Science.gov

Sample records for efficient extreme ultra-violet

  1. Counter-facing plasma guns for efficient extreme ultra-violet plasma light source

    NASA Astrophysics Data System (ADS)

    Kuroda, Yusuke; Yamamoto, Akiko; Kuwabara, Hajime; Nakajima, Mitsuo; Kawamura, Tohru; Horioka, Kazuhiko

    2013-11-01

    A plasma focus system composed of a pair of counter-facing coaxial guns was proposed as a long-pulse and/or repetitive high energy density plasma source. We applied Li as the source of plasma for improvement of the conversion efficiency, the spectral purity, and the repetition capability. For operation of the system with ideal counter-facing plasma focus mode, we changed the system from simple coaxial geometry to a multi-channel configuration. We applied a laser trigger to make synchronous multi-channel discharges with low jitter. The results indicated that the configuration is promising to make a high energy density plasma with high spectral efficiency.

  2. Complementary ion and extreme ultra-violet spectrometer for laser-plasma diagnosis

    SciTech Connect

    Ter-Avetisyan, S.; Ramakrishna, B.; Doria, D.; Sarri, G.; Zepf, M.; Borghesi, M.; Ehrentraut, L.; Stiel, H.; Steinke, S.; Schnuerer, M.; Nickles, P. V.; Sandner, W.; Priebe, G.

    2009-10-15

    Simultaneous detection of extreme ultra-violet (XUV) and ion emission along the same line of sight provides comprehensive insight into the evolution of plasmas. This type of combined spectroscopy is applied to diagnose laser interaction with a spray target. The use of a micro-channel-plate detector assures reliable detection of both XUV and ion signals in a single laser shot. The qualitative analysis of the ion emission and XUV spectra allows to gain detailed information about the plasma conditions, and a correlation between the energetic proton emission and the XUV plasma emission can be suggested. The measured XUV emission spectrum from water spray shows efficient deceleration of laser accelerated electrons with energies up to keV in the initially cold background plasma and the collisional heating of the plasma.

  3. Extreme ultra-violet movie camera for imaging microsecond time scale magnetic reconnection

    SciTech Connect

    Chai, Kil-Byoung; Bellan, Paul M.

    2013-12-15

    An ultra-fast extreme ultra-violet (EUV) movie camera has been developed for imaging magnetic reconnection in the Caltech spheromak/astrophysical jet experiment. The camera consists of a broadband Mo:Si multilayer mirror, a fast decaying YAG:Ce scintillator, a visible light block, and a high-speed visible light CCD camera. The camera can capture EUV images as fast as 3.3 × 10{sup 6} frames per second with 0.5 cm spatial resolution. The spectral range is from 20 eV to 60 eV. EUV images reveal strong, transient, highly localized bursts of EUV radiation when magnetic reconnection occurs.

  4. Exploring the temporally resolved electron density evolution in extreme ultra-violet induced plasmas

    NASA Astrophysics Data System (ADS)

    van der Horst, R. M.; Beckers, J.; Nijdam, S.; Kroesen, G. M. W.

    2014-07-01

    We measured the electron density in an extreme ultra-violet (EUV) induced plasma. This is achieved in a low-pressure argon plasma by using a method called microwave cavity resonance spectroscopy. The measured electron density just after the EUV pulse is 2.6 × 1016 m-3. This is in good agreement with a theoretical prediction from photo-ionization, which yields a density of 4.5 × 1016 m-3. After the EUV pulse the density slightly increases due to electron impact ionization. The plasma (i.e. electron density) decays in tens of microseconds.

  5. Analysis of observational data from Extreme Ultra-Violet Camera onboard Chang'E-3 mission

    NASA Astrophysics Data System (ADS)

    Yan, Yan; Wang, Hua-Ning; He, Han; He, Fei; Chen, Bo; Feng, Jian-Qing; Ping, Jin-Song; Shen, Chao; Xu, Rong-Lan; Zhang, Xiao-Xin

    2016-02-01

    The Extreme Ultra-Violet Camera (hereafter EUVC) is a scientific payload onboard the lander of the Chang'E-3 (hereafter CE-3) mission launched on December 1st, 2013. Centering on a spectral band around 30.4 nm, EUVC provides the global images of the Earth's plasmasphere from the meridian view, with a spatial resolution of 0.1 R_{oplus} in 150 × 150 pixels and a cadence of 10 minutes. Along with the data being publicly released online, some unsettled issues in the early stage have been clarified, including the geometrical preparations, the refined approach on the coefficient K for the background, and the alignment among the images. A demo of data after all the above processes is therefore presented as a guidance for users who are studying the structure and dynamics of the plasmasphere.

