Sample records for eastern devonian gas
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.
This document consists of the following papers: inorganic geochemistry studies of the Eastern Kentucky Gas Field; lithology studies of upper Devonian well cuttings in the Eastern Kentucky Gas Field; possible effects of plate tectonics on the Appalachian Devonian black shale production in eastern Kentucky; preliminary depositional model for upper Devonian Huron age organic black shale in the Eastern Kentucky Gas Field; the anatomy of a large Devonian black shale gas field; the Cottageville (Mount Alto) Gas Field, Jackson County, West Virginia: a case study of Devonian shale gas production; the Eastern Kentucky Gas Field: a geological study of the relationshipsmore » of Ohio Shale gas occurrences to structure, stratigraphy, lithology, and inorganic geochemical parameters; and a statistical analysis of geochemical data for the Eastern Kentucky Gas Field.« less
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Frankie, W.T.
The Kentucky Geological Survey (KGS) at the University of Kentucky is conducting a 2-year research project funded by the Gas Research Institute (GRI) to study hydrocarbon production from the Devonian shale in eastern Kentucky. Objectives are to develop an understanding of relationships between stratigraphy and hydrocarbon production, create a data base, and prepare geologic reports for each county in the study area. Data were compiled from the KGS, GRI Eastern Gas Data System (EGDS), U. S. Department of Energy (DOE), and industry. Research for Letcher County was completed and 270 Devonian wells were entered into the KGS computer data base.more » Devonian black-shale units were correlated using gamma-ray logs. Structure and isopach maps, and stratigraphic cross sections have been constructed. An isopotential map defining areas of equal initial gas production has been prepared. Statistics for Letcher County have been run on the data base using Datatrieve software package. Statistical analyses focused on different types of formation treatments and the resulting production. Temperature logs were used to detect gas-producing intervals within the Mississippian-Devonian black-shale sequence. The results of the research provide the petroleum industry with a valuable tool for gas exploration in the Devonian shales.« less
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Hydrocarbon potential of Upper Devonian black shale, eastern Kentucky
DOE Office of Scientific and Technical Information (OSTI.GOV)
Johnston, I.M.; Frankie, W.T.; Moody, J.R.
The gas-producing Upper Devonian black shales of eastern Kentucky represent cycles of organic units alternating with less-organic units that were dominated by an influx of clastics from a northeastern source. This pattern of sedimentation is typical throughout the southern Appalachian basin in areas basinal to, yet still influenced by, the Catskill delta to the northwest. These black shales, which thin westward onto the Cincinnati arch, dip eastward into the Appalachian basin. To evaluate the future gas potential of Devonian shale, a data base has been compiled, consisting of specific geologic and engineering information from 5920 Devonian shale wells in Letcher,more » Knott, Floyd, Martin, and Pike Counties, Kentucky. The first successful gas completion in eastern Kentucky was drilled in Martin County in 1901. Comparison of initial open-flow potential (IP) and long-term production data for these wells demonstrates that higher IP values generally indicate wells of higher production potential. Areas of higher IP are aligned linearly, and these lineaments are interpreted to be related to fracture systems within the Devonian shale. These fractures may be basement influenced. Temperature log analyses indicate that the greatest number of natural gas shows occur in the lower Huron Member of the Ohio Shale. Using both the temperature log to indicate gas shows and the gamma-ray log to determine the producing unit is a workable method for selecting the interval for treatment.« less
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Eastern Devonian shales: Organic geochemical studies, past and present
Breger, I.A.; Hatcher, P.G.; Romankiw, L.A.; Miknis, F.P.
1983-01-01
The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Ilinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of the fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales will be reviewed. Recent solid state 13C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a "coaly" nature and hence more prone to producing natural gas.
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Eastern Devonian shales: Organic geochemical studies
DOE Office of Scientific and Technical Information (OSTI.GOV)
Berger, I.A.; Hatchner, P.G.; Miknis, F.P.
The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Illinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of themore » fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales are reviewed. Recent solid state /sup 13/C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a ''coaly'' nature and hence more prone to producing natural gas.« less
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West, Mareta N.
1978-01-01
The U.S. Geological Survey (USGS), in a cooperative agreement with the U.S. Department of Energy (DOE), is participating in the Eastern Gas Shales Project. The purpose of the DOE project is to increase the production of natural gas from eastern United States shales in petroliferous basins through improved exploration and extraction techniques. The USGS participation includes stratigraphic studies which will contribute to the characterization and appraisal of the natural gas resources of Devonian shale in the Appalachian basin.This cross section differs from others in this series partly because many of the shales in the eastern part of the basin are less radioactive than those farther west and because in this area shales that may be gas-productive are not necessarily highly radioactive and black.
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The Devonian Marcellus Shale and Millboro Shale
Soeder, Daniel J.; Enomoto, Catherine B.; Chermak, John A.
2014-01-01
The recent development of unconventional oil and natural gas resources in the United States builds upon many decades of research, which included resource assessment and the development of well completion and extraction technology. The Eastern Gas Shales Project, funded by the U.S. Department of Energy in the 1980s, investigated the gas potential of organic-rich, Devonian black shales in the Appalachian, Michigan, and Illinois basins. One of these eastern shales is the Middle Devonian Marcellus Shale, which has been extensively developed for natural gas and natural gas liquids since 2007. The Marcellus is one of the basal units in a thick Devonian shale sedimentary sequence in the Appalachian basin. The Marcellus rests on the Onondaga Limestone throughout most of the basin, or on the time-equivalent Needmore Shale in the southeastern parts of the basin. Another basal unit, the Huntersville Chert, underlies the Marcellus in the southern part of the basin. The Devonian section is compressed to the south, and the Marcellus Shale, along with several overlying units, grades into the age-equivalent Millboro Shale in Virginia. The Marcellus-Millboro interval is far from a uniform slab of black rock. This field trip will examine a number of natural and engineered exposures in the vicinity of the West Virginia–Virginia state line, where participants will have the opportunity to view a variety of sedimentary facies within the shale itself, sedimentary structures, tectonic structures, fossils, overlying and underlying formations, volcaniclastic ash beds, and to view a basaltic intrusion.
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Milici, Robert C.; Swezey, Christopher S.; Ruppert, Leslie F.; Ryder, Robert T.
2014-01-01
This report presents the results of a U.S. Geological Survey (USGS) assessment of the technically recoverable undiscovered natural gas resources in Devonian shale in the Appalachian Basin Petroleum Province of the eastern United States. These results are part of the USGS assessment in 2002 of the technically recoverable undiscovered oil and gas resources of the province. This report does not use the results of a 2011 USGS assessment of the Devonian Marcellus Shale because the area considered in the 2011 assessment is much greater than the area of the Marcellus Shale described in this report. The USGS assessment in 2002 was based on the identification of six total petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian gas shales described in this report are within the Devonian Shale-Middle and Upper Paleozoic Total Petroleum System, which extends generally from New York to Tennessee. This total petroleum system is divided into ten assessment units (plays), four of which are classified as conventional and six as continuous. The Devonian shales described in this report make up four of these continuous assessment units. The assessment results are reported as fully risked fractiles (F95, F50, F5, and the mean); the fractiles indicate the probability of recovery of the assessment amount. The products reported are oil, gas, and natural gas liquids. The mean estimates for technically recoverable undiscovered hydrocarbons in the four gas shale assessment units are 12,195.53 billion cubic feet (12.20 trillion cubic feet) of gas and 158.91 million barrels of natural gas liquids
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
To evaluate the potential of the Devonian shale as a source of natural gas, the US Department of Energy (DOE) has undertaken the Eastern Gas Shales Project (EGSP). The EGSP is designed not only to identify the resource, but also to test improved methods of inducing permeability to facilitate gas drainage, collection, and production. The ultimate goal of this project is to increase the production of gas from the eastern shales through advanced exploration and exploitation techniques. The purpose of this report is to inform the general public and interested oil and gas operators about EGSP results as they pertainmore » to the Devonian gas shales of the Appalachian basin in Pennsylvania. Geologic data and interpretations are summarized and areas where the accumulation of gas may be large enough to justify commercial production are outlined. Because the data presented in this report are generalized and not suitable for evaluation of specific sites for exploration, the reader should consult the various reports cited for more detail and discussion of the data, concepts, and interpretations presented.« less
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East, Joseph A.; Swezey, Christopher S.; Repetski, John E.; Hayba, Daniel O.
2012-01-01
Much of the oil and gas in the Illinois, Michigan, and Appalachian basins of eastern North America is thought to be derived from Devonian shale that is within these basins (for example, Milici and others, 2003; Swezey, 2002, 2008, 2009; Swezey and others, 2005, 2007). As the Devonian strata were buried by younger sediments, the Devonian shale was subjected to great temperature and pressure, and in some areas the shale crossed a thermal maturity threshold and began to generate oil. With increasing burial (increasing temperature and pressure), some of this oil-generating shale crossed another thermal maturity threshold and began to generate natural gas. Knowledge of the thermal maturity of the Devonian shale is therefore useful for predicting the occurrence and the spatial distribution of oil and gas within these three basins. This publication presents a thermal maturity map of Devonian shale in the Illinois, Michigan, and Appalachian basins. The map shows outlines of the three basins (dashed black lines) and an outline of Devonian shale (solid black lines). The basin outlines are compiled from Thomas and others (1989) and Swezey (2008, 2009). The outline of Devonian shale is a compilation from Freeman (1978), Thomas and others (1989), de Witt and others (1993), Dart (1995), Nicholson and others (2004), Dicken and others (2005a,b), and Stoeser and others (2005).
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History of gas production from Devonian shale in eastern Kentucky
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kemper, J.R.; Frankie, W.T.; Smath, R.A.
More than 10,500 wells that penetrate the Devonian shale have been compiled into a data base covering a 25-county area of eastern Kentucky. This area includes the Big Sandy gas field, the largest in the Appalachian basin, and marginal areas to the southwest, west, and northwest. The development of the Big Sandy gas field began in the 1920s in western Floyd County, Kentucky, and moved concentrically outward through 1970. Since 1971, the trend has been for infill and marginal drilling, and fewer companies have been involved. The resulting outline of the Big Sandy gas field covers most of Letcher, Knott,more » Floyd, Martin, and Pike Counties in Kentucky; it also extends into West Virginia. Outside the Big Sandy gas field, exploration for gas has been inconsistent, with a much higher ratio of dry holes. The results of this study, which was partially supported by the Gas Research Institute (GRI), indicate that certain geologic factors, such as fracture size and spacing, probably determine the distribution of commercial gas reserves as well as the outline of the Big Sandy gas field. Future Big Sandy infill and extension drilling will need to be based on an understanding of these factors.« less
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Coleman, James L.; Milici, Robert C.; Cook, Troy A.; Charpentier, Ronald R.; Kirshbaum, Mark; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.
2011-01-01
Using a geology-based assessment methodology, the U.S. Geological Survey (USGS) estimated a mean undiscovered natural gas resource of 84,198 billion cubic feet and a mean undiscovered natural gas liquids resource of 3,379 million barrels in the Devonian Marcellus Shale within the Appalachian Basin Province. All this resource occurs in continuous accumulations. In 2011, the USGS completed an assessment of the undiscovered oil and gas potential of the Devonian Marcellus Shale within the Appalachian Basin Province of the eastern United States. The Appalachian Basin Province includes parts of Alabama, Georgia, Kentucky, Maryland, New York, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The assessment of the Marcellus Shale is based on the geologic elements of this formation's total petroleum system (TPS) as recognized in the characteristics of the TPS as a petroleum source rock (source rock richness, thermal maturation, petroleum generation, and migration) as well as a reservoir rock (stratigraphic position and content and petrophysical properties). Together, these components confirm the Marcellus Shale as a continuous petroleum accumulation. Using the geologic framework, the USGS defined one TPS and three assessment units (AUs) within this TPS and quantitatively estimated the undiscovered oil and gas resources within the three AUs. For the purposes of this assessment, the Marcellus Shale is considered to be that Middle Devonian interval that consists primarily of shale and lesser amounts of bentonite, limestone, and siltstone occurring between the underlying Middle Devonian Onondaga Limestone (or its stratigraphic equivalents, the Needmore Shale and Huntersville Chert) and the overlying Middle Devonian Mahantango Formation (or its stratigraphic equivalents, the upper Millboro Shale and middle Hamilton Group).
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Enomoto, Catherine B.; Coleman, James L.; Haynes, John T.; Whitmeyer, Steven J.; McDowell, Ronald R.; Lewis, J. Eric; Spear, Tyler P.; Swezey, Christopher S.
2012-01-01
Detailed and reconnaissance field mapping and the results of geochemical and mineralogical analyses of outcrop samples indicate that the Devonian shales of the Broadtop Synclinorium from central Virginia to southern Pennsylvania have an organic content sufficiently high and a thermal maturity sufficiently moderate to be considered for a shale gas play. The organically rich Middle Devonian Marcellus Shale is present throughout most of the synclinorium, being absent only where it has been eroded from the crests of anticlines. Geochemical analyses of outcrop and well samples indicate that hydrocarbons have been generated and expelled from the kerogen originally in place in the shale. The mineralogical characteristics of the Marcellus Shale samples from the Broadtop Synclinorium are slightly different from the averages of samples from New York, Pennsylvania, northeast Ohio, and northern West Virginia. The Middle Devonian shale interval is moderately to heavily fractured in all areas, but in some areas substantial fault shearing has removed a regular "cleat" system of fractures. Conventional anticlinal gas fields in the study area that are productive from the Lower Devonian Oriskany Sandstone suggest that a continuous shale gas system may be in place within the Marcellus Shale interval at least in a portion of the synclinorium. Third-order intraformational deformation is evident within the Marcellus shale exposures. Correlations between outcrops and geophysical logs from exploration wells nearby will be examined by field trip attendees.
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Biogeography of late Silurian and devonian rugose corals
Oliver, W.A.
1977-01-01
Three marine benthic faunal realms can be recognized in the Early and Middle Devonian. The Eastern Americas Realm consisted of most of the eastern half of North America and South America north of the Amazon. This realm extended in a southwest direction from the Devonian equator to approximately 35??S and was an isolated epicontinental sea during much of its history. The Eastern Americas Realm was bounded on the west by the Transcontinental Arch, on the north by the Canadian Shield and on the east and southeast by a peninsular extension of the Old Red Continent. These barriers were emergent during much, but not all, of Devonian time. Seaways beyond these barriers belonged to the Old World Realm. The Malvinokaffric Realm that was farther south was apparently temperate to arctic in climate and latitudinal position and contained few corals. Rugose corals in the Eastern Americas Realm show increasing generic-level endemism from the Late Silurian through the Early Devonian; during the late Early Devonian, 92% of the rugosan genera are not known anywhere else in the world. Endemism decreased through the Middle Devonian to zero in the early Late Devonian. The Early Devonian increase in endemism paralleled, and was probably related to, the development of the Old Red Continent as a barrier between America and Africa-Europe. The waning of endemism in the Middle Devonian reflects the breaching of the land barriers. This permitted some migration in and out of the realm in early Middle Devonian time but greatest movements were in late Middle Devonian time. Principal migration directions were from western or Arctic North America into the Michigan-Hudson Bay area and from the southern Appalachian area into Africa. ?? 1977.
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Drilling of a deviated well: E. C. Newell 10056-D Meigs County, Ohio
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rodgers, J.A.
1982-09-30
The Department of Energy's (DOE) Eastern Gas Shales Program (EGSP) has focused primarily on the resource characterization of the Devonian shales in the Appalachian, Michigan and Illinois Basins, where the collective volume of gas in place is estimated to be on the order of 280 Tcf. From an early assessment of the petrophysical properties of these shales, attention now has turned to an understanding of the mechanisms controlling production of this unconventional-gas source. However, present knowledge of the production history of the Devonian shales is inadequate for an accurate estimation of the gas reserves, the optimum well spacing for gasmore » extraction, and the preferred stimulation techniques to be used. As part of this program, a Deviated Well Test was designed to evaluate the spacing of natural fractures in the Devonian shale in Meigs County, Ohio as a follow-on test to further define shale production characteristics and to assess the benefit of additional section gained by drilling through the producing interval at the approximate angle for dip of 60/sup 0/ from vertical. The Columbia Gas Transmission Company, E.C. Newell 10056-D well, on the same site as a previous Off-Set Well Test, was selected for this investigation. This report summarizes drilling operations on this Deviated Well Test.« less
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Stage boundary recognition in the Eastern Americas realm based on rugose corals
Oliver, W.A.
2000-01-01
Most Devonian stages contain characteristic coral assemblages but these tend to be geographically and facies limited and may or may not be useful for recognising stage boundaries. Within eastern North America, corals contribute to the recognition of two boundaries: the base of the Lochkovian (Silurian-Devonian boundary) and the base of the Eifelian (Lower-Middle Devonian Series boundary).
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Dyman, T.S.; Wilcox, L.A.
1983-01-01
The U.S. Geological Survey and Petroleum Information Corporation in Denver, Colorado, developed the Eastern Gas Shale Project (EGSP)Data System for the U.S. Department of Energy, Morgantown, West Virginia. Geological, geochemical, geophysical, and engineering data from Devonian shale samples from more than 5800 wells and outcrops in the Appalachian basin were edited and converted to a Petroleum Information Corporation data base. Well and sample data may be retrieved from this data system to produce (1)production-test summaries by formation and well location; (2)contoured isopach, structure, and trendsurface maps of Devonian shale units; (3)sample summary reports for samples by location, well, contractor, and sample number; (4)cross sections displaying digitized log traces, geochemical, and lithologic data by depth for wells; and (5)frequency distributions and bivariate plots. Although part of the EGSP Data System is proprietary, and distribution of complete well histories is prohibited by contract, maps and aggregated well-data listings are being made available to the public through published reports. ?? 1983 Plenum Publishing Corporation.
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Strapoc, D.; Mastalerz, Maria; Schimmelmann, A.; Drobniak, A.; Hasenmueller, N.R.
2010-01-01
This study involved analyses of kerogen petrography, gas desorption, geochemistry, microporosity, and mesoporosity of the New Albany Shale (Devonian-Mississippian) in the eastern part of the Illinois Basin. Specifically, detailed core analysis from two locations, one in Owen County, Indiana, and one in Pike County, Indiana, has been conducted. The gas content in the locations studied was primarily dependent on total organic carbon content and the micropore volume of the shales. Gas origin was assessed using stable isotope geochemistry. Measured and modeled vitrinite reflectance values were compared. Depth of burial and formation water salinity dictated different dominant origins of the gas in place in the two locations studied in detail. The shallower Owen County location (415-433 m [1362-1421 ft] deep) contained significant additions of microbial methane, whereas the Pike County location (832-860 m [2730-2822 ft] deep) was characterized exclusively by thermogenic gas. Despite differences in the gas origin, the total gas in both locations was similar, reaching up to 2.1 cm3/g (66 scf/ton). Lower thermogenic gas content in the shallower location (lower maturity and higher loss of gas related to uplift and leakage via relaxed fractures) was compensated for by the additional generation of microbial methane, which was stimulated by an influx of glacial melt water, inducing brine dilution and microbial inoculation. The characteristics of the shale of the Maquoketa Group (Ordovician) in the Pike County location are briefly discussed to provide a comparison to the New Albany Shale. Copyright ??2010. The American Association of Petroleum Geologists. All rights reserved.
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Geology of the Devonian black shales of the Appalachian basin
Roen, J.B.
1983-01-01
Black shales of Devonian age in the Appalachian basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. Concurrent with periodic and varied economic exploitations of the black shales are geologic studies. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies produced a regional stratigraphic network that correlates the 15-foot sequence in Tennessee with 3,000 feet of interbedded black and gray shales in central New York. The classic Devonian black-shale sequence in New York has been correlated with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long range correlations within the Appalachian basin and provided a basis for correlations with the black shales of the Illinois and Michigan basins. Areal distribution of selected shale units along with paleocurrent studies, clay mineralogy, and geochemistry suggests variations in the sediment source and transport directions. Current structures, faunal evidence, lithologic variations, and geochemical studies provide evidence to support interpretation of depositional environments. In addition, organic geochemical data combined with stratigraphic and structural characteristics of the shale within the basin allow an evaluation of the resource potential of natural gas in the Devonian shale sequence.
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Devonian-Carboniferous boundary succession in Eastern Taurides, Turkey
NASA Astrophysics Data System (ADS)
Atakul-Özdemir, Ayşe; Altıner, Demir; Özkan-Altıner, Sevinç
2015-04-01
The succession covering the Devonian-Carboniferous boundary in Eastern Taurides comprises mainly limestones, shales and siltstones. The studied section starts at the base with bioturbated limestones alternating with shales and is followed upwards by platy limestones, and continues with the alternations of bioturbated and platy limestones. Towards the upper part of the succession the alternations of limestone, shales and siltstones reappear again and the top of the section is capped by quartz arenitic sandstone. The studied section spanning the Uppermost Devonian-Lower Carboniferous interval yields a not very abundant, but quite important assemblage of conodont taxa including species of Bispathodus, Polygnathus, Palmatolepis, Spathognathodus and Vogelgnathus. The uppermost Devonian part of the succession is characterized by the presence of Bispathodus costatus, Bispathodus aculeatus aculeatus, Polygnathus communis communis, Palmatolepis gracilis gracilis and Spathognathodus sp.. The Lower Carboniferous in the studied section is represented by the appearance of Polygnathus inornatus and Polygnathus communis communis. Based on the recovered conodont assemblages, Devonian-Carboniferous boundary in Eastern Turides has been determined by the appearance and disappearance of major conodont species.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Godec, Michael
Building upon advances in technology, production of natural gas from organic-rich shales is rapidly developing as a major hydrocarbon supply option in North America and around the world. The same technology advances that have facilitated this revolution - dense well spacing, horizontal drilling, and hydraulic fracturing - may help to facilitate enhanced gas recovery (EGR) and carbon dioxide (CO 2) storage in these formations. The potential storage of CO 2 in shales is attracting increasing interest, especially in Appalachian Basin states that have extensive shale deposits, but limited CO 2 storage capacity in conventional reservoirs. The goal of this cooperativemore » research project was to build upon previous and on-going work to assess key factors that could influence effective EGR, CO 2 storage capacity, and injectivity in selected Eastern gas shales, including the Devonian Marcellus Shale, the Devonian Ohio Shale, the Ordovician Utica and Point Pleasant shale and equivalent formations, and the late Devonian-age Antrim Shale. The project had the following objectives: (1) Analyze and synthesize geologic information and reservoir data through collaboration with selected State geological surveys, universities, and oil and gas operators; (2) improve reservoir models to perform reservoir simulations to better understand the shale characteristics that impact EGR, storage capacity and CO 2 injectivity in the targeted shales; (3) Analyze results of a targeted, highly monitored, small-scale CO 2 injection test and incorporate into ongoing characterization and simulation work; (4) Test and model a smart particle early warning concept that can potentially be used to inject water with uniquely labeled particles before the start of CO 2 injection; (5) Identify and evaluate potential constraints to economic CO 2 storage in gas shales, and propose development approaches that overcome these constraints; and (6) Complete new basin-level characterizations for the CO 2 storage capacity and injectivity potential of the targeted eastern shales. In total, these Eastern gas shales cover an area of over 116 million acres, may contain an estimated 6,000 trillion cubic feet (Tcf) of gas in place, and have a maximum theoretical storage capacity of over 600 million metric tons. Not all of this gas in-place will be recoverable, and economics will further limit how much will be economic to produce using EGR techniques with CO 2 injection. Reservoir models were developed and simulations were conducted to characterize the potential for both CO 2 storage and EGR for the target gas shale formations. Based on that, engineering costing and cash flow analyses were used to estimate economic potential based on future natural gas prices and possible financial incentives. The objective was to assume that EGR and CO 2 storage activities would commence consistent with the historical development practices. Alternative CO 2 injection/EGR scenarios were considered and compared to well production without CO 2 injection. These simulations were conducted for specific, defined model areas in each shale gas play. The resulting outputs were estimated recovery per typical well (per 80 acres), and the estimated CO 2 that would be injected and remain in the reservoir (i.e., not produced), and thus ultimately assumed to be stored. The application of this approach aggregated to the entire area of the four shale gas plays concluded that they contain nearly 1,300 Tcf of both primary production and EGR potential, of which an estimated 460 Tcf could be economic to produce with reasonable gas prices and/or modest incentives. This could facilitate the storage of nearly 50 Gt of CO 2 in the Marcellus, Utica, Antrim, and Devonian Ohio shales.« less
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18 CFR 270.303 - Natural gas produced from Devonian shale.
Code of Federal Regulations, 2013 CFR
2013-04-01
... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...
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18 CFR 270.303 - Natural gas produced from Devonian shale.
Code of Federal Regulations, 2012 CFR
2012-04-01
... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...
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18 CFR 270.303 - Natural gas produced from Devonian shale.
Code of Federal Regulations, 2014 CFR
2014-04-01
... from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Natural gas produced from Devonian shale. 270.303 Section 270.303 Conservation of Power and Water Resources FEDERAL ENERGY...
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18 CFR 270.303 - Natural gas produced from Devonian shale.
Code of Federal Regulations, 2010 CFR
2010-04-01
... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...
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18 CFR 270.303 - Natural gas produced from Devonian shale.
Code of Federal Regulations, 2011 CFR
2011-04-01
... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Natural gas produced... DETERMINATION PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.303 Natural gas produced from Devonian shale. A person seeking a determination that natural gas is produced from Devonian shale...
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Sedimentology of gas-bearing Devonian shales of the Appalachian Basin
NASA Astrophysics Data System (ADS)
Potter, P. E.; Maynard, J. B.; Pryor, W. A.
1981-01-01
Sedimentology of the Devonian shales and its relationship to gas, oil, and uranium are reported. Information about the gas bearing Devonian shales of the Appalachian Basin is organized in the following sections: paleogeography and basin analysis; lithology and internal stratigraphy; paleontology; mineralogy, petrology, and chemistry; and gas oil, and uranium.
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Geology of the Devonian black shales of the Appalachian Basin
Roen, J.B.
1984-01-01
Black shales of Devonian age in the Appalachian Basin are a unique rock sequence. The high content of organic matter, which imparts the characteristic lithology, has for years attracted considerable interest in the shales as a possible source of energy. The recent energy shortage prompted the U.S. Department of Energy through the Eastern Gas Shales Project of the Morgantown Energy Technology Center to underwrite a research program to determine the geologic, geochemical, and structural characteristics of the Devonian black shales in order to enhance the recovery of gas from the shales. Geologic studies by Federal and State agencies and academic institutions produced a regional stratigraphic network that correlates the 15 ft black shale sequence in Tennessee with 3000 ft of interbedded black and gray shales in central New York. These studies correlate the classic Devonian black shale sequence in New York with the Ohio Shale of Ohio and Kentucky and the Chattanooga Shale of Tennessee and southwestern Virginia. Biostratigraphic and lithostratigraphic markers in conjunction with gamma-ray logs facilitated long-range correlations within the Appalachian Basin. Basinwide correlations, including the subsurface rocks, provided a basis for determining the areal distribution and thickness of the important black shale units. The organic carbon content of the dark shales generally increases from east to west across the basin and is sufficient to qualify as a hydrocarbon source rock. Significant structural features that involve the black shale and their hydrocarbon potential are the Rome trough, Kentucky River and Irvine-Paint Creek fault zone, and regional decollements and ramp zones. ?? 1984.
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Rowan, E.L.; Kraemer, T.F.
2012-01-01
Samples of natural gas were collected as part of a study of formation water chemistry in oil and gas reservoirs in the Appalachian Basin. Nineteen samples (plus two duplicates) were collected from 11 wells producing gas from Upper Devonian sandstones and the Middle Devonian Marcellus Shale in Pennsylvania. The samples were collected from valves located between the wellhead and the gas-water separator. Analyses of the radon content of the gas indicated 222Rn (radon-222) activities ranging from 1 to 79 picocuries per liter (pCi/L) with an overall median of 37 pCi/L. The radon activities of the Upper Devonian sandstone samples overlap to a large degree with the activities of the Marcellus Shale samples.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Skrinak, V.M.
The Eastern Devonian Gas Shales Technology Review is a technology transfer vehicle designed to keep industry and research organizations aware of major happenings in the shales. Four issues were published, and the majority of the readership was found to be operators. Under the other major task in this project, areal and analytic analyses of the basin resulted in reducing the study area by 30% while defining a rectangular coordinate system for the basin. Shale-well cost and economic models were developed and validated, and a simplified flow model was prepared.
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Eastern Madre de Dios Devonian generated large volumes of oil
DOE Office of Scientific and Technical Information (OSTI.GOV)
Peters, K.E.; Wagner, J.B.; Carpenter, D.G.
This is the second part of an article giving details of a Mobil Corp. regional geological, geophysical, and geochemical study of the Madre de Dios basin. The assessment covered the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks.
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Brezinski, D.K.; Cecil, C.B.; Skema, V.W.
2010-01-01
Late Devonian strata in the eastern United States are generally considered as having been deposited under warm tropical conditions. However, a stratigraphically restricted Late Devonian succession of diamictite- mudstonesandstone within the Spechty Kopf and Rockwell Formations that extends for more than 400 km along depositional strike within the central Appalachian Basin may indicate other wise. This lithologic association unconformably overlies the Catskill Formation, where a 3- to 5-m-thick interval of deformed strata occurs immediately below the diamictite strata. The diamictite facies consists of several subfacies that are interpreted to be subglacial, englacial, supraglacial meltout, and resedimented deposits. The mudstone facies that overlies the diamictite consists of subfacies of chaotically bedded, clast-poor mudstone, and laminated mudstone sub facies that represent subaqueous proximal debris flows and distal glaciolacustrine rhythmites or varvites, respectively. The pebbly sandstone facies is interpreted as proglacial braided outwash deposits that both preceded glacial advance and followed glacial retreat. Both the tectonic and depositional frameworks suggest that the facies were deposited in a terrestrial setting within the Appalachian foreland basin during a single glacial advance and retreat. Regionally, areas that were not covered by ice were subject to increased rainfall as indicated by wet-climate paleosols. River systems eroded deeper channels in response to sea-level drop during glacial advance. Marine facies to the west contain iceborne dropstone boulders preserved within contemporaneous units of the Cleveland Shale Member of the Ohio Shale.The stratigraphic interval correlative with sea-level drop, climate change, and glacigenic succession represents one of the Appalachian Basin's most prolific oil-and gas-producing intervals and is contemporaneous with a global episode of sea-level drop responsible for the deposition of the Hangenberg Shale/Sandstone of Europe. This interval records the Hangenberg biotic crisis near the Devonian-Carboniferous boundary. ?? 2009 Geological Society of America.
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Breen, Kevin J.; Revesz, Kinga; Baldassare, Fred J.; McAuley, Steven D.
2007-01-01
In January 2001, State oil and gas inspectors noted bubbles of natural gas in well water during a complaint investigation near Tioga Junction, Tioga County, north-central Pa. By 2004, the gas occurrence in ground water and accumulation in homes was a safety concern; inspectors were taking action to plug abandoned gas wells and collect gas samples. The origins of the natural-gas problems in ground water were investigated by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection, in wells throughout an area of about 50 mi2, using compositional and isotopic characteristics of methane and ethane in gas and water wells. This report presents the results for gas-well and water-well samples collected from October 2004 to September 2005. Ground water for rural-domestic supply and other uses near Tioga Junction is from two aquifer systems in and adjacent to the Tioga River valley. An unconsolidated aquifer of outwash sand and gravel of Quaternary age underlies the main river valley and extends into the valleys of tributaries. Fine-grained lacustrine sediments separate shallow and deep water-bearing zones of the outwash. Outwash-aquifer wells are seldom deeper than 100 ft. The river-valley sediments and uplands adjacent to the valley are underlain by a fractured-bedrock aquifer in siliciclastic rocks of Paleozoic age. Most bedrock-aquifer wells produce water from the Lock Haven Formation at depths of 250 ft or less. A review of previous geologic investigations was used to establish the structural framework and identify four plausible origins for natural gas. The Sabinsville Anticline, trending southwest to northeast, is the major structural feature in the Devonian bedrock. The anticline, a structural trap for a reservoir of deep native gas in the Oriskany Sandstone (Devonian) (origin 1) at depths of about 3,900 ft, was explored and tapped by numerous wells from 1930-60. The gas reservoir in the vicinity of Tioga Junction, depleted of native gas, was converted to the Tioga gas-storage field for injection and withdrawal of non-native gases (origin 2). Devonian shale gas (shallow native gas) also has been reported in the area (origin 3). Gas might also originate from microbial degradation of buried organic material in the outwash deposits (origin 4). An inventory of combustible-gas concentrations in headspaces of water samples from 91 wells showed 49 wells had water containing combustible gases at volume fractions of 0.1 percent or more. Well depth was a factor in the observed occurrence of combustible gas for the 62 bedrock wells inventoried. As well-depth range increased from less than 50 ft to 51-150 ft to greater than 151 ft, the percentage of bedrock-aquifer wells with combustible gas increased. Wells with high concentrations of combustible gas occurred in clusters; the largest cluster was near the eastern boundary of the gas-storage field. A subsequent detailed gas-sampling effort focused on 39 water wells with the highest concentrations of combustible gas (12 representing the outwash aquifer and 27 from the bedrock aquifer) and 8 selected gas wells. Three wells producing native gas from the Oriskany Sandstone and five wells (two observation wells and three injection/withdrawal wells) with non-native gas from the gas-storage field were sampled twice. Chemical composition, stable carbon and hydrogen isotopes of methane (13CCH4 and DCH4), and stable carbon isotopes of ethane (13CC2H6) were analyzed. No samples could be collected to document the composition of microbial gas originating in the outwash deposits (outwash or 'drift' gas) or of native natural gas originating solely in Devonian shale at depths shallower than the Oriskany Sandstone, although two of the storage-field observation wells sampled reportedly yielded some Devonian shale gas. Literature values for outwash or 'drift' gas and Devonian shale gases were used to supplement the data collection. Non-native gases fr
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18 CFR 270.306 - Devonian shale wells in Michigan.
Code of Federal Regulations, 2011 CFR
2011-04-01
... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...
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18 CFR 270.306 - Devonian shale wells in Michigan.
Code of Federal Regulations, 2014 CFR
2014-04-01
... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...
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18 CFR 270.306 - Devonian shale wells in Michigan.
Code of Federal Regulations, 2013 CFR
2013-04-01
... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...
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18 CFR 270.306 - Devonian shale wells in Michigan.
Code of Federal Regulations, 2012 CFR
2012-04-01
... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Devonian shale wells in... PROCEDURES Requirements for Filings With Jurisdictional Agencies § 270.306 Devonian shale wells in Michigan. A person seeking a determination that natural gas is being produced from the Devonian Age Antrim...
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Late Devonian shale deposition based on known and predicted occurrence of Foerstia in Michigan basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Matthews, R.D.
The fossil Foerstia (Protosalvinia) marks a time zone within Late Devonian shale sequences in the eastern US. Its recent discovery in Michigan has led to more accurate correlations among the three large eastern basins. Subdivisions of the Devonian-Mississippi shale sequence in Michigan based on gamma-ray correlations reveal an idealized black shale geometry common to other eastern black shales, such as the Sunbury of Michigan and Ohio, the Clegg Creek of Indiana, the Dunkirk of Pennsylvania and New York, and the lower Huron of Ohio and West Virginia. In Michigan, Foerstia occurs at a stratigraphic position postulated to mark a majormore » change in depositional conditions and source areas. This position strengthens the physical and paleontologic evidence for a formal division of the Antrim. Isopach maps of the shale sequence above and below Foerstia show a relatively uniform and continuous black shale deposit (units 1A, 1B, and 1C) below Foerstia. This deposit is unlike the wedge of sediment found above Foerstia, which is composed of a western facies (Ellsworth) and an eastern facies (upper Antrim) that should be combined in a single stratigraphic unit conforming to Forgotson's concept of a format.« less
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McDowell, R.R.; Avary, K.L.; Matchen, D.L.; Britton, J.Q.
2007-01-01
Similar lithologies and lithofacies are present in two Upper Devonian siliciclastic units, the Brallier and Foreknobs formations, in eastern West Virginia and western Virginia, USA. Specimens of an unusual trace fossil, Pteridichnites biseriatus, occur in variable numbers throughout both stratigraphic units. P. biseriatus is present in abundance in the lowermost Brallier and this abundance-zone serves as a local stratigraphic marker for the Brallier. The trace fossil, originally suggested as an indication of polychaete or arthropod locomotion, is herein proposed as the locomotion trace of an unidentified ophiuroid.
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Enomoto, Catherine B.; Trippi, Michael H.; Higley, Debra K.; Rouse, William A.; Dulong, Frank T.; Klett, Timothy R.; Mercier, Tracey J.; Brownfield, Michael E.; Leathers-Miller, Heidi M.; Finn, Thomas M.; Marra, Kristen R.; Le, Phuong A.; Woodall, Cheryl A.; Schenk, Christopher J.
2018-04-19
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources of 10.7 trillion cubic feet of natural gas in Upper Devonian shales of the Appalachian Basin Province.
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Enomoto, Catherine B.; Rouse, William A.; Trippi, Michael H.; Higley, Debra K.
2016-04-11
Technically recoverable undiscovered hydrocarbon resources in continuous accumulations are present in Upper Devonian and Lower Mississippian strata in the Appalachian Basin Petroleum Province. The province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The Upper Devonian and Lower Mississippian strata are part of the previously defined Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) that extends from New York to Tennessee. This publication presents a revision to the extent of the Devonian Shale-Middle and Upper Paleozoic TPS. The most significant modification to the maximum extent of the Devonian Shale-Middle and Upper Paleozoic TPS is to the south and southwest, adding areas in Tennessee, Georgia, Alabama, and Mississippi where Devonian strata, including potential petroleum source rocks, are present in the subsurface up to the outcrop. The Middle to Upper Devonian Chattanooga Shale extends from southeastern Kentucky to Alabama and eastern Mississippi. Production from Devonian shale has been established in the Appalachian fold and thrust belt of northeastern Alabama. Exploratory drilling has encountered Middle to Upper Devonian strata containing organic-rich shale in west-central Alabama. The areas added to the TPS are located in the Valley and Ridge, Interior Low Plateaus, and Appalachian Plateaus physiographic provinces, including the portion of the Appalachian fold and thrust belt buried beneath Cretaceous and younger sediments that were deposited on the U.S. Gulf Coastal Plain.
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Leventhal, J.S.
1981-01-01
Gas Chromatographic analysis of volatile products formed by stepwise pyrolysis of black shales can be used to characterize the kerogen by relating it to separated, identified precursors such as land-derived vitrinite and marine-source Tasmanites. Analysis of a Tasmanites sample shows exclusively n-alkane and -alkene pyrolysis products, whereas a vitrinite sample shows a predominance of one- and two-ring substituted aromatics. For core samples from northern Tennessee and for a suite of outcrop samples from eastern Kentucky, the organic matter type and the U content (<10-120ppm) show variations that are related to precursor organic materials. The samples that show a high vitrinite component in their pyrolysis products are also those samples with high contents of U. ?? 1981.
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The New Albany shale in Illinois: Emerging play or prolific source
Crockett, Joan; Morse, David E.
2010-01-01
The New Albany shale (Upper Devonian) in the Illinois basin is the primary hydrocarbon source rock for the basins nearly 4 billion bbl of oil production to date. The gas play is well-established in Indiana and Western Kentucky. One in-situ oil producing well was reported in a multiply competed well in the New Albany at Johnsonville field in Wayne County, Illinois. The Illinois gas and oil wells at Russellville, in Lawrence County are closely associated with the 0.6% reflectance contour, which suggests a higher level of thermal maturity in this area. Today, only one field, Russellville in eastern Lawrence County has established commercial production in the Ness Albany in Illinois. Two wildcat wells with gas shows were drilled in recent years in southern Saline County, where the New Albany is relatively deeply buried and close to faults associated with the Fluorspar District.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Hall, V.S.
1980-06-01
This bibliography contains 2702 citations, most of which are annotated. They are arranged by author in numerical order with a geographical index following the listing. The work is international in scope and covers the early geological literature, continuing through 1979 with a few 1980 citations in Addendum II. Addendum I contains a listing of the reports, well logs and symposiums of the Unconventional Gas Recovery Program (UGR) through August 1979. There is an author-subject index for these publications following the listing. The second part of Addendum I is a listing of the UGR maps which also has a subject-author indexmore » following the map listing. Addendum II includes several important new titles on the Devonian shale as well as a few older citations which were not found until after the bibliography had been numbered and essentially completed. A geographic index for these citations follows this listing.« less
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Repetski, John E.; Ryder, Robert T.; Weary, David J.; Harris, Anita G.; Trippi, Michael H.; Ruppert, Leslie F.; Ryder, Robert T.
2014-01-01
The conodont color alteration index (CAI) introduced by Epstein and others (1977) and Harris and others (1978) is an important criterion for estimating the thermal maturity of Ordovician to Mississippian rocks in the Appalachian basin. Consequently, the CAI isograd maps of Harris and others (1978) are commonly used by geologists to characterize the thermal and burial history of the Appalachian basin and to better understand the origin and distribution of oil and gas resources in the basin. The main objectives of this report are to present revised CAI isograd maps for Ordovician and Devonian rocks in the Appalachian basin and to interpret the geologic and petroleum resource implications of these maps. The CAI isograd maps presented herein complement, and in some areas replace, the CAI-based isograd maps of Harris and others (1978) for the Appalachian basin. The CAI data presented in this report were derived almost entirely from subsurface samples, whereas the CAI data used by Harris and others (1978) were derived almost entirely from outcrop samples. Because of the different sampling methods, there is little geographic overlap of the two data sets. The new data set is mostly from the Allegheny Plateau structural province and most of the data set of Harris and others (1978) is from the Valley and Ridge structural province, east of the Allegheny structural front (fig. 1). Vitrinite reflectance, based on dispersed vitrinite in Devonian black shale, is another important parameter for estimating the thermal maturity in pre-Pennsylvanian-age rocks of the Appalachian basin (Streib, 1981; Cole and others, 1987; Gerlach and Cercone, 1993; Rimmer and others, 1993; Curtis and Faure, 1997). This chapter also presents a revised percent vitrinite reflectance (%R0) isograd map based on dispersed vitrinite recovered from selected Devonian black shales. The Devonian black shales used for the vitrinite studies reported herein also were analyzed by RockEval pyrolysis and total organic carbon (TOC) content in weight percent. Although the RockEval and TOC data are included in this chapter (table 1), they are not shown on the maps. The revised CAI isograd and percent vitrinite reflectance isograd maps cover all or parts of Kentucky, New York, Ohio, Pennsylvania, Virginia, and West Virginia (fig. 1), and the following three stratigraphic intervals: Upper Ordovician carbonate rocks, Lower and Middle Devonian carbonate rocks, and Middle and Upper Devonian black shales. These stratigraphic intervals were chosen for the following reasons: (1) they represent target reservoirs for much of the oil and gas exploration in the Appalachian basin; (2) they are stratigraphically near probable source rocks for most of the oil and gas; (3) they include geologic formations that are nearly continuous across the basin; (4) they contain abundant carbonate grainstone-packstone intervals, which give a reasonable to good probability of recovery of conodont elements from small samples of drill cuttings; and (5) the Middle and Upper Devonian black shale contains large amounts of organic matter for RockEval, TOC, and dispersed vitrinite analyses. Thermal maturity patterns of the Upper Ordovician Trenton Limestone are of particular interest here, because they closely approximate the thermal maturity patterns in the overlying Upper Ordovician Utica Shale, which is the probable source rock for oil and gas in the Upper Cambrian Rose Run Sandstone (sandstone), Upper Cambrian and Lower Ordovician Knox Group (Dolomite), Lower and Middle Ordovician Beekmantown Group (dolomite or Dolomite), Upper Ordovician Trenton and Black River Limestones, and Lower Silurian Clinton/Medina sandstone (Cole and others, 1987; Jenden and others, 1993; Laughrey and Baldassare, 1998; Ryder and others, 1998; Ryder and Zagorski, 2003). The thermal maturity patterns of the Lower Devonian Helderberg Limestone (Group), Middle Devonian Onondaga Limestone, and Middle Devonian Marcellus Shale-Upper Devonian Rhine street Shale Member-Upper Devonian Ohio Shale are of interest, because they closely approximate the thermal maturity patterns in the Marcellus Shale, Upper Devonian Rhinestreet Shale Member, and Upper Devonian Huron Member of the Ohio Shale, which are the most important source rocks for oil and gas in the Appalachian basin (de Witt and Milici, 1989; Klemme and Ulmishek, 1991). The Marcellus, Rhinestreet, and Huron units are black-shale source rocks for oil and (or) gas in the Lower Devonian Oriskany Sandstone, the Upper Devonian sandstones, the Middle and Upper Devonian black shales, and the Upper Devonian-Lower Mississippian(?) Berea Sandstone (Patchen and others, 1992; Roen and Kepferle, 1993; Laughrey and Baldassare, 1998).
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Regional stratigraphy and petroleum potential, Ghadames basin, Algeria
DOE Office of Scientific and Technical Information (OSTI.GOV)
Emme, J.J.; Sunderland, B.L.
1991-03-01
The Ghadames basin in east-central Algeria extends over 65,000 km{sup 2} (25,000 mi{sup 2}), of which 90% is covered by dunes of the eastern Erg. This intracratonic basin consists of up to 6000 m (20,000 ft) of dominantly clastic Paleozoic through Mesozoic strata. The Ghadames basin is part of a larger, composite basin complex (Ilizzi-Ghadames-Triassic basins) where Paleozoic strata have been truncated during a Hercynian erosional event and subsequently overlain by a northward-thickening wedge of Mesozoic sediments. Major reservoir rocks include Triassic sandstones that produce oil, gas, and condensate in the western Ghadames basin, Siluro-Devonian sandstones that produce mostly oilmore » in the shallower Ilizzi basin to the south, and Cambro-Ordovician orthoquartzites that produce oil at Hassi Messaoud to the northwest. Organic shales of the Silurian and Middle-Upper Devonian are considered primary source rocks. Paleozoic shales and Triassic evaporite/red bed sequences act as seals for hydrocarbon accumulations. The central Ghadames basin is underexplored, with less than one wildcat well/1700 km{sup 2} (one well/420,000 ac). Recent Devonian and Triassic oil discoveries below 3500 m (11,500 ft) indicate that deep oil potential exists. Exploration to date has concentrated on structural traps. Subcrop and facies trends indicate that potential for giant stratigraphic or combination traps exists for both Siluro-Devonian and Triassic intervals. Modern seismic acquisition and processing techniques in high dune areas can be used to successfully identify critical unconformity-bound sequences with significant stratigraphic trap potential. Advances in seismic and drilling technology combined with creative exploration should result in major petroleum discoveries in the Ghadames basin.« less
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NASA Astrophysics Data System (ADS)
López-Gamundí, O. R.; Rossello, E. A.
1993-04-01
The Devonian-Carboniferous contact in southern South America, characterized by a sharp unconformity, has been related to the Late Devonian-Early Carboniferous Eo-Hercynian orogeny. The Calingasta-Uspallata basin of western Argentina and the Sauce-Grande basin (Ventana Foldbelt) of eastern Argentina have been selected to characterize this unconformity. The Eo-Hercynian movements were accompanied in western Argentina by igneous activity related to a Late Devonian—Early Carboniferous magmatic arc mainly exposed today along the Andean Cordillera. This magmatic activity is partly reflected also in eastern Argentina (Ventana Foldbelt), where isotopic dates suggest a thermal event also related to the intrusions present to the west in the North Patagonian Massif and Sierras Pampeanas. The scarcity of Lower Carboniferous deposits in the stratigraphic record of southern South America suggests that the Early Carboniferous was a time interval dominated by uplift and erosion followed by widespread subsidence during the Middle and Late Carboniferous. The origin of the Eo-Hercynian orogeny can be linked with the convergence between the Arequipa Massif, and its southern extension, and the South American continent. Its effects are best represented along the ‘Palaeo-Pacific’ margin, although distant effects are discernible in the cratonic areas of eastern South America.
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Geology and hydrocarbon potential of the Oued Mya Basin, Algeria
DOE Office of Scientific and Technical Information (OSTI.GOV)
Benamrane, O.; Messaoudi, M.; Messelles, H.
1992-01-01
The hydrocarbon System Ourd Mya is located in the Sahara Basin. It is one of the producing basin in Algeria. The stratigraphic section consists of Paleozoic and Mesosoic, it is about 5000m thick. In the eastern part, the basin is limited by the Hassi-Messaoud high zone which is a giant oil field producing from the Cambrian sands. The western part is limited by Hassi R'mel which is one of the biggest gas field in the world, it is producing from the triassic sands. The Mesozoic section is laying on the lower Devonian and in the eastern part, on the Cambrian.more » The main source rock is the Silurian shale with an average thickness of 50m and a total organic matter of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also a source rock, but in a second order. Clastic reservoirs are in the Triassic sequence which is mainly fluvial deposits with complex alluvial channels, it is the main target in the basin. Clastic reservoirs within the lower Devonian section have a good hydrocarbon potential in the east of the basin through a southwest-northeast orientation. The late Triassic-Early Jurassic evaporites overlie the Triassic clastic interval and extend over the entire Oued Mya Basin. This is considered as a super-seal evaporate package, which consists predominantly of anhydrite and halite. For Paleozoic targets, a large number of potential seals exist within the stratigraphic column. The authors infer that a large amount of the oil volume generated by the Silurian source rock from the beginning of Cretaceous until now, still not discovered could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands and Cambro-Ordovician reservoirs.« less
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Subsurface stratigraphy of upper Devonian clastics in southern West Virginia
DOE Office of Scientific and Technical Information (OSTI.GOV)
Neal, D.W.; Patchen, D.G.
Studies of upper Devonian shales and siltstones in southern West Virginia have resulted in a refinement of the stratigraphic framework used in characterizing the gas-producing Devonian shales. Gamma-ray log correlation around the periphery of the Appalachian Basin has extended the usage of New York stratigraphic nomenclature for the interval between the base of the Dunkirk shale and the top of the Tully limestone to southern West Virginia. Equivalents of the Dunkirk shale and younger rocks of New York are recognized in southwestern West Virginia and are named according to Ohio usage. Gas production is primarily from the basal black shalemore » member of the Ohio shale. Gas shows from older black shale units (Rhinestreet and Marcellus shales) are recorded from wells east of the major producing trend. Provided suitable stimulation techniques can be developed, these older and deeper black shales may prove to be another potential gas resource.« less
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NASA Technical Reports Server (NTRS)
Wang, K.; Geldsetzer, H. H. J.
1992-01-01
Evidence from South China and Western Australia for a 365-Ma impact event in the Lower crepida conodont zone of the Famennian stage of the Late Devonian (about 1.5 Ma after the Frasnian/Famennian extinction event) includes microtektitelike glassy microspherules, geochemical anomalies (including a weak Ir), a probable impact crater (greater than 70 k) at Taihu in South China, and an Ir anomaly in Western Australia. A brachiopod faunal turnover in South China, and the 'strangelove ocean'-like c-delta 13 excursions in both Chinese and Australian sections indicate that at least a regional-scale extinction might have occurred at the time of the impact. A paleoreconstruction shows that South China was very close to and facing Western Australia in the Late Devonian. The carbon isotopic excursions, which occur at the same stratigraphic level in both South China and Western Australia cannot be explained as being coincidental. The c-delta 13 excursions and the brachiopod faunal turnover in South China indicate that there might have been at least a regional (possibly global) extinction in the Lower crepida zone. The impact-derived microspherules and geochemical anomalies (especially the Ir) indicate a Lower crepida zone impact event on eastern Gondwana. The location, type of target rocks, and possibly age of the Taihu Lake crater qualify as the probable site of this Late Devonian impact.
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Mankinen, E.A.; Lindsley-Griffin, N.; Griffin, J.R.
2002-01-01
New paleomagnetic results from the eastern Klamath Mountains of northern California show that Neoproterozoic rocks of the Trinity ophiolitic complex and overlying Middle Devonian volcanic rocks are latitudinally concordant with cratonal North America. Combining paleomagnetic data with regional geologic and faunal evidence suggests that the Trinity Complex and related terranes of the eastern Klamath plate were linked in some fashion to the North American craton throughout that time, but that distance between them may have varied considerably. A possible model that is consistent with our paleomagnetic results and the geologic evidence is that the Trinity Complex formed and migrated parallel to paleolatitude in the basin between Laurasia and Australia-East Antarctica as the Rodinian supercontinent began to break up. It then continued to move parallel to paleolatitude at least through Middle Devonian time. Although the eastern Klamath plate served as a nucleus against which more western components of the Klamath Mountains province amalgamated, the Klamath superterrane was not accreted to North America until Early Cretaceous time.
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Total petroleum systems of the Illizi Province, Algeria and Libya; Tanezzuft-Illizi
Klett, T.R.
2000-01-01
Undiscovered conventional oil and gas resources were assessed within a total petroleum system of the Illizi Province (2056) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Illizi Province is in eastern Algeria and a small portion of western Libya. The province and its total petroleum system coincide with the Illizi Basin. Although several total petroleum systems may exist within the Illizi Province, only one “composite” total petroleum system is identified. This total petroleum system comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. The total petroleum system was named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in the Tanezzuft-Illizi Total Petroleum System are 2,814 million barrels of oil (MMBO), 27,785 billion cubic feet of gas (BCFG), and 873 million barrels of natural gas liquids (MMBNGL).
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Petroleum geology and resources of the Dnieper-Donets Basin, Ukraine and Russia
Ulmishek, Gregory F.
2001-01-01
The Dnieper-Donets basin is almost entirely in Ukraine, and it is the principal producer of hydrocarbons in that country. A small southeastern part of the basin is in Russia. The basin is bounded by the Voronezh high of the Russian craton to the northeast and by the Ukrainian shield to the southwest. The basin is principally a Late Devonian rift that is overlain by a Carboniferous to Early Permian postrift sag. The Devonian rift structure extends northwestward into the Pripyat basin of Belarus; the two basins are separated by the Bragin-Loev uplift, which is a Devonian volcanic center. Southeastward, the Dnieper-Donets basin has a gradational boundary with the Donbas foldbelt, which is a structurally inverted and deformed part of the basin. The sedimentary succession of the basin consists of four tectono-stratigraphic sequences. The prerift platform sequence includes Middle Devonian to lower Frasnian, mainly clastic, rocks that were deposited in an extensive intracratonic basin. 1 The Upper Devonian synrift sequence probably is as thick as 4?5 kilometers. It is composed of marine carbonate, clastic, and volcanic rocks and two salt formations, of Frasnian and Famennian age, that are deformed into salt domes and plugs. The postrift sag sequence consists of Carboniferous and Lower Permian clastic marine and alluvial deltaic rocks that are as thick as 11 kilometers in the southeastern part of the basin. The Lower Permian interval includes a salt formation that is an important regional seal for oil and gas fields. The basin was affected by strong compression in Artinskian (Early Permian) time, when southeastern basin areas were uplifted and deeply eroded and the Donbas foldbelt was formed. The postrift platform sequence includes Triassic through Tertiary rocks that were deposited in a shallow platform depression that extended far beyond the Dnieper-Donets basin boundaries. A single total petroleum system encompassing the entire sedimentary succession is identified in the Dnieper-Donets basin. Discovered reserves of the system are 1.6 billion barrels of oil and 59 trillion cubic feet of gas. More than one-half of the reserves are in Lower Permian rocks below the salt seal. Most of remaining reserves are in upper Visean-Serpukhovian (Lower Carboniferous) strata. The majority of discovered fields are in salt-cored anticlines or in drapes over Devonian horst blocks; little exploration has been conducted for stratigraphic traps. Synrift Upper Devonian carbonate reservoirs are almost unexplored. Two identified source-rock intervals are the black anoxic shales and carbonates in the lower Visean and Devonian sections. However, additional source rocks possibly are present in the deep central area of the basin. The role of Carboniferous coals as a source rock for gas is uncertain; no coal-related gas has been identified by the limited geochemical studies. The source rocks are in the gas-generation window over most of the basin area; consequently gas dominates over oil in the reserves. Three assessment units were identified in the Dnieper-Donets Paleozoic total petroleum system. The assessment unit that contains all discovered reserves embraces postrift Carboniferous and younger rocks. This unit also contains the largest portion of undiscovered resources, especially gas. Stratigraphic and combination structural and stratigraphic traps probably will be the prime targets for future exploration. The second assessment unit includes poorly known synrift Devonian rocks. Carbonate reef reservoirs along the basin margins probably will contain most of the undiscovered resources. The third assessment unit is an unconventional, continuous, basin-centered gas accumulation in Carboniferous low-permeability clastic rocks. The entire extent of this accumulation is unknown, but it occupies much of the basin area. Resources of this assessment unit were not estimated quantitatively.
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Timing of terrane accretion in eastern and east-central Maine
NASA Astrophysics Data System (ADS)
Ludman, Allan
1986-05-01
The Norumbega fault zone is often cited as a post-Acadian suture between exotic blocks, even though stratigraphic, structural, and metamorphic data indicate that there is little offset of the Silurian-Devonian strata that the zone cuts in eastern Maine. Similarly, the Kingman fault zone has been shown by gravity and geochemical studies to separate distinct crustal blocks, whereas mapping shows that it lies entirely within a Silurian turbidite package. These conflicts are resolved if the two fault zones represent boundaries between Ordovician or older crustal blocks that had accreted to form a composite terrane prior to deposition of the cover sequences. The faults now mapped within these younger rocks formed by reactivation of the pre-Silurian boundaries during late Acadian time; movement continued until the late Carboniferous. Most of the accretionary history of Maine had thus ended before the Silurian. A complex composite terrane may have formed during Cambrian-Ordovician time that (1) interacted with cratonic North America during the Taconian orogeny and (2) became the “basement” upon which the Silurian and Lower Devonian strata of eastern Maine were deposited.
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Hackley, Paul C.; Ryder, Robert T.; Trippi, Michael H.; Alimi, Hossein
2013-01-01
To better estimate thermal maturity of Devonian shales in the northern Appalachian Basin, eleven samples of Marcellus and Huron Shale were characterized via multiple analytical techniques. Vitrinite reflectance, Rock–Eval pyrolysis, gas chromatography (GC) of whole rock extracts, and GC–mass spectrometry (GCMS) of extract saturate fractions were evaluated on three transects that lie across previously documented regional thermal maturity isolines. Results from vitrinite reflectance suggest that most samples are immature with respect to hydrocarbon generation. However, bulk geochemical data and sterane and terpane biomarker ratios from GCMS suggest that almost all samples are in the oil window. This observation is consistent with the presence of thermogenic gas in the study area and higher vitrinite reflectance values recorded from overlying Pennsylvanian coals. These results suggest that vitrinite reflectance is a poor predictor of thermal maturity in early mature areas of Devonian shale, perhaps because reported measurements often include determinations of solid bitumen reflectance. Vitrinite reflectance interpretations in areas of early mature Devonian shale should be supplanted by evaluation of thermal maturity information from biomarker ratios and bulk geochemical data.
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NASA Astrophysics Data System (ADS)
Lapierre, H.; Brouxel, M.; Albarede, F.; Coulin, C.; Lecuyer, C.; Martin, P.; Mascle, G.; Rouer, O.
1987-09-01
The Paleozoic to Early Mesozoic geology of the eastern Klamath Mountains (N California) is characterized by three major magmatic events of Ordovician, Late Ordovician to Early Devonian, and Permo-Triassic ages. The Ordovician event is represented by a calc-alkalic island-arc sequence (Lovers Leap Butte sequence) developed in the vicinity of a continental margin. The Late Ordovician to Early Devonian event consists of the 430-480 Ma old Trinity ophiolite formed during the early development of a marginal basin, and a series of low-K tholeiitic volcanic suites (Lovers Leap Basalt—Keratophyre unit, Copley and Balaklala Formations) belonging to intraoceanic island-arcs. Finally, the Permo-Triassic event gave rise to three successives phases of volcanic activity (Nosoni, Dekkas and Bully Hill) represented by the highly differentiated basalt-to-rhyolite low-K tholeiitic series of mature island-arcs. The Permo-Triassic sediments are indicative of shallow to moderate depth in an open, warm sea. The geodynamic evolution of the eastern Klamath Mountains during Paleozoic to Early Mesozoic times is therefore constrained by the geological, petrological and geochemical features of its island-arcs and related marginal basin. A consistent plate-tectonic model is proposed for the area, consisting of six main stages: (1) development during Ordovician times of a calc-alkalic island-arc in the vicinity of a continental margin; (2) extrusion during Late Ordovician to Silurian times of a primitive basalt-andesite intraoceanic island-arc suite, which terminated with boninites, the latter suggest rifting in the fore-arc, followed by the breakup of the arc; (3) opening and development of the Trinity back-arc basin around 430-480 Ma ago; (4) eruption of the Balaklala Rhyolite either in the arc or in the fore-arc, ending in Early Devonian time with intrusion of the 400 Ma Mule Mountain stock; (5) break in volcanic activity from the Early Devonian to the Early Permian; and (6) development of a mature island-arc from the Early Permian to the Late Triassic. The eastern Klamath Mountains island-arc formations and ophiolitic suite are part of the "Cordilleran suspect terranes", considered to be Gondwana margin fragments, that have undergone large northward translations before final collision with the North American craton during Late Mesozoic or Cenozoic times. These eastern Klamath Mountains island-arcs could be associated with the paleo-Pacific oceanic plate that led to accretion of these allochthonous terranes to the American margin.
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World class Devonian potential seen in eastern Madre de Dios basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Peters, K.E.; Wagner, J.B.; Carpenter, D.G.
The Madre de Dios basin in northern Bolivia contains thick, laterally extensive, organic-rich Upper Devonian source rocks that reached the oil-generative stage of thermal maturity after trap and seal formation. Despite these facts, less than one dozen exploration wells have been drilled in the Madre de Dios basin, and no significant reserves have been discovered. Mobil geoscientists conducted a regional geological, geophysical, and geochemical study of the Madre de Dios basin. The work reported here was designed to assess the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks. It is supported by data from over 3,000 mmore » of continuous slimhole core in two of the five Mobil wells in the basin. Source potential also exists in Cretaceous, Mississippian, and Permian intervals. The results of this study have important implications for future exploration in Bolivia and Peru.« less
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NASA Astrophysics Data System (ADS)
Botor, Dariusz
2018-03-01
The Lower Paleozoic basins of eastern Poland have recently been the focus of intensive exploration for shale gas. In the Lublin Basin potential unconventional play is related to Lower Silurian source rocks. In order to assess petroleum charge history of these shale gas reservoirs, 1-D maturity modeling has been performed. In the Łopiennik IG-1 well, which is the only well that penetrated Lower Paleozoic strata in the study area, the uniform vitrinite reflectance values within the Paleozoic section are interpreted as being mainly the result of higher heat flow in the Late Carboniferous to Early Permian times and 3500 m thick overburden eroded due to the Variscan inversion. Moreover, our model has been supported by zircon helium and apatite fission track dating. The Lower Paleozoic strata in the study area reached maximum temperature in the Late Carboniferous time. Accomplished tectono-thermal model allowed establishing that petroleum generation in the Lower Silurian source rocks developed mainly in the Devonian - Carboniferous period. Whereas, during Mesozoic burial, hydrocarbon generation processes did not develop again. This has negative influence on potential durability of shale gas reservoirs.
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NASA Astrophysics Data System (ADS)
Zhu, J.; Parris, T. M.; Taylor, C. J.; Webb, S. E.; Davidson, B.; Smath, R.; Richardson, S. D.; Molofsky, L.; Kromann, J. S.
2016-12-01
Rapid implementation of horizontal drilling and hydraulic fracturing technology to produce oil and gas from tight rock formations across the country has increased public concern about possible impact on the environment, especially on shallow drinking-water aquifers. In eastern Kentucky, horizontal drilling and hydraulic fracturing have been used to develop the Upper Devonian Berea Sandstone in recent years. Although production in the Berea Sandstone is at a relatively small scale, the Rogersville Shale, a deeper, thicker, and more spatially extensive organic-rich shale, is projected to become a major shale play in eastern Kentucky. This has necessitated a better understanding of groundwater quality, especially the occurrence of dissolved methane, in aquifers overlying the Berea and Rogersville plays to help address the public's environmental concerns and protect groundwater resources. To assess baseline groundwater chemistry and evaluate distribution and origin of methane detected in the groundwater, 51 water wells in Greenup, Carter, Boyd, Lawrence, Johnson, and Elliott Counties were sampled and analyzed for major cations and anions, metals, and dissolved light hydrocarbon gases including methane. Twenty-six wells were identified as having methane concentrations greater than 1 mg/L and were further analyzed for carbon and hydrogen isotopes. The results indicate that methane is a relatively common constituent in shallow groundwater in eastern Kentucky. Correlation of methane distribution with water chemistry data shows that elevated methane concentrations were more common in sodium bicarbonate type water and in low-nitrate, low-sulfate redox conditions. Carbon and hydrogen isotope analysis suggests that the methane detected in groundwater is derived primarily from bacterial sources from the CO2 reduction pathway.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Kuuskraa, V.A.; Brashear, J.P.; Doscher, T.M.
1978-10-01
This study was conducted to assist public decision-makers in selecting among many choices to obtain new gas supplies by addressing 2 questions: 1) how severe is the need for additional future supplies of natural gas, and what is the economic potential of providing part of future supply through enhanced recovery from unconventional natural gas resources. The study also serves to assist the DOE in designing a cost-effective R and D program to stimulate industry to recover this unconventional gas and to produce it sooner. Tight gas basins, Devonian shale, methane from coal seams, and methane from geopressured aquifers are considered.more » It is concluded that unconventional sources, already providing about 1 Tcf per year, could provide from 3 to 4 Tcf in 1985 and from 6 to 8 Tcf in 1990 (at $1.75 and $3.00 per Mcf, respectively). However, even with these additions to supply, gas supply is projected to remain below 1977 usage levels. (DLC)« less
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Unconventional shallow biogenic gas systems
Shurr, G.W.; Ridgley, J.L.
2002-01-01
Unconventional shallow biogenic gas falls into two distinct systems that have different attributes. Early-generation systems have blanketlike geometries, and gas generation begins soon after deposition of reservoir and source rocks. Late-generation systems have ringlike geometries, and long time intervals separate deposition of reservoir and source rocks from gas generation. For both types of systems, the gas is dominantly methane and is associated with source rocks that are not thermally mature. Early-generation biogenic gas systems are typified by production from low-permeability Cretaceous rocks in the northern Great Plains of Alberta, Saskatchewan, and Montana. The main area of production is on the southeastern margin of the Alberta basin and the northwestern margin of the Williston basin. The huge volume of Cretaceous rocks has a generalized regional pattern of thick, non-marine, coarse clastics to the west and thinner, finer grained marine lithologies to the east. Reservoir rocks in the lower part tend to be finer grained and have lower porosity and permeability than those in the upper part. Similarly, source beds in the units have higher values of total organic carbon. Patterns of erosion, deposition, deformation, and production in both the upper and lower units are related to the geometry of lineament-bounded basement blocks. Geochemical studies show that gas and coproduced water are in equilibrium and that the fluids are relatively old, namely, as much as 66 Ma. Other examples of early-generation systems include Cretaceous clastic reservoirs on the southwestern margin of Williston basin and chalks on the eastern margin of the Denver basin. Late-generation biogenic gas systems have as an archetype the Devonian Antrim Shale on the northern margin of the Michigan basin. Reservoir rocks are fractured, organic-rich black shales that also serve as source rocks. Although fractures are important for production, the relationships to specific geologic structures are not clear. Large quantities of water are coproduced with the gas, and geochemical data indicate that the water is fairly fresh and relatively young. Current thinking holds that biogenic gas was generated, and perhaps continues to be, when glacial meltwater descended into the plumbing system provided by fractures. Other examples of late-generation systems include the Devonian New Albany Shale on the eastern margin of the Illinois basin and the Tertiary coalbed methane production on the northwestern margin of the Powder River basin. Both types of biogenic gas systems have a similar resource development history. Initially, little technology is used, and gas is consumed locally; eventually, sweet spots are exploited, widespread unconventional reservoirs are developed, and transport of gas is interstate or international. However, drilling and completion techniques are very different between the two types of systems. Early-generation systems have water-sensitive reservoir rocks, and consequently water is avoided or minimized in drilling and completion. In contrast, water is an important constituent of late-generation systems; gas production is closely tied to dewatering the system during production. Existing production and resource estimates generally range from 10 to 100 tcf for both types of biogenic gas systems. Although both system types are examples of relatively continuous accumulations, the geologic frameworks constrain most-economic production to large geologic structures on the margins of basins. Shallow biogenic gas systems hold important resources to meet the increased domestic and international demands for natural gas.
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NASA Astrophysics Data System (ADS)
Hamilton, Stewart M.; Grasby, Stephen E.; McIntosh, Jennifer C.; Osborn, Stephen G.
2015-02-01
Baseline groundwater geochemical mapping of inorganic and isotopic parameters across 44,000 km2 of southwestern Ontario (Canada) has delineated a discreet zone of natural gas in the bedrock aquifer coincident with an 8,000-km2 exposure of Middle Devonian shale. This study describes the ambient geochemical conditions in these shales in the context of other strata, including Ordovician shales, and discusses shale-related natural and anthropogenic processes contributing to hydrogeochemical conditions in the aquifer. The three Devonian shales—the Kettle Point Formation (Antrim equivalent), Hamilton Group and Marcellus Formation—have higher DOC, DIC, HCO3, CO2(aq), pH and iodide, and much higher CH4(aq). The two Ordovician shales—the Queenston and Georgian-Bay/Blue Mountain Formations—are higher in Ca, Mg, SO4 and H2S. In the Devonian shale region, isotopic zones of Pleistocene-aged groundwater have halved in size since first identified in the 1980s; potentiometric data implicate regional groundwater extraction in the shrinkage. Isotopically younger waters invading the aquifer show rapid increases in CH4(aq), pH and iodide with depth and rapid decrease in oxidized carbon species including CO2, HCO3 and DIC, suggesting contemporary methanogenesis. Pumping in the Devonian shale contact aquifer may stimulate methanogenesis by lowering TDS, removing products and replacing reactants, including bicarbonate, derived from overlying glacial sedimentary aquifers.
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Lindquist, Sandra J.
1999-01-01
The Domanik-Paleozoic oil-prone total petroleum system covers most of the Timan-Pechora Basin Province of northwestern Arctic Russia. It contains nearly 20 BBOE ultimate recoverable reserves (66% oil). West of the province is the early Precambrian Eastern European craton margin. The province itself was the site of periodic Paleozoic tectonic events, culminating with the Hercynian Uralian orogeny along its eastern border. The stratigraphic record is dominated by Paleozoic platform and shelf-edge carbonates succeeded by Upper Permian to Triassic molasse siliciclastics that are locally present in depressions. Upper Devonian (Frasnian), deep marine shale and limestone source rocks ? with typically 5 wt % total organic carbon ? by middle Mesozoic time had generated hydrocarbons that migrated into reservoirs ranging in age from Ordovician to Triassic but most focused in Devonian and Permian rocks. Carboniferous structural inversions of old aulacogen borders, and Hercynian (Permian) to Early Cimmerian (Late Triassic to Early Jurassic) orogenic compression not only impacted depositional patterns, but also created and subsequently modified numerous structural traps within the province.
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Modern methods rediscover deep gas. [Texas
DOE Office of Scientific and Technical Information (OSTI.GOV)
McDonald, J.S.
1979-03-01
In 1973, Northern Natural Gas (NNG) Co.'s Midland exploration and production district acquired a 7-section lease block on a Devonian-Montoya prospect suggested by trend geology and limited seismic data. This acreage block was 2 miles west of the abandoned Hershey field, and included acreage on which the Devonian was tested at noncommercial rates in 1962. Additional seismic data confirmed the presence of a drillable prospect on NNG's acreage block. Engineering analyses of the reservoir characteristics suggested that modern completion and treatment techniques would result in a commercial producer. NNG's management approved the expenditure and the first well was spudded inmore » April, 1977. This well, the No. 1 Hershenson, was completed in Sept., 1977 as the discovery well in the Hershey West (Devonian-Montoya) field for a calculated open flow potential (CAOFP) of 20.5 mmcfd dry gas from perforations at 15,445 to 16,017 ft. The confirmation well, No. 1 Hershenson 6, was spudded in May, 1978, and completed in Oct., 1978, for a CAOFP of 86.3 mmcfd from perforations at 16,000 to 16,624 ft. A third well, No. 1 Maddox-Willbanks 15, was spudded in Nov., 1978. Rediscovered field potential justified construction of a gas processing plant and a 16-mile pipeline.« less
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18 CFR 270.201 - Applicability.
Code of Federal Regulations, 2010 CFR
2010-04-01
... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...
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18 CFR 270.201 - Applicability.
Code of Federal Regulations, 2013 CFR
2013-04-01
... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...
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18 CFR 270.201 - Applicability.
Code of Federal Regulations, 2011 CFR
2011-04-01
... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...
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18 CFR 270.201 - Applicability.
Code of Federal Regulations, 2014 CFR
2014-04-01
... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...
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18 CFR 270.201 - Applicability.
Code of Federal Regulations, 2012 CFR
2012-04-01
... jurisdictional agencies for tight formation gas, occluded natural gas produced from coal seams, and natural gas produced from Devonian shale that is produced through: (1) A well the surface drilling of which began after... recompletion commenced after December 31, 1979, but before January 1, 1993, where such gas could not have been...
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Tucker, R.D.; Osberg, P.H.; Berry, H.N.
2001-01-01
The zone of Acadian collision between the Medial New England and Composite Avalon terranes is well preserved in Maine. A transect from northwest (Rome) to southeast (Camden) crosses the eastern part of Medial New England comprising the Central Maine basin, Liberty-Orrington thrust sheet, and Fredericton trough, and the western part of Composite Avalon, including the Graham Lake, Clarry Hill, and Clam Cove thrust sheets. U-Pb geochronology of events before, during, and after the Acadian orogeny helps elucidate the nature and distribution of tectonostrati& graphic belts in this zone and the timing of some Acadian events in the Northern Appalachians. The Central Maine basin consists of sedimentary and volcanic rocks of Middle Ordovician (???470 to ???460 Ma) age overlain with probable conformity by latest Ordovician(?) through earliest Devonian marine rift and flysch sedimentary rocks; these are intruded by weakly to undeformed plutonic rocks of Early and Middle Devonian age (???399??378 Ma). The Fredericton trough consists of Early Silurian gray pelite and sandstone to earliest Late Silurian calcareous turbidite, deformed and variably metamorphosed prior to the emplacement of Late Silurian (???422 Ma) and Early to Late Devonian (???418 to ???368 Ma) plutons. The Liberty-Orrington thrust sheet consists of Cambrian(?)-Ordovician (>???474 to ???469 Ma and younger) clastic sedimentary and volcanic rocks intruded by highly deformed Late Silurian (???424 to ???422 Ma) and Devonian (???418 to ???389 Ma) plutons, possibly metamorphosed in Late Silurian time (prior to ???417 Ma), and metamorphosed to amphibolite facies in Early to Middle Devonian time (???400 to ???381 Ma). The Graham Lake thrust sheet contains possible Precambrian rocks, Cambrian sedimentary rocks with a volcanic unit dated at ???503 Ma, and Ordovician rocks with possible Caradocian Old World fossils, metamor& phosed and deformed in Silurian time and intruded by mildly to undeformed Late Silurian (???421 Ma) and Late Devonian (???371 to ???368 Ma) plutons. The Clarry Hill thrust sheet consists of poorly studied, highly metamorphosed Cambrian(?) rocks. The Clam Cove thrust sheet contains highly deformed Precambrian limestone, shale, sandstone, and conglomerate, metamorphosed to epidote amphibolite facies and intruded by a mildly deformed pluton dated at ???421 Ma. Metamorphism, deformation, and voluminous intrusive igneous activity of Silu& rian age are common to both the most southeastern parts of Medial New England and the thrust sheets of Composite Avalon. In contrast to Medial New England, the thrust sheets of Composite Avalon show only modest effects of Devonian deformation and metamorphism. Regional stratigraphic relations, paleontologic findings, and U-Pb geochronology suggest that the Graham Lake, Clarry Hill, and Clam Cove thrust sheets are far-traveled allochthons that were widely separated from Medial New England in the Silurian.
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18 CFR 270.101 - General definitions.
Code of Federal Regulations, 2011 CFR
2011-04-01
... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...
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18 CFR 270.101 - General definitions.
Code of Federal Regulations, 2012 CFR
2012-04-01
... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...
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18 CFR 270.101 - General definitions.
Code of Federal Regulations, 2013 CFR
2013-04-01
... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...
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18 CFR 270.101 - General definitions.
Code of Federal Regulations, 2010 CFR
2010-04-01
... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...
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18 CFR 270.101 - General definitions.
Code of Federal Regulations, 2014 CFR
2014-04-01
... fractures, pores and bedding planes of coal seams. (7) Natural gas produced from Devonian shale means natural gas produced from fractures, micropores and bedding planes of shales deposited during the... General Definitions § 270.101 General definitions. (a) NGPA definitions. Terms defined in the Natural Gas...
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The north-subducting Rheic Ocean during the Devonian: consequences for the Rhenohercynian ore sites
NASA Astrophysics Data System (ADS)
von Raumer, Jürgen F.; Nesbor, Heinz-Dieter; Stampfli, Gérard M.
2017-10-01
Base metal mining in the Rhenohercynian Zone has a long history. Middle-Upper Devonian to Lower Carboniferous sediment-hosted massive sulfide deposits (SHMS), volcanic-hosted massive sulfide deposits (VHMS) and Lahn-Dill-type iron, and base metal ores occur at several sites in the Rhenohercynian Zone that stretches from the South Portuguese Zone, through the Lizard area, the Rhenish Massif and the Harz Mountain to the Moravo-Silesian Zone of SW Bohemia. During Devonian to Early Carboniferous times, the Rhenohercynian Zone is seen as an evolving rift system developed on subsiding shelf areas of the Old Red continent. A reappraisal of the geotectonic setting of these ore deposits is proposed. The Middle-Upper Devonian to Early Carboniferous time period was characterized by detrital sedimentation, continental intraplate and subduction-related volcanism. The large shelf of the Devonian Old Red continent was the place of thermal subsidence with contemporaneous mobilization of rising thermal fluids along activated Early Devonian growth faults. Hydrothermal brines equilibrated with the basement and overlying Middle-Upper Devonian detrital deposits forming the SHMS deposits in the southern part of the Pyrite Belt, in the Rhenish Massif and in the Harz areas. Volcanic-hosted massive sulfide deposits (VHMS) formed in the more eastern localities of the Rhenohercynian domain. In contrast, since the Tournaisian period of ore formation, dominant pull-apart triggered magmatic emplacement of acidic rocks, and their metasomatic replacement in the apical zones of felsic domes and sediments in the northern part of the Iberian Pyrite belt, thus changing the general conditions of ore precipitation. This two-step evolution is thought to be controlled by syn- to post-tectonic phases in the Variscan framework, specifically by the transition of geotectonic setting dominated by crustal extension to a one characterized by the subduction of the supposed northern slab of the Rheic Ocean preceding the general Late Variscan crustal shortening and oroclinal bending.
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Chapman, Elizabeth C; Capo, Rosemary C; Stewart, Brian W; Kirby, Carl S; Hammack, Richard W; Schroeder, Karl T; Edenborn, Harry M
2012-03-20
Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ~375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε(Sr)(SW) = +13.8 to +41.6, where ε(Sr) (SW) is the deviation of the (87)Sr/(86)Sr ratio from that of seawater in parts per 10(4)); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.
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Sequence stratigraphy and a revised sea-level curve for the Middle Devonian of eastern North America
Brett, Carlton E.; Baird, G.C.; Bartholomew, A.J.; DeSantis, M.K.; Ver Straeten, C.A.
2011-01-01
The well-exposed Middle Devonian rocks of the Appalachian foreland basin (Onondaga Formation; Hamilton Group, Tully Formation, and the Genesee Group of New York State) preserve one of the most detailed records of high-order sea-level oscillation cycles for this time period in the world. Detailed examination of coeval units in distal areas of the Appalachian Basin, as well as portions of the Michigan and Illinois basins, has revealed that the pattern of high-order sea-level oscillations documented in the New York-Pennsylvania section can be positively identified in all areas of eastern North America where coeval units are preserved. The persistence of the pattern of high-order sea-level cycles across such a wide geographic area suggests that these cycles are allocyclic in nature with primary control on deposition being eustatic sea-level oscillation, as opposed to autocylic controls, such as sediment supply, which would be more local in their manifestation. There is strong evidence from studies of cyclicity and spectral analysis that these cycles are also related to Milankovitch orbital variations, with the short and long-term eccentricity cycles (100. kyr and 405. kyr) being the dominant oscillations in many settings. Relative sea-level oscillations of tens of meters are likely and raise considerable issues about the driving mechanism, given that the Middle Devonian appears to record a greenhouse phase of Phanerozoic history. These new correlations lend strong support to a revised high-resolution sea-level oscillation curve for the Middle Devonian for the eastern portion of North America. Recognized third-order sequences are: Eif-1 lower Onondaga Formation, Eif-2: upper Onondaga and Union Springs formations; Eif-Giv: Oatka Creek Formation; Giv-1: Skaneateles, Giv-2: Ludlowville, Giv-3: lower Moscow, Giv-4: upper Moscow-lower Tully, and Giv-5: middle Tully-Geneseo formations. Thus, in contrast with the widely cited eustatic curve of Johnson et al. (1985), which recognizes just one major transgressive-regressive (T-R) cycle in the early-mid Givetian (If) prior to the major late Givetian Taghanic unconformity (IIa, upper Tully-Geneseo Shale), we recognize four T-R cycles: If (restricted), Ig, Ih, and Ii. We surmise that third-order sequences record eustatic sea-level fluctuations of tens of meters with periodicities of 0.8-2. myr, while their medial-scale (fourth-order) subdivisions record lesser variations primarily of 405. kyr duration (long-term eccentricity). This high-resolution record of sea-level change provides strong evidence for high-order eustatic cycles with probable Milankovitch periodicities, despite the fact that no direct evidence for Middle Devonian glacial sediments has been found to date. ?? 2010.
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Enomoto, Catherine B.; Coleman, James L.; Swezey, Christopher S.; Niemeyer, Patrick W.; Dulong, Frank T.
2015-01-01
The presence of conventional anticlinal gas fields in the study area that are productive from the underlying Lower Devonian Oriskany Sandstone suggests that an unconventional (or continuous) shale gas system may be in place within the Marcellus Shale in the study area. Results of this study indicate that the Marcellus Shale in the Broadtop synclinorium generally is similar in organic geochemical nature throughout its extent, and based on the sample analyses, there are no clearly identifiable high potential areas (or “sweet spots”) in the study area. This report contains analyses of 132 outcrop and well drill-cuttings samples.
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Composition and genesis of the Konevinsky gold deposit, Eastern Sayan, Russia
NASA Astrophysics Data System (ADS)
Damdinov, B. B.; Zhmodik, S. M.; Roshchektaev, P. A.; Damdinova, L. B.
2016-03-01
The Konevinsky gold deposit in southeast Eastern Sayan is distinguished from most known deposits in this region (Zun-Kholba, etc.) by the geological setting and composition of mineralization. To elucidate the cause of the peculiar mineralization, we have studied the composition, formation conditions, and origin of this deposit, which is related to the Ordovician granitoid pluton 445-441 Ma in age cut by intermediate and basic dikes spatially associated with metavolcanic rocks of the Devonian-Carboniferous Ilei Sequence. Four mineral assemblages are recognized: (1) quartz-pyrite-molybdenite, (2) quartz-gold-pyrite, (3) gold-polysulfide, and (4) telluride. Certain indications show that the ore was formed as a result of the superposition of two distinct mineral assemblages differing in age. The first stage dated at ~440 Ma is related to intrusions generating Cu-Mo-Au porphyry mineralization and gold-polysulfide veins. The second stage is controlled by dikes pertaining to the Devonian-Carboniferous volcanic-plutonic association. The second stage is characterized by gain of Hg and Te and formation of gold-mercury-telluride paragenesis.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Ver Straeten, C.A.
1992-01-01
The K-bentonite-rich interval of the Esopus Formation (eastern New York and northeastern Pennsylvania) overlies the coeval Oriskany/Glenerie/Ridgely Formations and ranges from 1 to 6.3 m in thickness. Six to seventeen soapy-feeling, yellow, tan, green, or gray clay to claystone beds (0.001 to 0.5 m-thick) interbedded with thin siltstone and chert beds (0.02--1 m-thick) characterize outcrops in eastern New York. Heavy mineral separates from these layers yield abundant uncorraded euhedral zircons and apatites, indicating that these are K-bentonites. In eastern Pennsylvania, the westernmost outcrop of the Esopus Formation displays a 2.3 m-thick massive, soapy-feeling clay to claystone-dominated interval. The presence ofmore » both coarse, highly abraded and small, fragile, pristine-appearing zircons and apatites from a 20 cm sampled interval may indicate a complex amalgamation/reworking history to the relatively thick, clay-dominated strata. Similar clay/claystone-rich strata have been found in the lower 0.15 to 1 m of the Beaverdam Member (Needmore Formation) in central Pennsylvania. Interbedded clays and claystones with or without minor siltstone beds characterize some outcrops. Other localities are clay-dominated, with minor amounts of quartz sand present in strata immediately overlying the Ridgely Sandstone. These newly discovered K-bentonite-rich strata mark a transition from shelfal orthoquartzites and carbonates to basinal black/dark gray shales similar to the overlying Middle Devonian Tioga ash interval. Deposition of ash-rich strata, associated with increased volcanic activity, coincided with subsidence of the foreland basin/relative sea level rise. These events were concurrent with a flush of siliciclastic sediments into the basin and are indicative of the onset of an early tectophase of the Devonian Acadian Orogeny.« less
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Epstein, J.B.
1986-01-01
The rocks in the area, which range from Middle Ordovician to Late Devonian in age, are more than 7620 m thick. This diversified group of sedimentary rocks was deposited in many different environments, ranging from deep sea, through neritic and tidal, to alluvial. In general, the Middle Ordovician through Lower Devonian strata are a sedimentary cycle related to the waxing and waning of Taconic tectonism. The sequence began with a greywacke-argillite suite (Martinsburg Formation) representing synorogenic basin deepening. This was followed by basin filling and progradation of a sandstone-shale clastic wedge (Shawangunk Formation and Bloomsburg Red Beds) derived from the erosion of the mountains that were uplifted during the Taconic orogeny. The sequence ended with deposition of many thin units of carbonate, sandstone, and shale on a shelf marginal to a land area of low relief. Another tectonic-sedimentary cycle, related to the Acadian orogeny, began with deposition of Middle Devonian rocks. Deep-water shales (Marcellus Shale) preceded shoaling (Mahantango Formation) and turbidite sedimentation (Trimmers Rock Formation) followed by another molasse (Catskill Formation). -from Author
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Irwin, William P.; Mankinen, Edward A.
1998-01-01
The purpose of this report is to show graphically how the Klamath Mountains grew from a relatively small nucleus in Early Devonian time to its present size while rotating clockwise approximately 110°. This growth occurred by the addition of large tectonic slices of oceanic lithosphere, volcanic arcs, and melange during a sequence of accretionary episodes. The Klamath Mountains province consists of eight lithotectonoic units called terranes, some of which are divided into subterranes. The Eastern Klamath terrane, which was the early Paleozoic nucleus of the province, is divided into the Yreka, Trinity, and Redding subterranes. Through tectonic plate motion, usually involving subduction, the other terranes joined the early Paleozoic nucleus during seven accretionary episodes ranging in age from Early Devonian to Late Jurassic. The active terrane suture is shown for each episode by a bold black line. Much of the western boundary of the Klamath Mountains is marked by the South Fork and correlative faults along which the Klamath terranes overrode the Coast Range rocks during an eighth accretionary episode, forming the South Fork Mountain Schist in Early Cretaceous time.
