase 1

NASA Technical Reports Server (NTRS)

1973-01-01

An in-depth study of an Earth Storable Bimodal (ESB) Engine using earth storable propellants N2O/N2H4 and operating in either a monopropellant or bipropellant mode was conducted. Detailed studies were completed for both a hot-gas, regeneratively cooled thrust chamber and a ducted hot-gas, film cooled thrust chamber. Hydrazine decomposition products were used for cooling in either configuration. The various arrangements and configurations of hydrazine reactors, secondary injectors, chambers and gimbal methods were considered. The two basic materials selected for the major components were columbium alloys and L-605. The secondary injector types considered were previously demonstrated by JPL and consisted of a liquid-on-gas triplet, a liquid-on-gas doublet, and a liquid-on-gas coaxial injector. Various design tradeoffs were made with different reactor types located at: the secondary injector station, the thrust chamber throat, and the nozzle/extension interface. Associated thermal, structural, and mass analyses were completed.

Coprecipitation of Arsenate and Arsenite with Green Rust Minerals

EPA Science Inventory

The objectives of this experiment were to evaluate the extent and nature of arsenic co-precipitation with green rusts and to examine the influence of arsenic incorporation on the mineralogy of formed solid phases. Stoichiometric green rusts were obtained by coprecipitation of fe...

Earth as art three

USGS Publications Warehouse

,

2010-01-01

For most of us, deserts, mountains, river valleys, coastlines even dry lakebeds are relatively familiar features of the Earth's terrestrial environment. For earth scientists, they are the focus of considerable scientific research. Viewed from a unique and unconventional perspective, Earth's geographic attributes can also be a surprising source of awe-inspiring art. That unique perspective is space. The artists for the Earth as Art Three exhibit are the Landsat 5 and Landsat 7 satellites, which orbit approximately 705 kilometers (438 miles) above the Earth's surface. While studying the images these satellites beam down daily, researchers are often struck by the sheer beauty of the scenes. Such images inspire the imagination and go beyond scientific value to remind us how stunning, intricate, and simply amazing our planet's features can be. Instead of paint, the medium for these works of art is light. But Landsat satellite sensors don't see light as human eyes do; instead, they see radiant energy reflected from Earth's surface in certain wavelengths, or bands, of red, green, blue, and infrared light. When these different bands are combined into a single image, remarkable patterns, colors, and shapes emerge. The Earth as Art Three exhibit provides fresh and inspiring glimpses of different parts of our planet's complex surface. The images in this collection were chosen solely based on their aesthetic appeal. Many of the images have been manipulated to enhance color variations or details. They are not intended for scientific interpretation only for your viewing pleasure. Enjoy!

Comparison of Magnetorheological Fluids on Earth and in Space

NASA Technical Reports Server (NTRS)

2002-01-01

These are video microscope images of magnetorheological (MR) fluids, illuminated with a green light. Those on Earth, left, show the MR fluid forming columns or spikes structures. On the right, the fluids in microgravity aboard the International Space Station (ISS), formed broader columns.

Defect Clustering and Nano-Phase Structure Characterization of Multi-Component Rare Earth Oxide Doped Zirconia-Yttria Thermal Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Chen, Yuan L.; Miller, Robert A.

2003-01-01

Advanced oxide thermal barrier coatings have been developed by incorporating multi-component rare earth oxide dopants into zirconia-yttria to effectively promote the creation of the thermodynamically stable, immobile oxide defect clusters and/or nano-scale phases within the coating systems. The presence of these nano-sized defect clusters has found to significantly reduce the coating intrinsic thermal conductivity, improve sintering resistance, and maintain long-term high temperature stability. In this paper, the defect clusters and nano-structured phases, which were created by the addition of multi-component rare earth dopants to the plasma-sprayed and electron-beam physical vapor deposited thermal barrier coatings, were characterized by high-resolution transmission electron microscopy (TEM). The defect cluster size, distribution, crystallographic and compositional information were investigated using high-resolution TEM lattice imaging, selected area diffraction (SAD), electron energy-loss spectroscopy (EELS) and energy dispersive spectroscopy (EDS) analysis techniques. The results showed that substantial defect clusters were formed in the advanced multi-component rare earth oxide doped zirconia- yttria systems. The size of the oxide defect clusters and the cluster dopant segregation was typically ranging from 5 to 50 nm. These multi-component dopant induced defect clusters are an important factor for the coating long-term high temperature stability and excellent performance.

Defect Clustering and Nano-Phase Structure Characterization of Multi-Component Rare Earth Oxide Doped Zirconia-Yttria Thermal Barrier Coatings

NASA Technical Reports Server (NTRS)

Zhu, Dongming; Chen, Yuan L.; Miller, Robert A.

1990-01-01

Advanced oxide thermal barrier coatings have been developed by incorporating multi- component rare earth oxide dopants into zirconia-yttria to effectively promote the creation of the thermodynamically stable, immobile oxide defect clusters and/or nano-scale phases within the coating systems. The presence of these nano-sized defect clusters has found to significantly reduce the coating intrinsic thermal conductivity, improve sintering resistance, and maintain long-term high temperature stability. In this paper, the defect clusters and nano-structured phases, which were created by the addition of multi-component rare earth dopants to the plasma- sprayed and electron-beam physical vapor deposited thermal barrier coatings, were characterized by high-resolution transmission electron microscopy (TEM). The defect cluster size, distribution, crystallographic and compositional information were investigated using high-resolution TEM lattice imaging, selected area diffraction (SAD), and energy dispersive spectroscopy (EDS) analysis techniques. The results showed that substantial defect clusters were formed in the advanced multi-component rare earth oxide doped zirconia-yttria systems. The size of the oxide defect clusters and the cluster dopant segregation was typically ranging fiom 5 to 50 nm. These multi-component dopant induced defect clusters are an important factor for the coating long-term high temperature stability and excellent performance.

Optical thermometry based on green upconversion emission in Er3+/Yb3+ codoped BaGdF5 glass ceramics

NASA Astrophysics Data System (ADS)

Wu, Ting; Zhao, Shilong; Lei, Ruoshan; Huang, Lihui; Xu, Shiqing

2018-02-01

Er3+/Yb3+ codoped BaGdF5 glass ceramics have been prepared and used to develop a portable all-fiber temperature sensor based on fluorescence intensity ratio technique. XRD and TEM results affirm the generation of BaGdF5 nanocrystals in the borosilicate glass. Eu3+ ions are used as spectral probe to investigate external environment around rare earth (RE) ions. Intense green upconversion emissions from Er3+ ions are detected in the BaGdF5 glass ceramics and their intensity are enhanced about three orders of magnitude after heat treatment, which is attributed to the enrichment of RE ions in the BaGdF5 phase. Based on green upconversion emission from Er3+ ions, the temperature sensing property of the portable all-fiber temperature sensor is studied. The maximum absolute sensitivity is 15.5 × 10-4 K-1 at 567 K and the relative sensitivity is 1.28% K-1 at 298 K, respectively.

On-chip sample pretreatment using a porous polymer monolithic column for solid-phase microextraction and chemiluminescence determination of catechins in green tea.

PubMed

Lin, Ling; Chen, Hui; Wei, Huibin; Wang, Feng; Lin, Jin-Ming

2011-10-21

A porous polymer monolithic column for solid-phase microextraction and chemiluminescence detection was integrated into a simple microfluidic chip for the extraction and determination of catechins in green tea. The porous polymer was prepared by poly(glycidyl methacrylate-co-ethylene dimethacrylate) and modified with ethylenediamine. Catechins can be concentrated in the porous polymer monolithic column and react with potassium permanganate to give chemiluminescence. The microfluidic chip is reusable with high sensitivity and very low reagent consumption. The on-line preconcentration and detection can be realized without an elution step. The enrichment factor was calculated to be about 20 for catechins. The relative chemiluminescence intensity increased linearly with concentration of catechin from 5.0 × 10(-9) to 1.0 × 10(-6) M and the limit of detection was 1.0 × 10(-9) M. The proposed method was applied to determine catechin in green tea. The recoveries are from 90% to 110% which benefits the actual application for green tea samples.

Oxygen and indocyanine green loaded phase-transition nanoparticle-mediated photo-sonodynamic cytotoxic effects on rheumatoid arthritis fibroblast-like synoviocytes.

PubMed

Tang, Qin; Cui, Jianyu; Tian, Zhonghua; Sun, Jiangchuan; Wang, Zhigang; Chang, Shufang; Zhu, Shenyin

2017-01-01

Photodynamic therapy and sonodynamic therapy are developing, minimally invasive, and site-specific modalities for cancer therapy. A combined strategy PSDT (photodynamic therapy followed by sonodynamic therapy) has been proposed in this study. Here, we aimed to develop novel biodegradable poly(DL-lactide- co -glycolic acid) phase-transition nanoparticles simultaneously loaded with oxygen and indocyanine green (OI-NPs) and to investigate the cytotoxic effects and the potential mechanisms of OI-NP-mediated PSDT on MH7A synoviocytes. The OI-NPs were prepared using a modified double emulsion method and the physicochemical properties were determined. The cellular uptake of OI-NPs was detected by confocal microscopy and flow cytometry. 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazoliumbromide assay, flow cytometry, and Hoechst 33342/propidium iodide double staining were used to determine the cytotoxic effect of OI-NP-mediated PSDT on MH7A cells. Fluorescence microscope and fluorescence microplate reader were used to detect reactive oxygen species (ROS) generation. The OI-NPs were a stable and efficient carrier to deliver oxygen and indocyanine green, and enhanced cellular uptake was observed in MH7A cells with the nanoparticles. OI-NP-mediated PSDT caused more serious cell damage and more evident cell apoptosis, compared with other groups. Furthermore, increased generation of intracellular ROS was detected in MH7A cells treated with PSDT. Interestingly, the OI-NP-mediated PSDT-induced cell viability loss was effectively rescued by pretreatment with the ROS scavenger N -acetylcysteine. Multifunctional OI-NPs were successfully developed and characterized for the combined delivery of oxygen and indocyanine green, and OI-NP-mediated PSDT would be a potential cytotoxic treatment for MH7A cells. This study may provide a novel strategy for the treatment of RA and develop a model of theranostic application through phase-transition nanoparticle-mediated PSDT in the future.

Oxygen and indocyanine green loaded phase-transition nanoparticle-mediated photo-sonodynamic cytotoxic effects on rheumatoid arthritis fibroblast-like synoviocytes

PubMed Central

Tang, Qin; Cui, Jianyu; Tian, Zhonghua; Sun, Jiangchuan; Wang, Zhigang; Chang, Shufang; Zhu, Shenyin

2017-01-01

Background Photodynamic therapy and sonodynamic therapy are developing, minimally invasive, and site-specific modalities for cancer therapy. A combined strategy PSDT (photodynamic therapy followed by sonodynamic therapy) has been proposed in this study. Here, we aimed to develop novel biodegradable poly(DL-lactide-co-glycolic acid) phase-transition nanoparticles simultaneously loaded with oxygen and indocyanine green (OI-NPs) and to investigate the cytotoxic effects and the potential mechanisms of OI-NP–mediated PSDT on MH7A synoviocytes. Methods The OI-NPs were prepared using a modified double emulsion method and the physicochemical properties were determined. The cellular uptake of OI-NPs was detected by confocal microscopy and flow cytometry. 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazoliumbromide assay, flow cytometry, and Hoechst 33342/propidium iodide double staining were used to determine the cytotoxic effect of OI-NP–mediated PSDT on MH7A cells. Fluorescence microscope and fluorescence microplate reader were used to detect reactive oxygen species (ROS) generation. Results The OI-NPs were a stable and efficient carrier to deliver oxygen and indocyanine green, and enhanced cellular uptake was observed in MH7A cells with the nanoparticles. OI-NP–mediated PSDT caused more serious cell damage and more evident cell apoptosis, compared with other groups. Furthermore, increased generation of intracellular ROS was detected in MH7A cells treated with PSDT. Interestingly, the OI-NP–mediated PSDT-induced cell viability loss was effectively rescued by pretreatment with the ROS scavenger N-acetylcysteine. Conclusion Multifunctional OI-NPs were successfully developed and characterized for the combined delivery of oxygen and indocyanine green, and OI-NP–mediated PSDT would be a potential cytotoxic treatment for MH7A cells. This study may provide a novel strategy for the treatment of RA and develop a model of theranostic application through phase

SEPARATION OF SOME RARE EARTHS BY REVERSED-PHASE PARTITION CHROMATOGRAPHY. Report No. 129/V; Rozdzielenie Niektorych Ziem Rzadkich za Pomoca Chromatografii Podzialowej z Odwroconymi Fazami

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siekierski, S.; Fidelis, I.

1960-01-01

The reversed phase partition chromatography was applied to the separation of small amounts of some rare earths. As a stationary phase TBP was used. and the elution was carried out with concentrated HNO/sub 3/. (auth)

The quiet evening auroral arc and the structure of the growth phase near-Earth plasma sheet

NASA Astrophysics Data System (ADS)

Coroniti, F. V.; Pritchett, P. L.

2014-03-01

The plasma pressure and current configuration of the near-Earth plasma sheet that creates and sustains the quiet evening auroral arc during the growth phase of magnetospheric substorms is investigated. We propose that the quiet evening arc (QEA) connects to the thin near-Earth current sheet, which forms during the development of the growth phase enhancement of convection. The current sheet's large polarization electric fields are shielded from the ionosphere by an Inverted-V parallel potential drop, thereby producing the electron precipitation responsible for the arc's luminosity. The QEA is located in the plasma sheet region of maximal radial pressure gradient and, in the east-west direction, follows the vanishing of the approximately dawn-dusk-directed gradient or fold in the plasma pressure. In the evening sector, the boundary between the Region1 and Region 2 current systems occurs where the pressure maximizes (approximately radial gradient of the pressure vanishes) and where the approximately radial gradient of the magnetic flux tube volume also vanishes in an inflection region. The proposed intricate balance of plasma sheet pressure and currents may well be very sensitive to disruption by the arrival of equatorward traveling auroral streamers and their associated earthward traveling dipolarization fronts.

Fabrication of Rare-earth Aluminate (ReAlO3) Glass and Crystalline phases by Aerodynamic Levitation (ADL)

NASA Astrophysics Data System (ADS)

Basavalingu, B.; Yoda, Shinichi; Kumar, M. S. Vijaya

2012-07-01

Containerless processing by levitation technique has been extensively used for material science and engineering because it suppresses inhomogeneous nucleation from the container wall and helps to produce stable, metastable and glass phases. The containerless levitation technique is widely explored for material processing because of its technological and scientific advantages. Recently, research on bulk glass and glass-ceramics have attracted the attention of material scientists as they are considered as low cost optical materials of the future. In the present study, the formation of bulk spherical glass and crystalline ReAlO _{3}(Re=La-Lu,Y) phases has been investigated due to their unique features in terms of the solidification process from an undercooled melt, glass structure and optical properties. An Aerodynamic levitation (ADL) was used to undercool the melt well below the melting temperature. Sintered bits of ReAlO _{3} sample with a diameter of ~2.5 mm and mass of ~20-25 mg was levitated by an ADL and completely melted by a CO _{2} laser and then the droplet was cooled by turning off the CO _{2} laser and solidified. The surface temperature and solidification process of the levitated droplet was monitored using pyrometer and high speed video camera, respectively. Among the rare earth aluminum perovskites Lanthanum, Neodymium and samarium aluminum perovskites solidified as glass and others YAlO _{3} and Europium to Lutetium aluminum perovskites solidified as crystalline phases. The scanning electron microscopy (SEM) images of cross-sectioned samples, TG/DTA, Transmittance and Refractive Index studies were performed for both glass and crystalline phases. The results of the above studies revealed the formation of glass and crystalline phases directly from the undercooled melt. The glass transition temperature (Tg) gradually increased with increasing ionic radius of the rare-earth elements. The NdAlO _{3} glass phase showed a high refractive index of ~1

Earth observation taken by the Expedition 43 crew.

NASA Image and Video Library

2015-03-13

Earth observation taken during a day pass by the Expedition 43 crew aboard the International Space Station (ISS). Sent as part of Twitter message: #HappyStPatrickDay with best wishes from the #E43 crew! From space you can see the “Emerald Isle” is very green!

Scattering - a probe to Earth's small scale structure

NASA Astrophysics Data System (ADS)

Rost, S.; Earle, P.

2009-05-01

Much of the short-period teleseismic wavefield shows strong evidence for scattered waves in extended codas trailing the main arrivals predicted by ray theory. This energy mainly originates from high-frequency body waves interacting with fine-scale volumetric heterogeneities in the Earth. Studies of this energy revealed much of what we know about Earth's structure at scale lengths around 10 km throughout the Earth from crust to core. From these data we can gain important information about the mineral-physical and geochemical constitution of the Earth that is inaccessible to many other seismic imaging techniques. Previous studies used scattered energy related to PKP, PKiKP, and Pdiff to identify and map the small-scale structure of the mantle and core. We will present observations related to the core phases PKKP and P'P' to study fine-scale mantle heterogeneities. These phases are maximum travel-time phases with respect to perturbations at their reflection points. This allows observation of the scattered energy as precursors to the main phase avoiding common problems with traditional coda phases which arrive after the main pulse. The precursory arrival of the scattered energy allows the separation between deep Earth and crustal contributions to the scattered wavefield for certain source-receiver configurations. Using the information from these scattered phases we identify regions of the mantle that shows increased scattering potential likely linked to larger scale mantle structure identified in seismic tomography and geodynamical models.

SALICYLATE PROCESS FOR THORIUM SEPARATION FROM RARE EARTHS

DOEpatents

Cowan, G.A.

1959-08-25

The separation of thorium from rare earths is accomplished by forming an aqueous solution of salts of thorium and rare earths and sufficient acetate buffer to provide a pH of between 2 and 5, adding an ammonium salicylate to the aqueous buffered solution, contacting the resultant solution with a substantially water-immiscible organic solvent mixture of an ether and an ester, and separating the solvent extract phase containing thorium salicylate from the aqueous phase containing the rare earths.

Earth and Moon as viewed from Mars

NASA Image and Video Library

2003-05-22

This is the first image of Earth ever taken from another planet that actually shows our home as a planetary disk. Because Earth and the Moon are closer to the Sun than Mars, they exhibit phases, just as the Moon, Venus, & Mercury do when viewed from Earth

Strong impacts of daily minimum temperature on the green-up date and summer greenness of the Tibetan Plateau.

PubMed

Shen, Miaogen; Piao, Shilong; Chen, Xiaoqiu; An, Shuai; Fu, Yongshuo H; Wang, Shiping; Cong, Nan; Janssens, Ivan A

2016-09-01

Understanding vegetation responses to climate change on the Tibetan Plateau (TP) helps in elucidating the land-atmosphere energy exchange, which affects air mass movement over and around the TP. Although the TP is one of the world's most sensitive regions in terms of climatic warming, little is known about how the vegetation responds. Here, we focus on how spring phenology and summertime greenness respond to the asymmetric warming, that is, stronger warming during nighttime than during daytime. Using both in situ and satellite observations, we found that vegetation green-up date showed a stronger negative partial correlation with daily minimum temperature (Tmin ) than with maximum temperature (Tmax ) before the growing season ('preseason' henceforth). Summer vegetation greenness was strongly positively correlated with summer Tmin , but negatively with Tmax . A 1-K increase in preseason Tmin advanced green-up date by 4 days (P < 0.05) and in summer enhanced greenness by 3.6% relative to the mean greenness during 2000-2004 (P < 0.01). In contrast, increases in preseason Tmax did not advance green-up date (P > 0.10) and higher summer Tmax even reduced greenness by 2.6% K(-1) (P < 0.05). The stimulating effects of increasing Tmin were likely caused by reduced low temperature constraints, and the apparent negative effects of higher Tmax on greenness were probably due to the accompanying decline in water availability. The dominant enhancing effect of nighttime warming indicates that climatic warming will probably have stronger impact on TP ecosystems than on apparently similar Arctic ecosystems where vegetation is controlled mainly by Tmax . Our results are crucial for future improvements of dynamic vegetation models embedded in the Earth System Models which are being used to describe the behavior of the Asian monsoon. The results are significant because the state of the vegetation on the TP plays an important role in steering the monsoon. © 2016 John Wiley

Rare earth activated yttrium aluminate phosphors with modulated luminescence.

PubMed

Muresan, L E; Popovici, E J; Perhaita, I; Indrea, E; Oro, J; Casan Pastor, N

2016-06-01

Yttrium aluminate (Y3 A5 O12 ) was doped with different rare earth ions (i.e. Gd(3+) , Ce(3+) , Eu(3+) and/or Tb(3+) ) in order to obtain phosphors (YAG:RE) with general formula,Y3-x-a Gdx REa Al5 O12 (x = 0; 1.485; 2.97 and a = 0.03). The synthesis of the phosphor samples was done using the simultaneous addition of reagents technique. This study reveals new aspects regarding the influence of different activator ions on the morpho-structural and luminescent characteristics of garnet type phosphor. All YAG:RE phosphors are well crystallized powders containing a cubic-Y3 Al5 O12 phase as major component along with monoclinic-Y4 Al2 O9 and orthorhombic-YAlO3 phases as the impurity. The crystallites dimensions of YAG:RE phosphors vary between 38 nm and 88 nm, while the unit cell slowly increase as the ionic radius of the activator increases. Under UV excitation, YAG:Ce exhibits yellow emission due to electron transition in Ce(3+) from the 5d level to the ground state levels ((2) F5/2 , (2) F7/2 ). The emission intensity of Ce(3+) is enhanced in the presence of the Tb(3+) ions and is decreased in the presence of Eu(3+) ions due to some radiative or non-radiative processes that take place between activator ions. By varying the rare earth ions, the emission colour can be modulated from green to white and red. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

Comment on "Satellites reveal contrasting responses of regional climate to the widespread greening of Earth".

PubMed

Li, Yue; Zeng, Zhenzhong; Huang, Ling; Lian, Xu; Piao, Shilong

2018-06-15

Forzieri et al (Reports, 16 June 2017, p. 1180) used satellite data to show that boreal greening caused regional warming. We show that this positive sensitivity of temperature to the greening can be derived from the positive response of vegetation to boreal warming, which indicates that results from a statistical regression with satellite data should be carefully interpreted. Copyright © 2018, American Association for the Advancement of Science.

Measurements of reciprocity law failure in green-sensitive X-ray films.

PubMed

Arnold, B A; Eisenberg, H; Bjärngard, B E

1978-02-01

Reciprocity law failure was measured for four brands of medical x-ray films exposed with intensifying screens. Three of the films are green light-sensitized for use in combination with green light-emitting rare-earth screens. These films showed larger reciprocity failure effects than one conventional blue-sensitive film, Dupont Cronex-2. Development conditions had a small effect on reciprocity failure. As part of the investigation, a detector was constructed with a response that accurately monitors the light emission from the double screen-cassette combination over a wide range of x-ray photon energies.

University of Rhode Island Regional Earth Systems Center

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rothstein, Lewis; Cornillon, P.

The primary objective of this program was to establish the URI Regional Earth System Center (“Center”) that would enhance overall societal wellbeing (health, financial, environmental) by utilizing the best scientific information and technology to achieve optimal policy decisions with maximum stakeholder commitment for energy development, coastal environmental management, water resources protection and human health protection, while accelerating regional economic growth. The Center was to serve to integrate existing URI institutional strengths in energy, coastal environmental management, water resources, and human wellbeing. This integrated research, educational and public/private sector outreach Center was to focus on local, state and regional resources. Themore » centerpiece activity of the Center was in the development and implementation of integrated assessment models (IAMs) that both ‘downscaled’ global observations and interpolated/extrapolated regional observations for analyzing the complexity of interactions among humans and the natural climate system to further our understanding and, ultimately, to predict the future state of our regional earth system. The Center was to begin by first ‘downscaling’ existing global earth systems management tools for studying the causes of local, state and regional climate change and potential social and environmental consequences, with a focus on the regional resources identified above. The Center would ultimately need to address the full feedbacks inherent in the nonlinear earth systems by quantifying the “upscaled” impacts of those regional changes on the global earth system. Through an interacting suite of computer simulations that are informed by observations from the nation’s evolving climate observatories, the Center activities integrates climate science, technology, economics, and social policy into forecasts that will inform solutions to pressing issues in regional climate change science, ‘green

Green power: A renewable energy resources marketing plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barr, R.C.

Green power is electricity generated from renewable energy sources such as power generated from the sun, the wind, the heat of the earth, and biomass. Green pricing is the marketing strategy to sell green power to customers who voluntarily pay a premium for it. Green pricing is evolving from the deregulation of the electric industry, the need for clean air, reflected in part as concern over global warming, and technology advances. The goal of the renewable energy marketing plan is to generate enough revenues for a utility to fund power purchase agreements (PPAs) with renewable energy developers or construct itsmore » own renewable facilities. Long-term, fixed price PPAs enable developers to obtain financing to construct new facilities, sometimes taking technological risks which a utility might not take otherwise. The marketing plan is built around different rate premiums for different categories of ratepayers, volunteer customer participation, customer participation recognition, and budget allocations between project costs and power marketing costs. Green prices are higher than those for conventional sources, particularly prices from natural gas fired plants. Natural gas is abundant relative to oil in price per British thermal unit (Btu). Green pricing can help bridge the gap between the current oversupply of gas and the time, not far off, when all petroleum prices will exceed those for renewable energy. The rapid implementation of green pricing is important. New marketing programs will bolster the growing demand for renewable energy evidenced in many national surveys thus decreasing the consumption of power now generated by burning hydrocarbons. This paper sets forth a framework to implement a green power marketing plan for renewable energy developers and utilities working together.« less

Mobile Bay, Alabama area seen in Skylab 4 Earth Resources Experiment Package

NASA Technical Reports Server (NTRS)

1974-01-01

A near vertical view of the Mobile Bay, Alabama area seen in this Skylab 4 Earth Resources Experiment Package S190-B (five-inch earth terrain camera) photograph taken from the Skylab space station in earth orbit. North of Mobile the Tombigbee and Alabama Rivers join to form the Mobile River. Detailed configuration of the individual stream channels and boundaries can be defined as the Mobile River flows into Mobile Bay and into the Gulf of Mexico. The Mobile River Valley with its numerous stream channels is a distinct light shade in contrast to the dark green shade of the adjacent areas. The red coloration of Mobile Bay reflects the sediment load carried into the bay by the rivers. The westerly movement of the shore currents at the mouth of Mobile Bay is shown by the contrasting light blue of the sediment-laden current the the blue of the Gulf. Agricultural areas east and west of Mobile Bay are characterized by a rectangular pattern in green to white shades. Color variations may reflect

Determination of malachite green and its leuco form in water

USGS Publications Warehouse

Allen, J.L.; Meinertz, J.R.; Gofus, J.E.

1992-01-01

Liquid chromatographic (lc) analysis can detect malachite green residues in water at less than 10 mu-g/l. Water samples were concentrated on disposable diol columns, eluted with 0.05m P-toluene-sulfonic acid in methanol, and determined by reversed-phase lc. When combined with a lead oxide postcolumn reactor, the lc method can simultaneously determine both leuco and chromatic forms of malachite green. Recoveries averaged 95.4% For the chromatic form and 57.3% For the leuco form of malachite green oxalate and leuco malachite green in spiked pond water samples. Recoveries of the carbinol form of malachite green (an equilibrium product of the dye in water) from spiked tap water samples averaged 98.6%. Recoveries of leuco malachite green were low and ph-dependent.

Greens of the European Green Capitals

NASA Astrophysics Data System (ADS)

Cömertler, Seval

2017-10-01

Well established and maintained green areas have a key role on reaching the high quality of life and sustainability in urban environments. Therefore, green areas must be carefully accounted and evaluated in the urban planning affairs. In this context, the European Green Capitals, which attach a great importance to the green areas, have a great potential to act as a role model for both small and big cities in all around the world. These leading cities (chronologically, Stockholm, Hamburg, Vitoria-Gasteiz, Nantes, Copenhagen, Bristol, Ljubljana, Essen and Nijmegen) are inspiring for the other cities which seek to achieve more sustainable and environmentally friendly places through green areas. From this point of view, the aim of this paper was to investigate the green areas of the European Green Capitals. The paper covered whole European Green Capitals, and the application form of each Green Capital was used as a primary data source. Consequently, the paper put forwarded that the European Green Capitals have considerably large amount and high proportion of green areas. Further, these cities provide an excellent access to the public green areas. As a result of abundant provision and proper distribution, the almost all citizens in most of the Green Capitals live within a distance of 300 meters to a green area. For further researches, the paper suggested that these green capitals should be investigated in terms of their efforts, measures, goals and plans, policies and implications to administer, to protect, to enhance and to expand the green areas.

Green synthesis of isopropyl myristate in novel single phase medium Part II: Packed bed reactor (PBR) studies.

PubMed

Vadgama, Rajeshkumar N; Odaneth, Annamma A; Lali, Arvind M

2015-12-01

Isopropyl myristate is a useful functional molecule responding to the requirements of numerous fields of application in cosmetic, pharmaceutical and food industry. In the present work, lipase-catalyzed production of isopropyl myristate by esterification of myristic acid with isopropyl alcohol (molar ratio of 1:15) in the homogenous reaction medium was performed on a bench-scale packed bed reactors, in order to obtain suitable reaction performance data for upscaling. An immobilized lipase B from Candida antartica was used as the biocatalyst based on our previous study. The process intensification resulted in a clean and green synthesis process comprising a series of packed bed reactors of immobilized enzyme and water dehydrant. In addition, use of the single phase reaction system facilitates efficient recovery of the product with no effluent generated and recyclability of unreacted substrates. The single phase reaction system coupled with a continuous operating bioreactor ensures a stable operational life for the enzyme.

Protective effects of Asian green vegetables against oxidant induced cytotoxicity

PubMed Central

Rose, Peter; Ong, Choon Nam; Whiteman, Matt

2005-01-01

AIM: To evaluate the antioxidant and phase II detoxification enzyme inducing ability of green leaf vegetables consumed in Asia. METHODS: The antioxidant properties of six commonly consumed Asian vegetables were determined using the ABTS, DPPH, deoxyribose, PR bleaching and iron- ascorbate induced lipid peroxidation assay. Induce of phase II detoxification enzymes was also determined for each respective vegetable extract. Protection against authentic ONOO- and HOCl mediated cytotoxicity in human colon HCT116 cells was determined using the MTT 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrasodium bromide) viability assay. RESULTS: All of the extracts derived from green leaf vegetables exhibited antioxidant properties, while also having cytoprotective effects against ONOO- and HOCl mediated cytotoxicity. In addition, evaluation of the phase II enzyme inducing ability of each extract, as assessed by quinone reductase and glutathione-S-transferase activities, showed significant variation between the vegetables analyzed. CONCLUSION: Green leaf vegetables are potential sources of antioxidants and phase II detoxification enzyme inducers in the Asian diet. It is likely that consumption of such vegetables is a major source of beneficial phytochemical constituents that may protect against colonic damage. PMID:16437686

Phase- and size-controllable synthesis of hexagonal upconversion rare-earth fluoride nanocrystals through an oleic acid/ionic liquid two-phase system.

PubMed

He, Meng; Huang, Peng; Zhang, Chunlei; Ma, Jiebing; He, Rong; Cui, Daxiang

2012-05-07

Herein, we introduce a facile, user- and environmentally friendly (n-octanol-induced) oleic acid (OA)/ionic liquid (IL) two-phase system for the phase- and size-controllable synthesis of water-soluble hexagonal rare earth (RE = La, Gd, and Y) fluoride nanocrystals with uniform morphologies (mainly spheres and elongated particles) and small sizes (<50 nm). The unique role of the IL 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF(6)) and n-octanol in modulating the phase structure and particle size are discussed in detail. More importantly, the mechanism of the (n-octanol-induced) OA/IL two-phase system, the formation of the RE fluoride nanocrystals, and the distinctive size- and morphology-controlling capacity of the system are presented. BmimPF(6) is versatile in term of crystal-phase manipulation, size and shape maintenance, and providing water solubility in a one-step reaction. The luminescent properties of Er(3+)-, Ho(3+)-, and Tm(3+)-doped LaF(3), NaGdF(4), and NaYF(4) nanocrystals were also studied. It is worth noting that the as-prepared products can be directly dispersed in water due to the hydrophilic property of Bmim(+) (cationic part of the IL) as a capping agent. This advantageous feature has made the IL-capped products favorable in facile surface modifications, such as the classic Stober method. Finally, the cytotoxicity evaluation of NaYF(4):Yb,Er nanocrystals before and after silica coating was conducted for further biological applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Competing phases, phase separation, and coexistence in the extended one-dimensional bosonic Hubbard model

DOE PAGES

Batrouni, G. G.; Rousseau, V. G.; Scalettar, R. T.; ...

2014-11-17

Here, we study the phase diagram of the one-dimensional bosonic Hubbard model with contact (U) and near neighbor (V ) interactions focusing on the gapped Haldane insulating (HI) phase which is characterized by an exotic nonlocal order parameter. The parameter regime (U, V and μ) where this phase exists and how it competes with other phases such as the supersolid (SS) phase, is incompletely understood. We use the Stochastic Green Function quantum Monte Carlo algorithm as well as the density matrix renormalization group to map out the phase diagram. The HI exists only at = 1, the SS phase existsmore » for a very wide range of parameters (including commensurate fillings) and displays power law decay in the one body Green function were our main conclusions. Additionally, we show that at fixed integer density, the system exhibits phase separation in the (U, V ) plane.« less

Overview of Japanese Earth observation programs

NASA Astrophysics Data System (ADS)

Shimoda, Haruhisa; Honda, Yoshiaki

2017-09-01

Five programs, i.e. ASTER, GOSAT, GCOM-W1, GPM and ALOS-2 are going on in Japanese Earth Observation programs. ASTER has lost its short wave infrared channels. AMSR-E stopped its operation, but it started its operation from Sep. 2012 with slow rotation speed. It finally stopped on December 2015. GCOM-W1 was launched on 18, May, 2012 and is operating well as well as GOSAT. ALOS (Advanced Land Observing Satellite) was successfully launched on 24th Jan. 2006. ALOS carries three instruments, i.e., PRISM (Panchromatic Remote Sensing Instrument for Stereo Mapping), AVNIR-2 (Advanced Visible and Near Infrared Radiometer), and PALSAR (Phased Array L band Synthetic Aperture Radar). Unfortunately, ALOS has stopped its operation on 22nd, April, 2011 by power loss. GOSAT (Greenhouse Gas Observation Satellite) was successfully launched on 29, January, 2009. GOSAT carries 2 instruments, i.e. a green house gas sensor (TANSO-FTS) and a cloud/aerosol imager (TANSO-CAI). The main sensor is a Fourier transform spectrometer (FTS) and covers 0.76 to 15 μm region with 0.2 to 0.5 cm-1 resolution. SMILES (Superconducting Millimeter wave Emission Spectrometer) was launched on September 2009 to ISS and started the observation, but stopped its operation on April 2010. GPM (Global Precipitation Mission) core satellite was launched on Feb. 2014. GPM is a joint project with NASA and carries two instruments. JAXA has developed DPR (Dual frequency Precipitation Radar) which is a follow on of PR on TRMM. ALOS F/O satellites are divided into two satellites, i.e. SAR and optical satellites. The first one of ALOS F/O is called ALOS 2 and carries L-band SAR. It was launched on May 2014. JAXA is planning to launch follow on of optical sensors. It is now called Advanced Optical Satellite and the planned launch date is fiscal 2019. Other future satellites are GCOM-C1 (ADEOS-2 follow on), GOSAT-2 and EarthCare. GCOM-C1 will be launched on 2017 and GOSAT-2 will be launched on fiscal 2018. Another project

Multi-spacecraft observations of ICMEs propagating beyond Earth orbit during MSL/RAD flight and surface phases

NASA Astrophysics Data System (ADS)

von Forstner, J.; Guo, J.; Wimmer-Schweingruber, R. F.; Hassler, D.; Temmer, M.; Vrsnak, B.; Čalogović, J.; Dumbovic, M.; Lohf, H.; Appel, J. K.; Heber, B.; Steigies, C. T.; Zeitlin, C.; Ehresmann, B.; Jian, L. K.; Boehm, E.; Boettcher, S. I.; Burmeister, S.; Martin-Garcia, C.; Brinza, D. E.; Posner, A.; Reitz, G.; Matthiae, D.; Rafkin, S. C.; weigle, G., II; Cucinotta, F.

2017-12-01

The propagation of interplanetary coronal mass ejections (ICMEs) between Earth's orbit (1 AU) and Mars ( 1.5 AU) has been studied with their propagation speed estimated from both measurements and simulations. The enhancement of the magnetic fields related to ICMEs and their shock fronts cause so-called Forbush decreases, which can be detected as a reduction of galactic cosmic rays measured on-ground or on a spacecraft. We have used galactic cosmic ray (GCR) data from in-situ measurements at Earth, from both STEREO A and B as well as the GCR measurement by the Radiation Assessment Detector (RAD) instrument onboard Mars Science Laboratory (MSL) on the surface of Mars as well as during its flight to Mars in 2011-2012. A set of ICME events has been selected during the periods when Earth (or STEREO A or B) and MSL locations were nearly aligned on the same side of the Sun in the ecliptic plane (so-called opposition phase). Such lineups allow us to estimate the ICMEs' transit times between 1 AU and the MSL location by estimating the delay time of the corresponding Forbush decreases measured at each location. We investigate the evolution of their propagation speeds after passing Earth's orbit and find that the deceleration of ICMEs due to their interaction with the ambient solar wind continues beyond 1 AU. The results are compared to simulation data obtained from two CME propagation models, namely the Drag-Based Model (DBM) and the WSA-ENLIL plus cone model.

Properties of iron alloys under the Earth's core conditions

NASA Astrophysics Data System (ADS)

Morard, Guillaume; Andrault, Denis; Antonangeli, Daniele; Bouchet, Johann

2014-05-01

The Earth's core is constituted of iron and nickel alloyed with lighter elements. In view of their affinity with the metallic phase, their relative high abundance in the solar system and their moderate volatility, a list of potential light elements have been established, including sulfur, silicon and oxygen. We will review the effects of these elements on different aspects of Fe-X high pressure phase diagrams under Earth's core conditions, such as melting temperature depression, solid-liquid partitioning during crystallization, and crystalline structure of the solid phases. Once extrapolated to the inner-outer core boundary, these petrological properties can be used to constrain the Earth's core properties.

Anisotropy of Earth's D'' layer and stacking faults in the MgSiO3 post-perovskite phase.

PubMed

Oganov, Artem R; Martonák, Roman; Laio, Alessandro; Raiteri, Paolo; Parrinello, Michele

2005-12-22

The post-perovskite phase of (Mg,Fe)SiO3 is believed to be the main mineral phase of the Earth's lowermost mantle (the D'' layer). Its properties explain numerous geophysical observations associated with this layer-for example, the D'' discontinuity, its topography and seismic anisotropy within the layer. Here we use a novel simulation technique, first-principles metadynamics, to identify a family of low-energy polytypic stacking-fault structures intermediate between the perovskite and post-perovskite phases. Metadynamics trajectories identify plane sliding involving the formation of stacking faults as the most favourable pathway for the phase transition, and as a likely mechanism for plastic deformation of perovskite and post-perovskite. In particular, the predicted slip planes are {010} for perovskite (consistent with experiment) and {110} for post-perovskite (in contrast to the previously expected {010} slip planes). Dominant slip planes define the lattice preferred orientation and elastic anisotropy of the texture. The {110} slip planes in post-perovskite require a much smaller degree of lattice preferred orientation to explain geophysical observations of shear-wave anisotropy in the D'' layer.

A cavity radiometer for Earth albedo measurement, phase 1

NASA Technical Reports Server (NTRS)

1987-01-01

Radiometric measurements of the directional albedo of the Earth requires a detector with a flat response from 0.2 to 50 microns, a response time of about 2 seconds, a sensitivity of the order of 0.02 mw/sq cm, and a measurement uncertainty of less than 5 percent. Absolute cavity radiometers easily meet the spectral response and accuracy requirements for Earth albedo measurements, but the radiometers available today lack the necessary sensitivity and response time. The specific innovations addressed were the development of a very low thermal mass cavity and printed/deposited thermocouple sensing elements which were incorporated into the radiometer design to produce a sensitive, fast response, absolute radiometer. The cavity is applicable to the measurement of the reflected and radiated fluxes from the Earth surface and lower atmosphere from low Earth orbit satellites. The effort consisted of requirements and thermal analysis; design, construction, and test of prototype elements of the black cavity and sensor elements to show proof-of-concept. The results obtained indicate that a black body cavity sensor that has inherently a flat response from 0.2 to 50 microns can be produced which has a sensitivity of at least 0.02 mw/sq cm per micro volt ouput and with a time constant of less than two seconds. Additional work is required to develop the required thermopile.

Global demand for rare earth resources and strategies for green mining

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dutta, Tanushree

Rare earth elements (REEs) are essential raw materials for emerging renewable energy resources and ‘smart’ electronic devices. Global REE demand is slated to grow at an annual rate of 5% by 2020. This high growth rate will require a steady supply base of REEs in the long run. At present, China is responsible for 85% of global rare earth oxide (REO) production. To overcome this monopolistic supply situation, new strategies and investments are necessary to satisfy domestic supply demands. Concurrently, environmental, economic, and social problems arising from REE mining must be addressed. There is an urgent need to develop efficientmore » REE recycling techniques from end-of-life products, technologies to minimize the amount of REEs required per unit device, and methods to recover them from fly ash or fossil fuel-burning wastes.« less

Global demand for rare earth resources and strategies for green mining.

PubMed

Dutta, Tanushree; Kim, Ki-Hyun; Uchimiya, Minori; Kwon, Eilhann E; Jeon, Byong-Hun; Deep, Akash; Yun, Seong-Taek

2016-10-01

Rare earth elements (REEs) are essential raw materials for emerging renewable energy resources and 'smart' electronic devices. Global REE demand is slated to grow at an annual rate of 5% by 2020. This high growth rate will require a steady supply base of REEs in the long run. At present, China is responsible for 85% of global rare earth oxide (REO) production. To overcome this monopolistic supply situation, new strategies and investments are necessary to satisfy domestic supply demands. Concurrently, environmental, economic, and social problems arising from REE mining must be addressed. There is an urgent need to develop efficient REE recycling techniques from end-of-life products, technologies to minimize the amount of REEs required per unit device, and methods to recover them from fly ash or fossil fuel-burning wastes. Copyright © 2016 Elsevier Inc. All rights reserved.

Elastic properties and phase transitions of Fe7C3 and new constraints on the light element budget of the Earth's inner core

NASA Astrophysics Data System (ADS)

Prescher, C.; Bykova, E.; Kupenko, I.; Glazyrin, K.; Kantor, A.; McCammon, C. A.; Mookherjee, M.; Miyajima, N.; Cerantola, V.; Nakajima, Y.; Prakapenka, V.; Rüffer, R.; Chumakov, A.; Dubrovinsky, L. S.

2013-12-01

The Earth's inner core consists mainly of iron (or iron-nickel alloy) with some amount of light element(s) whereby their nature remains controversial. Seismological data suggest that the material forming Earth's inner core (pressures over 330 GPa and temperatures above 5000 K) has an enigmatically high Poisson's ratio ~0.44, while iron or it alloys with Si, S, O, or H expected to have at appropriate thermodynamic conditions Poisson's ratio well below 0.39. We will present an experimental study on a new high pressure variant in the iron carbide system. We have synthesized and solved structure of high-pressure orthorhombic phase of o-Fe7C3, and investigated its stability and behavior at pressures over 180 GPa and temperatures above 3500 K by means of different methods including single crystal X-ray diffraction, Mössbauer spectroscopy, and nuclear resonance scattering. O-Fe7C3 is structurally stable to at least outer core conditions and demonstrates magnetic or electronic transitions at ~18 GPa and ~70 GPa. The high pressure phase of o-Fe7C3 above 70 GPa exhibits anomalous elastic properties. When extrapolated to the conditions of the Earth's inner core it shows shear wave velocities and Poisson's ratios close to the values inferred by seismological models. Our results not only support earlier works suggesting that carbon may be an important component of Earth's core, but shows that it may drastically change iron's elastic properties, thus explaining anomalous Earth's inner core elastic properties.

