A Liquid Chromatography Detector for Transition and Rare-Earth Metal Ions Based on a Cupric Ion-Selective Electrode

DTIC Science & Technology

1981-05-01

RARE-EARTH METAL IONS BASED ON A CUPRIC ION-SELECTIVE ELECTRODE By - 4 R. CAMERON DOREY TECHNICAL REPORT FJSRL-TR-81-0005 MAY 1981 Approved for public...FORM . REPORT NUMBER 12. GOVT ACCESSION NO. 3. RECIPIENT’S CATALOG NUMBER FJSRL-TR-81-0005BO CO ENGO 4 . TITLE (and Subtitle) 5. TYPE OF REPORT & PERIOD...common anions, including halide ions, is shown, and the advantages and limitations of the system are discussed. II ’ 4 UNCLASSIFIED SECURITY

Biogenic oxygen from Earth transported to the Moon by a wind of magnetospheric ions

NASA Astrophysics Data System (ADS)

Terada, Kentaro; Yokota, Shoichiro; Saito, Yoshifumi; Kitamura, Naritoshi; Asamura, Kazushi; Nishino, Masaki N.

2017-01-01

For five days of each lunar orbit, the Moon is shielded from solar wind bombardment by the Earth's magnetosphere, which is filled with terrestrial ions. Although the possibility of the presence of terrestrial nitrogen and noble gases in lunar soil has been discussed based on their isotopic composition 1 , complicated oxygen isotope fractionation in lunar metal 2,3 (particularly the provenance of a 16O-poor component) re­mains an enigma 4,5 . Here, we report observations from the Japanese spacecraft Kaguya of significant numbers of 1-10 keV O+ ions, seen only when the Moon was in the Earth's plasma sheet. Considering the penetration depth into metal of O+ ions with such energy, and the 16O-poor mass-independent fractionation of the Earth's upper atmosphere 6 , we conclude that biogenic terrestrial oxygen has been transported to the Moon by the Earth wind (at least 2.6 × 104 ions cm-2 s-1) and implanted into the surface of the lunar regolith, at around tens of nanometres in depth 3,4 . We suggest the possibility that the Earth's atmosphere of billions of years ago may be preserved on the present-day lunar surface.

Lithium-Ion Batteries Being Evaluated for Low-Earth-Orbit Applications

NASA Technical Reports Server (NTRS)

McKissock, Barbara I.

2005-01-01

The performance characteristics and long-term cycle life of aerospace lithium-ion (Li-ion) batteries in low-Earth-orbit applications are being investigated. A statistically designed test using Li-ion cells from various manufacturers began in September 2004 to study the effects of temperature, end-of-charge voltage, and depth-of-discharge operating conditions on the cycle life and performance of these cells. Performance degradation with cycling is being evaluated, and performance characteristics and failure modes are being modeled statistically. As technology improvements are incorporated into aerospace Li-ion cells, these new designs can be added to the test to evaluate the effect of the design changes on performance and life. Cells from Lithion and Saft have achieved over 2000 cycles under 10 different test condition combinations and are being evaluated. Cells from Mine Safety Appliances (MSA) and modules made up of commercial-off-the-shelf 18650 Li-ion cells connected in series/parallel combinations are scheduled to be added in the summer of 2005. The test conditions include temperatures of 10, 20, and 30 C, end-of-charge voltages of 3.85, 3.95, and 4.05 V, and depth-of-discharges from 20 to 40 percent. The low-Earth-orbit regime consists of a 55 min charge, at a constant-current rate that is 110 percent of the current required to fully recharge the cells in 55 min until the charge voltage limit is reached, and then at a constant voltage for the remaining charge time. Cells are discharged for 35 min at the current required for their particular depth-of-discharge condition. Cells are being evaluated in four-cell series strings with charge voltage limits being applied to individual cells by the use of charge-control units designed and produced at the NASA Glenn Research Center. These charge-control units clamp the individual cell voltages as each cell reaches its end-of-charge voltage limit, and they bypass the excess current from that cell, while allowing the full

Investigation of the Transport of Solar Ions Through the Earth's Magnetosphere

NASA Technical Reports Server (NTRS)

Lennartsson, O. W.; Evans, David (Technical Monitor)

2000-01-01

The objective of this study has been to infer, by statistical means, the most probable mode of entry of solar wind plasma into Earth's magnetotail, using a particular set of archived data from the Lockheed Plasma Composition Experiment on the International Sun-Earth Explorer One (ISEE-1) satellite, jointly sponsored by the National Aeronautics and Space Administration (NASA) and the European Space Agency (ESA) in the 1970's and 80's. Despite their considerable age, the Lockheed ISEE-1 data are still, at the time of this report, the only substantial ion composition data in the sub-keV to keV energy range available from the magnetotail beyond 9 R(sub E), because of various technical problems with ion mass spectrometers on later missions, and are therefore a unique source of information about the mixing of solar and terrestrial origin plasmas in the tail, within the ISEE-1 apogee of almost 23 R(sub E). The entire set of archived data used in this study, covering the 4.5 years of operation of the instrument and comprising not only tail measurements but also data from the inner magnetosphere as well as data from outside the magnetopause, is now available to the public via the WorldWideWeb at the address: http://cis.spasci.com/ISEE_ions The fundamental assumption of this and other studies of magnetosphere ion composition is that He++ and O+ ions are virtually certain "tags" of solar and terrestrial origins, respectively. This is an assumption with strong theoretical basis and it is corroborated by observational evidence, including the often substantial differences between the velocity distribution functions of those two species. The H+ ions can have a dual origin, in principle, but the close resemblance in the ISEE-1 data between the dynamics of H+ and He++ ions indicates a predominantly solar origin of the H+ ions in the tail, at least. By the same token, the usually minor He+ ions are probably almost entirely of terrestrial origin, because of their similarity to the O

Origins of Energetic Ions in the Earth's Magnetosheath

NASA Technical Reports Server (NTRS)

Fuselter, S. A.; Shelley, E. G.; Klumpar, D. M.

1992-01-01

The analysis and interpretation of the combined scientific data from the Hot Plasma Composition Experiment (HPCE) and the Charge Energy Mass (CHEM) spectrometer on the Active Mesospheric Particle Tracer Experiment (AMPTE) Charge Composition Explorer (CCE) spacecraft are discussed. These combined data sets have and will be used to survey the energetic ion environment in the Earth's magnetosheath to determine the origins and relative strengths of the energetic ion populations found there. A computer code was developed to analyze and interpret the data sets. The focus of the first year was on the determination of the contribution of leaked magnetospheric protons to the total energetic proton population. Emphasis was placed on intervals when the AMPTE spacecraft was in the plasma depletion layer because it was argued that in this region, only the leaked population contributes to the energetic ion population. Manipulation of the CHEM data and comparison of the CHEM and HPCE data over their common energy range near the magnetopause also contributed directly to a second study of that region.

The Transport of Solar Ions Through the Earth's Magnetosphere

NASA Technical Reports Server (NTRS)

Lennartsson, O. W.

1999-01-01

This report covers the initial phase of an investigation that was originally selected by NASA Headquarters for funding by a grant but was later transferred to NASA GSFC for continued funding under a new and separate contract. The principal objective of the investigation, led by Dr. O.W. Lennartsson, is to extract information about the solar origin plasma in Earth's magnetosphere, specifically about the entry and transport of this plasma, using energetic (10 eV/e to 18 keV/e) ion composition data from the Lockheed Plasma Composition Experiment on the NASA/ESA International Sun-Earth Explorer One (ISEE 1) satellite. These data were acquired many years ago, from November 1977 through March of 1982, but, because of subsequent failures of similar experiments on several other spacecraft, they are still the only substantial ion composition data available from Earth's magnetotail, beyond 10 R(sub E), in the critically important sub-kev to keV energy range. All of the Lockheed data now exist in a compacted scientific format, suitable for large-scale statistical investigations, which has been archived both at Lockheed Martin in Palo Alto and at the National Space Science Data Center (NSSDC) in Greenbelt. The completion of the archiving, by processing the remaining half of the data, was made possible by separate funding through a temporary NASA program for data restoration and was given priority over the data analysis by a no-cost extension of the subject grant. By chance, the period of performance coincided with an international study of source and loss processes of magnetospheric plasma, sponsored by the International Space Science Institute (ISSI) in Bern, Switzerland, for which Dr. Lennartsson was invited to serve as one of 12 co-chairs. This study meshed well with the continued analysis of the NASA/Lockheed ISEE ion composition data and provided a natural forum for a broader discussion of the results from this unique experiment. What follows is arranged, for the most

MAVEN-Measured Meteoritic Ions on Mars - Tracers of Lower Ionosphere Processes With and Without Analogues On Earth

NASA Astrophysics Data System (ADS)

Benna, M.; Grebowsky, J. M.; Collinson, G.; Plane, J. M. C.; Mitchell, D.; Srivastava, N.

2017-12-01

MAVEN observations of meteoritic metal ion populations during "deep dip" campaigns at Mars have revealed unique non-Earth like behavior that are not yet understood. These deep dip campaigns (6 so far) consisted each of more than a score of repeated orbits through the Martian molecular-ion-dominated lower ionosphere, whose terrestrial parallel (Earth's E-region) has been rather sparcely surveyed in situ by sounding rockets. In regions of weak Mars magnetic fields, MAVEN found ordered exponentially decreasing metal ion concentrations above the altitude of peak meteor ablation. Such an ordered trend has never been observed on Earth. Isolated anomalous high-altitude layers in the metal ion are also encountered, typically on deep dip campaigns in the southern hemisphere where large localized surface remanent magnetic fields prevail. The source of these anomalous layers is not yet evident, although the occurrences of some high-altitude metal ion enhancements were in regions with measured perturbed magnetic fields, indicative of localized electrical currents. Further investigation shows that those currents are also sometimes associated with superthermal/energetic electron bursts offering evidence that that impact ionization of neutral metal populations persisting at high altitudes are the source of metal ion enhancement - a rather difficult assumption to accept far above the ablation region where the metal neutrals are deposited. The relationship of the anomalous layers to the coincident electron populations as well as to the orientation of the magnetic fields which can play a role in the neutral wind generated ion convergences as on Earth is investigated.

Indirect ultraviolet detection of alkaline earth metal ions using an imidazolium ionic liquid as an ultraviolet absorption reagent in ion chromatography.

PubMed

Liu, Yong-Qiang; Yu, Hong

2017-04-01

A convenient and versatile method was developed for the separation and detection of alkaline earth metal ions by ion chromatography with indirect UV detection. The chromatographic separation of Mg 2+ , Ca 2+ , and Sr 2+ was performed on a carboxylic acid base cation exchange column using imidazolium ionic liquid/acid as the mobile phase, in which the imidazolium ionic liquid acted as an UV-absorption reagent. The effects of imidazolium ionic liquids, detection wavelength, acids in the mobile phase, and column temperature on the retention of Mg 2+ , Ca 2+ , and Sr 2+ were investigated. The main factors influencing the separation and detection were the background UV absorption reagent and the concentration of hydrogen ion in ion chromatography with indirect UV detection. The successful separation and detection of Mg 2+ , Ca 2+ , and Sr 2+ within 14 min were achieved using the selected chromatographic conditions, and the detection limits (S/N = 3) were 0.06, 0.12, and 0.23 mg/L, respectively. A new separation and detection method of alkaline earth metal ions by ion chromatography with indirect UV detection was developed, and the application range of ionic liquids was expanded. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mars Ionosphere Meteoritic Ion Distributions -A Mixture of Earth and Venus Characteristics

NASA Astrophysics Data System (ADS)

Grebowsky, J. M.; Benna, M.; Collinson, G.; Mahaffy, P. R.

2016-12-01

The Neutral Gas and Ion Mass Spectrometer on the Mars Atmosphere and Volatile Evolution mission repeatedly observes metallic ions on MAVEN's traversals below 155 kilometers during special deep-dipping orbital campaigns. On such orbits which sample the topside of the main metal ion peak in the ablation region, three of the major metal ions seen at Earth (Na+, Mg+ and Fe+) are always detected. The relative composition of these species varies with the planetary locations of the deep-dip orbits as does the complexity of the altitude profiles of the metal ion concentrations. Quite frequently the decrease of the concentrations with altitude (observed on inbound or outbound legs of the orbit relative to periapsis) tracks the atmospheric density scale height, but only in the average sense. The individual concentration altitude profiles themselves typically have large coherent oscillations indicative of atmospheric gravity wave effects. The monotonically decreasing altitude trends are most characteristic of observations in the northern hemisphere, but there are orbits that encounter large concentration disturbances in the metal ion profiles. The latter are more prevalent in the southern hemisphere. The major background environment differences between the northern and southern hemispheres are the existence of large remanent magnetic fields in the southern hemisphere atmosphere, but not the north. It appears that there are two types of metal ion distributions. One type is associated with vertical diffusion profiles from the main metal ion peak arising in weak or no-magnetic field regions (like Venus). The other type exhibits the complex disturbances. The latter occur in regions where transport of the metal ions is controlled by the magnetic fields, through externally imposed electric fields and/or neutral wind-driven electrodynamic processes as at Earth. A comparison is made between the onset of the disturbed metal ion profiles with the ambient magnetic fields to isolate the

Adsorption of rare earth ions onto the cell walls of wild-type and lipoteichoic acid-defective strains of Bacillus subtilis.

PubMed

Moriwaki, Hiroshi; Koide, Remi; Yoshikawa, Ritsuko; Warabino, Yuya; Yamamoto, Hiroki

2013-04-01

The aim of this study is to investigate the potential of cell walls of wild-type and lipoteichoic acid-defective strains of Bacillus subtilis 168 to adsorb rare earth ions. Freeze-dried cell powders prepared from both strains were used for the evaluation of adsorption ability for the rare earth ions, namely, La(III), Eu(III), and Tm(III). The rare earth ions were efficiently adsorbed onto powders of both wild-type strain (WT powder) and lipoteichoic acid-defective strain (∆LTA powder) at pH 3. The maximum adsorption capacities for Tm(III) by WT and ∆LTA powders were 43 and 37 mg g(-1), respectively. Removal (in percent) of Tm(III), La(III), and Eu(III) from aqueous solution by WT powder was greater than by ∆LTA powder. These results indicate that rare earth ions are adsorbed to functional groups, such as phosphate and carboxyl groups, of lipoteichoic acid. We observed coagulated ∆LTA powder in the removal of rare earth ions (1-20 mg L(-1)) from aqueous solution. In contrast, sedimentation of WT powder did not occur under the same conditions. This unique feature of ∆LTA powder may be caused by the difference of the distribution between lipoteichoic acid and wall teichoic acid. It appears that ∆LTA powder is useful for removal of rare earth ions by adsorption, because aggregation allows for rapid separation of the adsorbent by filtration.

Short wavelength ion waves upstream of the earth's bow shock

NASA Technical Reports Server (NTRS)

Fuselier, S. A.; Gurnett, D. A.

1984-01-01

The identification and explanation of short wavelength antenna interference effects observed in spacecraft plasma wave data have provided an important new method of determining limits on the wavelength, direction of propagation, and Doppler shift of short wavelength electrostatic waves. Using the ISEE-1 wideband electric field data, antenna interference effects have been identified in the ion waves upstream of the earth's bow shock. This identification implies that wavelengths of the upstream ion waves are shorter than the antenna length. The interference effects also provide new measurements of the direction of propagation of the ion waves. The new measurements show that the wave vectors of the ion waves are not parallel to the interplanetary magnetic field (IMF) as previously reported. The direction of propagation does not appear to be controlled by the IMF. In addition, analysis of the Doppler shift of the short wavelength ion waves has provided a measurement of the dispersion relation. The upper limit of the rest frame frequency was found to be on the order of the ion plasma frequency. At this frequency, the wavelength is on the order of a few times the Debye length. The results of this study now provide strong evidence that the ion waves in the upstream region are Doppler-shifted ion acoustic waves. Previously announced in STAR as N83-36328

Ab initio calculations on the positive ions of the alkaline-earth oxides, fluorides, and hydroxides

NASA Technical Reports Server (NTRS)

Partridge, H.; Langhoff, S. R.; Bauschlicher, C. W., Jr.

1986-01-01

Theoretical dissociation energies are presented for the alkaline-earth fluoride, hydroxide, and oxide positive ions that are considered to be accurate to 0.1-0.2 eV. The r(e) for the positive ions are found to be consistently shorter than the corresponding neutrals by 0.07 + or -0.02 A. The bonding in the ground states is demonstrated to be of predominantly M + 2 X - character. The a 3 Pi and A 1 Pi are found to lie considerably above the X 1 Sigma + ground states of the alkaline-earth fluoride and hydroxide positive ions. The overall agreement of the theoretical ionization potentials with the available experimental appearance potentials is satisfactory; these values should represent the most accurate and consistent set available.

A rare-earth-magnet ion trap for confining low-Z, bare nuclei

NASA Astrophysics Data System (ADS)

Brewer, Samuel M.; Tan, Joseph N.

2009-05-01

Simplifications in the theory for Rydberg states of hydrogenlike ions allow a substantial improvement in the accuracy of predicted levels, which can yield information on the values of fundamental constants and test theory if they can be compared with precision frequency measurements.[1] We consider the trapping of bare nuclei (fully-stripped) to be used in making Rydberg states of one-electron ions with atomic number 1< Z < 11. Numerical simulation is used here to study ion confinement in a compact, Penning-style ion trap consisting of electrodes integrated with rare-earth permanent magnets, and to model the capture of charge-state-selected ions extracted from an electron beam ion trap (EBIT). An experimental apparatus adapted to the NIST EBIT will also be discussed. Reference: [1] U.D. Jentschura, P.J. Mohr, J.N. Tan, and B.J. Wundt, ``Fundamental constants and tests of theory in Rydberg states of hydrogenlike ions,'' Phys. Rev. Lett. 100, 160404 (2008).

Comparative study of ion cyclotron waves at Mars, Venus and Earth

NASA Astrophysics Data System (ADS)

Wei, H. Y.; Russell, C. T.; Zhang, T. L.; Blanco-Cano, X.

2011-08-01

Ion cyclotron waves are generated in the solar wind when it picks up freshly ionized planetary exospheric ions. These waves grow from the free energy of the highly anisotropic distribution of fresh pickup ions, and are observed in the spacecraft frame with left-handed polarization and a wave frequency near the ion's gyrofrequency. At Mars and Venus and in the Earth's polar cusp, the solar wind directly interacts with the planetary exospheres. Ion cyclotron waves with many similar properties are observed in these diverse plasma environments. The ion cyclotron waves at Mars indicate its hydrogen exosphere to be extensive and asymmetric in the direction of the interplanetary electric field. The production of fast neutrals plays an important role in forming an extended exosphere in the shape and size observed. At Venus, the region of exospheric proton cyclotron wave production may be restricted to the magnetosheath. The waves observed in the solar wind at Venus appear to be largely produced by the solar-wind-Venus interaction, with some waves at higher frequencies formed near the Sun and carried outward by the solar wind to Venus. These waves have some similarity to the expected properties of exospherically produced proton pickup waves but are characterized by magnetic connection to the bow shock or by a lack of correlation with local solar wind properties respectively. Any confusion of solar derived waves with exospherically derived ion pickup waves is not an issue at Mars because the solar-produced waves are generally at much higher frequencies than the local pickup waves and the solar waves should be mostly absorbed when convected to Mars distance as the proton cyclotron frequency in the plasma frame approaches the frequency of the solar-produced waves. In the Earth's polar cusp, the wave properties of ion cyclotron waves are quite variable. Spatial gradients in the magnetic field may cause this variation as the background field changes between the regions in which

Nucleation-dependant chemical bonding paradigm: the effect of rare earth ions on the nucleation of urea in aqueous solution.

PubMed

Chen, Xiaoyan; Sun, Congting; Wu, Sixin; Xue, Dongfeng

2017-03-29

Rare earth ions can be used to construct a variety of novel structures and are favorable to chemical bonding regulation and design. In this study, the chemical bonding paradigm between rare earth ions (Ln 3+ ) and urea molecules in an aqueous solution can be tracked by the evolution of C[double bond, length as m-dash]O, NH 2 , and CN vibration bands during the urea nucleation stage. Rare earth ions such as La 3+ , Gd 3+ , and Lu 3+ can manipulate the nucleation time of urea via regulating the nucleation-dependant N-C[double bond, length as m-dash]OH-N hydrogen-bonding between urea molecules. Two types of chemical bondings between Ln 3+ and urea molecules have been confirmed, which are Ln 3+ O[double bond, length as m-dash]C-N and Ln 3+ NH 2 -C. Compared with Ln 3+ NH 2 -C, Ln 3+ prefers to coordinate with the O[double bond, length as m-dash]C bond in urea. With a higher concentration of rare earth ions in the solution, some N-C[double bond, length as m-dash]OH-N hydrogen bonds are broken as a consequence of the incorporation of Ln 3+ into the lattice, resulting in the decreased symmetry of local urea molecules in the crystalline nuclei and the consequent Ln 3+ concentration-dependent nucleation time of urea. Moreover, using the ionic electronegativity scale of Ln 3+ , the different effects of La 3+ , Gd 3+ , and Lu 3+ on urea nucleation can be further distinguished. The present study provides basic data for unrevealing the chemical bonding regulation role of rare earth ions in the formation of hydrogen bonded materials, which may give insight into the design and fabrication of novel materials utilizing rare earth ions to adjust the chemical bonding process.

GYROSURFING ACCELERATION OF IONS IN FRONT OF EARTH's QUASI-PARALLEL BOW SHOCK

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kis, Arpad; Lemperger, Istvan; Wesztergom, Viktor

2013-07-01

It is well known that shocks in space plasmas can accelerate particles to high energies. However, many details of the shock acceleration mechanism are still unknown. A critical element of shock acceleration is the injection problem; i.e., the presence of the so called seed particle population that is needed for the acceleration to work efficiently. In our case study, we present for the first time observational evidence of gyroresonant surfing acceleration in front of Earth's quasi-parallel bow shock resulting in the appearance of the long-suspected seed particle population. For our analysis, we use simultaneous multi-spacecraft measurements provided by the Clustermore » spacecraft ion (CIS), magnetic (FGM), and electric field and wave instrument (EFW) during a time period of large inter-spacecraft separation distance. The spacecraft were moving toward the bow shock and were situated in the foreshock region. The results show that the gyroresonance surfing acceleration takes place as a consequence of interaction between circularly polarized monochromatic (or quasi-monochromatic) transversal electromagnetic plasma waves and short large amplitude magnetic structures (SLAMSs). The magnetic mirror force of the SLAMS provides the resonant conditions for the ions trapped by the waves and results in the acceleration of ions. Since wave packets with circular polarization and different kinds of magnetic structures are very commonly observed in front of Earth's quasi-parallel bow shock, the gyroresonant surfing acceleration proves to be an important particle injection mechanism. We also show that seed ions are accelerated directly from the solar wind ion population.« less

Electron magnetic reconnection without ion coupling in Earth's turbulent magnetosheath

NASA Astrophysics Data System (ADS)

Phan, T. D.; Eastwood, J. P.; Shay, M. A.; Drake, J. F.; Sonnerup, B. U. Ö.; Fujimoto, M.; Cassak, P. A.; Øieroset, M.; Burch, J. L.; Torbert, R. B.; Rager, A. C.; Dorelli, J. C.; Gershman, D. J.; Pollock, C.; Pyakurel, P. S.; Haggerty, C. C.; Khotyaintsev, Y.; Lavraud, B.; Saito, Y.; Oka, M.; Ergun, R. E.; Retino, A.; Le Contel, O.; Argall, M. R.; Giles, B. L.; Moore, T. E.; Wilder, F. D.; Strangeway, R. J.; Russell, C. T.; Lindqvist, P. A.; Magnes, W.

2018-05-01

Magnetic reconnection in current sheets is a magnetic-to-particle energy conversion process that is fundamental to many space and laboratory plasma systems. In the standard model of reconnection, this process occurs in a minuscule electron-scale diffusion region1,2. On larger scales, ions couple to the newly reconnected magnetic-field lines and are ejected away from the diffusion region in the form of bi-directional ion jets at the ion Alfvén speed3-5. Much of the energy conversion occurs in spatially extended ion exhausts downstream of the diffusion region6. In turbulent plasmas, which contain a large number of small-scale current sheets, reconnection has long been suggested to have a major role in the dissipation of turbulent energy at kinetic scales7-11. However, evidence for reconnection plasma jetting in small-scale turbulent plasmas has so far been lacking. Here we report observations made in Earth's turbulent magnetosheath region (downstream of the bow shock) of an electron-scale current sheet in which diverging bi-directional super-ion-Alfvénic electron jets, parallel electric fields and enhanced magnetic-to-particle energy conversion were detected. Contrary to the standard model of reconnection, the thin reconnecting current sheet was not embedded in a wider ion-scale current layer and no ion jets were detected. Observations of this and other similar, but unidirectional, electron jet events without signatures of ion reconnection reveal a form of reconnection that can drive turbulent energy transfer and dissipation in electron-scale current sheets without ion coupling.

Electron magnetic reconnection without ion coupling in Earth's turbulent magnetosheath.

PubMed

Phan, T D; Eastwood, J P; Shay, M A; Drake, J F; Sonnerup, B U Ö; Fujimoto, M; Cassak, P A; Øieroset, M; Burch, J L; Torbert, R B; Rager, A C; Dorelli, J C; Gershman, D J; Pollock, C; Pyakurel, P S; Haggerty, C C; Khotyaintsev, Y; Lavraud, B; Saito, Y; Oka, M; Ergun, R E; Retino, A; Le Contel, O; Argall, M R; Giles, B L; Moore, T E; Wilder, F D; Strangeway, R J; Russell, C T; Lindqvist, P A; Magnes, W

2018-05-01

Magnetic reconnection in current sheets is a magnetic-to-particle energy conversion process that is fundamental to many space and laboratory plasma systems. In the standard model of reconnection, this process occurs in a minuscule electron-scale diffusion region 1,2 . On larger scales, ions couple to the newly reconnected magnetic-field lines and are ejected away from the diffusion region in the form of bi-directional ion jets at the ion Alfvén speed 3-5 . Much of the energy conversion occurs in spatially extended ion exhausts downstream of the diffusion region 6 . In turbulent plasmas, which contain a large number of small-scale current sheets, reconnection has long been suggested to have a major role in the dissipation of turbulent energy at kinetic scales 7-11 . However, evidence for reconnection plasma jetting in small-scale turbulent plasmas has so far been lacking. Here we report observations made in Earth's turbulent magnetosheath region (downstream of the bow shock) of an electron-scale current sheet in which diverging bi-directional super-ion-Alfvénic electron jets, parallel electric fields and enhanced magnetic-to-particle energy conversion were detected. Contrary to the standard model of reconnection, the thin reconnecting current sheet was not embedded in a wider ion-scale current layer and no ion jets were detected. Observations of this and other similar, but unidirectional, electron jet events without signatures of ion reconnection reveal a form of reconnection that can drive turbulent energy transfer and dissipation in electron-scale current sheets without ion coupling.

First simultaneous detection of terrestrial ionospheric molecular ions in the Earth's inner magnetosphere and at the Moon

NASA Astrophysics Data System (ADS)

Dandouras, I.; Poppe, A. R.; Fillingim, M. O.; Kistler, L. M.; Mouikis, C. G.; Rème, H.

2017-09-01

First coordinated observation of escaping heavy molecular ions in the Earth's inner magnetosphere and at the Moon. Quantifying the underlying escape mechanisms is important in order to understand the long-term (billion years scale) evolution of the atmospheric composition, and in particular the evolution of the N/O ratio, which is essential for habitability. Terrestrial heavy ions, transported to the Moon, suggest also that the Earth's atmosphere of billions of years ago may be preserved on the present-day lunar regolith.

Source Distributions of Substorm Ions Observed in the Near-Earth Magnetotail

NASA Technical Reports Server (NTRS)

Ashour-Abdalla, M.; El-Alaoui, M.; Peroomian, V.; Walker, R. J.; Raeder, J.; Frank, L. A.; Paterson, W. R.

1999-01-01

This study employs Geotail plasma observations and numerical modeling to determine sources of the ions observed in the near-Earth magnetotail near midnight during a substorm. The growth phase has the low-latitude boundary layer as its most important source of ions at Geotail, but during the expansion phase the plasma mantle is dominant. The mantle distribution shows evidence of two distinct entry mechanisms: entry through a high latitude reconnection region resulting in an accelerated component, and entry through open field lines traditionally identified with the mantle source. The two entry mechanisms are separated in time, with the high-latitude reconnection region disappearing prior to substorm onset.

Distribution coefficients of rare earth ions in cubic zirconium dioxide

NASA Astrophysics Data System (ADS)

Romer, H.; Luther, K.-D.; Assmus, W.

1994-08-01

Cubic zirconium dioxide crystals are grown with the skull melting technique. The effective distribution coefficients for Nd(exp 3+), Sm(exp 3+) and Er(sup 3+) as dopants are determined experimentally as a function of the crystal growth velocity. With the Burton-Prim-Slichter theory, the equilibrium distribution coefficients can be calculated. The distribution coefficients of all other trivalent rare earth ions can be estimated by applying the correlation towards the ionic radii.

Energies of rare-earth ion states relative to host bands in optical materials from electron photoemission spectroscopy

NASA Astrophysics Data System (ADS)

Thiel, Charles Warren

There are a vast number of applications for rare-earth-activated materials and much of today's cutting-edge optical technology and emerging innovations are enabled by their unique properties. In many of these applications, interactions between the rare-earth ion and the host material's electronic states can enhance or inhibit performance and provide mechanisms for manipulating the optical properties. Continued advances in these technologies require knowledge of the relative energies of rare-earth and crystal band states so that properties of available materials may be fully understood and new materials may be logically developed. Conventional and resonant electron photoemission techniques were used to measure 4f electron and valence band binding energies in important optical materials, including YAG, YAlO3, and LiYF4. The photoemission spectra were theoretically modeled and analyzed to accurately determine relative energies. By combining these energies with ultraviolet spectroscopy, binding energies of excited 4fN-15d and 4fN+1 states were determined. While the 4fN ground-state energies vary considerably between different trivalent ions and lie near or below the top of the valence band in optical materials, the lowest 4f N-15d states have similar energies and are near the bottom of the conduction band. As an example for YAG, the Tb3+ 4f N ground state is in the band gap at 0.7 eV above the valence band while the Lu3+ ground state is 4.7 eV below the valence band maximum; however, the lowest 4fN-15d states are 2.2 eV below the conduction band for both ions. We found that a simple model accurately describes the binding energies of the 4fN, 4fN-1 5d, and 4fN+1 states. The model's success across the entire rare-earth series indicates that measurements on two different ions in a host are sufficient to predict the energies of all rare-earth ions in that host. This information provides new insight into electron transfer transitions, luminescence quenching, and valence

Electron traps in Gd3Ga3Al2O12:Ce garnets doped with rare-earth ions

NASA Astrophysics Data System (ADS)

Khanin, V. M.; Rodnyi, P. A.; Wieczorek, H.; Ronda, C. R.

2017-05-01

The curves of thermally stimulated luminescence of Gd3Ga3Al2O12:Ce3+ ceramics (a nominally pure sample and samples doped with rare-earth ions) are measured in the temperature range of 80-550 K. The depth and the frequency factor of electron traps established by Eu and Yb impurities are determined. An energy-level diagram of rare-earth ions in the bandgap of Gd3Ga3Al2O12 is presented.

Performance and Comparison of Lithium-Ion Batteries Under Low-Earth-Orbit Mission Profiles

NASA Technical Reports Server (NTRS)

Reid, Concha M.; Smart, Marshall C.; Bugga, Ratnakumar V.; Manzo, Michelle A.; Miller, Thomas B.; Gitzendanner, Rob

2007-01-01

The performance of two 28 V, 25 Ah lithium-ion batteries is being evaluated under low-Earth-orbit mission profiles for satellite and orbiter applications. The batteries are undergoing life testing and have achieved over 12,000 cycles to 40 percent depth-of-discharge.

A study of the formation and dynamics of the Earth's plasma sheet using ion composition data

NASA Technical Reports Server (NTRS)

Lennartsson, O. W.

1994-01-01

Over two years of data from the Lockheed Plasma Composition Experiment on the ISEE 1 spacecraft, covering ion energies between 100 eV/e and about 16 keV/e, have been analyzed in an attempt to extract new information about three geophysical issues: (1) solar wind penetration of the Earth's magnetic tail; (2) relationship between plasma sheet and tail lobe ion composition; and (3) possible effects of heavy terrestrial ions on plasma sheet stability.

Recent Advances of Rare-Earth Ion Doped Luminescent Nanomaterials in Perovskite Solar Cells.

PubMed

Qiao, Yu; Li, Shuhan; Liu, Wenhui; Ran, Meiqing; Lu, Haifei; Yang, Yingping

2018-01-15

Organic-inorganic lead halide based perovskite solar cells have received broad interest due to their merits of low fabrication cost, a low temperature solution process, and high energy conversion efficiencies. Rare-earth (RE) ion doped nanomaterials can be used in perovskite solar cells to expand the range of absorption spectra and improve the stability due to its upconversion and downconversion effect. This article reviews recent progress in using RE-ion-doped nanomaterials in mesoporous electrodes, perovskite active layers, and as an external function layer of perovskite solar cells. Finally, we discuss the challenges facing the effective use of RE-ion-doped nanomaterials in perovskite solar cells and present some prospects for future research.

Recent Advances of Rare-Earth Ion Doped Luminescent Nanomaterials in Perovskite Solar Cells

PubMed Central

Qiao, Yu; Li, Shuhan; Liu, Wenhui; Ran, Meiqing; Lu, Haifei

2018-01-01

Organic-inorganic lead halide based perovskite solar cells have received broad interest due to their merits of low fabrication cost, a low temperature solution process, and high energy conversion efficiencies. Rare-earth (RE) ion doped nanomaterials can be used in perovskite solar cells to expand the range of absorption spectra and improve the stability due to its upconversion and downconversion effect. This article reviews recent progress in using RE-ion-doped nanomaterials in mesoporous electrodes, perovskite active layers, and as an external function layer of perovskite solar cells. Finally, we discuss the challenges facing the effective use of RE-ion-doped nanomaterials in perovskite solar cells and present some prospects for future research. PMID:29342950

Venus, Earth, Mars: Comparative ion escape caused by the interaction with the solar wind

NASA Astrophysics Data System (ADS)

Barabash, Stas

For the solar system planets the non-thermal atmospheric escape exceeds by far the Jean escape for particles heavier than helium. In this talk we consider only ion escape and compare the total ion escape rates for Venus, Earth, and Mars caused by the interaction with the solar wind. We review the most recent data on the escape rates based on measurements from Mars Express, Venus Express, and Cluster. The comparison of the available numbers show that despite large differences in the atmospheric masses between these three planets (a factor of 100 -200), different types of the interactions with the solar wind (magnetized and non-magnetized obstacles), the escape rates for Mars, Venus, and the Earth are within the range 1024 - 1025 s-1 . Surprisingly, the expected shielding of the Earth atmosphere by the intrinsic magnetic field is not as efficient as one may think. The reason for this is the non-thermal escape caused by the solar wind interaction is a energy -limited process. Indeed, normalizing the escape rates to the planet-dependent escape energy and power available in the solar wind results in the normalized escape rates deferring only on a factor between three planets. The larger Earth's magnetosphere intercepts and tunnels down to the ionosphere more energy from the solar wind than more compact interaction regions of non-magnetized planets.

Enrichment of rare earth metal ions by the highly selective adsorption of phytate intercalated layered double hydroxide.

PubMed

Jin, Cheng; Liu, Huimin; Kong, Xianggui; Yan, Hong; Lei, Xiaodong

2018-02-27

Phytate intercalated MgAl layered double hydroxide (MgAl-LDH) was prepared by an anion exchange method with the precursor NO 3 - containing MgAl-LDH. The final as-synthesized product [Mg 0.69 Al 0.31 (OH) 2 ] (phytateNa 6 ) 0.05 (NO 3 ) 0.01 ·mH 2 O (phytate-LDH) has highly selective adsorption ability for some metal ions and can be used to enrich rare earth metal ions in mixed solution, such as Pr 3+ and Ce 3+ from a mixed solution of them with Pb 2+ and Co 2+ . At first, phytate-LDH has good adsorption performance for these ions in single metal ion solutions. At low concentration (below 10 mg L -1 ), all the capture rates of the four metal ions were more than 97%, for highly toxic Pb 2+ it was even up to nearly 100%, and a high capture rate (99.87%) was maintained for Pb 2+ at a high concentration (100 mg L -1 ). When all the four metal ions are co-existing in aqueous solution, the selectivity order is Pb 2+ ≫ Pr 3+ ≈ Ce 3+ > Co 2+ . In a solution containing mixtures of the three metal ions of Pr 3+ , Ce 3+ , and Co 2+ , the selectivity order is Pr 3+ ≈ Ce 3+ ≫ Co 2+ , and in a solution containing mixtures of Pr 3+ with Co 2+ and Ce 3+ with Co 2+ , the selectivity orders are Pr 3+ ≫ Co 2+ and Ce 3+ ≫ Co 2+ , respectively. The high selectivity and adsorption capacities for Pb 2+ , Co 2+ , Pr 3+ , and Ce 3+ result in the efficient removal of Pb 2+ and enrichment of the rare earth metal ions Pr 3+ and Ce 3+ by phytate-LDH. Based on the elemental analysis, it is found that the difference of the adsorption capacities is mainly due to the different coordination number of them with phytate-LDH. With molecular simulation, we believe that the adsorption selectivity is due to the difference of the binding energy between the metal ion and phytate-LDH. Therefore, the phytate-LDH is promising for the enrichment and/or purification of the rare earth metal ions and removal of toxic metal ions from waste water.

Source of seed fluctuations for electromagnetic ion cyclotron waves in Earth's magnetosphere

NASA Astrophysics Data System (ADS)

Gamayunov, K. V.; Engebretson, M. J.; Zhang, M.; Rassoul, H. K.

2015-06-01

We consider a nonlinear wave energy cascade from the low frequency range into the higher frequency domain of electromagnetic ion cyclotron (EMIC) wave generation as a possible source of seed fluctuations for EMIC wave growth due to the ion cyclotron instability in Earth's magnetosphere. The presented theoretical analysis shows that energy cascade from the Pc 4-5 frequency range (2-22 mHz) into the range of Pc 1-2 pulsations (0.1-5 Hz), i.e. into the frequency range of EMIC waves, is able to supply the needed level of seed fluctuations that guarantees growth of EMIC waves up to the observable level during one pass through the near equatorial region where the ion cyclotron instability takes place. We also analyze the magnetic field data from the Polar and Van Allen Probes spacecraft to test the suggested nonlinear mechanism. In this initial study we restrict our analysis to magnetic fluctuation spectra only. We do not analyze the third-order structure function, but judge whether a nonlinear energy cascade is present or whether it is not by only analyzing the appearance of power-law distributions in the low-frequency part of the magnetic field spectra. While the power-law spectrum alone does not guarantee that a nonlinear cascade is present, the power-law distribution is a strong indication of the possible development of a nonlinear cascade. Our analysis shows that a nonlinear energy cascade is indeed observed in both the outer and inner magnetosphere data, and EMIC waves are growing from this nonthermal background. All the analyzed data are in good agreement with the theoretical model presented in this study. Overall, the results of this study support a nonlinear energy cascade in Earth's magnetosphere as a mechanism which is responsible for supplying seed fluctuating energy in the higher frequency domain where EMIC waves grow due to the ion cyclotron instability.

Studies of the Core Conditions of the Earth and Super-Earths Using Intense Ion Beams at FAIR

NASA Astrophysics Data System (ADS)

Tahir, N. A.; Lomonosov, I. V.; Borm, B.; Piriz, A. R.; Shutov, A.; Neumayer, P.; Bagnoud, V.; Piriz, S. A.

2017-09-01

Using detailed numerical simulations, we present the design of an experiment that will generate samples of iron under extreme conditions of density and pressure believed to exist in the interior of the Earth and interior of extrasolar Earth-like planets. In the proposed experiment design, an intense uranium beam is used to implode a multilayered cylindrical target that consists of a thin Fe cylinder enclosed in a thick massive W shell. Such intense uranium beams will be available at the heavy-ion synchrotron, SIS100, at the Facility for Antiprotons and Ion Research (FAIR), at Darmstadt, which is under construction and will become operational in the next few years. It is expected that the beam intensity will increase gradually over a couple of years to its maximum design value. Therefore, in our studies, we have considered a wide range of beam parameters, from the initial beam intensity (“Day One”) to the maximum specified value. It is also worth noting that two different focal spot geometries have been used. In one case, a circular focal spot with a Gaussian transverse intensity distribution is considered, whereas in the other case, an annular focal spot is used. With these two beam geometries, one can access different parts of the Fe phase diagram. For example, heating the sample with a circular focal spot generates a hot liquid state, while an annular focal spot can produce a highly compressed liquid or a highly compressed solid phase depending on the beam intensity.

Ion Composition and Energization in the Earth's Inner Magnetosphere and the Effects on Ring Current Buildup

NASA Astrophysics Data System (ADS)

Keika, K.; Kistler, L. M.; Brandt, P. C.

2014-12-01

In-situ observations and modeling work have confirmed that singly-charged oxygen ions, O+, which are of Earth's ionospheric origin, are heated/accelerated up to >100 keV in the magnetosphere. The energetic O+ population makes a significant contribution to the plasma pressure in the Earth's inner magnetosphere during magnetic storms, although under quiet conditions H+ dominates the plasma pressure. The pressure enhancements, which we term energization, are caused by adiabatic heating through earthward transport of source population in the plasma sheet, local acceleration in the inner magnetosphere and near-Earth plasma sheet, and enhanced ion supply from the topside ionosphere. The key issues regarding stronger O+ energization than H+ are non-adiabatic local acceleration, responsible for increase in O+ temperature, and more significant O+ supply than H+, responsible for increase in O+ density. Although several acceleration mechanisms and O+ supply processes have been proposed, it remains an open question what mechanism(s)/process(es) play the dominant role in stronger O+ energization. In this paper we summarize important spacecraft observations including those from Van Allen Probes, introduces the proposed mechanisms/processes that generate O+-rich energetic plasma population, and outlines possible scenarios of O+ pressure abundance in the Earth's inner magnetosphere.

Ion Acceleration at Earth, Saturn and Jupiter and its Global Impact on Magnetospheric Structure

NASA Astrophysics Data System (ADS)

Brandt, Pontus

2016-07-01

The ion plasma pressures at Earth, Saturn and Jupiter are significant players in the electrodynamic force-balance that governs the structure and dynamics of these magnetospheres. There are many similarities between the physical mechanisms that are thought to heat the ion plasma to temperatures that even exceed those of the solar corona. In this presentation we compare the ion acceleration mechanisms at the three planetary magnetospheres and discuss their global impacts on magnetopsheric structure. At Earth, bursty-bulk flows, or "bubbles", have been shown to accelerate protons and O+ to high energies by the earthward moving magnetic dipolarization fronts. O+ ions display a more non-adiabatic energization in response to these fronts than protons do as they are energized and transported in to the ring-current region where they reach energies of several 100's keV. We present both in-situ measurements from the NASA Van Allen Probes Mission and global Energetic Neutral (ENA) images from the High-Energy Neutral Atom (HENA) Camera on board the IMAGE Mission, that illustrate these processes. The global impact on the magnetospheric structure is explored by comparing the empirical magnetic field model TS07d for given driving conditions with global plasma pressure distributions derived from the HENA images. At Saturn, quasi-periodic energization events, or large-scale injections, occur beyond about 9 RS around the post-midnight sector, clearly shown by the Ion and Neutral Atom Camera (INCA) on board the Cassini mission. In contrast to Earth, the corotational drift dominates even the energetic ion distributions. The large-scale injections display similar dipolarization front features can be found and there are indications that like at Earth the O+ responds more non-adiabatically than protons do. However, at Saturn there are also differences in that there appears to be energization events deep in the inner magnetosphere (6-9 RS) preferentially occurring in the pre

Accelerated ions and self-excited Alfvén waves at the Earth's bow shock

NASA Astrophysics Data System (ADS)

Berezhko, E. G.; Taneev, S. N.; Trattner, K. J.

2011-07-01

The diffuse energetic ion event and related Alfvén waves upstream of the Earth's bow shock, measured by AMPTE/IRM satellite on 29 September 1984, 06:42-07:22 UT, was studied using a self-consistent quasi-linear theory of ion diffusive shock acceleration and associated Alfvén wave generation. The wave energy density satisfies a wave kinetic equation, and the ion distribution function satisfies the diffusive transport equation. These coupled equations are solved numerically, and calculated ion and wave spectra are compared with observations. It is shown that calculated steady state ion and Alfvén wave spectra are established during the time period of about 1000 s. Alfvén waves excited by accelerated ions are confined within the frequency range (10-2 to 1) Hz, and their spectral peak with the wave amplitude δB ≈ B comparable to the interplanetary magnetic field value B corresponds to the frequency 2 × 10-2 Hz. The high-frequency part of the wave spectrum undergoes absorption by thermal protons. It is shown that the observed ion spectra and the associated Alfvén wave spectra are consistent with the theoretical prediction.

Nonthermal ions and associated magnetic field behavior at a quasi-parallel earth's bow shock

NASA Technical Reports Server (NTRS)

Wilkinson, W. P.; Pardaens, A. K.; Schwartz, S. J.; Burgess, D.; Luehr, H.; Kessel, R. L.; Dunlop, M.; Farrugia, C. J.

1993-01-01

Attention is given to ion and magnetic field measurements at the earth's bow shock from the AMPTE-UKS and -IRM spacecraft, which were examined in high time resolution during a 45-min interval when the field remained closely aligned with the model bow shock normal. Dense ion beams were detected almost exclusively in the midst of short-duration periods of turbulent magnetic field wave activity. Many examples of propagation at large elevation angles relative to the ecliptic plane, which is inconsistent with reflection in the standard model shock configuration, were discovered. The associated waves are elliptically polarized and are preferentially left-handed in the observer's frame of reference, but are less confined to the maximum variance plane than other previously studied foreshock waves. The association of the wave activity with the ion beams suggests that the former may be triggered by an ion-driven instability, and possible candidates are discussed.

Computational Studies of Thermodynamics and Kinetics of Metal Oxides in Li-Ion Batteries and Earth's Lower Mantle Materials

NASA Astrophysics Data System (ADS)

Xu, Shenzhen

Metal oxide materials are ubiquitous in nature and in our daily lives. For example, the Earth's mantle layer that makes up about 80% of our Earth's volume is composed of metal oxide materials, the cathode materials in the lithium-ion batteries that provide power for most of our mobile electronic devices are composed of metal oxides, the chemical components of the passivation layers on many kinds of metal materials that protect the metal from further corrosion are metal oxides. This thesis is composed of two major topics about the metal oxide materials in nature. The first topic is about our computational study of the iron chemistry in the Earth's lower mantle metal oxide materials, i.e. the bridgmanite (Fe-bearing MgSiO3 where iron is the substitution impurity element) and the ferropericlase (Fe-bearing MgO where iron is the substitution impurity element). The second topic is about our multiscale modeling works for understanding the nanoscale kinetic and thermodynamic properties of the metal oxide cathode interfaces in Li-ion batteries, including the intrinsic cathode interfaces (intergrowth of multiple types of cathode materials, compositional gradient cathode materials, etc.), the cathode/coating interface systems and the cathode/electrolyte interface systems. This thesis uses models based on density functional theory quantum mechanical calculations to explore the underlying physics behind several types of metal oxide materials existing in the interior of the Earth or used in the applications of lithium-ion batteries. The exploration of this physics can help us better understand the geochemical and seismic properties of our Earth and inspire us to engineer the next generation of electrochemical technologies.

Studies of the Core Conditions of the Earth and Super-Earths Using Intense Ion Beams at FAIR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tahir, N. A.; Neumayer, P.; Bagnoud, V.

Using detailed numerical simulations, we present the design of an experiment that will generate samples of iron under extreme conditions of density and pressure believed to exist in the interior of the Earth and interior of extrasolar Earth-like planets. In the proposed experiment design, an intense uranium beam is used to implode a multilayered cylindrical target that consists of a thin Fe cylinder enclosed in a thick massive W shell. Such intense uranium beams will be available at the heavy-ion synchrotron, SIS100, at the Facility for Antiprotons and Ion Research (FAIR), at Darmstadt, which is under construction and will becomemore » operational in the next few years. It is expected that the beam intensity will increase gradually over a couple of years to its maximum design value. Therefore, in our studies, we have considered a wide range of beam parameters, from the initial beam intensity (“Day One”) to the maximum specified value. It is also worth noting that two different focal spot geometries have been used. In one case, a circular focal spot with a Gaussian transverse intensity distribution is considered, whereas in the other case, an annular focal spot is used. With these two beam geometries, one can access different parts of the Fe phase diagram. For example, heating the sample with a circular focal spot generates a hot liquid state, while an annular focal spot can produce a highly compressed liquid or a highly compressed solid phase depending on the beam intensity.« less

Toward a System-Based Approach to Electromagnetic Ion Cyclotron Waves in Earth's Magnetosphere

NASA Astrophysics Data System (ADS)

Gamayunov, K. V.; Engebretson, M. J.; Rassoul, H.

2015-12-01

We consider a nonlinear wave energy cascade from the low frequency range into the higher frequency domain of electromagnetic ion cyclotron (EMIC) wave generation as a possible source of seed fluctuations for EMIC wave growth due to the ion cyclotron instability in Earth's magnetosphere. The theoretical analysis shows that energy cascade from the Pc 4-5 frequency range (2-22 mHz) into the range of Pc 1-2 pulsations (0.1-5 Hz) is able to supply the level of seed fluctuations that guarantees growth of EMIC waves up to an observable level during one pass through the near equatorial region where the ion cyclotron instability takes place. We also analyze magnetic field data from the Polar and Van Allen Probes spacecraft to test this nonlinear mechanism. We restrict our analysis to magnetic spectra only. We do not analyze the third-order moment for total energy of the magnetic and velocity fluctuations, but judge whether a nonlinear energy cascade is present or whether it is not by only analyzing the appearance of power-law distributions in the low frequency part of the magnetic field spectra. While the power-law spectrum alone does not guarantee that a nonlinear cascade is present, the power-law distribution is a strong indication of the possible development of a nonlinear cascade. Our data analysis shows that a nonlinear energy cascade is indeed observed in both the outer and inner magnetosphere, and EMIC waves are growing from this nonthermal background. All the analyzed data are in good agreement with the theoretical model presented in this study. Overall, the results of this study support a nonlinear energy cascade in Earth's magnetosphere as a mechanism which is responsible for supplying seed fluctuating energy in the higher frequency domain where EMIC waves grow due to the ion cyclotron instability. Keywords: nonlinear energy cascade, ultra low frequency waves, electromagnetic ion cyclotron waves, seed fluctuationsAcknowledgments: This paper is based upon work

Evidence for solar wind origin of energetic heavy ions in the earth's radiation belt

NASA Technical Reports Server (NTRS)

Hovestadt, D.; Klecker, B.; Scholer, M.; Gloeckler, G.; Ipavich, F. M.; Fan, C. Y.; Fisk, L. A.; Ogallagher, J. J.

1978-01-01

Analysis of data from our energetic ion composition experiment on ISEE-1 has revealed the presence of substantial fluxes of carbon, oxygen, and heavier ions above 400 keV/nucleon at L values between approximately 2.5 and 4 earth radii. The measured C/O ratio varies systematically from 1.3 at 450 keV/nucleon to 4.1 at 1.3 MeV/nucleon, and no iron is observed above 200 keV/nucleon. These results provide strong evidence for a solar wind origin for energetic ions in the outer radiation belt. The absence of iron and the increase of the carbon-to-oxygen ratio with energy suggest that the condition for the validity of the first adiabatic invariant may have a strong influence on the trapping of these particles.

Kinetic theory for the ion humps at the foot of the Earth's bow shock

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jovanovic, D.; Krasnoselskikh, V. V.

2009-10-15

The nonlinear kinetic theory is presented for the ion acoustic perturbations at the foot of the Earth's quasiperpendicular bow shock, that is characterized by weakly magnetized electrons and unmagnetized ions. The streaming ions, due to the reflection of the solar wind ions from the shock, provide the free energy source for the linear instability of the acoustic wave. In the fully nonlinear regime, a coherent localized solution is found in the form of a stationary ion hump, which is traveling with the velocity close to the phase velocity of the linear mode. The structure is supported by the nonlinearities comingmore » from the increased population of the resonant beam ions, trapped in the self-consistent potential. As their size in the direction perpendicular to the local magnetic field is somewhat smaller that the electron Larmor radius and much larger that the Debye length, their spatial properties are determined by the effects of the magnetic field on weakly magnetized electrons. These coherent structures provide a theoretical explanation for the bipolar electric pulses, observed upstream of the shock by Polar and Cluster satellite missions.« less

Raman scattering of rare earth hexaborides

NASA Astrophysics Data System (ADS)

Ogita, Norio; Hasegawa, Takumi; Udagawa, Masayuki; Iga, Fumitoshi; Kunii, Satoru

2009-06-01

Raman scattering spectra were measured for the rare-earth hexaborides RB6 (R = Ce, Gd, or Dy). All Raman-active phonons due to B6 vibrations were observed in the range 600 - 1400 cm-1. Anomalous peaks were detected below 200 cm-1, which correspond to vibrations of rare-earth ion excited by second-order Raman scattering process. The intensity and energy of the rare-earth mode decrease with decreasing temperature. This suggests that the rare-earth ion vibrates in a shallow and anharmonic potential due to the boron cage. Using the reported values of mean square displacement of rare-earth ion, we estimated the anharmonic contribution for the rare-earth vibrations.

Numerical simulations of the optical gain of crystalline fiber doped by rare earth and transition ion

NASA Astrophysics Data System (ADS)

Daoui, A. K.; Boubir, B.; Adouane, A.; Demagh, N.; Ghoumazi, M.

2015-02-01

A fiber laser is a laser whose gain medium is a doped fiber, although lasers whose cavity is made wholly of fibers have also been called fiber lasers. The gain media in a fiber laser is usually fiber doped with rare-earth ions, such as erbium (Er), neodymium (Nd), ytterbium (Yb), thulium (Tm), or praseodymium (Pr), which is doped into the core of the optical fiber, similar to those used to transmit telecommunications signals. Fiber lasers find many applications in materials processing, including cutting, welding, drilling, and marking metal. To maximize their market penetration, it is necessary to increase their output power. In this work, we present a detailed study based on the numerical simulation using MATLAB, of one of the principal characteristics of a fiber laser doped with rare earth ions and transition ion. The gain depends on several parameters such as the length of the doped fiber, the density, the pump power, noise, etc.). The used program resolves the state equations in this context together with those governing the light propagation phenomena. The developed code can also be used to study the dynamic operating modes of a doped fiber laser.

SEPARATION OF PLUTONYL IONS

DOEpatents

Connick, R.E.; McVey, Wm.H.

1958-07-15

A process is described for separating plutonyl ions from the acetate ions with which they are associated in certaln carrier precipitation methods of concentrating plutonium. The method consists in adding alkaline earth metal ions and subsequently alkalizing the solution, causing formation of an alkaltne earth plutonate precipitate. Barium hydroxide is used in a preferred embodiment since it provides alkaline earth metal ion and alkalizes the solution in one step forming insoluble barium platonate.

GeS2–In2S3–CsI Chalcogenide Glasses Doped with Rare Earth Ions for Near- and Mid-IR Luminescence

PubMed Central

Li, Legang; Bian, Junyi; Jiao, Qing; Liu, Zijun; Dai, Shixun; Lin, Changgui

2016-01-01

Chalcogenide glass has been considered as a promising host for the potential laser gain and amplifier media operating in near- and mid-IR spectral region. In this work, the IR luminescence spectra of rare earth ions (Tm3+, Er3+, and Dy3+) doped 65GeS2–25In2S3–10CsI chalcogenide glasses were measured under the excitation of an 808 nm laser diode. To the best of our knowledge, it firstly provides the luminescence spectra of a full near- and mid-IR spectral range from 1 to 4 μm in rare earth ions doped chalcogenide glasses. The results of absorption spectra, luminescence spectra, and fluorescence decay curves were obtained in these samples with singly-, co- and triply-doping behaviors of Tm3+, Er3+, and Dy3+ ions. In order to search possible efficient IR emissions, the luminescence behavior was investigated specifically with the variation of doping behaviors and dopant ions, especially in the samples co- and triply-doped active ions. The results suggest that favorable near- and mid-IR luminescence of rare earth ions can be further modified in chalcogenide glasses through an elaborated design of doping behavior and optically active ions. PMID:27869231

Electromagnetic Ion Cyclotron Waves Detected by Kaguya and Geotail in the Earth's Magnetotail

NASA Astrophysics Data System (ADS)

Nakagawa, Tomoko; Nishino, Masaki N.; Tsunakawa, Hideo; Takahashi, Futoshi; Shibuya, Hidetoshi; Shimizu, Hisayoshi; Matsushima, Masaki; Saito, Yoshifumi

2018-02-01

Narrowband electromagnetic ion cyclotron waves first discovered by the Apollo 15 and 16 Lunar Surface Magnetometers were surveyed in the magnetic field data obtained by the Kaguya satellite at an altitude of ˜100 km above the Moon in the tail lobe and plasma sheet boundary layer of the Earth's magnetosphere. The frequencies of the waves were typically 0.7 times the local proton cyclotron frequency, and 75% of the waves were left hand polarized with respect to the background magnetic field. They had a significant compressional component and comprised several discrete packets. They were detected on the dayside, nightside, and above the terminator of the Moon, irrespective of the lunar magnetic anomaly, or the magnetic connection to the lunar surface. The waves with the same characteristics were detected by Geotail in the absence of the Moon in the magnetotail. The most likely energy source of the electromagnetic ion cyclotron waves is the ring beam ions in the plasma sheet boundary layer.

Coordination chemistry of vitamin C. Part I. Interaction of L-ascorbic acid with alkaline earth metal ions in the crystalline solid and aqueous solution.

PubMed

Tajmir-Riahi, H A

1990-10-01

The interaction of L-ascorbic acid with alkaline earth metal ions has been investigated in aqueous solution at pH 6-7. The solid salts of the type Mg(L-ascorbate)2.4H2O, Ca(L-ascorbate)2.2H2O, Sr(L-ascorbate)2.2H2O and Ba(L-ascorbate)2.2H2O were isolated and characterized by means of 13C NMR and FT-IR spectroscopy. Spectroscopic and other evidence suggested that in aqueous solution, the binding of the alkaline earth metal ions is through the O-3 atom of the ascorbate anion, while in the solid state the binding of the Mg(II) is different from those of the other alkaline earth metal ion salts. The Mg(II) ion binds to the O-3, O-1 atom of the two ascorbate anions and to two H2O molecules, while the eight-coordination around the Ca(II), Sr(II), and Ba(II) ions would be completed by the coordination of three acid anions, through O-5, O-6 of the first, O-3, O-5, O-6 of the second and O-1 of the third anion as well as to two H2O molecules. The structural properties of the alkaline earth metal-ascorbate salts are different in the solid and aqueous solution.

Stochastic Growth of Ion Cyclotron And Mirror Waves In Earth's Magnetosheath

NASA Technical Reports Server (NTRS)

Cairns, Iver H.; Grubits, K. A.

2001-01-01

Electromagnetic ion cyclotron and mirror waves in Earth's magnetosheath are bursty, have widely variable fields, and are unexpectedly persistent, properties difficult to reconcile with uniform secular growth. Here it is shown for specific periods that stochastic growth theory (SGT) quantitatively accounts for the functional form of the wave statistics and qualitatively explains the wave properties. The wave statistics are inconsistent with uniform secular growth or self-organized criticality, but nonlinear processes sometimes play a role at high fields. The results show SGT's relevance near marginal stability and suggest that it is widely relevant to space and astrophysical plasmas.