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Algeria: structural evolution and hydrocarbon potential of a complicated Tectonic province
DOE Office of Scientific and Technical Information (OSTI.GOV)
Knudsen, H.W.
1985-02-01
During most of the pre-Carboniferous, Algeria was part of a stable foreland platform on which a thick clastic sequence was deposited. Caledonian tectonics were primarily epeirogenic, but they established structural alignments that were further reinforced by the much stronger movements of the Carboniferous Hercynian orogeny. In northern and eastern Algeria, a variable basal sandstone and a thick sequence of Triassic and Lower Jurassic evaporites were deposited over the eroded Hercynian surface. This provided a seal for subsequent hydrocarbon migration from the underlying Silurian and Devonian source rocks. Important epeirogenic events and tensional faulting occurred during the Jurassic and Cretaceous. Compressionalmore » forces in the tertiary culminated in the Alpine orogeny. A broad zone of uplift and southward-directed imbricate thrusting formed along the northern margins of Algeria obscuring much of the sub-Tertiary depositional and structural features. Hydrocarbon accumulation in Algeria has been predominantly controlled by the relationships among the Silurian-Devonian source rocks, the Hercynian unconformity, and the distribution of the overlying Triassic clastic and evaporite sequence. More than 65% of the recoverable oil reserves and 90% of the gas reserves are trapped immediately below or above the Hercynian unconformity, with the evaporites providing the seal. Heretofore, the complex geology of the Tertiary overthrust zone has been a deterrent to exploration in both the autochthonous Miocene basins and the sub-Tertiary sequence. However, improved seismic techniques and renewed interest in the potential of overthrust provinces point to increased activity in this area.« less
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Correlation of LANDSAT lineaments with Devonian gas fields in Lawrence County, Ohio
NASA Technical Reports Server (NTRS)
Johnson, G. O.
1981-01-01
In an effort to locate sources of natural gas in Ohio, the fractures and lineaments in Black Devonian shale were measured by: (1) field mapping of joints, swarms, and fractures; (2) stereophotointerpretation of geomorphic lineaments with precise photoquads; and (3) by interpreting the linear features on LANDSAT images. All results were compiled and graphically represented on 1:250,000 scale maps. The geologic setting of Lawrence County was defined and a field fracture map was generated and plotted as rose patterns at the exposure site. All maps were compared, contrasted, and correlated by superimposing each over the other as a transparency. The LANDSAT lineaments had significant correlation with the limits of oil and gas producing fields. These limits included termination of field production as well as extensions to other fields. The lineaments represent real rock fractures with zones of increased permeability in the near surface bedrock.
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NASA Astrophysics Data System (ADS)
Dahlquist, Juan A.; Alasino, Pablo H.; Basei, Miguel A. S.; Morales Cámera, Matías M.; Macchioli Grande, Marcos; da Costa Campos Neto, Mario
2018-04-01
We report a study integrating 13 new U-Pb LA-MC-ICP-MS zircon ages and Hf-isotope data from dated magmatic zircons together with complete petrological and whole-rock geochemistry data for the dated granitic rocks. Sample selection was strongly based on knowledge reported in previous investigations. Latest Devonian-Early Carboniferous granite samples were collected along a transect of 900 km, from the inner continental region (present-day Eastern Sierras Pampeanas) to the magmatic arc (now Western Sierras Pampeanas and Frontal Cordillera). Based on these data together with ca. 100 published whole-rock geochemical analyses we conclude that Late Devonian-Early Carboniferous magmatism at this latitude represents continuous activity (ranging from 322 to 379 Ma) on the pre-Andean margin of SW Gondwana, although important whole-rock and isotopic compositional variations occurred through time and space. Combined whole-rock chemistry and isotope data reveal that peraluminous A-type magmatism started in the intracontinental region during the Late Devonian, with subsequent development of synchronous Carboniferous peraluminous and metaluminous A-type magmatism in the retro-arc region and calc-alkaline magmatism in the western paleomargin. We envisage that magmatic evolution was mainly controlled by episodic fluctuations in the angle of subduction of the oceanic plate (between flat-slab and normal subduction), supporting a geodynamic switching model. Subduction fluctuations were relatively fast (ca. 7 Ma) during the Late Devonian and Early Carboniferous, and the complete magmatic switch-off and switch-on process lasted for 57 Ma. Hf T DM values of zircon (igneous and inherited) from some Carboniferous peraluminous A-type granites in the retro-arc suggest that Gondwana continental lithosphere formed during previous orogenies was partly the source of the Devonian-Carboniferous granitic magmas, thus precluding the generation of the parental magmas from exotic terranes.
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The pre-Devonian tectonic framework of Xing'an-Mongolia orogenic belt (XMOB) in north China
NASA Astrophysics Data System (ADS)
Xu, Bei; Zhao, Pan; Wang, Yanyang; Liao, Wen; Luo, Zhiwen; Bao, Qingzhong; Zhou, Yongheng
2015-01-01
A new tectonic division of the Xing'an-Mongolia orogenic belt (XMOB) in north China has been presented according to our research and a lot of new data of tectonics, geochronology and geochemistry. Four blocks and four sutures have been recognized in the XMOB, including the Erguna (EB), Xing'an-Airgin Sum (XAB), Songliao-Hunshandake (SHB), and Jiamusi (JB), and Xinlin-Xiguitu (XXS), Xilinhot-Heihe (XHS), Mudanjiang (MS) and Ondor Sum-Yongji sutures (OYS). The framework of the XMOB is characterized by a tectonic collage of the blocks and orogenic belts between them. Different Precambrian basements have been found in the blocks, including the Neoproterozoic metamorphic rocks and plutons in the EB, the Neoproterozoic metamorphic rocks in western and eastern of segments of the XAB, Mesoproterozoic and Neoproterozoic metamorphic rocks in middle segments of the XAB, respectively, the Neoproterozoic metamorphic rocks and Mesoproterozoic volcanic rocks and plutons in the SHB, and Neoproterozoic metamorphic rocks in the JB. The XXS resulted from a northwestward subduction of the XAB beneath the EB during the Cambrian, which was followed by the forming of the XHS and OYS in the northwest and south margins of the SHB in the Silurian, respectively. The MS was caused by a westward subduction of the JB beneath the east margin of the SHB during the middle Devonian. The three Cambrian, Silurian and middle Devonian events indicate that the XMOB belongs to a pre-middle Devonian multiple orogenic belt in the Central Asian Orogenic Belt (CAOB). Forming of the XMOB suggests that the southeast part of the Paleo Asian Ocean closed before the middle Devonian.
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Devonian (Emsian-Eifelian) fish from the Lower Bokkeveld Group (Ceres Subgroup), South Africa
NASA Astrophysics Data System (ADS)
Anderson, M. E.; Almond, J. E.; Evans, F. J.; Long, J. A.
1999-07-01
Four major groups of fish are represented by fragmentary remains from South Africa's Lower Bokkeveld Group of Early to Middle Devonian age: the Acanthodii, Chondrichthyes, Placodermi and Osteichthyes. These represent the oldest known occurrences of these groups in southern Africa, as well as an important addition to the very meagre record of earlier Devonian fish from the Malvinokaffric Province of southwestern Gondwana. Bokkeveld fish material comes from the Gydo (Late Emsian) and Tra Tra (Middle Eifelian) Formations of the Western Cape and Eastern Cape Provinces. The cosmopolitan marine acanthodian Machæracanthus is represented only by isolated fin spines which may belong to two different species on the basis of their external ornamentation, cross-sectional outline and internal histology. The elasmobranchs are represented by four elements: (1) a flattened chondrocranium which bears affinity to the Late Devonian-Carboniferous symmoriid (protacrodont) 'cladodont' sharks. It is probably the earliest known (Emsian) shark chondrocranium; (2) an isolated, primitive scapulocoracoid with a very short coracoidal ridge; (3) ankylosed and isolated radials, interpreted as parts of pterygial plates of a paired fin of an unknown chondrichthyan bearing affinity to the Middle Devonian Zamponiopteron from Bolivia; and (4) isolated barlike structures, perhaps gill arch or a jaw elements, thought to be from the same taxon as (3). The placoderms are represented by an incomplete trunk armour and fragmentary, finely ornamented plates of a primitive antiarch. The Osteichthyes are represented by a single large scale of an unidentified dipnoan from the Eifelian of the Cedarberg range, as well as a probable sarcopterygian dermal plate from the Emsian of the Prince Albert area. These are among the earliest sarcopterygian remains recorded from the Malvinokaffric Province.
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Brezinski, D.K.; Cecil, C.B.; Skema, V.W.; Stamm, R.
2008-01-01
A Late Devonian polymictic diamictite extends for more than 400??km from northeastern Pennsylvania across western Maryland and into east-central West Virginia. The matrix-supported, unbedded, locally sheared diamictite contains subangular to rounded clasts up to 2??m in diameter. The mostly rounded clasts are both locally derived and exotic; some exhibit striations, faceting, and polish. The diamictite commonly is overlain by laminated siltstone/mudstone facies associations (laminites). The laminites contain isolated clasts ranging in size from sand and pebbles to boulders, some of which are striated. The diamictite/laminite sequence is capped by massive, coarse-grained, pebbly sandstone that is trough cross-bedded. A stratigraphic change from red, calcic paleo-Vertisols in strata below the diamictite to non-calcic paleo-Spodosols and coal beds at and above the diamictite interval suggests that the climate became much wetter during deposition of the diamictite. The diamictite deposit is contemporaneous with regressive facies that reflect fluvial incision during the Late Devonian of the Appalachian basin. These deposits record a Late Devonian episode of climatic cooling so extreme that it produced glaciation in the Appalachian basin. Evidence for this episode of climatic cooling is preserved as the interpreted glacial deposits of diamictite, overlain by glaciolacustrine varves containing dropstones, and capped by sandstone interpreted as braided stream outwash. The Appalachian glacigenic deposits are contemporaneous with glacial deposits in South America, and suggest that Late Devonian climatic cooling was global. This period of dramatic global cooling may represent the end of the mid-Paleozoic warm interval that began in the Middle Silurian. ?? 2008 Elsevier B.V. All rights reserved.
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This report describes the retrospective case study for northeastern Pennsylvania, which was conducted in Bradford and Susquehanna Counties where some of the most intensive unconventional gas production from the Devonian-age Marcellus Shale has occurred. Gas production from the M...
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Dumoulin, Julie A.; Bradley, Dwight C.; Harris, Anita G.; Repetski, John E.
1999-01-01
Deep-water facies, chiefly hemipelagic deposits and turbidites, of Cambrian through Devonian age are widely exposed in the Medfra and Mt. McKinley quadrangles. These strata include the upper part of the Telsitna Formation (Middle-Upper Ordovician) and the Paradise Fork Formation (Lower Silurian-Lower Devonian) in the Nixon Fork terrane, the East Fork Hills Formation (Upper Cambrian-Lower Devonian) in the East Fork subterrane of the Minchumina terrane, and the chert and argillite unit (Ordovician) and the argillite and quartzite unit (Silurian- Devonian? and possibly older) in the Telida subterrane of the Minchumina terrane.In the western part of the study area (Medfra quadrangle), both hemipelagic deposits and turbidites are largely calcareous and were derived from the Nixon Fork carbonate platform. East- ern exposures (Mt. McKinley quadrangle; eastern part of the Telida subterrane) contain much less carbonate; hemipelagic strata are mostly chert, and turbidites contain abundant rounded quartz and lesser plagioclase and potassium feldspar. Deep-water facies in the Medfra quadrangle correlate well with rocks of the Dillinger terrane exposed to the south (McGrath quadrangle), but coeval strata in the Mt. McKinley quadrangle are compositionally similar to rocks to the northeast (Livengood quadrangle). Petrographic data thus suggest that the Telida subterranes presently defined is an artificial construct made up of two distinct sequences of disparate provenance.Restoration of 90 and 150 km of dextral strike-slip on the Iditarod and Farewell faults, respectively, aligns the deep-water strata of the Minchumina and Dillinger terranes in a position east of the Nixon Fork carbonate platform. This restoration supports the interpretation that lower Paleozoic rocks in the Nixon Fork and Dillinger terranes, and in the western part of the Minchumina terrane (East Fork subterrane and western part of the Telida subterrane), formed along a single continental margin. Rocks in the eastern part of the Telida subterrane are compositionally distinct from those to the west and may have had a different origin and history.
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Affinities and architecture of Devonian trunks of Prototaxites loganii.
Retallack, G J; Landing, Ed
2014-01-01
Devonian fossil logs of Prototaxites loganii have been considered kelp-like aquatic algae, rolled up carpets of liverworts, enormous saprophytic fungal fruiting bodies or giant lichens. Algae and rolled liverwort models cannot explain the proportions and branching described here of a complete fossil of Prototaxites loganii from the Middle Devonian (386 Ma) Bellvale Sandstone on Schunnemunk Mountain, eastern New York. The "Schunnemunk tree" was 8.83 m long and had six branches, each about 1 m long and 9 cm diam, on the upper 1.2 m of the main axis. The coalified outermost layer of the Schunnemunk trunk and branches have isotopic compositions (δ(13)CPDB) of -25.03 ± 0.13‰ and -26.17 ± 0.69‰, respectively. The outermost part of the trunk has poorly preserved invaginations above cortical nests of coccoid cells embraced by much-branched tubular cells. This histology is unlike algae, liverworts or vascular plants and most like lichen with coccoid chlorophyte phycobionts. Prototaxites has been placed within Basidiomycota but lacks clear dikaryan features. Prototaxites and its extinct order Nematophytales may belong within Mucoromycotina or Glomeromycota. © 2014 by The Mycological Society of America.
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Thermal maturity patterns in New York State using CAI and %Ro
Weary, D.J.; Ryder, R.T.; Nyahay, R.E.
2001-01-01
New conodont alteration index (CAI) and vitrinite reflectance (%Ro) data collected from drill holes in the Appalachian basin of New York State allow refinement of thermal maturity maps for Ordovician and Devonian rocks. CAI isotherms on the new maps show a pattern that approximates that published by Harris et al. (1978) in eastern and western New York, but it differs in central New York, where the isotherms are shifted markedly westward by more than 100 km and are more tightly grouped. This close grouping of isograds reflects a steeper thermal gradient than previously noted by Harris et al. (1978) and agrees closely with the abrupt west-to-east increase in thermal maturity across New York noted by Johnsson (1986). These data show, in concordance with previous studies, that thermal maturity levels in these rocks are higher than can be explained by simple burial heating beneath the present thickness of overburden. The Ordovician and Devonian rocks of the Appalachian Basin in New York must have been buried by very thick post-Devonian sediments (4-6 km suggested by Sarwar and Friedman 1995) or were exposed to a higher-than-normal geothermal flux caused by crustal extension, or a combination of the two.
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This report describes the retrospective case study conducted near Killdeer, Dunn County, North Dakota. The Killdeer study area is the location of historical oil and gas production, with current unconventional oil and gas production occurring in the late Devonian/early Mississipp...
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Bradley, W.H.; Pepper, J.F.
1941-01-01
The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age.Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits red shale and sandstone and gray mudstone in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pi. 2.)The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent.The structure of most of the area is shown by contour lines at 25-foot intervals, but where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines. tend to fork northeastward. All the folds have a westward or southwestward plunge. Throughout the area the rocks are jointed in two dominant sets one that trends northwest and the other east or northeast. No evident relation .between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible.The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults.Several of the larger streams and rivers occupy strike valleys, and their j courses swing to follow the changing strike of the rocks where they cross ( successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure. Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas.In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in tbe Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes maybe found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Woodhull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell,, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive.In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized. Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands presumably parts of the Dunkirk sandstone.
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Boucot, A.J.; Poole, F.G.; Amaya-Martinez, R.; Harris, A.G.; Sandberg, C.A.; Page, W.R.
2008-01-01
Three brachiopod faunas discussed herein record different depositional and tectonic settings along the southwestern margin of Laurentia (North America) during Devonian time. Depositional settings include inner continental shelf (Cerros de Los Murcielagos), medial continental shelf (Rancho Placeritos), and offshelf continental rise (Rancho Los Chinos). Ages of Devonian brachiopod faunas include middle Early (Pragian) at Rancho Placeritos in west-central Sonora, late Middle (Givetian) at Cerros de Los Murcielagos in northwestern Sonora, and late Late (Famennian) at Rancho Los Chinos in central Sonora. The brachiopods of these three faunas, as well as the gastropod Orecopia, are easily recognized in outcrop and thus are useful for local and regional correlations. Pragian brachiopods dominated by Acrospirifer and Meristella in the "San Miguel Formation" at Rancho Placeritos represent the widespread Appohimchi Subprovince of eastern and southern Laurentia. Conodonts of the early to middle Pragian sulcatus to kindlei Zones associated with the brachiopods confirm the ages indicated by the brachiopod fauna and provide additional information on the depositional setting of the Devonian strata. Biostratigraphic distribution of the Appohimchi brachiopod fauna indicates continuous Early Devonian shelf deposition along the entire southern margin of Laurentia. The largely emergent southwest-trending Transcontinental arch apparently formed a barrier preventing migration and mixing of many genera and species of brachiopods from the southern shelf of Laurentia in northern Mexico to the western shelf (Cordilleran mio-geocline) in the western United States. Middle Devonian Stringocephalus brachiopods and Late Devonian Orecopia gastropods in the "Los Murcielagos Formation" in northwest Sonora represent the southwest-ernmost occurrence of these genera in North America and date the host rocks as Givetian and Frasnian, respectively. Rhynchonelloid brachiopods (Dzieduszyckia sonora) and associated worm tubes in the Los Pozos Formation of the Sonora allochthon in central Sonora are also found in strati-form-barite facies in the upper Upper Devonian (Famennian) part of the Slaven Chert in the Roberts Mountains allochthon (upper plate) of central and western Nevada. Although these brachiopods and worm tubes occur in similar depositional settings along the margin of Laurentia in Mexico, they occur in allochthons that exhibit different tectonic styles and times of emplacement. Thus, the allochthons containing the brachiopods and worm tubes in Sonora and Nevada are parts of separate orogenic belts and have different geographic settings and tectonic histories. Devonian facies belts and faunas in northern Mexico indicate a continuous continental shelf along the entire southern margin of Laurentia. These data, in addition to the continuity of the late Paleozoic Ouachita-Marathon-Sonora orogen across northern Mexico, contradict the early Late Jurassic Mojave-Sonora megashear as a viable hypothesis for large-magnitude offset (600-1100 km) of Proterozoic through Middle Jurassic rocks from California to Sonora. ?? 2008 The Geological Society of America.
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Geological Structure of the Basement of Western and Eastern Parts of the West-Siberian Plain
ERIC Educational Resources Information Center
Ivanov, Kirill S.; Erokhin, Yuriy V.; Ponomarev, Vladimir S.; Pogromskaya, Olga E.; Berzin, Stepan V.
2016-01-01
The U-Pb dating (SHRIMP-II on zircon) was obtained for the first time from the basement of the West Siberian Plain in the Western half of the region. It is established that a large part of the protolith of the metamorphic depth in the Shaim-Kuznetsov meganticlinorium contained sedimentary late- and middle-Devonian rocks (395-358 million years).…
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Evidence of land plant affinity for the Devonian fossil Protosalvinia (Foerstia)
Romankiw, L.A.; Hatcher, P.G.; Roen, J.B.
1988-01-01
The Devonian plant fossil Protosalvinia (Foerstia) has been examined by solid-state 13C nuclear magnetic resonance spectroscopy (NMR) and pyrolysis-gas chromatography-mass spectrometry (PY-GC-MS). Results of these studies reveal that the chemical structure of Protosalvinia is remarkably similar to that of coalified wood. A well-defined phenolic carbon peak in the NMR spectra and the appearance of phenol and alkylated phenols in pyrolysis products are clearly indicative of lignin-like compounds. These data represent significant new information on the chemical nature of Protosalvinia and provide the first substantial organic geochemical evidence for land plant affinity. -Authors
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Dissolved methane in New York groundwater, 1999-2011
Kappel, William M.; Nystrom, Elizabeth A.
2012-01-01
New York State is underlain by numerous bedrock formations of Cambrian to Devonian age that produce natural gas and to a lesser extent oil. The first commercial gas well in the United States was dug in the early 1820s in Fredonia, south of Buffalo, New York, and produced methane from Devonian-age black shale. Methane naturally discharges to the land surface at some locations in New York. At Chestnut Ridge County Park in Erie County, just south of Buffalo, N.Y., several surface seeps of natural gas occur from Devonian black shale, including one behind a waterfall. Methane occurs locally in the groundwater of New York; as a result, it may be present in drinking-water wells, in the water produced from those wells, and in the associated water-supply systems (Eltschlager and others, 2001). The natural gas in low-permeability bedrock formations has not been accessible by traditional extraction techniques, which have been used to tap more permeable sandstone and carbonate bedrock reservoirs. However, newly developed techniques involving horizontal drilling and high-volume hydraulic fracturing have made it possible to extract previously inaccessible natural gas from low-permeability bedrock such as the Marcellus and Utica Shales. The use of hydraulic fracturing to release natural gas from these shale formations has raised concerns with water-well owners and water-resource managers across the Marcellus and Utica Shale region (West Virginia, Pennsylvania, New York and parts of several other adjoining States). Molofsky and others (2011) documented the widespread natural occurrence of methane in drinking-water wells in Susquehanna County, Pennsylvania. In the same county, Osborn and others (2011) identified elevated methane concentrations in selected drinking-water wells in the vicinity of Marcellus gas-development activities, although pre-development samples were not available for comparison. In order to manage water resources in areas of gas-well drilling and hydraulic fracturing in New York, the natural occurrence of methane in the State's aquifers needs to be documented. This brief report presents a compilation of data on dissolved methane concentrations in the groundwater of New York available from the U.S. Geological Survey (USGS) National Water Information System (NWIS) (http://waterdata.usgs.gov/nwis).
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Geologic structure and occurrence of gas in part of southwestern New York
Bradley, Wilmot H.; Pepper, James F.; Richardson, G.B.
1941-01-01
The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age.Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits—red shale and sandstone and gray mudstone—in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pl. 2.)The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent.The structure of most of the area is shown by contour lines at 25-foot intervals, but, where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines tend to fork northeastward. All the folds have a westward or southwestward plunge.Throughout the area the rocks are jointed in two dominant sets—one that trends northwest and the other east or northeast. No evident relation between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible.The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults ; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults.Several of the larger streams and rivers occupy strike valleys, and their courses swing to follow the changing strike of the rocks where they cross successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure.Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas.In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in the Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes may be found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Wood-hull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive.In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized.Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands— presumably parts of the Dunkirk sandstone.
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Doctor, Daniel H.; Orndorff, Randall C.; Parker, Ronald A.; Weary, David J.; Repetski, John E.
2010-01-01
The White Hall 7.5-minute quadrangle is located within the Valley and Ridge province of northern Virginia and the eastern panhandle of West Virginia. The quadrangle is one of several being mapped to investigate the geologic framework and groundwater resources of Frederick County, Va., as well as other areas in the northern Shenandoah Valley of Virginia and West Virginia. All exposed bedrock outcrops are clastic and carbonate strata of Paleozoic age ranging from Middle Cambrian to Late Devonian. Surficial materials include unconsolidated alluvium, colluvium, and terrace deposits of Quaternary age, and local paleo-terrace deposits possibly of Tertiary age. The quadrangle lies across the northeast plunge of the Great North Mountain anticlinorium and includes several other regional folds. The North Mountain fault zone cuts through the eastern part of the quadrangle; it is a series of thrust faults generally oriented northeast-southwest that separate the Silurian and Devonian clastic rocks from the Cambrian and Ordovician carbonate rocks and shales. Karst development in the quadrangle occurs in all of the carbonate rocks. Springs occur mainly near or on faults. Sinkholes occur within all of the carbonate rock units, especially where the rocks have undergone locally intensified deformation through folding, faulting, or some combination.
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NASA Astrophysics Data System (ADS)
Franchi, Fulvio; Turetta, Clara; Cavalazzi, Barbara; Corami, Fabiana; Barbieri, Roberto
2016-08-01
Trace and rare earth elements (REEs) have proven their utility as tools for assessing the genesis and early diagenesis of widespread geological bodies such as carbonate mounds, whose genetic processes are not yet fully understood. Carbonates from the Middle Devonian conical mud mounds of the Maïder Basin (eastern Anti-Atlas, Morocco) have been analysed for their REE and trace element distribution. Collectively, the carbonates from the Maïder Basin mud mounds appear to display coherent REE patterns. Three different geochemical patterns, possibly related with three different diagenetic events, include: i) dyke fills with a normal marine REE pattern probably precipitated in equilibrium with seawater, ii) mound micrite with a particular enrichment of overall REE contents and variable Ce anomaly probably related to variation of pH, increase of alkalinity or dissolution/remineralization of organic matter during early diagenesis, and iii) haematite-rich vein fills precipitated from venting fluids of probable hydrothermal origin. Our results reinforce the hypothesis that these mounds were probably affected by an early diagenesis induced by microbial activity and triggered by abundance of dispersed organic matter, whilst venting may have affected the mounds during a later diagenetic phase.
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NASA Astrophysics Data System (ADS)
Yang, Gaoxue; Li, Yongjun; Santosh, M.; Yang, Baokai; Yan, Jing; Zhang, Bing; Tong, Lili
2012-10-01
The West Junggar domain in NW China is a distinct tectonic unit of the Central Asian Orogenic Belt (CAOB). It is composed of Paleozoic ophiolitic mélanges, arcs and accretionary complexes. The Sartuohai ophiolitic mélange in the eastern West Junggar forms the northeastern part of the Darbut ophiolitic mélange, which contains serpentinized harzburgite, pyroxenite, dunite, cumulate, pillow lava, abyssal radiolarian chert and podiform chromite, overlain by the Early Carboniferous volcano-sedimentary rocks. In this paper we report new geochronological and geochemical data from basaltic and gabbroic blocks embedded within the Sartuohai ophiolitic mélange, to assess the possible presence of a Devonian mantle plume in the West Junggar, and evaluate the petrogenesis and implications for understanding of the Paleozoic continental accretion of CAOB. Zircon U-Pb analyses from the alkali basalt and gabbro by laser ablation inductively coupled plasma mass spectrometry yielded weighted mean ages of 375 ± 2 Ma and 368 ± 11 Ma. Geochemically, the Sartuohai ophiolitic mélange includes at least two distinct magmatic units: (1) a Late Devonian fragmented ophiolite, which were produced by ca. 2-10% spinel lherzolite partial melting in arc-related setting, and (2) contemporary alkali lavas, which were derived from 5% to 10% garnet + minor spinel lherzolite partial melting in an oceanic plateau or a seamount. Based on detailed zircon U-Pb dating and geochemical data for basalts and gabbros from the Sartuohai ophiolitic mélange, in combination with previous work, indicate a complex evolution by subduction-accretion processes from the Devonian to the Carboniferous. Furthermore, the alkali basalts from the Sartuohai ophiolitic mélange might be correlated to a Devonian mantle plume-related magmatism within the Junggar Ocean. If the plume model as proposed here is correct, it would suggest that mantle plume activity significantly contributed to the crustal growth in the CAOB.
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Kunk, Michael J.; Wintsch, R.P.; Naeser, C.W.; Naeser, N.D.; Southworth, C.S.; Drake, Avery A.; Becker, J.L.
2005-01-01
New 40Ar/39Ar data reveal ages and thermal discontinuities that identify mapped and unmapped fault boundaries in the Potomac terrane in northern Virginia, thus confirming previous interpretations that it is a composite terrane. The rocks of the Potomac terrane were examined along the Potomac River, where it has been previously subdivided into three units: the Mather Gorge, Sykesville, and Laurel Formations. In the Mather Gorge Formation, at least two metamorphic thermal domains were identified, the Blockhouse Point and Bear Island domains, separated by a fault active in the late Devonian. Early Ordovician (ca. 475 Ma) cooling ages of amphibole in the Bear Island domain reflect cooling from Taconic metamorphism, whereas the Blockhouse Point domain was first metamorphosed in the Devonian. The 40Ar/39Ar data from muscovites in a third (eastern) domain within the Mather Gorge Formation, the Stubblefield Falls domain, record thrusting of the Sykesville Formation over the Mather Gorge Formation on the Plummers Island fault in the Devonian. The existence of two distinctly different thermal domains separated by a tectonic boundary within the Mather Gorge argues against its status as a formation. Hornblende cooling ages in the Sykesville Formation are Early Devonian (ca. 400 Ma), reflecting cooling from Taconic and Acadian metamorphism. The ages of retrograde and overprinting muscovite in phyllonites from domain-bounding faults are late Devonian (Acadian) and late Pennsylvanian (Alleghanian), marking the time of assembly of these domains and subsequent movement on the Plummers Island fault. Our data indicate that net vertical motion between the Bear Island domain of the Mather Gorge complex and the Sykesville Formation across the Plummers Island fault is east-side-up. Zircon fission-track cooling ages demonstrate thermal equillbrium across the Potomac terrane in the early Permian, and apatite fission-track cooling ages record tilting of the Potomac terrane in the Cretaceous or later with the west side up at least 1 km. ?? 2005 Geological Society of America.
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Milici, Robert C.; Swezey, Christopher S.
2006-01-01
The U.S. Geological Survey (USGS) recently completed an assessment of the technically recoverable undiscovered hydrocarbon resources of the Appalachian Basin Province. The assessment province includes parts of New York, Pennsylvania, Ohio, Maryland, West Virginia, Virginia, Kentucky, Tennessee, Georgia and Alabama. The assessment was based on six major petroleum systems, which include strata that range in age from Cambrian to Pennsylvanian. The Devonian Shale-Middle and Upper Paleozoic Total Petroleum System (TPS) extends generally from New York to Tennessee. This petroleum system has produced a large proportion of the oil and natural gas that has been discovered in the Appalachian basin since the drilling of the Drake well in Pennsylvania in 1859. For assessment purposes, the TPS was divided into 10 assessment units (plays), 4 of which were classified as conventional and 6 as continuous. The results were reported as fully risked fractiles (F95, F50, F5 and the Mean), with the fractiles indicating the probability of recovery of the assessment amount. Products reported were oil (millions of barrels of oil, MMBO), gas (billions of cubic feet of gas, BCFG), and natural gas liquids (millions of barrels of natural gas liquids, MMBNGL). The mean estimates for technically recoverable undiscovered hydrocarbons in the TPS are: 7.53 MMBO, 31,418.88 BCFG (31.42 trillion cubic feet) of gas, and 562.07 MMBNGL.
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NASA Astrophysics Data System (ADS)
Zhu, Zhenhong; Yao, Genshun; Lou, Zhanghua; Jin, Aimin; Zhu, Rong; Jin, Chong; Chen, Chao
2018-05-01
Multiple sets of organic-rich shales developed in the Upper Paleozoic of the northwestern Guizhong Depression in South China. However, the exploration of these shales is presently at a relatively immature stage. The Upper Paleozoic shales in the northwestern Guizhong Depression, including the Middle Devonian Luofu shale, the Nabiao shale, and the Lower Carboniferous Yanguan shale, were investigated in this study. Mineral composition analysis, organic matter analysis (including total organic carbon (TOC) content, maceral of kerogen and the vitrinite reflection (Ro)), pore characteristic analysis (including porosity and permeability, pore type identification by SEM, and pore size distribution by nitrogen sorption), methane isothermal sorption test were conducted, and the distribution and thickness of the shales were determined, Then the characteristics of the two target shales were illustrated and compared. The results show that the Upper Paleozoic shales have favorable organic matter conditions (mainly moderate to high TOC content, type I and II1 kerogen and high to over maturity), good fracability potential (brittleness index (BI) > 40%), multiple pore types, stable distribution and effective thickness, and good methane sorption capacity. Therefore, the Upper Paleozoic shales in the northern Guizhong Depression have good shale gas potential and exploration prospects. Moreover, the average TOC content, average BI, thickness of the organic-rich shale (TOC > 2.0 wt%) and the shale gas resources of the Middle Devonian shales are better than those of the Lower Carboniferous shale. The Middle Devonian shales have better shale gas potential and exploration prospects than the Lower Carboniferous shales.
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,; Gaswirth, Stephanie B.; Marra, Kristen R.; Cook, Troy A.; Charpentier, Ronald R.; Gautier, Donald L.; Higley, Debra K.; Klett, Timothy R.; Lewan, Michael D.; Lillis, Paul G.; Schenk, Christopher J.; Tennyson, Marilyn E.; Whidden, Katherine J.
2013-01-01
In 2013, the U.S. Geological Survey assessed the technically recoverable oil and gas resources of the Bakken and Three Forks Formations of the U.S. portion of the Williston Basin. The Bakken and Three Forks Formations were assessed as continuous and hypothetical conventional oil accumulations using a methodology similar to that used in the assessment of other continuous- and conventional-type assessment units throughout the United States. The purpose of this report is to provide supplemental documentation and information used in the Bakken-Three Forks assessment.
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Peters, S.G.; Armstrong, A.K.; Harris, A.G.; Oscarson, R.L.; Noble, P.J.
2003-01-01
The Jerritt Canyon mining district in the northern Independence Range, northern Nevada, contains multiple, nearly horizontal, thrust masses of platform carbonate rocks that are exposed in a series of north- to northeast-elongated, tectonic windows through rocks of the Roberts Mountains allochthon. The Roberts Mountains allochthon was emplaced during the Late Devonian to Early Mississippian Antler orogeny. These thrust masses contain structurally and stratigraphically controlled Carlin-type gold deposits. The gold deposits are hosted in tectonically truncated units of the Silurian to Devonian Hanson Creek and Roberts Mountains Formations that lie within structural slices of an Eastern assemblage of Cambrian to Devonian carbonate rocks. In addition, these multiply thrust-faulted and folded host rocks are structurally interleaved with Mississippian siliciclastic rocks and are overlain structurally by Cambrian to Devonian siliciclastic units of the Roberts Mountains allochthon. All sedimentary rocks were involved in thrusting, high-angle faulting, and folding, and some of these events indicate substantial late Paleozoic and/or Mesozoic regional shortening. Early Pennsylvanian and late Eocene dikes also intrude the sedimentary rocks. These rocks all were uplifted into a northeast-trending range by subsequent late Cenozoic Basin and Range faulting. Eocene sedimentary and volcanic rocks flank part of the range. Pathways of hydrothermal fluid flow and locations of Carlin-type gold orebodies in the Jerritt Canyon mining district were controlled by structural and host-rock geometries within specific lithologies of the stacked thrust masses of Eastern assemblage rocks. The gold deposits are most common proximal to intersections of northeast-striking faults, northwest-striking dikes, and thrust planes that lie adjacent to permeable stratigraphic horizons. The host stratigraphic units include carbonate sequences that contained primary intercrystalline permeability, which provided initial pathways for fluid flow and later served as precipitation sites for ore minerals. Alteration, during, and perhaps prior to mineralization, enhanced primary permeability by dissolution, by removal of calcite, and by formation of dolomite. Ore-stage sulfide minerals and alteration minerals commonly precipitated in pore spaces among dolomite grains. Microveinlets and microbrecciation in zones of intense alteration also provided networks of secondary permeability that further enhanced fluid flux and produced additional sites for ore deposition.
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Colton, G.W.
1962-01-01
The Appalachian basin is an elongate depression in the crystalline basement complex< which contains a great volume of predominantly sedimentary stratified rocks. As defined in this paper it extends from the Adirondack Mountains in New York to central Alabama. From east to west it extends from the west flank of the Blue Ridge Mountains to the crest of the Findlay and Cincinnati arches and the Nashville dome. It encompasses an area of about 207,000 square miles, including all of West Virginia and parts of New York, New Jersey, Pennsylvania, Ohio, Maryland, Virginia, Kentucky, Tennessee, North Carolina, Georgia, and Alabama. The stratified rocks that occupy the basin constitute a wedge-shaped mass whose axis of greatest thickness lies close to and parallel to the east edge of the basin. The maximum thickness of stratified rocks preserved in any one part of the basin today is between 35,000 and 40,000 feet. The volume of the sedimentary rocks is approximately 510,000 cubic miles and of volcanic rocks is a few thousand cubic miles. The sedimentary rocks are predominantly Paleozoic in age, whereas the volcanic rocks are predominantly Late Precambrian. On the basis of gross lithology the stratified rocks overlying the crystalline basement complex can be divided into nine vertically sequential units, which are designated 'sequences' in this report. The boundaries between contiguous sequences do not necessarily coincide with the commonly recognized boundaries between systems or series. All sequences are grossly wedge shaped, being thickest along the eastern margin of the basin and thinnest along the western margin. The lowermost unit--the Late Precambrian stratified sequence--is present only along part of the eastern margin of the basin, where it lies unconformably on the basement complex. It consists largely of volcanic tuffs and flows but contains some interbedded sedimentary rocks. The Late Precambrian sequence is overlain by the Early Cambrian clastic sequence. Where the older sequence is absent, the Early Cambrian sequence rests on the basement complex. Interbedded fine- to coarse-grained noncarbonate detrital rocks comprise the bulk of the sequence, but some volcanic and carbonate rocks are included. Next above is the Cambrian-Ordovician carbonate sequence which consists largely of limestone and dolomite. Some quartzose sandstone is present in the lower part in the western half of the basin, and much shale is present in the upper part in the southeast part of the basin. The next higher sequence is the Late Ordovician clastic sequence, which consists largely of shale, siltstone, and sandstone. Coarse-grained light-gray to red rocks are common in the sequence along the eastern side of the basin, whereas fine-grained dark-gray to black calcareous rocks are common along the west side. The Late Ordovician clastic sequence is overlain--unconformably in many places--by the Early Silurian clastic sequence. The latter comprises a relatively thin wedge of coarse-grained clastic rocks. Some of the most prolific oil- and gas-producing sandstones in the Appalachian basin are included. Among these are the 'Clinton' sands of Ohio, the Medina Sandstones of New York and Pennsylvania, and the Keefer or 'Big Six' Sandstone of West Virginia and Kentucky. Conformably overlying the Early Silurian clastic sequence is the Silurian-Devonian carbonate sequence, which consists predominantly of limestone and dolomite. It also contains a salt-bearing unit in the north-central part of the basin and a thick wedge of coarse-grained red beds in the northeastern part. The sequence is absent in much of the southern part of the basin. Large volumes of gas and much oil are obtained from some of its rocks, especially from the Oriskany Sandstone and the Huntersville Chert. The Silurian-Devonian carbonate sequence is abruptly overlain by the Devonian clastic sequence--a thick succession of interbedded shale, mudrock, siltstone, and sandstone. Colors range f
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Klett, T.R.
2000-01-01
Undiscovered conventional oil and gas resources were assessed within total petroleum systems of the Trias/Ghadames Province (2054) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Trias/Ghadames Province is in eastern Algeria, southern Tunisia, and westernmost Libya. The province and its total petroleum systems generally coincide with the Triassic Basin. The province includes the Oued Mya Basin, Melrhir Basin, and Ghadames (Berkine) Basin. Although several total petroleum systems may exist within each of these basins, only three “composite” total petroleum systems were identified. Each total petroleum system occurs in a separate basin, and each comprises a single assessment unit.The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. Maturation history and the major migration pathways from source to reservoir are unique to each basin. The total petroleum systems were named after the oldest major source rock and the basin in which it resides.The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Trias/Ghadames Province are as follows [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids]:Tanezzuft-Oued Mya 830 MMBO 2,341 BCFG 110 MMBNGLTanezzuft-Melrhir 1,875 MMBO 4,887 BCFG 269 MMBNGLTanezzuft-Ghadames 4,461 MMBO 12,035 BCFG 908 MMBNGL
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The Tasmanides: Phanerozoic Tectonic Evolution of Eastern Australia
NASA Astrophysics Data System (ADS)
Rosenbaum, Gideon
2018-05-01
The Tasmanides occupy the eastern third of Australia and provide an extensive record of the evolution of the eastern Gondwanan convergent plate boundary from the Cambrian to the Triassic. This article presents a summary of the primary building blocks (igneous provinces and sedimentary basins) within the Tasmanides, followed by a discussion of the timing and extent of deformation events. Relatively short episodes of contractional deformation alternated with longer periods of crustal extension accompanied by voluminous magmatism. This behavior was likely controlled by plate boundary migration (trench retreat and advance) that was also responsible for bending and segmentation of the convergent plate margin. As a result, the Tasmanides were subjected to at least three major phases of oroclinal bending, in the Silurian, Devonian, and Permian. The most significant segmentation likely occurred at ˜420–400 Ma along a lithospheric-scale boundary that separated the northern and southern parts of the Tasmanides.
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Organic content of Devonian shale in western Appalachian basin.
Schmoker, J.W.
1980-01-01
In the organic-rich facies of the Devonian shale in the western part of the Appalachian basin, the distribution of organic matter provides an indirect measure of both gas in place and the capacity of the shale to supply gas to permeable pathways.The boundary between organic-rich ('black') and organic-poor ('gray') facies is defined here as 2% organic content by volume. The thickness of organic-rich facies ranges from 200ft in central Kentucky to 1000ft along the Kentucky-West Virginia border. The average content of the organic-rich facies increases from 5% by volume on the edge to 16% in central Kentucky. The net thickness of organic matter in the organic-rich facies shows the amount of organic material in the shale, and is the most fundamental of the organic-content characterizations. Net thickness of organic matter ranges between 20 and 80ft (6.1 and 24.4m) within the mapped area.-from Author
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Onondage pinnacle reefs in New York State
DOE Office of Scientific and Technical Information (OSTI.GOV)
Friedman, G.M.
1995-09-01
Onondaga pinnacle reefs, part of the Onondaga Formation, developed in an epeiric setting of the lowermost Middle Devonian (Eifelian). The reefs were initiated as coral-crinoidal mounds in the Edgecliff Member of the formation. Whereas most Devonian reefs are composed of rugose corals. Coral is the predominant kind of fossil, followed by crinoids, brachiopods, mollusks, undifferentiated skeletal debris, and possible sponges. The initial mineralogy of the corals is inferred to have been calcite. The porosity of these reefs is almost unique among reef reservoirs. most reefs produce from secondary or diagenetic porosity; by contrast Onondaga reefs display primary intracoralline or frameworkmore » porosity. Between framework builders and/or skeletal particles cryptocrystalline/microcrystalline cement fills pores. As observed in modern reefs this kind of cement resembles micrite, but probable formed as high-magnesian calcite in a high-energy setting. Syntaxial or rim cement common lines crinoid particles. Some of these pinnacle reefs, formerly gas producers, are presently under development as gas-storage reservoirs.« less
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Kostelnik, J.; Carter, K.M.
2009-01-01
The widespread distribution, favorable reservoir characteristics, and depth make the Lower Devonian Oriskany Sandstone a viable sequestration target in the Appalachian Basin. The Oriskany Sandstone is thickest in the structurally complex Ridge and Valley Province, thins toward the northern and western basin margins, and is even absent in other parts of the basin (i.e., the no-sand area of northwestern Pennsylvania). We evaluated four regions using petrographic data, core analyses, and geophysical log analyses. Throughout the entire study area, average porosities range from 1.35 to 14%. The most notable porosity types are primary intergranular, secondary dissolution, and fracture porosity. Intergranular primary porosity dominates at stratigraphic pinch-out zones near the Oriskany no-sand area and at the western limit of the Oriskany Sandstone. Secondary porosity occurs from dissolution of carbonate constituents primarily in the combination-traps natural gas play extending through western Pennsylvania, western West Virginia, and eastern Ohio. Fracture porosity dominates in the central Appalachian Plateau Province and Valley and Ridge Province. Based on average porosity, the most likely regions for successful sequestration in the Oriskany interval are (1) updip from Oriskany Sandstone pinch-outs in eastern Ohio, and (2) western Pennsylvania, western West Virginia, and eastern Ohio where production occurs from a combination of stratigraphic and structural traps. Permeability data, where available, were used to further evaluate the potential of these regions. Permeability ranges from 0.2 to 42.7 md. Stratigraphic pinch-outs at the northern and western limits of the basin have the highest permeabilities. We recommend detailed site assessments when evaluating the sequestration potential of a given injection site based on the variability observed in the Oriskany structure, lithology, and reservoir characteristics. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Ceosciences. All rights reserved.
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This report describes the retrospective case study for southwestern Pennsylvania, which was conducted in Amwell, Cross Creek, Hopewell, and Mount Pleasant Townships in Washington County, locations that have witnessed unconventional gas production from the Devonian-age Marcellus S...
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Lund, K.
2008-01-01
The U.S. and Canadian Cordilleran miogeocline evolved during several phases of Cryogenian-Devonian intracontinental rifting that formed the western mangin of Laurentia. Recent field and dating studies across central Idaho and northern Nevada result in identification of two segments of the rift margin. Resulting interpretations of rift geometry in the northern U.S. Cordillera are compatible with interpretations of northwest- striking asymmetric extensional segments subdivided by northeast-striking transform and transfer segments. The new interpretation permits integration of miogeoclinal segments along the length of the western North American Cordillera. For the U.S. Cordillera, miogeoclinal segments include the St. Mary-Moyie transform, eastern Washington- eastern Idaho upper-plate margin, Snake River transfer, Nevada-Utah lower-plate margin, and Mina transfer. The rift is orthogonal to most older basement domains, but the location of the transform-transfer zones suggests control of them by basement domain boundaries. The zigzag geometry of reentrants and promontories along the rift is paralleled by salients and recesses in younger thrust belts and by segmentation of younger extensional domains. Likewise, transform transfer zones localized subsequent transcurrent structures and igneous activity. Sediment-hosted mineral deposits trace the same zigzag geometry along the margin. Sedimentary exhalative (sedex) Zn-Pb-Ag ??Au and barite mineral deposits formed in continental-slope rocks during the Late Devonian-Mississippian and to a lesser degree, during the Cambrian-Early Ordovician. Such deposits formed during episodes of renewed extension along miogeoclinal segments. Carbonate-hosted Mississippi Valley- type (MVT) Zn-Pb deposits formed in structurally reactivated continental shelf rocks during the Late Devonian-Mississippian and Mesozoic due to reactivation of preexisting structures. The distribution and abundance of sedex and MVT deposits are controlled by the polarity and kinematics of the rift segment. Locally, discrete mineral belts parallel secondary structures such as rotated crustal blocks at depth that produced sedimentary subbasins and conduits for hydrothermal fluids. Where the miogeocline was overprinted by Mesozoic and Cenozoic deformation and magmatism, igneous rock-related mineral deposits are common. ??2008 Geological Society of America.
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Geologic Map of the Weaverville 15' Quadrangle, Trinity County, California
Irwin, William P.
2009-01-01
The Weaverville 15' quadrangle spans parts of five generally north-northwest-trending accreted terranes. From east to west, these are the Eastern Klamath, Central Metamorphic, North Fork, Eastern Hayfork, and Western Hayfork terranes. The Eastern Klamath terrane was thrust westward over the Central Metamorphic terrane during early Paleozoic (Devonian?) time and, in Early Cretaceous time (approx. 136 Ma), was intruded along its length by the massive Shasta Bally batholith. Remnants of overlap assemblages of the Early Cretaceous (Hauterivian) Great Valley sequence and the Tertiary Weaverville Formation cover nearly 10 percent of the quadrangle. The base of the Eastern Klamath terrane in the Weaverville quadrangle is a peridotite-gabbro complex that probably is correlative to the Trinity ophiolite (Ordovician), which is widely exposed farther north beyond the quadrangle. In the northeast part of the Weaverville quadrangle, the peridotite-gabbro complex is overlain by the Devonian Copley Greenstone and the Mississippian Bragdon Formation. Where these formations were intruded by the Shasta Bally batholith, they formed an aureole of gneissic and other metamorphic rocks around the batholith. Westward thrusting of the Eastern Klamath terrane over an adjacent body of mafic volcanic and overlying quartzose sedimentary rocks during Devonian time formed the Salmon Hornblende Schist and the Abrams Mica Schist of the Central Metamorphic terrane. Substantial beds of limestone in the quartzose sedimentary unit, generally found near the underlying volcanic rock, are too metamorphosed for fossils to have survived. Rb-Sr analysis of the Abrams Mica Schist indicates a metamorphic age of approx. 380 Ma. West of Weavervillle, the Oregon Mountain outlier of the Eastern Klamath terrane consists mainly of Bragdon Formation(?) and is largely separated from the underlying Central Metamorphic terrane by serpentinized peridotite that may be a remnant of the Trinity ophiolite. The North Fork terrane is faulted against the west edge of the Central Metamorphic terrane, and its northerly trend is disrupted by major left-lateral offsets along generally west-northwest-trending faults. The serpentinized peridotite-gabbro complex that forms the western base of the terrane is the Permian North Fork ophiolite, which to the east is overlain by broken formation of mafic-volcanic rocks, red chert, siliceous tuff, argillite, minor limestone, and clastic sedimentary rocks. The chert and siliceous tuff contain radiolarians of Permian and Mesozoic ages, and some are as young as Early Jurassic (Pliensbachian). Similar Pliensbachian radiolarians are found in Franciscan rocks of the Coast Ranges. The Eastern Hayfork terrane is broken formation and melange of mainly chert, sandstone, argillite, and various exotic blocks. The cherts yield radiolarians of Permian and Triassic ages but none of clearly Jurassic age. Limestone bodies of the Eastern Hayfork terrane contain Permian microfaunas of Tethyan affinity. The Western Hayfork terrane, exposed only in a small area in the southwestern part of the quadrangle, consists dominantly of mafic tuff and dark slaty argillite. Sparse paleontologic data indicate a Mesozoic age for the strata. The terrane includes small bodies of diorite that are related to the nearby Wildwood pluton of Middle Jurassic age and probably are related genetically to the stratified rocks. The terrane is interpreted to be the accreted remnants of a Middle Jurassic volcanic arc. Shortly after intrusion by Shasta Bally batholith (approx. 136 Ma), much of the southern half of the Weaverville quadrangle was overlapped by Lower Cretaceous, dominantly Hauterivian, marine strata of the Great Valley sequence, and to a lesser extent later during Oligocene and (or) Miocene time by fluvial and lacustrine deposits of the Weaverville Formation. This map of the Weaverville Quadrangle is a digital rendition of U.S. Geological Survey Miscellaneous Field
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NASA Astrophysics Data System (ADS)
Kuiper, Y. D.
2016-12-01
Crustal-scale dextral northeasterly trending ductile-brittle fault systems and increased igneous activity in mid-Paleozoic eastern New England and southern Maritime Canada are interpreted in terms of a subducted oceanic spreading ridge model. In the model, the fault systems form as a result of subduction of a spreading ridge-transform fault system, similar to the way the San Andreas fault system formed. Ridge subduction results in the formation of a sub-surface slab window, mantle upwelling, and increased associated magmatism in the overlying plate. The ridge-transform system existed in the Rheic Ocean, and was subducted below parts of Ganderia, Avalonia and Meguma in Maine, New Brunswick and Nova Scotia. The subduction zone jumped southeastward as a result of accretion of Avalonia. Where the ridge-transform system was subducted, plate motions changed from predominantly convergent between the northern Rheic Ocean and Laurentian plates to predominantly dextral between the southern Rheic Ocean and Laurentian plates. In the model, dextral fault systems include the Norumbega fault system between southwestern New Brunswick and southern Maine and New Hampshire, and the Kennebecasis, Belle Isle and Caledonia faults in southeastern New Brunswick. A latest Silurian transition from arc- to within-plate- magmatism in the Coastal Volcanic Belt in eastern Maine may suggest the onset of ridge subduction. Examples of increased latest Silurian to Devonian within-plate magmatism include the Cranberry Island volcanic series and coastal Maine magmatic province in Maine, and the South Mountain Batholith in Nova Scotia. Widespread Devonian to earliest Carboniferous granitic to intermediate plutons, beyond the Coastal Volcanic Belt towards southern Maine and central New Hampshire, may outline the shape of a subsurface slab window. The possibility of ridge-transform subduction in Newfoundland and in the southern Appalachians will be discussed. The northern Appalachians may be a unique location along the Eastern North American Margin and possibly on Earth, in that it may preserve the only known evidence for an ancient Mendocino-style triple junction and San Andreas-type fault.
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Characterization of the Helderberg Group as a geologic seal for CO 2 sequestration
Lewis, J.E.; McDowell, R.R.; Avary, K.L.; Carter, K.M.
2009-01-01
The Midwest Regional Carbon Sequestration Partnership recognizes that both the Devonian Oriskany Sandstone and the Silurian Salina Group offer potential for subsurface carbon dioxide storage in northern West Virginia. The Silurian-Devonian Helderberg Group lies stratigraphically between these two units, and consequendy, its potential as a geologic seal must be evaluated. Predominantly a carbonate interval with minor interbedded siliciclastics and chert, the Helderberg Group was deposited in an ancient epeiric sea. Although most previous investigations of this unit have concentrated on outcrops in eastern West Virginia, new information is available from an injection well drilled along the Ohio River at First Energy's R. E. Burger electric power plant near Shadyside, Ohio. Geophysical, seismic, and core data from this well have been combined with existing outcrop information to evaluate the Helderberg Group's potential as a seal. The data collected suggest that only secondary porosity remains, and permeability, if it exists, most likely occurs along faults or within fractures. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.
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Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.; ...
2017-10-25
Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.
Here, we investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from –7.8 to –6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from amore » well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns.« less
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NASA Astrophysics Data System (ADS)
López de Luchi, Mónica G.; Siegesmund, Siegfried; Wemmer, Klaus; Nolte, Nicole
2017-09-01
Middle Devonian granitoids intruded the Eastern Sierras Pampeanas basement ca. 600 km east of the inferred proto-Pacific margin of Gondwana along which a ca. 390 Ma collisional event developed. In the Sierra de San Luis, voluminous Middle Devonian (393-382 Ma) batholiths are composed of I- to A-type hybrid Monzonite and Granite suites. Shoshonite and subordinated high-K series, stocks, synplutonic dikes and enclaves make up the Monzonite Suite; rocks are metaluminous alkali-calcic magnesian porphyritic or equigranular monzonite, quartz monzonite, monzodiorite and scarce monzogabbro. High-K and subordinated shoshonite series metaluminous to mildly peraluminous magnesian alkali-calcic to calc-alkalic porphyritic or equigranular quartz monzonite, granodiorite, monzogranite and equigranular leucomonzogranites make up the Granite Suite plutons and batholiths. Only a small group of highly evolved granites are ferroan. SiO2 (46-62%), Cr, Ni, V, Sc, LILE, LREE, Th, Zr and variable, Sr/Y, (La/Yb)N and (Tb/Yb)N, smooth Eu/Eu*, moderate Na2O (ca 3.5), and troughs at Nb and Ta for Monzonite Suite rocks suggest an subduction-related enriched lithospheric mantle source. Sm-Nd data (TDM 0.98-1.08 Ga, εNd(380 Ma) 0.66-1.47) and 87Sr/86Sri (0.703520-0.704203) are compatible with an enriched mantle source. The metaluminous porphyritic quartz monzonite-monzogranite and the mildly peraluminous equigranular biotite monzogranites of the Granite Suite are characterized by relatively moderate Al2O3, CaO, and 87Sr/86Sri, high LILE, Cr, variable Sr/Y, (La/Yb)N and Eu/Eu* and low Rb/Sr (< 1.2) suggest a mafic source. The porphyritic monzogranite (TDM 1.20-1.28 Ga, εNd(380Ma) - 3.02 to - 3.3, 87Sr/86Sri 0.706578-0.707027) and the biotite monzogranites (TDM 1.31 Ga, εNd(380Ma) - 3.3, 87Sr/86Sri 0.707782) would share a common source. The equigranular alkali-calcic leucomonzogranites are characterized by Rb/Sr > 1.5, ASI 1.05-1.18, and Ga/Al 2.6-3.9, εNd(380 Ma) - 3.74 to - 3.95 and (87Sr/86Sr)i 0.710743-0.712955 which would point to metasedimentary or felsic igneous crustal sources. Nevertheless their TDM 1.36-1.38 Ga is considerably younger than the mean 1.8-1.6 Ga Eastern Sierras Pampeanas crustal residence age and less radiogenic. Middle Devonian magmatism would record an episode of crustal growth by enriched mantle derived magma input and variable degrees of partial melting of a lower crustal source at the waning stages of the Achalian orogeny.
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Devonian climate and reef evolution: Insights from oxygen isotopes in apatite
NASA Astrophysics Data System (ADS)
Joachimski, M. M.; Breisig, S.; Buggisch, W.; Talent, J. A.; Mawson, R.; Gereke, M.; Morrow, J. R.; Day, J.; Weddige, K.
2009-07-01
Conodonts, microfossils composed of carbonate-fluor apatite, are abundant in Palaeozoic-Triassic sediments and have a high potential to preserve primary oxygen isotope signals. In order to reconstruct the palaeotemperature history of the Devonian, the oxygen isotope composition of apatite phosphate was measured on 639 conodont samples from sequences in Europe, North America and Australia. The Early Devonian (Lochkovian; 416-411 Myr) was characterized by warm tropical temperatures of around 30 °C. A cooling trend started in the Pragian (410 Myr) with intermediate temperatures around 23 to 25 °C reconstructed for the Middle Devonian (397-385 Myr). During the Frasnian (383-375 Myr), temperatures increased again with temperatures to 30 °C calculated for the Frasnian-Famennian transition (375 Myr). During the Famennian (375-359 Myr), surface water temperatures slightly decreased. Reconstructed Devonian palaeotemperatures do not support earlier views suggesting the Middle Devonian was a supergreenhouse interval, an interpretation based partly on the development of extensive tropical coral-stromatoporoid communities during the Middle Devonian. Instead, the Devonian palaeotemperature record suggests that Middle Devonian coral-stromatoporoid reefs flourished during cooler time intervals whereas microbial reefs dominated during the warm to very warm Early and Late Devonian.
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The Mesozoic and Palaeozoic granitoids of north-western New Guinea
NASA Astrophysics Data System (ADS)
Jost, Benjamin M.; Webb, Max; White, Lloyd T.
2018-07-01
A large portion of the Bird's Head Peninsula of NW New Guinea is an inlier that reveals the pre-Cenozoic geological history of the northern margin of eastern Gondwana. The peninsula is dominated by a regional basement high exposing Gondwanan ('Australian') Palaeozoic metasediments intruded by Palaeozoic and Mesozoic granitoids. Here, we present the first comprehensive study of these granitoids, including field and petrographic descriptions, bulk rock geochemistry, and U-Pb zircon age data. We further revise and update previous subdivisions of granitoids in the area. Most granitoids were emplaced as small to medium-scale intrusions during two episodes in the Devonian-Carboniferous and the Late Permian-Triassic, separated by a period of apparent magmatic quiescence. The oldest rocks went unrecognised until this study, likely due to the younger intrusive events resetting the K-Ar isotopic system used in previous studies. Most of the Palaeozoic and Mesozoic granitoids are peraluminous and in large parts derived from partial melts of the country rock. This is corroborated by local migmatites and country rock xenoliths. Although rare, metaluminous and mafic rocks show that partial melts of mantle-derived material played a minor role in granitoid petrogenesis, especially during the Permian-Triassic. The Devonian-Carboniferous granitoids and associated volcanics are locally restricted, whereas the Permian-Triassic intrusions are found across NW New Guinea and further afield. The latter were likely part of an extensive active continental margin above a subduction system spanning the length of what is now New Guinea and potentially extending southward through eastern Australia and Antarctica.
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Pojeta, John
1986-01-01
A state-of-the-art summary of the Devonian rocks of China, correlation of the Lower and Middle Devonian of the Guangxi Autonomous Region with the European Standards, and detailed lithologic descriptions of the major Lower and Middle Devonian sections in Guangxi from which pelecypods were collected. Systematic descriptions are given for the Lower and Middle Devonian pelecypods of Guangxi. The Chinese pelecypods are principally compared with the previously little studied Givetian pelecypods of Michigan, which are also described.
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NASA Astrophysics Data System (ADS)
Szrek, P.; Niedźwiedzki, G.; Dec, M.
2012-04-01
Despite of more than 100 years of study, the Lower Devonian deposits of the Holy Cross Mountains (central Poland) are still not well understood from the biostratigraphical, environmental and also paleontological point of views. During field works and excavations conducted in 2011 numerous fossils (body and trace fossils) were discovered in a few Lower Devonian outcrops of the region. The siliciclastic sequence of the Lower Devonian of the southern part of the Holy Cross Mountains, is renowned for abundant vertebrate fossils, including mainly the jawless fish and placoderm remains. During the first detailed taphonomic study of the vertebrate assemblage from the so-called "Placoderm Sandstones" cropping out at the Podłazie near Daleszyce, abundant vertebrate remains have been collected (more than 600 specimens). Their analysis (that is in progress) will be the first description of so rich and numerous vertebrates association from the Central Europe that contains placoderms, sharks, acathodians and sarcopterygians. The degree of fragmentation of the bones and disarticulation of the skeletons suggest that the carcasses were reworked and transported before burial. Sedimentological data suggest deposition in a shallow marine environment. Numerous invertebrate ichnofossils (Phycodes isp. Skolithos isp., Diplichnites isp., Monomorphichnus isp., Lockeia cf. siliquaria, Corophioides isp. and Teichinus isp.) particularly well preserved were ascertained in another Lower Devonian site near Iwaniska. Moreover a very interesting assemblage of trace fossils corresponding to traces of feeding fishes were discovered. They are very similar to those found in much younger deposits (e.g. from the Eocene of Turkey). Its interpretation found them as made by placoderms is taken into consideration recently, because of its fiting to whole morphology of small coccosteids. They are also important that they could be the first imprints of soft body of the placoderm as a life animal according to good preservation of particular specimens. The occurrence of characteristic trace fossils is taken as strong evidence of marine influences of the studied section, where sedimentological features are not so clear, with exceptions of very few surfaces covered with symmetrical wave marks. The distribution of the most common trace fossils recognized in the field allowed for different interpretation than was proposed in the past which set up the river influence in the Lower Dewonian of the eastern part of the Holy Cross Mountains, but it is not confirmed by mentioned above invertebrate ichnofossils. Instead of this the development of Skolithos and Cruziana ichnofacies in Iwaniska profile, indicate high energy conditions in foreshore zone, respectively. All the Lower Devonian sites with trace fossils and vertebrate bonebeds from the Holy Cross Mountains are associated with sandy deposits and have been formed in a sea-coastal zone during rather rapid sedimentation episodes, but differ in fossil abundance and degree of preservation.
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Wedow, Helmuth
1983-01-01
The empirical model for sediment-associated, stratiform, exhalative, massive-sulfide deposits presented by D. Large in 1979 and 1980 has been redesigned to permit its use in a computer-assisted search for exploration-target areas in Devonian rocks of the Appalachian region using attribute-coincidence mapping (ACM). Some 36 gridded-data maps and selected maps derived therefrom were developed to show the orthogonal patterns, using the 7-1/2 minute quadrangle as an information cell, of geologic data patterns relevant to the empirical model. From these map and data files, six attribute-coincidence maps were prepared to illustrate both variation in the application of ACM techniques and the extent of possible significant exploration-target areas. As a result of this preliminary work in ACM, four major (and some lesser) exploration-target areas needing further study and analysis have been defined as follows: 1) in western and central New York in the outcrop area of lowermost Upper Devonian rocks straddling the Clarendon-Linden fault; 2) in western Virginia and eastern West Virginia in an area largely coincident with the well-known 'Oriskany' Mn-Fe ores; 3) an area in West Virginia, Maryland, and Virginia along and nearby the trend of the Alabama-New York lineament of King and Zietz approximately between 38- and 40-degrees N. latitude; and 4) an area in northeastern Ohio overlying an area coincident with a significant thickness of Silurian salt and high modern seismic activity. Some lesser, smaller areas suggested by relatively high coincidence may also be worthy of further study.
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Stratigraphy of lower to middle Paleozoic rocks of northern Nevada and the Antler orogeny
Ketner, Keith B.
2013-01-01
Commonly accepted concepts concerning the lower Paleozoic stratigraphy of northern Nevada are based on the assumption that the deep-water aspects of Ordovician to Devonian siliceous strata are due to their origin in a distant oceanic environment, and their presence where we find them is due to tectonic emplacement by the Roberts Mountains thrust. The concept adopted here is based on the assumption that their deep-water aspects are the result of sea-level rise in the Cambrian, and all of the Paleozoic strata in northern Nevada are indigenous to that area. The lower part of the Cambrian consists mainly of shallow-water cross-bedded sands derived from the craton. The upper part of the Cambrian, and part of the Ordovician, consists mainly of deep-water carbonate clastics carried by turbidity currents from the carbonate shelf in eastern Nevada, newly constructed as a result of sea-level rise. Ordovician to mid-Devonian strata are relatively deep-water siliceous deposits, which are the western facies assemblage. The basal contact of this assemblage on autochthonous Cambrian rocks is exposed in three mountain ranges and is clearly depositional in all three. The western facies assemblage can be divided into distinct stratigraphic units of regional extent. Many stratigraphic details can be explained simply by known changes in sea level. Upper Devonian to Mississippian strata are locally and westerly derived orogenic clastic beds deposited disconformably on the western facies assemblage. This disconformity, clearly exposed in 10 mountain ranges, indicates regional uplift and erosion of the western facies assemblage and absence of local deformation. The disconformity represents the Antler orogeny.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Zielinski, R.E.; Nance, S.W.
On shale samples from the WV-6 (Monongalia County, West Virginia) well, mean total gas yield was 80.4 ft/sup 3//ton. Mean hydrocarbon gas yield was 5.7 ft/sup 3//ton, 7% of total yield. Methane was the major hydrocarbon component and carbon dioxide the major nonhydrocarbon component. Oil yield was negligible. Clay minerals and organic matter were the dominant phases of the shale. Illite averages 76% of the total clay mineral content. This is detrital illite. Permeation of methane, parallel to the bedding direction for select samples from WV-5 (Mason County, West Virginia) well ranges from 10/sup -4/ to 10/sup -12/ darcys. Themore » permeability of these shales is affected by orgaic carbon content, density, particle orientation, depositional facies, etc. Preliminary studies of Devonian shale methane sorption rates suggest that these rates may be affected by shale porosity, as well as absorption and adsorption processes. An experimental system was designed to effectively simulate sorption of methane at natural reservoir conditions. The bulk density and color of select shales from Illinois, Appalachian and Michigan Basins suggest a general trend of decreasing density with increasing organic content. Black and grayish black shales have organic contents which normally exceed 1.0 wt %. Medium dark gray and gray shales generally have organic contents less than 1.0 wt %.« less
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Ryder, Robert T.
1996-01-01
INTRODUCTION: Black shale members of the Upper Devonian Antrim Shale are both the source and reservoir for a regional gas accumulation that presently extends across parts of six counties in the northern part of the Michigan basin (fig. 1). Natural fractures are considered by most petroleum geologists and oil and gas operators who work the Michigan basin to be a necessary condition for commercial gas production in the Antrim Shale. Fractures provide the conduits for free gas and associated water to flow to the borehole through the black shale which, otherwise, has a low matrix permeability. Moreover, the fractures assist in the release of gas adsorbed on mineral and(or) organic matter in the shale (Curtis, 1992). Depths to the gas-producing intervals (Norwood and Lachine Members) generally range from 1,200 to 1,800 ft (Oil and Gas Journal, 1994). Locally, wells that produce gas from the accumulation are as deep as 2,200 (Oil and Gas Journal, 1994). Even though natural fractures are an important control on Antrim Shale gas production, most wells require stimulation by hydraulic fracturing to attain commercial production rates (Kelly, 1992). In the U.S. Geological Survey's National Assessment of United States oil and gas, Dolton (1995) estimates that, at a mean value, 4.45 trillion cubic feet (TCF) of gas are recoverable as additions to already discovered quantities from the Antrim Shale in the productive area of the northern Michigan trend. Dolton (1995) also suggests that undiscovered Antrim Shale gas accumulations exist in other parts of the Michigan basin. The character, distribution, and origin of natural fractures in the Antrim Shale gas accumulation have been studied recently by academia and industry. The intent of these investigations is to: 1) predict 'sweet spots', prior to drilling, in the existing gas-producing trend, 2) improve production practices in the existing trend, 3) predict analogous fracture-controlled gas accumulations in other parts of the Michigan basin, and 4) improve estimates of the recoverable gas in the Antrim Shale gas plays (Dolton, 1995). This review of published literature on the characteristics of Antrim Shale fractures, their origin, and their controls on gas production will help to define objectives and goals in future U.S. Geological Survey studies of Antrim Shale gas resources.
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Coleman, James L.; Ryder, Robert T.; Milici, Robert C.; Brown, Stephen; Ruppert, Leslie F.; Ryder, Robert T.
2014-01-01
The Appalachian basin is the oldest and longest producing commercially viable petroleum-producing basin in the United States. Source rocks for reservoirs within the basin are located throughout the entire stratigraphic succession and extend geographically over much of the foreland basin and fold-and-thrust belt that make up the Appalachian basin. Major source rock intervals occur in Ordovician, Devonian, and Pennsylvanian strata with minor source rock intervals present in Cambrian, Silurian, and Mississippian strata.
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Structural evolution and petroleum productivity of the Baltic basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ulmishek, G.F.
The Baltic basin is an oval depression located in the western part of the Russian craton; it occupies the eastern Baltic Sea and adjacent onshore areas. The basin contains more than 5,000 m of sedimentary rocks ranging from latest Proterozoic to Tertiary in age. These rocks consist of four tectonostratigraphic sequences deposited during major tectonic episodes of basin evolution. Principal unconformities separate the sequences. The basin is underlain by a rift probably filled with Upper Proterozoic rocks. Vendian and Lower Cambrian rocks (Baikalian sequence) form two northeast-trending depressions. The principal stage of the basin development was during deposition of amore » thick Middle Cambrian-Lower Devonian (Caledonian) sequence. This stage was terminated by the most intense deformations in the basin history. The Middle Devonian-Carboniferous (Hercynian) and Permian-Tertiary (Kimmerian-Alpine) tectonic and depositional cycles only slightly modified the basin geometry and left intact the main structural framework of underlying rocks. The petroleum productivity of the basin is related to the Caledonian tectonostratigraphic sequence that contains both source rocks and reservoirs. However, maturation of source rocks, migration of oil, and formation of fields took place mostly during deposition of the Hercynian sequence.« less
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NASA Astrophysics Data System (ADS)
Li, Z. X.; Powell, C. McA.
2001-04-01
In the last 1000 million years, Australia has been part of two supercontinents: Palaeozoic Gondwanaland and Neoproterozoic Rodinia. Neoproterozoic Australia was covered by shallow epicontinental seas, and, in the late Neoproterozoic, by low-latitude glaciers. The breakup of Rodinia along the Tasman Line occurred at the end of the Sturtian glaciation (760 Ma) giving rise to the Palaeo-Pacific Ocean. Gondwanaland formed in the Early Cambrian, at the same time as the Tarim block broke away from northwestern Australia. Westward subduction of the Palaeo-Pacific Ocean along the eastern margin of Australia-Antarctica commenced during the Early Cambrian in northern Victoria Land and in the Middle Cambrian in South Australia, and culminated to the Late Cambrian-Early Ordovician Ross-Delamerian Mountains. In the Ordovician, the magmatic arc retreated from Australia's then-eastern continental margin, forming a marginal sea and offshore island arc. A shallow seaway across Australia in the Late Cambrian and Ordovician gradually gave way to desert-like conditions in Central Australia and the adjacent Canning Basin by Silurian time. The Silurian to mid-Devonian was an interval of rapidly changing palaeogeography in eastern Australia with deep volcanogenic troughs formed in a dextral transtensional tectonic setting. Widespread deformation in the Tasman orogenic zone in the Middle Devonian to Early Carboniferous, was accompanied by the development of an Andean-style magmatic arc along the Pacific continental margin of Australia. The most widespread Phanerozoic mountain-building stage in Central Australia occurred in the Late Devonian to mid-Carboniferous, as part of a world-wide Variscan orogenic episode associated with the collision of Gondwanaland with Laurussia to form Pangea. In the late Visean, Australia drifted rapidly southward from previous low latitudes to a near-polar position. Glacial conditions dominated the Late Carboniferous and earliest Permian. Transtensional basins associated with dextral oroclinal shear along the Panthalassan eastern margin of Australia developed in the Late Carboniferous and persisted until the Late Permian, when an Andean-style magmatic arc was re-established. Large foreland basins inboard of the Late Permian to Early Triassic magmatic arc accumulated major coal deposits during Late Permian volcanic phases, but drastic climatic changes at the end of the Permian, possibly caused by global greenhouse conditions, led to red-bed deposition in the Early Triassic. Pangea began to rift in the mid-Triassic, and by the Late Triassic, the Cimmerian blocks, which lay off northwestern Australia throughout the Palaeozoic, had departed the northern margin of Gondwanaland. A new Andean-style continental magmatic arc became established along the Pacific Ocean margin of Australia. Breakup between Australia-Antarctica and the northern part of Greater India commenced ca. 130 Ma, and between Australia and Antarctica around 96 Ma. At the beginning of the Palaeogene, Australia commenced its northward drift towards its present position. Seafloor spreading between Australia and Antarctica was at first slow, but increased to ca. 5 cm per year around 45 Ma. By 35 Ma, the circum-Antarctic current became established, thereby triggering glaciation in Antarctica. Northern Australia reached the tropics by the beginning of the Miocene, and Australia has progressively moved northwards at 7 to 8 cm per year since.
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NASA Astrophysics Data System (ADS)
Tohver, E.; Playton, T.; Hillbun, K.; Yan, M.; Pisarevsky, S.; Hansma, J.; Roelofs, B.; Trinajstic, K.; Kirschvink, J. L.; Haines, P.
2016-12-01
The Global Polarity Timescale presents a useful basis for chronostratigraphic correlations, but pre-Jurassic records depend on records from sedimentary basins preserved on the continents. At present, the record for the late Devonian is poorly established. Here we present an integrated magnetostratigraphic, biostratigraphic and C-isotope study of the Canning Basin of Western Australia, located on the northern margin of eastern Gondwana. The study region is part of the classic "Devonian Great Barrier Reef", and preserves an outstanding marine record of a prominent mass extinction event (i.e., the Frasnian-Fammenian event, the fifth of the "Big Five" mass extinctions). We present magnetostratigraphic profiles from six different sections (2200 m total) from four separate localities that record different paleowater depths, i.e., lowermost slope to reef/platform deposits of the basin. Correlations between localities are based on conodont assemblages that can be correlated to global records. Paleomagnetic sampling was carried out at the meter-scale for magnetostratigraphic analysis, with duplicate specimens used for carbon isotope stratigraphy. Most samples record a magnetic overprint parallel to the modern geomagnetic direction, but this remanence was removed by laboratory heating to ca. 180°C. Approximately forty percent of samples retain a high temperature characteristic remanent magnetization (ChRM), typically carried by magnetite or hematite. Before using these ChRMs to assign a magnetic polarity, we filtered paleomagnetic directions to eliminate directions >45 degrees from the Fisherian mean direction, avoiding spurious directions and low latitude virtual geomagnetic poles (VGPs) from transitional field directions. The resulting magnetostratigraphic profiles were used to correlate different sections on the basis of matching reversal records, yielding a composite record of the Middle to Late Devonian geomagnetic reversal record. We recognized seventeen major magnetozones, although the total number of individual reversals is much higher. We examine the distribution of both VGPs and ChRMs to assess whether non-Fisherian statistics should be applied to magnetostratigraphic datasets, and we assess the factors that might cause ellipticity of both datasets.
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Ketner, Keith B.
2008-01-01
An area between the towns of Winnemucca and Battle Mountain in northwestern Nevada, termed the arkosic triangle, includes the type areas of the middle to upper Paleozoic Inskip Formation and Havallah sequence, the Upper Devonian to Mississippian Harmony Formation, the Sonoma orogeny, and the Golconda thrust. According to an extensive body of scientific literature, the Havallah sequence, a diverse assemblage of oceanic rocks, was obducted onto the continent during the latest Permian or earliest Triassic Sonoma orogeny by way of the Golconda thrust. This has been the most commonly accepted theory for half a century, often cited but rarely challenged. The tectonic roles of the Inskip and Harmony Formations have remained uncertain, and they have never been fully integrated into the accepted theory. New, and newly interpreted, data are incompatible with the accepted theory and force comprehensive stratigraphic and tectonic concepts that include the Inskip and Harmony Formations as follows: middle to upper Paleozoic strata, including the Inskip, Harmony, and Havallah, form an interrelated assemblage that was deposited in a single basin on an autochthonous sequence of Cambrian, Ordovician, and lowest Silurian strata of the outer miogeocline. Sediments composing the Upper Devonian to Permian sequence entered the basin from both sides, arkosic sands, gravel, limestone olistoliths, and other detrital components entered from the west, and quartz, quartzite, chert, and other clasts from the east. Tectonic activity was expressed as: (1) Devonian uplift and erosion of part of the outer miogeocline; (2) Late Devonian depression of the same area, forming a trough, probably fault-bounded, in which the Inskip, Harmony, and Havallah were deposited; (3) production of intraformational and extrabasinal conglomerates derived from the basinal rocks; and (4) folding or tilting of the east side of the depositional basin in the Pennsylvanian. These middle to upper Paleozoic deposits were compressed in the Jurassic, causing east-verging thrusts in the eastern part of the depositional basin (Golconda thrust) and west-verging thrusts and folds in the western part. Hypotheses involving a far-traveled allochthon that was obducted from an ocean or back-arc basin are incompatible with modern observations and concepts.
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Evolution of Devonian carbonate-shelf margin, Nevada
Morrow, J.R.; Sandberg, C.A.
2008-01-01
The north-trending, 550-km-long Nevada segment of the Devonian carbonate-shelf margin, which fringed western North America, evidences the complex interaction of paleotectonics, eustasy, biotic changes, and bolide impact-related influences. Margin reconstruction is complicated by mid-Paleozoic to Paleogene compressional tectonics and younger extensional and strike-slip faulting. Reports published during the past three decades identify 12 important events that influenced development of shelf-margin settings; in chronological order, these are: (1) Early Devonian inheritance of Silurian stable shelf inargin, (2) formation of Early to early Middle 'Devonian shelf-margin basins, (3) propradation of later Middle Devonian shelf margin, (4) late Middle Devonian Taghanic ondap and continuing long-term Frasnian transgression, (5) initiation of latest Middle Devonian to early Frasnian proto-Antler orogenic forebulge, (6) mid-Frasnian Alamo Impact, (7) accelerated development of proto-Antler forebulge and backbulge Pilot basin, (8) global late Frasnian sentichatovae sea-level rise, (9) end-Frasnian sea-level fluctuations and ensuing mass extinction, (10) long-term Famennian regression and continept-wide erosion, (11) late Famennian emergence: of Ahtler orogenic highlands, and (12) end-Devonian eustatic sea-level fall. Although of considerable value for understanding facies relationships and geometries, existing standard carbonate platform-margin models developed for passive settings else-where do not adequately describe the diverse depositional and, structural settings along the Nevada Devonian platform margin. Recent structural and geochemical studies suggest that the Early to Middle Devonian-shelf-margin basins may have been fault-bound and controlled by inherited Precambrian structure. Subsequently, the migrating latest Middle to Late Devonian Antler orogenic forebulge exerted a dominant control on shelf-margin position, morphology, and sedimentation. ??Geological Society of America.
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Tull, J.F.; Barineau, C.I.; Mueller, P.A.; Wooden, J.L.
2007-01-01
In the southernmost Appalachians, the Hillabee Greenstone, an Ordovician volcanic arc fragment, lies directly atop the outermost Laurentian Devonian-earliest Mississippian(?) shelf sequence at the structural top of the greenschist facies Talladega belt, the frontal metamorphic allochthon along this orogenic segment. The Hillabee Greenstone was emplaced between latest Devonian and middle Mississippian time. It and the uppermost Laurentian section were later repeated together within a series of map-scale imbricate slices of a postmetamorphic, dextral, transpressional, Alleghanian thrust duplex system that placed the high-grade eastern Blue Ridge allochthon atop the Talladega belt. Geochemical and geochronologic (U-Pb zircon) studies indicate that the Hillabee Greenstone's interstratified tholeiitic metabasalt and calc-alkaline metadacite/rhyolite formed within an extensional setting on continental crust ca. 460-470 Ma. Palinspastic reconstructions of the southern Appalachian Ordovician margin place the Hillabee Greenstone outboard of the present position of the Pine Mountain terrane and suggest links to Ordovician plutonism in the overlying eastern Blue Ridge, and possibly to widespread K-bentonite deposits within Ordovician platform units. The tectonic evolution of the Hillabee Greenstone exhibits many unusual and intriguing features, including: (1) premetamorphic emplacement along a basal cryptic thrust, which is remarkably concordant to both hanging wall and footwall sequences across its entire extent (>230 km), (2) formation, transport, and emplacement of the arc fragment accompanied by minimal deformation of the Hillabee Greenstone and underlying outer-margin shelf rocks, (3) emplacement temporally coincident with the adjacent collision of the younger, tectonically independent Ouachita volcanic arc with southeastern Laurentia. These features highlight strong contrasts in the Ordovician-Taconian evolution of the southern and northern parts of the Appalachian orogen. ?? 2007 Geological Society of America.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Barron, L.S.; Ettensohn, F.R.
The Devonian-Mississippian black-shale sequence of eastern North America is a distinctive stratigraphic interval generally characterized by low clastic influx, high organic production in the water column, anaerobic bottom conditions, and the relative absence of fossil evidence for biologic activity. The laminated black shales which constitute most of the black-shale sequence are broken by two major sequences of interbedded greenish-gray, clayey shales which contain bioturbation and pyritized micromorph invertebrates. The black shales contain abundant evidence of life from upper parts of the water column such as fish fossils, conodonts, algae and other phytoplankton; however, there is a lack of evidence ofmore » benthic life. The rare brachiopods, crinoids, and molluscs that occur in the black shales were probably epiplanktic. A significant physical distinction between the environment in which the black sediments were deposited and that in which the greenish-gray sediments were deposited was the level of dissolved oxygen. The laminated black shales point to anaerobic conditions and the bioturbated greenish-gray shales suggest dysaerobic to marginally aerobic-dysaerobic conditions. A paleoenvironmental model in which quasi-estuarine circulation compliments and enhances the effect of a stratified water column can account for both depletion of dissolved oxygen in the bottom environments and the absence of oxygen replenishment during black-shale deposition. Periods of abundant clastic influx from fluvial environments to the east probably account for the abundance of clays in the greenish-gray shale as well as the small amounts of oxygen necessary to support the depauparate, opportunistic, benthic faunas found there. These pulses of greenish-gray clastics were short-lived and eventually were replaced by anaerobic conditions and low rates of clastic sedimentation which characterized most of black-shale deposition.« less
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77 FR 32624 - Eastern Shore Natural Gas Company; Notice of Application
Federal Register 2010, 2011, 2012, 2013, 2014
2012-06-01
... Natural Gas Company; Notice of Application Take notice that on May 14, 2012, Eastern Shore Natural Gas... Natural Gas Act (NGA) and Part 157 of the Commission's regulations, requesting authorization to construct..., Eastern Shore Natural Gas Company, 1110 Forrest Avenue, Suite 201, Dover, Delaware, 19904, or by calling...
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Haines, Seth S.; Varela, Brian A.; Hawkins, Sarah J.; Gianoutsos, Nicholas J.; Thamke, Joanna N.; Engle, Mark A.; Tennyson, Marilyn E.; Schenk, Christopher J.; Gaswirth, Stephanie B.; Marra, Kristen R.; Kinney, Scott A.; Mercier, Tracey J.; Martinez, Cericia D.
2017-06-23
The U.S. Geological Survey (USGS) has completed an assessment of water and proppant requirements and water production associated with the possible future production of undiscovered oil and gas resources in the Three Forks and Bakken Formations (Late Devonian to Early Mississippian) of the Williston Basin Province in Montana and North Dakota. This water and proppant assessment is directly linked to the geology-based assessment of the undiscovered, technically recoverable continuous oil and gas resources that is described in USGS Fact Sheet 2013–3013.
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NASA Astrophysics Data System (ADS)
Hoiland, C. W.; Miller, E. L.; Hourigan, J. K.
2013-12-01
The westernmost Brooks Range, Alaska, is underlain by basement of probable Baltic or Timanian affinity (e.g. Miller et al., 2011; Amato et al., 2009), while the eastern Brooks Range is underlain by Laurentian affinity basement (e.g. Strauss et al., 2013). A post-Timanian and pre-Mississippian suture or contact is thus required based on continuity of late Devonian and younger strata across the Brooks Range (e.g. Dumoulin et al., 2002). This inferred juxtaposition has been proposed as the distal and diachronous (though possibly non-collisional) continuation of the Caledonian orogen (e.g. Moore et al., 2012) but the actual location and character of this suture within basement rocks of the Brooks Range remain speculative. New laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb single grain detrital zircon (DZ) geochronology of basement rocks from the Cosmos Hills, Slate Creek, and Wiseman regions suggest that metamorphic rocks in these regions are Devonian, not pre-Devonian. New SHRIMP-RG analyses of the Kogoluktuk orthogneiss (Cosmos) (zircon: 383 Ma × 5 Ma, 2-sigma errors, consistent with Dillon et al. 1980) revealed no inherited cores from which to infer basement affinity. DZ spectra from metasedimentary and metavolcanic wall rock contain youngest detrital zircon populations with ages (390 Ma) just barely older than the cross-cutting intrusive age, providing tight bracketing of depositional age. These zircon ages are noticeably younger than Caledonian magmatic ages (430-420 Ma) suggesting deposition in a volcanically and tectonically active setting (likely extensional) as originally suggested by Hitzman et al (1986). Zircon spectra (Cosmos) contain notable amounts of "Timanian" age zircons (c. 700-550 Ma), and a spread of zircons from 1-2 Ga (including 1.5-1.6 Ga ages of the Laurentian "magmatic gap', e.g. Grove et al. 2008) more typical of derivation from Baltic rather than Laurentian sources. East in the Wiseman and Slate Creek localities, the detrital signature becomes characteristically Laurentian, with a notable absence of Timanian and "magmatic gap" ages. A youngest age population of 390 Ma still provides a maximum depositional age, but minimum age is poorly constrained. The coarse and feldspathic nature of many of these intercalated volcanic and clastic sequences suggests a proximal provenance, thus serving as a proxy for local pre-Devonian basement ages and affinity. We might, therefore, infer a non-Laurentian basement for the AACM at least as far east as the Cosmos Hills but not further east than the Wiseman region. These Devonian-age volcanic/rift basins may be related to slab roll-back and induced backarc rifting that occurred obliquely across a 'Caledonian' suture, possibly in response to global plate re-organization. Rifting, accompanied by bimodal volcanism (the Ambler Sequence), may have aided the removal and translation of peri-Baltic terranes to a position outboard of the proto-Cordilleran margin ('Northwestern Passage' of Colpron & Nelson, 2009). Further correlations might be drawn with the Sakmarian-Magnitogorsk arcs of the pre-Uralian margin of Europe. These Devonian backarc rift sequences - more widespread than previously thought - may serve as critical additional tie-points for paleogeographic reconstructions of the Arctic.
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The Calvin impact crater and its associated oil production, Cass County, Michigan
DOE Office of Scientific and Technical Information (OSTI.GOV)
Milstein, R.L.
1996-01-01
The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less
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The Calvin impact crater and its associated oil production, Cass County, Michigan
DOE Office of Scientific and Technical Information (OSTI.GOV)
Milstein, R.L.