Mobile Bay, Alabama area seen in Skylab 4 Earth Resources Experiment Package

NASA Image and Video Library

1974-02-01

SL4-92-300 (February 1974) --- A near vertical view of the Mobile Bay, Alabama area is seen in this Skylab 4 Earth Resources Experiments Package S190-B (five-inch earth terrain camera) photograph taken from the Skylab space station in Earth orbit. North of Mobile the Tombigbee and Alabama Rivers join to form the Mobile River. Detailed configuration of the individual stream channels and boundaries can be defined as the Mobile River flows into Mobile Bay, and thence into the Gulf of Mexico. The Mobile River Valley with its numerous stream channels is a distinct light shade in contrast to the dark green shade of the adjacent areas. The red coloration of Mobile Bay reflects the sediment load carried into the Bay by the rivers. Variations in red color indicate sediment load and the current paths within Mobile Bay. The waterly movement of the along shore currents at the mouth of Mobile Bay is shown by the contrasting light blue of the sediment-laden current and the blue of the Gulf predominately. Agricultural areas east and west of Mobile Bay are characterized by a rectangular pattern in green to white shades. Color variations may reflect the type and growth cycle of crops. Agricultural areas (light gray-greens) are also clearly visible in other parts of the photograph. Interstate 10 extends from near Pascagoula, Mississippi eastward through Mobile to the outskirts of Pensacola, Florida. Analysis of the EREP photographic data will be undertaken by the U.S. Corps of Engineers to determine bay dynamic processes. Federal agencies participating with NASA on the EREP project are the Departments of Agriculture, Commerce, Interior, the Environmental Protection Agency and the Corps of Engineers. All EREP photography is available to the public through the Department of Interior's Earth Resources Observations Systems Data Center, Sioux Falls, South Dakota. 57198 Photo credit: NASA

Quantitative phase imaging of human red blood cells using phase-shifting white light interference microscopy with colour fringe analysis

NASA Astrophysics Data System (ADS)

Singh Mehta, Dalip; Srivastava, Vishal

2012-11-01

We report quantitative phase imaging of human red blood cells (RBCs) using phase-shifting interference microscopy. Five phase-shifted white light interferograms are recorded using colour charge coupled device camera. White light interferograms were decomposed into red, green, and blue colour components. The phase-shifted interferograms of each colour were then processed by phase-shifting analysis and phase maps for red, green, and blue colours were reconstructed. Wavelength dependent refractive index profiles of RBCs were computed from the single set of white light interferogram. The present technique has great potential for non-invasive determination of refractive index variation and morphological features of cells and tissues.

Using EarthLabs to Enhance Earth Science Curriculum in Texas

NASA Astrophysics Data System (ADS)

Chegwidden, D. M.; Ellins, K. K.; Haddad, N.; Ledley, T. S.

2012-12-01

As an educator in Texas, a state that values and supports an Earth Science curriculum, I find it essential to educate my students who are our future voting citizens and tax payers. It is important to equip them with tools to understand and solve the challenges of solving of climate change. As informed citizens, students can help to educate others in the community with basic knowledge of weather and climate. They can also help to dispose of the many misconceptions that surround the climate change, which is perceived as a controversial topic. As a participant in a NSF-sponsored Texas Earth and Space (TXESS) Revolution teacher professional development program, I was selected to participate in a curriculum development project led by TERC to develop and test education resources for the EarthLabs climate literacy collection. I am involved in the multiple phases of the project, including reviewing labs that comprise the Climate, Weather and Biosphere module during the development phase, pilot teaching the module with my students, participating in research, and delivering professional development to other Texas teachers to expose them to the content found in the module and to encourage them to incorporate it into their teaching. The Climate, Weather and the Biosphere module emphasizes different forms of evidence and requires that learners apply different inquiry-based approaches to build the knowledge they need to develop as climate literate citizens. My involvement with the EarthLabs project has strengthened my overall knowledge and confidence to teach about Earth's climate system and climate change. In addition, the project has produced vigorous classroom discussion among my students as well as encouraged me to collaborate with other educators through our delivery of professional development to other teachers. In my poster, I will share my experiences, describe the impact the curriculum has made on my students, and report on challenges and valuable lessons gained by

Cloud-point extraction of green-polymers from Cupriavidus necator lysate using thermoseparating-based aqueous two-phase extraction.

PubMed

Leong, Yoong Kit; Lan, John Chi-Wei; Loh, Hwei-San; Ling, Tau Chuan; Ooi, Chien Wei; Show, Pau Loke

2017-03-01

Polyhydroxyalkanoates (PHAs), a class of renewable and biodegradable green polymers, have gained attraction as a potential substitute for the conventional plastics due to the increasing concern towards environmental pollution as well as the rapidly depleting petroleum reserve. Nevertheless, the high cost of downstream processing of PHA has been a bottleneck for the wide adoption of PHAs. Among the options of PHAs recovery techniques, aqueous two-phase extraction (ATPE) outshines the others by having the advantages of providing a mild environment for bioseparation, being green and non-toxic, the capability to handle a large operating volume and easily scaled-up. Utilizing unique properties of thermo-responsive polymer which has decreasing solubility in its aqueous solution as the temperature rises, cloud point extraction (CPE) is an ATPE technique that allows its phase-forming component to be recycled and reused. A thorough literature review has shown that this is the first time isolation and recovery of PHAs from Cupriavidus necator H16 via CPE was reported. The optimum condition for PHAs extraction (recovery yield of 94.8% and purification factor of 1.42 fold) was achieved under the conditions of 20 wt/wt % ethylene oxide-propylene oxide (EOPO) with molecular weight of 3900 g/mol and 10 mM of sodium chloride addition at thermoseparating temperature of 60°C with crude feedstock limit of 37.5 wt/wt %. Recycling and reutilization of EOPO 3900 can be done at least twice with satisfying yield and PF. CPE has been demonstrated as an effective technique for the extraction of PHAs from microbial crude culture. Copyright © 2016 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

The Sustainable University: Green Goals and New Challenges for Higher Education Leaders

ERIC Educational Resources Information Center

Martin, James; Samels, James E.

2012-01-01

Colleges and universities are at the forefront of efforts to preserve the earth's resources for future generations. Carbon neutrality, renewable energy sources, green building strategies, and related initiatives require informed and courageous leaders at all levels of higher education. James Martin and James E. Samels have worked closely with…

Critical evaluation and thermodynamic optimization of the Iron-Rare-Earth systems

NASA Astrophysics Data System (ADS)

Konar, Bikram

Rare-Earth elements by virtue of its typical magnetic, electronic and chemical properties are gaining importance in power, electronics, telecommunications and sustainable green technology related industries. The Magnets from RE-alloys are more powerful than conventional magnets which have more longevity and high temperature workability. The dis-equilibrium in the Rare-Earth element supply and demand has increased the importance of recycling and extraction of REE's from used permanent Magnets. However, lack of the thermodynamic data on RE alloys has made it difficult to design an effective extraction and recycling process. In this regard, Computational Thermodynamic calculations can serve as a cost effective and less time consuming tool to design a waste magnet recycling process. The most common RE permanent magnet is Nd magnet (Nd 2Fe14B). Various elements such as Dy, Tb, Pr, Cu, Co, Ni, etc. are also added to increase its magnetic and mechanical properties. In order to perform reliable thermodynamic calculations for the RE recycling process, accurate thermodynamic database for RE and related alloys are required. The thermodynamic database can be developed using the so-called CALPHAD method. The database development based on the CALPHAD method is essentially the critical evaluation and optimization of all available thermodynamic and phase diagram data. As a results, one set of self-consistent thermodynamic functions for all phases in the given system can be obtained, which can reproduce all reliable thermodynamic and phase diagram data. The database containing the optimized Gibbs energy functions can be used to calculate complex chemical reactions for any high temperature processes. Typically a Gibbs energy minimization routine, such as in FactSage software, can be used to obtain the accurate thermodynamic equilibrium in multicomponent systems. As part of a large thermodynamic database development for permanent magnet recycling and Mg alloy design, all

Design and optimization of a volume-phase holographic grating for simultaneous use with red, green, and blue light using unpolarized light.

PubMed

Mahamat, Adoum H; Narducci, Frank A; Schwiegerling, James

2016-03-01

Volume-phase holographic (VPH) gratings have been designed for use in many areas of science and technology, such as optical communication, optical imaging, and astronomy. In this paper, the design of a volume-phase holographic grating, simultaneously optimized to operate in the red, green, and blue wavelengths, is presented along with a study of its fabrication tolerances. The grating is optimized to produce 98% efficiency at λ=532  nm and at least 75% efficiency in the region between 400 and 700 nm, when the incident light is unpolarized. The optimization is done for recording in dichromated gelatin with a thickness of 12 μm, an average refractive index of 1.5, and a refractive index modulation of 0.022.

[How did the earth's oxygen atmosphere originate?].

PubMed

Schäfer, G

2004-09-01

The planet earth did not carry an oxygen atmosphere from the beginning. Though oxygen could arise from radiation mediated water splitting, these processes were not efficient enough to create a global gas atmosphere. Oxygen in the latter is a product of the photosynthetic activity of early green organisms. Only after biological mass-formation of oxygen the UV-protective ozone layer could develop, then enabeling life to move from water onto land. This took billions of years. The basics of the processes of biological oxygen liberation and utilization are described in the following as well as the importance of their steady state equilibrium. Also a hint is given to oxygen as a toxic compound though being a chemical prerequisite for aerobic life on earth.

Corrosion in drinking water pipes: the importance of green rusts.

PubMed

Swietlik, Joanna; Raczyk-Stanisławiak, Urszula; Piszora, Paweł; Nawrocki, Jacek

2012-01-01

Complex crystallographic composition of the corrosion products is studied by diffraction methods and results obtained after different pre-treatment of samples are compared. The green rusts are found to be much more abundant in corrosion scales than it has been assumed so far. The characteristic and crystallographic composition of corrosion scales and deposits suspended in steady waters were analyzed by X-ray diffraction (XRD). The necessity of the examination of corrosion products in the wet conditions is indicated. The drying of the samples before analysis is shown to substantially change the crystallographic phases originally present in corrosion products. On sample drying the unstable green rusts is converted into more stable phases such as goethite and lepidocrocite, while the content of magnetite and siderite decreases. Three types of green rusts in wet materials sampled from tubercles are identified. Unexpectedly, in almost all corrosion scale samples significant amounts of the least stable green rust in chloride form was detected. Analysis of corrosion products suspended in steady water, which remained between tubercles and possibly in their interiors, revealed complex crystallographic composition of the sampled material. Goethite, lepidocrocite and magnetite as well as low amounts of siderite and quartz were present in all samples. Six different forms of green rusts were identified in the deposits separated from steady waters and the most abundant was carbonate green rust GR(CO(3)(2-))(I). Copyright © 2011 Elsevier Ltd. All rights reserved.

EarthCache as a Tool to Promote Earth-Science in Public School Classrooms

NASA Astrophysics Data System (ADS)

Gochis, E. E.; Rose, W. I.; Klawiter, M.; Vye, E. C.; Engelmann, C. A.

2011-12-01

Geoscientists often find it difficult to bridge the gap in communication between university research and what is learned in the public schools. Today's schools operate in a high stakes environment that only allow instruction based on State and National Earth Science curriculum standards. These standards are often unknown by academics or are written in a style that obfuscates the transfer of emerging scientific research to students in the classroom. Earth Science teachers are in an ideal position to make this link because they have a background in science as well as a solid understanding of the required curriculum standards for their grade and the pedagogical expertise to pass on new information to their students. As part of the Michigan Teacher Excellence Program (MiTEP), teachers from Grand Rapids, Kalamazoo, and Jackson school districts participate in 2 week field courses with Michigan Tech University to learn from earth science experts about how the earth works. This course connects Earth Science Literacy Principles' Big Ideas and common student misconceptions with standards-based education. During the 2011 field course, we developed and began to implement a three-phase EarthCache model that will provide a geospatial interactive medium for teachers to translate the material they learn in the field to the students in their standards based classrooms. MiTEP participants use GPS and Google Earth to navigate to Michigan sites of geo-significance. At each location academic experts aide participants in making scientific observations about the locations' geologic features, and "reading the rocks" methodology to interpret the area's geologic history. The participants are then expected to develop their own EarthCache site to be used as pedagogical tool bridging the gap between standards-based classroom learning, contemporary research and unique outdoor field experiences. The final phase supports teachers in integrating inquiry based, higher-level learning student

Water and hydrogen are immiscible in Earth's mantle.

PubMed

Bali, Enikő; Audétat, Andreas; Keppler, Hans

2013-03-14

In the deep, chemically reducing parts of Earth's mantle, hydrous fluids contain significant amounts of molecular hydrogen (H2). Thermodynamic models of fluids in Earth's mantle so far have always assumed that molecular hydrogen and water are completely miscible. Here we show experimental evidence that water and hydrogen can coexist as two separate, immiscible phases. Immiscibility between water and hydrogen may be the cause of the formation of enigmatic, ultra-reducing domains in the mantle that contain moissanite (SiC) and other phases indicative of extremely reducing conditions. Moreover, the immiscibility between water and hydrogen may provide a mechanism for the rapid oxidation of Earth's upper mantle immediately following core formation.

Phase relations of iron and iron nickel alloys up to 300 GPa: Implications for composition and structure of the Earth's inner core

NASA Astrophysics Data System (ADS)

Kuwayama, Yasuhiro; Hirose, Kei; Sata, Nagayoshi; Ohishi, Yasuo

2008-09-01

We have investigated the phase relations of iron and iron-nickel alloys with 18 to 50 wt.% Ni up to over 300 GPa using a laser-heated diamond-anvil cell. The synchrotron X-ray diffraction measurements show the wide stability of hcp-iron up to 301 GPa and 2000 K and 319 GPa and 300 K without phase transition to dhcp, orthorhombic, or bcc phases. On the other hand, the incorporation of nickel has a remarkable effect on expanding the stability field of fcc phase. The geometry of the temperature-composition phase diagram of iron-nickel alloys suggests that the hcp-fcc-liquid triple point is located at 10 to 20 wt.% Ni at the pressure of the inner core boundary. The fcc phase could crystallize depending on the nickel and silicon contents in the Earth's core, both of which are fcc stabilizer.

Cancer prevention by green tea: evidence from epidemiologic studies.

PubMed

Yuan, Jian-Min

2013-12-01

In contrast to the consistent results of an inhibitory effect of green tea extracts and tea polyphenols on the development and growth of carcinogen-induced tumors in experimental animal models, results from human studies are mixed. Both observational and intervention studies have provided evidence in support of a protective role of green tea intake in the development of oral-digestive tract cancer or an inhibitory role of oral supplementation of green tea extract on a precancerous lesion of oral cavity. Evidence in support of green tea intake against the development of liver cancer risk is limited and inconsistent. An inverse association between green tea intake and lung cancer risk has been observed among never smokers but not among smokers. Although observational studies do not support a beneficial role of tea intake against the development of prostate cancer, several phase 2 clinical trials have shown an inhibitory effect of green tea extract against the progression of prostate premalignant lesions to malignant tumors. Prospective epidemiologic studies so far have not provided evidence for a protective effect of green tea consumption on breast cancer development. Current data neither confirm nor refute a definitive cancer-preventive role of green tea intake. Large randomized intervention trials on the efficacy of green tea polyphenols or extracts are required before a recommendation for green tea consumption for cancer prevention should be made.

Stability of the high pressure phase Fe3S2 up to Earth's core pressures in the Fe-S-O and the Fe-S-Si systems

NASA Astrophysics Data System (ADS)

Zurkowski, C. C.; Chidester, B.; Davis, A.; Brauser, N.; Greenberg, E.; Prakapenka, V. B.; Campbell, A.

2017-12-01

Earth's core is comprised of an iron-nickel alloy that contains 5-15% of a light element component. The abundance and alloying capability of sulfur, silicon and oxygen in the bulk Earth make them important core alloy candidates; therefore, the high-pressure phase equilibria of the Fe-S-O and Fe-S-Si systems are relevant for understanding the possible chemistry of Earth's core. Previously, a Fe3S2 phase was recognized as a low-pressure intermediate phase in the Fe-FeS system that is stable from 14-21 GPa, but the structure of this phase has not been resolved. We report in-situ XRD and chemical analysis of recovered samples to further examine the stability and structure of Fe3S2 as it coexists with other phases in the Fe-S-O and Fe-S-Si systems. In situ high P-T synchrotron XRD experiments were conducted in the laser-heated diamond anvil cell to determine the equilibrium phases in Fe75S7O18 and Fe80S5Si15 compositions between 30 and 174 GPa and up to 3000 K. In the S,O-rich samples, an orthorhombic Fe3S2 phase coexists with hcp-Fe, Fe3S and FeO and undergoes two monoclinic distortions between 60 and 174 GPa. In the S,Si-rich samples, the orthorhombic Fe3S2 phase was observed up to 115 GPa. With increasing pressure, the Fe3S2 phase becomes stable to higher temperatures in both compositions, suggesting possible Fe3(S,O)2 or Fe3(S,Si)2 solid solutions. SEM analysis of a laser heated Fe75S7O18 sample recovered from 40 GPa and 1450 K confirms a Fe3(S,O)2 phase with O dissolved into the structure. Based on the current melting data in the Fe-S-O and Fe-S-Si systems, the Fe3(S,O)2 stability field intersects the solidus in the outer core and could be a possible liquidus phase in Fe,S,O-rich planetary cores, whereas Fe3S is the stable sulfide at outer core pressures in Fe,S,Si-rich systems.

Earth observation

NASA Image and Video Library

2014-08-31

ISS040-E-113700 (31 Aug. 2014) --- This panorama view, photographed by an Expedition 40 crew member on the International Space Station, shows tan-colored dust of a major dust storm obscuring the Persian Gulf and the its northern shoreline. Strong north winds often blow in summer, churning up dust from the entire length of the desert surfaces of the Tigris and Euphrates valleys (top left). Dust partly obscures the hundreds of kilometers of Iraq’s light-green agricultural lands along these rivers (left). A line of thunderstorms is being set off by the Zagros Mountains of Iran (right), with the setting sun casting long shadows from the thunderheads. Space station crews see sixteen sunrises and sunsets every day from low Earth orbit. Here the crew captured dusk in a darkening Iranian landscape (right).

Earth Observation

NASA Image and Video Library

2011-07-15

ISS028-E-017123 (16 July 2011) --- Separate atmospheric optical phenomena were captured in this electronic still photograph from the Inernational Space Station. The thin greenish band stretching along the Earth's horizon is airglow; light emitted by the atmosphere from a layer about 30 kilometers thick and about 100 kilometers in altitude. The predominant emission in airglow is the green 5577 Angstrom wavelength light from atomic oxygen atoms. Airglow is always and everywhere present in the atmosphere; it results from the recombination of molecules that have been broken apart by solar radiation during the day. But airglow is so faint that it can only be seen at night by looking "edge on" at the emission layer, such as the view astronauts and cosmonauts have in orbit. The second phenomenon is the appearnce of Aurora Australis.

Surface loading of a viscoelastic earth-I. General theory

NASA Astrophysics Data System (ADS)

Tromp, Jeroen; Mitrovica, Jerry X.

1999-06-01

We present a new normal-mode formalism for computing the response of an aspherical, self-gravitating, linear viscoelastic earth model to an arbitrary surface load. The formalism makes use of recent advances in the theory of the Earth's free oscillations, and is based upon an eigenfunction expansion methodology, rather than the tradi-tional Love-number approach to surface-loading problems. We introduce a surface-load representation theorem analogous to Betti's reciprocity relation in seismology. Taking advantage of this theorem and the biorthogonality of the viscoelastic modes, we determine the complete response to a surface load in the form of a Green's function. We also demonstrate that each viscoelastic mode has its own unique energy partitioning, which can be used to characterize it. In subsequent papers, we apply the theory to spherically symmetric and aspherical earth models.

The Fe-Ni-(S) System at 23 GPa: The Possibility of Strong Chemical Fractionation Between Phases in the Cores of the Earth, Mars and Mercury

NASA Astrophysics Data System (ADS)

Stewart, A. J.; Schmidt, M. W.

2004-12-01

The presence of nickel in the Earths core is widely accepted based on cosmochemical and seismological arguments. However, experimental studies into core compositions rarely include nickel, thus adding a degree of simplicity to otherwise complex experiments. Diamond-anvil cell studies have discovered that Fe-Ni alloys appear to separate into two phases upon heating above 10 GPa: from a single hexagonally close-packed (hcp) phase to the presence of both hcp and face centered cubic (fcc) phases (Lin et al., 2002). Unfortunately, due to the small size of diamond-anvil cell samples, meaningful quantitative analysis is commonly impossible. We have conducted multi-anvil experiments at 23 GPa into the Fe-Ni system and have confirmed the presence of two phases in the sub-solidus system. The starting material for these experiments contains 6 wt% nickel, approximating the amount expected to be found in the Earths core (McDonough, 2003). In experiments to 1500° C (the highest temperature thus far examined), electron microprobe analyses show dramatic phase fractionation with charges separating into an iron-rich phase containing less than 1 wt% Ni and a nickel-rich phase containing as much as 98 wt% Ni. We have observed the effect over a range of more than 500° ºC; further experiments are underway to determine whether these phases both persist toward the melting point of the alloy. Multi-anvil experiments at 23 GPa have also been conducted to examine the effect of nickel on the Fe-S system. Sulphur is an element favoured by many researchers as the light element component in the core of the Earth as well as that of Mars. Previous research has suggested that the addition of nickel to the Fe-S system results in the lowering of eutectic temperatures by about 75° C (Pike et al., 1999). The starting material for these experiments is the same as that used for the pure Fe-Ni experiments discussed above, with the addition of sulphur. Our results indicate a pseudo-binary, (Fe, Ni

LIDAR technology developments in support of ESA Earth observation missions

NASA Astrophysics Data System (ADS)

Durand, Yannig; Caron, Jérôme; Hélière, Arnaud; Bézy, Jean-Loup; Meynart, Roland

2017-11-01

Critical lidar technology developments have been ongoing at the European Space Agency (ESA) in support of EarthCARE (Earth Clouds, Aerosols, and Radiation Explorer), the 6th Earth Explorer mission, and A-SCOPE (Advanced Space Carbon and Climate Observation of Planet Earth), one of the candidates for the 7th Earth Explorer mission. EarthCARE is embarking an Atmospheric backscatter Lidar (ATLID) while A-SCOPE is based on a Total Column Differential Absorption Lidar. As EarthCARE phase B has just started, the pre-development activities, aiming at validating the technologies used in the flight design and at verifying the overall instrument performance, are almost completed. On the other hand, A-SCOPE pre-phase A has just finished. Therefore technology developments are in progress, addressing critical subsystems or components with the lowest TRL, selected in the proposed instrument concepts. The activities described in this paper span over a broad range, addressing all critical elements of a lidar from the transmitter to the receiver.

A 2-phase labeling and choice architecture intervention to improve healthy food and beverage choices.

PubMed

Thorndike, Anne N; Sonnenberg, Lillian; Riis, Jason; Barraclough, Susan; Levy, Douglas E

2012-03-01

We assessed whether a 2-phase labeling and choice architecture intervention would increase sales of healthy food and beverages in a large hospital cafeteria. Phase 1 was a 3-month color-coded labeling intervention (red = unhealthy, yellow = less healthy, green = healthy). Phase 2 added a 3-month choice architecture intervention that increased the visibility and convenience of some green items. We compared relative changes in 3-month sales from baseline to phase 1 and from phase 1 to phase 2. At baseline (977,793 items, including 199,513 beverages), 24.9% of sales were red and 42.2% were green. Sales of red items decreased in both phases (P < .001), and green items increased in phase 1 (P < .001). The largest changes occurred among beverages. Red beverages decreased 16.5% during phase 1 (P < .001) and further decreased 11.4% in phase 2 (P < .001). Green beverages increased 9.6% in phase 1 (P < .001) and further increased 4.0% in phase 2 (P < .001). Bottled water increased 25.8% during phase 2 (P < .001) but did not increase at 2 on-site comparison cafeterias (P < .001). A color-coded labeling intervention improved sales of healthy items and was enhanced by a choice architecture intervention.

Hemispherical Anisotropic Patterns of the Earth's Inner Core

NASA Astrophysics Data System (ADS)

Mattesini, M.; Belonoshko, A. B.; Buforn, E.; Ramirez, M.; Simak, S. I.; Udias, A.; Mao, H.; Ahuja, R.

2010-12-01

It has been shown that the Earth's inner core has an axisymmetric anisotropic structure with seismic waves travelling ˜3% faster along polar paths than along equatorial directions. However, hemispherical anisotropic patterns of solid Earth's core are rather complex, and the commonly used hexagonal-close-packed (hcp) iron phase might be insufficient to account for seismological observations. We show that the data we collected are in good agreement with the presence of two anisotropically specular east and west core hemispheres. The detected travel-time anomalies can only be disclosed by a lattice preferred orientation of a body-centered-cubic iron aggregate (bcc), having a fraction of their [111] crystal axes parallel to the Earth's rotation axis. This is a compelling evidence for the presence of a body-centered-cubic Fe phase at the top 100 km of the Earth's inner core.

Near-Earth Phase Risk Comparison of Human Mars Campaign Architectures

NASA Technical Reports Server (NTRS)

Manning, Ted A.; Nejad, Hamed S.; Mattenberger, Chris

2013-01-01

A risk analysis of the launch, orbital assembly, and Earth-departure phases of human Mars exploration campaign architectures was completed as an extension of a probabilistic risk assessment (PRA) originally carried out under the NASA Constellation Program Ares V Project. The objective of the updated analysis was to study the sensitivity of loss-of-campaign risk to such architectural factors as composition of the propellant delivery portion of the launch vehicle fleet (Ares V heavy-lift launch vehicle vs. smaller/cheaper commercial launchers) and the degree of launcher or Mars-bound spacecraft element sparing. Both a static PRA analysis and a dynamic, event-based Monte Carlo simulation were developed and used to evaluate the probability of loss of campaign under different sparing options. Results showed that with no sparing, loss-of-campaign risk is strongly driven by launcher count and on-orbit loiter duration, favoring an all-Ares V launch approach. Further, the reliability of the all-Ares V architecture showed significant improvement with the addition of a single spare launcher/payload. Among architectures utilizing a mix of Ares V and commercial launchers, those that minimized the on-orbit loiter duration of Mars-bound elements were found to exceed the reliability of no spare all-Ares V campaign if unlimited commercial vehicle sparing was assumed

Presidential Green Chemistry Challenge: 2002 Designing Greener Chemicals Award

EPA Pesticide Factsheets

Presidential Green Chemistry Challenge 2002 award winner, Chemical Specialties, developed an alkaline copper quaternary wood preservative to replace chromated copper arsenate preservative phased out due to risk to children.

Decaying shock studies of phase transitions in MgO-SiO2 systems: implications for the Super-Earths' interiors

NASA Astrophysics Data System (ADS)

Bolis, R.; Morard, G.; Vinci, T.; Ravasio, A.; Bambrink, E.; Guarguaglini, M.; Koenig, M.; Musella, R.; Françoise, R.; Bouchet, J.; Ozaki, N.; Miyanishi, K.; Sekine, T.; Sakawa, Y.; Sano, T.; Kodama, R.; Guyot, F. J.; Benuzzi, A.

2016-12-01

Mantles of telluric exoplanets, so-called Earth-like and Super-Earths, are expected to be mainly composed of different type of oxides, such as periclase (MgO), enstatite (MgSiO3) and forsterite (Mg2SiO4). Determining the phase diagrams, melting curves and liquid properties of these compounds under extreme pressure (0.2-1 TPa) is crucial to model the internal dynamic of these exoplanets, as the melting of mantle components controls planetary temperature profiles [6]. Experimentally, these planetary thermodynamic states can be achieved with laser-shock compression. Here we present laser-driven decaying shock experiments on MgO, MgSiO3 and Mg2SiO4 samples performed at LULI and GEKKO laser facilities, where we focused 1.2-2.5 ns laser pulses with an intensity between 3-8 1013 W/cm2 exploring pressures between 0.2 and 1 TPa and temperature between 5000 and 30000 K. We determined the thermodynamic states using rear side optical diagnostics. We observed a single transition for MgO associated to melting (at 0.47 TPa ± 0.04 and 9863 ± 812 K) and no evidence of a liquid-liquid transition, dissociation or melting for all the other compounds in the range 150-500 Gpa and 200-800 Gpa respectively for MgSiO3 and Mg2SiO4. Some implications are presented comparing our data experimental and theoretical data found in literature [1, 2, 3, 4, 5]. In particular these results represent a key input to solve the controversy on a possible MgSiO3 liquid-liquid phase transition. Moreover we propose a revision of the phase diagram of MgO, with a lower melting line which results in a lower temperature profile for super-Earths. Finally our data evidence the presence of a poor electrically conducting liquid in the phase diagram of all the studied material, with implications for the modelling of magnetic field generation via dynamo mechanism.[1] McWilliams et al., Science 338 (2012): 1330-1333. [2] Spaulding et al., Physical Review Letters108 (2012): 065701. [3] Root et al., Physical Review

Equation of state and phase diagram of Fe-16Si alloy as a candidate component of Earth's core

NASA Astrophysics Data System (ADS)

Fischer, Rebecca A.; Campbell, Andrew J.; Caracas, Razvan; Reaman, Daniel M.; Dera, Przymyslaw; Prakapenka, Vitali B.

2012-12-01

The outer core of the Earth contains several weight percent of one or more unknown light elements, which may include silicon. Therefore it is critical to understand the high pressure-temperature properties and behavior of an iron-silicon alloy with a geophysically relevant composition (16 wt% silicon). We experimentally determined the melting curve, subsolidus phase diagram, and equations of state of all phases of Fe-16 wt%Si to 140 GPa, finding a conversion from the D03 crystal structure to a B2+hcp mixture at high pressures. The melting curve implies that 3520 K is a minimum temperature for the Earth's outer core, if it consists solely of Fe-Si alloy, and that the eutectic composition in the Fe-Si system is less than 16 wt% silicon at core-mantle boundary conditions. Comparing our new equation of state to that of iron and the density of the core, we find that for an Fe-Ni-Si outer core, 11.3±1.5 wt% silicon would be required to match the core's observed density at the core-mantle boundary. We have also performed first-principles calculations of the equations of state of Fe3Si with the D03 structure, hcp iron, and FeSi with the B2 structure using density-functional theory.

Equation of state and phase diagram of Fe-16Si alloy as a candidate component of Earth's core

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fischer, Rebecca A; Campbell, Andrew J; Caracas, Razvan

2016-07-29

The outer core of the Earth contains several weight percent of one or more unknown light elements, which may include silicon. Therefore it is critical to understand the high pressure–temperature properties and behavior of an iron–silicon alloy with a geophysically relevant composition (16 wt% silicon). We experimentally determined the melting curve, subsolidus phase diagram, and equations of state of all phases of Fe–16 wt%Si to 140 GPa, finding a conversion from the D0 3 crystal structure to a B2+hcp mixture at high pressures. The melting curve implies that 3520 K is a minimum temperature for the Earth's outer core, ifmore » it consists solely of Fe–Si alloy, and that the eutectic composition in the Fe–Si system is less than 16 wt% silicon at core–mantle boundary conditions. Comparing our new equation of state to that of iron and the density of the core, we find that for an Fe–Ni–Si outer core, 11.3±1.5 wt% silicon would be required to match the core's observed density at the core–mantle boundary. We have also performed first-principles calculations of the equations of state of Fe 3Si with the D0 3 structure, hcp iron, and FeSi with the B2 structure using density-functional theory.« less

The EarthLabs Approach to Curriculum and Professional Development: Earth Science Education in the 21st Century

NASA Astrophysics Data System (ADS)

Mote, A. S.; Ellins, K. K.; Haddad, N.

2011-12-01

Humans are modifying planet Earth at an alarming rate without fully understanding how our actions will affect the atmosphere, hydrosphere, or biosphere. Recognizing the value of educating people to become citizens who can make informed decisions about Earth's resources and challenges, Texas currently offers Earth and Space Science as a rigorous high school capstone course. The new course has created a need for high quality instructional resources and professional development to equip teachers with the most up to date content knowledge, pedagogical approaches, and technological skills to be able to teach a rigorous Earth and Space Science course. As a participant in the NSF-sponsored Texas Earth and Space Science (TXESS) Revolution teacher professional development program, I was selected to participate in a curriculum development project led by TERC to create Earth System Science and climate change resources for the EarthLabs collection. To this end, I am involved in multiple phases of the EarthLabs project, including reviewing the lab-based units during the development phase, pilot teaching the units with my students, participating in research, and ultimately delivering professional development to other teachers to turn them on to the new modules. My partnership with the EarthLabs project has strengthened my teaching practice by increasing my involvement with curriculum development and collaboration and interaction with other Earth science educators. Critically evaluating the lab modules prior to delivering the lessons to my students has prepared me to more effectively teach the EarthLabs modules in my classroom and present the material to other teachers during professional development workshops. The workshop was also strengthened by planning meetings held with EarthLabs partner teachers in which we engaged in lively discussions regarding misconceptions in Earth science, held by both students and adults, and pedagogical approaches to uncover these misconceptions

Human-induced greening of the northern extratropical land surface

DOE PAGES

Mao, Jiafu; Ribes, Aurélien; Yan, Binyan; ...

2016-06-27

Significant land greening in the northern extratropical latitudes (NEL) has been documented from satellite observations during the past three decades. This enhanced vegetation growth has broad implications for surface energy, water and carbon budgets, and ecosystem services across multiple scales. Discernible human impacts on the Earth’s climate system have been revealed by using statistical frameworks of detection–attribution. These impacts, however, were not previously identified on the NEL greening signal, owing to the lack of long-term observational records, possible bias of satellite data, different algorithms used to calculate vegetation greenness, and the lack of suitable simulations from coupled Earth system modelsmore » (ESMs). Here we have overcome these challenges to attribute recent changes in NEL vegetation activity. We have used two 30-year-long remote-sensing-based leaf area index (LAI) data sets, simulations from 19 coupled ESMs with interactive vegetation, and a formal detection and attribution algorithm. Our findings reveal that the observed greening record is consistent with an assumption of anthropogenic forcings, where greenhouse gases play a dominant role, but is not consistent with simulations that include only natural forcings and internal climate variability. These results provide the first clear evidence of a discernible human fingerprint on physiological vegetation changes other than phenology and range shifts.« less

Early Earth slab stagnation

NASA Astrophysics Data System (ADS)

Agrusta, R.; Van Hunen, J.

2016-12-01

At present day, the Earth's mantle exhibits a combination of stagnant and penetrating slabs within the transition zone, indicating a intermittent convection mode between layered and whole-mantle convection. Isoviscous thermal convection calculations show that in a hotter Earth, the natural mode of convection was dominated by double-layered convection, which may imply that slabs were more prone to stagnate in the transition zone. Today, slab penetration is to a large extent controlled by trench mobility for a plausible range of lower mantle viscosity and Clapeyron slope of the mantle phase transitions. Trench mobility is, in turn, governed by slab strength and density and upper plate forcing. In this study, we systematically investigate the slab-transition zone internation in the Early Earth, using 2D self-consistent numerical subduction models. Early Earth's higher mantle temperature facilitates decoupling between the plates and the underlying asthenosphere, and may result in slab sinking almost without trench retreat. Such behaviour together with a low resistance of a weak lower mantle may allow slabs to penetrate. The ability of slab to sink into the lower mantle throughout Earth's history may have important implications for Earth's evolution: it would provide efficient mass and heat flux through the transition zone therefore provide an efficient way to cool and mix the Earth's mantle.

Influence of governance structure on green stormwater infrastructure investment

USGS Publications Warehouse

Hopkins, Kristina G.; Grimm, Nancy B.; York, Abigail M.

2018-01-01

Communities are faced with the challenge of meeting regulatory requirements mandating reductions in water pollution from stormwater and combined sewer overflows (CSO). Green stormwater infrastructure and gray stormwater infrastructure are two types of water management strategies communities can use to address water pollution. In this study, we used long-term control plans from 25 U.S. cities to synthesize: the types of gray and green infrastructure being used by communities to address combined sewer overflows; the types of goals set; biophysical characteristics of each city; and factors associated with the governance of stormwater management. These city characteristics were then used to identify common characteristics of “green leader” cities—those that dedicated >20% of the control plan budget in green infrastructure. Five “green leader” cities were identified: Milwaukee, WI, Philadelphia, PA, Syracuse, NY, New York City, NY, and Buffalo, NY. These five cities had explicit green infrastructure goals targeting the volume of stormwater or percentage of impervious cover managed by green infrastructure. Results suggested that the management scale and complexity of the management system are less important factors than the ability to harness a “policy window” to integrate green infrastructure into control plans. Two case studies—Philadelphia, PA, and Milwaukee, WI—indicated that green leader cities have a long history of building momentum for green infrastructure through a series of phases from experimentation, demonstration, and finally—in the case of Philadelphia—a full transition in the approach used to manage CSOs.

Bringing the environment down to earth.

PubMed

Reinhardt, F L

1999-01-01

The debate on business and the environment has typically been framed in simple yes-or-no terms: "Does it pay to be green?" But the environment, like other business issues, requires a more complex approach--one that demands more than such all-or-nothing thinking. Managers need to ask instead, "Under what circumstances do particular kinds of environmental investments deliver returns to shareholders?" This article presents five approaches that managers can take to identify those circumstances and integrate the environment into their business thinking. These approaches will enable companies with the right industry structure, competitive position, and managerial skills to reconcile their responsibility to shareholders with the pressure to be faithful stewards of the earth's resources. Some companies can distance themselves from competitors by differentiating their products and commanding higher prices for them. Others may be able to "manage" their competitors by imposing a set of private regulations or by helping to shape the rules written by government officials. Still others may be able to cut costs and help the environment simultaneously. Almost all can learn to improve their management of risk and thus reduce the outlays associated with accidents, lawsuits, and boycotts. And some companies may even be able to make systemic changes that will redefine competition in their markets. All five approaches can help managers bring the environment down to earth. And that means bringing the environment back into the fold of business problems and determining when it really pays to be green.

Elementary Introduction to the Green Management of the Construction in Whole Process

NASA Astrophysics Data System (ADS)

Na), Wu Y. N.(Yun; Yu), Yan H. Y.(Hong; Jun), Huang Z. J.(Zhi

Construction industries consume more energy resources than necessary. it is essential to establish a management system with all pollution problems resolved to construct green buildings. By applying the theory of whole life cycle, this paper divides the whole process of construction into four sub-phases, which will also be subdivided into more concrete working procedures. Based on this, a systematic framework is promoted for the green management of the construction, especially and creatively, considering the green aims as important as the traditional three aims-"quality aim, schedule aim and cost aim". This framework, adhering to the integration idea-"customers first, whole optimal", regards the green control and workflow as an organic whole in order to build green, sustainable and healthy architecture, and then provide a perfect guide and reference to the green management.

A green deep eutectic solvent-based aqueous two-phase system for protein extracting.

PubMed

Xu, Kaijia; Wang, Yuzhi; Huang, Yanhua; Li, Na; Wen, Qian

2015-03-15

As a new type of green solvent, deep eutectic solvent (DES) has been applied for the extraction of proteins with an aqueous two-phase system (ATPS) in this work. Four kinds of choline chloride (ChCl)-based DESs were synthesized to extract bovine serum albumin (BSA), and ChCl-glycerol was selected as the suitable extraction solvent. Single factor experiments have been done to investigate the effects of the extraction process, including the amount of DES, the concentration of salt, the mass of protein, the shaking time, the temperature and PH value. Experimental results show 98.16% of the BSA could be extracted into the DES-rich phase in a single-step extraction under the optimized conditions. A high extraction efficiency of 94.36% was achieved, while the conditions were applied to the extraction of trypsin (Try). Precision, repeatability and stability experiments were studied and the relative standard deviations (RSD) of the extraction efficiency were 0.4246% (n=3), 1.6057% (n=3) and 1.6132% (n=3), respectively. Conformation of BSA was not changed during the extraction process according to the investigation of UV-vis spectra, FT-IR spectra and CD spectra of BSA. The conductivity, dynamic light scattering (DLS) and transmission electron microscopy (TEM) were used to explore the mechanism of the extraction. It turned out that the formation of DES-protein aggregates play a significant role in the separation process. All the results suggest that ChCl-based DES-ATPS are supposed to have the potential to provide new possibilities in the separation of proteins. Copyright © 2015 Elsevier B.V. All rights reserved.

Signals from the planets, via the Sun to the Earth

NASA Astrophysics Data System (ADS)

Solheim, J.-E.

2013-12-01

The best method for identification of planetary forcing of the Earth's climate is to investigate periodic variations in climate time series. Some natural frequencies in the Earth climate system seem to be synchronized to planetary cycles, and amplified to a level of detection. The response by the Earth depends on location, and in global averaged series, some planetary signals may be below detection. Comparing sea level rise with sunspot variations, we find phase variations, and even a phase reversal. A periodogram of the global temperature shows that the Earth amplifies other periods than observed in sunspots. A particular case is that the Earth amplifies the 22 yr Hale period, and not the 11 yr Schwabe period. This may be explained by alternating peak or plateau appearance of cosmic ray counts. Among longer periods, the Earth amplifies the 60 yr planetary period and keeps the phase during centennials. The recent global warming may be interpreted as a rising branch of a millennium cycle, identified in ice cores and sediments and also recorded in history. This cycle peaks in the second half of this century, and then a 500 yr cooling trend will start. An expected solar grand minimum due to a 200 yr cycle will introduce additional cooling in the first part of this century.

Behavior of new complexes of tetrakis(4-methoxylphenyl)porphyrin with heavy rare earth elements in reversed-phase high performance liquid chromatography.

PubMed

Zhang, Jun-Feng; Wang, Hong; Hou, An-Xin; Wang, Chang-Fa; Zhang, Hua-Shan

2004-08-01

An HPLC method has been developed for the separation of new complexes of tetrakis(4-methoxylphenyl)porphyrin (TMOPP) with four heavy rare earth elements (RE = Y, Er, Tm, and Yb). The function of amine and acid in the mobile phase has been investigated and a reasonable explanation is presented. Successful separation of the RE-TMOPP-Cl complexes is accomplished in 10 min with a mobile phase consisting of methanol-water-acetic acid-triethanolamine. The detection limits (S/N= 3) for the four complexes are 0.01 microg/mL. This method is rapid, sensitive, and simple.

Trace analysis of nitrite ions in environmental samples by using in-situ synthesized Zein biopolymeric nanoparticles as the novel green solid phase extractor.

PubMed

Hatamie, Amir; Nassiri, Mahmoud; Alivand, Meghdad Doust; Bhatnagar, Amit

2018-01-01

For the first time, a novel green method using Zein biopolymeric nanoparticles as a green dispersive solid-phase extractor is reported for the separation and preconcentration of trace amount of nitrite (NO 2 - ) ions in ppb levels. The Zein protein is a biodegradable hydrophobic plant protein that is obtained from corn and is composed of a number of hydrophobic amino acids. Zein bionanoparticles were synthesized in an anti-solvent process and used as a new biosorbent in the extraction technique. In the proposed technique, by using a standard method at first, a mixture of 1-naphthylamine and sulphanilic acid as selective regents was added to the samples, and in the presence of the nitrite ion, a red azo product was formed. After that, the ethanolic Zein solution (equal to 15mg) was injected rapidly into the sample, based on the anti-solvent process. Zein bionanoparticles (BNPs) were produced, the adsorbed colour product was separated by centrifugation, and finally samples were analysed with the spectrophotometric method. The influence of different variables such as pH, buffer and amount of buffer, amount of adsorbent and effect of time on extraction were investigated and Zein BNPs were characterized by TEM, SEM, and FT-IR techniques. The main advantages of Zein as a new solid-phase extractor are that this biopolymer is non-toxic, stable, widely available, biodegradable, very hydrophobic, and can be fabricated easily. Under optimal experimental conditions, the linear correlation coefficient (r 2 ) was found to be 0.9972 at the concentration range of 5.0-1000ngmL -1 . The limit of detection was 2.3ngmL -1 (0.05μM). This method was applied successfully for the analysis of sea and river waters as well as industrial wastewater samples. Finally, this method follows the US EPA (US Environmental Protection Agency) and WHO (World Health Organization) international standards for nitrite analysis. In addition, it has several advantages to warrant its applicability in the near

Effect of particle size in preparative reversed-phase high-performance liquid chromatography on the isolation of epigallocatechin gallate from Korean green tea.