An Update on the Lithium-Ion Cell Low-Earth-Orbit Verification Test Program

NASA Technical Reports Server (NTRS)

Reid, Concha M.; Manzo, Michelle A.; Miller, Thomas B.; McKissock, Barbara I.; Bennett, William

2007-01-01

A Lithium-Ion Cell Low-Earth-Orbit Verification Test Program is being conducted by NASA Glenn Research Center to assess the performance of lithium-ion (Li-ion) cells over a wide range of low-Earth-orbit (LEO) conditions. The data generated will be used to build an empirical model for Li-ion batteries. The goal of the modeling will be to develop a tool to predict the performance and cycle life of Li-ion batteries operating at a specified set of mission conditions. Using this tool, mission planners will be able to design operation points of the battery system while factoring in mission requirements and the expected life and performance of the batteries. Test conditions for the program were selected via a statistical design of experiments to span a range of feasible operational conditions for LEO aerospace applications. The variables under evaluation are temperature, depth-of-discharge (DOD), and end-of-charge voltage (EOCV). The baseline matrix was formed by generating combinations from a set of three values for each variable. Temperature values are 10 C, 20 C and 30 C. Depth-of-discharge values are 20%, 30% and 40%. EOCV values are 3.85 V, 3.95 V, and 4.05 V. Test conditions for individual cells may vary slightly from the baseline test matrix depending upon the cell manufacturer s recommended operating conditions. Cells from each vendor are being evaluated at each of ten sets of test conditions. Cells from four cell manufacturers are undergoing life cycle tests. Life cycling on the first sets of cells began in September 2004. These cells consist of Saft 40 ampere-hour (Ah) cells and Lith ion 30 Ah cells. These cells have achieved over 10,000 cycles each, equivalent to about 20 months in LEO. In the past year, the test program has expanded to include the evaluation of Mine Safety Appliances (MSA) 50 Ah cells and ABSL battery modules. The MSA cells will begin life cycling in October 2006. The ABSL battery modules consist of commercial Sony hard carbon 18650 lithium-ion

Structural, optical absorption and photoluminescence spectral studies of Sm3+ ions in Alkaline-Earth Boro Tellurite glasses

NASA Astrophysics Data System (ADS)

Siva Rama Krishna Reddy, K.; Swapna, K.; Mahamuda, Sk.; Venkateswarlu, M.; Srinivas Prasad, M. V. V. K.; Rao, A. S.; Prakash, G. Vijaya

2018-05-01

Sm3+ ions doped Alkaline-Earth Boro Tellurite (AEBT) glasses were prepared by using conventional melt quenching technique and characterized using the spectroscopic techniques such as FT-IR, optical absorption, emission and decay spectral measurements to understand their utility in optoelectronic devices. From absorption spectra, the bonding parameters, nephelauxetic ratios were determined to know the nature of bonding between Sm3+ ions and its surrounding ligands. From the measured oscillator strengths, the Judd-Ofelt (J-O) intensity parameters were evaluated and in turn used to estimate various radiative parameters for the fluorescent levels of Sm3+ ions in AEBT glasses. The PL spectra of Sm3+ ions exhibit three emission bands corresponding to the transitions 4G5/2 → 6H5/2, 6H7/2 and 6H9/2 in the visible region for which the emission cross-sections and branching ratios were evaluated. The decay spectral profiles measured for 4G5/2 → 6H7/2 transition showed single exponential for lower concentration and non-exponential for higher concentration of doped rare earth ion in the as prepared glasses. Conversion of decay spectral profiles from single to non-exponential have been analyzed using Inokuti-Hirayama (I-H) model to understand the energy transfer mechanism involved in the decay process. CIE Chromaticity coordinates were measured using emission spectral data to identify the exact region of emission from the as-prepared glasses. From the evaluated radiative parameters, emission cross-sections and quantum efficiencies, it was observed that AEBT glass with 1 mol% of Sm3+ ions is more suitable for designing optoelectronic devices.

Influence of other rare earth ions on the optical refrigeration efficiency in Yb:YLF crystals.

PubMed

Di Lieto, Alberto; Sottile, Alberto; Volpi, Azzurra; Zhang, Zhonghan; Seletskiy, Denis V; Tonelli, Mauro

2014-11-17

We investigated the effect of rare earth impurities on the cooling efficiency of Yb³⁺:LiYF₄ (Yb:YLF). The refrigeration performance of two single crystals, doped with 5%-at. Yb and with identical history but with different amount of contaminations, have been compared by measuring the cooling efficiency curves. Spectroscopic and elemental analyses of the samples have been carried out to identify the contaminants, to quantify their concentrations and to understand their effect on the cooling efficiencies. A model of energy transfer processes between Yb and other rare earth ions is suggested, identifying Erbium and Holmium as elements that produce a detrimental effect on the cooling performance.

Rare earth ions doped ZnO: Synthesis, characterization and preliminary photoactivity assessment

NASA Astrophysics Data System (ADS)

Cerrato, Erik; Gionco, Chiara; Berruti, Ilaria; Sordello, Fabrizio; Calza, Paola; Paganini, Maria Cristina

2018-08-01

This work reports the effect of doping zinc oxide with lanthanide ions on structural, EPR and UV visible properties. Bare and doped samples were synthesized using the simple and green hydrothermal process. Different rare earth ions (RE = La, Ce, Pr, Er and Yb) with 1% molar ratio RE/Zn were used. The samples have been studied using X Ray Diffraction, Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and UV visible diffuse reflectance spectroscopy. Finally, electron paramagnetic resonance (EPR) spectroscopy, was used to assess the materials photoactivity under UV irradiation, both in solid state, to see the charge carriers' generation and in solution, evaluating the OH• radical formation using the DMPO (5,5-Dimethyl-1-Pyrroline-N-Oxide) spin trapping technique. The results suggest that the synthesized materials could be interesting systems for the photocatalytic abatement of emerging organic persistent pollutants in wastewater treatment plants.

Bond-length distributions for ions bonded to oxygen: alkali and alkaline-earth metals.

PubMed

Gagné, Olivier Charles; Hawthorne, Frank Christopher

2016-08-01

Bond-length distributions have been examined for 55 configurations of alkali-metal ions and 29 configurations of alkaline-earth-metal ions bonded to oxygen, for 4859 coordination polyhedra and 38 594 bond distances (alkali metals), and for 3038 coordination polyhedra and 24 487 bond distances (alkaline-earth metals). Bond lengths generally show a positively skewed Gaussian distribution that originates from the variation in Born repulsion and Coulomb attraction as a function of interatomic distance. The skewness and kurtosis of these distributions generally decrease with increasing coordination number of the central cation, a result of decreasing Born repulsion with increasing coordination number. We confirm the following minimum coordination numbers: ([3])Li(+), ([3])Na(+), ([4])K(+), ([4])Rb(+), ([6])Cs(+), ([3])Be(2+), ([4])Mg(2+), ([6])Ca(2+), ([6])Sr(2+) and ([6])Ba(2+), but note that some reported examples are the result of extensive dynamic and/or positional short-range disorder and are not ordered arrangements. Some distributions of bond lengths are distinctly multi-modal. This is commonly due to the occurrence of large numbers of structure refinements of a particular structure type in which a particular cation is always present, leading to an over-representation of a specific range of bond lengths. Outliers in the distributions of mean bond lengths are often associated with anomalous values of atomic displacement of the constituent cations and/or anions. For a sample of ([6])Na(+), the ratio Ueq(Na)/Ueq(bonded anions) is partially correlated with 〈([6])Na(+)-O(2-)〉 (R(2) = 0.57), suggesting that the mean bond length is correlated with vibrational/displacement characteristics of the constituent ions for a fixed coordination number. Mean bond lengths also show a weak correlation with bond-length distortion from the mean value in general, although some coordination numbers show the widest variation in mean bond length for zero distortion, e.g. Li(+) in

Unambiguously identifying spin states of transition-metal ions in the Earth (Invited)

NASA Astrophysics Data System (ADS)

Hsu, H.

2010-12-01

The spin state of a transition-metal ion in crystalline solids, defined by the number of unpaired electrons in the ion’s incomplete 3d shell, may vary with many factors, such as temperature, pressure, strain, and the local atomic configuration, to name a few. Such a phenomenon, known as spin-state crossover, plays a crucial role in spintronic materials. Recently, the pressure-induced spin-state crossover in iron-bearing minerals has been recognized to affect the minerals’ structural and elastic properties. However, the detailed mechanism of such crossover in iron-bearing magnesium silicate perovskite, the most abundant mineral in the Earth, remains unclear. A significant part of this confusion arises from the difficulty in reliably extracting the spin state from experiments. For the same reason, the thermally-induced spin-state crossover in lanthanum cobaltite (LaCoO3) has been controversial for more than four decades. In this talk, I will discuss how first-principle calculations can help clarifying these long-standing controversies. In addition to the total energy, equation of state, and elastic properties of each spin state, first-principle calculations also predict the electric field gradient (EFG) at the nucleus of each transition-metal ion. Our calculations showed that the nuclear EFG, a quantity that can be measured via Mössbauer or nuclear magnetic resonance (NMR) spectroscopy, depends primarily on the spin state, irrespective of the concentration or configuration of transition-metal ions. Such robustness makes EFG a unique fingerprint to identify the spin state. The combination of first-principle calculations and Mössbauer/NMR spectroscopy can therefore be a reliable and efficient approach in tackling spin-state crossover problems in the Earth. This work was primarily supported by the MRSEC Program of NSF under Awards Number DMR-0212302 and DMR-0819885, and partially supported by NSF under ATM-0428774 (V-Lab), EAR-1019853, and EAR-0810272. The

Limitations of Electromagnetic Ion Cyclotron Wave Observations in Low Earth Orbit

NASA Astrophysics Data System (ADS)

Hwang, Junga; Kim, Hyangpyo; Park, Jaeheung; Lee, Jaejin

2018-03-01

Pc1 pulsations are geomagnetic fluctuations in the frequency range of 0.2 to 5 Hz. There have been several observations of Pc1 pulsations in low earth orbit by MAGSAT, DE-2, Viking, Freja, CHAMP, and SWARM satellites. However, there has been a clear limitation in resolving the spatial and temporal variations of the pulsation by using a single-point observation by a single satellite. To overcome such limitations of previous observations, a new space mission was recently initiated, using the concept of multi-satellites, named the Small scale magNetospheric and Ionospheric Plasma Experiments (SNIPE). The SNIPE mission consists of four nanosatellites ( 10 kg), which will be launched into a polar orbit at an altitude of 600 km (TBD) in 2020. Four satellites will be deployed in orbit, and the distances between each satellite will be controlled from 10 to 1,000 km by a highend formation-flying algorithm. One of the possible science targets of the SNIPE mission is observing electromagnetic ion cyclotron (EMIC) waves. In this paper, we report on examples of observations, showing the limitations of previous EMIC observations in low earth orbit, and suggest possibilities to overcome those limitations through a new mission.

Formation of the high-energy ion population in the earth's magnetotail: spacecraft observations and theoretical models

NASA Astrophysics Data System (ADS)

Artemyev, A. V.; Vasko, I. Y.; Lutsenko, V. N.; Petrukovich, A. A.

2014-10-01

We investigate the formation of the high-energy (E ∈ [20,600] keV) ion population in the earth's magnetotail. We collect statistics of 4 years of Interball / Tail observations (1995-1998) in the vicinity of the neutral plane in the magnetotail region (X <-17 RE, |Y| ≤ 20 RE in geocentric solar magnetospheric (GSM) system). We study the dependence of high-energy ion spectra on the thermal-plasma parameters (the temperature Ti and the amplitude of bulk velocity vi) and on the magnetic-field component Bz. The ion population in the energy range E ∈ [20,600] keV can be separated in the thermal core and the power-law tail with the slope (index) ~ -4.5. Fluxes of the high-energy ion population increase with the growth of Bz, vi and especially Ti, but spectrum index seems to be independent on these parameters. We have suggested that the high-energy ion population is generated by small scale transient processes, rather than by the global reconfiguration of the magnetotail. We have proposed the relatively simple and general model of ion acceleration by transient bursts of the electric field. This model describes the power-law energy spectra and predicts typical energies of accelerated ions.

Energy density of ionospheric and solar wind origin ions in the near-Earth magnetotail during substorms

NASA Technical Reports Server (NTRS)

Daglis, Loannis A.; Livi, Stefano; Sarris, Emmanuel T.; Wilken, Berend

1994-01-01

Comprehensive energy density studies provide an important measure of the participation of various sources in energization processes and have been relatively rare in the literature. We present a statistical study of the energy density of the near-Earth magnetotail major ions (H(+), O(+), He(++), He(+)) during substorm expansion phase and discuss its implications for the solar wind/magnetosphere/ionosphere coupling. Our aim is to examine the relation between auroral activity and the particle energization during substorms through the correlation between the AE indices and the energy density of the major magnetospheric ions. The data we used here were collected by the charge-energy-mass (CHEM) spectrometer on board the Active Magnetospheric Particle Trace Explorer (AMPTE)/Charge Composition Explorer (CCE) satellite in the near-equatorial nightside magnetosphere, at geocentric distances approximately 7 to 9 R(sub E). CHEM provided the opportunity to conduct the first statistical study of energy density in the near-Earth magnetotail with multispecies particle data extending into the higher energy range (greater than or equal to 20 keV/E). the use of 1-min AE indices in this study should be emphasized, as the use (in previous statistical studies) of the (3-hour) Kp index or of long-time averages of AE indices essentially smoothed out all the information on substorms. Most distinct feature of our study is the excellent correlation of O(+) energy density with the AE index, in contrast with the remarkably poor He(++) energy density - AE index correlation. Furthermore, we examined the relation of the ion energy density to the electrojet activity during substorm growth phase. The O(+) energy density is strongly correlated with the pre-onset AU index, that is the eastward electrojet intensity, which represents the growth phase current system. Our investigation shows that the near-Earth magnetotail is increasingly fed with energetic ionospheric ions during periods of enhanced

Theoretical Crystal-Field Calculations for Rare-Earth Ions in III-V semiconductor Compounds

DTIC Science & Technology

1991-10-01

AD-A243 098 TIC HDL-TM-91-16 1 Ii! 1 I!EiIII ’ii F CT F October 1991 aC7 1991J Theoretical Crystal-Field Calculations for Rare-Earth Ions in III-V...0188). Washngton. DC 20503 1 . AGENCY USE ONLY (Leave bia*) 2. REPORT DATE 3. REPORT TYPE AND DATES COVERED October 1991 Summary, from Jan 91 toJul 91...Laboratories HDL-TM-9 1 -16 2800 Powder Mill Road Adelphi, MD 20783-1197 9. SPONSORNG#AONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSORINGMONITORING

Discovery of ions with nuclear charge Z greater than or equal to 9 stability trapped in the earth's radiation belts

NASA Astrophysics Data System (ADS)

Spjeldvik, W. N.; Fritz, T. A.

1981-11-01

Observations of MeV heavy ions obtained by Explorer 45 in an equatorial earth orbit during a 7 month period in 1972 are presented, including data from four major magnetic storms. The spacecraft contained a heavy ion detector telescope and heavy ion discriminator electronics. Heavy ions were distinguished from protons and electrons, and He ions and ions heavier than F were recorded on separate data channels. The L equals 2.25 to L equals 4 zones were probed, and it was found that the relative enhancement in heavy ion fluxes in the radiation belts over the prestorm ion flux intensities tends to increase with increasing ion mass and/or increasing ion energy in the MeV range. The radial profiles of ions with nucleon number greater than nine peak at L equals 2.9, and MeV ions in this class decay on time scales from 23 days at L equals 3.25 to 55 days at L equals 2.25. Indirect evidence indicated a solar source for the very heavy ions in the magnetosphere.

Preparation and luminescent properties of the novel polymer-rare earth complexes composed of Poly(ethylene-co-acrylic acid) and Europium ions

NASA Astrophysics Data System (ADS)

Wu, Yuewen; Hao, Haixia; Wu, Qingyao; Gao, Zihan; Xie, Hongde

2018-06-01

A series of novel polymer-rare earth complexes with Eu3+ ions have been synthesized and investigated successfully, including the binary complexes containing the single ligand poly(ethylene-co-acrylic acid) (EAA) and the ternary complexes using 1,10-phenanthroline (phen), dibenzoylmethane (DBM) or thenoyltrifluoroacetone (TTA) as the second ligand. Their structures have been characterized by Fourier transform infrared spectroscopy (FT-IR), elemental analysis and X-ray diffraction (XRD), which confirm that both EAA and small molecules participate in the coordination reaction with rare earth ions, and they can disperse homogeneously in the polymer matrixes. Both ultraviolet-visible (UV-vis) absorption and photoluminescence tests for the complexes have been recorded. The relationship between fluorescence intensity of polymer-rare earth complexes and the quantity of ligand EAA has been studied and discussed. The films casted from the complexes solution can emit strong characteristic red light under UV light excitation. All these results suggest that the complexes possess potential application as luminescent materials.

Application of Laser Induced Breakdown Spectroscopy to Monitor Rare Earth Ions in Glass Matrix

NASA Astrophysics Data System (ADS)

Sharma, Prakash; Carter, Michael; Kumar, Akshaya

2013-05-01

The Laser Induced breakdown spectroscopy (LIBS) is a real time online technique that can be used to monitor the concentration of rare earth ions in amorphous glass matrix. This study has significant application in the glass industry where the composition of the glass can be monitored in real time using LIBS technology for quality control. The Eu3 + ions doped silicate glasses were developed via sol gel method. The glasses of varying molar percentages of Eu3 + (0.02, 0.05 and 0.08 mole percent), were prepared to study the effect of variation in concentration of Eu3 + ions on the LIBS signal and to calculate its limit of detection (LOD). The spectral assignment of the observed LIBS spectrum has been made. In order to find the maximum signal to noise ratio, we also recorded the intensity of LIBS signal for various integration start delay (ISD) time at a constant power of (pulsed Nd: YAG) laser. The ocean optics LIBS 2500plus spectrometer along with a Q switched Nd:YAG laser (Quantel, Big Sky) were used to record the LIBS spectrum.

Rare-Earth Oxide Ion (Tm3+, Ho3+, and U3+) Doped Glasses and Fibres for 1.8 to 4 Micrometer Coherent and Broadband Sources

DTIC Science & Technology

2006-07-24

oxide ( TeO2 ) , fluorine- containing silicate (SiOF2) and germanate (GeOF2) glass hosts for each dopant by characterising the spectroscopic properties...Earth Oxide Ion (Tm3+, Ho3+, And U3+) Doped Glasses And Fibres For 1.8 To 4 Micrometer Coherent And Broadband Sources 5c. PROGRAM ELEMENT NUMBER 5d...Rare-earth oxide ion (Tm3+, Ho3+, and U3+) doped glasses and fibres for 1.8 to 4 micrometer coherent and broadband sources Report prepared

Rare-Earth Ions in Niobium-Based Devices as a Quantum Memory: Magneto-Optical Effects on Room Temperature Electrical Transport

DTIC Science & Technology

2016-09-01

rare-earth neodymium by ion implantation in thin films of niobium and niobium-based heterostructure devices. We model the ion implantation process...the films and devices so they can properly designed and optimized for utility as quantum memory. We find that the magnetic field has a strong effect...thin films of niobium. Simulations are made at low 1013 cm-2 and high 1014 cm-2 dose at 60 keV. At high dose, disorder induced is significantly

Ion engine propelled Earth-Mars cycler with nuclear thermal propelled transfer vehicle, volume 2

NASA Technical Reports Server (NTRS)

Meyer, Rudolf X.; Baker, Myles; Melko, Joseph

1994-01-01

The goal of this project was to perform a preliminary design of a long term, reusable transportation system between earth and Mars which would be capable of providing both artificial gravity and shelter from solar flare radiation. The heart of this system was assumed to be a Cycler spacecraft propelled by an ion propulsion system. The crew transfer vehicle was designed to be propelled by a nuclear-thermal propulsion system. Several Mars transportation system architectures and their associated space vehicles were designed.

Low Temperature Life-Cycle Testing of a Lithium-Ion Battery for Low-Earth-Orbiting Spacecraft

NASA Technical Reports Server (NTRS)

Reid, Concha

2006-01-01

A flight-qualified, lithium-ion (Li-ion) battery developed for the Mars Surveyor Program 2001 Landeris undergoing life-testing at low temperature under a low-Earth-orbit (LEO) profile to assess its capability to provide long term energy storage for aerospace missions. NASA has embarked upon an ambitious course to return humans to the moon by 2015-2020 in preparation for robotic and human exploration of Mars and robotic exploration of the moons of outer planets. Li-ion batteries are excellent candidates to provide power and energy storage for multiple aspects of these missions due to their high specific energy, high energy density, and excellent low temperature performance. Laboratory testing of Li-ion technology is necessary in order to assess lifetime, characterize multi-cell battery-level performance under aerospace conditions, and to gauge safety aspects of the technology. Life-cycle testing provides an opportunity to examine battery-level performance and the dynamics of individual cells in the stack over the entire life of the battery. Data generated through this testing will be critical to establish confidence in the technology for its widespread use in manned and unmanned missions.

High charge state carbon and oxygen ions in Earth's equatorial quasi-trapping region

NASA Technical Reports Server (NTRS)

Christon, S. P.; Hamilton, D. C.; Gloeckler, G.; Eastmann, T. E.

1994-01-01

Observations of energetic (1.5 - 300 keV/e) medium-to-high charge state (+3 less than or equal to Q less than or equal to +7) solar wind origin C and O ions made in the quasi-trapping region (QTR) of Earth's magnetosphere are compared to ion trajectories calculated in model equatorial magnetospheric magnetic and electric fields. These comparisons indicate that solar wind ions entering the QTR on the nightside as an energetic component of the plasma sheet exit the region on the dayside, experiencing little or no charge exchange on the way. Measurements made by the CHarge Energy Mass (CHEM) ion spectrometer on board the Active Magnetospheric Particle Tracer Explorer/Charge Composition Explorer (AMPTE/CCE) spacecraft at 7 less than L less than 9 from September 1984 to January 1989 are the source of the new results contained herein: quantitative long-term determination of number densities, average energies, energy spectra, local time distributions, and their variation with geomagnetic disturbance level as indexed by Kp. Solar wind primaries (ions with charge states unchanged) and their secondaries (ions with generally lower charge states produced from primaries in the magnetosphere via charge exchange)are observed throughout the QTR and have distinctly different local time variations that persist over the entire 4-year analysis interval. During Kp larger than or equal to 3 deg intervals, primary ion (e.g., O(+6)) densities exhibit a pronounced predawn maximum with average energy minimum and a broad near-local-noon density minimum with average energy maximum. Secondary ion (e.g., O(+5)) densities do not have an identifiable predawn peak, rather they have a broad dayside maximum peaked in local morning and a nightside minimum. During Kp less than or equal to 2(-) intervals, primary ion density peaks are less intense, broader in local time extent, and centered near midnight, while secondary ion density local time variations diminish. The long-time-interval baseline helps

Near Earth Inner-Source and Interstellar Pickup Ions Observed with the Hot Plasma Composition Analyzer of the Magnetospheric Multiscale Mission Mms-Hpca

NASA Astrophysics Data System (ADS)

Gomez, R. G.; Fuselier, S. A.; Mukherjee, J.; Gonzalez, C. A.

2017-12-01

Pickup ions found near the earth are generally picked up in the rest frame of the solar wind, and propagate radially outward from their point of origin. While propagating, they simultaneously gyrate about the magnetic field. Pickup ions come in two general populations; interstellar and inner source ions. Interstellar ions originate in the interstellar medium, enter the solar system in a neutral charge state, are gravitationally focused on the side of the sun opposite their arrival direction and, are ionized when they travel near the sun. Inner-source ions originate at a location within the solar system and between the sun and the observation point. Both pickup ion populations share similarities in composition and charge states, so measuring of their dynamics, using their velocity distribution functions, f(v)'s, is absolutely essential to distinguishing them, and to determining their spatial and temporal origins. Presented here will be the results of studies conducted with the four Hot Plasma Composition Analyzers of the Magnetospheric Multiscale Mission (MMS-HPCA). These instruments measure the full sky (4π steradians) distribution functions of near earth plasmas at a 10 second cadence in an energy-to-charge range 0.001-40 keV/e. The instruments are also capable of parsing this combined energy-solid angle phase space with 22.5° resolution polar angle, and 11.25° in azimuthal angle, allowing for clear measurement of the pitch angle scattering of the ions.

A novel fluorescent probe (dtpa-bis(cytosine)) for detection of Eu(III) in rare earth metal ions

NASA Astrophysics Data System (ADS)

Yang, Fan; Ren, Peipei; Liu, Guanhong; Song, Youtao; Bu, Naishun; Wang, Jun

2018-03-01

In this paper, a novel fluorescent probe, dtpa-bis(cytosine), was designed and synthesized for detecting europium (Eu3 +) ion. Upon addition of Eu3 + ions into the dtpa-bis(cytosine) solution, the fluorescence intensity can strongly be enhanced. Conversely, adding other rare earth metal ions, such as Y3 +, Ce3 +, Pr3 +, Nd3 +, Sm3 +, Gd3 +, Tb3 +, Dy3 +, Ho3 +, Er3 +, Yb3 + and Lu3 +, into dtpa-bis(cytosine) solution, the fluorescence intensity is decreased slightly. Some parameters affecting the fluorescence intensity of dtpa-bis(cytosine) solution in the presence of Eu3 + ions were investigated, including solution pH value, Eu3 + ion concentration and interfering substances. The detection mechanism of Eu3 + ion using dtpa-bis(cytosine) as fluorescent probe was proposed. Under optimum conditions, the fluorescence emission intensities of EuIII-dtpa-bis(cytosine) at 375 nm in the concentration range of 0.50 × 10- 5 mol • L- 1-5.00 × 10- 5 mol • L- 1 of Eu3 + ion display a better linear relationship. The limit of detection (LOD) was determined as 8.65 × 10- 7 mol • L- 1 and the corresponding correlation coefficient (R2) of the linear equation is 0.9807. It is wished that the proposed method could be applied for sensitively and selectively detecting Eu3 + ion.

Origin, transport, and losses of energetic He(+) and He(2+) ions in the magnetosphere of the Earth - AMPTE/CCE observations

NASA Technical Reports Server (NTRS)

Kremser, G.; Wilken, B.; Gloeckler, G.; Hamilton, D. C.; Ipavich, F. M.; Kistler, L. M.; Tanskanen, P.

1993-01-01

Data from the ion charge-energy-mass spectrometer CHEM flown on AMPTE/CCE spacecraft are used to investigate the origin, transport, and losses of energetic He(+) and He(2+) ions in the earth's magnetosphere. The L profiles of the average ion phase space density f were determined as a function of the magnetic momentum. It is shown that the L profiles have an inner part, where f increases with L for both He(+) adn He(2+) and where steady-state conditions are fulfilled. The outer boundary L(lim) of this region is located at a distance that depends on the ion species and the geomagnetic activity level. Steady-state conditions continue outside L(lim) for He(+) ions, while the He(2+) ion distribution outside L(lim) is strongly influenced by ion convection causing a lack of steady-state conditions. It is concluded that solar wind is the origin of the He(2+), while a mixed origin is suggested for the He(+) ions, in which the major contribution is from the solar wind via charge exchange production from the He(2+) ions.

Effect of Rare Earth Ions on the Properties of Composites Composed of Ethylene Vinyl Acetate Copolymer and Layered Double Hydroxides

PubMed Central

Wang, Lili; Li, Bin; Zhao, Xiaohong; Chen, Chunxia; Cao, Jingjing

2012-01-01

Background The study on the rare earth (RE)-doped layered double hydroxides (LDHs) has received considerable attention due to their potential applications in catalysts. However, the use of RE-doped LDHs as polymer halogen-free flame retardants was seldom investigated. Furthermore, the effect of rare earth elements on the hydrophobicity of LDHs materials and the compatibility of LDHs/polymer composite has seldom been reported. Methodology/Principal Findings The stearate sodium surface modified Ni-containing LDHs and RE-doped Ni-containing LDHs were rapidly synthesized by a coprecipitation method coupled with the microwave hydrothermal treatment. The influences of trace amounts of rare earth ions La, Ce and Nd on the amount of water molecules, the crystallinity, the morphology, the hydrophobicity of modified Ni-containing LDHs and the adsorption of modifier in the surface of LDHs were investigated by TGA, XRD, TEM, contact angle and IR, respectively. Moreover, the effects of the rare earth ions on the interfacial compatibility, the flame retardancy and the mechanical properties of ethylene vinyl acetate copolymer (EVA)/LDHs composites were also explored in detail. Conclusions/Significance S-Ni0.1MgAl-La displayed more uniform dispersion and better interfacial compatibility in EVA matrix compared with other LDHs. Furthermore, the S-Ni0.1MgAl-La/EVA composite showed the best fire retardancy and mechanical properties in all composites. PMID:22693627

Optical spectroscopy of rare earth ion-doped TiO2 nanophosphors.

PubMed

Chen, Xueyuan; Luo, Wenqin

2010-03-01

Trivalent rare-earth (RE3+) ion-doped TiO2 nanophosphors belong to one kind of novel optical materials and have attracted increasing attention. The luminescence properties of different RE3+ ions in various TiO2 nanomaterials have been reviewed. Much attention is paid to our recent progresses on the luminescence properties of RE3+ (RE = Eu, Er, Sm, Nd) ions in anatase TiO2 nanoparticles prepared by a sol-gel-solvothermal method. Using Eu3+ as a sensitive optical probe, three significantly different luminescence centers of Eu3+ in TiO2 nanoparticles were detected by means of site-selective spectroscopy at 10 K. Based on the crystal-field (CF) splitting of Eu3+ at each site, C2v and D2 symmetries were proposed for Eu3+ incorporated at two lattice sites. A structural model for the formation of multiple sites was proposed based on the optical behaviors of Eu3+ at different sites. Similar multi-site luminescence was observed in Sm(3+)- or Nd(3+)-doped TiO2 nanoparticles. In Eu(3+)-doped TiO2 nanoparticles, only weak energy transfer from the TiO2 host to the Eu3+ ions was observed at 10 K due to the mismatch of energy between the TiO2 band-gap and the Eu3+ excited states. On the contrary, efficient host-sensitized luminescences were realized in Sm(3+)- or Nd(3+)-doped anatase TiO2 nanoparticles due to the match of energy between TiO2 band-gap and the Sm3+ and Nd3+ excited states. The excitation spectra of both Sm(3+)- and Nd(3+)-doped samples exhibit a dominant broad peak centered at approximately 340 nm, which is associated with the band-gap of TiO2, indicating that sensitized emission is much more efficient than direct excitation of the Sm3+ and Nd3+ ions. Single lattice site emission of Er3+ in TiO2 nanocrystals can be achieved by modifying the experimental conditions. Upon excitation by a Ti: sapphire laser at 978 nm, intense green upconverted luminescence was observed. The characteristic emission of Er3+ ions was obtained both in the ultraviolet-visible (UV-vis) and

Absorption and emission spectra of Ga1.7Ge25As8.3S65 glasses doped with rare-earth ions

NASA Astrophysics Data System (ADS)

Lupan, E. V.; Iaseniuc, O. V.; Ciornea, V. I.; Iovu, M. S.

2016-12-01

Excellent optical properties of chalcogenide glasses make them interesting for optoelectronic devices in the visible (VIS) and, especially, in the near- and mid-infrared (NIR and MIR) spectral regions. The rare-earth (RE3+) doped Ga17Ge25As8.3S65 glasses were prepared in evacuated ( 10-5 Pa) silica-glass ampoules which were heated up to 1000 °C at 2-4°C min-1, and then the melt was quenched. The absorption and photoluminescence spectra in the visible and near IR regions for GA1.7Ge25As8.3S65 doped with rare-earth RE+) ions (Sm3+, Nd3+, Pr3+, Dy3+ and co-doped with Ho3++Dy3+) are investigated. The energy transfer of the absorbed light in the broad band Urbach region of the host glass to the RE3+ ions is suggested for increasing the emission efficiency. The investigated Ga17Ge25As8.3S65 glasses doped with RE3+ ions are promising materials for optical amplifiers operating at 1300 and 1500 nm telecommunication windows.

Population gratings in saturable optical fibers with randomly oriented rare-earth ions

NASA Astrophysics Data System (ADS)

Stepanov, S.; Martinez, L. M.; Hernandez, E. H.; Agruzov, P.; Shamray, A.

2015-07-01

Formation of the dynamic population gratings in optical fibers with randomly oriented rare-earth ions is analyzed with a special interest to the grating component for readout with the orthogonal light polarization. It is shown that as compared with a simple model case of the collinearly oriented dipole-like centers their random orientation leads to approximately 2-times growth of the effective saturation power P sat when it is estimated from the incident power dependence of the fiber absorption or from that of the fluorescence intensity. An optimal incident power, for which the maximum of the dynamic population grating amplitude for collinear light polarization is observed, also follows this change in P sat, while formation of the grating for orthogonal polarization needs essentially higher light power. The reduced anisotropy of the active centers, which is in charge of the experimentally observed weakening of the polarization hole burning (PHB) and of the fluorescence polarization, compensates in some way the effect of random ion orientation. The ratio between the maximum conventional (i.e. for the interacting waves collinear polarizations) two-wave mixing (TWM) amplitude and the initial not saturable fiber optical density proves to be, however, nearly the same as in the model case of collinearly oriented dipoles. The ratio between the PHB effect and the amplitude of the anisotropic grating, which is responsible for TWM of the orthogonally polarized waves, is also not influenced significantly by the reduced anisotropy of ions.

Enhanced Scattering of Diffuse Ions on Front of the Earth's Quasi-Parallel Bow Shock: a Case Study

NASA Astrophysics Data System (ADS)

Kis, A.; Matsukiyo, S.; Otsuka, F.; Hada, T.; Lemperger, I.; Dandouras, I. S.; Barta, V.; Facsko, G. I.

2017-12-01

In the analysis we present a case study of three energetic upstream ion events at the Earth's quasi-parallel bow shock based on multi-spacecraft data recorded by Cluster. The CIS-HIA instrument onboard Cluster provides partial energetic ion densities in 4 energy channels between 10 and 32 keV.The difference of the partial ion densities recorded by the individual spacecraft at various distances from the bow shock surface makes possible the determination of the spatial gradient of energetic ions.Using the gradient values we determined the spatial profile of the energetic ion partial densities as a function of distance from the bow shock and we calculated the e-folding distance and the diffusion coefficient for each event and each ion energy range. Results show that in two cases the scattering of diffuse ions takes place in a normal way, as "by the book", and the e-folding distance and diffusion coefficient values are comparable with previous results. On the other hand, in the third case the e-folding distance and the diffusion coefficient values are significantly lower, which suggests that in this case the scattering process -and therefore the diffusive shock acceleration (DSA) mechanism also- is much more efficient. Our analysis provides an explanation for this "enhanced" scattering process recorded in the third case.

Heating of ions to superthermal energies in the topside ionosphere by electrostatic ion cyclotron waves

NASA Technical Reports Server (NTRS)

Ungstrup, E.; Klumpar, D. M.; Heikkila, W. J.

1979-01-01

The soft particle spectrometer on the Isis 2 spacecraft occasionally observes fluxes of ions moving upward out of the ionosphere in the vicinity of the auroral oval. These ion fluxes are characterized by a sharp pitch angle distribution usually peaked at an angle somewhat greater than 90 deg, indicative of particles heated to a large transverse temperature in a narrow range below the spacecraft. The observations are interpreted in terms of electrostatic ion cyclotron waves, which heat the ions to superthermal energies transverse to the earth's magnetic field. When the transverse energy increases, the repulsive force of the earth's magnetic field, proportional to the particle magnetic moment, repels the particles away from the earth.

Simulation of the low earth orbital atomic oxygen interaction with materials by means of an oxygen ion beam

NASA Technical Reports Server (NTRS)

Banks, Bruce A.; Rutledge, Sharon K.; Paulsen, Phillip E.; Steuber, Thomas J.

1989-01-01

Atomic oxygen is the predominant species in low-Earth orbit between the altitudes of 180 and 650 km. These highly reactive atoms are a result of photodissociation of diatomic oxygen molecules from solar photons having a wavelength less than or equal to 2430A. Spacecraft in low-Earth orbit collide with atomic oxygen in the 3P ground state at impact energies of approximately 4.2 to 4.5 eV. As a consequence, organic materials previously used for high altitude geosynchronous spacecraft are severely oxidized in the low-Earth orbital environment. The evaluation of materials durability to atomic oxygen requires ground simulation of this environment to cost effectively screen materials for durability. Directed broad beam oxygen sources are necessary to evaluate potential spacecraft materials performance before and after exposure to the simulated low-Earth orbital environment. This paper presents a description of a low energy, broad oxygen ion beam source used to simulate the low-Earth orbital atomic oxygen environment. The results of materials interaction with this beam and comparison with actual in-space tests of the same meterials will be discussed. Resulting surface morphologies appear to closely replicate those observed in space tests.

A novel fluorescent probe (dtpa-bis(cytosine)) for detection of Eu(III) in rare earth metal ions.

PubMed

Yang, Fan; Ren, Peipei; Liu, Guanhong; Song, Youtao; Bu, Naishun; Wang, Jun

2018-03-15

In this paper, a novel fluorescent probe, dtpa-bis(cytosine), was designed and synthesized for detecting europium (Eu 3+ ) ion. Upon addition of Eu 3+ ions into the dtpa-bis(cytosine) solution, the fluorescence intensity can strongly be enhanced. Conversely, adding other rare earth metal ions, such as Y 3+ , Ce 3+ , Pr 3+ , Nd 3+ , Sm 3+ , Gd 3+ , Tb 3+ , Dy 3+ , Ho 3+ , Er 3+ , Yb 3+ and Lu 3+ , into dtpa-bis(cytosine) solution, the fluorescence intensity is decreased slightly. Some parameters affecting the fluorescence intensity of dtpa-bis(cytosine) solution in the presence of Eu 3+ ions were investigated, including solution pH value, Eu 3+ ion concentration and interfering substances. The detection mechanism of Eu 3+ ion using dtpa-bis(cytosine) as fluorescent probe was proposed. Under optimum conditions, the fluorescence emission intensities of Eu III -dtpa-bis(cytosine) at 375nm in the concentration range of 0.50×10 -5 mol∙L -1 -5.00×10 -5 mol∙L -1 of Eu 3+ ion display a better linear relationship. The limit of detection (LOD) was determined as 8.65×10 -7 mol∙L -1 and the corresponding correlation coefficient (R 2 ) of the linear equation is 0.9807. It is wished that the proposed method could be applied for sensitively and selectively detecting Eu 3+ ion. Copyright © 2017 Elsevier B.V. All rights reserved.

First simultaneous detection of terrestrial ionospheric molecular ions in the Earth's inner magnetosphere and at the Moon

NASA Astrophysics Data System (ADS)

Dandouras, Iannis; Poppe, Andrew R.; Fillingim, Matt O.; Kistler, Lynn M.; Mouikis, Christopher G.; Rème, Henri

2017-04-01

Heavy molecular ions escaping from a planetary atmosphere can contribute to the long-term evolution of its composition. The ARTEMIS (Acceleration, Reconnection, Turbulence, and Electrodynamics of the Moon's Interaction with the Sun) spacecraft has recently observed outflowing molecular ions at lunar distances in the terrestrial magnetotail (Poppe et al., 2016). Backward particle tracing indicated that these ions should originate from the terrestrial inner magnetosphere. Here we have examined Cluster data acquired by the CIS-CODIF (Cluster Ion Spectrometry-Composition Distribution Function) ion mass spectrometer, obtained in the terrestrial magnetosphere. An event was selected where the orbital conditions were favourable and the Cluster spacecraft were in the high-latitude inner magnetosphere a few hours before the ARTEMIS molecular ion detection. Analysis shows that the CIS-CODIF instrument detected a series of energetic ion species, including not only O+ but also a group of molecular ions around 30 amu. Given the 5-7 m/Δm mass resolution of the instrument, these could include N2+, NO+, or O2+. These ions were detected by Cluster about 14 hours before the ARTEMIS observation in the lunar environment, a time which is compatible with the transfer to lunar distances. The event was during an active period followed by a northward rotation of the IMF. Although energetic heavy molecular ions have been detected in the storm time magnetosphere in the past (e.g. Klecker et al., 1986; Christon et al., 1994), this event constitutes the first coordinated observation in the Earth's inner magnetosphere and at the Moon. Additional events of coordinated outflowing molecular ion observations are currently under analysis. Future missions, as the proposed ESCAPE mission, should investigate in detail the mechanisms of molecular ion acceleration and escape, their link to the solar and magnetospheric activity, and their role in the magnetospheric dynamics and in the long-term evolution

Large-payload earth-orbit transportation with electric propulsion

NASA Technical Reports Server (NTRS)

Stearns, J. W.

1976-01-01

Economical unmanned earth orbit transportation for large payloads is evaluated. The high exhaust velocity achievable with electric propulsion is attractive because it minimizes the propellant that must be carried to low earth orbit. Propellant transport is a principal cost item. Electric propulsion subsystems utilizing advanced ion thrusters are compared to magnetoplasmadynamic (MPD) thrust subsystems. For very large payloads, a large lift vehicle is needed to low earth orbit, and argon propellant is required for electric propulsion. Under these circumstances, the MPD thruster is shown to be desirable over the ion thruster for earth orbit transportation.

Sol-gel-derived hybrid materials multi-doped with rare-earth metal ions

NASA Astrophysics Data System (ADS)

Zelazowska, E.; Rysiakiewicz-Pasek, E.; Borczuch-Laczka, M.; Cholewa-Kowalska, K.

2012-06-01

Four different hybrid organic-inorganic materials based on TiO2-SiO2 matrices with organic additives and doped with rare-earth metal ions (III) from the group of europium, cerium, terbium, neodymium, dysprosium and samarium, were synthesized by sol-gel method. Tetraethyl orthosilicate, titanium (IV) isopropoxide and organic compounds, such as butyl acrylate, butyl methacrylate, ethyl acetoacetate, ethylene glycol dimethacrylate, ethyl acetate, propylene carbonate, organic solvents and certain inorganic salts were used in the synthesis. The inorganic part of the sols, which were used in the synthesis of all the hybrid materials, was prepared separately and then the organic parts were added. The materials obtained were aged for three weeks at room temperature and then heated in an electric oven for three hours at temperatures of 80 °C-150 °C. Scanning electron microscopy equipped with energy dispersive X-ray spectroscopy (SEM/EDX); X-ray diffraction (XRD); Fourier transform infrared spectroscopy (KBr technique); 29Si magic-angle spinning nuclear magnetic resonance; and fluorescence spectroscopy were used for the examination of morphology, microstructure and luminescence properties, respectively. Photoluminescence properties with relatively intense narrow emission lines of Tb, Eu, Dy, Nd, Sm respectively to the RE-ions doping, were observed for all the hybrid materials.

Effect of upstream ULF waves on the energetic ion diffusion at the earth's foreshock: Theory, Simulation, and Observations

NASA Astrophysics Data System (ADS)

Otsuka, F.; Matsukiyo, S.; Kis, A.; Hada, T.

2017-12-01

Spatial diffusion of energetic particles is an important problem not only from a fundamental physics point of view but also for its application to particle acceleration processes at astrophysical shocks. Quasi-linear theory can provide the spatial diffusion coefficient as a function of the wave turbulence spectrum. By assuming a simple power-law spectrum for the turbulence, the theory has been successfully applied to diffusion and acceleration of cosmic rays in the interplanetary and interstellar medium. Near the earth's foreshock, however, the wave spectrum often has an intense peak, presumably corresponding to the upstream ULF waves generated by the field-aligned beam (FAB). In this presentation, we numerically and theoretically discuss how the intense ULF peak in the wave spectrum modifies the spatial parallel diffusion of energetic ions. The turbulence is given as a superposition of non-propagating transverse MHD waves in the solar wind rest frame, and its spectrum is composed of a piecewise power-law spectrum with different power-law indices. The diffusion coefficients are then estimated by using the quasi-linear theory and test particle simulations. We find that the presence of the ULF peak produces a concave shape of the diffusion coefficient when it is plotted versus the ion energy. The results above are used to discuss the Cluster observations of the diffuse ions at the Earth's foreshock. Using the density gradients of the energetic ions detected by the Cluster spacecraft, we determine the e-folding distances, equivalently, the spatial diffusion coefficients, of ions with their energies from 10 to 32 keV. The observed e-folding distances are significantly smaller than those estimated in the past statistical studies. This suggests that the particle acceleration at the foreshock can be more efficient than considered before. Our test particle simulation explains well the small estimate of the e-folding distances, by using the observed wave turbulence spectrum

METHOD OF SEPARATING RARE EARTHS BY ION EXCHANGE

DOEpatents

Spedding, F.H.; Powell, J.E.

1960-10-18

A process is given for separating yttrium and rare earth values having atomic numbers of from 57 through 60 and 68 through 71 from an aqueous solution whose pH value can range from 1 to 9. All rare earths and yttrium are first adsorbed on a cation exchange resin, and they are then eluted with a solution of N-hydroxyethylethylenediaminetriacetic acid (HEDTA) in the order of decreasing atomic number, yttrium behaving like element 61; the effluents are collected in fractions. The HEDTA is recovered by elution with ammonia solution and the resin is regenerated with sulfuric acid. Rare earths are precipitated from the various effluents with oxalic acid, and each supernatant is passed over cation exchange resin for adsorption of HEDTA and nonprecipitated rare earths: the oxalic acid is not retained by the resin.

Physical and electrochemical properties of alkaline earth doped, rare earth vanadates

NASA Astrophysics Data System (ADS)

Adijanto, Lawrence; Balaji Padmanabhan, Venu; Holmes, Kevin J.; Gorte, Raymond J.; Vohs, John M.

2012-06-01

The effect of partial substitution of alkaline earth (AE) ions, Sr2+ and Ca2+, for the rare earth (RE) ions, La3+, Ce3+, Pr3+, and Sm3+, on the physical properties of REVO4 compounds were investigated. The use of the Pechini method to synthesize the vanadates allowed for high levels of AE substitution to be obtained. Coulometric titration was used to measure redox isotherms for these materials and showed that the addition of the AE ions increased both reducibility and electronic conductivity under typical solid oxide fuel cell (SOFC) anode conditions, through the formation of compounds with mixed vanadium valence. In spite of their high electronic conductivity, REVO4-yttira stabilized zirconia (YSZ) composite anodes exhibited only modest performance when used in SOFCs operating with H2 fuel at 973 K due to their low catalytic activity. High performance was obtained, however, after the addition of a small amount of catalytically active Pd to the anode.

Radiative and Nonradiative Transitions of the Rare-Earth Ions Tm(3+) and Ho(3+) in Y3AI5O12 and LiYF4

NASA Technical Reports Server (NTRS)

Walsh, Brian M.; Armagan, Guzin; Dibartolo, Baldassare; Modlin, Edward A.

1995-01-01

The optical spectra of rare earth ions in solids arise primarily from electric and magnetic dipole transitions between stark split multiplets of the 4f(sup N) electronic configuration. Electric dipole transitions are parity forbidden between levels of the 4f(sup N) configuration, while those of magnetic dipole origin are allowed. It is known from experiment, however, that the significant contributions to the intensities of most transitions are electric dipole in nature. Judd and Ofelt developed the theory of forced electric dipole transitions of rare-earth ions. This study is devoted to determining electric dipole transition probabilities and branching ratios for Tm(3+) and Ho(3+) ions in Yttrium Aluminum Garnet (YAG) and Yttrium Lithium Fluoride (YLF) using the theory of Judd and Ofelt. The radiative rates determined from the Judd-Ofelt analysis are used with measured lifetimes to find nonradiative rates of relaxation.

Ion transport and loss in the earth's quiet ring current. I - Data and standard model

NASA Technical Reports Server (NTRS)

Sheldon, R. B.; Hamilton, D. C.

1993-01-01

A study of the transport and loss of ions in the earth's quiet time ring current, in which the standard radial diffusion model developed for the high-energy radiation belt particles is compared with the measurements of the lower-energy ring current ions, is presented. The data set provides ionic composition information in an energy range that includes the bulk of the ring current energy density, 1-300 keV/e. Protons are found to dominate the quiet time energy density at all altitudes, peaking near L of about 4 at 60 keV/cu cm, with much smaller contributions from O(+) (1-10 percent), He(+) (1-5 percent), and He(2+) (less than 1 percent). A minimization procedure is used to fit the amplitudes of the standard electric radial diffusion coefficient, yielding 5.8 x 10 exp -11 R(E-squared)/s. Fluctuation ionospheric electric fields are suggested as the source of the additional diffusion detected.

Rare-Earth Ion-Host Lattice Interactions: 15. Analysis of the Spectra of Nd3+ in Gd3Sc2Ga3O12.

DTIC Science & Technology

1984-05-01

Luminescence of Cr3+ Ions in Gadolinium Gallium and Gadolinium Scandium Gallium Garnet CT’stals, Soy. J. Quant. Electron. 12 (1982), 1124. 6M. Dutoit, J. C...Shcherbakov, Absolute Quantum Efficiency of the Luminescence of Cr3+ Ions in Gadolinium Gallium and Gadolinium Scandium Gallium Garnet Crystals, Soy. J...HDL Project: 324332 19. KEY WORDS (Continue on reverse side it necessary end Identify by block number) Rare earth Mixed garnet Spectra Laser Judd-Ofelt

Effects of chemical and hydrostatic pressures on structural, magnetic, and electronic properties of R2NiMn O6 (R =rare -earth ion ) double perovskites

NASA Astrophysics Data System (ADS)

Zhao, Hong Jian; Liu, Xiao Qiang; Chen, Xiang Ming; Bellaiche, L.

2014-11-01

The effects of chemical and hydrostatic pressures on structural, magnetic, and electronic properties of R2NiMn O6 double perovskites, with R being a rare-earth ion, have been systematically studied by using specific first-principles calculations. These latter reproduce well the correlation between several properties (e.g., lattice parameters, Ni-O-Mn bond angles, magnetic Curie temperature, and electronic band gap) and the rare-earth ionic radius (i.e., the chemical pressure). They also provide novel predictions awaiting experimental confirmation, such as (i) that many physical quantities respond in dramatically different manners to chemical versus hydrostatic pressure, unlike as commonly thought for perovskites containing rare-earth ions, and (ii) a dependence of antipolar displacements on chemical and hydrostatic pressures, which would further explain why the recently predicted electrical polarization of L a2NiMn O6/R2NiMn O6 superlattices [H. J. Zhao, W. Ren, Y. Yang, J. Íñiguez, X. M. Chen, and L. Bellaiche, Nat. Commun. 5, 4021 (2014), 10.1038/ncomms5021] can be created and controlled by playing with the rare-earth element.

Structure and ionic diffusion of alkaline-earth ions in mixed cation glasses A 2O–2MO–4SiO 2 with molecular dynamics simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Konstantinou, Konstantinos; Sushko, Petr; Duffy, Dorothy M.

2015-05-15

A series of mixed cation silicate glasses of the composition A2O – 2MO – 4SiO2, with A=Li,Na,K and M=Ca,Sr,Ba has been investigated by means of molecular dynamics simulations in order to understand the effect of the nature of the cations on the mobility of the alkaline-earth ions within the glass network. The size of the alkaline-earth cation was found to affect the inter-atomic distances, the coordination number distributions and the bond angle distributions , whereas the medium-range order was almost unaffected by the type of the cation. All the alkaline-earth cations contribute to lower vibrational frequencies but it is observedmore » that that there is a shift to smaller frequencies and the vibrational density of states distribution gets narrower as the size of the alkaline-earth increases. The results from our modeling for the ionic diffusion of the alkaline-earth cations are in a qualitative agreement with the experimental observations in that there is a distinct correlation between the activation energy for diffusion of alkaline earth-ions and the cation radii ratio. An asymmetrical linear behavior in the diffusion activation energy with increasing size difference is observed. The results can be described on the basis of a theoretical model that relates the diffusion activation energy to the electrostatic interactions of the cations with the oxygens and the elastic deformation of the silicate network.« less

Effects of dust polarity and nonextensive electrons on the dust-ion acoustic solitons and double layers in earth atmosphere

NASA Astrophysics Data System (ADS)

Ghobakhloo, Marzieh; Zomorrodian, Mohammad Ebrahim; Javidan, Kurosh

2018-05-01

Propagation of dustion acoustic solitary waves (DIASWs) and double layers is discussed in earth atmosphere, using the Sagdeev potential method. The best model for distribution function of electrons in earth atmosphere is found by fitting available data on different distribution functions. The nonextensive function with parameter q = 0.58 provides the best fit on observations. Thus we analyze the propagation of localized waves in an unmagnetized plasma containing nonextensive electrons, inertial ions, and negatively/positively charged stationary dust. It is found that both compressive and rarefactive solitons as well as double layers exist depending on the sign (and the value) of dust polarity. Characters of propagated waves are described using the presented model.

Ion acoustic waves in the solar wind

NASA Technical Reports Server (NTRS)

Gurnett, D. A.; Frank, L. A.

1978-01-01

Plasma wave measurements on the Helios 1 and 2 spacecraft have revealed the occurrence of electric field turbulence in the solar wind at frequencies between the electron and ion plasma frequencies. Wavelength measurements with the Imp 6 spacecraft now provide strong evidence that these waves are shortwavelength ion acoustic waves which are Doppler-shifted upward in frequency by the motion of the solar wind. Comparison of the Helios results with measurements from the earth-orbiting Imp 6 and 8 spacecraft shows that the ion acoustic wave turbulence detected in interplanetary space has characteristics essentially identical to those of bursts of electrostatic turbulence generated by protons streaming into the solar wind from the earth's bow shock. In a few cases, enhanced ion acoustic wave intensities have been observed in direct association with abrupt increases in the anisotropy of the solar wind electron distribution. This relationship strongly suggests that the ion acoustic waves detected by Helios far from the earth are produced by an electron heat flux instability, as was suggested by Forslund. Possible related mechanisms which could explain the generation of ion acoustic waves by protons streaming into the solar wind from the earth's bow shock are also considered.

Meteoric Ions in Planetary Ionospheres

NASA Technical Reports Server (NTRS)

Pesnell, W. D.; Grebowsky, Joseph M.; Vondrak, Richard R. (Technical Monitor)

2001-01-01

Solar system debris, in the form of meteoroids, impacts every planet. The flux, relative composition and speed of the debris at each planet depends on the planet's size and location in the solar system. Ablation in the atmosphere evaporates the meteoric material and leaves behind metal atoms. During the ablation process metallic ions are formed by impact ionization. For small inner solar system planets, including Earth, this source of ionization is typically small compared to either photoionization or charge exchange with ambient molecular ions. For Earth, the atmosphere above the main deposition region absorbs the spectral lines capable of ionizing the major metallic atoms (Fe and Mg) so that charge exchange with ambient ions is the dominant source. Within the carbon dioxide atmosphere of Mars (and possibly Venus), photoionization is important in determining the ion density. For a heavy planet like Jupiter, far from the sun, impact ionization of ablated neutral atoms by impacts with molecules becomes a prominent source of ionization due to the gravitational acceleration to high incident speeds. We will describe the processes and location and extent of metal ion layers for Mars, Earth and Jupiter, concentrating on flagging the uncertainties in the models at the present time. This is an important problem, because low altitude ionosphere layers for the planets, particularly at night, probably consist predominantly of metallic ions. Comparisons with Earth will be used to illustrate the differing processes in the three planetary atmospheres.

Some Rare Earth Elements Analysis by Microwave Plasma Torch Coupled with the Linear Ion Trap Mass Spectrometry

PubMed Central

Xiong, Xiaohong; Jiang, Tao; Qi, Wenhao; Zuo, Jun; Yang, Meiling; Fei, Qiang; Xiao, Saijin; Yu, Aimin; Zhu, Zhiqiang; Chen, Huanwen

2015-01-01

A sensitive mass spectrometric analysis method based on the microwave plasma technique is developed for the fast detection of trace rare earth elements (REEs) in aqueous solution. The plasma was produced from a microwave plasma torch (MPT) under atmospheric pressure and was used as ambient ion source of a linear ion trap mass spectrometer (LTQ). Water samples were directly pneumatically nebulized to flow into the plasma through the central tube of MPT. For some REEs, the generated composite ions were detected in both positive and negative ion modes and further characterized in tandem mass spectrometry. Under the optimized conditions, the limit of detection (LOD) was at the level 0.1 ng/mL using MS2 procedure in negative mode. A single REE analysis can be completed within 2~3 minutes with the relative standard deviation ranging between 2.4% and 21.2% (six repeated measurements) for the 5 experimental runs. Moreover, the recovery rates of these REEs are between the range of 97.6%–122.1%. Two real samples have also been analyzed, including well and orange juice. These experimental data demonstrated that this method is a useful tool for the field analysis of REEs in water and can be used as an alternative supplement of ICP-MS. PMID:26421013

Structural and Dynamical Properties of Alkaline Earth Metal Halides in Supercritical Water: Effect of Ion Size and Concentration.

PubMed

Keshri, Sonanki; Tembe, B L

2017-11-22

Constant temperature-constant pressure molecular dynamics simulations have been performed for aqueous alkaline earth metal chloride [M 2+ -Cl - (M = Mg, Ca, Sr, and Ba)] solutions over a wide range of concentrations (0.27-5.55 m) in supercritical (SC) and ambient conditions to investigate their structural and dynamical properties. A strong influence of the salt concentration is observed on the ion-ion pair correlation functions in both ambient and SC conditions. In SC conditions, significant clustering is observed in the 0.27 m solution, whereas the reverse situation is observed at room temperature and this is also supported by the residence times of the clusters. The concentration and ion size (cation size) seem to have opposite effects on the average number of hydrogen bonds. The simulation results show that the self-diffusion coefficients of water, cations, and the chloride ion increase with increasing temperature, whereas they decrease with increasing salt concentration. The cluster size distribution shows a strong density dependence in both ambient and SC conditions. In SC conditions, cluster sizes display a near-Gaussian distribution, whereas the distribution decays monotonically in ambient conditions.

Rare Earth Garnet Selective Emitter

NASA Technical Reports Server (NTRS)

Lowe, Roland A.; Chubb, Donald L.; Farmer, Serene C.; Good, Brian S.

1994-01-01

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approx. = 0.75, sup 4)|(sub 15/2) - (sup 4)|(sub 13/2),for Er-YAG and epsilon(sub lambda) approx. = 0.65, (sup 5)|(sub 7) - (sup 5)|(sub 8) for Ho-YAG) at 1500 K. In addition, low out-of-band spectral emittance, epsilon(sub lambda) less than 0.2, suggest these materials would be excellent candidates for high efficiency selective emitters in thermophotovoltaic (TPV) systems operating at moderate temperatures (1200-1500 K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. Selective emitters in the near IR are of special interest for thermophotovoltaic (TPV) energy conversion. The most promising solid selective emitters for use in a TPV system are rare earth oxides. Early spectral emittance work on rare earth oxides showed strong emission bands in the infrared (0.9 - 3 microns). However, the emittance outside the emission band was also significant and the efficiency of these emitters was low. Recent improvements in efficiency have been made with emitters fabricated from fine (5 - 10 microns) rare earth oxide fibers similar to the Welsbach mantle used in gas lanterns. However, the rare earth garnet emitters are more rugged than the mantle type emitters. A thin film selective emitter on a low emissivity substrate such as gold, platinum etc., is rugged and easily adapted to a wide variety of thermal sources. The garnet structure and its many subgroups have been successfully used as hosts for rare earth ions, introduced as substitutional

A scenario for solar wind penetration of earth's magnetic tail based on ion composition data from the ISEE 1 spacecraft

NASA Technical Reports Server (NTRS)

Lennartsson, W.

1992-01-01

Based on He(2+) and H(-) ion composition data from the Plasma Composition Experiment on ISEE 1, a scenario is proposed for the solar wind penetration of the earth's magnetic tail, which does not require that the solar wind plasma be magnetized. While this study does not take issue with the notion that earth's magnetic field merges with the solar wind magnetic field on a regular basis, it focuses on certain aspects of interaction between the solar wind particles and the earth's field, e.g, the fact that the geomagnetic tail always has a plasma sheet, even during times when the physical signs of magnetic merging are weak or absent. It is argued that the solar plasma enters along slots between the tail lobes and the plasma sheet, even quite close to earth, convected inward along the plasma sheet boundary layer or adjacent to it, by the electric fringe field of the ever present low-latitude magnetopause boundary layer (LLBL). The required E x B drifts are produced by closing LLBL equipotential surfaces through the plasma sheet.

Uniform surface modification of diatomaceous earth with amorphous manganese oxide and its adsorption characteristics for lead ions

NASA Astrophysics Data System (ADS)

Li, Song; Li, Duanyang; Su, Fei; Ren, Yuping; Qin, Gaowu

2014-10-01

A novel method to produce composite sorbent material compromising porous diatomaceous earth (DE) and surface functionalized amorphous MnO2 is reported. Via a simple in situ redox reaction over the carbonized DE powders, a uniform layer of amorphous MnO2 was anchored onto the DE surface. The hybrid adsorbent was characterized by X-ray diffraction, scanning electron microscopy, and infrared spectroscopy. The batch method has been employed to investigate the effects of surface coating on adsorption performance of DE. According to the equilibrium studies, the adsorption capacity of DE for adsorbing lead ions after MnO2 modification increased more than six times. And the adsorption of Pb2+ on the MnO2 surface is based on ion-exchange mechanism. The developed strategy presents a novel opportunity to prepare composite adsorbent materials by integrating nanocrystals with porous matrix.

Low Temperature Life-cycle Testing of a Lithium-ion Battery for Low-earth-orbiting Spacecraft

NASA Technical Reports Server (NTRS)

Reid, Concha

2004-01-01

A flight-qualified, lithium-ion (Li-ion) battery developed for the Mars Surveyor Program 2001 lander is undergoing life-testing at low temperature under a low-Earth-orbit (LEO) profile to assess its capability to provide long term energy storage for aerospace missions. NASA has embarked upon an ambitious course to return humans to the moon by 2015-2020 in preparation for robotic and human exploration of Mars and robotic exploration of the moons of outer planets. Li-ion batteries are excellent candidates to provide power and energy storage for multiple aspects of these missions due to their low specific energy, low energy density, and excellent low temperature performance. Laboratory testing of Li-ion technology is necessary in order to assess lifetime, characterize multi-cell battery-level performance under aerospace conditions, and to gauge safety aspects of the technology. Life-cycle testing provides an opportunity to examine battery-level performance and the dynamics of individual cells in the stack over the entire life of the battery. Data generated through this testing will be critical to establish confidence in the technology for its widespread use in manned and unmanned mission. This paper discusses the performance of the 28 volt, 25 ampere-hour battery through 6000 LEO cycles, which corresponds to one year on LEO orbit. Testing is being performed at 0 C and 40% depth-of-discharge. Individual cell behaviors and their effect on the performance of the battery are described. Capacity, impedance, energy efficiency and end-of-discharge voltage at 1000 cycle intervals are reported. Results from this life-testing will help contribute to the database on battery-level performance of aerospace Li-ion batteries and low temperature cycling under LEO conditions.