1996-12-31
The Calvin impact crater is an isolated, nearly circular subsurface structure of Late Ordovician age in southwestern Michigan. The crater is defined by 110 oil and gas test wells, has a diameter of 6.2 km, and consists of a central dome exhibiting 415 m of structural uplift, an annular depression, and an encircling anticlinal rim. Exploration and development of three Devonian oil fields associated wit this structure provide all available subsurface data. All oil production is from the Middle Devonian Traverse Limestone, with the exception of one well producing from the Middle Devonian Sylvania Sandstone. This study models the grossmore » morphology of the Calvin structure using multiple tools and compares the results to known impact craters. Combined results of reflection seismic, gravity, magnetic, and resistivity data, as well as organized relationships between stratigraphic displacement and structural diameters observed in complex impact craters, suggest the Calvin structure is morphologically similar to recognized complex impact craters in sedimentary targets. In addition, individual quartz grains recovered from the Calvin structure exhibit decorated shock lamellae, Boehm lamellae, rhombohederal cleavage, and radiating concussion fractures. Based on the available data, I conclude the Calvin structure is a buried complex impact crater and that the trapping and reservoir characteristics of the associated Calvin 20, Juno Lake, and Calvin 28 oil fields are resultant of the craters morphology.« less
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77 FR 65542 - Eastern Shore Natural Gas Company; Notice of Application
Federal Register 2010, 2011, 2012, 2013, 2014
2012-10-29
... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. CP13-6-000] Eastern Shore Natural Gas Company; Notice of Application Take notice that on October 12, 2012, Eastern Shore Natural Gas Company (Eastern Shore), 1110 Forrest Avenue, Dover, Delaware 19904, filed in the above referenced docket...
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Elliott, James E.; Wells, John David
1968-01-01
The Mill Canyon area is in the eastern part of the Cortez window of the Roberts Mountains thrust belt in the Cortez quadrangle, north-central Nevada. Gold and silver ores have been mined from fissure veins in Jurassic quartz monzonite and in the bordering Wenban Limestone of Devonian age. Geochemical data show anomalies of gold, silver, lead, zinc, copper, arsenic, antimony, mercury, and tellurium. Geologic and geochemical studies indicate that a formation favorable for gold deposition, the Roberts Mountains Limestone of Silurian age, may be found at depth near the mouth of Mill Canyon.
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Barbot, Elise; Vidic, Natasa S; Gregory, Kelvin B; Vidic, Radisav D
2013-03-19
The exponential increase in fossil energy production from Devonian-age shale in the Northeastern United States has highlighted the management challenges for produced waters from hydraulically fractured wells. Confounding these challenges is a scant availability of critical water quality parameters for this wastewater. Chemical analyses of 160 flowback and produced water samples collected from hydraulically fractured Marcellus Shale gas wells in Pennsylvania were correlated with spatial and temporal information to reveal underlying trends. Chloride was used as a reference for the comparison as its concentration varies with time of contact with the shale. Most major cations (i.e., Ca, Mg, Sr) were well-correlated with chloride concentration while barium exhibited strong influence of geographic location (i.e., higher levels in the northeast than in southwest). Comparisons against brines from adjacent formations provide insight into the origin of salinity in produced waters from Marcellus Shale. Major cations exhibited variations that cannot be explained by simple dilution of existing formation brine with the fracturing fluid, especially during the early flowback water production when the composition of the fracturing fluid and solid-liquid interactions influence the quality of the produced water. Water quality analysis in this study may help guide water management strategies for development of unconventional gas resources.
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NASA Astrophysics Data System (ADS)
Mao, Ling-Juan; He, Zhen-Yu; Zhang, Ze-Ming; Klemd, Reiner; Xiang, Hua; Tian, Zuo-Lin; Zong, Ke-Qing
2015-12-01
The Chinese Tianshan in the southwestern part of the Central Asian Orogenic Belt (CAOB) is characterized by a variety of high-grade metamorphic rocks, which provide critical constraints for understanding the geodynamic evolution of the CAOB. In this paper, we present detailed petrological and zircon U-Pb geochronological studies of the Weiya low-pressure and high-temperature (LP-HT) granulites of the Chinese Eastern Tianshan. These granulites were previously considered to be a product of a regional metamorphic orogenic event. Due to different bulk-rock chemistries the Weiya granulites, which occur as lenses within the contact metamorphic aureole of the Weiya granitic ring complex, have a variety of felsic-pelitic and mafic granulites with different textural equilibrium mineral assemblages including garnet-cordierite-sillimanite-bearing granulites, cordierite-sillimanite-bearing granulites, cordierite-orthopyroxene-bearing granulites, and orthopyroxene-clinopyroxene-bearing granulites. Average P-T thermobarometric calculations and conventional geothermobarometry indicates that the Weiya granulites underwent early prograde metamorphism under conditions of 600-650 °C at 3.2-4.2 kbar and peak metamorphism of 750-840 °C at 2.9-6.3 kbar, indicating a rather high geothermal gradient of ca. 60 °C/km. Zircon U-Pb LA-ICP-MS dating revealed metamorphic ages between 244 ± 1 to 237 ± 3 Ma, which are in accordance with the crystallization age of the Weiya granitic ring complex. We suggest that the formation of the Weiya granulites was related to contemporaneous granitic magmatism instead of a regional metamorphic orogenic event. In addition, a Late Devonian metamorphic age of ca. 380 Ma was recorded in zircon mantle domains from two pelitic samples which is consistent with the metamorphic age of the Xingxingxia metamorphic complex in the Chinese Eastern Tianshan. This suggests that the mantle domains of the zircon grains of the Weiya granulites probably formed during the Late Devonian regional metamorphism and were overprinted by the Early Triassic contact metamorphism. Therefore, Early Triassic geodynamic models for the southwestern part of the CAOB, which are based on a previously suggested regional metamorphic orogenic event of the Weiya granulites, need to be viewed with caution.
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Petroleum geology and resources of the North Ustyurt Basin, Kazakhstan and Uzbekistan
Ulmishek, Gregory F.
2001-01-01
The triangular-shaped North Ustyurt basin is located between the Caspian Sea and the Aral Lake in Kazakhstan and Uzbekistan and extends offshore both on the west and east. Along all its sides, the basin is bounded by the late Paleozoic and Triassic foldbelts that are partially overlain by Jurassic and younger rocks. The basin formed on a cratonic microcontinental block that was accreted northward to the Russian craton in Visean or Early Permian time. Continental collision and deformation along the southern and eastern basin margins occurred in Early Permian time. In Late Triassic time, the basin was subjected to strong compression that resulted in intrabasinal thrusting and faulting. Jurassic-Tertiary, mostly clastic rocks several hundred meters to 5 km thick overlie an older sequence of Devonian?Middle Carboniferous carbonates, Upper Precambrian massifs and deformed Caledonian foldbelts. The Carboniferous?Lower Permian clastics, carbonates, and volca-basement is at depths from 5.5 km on the highest uplifts to 11 nics, and Upper Permian?Triassic continental clastic rocks, pri-km in the deepest depressions. marily red beds. Paleogeographic conditions of sedimentation, Three total petroleum systems are identified in the basin. the distribution of rock types, and the thicknesses of pre-Triassic Combined volumes of discovered hydrocarbons in these sysstratigraphic units are poorly known because the rocks have been tems are nearly 2.4 billion barrels of oil and 2.4 trillion cubic penetrated by only a few wells in the western and eastern basin feet of gas. Almost all of the oil reserves are in the Buzachi Arch areas. The basement probably is heterogeneous; it includes and Surrounding Areas Composite Total Petroleum System in 2 Petroleum Geology, Resources?North Ustyurt Basin, Kazakhstan and Uzbekistan the western part of the basin. Oil pools are in shallow Jurassic and Neocomian sandstone reservoirs, in structural traps. Source rocks are absent in the total petroleum system area; therefore, the oil could have migrated from the adjacent North Caspian basin. The North Ustyurt Jurassic Total Petroleum System encompasses the rest of the basin area and includes Jurassic and younger rocks. Several oil and gas fields have been discovered in this total petroleum system. Oil accumulations are in Jurassic clastic reservoirs, in structural traps at depths of 2.5?3 km. Source rocks for the oil are lacustrine beds and coals in the continental Jurassic sequence. Gas fields are in shallow Eocene sandstones in the northern part of the total petroleum system. The origin of the gas is unknown. The North Ustyurt Paleozoic Total Petroleum System stratigraphically underlies the North Ustyurt Jurassic system and occupies the same geographic area. The total petroleum system is almost unexplored. Two commercial flows of gas and several oil and gas shows have been tested in Carboniferous shelf carbonates in the eastern part of the total petroleum system. Source rocks probably are adjacent Carboniferous deep-water facies interpreted from seismic data. The western extent of the total petroleum system is conjectural. Almost all exploration drilling in the North Ustyurt basin has been limited to Jurassic and younger targets. The underlying Paleozoic-Triassic sequence is poorly known and completely unexplored. No wells have been drilled in offshore parts of the basin. Each of three total petroleum systems was assessed as a single assessment unit. Undiscovered resources of the basin are small to moderate. Most of the undiscovered oil probably will be discovered in Jurassic and Neocomian stratigraphic and structural traps on the Buzachi arch, especially on its undrilled off-shore extension. Most of the gas discoveries are expected to be in Paleozoic carbonate reservoirs in the eastern part of the basin.
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78 FR 39719 - Eastern Shore Natural Gas Company; Notice of Application
Federal Register 2010, 2011, 2012, 2013, 2014
2013-07-02
... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [ Docket No. CP13-498-000] Eastern Shore Natural Gas Company; Notice of Application Take notice that on June 13, 2013, Eastern Shore Natural Gas...(c) of the Natural Gas Act to construct, and operate its White Oak Lateral Project (Project) located...
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75 FR 13524 - Eastern Shore Natural Gas Company; Notice of Application
Federal Register 2010, 2011, 2012, 2013, 2014
2010-03-22
... Natural Gas Company; Notice of Application March 15, 2010. Take notice that on March 5, 2010, Eastern Shore Natural Gas Company, (Eastern Shore), 1110 Forrest Avenue, Dover, Delaware 19904, pursuant to section 7(c) of the Natural Gas Act (NGA), as amended, and Part 157 of the Federal Energy Regulatory...
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Evaluation of Methane Sources in Groundwater in Northeastern Pennsylvania
Molofsky, Lisa J; Connor, John A; Wylie, Albert S; Wagner, Tom; Farhat, Shahla K
2013-01-01
Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium-sodium-bicarbonate, sodium-bicarbonate, and sodium-chloride rich waters—indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale-gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale-gas extraction. PMID:23560830
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The crustal structure in the transition zone between the western and eastern Barents Sea
NASA Astrophysics Data System (ADS)
Shulgin, Alexey; Mjelde, Rolf; Faleide, Jan Inge; Høy, Tore; Flueh, Ernst; Thybo, Hans
2018-07-01
We present a crustal-scale seismic profile in the Barents Sea based on new data. Wide-angle seismic data were recorded along a 600 km long profile at 38 ocean bottom seismometer and 52 onshore station locations. The modelling uses the joint refraction/reflection tomography approach where co-located multichannel seismic reflection data constrain the sedimentary structure. Further, forward gravity modelling is based on the seismic model. We also calculate net regional erosion based on the calculated shallow velocity structure. Our model reveals a complex crustal structure of the Baltic Shield to Barents shelf transition zone, as well as strong structural variability on the shelf itself. We document large volumes of pre-Carboniferous sedimentary strata in the transition zone which reach a total thickness of 10 km. A high-velocity crustal domain found below the Varanger Peninsula likely represents an independent crustal block. Large lower crustal bodies with very high velocity and density below the Varanger Peninsula and the Fedynsky High are interpreted as underplated material that may have fed mafic dykes in the Devonian. We speculate that these lower crustal bodies are linked to the Devonian rifting processes in the East European Craton, or belonging to the integral part of the Timanides, as observed onshore in the Pechora Basin.
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NASA Astrophysics Data System (ADS)
Suk, Dongwoo; Van der Voo, Rob; Peacor, Donald R.
Early to middle Paleozoic carbonates of eastern North America have been pervasively remagnetized. In order to determine the process of remagnetization, scanning and scanning transmission electron microscopy have been used to characterize magnetite in thin sections and in concentrated separates. Samples included Ordovician Knox carbonates from east Tennessee, Ordovician Trenton limestone and Devonian Onondaga and Helderberg limestones from New York, and Ordovician Trenton carbonates from Michigan. Inclusions of authigenic minerals within magnetite grains, lack of cations other than iron, and a variety of textural relations all imply that the magnetite is authigenic. These data are consistent with estimates that paleotemperatures never exceeded values that would reset magnetic directions. The remagnetization is thus a chemical remanent magnetization (CRM) rather than viscous remanent magnetization (VRM). As the timing of remagnetization corresponds to the Alleghenian orogeny, the observed relations imply stress-induced crystallization of magnetite that was mediated by fluids, consistent with but not requiring fluid flow on a regional basis.
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Nilsen, T.H.; Moore, T.E.
1982-01-01
The Upper Devonian and Lower Mississippian(?) Kanayut Conglomerate forms a major stratigraphic unit along the crest of the Brooks Range of northern Alaska. It crops out for an east-west distance of about 900 km and a north-south distance of about 65 km. The Kanayut is wholly allochthonous and has probably been transported northward on a series of thrust plates. The Kanayut is as thick as 2,600 m in the east-central Brooks Range. It thins and fines to the south and west. The Kanayut forms the middle part of the allochthonous sequence of the Endicott Group, an Upper Devonian and Mississippian clastic sequence underlain by platform limestones of the Baird Group and overlain by platform limestone, carbonaceous shale, and black chert of the Lisburne Group. The Kanayut overlies the marine Upper Devonian Noatak Sandstone or, where it is missing, the marine Upper Devonian Hunt Fork Shale. It is overlain by the marine Mississippian Kayak Shale. The Kanayut Conglomerate forms the fluvial part of a large, coarse-grained delta that prograded to the southwest in Late Devonian time and retreated in Early Mississippian time. Four sections of the Kanayut Conglomerate in the central Brooks Range and five in the western Brooks Range were measured in 1981. The sections from the western Brooks Range document the presence of fluvial cycles in the Kanayut as far west as the shores of the Chukchi Sea. The Kanayut in this area is generally finer grained than it is in the central and eastern Brooks Range, having a maximum clast size of 3 cm. It is probably about 300 m thick. The upper and lower contacts of the Kanayut are gradational. The lower Kanayut contains calcareous, marine-influenced sandstone within channel deposits, and the upper Kanayut contains probable marine interdistributary-bay shale sequences. The members of the Kanayut Conglomerate cannot be differentiated in this region. In the central Brooks Range, sections of the Kanayut Conglomerate at Siavlat Mountain and Kakivilak Creek are typically organized into fining-upward fluvial cycles. The maximum clast size is about 3 cm in this area. The Kanayut in this region is 200-500 m thick and can be divided into the Ear Peak, Shainin Lake, and Stuver Members. The upper contact of the Kanayut with the Kayak Shale is very gradational at Kakivilak Creek and very abrupt at Siavlat Mountain. Paleocurrents from fluvial strata of the Kanayut indicate sediment transport toward the west and south in both the western and central Brooks Range. The maximum clast size distribution generally indicates westward fining from the Shainin Lake region.
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NASA Astrophysics Data System (ADS)
Zhang, Qi-Qi; Zhang, Shuan-Hong; Zhao, Yue; Liu, Jian-Min
2018-03-01
Some Devonian magmatic rocks have been identified from the northern margin of the North China Block (NCB) in recent years. However, their petrogenesis and tectonic setting are still highly controversial. Here we present new geochronological, Sr-Nd-Hf isotopic and whole-rock chemical data on several newly identified and previously reported Devonian alkaline complexes, including mafic-ultramafic rocks (pyroxenites and gabbros), alkaline rocks (syenites, monzonites) and alkaline granites in the northern NCB. We firstly identified some mafic-ultramafic rocks coeval with monzonite and quartz monzonite in the Sandaogou and Wulanhada alkaline intrusions. New zircon U-Pb dating of 16 samples from the Baicaigou, Gaojiacun, Sandaogou, Wulanhada and Chifeng alkaline intrusions combined with previous geochronological results indicate that the Devonian alkaline rocks emplaced during the early-middle Devonian at around 400-380 Ma and constitute an E-W-trending alkaline magmatic belt that extend ca. 900 km long along the northern margin of the NCB. Whole-rock geochemical and Sr-Nd-Hf isotopic data reveal that the Devonian alkaline rocks were mainly originated from partial melting of a variably enriched lithospheric mantle with different involvement of ancient lower crustal component and fractional crystallization. The Devonian alkaline magmatic belt rocks in the northern NCB are characterized by very weak or no deformations and were most likely related to post-collision extension after arc-continent collision between the Bainaimiao island arc and the northern margin of North China Craton during the latest Silurian. Partial melting of subcontinental lithospheric mantle to produce the Devonian alkaline magmatic rocks suggests that the northern North China Craton has an inhomogeneous, variably enriched subcontinental lithospheric mantle and was characterized by significant vertical crustal growth during the Devonian period.
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NASA Astrophysics Data System (ADS)
Kroner, Uwe; Roscher, Marco; Romer, Rolf L.
2016-06-01
The formation and destruction of supercontinents requires prolonged convergent tectonics between particular plates, followed by intra-continental extension during subsequent breakup stages. A specific feature of the Late Paleozoic supercontinent Pangea is the prolonged and diachronous formation of the collisional belts of the Rheic suture zone coeval with recurrent continental breakup and subsequent formation of the mid-ocean ridge systems of the Paleo- and Neo-Tethys oceans at the Devonian and Permian margins of the Gondwana plate, respectively. To decide whether these processes are causally related or not, it is necessary to accurately reconstruct the plate motion of Gondwana relative to Laurussia. Here we propose that the strain pattern preserved in the continental crust can be used for the reconstruction of ancient plate kinematics. We present Euler pole locations for the three fundamental stages of the Late Paleozoic assembly of Pangea and closure of the Rheic Ocean: (I) Early Devonian (ca. 400 Ma) collisional tectonics affected Gondwana at the Armorican Spur north of western Africa and at the promontory of the South China block/Australia of eastern Gondwana, resulting in the Variscan and the Qinling orogenies, respectively. The Euler pole of the rotational axis between Gondwana and Laurussia is positioned east of Gondwana close to Australia. (II) Continued subduction of the western Rheic Ocean initiates the clockwise rotation of Gondwana that is responsible for the separation of the South China block from Gondwana and the opening of Paleo-Tethys during the Late Devonian. The position of the rotational axis north of Africa reveals a shift of the Euler pole to the west. (III) The terminal closure of the Rheic Ocean resulted in the final tectonics of the Alleghanides, the Mauritanides and the Ouachita-Sonora-Marathon belt, occurred after the cessation of the Variscan orogeny in Central Europe, and is coeval with the formation of the Central European Extensional Province and the opening of Neo-Tethys at ca. 300 Ma. The Euler pole for the final closure of the Rheic Ocean is positioned near Oslo (Laurussia). Thus, the concomitant formation of convergent and divergent plate boundaries during the assembly of Pangea is due to the relocation of the particular rotational axis. From a geodynamic point of view, coupled collisional (western Pangea) and extensional tectonics (eastern Pangea) due to plate tectonic reorganization is fully explained by slab pull and ridge push forces.
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187Re - 187Os nuclear geochronometry: age dating with permil precision
NASA Astrophysics Data System (ADS)
Roller, Goetz
2016-04-01
Recently, 187Re - 187Os nuclear geochronometry, a new dating method combining ideas of nuclear astrophysics with geochronology, has successfully been used to calculate two-point-isochron (TPI) ages for Devonian black gas shales using the isotopic signature of an r-process geochronometer as one data point in a TPI diagram [1]. Based upon a nuclear production ratio 187Re/188Os = 5.873, TPI ages were calculated for 12 SDO-1 (Devonian Ohio Shale, Appalachian Basin) aliquants, for which repeated Re-Os measurements are reported in the literature [2]. TPI ages range from 384.5 ± 2.7 Ma (187Os/188Osi = 0.29413 ± 0.00023) to 387.7 ± 2.1 Ma (187Os/188Osi = 0.29407 ± 0.00019) with a mean of 386.67 ± 1.79 Ma). The result is consistent with the isochronous age from the 12 aliquants alone (386 ± 16 Ma, 187Os/188Osi = 0.31±0.31), which is bracketed by U-Pb ages for the Belpre Ash (381.1 ± 3.3 Ma) and the Tioga Ash bed (390.0 ± 2.5 Ma) [3] from the Appalachian Basin. Hence, SDO-1 can be assigned to the Givetian stage (varcus-zone) of the Middle Devonian, close to the Eifelian/Givetian boundary (using the time-scale of [3] or [4]). If an age is calculated from an isochron diagram for the 12 aliquants including the nuclear geochronometer, a permil precision can be achieved, an interesting feature with respect to any effort towards calibrating the Geologic Timescale. Additionally, a Th/U evolution (or: Th/U-time) diagram can be plotted using U-Pb zircon age data and Th/U ratios from volcanic rocks and ashes reported in the literature [3] for specific Devonian samples from the Appalachian Basin. Since the Re-Os age obtained for SDO-1 can also be connected to its Th/U ratio, it turns out, that Th/U ratios might be helpful age indicators, as demonstrated for the Devonian using the U-Pb and Re-Os datasets. [1] Roller (2015), GSA Abstr. with Programs 47, #248-14. [2] Du Vivier et al. (2014), Earth Planet. Sci. Lett. 389, 23 - 33. [3] Tucker et al. (1998), Earth Planet. Sci. Lett. 158, 175 - 186. [4] Kaufmann (2006), Earth-Sci. Revs. 76, 175 - 190.
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NASA Astrophysics Data System (ADS)
Choi, Jiyoung; Hong, Sung Kyung; Lee, Hyun Suk
2017-04-01
In this study, we investigate organic matter characteristics from the analysis of Rock-Eval6 and biomarker, and estimate methane concentration from headspace method in the Devonian Horn River Formation, which is one of the largest shale reservoir in western Canada. The Horn River Formation consists of the Evie, Otterpark and Muskwa members in ascending stratigraphic order. Total Organic Carbon (TOC) ranges from 0.34 to 7.57 wt%, with an average of 2.78 wt%. The Evie, middle Otterpark and Muskwa members have an average TOC of more than 3%, whereas those of the lower and upper Otterpark Member are less than 2%. Based on Pristane/n-C17 (0.2 0.6) and Phytane/n-C18 (0.3 0.9) ratios, the organic matter in the Evie, middle Otterpark and Muskwa members mainly consists of type II kerogen which are formed in reducing marine environment. Thermal maturity were examined through the use of the distributions of Phenanthrene (P) and Methylphenantrenes (MP) based on m/z 178 and 192 mass chromatograms, respectively (Radke et al., 1982). The methylphenanthrene index (MPI-1) are calculated as follows : MPI-1 = 1.5 × (2MP+3MP)/(P+1MP+9MP), and Ro are calculated as follows : Ro = -0.6 × MPI-1 + 2.3. Estimated Ro ranges between 1.88 and 1.93%, which indicates the last stage of wet gas generation. The methane concentrations in headspace range from 15 to 914 ppmv, with an average of 73.5 ppmv. The methane concentrations in the Evie, middle Otterpark and Muskwa members (up to 914 ppmv) are higher than those of the lower and upper Otterpark Member (up to 75 ppmv). Considering the organic geochemical characteristics and gas concentrations, the shale gas potentials of the Evie, middle Otterpark and Muskwa members are higher than those of other members.
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Evaluation of methane sources in groundwater in northeastern Pennsylvania.
Molofsky, Lisa J; Connor, John A; Wylie, Albert S; Wagner, Tom; Farhat, Shahla K
2013-01-01
Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium-sodium-bicarbonate, sodium-bicarbonate, and sodium-chloride rich waters--indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale-gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale-gas extraction. © 2013, Cabot Oil and Gas Corporation. Groundwater © 2013, National GroundWater Association.
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Bedrock geology of the Mount Carmel and Southington quadrangles, Connecticut
Fritts, Crawford Ellswroth
1962-01-01
New data concerning the geologic structure, stratigraphy, petrography, origin, and ages of bedrock formations in an area of approximately 111 square miles in south-central Connecticut were obtained in the course of detailed geologic mapping from 1957 to 1960. Mapping was done at a scale of 1:24,000 on topographic base maps having a 10-foot contour interval. Bedrock formations are classified in two principal categories. The first includes metasedimentary, meta-igneous, and igneous rocks of Precambrian to Devonian age, which crop out in the western parts of both quadrangles. The second includes sedimentary and igneous rocks of the Newark Group of Late Triassic age, which crop out in the eastern parts of the quadrangles. Diabase dikes, which are Late Triassic or younger in age, intruded rocks in both the western and eastern parts of the map area. Rocks in the western part of the area underwent progressive regional metamorphism in Middle to Late Devonian time. The arrangement of the chlorite, garnet, biotite, staurolite, and kyanite zones here is approximately the mirror-image of metamorphic zones in Dutchess County, New York. However, garnet appeared before biotite in politic rocks in the map area, because the ration MgO/FeO is low. Waterbury Gneiss and the intrusive Woodtick Gneiss are parts of a basement complex of Precambrian age, which forms the core of the Waterbury dome. This structure is near the southern end of a line of similar domes that lie along the crest of a geanticline east of the Green Mountain anticlinorium. The Waterbury Gneiss is believed to have been metamorphosed in Precambrian time as well as in Paleozoic time. The Woodtick Gneiss also may have been metamorphosed more than once. In Paleozoic time, sediments were deposited in geosynclines during two main cycles of sedimentation. The Straits, Southington Mountain, and Derby Hill Schists, which range in age from Cambrian to Ordovician, reflect a transition from relatively clean politic sediments to thinly layered sediments that contained rather high percentages of fine-grained volcanic debris. Metadiabase and metabasalt extrusives above Derby Hill Schist south of the map area represent more intense volcanic activity before or during the early stages of the Taconic disturbance in Late Ordovician time. Impure argillaceous, siliceous, and minor calcareous sediments of the Wepawaug Schist, which is Silurian and Devonian in age, were deposited unconformably on older rocks during renewed subsidence of a geosyncline. The Wepawaug now occupies the trough of a tight syncline, which formed before and during progressive regional metamorphism at the time of the Acadian orogeny in middle to Late Devonian time. Felsic igneous rocks were intruded into the metasedimentary formations of Paleozoic age before the climax of the latest progressive regional metamorphism. Intrusives that gave rise to the Prospect and Ansonia Gneisses were emplaced mainly in the Southington Mountain Schist, and the igneous rocks as well as the host rocks were metamorphosed in the staurolite zone. Although it is possible that these two intrusives were emplaced during the Taconic disturbance, the writer believes it more likely that the igneous rocks from which the Prospect and Ansonia Gneisses formed were emplaced during the Acadian orogeny. Woodbridge Granite, which intruded the Wepawaug Schist, is Devonian in age and undoubtedly was emplaced during the Acadian orogeny. In this area the granite is essentially unmetamorphosed, because it is in the chlorite, garnet, and biotite zones. Southwest of the map area, however, metamorphic equivalents of the Woodbridge are found in Wepawaug Schist in the staurolite zone. The Ansonia Gneiss, therefore, may be a metamorphic equivalent of the Woodbridge Granite. Rocks of Late Triassic age formerly covered the entire map area, but were eroded from the western part after tilting and faulting in Late Triassic time. The New Haven Arkose of the Newark
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Peterson, James A.; Clarke, James W.
1983-01-01
The Volga-Ural petroleum province is in general coincident with the Volga-Ural regional high, a broad upwarp of the east-central part of the Russian (East European) platform. The central part of the province is occupied by the Tatar arch, which contains the major share of the oil fields of the province. The Perm-Bashkir arch forms the northeastern part of the regional high, and the Zhigulevsko-Orenburg arch makes up the southern part. These arches are separated from one another by elongate downwarps. The platform cover overlies an Archean crystalline basement and consists of seven main sedimentation cycles as follows: 1) Riphean (lower Bavly) continental sandstone, shale, and conglomerate beds from 500 to 5,000 m thick deposited in aulacogens. 2) Vendian (upper Bavly) continental and marine shale and sandstone up to 3,000 m thick. 3) Middle Devonian-Tournaisian transgressive deposits, which are sandstone, siltstone, and shale in the lower part and carbonates with abundant reefs in the upper; thickness is 300-1,000 m. In the upper carbonate part is the Kamsko-Kinel trough system, which consists of narrow interconnected deep-water troughs. 4) The Visean-Namurian-Bashkirian cycle, which began with deposition of Visean clastics that draped over reefs of the previous cycle and filled in an erosional relief that had formed in some places on the sediments of the previous cycle. The Visean clastics are overlain by marine carbonates. Thickness of the cycle is 50-800 m. 5) Early Moscovian-Early Permian terrigenous clastic deposits and marine carbonate beds 1,000-3,000 m thick. 6) The late Early Permian-Late Permian cycle, which reflects maximum growth of the Ural Mountains and associated Ural foredeep. Evaporites were first deposited, then marine limestones and dolomites, which intertongue eastward with clastic sediments from the Ural Mountains. 7) Continental redbeds of Triassic age and mixed continental and marine elastic beds of Jurassic and Cretaceous age, which were deposited on the southern, southwestern, and northern margins of the Russian platform; they are generally absent in the Volga-Ural province, however. The Volga-Ural oil and gas basin is a single artesian system that contains seven aquifers separated by seals. The areas of greatest hydraulic head are in the eastern parts of the basin near areas where the aquifers crop out on the western slopes of the Ural Mountains. The Peri-Caspian basin is the principal drainage area of the artesian system. Approximately 600 oil and gas fields and 2,000 pools have been found in the Volga-Ural province. Nine productive sequences are recognized as follows: 1) Upper Proterozoic (Bavly beds), which are promising but not yet commercial. 2) Clastic Devonian, which contains the major reserves and includes the main pays of the super-giant Romashkino field. 3) Carbonate Upper Devonian and lowermost Carboniferous, which is one of the main reef-bearing intervals. 4) Visean (Lower Carboniferous) elastics, which are the main pays in the super-giant Arian field. 5) Carbonate Lower and Middle Carboniferous. 6) Clastic Middle Carboniferous Moscovian. 7) Carbonate Middle and Upper Carboniferous. 8) Carbonate-evaporite Lower Permian, which contains the major gas reserves and the lower part of the Melekess tar deposits. 9) Clastic-carbonate Upper Permian, which contains the major part of the Melekess tar deposits. The Volga-Ural province is divided into several productive regions on a basis of differences in structure, distribution of reservoir and source-rock facies, and general composition of the petroleum accumulations. These regions are the Tatar arch, Birsk saddle, Upper Kama depression, Perm-Bashkir arch, Ufa-Orenburg monocline, Melekess-Sernovodsko-Abdulino basin, Zhligulevsko-Orenburg arch, Ural foredeep, and north borders of the Peri-Casplan depression. Exploration activity has declined in recent years; however, interest remains high in several parts of the province, particula
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NASA Astrophysics Data System (ADS)
Mao, Qigui; Yu, Mingjie; Xiao, Wenjiao; Windley, Brian F.; Li, Yuechen; Wei, Xiaofeng; Zhu, Jiangjian; Lü, Xiaoqiang
2018-03-01
The geodynamic control of mineralization in the accretionary evolution of the Central Asian Orogenic Belt (CAOB) has long been controversial. Here we report new field, geochemical and geochronological data on recently defined porphyry and skarn-type ore deposits (Devonian-Early Carboniferous) in the Kalatage area in the middle of the Harlik-Dananhu arc, Eastern Tianshan, NW China in the southern CAOB, with the aim of better understanding the accretionary tectonics and genesis of porphyry and skarn-type mineralization. The Yudai porphyry Cu-(Au) deposits and the Xierqu skarn Cu-Fe-(Au) deposits are closely associated with Middle Devonian adakitic diorite porphyries (382-390 Ma), which are calc-alkaline and characterized by high Na2O/K2O ratios and Sr contents (310-1020 ppm), strong depletion of HREE (e.g., Yb = 0.80-1.44 ppm) and Y (7.68-14.50 ppm), and all enriched in Rb, Sr, Ba, K and depleted in Nb and Ti. They are characterized by distinctive Eu positive anomalies, high Na2O contents and MORB-like Sr and Nd isotope signatures (high εNd(t) = +6.1 to +7.0 and low (87Sr/86Sr)i = 0.70412-0.70462). These adakites most likely formed by melting of a young/hot subducted oceanic slab, and adakites in general are important carriers of porphyry Cu ± (Au) deposits. Early Carboniferous adakites in the Tuwu area south of Kalatage are known to have similar features. Therefore, skarn-mineralized porphyry adakites get younger from north to south, suggesting southward migration of the Harlik-Dananhu arc from 390 Ma to 322 Ma. These data indicate that partial melting of hot (and/or young) oceanic crustal slabs were an important mechanism of accretionary crustal growth and mineralization in the southern CAOB.
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Devonian and Mississippian rocks of the northern Antelope Range, Eureka County, Nevada
Hose, Richard Kenneth; Armstrong, A.K.; Harris, A.G.; Mamet, B.L.
1982-01-01
Lower through Upper Devonian rocks of the northern Antelope Range, Nev., consist of four formational rank units more than 800 m thick, separated from Mississippian units by an unconformity. The lower three Devonian units, the Beacon Peak Dolomite, McColley Canyon Formation, and Denay Limestone are known in other areas; the top unit, the Fenstermaker Wash Formation, is new. The Mississippian units, more than 280 m thick, are divisible into three units which are unlike coeval units elsewhere, and are herein named the Davis Spring Formation, Kinkead Spring Limestone, and Antelope Range Formation. Systematic sampling of the Devonian sequence has yielded relatively abundant conodonts containing several biostratigraphic ally significant taxa. The Mississippian units contain redeposited conodonts of chiefly Late Devonian and Early Mississippian (Kinderhookian) age together with indigenous Osagean foraminifers and algae in the Kinkead Spring Limestone.
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NASA Astrophysics Data System (ADS)
Husson, Jon M.; Schoene, Blair; Bluher, Sarah; Maloof, Adam C.
2016-02-01
The Devonian Period hosts extraordinary changes to Earth's biosphere. Land plants began their rise to prominence, with early vascular vegetation beginning its colonization of near-shore environments in the latest Silurian. Across the Silurian-Devonian (Pridoli-Lochkovian) transition, carbon isotope analyses of bulk marine carbonates (δC13carb) from Laurentian and Baltic successions reveal a positive δC13carb shift. Known as the Klonk Event, values reach + 5.8 ‰, making it one of the largest carbon isotope excursions in the Phanerozoic. Assigning rates and durations to these significant events requires a robust, precise Devonian time scale. Here we present 675 micritic matrix and 357 fossil-specific δC13carb analyses from the lower Devonian Helderberg Group of New York and West Virginia that exhibit the very positive δC13carb values observed in other Silurian-Devonian basins. This chemostratigraphic dataset is coupled with 66 ID-TIMS U-Pb dates on single zircons from six ash falls intercalated within Helderberg sediments, including dates on the stratigraphically lowest Devonian ashes yet developed. In this work, we (a) demonstrate that matrix and fossil-specific δC13carb values track one another closely in the Helderberg Group, (b) estimate the Silurian-Devonian boundary age in New York to be 421.3 ± 1.2 Ma (2σ; including decay constant uncertainties), and (c) calculate the time required to evolve from baseline to peak δC13carb values at the onset of the Klonk event to be 1.00 ± 0.25 Myr. Under these constraints, a steady-state perturbation to the global carbon cycle can explain the observed excursion with modern fluxes, as long as DIC concentration in the Devonian ocean remained below ∼2× the modern value. Therefore, potential drivers, such as enhanced burial of organic carbon, need not rely on anomalously high total fluxes of carbon to explain the Klonk Event.
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The impact of precession and obliquity on the Late-Devonian greenhouse climate
NASA Astrophysics Data System (ADS)
De Vleeschouwer, D.; Crucifix, M.; Bounceur, N.; Claeys, P. F.
2012-12-01
To date, only few general circulation model (GCM) have been used to simulate the extremely warm greenhouse climate of the Late-Devonian (~370 Ma). As a consequence, the current knowledge on Devonian climate dynamics comes almost exclusively from geological proxy data. Given the fragmentary nature of these data sources, the understanding of the Devonian climate is rather limited. Nonetheless, the Late-Devonian is a key-period in the evolution of life on Earth: the continents were no longer bare but were invaded by land plants, the first forests appeared, soils were formed, fish evolved to amphibians and 70-80% of all animal species were wiped out during the Late Devonian extinction (~376 Ma). In order to better understand the functioning of the climate system during this highly important period in Earth's history, we applied the HadSM3 climate model to the Devonian period under different astronomical configurations. This approach provides insight into the response of Late-Devonian climate to astronomical forcing due to precession and obliquity. Moreover, the assessment of the sensitivity of the Late-Devonian climate to astronomical forcing, presented here, will allow cyclostratigraphers to make better and more detailed interpretations of recurring patterns often observed in Late-Devonian sections. We simulated Late-Devonian climates by prescribing palaeogeography, vegetation distribution and pCO2 concentration (2180 ppm). Different experiments were carried out under 31 different astronomical configurations: three levels for obliquity (ɛ = 22°; 23.5° and 24.5°) and eccentricity (e = 0; 0.03 and 0.07) were chosen. For precession, 8 levels were considered (longitude of the perihelion= 0°; 45°; 90°; 135°; 180°; 235°; 270°). First results suggest that the intensity of precipitation on the tropical Euramerican continent (also known as Laurussia) is highly dependent on changes in precession: During precession maxima (= maximal insolation in SH during winter solstice), precipitation is up to 300 mm/month higher compared to precession minima during the wet season (September - May). During the dry season (June-July-August), the climate is up to 7°C colder during a precession maxima compared to a precession minima. Obliquity doesn't show a significant influence on the climate of the tropical Euramerican continent. However, the imprint of obliquity on the polar climates is extensive with up to 6°C temperature-differences between obliquity maxima and minima at both poles.
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Invasive species and biodiversity crises: testing the link in the late devonian.
Stigall, Alycia L
2010-12-29
During the Late Devonian Biodiversity Crisis, the primary driver of biodiversity decline was the dramatic reduction in speciation rates, not elevated extinction rates; however, the causes of speciation decline have been previously unstudied. Speciation, the formation of new species from ancestral populations, occurs by two primary allopatric mechanisms: vicariance, where the ancestral population is passively divided into two large subpopulations that later diverge and form two daughter species, and dispersal, in which a small subset of the ancestral population actively migrates then diverges to form a new species. Studies of modern and fossil clades typically document speciation by vicariance in much higher frequencies than speciation by dispersal. To assess the mechanism behind Late Devonian speciation reduction, speciation rates were calculated within stratigraphically constrained species-level phylogenetic hypotheses for three representative clades and mode of speciation at cladogenetic events was assessed across four clades in three phyla: Arthropoda, Brachiopoda, and Mollusca. In all cases, Devonian taxa exhibited a congruent reduction in speciation rate between the Middle Devonian pre-crisis interval and the Late Devonian crisis interval. Furthermore, speciation via vicariance is almost entirely absent during the crisis interval; most episodes of speciation during this time were due to dispersal. The shutdown of speciation by vicariance during this interval was related to widespread interbasinal species invasions. The lack of Late Devonian vicariance is diametrically opposed to the pattern observed in other geologic intervals, which suggests the loss of vicariant speciation attributable to species invasions during the Late Devonian was a causal factor in the biodiversity crisis. Similarly, modern ecosystems, in which invasive species are rampant, may be expected to exhibit similar shutdown of speciation by vicariance as an outcome of the modern biodiversity crisis.
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Early Forest Soils and Their Role in Devonian Global Change
Retallack
1997-04-25
A paleosol in the Middle Devonian Aztec Siltstone of Victoria Land, Antarctica, is the most ancient known soil of well-drained forest ecosystems. Clay enrichment and chemical weathering of subsurface horizons in this and other Devonian forested paleosols culminate a long-term increase initiated during the Silurian. From Silurian into Devonian time, red clayey calcareous paleosols show a greater volume of roots and a concomitant decline in the density of animal burrows. These trends parallel the decline in atmospheric carbon dioxide determined from isotopic records of pedogenic carbonate in these same paleosols. The drawdown of carbon dioxide began well before the Devonian appearance of coals, large logs, and diverse terrestrial plants and animals, and it did not correlate with temporal variation in volcanic or metamorphic activity. The early Paleozoic greenhouse may have been curbed by the evolution of rhizospheres with an increased ratio of primary to secondary production and by more effective silicate weathering during Silurian time.
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Gondwana dispersion and Asian accretion: Tectonic and palaeogeographic evolution of eastern Tethys
NASA Astrophysics Data System (ADS)
Metcalfe, I.
2013-04-01
Present-day Asia comprises a heterogeneous collage of continental blocks, derived from the Indian-west Australian margin of eastern Gondwana, and subduction related volcanic arcs assembled by the closure of multiple Tethyan and back-arc ocean basins now represented by suture zones containing ophiolites, accretionary complexes and remnants of ocean island arcs. The Phanerozoic evolution of the region is the result of more than 400 million years of continental dispersion from Gondwana and plate tectonic convergence, collision and accretion. This involved successive dispersion of continental blocks, the northwards translation of these, and their amalgamation and accretion to form present-day Asia. Separation and northwards migration of the various continental terranes/blocks from Gondwana occurred in three phases linked with the successive opening and closure of three intervening Tethyan oceans, the Palaeo-Tethys (Devonian-Triassic), Meso-Tethys (late Early Permian-Late Cretaceous) and Ceno-Tethys (Late Triassic-Late Cretaceous). The first group of continental blocks dispersed from Gondwana in the Devonian, opening the Palaeo-Tethys behind them, and included the North China, Tarim, South China and Indochina blocks (including West Sumatra and West Burma). Remnants of the main Palaeo-Tethys ocean are now preserved within the Longmu Co-Shuanghu, Changning-Menglian, Chiang Mai/Inthanon and Bentong-Raub Suture Zones. During northwards subduction of the Palaeo-Tethys, the Sukhothai Arc was constructed on the margin of South China-Indochina and separated from those terranes by a short-lived back-arc basin now represented by the Jinghong, Nan-Uttaradit and Sra Kaeo Sutures. Concurrently, a second continental sliver or collage of blocks (Cimmerian continent) rifted and separated from northern Gondwana and the Meso-Tethys opened in the late Early Permian between these separating blocks and Gondwana. The eastern Cimmerian continent, including the South Qiangtang block and Sibumasu Terrane (including the Baoshan and Tengchong blocks of Yunnan) collided with the Sukhothai Arc and South China/Indochina in the Triassic, closing the Palaeo-Tethys. A third collage of continental blocks, including the Lhasa block, South West Borneo and East Java-West Sulawesi (now identified as the missing "Banda" and "Argoland" blocks) separated from NW Australia in the Late Triassic-Late Jurassic by opening of the Ceno-Tethys and accreted to SE Sundaland by subduction of the Meso-Tethys in the Cretaceous.
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NASA Astrophysics Data System (ADS)
Vermeesch, P.; Avigad, D.
2009-04-01
Following the Neoproterozoic Pan-African orogeny, the Arabian-Nubian Shield (ANS) of North Africa and Arabia was eroded and then covered by Cambrian sandstones that record the onset of platform sedimentation. We applied K-feldspar 40Ar/39Ar, zircon and apatite fission track and apatite (U-Th)/He thermochronology to detritus from Cambrian sandstones of southern Israel deposited at about 500 Ma. U-Pb detrital zircon ages from these sandstones predate deposition and record the earlier Neoproterozoic crustal evolution of the Pan-African orogens. 40Ar/39Ar ages from 50 single grains of K-feldspar yield a Cambrian mean of approximately 535 Ma. The 40Ar/39Ar age spectrum of a multi-grain K-feldspar aliquot displays diffusion behaviour compatible with >560 Ma cooling later affected by a heating event. Assuming that the high temperature domains of the K-feldspars have not been affected by subsequent (hydro)thermal events, and taking previously published K-Ar and Rb-Sr ages from other parts of the East African Orogen at face value, these ages apparently record Pan-African thermal resetting below a thick volcano-sedimentary pile similar to the Saramuj conglomerate in Jordan and/or the Hammamat in Egypt. Detrital zircon fission track (ZFT) ages cluster around 380 Ma, consistent with previous ZFT results from Neoproterozoic basement and sediments of the region, revealing that the Cambrian platform sequence experienced a middle Devonian thermal event and low-grade metamorphism. Regional correlation indicates that during Devonian time the sedimentary cover atop the Cambrian in Israel was never in excess of 2.5 km, requiring an abnormally steep geothermal gradient to explain the complete ZFT annealing. A basal Carboniferous unconformity can be traced from Syria to southern Saudi Arabia, suggesting that the observed Devonian ZFT ages represent a regional tectonothermal event. Similar Devonian ZFT ages were reported from ANS basement outcrops in the Eastern Desert, 500 km south of Eilat. The detrital apatites we studied all have extremely rounded cores suggestive of a distant provenance, but some grains also feature distinct euhedral U-rich apatite overgrowth rims. Authigenic apatite may have grown during the late Devonian thermal event we dated by ZFT, coinciding with existing Rb-Sr ages from authigenic clays in the same deposits and leading to the conclusion that the Devonian event was probably hydrothermal. Like the ZFT ages, the detrital apatite fission track (AFT) ages were also completely reset after deposition. Sixty single grain detrital apatite fission track (AFT) ages group at ~270 Ma with significant dispersion. Inverse modeling of the AFT data indicate extended and/or repeated residence in the AFT partial annealing zone, in turn suggesting an episodic burial-erosion history during the Mesozoic caused by low-amplitude vertical motions. Seven detrital apatite (U-Th)/He ages scatter between 33 and 77 Ma, possibly resulting from extreme compositional zonation associated with the authigenic U-rich overgrowths. The ~70 Ma (U-Th)/He ages are more likely to be accurate, setting 1-2 km as an upper limit (depending on the geothermal gradient) on the post-Cretaceous exhumation of the Cambrian sandstone and showing no evidence for substantial denudation related to Tertiary rifting of the Red Sea.
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Geological fieldwork in the Libyan Sahara: A multidisciplinary approach
NASA Astrophysics Data System (ADS)
Meinhold, Guido; Whitham, Andrew; Howard, James P.; Morton, Andrew; Abutarruma, Yousef; Bergig, Khaled; Elgadry, Mohamed; Le Heron, Daniel P.; Paris, Florentin; Thusu, Bindra
2010-05-01
Libya is one of the most hydrocarbon-rich countries in the world. Its large oil and gas reserves make it attractive to international oil and gas companies, which provide the impetus for field-based research in the Libyan Sahara. North Africa is made up of several enormous intracratonic basins, two of which are found in southern Libya: the Murzuq Basin, in the southwest, and the Kufra Basin, in the southeast, separated by the Tibesti Massif. Both basins are filled with Palaeozoic and Mesozoic clastic sedimentary rocks reaching up to 5 km in thickness. These basins developed from the Cambrian onwards following an earlier period of orogenesis (the Panafrican Orogeny) in the Neoproterozoic. Precambrian metasediments and granitoids are unconformably overlain by Cambrian and Ordovician conglomerates and sandstones. They show a transitional environment from continental to shallow marine. Skolithos-bearing sandstone is common in Ordovician strata. By the Late Ordovician, ice masses had developed across West Gondwana. Upon melting of the ice sheets in the latest Hirnantian, large volumes of melt water and sediment were released that were transported to the periphery of Gondwana. In Libya, these sediments are predominantly highly mature sandstones, which, in many places, are excellent hydrocarbon reservoirs. Polished and striated surfaces in these sandstones clearly point to their glaciogenic origin. Following Late Ordovician deglaciation, black shale deposition occurred in the Silurian. Some of the shales are characterised by high values of total organic carbon (TOC). These shales are commonly referred to as ‘hot shales' due to their associated high uranium content, and are the major source rock for Early Palaeozoic-sourced hydrocarbons in North Africa. Late Ordovician glaciogenic sediments and the Early Silurian ‘hot shales' are therefore the main focus of geological research in the Libyan Sahara. Fluvial conglomerates and sandstones of Devonian age unconformably overlie these strata. Marine intervals occur in the Late Devonian, and the Carboniferous is characterised by shallow marine clastic sediments with carbonate horizons. Permian rocks are only known from subsurface drill cores and comprise continental and deltaic facies. The centre of the Murzuq Basin has been relatively well investigated by drilling and seismic profiles. The basin margins, however, lack detailed geological investigation. In comparison, the Kufra Basin is underexplored with few boreholes drilled. Our studies have focused on the eastern and northern margins of the Murzuq Basin and the northern, eastern and western margins of the Kufra Basin. The main objective of fieldwork has been to characterise the Infracambrian-Lower Palaeozoic stratigraphy, deduce the structural evolution of each study area, and to collect samples for follow-up analyses including provenance studies and biostratigraphy. In addition to outcrop-based fieldwork shallow boreholes up to 70 m depth were successfully drilled in the Early Silurian shales. The unweathered samples retrieved from two of the boreholes have been used for biostratigraphical and whole-rock geochemical investigations. The provenance study of the sandstone succession with conventional heavy mineral analysis together with U-Pb zircon dating provides, for the first time, an understanding of the ancient source areas. Because most of the Early Palaeozoic succession in southern Libya is barren of fossils, heavy mineral chemostratigraphy is moreover used as a correlation test on surface outcrops in the Kufra and Murzuq basins.
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Evaporite karst of northern lower Michigan
Black, T.J.
1997-01-01
Michigan has three main zones of evaporite karst: collapse breccia in Late Silurian deposits of the Mackinac Straits region; breccia, collapse sinks, and mega-block collapse in Middle Devonian deposits of Northern Lower Michigan, which overlaps the preceding area; and areas of soil swallows in sinks of Mississippian deposits between Turner and Alabaster in Arenac and Iosco counties, and near Grand Rapids in Kent County. The author has focused his study on evaporite karst of the Middle Devonian deposits. The Middle Devonian depos its are the Detroit River Group: a series consisting of limestone, dolomite, shale, salt, gypsum, and anhydrite. The group occurs from subcrop, near the surface, to nearly 1400 feet deep from the northern tip of the Southern Peninsula to the south edge of the "solution front" Glacial drift is from zero to 350 feet thick. Oil and gas exploration has encountered some significant lost-circulation zones throughout the area. Drilling without fluid returns, casing-seal failures, and lost holes are strong risks in some parts of the region. Lost fluid returns near the top of the group in nearby areas indicate some karst development shortly after deposition. Large and irregular lost-circulation zones, linear and patch trends of large sink holes, and 0.25 mile wide blocks of down-dropped land in the northern Lower Peninsula of Michigan were caused by surface- and ground-water movement along faults into the Detroit River Group. Glaciation has removed some evidence of the karst area at the surface. Sinkhole development, collapse valleys, and swallows developed since retreat of the glacier reveal an active solution front in the Detroit River Group.
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NASA Astrophysics Data System (ADS)
Neef, G.; Bottrill, R. S.; Cohen, D. R.
1996-05-01
Extensive and well exposed, fine-grained fluvial sandstone and less common pebbly coarse-grained fluvial sandstone of Devonian age, crop out in the northern Barrier Ranges of far west New South Wales, Australia. These strata were deposited largely on low-gradient alluvial fans in a basin and range landscape and contain common sedimentary structures (especially streaming lineations and tabular cross-beds). Around 400 of these sedimentary structures were measured to determine the palaeoflow trends of the sheet floods, streams or rivers which deposited the sandstone. The strata are mapped as the Mid Devonian Coco Range Sandstone and the Late Devonian Nundooka Sandstone, which together are around 2.7 km thick. They were deposited at the western margin of the large Emsian to Early Carboniferous Darling Basin. The Coco Range Sandstone is Emsian to Eifelian in age (based on fragments) of fossil fish) and it is separated from the Frasnian-Famennian (Late Devonian) Nundooka Sandstone by the north-trending Nundooka Creek Fault. The eastern boundary of the Nundooka Sandstone is formed by the Western Boundary Fault. Eastward of this fault is the north-trending and 40 km wide Bancannia Trough, which contains gently folded Late Silurian to Early Carboniferous strata up to 7.5 km thick. Most of the Coco Range Sandstone and all of the Nundooka Sandstone are non-graded, fine and very fine-grained, light brown sub-litharenites which are considered to have been deposited mainly on low-gradient alluvial fans. Sedimentary successions of 1.75 to 5.25 m thickness in the fine-grained arenite usually commence with Sm (massive or slumped) → Sh (laminated arenite) or St (trough cross-beds) → Sp (tabular cross-bedded sandstone). An erosional surface commonly underlies the sedimentary successions and they are interpreted to be the result of deposition from decelerating sheet floods. Units composed of tabular cross-bedded strata several metres thick are rarely channelised and are interpreted to represent deposition within braided streams flowing upon the fans or deposited at the margin of sheet floods. In the Coco Range Sandstone there are two sheet-like coarse pebbly arenite units (The Valley Tank and Copi Dam Members) which together total 200 m in thickness. Unimodal palaeocurrent trends and heavy mineral suites from within the coarse-grained arenite indicate a derivation from the south near Broken Hill. Sedimentary structures within the coarse-grained arenite indicate a Platte River style of deposition upon distal braid plains, whereas local interdigitation of coarse-grained arenite with fine arenite strata shows that deposition was essentially continuous (i.e. the coarse arenite do not overlie unconformities) and the two lithotypes represent interdigitation of alluvial fans and braid plain deposition. The northward progradation of the coarse arenite units was probably due to a sudden retardation of basement downwarping.
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Well-Production Data and Gas-Reservoir Heterogeneity -- Reserve Growth Applications
Dyman, Thaddeus S.; Schmoker, James W.
2003-01-01
Oil and gas well production parameters, including peakmonthly production (PMP), peak-consecutive-twelve month production (PYP), and cumulative production (CP), are tested as tools to quantify and understand the heterogeneity of reservoirs in fields where current monthly production is 10 percent or less of PMP. Variation coefficients, defined as VC= (F5-F95)/F50, where F5, F95, and F50 are the 5th, 95th, and 50th (median) fractiles of a probability distribution, are calculated for peak and cumulative production and examined with respect to internal consistency, type of production parameter, conventional versus unconventional accumulations, and reservoir depth. Well-production data for this study were compiled for 69 oil and gas fields in the Lower Pennsylvanian Morrow Formation of the Anadarko Basin, Oklahoma. Of these, 47 fields represent production from marine clastic facies. The Morrow data were supplemented by data from the Upper Cambrian and Lower Ordovician Arbuckle Group, Middle Ordovician Simpson Group, Middle Pennsylvanian Atoka Formation, and Silurian and Lower Devonian Hunton Group of the Anadarko Basin, one large gas field in Upper Cretaceous reservoirs of north-central Montana (Bowdoin field), and three areas of the Upper Devonian and Lower Mississippian Bakken Formation continuous-type (unconventional) oil accumulation in the Williston Basin, North Dakota and Montana. Production parameters (PMP, PYP, and CP) measure the net result of complex geologic, engineering, and economic processes. Our fundamental hypothesis is that well-production data provide information about subsurface heterogeneity in older fields that would be impossible to obtain using geologic techniques with smaller measurement scales such as petrographic, core, and well-log analysis. Results such as these indicate that quantitative measures of production rates and production volumes of wells, expressed as dimensionless variation coefficients, are potentially valuable tools for documenting reservoir heterogeneity in older fields for field redevelopment and risk analysis.
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36. EASTERN VIEW OF BOTTOM CONE OF GAS COOLING TOWER ...
36. EASTERN VIEW OF BOTTOM CONE OF GAS COOLING TOWER No. 1 AND TWO GAS COOLING TOWER SERVICE WATER PUMPS IN THE GAS WASHER PUMP HOUSE. - U.S. Steel Duquesne Works, Basic Oxygen Steelmaking Plant, Along Monongahela River, Duquesne, Allegheny County, PA
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Tectonic setting of synorogenic gold deposits of the Pacific Rim
Goldfarb, R.J.; Phillips, G.N.; Nokleberg, W.J.
1998-01-01
More than 420 million oz of gold were concentrated in circum-Pacific synorogenic quartz loades mainly during two periods of continental growth, one along the Gondwanan margin in the Palaeozoic and the other in the northern Pacific basin between 170 and 50 Ma. These ores have many features in common and can be grouped into a single type of lode gold deposit widespread throughout clastic sedimentary-rock dominant terranes. The auriferous veins contain only a few percent sulphide minerals, have gold:silver ratios typically greater than 1:1, show a distinct association with medium grade metamorphic rocks, and may be associated with large-scale fault zone. Ore fluids are consistently of low salinity and are CO2-rich. In the early and middle Palaeozoic in the southern Pacific basin, a single immense turbidite sequence was added to the eastern margin of Gondwanaland. Deformation of these rocks in southeastern Australia was accompanied by deposition of at least 80 million oz of gold in the Victorian sector of the Lachlan fold belt mainly during the Middle and Late Devonian. Lesser Devonian gold accumulations characterized the more northerly parts of the Gondwanan margin within the Hodgkinson-Broken River and Thomson fold belts. Additional lodes were emplaced in this flyschoid sequence in Devonian or earlier Palaeozoic times in what is now the Buller Terrane, Westland, New Zealand. Minor post-Devonian growth of Gondwanaland included terrane collision and formation of gold-bearing veins in the Permian in Australia's New England fold belt and in the Jurassic-Early Cretaceous in New Zealand's Otago schists. Collision and accretion of dozens of terranes for a 100-m.y.-long period against the western margin of North America and eastern margin of Eurasia led to widespread, lattest Jurassic to Eocene gold veining in the northern Pacific basin. In the former location, Late Jurassic and Early Cretaceous veins and related placer deposits along the western margin of the Sierra Nevada batholith have yielded more than 100 million oz of gold. Additional significant ore-forming events during the development of North America's Cordilleran orogen included those in the Klamath Mountains region, California in the Late Jurassic and Early Cretaceous; the Klondike district, Yukon by the Early Cretaceous; the Nome and Fairbanks districts, Alaska, and the Bridge River district, British Columbia in the middle Cretaceous; and the Juneau gold belt, Alaska in the Eocene. Gold-bearing veins deposited during the Late Jurassic and Early Cretaceous terrane collision that formed the present-day Russian Far East have been the source for more than 130 million oz of placer gold. The abundance of gold-bearing quartz-carbonate veins throughout the Gondwanan, North American and Eurasian continental margins suggests the migration and concentration of large fluid volumes during continental growth. Such volumes could be released during orogenic heating of hydrous silicate mineral phases within accreted marine strata. The common temporal association between gold veining and magmatism around the Pacific Rim reflects these thermal episodes. Melting of the lower thickened crust during arc formation, slab rollback and extensional tectonism, and subduction of a slab window beneath the seaward part of the forearc region can all provide the required heat for initation of the ore-forming processes.
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Early Paleozoic magmatic events in the eastern Klamath Mountains, northern California
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wallin, E.T.; Mattinson, J.M.; Potter, A.W.
1988-02-01
New U-Pb zircon ages for nine samples of tonalite and pegmatitic trondhjemite from the Trinity ophiolite and associated melange reveal a complex history of magmatic activity extending back into the earliest Cambrian, much older than previously believed. Earlier investigations, based on limited data, recognized lower Paleozoic crustal elements in the eastern Klamath terrane (EKT) ranging in age from Middle Ordovician to Early to Middle Devonian. The new work in the Yreka-Callahan area of the EKT confirms the Ordovician (440-475 Ma) and younger ages, but reveals for the first time the presence of tonalitic rocks that crystallized during a narrow timemore » interval at about 565-570 Ma. The authors also recognize younger, Late Silurian magmatism at 412 Ma. In the context of available mapping, these ages indicate that the Trinity ophiolite is broadly polygenetic because parts of it yield crystallization ages that span approximately 150 m.y. Superjacent dismembered units of probable early Paleozoic age may be tectonostratigraphically equivalent to the Sierra City melange in the northern Sierra Nevada.« less
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Ordovician "sphinctozoan" sponges from Prince of Wales Island, southeastern Alaska
Rigby, J.K.; Karl, Susan M.; Blodgett, R.B.; Baichtal, J.F.
2005-01-01
A faunule of silicified hypercalcified "sphinctozoan" sponges has been recovered from a clast of Upper Ordovician limestone out of the Early Devonian Karheen Formation on Prince of Wales Island in southeastern Alaska. Included in the faunule are abundant examples of the new genus Girtyocoeliana, represented by Girtyocoeliana epiporata (Rigby and Potter), and Corymbospongia adnata Rigby and Potter, along with rare Corymbospongia amplia n. sp., and Girtyocoelia(?) sp., plus common Amblysiphonella sp. 1 and rare Amblysiphonella(?) sp. 2. The assemblage is similar to that from Ordovician clasts from the eastern Klamath Mountains of northern California. This indicates that the Alexander terrane of southeastern Alaska is related paleogeographically to the lithologically and paleontologically similar terrane of the eastern Klamath Mountains. This lithology and fossil assemblage of the clast cannot be tied to any currently known local rock units on Prince of Wales Island. Other clasts in the conglomerate appear to have been locally derived, so it is inferred that the limestone clasts were also locally derived, indicating the presence of a previously undocumented Ordovician limestone unit on northern Prince of Wales Island.
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Sandberg, C.A.; Morrow, J.R.; Poole, F.G.; Ziegler, W.
2003-01-01
The classic type section of the Devils Gate Limestone at Devils Gate Pass is situated on the eastern slope of a proto-Antler forebulge that resulted from convergence of the west side of the North American continent with an ocean plate. The original Late Devonian forebulge, the site of which is now located between Devils Gate Pass and the Northern Antelope Range, separated the continental-rise to deep-slope Woodruff basin on the west from the backbulge Pilot basin on the east. Two connections between these basins are recorded by deeper water siltstone beds at Devils Gate; the older one is the lower tongue of the Woodruff Formation, which forms the basal unit of the upper member of the type Devils Gate, and the upper one is the overlying, thin lower member of the Pilot Shale. The forebulge and the backbulge Pilot basin originated during the middle Frasnian (early Late Devonian) Early hassi Zone, shortly following the Alamo Impact within the punctata Zone in southern Nevada. Evidence of this impact is recorded by coeval and reworked shocked quartz grains in the Northern Antelope Range and possibly by a unique bypass-channel or megatsunami-uprush sandy diamictite within carbonate-platform rocks of the lower member of the type Devils Gate Limestone. Besides the Alamo Impact and three regional events, two other important global events are recorded in the Devils Gate section. The semichatovae eustatic rise, the maximum Late Devonian flooding event, coincides with the sharp lithogenetic change at the discordant boundary above the lower member of the Devils Gate Limestone. Most significantly, the Devils Gate section contains the thickest and most complete rock record in North America across the late Frasnian linguiformis Zone mass extinction event. Excellent exposures include not only the extinction shale, but also a younger. Early triangularis Zone tsunamite breccia, produced by global collapse of carbonate platforms during a shallowing event that continued into the next younger Famennian Stage. The Northern Antelope Range section is located near the top of the west side of the proto-Antler forebulge. Because of its unusual, tectonically active location, unmatched at any other Nevada localities, this section records only four regional and global events during a timespan slightly longer than that of the Devils Gate section. The global semichatovae rise and late Frasnian mass extinction event are largely masked because of the depositional complexities resulting from this location.
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Amato, J.M.; Toro, J.; Miller, E.L.; Gehrels, G.E.; Farmer, G.L.; Gottlieb, E.S.; Till, A.B.
2009-01-01
The Seward Peninsula of northwestern Alaska is part of the Arctic Alaska-Chukotka terrane, a crustal fragment exotic to western Laurentia with an uncertain origin and pre-Mesozoic evolution. U-Pb zircon geochronology on deformed igneous rocks reveals a previously unknown intermediate-felsic volcanic event at 870 Ma, coeval with rift-related magmatism associated with early breakup of eastern Rodinia. Orthogneiss bodies on Seward Peninsula yielded numerous 680 Ma U-Pb ages. The Arctic Alaska-Chukotka terrane has pre-Neoproterozoic basement based on Mesoproterozoic Nd model ages from both 870 Ma and 680 Ma igneous rocks, and detrital zircon ages between 2.0 and 1.0 Ga in overlying cover rocks. Small-volume magmatism occurred in Devonian time, based on U-Pb dating of granitic rocks. U-Pb dating of detrital zircons in 12 samples of metamorphosed Paleozoic siliciclastic cover rocks to this basement indicates that the dominant zircon age populations in the 934 zircons analyzed are found in the range 700-540 Ma, with prominent peaks at 720-660 Ma, 620-590 Ma, 560-510 Ma, 485 Ma, and 440-400 Ma. Devonian- and Pennsylvanian-age peaks are present in the samples with the youngest detrital zircons. These data show that the Seward Peninsula is exotic to western Laurentia because of the abundance of Neoproterozoic detrital zircons, which are rare or absent in Lower Paleozoic Cordilleran continental shelf rocks. Maximum depositional ages inferred from the youngest detrital age peaks include latest Proterozoic-Early Cambrian, Cambrian, Ordovician, Silurian, Devonian, and Pennsylvanian. These maximum depositional ages overlap with conodont ages reported from fossiliferous carbonate rocks on Seward Peninsula. The distinctive features of the Arctic Alaska-Chukotka terrane include Neoproterozoic felsic magmatic rocks intruding 2.0-1.1 Ga crust overlain by Paleozoic carbonate rocks and Paleozoic siliciclastic rocks with Neoproterozoic detrital zircons. The Neoproterozoic ages are similar to those in the peri-Gondwanan Avalonian-Cadomian arc system, the Timanide orogen of Baltica, and other circum-Arctic terranes that were proximal to Arctic Alaska prior to the opening of the Amerasian basin in the Early Cretaceous. Our Neoproterozoic reconstruction places the Arctic Alaska-Chukotka terrane in a position near Baltica, northeast of Laurentia, in an arc system along strike with the Avalonian-Cadomian arc terranes. Previously published faunal data indicate that Seward Peninsula had Siberian and Laurentian links by Early Ordovician time. The geologic links between the Arctic Alaska-Chukotka terrane and eastern Laurentia, Baltica, peri-Gondwanan arc terranes, and Siberia from the Paleoproterozoic to the Paleozoic help to constrain paleogeographic models from the Neoproterozoic history of Rodinia to the Mesozoic opening of the Arctic basin. ?? 2009 Geological Society of America.
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De Vleeschouwer, David; Da Silva, Anne-Christine; Sinnesael, Matthias; Chen, Daizhao; Day, James E; Whalen, Michael T; Guo, Zenghui; Claeys, Philippe
2017-12-22
The Late Devonian envelops one of Earth's big five mass extinction events at the Frasnian-Famennian boundary (374 Ma). Environmental change across the extinction severely affected Devonian reef-builders, besides many other forms of marine life. Yet, cause-and-effect chains leading to the extinction remain poorly constrained as Late Devonian stratigraphy is poorly resolved, compared to younger cataclysmic intervals. In this study we present a global orbitally calibrated chronology across this momentous interval, applying cyclostratigraphic techniques. Our timescale stipulates that 600 kyr separate the lower and upper Kellwasser positive δ 13 C excursions. The latter excursion is paced by obliquity and is therein similar to Mesozoic intervals of environmental upheaval, like the Cretaceous Ocean-Anoxic-Event-2 (OAE-2). This obliquity signature implies coincidence with a minimum of the 2.4 Myr eccentricity cycle, during which obliquity prevails over precession, and highlights the decisive role of astronomically forced "Milankovitch" climate change in timing and pacing the Late Devonian mass extinction.
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Linking Fossil Fish Cyclicity and Paleoenvironmental Proxies in the mid-Devonian
NASA Astrophysics Data System (ADS)
Grogan, D.; Whiteside, J. H.; Trewin, N. H.; Johnson, J. E.
2009-12-01
The significant radiation of fishes throughout the Devonian, combined with the abundance of well-preserved fossil fish assemblages from this period, provides for a high-resolution record of prevalent fish taxa in the Orcadian basin of North Scotland. In addition to their ability to serve as a lake-level and lake-chemistry proxy, the waxing and waning of dominant fish taxa exhibit a pronounced cyclicity, suggesting they respond to broader climate rhythms. Recent studies of mid-Devonian lacustrine sedimentary sequences have quantitatively demonstrated the presence of Milankovitch cyclicity in geochemical and gamma ray proxy records. Spectral analysis of gamma ray data show a strong obliquity peak usually associated with ice-house conditions; this obliquity signal is unexpected as tropical latitudes in the mid-Devonian are traditionally thought to have been in a greenhouse climate. Geochemical data include the measurement of bulk carbon and nitrogen stable isotopes, molecule-specific carbon isotopes of plant biomarkers, and depth ranks from eight sections of the Caithness Flagstone Group of the Orcadian Basin. Evidence for orbital forcing of climate change paired with the fossil fish record provides a unique opportunity to establish an astronomically calibrated timescale for the mid-Devonian, as well as to make a quantitative assessment of the validity of a greenhouse climate existing in the mid-Devonian.
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Placoderms (Armored Fish): Dominant Vertebrates of the Devonian Period
NASA Astrophysics Data System (ADS)
Young, Gavin C.
2010-05-01
Placoderms, the most diverse group of Devonian fishes, were globally distributed in all habitable freshwater and marine environments, like teleost fishes in the modern fauna. Their known evolutionary history (Early Silurian-Late Devonian) spanned at least 70 million years. Known diversity (335 genera) will increase when diverse assemblages from new areas are described. Placoderms first occur in the Early Silurian of China, but their diversity remained low until their main evolutionary radiation in the Early Devonian, after which they became the dominant vertebrates of Devonian seas. Most current placoderm data are derived from the second half of the group's evolutionary history, and recent claims that they form a paraphyletic group are based on highly derived Late Devonian forms; 16 shared derived characters are proposed here to support placoderm monophyly. Interrelationships of seven placoderm orders are unresolved because Silurian forms from China are still poorly known. The relationship of placoderms to the two major extant groups of jawed fishes—osteichthyans (bony fishes) and chondrichthyans (cartilaginous sharks, rays, and chimaeras)—remains uncertain, but the detailed preservation of placoderm internal braincase structures provides insights into the ancestral gnathostome (jawed vertebrate) condition. Placoderms provide the most complex morphological and biogeographic data set for the Middle Paleozoic; marked discrepancies in stratigraphic occurrence between different continental regions indicate strongly endemic faunas that were probably constrained by marine barriers until changes in paleogeography permitted range enlargement into new areas. Placoderm distributions in time and space indicate major faunal interchange between Gondwana and Laurussia near the Frasnian-Famennian boundary; closure of the Devonian equatorial ocean is a possible explanation.
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Hunt, Andrew G.; Darrah, Thomas H.; Poreda, Robert J.
2012-01-01
Silurian and Devonian natural gas reservoirs present within New York state represent an example of unconventional gas accumulations within the northern Appalachian Basin. These unconventional energy resources, previously thought to be noneconomically viable, have come into play following advances in drilling (i.e., horizontal drilling) and extraction (i.e., hydraulic fracturing) capabilities. Therefore, efforts to understand these and other domestic and global natural gas reserves have recently increased. The suspicion of fugitive mass migration issues within current Appalachian production fields has catalyzed the need to develop a greater understanding of the genetic grouping (source) and migrational history of natural gases in this area. We introduce new noble gas data in the context of published hydrocarbon carbon (C1,C2+) (13C) data to explore the genesis of thermogenic gases in the Appalachian Basin. This study includes natural gases from two distinct genetic groups: group 1, Upper Devonian (Marcellus shale and Canadaway Group) gases generated in situ, characterized by early mature (13C[C1 C2][13C113C2]: –9), isotopically light methane, with low (4He) (average, 1 103 cc/cc) elevated 4He/40Ar and 21Ne/40Ar (where the asterisk denotes excess radiogenic or nucleogenic production beyond the atmospheric ratio), and a variable, atmospherically (air-saturated–water) derived noble gas component; and group 2, a migratory natural gas that emanated from Lower Ordovician source rocks (i.e., most likely, Middle Ordovician Trenton or Black River group) that is currently hosted primarily in Lower Silurian sands (i.e., Medina or Clinton group) characterized by isotopically heavy, mature methane (13C[C1 – C2] [13C113C2]: 3), with high (4He) (average, 1.85 103 cc/cc) 4He/40Ar and 21Ne/40Ar near crustal production levels and elevated crustal noble gas content (enriched 4He,21Ne, 40Ar). Because the release of each crustal noble gas (i.e., He, Ne, Ar) from mineral grains in the shale matrix is regulated by temperature, natural gases obtain and retain a record of the thermal conditions of the source rock. Therefore, noble gases constitute a valuable technique for distinguishing the genetic source and post-genetic processes of natural gases.
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Ruppert, Leslie F.; Lentz, Erika E.; Tewalt, Susan J.; Román Colón, Yomayra A.; Ruppert, Leslie F.; Ryder, Robert T.
2014-01-01
The Appalachian basin contains abundant coal and petroleum resources that have been studied and extracted for at least 150 years. In this volume, U.S. Geological Survey (USGS) scientists describe the geologic framework and geochemical character of the fossil-fuel resources of the central and southern Appalachian basin. Separate subchapters (some previously published) contain geologic cross sections; seismic profiles; burial history models; assessments of Carboniferous coalbed methane and Devonian shale gas; distribution information for oil, gas, and coal fields; data on the geochemistry of natural gas and oil; and the fossil-fuel production history of the basin. Although each chapter and subchapter includes references cited, many historical or other important references on Appalachian basin and global fossil-fuel science were omitted because they were not directly applicable to the chapters.
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Rimmer, Susan M.; Hawkins, Sarah J.; Scott, Andrew C.; Cressler, Walter L.
2015-01-01
Fossil charcoal provides direct evidence for fire events that, in turn, have implications for the evolution of both terrestrial ecosystems and the atmosphere. Most of the ancient charcoal record is known from terrestrial or nearshore environments and indicates the earliest occurrences of fire in the Late Silurian. However, despite the rise in available fuel through the Devonian as vascular land plants became larger and trees and forests evolved, charcoal occurrences are very sparse until the Early Mississippian where extensive charcoal suggests well-established fire systems. We present data from the latest Devonian and Early Mississippian of North America from terrestrial and marine rocks indicating that fire became more widespread and significant at this time. This increase may be a function of rising O2 levels and the occurrence of fire itself may have contributed to this rise through positive feedback. Recent atmospheric modeling suggests an O2 low during the Middle Devonian (around 17.5%), with O2 rising steadily through the Late Devonian and Early Mississippian (to 21–22%) that allowed for widespread burning for the first time. In Devonian-Mississippian marine black shales, fossil charcoal (inertinite) steadily increases up-section suggesting the rise of widespread fire systems. There is a concomitant increase in the amount of vitrinite (preserved woody and other plant tissues) that also suggests increased sources of terrestrial organic matter. Even as end Devonian glaciation was experienced, fossil charcoal continued to be a source of organic matter being introduced into the Devonian oceans. Scanning electron and reflectance microscopy of charcoal from Late Devonian terrestrial sites indicate that the fires were moderately hot (typically 500–600 °C) and burnt mainly surface vegetation dominated by herbaceous zygopterid ferns and lycopsids, rather than being produced by forest crown fires. The occurrence and relative abundance of fossil charcoal in marine black shales are significant in that these shales may provide a more continuous record of fire than is preserved in terrestrial environments. Our data support the idea that major fires are not seen in the fossil record until there is both sufficient and connected fuel and a high enough atmospheric O2 content for it to burn.
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Lamsdell, James C; Selden, Paul A
2017-01-01
Mass extinctions have altered the trajectory of evolution a number of times over the Phanerozoic. During these periods of biotic upheaval a different selective regime appears to operate, although it is still unclear whether consistent survivorship rules apply across different extinction events. We compare variations in diversity and disparity across the evolutionary history of a major Paleozoic arthropod group, the Eurypterida. Using these data, we explore the group's transition from a successful, dynamic clade to a stagnant persistent lineage, pinpointing the Devonian as the period during which this evolutionary regime shift occurred. The late Devonian biotic crisis is potentially unique among the "Big Five" mass extinctions in exhibiting a drop in speciation rates rather than an increase in extinction. Our study reveals eurypterids show depressed speciation rates throughout the Devonian but no abnormal peaks in extinction. Loss of morphospace occupation is random across all Paleozoic extinction events; however, differential origination during the Devonian results in a migration and subsequent stagnation of occupied morphospace. This shift appears linked to an ecological transition from euryhaline taxa to freshwater species with low morphological diversity alongside a decrease in endemism. These results demonstrate the importance of the Devonian biotic crisis in reshaping Paleozoic ecosystems. © 2016 The Author(s). Evolution © 2016 The Society for the Study of Evolution.
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Pardo, Jason D.; Huttenlocker, Adam K.; Small, Bryan J.
2014-01-01
Complete, exceptionally-preserved skulls of the Permian lungfish Persephonichthys chthonica gen. et sp. nov. are described. Persephonichthys chthonica is unique among post-Devonian lungfishes in preserving portions of the neurocranium, permitting description of the braincase of a stem-ceratodontiform for the first time. The completeness of P. chthonica permits robust phylogenetic analysis of the relationships of the extant lungfish lineage within the Devonian lungfish diversification for the first time. New analyses of the relationships of this new species within two published matrices using both maximum parsimony and Bayesian inference robustly place P. chthonica and modern lungfishes within dipterid-grade dipnoans rather than within a clade containing Late Devonian ‘phaneropleurids’ and common Late Paleozoic lungfishes such as Sagenodus. Monophyly of post-Devonian lungfishes is not supported and the Carboniferous-Permian taxon Sagenodus is found to be incidental to the origins of modern lungfishes, suggesting widespread convergence in Late Paleozoic lungfishes. Morphology of the skull, hyoid arch, and pectoral girdle suggests a deviation in feeding mechanics from that of Devonian lungfishes towards the more dynamic gape cycle and more effective buccal pumping seen in modern lungfishes. Similar anatomy observed previously in ‘Rhinodipterus’ kimberyensis likely represents an intermediate state between the strict durophagy observed in most Devonian lungfishes and the more dynamic buccal pump seen in Persephonichthys and modern lungfishes, rather than adaptation to air-breathing exclusively. PMID:25265394
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Gas Hydrate Characterization from a 3D Seismic Dataset in the Eastern Deepwater Gulf of Mexico
DOE Office of Scientific and Technical Information (OSTI.GOV)
McConnell, Dan
The presence of a gas hydrate petroleum system and seismic attributes derived from 3D seismic data are used for the identification and characterization of gas hydrate deposits in the deepwater eastern Gulf of Mexico. In the central deepwater Gulf of Mexico (GoM), logging while drilling (LWD) data provided insight to the amplitude response of gas hydrate saturation in sands, which could be used to characterize complex gas hydrate deposits in other sandy deposits. In this study, a large 3D seismic data set from equivalent and distal Plio-Pleistocene sandy channel deposits in the deepwater eastern Gulf of Mexico is screened formore » direct hydrocarbon indicators for gas hydrate saturated sands.« less
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Tectonics and hydrocarbon potential of the Barents Megatrough
DOE Office of Scientific and Technical Information (OSTI.GOV)
Baturin, D.; Vinogradov, A.; Yunov, A.
1991-08-01
Interpretation of geophysical data shows that the geological structure of the Eastern Barents Shelf, named Barents Megatrough (BM), extends sublongitudinally almost from the Baltic shield to the Franz Josef Land archipelago. The earth crust within the axis part of the BM is attenuated up to 28-30 km, whereas in adjacent areas its thickness exceeds 35 km. The depression is filled with of more than 15 km of Upper Paleozoic, Mesozoic, and Cenozoic sediments overlying a folded basement of probable Caledonian age. Paleozoic sediments, with exception of the Upper Permian, are composed mainly of carbonates and evaporites. Mesozoic-Cenozoic sediments are mostlymore » terrigenous. The major force in the development of the BM was due to extensional tectonics. Three rifting phases are recognizable: Late Devonian-Early Carboniferous, Early Triassic, and Jurassic-Early Cretaceous. The principal features of the geologic structure and evolution of the BM during the late Paleozoic-Mesozoic correlate well with those of the Sverdup basin, Canadian Arctic. Significant quantity of Late Jurassic-Early Cretaceous basaltic dikes and sills were intruded within Triassic sequence during the third rifting phase. This was probably the main reason for trap disruption and hydrocarbon loss from Triassic structures. Lower Jurassic and Lower Cretaceous reservoir sandstones are most probably the main future objects for oil and gas discoveries within the BM. Upper Jurassic black shales are probably the main source rocks of the BM basin, as well as excellent structural traps for hydrocarbon fluids from the underlying sediments.« less
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NASA Astrophysics Data System (ADS)
Majka, Jarosław; Mazur, Stanisław; Kośmińska, Karolina; Dudek, Krzysztof
2015-04-01
Blueschists are tracers of sutures, thus marking fossil subduction zones at convergent plate boundaries and providing important constraints on plate tectonic reconstructions. Their occurrences are scarce in the Variscan belt owing to a strong collisional overprint but just because of that each locality deserves particular attention. The Variscan blueschists must have formed during the early stage of the Variscan Orogeny and may represent a vestige of missing marginal basins fringing the Rheic Ocean at the onset of subduction. The studied rocks from the Kopina Mt. consist mainly of garnet, glaucophane, clinozoisite-epidote, chlorite-I, titanite, hematite and quartz. The original high-pressure assemblage is overprinted by later, lower pressure paragenesis, which comprises mostly Ca-amphiboles, chlorite-II, albite and K-feldspar. The latter occurs in polymineral inclusions in other phases together with albite and chlorite that are interpreted as phengite breakdown products. Garnet shows chemical compositional variation from Alm54Prp3Grs30Sps13 in the cores to Alm66Prp4Grs29Sps1 in the rims. The almandine zoning is bowl-shaped, whereas spessartine profiles show bell-shaped trends. The grossular and pyrope contents are generally constant throughout the grain. Rather gradual changes in the chemical zoning suggest a progressive, one-step garnet growth pattern. Glaucophane, although commonly well preserved, in some cases disintegrates to the albite-chlorite assemblage. The pressure-temperature (P-T) conditions were estimated using the phase equilibrium modelling in the NCKFMMnASHTO system using the PerpleX software. The compositional isopleths cross cut in the stability field of Grt+Gln+Ep+Chl+Pheng+Ttn+Hem+Q. P-T estimates indicate that the peak conditions occur at c. 14-17 kbar and 470-500°C, which corresponds to quite a low geothermal gradient in the range of 8-10°C/km. The P-T conditions estimated lie on a low temperature geotherm that is typical for a relatively cool subduction of the oceanic crust. Therefore, the origin of the studied rocks dates back to the time preceding accretion of the eastern Variscides and defines one of the key tectonic boundaries in the Bohemian Massif. A mechanism for syn-collisional emplacement and exhumation of the Kopina blueschists can be tentatively explained through activation of the double subduction system operating towards the east. First subduction commenced already in the Early Devonian and operated beneath an island arc located in proximity to the Saxothuringian margin, within the Rheic Ocean. After the mid-Devonian exhumation of the Central Sudetes allochthon, another subduction system was initiated along the eastern margin of the Rheic Ocean, beneath the Brunia microplate. Subducted oceanic crust of the Rheic Ocean (including the Kopina Mt. blueschists) reached peak metamorphic conditions in the Late Devonian, the event pronounced by a continental arc volcanism along the Brunian margin. Exhumation of the subducted oceanic crust was accommodated by the slab roll-back, which is inferred from the bimodal age and spatial distribution of the volcanic activity within the Brunian active margin. Shortly after the Kopina Mt. blueschists exhumation this eastern subduction system became probably inactive. In contrast, the western one involving the Saxothuringian margin was still operating leading to the subsequent collision with Brunia in the Early Carboniferous that produced a widespread high temperature overprint mostly wiping up the earlier metamorphic history.
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NASA Astrophysics Data System (ADS)
Zhang, Donghai; Huang, Baochun; Zhao, Jie; Meert, Joseph; Zhang, Ye; Liang, Yalun; Bai, Qianhui; Zhao, Qian; Zhou, Tinghong
2017-04-01
We carry out a combined paleomagnetic and U-Pb geochronologic study on Paleozoic strata ranging from Lower Devonian to Upper Permian in mid-eastern Inner Mongolia, NE China with the purpose of puzzling out the timing and location of the final closure of Paleo-Asian Ocean (PAO), and thus provides further implications for the evolution of eastern Central Asian Orogenic Belt (CAOB). Inside North Margin of North China Block (NMNCB), 20 sites from Middle Permian Elitu formation and 9 sites from Lower Permian Sanmianjing formation yields a high temperature Characteristic Remanent Magnetism (ChRM) of Dg=330.9, Ig=54.3, Kg=4.9, a95g=14.9 N= 24 before and Ds=347.4, Is=38.1, Ks=28.6, a95s=5.6, N=24 after tilt correction. 13 sites from Songliao-Xilinhot Block (SXB) isolate a ChRM of Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=13; Ds=222.9, Is=20.5, Ks=15.7 a95s=11.9, N=13 with a positive fold test, which suggests a likely primary magnetization. Inside of Khingan-Airgin Sum Block (KAB), 2 different component is extracted from Lower Devonian Niqiuhe formation, Upper Carboniferous Baoligaomiao formation and Lower Permian Dashizhai formation. A high temperature Component A (Dg=28.3, Ig=29.7, Kg=24.4, a95g=6.6, N= 21; Ds=49.8, Is=62.1, Ks=57.4, a95s=4.2, N=21) with a synfolding origin is derived from 21 sites of Baoligaomiao formation in west KAB, which is traditionally named as Uliastai passive continental margin, whilst 11 sites from Lower Devonian Niqiuhe formation in east KAB generate a post-folding Component B (Dg=196.6, Ig=36.4, Kg=18.0, a95g=11.1, N=11; Ds=222.9, Is=20.5, Ks=15.7, a95s=11.9, N=11) with a possible remagnetization in early Permian suggested by widely exposed granitic intrusion of 299 Ma in adjacent areas. Accordingly, 4 paleomagnetic poles are calculated as early-middle Permian of NMNCB (Plat=67.9°N, Plong=326.7°E, A95=4.2°), early Permian of SXB (Plat=45.3°N, Plong=250.3°E, A95=5.8°), late Carboniferous of west KAB (Plat=55.1°N, Plong=187.8°E, A95=6.2°) and early Permian of (Plat=-16.3°N, Plong=109.1°E, A95=8.4°). The early Permian paleomagnetic pole of SXB and NMNCB are located at a common small circle centered around the reference site (43° N, 114° E), whilst late Carboniferous pole of west KAB and early Permian pole of east KAB share a similar paleolatitude, about 17.8° higher than that of SXB and NMNCB, with a huge 85° longitudinal difference in between. These data indicate the final closure of PAO happened at the northern Hegenshan-Heihe Suture Zone (HHSZ) after early Permian instead of the pre-assumed southern Solonker-Xar Moron Suture Zone (SXMSZ) with a remaining open paleogeography of Paleo-Asian Ocean between SXB and KAB by early Permian. Keywords: Paleo-Asian Ocean, Central Asian Orogenic Belt, Paleomagnetism, Paleolatitude, Late Paleozoic, XMOB.
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Fiber glass reinforcement wrap gets DOT nod for gas-line use
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1993-12-13
Panhandle Eastern Corp.'s Texas Eastern Transmission Corp. has become the first US natural-gas pipeline company to install, under federal waiver, a fiber glass reinforcement on an in-service gas pipeline. The Clock Spring repair system was installed in August on six segments of Texas Eastern's 20-in. gas pipeline in Fayette County, Ohio, after the company had received a US Department of Transportation (DOT) waiver to use the system in place of conventional DOT-mandated repair methods. The paper describes the conventional methods, as well as comparing costs of both methods.
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Lower permian reef-bank bodies’ characterization in the pre-caspian basin
NASA Astrophysics Data System (ADS)
Wang, Zhen; Wang, Yankun; Yin, Jiquan; Luo, Man; Liang, Shuang
2018-02-01
Reef-bank reservoir is one of the targets for exploration of marine carbonate rocks in the Pre-Caspian Basin. Within this basin, the reef-bank bodies were primarily developed in the subsalt Devonian-Lower Permian formations, and are dominated by carbonate platform interior and margin reef-banks. The Lower Permian reef-bank present in the eastern part of the basin is considered prospective. This article provides a sequence and sedimentary facies study utilizing drilling and other data, as well as an analysis and identification of the Lower Permian reef-bank features along the eastern margin of the Pre-Caspian Basin using sub-volume coherence and seismic inversion techniques. The results indicate that the sub-volume coherence technique gives a better reflection of lateral distribution of reefs, and the seismic inversion impedance enables the identification of reef bodies’ development phases in the vertical direction, since AI (impedance) is petrophysically considered a tool for distinguishing the reef limestone and the clastic rocks within the formation (limestone exhibits a relatively high impedance than clastic rock). With this method, the existence of multiple phases of the Lower Permian reef-bank bodies along the eastern margin of the Pre-Caspian Basin has been confirmed. These reef-bank bodies are considered good subsalt exploration targets due to their lateral connectivity from south to north, large distribution range and large scale.