PubMed

Kim, Jung Il; Hong, Seung Bum; Row, Kyung Ho

2002-03-08

To isolate epigallocatechin gallate (EGCG) of catechin compounds from Korean green tea (Bosung, Chonnam), a C18 reversed-phase preparative column (250x22 mm) packed with packings of three different sizes (15, 40-63, and 150 microm) was used. The sample extracted with water was partitioned with chloroform and ethyl acetate to remove the impurities including caffeine. The mobile phases in this experiment were composed of 0.1% acetic acid in water, acetonitrile, methanol and ethyl acetate. The injection volume was fixed at 400 microl and the flow rate was increased as the particle size becomes larger. The isolation of EGCG with particle size was compared at a preparative scale and the feasibility of separation of EGCG at larger particle sizes was confirmed. The optimum mobile phase composition for separating EGCG was experimentally obtained at the particle sizes of 15 and 40-63 microm in the isocratic mode, but EGCG was not purely separated at the particle size of 150 microm.

The role of upper mantle mineral phase transitions on the current structure of large-scale Earth's mantle convection.

NASA Astrophysics Data System (ADS)

Thoraval, C.

2017-12-01

Describing the large-scale structures of mantle convection and quantifying the mass transfer between upper and lower mantle request to account for the role played by mineral phase transitions in the transition zone. We build a density distribution within the Earth mantle from velocity anomalies described by global seismic tomographic models. The density distribution includes thermal anomalies and topographies of the phase transitions at depths of 410 and 660 km. We compute the flow driven by this density distribution using a 3D spherical circulation model, which account for depth-dependent viscosity. The dynamic topographies at the surface and at the CMB and the geoid are calculated as well. Within the range of viscosity profiles allowing for a satisfying restitution of the long wavelength geoid, we perform a parametric study to decipher the role of the characteristics of phase diagrams - mainly the Clapeyron's slopes - and of the kinetics of phase transitions, which may modify phase transition topographies. Indeed, when a phase transition is delayed, the boundary between two mineral phases is both dragged by the flow and interfere with it. The results are compared to recent estimations of surface dynamic topography and to the phase transition topographies as revealed by seismic studies. The consequences are then discussed in terms of structure of mantle flow. Comparisons between various tomographic models allow us to enlighten the most robust features. At last, the role played by the phase transitions on the lateral variations of mass transfer between upper and lower mantle are quantified by comparison to cases with no phase transitions and confronted to regional tomographic models, which reflect the variability of the behaviors of the descending slabs in the transition zone.

Scarcity of rare earth elements.

PubMed

de Boer, M A; Lammertsma, K

2013-11-01

Rare earth elements (REEs) are important for green and a large variety of high-tech technologies and are, therefore, in high demand. As a result, supply with REEs is likely to be disrupted (the degree of depends on the REE) in the near future. The 17 REEs are divided into heavy and light REEs. Other critical elements besides REEs, identified by the European Commission, are also becoming less easily available. Although there is no deficiency in the earth's crust of rare earth oxides, the economic accessibility is limited. The increased demand for REEs, the decreasing export from China, and geopolitical concerns on availability contributed to the (re)opening of mines in Australia and the USA and other mines are slow to follow. As a result, short supply of particularly terbium, dysprosium, praseodymium, and neodymium is expected to be problematic for at least the short term, also because they cannot be substituted. Recycling REEs from electronic waste would be a solution, but so far there are hardly any established REE recycling methods. Decreasing the dependency on REEs, for example, by identifying possible replacements or increasing their efficient use, represents another possibility. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Immobilization of chromate in hyperalkaline waste streams by green rusts and zero-valent iron.

PubMed

Rogers, Christine M; Burke, Ian T; Ahmed, Imad A M; Shaw, Samuel

2014-01-01

Zero-valent iron (ZVI) and green rusts can be used as reductants to convert chromium from soluble, highly toxic Cr(VI) to insoluble Cr(III). This study compared the reduction rates of Cr(VI) by ZVI and two carbonate green rust phases in alkaline/hyperalkaline solutions. Batch experiments were carried out with synthetic chromate solutions at pH 7.7-12.3 and a chromite ore processing residue (COPR) leachate (pH approximately 12.2). Green rust removes chromate from high pH solutions (pH 10-12.5) very rapidly (<400 s). Chromate reduction rates for both green rust phases were consistently higher than for ZVI throughout the pH range studied; the surface area normalized rate constants were two orders of magnitude higher in the COPR leachate solution at pH 12.2. The performances of both green rusts were unaffected by changes in pH. In contrast, ZVI exhibited a marked decline in reduction rate with increasing pH to become almost ineffective above pH12.

NASA Captures 'EPIC' Earth Image

NASA Image and Video Library

2017-12-08

A NASA camera on the Deep Space Climate Observatory satellite has returned its first view of the entire sunlit side of Earth from one million miles away. This color image of Earth was taken by NASA’s Earth Polychromatic Imaging Camera (EPIC), a four megapixel CCD camera and telescope. The image was generated by combining three separate images to create a photographic-quality image. The camera takes a series of 10 images using different narrowband filters -- from ultraviolet to near infrared -- to produce a variety of science products. The red, green and blue channel images are used in these color images. The image was taken July 6, 2015, showing North and Central America. The central turquoise areas are shallow seas around the Caribbean islands. This Earth image shows the effects of sunlight scattered by air molecules, giving the image a characteristic bluish tint. The EPIC team is working to remove this atmospheric effect from subsequent images. Once the instrument begins regular data acquisition, EPIC will provide a daily series of Earth images allowing for the first time study of daily variations over the entire globe. These images, available 12 to 36 hours after they are acquired, will be posted to a dedicated web page by September 2015. The primary objective of DSCOVR, a partnership between NASA, the National Oceanic and Atmospheric Administration (NOAA) and the U.S. Air Force, is to maintain the nation’s real-time solar wind monitoring capabilities, which are critical to the accuracy and lead time of space weather alerts and forecasts from NOAA. For more information about DSCOVR, visit: www.nesdis.noaa.gov/DSCOVR/

Earth-to-Orbit Rocket Propulsion

NASA Technical Reports Server (NTRS)

Beaurain, Andre; Souchier, Alain; Moravie, Michel; Sackheim, Robert L.; Cikanek, Harry A., III

2003-01-01

The Earth-to-orbit (ETO) phase of access to space is and always will be the first and most critical phase of all space missions. This first phase of all space missions has unique characteristics that have driven space launcher propulsion requirements for more than half a century. For example, the need to overcome the force of the Earth s gravity in combination with high levels of atmospheric drag to achieve the initial orbital velocity; i.e., Earth parking orbit or =9 km/s, will always require high thrust- to-weight (TN) propulsion systems. These are necessary with a T/W ratio greater than one during the ascent phase. The only type of propulsion system that can achieve these high T/W ratios are those that convert thermal energy to kinetic energy. There are only two basic sources of onboard thermal energy: chemical combustion-based systems or nuclear thermal-based systems (fission, fusion, or antimatter). The likelihood of advanced open-cycle, nuclear thermal propulsion being developed for flight readiness or becoming environmentally acceptable during the next century is extremely low. This realization establishes that chemical propulsion for ET0 launchers will be the technology of choice for at least the next century, just as it has been for the last half century of rocket flight into space. The world s space transportation propulsion requirements have evolved through several phases over the history of the space program, as has been necessitated by missions and systems development, technological capabilities available, and the growth and evolution of the utilization of space for economic, security, and science benefit. Current projections for the continuing evolution of requirements and concepts may show how future space transportation system needs could be addressed. The evolution and projections will be described in detail in this manuscript.

Seismic source inversion using Green's reciprocity and a 3-D structural model for the Japanese Islands

NASA Astrophysics Data System (ADS)

Simutė, S.; Fichtner, A.

2015-12-01

We present a feasibility study for seismic source inversions using a 3-D velocity model for the Japanese Islands. The approach involves numerically calculating 3-D Green's tensors, which is made efficient by exploiting Green's reciprocity. The rationale for 3-D seismic source inversion has several aspects. For structurally complex regions, such as the Japan area, it is necessary to account for 3-D Earth heterogeneities to prevent unknown structure polluting source solutions. In addition, earthquake source characterisation can serve as a means to delineate existing faults. Source parameters obtained for more realistic Earth models can then facilitate improvements in seismic tomography and early warning systems, which are particularly important for seismically active areas, such as Japan. We have created a database of numerically computed 3-D Green's reciprocals for a 40°× 40°× 600 km size area around the Japanese Archipelago for >150 broadband stations. For this we used a regional 3-D velocity model, recently obtained from full waveform inversion. The model includes attenuation and radial anisotropy and explains seismic waveform data for periods between 10 - 80 s generally well. The aim is to perform source inversions using the database of 3-D Green's tensors. As preliminary steps, we present initial concepts to address issues that are at the basis of our approach. We first investigate to which extent Green's reciprocity works in a discrete domain. Considering substantial amounts of computed Green's tensors we address storage requirements and file formatting. We discuss the importance of the initial source model, as an intelligent choice can substantially reduce the search volume. Possibilities to perform a Bayesian inversion and ways to move to finite source inversion are also explored.

Earth observation mission operation of COMS during in-orbit test

NASA Astrophysics Data System (ADS)

Cho, Young-Min

2011-11-01

Communication Ocean Meteorological Satellite (COMS) for the hybrid mission of meteorological observation, ocean monitoring, and telecommunication service was launched onto Geostationary Earth Orbit on June 27, 2010 and it is currently under normal operation service after the In-Orbit Test (IOT) phase. The COMS is located on 128.2° East of the geostationary orbit. In order to perform the three missions, the COMS has 3 separate payloads, the meteorological imager (MI), the Geostationary Ocean Color Imager (GOCI), and the Ka-band antenna. Each payload is dedicated to one of the three missions, respectively. The MI and GOCI perform the Earth observation mission of meteorological observation and ocean monitoring, respectively. During the IOT phase the functionality and the performance of many aspects of the COMS satellite and ground station have been checked through the Earth observation mission operation for the observation of the meteorological phenomenon over several areas of the Earth and the monitoring of marine environments around the Korean peninsula. The Earth observation mission operation of COMS during the IOT phase is introduced in terms of mission operation characteristics, mission planning, and mission operation results for the missions of meteorological observation and ocean monitoring, respectively.

A volatile rich Earth's core?

NASA Astrophysics Data System (ADS)

Morard, G.; Antonangeli, D.; Andrault, D.; Nakajima, Y.

2017-12-01

The composition of the Earth's core is still an open question. Although mostly composed of iron, it contains impurities that lower its density and melting point with respect to pure Fe. Knowledge of the nature and abundance of light elements (O, S, Si, C or H) in the core has major implications for establishing the bulk composition of the Earth and for building the model of Earth's differentiation. Geochemical models of the Earth's formation point out that its building blocks were depleted in volatile elements compared to the chondritic abundance, therefore light elements such as S, H or C cannot be the major elements alloyed with iron in the Earth's core. However, such models should be compatible with the comparison of seismic properties of the Earth's core and physical properties of iron alloys under extreme conditions, such as sound velocity or density of solid and liquid. The present work will discuss the recent progress for compositional model issued from studies of phase diagrams and elastic properties of iron alloys under core conditions and highlight the compatibility of volatile elements with observed properties of the Earth's core, in potential contradiction with models derived from metal-silicate partitioning experiments.

Melting in super-earths.

PubMed

Stixrude, Lars

2014-04-28

We examine the possible extent of melting in rock-iron super-earths, focusing on those in the habitable zone. We consider the energetics of accretion and core formation, the timescale of cooling and its dependence on viscosity and partial melting, thermal regulation via the temperature dependence of viscosity, and the melting curves of rock and iron components at the ultra-high pressures characteristic of super-earths. We find that the efficiency of kinetic energy deposition during accretion increases with planetary mass; considering the likely role of giant impacts and core formation, we find that super-earths probably complete their accretionary phase in an entirely molten state. Considerations of thermal regulation lead us to propose model temperature profiles of super-earths that are controlled by silicate melting. We estimate melting curves of iron and rock components up to the extreme pressures characteristic of super-earth interiors based on existing experimental and ab initio results and scaling laws. We construct super-earth thermal models by solving the equations of mass conservation and hydrostatic equilibrium, together with equations of state of rock and iron components. We set the potential temperature at the core-mantle boundary and at the surface to the local silicate melting temperature. We find that ancient (∼4 Gyr) super-earths may be partially molten at the top and bottom of their mantles, and that mantle convection is sufficiently vigorous to sustain dynamo action over the whole range of super-earth masses.

Propagation of a radio-frequency pulsed signal over the Earth. The JOLLY programs

NASA Astrophysics Data System (ADS)

Carroll, D.; Detch, J. L.; Malik, J.

1983-07-01

The interpretation of observed radioflash/electromagnetic pulse (emp) observed signals from nuclear detonations in terms of theoretical models or extrapolation to signals expected at military systems involves correction for ground-wave propagation effects. For most applications, previously developed programs have been adequate. There have been problems when these techniques have been tried for situations in the near tangent regime where a considerable concern exists. It has been found that the problem of predicting propagation response functions in the near tangent regime has been the inconsistent derivation of the equations. Resolution of this problem has evolved into a program to better predict ground-wave propagation. The description of the method and detailed description of the programs are described for both propagation over realistic earth and sea-water paths. Results can be given in terms of amplitude and phase as a function of the frequency or as amplitude versus time, the usual Green's or resolution function.

Structure and Charge Hopping Dynamics in Green Rust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wander, Matthew C; Rosso, Kevin M; Schoonen, Martin A

Green rust is a family of mixed-valent iron phases formed by a number of abiotic and biotic processes under alkaline suboxic conditions. Due to its high Fe 2+ content, green rust is a potentially important phase for pollution remediation by serving as a powerful electron donor for reductive transformation. However, mechanisms of oxidation of this material are poorly understood. An essential component of the green rust structure is a mixed-valent brucite-like Fe(OH) 2 sheet comprised of a two dimensional network of edge-sharing iron octahedra. Room temperature Mössbauer spectra show a characteristic signature for intermediate valence on the iron atoms inmore » this sheet, indicative of a Fe 2+-Fe 3+ valence interchange reaction faster than approximately 10 7 s -1. Using Fe(OH) 2 as structural analogue for reduced green rust, we performed Hartree-Fock calculations on periodic slab models and cluster representations to determine the structure and hopping mobility of Fe 3+ hole polarons in this material, providing a first principles assessment of the Fe 2+-Fe 3+ valence interchange reaction rate. The calculations show that among three possible symmetry unique iron-to-iron hops within a sheet, a hop to next-nearest neighbors at an intermediate distance of 5.6 Å is the fastest. The predicted rate is on the order of 10 12 s -1 consistent the Mössbauer-based constraint. All other possibilities, including hopping across interlayer spaces, are predicted to be slower than 10 7 s -1. Collectively, the findings suggest the possibility of hole self-diffusion along sheets as a mechanism for regeneration of lattice Fe 2+ sites, consistent with previous experimental observations of edge-inward progressive oxidation of green rust.« less

Volatile aroma compounds in various brewed green teas.

PubMed

Lee, Jeehyun; Chambers, Delores H; Chambers, Edgar; Adhikari, Koushik; Yoon, Youngmo

2013-08-20

This study identifies and semi-quantifies aroma volatiles in brewed green tea samples. The objectives of this study were to identify using a gas chromatograph-mass spectrometer (GC-MS) paired with a headspace solid-phase micro-extraction (HS-SPME) the common volatile compounds that may be responsible for aroma/flavor of the brewed liquor of a range of green tea samples from various countries as consumed and to determine if green teas from the same region have similarities in volatile composition when green tea samples are prepared for consumption. Twenty-four green tea samples from eight different countries were brewed as recommended for consumer brewing. The aroma volatiles were extracted by HS-SPME, separated on a gas chromatograph and identified using a mass spectrometer. Thirty-eight compounds were identified and the concentrations were semi-quantified. The concentrations were lower than those reported by other researchers, probably because this research examined headspace volatiles from brewed tea rather than solvent extraction of leaves. No relationship to country of origin was found, which indicates that other factors have a greater influence than country of origin on aroma.

The Early Years: The Earth-Sun System

ERIC Educational Resources Information Center

Ashbrook, Peggy

2015-01-01

We all experience firsthand many of the phenomena caused by Earth's Place in the Universe (Next Generation Science Standard 5-ESS1; NGSS Lead States 2013) and the relative motion of the Earth, Sun, and Moon. Young children can investigate phenomena such as changes in times of sunrise and sunset (number of daylight hours), Moon phases, seasonal…

Prospects for tracking spacecrafts within 2 million Km of Earth with phased array antennas

NASA Technical Reports Server (NTRS)

Amoozegar, F.; Jamnejad, V.; Cesarone, R.

2003-01-01

Recent advances in space technology for Earth observations, global communications, and positioning systems have created heavy traffic at a variety of orbits. These include smart sensors in low Earth orbits (LEO), internet satellites in LEO and GEO orbits, Earth observing satellites in high Earth orbits (HEO), observatory class satellites at Lagrangian libration points, and those heading for deep space.

A divalent rare earth oxide semiconductor: Yttrium monoxide

NASA Astrophysics Data System (ADS)

Kaminaga, Kenichi; Sei, Ryosuke; Hayashi, Kouichi; Happo, Naohisa; Tajiri, Hiroo; Oka, Daichi; Fukumura, Tomoteru; Hasegawa, Tetsuya

Rare earth sesquioxides like Y2O3 are known as widegap insulators with the highly stable closed shell trivalent rare earth ions. On the other hand, rare earth monoxides such as YO have been recognized as gaseous phase, and only EuO and YbO were thermodynamically stable solid-phase rock salt monoxides. In this study, solid-phase rock salt yttrium monoxide, YO, was synthesized in a form of epitaxial thin film by pulsed laser deposition method. YO possesses unusual valence of Y2+ ([Kr] 4d1) . In contrast with Y2O3, YO was narrow gap semiconductor with dark-brown color. The electrical conductivity was tunable from 10-1 to 103 Ω-1 cm-1 by introducing oxygen vacancies as electron donor. Weak antilocalization behavior was observed indicating significant spin-orbit coupling owing to 4 d electron carrier. The absorption spectral shape implies the Mott-Hubbard insulator character of YO. Rare earth monoixdes will be new platform of functional oxides. This work was supported by JST-CREST, the Japan Society for the Promotion of Science (JSPS) with Grant-in-Aid for Scientific Research on Innovative Areas (Nos. 26105002 and 26105006), and Nanotechnology Platform (Project No.12024046) of MEXT, Japan.

Therapeutic properties of green tea against environmental insults

PubMed Central

Chen, Lixia; Mo, Huanbiao; Zhao, Ling; Gao, Weimin; Wang, Shu; Cromie, Meghan M; Lu, Chuanwen; Wang, Jia-Sheng; Shen, Chwan-Li

2016-01-01

Pesticides, smoke, mycotoxins, polychlorinated biphenyls, and arsenic are the most common environmental toxins and toxicants to humans. These toxins and toxicants may impact on human health at the molecular (DNA, RNA, or protein), organelle (mitochondria, lysosome, or membranes), cellular (growth inhibition or cell death), tissue, organ, and systemic levels. Formation of reactive radicals, lipid peroxidation, inflammation, genotoxicity, hepatotoxicity, embryotoxicity, neurological alterations, apoptosis, and carcinogenic events are some of the mechanisms mediating the toxic effects of the environmental toxins and toxicants. Green tea, the non-oxidized and non-fermented form of tea that contains several polyphenols, including green tea catechins, exhibits protective effects against these environmental toxins and toxicants in preclinical studies and to a much-limited extent, in clinical trials. The protective effects are collectively mediated by antioxidant, anti-inflammatory, anti-mutagenic, hepato- and neuroprotective, and anti-carcinogenic activities. In addition, green tea modulates signaling pathway including NFκB and ERK pathways, preserves mitochondrial membrane potential, inhibits caspase-3 activity, down-regulates pro-apoptotic proteins, and induces the phase II detoxifying pathway. The bioavailability and metabolism of green tea and its protective effects against environmental insults induced by pesticides, smoke, mycotoxins, polychlorinated biphenyls, and arsenic are reviewed in this paper. Future studies with emphasis on clinical trials should identify biomarkers of green tea intake, examine the mechanisms of action of green tea polyphenols, and investigate potential interactions of green tea with other toxicant-modulating dietary factors. PMID:27723473

Phase Transformation and Lattice Parameter Changes of Non-trivalent Rare Earth-Doped YSZ as a Function of Temperature

NASA Astrophysics Data System (ADS)

Jiang, Shengli; Huang, Xiao; He, Zhang; Buyers, Andrew

2018-01-01

To examine the effect of doping/co-doping on high-temperature phase compositions of YSZ, stand-alone YSZ and CeO2 and Nb2O5 co-doped YSZ samples were prepared using mechanical alloy and high-temperature sintering. XRD analysis was performed on these samples from room temperature to 1100 °C. The results show that the structure for the co-doped samples tends to be thermally stable when the test temperature is higher than a critical value. Monoclinic phase was dominant in Nb2O5 co-doped YSZ at temperatures lower than 600 °C, while for the YSZ and CeO2 co-doped YSZ, cubic/tetragonal phase was dominant in the whole test temperature range. The lattice parameters for all the samples increase with increasing test temperature generally. The lattice parameters for the two non-trivalent rare earth oxides co-doped YSZ show that the lattice parameter a for the cubic phase of the Ce4+ co-doped YSZ is consistently greater than that of 7YSZ which is related to the presence of larger radius of Ce4+ in the matrix. The lattice parameters a, b, c for the monoclinic phase of Ce4+ co-doped YSZ are much closer to each other than that of the Nb5+ co-doped YSZ, indicating the former has better tendency to form cubic/tetragonal phase, which is desired for vast engineering applications.

Phase Transformation and Lattice Parameter Changes of Non-trivalent Rare Earth-Doped YSZ as a Function of Temperature

NASA Astrophysics Data System (ADS)

Jiang, Shengli; Huang, Xiao; He, Zhang; Buyers, Andrew

2018-05-01

To examine the effect of doping/co-doping on high-temperature phase compositions of YSZ, stand-alone YSZ and CeO2 and Nb2O5 co-doped YSZ samples were prepared using mechanical alloy and high-temperature sintering. XRD analysis was performed on these samples from room temperature to 1100 °C. The results show that the structure for the co-doped samples tends to be thermally stable when the test temperature is higher than a critical value. Monoclinic phase was dominant in Nb2O5 co-doped YSZ at temperatures lower than 600 °C, while for the YSZ and CeO2 co-doped YSZ, cubic/tetragonal phase was dominant in the whole test temperature range. The lattice parameters for all the samples increase with increasing test temperature generally. The lattice parameters for the two non-trivalent rare earth oxides co-doped YSZ show that the lattice parameter a for the cubic phase of the Ce4+ co-doped YSZ is consistently greater than that of 7YSZ which is related to the presence of larger radius of Ce4+ in the matrix. The lattice parameters a, b, c for the monoclinic phase of Ce4+ co-doped YSZ are much closer to each other than that of the Nb5+ co-doped YSZ, indicating the former has better tendency to form cubic/tetragonal phase, which is desired for vast engineering applications.

Fungal Microbiomes Associated with Green and Non-Green Building Materials

PubMed Central

Coombs, Kanistha; Vesper, Stephen; Green, Brett J.; Yermakov, Mikhail; Reponen, Tiina

2018-01-01

Water-damaged buildings can lead to fungal growth and occupant health problems. Green building materials, derived from renewable sources, are increasingly utilized in construction and renovations. However, the question as to what fungi will grow on these green compared to non-green materials, after they get wet, has not been adequately studied. By determining what fungi grow on each type of material, the potential health risks can be more adequately assessed. In this study, we inoculated green and non-green pieces of ceiling tile, composite board, drywall, and flooring with indoor dust containing a complex mixture of naturally occurring fungi. The materials were saturated with water and incubated for two months in a controlled environment. The resulting fungal microbiomes were evaluated using ITS amplicon sequencing. Overall, the richness and diversity of the mycobiomes on each pair of green and non-green pieces were not significantly different. However, different genera dominated on each type of material. For example, Aspergillus spp. had the highest relative abundance on green and non-green ceiling tiles and green composite boards, but Peniophora spp. dominated the non-green composite board. In contrast, Penicillium spp. dominated green and non-green flooring samples. Green gypsum board was dominated by Phialophora spp. and Stachybotrys spp., but non-green gypsum board by Myrothecium spp. These data suggest that water-damaged green and non-green building materials can result in mycobiomes that are dominated by fungal genera whose member species pose different potentials for health risks. PMID:29681691

Fungal Microbiomes Associated with Green and Non-Green Building Materials.

PubMed

Coombs, Kanistha; Vesper, Stephen; Green, Brett J; Yermakov, Mikhail; Reponen, Tiina

2017-01-01

Water-damaged buildings can lead to fungal growth and occupant health problems. Green building materials, derived from renewable sources, are increasingly utilized in construction and renovations. However, the question as to what fungi will grow on these green compared to non-green materials, after they get wet, has not been adequately studied. By determining what fungi grow on each type of material, the potential health risks can be more adequately assessed. In this study, we inoculated green and non-green pieces of ceiling tile, composite board, drywall, and flooring with indoor dust containing a complex mixture of naturally occurring fungi. The materials were saturated with water and incubated for two months in a controlled environment. The resulting fungal microbiomes were evaluated using ITS amplicon sequencing. Overall, the richness and diversity of the mycobiomes on each pair of green and non-green pieces were not significantly different. However, different genera dominated on each type of material. For example, Aspergillus spp. had the highest relative abundance on green and non-green ceiling tiles and green composite boards, but Peniophora spp. dominated the non-green composite board. In contrast, Penicillium spp. dominated green and non-green flooring samples. Green gypsum board was dominated by Phialophora spp. and Stachybotrys spp., but non-green gypsum board by Myrothecium spp. These data suggest that water-damaged green and non-green building materials can result in mycobiomes that are dominated by fungal genera whose member species pose different potentials for health risks.

Evaluation of green building rating tools based on existing green building achievement in Indonesia using Life Cycle Assessment Method

NASA Astrophysics Data System (ADS)

Basten, Van; Latief, Yusuf; Berawi, Mohammed Ali; Budiman, Rachmat; Riswanto

2017-03-01

Total completed building construction value in Indonesia increased 116% during 2009 to 2011. That's followed by increasing 11% energy consumption in Indonesia in the last three years with 70% energy met to the electricity needs of commercial building. In addition, a few application of green building concept in Indonesia made the greenhouse gas emissions or CO2 amount increased by 25%. Construction, operation, and maintain of building cost consider relatively high. The evaluation in this research is used to improve the building performance with some of green concept alternatives. The research methodology is conducted by combination of qualitative and quantitative approaches through interview and case study. Assessing the successful of optimization functions in the existing green building is based on the operational and maintenance phase with the Life Cycle Assessment (LCA) Method. The result of optimization that is the largest efficiency and effective of building life cycle.

Uncertainties in Cloud Phase and Optical Thickness Retrievals from the Earth Polychromatic Imaging Camera (EPIC)

NASA Technical Reports Server (NTRS)

Meyer, Kerry; Yang, Yuekui; Platnick, Steven

2016-01-01

This paper presents an investigation of the expected uncertainties of a single channel cloud optical thickness (COT) retrieval technique, as well as a simple cloud-temperature-threshold-based thermodynamic phase approach, in support of the Deep Space Climate Observatory (DSCOVR) mission. DSCOVR cloud products will be derived from Earth Polychromatic Imaging Camera (EPIC) observations in the ultraviolet and visible spectra. Since EPIC is not equipped with a spectral channel in the shortwave or mid-wave infrared that is sensitive to cloud effective radius (CER), COT will be inferred from a single visible channel with the assumption of appropriate CER values for liquid and ice phase clouds. One month of Aqua MODIS daytime granules from April 2005 is selected for investigating cloud phase sensitivity, and a subset of these granules that has similar EPIC sun-view geometry is selected for investigating COT uncertainties. EPIC COT retrievals are simulated with the same algorithm as the operational MODIS cloud products (MOD06), except using fixed phase-dependent CER values. Uncertainty estimates are derived by comparing the single channel COT retrievals with the baseline bi-spectral MODIS retrievals. Results show that a single channel COT retrieval is feasible for EPIC. For ice clouds, single channel retrieval errors are minimal (less than 2 percent) due to the particle- size insensitivity of the assumed ice crystal (i.e., severely roughened aggregate of hexagonal columns) scattering properties at visible wavelengths, while for liquid clouds the error is mostly limited to within 10 percent, although for thin clouds (COT less than 2) the error can be higher. Potential uncertainties in EPIC cloud masking and cloud temperature retrievals are not considered in this study.

Uncertainties in cloud phase and optical thickness retrievals from the Earth Polychromatic Imaging Camera (EPIC)

PubMed Central

Meyer, Kerry; Yang, Yuekui; Platnick, Steven

2018-01-01

This paper presents an investigation of the expected uncertainties of a single channel cloud optical thickness (COT) retrieval technique, as well as a simple cloud temperature threshold based thermodynamic phase approach, in support of the Deep Space Climate Observatory (DSCOVR) mission. DSCOVR cloud products will be derived from Earth Polychromatic Imaging Camera (EPIC) observations in the ultraviolet and visible spectra. Since EPIC is not equipped with a spectral channel in the shortwave or mid-wave infrared that is sensitive to cloud effective radius (CER), COT will be inferred from a single visible channel with the assumption of appropriate CER values for liquid and ice phase clouds. One month of Aqua MODIS daytime granules from April 2005 is selected for investigating cloud phase sensitivity, and a subset of these granules that has similar EPIC sun-view geometry is selected for investigating COT uncertainties. EPIC COT retrievals are simulated with the same algorithm as the operational MODIS cloud products (MOD06), except using fixed phase-dependent CER values. Uncertainty estimates are derived by comparing the single channel COT retrievals with the baseline bi-spectral MODIS retrievals. Results show that a single channel COT retrieval is feasible for EPIC. For ice clouds, single channel retrieval errors are minimal (< 2%) due to the particle size insensitivity of the assumed ice crystal (i.e., severely roughened aggregate of hexagonal columns) scattering properties at visible wavelengths, while for liquid clouds the error is mostly limited to within 10%, although for thin clouds (COT < 2) the error can be higher. Potential uncertainties in EPIC cloud masking and cloud temperature retrievals are not considered in this study. PMID:29619116

Uncertainties in cloud phase and optical thickness retrievals from the Earth Polychromatic Imaging Camera (EPIC).

PubMed

Meyer, Kerry; Yang, Yuekui; Platnick, Steven

2016-01-01

This paper presents an investigation of the expected uncertainties of a single channel cloud optical thickness (COT) retrieval technique, as well as a simple cloud temperature threshold based thermodynamic phase approach, in support of the Deep Space Climate Observatory (DSCOVR) mission. DSCOVR cloud products will be derived from Earth Polychromatic Imaging Camera (EPIC) observations in the ultraviolet and visible spectra. Since EPIC is not equipped with a spectral channel in the shortwave or mid-wave infrared that is sensitive to cloud effective radius (CER), COT will be inferred from a single visible channel with the assumption of appropriate CER values for liquid and ice phase clouds. One month of Aqua MODIS daytime granules from April 2005 is selected for investigating cloud phase sensitivity, and a subset of these granules that has similar EPIC sun-view geometry is selected for investigating COT uncertainties. EPIC COT retrievals are simulated with the same algorithm as the operational MODIS cloud products (MOD06), except using fixed phase-dependent CER values. Uncertainty estimates are derived by comparing the single channel COT retrievals with the baseline bi-spectral MODIS retrievals. Results show that a single channel COT retrieval is feasible for EPIC. For ice clouds, single channel retrieval errors are minimal (< 2%) due to the particle size insensitivity of the assumed ice crystal (i.e., severely roughened aggregate of hexagonal columns) scattering properties at visible wavelengths, while for liquid clouds the error is mostly limited to within 10%, although for thin clouds (COT < 2) the error can be higher. Potential uncertainties in EPIC cloud masking and cloud temperature retrievals are not considered in this study.

Uncertainties in cloud phase and optical thickness retrievals from the Earth Polychromatic Imaging Camera (EPIC)

NASA Astrophysics Data System (ADS)

Meyer, Kerry; Yang, Yuekui; Platnick, Steven

2016-04-01

This paper presents an investigation of the expected uncertainties of a single-channel cloud optical thickness (COT) retrieval technique, as well as a simple cloud-temperature-threshold-based thermodynamic phase approach, in support of the Deep Space Climate Observatory (DSCOVR) mission. DSCOVR cloud products will be derived from Earth Polychromatic Imaging Camera (EPIC) observations in the ultraviolet and visible spectra. Since EPIC is not equipped with a spectral channel in the shortwave or mid-wave infrared that is sensitive to cloud effective radius (CER), COT will be inferred from a single visible channel with the assumption of appropriate CER values for liquid and ice phase clouds. One month of Aqua MODerate-resolution Imaging Spectroradiometer (MODIS) daytime granules from April 2005 is selected for investigating cloud phase sensitivity, and a subset of these granules that has similar EPIC Sun-view geometry is selected for investigating COT uncertainties. EPIC COT retrievals are simulated with the same algorithm as the operational MODIS cloud products (MOD06), except using fixed phase-dependent CER values. Uncertainty estimates are derived by comparing the single-channel COT retrievals with the baseline bi-spectral MODIS retrievals. Results show that a single-channel COT retrieval is feasible for EPIC. For ice clouds, single-channel retrieval errors are minimal (< 2 %) due to the particle size insensitivity of the assumed ice crystal (i.e., severely roughened aggregate of hexagonal columns) scattering properties at visible wavelengths, while for liquid clouds the error is mostly limited to within 10 %, although for thin clouds (COT < 2) the error can be higher. Potential uncertainties in EPIC cloud masking and cloud temperature retrievals are not considered in this study.

Location of the Green Canyon (Offshore Southern Louisiana) Seismic Event of February 10, 2006

USGS Publications Warehouse

Dewey, James W.; Dellinger, Joseph A.

2008-01-01

We calculated an epicenter for the Offshore Southern Louisiana seismic event of February 10, 2006 (the 'Green Canyon event') that was adopted as the preferred epicenter for the event by the USGS/NEIC. The event is held at a focal depth of 5 km; the focal depth could not be reliably calculated but was most likely between 1 km and 15 km beneath sea level. The epicenter was calculated with a radially symmetric global Earth model similar to that routinely used at the USGS/NEIC for all earthquakes worldwide. The location was calculated using P-waves recorded by seismographic stations from which the USGS/NEIC routinely obtains seismological data, plus data from two seismic exploration arrays, the Atlantis ocean-bottom node array, operated by BP in partnership with BHP Billiton Limited, and the CGG Green Canyon phase VIII multi-client towed-streamer survey. The preferred epicenter is approximately 26 km north of an epicenter earlier published by the USGS/NEIC, which was obtained without benefit of the seismic exploration arrays. We estimate that the preferred epicenter is accurate to within 15 km. We selected the preferred epicenter from a suite of trial calculations that attempted to fit arrival times of seismic energy associated with the Green Canyon event and that explored the effect of errors in the velocity model used to calculate the preferred epicenter. The various trials were helpful in confirming the approximate correctness of the preferred epicenter and in assessing the accuracy of the preferred epicenter, but none of the trial calculations, including that of the preferred epicenter, was able to reconcile arrival-time observations and assumed velocity model as well as is typical for the vast majority of earthquakes in and near the continental United States. We believe that remaining misfits between the preferred solution and the observations reflect errors in interpreted arrival times of emergent seismic phases that are due partly to a temporally extended source

Use of an Annular Silicon Drift Detector (SDD) Versus a Conventional SDD Makes Phase Mapping a Practical Solution for Rare Earth Mineral Characterization.

PubMed

Teng, Chaoyi; Demers, Hendrix; Brodusch, Nicolas; Waters, Kristian; Gauvin, Raynald

2018-06-04

A number of techniques for the characterization of rare earth minerals (REM) have been developed and are widely applied in the mining industry. However, most of them are limited to a global analysis due to their low spatial resolution. In this work, phase map analyses were performed on REM with an annular silicon drift detector (aSDD) attached to a field emission scanning electron microscope. The optimal conditions for the aSDD were explored, and the high-resolution phase maps generated at a low accelerating voltage identify phases at the micron scale. In comparisons between an annular and a conventional SDD, the aSDD performed at optimized conditions, making the phase map a practical solution for choosing an appropriate grinding size, judging the efficiency of different separation processes, and optimizing a REM beneficiation flowsheet.

Earth meandering

NASA Astrophysics Data System (ADS)

Asadiyan, H.; Zamani, A.

2009-04-01

In this paper we try to put away current Global Tectonic Model to look the tectonic evolution of the earth from new point of view. Our new dynamic model is based on study of river meandering (RM) which infer new concept as Earth meandering(EM). In a universal gravitational field if we consider a clockwise spiral galaxy model rotate above Ninety East Ridge (geotectonic axis GA), this system with applying torsion field (likes geomagnetic field) in side direction from Rocky Mt. (west geotectonic pole WGP) to Tibetan plateau TP (east geotectonic pole EGP),it seems that pulled mass from WGP and pushed it in EGP due to it's rolling dynamics. According to this idea we see in topographic map that North America and Green land like a tongue pulled from Pacific mouth toward TP. Actually this system rolled or meander the earth over itself fractaly from small scale to big scale and what we see in the river meandering and Earth meandering are two faces of one coin. River transport water and sediments from high elevation to lower elevation and also in EM, mass transport from high altitude-Rocky Mt. to lower altitude Himalaya Mt. along 'S' shape geodetic line-optimum path which connect points from high altitude to lower altitude as kind of Euler Elastica(EE). These curves are responsible for mass spreading (source) and mass concentration (sink). In this regard, tiltness of earth spin axis plays an important role, 'S' are part of sigmoidal shape which formed due to intersection of Earth rolling with the Earth glob and actual feature of transform fault and river meandering. Longitudinal profile in mature rivers as a part of 'S' curve also is a kind of EE. 'S' which bound the whole earth is named S-1(S order 1) and cube corresponding to this which represent Earth fracturing in global scale named C-1(cube order 1 or side vergence cube SVC), C-1 is a biggest cycle of spiral polygon, so it is not completely closed and it has separation about diameter of C-7. Inside SVC we introduce cone

Bistability and chaos in the Taylor-Green dynamo.

PubMed

Yadav, Rakesh K; Verma, Mahendra K; Wahi, Pankaj

2012-03-01

Using direct numerical simulations, we study dynamo action under Taylor-Green forcing for a magnetic Prandtl number of 0.5. We observe bistability with weak- and strong-magnetic-field branches. Both the dynamo branches undergo subcritical dynamo transition. We also observe a host of dynamo states including constant, periodic, quasiperiodic, and chaotic magnetic fields. One of the chaotic states originates through a quasiperiodic route with phase locking, while the other chaotic attractor appears to follow the Newhouse-Ruelle-Takens route to chaos. We also observe intermittent transitions between quasiperiodic and chaotic states for a given Taylor-Green forcing.

Constraints on High Northern Photosynthesis Increase Using Earth System Models and a Set of Independent Observations

NASA Astrophysics Data System (ADS)

Winkler, A. J.; Brovkin, V.; Myneni, R.; Alexandrov, G.

2017-12-01

Plant growth in the northern high latitudes benefits from increasing temperature (radiative effect) and CO2 fertilization as a consequence of rising atmospheric CO2 concentration. This enhanced gross primary production (GPP) is evident in large scale increase in summer time greening over the 36-year record of satellite observations. In this time period also various global ecosystem models simulate a greening trend in terms of increasing leaf area index (LAI). We also found a persistent greening trend analyzing historical simulations of Earth system models (ESM) participating in Phase 5 of the Coupled Model Intercomparison Project (CMIP5). However, these models span a large range in strength of the LAI trend, expressed as sensitivity to both key environmental factors, temperature and CO2 concentration. There is also a wide spread in magnitude of the associated increase of terrestrial GPP among the ESMs, which contributes to pronounced uncertainties in projections of future climate change. Here we demonstrate that there is a linear relationship across the CMIP5 model ensemble between projected GPP changes and historical LAI sensitivity, which allows using the observed LAI sensitivity as an "emerging constraint" on GPP estimation at future CO2 concentration. This constrained estimate of future GPP is substantially higher than the traditional multi-model mean suggesting that the majority of current ESMs may be significantly underestimating carbon fixation by vegetation in NHL. We provide three independent lines of evidence in analyzing observed and simulated CO2 amplitude as well as atmospheric CO2 inversion products to arrive at the same conclusion.

Elasticity of Deep-Earth Materials at High P and T: Implication for Earths Lower Mantle

NASA Astrophysics Data System (ADS)

Bass, Jay; Sinogeikin, S. V.; Mattern, Estelle; Jackson, J. M.; Matas, J.; Wang, J.; Ricard, Y.

2005-03-01

Brillouin spectroscopy allows measurements of sound velocities and elasticity on phases of geophysical interest at high Pressures and Temperatures. This technique was used to measure the properties of numerous important phases of Earths deep interior. Emphasis is now on measurements at elevated P-T conditions, and measurements on dense polycrystals. Measurements to 60 GPa were made using diamond anvil cells. High temperature is achieved by electrical resistance and laser heating. Excellent results are obtained for polycrystalline samples of dense oxides such as silicate spinels, and (Mg,Al)(Si,Al)O3 --perovskites. A wide range of materials can now be characterized. These and other results were used to infer Earths average lower mantle composition and thermal structure by comparing mineral properties at lower mantle P-T conditions to global Earth models. A formal inversion procedure was used. Inversions of density and bulk sound velocity do not provide robust compositional and thermal models. Including shear properties in the inversions is important to obtain unique solutions. We discuss the range of models consistent with present lab results, and data needed to further refine lower mantle models.

Green certification, e-commerce, and low-carbon economy for international tourist hotels.

PubMed

Chen, Long-Fei

2018-05-22

Increasing population and over-consumption are placing unprecedented demands on agriculture and natural resources. The Earth is suffering from global warning and environmental destruction while our agricultural systems are concurrently degrading land, water, biodiversity, and climate on a global scale. For a sustainable future, green certification, e-commerce, and environment education can boost low-carbon economy with decreasing carbon emissions, but very few researches address them for the hotel industry. This research studies the performance impact of e-commerce, international hotel chain, local hotel chain, and green certification for carbon emission reductions of international tourist hotels of Taiwan. It reveals that, after a sufficiently long time, there is an improvement in the environmental and economic performance of the green-certified hotel group. In addition, it reveals that, as recommended by the operation policy, the international hotel chain group together with e-commerce has better performance than local hotel chain. It is also discussed how to sustain the continuing improvement in low-carbon performance of the hotel industry.