Rare Earth Ion-Doped Upconversion Nanocrystals: Synthesis and Surface Modification

PubMed Central

Chang, Hongjin; Xie, Juan; Zhao, Baozhou; Liu, Botong; Xu, Shuilin; Ren, Na; Xie, Xiaoji; Huang, Ling; Huang, Wei

2014-01-01

The unique luminescent properties exhibited by rare earth ion-doped upconversion nanocrystals (UCNPs), such as long lifetime, narrow emission line, high color purity, and high resistance to photobleaching, have made them widely used in many areas, including but not limited to high-resolution displays, new-generation information technology, optical communication, bioimaging, and therapy. However, the inherent upconversion luminescent properties of UCNPs are influenced by various parameters, including the size, shape, crystal structure, and chemical composition of the UCNPs, and even the chosen synthesis process and the surfactant molecules used. This review will provide a complete summary on the synthesis methods and the surface modification strategies of UCNPs reported so far. Firstly, we summarize the synthesis methodologies developed in the past decades, such as thermal decomposition, thermal coprecipitation, hydro/solvothermal, sol-gel, combustion, and microwave synthesis. In the second part, five main streams of surface modification strategies for converting hydrophobic UCNPs into hydrophilic ones are elaborated. Finally, we consider the likely directions of the future development and challenges of the synthesis and surface modification, such as the large-scale production and actual applications, stability, and so on, of the UCNPs. PMID:28346995

Physical and optical absorption studies of Fe{sup 3+} - ions doped lithium borate glasses containing certain alkaline earths

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhogi, Ashok; Kumar, R. Vijaya; Kistaiah, P., E-mail: pkistaiah@yahoo.com

Iron ion doped lithium borate glasses with the composition 15RO-25Li{sub 2}O-59B{sub 2}O{sub 3}-1Fe{sub 2}O{sub 3} (where R= Ca, Sr and Ba) have been prepared by the conventional melt quenching technique and characterized to investigate the physical and optical properties using XRD, density, molar volume and UV-Visible spectroscopy. The optical absorption spectra exhibit a band at around 460 nm which is assigned to {sup 6}A{sub 1g}(S) → 4E{sub g} (G) of Fe{sup 3+} ions with distorted octahedral symmetry. From ultraviolet absorption edges, the optical band gap and Urbach energies have been evaluated. The effect of alkaline earths on these properties ismore » discussed.« less

Energetic O+ and H+ Ions in the Plasma Sheet: Implications for the Transport of Ionospheric Ions

NASA Technical Reports Server (NTRS)

Ohtani, S.; Nose, M.; Christon, S. P.; Lui, A. T.

2011-01-01

The present study statistically examines the characteristics of energetic ions in the plasma sheet using the Geotail/Energetic Particle and Ion Composition data. An emphasis is placed on the O+ ions, and the characteristics of the H+ ions are used as references. The following is a summary of the results. (1) The average O+ energy is lower during solar maximum and higher during solar minimum. A similar tendency is also found for the average H+ energy, but only for geomagnetically active times; (2) The O+ -to -H+ ratios of number and energy densities are several times higher during solar maximum than during solar minimum; (3) The average H+ and O+ energies and the O+ -to -H+ ratios of number and energy densities all increase with geomagnetic activity. The differences among different solar phases not only persist but also increase with increasing geomagnetic activity; (4) Whereas the average H+ energy increases toward Earth, the average O+ energy decreases toward Earth. The average energy increases toward dusk for both the H+ and O+ ions; (5) The O+ -to -H+ ratios of number and energy densities increase toward Earth during all solar phases, but most clearly during solar maximum. These results suggest that the solar illumination enhances the ionospheric outflow more effectively with increasing geomagnetic activity and that a significant portion of the O+ ions is transported directly from the ionosphere to the near ]Earth region rather than through the distant tail.

Ion transport and loss in the Earth's quiet ring current. 2: Diffusion and magnetosphere-ionosphere coupling

NASA Technical Reports Server (NTRS)

Sheldon, R. B.

1994-01-01

We have studied the transport and loss of H(+), He(+), and He(++) ions in the Earth's quiet time ring current (1 to 300 keV/e, 3 to 7 R(sub E), Kp less than 2+, absolute value of Dst less than 11, 70 to 110 degs pitchangles, all LT) comparing the standard radial diffusion model developed for the higher-energy radiation belt particles with measurements of the lower energy ring current ions in a previous paper. Large deviations of that model, which fit only 50% of the data to within a factor of 10, suggested that another transport mechanism is operating in the ring current. Here we derive a modified diffusion coefficient corrected for electric field effects on ring current energy ions that fit nearly 80% of the data to within a factor of 2. Thus we infer that electric field fluctuations from the low-latitude to midlatitude ionosphere (ionospheric dynamo) dominated the ring current transport, rather than high-latitude or solar wind fluctuations. Much of the remaining deviation may arise from convective electric field transport of the E less than 30 keV particles. Since convection effects cannot be correctly treated with this azimuthally symmetric model, we defer treatment of the lowest-energy ions to a another paper. We give chi(exp 2) contours for the best fit, showing the dependence of the fit upon the internal/external spectral power of the predicted electric and magnetic field fluctuations.

Synthesis and characterization of rare-earth-doped calcium tungstate nanocrystals

NASA Astrophysics Data System (ADS)

Suneeta, P.; Rajesh, Ch.; Ramana, M. V.

2018-02-01

In this paper, we report synthesis and characterization of rare-earth-ion-doped calcium tungstate (CaWO4) nanocrystals (NCs). Rare-earth ions, such as gadolinium (Gd), neodymium (Nd), praseodymium (Pr), samarium (Sm) and holmium (Ho), were successfully doped in the CaWO4 NCs by changing the synthesis conditions. The adopted synthesis route was found to be fast and eco-friendly. Structural characterizations, such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and compositional analysis, were performed using energy dispersive analysis of X-rays (EDAX) on as-synthesized NCs. The results indicate the size of the NCs ranging between 47 to 68nm and incorporation of rare-earth ions in CaWO4 NCs.

The manipulated left-handedness in a rare-earth-ion-doped optical fiber by the incoherent pumping field

NASA Astrophysics Data System (ADS)

Zhao, Shun-Cai; Guo, Hong-Wei; Wei, Xiao-Jing

2017-10-01

The left-handedness was demonstrated by the simulation with a three-level quantum system in an Er3+ -dopped ZrF4-BaF2-LaF3- AlF3-NaF (ZBLAFN) optical fiber. And the left-handedness can be regulated by the incoherent pumping field. Our scheme may provide a solid candidate other than the coherent atomic vapor for left-handedness, and may extend the application of the rare-earth-ion-doped optical fiber in metamaterials and of the incoherent pumping light field in quantum optics.

Modeling the near-Earth interaction between ring current ions and exospheric neutrals: escape through energetic neutral atoms (ENAs)

NASA Astrophysics Data System (ADS)

LLera, K.; Goldstein, J.; McComas, D. J.; Valek, P. W.

2016-12-01

The two major loss processes for ring current decay are precipitation and energetic neutral atoms (ENAs). Since the exospheric neutral density increases with decreasing altitudes, precipitating ring current ions (reaching down to 200 - 800 km in altitude) also produce low-altitude ENA signatures that can be stronger than the ring current emission at equatorial distances ( 2 - 9 Re). The higher density results in multiple collisions between the ring current ions and exospheric oxygen. The affect on hydrogen ions is the focus of this study. Since the H particle sustains energy loss ( 36 eV) at each neutralizing or re-ionizing interaction, the escaped ENAs do not directly reflect the ring current properties. We model the energy loss due to multiple charge exchange and electron stripping interactions of 1 - 100 keV precipitating ring current ions undergo before emerging as low-altitude ENAs. The H particle is either an ion or an ENA throughout the simulation. Their lifetime is analytically determined by the length of one mean free path. We track the ion state with Lorentz motion while the ENA travels ballistically across the geomagnetic field. Our simulations show the energy loss is greater than 20% for hydrogen ring current ions below 30 keV (60 keV for the simulations that wander equatorward). This is the first quantification of the energy loss associated with the creation of low-altitude ENAs. Our model (currently constrained in the meridional plane) has revealed characteristics on how precipitation is affected by the near-Earth neutral exosphere. This ion-neutral interaction removes particles from the loss cone but promotes loss through ENA generation. These findings should be implemented in models predicting the ring current decay and used as an analysis tool to reconstruct the ring current population from observed low-altitude ENAs.

Tuning the Origin of Magnetic Relaxation by Substituting the 3d or Rare-Earth Ions into Three Isostructural Cyano-Bridged 3d-4f Heterodinuclear Compounds.

PubMed

Zhang, Yan; Guo, Zhen; Xie, Shuang; Li, Hui-Li; Zhu, Wen-Hua; Liu, Li; Dong, Xun-Qing; He, Wei-Xun; Ren, Jin-Chao; Liu, Ling-Zhi; Powell, Annie K

2015-11-02

Three isostructural cyano-bridged 3d-4f compounds, [YFe(CN)6(hep)2(H2O)4] (1), [DyFe(CN)6(hep)2(H2O)4] (2), and [DyCo(CN)6(hep)2(H2O)4] (3), were successfully assembled by site-targeted substitution of the 3d or rare-earth ions. All compounds have been structurally characterized to display slightly distorted pentagonal-bipyramidal local coordination geometry around the rare-earth ions. Magnetic analyses revealed negligible magnetic coupling in compound 1, antiferromagnetic intradimer interaction in 2, and weak ferromagnetic coupling through dipolar-dipolar interaction in 3. Under an applied direct-current (dc) field, 1 (Hdc = 2.5 kOe, τ0 = 1.3 × 10(-7) s, and Ueff/kB = 23 K) and 3 (Hdc = 2.0 kOe, τ0 = 7.1 × 10(-11) s, and Ueff/kB = 63 K) respectively indicated magnetic relaxation behavior based on a single [Fe(III)]LS ion and a Dy(III) ion; nevertheless, 2 (Hdc = 2.0 kOe, τ0 = 9.7 × 10(-8) s, and Ueff/kB = 23 K) appeared to be a single-molecule magnet based on a cyano-bridged DyFe dimer. Compound 1, which can be regarded as a single-ion magnet of the [Fe(III)]LS ion linked to a diamagnetic Y(III) ion in a cyano-bridged heterodimer, represents one of the rarely investigated examples based on a single Fe(III) ion explored in magnetic relaxation behavior. It demonstrated that the introduction of intradimer magnetic interaction of 2 through a cyano bridge between Dy(III) and [Fe(III)]LS ions negatively affects the energy barrier and χ″(T) peak temperature compared to 3.

The Earth's Plasmasphere

NASA Technical Reports Server (NTRS)

Gallagher, D. L.

2015-01-01

The Earth's plasmasphere is an inner part of the magneteosphere. It is located just outside the upper ionosphere located in Earth's atmosphere. It is a region of dense, cold plasma that surrounds the Earth. Although plasma is found throughout the magnetosphere, the plasmasphere usually contains the coldest plasma. Here's how it works: The upper reaches of our planet's atmosphere are exposed to ultraviolet light from the Sun, and they are ionized with electrons that are freed from neutral atmospheric particles. The results are electrically charged negative and positive particles. The negative particles are electrons, and the positive particles are now called ions (formerly atoms and molecules). If the density of these particles is low enough, this electrically charged gas behaves differently than it would if it were neutral. Now this gas is called plasma. The atmospheric gas density becomes low enough to support the conditions for a plasma around earth at about 90 kilometers above Earth's surface. The electrons in plasma gain more energy, and they are very low in mass. They move along Earth's magnetic field lines and their increased energy is enough to escape Earth's gravity. Because electrons are very light, they don't have to gain too much kinetic energy from the Sun's ultraviolet light before gravity loses its grip on them. Gravity is not all that holds them back, however. As more and more electrons begin to escape outward, they leave behind a growing net positive electric charge in the ionosphere and create a growing net negative electric charge above the ionosphere; an electric field begins to develop (the Pannekoek-Rosseland E-field). Thus, these different interacting charges result in a positively charged ionosphere and negatively charged region of space above it. Very quickly this resulting electric field opposed upward movement of the electrons out of the ionosphere. The electrons still have this increased energy, however, so the electric field doesn't just

Rare Earth Polyoxometalates.

PubMed

Boskovic, Colette

2017-09-19

Longstanding and important applications make use of the chemical and physical properties of both rare earth metals and polyoxometalates of early transition metals. The catalytic, optical, and magnetic features of rare earth metal ions are well-known, as are the reversible multielectron redox and photoredox capabilities of polyoxomolybdates and polyoxotungstates. The combination of rare earth ions and polyoxometalates in discrete molecules and coordination polymers is of interest for the unique combination of chemical and physical properties that can arise. This Account surveys our efforts to synthesize and investigate compounds with rare earth ions and polyoxometalates (RE-POMs), sometimes with carboxylate-based organic coligands. Our general synthetic approach is "bottom-up", which affords well-defined nanoscale molecules, typically in crystalline form and amenable to single-crystal X-ray diffraction for structure determination. Our particular focus is on elucidation of the physical properties conferred by the different structural components with a view to ultimately being able to tune these properties chemically. For this purpose, we employ a variety of spectroscopic, magnetochemical, electrochemical, and scattering techniques in concert with theoretical modeling and computation. Studies of RE-POM single-molecule magnets (SMMs) have utilized magnetic susceptibility, inelastic neutron scattering, and ab initio calculations. These investigations have allowed characterization of the crystal field splitting of the rare earth(III) ions that is responsible for the SMM properties of slow magnetic relaxation and magnetization quantum tunneling. Such SMMs are promising for applications in quantum computing and molecular spintronics. Photophysical measurements of a family of hybrid RE-POMs with organic ligands have afforded insights into sensitization of Tb(III) and Eu(III) emission through both organic and polyoxometalate chromophores in the same molecule. Detailed

Antiferromagnetic coupling between rare earth ions and semiquinones in a series of 1:1 complexes.

PubMed

Caneschi, Andrea; Dei, Andrea; Gatteschi, Dante; Poussereau, Sandrine; Sorace, Lorenzo

2004-04-07

We use the strategy of diamagnetic substitution for obtaining information on the crystal field effects in paramagnetic rare earth ions using the homologous series of compounds with the diamagnetic tropolonato ligand, Ln(Trp)(HBPz(3))(2), and the paramagnetic semiquinone ligand, Ln(DTBSQ)(HBPz(3))(2), (DTBSQ = 3,5-di-tert-butylsemiquinonato, Trp = tropolonate, HBPz(3)= hydrotrispyrazolylborate) for Ln = Sm(iii), Eu(iii), Gd(iii), Tb(iii), Dy(iii), Ho(iii), Er(iii) or Yb(iii). The X-ray crystal structure of a new form of tropolonate derivative is presented, which shows, as expected, a marked similarity with the structure of the semiquinonate derivative. The Ln(Trp)(HBPz(3))(2) derivatives were then used as a reference for the qualitative determination of crystal field effects in the exchange coupled semiquinone derivatives. Through magnetisation and susceptibility measurements this empirical diamagnetic substitution method evidenced for Er(iii), Tb(iii), Dy(iii) and Yb(iii) derivatives a dominating antiferromagnetic coupling. The increased antiferromagnetic contribution compared to other radical-rare earth metal complexes formed by nitronyl nitroxide ligands may be related to the increased donor strength of the semiquinone ligand.

In Situ Measurements of Meteoric Ions

NASA Technical Reports Server (NTRS)

Grebowsky, Joseph M.; Aiken, Arthur C.; Einaudi, Franco (Technical Monitor)

2001-01-01

Extraterrestrial material is the source of metal ions in the Earth's atmosphere, Each year approx. 10(exp 8) kg of material is intercepted by the Earth. The origin of this material is predominantly solar orbiting interplanetary debris from comets or asteroids that crosses the Earth's orbit. It contains a very small amount of interstellar material. On occasion the Earth passes through enhanced amounts of debris associated with the orbit of a decaying comet. This leads to enhanced meteor shower displays for up to several days. The number flux of shower material is typically several times the average sporadic background influx of material. Meteoric material is some of the earliest material formed in the solar system. By studying the relative elemental abundances of atmospheric metal ions, information can be gained on the chemical composition of cometary debris and the chemical makeup of the early solar system. Using in situ sampling with rocket-borne ion mass spectrometers; there have been approximately 50 flights that made measurements of the metal ion abundances at attitudes between 80 and 130 km. It is this altitude range where incoming meteoric particles am ablated, the larger ones giving rise to visible meteor. displays. In several rocket measurements isotopic ratios of different atomic ion mass components and metal molecular ion concentrations have been determined and used to identify unambiguously the measured species and to investigate the processes controlling the metal ion distributions The composition of the Earth's ionosphere was first sampled by an ion mass spectrometer flown an a rocket in 1956. In 1958 a rocket-borne ion spectrometer identified, fbr the first time, a layer of metal ions near 95 km. These data were interpreted as evidence of an extraterrestrial rather than a terrestrial source. Istomin predicted: "It seems probable that with some improvement in the method that analysis of the ion composition in the E-region may be used for determining

Discovery of Suprathermal Ionospheric Origin Fe+ in and Near Earth's Magnetosphere

NASA Astrophysics Data System (ADS)

Christon, S. P.; Hamilton, D. C.; Plane, J. M. C.; Mitchell, D. G.; Grebowsky, J. M.; Spjeldvik, W. N.; Nylund, S. R.

2017-11-01

Suprathermal (87-212 keV/e) singly charged iron, Fe+, has been discovered in and near Earth's 9-30 RE equatorial magnetosphere using 21 years of Geotail STICS (suprathermal ion composition spectrometer) data. Its detection is enhanced during higher geomagnetic and solar activity levels. Fe+, rare compared to dominant suprathermal solar wind and ionospheric origin heavy ions, might derive from one or all three candidate lower-energy sources: (a) ionospheric outflow of Fe+ escaped from ion layers near 100 km altitude, (b) charge exchange of nominal solar wind iron, Fe+≥7, in Earth's exosphere, or (c) inner source pickup Fe+ carried by the solar wind, likely formed by solar wind Fe interaction with near-Sun interplanetary dust particles. Earth's semipermanent ionospheric Fe+ layers derive from tons of interplanetary dust particles entering Earth's atmosphere daily, and Fe+ scattered from these layers is observed up to 1000 km altitude, likely escaping in strong ionospheric outflows. Using 26% of STICS's magnetosphere-dominated data when possible Fe+2 ions are not masked by other ions, we demonstrate that solar wind Fe charge exchange secondaries are not an obvious Fe+ source. Contemporaneous Earth flyby and cruise data from charge-energy-mass spectrometer on the Cassini spacecraft, a functionally identical instrument, show that inner source pickup Fe+ is likely not important at suprathermal energies. Consequently, we suggest that ionospheric Fe+ constitutes at least a significant portion of Earth's suprathermal Fe+, comparable to the situation at Saturn where suprathermal Fe+ is also likely of ionospheric origin.

Influence of rare earth ions on microstructural and optical properties of ZnO nanostructures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riyajuddin, Sk., E-mail: riyaj5303@gmail.com; Ahmad, Shabbir; Faizan, M.

2016-05-23

Pure and 3% rare earth ions (Nd{sup 3+} & Gd{sup 3+}) doped ZnO samples were synthesized by sol-gel method, followed by annealing at temperature 450°C for 2hr. The samples were characterized by XRD, FTIR and UV-visible spectroscopy. XRD result confirmed single phase nature of all samples with crystalline structure. The average crystallite size of the doped samples found to be decreases as caculated using Debye-Scherrer’s formula. FTIR spectra indicate absorption band centered at 464 cm{sup −1} which is attributed to Zn-O lattice vibration. It confirms the formaton of compounds. UV-visible spectroscopy was used to study the optical properties and band gapmore » of the synthesised materials using Tauc’s relation.« less

Solid Phase Luminescence of Several Rare Earth Ions on Ion-Exchange Films

NASA Technical Reports Server (NTRS)

Tanner, Stephen P.; Street, Kenneth W., Jr.

1999-01-01

The development and characterization of a novel ion-exchange film for solid-phase fluorometry and phosphorimetry is reported. This new cation-exchange material is suitable for spectroscopic applications in the ultraviolet and visible regions. It is advantageous because it, as a single entity, is easily recovered from solution and mounted in the spectrofluorometers. After preconcentration on the film, the luminescence intensity of lanthanide ions is several orders of magnitude greater than that of the corresponding solution, depending on the volume of solution and the amount of film. This procedure allows emission spectral measurements and determination of lanthanide ions at solution concentrations of < 5 (micro)g/L. The film may be stored for subsequent reuse or as a permanent record of the analysis. The major drawback to the use of the film is slow uptake of analyte due to diffusion limitations.

Is There Segregation of Rare Earth Ions in Garnet Optical Ceramics?

NASA Astrophysics Data System (ADS)

Boulon, Georges; Epicier, T.; Zhao, W.; Guzik, M.; Pan, Y.; Jiang, B.

Research on advanced optical materials for a large variety of applications is always increasing. As an example, we can note high progress in solid-state laser sources like laser-diode (LD) - pumped solid-state lasers (DPSSL) including developments of new materials and high-power laser diode led to high-power and tuneable solid-state lasers. A wide variety of materials has been studied to develop more efficient and high power microchip lasers [1]. In end-pumping schemes, in particular, materials with a short absorption length for the LD pump beam are strongly anticipated for highly efficient operations because of the excellent match between the mode and pump beam profiles. High Nd3+ concentrations were so considered such as NdP5O14, LiNdP4O12 (LNP), and NdAl3(BO3)O4. However, crystal growths of these compositions are not so easy. Cubic crystals are much more researched. When looking at the literature for actual applications, we see immediately the importance of cubic garnet crystals for which dodecahedral (Y3+), octahedral (Al3+) and tetrahedral (Al3+) sites are considered as a reservoir for many activators like: Ce3+, Nd3+, Er3+, Tm3+, Ho3+, Yb3+ rare earth ions in dodecahedral symmetry sites and transition metal ions like Cr3+ in the octahedral symmetry sites or Cr4+ in the tetrahedral symmetry sites. Among garnet crystals, Y3Al5O12 (YAG) host is the most used, commercially produced by the Czochralski method. However, in the case of the most used Nd3+: YAG laser crystal, the Nd3+ concentration that affects the performance in laser applications, is strongly limited to 0.2-1.4 Nd3+ at. % as a result of the segregation distribution coefficient [1].

Tunable, rare earth-doped solid state lasers

DOEpatents

Emmett, John L.; Jacobs, Ralph R.; Krupke, William F.; Weber, Marvin J.

1980-01-01

Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.

Ferroelectricity of domain walls in rare earth iron garnet films.

PubMed

Popov, A I; Zvezdin, K A; Gareeva, Z V; Mazhitova, F A; Vakhitov, R M; Yumaguzin, A R; Zvezdin, A K

2016-11-16

In this paper, we report on electric polarization arising in a vicinity of Bloch-like domain walls in rare-earth iron garnet films. The domain walls generate an intrinsic magnetic field that breaks an antiferroelectric structure formed in the garnets due to an exchange interaction between rare earth and iron sublattices. We explore 180° domain walls whose formation is energetically preferable in the films with perpendicular magnetic anisotropy. Magnetic and electric structures of the 180° quasi-Bloch domain walls have been simulated at various relations between system parameters. Singlet, doublet ground states of rare earth ions and strongly anisotropic rare earth Ising ions have been considered. Our results show that electric polarization appears in rare earth garnet films at Bloch domain walls, and the maximum of magnetic inhomogeneity is not always linked to the maximum of electric polarization. A number of factors including the temperature, the state of the rare earth ion and the type of a wall influence magnetically induced electric polarization. We show that the value of polarization can be enhanced by the shrinking of the Bloch domain wall width, decreasing the temperature, and increasing the deviations of magnetization from the Bloch rotation that are regulated by impacts given by magnetic anisotropies of the films.

Probing Molecular Ions With Laser-Cooled Atomic Ions

DTIC Science & Technology

2017-10-11

Sept. 23, 2015 Precision Chemical Dynamics and Quantum Control of Ultracold Molecular Ion Reactions , Cold Molecular Ions at the Quantum limit (COMIQ...ken.brown@chemistry.gatech.edu This work solved an old mystery about the lifetime of Ca+ due to reactions with background gases in laser-cooling experiments...Relative to other alkaline earths, Ca+ had a much slower reaction rate. We discovered the reason is that the Doppler cooling laser is near

Novel online security system based on rare-earth-doped glass microbeads

NASA Astrophysics Data System (ADS)

Officer, Simon; Prabhu, G. R.; Pollard, Pat; Hunter, Catherine; Ross, Gary A.

2004-06-01

A novel fluorescent security label has been produced that could replace numerous conventional fluorescent dyes in document security. This label utilizes rare earth ions doped in a borosilicate glass matrix to produce sharp spectral fluorescence peaks with characteristic long lifetimes due to the rare earth ions. These are subsequently detected by an online detection system based on fluorescence and the long lifetimes to avoid any interference from other fluorophores present in the background. Security is further enhanced by the interaction of the rare earth ions with each other and the effect of the host on the emission spectra and therefore the number of permutations that could be produced. This creates a very secure label with various applications for the security market.

Impact of Near-Earth Plasma Sheet Dynamics on the Ring Current Composition

NASA Astrophysics Data System (ADS)

Kistler, L. M.; Mouikis, C.; Menz, A.; Spence, H. E.; Mitchell, D. G.; Gkioulidou, M.; Lanzerotti, L. J.; Skoug, R. M.; Larsen, B.; Claudepierre, S. G.; Fennell, J. F.; Blake, J. B.

2014-12-01

How the dynamics in the near-earth plasma sheet affects the heavy ion content, and therefore the ion pressure, of the ring current in Earth's magnetosphere is an outstanding question. Substorms accelerate plasma in the near-earth region and drive outflow from the aurora, and both these processes can preferentially enhance the population of heavy ions in this region. These heavy ions are then driven into the inner magnetosphere during storms. Thus understanding how the composition of the ring current changes requires simultaneous observations in the near-earth plasma sheet and in the inner magnetosphere. We use data from the CODIF instrument on Cluster and HOPE, RBSPICE, and MagEIS instruments on the Van Allen Probes to study the acceleration and transport of ions from the plasma sheet into the ring current. During the main phase of a geomagnetic storm on Aug 4-6, 2013, the Cluster spacecraft were moving inbound in the midnight central plasma sheet, while the apogees of the two Van Allen Probes were located on the duskside. The Cluster spacecraft measure the composition and spectral changes in the plasma sheet, while the Van Allen Probes measure the ions that reach the inner magnetosphere. A strong increase in 1-40 keV O+ was observed at the Cluster location during the storm main phase, and the Van Allen Probes observed both H+ and O+ being driven deep into the inner magnetosphere. By comparing the variations in phase space density (PSD) vs. magnetic moment at the Cluster and the Van Allen Probes locations, we examine how the composition changes non-adiabatically in the near-earth plasma sheet, and how those changes are propagated into the inner magnetosphere, populating the hto ion ring current.

Spherical ion acoustic waves in pair ion plasmas with nonthermal electrons

NASA Astrophysics Data System (ADS)

Selim, M. M.

2016-04-01

Propagation of nonplanar ion acoustic waves in a plasma composed of negative and positive ions and nonthermally distributed electrons is investigated using reductive perturbation theory. The spherical Kadomtsev-Petviashvili (SKP) equation which describes the dynamics of the nonlinear spherical ion acoustic waves is derived. It is found that compressive and rarefactive ion-acoustic solitary wave characteristics significantly depend on the density and mass ratios of the positive to negative ions, the nonthermal electron parameter, and the geometry factor. The possible regions for the existence of spherical ion acoustic waves are defined precisely for typical parameters of (H+, O2 -) and (H+, H-) plasmas in the D and F-regions of the Earth's ionosphere, as well as for laboratory plasma (Ar+, F-).

3D ion-scale dynamics of BBFs and their associated emissions in Earth's magnetotail using 3D hybrid simulations and MMS multi-spacecraft observations

NASA Astrophysics Data System (ADS)

Breuillard, H.; Aunai, N.; Le Contel, O.; Catapano, F.; Alexandrova, A.; Retino, A.; Cozzani, G.; Gershman, D. J.; Giles, B. L.; Khotyaintsev, Y. V.; Lindqvist, P. A.; Ergun, R.; Strangeway, R. J.; Russell, C. T.; Magnes, W.; Plaschke, F.; Nakamura, R.; Fuselier, S. A.; Turner, D. L.; Schwartz, S. J.; Torbert, R. B.; Burch, J.

2017-12-01

Transient and localized jets of hot plasma, also known as Bursty Bulk Flows (BBFs), play a crucial role in Earth's magnetotail dynamics because the energy input from the solar wind is partly dissipated in their vicinity, notably in their embedded dipolarization front (DF). This dissipation is in the form of strong low-frequency waves that can heat and accelerate energetic particles up to the high-latitude plasma sheet. The ion-scale dynamics of BBFs have been revealed by the Cluster and THEMIS multi-spacecraft missions. However, the dynamics of BBF propagation in the magnetotail are still under debate due to instrumental limitations and spacecraft separation distances, as well as simulation limitations. The NASA/MMS fleet, which features unprecedented high time resolution instruments and four spacecraft separated by kinetic-scale distances, has also shown recently that the DF normal dynamics and its associated emissions are below the ion gyroradius scale in this region. Large variations in the dawn-dusk direction were also observed. However, most of large-scale simulations are using the MHD approach and are assumed 2D in the XZ plane. Thus, in this study we take advantage of both multi-spacecraft observations by MMS and large-scale 3D hybrid simulations to investigate the 3D dynamics of BBFs and their associated emissions at ion-scale in Earth's magnetotail, and their impact on particle heating and acceleration.

[An investigation of ionizing radiation dose in a manufacturing enterprise of ion-absorbing type rare earth ore].

PubMed

Zhang, W F; Tang, S H; Tan, Q; Liu, Y M

2016-08-20

Objective: To investigate radioactive source term dose monitoring and estimation results in a manufacturing enterprise of ion-absorbing type rare earth ore and the possible ionizing radiation dose received by its workers. Methods: Ionizing radiation monitoring data of the posts in the control area and supervised area of workplace were collected, and the annual average effective dose directly estimated or estimated using formulas was evaluated and analyzed. Results: In the control area and supervised area of the workplace for this rare earth ore, α surface contamination activity had a maximum value of 0.35 Bq/cm 2 and a minimum value of 0.01 Bq/cm 2 ; β radioactive surface contamination activity had a maximum value of 18.8 Bq/cm 2 and a minimum value of 0.22 Bq/cm 2 . In 14 monitoring points in the workplace, the maximum value of the annual average effective dose of occupational exposure was 1.641 mSv/a, which did not exceed the authorized limit for workers (5 mSv/a) , but exceeded the authorized limit for general personnel (0.25 mSv/a) . The radionuclide specific activity of ionic mixed rare earth oxides was determined to be 0.9. Conclusion: The annual average effective dose of occupational exposure in this enterprise does not exceed the authorized limit for workers, but it exceeds the authorized limit for general personnel. We should pay attention to the focus of the radiation process, especially for public works radiation.

Separation of rare earths from transition metals by liquid-liquid extraction from a molten salt hydrate to an ionic liquid phase.

PubMed

Rout, Alok; Binnemans, Koen

2014-02-28

The solvent extraction of trivalent rare-earth ions and their separation from divalent transition metal ions using molten salt hydrates as the feed phase and an undiluted fluorine-free ionic liquid as the extracting phase were investigated in detail. The extractant was tricaprylmethylammonium nitrate, [A336][NO3], and the hydrated melt was calcium nitrate tetrahydrate, Ca(NO3)2·4H2O. The extraction behavior of rare-earth ions was studied for solutions of individual elements, as well as for mixtures of rare earths in the hydrated melt. The influence of different extraction parameters was investigated: the initial metal loading in the feed phase, percentage of water in the feed solution, equilibration time, and the type of hydrated melt. The extraction of rare earths from Ca(NO3)2·4H2O was compared with extraction from CaCl2·4H2O by [A336][Cl] (Aliquat 336). The nitrate system was found to be the better one. The extraction and separation of rare earths from the transition metals nickel, cobalt and zinc were also investigated. Remarkably high separation factors of rare-earth ions over transition metal ions were observed for extraction from Ca(NO3)2·4H2O by the [A336][NO3] extracting phase. Furthermore, rare-earth ions could be separated efficiently from transition metal ions, even in melts with very high concentrations of transition metal ions. Rare-earth oxides could be directly dissolved in the Ca(NO3)2·4H2O phase in the presence of small amounts of Al(NO3)3·9H2O or concentrated nitric acid. The efficiency of extraction after dissolving the rare-earth oxides in the hydrated nitrate melt was identical to extraction from solutions with rare-earth nitrates dissolved in the molten phase. The stripping of the rare-earth ions from the loaded ionic liquid phase and the reuse of the recycled ionic liquid were also investigated in detail.

Earth Science

NASA Image and Video Library

1991-01-01

In July 1990, the Marshall Space Flight Center, in a joint project with the Department of Defense/Air Force Space Test Program, launched the Combined Release and Radiation Effects Satellite (CRRES) using an Atlas I launch vehicle. The mission was designed to study the effects of artificial ion clouds produced by chemical releases on the Earth's ionosphere and magnetosphere, and to monitor the effects of space radiation environment on sophisticated electronics.

Short Wavelength Electrostatic Waves in the Earth’s Magnetosheath.

DTIC Science & Technology

1982-07-01

to an antenna effect. Emissions likely to be ion-acoustic mode waves have been found up- stream of the bow shock ( foreshock ) in the solar wind...particles apparently reflected at the bow shock and associated with ion- acoustic mode waves in the Earth’s foreshock are also observed [Eastman et al...Res., 86, A 4493-4510, 1981. Eastman, T.E., 1.R. Anderson, L.A. Frank, and G.K. Parks, Upstream particles observed in the Earth’s foreshock region

The adsorption kinetics of metal ions onto different microalgae and siliceous earth.

PubMed

Schmitt, D; Müller, A; Csögör, Z; Frimmel, F H; Posten, C

2001-03-01

In the present work the adsorption kinetics of the six metal ions aluminum, zinc, mercury, lead, copper, and cadmium onto living microalgae were measured. The freshwater green microalga Scenedesmus subspicatus, the brackish water diatom Cyclotella cryptica, the seawater diatom Phaeodactylum tricornutum, and the seawater red alga Porphyridium purpureum were the subject of investigation. In most cases the adsorption rate of the metals could be well described by using the equation of the Langmuir adsorption rate expression. Inverse parameter estimation allowed the determination of the rate constants of the adsorption process and the maximum metal content of the algae. The highest values for the rate constant were obtained for Porphyridium purpureum followed by Phaeodactylum tricornutum. High values for the maximum content were obtained for Cyclotella cryptica and Scenedesmus subspicatus. The maximum rate constant was 24.21 h-1 for the adsorption of Hg to Porphyridium purpureum whereas the maximum metal content (0.243 g g-1) was obtained for Zn on Cyclotella cryptica. A comparison of these values with those obtained for the mineral siliceous earth exhibiting low maximum content and high adsorption rates reveals that the mechanism of adsorption onto the algae is a mixture of adsorption and accumulation.

Enhanced pinning in mixed rare earth-123 films

DOEpatents

Driscoll, Judith L [Los Alamos, NM; Foltyn, Stephen R [Los Alamos, NM

2009-06-16

An superconductive article and method of forming such an article is disclosed, the article including a substrate and a layer of a rare earth barium cuprate film upon the substrate, the rare earth barium cuprate film including two or more rare earth metals capable of yielding a superconductive composition where ion size variance between the two or more rare earth metals is characterized as greater than zero and less than about 10.times.10.sup.-4, and the rare earth barium cuprate film including two or more rare earth metals is further characterized as having an enhanced critical current density in comparison to a standard YBa.sub.2Cu.sub.3O.sub.y composition under identical testing conditions.

Discovery of Suprathermal Fe+ in and near Earth's Magnetosphere

NASA Astrophysics Data System (ADS)

Christon, S. P.; Hamilton, D. C.; Plane, J. M. C.; Mitchell, D. G.; Grebowsky, J. M.; Spjeldvik, W. N.; Nylund, S. R.

2017-12-01

Suprathermal (87-212 keV/e) singly charged iron, Fe+, has been observed in and near Earth's equatorial magnetosphere using long-term ( 21 years) Geotail/STICS ion composition data. Fe+ is rare compared to dominant suprathermal solar wind and ionospheric origin heavy ions. Earth's suprathermal Fe+ appears to be positively associated with both geomagnetic and solar activity. Three candidate lower-energy sources are examined for relevance: ionospheric outflow of Fe+ escaped from ion layers altitude, charge exchange of nominal solar wind Fe+≥7, and/or solar wind transported inner source pickup Fe+ (likely formed by solar wind Fe+≥7 interaction with near sun interplanetary dust particles, IDPs). Semi-permanent ionospheric Fe+ layers form near 100 km altitude from the tons of IDPs entering Earth's atmosphere daily. Fe+ scattered from these layers is observed up to 1000 km altitude, likely escaping in strong ionospheric outflows. Using 26% of STICS's magnetosphere-dominated data at low-to-moderate geomagnetic activity levels, we demonstrate that solar wind Fe charge exchange secondaries are not an obvious Fe+ source then. Earth flyby and cruise data from Cassini/CHEMS, a nearly identical instrument, show that inner source pickup Fe+ is likely not important at suprathermal energies. Therefore, lacking any other candidate sources, it appears that ionospheric Fe+ constitutes at least an important portion of Earth's suprathermal Fe+, comparable to observations at Saturn where ionospheric origin suprathermal Fe+ has also been observed.

Anomalous momentum and energy transfer rates for electrostatic ion-cyclotron turbulence in downward auroral-current regions of the Earth's magnetosphere. III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jasperse, John R.; Basu, Bamandas; Lund, Eric J.

2010-06-15

Recently, a new multimoment fluid theory was developed for inhomogeneous, nonuniformly magnetized plasma in the guiding-center and gyrotropic approximation that includes the effect of electrostatic, turbulent, wave-particle interactions (see Jasperse et al. [Phys. Plasmas 13, 072903 (2006); ibid.13, 112902 (2006)]). In the present paper, which is intended as a sequel, it is concluded from FAST satellite data that the electrostatic ion-cyclotron turbulence that appears is due to the operation of an electron, bump-on-tail-driven ion-cyclotron instability for downward currents in the long-range potential region of the Earth's magnetosphere. Approximate closed-form expressions for the anomalous momentum and energy transfer rates for themore » ion-cyclotron turbulence are obtained. The turbulent, inhomogeneous, nonuniformly magnetized, multimoment fluid theory given above, in the limit of a turbulent, homogeneous, uniformly magnetized, quasisteady plasma, yields the well-known formula for the anomalous resistivity given by Gary and Paul [Phys. Rev. Lett. 26, 1097 (1971)] and Tange and Ichimaru [J. Phys. Soc. Jpn. 36, 1437 (1974)].« less

Hydrothermal method of synthesis of rare-earth tantalates and niobates

DOEpatents

Nyman, May D; Rohwer, Lauren E.S.; Martin, James E

2012-10-16

A hydrothermal method of synthesis of a family of rare-earth Group 5 oxides, where the Group 5 oxide is a niobate or tantalate. The rare-earth Group 5 oxides can be doped with suitable emitter ions to form nanophosphors.

Effect of doping rare earths on magnetostriction characteristics of CoFe2O4 prepared from spent Li-ion batteries

NASA Astrophysics Data System (ADS)

Xi, Guoxi; Zhao, Tingting; Wang, Lu; Dun, Changwei; Zhang, Ye

2018-04-01

Recovering spent Li-ion batteries is beneficial to the economy and environment. Therefore, this study synthesized nanoparticles of cobalt ferrite doped with different rare earth ions (Nd, Ce, and Pr) by a sol-gel auto-combustion method using spent Li-ion batteries. The effect of the different doping elements on grain sizes, structure, magnetic and magnetostrictive properties, and strain derivative were confirmed by X-ray diffraction, scanning election microscopy, vibrating sample magnetometer, and a magnetostrictive coefficient measuring system. Substitution of a small amount of Fe3+ with RE3+ in CoRExFe2-xO4 (x = 0.025, 0.05, and 0.1) had a large effect on magnetostrictive properties and strain derivative, which was improved compared with pure cobalt ferrite at low magnetic field. The maximum strain derivative (dλ/dH = -1.49 × 10-9 A-1 m at 18 kA m-1) was obtained for Nd, x = 0.05. Changes in the magnetostriction coefficients and strain derivatives were correlated with changes in cation distribution, microstructure, and magnetic anisotropy, which depended strongly on RE3+ substitution and distribution in the spinel structure.

A statistical study of ion pitch-angle distributions

NASA Technical Reports Server (NTRS)

Sibeck, D. G.; Mcentire, R. W.; Lui, A. T. Y.; Krimigis, S. M.

1987-01-01

Preliminary results of a statistical study of energetic (34-50 keV) ion pitch-angle distributions (PADs) within 9 Re of earth provide evidence for an orderly pattern consistent with both drift-shell splitting and magnetopause shadowing. Normal ion PADs dominate the dayside and inner magnetosphere. Butterfly PADs typically occur in a narrow belt stretching from dusk to dawn through midnight, where they approach within 6 Re of earth. While those ion butterfly PADs that typically occur on closed drift paths are mainly caused by drift-shell splitting, there is also evidence for magnetopause shadowing in observations of more frequent butterfly PAD occurrence in the outer magnetosphere near dawn than dusk. Isotropic and gradient boundary PADs terminate the tailward extent of the butterfly ion PAD belt.

Ion beam sputter-deposited thin film coatings for protection of spacecraft polymers in low Earth orbit

NASA Technical Reports Server (NTRS)

Banks, B. A.; Mirtich, M. J.; Rutledge, S. K.; Swec, D. M.; Nahra, H. K.

1985-01-01

Ion beam sputter-deposited thin films of Al2O3, SiO2, and a codeposited mixture of predominantly SiO2 with small amounts of a fluoropolymer were evaluated both in laboratory plasma ashing tests and in space on board shuttle flight STS-8 for effectiveness in preventing oxidation of polyimide Kapton. Measurements of mass loss and optical performance of coated and uncoated polyimide samples exposed to the low Earth orbital environment are presented. Optical techniques were used to measure loss rates of protective films exposed to atomic oxygen. Results of the analysis of the space flight exposed samples indicate that thin film metal oxide coatings are very effective in protecting the polyimide. Metal oxide coatings with a small amount of fluoropolymer codeposited have the additional benefit of great flexibility.

Ion beam sputter-deposited thin film coatings for protection of spacecraft polymers in low earth orbit

NASA Technical Reports Server (NTRS)

Banks, B. A.; Mirtich, M. J.; Rutledge, S. K.; Swec, D. M.; Nahra, H. K.

1985-01-01

Ion beam sputter-deposited thin films at Al2O3, SiO2, and a codeposited mixture of predominantly SiO2 with small amounts of fluoropolymer were evaluated both in laboratory plasma ashing tests and in space on board Shuttle flight STS-8 for effectiveness in preventing oxidation of polyimide Kapton. Measurements of mass loss and optical performance of coated and uncoated polyimide samples exposed to the low earth orbital environment are presented. Optical techniques were used to measure loss rates of protective films exposed to atomic oxygen. Results of the analysis of the space flight exposed samples indicate that thin film metal oxide coatings are very effective in protecting the polyimide. Metal oxide coatings with a small amount of fluoropolymer codeposited have the additional benefit of great flexibility.

Non-resonant excitation of rare-earth ions via virtual Auger process

NASA Astrophysics Data System (ADS)

Yassievich, I. N.

2011-05-01

The luminescence of rare-earth ions (REI) is often intensified by defects associated with REIs or excitons bound to these defects. In this paper we show that the presence of such a state opens the possibility of non-resonance optical pumping via the process involving virtual Auger transition. It is the second order perturbation process when an electron arrives in an virtual intermediate state due to the optical transition (the first step) and the Auger transition is the second one. We have calculated the cross-section of such an excitation process when the optical transition is accompanied by creation of the exciton bound to the defect associated with REI and obtained a simple analytical expression for the cross-section. The excess energy of the excitation quanta is taken away by multiphonon emission. The electron-phonon interaction with local phonon vibrations of the bound exciton is assumed to determine the multiphonon process. It is shown that the probability of the process under study exceeds considerably the probability of direct optical 4f-4f absorption even in the case when the energy distance between the excitation quantum energy and the exciton energy is about 0.1 of the exciton energy. The excitation mechanism considered leads to the appearance of a broad unsymmetrical band in the excitation spectrum with the red side much wider and flatter than the blue one.

Resistivity and magnetoresistivity of amorphous rare-earth alloys

NASA Astrophysics Data System (ADS)

Borchi, E.; Poli, M.; De Gennaro, S.

1982-05-01

The resistivity and magnetoresistivity of amorphous rare-earth alloys are studied starting from the general approach of Van Peski-Tinbergen and Dekker. The random axial crystal-field and the magnetic correlations between the rare-earth ions are consistently taken into account. The characteristic features of the available experimental data are explained both of the case of random ferromagnetic and antiferromagnetic order.

Influence of iron substitution by selected rare-earth ions on the properties of NiZn ferrite fillers and PVC magneto-polymer composites

NASA Astrophysics Data System (ADS)

Ušák, Elemír; Ušáková, Mariana; Dosoudil, Rastislav; Šoka, Martin; Dobročka, Edmund

2018-04-01

Nickel-zinc ferrites are very important soft magnetic materials from the point of view of diverse technical applications (such as, e.g., various electronic devices and components) for their high magnetic permeability and permittivity, low core loss, high resistivity, high Curie temperature as well as mechanical strength and chemical stability. Due to their good absorbing properties, they can be used as microwave absorbing and shielding materials with the aim of decreasing the environmental pollution caused by non-ionizing microwave radiation. The ferrite material incorporated into the polymer matrix creates qualitatively new magneto-polymer composite material taking benefits from both components. The properties typical for polymers (elasticity, mouldability, etc.) are combined with good high-frequency magnetic parameters, thus allowing to utilize these materials, e.g., in high-frequency applications where especially flexibility of composite materials plays a key role. Small amounts of selected rare-earth (RE) ions, in particular Y3+, La3+, Eu3+ and Gd3+ have been embedded into the nickel-zinc ferrite that has been used as the magnetic filler in magnetic polymer composites with polyvinylchloride (PVC) acting as the polymeric matrix. The effect of various types of rare-earth ions on the structural as well as quasi-static and dynamic (electro)magnetic properties of the ferrite fillers as well as ferrite/PVC composites, in particular the frequency dispersion of the complex permeability, has been studied.

Acceleration of Particles Near Earth's Bow Shock

NASA Astrophysics Data System (ADS)

Sandroos, A.

2012-12-01

Collisionless shock waves, for example, near planetary bodies or driven by coronal mass ejections, are a key source of energetic particles in the heliosphere. When the solar wind hits Earth's bow shock, some of the incident particles get reflected back towards the Sun and are accelerated in the process. Reflected ions are responsible for the creation of a turbulent foreshock in quasi-parallel regions of Earth's bow shock. We present first results of foreshock macroscopic structure and of particle distributions upstream of Earth's bow shock, obtained with a new 2.5-dimensional self-consistent diffusive shock acceleration model. In the model particles' pitch angle scattering rates are calculated from Alfvén wave power spectra using quasilinear theory. Wave power spectra in turn are modified by particles' energy changes due to the scatterings. The new model has been implemented on massively parallel simulation platform Corsair. We have used an earlier version of the model to study ion acceleration in a shock-shock interaction event (Hietala, Sandroos, and Vainio, 2012).

On ion escape from Venus

NASA Astrophysics Data System (ADS)

Jarvinen, R.

2011-04-01

This doctoral thesis is about the solar wind influence on the atmosphere of the planet Venus. A numerical plasma simulation model was developed for the interaction between Venus and the solar wind to study the erosion of charged particles from the Venus upper atmosphere. The developed model is a hybrid simulation where ions are treated as particles and electrons are modelled as a fluid. The simulation was used to study the solar wind induced ion escape from Venus as observed by the European Space Agency's Venus Express and NASA's Pioneer Venus Orbiter spacecraft. Especially, observations made by the ASPERA-4 particle instrument onboard Venus Express were studied. The thesis consists of an introductory part and four peer-reviewed articles published in scientific journals. In the introduction Venus is presented as one of the terrestrial planets in the Solar System and the main findings of the work are discussed within the wider context of planetary physics.Venus is the closest neighbouring planet to the Earth and the most earthlike planet in its size and mass orbiting the Sun. Whereas the atmosphere of the Earth consists mainly of nitrogen and oxygen, Venus has a hot carbon dioxide atmosphere, which is dominated by the greenhouse effect. Venus has all of its water in the atmosphere, which is only a fraction of the Earth's total water supply. Since planets developed presumably in similar conditions in the young Solar System, why Venus and Earth became so different in many respects?One important feature of Venus is that the planet does not have an intrinsic magnetic field. This makes it possible for the solar wind, a continuous stream of charged particles from the Sun, to flow close to Venus and to pick up ions from the planet's upper atmosphere. The strong intrinsic magnetic field of the Earth dominates the terrestrial magnetosphere and deflects the solar wind flow far away from the atmosphere. The region around Venus where the planet's atmosphere interacts with the

On ion escape from Venus

NASA Astrophysics Data System (ADS)

Jarvinen, Riku

2011-04-01

This doctoral thesis is about the solar wind influence on the atmosphere of the planet Venus. A numerical plasma simulation model was developed for the interaction between Venus and the solar wind to study the erosion of charged particles from the Venus upper atmosphere. The developed model is a hybrid simulation where ions are treated as particles and electrons are modelled as a fluid. The simulation was used to study the solar wind induced ion escape from Venus as observed by the European Space Agency's Venus Express and NASA's Pioneer Venus Orbiter spacecraft. Especially, observations made by the ASPERA-4 particle instrument onboard Venus Express were studied. The thesis consists of an introductory part and four peer-reviewed articles published in scientific journals. In the introduction Venus is presented as one of the terrestrial planets in the Solar System and the main findings of the work are discussed within the wider context of planetary physics. Venus is the closest neighbouring planet to the Earth and the most earthlike planet in its size and mass orbiting the Sun. Whereas the atmosphere of the Earth consists mainly of nitrogen and oxygen, Venus has a hot carbon dioxide atmosphere, which is dominated by the greenhouse effect. Venus has all of its water in the atmosphere, which is only a fraction of the Earth's total water supply. Since planets developed presumably in similar conditions in the young Solar System, why Venus and Earth became so different in many respects? One important feature of Venus is that the planet does not have an intrinsic magnetic field. This makes it possible for the solar wind, a continuous stream of charged particles from the Sun, to flow close to Venus and to pick up ions from the planet's upper atmosphere. The strong intrinsic magnetic field of the Earth dominates the terrestrial magnetosphere and deflects the solar wind flow far away from the atmosphere. The region around Venus where the planet's atmosphere interacts with the

Energization of Ions in near-Earth current sheet disruptions

NASA Technical Reports Server (NTRS)

Taktakishvili, A.; Lopez, R. E.; Goodrich, C. C.

1995-01-01

In this study we examine observations made by AMPTE/CCE of energetic ion bursts during seven substorm periods when the satellite was located near the neutral sheet, and CCE observed the disruption cross-tail current in situ. We compare ion observations to analytic calculations of particle acceleration. We find that the acceleration region size, which we assume to be essentially the current disruption region, to be on the order of 1 R(sub E). Events exhibiting weak acceleration had either relatively small acceleration regions (apparently associated with pseudobreakup activity on the ground) or relatively small changes in the local magnetic field (suggesting that the magnitude of the local current disruption region was limited). These results add additional support for the view that the particle bursts observed during turbulent current sheet disruptions are due to inductive acceleration of ions.

Ion flow ripples in the Earth's plasma sheet

NASA Astrophysics Data System (ADS)

De Spiegeleer, Alexandre; Hamrin, Maria; Pitkänen, Timo; Norqvist, Patrik; Mann, Ingrid

2016-04-01

For a long time, magnetotail flows were considered rather smooth and laminar, and primarily dominated by a simple convection flow pattern. However, in the early 90's, high speed bursty bulk flows (BBFs) were discovered and found to commonly perturb the underlying convection flows. In addition, there are other disturbances complicating the magnetotail flow pattern. Instabilities such as the Kelvin-Helmholz instability and the kink instability can cause different types of magnetic field oscillations, such as field line resonances. It is expected that ions will follow these oscillations if the typical time and length scales are larger than the gyroperiod and gyroradius of the ions. Though low-velocity sloshing and ripple disturbances of the average magnetotail convection flows have been observed, their connection with magnetic field oscillations is not fully understood. Furthermore, when studying BFFs, these "Ion Flow Ripples" (IFRs) are often neglected, dismissed as noise or can even erroneously be identified as BBFs. It is therefore of utter importance to find out and understand the role of IFRs in magnetotail dynamics. In a statistical investigation, we use several years of Cluster plasma sheet data to study the low-speed flows in the magnetotail. We investigate different types of IFRs, study their occurrence, and discuss their possible causes.

China's rare-earth industry

USGS Publications Warehouse

Tse, Pui-Kwan

2011-01-01

Introduction China's dominant position as the producer of over 95 percent of the world output of rare-earth minerals and rapid increases in the consumption of rare earths owing to the emergence of new clean-energy and defense-related technologies, combined with China's decisions to restrict exports of rare earths, have resulted in heightened concerns about the future availability of rare earths. As a result, industrial countries such as Japan, the United States, and countries of the European Union face tighter supplies and higher prices for rare earths. This paper briefly reviews China's rare-earth production, consumption, and reserves and the important policies and regulations regarding the production and trade of rare earths, including recently announced export quotas. The 15 lanthanide elements-lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium (atomic numbers 57-71)-were originally known as the rare earths from their occurrence in oxides mixtures. Recently, some researchers have included two other elements-scandium and yttrium-in their discussion of rare earths. Yttrium (atomic number 39), which lies above lanthanum in transition group III of the periodic table and has a similar 3+ ion with a noble gas core, has both atomic and ionic radii similar in size to those of terbium and dysprosium and is generally found in nature with lanthanides. Scandium (atomic number 21) has a smaller ionic radius than yttrium and the lanthanides, and its chemical behavior is intermediate between that of aluminum and the lanthanides. It is found in nature with the lanthanides and yttrium. Rare earths are used widely in high-technology and clean-energy products because they impart special properties of magnetism, luminescence, and strength. Rare earths are also used in weapon systems to obtain the same properties.

Nanosheets of earth-abundant jarosite as novel anodes for high-rate and long-life lithium-ion batteries.

PubMed

Ding, Yuan-Li; Wen, Yuren; Chen, Chia-Chin; van Aken, Peter A; Maier, Joachim; Yu, Yan

2015-05-20

Nanosheets of earth-abundant jarosite were fabricated via a facile template-engaged redox coprecipitation strategy at room temperature and employed as novel anode materials for lithium-ion batteries (LIBs) for the first time. These 2D materials exhibit high capacities, excellent rate capability, and prolonged cycling performance. As for KFe3(SO4)2(OH)6 jarosite nanosheets (KNSs), the reversible capacities of above 1300 mAh g(-1) at 100 mA g(-1) and 620 mAh g(-1) after 4000 cycles at a very high current density of 10 A g(-1) were achieved, respectively. Moreover, the resulting 2D nanomaterials retain good structural integrity upon cycling. These results reveal great potential of jarosite nanosheets as low-cost and high-performance anode materials for next-generation LIBs.

Normal and Tangential Momentum Accommodation for Earth Satellite Conditions

NASA Technical Reports Server (NTRS)

Knechtel, Earl D.; Pitts, William C.

1973-01-01

Momentum accommodation was determined experimentally for gas-surface interactions simulating in a practical way those of near-earth satellites. Throughout the ranges of gas energies and incidence angles of interest for earth-conditions, two components of force were measured by means of a vacuum microbalance to determine the normal and tangential momentum-accommodation coefficients for nitrogen ions on technical-quality aluminum surfaces. For these experimental conditions, the electrodynamics of ion neutralization near the surface indicate that results for nitrogen ions should differ relatively little from those for nitrogen molecules, which comprise the largest component of momentum flux for near-earth satellites. The experimental results indicated that both normal and tangential momentum-accommodation coefficients varied widely with energy, tending to be relatively well accommodated at the higher energies, but becoming progressively less accommodated as the energy was reduced to and below that for earth-satellite speeds. Both coefficients also varied greatly with incidence angle, the normal momentum becoming less accommodated as the incidence angle became more glancing, whereas the tangential momentum generally became more fully accommodated. For each momentum coefficient, an empirical correlation function was obtained which closely approximated the experimental results over the ranges of energy and incidence angle. Most of the observed variations of momentum accommodation with energy and incidence angle were qualitatively indicated by a calculation using a three-dimensional model that simulated the target surface by a one-dimensional attractive potential and hard sphere reflectors.

Formation of gyrotropic and non gyrotropic field-aligned beams in the Earth's quasi-perpendicular Ion Foreshock: Full-particle 2D simulation results

NASA Astrophysics Data System (ADS)

Savoini, P.; Lembege, B.

2013-12-01

The ion foreshock located upstream of the Earth's bow shock is populated with ions reflected back by the shock front with an high energy gain. In-situ spacecraft measurements have clearly established the existence of two distinct populations in the foreshock upstream of quasi-perpendicular shock region (i.e. for 45° ≤ ΘBn≤ 90°, where ΘBn is the angle between the shock normal and the upstream magnetostatic field): (i) field-aligned (';FAB') ion beams characterized by a gyrotropic distribution, and (ii) gyro-phase bunched (';GPB') ions characterized by a NON gyrotropic distribution, which exhibits a non-vanishing perpendicular bulk velocity. The purpose of the present work is to identify the possible sources of the different backstreaming ions and is based on the use of 2D PIC simulations of a curved shock, where full curvature effects, time of flight effects and both electrons and ions dynamics are fully described by a self consistent approach. Our analysis evidences that the two populations mentionned above may have different origins identified both in terms of interaction time and distance of penetration within the shock front. In particular, ours simulations evidence that "GPB" and ';FAB' populations are characterized by a short (Δinter= 1 to 2 tci) and much larger (Δinter= 1 to 10 tci) interaction time respectively, where τci is the ion upstream gyroperiod. In addition, a deeper statistical analysis of ion trajectories evidences that: (i) both populations can be discriminated in terms of injection angle into the shock front (i.e. defined between the local normal to the shock front and the gyration velocity vector at the time ions reach the front). Such a behavior explains how reflected ions can be splitted in the observed two populations "FAB" and "GPB". (ii) ion trajectories strongly differ between the "FAB" and "GPB" populations at the shock front. In particular, ';FAB' ions suffer multi-bounces whereas ';GPB '; ions make only one bounce. Such

Unique, Non-Earthlike, Meteoritic Ion Behavior in Upper Atmosphere of Mars

NASA Technical Reports Server (NTRS)

Grebowsky, J. M.; Benna, M.; Plane, J. M. C.; Collinson, G. A.; Mahaffy, P. R.; Jakosky, B. M.

2017-01-01

Abstract Interplanetary dust particles have long been expected to produce permanent ionospheric metal ion layers at Mars, as on Earth, but the two environments are so different that uncertainty existed as to whether terrestrial-established understanding would apply to Mars. The Mars Atmosphere and Volatile EvolutioN (MAVEN) mission made the first in situ detection of the continuous presence of Na+, Mg+, and Fe+ at Mars and indeed revealed non-Earthlike features/processes. There is no separation of the light Mg+ and the heavy Fe+ with increasing altitude as expected for gravity control. The metal ions are well-mixed with the neutral atmosphere at altitudes where no mixing process is expected. Isolated metal ion layers mimicking Earths sporadic E layers occur despite the lack of a strong magnetic field as required at Earth. Further, the metal ion distributions are coherent enough to always show atmospheric gravity wave signatures. All features and processes are unique to Mars.

Active Radiation Detectors for Use in Space Beyond Low Earth Orbit: Spatial and Energy Resolution Requirements and Methods for Heavy Ion Charge Classification

NASA Astrophysics Data System (ADS)

McBeth, Rafe A.

Space radiation exposure to astronauts will need to be carefully monitored on future missions beyond low earth orbit. NASA has proposed an updated radiation risk framework that takes into account a significant amount of radiobiological and heavy ion track structure information. These models require active radiation detection systems to measure the energy and ion charge Z. However, current radiation detection systems cannot meet these demands. The aim of this study was to investigate several topics that will help next generation detection systems meet the NASA objectives. Specifically, this work investigates the required spatial resolution to avoid coincident events in a detector, the effects of energy straggling and conversion of dose from silicon to water, and methods for ion identification (Z) using machine learning. The main results of this dissertation are as follows: 1. Spatial resolution on the order of 0.1 cm is required for active space radiation detectors to have high confidence in identifying individual particles, i.e., to eliminate coincident events. 2. Energy resolution of a detector system will be limited by energy straggling effects and the conversion of dose in silicon to dose in biological tissue (water). 3. Machine learning methods show strong promise for identification of ion charge (Z) with simple detector designs.