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NASA Astrophysics Data System (ADS)
Dan, Wei; Wang, Qiang; Zhang, Xiu-Zheng; Zhang, Chunfu; Tang, Gong-Jian; Wang, Jun; Ou, Quan; Hao, Lu-Lu; Qi, Yue
2018-05-01
Recognizing the early-developed intra-oceanic arc is important in revealing the early evolution of East Paleo-Tethys Ocean. In this study, new SIMS zircon U-Pb dating, O-Hf isotopes, and whole-rock geochemical data are reported for the newly-discovered Late Devonian-Early Carboniferous arc in Qiangtang, central Tibet. New dating results reveal that the eastern Riwanchaka volcanic rocks were formed at 370-365 Ma and were intruded by the 360 Ma Gangma Co alkali feldspar granites. The volcanic rocks consist of basalts, andesites, dacites, and rhyodacites, whose geochemistry is similar to that typical of subduction-related volcanism. The basalts and andesites were generated by partial melting of the fluid and sediment-melt metasomatized mantle, respectively. The rhyodacites and dacites were probably derived from the fractional crystallization of andesites and from partial melting of the juvenile underplated mafic rocks, respectively. The Gangma Co alkali feldspar granites are A-type granites, and were possibly derived by partial melting of juvenile underplated mafic rocks in a post-collisional setting. The 370-365 Ma volcanic arc was characterized by basalts with oceanic arc-like Ce/Yb ratios and by rhyodacites with mantle-like or slightly higher zircon δ18O values, and it was associated with the contemporary ophiolites. Thus, we propose that it is the earliest intra-oceanic arc in the East Paleo-Tethys Ocean, and was accreted to the Northern Qiangtang Terrane during 365-360 Ma.
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Organic metamorphism in the Lower Mississippian-Upper Devonian Bakken shales-II: Soxhlet extraction.
Price, L.C.; Ging, T.; Love, A.; Anders, D.
1986-01-01
We report on Soxhlet extraction (and subsequent related analyses) of 39 Lower Mississippian-Upper Devonian Bakken shales from the North Dakota portion of the Williston Basin, and analyses of 28 oils from the Basin. Because of the influence of primary petroleum migration, no increase in the relative or absolute concentrations of hydrocarbons or bitumen was observed at the threshold of intense hydrocarbon generation (TIHG), or during mainstage hydrocarbon generation in the Bakken shales. Thus, the maturation indices that have been so useful in delineating the TIHG and mainstage hydrocarbon generation in other studies were of no use in this study, where these events could clearly be identified only by Rock-Eval pyrolysis data. The data of this study demonstrate that primary petroleum migration is a very efficient process. Four distinctive classes of saturated hydrocarbon gas chromatograms from the Bakken shales arose from facies, maturation, and primary migration controls. As a consequence of maturation, the % of saturated hydrocarbons increased in the shale extract at the expense of decreases in the resins and asphaltenes. Measurements involving resins and asphaltenes appear to be excellent maturation indices in the Bakken shales. Two different and distinct organic facies were present in immature Bakken shales. -from Authors
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The Eastring gas pipeline in the context of the Central and Eastern European gas supply challenge
NASA Astrophysics Data System (ADS)
Mišík, Matúš; Nosko, Andrej
2017-11-01
Ever since the 2009 natural gas crisis, energy security has been a crucial priority for countries of Central and Eastern Europe. Escalating in 2014, the conflict between Ukraine and Russia further fuelled negative expectations about the future development of energy relations for the region predominantly supplied by Russia. As a response to the planned cessation of gas transit through the Brotherhood pipeline, which brings Russian gas to Europe via Ukraine and Slovakia, the Slovak transmission system operator Eustream proposed the Eastring pipeline. This Perspective analyses this proposal and argues that neither the perceived decrease in Slovak energy security nor the loss of economic rent from the international gas transit should be the main policy driver behind such a major infrastructure project. Although marketed as an answer to current Central and Eastern European gas supply security challenges, the Eastring pipeline is actually mainly focused on issues connected to the Slovak gas transit.
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NASA Astrophysics Data System (ADS)
Anfinson, Owen Anthony
More than 2300 detrital zircon uranium-lead (U-Pb) ages, 32 176Hf/177Hf (eHf) isotopic values, 37 apatite helium (AHe) ages, and 72 zircon helium (ZHe) ages represent the first in-depth geochronologic and thermochronologic study of Franklinian Basin strata in the Canadian Arctic and provide new insight on >500 M.y. of geologic history along the northern Laurentian margin (modern orientation). Detrital zircon U-Pb age data demonstrate that the Franklinian Basin succession is composed of strata with three distinctly different provenance signatures. Neoproterozoic and Lower Cambrian formations contain detrital zircon populations consistent with derivation from Archean to Paleoproterozoic gneisses and granites of the west Greenland--northeast Canadian Shield. Lower Silurian to Middle Devonian strata are primarily derived from foreland basin strata of the East Greenland Caledonides (Caledonian orogen). Middle Devonian to Upper Devonian strata also contain detrital zircon populations interpreted as being primarily northerly derived from the continental landmass responsible for the Ellesmerian Orogen (often referred to as Crockerland). U-Pb age data from basal turbidites of the Middle to Upper Devonian clastic succession suggest Crockerland contributed sediment to the northern Laurentian margin by early-Middle Devonian time and that prior to the Ellesmerian Orogeny Crockerland had a comparable geologic history to the northern Baltica Craton. Detrital zircon U-Pb ages in Upper Devonian strata suggest Crockerland became the dominant source by the end of Franklinian Basin sedimentation. Mean eHf values from Paleozoic detrital zircon derived from Crockerland suggest the zircons were primarily formed in either an island arc or continental arc built on accreted oceanic crust setting. ZHe cooling ages from Middle and Upper Devonian strata were not buried deeper than 7 km since deposition and suggest Crockerland was partially exhumed during the Caledonian Orogen. AHe cooling ages are partially reset since deposition and experienced varying burial histories depending on stratigraphic and geographic location within the basin. AHe ages from Middle Devonian strata from the western margin of the basin indicate episodes of exhumation associated with clastic influxes of sediment into the Sverdrup Basin during the Late Jurassic-Early Cretaceous and Late Cretaceous.
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Wainwright, A.J.; Tosdal, R.M.; Wooden, J.L.; Mazdab, F.K.; Friedman, R.M.
2011-01-01
Uranium-Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu-Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt, the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions (??Nd(t) range from +3.1 to +7.5 and 206Pb/204Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have <1.5% TiO2) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu-Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism. Uranium-Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu-Au deposits are ~372Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu-Au mineralization are ~366Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu-Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu-Au deposits from younger magmatic suites in the district. ?? 2010 Elsevier B.V.
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Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-14
... of 16-inch-diameter natural gas pipeline; One meter station/pig \\1\\ launcher at the interconnect with Texas Eastern Transmission, LP, near Honey Brook, Pennsylvania; \\1\\ A ``pig'' is a tool that is inserted... other purposes. One mainline valve; and One interconnect/pig receiver at the existing Eastern Shore...
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NASA Astrophysics Data System (ADS)
Baidder, L.; Michard, A.; Soulaimani, A.; Fekkak, A.; Eddebbi, A.; Rjimati, E.-C.; Raddi, Y.
2016-07-01
Conflicting views are expressed in literature concerning fold interference patterns in thick-skinned tectonic context (e.g. Central Anti-Atlas and Rocky Mountains-Colorado areas). Such patterns are referred to superimposed events with distinct orientation of compression or to the inversion of paleofaults with distinct strike during a single compressional event. The present work presents a case study where both types of control on fold interference are likely to be combined. The studied folds occur in the Tafilalt-Maider area of eastern Anti-Atlas, i.e. in the E-trending foreland fold belt of the Meseta Variscan Orogen in the area where it connects with the SE-trending, intracontinental Ougarta Variscan belt. Detail mapping documents unusual fold geometries such as sigmoidal and croissant- or boomerang-shaped folds associated with a complex major fault pattern. The folded rock material corresponds to a 6-8 km-thick Cambrian-Serpukhovian sedimentary pile that includes alternating competent and incompetent formations. The basement of the Paleozoic succession is made up of rhomboedric tilted blocks that formed during the Cambrian rifting of north-western Gondwana and the Devonian dislocation of the Sahara platform. The latter event is responsible for an array of paleofaults bounding the Maider and South Tafilalt Devonian-Early Carboniferous basins with respect to the adjoining high axes. The Variscan Orogeny began during the Bashkirian-Westphalian with a N-S direction of shortening that converted the NW-trending Ougnat-Ouzina paleogeographic high into a mega dextral shear zone. Folds developed on top of a moving mosaic of basement blocks, being oriented en echelon on the inverted paleofaults or above intensely sheared fault zones. However, a dominantly NE-SW compression responsible for the building of the Ougarta belt also affected the studied area, presumably during the latest Carboniferous-Early Permian. The resulting fold interference pattern and peculiar geometries (J. Tijekht croissant-shaped fold) would exemplify a dual control of deformation by both the variably oriented basement paleofaults and the evolution of the regional shortening direction with time.
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Federal Register 2010, 2011, 2012, 2013, 2014
2012-09-14
... Natural Gas Company; Notice of Availability of the Environmental Assessment for the Proposed 2012... prepared an environmental assessment (EA) for the 2012 Greenspring Expansion Project (Project) proposed by Eastern Shore Natural Gas Company (ESNG) in the above-referenced docket. ESNG requests authorization to...
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NASA Astrophysics Data System (ADS)
Pease, V.; Scarrow, J. H.; Silva, I. G. Nobre; Cambeses, A.
2016-11-01
Devonian mafic magmatism of the northern East European Craton (EEC) has been variously linked to Uralian subduction, post-orogenic extension associated with Caledonian collision, and rifting. New elemental and isotopic analyses of Devonian basalts from the Timan Range and Kanin Peninsula, Russia, in the northern EEC constrain magma genesis, mantle source(s) and the tectonic process(es) associated with this Devonian volcanism to a rift-related context. Two compositional groups of low-K2O tholeiitic basalts are recognized. On the basis of Th concentrations, LREE concentrations, and (LREE/HREE)N, the data suggest two distinct magma batches. Incompatible trace elements ratios (e.g., Th/Yb, Nb/Th, Nb/La) together with Nd and Pb isotopes indicate involvement of an NMORB to EMORB 'transitional' mantle component mixed with variable amounts of a continental component. The magmas were derived from a source that developed high (U,Th)/Pb, U/Th and Sm/Nd over time. The geochemistry of Timan-Kanin basalts supports the hypothesis that the genesis of Devonian basaltic magmatism in the region resulted from local melting of transitional mantle and lower crust during rifting of a mainly non-volcanic continental rifted margin.
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Devonian of the Northern Rocky Mountains and plains
Sandberg, Charles A.; Mapel, William J.
1967-01-01
5. Undivided uppermost Devonian (Famennian, to V-VI) and lowermost Mississippian (Tournaisian, cuI-lower cuIIα) carbonaceous and clastic rocks deposited in six shallow basins interspersed among areas uplifted during the penecontemporaneous Antler orogeny.
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NASA Astrophysics Data System (ADS)
Qin, Yu; Feng, Qiao; Chen, Gang; Chen, Yan; Zou, Kaizhen; Liu, Qian; Jiao, Qianqian; Zhou, Dingwu; Pan, Lihui; Gao, Jindong
2018-05-01
The Maoniushan Formation in the northern part of the North Qaidam Orogen (NQO), NW China, contains key information on a Paleozoic change in tectonic setting of the NQO from compression to extension. Here, new zircon U-Pb, petrological, and sedimentological data for the lower molasse sequence of the Maoniushan Formation are used to constrain the timing of this tectonic transition. Detrital zircons yield U-Pb ages of 3.3-0.4 Ga with major populations at 0.53-0.4, 1.0-0.56, 2.5-1.0, and 3.3-2.5 Ga. The maximum depositional age of the Maoniushan Formation is well constrained by a youngest detrital zircon age of ∼409 Ma. Comparing these dates with geochronological data for the region indicates that Proterozoic-Paleozoic zircons were derived mainly from the NQO as well as the Oulongbuluk and Qaidam blocks, whereas Archean zircons were probably derived from the Oulongbuluk Block and the Tarim Craton. The ∼924, ∼463, and ∼439 Ma tectonothermal events recorded in this region indicate that the NQO was involved in the early Neoproterozoic assembly of Rodinia and early Paleozoic microcontinental convergence. A regional angular unconformity between Devonian and pre-Devonian strata within the NQO suggests a period of strong mountain building between the Oulongbuluk and Qaidam blocks during the Silurian, whereas an Early Devonian post-orogenic molasse, evidence of extensional collapse, and Middle to Late Devonian bimodal volcanic rocks and Carboniferous marine carbonate rocks clearly reflect long-lived tectonic extension. Based on these results and the regional geology, we suggest that the Devonian volcano-sedimentary rocks within the NQO were formed in a post-orogenic extensional setting similar to that of the East Kunlun Orogen, indicating that a major tectonic transition from compression to extension in these two orogens probably commenced in the Early Devonian.
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Rankin, Douglas W.
2018-04-20
The bedrock geologic map of the Lisbon quadrangle, and parts of the Sugar Hill and East Haverhill quadrangles, Grafton County, New Hampshire, covers an area of approximately 73 square miles (189 square kilometers) in west-central New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic Suite, and extends from Maine, through western New Hampshire (down the eastern side of the Connecticut River), through southern New England to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (lower and upper sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of slate, phyllite, ironstone, chert, sandstone, and pelite. The Albee Formation underlies the Ammonoosuc Volcanics and is predominantly composed of interbedded metamorphosed sandstone, siltstone, and phyllite.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics including the Moody Ledge pluton and the Scrag granite of Billings (1937). Subsequent plutonism related to the Acadian orogeny occurred after volcanism and deposition resulted in the Littleton Formation during the Late Devonian, including the intrusion of the Haverhill pluton and French Pond Granite found in the southern part of the map.This report consists of a geologic map and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information. The geologic map is intended to serve as a foundation for applying geologic information to problems involving land use decisions, groundwater availability and quality, earth resources such as natural aggregate for construction, assessment of natural hazards, and engineering and environmental studies for waste disposal sites and construction projects.
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Assessment of Undiscovered Gas Resources of the Eastern Oregon and Washington Province, 2006
Brownfield, Michael E.; Tennyson, Marilyn E.; Ahlbrandt, Thomas S.; Charpentier, Ronald R.; Cook, Troy A.; Klett, Timothy R.; Pollastro, Richard M.; Schenk, Christopher J.
2006-01-01
Using a geology-based assessment methodology, the U.S. Geological Survey estimated a mean of 2.4 trillion cubic feet (TCF) of undiscovered natural gas in the Eastern Oregon and Washington Province. More than 90 percent, or 2.1 TCF, of the estimated undiscovered natural gas is continuous gas estimated to be trapped in Tertiary rocks overlain by the Columbia River Basalt Group.
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No geochemical evidence for an asteroidal impact at late Devonian mass extinction horizon
NASA Astrophysics Data System (ADS)
McGhee, G. R., Jr.; Gilmore, J. S.; Orth, C. J.; Olsen, E.
1984-04-01
Three sedimentary sequences in New York State (Dunkirk Beach, Walnut Creek Gorge, and Mills Mills) and one sedimentary sequence in Belgium (Sinsin), that cross the Devonian Frasnian-Famennian boundary, were examined for an iridium (Ir) anomaly to determine whether the biotic extinctions at the end of the Cretaceous could have been caused by an asteroidal impact. The sampling at three of the four areas was on 2-cm center points, and 15 to 20 g of sample were collected. The instrumental neutron activation method required 5 g samples, and consequently the distance between samples was less than 1 cm. Though the Devonian samples studied had a high probability of locating an Ir anomaly, none was found. The highest Ir values were between 0.2 and 2 percent of those reported for the marine and terrestrial Ir analyses at the Cretaceous-Tertiary boundary, and Devonian pyrite-rich sediments did not exhibit high Ir concentrations.
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Exploration limited since '70s in Libya's Sirte basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thomas, D.
1995-03-13
Esso Standard made the first Libyan oil discovery in the western Ghadames basin in 1957. The Atshan-2 well tested oil from Devonian sandstones, and the play was a continuation of the Paleozoic trend found productive in the neighboring Edjeleh region of eastern Algeria. Exploration in the Sirte basin began in earnest in 1958. Within the next 10 years, 16 major oil fields had been discovered, each with recoverable reserves greater than 500 million bbl of oil. Libya currently produces under OPEC quota approximately 1.4 million b/d of oil, with discovered in-place reserves of 130 billion bbl of oil. The papermore » describes the structural framework, sedimentary basins of Libya, the Sirte basin, petroleum geology, play types, source rocks, generation and migration of hydrocarbons, oil reserves, potential, and acreage availability.« less
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Gas hydrate characterization from a 3D seismic dataset in the deepwater eastern Gulf of Mexico
DOE Office of Scientific and Technical Information (OSTI.GOV)
McConnell, Daniel; Haneberg, William C.
Principal component analysis of spectral decomposition results combined with amplitude and frequency seismic attributes derived from 3D seismic data are used for the identification and characterization of gas hydrate deposits in the deepwater eastern Gulf of Mexico. In the central deepwater Gulf of Mexico (GoM), logging while drilling LWD data provided insight to the amplitude response of gas hydrate saturation in sands, which could be used to characterize complex gas hydrate deposits in other sandy deposits. In this study, a large 3D seismic data set from equivalent and distal Plio Pleistocene sandy channel deposits in the deepwater eastern Gulf ofmore » Mexico is screened for direct hydrocarbon indicators for gas hydrate saturated sands.« less
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Total Petroleum Systems of the Carpathian - Balkanian Basin Province of Romania and Bulgaria
Pawlewicz, Mark
2007-01-01
The U.S. Geological Survey defined the Moesian Platform Composite Total Petroleum System and the Dysodile Schist-Tertiary Total Petroleum System, which contain three assessment units, in the Carpathian-Balkanian Basin Province of Romania and Bulgaria. The Moesian Platform Assessment Unit, contained within the Moesian Platform Composite Total Petroleum System, is composed of Mesozoic and Cenozoic rocks within the Moesian platform region of southern Romania and northern Bulgaria and also within the Birlad depression in the northeastern platform area. In Romania, hydrocarbon sources are identified as carbonate rocks and bituminous claystones within the Middle Devonian, Middle Jurassic, Lower Cretaceous, and Neogene stratigraphic sequences. In the Birlad depression, Neogene pelitic strata have the best potential for generating hydrocarbons. In Bulgaria, Middle and Upper Jurassic shales are the most probable hydrocarbon sources. The Romania Flysch Zone Assessment Unit in the Dysodile Schist-Tertiary Total Petroleum System encompasses three structural and paleogeographic subunits within the Pre-Carpathian Mountains region: (1) the Getic depression, a segment of the Carpathian foredeep; (2) the flysch zone of the eastern Carpathian Mountains (also called the Marginal Fold nappe); and (3) the Miocene zone (also called the Sub-Carpathian nappe). Source rocks are interpreted to be Oligocene dysodile schist and black claystone, along with Miocene black claystone and marls. Also part of the Dysodile Schist-Tertiary Total Petroleum System is the Romania Ploiesti Zone Assessment Unit, which includes a zone of diapir folds. This zone lies between the Rimnicu Sarat and Dinibovita valleys and between the folds of the inner Carpathian Mountains and the external flanks of the Carpathian foredeep. The Oligocene Dysodile Schist is considered the main hydrocarbon source rock and Neogene black marls and claystones are likely secondary sources; all are thought to be at their maximum thermal maturation. Undiscovered resources in the Carpathian-Balkanian Basin Province are estimated, at the mean, to be 2,076 billion cubic feet of gas, 1,013 million barrels of oil, and 116 million barrels of natural gas liquids.
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Bimodal Silurian and Lower Devonian volcanic rock assemblages in the Machias-Eastport area, Maine
Gates, Olcott; Moench, R.H.
1981-01-01
Exposed in the Machias-Eastport area of southeastern Maine is the thickest (at least 8,000 m), best exposed, best dated, and most nearly complete succession of Silurian and Lower Devonian volcanic strata in the coastal volcanic belt, remnants of which crop out along the coasts of southern New Brunswick, Canada, and southeastern New England in the United States. The volcanics were erupted through the 600-700-million-year-old Avalonian sialic basement. To test the possibility that this volcanic belt was a magmatic arc above a subduction zone prior to presumed Acadian continental collision, samples representing the entire section in the Machias-Eastport area of Maine were chemically analyzed. Three strongly bimodal assemblages of volcanic rocks and associated intrusives are recognized, herein called the Silurian, older Devonian, and younger Devonian assemblages. The Silurian assemblage contains typically nonporphyritic high-alumina tholeiitic basalts, basaltic andesites, and diabase of continental characterand calc-alkalic rhyolites, silicic dacites, and one known dike of andesite. These rocks are associated with fossiliferous, predominantly marine strata of the Quoddy, Dennys, and Edmunds Formations, and the Leighton Formation of the Pembroke Group (the stratigraphic rank of both is revised herein for the Machias-Eastport area), all of Silurian age. The shallow marine Hersey Formation (stratigraphic rank also revised herein) of the Pembroke Group, of latest Silurian age (and possibly earliest Devonian, as suggested by an ostracode fauna), contains no known volcanics; and it evidently was deposited during a volcanic hiatus that immediately preceded emergence of the coastal volcanic belt and the eruption of the older Devonian assemblage. The older Devonian assemblage, in the lagoonal to subaerial Lower Devonian Eastport Formation, contains tholeiitic basalts and basaltic andesites, typically with abundant plagioclase phenocrysts and typically richer in iron and titanium and poorer in magnesium and nickel than the Silurian basalts; and the Eastport Formation has rhyolites and silicic dacites that have higher average SiO2 and K2O contents and higher ratios of FeO* to MgO than the Silurian ones. The younger Devonian assemblage is represented by one sample of basalt from a flow in red beds of the post-Acadian Upper Devonian Perry Formation, and by three samples from pre-Acadian diabases that intrude the Leighton and Hersey Formations. These rocks are even richer in titanium and iron and poorer in magnesium and nickel than the older Devonian basalts. Post-Acadian granitic plutons exposed along the coastal belt for which analyses are available are tentatively included in the younger Devonian assemblage. The most conspicuous features of the coastal volcanics and associated intrusives are the preponderance of rocks of basaltic composition ( < 52 percent SiO2 ) in the Silurian assemblage, and the near absence in all assemblages of intermediate rocks having 57-67 percent SiO2 (calculated without volatiles). All the rocks are variably altered spilites and keratophyres. The basaltic types are adequately defined, however, by eight samples of least altered basalts having calcic plagioclase, clinopyroxene, and 0.5 percent or less CO2 , The more altered basalts are variably enriched or depleted in Na2O, K2O, and CaO relative to the least altered ones. In the silicic rocks no primary ferromagnesian minerals are preserved. The Na2O and K2O contents of the silicic rocks are erratic; they are approximately reciprocal, possibly owing to alkali exchange while the rocks were still glassy. We propose that the coastal volcanic belt extended along an axis of thermal swelling in the Earth's mantle and upward intrusion of partially melted mantle into the sialic Avalonian crust. These processes were accompanied by shoaling and emergence of the belt, and they produced the bimodal volcanism. Tholeiitic basaltic melts segregated from mantle material
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Bartberger, Charles E.; Dyman, Thaddeus S.; Condon, Steven M.
2003-01-01
The potential of Lower Cretaceous sandstones of the Travis Peak Formation in the northern Gulf Coast Basin to harbor a basin-centered gas accumulation was evaluated by examining (1) the depositional and diagenetic history and reservoir properties of Travis Peak sandstones, (2) the presence and quality of source rocks for generating gas, (3) the burial and thermal history of source rocks and time of gas generation and migration relative to tectonic development of Travis Peak traps, (4) gas and water recoveries from drill-stem and formation tests, (5) the distribution of abnormal pressures based on shut-in-pressure data, and (6) the presence or absence of gas-water contacts associated with gas accumulations in Travis Peak sandstones. The Travis Peak Formation (and correlative Hosston Formation) is a basinward-thickening wedge of terrigenous clastic sedimentary rocks that underlies the northern Gulf Coast Basin from eastern Texas across northern Louisiana to southern Mississippi. Clastic infl ux was focused in two main fl uvial-deltaic depocenters?one located in northeastern Texas and the other in southeastern Mississippi and northeastern Louisiana. Across the main hydrocarbon-productive trend in eastern Texas and northern Louisiana, the Travis Peak Formation is about 2,000 ft thick. Most Travis Peak hydrocarbon production in eastern Texas comes from drilling depths between 6,000 and 10,000 ft. Signifi cant decrease in porosity and permeability occurs through that depth interval. Above 8,000-ft drilling depth in eastern Texas, Travis Peak sandstone matrix permeabilities often are signifi cantly higher than the 0.1-millidarcy (mD) cutoff that characterizes tight-gas reservoirs. Below 8,000 ft, matrix permeability of Travis Peak sandstones is low because of pervasive quartz cementation, but abundant natural fractures impart signifi cant fracture permeability. Although pressure data within the middle and lower Travis Peak Formation are limited in eastern Texas, overpressured reservoirs caused by thermal generation of gas, typical of basin-centered gas accumulations, are not common in the Travis Peak Formation. Signifi cant overpressure was found in only one Travis Peak sandstone reservoir in 1 of 24 oil and gas fi elds examined across eastern Texas and northern Louisiana. The presence of gas-water contacts is perhaps the most defi nitive criterion indicating that a gas accumulation is conventional rather than a ?sweet spot? within a basin-centered gas accumulation. Hydrocarbon-water contacts within Travis Peak sandstone reservoirs were documented in 17 fi elds and probably occur in considerably more fi elds across the productive Travis Peak trend in eastern Texas and northern Louisiana. All known hydrocarbon-water contacts in Travis Peak reservoirs in eastern Texas, however, occur within sandstones in the upper 500 ft of the formation. Although no gas-water contacts have been reported within the lower three-fourths of the Travis Peak Formation in northeastern Texas, gas production from that interval is limited. The best available data suggest that most middle and lower Travis Peak sandstones are water bearing in northeastern Texas. Insuffi cient hydrocarbon charge relative to permeability of Travis Peak reservoirs might be responsible for lack of overpressure and basin-centered gas within the Travis Peak Formation. Shales interbedded with Travis Peak sandstones in eastern Texas are primarily oxidized fl ood-plain deposits with insuffi cient organic-carbon content to be signifi cant sources of oil and gas. The most likely source rocks for hydrocarbons in Travis Peak reservoirs are two stratigraphically lower units, the Jurassic-age Bossier Shale of the Cotton Valley Group, and laminated, lime mudstones of the Jurassic Smackover Formation. Hydrocarbon charge, therefore, might be suffi cient for development of conventional gas accumulations, but it is insuffi cient for
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Sandberg, C.A.; Gutschick, R.C.; Johnson, J.G.; Poole, F.G.; Sando, W.J.
1986-01-01
Twenty eustatic and epeirogenic events mainly dated by conodonts are distinguished between the Middle Devonian and the lower Upper Mississippian in Great Basin, in Rocky Mountains and in the Overthrust belt regions.-Journal Editors
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Geometry of an outcrop-scale duplex in Devonian flysch, Maine
Bradley, D.C.; Bradley, L.M.
1994-01-01
We describe an outcrop-scale duplex consisting of 211 exposed repetitions of a single bed. The duplex marks an early Acadian (Middle Devonian) oblique thrust zone in the Lower Devonian flysch of northern Maine. Detailed mapping at a scale of 1:8 has enabled us to measure accurately parameters such as horse length and thickness, ramp angles and displacements; we compare these and derivative values with those of published descriptions of duplexes, and with theoretical models. Shortening estimates based on line balancing are consistently smaller than two methods of area balancing, suggesting that layer-parallel shortening preceded thrusting. ?? 1994.
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Ettensohn, F.R.; Pashin, J.C.
1997-01-01
The Devonian-Carboniferous transition on Laurussia was a time of diverse geologic activity associated with the assembly of Pangea, including episodes of Late Devonian glacial-eustatic lowstand and active orogeny on four margins. Six widespread unconformities are present in the Devonian-Carboniferous (Mississippian) interval on southern parts of Laurussia. We suggest that attention to the timing and plan of the unconformities may provide ways of discerning tectonic and climatic controls on their respective origins. Indeed, unconformities generated by pure eustasy are ideally of interregional extent, whereas unconformities generated by tectonism reflect more local factors associated with the evolution of sedimentary basins. Each of the six unconformities analyzed provides evidence for concurrent eustasy and tectonism. Glaciation was apparently the dominant factor driving the development of unconformities during the latest Devonian. During the Early Carboniferous, however, the volume of glacial ice available to drive eustasy was limited and, at times, tectonism may have been the source of a subordinate eustatic signal. Development of unconformities in southern Laurussia appear to be local manifestations of tectonic and climatic processes associated with supercontinent assembly. Thus, the time may be at hand for construction of a new global stratigraphic paradigm that is based on the plate tectonic supercycle affecting continentality and climate.
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Air-breathing adaptation in a marine Devonian lungfish.
Clement, Alice M; Long, John A
2010-08-23
Recent discoveries of tetrapod trackways in 395 Myr old tidal zone deposits of Poland (Niedźwiedzki et al. 2010 Nature 463, 43-48 (doi:10.1038/nature.08623)) indicate that vertebrates had already ventured out of the water and might already have developed some air-breathing capacity by the Middle Devonian. Air-breathing in lungfishes is not considered to be a shared specialization with tetrapods, but evolved independently. Air-breathing in lungfishes has been postulated as starting in Middle Devonian times (ca 385 Ma) in freshwater habitats, based on a set of skeletal characters involved in air-breathing in extant lungfishes. New discoveries described herein of the lungfish Rhinodipterus from marine limestones of Australia identifies the node in dipnoan phylogeny where air-breathing begins, and confirms that lungfishes living in marine habitats had also developed specializations to breathe air by the start of the Late Devonian (ca 375 Ma). While invasion of freshwater habitats from the marine realm was previously suggested to be the prime cause of aerial respiration developing in lungfishes, we believe that global decline in oxygen levels during the Middle Devonian combined with higher metabolic costs is a more likely driver of air-breathing ability, which developed in both marine and freshwater lungfishes and tetrapodomorph fishes such as Gogonasus.
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Air-breathing adaptation in a marine Devonian lungfish
Clement, Alice M.; Long, John A.
2010-01-01
Recent discoveries of tetrapod trackways in 395 Myr old tidal zone deposits of Poland (Niedźwiedzki et al. 2010 Nature 463, 43–48 (doi:10.1038/nature.08623)) indicate that vertebrates had already ventured out of the water and might already have developed some air-breathing capacity by the Middle Devonian. Air-breathing in lungfishes is not considered to be a shared specialization with tetrapods, but evolved independently. Air-breathing in lungfishes has been postulated as starting in Middle Devonian times (ca 385 Ma) in freshwater habitats, based on a set of skeletal characters involved in air-breathing in extant lungfishes. New discoveries described herein of the lungfish Rhinodipterus from marine limestones of Australia identifies the node in dipnoan phylogeny where air-breathing begins, and confirms that lungfishes living in marine habitats had also developed specializations to breathe air by the start of the Late Devonian (ca 375 Ma). While invasion of freshwater habitats from the marine realm was previously suggested to be the prime cause of aerial respiration developing in lungfishes, we believe that global decline in oxygen levels during the Middle Devonian combined with higher metabolic costs is a more likely driver of air-breathing ability, which developed in both marine and freshwater lungfishes and tetrapodomorph fishes such as Gogonasus. PMID:20147310
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NASA Astrophysics Data System (ADS)
Jost, B.; Webb, M.; White, L. T.
2017-12-01
In northwest New Guinea, Palaeozoic basement rocks forming part of the northern margin of the Australian continent are exposed in a rugged mountain range. This remote and understudied region provides a unique window into the complex Palaeozoic evolution and tectonic history of this region, which we help unravel with new field, petrographic, geochemical, and geochronological data. The basement rocks consist of extensive meta-turbidites that were subject to low pressure-high temperature metamorphism along their eastern margin. They are cross-cut by predominantly acidic granitoids. U-Pb zircon dating reveals that these granitoids intruded in three episodes in the Devonian-Carboniferous, the Carboniferous, and the Triassic. The first episode has not previously been reported in the region. The granitoids are strongly peraluminous, suggesting that partial melting of the meta-sedimentary country rock contributed to their petrogenesis (S-type). The occurrence and character of country rock xenoliths and migmatites supports this interpretation. Equilibrium thermodynamic modelling of the metapelites and the migmatites indicates that a substantial amount of heat was added to the lower and middle crust to cause partial melting and regional metamorphism at relatively low pressure. We propose repeated intrusion of hot magma as the mechanism responsible for advecting the necessary heat from the mantle. This likely occurred in an active continental margin setting during the Devonian-Carboniferous and the Triassic, possibly separated by an interval of magmatic quiescence during most of the Permian. New biostratigraphic and low-temperature thermochronological data reveal very recent Pliocene-Pleistocene uplift and unroofing of these basement rocks.
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Dusel-Bacon, C.; Williams, I.S.
2009-01-01
Sensitive high-resolution ion microprobe (SHRIMP) U-Pb analyses of igneous zircons from the Lake George assemblage in the eastern Yukon-Tanana Upland (Tanacross quadrangle) indicate both Late Devonian (???370 Ma) and Early Mississippian (???350 Ma) magmatic pulses. The zircons occur in four textural variants of granitic orthogneiss from a large area of muscovite-biotite augen gneiss. Granitic orthogneiss from the nearby Fiftymile batholith, which straddles the Alaska-Yukon border, yielded a similar range in zircon U-Pb ages, suggesting that both the Fiftymile batholith and the Tanacross orthogneiss body consist of multiple intrusions. We interpret the overall tectonic setting for the Late Devonian and Early Mississippian magmatism as an extending continental margin (broad back-arc region) inboard of a northeast-dipping (present coordinates) subduction zone. New SHRIMP U-Pb ages of inherited zircon cores in the Tanacross orthogneisses and of detrital zircons from quartzite from the Jarvis belt in the Alaska Range (Mount Hayes quadrangle) include major 2.0-1.7 Ga clusters and lesser 2.7-2.3 Ga clusters, with subordinate 3.2, 1.4, and 1.1 Ga clusters in some orthogneiss samples. For the most part, these inherited and core U-Pb ages match those of basement provinces of the western Canadian Shield and indicate widespread potential sources within western Laurentia for most grain populations; these ages also match the detrital zircon reference for the northern North American miogeocline and support a correlation between the two areas.
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78 FR 43874 - Texas Eastern Transmission, LP; Notice of Application
Federal Register 2010, 2011, 2012, 2013, 2014
2013-07-22
... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. CP13-514-000] Texas Eastern Transmission, LP; Notice of Application On July 2, 2013, Texas Eastern Transmission, LP (Texas Eastern) filed... natural gas facilities no longer in service. As described more fully in the Application, Texas Eastern...
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Heilweil, Victor M; Grieve, Paul L; Hynek, Scott A; Brantley, Susan L; Solomon, D Kip; Risser, Dennis W
2015-04-07
The environmental impacts of shale-gas development on water resources, including methane migration to shallow groundwater, have been difficult to assess. Monitoring around gas wells is generally limited to domestic water-supply wells, which often are not situated along predominant groundwater flow paths. A new concept is tested here: combining stream hydrocarbon and noble-gas measurements with reach mass-balance modeling to estimate thermogenic methane concentrations and fluxes in groundwater discharging to streams and to constrain methane sources. In the Marcellus Formation shale-gas play of northern Pennsylvania (U.S.A.), we sampled methane in 15 streams as a reconnaissance tool to locate methane-laden groundwater discharge: concentrations up to 69 μg L(-1) were observed, with four streams ≥ 5 μg L(-1). Geochemical analyses of water from one stream with high methane (Sugar Run, Lycoming County) were consistent with Middle Devonian gases. After sampling was completed, we learned of a state regulator investigation of stray-gas migration from a nearby Marcellus Formation gas well. Modeling indicates a groundwater thermogenic methane flux of about 0.5 kg d(-1) discharging into Sugar Run, possibly from this fugitive gas source. Since flow paths often coalesce into gaining streams, stream methane monitoring provides the first watershed-scale method to assess groundwater contamination from shale-gas development.
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NASA Astrophysics Data System (ADS)
Sedorko, Daniel; Netto, Renata G.; Savrda, Charles E.
2018-04-01
Previous studies of the Paraná Supersequence (Furnas and Ponta Grossa formations) of the Paraná Basin in southern Brazil have yielded disparate sequence stratigraphic interpretations. An integrated sedimentological, paleontological, and ichnological model was created to establish a refined sequence stratigraphic framework for this succession, focusing on the Ponta Grossa Formation. Twenty-nine ichnotaxa are recognized in the Ponta Grossa Formation, recurring assemblages of which define five trace fossil suites that represent various expressions of the Skolithos, Glossifungites and Cruziana ichnofacies. Physical sedimentologic characteristics and associated softground ichnofacies provide the basis for recognizing seven facies that reflect a passive relationship to bathymetric gradients from shallow marine (shoreface) to offshore deposition. The vertical distribution of facies provides the basis for dividing the Ponta Grossa Formation into three major (3rd-order) depositional sequences- Siluro-Devonian and Devonian I and II-each containing a record of three to seven higher-order relative sea-level cycles. Major sequence boundaries, commonly coinciding with hiatuses recognized from previously published biostratigraphic data, are locally marked by firmground Glossifungites Ichnofacies associated with submarine erosion. Maximum transgressive horizons are prominently marked by unbioturbated or weakly bioturbated black shales. By integrating observations of the Ponta Grossa Formation with those recently made on the underlying marginal- to shallow-marine Furnas Formation, the entire Paraná Supersequence can be divided into four disconformity-bound sequences: a Lower Silurian (Llandovery-Wenlock) sequence, corresponding to lower and middle units of the Furnas; a Siluro-Devonian sequence (?Pridoli-Early Emsian), and Devonian sequences I (Late Emsian-Late Eifelian) and II (Late Eifelian-Early Givetian). Stratigraphic positions of sequence boundaries generally coincide with regressive phases on established global sea-level curves for the Silurian-Devonian.
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Barnett, S.F.; Ettensohn, F.R.; Norby, R.D.
1996-01-01
Black shales previously interpreted to be Late Devonian cave-fill or slide deposits are shown to be much older Middle Devonian black shales only preserved locally in Middle Devonian grabens and structural lows in central Kentucky. This newly recognized - and older -black-shale unit occurs at the base of the New Albany Shale and is named the Carpenter Fork Bed of the Portwood Member of the New Albany Shale after its only known exposure on Carpenter Fork in Boyle County, central Kentucky; two other occurrences are known from core holes in east-central Kentucky. Based on stratigraphic position and conodont biostratigraphy, the unit is Middle Devonian (Givetian: probably Middle to Upper P. varcus Zone) in age and occurs at a position represented by an unconformity atop the Middle Devonian Boyle Dolostone and its equivalents elsewhere on the outcrop belt. Based on its presence as isolated clasts in the overlying Duffin Bed of the Portwood Member, the former distribution of the unit was probably much more widespread - perhaps occurring throughout western parts of the Rome trough. Carpenter Fork black shales apparently represent an episode of subsidence or sea-level rise coincident with inception of the third tectophase of the Acadian orogeny. Deposition, however, was soon interrupted by reactivation of several fault zones in central Kentucky, perhaps in response to bulge migration accompanying start of the tectophase. As a result, much of central Kentucky was uplifted and tilted, and the Carpenter Fork Bed was largely eroded from the top of the Boyle, except in a few structural lows like the Carpenter Fork graben where a nearly complete record of Middle to early Late Devonian deposition is preserved.
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Petroleum system modeling of the western Canada sedimentary basin - isopach grid files
Higley, Debra K.; Henry, Mitchell E.; Roberts, Laura N.R.
2005-01-01
This publication contains zmap-format grid files of isopach intervals that represent strata associated with Devonian to Holocene petroleum systems of the Western Canada Sedimentary Basin (WCSB) of Alberta, British Columbia, and Saskatchewan, Canada. Also included is one grid file that represents elevations relative to sea level of the top of the Lower Cretaceous Mannville Group. Vertical and lateral scales are in meters. The age range represented by the stratigraphic intervals comprising the grid files is 373 million years ago (Ma) to present day. File names, age ranges, formation intervals, and primary petroleum system elements are listed in table 1. Metadata associated with this publication includes information on the study area and the zmap-format files. The digital files listed in table 1 were compiled as part of the Petroleum Processes Research Project being conducted by the Central Energy Resources Team of the U.S. Geological Survey, which focuses on modeling petroleum generation, 3 migration, and accumulation through time for petroleum systems of the WCSB. Primary purposes of the WCSB study are to Construct the 1-D/2-D/3-D petroleum system models of the WCSB. Actual boundaries of the study area are documented within the metadata; excluded are northern Alberta and eastern Saskatchewan, but fringing areas of the United States are included.Publish results of the research and the grid files generated for use in the 3-D model of the WCSB.Evaluate the use of petroleum system modeling in assessing undiscovered oil and gas resources for geologic provinces across the World.
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Causes of the great mass extinction of marine organisms in the Late Devonian
NASA Astrophysics Data System (ADS)
Barash, M. S.
2016-11-01
The second of the five great mass extinctions of the Phanerozoic occurred in the Late Devonian. The number of species decreased by 70-82%. Major crises occurred at the Frasnian-Famennian and Devonian-Carboniferous boundary. The lithological and geochemical compositions of sediments, volcanic deposits, impactites, carbon and oxygen isotope ratios, evidence of climate variability, and sea level changes reflect the processes that led the critical conditions. Critical intervals are marked by layers of black shales, which were deposited in euxinic or anoxic environments. These conditions were the main direct causes of the extinctions. The Late Devonian mass extinction was determined by a combination of impact events and extensive volcanism. They produced similar effects: emissions of harmful chemical compounds and aerosols to cause greenhouse warming; darkening of the atmosphere, which prevented photosynthesis; and stagnation of oceans and development of anoxia. Food chains collapsed and biological productivity decreased. As a result, all vital processes were disturbed and a large portion of the biota became extinct.
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Late Devonian Anoxia Events in the Central Asian Orogenic Belt: a Global Phenomenon
NASA Astrophysics Data System (ADS)
Carmichael, S. K.; Waters, J. A.; Suttner, T. J.; Kido, E.; DeReuil, A. A.; Moore, L. M.; Batchelor, C. J.
2013-12-01
Atmospheric CO2 values decreased dramatically during the Middle Devonian due to the rapid rise of land plants. These changing environmental conditions resulted in widespread anoxia and extinction events throughout the Late Devonian, including the critical Kellwasser and Hangenberg anoxia events, which are associated with major mass extinctions at both the beginning and end of the Famennian Stage of the Late Devonian. Fammenian sediments in northwestern Xinjiang Province, China, represent a highly fossiliferous shallow marine setting associated with a Devonian oceanic island arc complex. Analysis of multiple geochemical proxies (such as U/Th, Ba, normalized P2O5, V/Cr, Zr), magnetic susceptibility, and mineralogical data (biogenic apatite and pyrite framboids) indicates that these Famennian sequences record not only the Upper Kellwasser Anoxic Event at the Frasnian/Famennian (F/F) boundary but also the rebound from the F/F extinction event. Preliminary evidence suggests that the Hangenberg Anoxic Event can also be recognized in the same sequence, although our biostratigraphic control is less precise. Previous studies of the Kellwasser and Hangenberg Events have been performed on continental shelf environments of Laurussia, Gondwana, Siberia, and South China. The Devonian formations of northwest Xinjiang in this study, however, are part of the Central Asian Orogenic Belt (CAOB), which is thought to have formed as part of a complex amalgamation of intra-oceanic island arcs and continental fragments prior to the end of the latest Carboniferous. These results allow us to confirm the presence of the Kellwasser and Hangenberg Events in the open oceanic part of Paleotethys, indicating that both events were global in scope. The presence of an abundant diverse Famennian fauna between these anoxia/extinction events suggests that the shallow marine ecosystems in the CAOB were somewhat protected due to their tectonic location and relative isolation within an open ocean system. Our new data puts the Late Devonian anoxic events recognized in the CAOB into a global rather than regional context, and helps constrain the nature of ocean anoxia during this period by analysis of locations outside subequatorial North America and Europe.
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The geology of Burnsville Cove, Bath and Highland Counties, Virginia
Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.
2015-01-01
Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.
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NASA Astrophysics Data System (ADS)
Peralta Arnold, Yesica; Cabassi, Jacopo; Tassi, Franco; Caffe, Pablo; Vaselli, Orlando
2016-04-01
The western sector of the Jujuy province (22°-24° S), Argentina, basically consisting of the Puna region (from 3,500 to 4,700 m a.s.l.) that borders the Central Volcanic Zone (CVZ), is characterized by sub-meridional ridges that alternate with elongated basins and by extremely voluminous intermediate and silicic ignimbrite deposits, the latter being related to late miocenic and pliocenic calderas and central volcanic edifices. In this region, several hydrothermal discharges with outlet temperatures up to 62°C occur. Among them, the Coranzulí and Pairique thermal emissions show a spatial relationship with miocenic volcanic complexes, whereas other thermal manifestations (Queñual, Orosmayo, Pirquitas, Arizutar, Cono Panizo and Rachaite) are clearly controlled by the local structural setting. Most of these thermal waters have relatively high total dissolved solids (TDS up to 46,500 mg/L), an alkaline-chloride composition and significant concentrations of B, NH4 and SiO2, i.e. they show the typical geochemical features of geothermal brine. Exceptions are the Coranzulí, Orosmayo and Rachaite springs, mainly fed by a shallow Na(Ca)-bicarbonate aquifer. The eastern sector of the province consists of the Eastern Cordillera, composed of a proterozoic basement constituted by the sedimentary sequences of the Puncoviscana Fm, and the Subandean Range, which shows wide east-vergence anticlines whose detachment levels are Silurian-Devonian shales. Both regions are separated by a major thrust that rises the Proterozoic and Eopaleozoic sequences over the Subandean System. The thermal waters in the Eastern Cordillera, namely Termas de Reyes, are characterized by alkaline-sulfate composition, temperature of ≈50°C and neutral pH. In contrast, in the Subandean Ranges, which is separated from the Eastern Cordillera by a thrust rising Proterozoic and Eopaleozoic sequences over the Subandean System, the Aguas Calientes springs are characterized by low temperature (from 21°C to 33°C) and a Ca-bicarbonate composition, with no significant evidences of deep fluid contribution. In spite of the clear differences in water chemistry of the thermal waters from the two domains of the studied area, the chemical composition of the associated gas phases are invariably dominated by CO2, with minor abundances of organic and atmospheric gases. The carbon isotopic signature of CO2 is consistent with that typically found in hydrothermal fluids, i.e. with significant contribution from a crustal source. Nevertheless, the R/Ra values indicate a significant fraction of mantle He (up to 17%). and the CO2/3He ratios are 2.9×1012, up to three orders of magnitude higher than the MORB value.
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NASA Astrophysics Data System (ADS)
Spradlin, J.; Fiorentino, A. J., II; Siegel, D. I.
2014-12-01
We report the results of an evaluation of the trace and major metal composition of shallow sedimentary rock formations in the Appalachian Basin that control the quality of potable water produced in domestic and other wells. In particular, we quantify the mobile and total metals for which there are health concerns related to unconventional gas exploitation; Fe, Mn, Sr, Ba, As, and Pb. To do this, we sampled the upper 400 feet of Devonian to Pennsylvanian aged bedrock from Marcellus, NY to State College, PA. We used a variation of the U.S. Geological Survey Field Leach Test to assess water reactivity and leaching potential. Al, Zn, and U potentially can be leached from aquifer rocks naturally under acidic conditions, such as where pyrite might oxidize, to above current allowable regulatory values for these metals (2 mg/L, 5 mg/L, and 0.03 mg/L respectively) from some of the clay-rich formations. Groundwater analyses from both New York and Pennsylvania show that natural ion exchange occurs along flow paths from ridges to valleys. We find the laboratory cation exchange capacity (CEC) spans what might be expected for illite and chlorite commonly found in these rocks. Given the low surface area of the mineral surfaces of the fractures through which most of the water moves, the observed ion exchange in these rocks is not well understood. Along with this broad scale study area we investigated a Devonian outcrop 4 miles North of Cortland, NY to evaluate small-scale trace metal heterogeneity within a single stratigraphic section. Together these two studies provide important information to determine the extent to which ground water might be naturally high in trace metal composition, either because of geochemical conditions or entrainment of suspended material not removed prior to sampling.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.
2013-04-01
Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotopemore » mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.« less
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,
2007-01-01
Introduction The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geologically based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States. The U.S. Geological Survey (USGS) recently completed an assessment of the undiscovered oil and gas potential of the Eastern Great Basin Province of eastern Nevada, western Utah, southeastern Idaho, and northwestern Arizona. This assessment is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (sequence stratigraphy and petrophysical properties), and hydrocarbon traps (trap formation and timing). The USGS used this geologic framework to define one total petroleum system and three assessment units. All three assessment units were quantitatively assessed for undiscovered oil and gas resources.
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Silurian and Devonian in Vietnam—Stratigraphy and facies
NASA Astrophysics Data System (ADS)
Thanh, Tống Duy; Phương, Tạ Hoàng; Janvier, Philippe; Hùng, Nguyễn Hữu; Cúc, Nguyễn Thị Thu; Dương, Nguyễn Thùy
2013-09-01
Silurian and Devonian deposits in Viet Nam are present in several zones and regions, including Quang Ninh, East Bac Bo, and West Bac Bo Zones of the Bac Bo Region, the Dien Bien-Nghe An and Binh Tri Thien Zones of the Viet-Lao Region, and the South Trung Bo, and Western Nam Bo Zones of the South Viet Nam Region (Fig. 1). The main lithological features and faunal composition of the Silurian and Devonian Units in all these zones are briefly described. The Silurian consists of deep-water deposits of the upper parts of the Co To and Tan Mai Formations in the Quang Ninh Zone, the upper parts of the Phu Ngu Formation in the East Bac Bo Zone and the upper parts of the Long Dai and Song Ca Formations in the Viet-Lao Region. Shallow water facies Silurian units containing benthic faunas are more widely distributed, including the upper part of the Sinh Vinh and Bo Hieng Formations in the West Bac Bo Zone, the Kien An Formation in the Quang Ninh Zone, and, in the Viet-Lao Region, the Dai Giang Formation and the upper part of the Tay Trang Formation. No Lower and Middle Devonian deposits indicate deep water facies, but they are characterized by different shallow water facies. Continental to near shore, deltaic facies characterize the Lower Devonian Song Cau Group in the East Bac Bo Zone, the Van Canh Formation in the Quang Ninh Zone, and the A Choc Formation in the Binh Tri Thien Zone. Similar facies also occur in the Givetian Do Son Formation of the Quang Ninh Zone, and the Tan Lap Formation in the East Bac Bo Zone, and consist of coarse terrigenous deposits—cross-bedded conglomerates, sandstone, etc. Most Devonian units are characterized by shallow marine shelf facies. Carbonate and terrigenous-carbonate facies dominate, and terrigenous facies occur in the Lower and Middle Devonian sections in some areas only. The deep-water-like facies is characteriztic for some Upper Devonian formations in the Bac Bo (Bang Ca and Toc Tat Formations) and Viet-Lao Regions (Thien Nhan and Xom Nha Formations). These formations contain cherty shale or siliceous limestone, and fossils consist of conodonts, but there are also brachiopods and other benthos. They were possibly deposited in a deep water environment on the slope of the continental shelf. Most Devonian units distributed in the North and the Central Viet Nam consist of self shallow water sediments, and apparently they were deposited in a passive marginal marine environment. The coarse clastic continental or subcontinental deposits are distributed only in some areas of the East Bac Bo and of the Quang Ninh zones of the Bac Bo Region, and in the south of the Binh Tri Thien Zone. This situation suggests the influence of the Caledonian movement at the end of the Silurian period that called the Guangxi movement in South China.
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18 CFR 270.306 - Devonian shale wells in Michigan.
Code of Federal Regulations, 2010 CFR
2010-04-01
... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Devonian shale wells in Michigan. 270.306 Section 270.306 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY...) Attesting the applicant has no knowledge of any information not described in the application which is...
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Pollastro, Richard M.; Potter, Christopher J.; Schenk, Christopher J.; Charpentier, Ronald R.; Cook, Troy A.; Klett, Timothy R.; Kirschbaum, Mark A.
2012-01-01
The U.S. Geological Survey estimated a mean of 448 billion cubic feet of potential technically recoverable unconventional natural gas in Carboniferous and Permian coal-bearing strata in the eastern uplift of the Liaohe Basin, Liaoning Province, China.
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NASA Astrophysics Data System (ADS)
Templeton, J.; Anders, M.; Fossen, H.
2014-12-01
The Hornelen basin is the largest of the Devonian 'Old Red' sandstone basins in Norway, comprising 25 km of alluvial-fluvial deposits which are organized into basin-wide, coarsening-upward megacycles. Hornelen sits with several smaller basins in the hanging wall a major extensional shear zone along which the ultra-high pressure metamorphic core of subducted Baltican crust was rapidly exhumed during the extensional collapse of the Caledonian orogeny. The timing of orogenic collapse corresponds closely to the timing of the basins, which are loosely constrained by sparse trace-fossil assemblages to a mid-Devonian age. Further, the basins are now in brittle fault contact with the underlying mylonitic shear zone and the metamorphic core, implying that they are the upper-crustal expression of large-scale extension and deep-crustal exhumation. Two distinct structural models have been proposed for Hornelen to account for these observations. The strike-slip model juxtaposes different source terranes across the basin-controlling fault and predicts spatially changing provenance within chronostratigraphic units. The supradetachment model links the filling of the basin directly to unroofing of the metamorphic core on a low-angle detachment fault, and predicts basin-wide changes in provenance through time with progressive exhumation of the metamorphic hinterland. We present an extensive new provenance dataset, spanning the Hornelen basin strata through space and time. Detrital zircon U/Pb ages from 18 new samples comprise three distinct populations (1.6, 1.0, and 0.43 Ga) with the Caledonian-aged zircons (ca 0.43 Ga) present mainly along the northern margin of the basin, representing an Upper Allochthon source not found on the southern or eastern margins of the basin. Juxtaposition of different source terranes across the basin supports the strike-slip model. 40Ar/39Ar detrital white mica from the same sample set documents a younging of the dominant age peak from 432 Ma in the oldest sediments to 401 Ma in the youngest units, but does not document any difference between northern and southern mica sources. This trend supports the supradetachment model, but may also be explained by passive, isostatically-driven erosional unroofing of the overthickened orogenic crust.
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Detrital zircon age patterns and provenance of the metamorphic complexes of southern Chile
NASA Astrophysics Data System (ADS)
Hervé, F.; Fanning, C. M.; Pankhurst, R. J.
2003-05-01
Zircon SHRIMP U-Pb age patterns are reported for 13 metasedimentary rocks from the low grade metamorphic complexes of the Patagonian Andes. Combined with four recently published patterns, these provide the first detailed survey of the provenance of these complexes. The youngest dated zircons, corresponding to maximum sedimentation ages, are Devonian-Late Triassic in the eastern Andes metamorphic complex, Carboniferous in the main range metamorphic complex, Permian in the Duque de York complex, and Late Triassic in the Chonos metamorphic complex. In the last two cases, these ages are in agreement with their respective fossil ages. Older components in the eastern Andes metamorphic complex include a large proportion of Proterozoic (predominantly 1000-1200 Ma) zircons, which may indicate distribution, probably by rivers, of detrital material from regions currently in northern South America, Africa, or east Antarctica. The abundance of Proterozoic zircons is very much less in the Duque de York complex, possibly because of the rise of an inferred Permian magmatic arc related to the Gondwanan orogeny and consequent westward migration of the watershed. A Late Triassic magmatic episode is registered in the Chonos metamorphic complex, where reappearance of significant Proterozoic zircons indicates exhumation of the cratonic areas or of recycled sedimentary material.
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Rankin, Douglas W.
2018-06-13
The bedrock geologic map of the Littleton and Lower Waterford quadrangles covers an area of approximately 107 square miles (277 square kilometers) north and south of the Connecticut River in east-central Vermont and adjacent New Hampshire. This map was created as part of a larger effort to produce a new bedrock geologic map of Vermont through the collection of field data at a scale of 1:24,000. A large part of the map area consists of the Bronson Hill anticlinorium, a post-Early Devonian structure that is cored by metamorphosed Cambrian to Devonian sedimentary, volcanic, and plutonic rocks. The northwestern part of the map is divided by the Monroe fault which separates Early Devonian rocks of the Connecticut Valley-Gaspé trough from rocks of the Bronson Hill anticlinorium.The Bronson Hill anticlinorium is the apex of the Middle Ordovician to earliest-Silurian Bronson Hill magmatic arc that contains the Ammonoosuc Volcanics, Partridge Formation, and Oliverian Plutonic suite, and extends from Maine, down the eastern side of the Connecticut River in New Hampshire, to Long Island Sound. The deformed and partially eroded arc is locally overlain by a relatively thin Silurian section of metasedimentary rocks (Clough Quartzite and Fitch Formation) that thickens to the east. The Silurian section near Littleton is disconformably overlain by a thicker, Lower Devonian section that includes mostly metasedimentary rocks and minor metavolcanic rocks of the Littleton Formation. The Bronson Hill anticlinorium is bisected by a series of northeast-southwest trending Mesozoic normal faults. Primarily among them is the steeply northwest-dipping Ammonoosuc fault that divides older and younger units (upper and lower sections) of the Ammonoosuc Volcanics. The Ammonoosuc Volcanics are lithologically complex and predominantly include interlayered and interfingered rhyolitic to basaltic volcanic and volcaniclastic rocks, as well as lesser amounts of metamorphic and metasedimentary rocks. The Ammonoosuc Volcanics overlies the Albee Formation that consists of interlayered feldspathic sandstone, siltstone, pelite, and slate.During the Late Ordovician, a series of arc-related plutons intruded the Ammonoosuc Volcanics, including the Whitefield pluton to the east, the Scrag granite of Billing (1937) in the far southeastern corner of the map, the Highlandcroft Granodiorite just to the west of the Ammonoosuc fault, and the Joslin Turn tonalite (just north of the Connecticut River). To the east of the Monroe fault lies the late Silurian Comerford Intrusive Complex, which consists of metamorphosed gabbro, diorite, tonalite, aplitic tonalite, and crosscutting diabase dikes. Abundant mafic dikes of the Comerford Intrusive Complex intruded the Albee Formation and Ammonoosuc Volcanics well east of the Monroe fault.This report consists of a single geologic map sheet and an online geographic information systems database that includes contacts of bedrock geologic units, faults, outcrops, and structural geologic information.
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NASA Astrophysics Data System (ADS)
Smith, K.; Cameron, T. D. J.
2009-04-01
Controls of late Palaeozoic and Mesozoic extension in the British Isles: evidence from seismic reflection data in the Central North Sea. Kevin Smith (1) and Don Cameron (2) (1) British Geological Survey, Murchison House, West Mains Road, Edinburgh, EH9 3LA. (ksm@bgs.ac.uk). (2) British Geological Survey, 376 Gilmerton Road, Edinburgh, EH17 7QS. In the area of the British Isles during the late Devonian and early Carboniferous, the oblique convergence of Laurentia and Gondwana imposed a torque on the adjoining terranes of Baltica and Avalonia. Their resulting clockwise rotation was accommodated by widely distributed N-S extension in the intervening zones previously formed by Caledonian and Acadian convergence. South of Laurentia and Baltica, late Palaeozoic extension was focused (1) at terrane margins, (2) in areas of limited Caledonian-Acadian plutonism, and (3) in places where the western (Iapetus) and eastern (Tornquist) convergence zones intersect at a high angle. One of these latter areas lies in Central England immediately north of the Midland Microcraton (part of Eastern Avalonia), where thermal subsidence associated with early Carboniferous extension gave rise to the late Carboniferous Pennine Basin. Interpretation of an extensive set of 3D and 2D long-offset seismic reflection data suggests that a similar area of enhanced extension at a fold belt intersection lies to north of the Mid North Sea High in the middle of the Central North Sea. Variscan uplift and inversion of the late Palaeozoic basins began to predominate in mid-Carboniferous times as final amalgamation of all the different terranes to form Pangaea curtailed the initial episode of extension and thermal subsidence. This change in the tectonic regime was associated with the onset of tholeiitic volcanism within the convergence zones, and was followed by localised extension during the earliest Permian. Evidence obtained from seismic interpretation of the deep structure of the UK sector of the Central North Sea, suggests that late Carboniferous uplift and inversion along a northerly-trending axis analogous to the Pennine anticline controlled rift orientation during the episode of late Jurassic and early Cretaceous extension that formed the Central Graben. Other evidence indicates that subsequent local inversion of the Mesozoic basins in the same area can be spatially linked to the previous framework of late Devonian and early Carboniferous extension. In Scotland, north of the Southern Uplands, the pattern of late Palaeozoic extension in the Midland Valley is similar to that in England and the Central North Sea. Minor differences can be attributed to the greater effect of Laurentian tectonics in Scotland, including the development of Lower Devonian basins and volcanic rocks, and the influence of strike-slip faults of the NNE-trending Great Glen set, which originated between Laurentia and Baltica, largely to the north of the terranes of southern, Gondwanan, affinity. Published regional interpretations of variation in depth to the Moho in the UK can be used to examine the relative contribution of crustal stretching and magmatic underplating across the area.
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Schenk, Christopher J.; Brownfield, Michael E.; Charpentier, Ronald R.; Cook, Troy A.; Klett, Timothy R.; Pitman, Janet K.; Pollastro, Richard M.
2012-01-01
Using a geology-based assessment methodology, the U.S. Geological Survey estimated means of 5.8 billion barrels of oil and 115 trillion cubic feet of undiscovered natural gas in five geologic provinces in the areas of Papua New Guinea, eastern Indonesia, and East Timor.
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Euryhaline ecology of early tetrapods revealed by stable isotopes.
Goedert, Jean; Lécuyer, Christophe; Amiot, Romain; Arnaud-Godet, Florent; Wang, Xu; Cui, Linlin; Cuny, Gilles; Douay, Guillaume; Fourel, François; Panczer, Gérard; Simon, Laurent; Steyer, J-Sébastien; Zhu, Min
2018-06-01
The fish-to-tetrapod transition-followed later by terrestrialization-represented a major step in vertebrate evolution that gave rise to a successful clade that today contains more than 30,000 tetrapod species. The early tetrapod Ichthyostega was discovered in 1929 in the Devonian Old Red Sandstone sediments of East Greenland (dated to approximately 365 million years ago). Since then, our understanding of the fish-to-tetrapod transition has increased considerably, owing to the discovery of additional Devonian taxa that represent early tetrapods or groups evolutionarily close to them. However, the aquatic environment of early tetrapods and the vertebrate fauna associated with them has remained elusive and highly debated. Here we use a multi-stable isotope approach (δ 13 C, δ 18 O and δ 34 S) to show that some Devonian vertebrates, including early tetrapods, were euryhaline and inhabited transitional aquatic environments subject to high-magnitude, rapid changes in salinity, such as estuaries or deltas. Euryhalinity may have predisposed the early tetrapod clade to be able to survive Late Devonian biotic crises and then successfully colonize terrestrial environments.
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NASA Astrophysics Data System (ADS)
Darrah, Thomas H.; Jackson, Robert B.; Vengosh, Avner; Warner, Nathaniel R.; Whyte, Colin J.; Walsh, Talor B.; Kondash, Andrew J.; Poreda, Robert J.
2015-12-01
The last decade has seen a dramatic increase in domestic energy production from unconventional reservoirs. This energy boom has generated marked economic benefits, but simultaneously evoked significant concerns regarding the potential for drinking-water contamination in shallow aquifers. Presently, efforts to evaluate the environmental impacts of shale gas development in the northern Appalachian Basin (NAB), located in the northeastern US, are limited by: (1) a lack of comprehensive ;pre-drill; data for groundwater composition (water and gas); (2) uncertainty in the hydrogeological factors that control the occurrence of naturally present CH4 and brines in shallow Upper Devonian (UD) aquifers; and (3) limited geochemical techniques to quantify the sources and migration of crustal fluids (specifically methane) at various time scales. To address these questions, we analyzed the noble gas, dissolved ion, and hydrocarbon gas geochemistry of 72 drinking-water wells and one natural methane seep all located ≫1 km from shale gas drill sites in the NAB. In the present study, we consciously avoided groundwater wells from areas near active or recent drilling to ensure shale gas development would not bias the results. We also intentionally targeted areas with naturally occurring CH4 to characterize the geochemical signature and geological context of gas-phase hydrocarbons in shallow aquifers of the NAB. Our data display a positive relationship between elevated [CH4], [C2H6], [Cl], and [Ba] that co-occur with high [4He]. Although four groundwater samples show mantle contributions ranging from 1.2% to 11.6%, the majority of samples have [He] ranging from solubility levels (∼45 × 10-6 cm3 STP/L) with below-detectable [CH4] and minor amounts of tritiogenic 3He in low [Cl] and [Ba] waters, up to high [4He] = 0.4 cm3 STP/L with a purely crustal helium isotopic end-member (3He/4He = ∼0.02 times the atmospheric ratio (R/Ra)) in samples with CH4 near saturation for shallow groundwater (P(CH4) = ∼1 atmosphere) and elevated [Cl] and [Ba]. These data suggest that 4He is dominated by an exogenous (i.e., migrated) crustal source for these hydrocarbon gas- and salt-rich fluids. In combination with published inorganic geochemistry (e.g., 87Sr/86Sr, Sr/Ba, Br-/Cl-), new noble gas and hydrocarbon isotopic data (e.g., 20Ne/36Ar, C2+/C1, δ13C-CH4) suggest that a hydrocarbon-rich brine likely migrated from the Marcellus Formation (via primary hydrocarbon migration) as a dual-phase fluid (gas + liquid) and was fractionated by solubility partitioning during fluid migration and emplacement into conventional UD traps (via secondary hydrocarbon migration). Based on the highly fractionated 4He/CH4 data relative to Marcellus and UD production gases, we propose an additional phase of hydrocarbon gas migration where natural gas previously emplaced in UD hydrocarbon traps actively diffuses out into and equilibrates with modern shallow groundwater (via tertiary hydrocarbon migration) following uplift, denudation, and neotectonic fracturing. These data suggest that by integrating noble gas geochemistry with hydrocarbon and dissolved ion chemistry, one can better determine the source and migration processes of natural gas in the Earth's crust, which are two critical factors for understanding the presence of hydrocarbon gases in shallow aquifers.
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Merschat, Arthur J.; Hatcher, Robert D.; Byars, Heather E.; Gilliam, William G.; Eppes, Martha Cary; Bartholomew, Mervin J.
2012-01-01
The Inner Piedmont extends from North Carolina to Alabama and comprises the Neoacadian (360–345 Ma) orogenic core of the southern Appalachian orogen. Bordered to west by the Blue Ridge and the exotic Carolina superterrane to the east, the Inner Piedmont is cored by an extensive region of migmatitic, sillimanite-grade rocks. It is a composite of the peri-Laurentian Tugaloo terrane and mixed Laurentian and peri-Gondwanan affinity Cat Square terrane, which are exposed in several gentle-dipping thrust sheets (nappes). The Cat Square terrane consists of Late Silurian to Early Devonian pelitic schist and metagraywacke intruded by several Devonian to Mississippian peraluminous granitoids, and juxtaposed against the Tugaloo terrane by the Brindle Creek fault. This field trip through the North Carolina Inner Piedmont will examine the lithostratigraphies of the Tugaloo and Cat Square terranes, deformation associated with Brindle Creek fault, Devonian-Mississippian granitoids and charnockite of the Cat Square terrane, pervasive amphibolite-grade Devonian-Mississippian (Neoacadian) deformation and metamorphism throughout the Inner Piedmont, and existence of large crystalline thrust sheets in the Inner Piedmont. Consistent with field observations, geochronology and other data, we have hypothesized that the Carolina superterrane collided obliquely with Laurentia near the Pennsylvania embayment during the Devonian, overrode the Cat Square terrane and Laurentian margin, and squeezed the Inner Piedmont out to the west and southwest as an orogenic channel buttressed against the footwall of the Brevard fault zone.
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Giles, Sam; Darras, Laurent; Clément, Gaël; Blieck, Alain; Friedman, Matt
2015-01-01
Actinopterygians (ray-finned fishes) are the most diverse living osteichthyan (bony vertebrate) group, with a rich fossil record. However, details of their earliest history during the middle Palaeozoic (Devonian) ‘Age of Fishes' remains sketchy. This stems from an uneven understanding of anatomy in early actinopterygians, with a few well-known species dominating perceptions of primitive conditions. Here we present an exceptionally preserved ray-finned fish from the Late Devonian (Middle Frasnian, ca 373 Ma) of Pas-de-Calais, northern France. This new genus is represented by a single, three-dimensionally preserved skull. CT scanning reveals the presence of an almost complete braincase along with near-fully articulated mandibular, hyoid and gill arches. The neurocranium differs from the coeval Mimipiscis in displaying a short aortic canal with a distinct posterior notch, long grooves for the lateral dorsal aortae, large vestibular fontanelles and a broad postorbital process. Identification of similar but previously unrecognized features in other Devonian actinopterygians suggests that aspects of braincase anatomy in Mimipiscis are apomorphic, questioning its ubiquity as stand-in for generalized actinopterygian conditions. However, the gill skeleton of the new form broadly corresponds to that of Mimipiscis, and adds to an emerging picture of primitive branchial architecture in crown gnathostomes. The new genus is recovered in a polytomy with Mimiidae and a subset of Devonian and stratigraphically younger actinopterygians, with no support found for a monophyletic grouping of Moythomasia with Mimiidae. PMID:26423841
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Perkins, R.B.; Piper, D.Z.; Mason, C.E.
2008-01-01
The hydrography of the Appalachian Basin in late Devonian-early Mississippian time is modeled based on the geochemistry of black shales and constrained by others' paleogeographic reconstructions. The model supports a robust exchange of basin bottom water with the open ocean, with residence times of less than forty years during deposition of the Cleveland Shale Member of the Ohio Shale. This is counter to previous interpretations of these carbon-rich units having accumulated under a stratified and stagnant water column, i.e., with a strongly restricted bottom bottom-water circulation. A robust circulation of bottom waters is further consistent with the palaeoclimatology, whereby eastern trade-winds drove upwelling and arid conditions limited terrestrial inputs of siliciclastic sediment, fresh waters, and riverine nutrients. The model suggests that primary productivity was high (~ 2??g C m- 2 d- 1), although no higher than in select locations in the ocean today. The flux of organic carbon settling through the water column and its deposition on the sea floor was similar to fluxes found in modern marine environments. Calculations based on the average accumulation rate of the marine fraction of Ni suggest the flux of organic carbon settling out of the water column was approximately 9% of primary productivity, versus an accumulation rate (burial) of organic carbon of 0.5% of primary productivity. Trace-element ratios of V:Mo and Cr:Mo in the marine sediment fraction indicate that bottom waters shifted from predominantly anoxic (sulfate reducing) during deposition of the Huron Shale Member of the Ohio Shale to predominantly suboxic (nitrate reducing) during deposition of the Cleveland Shale Member and the Sunbury Shale, but with anoxic conditions occurring intermittently throughout this period. ?? 2008 Elsevier B.V.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Gauthier, F.J.; Boudjema, A.; Lounis, R.
1995-08-01
The Ghadames and Illizi basins cover the majority of the eastern Sahara of Algeria. Geologicaly, this part of the Central Saharan platform has been influenced by a series of structural arches and {open_quotes}moles{close_quotes} (continental highs) which controlled sedimentation and structure through geologic time. These features, resulting from and having been affected by nine major tectonic phases ranging from pre-Cambrian to Tertiary, completely bound the Ghadames and Illizi Basins. During the Paleozoic both basins formed one continuous depositional entity with the Ghadames basin being the distal portion of the continental sag basin where facies and thickness variations are observed over largemore » distances. It is during the Mesozoic-Cenozoic that the Ghadames basin starts to evolve differently from the Illizi Basin. Eustatic low-stand periods resulted in continental deposition yielding the major petroleum-bearing reservoir horizons (Cambrian, Ordovician, Siluro-Devonian and Carboniferous). High-stand periods corresponds to the major marine transgressions covering the majority of the Saharan platform. These transgressions deposited the principal source rock intervals of the Silurian and Middle to Upper Devonian. The main reservoirs of the Mesozoic and Cenozoic are Triassic sandstone sequences which are covered by a thick evaporite succession forming a super-seal. Structurally, the principal phases affecting this sequence are the extensional events related to the breakup of Pangea and the Alpine compressional events. The Ghadames and Illizi basins, therefore, have been controlled by a polphase tectonic history influenced by Pan African brittle basement fracturing which resulted in complex structures localized along the major basin bounding trends as well as several subsidiary trends within the basin. These trends, as demonstrated with key seismic data, have been found to contain the majority of hydrocarbons trapped.« less
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Ludvigson, G.A.; Gonzalez, L.S.; Witzke, B.J.
1993-03-01
The Middle-Upper Devonian Cedar Valley Gp in Iowa is subdivided into four formations each representing a broad transgressive-regressive (T-R) cycle of deposition. Cycles consist of basal open marine facies that shallow upward into capping peritidal facies. Results from ongoing diagenetic studies of the Coralville Fm (late Givetian), the second T-R cycle of the Cedar Valley Gp, have focused attention on the origins of early cements. Early calcite cements in the Coralville Fm of Johnson County, Iowa, include blocky equant spars filling fenestral voids in birdseye limestones of the Iowa City Mbr and isopachous bladed spars that occur throughout the Coralville.more » Bladed spars fill stromatactis and microkarstic voids in the Iowa City Mbr, and sheltered voids in underlying open-marine skeletal packstones of the Cou Falls Mbr (lower Coralville cycle). The bladed spars include nonluminescent inclusion-free domains that contain up to 4,000 ppm Mg, and luminescent inclusion-rich domains that contain less than 2,000 ppm Mg. Birdseye spars have a constructive oscillatory luminescent-nonluminescent zonation controlled by Mn contents and contain less than 1,000 ppm Mg. Nonluminescent domains in bladed spars have the heaviest oxygen isotopic compositions of all components in the Coralville, similar to the isotopically heaviest nonluminescent brachiopods but have [delta][sup 13]C values ranging from [minus]3 to [minus]5 [per thousand]. They are interpreted to have precipitated from marine fluids saturated by CO[sub 2] produced from bacterial oxidation of organic matter. Altered luminescent domains in the bladed spars have the same [delta][sup 13]C compositions, but have widely varying [delta][sup 18]O compositions, ranging to [minus]9 [per thousand].« less
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BULGARIA’S MULTI-VECTOR FOREIGN POLICY APPROACH TO SECURITY CHALLENGES IN EASTERN EUROPE
2017-04-06
withdraw from the South Stream natural gas pipeline project which could turn Bulgaria into a leading gas hub in the Balkans. Amid Ukrainian Crisis, the EU...Corporation. Micco, Pasquale De. July 2015. Changing Pipelines , Shifting Strategies: Gas in South-eastern Europe, and the Implications for Ukraine. In...catastrophe. In support of this strategic approach, this paper finds a theoretical explanation in the realist school of study and presents an analysis of the
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Pollastro, R.M.; Roberts, L.N.R.; Cook, T.A.; Lewan, M.D.
2008-01-01
The U.S. Geological Survey (USGS) has completed an assessment of the undiscovered oil and associated gas resources of the Upper Devonian to Lower Mississippian Bakken Formation in the U.S. portion of the Williston Basin of Montana and North Dakota and within the Williston Basin Province. The assessment is based on geologic elements of a total petroleum system (TPS), which include (1) source-rock distribution, thickness, organic richness, maturation, petroleum generation, and migration; (2) reservoir-rock type (conventional or continuous), distribution, and quality; and (3) character of traps and time of formation with respect to petroleum generation and migration. Framework studies in stratigraphy and structural geology and modeling of petroleum geochemistry, combined with historical exploration and production analyses, were used to estimate the undiscovered, technically recoverable oil resource of the Bakken Formation. Using this framework, the USGS defined a Bakken-Lodgepole TPS and seven assessment units (AU) within the system. For the Bakken Formation, the undiscovered oil and associated gas resources were quantitatively estimated for six of these AUs.
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Paleozoic carbonate buildup (reef) inventory, central and southeastern Idaho
DOE Office of Scientific and Technical Information (OSTI.GOV)
Isaacson, P.E.
1987-08-01
Knowledge of central and southeastern Idaho's Paleozoic rocks to date suggest that three styles of buildup (reef) complexes occur in Late Devonian, Mississippian, and Pennsylvanian-Permian time. The Late Devonian Jefferson Formation has stromatoporoid and coral (both rugosan and tabulate) organisms effecting a buildup in the Grandview Canyon vicinity; Early Mississippian Waulsortian-type mud mounds occur in the Lodgepole formation of southeastern Idaho; there are Late Mississippian Waulsortian-type mounds in the Surrett Canyon Formation of the Lost River Range; and cyclic Pennsylvanian-Permian algal and hydrozoan buildups occur in the Juniper gulch Member of the Snaky Canyon Formation in the Arco Hills andmore » Lemhi Range. Late Devonian (Frasnian) carbonates of the Jefferson formation show buildup development on deep ramp sediments.« less
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Geologic Assessment of Undiscovered Gas Resources of the Eastern Oregon and Washington Province
U.S. Geological Survey Eastern Oregon and Washington Province Assessment Team, (compiler)
2008-01-01
The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered oil and gas potential of the Eastern Oregon and Washington Province of Oregon and Washington (USGS Province 5005). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Eastern Oregon and Washington Province, the USGS used this geologic framework to define one total petroleum system and two assessment units within the total petroleum system, and quantitatively estimated the undiscovered gas resources within each assessment unit.
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Feasibility Assessment of CO2 Sequestration and Enhanced Recovery in Gas Shale Reservoirs
NASA Astrophysics Data System (ADS)
Vermylen, J. P.; Hagin, P. N.; Zoback, M. D.
2008-12-01
CO2 sequestration and enhanced methane recovery may be feasible in unconventional, organic-rich, gas shale reservoirs in which the methane is stored as an adsorbed phase. Previous studies have shown that organic-rich, Appalachian Devonian shales adsorb approximately five times more carbon dioxide than methane at reservoir conditions. However, the enhanced recovery and sequestration concept has not yet been tested for gas shale reservoirs under realistic flow and production conditions. Using the lessons learned from previous studies on enhanced coalbed methane (ECBM) as a starting point, we are conducting laboratory experiments, reservoir modeling, and fluid flow simulations to test the feasibility of sequestration and enhanced recovery in gas shales. Our laboratory work investigates both adsorption and mechanical properties of shale samples to use as inputs for fluid flow simulation. Static and dynamic mechanical properties of shale samples are measured using a triaxial press under realistic reservoir conditions with varying gas saturations and compositions. Adsorption is simultaneously measured using standard, static, volumetric techniques. Permeability is measured using pulse decay methods calibrated to standard Darcy flow measurements. Fluid flow simulations are conducted using the reservoir simulator GEM that has successfully modeled enhanced recovery in coal. The results of the flow simulation are combined with the laboratory results to determine if enhanced recovery and CO2 sequestration is feasible in gas shale reservoirs.
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Climate effects caused by land plant invasion in the Devonian
NASA Astrophysics Data System (ADS)
Hir guillaume, Le; yannick, Donnadieu; yves, Goddéris; brigitte, Meyer-Berthaud; gilles, Ramstein
2017-04-01
Land plants invaded continents during the Mid-Paleozoic. Their spreading and diversification have been compared to the Cambrian explosion in terms of intensity and impact on the diversification of life on Earth. Whereas prior studies were focused on the evolution of the root system and its weathering contribution, here we investigated the biophysical impacts of plant colonization on the surface climate through changes in continental albedo, roughness, thermal properties, and potential evaporation using a 3D-climate model coupled to a global biogeochemical cycles associated to a simple model for vegetation dynamics adapted to Devonian conditions. From the Early to the Late Devonian, we show that continental surface changes induced by land plants and tectonic drift have produced a large CO2 drawdown without being associated to a global cooling, because the cooling trend is counteracted by a warming trend resulting from the surface albedo reduction. If CO2 is consensually assumed as the main driver of the Phanerozoic climate, during land-plant invasion, the modifications of soil properties could have played in the opposite direction of the carbon dioxide fall, hence maintaining warm temperatures during part of the Devonian.
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NASA Astrophysics Data System (ADS)
Thanh, Tong-Dzuy; Duyen, Than Duc; Hung, Nguyen Huu; My, Bui Phu
2007-01-01
Lower Devonian corals and stromatoporoids have recently been discovered in limestones among low grade metamorphic rocks on the western margin of the Kon Tum Block (South Viet Nam). This unit has been identified as the Cu Brei Formation. Coral and stromatoporoid species have been described including Squameofavosites aff. spongiosus, Parallelostroma cf. multicolumnum, Amphipora cf. rasilis, A. cf. raritalis, Simplexodictyon cf. artyschtense, Stromatopora cf. boriarchinovi and Stromatopora sp. indet. The Cu Brei Formation is exposed in a small area 6 km in length and 3 km wide at the foot of Cu Brei Mountain (Sa Thay District, Kon Tum Province). As this formation is in marine shelf facies it is probable that further exposures of Lower Devonian sediments may be discovered in the Kon Tum Block. This discovery raises the question of the tectonic history of the metamorphic Kon Tum Block. It is possible that the block was not an area of positive uplift from the beginning of Paleozoic as has been supposed, but was submerged in a marine environment, at least on its outer margins, in the Devonian, and possibly even earlier, in Early Paleozoic.
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Hydrology, water quality, and effects of drought in Monroe County, Michigan
Nicholas, J.R.; Rowe, Gary L.; Brannen, J.R.
1996-01-01
Monroe County relies heavily on its aquifers and streams for drinking water, irrigation, and other ~ses; however, increased water use, high concentrations of certain constituents in ground water, and droughts may limit the availability of water resources. Although the most densely populated parts of the county use water from the Great Lakes, large amounts of ground water are withdrawn for quarry dewatering, domestic supply, and irrigation.Unconsolidated deposits and bedrock of Silurian and Devonian age underlie Mon_roe County. The unconsolidated deposits are mostly clayey and less than 50 feet thick. Usable amounts of ground water generally are obtained from thin, discontinuous surficial sand deposits or, in the northwestern part of the county, from deep glaciofluvial deposits. In most of the county, however, ground water in unconsolidated deposits is highly susceptible to effects of droughts and to contamination.The bedrock is mostly carbonate rock, and usable quantities of ground water can be obtained from fractures and other secondary openings throughout the county. Transmissivities of the Silurian-Devonian aquifer range from 10 to 6,600 feet squared per day. Aquifer tests and historical informati.on indicate that the Silurian-Devonian aquifer is confmed throughout most of the county. The major recharge area for the Silurian-Devonian aquifer in Monroe County is in the southwest, and groundwater flow is mostly southeastward toward Lake Erie. In the northeastern and southeastern parts of the county, the potentiometric surface of the SilurianDevonian aquifers has been lowered by pumpage to below the elevation of Lake Erie.Streams and artificial drains in Monroe County are tributary to Lake Erie. Most streams are perennial because of sustained discharge from the sand aquifer and the Silurian-Devonian aquifer; however, the lower reaches of River Raisin and Plum Creek lost water to the Silurian-Devonian aquifer in July 1990.The quality of ground water and of streamwater at low flow is suitable for most domestic u~es, irrigation, and recreation. In ground water, dissolved solids and hydrogen sulfide are present at concentrations objectionable to some users. Indicators of ground-water contamination from agricultural activities-pesticides and nitrates-were not present at detectable concentrations or were below U.S. Environmental Protection Agency (USEPA) limits. In streamwater, some treatment to remove bacteria may be necessary in summer months; nitrate concentrations, however, were found to be below USEPA limits.Tritium concentrations indicative of recent recharge to the Silurian-Devonian aquifer are present in a southwest-to-northeast-trending band from Whiteford to Berlin Townships. Generally, where glacial deposits are thicker than 30 feet, rech~rge.takes more than 40 years. Carbon isotope data md1cate that some of the ground water in the Silurian-Devonian aquifer is more than 14,000 years old.Mild droughts are common in Michigan, but long severe droughts, such as those during 1930-37 and 1960-67, are infrequent. The most recent drought, during 1988, was severe but short. Ground-water levels declined throughout the county; the largest declines were probably in the southwest. Shallow bedrock wells completed in only the upper part of the Silurian-Devonian aquifer and near large uses of ground water were especially susceptible to the effects of drought. Deep bedrock wells continued to produce water through the drought of 1988.During droughts, streamflow is reduced because of low ground-water levels and high consumptive uses of surface water. In 1988, annual discharge on the River Raisin was near normal, but monthly averages were below normal from March through August. The quality of surface water during droughts is similar to that during normal lowflow conditions.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Seyler, Beverly; Harris, David; Keith, Brian
2008-06-30
This study examined petroleum occurrence in Ordovician, Silurian and Devonian reservoirs in the Illinois Basin. Results from this project show that there is excellent potential for additional discovery of petroleum reservoirs in these formations. Numerous exploration targets and exploration strategies were identified that can be used to increase production from these underexplored strata. Some of the challenges to exploration of deeper strata include the lack of subsurface data, lack of understanding of regional facies changes, lack of understanding the role of diagenetic alteration in developing reservoir porosity and permeability, the shifting of structural closures with depth, overlooking potential producing horizons,more » and under utilization of 3D seismic techniques. This study has shown many areas are prospective for additional discoveries in lower Paleozoic strata in the Illinois Basin. This project implemented a systematic basin analysis approach that is expected to encourage exploration for petroleum in lower Paleozoic rocks of the Illinois Basin. The study has compiled and presented a broad base of information and knowledge needed by independent oil companies to pursue the development of exploration prospects in overlooked, deeper play horizons in the Illinois Basin. Available geologic data relevant for the exploration and development of petroleum reservoirs in the Illinois Basin was analyzed and assimilated into a coherent, easily accessible digital play portfolio. The primary focus of this project was on case studies of existing reservoirs in Devonian, Silurian, and Ordovician strata and the application of knowledge gained to future exploration and development in these underexplored strata of the Illinois Basin. In addition, a review of published reports and exploration in the New Albany Shale Group, a Devonian black shale source rock, in Illinois was completed due to the recent increased interest in Devonian black shales across the United States. The New Albany Shale is regarded as the source rock for petroleum in Silurian and younger strata in the Illinois Basin and has potential as a petroleum reservoir. Field studies of reservoirs in Devonian strata such as the Geneva Dolomite, Dutch Creek Sandstone and Grassy knob Chert suggest that there is much additional potential for expanding these plays beyond their current limits. These studies also suggest the potential for the discovery of additional plays using stratigraphic concepts to develop a subcrop play on the subkaskaskia unconformity boundary that separates lower Devonian strata from middle Devonian strata in portions of the basin. The lateral transition from Geneva Dolomite to Dutch Creek Sandstone also offers an avenue for developing exploration strategies in middle Devonian strata. Study of lower Devonian strata in the Sesser Oil Field and the region surrounding the field shows opportunities for development of a subcrop play where lower Devonian strata unconformably overlie Silurian strata. Field studies of Silurian reservoirs along the Sangamon Arch show that opportunities exist for overlooked pays in areas where wells do not penetrate deep enough to test all reservoir intervals in Niagaran rocks. Mapping of Silurian reservoirs in the Mt. Auburn trend along the Sangamon Arch shows that porous reservoir rock grades laterally to non-reservoir facies and several reservoir intervals may be encountered in the Silurian with numerous exploration wells testing only the uppermost reservoir intervals. Mapping of the Ordovician Trenton and shallower strata at Centralia Field show that the crest of the anticline shifted through geologic time. This study illustrates that the axes of anticlines may shift with depth and shallow structure maps may not accurately predict structurally favorable reservoir locations at depth.« less
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Lamsdell, James C.; Braddy, Simon J.