Synthesis of Green-Emitting (La,Gd)OBr:Tb3+ Phosphors

PubMed Central

Kim, Sun Woog; Jyoko, Kazuya; Masui, Toshiyuki; Imanaka, Nobuhito

2010-01-01

Green-emitting phosphors based on lanthanum-gadolinium oxybromide were synthesized in a single phase form by the conventional solid state reaction method, and photoluminescence properties of them were characterized. The excitation peak wavelength of (La1-xGdx)OBr:Tb3+ shifted to the shorter wavelength side with the increase in the crystal field around the Tb3+ ions by doping Gd3+ ions into the La3+ site, and, as a result, the green emission intensity was successfully enhanced. The maximum emission intensity was obtained for (La0.95Gd0.05)OBr:5%Tb3+, where the relative emission intensity was 45% of that of a commercial green-emitting LaPO4:Ce3+,Tb3+ phosphor.

EarthServer: Cross-Disciplinary Earth Science Through Data Cube Analytics

NASA Astrophysics Data System (ADS)

Baumann, P.; Rossi, A. P.

2016-12-01

The unprecedented increase of imagery, in-situ measurements, and simulation data produced by Earth (and Planetary) Science observations missions bears a rich, yet not leveraged potential for getting insights from integrating such diverse datasets and transform scientific questions into actual queries to data, formulated in a standardized way.The intercontinental EarthServer [1] initiative is demonstrating new directions for flexible, scalable Earth Science services based on innovative NoSQL technology. Researchers from Europe, the US and Australia have teamed up to rigorously implement the concept of the datacube. Such a datacube may have spatial and temporal dimensions (such as a satellite image time series) and may unite an unlimited number of scenes. Independently from whatever efficient data structuring a server network may perform internally, users (scientist, planners, decision makers) will always see just a few datacubes they can slice and dice.EarthServer has established client [2] and server technology for such spatio-temporal datacubes. The underlying scalable array engine, rasdaman [3,4], enables direct interaction, including 3-D visualization, common EO data processing, and general analytics. Services exclusively rely on the open OGC "Big Geo Data" standards suite, the Web Coverage Service (WCS). Conversely, EarthServer has shaped and advanced WCS based on the experience gained. The first phase of EarthServer has advanced scalable array database technology into 150+ TB services. Currently, Petabyte datacubes are being built for ad-hoc and cross-disciplinary querying, e.g. using climate, Earth observation and ocean data.We will present the EarthServer approach, its impact on OGC / ISO / INSPIRE standardization, and its platform technology, rasdaman.References: [1] Baumann, et al. (2015) DOI: 10.1080/17538947.2014.1003106 [2] Hogan, P., (2011) NASA World Wind, Proceedings of the 2nd International Conference on Computing for Geospatial Research

Earth Science Geostationary Platform Technology

NASA Technical Reports Server (NTRS)

Wright, Robert L. (Editor); Campbell, Thomas G. (Editor)

1989-01-01

The objective of the workshop was to address problems in science and in four technology areas (large space antenna technology, microwave sensor technology, electromagnetics-phased array adaptive systems technology, and optical metrology technology) related to Earth Science Geostationary Platform missions.

Green thunderstorms

NASA Astrophysics Data System (ADS)

Gallagher, Frank Woolsey, III

Many people around the world have observed green light apparently emanating from severe thunderstorms, but until recently there has been no scientific study of the phenomenon. Green thunderstorms have been observed from time to time in association with deep convection or severe weather events. Some skeptics who have not personally observed a green thunderstorm suggest that they are some kind of illusion. The existence of green thunderstorms has been objectively demonstrated by recording spectra of light from thunderstorms using a handheld spectrophotometer. During the spring and summer of 1995 and the spring of 1996 numerous storms were observed and spectra of the light emanating from these storms were recorded. Observations were made both at the ground and aboard research aircraft. Furthermore, time series of spectra were recorded as the observed color of some storms changed from dark blue to a bluish-green. Several hypotheses have been advanced to explain the occurrence of green light in connection with severe storms. Fankhauser gave some observational support to the belief that green light from thunderstorms is possible and believed that the source of the light is from the blue sky penetrating thin regions in the clouds. Fraser believes that light from the setting sun, in combination with the process of scattering by atmospheric molecules, creates the green light associated with severe weather and the thunderstorm acts only as a black backdrop. Unfortunately, no cloud illuminated by the sun is black and the green airlight produced by the Fraser theory is in reality overwhelmed by light reflected by the cloud. Often the unusual coloration has been attributed to hail or to reflection of light from foliage on the ground. The quantitative measurements made during the observation period fail to support these assumptions. We have observed thunderstorms to be green over ground that was not green and we have observed blue thunderstorms over ground that was green

A synthetic high fidelity, high cadence spectral Earth database

NASA Astrophysics Data System (ADS)

Schwieterman, Edward; Meadows, Victoria; Robinson, Tyler D.; Lustig-Yaeger, Jacob; Sparks, William B.; Cracraft, Misty

2016-10-01

Earth is currently our only, and will always be our best, example of a living planet. While Earth data model comparisons have been effectively used in recent years to validate spectral models, observations by interplanetary spacecraft are limited to "snapshots" in terms of viewing geometry and Earth's dynamic surface and atmosphere state. We use the well-validated Virtual Planetary Laboratory 3D spectral Earth model to generate both simulated disk-averaged spectra and high resolution, spatially resolved spectral data cubes of Earth at a viewing geometry consistent with Lunar viewing angles at wavelengths from the far UV (0.1 μm) the to the far IR (200 μm). The database includes disk-averaged spectra from dates 03/19/2008 to 04/23/2008 at one-hour cadence and fully spectral data cubes for a subset of those times. These spectral products have a wide range of applications including calibration of spacecraft instrumentation (Robinson et al. 2014), modeling the radiation environment of permanently shadowed Lunar craters due to Earthshine (Glenar et al., in prep), and testing the detectability of atmospheric and surface features of an Earth-like planet orbiting a distant star with a large space-based telescope mission concepts such as LUVOIR. These data include the phase and time-dependent changes in spectral biosignatures (O2, O3, CH4, VRE) and habitability markers (N2, H2O, CO2, ocean glint). The advantages of the VPL Earth model data products over 1D spectra traditionally used for testing instrument architectures include accurate modeling of Earth's surface inhomogeneity (continental distribution and ice caps), cloud cover and variability, pole to equator temperature gradients, obliquity, phase-dependent scattering effects, and rotation. We present a subset of this spectral data including anticipated signal-to-noise calculations of an exoEarth twin at different phases using a coronagraph instrument model (Robinson et al. 2015). We also calculate time

Green approach using monolithic column for simultaneous determination of coformulated drugs.

PubMed

Yehia, Ali M; Mohamed, Heba M

2016-06-01

Green chemistry and sustainability is now entirely encompassed across the majority of pharmaceutical companies and research labs. Researchers' attention is careworn toward implementing the green analytical chemistry principles for more eco-friendly analytical methodologies. Solvents play a dominant role in determining the greenness of the analytical procedure. Using safer solvents, the greenness profile of the methodology could be increased remarkably. In this context, a green chromatographic method has been developed and validated for the simultaneous determination of phenylephrine, paracetamol, and guaifenesin in their ternary pharmaceutical mixture. The chromatographic separation was carried out using monolithic column and green solvents as mobile phase. The use of monolithic column allows efficient separation protocols at higher flow rates, which results in short time of analysis. Two-factor three-level experimental design was used to optimize the chromatographic conditions. The greenness profile of the proposed methodology was assessed using eco-scale as a green metrics and was found to be an excellent green method with regard to the usage and production of hazardous chemicals and solvents, energy consumption, and amount of produced waste. The proposed method improved the environmental impact without compromising the analytical performance criteria and could be used as a safer alternate for the routine analysis of the studied drugs. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Phase relations of Fe-Si-Ni alloys at core conditions: Implications for the Earth inner core

NASA Astrophysics Data System (ADS)

Fiquet, G.; Boulard, E.; Auzende, A.; Antonangeli, D.; Badro, J.; Morard, G.; Siebert, J.; Perrillat, J.; Mezouar, M.

2008-12-01

The Earth core consists of a liquid outer core and a solid inner core, which are believed to be made predominantly of iron (Fe). Among all crystallographic structures proposed, a consensus has more or less emerged with the hexagonal closed packed structure -hcp- for iron. The question of the structure of this alloy at core conditions, in particular in vicinity of the melting line is however still largely debated. Among others, a possible thermal and chemical stabilization of body-centered cubic iron in the Earth's core has indeed been proposed with the theoretical calculations of Vocadlo et al. [Nature, 424, 536, 2003]. Recent X-ray experiments have shown the existence of such a bcc structure above 220 GPa at high-temperature for iron- nickel alloys [Dubrovinsky et al., Science, 316, 1880, 2007]. It is also known from density systematics that the Earth's core is made of iron alloyed with light elements [see Poirier, Phys. Earth Planet. Int., 85, 319, 1994]. We recently proposed a compositional model for the Earth's inner core from a systematic study of the effect of light elements on sound velocities at high pressure. Our preferred core model is an inner core which contains 2.3 wt % silicon and traces of oxygen [see Badro et al., Earth Planet. Sci. Lett., 254, 233, 2007 for more details]. Recent studies, however, suggest that small amount of silicon or nickel can substantially affect the phase relations and thermodynamic properties of iron alloys. We present results from an X-ray diffraction carried out at ESRF at high-pressure and high-temperature, using a state-of-the-art double sided laser heating system. We address the question of the structure of this alloy at core conditions. Two different alloys have been synthesized for this experiment, with Fe : 92.4, Si : 3.7, Ni 3.9 and Fe: 88.4, Si: 7.3, Ni: 4.3 in wt %, so as to satisfy the core preferred compositional model described in Badro et al. [2007]. The samples were loaded in a diamond anvil cell with neon as

Safety effects of exclusive and concurrent signal phasing for pedestrian crossing.

PubMed

Zhang, Yaohua; Mamun, Sha A; Ivan, John N; Ravishanker, Nalini; Haque, Khademul

2015-10-01

This paper describes the estimation of pedestrian crash count and vehicle interaction severity prediction models for a sample of signalized intersections in Connecticut with either concurrent or exclusive pedestrian phasing. With concurrent phasing, pedestrians cross at the same time as motor vehicle traffic in the same direction receives a green phase, while with exclusive phasing, pedestrians cross during their own phase when all motor vehicle traffic on all approaches is stopped. Pedestrians crossing at each intersection were observed and classified according to the severity of interactions with motor vehicles. Observation intersections were selected to represent both types of signal phasing while controlling for other physical characteristics. In the nonlinear mixed models for interaction severity, pedestrians crossing on the walk signal at an exclusive signal experienced lower interaction severity compared to those crossing on the green light with concurrent phasing; however, pedestrians crossing on a green light where an exclusive phase was available experienced higher interaction severity. Intersections with concurrent phasing have fewer total pedestrian crashes than those with exclusive phasing but more crashes at higher severity levels. It is recommended that exclusive pedestrian phasing only be used at locations where pedestrians are more likely to comply. Copyright © 2015. Published by Elsevier Ltd.

Phosphors with long-persistent green phosphorescence

DOEpatents

Yen, William M; Jia, Weiyi; Lu, Lizhu; Yuan, Huabiao

2001-01-01

This invention relates to phosphors including long-persistence green phosphors. Phosphors of the invention are represented by the general formula: M.sub.k Al.sub.2 O.sub.4 :2xEu.sup.2+,2yR.sup.3+ wherein k-1-2x-2y, x is a number ranging from about 0.0001 to about 0.05, y is a number ranging from about x to about 3x, M is an alkaline earth metal, and R.sup.3+ is one or more trivalent metal ions. Phosphors of this invention include powders, ceramics, single crystals and single crystal fibers. A method of manufacturing improved phosphors and a method of manufacturing single crystal phosphors are also provided.

Behaviour of Rare Earth Elements during the Earth's core formation

NASA Astrophysics Data System (ADS)

Faure, Pierre; Bouhifd, Mohamed Ali; Boyet, Maud; Hammouda, Tahar; Manthilake, Geeth

2017-04-01

Rare Earth Elements (REE) are classified in the refractory group, which means that they have a high temperature condensation and their volatility-controlled fractionation is limited to high-temperature processes. Anomalies have been measured for Eu, Yb and Sm, which are the REE with the lowest condensation temperatures in CAIs and chondrules (e.g. [1]). REE are particularly abundant in the sulfides of enstatite chondrites, 100 to 1000 times the CI value [e.g. 2,3], proving that these elements are not strictly lithophile under extremely reducing conditions. However by investigating experimentally the impact of Earth's core formation on the behavior of Sm and Nd, we have shown the absence of fractionation between Sm and Nd during the segregation of the metallic phase [4]. Recently, Wohlers and Wood [5] proposed that Nd and Sm could be fractionated in presence of a S-rich alloy phase. However, their results were obtained at pressure and temperature conditions below the plausible conditions of the Earth's core formation. Clearly, large pressure range needs to be covered before well-constrained model can be expected. Furthermore, our preliminary metal-silicate partitioning results show that Ce and Eu have higher metal/silicate partition coefficients than their neighboring elements, and that the presence of sulphur enhances the relative difference between partition coefficients. In this presentation, we will present and discuss new metal-silicate partition coefficients of all REE at a deep magma ocean at pressures ranging from those of the uppermost upper mantle ( 5 GPa) to a maximum pressure expected in the range of 20 GPa, temperatures ranging from 2500 to about 3000 K, and oxygen fugacities within IW-1 to IW-5 (1 to 5 orders of magnitude lower than the iron-wüstite buffer). We will discuss the effect of S, as well as the effect of H2O on the behaviour of REE during the Earth's core formation: recent models suggest that contrary to currently accepted beliefs, the

NASA's Van Allen Probes Discover a Surprise Circling Earth

NASA Image and Video Library

2017-12-08

Two giant swaths of radiation, known as the Van Allen Belts, surrounding Earth were discovered in 1958. In 2012, observations from the Van Allen Probes showed that a third belt can sometimes appear. The radiation is shown here in yellow, with green representing the spaces between the belts. Credit: NASA/Van Allen Probes/Goddard Space Flight Center To read more go to: www.nasa.gov/mission_pages/rbsp/news/third-belt.html NASA image use policy. NASA Goddard Space Flight Center enables NASA’s mission through four scientific endeavors: Earth Science, Heliophysics, Solar System Exploration, and Astrophysics. Goddard plays a leading role in NASA’s accomplishments by contributing compelling scientific knowledge to advance the Agency’s mission. Follow us on Twitter Like us on Facebook Find us on Instagram

Rare-earth-doped optical-fiber core deposition using full vapor-phase SPCVD process

NASA Astrophysics Data System (ADS)

Barnini, A.; Robin, T.; Cadier, B.; Aka, G.; Caurant, D.; Gotter, T.; Guyon, C.; Pinsard, E.; Guitton, P.; Laurent, A.; Montron, R.

2017-02-01

One key parameter in the race toward ever-higher power fiber lasers remains the rare earth doped optical core quality. Modern Large Mode Area (LMA) fibers require a fine radial control of the core refractive index (RI) close to the silica level. These low RI are achieved with multi-component materials that cannot be readily obtained using conventional solution doping based Modified Chemical Vapor Deposition (MCVD) technology. This paper presents a study of such optical material obtained through a full-vapor phase Surface Plasma Chemical Vapor Deposition (SPCVD). The SPCVD process generates straight glassy films on the inner surface of a thermally regulated synthetic silica tube under vacuum. The first part of the presented results points out the feasibility of ytterbium-doped aluminosilicate fibers by this process. In the second part we describe the challenge controlling the refractive index throughout the core diameter when using volatile fluorine to create efficient LMA fiber profiles. It has been demonstrated that it is possible to counter-act the loss of fluorine at the center of the core by adjusting the core composition locally. Our materials yielded, when used in optical fibers with numerical apertures ranging from 0.07 to 0.09, power conversion efficiency up to 76% and low background losses below 20 dB/km at 1100nm. Photodarkening has been measured to be similar to equivalent MCVD based fibers. The use of cerium as a co-dopant allowed for a complete mitigation of this laser lifetime detrimental effect. The SPCVD process enables high capacity preforms and is particularly versatile when it comes to radial tailoring of both rare earth doping level and RI. Large core diameter preforms - up to 4mm - were successfully produced.

A 2-Phase Labeling and Choice Architecture Intervention to Improve Healthy Food and Beverage Choices

PubMed Central

Sonnenberg, Lillian; Riis, Jason; Barraclough, Susan; Levy, Douglas E.

2012-01-01

Objectives. We assessed whether a 2-phase labeling and choice architecture intervention would increase sales of healthy food and beverages in a large hospital cafeteria. Methods. Phase 1 was a 3-month color-coded labeling intervention (red = unhealthy, yellow = less healthy, green = healthy). Phase 2 added a 3-month choice architecture intervention that increased the visibility and convenience of some green items. We compared relative changes in 3-month sales from baseline to phase 1 and from phase 1 to phase 2. Results. At baseline (977 793 items, including 199 513 beverages), 24.9% of sales were red and 42.2% were green. Sales of red items decreased in both phases (P < .001), and green items increased in phase 1 (P < .001). The largest changes occurred among beverages. Red beverages decreased 16.5% during phase 1 (P < .001) and further decreased 11.4% in phase 2 (P < .001). Green beverages increased 9.6% in phase 1 (P < .001) and further increased 4.0% in phase 2 (P < .001). Bottled water increased 25.8% during phase 2 (P < .001) but did not increase at 2 on-site comparison cafeterias (P < .001). Conclusions. A color-coded labeling intervention improved sales of healthy items and was enhanced by a choice architecture intervention. PMID:22390518

EarthEd Online: Open Source Online Software to Support Large Courses

NASA Astrophysics Data System (ADS)

Prothero, W. A.

2003-12-01

from the course web server. Students rate the writing assignments as the most effective learning activity in the course. This project is in an evaluation and dissemination phase. An open source model is planned for distribution. For documentation and information about the EarthEd team, see: http://oceanography.geol.ucsb.edu/Collab/software.html

Non-rare earth magnetic nanoparticles

DOEpatents

Carpenter, Everett E.; Huba, Zachary J.; Carroll, Kyler J.; Farghaly, Ahmed; Khanna, Shiv N.; Qian, Meichun; Bertino, Massimo

2017-09-26

Continuous flow synthetic methods are used to make single phase magnetic metal alloy nanoparticles that do not contain rare earth metals. Soft and hard magnets made from the magnetic nanoparticles are used for a variety of purposes, e.g. in electric motors, communication devices, etc.

Frequency-domain Green's functions for radar waves in heterogeneous 2.5D media

USGS Publications Warehouse

Ellefsen, K.J.; Croize, D.; Mazzella, A.T.; McKenna, J.R.

2009-01-01

Green's functions for radar waves propagating in heterogeneous 2.5D media might be calculated in the frequency domain using a hybrid method. The model is defined in the Cartesian coordinate system, and its electromagnetic properties might vary in the x- and z-directions, but not in the y-direction. Wave propagation in the x- and z-directions is simulated with the finite-difference method, and wave propagation in the y-direction is simulated with an analytic function. The absorbing boundaries on the finite-difference grid are perfectly matched layers that have been modified to make them compatible with the hybrid method. The accuracy of these numerical Greens functions is assessed by comparing them with independently calculated Green's functions. For a homogeneous model, the magnitude errors range from -4.16% through 0.44%, and the phase errors range from -0.06% through 4.86%. For a layered model, the magnitude errors range from -2.60% through 2.06%, and the phase errors range from -0.49% through 2.73%. These numerical Green's functions might be used for forward modeling and full waveform inversion. ?? 2009 Society of Exploration Geophysicists. All rights reserved.

[Comparison of productivity of different vitamin green technologies under the space station conditions].

PubMed

Levinskikh, M A

2002-01-01

At present, fresh plant products for nutrition of the International space station (ISS) crews are delivered from Earth in small quantities. Regular supply of additional fresh greens could be positive for improvement as of nutrition, so psychophysical state of ISS crews. Vitamin greens can be produced with the use of various technologies: planting leaf cultures in greenhouses, forcing the greens from onions and root vegetables (onion, garlic, chicory, beet, parsley etc.), and germinating seeds. Purpose of this study was to compare productivity of these technologies in order to specify inputs for designers of a vitamin greenhouse to be mounted in the space station and a Martian vehicle. Based on comparison of the productivity of various technologies, specific productivity of different greenhouses per a unit of power consumption, and a volume unit it will be maximal if used for germinating seeds and minimal if used for growing leaf vegetables in a greenhouse with a cylindrical crop surface.

Earth observation (Australia) taken by Galileo spacecraft

NASA Technical Reports Server (NTRS)

1990-01-01

Earth observation of Australia was taken by Galileo Spacecraft after completing its first Earth Gravity Assist. Color image of the Simpson Desert in Australia was obtained by Galileo at about 2:30 pm Pacific Standard Time (PST), 12-08-90, at a range of more than 35,000 miles. The color composite was made from images taken through the red, green, and violet filters. The area shown, about 280 miles wide by about 340 miles north-to-south, is southeast of Alice Springs. At lower left is Lake Eyre, a salt lake below sea level, subject to seasonal water-level fluctuations; when this image was acquired the lake was nearly dry. At lower right is the greenish Lake Blanche. Fields of linear sand dunes stretch north and east of Lake Eyre, shaped by prevailing winds from the south and showing, in different colors, the various sources and/or ages of their sands. Photo provided by Jet Propulsion Laboratory (JPL) with alternate number P-37331, 12-19-90.

Check-Up of Planet Earth at the Turn of the Millennium: Anticipated New Phase in Earth Sciences

NASA Technical Reports Server (NTRS)

Kaufman, Y. J.; Ramanathan, V.

1998-01-01

Langley's remarkable solar and lunar spectra collected from Mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. In 1999, NASA's Earth Observing AM Satellite (EOS-AM) will repeat Langley's experiment, but for the entire planet, thus pioneering calibrated spectral observations from space. Conceived in response to real environmental problems, EOS-AM, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution of few kilometers on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-AM can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment.

Access, labor, and wild floral greens management in western Washington's forests.

Treesearch

Kathryn A. Lynch; Rebecca J. McLain

2003-01-01

This report compares the changes that took place between 1994 and 2002 in the nontimber forest product (NTFP) management regime that governed access to floral greens and other NTFPs in western coastal Washington. A rapid rural appraisal approach was used to gather data from 24 NTFP stakeholders during phase I (1994) and from 37 NTFP stakeholders during phase II (2002...

Subsonic Ultra Green Aircraft Research. Phase II - Volume I; Truss Braced Wing Design Exploration

NASA Technical Reports Server (NTRS)

Bradley, Marty K.; Droney, Christopher K.; Allen, Timothy J.

2015-01-01

This report summarizes the Truss Braced Wing (TBW) work accomplished by the Boeing Subsonic Ultra Green Aircraft Research (SUGAR) team, consisting of Boeing Research and Technology, Boeing Commercial Airplanes, General Electric, Georgia Tech, Virginia Tech, NextGen Aeronautics, and Microcraft. A multi-disciplinary optimization (MDO) environment defined the geometry that was further refined for the updated SUGAR High TBW configuration. Airfoil shapes were tested in the NASA TCT facility, and an aeroelastic model was tested in the NASA TDT facility. Flutter suppression was successfully demonstrated using control laws derived from test system ID data and analysis models. Aeroelastic impacts for the TBW design are manageable and smaller than assumed in Phase I. Flutter analysis of TBW designs need to include pre-load and large displacement non-linear effects to obtain a reasonable match to test data. With the updated performance and sizing, fuel burn and energy use is reduced by 54% compared to the SUGAR Free current technology Baseline (Goal 60%). Use of the unducted fan version of the engine reduces fuel burn and energy by 56% compared to the Baseline. Technology development roadmaps were updated, and an airport compatibility analysis established feasibility of a folding wing aircraft at existing airports.

The Concept Currency of K-12 Science Textbooks Relative to Earth Science Concepts.

ERIC Educational Resources Information Center

Janke, Delmar Lester

This study was undertaken to determine the degree of agreement between science textbooks and scholars in earth science relative to earth science concepts to be included in the K-12 science curriculum. The study consisted of two phases: (1) the identification of a sample of earth science concepts rated by earth scientists as important for inclusion…

EarthCube: A Community Organization for Geoscience Cyberinfrastructure

NASA Astrophysics Data System (ADS)

Patten, K.; Allison, M. L.

2014-12-01

The National Science Foundation's (NSF) EarthCube initiative is a community-driven approach to building cyberinfrastructure for managing, sharing, and exploring geoscience data and information to better address today's grand-challenge science questions. The EarthCube Test Enterprise Governance project is a two-year effort seeking to engage diverse geo- and cyber-science communities in applying a responsive approach to the development of a governing system for EarthCube. During Year 1, an Assembly of seven stakeholder groups representing the broad EarthCube community developed a draft Governance Framework. Finalized at the June 2014 EarthCube All Hands Meeting, this framework will be tested during the demonstration phase in Year 2, beginning October 2014. A brief overview of the framework: Community-elected members of the EarthCube Leadership Council will be responsible for managing strategic direction and identifying the scope of EarthCube. Three Standing Committees will also be established to oversee the development of technology and architecture, to coordinate among new and existing data facilities, and to represent the academic geosciences community in driving development of EarthCube cyberinfrastructure. An Engagement Team and a Liaison Team will support communication and partnerships with internal and external stakeholders, and a central Office will serve a logistical support function to the governance as a whole. Finally, ad hoc Working Groups and Special Interest Groups will take on other issues related to EarthCube's goals. The Year 2 demonstration phase will test the effectiveness of the proposed framework and allow for elements to be changed to better meet community needs. It will begin by populating committees and teams, and finalizing leadership and decision-making processes to move forward on community-selected priorities including identifying science drivers, coordinating emerging technical elements, and coming to convergence on system architecture. A

Oxycarbonitride phosphors and light emitting devices using the same

DOEpatents

Li, Yuanqiang; Romanelli, Michael Dennis; Tian, Yongchi

2013-10-08

Disclosed herein is a novel family of oxycarbidonitride phosphor compositions and light emitting devices incorporating the same. Within the sextant system of M--Al--Si--O--N--C--Ln and quintuplet system of M--Si--O--N--C--Ln (M=alkaline earth element, Ln=rare earth element), the phosphors are composed of either one single crystalline phase or two crystalline phases with high chemical and thermal stability. In certain embodiments, the disclosed phosphor of silicon oxycarbidonitrides emits green light at wavelength between 530-550 nm. In further embodiments, the disclosed phosphor compositions emit blue-green to yellow light in a wavelength range of 450-650 nm under near-UV and blue light excitation.

Oxycarbonitride phosphors and light emitting devices using the same

DOEpatents

Li, Yuanqiang; Romanelli, Michael Dennis; Tian, Yongchi

2014-07-08

Disclosed herein is a novel family of oxycarbonitride phosphor compositions and light emitting devices incorporating the same. Within the sextant system of M--Al--Si--O--N--C--Ln and quintuplet system of M--Si--O--N--C--Ln (M=alkaline earth element, Ln=rare earth element), the phosphors are composed of either one single crystalline phase or two crystalline phases with high chemical and thermal stability. In certain embodiments, the disclosed phosphor of silicon oxycarbonitrides emits green light at wavelength between 530-550 nm. In further embodiments, the disclosed phosphor compositions emit blue-green to yellow light in a wavelength range of 450-650 nm under near-UV and blue light excitation.

The Dark Side of the Earth

NASA Astrophysics Data System (ADS)

Frankel, Henry

1986-10-01

Wood's The Dark Side of the Earth is another addition to the growing list of books on the recent revolution in the earth sciences. Wood rightly points out that any new book on the topic should break new ground. In the preface, he writes of himself and his book that he has benefited from previous accounts by saving himself research time, and that his book, unlike others, “attempts to tell one complete story of the study of the Earth, geologists, geophysicists, dreamers and all” (p. vi). Wood is ambitious, for his work covers much of 19th-century geology as well as the development, reception, rejection, and eventual acceptance of mobilist ideas. Before discussing the work of the German meteorologist and geophysicist Alfred L. Wegener, American glacial geomorphologist Frank Taylor, and several of their predecessors who proposed “mobilist” ideas, he manages to string together brief descriptions of the contributions of (among others) German mineralogist Abraham Gottlob Werner, British geologists James Hutten and John Playfair, British engineer William Smith, British geologist Charles Lyell, American geologists James Hall and James Dwight Dana, British volcanologist William Lowthian Green, American geologist Grove Karl Gilbert, French geologist Elie de Beaumont, British geologist and mathematician Osmond Fisher, American geologist Clarence Dutton, British mathematician and physicist Lord Kelvin, Austrian geologist Eduard Suess, French geologist Marcel Bertrand, and American geologist Thomas Chrowder Chamberlin. Moreover, Wood offers an interesting thesis about the revolution in the earth sciences. He claims that the real revolution was not the replacement of fixist views with the mobilist ones of sea floor spreading and plate tectonics, but rather the replacement of geology with the new discipline of the earth sciences in which geophysics and geochemistry play the central role.

Method for testing earth samples for contamination by organic contaminants

DOEpatents

Schabron, John F.

1996-01-01

Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants.

Method for testing earth samples for contamination by organic contaminants

DOEpatents

Schabron, J.F.

1996-10-01

Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants. 2 figs.

Electroluminescence color tuning between green and red from metal-oxide-semiconductor devices fabricated by spin-coating of rare-earth (terbium + europium) organic compounds on silicon

NASA Astrophysics Data System (ADS)

Matsuda, Toshihiro; Hattori, Fumihiro; Iwata, Hideyuki; Ohzone, Takashi

2018-04-01

Color tunable electroluminescence (EL) from metal-oxide-semiconductor devices with the rare-earth elements Tb and Eu is reported. Organic compound liquid sources of (Tb + Ba) and Eu with various Eu/Tb ratios from 0.001 to 0.4 were spin-coated on an n+-Si substrate and annealed to form an oxide insulator layer. The EL spectra had only peaks corresponding to the intrashell Tb3+/Eu3+ transitions in the spectral range from green to red, and the intensity ratio of the peaks was appropriately tuned using the appropriate Eu/Tb ratios in liquid sources. Consequently, the EL emission colors linearly changed from yellowish green to yellowish orange and eventually to reddish orange on the CIE chromaticity diagram. The gate current +I G current also affected the EL colors for the medium-Eu/Tb-ratio device. The structure of the surface insulator films analyzed by cross-sectional transmission electron microscopy (TEM), X-ray diffraction (XRD) analysis, and X-ray photoelectron spectroscopy (XPS) has four layers, namely, (Tb4O7 + Eu2O3), [Tb4O7 + Eu2O3 + (Tb/Eu/Ba)SiO x ], (Tb/Eu/Ba)SiO x , and SiO x -rich oxide. The EL mechanism proposed is that electrons injected from the Si substrate into the SiO x -rich oxide and Tb/Eu/Ba-silicate layers become hot electrons accelerated in a high electric field, and then these hot electrons excite Tb3+ and Eu3+ ions in the Tb4O7/Eu2O3 layers resulting in EL emission from Tb3+ and Eu3+ intrashell transitions.

The Green Footprint Project: How Middle School Students Inspired Their Community and Raised Their Self-Worth

ERIC Educational Resources Information Center

Cortez-Riggio, Kim-Marie

2011-01-01

Project "Green Footprint" is a local community environment project created by fifth-grade students to remind the citizens of their school (and Earth) to tread lightly on Mother Nature's creations. The students chose to focus on the air quality outside the school, specifically the carbon emissions produced by idling cars. Students complete Internet…

Greenness and Carbon Stocks of Mangroves: A climate-driven Effect

NASA Astrophysics Data System (ADS)

Lule, A. V.; Colditz, R. R.; Herrera-Silveira, J.; Guevara, M.; Rodriguez-Zuniga, M. T.; Cruz, I.; Ressl, R.; Vargas, R.

2017-12-01

Mangroves cover less than 1% of the earth's surface and are one o­­­f the most productive ecosystems of the world. They are highly vulnerable to climate variability due to their sensitivity to environmental changes; therefore, there are scientific and societal needs to designed frameworks to assess mangrove's vulnerability. We study the relationship between climate drivers, canopy greenness and carbon stocks to quantify a potential climate-driven effect on mangrove carbon dynamics. We identify greenness trends and their relationships with climate drivers and carbon stocks throughout 15 years (2001-2015) across mangrove forests of Mexico. We defined several categories for mangroves: a) Arid mangroves with superficial water input (ARsw); b) Humid mangroves with interior or underground water input (HUiw); and c) Humid mangroves with superficial water input (HUsw). We found a positive significant trend of greenness for ARsw and HUsw categories (p<0.01), a significant increment in temperature for both humid mangrove's categories (p<0.001), and a significant decrease in precipitation for ARsw (p<0.001). All mangrove categories showed higher greenness values during winter; which is likely driven by temperature with a lag of -3 to -5 months (r2 > 0.69). Precipitation and temperature drive canopy greenness only across HUsw. Regarding carbon stocks, the HUiw shows the lower amount of aboveground carbon (AGC; 12.7 Mg C ha-1) and the higher belowground carbon (BGC; 219 Mg C ha-1). The HUsw shows the higher amount of AGC (169.5 Mg C ha-1) and the ARsw the lower of BGC (92.4 Mg C ha-1). Climate drivers are better related with canopy greenness and AGC for both humid mangrove categories (r2 > 0.48), while the relationship of BGC and canopy greenness is lower for all categories (r2 < 0.21). Our results have implications for better understanding mangrove's ecosystem function and environmental services, as well as their potential vulnerability to climate variability.

EAARL Coastal Topography - Northeast Barrier Islands 2007: Bare Earth

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Sallenger, A.H.; Wright, C. Wayne; Yates, Xan; Bonisteel, Jamie M.

2008-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived bare earth (BE) topography were produced collaboratively by the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the northeast coastal barrier islands in New York and New Jersey, acquired April 29-30 and May 15-16, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom

EAARL Coastal Topography-Pearl River Delta 2008: Bare Earth

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Miner, Michael D.; Yates, Xan; Bonisteel, Jamie M.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived bare earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the University of New Orleans (UNO), Pontchartrain Institute for Environmental Sciences (PIES), New Orleans, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Pearl River Delta in Louisiana and Mississippi, acquired March 9-11, 2008. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the

EAARL Topography - Vicksburg National Military Park 2008: Bare Earth

USGS Publications Warehouse

Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Segura, Martha; Yates, Xan

2008-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived bare earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Vicksburg National Military Park in Mississippi, acquired on March 6, 2008. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed

EAARL Coastal Topography-Chandeleur Islands, Louisiana, 2010: Bare Earth

USGS Publications Warehouse

Nayegandhi, Amar; Bonisteel-Cormier, Jamie M.; Brock, John C.; Sallenger, A.H.; Wright, C. Wayne; Nagle, David B.; Vivekanandan, Saisudha; Yates, Xan; Klipp, Emily S.

2010-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and submerged topography datasets were produced collaboratively by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL, and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of a portion of the Chandeleur Islands, acquired March 3, 2010. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom

19 CFR 351.522 - Green light and green box subsidies.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 19 Customs Duties 3 2010-04-01 2010-04-01 false Green light and green box subsidies. 351.522... COUNTERVAILING DUTIES Identification and Measurement of Countervailable Subsidies § 351.522 Green light and green... domestic support measures that are provided to certain agricultural products (i.e., products listed in...

Earth Shadows and the SEV Angle of MAP's Lissajous Orbit At L2

NASA Technical Reports Server (NTRS)

Edery, Ariel

2002-01-01

The Microwave Anisotropy Probe (MAP) launched successfully on June 30, 2001 and is presently in a Lissajous orbit about the Sun-Earth libration point L2. To avoid Earth shadows at L2, the Sun-Earth-Vehicle (SEV) angle of MAP has to be greater than 0.5 deg for an extended mission of four years. An equation is derived for the SEV angle in terms of the phase angle, frequencies and amplitudes of the Lissajous. The SEV angle is shown to oscillate with a period of 90.4 days within an amplitude envelope of period 13.9 years. A range of phase angles that avoids shadows is identified. MAP'S present phase angle is within this range and will avoid shadows for approximately 5.8 years.

New Instrumentation for Phase Partitioning

NASA Technical Reports Server (NTRS)

Harris, J. M.

1985-01-01

Cells and molecules can be purified by partitioning between the two immiscible liquid phases formed by aqueous solutions of poly/ethylene glycol and dextran. Such purification can be more selective, higher yielding, and less destructive to sensitive biological materials than other available techniques. Earth's gravitational field is a hindering factor as it causes sedimentation of particles to be purified and shear-induced particle randomization. The present proposal is directed toward developing new instrumentation for performing phase partitioning both on Earth and in microgravity.

Structure and dynamics of Earth's lower mantle.

PubMed

Garnero, Edward J; McNamara, Allen K

2008-05-02

Processes within the lowest several hundred kilometers of Earth's rocky mantle play a critical role in the evolution of the planet. Understanding Earth's lower mantle requires putting recent seismic and mineral physics discoveries into a self-consistent, geodynamically feasible context. Two nearly antipodal large low-shear-velocity provinces in the deep mantle likely represent chemically distinct and denser material. High-resolution seismological studies have revealed laterally varying seismic velocity discontinuities in the deepest few hundred kilometers, consistent with a phase transition from perovskite to post-perovskite. In the deepest tens of kilometers of the mantle, isolated pockets of ultralow seismic velocities may denote Earth's deepest magma chamber.

Phase-Shift Interferometry with a Digital Photocamera

ERIC Educational Resources Information Center

Vannoni, Maurizio; Trivi, Marcelo; Molesini, Giuseppe

2007-01-01

A phase-shift interferometry experiment is proposed, working on a Twyman-Green optical configuration with additional polarization components. A guideline is provided to modern phase-shift interferometry, using concepts and laboratory equipment at the level of undergraduate optics courses. (Contains 5 figures.)

Structural phase transitions in yttrium under ultrahigh pressures

NASA Astrophysics Data System (ADS)

Samudrala, Gopi K.; Tsoi, Georgiy M.; Vohra, Yogesh K.

2012-09-01

X-ray diffraction studies were carried out on the rare earth metal yttrium up to 177 GPa in a diamond anvil cell at room temperature. Yttrium was compressed to 37% of its initial volume at the highest pressure. The rare earth crystal structure sequence hcp → Sm type → dhcp → mixed(dhcp + fcc) → distorted fcc (dfcc) is observed in yttrium below 50 GPa. The dfcc (hR24) phase has been observed to persist in the pressure range of 50-95 GPa. A structural transition from dfcc to a low symmetry phase has been observed in yttrium at 99 ± 4 GPa with a volume change of - 2.6%. This low symmetry phase has been identified as a monoclinic C2/m phase, which has also been observed in other rare earth elements under high pressures. The appearance of this low symmetry monoclinic phase in yttrium shows that its electronic structure under extreme conditions resembles that of heavy rare earth metals, with a significant increase in d-band character of the valence electrons and possibly some f-electron states near the Fermi level.

Structural phase transitions in yttrium under ultrahigh pressures.

PubMed

Samudrala, Gopi K; Tsoi, Georgiy M; Vohra, Yogesh K

2012-09-12

X-ray diffraction studies were carried out on the rare earth metal yttrium up to 177 GPa in a diamond anvil cell at room temperature. Yttrium was compressed to 37% of its initial volume at the highest pressure. The rare earth crystal structure sequence hcp → Sm type → dhcp → mixed(dhcp + fcc) → distorted fcc (dfcc) is observed in yttrium below 50 GPa. The dfcc (hR24) phase has been observed to persist in the pressure range of 50-95 GPa. A structural transition from dfcc to a low symmetry phase has been observed in yttrium at 99 ± 4 GPa with a volume change of - 2.6%. This low symmetry phase has been identified as a monoclinic C2/m phase, which has also been observed in other rare earth elements under high pressures. The appearance of this low symmetry monoclinic phase in yttrium shows that its electronic structure under extreme conditions resembles that of heavy rare earth metals, with a significant increase in d-band character of the valence electrons and possibly some f-electron states near the Fermi level.

A LOW-COST RARE EARTH ELEMENTS RECOVERY TECHNOLOGY - PHASE I

EPA Science Inventory

Determination of green, blue and yellow artificial food colorants and their abuse in herb-coloured green Easter beers on tap.

PubMed

Stachová, Ivana; Lhotská, Ivona; Solich, Petr; Šatínský, Dalibor

2016-07-01

Beer is one of the most popular alcoholic beverages worldwide. For consumer acceptance, significant factors are its taste, flavour and colour. This study determines selected synthetic green, blue and yellow food colorants in popular Easter herb-coloured green beers on tap produced in breweries on Holy Thursday. The abuse of beer colouring with Tartrazine (E 102), Quinoline yellow (E 104), Sunset yellow (E 110), Patent blue (E 131), Indigo carmine (E 132), Brilliant blue FCF (E 133), Green S (E 142) and Fast green FCF (E 143) was assessed in 11 green beer samples purchased in local restaurants. HPLC was used for the separation and detection of artificial colorants with diode-array detection and a Chromolith Performance CN 100 × 4.6 mm column with guard pre-column Chromolith CN 5 × 4.6 mm. Separation was performed in gradient elution with mobile phase containing methanol-aqueous 2% ammonium acetate at pH 7.0. The study showed that eight beers (70%) marketed in the Czech Republic contained artificial colorants (Tartrazine and Brilliant blue FCF). The concentration of colorants found in analysed green herb-coloured beers ranged from 1.58 to 3.49 mg l(-)(1) for Tartrazine, 0.45-2.18 mg l(-)(1) for Brilliant blue, while Indigo carmine was detected only once at concentration 2.36 mg l(-)(1). Only three beers showed no addition of the synthetic colorants. However, the levels of artificial colorants found in beers marketed in the Czech region were very low and did not show a serious risk for consumers' health.

Extraction and preparation of high-aroma and low-caffeine instant green teas by the novel column chromatographic extraction method with gradient elution.

PubMed

Li, Qing-Rong; Wu, Min; Huang, Rui-Jie; Chen, Ya-Fei; Chen, Chan-Jian; Li, Hui; Ni, He; Li, Hai-Hang

2017-06-01

The lack of aroma and natural taste is a critical problem in production and consumption of instant green teas. A method to prepare instant green teas high in-natural-aroma and low-caffeine by the novel column chromatographic extraction with gradient elution is reported. This method simultaneously extracted aroma (or volatile) and non-aroma compounds from green tea. Green tea was loaded into columns with 2.0-fold of petroleum ether (PE): ethanol (8:2). After standing for 3 h until the aroma compounds dissolved, the column was sequentially eluted with 3.0-fold 40% ethanol and 3.5-fold water. The eluant was collected together and automatically separated into PE and ethanol aqueous phases. The aroma extracts was obtained by vacuum-evaporation of PE phase at 45 °C. The ethanol aqueous phase was vacuum-concentrated to aqueous and partially or fully decaffeinated with 4% or 9% charcoal at 70 °C. A regular instant green tea with epigallocatechin-3-gallate: caffeine of 3.5:1 and a low-caffeine instant green tea (less than 1% caffeine) with excellent aroma and taste were prepared, by combining the aroma and non-aroma extracts at a 1:10 ratio. This work provides a practical approach to solve the low-aroma and low-taste problems in the production of high quality instant green teas.

Green Thunderstorms Observed.

NASA Astrophysics Data System (ADS)

Gallagher, Frank W., III; Beasley, William H.; Bohren, Craig F.

1996-12-01

Green thunderstorms have been observed from time to time in association with deep convection or severe weather events. Often the green coloration has been attributed to hail or to reflections of light from green foliage on the ground. Some skeptics who have not personally observed a green thunderstorm do not believe that green thunderstorms exist. They suggest that the green storms may be fabrications by excited observers. The authors have demonstrated the existence of green thunderstorms objectively using a spectrophotometer. During the spring and summer of 1995 the authors observed numerous storms and recorded hundreds of spectra of the light emanating corn these storms. It was found that the subjective judgment of colors can vary somewhat between observers, but the variation is usually in the shade of green. The authors recorded spectra of green and nongreen thunderstorms and recorded spectral measurements as a storm changed its appearance from dark blue to a bluish green. The change in color is gradual when observed from a stationary position. Also, as the light from a storm becomes greener, the luminance decreases. The authors also observed and recorded the spectrum of a thunderstorm during a period of several hours as they flew in an aircraft close to a supercell that appeared somewhat green. The authors' observations refute the ground reflection hypothesis and raise questions about explanations that require the presence of hail.