Solar cycle variation of interstellar neutral He, Ne, O density and pick-up ions along the Earth's orbit

NASA Astrophysics Data System (ADS)

Sokół, Justyna M.; Bzowski, Maciej; Kubiak, Marzena A.; Möbius, Eberhard

2016-06-01

We simulated the modulation of the interstellar neutral (ISN) He, Ne, and O density and pick-up ion (PUI) production rate and count rate along the Earth's orbit over the solar cycle (SC) from 2002 to 2013 to verify if SC-related effects may modify the inferred ecliptic longitude of the ISN inflow direction. We adopted the classical PUI model with isotropic distribution function and adiabatic cooling, modified by time- and heliolatitude-dependent ionization rates and non-zero injection speed of PUIs. We found that the ionization losses have a noticeable effect on the derivation of the ISN inflow longitude based on the Gaussian fit to the crescent and cone peak locations. We conclude that the non-zero radial velocity of the ISN flow and the energy range of the PUI distribution function that is accumulated are of importance for a precise reproduction of the PUI count rate along the Earth orbit. However, the temporal and latitudinal variations of the ionization in the heliosphere, and particularly their variation on the SC time-scale, may significantly modify the shape of PUI cone and crescent and also their peak positions from year to year and thus bias by a few degrees the derived longitude of the ISN gas inflow direction.

Argon ion pollution of the magnetosphere

NASA Technical Reports Server (NTRS)

Lopez, R. E.

1985-01-01

Construction of a Solar Power Satellite (SPS) would require the injection of large quantities of propellant to transport material from Low Earth Orbit (LEO) to the construction site at Geostationary Earth Orbit (GEO). This injection, in the form of approx 10 to the 32nd power, 2 KeV argon ions (and associated electrons) per SPS, is comparable to the content of the plasmasphere (approx 10 to the 31st power ions). In addition to the mass deposited, this represents a considerable injection of energy. The injection is examined in terms of a simple model for the expansion of the beam plasma. General features of the subsequent magnetospheric convection of the argon are also examined.

Effects of rare earth doping on multi-core iron oxide nanoparticles properties

NASA Astrophysics Data System (ADS)

Petran, Anca; Radu, Teodora; Borodi, Gheorghe; Nan, Alexandrina; Suciu, Maria; Turcu, Rodica

2018-01-01

New multi-core iron oxide magnetic nanoparticles doped with rare earth metals (Gd, Eu) were obtained by a one step synthesis procedure using a solvothermal method for potential biomedical applications. The obtained clusters were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy-dispersive X-ray microanalysis (EDX), X-ray photoelectron spectroscopy (XPS) and magnetization measurements. They possess high colloidal stability, a saturation magnetization of up to 52 emu/g, and nearly spherical shape. The presence of rare earth ions in the obtained samples was confirmed by EDX and XPS. XRD analysis proved the homogeneous distribution of the trivalent rare earth ions in the inverse-spinel structure of magnetite and the increase of crystal strain upon doping the samples. XPS study reveals the valence state and the cation distribution on the octahedral and tetrahedral sites of the analysed samples. The observed shift of the XPS valence band spectra maximum in the direction of higher binding energies after rare earth doping, as well as theoretical valence band calculations prove the presence of Gd and Eu ions in octahedral sites. The blood protein adsorption ability of the obtained samples surface, the most important factor of the interaction between biomaterials and body fluids, was assessed by interaction with bovine serum albumin (BSA). The rare earth doped clusters surface show higher afinity for binding BSA. In vitro cytotoxicity test results for the studied samples showed no cytotoxicity in low and medium doses, establishing a potential perspective for rare earth doped MNC to facilitate multiple therapies in a single formulation for cancer theranostics.

Observations of nonadiabatic acceleration of ions in Earth's magnetotail

NASA Technical Reports Server (NTRS)

Frank, L. A.; Paterson, W. R.; Kivelson, M. G.

1994-01-01

We present observations of the three-dimensional velocity distributions of protons in the energy range 20 eV to 52 keV at locations within and near the current sheet of Earth's magnetotail at geocentric radial distances 35 to 87 R(sub E). These measurements were acquired on December 8, 1990, with a set of electrostatic analyzers on board the Galileo spacecraft during its approach to Earth in order to obtain one of its gravitational assists to Jupiter. It is found that the velocity distributions are inadequately described as quasi-Maxwellian distributions such as those found in the central plasma sheet at positions nearer to Earth. Instead the proton velocity distributions can be categorized into two major types. The first type is the 'lima bean' shaped distribution with high-speed bulk flows and high temperatures that are similar to those found nearer to Earth in the plasma sheet boundary layer. The second type consists of colder protons with considerably lesser bulk flow speeds. Examples of velocity distributions are given for the plasma mantle, a region near the magnetic neutral line, positions earthward and tailward of the neutral line, and the plasma sheet boundary layer. At positions near the neutral line, only complex velocity distributions consisting of the colder protons are found, whereas both of the above types of distributions are found in and near the current sheet at earthward and tailward locations. Bulk flows are directed generally earthward and tailward at positions earthward and tailward of the neutral line, respectively. Only the high-speed, hot distribution is present in the plasma sheet boundary layer. The observations are interpreted in terms of the nonadiabatic acceleration of protons that flow into the current sheet from the plasma mantle. For this interpretation the hot, 'lima bean' shaped distributions are associated with meandering, or Speiser, orbits in the current sheet. It is suggested that the colder, lower-speed proton velocity

Rare Earth Doped High Temperature Ceramic Selective Emitters

NASA Technical Reports Server (NTRS)

Chubb, Donald L.; Pal, AnnaMarie; Patton, Martin O.; Jenkins, Phillip P.

1999-01-01

As a result of their electron structure, rare earth ions in crystals at high temperature emit radiation in several narrow bands rather than in a continuous blackbody manner. This study develops a spectral emittance model for films of rare earth containing materials. Although there are several possible rare earth doped high temperature materials, this study was confined to rare earth aluminum garnets. Good agreement between experimental and theoretical spectral emittances was found for erbium, thulium and erbium-holmium aluminum garnets. Spectral emittances of these films are sensitive to temperature differences across the film. Emitter efficiency is also a sensitive function of temperature. For thulium aluminum garnet the efficiency is 0.38 at 1700 K but only 0.19 at 1262 K.

Hybrid simulation techniques applied to the earth's bow shock

NASA Technical Reports Server (NTRS)

Winske, D.; Leroy, M. M.

1985-01-01

The application of a hybrid simulation model, in which the ions are treated as discrete particles and the electrons as a massless charge-neutralizing fluid, to the study of the earth's bow shock is discussed. The essentials of the numerical methods are described in detail; movement of the ions, solution of the electromagnetic fields and electron fluid equations, and imposition of appropriate boundary and initial conditions. Examples of results of calculations for perpendicular shocks are presented which demonstrate the need for a kinetic treatment of the ions to reproduce the correct ion dynamics and the corresponding shock structure. Results for oblique shocks are also presented to show how the magnetic field and ion motion differ from the perpendicular case.

Solvation structures and dynamics of alkaline earth metal halides in supercritical water: A molecular dynamics study

NASA Astrophysics Data System (ADS)

Keshri, Sonanki; Mandal, Ratnamala; Tembe, B. L.

2016-09-01

Constrained molecular dynamics simulations of alkaline earth metal halides have been carried out to investigate their structural and dynamical properties in supercritical water. Potentials of mean force (PMFs) for all the alkaline earth metal halides in supercritical water have been computed. Contact ion pairs (CIPs) are found to be more stable than all other configurations of the ion pairs except for MgI2 where solvent shared ion pair (SShIP) is more stable than the CIP. There is hardly any difference in the PMFs between the M2+ (M = Mg, Ca, Sr, Ba) and the X- (X = F, Cl, Br, I) ions whether the second X- ion is present in the first coordination shell of the M2+ ion or not. The solvent molecules in the solvation shells diffuse at a much slower rate compared to the bulk. Orientational distribution functions of solvent molecules are sharper for smaller ions.

MAGNETIC PROPERTIES OF RARE EARTH ALUMINUM COMPOUNDS WITH MgCu$sub 2$ STRUCTURE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, H.J.; Wernick, J.H.; Nesbitt, E.A.

1962-03-01

The magnetic moments of some RAl/sub 2/ (R = rare earth element) cubic Laves phase compounds were measured at temperatures from 1.4 to 300 deg K. The measurements indicate that the spin moments of the rare earth ions are coupled ferromagnetically. The Curie points of the RAl/sub 2/ compounds are found to be uniformly higher than the corresponding Laves compounds, ROs/sub 2/, Rlr/sub 2/ and RRu/sub 2/. Solid solutions of some of the compounds were also investigated. For example, in the Gd/sub x/Pr/sub (1-x)/Al/sub 2/ compounds, the magnetic moments of the Gd ions are antiparallel to those of the Prmore » ions because J is antiparallel to S in the ground state of the Pr ion. Compensation points were observed in this system. (auth)« less

Low-Power Ion Propulsion for Small Spacecraft

NASA Technical Reports Server (NTRS)

Patterson, Michael J.; Oleson, Steven R.

1997-01-01

Analyses were conducted which indicate that sub kW-class ion thrusters may provide performance benefits for near-Earth space commercial and science missions. Small spacecraft applications with masses ranging from 50 to 500 kg and power levels less than 0.5 kW were considered. To demonstrate the efficacy of propulsion systems of this class, two potential missions were chosen as examples; a geosynchronous north-south station keeping application, and an Earth orbit magnetospheric mapping satellite constellation. Xenon ion propulsion system solutions using small thrusters were evaluated for these missions. A payload mass increase of more than 15% is provided by a 300-W ion system for the north-south station keeping mission. A launch vehicle reduction from four to one results from using the ion thruster for the magnetospheric mapping mission. Typical projected thruster performance over the input power envelope of 100-300 W range from approximately 40% to 54% efficiency and approximately 2000 to 3000 seconds specific impulse. Thruster technologies required to achieve the mission-required performance and lifetime are identified.

Synthesis of ion-exchange resin for selective thorium and uranyl ions sorption

NASA Astrophysics Data System (ADS)

Konovalov, Konstantin; Sachkov, Victor

2017-11-01

In this work, the method of ion-exchange resin synthesis selective to radionuclides (uranium and thorium) is presented. The method includes synthesis of polymeric styrene-divinylbenzene macroporous matrix with size of 0.1-0.2 mm, and its subsequent transformation by nitration and then reduction by tin (II) chloride. For passivation of active primary amines partially oxidation by oxygen from air is used. Obtained ion-exchange resin has ratio of sorption sum U+Th to sorption sum of other total rare-earth elements as 1:1.88 at ratio of solid to liquid phase 1:200. The proposed method of ion-exchange resin synthesis is scaled-up for laboratory reactors with volume of 5 and 50 liters.

Superposition-model analysis of rare-earth doped BaY2F8

NASA Astrophysics Data System (ADS)

Magnani, N.; Amoretti, G.; Baraldi, A.; Capelletti, R.

The energy level schemes of four rare-earth dopants (Ce3+ , Nd3+ , Dy3+ , and Er3+) in BaY2 F-8 , as determined by optical absorption spectra, were fitted with a single-ion Hamiltonian and analysed within Newman's Superposition Model for the crystal field. A unified picture for the four dopants was obtained, by assuming a distortion of the F- ligand cage around the RE site; within the framework of the Superposition Model, this distortion is found to have a marked anisotropic behaviour for heavy rare earths, while it turns into an isotropic expansion of the nearest-neighbours polyhedron for light rare earths. It is also inferred that the substituting ion may occupy an off-center position with respect to the original Y3+ site in the crystal.

Metal sulfide and rare-earth phosphate nanostructures and methods of making same

DOEpatents

Wong, Stanislaus; Zhang, Fen

2016-06-28

The present invention provides a method of producing a crystalline rare earth phosphate nanostructure. The method comprising: providing a rare earth metal precursor solution and providing a phosphate precursor solution; placing a porous membrane between the metal precursor solution and the phosphate precursor solution, wherein metal cations of the metal precursor solution and phosphate ions of the phosphate precursor solution react, thereby producing a crystalline rare earth metal phosphate nanostructure.

Earth orbital assessment of solar electric and solar sail propulsion systems

NASA Technical Reports Server (NTRS)

Teeter, R. R.

1977-01-01

The earth orbital applications potential of Solar Electric (Ion Drive) and Solar Sail low-thrust propulsion systems are evaluated. Emphasis is placed on mission application in the 1980s. The two low-thrust systems are compared with each other and with two chemical propulsion Shuttle upper stages (the IUS and SSUS) expected to be available in the 1980s. The results indicate limited Earth orbital application potential for the low-thrust systems in the 1980s (primarily due to cost disadvantages). The longer term potential is viewed as more promising. Of the two systems, the Ion Drive exhibits better performance and appears to have better overall application potential.

Thermophysical properties of liquid rare earth metals

NASA Astrophysics Data System (ADS)

Thakor, P. B.; Sonvane, Y. A.; Patel, H. P.; Jani, A. R.

2013-06-01

The thermodynamical properties like long wavelength limit S(0), iso-thermal compressibility (χT), thermal expansion coefficient (αV), thermal pressure coefficient (γV), specific heat at constant volume (CV) and specific heat at constant pressure (CP) are calculated for liquid rare earth metals. Our newly constructed parameter free model potential is used to describe the electron ion interaction due to Sarkar et al (S) local field correction function. Lastly, we conclude that our newly constructed model potential is capable to explain the thermophysical properties of liquid rare earth metals.

Heavy ion-acoustic rogue waves in electron-positron multi-ion plasmas

NASA Astrophysics Data System (ADS)

Chowdhury, N. A.; Mannan, A.; Hasan, M. M.; Mamun, A. A.

2017-09-01

The nonlinear propagation of heavy-ion-acoustic (HIA) waves (HIAWs) in a four-component multi-ion plasma (containing inertial heavy negative ions and light positive ions, as well as inertialess nonextensive electrons and positrons) has been theoretically investigated. The nonlinear Schrödinger (NLS) equation is derived by employing the reductive perturbation method. It is found that the NLS equation leads to the modulational instability (MI) of HIAWs, and to the formation of HIA rogue waves (HIARWs), which are due to the effects of nonlinearity and dispersion in the propagation of HIAWs. The conditions for the MI of HIAWs and the basic properties of the generated HIARWs are identified. It is observed that the striking features (viz., instability criteria, growth rate of MI, amplitude and width of HIARWs, etc.) of the HIAWs are significantly modified by the effects of nonextensivity of electrons and positrons, the ratio of light positive ion mass to heavy negative ion mass, the ratio of electron number density to light positive ion number density, the ratio of electron temperature to positron temperature, etc. The relevancy of our present investigation to the observations in space (viz., cometary comae and earth's ionosphere) and laboratory (viz., solid-high intense laser plasma interaction experiments) plasmas is pointed out.

Heavy ion-acoustic rogue waves in electron-positron multi-ion plasmas.

PubMed

Chowdhury, N A; Mannan, A; Hasan, M M; Mamun, A A

2017-09-01

The nonlinear propagation of heavy-ion-acoustic (HIA) waves (HIAWs) in a four-component multi-ion plasma (containing inertial heavy negative ions and light positive ions, as well as inertialess nonextensive electrons and positrons) has been theoretically investigated. The nonlinear Schrödinger (NLS) equation is derived by employing the reductive perturbation method. It is found that the NLS equation leads to the modulational instability (MI) of HIAWs, and to the formation of HIA rogue waves (HIARWs), which are due to the effects of nonlinearity and dispersion in the propagation of HIAWs. The conditions for the MI of HIAWs and the basic properties of the generated HIARWs are identified. It is observed that the striking features (viz., instability criteria, growth rate of MI, amplitude and width of HIARWs, etc.) of the HIAWs are significantly modified by the effects of nonextensivity of electrons and positrons, the ratio of light positive ion mass to heavy negative ion mass, the ratio of electron number density to light positive ion number density, the ratio of electron temperature to positron temperature, etc. The relevancy of our present investigation to the observations in space (viz., cometary comae and earth's ionosphere) and laboratory (viz., solid-high intense laser plasma interaction experiments) plasmas is pointed out.

Rare earth-doped lead borate glasses and transparent glass-ceramics: structure-property relationship.

PubMed

Pisarski, W A; Pisarska, J; Mączka, M; Lisiecki, R; Grobelny, Ł; Goryczka, T; Dominiak-Dzik, G; Ryba-Romanowski, W

2011-08-15

Correlation between structure and optical properties of rare earth ions in lead borate glasses and glass-ceramics was evidenced by X-ray-diffraction, Raman, FT-IR and luminescence spectroscopy. The rare earths were limited to Eu(3+) and Er(3+) ions. The observed BO(3)↔BO(4) conversion strongly depends on the relative PbO/B(2)O(3) ratios in glass composition, giving important contribution to the luminescence intensities associated to (5)D(0)-(7)F(2) and (5)D(0)-(7)F(1) transitions of Eu(3+). The near-infrared luminescence and up-conversion spectra for Er(3+) ions in lead borate glasses before and after heat treatment were measured. The more intense and narrowing luminescence lines suggest partial incorporation of Er(3+) ions into the orthorhombic PbF(2) crystalline phase, which was identified using X-ray diffraction analysis. Copyright © 2010 Elsevier B.V. All rights reserved.

The equilibrium of atmospheric sodium. [in atmospheres of Earth, Io, Mercury and Moon

NASA Technical Reports Server (NTRS)

Hunten, Donald M.

1992-01-01

We now have four examples of planetary objects with detectable sodium (and potassium) in their atmospheres: Earth, Io, Mercury and the moon. After a summary of the observational data, this survey discusses proposed sources and sinks. It appears that Io's surface material is rich in frozen SO2, but with around 1 percent of some sodium compound. The Io plasma torus contains ions of S, O and Na, also with at least one molecular ion containing Na. In turn, impact by these ions probably sustains the torus, as well as an extended neutral corona. A primary source for the Earth, Mercury and the moon is meteoroidal bombardment; at Mercury and perhaps the moon it may be supplemented by degassing of atoms from the regolith. Photoionization is important everywhere, although hot electrons are dominant at Io.

Towards a better understanding of high-energy electron pitch-angle scattering by electromagnetic ion cyclotron waves

NASA Astrophysics Data System (ADS)

Vincena, S.; Gekelman, W.; Pribyl, P.; Tang, S., W.,; Papadopoulos, K.

2017-10-01

Shear Alfven waves are a fundamental mode in magnetized plasmas. Propagating near the ion cyclotron frequency, these waves are often termed electromagnetic ion cyclotron (EMIC) waves and can involve multiple ion species. Near the earth, for example, the wave may interact resonantly with oxygen ions at altitudes ranging from 1000 to 2000 km. The waves may either propagate from space towards the earth (possibly involving mode conversion), or be generated by RF transmitters on the ground. These preliminary experiments are motivated by theoretical predictions that such waves can pitch-angle scatter relativistic electrons trapped in the earth's dipole field. EMIC waves are launched in the Large Plasma Device at UCLA's Basic Plasma Science Facility in plasmas with single and multiple ion species into magnetic field gradients where ion cyclotron resonance is satisfied. We report here on the frequency and k-spectra in the critical layer and how they compare with theoretical predictions in computing an effective diffusion coefficient for high-energy electrons. Funding is provided by the NSF, DoE, and AFSOR.

Response of thermal ions to electromagnetic ion cyclotron waves

NASA Technical Reports Server (NTRS)

Anderson, B. J.; Fuselier, S. A.

1994-01-01

Electromagnetic ion cyclotron waves generated by 10 - 50 keV protons in the Earth's equatorial magnetosphere will interact with the ambient low-energy ions also found in this region. We examine H(+) and He(+) distribution functions from approx. equals 1 to 160 eV using the Hot Plasma Composition Experiment instrument on AMPTE/CCE to investigate the thermal ion response to the waves. A total of 48 intervals were chosen on the basis of electromagnetic ion cyclotron (EMIC) wave activity: 24 with prevalent EMIC waves and 24 with no EMIC waves observed on the orbit. There is a close correlation between EMIC waves and perpendicular heated ion distributions. For protons the perpendicular temperature increase is modest, about 5 eV, and is always observed at 90 deg pitch angles. This is consistent with a nonresonant interaction near the equator. By contrast, He(+) temperatures during EMIC wave events averaged 35 eV and sometimes exceeded 100 eV, indicating stronger interaction with the waves. Furthermore, heated He(+) ions have X-type distributions with maximum fluxes occurring at pitch angles intermediate between field-aligned and perpendicular directions. The X-type He(+) distributions are consistent with a gyroresonant interaction off the equator. The concentration of He(+) relative to H(+) is found to correlate with EMIC wave activity, but it is suggested that the preferential heating of He(+) accounts for the apparent increase in relative He(+) concentration by increasing the proportion of He(+) detected by the ion instrument.

First Satellite Measurement of the ULF Wave Growth Rate in the Ion Foreshock

NASA Astrophysics Data System (ADS)

Dorfman, Seth

2017-10-01

Waves generated by accelerated particles are important throughout our heliosphere. These particles often gain their energy at shocks via Fermi acceleration. At the Earth's bow shock, this mechanism accelerates ion beams back into the solar wind; the beams can then generate ultra low frequency (ULF) waves via an ion-ion right hand resonant instability. These waves influence the shock structure and particle acceleration, lead to coherent structures in the magnetosheath, and are ideal for non-linear interaction studies relevant to turbulence. We report the first satellite measurement of the ultralow frequency (ULF) wave growth rate in the upstream region of the Earth's bow shock. This is made possible by employing the two ARTEMIS spacecraft orbiting the moon at 60 Earth radii from Earth to characterize crescent-shaped reflected ion beams and relatively monochromatic ULF waves. The event to be presented features spacecraft separation of 2.5 Earth radii (0.9 +/- 0.1 wavelengths) in the solar wind flow direction along a nearly radial interplanetary magnetic field. By contrast, most prior ULF wave observations use spacecraft with insufficient separation to see wave growth and are so close to Earth (within 30 Earth radii) that waves convected from different events interfere. Using ARTEMIS data, the ULF wave growth rate is estimated and found to fall within dispersion solver predictions during the initial growth time. Observed frequencies and wave numbers are within the predicted range. Other ULF wave properties such as the phase speed, obliquity, and polarization are consistent with expectations from resonant beam instability theory and prior satellite measurements. These results not only advance our understanding of the foreshock, but will also inform future nonlinear studies related to turbulence and dissipation in the heliosphere. Supported by NASA, NASA Eddy Postdoctoral Fellowship.

Controlling Factors of the Fate of Ionospheric Outflow at Earth and Mars

NASA Astrophysics Data System (ADS)

Liemohn, M. W.; Welling, D. T.; Ilie, R.; Ganushkina, N. Y.; Johnson, B. C.; Xu, S.; Dong, C.

2015-12-01

Both Earth and Mars experience ionospheric outflow, but the radically different magnetic field configurations at the two planets yield significantly different patterns of outflow and processes governing outflow. This study examines a set of numerical simulations for Earth and Mars to explore the factors controlling ionospheric outflow and the fate of the escaping ions (immediate precipitation, magnetospheric recirculation, or loss to deep space). Specifically, simulation results from the Space Weather Modeling Framework (SWMF), which is capable of handling both planetary space environments, are analyzed to assess the physical processes governing the fate of ionospheric ions. Velocity streamlines from the SWMF results are traced from the high-latitude inner boundary of the BATS-R-US MHD simulation domain and followed through geospace. Some of these streamlines return to the inner boundary of the simulation domain, others extend to the outer boundary of the domain, while most others eventually cross (or at least approach) the magnetospheric equatorial plane. At Earth, this plane is well defined, while at Mars there are multiple mini-magnetospheres in which ionospheric ions can become trapped. These streamlines are categorized according to their eventual destination. Multi-fluid MHD simulations are examined in this study, assessing the influence of species mass on trajectories through near-planet space. Steady-state numerical experiments with different levels of solar driving are examined to quantify the influence of each driver on outflow characteristics and the fate of outflowing ions. Real event intervals are considered to assess flows in a time-varying magnetospheric system. For Earth, as solar wind dynamic pressure increases, the dominant outflow region moves to lower latitudes and significantly more of the outflowing ions escape to deep space. As the interplanetary magnetic field increases in southward magnitude, the region of dominant outflow shifts to lower

Use of natural clays as sorbent materials for rare earth ions: Materials characterization and set up of the operative parameters.

PubMed

Iannicelli-Zubiani, Elena Maria; Cristiani, Cinzia; Dotelli, Giovanni; Gallo Stampino, Paola; Pelosato, Renato; Mesto, Ernesto; Schingaro, Emanuela; Lacalamita, Maria

2015-12-01

Two mineral clays of the montmorillonite group were tested as sorbents for the removal of Rare Earths (REs) from liquid solutions. Lanthanum and neodymium model solutions were used to perform uptake tests in order to: (a) verify the clays sorption capability, (b) investigate the sorption mechanisms and (c) optimize the experimental parameters, such as contact time and pH. The desorption was also studied, in order to evaluate the feasibility of REs recovery from waters. The adsorption-desorption procedure with the optimized parameters was also tested on a leaching solution obtained by dissolution of a dismantled NdFeB magnet of a hard-disk. The clays were fully characterized after REs adsorption and desorption by means of X-ray powder diffraction (XRPD) and X-ray photoelectron spectroscopy (XPS); the liquid phase was characterized via Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) analyses. The experimental results show that both clays are able to capture and release La and Nd ions, with an ion exchange mechanism. The best total efficiency (capture ≈ 50%, release ≈ 70%) is obtained when the uptake and release processes are performed at pH=5 and pH=1 respectively; in real leached scrap solutions, the uptake is around 40% but release efficiency is strongly decreased passing from a mono-ion system to a real system (from 80% to 5%). Furthermore, a strong matrix effect is found, with the matrix largely affecting both the uptake and the release of neodymium. Copyright © 2015 Elsevier Ltd. All rights reserved.

Energetic ion and cosmic ray characteristics of a magnetic cloud

NASA Astrophysics Data System (ADS)

Sanderson, T. R.; Beeck, J.; Marsden, R. G.; Tranquille, C.; Wenzel, K.-P.; McKibben, R. B.; Smith, E. J.

The large interplanetary shock event of February 11, 1982, has yielded ISEE-3 energetic ion and magnetic field data as well as ground-based neutron-monitor cosmic-ray data. The timing and the onset of the Forbush decrease associated with this shock event coincide with the arrival at the earth of its magnetic cloud component; the duration of the decrease, similarly, corresponds to that of the cloud's passage past the earth. The large scattering mean free path readings suggest that while magnetic cloud ions can easily travel along magnetic field lines, they cannot travel across them, so that they cannot escape the cloud after entering it. Similarly, the cloud field lines prevented cosmic ray entrance, and could have prevented their reaching the earth. The cloud is therefore a major basis for the Forbush decrease.

Rare Earth elements in individual minerals in Shergottites

NASA Technical Reports Server (NTRS)

Wadhwa, Meenakshi; Crozaz, Ghislaine

1993-01-01

Shergottites (i.e., Shergotty, Zagami, EETA79001, ALHA77005, and LEW88516) are an important set of achondrites because they comprise the majority of the SNC group of meteorites (nine, in total, known to us), which are likely to be samples of the planet Mars. Study of these meteorites may therefore provide valuable information about petrogenetic processes on a large planetary body other than Earth. Rare earth element (REE) distributions between various mineral phases were found to be useful in geochemically modeling the petrogenesis of various rock types (terrestrial and meteoritic). However, with the exception of a few ion microprobe studies and analyses of mineral separates, there has previously not been any comprehensive effort to characterize and directly compare REE in individual minerals in each of the five known shergottites. Ion microprobe analyses were made on thin sections of each of the shergottites. Minerals analyzed were pyroxenes (pigeonite and augite), maskelynite, and whitlockite. The REE concentrations in each mineral type in each shergottite is given.

Computer simulations of electromagnetic cool ion beam instabilities. [in near earth space

NASA Technical Reports Server (NTRS)

Gary, S. P.; Madland, C. D.; Schriver, D.; Winske, D.

1986-01-01

Electromagnetic ion beam instabilities driven by cool ion beams at propagation parallel or antiparallel to a uniform magnetic field are studied using computer simulations. The elements of linear theory applicable to electromagnetic ion beam instabilities and the simulations derived from a one-dimensional hybrid computer code are described. The quasi-linear regime of the right-hand resonant ion beam instability, and the gyrophase bunching of the nonlinear regime of the right-hand resonant and nonresonant instabilities are examined. It is detected that in the quasi-linear regime the instability saturation is due to a reduction in the beam core relative drift speed and an increase in the perpendicular-to-parallel beam temperature; in the nonlinear regime the instabilities saturate when half the initial beam drift kinetic energy density is converted to fluctuating magnetic field energy density.

Coronal mass ejection (CME) activity of low mass M stars as an important factor for the habitability of terrestrial exoplanets. II. CME-induced ion pick up of Earth-like exoplanets in close-in habitable zones.

PubMed

Lammer, Helmut; Lichtenegger, Herbert I M; Kulikov, Yuri N; Griessmeier, Jean-Mathias; Terada, N; Erkaev, Nikolai V; Biernat, Helfried K; Khodachenko, Maxim L; Ribas, Ignasi; Penz, Thomas; Selsis, Franck

2007-02-01

Atmospheric erosion of CO2-rich Earth-size exoplanets due to coronal mass ejection (CME)-induced ion pick up within close-in habitable zones of active M-type dwarf stars is investigated. Since M stars are active at the X-ray and extreme ultraviolet radiation (XUV) wave-lengths over long periods of time, we have applied a thermal balance model at various XUV flux input values for simulating the thermospheric heating by photodissociation and ionization processes due to exothermic chemical reactions and cooling by the CO2 infrared radiation in the 15 microm band. Our study shows that intense XUV radiation of active M stars results in atmospheric expansion and extended exospheres. Using thermospheric neutral and ion densities calculated for various XUV fluxes, we applied a numerical test particle model for simulation of atmospheric ion pick up loss from an extended exosphere arising from its interaction with expected minimum and maximum CME plasma flows. Our results indicate that the Earth-like exoplanets that have no, or weak, magnetic moments may lose tens to hundreds of bars of atmospheric pressure, or even their whole atmospheres due to the CME-induced O ion pick up at orbital distances Earth radius above the surface. Furthermore, our study indicates that magnetic moments of tidally locked Earth-like exoplanets are essential for protecting their expanded upper atmospheres because of intense XUV radiation against CME plasma erosion. Therefore, we suggest that larger and more massive terrestrial-type exoplanets may better protect their

Rare earth activated yttrium aluminate phosphors with modulated luminescence.

PubMed

Muresan, L E; Popovici, E J; Perhaita, I; Indrea, E; Oro, J; Casan Pastor, N

2016-06-01

Yttrium aluminate (Y3 A5 O12 ) was doped with different rare earth ions (i.e. Gd(3+) , Ce(3+) , Eu(3+) and/or Tb(3+) ) in order to obtain phosphors (YAG:RE) with general formula,Y3-x-a Gdx REa Al5 O12 (x = 0; 1.485; 2.97 and a = 0.03). The synthesis of the phosphor samples was done using the simultaneous addition of reagents technique. This study reveals new aspects regarding the influence of different activator ions on the morpho-structural and luminescent characteristics of garnet type phosphor. All YAG:RE phosphors are well crystallized powders containing a cubic-Y3 Al5 O12 phase as major component along with monoclinic-Y4 Al2 O9 and orthorhombic-YAlO3 phases as the impurity. The crystallites dimensions of YAG:RE phosphors vary between 38 nm and 88 nm, while the unit cell slowly increase as the ionic radius of the activator increases. Under UV excitation, YAG:Ce exhibits yellow emission due to electron transition in Ce(3+) from the 5d level to the ground state levels ((2) F5/2 , (2) F7/2 ). The emission intensity of Ce(3+) is enhanced in the presence of the Tb(3+) ions and is decreased in the presence of Eu(3+) ions due to some radiative or non-radiative processes that take place between activator ions. By varying the rare earth ions, the emission colour can be modulated from green to white and red. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.

Rare Earth Element Partition Coefficients from Enstatite/Melt Synthesis Experiments

NASA Technical Reports Server (NTRS)

Schwandt, Craig S.; McKay, Gordon A.

1997-01-01

Enstatite (En(80)Fs(19)Wo(01)) was synthesized from a hypersthene normative basaltic melt doped at the same time with La, Ce, Nd, Sm, Eu, Dy, Er, Yb and Lu. The rare earth element concentrations were measured in both the basaltic glass and the enstatite. Rare earth element concentrations in the glass were determined by electron microprobe analysis with uncertainties less than two percent relative. Rare earth element concentrations in enstatite were determined by secondary ion mass spectrometry with uncertainties less than five percent relative. The resulting rare earth element partition signature for enstatite is similar to previous calculated and composite low-Ca pigeonite signatures, but is better defined and differs in several details. The partition coefficients are consistent with crystal structural constraints.

Juno JEDI high latitude snapshot of Earth's energetic charged particle distributions during the coordinated Juno spacecraft encounter with Earth

NASA Astrophysics Data System (ADS)

Paranicas, C.; Mauk, B.; Haggerty, D. K.; Schlemm, C.; Jaskulek, S.; Kim, C.; Brown, L. E.; Bagenal, F.; Thorne, R. M.

2013-12-01

NASA's Juno spacecraft will begin its orbit of Jupiter in mid-2016. During Juno's gravity assist encounter with Earth on October 9, 2013, the Jupiter Energetic Particle Detector Instrument (JEDI) will take measurements of the energetic electron and ion distributions at relatively high latitudes. These measurements will contribute substantially to a coordinated activity to obtain a comprehensive characterization of Earth's space environment during the encounter period. Here we present and describe the JEDI measurements and discuss them in the context of measurements taken at the same time, including those obtained by the Van Allen Probes mission. JEDI comprises three nearly identical energetic charged particle sensors. Each sensor detects energetic electrons (above 25 keV up to > 1000 keV) and energetic ions (about 20 keV to > 1 MeV for protons, and 50 keV to > 10 MeV for oxygen and sulfur) with high energy, time, and angular resolution. Two of the sensors are fans viewing almost entirely in the plane perpendicular to Juno's high-gain antenna. The third fan is perpendicular to this plane, so that combined with the spacecraft spin rate of about 2 rpm, nearly the whole sky is sampled every 30 s. During the gravitational assist encounter of Earth, JEDI obtains continuous data from about 3 days prior to closest approach through at least 2 weeks after closest approach. This will include data obtained outside and through the bow shock and magnetosheath, to deep within the magnetosphere. Due to the low flyby altitude of about 560 km, JEDI will operate its high voltage (thereby obtaining ion composition information) only outside of a few RE geocentric distances. Also, by using the so-called witness detectors, on one of the three sensors, the instrument is expected to obtain an integral channel measurement inside the radiation belts.

Formation Mechanism, Structural, and Upconversion Properties of Alkaline Rare-Earth Fluoride Nanocrystals Doped With Yb3+/Er3+ Ions.

PubMed

Grzyb, Tomasz; Przybylska, Dominika

2018-06-04

Ultrasmall (9-30 nm) Yb 3+ /Er 3+ -doped, upconverting alkaline rare-earth fluorides that are promising for future applications were synthesized by the microwave-assisted hydrothermal method. The formation mechanism was proposed, indicating the influence of the stability of metal ions complexes with ethylenediaminetetraacetic acid on the composition of the product and tendency to form M 2 REF 7 (M 0.67 RE 0.33 F 2.33 ) cubic compounds in the M-RE-F systems. Their physicochemical properties (structure, morphology, and spectroscopic properties) are compared and discussed. The obtained nanoparticles exhibited emission of light in the visible spectra under excitation by 976 nm laser radiation. Excitation and emission spectra, luminescence decays, laser energy dependencies, and upconversion quantum yields were measured to determine the spectroscopic properties of prepared materials. The Yb 3+ /Er 3+ pair of ions used as dopants was responsible for an intense yellowish-green emission. The upconversion quantum yields determined for the first time for M 2 REF 7 -based materials were 0.0192 ± 0.001% and 0.0176 ± 0.001% for Sr 2 LuF 7 :Yb 3+ ,Er 3+ and Ba 2 LuF 7 :Yb 3+ ,Er 3+ respectively, the two best emitting samples. These results indicated the prepared materials are good and promising alternatives for the most studied NaYF 4 :Yb 3+ ,Er 3+ nanoparticles.

Separation and preconcentration of the rare-earth elements and yttrium from geological materials by ion-exchange and sequential acid elution

USGS Publications Warehouse

Crock, J.G.; Lichte, F.E.; Riddle, G.O.; Beech, C.L.

1986-01-01

The abundance of rare-earth elements (REE) and yttrium in geological materials is generally low, and most samples contain elements that interfere in the determination of the REE and Y, so a separation and/or preconcentration step is often necessary. This is often achieved by ion-exchange chromatography with either nitric or hydrochloric acid. It is advantageous, however, to use both acids sequentially. The final solution thus obtained contains only the REE and Y, with minor amounts of Al, Ba, Ca, Sc, Sr and Ti. Elements that potentially interfere, such as Be, Co, Cr, Fe, Mn, Th, U, V and Zr, are virtually eliminated. Inductively-coupled argon plasma atomic-emission spectroscopy can then be used for a final precise and accurate measurement. The method can also be used with other instrumental methods of analysis. ?? 1986.

International Space Station Lithium-Ion Battery

NASA Technical Reports Server (NTRS)

Dalton, Penni J.; Balcer, Sonia

2016-01-01

The International Space Station (ISS) Electric Power System (EPS) currently uses Nickel-Hydrogen (Ni-H2) batteries to store electrical energy. The batteries are charged during insolation and discharged during eclipse. The Ni-H2 batteries are designed to operate at a 35 depth of discharge (DOD) maximum during normal operation in a Low Earth Orbit. Since the oldest of the 48 Ni-H2 battery Orbital Replacement Units (ORUs) has been cycling since September 2006, these batteries are now approaching their end of useful life. In 2010, the ISS Program began the development of Lithium-Ion (Li-ion) batteries to replace the Ni-H2 batteries and concurrently funded a Li-ion cell life testing project. This paper will include an overview of the ISS Li-Ion battery system architecture and the progress of the Li-ion battery design and development.

Hydration energies and structures of alkaline earth metal ions, M2+(H2O)n, n = 5-7, M = Mg, Ca, Sr, and Ba.

PubMed

Rodriguez-Cruz, S E; Jockusch, R A; Williams, E R

1999-09-29

The evaporation of water from hydrated alkaline earth metal ions, produced by electrospray ionization, was studied in a Fourier transform mass spectrometer. Zero-pressure-limit dissociation rate constants for loss of a single water molecule from the hydrated divalent metal ions, M(2+)(H(2)O)(n) (M = Mg, Ca, and Sr for n = 5-7, and M = Ba for n = 4-7), are measured as a function of temperature using blackbody infrared radiative dissociation. From these values, zero-pressure-limit Arrhenius parameters are obtained. By modeling the dissociation kinetics using a master equation formalism, threshold dissociation energies (E(o)) are determined. These reactions should have a negligible reverse activation barrier; therefore, E(o) values should be approximately equal to the binding energy or hydration enthalpy at 0 K. For the hepta- and hexahydrated ions at low temperature, binding energies follow the trend expected on the basis of ionic radii: Mg > Ca > Sr > Ba. For the hexahydrated ions at high temperature, binding energies follow the order Ca > Mg > Sr > Ba. The same order is observed for the pentahydrated ions. Collisional dissociation experiments on the tetrahydrated species result in relative dissociation rates that directly correlate with the size of the metals. These results indicate the presence of two isomers for hexahydrated magnesium ions: a low-temperature isomer in which the six water molecules are located in the first solvation shell, and a high-temperature isomer with the most likely structure corresponding to four water molecules in the inner shell and two water molecules in the second shell. These results also indicate that the pentahydrated magnesium ions have a structure with four water molecules in the first solvation shell and one in the outer shell. The dissociation kinetics for the hexa- and pentahydrated clusters of Ca(2+), Sr(2+), and Ba(2+) are consistent with structures in which all the water molecules are located in the first solvation shell.

Geomagnetic transmission disturbances and heavy-ion fluences observed in low Earth orbit during the solar energetic particle events of October 1989.

PubMed

Boberg, P R; Tylka, A J; Adams, J H; Beahm, L P; Fluckiger, E O; Kleis, T; Kobel, E

1996-01-01

The large solar energetic particle (SEP) events and simultaneous large geomagnetic disturbances observed during October 1989 posed a significant, rapidly evolving space radiation hazard. Using data from the GOES-7, NOAA-10, IMP-8 and LDEF satellites, we determined the geomagnetic transmission, heavy ion fluences, mean Fe ionic charge state, and effective radiation hazard observed in low Earth orbit (LEO) for these SEPs. We modeled the geomagnetic transmission by tracing particles through the combination of the internal International Geomagnetic Reference Field (IGRF) and the Tsyganenko (1989) magnetospheric field models, extending the modeling to large geomagnetic disturbances. We used our results to assess the radiation hazard such very large SEP events would pose in the anticipated 52 degrees inclination space station orbit.

High time resolution characteristics of intermediate ion distributions upstream of the earth's bow shock

NASA Technical Reports Server (NTRS)

Potter, D. W.

1985-01-01

High time resolution particle data upstream of the bow shock during time intervals that have been identified as having intermediate ion distributions often show high amplitude oscillations in the ion fluxes of energy 2 and 6 keV. These ion oscillations, observed with the particle instruments of the University of California, Berkeley, on the ISEE 1 and 2 spacecraft, are at the same frequency (about 0.04 Hz) as the magnetic field oscillations. Typically, the 6-keV ion flux increases then the 2-keV flux increases followed by a decrease in the 2-keV flux and then the 6-keV flux decreases. This process repeats many times. Although there is no entirely satisfactory explanation, the presence of these ion flux oscillations suggests that distributions often are misidentified as intermediate ion distributions.

The SupraThermal Ion Monitor for space weather predictions.

PubMed

Allegrini, F; Desai, M I; Livi, S; McComas, D J; Ho, G C

2014-05-01

Measurement of suprathermal energy ions in the heliosphere has always been challenging because (1) these ions are situated in the energy regime only a few times higher than the solar wind plasma, where intensities are orders of magnitude higher and (2) ion energies are below or close to the threshold of state-of-art solid-state detectors. Suprathermal ions accelerated at coronal mass ejection-driven shocks propagate out ahead of the shocks. These shocks can cause geomagnetic storms in the Earth's magnetosphere that can affect spacecraft and ground-based power and communication systems. An instrument with sufficient sensitivity to measure these ions can be used to predict the arrival of the shocks and provide an advance warning for potentially geo-effective space weather. In this paper, we present a novel energy analyzer concept, the Suprathermal Ion Monitor (STIM) that is designed to measure suprathermal ions with high sensitivity. We show results from a laboratory prototype and demonstrate the feasibility of the concept. A list of key performances is given, as well as a discussion of various possible detectors at the back end. STIM is an ideal candidate for a future space weather monitor in orbit upstream of the near-earth environment, for example, around L1. A scaled-down version is suitable for a CubeSat mission. Such a platform allows proofing the concept and demonstrating its performance in the space environment.

Distribution of energetic oxygen and hydrogen in the near-Earth plasma sheet

NASA Astrophysics Data System (ADS)

Kronberg, E. A.; Grigorenko, E. E.; Haaland, S. E.; Daly, P. W.; Delcourt, D. C.; Luo, H.; Kistler, L. M.; Dandouras, I.

2015-05-01

The spatial distributions of different ion species are useful indicators for plasma sheet dynamics. In this statistical study based on 7 years of Cluster observations, we establish the spatial distributions of oxygen ions and protons at energies from 274 to 955 keV, depending on geomagnetic and solar wind (SW) conditions. Compared with protons, the distribution of energetic oxygen has stronger dawn-dusk asymmetry in response to changes in the geomagnetic activity. When the interplanetary magnetic field (IMF) is directed southward, the oxygen ions show significant acceleration in the tail plasma sheet. Changes in the SW dynamic pressure (Pdyn) affect the oxygen and proton intensities in the same way. The energetic protons show significant intensity increases at the near-Earth duskside during disturbed geomagnetic conditions, enhanced SW Pdyn, and southward IMF, implying there location of effective inductive acceleration mechanisms and a strong duskward drift due to the increase of the magnetic field gradient in the near-Earth tail. Higher losses of energetic ions are observed in the dayside plasma sheet under disturbed geomagnetic conditions and enhanced SW Pdyn. These observations are in agreement with theoretical models.

The firehose instability during multiple reconnection in the Earth's magnetotail

NASA Astrophysics Data System (ADS)

Alexandrova, Alexandra; Divin, Andrey; Retino, Alessandro; Deca, Jan; Catapano, Filomena; Cozzani, Giulia

2017-04-01

We found unique events in the Cluster spacecraft observations of the Earth's magnetotail which correspond to the case of multiple reconnection sites. The ion temperature anisotropy of more energized ions in the direction parallel to the magnetic field, rather than in the perpendicular direction, is observed in the region of dynamical interaction between two active X-lines. The magnetic field and plasma parameters associated with the anisotropy correspond to the firehose instability conditions. We discuss possible scenarios of development of the firehose instability in multiple reconnection by comparing the observations with numerical simulations. Conventional Particle-in-Cell simulations of 2D magnetic reconnection starting from Harris equilibria are performed using implicit PIC code iPIC3D [Markidis, 2010]. At earlier stages the evolution creates fronts which push the weakly magnetized current sheet plasma away from the X-line. Fronts accelerate and reflect particles, producing parallel ion beams and increasing parallel ion temperature ahead of the front. If multiple X-lines are present, then the counterstreaming ion beams appear inside the original current sheet between colliding reconnection jet fronts. For large enough parallel ion pressure anisotropy, the firehose-like mode is excited inside the original current sheet with a flapping-like appearance along the X GSM direction but not Y GSM (current) direction. One should note that our simulations do not include the Bz magnetic field component (normal to the current sheet), hence ion beams cannot escape into the lobes and the whole region between two colliding fronts is unstable to firehose-like instability. In the Earth's magnetotail such configuration likely occurs when two active X-lines are close enough to each other, similar to a few cases we found in the Cluster observations.

The outer magnetosphere. [composition and comparison with earth

NASA Technical Reports Server (NTRS)

Schardt, A. W.; Behannon, K. W.; Lepping, R. P.; Carbary, J. F.; Eviatar, A.; Siscoe, G. L.

1984-01-01

Similarities between the Saturnian and terrestrial outer magnetosphere are examined. Saturn, like earth, has a fully developed magnetic tail, 80 to 100 RS in diameter. One major difference between the two outer magnetospheres is the hydrogen and nitrogen torus produced by Titan. This plasma is, in general, convected in the corotation direction at nearly the rigid corotation speed. Energies of magnetospheric particles extend to above 500 keV. In contrast, interplanetary protons and ions above 2 MeV have free access to the outer magnetosphere to distances well below the Stormer cutoff. This access presumably occurs through the magnetotail. In addition to the H+, H2+, and H3+ ions primarily of local origin, energetic He, C, N, and O ions are found with solar composition. Their flux can be substantially enhanced over that of interplanetary ions at energies of 0.2 to 0.4 MeV/nuc.

Spherical solitons in Earth'S mesosphere plasma

NASA Astrophysics Data System (ADS)

Annou, K.; Annou, R.

2016-01-01

Soliton formation in Earth's mesosphere plasma is described. Nonlinear acoustic waves in plasmas with two-temperature ions and a variable dust charge where transverse perturbation is dealt with are studied in bounded spherical geometry. Using the perturbation method, a spherical Kadomtsev-Petviashvili equation that describes dust acoustic waves is derived. It is found that the parameters taken into account have significant effects on the properties of nonlinear waves in spherical geometry.

ISEE observations of low frequency waves and ion distribution function evolution in the plasma sheet boundary layer

NASA Technical Reports Server (NTRS)

Elphic, R. C.; Gary, S. P.

1990-01-01

This paper describes ISEE plasma and magnetic fluctuation observations during two crossings of the plasma sheet boundary layer (PSBL) in the earth's magnetotail. Distribution function observations show that the counterstreaming ion components undergo pitch-angle scattering and evolve into a shell distribution in velocity space. This evolution is correlated with the development of low frequency, low amplitude magnetic fluctuations. However, the measured wave amplitudes are insufficient to accomplish the observed degree of ion pitch-angle scatttering locally; the near-earth distributions may be the result of processes occurring much farther down the magnetotail. Results show a clear correlation between the ion component beta and the relative streaming speed of the two components, suggesting that electromagnetic ion/ion instabilities do play an important role in the scattering of PSBL ions.

Ion acceleration by Alfvén waves on auroral field lines

NASA Astrophysics Data System (ADS)

Bingham, Robert; Eliasson, Bengt; Tito Mendonça, José; Stenflo, Lennart

2013-05-01

Observations of ion acceleration along auroral field lines at the boundary of the plasma sheet and tail lobe of the Earth show that the energy of the ions increases with decreasing density. The observations can be explained by ion acceleration through Landau resonance with kinetic Alfvén waves (KAWs) such that kA·vi = ωA, where kA is the wave vector, vi is the ion resonance velocity and ωA is the Alfvén wave frequency. The ion resonance velocities are proportional to the Alfvén velocity which increases with decreasing density. This is in agreement with the data if the process is occurring at the plasma sheet tail lobe boundary. A quasi-linear theory of ion acceleration by KAWs is presented. These ions propagate both down towards and away from the Earth. The paths of the Freja and Polar satellites indicate that the acceleration takes place between the two satellites, between 1Re and 5Re. The downward propagating ions develop a horseshoe-type of distribution which has a positive slope in the perpendicular direction. This type of distribution can produce intense lower hybrid wave activity, which is also observed. Finally, the filamentation of shear Alfvén waves is considered. It may be responsible for large-scale density striations. In memory of Padma Kant Shukla, a great scientist and a good friend.

Multiple rare-earth ion environments in amorphous (Gd2O3 ) 0.230(P2O5) 0.770 revealed by gadolinium K -edge anomalous x-ray scattering

NASA Astrophysics Data System (ADS)

Cole, Jacqueline M.; Cramer, Alisha J.; Shastri, Sarvjit D.; Mukaddem, Karim T.; Newport, Robert J.

2018-04-01

A Gd K -edge anomalous x-ray scattering (AXS) study is performed on the rare-earth (R ) phosphate glass, (Gd2O3 ) 0.230(P2O5) 0.770 , in order to determine Gd ⋯Gd separations in its local structure. The minimum rare-earth separation is of particular interest given that the optical properties of these glasses can quench when rare-earth ions become too close to each other. To this end, a weak Gd ⋯Gd pairwise correlation is located at 4.2 (1 )Å , which is representative of a metaphosphate R ⋯R separation. More intense first-neighbor Gd ⋯Gd pairwise correlations are found at the larger radial distributions, 4.8(1), 5.1(1), and 5.4 (1 )Å . These reflect a mixed ultraphosphate and metaphosphate structural character, respectively. A second-neighbor Gd ⋯Gd pairwise correlation lies at 6.6 (1 )Å which is indicative of metaphosphate structures. Meta- and ultraphosphate classifications are made by comparing the R ⋯R separations against those of rare-earth phosphate crystal structures, R (PO3) 3 and R P5O14 , respectively, or difference pair-distribution function (Δ PDF ) features determined on similar glasses using difference neutron-scattering methods. The local structure of this glass is therefore found to display multiple rare-earth ion environments, presumably because its composition lies between these two stoichiometric formulae. These Gd ⋯Gd separations are well-resolved in Δ PDFs that represent the AXS signal. Indeed, the spatial resolution is so good that it also enables the identification of R ⋯X (X =R , P, O) pairwise correlations up to r ˜9 Å ; their average separations lie at r ˜7.1 (1 ) , 7.6(1), 7.9(1), 8.4(1), and 8.7 (1 )Å . This is a report of a Gd K -edge AXS study on an amorphous material. Its demonstrated ability to characterize the local structure of a glass up to such a long range of r heralds exciting prospects for AXS studies on other ternary noncrystalline materials. However, the technical

Effect of silver ions and clusters on the luminescence properties of Eu-doped borate glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiao, Qing, E-mail: jiaoqing@nbu.edu.cn; Wang, Xi; Qiu, Jianbei

2015-12-15

Highlights: • Ag{sup +} and Ag clusters are investigated in the borate glasses via ion exchange method. • The aggregation of silver ions to the clusters was controlled by the ion exchange concentration. • Eu{sup 3+}/Eu{sup 2+} ions emission was enhanced with the sensitization of the silver species. • Energy transfer process from Ag ions and Ag clusters to Eu ions is identified by the lifetime measurements. - Abstract: Silver ions and clusters were applied to Eu{sup 3+}-doped borate glasses via the Ag{sup +}–Na{sup +} ion exchange method. Eu{sup 3+}/Eu{sup 2+} ion luminescence enhancement was achieved after silver ion exchange.more » Absorption spectra showed no band at 420 nm, which indicates that silver nanoparticles can be excluded as a silver state in the glass. Silver ion aggregation into clusters during the ion exchange process may be inferred. The effect of silver ions and clusters on rare earth emissions was investigated using spectral information and lifetime measurements. Significant luminescence enhancements were observed from the energy transfer of Ag{sup +} ions and clusters to Eu{sup 3+}/Eu{sup 2+} ions, companied with the silver ions aggregated into the clusters state. The results of this research may extend the current understanding of interactions between rare-earth ions and Ag species.« less

A Signature of Spatial Correlations between rare earth ions and single-wall nanotubes wrapped with DNA in their mixed solution

NASA Astrophysics Data System (ADS)

Ignatova, Tetyana; Rotkin, Slava V.

2012-02-01

We propose that the fluorescence resonance energy transfer (FRET) between the rare earth ions (REI) and single-wall nanotubes (SWNT) can be used to measure their Coulomb correlation in solution. As a calibration experiment the FRET between two different REIs, being the energy donor and the acceptor, in their mixed solution has been used. From the photoluminescence decay time we were able to extract the characteristic distance between unlike REIs. Our study revealed negative correlation (the repulsion) for Tb-Eu solution. In the case of the solution containing the REI and the SWNTs wrapped with DNA we observed a significant positive correlation (the attraction and the complex formation). The data is in a good agreement with the theoretical estimates and allows to propose REIs and their FRET as a sensitive tool for detecting kinetics of interaction of SWNTs in aqueous solutions.

Energetic-ion acceleration and transport in the upstream region of Jupiter: Voyager 1 and 2

NASA Technical Reports Server (NTRS)

Baker, D. N.; Zwickl, R. D.; Carbary, J. F.; Krimigis, S. M.; Lepping, R. P.

1982-01-01

Long-lived upstream energetic ion events at Jupiter appear to be very similar in nearly all respects to upstream ion events at Earth. A notable difference between the two planetary systems is the enhanced heavy ion compositional signature reported for the Jovian events. This compositional feature has suggested that ions escaping from the Jovian magnetosphere play an important role in forming upstream ion populations at Jupiter. In contrast, models of energetic upstream ions at Earth emphasize in situ acceleration of reflected solar wind ions within the upstream region itself. Using Voyager 1 and 2 energetic ( approximately 30 keV) ion measurements near the magnetopause, in the magnetosheath, and immediately upstream of the bow shock, the compositional patterns are examined together with typical energy spectra in each of these regions. A model involving upstream Fermi acceleration early in events and emphasizing energetic particle escape in the prenoon part of the Jovian magnetosphere late in events is presented to explain many of the features in the upstream region of Jupiter.

Magnetic interactions in new fluorite-related rare earth oxides LnLn’{sub 2}RuO{sub 7} (Ln, Ln’=rare earths)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hinatsu, Yukio, E-mail: hinatsu@sci.hokudai.ac.jp; Doi, Yoshihiro

2016-07-15

New fluorite-related quaternary rare earth oxides Pr{sub 2}YRuO{sub 7} and La{sub 2}TbRuO{sub 7} have been prepared. They crystallize in an orthorhombic superstructure of cubic fluorite with space group Cmcm. Through magnetic susceptibility and specific heat measurements, Pr{sub 2}YRuO{sub 7} shows an antiferromagnetic transition at 27 K, which is considerably lowered compared with that for Pr{sub 3}RuO{sub 7}. Analysis of the magnetic specific heat indicates that the magnetic behavior observed at 27 K for Pr{sub 2}YRuO{sub 7} is predominantly due to the magnetic interactions between Ru ions, and that the interactions between the Pr{sup 3+} and Ru{sup 5+} ions are alsomore » important. La{sub 2}TbRuO{sub 7} shows magnetic ordering at 9.0 K, which is ascribed to the magnetic ordering between Ru{sup 5+} ions from the analysis of the magnetic specific heat data. - Graphical abstract: New fluorite-related quaternary rare earth oxides Pr{sub 2}YRuO{sub 7} and La{sub 2}TbRuO{sub 7} have been prepared. Through magnetic susceptibility and specific heat measurements, Pr{sub 2}YRuO{sub 7} and La{sub 2}TbRuO{sub 7} show an antiferromagnetic transition at 27 and 9.0 K, respectively. Display Omitted - Highlights: • New fluorite-related quaternary rare earth oxides LnLn’{sub 2}RuO{sub 7} have been prepared. • Pr{sub 2}YRuO{sub 7} shows an antiferromagnetic transition at 27 K. • La{sub 2}TbRuO{sub 7} shows magnetic ordering at 9.0 K. • Their magnetic exchange mechanism has been elucidated by the magnetic entropy change.« less

Hydration Energies and Structures of Alkaline Earth Metal Ions, M2+ (H2O)n, n = 5–7, M = Mg, Ca, Sr, and Ba

PubMed Central

Rodriguez-Cruz, Sandra E.; Jockusch, Rebecca A.

2005-01-01

The evaporation of water from hydrated alkaline earth metal ions, produced by electrospray ionization, was studied in a Fourier transform mass spectrometer. Zero-pressure-limit dissociation rate constants for loss of a single water molecule from the hydrated divalent metal ions, M2+(H2O)n (M = Mg, Ca, and Sr for n = 5–7, and M = Ba for n = 4–7), are measured as a function of temperature using blackbody infrared radiative dissociation. From these values, zero-pressure-limit Arrhenius parameters are obtained. By modeling the dissociation kinetics using a master equation formalism, threshold dissociation energies (Eo) are determined. These reactions should have a negligible reverse activation barrier; therefore, Eo values should be approximately equal to the binding energy or hydration enthalpy at 0 K. For the hepta- and hexahydrated ions at low temperature, binding energies follow the trend expected on the basis of ionic radii: Mg > Ca > Sr > Ba. For the hexahydrated ions at high temperature, binding energies follow the order Ca > Mg > Sr > Ba. The same order is observed for the pentahydrated ions. Collisional dissociation experiments on the tetrahydrated species result in relative dissociation rates that directly correlate with the size of the metals. These results indicate the presence of two isomers for hexahydrated magnesium ions: a low-temperature isomer in which the six water molecules are located in the first solvation shell, and a high-temperature isomer with the most likely structure corresponding to four water molecules in the inner shell and two water molecules in the second shell. These results also indicate that the pentahydrated magnesium ions have a structure with four water molecules in the first solvation shell and one in the outer shell. The dissociation kinetics for the hexa- and pentahydrated clusters of Ca2+, Sr2+, and Ba2+ are consistent with structures in which all the water molecules are located in the first solvation shell. PMID:16429612

Influence of rare earth doping on thermoelectric properties of SrTiO3 ceramics

NASA Astrophysics Data System (ADS)

Liu, J.; Wang, C. L.; Li, Y.; Su, W. B.; Zhu, Y. H.; Li, J. C.; Mei, L. M.

2013-12-01

Thermoelectric properties of SrTiO3 ceramics, doped with different rare earth elements, were investigated in this work. It's found that the ionic radius of doping elements plays an important role on thermoelectric properties: SrTiO3 ceramics doped with large rare earth ions (such as La, Nd, and Sm) exhibit large power factors, and those doped with small ions (such as Gd, Dy, Er, and Y) exhibit low thermal conductivities. Therefore, a simple approach for enhancing the thermoelectric performance of SrTiO3 ceramics is proposed: mainly doped with large ions to obtain a large power factor and, simultaneously, slightly co-doped with small ions to obtain a low thermal conductivity. Based on this rule, Sr0.8La0.18Yb0.02TiO3 ceramics were prepared, whose ZT value at 1 023 K reaches 0.31, increasing by a factor of 19% compared with the single-doped counterpart Sr0.8La0.2TiO3 (ZT = 0.26).

Heavy ions in Jupiter's environment

NASA Technical Reports Server (NTRS)

Brown, R. A.

1980-01-01

The extended atmosphere of the Jupiter system consists of atoms and ions of heavy elements. This material originates on the satellite Io. Energy is lost from the thermal plasma in collisionally excited optical and ultraviolet emission. The juxtaposition of Earth and spacecraft measurements provide insight concerning the underlying processes of particle transport and energy supply.

Material exposure effects in a simulated low-Earth orbit environment

NASA Astrophysics Data System (ADS)

Maldonado, C.; McHarg, G.; Asmolova, O.; Andersen, G.; Rodrigues, S.; Ketsdever, A.