2010-01-01
Gigantism is widespread among Palaeozoic arthropods, yet causal mechanisms, particularly the role of (abiotic) environmental factors versus (biotic) competition, remain unknown. The eurypterids (Arthropoda: Chelicerata) include the largest arthropods; gigantic predatory pterygotids (Eurypterina) during the Siluro-Devonian and bizarre sweep-feeding hibbertopterids (Stylonurina) from the Carboniferous to end-Permian. Analysis of family-level originations and extinctions among eurypterids and Palaeozoic vertebrates show that the diversity of Eurypterina waned during the Devonian, while the Placodermi radiated, yet Stylonurina remained relatively unaffected; adopting a sweep-feeding strategy they maintained their large body size by avoiding competition, and persisted throughout the Late Palaeozoic while the predatory nektonic Eurypterina (including the giant pterygotids) declined during the Devonian, possibly out-competed by other predators including jawed vertebrates. PMID:19828493
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The first direct evidence of a Late Devonian coelacanth fish feeding on conodont animals
NASA Astrophysics Data System (ADS)
Zatoń, Michał; Broda, Krzysztof; Qvarnström, Martin; Niedźwiedzki, Grzegorz; Ahlberg, Per Erik
2017-04-01
We describe the first known occurrence of a Devonian coelacanth specimen from the lower Famennian of the Holy Cross Mountains, Poland, with a conodont element preserved in its digestive tract. A small spiral and phosphatic coprolite (fossil excrement) containing numerous conodont elements and other unrecognized remains was also found in the same deposits. The coprolite is tentatively attributed to the coelacanth. Although it is unclear whether the Late Devonian coelacanth from Poland was an active predator or a scavenger, these finds provide the first direct evidence of feeding on conodont animals by early coelacanth fish, and one of the few evidences of feeding on these animals known to date. It also expands our knowledge about the diet and trophic relations between the Paleozoic marine animals in general.
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NASA Astrophysics Data System (ADS)
Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.
2017-05-01
Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the Frasnian sedimentation occurred through the opening of a back-arc basin formed along the Laurussian active margin during Rheic Ocean subduction, as has been recently proposed for the Rhenohercynian Zone in Central Europe. Detrital zircon ages in the Frasnian siliciclastic rocks indicate provenance in the Meguma terrane, Avalonia and Devonian Rheic Ocean arc(s). As a result of back-arc basin inversion, the Frasnian formations underwent deformation, metamorphism and denudation and were unconformably overlain by Famennian to Visean siliciclastic strata (including the Phyllite-Quartzite Formation of the South Portuguese Zone). The Latest Devonian-Early Carboniferous detritus were probably shed to the Pulo do Lobo Zone (Represa and Santa Iria formations) by recycling of Devonian siliciclastic rocks, from the South Portuguese Zone (Meguma terrane) and from a new distinct source with Baltica/Laurentia derivation (preserved in the Horta da Torre Formation and Alajar Mélange).
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Quantifying methane emissions from natural gas production in north-eastern Pennsylvania
NASA Astrophysics Data System (ADS)
Barkley, Zachary R.; Lauvaux, Thomas; Davis, Kenneth J.; Deng, Aijun; Miles, Natasha L.; Richardson, Scott J.; Cao, Yanni; Sweeney, Colm; Karion, Anna; Smith, MacKenzie; Kort, Eric A.; Schwietzke, Stefan; Murphy, Thomas; Cervone, Guido; Martins, Douglas; Maasakkers, Joannes D.
2017-11-01
Natural gas infrastructure releases methane (CH4), a potent greenhouse gas, into the atmosphere. The estimated emission rate associated with the production and transportation of natural gas is uncertain, hindering our understanding of its greenhouse footprint. This study presents a new application of inverse methodology for estimating regional emission rates from natural gas production and gathering facilities in north-eastern Pennsylvania. An inventory of CH4 emissions was compiled for major sources in Pennsylvania. This inventory served as input emission data for the Weather Research and Forecasting model with chemistry enabled (WRF-Chem), and atmospheric CH4 mole fraction fields were generated at 3 km resolution. Simulated atmospheric CH4 enhancements from WRF-Chem were compared to observations obtained from a 3-week flight campaign in May 2015. Modelled enhancements from sources not associated with upstream natural gas processes were assumed constant and known and therefore removed from the optimization procedure, creating a set of observed enhancements from natural gas only. Simulated emission rates from unconventional production were then adjusted to minimize the mismatch between aircraft observations and model-simulated mole fractions for 10 flights. To evaluate the method, an aircraft mass balance calculation was performed for four flights where conditions permitted its use. Using the model optimization approach, the weighted mean emission rate from unconventional natural gas production and gathering facilities in north-eastern Pennsylvania approach is found to be 0.36 % of total gas production, with a 2σ confidence interval between 0.27 and 0.45 % of production. Similarly, the mean emission estimates using the aircraft mass balance approach are calculated to be 0.40 % of regional natural gas production, with a 2σ confidence interval between 0.08 and 0.72 % of production. These emission rates as a percent of production are lower than rates found in any other basin using a top-down methodology, and may be indicative of some characteristics of the basin that make sources from the north-eastern Marcellus region unique.
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NASA Astrophysics Data System (ADS)
Glorie, Stijn; Agostino, Kate; Dutch, Rian; Pawley, Mark; Hall, James; Danišík, Martin; Evans, Noreen J.; Collins, Alan S.
2017-04-01
Multi-method geo- and thermochronological data obtained for Palaeo- and Mesoproterozoic granitoids traversing the main structural architecture of the eastern Musgrave Province within South Australia reveal multiphase cooling histories. Apatite U-Pb dating on six samples yield consistent ages of 1075-1025 Ma, suggesting a thermal reset coinciding with mantle-derived magmatism of the greater Warakurna Large Igneous Province ( 1080-1040 Ma). Apatite fission track (AFT) analysis indicate that four discrete thermal events affected the study area, inducing cooling through the AFT partial annealing zone ( 60-120 °C), supported by apatite and zircon (U-Th-Sm)/He data. Late Neoproterozoic cooling from deep crustal levels to temperatures < 200 °C was discerned, which is thought to be related to exhumation and denudation during the Petermann Orogeny. Subsequent cooling events at 450-400 Ma (Silurian-Devonian) and 310-290 Ma (Late Carboniferous) are interpreted to represent exhumation associated with the Alice Springs Orogeny. The latter event exhumed the sampled plutons to shallow crustal depths. An additional Triassic - early Jurassic thermal event, likely recording elevated geothermal gradients at that time, was observed throughout the study area, however, more data is needed to further support this interpretation. The high sample density across the structural architecture of the study area furthermore reveals patterns of fault reactivation and resulting differential exhumation, indicating shallower exhumation levels in the centre and deeper exhumation towards the margins of the sampled transect. The observed differential exhumation patterns match with existing seismic data and fit a model of an inverted graben system for the Phanerozoic evolution of the eastern Musgraves. The results highlight a complex Phanerozoic thermal history for the eastern Musgraves and help to elucidate the poorly appreciated tectonic evolution of inland Australia. This study further demonstrates how high-density sample transects across structural architecture can assess the relative crustal level and associated preservation of the thermal history record within fault-reactivated terranes.
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Alligator ridge district, East-Central Nevada: Carlin-type gold mineralization at shallow depths
Nutt, C.J.; Hofstra, A.H.
2003-01-01
Carlin-type deposits in the Alligator Ridge mining district are present sporadically for 40 km along the north-striking Mooney Basin fault system but are restricted to a 250-m interval of Devonian to Mississippian strata. Their age is bracketed between silicified ca. 45 Ma sedimentary rocks and unaltered 36.5 to 34 Ma volcanic rocks. The silicification is linked to the deposits by its continuity with ore-grade silicification in Devonian-Mississippian strata and by its similar ??18O values (_e1???17???) and trace element signature (As, Sb, Tl, Hg). Eocene reconstruction indicates that the deposits formed at depths of ???300 to 800 m. In comparison to most Carlin-type gold deposits, they have lower Au/Ag, Au grades, and contained Au, more abundant jasperoid, and textural evidence from deposition of an amorphous silica precursor in jasperoid. These differences most likely result from their shallow depth of formation. The peak fluid temperature (_e1???230??C) and large ??18OH2O value shift from the meteroric water line (_e1???20???) suggest that ore fluids were derived from depths of 8 km or more. A magnetotelluric survey indicates that the Mooney Basin fault system penetrates to mid-crustal depths. Deep circulation of meteoric water along the Mooney Basin fault system may have been in response to initial uplift of the East Humboldt-Ruby Mountains metamorphic core complex; convection also may have been promoted by increased heat flow associated with large magnitude extension in the core complex and regional magmatism. Ore fluids ascended along the fault system until they encountered impermeable Devonian and Mississippian shales, at which point they moved laterally through permeable strata in the Devonian Guilmette Formation, Devonian-Mississippian Pilot Shale, Mississippian Joana Limestone, and Mississippian Chainman Shale toward erosional windows where they ascended into Eocene fluvial conglomerates and lake sediments. Most gold precipitated by sulfidation of host-rock Fe and mixing with local ground water in zones of lateral fluid flow in reactive strata, such as the Lower Devonian-Mississippian Pilot Shale.
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Higley, Debra K.
2013-01-01
The Upper Devonian and Lower Mississippian Woodford Shale is an important petroleum source rock for Mississippian reservoirs in the Anadarko Basin Province of Oklahoma, Kansas, Texas, and Colorado, based on results from a 4D petroleum system model of the basin. The Woodford Shale underlies Mississippian strata over most of the Anadarko Basin portions of Oklahoma and northeastern Texas. The Kansas and Colorado portions of the province are almost entirely thermally immature for oil generation from the Woodford Shale or potential Mississippian source rocks, based mainly on measured vitrinite reflectance and modeled thermal maturation. Thermal maturities of the Woodford Shale range from mature for oil to overmature for gas generation at present-day depths of about 5,000 to 20,000 ft. Oil generation began at burial depths of about 6,000 to 6,500 ft. Modeled onset of Woodford Shale oil generation was about 330 million years ago (Ma); peak oil generation was from 300 to 220 Ma.Mississippian production, including horizontal wells of the informal Mississippi limestone, is concentrated within and north of the Sooner Trend area in the northeast Oklahoma portion of the basin. This large pod of oil and gas production is within the area modeled as thermally mature for oil generation from the Woodford Shale. The southern boundary of the trend approximates the 99% transformation ratio of the Woodford Shale, which marks the end of oil generation. Because most of the Sooner Trend area is thermally mature for oil generation from the Woodford Shale, the trend probably includes short- and longer-distance vertical and lateral migration. The Woodford Shale is absent in the Mocane-Laverne Field area of the eastern Oklahoma panhandle; because of this, associated oil migrated from the south into the field. If the Springer Formation or deeper Mississippian strata generated oil, then the southern field area is within the oil window for associated petroleum source rocks. Mississippian fields along the western boundary of the study area were supplied by oil that flowed northward from the Panhandle Field area and westward from the deep basin.
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NASA Astrophysics Data System (ADS)
Warner, N. R.; Darrah, T. H.; Jackson, R. B.; Osborn, S.; Down, A.; Vengosh, A.
2012-12-01
The acceleration in production of natural gas from shale formations through horizontal drilling and hydraulic fracturing has altered the landscape of domestic energy production in the USA. Yet shale gas exploration has generated an increased awareness of risks to drinking water quality amid concerns for the possible migration of stray gas or hydraulic fracturing fluid and/or flowback brine to shallow drinking water aquifers. The degree to which shallow drinking water is at risk from hydraulic fracturing could depend upon the hydraulic connectivity between the shale gas formations and the surface. In this study, we analyzed the geochemistry of over 400 water samples located across six counties of northeastern Pennsylvania in the three principle aquifers, two Upper Devonian Age bedrock aquifers (Catskill and Lock Haven) and one Quaternary Age (Alluvium) that overlie the Marcellus Formation. Based on a detailed analysis of major (Br, Cl, Na, Mg, Ba, and Sr) and trace (Li) element geochemistry, coupled with utilization of a specific spectrum of isotopic tracers (87Sr/86Sr, 228Ra/ 226Ra, 2H/H, 18O/16O), we identify a salinized (Cl> 20 mg/L) shallow groundwater type which suggests conservative mixing relationships between fresh shallow groundwater and an underlying brine. Identification of the brine source is complicated as many of the brines in the northern Appalachian Basin likely share a common origin as the expelled remnants of the formation of the Silurian Salina evaporate deposits. To determine the ultimate source of the diluted brine we compared the observed geochemistry to over 80 brines produced from northern Appalachian Basin formations. The shallow salinized groundwater most closely resembles diluted produced water from the Middle Devonian Marcellus Formation. The 18O/16O and 2H/H of the salinized groundwater indicate that the brine is likely diluted with post-glacial (<10,000 ybp) meteoric water. Combined, these data indicate that hydraulic connections allowed cross formational migration of brine from deeper formations (1-2 kilometers below ground surface) and subsequent dilution. The occurrence of the saline water does not appear to be correlated with the location of shale-gas wells. Also, salinized groundwater with similar major element chemistry was reported prior to the most recent shale-gas development in the region. The source of the salinized water is likely not the recent drilling and hydraulic fracturing; instead brine migrated into the shallow aquifers and was recently diluted through natural pathways and processes. However, the presence of natural hydraulic connections to deeper formations suggests specific structural and hydrodynamic regimes in northeastern Pennsylvania where shallow drinking water resources are at greater risk of contamination, particularly with fugitive gases, during drilling and hydraulic fracturing of shale gas. The severity of the risk could depend upon the presence of pathways that allow the migration of fluids into the shallow aquifers on human time scales.
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NASA Astrophysics Data System (ADS)
Gilotti, Jane A.; Nutman, Allen P.; Brueckner, Hannes K.
2004-10-01
A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th/U values than the HP ones, no Eu anomaly, and are thus comparable to UHP zircons in the literature. The 206Pb/238U age of these zircons is 360±5 Ma, much younger than the HP eclogites. The same sample gives a Sm-Nd age of 342±6 Ma. Unlike the HP eclogites, the Sm-Nd age of the UHP rock is ca. 20 Ma younger than the U-Pb zircon age and most likely records slow cooling through the closure temperature, since peak temperatures were in excess of 900°C. Widespread HP metamorphism of both the Laurentian and Baltica continental margins marks the culmination of this continent continent collision in the Devonian. Carboniferous UHP conditions, though localized in the east, suggest a prolonged collisional history rather than a short-lived Scandian orogeny. The traditional Silurian Scandian orogeny should thus be extended through the Devonian.
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Ziegler, W.; Sandberg, C.A.
2000-01-01
Conodonts are accepted internationally to define Devonian Series and Stage boundaries. Hence, the evolution and taxonomy of pelagic palmatolepids, primarily Palmatolepis and its direct ancestor Mesotaxis, and shallow-water icriodontids, Icriodus, Pelekysgnathus, and "Icriodus", are the major tools for recognizing subdivisions of the Upper Devonian. Palmatolepids are the basis for the Late Devonian Standard Conodont Zonation (ZIEGLER & SANDBERG 1990), whereas icriodontids are the basis for the alternative, integrated shallow-water zonation (SANDBERG & DREESEN 1984). However, an alternative palmatolepid taxonomy for some Frasnian species has been employed recently by some conodont workers using the Montagne Noire (M.N.) zonation, shape analyses of Pa elements, and multielement reconstructions of KLAPPER (1989), KLAPPER & FOSTER (1993); and KLAPPER et al. (1996). Herein, the evolution of palmatolepids and icriodontids is summarized in terms of our zonation and some of the taxonomic differences with the alternative M.N. zonation are exemplified. One of the problems in relating the Standard and M.N. zonations arises from previous errors of interpretation and drafting of the Martenberg section in Germany. This section was designated the reference section for the Frasnian transitans through jamieae Zones by ZIEGLER & SANDBERG (1990). Herein, the early and middle Frasnian zonal boundaries at Martenberg are improved by re-study of our old and recent collections from three profiles, spaced only 4 m apart. Serious problems exist with the Global Stratotype Sections and Points (GSSP's), selected by the Subcommission on Devonian Stratigraphy, following the paleontologic definition of the bases of the Frasnian, Famennian, and Tournaisian Stages, because of the difficulty in making global correlations from these GSSP's. Our summary of these problems should be helpful if future workers decide to relocate these GSSP's.
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Algeo, T. J.
1998-01-01
The Devonian Period was characterized by major changes in both the terrestrial biosphere, e.g. the evolution of trees and seed plants and the appearance of multi-storied forests, and in the marine biosphere, e.g. an extended biotic crisis that decimated tropical marine benthos, especially the stromatoporoid-tabulate coral reef community. Teleconnections between these terrestrial and marine events are poorly understood, but a key may lie in the role of soils as a geochemical interface between the lithosphere and atmosphere/hydrosphere, and the role of land plants in mediating weathering processes at this interface. The effectiveness of terrestrial floras in weathering was significantly enhanced as a consequence of increases in the size and geographic extent of vascular land plants during the Devonian. In this regard, the most important palaeobotanical innovations were (1) arborescence (tree stature), which increased maximum depths of root penetration and rhizoturbation, and (2) the seed habit, which freed land plants from reproductive dependence on moist lowland habitats and allowed colonization of drier upland and primary successional areas. These developments resulted in a transient intensification of pedogenesis (soil formation) and to large increases in the thickness and areal extent of soils. Enhanced chemical weathering may have led to increased riverine nutrient fluxes that promoted development of eutrophic conditions in epicontinental seaways, resulting in algal blooms, widespread bottomwater anoxia, and high sedimentary organic carbon fluxes. Long-term effects included drawdown of atmospheric pCO2 and global cooling, leading to a brief Late Devonian glaciation, which set the stage for icehouse conditions during the Permo-Carboniferous. This model provides a framework for understanding links between early land plant evolution and coeval marine anoxic and biotic events, but further testing of Devonian terrestrial-marine teleconnections is needed.
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NASA Astrophysics Data System (ADS)
Insel, N.; Grove, M.; Haschke, M.; Barnes, J. B.; Schmitt, A. K.; Strecker, M. R.
2012-12-01
Constraining the pre-Neogene history of the Puna plateau is crucial for establishing the initial conditions that attended the early stage evolution of the southern extent of the Andean plateau. We apply high- to low-temperature thermochronology data from plutonic rocks in northwestern Argentina to quantify the Paleozoic, Mesozoic and early Tertiary cooling history of the Andean crust. U-Pb crystallization ages of zircons indicate that pluton intrusion occurred during the early mid-Ordovician (490-470 Ma) and the late Jurassic (160-150 Ma). Lower-temperature cooling histories from 40Ar/39Ar analyses of K-feldspar vary substantially. Basement rocks underlying the western Puna resided at temperatures below 200°C (<6 km depth) since the Devonian (˜400 Ma). In contrast, basement rocks underlying the southeastern Puna were hotter (˜200-300°C) throughout the Paleozoic and Jurassic and cooled to temperatures of <200°C by ˜120 Ma. The southeastern Puna basement records a rapid cooling phase coeval with active extension of the Cretaceous Salta rift at ˜160-100 Ma that we associate with tectonic faulting and lithospheric thinning. The northeastern Puna experienced protracted cooling until the late Cretaceous with temperatures <200°C during the Paleocene. Higher cooling rates between 78 and 55 Ma are associated with thermal subsidence during the postrift stage of the Salta rift and/or shortening-related flexural subsidence. Accelerated cooling and deformation during the Eocene was focused within a narrow zone along the eastern Puna/Eastern Cordillera transition that coincides with Paleozoic/Mesozoic structural and thermal boundaries. Our results constrain regional erosion-induced cooling throughout the Cenozoic to have been less than ˜150°C, which implies total Cenozoic denudation of <6-4 km.
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NASA Astrophysics Data System (ADS)
Jeon, Heejin; Williams, Ian S.; Bennett, Vickie C.
2014-12-01
The Permo-Triassic granites of the New England Orogen, eastern Australia, were emplaced into a volcanic arc complex accreted to the eastern Gondwana margin in the Late Devonian or Early Carboniferous. Zircon U-Pb dating shows that the S-type Hillgrove (∼297 Ma) and Bundarra (∼287 Ma) Supersuites predated intrusion of the I-type Moonbi Supersuite (∼250 Ma) by up to 50 Ma. The high δ18Ozrn of the S-type granites (10.0-11.5‰), and range of U-Pb ages (∼370-300 Ma) and δ18Ozrn (∼5-10‰) of their inherited zircon cores, show that their source rocks were predominantly weathered Carboniferous volcaniclastics, the youngest deposited < 25 Ma before the granites were emplaced. In contrast, the lower δ18Ozrn (6.9-7.8‰) and lack of inheritance in the I-type granites is consistent with a zircon poor, more juvenile source, probably a mafic igneous underplate mixed with a small amount of volcanogenic and/or oceanic sediment. Despite the differences in source materials, the εHf(t) values of all granites, both S- and I-type, are similar (+5.0 ± 0.5 cf. +5.9 ± 0.5), consistent with both the mafic and sedimentary components in the granite sources being relatively young and similar in Hf isotopic composition at the time of granite genesis. In young, isotopically juvenile orogens, the O isotopic composition of well-dated igneous and inherited zircon can be a much more sensitive indicator of petrogenetic processes than the zircon Hf isotopic compositions alone.
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The pre-Mesozoic tectonic unit division of the Xing-Meng orogenic belt (XMOB)
NASA Astrophysics Data System (ADS)
Xu, Bei; Zhao, Pan
2014-05-01
According to the viewpoint that the paleo-Asian ocean closed by the end of early Paleozoic and extended during the late Paleozoic, a pre-Mesozoic tectonic unit division has been suggested. Five blocks and four sutures have been recognized in the pre-Devonia stage, the five blocks are called Erguna (EB), Xing'an (XB), Airgin Sum-Xilinhot (AXB), Songliao-Hunshandak (SHB) and Jiamusi (JB) blocks and four sutures, Xinlin-Xiguitu (XXS), Airgin Sum-Xilinhot-Heihe (AXHS), Ondor Sum-Jizhong-Yanji (OJYS) and Mudanjiang (MS) sutures. The EB contains the Precambrian base with the ages of 720-850Ma and ɛHf(T)=+2.5to +8.1. The XB is characterized by the Paleoproterozoic granitic gneiss with ɛHf(T)=-3.9 to -8.9. Several ages from 1150 to 1500 Ma bave been acquired in the AXB, proving presence of old block that links with Hutag Uul block in Mongolia to the west. The Paleoproterozoic (1.8-1.9Ga) and Neoproterozoic (750-850Ma) ages have been reported from southern and eastern parts of the SHB, respectively. As a small block in east margin of the XMOB, the JB outcrops magmatite and granitic gneiss bases with ages of 800-1000Ma. The XXS is marked by blueschists with zircon ages of 490-500Ma in Toudaoqiao village, ophiolites in Xiguitu County and granite with ages of about 500Ma along the northern segment of XXS. The AXHS is characterized by the early Paleozoic arc magmatic rocks with ages from 430Ma to 490Ma, mélange and the late Devonia molass basins, which indicates a northward subduction of the SHB beneath the AXB during the early-middle Paleozoic. The OJYS is composed of the early Paleozoic volcanic rocks, diorites and granites with ages of 425-475Ma, blueschists, ophiolitic mélange, the late Silurian flysch and Early-Middle Devonian molasses in western segment, granites (420-450Ma) in middle segment, and plagiogranites (443Ma) and the late Silurian molasses in eastern segment. This suture was caused by a southward subduction of the SHB beneath the North China block. The MS is between the SHB and JB, marked by the three phase granites of 485, 450 and 425Ma in the SHB. Tectonic units of the middle Devonian-Carboniferous tectonic stage include the middle-late Devonian continental basin, Carboniferious continental and epeiric sea basin, intrusive and irruptive igneous rock belt with ages from 300Ma to 330Ma containing granites, diorites, gabbros and biomodal volcanic rocks, and early Carboniferious ophiolites of 330-350Ma in Hegenshan and Erenhot. The Permian tectonic units can be divided into continental rift belt, ophiolite belt, alkaline rock belt and "red sea"-like ocean basin, which indicates an continuous extension environment during the Permian. The continental rift belt is composed of thick continental sedimentary rocks containing plant fossils, biomodal volcanic rocks (270-290Ma). The alkaline rocks can be divided into north and south belts by their distribution. The Solonker ophiolite is a thrust sheet that is inserted in a thrust stack containing the Upper Carboniferious epeiric sea clastic rocks and carbornates. The "red sea"-like ocean basin is characterized by basalt sequences with ages of 246-260Ma, which shows an affinity to E-MORB and a tendency towards OIB.
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Thermal Maturity of Pennsylvanian Coals and Coaly Shales, Eastern Shelf and Fort Worth Basin, Texas
Hackley, Paul C.; Guevara, Edgar H.; Hentz, Tucker F.; Hook, Robert W.
2007-01-01
The U.S. Geological Survey and the Texas Bureau of Economic Geology are engaged in an ongoing collaborative study to characterize the organic composition and thermal maturity of Upper Paleozoic coal-bearing strata from the Eastern Shelf of the Midland basin and from the Fort Worth basin, north-central Texas. Data derived from this study will have application to a better understanding of the potential for coalbed gas resources in the region. This is an important effort in that unconventional resources such as coalbed gas are expected to satisfy an increasingly greater component of United States and world natural gas demand in coming decades. In addition, successful coalbed gas production from equivalent strata in the Kerr basin of southern Texas and from equivalent strata elsewhere in the United States suggests that a closer examination of the potential for coalbed gas resources in north-central Texas is warranted. This report presents thermal maturity data for shallow (<2,000 ft; <610 m) coal and coaly shale cuttings, core, and outcrop samples from the Middle-Upper Pennsylvanian Strawn, Canyon, and Cisco Groups from the Eastern Shelf of the Midland basin. Data for Lower Pennsylvanian Atoka Group strata from deeper wells (5,400 ft; 1,645 m) in the western part of the Fort Worth basin also are included herein. The data indicate that the maturity of some Pennsylvanian coal and coaly shale samples is sufficient to support thermogenic coalbed gas generation on the Eastern Shelf and in the western Fort Worth basin.
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Insights into oil cracking based on laboratory experiments
Hill, R.J.; Tang, Y.; Kaplan, I.R.
2003-01-01
The objectives of this pyrolysis investigation were to determine changes in (1) oil composition, (2) gas composition and (3) gas carbon isotope ratios and to compare these results with hydrocarbons in reservoirs. Laboratory cracking of a saturate-rich Devonian oil by confined, dry pyrolysis was performed at T = 350-450??C, P = 650 bars and times ranging from 24 h to 33 days. Increasing thermal stress results in the C15+ hydrocarbon fraction cracking to form C6-14 and C1-5 hydrocarbons and pyrobitumen. The C6-14 fraction continues to crack to C 1-5 gases plus pyrobitumen at higher temperatures and prolonged heating time and the ?? 13Cethane-?? 13Cpropane difference becomes greater as oil cracking progresses. There is considerable overlap in product generation and product cracking. Oil cracking products accumulate either because the rate of generation of any product is greater than the rate of removal by cracking of that product or because the product is a stable end member under the experimental conditions. Oil cracking products decrease when the amount of product generated from a reactant is less than the amount of product cracked. If pyrolysis gas compositions are representative of gases generated from oil cracking in nature, then understanding the processes that alter natural gas composition is critical. ?? 2003 Elsevier Ltd. All rights reserved.
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Geology and hydrology for environmental planning in Washtenaw County, Michigan
Fleck, William B.
1980-01-01
Washteaw County is underlain by glacial deposits that range in thickness from about 50 feet to about 450 feet. Underlying the glacial deposits are sedimentary rocks of Mississippian and Devonian age. The youngest of these rocks are the sandstones of the Marshall Formation in the western part of the county; the oldest are the limestones of the Detroit River Group in the southeast corner.Sand and gravel deposits in some places in the county may yield more than 500 gallons per minute of water. Approximately 50 percent of the wells tapping the Marshall Formation, the most reliable bedrock aquifer, can yield as much as 60 gallons per minute.Washtenaw County has sand and gravel deposits that are more than 50 feet thick. The deposits are mined in several areas and are of economic importance. In addition, there may be potential for peat production in the western part of the county and for clay production in the eastern part.
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75 FR 54867 - Combined Notice of Filings No. 3
Federal Register 2010, 2011, 2012, 2013, 2014
2010-09-09
.... Eastern Time on Monday, September 13, 2010. Docket Numbers: RP10-896-001. Applicants: Granite State Gas... Numbers: RP10-963-001. Applicants: Granite State Gas Transmission, Inc. Description: Granite State Gas...
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Geochemical Aspects of Formation of Large Oil Deposits in the Volga-Ural Sedimentary Basin
NASA Astrophysics Data System (ADS)
Plotnikova, I.; Nosova, F.; Pronin, N.; Nosova, J.; Budkevich, T.
2012-04-01
The study of the rocks domanikoid type in the territory of the Ural-Volga region has an almost century-long history, beginning with the first studies of A.D. Archangelsky in the late 20's of last century. But nevertheless the question of the source of oil that formed the industrial deposits of Volga-Ural oil and gas province (OGP), where Romashkinskoye oil field occupies a special place, remains unresolved and topical. According to the sedimentary-migration theory of origin of oil and gas, it is supposed that the primary source of hydrocarbons in this area are the deposits of domanikoid type that contain a large ammount of sapropel organic matter (OM). Semiluki (domanik) horizon of srednefranski substage of the Upper Devonian is considered to be a typical domanikoid stratum. Investigation of the OM of the rocks and oils of the sedimentary cover on the basis of chromato-mass spectrometry method allows us to study the correlations between rock and oil and to assess the location (or absence) of the sources of hydrocarbons in the Paleozoic sedimentary cover. The results of geochemical study of dispersed organic matter (DOM) of rocks from Semiluksky horizon of the Upper Devonian and of the oil from Pashiysky horizon of the Middle Devonian form the basis of this paper. The objectives of this study were the following: to determine the original organic matter of the rocks, which would indicate the conditions of sedimentation of the supposed rock-oil sources; the study of chemofossils (biomarkers) in oil from Pashiyskiy horizon; and the identification of genetic association of DOM rocks from Semiluksky horizon with this oil on the basis of the oil-DOM correlation. The study of biomarkers was carried out with the help of chromato-mass spectrometry in the Laboratory of Geochemistry of Fossil Fuels (Kazan Federal University). In this study we used several informative parameters characterizing the depositional environment, the type of source OM and its maturity: STER / PENT, hC35/hC34, GAM / HOP, S27/S28/S29 (steranes), DIA / REG, Ts / Tm, MOR / HOP, NOR / HOP, TET / TRI, C29SSR, C29BBAA, C31HSR, S30STER, TRI / PENT, TRI / HOP. Comparison in the rock-oil system was performed primarily according to the parameters indicating the depositional environment of the source rock that contains syngenetic DOM - according to the coefficients that determine lithological conditions for the formation of the supposed oil-source bed strata (DIA / REG, Ts / Tm, NOR / HOP, TRI / HOP and STER / PENT). Biomarker ratios indicate a different type of sedimentation basins. Sediments, which accumulated DOM from Semilukskiy horizon, can be characterized by low clay content, or its absence, that is consistent with the carbonate type of cut of the horizon. The bacterial material that was accumulated under reducing conditions of sedimentation appeared to be the source of syngenetic OM. Chemofossils found in oils from Pashiyskiy horizon are typical of sedimentary strata that contain clay - for clastic rocks, which in the study area are mainly represented by deposits and Eyfel Givetian layers of the Middle Devonian and lowfransk substage of the Upper Devonian. The study of correlations obtained for the different coefficients of OM and oils showed that only the relationships between Ts/Tm and DIA/REG and between NOR/HOP and TRI/HOP are characteristic of close, almost similar values of correlation both for the dispersed organic matter and for oil. In all other cases, the character of the correlation of OM is significantly different from that of oil. The differences in values and ranges of biomarker ratios as well as the character of their correlation indicates the absence of genetic connection between the oil from Pashiyskiy horizon for the dispersed organic matter from Semilukskiy horizon. This conclusion is based on the study of five biomarker parameters (DIA/REG, Ts/Tm, NOR/HOP, TRI/HOP and STER/PENT). The research results described in the article clearly indicate the need for further studies of geochemical features of the organic matter of the Paleozoic mantle rocks and the underlying sedimentary and crystalline complexes of Precambrian.
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Thermal maturity of type II kerogen from the New Albany Shale assessed by13C CP/MAS NMR
Werner-Zwanziger, U.; Lis, G.; Mastalerz, Maria; Schimmelmann, A.
2005-01-01
Thermal maturity of oil and gas source rocks is typically quantified in terms of vitrinite reflectance, which is based on optical properties of terrestrial woody remains. This study evaluates 13C CP/MAS NMR parameters in kerogen (i.e., the insoluble fraction of organic matter in sediments and sedimentary rocks) as proxies for thermal maturity in marine-derived source rocks where terrestrially derived vitrinite is often absent or sparse. In a suite of samples from the New Albany Shale (Middle Devonian to the Early Mississippian, Illinois Basin) the abundance of aromatic carbon in kerogen determined by 13C CP/MAS NMR correlates linearly well with vitrinite reflectance. ?? 2004 Elsevier Inc. All rights reserved.
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Multiple fracturing experiments: propellant and borehole considerations
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cuderman, J F
1982-01-01
The technology for multiple fracturing of a wellbore, using progressively burning propellants, is being developed to enhance natural gas recovery. Multiple fracturing appears especially attractive for stimulating naturally fractured reservoirs such as Devonian shales where it is expected to effectively intersect existing fractures and connect them to a wellbore. Previous experiments and modeling efforts defined pressure risetimes required for multiple fracturing as a function of borehole diameter, but identified only a weak dependence on peak pressure attained. Typically, from four to eight equally spaced major fractures occur as a function of pressure risetime and in situ stress orientation. The presentmore » experiments address propellant and rock response considerations required to achieve the desired pressure risetimes for reliable multiple fracturing.« less
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76 FR 28972 - Eastern Shore Natural Gas Company; Notice of Request Under Blanket Authorization
Federal Register 2010, 2011, 2012, 2013, 2014
2011-05-19
.... Eastern Shore will recover its project costs entirely from Chesapeake, with no subsidy from Eastern Shore's other firm service customers. The total estimate cost of the proposed facilities is $5,850,450... questions concerning this application may be directed to Glen DiEleuterio, Project Manager, at (302) 734...
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Potter, P.E.; Maynard, J.B.; Pryor, W.A.
Studies of shales in the Appalachian area are reported (mainly in the form of abstracts of reports or manuscripts). They discuss the geology, lithology, stratigraphy, radioactivity, organic matter, the isotopic abundance of carbon and sulfur isotopes, etc. of shales in this area with maps. One report discusses Devonian paliocurrents in the central and northern Appalachian basin. Another discusses sedimentology of the Brallier Formation. The stratigraphy of upper Devonian shales along the southern shore of Lake Erie was also studied. (LTN)
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Benefits of applying technology to Devonian shale wells. Topical report, July-December 1992
DOE Office of Scientific and Technical Information (OSTI.GOV)
Voneiff, G.W.; Gatens, J.M.
1993-01-01
The report summarizes the benefits of applying technology to Devonian Shales wells in the Appalachian Basin. The results of the work suggest that an intermediate level of technology application, with an incremental cost of $6,700/well, is best for routine application in the Devonian Shales. The technology level uses conventional well tests, rock mechanical properties logs, a borehole camera, and a moderate logging suite. Most of these tools and technologies should be used on only a portion of the wells in multi-well projects, reducing the per well cost of the technology. Determining the correct reservoir description is critical to optimizing themore » stimulation treatment. The most critical reservoir properties are bulk and matrix permeabilities, net pay, stress profile, and natural fracture spacing in the direction perpendicular to induced hydraulic fractures. Applying technology to improve the accuracy of the reservoir description can significantly increase well profitability.« less
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Tetrapod trackways from the early Middle Devonian period of Poland.
Niedźwiedzki, Grzegorz; Szrek, Piotr; Narkiewicz, Katarzyna; Narkiewicz, Marek; Ahlberg, Per E
2010-01-07
The fossil record of the earliest tetrapods (vertebrates with limbs rather than paired fins) consists of body fossils and trackways. The earliest body fossils of tetrapods date to the Late Devonian period (late Frasnian stage) and are preceded by transitional elpistostegids such as Panderichthys and Tiktaalik that still have paired fins. Claims of tetrapod trackways predating these body fossils have remained controversial with regard to both age and the identity of the track makers. Here we present well-preserved and securely dated tetrapod tracks from Polish marine tidal flat sediments of early Middle Devonian (Eifelian stage) age that are approximately 18 million years older than the earliest tetrapod body fossils and 10 million years earlier than the oldest elpistostegids. They force a radical reassessment of the timing, ecology and environmental setting of the fish-tetrapod transition, as well as the completeness of the body fossil record.
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Geological duration of ammonoids controlled their geographical range of fossil distribution.
Wani, Ryoji
2017-01-01
The latitudinal distributions in Devonian-Cretaceous ammonoids were analyzed at the genus level, and were compared with the hatchling sizes (i.e., ammonitella diameters) and the geological durations. The results show that (1) length of temporal ranges of ammonoids effected broader ranges of fossil distribution and paleobiogeography of ammonoids, and (2) the hatchling size was not related to the geographical range of fossil distribution of ammonoids. Reducing the influence of geological duration in this analysis implies that hatchling size was one of the controlling factors that determined the distribution of ammonoid habitats at any given period in time: ammonoids with smaller hatchling sizes tended to have broader ammonoid habitat ranges. These relationships were somewhat blurred in the Devonian, Carboniferous, Triassic, and Jurassic, which is possibly due to (1) the course of development of a reproductive strategy with smaller hatchling sizes in the Devonian and (2) the high origination rates after the mass extinction events.
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75 FR 1767 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-01-13
..., 2009. Take notice that the Commission has received the following Natural Gas Pipeline Rate and Refund... Pipeline Company submits Second Substitute Eighth Revised Sheet 8 to its FERC Gas Tariff, First Revised... Shore Natural Gas Company. Description: Eastern Shore Natural Gas Company submits the corrected...
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76 FR 28972 - Eastern Shore Natural Gas Company; Notice of Request Under Blanket Authorization
Federal Register 2010, 2011, 2012, 2013, 2014
2011-05-19
... project costs entirely from the Shippers, with no subsidy from Eastern Shore's other firm service customers. The total estimate cost of the proposed facilities is $13,018,853. Eastern Shore proposes the... directed to Glen DiEleuterio, Project Manager, at (302) 734-6710, ext. 6723 or via fax (302) 734-6745, or e...
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NASA Astrophysics Data System (ADS)
Thomas, R. M., Jr.; Carmichael, S. K.; Waters, J. A.; Batchelor, C. J.
2017-12-01
Two of the top five most devastating mass extinctions in Earth's history occurred during the Late Devonian (419.2 Ma - 358.9 Ma), and are commonly associated with the black shale deposits of the Kellwasser and Hangenberg ocean anoxia events. Our understanding of these extinction events is incomplete partly due to sample bias, as 95% of the field sites studying the Late Devonian are limited to continental shelves and continental marine basins, and 77% of these sites are derived from the Euramerican paleocontinent. The Samnuuruul Formation at the Hoshoot Shiveetiin Gol locality (HSG), located in southwestern Mongolia, offers a unique opportunity to better understand global oceanic conditions during the Late Devonian. The HSG locality shows a continuous sequence of terrestrial to marine sediments on the East Junggar arc; an isolated, open-ocean island arc within the Central Asian Orogenic Belt (CAOB). Samples from this near shore locality consist of volcanogenic silts, sands and immature conglomerates as well as calc-alkalic basalt lava flows. Offshore sections contain numerous limestones with Late Devonian fossil assemblages. Preliminary biostratigraphy of the associated marine and terrestrial sequences can only constrain the section to a general Late Devonian age, but TIMS analysis of detrital zircons from volcanogenic sediments from the Samnuuruul Formation in localities 8-50 km from the site suggests a late Frasnian age (375, 376 Ma). To provide a more precise radiometric age of the HSG locality, zircon geochronology using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) will be performed at UNC-Chapel Hill. If the HSG section crosses the Frasnian-Famennian boundary, geochemical, mineralogical, and ichnological signatures of the Kellwasser Event are expected to be preserved, if the Kellwasser Event was indeed global in scope (as suggested by Carmichael et al. (2014) for analogous sites on the West Junggar arc in the CAOB). Black shale accumulation anywhere in the CAOB would be unlikely due to the paleoenvironment and arc topography, so additional multiproxy techniques are required for recognition of the Kellwasser Event in regions such as the HSG, which are outside of the basins where they have historically been studied. Carmichael et al. (2014) Paleo3 399, 394-403.
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Cyclostratigraphic calibration of the Famennian stage (Late Devonian, Illinois Basin, USA)
NASA Astrophysics Data System (ADS)
Pas, Damien; Hinnov, Linda; Day, James E. (Jed); Kodama, Kenneth; Sinnesael, Matthias; Liu, Wei
2018-04-01
The Late Devonian biosphere was affected by two of the most severe biodiversity crises in Earth's history, the Kellwasser and Hangenberg events near the Frasnian-Famennian (F-F) and the Devonian-Carboniferous (D-C) boundaries, respectively. Current hypotheses for the causes of the Late Devonian extinctions are focused on climate changes and associated ocean anoxia. Testing these hypotheses has been impeded by a lack of sufficient temporal resolution in paleobiological, tectonic and climate proxy records. While there have been recent advances in astronomical calibration that have improved the accuracy of the Frasnian time scale and part of the Famennian, the time duration of the entire Famennian Stage remains poorly constrained. During the Late Devonian, a complete Late Frasnian-Early Carboniferous succession of deep-shelf deposits accumulated in the epieric sea in Illinois Basin of the central North-American mid-continent. A record of this sequence is captured in three overlapping cores (H-30, Sullivan and H-32). The H-30 core section spans the F-F boundary; the Sullivan section spans almost all of the Famennian and the H-32 section sampled spans the interval of the Upper Famennian and the D-C boundary. To have the best chance of capturing Milankovitch cycles, 2000 rock samples were collected at minimum 5-cm-interval across the entire sequence. Magnetic susceptibility (MS) was measured on each sample and the preservation of climatic information into the MS signal was verified through geochemical analyses and low-temperature magnetic susceptibility acquisition. To estimate the duration of the Famennian Stage, we applied multiple spectral techniques and tuned the MS signal using the highly stable 405 kyr cycle for Sullivan and the obliquity cycle for the H-30 and H-32 cores. Based on the correlation between the cores we constructed a Famennian floating astronomical time scale, which indicates a duration of 13.5 ± 0.5 myr. An uncertainty of 0.5 myr was estimated for the uncertainties arising from the errors in the stratigraphic position of the F-F and D-C boundaries, and the 405 kyr cycle counting. Interpolated from the high-resolution U-Pb radiometric ages available for the Devonian-Carboniferous boundary we recalibrated the Frasnian-Famennian boundary numerical age to 372.4 ± 0.9 Ma.
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NASA Astrophysics Data System (ADS)
Klapper, Gilbert; Vodrážková, Stanislava
2013-06-01
Klapper, G. and Vodražkova, S. 2013. Ontogenetic and intraspecific variation in the late Emsian - Eifelian (Devonian) conodonts Polygnathus serotinus and P. bultyncki in the Prague Basin (Czech Republic) and Nevada (western U.S.). Acta Geologica Polonica, 63 (2), 153-174, Warszawa. Samples from populations of Polygnathus serotinus Telford 1975 and P. bultyncki Weddige 1977 from the Prague Basin and Nevada display normal variation for Devonian conodont species. A considerable number of previous authors, however, have proposed unnecessary synonyms of these two species, primarily because they have not recognized ontogenetic variation. In contrast, we interpret the variation as ontogenetic as well as intraspecific and present detailed synonymies as a result. A third species, P. praetrigonicus Bardashev 1992, which has been carried in open nomenclature for many years, is an important indicator of the basal costatus Zone in the Prague Basin, New York, and Nevada. We review the stratigraphic distribution of these three species and the conodont zonation across the Emsian-Eifelian (Lower-Middle Devonian) boundary. Polygnathus pseudocostatus sp. nov. (partitus-costatus zones, central Nevada) is described herein. We have observed a decrease in the pit size during ontogeny in P. bultyncki although we have not measured enough specimens to rule out intraspecific versus ontogenetic variation.
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Upper Devonian outcrop stratigraphy, southwestern Virginia and southeastern West Virginia
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dennison, J.M.; Filer, J.K.; Rossbach, T.J.
Ongoing outcrop studies are resulting in the extension of existing formal lithostratigraphic units and revision of previously less refined subdivisions of Upper Devonian strata in southwestern Virginia and southeastern West Virginia. A 425 km (263 mi) long stratigraphic cross-section has been constructed primarily from the outcrop belt along the Allegheny Structural Front, supplemented by sections from nearby outcrop belts. This NE-SW striking cross-section is oblique to the nearly due N-S depositional strike of the Upper Devonian Acadian orogenic wedge. To the southwest, the Upper Devonian section thins from 2,100 meters (6,900 feet) to 230 meters (756 feet) as progressively moremore » distal deposits are encountered. An integrated approach has been taken to establish chronostratigraphic control within the cross-section. The best time markers include particularly regressive parasequences which can be identified across facies boundaries (especially the Pound and Briery Gap Sandstones and their equivalents), volcanic ashes, and an organic-rich shale zone marking the base of a major transgression (equivalent to the base of the Huron Shale in Ohio and the Dunkirk Shale of New York). These tools provide chronostratigraphic correlation through the undivided Brallier Formation. Supplemental control includes biostratigraphic markers as well as marine dull redbeds within the Foreknobs which parallel other time lines and may represent partially reduced influxes of oxidized coastal plain sediments during minor parasequence scale regressions.« less
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Conkin, J.E.; Conkin, B.M.
1994-04-01
Internal units within the Columbus Limestone (Early Devonian Emsian [Schoharie] to Middle Devonian Eifelian [late Onesquethawan]) and the Delaware Formation (Middle Devonian early Givetian [Cazenovian]) of central Ohio are separated by disconformities of the magnitude of paracontinuities. Stauffer (1909) divided the Columbus Limestone into zones A--H and the Delaware Formation into zones I--M. Within the Columbus, the A Zone (conglomerate at the base of Bellepoint Member) disconformably overlies Late Silurian beds. The D zone at top of the Bellepoint Member (bearing the Kawkawlin Metabentonite horizon) is overlain paracontinuously by the Marblehead Member (Lower Paraspirifer acuminatus-Spirifer macrothyris to Brevispirifer gregarius-Moellerina greeneimore » zones [= E--G zones]), with the Onondagan Indian Nation Metabentonite in the top of the G Zone. The Marblehead Member is overlain paracontinuously by a bone bed at base of the Venice Member (H zone = Upper Paraspirifer acuminatus- Spirifer duodenarius'' Zone). I Zone (Dublin Shale=Marcellus) of the Delaware Formation overlies the Columbus and has two bone beds at its base; Tioga Metabentonite (restricted) overlies the I Zone bone beds and is a few tenths to 1.85 feet above the base of the I Zone. Paracontinuities and bone beds occur at the bases of J, K, and L zones. Conkin and Conkin (1975) have shown Stauffer's (1909) M Zone is an extension of his L Zone. The Olentangy paracontinuously overlies the L Zone.« less
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Hanson, Richard E.; Girty, Gary H.; Harwood, David S.; Schweickert, Richard A.
2000-01-01
This field trip provides an overview of the stratigraphic and structural evolution of the northern Sierra terrane, which forms a significant part of the wall rocks on the western side of the later Mesozoic Sierra Nevada batholith in California. The terrane consists of a pre-Late Devonian subduction complex (Shoo Fly Complex) overlain by submarine arc-related deposits that record the evolution of three separate island-arc systems in the Late Sevonian-Early Mississippian, Permian, and Late Triassic-Jurassic. The two Paleozoic are packages and the underlying Shoo Fly Complex have an important bearing on plate-tectonic processes affecting the convergent margin outboard of the Paleozoic Cordilleran miogeocline, although their original paleogeographic relations to North America are controversial. The third arc package represents an overlap assemblage that ties the terrane to North America by the Late Triassic and helps constrain the nature and timing of Mesozoic orogenesis. Several of the field-trip stops examine the record of pre-Late Devonian subduction contained in the Shoo Fly Complex, as well as the paleovolcanology of the overlying Devonian to Jurassic arc rocks. Excellent glaciated exposures provide the opportunity to study a cross section through a tilted Devonian volcano-plutonic association. Additional stops focus on plutonic rocks emplaced during the Middle Jurassic arc magmatism in the terrane, and during the main pulse of Cretaceous magmatism in the Sierra Nevada batholith to the east.
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78 FR 49493 - Combined Notice of Filings #1
Federal Register 2010, 2011, 2012, 2013, 2014
2013-08-14
... Company, Potomac Electric Power Company, Pepco Energy Services, Inc., Bethlehem Renewable Energy, LLC, Eastern Landfill Gas, LLC, Potomac Power Resources, Inc., Fauquier Landfill Gas, LLC. Description...
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Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte
Matsunaga, Kelly K. S.; Tomescu, Alexandru M. F.
2016-01-01
Background and Aims The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Methods Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian–Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. Key Results The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. Conclusions This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant–substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. PMID:26921730
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NASA Astrophysics Data System (ADS)
Qiu, Wenhong Johnson; Zhou, Mei-Fu; Liu, Zerui Ray
2018-05-01
SEDEX sulfide deposits hosted in black shale and carbonate are common in the South China Block. The Dajiangping pyrite deposit is the largest of these deposits and is made up of stratiform orebodies hosted in black shales. Sandstone interlayered with stratiform orebodies contains detrital zircon grains with the youngest ages of 429 Ma. Pyrite from the orebodies has a Re-Os isochron age of 389 ± 62 Ma, indicative of formation of the hosting strata and syngenetic pyrite ores in the mid-late Devonian. The hosting strata is a transgression sequence in a passive margin and composed of carbonaceous limestone in the lower part and black shales in the upper part. The ore-hosting black shales have high TOC (total organic carbon), Mo, As, Pb, Zn and Cd, indicating an anoxic-euxinic deep basin origin. The high redox proxies, V/(V + Ni) > 0.6 and V/Cr > 1, and the positive correlations of TOC with Mo and V in black shales are also consistent with an anoxic depositional environment. The Dajiangping deposit is located close to the NE-trending Wuchuan-Sihui fault, which was active during the Devonian. The mid-late Devonian mineralization age and the anoxic-euxinic deep basinal condition of this deposit thus imply that the formation of this deposit was causally linked to hydrothermal fluid exhalation in an anoxic fault-bounded basin that developed in a carbonate platform of the South China Block. The regional distribution of many Devonian, stratiform, carbonaceous sediment-hosted sulfide deposits along the NE-trending fault-bounded basins in South China, similar to the Dajiangping deposit, indicates that these deposits formed at a basin developed in the passive margin setting of the South China Block during the Devonian. This environment was caused by the break-up and northward migration of the South China Block from Gandwana.
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NASA Astrophysics Data System (ADS)
Zwing, A.; Clauer, N.; Liewig, N.; Bachtadse, V.
2009-06-01
This study combines mineralogical, chemical (rare earth elemental (REE)) and isotopic (K-Ar) data of clay minerals as well as chemical compositions (major and REE) of Fe oxide leachates from remagnetized Palaeozoic sedimentary rocks from NE Rhenish Massif in Germany, for which the causes of remagnetization are not yet clear. The dominant carrier of the syntectonic, pervasive Carboniferous magnetization is magnetite. The Middle Devonian clastic rocks record an illitization event at 348 ± 7 Ma probably connected to a major magmatic event in the Mid-German Crystalline Rise, whereas a second illitization episode at 324 ± 3 Ma is coeval to the northward migrating deformation through the Rhenish Massif, being only detected in Upper Devonian and Lower Carboniferous rocks. The age of that younger illitization is not significantly different from that of the remagnetization, which, however, is not restricted to the upper part of the orogenic belt, but affects also the Middle Devonian strata. The REE patterns of the Fe-enriched leachates support two mineralization episodes with varied oxidation-reduction conditions outlined by varied Eu and Ce anomalies. This is not compatible with a unique, pervasive migration of orogenic fluids on a regional scale to explain the remagnetization in the studied region. While clay diagenesis and remagnetization are time-equivalent in Upper Devonian and Lower Carboniferous rocks, they are not so in Middle Devonian rocks. Transformation of smectite into illite cannot, therefore, account for the growth of associated authigenic magnetite, which must have been triggered by a different process. Since remagnetization and deformation ages are similar, the mechanism could relate to local physical conditions such as pressure solution and changing pore fluid pressure due to tectonic stress as well as to chemical conditions such as changing composition of the pore fluids.
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NASA Astrophysics Data System (ADS)
Broughton, Paul L.
2013-01-01
The sub-Cretaceous paleotopography underlying giant Lower Cretaceous Athabasca oil sands, northern Alberta, has an orthogonal lattice pattern of troughs up to 50 km long and 100 m deep between pairs of cross-cutting lineaments. These structures are interpreted to have been inherited from a similar pattern of dissolution collapse-subsidence troughs in the underlying Middle Devonian salt beds. Removal of more than 100 m of halite salt fragmented the overlying Upper Devonian strata into fault blocks and collapse breccias that subsided into the underlying dissolution troughs. The unusually low 1:2 to 1:3 thickness ratios of halite salts to the overlying strata resulted in the Upper Devonian strata collapse-subsidence into underlying salt dissolution troughs being more cataclysmic during the first phase of salt removal. The second phase of slower but complete salt removal between the earlier troughs resulted in a more gradual subsidence of the overlying strata. This obliterated the earlier pattern of giant cross-cutting dissolution troughs bounded by major lineaments. The collapse breccia fabrics underlying the earlier troughs differ from those from areas between the troughs. Collapse breccias underlying the large troughs often have crushed fabrics distributed in zones that rapidly pinched out between fault blocks. Breccias between troughs developed as giant mosaics of detached carbonate blocks that formed breccia pipe complexes. Multiple sinkholes up to 100 m deep aligned along multi-km linear valley trends that dissected the sub-Cretaceous paleotopography. These sinkhole trends formed orthogonal patterns inherited from underlying lattice of NW-SE and NE-SW salt structured lineaments. These cross-cutting sinkhole trends have a smaller 5 km scale reticulate pattern similar to the giant 50 km scale pattern of collapse-subsidence troughs. Other sinkholes developed as lower McMurray strata sagged when underlying Devonian fault blocks and breccia pipes differentially subsided.
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NASA Astrophysics Data System (ADS)
Manton, Ryan J.; Buckman, Solomon; Nutman, Allen P.; Bennett, Vickie C.
2017-08-01
Early Paleozoic intra-oceanic terranes crop out along the Peel-Manning Fault System, in the southern New England Orogen, NSW Australia. These are the Cambrian ophiolitic Weraerai terrane and the Siluro-Devonian island arc Gamilaroi terrane. There has been debate whether these terranes formed at the Gondwana margin or if they are intra-oceanic, and were accreted to Gondwana later in the Paleozoic. Major-trace-REE elemental data indicate Weraerai terrane formed in a supra-subduction environment. Rare zircons extracted from Weraerai terrane gabbro-plagiogranite suites at Barry Station yield a U-Pb zircon date of 504.9 ± 3.5 Ma with initial εHf values of + 11.1 indicating a juvenile source. Amphibole-bearing felsic dykes and net-vein complexes are also found within the gabbro with a U-Pb zircon date of 503.2 ± 5.7 Ma and initial εHf values of + 11.6. These are coeval in age with their host rocks and we propose they represent partial melts of the mafic crust during the circulation of seawater. The Gamilaroi trondhjemites of prehnite-pumpellyite-greenschist metamorphic grade terrane yielded very few zircons with an age of 413 ± 8.7 Ma. Zircon initial εHf values range from + 5.0 to + 2.9, indicating an input from an evolved crustal source, unlike the purely oceanic Weraerai terrane. Gamilaroi terrane trondhjemites are enriched in LREE have low K2O and K2O/Na2O ratios and strong negative Nb anomalies consistent with supra-subduction zone environments. Multiple subduction zones may well have existed within the Panthalassa Ocean during the early-mid Paleozoic with the Weraerai-Gamilaroi being accreted onto the Gondwanan margin during the latest Devonian.
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Composition, Age, and Origin of Cretaceous Granitic Magmatism on the Eastern Chukchi Peninsula
NASA Astrophysics Data System (ADS)
Luchitskaya, M. V.; Sokolov, S. D.; Pease, V.; Miller, E.; Belyatsky, B. V.
2018-05-01
New geochronological and isotopic geochemical data are given, which make it possible to recognize two types of granitic rocks on the eastern Chukchi Peninsula. Early Cretaceous Tkachen and Dolina granitic plutons with zircon ages (U-Pb SIMS) of 119-122 and 131-136 Ma are related to the first type. They cut through Devonian-Lower Carboniferous basement rocks and are overlain by the Aptian-Albian Etelkuyum Formation. Basal units of the latter contain fragments of granitic rocks. Late Cretaceous Provideniya and Rumilet granitic plutons, which contain zircons with ages of 94 and 85 Ma (U-Pb SIMS), respectively, belong to the second type. They cut through volcanic-sedimentary rocks of the Etelkuyum and Leurvaam formations pertaining to the Okhotsk-Chukotka Volcanic Belt. In petrographic and geochemical features, the Early Cretaceous granitic rocks of the Tkachen Pluton are commensurable with I-type granites, while Late Cretaceous granite of the Rumilet Pluton is comparable to A2-type granite. The Sr-Nd isotopic data provide evidence that from the Early Cretaceous Tkachen and Dolina plutons to the Late Cretaceous Provideniya and Rumilet plutons, the degree of crustal assimilation of suprasubduction mantle-derived melts increases up to partial melting of heterogeneous continental crust enriched in rubidium. An unconformity and various degrees of secondary alteration of volcanic-sedimentary rocks have been established in the Okhotsk-Chukotka Volcanic Belt, and this was apparently caused by transition of the tectonic setting from suprasubduction to a transform margin with local extension.
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Coburn, T.C.; Freeman, P.A.; Attanasi, E.D.
2012-01-01
The primary objectives of this research were to (1) investigate empirical methods for establishing regional trends in unconventional gas resources as exhibited by historical production data and (2) determine whether or not incorporating additional knowledge of a regional trend in a suite of previously established local nonparametric resource prediction algorithms influences assessment results. Three different trend detection methods were applied to publicly available production data (well EUR aggregated to 80-acre cells) from the Devonian Antrim Shale gas play in the Michigan Basin. This effort led to the identification of a southeast-northwest trend in cell EUR values across the play that, in a very general sense, conforms to the primary fracture and structural orientations of the province. However, including this trend in the resource prediction algorithms did not lead to improved results. Further analysis indicated the existence of clustering among cell EUR values that likely dampens the contribution of the regional trend. The reason for the clustering, a somewhat unexpected result, is not completely understood, although the geological literature provides some possible explanations. With appropriate data, a better understanding of this clustering phenomenon may lead to important information about the factors and their interactions that control Antrim Shale gas production, which may, in turn, help establish a more general protocol for better estimating resources in this and other shale gas plays. ?? 2011 International Association for Mathematical Geology (outside the USA).
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Basin-mountain structures and hydrocarbon exploration potential of west Junggar orogen in China
NASA Astrophysics Data System (ADS)
Wu, Xiaozhi; He, Dengfa; Qi, Xuefeng
2016-04-01
Situated in northern Xinjiang, China, in NE-SW trend, West Junggar Orogen is adjacent to Altai fold belt on the north with the Ertix Fault as the boundary, North Tianshan fold belt on the south with the Ebinur Lake Strike-slip Fault as the boundary, and the Junggar Basin on the southeast with Zaire-Genghis Khan-Hala'alat fold belt as the boundary. Covering an area of about 10×104 km2 in China, there are medium and small intermontane basins, Burqin-Fuhai, Tacheng, Hefeng and Hoxtolgay, distributing inside the orogen. Tectonically West Junggar Orogen lies in the middle section of the Palaeo-Asian tectonic domain where the Siberia, Kazakhstan and Tarim Plates converge, and is the only orogen trending NE-SW in the Palaeo-Asian tectonic domain. Since the Paleozoic, the orogen experienced pre-Permian plate tectonic evolution and post-Permian intra-plate basin evolution. Complex tectonic evolution and multi-stage structural superimposition not only give rise to long term controversial over the basin basement property but also complex basin-mountain coupling relations, structures and basin superimposition modes. According to analysis of several kinds of geological and geophysical data, the orogen was dominated by compressive folding and thrust napping from the Siberia plate in the north since the Late Paleozoic. Compressive stress weakened from north to south, corresponding to subdued vertical movement and enhanced horizontal movement of crustal surface from north to south, and finally faded in the overthrust-nappe belt at the northwest margin of the Junggar Basin. The variation in compressive stress is consistent with the surface relief of the orogen, which is high in the north and low in the south. There are two kinds of basin-mountain coupling relationships, i.e. high angle thrusting and overthrusting and napping, and two kinds of basin superimposition modes, i.e. inherited and progressive, and migrating and convulsionary modes. West Junggar orogen has rich oil and gas shows, and oil and gas fields have also been discovered in the Zaysan Basin in adjacent Kazakhstan and in adjacent Junggar, Tuha and Santanghu Basins. Drilling data, geochemical analysis of outcrop data, and the disection of ancient Bulongguoer oil reservoir at the south margin of the Hefeng Basin show there developed two sets of good transitional source rocks, the lower Hujierste Formation in the Middle Devonian (D2h1) and the Hebukehe Formation in the Upper Devonian and Lower Carboniferous (D3-C1h) in this area, which, 10 to 300 m thick, mainly distribute in the shoal water zone along Tacheng-Ertai Late Paleozoic island arc belt. Reservoirs were mainly formed in the Jurassic and then adjusted in two periods, one from the end of the Jurassic to middle Cretaceous and the other in early Paleogene. Those early oil reservoirs might be destroyed in areas such as Bulongguoer with poor preservation conditions, but in an area with good geologic and preserving conditions, oil and gas might accumulate again to form new reservoirs. Therefore, a potential Middle Devonian-Lower Carboniferous petroleum system may exist in Tacheng-Ertai island arc belt, which may become a new domain for exploration, north faulted fold belt in the Heshituoluogai basin, and Hongyan fault bench zone in north Ulungur Depression in the Junggar Basin are promising areas for hydrocarbon exploration.
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76 FR 537 - Eurasian Oil and Gas Suppliers Mission to Almaty, Kazakhstan Ankara and Istanbul Turkey
Federal Register 2010, 2011, 2012, 2013, 2014
2011-01-05
... gas drilling and production equipment and services; Turbines, compressors and pumps for pipeline...,300 km NABUCCO natural gas pipeline will link Caspian and Middle Eastern suppliers through Turkey to... Interconnector (ITGI) and Trans Adriatic Pipeline (TAP). In addition to oil and gas exploration and production...
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Water Resources and Natural Gas Production from the Marcellus Shale
Soeder, Daniel J.; Kappel, William M.
2009-01-01
The Marcellus Shale is a sedimentary rock formation deposited over 350 million years ago in a shallow inland sea located in the eastern United States where the present-day Appalachian Mountains now stand (de Witt and others, 1993). This shale contains significant quantities of natural gas. New developments in drilling technology, along with higher wellhead prices, have made the Marcellus Shale an important natural gas resource. The Marcellus Shale extends from southern New York across Pennsylvania, and into western Maryland, West Virginia, and eastern Ohio (fig. 1). The production of commercial quantities of gas from this shale requires large volumes of water to drill and hydraulically fracture the rock. This water must be recovered from the well and disposed of before the gas can flow. Concerns about the availability of water supplies needed for gas production, and questions about wastewater disposal have been raised by water-resource agencies and citizens throughout the Marcellus Shale gas development region. This Fact Sheet explains the basics of Marcellus Shale gas production, with the intent of helping the reader better understand the framework of the water-resource questions and concerns.
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Genetic features of petroleum systems in rift basins of eastern China
Qiang, J.; McCabe, P.J.
1998-01-01
Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes nevessary for a petroleum system. A four stage evolution model is suggested for the controls in the rift basin. A rift basin may consist of sub-basins, depressions, sub-depressions, and major, moderate, and minor uplifts. A depression or sub-depression has its own depocentre (mainly occupied by source rock) and all kinds of lacustrine sediments, and thus has all the essential elements of a petroleum system. However, only those depressions or sub-depressions which are rich in organic matter and deeply buried to generate oil and gas form petroleum systems. Immature oil, another characteristic, complicates the petroleum system in the rift basins. Three types of oil and gas habitats are described as a result of this analysis of the petroleum systems of the 26 largest oil and gas fields discovered in eastern China rift basins: uplifts between oil source centres are the most prospective areas for oil and gas accumulations, slopes connecting oil source centres and uplifts are the second, and the third type is subtle traps in the soil source centre.Most oil-bearing basins in eastern China are Mesozoic-Cenozoic continental rifts which have played a habitat for oil and gas in China. Investigation of the petroleum systems may give a better understanding of the oil and gas habitats in these basins. Of the essential elements of the petroleum system, the source rock is the most important in rift basins. However, rift tectonic evolution controls all the essential elements and processes necessary for a petroleum system. A four stage evolution model is suggested for the controls in the rift basin. A rift basin may consist of sub-basins, depressions, sub-depressions, and major, moderate, and minor uplifts. A depression or sub-depression has its own depocentre (mainly occupied by source rock) and all kinds of lacustrine sediments, and thus has all the essential elements of a petroleum system. However, only those depressions or sub-depressions which are rich in organic matter and deeply buried to generate oil and gas form petroleum systems. Immature oil, another characteristic, complicates the petroleum system in the rift basins. Three types of oil and gas habitats are described as a result of this analysis of the petroleum systems of the 26 largest oil and gas fields discovered in eastern China rift basins: uplifts between oil source centres are the most prospective areas for oil and gas accumulations, slopes connecting oil source centres and uplifts are the second, and the third type is subtle traps in the oil source centre.
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Higley, Debra K.
2011-01-01
In 2010 the U.S. Geological Survey assessed undiscovered oil and gas resources for the Anadarko Basin Province of Colorado, Kansas, Oklahoma, and Texas. The assessment included three continuous (unconventional) assessment units (AU). Mean undiscovered resources for the (1) Devonian Woodford Shale Gas AU are about 16 trillion cubic feet of gas (TCFG) and 192 million barrels of natural gas liquids (MMBNGL), (2) Woodford Shale Oil AU are 393 million barrels of oil (MMBO), 2 TCFG, and 59 MMBNGL, and (3) Pennsylvanian Thirteen Finger Limestone-Atoka Shale Gas AU are 6.8 TCFG and 82 MMBNGL. The continuous gas AUs are mature for gas generation within the deep basin of Oklahoma and Texas. Gas generation from the Woodford Shale source rock started about 335 Ma, and from the Thirteen Finger Limestone-Atoka Shale AU about 300 Ma. Maturation results are based on vitrinite reflectance data, and on 1D and 4D petroleum system models that calculated vitrinite reflectance (Ro), and Rock-Eval and hydrous pyrolysis transformation (HP) ratios through time for petroleum source rocks. The Woodford Shale Gas AU boundary and sweet spot were defined mainly on (1) isopach thickness from well-log analysis and published sources; (2) estimated ultimate recoverable production from existing, mainly horizontal, wells; and (3) levels of thermal maturation. Measured and modeled Ro ranges from about 1.2% to 5% in the AU, which represents marginally mature to overmature for gas generation. The sweet spot included most of the Woodford that was deposited within eroded channels in the unconformably underlying Hunton Group. The Thirteen Finger Limestone-Atoka Shale Gas AU has no known production in the deep basin. This AU boundary is based primarily on the gas generation window, and on thickness and distribution of organic-rich facies from these mainly thin shale and limestone beds. Estimates of organic richness were based on well-log signatures and published data.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Anderson, A.V.; Coney, P.J.
1987-11-01
Late Devonian sandstone beds are exposed as allochthonous sequences that extend for over 1000 km along the east-west strike of the Brooks Range in northern Alaska. These horizons, at least in part, record Late Devonian tectonism and deposition along the southern margin of the Arctic Alaska block. This study identifies clastic petrofacies in the western Philip Smith Mountains and southern Arctic quadrangles and infers the composition of the source terrane. The paleogeography is not known and the original distribution of lithofacies is uncertain, owing to the extensive post-depositional tectonism. In the study area the sandstones are exposed along rugged mountainmore » tops and high ridges. Although exposures are excellent, access is often difficult. Samples were collected from exposures near the western end of the Chandalar Shelf, Atigun Pass, and the Atigun River valley in the Philip Smith Mountains quadrangle and from the Crow Nest Creek and Ottertail Creek areas in the Arctic quadrangle. 34 refs., 17 figs.« less
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Emsian synorogenic paleogeography of the Maine Applachians
Bradley, D.; Tucker, R.
2002-01-01
The Acadian deformation front in the northern Appalachians of Maine and New Hampshire can now be closely located during the early Emsian (Early Devonian; 408-406 Ma). Tight correlations between paleontologically and isotopically dated rocks are possible only because of a new 408-Ma time scale tie point for the early Emsian. The deformation front lay between a belt of Lower Devonian flysch and molasse that were deposited in an Acadian foreland basin and had not yet been folded and a belt of early Emsian plutons that intruded folded Lower Devonian rocks. This plutonic belt includes the newly dated Ore Mountain gabbro (U/Pb; 406 Ma), which hosts magmatic-sulfide mineralization. Along the deformation front, a 407-Ma pluton that locally truncates Acadian folds (Katahdin) was the feeder to volcanic rocks (Traveler Rhyolite; 406-407 Ma) that are part of the foreland-basin succession involved in these same folds. The Emsian igneous rocks thus define a syncollisional magmatic province that straddled the deformation front. These findings bear on three alternative subduction geometries for the Acadian collision.
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Wangshangkia, a new Devonian ostracod genus from Dushan of Guizhou, South China
NASA Astrophysics Data System (ADS)
Song, Junjun; Gong, Yiming
2018-02-01
Wangshangkia, a new genus of Ostracoda, from the Late Devonian in Dushan of Guizhou, South China, is described. This genus belongs to the family Bairdiocyprididae Shaver, 1961 and includes two new species, i.e. Wangshangkia dushaniensis and W. bailouiensis. The new genus is characterized by a wide ventral carina with radial striae. It is reported from the Famennian of South China and disappeared just below the Devonian-Carboniferous boundary. Wangshangkia is essentially a benthic crawler and is restricted to the shallow-marine depositional environment with a low hydrodynamic condition. Wangshangkia: urn:lsid:zoobank.org:act:34BF01D4-D202-492D-8E27-BC508EF7EFFB W. dushaniensis: urn:lsid:zoobank.org:act:D267C362-7510-4D19-996B-EA1848D7D025 W. bailouiensis: urn:lsid:zoobank.org:act:FE988AA0-7363-4D9E-A5AB-1526C8DBCDD9
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NASA Astrophysics Data System (ADS)
Fernández-Remolar, David C.; Harir, Mourad; Carrizo, Daniel; Schmitt-Kopplin, Philippe; Amils, Ricardo
2018-03-01
The geological materials produced during catastrophic and destructive events are an essential source of paleobiological knowledge. The paleobiological information recorded by such events can be rich in information on the size, diversity, and structure of paleocommunities. In this regard, the geobiological study of late Devonian organic matter sampled in Tharsis (Iberian Pyrite Belt) provided some new insights into a Paleozoic woodland community, which was recorded as massive sulfides and black shale deposits affected by a catastrophic event. Sample analysis using TOF-SIMS (Time of Flight Secondary Ion Mass Spectrometer), and complemented by GC/MS (Gas Chromatrograph/Mass Spectrometer) identified organic compounds showing a very distinct distribution in the rock. While phytochemical compounds occur homogeneously in the sample matrix that is composed of black shale, the microbial-derived organics are more abundant in the sulfide nodules. The cooccurrence of sulfur bacteria compounds and the overwhelming presence of phytochemicals provide support for the hypothesis that the formation of the massive sulfides resulted from a high rate of vegetal debris production and its oxidation through sulfate reduction under suboxic to anoxic conditions. A continuous supply of iron from hydrothermal activity coupled with microbial activity was strictly necessary to produce this massive orebody. A rough estimate of the woodland biomass was made possible by accounting for the microbial sulfur production activity recorded in the metallic sulfide. As a result, the biomass size of the late Devonian woodland community was comparable to modern woodlands like the Amazon or Congo rainforests.
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76 FR 55894 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-09-09
.... Eastern Time on Tuesday, September 13, 2011. Docket Numbers: RP11-2544-000. Applicants: Granite State Gas Transmission, Inc. Description: Granite State Gas Transmission, Inc. submits tariff filing per 154.203...
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NASA Astrophysics Data System (ADS)
Perkone, E.; Delina, A.; Saks, T.; Raga, B.; Jātnieks, J.; Klints, I.; Popovs, K.; Babre, A.; Bikše, J.; Kalvāns, A.; Retike, I.; Ukass, J.
2012-04-01
Carbonate aquifers show a very wide range of hydrogeological characteristics. Carbonate rock hydrogeology display two extremes: on one hand hydrogeological properties of the carbonates are governed by the pathways of the preferential groundwater flow typical in karstic regions, on the other - some carbonate aquifers behave almost like a homogeneous, isotropic, porous medium. Most lie between these extremes, but these case variations complicates the study of carbonate aquifer properties. In this study the results of the hydraulic conductivity in carbonate aquifers measurements, hydraulic conductivity correlation between sediments lithology and the aquifer surface depth and fractures research is presented. Upper Devonian Frasnian stage Pļaviņu and Daugava carbonate aquifers in the Latvian part of the Baltic basin is considered. The aim of this research is to elaborate characteristic hydraulic conductivity values for each aquifer based on existing data of the pumping test results and other aquifer properties. Pļaviņu and Daugava carbonate aquifers mainly consist of jointed dolomite with intermediate layers of dolomitic marlstone, limestone, clays and gypsum. These aquifers are prevalent in most of the study area, except Northern and South - Eastern parts of the territory. In geological structure Daugava aquifer lies above Pļaviņu aquifer. Daugava aquifer depth changes from 10 - 20 and even less meters in Eastern part to 250 - 300 m in South - West part of study area, but thickness varies from few meters to 30 m. Pļaviņu aquifer surface depth varies from 20 - 30 m, but in uplands surface depth reaches more than 120 m, in Eastern part to more than 300 m in South - West part of study area. Aquifer average thickness varies from 20 - 40 m, but in areas with buried valleys thickness can be less than 10 meters. Outcrops of these sediments are occurring in banks of largest rivers and in some areas aquifers are karstified. In studies of the carbonate aquifers it is very important to take into account the fact that groundwater flow in carbonate aquifers is often almost entirely dependent on jointing and concomitant joint enlargement by dissolution. In this study pumping test results provide a wide range of hydraulic conductivity values, for example in Pļaviņu aquifer hydraulic conductivity varies from 0,03 - 266 m/day but in Daugava aquifer values range from 0,06 - 735 m/day. Pumping test results is provided by Latvian Environment, Geology and Meteorology Centre. Studying average values of hydraulic conductivity there exists a correlation between K and aquifer flat depth - Daugava aquifer, which in geological structure, is located above the Pļaviņu aquifer has higher average K value - 32 m/day, in Pļaviņu aquifer - 27 m/day. Correlative study of the depth and hydraulic conductivity allowed to characterize the mean values as function of the aquifer depth for the regional groundwater flow modelling. This study is supported by the European Social Fund project No. 2009/0212/1DP/1.1.1.2.0/09/APIA/VIAA/060
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Liu, Le; Wang, Deming; Meng, Meicen; Xue, Jinzhuang
2017-06-26
The earliest seed plants in the Late Devonian (Famennian) are abundant and well known. However, most of them lack information regarding the frond system and reconstruction. Cosmosperma polyloba represents the first Devonian ovule in China and East Asia, and its cupules, isolated synangiate pollen organs and pinnules have been studied in the preceding years. New fossils of Cosmosperma were obtained from the type locality, i.e. the Leigutai Member of the Wutong Formation in Fanwan Village, Changxing County, Zhejiang Province, South China. The collection illustrates stems and fronds extensively covered in prickles, as well as fertile portions including uniovulate cupules and anisotomous branches bearing synangiate pollen organs. The stems are unbranched and bear fronds helically. Fronds are dimorphic, displaying bifurcate and trifurcate types, with the latter possibly connected to fertile rachises terminated by pollen organs. Tertiary and quaternary rachises possessing pinnules are arranged alternately (pinnately). The cupule is uniovulate and the ovule has four linear integumentary lobes fused in basal 1/3. The striations on the stems and rachises may indicate a Sparganum-type cortex. Cosmosperma further demonstrates diversification of frond branching patterns in the earliest seed plants. The less-fused cupule and integument of this plant are considered primitive among Devonian spermatophytes with uniovulate cupules. We tentatively reconstructed Cosmosperma with an upright, semi-self-supporting habit, and the prickles along stems and frond rachises were interpreted as characteristics facilitating supporting rather than defensive structures.
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Chapter 1: An overview of the petroleum geology of the Arctic
Spencer, A.M.; Embry, A.F.; Gautier, D.L.; Stoupakova, A.V.; Sorensen, K.
2011-01-01
Nine main petroleum provinces containing recoverable resources totalling 61 Bbbl liquids + 269 Bbbloe of gas are known in the Arctic. The three best known major provinces are: West Siberia-South Kara, Arctic Alaska and Timan-Pechora. They have been sourced principally from, respectively, Upper Jurassic, Triassic and Devonian marine source rocks and their hydrocarbons are reservoired principally in Cretaceous sandstones, Triassic sandstones and Palaeozoic carbonates. The remaining six provinces except for the Upper Cretaceous-Palaeogene petroleum system in the Mackenzie Delta have predominantly Mesozoic sources and Jurassic reservoirs. There are discoveries in 15% of the total area of sedimentary basins (c. 8 ?? 106 km2), dry wells in 10% of the area, seismic but no wells in 50% and no seismic in 25%. The United States Geological Survey estimate yet-to-find resources to total 90 Bbbl liquids + 279 Bbbloe gas, with four regions - South Kara Sea, Alaska, East Barents Sea, East Greenland - dominating. Russian estimates of South Kara Sea and East Barents Sea are equally positive. The large potential reflects primarily the large undrilled areas, thick basins and widespread source rocks. ?? 2011 The Geological Society of London.
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Petroleum potential of the Reggane Basin, Algeria
DOE Office of Scientific and Technical Information (OSTI.GOV)
Boudjema, A.; Hamel, M.; Mohamedi, A.
1990-05-01
The intracratonic Reggane basin is located on the Saharan platform, southwest of Algeria. The basin covers an area of approximately 140,000 km{sup 2}, extending between the Eglab shield in the south and the Ougarta ranges in the north. Although exploration started in the early 1950s, only a few wells were drilled in this basin. Gas was discovered with a number of oil shows. The sedimentary fill, mainly Paleozoic shales and sandstones, has a thickness exceeding 5,000 m in the central part of the basin. The reservoirs are Cambrian-Ordovician, Siegenian, Emsian, Tournaisian, and Visean sandstones with prospective petrophysical characteristics. Silurian Uppermore » Devonian and, to a lesser extent Carboniferous shales are the main source rocks. An integrated study was done to assess the hydrocarbon potential of this basin. Tectonic evolution source rocks and reservoirs distribution maturation analyses followed by kinetic modeling, and hydrogeological conditions were studied. Results indicate that gas accumulations could be expected in the central and deeper part of the basin, and oil reservoirs could be discovered on the basin edge.« less
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Petroleum geology and resources of the North Caspian Basin, Kazakhstan and Russia
Ulmishek, Gregory F.
2001-01-01
The North Caspian basin is a petroleum-rich but lightly explored basin located in Kazakhstan and Russia. It occupies the shallow northern portion of the Caspian Sea and a large plain to the north of the sea between the Volga and Ural Rivers and farther east to the Mugodzhary Highland, which is the southern continuation of the Ural foldbelt. The basin is bounded by the Paleozoic carbonate platform of the Volga-Ural province to the north and west and by the Ural, South Emba, and Karpinsky Hercynian foldbelts to the east and south. The basin was originated by pre-Late Devonian rifting and subsequent spreading that opened the oceanic crust, but the precise time of these tectonic events is not known. The sedimentary succession of the basin is more than 20 km thick in the central areas. The drilled Upper Devonian to Tertiary part of this succession includes a prominent thick Kungurian (uppermost Lower Permian) salt formation that separates strata into the subsalt and suprasalt sequences and played an important role in the formation of oil and gas fields. Shallow-shelf carbonate formations that contain various reefs and alternate with clastic wedges compose the subsalt sequence on the 1 basin margins. Basinward, these rocks grade into deep-water anoxic black shales and turbidites. The Kungurian salt formation is strongly deformed into domes and intervening depressions. The most active halokinesis occurred during Late Permian?Triassic time, but growth of salt domes continued later and some of them are exposed on the present-day surface. The suprasalt sequence is mostly composed of clastic rocks that are several kilometers thick in depressions between salt domes. A single total petroleum system is defined in the North Caspian basin. Discovered reserves are about 19.7 billion barrels of oil and natural gas liquids and 157 trillion cubic feet of gas. Much of the reserves are concentrated in the supergiant Tengiz, Karachaganak, and Astrakhan fields. A recent new oil discovery on the Kashagan structure offshore in the Caspian Sea is probably also of the supergiant status. Major oil and gas reserves are located in carbonate reservoirs in reefs and structural traps of the subsalt sequence. Substantially smaller reserves are located in numerous fields in the suprasalt sequence. These suprasalt fields are largely in shallow Jurassic and Cretaceous clastic reservoirs in salt dome-related traps. Petroleum source rocks are poorly identified by geochemical methods. However, geologic data indicate that the principal source rocks are Upper Devonian to Lower Permian deep-water black-shale facies stratigraphically correlative to shallow-shelf carbonate platforms on the basin margins. The main stage of hydrocarbon generation was probably in Late Permian and Triassic time, during deposition of thick orogenic clastics. Generated hydrocarbons migrated laterally into adjacent subsalt reservoirs and vertically, through depressions between Kungurian salt domes where the salt is thin or absent, into suprasalt clastic reservoirs. Six assessment units have been identified in the North Caspian basin. Four of them include Paleozoic subsalt rocks of the basin margins, and a fifth unit, which encompasses the entire total petroleum system area, includes the suprasalt sequence. All five of these assessment units are underexplored and have significant potential for new discoveries. Most undiscovered petroleum resources are expected in Paleozoic subsalt carbonate rocks. The assessment unit in subsalt rocks with the greatest undiscovered potential occupies the south basin margin. Petroleum potential of suprasalt rocks is lower; however, discoveries of many small to medium size fields are expected. The sixth identified assessment unit embraces subsalt rocks of the central basin areas. The top of subsalt rocks in these areas occurs at depths ranging from 7 to 10 kilometers and has not been reached by wells. Undiscovered resources of this unit did not rec
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NASA Astrophysics Data System (ADS)
Han, Seokyoung; de Jong, Koen; Yi, Keewook
2017-08-01
Sensitive High-Resolution Ion Microprobe (SHRIMP) U-Th-Pb isotopic data of detrital zircons from mature, quartz-rich meta-sandstones are used to constrain possible tectonic affinities and source regions of the rhythmically layered and graded-bedded series in the Yeoncheon Complex (Imjingang Belt) and the correlative Taean Formation. These metamorphic marine turbidite sequences presently occur along the Paleoproterozoic (1.93-1.83 Ga) Gyeonggi Massif, central Korea's main high-grade metamorphic gneiss terrane. Yet, detrital zircons yielded highly similar multimodal age spectra with peaks that do not match the age repartition in these basement rocks, as late (1.9-1.8 Ga) and earliest (∼ 2.5 Ga) Paleoproterozoic detrital modes are subordinate but, in contrast, Paleozoic (440-425 Ma) and Neoproterozoic (980-920 Ma) spikes are prominent, yet the basement essentially lacks lithologies with such ages. The youngest concordant zircon ages in each sample are: 378, 394 and 423 Ma. The maturity of the meta-sandstones and the general roundness of zircons of magmatic signature, irrespective of their age, suggest that sediments underwent considerable transport from source to sink, and possibly important weathering and recycling, which may have filtered out irradiation-weakened metamorphic zircon grains. In combination with these isotopic data, presence of a low-angle ductile fault contact between the Yeoncheon Complex and the Taean Formation and the underlying mylonitized Precambrian basement implies that they are in tectonic contact and do not have a stratigraphic relationship, as often assumed. Consequently, in all likelihood, both meta-sedimentary formations: (1) are at least of early Late Devonian age, (2) received much of their detritus from distant (reworked) Silurian-Devonian and Early Neoproterozoic magmatic sources, not present in the Gyeonggi Massif, (3) and not from Paleoproterozoic crystalline rocks of this massif, or other Korean Precambrian basement terranes, and (4) should be viewed as independent tectonic units that had sources not exposed in Korea. A thorough literature review reveals that the Yeoncheon Complex and the Taean Formation were potentially sourced from the Liuling, Nanwan and Foziling groups in the Qinling-Dabie Belt, which all show very similar detrital zircon age spectra. These immature middle-late Devonian sandstones were deposited in a pro-foreland basin formed as a result of the aborted subduction of the South Qinling Terrane below the North Qinling Terrane, which was uplifted and eroded during post-collision isostatic rebound. The submarine fans where the mature distal turbiditic Yeoncheon and Taean sandstones were deposited may have constituted the eastern terminal part of a routing system originating in the uplifted and eroded middle Paleozoic Qinling Belt and adjacent part of the foreland basin.
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Conventional oil and gas development alters forest songbird communities
Emily H. Thomas; Margaret C. Brittingham; Scott H. Stoleson
2014-01-01
Energy extraction within forest habitat is increasing at a rapid rate throughout eastern North America from the combined presence of conventional oil and gas, shale gas, and wind energy. We examined the effects of conventional oil and gas development on forest habitat including amounts of core and edge forest, the abundance of songbird species and guilds, species...
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Palaeozoic gas charging in the Ahnet-Timimoun basin, Algeria
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cawley, S.J.; Wilson, N.P.; Primmer, T.
1995-08-01
The Ahnet-Timimoun Basin, Southern Algeria, contains significant gas reserves expelled from originally oil prone Silurian and Frasnian shales. The gas is reservoired in Devonian and Carboniferous clastics in inversion anticlines formed, primarily, during the Hercynian orogeny. Integration of organic and inorganic geochemical techniques, such as AFTA, ZFTA, fluid inclusion analysis, vitrinite and chitinizoan reflectance, is entirely consistent with gas generation 300 +/- 30MY, immediately prior to or synchronous with the Hercynian orogeny. Data from gas fields has shown the remobilisation of gas during post Hercynian tectonics. A {open_quotes}two-event{close_quotes} heating/cooling history is proposed: (1) Maximum burial and palaeotemperature at ca. 300more » +/- 30MY prior to or synchronous with Hercynian uplift and cooling. (2) Cooling from a secondary peak (lower than maximum) palaeotemperature at ca. 30-60My following Creataceous burial. Calibrated thermal modelling indicates that Palaeozoic source rocks were heated above 200{degrees}C in the Late Carboniferous. Such high temperatures are consistent with the widespread occurrence of pyrophyllite in Silurian shales. Two end-member thermal models can account for the observed maturities. The first is a constant high Pre-Hercynian heat flow which rapidly decreases during Hercynian uplift to remain at Present day values of 50-75mW/m{sup 2}. Gas expulsion in this case commences much earlier than trap formation. The second is {open_quotes}normal{close_quotes} heat flow of ca. 50mW/m{sup 2} until ca. 310My with a rapid increase at ca. 290My followed by an equally rapid drop to constant present day values - in this model, petroleum generation and expulsion is late in relation to structuring.« less
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Current perspectives on unconventional shale gas extraction in the Appalachian Basin.