Industrial application of green chromatography--I. Separation and analysis of niacinamide in skincare creams using pure water as the mobile phase.

PubMed

Yang, Yu; Strickland, Zackary; Kapalavavi, Brahmam; Marple, Ronita; Gamsky, Chris

2011-03-15

In this work, chromatographic separation of niacin and niacinamide using pure water as the sole component in the mobile phase has been investigated. The separation and analysis of niacinamide have been optimized using three columns at different temperatures and various flow rates. Our results clearly demonstrate that separation and analysis of niacinamide from skincare products can be achieved using pure water as the eluent at 60°C on a Waters XTerra MS C18 column, a Waters XBridge C18 column, or at 80°C on a Hamilton PRP-1 column. The separation efficiency, quantification quality, and analysis time of this new method are at least comparable with those of the traditional HPLC methods. Compared with traditional HPLC, the major advantage of this newly developed green chromatography technique is the elimination of organic solvents required in the HPLC mobile phase. In addition, the pure water chromatography separations described in this work can be directly applied in industrial plant settings without further modification of the existing HPLC equipment. Copyright © 2011 Elsevier B.V. All rights reserved.

Human Exploration of Earth's Neighborhood and Mars

NASA Technical Reports Server (NTRS)

Condon, Gerald

2003-01-01

The presentation examines Mars landing scenarios, Earth to Moon transfers comparing direct vs. via libration points. Lunar transfer/orbit diagrams, comparison of opposition class and conjunction class missions, and artificial gravity for human exploration missions. Slides related to Mars landing scenarios include: mission scenario; direct entry landing locations; 2005 opportunity - Type 1; Earth-mars superior conjunction; Lander latitude accessibility; Low thrust - Earth return phase; SEP Earth return sequence; Missions - 200, 2007, 2009; and Mission map. Slides related to Earth to Moon transfers (direct vs. via libration points (L1, L2) include libration point missions, expeditionary vs. evolutionary, Earth-Moon L1 - gateway for lunar surface operations, and Lunar mission libration point vs. lunar orbit rendezvous (LOR). Slides related to lunar transfer/orbit diagrams include: trans-lunar trajectory from ISS parking orbit, trans-Earth trajectories, parking orbit considerations, and landing latitude restrictions. Slides related to comparison of opposition class (short-stay) and conjunction class (long-stay) missions for human exploration of Mars include: Mars mission planning, Earth-Mars orbital characteristics, delta-V variations, and Mars mission duration comparison. Slides related to artificial gravity for human exploration missions include: current configuration, NEP thruster location trades, minor axis rotation, and example load paths.

Studies on phase transition temperature of rare earth niobates Ln3NbO7 (Ln = Pr, Sm, Eu) with orthorhombic fluorite-related structure

NASA Astrophysics Data System (ADS)

Hinatsu, Yukio; Doi, Yoshihiro

2017-06-01

The phase transition of ternary rare earth niobates Ln3NbO7 (Ln = Pr, Sm, Eu) was investigated by the measurements of high-temperature and low-temperature X-ray diffraction, differential scanning calorimetry (DSC) and differential thermal analysis (DTA). These compounds crystallize in an orthorhombic superstructure derived from the structure of cubic fluorite (space group Pnma for Ln = Pr; C2221 for Ln = Sm, Eu). Sm3NbO7 undergoes the phase transition when the temperature is increased through ca. 1080 K and above the transition temperature, its structure is well described with space group Pnma. For Eu3NbO7, the phase transition was not observed up to 1273 K Pr3NbO7 indicates the phase transition when the temperature is increased through ca. 370 K. The change of the phase transition temperature against the Ln ionic radius for Ln3NbO7 is quite different from those for Ln3MO7 (M = Mo, Ru, Re, Os, or Ir), i.e., no systematic relationship between the phase transition temperature and the Ln ionic radius has been observed for Ln3NbO7 compounds.

Multi-Hierarchical Gray Correlation Analysis Applied in the Selection of Green Building Design Scheme

NASA Astrophysics Data System (ADS)

Wang, Li; Li, Chuanghong

2018-02-01

As a sustainable form of ecological structure, green building is widespread concerned and advocated in society increasingly nowadays. In the survey and design phase of preliminary project construction, carrying out the evaluation and selection of green building design scheme, which is in accordance with the scientific and reasonable evaluation index system, can improve the ecological benefits of green building projects largely and effectively. Based on the new Green Building Evaluation Standard which came into effect on January 1, 2015, the evaluation index system of green building design scheme is constructed taking into account the evaluation contents related to the green building design scheme. We organized experts who are experienced in construction scheme optimization to mark and determine the weight of each evaluation index through the AHP method. The correlation degree was calculated between each evaluation scheme and ideal scheme by using multilevel gray relational analysis model and then the optimal scheme was determined. The feasibility and practicability of the evaluation method are verified by introducing examples.

Earth resources data analysis program, phase 2

NASA Technical Reports Server (NTRS)

1974-01-01

The efforts and findings of the Earth Resources Data Analysis Program are summarized. Results of a detailed study of the needs of EOD with respect to an applications development system (ADS) for the analysis of remotely sensed data, including an evaluation of four existing systems with respect to these needs are described. Recommendations as to possible courses for EOD to follow to obtain a viable ADS are presented. Algorithmic development comprised of several subtasks is discussed. These subtasks include the following: (1) two algorithms for multivariate density estimation; (2) a data smoothing algorithm; (3) a method for optimally estimating prior probabilities of unclassified data; and (4) further applications of the modified Cholesky decomposition in various calculations. Little effort was expended on task 3, however, two reports were reviewed.

Navigating the Return Trip from the Moon Using Earth-Based Ground Tracking and GPS

NASA Technical Reports Server (NTRS)

Berry, Kevin; Carpenter, Russell; Moreau, Michael C.; Lee, Taesul; Holt, Gregg N.

2009-01-01

NASA s Constellation Program is planning a human return to the Moon late in the next decade. From a navigation perspective, one of the most critical phases of a lunar mission is the series of burns performed to leave lunar orbit, insert onto a trans-Earth trajectory, and target a precise re-entry corridor in the Earth s atmosphere. A study was conducted to examine sensitivity of the navigation performance during this phase of the mission to the type and availability of tracking data from Earth-based ground stations, and the sensitivity to key error sources. This study also investigated whether GPS measurements could be used to augment Earth-based tracking data, and how far from the Earth GPS measurements would be useful. The ability to track and utilize weak GPS signals transmitted across the limb of the Earth is highly dependent on the configuration and sensitivity of the GPS receiver being used. For this study three GPS configurations were considered: a "standard" GPS receiver with zero dB antenna gain, a "weak signal" GPS receiver with zero dB antenna gain, and a "weak signal" GPS receiver with an Earth-pointing direction antenna (providing 10 dB additional gain). The analysis indicates that with proper selection and configuration of the GPS receiver on the Orion spacecraft, GPS can potentially improve navigation performance during the critical final phases of flight prior to Earth atmospheric entry interface, and may reduce reliance on two-way range tracking from Earth-based ground stations.

Venus Phasing.

ERIC Educational Resources Information Center

Riddle, Bob

1997-01-01

Presents a science activity designed to introduce students to the geocentric and heliocentric models of the universe. Helps students discover why phase changes on Venus knocked Earth out of the center of the universe. (DKM)

Chandler wobble: two more large phase jumps revealed

NASA Astrophysics Data System (ADS)

Malkin, Zinovy; Miller, Natalia

2010-12-01

Investigations of the anomalies in the Earth rotation, in particular, the polar motion components, play an important role in our understanding of the processes that drive changes in the Earth's surface, interior, atmosphere, and ocean. This paper is primarily aimed at investigation of the Chandler wobble (CW) at the whole available 163-year interval to search for the major CW amplitude and phase variations. First, the CW signal was extracted from the IERS (International Earth Rotation and Reference Systems Service) Pole coordinates time series using two digital filters: the singular spectrum analysis and Fourier transform. The CW amplitude and phase variations were examined by means of the wavelet transform and Hilbert transform. Results of our analysis have shown that, besides the well-known CW phase jump in the 1920s, two other large phase jumps have been found in the 1850s and 2000s. As in the 1920s, these phase jumps occurred contemporarily with a sharp decrease in the CW amplitude.

Extravehicular activity at geosynchronous earth orbit

NASA Technical Reports Server (NTRS)

Shields, Nicholas, Jr.; Schulze, Arthur E.; Carr, Gerald P.; Pogue, William

1988-01-01

The basic contract to define the system requirements to support the Advanced Extravehicular Activity (EVA) has three phases: EVA in geosynchronous Earth orbit; EVA in lunar base operations; and EVA in manned Mars surface exploration. The three key areas to be addressed in each phase are: environmental/biomedical requirements; crew and mission requirements; and hardware requirements. The structure of the technical tasks closely follows the structure of the Advanced EVA studies for the Space Station completed in 1986.

High energy, high average power solid state green or UV laser

DOEpatents

Hackel, Lloyd A.; Norton, Mary; Dane, C. Brent

2004-03-02

A system for producing a green or UV output beam for illuminating a large area with relatively high beam fluence. A Nd:glass laser produces a near-infrared output by means of an oscillator that generates a high quality but low power output and then multi-pass through and amplification in a zig-zag slab amplifier and wavefront correction in a phase conjugator at the midway point of the multi-pass amplification. The green or UV output is generated by means of conversion crystals that follow final propagation through the zig-zag slab amplifier.

Vesicles in Apollo 15 Green Glasses: The Nature of Ancient Lunar Gases

NASA Technical Reports Server (NTRS)

Thomas-Keprta, K. L.; Clemett, S. J.; Berger, E. L.; Rahman, Z.; McKay, D. S.; Gibson, E. K.; Wentworth, S. J.

2014-01-01

Detailed studies of Apollo 15 green glass and related beads have shown they were formed in gas-rich fire fountains.. As the magmatic fluid became super-saturated in volatile gas, bubbles or vesicles formed within the magma. These exsolved gases became trapped within vesicles as the glasses were ejected from the fire-fountain and subsequently quenched. One of the keys to understanding formation processes on the ancient moon includes determining the composition of volatile species and elements, including metals, dissolved in magmatic gases. Here we report the nature of mineral phases spatially associated with vesicles in a green glass bead from Apollo sample 15411,42. The phases reflect the composition of the cooling/degassing magmatic vapors and fluids present at the time of bead formation approx, 3 Ga ago

Support for equatorial anisotropy of Earth's inner-inner core from seismic interferometry at low latitudes

NASA Astrophysics Data System (ADS)

Wang, Tao; Song, Xiaodong

2018-03-01

Anisotropy of Earth's inner core provides a key role to understand its evolution and the Earth's magnetic field. Recently, using autocorrelations from earthquake's coda, we found an equatorial anisotropy of the inner-inner core (IIC), in apparent contrast to the polar anisotropy of the outer-inner core (OIC). To reduce the influence of the polar anisotropy and reduce possible contaminations from the large Fresnel zone of the PKIKP2 and PKIIKP2 phases at low frequencies, we processed coda noise of large earthquakes (10,000-40,000 s after magnitude ≥7.0) from stations at low latitudes (within ±35°) during 1990-2013. Using a number of improved procedures of both autocorrelation and cross-correlation, we extracted 52 array-stacked high-quality empirical Green's functions (EGFs), an increase of over 60% from our previous study. The high-quality data allow us to measure the relative arrival times by automatic waveform cross correlation. The results show large variation (∼10.9 s) in the differential times between the PKIKP2 and PKIIKP2 phases. The estimated influence of the Fresnel zone is insignificant (<1.1 s), compared to the observed data variation and measurement uncertainty. The observed time residuals match very well previous IIC model with a quasi-equatorial fast axis (near Central America and the Southeast Asia) and the spatial pattern from the low-latitude measurements is similar to the previous global dataset, including the fast axis and two low-velocity open rings, thus providing further support for the equatorial anisotropy model of the IIC. Speculations for the shift of the fast axis between the OIC and the IIC include: change of deformation regimes during the inner core history, change of geomagnetic field, and a proto-inner core.

Apollo 15 green glass - Compositional distribution and petrogenesis

NASA Technical Reports Server (NTRS)

Steele, Alison M.; Colson, Russell O.; Korotev, Randy L.; Haskin, Larry A.

1992-01-01

We have characterized a comprehensive suite of individual green-glass beads from Apollo 15 soil to determine interelement behavior and to constrain petrogenetic relationships. We analyzed 365 particles for trace elements by instrumental neutron activation analysis and analyzed 52 of them, selected to cover the compositional ranges observed for trace elements, for major elements by electron microprobe analysis. We confirm the observation of Delano (1979) that the beads comprise discrete compositional groups, although two of the groups he defined are further split on the basis of trace-element compositions. Each of the resulting seven groups has distinct average rare-earth abundances. The coherence between major- and trace-element data was masked in previous studies by imprecision, correlated error, and nonrepresentative sampling of the different groups. Most of the compositional characteristics of the green glasses can be explained by a model for batch equilibrium melting of a nearly homogeneous, ultramafic source region, when the complicating effects of high pressure and low oxygen fugacity are taken into account. The previously puzzling behavior of Ni and Co as apparently incompatible elements may arise from partial reduction of those elements to the zero oxidation state, resulting in low mineral/melt partition coefficients. The model also offers explanations for why the green glasses form boomerang-shaped trends on many two-element variation diagrams and why certain compositions (Groups A and D) are more abundant than glasses with other compositions.

Green Power Partnership 100 Green Power Users

EPA Pesticide Factsheets

EPA's Green Power Partnership is a voluntary program designed to reduce the environmental impact of electricity generation by promoting renewable energy. Partners on this list use green power to meet 100 of their U.S. organization-wide electricity use.

Titanium-bearing phases in the Earth's mantle (evidence from experiments in the MgO-SiO2-TiO2 ±Al2O3 system at 10-24 GPa)

NASA Astrophysics Data System (ADS)

Sirotkina, Ekaterina; Bobrov, Andrey; Bindi, Luca; Irifune, Tetsuo

2017-04-01

Introduction Despite significant interest of experimentalists to the study of geophysically important phase equilibria in the Earth's mantle and a huge experimental database on a number of the model and multicomponent systems, incorporation of minor elements in mantle phases was mostly studied on a qualitative level. The influence of such elements on structural peculiarities of high-pressure phases is poorly investigated, although incorporation of even small portions of them may have a certain impact on the PT-parameters of phase transformations. Titanium is one of such elements with the low bulk concentrations in the Earth's mantle (0.2 wt % TiO2) [1]; however, Ti-rich lithologies may occur in the mantle as a result of oceanic crust subduction. Thus, the titanium content is 0.6 wt% in Global Oceanic Subducted Sediments (GLOSS) [2], and 1.5 wt% TiO2, in MORB [3]. In this regard, accumulation of titanium in the Earth's mantle is related to crust-mantle interaction during the subduction of crustal material at different depths of the mantle. Experimental methods At 10-24 GPa and 1600°C, we studied the full range of the starting materials in the MgSiO3 (En) - MgTiO3 (Gkl) system in increments of 10-20 mol% Gkl and 1-3 GPa, which allowed us to plot the phase PX diagram for the system MgSiO3-MgTiO3 and synthesize titanium-bearing phases with a wide compositional range. The experiments were performed using a 2000-t Kawai-type multi-anvil high-pressure apparatus at the Geodynamics Research Center, Ehime University (Japan). The quenched samples were examined by single-crystal X-ray diffractometer, and the composition of phases was analyzed using SEM-EDS. Results The main phases obtained in experiments were rutile, wadsleyite, MgSiO3-enstatite, MgTiO3-ilmenite, MgTiSi2O7 with the weberite structure type (Web), Mg(Si,Ti)O3 and MgSiO3 with perovskite-type structure. At a pressure of 13 GPa for Ti-poor bulk compositions, an association of En+Wad+Rt is replaced by the

Earth-Space Link Attenuation Estimation via Ground Radar Kdp

NASA Technical Reports Server (NTRS)

Bolen, Steven M.; Benjamin, Andrew L.; Chandrasekar, V.

2003-01-01

A method of predicting attenuation on microwave Earth/spacecraft communication links, over wide areas and under various atmospheric conditions, has been developed. In the area around the ground station locations, a nearly horizontally aimed polarimetric S-band ground radar measures the specific differential phase (Kdp) along the Earth-space path. The specific attenuation along a path of interest is then computed by use of a theoretical model of the relationship between the measured S-band specific differential phase and the specific attenuation at the frequency to be used on the communication link. The model includes effects of rain, wet ice, and other forms of precipitation. The attenuation on the path of interest is then computed by integrating the specific attenuation over the length of the path. This method can be used to determine statistics of signal degradation on Earth/spacecraft communication links. It can also be used to obtain real-time estimates of attenuation along multiple Earth/spacecraft links that are parts of a communication network operating within the radar coverage area, thereby enabling better management of the network through appropriate dynamic routing along the best combination of links.

Efficient Green Emission from Wurtzite Al xIn1- xP Nanowires.

PubMed

Gagliano, L; Kruijsse, M; Schefold, J D D; Belabbes, A; Verheijen, M A; Meuret, S; Koelling, S; Polman, A; Bechstedt, F; Haverkort, J E M; Bakkers, E P A M

2018-06-13

Direct band gap III-V semiconductors, emitting efficiently in the amber-green region of the visible spectrum, are still missing, causing loss in efficiency in light emitting diodes operating in this region, a phenomenon known as the "green gap". Novel geometries and crystal symmetries however show strong promise in overcoming this limit. Here we develop a novel material system, consisting of wurtzite Al x In 1- x P nanowires, which is predicted to have a direct band gap in the green region. The nanowires are grown with selective area metalorganic vapor phase epitaxy and show wurtzite crystal purity from transmission electron microscopy. We show strong light emission at room temperature between the near-infrared 875 nm (1.42 eV) and the "pure green" 555 nm (2.23 eV). We investigate the band structure of wurtzite Al x In 1- x P using time-resolved and temperature-dependent photoluminescence measurements and compare the experimental results with density functional theory simulations, obtaining excellent agreement. Our work paves the way for high-efficiency green light emitting diodes based on wurtzite III-phosphide nanowires.

Validation of AN Hplc-Dad Method for the Classification of Green Teas

NASA Astrophysics Data System (ADS)

Yu, Jingbo; Ye, Nengsheng; Gu, Xuexin; Liu, Ni

A reversed phase high performance liquid chromatography (RP-HPLC) separation coupled with diode array detection (DAD) and electrospray ionization mass spectrometer (ESI/MS) was developed and optimized for the classification of green teas. Five catechins [epigallocatechin (EGC), epigallocatechin gallate (EGCG), epicatechin (EC), gallocatechin gallate (GCG), epicatechin gallate (ECG)] had been identified and quantified by the HPLC-DAD-ESI/MS/MS method. The limit of detection (LOD) of five catechins was within the range of 1.25-15 ng. All the analytes exhibited good linearity up to 2500 ng. These compounds were considered as chemical descriptors to define groups of green teas. Chemometric methods including principal component analysis (PCA) and hierarchical cluster analysis (HCA) were applied for the purpose. Twelve green tea samples originating from different regions were subjected to reveal the natural groups. The results showed that the analyzed green teas were differentiated mainly by provenance; HCA afforded an excellent performance in terms of recognition and prediction abilities. This method was accurate and reproducible, providing a potential approach for authentication of green teas.

EAARL Coastal Topography - Northern Gulf of Mexico, 2007: Bare Earth

USGS Publications Warehouse

Smith, Kathryn E.L.; Nayegandhi, Amar; Wright, C. Wayne; Bonisteel, Jamie M.; Brock, John C.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of Lidar-derived bare earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Gulf Coast Network, Lafayette, LA; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. The purpose of this project is to provide highly detailed and accurate datasets of select barrier islands and peninsular regions of Louisiana, Mississippi, Alabama, and Florida, acquired on June 27-30, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using

EAARL Coastal Topography-Assateague Island National Seashore, 2008: Bare Earth

USGS Publications Warehouse

Bonisteel, Jamie M.; Nayegandhi, Amar; Brock, John C.; Wright, C. Wayne; Stevens, Sara; Yates, Xan; Klipp, Emily S.

2009-01-01

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) topography were produced as a collaborative effort between the U.S. Geological Survey (USGS), Florida Integrated Science Center (FISC), St. Petersburg, FL; the National Park Service (NPS), Northeast Coastal and Barrier Network, Kingston, RI; and the National Aeronautics and Space Administration (NASA), Wallops Flight Facility, VA. This project provides highly detailed and accurate datasets of the Assateague Island National Seashore in Maryland and Virginia, acquired March 24-25, 2008. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL) was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multi-spectral color infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the

Geochemical Constraints on Core Formation in the Earth

NASA Technical Reports Server (NTRS)

Jones, John H.; Drake, Michael J.

1986-01-01

New experimental data on the partitioning of siderophile and chalcophile elements among metallic and silicate phases may be used to constrain hypotheses of core formation in the Earth. Three current hypotheses can explain gross features of mantle geochemistry, but none predicts siderophile and chalcophile element abundances to within a factor of two of observed values. Either our understanding of metal-silicate interactions and/or our understanding of the early Earth requires revision.

Green Chemistry Metrics with Special Reference to Green Analytical Chemistry.

PubMed

Tobiszewski, Marek; Marć, Mariusz; Gałuszka, Agnieszka; Namieśnik, Jacek

2015-06-12

The concept of green chemistry is widely recognized in chemical laboratories. To properly measure an environmental impact of chemical processes, dedicated assessment tools are required. This paper summarizes the current state of knowledge in the field of development of green chemistry and green analytical chemistry metrics. The diverse methods used for evaluation of the greenness of organic synthesis, such as eco-footprint, E-Factor, EATOS, and Eco-Scale are described. Both the well-established and recently developed green analytical chemistry metrics, including NEMI labeling and analytical Eco-scale, are presented. Additionally, this paper focuses on the possibility of the use of multivariate statistics in evaluation of environmental impact of analytical procedures. All the above metrics are compared and discussed in terms of their advantages and disadvantages. The current needs and future perspectives in green chemistry metrics are also discussed.

Plasma and magnetic field variations in the distant magnetotail associated with near-earth substorm effects

NASA Technical Reports Server (NTRS)

Baker, D. N.; Bame, S. J.; Mccomas, D. J.; Zwickl, R. D.; Slavin, J. A.; Smith, E. J.

1987-01-01

Examination of many individual event periods in the ISEE 3 deep-tail data set has suggested that magnetospheric substorms produce a characteristic pattern of effects in the distant magnetotail. During the growth, or tail-energy-storage phase of substorms, the magnetotail appears to grow diametrically in size, often by many earth radii. Subsequently, after the substorm expansive phase onset at earth, the distant tail undergoes a sequence of plasma, field, and energetic-particle variations as large-scale plasmoids move rapidly down the tail following their disconnection from the near-earth plasma sheet. ISEE 3 data are appropriate for the study of these effects since the spacecraft remained fixed within the nominal tail location for long periods. Using newly available auroral electrojet indices (AE and AL) and Geo particle data to time substorm onsets at earth, superposed epoch analyses of ISEE 3 and near-earth data prior to, and following, substorm expansive phase onsets have been performed. These analyses quantify and extend substantially the understanding of the deep-tail pattern of response to global substorm-induced dynamical effects.

A Case for an Atmosphere on Super-Earth 55 Cancri e

NASA Astrophysics Data System (ADS)

Angelo, Isabel; Hu, Renyu

2017-12-01

One of the primary questions when characterizing Earth-sized and super-Earth-sized exoplanets is whether they have a substantial atmosphere like Earth and Venus or a bare-rock surface like Mercury. Phase curves of the planets in thermal emission provide clues to this question, because a substantial atmosphere would transport heat more efficiently than a bare-rock surface. Analyzing phase-curve photometric data around secondary eclipses has previously been used to study energy transport in the atmospheres of hot Jupiters. Here we use phase curve, Spitzer time-series photometry to study the thermal emission properties of the super-Earth exoplanet 55 Cancri e. We utilize a semianalytical framework to fit a physical model to the infrared photometric data at 4.5 μm. The model uses parameters of planetary properties including Bond albedo, heat redistribution efficiency (I.e., ratio between radiative timescale and advective timescale of the atmosphere), and the atmospheric greenhouse factor. The phase curve of 55 Cancri e is dominated by thermal emission with an eastward-shifted hotspot. We determine the heat redistribution efficiency to be {1.47}-0.25+0.30, which implies that the advective timescale is on the same order as the radiative timescale. This requirement cannot be met by the bare-rock planet scenario because heat transport by currents of molten lava would be too slow. The phase curve thus favors the scenario with a substantial atmosphere. Our constraints on the heat redistribution efficiency translate to an atmospheric pressure of ˜1.4 bar. The Spitzer 4.5 μm band is thus a window into the deep atmosphere of the planet 55 Cancri e.

Decon Green (trademark)

DTIC Science & Technology

2004-11-17

Bacillus stearothermophilus spores, a species considered extremely resistant to peroxide sterilants . As seen for Decon GreenTM Classic, New Decon...Additional data is given for Bacillus anthracis and Bacillus stearothermophilus demonstrating that Decon GreenTM is also effective against bio...GreenTM retains excellent bio decon efficacy. TABLE 4. Decontamination of Bacillus stearothermophilus by New Decon GreenTM Challenge CFU Recovered

Shore phases of the Green River formation in northern Sweetwater County, Wyoming

USGS Publications Warehouse

Bradley, Wilmont H.

1926-01-01

and the climatic conditions under which the deposits accumulated. From the same evidence the writer has also endeavored to determine the kinds and relative abundance of both plant and animal life that existed in the Green River lake and on the adjacent land. Such evidence is fragmentary, as was to be expected, but it serves well as a basis for fur her study and interpretation.

Green nanoparticle production using micro reactor technology

NASA Astrophysics Data System (ADS)

Kück, A.; Steinfeldt, M.; Prenzel, K.; Swiderek, P.; Gleich, A. v.; Thöming, J.

2011-07-01

The importance and potential of nanoparticles in daily life as well as in various industrial processes is becoming more predominant. Specifically, silver nanoparticles are increasingly applied, e.g. in clothes and wipes, due to their antibacterial properties. For applications in liquid phase it is advantageous to produce the nanoparticles directly in suspension. This article describes a green production of silver nanoparticles using micro reactor technology considering principles of green chemistry. The aim is to reveal the potential and constraints of this approach and to show, how economic and environmental costs vary depending on process conditions. For this purpose our research compares the proposed process with water-based batch synthesis and demonstrates improvements in terms of product quality. Because of the lower energy consumption and lower demand of cleaning agents, micro reactor is the best ecological choice.

Modeling Earth's Disk-Integrated, Time-Dependent Spectrum: Applications to Directly Imaged Habitable Planets

NASA Astrophysics Data System (ADS)

Lustig-Yaeger, Jacob; Schwieterman, Edward; Meadows, Victoria; Fujii, Yuka; NAI Virtual Planetary Laboratory, ISSI 'The Exo-Cartography Inverse Problem'

2016-10-01

Earth is our only example of a habitable world and is a critical reference point for potentially habitable exoplanets. While disk-averaged views of Earth that mimic exoplanet data can be obtained by interplanetary spacecraft, these datasets are often restricted in wavelength range, and are limited to the Earth phases and viewing geometries that the spacecraft can feasibly access. We can overcome these observational limitations using a sophisticated UV-MIR spectral model of Earth that has been validated against spacecraft observations in wavelength-dependent brightness and phase (Robinson et al., 2011; 2014). This model can be used to understand the information content - and the optimal means for extraction of that information - for multi-wavelength, time-dependent, disk-averaged observations of the Earth. In this work, we explore key telescope parameters and observing strategies that offer the greatest insight into the wavelength-, phase-, and rotationally-dependent variability of Earth as if it were an exoplanet. Using a generalized coronagraph instrument simulator (Robinson et al., 2016), we synthesize multi-band, time-series observations of the Earth that are consistent with large space-based telescope mission concepts, such as the Large UV/Optical/IR (LUVOIR) Surveyor. We present fits to this dataset that leverage the rotationally-induced variability to infer the number of large-scale planetary surface types, as well as their respective longitudinal distributions and broadband albedo spectra. Finally, we discuss the feasibility of using such methods to identify and map terrestrial exoplanets surfaces with the next generation of space-based telescopes.

Fluorescence imaging of the nanoparticles modified with indocyanine green

NASA Astrophysics Data System (ADS)

Gareev, K. G.; Babikova, K. Y.; Postnov, V. N.; Naumisheva, E. B.; Korolev, D. V.

2017-11-01

The comparative research of silica, the magnetite and magnetite-silica nanoparticles modified with fluorescent dyes using gas-phase and liquid-phase methods was conducted. At the content of fluorescent dye comparable in size a particular spectrophotometric method, nanoparticles with fluorescein have up to 1000 times larger overall luminous efficiency. It is revealed that magnetic nanoparticles are characterized by a smaller light efficiency in comparison with silica particles, at the same time particles of a magnetite are most effective at modification with fluorescein, and magnetite-silica particles - at modification with indocyanine green.

The Near-Earth Object Camera

NASA Astrophysics Data System (ADS)

Mainzer, Amy K.; NEOCam Science Team

2017-10-01

The Near-Earth Object Camera (NEOCam) is a NASA mission in formulation designed to find, track, and provide basic physical characterization of asteroids and comets that make close approaches to Earth. Its goal is to reduce the risk of impacts from undetected near-Earth objects (NEOs) capable of causing global and regional disasters. NEOCam consists of a 50 cm telescope operating at two channels dominated by NEO thermal emission, 4.2-5.0um and 6-10um, in order to better constrain the objects' temperatures and diameters. Orbiting the Sun-Earth L1 Lagrange point, the mission would find hundreds of thousands of NEOs and would make significant progress toward the Congressional objective of discovering more than 90% of NEOs larger than 140 m during its five-year lifetime. The mission uses novel 2048x2048 HgCdTe detectors that extend the wavelength cutoff beyond 10um at an operating temperature of 40K (Dorn et al. 2016). Both the optical system and the detectors are cooled passively using radiators and thermal shields to enable long mission life and to avoid the complexity of cryocoolers or cryogens. NEOCam is currently in an extended Phase A.

Earth orbiting Sisyphus system study

NASA Technical Reports Server (NTRS)

Jurkevich, I.; Krause, K. W.; Neste, S. L.; Soberman, R. K.

1971-01-01

The feasibility of employing an optical meteoroid detecting system, known as Sisyphus, to measure the near-earth particulates from an earth orbiting vehicle, is considered. A Sisyphus system can discriminate between natural and man-made particles since the system measures orbital characteristics of particles. A Sisyphus system constructed for the Pioneer F/G missions to Jupiter is used as the baseline, and is described. The amount of observing time which can be obtained by a Sisyphus instrument launched into various orbits is determined. Observation time is lost when, (1) the Sun is in or near the field of view, (2) the lighted Earth is in or near the field of view, (3) the instrument is eclipsed by the Earth, and (4) the phase angle measured at the particle between the forward scattering direction and the instrument is less than a certain critical value. The selection of the launch system and the instrument platform with a dedicated, attitude controlled payload package is discussed. Examples of such systems are SATS and SOLRAD 10(C) vehicles, and other possibilities are AVCO Corp. S4 system, the OWL system, and the Delta Payload Experiment Package.

Educating the Public about Deep-Earth Science

NASA Astrophysics Data System (ADS)

Cronin, V. S.

2010-12-01

The nature of Earth’s interior is an active frontier of scientific research. Much of our current understanding of sub-crustal Earth is based on knowledge acquired in the last 2-3 decades, made possible by public funding and by dense seismic arrays, satellite remote sensing, increases in computer power that enable use of enhanced numerical techniques, improved theoretical and experimental knowledge of high PT mineral physics and chemistry, and a vigorous scientific community that has been trained to take advantage of these opportunities. An essential component of science is effective communication; therefore, providing for public education about science is a responsibility of the research community. Current public understanding of Earth’s interior is meager at best. In pre-college texts and in non-technical mass media, Earth's interior is typically visualized as an onion or baseball of concentric different-colored shells along whose upper surface "crustal" plates move like packages on conveyor belts of convecting mantle. Or the crust is thought to float on a molten mantle, as in the 19th century ideas of William Lowthian Green. Misconceptions about Earth that are brought to the undergraduate classroom must be confronted frankly and replaced by current understanding based on good science. Persistent ignorance has consequences. What do we want the public to know? First, the public should understand that knowledge of Earth's interior is important, not irrelevant. The public should know that deep-Earth processes result in Earth's dynamic magnetic field. Deep-Earth processes affect how radiation from the Sun reaches Earth, consequently affecting the atmosphere, the oceans, and the viability of life on Earth. The composition and differentiated structure of Earth's interior is a result of the early accretionary history of Earth and the Earth-Moon system. The public should also know that lithospheric tectonics, with all of its consequences (dynamic topography, volcanoes

Earth limb views with greenish bands of airglow during STS-99

NASA Image and Video Library

2000-04-06

STS099-355-024 (11-22 February 2000) -- Two separate atmospheric optical phenomena appear in this 35mm photograph captured from the Space Shuttle Endeavour. The thin greenish band above the horizon is airglow; radiation emitted by the atmosphere from a layer about 30-kilometers thick and about 100-kilometers' altitude. The predominant emission in airglow is the green 5577-Angstrom wavelength emission from atomic oxygen atoms, which is also the predominant emission from the aurora. A yellow-orange color is also seen in airglow, which is the emission of the 5800-Angstrom wavelength from sodium atoms. Airglow is always present in the atmosphere; it results from the recombination of molecules that have been broken apart by solar radiation during the day. But airglow is so faint that it can only be seen at night by looking "edge on" at the emission layer, such as the view that astronauts have in Earth orbit. The other phenomenon in the photo appears to be a faint, diffuse red aurora. Red aurora occur from about 200 kilometers to as high as 500 kilometers altitude only in the auroral zones at polar latitudes. They are caused by the emission of 6300- Angstrom wavelength light from oxygen atoms that have been raised to a higher energy level (excited) by collisions with energetic electrons pouring down from the Earth's magnetosphere. The light is emitted when the atoms return to their original unexcited state. With the red light so faint in this picture, scientists are led to believe that the flux density of incoming electrons was small. Also, since there is no green aurora below the red, that indicates that the energy of the incoming electrons was low - higher energy electrons would penetrate deeper into the atmosphere where the green aurora is energized.

The EPOS Architecture: Integrated Services for solid Earth Science

NASA Astrophysics Data System (ADS)

Cocco, Massimo; Consortium, Epos

2013-04-01

The European Plate Observing System (EPOS) represents a scientific vision and an IT approach in which innovative multidisciplinary research is made possible for a better understanding of the physical processes controlling earthquakes, volcanic eruptions, unrest episodes and tsunamis as well as those driving tectonics and Earth surface dynamics. EPOS has a long-term plan to facilitate integrated use of data, models and facilities from existing (but also new) distributed research infrastructures, for solid Earth science. One primary purpose of EPOS is to take full advantage of the new e-science opportunities coming available. The aim is to obtain an efficient and comprehensive multidisciplinary research platform for the Earth sciences in Europe. The EPOS preparatory phase (EPOS PP), funded by the European Commission within the Capacities program, started on November 1st 2010 and it has completed its first two years of activity. EPOS is presently mid-way through its preparatory phase and to date it has achieved all the objectives, milestones and deliverables planned in its roadmap towards construction. The EPOS mission is to integrate the existing research infrastructures (RIs) in solid Earth science warranting increased accessibility and usability of multidisciplinary data from monitoring networks, laboratory experiments and computational simulations. This is expected to enhance worldwide interoperability in the Earth Sciences and establish a leading, integrated European infrastructure offering services to researchers and other stakeholders. The Preparatory Phase aims at leveraging the project to the level of maturity required to implement the EPOS construction phase, with a defined legal structure, detailed technical planning and financial plan. We will present the EPOS architecture, which relies on the integration of the main outcomes from legal, governance and financial work following the strategic EPOS roadmap and according to the technical work done during the

Stability and Solid Solutions of Hydrous Alumino-Silicates in the Earth's Mantle

NASA Astrophysics Data System (ADS)

Panero, W. R.; Caracas, R.

2017-12-01

The degree to which the Earth's mantle stores and cycles water in excess of the storage capacity of nominally anhydrous minerals is dependent upon the stability of hydrous phases under mantle-relevant pressures, temperatures, and compositions. Two hydrous phases, phase D and phase H are stable to the pressures and temperatures of the Earth's lower mantle, suggesting that the Earth's lower mantle may participate in the cycling of water. Each phase has a wide solid solution series between MgSi2O6H2-Al2SiO6H2 and MgSiO4H2-2δAlOOH-SiO2, respectively, yet most work addresses end-member compositions for analysis of stability and elastic properties. We present the results of density functional theory calculations on the stability, structure, bonding, partitioning, and elasticity of hydrous phases D and H in the Al2O3-SiO2-MgO-H2O system, addressing the solid solution series through a statistical sampling of site occupancy and calculation of the partition function from the grand canonical ensemble. We find that the addition of Al to the endmember compositions stabilizes each phase to higher temperatures through additional configurational entropy. We further find that solid solutions tend not to undergo hydrogen-bond symmetrization as is found in the end member compositions as a result of non-symmetric bonding environments.

Smarter Earth Science Data System

NASA Technical Reports Server (NTRS)

Huang, Thomas

2013-01-01

The explosive growth in Earth observational data in the recent decade demands a better method of interoperability across heterogeneous systems. The Earth science data system community has mastered the art in storing large volume of observational data, but it is still unclear how this traditional method scale over time as we are entering the age of Big Data. Indexed search solutions such as Apache Solr (Smiley and Pugh, 2011) provides fast, scalable search via keyword or phases without any reasoning or inference. The modern search solutions such as Googles Knowledge Graph (Singhal, 2012) and Microsoft Bing, all utilize semantic reasoning to improve its accuracy in searches. The Earth science user community is demanding for an intelligent solution to help them finding the right data for their researches. The Ontological System for Context Artifacts and Resources (OSCAR) (Huang et al., 2012), was created in response to the DARPA Adaptive Vehicle Make (AVM) programs need for an intelligent context models management system to empower its terrain simulation subsystem. The core component of OSCAR is the Environmental Context Ontology (ECO) is built using the Semantic Web for Earth and Environmental Terminology (SWEET) (Raskin and Pan, 2005). This paper presents the current data archival methodology within a NASA Earth science data centers and discuss using semantic web to improve the way we capture and serve data to our users.

Magnetic solid-phase extraction for determination of the total malachite green, gentian violet and leucomalachite green, leucogentian violet in aquaculture water by high-performance liquid chromatography with fluorescence detection.

PubMed

Zhao, Jiao; Wei, Daqiao; Yang, Yaling

2016-06-01

In this study, magnetic multi-walled carbon nanotube nanoparticles were synthesized and used as the adsorbent for the sums of malachite green, gentian violet and leucomalachite green, leucogentian violet in aquaculture water samples followed by high performance liquid chromatography with fluorescence detection. This method was based on in situ reduction of chromic malachite green, gentian violet to colorless leucomalachite green, leucogentian violet with potassium borohydride, respectively. The obtained adsorbent combines the advantages of carbon nanotubes and Fe3 O4 nanoparticles in one material for separation and preconcentration of the reductive dyes in aqueous media. The structure and properties of the prepared nanoparticles were characterized by transmission and scanning electron microscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy. The main parameters affecting the adsorption recoveries were investigated and optimized, including reducing agent concentration, type and amount of sorbent, sample pH, and eluting conditions. Under the optimum conditions, the limits of detection in this method were 0.22 and 0.09 ng/mL for malachite green and gentian violet, respectively. Product recoveries ranged from 87.0 to 92.8% with relative standard deviations from 4.6 to 5.9%. The results indicate that the sorbent is a suitable material for the removal and concentration of triphenylmethane dyes from polluted environmental samples. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Green Ocean Over the Amazon: Implications for Cloud Electrification

NASA Technical Reports Server (NTRS)

Williams, E.; Blakeslee, R.; Boccippio, D.; Arnold, James E. (Technical Monitor)

2001-01-01

A convective regime with distinct maritime characteristics (weak updraft, low CCN, prevalent coalescence and rainout, weak mixed phase reflectivity, low glaciation temperature, and little if any lightning) is documented over the Amazon basin of the South American continent, and dubbed the "green ocean". Radar, lightning, thermodynamic and AVHRR satellite observations are examined to shed light on the roles of updraft and aerosol in providing departures from the green ocean regime toward continental behavior. Extreme case studies are identified in which the updraft control is dominant and in which the aerosol control is dominant. The tentative conclusion gives importance to both updrafts and aerosol in shaping the electrification of tropical convection.

Nitrite reduction by biogenic hydroxycarbonate green rusts: evidence for hydroxy-nitrite green rust formation as an intermediate reaction product.

PubMed

Guerbois, Delphine; Ona-Nguema, Georges; Morin, Guillaume; Abdelmoula, Mustapha; Laverman, Anniet M; Mouchel, Jean-Marie; Barthelemy, Kevin; Maillot, Fabien; Brest, Jessica

2014-04-15

The present study investigates for the first time the reduction of nitrite by biogenic hydroxycarbonate green rusts, bio-GR(CO3), produced from the bioreduction of ferric oxyhydroxycarbonate (Fohc), a poorly crystalline solid phase, and of lepidocrocite, a well-crystallized Fe(III)-oxyhydroxide mineral. Results show a fast Fe(II) production from Fohc, which leads to the precipitation of bio-GR(CO3) particles that were roughly 2-fold smaller (2.3 ± 0.4 μm) than those obtained from the bioreduction of lepidocrocite (5.0 ± 0.4 μm). The study reveals that both bio-GR(CO3) are capable of reducing nitrite ions into gaseous nitrogen species such as NO, N2O, or N2 without ammonium production at neutral initial pH and that nitrite reduction proceeded to a larger extent with smaller particles than with larger ones. On the basis of the identification of intermediates and end-reaction products using X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge, our study shows the formation of hydroxy-nitrite green rust, GR(NO2), a new type of green rust 1, and suggests that the reduction of nitrite by biogenic GR(CO3) involves both external and internal reaction sites and that such a mechanism could explain the higher reactivity of green rust with respect to nitrite, compared to other mineral substrates possessing only external reactive sites.

Averaged variational principle for autoresonant Bernstein-Greene-Kruskal modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khain, P.; Friedland, L.

2010-10-15

Whitham's averaged variational principle is applied in studying dynamics of formation of autoresonant (continuously phase-locked) Bernstein-Greene-Kruskal (BGK) modes in a plasma driven by a chirped frequency ponderomotive wave. A flat-top electron velocity distribution is used as a model allowing a variational formulation within the water bag theory. The corresponding Lagrangian, averaged over the fast phase variable yields evolution equations for the slow field variables, allows uniform description of all stages of excitation of driven-chirped BGK modes, and predicts modulational stability of these nonlinear phase-space structures. Numerical solutions of the system of slow variational equations are in good agreement with Vlasov-Poissonmore » simulations.« less

EarthCube: A Community-Driven Cyberinfrastructure for the Geosciences

NASA Astrophysics Data System (ADS)

Koskela, Rebecca; Ramamurthy, Mohan; Pearlman, Jay; Lehnert, Kerstin; Ahern, Tim; Fredericks, Janet; Goring, Simon; Peckham, Scott; Powers, Lindsay; Kamalabdi, Farzad; Rubin, Ken; Yarmey, Lynn

2017-04-01

EarthCube is creating a dynamic, System of Systems (SoS) infrastructure and data tools to collect, access, analyze, share, and visualize all forms of geoscience data and resources, using advanced collaboration, technological, and computational capabilities. EarthCube, as a joint effort between the U.S. National Science Foundation Directorate for Geosciences and the Division of Advanced Cyberinfrastructure, is a quickly growing community of scientists across all geoscience domains, as well as geoinformatics researchers and data scientists. EarthCube has attracted an evolving, dynamic virtual community of more than 2,500 contributors, including earth, ocean, polar, planetary, atmospheric, geospace, computer and social scientists, educators, and data and information professionals. During 2017, EarthCube will transition to the implementation phase. The implementation will balance "innovation" and "production" to advance cross-disciplinary science goals as well as the development of future data scientists. This presentation will describe the current architecture design for the EarthCube cyberinfrastructure and implementation plan.