  6. True covariance simulation of the EUVE (extreme ultra violet explorer) update filter

    NASA Technical Reports Server (NTRS)

    Bar-Itzhack, I. Y.; Harman, R. R.

    1990-01-01

    This paper presents a covariance analysis of the performance and sensitivity of the attitude determination Extended Kalman Filter (EKF) used by the onboard computer (OBC) of the Extreme Ultra Violet Explorer (EUVE) spacecraft. The linearized dynamics and measurement equations of the error states are used in formulating the 'truth model' describing the order of the systems involved. The 'design model' used by the OBC EKF is then obtained by reducing the order of the truth model. The covariance matrix of the EKF which uses the reduced order model is not the correct covariance of the EKF estimation error. A 'true covariance analysis' has to be carried out in order to evaluate the correct accuracy of the OBC generated estimates. The results of such analysis are presented which indicate both the performance and the sensitivity of the OBC EKF.

  7. Extreme Ultra-Violet Spectroscopy of the Lower Solar Atmosphere During Solar Flares (Invited Review)

    NASA Astrophysics Data System (ADS)

    Milligan, Ryan O.

    2015-12-01

    The extreme ultra-violet (EUV) portion of the solar spectrum contains a wealth of diagnostic tools for probing the lower solar atmosphere in response to an injection of energy, particularly during the impulsive phase of solar flares. These include temperature- and density-sensitive line ratios, Doppler-shifted emission lines, nonthermal broadening, abundance measurements, differential emission measure profiles, continuum temperatures and energetics, among others. In this article I review some of the recent advances that have been made using these techniques to infer physical properties of heated plasma at footpoint and ribbon locations during the initial stages of solar flares. I primarily focus on studies that have utilised spectroscopic EUV data from Hinode/EUV Imaging Spectrometer (EIS) and Solar Dynamics Observatory/EUV Variability Experiment (SDO/EVE), and I also provide some historical background and a summary of future spectroscopic instrumentation.

  8. Carbon deposition on multi-layer mirrors by extreme ultra violet ray irradiation

    NASA Astrophysics Data System (ADS)

    Matsunari, S.; Aoki, T.; Murakami, K.; Gomei, Y.; Terashima, S.; Takase, H.; Tanabe, M.; Watanabe, Y.; Kakutani, Y.; Niibe, M.; Fukuda, Y.

    2007-03-01

    Organic gases cause carbon depositions on the multi-layer mirrors by Extreme Ultra Violet (EUV) light irradiations in EUV lithography tool. The dependences on organic gas species, organic gas pressure and EUV light intensity in the carbon deposition were researched in order to understand this reaction. EUV light was irradiated on a (Si/Mo) multilayer mirror sample injecting organic gas like buthane, buthanol, methyl propionate, hexane, perfluoro octane, decane, decanol, methyl nonanoate, diethyl benzene, dimethyl phthalate and hexadecane. X-ray photoelectron spectroscopy measurements revealed that organic gases with heavier molecule weight or higher boiling temperature caused faster carbon deposition rates. Carbon deposition rates increased linearly with organic gas pressures. Dependence on EUV light intensity was estimated from comparisons between an EUV light profile and carbon distributions on irradiated samples. Carbon deposition rates increased rapidly, but became saturated at higher EUV light intensities. Three chemical reactions, an adsorption, a desorption and a carbon deposition by EUV light irradiation, were taken into account to explain the behavior of the carbon deposition. Electron irradiation on a mirror sample revealed that photoelectrons emitting from the mirror surface played an important role in carbon deposition.