Lampe, David J; Stolz, John F
2015-01-01
The Appalachian Basin is home to three major shales, the Upper Devonian, Marcellus, and Utica. Together, they contain significant quantities of tight oil, gas, and mixed hydrocarbons. The Marcellus alone is estimated to contain upwards of 500 trillion cubic feet of natural gas. The extraction of these deposits is facilitated by a combination of horizontal drilling and slick water stimulation (e.g., hydraulic fracturing) or "fracking." The process of fracking requires large volumes of water, proppant, and chemicals as well as a large well pad (3-7 acres) and an extensive network of gathering and transmission pipelines. Drilling can generate about 1,000 tons of drill cuttings depending on the depth of the formation and the length of the horizontal bore. The flowback and produced waters that return to the surface during production are high in total dissolved solids (TDS, 60,000-350,000 mg L(-1)) and contain halides (e.g., chloride, bromide, fluoride), strontium, barium, and often naturally occurring radioactive materials (NORMs) as well as organics. The condensate tanks used to store these fluids can off gas a plethora of volatile organic compounds. The waste water, with its high TDS may be recycled, treated, or disposed of through deep well injection. Where allowed, open impoundments used for recycling are a source of air borne contamination as they are often aerated. The gas may be "dry" (mostly methane) or "wet," the latter containing a mixture of light hydrocarbons and liquids that need to be separated from the methane. Although the wells can produce significant quantities of natural gas, from 2-7 bcf, their initial decline rates are significant (50-75%) and may cease to be economic within a few years. This review presents an overview of unconventional gas extraction highlighting the environmental impacts and challenges.
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Gas hydrate characterization from a 3D seismic dataset in the deepwater eastern Gulf of Mexico
DOE Office of Scientific and Technical Information (OSTI.GOV)
McConnell, Daniel; Haneberg, William C.
Seismic stratigraphic features are delineated using principal component analysis of the band limited data at potential gas hydrate sands, and compared and calibrated with spectral decomposition thickness to constrain thickness in the absence of well control. Layers in the abyssal fan sediments are thinner than can be resolved with 50 Hz seismic and thus comprise composite thin-bed reflections. Amplitude vs frequency analysis are used to indicate gas and gas hydrate reflections. Synthetic seismic wedge models show that with 50Hz seismic data, a 40% saturation of a Plio Pleistocene GoM sand in the hydrate stability zone with no subjacent gas canmore » produce a phase change (negative to positive) with a strong correlation between amplitude and hydrate saturation. The synthetic seismic response is more complicated if the gas hydrate filled sediments overlie gassy sediments. Hydrate (or gas) saturation in thin beds enhances the amplitude response and can be used to estimate saturation. Gas hydrate saturation from rock physics, amplitude, and frequency analysis is compared to saturation derived from inversion at several interpreted gas hydrate accumulations in the eastern Gulf of Mexico.« less
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75 FR 42732 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-22
...: 5 p.m. Eastern Time on Monday, July 26, 2010. Docket Numbers: RP10-967-000. Applicants: Garden Banks Gas Pipeline, LLC. Description: Garden Banks Gas Pipeline, LLC submits tariff filing per 154.203...
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Eastern Europe: USSR aims to improve production
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rigassi, D.A.
1986-08-01
This article details the perspectives for Eastern European petroleum development. Observations include: Oil output in Russia declined 2.6% last year, a drop more than twice as bad as 1984; Gorbachev cleaned house in 1985 after inspecting production problems in West Siberia; USSR exploratory/appraisal drilling the next five years should exceed 1981-85 by 40%; Gas output in USSR for '85 was 57.5 bcfd. A peak of 64 bcfd was reached last February; Poland hit a major offshore oil and gas find in the Baltic Sea during October 1985; Cash-short Yugoslavia plans to develop Ivana offshore gas field in the Adriatic Sea;more » Faced with stumbling domestic oil production, Romania turns to the USSR to fill the gap; Gas production in Hungary may drop despite added production from new and old fields.« less
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Tucci, Patrick; McKay, Robert M.
2006-01-01
The greatest limitation to the model is the lack of measured or estimated water-budget components for comparison to simulated water-budget components. Because the model is only calibrated to measured water levels, and not to water-budget components, the model results are nonunique. Other model limitations include the relatively coarse grid scale, lack of detailed information on pumpage from the quarry and from private developments and domestic wells, and the lack of separate water-level data for the Silurian- and Devonian-age rocks.
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1. GENERAL VIEW OF EASTERN BEEHIVE BRICK, SAN ANTONIO, TEXAS. ...
1. GENERAL VIEW OF EASTERN BEEHIVE BRICK, SAN ANTONIO, TEXAS. KILNS 1A, 2A, 3A, AND 4A IN FOREGROUND. GAS VALVE AND METERING HOUSE TO LEFT OF PICTURE. - Jenkins Brick Company, Plant No. 2, Furnace Street, Montgomery, Montgomery County, AL
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Mao, J.; Goldfarb, R.J.; Wang, Y.; Hart, C.J.; Wang, Z.; Yang, J.
2005-01-01
The East Tianshan is a remote Gobi area located in eastern Xinjiang, northwestern China. In the past several years, a number of gold, porphyry copper, and Fe(-Cu) and Cu-Ag-Pb-Zn skarn deposits have been discovered there and are attracting exploration interest. The East Tianshan is located between the Junggar block to the north and early Paleozoic terranes of the Middle Tianshan to the south. It is part of a Hercynian orogen with three distinct E-W-trending tectonic belts: the Devonian-Early Carboniferous Tousuquan-Dananhu island arc on the north and the Carboniferous Aqishan - Yamansu rift basin to the south, which are separated by rocks of the Kanggurtag shear zone. The porphyry deposits, dated at 322 Ma, are related to the late evolutionary stages of a subduction-related oceanic or continental margin arc. In contrast, the skarn, gold, and magmatic Ni-Cu deposits are associated with post-collisional tectonics at ca. 290-270 Ma. These Late Carboniferous - Early Permian deposits are associated with large-scale emplacement and eruption of magmas possibly caused by lithosphere delamination and rifting within the East Tianshan.
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NASA Astrophysics Data System (ADS)
Jirásek, Jakub; Otava, Jiří; Matýsek, Dalibor; Sivek, Martin; Schmitz, Mark D.
2018-03-01
The Březina Formation represents the initiation of siliciclastic flysch turbidite sedimentation at the eastern margin of Bohemian Massif or within the Rhenohercynian foreland basin. Its deposition started after drowning of the Devonian carbonate platform during Viséan (Mississippian) times, resulting in a significant interval of black siliceous shale and variegated fossiliferous shale deposition in a starved basin. Near the top of the Březina Formation an acidic volcanoclastic layer (tuff) of rhyolitic composition has been dated with high precision U-Pb zircon chemical abrasion isotope dilution method at 337.73 ± 0.16 Ma. This new radiometric age correlates with the previously inferred stratigraphic age of the locality and the current calibration of the Early Carboniferous geologic time scale. Shales of the Březina Formation pass gradually upwards into the siliciclastics of the Rozstání Formation of the Drahany culm facies. Thus our new age offers one of the few available radioisotopic constraints on the time of onset of siliciclastic flysch turbidites in the Rhenohercynian foreland basin of the European Variscides.
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Ulmishek, Gregory F.
2001-01-01
Three structural provinces of this report, the Nepa-Botuoba High, the Angara-Lena Terrace, and the Cis-Patom Foredeep, occupy the southeastern part of the Siberian craton northwest of the Baikal-Patom folded region (fig. 1). The provinces are similar in many aspects of their history of development, stratigraphic composition, and petroleum geology characteristics. The sedimentary cover of the provinces overlies the Archean?Lower Proterozoic basement of the Siberian craton. Over most of the area of the provinces, the basement is covered by Vendian (uppermost Proterozoic, 650?570 Ma) clastic and carbonate rocks. Unlike the case in the more northwestern areas of the craton, older Riphean sedimentary rocks here are largely absent and they appear in the stratigraphic sequence only in parts of the Cis-Patom Foredeep province. Most of the overlying sedimentary section consists of Cambrian and Ordovician carbonate and clastic rocks, and it includes a thick Lower Cambrian salt-bearing formation. Younger rocks are thin and are present only in marginal areas. 1 A single total petroleum system (TPS) embraces all three provinces. The TPS is unique in two aspects: (1) its rich hydro-carbon reserves are derived from Precambrian source rocks and (2) preservation of oil and gas fields is extremely long owing to the presence of the Lower Cambrian undeformed salt seal. Discovered reserves of the TPS are about 2 billion barrels of oil and more than 30 trillion cubic feet of gas. The stratigraphic distribution of oil and gas reserves is narrow; all fields are in Vendian to lowermost Cambrian clastic and carbonate reservoirs that occur below Lower Cambrian salt. Both structural and stratigraphic traps are known. Source rocks are absent in the sedimentary cover of the provinces, with the possible exception of a narrow zone on the margin of the Cis-Patom Foredeep province. Source rocks are interpreted here to be Riphean and Vendian organic-rich shales of the Baikal-Patom folded region. These rocks presently are deformed and metamorphosed, but they generated oil and gas before the deformation occurred in Late Silurian and Devonian time. Generated hydrocarbons migrated updip onto the craton margin. The time of migration and formation of fields is constrained by the deposition of Lower Cambrian salt and by the Late Silurian or Devonian metamorphism of source rocks. This time frame indicates that the TPS is one of the oldest petroleum systems in the world. All three provinces are exploration frontiers, and available geologic data are limited; therefore, only one assessment unit has been identified. The largest undiscovered hydrocarbon resources are expected to be in Vendian clastic reservoirs in both structural and stratigraphic traps of the Nepa-Botuoba High province. The petroleum potential of Vendian?lowermost Cambrian carbonate reservoirs is smaller. Nevertheless, these reservoirs may contain significant resources. Gas is expected to dominate over oil in the resource base.
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Kirschbaum, Mark A.; Schenk, Christopher J.; Charpentier, Ronald R.; Klett, Timothy R.; Brownfield, Michael E.; Pitman, Janet K.; Cook, Troy A.; Tennyson, Marilyn E.
2010-01-01
The U.S. Geological Survey estimated means of 1.8 billion barrels of recoverable oil, 223 trillion cubic feet of recoverable gas, and 6 billion barrels of natural gas liquids in the Nile Delta Basin Province using a geology-based assessment methodology.
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NASA Astrophysics Data System (ADS)
Phan, Thai T.; Gardiner, James B.; Capo, Rosemary C.; Stewart, Brian W.
2018-02-01
We investigate sediment sources, depositional conditions and diagenetic processes affecting the Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, a major target of natural gas exploration. Multiple proxies, including trace metal contents, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U isotopes were applied to whole rock digestions and sequentially extracted fractions of the Marcellus shale and adjacent units from two locations in the Appalachian Basin. The narrow range of εNd values (from -7.8 to -6.4 at 390 Ma) is consistent with derivation of the clastic sedimentary component of the Marcellus Shale from a well-mixed source of fluvial and eolian material of the Grenville orogenic belt, and indicate minimal post-depositional alteration of the Sm-Nd system. While silicate minerals host >80% of the REE in the shale, data from sequentially extracted fractions reflect post-depositional modifications at the mineralogical scale, which is not observed in whole rock REE patterns. Limestone units thought to have formed under open ocean (oxic) conditions have δ238U values and REE patterns consistent with modern seawater. The δ238U values in whole rock shale and authigenic phases are greater than those of modern seawater and the upper crust. The δ238U values of reduced phases (the oxidizable fraction consisting of organics and sulfide minerals) are ∼0.6‰ greater than that of modern seawater. Bulk shale and carbonate cement extracted from the shale have similar δ238U values, and are greater than δ238U values of adjacent limestone units. We suggest these trends are due to the accumulation of chemically and, more likely, biologically reduced U from anoxic to euxinic bottom water as well as the influence of diagenetic reactions between pore fluids and surrounding sediment and organic matter during diagenesis and catagenesis.
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NASA Astrophysics Data System (ADS)
Phan, T. T.; Capo, R. C.; Gardiner, J. B.; Stewart, B. W.
2017-12-01
The organic-rich Middle Devonian Marcellus Shale in the Appalachian Basin, eastern USA, is a major target of natural gas exploration. Constraints on local and regional sediment sources, depositional environments, and post-depositional processes are essential for understanding the evolution of the basin. In this study, multiple proxies, including trace metals, rare earth elements (REE), the Sm-Nd and Rb-Sr isotope systems, and U and Li isotopes were applied to bulk rocks and authigenic fractions of the Marcellus Shale and adjacent limestone/sandstone units from two locations separated by 400 km. The range of ɛNd values (-7.8 to -6.4 at 390 Ma) is consistent with a clastic sedimentary component derived from a well-mixed source of fluvial and eolian material of the Grenville orogenic belt. The Sm-Nd isotope system and bulk REE distributions appear to have been minimally affected by post-depositional processes, while the Rb-Sr isotope system shows evidence of limited post-depositional redistribution. While REE are primarily associated with silicate minerals (80-95%), REE patterns of sequentially extracted fractions reflect post-depositional alteration at the intergranular scale. Although the chemical index of alteration (CIA = 54 to 60) suggests the sediment source was not heavily weathered, Li isotope data are consistent with progressively increasing weathering of the source region during Marcellus Shale deposition. δ238U values in bulk shale and reduced phases (oxidizable fraction) are higher than those of modern seawater and upper crust. The isotopically heavy U accumulated in these authigenic phases can be explained by the precipitation of insoluble U in anoxic/euxinic bottom water. Unlike carbonate cement within the shale, the similarity between δ238U values and REE patterns of the limestone units and those of modern seawater indicates that the limestone formed under open ocean (oxic) conditions.
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Root evolution at the base of the lycophyte clade: insights from an Early Devonian lycophyte.
Matsunaga, Kelly K S; Tomescu, Alexandru M F
2016-04-01
The evolution of complex rooting systems during the Devonian had significant impacts on global terrestrial ecosystems and the evolution of plant body plans. However, detailed understanding of the pathways of root evolution and the architecture of early rooting systems is currently lacking. We describe the architecture and resolve the structural homology of the rooting system of an Early Devonian basal lycophyte. Insights gained from these fossils are used to address lycophyte root evolution and homology. Plant fossils are preserved as carbonaceous compressions at Cottonwood Canyon (Wyoming), in the Lochkovian-Pragian (∼411 Ma; Early Devonian) Beartooth Butte Formation. We analysed 177 rock specimens and documented morphology, cuticular anatomy and structural relationships, as well as stratigraphic position and taphonomic conditions. The rooting system of the Cottonwood Canyon lycophyte is composed of modified stems that bear fine, dichotomously branching lateral roots. These modified stems, referred to as root-bearing axes, are produced at branching points of the above-ground shoot system. Root-bearing axes preserved in growth position exhibit evidence of positive gravitropism, whereas the lateral roots extend horizontally. Consistent recurrence of these features in successive populations of the plant preserved in situ demonstrates that they represent constitutive structural traits and not opportunistic responses of a flexible developmental programme. This is the oldest direct evidence for a rooting system preserved in growth position. These rooting systems, which can be traced to a parent plant, include some of the earliest roots known to date and demonstrate that substantial plant-substrate interactions were under way by Early Devonian time. The morphological relationships between stems, root-bearing axes and roots corroborate evidence that positive gravitropism and root identity were evolutionarily uncoupled in lycophytes, and challenge the hypothesis that roots evolved from branches of the above-ground axial system, suggesting instead that lycophyte roots arose as a novel organ. © The Author 2016. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
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Reconstructing the Thermo-tectonic history of the Rwenzori Mountains, D. R. Congo
NASA Astrophysics Data System (ADS)
Mansour, S.; Bauer, F.; Glasmacher, P. D. U. A. A.; Grobe, R. W.; Starz, M.
2014-12-01
The Albertine Rift forms the northern section of the western Rift of the East African Rift System (EARS). The Rwenzori Mtns evolved along the eastern rift shoulder of the Albertine Rift, rising up to form a striking feature within the rift valley with elevations reaching 5109 m a.s.l. While, the scarcity of volcanic activity in the Western Rift has raised questions about the Rwenzori Mtns origin and how this fits into the general evolution of the Albertine Rift and the EARS. Detailed thermochronologic study of Bauer et al., (2013) on the eastern side on Rwenzori Mtns, differentiated it into northern and southern blocks. The northern block cooled faster to ~120 °C in Carboniferous to Permian times. The second cooling event to ~70 °C occurred in Mesozoic time. The third cooling event to surface temperature occurred in the Neogene. While, the southern block shows an earlier onset of cooling at >400 Ma. Temperatures of about 70 °C were reached in Silurian to Devonian times. During this study, 33 samples were collected from the western side of central Rwenzori. Zircon and apatite fission track and (U/Th)-He techniques were applied on these samples. The apatite fission track data could be divided into three age groups; ~45±11, ~25±5, ~12±2 Ma. These results reveal the difference in thermo-tectonic history between the eastern and western flanks of Rwenzori Mtns and support the tilt uplift geometry hypotheses (e.g. Pickford et al., 1993). ReferencesBauer, F.U., Glasmacher, U.A., Ring, U., Karl, M., Schumann, A., Nagudi, B., 2013. Tracing the exhumation history of the Rwenzori Mountains, Albertine Rift, Uganda, using low-temperature thermochronology, Tectonophysics, 599, 8-28. http://dx.doi.org/10.1016/j.tecto.2013.03.032. Pickford, M., Senut, B., Hadoto, D., 1993. Geology and Palaeobiology of the Albertine Rift Valley Uganda-Zaire, vol. 1. Geology. CIFEG Occas, Orleans. Publication, vol. 24, pp. 1-190.
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NASA Astrophysics Data System (ADS)
Sahoo, S. K.; Jin, H.
2017-12-01
The evolution of Earth's biogeochemical cycles is intimately linked to the oxygenation of the oceans and atmosphere. The Late Devonian is no exception as its characterized with mass extinction and severe euxinia. Here we use concentrations of Molybdenum (Mo), Vanadium (V), Uranium (U) and Chromium (Cr) in organic rich black shales from the Lower Bakken Formation of the Williston Basin, to explore the relationship between extensive anoxia vs. euxinia and it's relation with massive release of oxygen in the ocean atmosphere system. XRF data from 4 core across the basin shows that modern ocean style Mo, U and Cr enrichments are observed throughout the Lower Bakken Formation, yet V is not enriched until later part of the formation. Given the coupling between redox-sensitive-trace element cycles and ocean redox, various models for Late Devonian ocean chemistry imply different effects on the biogeochemical cycling of major and trace nutrients. Here, we examine the differing redox behavior of molybdenum and vanadium under an extreme anoxia and relatively low extent of euxinia. The model suggests that Late Devonian was perhaps extensively anoxic- 40-50% compared to modern seafloor area, and a very little euxinia. Mo enrichments extend up to 500 p.p.m. throughout the section, representative of a modern reducing ocean. However, coeval low V enrichments only support towards anoxia, where anoxia is a source of V, and a sink for Mo. Our model suggests that the oceanic V reservoir is extremely sensitive to perturbations in the extent of anoxic condition, particularly during post glacial times.
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Geometry, kinematics and tectonic models of the Kazakhstan Orocline, Central Asian Orogenic Belt
NASA Astrophysics Data System (ADS)
Li, Pengfei; Sun, Min; Rosenbaum, Gideon; Yuan, Chao; Safonova, Inna; Cai, Keda; Jiang, Yingde; Zhang, Yunying
2018-03-01
The Central Asian Orogenic Belt (CAOB) is one of the largest accretionary orogens on Earth and is characterized by the occurrence of tight oroclines (Kazakhstan and Tuva-Mongolian oroclines). The origin of these large-scale orogenic curvatures is not quite understood, but is fundamentally important for understanding crustal growth and tectonic evolution of the CAOB. Here we provide an outline of available geological and paleomagnetic data around the Kazakhstan Orocline, with an aim of clarifying the geometry, kinematics and geodynamic origin of the orocline. The Kazakhstan Orocline is evident in a total magmatic image, and can be traced by the continuation of high magnetic anomalies associated with the Devonian Volcanic Belt and the Late Devonian to Carboniferous Balkhash-Yili arc. Paleomagnetic data show ∼112-126° clockwise rotation of the northern limb relative to the southern limb in the Late Devonian to Early Carboniferous, as well as ∼15-28° clockwise rotation of the northern limb and ∼39-40° anticlockwise rotation of the southern limb relative to the hinge of the orocline during the Late Carboniferous to Permian. We argue that the Kazakhstan Orocline experienced two-stage bending with the early stage of bending (Late Devonian to Early Carboniferous; ∼112-126°) driven by slab rollback, and the later stage (Late Carboniferous to Permian; 54-68°) possibly associated with the amalgamation of the Siberian, Tarim and Baltic cratons. This new tectonic model is compatible with the occurrence of rift basins, the spatial migration of magmatic arc, and the development of large-scale strike-slip fault systems during oroclinal bending.
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New U-Pb zircon ages and the duration and division of Devonian time
Tucker, R.D.; Bradley, D.C.; Ver Straeten, C.A.; Harris, A.G.; Ebert, J.R.; McCutcheon, S.R.
1998-01-01
Newly determined U-Pb zircon ages of volcanic ashes closely tied to biostratigraphic zones are used to revise the Devonian time-scale. They are: 1) 417.6 ?? 1.0 Ma for an ash within the conodont zone of Icriodus woschmidti/I. w. hesperius Lochkovian); 2) 408.3 ?? 1.9 Ma for an ash of early Emsian age correlated with the conodont zones of Po. dehiscens--Lower Po. inversus; 3) 391.4 ?? 1.8 Ma for an ash within the Po. c. costatus Zone and probably within the upper half of the zone (Eifelian); and 4) 381.1 ?? 1.3 Ma for an ash within the range of the Frasnian conodont Palmatolepis punctata (Pa. punctata Zone to Upper Pa. hassi Zone). U-Pb zircon ages for two rhyolites bracketing a palyniferous bed of the pusillites-lepidophyta spore zone, are dated at 363.8 ?? 2.2 Ma and 363 ?? 2.2 Ma and 363.4 ?? 1.8 Ma, respectively, suggesting an age of ~363 Ma for a level within the late Famennian Pa. g. expansa Zone. These data, together with other published zircon ages, suggest that the base and top of the Devonian lie close to 418 Ma and 362 Ma, respectively, thus lengthening the period of ~20% over current estimates. We suggest that the duration of the Middle Devonian (Eifelian and Givitian) is rather brief, perhaps no longer than 11.5 Myr (394 Ma-382.5 Ma), and that the Emsian and Famennian are the longest stages in the period with estimated durations of ~15.5 Myr and 14.5 Myr, respectively.
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Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le
2015-01-01
Background and Aims With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Methods Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. Key Results A new fern-like taxon, Shougangia bella gen. et sp. nov., is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Conclusions Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. PMID:25979918
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Oxygenation history of the Neoproterozoic to early Phanerozoic and the rise of land plants
NASA Astrophysics Data System (ADS)
Wallace, Malcolm W.; Hood, Ashleigh vS.; Shuster, Alice; Greig, Alan; Planavsky, Noah J.; Reed, Christopher P.
2017-05-01
There has been extensive debate about the history of Earth's oxygenation and the role that land plant evolution played in shaping Earth's ocean-atmosphere system. Here we use the rare earth element patterns in marine carbonates to monitor the structure of the marine redox landscape through the rise and diversification of animals and early land plants. In particular, we use the relative abundance of cerium (Ceanom), the only redox-sensitive rare earth element, in well-preserved marine cements and other marine precipitates to track seawater oxygen levels. Our results indicate that there was only a moderate increase in oceanic oxygenation during the Ediacaran (average Cryogenian Ceanom = 1.1, average Ediacaran Ceanom = 0.62), followed by a decrease in oxygen levels during the early Cambrian (average Cryogenian Ceanom = 0.90), with significant ocean anoxia persisting through the early and mid Paleozoic (average Early Cambrian-Early Devonian Ceanom = 0.84). It was not until the Late Devonian that oxygenation levels are comparable to the modern (average of all post-middle Devonian Ceanom = 0.55). Therefore, this work confirms growing evidence that the oxygenation of the Earth was neither unidirectional nor a simple two-stage process. Further, we provide evidence that it was not until the Late Devonian, when large land plants and forests first evolved, that oxygen levels reached those comparable to the modern world. This is recorded with the first modern-like negative Ceanom (values <0.6) occurring at around 380 Ma (Frasnian). This suggests that land plants, rather than animals, are the 'engineers' responsible for the modern fully oxygenated Earth system.
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Chemical characterization of gas- and oil-bearing shales by instrumental neutron activation analysis
Frost, J.K.; Koszykowski, R.F.; Klemm, R.C.
1982-01-01
The concentration of As, Ba, Ca, Co, Cr, Cs, Dy, Eu, Fe, Ga, Hf, K, La, Lu, Mn, Mo, Na, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, and Zn were determined by instrumental neutron activation analysis in block shale samples of the New Albany Group (Devonian-Mississippian) in the in the Illinois Basin. Uranium content of the samples was as high as 75 ppm and interfered in the determination of samarium, molybdenum, barium and cerium. In the determination of selenium a correction was made for interference from tantalum. U, As, Co, Mo, Ni and Sb as well as Cu, V and pyritic sulphur which were determined by other methods, were found to correlate positively with the organic carbon content of the samples. ?? 1982 Akade??miai Kiado??.
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Walsh, Gregory J.; Jahns, Richard H.; Aleinikoff, John N.
2013-01-01
The bedrock geology of the 7.5-minute Nashua South quadrangle consists primarily of deformed Silurian metasedimentary rocks of the Berwick Formation. The metasedimentary rocks are intruded by a Late Silurian to Early Devonian diorite-gabbro suite, Devonian rocks of the Ayer Granodiorite, Devonian granitic rocks of the New Hampshire Plutonic Suite including pegmatite and the Chelmsford Granite, and Jurassic diabase dikes. The bedrock geology was mapped to study the tectonic history of the area and to provide a framework for ongoing hydrogeologic characterization of the fractured bedrock of Massachusetts and New Hampshire. This report presents mapping by G.J. Walsh and R.H. Jahns and zircon U-Pb geochronology by J.N. Aleinikoff. The complete report consists of a map, text pamphlet, and GIS database. The map and text pamphlet are only available as downloadable files (see frame at right). The GIS database is available for download in ESRITM shapefile and Google EarthTM formats, and includes contacts of bedrock geologic units, faults, outcrops, structural geologic information, photographs, and a three-dimensional model.
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76 FR 62830 - Notice of Proposed Reinstatement of Terminated Oil and Gas Lease, Mississippi
Federal Register 2010, 2011, 2012, 2013, 2014
2011-10-11
... DEPARTMENT OF THE INTERIOR Bureau of Land Management [ES-930-1310-FI; MSES 56250] Notice of Proposed Reinstatement of Terminated Oil and Gas Lease, Mississippi AGENCY: Bureau of Land Management... Bureau of Land Management-Eastern States (BLM-ES) received a petition for reinstatement of oil and gas...
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Karl, Susan M.; Layer, Paul W.; Harris, Anita G.; Haeussler, Peter J.; Murchey, Benita L.
2011-01-01
The Cannery Formation consists of green, red, and gray ribbon chert, siliceous siltstone, graywacke-chert turbidites, and volcaniclastic sandstone. Because it contains early Permian fossils at and near its type area in Cannery Cove, on Admiralty Island in southeastern Alaska, the formation was originally defined as a Permian stratigraphic unit. Similar rocks exposed in Windfall Harbor on Admiralty Island contain early Permian bryozoans and brachiopods, as well as Mississippian through Permian radiolarians. Black and green bedded chert with subordinate lenses of limestone, basalt, and graywacke near Kake on Kupreanof Island was initially correlated with the Cannery Formation on the basis of similar lithology but was later determined to contain Late Devonian conodonts. Permian conglomerate in Keku Strait contains chert cobbles inferred to be derived from the Cannery Formation that yielded Devonian and Mississippian radiolarians. On the basis of fossils recovered from a limestone lens near Kake and chert cobbles in the Keku Strait area, the age of the Cannery Formation was revised to Devonian and Mississippian, but this revision excludes rocks in the type locality, in addition to excluding bedded chert on Kupreanof Island east of Kake that contains radiolarians of Late Pennsylvanian and early Permian age. The black chert near Kake that yielded Late Devonian conodonts is nearly contemporaneous with black chert interbedded with limestone that also contains Late Devonian conodonts in the Saginaw Bay Formation on Kuiu Island. The chert cobbles in the conglomerate in Keku Strait may be derived from either the Cannery Formation or the Saginaw Bay Formation and need not restrict the age of the Cannery Formation, regardless of their source. The minimum age of the Cannery Formation on both Admiralty Island and Kupreanof Island is constrained by the stratigraphically overlying fossiliferous Pybus Formation, of late early and early late Permian age. Because bedded radiolarian cherts on both Admiralty and Kupreanof Islands contain radiolarians as young as Permian, the age of the Cannery Formation is herein extended to Late Devonian through early Permian, to include the early Permian rocks exposed in its type locality. The Cannery Formation is folded and faulted, and its stratigraphic thickness is unknown but inferred to be several hundred meters. The Cannery Formation represents an extended period of marine deposition in moderately deep water, with slow rates of deposition and limited clastic input during Devonian through Pennsylvanian time and increasing argillaceous, volcaniclastic, and bioclastic input during the Permian. The Cannery Formation comprises upper Paleozoic rocks in the Alexander terrane of southeastern Alaska. In the pre-Permian upper Paleozoic, the tectonic setting of the Alexander terrane consisted of two or more evolved oceanic arcs. The lower Permian section is represented by a distinctive suite of rocks in the Alexander terrane, which includes sedimentary and volcanic rocks containing early Permian fossils, metamorphosed rocks with early Permian cooling ages, and intrusive rocks with early Permian cooling ages, that form discrete northwest-trending belts. After restoration of 180 km of dextral displacement of the Chilkat-Chichagof block on the Chatham Strait Fault, these belts consist, from northeast to southwest, of (1) bedded chert, siliceous argillite, volcaniclastic turbidites, pillow basalt, and limestone of the Cannery Formation and the Porcupine Slate of Gilbert and others (1987); (2) greenschist-facies Paleozoic metasedimentary and metavolcanic rocks that have Permian cooling ages; (3) silty limestone and calcareous argillite interbedded with pillow basalt and volcaniclastic rocks of the Halleck Formation and the William Henry Bay area; and (4) intermediate-composition and syenitic plutons. These belts correspond to components of an accretionary complex, contemporary metamorphic rocks, forearc-basin deposits,
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Zhang, Liwei; Anderson, Nicole; Dilmore, Robert; Soeder, Daniel J; Bromhal, Grant
2014-09-16
Potential natural gas leakage into shallow, overlying formations and aquifers from Marcellus Shale gas drilling operations is a public concern. However, before natural gas could reach underground sources of drinking water (USDW), it must pass through several geologic formations. Tracer and pressure monitoring in formations overlying the Marcellus could help detect natural gas leakage at hydraulic fracturing sites before it reaches USDW. In this study, a numerical simulation code (TOUGH 2) was used to investigate the potential for detecting leaking natural gas in such an overlying geologic formation. The modeled zone was based on a gas field in Greene County, Pennsylvania, undergoing production activities. The model assumed, hypothetically, that methane (CH4), the primary component of natural gas, with some tracer, was leaking around an existing well between the Marcellus Shale and the shallower and lower-pressure Bradford Formation. The leaky well was located 170 m away from a monitoring well, in the Bradford Formation. A simulation study was performed to determine how quickly the tracer monitoring could detect a leak of a known size. Using some typical parameters for the Bradford Formation, model results showed that a detectable tracer volume fraction of 2.0 × 10(-15) would be noted at the monitoring well in 9.8 years. The most rapid detection of tracer for the leak rates simulated was 81 days, but this scenario required that the leakage release point was at the same depth as the perforation zone of the monitoring well and the zones above and below the perforation zone had low permeability, which created a preferred tracer migration pathway along the perforation zone. Sensitivity analysis indicated that the time needed to detect CH4 leakage at the monitoring well was very sensitive to changes in the thickness of the high-permeability zone, CH4 leaking rate, and production rate of the monitoring well.
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Enomoto, Catherine B.; Olea, Ricardo A.; Coleman, James L.
2014-01-01
The Middle Devonian Marcellus Shale in the Appalachian basin extends from central Ohio on the west to eastern New York on the east, and from north-central New York on the north to northern Tennessee on the south. Its thickness ranges from 0 feet (ft) where it pinches out to the west to as much as 700 ft in its eastern extent. Within the Broadtop synclinorium, the thickness of the Marcellus Shale ranges from 250 to 565 ft. Although stratigraphic complexities have been documented, a significant range in thickness most likely is because of tectonic thickening from folds and thrust faults. Outcrop studies in the Valley and Ridge and Appalachian Plateaus provinces illustrate the challenges of interpreting the relation of third-order faults, folds, and “disturbed” zones to the regional tectonic framework. Recent field work within the Valley and Ridge province determined that significant faulting and intraformational deformation are present within the Marcellus Shale at the outcrop scale. In an attempt to determine if this scale of deformation is detectable with conventional wireline logs, petrophysical properties (primarily mineralogy and porosity) were measured by interpretation of gamma-ray and bulk-density logs. The results of performing a statistical correlation of wireline logs from nine wells indicated that there are discontinuities within the Millboro Shale (undifferentiated Marcellus Shale and Mahantango Formation) where there are significant thickness differences between wells. Also, some intervals likely contain mineralogy that makes these zones more prone to layer-shortening cleavage duplexes. The Correlator program proved to be a useful tool in a region of contractional deformation.
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Widespread effects of middle Mississippian deformation in the Great Basin of western North America
Trexler, J.H.; Cashman, P.H.; Cole, J.C.; Snyder, W.S.; Tosdal, R.M.; Davydov, V.I.
2003-01-01
Stratigraphic analyses in central and eastern Nevada reveal the importance of a deformation event in middle Mississippian time that caused widespread deformation, uplift, and erosion. It occurred between middle Osagean and late Meramecian time and resulted in deposition of both synorogenic and postorogenic sediments. The deformation resulted in east-west shortening, expressed as east-vergent folding and east-directed thrusting; it involved sedimentary rocks of the Antler foredeep as well as strata associated with the Roberts Mountains allochthon. A latest Meramecian to early Chesterian unconformity, with correlative conformable lithofacies changes, postdates this deformation and occurs throughout Nevada. A tectonic highland-created in the middle Mississippian and lasting into the Pennsylvanian and centered in the area west and southwest of Carlin, Nevada- shed sediments eastward across the Antler foreland, burying the unconformity. Postorogenic strata are late Meramecian to early Chesterian at the base and are widespread throughout the Great Basin. The tectonism therefore occurred 20 to 30 m.y. after inception of the Late Devonian Antler orogeny, significantly extending the time span of this orogeny or representing a generally unrecognized orogenic event in the Paleozoic evolution of western North America. We propose a revised stratigraphic nomenclature for Mississippian strata in Nevada, based on detailed age control and the recognition of unconformities. This approach resolves the ambiguity of some stratigraphic names and emphasizes genetic relationships within the upper Paleozoic section. We take advantage of better stratigraphic understanding to propose two new stratigraphic units for southern and eastern Nevada: the middle Mississippian Gap Wash and Late Mississippian Captain Jack Formations.
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Some contrasting biostratigraphic links between the Baker and Olds Ferry Terranes, eastern Oregon
Nestell, Merlynd K.; Blome, Charles D.
2016-01-01
New stratigraphic and paleontologic data indicate that ophiolitic melange windows in the Olds Ferry terrane of eastern Oregon contain limestone blocks and chert that are somewhat different in age than those present in the adjacent Baker terrane melange. The melange windows in the Olds Ferry terrane occur as inliers in the flyschoid Early and Middle Jurassic age Weatherby Formation, which depositionally overlies the contact between the melange-rich Devonian to Upper Triassic rocks of the Baker terrane on the north, and Upper Triassic and Early Jurassic volcanic arc rocks of the Huntington Formation on the south. The Baker terrane and Huntington Formation represent fragments of a subduction complex and related volcanic island arc, whereas the Weatherby Formation consists of forearc basin sedimentary deposits. The tectonic blocks in the melange windows of the Weatherby Formation (in the Olds Ferry terrane) are dated by scarce biostratigraphic evidence as Upper Pennsylvanian to Lower Permian and Upper Triassic. In contrast, tectonic blocks of limestone in theBaker terrane yield mostly fusulinids and small foraminifers of Middle Pennsylvanian Moscovian age at one locality.Middle Permian (Guadalupian) Tethyan fusulinids and smaller foraminifers (neoschwagerinids and other Middle Permian genera) are present at a few other localities. Late Triassic conodonts and bryozoans are also present in a few of the Baker terrane tectonic blocks. These limestone blocks are generally embedded in Permian and Triassic radiolarian bearing chert or argillite. Based on conodont, radiolarian and fusulinid data, the age limits of the meange blocks in the Weatherby Formation range from Pennsylvanian to Late Triassic.
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Taylor, Cliff D.; Finn, Carol A.; Anderson, Eric D.; Joud, M. Y.; Taleb, M. A.; Horton, John D.
2015-01-01
Phanerozoic oolitic ironstones are hosted in the upper Silurian and lower Devonian rocks of the Gara Bouya Ali Group and the Zemmour Group in the Tindouf Basin in northern Mauritania and in the end Ordovician Tichit Group, the Silurian Oued Chig Group, and the lower Devonian Tenemouj Group in the Taoudeni Basin near Tidjikja. These rock groups define 11 permissive tracts for Algoma-, Superior-, and oolitic-type iron deposits in Mauritania.
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McCartan, Lucy; Bradshaw, Margaret A.
1987-01-01
The Horlick Formation of Early Devonian age is as thick as 50 m and consists of subhorizontal, interbedded subarkosic sandstone and chloritic shale and mudstone. The Horlick overlies an erosion surface cut into Ordovician granitic rocks and is, in turn, overlain by Carboniferous and Permian glacial and periglacial deposits. Textures, sedimentary structures, and ubiquitous marine body fossils and animal traces suggest that the Horlick was deposited on a shallow shelf having moderate wave energy and a moderate tidal range. The source terrane probably lay to the north, and longshore transport was toward the west.
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Plate tectonic history of the Arctic
NASA Technical Reports Server (NTRS)
Burke, K.
1984-01-01
Tectonic development of the Arctic Ocean is outlined, and geological maps are provided for the Arctic during the mid-Cenozoic, later Cretaceous, late Jurassic, early Cretaceous, early Jurassic and late Devonian. It is concluded that Arctic basin history is moulded by the events of the following intervals: (1) continental collision and immediately subsequent rifting and ocean formation in the Devonian, and continental rifting ocean formation, rapid rotation of microcontinents, and another episode of collision in the latest Jurassic and Cretaceous. It is noted that Cenozoic Arctic basin formation is a smaller scale event superimposed on the late Mesozoic ocean basin.
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High-resolution seismic reflection to delineate shallow gas in Eastern Kansas
Miller, R.D.; Watney, W.L.; Begay, D.K.; Xia, J.
2000-01-01
Unique amplitude characteristics of shallow gas sands within Pennsylvanian clastic-carbonate dominated sequences are discernible on high-resolution seismic reflection data in eastern Kansas. Upward grading sequences of sand into shale represent a potential gas reservoir with a low-impedence acoustic contrast at the base of the encasing layer. The gas sand and encasing shale, which define the gas reservoir studied here, are part of an erosional incised valley where about 30 m of carbonates and shale have been replaced by sandstone and shale confined to the incised valley. These consolidated geologic settings would normally possess high impedence gas sand reservoirs as defined by abrupt contacts between the gas sand and encasing shale. Based orr core and borehole logs, the gas sand studied here grades from sand into shale in a fashion analogous to that observed in classic low-impedance environments. Amplitude and phase characteristics of high-resolution seismic data across this approximately 400-m wide gas sand are indicative of a low-impedance reservoir. Shot gathers possess classic amplitude with offsett-dependent characteristics which are manifeted on the stacked section as "bright spots." Dominant Frequencies of around 120 Hz allow detection of several reflectors within the 30+ meters of sand/shale that make up this localized gas-rich incised valley fill. The gradational nature of the trapping mechanism observed in this gas reservoir would make detection with conventional seismic reflection methods unlikely.
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Federal Register 2010, 2011, 2012, 2013, 2014
2012-04-18
... five potential sources of threat under this factor: 1. Global Climate Warming and Ocean Acidification... 5. Oil and Gas Development. Global climate warming and ocean acidification pose a potential threat... information suggests it is likely that global warming and ocean acidification may affect eastern North Pacific...
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Spatial and temporal distribution of imidacloprid in eastern hemlock
Richard M. Turcotte
2007-01-01
Enzyme-linked immunosorbent assay (ELISA) and gas chromatography/mass spectrometry (GC/MS) techniques were used to measure imidacloprid and metabolite concentrations in xylem fluid extracted from eastern hemlock (Tsuga canadensis) trees treated in the spring or fall with soil or trunk applications of the systemic insecticides Merit® 2F and...
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78 FR 24192 - Texas Eastern Transmission, LP; Notice of Request Under Blanket Authorization
Federal Register 2010, 2011, 2012, 2013, 2014
2013-04-24
... regulations under the Natural Gas Act (NGA). Texas Eastern seeks authorization to perform [[Page 24193... to section 157.205 of the Commission's Regulations under the NGA (18 CFR 157.205) a protest to the... as an application for authorization pursuant to section 7 of the NGA. The Commission strongly...
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75 FR 26211 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-11
...: 5 p.m. Eastern Time on Monday, May 10, 2010. Docket Numbers: RP10-653-000. Applicants: Discovery Gas.... Accession Number: 20100427-5175. Comment Date: 5 p.m. Eastern Time on Monday, May 10, 2010. Docket Numbers... Trading North America, LLC. Filed Date: 04/28/2010 Accession Number: 20100428-0211. Comment Date: 5 p.m...
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77 FR 51985 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2012-08-28
... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Combined Notice of Filings Take notice that the Commission has received the following Natural Gas Pipeline Rate and Refund Report filings: Filings Instituting Proceedings Docket Numbers: RP12-947-000. Applicants: Eastern Shore Natural Gas...
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NASA Astrophysics Data System (ADS)
Mark, D.; Rice, C.; Stuart, F.; Trewin, N.
2011-12-01
The Rhynie cherts are hot spring sinters that contain world-renowned plant and animal remains and anomalously high quantities of heavy metals, including gold. The biota in several beds is preserved undeformed with plants in life positions thus establishing that they and the indurating hydrothermal fluids were coeval. Despite the international importance of the Rhynie cherts their age has been poorly constrained for three reasons: (1) lack of a precise radio-isotopic age, (2) low resolution of spore biostratigraphic schemes for Devonian terrestrial deposits, with only one to a few zones per stage, and (3) poor resolution of the early Devonian timescale. Wellman (2004) assigned a Pragian-?earliest Emsian age to the Rhynie cherts on the basis of the spore assemblage. An 40Ar/39Ar dating study targeting Rhynie chert yielded an age of 395 ± 12 Ma (1σ) (Rice et al., 1995). This contribution discusses a new high-precision 40Ar/39Ar age (407.1 ± 2.2 Ma, 2σ) for the Devonian hot-spring system at Rhynie (Mark et al., 2011) and demonstrates that a proposed U-Pb age (411.5 ± 1.1 Ma, 2σ) for the Rhynie cherts (Parry et al., 2011) is inconsistent with both field evidence and our interpretation of the U-Pb data. The 40Ar/39Ar age provides a robust marker for the polygonalis-emsiensis Spore Assemblage Biozone within the Pragian-?earliest Emsian. It also constrains the age of a wealth of flora and fauna preserved in life positions as well as dating gold mineralization. Furthermore, we have now determined the Ar isotope composition of pristine samples of the Rhynie chert using an ARGUS multi-collector mass spectrometer and a low blank laser extraction technique. 40Ar/36Ar are systematically lower than the modern air value (Lee et al., 2006), and are not accompanied by non-atmospheric 38Ar/36Ar ratios. We conclude that the Rhynie chert captured and has preserved Devonian atmosphere-derived Ar. The data indicate that the 40Ar/36Ar of Devonian atmosphere was at least 3 % lower than the modern air value (Lee et al., 2006). Thus the Earth's atmosphere has accumulated at least 5 ± 0.2 x 1016 moles of 40Ar in the last c. 407 Ma, at an average rate of 1.24 ± 0.06 x 108 mol 40Ar/year. This overlaps the 40Ar accumulation rate determined from ice cores for the last 800,000 years (Bender et al. 2008) and implies that there has been no resolvable temporal change in outgassing rate since the mid-Palaeozoic. The new chronological and Ar isotope data provide a unique tie point and dictate outgassing of the Earth's interior early in Earth history. [1] Bender, M. et al. (2008) Proceedings of the National Academy of Sciences, 105, 8232-8237. [2] Wellman, C.H., 2004. Proceedings of the Royal Society of London. Biological Sciences, 271, 985-992. [3] Lee, J.Y. et al. (2006) Geochimica et Cosmochimica Acta, 70, 4507-4512. [4] Mark, D.F. et al. (2011) Geochimica et Cosmochimica Acta, 75, 555-569. [5] Parry, S.F. et al. (2011) Journal of the Geological Society, London, 168, 863-872. [6] Rice, C.M. et al. (1995) Journal of the Geological Society, London, 152, 229-2250.
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NASA Astrophysics Data System (ADS)
Koehl, Jean-Baptiste P.; Bergh, Steffen G.; Henningsen, Tormod; Faleide, Jan Inge
2018-03-01
The SW Barents Sea margin experienced a pulse of extensional deformation in the Middle-Late Devonian through the Carboniferous, after the Caledonian Orogeny terminated. These events marked the initial stages of formation of major offshore basins such as the Hammerfest and Nordkapp basins. We mapped and analyzed three major fault complexes, (i) the Måsøy Fault Complex, (ii) the Rolvsøya fault, and (iii) the Troms-Finnmark Fault Complex. We discuss the formation of the Måsøy Fault Complex as a possible extensional splay of an overall NE-SW-trending, NW-dipping, basement-seated Caledonian shear zone, the Sørøya-Ingøya shear zone, which was partly inverted during the collapse of the Caledonides and accommodated top-NW normal displacement in Middle to Late Devonian-Carboniferous times. The Troms-Finnmark Fault Complex displays a zigzag-shaped pattern of NNE-SSW- and ENE-WSW-trending extensional faults before it terminates to the north as a WNW-ESE-trending, NE-dipping normal fault that separates the southwesternmost Nordkapp basin in the northeast from the western Finnmark Platform and the Gjesvær Low in the southwest. The WNW-ESE-trending, margin-oblique segment of the Troms-Finnmark Fault Complex is considered to represent the offshore prolongation of a major Neoproterozoic fault complex, the Trollfjorden-Komagelva Fault Zone, which is made of WNW-ESE-trending, subvertical faults that crop out on the island of Magerøya in NW Finnmark. Our results suggest that the Trollfjorden-Komagelva Fault Zone dies out to the northwest before reaching the western Finnmark Platform. We propose an alternative model for the origin of the WNW-ESE-trending segment of the Troms-Finnmark Fault Complex as a possible hard-linked, accommodation cross fault that developed along the Sørøy-Ingøya shear zone. This brittle fault decoupled the western Finnmark Platform from the southwesternmost Nordkapp basin and merged with the Måsøy Fault Complex in Carboniferous times. Seismic data over the Gjesvær Low and southwesternmost Nordkapp basin show that the low-gravity anomaly observed in these areas may result from the presence of Middle to Upper Devonian sedimentary units resembling those in Middle Devonian, spoon-shaped, late- to post-orogenic collapse basins in western and mid-Norway. We propose a model for the formation of the southwesternmost Nordkapp basin and its counterpart Devonian basin in the Gjesvær Low by exhumation of narrow, ENE-WSW- to NE-SW-trending basement ridges along a bowed portion of the Sørøya-Ingøya shear zone in the Middle to Late Devonian-early Carboniferous. Exhumation may have involved part of a large-scale metamorphic core complex that potentially included the Lofoten Ridge, the West Troms Basement Complex and the Norsel High. Finally, we argue that the Sørøya-Ingøya shear zone truncated and decapitated the Trollfjorden-Komagelva Fault Zone during the Caledonian Orogeny and that the western continuation of the Trollfjorden-Komagelva Fault Zone was mostly eroded and potentially partly preserved in basement highs in the SW Barents Sea.
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Lithologies of the basement complex (Devonian and older) in the National Petroleum Reserve - Alaska
Dumoulin, Julie A.; Houseknecht, David W.
2001-01-01
Rocks of the basement complex (Devonian and older) were encountered in at least 30 exploratory wells in the northern part of the NPRA. Fine-grained, variably deformed sedimentary rocks deposited in a slope or basinal setting predominate and include varicolored (mainly red and green) argillite in the Simpson area, dark argillite and chert near Barrow, and widespread gray argillite. Chitinozoans of Middle-Late Ordovician and Silurian age occur in the dark argillite and chert unit. Sponge spicules and radiolarians establish a Phanerozoic age for the varicolored and gray argillite units, both of which contain local interbeds of chert-rich sandstone and silt-stone. Conglomerate and sandstone, also chert-rich but interbedded with mudstone and coal and of Early-Middle Devonian age, occur in the Topagoruk area; these strata formed in a fluvial environment. At East Teshekpuk, granite of probable Devonian age was penetrated. Brecciated, quartz-veined rock of uncertain protolith that may be part of the basement complex was encountered in the Ikpikpuk well. Seismic data indicate that angular unconformities truncate all sedimentary units of the basement complex in NPRA. Rocks correlative in age and lithofacies with the dark argillite and chert unit occur in the subsurface near Prudhoe Bay. Other argillite units in NPRA have similarities to basement rocks in the subsurface adjacent to ANWR and the Ordovician-Silurian Iviagik Group at Cape Lisburne, but lack the interbedded limestones found in the ANWR strata, and are less metamorphosed than, and compositionally distinct from, the Iviagik. The Topagoruk conglomerate and the East Teshekpuk granite resemble the Ulungarat formation and the Okpilak batholith, respectively, in the northeastern Brooks Range.
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Friedman, Matt; Brazeau, Martin D
2011-02-07
Past research on the emergence of digit-bearing tetrapods has led to the widely accepted premise that this important evolutionary event occurred during the Late Devonian. The discovery of convincing digit-bearing tetrapod trackways of early Middle Devonian age in Poland has upset this orthodoxy, indicating that current scenarios which link the timing of the origin of digited tetrapods to specific events in Earth history are likely to be in error. Inspired by this find, we examine the fossil record of early digit-bearing tetrapods and their closest fish-like relatives from a statistical standpoint. We find that the Polish trackways force a substantial reconsideration of the nature of the early tetrapod record when only body fossils are considered. However, the effect is less drastic (and often not statistically significant) when other reliably dated trackways that were previously considered anachronistic are taken into account. Using two approaches, we find that 95 per cent credible and confidence intervals for the origin of digit-bearing tetrapods extend into the Early Devonian and beyond, spanning late Emsian to mid Ludlow. For biologically realistic diversity models, estimated genus-level preservation rates for Devonian digited tetrapods and their relatives range from 0.025 to 0.073 per lineage-million years, an order of magnitude lower than species-level rates for groups typically considered to have dense records. Available fossils of early digited tetrapods and their immediate relatives are adequate for documenting large-scale patterns of character acquisition associated with the origin of terrestriality, but low preservation rates coupled with clear geographical and stratigraphic sampling biases caution against building scenarios for the origin of digits and terrestrialization tied to the provenance of particular specimens or faunas.
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Wang, De-Ming; Xu, Hong-He; Xue, Jin-Zhuang; Wang, Qi; Liu, Le
2015-06-01
With the exception of angiosperms, the main euphyllophyte lineages (i.e. ferns sensu lato, progymnosperms and gymnosperms) had evolved laminate leaves by the Late Devonian. The evolution of laminate leaves, however, remains unclear for early-diverging ferns, largely represented by fern-like plants. This study presents a novel fern-like taxon with pinnules, which provides new insights into the early evolution of laminate leaves in early-diverging ferns. Macrofossil specimens were collected from the Upper Devonian (Famennian) Wutong Formation of Anhui and Jiangsu Provinces, South China. A standard degagement technique was employed to uncover compressed plant portions within the rock matrix. A new fern-like taxon, SHOUGANGIA BELLA GEN ET SP NOV: , is described and represents an early-diverging fern with highly derived features. It has a partially creeping stem with adventitious roots only on one side, upright primary and secondary branches arranged in helices, tertiary branches borne alternately or (sub)oppositely, laminate and usually lobed leaves with divergent veins, and complex fertile organs terminating tertiary branches and possessing multiple divisions and numerous terminal sporangia. Shougangia bella provides unequivocal fossil evidence for laminate leaves in early-diverging ferns. It suggests that fern-like plants, along with other euphyllophyte lineages, had independently evolved megaphylls by the Late Devonian, possibly in response to a significant decline in atmospheric CO2 concentration. Among fern-like plants, planate ultimate appendages are homologous with laminate pinnules, and in the evolution of megaphylls, fertile organs tend to become complex. © The Author 2015. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
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Zhu, Zhi-Liang; Reed, Bradley C.; Zhu, Zhi-Liang; Reed, Bradley C.
2014-01-01
This assessment was conducted to fulfill the requirements of section 712 of the Energy Independence and Security Act of 2007 and to conduct a comprehensive national assessment of storage and flux (flow) of carbon and the fluxes of other greenhouse gases in ecosystems of the Eastern United States. These carbon and greenhouse gas variables were examined for major terrestrial ecosystems (forests, grasslands/shrublands, agricultural lands, and wetlands) and aquatic ecosystems (rivers, streams, lakes, estuaries, and coastal waters) in the Eastern United States in two time periods: baseline (from 2001 through 2005) and future (projections from the end of the baseline through 2050). The Great Lakes were not included in this assessment due to a lack of input data. The assessment was based on measured and observed data collected by the U.S. Geological Survey and many other agencies and organizations and used remote sensing, statistical methods, and simulation models.
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NASA Technical Reports Server (NTRS)
McAdam, A.; Stern, J. C.; Mahaffy, P. R.; Blake, D. F.; Bristow, T.; Steele, A.; Amundsen, H. E. F.
2012-01-01
The 2011 Arctic Mars Analog Svalbard Expedition (AMASE) investigated several geologic settings on Svalbard, using methodologies and techniques being developed or considered for future Mars missions, such as the Mars Science Laboratory (MSL). The Sample Analysis at Mars (SAM) instrument suite on MSL consists of a quadrupole mass spectrometer (QMS), a gas chromatograph (GC), and a tunable laser spectrometer (TLS), which analyze gases created by pyrolysis of samples. During AMASE, a Hiden Evolved Gas Analysis-Mass Spectrometer (EGA-MS) system represented the EGA-QMS capability of SAM. Another MSL instrument, CheMin, will use x-ray diffraction (XRD) and x-ray fluorescence (XRF) to perform quantitative mineralogical characterization of samples. Field-portable versions of CheMin were used during AMASE. AMASE 2011 sites spanned a range of environments relevant to understanding martian surface materials, processes and habitability. They included the basaltic Sverrefjell volcano, which hosts carbonate globules, cements and coatings, carbonate and sulfate units at Colletth0gda, Devonian sandstone redbeds in Bockfjorden, altered basaltic lava delta deposits at Mt. Scott Keltie, and altered dolerites and volcanics at Botniahalvoya. Here we focus on SAM-like EGA-MS of a subset of the samples, with mineralogy comparisons to CheMin team results. The results allow insight into sample organic content as well as some constraints on sample mineralogy.
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Structural features and oil-and-gas bearing of the Caribbean region
NASA Astrophysics Data System (ADS)
Zabanbark, A.; Lobkovsky, L. I.
2017-09-01
The structure of the Caribbean region testifies to the extremely unstable condition of the terrestrial crust of this intercontinental and simultaneously interoceanic area. In the recent geological epoch, the Caribbean region is represented by a series of structural elements, the main of which are the Venezuelan and Colombian deep-sea suboceanic depressions, the Nicaraguan Rise, and the Greater and Lesser Antilles bordering the Caribbean Sea in the north and east. There are 63 sedimentary basins in the entire Caribbean region. However, only the Venezuelan and Colombian basins, the Miskito Basin in Nicaragua, and the northern and eastern shelves of the Antilles, Paria Bay, Barbodos-Tobago, and Grenada basins are promising in terms of oil-and-gas bearig. In the Colombian Basin, the southwestern part, located in the rift zone of the Gulf of Uraba, is the most promising. In the Venezuelan Basin, possible oil-and-gas-bearing basins showing little promise are assumed to be in the northern and eastern margins. The main potential of the eastern Caribbean region is attributed to the southern margin, at the shelf zone of which are the Tokuyo-Bonaire, Tuy-Cariaco, Margarita, Paria Bay, Barbados-Tobago, and Grenada oil-and-gas-bearing basins. The rest of the deepwater depressions of the Caribbean Sea show little promise for hydrocarbon research due to the small thickness of the deposits, their flat bedding, and probably a lack of fluid seals.
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Mancini, E.A.; Li, P.; Goddard, D.A.; Ramirez, V.O.; Talukdar, S.C.
2008-01-01
The Mesozoic (Upper Jurassic-Lower Cretaceous) deeply buried gas reservoir play in the central and eastern Gulf coastal plain of the United States has high potential for significant gas resources. Sequence-stratigraphic study, petroleum system analysis, and resource assessment were used to characterize this developing play and to identify areas in the North Louisiana and Mississippi Interior salt basins with potential for deeply buried gas reservoirs. These reservoir facies accumulated in Upper Jurassic to Lower Cretaceous Norphlet, Haynesville, Cotton Valley, and Hosston continental, coastal, and marine siliciclastic environments and Smackover and Sligo nearshore marine shelf, ramp, and reef carbonate environments. These Mesozoic strata are associated with transgressive and regressive systems tracts. In the North Louisiana salt basin, the estimate of secondary, nonassociated thermogenic gas generated from thermal cracking of oil to gas in the Upper Jurassic Smackover source rocks from depths below 3658 m (12,000 ft) is 4800 tcf of gas as determined using software applications. Assuming a gas expulsion, migration, and trapping efficiency of 2-3%, 96-144 tcf of gas is potentially available in this basin. With some 29 tcf of gas being produced from the North Louisiana salt basin, 67-115 tcf of in-place gas remains. Assuming a gas recovery factor of 65%, 44-75 tcf of gas is potentially recoverable. The expelled thermogenic gas migrated laterally and vertically from the southern part of this basin to the updip northern part into shallower reservoirs to depths of up to 610 m (2000 ft). Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.
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Blodgett, R.B.
1993-01-01
A new gastropod genus, Dutrochus, is established for members of the family Microdomatidae that are characterized by a reticulate ornament of spiral cords and intersecting, finer collabral threads, with all but one spiral cord being of nearly equal strength, and the single remaining cord being of stronger (nearly twice the order) magnitude and being situated at the periphery. It is represented by the type and only known species, Dutrochus alaskensis n. gen. and sp., from the upper part (lower Eifelian) of the Lower? and Middle Devonian Cheeneetnuk Limestone. The genus is very close and nearly homeomorphic to the Permian microdomatid genus Glyptospira. -from Author
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Impact ejecta layer from the mid-Devonian: possible connection to global mass extinctions.
Ellwood, Brooks B; Benoist, Stephen L; El Hassani, Ahmed; Wheeler, Christopher; Crick, Rex E
2003-06-13
We have found evidence for a bolide impacting Earth in the mid-Devonian ( approximately 380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.
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Oliver, W.A.
1997-01-01
Heliophyllum halli Milne-Edwards and Haime is common to abundant in many Lower and Middle Devonian stratigraphic units in New York. Most Heliophyllum are solitary, but both branching and massive colonies are known. Four 'populations' of colonial Heliophyllum in the Givetian part of the sequence are distinct, as is a fifth form that occurs through the section. Each of the colonial forms is interpreted as an independent derivative of solitary forms of H. halli. The relationships appear to range from infrasubspecific to specific, and it is suggested that the complex should be recognized as the Heliophyllum halli species group.
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Impact Ejecta Layer from the Mid-Devonian: Possible Connection to Global Mass Extinctions
NASA Astrophysics Data System (ADS)
Ellwood, Brooks B.; Benoist, Stephen L.; Hassani, Ahmed El; Wheeler, Christopher; Crick, Rex E.
2003-06-01
We have found evidence for a bolide impacting Earth in the mid-Devonian (~380 million years ago), including high concentrations of shocked quartz, Ni, Cr, As, V, and Co anomalies; a large negative carbon isotope shift (-9 per mil); and microspherules and microcrysts at Jebel Mech Irdane in the Anti Atlas desert near Rissani, Morocco. This impact is important because it is coincident with a major global extinction event (Kacák/otomari event), suggesting a possible cause-and-effect relation between the impact and the extinction. The result may represent the extinction of as many as 40% of all living marine animal genera.
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NASA Astrophysics Data System (ADS)
Barash, M. S.
2017-08-01
During the Late Devonian extinction, 70-82% of all marine species disappeared. The main causes of this mass extinction include tectonic activity, climate and sea-level fluctuations, volcanism, and the collision of the Earth with cosmic bodies (impact events). The major causes are considered to be volcanism accompanying formation of the Viluy traps and, probably, basaltic magmatism in the Southern Urals, alkaline magmatism within the East European platform, and volcanism in northern Iran and northern and southern China. Several large impact craters of Late Devonian age have been documented in different parts of the world. The available data indicate that this time period on the Earth was marked by two major sequences of events: terrestrial events that resulted in extensive volcanism and cosmic (or impact) events. They produced similar effects such as emissions of harmful chemical compounds and aerosols to cause greenhouse warming and the darkening of the atmosphere, which prevented photosynthesis and cause ocean stagnation and anoxia. This disrupted the food chain and reduced ecosystem productivity. As a result, all vital processes were disturbed and a large part of the marine biota became extinct.
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Fossil record of stem groups employed in evaluating the chronogram of insects (Arthropoda: Hexapoda)
Wang, Yan-hui; Engel, Michael S.; Rafael, José A.; Wu, Hao-yang; Rédei, Dávid; Xie, Qiang; Wang, Gang; Liu, Xiao-guang; Bu, Wen-jun
2016-01-01
Insecta s. str. (=Ectognatha), comprise the largest and most diversified group of living organisms, accounting for roughly half of the biodiversity on Earth. Understanding insect relationships and the specific time intervals for their episodes of radiation and extinction are critical to any comprehensive perspective on evolutionary events. Although some deeper nodes have been resolved congruently, the complete evolution of insects has remained obscure due to the lack of direct fossil evidence. Besides, various evolutionary phases of insects and the corresponding driving forces of diversification remain to be recognized. In this study, a comprehensive sample of all insect orders was used to reconstruct their phylogenetic relationships and estimate deep divergences. The phylogenetic relationships of insect orders were congruently recovered by Bayesian inference and maximum likelihood analyses. A complete timescale of divergences based on an uncorrelated log-normal relaxed clock model was established among all lineages of winged insects. The inferred timescale for various nodes are congruent with major historical events including the increase of atmospheric oxygen in the Late Silurian and earliest Devonian, the radiation of vascular plants in the Devonian, and with the available fossil record of the stem groups to various insect lineages in the Devonian and Carboniferous. PMID:27958352
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Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant
NASA Astrophysics Data System (ADS)
Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang
2016-08-01
The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.
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Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant.
Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F; Hao, Shougang
2016-08-23
The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant-soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet-dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant-soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated.
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Belowground rhizomes in paleosols: The hidden half of an Early Devonian vascular plant
Xue, Jinzhuang; Deng, Zhenzhen; Huang, Pu; Huang, Kangjun; Benton, Michael J.; Cui, Ying; Wang, Deming; Liu, Jianbo; Shen, Bing; Basinger, James F.; Hao, Shougang
2016-01-01
The colonization of terrestrial environments by rooted vascular plants had far-reaching impacts on the Earth system. However, the belowground structures of early vascular plants are rarely documented, and thus the plant−soil interactions in early terrestrial ecosystems are poorly understood. Here we report the earliest rooted paleosols (fossil soils) in Asia from Early Devonian deposits of Yunnan, China. Plant traces are extensive within the soil and occur as complex network-like structures, which are interpreted as representing long-lived, belowground rhizomes of the basal lycopsid Drepanophycus. The rhizomes produced large clones and helped the plant survive frequent sediment burial in well-drained soils within a seasonal wet−dry climate zone. Rhizome networks contributed to the accumulation and pedogenesis of floodplain sediments and increased the soil stabilizing effects of early plants. Predating the appearance of trees with deep roots in the Middle Devonian, plant rhizomes have long functioned in the belowground soil ecosystem. This study presents strong, direct evidence for plant−soil interactions at an early stage of vascular plant radiation. Soil stabilization by complex rhizome systems was apparently widespread, and contributed to landscape modification at an earlier time than had been appreciated. PMID:27503883
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NASA Astrophysics Data System (ADS)
Patočka, F.; Pruner, P.; Štorch, P.
The Barrandian area (the Teplá-Barrandian unit, Bohemian Massif) provided palaeomagnetic results on Early Palaeozoic rocks and chemical data on siliciclastic sediments of both Middle Cambrian and Early Ordovician to Middle Devonian sedimentary sequences; an outcoming interpretation defined source areas of clastic material and palaeotectonic settings of the siliciclastic rock deposition. The siliciclastic rocks of the earliest Palaeozoic sedimentation cycle, deposited in the Cambrian Příbram-Jince Basin of the Barrandian, were derived from an early Cadomian volcanic island arc developed on Neoproterozoic oceanic lithosphere and accreted to a Cadomian active margin of northwestern Gondwana. Inversion of relief terminated the Cambrian sedimentation, and a successory Prague Basin subsided nearby since Tremadocian. Source area of the Ordovician and Early Silurian shallow-marine siliciclastic sediments corresponded to progressively dissected crust of continental arc/active continental margin type of Cadomian age. Since Late Ordovician onwards both synsedimentary within-plate basic volcanics and older sediments had been contributing in recognizable proportions to the siliciclastic rocks. The siliciclastic sedimentation was replaced by deposition of carbonate rocks throughout late Early Silurian to Early Devonian period of withdrawal of the Cadomian clastic material source. Above the carbonates an early Givetian flysch-like siliciclastic suite completed sedimentation in the Barrandian. In times between Middle Cambrian and Early/Middle Devonian boundary interval an extensional tectonic setting prevailed in the Teplá-Barrandian unit. The extensional regime was related to Early Palaeozoic large-scale fragmentation of the Cadomian belt of northwestern Gondwana and origin of Armorican microcontinent assemblage. The Teplá-Barrandian unit was also engaged in a peri-equatorially oriented drift of Armorican microcontinent assemblage throughout the Early Palaeozoic: respective palaeolatitudes of 58°S (Middle Cambrian) and 17°S (Middle Devonian) were inferred for the Barrandian rocks. The Middle Devonian flysch-like siliciclastics of the Prague Basin suggest a reappearance of the deeply dissected Cadomian source area in a proximity of the Barrandian due to early Variscan convergences and collisions of the Armorican microcontinents. Significant palaeotectonic rotations are palaeomagnetically evidenced to take place during oblique convergence and final docking of the Teplá-Barrandian microplate within the Variscan terrane mosaic of the Bohemian Massif.
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NASA Astrophysics Data System (ADS)
Niedźwiedzki, G.
2012-04-01
Numerous trackways and isolated prints with digit impressions, which are similar to the foot anatomy of early tetrapods such as Ichthyostega, were found on the three dolomite bed-surfaces in the lower part of the Wojciechowice Formation exposed in the Zachełmie Quarry in the Holy Cross Mountains (south-central Poland), (Niedźwiedzki et al., 2010). The age of the tetrapod track-bearing strata is well-constrained, but the detailed sedimentology of the lower section with tetrapod ichnites is still under study. The Wojciechowice Formation represent one of the first carbonate stages of a transgressive succession that begins with Early Devonian continental to marginal marine clastics and culminates in the development of a Givetian coral-stromatoporoid carbonate platform. The tetrapod track-bearing complex is composed of grey to reddish, thin- to medium-bedded dolomitic shales and marly dolomite mudstones. These deposits from the tetrapod track-bearing horizon lack definitive marine body fossils, and may have formed in a marginal marine environment, e.g. around a coastal lagoon. Mudcracks, columnar peds, root traces, and microbially induced sedimentary structures were found in three distinct pedotypes of very weakly to weakly developed paleosols (Retallack, 2011). Conodonts of the costatus zone (mid-Eifelian) were found 20 m above the uppermost surface with tetrapod tracks in limestones of the upper Wojciechowice Formation, which contain also brachiopod and crinoidal debris. The overlying Kowala Formation is a marine coral limestone and dolostone. The parts of profile with tetrapod ichnites and invertebrate and conodont fossils contain also records of invertebrate traces. Seven ichnotaxa are distributed among four recognized ichnoassemblages. The recognized ichnocoenoses are typical for the shallow-marine (Cruziana ichnofacies) and land-water transitional (Skolithos/Psilonichnus ichnofacies) carbonate depositional environments. The ichnocoenoses are dominated by trace fossils produced by arthropods (probably crustaceans), a group that can create large and distinctive burrows. The palaeoecological information from the Zachełmie section has direct bearing on the interpretation of environmental aspects of tetrapod emergence and terrestrialization. It should be fully integrated with data from other Devonian tetrapod tracksites. Niedźwiedzki, G., Szrek P., Narkiewicz K., Narkiewicz M. and Ahlberg P.E. 2010. Tetrapod trackways from the early Middle Devonian period of Poland. Nature, 463: 43-48. Retallack, G.J. 2011. Woodland Hypothesis for Devonian Tetrapod Evolution. The Journal of Geology, 119, 3: 235-258
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NASA Astrophysics Data System (ADS)
Ma, Xiaomei; Cai, Keda; Zhao, Taiping; Bao, Zihe; Wang, Xiangsong; Chen, Ming; Buslov, M. M.
2018-07-01
Ridge-trench interaction is a common tectonic process of the present-day Pacific Rim accretionary orogenic belts, and this process may facilitate "slab-window" magmatism that can produce significant thermal anomalies and geochemically unusual magmatic events. However, ridge-trench interaction has rarely been well-documented in the ancient geologic record, leading to grossly underestimation of this process in tectonic syntheses of plate margins. The Chinese Altai was inferred to have undergone ridge subduction in the Devonian and a slab-window model is proposed to interpret its high-temperature metamorphism and geochemically unique magmatic rocks, which can serve as an excellent and unique place to refine the tectonic evolution associated with ridge subduction in an ancient accretionary orogeny. For this purpose, we carried out geochemical and geochronological studies on Devonian basaltic rocks in this region. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating results yield an age of 376.2 ± 2.4 Ma, suggesting an eruption at the time of Late Devonian. Geochemically, the samples in this study have variable SiO2 (43.3-58.3 wt%), low K2O (0.02-0.07 wt%) and total alkaline contents (2.16-5.41 wt%), as well as Fe2O3T/MgO ratios, showing typical tholeiitic affinity. On the other hand, the basaltic rocks display MORB-like REE patterns ((La/Yb)N = 0.90-2.57) and (Ga/Yb)N = 0.97-1.28), and have moderate positive εNd(t) values (+4.4 to +5.4), which collectively suggest a derivation from a mixing source comprising MORB-like mantle of a mature back-arc basin and subordinate arc mantle wedge. These basaltic rocks are characterized by Low La/Yb (1.26-3.69), Dy/Yb (1.51-1.77) and Sm/Yb (0.83-1.32) ratios, consistent with magmas derived from low degree (∼10%) partial melting of the spinel lherzolite source at a quite shallow mantle depth. Considering the distinctive petrogenesis of the basaltic rocks in this region, the Late Devonian basalts in the southern Chinese Altai is suggested to have witnessed the propagating process of slab-window magmatism that was induced by ridge subduction in a nascent rifting stage of a back-arc basin.
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Milici, Robert C.
2004-01-01
The Carboniferous Coal-bed Gas Total Petroleum System, lies within the central and northern parts of the Appalachian coal field. It consists of five assessment units (AU): the Pocahontas Basin in southwestern Virginia, southern West Virginia, and eastern Kentucky, the Central Appalachian Shelf in Tennessee, eastern Kentucky and southern West Virginia, East Dunkard (Folded) in western Pennsylvania and northern West Virginia, West Dunkard (Unfolded) in Ohio and adjacent parts of Pennsylvania and West Virginia, and the Appalachian Anthracite and Semi-Anthracite AU in Pennsylvania and Virginia. Of these, only the Pocahontas Basin and West Dunkard (Folded) AU were assessed quantitatively by the U.S. Geological survey in 2002 as containing about 3.6 and 4.8 Tcf of undiscovered, technically recoverable gas, respectively (Milici and others, 2003). In general, the coal beds of this Total Petroleum System, which are both the source rock and reservoir, were deposited together with their associated sedimentary strata in Mississippian and Pennsylvanian (Carboniferous) time. The generation of biogenic (microbial) gas probably began almost immediately as the peat deposits were first formed. Microbial gas generation is probably occurring at present to some degree throughout the basin, where the coal beds are relatively shallow and wet. With sufficient depth of burial, compaction, and coalification during the late Paleozoic and Early Mesozoic, the coal beds were heated sufficiently to generate thermogenic gas in the eastern part of the Appalachian basin. Trap formation began initially with the deposition of the paleopeat deposits during the Mississippian, and continued into the Late Pennsylvanian and Permian as the Appalachian Plateau strata were deformed during the Alleghanian orogeny. Seals are the connate waters that occupy fractures and larger pore spaces within the coal beds as well as the fine-grained siliciclastic sedimentary strata that are intercalated with the coal. The critical moment for the petroleum system occurred during this orogeny, when deformation created geologic structures in the eastern part of the basin that enhanced fracture porosity within the coal beds. In places, burial by thrust sheets (thrust loading) within the Appalachian fold-and-thrust belt may have resulted in additional generation of thermogenic CBM in the anthracite district of Pennsylvania and in the semianthracite deposits of Virginia and West Virginia.
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Structure and shale gas production patterns from eastern Kentucky field
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shumaker, R.C.
Computer-derived subsurface structure, isopach, and gas-flow maps, based on 4000 drillers logs, have been generated for eastern Kentucky under a project sponsored by the Gas Research Institute. Structure maps show low-relief flextures related to basement structure. Some structures have been mapped at the surface, others have not. Highest final open-flow (fof) of shale gas from wells in Martin County follow a structural low between (basement) anticlines. From there, elevated gas flows (fof) extend westward along the Warfield monocline to Floyd County where the high flow (fof) trend extends southward along the Floyd County channel. In Knott County, the number ofmore » wells with high gas flow (fof) decreases abruptly. The center of highest gas flow (fof) in Floyd County spreads eastward to Pike County, forming a triangular shaped area of high production (fof). The center of highest gas flow (fof) is in an area where possible (basement) structure trends intersect and where low-relief surface folds (probably detached structure) were mapped and shown on the 1922 version of the Floyd County structure map. Modern regional maps, based on geophysical logs from widely spaced wells, do not define the low-relief structures that have been useful in predicting gas flow trends. Detailed maps based on drillers logs can be misleading unless carefully edited. Comparative analysis of high gas flows (fof) and 10-year cumulative production figures in a small area confirms that there is a relationship between gas flow (fof) values and long-term cumulative production.« less
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Federal Register 2010, 2011, 2012, 2013, 2014
2010-05-04
... station/pig \\1\\ launcher at the interconnect with Texas Eastern Transmission, LP, near Honey Brook, Pennsylvania; \\1\\ A ``pig'' is a tool that is inserted into and moves through the pipeline, and is used for.../pig receiver at the existing ESNG meter station near Parkesburg, Pennsylvania. The general location of...
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Plan of study for the Ohio-Indiana carbonate-bedrock and glacial- aquifer system
Bugliosi, E.F.
1990-01-01
The major aquifers of 35,000 sq mi area in western Ohio and eastern Indiana consist of Silurian and Devonian carbonate bedrock and Quaternary glacial deposits. These bedrock units and glacial deposits have been designated for study as part of the U.S. Geological Survey 's Regional Aquifer System Analysis program, a nationwide program to assess the regional hydrology, geology and water quality of the Nation 's most important aquifers. The purpose of the study is to define the hydrology, geochemistry, and geologic framework of the aquifer system within the Silurian and Devonian rocks and glacial deposits, with emphasis on describing the groundwater flow patterns and characterizing the water quality. The study, which began in 1988 , is expected to be completed in 1993. In 1980, the aquifers in the study area supplied more than 280 million gallons of water/day to industry, agriculture, and a population of more than 6.3 million people. With a projected future population growth to 7.1 million in 1990, and with intensified agricultural and industrial uses, water withdrawals from these bedrock and glacial aquifers are expected to be increased. The most significant groundwater problems in the study area result from the pronounced areal differences in availability and quality of the groundwater. These differences are related to the lateral discontinuity of many of the glacial deposits and to variations in secondary permeability of the bedrock aquifers associated with patterns of fracturing. Planned activities of the study include compilation of available geohydrologic and water quality data, such as groundwater levels, geohydrologic properties of aquifers, chemical analyses, land use and water use data, and ancillary data such as digital satellite images. Additional geohydrologic and water quality data may be collected from existing wells or wells that may be drilled for this study. A computerized, geographic information system will be used as a data base management tool and for spatial analysis and presentation of the data. A digital computer model will be developed to study the regional groundwater flow system and to investigate the effects of development on the aquifer system. (USGS)
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NASA Astrophysics Data System (ADS)
Zhao, Yan; Sun, Yong; Diwu, Chunrong; Zhu, Tao; Ao, Wenhao; Zhang, Hong; Yan, Jianghao
2017-05-01
The Dunhuang tectonic belt (DTB) is of great importance for understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt (CAOB). In this study, the temporal-spatial distribution, petrogenesis and tectonic setting of the Paleozoic representative intrusive rocks from the DTB were systematically investigated to discuss crustal evolution history and tectonic regime of the DTB during Paleozoic. Our results reveal that the Paleozoic magmatism within the DTB can be broadly divided into two distinct episodes of early Paleozoic and late Paleozoic. The early Paleozoic intrusive rocks, represented by a suite metaluminous-slight peraluminous and medium- to high-K calc-alkaline I-type granitoids crystallized at Silurian (ca. 430-410 Ma), are predominantly distributed along the northern part of the DTB. They were probably produced with mineral assemblage of eclogite or garnet + amphibole + rutile in the residue, and were derived from magma mixing source of depleted mantle materials with various proportions of Archean-Mesoproterozoic continental crust. The late Paleozoic intrusive rocks can be further subdivided into two stages of late Devonian stage (ca. 370-360 Ma) and middle Carboniferous stage (ca. 335-315 Ma). The former stage is predominated by metaluminous to slight peraluminous and low-K tholeiite to high-K calc-alkaline I-type granitic rocks distributed in the central part of the DTB. They were also generated with mineral assemblage of amphibolite- to eclogite-facies in the residue, and originated from magma source of depleted mantle materials mixed with different degrees of old continental crust. The later stage is represented by adakite and alkali-rich granite exposed in the southern part of the DTB. The alkali-rich granites studied in this paper were possibly produced with mineral assemblage of granulite-facies in the residue and were generated by partial melting of thickened lower continental crust. Zircon Hf isotopes and field distribution of those Paleozoic intrusive rocks reveal that both the Silurian and the late Devonian magmatic activities predominantly represent crustal growth processes in the DTB, accompanied by different degrees of reworking of pre-existing continental crust. However, the middle Carboniferous (ca. 335-315 Ma) magmatic activity reflects a crustal reworking process. The Silurian and late Devonian intrusive rocks were most likely formed in the arc-related subduction zones, whereas, the middle Carboniferous intrusive rocks were possibly formed in a transitional tectonic setting from compression to extension, representing the final stage of Paleozoic orogeny in the DTB. These Paleozoic magmatic rocks further suggest that the DTB has reactivated from a stable block to an orogen and undergone two episodes (the early Paleozoic and the late Paleozoic) of orogeny during Paleozoic. It represents a Paleozoic accretionary orogen of the southernmost margin of the CAOB between the Tarim Craton and North China Craton, and tectonically extends northward to the Beishan orogen and westward to the eastern South Tianshan Belt.
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Characterization of Gas and Particle Emissions from Laboratory Burns of Peat
Peat cores collected from two locations in eastern North Carolina (NC, USA) were burned in a laboratory facility to characterize emissions during simulated field combustion. Particle and gas samples were analyzed to quantify emission factors for particulate matter (PM2.5), organi...
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76 FR 30334 - Combined Notice of Filings
Federal Register 2010, 2011, 2012, 2013, 2014
2011-05-25
...: Docket Numbers: RP11-2067-000. Applicants: Northern Natural Gas Company. Description: Northern Natural Gas Company submits tariff filing per 154.204: 20110401 Section 58 Other Provisions to be effective 6... Company, LP. Description: Panhandle Eastern Pipe Line Company, LP submits tariff filing per 154.204...
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NASA Astrophysics Data System (ADS)
Hong, Keyan; Li, Bo; Zhu, Liangliang; Hu, Xiaolan
2017-06-01
Laifeng-Xianfeng Block whose licensee of exploration belongs to China Huadian Corporation, is located in the west of Hubei province, the eastern edge of the Sichuan Basin and close to the eastern Sichuan high steep fold belt. This block is a mountain landform, in which the geology conditions are complicated. Thus, this paper focuses on 11 two-dimension seismic data and one discovery well in this block. By jointing logging to seismic, the bottom interface of shale gas reservoir in Wufeng-Longmaxi Formation are determined precisely and this type of Formation is characterized by low frequency, strong dual phases, stable distribution, and can be traced in the full-region. Finally, the structure style and distribution of target formations are identified, on the basis of which the integrated evaluation of preservation conditions for shale gas syncline structure is carried out, leading to a selection of Lianghekou Syncline for the best exploration area, which lays a foundation for the future exploration and deployment of shale gas.
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Relationship between deep structure and oil-gas in the eastern Tarim Basin
NASA Astrophysics Data System (ADS)
Yu, Changqing; Qu, Chen; Han, Jianguang
2017-04-01
The Tarim Basin is a large composite superimposed basin which developed in the Presinian continental basement. It is an important area for oil and gas replacement in China. In the eastern part of Tarim Basin, the exploration and research degree is very low and less system, especially in the study of tectonic evolution and physical property change. Basing on the study of geophysics, drilling and regional geological data in this area, analysis of comprehensive geophysical, geological and geophysical analysis comparison are lunched by new methods and new technology of geophysical exploration. Fault, tectonic evolution and change of deep character in the eastern Tarim Basin are analyzed in system. Through in-depth study and understanding of the deep structure and physical changes of the eastern region, we obtain the fault characteristics in the study area and the deep structure and physical change maps to better guide the oil and gas exploration in this area. The east area is located in the eastern Tarim Basin, west from the Garr Man depression, Well Kunan 1 - Well Gucheng 4 line to the East, north to Kuruketage uplift group near Qunke 1 wells, south to Cherchen fault zone, east to Lop Nor depression, an area of about 9 * 104 square kilometres, Including the East of Garr Man sag, Yingjisu depression, Kongquehe slope, Tadong low uplift and the Lop Nor uplift, five two grade tectonic units. The east area of Tarim is belonging to Tarim plate. It changes with the evolution of the Tarim plate. The Tarim plate is closely related to the collision between the Yining - the Junggar plate, the Siberia plate and the southern Qiangtang - the central Kunlun plate. Therefore, it creates a complex tectonic pattern in the eastern Tarim basin. Earth electromagnetic, gravity, deep seismic and other geophysical data are processed by a new generation of geophysical information theory and method, including multi-scale inversion of potential field inversion (Hou and Yang, 2011), 3D magnetotelluric data (Yang et al., 2012) and micro seismic wave field information recognition technology in the eastern Tarim Basin. Combining the information of the deep faults, tectonic evolution characteristics of the study area and the physical changes from geological data, we analyze the relationship between the change of the physical structure and the oil and gas, and predict the favorable oil and gas area and the exploration target area by information extraction, processing and interpretation analysis based on integrated geophysical technology. References 1. Hou, Z. Z., W. C. Yang, 2011, multi scale gravity field inversion and density structure in Tarim Basin: Chinese science, 41, 29-39. 2. Yang W. C., J. L. Wang, H. Z. Zhong, 2012, The main port of the Tarim Basin Analysis of magnetic field and magnetic source structure: Chinese Journal of Geophysics, 55, 1278-1287.
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NASA Astrophysics Data System (ADS)
Owari, S.; Tomaru, H.; Matsumoto, R.
2016-12-01
We have conducted ROV researches in the eastern margin of the Japan Sea where active gas venting and outcropping of gas hydrates were observed near the seafloor and have found the strength and location of venting had changed within a few days. These observations indicate the seafloor environments with the shallow gas hydrate system could have changed for short period compared to a geological time scale. We have applied a long-term osmotic fluid sampling system "OsmoSampler" on the active gas hydrate system for one year in order to document how the gas venting and gas hydrate activity have changed the geochemical environments near the seafloor. All the major ion concentrations in the interstitial water show synchronous increase and decrease repeatedly in three to five days, reflecting the incorporation and release of fresh water in gas hydrates in response to the gas concentration change near the sampling site. Dissolved methane concentration increases rapidly and excessively (over several mM) in the first 40 days corresponding to the active gas venting. The increases of methane concentration are often associated with high ion concentration during high water pressure period, indicating excess gas release from shallow gas pockets. Contrarily, enhanced gas hydrate growth may plug the fluid-gas paths in shallow sediment, reducing gas hydrate formation due to the decrease of methane flux. This study was conducted under the commission from AIST as a part of the methane hydrate research project funded by METI (the Ministry of Economy, Trade and Industry, Japan).
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Basin-centered gas evaluated in Dnieper-Donets basin, Donbas foldbelt, Ukraine
Law, B.E.; Ulmishek, G.F.; Clayton, J.L.; Kabyshev, B.P.; Pashova, N.T.; Krivosheya, V.A.
1998-01-01
An evaluation of thermal maturity, pore pressures, source rocks, reservoir quality, present-day temperatures, and fluid recovery data indicates the presence of a large basin-centered gas accumulation in the Dnieper-Donets basin (DDB) and Donbas foldbelt (DF) of eastern Ukraine (Fig. 1).
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Towards adaptable, interactive and quantitative paleogeographic maps
NASA Astrophysics Data System (ADS)
Wright, N.; Zahirovic, S.; Müller, R. D.; Seton, M.
2012-07-01
A variety of paleogeographic atlases have been constructed, with applications from paleoclimate, ocean circulation and faunal radiation models to resource exploration; yet their uncertainties remain difficult to assess, as they are generally presented as low-resolution static maps. We present a methodology for ground-truthing paleogeographic maps, by linking the GPlates plate reconstruction tool to the global Paleobiology Database and a Phanerozoic plate motion model. We develop a spatio-temporal data mining workflow to compare a Phanerozoic Paleogeographic Atlas of Australia with biogeographic indicators. The agreement between fossil data and paleogeographic maps is quite good, but the methodology also highlights key inconsistencies. The Early Devonian paleogeography of southeastern Australia insufficiently describes the Emsian inundation that is supported by biogeography. Additionally, the Cretaceous inundation of eastern Australia retreats by 110 Ma according to the paleogeography, but the biogeography indicates that inundation prevailed until at least 100 Ma. Paleobiogeography can also be used to refine Gondwana breakup and the extent of pre-breakup Greater India can be inferred from the southward limit of inundation along western Australia. Although paleobiology data provide constraints only for paleoenvironments with high preservation potential of organisms, our approach enables the use of additional proxy data to generate improved paleogeographic reconstructions.
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NASA Astrophysics Data System (ADS)
Wright, N.; Zahirovic, S.; Müller, R. D.; Seton, M.