Membrane assisted solvent extraction for rare earth element recovery

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhave, Ramesh R.; Kim, Daejin; Peterson, Eric S.

Systems and methods for the recovery of rare earth elements are provided. The systems and methods generally include membrane assisted solvent extraction using permeable hollow fibers having an immobilized organic phase within the pores of the hollow fibers. The permeable hollow fibers are generally in contact with an acidic aqueous feed on one side thereof and a strip solution on another side thereof. The systems and methods generally include the simultaneous extraction and stripping of rare earth elements as a continuous recovery process that is well suited for post-consumer products, end-of-life products, and other recovery sources of rare earth elements.

Rare earth element scavenging in seawater

NASA Astrophysics Data System (ADS)

Byrne, Robert H.; Kim, Ki-Hyun

1990-10-01

Examinations of rare earth element (REE) adsorption in seawater, using a variety of surface-types, indicated that, for most surfaces, light rare earth elements (LREEs) are preferentially adsorbed compared to the heavy rare earths (HREEs). Exceptions to this behavior were observed only for silica phases (glass surfaces, acid-cleaned diatomaceous earth, and synthetic SiO 2). The affinity of the rare earths for surfaces can be strongly affected by thin organic coatings. Glass surfaces which acquired an organic coating through immersion in Tampa Bay exhibited adsorptive behavior typical of organic-rich, rather than glass, surfaces. Models of rare earth distributions between seawater and carboxylate-rich surfaces indicate that scavenging processes which involve such surfaces should exhibit a strong dependence on pH and carbonate complexation. Scavenging models involving carboxylate surfaces produce relative REE abundance patterns in good general agreement with observed shale-normalized REE abundances in seawater. Scavenging by carboxylate-rich surfaces should produce HREE enrichments in seawater relative to the LREEs and may produce enrichments of lanthanum relative to its immediate trivalent neighbors. Due to the origin of distribution coefficients as a difference between REE solution complexation (which increases strongly with atomic number) and surface complexation (which apparently also increases with atomic number) the relative solution abundance patterns of the REEs produced by scavenging reactions can be quite complex.

The Earth System (ES-DOC) Project

NASA Astrophysics Data System (ADS)

Greenslade, Mark; Murphy, Sylvia; Treshansky, Allyn; DeLuca, Cecilia; Guilyardi, Eric; Denvil, Sebastien

2014-05-01

ESSI1.3 New Paradigms, Modelling, and International Collaboration Strategies for Earth System Sciences Earth System Documentation (ES-DOC) is an international project supplying tools & services in support of earth system documentation creation, analysis and dissemination. It is nurturing a sustainable standards based documentation eco-system that aims to become an integral part of the next generation of exa-scale dataset archives. ES-DOC leverages open source software and places end-user narratives at the heart of all it does. ES-DOC has initially focused upon nurturing the Earth System Model (ESM) documentation eco-system. Within this context ES-DOC leverages emerging documentation standards and supports the following projects: Coupled Model Inter-comparison Project Phase 5 (CMIP5); Dynamical Core Model Inter-comparison Project (DCMIP); National Climate Predictions and Projections Platforms Quantitative Evaluation of Downscaling Workshop. This presentation will introduce the project to a wider audience and demonstrate the range of tools and services currently available for use. It will also demonstrate how international collaborative efforts are essential to the success of ES-DOC.

Dishwasher For Earth Or Outer Space

NASA Technical Reports Server (NTRS)

Tromble, Jon D.

1991-01-01

Dishwashing machine cleans eating utensils in either Earth gravity or zero gravity of outer space. Cycle consists of three phases: filling, washing, and draining. Rotation of tub creates artificial gravity aiding recirculation of water during washing phase in absence of true gravity. Centrifugal air/water separator helps system function in zero gravity. Self-cleaning filter contains interdigitating blades catching solid debris when water flows between them. Later, blades moved back and forth in scissor-like manner to dislodge debris, removed by backflow of water.

Molecularly imprinted polymer for selective extraction of malachite green from seawater and seafood coupled with high-performance liquid chromatographic determination.

PubMed

Lian, Ziru; Wang, Jiangtao

2012-12-01

In this paper, a highly selective sample cleanup procedure combining molecular imprinting technique (MIT) and solid-phase extraction (SPE) was developed for the isolation of malachite green in seawater and seafood samples. The molecularly imprinted polymer (MIP) was prepared using malachite green as the template molecule, methacrylic acid as the functional monomer and ethylene glycol dimethacrylate as the cross-linking monomer. The imprinted polymer and non-imprinted polymer were characterized by scanning electron microscope and static adsorption experiments. The MIP showed a high adsorption capacity and was used as selective sorbent for the SPE of malachite green. An off-line molecularly imprinted solid-phase extraction (MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of malachite green in seawater and seafood samples was also established. Finally, five samples were determined. The results showed that malachite green concentration in one seawater sample was at 1.30 μg L⁻¹ and the RSD (n=3) was 4.15%. Crown Copyright © 2012. Published by Elsevier Ltd. All rights reserved.

Solar sail trajectory design in the Earth-Moon circular restricted three body problem

NASA Astrophysics Data System (ADS)

Das, Ashwati

The quest to explore the Moon has helped resolve scientific questions, has spurred leaps in technology development, and has revealed Earth's celestial companion to be a gateway to other destinations. With a renewed focus on returning to the Moon in this decade, alternatives to chemical propulsion systems are becoming attractive methods to efficiently use scarce resources and support extended mission durations. Thus, an investigation is conducted to develop a general framework, that facilitates propellant-free Earth-Moon transfers by exploiting sail dynamics in combination with advantageous transfer options offered in the Earth-Moon circular restricted multi-body dynamical model. Both periodic orbits in the vicinity of the Earth-Moon libration points, and lunar-centric long-term capture orbits are incorporated as target destinations to demonstrate the applicability of the general framework to varied design scanarios, each incorporating a variety of complexities and challenges. The transfers are comprised of three phases - a spiral Earth escape, a transit period, and, finally, the capture into a desirable orbit in the vicinity of the Moon. The Earth-escape phase consists of spiral trajectories constructed using three different sail steering strategies - locally optimal, on/off and velocity tangent. In the case of the Earth-libration point transfers, naturally occurring flow structures (e.g., invariant manifolds) arising from the mutual gravitational interaction of the Earth and Moon are exploited to link an Earth departure spiral with a destination orbit. In contrast, sail steering alone is employed to establish a link between the Earth-escape phase and capture orbits about the Moon due to a lack of applicable natural structures for the required connection. Metrics associated with the transfers including flight-time and the influence of operational constraints, such as occultation events, are investigated to determine the available capabilities for Earth

Check-Up of Planet Earth at the Turn of the Millennium Anticipated New Phase in Earth Sciences

NASA Technical Reports Server (NTRS)

Kaufman, Yoram

1999-01-01

Langley's remarkable solar and lunar spectra collected from mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. In 1999, NASA's Earth Observing AM Satellite named recently "Terra" (by Ms. Sasha Jones, a 17 year old student in St. Louis, MO) will repeat Langley's experiment, but for the entire planet, thus pioneering calibrated spectral observations from space. Conceived in response to real environmental problems, EOS-AM, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution of few kilometers on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-AM can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment. In this talk I shall a give a historical perspective for the need for this expensive mission, give examples of the science that we anticipate to achieve using Terra measurements and describe this exciting mission.

On the brittle nature of rare earth pnictides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shriya, S.; Sapkale, R.; Varshney, Dinesh, E-mail: vdinesh33@rediffmail.com, E-mail: sapkale.raju@rediffmail.com

The high-pressure structural phase transition and pressure as well temperature induced elastic properties in ReY; (Re = La, Sc, Pr; Y = N, P, As, Sb, Bi) pnictides have been performed using effective interionic interaction potential with emphasis on charge transfer interactions and covalent contribution. Estimated values of phase transition pressure and the volume discontinuity in pressure-volume phase diagram indicate the structural phase transition from NaCl to CsCl structure. From the investigations of elastic constants the pressure (temperature) dependent volume collapse/expansion, second order Cauchy discrepancy, anisotropy, hardness and brittle/ductile nature of rare earth pnictides are computed.

Lightweight Phase-Change Material For Solar Power

NASA Technical Reports Server (NTRS)

Stark, Philip

1993-01-01

Lightweight panels containing phase-change materials developed for use as heat-storage elements of compact, lightweight, advanced solar dynamic power system. During high insolation, heat stored in panels via latent heat of fusion of phase-change material; during low insolation, heat withdrawn from panels. Storage elements consist mainly of porous carbon-fiber structures imbued with germanium. Developed for use aboard space station in orbit around Earth, also adapted to lightweight, compact, portable solar-power systems for use on Earth.

Green Team Recognized with HHS Green Champion Award Honorable Mention | Poster

Cancer.gov

Courtesy of the NCI at Frederick Green Team The NCI at Frederick Green Team received a Department of Health and Human Services (HHS) Green Champion Award honorable mention in June for the team’s plant swap initiative, begun in October 2012.  “The Green Team has been doing a great job this past year, and it is wonderful that their efforts have been recognized by the HHS through

The first 800 million years of earth's history

NASA Technical Reports Server (NTRS)

Smith, J. V.

1981-01-01

It is pointed out that there is no direct geological information on the first 750 Ma of earth history. Consequently the reported study is based on controversial inferences drawn from the moon, other planets and meteorites, coupled with backward extrapolation from surviving terrestrial rocks, especially those of Archaean age. Aspects of accretion are considered, taking into account cosmochemical and cosmophysical evidence, a new earth model, and convection systems. Attention is given to phase-equilibrium constraints, estimates of heat production, the bombardment history of the moon and implications for the earth, and the nature of the early crust. From a combination of physical, chemical, and petrological arguments, it is concluded that the earth's surface underwent intense volcanism in the pre-Archaean era, and that the rock types were chemically similar to those found in the early Archaean era.

Baltic Earth - Earth System Science for the Baltic Sea Region

NASA Astrophysics Data System (ADS)

Meier, Markus; Rutgersson, Anna; Lehmann, Andreas; Reckermann, Marcus

2014-05-01

The Baltic Sea region, defined as its river catchment basin, spans different climate and population zones, from a temperate, highly populated, industrialized south with intensive agriculture to a boreal, rural north. It encompasses most of the Scandinavian Peninsula in the west; most of Finland and parts of Russia, Belarus, and the Baltic states in the east; and Poland and small parts of Germany and Denmark in the south. The region represents an old cultural landscape, and the Baltic Sea itself is among the most studied sea areas of the world. Baltic Earth is the new Earth system research network for the Baltic Sea region. It is the successor to BALTEX, which was terminated in June 2013 after 20 years and two successful phases. Baltic Earth stands for the vision to achieve an improved Earth system understanding of the Baltic Sea region. This means that the research disciplines of BALTEX continue to be relevant, i.e. atmospheric and climate sciences, hydrology, oceanography and biogeochemistry, but a more holistic view of the Earth system encompassing processes in the atmosphere, on land and in the sea as well as in the anthroposphere shall gain in importance in Baltic Earth. Specific grand research challenges have been formulated, representing interdisciplinary research questions to be tackled in the coming years. A major means will be scientific assessments of particular research topics by expert groups, similar to the BACC approach, which shall help to identify knowledge gaps and develop research strategies. Preliminary grand challenges and topics for which Working Groups have been installed include: • Salinity dynamics in the Baltic Sea • Land-Sea biogeochemical feedbacks in the Baltic Sea region • Natural hazards and extreme events in the Baltic Sea region • Understanding sea level dynamics in the Baltic Sea • Understanding regional variability of water and energy exchange • Utility of Regional Climate Models • Assessment of Scenario Simulations

Time Course Exo-Metabolomic Profiling in the Green Marine Macroalga Ulva (Chlorophyta) for Identification of Growth Phase-Dependent Biomarkers

PubMed Central

Alsufyani, Taghreed; Weiss, Anne; Wichard, Thomas

2017-01-01

The marine green macroalga Ulva (Chlorophyta) lives in a mutualistic symbiosis with bacteria that influence growth, development, and morphogenesis. We surveyed changes in Ulva’s chemosphere, which was defined as a space where organisms interact with each other via compounds, such as infochemicals, nutrients, morphogens, and defense compounds. Thereby, Ulva mutabilis cooperates with bacteria, in particular, Roseovarius sp. strain MS2 and Maribacter sp. strain MS6 (formerly identified as Roseobacter sp. strain MS2 and Cytophaga sp. strain MS6). Without this accompanying microbial flora, U. mutabilis forms only callus-like colonies. However, upon addition of the two bacteria species, in effect forming a tripartite community, morphogenesis can be completely restored. Under this strictly standardized condition, bioactive and eco-physiologically-relevant marine natural products can be discovered. Solid phase extracted waterborne metabolites were analyzed using a metabolomics platform, facilitating gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS) analysis, combined with the necessary acquisition of biological metadata. Multivariate statistics of the GC-MS and LC-MS data revealed strong differences between Ulva’s growth phases, as well as between the axenic Ulva cultures and the tripartite community. Waterborne biomarkers, including glycerol, were identified as potential indicators for algal carbon source and bacterial-algal interactions. Furthermore, it was demonstrated that U. mutabilis releases glycerol that can be utilized for growth by Roseovarius sp. MS2. PMID:28075408

Photoabsorption of green and red fluorescent protein chromophore anions in vacuo.

PubMed

Wan, Songbo; Liu, Shasha; Zhao, Guangjiu; Chen, Maodu; Han, Keli; Sun, Mengtao

2007-09-01

Photoabsorption properties of green and red fluorescent protein chromophore anions in vacuo were investigated theoretically, based on the experimental results in gas phase [Phys. Rev. Lett. 2001, 87, 228102; Phys. Rev. Lett. 2003, 90, 118103]. Their calculated transition energies in absorption with TD-DFT and ZINDO methods are directly compared to the experimental reports in gas phase, and the calculations with ZINDO method can correctly reproduce the absorption spectra. The orientation and strength of their transition dipole moments were revealed with transition density. We also showed the orientation and result of their intramolecular charge transfer with transition difference density. The calculated results show that with the increase of the extended conjugated system, the orientation of transition dipole moments and the orientation of charge transfer can be reversed. They are the linear responds with the external electric fields. These theoretical results reveal the insight understanding of the photoinduced dynamics of green and red fluorescent protein chromophore anions and cations in vacuo.

Direct estimation of tidally induced Earth rotation variations observed by VLBI

NASA Astrophysics Data System (ADS)

Englich, S.; Heinkelmann, R.; BOHM, J.; Schuh, H.

2009-09-01

The subject of our study is the investigation of periodical variations induced by solid Earth tides and ocean tides in Earth rotation parameters (ERP: polar motion, UT1)observed by VLBI. There are two strategies to determine the amplitudes and phases of Earth rotation variations from observations of space geodetic techniques. The common way is to derive time series of Earth rotation parameters first and to estimate amplitudes and phases in a second step. Results obtained by this means were shown in previous studies for zonal tidal variations (Englich et al.; 2008a) and variations caused by ocean tides (Englich et al.; 2008b). The alternative method is to estimate the tidal parameters directly within the VLBI data analysis procedure together with other parameters such as station coordinates, tropospheric delays, clocks etc. The purpose of this work was the application of this direct method to a combined VLBI data analysis using the software packages OCCAM (Version 6.1, Gauss-Markov-Model) and DOGSCS (Gerstl et al.; 2001). The theoretical basis and the preparatory steps for the implementation of this approach are presented here.

Earth Observations taken by the Expedition 39 Crew

NASA Image and Video Library

2014-04-02

ISS039-E-009160 (2 April 2014) --- This nighttime view featuring the aurora borealis, the moon and Moscow was photographed by an Expedition 39 crew member on the International Space Station. A thin green line of the aurora borealis crosses the top of this image. The moon appears as a white disc just above the aurora. Airglow appears as a blue-white cusp on Earth's limb. Russia's capital city Moscow makes a splash of yellow (lower left), with its easily recognized radial pattern of highways. Other cities are Nizhni Novgorod (lower center) 400 kilometers from Moscow, St. Petersburg (left) 625 kilometers from Moscow, and Finland?s capital city Helsinki.

Iron-carbonate interaction at Earth's core-mantle boundary

NASA Astrophysics Data System (ADS)

Dorfman, S. M.; Badro, J.; Nabiei, F.; Prakapenka, V.; Gillet, P.

2015-12-01

Carbon storage and flux in the deep Earth are moderated by oxygen fugacity and interactions with iron-bearing phases. The amount of carbon stored in Earth's mantle versus the core depends on carbon-iron chemistry at the core-mantle boundary. Oxidized carbonates subducted from Earth's surface to the lowermost mantle may encounter reduced Fe0 metal from disproportionation of Fe2+ in lower mantle silicates or mixing with the core. To understand the fate of carbonates in the lowermost mantle, we have performed experiments on sandwiches of single-crystal (Ca0.6Mg0.4)CO3 dolomite and Fe foil in the laser-heated diamond anvil cell at lower mantle conditions of 49-110 GPa and 1800-2500 K. Syntheses were conducted with in situ synchrotron X-ray diffraction to identify phase assemblages. After quench to ambient conditions, samples were sectioned with a focused Ga+ ion beam for composition analysis with transmission electron microscopy. At the centers of the heated spots, iron melted and reacted completely with the carbonate to form magnesiowüstite, iron carbide, diamond, magnesium-rich carbonate and calcium carbonate. In samples heated at 49 and 64 GPa, the two carbonates exhibit a eutectoid texture. In the sample heated at 110 GPa, the carbonates form rounded ~150-nm-diameter grains with a higher modal proportion of interspersed diamonds. The presence of reduced iron in the deep lower mantle and core-mantle boundary region will promote the formation of diamonds in carbonate-bearing subducted slabs. The complete reaction of metallic iron to oxides and carbides in the presence of mantle carbonate supports the formation of these phases at the Earth's core-mantle boundary and in ultra-low velocity zones.

Application of green IT for physics data processing at INCDTIM

NASA Astrophysics Data System (ADS)

Farcas, Felix; Trusca, Radu; Albert, Stefan; Szabo, Izabella; Popeneciu, Gabriel

2012-02-01

Green IT is the next generation technology used in all datacenter around the world. Its benefit is of economic and financial interest. The new technologies are energy efficient, reduce cost and avoid potential disruptions to the existing infrastructure. The most important problem appears at the cooling systems which are the most important in the functionality of a datacenter. Green IT used in Grid Network will benefit the environment and is the next phase in computer infrastructure that will fundamentally change the way we think about and use computing power. At the National Institute for Research and Development of Isotopic and Molecular Technologies Cluj-Napoca (INCDTIM) we have implemented such kind of technology and its support helped us in processing multiple data in different domains, which brought INCDTIM on the major Grid domain with the RO-14-ITIM Grid site. In this paper we present benefits that the new technology brought us and the result obtained in the last year after the implementation of the new green technology.

FLORIS: phase A status of the fluorescence imaging spectrometer of the Earth Explorer mission candidate FLEX

NASA Astrophysics Data System (ADS)

Kraft, S.; Bézy, J.-L.; Del Bello, U.; Berlich, R.; Drusch, M.; Franco, R.; Gabriele, A.; Harnisch, B.; Meynart, R.; Silvestrin, P.

2013-10-01

The Fluorescence Explorer (FLEX) mission is currently subject to feasibility (Phase A) study as one of the two candidates of ESA's 8th Earth Explorer opportunity mission. The FLuORescence Imaging Spectrometer (FLORIS) will be an imaging grating spectrometer onboard of a medium sized satellite flying in tandem with Sentinel-3 in a Sun synchronous orbit at a height of about 815 km. FLORIS will observe vegetation fluorescence and reflectance within a spectral range between 500 nm and 780 nm. It will thereby cover the photochemical reflection features between 500 nm and 600 nm, the Chlorophyll absorption band between 600 and 677 nm, and the red-edge in the region from 697 nm to 755 nm being located between the Oxygen A and B absorption bands. By this measurement approach, it is expected that the full spectrum and amount of the vegetation fluorescence radiance can be retrieved, and that atmospheric corrections can efficiently be applied. FLORIS will measure Earth reflected spectral radiance at a relatively high spectral resolution of ~0.3 nm around the Oxygen absorption bands. Other spectral band areas with less pronounced absorption features will be measured at medium spectral resolution between 0.5 and 2 nm. FLORIS will provide imagery at 300 m resolution on ground with a swath width of 150 km. This will allow achieving global revisit times of less than one month so as to monitor seasonal variations of the vegetation cycles. The mission life time is expected to be at least 4 years. The fluorescence retrieval will make use of information coming from OLCI and SLSTR, which are onboard of Sentinel-3, to monitor temperature, to detect thin clouds and to derive vegetation reflectance and information on the aerosol content also outside the FLORIS spectral range. In order to mitigate the technological and programmatic risk of this Explorer mission candidate, ESA has initiated two comprehensive bread-boarding activities, in which the most critical technologies and instrument

The Earth Observing System

NASA Technical Reports Server (NTRS)

Shaffer, Lisa Robock

1992-01-01

The restructuring of the NASA Earth Observing System (EOS), designed to provide comprehensive long term observations from space of changes occurring on the Earth from natural and human causes in order to have a sound scientific basis for policy decisions on protection of the future, is reported. In response to several factors, the original program approved in the fiscal year 1991 budget was restructured and somewhat reduced in scope. The resulting program uses three different sized launch vehicles to put six different spacecraft in orbit in the first phase, followed by two replacement launches for each of five of the six satellites to maintain a long term observing capability to meet the needs of global climate change research and other science objectives. The EOS system, including the space observatories, the data and information system, and the interdisciplinary global change research effort, are approved and proceeding. Elements of EOS are already in place, such as the research investigations and initial data system capabilities. The flights of precursor satellite and Shuttle missions, the ongoing data analysis, and the evolutionary enhancements to the integrated Earth science data management capabilities are all important building blocks to the full EOS program.

Impacts of Greening Materials and Seed Pretreatment on Vegetation Development at an initial stage

NASA Astrophysics Data System (ADS)

Obriejetan, Michael

2015-04-01

Slope protection using greening measures as an integral part of soil-bioengineering is characterized by an increasing demand in research and practice. However, successful greening is a very complex issue due to the vast variety in specific slope characteristics such as morphology, soil properties and environmental factors. Because of practical experience in the greening of slopes and the results of further investigations in small-scale tests, it can be stated that the use of appropriate planting techniques, the quality of the materials used and the proper implementation of potential needed auxiliary materials at difficult locations are seen as key success criteria for sustainable vegetation development. Within this framework small-scale testing series were conducted regarding the influence of specific soil-properties, the use of auxiliary greening materials (fertilizer, mycorrhiza fungi, Bonded fiber matrix (BFM)…), application of different seed-pretreatment methods and influences of specific environmental factors (inclination, seeding depth) on vegetational development in an early phase. The aim of the series is to quantitatively and thus economically optimize the use of different greening-components and seed mixtures for practical application, while ensuring optimal development of vegetation. To quantify the influence of the treatment systems, vegetation cover ratio, biomass production (aboveground and belowground) and the germination of plant seeds served as main criteria for assessing the development in an initial stage. Selected findings for instance show that the admixture of mycorrhiza fungi can increase the cover ratio up to 23 % compared to untreated plots. In addition, pretreatment of seeds showed distinct effects too by shortening germination phase and increasing the capability of producing a higher amount of healthy sprouts. From a bioengineering perspective the results will serve as potential decisive advantage for successful implementation of

Organic chemistry in a CO2 rich early Earth atmosphere

NASA Astrophysics Data System (ADS)

Fleury, Benjamin; Carrasco, Nathalie; Millan, Maëva; Vettier, Ludovic; Szopa, Cyril

2017-12-01

The emergence of life on the Earth has required a prior organic chemistry leading to the formation of prebiotic molecules. The origin and the evolution of the organic matter on the early Earth is not yet firmly understood. Several hypothesis, possibly complementary, are considered. They can be divided in two categories: endogenous and exogenous sources. In this work we investigate the contribution of a specific endogenous source: the organic chemistry occurring in the ionosphere of the early Earth where the significant VUV contribution of the young Sun involved an efficient formation of reactive species. We address the issue whether this chemistry can lead to the formation of complex organic compounds with CO2 as only source of carbon in an early atmosphere made of N2, CO2 and H2, by mimicking experimentally this type of chemistry using a low pressure plasma reactor. By analyzing the gaseous phase composition, we strictly identified the formation of H2O, NH3, N2O and C2N2. The formation of a solid organic phase is also observed, confirming the possibility to trigger organic chemistry in the upper atmosphere of the early Earth. The identification of Nitrogen-bearing chemical functions in the solid highlights the possibility for an efficient ionospheric chemistry to provide prebiotic material on the early Earth.

The role of the water footprint in the context of green marketing.

PubMed

Symeonidou, Stella; Vagiona, Dimitra

2018-04-03

The environmental degradation, because of various factors, such as climate change, human activities, increase of population globally, etc. have brought on pressures on the fresh water supplies that vary on time and space. Consequently, economic, environmental, and social tools have emerged known as footprints, in an effort to examine and measure the needs and consequences of humanity on the Earth's life support systems and take measures towards sustainable development. Furthermore, the constantly worsening environmental conditions have resulted in the cultivation of a green culture among society stakeholders that brought on terms such as green marketing and green products. This paper deals with the water footprint (WF) concept and an effort is performed, to explore through a literature review, in which ways it can contribute to the sustainable development of water use, in the context of green marketing (GM) strategies. The approach of the analysis is based on the discrimination to the following aspects: international scale, national and subnational scale, farmers, business, and consumers, in order to track the affection of each part in water issues. The main findings of the literature review showed that the aforementioned factors are playing a key role in protecting water recourses, by the way they formulate their water use and they are interrelated and interdependent. WFs can be useful in the context of GM, by providing helpful information about direct and indirect water consumption, to every contributor factor in supply chains, to consumers, governments, and water managers.

RP-HPLC×HILIC chromatography for quantifying ertapenem sodium with a look at green chemistry.

PubMed

Pedroso, Tahisa M; Medeiros, Ana C D; Salgado, Herida R N

2016-11-01

Ertapenem sodium is a polar and ionizable compound; therefore, it has little retention on traditional C18 columns in reverse-phase high-performance liquid chromatography, even using a highly-aqueous mobile phase that can result in dewetting in the stationary phase. Thus, the most coherent process for ERTM is to develop a method for Hydrophilic Interaction Chromatography. However, for the traditional methods in HILIC, the use of a highly organic mobile phase is necessary; usually an amount exceeding 80% acetonitrile is necessary. On the other hand, the RP-HPLC mode is considered for the analysis technique, which is more often used for quantification of substances, and new columns are often introduced to analyze different groups of compounds. Two new analytical methods have been developed for routine analysis. The proposed chromatographic method was adequate and advantageous by presenting simplicity, linearity, precision, accuracy, robustness, detection limits, and satisfactory quantification. Analytical methods are constantly undergoing changes and improvements. Researchers worldwide are rapidly adopting Green Chemistry. The development of new pharmaceutical methods based in Green chemistry has been encouraged by universities and the pharmaceutical industry. Issues related to green chemistry are in evidence and they have been featured in international journals of high impact. The methods described here have economic advantages and they feature an eco-friendly focus, which is discussed in this work. This work was developed with an environmental conscience, always looking to minimize the possible generated organic waste. Therefore, discussion on this aspect is included. Copyright © 2016 Elsevier B.V. All rights reserved.

Model for the formation of the earth's core

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCammon, C.A.; Ringwood, A.E.; Jackson, I.

1983-02-15

The recent discovery of a phase transformation in Fe/sub 0.94/O by Jeanloz and Ahrens has allowed a more detailed development of a model for core formation involving oxygen as the principal light alloying element in the core. It is predicted, based on calculations, that an increasing pressure in the system FeO-MgO will result in a gradual exsolution of an almost pure high-pressure phase FeO(hpp), leaving an iron-depleted (Fe,Mg)O rocksalt (B1) phase. We also predict that FeO(hhp) will form a low-melting point alloy with Fe at high temperature and high pressure. On the basis of our interpretations, we have constructed amore » model for core segregation. Assuming the earth to have accreted from the primordial solar nebula as a relatively homogeneous mixture of metallic iron and silicate-oxide phases, core segregation involving oxygen would commence at a depth where pressure is sufficiently high to cause exsolution of FeO(hpp) from the rocksalt phase, and temperature is sufficiently high to allow formation of an Fe-FeO(hpp) melt. A gravitational instability arises, leading to vertical differentiation of the earth as molten blobs of the metal sink downwards to form the core and the residual depleted silicate material coalesces to form large bodies which rise diapirically upwards to form the mantle.« less

An Energy Saving Green Plug Device for Nonlinear Loads

NASA Astrophysics Data System (ADS)

Bloul, Albe; Sharaf, Adel; El-Hawary, Mohamed

2018-03-01

The paper presents a low cost a FACTS Based flexible fuzzy logic based modulated/switched tuned arm filter and Green Plug compensation (SFC-GP) scheme for single-phase nonlinear loads ensuring both voltage stabilization and efficient energy utilization. The new Green Plug-Switched filter compensator SFC modulated LC-Filter PWM Switched Capacitive Compensation Devices is controlled using a fuzzy logic regulator to enhance power quality, improve power factor at the source and reduce switching transients and inrush current conditions as well harmonic contents in source current. The FACTS based SFC-GP Device is a member of family of Green Plug/Filters/Compensation Schemes used for efficient energy utilization, power quality enhancement and voltage/inrush current/soft starting control using a dynamic error driven fuzzy logic controller (FLC). The device with fuzzy logic controller is validated using the Matlab / Simulink Software Environment for enhanced power quality (PQ), improved power factor and reduced inrush currents. This is achieved using modulated PWM Switching of the Filter-Capacitive compensation scheme to cope with dynamic type nonlinear and inrush cyclical loads..

A new carbon-rich phase (COPS) in Antarctic micrometeorites

NASA Technical Reports Server (NTRS)

Engrand, C.; Maurette, M.; Kurat, G.; Brandstatter, F.; Perreau, M.

1993-01-01

The contemporary flux of micrometeorites with sizes greater than 50 microns reaching the Earth's surface each year (about 20,000 tons/a) is much greater than the value of approximately 100 tons/a reported for conventional meteorites up to masses of approximately 10,000 tons. Moreover, on the average, Antarctic micrometeorites contain at least as much carbon as does Orgueil, the most C-rich meteorite. Micrometeorites are thus responsible for most of the carbon accreted by the Earth. In this paper we report SEM observations of a new C-rich 'dirty magnetite' phase observed as tiny inclusions in both melted and unmelted micrometeorites. This phase, which is enriched in C, O, P, S, Fe, frequently shows Ni contents in excess of 0.2 percent, strongly suggestive of an 'extraterrestrial' origin. We also discovered this 'COPS' phase in the fusion crust of Murchison. It appears likely that COPS is a product of meteoroid reprocessing during frictional heating in the Earth's atmosphere and/or its fast 'weathering' in the upper atmosphere. Upon 'catalyzed' hydrolysis this phase might have facilitated the functioning of micrometeorites as 'micro-chondritic-reactors' for the synthesis of prebiotic molecules on the early Earth.

A cautionary approach in transitioning to 'green' energy technologies and practices is required.

PubMed

Matatiele, Puleng; Gulumian, Mary

2016-06-01

Renewable energy technologies (wind turbines, solar cells, biofuels, etc.) are often referred to as 'clean' or 'green' energy sources, while jobs linked to the field of environmental protection and energy efficiency are referred to as 'green' jobs. The energy efficiency of clean technologies, which is likely to reduce and/or eliminate reliance on fossil fuels, is acknowledged. However, the potential contribution of green technologies and associated practices to ill health and environmental pollution resulting from consumption of energy and raw materials, generation of waste, and the negative impacts related to some life cycle phases of these technologies are discussed. Similarly, a point is made that the green jobs theme is mistakenly oversold because the employment opportunities generated by transitioning to green technologies are not necessarily safe and healthy jobs. Emphasis is put on identifying the hazards associated with these green designs, assessing the risks to the environment and worker health and safety, and either eliminating the hazards or minimizing the risks as essential elements to the design, construction, operation, and maintenance of green technologies. The perception that it is not always economically possible to consider all risk factors associated with renewable energy technologies at the beginning without hampering their implementation, especially in the poor developing countries, is dismissed. Instead, poor countries are encouraged to start implementing environmentally sound practices while transitioning to green technologies in line with their technological development and overall economic growth.

Role of (-)-epigallocatechin gallate in the pharmacokinetic interaction between nadolol and green tea in healthy volunteers.

PubMed

Abe, Osamu; Ono, Tomoyuki; Sato, Hideyuki; Müller, Fabian; Ogata, Hiroshi; Miura, Itaru; Shikama, Yayoi; Yabe, Hirooki; Onoue, Satomi; Fromm, Martin F; Kimura, Junko; Misaka, Shingen

2018-06-01

The aim of the present study is to investigate a possible role of a single dose of (-)-epigallocatechin gallate (EGCG), the major catechin in green tea, for the pharmacokinetic interaction between green tea and nadolol in humans. In a randomized three-phase crossover study, 13 healthy volunteers received single doses of 30 mg nadolol orally with water (control), or an aqueous solution of EGCG-concentrated green tea extract (GTE) at low or high dose. Plasma concentrations and urinary excretion of nadolol were determined up to 48 h. In addition, blood pressure and pulse rate were monitored. In vitro transport kinetic experiments were performed using human embryonic kidney 293 cells stably expressing organic anion transporting polypeptide (OATP)1A2 to evaluate the inhibitory effect of EGCG on OATP1A2-mediated substrate transport. Single coadministration of low and high dose GTE significantly reduced the plasma concentrations of nadolol. The geometric mean ratios with 90% CI for area under the plasma concentration-time curves from 0 to infinity of nadolol were 0.72 (0.56-0.87) for the low and 0.60 (0.51-0.69) for the high dose. There were no significant differences in T max , elimination half-life, and renal clearance between GTE and water phases. No significant changes were observed for blood pressure and pulse rate between phases. EGCG competitively inhibited OATP1A2-mediated uptake of sulphobromophthalein and nadolol with K i values of 21.6 and 19.4 μM, respectively. EGCG is suggested to be a key contributor to the interaction of green tea with nadolol. Moreover, even a single coadministration of green tea may significantly affect nadolol pharmacokinetics.

The Distribution of Heat-Producing Radioactive Elements in the Deep Earth

NASA Astrophysics Data System (ADS)

Chidester, Bethany A.

The Earth is a heat engine, where large differences in temperature between the interior and the surface drive large-scale movement that manifests as plate tectonics and the geomagnetic field that protects us from the Sun's harmful charged particles. Decay of the long-lived radioactive elements U, Th, and K is expected to contribute as much as 45% of the current heat production in the Earth, and that heat production was five times higher early in Earth's history. It is unclear how this heat source affects the thermal and dynamic evolution of the Earth's core and mantle and how that contribution has changed over geologic time. This dissertation addresses this problem in several different ways. This work represents the first high-pressure, high-temperature metal-silicate partitioning experiments for U, Th, and K in the laser-heated diamond anvil cell at conditions relevant to core formation. A chemical model is developed using parameterization of these partitioning data to constrain the concentrations of each of these elements in the core. Using a numerical calculation, it is then determined how that radioactive heat would contribute to the core's energy and entropy budget through time. One finds that, despite its strong lithophile nature at the surface, U partitions significantly into the metallic phase at increasing temperatures. This may be due to a decrease in U valence from 4+ to 2+ in high-pressure silicate melts, which our data supports. However, K and Th do not exhibit a similar change in behavior at these conditions, and this may drive fractionation between U and Th in the deep mantle. At the most extreme conditions of core formation, enough U could exist in the core to produce up to 4.4 TW of heat 4.5 billion years ago. Potassium could produce much less heat than U early on (< 1 TW), and due to its short half-life, would have decayed away much faster. While this energy source is significantly greater than was previously thought to be possible, it is likely

Tropical Carbon Response to Seasonal Phasing and Intensity of Precipitation in CMIP5 Earth System Models

NASA Astrophysics Data System (ADS)

Basile, S.; Keppel-Aleks, G.

2016-12-01

Carbon cycling and water fluxes are connected over land. Understanding the current sensitivity of tropical ecosystems to climate drivers, such as precipitation, at short timescales is important for projecting future trends in the land sink of anthropogenic CO2. Several recent studies have shown that interannual droughts in 2005 and 2010 reduced net carbon uptake in the Amazon rainforest. In 2011 Southern Hemisphere semi-arid regions, especially Australian ecosystems, were found to largely contribute to the above average increase in the land carbon sink following consecutive wet seasons under La Nina conditions. Earth system models (ESMs) are able to simulate these sensitivities with varying degrees of fidelity, and ESMs also show a wide range of changes in precipitation phasing and intensity by 2100. Unsurprisingly, model projections of the land carbon sink also vary widely, with some simulations showing land becoming a CO2 source to the atmosphere. To constrain projections of the tropical land carbon balance among an ensemble of ESMs, we analyzed seasonal and interannual precipitation-carbon relationships in Coupled Model Intercomparison Project Phase 5 (CMIP5) ESMs for the period from 1982-2006. The sensitivity of net biospheric production on land (NBP) to precipitation was quantified on seasonal and annual timescales, and NBP was spatially correlated to precipitation across tropical and subtropical regions (+/- 30 degrees) within humid and semi-arid ecosystems. This analysis was expanded to soil moisture and drought metrics were used to distinguish between wet and dry seasons. Large scale precipitation was used to resolve Intertropical Convergence Zone (ITCZ) movement and convective precipitation was used to diagnose the short-term NBP response within the wet season. Results revealed a spread in NBP sensitivity to precipitation intensity as well as how individual models simulated precipitation phasing across different tropical regions.

Equilibrium distribution of rare earth elements between molten KCl-LiCl eutectic salt and liquid cadmium

NASA Astrophysics Data System (ADS)

Sakata, Masahiro; Kurata, Masaki; Hijikata, Takatoshi; Inoue, Tadashi

1991-11-01

Distribution experiments for several rare earth elements (La, Ce, Pr, Nd and Y) between molten KCl-LiCl eutectic salt and liquid Cd were carried out at 450, 500 and 600°C. The material balance of rare earth elements after reaching the equilibrium and their distribution and chemical states in a Cd sample frozen after the experiment were examined. The results suggested the formation of solid intermetallic compounds at the lower concentrations of rare earth metals dissolved in liquid Cd than those solubilities measured in the binary alloy system. The distribution coefficients of rare earth elements between two phases (mole fraction in the Cd phase divided by mole fraction in the salt phase) were determined at each temperature. These distribution coefficients were explained satisfactorily by using the activity coefficients of chlorides and metals in salt and Cd. Both the activity coefficients of metal and chloride caused a much smaller distribution coefficient of Y relative to those of other elements.

Phase characteristics of rare earth elements in metallic fuel for a sodium-cooled fast reactor by injection casting

NASA Astrophysics Data System (ADS)

Kuk, Seoung Woo; Kim, Ki Hwan; Kim, Jong Hwan; Song, Hoon; Oh, Seok Jin; Park, Jeong-Yong; Lee, Chan Bock; Youn, Young-Sang; Kim, Jong-Yun

2017-04-01

Uranium-zirconium-rare earth (U-Zr-RE) fuel slugs for a sodium-cooled fast reactor were manufactured using a modified injection casting method, and investigated with respect to their uniformity, distribution, composition, and phase behavior according to RE content. Nd, Ce, Pr, and La were chosen as four representative lanthanide elements because they are considered to be major RE components of fuel ingots after pyroprocessing. Immiscible layers were found on the top layers of the melt-residue commensurate with higher fuel slug RE content. Scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS) data showed that RE elements in the melt-residue were distributed uniformly throughout the fuel slugs. RE element agglomeration did not contaminate the fuel slugs but strongly affected the RE content of the slugs.

Green Roofs: A Part of Green Infrastructure Strategy for Urban Areas

EPA Science Inventory

This is a presentation on the basics of green roof technology. The presentation highlights some of the recent ORD research projects on green roofs and provides insight for the end user as to the benefits for green roof technology. It provides links to currently available EPA rep...

Green Builder Coalition |

Science.gov Websites

- Learn More Here - Join the Green Builder® Coalition today! - The Coalition supports the SAVE Act Assistance Advocacy Member Benefits Join Contact © 2016 Green Builder Coalition - Newsletter Signup - info @greenbuildercoalition.org - This site is green - Website by Triple Smart Follow Us

Steam cooking significantly improves in vitro bile acid binding of collard greens, kale, mustard greens, broccoli, green bell pepper, and cabbage.

PubMed

Kahlon, Talwinder Singh; Chiu, Mei-Chen M; Chapman, Mary H

2008-06-01

Bile acid binding capacity has been related to the cholesterol-lowering potential of foods and food fractions. Lowered recirculation of bile acids results in utilization of cholesterol to synthesize bile acid and reduced fat absorption. Secondary bile acids have been associated with increased risk of cancer. Bile acid binding potential has been related to lowering the risk of heart disease and that of cancer. Previously, we have reported bile acid binding by several uncooked vegetables. However, most vegetables are consumed after cooking. How cooking would influence in vitro bile acid binding of various vegetables was investigated using a mixture of bile acids secreted in human bile under physiological conditions. Eight replicate incubations were conducted for each treatment simulating gastric and intestinal digestion, which included a substrate only, a bile acid mixture only, and 6 with substrate and bile acid mixture. Cholestyramine (a cholesterol-lowering, bile acid binding drug) was the positive control treatment and cellulose was the negative control. Relative to cholestyramine, in vitro bile acid binding on dry matter basis was for the collard greens, kale, and mustard greens, 13%; broccoli, 10%; Brussels sprouts and spinach, 8%; green bell pepper, 7%; and cabbage, 5%. These results point to the significantly different (P < or = .05) health-promoting potential of collard greens = kale = mustard greens > broccoli > Brussels sprouts = spinach = green bell pepper > cabbage as indicated by their bile acid binding on dry matter basis. Steam cooking significantly improved the in vitro bile acid binding of collard greens, kale, mustard greens, broccoli, green bell pepper, and cabbage compared with previously observed bile acid binding values for these vegetables raw (uncooked). Inclusion of steam-cooked collard greens, kale, mustard greens, broccoli, green bell pepper, and cabbage in our daily diet as health-promoting vegetables should be emphasized. These green

Photoluminescence and afterglow luminescence properties of a green-emitting Na2BeGeO4:Mn2+ phosphor

NASA Astrophysics Data System (ADS)

Lu, Jie; Shen, Linjiang

2018-07-01

Recently, developing free rare-earth (RE) doped afterglow phosphors has received great attentions in the lighting field. In this work, we prepare and report a RE-free phosphor, Na2BeGeO4:Mn2+, which can simultaneously emit the green fluorescence and afterglow luminescence upon excitation at UV light. Our results reveal that the as-prepared samples crystallize in orthorhombic type with the space group of Pmn21 (31). The green emission is a broad band centered at 525 nm, corresponds to the 4T1(4G)-6A1(6S) transition of Mn2+ ions. After exposing to a 254 nm UV lamp for 10 min, the green afterglow luminescence seen with naked eyes can last more than 5 h. Together with the structural analysis and thermoluminescence (TL) spectra, the afterglow luminescence mechanism is also discussed in this work.

Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

DOE PAGES

Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; ...