2016-11-01

Spacecraft operating in low-Earth orbit (LEO) are subjected to a number of hazardous environmental constituents that can lead to decreased system performance and reduced operational lifetimes. Due to their thermal, optical, and mechanical properties, polymers are used extensively in space systems; however they are particularly susceptible to material erosion and degradation as a result of exposure to the LEO environment. The focus of this research is to examine the material erosion and mass loss experienced by the Novastrat 500 polyimide due to exposure in a simulated LEO environment. In addition to the polymer samples, chrome, silver and gold specimens will be examined to measure the oxidation rate and act as a control specimen, respectively. A magnetically filtered atomic oxygen plasma source has previously been developed and characterized for the purpose of simulating the low-Earth orbit environment. The plasma source can be operated at a variety of discharge currents and gas flow rates, of which the plasma parameters downstream of the source are dependent. The characteristics of the generated plasma were examined as a function of these operating parameters to optimize the production of O+ ions with energy relevant to LEO applications, where the ram energy of the ions due to the motion of the satellite relative to the LEO plasma is high (e.g. 7800 m/s, which corresponds to approximately 5 eV of kinetic energy for O+ ions). The plasma downstream of the source consists of streaming ions with energy of approximately 5 eV and an ion species fraction that is approximately 90% O+.

Analysis of data from the plasma composition experiment on the International Sun-Earth Explorer (ISEE 1)

NASA Technical Reports Server (NTRS)

Lennartsson, O. W.

1994-01-01

The Lockheed plasma composition experiment on the ISEE 1 spacecraft has provided one of the largest and most varied sets of data on earth's energetic plasma environment, covering both the solar wind, well beyond the bow shock, and the near equatorial magnetosphere to a distance of almost 23 earth radii. This report is an overview of the last four years of data analysis and archiving. The archiving for NSSDC includes most data obtained during the initial 28-months of instrument operation, from early November 1977 through the end of February 1980. The data products are a combination of spectra (mass and energy angle) and velocity moments. A copy of the data user's guide and examples of the data products are attached as appendix A. The data analysis covers three major areas: solar wind ions upstream and downstream of the day side bowshock, especially He(++) ions; terrestrial ions flowing upward from the auroral regions, especially H(+), O(+), and He(+) ions; and ions of both solar and terrestrial origins in the tail plasma sheet and lobe regions. Copies of publications are attached.

Ion composition and energy distribution during 10 magnetic storms

NASA Technical Reports Server (NTRS)

Lennartsson, W.; Sharp, R. D.; Shelley, E. G.; Johnson, R. G.; Balsiger, H.

1981-01-01

Data from the plasma composition experiment of ISEE 1 are used to investigate the relative quantities and energy characteristics of H(+), He(++), He(+), and O(+) ions in the near-equatorial magnetosphere during magnetic storm conditions. The ions in the study had energies between 0.1 and 17 keV/e and pitch angles between 45 and 135 deg. The data were obtained during 10 storms, for the most part at or immediately following the peak Dst, covering all major local time sectors and geocentric distances between 2 and 15 earth radii. The ion fluxes are averaged over the spacecraft spin angle and over time for periods ranging from about 20 min close to the earth to more than an hour in most distant regions. The inferred 'isotropic' number densities are characterized by a large to dominant fraction of terrestrial ions throughout the energy range covered. The data are found to be consistent with a terrestrial origin for all of the O(+), most of the He(+), and a large but varying fraction of the H(+), whereas the He(++) and part of the H(+) appear to be of solar wind origin.

Structural diversity of alkaline-earth 2,5-thiophenedicarboxylates

NASA Astrophysics Data System (ADS)

Balendra; Ramanan, Arunachalam

2017-03-01

Exploration of the structural landscape of the system containing divalent alkaline-earth metal ion (Mg, Ca and Sr) with the rigid 2,5-thiophenedicarboxylic acid (TDC) under varying solvothermal condition (DMF, DMA and DEF) yielded five new crystals: [Mg(TDC) (DEF)2(H2O)1/2] (1), [Ca(TDC) (DMA)] (2), [Ca(TDC) (DMA) (H2O)] (3), [Sr(TDC) (DMA)] (4) and [Sr(TDC) (DMA) (H2O)] (5) and two known solids. Single crystal structures of all the solids are characteristic of extended coordination interaction between metal and carboxylate ions. While the smaller magnesium ion crystallized into a 2D coordination polymer, the larger calcium and strontium compounds resulted into the growth of 3D metal organic frameworks. All the solids show blue emission arising from intra ligand charge transfer.

Magnetic properties of rare-earth-doped La0.7Sr0.3MnO3.

PubMed

Veverka, Pavel; Kaman, Ondřej; Knížek, Karel; Novák, Pavel; Maryško, Miroslav; Jirák, Zdeněk

2017-01-25

Rare-earth-doped ferromagnetic manganites La 0.63 RE 0.07 Sr 0.30 MnO 3 (RE  =  Gd, Tb, Dy, and Ho) are synthesized in the form of sintered ceramics and nanocrystalline phases with the mean size of crystallites  ≈30 nm. The electronic states of the dopants are investigated by SQUID magnetometry and theoretically interpreted based on the calculations of the crystal field splitting of rare-earth energy levels. The samples show the orthorhombic perovskite structure of Ibmm symmetry, with a complete FM order of Mn spins in bulk and reduced order in nanoparticles. Non-zero moments are also detected at the perovskite A sites, which can be attributed to magnetic polarization of the rare-earth dopants. The measurements in external field up to 70 kOe show a standard Curie-type contribution of the spin-only moments of Gd 3+ ions, whereas Kramers ions Dy 3+ and non-Kramers ions Ho 3+ contribute by Ising moments due to their doublet ground states. The behaviour of non-Kramers ions Tb 3+ is anomalous, pointing to singlet ground state with giant Van Vleck paramagnetism. The Tb 3+ doping leads also to a notably increased coercivity compared to other La 0.63 RE 0.07 Sr 0.30 MnO 3 systems.

Comment on "A hydrogen-rich early Earth atmosphere".

PubMed

Catling, David C

2006-01-06

Tian et al. (Reports, 13 May 2005, p. 1014) proposed a hydrogen-rich early atmosphere with slow hydrogen escape from a cold thermosphere. However, their model neglects the ultraviolet absorption of all gases other than H2. The model also neglects Earth's magnetic field, which affects the temperature and density of ions and promotes nonthermal escape of neutral hydrogen.

Early Life on Earth and the Search for Extraterrestrial Biosignatures

NASA Technical Reports Server (NTRS)

Oehler, Dorothy Z.; House, Christopher

2014-01-01

In the last 2 years, scientists within the ARES Directorate at JSC have applied the technology of Secondary Ion Mass Spectrometry (SIMS) to individual organic structures preserved in Archean (approximately 3 billion years old) sediments on Earth. These organic structures are among the oldest on Earth that may be microfossils - structurally preserved remnants of ancient microbes. The SIMS work was done to determine the microfossils' stable carbon isotopic composition (delta C-13 values). This is the first time that such ancient, potential microfossils have been successfully analyzed for their individual delta C-13 values. The results support the interpretation that these structures are remnants of early life on Earth and that they may represent planktonic organisms that were widely distributed in the Earth's earliest oceans. This study has been accepted for publication in the journal Geology.

Specific spacecraft evaluation: Special report. [charged particle transport from a mercury ion thruster to spacecraft surfaces

NASA Technical Reports Server (NTRS)

Sellen, J. M., Jr.

1978-01-01

Charged and neutral particle transport from an 8 cm mercury ion thruster to the surfaces of the P 80-1 spacecraft and to the Teal Ruby sensor and the ECOM-501 sensor of that spacecraft were investigated. Laboratory measurements and analyses were used to examine line-of-sight and nonline-of sight particle transport modes. The recirculation of Hg(+) ions in the magnetic field of the earth was analyzed for spacecraft velocity and Earth magnetic field vector configurations which are expected to occur in near Earth, circular, high inclination orbits. For these magnetic field and orbit conditions and for expected ion release distribution functions, in both angles and energies, the recirculation/re-interception of ions on spacecraft surfaces was evaluated. The refraction of weakly energetic ions in the electric fields of the thruster plasma plume and in the electric fields between this plasma plume and the material boundaries of the thruster, the thruster sputter shield, and the various spacecraft surfaces were examined. The neutral particle transport modes of interest were identified as sputtered metal atoms from the thruster beam shield. Results, conclusions, and future considerations are presented.

A Lunar-Based Spacecraft Propulsion Concept - The Ion Beam Sail

NASA Technical Reports Server (NTRS)

Brown, Ian G.; Lane, John E.; Youngquist, Robert C.

2006-01-01

We describe a concept for spacecraft propulsion by means of an energetic ion beam, with the ion source fixed at the spacecraft starting point (e.g., a lunar-based ion beam generator) and not onboard the vessel. This approach avoids the substantial mass penalty associated with the onboard ion source and power supply hardware, and vastly more energetic ion beam systems can be entertained. We estimate the ion beam parameters required for various scenarios, and consider some of the constraints limiting the concept. We find that the "ion beam sail' approach can be viable and attractive for journey distances not too great, for example within the Earth-Moon system, and could potentially provide support for journeys to the inner planets.

AFE ion mass spectrometer design study

NASA Technical Reports Server (NTRS)

Wright, Willie

1989-01-01

This final technical report covers the activities engaged in by the University of Texas at Dallas, Center for Space Sciences in conjunction with the NASA Langley Research Center, Systems Engineering Division in design studies directed towards defining a suitable ion mass spectrometer to determine the plasma parameter around the Aeroassisted Flight Experiment vehicle during passage through the earth's upper atmosphere. Additional studies relate to the use of a Langmuir probe to measure windward ion/electron concentrations and temperatures. Selected instrument inlet subsystems were tested in the NASA Ames Arc-Jet Facility.

The earth's foreshock, bow shock, and magnetosheath

NASA Technical Reports Server (NTRS)

Onsager, T. G.; Thomsen, M. F.

1991-01-01

Studies directly pertaining to the earth's foreshock, bow shock, and magnetosheath are reviewed, and some comparisons are made with data on other planets. Topics considered in detail include the electron foreshock, the ion foreshock, the quasi-parallel shock, the quasi-perpendicular shock, and the magnetosheath. Information discussed spans a broad range of disciplines, from large-scale macroscopic plasma phenomena to small-scale microphysical interactions.

Self-assemblies of luminescent rare earth compounds in capsules and multilayers.

PubMed

Zhang, Renjie; Shang, Juanjuan; Xin, Jing; Xie, Beibei; Li, Ya; Möhwald, Helmuth

2014-05-01

This review addresses luminescent rare earth compounds assembled in microcapsules as well as in planar films fabricated by the layer-by-layer (LbL) technique, the Langmuir-Blodgett (LB) method and in self-assembled monolayers. Chemical precipitation, electrostatic, van der Waals interactions and covalent bonds are involved in the assembly of these compounds. Self-organized ring patterns of rare earth complexes in Langmuir monolayers and on planar surfaces with stripe patterns, as well as fluorescence enhancement due to donor-acceptor pairs, microcavities, enrichment of rare earth compounds, and shell protection against water are described. Recent information on the tuning of luminescence intensity and multicolors by the excitation wavelength and the ratio of rare earth ions, respectively, are also reviewed. Potential applications of luminescent rare earth complex assemblies serving as biological probes, temperature and gas sensors are pointed out. Copyright © 2014 Elsevier B.V. All rights reserved.

Multiple rare-earth ion environments in amorphous ( G d 2 O 3 ) 0.230 ( P 2 O 5 ) 0.770 revealed by gadolinium K -edge anomalous x-ray scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cole, Jacqueline M.; Cramer, Alisha J.; Shastri, Sarvjit D.

A Gd K-edge anomalous X-ray scattering (AXS) study is performed on the rare-earth (R) phosphate glass, (Gd2O3)0.230(P2O5)0.770, in order to determine Gd…Gd separations in its local structure. The minimum rare-earth separation is of particular interest given that the optical properties of these glasses can quench when rare-earth ions become too close to each other. To this end, a weak Gd…Gd pairwise correlation is located at 4.2(1) Å which is representative of a meta-phosphate R…R separation. More intense first neighbor Gd…Gd pairwise correlations are found at the larger radial distributions, 4.8(1) Å, 5.1(1) Å and 5.4(1) Å. These reflect a mixedmore » ultra-phosphate and meta-phosphate structural character, respectively. A second neighbor Gd…Gd pairwise correlation lies at 6.6(1) Å which is indicative of meta-phosphate structures. Meta- and ultra-phosphate classifications are made by comparing the R…R separations against those of rare-earth phosphate crystal structures, R(PO3)3 and RP5O14 respectively, or difference pair distribution function (ΔPDF) features determined on similar glasses using difference neutron scattering methods. The local structure of this glass is therefore found to display multiple rare-earth ion environments, presumably because its composition lies between these two stoichiometric formulae. These Gd…Gd separations are well resolved in the ΔPDFs that represent the AXS signal. Indeed, the spatial resolution is so good that it also enables the identification of R…X (X = R, P, O) pairwise correlations up to r ~ 9 Å; their average separations lie at r ~ 7.1(1) Å, 7.6(1) Å 7.9(1) Å, 8.4(1) Å and 8.7(1) Å. This is the first report of a Gd K-edge AXS study on an amorphous material. Its demonstrated ability to characterize the local structure of a glass up to such a long-range of r, heralds exciting prospects for AXS studies on other ternary non-crystalline materials. However, the technical challenge of such an

Ion-Scale Wave Properties and Enhanced Ion Heating across the Magnetopause during Kelvin-Helmholtz Instability

NASA Astrophysics Data System (ADS)

Nykyri, K.; Moore, T.; Dimmock, A. P.

2017-12-01

In the Earth's magnetosphere, the magnetotail plasma sheet ions are much hotter than in the shocked solar wind. On the dawn-sector, the cold-component ions are more abundant and hotter by 30-40 percent when compared to the dusk sector. Recent statistical studies of the flank magnetopause and magnetosheath have shown that the level of temperature asymmetry of the magnetosheath is unable to account for this, so additional physical mechanisms must be at play, either at the magnetopause or plasma sheet that contribute to this asymmetry. In this study, we perform a statistical analysis on the ion-scale wave properties in the three main plasma regimes common to flank magnetopause boundary crossings when the boundary is unstable to KHI: hot and tenuous magnetospheric, cold and dense magnetosheath and mixed [Hasegawa 2004 et al., 2004]. These statistics of ion-scale wave properties are compared to observations of fast magnetosonic wave modes that have recently been linked to Kelvin-Helmholtz vortex centered ion heating [Moore et al., 2016]. The statistical analysis shows that during KH events there is enhanced non-adiabatic heating calculated during (temporal) ion scale wave intervals when compared to non-KH events.

Energetic Ionic Liquids Based on Anionic Rare Earth Nitrate Complexes (Preprint)

DTIC Science & Technology

2008-07-10

a glass transition temperature (Tg) at -46 oC. However, it is only stable in dry air, and thus must be protected from water. At 75 oC, clear weight...involved highly toxic and corrosive chemicals, N2O4 and NOCl. Ligands which coordinate via oxygen atoms to a rare earth metal ion give rise to stable...complexes. Thus higher air and thermal stabilities may be obtained by introducing rare earth metal nitrates as main components of ionic liquids. We

Mechanisms for the Dissipation of Alfven Waves in Near-Earth Space Plasma

NASA Technical Reports Server (NTRS)

Singh, Nagendra; Khazanov, George; Krivorutsky, E. N.; Davis, John M. (Technical Monitor)

2002-01-01

Alfven waves are a major mechanism for the transport of electromagnetic energy from the distant part of the magnetosphere to the near-Earth space. This is especially true for the auroral and polar regions of the Earth. However, the mechanisms for their dissipation have remained illusive. One of the mechanisms is the formation of double layers when the current associated with Alfven waves in the inertial regime interact with density cavities, which either are generated nonlinearly by the waves themselves or are a part of the ambient plasma turbulence. Depending on the strength of the cavities, weak and strong double layers could form. Such double layers are transient; their lifetimes depend on that of the cavities. Thus they impulsively accelerate ions and electrons. Another mechanism is the resonant absorption of broadband Alfven- wave noise by the ions at the ion cyclotron frequencies. But this resonant absorption may not be possible for the very low frequency waves, and it may be more suited for electromagnetic ion cyclotron waves. A third mechanism is the excitation of secondary waves by the drifts of electrons and ions in the Alfven wave fields. It is found that under suitable conditions, the relative drifts between different ion species and/or between electrons and ions are large enough to drive lower hybrid waves, which could cause transverse accelerations of ions and parallel accelerations of electrons. This mechanism is being further studied by means of kinetic simulations using 2.5- and 3-D particle-in-cell codes. The ongoing modeling efforts on space weather require quantitative estimates of energy inputs of various kinds, including the electromagnetic energy. Our studies described here contribute to the methods of determining the estimates of the input from ubiquitous Alfven waves.

Locating dayside magnetopause reconnection with exhaust ion distributions

NASA Astrophysics Data System (ADS)

Broll, J. M.; Fuselier, S. A.; Trattner, K. J.

2017-05-01

Magnetic reconnection at Earth's dayside magnetopause is essential to magnetospheric dynamics. Determining where reconnection takes place is important to understanding the processes involved, and many questions about reconnection location remain unanswered. We present a method for locating the magnetic reconnection X line at Earth's dayside magnetopause under southward interplanetary magnetic field conditions using only ion velocity distribution measurements. Particle-in-cell simulations based on Cluster magnetopause crossings produce ion velocity distributions that we propagate through a model magnetosphere, allowing us to calculate the field-aligned distance between an exhaust observation and its associated reconnection line. We demonstrate this procedure for two events and compare our results with those of the Maximum Magnetic Shear Model; we find good agreement with its results and show that when our method is applicable, it produces more precise locations than the Maximum Shear Model.

International Space Station Lithium-Ion Battery

NASA Technical Reports Server (NTRS)

Dalton, Penni J.; Schwanbeck, Eugene; North, Tim; Balcer, Sonia

2016-01-01

The International Space Station (ISS) primary Electric Power System (EPS) currently uses Nickel-Hydrogen (Ni-H2) batteries to store electrical energy. The electricity for the space station is generated by its solar arrays, which charge batteries during insolation for subsequent discharge during eclipse. The Ni-H2 batteries are designed to operate at a 35 depth of discharge (DOD) maximum during normal operation in a Low Earth Orbit. Since the oldest of the 48 Ni-H2 battery Orbital Replacement Units (ORUs) has been cycling since September 2006, these batteries are now approaching their end of useful life. In 2010, the ISS Program began the development of Lithium-Ion (Li-Ion) batteries to replace the Ni-H2 batteries and concurrently funded a Li-Ion ORU and cell life testing project. When deployed, they will be the largest Li-Ion batteries ever utilized for a human-rated spacecraft. This paper will include an overview of the ISS Li-Ion battery system architecture, the Li-Ion battery design and development, controls to limit potential hazards from the batteries, and the status of the Li-Ion cell and ORU life cycle testing.

Theoretical study of metal noble-gas positive ions

NASA Technical Reports Server (NTRS)

Bauschlicher, Charles W., Jr.; Partridge, Harry; Langhoff, Stephen R.

1989-01-01

Theoretical calculations have been performed to determine the spectroscopic constant for the ground and selected low-lying electronic states of the transition-metal noble-gas ions Var(+), FeAr(+), CoAr(+), CuHe(+), CuAr(+), and CuKr(+). Analogous calculations have been performed for the ground states of the alkali noble-gas ions LiAr(+), LiKr(+), NaAr(+), and KAr(+) and the alkaline-earth noble-gas ion MgAr(+) to contrast the difference in binding energies between the simple and transition-metal noble-gas ions. The binding energies increase with increasing polarizability of the noble-gas ions, as expected for a charge-induced dipole bonding mechanism. It is found that the spectroscopic constants of the X 1Sigma(+) states of the alkali noble-gas ions are well described at the self-consistent field level. In contrast, the binding energies of the transition-metal noble-gas ions are substantially increased by electron correlation.

Cyanobacterial megamolecule sacran efficiently forms LC gels with very heavy metal ions.

PubMed

Okajima, Maiko K; Miyazato, Shinji; Kaneko, Tatsuo

2009-08-04

We extracted the megamolecular polysaccharide sacran, which contains carboxylate and sulfate groups, from the jellylike extracellular matrix (ECM) of the cyanobacterium Aphanothece sacrum, which has mineral adsorption bioactivity. We investigated the gelation properties of sacran binding with various heavy metal ions. The sacran chain adsorbed heavier metal ions such as indium, rare earth metals, and lead ions more efficiently to form gel beads. In addition, trivalent metal ions adsorbed onto the sacran chains more efficiently than did divalent ions. The investigation of the metal ion binding ratio on sacran chains demonstrated that sacran adsorbed gadolinium trivalent ions more efficiently than indium trivalent ions. Gel bead formation may be closely correlated to the liquid-crystalline organization of sacran.

Rare-earth doped polymer waveguides and light emitting diodes

NASA Astrophysics Data System (ADS)

Slooff, L. H.

2000-11-01

Polymer-based optical waveguide amplifiers offer a low-cost alternative for inorganic waveguide amplifiers. Due to the fact that their refractive index is almost similar to that of standard optical fibers, they can be easily coupled with existing fibers at low coupling losses. Doping the polymer with rare-earth ions that can yield optical gain is not straightforward, as the rare-earth salts are poorly soluble in the polymer matrix. This thesis studies two different approaches to dope a polymer waveguide with rare-earth ions. The first one is based on organic cage-like complexes that encapsulate the rare-earth ion and are designed to provide enough coordination sites to bind the rare-earth ion and to shield it from the surrounding matrix. Chapter 2 describes the optical properties of Er-doped organic polydentate cage complexes. The complexes show clear photoluminescence at 1.54 mm with a bandwidth of 70 nm, the highest reported for an erbium-doped material so far. The luminescence lifetime is very short (~1 ms) due to coupling to vibrational overtones of O-H and C-H bonds. Due to this short luminescence lifetime, high pump powers (~1 W) are needed for optical gain in a waveguide amplifier based on these complexes. The pump power can be reduced if the Er is excited via the aromatic part of the complex, which has a higher absorption cross section. In Chapter 3 a lissamine-functionalised neodymium complex is studied in which the highly absorbing lissamine acts as a sensitiser. The lissamine is first excited into the singlet state from which intersystem crossing to the triplet state can take place. From there it can transfer its energy to the Nd ion by a Dexter transfer mechanism. Room-temperature photoluminescence at 890, 1060, and 1340 nm from Nd is observed, together with luminescence from the lissamine sensitiser at 600 nm. Photodegradation of the lissamine sensitiser is observed, which is studied in more detail in Chapter 4. The observed change in time of the

Solar wind deceleration and MHD turbulence in the earth's foreshock region - ISEE 1 and 2 and IMP 8 observations

NASA Technical Reports Server (NTRS)

Bonifazi, C.; Moreno, G.; Russell, C. T.; Lazarus, A. J.; Sullivan, J. D.

1983-01-01

The interaction of the solar wind with ions backstreaming from the earth's bow shock is investigated using plasma and magnetic field measurements on ISEE 1 and 2 and IMP 8 at widely separated positions in the earth's foreshock. This technique separates temporal and spatial variations within the foreshock. It is found that the solar wind acceleration associated with backstreaming ions is correlated with the amplitude of the MHD turbulence, and that the largest decelerations are seen close to the bow shock. The density of the backstreaming ion beam is strongly correlated with distance from the shock, and decreases by about a factor of three in a distance of about 3R(e).

Correlation of an infrared absorption with carriers in rare-earth monoantimonides

NASA Astrophysics Data System (ADS)

Kwon, Y. S.; Jung, M. H.; Lee, K. R.; Kimura, S.; Suzuki, T.

1997-09-01

Dielectric constants spectra were obtained in the single crystals LaSb, PrSb, GdSb and DySb at several temperatures. The spectra for these crystals except for LaSb show Drude's behavior with a hump due to an anomalous absorption lying at about 0.25 eV. The inverse of effective electron number ( NIA) of the absorption is linear in temperature, and the NIA at each temperature is dependent on the square of the effective Bohr magneton of each rare-earth ion. The sum of the number of effective electrons due to Drude adsorption and that due to infrared absorption agree well with the number of carriers obtained from their band calculations or their dHvAs. Therefore, this absorption seems to be due to the intraband transition induced by the scattering between the spin of carriers and the localized magnetic moments at each site of rare-earth ion.

Magnetic interactions in rhenium-containing rare earth double perovskites Sr{sub 2}LnReO{sub 6} (Ln=rare earths)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishiyama, Atsuhide; Doi, Yoshihiro; Hinatsu, Yukio, E-mail: hinatsu@sci.hokudai.ac.jp

The perovskite-type compounds containing both rare earth and rhenium Sr{sub 2}LnReO{sub 6} (Ln=Y, Tb-Lu) have been prepared. Powder X-ray diffraction measurements and Rietveld analysis show that Ln{sup 3+} and Re{sup 5+} ions are structurally ordered at the B site of the perovskite SrBO{sub 3}. Magnetic anomalies are found in their magnetic susceptibility and specific heat measurements at 2.6–20 K for Ln=Y, Tb, Dy, Yb, Lu compounds. They are due to magnetic interactions between Re{sup 5+} ions. The results of the magnetic hysteresis and remnant magnetization measurements for Sr{sub 2}YReO{sub 6} and Sr{sub 2}LuReO{sub 6} indicate that the antiferromagnetic interactions betweenmore » Re{sup 5+} ions below transition temperatures have a weak ferromagnetic component. The analysis of the magnetic specific heat data for Sr{sub 2}YbReO{sub 6} shows that both the Yb{sup 3+} and Re{sup 5+} ions magnetically order at 20 K. For the case of Sr{sub 2}DyReO{sub 6}, magnetic ordering of the Re{sup 5+} moments occurs at 93 K, and with decreasing temperature, the moments of Dy{sup 3+} ferromagnetically order at 5 K from the measurements of magnetic susceptibility and specific heat. - Graphical abstract: Crystal structure of double perovskite Sr{sub 2}LnReO{sub 6}. Red and black lines show cubic and monoclinic unit cells, respectively. - Highlights: • Double perovskites Sr{sub 2}LnReO{sub 6} (Ln=rare earths) were prepared. • They show an antiferromagnetic transition at 2.6–20 K. • In Sr{sub 2}DyReO{sub 6}, Dy and Re moments magnetically order at 5 and 93 K, respectively.« less

Rare-Earth-compound nanowires, nanotubes, and fullerene-like nanoparticles: synthesis, characterization, and properties.

PubMed

Wang, Xun; Li, Yadong

2003-11-21

Various low-dimensional nanostructures, such as nanowires, nanotubes, nanosheets, and fullerene-like nanoparticles have been selectively synthesized from rare-earth compounds (hydroxides, fluorides) based on a facile hydrothermal method. The subsequent dehydration, sulfidation, and fluoridation processes lead to the formation of rare-earth oxide, oxysulfide, and oxyhalide nanostructures, which can be functionalized further by doping with other rare-earth ions or by coating with metal nanoparticles. Owing to the interesting combination of novel nanostructures and functional compounds, these nanostructures can be expected to bring new opportunities in the vast research areas of and application in biology, catalysts, and optoelectronic devices.

Chromatographic Techniques for Rare Earth Elements Analysis

NASA Astrophysics Data System (ADS)

Chen, Beibei; He, Man; Zhang, Huashan; Jiang, Zucheng; Hu, Bin

2017-04-01

The present capability of rare earth element (REE) analysis has been achieved by the development of two instrumental techniques. The efficiency of spectroscopic methods was extraordinarily improved for the detection and determination of REE traces in various materials. On the other hand, the determination of REEs very often depends on the preconcentration and separation of REEs, and chromatographic techniques are very powerful tools for the separation of REEs. By coupling with sensitive detectors, many ambitious analytical tasks can be fulfilled. Liquid chromatography is the most widely used technique. Different combinations of stationary phases and mobile phases could be used in ion exchange chromatography, ion chromatography, ion-pair reverse-phase chromatography and some other techniques. The application of gas chromatography is limited because only volatile compounds of REEs can be separated. Thin-layer and paper chromatography are techniques that cannot be directly coupled with suitable detectors, which limit their applications. For special demands, separations can be performed by capillary electrophoresis, which has very high separation efficiency.

MMS Observations of Protons and Heavy Ions Acceleration at Plasma Jet Fronts

NASA Astrophysics Data System (ADS)

Catapano, F.; Retino, A.; Zimbardo, G.; Cozzani, G.; Breuillard, H.; Le Contel, O.; Alexandrova, A.; Mirioni, L.; Cohen, I. J.; Turner, D. L.; Perri, S.; Greco, A.; Mauk, B.; Torbert, R. B.; Russell, C. T.; Khotyaintsev, Y. V.; Lindqvist, P. A.; Ergun, R.; Giles, B. L.; Fuselier, S. A.; Moore, T. E.; Burch, J.

2017-12-01

Plasma jet fronts in the Earth's magnetotail are kinetic-scale boundaries separating hot fast plasma jets, generally attributed to reconnection outflows, from colder ambient plasma. Jet fronts are typically associated with a sharp increase of the vertical component of the magnetic field Bz, an increase of the plasma temperature and a drop of plasma density. Spacecraft observations and numerical simulations indicate that jet fronts are sites of major ion acceleration. The exact acceleration mechanisms as well as the dependence of such mechanisms on ion composition are not fully understood, yet. Recent high-resolution measurements of ion distribution functions in the magnetotail allow for the first time to study the acceleration mechanisms in detail. Here, we show several examples of jet fronts and discuss ion acceleration therein. We show fronts that propagate in the mid-tail magnetotail both as isolated laminar boundaries and as multiple boundaries embedded in strong magnetic fluctuations and turbulence. We also show fronts in the near-Earth jet braking region, where they interact with the dipolar magnetic field and are significantly decelerated/diverted. Finally, we study the acceleration of different ion species (H+, He++, O+) at different types of fronts and we discuss possible different acceleration mechanisms and how they depend on the ion species.

Energetic atomic and molecular ions of ionospheric origin observed in distant magnetotail flow-reversal events

NASA Technical Reports Server (NTRS)

Christon, S. P.; Gloeckler, G.; Williams, D. J.; Mukai, T.; Mcentire, R. W.; Jacquey, C.; Angelopoulos, V.; Lui, A. T. Y.; Kokubun, S.; Fairfield, D. H.

1994-01-01

Energetic atomic (O(+1) and N(+1)) and molecular (O2(+1), NO(+1), and N2(+1)) ions of ionospheric origin were observed in Earth's magnetotail at X approximately -146 R(sub E) during two plasma sheet sunward/tailward flow-reversal events measured by instruments on the GEOTAIL spacecraft. These events were associated with concurrent ground-measured geomagnetic disturbance intensification at auroral-and mid-latitudes (Kp = 7(-)). Energetic ions in the sunward-component and tailward flows were from both the solar wind and ionosphere. Plasma and energetic ions participated in the flows. During tailward flow, ionospheric origin ion abundance ratios at approximately 200-900 km/s in the rest frame were N(+1)/O(+1) = approximately 25-30% and ((O2(+1), NO(+1), and N2(+1))/O(+1) = approximately 1-2%. We argue that tailward flow most likely initiated approximately 80-100 R(sub E) tailward of Earth and molecular ions were in the plasma sheet prior to geomagnetic intensification onset.

Synthesis and photoluminescence properties of novel Schiff base type polymer-rare earth complexes containing furfural-based bidentate Schiff base ligands

NASA Astrophysics Data System (ADS)

Gao, Baojiao; Zhang, Dandan; Li, Yanbin

2018-03-01

Luminescent polymer-rare earth complexes are an important class of photoluminescence and electroluminescence materials. Via molecular design, two furfural-based bidentate Schiff base ligands, furfural-aniline (FA) type ligand and furfural-cyclohexylamine (FC) type ligand, were bonded on the side chains of polysulfone (PSF), respectively, forming two functionalized macromolecules, PSF-FA and PSF-FC. And then through respective coordination reactions of the two functionalized macromolecules with Eu(Ⅲ) ion and Tb(Ⅲ) ion, novel luminescent binary and ternary (with 1,10-phenanthroline as the second ligand) polymer-rare earth complexes were synthesized. For these complexes, on basis of the characterization of their chemical structures, they photoluminescence properties were main researched, and the relationship between their luminescent properties and structures was explored. The experimental results show that the complexes coming from PSF-FA and Eu(Ⅲ) ion including binary and ternary complexes emit strong red luminescence, indicating that the bonded bidentate Schiff base ligand FA can sensitize the fluorescence emission of Eu(III) ion. While the complexes coming from PSF-FC and Tb(Ⅲ) ion produce green luminescence, displaying that the bonded bidentate Schiff base ligand FC can sensitize the fluorescence emission of Tb(Ⅲ) ion. The fluorescence emission intensities of the ternary complexes were stronger than that of binary complexes, reflecting the important effect of the second ligand. The fluorescence emission of the solid film of complexes is much stronger than that of the solutions of complexes. Besides, by comparison, it is found that the furfural (as a heteroaromatic compound)-based Schiff base type polymer-rare earth complexes have stronger fluorescence emission and higher energy transfer efficiency than salicylaldehyde (as a common aromatic compound)-based Schiff base type polymer-rare earth complexes.

The role of nitrogen ions in the ring current dynamics

NASA Astrophysics Data System (ADS)

Ilie, R.; Liemohn, M. W.; Dandouras, I. S.

2017-12-01

Changes in the ion composition throughout the Earth's magnetosphere can have profound implications on plasma structures and dynamics, since it can modify the temperature and the magnetic field configuration, altering the convection patterns inside the magnetosphere. The ratio of hydrogen to oxygen ions has been shown to be highly dependent of geomagnetic activity, with the O+ content increasing with increasing activity. This suggests that ions of ionospheric origin can become the dominant species in the inner magnetosphere during disturbed times. Therefore, numerous studies have focused on the transport and energization of O+ through the ionosphere-magnetosphere system; however, relatively few have considered the contribution of N+, in addition to that of O+ to the near-Earth plasma dynamics, even though past observations have established that N+ is a significant ion species in the ionosphere and its presence in the magnetosphere is significant. Ring current observations from the Active Magnetospheric Particle Tracer Explorer (AMPTE) spacecraft show that high energy N+ fluxes are comparable to those of O+ during disturbed times, confirming the substantial presence of N+ions in the inner magnetosphere. In spite of only 12% mass difference, N+ and O+ have different ionization potentials, scale heights and charge exchange cross sections. The latter, together with the geocoronal density distribution, plays a key role in the formation of Energetic Neutral Atoms (ENAs), which in turn control the energy budget of the inner magnetosphere and the decay of the ring current. Numerical simulations using the Hot Electron and Ion Drift Integrator (HEIDI) model suggest that the contribution of N+ to the ring current dynamics is significant, as the presence of N+, in addition to that of O+, alters the development and the decay rate of the ring current. These findings suggest that differentiating the N+ transport from that of O+ in the near-Earth environment has a profound impact

Wave and ion evolution downstream of quasi-perpendicular bow shocks

NASA Technical Reports Server (NTRS)

Mckean, M. E.; Omidi, N.; Krauss-Varban, D.

1995-01-01

Distribution functions of ions heated in quasi-perpendicular bow shocks have a large perpendicular temperature anisotropy that provides free energy for the growth of Alfven ion cyclotron (AIC) waves and mirror waves. Both types of waves have been observed in the Earth's magnetosheath downstream of quasi-perpendicular shocks. We use a two-dimensional hybrid simulations to give a self-consistent description of the evolution of the wave spectra downstream of quasi-perpendicular shocks. Both mirror and AIC waves are identified in the simulated magnetosheath. They are generated at or near the shock front and convected away from it by the sheath plasma. Near the shock, the waves have a broad spectrum, but downstream of the shock, shorter-wavelength modes are heavily damped and only longer-wavelength modes persist. The characteristics of these surviving modes can be predicted with reasonable accuracy by linear kinetic theory appropriate for downstream conditions. We also follow the evolution of the ion distribution function. The shocked ions that provide the free energy for wave growth have a two-component distribution function. The halo is initially gyrophase-bunched and extremely anisotropic. Within a relatively short distance downstream of the shock (of the order of 10 ion inertial lengths), wave-particle interactions remove these features from the halo and reduce the anisotropy of the distribution to near-threshold levels for the mirror and AIC instabilities. A similar evolution has been observed for ions at the Earth's bow shock.

Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

DOE PAGES

Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; ...

2016-01-01

When appropriately activated, alkali rare-earth double phosphates of the form: M 3RE(PO 4) 2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K 3RE(PO 4) 2 with RE = Lu, Er, Ho,more » Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A 3Lu(PO 4) 2, with A = Rb, and Cs. The double phosphate K 3Lu(PO 4) 2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K 3Lu(PO 4) 2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K 3Lu(PO 4) 2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K 3Yb(PO 4) 2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated

Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.

When appropriately activated, alkali rare-earth double phosphates of the form: M 3RE(PO 4) 2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K 3RE(PO 4) 2 with RE = Lu, Er, Ho,more » Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A 3Lu(PO 4) 2, with A = Rb, and Cs. The double phosphate K 3Lu(PO 4) 2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K 3Lu(PO 4) 2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K 3Lu(PO 4) 2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K 3Yb(PO 4) 2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated

The role of Nb in intensity increase of Er ion upconversion luminescence in zirconia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smits, K., E-mail: smits@cfi.lu.lv; Sarakovskis, A.; Grigorjeva, L.

2014-06-07

It is found that Nb co-doping increases the luminescence and upconversion luminescence intensity in rare earth doped zirconia. Er and Yb-doped nanocrystalline samples with or without Nb co-doping were prepared by sol-gel method and thermally annealed to check for the impact of phase transition on luminescence properties. Phase composition and grain sizes were examined by X-ray diffraction; the morphology was checked by scanning- and high-resolution transmission electron microscopes. Both steady-state and time-resolved luminescence were studied. Comparison of samples with different oxygen vacancy concentrations and different Nb concentrations confirmed the known assumption that oxygen vacancies are the main agents for tetragonalmore » or cubic phase stabilization. The oxygen vacancies quench the upconversion luminescence; however, they also prevent agglomeration of rare-earth ions and/or displacement of rare-earth ions to grain surfaces. It is found that co-doping with Nb ions significantly (>20 times) increases upconversion luminescence intensity. Hence, ZrO{sub 2}:Er:Yb:Nb nanocrystals may show promise for upconversion applications.« less

Research of green emitting rare-earth doped materials as potential quantum-cutter

NASA Astrophysics Data System (ADS)

Moine, Bernard; Beauzamy, Lena; Gredin, Patrick; Wallez, Gilles; Labeguerie, Jessica

2008-03-01

Because the energy of vacuum ultraviolet (VUV) photons emitted by xenon plasma discharge is more than twice that of visible photons, quantum cutting appears to be a promising process in rare-earth doped materials in order to obtain efficient phosphors for mercury free lighting devices as well as for plasma display panels. With an aim of application, it is important to take into account the emitting color of the developed new phosphors. Most of the time, this leads to use systems with at least two kinds of rare earth ions: one of them playing the role of energy sensitizer, and the other one being in charge of emitting the light of the suitable color. We focus our attention on green rare-earth doped materials. In order to get very efficient phosphors, it is not only necessary to get the highest possible quantum yield, but also to have a material characterized by a strong absorption in the VUV range. Borate and fluoride matrices doped with Dy 3+/Tb 3+ couples of ions are selected according to the position of the 5d band of dysprosium as green emitters.

A Study of Fermi Acceleration of Suprathermal Solar Wind Ions

NASA Astrophysics Data System (ADS)

Freeman, Theodore James

The Wind spacecraft has observed numerous sunward bursts of ~2 MeV ions upstream of the Earth's bow shock. The bursts typically last several minutes at the highest energies, but they can last for tens of minutes at intermediate energies (tens to hundreds of keV). The MeV ions are not protons or alpha particles, and are probably oxygen ions. There are two possible sources of these particles: Fermi acceleration of solar wind ions, and ring current particles which have escaped from the Earth's magnetosphere. In this dissertation, Wind observations and numerical particle simulations of Fermi acceleration are presented which demonstrate that suprathermal solar wind O6+ ions are the most likely source of these bursts. Since the Fermi mechanism accelerates all ions to approximately the same ratio of energy to charge, H+ and He2+ ions are accelerated to much lower energies than O6+ ions. In this model, suprathermal ions are reflected between the bow shock and rotations in the interplanetary magnetic field (IMF) upstream of the shock, gaining energy due to the relative motion of the reflecting magnetic structures. Each burst either coincides with or is closely followed by a large IMF rotation. By using measured magnetic field data, the timing of the bursts detected by Wind is precisely reproduced in the simulation. The energy spectra observed by Wind are also reproduced by adding H+ , He2+ , and O6+ fluxes together, and assuming that there is an increase of ~2 orders of magnitude in the high energy tail of the solar wind oxygen distribution. An enhancement of this order of magnitude in CNO group ions was measured by the ion composition experiment on Wind in association with these bursts. An examination of the magnetospheric escape model shows that while escaping O+ ions can account for some features of the data, such as the longer bursts of intermediate energy ions, it cannot account for the short duration ~2 MeV bursts themselves, because O+ ions scatter diffusively in the

Hydrogels dispersed by doped rare earth fluoride nanocrystals: ionic liquid dispersion and down/up-conversion luminescence.

PubMed

Yan, Zhi-Yuan; Jia, Li-Ping; Yan, Bing

2014-01-01

Two typical kinds of rare earth fluoride nanocrystals codoped with rare earth ions (Eu(3+) and Tm(3+)/Er(3+),Yb(3+)) are synthesized and dispersed in ionic liquid compound (1-chlorohexane-3-methylimidazolium chloride, abbreviated as [C6mim][Cl]). Assisted by agarose, the luminescent hydrogels are prepared homogeneously. The down/up-conversion luminescence of these hydrogels can be realized for the dispersed rare earth fluoride nanocrystals. The results provide a strategy to prepare luminescent (especially up-conversion luminescent) hydrogels with ionic liquid to disperse rare earth fluoride nanocrystals. Copyright © 2013 Elsevier B.V. All rights reserved.

The Suess-Urey mission (return of solar matter to Earth).

PubMed

Rapp, D; Naderi, F; Neugebauer, M; Sevilla, D; Sweetnam, D; Burnett, D; Wiens, R; Smith, N; Clark, B; McComas, D; Stansbery, E

1996-01-01

The Suess-Urey (S-U) mission has been proposed as a NASA Discovery mission to return samples of matter from the Sun to the Earth for isotopic and chemical analyses in terrestrial laboratories to provide a major improvement in our knowledge of the average chemical and isotopic composition of the solar system. The S-U spacecraft and sample return capsule will be placed in a halo orbit around the L1 Sun-Earth libration point for two years to collect solar wind ions which implant into large passive collectors made of ultra-pure materials. Constant Spacecraft-Sun-Earth geometries enable simple spin stabilized attitude control, simple passive thermal control, and a fixed medium gain antenna. Low data requirements and the safety of a Sun-pointed spinner, result in extremely low mission operations costs.

Electron Bombardment Ion Thruster

NASA Image and Video Library

1970-08-21

Researchers at the Lewis Research Center had been studying different methods of electric rocket propulsion since the mid-1950s. Harold Kaufman created the first successful engine, the electron bombardment ion engine, in the early 1960s. Over the ensuing decades Lewis researchers continued to advance the original ion thruster concept. A Space Electric Rocket Test (SERT) spacecraft was launched in June 1964 to test Kaufman’s engine in space. SERT I had one cesium engine and one mercury engine. The suborbital flight was only 50 minutes in duration but proved that the ion engine could operate in space. This was followed in 1966 by the even more successful SERT II, which operated on and off for over ten years. Lewis continued studying increasingly more powerful ion thrusters. These electric engines created and accelerated small particles of propellant material to high exhaust velocities. Electric engines have a very small amount of thrust and are therefore not capable of lifting a spaceship from the surface of the Earth. Once lofted into orbit, however, electric engines are can produce small, continuous streams of thrust for several years.

Near-Earth Reconnection Ejecta at Lunar Distances

NASA Astrophysics Data System (ADS)

Runov, A.; Angelopoulos, V.; Artemyev, A.; Lu, S.; Zhou, X.-Z.

2018-04-01

Near-Earth magnetotail reconnection leads to formation of earthward and tailward directed plasma outflows with an increased north-south magnetic field strength(|Bz|) at their leading edges. We refer to these regions of enhanced |Bz| and magnetic flux transport Ey as reconnection ejecta. They are composed of what have been previously referred to as earthward dipolarizing flux bundles (DFBs) and tailward rapid flux transport (RFT) events. Using two-point observations of magnetic and electric fields and particle fluxes by the Acceleration, Reconnection, Turbulence, and Electrodynamics of Moon's Interaction with the Sun probes orbiting around Moon at geocentric distances R ˜ 60RE, we statistically studied plasma moments and particle energy spectra in RFTs and compared them with those observed within DFBs in the near-Earth plasma sheet by the Time History of Events and Macroscale Interactions during Substorms probes. We found that the ion average temperatures and spectral slopes in RFTs at R ˜ 60RE are close to those in DFBs observed at 15 < R < 25RE, just earthward of the probable reconnection region location. Assuming plasma sheet pressure balance, the average RFT ion temperature corresponds to a lobe field BL˜20 nT. This leads us to suggest that the ion population within the tailward ejecta originated in the midtail plasma sheet at 20≤R≤30RE and propagated to the Acceleration, Reconnection, Turbulence, and Electrodynamics of Moon's Interaction with the Sun location without undergoing any further energy gain. Conversely, electron temperatures in DFBs at 15 < R < 25RE are a factor of 2.5 higher than those in RFTs at R ˜ 60RE.

Ion probe determinations of the rare earth concentrations of individual meteoritic phosphate grains

NASA Technical Reports Server (NTRS)

Crozaz, G.; Zinner, E.

1985-01-01

A new ion probe method for quantitative measurements of the concentrations of all the REE down to the ppm level in 5-20 micron spots is presented. The first application of the method is the determination of REE abundances in meteoritic phosphates. Results are shown to be in good agreement with previous INAA and ion probe determinations. The merrillites in the St. Severin amphoterite are richer in REE than the apatites (the enrichment factors, for various REE, range from 2.3 to 14.2) in contradiction with the results of Ebihara and Honda (1983). Provided good standards for other mineral phases are found or implanted marker ion techniques are used, the method should find a wide range of applications for the study of both terrestrial and extraterrestrial crystals at the microscopic level.

Ion exchange polymers and method for making

NASA Technical Reports Server (NTRS)

Philipp, Warren H. (Inventor); Street, Kenneth W., Jr. (Inventor)

1994-01-01

An ion exchange polymer comprised of an alkali metal or alkaline earth metal salt of a poly(carboxylic acid) in a poly(vinyl acetal) matrix is described. The polymer is made by treating a mixture made of poly(vinyl alcohol) and poly(acrylic acid) with a suitable aldehyde and an acid catalyst to cause acetalization with some cross-linking. The material is then subjected to an alkaline aqueous solution of an alkali metal salt or an alkali earth metal salt. All of the film forming and cross-linking steps can be carried out simultaneously, if desired.

Simplified power processing for ion-thruster subsystems

NASA Technical Reports Server (NTRS)

Wessel, F. J.; Hancock, D. J.

1983-01-01

Compared to chemical propulsion, ion propulsion offers distinct payload-mass increases for many future low-thrust earth-orbital and deep-space missions. Despite this advantage, the high initial cost and complexity of ion-propulsion subsystems reduce their attractiveness for most present and near-term spacecraft missions. Investigations have, therefore, been conducted with the objective to attempt to simplify the power-processing unit (PPU), which is the single most complex and expensive component in the thruster subsystem. The present investigation is concerned with a program to simplify the design of the PPU employed in a 8-cm mercury-ion-thruster subsystem. In this program a dramatic simplification in the design of the PPU could be achieved, while retaining essential thruster control and subsystem operational flexibility.

Coordination Chemistry of Alkali and Alkaline-Earth Cations with Macrocyclic Ligands.

ERIC Educational Resources Information Center

Dietrich, Bernard

1985-01-01

Discusses: (l) alkali and alkaline-earth cations in biology (considering naturally occurring lonophores, their X-ray structures, and physiochemical studies); (2) synthetic complexing agents for groups IA and IIA; and (3) ion transport across membranes (examining neutral macrobicyclic ligands as metal cation carriers, transport by anionic carriers,…

THOR Ion Mass Spectrometer instrument - IMS

NASA Astrophysics Data System (ADS)

Retinò, Alessandro; Kucharek, Harald; Saito, Yoshifumi; Fraenz, Markus; Verdeil, Christophe; Leblanc, Frederic; Techer, Jean-Denis; Jeandet, Alexis; Macri, John; Gaidos, John; Granoff, Mark; Yokota, Shoichiro; Fontaine, Dominique; Berthomier, Matthieu; Delcourt, Dominique; Kistler, Lynn; Galvin, Antoniette; Kasahara, Satoshi; Kronberg, Elena

2016-04-01

Turbulence Heating ObserveR (THOR) is the first mission ever flown in space dedicated to plasma turbulence. Specifically, THOR will study how turbulent fluctuations at kinetic scales heat and accelerate particles in different turbulent environments within the near-Earth space. To achieve this goal, THOR payload is being designed to measure electromagnetic fields and particle distribution functions with unprecedented resolution and accuracy. Here we present the Ion Mass Spectrometer (IMS) instrument that will measure the full three-dimensional distribution functions of near-Earth main ion species (H+, He+, He++ and O+) at high time resolution (~ 150 ms for H+ , ~ 300 ms for He++) with energy resolution down to ~ 10% in the range 10 eV/q to 30 keV/q and angular resolution ~ 10°. Such high time resolution is achieved by mounting multiple sensors around the spacecraft body, in similar fashion to the MMS/FPI instrument. Each sensor combines a top-hat electrostatic analyzer with deflectors at the entrance together with a time-of-flight section to perform mass selection. IMS electronics includes a fast sweeping high voltage board that is required to make measurements at high cadence. Ion detection includes Micro Channel Plates (MCP) combined with Application-Specific Integrated Circuits (ASICs) for charge amplification, discrimination and time-to-digital conversion (TDC). IMS is being designed to address many of THOR science requirements, in particular ion heating and acceleration by turbulent fluctuations in foreshock, shock and magnetosheath regions. The IMS instrument is being designed and will be built by an international consortium of scientific institutes with main hardware contributions from France, USA, Japan and Germany.

North-south asymmetries in cold ion outflow and lobe density

NASA Astrophysics Data System (ADS)

Haaland, Stein; Laundal, Karl; Maes, Lukas; Baddeley, Lisa; Lybekk, Bjørn

2016-04-01

A significant fraction of the plasma in the terrestrial magnetosphere is supplied by the high-latitude ionosphere. The filling process starts with ionization of atoms and gas molecules in the thermosphere, and is often accompanied by upflow due to thermal and electromagnetic forces. Some of this material can reach escape velocities and be further accelerated and eventually evacuated into space. Ions are governed by electromagnetic forces and their transport path from the ionosphere to the magnetosphere go through the magnetotail lobes. The transport is largely dictated by magnetospheric convection. External influences, such as daily and seasonal variations in the Earth's tilt angle, but also non-dipolar terms in the Earth's internal magnetic field introduce north-south asymmetries in the magnetic field and thus north-south asymmetries in the ion outflow and lobe filling. In this presentation, we show observational results of this asymmetry. The results are based on more than a full solar cycle of cold ion measurements from the Cluster constellation of spacecraft, and allows us to quantify the outflow, identify sources of asymmetry and estimate transport paths.

Cold Ion Demagnetization near the X-line of Magnetic Reconnection

NASA Technical Reports Server (NTRS)

Toledo-Redondo, Serio; Andre, Mats; Khotyaintsev, Yuri V.; Vaivads, Andris; Walsh, Andrew; Li, Wenya; Graham, Daniel B.; Lavraud, Benoit; Masson, Arnaud; Aunai, Nicolas;

Cold ion demagnetization near the X-line of magnetic reconnection

NASA Astrophysics Data System (ADS)

Toledo-Redondo, Sergio; André, Mats; Khotyaintsev, Yuri V.; Vaivads, Andris; Walsh, Andrew; Li, Wenya; Graham, Daniel B.; Lavraud, Benoit; Masson, Arnaud; Aunai, Nicolas; Divin, Andrey; Dargent, Jeremy; Fuselier, Stephen; Gershman, Daniel J.; Dorelli, John; Giles, Barbara; Avanov, Levon; Pollock, Craig; Saito, Yoshifumi; Moore, Thomas E.; Coffey, Victoria; Chandler, Michael O.; Lindqvist, Per-Arne; Torbert, Roy; Russell, Christopher T.

2016-07-01

Although the effects of magnetic reconnection in magnetospheres can be observed at planetary scales, reconnection is initiated at electron scales in a plasma. Surrounding the electron diffusion region, there is an Ion-Decoupling Region (IDR) of the size of the ion length scales (inertial length and gyroradius). Reconnection at the Earth's magnetopause often includes cold magnetospheric (few tens of eV), hot magnetospheric (10 keV), and magnetosheath (1 keV) ions, with different gyroradius length scales. We report observations of a subregion inside the IDR of the size of the cold ion population gyroradius (˜15 km) where the cold ions are demagnetized and accelerated parallel to the Hall electric field. Outside the subregion, cold ions follow the E × B motion together with electrons, while hot ions are demagnetized. We observe a sharp cold ion density gradient separating the two regions, which we identify as the cold and hot IDRs.

Radiative, nonradiative, and mixed-decay transitions of rare-earth ions in dielectric media

NASA Astrophysics Data System (ADS)

Burshtein, Zeev

2010-09-01

We present and discuss in a comprehensive, deductive, and simplified manner, issues of nonradiative transitions involvement in fluorescence of ions embedded in dielectric solid matrices. The semiclassical approach is favored over a full quantum description, and empiric quantities are introduced from the start. One issue is nonradiative single-phonon transitions when the energy gap between the adjacent electronic ion states is smaller than the cutoff matrix phonon energy. Another issue is transitions in a complex energy scheme, where some visible and near-visible transitions are radiative and others are nonradiative. A refined Füchtbauer-Ladenburg recipe for calculation of the stimulated emission spectrum on the basis of measurable absorption and fluorescence emission spectra is worked out. The last issue is multiphonon nonradiative transitions occurring when the energy gap between adjacent electronic ion states is larger than the cutoff matrix phonon energy. Transition probabilities were calculated on the basis of anharmonicity of the effective potential supporting the internal atomic basis vibrations. An expression in a closed form is obtained, similar to the empiric ``energy gap'' law, however, with parameters related to specific host material properties and the actual transition in the ion. Comparison to existing experimental evidence is presented and discussed in detail.

Ion Transport and Acceleration at Dipolarization Fronts: High-Resolution MHD/Test-Particle Simulations

NASA Astrophysics Data System (ADS)

Ukhorskiy, A. Y.; Sorathia, K.; Merkin, V. G.; Sitnov, M. I.; Mitchell, D. G.; Wiltberger, M. J.; Lyon, J.

2017-12-01

Much of plasma heating and transport from the magnetotail into the inner magnetosphere occurs in the form of mesoscale discrete injections associated with sharp dipolarizations of magnetic field (dipolarization fronts). In this study we investigate the mechanisms of ion acceleration at dipolarization fronts in a high-resolution global magnetospheric MHD model (LFM). We use large-scale three-dimensional test-particle simulations (CHIMP) to address the following science questions: 1) what are the characteristic scales of dipolarization regions that can stably trap ions? 2) what role does the trapping play in ion transport and acceleration? 3) how does it depend on particle energy and distance from Earth? 4) to what extent ion acceleration is adiabatic? High-resolution LFM was run using idealized solar wind conditions with fixed nominal values of density and velocity and a southward IMF component of -5 nT. To simulate ion interaction with dipolarization fronts, a large ensemble of test particles distributed in energy, pitch-angle, and gyrophase was initialized inside one of the LFM dipolarization channels in the magnetotail. Full Lorentz ion trajectories were then computed over the course of the front inward propagation from the distance of 17 to 6 Earth radii. A large fraction of ions with different initial energies stayed in phase with the front over the entire distance. The effect of magnetic trapping at different energies was elucidated with a correlation of the ion guiding center and the ExB drift velocities. The role of trapping in ion energization was quantified by comparing the partial pressure of ions that exhibit trapping to the pressure of all trapped ions.

Magnetic separation of Dy(III) ions from homogeneous aqueous solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pulko, B., E-mail: Barbara.Pulko@tu-dresden.de; Yang, X.; Lei, Z.

2014-12-08

The possibility to enrich paramagnetic dysprosium(III) ions in a magnetic field gradient is proved by means of interferometry, which may open the route for a magnetic separation of rare earth ions from aqueous solutions. The separation dynamics are studied for three different concentrations of DyCl{sub 3} and compared with those found recently in a sulphate solution of the 3d ion Mn(II). In view of the similar-sized hydration spheres for Dy(III) and Mn(II), the slower separation dynamics in DyCl{sub 3} is attributed to both a higher densification coefficient and the strong impact of Brownian motion due to the absence of ion-pairmore » clusters.« less

Low energy spin dynamics of rare-earth orthoferrites YFeO3 and LaFeO3

NASA Astrophysics Data System (ADS)

Park, Kisoo; Sim, Hasung; Leiner, Jonathan; Yoshida, Yoshiyuki; Eisaki, Hiroshi; Yano, Shinichiro; Gardner, Jason; Park, Je-Geun

YFeO3 and LaFeO3\\ are members of the rare-earth orthoferrites (RFeO3) family with Pbnm space group. With the strong superexchange interaction between Fe3 + ions, both compounds exhibit the room temperature antiferromagnetic order (TN >600 K) with a slight spin canting. Here we report low-energy magnetic excitation of YFeO3 and LaFeO3 using inelastic neutron scattering measurements, showing evidence of magnon mode splitting and a spin anisotropy gap at the zone center. Spin wave calculations with the spin Hamiltonian including both Dzyaloshinsky-Moriya interaction and single-ion anisotropy accounts for the observed features well. Our results offer insight into the underlying physics of other RFeO3\\ with magnetic rare-earth ions or related Fe3+-based multiferroic perovskites such as BiFeO3. The work at the IBS CCES (South Korea) was supported by the research program of the Institute for Basic Science (IBS-R009-G1).

Transverse eV Ion Heating by Random Electric Field Fluctuations in the Plasmasphere

NASA Technical Reports Server (NTRS)

Artemyev, A. V.; Mourenas, D.; Agapitov, O. V.; Blum, L.

2017-01-01

Charged particle acceleration in the Earth inner magnetosphere is believed to be mainly due to the local resonant wave-particle interaction or particle transport processes. However, the Van Allen Probes have recently provided interesting evidence of a relatively slow transverse heating of eV ions at distances about 2-3 Earth radii during quiet times. Waves that are able to resonantly interact with such very cold ions are generally rare in this region of space, called the plasmasphere. Thus, non-resonant wave-particle interactions are expected to play an important role in the observed ion heating. We demonstrate that stochastic heating by random transverse electric field fluctuations of whistler (and possibly electromagnetic ion cyclotron) waves could explain this weak and slow transverse heating of H+ and O+ ions in the inner magnetosphere. The essential element of the proposed model of ion heating is the presence of trains of random whistler (hiss) wave packets, with significant amplitude modulations produced by strong wave damping, rapid wave growth, or a superposition of wave packets of different frequencies, phases, and amplitudes. Such characteristics correspond to measured characteristics of hiss waves in this region. Using test particle simulations with typical wave and plasma parameters, we demonstrate that the corresponding stochastic transverse ion heating reaches 0.07-0.2 eV/h for protons and 0.007-0.015 eV/h for O+ ions. This global temperature increase of the Maxwellian ion population from an initial Ti approx. 0.3 eV could potentially explain the observations.

In Situ Measurements of Meteoric Ions. Chapter 8

NASA Technical Reports Server (NTRS)

Grebowsky, Joseph M.; Aikin, Arthur C.; Vondrak, Richard R. (Technical Monitor)

2001-01-01

Metal ions found in the atmosphere above 60 km are the result of incoming meteoroid atmospheric ablation. Layers of metal ions are detected by sounding rocket in situ mass spectrometric sampling in the 80 to 130 km region, which coincides with the altitude region where meteors are observed. Enhancements of metal ion concentrations occur during meteor showers. Even outside of shower periods, the metal ion altitude profiles vary from measurement to measurement. Double layers are frequent at middle latitudes. More than 40 different meteoric atomic and molecular ions, including isotopes, have been detected. Atmospheric metal ions on average have an abundance that matches chrondritic material, the same composition as the early solar system. However there are frequently local departures from this composition due to differential ablation, species dependent chemistry and mass dependent ion transport. Metal ions react with atmospheric O2, O, O3, H2O and H2O2 to form oxygenated and hydrogenated ionic compounds. Metal atomic ions at high altitudes have long lifetimes. As a result, these ions, in the presence of Earth's magnetic field, are transported over long distances by upper atmospheric winds and ionospheric electric fields. Satellite measurements have detected metal ions as high as, approximately 1000 km and have revealed circulation of the ions on a global scale.

Determination of amines used in the oil and gas industry (upstream section) by ion chromatography.

PubMed

Kadnar, R

1999-07-30

During production and purification of crude oil and natural gas several different amines are used as chemicals or operating materials, e.g. film forming long chain amines as corrosion inhibitors, steam volatile amines for pH correction and corrosion protection, alkanolamines as absorbents in sour gas treatment plants, etc. For analytical checks, e.g. determination of corrosion inhibitor concentration in produced media, classical chemical methods are used predominantly, because most of them can be performed in small field laboratories. Some amines, especially the small molecular aliphatic and heterocyclic amines can also be determined by ion chromatography. In our laboratory two types of separation columns (IonPac CS10 and CS12A) were available for ion chromatographic separation. The analysis of the amines in low-salt-containing water, soft water or steam condensate can be performed without problems. The presence of alkali and/or alkaline earth ions in the sample can lead to coelution with these ions, to poor peak resolution or enhanced analysis times, depending on the chromatographic conditions. This work shows some examples of ion chromatography applications for the determination of low-molecular-mass ethanolamines, morpholine and piperazine and discusses the possible interferences and troubles caused by alkali and alkaline earth ions in the matrix.