2013-03-01
A variety of paleogeographic reconstructions have been published, with applications ranging from paleoclimate, ocean circulation and faunal radiation models to resource exploration; yet their uncertainties remain difficult to assess as they are generally presented as low-resolution static maps. We present a methodology for ground-truthing the digital Palaeogeographic Atlas of Australia by linking the GPlates plate reconstruction tool to the global Paleobiology Database and a Phanerozoic plate motion model. We develop a spatio-temporal data mining workflow to validate the Phanerozoic Palaeogeographic Atlas of Australia with paleoenvironments derived from fossil data. While there is general agreement between fossil data and the paleogeographic model, the methodology highlights key inconsistencies. The Early Devonian paleogeographic model of southeastern Australia insufficiently describes the Emsian inundation that may be refined using biofacies distributions. Additionally, the paleogeographic model and fossil data can be used to strengthen numerical models, such as the dynamic topography and the associated inundation of eastern Australia during the Cretaceous. Although paleobiology data provide constraints only for paleoenvironments with high preservation potential of organisms, our approach enables the use of additional proxy data to generate improved paleogeographic reconstructions.
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Potentiometric surface of the Ozark aquifer in northern Arkansas, 2004
Schrader, T.P.
2005-01-01
The Ozark aquifer in northern Arkansas comprises dolomites, limestones, sandstones, and shales of Late Cambrian to Middle Devonian age, and ranges in thickness from approximately 1,100 feet to more than 4,000 feet. Hydrologically, the aquifer is complex, characterized by discrete and discontinuous flow components with large variations in permeability. The potentiometric-surface map, based on 59 well and 5 spring water-level measurements collected in 2004 in Arkansas and Missouri, indicates maximum water-level altitudes of about 1,188 feet in Benton County and minimum water-level altitudes of about 116 feet in Randolph County. Regionally, the flow within the aquifer is to the south and southeast in the eastern and central part of the study area and to the northwest and north in the western part of the study area. Comparing the 2004 potentiometric- surface map with a predevelopment potentiometricsurface map indicates general agreement between the two surfaces. Potentiometric-surface differences could be attributed to differences in pumping related to changing population from 1990 to 2000, change in source for public supplies, processes or water use outside the study area, or differences in data-collection or map-construction methods.
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Topkaya, Aynur Eren; Balıkcı, Ahmet; Aydın, Faruk; Hasçelik, Gülşen; Kayman, Tuba; Kesli, Recep; Aydemir, Söhret; Akyar, Işın; Gökalp, Aslı; Dündar, Günnur; Gürler, Nezahat; Perçin, Duygu; Fındık, Duygu; Avunduk, Haluk; Bayraktar, Banu
2014-01-01
A one-year active surveillance study was conducted to investigate the epidemiological and microbiological characteristics of invasive group A streptococci (GAS) infections in Turkey and to provide data for the establishment of national preventive strategies related to invasive GAS infections. A total of 46 clinical microbiology laboratories from 12 different regions of Turkey (Istanbul; Eastern and Western Marmara; Eastern and Western Blacksea; Aegean; Mediterranean; Western, Central, Northeastern, Middle-eastern and Southeastern Anatolia) participated in the study. Accordingly, GAS strains isolated from sterile body sites (blood, cerebrospinal, synovial, pleural, peritoneal, pericardial fluids) in the study centers between June 2010-June 2011, were sent to Maltepe University Hospital Clinical Microbiology Laboratory for microbiological confirmation and further analysis. The isolates were identified by conventional methods, and for serotyping, opacity factor (OF) and T protein types were investigated. For genotyping GAS lysate preparation, emm gene amplification and sequencing were performed by using the protocols recommended by Centers for Disease Control and Prevention. A total of 65 invasive GAS strains were isolated in 15 of the participant centers, during the study period. The rate of invasive GAS isolation exhibited regional variation, with the highest rates in the Eastern Blacksea (Trabzon, n= 19), followed by Istanbul (n= 17) and Western Anatolia (Ankara, Konya, n= 14). Of the patients with invasive GAS infection 33 were female, 32 were male, with the age range of 0-89 years. GAS strains were most commonly isolated from soft tissue specimens (n= 18), followed by abscess material (n= 10), sterile body fluids (n= 8) and blood (n= 7) samples. Serotyping revealed that 55% (36/65) of the strains were OF positive, and the majority of T protein was polygroup T (n= 20), followed by U (n= 14), B (n= 5), X (n= 3) and Y (n= 2). T protein was not detected in 22 isolates. The strains were found to have 17 different emm types;emm1 (n= 13), emm4 (n= 6), emm6 (n= 6), emm12 (n= 6), emm24 (n= 4), emm14 (n= 3) and emm28 (n= 3). Nine of the strains could not be typed by sequencing. The correlation between emm typing and serotyping was detected as 58%. It was observed that 26-valent vaccines included 70.5% of the invasive GAS strains included in this study. Our study provided initial data concerning the epidemiological properties of invasive GAS infections and characterization of GAS strains in Turkey. The incidence of invasive GAS infections is low in our country. Although immunization programme by 26-valent GAS vaccine is not currently an urgent public health issue for our country, the results of this study indicated that emm types 4 and 24 should better be included in such a vaccine to be used in Turkey. Additionally, since epidemiological features of GAS infections and the microbiological characteristics of the strains can vary by time, for the diagnosis of invasive streptococcal infections and to take the necessary preventive measures, epidemiological studies should be conducted repeatedly.
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Habitat loss and modification due to gas development in the Fayetteville shale.
Moran, Matthew D; Cox, A Brandon; Wells, Rachel L; Benichou, Chloe C; McClung, Maureen R
2015-06-01
Hydraulic fracturing and horizontal drilling have become major methods to extract new oil and gas deposits, many of which exist in shale formations in the temperate deciduous biome of the eastern United States. While these technologies have increased natural gas production to new highs, they can have substantial environmental effects. We measured the changes in land use within the maturing Fayetteville Shale gas development region in Arkansas between 2001/2002 and 2012. Our goal was to estimate the land use impact of these new technologies in natural gas drilling and predict future consequences for habitat loss and fragmentation. Loss of natural forest in the gas field was significantly higher compared to areas outside the gas field. The creation of edge habitat, roads, and developed areas was also greater in the gas field. The Fayetteville Shale gas field fully developed about 2% of the natural habitat within the region and increased edge habitat by 1,067 linear km. Our data indicate that without shale gas activities, forest cover would have increased slightly and edge habitat would have decreased slightly, similar to patterns seen recently in many areas of the southern U.S. On average, individual gas wells fully developed about 2.5 ha of land and modified an additional 0.5 ha of natural forest. Considering the large number of wells drilled in other parts of the eastern U.S. and projections for new wells in the future, shale gas development will likely have substantial negative effects on forested habitats and the organisms that depend upon them.
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Chris A. Maier; R.O. Teskey
1992-01-01
Leaf gas exchange and water relations were monitored in the upper canopy of two 25 m tall eastern white pine (Pinus strobus L.) trees over two consecutive growing seasons (1986 and 1987). Examination of the seasonal and diurnal patterns of net photosynthesis and leaf conductance showed that both internal and external (environmental) factors were...
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Federal Register 2010, 2011, 2012, 2013, 2014
2013-12-04
... of the Proposed Notice of Sale (NOS) for Eastern Gulf of Mexico Planning Area (EPA) Outer Continental Shelf (OCS) Oil and Gas Lease Sale 225 (EPA Sale 225) AGENCY: Bureau of Ocean Energy Management (BOEM), Interior. ACTION: Notice of Availability of the Proposed Notice of EPA Sale 225. SUMMARY: BOEM announces...
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NASA Astrophysics Data System (ADS)
Matsumoto, R.
2014-12-01
Agency of Natural Resources and Energy of METI launched a 3 years shallow gas hydrate exploration project in 2013 to make a precise resource assessment of shallow gas hydrates in the eastern margin of Japan Sea and around Hokkaido. Shallow gas hydrates of Japan Sea occur in fine-grained muddy sediments of shallow subsurface of mounds and gas chimneys in the form of massive nodular to platy accumulation. Gas hydrate bearing mounds are often associated with active methane seeps, bacterial mats and carbonate concretions and pavements. Gases of gas hydrates are derived either from deep thermogenic, shallow microbial or from the mixed gases, contrasting with totally microbial deep-seated stratigraphically controlled hydrates. Shallow gas hydrates in Japan Sea have not been considered as energy resource due to its limited distribution in narrow Joetsu basin. However recently academic research surveys have demonstrated regional distribution of gas chimney and hydrate mound in a number of sedimentary basins along the eastern margin of Japan Sea. Regional mapping of gas chimney and hydrate mound by means of MBES and SBP surveys have confirmed that more than 200 gas chimneys exist in 100 km x 100 km area. ROV dives have identified dense accumulation of hydrates on the wall of half collapsed hydrate mound down to 30 mbsf. Sequential LWD and shallow coring campaign in the Summer of 2014, R/V Hakurei, which is equipped with Fugro Seacore R140 drilling rig, drilled through hydrate mounds and gas chimneys down to the BGHS (base of gas hydrate stability) level and successfully recovered massive gas hydrates bearing sediments from several horizons.
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76 FR 48838 - Combined Notice of Filings No. 1
Federal Register 2010, 2011, 2012, 2013, 2014
2011-08-09
...: Docket Numbers: RP11-2331-000. Applicants: Natural Gas Pipeline Company of America LLC. Description: Natural Gas Pipeline Company of America LLC submits tariff filing per 154.402: Annual Charge Adjustment to... p.m. Eastern Time on Monday, August 15, 2011. Docket Numbers: RP11-2340-000. Applicants: Discovery...
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Water resources of the Clarion River and Redbank Creek basins, northwestern Pennsylvania
Buckwalter, Theodore F.; Dodge, C.H.; Schiner, G.R.; Koester, H.F.
1981-01-01
The Clarion River and Redbank Creek basin occupy 1,280 and 545 square miles, respectively, in northwatern Pennsylvania. The area is mostly in Clerion, Elk, and Jefferson Counties and is approximately 70 miles long and 30 miles wide. All drainage is to the Allegheny River. Sedimentary rocks of Late Devionian Early Mississippian, and Pennsylvanian age underlie the area. Rocks of Late Devonian age underlie the entire area and crop out in the deep stream valleys in the north. Lower Mississippian rocks generally crop out in strips along major stream valleys; the strips are narrow in the south and broaden northward. Pennsylvanian rocks cover most of the interfluvial areas between major streams. The Upper Devonian and Lower Mississippian rocks are composed mostly of alternating sandstone and shale. Sandstone may intertongue laterally with shale. The Pennsylvanian rocks are most heterogeneous and contain many commercial coal beds. The major mineral resources are bituminous coal, petroleum, and natural gas. Narly all coal production is from strip mining in Clarion, Elk, and Jefferson Counties. Total coal production exceeded 8 million short tons in 1976. The basins are south and east of the major oil-producing regions in Pennsylvania, but more than 50,000 barrels of crude oil were produced here in 1975. Commercial quantities of natural gas are also obtained. Thirty-three public water-supply systems furnish about two-thirds of the water for domestic use. Surface water is the source of about 90 percent of public-supply water. The remainder is from wells and springs. In an average year, 64 percent of the precipitation in the Clarion River basin and 60 percent in the Redbank Creek basin leave the area as streamflow. The percentage of annuual discharge from each basin that is base runoff averaged 53 and 51 percent, respectively, during 1972-75. Only 4 of 10 stream-gaging stations recorded an average 10-year, 7-consecutive day low flow of at least 0.15 cubic feet per second per square mile. Most wells are completed on bedrock. Yields of bedrock wells are affected mostly by rock type, type of overburden, topography, depth of water-bearing zones, and by the rate and duration of pumping. Water in the bedrock occurs chiefly along fractures and bedding planes. Most wells get water from several zones. Yielding zones occur less frequently as depth increases, but are reported as much as 400 feet below land surface. Optimum well depth is about 350 feet. Well yields range from less than 1 to more than 550 gallons per minute. The best bedrock aquifers are the Lower Mississippian rocks, which have a median specific capacity of 4.3 gallons per minute per foot of drawdown compared to median between 0.38 and 0.67 in the Conemaugh, Allegheny, and Pottsville Groups. The major water-qualitty problems are due to high concentrations of iron, manganese, hardness, and acidity. Some of these problems are related to coal mining that has degraded water quality in parts of Clarion, Clearfield, Elk, and Jefferson Counties. Water-quality problems result from the rock composition. Many streams have low alkalinity concentrations and, consequently, have little capacity to neutralize the acid water from coal mines. Large forested areas, with little development, in Elk, Forest, and Jefferson Counties, have good quality water. The water from over three-quarters of the bedrock wells sampled has dissolved-solids concentratins less than 250 milligrams per liter. Water from aqufers of Pennsylvanian age is generally lower in dissolved solids than that from Lower Mississippian aquifers. Salt water is not a problem, except locally in Devonian rocks. Water from wells on hilltops is generally of better quality than that from wells in valleys (median dissolved solids 140 versus 340 millgrams per liter). In many valleys in Clarion and Jefferson Counties, old abandoned flowing oil and gas wells contribute high
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NASA Astrophysics Data System (ADS)
Hrouda, F.; Schulmann, K.; Chlupacova, M.; Aichler, J.; Mixa, P.; Pecina, V.; Zacek, V.; Kroener, A.
2003-04-01
The eastern Variscan front at the Czech and Polish border is characterised by oblique underthrusting of Neo-Proterozoic continental margin below thickened crustal root. The underthrust plate is subsequently imbricated and forms obliquely convergent crustal wedge which was further thrust over the foreland. Several granitic plutons of arc geochemical affinity are intruded during different stages of crustal thickening and exhumation. Analysis of anisotropy of magnetic susceptibility was carried out to study the relationships between host rock deformation and magma emplacement fabrics in different crustal levels and geographical positions with respect to crustal wedge and westerly orogenic root. Deep seated granodiorite sheets (Javornik intrusion 348 Ma, and Stare Mesto sill 340 Ma) are emplaced in the deepest and more internal high grade parts of the orogen along the margin of thickened crustal root. They show AMS fabrics entirely concordant with surrounding high grade gneisses and were emplaced during contractional (transpressive) regime.The Sumperk granodiorite is a more shallow intrusion emplaced in the central part of the crustal wedge. This sheet-like intrusion shows its AMS fabrics conformable to transpressional fabrics of surrounding mylonitised barovian schists and gneisses. The Zulova Pluton 330 Ma, representing the shallowest intrusion, intrudes the most external part of the crustal wedge. It shows the magnetic fabrics virtually perpendicular to compressional structures in the neighbouring areas. In addition, these fabrics are clearly concordant with large-scale detachment zone along which the Devonian meta-sedimentary cover slided to the west. The AMS fabrics of granitoids thus testify the progressive oblique convergence prograding to the east followed by collapse of external part of orogenic wedge. The AMS fabric data allow us to evaluate the mechanical role of arc magmas syntectonically emplaced during oblique convergence and finally during normal shearing perpendicular to the orogen.
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NASA Astrophysics Data System (ADS)
Phillips, G.; Offler, R.; Rubatto, D.; Phillips, D.
2015-09-01
New geochemical, metamorphic, and isotopic data are presented from high-pressure metamorphic rocks in the southern New England Orogen (eastern Australia). Conventional and optimal thermobarometry are augmented by U-Pb zircon and 40Ar/39Ar phengite dating to define pressure-temperature-time (P-T-t) histories for the rocks. The P-T-t histories are compared with competing geodynamic models for the Tasmanides, which can be summarized as (i) a retreating orogen model, the Tasmanides formed above a continuous, west dipping, and eastward retreating subduction zone, and (ii) a punctuated orogen model, the Tasmanides formed by several arc accretion, subduction flip, and/or transference events. Whereas both scenarios are potentially supported by the new data, an overlap between the timing of metamorphic recrystallization and key stages of Tasmanides evolution favors a relationship between a single, long-lived subduction zone and the formation, exhumation, and exposure of the high-pressure rocks. By comparison with the retreating orogen model, the following links with the P-T-t histories emerge: (i) exhumation and underplating of oceanic eclogite during the Delamerian Orogeny, (ii) recrystallization of underplated and exhuming high-pressure rocks at amphibolite facies conditions coeval with a period of rollback, and (iii) selective recrystallization of high-pressure rocks at blueschist facies conditions, reflecting metamorphism in a cooled subduction zone. The retreating orogen model can also account for the anomalous location of the Cambrian-Ordovician high-pressure rocks in the Devonian-Carboniferous New England Orogen, where sequential rollback cycles detached and translated parts of the leading edge of the overriding plate to the next, younger orogenic cycle.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Witzke, B.J.; Bunker, B.J.
1994-04-01
Ongoing studies of the Cedar Valley Group were fortuitously aided by the exhumation of Rapid Mbr (Little Cedar Fm) carbonate strata below the coralville spillway, Johnson Co., Iowa, during the summer floods of 1993. Extensive bedding-plane exposures provided an exceptional opportunity to document fine-scale lateral biotic and lithologic variations within the member, and to compare these with data from elsewhere in eastern Iowa. The base of the Rapid Mbr is drawn at an abrupt lithic change above packstones of the Solon Mbr, marking a regional transgressive event. The basal 2.6 m of the Rapid is dominated by argillaceous skeletal wackestonesmore » with common brachiopods and echinoderm debris, interspersed with thin mudstones. The overlying 4 m comprises a series of 50--100 cm thick couplets which display alternations of thin mudstones and thicker brachiopod-rich wackepackstones. The next unit (2.9 m) is dominated by sparse-skeletal argillaceous mudstones. The paucity of burrowing and skeletal benthos through much of the unit is interpreted to reflect bottom oxygen stress in a relatively deep, possibly stratified cratonic seaway. Nevertheless, skeletal horizons within the unit indicate episodically favorable benthic conditions. The mudstone unit shallows upward into a brachiopod-rich wackestone interval which is, in turn, capped by a condensed horizon of phosphatic and glauconitic enrichment (near base of subterminus Fauna). Above this, two regionally extensive coral-rich biostromes occur. Upper Rapid strata show a complex of wackestone and packstone facies, with glauconitic enrichment and hardgrounds noted. The member is capped by shoal-water grainstones in the Coralville area, and by peritidal facies in northern Iowa.« less
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Desborough, George A.; Poole, F.G.; Hose, R.K.; Radtke, A.S.
1979-01-01
A kerogen-rich sequence of siliceous mudstone, siltstone, and chert as much as 60 m thick on ridge 7129 in the southern Fish Creek Range, referred to as Gibellini facies of the Woodruff Formation, has been evaluated on the surface and in drill holes principally for its potential resources of vanadium, zinc, selenium, molybdenum, and syncrude oil content. The strata are part of a strongly deformed allochthonous mass of eugeosynclinal Devonian marine rocks that overlie deformed allochthonous Mississippian siliceous rocks and relatively undeformed autochthonous Mississippian Antler flysch at this locality. The vanadium in fresh black rocks obtained from drill holes and fresh exposures in trenches and roadcuts occurs chiefly in organic matter. Concentrations of vanadium oxide (V2O5) in unoxidized samples range from 3,000 to 7,000 ppm. In oxidized and bleached rock that is prevalent at the surface, concentrations of vanadium oxide range from 6,000 to 8,000 ppm, suggesting a tendency toward enrichment due to surficial weathering and ground-water movement. Zinc occurs in sphalerite, and selenium occurs in organic matter; molybdenum appears to occur both in molybdenite and in organic matter. Concentrations of zinc in unoxidized rock range from 4,000 to 18,000 ppm, whereas in oxidized rock they range from 30 to 100 ppm, showing strong depletion due to weathering. Concentrations of selenium in unoxidized rock range from 30 to 200 ppm, whereas in oxidized rock they range from 200 to 400 ppm, indicating some enrichment upon weathering. Concentrations of molybdenum in unoxidized rock range from 70 to 960 ppm, whereas in oxidized rock they range from 30 to 80 ppm, indicating strong depletion upon weathering. Most fresh black rock is low-grade oil shale, and yields as much as 12 gallons/short ton of syncrude oil. Metahewettite is the principal vanadium mineral in the oxidized zone, but it also occurs sparsely as small nodules and fillings of microfractures in unweathered strata. In fresh rock, bluish-white opaline-like silica (chalcedonic quartz) fills microfractures, and is believed to have originated by diagenetic mobilization of opaline silica from radiolarian tests and sponge spicules. As revealed by microscopic study, the Gibellini facies originally consisted of siliceous muds, slimes, and oozes high in organic constituents. The organic matter is amorphous flaky and stringy sapropel, and probably includes remains of bacteria, phytoplankton, zooplankton, and minor higher plants. Recognizable organic remnants include radiolarian tests, sponge spicules, conodonts, brachiopod shells, algae, and humic debris. Diagnostic radiolarians indicate a Late Devonian age for the Gibellini facies of the Woodruff Formation. Some pyrite is disseminated through the rock and may be primary (syngenetic) but significant pyrite and marcasite occur in chalcedonic quartz veinlets and appear to be diagenetic. In fresh rock, black solid bitumen and liquid oil fill voids and microfractures. These early phase hydrocarbons probably were released during diagenesis from complex nonhydrocarbon molecular structures originating from living organisms, and formed without any major thermal degradation of the kerogen. Gas chromatographic analysis of the saturated hydrocarbon fraction indicates a very complex mixture dominated by branched and cyclic compounds. Conodont and palynomorph color alteration, vitrinite reflectance, and other organic geochemical data suggest that the organic matter in the rock is thermally immature and has not been subjected to temperatures greater than 60?C since deposition in Devonian time. All of these characteristics are consistent with the interpretation of a relatively low temperature and a shallow-burial history for the Gibellini facies on ridge 7129.
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Blodgett, R.B.; Johnson, J.G.
1994-01-01
The brachiopod genus Verneuilia Hall and Clarke, 1893, is recognized for the first time in North America, where it is represented by a new species described here. V. langenstrasseni. This occurrence extends not only the geographic range of the genus, but also the lower age and stratigraphic limit into the Eifelian (early Middle Devonian). Previously, the oldest known species was the type, V. cheiropteryx d'Archiac and de Verneuil, 1842, from the Givetian (late Middle Devonian) of Germany. Internal structures of V. langenstrasseni n.sp. are similar to those of genera in the ambocoeliid subfamily Rhynchospiriferinae, providing the first good evidence of a systematic relationship. -Authors
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Lyman, Seth N; Watkins, Cody; Jones, Colleen P; Mansfield, Marc L; McKinley, Michael; Kenney, Donna; Evans, Jordan
2017-10-17
We measured fluxes of methane, nonmethane hydrocarbons, and carbon dioxide from natural gas well pad soils and from nearby undisturbed soils in eastern Utah. Methane fluxes varied from less than zero to more than 38 g m -2 h -1 . Fluxes from well pad soils were almost always greater than from undisturbed soils. Fluxes were greater from locations with higher concentrations of total combustible gas in soil and were inversely correlated with distance from well heads. Several lines of evidence show that the majority of emission fluxes (about 70%) were primarily due to subsurface sources of raw gas that migrated to the atmosphere, with the remainder likely caused primarily by re-emission of spilled liquid hydrocarbons. Total hydrocarbon fluxes during summer were only 39 (16, 97)% as high as during winter, likely because soil bacteria consumed the majority of hydrocarbons during summer months. We estimate that natural gas well pad soils account for 4.6 × 10 -4 (1.6 × 10 -4 , 1.6 × 10 -3 )% of total emissions of hydrocarbons from the oil and gas industry in Utah's Uinta Basin. Our undisturbed soil flux measurements were not adequate to quantify rates of natural hydrocarbon seepage in the Uinta Basin.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1990-11-01
This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivitymore » values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.« less
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A new osteichthyan from the late Silurian of Yunnan, China.
Choo, Brian; Zhu, Min; Qu, Qingming; Yu, Xiaobo; Jia, Liantao; Zhao, Wenjin
2017-01-01
Our understanding of early gnathostome evolution has been hampered by a generally scant fossil record beyond the Devonian. Recent discoveries from the late Silurian Xiaoxiang Fauna of Yunnan, China, have yielded significant new information, including the earliest articulated osteichthyan fossils from the Ludlow-aged Kuanti Formation. Here we describe the partial postcranium of a new primitive bony fish from the Kuanti Formation that represents the second known taxon of pre-Devonian osteichthyan revealing articulated remains. The new form, Sparalepis tingi gen. et sp. nov., displays similarities with Guiyu and Psarolepis, including a spine-bearing pectoral girdle and a placoderm-like dermal pelvic girdle, a structure only recently identified in early osteichthyans. The squamation with particularly thick rhombic scales shares an overall morphological similarity to that of Psarolepis. However, the anterior flank scales of Sparalepis possess an unusual interlocking system of ventral bulges embraced by dorsal concavities on the outer surfaces. A phylogenetic analysis resolves Sparalepis within a previously recovered cluster of stem-sarcopterygians including Guiyu, Psarolepis and Achoania. The high diversity of osteichthyans from the Ludlow of Yunnan strongly contrasts with other Silurian vertebrate assemblages, suggesting that the South China block may have been an early center of diversification for early gnathostomes, well before the advent of the Devonian "Age of Fishes".
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Yao, Le; Aretz, Markus; Chen, Jitao; Webb, Gregory E.; Wang, Xiangdong
2016-01-01
Microbial carbonates commonly flourished following mass extinction events. The end-Devonian (Hangenberg) mass extinction event is a first-order mass extinction on the scale of the ‘Big Five’ extinctions. However, to date, it is still unclear whether global microbial carbonate proliferation occurred after the Hangenberg event. The earliest known Carboniferous stromatolites on tidal flats are described from intertidal environments of the lowermost Tournaisian (Qianheishan Formation) in northwestern China. With other early Tournaisian microbe-dominated bioconstructions extensively distributed on shelves, the Qianheishan stromatolites support microbial carbonate proliferation after the Hangenberg extinction. Additional support comes from quantitative analysis of the abundance of microbe-dominated bioconstructions through the Famennian and early Tournaisian, which shows that they were globally distributed (between 40° latitude on both sides of the palaeoequator) and that their abundance increased distinctly in the early Tournaisian compared to the latest Devonian (Strunian). Comparison of variations in the relative abundance of skeleton- versus microbe-dominated bioconstructions across the Hangenberg and ‘Big Five’ extinctions suggests that changes in abundance of skeletal bioconstructors may play a first-order control on microbial carbonate proliferation during extinction transitions but that microbial proliferation is not a general necessary feature after mass extinctions. PMID:28009013
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Pawlewicz, Mark
2006-01-01
Three total petroleum systems were identified in the North Carpathian Province (4047) that includes parts of Poland, Ukraine, Austria, and the Czech Republic. They are the Isotopically Light Gas Total Petroleum System, the Mesozoic-Paleogene Composite Total Petroleum System, and the Paleozoic Composite Total Petroleum System. The Foreland Basin Assessment Unit of the Isotopically Light Gas Total Petroleum System is wholly contained within the shallow sedimentary rocks of Neogene molasse in the Carpathian foredeep. The biogenic gas is generated locally as the result of bacterial activity on dispersed organic matter. Migration is also believed to be local, and gas is believed to be trapped in shallow stratigraphic traps. The Mesozoic-Paleogene Composite Total Petroleum System, which includes the Deformed Belt Assessment Unit, is structurally complex, and source rocks, reservoirs, and seals are juxtaposed in such a way that a single stratigraphic section is insufficient to describe the geology. The Menilite Shale, an organic-rich rock widespread throughout the Carpathian region, is the main hydrocarbon source rock. Other Jurassic to Cretaceous formations also contribute to oil and gas in the overthrust zone in Poland and Ukraine but in smaller amounts, because those formations are more localized than the Menilite Shale. The Paleozoic Composite Total Petroleum System is defined on the basis of the suspected source rock for two oil or gas fields in western Poland. The Paleozoic Reservoirs Assessment Unit encompasses Devonian organic-rich shale believed to be a source of deep gas within the total petroleum system. East of this field is a Paleozoic oil accumulation whose source is uncertain; however, it possesses geochemical similarities to oil generated by Upper Carboniferous coals. The undiscovered resources in the North Carpathian Province are, at the mean, 4.61 trillion cubic feet of gas and 359 million barrels of oil. Many favorable parts of the province have been extensively explored for oil and gas. The lateral and vertical variability of the structure, the distribution and complex geologic nature of source rocks, and the depths of potential exploration targets, as well as the high degree of exploration, all indicate that future discoveries in this province are likely to be numerous but in small fields.
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NASA Astrophysics Data System (ADS)
Brand, Uwe
1989-12-01
A progressive trend towards heavier δ 13C values of Devonian-Mississippian brachiopods from North America, Europe, Afghanistan and Algeria probably reflects expansion of the terrestrestrial and/or marine biomass and/or burial of carbon in soils/sediments. Oceanic Productivity crises, based on perturbations in the overall δ 13C trend, are recognized for the Mid Givetian, Early Famennian, Late Kinderhookian, Late Osagean and Early and Late Meramecian. The Givetian productivity crisis was probably accompanied by massive overturn of biologically toxic deep-ocean water. Temperature data, adjusted for the possible secular variation of seawater, support the hypothesis of global greenhouse conditions for the Devonian (mean of 30°C, mean of 26°C if extrinsic data are deleted) and icehouse conditions for the Mississippian (mean of 17°C). During the Mid Givetian, Frasnian and Early Famennian calculated water temperatures for tropical epeiric seas were generally above the thermal threshold limit (˜ 38°C) of most marine invertebrates or epeiric seawater was characterized by unusually low salinities (˜ pp ppt) or a combination of the two. These elevated water temperatures and/or low salinities, in conjunction with the postulated productivity crises and overturning of toxic deep waters are considered prime causes for the biotic crisis of the Late Devonian. In addition, a presumed expanding oxygen-minimum zone and general anoxia in the oceans prevented shallow-water organisms from escaping these inhospitable conditions. Re-population of the tropical seas occurred, after either water temperatures had dropped below the thermal threshold limit and/or salinities were back to normal, and oceanic productivity had increased due to more vigorous oceanic circulation, sometime during the Mid-Late Famennian. Migration of eurythermal, shallow- and deeper-water organisms into the vacant niches of the shallow seas was possible because of, generally, slightly lower sea levels, but, more importantly of more restricted oxygen-minimum zone and generally reduced oceanic anoxia.
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A new Late Devonian genus with seed plant affinities.
Wang, Deming; Liu, Le
2015-02-26
Many ovules of Late Devonian (Famennian) seed plants have been well studied. However, because few taxa occur with anatomically preserved stems and/or petioles, the vascular system of these earliest spermatophytes is little understood and available data come mostly from Euramerica. There remains great controversy over the anatomical differentiation of Late Devonian and Carboniferous seed plant groups of Buteoxylonales, Calamopityales and Lyginopteridales. Protostele evolution of these early spermatophytes needs more research. A new taxon Yiduxylon trilobum gen. et sp. nov. with seed plant affinities has been discovered in the Upper Devonian (Famennian) Tizikou Formation of Hubei Province, China. It is represented by stems, helically arranged and bifurcate fronds with two orders of pinnae and planate pinnules. Both secondary pinnae and pinnules are borne alternately. Stems contain a small protostele with three primary xylem ribs possessing a single peripheral protoxylem strand. Thick secondary xylem displays multiseriate bordered pitting on the tangential and radial walls of the tracheids, and has biseriate to multiseriate and high rays. A narrow cortex consists of inner cortex without sclerotic nests and sparganum-type outer cortex with peripheral bands of vertically aligned sclerenchyma cells. Two leaf traces successively arise tangentially from each primary xylem rib and they divide once to produce four circular-oval traces in the stem cortex. Four vascular bundles occur in two C-shaped groups at each petiole base with ground tissue and peripheral bands of sclerenchyma cells. Yiduxylon justifies the assignment to a new genus mainly because of the protostele with protoxylem strands only near the periphery of primary xylem ribs, leaf trace origination and petiolar vascular supply structure. It shares many definitive characters with Calamopityales and Lyginopteridales, further underscoring the anatomical similarities among early seed plants. The primary vascular system, pycnoxylic-manoxylic secondary xylem with bordered pits on both tangential and radial walls of a tracheid and leaf trace divergence of Yiduxylon suggest transitional features between the early spermatophytes and ancestral aneurophyte progymnosperms.
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New Plants from the Lower Devonian Pingyipu Group, Jiangyou County, Sichuan Province, China
Edwards, Dianne; Geng, Bao-Yin; Li, Cheng-Sen
2016-01-01
Descriptions of Lower Devonian plants from Yunnan, South China, have revolutionized concepts of diversity and disparity in tracheophytes soon after they became established on land. Sichuan assemblages have received little attention since their discovery almost 25 years ago and require revision. With this objective, fieldwork involving detailed logging and collection of fossils was undertaken in the Longmenshan Mountain Region, Jiangyou County and yielded the two new taxa described here. They are preserved as coalified compressions and impressions that allowed morphological but not anatomical analyses. Yanmenia (Zosterophyllum) longa comb nov is based on numerous rarely branching shoots with enations resembling lycophyte microphylls, without evidence for vasculature. The presence of sporangia is equivocal making assignation to the Lycopsida conjectural. The plant was recently described as a zosterophyll, but lacks strobili. These are present in the second plant and comprise bivalved sporangia. The strobili terminate aerial stems which arise from a basal axial complex displaying diversity in branching including H- and K- forms. These features characterise the Zosterophyllopsida, although the plant differs from Zosterophyllum in valve shape. Comparisons indicate greatest similarities to the Lower Devonian Guangnania cuneata, from Yunnan, but differences, particularly in the nature of the sporangium border, require the erection of a new species, G. minor. Superficial examination of specimens already published indicate a high degree of endemism at both species and generic level, while this study shows that Yanmenia is confined to Sichuan and Guangnania is one of the very few genera shared with Yunnan, where assemblages also show a high proportion of further endemic genera. Such provincialism noted in the Chinese Lower Devonian is explained by the palaeogeographic isolation of the South China plate, but this cannot account for differences/endemism between the Sichuan and Yunnan floras. Such an enigma demands further integrated geological, palaeobotanical and palynological studies. PMID:27851760
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NASA Astrophysics Data System (ADS)
Veselovskiy, Roman V.; Bazhenov, Mikhail L.; Arzamastsev, Andrey A.
2016-04-01
Mafic dykes and large alkaline and carbonatite intrusions of Middle-Late Devonian age are widespread on the Kola Peninsula in NE Fennoscandia. These magmatic rocks are well characterized with petrographic, geochemical and geochronological data but no paleomagnetic results have been reported yet. We studied dolerite dykes from the northern part of the Peninsula and isolated three paleomagnetic components in these rocks. A low-temperature component is aligned along the present-day field, while a major constituent of natural remanent magnetization is an intermediate-temperature component (Decl. = 79.6°, Inc. = 78.5°, α95 = 5,9°, N = 17 sites) that is present in most Devonian dykes but is found in some baked metamorphic rocks and Proterozoic dykes too. Finally, a primary Devonian component could be reliably isolated from two dykes only. Rock-magnetic studies point to presumably primary low-Ti titanomagnetite and/or pure magnetite as the main remanence carriers but also reveal alteration of the primary minerals and the formation of new magnetic phases. The directions of a major component differ from the Middle Paleozoic reference data for Baltica but closely match those for the 190 ± 10 Ma interval recalculated from the apparent polar wander path of the craton. We assume that this Early Jurassic component is a low-temperature overprint of chemical origin. The main impact of the new results is not to mid-Paleozoic or Early Mesozoic times but to much older epochs. Analysis of paleomagnetic data shows that the directionally similar remanences are present in objects with the ages ranging from 500 Ma to 2 Ga over entire Fennoscandia. Hence we argue that an Early Jurassic remagnetization is of regional extent but cannot link it to a certain process and a certain tectonic event. If true, this hypothesis necessitates a major revision of the APWP for Baltica over a wide time interval.
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Federal Register 2010, 2011, 2012, 2013, 2014
2013-06-27
... application under Section 7 of the Natural Gas Act and Part 157 the Commission's Rules and Regulations for...-388 at Texas Eastern Transmission, LP-- Summerfield, Tennessee Gas--Pipeline-Gilmore, Rockies Express... Utica Shale production for processing at one of Blue Racer's plants--Natrium, Lewis or Berne. Blue Racer...
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USDA-ARS?s Scientific Manuscript database
Essential oils obtained by hydrodistillation were analyzed both by gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). The main constituents found in Achillea oil were as follows: A. filipendulina Lam.: 43.8% santolina alcohol, 14.5% 1,8-cineole and 12.5% cis-chrysanthenyl acet...
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NASA Astrophysics Data System (ADS)
Derder, M. E. M.; Maouche, S.; Liégeois, J. P.; Henry, B.; Amenna, M.; Ouabadi, A.; Bellon, H.; Bruguier, O.; Bayou, B.; Bestandji, R.; Nouar, O.; Bouabdallah, H.; Ayache, M.; Beddiaf, M.
2016-03-01
Intraplate deformation is most often linked to major stress applied on plate margins. When such intraplate events are accompanied by magmatism, the use of several dating methods integrated within a multidisciplinary approach can bring constraints on the age, nature and source mobilized for generating the magma and in turn on the nature of the intraplate deformation. This study focuses on the large gabbro Arrikine sill (35 km in extension) emplaced within the Silurian sediments of the western margin of the Murzuq cratonic basin in southeastern Algeria. Its emplacement is dated during the early Devonian (415-400 Ma) through the determination of a reliable paleomagnetic pole by comparison with the Gondwana Apparent Polar Wander Path (APWP). This age can be correlated with deep phreatic eruptions before Pragian time thought to be at the origin of sand injections and associated circular structures in Algeria and Libya. For the sill, the K-Ar age of 325.6 ± 7.7 Ma is related to a K-rich aplitic phase that has K-enriched by more than 20% the Devonian gabbro. Laser-ICP-MS U-Pb method dates only inherited zircons mostly at c. 2030 Ma with additional ages at c. 2700 Ma and younger ones in the 766-598 Ma age range. The Arrikine sill is a high-Ti alkaline gabbro having the geochemical composition of a hawaiite akin to several intraplate continental and oceanic provinces, including the contemporaneous Aïr ring complexes province in Niger, but also to the Mauna Loa volcano in Hawaii. This peculiar composition akin to that of the contemporaneous Aïr province is in agreement with a lower Devonian age for the Arrikine sill. The lower Devonian Arrikine sill emplacement is related to a "Caledonian" transtensive reactivation of the western metacratonic boundary of the Murzuq craton. This event also generated in the Saharan platform the so-called "Caledonian unconformity" of regional extension, the Aïr ring complexes and magmatic rocks that produced sand injections. It could be related to rifting of the Hun terranes that occurred at the plate margin to the north (Stampfli and Borel, 2002, Blackey, 2008 and references therein). The mid-Carboniferous (c. 326 Ma) reactivation corresponds to Variscan compression on NW Africa generating aplitic fluids, but also to the major "Hercynian unconformity" of regional extension. The generation of the Arrikine magma is attributed to partial melting through adiabatic pressure release of uprising asthenosphere along tectonically reactivated mega-shear zones, here bordering the relictual Murzuq craton enclosed in the Saharan metacraton.
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NASA Astrophysics Data System (ADS)
Bábek, Ondřej; Faměra, Martin; Šimíček, Daniel; Weinerová, Hedvika; Hladil, Jindřich; Kalvoda, Jiří
2018-01-01
The Devonian marine stratigraphic record is characterized by a number of bioevents - overturns in pelagic and benthic faunal assemblages, which are associated with distinct changes in lithology. The coincidence of lithologic and biotic changes can be explained by the causal link between biotic evolution, carbonate production and relative sea-level changes. To gain insight into the sea-level history of Early and Middle Devonian bioevents (the Lochkovian/Pragian Event, Basal Zlíchovian E., Daleje E., and Choteč E.) we carried out a sequence-stratigraphic analysis of carbonate-dominated successions in the Prague Basin (peri-Gondwana), a classic area of Devonian bioevents. The study is based on a basin-wide correlation of facies and field gamma-ray spectrometry (GRS) logs from 18 sections (Lochkovian to Eifelian), supported by element geochemistry and published biostratigraphic and carbon isotope data. Devonian carbonate deposition in the Prague Basin alternated between two end-member modes: an oligotrophic, homoclinal ramp (Praha and Daleje-Třebotov Formations) and a mesotrophic, distally steepened ramp (Lochkov, Zlíchov, and Choteč Formations). They show contrasting facies, particularly the absence/presence of gravity-flow deposits, allochem composition, U/Th ratios, and geochemical composition (productivity proxies such as P/Al, Si/Al, Zn/Al, TOC and stable carbon isotopes). The mesotrophic systems reflect an increased availability of nutrients on the shelf during the late Lochkovian, early Emsian (Zlíchovian), and Eifelian periods when sea surface temperature, pCO2, and silicate weathering rates were higher. The oligotrophic systems deposited during the Pragian-to-earliest Emsian and late Emsian (Dalejan) periods reflect reversed palaeoclimatic trends. We identified three depositional sequences (DS), DS1 (base of Pragian to early Emsian); DS2 (early Emsian to mid Emsian); and DS3 (mid Emsian to mid Eifelian). These sequences were integrated into a peri-Gondwana relative sea-level curve, which was then compared with the Euramerican sea-level curve of Johnson et al. (1985). The bioevents coincided with several sequence stratigraphic surfaces, representing variable limbs of the relative sea-level curve. On the other hand, their conspicuous coincidence with the switching intervals between the colder oligotrophic and warmer mesotrophic modes suggests that organic production linked to global climate was the primary control on biotic overturns, while sea-level fluctuations may have only amplified its effects.
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NASA Astrophysics Data System (ADS)
Glikson, Andrew Y.; Uysal, I. Tonguç; Fitz Gerald, John D.; Saygin, Erdinc
2013-03-01
The Eastern Warburton Basin, Northeast South Australia, features major geophysical anomalies, including a magnetic high of near-200 nT centred on a 25 km-wide magnetic low (< 100 nT), interpreted in terms of a magmatic body below 6 km depth. A distinct seismic tomographic low velocity anomaly may reflect its thick (9.5 km) sedimentary section, high temperatures and possible deep fracturing. Scanning electron microscope (SEM) analyses of granites resolves microbreccia veins consisting of micron-scale particles injected into resorbed quartz grains. Planar and sub-planar elements in quartz grains (Qz/PE) occur in granites, volcanics and sediments of the > 30,000 km-large Eastern Warburton Basin. The Qz/PE include multiple intersecting planar to curved sub-planar elements with relic lamellae less than 2 μm wide with spacing of 4-5 μm. Qz/PE are commonly re-deformed, displaying bent and wavy patterns accompanied with fluid inclusions. U-stage measurements of a total of 243 planar sets in 157 quartz grains indicate dominance of ∏{10-12}, ω{10-13} and subsidiary §{11-22}, {22-41}, m{10-11} and x{51-61} planes. Transmission Electron Microscopy (TEM) analysis displays relic narrow ≤ 1 μm-wide lamellae and relic non-sub grain boundaries where crystal segments maintain optical continuity. Extensive sericite alteration of feldspar suggests hydrothermal alteration to a depth of 500 m below the unconformity which overlies the Qz/PE-bearing Warburton Basin terrain. The data are discussed in terms of (A) Tectonic-metamorphic deformation and (B) impact shock metamorphism producing planar deformation features (Qz/PDF). Deformed Qz/PE are compared to re-deformed Qz/PDFs in the Sudbury, Vredefort, Manicouagan and Charlevoix impact structures. A 4-5 km uplift of the Big Lake Granite Suite during 298-295 Ma is consistent with missing of upper Ordovician to Devonian strata and possible impact rebound. The occurrence of circular seismic tomography anomalies below the east Warburton Basin, the Poolowana Basin and the Woodleigh impact structure signifies a potential diagnostic nature of circular tomographic anomalies.
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Tectonic Setting of NGHP-1 Site 17, Andaman Forearc
NASA Astrophysics Data System (ADS)
Cochran, J. R.
2008-12-01
The National Gas Hydrate Program (NGHP) Expedition 1 was an 'IODP-like' coring and logging program to investigate gas hydrate occurrences along the margins of India. Although most sites were located along the east coast of India, Site NGHP-01-17 was located near 10° 45'N on the Andaman forearc approximately 50 km east of Little Andaman Island in a water depth of 1325 m. Seismic lines across the site show an anomalously deep bottom simulating reflector (BSR) at a depth of about 600 mbsf. Coring and logging results confirmed that the BSR does mark the base of the gas hydrate stability zone. The age of the sediments at the base of the hole was estimated as 12.3 Ma. The Andaman Sea is an extensional basin resulting from strain partitioning during oblique subduction at the Sunda trench. The site is located within the eastern portion of the Andaman-Nicobar outer arc accretionary ridge on a long sliver of crust between the Eastern Margin Fault and the Diligent Fault. They are both down-to-the-east normal faults that form the eastern edge of the accretionary prism. The West Andaman Fault (WAF), which forms the principal active plate boundary between the Sumatra Fault and the Andaman Spreading Center, is located about 45 km further east along the eastern side of Invisible Bank. The Eastern Margin Fault forms the eastern edge of the block containing Little Andaman Island and extends northward for at least 100 km along the eastern side of South Andaman Island where it appears to die out. It can be traced south to about 8° 20'N where it dies out east of Tarasa Island. The Diligent Fault extends south to about 9° N where it apparently merges with the WAF. It forms the eastern edge of the accretionary prism northward to at least to 13° N and most likely to the Mynamar shelf at 14° N. It probably continues on to join the Kabaw Fault, which marks the eastern boundary of the accretionary prism in Myanmar. Although there is a significant vertical offset across both faults near the NGDP-1-17 site, the Diligent Fault appears to have also experienced strike-slip faulting at some point, probably prior to formation of the Andaman Spreading Center at about 4 Ma. At that time the situation may have been similar to that now found between about 7° N and 4° N where the northern motion of the sliver plate is concentrated at two locations, a fault system along the landward margin of the accretionary prism and another system further landward that forms the main plate boundary.
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NASA Astrophysics Data System (ADS)
De Vleeschouwer, David; Da Silva, Anne-Christine; Day, James E.; Whalen, Michael; Claeys, Philippe
2016-04-01
Milankovitch cycles (obliquity, eccentricity and precession) result in changes in the distribution of solar energy over seasons, as well as over latitudes, on time scales of ten thousands of years to millions of years. These changing patterns in insolation have induced significant variations in Earth's past climate over the last 4.5 billion years. Cyclostratigraphy and astrochronology utilize the geologic imprint of such quasi-cyclic climatic variations to measure geologic time. In recent years, major improvements of the Geologic Time Scale have been proposed through the application of cyclostratigraphy, mostly for the Mesozoic and Cenozoic (Gradstein et al., 2012). However, the field of Paleozoic cyclostratigraphy and astrochronology is still in its infancy and the application of cyclostratigraphic techniques in the Paleozoic allows for a whole new range of research questions. For example, unraveling the timing and pacing of environmental changes over the Late Devonian mass extinction on a 105-year time-scale concerns such a novel research question. Here, we present a global cyclostratigraphic framework for late Frasnian to early Famennian climatic and environmental change, through the integration of globally distributed sections. The backbone of this relative time scale consists of previously published cyclostratigraphies for western Canada and Poland (De Vleeschouwer et al., 2012; De Vleeschouwer et al., 2013). We elaborate this Euramerican base by integrating new proxy data -interpreted in terms of astronomical climate forcing- from the Iowa basin (USA, magnetic susceptibility and carbon isotope data) and Belgium (XRF and carbon isotope data). Next, we expand this well-established cyclostratigraphic framework towards the Paleo-Tethys Ocean, using magnetic susceptibility and carbon isotope records from the Fuhe section in South China (Whalen et al., 2015). The resulting global cyclostratigraphic framework implies an important refinement of the late Frasnian to early Famennian stratigraphy, but also allows for an evaluation of the role of astronomical forcing in perturbing the global carbon cycle and pacing anoxic conditions throughout the Late Devonian mass extinction event. The late Frasnian anoxic Kellwasser events, for example, each represent only a portion of a 405-kyr eccentricity cycle, with the onset of both events separated by 500-600 kyr. References: De Vleeschouwer, D., Whalen, M. T., Day, J. E., and Claeys, P., 2012, Cyclostratigraphic calibration of the Frasnian (Late Devonian) time scale (western Alberta, Canada): Geological Society of America Bulletin, v. 124, no. 5-6, p. 928-942. De Vleeschouwer, D., Rakociński, M., Racki, G., Bond, D. P., Sobień, K., and Claeys, P., 2013, The astronomical rhythm of Late-Devonian climate change (Kowala section, Holy Cross Mountains, Poland): Earth and Planetary Science Letters, v. 365, p. 25-37. Gradstein, F. M., Ogg, J. G., Schmitz, M., and Ogg, G., 2012, The Geologic Time Scale 2012 2-Volume Set, Elsevier. Whalen, M. T., Śliwiński, M. G., Payne, J. H., Day, J. E., Chen, D., and da Silva, A.-C., 2015, Chemostratigraphy and magnetic susceptibility of the Late Devonian Frasnian-Famennian transition in western Canada and southern China: implications for carbon and nutrient cycling and mass extinction: Geological Society, London, Special Publications, v. 414.
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Rowan, E.L.; Engle, M.A.; Kirby, C.S.; Kraemer, T.F.
2011-01-01
Radium activity data for waters co-produced with oil and gas in New York and Pennsylvania have been compiled from publicly available sources and are presented together with new data for six wells, including one time series. When available, total dissolved solids (TDS), and gross alpha and gross beta particle activities also were compiled. Data from the 1990s and earlier are from sandstone and limestone oil/gas reservoirs of Cambrian-Mississippian age; however, the recent data are almost exclusively from the Middle Devonian Marcellus Shale. The Marcellus Shale represents a vast resource of natural gas the size and significance of which have only recently been recognized. Exploitation of the Marcellus involves hydraulic fracturing of the shale to release tightly held gas. Analyses of the water produced with the gas commonly show elevated levels of salinity and radium. Similarities and differences in radium data from reservoirs of different ages and lithologies are discussed. The range of radium activities for samples from the Marcellus Shale (less than detection to 18,000 picocuries per liter (pCi/L)) overlaps the range for non-Marcellus reservoirs (less than detection to 6,700 pCi/L), and the median values are 2,460 pCi/L and 734 pCi/L, respectively. A positive correlation between the logs of TDS and radium activity can be demonstrated for the entire dataset, and controlling for this TDS dependence, Marcellus shale produced water samples contain statistically more radium than non-Marcellus samples. The radium isotopic ratio, Ra-228/Ra-226, in samples from the Marcellus Shale is generally less than 0.3, distinctly lower than the median values from other reservoirs. This ratio may serve as an indicator of the provenance or reservoir source of radium in samples of uncertain origin.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Van Tyne, A.M.
1995-09-01
Seven subsurface Onondaga reefs have been found in southwestern New York (6) and northwestern Pennsylvania (1). These reefs have had a maximum thickness of about 200 feet and cover an area of a few hundred acres. They are similar to nearly 30 smaller reefs in the same geologic section which have previously been found along the Onodaga outcrop. The discovery well for Onodaga reef gas, although not recognized as such at the time, was the No. 1 Quinlan Oil. The well was drilled in 1933 in the Town of Olean, Cattaraugus County, New York near the New York-Pennsylvania State line.more » The first of the more recent Onondaga reef discoveries occurred in 1967 at Wyckoff in the Town of Jasper, Steuben County, New York. This discovery touched off a leasing and seismic exploration boom in this area of New York. As a result of these studies, two more reefs were discovered in 1971, two in 1974 and the last so far in 1981. These seven reefs have produced 7.1 billion cubic feet of gas. The smallest, Flatstone, has production to data of about 700 million cubic feet. The Onondaga reefs are of basal Onondaga, or Edgecliff, age. The Edgecliff is a light gray, coarsely crystalline, biostromal limestone. Onondaga reefs may have begun forming on somewhat higher parts of the sea floor in crinoid thickets. Because the Onondaga is considerably thicker in that area these so-called {open_quotes}reefs{close_quotes} are buried entirely within the total Onondaga section. They have been called reefs mainly because gas shows have been encountered in the lower Onondaga when it was drilled through by wells aiming for deeper Medina sandstones gas production. Nevertheless, gas production from them has been minimal. The seal consists of surrounding and overlapping black and gray middle Devonian Hamilton shales. The basal portions are surrounded by onlapping upper Onondaga limestones. The source of the gas is believed to be the highly organic Hamilton shale.« less
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Prediction of resource volumes at untested locations using simple local prediction models
Attanasi, E.D.; Coburn, T.C.; Freeman, P.A.
2006-01-01
This paper shows how local spatial nonparametric prediction models can be applied to estimate volumes of recoverable gas resources at individual undrilled sites, at multiple sites on a regional scale, and to compute confidence bounds for regional volumes based on the distribution of those estimates. An approach that combines cross-validation, the jackknife, and bootstrap procedures is used to accomplish this task. Simulation experiments show that cross-validation can be applied beneficially to select an appropriate prediction model. The cross-validation procedure worked well for a wide range of different states of nature and levels of information. Jackknife procedures are used to compute individual prediction estimation errors at undrilled locations. The jackknife replicates also are used with a bootstrap resampling procedure to compute confidence bounds for the total volume. The method was applied to data (partitioned into a training set and target set) from the Devonian Antrim Shale continuous-type gas play in the Michigan Basin in Otsego County, Michigan. The analysis showed that the model estimate of total recoverable volumes at prediction sites is within 4 percent of the total observed volume. The model predictions also provide frequency distributions of the cell volumes at the production unit scale. Such distributions are the basis for subsequent economic analyses. ?? Springer Science+Business Media, LLC 2007.
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North Dakota`s Dickinson Lodgepole discovery: A Preliminary exploration model
DOE Office of Scientific and Technical Information (OSTI.GOV)
LeFever, J.A.; Halabura, S.P.; Martiniuk, C.D.
1995-08-14
Interest in the Mississippian Lodgepole formation of North Dakota has intensified since the successful completion of the Duncan Oil Inc. 1-11 Knopik flowing 2,707 b/d of oil and 1.55 MMcfd of gas 430 cu m of oil and 43,891 cu m of gas. The play began when Conoco drilled an in-field wildcat in an attempt to establish deeper production in Dickinson oil field. The discovery well, 74 Dickinson State, was completed in a clean lower Lodgepole limestone section that is thought to represent a Waulsortian mound. The most important questions asked concerning the Lodgepole play are whether or not itmore » will step out of the Dickinson area, what are the factors that control the development of these mounds, what controlled the development of the reservoir and trap, and how it was charged with oil. Other than the reservoir section, the most significant feature observed from wireline logs of the area is the anomalously thick Bakken formation (Mississippian-Devonian). This observation is important to understanding the Lodgepole play and can be used to help explore for similar features elsewhere in the basin. The paper describes the regional setting, the Lodgepole stratigraphy, deposition, regional equivalents, and a salt collapse model that can readily explain the features observed at the Dickinson field.« less
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Exploration in Ordovician of central Michigan Basin
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fisher, J.H.; Barratt, M.W.
1985-12-01
Deep wells in the central Michigan basin have provided sufficient data to define two new mappable formations - the Foster Formation and the Bruggers Formation. Recent conodont studies have corrected the age assignments of the strata containing these formations. Previously, the lower section (Foster) was classified as mostly Cambrian, and the upper unit (Bruggers) was identified as Early Ordovician. Conodont identifications indicate an Early and Middle Ordovician age for the Foster Formation and a Middle Ordovician age for the Bruggers Formation. The Michigan basin existed in embryonic form in the Late Cambrian, but the full outline of the present-day basinmore » did not develop until Early Ordovician. Gas and condensate are produced from the Bruggers Formation as deep as 11,252 ft (3429 m). Geothermal investigations suggest that gas production is possible to the base of the Paleozoic section in the central basin (17,000 ft or 5181 m). Paleotemperatures were higher during the Paleozoic owing to 3000-4000 ft (914-1291 m) of additional sedimentary cover. Five wells are producing from the Bruggers Formation. All are deeper tests in anticlines producing from Devonian reservoirs discovered earlier. The structures are the result of vertical movements of basement fault blocks activated by regional stresses. 12 figures, 2 tables.« less
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Kin, Adrian; Błażejowski, Błażej
2013-01-01
This study presents a detailed morphological analysis of a new species belonging to the blind trilobite Trimerocephalus McCoy, 1849, T. chopini n. sp., based on exceptionally well preserved articulated specimens from the Late Devonian (Early Famennian) of the Holy Cross Mountains in central Poland. The occurrence of this taxon in Kowala Quarry near Kielce has been reported previously, with specimens often found in single-file queues representing migratory behaviour that was followed by a mass mortality event that preserved these assemblages. The new taxon is compared with other species of Trimerocephalus and is interpreted as being most closely related to a clade consisting of T. caecus, T. lelievrei, T, inimbi, T. shotoriensis and T. tardispinosus.
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Active Microbial Methane Production and Organic Matter Degradation in a Devonian Black Shale
NASA Astrophysics Data System (ADS)
Martini, A. M.; Petsch, S. T.; Nuesslein, K.; McIntosh, J. C.
2003-12-01
Microorganisms employ many novel strategies to derive energy and obtain nutrients, and in doing so alter the chemistry of their environments in ways that are significant for formation and transformation of geologic materials. One such strategy is natural gas generation in sedimentary basins. Previous research has shown that stable isotopic signatures of CH4, CO2 and H2O in formation waters of gas-producing black shales indicate a microbial origin for several economically viable natural gas reserves. However, these signatures leave several intriguing issues unaddressed, including the identity of the organisms and their metabolic roles and impacts on mineral, isotopic and biomarker signatures. We hypothesize that the extreme reducing conditions required for sedimentary basin methanogenesis are simply the end product of a cascade of microbial processes, initiated by anaerobic respiration of shale organic matter through NO3, SO4 and/or Fe(III) reduction, secondary processing of anaerobe biomass by fermentative organisms yielding volatile fatty acids and H2, and ultimately CO2 reduction and/or acetate fermentation to produce CH4. This research holds importance for the several aspects of the geochemical carbon cycle. It describes anaerobic hydrocarbon degradation leading to methanogenesis in a sedimentary basin; in many instances this activity has generated economically viable reserves of natural gas. It also provides a benchmark detailing how post-depositional microbial activity in rocks may confound and overprint ancient biosignatures. Interpretation of past environmental conditions depends on molecular and isotopic signatures contained in ancient sedimentary rocks, separated from signatures of metabolically similar modern microbiota living in sedimentary basins. In addition, this research sheds light on an unrecognized and thus unconstrained source of reduced gases to Earth's atmosphere, important for understanding the rates and controls on carbon cycling through geologic time.
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Federal Register 2010, 2011, 2012, 2013, 2014
2011-11-18
..., these comments should identify specific CMP policies of concern, the nature of the conflict foreseen... conditions or conflicts, or other information that might bear upon the potential leasing and development of this area. Comments are also sought on potential conflicts between future OCS oil and gas activities...
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Alternative Fuels Data Center: Pennsylvania School Buses Run on Natural Gas
reduce petroleum use and save money. For information about this project, contact Eastern Pennsylvania Renzenberger Inc Saves Money With Propane Vans Feb. 1, 2014 Photo of a school bus Michigan Transports Students Natural Gas School Buses Help Kansas City Save Money Nov. 12, 2011 Metropolitan Utilities District Fuels
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Federal Register 2010, 2011, 2012, 2013, 2014
2013-10-11
... Garrison Energy Center, a 309-megawatt combined cycle natural gas fueled power plant under development in... measures, would not constitute a major federal action significantly affecting the quality of the human... and groups; newspapers and libraries in the project area; and parties to this proceeding. In addition...
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75 FR 42735 - Combined Notice of Filings No. 1
Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-22
... Gas Tariff, Second Revised Volume 1, to be effective 8/13/10. Filed Date: 07/13/2010. Accession Number... effective 7/13/2010. Filed Date: 07/13/2010. Accession Number: 20100713-5061. Comment Date: 5 p.m. Eastern Time on Monday, July 26, 2010. Docket Number: CP10-467-000. Applicants: Transcontinental Gas Pipe Line...
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TIDAL TAILS OF MINOR MERGERS. II. COMPARING STAR FORMATION IN THE TIDAL TAILS OF NGC 2782
DOE Office of Scientific and Technical Information (OSTI.GOV)
Knierman, Karen A.; Scowen, Paul; Veach, Todd
2013-09-10
The peculiar spiral NGC 2782 is the result of a minor merger with a mass ratio {approx}4: 1 occurring {approx}200 Myr ago. This merger produced a molecular and H I-rich, optically bright eastern tail and an H I-rich, optically faint western tail. Non-detection of CO in the western tail by Braine et al. suggested that star formation had not yet begun. However, deep UBVR and H{alpha} narrowband images show evidence of recent star formation in the western tail, though it lacks massive star clusters and cluster complexes. Using Herschel PACS spectroscopy, we discover 158 {mu}m [C II] emission at themore » location of the three most luminous H{alpha} sources in the eastern tail, but not at the location of the even brighter H{alpha} source in the western tail. The western tail is found to have a normal star formation efficiency (SFE), but the eastern tail has a low SFE. The lack of CO and [C II] emission suggests that the western tail H II region may have a low carbon abundance and be undergoing its first star formation. The western tail is more efficient at forming stars, but lacks massive clusters. We propose that the low SFE in the eastern tail may be due to its formation as a splash region where gas heating is important even though it has sufficient molecular and neutral gas to make massive star clusters. The western tail, which has lower gas surface density and does not form high-mass star clusters, is a tidally formed region where gravitational compression likely enhances star formation.« less
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Morphology and kinematics of the gas envelope of Mira Ceti
NASA Astrophysics Data System (ADS)
Nhung, P. T.; Hoai, D. T.; Diep, P. N.; Phuong, N. T.; Thao, N. T.; Tuan-Anh, P.; Darriulat, P.
2016-07-01
Observations of 12CO(3-2) emission of the circumbinary envelope of Mira Ceti, made by Atacama Large Millimetre/sub-millimetre Array, are analysed. The observed Doppler velocity distribution is made of three components: a blueshifted south-eastern arc, which can be described as a ring in slow radial expansion, ˜1.7 km s-1, making an angle of ˜50° with the plane of the sky and born some 2000 years ago; a few arcs, probably born at the same epoch as the blueshifted arc, all sharing Doppler velocities redshifted by approximately 3±2 km s-1 with respect to the main star; thirdly, a central region dominated by the circumbinary envelope, displaying two outflows in the south-western and north-eastern hemispheres. At short distances from the star, up to ˜1.5 arcsec, these hemispheres display very different morphologies: the south-western outflow covers a broad solid angle, expands radially at a rate between 5 and 10 km s-1 and is slightly redshifted; the north-eastern outflow consists of two arms, both blueshifted, bracketing a broad dark region where emission is suppressed. At distances between ˜1.5 and ˜2.5 arcsec the asymmetry between the two hemispheres is significantly smaller and detached arcs, particularly spectacular in the north-eastern hemisphere are present. Close to the stars, we observe a mass of gas surrounding Mira B, with a size of a few tens of au, and having Doppler velocities with respect to Mira B reaching ±1.5 km s-1, which we interpret as gas flowing from Mira A towards Mira B.
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Morrow, J.R.; Sandberg, C.A.; Malkowski, K.; Joachimski, M.M.
2009-01-01
At Hancock Summit West, Nevada, western USA, uppermost Givetian (upper Middle Devonian) and lower and middle Frasnian (lower Upper Devonian) rocks of the lower Guilmette Formation include, in stratigraphic sequence, carbonate-platform facies of the conodont falsiovalis, transitans, and punctata Zones; the type Alamo Breccia Member of the middle punctata Zone; and slope facies of the punctata and hassi Zones. The catastrophically deposited Alamo Breccia and related phenomena record the ~ 382??Ma Alamo event, produced by a km-scale bolide impact into a marine setting seaward of an extensive carbonate platform fringing western North America. Re-evaluation of conodonts from the lower Guilmette Formation and Alamo Breccia Member, together with regional sedimentologic and conodont biofacies comparisons, now firmly locates the onset of the Johnson et al. (1985) transgressive-regressive (T-R) cycle IIc, which occurred after the start of the punctata Zone, within a parautochthonous megablock low in the Alamo Breccia. Whole-rock carbon isotope analyses through the lower Guilmette Formation and Alamo Breccia Member reveal two positive ??13Ccarb excursions: (1) a small, 3??? excursion, which is possibly correlative with the falsiovalis Event previously identified from sections in Western Europe and Australia, occurs below the breccia in the Upper falsiovalis Zone to early part of the transitans Zone; and (2) a large, multi-part excursion, dominated by a 6??? positive shift, begins above the start of the punctata Zone and onset of T-R cycle IIc and continues above the Alamo Breccia, ending near the punctata- hassi zonal boundary. This large excursion correlates with the punctata Event, a major positive ??13C excursion previously recognized in eastern Laurussia and northern Gondwana. Consistent with previous studies, at Hancock Summit West the punctata Event is apparently not associated with any regional extinctions or ecosystem reorganizations. In the study area, onset of the main punctata Event began after the start of both the punctata Zone and T-R cycle IIc, and preceded the Alamo impact by less than 650??k.y., as inferred from conodont biochronologic and regional rock-accumulation rate estimates. Although complicated by the heterolithic, high-energy deposits of the Alamo Breccia, the carbon isotope record of the breccia and post-breccia beds does not indicate a major impact-correlative perturbation to the carbon cycle. This study extends recognition of the punctata Event to western Laurussia, further reinforcing the potential global scale of the event and its potential importance to understanding early to middle Frasnian marine geochemistry and palaeoenvironments. Based on previous models and our observations, increased tectonic activity, increased nutrient flux to oceans, increased marine bioproductivity, widespread anoxia, and increased organic carbon burial were all likely key factors in driving the punctata Event excursion. Furthermore, periodic eustatic and regional relative sea-level rises may have played an important role in promoting organic carbon burial and in maintaining a link between the primary open-marine geochemical signal and that recorded on the shallow-marine, lower Guilmette carbonate platform. ?? 2009 Elsevier B.V. All rights reserved.
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Geology and hydrocarbon potential of the Oued Mya basin, Algeria
DOE Office of Scientific and Technical Information (OSTI.GOV)
Benamrane, O.; Messaoudi, M.; Messelles, H.
1993-09-01
The Oued Mya hydrocarbon system is located in the Sahara basin. It is one of the best producing basins in Algeria, along with the Ghadames and Illizi basins. The stratigraphic section consists of Paleozoic and Mesozoic, and is about 5000 m thick. This intracratonic basin is limited to the north by the Toughourt saddle, and to the west and east it is flanked by regional arches, Allal-Tilghemt and Amguid-Hassi Messaoud, which culminate in the super giant Hassi Messaoud and Hassi R'mel hydrocarbon accumulations, respectively, producing oil from the Cambrian sands and gas from the Trissic sands. The primary source rockmore » in this basin is lower Silurian shale, with an average thickness of 50 m and a total organic carbon of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also source rocks, but in a second order. Clastic reservoirs are in the Trissic sequence, which is mainly fluvial deposits with complex alluvial channels, and the main target in the basin. Clastic reservoirs in the lower Devonian section have a good hydrocarbon potential east of the basin through a southwest-northwest orientation. The Late Trissic-Early Jurassic evaporites that overlie the Triassic clastic interval and extend over the entire Oued Mya basin, are considered to be a super-seal evaporite package, which consists predominantly of anhydrite and halite. For paleozoic targets, a large number of potential seals exist within the stratigraphic column. This super seal does not present oil dismigration possibilities. We can infer that a large amount of the oil generated by the Silurian source rock from the beginning of Cretaceous until now still is not discovered and significantly greater volumes could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands, and Cambrian-Ordovician reservoirs.« less
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Bedded Barite Deposits from Sonora (nw Mexico): a Paleozoic Analog for Modern Cold Seeps
NASA Astrophysics Data System (ADS)
Canet, C.; Anadón, P.; González-Partida, E.; Alfonso, P.; Rajabi, A.; Pérez-Segura, E.; Alba-Aldave, L. A.
2013-05-01
The Mazatán barite deposits represent an outstanding example of Paleozoic bedded barite, a poorly understood type of mineral deposit of major economic interest. The largest barite bodies of Mazatán are hosted within an Upper Carboniferous flysch succession, which formed part of an accretionary wedge related to the subduction of the Rheic Ocean beneath Gondwana. As well, a few barite occurrences are hosted in Upper Devonian, pre-orogenic turbidites. A variety of mineralized structures is displayed by barite, including: septaria nodules, enterolitic structures, rosettes and debris-flow conglomerates. Barite is accompanied by chalcedony, pyrite (framboids) and berthierine. Gas-rich fluid inclusions in barite were analyzed by Raman spectroscopy and methane was identified, suggesting the occurrence of light hydrocarbons in the environment within which barite precipitated. 13C-depleted carbonates (δ13C: -24.3 to -18.8‰) were found in the barite deposits; they formed through anaerobic oxidation of methane coupled to sulfate reduction, and yield negative δ18O values (-11.9 to -5.2‰) reflecting the isotopic composition of Devonian-Carboniferous seawater. Methane-derived carbonates occur in modern hydrocarbon seeps and have been reported from Mesozoic and Cenozoic seep sediments, but they have never before been described in Paleozoic bedded barite deposits. δ34S of barite varies from +17.6 to +64.1‰, with the lowest values overlapping the range for coeval seawater sulfate; this distribution indicates a process of sulfate reduction. Barite precipitation can be explained by mixing of methane- and barium-rich fluids with pore-water (seawater) containing sulfate residual from microbial reduction. Two analyses from barite gave an 87Sr/86Sr within and slightly above the range for seawater at the time of deposition, with 0.708130 and 0.708588, which would preclude the involvement of hydrothermal fluids in the mineralization process.
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Tomescu, Alexandru M. F.
2017-01-01
Abstract Background and Aims Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. Methods This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Key Results Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Conclusions Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. PMID:28334100
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Syngenetic Au on the Carlin trend: Implications for Carlin-type deposits
Emsbo, P.; Hutchinson, R.W.; Hofstra, A.H.; Volk, J.A.; Bettles, K.H.; Baschuk, G.J.; Johnson, C.A.
1999-01-01
A new type of gold occurrence recently discovered in the Carlin trend, north-central Nevada, is clearly distinct from classic Carlin-type gold ore. These occurrences are interpreted to be of sedimentary exhalative (sedex) origin because they are stratiform and predate compaction and lithification of their unaltered Devonian host rocks. They contain barite that exhibits ??34S and ??18O values identical to sulfate in Late Devonian seawater and sedex-type barite deposits. Abrupt facies changes in the host rocks strongly suggest synsedimentary faulting and foundering of the carbonate shelf during mineralization, as is characteristic of sedex deposits. Gold occurs both as native inclusions in synsedimentary base-metal sulfides and barite, and as chemical enrichments in sulfide minerals. The absence of alteration and lack of ??13C and ??18O isotopic shift of primary carbonates in these rocks is strong evidence that this gold was not introduced with classic Carlin-type mineralization. Collectively, these features show that the Devonian strata were significantly enriched in gold some 300 m.y. prior to generation of the mid-Tertiary Carlin-type deposits. These strata may have been an important, perhaps even vital, source of gold for the latter. Although gold is typically low in most Zn-Pb-rich sedex deposits, our evidence suggests that transport of gold in basinal fluids, and its subsequent deposition in the sedex environment, can be significant.
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NASA Astrophysics Data System (ADS)
Zapalski, Mikołaj K.; Wrzołek, Tomasz; Skompski, Stanisław; Berkowski, Błażej
2017-09-01
Recent mesophotic coral ecosystems (MCE) occur at depths between 30 and 150 m and are characterized by dominance of platy corals. Such morphology is an effect of specific adaptation to efficient light harvesting. Here, we describe and analyze platy coral assemblages from two Middle Devonian localities in the Holy Cross Mountains (Poland) that during this time were located on the southern shelf of Laurussia at tropical latitudes. The Eifelian argillaceous sediments of Skały are dominated by platy and encrusting tabulate corals ( Roseoporella, Platyaxum and Alveolites). Coeval faunas from the shallow-water parts of the Holy Cross Mountains basin display bulbous and branching morphology, thus indicating a Paleozoic coral zonation similar to that known in the Recent. Hence, the Skały site seems to be the oldest known MCE (ca. 390 Ma). A Givetian biostrome from Laskowa Quarry is a second example dominated by platy corals, with abundant branching forms; this site can be recognized as another Devonian MCE. Frondescent Platyaxum, common at both sites, had a growth habit similar to that of Recent Leptoseris, Mycedium or Pavona. Platy morphology is photoadaptive and may evidence photosymbiosis in tabulate ( Alveolites, Roseoporella, Platyaxum) and rugose corals ( Phillipsastrea). Furthermore, it may serve as a tool for recognition of the lower euphotic zone in the fossil record.
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Unsuspected functional disparity in Devonian fishes revealed by tooth morphometrics?
NASA Astrophysics Data System (ADS)
Gauchey, Samuel; Girard, Catherine; Adnet, Sylvain; Renaud, Sabrina
2014-09-01
The shape of features involved in key biological functions, such as teeth in nutrition, can provide insights into ecological processes even in ancient time, by linking the occupation of the morphological space (disparity) to the occupation of the ecological space. Investigating disparity in radiating groups may provide insights into the ecological diversification underlying evolution of morphological diversity. Actinopterygian fishes initiated their radiation in the Devonian, a period characterized by the diversification of marine ecosystem. Although a former morpho-functional analysis of jaw shape concluded to conservative and poorly diversified morphologies in this early part of their history, fish tooth disparity evidenced here an unsuspected diversity of possible functional significance in the pivotal period of the Late Devonian (Famennian). All teeth being caniniforms, some were stocky and robust, in agreement with expectations for active generalist predators. More surprisingly, elongated teeth also occurred at the beginning of Famennian. Their needle-like shape challenges morpho-functional interpretations by making them fragile in response to bending or torsion. The occurrence of both types of fish teeth during the beginning of the Famennian points to a discrete but real increase in disparity, thus testifying a first burst of feeding specialization despite overall conservative jaw morphology. The disappearance of these needle-like teeth in the Late Famennian might have been related to a relay in dental diversity with abundant co-occurring groups, namely conodonts and chondrichthyans (sharks).
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NASA Astrophysics Data System (ADS)
Suttner, Thomas J.; Kido, Erika; Chen, Xiuqin; Mawson, Ruth; Waters, Johnny A.; Frýda, Jiří; Mathieson, David; Molloy, Peter D.; Pickett, John; Webster, Gary D.; Frýdová, Barbora
2014-02-01
Late Devonian to Early Carboniferous stratigraphic units within the 'Zhulumute' Formation, Hongguleleng Formation (stratotype), 'Hebukehe' Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and 'Hebukehe' formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding 'Hebukehe' Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. 'Blastoid Hill') and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.
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Sedimentology of the Sbaa oil reservoir in the Timimoun basin (S. Algeria)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mehadi, Z.
1990-05-01
In 1980 oil was discovered in the Timimoun portion of the Sbaa depression in Southern Algeria. Until that time this basin had produced only dry gas. Since the 1980 oil discovery, several wells have been drilled. Data acquired from these wells were analyzed and are presented in this study. The oil reservoir is located within a sandstone interval of the Sbaa formation which has an average thickness of 75 m. The Sbaa lies between the Tournaisian (Lower Carboniferous) silts and the Strunian (uppermost Devonian) shales and sandstones. The sedimentological study reveals that the Sbaa formation contains bimodal facies consisting ofmore » coarse siltstones and fine sandstones. The sequence has been attributed to a deltaic environment developed in the central part of the Ahnet basin. The sources of the associated fluvial system are from the surrounding In-Semmen, Tinessourine, and Arak-Foum-Belrem paleohighs. Thermoluminescence indicates the provenance for the Sbaa sands was the crystalline basement Cambrian and Ordovician sections.« less
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Geology, Murzuk oil development could boost S. W. Libya prospects
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thomas, D.
1995-03-06
With the recent involvement of Repsol, Total, and OMV in developing the 2 billion bbl oil-in-place Murzuk field complex, an infrastructure will be finally constructed in western Libya which will act as a precursor to more exploration activity and development projects in the Murzuk and Ghadames basins. Murzuk, an intra-cratonic sag basin, is a huge ladle-shaped structural basin covering more than 400,000 sq km and extending beyond the borders of southern Libya. The structure of the area is quite simple. The sub-horizontal or gently dipping strata are faulted and the faults are most frequently parallel to the anticlinal axis. Tectonicmore » movements affected the basin to a greater or lesser degree from early Paleozoic (Caledonian) to post-Eocene (Alpine) times. The paper describes the exploration history; stratigraphy; the Ordovician, Silurian and Devonian, and Carboniferous reservoirs; source rocks; oil gravity and gas content; hydrogeologic constraints; aquifer influence on hydrocarbon accumulation; geologic structures; Murzuk field development; and acreage availability.« less
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History of displacement along Ste. Genevieve Fault Zone, Southwestern Illinois
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schwalb, H.R.
1983-09-01
The Ste. Genevieve fault zone extends eastward from Missouri across the Mississippi River into Jackson County, Illinois, about 75 mi (120 km) southeast of St. Louis. Outcrop studies have dated movement along portions of the zone as pre-Middle Devonian, post-Mississippian, and post-Pennsylvanian. Present displacement is down to the north and east with throw ranging up to 3,000 ft (915 m). However, pre-Middle Devonian movement was down to the south and west. The present upthrown block shows no evidence of vertical movement during the Cambrian and Ordovician. Nor is there any indication that the fault zone was part of the northernmore » border of the Reelfoot basin, where earliest Paleozoic sediments infilled an aulacogen at the northern end of the Mississippi embayment.« less
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NASA Astrophysics Data System (ADS)
Long, John A.; Trinajstic, Kate
2010-05-01
The Gogo Formation of Western Australia preserves a unique Late Devonian (Frasnian) reef fauna. The exceptional three-dimensional preservation of macrofossils combined with unprecedented soft-tissue preservation (including muscle bundles, nerve cells, and umbilical structures) has yielded a particularly rich assemblage with almost 50 species of fishes described. The most significant discoveries have contributed to resolving placoderm phylogeny and elucidating their reproductive physiology. Specifically, these discoveries have produced data on the oldest known vertebrate embryos; the anatomy of the primitive actinopterygian neurocranium and phylogeny of the earliest actinopterygians; the histology, radiation, and plasticity of dipnoan (lungfish) dental and cranial structures; the anatomy and functional morphology of the extinct onychodonts; and the anatomy of the primitive tetrapodomorph head and pectoral fin.
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Carbonate rocks of the Seward Peninsula, Alaska: Their correlation and paleogeographic significance
Dumoulin, Julie A.; Harris, Alta; Repetski, John E.
2014-01-01
Paleozoic carbonate strata deposited in shallow platform to off-platform settings occur across the Seward Peninsula and range from unmetamorphosed Ordovician–Devonian(?) rocks of the York succession in the west to highly deformed and metamorphosed Cambrian–Devonian units of the Nome Complex in the east. Faunal and lithologic correlations indicate that early Paleozoic strata in the two areas formed as part of a single carbonate platform. The York succession makes up part of the York terrane and consists of Ordovician, lesser Silurian, and limited, possibly Devonian rocks. Shallow-water facies predominate, but subordinate graptolitic shale and calcareous turbidites accumulated in deeper water, intraplatform basin environments, chiefly during the Middle Ordovician. Lower Ordovician strata are mainly lime mudstone and peloid-intraclast grainstone deposited in a deepening upward regime; noncarbonate detritus is abundant in lower parts of the section. Upper Ordovician and Silurian rocks include carbonate mudstone, skeletal wackestone, and coral-stromatoporoid biostromes that are commonly dolomitic and accumulated in warm, shallow to very shallow settings with locally restricted circulation. The rest of the York terrane is mainly Ordovician and older, variously deformed and metamorphosed carbonate and siliciclastic rocks intruded by early Cambrian (and younger?) metagabbros. Older (Neoproterozoic–Cambrian) parts of these units are chiefly turbidites and may have been basement for the carbonate platform facies of the York succession; younger, shallow- and deep-water strata likely represent previously unrecognized parts of the York succession and its offshore equivalents. Intensely deformed and altered Mississippian carbonate strata crop out in a small area at the western edge of the terrane. Metacarbonate rocks form all or part of several units within the blueschist- and greenschist-facies Nome Complex. The Layered sequence includes mafic meta¬igneous rocks and associated calcareous metaturbidites of Ordovician age as well as shallow-water Silurian dolostones. Scattered metacarbonate rocks are chiefly Cambrian, Ordovician, Silurian, and Devonian dolostones that formed in shallow, warm-water settings with locally restricted circulation and marbles of less constrained Paleozoic age. Carbonate metaturbidites occur on the northeast and southeast coasts and yield mainly Silurian and lesser Ordovician and Devonian conodonts; the northern succession also includes debris flows with meter-scale clasts and an argillite interval with Late Ordovician graptolites and lenses of radiolarian chert. Mafic igneous rocks at least partly of Early Devonian age are common in the southern succession. Carbonate rocks on Seward Peninsula experienced a range of deformational and thermal histories equivalent to those documented in the Brooks Range. Conodont color alteration indices (CAIs) from Seward Peninsula, like those from the Brooks Range, define distinct thermal provinces that likely reflect structural burial. Penetratively deformed high-pressure metamorphic rocks of the Nome Complex (CAIs ≥5) correspond to rocks of the Schist belt in the southern Brooks Range; both record subduction during early stages of the Jurassic–Cretaceous Brooks Range orogeny. Weakly metamorphosed to unmetamorphosed strata of the York terrane (CAIs mainly 2–5), like Brooks Range rocks in the Central belt and structural allochthons to the north, experienced moderate to shallow burial during the main phase of the Brooks Range orogeny. The nature of the contact between the York terrane and the Nome Complex is uncertain; it may be a thrust fault, an extensional surface, or a thrust fault later reactivated as an extensional fault. Lithofacies and biofacies data indicate that, in spite of their divergent Mesozoic histories, rocks of the York terrane and protoliths of the Nome Complex formed as part of the same lower Paleozoic carbonate platform. Stratigraphies in both
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Assessment of Appalachian Basin Oil and Gas Resources: Utica-Lower Paleozoic Total Petroleum System
Ryder, Robert T.
2008-01-01
The Utica-Lower Paleozoic Total Petroleum System (TPS) is an important TPS identified in the 2002 U.S. Geological Survey (USGS) assessment of undiscovered, technically recoverable oil and gas resources in the Appalachian basin province (Milici and others, 2003). The TPS is named for the Upper Ordovician Utica Shale, which is the primary source rock, and for multiple lower Paleozoic sandstone and carbonate units that are the important reservoirs. Upper Cambrian through Upper Silurian petroleum-bearing strata that constitute the Utica-Lower Paleozoic TPS thicken eastward from about 2,700 ft at the western margin of the Appalachian basin to about 12,000 ft at the thrust-faulted eastern margin of the Appalachian basin. The Utica-Lower Paleozoic TPS covers approximately 170,000 mi2 of the Appalachian basin from northeastern Tennessee to southeastern New York and from central Ohio to eastern West Virginia. The boundary of the TPS is defined by the following geologic features: (1) the northern boundary (from central Ontario to northeastern New York) extends along the outcrop limit of the Utica Shale-Trenton Limestone; (2) the northeastern boundary (from southeastern New York, through southeastern Pennsylvania-western Maryland-easternmost West Virginia, to northern Virginia) extends along the eastern limit of the Utica Shale-Trenton Limestone in the thrust-faulted eastern margin of the Appalachian basin; (3) the southeastern boundary (from west-central and southwestern Virginia to eastern Tennessee) extends along the eastern limit of the Trenton Limestone in the thrust-faulted eastern margin of the Appalachian basin; (4) the southwestern boundary (from eastern Tennessee, through eastern Kentucky, to southwestern Ohio) extends along the approximate facies change from the Trenton Limestone with thin black shale interbeds (on the east) to the equivalent Lexington Limestone without black shale interbeds (on the west); (5) the northern part of the boundary in southwestern Ohio to the Indiana border extends along an arbitrary boundary between the Utica Shale of the Appalachian basin and the Utica Shale of the Sebree trough (Kolata and others, 2001); and (6) the northwestern boundary (from east-central Indiana, through northwesternmost Ohio and southeasternmost Michigan, to central Ontario) extends along the approximate southeastern boundary of the Michigan Basin. Although the Utica-Lower Paleozoic TPS extends into northwestern Ohio, southeastern Michigan, and northeastern Indiana, these areas have been assigned to the Michigan Basin (Swezey and others, 2005) and are outside the scope of this report. Furthermore, although the northern part of the Utica-Lower Paleozoic TPS extends across the Great Lakes (Lake Erie and Lake Ontario) into southern Ontario, Canada, only the undiscovered oil and gas resources in the U.S. waters of the Great Lakes have been included in the USGS assessment of the Utica-Lower Paleozoic TPS. This TPS is similar to the Point Pleasant-Brassfield petroleum system previously identified by Drozd and Cole (1994) in the Ohio part of the Appalachian basin.
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Reconnaissance Geologic Map of the Hayfork 15' Quadrangle, Trinity County, California
Irwin, William P.
2010-01-01
The Hayfork 15' quadrangle is located just west of the Weaverville 15' quadrangle in the southern part of the Klamath Mountains geologic province of northern California. It spans parts of six generally north-northwest-trending tectonostratigraphic terranes that are, from east to west, the Eastern Klamath, Central Metamorphic, North Fork, Eastern Hayfork, Western Hayfork, and Rattlesnake Creek terranes. Remnants of a once-widespread postaccretionary overlap assemblage, the Cretaceous Great Valley sequence, crop out at three localities in the southern part of the Hayfork quadrangle. The Tertiary fluvial and lacustrine Weaverville Formation occupies a large, shallow, east-northeast-trending graben in the south half of the quadrangle. The small area of Eastern Klamath terrane is part of the Oregon Mountain outlier, which is more widely exposed to the east in the Weaverville 15' quadrangle. It was originally mapped as a thrust plate of Bragdon(?) Formation, but it is now thought by some to be part of an outlier of Yreka terrane that has been dislocated 60 km southward by the La Grange Fault. The Central Metamorphic terrane, which forms the footwall of the La Grange Fault, was formed by the eastward subduction of oceanic crustal basalt (the Salmon Hornblende Schist) and its overlying siliceous sediments with interbedded limestone (the Abrams Mica Schist) beneath the Eastern Klamath terrane. Rb-Sr analysis of the Abrams Mica Schist indicates a Middle Devonian metamorphic age of approximately 380 Ma, which probably represents the age of subduction. The North Fork terrane, which is faulted against the western boundary of the Central Metamorphic terrane, consists of the Permian(?) North Fork ophiolite and overlying broken formation and melange of Permian to Early Jurassic (Pliensbachian) marine metasedimentary and metavolcanic rocks. The ophiolite, which crops out along the western border of the terrane, is thrust westward over the Eastern Hayfork terrane. The Eastern Hayfork terrane is a broken formation and melange of volcanic and sedimentary rocks, including chert and blocks of amphibolite, limestone, and serpentinized ultramafic rocks. The chert contains radiolarians of Permian and Triassic ages, but none of clearly Jurassic age. In contrast, the cherts of the North Fork terrane contain Early and Middle Jurassic radiolarians in addition to those of Permian and Triassic ages; also, some limestones of the Eastern Hayfork terrane contain fossil faunas of Tethyan affinity, but those of the North Fork terrane do not. The Western Hayfork terrane is an andesitic volcanic arc that was accreted to the Eastern Hayfork terrane. It consists mainly of metavolcaniclastic andesitic agglomerate and tuff, as well as argillite and chert, and it includes the dioritic Ironside Mountain batholith, which intruded during Middle Jurassic time. Two large patches of Western Hayfork terrane mapped in the central part of the Eastern Hayfork terrane may be exposed through windows in the Eastern Hayfork terrane, although the structural relation is not clear. The Rattlesnake Creek terrane is a melange that occupies only a small area in the southwest corner of the Hayfork quadrangle; however, it is a major unit in the Hyampom 15' quadrangle to the west. It consists mainly of broken and sheared ophiolitic rocks of probable Permian or early Mesozoic age. The Cretaceous Great Valley sequence overlap assemblage here postdates the Early Cretaceous (approximately 136 Ma) emplacement of the Shasta Bally batholith, which is widely exposed to the east in the Weaverville 15' quadrangle. The Great Valley sequence once covered much of the southern Klamath Mountains; however, in the Hayfork quadrangle, only three small patches remain near its southern boundary. Weakly consolidated nonmarine sedimentary rocks of the Weaverville Formation of mid-Tertiary age, which contain abundant fossil plants, occupy a large, shallow, east-northeast-trending graben
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Leventhal, J.S.