2016-01-01

When appropriately activated, alkali rare-earth double phosphates of the form: M 3RE(PO 4) 2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K 3RE(PO 4) 2 with RE = Lu, Er, Ho,more » Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A 3Lu(PO 4) 2, with A = Rb, and Cs. The double phosphate K 3Lu(PO 4) 2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K 3Lu(PO 4) 2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K 3Lu(PO 4) 2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K 3Yb(PO 4) 2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated

Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.

When appropriately activated, alkali rare-earth double phosphates of the form: M 3RE(PO 4) 2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K 3RE(PO 4) 2 with RE = Lu, Er, Ho,more » Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A 3Lu(PO 4) 2, with A = Rb, and Cs. The double phosphate K 3Lu(PO 4) 2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K 3Lu(PO 4) 2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K 3Lu(PO 4) 2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K 3Yb(PO 4) 2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated

Contributions to the Earth's Obliquity Rate, Precession, and Nutation

NASA Technical Reports Server (NTRS)

Williams, James G.

1994-01-01

The precession and nutation of the Earth's equator arise from solar, lunar, and planetary torques on the oblate Earth. The mean lunar orbit plane is nearly coincident with the ecliptic plane. A small tilt out of the ecliptic is caused by planetary perturbations and the Earth's gravitational harmonic J(sub 2). These planetary perturbations on the lunar orbit result in torques on the oblate Earth which contribute to precession, obliquity rate, and nutation while the J(sub 2) perturbations contribute to precession and nutation. Small additional contributions to the secular rates arise from tidal effects and planetary torques on the Earth's bulge. The total correction to the obliquity rate is -0.024 sec/century, it is an observable motion in space (the much larger conventional obliquity rate is wholly from the motion of the ecliptic, not the equator), and it is not present in the IAU-adopted expressions for the orientation of the Earth's equator. The effects have generally been allowed for in past nutation theories and some precession theories. For the planetary effect, the contributions to the 18.6 yr nutation are -0.03 mas (milliarcseconds) for the in-phase Delta(psi) plus out-of-phase contributions of 0.14 mas in Delta(psi) and -0.03 mas in Delta(sub epsilon). The latter terms demonstrate that out-of-phase contributions can arise by means other than dissipation. The sum of the contributions to the precession rate is considered and the inferred value of the moment of inertia combination (C-A)/C, which is used to scale the coefficients in the nutation series, is evaluated. Using an updated value for the precession rate, the rigid body (C-A)/C =0.003 273 763 4 which, in combination with a satellite-derived J(sub 2), gives a normalized polar moment of inertia C/MR(exp 2) = 0.330 700 7. The planetary contributions to the precession and obliquity rates are not constant for long times causing accelerations in both quantities. Acceleration in precession also arises from

Pharmacokinetic study of indocyanine Green after intravenous administration by UPLC-MS/MS.

PubMed

Chen, Yu; Chen, Dongxin; Hu, Wenhao; Lin, Guanyang; Huang, Shiyong

2015-01-01

Indocyanine Green is widely used in medical diagnosis and to evaluate liver function and other regional blood flows in clinical application or animal experiments. In this work, a sensitive and selective ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method for determination of Indocyanine Green in rat plasma was developed and validated. After addition of rutin as an internal standard (IS), protein precipitation by acetonitrile-methanol (9:1, v/v) was used to prepare samples. Chromatographic separation was achieved on a UPLC BEH C18 column (2.1 mm × 100 mm, 1.7 μm) with 0.1% formic acid and acetonitrile as the mobile phase with gradient elution. An electrospray ionization source was applied and operated in positive ion mode; multiple reactions monitoring (MRM) mode was used for quantification using target fragment ions m/z 753.4→330.2 for Indocyanine Green, and m/z 611.1→303.1 for IS. Calibration plots were linear throughout the range 20-5000 ng/mL for Indocyanine Green in rat plasma. Mean recoveries of Indocyanine Green in rat plasma ranged from 79.5% to 85.4%. RSD of intra-day and inter-day precision were both < 12%. The accuracy of the method was between 95.9% and 113.9%. The method was successfully applied to pharmacokinetic study of Indocyanine Green after intravenous administration.

Pharmacokinetic study of indocyanine Green after intravenous administration by UPLC-MS/MS

PubMed Central

Chen, Yu; Chen, Dongxin; Hu, Wenhao; Lin, Guanyang; Huang, Shiyong

2015-01-01

Indocyanine Green is widely used in medical diagnosis and to evaluate liver function and other regional blood flows in clinical application or animal experiments. In this work, a sensitive and selective ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method for determination of Indocyanine Green in rat plasma was developed and validated. After addition of rutin as an internal standard (IS), protein precipitation by acetonitrile-methanol (9:1, v/v) was used to prepare samples. Chromatographic separation was achieved on a UPLC BEH C18 column (2.1 mm × 100 mm, 1.7 μm) with 0.1% formic acid and acetonitrile as the mobile phase with gradient elution. An electrospray ionization source was applied and operated in positive ion mode; multiple reactions monitoring (MRM) mode was used for quantification using target fragment ions m/z 753.4→330.2 for Indocyanine Green, and m/z 611.1→303.1 for IS. Calibration plots were linear throughout the range 20-5000 ng/mL for Indocyanine Green in rat plasma. Mean recoveries of Indocyanine Green in rat plasma ranged from 79.5% to 85.4%. RSD of intra-day and inter-day precision were both < 12%. The accuracy of the method was between 95.9% and 113.9%. The method was successfully applied to pharmacokinetic study of Indocyanine Green after intravenous administration. PMID:26629038

Tidal-friction theory of the earth-moon system

NASA Technical Reports Server (NTRS)

Lyttleton, R. A.

1980-01-01

Serious errors contained in Jeffreys' (1952, 1959, 1970, 1976) discussion of tidal friction in the earth-moon system are identified and their consequences are discussed. A direct solution of the dynamical tidal equations for the couple from the earth acting upon the moon and the couple from the earth acting upon the sun, which were left unsolved by Jeffreys, is found to be incompatible with observations and the predictions of linear or quadratic friction theory, due to his failure to take into account the possible change of the moment of inertia of the earth with time in the derivation of the dynamical equations. Consideration of this factor leads to the conclusion that the earth must be contracting at a rate of 14.7 x 10 to the -11th/year, which can be accounted for only by the Ramsey theory, in which the terrestrial core is considered as a phase change rather than a change in chemical composition. Implications of this value for the rates of changes in day length and lunar distance are also indicated.

Green(ing) English: Voices Howling in the Wilderness?

ERIC Educational Resources Information Center

Bruce, Heather E.

2011-01-01

The relatively new fields of ecocriticism in literary studies and ecocomposition in rhetoric and composition studies provide a usable foundation for those interested in green(ing) English. Nevertheless, even suggesting that interest in the environment within English studies is a relatively new concern is somewhat misleading. Contemplation of…

Greening Steel Work: Varieties of Capitalism and the "Greening" of Skills

ERIC Educational Resources Information Center

Evans, Claire; Stroud, Dean

2016-01-01

An important driver of change in work, employment and skills is European Union policy aims of sustainable economic growth and the cultivation of a green economy. Part of the latter--which is supported by increasing environmental regulation--focuses on the development of a "green skills agenda," which involves the "greening" of…

In the Green

ERIC Educational Resources Information Center

Kennedy, Mike

2011-01-01

Education officials used to debate whether they could afford to pursue green design and construction. Now the green movement has gained a foothold not just in education, but in society at large, and the prevailing attitude seems to have shifted. Can schools afford "not" to go green? As budgets are slashed repeatedly, education administrators must…

Can We Make Green Bonds An Effective Tool For Urban Carbon Management?

NASA Astrophysics Data System (ADS)

Yamagata, Y.; Murakami, D.

2016-12-01

The "Paris Agreement" requires major carbon emitting countries to conduct massive reduction efforts during the 21st century. At the same time, new carbon financing mechanisms are emerging. Among others, Green Bonds (GBs) is rapidly developing. In this paper, we discuss about the potential use of GBs for financing city level carbon management. In order to make the application effective, there are several issues to be studied with financial and environmental researchers together. Especially at city level, it is necessary to develop new GBs assessment methods to check the comprehensive environmental implications of the GBs projects. For this purpose, we discuss about the enhancement of currently developing district level Green Building standards and certification systems (LEED-ND). We also report about our new research results regarding city scale monitoring system (CO2, energy, transport, ecosystem etc.) for the reporting. *This paper is related to a Future Earth (Global Carbon Project) project proposal. It is also linked with development regarding the Knowledge Action Networks.

The Search for Extraterrestrial Intelligence in Earth's Solar Transit Zone.

PubMed

Heller, René; Pudritz, Ralph E

2016-04-01

Over the past few years, astronomers have detected thousands of planets and candidate planets by observing their periodic transits in front of their host stars. A related method, called transit spectroscopy, might soon allow studies of the chemical imprints of life in extrasolar planetary atmospheres. Here, we address the reciprocal question, namely, from where is Earth detectable by extrasolar observers using similar methods. We explore Earth's transit zone (ETZ), the projection of a band around Earth's ecliptic onto the celestial plane, where observers can detect Earth transits across the Sun. ETZ is between 0.520° and 0.537° wide due to the noncircular Earth orbit. The restricted Earth transit zone (rETZ), where Earth transits the Sun less than 0.5 solar radii from its center, is about 0.262° wide. We first compile a target list of 45 K and 37 G dwarf stars inside the rETZ and within 1 kpc (about 3260 light-years) using the Hipparcos catalogue. We then greatly enlarge the number of potential targets by constructing an analytic galactic disk model and find that about 10(5) K and G dwarf stars should reside within the rETZ. The ongoing Gaia space mission can potentially discover all G dwarfs among them (several 10(4)) within the next 5 years. Many more potentially habitable planets orbit dim, unknown M stars in ETZ and other stars that traversed ETZ thousands of years ago. If any of these planets host intelligent observers, they could have identified Earth as a habitable, or even as a living, world long ago, and we could be receiving their broadcasts today. The K2 mission, the Allen Telescope Array, the upcoming Square Kilometer Array, or the Green Bank Telescope might detect such deliberate extraterrestrial messages. Ultimately, ETZ would be an ideal region to be monitored by the Breakthrough Listen Initiatives, an upcoming survey that will constitute the most comprehensive search for extraterrestrial intelligence so far.

The Search for Extraterrestrial Intelligence in Earth's Solar Transit Zone

NASA Astrophysics Data System (ADS)

Heller, René; Pudritz, Ralph E.

2016-04-01

Over the past few years, astronomers have detected thousands of planets and candidate planets by observing their periodic transits in front of their host stars. A related method, called transit spectroscopy, might soon allow studies of the chemical imprints of life in extrasolar planetary atmospheres. Here, we address the reciprocal question, namely, from where is Earth detectable by extrasolar observers using similar methods. We explore Earth's transit zone (ETZ), the projection of a band around Earth's ecliptic onto the celestial plane, where observers can detect Earth transits across the Sun. ETZ is between 0.520° and 0.537° wide due to the noncircular Earth orbit. The restricted Earth transit zone (rETZ), where Earth transits the Sun less than 0.5 solar radii from its center, is about 0.262° wide. We first compile a target list of 45 K and 37 G dwarf stars inside the rETZ and within 1 kpc (about 3260 light-years) using the Hipparcos catalogue. We then greatly enlarge the number of potential targets by constructing an analytic galactic disk model and find that about 105 K and G dwarf stars should reside within the rETZ. The ongoing Gaia space mission can potentially discover all G dwarfs among them (several 104) within the next 5 years. Many more potentially habitable planets orbit dim, unknown M stars in ETZ and other stars that traversed ETZ thousands of years ago. If any of these planets host intelligent observers, they could have identified Earth as a habitable, or even as a living, world long ago, and we could be receiving their broadcasts today. The K2 mission, the Allen Telescope Array, the upcoming Square Kilometer Array, or the Green Bank Telescope might detect such deliberate extraterrestrial messages. Ultimately, ETZ would be an ideal region to be monitored by the Breakthrough Listen Initiatives, an upcoming survey that will constitute the most comprehensive search for extraterrestrial intelligence so far.

Visualizing Sun-Earth-Moon Relationships through Hands-On Modeling

NASA Astrophysics Data System (ADS)

Morton, Abby

2013-04-01

"Tell me and I forget, teach me and I may remember, involve me and I learn." -Benjamin Franklin Understanding the spatial relationships between the sun, Earth and Moon is fundamental to any basic earth science education. Since both of the following concepts involve shadows on three-dimensional spheres, seeing them on paper is not often conducive to understanding. In the first activity, students use five Styrofoam balls painted to look like the sun and the four positions of the earth in each season. Students position the Earth-balls in their correct order around the sun and translate what they are seeing onto paper. In the second activity, students hold up a Styrofoam ball painted half white, half black. A picture of the sun is projected at the front of the classroom. They move the ball around their heads as if they were the Earth, keeping the lit side of the moon always facing the sun. They then draw the phases of the moon as they see them.

The high-pressure phase diagram of Fe(0.94)O - A possible constituent of the earth's core

NASA Technical Reports Server (NTRS)

Knittle, Elise; Jeanloz, Raymond

1991-01-01

Electrical resistivity measurements to pressures of 83 GPa and temperatures ranging from 300 K to 4300 K confirm the presence of both crystalline and liquid metallic phases of FeO at pressures above 60-70 GPa and temperatures above 1000 K. By experimentally determinig the melting temperature of FeO to 100 GPa and of a model-core composition at 83 GPa, it is found that the solid-melt equilibria can be described by complete solid solution across the Fe-FeO system at pressures above 70 GPa. The results indicate that oxygen is a viable and likely candidate for the major light alloying element of the earth's liquid outer core. The data suggest that the temperature at the core-mantle boundary is close to 4800 K and that heat lost out of the core accounts for more than 20 percent of the heat flux observed at the surface.

Finite-Source Inversion for the 2004 Parkfield Earthquake using 3D Velocity Model Green's Functions

NASA Astrophysics Data System (ADS)

Kim, A.; Dreger, D.; Larsen, S.

2008-12-01

We determine finite fault models of the 2004 Parkfield earthquake using 3D Green's functions. Because of the dense station coverage and detailed 3D velocity structure model in this region, this earthquake provides an excellent opportunity to examine how the 3D velocity structure affects the finite fault inverse solutions. Various studies (e.g. Michaels and Eberhart-Phillips, 1991; Thurber et al., 2006) indicate that there is a pronounced velocity contrast across the San Andreas Fault along the Parkfield segment. Also the fault zone at Parkfield is wide as evidenced by mapped surface faults and where surface slip and creep occurred in the 1966 and the 2004 Parkfield earthquakes. For high resolution images of the rupture process"Ait is necessary to include the accurate 3D velocity structure for the finite source inversion. Liu and Aurchuleta (2004) performed finite fault inversions using both 1D and 3D Green's functions for 1989 Loma Prieta earthquake using the same source paramerization and data but different Green's functions and found that the models were quite different. This indicates that the choice of the velocity model significantly affects the waveform modeling at near-fault stations. In this study, we used the P-wave velocity model developed by Thurber et al (2006) to construct the 3D Green's functions. P-wave speeds are converted to S-wave speeds and density using by the empirical relationships of Brocher (2005). Using a finite difference method, E3D (Larsen and Schultz, 1995), we computed the 3D Green's functions numerically by inserting body forces at each station. Using reciprocity, these Green's functions are recombined to represent the ground motion at each station due to the slip on the fault plane. First we modeled the waveforms of small earthquakes to validate the 3D velocity model and the reciprocity of the Green"fs function. In the numerical tests we found that the 3D velocity model predicted the individual phases well at frequencies lower than 0

Indocyanine green angiography of juvenile X-linked retinoschisis.

PubMed

Souied, Eric H; Goritsa, Anna; Querques, Giuseppe; Coscas, Gabriel; Soubrane, Gisele

2005-09-01

In juvenile X-linked retinoschisis (XLRS), fluorescein angiography is usually unremarkable and contributes poorly to the diagnosis. However, indocyanine green (ICG) angiography features in eyes that are affected with XLRS were not yet described. Retrospective observational case series. A complete ophthalmologic examination that included ICG angiography was performed on three unrelated male patients (six eyes) who were 15, 22, and 48 years old. A distinct hyperfluorescent stellate pattern in the macular area that was associated with radial lines of hypofluorescence that were centered on the foveola was observed on the early phase of ICG examination (six of six eyes). This feature disappeared on the late phase of ICG examination. On these six XLRS eyes, early phases of ICG examination revealed an unusual radial aspect on the macula. This finding suggests that ICG angiography may be useful for the diagnosis of XLRS.

DSCOVR/EPIC Images and Science: A New Way to View the Entire Sunlit Earth From A Sun-Earth Lagrange-1 Orbit

NASA Astrophysics Data System (ADS)

Herman, J. R.; Marshak, A.; Szabo, A.

2015-12-01

The DSCOVR mission was launched into a Sun-Earth Lagrange-1 orbit 1.5 million kilometers from earth in February 2015 onboard a SpaceX Falcon-9 rocket. The solar wind and earth science instruments were tested during the 4.5 month journey to L-1. The first data were obtained during the June-July commissioning phase, which included the first moderate resolution (10 km) color images of the entire sunlit earth, color images of the Moon, and scientific data from 10 narrow band filters (317.5, 325, 340, 388, 443, 551, 680, 687.75, 764, and 779.5 nm). Three of these filters were used to construct the color images (443, 551, 680 nm) based on the average eye response histogram of the sunlit earth. This talk will discuss some of the issues involved in deriving science quality data for global ozone, the aerosol index (dust, smoke, and volcanic ash), cloud amounts and reflectivity, and cloud height (measured from the O2 A- and B-bands). As with most new satellites, the science data are preliminary.

Interactions of microorganisms with rare earth ions and their utilization for separation and environmental technology.

PubMed

Moriwaki, Hiroshi; Yamamoto, Hiroki

2013-01-01

In recent years, rare earth elements (REEs) have been widely used in various modern technological devices and the global demand for REE has been increasing. The increased demand for REEs has led to environmental exposure or water pollution from rare earth metal mines and various commercial products. Therefore, the development of a safe technology for the separation and adsorption of REEs is very important from the perspective of green chemistry and environmental pollution. In this review, the application and mechanisms of microorganisms for the removal and extraction of REEs from aqueous solutions are described. In addition, the advantages in using microorganisms for REE adsorption and future studies on this topic are discussed.

Is green economy achievable through championing green growth? A local government experience from Zambia

PubMed Central

2016-01-01

The need to enhance environmental sustainability, sustainable development and growth that takes into account the well-being of the people and nature because of the increased production and consumption of goods and services is the major driver to the introduction of green economy in Zambia and countries in southern Africa. This article examines the extent to which local government in Zambia has embraced green growth and green economy and critically analyses the concept of green economy and green growth. This study is based on a review of planning and policy documents, a household questionnaire survey and interviews with various institutions, planners and rural development organisations. A number of policies implemented at the local government level were analysed and reflected upon irrespective of whether they contain the components of green growth and green economy and the extent to which they contribute to attaining green economy. The article argues that the need for economic diversification is important as far as green economy is concerned. The article recommends the need to invest in research and development in order to find more carbon-free economic activities. The conclusion is that local government is key to achieving green growth and green economy, because it is involved at all levels, from policy formulation to implementation.

What Is Green?

ERIC Educational Resources Information Center

Pokrandt, Rachel

2010-01-01

Green is a question with varying answers and sometimes no answer at all. It is a question of location, resources, people, environment, and money. As green really has no end point, a teacher's goal should be to teach students to question and consider green. In this article, the author provides several useful metrics to help technology teachers…

Green Transportation for a Green Earth

ERIC Educational Resources Information Center

Katsioloudis, Petros J.; Jones, Mildred V.

2012-01-01

Transportation is one of the biggest contributors to the destruction of the environment. Results from environmental research and pursuant governmental regulations are changing the way companies do business and how transportation systems address the future. The Environmental Protection Agency (EPA) has been at the forefront in leading environmental…

Subsonic Ultra Green Aircraft Research

NASA Technical Reports Server (NTRS)

Bradley, Marty K.; Droney, Christopher K.

2011-01-01

This Final Report summarizes the work accomplished by the Boeing Subsonic Ultra Green Aircraft Research (SUGAR) team in Phase 1, which includes the time period of October 2008 through March 2010. The team consisted of Boeing Research and Technology, Boeing Commercial Airplanes, General Electric, and Georgia Tech. The team completed the development of a comprehensive future scenario for world-wide commercial aviation, selected baseline and advanced configurations for detailed study, generated technology suites for each configuration, conducted detailed performance analysis, calculated noise and emissions, assessed technology risks, and developed technology roadmaps. Five concepts were evaluated in detail: 2008 baseline, N+3 reference, N+3 high span strut braced wing, N+3 gas turbine battery electric concept, and N+3 hybrid wing body. A wide portfolio of technologies was identified to address the NASA N+3 goals. Significant improvements in air traffic management, aerodynamics, materials and structures, aircraft systems, propulsion, and acoustics are needed. Recommendations for Phase 2 concept and technology projects have been identified.

Green Power Partnership Videos

EPA Pesticide Factsheets

The Green Power Partnership develops videos on a regular basis that explore a variety of topics including, Green Power partnership, green power purchasing, Renewable energy certificates, among others.

Substorm Evolution in the Near-Earth Plasma Sheet

NASA Technical Reports Server (NTRS)

Erickson, Gary M.

2004-01-01

This grant represented one-year, phase-out funding for the project of the same name (NAG5-9110 to Boston University) to determine precursors and signatures of local substorm onset and how they evolve in the plasma sheet using the Geotail near-Earth database. We report here on two accomplishments: (1) Completion of an examination of plasma velocity signature at times of local onsets in the current disruption (CD) region. (2) Initial investigation into quantification of near-Earth flux-tube contents of injected plasma at times of substorm injections.

Lack of pharmacokinetic interaction between fluvastatin and green tea in healthy volunteers.

PubMed

Misaka, Shingen; Abe, Osamu; Sato, Hideyuki; Ono, Tomoyuki; Shikama, Yayoi; Onoue, Satomi; Yabe, Hirooki; Kimura, Junko

2018-05-01

The objective of this study is to assess the effects of green tea and its major catechin component, (-)-epigallocatechin gallate (EGCG), on CYP2C9-mediated substrate metabolism in vitro, and the pharmacokinetics of fluvastatin in healthy volunteers. The metabolism of diclofenac and fluvastatin in human recombinant CYP2C9 was investigated in the presence of EGCG. In a randomized three-phase crossover study, 11 healthy volunteers ingested a single 20-mg dose of fluvastatin with green tea extract (GTE), containing 150 mg of EGCG, along with water (300 mL), brewed green tea (300 mL), or water (300 mL) after overnight fasting. Plasma concentrations of fluvastatin and EGCG were measured by ultra-performance liquid chromatography with fluorescence detection and a single mass spectrometer. EGCG inhibited diclofenac 4'-hydroxylation and fluvastatin degradation with IC 50 of 2.23 and 48.04 μM, respectively. Brewed green tea used in the clinical study also dose-dependently inhibited the metabolism of diclofenac and fluvastatin in vitro. However, no significant effects of GTE and brewed green tea were observed in plasma concentrations of fluvastatin. The geometric mean ratios with 90% CI for area under the plasma concentration-time curve (AUC 0-∞ ) of fluvastatin were 0.993 (0.963-1.024, vs. brewed green tea) and 0.977 (0.935-1.020, vs. GTE). Although in vitro studies indicated that EGCG and brewed green tea produce significant inhibitory effects on CYP2C9 activity, the concomitant administration of green tea and fluvastatin in healthy volunteers did not influence the pharmacokinetics of fluvastatin.

Compositional and phase relations among rare earth element minerals

NASA Technical Reports Server (NTRS)

Burt, D. M.

1989-01-01

A review is presented that mainly treats minerals in which the rare-earth elements are essential constituents, e.g., bastnaesite, monazite, xenotime, aeschynite, allanite. The chemical mechanisms and limits of REE substitution in some rock-forming minerals (zircon, apatite, titanite, garnet) are also derived. Vector representation of complex coupled substitutions in selected REE-bearing minerals is examined and some comments on REE-partitioning between minerals as related to acid-based tendencies and mineral stabilities are presented. As the same or analogous coupled substitutions involving the REE occur in a wide variety of mineral structures, they are discussed together.

Check-Up of Planet Earth at the Turn of the Millennium: Contribution of EOS-Terra to a New Phase in Earth Sciences

NASA Technical Reports Server (NTRS)

Kaufman, Yoram

1999-01-01

Langley's remarkable solar and lunar spectra collected from Mt. Whitney inspired Arrhenius to develop the first quantitative climate model in 1896. In 1999, NASA's Earth Observing AM Satellite (EOS-Terra) will repeat Langley's experiment, but for the entire planet, thus pioneering a wide array of calibrated spectral observations from space of the Earth System. Conceived in response to real environmental problems, EOS-Terra, in conjunction with other international satellite efforts, will fill a major gap in current efforts by providing quantitative global data sets with a resolution of few kilometers on the physical, chemical and biological elements of the earth system. Thus, like Langley's data, EOS-Terra can revolutionize climate research by inspiring a new generation of climate system models and enable us to assess the human impact on the environment. In the talk I shall review the historical developments that brought to the Terra mission, its objectives and example of application to biomass burning.

Evolution of the Oxidation State of the Earth's Mantle

NASA Technical Reports Server (NTRS)

Danielson, L. R.; Righter, K.; Keller, L.; Christoffersen, E.; Rahman, Z.

2015-01-01

The oxidation state of the Earth's mantle during formation remains an unresolved question, whether it was constant throughout planetary accretion, transitioned from reduced to oxidized, or from oxidized to reduced. We investigate the stability of Fe3(+) at depth, in order to constrain processes (water, late accretion, dissociation of FeO) which may reduce or oxidize the Earth's mantle. In our previous experiments on shergottite compositions, variable fO2, T, and P less than 4 GPa, Fe3(+)/sigma Fe decreased slightly with increasing P, similar to terrestrial basalt. For oxidizing experiments less than 7GPa, Fe3(+)/sigma Fe decreased as well, but it's unclear from previous modelling whether the deeper mantle could retain significant Fe3(+). Our current experiments expand our pressure range deeper into the Earth's mantle and focus on compositions and conditions relevant to the early Earth. Preliminary multi-anvil experiments with Knippa basalt as the starting composition were conducted at 5-7 GPa and 1800 C, using a molybdenum capsule to set the fO2 near IW, by buffering with Mo-MoO3. TEM and EELS analyses revealed the run products quenched to polycrystalline phases, with the major phase pyroxene containing approximately equal to Fe3(+)/2(+). Experiments are underway to produce glassy samples that can be measured by EELS and XANES, and are conducted at higher pressures.

Use of indocyanine green and sodium fluorescein for anterior segment angiography in ophthalmologically normal cats.

PubMed

Pirie, Chris G; Alario, Anthony

2015-10-01

To assess and compare results of anterior segment angiography of ophthalmologically normal cats following IV injection with indocyanine green and sodium fluorescein dyes. 10 client-owned cats. Anterior segment angiography was performed in anesthetized cats following administration of 0.25% indocyanine green (1.0 mg/kg, IV) or 10% sodium fluorescein (20 mg/kg, IV) solution. All cats received both treatments. Imaging (1 eye/cat) was performed with a full-spectrum digital single-lens reflex camera equipped with an adaptor (1 image/s for 30 seconds) immediately following IV dye injection and 1, 2, 3, 4, and 5 minutes after injection. Onset and duration of arterial, capillary, and venous phases of iris vasculature were identified and compared statistically between treatments. Degree of iridal pigmentation, leakage of dye from iris vasculature, and image quality were subjectively assessed. No differences were found in onset or duration of vascular phases between treatments. Visibility of the iris vasculature was not impaired by poor or moderate iridal pigmentation with either method. Indocyanine green provided subjectively better vascular detail and image contrast than sodium fluorescein. No vascular dye leakage was observed following indocyanine green administration. Leakage of dye from blood vessels in the stroma (in 10 cats) and presence of dye in the anterior chamber (in 5 cats) were detected after sodium fluorescein administration. Images obtained with either fluorescent dye were considered to be of diagnostic quality. Lack of leakage following indocyanine green administration suggested this treatment may have better diagnostic utility for anterior segment angiography. The photographic equipment used provided a cost-effective alternative to existing imaging systems.

Solvent Extraction of Rare Earth Elements from a Nitric Acid Leach Solution of Apatite by Mixtures of Tributyl Phosphate and Di-(2-ethylhexyl) Phosphoric Acid

NASA Astrophysics Data System (ADS)

Ferdowsi, Ali; Yoozbashizadeh, Hossein

2017-12-01

Solvent extraction of rare earths from nitrate leach liquor of apatite using mixtures of tributyl phosphate (TBP) and di-(2-ethylhexyl) phosphoric acid (D2EHPA) was studied. The effects of nitrate and hydrogen ion concentration of the aqueous phase as well as the composition and concentration of extractants in the organic phase on the extraction behavior of lanthanum, cerium, neodymium, and yttrium were investigated. The distribution ratio of REEs increases by increasing the nitrate concentration in aqueous phase and concentration of extractants in organic phase, but the hydrogen ion concentration in aqueous phase has a decreasing effect. Yttrium as a heavy rare earth is more sensitive to these parameters than light rare earth elements. Although the composition of organic phase has a minor effect on the extraction of light rare earths, the percent of extraction of yttrium decreases dramatically by increasing the TBP content of organic phase. Mixtures of TBP and D2EHPA can show either synergism or antagonism extraction depending on the concentration and composition of extractants in organic phase. The best condition for separating rare earth elements in groups of heavy and light REEs can be achieved at high nitrate concentration, low H+ concentration, and high concentration of D2EHPA in organic phase. Separation of Ce and La by TBP and D2EHPA is practically impossible in the studied conditions; however, low nitrate concentration and high hydrogen ion concentration in aqueous phase and low concentration of extractants in organic phase favor the separation of Nd from other light rare earth elements.

Retention performance of green roofs in representative climates worldwide

NASA Astrophysics Data System (ADS)

Viola, F.; Hellies, M.; Deidda, R.

2017-10-01

role of climatic conditions, namely annual rainfall, potential evapotranspiration and their seasonality cycles, we found that they drive green roofs retention performance, which are the maxima when rainfall and temperature are in phase. Finally, we provide design charts for a first approximation of possible hydrological benefits deriving from the implementation of intensive or extensive green roofs in different world areas. As an example, 25 big cities have been indicated as benchmark case studies.

Earth Observations taken by Expedition 30 crewmember

NASA Image and Video Library

2012-01-29

ISS030-E-055569 (29 Jan. 2012) --- Southeastern USA at night is featured in this image photographed by an Expedition 30 crew member on the International Space Station. The brightly lit metropolitan areas of Atlanta, GA (center) and Jacksonville, FL (lower right) appear largest in the image with numerous other urban areas forming an interconnected network of light across the region. A large dark region to the northwest of Jacksonville, FL is the Okefenokee National Wildlife Refuge; likewise the ridges of the Appalachian Mountains form dark swaths to the north of Atlanta, GA and west of Charlotte, NC (center). The faint gold and green line of airglow—caused by ultraviolet radiation exciting the gas molecules in the upper atmosphere—parallels the horizon (or Earth limb).

Green Campus initiative and its impacts on quality of life of stakeholders in Green and Non-Green Campus universities.

PubMed

Tiyarattanachai, Ronnachai; Hollmann, Nicholas M

2016-01-01

In 2010, Universitas Indonesia (UI) developed the UI GreenMetric World University Ranking for universities to share information about their sustainability practices. This ranking system was well aligned with the basis of Sustainability for Higher Education. The scoring system can also be used as a guideline for universities to achieve sustainability in their campuses. Since its first launch, more universities around the world have increasingly participated in the ranking system including many universities in Thailand. This study compared perception of stakeholders in Green Campus and Non-Green Campus universities in Thailand regarding stakeholders' satisfaction on sustainability practices and perceived quality of life at their campuses. The results showed that stakeholders at the studied Green Campus University were more satisfied and had significantly better perceived quality of life compared to stakeholders from the studied Non-Green Campus university. The results suggested that universities should adopt the criteria set in the UI GreenMetric World University Ranking to achieve better sustainability in their campuses and improve quality of life of their stakeholders.

The Green Man

ERIC Educational Resources Information Center

Watson-Newlin, Karen

2010-01-01

The Jolly Green Giant. Robin Hood. The Bamberg Cathedral. Tales of King Arthur. Ecology. What do they have in common? What legends and ancient myths are shrouded in the tales of the Green Man? Most often perceived as an ancient Celtic symbol as the god of spring and summer, the Green Man disappears and returns year after year, century after…

NITRATE IN LEAFY GREEN VEGETABLES AND ESTIMATED INTAKE.

PubMed

Brkić, Danijel; Bošnir, Jasna; Bevardi, Martina; Bošković, Andrea Gross; Miloš, Sanja; Lasić, Dario; Krivohlavek, Adela; Racz, Aleksandar; Ćuić, Ana Mojsović; Trstenjak, Natalija Uršulin

2017-01-01

Vegetarian diets are rich in vegetables. Green leafy vegetables are foods that contain considerable amounts of nitrate, which can have both positive and negative effects on the human body. Their potential carcinogenicity and toxicity have been proven, particularly after the reduction of nitrate to nitrite itself or just serving as a reactant with amines and/or amides in the formation of N-nitroso compounds -N-nitrosamines and other nitrogen compounds which may have high levels of nitrate. The aim of this study was to determine whether there is a significant difference, considering the location and seasonal sampling period, in the level of nitrate in certain types of green vegetables, all in order to be able to assess their intake, and possible impact on human health, especially knowing that exposure to nitrate can be potentially higher for vegetarian population group. For this purpose, the sampling of 200 different leafy green vegetables was conducted, all of which could be found in free sale in the Republic of Croatia. The sampling was conducted during two seasonal periods - the spring and autumn period. In the springtime, lettuce (sem), spinach (pinacho), kale (kale), chard (mangel) and cabbage (brassica) were sampled, and in autumn lettuce, spinach, kale, chard and arugula. Samples were analyzed using high performance liquid chromatography (HPLC) with UV detection. The results from the spring sampling phase were in the range of 603 mg/kg for cabbage - 972 mg/kg for chard, and for autumn phase of 1.024 mg/kg for chard to 4.354 mg/kg for the arugula. The results showed that there were significant differences (p <0.05) for most of the samples analyzed, considering the sampling locations and time period. The results indicate that the analyzed vegetables contain significant amounts of nitrate in their composition, which represents relatively significant, but still acceptable intake into the human body.

A divalent rare earth oxide semiconductor: Yttrium monoxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaminaga, Kenichi; Sei, Ryosuke; Department of Chemistry, Tohoku University, Sendai 980-8578

Rare earth oxides are usually widegap insulators like Y{sub 2}O{sub 3} with closed shell trivalent rare earth ions. In this study, solid phase rock salt structure yttrium monoxide, YO, with unusual valence of Y{sup 2+} (4d{sup 1}) was synthesized in a form of epitaxial thin film by pulsed laser deposition method. YO has been recognized as gaseous phase in previous studies. In contrast with Y{sub 2}O{sub 3}, YO was dark-brown colored and narrow gap semiconductor. The tunable electrical conductivity ranging from 10{sup −1} to 10{sup 3} Ω{sup −1 }cm{sup −1} was attributed to the presence of oxygen vacancies serving as electron donor.more » Weak antilocalization behavior observed in magnetoresistance indicated significant role of spin-orbit coupling as a manifestation of 4d electron carrier.« less

Thermodynamic and Thermoelastic properties of the NAL Phase

NASA Astrophysics Data System (ADS)

Marcondes, M. L.; Yao, C.; Wu, Z.; Wentzcovitch, R.

2017-12-01

Subduction of Mid Ocean Ridge Basalt (MORB) transports crust elements to the deep Earth. Therefore, it is important to study MORB in order to understand geophysical processes in the mantle. The high Al2O3 content of the MORB gives rise to a new aluminous phase (NAL) that constitutes up to 25% of its composition [1]. Phase equilibrium study of MgAl2O4-CaAl2O4 generated the mineral CaMg2Al6O12 with hexagonal symmetry, which was proposed for the NAL phase [2,3]. The NAL chemical composition, however, shows significantly less calcium [1,4] and several compositions have been considered in previous studies of this phase [5,6]. Here we present an ab initio study of NAL phases at high temperatures with several possible compositions. We used the quasiharmonic approximation to address thermodynamic and thermoelastic properties and seismic velocities of this phase as function of composition. References[1] T. Irifune and A. E. Ringwood, Earth Planet. Sci. Lett. 117, 101 (1993). [2] H. Miura, Y. Hamada, T. Suzuki, M. Akaogi, N. Miyajima, and K. Fujino, Am. Mineral. 85, 1799 (2000). [3] M. Akaogi, Y. Hamada, T. Suzuki, M. Kobayashi, and M. Okada, Phys. Earth Planet. Inter. 115, 67 (1999). [4] A. Ricolleau, J. P. Perrillat, G. Fiquet, I. Daniel, J. Matas, A. Addad, N. Menguy, H. Cardon, M. Mezouar, and N. Guignot, J. Geophys. Res. Solid Earth 115, B08202 (2010). [5] M. Mookherjee, B. B. Karki, L. Stixrude, and C. Lithgow-Bertelloni, Geophys. Res. Lett. 39, L19306 (2012). [6] K. Kawai and T. Tsuchiya, Geophys. Res. Lett. 37, L17302 (2010).

Green Buildings and Health.

PubMed

Allen, Joseph G; MacNaughton, Piers; Laurent, Jose Guillermo Cedeno; Flanigan, Skye S; Eitland, Erika Sita; Spengler, John D

2015-09-01

Green building design is becoming broadly adopted, with one green building standard reporting over 3.5 billion square feet certified to date. By definition, green buildings focus on minimizing impacts to the environment through reductions in energy usage, water usage, and minimizing environmental disturbances from the building site. Also by definition, but perhaps less widely recognized, green buildings aim to improve human health through design of healthy indoor environments. The benefits related to reduced energy and water consumption are well-documented, but the potential human health benefits of green buildings are only recently being investigated. The objective of our review was to examine the state of evidence on green building design as it specifically relates to indoor environmental quality and human health. Overall, the initial scientific evidence indicates better indoor environmental quality in green buildings versus non-green buildings, with direct benefits to human health for occupants of those buildings. A limitation of much of the research to date is the reliance on indirect, lagging and subjective measures of health. To address this, we propose a framework for identifying direct, objective and leading "Health Performance Indicators" for use in future studies of buildings and health.

Am phases in the matrix of a U–Pu–Zr alloy with Np, Am, and rare-earth elements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Janney, Dawn E.; Kennedy, J. Rory; Madden, James W.

2015-01-01

Phases and microstructures in the matrix of an as-cast U-Pu-Zr alloy with 3 wt% Am, 2% Np, and 8% rare-earth elements were characterized by scanning and transmission electron microscopy. The matrix consists primarily of two phases, both of which contain Am: ζ-(U, Np, Pu, Am) (~70 at% U, 5% Np, 14% Pu, 1% Am, and 10% Zr) and δ-(U, Np, Pu, Am)Zr 2 (~25% U, 2% Np, 10-15% Pu, 1-2% Am, and 55-60 at% Zr). These phases are similar to those in U-Pu-Zr alloys, although the Zr content in ζ-(U, Np, Pu, Am) is higher than that in ζ-(U, Pu)more » and the Zr content in δ-(U, Np, Pu, Am)Zr 2 is lower than that in δ-UZr 2. Nanocrystalline actinide oxides with structures similar to UO2 occurred in some areas, but may have formed by reactions with the atmosphere during sample handling. Planar features consisting of a central zone of ζ-(U, Np, Pu, Am) bracketed by zones of δ-(U, Np, Pu, Am)Zr 2 bound irregular polygons ranging in size from a few micrometers to a few tens of micrometers across. The rest of the matrix consists of elongated domains of ζ-(U, Np, Pu, Am) and δ-(U, Np, Pu, Am)Zr 2. Each of these domains is a few tens of nanometers across and a few hundred nanometers long. The domains display strong preferred orientations involving areas a few hundred nanometers to a few micrometers across.« less

77 FR 24494 - Office of Federal High-Performance Green Buildings; Green Building Advisory Committee...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-24

... Federal High-Performance Green Buildings; Green Building Advisory Committee; Notification of Upcoming... agenda for the May 9, 2012, meeting of the Green Building Advisory Committee Meeting (the Committee). The... Sandler, Designated Federal Officer, Office of Federal High-Performance Green Buildings, Office of...

77 FR 66616 - Office of Federal High-Performance Green Buildings; Green Building Advisory Committee...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-06

... Federal High-Performance Green Buildings; Green Building Advisory Committee; Notification of Upcoming... and agenda for the November 27, 2012, meeting of the Green Building Advisory Committee Meeting (the... Green Buildings, Office of Government-wide Policy, General Services Administration, 1275 First Street NE...

78 FR 21368 - Office of Federal High-Performance Green Buildings; Green Building Advisory Committee...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-10

... Federal High-Performance Green Buildings; Green Building Advisory Committee; Notification of Upcoming... and agenda for the May 1, 2013, meeting of the Green Building Advisory Committee Meeting (the... Green Buildings, Office of Government-wide Policy, General Services Administration, 1275 First Street NE...

Screening and genetic manipulation of green organisms for establishment of biological life support systems in space.

PubMed

Saei, Amir Ata; Omidi, Amir Ali; Barzegari, Abolfazl

2013-01-01

Curiosity has driven humankind to explore and conquer space. However, today, space research is not a means to relieve this curiosity anymore, but instead has turned into a need. To support the crew in distant expeditions, supplies should either be delivered from the Earth, or prepared for short durations through physiochemical methods aboard the space station. Thus, research continues to devise reliable regenerative systems. Biological life support systems may be the only answer to human autonomy in outposts beyond Earth. For construction of an artificial extraterrestrial ecosystem, it is necessary to search for highly adaptable super-organisms capable of growth in harsh space environments. Indeed, a number of organisms have been proposed for cultivation in space. Meanwhile, some manipulations can be done to increase their photosynthetic potential and stress tolerance. Genetic manipulation and screening of plants, microalgae and cyanobacteria is currently a fascinating topic in space bioengineering. In this commentary, we will provide a viewpoint on the realities, limitations and promises in designing biological life support system based on engineered and/or selected green organism. Special focus will be devoted to the engineering of key photosynthetic enzymes in pioneer green organisms and their potential use in establishment of transgenic photobioreactors in space.

Screening and genetic manipulation of green organisms for establishment of biological life support systems in space

PubMed Central

Saei, Amir Ata; Omidi, Amir Ali; Barzegari, Abolfazl

2013-01-01

Curiosity has driven humankind to explore and conquer space. However, today, space research is not a means to relieve this curiosity anymore, but instead has turned into a need. To support the crew in distant expeditions, supplies should either be delivered from the Earth, or prepared for short durations through physiochemical methods aboard the space station. Thus, research continues to devise reliable regenerative systems. Biological life support systems may be the only answer to human autonomy in outposts beyond Earth. For construction of an artificial extraterrestrial ecosystem, it is necessary to search for highly adaptable super-organisms capable of growth in harsh space environments. Indeed, a number of organisms have been proposed for cultivation in space. Meanwhile, some manipulations can be done to increase their photosynthetic potential and stress tolerance. Genetic manipulation and screening of plants, microalgae and cyanobacteria is currently a fascinating topic in space bioengineering. In this commentary, we will provide a viewpoint on the realities, limitations and promises in designing biological life support system based on engineered and/or selected green organism. Special focus will be devoted to the engineering of key photosynthetic enzymes in pioneer green organisms and their potential use in establishment of transgenic photobioreactors in space. PMID:22992434

Effects of dynamic long-period ocean tides on changes in earth's rotation rate

NASA Technical Reports Server (NTRS)

Nam, Young; Dickman, S. R.