Dissociation Energies of the Alkaline Earth Monofluorides

DOE Office of Scientific and Technical Information (OSTI.GOV)

BLUE, GARY D.; GREEN, JOHN W.; EHLERT, THOMAS C.

1963-08-24

New results and theoretical calculations are presented that indicate consistently high dissocintion energies for all the alkaline earth monofluorides. Experimental results were obtained by utilizing a mass spectrometer to analyze the vapors from a heated Ta Knudsen cell containing an alkaline earth fluoride salt with Al present as a reducing agent. Ionization efficiency curves were obtained and temperature dependence investigations were made to determine the molecular precursor of the ions observed. Values of the equilibrium constants at different temperatures were used together with the free-energy functions to calculate the third law heats of reaction at 298 deg K. Data aremore » tabulated for the heats of various reactions for Al--MF2 systems with M = Mg, Ca, Sr, and Ba, and dissociation energies of MF molecules by various methods for Be, Mg, Ca, Sr, and Ba. (C.H.)« less

Dynamics Explorer 1: Energetic Ion Composition Spectrometer (EICS)

NASA Technical Reports Server (NTRS)

Shelley, E. G.; Peterson, W. K.; Collin, H. L.

1994-01-01

The Energetic Ion Composition Spectrometer (EICS) experiment was selected as part of the Dynamics Explorer (DE) Program. One of the primary goals of the DE program was to investigate in detail the plasma physics processes responsible for energizing thermal (approximately 1 eV) ionospheric ions and transporting them to the earth's plasma sheet and distant polar cap. The results of the EICS data analysis (including support of other investigators) and of the archiving efforts supported by this contract are summarized in this document. Also reported are some aspects of our operational support activities.

Interfacing broadband photonic qubits to on-chip cavity-protected rare-earth ensembles

NASA Astrophysics Data System (ADS)

Zhong, Tian; Kindem, Jonathan M.; Rochman, Jake; Faraon, Andrei

2017-01-01

Ensembles of solid-state optical emitters enable broadband quantum storage and transduction of photonic qubits, with applications in high-rate quantum networks for secure communications and interconnecting future quantum computers. To transfer quantum states using ensembles, rephasing techniques are used to mitigate fast decoherence resulting from inhomogeneous broadening, but these techniques generally limit the bandwidth, efficiency and active times of the quantum interface. Here, we use a dense ensemble of neodymium rare-earth ions strongly coupled to a nanophotonic resonator to demonstrate a significant cavity protection effect at the single-photon level--a technique to suppress ensemble decoherence due to inhomogeneous broadening. The protected Rabi oscillations between the cavity field and the atomic super-radiant state enable ultra-fast transfer of photonic frequency qubits to the ions (~50 GHz bandwidth) followed by retrieval with 98.7% fidelity. With the prospect of coupling to other long-lived rare-earth spin states, this technique opens the possibilities for broadband, always-ready quantum memories and fast optical-to-microwave transducers.

Theoretical Study of pKa Values for Trivalent Rare-Earth Metal Cations in Aqueous Solution.

PubMed

Yu, Donghai; Du, Ruobing; Xiao, Ji-Chang; Xu, Shengming; Rong, Chunying; Liu, Shubin

2018-01-18

Molecular acidity of trivalent rare-earth metal cations in aqueous solution is an important factor dedicated to the efficiency of their extraction and separation processes. In this work, the aqueous acidity of these metal ions has been quantitatively investigated using a few theoretical approaches. Our computational results expressed in terms of pK a values agree well with the tetrad effect of trivalent rare-earth ions extensively reported in the extraction and separation of these elements. Strong linear relationships have been observed between the acidity and quantum electronic descriptors such as the molecular electrostatic potential on the acidic nucleus and the sum of the valence natural atomic orbitals energies of the dissociating proton. Making use of the predicted pK a values, we have also predicted the major ionic forms of these species in the aqueous environment with different pH values, which can be employed to rationalize the behavior difference of different rare-earth metal cations during the extraction process. Our present results should provide needed insights not only for the qualitatively understanding about the extraction and separation between yttrium and lanthanide elements but also for the prediction of novel and more efficient rare-earth metal extractants in the future.

Origins and Transport of Ions during Magnetospheric Substorms

NASA Technical Reports Server (NTRS)

Ashour-Abdalla, Maha; El-Alaoui, Mostafa; Peroomian, Vahe; Raeder, Joachim; Walker, Ray J.; Frank, L. A.; Paterson, W. R.

1999-01-01

We investigate the origins and the transport of ions observed in the near-Earth plasma sheet during the growth and expansion phases of a magnetospheric substorm that occurred on November 24, 1996. Ions observed at Geotail were traced backward in time in time-dependent magnetic and electric fields to determine their origins and the acceleration mechanisms responsible for their energization. Results from this investigation indicate that, during the growth phase of the substorm, most of the ions reaching Geotail had origins in the low latitude boundary layer (LLBL) and had alread@, entered the magnetosphere when the growth phase began. Late in the growth phase and in the expansion phase a higher proportion of the ions reaching Geotail had their origin in the plasma mantle. Indeed, during the expansion phase more than 90% of the ions seen by Geotail were from the mantle. The ions were accelerated enroute to the spacecraft; however, most of the ions' energy gain was achieved by non-adiabatic acceleration while crossing the equatorial current sheet just prior to their detection by Geotail. In general, the plasma mantle from both southern and northern hemispheres supplied non-adiabatic ions to Geotail, whereas the LLBL supplied mostly adiabatic ions to the distributions measured by the spacecraft.

A study of environmental effects caused by cesium from ion thrusters

NASA Technical Reports Server (NTRS)

1971-01-01

The ATS-F satellite will carry two cesium ion thrusters. Cesium is a material that is not present in the upper atmosphere, and there is concern that the introduction of this material may result in some unexpected behavior. A study has been conducted to assess the magnitude of the effects that are to be expected. No observable effects were found as a result of the study. Consideration was given to the origin and destination of the material and the various reactions that could occur. The origin was considered to be anywhere in space from altitudes of about 100 km upward. The probable short term destination is in the form of cesium ions trapped in the earth's magnetic field or as ions and atoms in the heterosphere. The maximum possible number of cesium atoms in the field of view of an earth based observer is of the order of one million per square centimeter, far too few to be observable by visible, near-visible, or radio-frequency means. Further, no phenomena could be found that would result in the occurance of an observable event.

A divalent rare earth oxide semiconductor: Yttrium monoxide

NASA Astrophysics Data System (ADS)

Kaminaga, Kenichi; Sei, Ryosuke; Hayashi, Kouichi; Happo, Naohisa; Tajiri, Hiroo; Oka, Daichi; Fukumura, Tomoteru; Hasegawa, Tetsuya

Rare earth sesquioxides like Y2O3 are known as widegap insulators with the highly stable closed shell trivalent rare earth ions. On the other hand, rare earth monoxides such as YO have been recognized as gaseous phase, and only EuO and YbO were thermodynamically stable solid-phase rock salt monoxides. In this study, solid-phase rock salt yttrium monoxide, YO, was synthesized in a form of epitaxial thin film by pulsed laser deposition method. YO possesses unusual valence of Y2+ ([Kr] 4d1) . In contrast with Y2O3, YO was narrow gap semiconductor with dark-brown color. The electrical conductivity was tunable from 10-1 to 103 Ω-1 cm-1 by introducing oxygen vacancies as electron donor. Weak antilocalization behavior was observed indicating significant spin-orbit coupling owing to 4 d electron carrier. The absorption spectral shape implies the Mott-Hubbard insulator character of YO. Rare earth monoixdes will be new platform of functional oxides. This work was supported by JST-CREST, the Japan Society for the Promotion of Science (JSPS) with Grant-in-Aid for Scientific Research on Innovative Areas (Nos. 26105002 and 26105006), and Nanotechnology Platform (Project No.12024046) of MEXT, Japan.

Cold Ionospheric Ions in the Magnetic Reconnection Outflow Region

NASA Astrophysics Data System (ADS)

Li, W. Y.; André, M.; Khotyaintsev, Yu. V.; Vaivads, A.; Fuselier, S. A.; Graham, D. B.; Toledo-Redondo, S.; Lavraud, B.; Turner, D. L.; Norgren, C.; Tang, B. B.; Wang, C.; Lindqvist, P.-A.; Young, D. T.; Chandler, M.; Giles, B.; Pollock, C.; Ergun, R.; Russell, C. T.; Torbert, R.; Moore, T.; Burch, J.

2017-10-01

Magnetosheath plasma usually determines properties of asymmetric magnetic reconnection at the subsolar region of Earth's magnetopause. However, cold plasma that originated from the ionosphere can also reach the magnetopause and modify the kinetic physics of asymmetric reconnection. We present a magnetopause crossing with high-density (10-60 cm-3) cold ions and ongoing reconnection from the observation of the Magnetospheric Multiscale (MMS) spacecraft. The magnetopause crossing is estimated to be 300 ion inertial lengths south of the X line. Two distinct ion populations are observed on the magnetosheath edge of the ion jet. One population with high parallel velocities (200-300 km/s) is identified to be cold ion beams, and the other population is the magnetosheath ions. In the deHoffman-Teller frame, the field-aligned magnetosheath ions are Alfvénic and move toward the jet region, while the field-aligned cold ion beams move toward the magnetosheath boundary layer, with much lower speeds. These cold ion beams are suggested to be from the cold ions entering the jet close to the X line. This is the first observation of the cold ionospheric ions in the reconnection outflow region, including the reconnection jet and the magnetosheath boundary layer.

International Space Station Lithium-Ion Battery Start-Up

NASA Technical Reports Server (NTRS)

Dalton, Penni J.; North, Tim; Bowens, Ebony; Balcer, Sonia

2017-01-01

International Space Station Lithium-Ion Battery Start-Up.The International Space Station (ISS) primary Electric Power System (EPS) was originally designed to use Nickel-Hydrogen (Ni-H2) batteries to store electrical energy. The electricity for the space station is generated by its solar arrays, which charge batteries during insolation for subsequent discharge during eclipse. The Ni-H2 batteries are designed to operate at a 35 depth of discharge (DOD) maximum during normal operation in a Low Earth Orbit. As the oldest of the 48 Ni-H2 battery Orbital Replacement Units (ORUs) has been cycling since September 2006, these batteries are now approaching their end of useful life. In 2010, the ISS Program began the development of Lithium-Ion (Li-ion) batteries to replace the Ni-H2 batteries and concurrently funded a Li-Ion ORU and cell life testing project. The first set of 6 Li-ion battery replacements were launched in December 2016 and deployed in January 2017. This paper will discuss the Li-ion battery on-orbit start-up and the status of the Li-Ion cell and ORU life cycle testing.

The Stanford-U.S. Geological Survey SHRIMP ion microprobe--a tool for micro-scale chemical and isotopic analysis

USGS Publications Warehouse

Bacon, Charles R.; Grove, Marty; Vazquez, Jorge A.; Coble, Matthew A.

2012-01-01

Answers to many questions in Earth science require chemical analysis of minute volumes of minerals, volcanic glass, or biological materials. Secondary Ion Mass Spectrometry (SIMS) is an extremely sensitive analytical method in which a 5–30 micrometer diameter "primary" beam of charged particles (ions) is focused on a region of a solid specimen to sputter secondary ions from 1–5 nanograms of the sample under high vacuum. The elemental abundances and isotopic ratios of these secondary ions are determined with a mass spectrometer. These results can be used for geochronology to determine the age of a region within a crystal thousands to billions of years old or to precisely measure trace abundances of chemical elements at concentrations as low as parts per billion. A partnership of the U.S. Geological Survey and the Stanford University School of Earth Sciences operates a large SIMS instrument, the Sensitive High-Resolution Ion Microprobe with Reverse Geometry (SHRIMP–RG) on the Stanford campus.

Half-sandwich rare-earth-catalyzed olefin polymerization, carbometalation, and hydroarylation.

PubMed

Nishiura, Masayoshi; Guo, Fang; Hou, Zhaomin

2015-08-18

The search for new catalysts for more efficient, selective chemical transformations and for the synthesis of new functional materials has been a long-standing research subject in both academia and industry. To develop new generations of catalysts that are superior or complementary to the existing ones, exploring the potential of untapped elements is an important strategy. Rare-earth elements, including scandium, yttrium, and the lanthanides (La-Lu), constitute one important frontier in the periodic table. Rare-earth elements possess unique chemical and physical properties that are different from those of main-group and late-transition metals. The development of rare-earth-based catalysts by taking the advantage of these unique properties is of great interest and importance. The most stable oxidation state of rare-earth metals is 3+, which is difficult to change under many reaction conditions. The oxidative addition and reductive elimination processes often observed in catalytic cycles involving late transition metals are generally difficult in the case of rare-earth complexes. The 18-electron rule that is applicable to late-transition-metal complexes does not fit rare-earth complexes, whose structures are mainly governed by the sterics (rather than the electron numbers) of the ligands. In the lanthanide series (La-Lu), the ionic radius gradually decreases with increasing atomic number because of the influence of the 4f electrons, which show poor shielding of nuclear charge. Rare-earth metal ions generally show strong Lewis acidity and oxophilicity. Rare-earth metal alkyl and hydride species are highly reactive, showing both nucleophilicity and basicity. The combination of these features, such as the strong nucleophilicity and moderate basicity of the alkyl and hydride species and the high stability, strong Lewis acidity, and unsaturated C-C bond affinity of the 3+ metal ions, can make rare-earth metals unique candidates for the formation of excellent single

Atomic oxygen ions as ionospheric biomarkers on exoplanets

NASA Astrophysics Data System (ADS)

Mendillo, Michael; Withers, Paul; Dalba, Paul A.

2018-04-01

The ionized form of atomic oxygen (O+) is the dominant ion species at the altitude of maximum electron density in only one of the many ionospheres in our Solar System — Earth's. This ionospheric composition would not be present if oxygenic photosynthesis was not an ongoing mechanism that continuously impacts the terrestrial atmosphere. We propose that dominance of ionospheric composition by O+ ions at the altitude of maximum electron density can be used to identify a planet in orbit around a solar-type star where global-scale biological activity is present. There is no absolute numerical value required for this suggestion of an atmospheric plasma biomarker — only the dominating presence of O+ ions at the altitude of peak electron density.

Rare Earth Doped Yttrium Aluminum Garnet (YAG) Selective Emitters

NASA Technical Reports Server (NTRS)

Chubb, Donald L.; Pal, AnnaMarie T.; Patton, Martin O.; Jenkins, Phillip P.

1999-01-01

As a result of their electron structure, rare earth ions in crystals at high temperature emit radiation in several narrow bands rather than in a continuous blackbody manner. This study presents a spectral emittance model for films and cylinders of rare earth doped yttrium aluminum garnets. Good agreement between experimental and theoretical film spectral emittances was found for erbium and holmium aluminum garnets. Spectral emittances of films are sensitive to temperature differences across the film. For operating conditions of interest, the film emitter experiences a linear temperature variation whereas the cylinder emitter has a more advantageous uniform temperature. Emitter efficiency is also a sensitive function of temperature. For holminum aluminum garnet film the efficiency is 0.35 at 1446K but only 0.27 at 1270 K.

Comparative investigation of the energetic ion spectra comprising the magnetospheric ring currents of the solar system

PubMed Central

Mauk, B H

2014-01-01

Investigated here are factors that control the intensities and shapes of energetic ion spectra that make up the ring current populations of the strongly magnetized planets of the solar system, specifically those of Earth, Jupiter, Saturn, Uranus, and Neptune. Following a previous and similar comparative investigation of radiation belt electrons, we here turn our attention to ions. Specifically, we examine the possible role of the differential ion Kennel-Petschek limit, as moderated by Electromagnetic Ion Cyclotron (EMIC) waves, as a standard for comparing the most intense ion spectra within the strongly magnetized planetary magnetospheres. In carrying out this investigation, the substantial complexities engendered by the very different ion composition distributions of these diverse magnetospheres must be addressed, given that the dispersion properties of the EMIC waves are strongly determined by the ion composition of the plasmas within which the waves propagate. Chosen for comparison are the ion spectra within these systems that are the most intense observed, specifically at 100 keV and 1 MeV. We find that Earth and Jupiter are unique in having their most intense ion spectra likely limited and sculpted by the Kennel-Petschek process. The ion spectra of Saturn, Uranus, and Neptune reside far below their respective limits and are likely limited by interactions with gas and dust (Saturn) and by the absence of robust ion acceleration processes (Uranus and Neptune). Suggestions are provided for further testing the efficacy of the differential Kennel-Petschek limit for ions using the Van Allen Probes. PMID:26167438

Drift paths of ions composing multiple-nose spectral structures near the inner edge of the plasma sheet

NASA Astrophysics Data System (ADS)

Ferradas, C. P.; Zhang, J.-C.; Spence, H. E.; Kistler, L. M.; Larsen, B. A.; Reeves, G.; Skoug, R.; Funsten, H.

2016-11-01

We present a case study of the H+, He+, and O+ multiple-nose structures observed by the Helium, Oxygen, Proton, and Electron instrument on board Van Allen Probe A over one complete orbit on 28 September 2013. Nose structures are observed near the inner edge of the plasma sheet and constitute the signatures of ion drift in the highly dynamic environment of the inner magnetosphere. We find that the multiple noses are intrinsically associated with variations in the solar wind. Backward ion drift path tracings show new details of the drift trajectories of these ions; i.e., multiple noses are formed by ions with a short drift time from the assumed source location to the inner region and whose trajectories (1) encircle the Earth different number of times or (2) encircle the Earth equal number of times but with different drift time, before reaching the observation site.

Microwave ECR Ion Thruster Development Activities at NASA Glenn Research Center

NASA Technical Reports Server (NTRS)

Foster, John E.; Patterson, Michael J.

2002-01-01

Outer solar system missions will have propulsion system lifetime requirements well in excess of that which can be satisfied by ion thrusters utilizing conventional hollow cathode technology. To satisfy such mission requirements, other technologies must be investigated. One possible approach is to utilize electrodeless plasma production schemes. Such an approach has seen low power application less than 1 kW on earth-space spacecraft such as ARTEMIS which uses the rf thruster the RIT 10 and deep space missions such as MUSES-C which will use a microwave ion thruster. Microwave and rf thruster technologies are compared. A microwave-based ion thruster is investigated for potential high power ion thruster systems requiring very long lifetimes.

Recombination of electrons with NH4/+/-/NH3/n-series ions

NASA Technical Reports Server (NTRS)

Huang, C.-M.; Biondi, M. A.; Johnsen, R.

1976-01-01

The paper examines the recombination of electrons with ammonium-series cluster ions, NH4(+)-(NH3)n, for two reasons: (1) NH4(+) may be a significant ion in the lower atmospheres of the earth and the outer planets, and (2) to investigate the weak temperature dependence of the cluster ion's recombination coefficient. A microwave afterglow mass spectrometer was used to determine the recombination coefficients for the first five members of the ammonium series, (18+) through (86+), at temperatures between 200 and 410 K. The electron temperature dependence of the recombination coefficient was determined for (35+) and (52+), the n = 1 and 2 cluster ions, over the temperature range 300-3000 K.

Rationally designed mineralization for selective recovery of the rare earth elements

NASA Astrophysics Data System (ADS)

Hatanaka, Takaaki; Matsugami, Akimasa; Nonaka, Takamasa; Takagi, Hideki; Hayashi, Fumiaki; Tani, Takao; Ishida, Nobuhiro

2017-05-01

The increasing demand for rare earth (RE) elements in advanced materials for permanent magnets, rechargeable batteries, catalysts and lamp phosphors necessitates environmentally friendly approaches for their recovery and separation. Here, we propose a mineralization concept for direct extraction of RE ions with Lamp (lanthanide ion mineralization peptide). In aqueous solution containing various metal ions, Lamp promotes the generation of RE hydroxide species with which it binds to form hydrophobic complexes that accumulate spontaneously as insoluble precipitates, even under physiological conditions (pH ~6.0). This concept for stabilization of an insoluble lanthanide hydroxide complex with an artificial peptide also works in combination with stable scaffolds like synthetic macromolecules and proteins. Our strategy opens the possibility for selective separation of target metal elements from seawater and industrial wastewater under mild conditions without additional energy input.

Rationally designed mineralization for selective recovery of the rare earth elements.

PubMed

Hatanaka, Takaaki; Matsugami, Akimasa; Nonaka, Takamasa; Takagi, Hideki; Hayashi, Fumiaki; Tani, Takao; Ishida, Nobuhiro

2017-05-26

The increasing demand for rare earth (RE) elements in advanced materials for permanent magnets, rechargeable batteries, catalysts and lamp phosphors necessitates environmentally friendly approaches for their recovery and separation. Here, we propose a mineralization concept for direct extraction of RE ions with Lamp (lanthanide ion mineralization peptide). In aqueous solution containing various metal ions, Lamp promotes the generation of RE hydroxide species with which it binds to form hydrophobic complexes that accumulate spontaneously as insoluble precipitates, even under physiological conditions (pH ∼6.0). This concept for stabilization of an insoluble lanthanide hydroxide complex with an artificial peptide also works in combination with stable scaffolds like synthetic macromolecules and proteins. Our strategy opens the possibility for selective separation of target metal elements from seawater and industrial wastewater under mild conditions without additional energy input.

Dominance of high-energy (>150 keV) heavy ion intensities in Earth's middle to outer magnetosphere

NASA Astrophysics Data System (ADS)

Cohen, Ian J.; Mitchell, Donald G.; Kistler, Lynn M.; Mauk, Barry H.; Anderson, Brian J.; Westlake, Joseph H.; Ohtani, Shinichi; Hamilton, Douglas C.; Turner, Drew L.; Blake, J. Bernard; Fennell, Joseph F.; Jaynes, Allison N.; Leonard, Trevor W.; Gerrard, Andrew J.; Lanzerotti, Louis J.; Allen, Robert C.; Burch, James L.

2017-09-01

Previous observations have driven the prevailing assumption in the field that energetic ions measured by an instrument using a bare solid state detector (SSD) are predominantly protons. However, new near-equatorial energetic particle observations obtained between 7 and 12 RE during Phase 1 of the Magnetospheric Multiscale mission challenge the validity of this assumption. In particular, measurements by the Energetic Ion Spectrometer (EIS) instruments have revealed that the intensities of heavy ion species (specifically oxygen and helium) dominate those of protons at energies ≳150-220 keV in the middle to outer (>7 RE) magnetosphere. Given that relative composition measurements can drift as sensors degrade in gain, quality cross-calibration agreement between EIS observations and those from the SSD-based Fly's Eye Energetic Particle Spectrometer (FEEPS) sensors provides critical support to the veracity of the measurement. Similar observations from the Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instruments aboard the Van Allen Probes spacecraft extend the ion composition measurements into the middle magnetosphere and reveal a strongly proton-dominated environment at L≲6 but decreasing proton intensities at L≳6. It is concluded that the intensity dominance of the heavy ions at higher energies (>150 keV) arises from the existence of significant populations of multiply-charged heavy ions, presumably of solar wind origin.

Li-Ion Battery Studies at NASA/Goddard Space Flight Center

NASA Technical Reports Server (NTRS)

Lee, Leonine; Rao, Gopalakrishna M.

2006-01-01

This viewgraph presentation reviews NASA and GSFC's interest in Lithium Ion Batteries as power suupplies for space usage, the tests, and results on several commercially available batteries. Severl batteries were tested for Geosynchronous orbit, Low Earth Orbit, and Low Lunar Orbit conditions.

Strides made in understanding space weather at Earth

NASA Astrophysics Data System (ADS)

Buonsanto, M. J.; Fuller-Rowell, T. J.

Disturbances on the Sun can produce dramatic effects in the space environment surrounding the Earth. Energetic particle effects become more intense and pose a hazard to astronauts and damage spacecraft electronics; satellite lifetimes are shortened by increased atmospheric drag, and communications and navigation are disrupted by the changing plasma environment.“Space weather” has become the modern idiom for these effects, and periods of high activity are called geomagnetic storms. During a storm the ionosphere can be severely altered. A typical episode may reveal either a large decrease (negative phase) or increase (positive phase) in the normal daily peak ion density (NmF2) or total electron content (TEC). These changes in ion density are sometimes called ionospheric storms, and often persist for more than a day after a period of high geomagnetic activity.

Cathodoluminescence of rare earth implanted Ga2O3 and GeO2 nanostructures.

PubMed

Nogales, E; Hidalgo, P; Lorenz, K; Méndez, B; Piqueras, J; Alves, E

2011-07-15

Rare earth (RE) doped gallium oxide and germanium oxide micro- and nanostructures, mostly nanowires, have been obtained and their morphological and optical properties have been characterized. Undoped oxide micro- and nanostructures were grown by a thermal evaporation method and were subsequently doped with gadolinium or europium ions by ion implantation. No significant changes in the morphologies of the nanostructures were observed after ion implantation and thermal annealing. The luminescence emission properties have been studied with cathodoluminescence (CL) in a scanning electron microscope (SEM). Both β-Ga(2)O(3) and GeO(2) structures implanted with Eu show the characteristic red luminescence peak centered at around 610 nm, due to the (5)D(0)-(7)F(2) Eu(3+) intraionic transition. Sharpening of the luminescence peaks after thermal annealing is observed in Eu implanted β-Ga(2)O(3), which is assigned to the lattice recovery. Gd(3+) as-implanted samples do not show rare earth related luminescence. After annealing, optical activation of Gd(3+) is obtained in both matrices and a sharp ultraviolet peak centered at around 315 nm, associated with the Gd(3+) (6)P(7/2)-(8)S(7/2) intraionic transition, is observed. The influence of the Gd ion implantation and the annealing temperature on the gallium oxide broad intrinsic defect band has been analyzed.

Inner Source and Interstellar Pickup Ions observed by MMS-HPCA

NASA Astrophysics Data System (ADS)

Gomez, Roman; Fuselier, Stephen; Burch, James L.; Mukherjee, Joey; Valek, Phillip W.; Allegrini, Frederic; Desai, Mihir I.

2017-04-01

Pickup Ions in the solar system are either of interstellar origin, or come from an inner source whose existence is confirmed, but which has not been directly observed. The Hot Plasma Composition Analyzer of the Magnetospheric Multiscale mission (MMS-HPCA) measures the energy and directional flux of ions with M/Q from 1 eV/e to 40 keV/e and is used measure the composition and dynamics of reconnection plasmas near the earth. During the first phase of the mission, from 1 September 2015 to 8 March 2016, the spacecraft at 12 Earth Radii apogee swept through the dayside from 1800 to 0600 local time. Although the apogee was designed to maximize encounters with the magnetopause, there were many instances when the spacecraft crossed the bow shock and sampled the solar wind. In November and December, while the spacecraft were downstream of the interstellar neutral focusing cone, HPCA detected pick up ions, such as He+, O+, and Ne+. He+ was distributed in an energy range of 14 eV - 20.6 keV, peaking at 757 eV; presumably of interstellar origin. O+ was observed in the energy range of 390 eV - 10.6 keV, and also seems to come from the interstellar medium. Ne+ was observed to be tightly distributed around a center energy of 5.5 keV, which implies an inner source origin. The mass - energy - angle analysis of these pick up ion distributions is presented, and their interpretation in terms of interstellar and inner source ions is discussed.

Xenon ion propulsion for orbit transfer

NASA Technical Reports Server (NTRS)

Rawlin, V. K.; Patterson, M. J.; Gruber, R. P.

1990-01-01

For more than 30 years, NASA has conducted an ion propulsion program which has resulted in several experimental space flight demonstrations and the development of many supporting technologies. Technologies appropriate for geosynchronous stationkeeping, earth-orbit transfer missions, and interplanetary missions are defined and evaluated. The status of critical ion propulsion system elements is reviewed. Electron bombardment ion thrusters for primary propulsion have evolved to operate on xenon in the 5 to 10 kW power range. Thruster efficiencies of 0.7 and specific impulse values of 4000 s were documented. The baseline thruster currently under development by NASA LeRC includes ring-cusp magnetic field plasma containment and dished two-grid ion optics. Based on past experience and demonstrated simplifications, power processors for these thrusters should have approximately 500 parts, a mass of 40 kg, and an efficiency near 0.94. Thrust vector control, via individual thruster gimbals, is a mature technology. High pressure, gaseous xenon propellant storage and control schemes, using flight qualified hardware, result in propellant tankage fractions between 0.1 and 0.2. In-space and ground integration testing has demonstrated that ion propulsion systems can be successfully integrated with their host spacecraft. Ion propulsion system technologies are mature and can significantly enhance and/or enable a variety of missions in the nation's space propulsion program.

XUV-exposed, non-hydrostatic hydrogen-rich upper atmospheres of terrestrial planets. Part II: hydrogen coronae and ion escape.

PubMed

Kislyakova, Kristina G; Lammer, Helmut; Holmström, Mats; Panchenko, Mykhaylo; Odert, Petra; Erkaev, Nikolai V; Leitzinger, Martin; Khodachenko, Maxim L; Kulikov, Yuri N; Güdel, Manuel; Hanslmeier, Arnold

2013-11-01

We studied the interactions between the stellar wind plasma flow of a typical M star, such as GJ 436, and the hydrogen-rich upper atmosphere of an Earth-like planet and a "super-Earth" with a radius of 2 R(Earth) and a mass of 10 M(Earth), located within the habitable zone at ∼0.24 AU. We investigated the formation of extended atomic hydrogen coronae under the influences of the stellar XUV flux (soft X-rays and EUV), stellar wind density and velocity, shape of a planetary obstacle (e.g., magnetosphere, ionopause), and the loss of planetary pickup ions on the evolution of hydrogen-dominated upper atmospheres. Stellar XUV fluxes that are 1, 10, 50, and 100 times higher compared to that of the present-day Sun were considered, and the formation of high-energy neutral hydrogen clouds around the planets due to the charge-exchange reaction under various stellar conditions was modeled. Charge-exchange between stellar wind protons with planetary hydrogen atoms, and photoionization, lead to the production of initially cold ions of planetary origin. We found that the ion production rates for the studied planets can vary over a wide range, from ∼1.0×10²⁵ s⁻¹ to ∼5.3×10³⁰ s⁻¹, depending on the stellar wind conditions and the assumed XUV exposure of the upper atmosphere. Our findings indicate that most likely the majority of these planetary ions are picked up by the stellar wind and lost from the planet. Finally, we estimated the long-time nonthermal ion pickup escape for the studied planets and compared them with the thermal escape. According to our estimates, nonthermal escape of picked-up ionized hydrogen atoms over a planet's lifetime within the habitable zone of an M dwarf varies between ∼0.4 Earth ocean equivalent amounts of hydrogen (EO(H)) to <3 EO(H) and usually is several times smaller in comparison to the thermal atmospheric escape rates.

Characteristics of low energy ions in the Heavy Ions In Space (HIIS) experiment

NASA Technical Reports Server (NTRS)

Kleis, Thomas; Tylka, Allan J.; Boberg, Paul R.; Adams, James H., Jr.; Beahm, Lorraine P.

1995-01-01

We present preliminary data on heavy ions (Z greater than or equal to 10) detected in the topmost Lexan sheets of the track detector stacks of the Heavy Ions in space (HIIS) experiment (M0001) on LDEF. The energy interval covered by these observations varies with the element, with (for example) Ne observable at 18-100 MeV nuc and Fe at 45-200 MeV/nuc. All of the observed ions are at energies far below the geomagnetic cutoff for fully-ionized particles at the LDEF orbit. Above 50 MeV/nuc (where most of our observed particles are Fe), the ions arrive primarily from the direction of lowest geomagnetic cutoff. This suggests that these particles originate outside the magnetosphere from a source with a steeply-falling spectrum and may therefore be associated with solar energetic particle (SEP) events. Below 50 MeV/nuc, the distribution of arrival directions suggests that most of the observed heavy ions are trapped in the Earth's magnetic field. Preliminary analysis, however, shows that these trapped heavy ions have a very surprising composition: they include not only Ne and Ar, which are expected from the trapping of anomalous cosmic rays (ACR's), but also Mg and Si, which are not part of the anomalous component. Our preliminary analysis shows that trapped heavy ions at 12 less than or equal to Zeta less than or equal to 14 have a steeply-falling spectrum, similar to that reported by the Kiel experiment (exp 1,2,3) on LDEF (M0002) for trapped Ar and Fe at E less than 50 MeV/nuc. The trapped Mg, Si, and Fe may also be associated with SEP events, but the mechanism by which they have appeared to deep in the inner magnetosphere requires further theoretical investigation.

Energetic ion leakage from foreshock transient cores

NASA Astrophysics Data System (ADS)

Liu, Terry Z.; Angelopoulos, Vassilis; Hietala, Heli

2017-07-01

Earth's foreshock is filled with backstreaming particles that can interact with the ambient solar wind and its discontinuities to form foreshock transients. Many foreshock transients have a core with low dynamic pressure that can significantly perturb the bow shock and the magnetosphere-ionosphere system. Foreshock transients have also been recently recognized as sites of particle acceleration, which may be important for seeding the parent shock with energetic particles. A relevant step of this seeding would be energetic ion leakage into the surrounding foreshock environment. On the other hand, such leakage would also suppress the energetic particle flux contrast across foreshock transients' boundaries masking their perceived contribution to ion energization. To further examine this hypothesis of ion leakage, we report on multipoint case studies of three foreshock transient events selected from a large database. The cases were selected to exemplify, in increasing complexity, the nature and consequences of energetic ion leakage. Ion energy dispersion, observed upstream and/or downstream of the foreshock transients, is explained with a simple, ballistic model of ions leaking from the foreshock transients. Larger energies are required for leaked ions to reach the spacecraft as the distance between the transient and spacecraft increases. Our model, which explains well the observed ion energy dispersion and velocity distributions, can also be used to reveal the shape of the foreshock transients in three dimensions. Our results suggest that ion leakage from foreshock transient cores needs to be accounted for both in statistical studies and in global models of ion acceleration under quasi-parallel foreshock conditions.

Strategy for earth explorers in global earth sciences

NASA Technical Reports Server (NTRS)

1988-01-01

The goal of the current NASA Earth System Science initiative is to obtain a comprehensive scientific understanding of the Earth as an integrated, dynamic system. The centerpiece of the Earth System Science initiative will be a set of instruments carried on polar orbiting platforms under the Earth Observing System program. An Earth Explorer program can open new vistas in the earth sciences, encourage innovation, and solve critical scientific problems. Specific missions must be rigorously shaped by the demands and opportunities of high quality science and must complement the Earth Observing System and the Mission to Planet Earth. The committee believes that the proposed Earth Explorer program provides a substantial opportunity for progress in the earth sciences, both through independent missions and through missions designed to complement the large scale platforms and international research programs that represent important national commitments. The strategy presented is intended to help ensure the success of the Earth Explorer program as a vital stimulant to the study of the planet.

Drift paths of ions composing multiple-nose spectral structures near the inner edge of the plasma sheet

DOE PAGES

Ferradas, C. P.; Zhang, J. -C.; Spence, H. E.; ...

2016-11-05

Here in this paper, we present a case study of the H +, He +, and O + multiple-nose structures observed by the Helium, Oxygen, Proton, and Electron instrument on board Van Allen Probe A over one complete orbit on 28 September 2013. Nose structures are observed near the inner edge of the plasma sheet and constitute the signatures of ion drift in the highly dynamic environment of the inner magnetosphere. We find that the multiple noses are intrinsically associated with variations in the solar wind. Backward ion drift path tracings show new details of the drift trajectories of thesemore » ions; i.e., multiple noses are formed by ions with a short drift time from the assumed source location to the inner region and whose trajectories (1) encircle the Earth different number of times or (2) encircle the Earth equal number of times but with different drift time, before reaching the observation site.« less

Drift paths of ions composing multiple-nose spectral structures near the inner edge of the plasma sheet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferradas, C. P.; Zhang, J. -C.; Spence, H. E.

Here in this paper, we present a case study of the H +, He +, and O + multiple-nose structures observed by the Helium, Oxygen, Proton, and Electron instrument on board Van Allen Probe A over one complete orbit on 28 September 2013. Nose structures are observed near the inner edge of the plasma sheet and constitute the signatures of ion drift in the highly dynamic environment of the inner magnetosphere. We find that the multiple noses are intrinsically associated with variations in the solar wind. Backward ion drift path tracings show new details of the drift trajectories of thesemore » ions; i.e., multiple noses are formed by ions with a short drift time from the assumed source location to the inner region and whose trajectories (1) encircle the Earth different number of times or (2) encircle the Earth equal number of times but with different drift time, before reaching the observation site.« less

Rare earth elements geochemistry in springs from Taftan geothermal area SE Iran

NASA Astrophysics Data System (ADS)

Shakeri, Ata; Ghoreyshinia, Sayedkazem; Mehrabi, Behzad; Delavari, Morteza

2015-10-01

Concentrations of rare earth elements (REEs) were determined in springs and andesitic-dacitic rocks of Taftan geothermal field. Hydrochemical results of major ions indicate that thermal springs are Na-SO4-Cl and Ca-SO4-Cl types. Concentrations of REEs are in ranges of 10- 4 to 1.2 and 49 to 62 times of chondrite for springwater and rock samples, respectively. The thermal (STS and TTS) and the cold (APS) springs with low pH values exhibit a very high REE contents (0.64 to 3.15 mg/l). Saturation index indicates that Fe and Al phases can control dissolved REE concentration in FTS and PF cold springs. The speciation of REE complexes indicates dominant presence of LnSO4+ and free ion in the Taftan thermal springs. In APS cold spring with pH 4, fluoride complexes are dominate over the free ion and sulfate species, while in PF and FTS cold springs with pH 6.4 and 7, respectively, carbonate complexes (LnCO3+) are predominant species. Chondrite-normalized pattern for the low-pH waters show very distinctive gull-wing patterns, characteristic feature of acid-sulfate geothermal systems, and are similar to those of the host rocks. Chemical characteristics of rare earth elements in spring and volcanic rock samples indicate that REEs are originated from the andesitic-dacitic host rocks. Whole-rock-normalized REE patterns and petrographic evidences show that rare earth elements leached mainly from marginal alteration of minerals and matrix decomposition in volcanic rocks. In chondrite-normalized REE patterns, significant negative Eu anomaly in the cold springs compare to the thermal and acidic springs indicates that alteration of plagioclase is more intense in the later, corresponding to increasing in temperature and acidic state of reactant water.

Helicon Modes Driven by Ionosheric 0+ Ions in the Plasma Sheet Region

NASA Technical Reports Server (NTRS)

Lakhina, Gurbax S.; Tsurutani, Bruce T.

1996-01-01

It is shown that the precence of ionospheric-origin oxygen ion beams with anisotropic pressure can excite helicon modes in the near-Earth plasma shet region provided their Alfvenic Mach numbers lie in a certain range.

Ion engine auxiliary propulsion applications and integration study

NASA Technical Reports Server (NTRS)

Zafran, S. (Editor)

1977-01-01

The benefits derived from application of the 8-cm mercury electron bombardment ion thruster were assessed. Two specific spacecraft missions were studied. A thruster was tested to provide additional needed information on its efflux characteristics and interactive effects. A Users Manual was then prepared describing how to integrate the thruster for auxiliary propulsion on geosynchronous satellites. By incorporating ion engines on an advanced communications mission, the weight available for added payload increases by about 82 kg (181 lb) for a 100 kg (2200 lb) satellite which otherwise uses electrothermal hydrazine. Ion engines can be integrated into a high performance propulsion module that is compatible with the multimission modular spacecraft and can be used for both geosynchronous and low earth orbit applications. The low disturbance torques introduced by the ion engines permit accurate spacecraft pointing with the payload in operation during thrusting periods. The feasibility of using the thruster's neutralizer assembly for neutralization of differentially charged spacecraft surfaces at geosynchronous altitude was demonstrated during the testing program.

The effect of the earth's and stray magnetic fields on mobile mass spectrometer systems.

PubMed

Bell, Ryan J; Davey, Nicholas G; Martinsen, Morten; Short, R Timothy; Gill, Chris G; Krogh, Erik T

2015-02-01

Development of small, field-portable mass spectrometers has enabled a rapid growth of in-field measurements on mobile platforms. In such in-field measurements, unexpected signal variability has been observed by the authors in portable ion traps with internal electron ionization. The orientation of magnetic fields (such as the Earth's) relative to the ionization electron beam trajectory can significantly alter the electron flux into a quadrupole ion trap, resulting in significant changes in the instrumental sensitivity. Instrument simulations and experiments were performed relative to the earth's magnetic field to assess the importance of (1) nonpoint-source electron sources, (2) vertical versus horizontal electron beam orientation, and (3) secondary magnetic fields created by the instrument itself. Electron lens focus effects were explored by additional simulations, and were paralleled by experiments performed with a mass spectrometer mounted on a rotating platform. Additionally, magnetically permeable metals were used to shield (1) the entire instrument from the Earth's magnetic field, and (2) the electron beam from both the Earth's and instrument's magnetic fields. Both simulation and experimental results suggest the predominant influence on directionally dependent signal variability is the result of the summation of two magnetic vectors. As such, the most effective method for reducing this effect is the shielding of the electron beam from both magnetic vectors, thus improving electron beam alignment and removing any directional dependency. The improved ionizing electron beam alignment also allows for significant improvements in overall instrument sensitivity.

Low-phonon-frequency chalcogenide crystalline hosts for rare earth lasers operating beyond three microns

DOEpatents

Payne, Stephen A.; Page, Ralph H.; Schaffers, Kathleen I.; Nostrand, Michael C.; Krupke, William F.; Schunemann, Peter G.

2000-01-01

The invention comprises a RE-doped MA.sub.2 X.sub.4 crystalline gain medium, where M includes a divalent ion such as Mg, Ca, Sr, Ba, Pb, Eu, or Yb; A is selected from trivalent ions including Al, Ga, and In; X is one of the chalcogenide ions S, Se, and Te; and RE represents the trivalent rare earth ions. The MA.sub.2 X.sub.4 gain medium can be employed in a laser oscillator or a laser amplifier. Possible pump sources include diode lasers, as well as other laser pump sources. The laser wavelengths generated are greater than 3 microns, as becomes possible because of the low phonon frequency of this host medium. The invention may be used to seed optical devices such as optical parametric oscillators and other lasers.

Interfacing broadband photonic qubits to on-chip cavity-protected rare-earth ensembles

PubMed Central

Zhong, Tian; Kindem, Jonathan M.; Rochman, Jake; Faraon, Andrei

2017-01-01

Ensembles of solid-state optical emitters enable broadband quantum storage and transduction of photonic qubits, with applications in high-rate quantum networks for secure communications and interconnecting future quantum computers. To transfer quantum states using ensembles, rephasing techniques are used to mitigate fast decoherence resulting from inhomogeneous broadening, but these techniques generally limit the bandwidth, efficiency and active times of the quantum interface. Here, we use a dense ensemble of neodymium rare-earth ions strongly coupled to a nanophotonic resonator to demonstrate a significant cavity protection effect at the single-photon level—a technique to suppress ensemble decoherence due to inhomogeneous broadening. The protected Rabi oscillations between the cavity field and the atomic super-radiant state enable ultra-fast transfer of photonic frequency qubits to the ions (∼50 GHz bandwidth) followed by retrieval with 98.7% fidelity. With the prospect of coupling to other long-lived rare-earth spin states, this technique opens the possibilities for broadband, always-ready quantum memories and fast optical-to-microwave transducers. PMID:28090078

Rationally designed mineralization for selective recovery of the rare earth elements

PubMed Central

Hatanaka, Takaaki; Matsugami, Akimasa; Nonaka, Takamasa; Takagi, Hideki; Hayashi, Fumiaki; Tani, Takao; Ishida, Nobuhiro

2017-01-01

The increasing demand for rare earth (RE) elements in advanced materials for permanent magnets, rechargeable batteries, catalysts and lamp phosphors necessitates environmentally friendly approaches for their recovery and separation. Here, we propose a mineralization concept for direct extraction of RE ions with Lamp (lanthanide ion mineralization peptide). In aqueous solution containing various metal ions, Lamp promotes the generation of RE hydroxide species with which it binds to form hydrophobic complexes that accumulate spontaneously as insoluble precipitates, even under physiological conditions (pH ∼6.0). This concept for stabilization of an insoluble lanthanide hydroxide complex with an artificial peptide also works in combination with stable scaffolds like synthetic macromolecules and proteins. Our strategy opens the possibility for selective separation of target metal elements from seawater and industrial wastewater under mild conditions without additional energy input. PMID:28548098

Site preference for luminescent activator ions in doped fluoroperovskite RbZnF3.

PubMed

Saroj, Sanjay Kumar; Nagarajan, Rajamani

2018-08-05

With the dual objective of investigating the site preferences of larger sized activator ions and to append luminescence property to the perovskite structured RbZnF 3 , doping of manganese(II), cerium(III), europium(III) and terbium(III) ions (5 mol%) was carried out. Although cubic symmetry of RbZnF 3 was preserved for all the doped samples, site preference of rare-earth ions for the A-site Rb + leading to an inverse perovskite arrangement has been noticed from careful analysis of lattice parameters from refinement of powder X-ray diffraction data. Undoped RbZnF 3 exhibited rod-like morphology in the transmission electron microscopic image. In addition to an intense band around 230 nm assignable to the charge transfer from ZnF 3 - to Rb + , typical transitions of respective dopant ions were observed in their UV-visible spectra. The doped samples showed luminescence in blue, green and red regions and time decay experiments suggested uniform dispersion of them without any clustering effect. The lower phonon energy of RbZnF 3 matrix by virtue of the presence of heavier rubidium at the A-site together with its doping with rare-earth ions resulting in an inverse perovskite like arrangement could favour their utility in various practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

Rare earth garnet selective emitter

NASA Technical Reports Server (NTRS)

Lowe, Roland A.; Chubb, Donald L.; Farmer, Serene C.; Good, Brian S.

1994-01-01

Thin film Ho-YAG and Er-YAG emitters with a platinum substrate exhibit high spectral emittance in the emission band (epsilon(sub lambda) approximately equal to 0.74, ((4)l(sub 15/2)) - ( (4)l(sub13/2)), for Er-YAG and epsilon(sub lambda) approximately equal to 0.65, ((5)l(sub 7))-((5)l(sub 8)) for Ho-YAG) at excellent candidates for high efficiency selective emitters in the thermophotovoltaics (TPV) systems operating at moderate temperatures (1200-1500K). Spectral emittance measurements of the thin films were made (1.2 less than lambda less than 3.0 microns) and compared to the theoretical emittances calculated using measured values of the spectral extinction coefficient. In this paper we present the results for a new class of rare earth ion selective emitters. These emitters are thin sections (less than 1 mm) of yttrium aluminum garnet (YAG) single crystal with a rare earth substitutional impurity. This paper presents normal spectral emittance, epsilon(sub lambda), measurements of holmium (Ho), and erbium (Er) doped YAG thin film selective emitters at 1500 K, and compares those results with the theoretical spectral emittance.

Rare-earth-doped materials with application to optical signal processing, quantum information science, and medical imaging technology

NASA Astrophysics Data System (ADS)

Cone, R. L.; Thiel, C. W.; Sun, Y.; Böttger, Thomas; Macfarlane, R. M.

2012-02-01

Unique spectroscopic properties of isolated rare earth ions in solids offer optical linewidths rivaling those of trapped single atoms and enable a variety of recent applications. We design rare-earth-doped crystals, ceramics, and fibers with persistent or transient "spectral hole" recording properties for applications including high-bandwidth optical signal processing where light and our solids replace the high-bandwidth portion of the electronics; quantum cryptography and information science including the goal of storage and recall of single photons; and medical imaging technology for the 700-900 nm therapeutic window. Ease of optically manipulating rare-earth ions in solids enables capturing complex spectral information in 105 to 108 frequency bins. Combining spatial holography and spectral hole burning provides a capability for processing high-bandwidth RF and optical signals with sub-MHz spectral resolution and bandwidths of tens to hundreds of GHz for applications including range-Doppler radar and high bandwidth RF spectral analysis. Simply stated, one can think of these crystals as holographic recording media capable of distinguishing up to 108 different colors. Ultra-narrow spectral holes also serve as a vibration-insensitive sub-kHz frequency reference for laser frequency stabilization to a part in 1013 over tens of milliseconds. The unusual properties and applications of spectral hole burning of rare earth ions in optical materials are reviewed. Experimental results on the promising Tm3+:LiNbO3 material system are presented and discussed for medical imaging applications. Finally, a new application of these materials as dynamic optical filters for laser noise suppression is discussed along with experimental demonstrations and theoretical modeling of the process.

ION INJECTION AT QUASI-PARALLEL SHOCKS SEEN BY THE CLUSTER SPACECRAFT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johlander, A.; Vaivads, A.; Khotyaintsev, Yu. V.

2016-01-20

Collisionless shocks in space plasma are known to be capable of accelerating ions to very high energies through diffusive shock acceleration (DSA). This process requires an injection of suprathermal ions, but the mechanisms producing such a suprathermal ion seed population are still not fully understood. We study acceleration of solar wind ions resulting from reflection off short large-amplitude magnetic structures (SLAMSs) in the quasi-parallel bow shock of Earth using in situ data from the four Cluster spacecraft. Nearly specularly reflected solar wind ions are observed just upstream of a SLAMS. The reflected ions are undergoing shock drift acceleration (SDA) andmore » obtain energies higher than the solar wind energy upstream of the SLAMS. Our test particle simulations show that solar wind ions with lower energy are more likely to be reflected off the SLAMS, while high-energy ions pass through the SLAMS, which is consistent with the observations. The process of SDA at SLAMSs can provide an effective way of accelerating solar wind ions to suprathermal energies. Therefore, this could be a mechanism of ion injection into DSA in astrophysical plasmas.« less

The structure of crystallographic damage in GaN formed during rare earth ion implantation with and without an ultrathin AlN capping layer

NASA Astrophysics Data System (ADS)

Gloux, F.; Ruterana, P.; Wojtowicz, T.; Lorenz, K.; Alves, E.

2006-10-01

The crystallographic nature of the damage created in GaN implanted by rare earth ions at 300 keV and room temperature has been investigated by transmission electron microscopy versus the fluence, from 7×10 13 to 2×10 16 at/cm 2, using Er, Eu or Tm ions. The density of point defect clusters was seen to increase with the fluence. From about 3×10 15 at/cm 2, a highly disordered 'nanocrystalline layer' (NL) appears on the GaN surface. Its structure exhibits a mixture of voids and misoriented nanocrystallites. Basal stacking faults (BSFs) of I 1, E and I 2 types have been noticed from the lowest fluence, they are I 1 in the majority. Their density increases and saturates when the NL is observed. Many prismatic stacking faults (PSFs) with Drum atomic configuration have been identified. The I 1 BSFs are shown to propagate easily through GaN by folding from basal to prismatic planes thanks to the PSFs. When implanting through a 10 nm AlN cap, the NL threshold goes up to about 3×10 16 at/cm 2. The AlN cap plays a protective role against the dissociation of the GaN up to the highest fluences. The flat surface after implantation and the absence of SFs in the AlN cap indicate its high resistance to the damage formation.

Electron Currents and Heating in the Ion Diffusion Region of Asymmetric Reconnection

NASA Technical Reports Server (NTRS)

Graham, D. B.; Khotyaintsev, Yu. V.; Norgren, C.; Vaivads, A.; Andre, M.; Lindqvist, P. A.; Marklund, G. T.; Ergun, R. E.; Paterson, W. R.; Gershman, D. J.;

Distribution of Nd3+ ions in oxyfluoride glass ceramics

PubMed Central

2012-01-01

It has been an open question whether Nd3+ ions are incorporated into the crystalline phase in oxyfluoride glass ceramics or not. Moreover, relative research has indicated that spectra characters display minor differences between before and after heat treatment in oxyfluoride glass compared to similar Er3+-, Yb3+-, Tm3+-, Eu3+-, etc.-doped materials. Here, we have studied the distribution of Nd3+ ions in oxyfluoride glass ceramics by X-ray diffraction quantitative analysis and found that almost none of the Nd3+ ions can be incorporated into the crystalline phase. In order to confirm the rationality of the process, the conventional mathematical calculation and energy-dispersive spectrometry line scanning are employed, which show good consistency. The distribution of Nd3+ ions in oxyfluoride glass ceramics reported here is significant for further optical investigations and applications of rare-earth doped oxyfluoride glass ceramics. PMID:22647385

Interaction of a finite-length ion beam with a background plasma - Reflected ions at the quasi-parallel bow shock

NASA Technical Reports Server (NTRS)

Onsager, T. G.; Winske, D.; Thomsen, M. F.

1991-01-01

The coupling of a finite-length, field-aligned, ion beam with a uniform background plasma is investigated using one-dimensional hybrid computer simulations. The finite-length beam is used to study the interaction between the incident solar wind and ions reflected from the earth's quasi-parallel bow shock, where the reflection process may vary with time. The coupling between the reflected ions and the solar wind is relevant to ion heating at the bow shock and possibly to the formation of hot, flow anomalies and re-formation of the shock itself. Consistent with linear theory, the waves which dominate the interaction are the electromagnetic right-hand polarized resonant and nonresonant modes. However, in addition to the instability growth rates, the length of time that the waves are in contact with the beam is also an important factor in determining which wave mode will dominate the interaction. It is found that interaction will result in strong coupling, where a significant fraction of the available free energy is converted into thermal energy in a short time, provided the beam is sufficiently dense or sufficiently long.

Photoluminescence of rare-earth ion (Eu3+, Tm3+, and Er3+)-doped and co-doped ZnNb2O6 for solar cells

NASA Astrophysics Data System (ADS)

Gao, Sen-Pei; Qian, Yan-Nan; Wang, Biao

2015-08-01

Visible converted emissions produced at an excitation of 286 nm in ZnNb2O6 ceramics doped with rare-earth ions (RE = Eu3+, Tm3+, Er3+ or a combination of these ions) were investigated with the aim of increasing the photovoltaic efficiency of solar cells. The structure of RE:ZnNb2O6 ceramics was confirmed by x-ray diffraction patterns. The undoped ZnNb2O6 could emit a blue emission under 286-nm excitation, which is attributed to the self-trapped excitons’ recombination of the efficient luminescence centers of edge-shared NbO6 groups. Upon 286-nm excitation, Eu:ZnNb2O6, Tm:ZnNb2O6, and Er:ZnNb2O6 ceramics showed blue, green, and red emissions, which correspond to the transitions of 5D0 → 7FJ (J = 1-4) (Eu3+), 1G4 → 3H6 (Tm3+), and 2H11/2/4S3/2 → 4I15/2 (Er3+), respectively. The calculated CIE chromaticity coordinates of Eu:ZnNb2O6, Tm:ZnNb2O6, and Er:ZnNb2O6 are (0.50, 0.31), (0.14, 0.19), and (0.29, 0.56), respectively. RE ion-co-doped ZnNb2O6 showed a combination of characteristic emissions. The chromaticity coordinates of Eu/Tm:ZnNb2O6, Eu/Er:ZnNb2O6, and Tm/Er:ZnNb2O6 were calculated to be (0.29, 0.24), (0.45, 0.37), and (0.17, 0.25). Project supported by the National Natural Science Foundation of China (Grant Nos. 10572155 and 10732100) and the Research Fund for the Doctoral Program of Ministry of Education, China (Grant No. 20130171130003).

Luminescence quenching versus enhancement in WO3-NaPO3 glasses doped with trivalent rare earth ions and containing silver nanoparticles

NASA Astrophysics Data System (ADS)

Dousti, M. Reza; Poirier, Gael Y.; Amjad, Raja J.; de Camargo, Andrea S. S.

2016-10-01

We report on the influence of silver nanoparticles (NPs) on the luminescence behavior of trivalent rare earth (RE) ion doped tungsten-phosphate glasses. In order to induce the growth of NPs, the as-prepared glass samples containing silver atoms, are exposed to heat-treatment above the glass transition temperature. The surface plasmon resonance band of the Ag NPs is observed in the visible range around 420 and 537 nm in the glasses with low and high tungsten content, respectively. Such difference in spectral shift of the plasmon band is attributed to the difference in the refractive index of the two studied glass compositions. Heat-treatment results in the general increase in number of NPs, while in the case of glasses with low tungsten content, it also imposes a shift to the Ag plasmon band. The NPs size distribution (4-10 nm) was determined in good agreement with the values obtained by using Mie theory and by transmission electron microscopy. The observed quenching in the visible luminescence of glasses doped with Eu3+, Tb3+ or Er3+is attributed to energy transfer from the RE ions to Ag species, while an enhanced near-infrared emission in Er3+ doped glasses is discussed in terms of the chemical contribution of silver, rather than the most commonly claimed enhancement of localized field or energy transfer from silver species to Er3+. The results are supported by the lifetime measurements. We believe that this study gives further insight and in-depth exploration of the somewhat controversial discussions on the influence of metallic NPs plasmonic effects in RE-doped glasses.

Preface to the Special Issue of Optical Materials associated with the ;Photoluminescence in Rare Earths 2016: Photonic Materials and Devices (PRE'16); Workshop

NASA Astrophysics Data System (ADS)

Jacobsohn, Luiz G.; Ballato, John

2017-06-01

Since the inaugural meeting in 2005, the Photoluminescence in Rare Earths: Photonic Materials and Devices (PRE) workshop has grown into a global forum for material scientists, chemists and physicists to discuss and debate the state of the art and future perspectives for photonic materials based on rare earth ions.

A study of the coherence length of ULF waves in the earth's foreshock

NASA Technical Reports Server (NTRS)

Le, G.; Russell, C. T.

1990-01-01

High-time-resolution magnetic-field data for different separations of ISEE 1 and 2 in the earth's ion foreshock region are examined to study the coherence length of upstream ULF waves. Examining the correlation coefficients of the low-frequency waves as a function of separation distance shows that the correlation coefficient depends mainly on the separation distance of ISEE 1 and 2 transverse to the solar-wind flow. It drops to about 0.5 when the transverse separation is about 1 earth radius, a distance much larger than the proton thermal gyroradius in the solar wind. Thus the coherence length of the low-frequency waves is about one earth radius, which is of the order of the wavelength, and is consistent with that estimated from the bandwidth of the waves.

Magnetic holes in the dipolarized magnetotail: ion and electron anisotropies

NASA Astrophysics Data System (ADS)

Shustov, P.; Artemyev, A.; Zhang, X. J.; Yushkov, E.; Petrukovich, A. A.

2017-12-01

We conduct statistics on magnetic holes observed by THEMIS spacecraft in the near-Earth magnetotail. Groups of holes are detected after dipolarizations in the quiet, equatorial plasma sheet. Magnetic holes are characterized by significant magnetic field depressions (up to 50%) and strong electron currents ( 10-50 nA/m2), with spatial scales much smaller than the ion gyroradius. These magnetic holes are populated by hot (>10 keV), transversely anisotropic electrons supporting the pressure balance. We present statistical properties of these sub-ion scale magnetic holes and discuss possible mechanisms on the hole formation.

Ion-Scale Wave Properties and Enhanced Ion Heating Across the Low-Latitude Boundary Layer During Kelvin-Helmholtz Instability

NASA Astrophysics Data System (ADS)

Moore, T. W.; Nykyri, K.; Dimmock, A. P.

2017-11-01

In the Earth's magnetosphere, the magnetotail plasma sheet ions are much hotter than in the shocked solar wind. On the dawn sector, the cold-component ions are more abundant and hotter by 30-40% when compared to the dusk sector. Recent statistical studies of the flank magnetopause and magnetosheath have shown that the level of temperature asymmetry of the magnetosheath is unable to account for this, so additional physical mechanisms must be at play, either at the magnetopause or plasma sheet that contributes to this asymmetry. In this study, we perform a statistical analysis on the ion-scale wave properties in the three main plasma regimes common to flank magnetopause boundary crossings when the boundary is unstable to Kelvin-Helmholtz instability (KHI): hot and tenuous magnetospheric, cold and dense magnetosheath, and mixed (Hasegawa et al., 2004). These statistics of ion-scale wave properties are compared to observations of fast magnetosonic wave modes that have recently been linked to Kelvin-Helmholtz (KH) vortex centered ion heating (Moore et al., 2016). The statistical analysis shows that during KH events there is enhanced nonadiabatic heating calculated during ion scale wave intervals when compared to non-KH events. This suggests that during KH events there is more free energy for ion-scale wave generation, which in turn can heat ions more effectively when compared to cases when KH waves are absent. This may contribute to the dawn favored temperature asymmetry of the plasma sheet; recent studies suggest KH waves favor the dawn flank during Parker-Spiral interplanetary magnetic field.

Resonance electronic Raman scattering in rare earth crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, G.M.

1988-11-10

The intensities of Raman scattering transitions between electronic energy levels of trivalent rare earth ions doped into transparent crystals were measured and compared to theory. A particle emphasis was placed on the examination of the effect of intermediate state resonances on the Raman scattering intensities. Two specific systems were studied: Ce/sup 3 +/(4f/sup 1/) in single crystals of LuPO/sub 4/ and Er/sup 3 +/(4f/sup 11/) in single crystals of ErPO/sub 4/. 134 refs., 92 figs., 33 tabs.