1991-01-01
In most black shales, such as the Chattanooga Shale and related shales of the eastern interior United States, increased metal and metalloid contents are generally related to increased organic carbon content, decreased sedimentation rate, organic matter type, or position in the basin. In areas where the stratigraphic equivalents of the Chattanooga Shale are deeply buried and and the organic material is thermally mature, metal contents are essentially the same as in unheated areas and correlate with organic C or S contents. This paradigm does not hold for the Cambrian Alum Shale Formation of Sweden where increased metal content does not necessarily correlate with organic matter content nor is metal enrichment necessarily related to land derived humic material because this organic matter is all of marine source. In southcentral Sweden the elements U, Mo, V, Ni, Zn, Cd and Pb are all enriched relative to average black shales but only U and Mo correlate to organic matter content. Tectonically disturbed and metamorphosed allochthonous samples of Alum Shale on the Caledonian front in western Sweden have even higher amounts for some metals (V, Ni, Zn and Ba) relative to the autochthonous shales in this area and those in southern Sweden. ?? 1991 Springer-Verlag.
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The Panther Mountain circular structure, a possible buried meteorite crater
NASA Astrophysics Data System (ADS)
Isachsen, Y. W.; Wright, S. F.; Revetta, F. A.; Duneen, R. J.
Panther Mountain, located near Phoenicia, New York, is part of the Catskill Mountains, which form the eastern end of the Allegheny Plateau in New York. It is a circular mass defined physiographically by an anomalous circular drainage pattern produced by Esopus Creek and its tributary Woodland Creek. The circular valley that rings the mountain is fracture-controlled; where bedrock is exposed, it shows a joint density 5 to 10 times greater than that on either side of the valley. Where obscured by alluvial valley fill, the bedrock's low seismic velocity suggests that this anomalous fracturing is continuous in the bedrock underlying the rim valley. North-south and east-west gravity and magnetic profiles were made across the structure. Terrane-corrected, residual gravity profiles show an 18-mgal negative anomaly, and very steep gradients indicate a near-surface source. Several possible explanations of the gravity data were modeled. We conclude that the Panther Mountain circular structure is probably a buried meteorite crater that formed contemporaneously with marine or fluvial sedimentation during Silurian or Devonian time. An examination of drill core and cuttings in the region is underway to search for ejecta deposits and possible seismic and tsunami effects in the sedimentary section. Success would result in both dating the impact and furnishing a chronostratigraphic marker horizon.
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Fryda, J.; Blodgett, R.B.
2008-01-01
The vast majority of Emsian gastropods from Limestone Mountain, Medfra B-4 quadrangle, west-central Alaska (Farewell terrane) belong to species with lecithotrophic larval strategy. The present data show that there is no significant difference in the paleobiogeo-graphic distribution of Emsian gastropod genera with lecithotrophic and planktotrophic larval strategies. Numerical analysis of the faunal affinities of the Emsian gastropod fauna from the Farewell terrane reveals that this terrane has much stronger faunal connections to regions like Variscan Europe, eastern Australia, and the Alexander terrane of southeast Alaska than to cratonic North America (Laurentia). The Canadian Arctic Islands is the only region of cratonic North America (Laurentia) that shows significant faunal affinities to the Emsian gastropod faunas of the Farewell terrane. The analysis also indicates a close faunal link between the Farewell and Alexander terranes. Published paleontological and geological data suggest that the Farewell and Alexander terranes represents tectonic entities that have been rifted away from the Siberia, Baltica, or the paleo-Pacific margin of Australia. The results of the present numerical analysis are not in conflict with any of these possibilities. However, the principle of spatial continuity of the wandering path prefers Siberia as the most probable "parental" paleocontinent for the derivation of both the Farewell and Alexander terranes. ?? 2008 The Geological Society of America.
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The Panther Mountain circular structure, a possible buried meteorite crater
NASA Technical Reports Server (NTRS)
Isachsen, Y. W.; Wright, S. F.; Revetta, F. A.; Duneen, R. J.
1992-01-01
Panther Mountain, located near Phoenicia, New York, is part of the Catskill Mountains, which form the eastern end of the Allegheny Plateau in New York. It is a circular mass defined physiographically by an anomalous circular drainage pattern produced by Esopus Creek and its tributary Woodland Creek. The circular valley that rings the mountain is fracture-controlled; where bedrock is exposed, it shows a joint density 5 to 10 times greater than that on either side of the valley. Where obscured by alluvial valley fill, the bedrock's low seismic velocity suggests that this anomalous fracturing is continuous in the bedrock underlying the rim valley. North-south and east-west gravity and magnetic profiles were made across the structure. Terrane-corrected, residual gravity profiles show an 18-mgal negative anomaly, and very steep gradients indicate a near-surface source. Several possible explanations of the gravity data were modeled. We conclude that the Panther Mountain circular structure is probably a buried meteorite crater that formed contemporaneously with marine or fluvial sedimentation during Silurian or Devonian time. An examination of drill core and cuttings in the region is underway to search for ejecta deposits and possible seismic and tsunami effects in the sedimentary section. Success would result in both dating the impact and furnishing a chronostratigraphic marker horizon.
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Capturing CO2 from Coal-Fired Power Plants: Challenges for a Comprehensive Strategy
2008-08-15
efficient flue gas desulfurization (FGD) or selective catalytic reduction (SCR) devices (or none), requiring either upgrading of existing FGD and SCR...saturated flue Figure 6. CO2 Price Projections CRS-16 42 Donald Shattuck, et al., A History of Flue Gas Desulfurization (FGD) — The Early Years, UE Technical...available in both the eastern and western parts of the United States, or by the use of emerging flue gas desulfurization (FGD) devices.46 At the time
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NASA Astrophysics Data System (ADS)
Tanahashi, M.; Morita, S.; Matsumoto, R.
2016-12-01
GR14 and HR15 survey cruises, which were dedicated to the LWD (Logging While Drilling), were carried out in summers of 2014 and 2015, respectively, by Meiji University and Geological Survey of Japan, AIST to explore the "gas chimney" structures in eastern margin of Japan Sea. Shallow (33 to 172m-bsf, average 136m-bsf) 33 LWD drilling were performed in Oki Trough, Off-Joetsu, and Mogami Trough areas along eastern margin of Japan Sea during two cruises. Schlumberger LWD tools, GeoVISION (resistivity), TeleScope, ProVISION (NMR) and SonicVISION were used during GR14. NeoScope (neutron) was added and SonicScope was replaced for SonicVISION during HR14. The data quality was generally good. "Gas chimney" structures with acoustic blanking columns on the high frequency seismic sections with mound and pockmark morphologic features on the sea bottom, are well developed within survey areas. Every LWD records taken from gas chimney structures during the cruises show high resistivity and acoustic velocity anomalies which suggest the development of gas hydrate. Characteristic development of massive gas hydrate was interpreted at the Umitaka CW mound structure, Off-Joetsu. The mound lies at 890-910m in water depth and has very rough bottom surface, regional high resistivity, regional high heat flow, several natural seep sites, 200m x 300m area, and 10-20m height. 8 LWD holes, J18L to J21L and J23L to J26L, were drilled on and around the mound. There are highly anomalous intervals which suggest the development of massive gas hydrate at J24L, with high resistivity, high Vp and Vs, high neutron porosity, low natural gamma ray intensity, low neutron gamma density, low NMR porosity, low NMR permeability, low formation sigma, from 10 to 110m-bsf with intercalating some thin less hydrate layers. It is interpreted that there is several tens of meter thick massive gas hydrate in the gas chimney mound. It is partly confirmed by the later nearby coring result which showed the repetition of the several meter thick massive hydrate recovery (Matsumoto et al., in this conference). Other LWD data at the sites on the mound shows lesser than J24L but still highly concentrated gas hydrate deposits. This study was conducted as a part of the methane hydrate research project funded by METI (the Ministry of Economy, Trade and Industry, Japan).
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NASA Astrophysics Data System (ADS)
Hong, Sung Kyung; Shinn, Young Jae; Choi, Jiyoung; Lee, Hyun Suk
2017-04-01
The gas generation and storage potentials of shale has mostly been assessed by original TOC (TOCo) and original kerogen type. However, in the Horn River Formation, organic geochemical tools and analysis are barely sufficient for assessing the TOCo and original kerogen type because residual carbon contents represent up to 90% of TOC in shales. Major and trace elements are used as proxies for the bottom water oxygen level, for terrestrial sediment input and for productivity, which is related with variation of kerogen type. By using the inorganic geochemical proxies, we attempt to assess original kerogen type in shale gas formation and suggest its implication for HIo (original Hydrogen Index) estimation. The estimated HIo in this study allows us to calculate a reliable TOCo. These results provide new insights into the accurate estimation of the hydrocarbon potential of shale gas resources. The inorganic geochemical proxies indicate vertical variations of productivity (EX-SiO2 and Baauth), terrestrial sediment input (Al2O3, Zr, Hf, and Nb) and oxygen content in bottom water during deposition (Moauth, Uauth and Th/U), which represent the temporal changes in the mixing ratio between Type II and III kerogens. The Horn River Formation has different HIo values calculated from EX-SiO2 (biogenic origin) and it is ranked by HIo value in descending order: Evie and Muskwa members (500-700 mgHC/gTOC) > middle Otterpark Member (400-500 mgHC/gTOC) > upper Otterpark Member (300-400 mgHC/gTOC) > lower Otterpark Member (200 mgHC/gTOC). Based on the original kerogen type and TOCo, the gas generation and storage potentials of the Evie, middle Otterpark and Muskwa members are higher than those of other members. The source rock potential is excellent for the Evie Member with a remarkable difference between TOCo and measured TOC.
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NASA Astrophysics Data System (ADS)
Tanahashi, M.; Morita, S.; Matsumoto, R.
2017-12-01
Two dedicated LWD (Logging While Drilling) cruises, GR14 and HR15, were conducted in summers of 2014 and 2015, respectively, by Meiji University and Geological Survey of Japan, AIST to explore the gas chimney structures, which are characterized by the columnar acoustic blanking below the topographic mound and/or pockmarks in eastern margin of Japan Sea. Shallow (33 to 172m-bsf, average 136m-bsf) 33 LWD drillings were carried out generally in and around gas chimney structures which are in Oki Trough, Off-Joetsu, and Mogami Trough areas, eastern margin of Japan Sea, during two cruises. Schlumberger LWD tools, GeoVISION (resistivity), TeleScope, ProVISION (NMR) and SonicVISION (sonic) were applied during GR14. NeoScope (neutron) was added and SonicScope was replaced for SonicVISION during HR15. The presence of thick highly-anomalous intervals within the LWD data at site J24L suggests the development of massive gas hydrate within Off-Joetsu, by very high resistivity ( 10,000 Ωm), high Vp ( 3,700 m/s) and Vs (370-1,839 m/s), high neutron porosity ( 1.2), low natural gamma ray intensity ( 0 API), low neutron gamma density ( 0.8 g/cm3), low NMR porosity ( 0.0), low permeability (10-2-10-4 mD), low formation neutron sigma (26-28). The extreme physical properties intervals suggest the development of the almost pure hydrate. Because of the clear contrast between pure hydrate and seawater saturated fine sediments, the hydrate amount can be estimated quantitatively based on the assumptions as the two component system of pure hydrate and the monotonous seawater saturated fine sediments. This study was conducted as a part of the methane hydrate research project funded by METI (the Ministry of Economy, Trade and Industry, Japan).
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Towards a High-resolution Time Scale for the Early Devonian
NASA Astrophysics Data System (ADS)
Dekkers, M. J.; da Silva, A. C.
2017-12-01
High-resolution time scales are crucial to understand Earth's history in detail. The construction of a robust geological time scale, however, inevitably becomes increasingly harder further back in time. Uncertainties associated with anchor radiometric ages increase in size, not speaking of the mere presence of suitable datable strata. However, durations of stages can be tightly constrained by making use of cyclic expressions in sediments, an approach that revolutionized the Cenozoic time scale. When precisely determined durations are stitched together, ultimately, a very precise time scale is the result. For the Mesozoic and Paleozoic an astronomical solution as a tuning target is not available but the dominant periods of eccentricity, obliquity and precession are reasonably well constrained for the entire Phanerozoic which enables their detection by means of spectral analysis. Eccentricity is time-invariant and is used as the prime building block. Here we focus on the Early Devonian, on its lowermost three stages: the Lochkovian, Pragian and Emsian. The uncertainties on the Devonian stage boundaries are currently in the order of several millions of years. The preservation of climatic cycles in diagenetically or even anchimetamorphically affected successions, however, is essential. The fit of spectral peak ratios with those calculated for orbital cycles, is classically used as a strong argument for a preserved climatic signal. Here we use primarily the low field magnetic susceptibility (MS) as proxy parameter, supported by gamma-ray spectrometry to test for consistency. Continuous Wavelet Transform, Evolutive Harmonic Analysis, Multitaper Method, and Average Spectral Misfit are used to reach an optimal astronomical interpretation. We report on classic Early Devonian sections from the Czech Republic: the Pozar-CS (Lochkovian and Pragian), Pod Barrandovem (Pragian and Lower Emsian), and Zlichov (Middle-Upper Emsian). Also a Middle-Upper Emsian section from the US (Road 199 section, Kingston, New York) will be targeted. Strata display Milankovitch cycles to a varying visible degree but spectral analysis of MS with supporting magnetic property tests enables to constrain durations up to an order of magnitude more precise than in the current (2012) Geological Time Scale.
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NASA Astrophysics Data System (ADS)
Glen, R. A.
The Palaeozoic history of the western part of the Lachlan Fold Belt in New South Wales was dominated by strike-slip tectonics. In the latest Silurian to late Early Devonian, an area of crust >25,000 km 2 lying west of the Gilmore Suture underwent regional sinistral transtension, leading to the development of intracratonic successor basins, troughs and flanking shelves. The volcaniclastic deep-water Mount Hope Trough and Rast Trough, the siliciclastic Cobar Basin and the volcanic-rich Canbelego-Mineral Hill Belt of the Kopyje Shelf all were initiated around the Siluro-Devonian boundary. They all show clear evidence of having evolved by both active syn-rift processes and passive later post-rift (sag-phase) processes. Active syn-rift faulting is best documented for the Cobar Basin and Mount Hope Trough. In the former case, the synchronous activity on several fault sets suggests that the basin formed by sinistral transtension in response to a direction of maximum extension oriented NE-SW. Structures formed during inversion of the Cobar Basin and Canbelego-Mineral Hill Belt indicate closure under a dextral transpressive strain regime, with a far-field direction of maximum shortening oriented NE-SW. In the Cobar Basin, shortening was partitioned into two structural zones. A high-strain zone in the east was developed into a positive half-flower structure by re-activation of early faults and by formation of short-cut thrusts, some with strike-slip movement, above an inferred steep strike-slip fault. Intense subvertical cleavage, a steep extension lineation and variably plunging folds are also present. A lower-strain zone to the west developed by syn-depositional faults being activated as thrusts soling into a gently dipping detachment. A subvertical cleavage and steep extension lineation are locally present, and variably plunging folds are common. Whereas Siluro-Devonian basin-opening appeared to be synchronous in the western part of the fold belt, the different period of basin inversion in the Cobar region (late Early Devonian and Carboniferous) may reflect different movement histories on the master strike-slip faults in this part of the fold belt, the Gilmore Suture and Kiewa Fault.
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Frappier, Amy Benoit; Lindemann, Richard H; Frappier, Brian R
2015-04-30
Dacryoconarids are extinct marine zooplankton known from abundant, globally distributed calcite microfossils in the Devonian, but their shell stable isotope composition has not been previously explored. Devonian stable isotope stratigraphy is currently limited to less common invertebrates or bulk rock analyses of uncertain provenance. As with Cenozoic planktonic foraminifera, isotopic analysis of dacryoconarid shells could facilitate higher-resolution, geographically widespread stable isotope records of paleoenvironmental change, including marine hypoxia events, climate changes, and biocrises. We explored the use of Dacryoconarid isotope stratigraphy as a viable method in interpreting paleoenvironments. We applied an established method for determining stable isotope ratios (δ(13) C, δ(18) O values) of small carbonate microfossils to very well-preserved dacryoconarid shells. We analyzed individual calcite shells representing five common genera using a Kiel carbonate device coupled to a MAT 253 isotope ratio mass spectrometer. Calcite shell δ(13) C and δ(18) O values were compared by taxonomic group, rock unit, and locality. Single dacryoconarid calcite shells are suitable for stable isotope analysis using a Kiel-IRMS setup. The dacryoconarid shell δ(13) C values (-4.7 to 2.3‰) and δ(18) O values (-10.3 to -4.8‰) were consistent across taxa, independent of shell size or part, but varied systematically through time. Lower fossil δ(18) O values were associated with warmer water temperature and more variable δ(13) C values were associated with major bioevents. Dacryoconarid δ(13) C and δ(18) O values differed from bulk rock carbonate values. Dacryoconarid individual microfossil δ(13) C and δ(18) O values are highly sensitive to paleoenvironmental changes, thus providing a promising avenue for stable isotope chemostratigraphy to better resolve regional to global paleoceanographic changes throughout the upper Silurian to the upper Devonian. Our results warrant further exploration of dacryoconarid stable isotope proxy sensitivity, the isotopic contrast among dacryoconarids, other taxa, and bulk rock, as well as other potential dacryoconarid proxies (Mg/Ca, Sr/Ca, (87) Sr/(86) Sr, microlaser and ion microprobe isotope techniques, and clumped isotopes) for stratigraphic research. Copyright © 2015 John Wiley & Sons, Ltd.
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Economic decision making and the application of nonparametric prediction models
Attanasi, E.D.; Coburn, T.C.; Freeman, P.A.
2008-01-01
Sustained increases in energy prices have focused attention on gas resources in low-permeability shale or in coals that were previously considered economically marginal. Daily well deliverability is often relatively small, although the estimates of the total volumes of recoverable resources in these settings are often large. Planning and development decisions for extraction of such resources must be areawide because profitable extraction requires optimization of scale economies to minimize costs and reduce risk. For an individual firm, the decision to enter such plays depends on reconnaissance-level estimates of regional recoverable resources and on cost estimates to develop untested areas. This paper shows how simple nonparametric local regression models, used to predict technically recoverable resources at untested sites, can be combined with economic models to compute regional-scale cost functions. The context of the worked example is the Devonian Antrim-shale gas play in the Michigan basin. One finding relates to selection of the resource prediction model to be used with economic models. Models chosen because they can best predict aggregate volume over larger areas (many hundreds of sites) smooth out granularity in the distribution of predicted volumes at individual sites. This loss of detail affects the representation of economic cost functions and may affect economic decisions. Second, because some analysts consider unconventional resources to be ubiquitous, the selection and order of specific drilling sites may, in practice, be determined arbitrarily by extraneous factors. The analysis shows a 15-20% gain in gas volume when these simple models are applied to order drilling prospects strategically rather than to choose drilling locations randomly. Copyright ?? 2008 Society of Petroleum Engineers.
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Klett, T.R.
2000-01-01
Undiscovered, conventional oil and gas resources were assessed within total petroleum systems of the Grand Erg/Ahnet Province (2058) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The majority of the Grand Erg/ Ahnet Province is in western Algeria; a very small portion extends into Morocco. The province includes the Timimoun Basin, Ahnet Basin, Sbaa Basin, Mouydir Basin, Benoud Trough, Bechar/Abadla Basin(s), and part of the Oued Mya Basin. Although several petroleum systems may exist within each of these basins, only seven ?composite? total petroleum systems were identified. Each total petroleum system occurs in a separate basin, and each comprises a single assessment unit. The main source rocks are the Silurian Tanezzuft Formation (or lateral equivalents) and Middle to Upper Devonian mudstone. Maturation history and the major migration pathways from source to reservoir are unique to each basin. The total petroleum systems were named after the oldest major source rock and the basin in which it resides. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Grand Erg/ Ahnet Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Tanezzuft-Timimoun 31 1,128 56 Tanezzuft-Ahnet 34 2,973 149 Tanezzuft-Sbaa 162 645 11 Tanezzuft-Mouydir 12 292 14 Tanezzuft-Benoud 72 2,541 125 Tanezzuft-Bechar/Abadla 16 441 22
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NASA Astrophysics Data System (ADS)
Keppie, J. Duncan; Nance, R. Damian; Murphy, J. Brendan; Dostal, J.
2003-04-01
Modern Tethyan, Mediterranean, and Pacific analogues are considered for several Appalachian, Caledonian, and Variscan terranes (Carolina, West and East Avalonia, Oaxaquia, Chortis, Maya, Suwannee, and Cadomia) that originated along the northern margin of Neoproterozoic Gondwana. These terranes record a protracted geological history that includes: (1) ˜1 Ga (Carolina, Avalonia, Oaxaquia, Chortis, and Suwannee) or ˜2 Ga (Cadomia) basement; (2) 750-600 Ma arc magmatism that diachronously switched to rift magmatism between 590 and 540 Ma, accompanied by development of rift basins and core complexes, in the absence of collisional orogenesis; (3) latest Neoproterozoic-Cambrian separation of Avalonia and Carolina from Gondwana leading to faunal endemism and the development of bordering passive margins; (4) Ordovician transport of Avalonia and Carolina across Iapetus terminating in Late Ordovician-Early Silurian accretion to the eastern Laurentian margin followed by dispersion along this margin; (5) Siluro-Devonian transfer of Cadomia across the Rheic Ocean; and (6) Permo-Carboniferous transfer of Oaxaquia, Chortis, Maya, and Suwannee during the amalgamation of Pangea. Three potential models are provided by more recent tectonic analogues: (1) an "accordion" model based on the orthogonal opening and closing of Alpine Tethys and the Mediterranean; (2) a "bulldozer" model based on forward-modelling of Australia during which oceanic plateaus are dispersed along the Australian plate margin; and (3) a "Baja" model based on the Pacific margin of North America where the diachronous replacement of subduction by transform faulting as a result of ridge-trench collision has been followed by rifting and the transfer of Baja California to the Pacific Plate. Future transport and accretion along the western Laurentian margin may mimic that of Baja British Columbia. Present geological data for Avalonia and Carolina favour a transition from a "Baja" model to a "bulldozer" model. By analogy with the eastern Pacific, we name the oceanic plates off northern Gondwana: Merlin (≡Farallon), Morgana (≡Pacific), and Mordred (≡Kula). If Neoproterozoic subduction was towards Gondwana, application of this combined model requires a total rotation of East Avalonia and Carolina through 180° either during separation (using a western Transverse Ranges model), during accretion (using a Baja British Columbia "train wreck" model), or during dispersion (using an Australia "bulldozer" model). On the other hand, Siluro-Devonian orthogonal transfer ("accordion" model) from northern Africa to southern Laurussia followed by a Carboniferous "Baja" model appears to best fit the existing data for Cadomia. Finally, Oaxaquia, Chortis, Maya, and Suwannee appear to have been transported along the margin of Gondwana until it collided with southern Laurentia on whose margin they were stranded following the breakup of Pangea. Forward modeling of a closing Mediterranean followed by breakup on the African margin may provide a modern analogue. These actualistic models differ in their dictates on the initial distribution of the peri-Gondwanan terranes and can be tested by comparing features of the modern analogues with their ancient tectonic counterparts.
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Geology and hydrocarbon habitat of the Amu-Darya region (central Asia)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stoecklin, J.; Orassianou, T.
1991-08-01
The Amu-Darya region, shared by the Soviet Republics of Turkmenistan, Uzbekistan, and Tadzhikistan, is the second-largest gas province of the USSSR after western Siberia both production and reserves. Its more than 180 gas, gas-condensate, and minor oil fields include 6 giants with reserves of over 3 tcf, such as the Sovietabad field of eastern Turkmenistan, which in 1989 produced nearly 1 tcf of gas and which had an initial recoverable reserve of 38 tcf of gas. oil in addition to gas is produced mainly in the eastern Uzbekian and Tadzhikian parts. The region represents a large depression covering the southeasternmore » portion of the epi-Hercynian Turan platform to the north of the Alpine-Himalayan fold belts of northeastern Iran and northern Afghanistan. Continental, paralic, lagoonal, and shallow-marine environments characterized Mesozoic-Tertiary platform sedimentation, with maximum sediment thicknesses of about 10 km in the Alpine foredeeps at the southern platform margin. Large amounts of essentially gas-prone organic matter accumulated in the Late Triassic to Middle Jurassic. Main hydrocarbon reservoirs are Callovian-Oxfordian shelf-platform and reefal carbonates under cover of thick Kimmeridgian-Tithonian salt, and shale-sealed Lower Cretaceous continental and near-shore deltaic sandstones. In the Tadzhik basin in the extreme east, oil is contained in Lower Tertiary fractured carbonates interbedded with bituminous shales. Synsedimentary differential movements and gently folding in the Miocene to Pliocene were the main trap mechanisms. The region has still a considerable undrilled future potential, particularly in its deeper southern parts.« less
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Federal Register 2010, 2011, 2012, 2013, 2014
2010-07-27
... prepared by the FERC entitled ``An Interstate Natural Gas Facility on My Land? What Do I Need To Know?'' is available for viewing on the FERC Web site ( http://www.ferc.gov ). This fact sheet addresses a number of... metering and regulating (M&R) station in the Borough of Staten Island, New York; Construction of...
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Burke, C M; Montevecchi, W A; Wiese, F K
2012-08-15
Petroleum exploration and production on the Grand Bank of eastern Canada overlaps with productive marine habitat that supports over 40 million marine birds annually. Environmental assessments for oil and gas projects in the region predict insignificant adverse effects on marine birds from oil spills, incineration in platform flares and collisions. Limited baseline data on seasonal occupancies and a failure to quantify the nature and extent of marine bird attraction to platforms and related mortality undermines these assessments. We conducted 22 surveys to offshore platforms on the Grand Bank during 1999-2003 to measure avian associations with platforms and to determine the level of monitoring needed to assess the risks to marine birds. We document seasonal shifts in marine bird occurrences and higher densities of auks (fall) and shearwaters (summer) around platforms relative to surrounding areas. The limited temporal and spatial coverage of our surveys is more robust than existing industry monitoring efforts, yet it is still inadequate to quantify the scale of marine bird associations with platforms or their associated mortality risks. Systematic observations by independent biologists on vessels and platforms are needed to generate reliable assessments of risks to marine birds. Instead, the regulatory body for offshore oil and gas in eastern Canada (Canada - Newfoundland and Labrador Offshore Petroleum Board; C-NLOPB) supports industry self-reporting as the accepted form of environmental monitoring. Conflicting responsibilities of oil and gas regulatory agencies for both energy development and environmental monitoring are major barriers to transparency, unbiased scientific inquiry and adequate environmental protection. Similar conflicts with the oil and gas regulatory body in the United States, the former Minerals and Management Service (MMS) were identified by the U.S. President as a major contributor to the Deepwater Horizon disaster in the Gulf of Mexico. The MMS has since been restructured into the Bureau of Ocean Energy Management, (BOEM) with separate departments responsible for drilling leases and the regulation of drilling activities. Similar restructuring of the oil and gas regulatory bodies in Canada is needed for better public information, scientific investigation and environmental protection in the offshore. Copyright © 2012 Elsevier Ltd. All rights reserved.
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Evaluating the CO 2 emissions reduction potential and cost of power sector re-dispatch
DOE Office of Scientific and Technical Information (OSTI.GOV)
Steinberg, Daniel C.; Bielen, David A.; Townsend, Aaron
Prior studies of the U.S. electricity sector have recognized the potential to reduce carbon dioxide (CO2) emissions by substituting generation from coal-fired units with generation from under-utilized and lower-emitting natural gas-fired units; in fact, this type of 're-dispatch' was invoked as one of the three building blocks used to set the emissions targets under the Environmental Protection Agency's Clean Power Plan. Despite the existence of surplus natural gas capacity in the U.S., power system operational constraints not often considered in power sector policy analyses, such as transmission congestion, generator ramping constraints, minimum generation constraints, planned and unplanned generator outages, andmore » ancillary service requirements, could limit the potential and increase the cost of coal-to-gas re-dispatch. Using a highly detailed power system unit commitment and dispatch model, we estimate the maximum potential for re-dispatch in the Eastern Interconnection, which accounts for the majority of coal capacity and generation in the U.S. Under our reference assumptions, we find that maximizing coal-to-gas re-dispatch yields emissions reductions of 230 million metric tons (Mt), or 13% of power sector emissions in the Eastern Interconnection, with a corresponding average abatement cost of $15-$44 per metric ton of CO2, depending on the assumed supply elasticity of natural gas.« less
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Gillespie, W.H.; Rothwell, G.W.; Scheckler, S.E.
1981-01-01
Lagenostomalean-type seeds in bifurcating cupule systems have been discovered in the late Devonian Hampshire Formation of Randolph County, West Virginia, USA (Fig. 1). The associated megaflora, plants from coal balls, and vertebrate and invertebrate faunas demonstrate that the material is Famennian; the microflora indicates a more specific Fa2c age. Consequently, these seeds predate Archaeosperma arnoldii1 from the Fa2d of northeastern Pennsylvania, the oldest previously reported seed. By applying precision fracture, transfer, de??gagement, and thin-section techniques to selected cupules from the more than 100 specimens on hand, we have determined the three-dimensional morphology and histology of the seeds (Fig. 2a-h, k) and cupule systems. A comparison with known late Devonian to early Carboniferous seeds reveals that ours are more primitively organized than all except Genomosperma2,3. ?? 1981 Nature Publishing Group.
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Paleocurrent analysis of a deformed Devonian foreland basin in the northern Appalachians, Maine, USA
Bradley, D.C.; Hanson, L.S.
2002-01-01
New paleocurrent data indicate that the widespread Late Silurian and Devonian flysch and molasse succession in Maine was deposited in an ancestral, migrating foreland basin adjacent to an advancing Acadian orogenic belt. The foreland-basin sequence spread across a varied Silurian paleogeography of deep basins and small islands-the vestiges of an intraoceanic arc complex that not long before had collided with the Laurentian passive margin during the Ordovician Taconic Orogeny. We report paleocurrents from 43 sites representing 12 stratigraphic units, the most robust and consistent results coming from three units: Madrid Formation (southwesterly paleoflow), Carrabassett Formation (northerly paleoflow), and Seboomook Group (westerly paleoflow). Deformation and regional metamorphism are sufficiently intense to test the limits of paleocurrent analysis requiring particular care in retrodeformation. ?? 2002 Elsevier Science B.V. All rights reserved.
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Gibson, D.L.
2000-01-01
Previously undated post-Devonian sediments outcropping north of Fowlers Gap station near the western margin of the Bancannia Trough are shown by plant macro- and microfossil determinations to be of Early Cretaceous (most likely Neocomian and/or Aptian) age, and thus part of the Eromanga Basin. They are assigned to the previously defined Telephone Creek Formation. Study of the structural configuration of this unit and the unconformably underlying Devonian rocks suggests that the gross landscape architecture of the area results from post-Early Cretaceous monoclinal folding along blind faults at the western margin of the trough, combined with the effects of differential erosion. This study shows that, while landscape evolution in the area has been dynamic, the major changes that have occurred are on a geological rather than human timescale.
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Matsunaga, Kelly K S; Tomescu, Alexandru M F
2017-05-01
Fossil plants are found as fragmentary remains and understanding them as natural species requires assembly of whole-organism concepts that integrate different plant parts. Such concepts are essential for incorporating fossils in hypotheses of plant evolution and phylogeny. Plants of the Early Devonian are crucial to reconstructing the initial radiation of tracheophytes, yet few are understood as whole organisms. This study assembles a whole-plant concept for the Early Devonian lycophyte Sengelia radicans gen. et sp. nov., based on morphometric data and taphonomic observations from >1000 specimens collected in the Beartooth Butte Formation (Wyoming, USA). Sengelia radicans occupies a key position between stem-group and derived lycophyte lineages. Sengelia had a rooting system of downward-growing root-bearing stems, formed dense monotypic mats of prostrate shoots in areas that experienced periodic flooding, and was characterized by a life-history strategy adapted for survival after floods, dominated by clonality, and featuring infrequent sexual reproduction. Sengelia radicans is the oldest among the very few early tracheophytes for which a detailed, rigorous whole-plant concept integrates morphology, growth habit, life history and growth environment. This plant adds to the diversity of body plans documented among lycophytes and may help elucidate patterns of morphological evolution in the clade. © The Author 2017. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com
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Faulting at Thebes Gap, Mo. -Ill. : Implications for New Madrid tectonism
DOE Office of Scientific and Technical Information (OSTI.GOV)
Harrison, R.W.; Schultz, A.P.
1992-01-01
Recent geologic mapping in the Thebes Gap area has identified numerous NNE- and NE-striking faults having a long-lived and complex structural history. The faults are located in an area of moderate recent seismicity at the northern margin of the Mississippi embayment, approximately 45 km north of the New Madrid seismic zone. Earliest deformation occurred along dextral strike-slip faults constrained as post-Devonian and pre-Cretaceous. Uplift and erosion of all Carboniferous strata suggest that this faulting is related to development of the Pascola arch (Ouachita orogeny). This early deformation is characterized by strongly faulted and folded Ordovician through Devonian rocks overlain inmore » places with angular unconformity by undeformed Cretaceous strata. Elsewhere, younger deformation involves Paleozoic, Cretaceous, Paleocene, and Eocene formations. These units have experienced both minor high-angle normal faulting and major, dextral strike-slip faulting. Quaternary-Tertiary Mounds Gravel is also involved in the latest episode of strike-slip deformation. Enechelon north-south folds, antithetic R[prime] shears, and drag folds indicate right-lateral motion. Characteristic positive and negative flower structures are commonly revealed in cross section. Right-stepping fault strands have produced pull-apart basins where Ordovician, Silurian, Devonian, Cretaceous, and Tertiary units are downdropped several hundreds of meters and occur in chaotic orientations. Similar fault orientations and kinematics, as well as recent seismicity and close proximity, clearly suggest a structural relationship between deformation at Thebes Gap and tectonism associated with the New Madrid area.« less
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Walsh, Gregory J.; Kim, Jonathan; Gale, Marjorie H.; King, Sarah M.
2010-01-01
The bedrock geology of the Montpelier and Barre West quadrangles consists of Silurian and Devonian metasedimentary rocks of the Connecticut Valley-Gaspe synclinorium (CVGS) and metasedimentary, metavolcanic, and metaintrusive rocks of the Cambrian and Ordovician Moretown and Cram Hill Formations. Devonian granite dikes occur throughout the two quadrangles but are more abundant in the Silurian and Devonian rocks. The pre-Silurian rocks are separated from the rocks of the CVGS by the informally named 'Richardson Memorial Contact,' historically interpreted as either an unconformity or a fault. The results of this report represent mapping by G.J. Walsh, Jonathan Kim, and M.H. Gale from 2002 to 2005. S.M. King assisted Kim and Gale from 2002 to 2003. A.M. Satkoski (Indiana University) assisted Walsh, and L.R. Pascale (University of Vermont) and C.M. Orsi (Middlebury College) assisted Kim and Gale as summer interns in 2003. This study was designed to map the bedrock geology in the area. This map supersedes a preliminary map of the Montpelier quadrangle (Kim, Gale, and others, 2003). A companion study in the Barre West quadrangle (Walsh and Satkoski, 2005) determined the levels of naturally occurring radioactivity in the bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping to identify which rock types were potential sources of radionuclides. Results of that study indicate that the carbonaceous phyllites in the CVGS have the highest levels of natural radioactivity.
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NASA Astrophysics Data System (ADS)
Wolniewicz, Paweł
2016-09-01
Stromatoporoids of the family Actinostromatidae are common constituents of Givetian to Frasnian (Devonian) organic buildups. The species-level structure of actinostromatid assemblages from the Devonian of southern Poland is described in the present paper, with special emphasis on ecological factors that influenced species composition of the communities. Nine species of the genera Actinostroma and Bifariostroma are distinguished. Members of the family Actinostromatidae predominated in stromatoporoid assemblages within lower Frasnian carbonate buildup margins. The most diverse actinostromatid faunas were found within the middle Givetian Stringocephalus Bank, in the upper Givetian-lower Frasnian biostromal complex and in the lower Frasnian organic buildups. Species-level biodiversity was lowest within detrital facies which surrounded the Frasnian carbonate buildups. Species of Actinostroma with well-developed colliculi are commonest within the middle Givetian to early Frasnian coral-stromatoporoid biostromal complexes, whereas species with strongly reduced colliculi predominate early-middle Frasnian organic buildups. The skeletal structure of actinostromatids reflects environmental changes, documenting a transition from species with thin, close-set pillars and widely spaced laminae (common in the middle Givetian) to those with long, thick pillars and megapillars (in Bifariostroma), which were predominant during the early and middle Frasnian. The distribution of growth forms among species reveals a significant intraspecific variation. Species of Actinostroma can be either tabular or low domical, depending on the palaeoenvironmental setting. Thus, the present study confirms that stromatoporoid morphology was influenced by environmental conditions.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Lorenz, J.C.
1997-03-01
The Molina Member of the Wasatch Formation produces natural gas from several fields along the Colorado River in the Piceance Basin, northwestern Colorado. The Molina Member is a distinctive sandstone that was deposited in a unique fluvial environment of shallow-water floods. This is recorded by the dominance of plane-parallel bedding in many of the sandstones. The Molina sandstones crop out on the western edge of the basin, and have been projected into the subsurface and across the basin to correlate with thinner sandy units of the Wasatch Formation at the eastern side of the basin. Detailed study, however, has shownmore » that the sedimentary characteristics of the type-section Molina sandstones are incompatible with a model in which the eastern sandstones are its distal facies equivalent. Rather, the eastern sandstones represent separate and unrelated sedimentary systems that prograded into the basin from nearby source-area highlands. Therefore, only the subsurface {open_quotes}Molina{close_quotes} reservoirs that are in close proximity to the western edge of the basin are continuous with the type-section sandstones. Reservoirs in the Grand Valley and Rulison gas fields were deposited in separate fluvial systems. These sandstones contain more typical fluvial sedimentary structures such as crossbeds and lateral accretion surfaces. Natural fractures play an important role in enhancing the conductivity and permeability of the Molina and related sandstones of the Wasatch Formation.« less
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Ryder, Robert T.
1998-01-01
Oil and gas trapped in Lower Silurian 'Clinton' sands and Medina Group sandstone constitute a regional hydrocarbon accumulation that extends 425 mi in length from Ontario, Canada to northeastern Kentucky. The 125-mi width of the accumulation extends from central Ohio eastward to western Pennsylvania and west-central New York. Lenticular and intertonguing reservoirs, a gradual eastward decrease in reservoir porosity and permeability, and poorly segregated gas, oil, and water in the reservoirs make it very difficult to recognize clear-cut geologic- and production-based subdivisions in the accumulation that are relevant to resource assessment. However, subtle variations are recognizable that permit the regional accumulation to be subdivided into three tentative parts: a western gas-bearing part having more or less discrete fields; an eastern gas-bearing part having many characteristics of a basin-centered accumulation; and a central oil- and gas-bearing part with 'hybrid' fields that share characteristics of both discrete and basin-centered accumulation. A data set of 25 oil and gas fields is used in the report to compare selected attributes of the three parts of the regional accumulation. A fourth part of the regional accumulation, not discussed here, is an eastern extension of basin-centered accumulation having local commercial gas in the Tuscarora Sandstone, a proximal facies of the Lower Silurian depositional system. A basin-centered gas accumulation is a regionally extensive and commonly very thick zone of gas saturation that occurs in low-permeability rocks in the central, deeper part of a sedimentary basin. Another commonly used term for this type of accumulation is deep-basin gas accumulation. Basin-centered accumulation is a variety of continuous-type accumulation. The 'Clinton' sands and Medina Group sandstone part of the basin-centered gas accumulation is characterized by: a) reservoir porosity ranging from about 5 to 10 percent; b) reservoir permeability equal to or less than 0.1 mD; c) low reservoir water saturation and an average water yield per well less than about 9 to 13 BW/MMCFG; d) a broadly defined updip water-block trap; e) underpressured reservoirs with a gradient ranging from 0.25 to 0.35 psi/ft; and f) reservoir temperature of at least 125? F (52? C). Other than for historical and location purposes, the term field has little or no meaning as an assessment unit for the regional accumulation. In practice, each designated field represents a production sweet spot having relatively high EURs per well that in turn merges with surrounding gas-productive regions that are generally larger in area but have lower EURs per well. This important feature of the Lower Silurian regional accumulation, whereby most wells drilled into it are gas productive, must be considered when assessing its potential for remaining recoverable gas resources. Most of the remaining gas resources reside in 'Clinton' sands and Medina Group sandstone in the basin-centered part of the accumulation where as much as several tens of TCF of natural gas may be technically recoverable. The Tuscarora Sandstone in the eastern extension of the basin-centered part of the accumulation underlies a very large area and, although commonly characterized by very low porosity and permeability and low-Btu gas, probably contains additional gas resources. Remaining undiscovered recoverable gas and oil resources in the discrete and hybrid parts of the accumulation are primarily located beneath Lake Erie.
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Reconnaissance of ground-water resources in the Eastern Coal Field Region, Kentucky
Price, William E.; Mull, D.S.; Kilburn, Chabot
1962-01-01
In the Eastern Coal Field region of Kentucky, water is obtained from consolidated sedimentary rocks ranging in age from Devonian to Pennsylvanian and from unconsolidated sediments of Quaternary age. About 95 percent of the area is underlain by shale, sandstone, and coal of Pennsylvanian age. Principal factors governing the availability of water in the region are depth, topographic location, and the lithology of the aquifer penetrated. In general, the yield of the well increases as the depth increases. Wells drilled in topographic lows, such as valleys, are likely to yield more water than wells drilled on topographic highs, such as hills. Sand and gravel, present in thick beds in the alluvium along the Ohio River, form the most productive aquifer in the Eastern Coal Field. Of the consolidated rocks in the region sandstone strata are the best aquifers chiefly because joints, openings along bedding planes, and intergranular pore spaces are best developed in them. Shale also supplies water to many wells in the region, chiefly from joints and openings along bedding planes. Coal constitutes a very small part of the sedimentary section, but it yields water from fractures to many wells. Limestone yields water readily from solution cavities developed along joint and bedding-plane openings. The availability of water in different parts of the region was determined chiefly by analyzing well data collected during the reconnaissance. The resulting water-availability maps, published as hydrologic investigations atlases (Price and others, 1961 a, b; Kilburn and others, 1961) were designed to be used in conjunction with this report. The maps were constructed by dividing the region into 5 physiographic areas, into 10 subareas based chiefly on lithologic facies, and, in the case of the Kanawha section, into 2 quality-of-water areas. The 5 physiographic areas are the Knobs, Mississippian Plateau, Cumberland Plateau section, Kanawha section, and Cumberland Mountain section. The 10 subareas are as follows: 1. The Chattanooga shale. This black shale yields only enough water for a minimum domestic supply-100 to 500 gpd (gallons per day). 2. Mississippian-Devonian rocks exposed along Pine Mountain. These rocks consist of shale, limestone, and sandstone. The limestone yields water to springs, and faulted limestone and sandstone lying below drainage may yield several hundred gallons per minute to wells. 3. Mississippian rocks exposed along the western margin of the region. These rocks consist of thick limestone underlain by shale. The limestone yields enough water for a modern domestic supply (more than 500 gpd) , and discharges as much as 100 gpm (gallons per minute) to springs. The shale yields only enough water for a minimum domestic supply. 4. Subarea 1 of the Lee formation of Pennsylvanian age. The thin shaly rocks of this subarea generally yield only enough water for a minimum domestic supply. 5. Subarea 2 of the Lee formation of Pennsylvanian age. This subarea is predominantly underlain by massive sandstones; it generally yields enough water for a modern domestic supply, and in some places, enough water for small public and industrial supplies. 6. Subarea 1 of the Breathitt and Conemaugh formations of Pennsylvanian age. Rocks in this subarea contain more shale than sandstone. Wells in this subarea range from adequate for a minimum domestic supply to adequate for a modern domestic supply. 7. Subarea 2 of the Breathitt formation of Pennsylvanian age and undifferentiated post-Lee Pennsylvanian rocks. Wells in this subarea yield enough water for a modern domestic supply, and in many places, enough water for small public and industrial supplies. 8. Alluvium along the Ohio River. Mostly composed of glacial outwash sand and gravel, the alluvium is reported to yield as much as 360 gpm to wells. 9. Alluvium along the Big Sandy River and lower reaches of its Tug and Levisa Forks. Where consisting mostly of sand,
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Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Pilot-Scale Test Results
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gary M. Blythe
2006-03-01
This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, ''Field Testing of a Wet FGD Additive.'' The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemissions of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate that the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal.more » The project will conduct pilot and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosage requirements to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB co-fired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot and full-scale jet bubbling reactor (JBR) FGD systems to be tested. A third utility, to be named later, will provide the high-sulfur Eastern bituminous coal full-scale FGD test site. Degussa Corporation is providing the TMT-15 additive and technical support to the test program. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High Sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. This topical report presents the results from the Task 2 and Task 4 pilot-scale additive tests. The Task 3 and Task 5 full-scale additive tests will be conducted later in calendar year 2006.« less
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Physical oceanography of the US Atlantic and eastern Gulf of Mexico. Final report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Milliman, J.D.; Imamura, E.
The report provides a summary of the physical oceanography of the U.S. Atlantic and Eastern Gulf of Mexico and its implication to offshore oil and gas exploration and development. Topics covered in the report include: meteorology and air-sea interactions, circulation on the continental shelf, continental slope and rise circulation, Gulf Stream, Loop Current, deep-western boundary current, surface gravity-wave climatology, offshore engineering implications, implications for resource commercialization, and numerical models of pollutant dispersion.
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NASA Astrophysics Data System (ADS)
2002-09-01
The Federal Government plans to offer U.S. Outer Continental Shelf (OCS) lands in the Eastern Planning Area of the Gulf of Mexico (GOM) for oil and gas leasing. This report summarizes results of that analysis, the objective of which was to estimate the risk of oil-spill contact to sensitive offshore and onshore environmental resources and socioeconomic features from oil spills accidentally occurring from the OCS activities.
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Constraints on the magnitude and rate of carbon dioxide dissolution at Bravo Dome natural gas field
NASA Astrophysics Data System (ADS)
Sathaye, K.; Hesse, M. A.
2013-12-01
The Bravo Dome field in northeastern New Mexico contains at least 10 trillion cubic feet (tcf) of magmatic CO2. The CO2 has been emplaced in the reservoir for at least 10,000 years, providing a useful analog for geologic CO2 storage. The reservoir is comprised of a CO2 gas layer overlying brine water in a sandstone reservoir. Previous estimates have used differences in the CO2/3He ratio in the gas to infer that locally, half of the CO2 originally emplaced has dissolved into the underlying brine. This study presents the first estimate of the total amount of CO2 dissolved. We incorporate gas pressure, reservoir geometry, and gas layer thickness to show that over 80% of the CO2 originally emplaced is still present in the gas layer. It is generally assumed that the dissolution of CO2 is driven by convective currents in the brine. We present an alternative hypothesis for the spatial differences of the CO2/3He ratio seen in this reservoir. Gas injection theory predicts that as gas displaces a liquid, relatively insoluble gas components will become enriched at the front of the displacement. If the emplacement occurred from west to east this would cause 3He enrichment in the eastern portion of the Bravo Dome field overlying the brine. This effect could be responsible for the spatial differences in the CO2/3He ratio. Mass per area in the gas layer of the reservoir is seen in the 2 right panes. The measured bottom hole pressure data from 1981 is used in combination with CO2/3He measurements to estimate the mass of CO2 originally in place. The water thickness is inversely correlated with the CO2/3He ratio, suggesting that there may be convective dissolution occurring in the eastern part of the reservoir. Present day mass of CO2 is roughly 83% of the original total.
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Anna, Lawrence O.
2011-01-01
Parts of the northern Great Plains in eastern Montana and western North Dakota and southeastern Alberta and southwestern Saskatchewan, Canada, were studied as part of an assessment of shallow biogenic gas in Upper Cretaceous rocks.Parts of the northern Great Plains in eastern Montana and western North Dakota and southeastern Alberta and southwestern Saskatchewan, Canada, were studied as part of an assessment of shallow biogenic gas in Upper Cretaceous rocks. Large quantities of shallow biogenic gas are produced from low-permeability, Upper Cretaceous reservoirs in southeastern Alberta and southwestern Saskatchewan, Canada. Rocks of similar types and age produce sparingly in the United States except on large structures, such as Bowdoin dome and Cedar Creek anticline. Significant production also occurs in the Tiger Ridge area, where uplift of the Bearpaw Mountains created stratigraphic traps. The resource in Canada is thought to be a continuous, biogenic-gas-type accumulation with economic production in a variety of subtle structures and stratigraphic settings. The United States northern Great Plains area has similar conditions but only broad structural closures or stratigraphic traps associated with local structure have produced economically to date. Numerical flow modeling was used to help determine that biogenic gas in low-permeability reservoirs is held in place by high hydraulic head that overrides buoyancy forces of the gas. Modeling also showed where hydraulic head is greater under Tertiary capped topographic remnants rather than near adjacent topographic lows. The high head can override the capillary pressure of the rock and force gas to migrate to low head in topographically low areas. Most current biogenic gas production is confined to areas between mapped lineaments in the northern Great Plains. The lineaments may reflect structural zones in the Upper Cretaceous that help compartmentalize reservoirs and confine gas accumulations.
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Cocker, Mark D.; Orris, Greta J.; Dunlap, Pamela; Lipin, Bruce R.; Ludington, Steve; Ryan, Robert J.; Słowakiewicz, Mirosław; Spanski, Gregory T.; Wynn, Jeff; Yang, Chao
2017-08-03
Undiscovered potash resources in the Pripyat Basin, Belarus, and Dnieper-Donets Basin, Ukraine, were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey (USGS). The Pripyat Basin (in Belarus) and the Dnieper-Donets Basin (in Ukraine and southern Belarus) host stratabound and halokinetic Upper Devonian (Frasnian and Famennian) and Permian (Cisuralian) potash-bearing salt. The evaporite basins formed in the Donbass-Pripyat Rift, a Neoproterozoic continental rift structure that was reactivated during the Late Devonian and was flooded by seawater. Though the rift was divided, in part by volcanic deposits, into the separate Pripyat and Dnieper-Donets Basins, both basins contain similar potash‑bearing evaporite sequences. An Early Permian (Cisuralian) sag basin formed over the rift structure and was also inundated by seawater resulting in another sequence of evaporite deposition. Halokinetic activity initiated by basement faulting during the Devonian continued at least into the Permian and influenced potash salt deposition and structural evolution of potash-bearing salt in both basins.Within these basins, four areas (permissive tracts) that permit the presence of undiscovered potash deposits were defined by using geological criteria. Three tracts are permissive for stratabound potash-bearing deposits and include Famennian (Upper Devonian) salt in the Pripyat Basin, and Famennian and Cisuralian (lower Permian) salt in the Dnieper-Donets Basin. In addition, a tract was delineated for halokinetic potash-bearing Famennian salt in the Dnieper-Donets Basin.The Pripyat Basin is the third largest source of potash in the world, producing 6.4 million metric tons of potassium chloride (KCl) (the equivalent of about 4.0 million metric tons of potassium oxide or K2O) in 2012. Potash production began in 1963 in the Starobin #1 mine, near the town of Starobin, Belarus, in the northwestern corner of the basin. Potash is currently produced from six potash mines in the Starobin area. Published reserves in the Pripyat Basin area are about 7.3 billion metric tons of potash ore (about 1.3 billion metric tons of K2O) mostly from potash-bearing salt horizons in the Starobin and Petrikov mine areas. The 15,160-square-kilometer area of the Pripyat Basin underlain by Famennian potash-bearing salt contains as many as 60 known potash-bearing salt horizons. Rough estimates of the total mineral endowment associated with stratabound Famennian salt horizons in the Pripyat Basin range from 80 to 200 billion metric tons of potash-bearing salt that could contain 15 to 30 billion metric tons of K2O.Parameters (including the number of economic potash horizons, grades, and depths) for these estimates are not published so the estimates are not easily confirmed. Historically, reserves have been estimated above a depth of 1,200 meters (m) (approximately the depths of conventional underground mining). Additional undiscovered K2O resources could be significantly greater in the remainder of the Fammenian salt depending on the extents and grades of the 60 identified potash horizons above the USGS assessment depth of 3,000 m in the remainder of the tract. Increasing ambient temperatures with increasing depths in the eastern parts of the Pripyat Basin may require a solution mining process which is aided by higher temperatures.No resource or reserve data have been published and little is known about stratabound Famennian and Frasnian salt in the Dnieper-Donets Basin. These Upper Devonian salt units dip to the southeast and extend to depths of 15–19 kilometers (km) or greater. The tract of stratabound Famennian salt that lies above a depth of 3 km, the depth above which potash is technically recoverable by solution mining, underlies an area of about 15,600 square kilometers (km2). If Upper Devonian salt units in the Dnieper-Donets Basin contain potash-bearing strata similar to salt of the same age in the Pripyat Basin, then the stratabound Famennian tract in the Dnieper-Donets Basin could contain significant undiscovered potash resources.The Cisuralian evaporite sequence in the Dnieper-Donets Basin consists of 10 evaporite cycles with the upper 3 cycles containing potash-bearing salt (mainly as sylvite and carnallite) in several subbasins and polyhalite in the sulfate bearing parts of the identified tract. The area of the Cisuralian tract is 62,700 km2. Potash-bearing cycles are as much as 40 m thick. One subbasin is reported to contain 794 million metric tons of “raw or crude” potash-bearing salt which could contain 50 to 150 million metric tons of K2O, depending on the grade. Undiscovered potash resources in the remainder of this permissive tract may be significantly greater. Depths to the Permian salt range from less than 100 to about 1,500 m.Undiscovered resources of halokinetic potash-bearing salt in the Dnieper-Donets Basin were assessed quantitatively for this study by using the standard USGS three-part form of mineral resource assessment (Singer, 2007a; Singer and Menzie, 2010). Delineation of the permissive tract was based on distributions of mapped halokinetic salt structures. This tract contains at least 248 diapiric salt structures with a total area of 7,840 km2 that occupies approximately 8 percent of the basin area. The vertical extent of these salt structures is hundreds of meters to several kilometers. This assessment estimated that a total mean of 11 undiscovered deposits contain an arithmetic mean estimate of about 840 million metric tons of K2O in the halokinetic salt structures of the Dnieper-Donets Basin for which the probabilistic estimate was made.
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NASA Astrophysics Data System (ADS)
Haskins, M. N.; Vollmer, F. W.; Rayburn, J. A.; Gurdak, J. J.
2010-12-01
To investigate joint control on hydrology as well as tectonic implications, we conducted a study of joint orientations near the Stony Clove and Warner Creek drainages of the Catskill Mountains, Eastern New York. Specific goals of this research were to determine joint control on stream orientations and groundwater flow, to compare results with previous studies in the area, and to investigate their tectonic significance. Trails, streams, and road cuts were traversed to locate bedrock outcrops whose positions were determined using topographic maps and a handheld GPS unit. Additional outcrops were located using aerial photographs and GIS data. Joint orientations were measured using a standard Brunton pocket transit. The data was analyzed using Orient (Vollmer, 2010), an orientation analysis program, to plot joint and stream orientations on rose diagrams. ArcGIS was used to produce topographic, hill-shade, and stream drainage maps. Over 500 joint orientations at over 100 outcrop stations were collected. The data were plotted on a rose diagrams, and two major joint sets were found, one with a mean strike of 021° and one with a mean strike of 096°. Stream orientations were also plotted on a rose diagram showing an axial mean of 022°, and indicate that the joint set with mean strike of 021 may have a significant control on stream orientations. The hill-shade maps also demonstrate clearly the strong control of jointing on the topography. The data collected in this research expands on previous joint orientation studies of Engelder and Geiser (1980) in the southwestern and central Catskills, and is similar to joint orientations found by Isachsen et al. (1977) in their study of the Panther Mountain circular structure, a possible impact-related feature. The origin of this jointing is thought to be related to Alleghanian (Permian) and possibly Acadian (Devonian) orogenic events.
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Variscan tectonics in Dodecanese, Kalymnos island, Greece
NASA Astrophysics Data System (ADS)
Chatziioannou, Eleftheria; Grasemann, Bernhard; Schneider, David; Hubmann, Bernhard; Soukis, Konstantinos
2015-04-01
Kalymnos island is located in the Dodecanese, southeastern Aegean Sea, and geologically appears to be part of the external Hellenides. Pre-Alpidic basement rocks on the Dodecanese islands have been suggested to record compelling similarities with the basement rocks in Eastern Crete with respect to their lithologies and pre-Alpidic metamorphic evolution. The lithotectonic units experienced greenschist to amphibolite facies conditions during the Variscan orogeny. Whereas the rocks in Eastern Crete reveal Alpine high-pressure overprint, the Variscan basement units in the Dodecanese record no or low-grade Alpine metamorphism. A field study of basement rocks below Mesozoic limestones and dolomites in the NW part of Kalymnos near Emporios uncovered a complex history of metamorphism, folding and faulting. Three different tectonic units can be discriminated from top to bottom: a) a quartz-mica schist, b) a white-grey, fossiliferous coarse grained marble and c) a fine-grained fossiliferous blue-grey marble. In the marbles macrofossils such as brachiopods, ammonoid cephalopods (Goniatids?) and crinoids suggest a Middle-Upper Devonian deposition age (Givetian- Frasnian). Structural mapping the area resolved a dominant W-E shortening event, resulting in an overall inverted metamorphic gradient. The lowermost blue-grey marble unit is folded into large-scale upright folds, which are truncated by top-to-east overthrusting of the white-grey marble unit. Whereas deformation mechanisms in the blue-grey marble unit are dominated by dissolution-precipitation creep, the white-grey marble suffered intense crystal plastic deformation with localized high-strain mylonitic shear zones. The uppermost quartz-mica schist unit is separated from the lower units by a cataclastic phyllonitic shear zone. 40Ar/39Ar geochronological dating on white micas from the quartz-mica schists yielded cooling ages between 240 and 334 Ma indicative of Variscan cooling. Our data suggest that this part of the Dodecanese experienced intense Variscan deformation with no high-temperature Alpine overprint.
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Lenticular stretch structures in eastern Nevada - possible trapping mechanism in supposed graben
DOE Office of Scientific and Technical Information (OSTI.GOV)
Walker, C.T.; Dennis, J.G.; Lumsden, W.W.
Eastern Nevada is widely recognized as a region of tectonic extension. The dominant structures are generally agreed to be low-dipping, younger over older faults and steeper listric faults that are responsible for the basins (grabens) and ranges (horsts). In the Schell Creek-Duck Creek Range, east of Ely, and in the White Pine Range, southwest of Ely, small lenticular structures bounded by tectonic discontinuities can be clearly seen in the field. These lenticular units, or stretch structures, range in length from a few meters to more than 200 m. All lenticular stretch structures that can be clearly seen in the fieldmore » are stratigraphically restricted; the stretched formations are the Eureka Quartzite, the Pilot Shale, the Joana Limestone, and the Chainman Shale. Still larger stretch structures, which may include several formations, are inferred, and the authors suggest that extension has created lenticular structures at all scales. The Duck Creek and Schell Creek Ranges east of Ely consist mostly of Devonian and older rocks. They are separated by a topographically lower area containing mostly Mississippian and Pennsylvanian rocks. This structure, which separates the ranges, has been referred to as a graben, but field evidence suggests that it is a large-scale lenticular stretch structure. Unlike a true graben, the structure does not extend downward. For example, in several places within the supposed graben, Cambrian and Ordovician rocks project through a cover of Carboniferous Chainman Shale and Ely Limestone, suggesting the Chainman-Ely is a thin sheet underlain by Cambrian-Ordovician rocks. Accordingly, they suggest that extension in the Duck Creek-Schell Creek Ranges stretched the formations into lenticular bodies. Between the Duck Creek and Schell Creek Ranges, the Cambrian-Ordovician is attenuated, and the resulting tectonic depression is occupied by a lenticular mass of Carboniferous rocks.« less
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Geologic map of the Nelson quadrangle, Lewis and Clark County, Montana
Reynolds, Mitchell W.; Hays, William H.
2003-01-01
The geologic map of the Nelson quadrangle, scale 1:24,000, was prepared as part of the Montana Investigations Project to provide new information on the stratigraphy, structure, and geologic history of an area in the geologically complex southern part of the Montana disturbed belt. In the Nelson area, rocks ranging in age from Middle Proterozoic through Cretaceous are exposed on three major thrust plates in which rocks have been telescoped eastward. Rocks within the thrust plates are folded and broken by thrust faults of smaller displacement than the major bounding thrust faults. Middle and Late Tertiary sedimentary and volcaniclastic rocks unconformably overlie the pre-Tertiary rocks. A major normal fault displaces rocks of the western half of the quadrangle down on the west with respect to strata of the eastern part. Alluvial and terrace gravels and local landslide deposits are present in valley bottoms and on canyon walls in the deeply dissected terrain. Different stratigraphic successions are exposed at different structural levels across the quadrangle. In the northeastern part, strata of the Middle Cambrian Flathead Sandstone, Wolsey Shale, and Meagher Limestone, the Middle and Upper Cambrian Pilgrim Formation and Park Shale undivided, the Devonian Maywood, Jefferson, and lower part of the Three Forks Formation, and Lower and Upper Mississippian rocks assigned to the upper part of the Three Forks Formation and the overlying Lodgepole and Mission Canyon Limestones are complexly folded and faulted. These deformed strata are overlain structurally in the east-central part of the quadrangle by a succession of strata including the Middle Proterozoic Greyson Formation and the Paleozoic succession from the Flathead Sandstone upward through the Lodgepole Limestone. In the east-central area, the Flathead Sandstone rests unconformably on the middle part of the Greyson Formation. The north edge, northwest quarter, and south half of the quadrangle are underlain by a succession of rocks that includes not only strata equivalent to those of the remainder of the quadrangle, but also the Middle Proterozoic Newland, Greyson, and Spokane Formations, Pennsylvanian and Upper Mississippian Amsden Formation and Big Snowy Group undivided, the Permian and Pennsylvanian Phosphoria and Quadrant Formations undivided, the Jurassic Ellis Group and Lower Cretaceous Kootenai Formation. Hornblende diorite sills and irregular bodies of probable Late Cretaceous age intrude Middle Proterozoic, Cambrian and Devonian strata. No equivalent intrusive rocks are present in structurally underlying successions of strata. In this main part of the quadrangle, the Flathead Sandstone cuts unconformably downward from south to north across the Spokane Formation into the upper middle part of the Greyson Formation. Tertiary (Miocene?) strata including sandstone, pebble and cobble conglomerate, and vitric crystal tuff underlie, but are poorly exposed, in the southeastern part of the quadrangle where they are overlain by late Tertiary and Quaternary gravel. The structural complexity of the quadrangle decreases from northeast to southwest across the quadrangle. At the lowest structural level (Avalanche Butte thrust plate) exposed in the canyon of Beaver Creek, lower and middle Paleozoic rocks are folded in northwest-trending east-inclined disharmonic anticlines and synclines that are overlain by recumbently folded and thrust faulted Devonian and Mississippian rocks. The Mississippian strata are imbricated adjacent to the recumbent folds. In the east-central part of the quadrangle, a structurally overlying thrust plate, likely equivalent to the Hogback Mountain thrust plate of the Hogback Mountain quadrangle adjacent to the east (Reynolds, 20xx), juxtaposes recumbently folded Middle Proterozoic and unconformably overlying lower Paleozoic rocks on the complexly folded and faulted rocks of the Avalanche Butte thrust plate. The highest structural plate, bounded below
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NASA Astrophysics Data System (ADS)
Zhang, Ji'en; Xiao, Wenjiao; Luo, Jun; Chen, Yichao; Windley, Brian F.; Song, Dongfang; Han, Chunming; Safonova, Inna
2018-06-01
Western Junggar in NW China, located to the southeast of the Boshchekul-Chingiz (BC) Range and to the north of the Chu-Balkhash-Yili microcontinent (CBY), played a key role in the architectural development of the western Altaids. However, the mutual tectonic relationships have been poorly constrained. In this paper, we present detailed mapping, field structural geology, and geochemical data from the Barleik-Mayile-Tangbale Complex (BMTC) in Western Junggar. The Complex is divisible into Zones I, II and III, which are mainly composed of Cambrian-Silurian rocks. Zone I contains pillow lava, siliceous shale, chert, coral-bearing limestone, sandstone and purple mudstone. Zone II consists of basaltic lava, siliceous shale, chert, sandstone and mudstone. Zone III is characterized by basalt, chert, sandstone and mudstone. These rocks represent imbricated ocean plate stratigraphy, which have been either tectonically juxtaposed by thrusting or form a mélange with a block-in-matrix structure. All these relationships suggest that the BMTC is an Early-Middle Paleozoic accretionary complex in the eastern extension of the BC Range. These Early Paleozoic oceanic rocks were thrust onto Silurian sediments forming imbricate thrust stacks that are unconformably overlain by Devonian limestone, conglomerate and sandstone containing fossils of brachiopoda, crinoidea, bryozoa, and plant stems and leaves. The tectonic vergence of overturned folds in cherts, drag-related curved cleavages and σ-type structures on the main thrust surface suggests top-to-the-NW transport. Moreover, the positive εNd(t) values of volcanic rocks from the Tacan-1 drill-core, and the positive εHf(t) values and post-Cambrian ages of detrital zircons from Silurian and Devonian strata to the south of the Tacheng block indicate that its basement is a depleted and juvenile lithosphere. And there was a radial outward transition from coral-bearing shallow marine (shelf) to deep ocean (pelagic) environments, and from OIB/E-MORB to N-MORB lava geochemistry away from the Tacheng block. Comparisons with published data suggest that these positive isotopic values, stratigraphic, structural and geochemical relationships can be best understood as an analogue of the relationships between the Ontong Java oceanic plateau and the Pacific oceanic crust. Therefore we propose that the basement of the Tacheng block was an Early Paleozoic oceanic plateau. The southern part of the Tacheng block was an accretionary complex and the northern part was an oceanic basin in the Early Paleozoic, the configuration of which is similar to that of the present Ontong Java oceanic plateau situated on the Pacific oceanic crust, and its accretion into the Solomon accretionary complex. The presence of Ordovician SSZ-type ophiolites, early Paleozoic blueschist and Silurian SSZ-type intrusions in the BMTC, and Early-Middle Paleozoic continental arc-related intrusive rocks in the northern margin of the CBY provide further corroboration of a former subduction zone between the southern West Junggar and the northern margin of the CBY. Furthermore, consideration of the fact that the Kokchetav-North Tianshan range was collaged to the southern margin of the CBY in the Ordovician-Devonian indicates that both ranges were amalgamated synchronously with the CBY constructing the Early-Middle Paleozoic architecture of western Altaids.
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75 FR 76721 - Combined Notice of Filings No. 2
Federal Register 2010, 2011, 2012, 2013, 2014
2010-12-09
....m. Eastern Time on Monday, November 29, 2010. Docket Numbers: RP10-911-001. Applicants: Gas... per 154.203: RP10-911 Compliance to be effective 6/30/2010. Filed Date: 11/23/2010. Accession Number...
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78 FR 13873 - Environmental Impacts Statements; Notice of Availability
Federal Register 2010, 2011, 2012, 2013, 2014
2013-03-01
..., CA, Middle Fork American River Project, Review Period Ends: 04/01/2013, Contact: Matt Buhyoff 202-502.... 20130048, Draft EIS, BOEM, 00, Gulf of Mexico OCS Oil and Gas Lease Sales: 2014 and 2016 Eastern Planning...
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Gold Veins near Great Falls, Maryland
Reed, John Calvin; Reed, John C.
1969-01-01
Small deposits of native gold are present along an anastomosing system of quartz veins and shear zones just east of Great Falls, Montgomery County, Md. The deposits were discovered in 1861 and were worked sporadically until 1951, yielding more than 5,000 ounces of gold. The vein system and the principal veins within it strike a few degrees west of north, at an appreciable angle to foliation and fold axial planes in enclosing rocks of the Wissahickon Formation of late Precambrian (?) age. The veins cut granitic rocks of Devonian or pre-Devonian age and may be as young as Triassic. Further development of the deposits is unlikely under present economic conditions because of their generally low gold content and because much of the vein system lies on park property, but study of the Great Falls vein system may be useful in the search for similar deposits elsewhere in the Appalachian Piedmont.
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Indirect and direct tensile behavior of Devonian oil shales
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chong, K.P.; Chen, J.L.; Dana, G.F.
1984-03-01
Ultimate indirect tensile strengths of Devonian oil shales across the bedding planes is a mechanical property parameter important to predicting how oil shale will break. This is particularly important to in-situ fragmentation. The Split Cylinder Test was used to determine the indirect tensile strengths between the bedding planes. Test specimens, cored perpendicular to the bedding planes, representing oil shales of different oil yields taken from Silver Point Quad in DeKalb County, Tennessee and Friendship in Scioto County, Ohio, were subjected to the Split Cylinder Test. Linear regression equations relating ultimate tensile strength across the bedding planes to volume percent ofmore » organic matter in the rock were developed from the test data. In addition, direct tensile strengths were obtained between the bedding planes for the Tennessee oil shales. This property is important for the design of horizontal fractures in oil shales. Typical results were presented.« less
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Krings, Michael; Taylor, Thomas N; Martin, Helmut
2016-01-01
Litter layers in the Lower Devonian (~ 410 Ma) Rhynie chert were inhabited by a wide variety of saprotrophic fungi, however, only a few of these organisms have been described formally. A new microfungus, Trewinomyces annulifer gen. et sp. nov., occurs as tufts on decaying land plant axes from the Rhynie chert. The fungus consists of an intramatrical rhizoidal system and an erect extramatrical hypha (stalk) that bears a single, terminal sporangium. One or two successive rings often are present in the stalk immediately below the sporangium base. Overall morphology of T. annulifer resembles the extant genera Macrochytrium (Chytridiomycota) and Blastocladiella (Blastocladiomycota). However, the rhizoids are septate or pseudoseptate, a feature not known in extant zoosporic fungi, and thus render the systematic affinities of T. annulifer unresolved. Trewinomyces annulifer offers a rare view of the morphology of a distinctive Early Devonian saprotrophic microfungus. © 2016 by The Mycological Society of America.
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Unusual anal fin in a Devonian jawless vertebrate reveals complex origins of paired appendages
Sansom, Robert S.; Gabbott, Sarah E.; Purnell, M. A.
2013-01-01
Jawed vertebrates (gnathostomes) have undergone radical anatomical and developmental changes in comparison with their jawless cousins (cyclostomes). Key among these is paired appendages (fins, legs and wings), which first evolved at some point on the gnathostome stem. The anatomy of fossil stem gnathostomes is, therefore, fundamental to our understanding of the nature and timing of the origin of this complex innovation. Here, we show that Euphanerops, a fossil jawless fish from the Devonian, possessed paired anal-fin radials, but no pectoral or pelvic fins. This unique condition occurs at an early stage on the stem-gnathostome lineage. This condition, and comparison with the varied condition of paired fins in other ostracoderms, indicates that there was a large amount of developmental plasticity during this episode—rather than a gradual evolution of this complex feature. Apparently, a number of different clades were exploring morphospace or undergoing multiple losses. PMID:23576777
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The largest Silurian vertebrate and its palaeoecological implications
Choo, Brian; Zhu, Min; Zhao, Wenjin; Jia, Liaotao; Zhu, You'an
2014-01-01
An apparent absence of Silurian fishes more than half-a-metre in length has been viewed as evidence that gnathostomes were restricted in size and diversity prior to the Devonian. Here we describe the largest pre-Devonian vertebrate (Megamastax amblyodus gen. et sp. nov.), a predatory marine osteichthyan from the Silurian Kuanti Formation (late Ludlow, ~423 million years ago) of Yunnan, China, with an estimated length of about 1 meter. The unusual dentition of the new form suggests a durophagous diet which, combined with its large size, indicates a considerable degree of trophic specialisation among early osteichthyans. The lack of large Silurian vertebrates has recently been used as constraint in palaeoatmospheric modelling, with purported lower oxygen levels imposing a physiological size limit. Regardless of the exact causal relationship between oxygen availability and evolutionary success, this finding refutes the assumption that pre-Emsian vertebrates were restricted to small body sizes. PMID:24921626
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NASA Astrophysics Data System (ADS)
Antczak, Mateusz; Berkowski, Błażej
2017-06-01
Dermal bones are formed early during growth and thus constitute an important tool in studies of ontogenetic and evolutionary changes amongst early vertebrates. Ornamentation of dermal bones of terrestrial vertebrates is often used as a taxonomic tool, for instance in Aetosauria, extant lungfishes (Dipnoi) and ray-finned fishes (Actinopterygii), for which it have been proved to be of use in differentiating specimens to species level. However, it has not been utilised to the same extent in placoderms. Several features of the ornamentation of Early Devonian placoderms from Hamar Laghdad (Morocco) were examined using both optical and scanning electron microscopy to determine whether it is possible to distinguish armoured Palaeozoic fishes. Four distinct morphotypes, based on ornamentation of dermal bones, are differentiated. These distinct types of ornamentation may be the result of either different location of dermal plates on the body or of ontogenetic (intraspecific) and/or interspecific variation.
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Ma, Shuangmei; Zhou, Tianjun; Stone, Dáithí A.; ...
2017-05-19
In the midsummer of 2013, Central and Eastern China (CEC) was hit by an extraordinary heat event, with the region experiencing the warmest July-August on record. To explore how human-induced greenhouse gas emissions and natural internal variability contributed to this heat event, we compare observed July-August mean surface air temperature wit h that simulated by climate models. We find that both atmospheric natural variability and anthropogenic factors contributed to this heat event. This extreme warm midsummer was associated with a positive high-pressure anomaly that was closely related to the stochastic behavior of atmospheric circulation. Diagnosis of CMIP5 models and largemore » ensembles of two atmospheric models indicates that human influence has substantially increased the chance of warm mid-summers such as 2013 in CEC, although the exact estimated increase depends on the selection of climate models.« less
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NASA Astrophysics Data System (ADS)
Piskunov, Maksim V.; Voytkov, Ivan S.; Vysokomornaya, Olga V.; Vysokomorny, Vladimir S.
2015-01-01
The new approach was developed to analyze the failure causes in operation of linear facilities independent power supply sources (mini-CHP-plants) of gas-transmission system in Eastern part of Russia. Triggering conditions of ceiling operation substance temperature at condenser output were determined with mathematical simulation use of unsteady heat and mass transfer processes in condenser of mini-CHP-plants. Under these conditions the failure probability in operation of independent power supply sources is increased. Influence of environmental factors (in particular, ambient temperature) as well as output electric capability values of power plant on mini-CHP-plant operation reliability was analyzed. Values of mean time to failure and power plant failure density during operation in different regions of Eastern Siberia and Far East of Russia were received with use of numerical simulation results of heat and mass transfer processes at operation substance condensation.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Ma, Shuangmei; Zhou, Tianjun; Stone, Dáithí A.
In the midsummer of 2013, Central and Eastern China (CEC) was hit by an extraordinary heat event, with the region experiencing the warmest July-August on record. To explore how human-induced greenhouse gas emissions and natural internal variability contributed to this heat event, we compare observed July-August mean surface air temperature wit h that simulated by climate models. We find that both atmospheric natural variability and anthropogenic factors contributed to this heat event. This extreme warm midsummer was associated with a positive high-pressure anomaly that was closely related to the stochastic behavior of atmospheric circulation. Diagnosis of CMIP5 models and largemore » ensembles of two atmospheric models indicates that human influence has substantially increased the chance of warm mid-summers such as 2013 in CEC, although the exact estimated increase depends on the selection of climate models.« less
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Maps showing gas-hydrate distribution off the east coast of the United States
Dillon, William P.; Fehlhaber, Kristen L.; Coleman, Dwight F.; Lee, Myung W.; Hutchinson, Deborah R.
1995-01-01
These maps present the inferred distribution of natural-gas hydrate within the sediments of the eastern United States continental margin (Exclusive Economic Zone) in the offshore region from Georgia to New Jersey (fig. 1). The maps, which were created on the basis of seismic interpretations, represent the first attempt to map volume estimates for gas hydrate. Gas hydrate forms a large reservoir for methane in oceanic sediments. Therefore it potentially may represent a future source of energy and it may influence climate change because methane is a very effective greenhouse gas. Hydrate breakdown probably is a controlling factor for sea-floor landslides, and its presence has significant effect on the acoustic velocity of sea-floor sediments.
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The diversification of Paleozoic fire systems and fluctuations in atmospheric oxygen concentration
Scott, Andrew C.; Glasspool, Ian J.
2006-01-01
By comparing Silurian through end Permian [≈250 million years (Myr)] charcoal abundance with contemporaneous macroecological changes in vegetation and climate we aim to demonstrate that long-term variations in fire occurrence and fire system diversification are related to fluctuations in Late Paleozoic atmospheric oxygen concentration. Charcoal, a proxy for fire, occurs in the fossil record from the Late Silurian (≈420 Myr) to the present. Its presence at any interval in the fossil record is already taken to constrain atmospheric oxygen within the range of 13% to 35% (the “fire window”). Herein, we observe that, as predicted, atmospheric oxygen levels rise from ≈13% in the Late Devonian to ≈30% in the Late Permian so, too, fires progressively occur in an increasing diversity of ecosystems. Sequentially, data of note include: the occurrence of charcoal in the Late Silurian/Early Devonian, indicating the burning of a diminutive, dominantly rhyniophytoid vegetation; an apparent paucity of charcoal in the Middle to Late Devonian that coincides with a predicted atmospheric oxygen low; and the subsequent diversification of fire systems throughout the remainder of the Late Paleozoic. First, fires become widespread during the Early Mississippian, they then become commonplace in mire systems in the Middle Mississippian; in the Pennsylvanian they are first recorded in upland settings and finally, based on coal petrology, become extremely important in many Permian mire settings. These trends conform well to changes in atmospheric oxygen concentration, as predicted by modeling, and indicate oxygen levels are a significant control on long-term fire occurrence. PMID:16832054
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Unique growth strategy in the Earth's first trees revealed in silicified fossil trunks from China.
Xu, Hong-He; Berry, Christopher M; Stein, William E; Wang, Yi; Tang, Peng; Fu, Qiang
2017-11-07
Cladoxylopsida included the earliest large trees that formed critical components of globally transformative pioneering forest ecosystems in the Mid- and early Late Devonian (ca. 393-372 Ma). Well-known cladoxylopsid fossils include the up to ∼1-m-diameter sandstone casts known as Eospermatopteris from Middle Devonian strata of New York State. Cladoxylopsid trunk structure comprised a more-or-less distinct cylinder of numerous separate cauline xylem strands connected internally with a network of medullary xylem strands and, near the base, externally with downward-growing roots, all embedded within parenchyma. However, the means by which this complex vascular system was able to grow to a large diameter is unknown. We demonstrate-based on exceptional, up to ∼70-cm-diameter silicified fossil trunks with extensive preservation of cellular anatomy from the early Late Devonian (Frasnian, ca. 374 Ma) of Xinjiang, China-that trunk expansion is associated with a cylindrical zone of diffuse secondary growth within ground and cortical parenchyma and with production of a large amount of wood containing both rays and growth increments concentrically around individual xylem strands by normal cambia. The xylem system accommodates expansion by tearing of individual strand interconnections during secondary development. This mode of growth seems indeterminate, capable of producing trees of large size and, despite some unique features, invites comparison with secondary development in some living monocots. Understanding the structure and growth of cladoxylopsids informs analysis of canopy competition within early forests with the potential to drive global processes. Published under the PNAS license.
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Dumoulin, Julie A.; Harris, Anita G.; Gagiev, Mussa; Bradley, Dwight C.; Repetski, John E.
2002-01-01
Lower Paleozoic platform carbonate strata in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes; herein called the North Alaska carbonate platform) and central Alaska (Farewell terrane) share distinctive lithologic and faunal features, and may have formed on a single continental fragment situated between Siberia and Laurentia. Sedimentary successions in northern and central Alaska overlie Late Proterozoic metamorphosed basement; contain Late Proterozoic ooid-rich dolostones, Middle Cambrian outer shelf deposits, and Ordovician, Silurian, and Devonian shallow-water platform facies, and include fossils of both Siberian and Laurentian biotic provinces. The presence in the Alaskan terranes of Siberian forms not seen in wellstudied cratonal margin sequences of western Laurentia implies that the Alaskan rocks were not attached to Laurentia during the early Paleozoic.The Siberian cratonal succession includes Archean basement, Ordovician shallow-water siliciclastic rocks, and Upper Silurian–Devonian evaporites, none of which have counterparts in the Alaskan successions, and contains only a few of the Laurentian conodonts that occur in Alaska. Thus we conclude that the lower Paleozoic platform successions of northern and central Alaska were not part of the Siberian craton during their deposition, but may have formed on a crustal fragment rifted away from Siberia during the Late Proterozoic. The Alaskan strata have more similarities to coeval rocks in some peri-Siberian terranes of northeastern Russia (Kotelny, Chukotka, and Omulevka). Lithologic ties between northern Alaska, the Farewell terrane, and the peri-Siberian terranes diminish after the Middle Devonian, but Siberian afµnities in northern and central Alaskan biotas persist into the late Paleozoic.
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Gueidan, Cécile; Ruibal, Constantino; de Hoog, G S; Schneider, Harald
2011-10-01
Non-lichenized rock-inhabiting fungi (RIF) are slow-growing melanized ascomycetes colonizing rock surfaces in arid environments. They possess adaptations, which allow them to tolerate extreme abiotic conditions, such as high UV radiations and extreme temperatures. They belong to two separate lineages, one consisting in the sister classes Dothideomycetes and Arthoniomycetes (Dothideomyceta), and the other consisting in the order Chaetothyriales (Eurotiomycetes). Because RIF often form early diverging groups in Chaetothyriales and Dothideomyceta, the ancestors of these two lineages were suggested to most likely be rock-inhabitants. The lineage of RIF related to the Chaetothyriales shows a much narrower phylogenetic spectrum than the lineage of RIF related to Dothideomyceta, suggesting a much more ancient origin for the latter. Our study aims at investigating the times of origin of RIF using a relaxed clock model and several fossil and secondary calibrations. Our results show that the RIF in Dothideomyceta evolved in the late Devonian, much earlier than the RIF in Chaetothyriales, which originated in the middle Triassic. The origin of the chaetothyrialean RIF correlates well with a period of recovery after the Permian-Triassic mass extinction and an expansion of arid landmasses. The period preceding the diversification of the RIF related to Dothideomyceta (Silurian--Devonian) is also characterized by large arid landmasses, but temperatures were much cooler than during the Triassic. The paleoclimate record provides a good explanation for the diversification of fungi subjected to abiotic stresses and adapted to life on rock surfaces in nutrient-poor habitats. Copyright © 2011 British Mycological Society. Published by Elsevier Ltd. All rights reserved.
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Edgecliff reefs - Devonian temperate water carbonate deposition
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wolosz, T.H.
1991-03-01
The Middle Devonian Edgecliff Member of the Onondaga Formation in New York and Ontario, Canada, is a coral-rich, reefy,' crinoidal grainstone/packstone. The reefs contain only rare stromatoporoids and are devoid of algae, having been constructed by a fauna of mound and thicket-forming branching colonial rugosans, and large sheet favositids that populated grainstone/packstone flank beds and banks. Despite the restricted fauna, the reefs display a variety of growth patterns. Rugosan mounds range in size from 2-3 m diameter by 1 m thick, up to 230 m diameter by 15 m thick. Composite structures consist of interbedded rugosan buildups and packstone/grainstone flanks,more » ranging from shield-shaped reefs (240 m diameter by 6 m thick) in which the rugosans occur only as thickets, to pinnacle reefs (up to 3 km diameter by 60 m thick) in which rugosan mounds are interbedded with crinoidal flanks. Geographic distribution of these reef types and analysis of surrounding facies suggests that reef growth pattern was controlled by water depth and local rate of subsidence. Despite superfacial resemblance to modern deep water ahermatypic coral mounds and thickets, abundant coral breakage and overturning, and erosion of at least one reef core during an intermediate stage of reef growth supports a shallow water origin of these reefs. It is suggested that the Edgecliff and its reefs represent an example of Devonian cool water carbonate deposition, a hypothesis supported by a trend of increasing stromatoporoid abundance westwards across New York (in the direction of the paleo-equator).« less
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Cramer, Bradley D.; Saltzman, Matthew R.; Day, J.E.; Witzke, B.J.
2008-01-01
Latest Famennian marine carbonates from the mid-continent of North America were examined to investigate the Late Devonian (very late Famennian) Hangenberg positive carbon-isotope (??13 Ccarb) excursion. This global shift in the ?? 13C of marine waters began during the late Famennian Hangenberg Extinction Event that occurred during the Middle Siphonodella praesulcata conodont zone. The post-extinction recovery interval spans the Upper S. praesulcata Zone immediately below the Devonian-Carboniferous boundary. Positive excursions in ?? 13 Ccarb are often attributed to the widespread deposition of organic-rich black shales in epeiric sea settings. The Hangenberg ??13 Ccarb excursion documented in the Louisiana Limestone in this study shows the opposite trend, with peak ??13 Ccarb values corresponding to carbonate production in the U.S. mid-continent during the highstand phase of the very late Famennian post-glacial sea level rise. Our data indicate that the interval of widespread black shale deposition (Hangenberg Black Shale) predates the peak isotope values of the Hangenberg ??13 Ccarb excursion and that peak values of the Hangenberg excursion in Missouri are not coincident with and cannot be accounted for by high Corg burial in epeiric seas. We suggest instead that sequestration and burial of Corg in the deep oceans drove the peak interval of the ??13Ccarb excursion, as a result of a change in the site of deep water formation to low-latitude epeiric seas as the global climate shifted between cold and warm states.
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Economic decision making and the application of nonparametric prediction models
Attanasi, E.D.; Coburn, T.C.; Freeman, P.A.
2007-01-01
Sustained increases in energy prices have focused attention on gas resources in low permeability shale or in coals that were previously considered economically marginal. Daily well deliverability is often relatively small, although the estimates of the total volumes of recoverable resources in these settings are large. Planning and development decisions for extraction of such resources must be area-wide because profitable extraction requires optimization of scale economies to minimize costs and reduce risk. For an individual firm the decision to enter such plays depends on reconnaissance level estimates of regional recoverable resources and on cost estimates to develop untested areas. This paper shows how simple nonparametric local regression models, used to predict technically recoverable resources at untested sites, can be combined with economic models to compute regional scale cost functions. The context of the worked example is the Devonian Antrim shale gas play, Michigan Basin. One finding relates to selection of the resource prediction model to be used with economic models. Models which can best predict aggregate volume over larger areas (many hundreds of sites) may lose granularity in the distribution of predicted volumes at individual sites. This loss of detail affects the representation of economic cost functions and may affect economic decisions. Second, because some analysts consider unconventional resources to be ubiquitous, the selection and order of specific drilling sites may, in practice, be determined by extraneous factors. The paper also shows that when these simple prediction models are used to strategically order drilling prospects, the gain in gas volume over volumes associated with simple random site selection amounts to 15 to 20 percent. It also discusses why the observed benefit of updating predictions from results of new drilling, as opposed to following static predictions, is somewhat smaller. Copyright 2007, Society of Petroleum Engineers.