1990-01-01

As a generalization of the zonal response coefficient first introduced by Agnew and Farrell (1978), the zonal response function kappa of the solid earth-ocean system is defined as the ratio, in the frequency domain, of the tidal change in earth's rotation rate to the tide-generating potential. Amplitudes and phases of kappa for the monthly, fortnightly, and nine-day lunar tides are estimated from 2 1/2 years of VLBI UT1 observations, corrected for atmospheric angular momentum effects using NMC wind and pressure series. Using the dynamic ocean tide model of Dickman (1988, 1989), amplitudes and phases of kappa for an elastic earth-ocean system are predicted. The predictions confirm earlier results which found that dynamic effects of the longer-period ocean tides reduce the amplitude of kappa by about 1 percent.

Satellites reveal contrasting responses of regional climate to the widespread greening of Earth.

PubMed

Forzieri, Giovanni; Alkama, Ramdane; Miralles, Diego G; Cescatti, Alessandro

2017-06-16

Changes in vegetation cover associated with the observed greening may affect several biophysical processes, whose net effects on climate are unclear. We analyzed remotely sensed dynamics in leaf area index (LAI) and energy fluxes in order to explore the associated variation in local climate. We show that the increasing trend in LAI contributed to the warming of boreal zones through a reduction of surface albedo and to an evaporation-driven cooling in arid regions. The interplay between LAI and surface biophysics is amplified up to five times under extreme warm-dry and cold-wet years. Altogether, these signals reveal that the recent dynamics in global vegetation have had relevant biophysical impacts on the local climates and should be considered in the design of local mitigation and adaptation plans. Copyright © 2017, American Association for the Advancement of Science.

Hydrogen production by a thermophilic blue-green alga Mastigocladus laminosus

NASA Astrophysics Data System (ADS)

Miura, Y.; Yokoyama, H.; Miyamoto, K.; Okazaki, M.; Komemushi, S.

Light-driven hydrogen evolution by a thermophilic blue-green alga, Mastigocladus laminosus, was demonstrated and characterized under nitrogen-starved conditions. Air-grown cultures of this alga evolved hydrogen under Ar/CO2 at rates up to 2.2 ml/mg chl/hr. The optimum temperature and pH for the hydrogen evolution were 44-49 C and pH 7.0-7.5, respectively. Evolution in light was depressed by N2 gas and inhibited by salicylaldoxime or 2,4-dinitrophenol, indicating that nitrogenase was mainly responsible for the hydrogen evolution. The evolution rate was improved by adding carbon monoxide and acetylene to the gas phase of Ar/CO2. In addition, photobiological production of hydrogen (biophotolysis) by various blue-green algae is briefly reviewed and discussed.

In situ characterization of green rust in the presence of arsenate and phosphate in simulated oxidized and reduced environments.

NASA Astrophysics Data System (ADS)

Root, R. A.; O'Day, P. A.

2008-12-01

Nano- to micron-scale particles of mixed-valent iron hydroxide, specifically green rust (GR [FeII6- x(OH)y FeIIIx(OH)12-y]x+[Anionx- + H2O]x-), have been identified and studied as corrosion products of steel, and recently rediscovered in hydromorphic soils and sediments. Green rusts are intermediate phases produced by biotic and abiotic reductive dissolution of ferric oxyhydroxides, or by oxidation of dissolved ferrous iron. Adsorbed oxyanions can stabilize GR phases and inhibit the formation of thermodynamically favored iron phases such as magnetite or lepidocrocite in subsurface environments. This study used synchrotron XRD to characterize iron (hydr)oxide minerals precipitated from solution and subsequent aging products under different environmental conditions of pH and Eh. Here we show the in situ abiotic development of green rust and its stabilization by the addition of adsorbed oxyanions or alternatively, subsequent rapid transformation to magnetite or lepidocrocite in the absence of added anions. A closed batch reactor with an in-line capillary was used to expose the reaction products to continuous synchrotron radiation. Laue patterns were collected at time intervals of 3-5 minutes and used to detect the formation of crystalline iron (hydr)oxide minerals that precipitate as a function time and chemical perturbations to the system, i.e. changing the pH, redox potential, ratio of Fe2+ to OH- , and addition of an oxyanion, arsenate or phosphate. The reactions were monitored by observing the development of diagnostic green rust XRD d-spacing peak at 10.9 Å (300), the 3.29 Å (210) d- spacing for lepidocrocite, and the 2.53 Å (100) d-spacing for magnetite, with continuous in-line measurement of pH and ORP. We found that green rust was stabilized by the adsorption of arsenate and phosphate. In the presence of arsenate or phosphate at pH =7, green rust transformed to lepidocrocite after several hours when anoxic controls were removed. When pH and Eh were constant

Green Power Community News

EPA Pesticide Factsheets

This page features news about EPA's Green Power Communities. GPCs are a subset of the Green Power Partnership; municipalities or tribal governments where government, businesses, and residents collectively use enough green power to meet GPP requirements.

Rare-earth metal oxide doped transparent mesoporous silica plates under non-aqueous condition as a potential UV sensor.

PubMed

Lee, Sang-Joon; Park, Sung Soo; Lee, Sang Hyun; Hong, Sang-Hyun; Ha, Chang-Sik

2013-11-01

Transparent mesoporous silica plates doped with rare-earth metal oxide were prepared using solvent-evaporation method based on the self-organization between structure-directing agent and silicate in a non-aqueous solvent. A triblock copolymer, Pluronic (F127 or P123), was used as the structure-directing agent, while tetraethyl orthosilicate (TEOS) was used as a silica source. The pore diameter and the surface area of the mesoporous silica plate prepared with the optimized conditions were ca 40 A and 600 m2 g(-1), respectively, for both structure-directing agent. Rare-earth metal oxides (Eu, Tb, Tm oxide) in mesochannel were formed via one-step synthetic route based on the preparation method of a silica plate. Optical properties of rare-earth metal oxide-doped mesoporous silica plates were investigated by UV irradiation and photoluminescence (PL) spectroscopy. Under the exitation wavelength of 254 nm, the doped mesoporous silica plates emitted red, green and blue for Eu, Tb and Tm oxides, respectively. Rare-earth metal oxide-doped mesoporous silica plates showed enhanced PL intensity compared to that of the bulk rare-earth metal oxide.

Green space definition affects associations of green space with overweight and physical activity.

PubMed

Klompmaker, Jochem O; Hoek, Gerard; Bloemsma, Lizan D; Gehring, Ulrike; Strak, Maciej; Wijga, Alet H; van den Brink, Carolien; Brunekreef, Bert; Lebret, Erik; Janssen, Nicole A H

2018-01-01

In epidemiological studies, exposure to green space is inconsistently associated with being overweight and physical activity, possibly because studies differ widely in their definition of green space exposure, inclusion of important confounders, study population and data analysis. We evaluated whether the association of green space with being overweight and physical activity depended upon definition of greenspace. We conducted a cross-sectional study using data from a Dutch national health survey of 387,195 adults. Distance to the nearest park entrance and surrounding green space, based on the Normalized Difference Vegetation Index (NDVI) or a detailed Dutch land-use database (TOP10NL), was calculated for each residential address. We used logistic regression analyses to study the association of green space exposure with being overweight and being moderately or vigorously physically active outdoors at least 150min/week (self-reported). To study the shape of the association, we specified natural splines and quintiles. The distance to the nearest park entrance was not associated with being overweight or outdoor physical activity. Associations of surrounding green space with being overweight or outdoor physical activity were highly non-linear. For NDVI surrounding greenness, we observed significantly decreased odds of being overweight [300m buffer, odds ratio (OR) = 0.88; 95% CI: 0.86, 0.91] and increased odds for outdoor physical activity [300m buffer, OR = 1.14; 95% CI: 1.10, 1.17] in the highest quintile compared to the lowest quintile. For TOP10NL surrounding green space, associations were mostly non-significant. Associations were generally stronger for subjects living in less urban areas and for the smaller buffers. Associations of green space with being overweight and outdoor physical activity differed considerably between different green space definitions. Associations were strongest for NDVI surrounding greenness. Copyright © 2017 The Authors. Published by

Green Power Partner Resources

EPA Pesticide Factsheets

EPA Green Power Partners can access tools and resources to help promote their green power commitments. Partners use these tools to communicate the benefits of their green power use to their customers, stakeholders, and the general public.

Review of Development Survey of Phase Change Material Models in Building Applications

PubMed Central

Akeiber, Hussein J.; Wahid, Mazlan A.; Hussen, Hasanen M.; Mohammad, Abdulrahman Th.

2014-01-01

The application of phase change materials (PCMs) in green buildings has been increasing rapidly. PCM applications in green buildings include several development models. This paper briefly surveys the recent research and development activities of PCM technology in building applications. Firstly, a basic description of phase change and their principles is provided; the classification and applications of PCMs are also included. Secondly, PCM models in buildings are reviewed and discussed according to the wall, roof, floor, and cooling systems. Finally, conclusions are presented based on the collected data. PMID:25313367

Strategy for earth explorers in global earth sciences

NASA Technical Reports Server (NTRS)

1988-01-01

The goal of the current NASA Earth System Science initiative is to obtain a comprehensive scientific understanding of the Earth as an integrated, dynamic system. The centerpiece of the Earth System Science initiative will be a set of instruments carried on polar orbiting platforms under the Earth Observing System program. An Earth Explorer program can open new vistas in the earth sciences, encourage innovation, and solve critical scientific problems. Specific missions must be rigorously shaped by the demands and opportunities of high quality science and must complement the Earth Observing System and the Mission to Planet Earth. The committee believes that the proposed Earth Explorer program provides a substantial opportunity for progress in the earth sciences, both through independent missions and through missions designed to complement the large scale platforms and international research programs that represent important national commitments. The strategy presented is intended to help ensure the success of the Earth Explorer program as a vital stimulant to the study of the planet.

A Free-Return Earth-Moon Cycler Orbit for an Interplanetary Cruise Ship

NASA Technical Reports Server (NTRS)

Genova, Anthony L.; Aldrin, Buzz

2015-01-01

A periodic circumlunar orbit is presented that can be used by an interplanetary cruise ship for regular travel between Earth and the Moon. This Earth-Moon cycler orbit was revealed by introducing solar gravity and modest phasing maneuvers (average of 39 m/s per month) which yields close-Earth encounters every 7 or 10 days. Lunar encounters occur every 26 days and offer the chance for a smaller craft to depart the cycler and enter lunar orbit, or head for a Lagrange point (e.g., EM-L2 halo orbit), distant retrograde orbit (DRO), or interplanetary destination such as a near-Earth object (NEO) or Mars. Additionally, return-to-Earth abort options are available from many points along the cycling trajectory.

Mapping Near-Earth Hazards

NASA Astrophysics Data System (ADS)

Kohler, Susanna

2016-06-01

How can we hunt down all the near-Earth asteroids that are capable of posing a threat to us? A new study looks at whether the upcoming Large Synoptic Survey Telescope (LSST) is up to the job.Charting Nearby ThreatsLSST is an 8.4-m wide-survey telescope currently being built in Chile. When it goes online in 2022, it will spend the next ten years surveying our sky, mapping tens of billions of stars and galaxies, searching for signatures of dark energy and dark matter, and hunting for transient optical events like novae and supernovae. But in its scanning, LSST will also be looking for asteroids that approach near Earth.Cumulative number of near-Earth asteroids discovered over time, as of June 16, 2016. [NASA/JPL/Chamberlin]Near-Earth objects (NEOs) have the potential to be hazardous if they cross Earths path and are large enough to do significant damage when they impact Earth. Earths history is riddled with dangerous asteroid encounters, including the recent Chelyabinsk airburst in 2013, the encounter that caused the kilometer-sized Meteor Crater in Arizona, and the impact thought to contribute to the extinction of the dinosaurs.Recognizing the potential danger that NEOs can pose to Earth, Congress has tasked NASA with tracking down 90% of NEOs larger than 140 meters in diameter. With our current survey capabilities, we believe weve discovered roughly 25% of these NEOs thus far. Now a new study led by Tommy Grav (Planetary Science Institute) examines whether LSST will be able to complete this task.Absolute magnitude, H, of asynthetic NEO population. Though these NEOs are all larger than 140 m, they have a large spread in albedos. [Grav et al. 2016]Can LSST Help?Based on previous observations of NEOs and resulting predictions for NEO properties and orbits, Grav and collaborators simulate a synthetic population of NEOs all above 140 m in size. With these improved population models, they demonstrate that the common tactic of using an asteroids absolute magnitude as a

Characterization of carbon silica hybrid fillers obtained by pyrolysis of waste green tires by the STEM–EDX method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Hartomy, Omar A.; Department of Physics, Faculty of Science, University of Tabuk, Tabuk 71491; Al-Ghamdi, Ahmed A.

2015-03-15

Dual phase carbon–silica hybrid fillers obtained by pyrolysis-cum-water vapor of waste green tires have been characterized by energy dispersive X-ray spectroscopy in a scanning transmission electron microscope, silicate analysis, weight analysis, atomic absorption spectroscopy and by inductively coupled plasma–optical emission spectroscopy. The results achieved have shown that the location and distribution of the phases in the carbon silica hybrid fillers as well as their most essential characteristics are influenced by the pyrolysis conditions. The carbon phase of the filler thus obtained is located predominantly in the space among silica aggregates which have already been existing while it has been formedmore » by elastomer destruction in the course of pyrolysis. The presence of ZnS also has been found in the hybrid fillers investigated. - Highlights: • Dual phase fillers obtained by pyrolysis of waste green tires have been characterized. • The STEM–EDX method was used for characterization. • The phase distributions in the fillers are influenced by the pyrolysis conditions.« less

Chinook salmon and green sturgeon migrate through San Francisco Estuary despite large distortions in the local magnetic field produced by bridges.

PubMed

Klimley, A Peter; Wyman, Megan T; Kavet, Robert

2017-01-01

Empirical evidence exists that some marine animals perceive and orient to local distortions in the earth's main static geomagnetic field. The magnetic fields produced by undersea electric power cables that carry electricity from hydrokinetic energy sources to shore-based power stations may produce similar local distortions in the earth's main field. Concerns exist that animals migrating along the continental shelves might orient to the magnetic field from the cables, and move either inshore or offshore away from their normal path. We have studied the effect of the Trans Bay Cable (TBC), an 85-km long, high voltage, direct current (DC) transmission line leading underwater from Pittsburg, CA to San Francisco, CA, on fishes migrating through the San Francisco Estuary. These included Chinook salmon smolts (Oncorhynchus tshawytscha) that migrate downstream through the San Francisco Estuary to the Pacific Ocean and adult green sturgeon (Acipenser medirostris), which migrate upstream from the ocean through the estuary to their spawning habitat in the upper Sacramento River and return to the ocean after spawning occurs. Based on a detailed gradiometer survey, we found that the distortions in the earth's main field produced by bridges across the estuary were much greater than those from the Trans Bay Cable. The former anomalies exceeded the latter by an order of magnitude or more. Significant numbers of tagged Chinook salmon smolts migrated past bridges, which produced strong magnetic anomalies, to the Golden Gate Bridge, where they were recorded by dual arrays of acoustic tag-detecting monitors moored in lines across the mouth of the bay. In addition, adult green sturgeon successfully swam upstream and downstream through the estuary on the way to and from their spawning grounds. Hence, the large anomalies produced by the bridges do not appear to present a strong barrier to the natural seasonal movement patterns of salmonid smolts and adult green sturgeon.

Chinook salmon and green sturgeon migrate through San Francisco Estuary despite large distortions in the local magnetic field produced by bridges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klimley, A. Peter; Wyman, Megan T.; Kavet, Robert

Empirical evidence exists that some marine animals perceive and orient to local distortions in the earth's main static geomagnetic field. The magnetic fields produced by undersea electric power cables that carry electricity from hydrokinetic energy sources to shore-based power stations may produce similar local distortions in the earth's main field. Concerns exist that animals migrating along the continental shelves might orient to the magnetic field from the cables, and move either inshore or offshore away from their normal path. We studied the effect of the Trans Bay Cable (TBC), an 85-km long, high voltage, direct current (DC) transmission line leadingmore » underwater from Pittsburg, CA to San Francisco, CA, on fishes migrating through the San Francisco Estuary. These included Chinook salmon smolts (Oncorhynchus tshawytscha) that migrate downstream through the San Francisco Estuary to the Pacific Ocean and adult green sturgeon (Acipenser medirostris), which migrate upstream from the ocean through the estuary to their spawning habitat in the upper Sacramento River and return to the ocean after spawning occurs. And based on a detailed gradiometer survey, we found that the distortions in the earth's main field produced by bridges across the estuary were much greater than those from the Trans Bay Cable. The former anomalies exceeded the latter by an order of magnitude or more. Significant numbers of tagged Chinook salmon smolts migrated past bridges, which produced strong magnetic anomalies, to the Golden Gate Bridge, where they were recorded by dual arrays of acoustic tag-detecting monitors moored in lines across the mouth of the bay. Additionally, adult green sturgeon successfully swam upstream and downstream through the estuary on the way to and from their spawning grounds. Hence, the large anomalies produced by the bridges do not appear to present a strong barrier to the natural seasonal movement patterns of salmonid smolts and adult green sturgeon.« less

Chinook salmon and green sturgeon migrate through San Francisco Estuary despite large distortions in the local magnetic field produced by bridges

DOE PAGES

Klimley, A. Peter; Wyman, Megan T.; Kavet, Robert; ...

2017-06-02

Empirical evidence exists that some marine animals perceive and orient to local distortions in the earth's main static geomagnetic field. The magnetic fields produced by undersea electric power cables that carry electricity from hydrokinetic energy sources to shore-based power stations may produce similar local distortions in the earth's main field. Concerns exist that animals migrating along the continental shelves might orient to the magnetic field from the cables, and move either inshore or offshore away from their normal path. We studied the effect of the Trans Bay Cable (TBC), an 85-km long, high voltage, direct current (DC) transmission line leadingmore » underwater from Pittsburg, CA to San Francisco, CA, on fishes migrating through the San Francisco Estuary. These included Chinook salmon smolts (Oncorhynchus tshawytscha) that migrate downstream through the San Francisco Estuary to the Pacific Ocean and adult green sturgeon (Acipenser medirostris), which migrate upstream from the ocean through the estuary to their spawning habitat in the upper Sacramento River and return to the ocean after spawning occurs. And based on a detailed gradiometer survey, we found that the distortions in the earth's main field produced by bridges across the estuary were much greater than those from the Trans Bay Cable. The former anomalies exceeded the latter by an order of magnitude or more. Significant numbers of tagged Chinook salmon smolts migrated past bridges, which produced strong magnetic anomalies, to the Golden Gate Bridge, where they were recorded by dual arrays of acoustic tag-detecting monitors moored in lines across the mouth of the bay. Additionally, adult green sturgeon successfully swam upstream and downstream through the estuary on the way to and from their spawning grounds. Hence, the large anomalies produced by the bridges do not appear to present a strong barrier to the natural seasonal movement patterns of salmonid smolts and adult green sturgeon.« less

Green Streets Help Baltimore, Others

EPA Pesticide Factsheets

Fifteen Green Streets, Green Towns, Green Jobs (G3) grants for will support projects in three states, including the conversion of hard surfaces to green space at Sarah’s Hope, a homeless shelter in a troubled Baltimore neighborhood.

It's hard to be green: Reverse green value chain.

PubMed

Couto, João; Tiago, Teresa; Gil, Artur; Tiago, Flávio; Faria, Sandra

2016-08-01

Firms have recently discovered that it is not enough to optimize internal processes and relationships with partners along the value chain to create a sustainable competitive market position. A clear customer orientation, which acknowledges that consumer buying behavior is complex and includes many elements implied in the value chain, is required. As companies offering green products are no exception to this rule, this study analyzes consumer behavior in Europe from a reserve green supply chain management perspective, using descriptive analyses and a structural equation model, with data collected by Flash Barometer comprising 26,573 responses from 28 European countries. The results suggest that European consumers are conscious of the green concept, but are not willing to buy or pay more for these products since the value is unclear. Companies offering green products must therefore rethink their strategies, especially in terms of value proposition, communication strategies, and eco-labeling. Copyright © 2016 Elsevier Inc. All rights reserved.

Green hydrophilic interaction chromatography using ethanol-water-carbon dioxide mixtures.

PubMed

Pereira, Alberto dos Santos; Girón, Ana Jiménez; Admasu, Engdawork; Sandra, Pat

2010-03-01

In hydrophilic interaction chromatography (HILIC), best results are obtained with high concentrations of acetonitrile. In the framework of green chromatography, different concentrations of carbon dioxide were added to the mobile phases acetonitrile-water and ethanol-water and the impact on retention and separation in HILIC using bare silica as stationary phase was explored. The features of HILIC using enhanced-fluidity mobile phases are illustrated with the analysis of the nucleobases and a mixture containing the nucleobases and cortisol, flurbiprofen, theophylline and caffeine. For both organic constituents, the elution window is widened in function of the carbon dioxide concentration and selectivity changes. At high concentrations of carbon dioxide in ethanol, separations were similar to those obtained with acetonitrile without carbon dioxide addition.

Method for preparing high cure temperature rare earth iron compound magnetic material

DOEpatents

Huang, Yuhong; Wei, Qiang; Zheng, Haixing

2002-01-01

Insertion of light elements such as H,C, or N in the R.sub.2 Fe.sub.17 (R=rare earth metal) series has been found to modify the magnetic properties of these compounds, which thus become prospective candidates for high performance permanent magnets. The most spectacular changes are increases of the Curie temperature, T.sub.c, of the magnetization, M.sub.s, and of coercivity, H.sub.c, upon interstitial insertion. A preliminary product having a component R--Fe--C,N phase is produced by a chemical route. Rare earth metal and iron amides are synthesized followed by pyrolysis and sintering in an inert or reduced atmosphere, as a result of which, the R--Fe--C,N phases are formed. Fabrication of sintered rare earth iron nitride and carbonitride bulk magnet is impossible via conventional process due to the limitation of nitridation method.

Atmospheric Production of Perchlorate on Earth and Mars

NASA Astrophysics Data System (ADS)

Claire, M.; Catling, D. C.; Zahnle, K. J.

2009-12-01

Natural production and preservation of perchlorate on Earth occurs only in arid environments. Isotopic evidence suggests a strong role for atmospheric oxidation of chlorine species via pathways including ozone or its photochemical derivatives. As the Martian atmosphere is both oxidizing and drier than the driest places on Earth, we propose an atmospheric origin for the Martian perchlorates measured by NASA's Phoenix Lander. A variety of hypothetical formation pathways can be proposed including atmospheric photochemical reactions, electrostatic discharge, and gas-solid reactions. Here, we investigate gas phase formation pathways using a 1-D photochemical model (Catling et al. 2009, accepted by JGR). Because perchlorate-rich deposits in the Atacama desert are closest in abundance to perchlorate measured at NASA's Phoenix Lander site, we start with a study of the means to produce Atacama perchlorate. We found that perchlorate can be produced in sufficient quantities to explain the abundance of perchlorate in the Atacama from a proposed gas phase oxidation of chlorine volatiles to perchloric acid. These results are sensitive to estimated reaction rates for ClO3 species. The feasibility of gas phase production for the Atacama provides justification for further investigations of gas phase photochemistry as a possible source for Martian perchlorate. In addition to the Atacama results, we will present a preliminary study incorporating chlorine chemistry into an existing Martian photochemical model (Zahnle et al. JGR 2008).

Green Power Communities Brochure

EPA Pesticide Factsheets

The Green Power Communities Brochure provides basic information about GPP's Green Power Communities (GPCs). The four-page brochure includes information about how to become a GPC, the benefits of procuring green power, and examples of how current GPCs are u

Effect of alkaline earth metals on the liquid-phase hydrogenation of hydroquinone over Ru-based catalysts

NASA Astrophysics Data System (ADS)

Li, Hongwei; Ji, Dong; Li, Yu; Liang, Yalan; Li, Gui Xian

2015-12-01

A series of Ru-based catalysts modified by alkaline earth metals were prepared by the impregnation-precipitation method and characterized using transmission electron microscopy, X-ray diffraction, ICP optical emission spectroscopy, Infrared Spectroscopy of adsorbed pyridine analysis and surface area analysis. The performance of the catalysts was measured via liquid-phase hydroquinone hydrogenation reaction. Results show that the Ru-Sr/NaY catalyst has the best activity and selectivity among those Ru-based catalysts. The conversion of hydroquinone and the selectivity to 1,4-cyclohexanediol reached up to 99.6% and 89.6% at optimum reaction condition (700 r/min, 423 K and 5 MPa pressure of H2 in 3 h). This may be attributed to the fact that the right amount of Strontium is beneficial to the good dispersion of the ruthenium nanoclusters on the surface of NaY and modify the acidic properties of the catalyst. Moreover, IR of adsorbed pyridine analysis suggested the proper ratio of L/B acid of the catalysts played an important role in the performance of the hydroquinone hydrogenation reaction.

Equatorial anisotropy of the Earth's inner-inner core

NASA Astrophysics Data System (ADS)

Song, X.; Wang, T.; Xia, H.

2015-12-01

Anisotropy of Earth's inner core is a key to understand its evolution and the generation of the Earth's magnetic field. All the previous inner core anisotropy models have assumed a cylindrical anisotropy with the symmetry axis parallel (or nearly parallel) to the Earth's spin axis. However, we have recently found that the fast axis in the inner part of the inner core is close to the equator from inner-core waves extracted from earthquake coda. We obtained inner core phases, PKIIKP2 and PKIKP2 (round-trip phases between the station and its antipode that passes straight through the center of the Earth and that is reflected from the inner core boundary, respectively), from stackings of autocorrelations of the coda of large earthquakes (10,000~40,000 s after Mw>=7.0 earthquakes) at seismic station clusters around the world. We observed large variation of up to 10 s along equatorial paths in the differential travel times PKIIKP2 - PKIKP2, which are sensitive to inner-core structure. The observations can be explained by a cylindrical anisotropy in the inner inner core (IIC) (with a radius of slightly less than half the inner core radius) that has a fast axis aligned near the equator and a cylindrical anisotropy in the outer inner core (OIC) that has a fast axis along the north-south direction. We have obtained more observations using the combination of autocorrelations and cross-correlations at low-latitude station arrays. The results further confirm that the IIC has an equatorial anisotropy and a pattern different from the OIC. The equatorial fast axis of the IIC is near the Central America and the Southeast Asia. The drastic change in the fast axis and the form of anisotropy from the IIC to the OIC may suggest a phase change of the iron or a major shift in the crystallization and deformation during the formation and growth of the inner core.

Relationship between covalence and displacive phase transition temperature in RAO{sub 4} and LiAO{sub 3} (R = rare-earth element and A = Nb and Ta)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsunekawa, S.; Fukuda, T.; Kimiyama, T.

Crystal structure analyses by TOF neutron powder diffraction are performed for R TaO{sub 4} (R = rare-earth element) and the Ta-O interatomic distances are determined. The relationship between the covalency of A-O bonds (A = Nb and Ta), which show the most shortening upon phase transition, and the transition temperature is discussed for RAO{sub 4} and LiAO{sub 3}, and the parameters of Ta-O covalence are determined.

The Day the Earth Smiled: Sneak Preview

NASA Image and Video Library

2013-07-22

In this rare image taken on July 19, 2013, the wide-angle camera on NASA's Cassini spacecraft has captured Saturn's rings and our planet Earth and its moon in the same frame. It is only one footprint in a mosaic of 33 footprints covering the entire Saturn ring system (including Saturn itself). At each footprint, images were taken in different spectral filters for a total of 323 images: some were taken for scientific purposes and some to produce a natural color mosaic. This is the only wide-angle footprint that has the Earth-moon system in it. The dark side of Saturn, its bright limb, the main rings, the F ring, and the G and E rings are clearly seen; the limb of Saturn and the F ring are overexposed. The "breaks" in the brightness of Saturn's limb are due to the shadows of the rings on the globe of Saturn, preventing sunlight from shining through the atmosphere in those regions. The E and G rings have been brightened for better visibility. Earth, which is 898 million miles (1.44 billion kilometers) away in this image, appears as a blue dot at center right; the moon can be seen as a fainter protrusion off its right side. An arrow indicates their location in the annotated version. (The two are clearly seen as separate objects in the accompanying composite image PIA14949.) The other bright dots nearby are stars. This is only the third time ever that Earth has been imaged from the outer solar system. The acquisition of this image, along with the accompanying composite narrow- and wide-angle image of Earth and the moon and the full mosaic from which both are taken, marked the first time that inhabitants of Earth knew in advance that their planet was being imaged. That opportunity allowed people around the world to join together in social events to celebrate the occasion. This view looks toward the unilluminated side of the rings from about 20 degrees below the ring plane. Images taken using red, green and blue spectral filters were combined to create this natural color

Green light in photomorphogenic development

NASA Astrophysics Data System (ADS)

Maruhnich, Stefanie Anne

Light quality, quantity, and duration provide essential environmental cues that shape plant growth and development. Over the last century, researchers have worked to discover how plants sense, integrate, and respond to red, blue, and far-red light. Green light is often considered a “benign” wavelength with little to no effect in plant development. However, sparse experiments in the literature demonstrate that green effects are often counterintuitive to normal light responses and oppose red- and blue-light-induced responses. Green light effects on plant growth and development are described here through the use of custom, tunable LED, light-emitting diode, chambers. These light sources allow for specific light qualities and quantities to be administered. The effects of green wavebands were assessed when red and blue photomorphogenic systems were active to answer the question: Are the effects of an inhibitor (green light) more evident in the presence of inducers (red and blue light)? In seedlings, supplemental green light increased hypocotyl elongation opposite to classical inhibition of hypocotyl elongation associated with growth in light and induced by red and blue wavebands. Results indicate that added green light induced a reversion of light-grown phenotypes. In mature plants, supplemental green light induced phenotypes typical of the shade-avoidance syndrome, including elongated petioles, smaller leaf areas, and leaf hyponasty. These responses are typical of lower-light conditions or far-red enriched environments. Contrary to far-red-light-induced shade-avoidance, data indicate green delays flowering. In Arabidopsis and strawberry plants, anthocyanin levels also decreased when green light was added to red and blue light treatments, which is again opposite to normal light-induced phenotypes. Photoreceptor mutants were tested and indicate green light effects in early development are cryptochromedependent. However, green-light-induced shade-avoidance responses

Heating and cooling of the earth's plasma sheet

NASA Technical Reports Server (NTRS)

Goertz, C. K.

1990-01-01

Magnetic-field models based on pressure equilibrium in the quiet magnetotail require nonadiabatic cooling of the plasma as it convects inward or a decrease of the flux tube content. Recent in situ observations of plasma density and temperature indicate that, during quiet convection, the flux tube content may actually increase. Thus the plasma must be cooled during quiet times. The earth plasma sheet is generally significantly hotter after the expansion phase of a substorm than before the plasma sheet thinning begins and cools during the recovery phase. Heating mechanisms such as reconnection, current sheet acceleration, plasma expansion, and resonant absorption of surface waves are discussed. It seems that all mechanisms are active, albeit in different regions of the plasma sheet. Near-earth tail signatures of substorms require local heating as well as a decrease of the flux tube content. It is shown that the resonant absorption of surface waves can provide both.

Building thematic and integrated services for solid Earth sciences: the EPOS integrated approach

NASA Astrophysics Data System (ADS)

Cocco, Massimo; Consortium, Epos

2016-04-01

EPOS has been designed with the vision of creating a pan-European infrastructure for solid Earth science to support a safe and sustainable society. In accordance with this scientific vision, the EPOS mission is to integrate the diverse and advanced European Research Infrastructures for solid Earth science relying on new e-science opportunities to monitor and unravel the dynamic and complex Earth System. EPOS will enable innovative multidisciplinary research for a better understanding of the Earth's physical and chemical processes that control earthquakes, volcanic eruptions, ground instability and tsunami as well as the processes driving tectonics and Earth's surface dynamics. To accomplish its mission, EPOS is engaging different stakeholders, not limited to scientists, to allow the Earth sciences to open new horizons in our understanding of the planet. EPOS also aims at contributing to prepare society for geo-hazards and to responsibly manage the exploitation of geo-resources. Through integration of data, models and facilities, EPOS will allow the Earth science community to make a step change in developing new concepts and tools for key answers to scientific and socio-economic questions concerning geo-hazards and geo-resources as well as Earth sciences applications to the environment and human welfare. A long-term integration plan is necessary to accomplish the EPOS mission. EPOS is presently in its implementation phase further extending its pan-European dimension. The EPOS Implementation Phase builds on the achievements of the successful EPOS Preparatory Phase project and consists of two key activities: the legal establishment of the EPOS-ERIC and the EPOS IP project. The EPOS implementation phase will last from 2015 to 2019. Key objectives of the project are: implementing Thematic Core Services (TCS), the domain-specific service hubs for coordinating and harmonizing national resources/plans with the European dimension of EPOS; building the Integrated Core

Building the green way.

PubMed

Lockwood, Charles

2006-06-01

Just five or six years ago, the term "green building" evoked visions of barefoot, tie-dyed, granola-munching denizens. There's been a large shift in perception. Of course, green buildings are still known for conserving natural resources by, for example, minimizing on-site grading, using alternative materials, and recycling construction waste. But people now see the financial advantages as well. Well-designed green buildings yield lower utility costs, greater employee productivity, less absenteeism, and stronger attraction and retention of workers than standard buildings do. Green materials, mechanical systems, and furnishings have become more widely available and considerably less expensive than they used to be-often cheaper than their standard counterparts. So building green is no longer a pricey experiment; just about any company can do it on a standard budget by following the ten rules outlined by the author. Reliable building-rating systems like the U.S. Green Building Council's rigorous Leadership in Energy and Environmental Design (LEED) program have done much to underscore the benefits of green construction. LEED evaluates buildings and awards points in several areas, such as water efficiency and indoor environmental quality. Other rating programs include the UK's BREEAM (Building Research Establishment's Environmental Assessment Method) and Australia's Green Star. Green construction is not simply getting more respect; it is rapidly becoming a necessity as corporations push it fully into the mainstream over the next five to ten years. In fact, the author says, the owners of standard buildings face massive obsolescence. To avoid this problem, they should carry out green renovations. Corporations no longer have an excuse for eschewing environmental and economic sustainability. They have at their disposal tools proven to lower overhead costs, improve productivity, and strengthen the bottom line.

Vegetation Greening and Climate Change Promote Multidecadal Rises of Global Land Evapotranspiration.

PubMed

Zhang, Ke; Kimball, John S; Nemani, Ramakrishna R; Running, Steven W; Hong, Yang; Gourley, Jonathan J; Yu, Zhongbo

2015-10-30

Recent studies showed that anomalous dry conditions and limited moisture supply roughly between 1998 and 2008, especially in the Southern Hemisphere, led to reduced vegetation productivity and ceased growth in land evapotranspiration (ET). However, natural variability of Earth's climate system can degrade capabilities for identifying climate trends. Here we produced a long-term (1982-2013) remote sensing based land ET record and investigated multidecadal changes in global ET and underlying causes. The ET record shows a significant upward global trend of 0.88 mm yr(-2) (P < 0.001) over the 32-year period, mainly driven by vegetation greening (0.018% per year; P < 0.001) and rising atmosphere moisture demand (0.75 mm yr(-2); P = 0.016). Our results indicate that reduced ET growth between 1998 and 2008 was an episodic phenomenon, with subsequent recovery of the ET growth rate after 2008. Terrestrial precipitation also shows a positive trend of 0.66 mm yr(-2) (P = 0.08) over the same period consistent with expected water cycle intensification, but this trend is lower than coincident increases in evaporative demand and ET, implying a possibility of cumulative water supply constraint to ET. Continuation of these trends will likely exacerbate regional drought-induced disturbances, especially during regional dry climate phases associated with strong El Niño events.

Aqueous-phase oxidation of green leaf volatiles by hydroxyl radical as a source of SOA: Product identification from methyl jasmonate and methyl salicylate oxidation

NASA Astrophysics Data System (ADS)

Hansel, Amie K.; Ehrenhauser, Franz S.; Richards-Henderson, Nicole K.; Anastasio, Cort; Valsaraj, Kalliat T.

2015-02-01

Green leaf volatiles (GLVs) are a group of biogenic volatile organic compounds (BVOCs) released into the atmosphere by vegetation. BVOCs produce secondary organic aerosol (SOA) via gas-phase reactions, but little is known of their aqueous-phase oxidation as a source of SOA. GLVs can partition into atmospheric water phases, e.g., fog, mist, dew or rain, and be oxidized by hydroxyl radicals (˙OH). These reactions in the liquid phase also lead to products that have higher molecular weights, increased polarity, and lower vapor pressures, ultimately forming SOA after evaporation of the droplet. To examine this process, we investigated the aqueous, ˙OH-mediated oxidation of methyl jasmonate (MeJa) and methyl salicylate (MeSa), two GLVs that produce aqueous-phase SOA. High performance liquid chromatography/electrospray ionization mass spectrometry (HPLC-ESI-MS) was used to monitor product formation. The oxidation products identified exhibit higher molecular mass than their parent GLV due to either dimerization or the addition of oxygen and hydroxyl functional groups. The proposed structures of potential products are based on mechanistic considerations combined with the HPLC/ESI-MS data. Based on the structures, the vapor pressure and the Henry's law constant were estimated with multiple methods (SPARC, SIMPOL, MPBPVP, Bond and Group Estimations). The estimated vapor pressures of the products identified are significantly (up to 7 orders of magnitude) lower than those of the associated parent compounds, and therefore, the GLV oxidation products may remain as SOA after evaporation of the water droplet. The contribution of the identified oxidation products to SOA formation is estimated based on measured HPLC-ESI/MS responses relative to previous aqueous SOA mass yield measurements.

77 FR 2296 - Office of Federal High-Performance Green Buildings; the Green Building Advisory Committee...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-17

... Federal High-Performance Green Buildings; the Green Building Advisory Committee; Notification of Upcoming... teleconference meetings of the Green Building Advisory Committee (the Committee). The teleconference meetings are... Federal High Performance Green Buildings, Office of Governmentwide Policy, General Services Administration...

Mass driver retrievals of earth-approaching asteroids. [earth orbit capture for mining purposes

NASA Technical Reports Server (NTRS)

Oleary, B.

1977-01-01

Mass driver tugs can be designed to move Apollo and Amor asteroids at opportunities of low velocity increment to the vicinity of the earth. The cost of transferring asteroids through a velocity interval of 3 km/sec by mass driver is about 16 cents per kilogram amortized over 10 years, about ten times less than that required to retrieve lunar resources during the early phases of a program of space manufacturing. About 22 per cent of a 200-meter diameter asteroid could be transferred to high earth orbit by an automated 100 megawatt solar-powered mass driver in a period of five years for a cost of approximately $1 billion. Estimates of the total investment of a space manufacturing program could be reduced twofold by using asteroidal instead of lunar resources; such a program could begin several years sooner with minimal concurrent development if asteroidal search programs and mass driver development are immediately accelerated.

Contributions to the Earth's obliquity rate, precession, and nutation

NASA Technical Reports Server (NTRS)

Williams, James G.

1994-01-01

The precession and nutation of the Earth's equator arise from solar, lunar, and planetary torques on the oblate Earth. The mean lunar orbit plane is nearly coincident with the ecliptic plane. A small tilt out of the ecliptic is caused by planetary perturbations and the Earth's gravitational harmonic J(sub2). These planetary perturbations on the lunar orbit result in torques on the oblate Earth which contribute to precession, obliquity rate, and nutation while the J(sub 2) perturbations contribute to precession and nutation. Small additional contributions to the secular rates arise from tidal effects and planetary torques on the Earth's bulge. The total correction to the obliquity rate is -0.024sec/century, it is an observable motion in space (the much larger conventional obliquity rate is wholly from the motion of the ecliptic, not the equator), and it is not present in the IAU-adopted expressions for the orientation of the Earth's equator. The J(sub2) effects have generally been allowed for in past nutation theories and some procession theories. For the planetary effect, the contributions to the 18.6 yr nutation are -0.03 mas (milliarcseconds) for the in-phase Delta phi plus out-of-phase contributions of 0.14 mas in Delta phi and -0.03 mas in Delta epsilon. The latter terms demonstrate that out-of-phase contributions can arise by means other than dissipation. The sum of the contributions to the precession rate is considered and the inferred value of the moment of inertia combination (C-A)/C, which is used to scale the coefficients in the nutation series, is evaluated. Using an updated value for the precession rate, the rigid body (C-A)/C = 0.003 273 763 4 which, in combination with a satellite-derived J(sub2), gives a normalized polar moment of inertia C/MR(exp2) = 0.330 700 7. The planetary contributions to the precession and obliquity rates are not constant for long times causing accelerations in both quantities. Acceleration in precession also arises from tides

A new numerical algorithm for the analytic continuation of Green`s functions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Natoli, V.D.; Cohen, M.H.; Fornberg, B.

1996-06-01

The need to calculate the spectral properties of a Hermitian operation H frequently arises in the technical sciences. A common approach to its solution involves the construction of the Green`s function operator G(z) = [z - H]{sup -1} in the complex z plane. For example, the energy spectrum and other physical properties of condensed matter systems can often be elegantly and naturally expressed in terms of the Kohn-Sham Green`s functions. However, the nonanalyticity of resolvents on the real axis makes them difficult to compute and manipulate. The Herglotz property of a Green`s function allows one to calculate it along anmore » arc with a small but finite imaginary part, i.e., G(x + iy), and then to continue it to the real axis to determine quantities of physical interest. In the past, finite-difference techniques have been used for this continuation. We present here a fundamentally new algorithm based on the fast Fourier transform which is both simpler and more effective. 14 refs., 9 figs.« less

Complete synthetic seismograms based on a spherical self-gravitating Earth model with an atmosphere-ocean-mantle-core structure

NASA Astrophysics Data System (ADS)

Wang, Rongjiang; Heimann, Sebastian; Zhang, Yong; Wang, Hansheng; Dahm, Torsten

2017-09-01

A hybrid method is proposed to calculate complete synthetic seismograms based on a spherically symmetric and self-gravitating Earth with a multilayered structure of atmosphere, ocean, mantle, liquid core and solid core. For large wavelengths, a numerical scheme is used to solve the geodynamic boundary-value problem without any approximation on the deformation and gravity coupling. With decreasing wavelength, the gravity effect on the deformation becomes negligible and the analytical propagator scheme can be used. Many useful approaches are used to overcome the numerical problems that may arise in both analytical and numerical schemes. Some of these approaches have been established in the seismological community and the others are developed for the first time. Based on the stable and efficient hybrid algorithm, an all-in-one code QSSP is implemented to cover the complete spectrum of seismological interests. The performance of the code is demonstrated by various tests including the curvature effect on teleseismic body and surface waves, the appearance of multiple reflected, teleseismic core phases, the gravity effect on long period surface waves and free oscillations, the simulation of near-field displacement seismograms with the static offset, the coupling of tsunami and infrasound waves, and free oscillations of the solid Earth, the atmosphere and the ocean. QSSP is open source software that can be used as a stand-alone FORTRAN code or may be applied in combination with a Python toolbox to calculate and handle Green's function databases for efficient coding of source inversion problems.

Phytoforensics, dendrochemistry, and phytoscreening: New green tools for delineating contaminants from past and present

USGS Publications Warehouse

Burken, J.G.; Vroblesky, D.A.; Balouet, J.-C.

2011-01-01

As plants evolved to be extremely proficient in mass transfer with their surroundings and survive as earth's dominant biomass, they also accumulate and store some contaminants from surroundings, acting as passive samplers. Novel applications and analytical methods have been utilized to gain information about a wide range of contaminants in the biosphere soil, water, and air, with information available on both past (dendrochemistry) and present (phytoscreening). Collectively these sampling approaches provide rapid, cheap, ecologically friendly, and overall "green" tools termed "Phytoforensics". ?? 2011 American Chemical Society.

Effects of dynamic long-period ocean tides on changes in Earth's rotation rate

DOE Office of Scientific and Technical Information (OSTI.GOV)