A divalent rare earth oxide semiconductor: Yttrium monoxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaminaga, Kenichi; Sei, Ryosuke; Department of Chemistry, Tohoku University, Sendai 980-8578

Rare earth oxides are usually widegap insulators like Y{sub 2}O{sub 3} with closed shell trivalent rare earth ions. In this study, solid phase rock salt structure yttrium monoxide, YO, with unusual valence of Y{sup 2+} (4d{sup 1}) was synthesized in a form of epitaxial thin film by pulsed laser deposition method. YO has been recognized as gaseous phase in previous studies. In contrast with Y{sub 2}O{sub 3}, YO was dark-brown colored and narrow gap semiconductor. The tunable electrical conductivity ranging from 10{sup −1} to 10{sup 3} Ω{sup −1 }cm{sup −1} was attributed to the presence of oxygen vacancies serving as electron donor.more » Weak antilocalization behavior observed in magnetoresistance indicated significant role of spin-orbit coupling as a manifestation of 4d electron carrier.« less

Elements and inorganic ions as source tracers in recent Greenland snow

NASA Astrophysics Data System (ADS)

Lai, Alexandra M.; Shafer, Martin M.; Dibb, Jack E.; Polashenski, Chris M.; Schauer, James J.

2017-09-01

Atmospheric transport of aerosols leads to deposition of impurities in snow, even in areas of the Arctic as remote as Greenland. Major ions (e.g. Na+, Ca2+, NH4+, K+, SO42-) are frequently used as tracers for common aerosol sources (e.g. sea spray, dust, biomass burning, anthropogenic emissions). Trace element data can supplement tracer ion data by providing additional information about sources. Although many studies have considered either trace elements or major ions, few have reported both. This study determined total and water-soluble concentrations of 31 elements (Al, As, Ca, Cd, Ce, Co, Cr, Dy, Eu, Fe, Gd, K, La, Mg, Mn, Na, Nb, Nd, Pb, Pr, S, Sb, Si, Sm, Sn, Sr, Ti, V, U, Y, Zn) in shallow snow pits at 22 sampling sites in Greenland, along a transect from Summit Station to sites in the northwest. Black carbon (BC) and inorganic ions were measured in colocated samples. Sodium, which is typically used as a tracer of sea spray, did not appear to have any non-marine sources. The rare earth elements, alkaline earth elements (Mg, Ca, Sr), and other crustal elements (Fe, Si, Ti, V) were not enriched above crustal abundances relative to Al, indicating that these elements are primarily dust sourced. Calculated ratios of non-sea salt Ca (nssCa) to estimated dust mass affirm the use of nssCa as a dust tracer, but suggest up to 50% uncertainty in that estimate in the absence of other crustal element data. Crustal enrichment factors indicated that As, Cd, Pb, non-sea-salt S, Sb, Sn, and Zn were enriched in these samples, likely by anthropogenic sources. Principal component analysis indicated more than one crustal factor, and a variety of factors related to anthropogenically enriched elements. Analysis of trace elements alongside major tracer ions does not change interpretation of ion-based source attribution for sources that are well-characterized by ions, but is valuable for assessing uncertainty in source attribution and identifying sources not represented by major ions.

Solvent Extraction of Rare Earth Elements from a Nitric Acid Leach Solution of Apatite by Mixtures of Tributyl Phosphate and Di-(2-ethylhexyl) Phosphoric Acid

NASA Astrophysics Data System (ADS)

Ferdowsi, Ali; Yoozbashizadeh, Hossein

2017-12-01

Solvent extraction of rare earths from nitrate leach liquor of apatite using mixtures of tributyl phosphate (TBP) and di-(2-ethylhexyl) phosphoric acid (D2EHPA) was studied. The effects of nitrate and hydrogen ion concentration of the aqueous phase as well as the composition and concentration of extractants in the organic phase on the extraction behavior of lanthanum, cerium, neodymium, and yttrium were investigated. The distribution ratio of REEs increases by increasing the nitrate concentration in aqueous phase and concentration of extractants in organic phase, but the hydrogen ion concentration in aqueous phase has a decreasing effect. Yttrium as a heavy rare earth is more sensitive to these parameters than light rare earth elements. Although the composition of organic phase has a minor effect on the extraction of light rare earths, the percent of extraction of yttrium decreases dramatically by increasing the TBP content of organic phase. Mixtures of TBP and D2EHPA can show either synergism or antagonism extraction depending on the concentration and composition of extractants in organic phase. The best condition for separating rare earth elements in groups of heavy and light REEs can be achieved at high nitrate concentration, low H+ concentration, and high concentration of D2EHPA in organic phase. Separation of Ce and La by TBP and D2EHPA is practically impossible in the studied conditions; however, low nitrate concentration and high hydrogen ion concentration in aqueous phase and low concentration of extractants in organic phase favor the separation of Nd from other light rare earth elements.

Relative abundance of heavy ions in the inner zone of the radiation belts of the earth

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panasyuk, M.I.

1986-03-01

The energy dependences of the relative abundances of energetic (E > 1 MeV/nucleon) H, He, and O ions in the radiation belts are analyzed on the basis of experimental results obtained from measurement of their spectral characteristics on several satellites: Molniya-2, Kosmos-900, Prognoz-5, Explorer-45, ISEE-1, and OV1-19. It is shown that the formation of the energy dependence of He/H and O/H can be explained with a model providing for ion diffusion into the interior of the radiation belts with Coulomb losses taken into account under thecondition that the total-energy spectra at the boundary are more rigid for the heavy ionsmore » and are determined by such parameters of the quiet solar wind as the relative concentrations of the individual ion components and their charge states. It is shown that the fluxes of O and Fe ions with E > 1 MeV/nucleon measured on the orbital stations Salyut-6 and Skylab have an energy dependence of the relative abundances not inconsistent with above-noted mechanism for the formation of energetic ions of the inner radiation belt.« less

Formation of vortices in the presence of sheared electron flows in the earth's ionosphere

NASA Astrophysics Data System (ADS)

Farid, T.; Shukla, P. K.; Sakanaka, P. H.; Mirza, A. M.

2000-12-01

It is shown that sheared electron flows can generate long as well as short wavelength (in comparison with the ion gyroradius) electrostatic waves in a nonuniform magnetplasma. For this purpose, we derive dispersion relations by employing two-fluid and hybrid models; in the two-fluid model the dynamics of both the electrons and ions are governed by the hydrodynamic equations and the guiding center fluid drifts, whereas the hybrid model assumes kinetic ions and fluid electrons. Explicit expressions for the growth rates and thresholds are presented. Linearly excited waves attain finite amplitudes and start interacting among themselves. The interaction is governed by the nonlinear equations containing the Jacobian nonlinearities. Stationary solutions of the nonlinear mode coupling equations can be represented in the form of a dipolar vortex and a vortex street. Conditions under which the latter arise are given. Numerical results for the growth rates of linearly excited modes as well as for various types of vortices are displayed for the parameters that are relevant for the F-region of the Earth's ionosphere. It is suggested that the results of the present investigation are useful in understanding the properties of nonthermal electrostatic waves and associated nonlinear vortex structures in the Earth's ionosphere.

Extended X-ray Absorption Fine Structure (EXAFS) Analysis of Vitreous Rare Earth Sodium Phosphates

NASA Astrophysics Data System (ADS)

Yoo, Changhyeon; Marasinghe, Kanishka; Segre, Carlo; Shibata, Tomohiro

2015-03-01

The local structure around rare-earth ions (RE3+) in rare-earth ultraphosphate (REUP) glasses has been studied using RE LIII edge (RE = Nd, Er, Dy, and Eu) and K edge (RE = Nd, Pr, Dy, and Eu) extended X-ray absorption fine structure (EXAFS) spectroscopy. (RE2O3)x (Na2O)y(P2O5) 1 - x - y glasses in the compositional range 0 <= x <= 0.14 and x + y = 0.3 and 0.4 were studied. RE-oxygen (RE-O) coordination number decreases from ~ 10 to ~ 7.5 with increasing RE-content for Nd, Pr, Eu, and Dy. For Er, RE-O coordination number increases from ~ 8.7 to ~ 10 with increasing RE-content. For the first oxygen shell, the RE-O distance ranges between 2.41-2.43 Å, 2.44-2.46 Å, 2.24-2.26 Å, 2.28-2.32 Å, and 2.32-2.36 Å for Nd, Pr, Er, Dy, and EU glasses, respectively. Second shell around RE ions consists of phosphorus atoms, with RE-P distance about 3.0-3.5 Å and coordination number ranging from 1 to 3. The third shell primarily contains oxygen and is at a distance about 4.0-4.1 Å from RE ions.

Planetary Protection Progress of Hayabusa2 and Its Piggyback PROCYON: Launch, Earth Swingby and Outbound Cruising Phases

NASA Astrophysics Data System (ADS)

Yano, Hajime; Yoshikawa, Makoto; Sarli, Bruno; Ozaki, Naoya; Funase, Ryu; Tsuda, Yuichi; Chujo, Toshihiro; Ariu, Kaito

2016-07-01

Hayabusa-2 is Japan's second asteroid sample return mission which was successfully launched into the planned Earth departure trajectory with the H-IIA rocket on December 3rd, 2014, together with a group of its interplanetary piggyback micro- spacecraft, including the PROCYON(Proximate Object Close flYby with Optical Navigation)spacecraft, the world's first 50 kg-class deep space micro-spacecraft developed by the University of Tokyo and the Japan Aerospace Exploration Agency. The Hayabusa-2 spacecraft will go to Rug, a C-type NEO, and attempt surface investigations with daughter rovers (MINERVA-II series and MASCOT), artificial impact cratering experiment (SCI) and both surface and sub-surface sampling (Sampler) in 2018-2019 and plans to return to the Earth in December 2020. The PROCYON mission objective was to demonstrate a micro-spacecraft bus technology for deep space exploration and proximity flyby to asteroids performing optical measurements. Both of the above missions were fully evaluated by the COSPAR Planetary Protection Panel at the dedicated COSPAR colloquium and scientific assembly in 2014 and the COSPAR PPP has endorsed the Category-2 for their outbound trajectories and the non-restricted Earth return for the inbound trajectory of Hayabusa-2. As a part of the fulfillments of the Category-2 classification, both spacecraft must be compliant with the COSPAR PPP requirements of non-impact probability to Mars since they would have enough energy to reach and beyond the orbit of Mars, due to the Earth swing-by and ion engine operations for their outbound cruising. As for the Hayabusa-2 spacecraft, it successfully performed its Earth gravity assist in December 2015, resulting on accurate orbit determination for the post-swing-by orbit to be ready to restart the ion engine operation. Thus the non-impact probability to Mars did not change from the estimate given by Chujo, et al. (2015). As for the PROCYON spacecraft after the completion of the bus system

Low pressure ion chromatography with a low cost paired emitter-detector diode based detector for the determination of alkaline earth metals in water samples.

PubMed

Barron, Leon; Nesterenko, Pavel N; Diamond, Dermot; O'Toole, Martina; Lau, King Tong; Paull, Brett

2006-09-01

The use of a low pressure ion chromatograph based upon short (25 mm x 4.6 mm) surfactant coated monolithic columns and a low cost paired emitter-detector diode (PEDD) based detector, for the determination of alkaline earth metals in aqueous matrices is presented. The system was applied to the separation of magnesium, calcium, strontium and barium in less than 7min using a 0.15M KCl mobile phase at pH 3, with post-column reaction detection at 570 nm using o-cresolphthalein complexone. A comparison of the performance of the PEDD detector with a standard laboratory absorbance detector is shown, with limits of detection for magnesium and calcium using the low cost PEDD detector equal to 0.16 and 0.23 mg L(-1), respectively. Finally, the developed system was used for the determination of calcium and magnesium in a commercial spring water sample.

Dissipation Mechanisms and Particle Acceleration at the Earth's Bow Shock

NASA Astrophysics Data System (ADS)

Desai, M. I.; Burch, J. L.; Broll, J. M.; Genestreti, K.; Torbert, R. B.; Ergun, R.; Wei, H.; Giles, B. L.; Russell, C. T.; Phan, T.; Chen, L. J.; Lai, H.; Wang, S.; Schwartz, S. J.; Allen, R. C.; Mauk, B.; Gingell, I.

2017-12-01

NASA's Magnetospheric Multiscale (MMS) mission has four spacecraft equipped with identical state-of-the-art instruments that acquire magnetic and electric field, plasma wave, and particle data at unprecedented temporal resolution to study the fundamental physics of magnetic reconnection in the Earth's magnetosphere. During Phase 1a, MMS also encountered and crossed the Earth's bow shock more than 300 times. We use burst data during 2 bow shock crossings to shed new light on key open questions regarding the formation, evolution, and dissipation mechanisms at collisionless shocks. Specifically, we focus on two events that exhibit clear differences in the ion and electron properties, the associated wave activity, and, therefore in the nature of the dissipation. In the case of a quasi-perpendicular, low beta shock crossing, we find that the dissipation processes are most likely associated with field-aligned electron beams that are coincident with high frequency electrostatic waves. On the other hand, the dissipation processes at an oblique, high beta shock crossing are largely governed by the quasi-static electric field and generation of magnetosonic whistler waves that result in perpendicular temperature anisotropy for the electrons. We also discuss the implications of these results for ion heating, reflection, and particle acceleration.

THOR Ion Mass Spectrometer (IMS)

NASA Astrophysics Data System (ADS)

Retinò, Alessandro

2017-04-01

Turbulence Heating ObserveR (THOR) is the first mission ever flown in space dedicated to plasma turbulence. The Ion Mass Spectrometer (IMS) onboard THOR will provide the first high-time resolution measurements of mass-resolved ions in near-Earth space, focusing on hot ions in the foreshock, shock and magnetosheath turbulent regions. These measurements are required to study how kinetic-scale turbulent fluctuations heat and accelerate different ion species. IMS will measure the full three-dimensional distribution functions of main ion species (H+, He++, O+) in the energy range 10 eV/q to 30 keV/q with energy resolution DE/E down to 10% and angular resolution down to 11.25˚ . The time resolution will be 150 ms for O+, 300 ms for He++ and ˜ 1s for O+, which correspond to ion scales in the the foreshock, shock and magnetosheath regions. Such high time resolution is achieved by mounting four identical IMS units phased by 90˚ in the spacecraft spin plane. Each IMS unit combines a top-hat electrostatic analyzer with deflectors at the entrance together with a time-of-flight section to perform mass selection. Adequate mass-per-charge resolution (M/q)/(ΔM/q) (≥ 8 for He++ and ≥ 3 for O+) is obtained through a 6 cm long Time-of-Flight (TOF) section. IMS electronics includes a fast sweeping high voltage board that is required to make measurements at high cadence. Ion detection includes Micro Channel Plates (MCPs) combined with Application-Specific Integrated Circuits (ASICs) for charge amplification and discrimination and a discrete Time-to-Amplitude Converter (TAC) to determine the ion time of flight. A processor board will be used to for ion events formatting and will interface with the Particle Processing Unit (PPU), which will perform data processing for THOR particle detectors. The IMS instrument is being designed and will be built and calibrated by an international consortium of scientific institutes from France, USA, Germany and Japan and Switzerland.

Advanced ion thruster and electrochemical launcher research

NASA Technical Reports Server (NTRS)

Wilbur, P. J.

1983-01-01

The theoretical model of orificed hollow cathode operation predicted experimentally observed cathode performance with reasonable accuracy. The deflection and divergence characteristics of ion beamlets emanating from a two grid optics system as a function of the relative offset of screen and accel grids hole axes were described. Ion currents associated with discharge chamber operation were controlled to improve ion thruster performance markedly. Limitations imposed by basic physical laws on reductions in screen grid hole size and grid spacing for ion optics systems were described. The influence of stray magnetic fields in the vicinity of a neutralizer on the performance of that neutralizer was demonstrated. The ion current density extracted from a thruster was enhanced by injecting electrons into the region between its ion accelerating grids. Theoretical analysis of the electrothermal ramjet concept of launching space bound payloads at high acceleration levels is described. The operation of this system is broken down into two phases. In the light gas gun phase the payload is accelerated to the velocity at which the ramjet phase can commence. Preliminary models of operation are examined and shown to yield overall energy efficiences for a typical Earth escape launch of 60 to 70%. When shock losses are incorporated these efficiencies are still observed to remain at the relatively high values of 40 to 50%.

A 3.8-V earth-abundant sodium battery electrode

PubMed Central

Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi; Chung, Sai-Cheong; Yamada, Atsuo

2014-01-01

Rechargeable lithium batteries have ushered the wireless revolution over last two decades and are now matured to enable green automobiles. However, the growing concern on scarcity and large-scale applications of lithium resources have steered effort to realize sustainable sodium-ion batteries, Na and Fe being abundant and low-cost charge carrier and redox centre, respectively. However, their performance is limited owing to low operating voltage and sluggish kinetics. Here we report a hitherto-unknown material with entirely new composition and structure with the first alluaudite-type sulphate framework, Na2Fe2(SO4)3, registering the highest-ever Fe3+/Fe2+ redox potential at 3.8 V (versus Na, and hence 4.1 V versus Li) along with fast rate kinetics. Rare-metal-free Na-ion rechargeable battery system compatible with the present Li-ion battery is now in realistic scope without sacrificing high energy density and high power, and paves way for discovery of new earth-abundant sustainable cathodes for large-scale batteries. PMID:25030272

Evidence of dilute ferromagnetism in rare-earth doped yttrium aluminium garnet

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farr, Warrick G.; Goryachev, Maxim; Le Floch, Jean-Michel

This work demonstrates strong coupling regime between an erbium ion spin ensemble and microwave hybrid cavity-whispering gallery modes in a yttrium aluminium garnet dielectric crystal. Coupling strengths of 220 MHz and mode quality factors in excess of 10{sup 6} are demonstrated. Moreover, the magnetic response of high-Q modes demonstrates behaviour which is unusual for paramagnetic systems. This behaviour includes hysteresis and memory effects. Such qualitative change of the system's magnetic field response is interpreted as a phase transition of rare earth ion impurities. This phenomenon is similar to the phenomenon of dilute ferromagnetism in semiconductors. The clear temperature dependence of themore » phenomenon is demonstrated.« less

An embedding structure of the cross-tail CSs and its relation to the ion composition according to MAVEN observations in the Martian magnetotai

NASA Astrophysics Data System (ADS)

Grigorenko, E. E.; Shuvalov, S. D.; Malova, H. V.; Zelenyi, L. M.

2017-12-01

The multilayered (embedded) Current Sheets (CS) are often observed in the Earth's magnetotail. Simulations based on quasi-adiabatic dynamics of different ion components showed that the observed embedding structures can be reconstructed by taking into account the net electric currents carried by ions with different masses and, thus, with different gyroradii. The last determines the spatial scales of the corresponding current layers. The embedding can be quantitatively described by the ratio of the magnetic field value at the edges of a thin embedded layer Bext to the value of the magnetic field outside a thick CS, B0. For the Earth's magnetotail it was shown that there is a relation between the Bext/B0 and the relative densities of heavy and light ion components. In the Martian magnetotail the embedding feature is also often observed in the cross-tail CS formed by the draping of the IMF field lines. The analysis of 100 CS crossings by MAVEN spacecraft showed that in the Martian magnetotail the relation between the embedding characteristics and ion composition is similar to the one observed in the Earth's magnetotail and the spatial scales of the embedded layers are defined by the gyroradii of the current carrying ion component.

Alkaline earth-based coordination polymers derived from a cyclotriphosphazene-functionalized hexacarboxylate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ling, Yajing; Bai, Dongjie; Feng, Yunlong

Combination of hexakis(4-carboxylatephenoxy)cyclotriphosphazene with alkaline earth ions of increasing ionic radii (Mg{sup 2+}, Ca{sup 2+} and Ba{sup 2+}) under different solvothermal conditions yielded three new coordination polymers, and their crystal structures were determined by single-crystal X-ray diffraction analysis. The magnesium compound displays a three dimensional (3D) network structure constructed from the deprotonated ligand and the secondary building block Mg(COO){sub 4}, which can be rationalized as a (4,6)-connected topological net with the Schläfli symbol of (4{sup 4}·6{sup 2}){sub 3}(4{sup 9}·6{sup 6}){sub 2}. The calcium compound consists of 1D infinite “Ca-O” inorganic chains connected by the deprotonated ligands to from a 3Dmore » framework. The barium compound exhibits a 3D framework in which 1D “Ba-O” inorganic chains are connected together by the deprotonated organic linkers. Due to the semi-rigid nature, the ligand adopts distinctly different conformations in the three compounds. The metal ions’ influence exerted on the final structure of the resulting coordination polymers is also discussed. When the radii of alkaline earth ions increases descending down the group from Mg(II) to Ba(II), the coordination number becomes larger and more versatile: from 6 in the magnesium compound, to 6,7 and 10 in the calcium compound, and to 8 and 9 in the barium compound, thus substantially influencing the resulting final framework structures. Also, the photophysical properties were investigated systematically, revealing that the three compounds are photoluminscent in the solid state at room temperature. This work demonstrates that although the multiplicity of conformation in the hexacarboxylate ligand based on the inorganic scaffold cyclotriphosphazene makes it difficult to predict how this ligand will form extended network, but provides unique opportunities for the formation of diverse inorganic-organic hybrids exhibiting rich structural

Investigation of the magnetic properties in double perovskite R2CoMnO6 single crystals (R  =  rare earth: La to Lu).

PubMed

Kim, M K; Moon, J Y; Choi, H Y; Oh, S H; Lee, N; Choi, Y J

2015-10-28

We have successfully synthesized the series of the double-perovskite R2CoMnO6 (R  =  rare earth: La to Lu) single crystals and have investigated their magnetic properties. The ferromagnetic order of Co(2+)/Mn(4+) spins emerges mainly along the c axis. Upon decreasing the size of rare earth ion, the magnetic transition temperature decreases linearly from 204 K for La2CoMnO6 to 48 K for Lu2CoMnO6, along with the enhancement of monoclinic distortion. The temperature and magnetic-field dependences of magnetization reveal the various magnetic characteristics such as the metamagnetic transition in R  =  Eu, the isotropic nature of rare earth moment in R  =  Gd, and the reversal of magnetic anisotropy in R  =  Tb and Dy. Our results offer comprehensive information for understanding the roles of mixed-valent magnetic ions and rare earth magnetic moments on the magnetic properties.

Earth: Earth Science and Health

NASA Technical Reports Server (NTRS)

Maynard, Nancy G.

2001-01-01

A major new NASA initiative on environmental change and health has been established to promote the application of Earth science remote sensing data, information, observations, and technologies to issues of human health. NASA's Earth Sciences suite of Earth observing instruments are now providing improved observations science, data, and advanced technologies about the Earth's land, atmosphere, and oceans. These new space-based resources are being combined with other agency and university resources, data integration and fusion technologies, geographic information systems (GIS), and the spectrum of tools available from the public health community, making it possible to better understand how the environment and climate are linked to specific diseases, to improve outbreak prediction, and to minimize disease risk. This presentation is an overview of NASA's tools, capabilities, and research advances in this initiative.

Uncoupling metallonuclease metal ion binding sites via nudge mutagenesis.

PubMed

Papadakos, Grigorios A; Nastri, Horacio; Riggs, Paul; Dupureur, Cynthia M

2007-05-01

The hydrolysis of phosphodiester bonds by nucleases is critical to nucleic acid processing. Many nucleases utilize metal ion cofactors, and for a number of these enzymes two active-site metal ions have been detected. Testing proposed mechanistic roles for individual bound metal ions has been hampered by the similarity between the sites and cooperative behavior. In the homodimeric PvuII restriction endonuclease, the metal ion dependence of DNA binding is sigmoidal and consistent with two classes of coupled metal ion binding sites. We reasoned that a conservative active-site mutation would perturb the ligand field sufficiently to observe the titration of individual metal ion binding sites without significantly disturbing enzyme function. Indeed, mutation of a Tyr residue 5.5 A from both metal ions in the enzyme-substrate crystal structure (Y94F) renders the metal ion dependence of DNA binding biphasic: two classes of metal ion binding sites become distinct in the presence of DNA. The perturbation in metal ion coordination is supported by 1H-15N heteronuclear single quantum coherence spectra of enzyme-Ca(II) and enzyme-Ca(II)-DNA complexes. Metal ion binding by free Y94F is basically unperturbed: through multiple experiments with different metal ions, the data are consistent with two alkaline earth metal ion binding sites per subunit of low millimolar affinity, behavior which is very similar to that of the wild type. The results presented here indicate a role for the hydroxyl group of Tyr94 in the coupling of metal ion binding sites in the presence of DNA. Its removal causes the affinities for the two metal ion binding sites to be resolved in the presence of substrate. Such tuning of metal ion affinities will be invaluable to efforts to ascertain the contributions of individual bound metal ions to metallonuclease function.

Transport, charge exchange and loss of energetic heavy ions in the earth's radiation belts - Applicability and limitations of theory

NASA Technical Reports Server (NTRS)

Spjeldvik, W. N.

1981-01-01

Computer simulations of processes which control the relative abundances of ions in the trapping regions of geospace are compared with observations from discriminating ion detectors. Energy losses due to Coulomb collisions between ions and exospheric neutrals are considered, along with charge exchange losses and internal charge exchanges. The time evolution of energetic ion fluxes of equatorially mirroring ions under radial diffusion is modelled to include geomagnetic and geoelectric fluctutations. Limits to the validity of diffusion transport theory are discussed, and the simulation is noted to contain provisions for six ionic charge states and the source effect on the radiation belt oxygen ion distributions. Comparisons are made with ion flux data gathered on Explorer 45 and ISEE-1 spacecraft and results indicate that internal charge exchanges cause the radiation belt ion charge state to be independent of source charge rate characteristics, and relative charge state distribution is independent of the radially diffusive transport rate below the charge state redistribution zone.

The interplay of long-range magnetic order and single-ion anisotropy in rare earth nickel germanides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Islam, Z.

1999-05-10

This dissertation is concerned with the interplay of long-range order and anisotropy in the tetragonal RNi{sub 2}Ge{sub 2} (R = rare earth) family of compounds. Microscopic magnetic structures were studied using both neutron and x-ray resonant exchange scattering (XRES) techniques. The magnetic structures of Tb, Dy, Eu and Gd members have been determined using high-quality single-crystal samples. This work has correlated a strong Fermi surface nesting to the magnetic ordering in the RNi{sub 2}Ge{sub 2} compounds. Generalized susceptibility, {chi}{sub 0}(q), calculations found nesting to be responsible for both incommensurate ordering wave vector in GdNi{sub 2}Ge{sub 2}, and the commensurate structuremore » in EuNi{sub 2}Ge{sub 2}. A continuous transition from incommensurate to commensurate magnetic structures via band filling is predicted. The surprisingly higher T{sub N} in EuNi{sub 2}Ge{sub 2} than that in GdNi{sub 2}Ge{sub 2} is also explained. Next, all the metamagnetic phases in TbNi{sub 2}Ge{sub 2} with an applied field along the c axis have been characterized with neutron diffraction measurements. A mixed phase model for the first metamagnetic structure consisting of fully-saturated as well as reduced-moment Tb ions is presented. The moment reduction may be due to moment instability which is possible if the exchange is comparable to the low-lying CEF level splitting and the ground state is a singlet. In such a case, certain Tb sites may experience a local field below the critical value needed to reach saturation.« less

Static magnetic susceptibility, crystal field and exchange interactions in rare earth titanate pyrochlores.

PubMed

Malkin, B Z; Lummen, T T A; van Loosdrecht, P H M; Dhalenne, G; Zakirov, A R

2010-07-14

The experimental temperature dependence (T = 2-300 K) of single crystal bulk and site susceptibilities of rare earth titanate pyrochlores R(2)Ti(2)O(7) (R = Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) is analyzed in the framework of crystal field theory and a mean field approximation. Analytical expressions for the site and bulk susceptibilities of the pyrochlore lattice are derived taking into account long range dipole-dipole interactions and anisotropic exchange interactions between the nearest neighbor rare earth ions. The sets of crystal field parameters and anisotropic exchange coupling constants have been determined and their variations along the lanthanide series are discussed.

White emission materials from glass doped with rare Earth ions: A review

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yasaka, P.; Kaewkhao, J., E-mail: mink110@hotmail.com; Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University, 73000

2016-03-11

Solid State Lighting (SSL) based devices are predicted to play a crucial role in the coming years. Development of W-LED, which have an edge over traditional lighting sources due to their compact size, higher reliability, shock resistance, interesting design possibilities, higher transparency and an extremely long lifetime. Over the fifteen trivalent lanthanide ions, Dy{sup 3+} ions doped glasses are most appropriate for white light generation because of the fact that it exhibits two intense emission bands corresponds to the {sup 4}F{sub 9/2}→{sup 6}H{sub 15/2} (magnetic dipole) and {sup 4}F{sub 9/2}→{sup 6}H{sub 13/2} (electric dipole) transitions at around 480-500 nm and 580-600 nmmore » pertaining to blue and yellow regions respectively. In this work, the developments of Dy3+ doped in several glass structures for white emitting materials application have reviewed. Properties of Dy{sup 3+} doped in glasses were discussed for use as a solid state lighting materials application.« less

Ion specific effects: decoupling ion-ion and ion-water interactions

PubMed Central

Song, Jinsuk; Kang, Tae Hui; Kim, Mahn Won; Han, Songi

2015-01-01

Ion-specific effects in aqueous solution, known as the Hofmeister effect is prevalent in diverse systems ranging from pure ionic to complex protein solutions. The objective of this paper is to explicitly demonstrate how complex ion-ion and ion-water interactions manifest themselves in the Hofmeister effects, based on a series of recent experimental observation. These effects are not considered in the classical description of ion effects, such as the Deryaguin-Landau-Verwey-Overbeek (DLVO) theory that, likely for that reason, fail to describe the origin of the phenomenological Hofmeister effect. However, given that models considering the basic forces of electrostatic and van der Waals interactions can offer rationalization for the core experimental observations, a universal interaction model stands a chance to be developed. In this perspective, we separately derive the contribution from ion-ion electrostatic interaction and ion-water interaction from second harmonic generation (SHG) data at the air-ion solution interface, which yields an estimate of ion-water interactions in solution. Hofmeister ion effects observed on biological solutes in solution should be similarly influenced by contributions from ion-ion and ion-water interactions, where the same ion-water interaction parameters derived from SHG data at the air-ion solution interface could be applicable. A key experimental data set available from solution systems to probe ion-water interaction is the modulation of water diffusion dynamics near ions in bulk ion solution, as well as near biological liposome surfaces. It is obtained from Overhauser dynamic nuclear polarization (ODNP), a nuclear magnetic resonance (NMR) relaxometry technique. The surface water diffusivity is influenced by the contribution from ion-water interactions, both from localized surface charges and adsorbed ions, although the relative contribution of the former is larger on liposome surfaces. In this perspective, ion-water interaction

Interactions of microorganisms with rare earth ions and their utilization for separation and environmental technology.

PubMed

Moriwaki, Hiroshi; Yamamoto, Hiroki

2013-01-01

In recent years, rare earth elements (REEs) have been widely used in various modern technological devices and the global demand for REE has been increasing. The increased demand for REEs has led to environmental exposure or water pollution from rare earth metal mines and various commercial products. Therefore, the development of a safe technology for the separation and adsorption of REEs is very important from the perspective of green chemistry and environmental pollution. In this review, the application and mechanisms of microorganisms for the removal and extraction of REEs from aqueous solutions are described. In addition, the advantages in using microorganisms for REE adsorption and future studies on this topic are discussed.

Measurement of the electron beam mode in earth's foreshock

NASA Technical Reports Server (NTRS)

Onsager, T. G.; Holzworth, R. H.

1990-01-01

High frequency electric field measurements from the AMPTE IRM plasma wave receiver are used to identify three simultaneously excited electrostatic wave modes in the earth's foreshock region: the electron beam mode, the Langmuir mode, and the ion acoustic mode. A technique is developed which allows the rest frame frequecy and wave number of the electron beam waves to be determined. It is shown that the experimentally determined rest frame frequency and wave number agree well with the most unstable frequency and wave number predicted by linear homogeneous Vlasov theory for a plasma with Maxwellian background electrons and a Lorentzian electron beam. From a comparison of the experimentally determined and theoretical values, approximate limits are put on the electron foreshock beam temperatures. A possible generation mechanism for ion acoustic waves involving mode coupling between the electron beam and Langmuir modes is also discussed.

Dynamic ion-ion and water-ion interactions in ion channels.

PubMed Central

Wu, J V

1992-01-01

The dynamic interactions among ions and water molecules in ion channels are treated based on an assumption that ions at binding sites can be knocked off by both transient entering ions and local water molecules. The theory, when applied to a single-site model K+ channel, provides solutions for super- and subsaturations, flux-ratio exponent (n') greater than 1, osmotic streaming current, activity-dependent reversal potentials, and anomalous mole-fraction behavior. The analysis predicts that: (a) the saturation may but, in general, does not follow the Michaelis-Menten relation; (b) streaming current results from imbalanced water-ion knock-off interactions; (c) n' greater than 1 even for single-site channels, but it is unlikely to exceed 1.4 unless the pore is occupied by one or more ion(s); (d) in the calculation involving two permeant ion species with similar radii, the heavier ions show higher affinity; the ion-ion knock-off dissociation from the site is more effective when two interacting ions are identical. Therefore, the "multi-ion behaviors" found in most ion channels are the consequences of dynamic ion-ion and water-ion interactions. The presence of these interactions does not require two or more binding sites in channels. PMID:1376158

High-Power, High-Thrust Ion Thruster (HPHTion)

NASA Technical Reports Server (NTRS)

Peterson, Peter Y.

2015-01-01

Advances in high-power photovoltaic technology have enabled the possibility of reasonably sized, high-specific power solar arrays. At high specific powers, power levels ranging from 50 to several hundred kilowatts are feasible. Ion thrusters offer long life and overall high efficiency (typically greater than 70 percent efficiency). In Phase I, the team at ElectroDynamic Applications, Inc., built a 25-kW, 50-cm ion thruster discharge chamber and fabricated a laboratory model. This was in response to the need for a single, high-powered engine to fill the gulf between the 7-kW NASA's Evolutionary Xenon Thruster (NEXT) system and a notional 25-kW engine. The Phase II project matured the laboratory model into a protoengineering model ion thruster. This involved the evolution of the discharge chamber to a high-performance thruster by performance testing and characterization via simulated and full beam extraction testing. Through such testing, the team optimized the design and built a protoengineering model thruster. Coupled with gridded ion thruster technology, this technology can enable a wide range of missions, including ambitious near-Earth NASA missions, Department of Defense missions, and commercial satellite activities.

The adsorption of rare earth ions using carbonized polydopamine nano shells

DOE PAGES

Sun, Xiaoqi; Luo, Huimin; Mahurin, Shannon Mark; ...

2016-01-07

Herein we report the structure effects of nano carbon shells prepared by carbonized polydopamine for rare earth elements (REEs) adsorption for the first time. The solid carbon sphere, 60 nm carbon shell and 500 nm carbon shell were prepared and investigated for adsorption and desorption of REEs. The adsorption of carbon shells for REEs was found to be better than the solid carbon sphere. The effect of acidities on the adsorption and desorption properties was discussed in this study. The good adsorption performance of carbon shells can be attributed to their porous structure, large specific surface area, amine group andmore » carbonyl group of dopamine.« less

Competing Structural Instabilities in the Ruddlesden–Popper Derivatives HRTiO 4 (R = Rare Earths): Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity

DOE PAGES

Sen Gupta, Arnab; Akamatsu, Hirofumi; Brown, Forrest G.; ...

2016-12-06

We report the discovery of noncentrosymmetry in the family of HRTiO 4 (R = Eu, Gd, Dy) layered oxides possessing a Ruddlesden-Popper derivative structure, by second harmonic generation and synchrotron x-ray diffraction with the support of density functional theory calculations. These oxides were previously thought to possess inversion symmetry. Here, inversion symmetry is broken by oxygen octahedral rotations, a mechanism that is not active in simple perovskites. We discover a competition between oxygen octahedral rotations and sliding of the octahedral perovskite blocks at the OH layers. For the smaller rare earth ions, R = Eu, Gd, Dy, which favor themore » octahedral rotations, noncentrosymmetry is present but the sliding at the OH layer is absent. For the larger rare earth ions, R = Nd and Sm, the octahe-dral rotations are absent, but sliding of the octahedral blocks at the OH layer is present, likely to optimize the hydrogen bond length arising from the directional nature of these bonds in the crystal structure. The study reveals a new mechanism for inducing noncentrosymmetry in layered oxides, and chemical-structural effects related to rare earth ion size and hydrogen bonding that can turn this mechanism on and off. In conclusion, we construct a complete phase diagram of temperature versus rare earth ionic radius for the HRTiO 4 family.« less

Competing Structural Instabilities in the Ruddlesden–Popper Derivatives HRTiO 4 (R = Rare Earths): Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sen Gupta, Arnab; Akamatsu, Hirofumi; Brown, Forrest G.

We report the discovery of noncentrosymmetry in the family of HRTiO 4 (R = Eu, Gd, Dy) layered oxides possessing a Ruddlesden-Popper derivative structure, by second harmonic generation and synchrotron x-ray diffraction with the support of density functional theory calculations. These oxides were previously thought to possess inversion symmetry. Here, inversion symmetry is broken by oxygen octahedral rotations, a mechanism that is not active in simple perovskites. We discover a competition between oxygen octahedral rotations and sliding of the octahedral perovskite blocks at the OH layers. For the smaller rare earth ions, R = Eu, Gd, Dy, which favor themore » octahedral rotations, noncentrosymmetry is present but the sliding at the OH layer is absent. For the larger rare earth ions, R = Nd and Sm, the octahe-dral rotations are absent, but sliding of the octahedral blocks at the OH layer is present, likely to optimize the hydrogen bond length arising from the directional nature of these bonds in the crystal structure. The study reveals a new mechanism for inducing noncentrosymmetry in layered oxides, and chemical-structural effects related to rare earth ion size and hydrogen bonding that can turn this mechanism on and off. In conclusion, we construct a complete phase diagram of temperature versus rare earth ionic radius for the HRTiO 4 family.« less

An Earth-sized planet with an Earth-like density.

PubMed

Pepe, Francesco; Cameron, Andrew Collier; Latham, David W; Molinari, Emilio; Udry, Stéphane; Bonomo, Aldo S; Buchhave, Lars A; Charbonneau, David; Cosentino, Rosario; Dressing, Courtney D; Dumusque, Xavier; Figueira, Pedro; Fiorenzano, Aldo F M; Gettel, Sara; Harutyunyan, Avet; Haywood, Raphaëlle D; Horne, Keith; Lopez-Morales, Mercedes; Lovis, Christophe; Malavolta, Luca; Mayor, Michel; Micela, Giusi; Motalebi, Fatemeh; Nascimbeni, Valerio; Phillips, David; Piotto, Giampaolo; Pollacco, Don; Queloz, Didier; Rice, Ken; Sasselov, Dimitar; Ségransan, Damien; Sozzetti, Alessandro; Szentgyorgyi, Andrew; Watson, Christopher A

2013-11-21

Recent analyses of data from the NASA Kepler spacecraft have established that planets with radii within 25 per cent of the Earth's (R Earth symbol) are commonplace throughout the Galaxy, orbiting at least 16.5 per cent of Sun-like stars. Because these studies were sensitive to the sizes of the planets but not their masses, the question remains whether these Earth-sized planets are indeed similar to the Earth in bulk composition. The smallest planets for which masses have been accurately determined are Kepler-10b (1.42 R Earth symbol) and Kepler-36b (1.49 R Earth symbol), which are both significantly larger than the Earth. Recently, the planet Kepler-78b was discovered and found to have a radius of only 1.16 R Earth symbol. Here we report that the mass of this planet is 1.86 Earth masses. The resulting mean density of the planet is 5.57 g cm(-3), which is similar to that of the Earth and implies a composition of iron and rock.

Device for providing high-intensity ion or electron beam

DOEpatents

McClanahan, Edwin D.; Moss, Ronald W.

1977-01-01

A thin film of a low-thermionic-work-function material is maintained on the cathode of a device for producing a high-current, low-pressure gas discharge by means of sputter deposition from an auxiliary electrode. The auxiliary electrode includes a surface with a low-work-function material, such as thorium, uranium, plutonium or one of the rare earth elements, facing the cathode but at a disposition and electrical potential so as to extract ions from the gas discharge and sputter the low-work-function material onto the cathode. By continuously replenishing the cathode film, high thermionic emissions and ion plasmas can be realized and maintained over extended operating periods.

Observation of a Rare Earth Ion–Extractant Complex Arrested at the Oil–Water Interface During Solvent Extraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bu, Wei; Yu, Hao; Luo, Guangming

2014-09-11

Selective extraction of metal ions from a complex aqueous mixture into an organic phase is used to separate toxic or radioactive metals from polluted environments and nuclear waste, as well as to produce industrially relevant metals, such as rare earth ions. Selectivity arises from the choice of an extractant amphiphile, dissolved in the organic phase, which interacts preferentially with the target metal ion. The extractant-mediated process of ion transport from an aqueous to an organic phase takes place at the aqueous–organic interface; nevertheless, little is known about the molecular mechanism of this process despite its importance. Although state-of-the-art X-ray scatteringmore » is uniquely capable of probing molecular ordering at a liquid–liquid interface with subnanometer spatial resolution, utilizing this capability to investigate interfacial dynamical processes of short temporal duration remains a challenge. We show that a temperature-driven adsorption transition can be used to turn the extraction on and off by controlling adsorption and desorption of extractants at the oil–water interface. Lowering the temperature through this transition immobilizes a supramolecular ion–extractant complex at the interface during the extraction of rare earth erbium ions. Under the conditions of these experiments, the ion–extractant complexes condense into a two-dimensional inverted bilayer, which is characterized on the molecular scale with synchrotron X-ray reflectivity and fluorescence measurements. Raising the temperature above the transition leads to Er ion extraction as a result of desorption of ion–extractant complexes from the interface into the bulk organic phase. XAFS measurements of the ion–extractant complexes in the bulk organic phase demonstrate that they are similar to the interfacial complexes.« less

Neon isotopes show that Earth was accreted from irradiated material

NASA Astrophysics Data System (ADS)

Moreira, M. A.

2015-12-01

Since the 1980s, the notion that the Earth's mantle has a "solar" isotopic signature for neon has been favoured. Indeed, the 20Ne/22Ne ratio is above 12.5 in the mantle sources of OIB and MORB, close to the solar composition (13.4 for the Sun or 13.8 for the solar wind) and different from both atmospheric and chondritic compositions (Phase Q, Neon A). The most well accepted process invoked to explain this observed solar composition in the mantle is dissolution into a magma ocean of solar gases captured by gravity around the proto-Earth. However, Earth was accreted after gas from the proto-planetary disk had evaporated, suggesting that Earth itself could not have captured such a solar primordial atmosphere. Only planetary embryos were formed when the gas was still present in the disk. However, these planetary embryos with the mass of Mars are not massive enough to capture a solar dense atmosphere able to incorporate enough neon into the mantle. New estimates of the neon isotopic compositions of both the Earth's mantle and of the implanted solar wind into grains suggest that the origin of the neon on Earth is related to solar wind irradiation on μm grains before planetary accretion started and not dissolution. Although incorporation of solar ions by this process is only significant for very volatiles (depleted) elements, the irradiation by x-rays has important consequences for the bulk chemistry of irradiated grains as it has been demonstrated that it produces depletion in Mg and Si, relatively to O (e.g Bradley et al., 1994), a pattern also observed for the Bulk silicate Earth. References Bradley, J. (1994). "Chemically Anomalous, Preaccretionally irradiated Grains in Interplanetary fust from Comets." Science 265: 925-929.

Structure of the plasmapause from ISEE 1 low-energy ion and plasma wave observations

NASA Technical Reports Server (NTRS)

Nagai, T.; Horwitz, J. L.; Anderson, R. R.; Chappell, C. R.

1985-01-01

Low-energy ion pitch angle distributions are compared with plasma density profiles in the near-earth magnetosphere using ISEE 1 observations. The classical plasmapause determined by the sharp density gradient is not always observed in the dayside region, whereas there almost always exists the ion pitch angle distribution transition from cold, isotropic to warm, bidirectional, field-aligned distributions. In the nightside region the plasmapause density gradient is typically found, and it normally coincides with the ion pitch angle distribution transition. The sunward motion of the plasma is found in the outer part of the 'plasmaspheric' plasma in the dusk bulge region.

Contribution of energetic and heavy ions to the plasma pressure: The 27 September to 3 October 2002 storm

NASA Astrophysics Data System (ADS)

Kronberg, E. A.; Welling, D.; Kistler, L. M.; Mouikis, C.; Daly, P. W.; Grigorenko, E. E.; Klecker, B.; Dandouras, I.

2017-09-01

Magnetospheric plasma sheet ions drift toward the Earth and populate the ring current. The ring current plasma pressure distorts the terrestrial internal magnetic field at the surface, and this disturbance strongly affects the strength of a magnetic storm. The contribution of energetic ions (>40 keV) and of heavy ions to the total plasma pressure in the near-Earth plasma sheet is not always considered. In this study, we evaluate the contribution of low-energy and energetic ions of different species to the total plasma pressure for the storm observed by the Cluster mission from 27 September until 3 October 2002. We show that the contribution of energetic ions (>40 keV) and of heavy ions to the total plasma pressure is ≃76-98.6% in the ring current and ≃14-59% in the magnetotail. The main source of oxygen ions, responsible for ≃56% of the plasma pressure of the ring current, is located at distances earthward of XGSE ≃ -13.5 RE during the main phase of the storm. The contribution of the ring current particles agrees with the observed Dst index. We model the magnetic storm using the Space Weather Modeling Framework (SWMF). We assess the plasma pressure output in the ring current for two different ion outflow models in the SWMF through comparison with observations. Both models yield reasonable results. The model which produces the most heavy ions agrees best with the observations. However, the data suggest that there is still potential for refinement in the simulations.

Fabrication of novel metal ion imprinted xanthan gum-layered double hydroxide nanocomposite for adsorption of rare earth elements.

PubMed

Iftekhar, Sidra; Srivastava, Varsha; Hammouda, Samia Ben; Sillanpää, Mika

2018-08-15

The work focus to enhance the properties of xanthan gum (XG) by anchoring metal ions (Fe, Zr) and encapsulating inorganic matrix (M@XG-ZA). The fabricated nanocomposite was characterized by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDX), Fourier Transform Infrared Spectroscopy (FTIR), surface area (BET) and zeta potential analysis. The adsorption of Sc, Nd, Tm and Yb was investigated after screening of synthesized materials in detail to understand the influence of pH, contact time, temperature and initial REE (rare earth element) concentration both in single and multicomponent system via batch adsorption. The adsorption mechanism was verified by FTIR, SEM and elemental mapping. The SEM images of Zr@XG-ZA demonstrate scutes structure, which disappeared after adsorption of REEs. The maximum adsorption capacities were 132.30, 14.01, 18.15 and 25.73 mg/g for Sc, Nd, Tm and Yb, respectively. The adsorption efficiency over Zr@XG-ZA in multicomponent system was higher than single system and the REEs followed the order: Sc > Yb > Tm > Nd. The Zr@XG-ZA demonstrate good adsorption behavior for REEs up to five cycles and then it can be used as photocatalyst for the degradation of tetracycline. Thus, the work adds a new insight to design and preparation of efficient bifunctional adsorbents from sustainable materials for water purification. Copyright © 2018 Elsevier Ltd. All rights reserved.

Initial assessment of the effects of energetic ion injections in the magnetosphere due to the transport of satellite power system components from low earth orbit to geosynchronous earth orbit

NASA Astrophysics Data System (ADS)

Curtis, S. A.; Grebowsky, J. M.

1980-07-01

Potentially serious environmental effects exist when cargo orbital transfer vehicle (COTV) ion propulsion is used on the scale proposed in the preliminary definition studies of the Satellite Power System. These effects of the large scale injections of ion propulsion exhaust in the plasmasphere and in the outer magnetosphere were shown to be highly model dependent with major differences existing in the predicted effects of two models, the ion cloud model and the ion sheath model. The expected total number density deposition of the propellant Ar(+) in the plasmasphere, the energy spectra of the deposited Ar(+) and time dependent behavior of the Ar(+) injected into the plasmasphere by a fleet of COTV vehicles differ drastically between the two models. The ion sheath model was demonstrated to be applicable to the proposed Ar(+) beam physics if the beam was divergent and turbulent whereas the ion cloud model was not a realistic approximation for such a beam because the "frozen-field" assumption on which it is based is not valid.

Ion Acceleration by Flux Transfer Events in the Terrestrial Magnetosheath

NASA Astrophysics Data System (ADS)

Jarvinen, R.; Vainio, R.; Palmroth, M.; Juusola, L.; Hoilijoki, S.; Pfau-Kempf, Y.; Ganse, U.; Turc, L.; von Alfthan, S.

2018-02-01

We report ion acceleration by flux transfer events in the terrestrial magnetosheath in a global two-dimensional hybrid-Vlasov polar plane simulation of Earth's solar wind interaction. In the model we find that propagating flux transfer events created in magnetic reconnection at the dayside magnetopause drive fast-mode bow waves in the magnetosheath, which accelerate ions in the shocked solar wind flow. The acceleration at the bow waves is caused by a shock drift-like acceleration process under stationary solar wind and interplanetary magnetic field upstream conditions. Thus, the energization is not externally driven but results from plasma dynamics within the magnetosheath. Energetic proton populations reach the energy of 30 keV, and their velocity distributions resemble time-energy dispersive ion injections observed by the Cluster spacecraft in the magnetosheath.

Adsorption of heavy metal ions by sawdust of deciduous trees.

PubMed

Bozić, D; Stanković, V; Gorgievski, M; Bogdanović, G; Kovacević, R

2009-11-15

The adsorption of heavy metal ions from synthetic solutions was performed using sawdust of beech, linden and poplar trees. The adsorption depends on the process time, pH of the solution, type of ions, initial concentration of metals and the sawdust concentration in suspension. The kinetics of adsorption was relatively fast, reaching equilibrium for less than 20 min. The adsorption equilibrium follows Langmuir adsorption model. The ion exchange mechanism was confirmed assuming that the alkali-earth metals from the adsorbent are substituted by heavy metal ions and protons. On lowering the initial pH, the adsorption capacity decreased, achieving a zero value at a pH close to unity. The maximum adsorption capacity (7-8 mg g(-1) of sawdust) was achieved at a pH between 3.5 and 5 for all the studied kinds of sawdust. The initial concentration of the adsorbate and the concentration of sawdust strongly affect the process. No influence of particles size was evidenced. A degree of adsorption higher than 80% can be achieved for Cu(2+) ions but it is very low for Fe(2+) ions, not exceeding 10%.

Energy conversion through mass loading of escaping ionospheric ions for different Kp values

NASA Astrophysics Data System (ADS)

Yamauchi, Masatoshi; Slapak, Rikard

2018-01-01

By conserving momentum during the mixing of fast solar wind flow and slow planetary ion flow in an inelastic way, mass loading converts kinetic energy to other forms - e.g. first to electrical energy through charge separation and then to thermal energy (randomness) through gyromotion of the newly born cold ions for the comet and Mars cases. Here, we consider the Earth's exterior cusp and plasma mantle, where the ionospheric origin escaping ions with finite temperatures are loaded into the decelerated solar wind flow. Due to direct connectivity to the ionosphere through the geomagnetic field, a large part of this electrical energy is consumed to maintain field-aligned currents (FACs) toward the ionosphere, in a similar manner as the solar wind-driven ionospheric convection in the open geomagnetic field region. We show that the energy extraction rate by the mass loading of escaping ions (ΔK) is sufficient to explain the cusp FACs, and that ΔK depends only on the solar wind velocity accessing the mass-loading region (usw) and the total mass flux of the escaping ions into this region (mloadFload), as ΔK ˜ -mloadFloadu2sw/4. The expected distribution of the separated charges by this process also predicts the observed flowing directions of the cusp FACs for different interplanetary magnetic field (IMF) orientations if we include the deflection of the solar wind flow directions in the exterior cusp. Using empirical relations of u0 ∝ Kp + 1.2 and Fload ∝ exp(0.45Kp) for Kp = 1-7, where u0 is the solar wind velocity upstream of the bow shock, ΔK becomes a simple function of Kp as log10(ΔK) = 0.2 ṡ Kp + 2 ṡ log10(Kp + 1.2) + constant. The major contribution of this nearly linear increase is the Fload term, i.e. positive feedback between the increase of ion escaping rate Fload through the increased energy consumption in the ionosphere for high Kp, and subsequent extraction of more kinetic energy ΔK from the solar wind to the current system by the increased

Discrimination of ionic species from broad-beam ion sources

NASA Technical Reports Server (NTRS)

Anderson, J. R.

1993-01-01

The performance of a broad-beam, three-grid, ion extraction system incorporating radio frequency (RF) mass discrimination was investigated experimentally. This testing demonstrated that the system, based on a modified single-stage Bennett mass spectrometer, can discriminate between ionic species having about a 2-to-1 mass ratio while producing a broad-beam of ions with low kinetic energy (less than 15 eV). Testing was conducted using either argon and krypton ions or atomic and diatomic oxygen ions. A simple one-dimensional model, which ignores magnetic field and space-charge effects, was developed to predict the species separation capabilities as well as the kinetic energies of the extracted ions. The experimental results correlated well with the model predictions. This RF mass discrimination system can be used in applications where both atomic and diatomic ions are produced, but a beam of only one of the species is desired. An example of such an application is a 5 eV atomic oxygen source. This source would produce a beam of atomic oxygen with 5 eV kinetic energy, which would be directed onto a material specimen, to simulate the interaction between the surface of a satellite and the rarefied atmosphere encountered in low-Earth orbit.

Understanding the Earth's Mantle Through Advanced Elasticity Measurements

NASA Astrophysics Data System (ADS)

Marquardt, Hauke; Schulze, Kirsten; Kurnosov, Alexander; Buchen, Johannes; Frost, Daniel; Boffa Ballaran, Tiziana; Marquardt, Katharina; Kawazoe, Takaaki

2017-04-01

Constraints on the inner structure, chemical and mineralogical composition as well as dynamics of Earth's mantle can be derived through comparison of laboratory elasticity data to seismological observables. A quantitative knowledge of the elastic properties of mantle minerals, and their variations with chemical composition, at pressure and temperature conditions of Earth's mantle is key to construct reliable synthetic mineral physics-based seismic velocity models to be compared to seismic observables. We will discuss results of single-crystal elasticity measurements on Earth mantle minerals that have been conducted using the combined Brillouin scattering and x-ray diffraction (XRD) system at BGI Bayreuth in combination with advanced sample preparation using the focused ion beam (FIB) technique [1] that allows for tailoring sizes and shapes of tiny single-crystals. In our experiments, multiple FIB-prepared single-crystals were loaded in a single sample chamber of a resistively-heated diamond-anvil cell (DAC). The possiblity to measure simultaneously acoustic wave velocities and density (unit-cell parameters) in the DAC in combination with the multi-sample approach facilitates direct quantification of the effects of chemical substitution on the elasticity and seismic wave velocities at non-ambient conditions. Our experimental approach eliminates uncertainties arising from the combination of data collected under (potentially) different conditions in several DAC runs, in different laboratories and/or from using different pressure-temperature sensors. We will present our recent experiments on the elasticity of single-crystal Fe-Al-bearing bridgmanite in the lower mantle and discuss implications for the composition and oxidation state of Earth's lower mantle. We will further discuss our laboratory data on the effects of 'water' and iron on the seismic wave velocities of ringwoodite in Earth's transition zone and outline implications for mapping 'water' in the transition

Cuspp: Cubesat Mission to Study Solar Particles over the Earth's Poles

NASA Astrophysics Data System (ADS)

Allegrini, F.; Desai, M. I.; Ebert, R. W.; George, D. E.; Jahn, J. M.; Livi, S. A.; Ogasawara, K.; Christian, E. R.; Kanekal, S. G.

2014-12-01

The CubeSat mission to study Solar Particles over the Earth's Poles (CuSPP) has recently been selected by NASA part of the LCAS program. It is a 4-year project to design, develop, and integrate a 3U CubeSat with a miniaturized suprathermal ion spectrograph (SIS) to measure the temporal, spectral, and angular distributions of ~3-70 keV/q suprathermal ions that constitute the source material for solar and interplanetary particle events. SIS is a novel, electrostatic analyzer-microchannel plate based sensor that is the scaled down version of a potential future larger sensor for space weather predictions and suprathermal ion science. CuSPP's technical objective is to increase the technological readiness level (TRL) of SIS so that it can be proposed and flown with significantly reduced risk and cost on future Heliophysics mission. From a ~500 km nearly circular, high inclination (>65°) LEO, CuSPP sweeps through the polar cap regions, where it will measure ion precipitation, and all magnetospheric L-shells at an orbital period of ~95 minutes. We will present the mission concept, the science objectives, the sensor, and report on the status.

Contributed Review: A review of the investigation of rare-earth dopant profiles in optical fibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sidiroglou, F.; Baxter, G.; Roberts, A.

Rare-earth doped optical fibers have captivated the interest of many researchers around the world across the past three decades. The growth of this research field has been stimulated primarily through their application in optical communications as fiber lasers and amplifiers, although rare-earth doped optical fiber based devices are now finding important uses in many other scientific and industrial areas (for example, medicine, sensing, the military, and material processing). Such wide commercial interest has provided a strong incentive for innovative fiber designs, alternative glass compositions, and novel fabrication processes. A prerequisite for the ongoing progress of this research field is developingmore » the capacity to provide high resolution information about the rare-earth dopant distribution profiles within the optical fibers. This paper constitutes a comprehensive review of the imaging techniques that have been utilized in the analysis of the distribution of the rare-earth ion erbium within the core of optical fibers.« less

Contributed Review: A review of the investigation of rare-earth dopant profiles in optical fibers.

PubMed

Sidiroglou, F; Roberts, A; Baxter, G

2016-04-01

Rare-earth doped optical fibers have captivated the interest of many researchers around the world across the past three decades. The growth of this research field has been stimulated primarily through their application in optical communications as fiber lasers and amplifiers, although rare-earth doped optical fiber based devices are now finding important uses in many other scientific and industrial areas (for example, medicine, sensing, the military, and material processing). Such wide commercial interest has provided a strong incentive for innovative fiber designs, alternative glass compositions, and novel fabrication processes. A prerequisite for the ongoing progress of this research field is developing the capacity to provide high resolution information about the rare-earth dopant distribution profiles within the optical fibers. This paper constitutes a comprehensive review of the imaging techniques that have been utilized in the analysis of the distribution of the rare-earth ion erbium within the core of optical fibers.

Hybridization wave as the cause of the metal-insulator transition in rare earth nickelates

NASA Astrophysics Data System (ADS)

Park, Hyowon; Marianetti, Chris A.; Millis, Andrew J.

2012-02-01

The metal-insulator transition driven by varying rare earth (Re) ion in ReNiO3 has been a longstanding challenge to materials theory. Experimental evidence suggesting charge order is seemingly incompatible with the strong Mott-Hubbard correlations characteristic of transition metals. We present density functional, Hartree-Fock and Dynamical Mean field calculations showing that the origin of the insulating phase is a hybridization wave, in which a two sublattice ordering of the oxygen breathing mode produces two Ni sites with almost identical Ni d-charge densities but very different magnetic moments and other properties. The high temperature crystal structure associated with smaller Re ions such as Lu is shown to be more susceptible to the distortion than the high temperature structure associated with larger Re ions such as La.

Conical pitch angle distributions of very low-energy ion fluxes observed by ISEE 1

NASA Technical Reports Server (NTRS)

Horwitz, J. L.; Baugher, C. R.; Chappell, C. R.; Shelley, E. G.; Young, D. T.

1982-01-01

Observations are presented of conical distributions of low-energy ion fluxes from throughout the magnetosphere. The data were provided by the plasma composition experiment (PCE) on ISEE 1. ISEE 1 was launched in October 1977 into a highly elliptical orbit with a 30 deg inclination to the equator and 22.5 earth radii apogee. Particular attention is given to data taken when the instrument was in its thermal plasma mode, sampling ions in the energy per charge range 0-100 eV/e. Attention is given to examples of conical distributions in 0- to 100-eV/e ions, the occurrence of conical distributions of 0- to 100-eV ions in local time-geocentric distance and latitude-geocentric distance coordinates, the cone angles in 0- to 100-eV ion conics, Kp distributions of 0- to 100-eV ion conics, and some compositional aspects of 0- to 100-eV ion conics.

Discover Earth

NASA Technical Reports Server (NTRS)

Steele, Colleen

1998-01-01

Discover Earth is a NASA-sponsored project for teachers of grades 5-12, designed to: (1) enhance understanding of the Earth as an integrated system; (2) enhance the interdisciplinary approach to science instruction; and (3) provide classroom materials that focus on those goals. Discover Earth is conducted by the Institute for Global Environmental Strategies in collaboration with Dr. Eric Barron, Director, Earth System Science Center, The Pennsylvania State University; and Dr. Robert Hudson, Chair, the Department of Meteorology, University of Maryland at College Park. The enclosed materials: (1) represent only part of the Discover Earth materials; (2) were developed by classroom teachers who are participating in the Discover Earth project; (3) utilize an investigative approach and on-line data; and (4) can be effectively adjusted to classrooms with greater/without technology access. The Discover Earth classroom materials focus on the Earth system and key issues of global climate change including topics such as the greenhouse effect, clouds and Earth's radiation balance, surface hydrology and land cover, and volcanoes and climate change. All the materials developed to date are available on line at (http://www.strategies.org) You are encouraged to submit comments and recommendations about these materials to the Discover Earth project manager, contact information is listed below. You are welcome to duplicate all these materials.

Development of advanced inert-gas ion thrusters

NASA Technical Reports Server (NTRS)

Poeschel, R. L.

1983-01-01

Inert gas ion thruster technology offers the greatest potential for providing high specific impulse, low thrust, electric propulsion on large, Earth orbital spacecraft. The development of a thruster module that can be operated on xenon or argon propellant to produce 0.2 N of thrust at a specific impulse of 3000 sec with xenon propellant and at 6000 sec with argon propellant is described. The 30 cm diameter, laboratory model thruster is considered to be scalable to produce 0.5 N thrust. A high efficiency ring cusp discharge chamber was used to achieve an overall thruster efficiency of 77% with xenon propellant and 66% with argon propellant. Measurements were performed to identify ion production and loss processes and to define critical design criteria (at least on a preliminary basis).

Strong Turbulence in Alkali Halide Negative Ion Plasmas

NASA Astrophysics Data System (ADS)

Sheehan, Daniel

1999-11-01

Negative ion plasmas (NIPs) are charge-neutral plasmas in which the negative charge is dominated by negative ions rather than electrons. They are found in laser discharges, combustion products, semiconductor manufacturing processes, stellar atmospheres, pulsar magnetospheres, and the Earth's ionosphere, both naturally and man-made. They often display signatures of strong turbulence^1. Development of a novel, compact, unmagnetized alkali halide (MX) NIP source will be discussed, it incorporating a ohmically-heated incandescent (2500K) tantulum solenoid (3cm dia, 15 cm long) with heat shields. The solenoid ionizes the MX vapor and confines contaminant electrons, allowing a very dry (electron-free) source. Plasma densities of 10^10 cm-3 and positive to negative ion mass ratios of 1 <= fracm_+m- <= 20 are achievable. The source will allow tests of strong turbulence theory^2. 1 Sheehan, D.P., et al., Phys. Fluids B5, 1593 (1993). 2 Tsytovich, V. and Wharton, C.W., Comm. Plasma Phys. Cont. Fusion 4, 91 (1978).

The measurement of Earth rotation on a deformable Earth

NASA Technical Reports Server (NTRS)

Cannon, W. H.

1980-01-01

Until recently, the methods of geodetic positioning on the Earth were limited to a precision of roughly one part in 10 to the 6th power. At this level of precision, the Earth can be regarded as a rigid body since the largest departure of the Earth from rigidity is manifested in the strains of the Earth tides which are of the order of one part in 10 to the 7th power. Long baseline interferometry is expected to routinely provide global positioning to a precision of one part in 10 to the 8th power or better. At this level of precision, all parts of the Earth's surface must be regarded as being, at least potentially, in continual motion relative to the geocenter as a result of a variety of geophysical effects. The general implications of this phenomenon for the theory of the Earth's rotation is discussed. Particular attention is given to the question of the measurement of the 'Earth's rotation vector' on a deformable Earth.

Performance of large area xenon ion thrusters for orbit transfer missions

NASA Technical Reports Server (NTRS)

Rawlin, Vincent K.

1989-01-01

Studies have indicated that xenon ion propulsion systems can enable the use of smaller Earth-launch vehicles for satellite placement which results in significant cost savings. These analyses have assumed the availability of advanced, high power ion thrusters operating at about 10 kW or higher. A program was initiated to explore the viability of operating 50 cm diameter ion thrusters at this power level. Operation with several discharge chamber and ion extraction grid set combinations has been demonstrated and data were obtained at power levels to 16 kW. Fifty cm diameter thrusters using state of the art 30 cm diameter grids or advanced technology 50 cm diameter grids allow discharge power and beam current densities commensurate with long life at power levels up to 10 kW. In addition, 50 cm diameter thrusters are shown to have the potential for growth in thrust and power levels beyond 10 KW.

MMS observations of magnetic reconnection signatures of dissipating ion inertial-scale flux ropes associated with dipolarization events

NASA Astrophysics Data System (ADS)

Poh, G.; Slavin, J. A.; Lu, S.; Le, G.; Cassak, P.; Eastwood, J. P.; Ozturk, D. S.; Zou, S.; Nakamura, R.; Baumjohann, W.; Russell, C. T.; Gershman, D. J.; Giles, B. L.; Pollock, C.; Moore, T. E.; Torbert, R. B.; Burch, J. L.

2017-12-01

The formation of flux ropes is thought to be an integral part of the process that may have important consequences for the onset and subsequent rate of reconnection in the tail. Earthward flows, i.e. bursty bulk flows (BBFs), generate dipolarization fronts (DFs) as they interact with the closed magnetic flux in their path. Global hybrid simulations and THEMIS observations have shown that earthward-moving flux ropes can undergo magnetic reconnection with the near-Earth dipole field in the downtail region between the Near Earth Neutral Line and the near-Earth dipole field to create DFs-like signatures. In this study, we analyzed sequential "chains" of earthward-moving, ion-scale flux ropes embedded within DFs observed during MMS first tail season. MMS high-resolution plasma measurements indicate that these earthward flux ropes embedded in DFs have a mean bulk flow velocity and diameter of 250 km/s and 1000 km ( 2‒3 ion inertial length λi), respectively. Magnetic reconnection signatures preceding the flux rope/DF encounter were also observed. As the southward-pointing magnetic field in the leading edge of the flux rope reconnects with the northward-pointing geomagnetic field, the characteristic quadrupolar Hall magnetic field in the ion diffusion region and electron outflow jets in the north-south direction are observed. Our results strongly suggest that the earthward moving flux ropes brake and gradually dissipate due to magnetic reconnection with the near Earth magnetic field. We have also examined the occurrence rate of these dissipating flux ropes/DF events as a function of downtail distances.

In-Situ U-Pb Dating of Apatite by Hiroshima-SHRIMP: Contributions to Earth and Planetary Science.

PubMed

Terada, Kentaro; Sano, Yuji

2012-01-01

The Sensitive High Resolution Ion MicroProbe (SHRIMP) is the first ion microprobe dedicated to geological isotopic analyses, especially in-situ analyses related to the geochronology of zircon. Such a sophisticated ion probe, which can attain a high sensitivity at a high mass resolution, based on a double focusing high mass-resolution spectrometer, designed by Matsuda (1974), was constructed at the Australian National University. In 1996, such an instrument was installed at Hiroshima University and was the first SHRIMP to be installed in Japan. Since its installation, our focus has been on the in-situ U-Pb dating of the mineral apatite, as well as zircon, which is a more common U-bearing mineral. This provides the possibility for extending the use of in-situ U-Pb dating from determining the age of formation of volcanic, granitic, sedimentary and metamorphic minerals to the direct determination of the diagenetic age of fossils and/or the crystallization age of various meteorites, which can provide new insights into the thermal history on the Earth and/or the Solar System. In this paper, we review the methodology associated with in-situ apatite dating and our contribution to Earth and Planetary Science over the past 16 years.

In-Situ U–Pb Dating of Apatite by Hiroshima-SHRIMP: Contributions to Earth and Planetary Science

PubMed Central

Terada, Kentaro; Sano, Yuji

2012-01-01

The Sensitive High Resolution Ion MicroProbe (SHRIMP) is the first ion microprobe dedicated to geological isotopic analyses, especially in-situ analyses related to the geochronology of zircon. Such a sophisticated ion probe, which can attain a high sensitivity at a high mass resolution, based on a double focusing high mass-resolution spectrometer, designed by Matsuda (1974), was constructed at the Australian National University. In 1996, such an instrument was installed at Hiroshima University and was the first SHRIMP to be installed in Japan. Since its installation, our focus has been on the in-situ U–Pb dating of the mineral apatite, as well as zircon, which is a more common U-bearing mineral. This provides the possibility for extending the use of in-situ U–Pb dating from determining the age of formation of volcanic, granitic, sedimentary and metamorphic minerals to the direct determination of the diagenetic age of fossils and/or the crystallization age of various meteorites, which can provide new insights into the thermal history on the Earth and/or the Solar System. In this paper, we review the methodology associated with in-situ apatite dating and our contribution to Earth and Planetary Science over the past 16 years. PMID:24349912

Evidence for specularly reflected ions upstream from the quasi-parallel bow shock

NASA Technical Reports Server (NTRS)

Gosling, J. T.; Thomsen, M. F.; Bame, S. J.; Feldman, W. C.; Paschmann, G.; Sckopke, N.

1982-01-01

Ion velocity distributions in the form of bunches of gyrating particles traveling along helical paths have been observed moving sunward immediately upstream from quasi-parallel parts of the earth's bow shock using Los Alamos/Garching instruments on ISEE-1 and -2. These distributions have characteristics which indicate that they are produced by the nearly specular reflection at the shock of a portion of the incident solar wind ions. In particular, the guiding center motion and the gyrospeeds of the gyrating ions are quantitatively consistent with simple geometrical considerations for specular reflection. These considerations reveal that specularly reflected ions can escape upstream when the angle between the upstream magnetic field and the local shock normal is less than 45 deg but not when the angle is greater than 45 deg. These upstream gyrating ions are an important signature of one of the processes by which solar wind streaming energy is dissipated into other forms of energy at the shock.

Foreshock waves as observed in energetic ion flux

NASA Astrophysics Data System (ADS)

Petrukovich, A. A.; Chugunova, O. M.; Inamori, T.; Kudela, K.; Stetiarova, J.

2017-05-01

Oscillations of energetic ion fluxes with periods 10-100 s are often present in the Earth's foreshock. Detailed analysis of wave properties with Time History of Events and Macroscale Interactions during Substorms data and comparisons with other data sets confirm that these oscillations are the previously unnoticed part of well-known "30 s" waves but are observed mainly for higher-speed solar wind. Simultaneous magnetic oscillations have similar periods, large amplitudes, and nonharmonic unstable waveforms or shocklet-type appearance, suggesting their nonlinearity, also typical for high solar wind speed. Analysis of the general foreshock data set of Interball project shows that the average flux of the backstreaming energetic ions increases more than 1 order of magnitude, when solar wind speed increases from 400 to 500 km/s.

A Kirkwood-Buff derived force field for alkaline earth halide salts

NASA Astrophysics Data System (ADS)

Naleem, Nawavi; Bentenitis, Nikolaos; Smith, Paul E.

2018-06-01

The activity and function of many macromolecules in cellular environments are coupled with the binding of divalent ions such as calcium or magnesium. In principle, computer simulations can be used to understand the molecular level aspects of how many important macromolecules interact with ions. However, most of the force fields currently available often fail to accurately reproduce the properties of divalent ions in aqueous environments. Here we develop classical non-polarizable force fields for the aqueous alkaline earth metal halides (MX2), where M = Mg2+, Ca2+, Sr2+, Ba2+ and X = Cl-, Br-, I-, which can be used in bimolecular simulations and which are compatible with the Simple Point Charge/Extended (SPC/E) water model. The force field parameters are specifically developed to reproduce the experimental Kirkwood-Buff integrals for aqueous solutions and thereby the experimental activity derivatives, partial molar volumes, and excess coordination numbers. This ensures that a reasonable balance between ion-ion, ion-water, and water-water distributions is obtained. However, this requires a scaling of the cation to water oxygen interaction strength in order to accurately reproduce the integrals. The scaling factors developed for chloride salts are successfully transferable to the bromide and iodide salts. Use of these new models leads to reasonable diffusion constants and dielectric decrements. However, the performance of the models decreases with increasing salt concentration (>4m), and simulations of the pure crystals exhibited unstable behavior.

A Kirkwood-Buff derived force field for alkaline earth halide salts.

PubMed

Naleem, Nawavi; Bentenitis, Nikolaos; Smith, Paul E

2018-06-14

The activity and function of many macromolecules in cellular environments are coupled with the binding of divalent ions such as calcium or magnesium. In principle, computer simulations can be used to understand the molecular level aspects of how many important macromolecules interact with ions. However, most of the force fields currently available often fail to accurately reproduce the properties of divalent ions in aqueous environments. Here we develop classical non-polarizable force fields for the aqueous alkaline earth metal halides (MX 2 ), where M = Mg 2+ , Ca 2+ , Sr 2+ , Ba 2+ and X = Cl - , Br - , I - , which can be used in bimolecular simulations and which are compatible with the Simple Point Charge/Extended (SPC/E) water model. The force field parameters are specifically developed to reproduce the experimental Kirkwood-Buff integrals for aqueous solutions and thereby the experimental activity derivatives, partial molar volumes, and excess coordination numbers. This ensures that a reasonable balance between ion-ion, ion-water, and water-water distributions is obtained. However, this requires a scaling of the cation to water oxygen interaction strength in order to accurately reproduce the integrals. The scaling factors developed for chloride salts are successfully transferable to the bromide and iodide salts. Use of these new models leads to reasonable diffusion constants and dielectric decrements. However, the performance of the models decreases with increasing salt concentration (>4m), and simulations of the pure crystals exhibited unstable behavior.

Monitoring of photoluminescence decay by alkali and alkaline earth metal cations using a photoluminescent bolaamphiphile self-assembly as an optical probe.

PubMed

Kim, Sunhyung; Kwak, Jinyoung; Lee, Sang-Yup

2014-05-01

Photoluminescence (PL) decay induced by the displacement of an ionic fluorescence component, Tb(3+), with alkali and alkaline earth metal cations was investigated using photoluminescent spherical self-assemblies as optical probes. The photoluminescent spherical self-assembly was prepared by the self-organization of a tyrosine-containing bolaamphiphile molecule with a photosensitizer and Tb(3+) ion. The lanthanide ion, Tb(3+), electrically bound to the carboxyl group of the bolaamphiphile molecule, was displaced by alkali and alkaline earth metal cations that had stronger electrophilicity. The PL of the self-assembly decayed remarkably due to the substitution of lanthanide ions with alkali and alkaline earth metal cations. The PL decay showed a positive correlation with cation concentration and was sensitive to the cation valency. Generally, the PL decay was enhanced by the electrophilicity of the cations. However, Ca(2+) showed greater PL decay than Mg(2+) because Ca(2+) could create various complexes with the carboxyl groups of the bolaamphiphile molecule. Microscopic and spectroscopic investigations were conducted to study the photon energy transfer and displacement of Tb(3+) by the cation exchange. This study demonstrated that the PL decay by the displacement of the ionic fluorescent compound was applied to the detection of various cations in aqueous media and is applicable to the development of future optical sensors. Copyright © 2014 Elsevier B.V. All rights reserved.

Enhancement of negative hydrogen ion production in an electron cyclotron resonance source

NASA Astrophysics Data System (ADS)

Dugar-Zhabon, V. D.; Murillo, M. T.; Karyaka, V. I.

2013-07-01

In this paper, we present a method for improving the negative hydrogen ion yield in the electron cyclotron resonance source with driven plasma rings where the negative ion production is realized in two stages. First, the hydrogen and deuterium molecules are excited in collisions with plasma electrons to high-laying Rydberg and high vibration levels in the plasma volume. The second stage leads to negative ion production through the process of repulsive attachment of low-energy electrons by the excited molecules. The low-energy electrons originate due to a bombardment of the plasma electrode surface by ions of a driven ring and the thermoelectrons produced by a rare earth ceramic electrode, which is appropriately installed in the source chamber. The experimental and calculation data on the negative hydrogen ion generation rate demonstrate that very low-energy thermoelectrons significantly enhance the negative-ion generation rate that occurs in the layer adjacent to the plasma electrode surface. It is found that heating of the tungsten filaments placed in the source chamber improves the discharge stability and extends the pressure operation range.

On the velocity distribution of ion jets during substorm recovery

NASA Technical Reports Server (NTRS)

Birn, J.; Forbes, T. G.; Hones, E. W., Jr.; Bame, S. J.; Paschmann, G.

1981-01-01

The velocity distribution of earthward jetting ions that are observed principally during substorm recovery by satellites at approximately 15-35 earth radii in the magnetotail is quantitatively compared with two different theoretical models - the 'adiabatic deformation' of an initially flowing Maxwellian moving into higher magnetic field strength (model A) and the field-aligned electrostatic acceleration of an initially nonflowing isotropic Maxwellian including adiabatic deformation effects (model B). The assumption is made that the ions are protons or, more generally, that they consist of only one species. It is found that both models can explain the often observed concave-convex shape of isodensity contours of the distribution function.

Evaluation of Skylab earth laser beacon imagery. [spaceborne photography

NASA Technical Reports Server (NTRS)

Piech, K. R.; Schott, J. R.

1975-01-01

During the Skylab 3 and 4 missions the Skylab spacecraft was illuminated by a low power argon ion and dye laser. The earth laser beacon was studied visually by the astronauts. In addition, they collected 35 mm hand-held color photographs of the beacons. Photographs are shown that were obtained on Skylab 3 and Skylab 4. The imagery collected during the Skylab mission was analyzed to evaluate the utility of beacon lasers as terrestial 'artificial stars' for space navigation. The analyses of the imagery revealed two unusual features of the earth laser beacon: (1) The beacon, even though of a low power (approximately 1 watt), is considerably brighter than any other terrain feature and is readily visible on imagery at a distance in excess of 1500 km (900 miles). (2) Another feature of the beacon is its large size. The typical beacon extends over about 5 resolution areas with a characteristic dimension of about 200 m.

Analysis of “Favorable Growth Element” Based on Rare Earth-aluminum Composite Mechanism of Compound Process

NASA Astrophysics Data System (ADS)

Hao, Baohong; Zeng, Qihui; Zhao, Jin

2018-01-01

Under the background that failure resulted in by high temperature once only aluminum oxide is used as the gasoline additive. This paper, with the purpose to solve this problem, is to synthesize AcAl oxide for gasoline additive. In order to get the rare-earth-aluminum oxide, first, a complex model of rare earth oxide based on theories about ion coordination is established. Then, by the complex model, the type of “compound growth unit” when rare earth elements join the hydrothermal conditions and the inclination that “diversification” might probably happen are deduced. Depending on the results got by complex model, this paper introduces the type of compound and its existence conditions of “Compound growth unit” owned by stable rare-earth-aluminum oxide. By adjusting the compositions of modifier, compound materials of rare earth-aluminum oxide used for gasoline additive is made. By XRD test, aperture test, adsorption test and desorption test, the theoretical deduction is proved to be right. From the experiment, it is concluded that: a dense environment is the pre-condition to form rare-earth-aluminum polymer, which is also an essential condition for the polymer to update to a favorable growth unit and produce mesoporous rare-earth-aluminum oxide with high activity.

Long-period comet impact risk mitigation with Earth-based laser arrays

NASA Astrophysics Data System (ADS)

Zhang, Qicheng; Lubin, Philip M.; Hughes, Gary B.

2017-09-01

Long-period comets (LPCs) frequently transit the inner solar system, and like near-Earth asteroids (NEAs), pose a continued risk of impact with Earth. Unlike NEAs, LPCs follow nearly parabolic trajectories and approach from the distant outer solar system where they cannot be observed. An LPC on an Earth-impact trajectory is unlikely to be discovered more than a few years in advance of its arrival, even with significant advancements in sky survey detection capabilities, likely leaving insufficient time to develop and deliver an interception mission to deflect the comet. However, recent proposals have called for the development of one or more large ˜ 1 km laser arrays placed on or near Earth primarily as a means for photon propulsion of low-mass spacecraft at delta-v above what would be feasible by traditional chemical or ion propulsion methods. Such a laser array can also be directed to target and heat a threatening comet, sublimating its ices and activating jets of dust and vapor which alter the comet's trajectory in a manner similar to rocket propulsion. Simulations of directed energy comet deflection were previously developed from astrometric models of nongravitational orbital perturbations from solar heating, an analogous process that has been observed in numerous comets. These simulations are used together with the distribution of known LPC trajectories to evaluate the effect of an operational Earth-based laser array on the LPC impact risk.

Atmospheric ions, boreal forests and impacts on climate

NASA Astrophysics Data System (ADS)

Manninen, H. E.; Nieminen, T.; Franchin, A.; Järvinen, E.; Kontkanen, J.; Hirsikko, A.; Hõrrak, U.; Mirme, A.; Tammet, H.; Kerminen, V.-M.; Petäjä, T.; Kulmala, M.

2012-04-01

Aerosol particles play an important role in the Earth's atmosphere and in the climate system: They scatter and absorb solar radiation, facilitate chemical processes, and serve as seeds for cloud formation. The aerosol particles have direct cooling and warming effects on climate (IPCC, 2007). Secondary new particle formation (NPF) is a globally important source of aerosol particles (Kulmala and Kerminen, 2008). Currently, the mechanisms of particle formation and the vapors participating in this process are, however, not truly understood. Several formation and growth mechanisms have been proposed for the very first steps of the process: homogeneous, heterogeneous, ion-induced and kinetic nucleation and activation type cluster growth. Small ions are part of the atmospheric aerosol spectrum, and in atmospheric sciences study of ion-aerosol interactions is essential. Small ions are small molecular clusters carrying a net electric charge. They are produced by ionisation of molecules in the air. Typically the small ion concentrations vary in the range of 100-2000 cm-3 in both polarities (Hirsikko et al., 2011). Ion-induced NPF is limited by the ion production rate, which typically is around 10 ion pairs cm-3s-1 in the boundary layer over the ground. The ion production rate has strong spatial and temporal dependence. The ionisation mechanisms change with altitude: radon and gamma radiation from the ground and galactic cosmic rays dominate close to the Earth's surface, while higher in the free troposphere cosmic rays become the main driving factor. In order to fully explain atmospheric NPF and subsequent growth, we need to measure directly the very initial steps of the formation processes. Air ion spectrometers measure the mobility distributions of charged aerosol particles in the mobility diameter range of 0.8-42 nm (Mirme et al., 2007; Tammet et al., 2011). Neutral cluster and air ion spectrometers measure additionally the mobility distribution of neutral particles larger

Slow electron acoustic double layer (SEADL) structures in bi-ion plasma with trapped electrons

NASA Astrophysics Data System (ADS)

Shan, Shaukat Ali; Imtiaz, Nadia

2018-05-01

The properties of ion acoustic double layer (IADL) structures in bi-ion plasma with electron trapping are investigated by using the quasi-potential analysis. The κ-distributed trapped electrons number density expression is truncated to some finite order of the electrostatic potential. By utilizing the reductive perturbation method, a modified Schamel equation which describes the evolution of the slow electron acoustic double layer (SEADL) with the modified speed due to the presence of bi-ion species is investigated. The Sagdeev-like potential has been derived which accounts for the effect of the electron trapping and superthermality in a bi-ion plasma. It is found that the superthermality index, the trapping efficiency of electrons, and ion to electron temperature ratio are the inhibiting parameters for the amplitude of the slow electron acoustic double layers (SEADLs). However, the enhanced population of the cold ions is found to play a supportive role for the low frequency DLs in bi-ion plasmas. The illustrations have been presented with the help of the bi-ion plasma parameters in the Earth's ionosphere F-region.

Use of thulium-sensitized rare earth-doped low phonon energy crystalline hosts for IR sources.

PubMed

Ganem, Joseph; Bowman, Steven R

2013-11-01

Crystalline hosts with low phonon energies enable novel energy transfer processes when doped with rare earth ions. Two applications of energy transfer for rare earth ions in thulium-sensitized low phonon energy crystals that result in infrared luminescence are discussed. One application is an endothermic, phonon-assisted cross-relaxation process in thulium-doped yttrium chloride that converts lattice phonons to infrared emission, which raises the possibility of a fundamentally new method for achieving solid-state optical cooling. The other application is an optically pumped mid-IR phosphor using thulium-praseodymium-doped potassium lead chloride that converts 805-nm diode light to broadband emission from 4,000 to 5,500 nm. These two applications in chloride crystals are discussed in terms of critical radii calculated from Forster-Dexter energy transfer theory. It is found that the critical radii for electric dipole-dipole interactions in low phonon energy chloride crystals are comparable to those in conventional oxide and fluoride crystals. It is the reduction in multi-phonon relaxation rates in chloride crystals that enable these additional energy transfer processes and infrared luminescence.

Use of thulium-sensitized rare earth-doped low phonon energy crystalline hosts for IR sources

PubMed Central

2013-01-01

Crystalline hosts with low phonon energies enable novel energy transfer processes when doped with rare earth ions. Two applications of energy transfer for rare earth ions in thulium-sensitized low phonon energy crystals that result in infrared luminescence are discussed. One application is an endothermic, phonon-assisted cross-relaxation process in thulium-doped yttrium chloride that converts lattice phonons to infrared emission, which raises the possibility of a fundamentally new method for achieving solid-state optical cooling. The other application is an optically pumped mid-IR phosphor using thulium-praseodymium-doped potassium lead chloride that converts 805-nm diode light to broadband emission from 4,000 to 5,500 nm. These two applications in chloride crystals are discussed in terms of critical radii calculated from Forster-Dexter energy transfer theory. It is found that the critical radii for electric dipole-dipole interactions in low phonon energy chloride crystals are comparable to those in conventional oxide and fluoride crystals. It is the reduction in multi-phonon relaxation rates in chloride crystals that enable these additional energy transfer processes and infrared luminescence. PMID:24180684

Use of thulium-sensitized rare earth-doped low phonon energy crystalline hosts for IR sources

NASA Astrophysics Data System (ADS)

Ganem, Joseph; Bowman, Steven R.

2013-11-01

Crystalline hosts with low phonon energies enable novel energy transfer processes when doped with rare earth ions. Two applications of energy transfer for rare earth ions in thulium-sensitized low phonon energy crystals that result in infrared luminescence are discussed. One application is an endothermic, phonon-assisted cross-relaxation process in thulium-doped yttrium chloride that converts lattice phonons to infrared emission, which raises the possibility of a fundamentally new method for achieving solid-state optical cooling. The other application is an optically pumped mid-IR phosphor using thulium-praseodymium-doped potassium lead chloride that converts 805-nm diode light to broadband emission from 4,000 to 5,500 nm. These two applications in chloride crystals are discussed in terms of critical radii calculated from Forster-Dexter energy transfer theory. It is found that the critical radii for electric dipole-dipole interactions in low phonon energy chloride crystals are comparable to those in conventional oxide and fluoride crystals. It is the reduction in multi-phonon relaxation rates in chloride crystals that enable these additional energy transfer processes and infrared luminescence.

Simulation of electromagnetic ion cyclotron triggered emissions in the Earth's inner magnetosphere

NASA Astrophysics Data System (ADS)

Shoji, Masafumi; Omura, Yoshiharu

2011-05-01

In a recent observation by the Cluster spacecraft, emissions triggered by electromagnetic ion cyclotron (EMIC) waves were discovered in the inner magnetosphere. We perform hybrid simulations to reproduce the EMIC triggered emissions. We develop a self-consistent one-dimensional hybrid code with a cylindrical geometry of the background magnetic field. We assume a parabolic magnetic field to model the dipole magnetic field in the equatorial region of the inner magnetosphere. Triggering EMIC waves are driven by a left-handed polarized external current assumed at the magnetic equator in the simulation model. Cold proton, helium, and oxygen ions, which form branches of the dispersion relation of the EMIC waves, are uniformly distributed in the simulation space. Energetic protons with a loss cone distribution function are also assumed as resonant particles. We reproduce rising tone emissions in the simulation space, finding a good agreement with the nonlinear wave growth theory. In the energetic proton velocity distribution we find formation of a proton hole, which is assumed in the nonlinear wave growth theory. A substantial amount of the energetic protons are scattered into the loss cone, while some of the resonant protons are accelerated to higher pitch angles, forming a pancake velocity distribution.

Volatiles in the Earth: All shallow and all recycled

NASA Technical Reports Server (NTRS)

Anderson, Don L.

1994-01-01

A case can be made that accretion of the Earth was a high-temperature process and that the primordial Earth was dry. A radial zone-refining process during accretion may have excluded low-melting point and volatile material, including large-ion lithophile elements toward the surface, leaving a refractory and zoned interior. Water, sediments and altered hydrous oceanic crust are introduced back into the interior by subduction, a process that may be more efficient today than in the past. Seismic tomography strongly suggests that a large part of the uppermantle is above the solidus, and this implies wet melting. The mantle beneath Archean cratons has very fast seismic velocities and appears to be strong to 150 km or greater. This is consistent with very dry mantle. It is argued that recycling of substantial quantities of water occurs in the shallow mantle but only minor amounts recycle to depths greater than 200 km. Recycling also oxidizes that mantle; ocean island ('hotspot') basalts are intermediate in oxidation state to island-arc and midocean ridge basalts (MORB). This suggests a deep uncontaminated reservoir for MORB. Plate tectonics on a dry Earth is discussed in order to focus attention on inconsistencies in current geochemical models of terrestrial evolution and recycling.

Environment spectrum and coherence behaviours in a rare-earth doped crystal for quantum memory.

PubMed

Gong, Bo; Tu, Tao; Zhou, Zhong-Quan; Zhu, Xing-Yu; Li, Chuan-Feng; Guo, Guang-Can

2017-12-21

We theoretically investigate the dynamics of environment and coherence behaviours of the central ion in a quantum memory based on a rare-earth doped crystal. The interactions between the central ion and the bath spins suppress the flip-flop rate of the neighbour bath spins and yield a specific environment spectral density S(ω). Under dynamical decoupling pulses, this spectrum provides a general scaling for the coherence envelope and coherence time, which significantly extend over a range on an hour-long time scale. The characterized environment spectrum with ultra-long coherence time can be used to implement various quantum communication and information processing protocols.

Mechanistic study of lead desorption during the leaching process of ion-absorbed rare earths: pH effect and the column experiment.

PubMed

Tang, Jie; Xue, Qiang; Chen, Honghan; Li, Wenting

2017-05-01

High concentrations of ammonium sulfate, often used in the in situ mining process, can result in a decrease of pH in the environment and dissolution of rare earth metals. Ammonium sulfate can also cause desorption of toxic heavy metals, leading to environmental and human health implications. In this study, the desorption behavior and fraction changes of lead in the ion-absorbed rare earth ore were studied using batch desorption experiments and column leaching tests. Results from batch desorption experiments showed that the desorption process of lead included fast and slow stages and followed an Elovich model well. The desorption rate and the proportion of lead content in the solution to the total lead in the soil were observed to increase with a decrease in the initial pH of the ammonium sulfate solution. The lead in soil included an acid-extractable fraction, reducible fraction, oxidizable fraction, and a residual fraction, with the predominant fractions being the reducible and acid-extractable fractions. Ninety-six percent of the extractable fraction in soil was desorbed into solution at pH = 3.0, and the content of the reducible fraction was observed to initially increase (when pH >4.0) and then decrease (when pH <4.0) with a decrease in pH. Column leaching tests indicated that the content of lead in the different fractions of soil followed the trend of reducible fraction > oxidizable fraction > acid-extractable fraction > residual fraction after the simulating leaching mining process. The change in pH was also found to have a larger influence on the acid-extractable and reducible fractions than the other two fractions. The proportion of the extractable fraction being leached was ca. 86%, and the reducible fraction was enriched along the migration direction of the leaching liquid. These results suggest that certain lead fractions may desorb again and contaminate the environment via acid rain, which provides significant information for environmental assessment

Mechanistic study of lead desorption during the leaching process of ion-absorbed rare earths: pH effect and the column experiment

NASA Astrophysics Data System (ADS)

Xue, Q.; Tang, J., Sr.; Chen, H.

2017-12-01

High concentrations of ammonium sulfate, often used in the in-situ mining process, can result in a decrease of pH in the environment and dissolution of rare earth metals. Ammonium sulfate can also cause desorption of toxic heavy metals, leading to environmental and human health implications. In this study, the desorption behavior and fraction changes of lead in the ion-absorbed rare earth ore were studied using batch desorption experiments and column leaching tests. Results from batch desorption experiments showed that the desorption process of lead included fast and slow stages, and followed an Elovich model well. The desorption rate and the proportion of lead content in the solution to the total lead in the soil were observed to increase with a decrease in the initial pH of the ammonium sulfate solution. The lead in soil included an acid extractable fraction, reducible fraction, oxidizable fraction, and a residual fraction, with the predominant fractions being the reducible and acid extractable fractions. 96% of the extractable fraction in soil were desorbed into solution at pH=3.0, and the content of the reducible fraction was observed to initially increase (when pH>4.0) and then decrease (when pH<4.0) with a decrease in pH. Column leaching tests indicated that the content of lead in the different fractions of soil followed the trend of reducible fraction > oxidizable fraction > acid extractable fraction > residual fraction after the simulating leaching mining process. The change in pH was also found to have a larger influence on the acid extractable and reducible fractions than the other two fractions. The proportion of the extractable fraction being leached was ca. 86%, and the reducible fraction was enriched along the migration direction of the leaching liquid. These results suggest that certain lead fractions may desorb again and contaminate the environment via acid rain, which provides significant information for environmental assessment and remediation

Earth as an Extrasolar Planet: Earth Model Validation Using EPOXI Earth Observations

NASA Technical Reports Server (NTRS)

Robinson, Tyler D.; Meadows, Victoria S.; Crisp, David; Deming, Drake; A'Hearn, Michael F.; Charbonneau, David; Livengood, Timothy A.; Seager, Sara; Barry, Richard; Hearty, Thomas;

Earth as an Extrasolar Planet: Earth Model Validation Using EPOXI Earth Observations

NASA Astrophysics Data System (ADS)

Robinson, Tyler D.; Meadows, Victoria S.; Crisp, David; Deming, Drake; A'Hearn, Michael F.; Charbonneau, David; Livengood, Timothy A.; Seager, Sara; Barry, Richard K.; Hearty, Thomas; Hewagama, Tilak; Lisse, Carey M.; McFadden, Lucy A.; Wellnitz, Dennis D.

2011-06-01

The EPOXI Discovery Mission of Opportunity reused the Deep Impact flyby spacecraft to obtain spatially and temporally resolved visible photometric and moderate resolution near-infrared (NIR) spectroscopic observations of Earth. These remote observations provide a rigorous validation of whole-disk Earth model simulations used to better understand remotely detectable extrasolar planet characteristics. We have used these data to upgrade, correct, and validate the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional line-by-line, multiple-scattering spectral Earth model. This comprehensive model now includes specular reflectance from the ocean and explicitly includes atmospheric effects such as Rayleigh scattering, gas absorption, and temperature structure. We have used this model to generate spatially and temporally resolved synthetic spectra and images of Earth for the dates of EPOXI observation. Model parameters were varied to yield an optimum fit to the data. We found that a minimum spatial resolution of ∼100 pixels on the visible disk, and four categories of water clouds, which were defined by using observed cloud positions and optical thicknesses, were needed to yield acceptable fits. The validated model provides a simultaneous fit to Earth's lightcurve, absolute brightness, and spectral data, with a root-mean-square (RMS) error of typically less than 3% for the multiwavelength lightcurves and residuals of ∼10% for the absolute brightness throughout the visible and NIR spectral range. We have extended our validation into the mid-infrared by comparing the model to high spectral resolution observations of Earth from the Atmospheric Infrared Sounder, obtaining a fit with residuals of ∼7% and brightness temperature errors of less than 1 K in the atmospheric window. For the purpose of understanding the observable characteristics of the distant Earth at arbitrary viewing geometry and observing cadence, our validated forward model can be

Earth as an extrasolar planet: Earth model validation using EPOXI earth observations.

PubMed

Robinson, Tyler D; Meadows, Victoria S; Crisp, David; Deming, Drake; A'hearn, Michael F; Charbonneau, David; Livengood, Timothy A; Seager, Sara; Barry, Richard K; Hearty, Thomas; Hewagama, Tilak; Lisse, Carey M; McFadden, Lucy A; Wellnitz, Dennis D

2011-06-01

The EPOXI Discovery Mission of Opportunity reused the Deep Impact flyby spacecraft to obtain spatially and temporally resolved visible photometric and moderate resolution near-infrared (NIR) spectroscopic observations of Earth. These remote observations provide a rigorous validation of whole-disk Earth model simulations used to better understand remotely detectable extrasolar planet characteristics. We have used these data to upgrade, correct, and validate the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional line-by-line, multiple-scattering spectral Earth model. This comprehensive model now includes specular reflectance from the ocean and explicitly includes atmospheric effects such as Rayleigh scattering, gas absorption, and temperature structure. We have used this model to generate spatially and temporally resolved synthetic spectra and images of Earth for the dates of EPOXI observation. Model parameters were varied to yield an optimum fit to the data. We found that a minimum spatial resolution of ∼100 pixels on the visible disk, and four categories of water clouds, which were defined by using observed cloud positions and optical thicknesses, were needed to yield acceptable fits. The validated model provides a simultaneous fit to Earth's lightcurve, absolute brightness, and spectral data, with a root-mean-square (RMS) error of typically less than 3% for the multiwavelength lightcurves and residuals of ∼10% for the absolute brightness throughout the visible and NIR spectral range. We have extended our validation into the mid-infrared by comparing the model to high spectral resolution observations of Earth from the Atmospheric Infrared Sounder, obtaining a fit with residuals of ∼7% and brightness temperature errors of less than 1 K in the atmospheric window. For the purpose of understanding the observable characteristics of the distant Earth at arbitrary viewing geometry and observing cadence, our validated forward model can be

Earth as an Extrasolar Planet: Earth Model Validation Using EPOXI Earth Observations

PubMed Central

Meadows, Victoria S.; Crisp, David; Deming, Drake; A'Hearn, Michael F.; Charbonneau, David; Livengood, Timothy A.; Seager, Sara; Barry, Richard K.; Hearty, Thomas; Hewagama, Tilak; Lisse, Carey M.; McFadden, Lucy A.; Wellnitz, Dennis D.

2011-01-01

Abstract The EPOXI Discovery Mission of Opportunity reused the Deep Impact flyby spacecraft to obtain spatially and temporally resolved visible photometric and moderate resolution near-infrared (NIR) spectroscopic observations of Earth. These remote observations provide a rigorous validation of whole-disk Earth model simulations used to better understand remotely detectable extrasolar planet characteristics. We have used these data to upgrade, correct, and validate the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional line-by-line, multiple-scattering spectral Earth model. This comprehensive model now includes specular reflectance from the ocean and explicitly includes atmospheric effects such as Rayleigh scattering, gas absorption, and temperature structure. We have used this model to generate spatially and temporally resolved synthetic spectra and images of Earth for the dates of EPOXI observation. Model parameters were varied to yield an optimum fit to the data. We found that a minimum spatial resolution of ∼100 pixels on the visible disk, and four categories of water clouds, which were defined by using observed cloud positions and optical thicknesses, were needed to yield acceptable fits. The validated model provides a simultaneous fit to Earth's lightcurve, absolute brightness, and spectral data, with a root-mean-square (RMS) error of typically less than 3% for the multiwavelength lightcurves and residuals of ∼10% for the absolute brightness throughout the visible and NIR spectral range. We have extended our validation into the mid-infrared by comparing the model to high spectral resolution observations of Earth from the Atmospheric Infrared Sounder, obtaining a fit with residuals of ∼7% and brightness temperature errors of less than 1 K in the atmospheric window. For the purpose of understanding the observable characteristics of the distant Earth at arbitrary viewing geometry and observing cadence, our validated forward

Earth From Space: "Beautiful Earth's" Integration of Media Arts, Earth Science, and Native Wisdom in Informal Learning Environments

NASA Astrophysics Data System (ADS)

Casasanto, V.; Hallowell, R.; Williams, K.; Rock, J.; Markus, T.

2015-12-01

"Beautiful Earth: Experiencing and Learning Science in an Engaging Way" was a 3-year project funded by NASA's Competitive Opportunities in Education and Public Outreach for Earth and Space Science. An outgrowth of Kenji Williams' BELLA GAIA performance, Beautiful Earth fostered a new approach to teaching by combining live music, data visualizations and Earth science with indigenous perspectives, and hands-on workshops for K-12 students at 5 science centers. Inspired by the "Overview Effect," described by many astronauts who were awestruck by seeing the Earth from space and their realization of the profound interconnectedness of Earth's life systems, Beautiful Earth leveraged the power of multimedia performance to serve as a springboard to engage K-12 students in hands-on Earth science and Native wisdom workshops. Results will be presented regarding student perceptions of Earth science, environmental issues, and indigenous ways of knowing from 3 years of evaluation data.

Spectral characteristics of plasma sheet ion and electron populations during undisturbed geomagnetic conditions

NASA Technical Reports Server (NTRS)

Christon, S. P.; Williams, D. J.; Mitchell, D. G.; Frank, L. A.; Huang, C. Y.

1989-01-01

The spectral characteristics of plasma-sheet ion and electron populations during periods of low geomagnetic activity were determined from the analysis of 127 one-hour average samples of central plasma sheet ions and electrons. Particle data from the ISEE-1 low-energy proton and electron differential energy analyzer and medium-energy particle instrument were combined to obtain differential energy spectra in the plasma sheet at geocentric radial distances above 12 earth radii. The relationships between the ion and electron spectral shapes and between the spectral shapes and the geomagnetic activity index were statistically investigated. It was found that the presence of interplanetary particle fluxes does not affect the plasma sheet particle spectral shape.

MARCO POLO: near earth object sample return mission

NASA Astrophysics Data System (ADS)

Barucci, M. A.; Yoshikawa, M.; Michel, P.; Kawagushi, J.; Yano, H.; Brucato, J. R.; Franchi, I. A.; Dotto, E.; Fulchignoni, M.; Ulamec, S.

2009-03-01

MARCO POLO is a joint European-Japanese sample return mission to a Near-Earth Object. This Euro-Asian mission will go to a primitive Near-Earth Object (NEO), which we anticipate will contain primitive materials without any known meteorite analogue, scientifically characterize it at multiple scales, and bring samples back to Earth for detailed scientific investigation. Small bodies, as primitive leftover building blocks of the Solar System formation process, offer important clues to the chemical mixture from which the planets formed some 4.6 billion years ago. Current exobiological scenarios for the origin of Life invoke an exogenous delivery of organic matter to the early Earth: it has been proposed that primitive bodies could have brought these complex organic molecules capable of triggering the pre-biotic synthesis of biochemical compounds. Moreover, collisions of NEOs with the Earth pose a finite hazard to life. For all these reasons, the exploration of such objects is particularly interesting and urgent. The scientific objectives of MARCO POLO will therefore contribute to a better understanding of the origin and evolution of the Solar System, the Earth, and possibly Life itself. Moreover, MARCO POLO provides important information on the volatile-rich (e.g. water) nature of primitive NEOs, which may be particularly important for future space resource utilization as well as providing critical information for the security of Earth. MARCO POLO is a proposal offering several options, leading to great flexibility in the actual implementation. The baseline mission scenario is based on a launch with a Soyuz-type launcher and consists of a Mother Spacecraft (MSC) carrying a possible Lander named SIFNOS, small hoppers, sampling devices, a re-entry capsule and scientific payloads. The MSC leaves Earth orbit, cruises toward the target with ion engines, rendezvous with the target, conducts a global characterization of the target to select a sampling site, and delivers small

A novel coumarin Schiff-base as a Ni(II) ion colorimetric sensor

NASA Astrophysics Data System (ADS)

Wang, Lingyun; Ye, Decheng; Cao, Derong

2012-05-01

A novel coumarin Schiff base compound (L) prepared from 7-diethylaminocoumarin-3-aldehyde and 3-amino-7-hydroxycoumarin was synthesized and evaluated as a chemoselective Ni2+ sensor. Addition of Ni2+ to CH3CN solution of L resulted in a rapid color change from yellow to red together with a large red shift from 465 to 516 nm. Moreover, other common alkali-, alkaline earth-, transition- and rare earth metal ions induced no or minimal spectral changes. Experimental results indicated that L could be used as a potential Ni2+ colorimetric and naked-eye chemosensor in CH3CN solution.

The distribution of Sr and REE between diopside and silicate liquid. [Rare Earth Elements

NASA Technical Reports Server (NTRS)

Grutzeck, M.; Kridelbaugh, S.; Weill, D.

1974-01-01

Experimental determination of the distribution coefficients in diopside-liquid pairs for strontium and nine rare-earth elements in the system CaMgSi2O6-NaAlSi3O8-CaAl2Si2O8. In experiments in air at 1265 C it is found that most of the Sr(2+), Eu(2+), and RE(3+) ions substitute for Ca(2+) and, in addition, a coupled substitution of Al(3+) for Si(4+) occurs. All of the trace ions considered are found to be excluded from the diopside lattice relative to the liquid. In the case of the trivalent ions the exclusion is much more pronounced for La and Ce, which have ionic radii larger than that of Ca(2+) in 8-fold oxygen coordination. Divalent Sr and Eu with even larger radii are also strongly excluded.

Digital Earth - A sustainable Earth

NASA Astrophysics Data System (ADS)

Mahavir

2014-02-01

All life, particularly human, cannot be sustainable, unless complimented with shelter, poverty reduction, provision of basic infrastructure and services, equal opportunities and social justice. Yet, in the context of cities, it is believed that they can accommodate more and more people, endlessly, regardless to their carrying capacity and increasing ecological footprint. The 'inclusion', for bringing more and more people in the purview of development is often limited to social and economic inclusion rather than spatial and ecological inclusion. Economic investment decisions are also not always supported with spatial planning decisions. Most planning for a sustainable Earth, be at a level of rural settlement, city, region, national or Global, fail on the capacity and capability fronts. In India, for example, out of some 8,000 towns and cities, Master Plans exist for only about 1,800. A chapter on sustainability or environment is neither statutorily compulsory nor a norm for these Master Plans. Geospatial technologies including Remote Sensing, GIS, Indian National Spatial Data Infrastructure (NSDI), Indian National Urban Information Systems (NUIS), Indian Environmental Information System (ENVIS), and Indian National GIS (NGIS), etc. have potential to map, analyse, visualize and take sustainable developmental decisions based on participatory social, economic and social inclusion. Sustainable Earth, at all scales, is a logical and natural outcome of a digitally mapped, conceived and planned Earth. Digital Earth, in fact, itself offers a platform to dovetail the ecological, social and economic considerations in transforming it into a sustainable Earth.

Reconstructing Ion Spectra from Low-Altitude ENAs: Moderate to Large Storms.

NASA Astrophysics Data System (ADS)

LLera, K.; Goldstein, J.; McComas, D. J.; Valek, P. W.

2015-12-01

Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) Energetic neutral atom (ENA) imagers regularly observe Low-altitude Emission (LAE) intensifications during geomagnetic storm intervals. Since LAEs are produced by the interaction between ions and the near-Earth exosphere (altitudes ~200-800 km), they are a global signature of how the ring current decays in response to solar wind conditions. In this "optically thick" region, an ENA readily becomes reionized, and an ion is readily neutralized. Therefore, emerging ENAs that contribute to the LAE signal (detectable several RE away) have undergone multiple charge exchange and electron stripping interactions. Accounting for the ~36 eV energy loss per interaction, we developed a model to quantify the total energy lost by emergent LAEs. The analytical tool is applied to an ensemble of moderate to large storms (including the recent 17 March and 23 June storms in 2015) to reconstruct the parent ion spectra from TWINS ENA images. We examine the ion spectra energy characteristics among the various storm events.

Distribution of escaping ions produced by non-specular reflection at the stationary quasi-perpendicular shock front

NASA Astrophysics Data System (ADS)

Gedalin, M.; Liverts, M.; Balikhin, M. A.

2008-05-01

Field-aligned and gyrophase bunched ion beams are observed in the foreshock of the Earth bow shock. One of the mechanisms proposed for their production is non-specular reflection at the shock front. We study the distributions which are formed at the stationary quasi-perpendicular shock front within the same process which is responsible for the generation of reflected ions and transmitted gyrating ions. The test particle motion analysis in a model shock allows one to identify the parameters which control the efficiency of the process and the features of the escaping ion distribution. These parameters are: the angle between the shock normal and the upstream magnetic field, the ratio of the ion thermal velocity to the flow velocity upstream, and the cross-shock potential. A typical distribution of escaping ions exhibits a bimodal pitch angle distribution (in the plasma rest frame).

Low-energy near Earth asteroid capture using Earth flybys and aerobraking

NASA Astrophysics Data System (ADS)

Tan, Minghu; McInnes, Colin; Ceriotti, Matteo

2018-04-01

Since the Sun-Earth libration points L1 and L2 are regarded as ideal locations for space science missions and candidate gateways for future crewed interplanetary missions, capturing near-Earth asteroids (NEAs) around the Sun-Earth L1/L2 points has generated significant interest. Therefore, this paper proposes the concept of coupling together a flyby of the Earth and then capturing small NEAs onto Sun-Earth L1/L2 periodic orbits. In this capture strategy, the Sun-Earth circular restricted three-body problem (CRTBP) is used to calculate target Lypaunov orbits and their invariant manifolds. A periapsis map is then employed to determine the required perigee of the Earth flyby. Moreover, depending on the perigee distance of the flyby, Earth flybys with and without aerobraking are investigated to design a transfer trajectory capturing a small NEA from its initial orbit to the stable manifolds associated with Sun-Earth L1/L2 periodic orbits. Finally, a global optimization is carried out, based on a detailed design procedure for NEA capture using an Earth flyby. Results show that the NEA capture strategies using an Earth flyby with and without aerobraking both have the potential to be of lower cost in terms of energy requirements than a direct NEA capture strategy without the Earth flyby. Moreover, NEA capture with an Earth flyby also has the potential for a shorter flight time compared to the NEA capture strategy without the Earth flyby.

Compendium of Single Event Effects (SEE) Test Results for COTS and Standard Electronics for Low Earth Orbit and Deep Space Applications

NASA Technical Reports Server (NTRS)

Reddell, Brandon; Bailey, Chuck; Nguyen, Kyson; O'Neill, Patrick; Gaza, Razvan; Patel, Chirag; Cooper, Jaime; Kalb, Theodore

2017-01-01

We present the results of SEE testing with high energy protons and with low and high energy heavy ions. This paper summarizes test results for components considered for Low Earth Orbit and Deep Space applications.

Synthesis, characterization and thermal decomposition of tetramethylammonium rare earth double selenates

NASA Astrophysics Data System (ADS)

Divekar, Sandesh K.; Achary, S. Nagabhusan; Ajgaonkar, Vishnu R.

2018-06-01

A series of double selenates, as (CH3)4NLn(SeO4)2rad 4H2O (Ln = Rare earth ion like La, Pr, Nd, Sm, Gd, Tb, Dy) was crystallized from mixed solution and characterized in detail for their structure, vibrational and optical properties as well as thermal stabilities. The crystal structure of the praseodymium compound was obtained by single crystal X-ray diffraction (XRD) and revealed a monoclinic (C2/c) lattice with chains formed by PrO8 and SeO4 units. The chains with compositions [Pr(SeO4)4(H2O)4]- are stacked in three dimensions and the (CH3)4N+ ions located in between them provide charge neutrality to the structure. The characterization of other compounds were carried out from powder XRD data and revealed that they all are isostructural to Pr-compound. All the functional groups were identified by Raman and IR spectroscopic studies. Solid state 77Se NMR revealed noticeable changes in selenium environment in these compounds. The optical absorption studies on the compounds show strong band edge absorptions in UV region. Thermal stabilities of the compounds, as investigated by simultaneous TG-DTA techniques indicate their sequential decompositions due to loss of H2O, (CH3)4N+ group, SeO2 and finally leaving their corresponding rare earth oxides.

Ancient Earth, Alien Earths Event

NASA Image and Video Library

2014-08-20

Panelists pose for a group photo at the “Ancient Earth, Alien Earths” Event at NASA Headquarters in Washington, DC Wednesday, August 20, 2014. The event was sponsored by NASA, the National Science Foundation (NSF), and the Smithsonian Institution and highlighted how research on early Earth could help guide our search for habitable planets orbiting other stars. Photo Credit: (NASA/Aubrey Gemignani)

Ion propulsion engine installed on Deep Space 1 at CCAS

NASA Technical Reports Server (NTRS)

1998-01-01

Workers in the Defense Satellite Communications Systems Processing Facility (DPF) at Cape Canaveral Air Station (CCAS) finish installing the ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight-tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched Oct. 25 aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS.

Ion propulsion engine installed on Deep Space 1 at CCAS

NASA Technical Reports Server (NTRS)

1998-01-01

Workers at the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station (CCAS), install an ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight-tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS, in October.

Theoretical study of the BeLi, BeNa, MgLi, MgNa, and AlBe molecules and their negative ions

NASA Technical Reports Server (NTRS)

Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Partridge, Harry

1992-01-01

The alkaline earth-alkali diatomics are found to have weak bonds, because the diffuse alkali valence s orbitals cannot form a bond of sufficient strength to pay the promotion energy of the alkaline-earth atoms. This leads to van der Waals bonding in the neutrals as well as the negative ions. In fact, the negative ions have larger binding energies than the neutrals as a result of the much larger polarizability of the negative ion. The binding energy of AlBe is significantly larger than the Be-alkali molecules, due to a covalent contribution to the bonding. The binding energy in AlBe(-) is considerably larger than AlBe; the binding energy of the X 3Sigma(-) state of AlBe(-) is computed to be 1.36 eV, as compared with 0.57 eV for the X 2Pi state of AlBe.

Mars, Venus, Earth and Titan UV Laboratory Aeronomy by Electron Impact

NASA Astrophysics Data System (ADS)

Malone, C. P.; Ajello, J. M.; McClintock, W. E.; Eastes, R.; Evans, J. S.; Holsclaw, G.; Schneider, N. M.; Jain, S.; Gerard, J. C. M. C.; Hoskins, A.

2017-12-01

The UV response of the Mars, Earth, Titan and Venus upper atmospheres to the solar radiation fields [solar wind and solar EUV] is the focus of the present generation of Mars, Earth, Titan and Venus missions. These missions are Mars Express (MEX), the Mars Atmosphere and Volatile Evolution Mission (MAVEN), Cassini at Titan, Global-scale Observations of the Limb and Disk (GOLD) mission for Earth and Venus Express (VEX). Each spacecraft is equipped with a UV spectrometer that senses far ultraviolet (FUV) emissions from 110-190 nm, whose dayglow intensities are proportional to three quantities:1) particle (electron, ion) fluxes, 2) the altitude distribution of species in the ionosphere: CO, CO2, O, N2 at Venus and Mars and N2, O and O2 at Titan and Earth and 3) the emission cross section for the interaction process. UV spectroscopy provides a benchmark to the present space environment and indicates pathways for removing upper atmosphere gas (e.g., water escape from Mars and Earth) or N2 escape at Titan over eons. We present a UV laboratory program that utilizes an instrument, unique in the world, at the University of Colorado that can measure excitation mechanisms by particle (electron, ion) impact and the resulting emission cross sections that include processes occurring in a planetary atmosphere, particularly the optically forbidden emissions presented by the Cameron bands, the Lyman Birge Hopfield bands and the OI 135.6 nm multiplet. There are presently uncertainties by a factor of two in the existing measurements of the emission cross section, affecting modeling of electron transport. We have utilized the MAVEN Imaging Ultraviolet Spectrograph (IUVS) engineering model which operates at moderate spectral resolution ( 0.5-1.0nm FWHM) to obtain the full vibrational spectra of the Cameron band system CO(a 3Π → X 1Σ+) from both CO direct excitation and CO2 dissociative excitation, and for the dipole-allowed Fourth Positive band system of CO, while for N2 we have

Towards the development of new phosphors with reduced content of rare earth elements: Structural and optical characterization of Ce:Tb: Al{sub 2}SiO{sub 5}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiriu, D.; Stagi, L.; Carbonaro, C.M.

2016-05-15

Highlights: • A new promising inert matrix as host of luminescent ions is proposed. • Al2SiO5 matrix is free from Rare earths (critical raw materials). • Doping the matrix with Ce and Tb we obtain an efficient green emitter. • Cerium acts as sensitizer for Terbium emission. - Abstract: A new promising inert matrix as host of luminescent ions is proposed. Al2SiO5 samples, doped with rare earths (Ce, Tb single doped and co-doped) are proposed as good prospect for the development of new UV–vis converter with reduced content of rare earths elements. Structural characterization by Raman, XRD spectroscopy and TEMmore » imaging reveals the sillimanite phase and nano sized dimension of the investigated powders. Optical characterization by steady time and time resolved emission spectroscopy for the single doped and co-doped samples allows to identify an efficient energy transfer from Ce to Tb ions under near UV excitation wavelength. The intense green emission observed in the Ce:Tb co-doped Al2SiO5 system suggests its potential application as efficient blue pumped green emitter phosphor to be exploited for white LED: to this purpose we tested the compound in combination with a red emitting doping ion recording for Ce:Tb:Cr:ASO system a correlated color temperature of 6720 K.« less

The role of kinetic ion physics in the interaction of magnetic islands

NASA Astrophysics Data System (ADS)

Stanier, A.

2016-12-01

Magnetic islands are two-dimensional representations of magnetic flux-ropes, a fundamental building block of magnetized plasmas. Here we model magnetic reconnection during the coalescence of magnetic islands with a range of guide fields that have application to the Earth's magnetosphere. It is demonstrated that the Hall-MHD model is able to reproduce the reconnection rates of the fully kinetic system only in the presence of a fairly strong guide field (Bg≥ 3Bx). In the weak guide field limit non-isotropic ion pressure tensor effects that are missing from Hall-MHD are crucial to describe many key features of this reconnection test-problem [1], including the peak and average rates, pile-up field, outflow velocity, and global evolution of the system. A hybrid model which retains the full kinetic physics for ions along with mass-less fluid electrons gives good agreement with fully kinetic results for the full range of guide fields considered. These results suggest that kinetic ions may be important for a large number of reconnection events in the Earth's magnetosphere. References: [1] A. Stanier, W. Daughton, L. Chacon, H. Karimabadi, J. Ng, Y.-M. Huang, A. Hakim, and A. Bhattacharjee, Phys. Rev. Lett. 115, 175004 (2015).

Improving soft magnetic properties of Mn-Zn ferrite by rare earth ions doping

NASA Astrophysics Data System (ADS)

Zhong, X. C.; Guo, X. J.; Zou, S. Y.; Yu, H. Y.; Liu, Z. W.; Zhang, Y. F.; Wang, K. X.

2018-04-01

Mn-Zn ferrites doped with different Sm2O3, Gd2O3, Ce2O3 or Y2O3 were prepared by traditional ceramic technology using industrial pre-sintered powders. A small amount of Sm2O3, Gd2O3, Ce2O3 or Y2O3 can significantly improve the microstructure and magnetic properties. The single spinel phase structure can be maintained with the doping amount up to 0.07 wt.%. A refined grain structure and uniform grain size distribution can be obtained by doping. For all rare earth oxides, a small amount of doping can significantly increase the permeability and reduce the coercivity and magnetic core loss. The optimized doping amount for Sm2O3 or Gd2O3 is 0.01 wt.%, while for Ce2O3 or Y2O3 is 0.03 wt.%. A further increase of the doping content will lead to reduced soft magnetic properties. The ferrite sample with 0.01 wt.% Sm2O3 exhibits the good magnetic properties with permeability, loss, and coercivity of 2586, 316 W/kg, and 24A/m, respectively, at 200 mT and 100 kHz. The present results indicate that rare earth doping can be suggested to be one of the effective ways to improve the performance of soft ferrites.

Preliminary results from the heavy ions in space experiment

NASA Technical Reports Server (NTRS)

Adams, James H., Jr.; Beahm, Lorraine P.; Tylka, Allan J.

1992-01-01

The Heavy Ions In Space (HIIS) experiment has two primary objectives: (1) to measure the elemental composition of ultraheavy galactic cosmic rays, beginning in the tin-barium region of the periodic table; and (2) to study heavy ions which arrive at LDEF below the geomagnetic cutoff, either because they are not fully stripped of electrons or because their source is within the magnetosphere. Both of these objectives have practical as well as astrophysical consequences. In particular, the high atomic number of the ultraheavy galactic cosmic rays puts them among the most intensely ionizing particles in Nature. They are therefore capable of upsetting electronic components normally considered immune to such effects. The below cutoff heavy ions are intensely ionizing because of their low velocity. They can be a significant source of microelectronic anomalies in low inclination orbits, where Earth's magnetic field protects satellites from most particles from interplanetary space. The HIIS results will lead to significantly improved estimates of the intensely ionizing radiation environment.

Fundamental Investigation of Si Anode in Li-Ion Cells

NASA Technical Reports Server (NTRS)

Wu, James J.; Bennett, William R.

2012-01-01

Silicon is a promising and attractive anode material to replace graphite for high capacity lithium ion cells since its theoretical capacity is approximately 10 times of graphite and it is an abundant element on earth. However, there are challenges associated with using silicon as Li-ion anode due to the significant first cycle irreversible capacity loss and subsequent rapid capacity fade during cycling. In this paper, cyclic voltammetry and electrochemical impedance spectroscopy are used to build a fundamental understanding of silicon anodes. The results show that it is difficult to form the SEI film on the surface of Si anode during the first cycle, the lithium ion insertion and de-insertion kinetics for Si are sluggish, and the cell internal resistance changes with the state of lithiation after electrochemical cycling. These results are compared with those for extensively studied graphite anodes. The understanding gained from this study will help to design better Si anodes.

Particle injection and acceleration at earth's bow shock - Comparison of upstream and downstream events

NASA Technical Reports Server (NTRS)

Ellison, Donald C.; Moebius, Eberhard; Paschmann, Goetz