  9. The solar extreme ultra-violet corona: Resolved loops and the unresolved active region corona

    NASA Astrophysics Data System (ADS)

    Cirtain, Jonathan Wesley

    In this work, physical characteristics of the solar corona as observed in the Extreme Ultra-Violet (EUV) regime are investigated. The focus will be the regions of intense EUV radiation generally found near the locations of sunspots. These regions are commonly called active regions. Multiple space- based observing platforms have been deployed in the last decade; it is possible to use several of these observatories in combination to develop a more complete picture of the solar corona. Joint Observing Program 146 was created to collect spectroscopic intensities using the Coronal Diagnostic Spectrometer on Solar and Heliospheric Observatory and EUV images using NASA's Transition Region and Coronal Explorer. The emission line intensities are analyzed to develop an understanding of the temperature and density of the active region coronal plasma. However, the performance of the CDS instrument in the spatial and temporal domains is limited and to compensate for these limitations, data collected by the TRACE instrument provide a high spatial and temporal resolution set of observations. One of the most exciting unsolved problems in solar astrophysics is to understand why the corona maintains a temperature roughly two orders of magnitude higher than the underlying material. A detailed investigation of the coronal emission has provided constraints on models of the heating mechanism, since the temperature, density and evolution of emission rates for multiple ionic species are indicative of the mechanism(s) working to heat the corona. The corona appears to consist of multiple unresolved structures as well as resolved active region structures, called coronal loops. The purpose of the present work is to determine the characteristics of the unresolved background corona. Using the characterizations of the coronal unresolved background, results for loops after background subtraction are also presented. This work demonstrates the magnitude of the unresolved coronal emission with

  10. Highly selective etching of SnO2 absorber in binary mask structure for extreme ultra-violet lithography.

    PubMed

    Lee, Soo Jin; Jung, Chang Yong; Park, Sung Jin; Hwangbo, Chang Kweun; Seo, Hwan Seok; Kim, Sung Soo; Lee, Nae-Eung

    2012-04-01

    Among the core EUVL (extreme ultra-violet lithography) technologies for nanoscale patterning below the 30 nm node for Si chip manufacturing, new materials and fabrication processes for high-performance EUVL masks are of considerable importance due to the use of new reflective optics. In this work, the selective etching of SnO2 (tin oxide) as a new absorber material, with high EUV absorbance due to its large extinction coefficient, for the binary mask structure of SnO2 (absorber layer)/Ru (capping/etch stop layer)/Mo-Si multilayer (reflective layer)/Si (substrate), was investigated. Because infinitely high selectivity of the SnO2 layer to the Ru ESL is required due to the ultrathin nature of the Ru layer, various etch parameters were assessed in the inductively coupled Cl2/Ar plasmas in order to find the process window required for infinitely high etch selectivity of the SnO2 layer. The results showed that the gas flow ratio and V(dc) value play an important role in determining the process window for the infinitely high etch selectivity of SnO2 to Ru ESL. The high EUV-absorbance SnO2 layer, patternable by a dry process, allows a smaller absorber thickness, which can mitigate the geometric shadowing effects observed for high-performance binary EUVL masks.

  11. Beyond Extreme Ultra Violet (BEUV) Radiation from Spherically symmetrical High-Z plasmas

    NASA Astrophysics Data System (ADS)

    Yoshida, Kensuke; Fujioka, Shinsuke; Higashiguchi, Takeshi; Ugomori, Teruyuki; Tanaka, Nozomi; Kawasaki, Masato; Suzuki, Yuhei; Suzuki, Chihiro; Tomita, Kentaro; Hirose, Ryouichi; Eshima, Takeo; Ohashi, Hayato; Nishikino, Masaharu; Scally, Enda; Nshimura, Hiroaki; Azechi, Hiroshi; O'Sullivan, Gerard

    2016-03-01

    Photo-lithography is a key technology for volume manufacture of high performance and compact semiconductor devices. Smaller and more complex structures can be fabricated by using shorter wavelength light in the photolithography. One of the most critical issues in development of the next generation photo-lithography is to increase energy conversion efficiency (CE) from laser to shorter wavelength light. Experimental database of beyond extreme ultraviolet (BEUV) radiation was obtained by using spherically symmetrical high-Z plasmas generated with spherically allocated laser beams. Absolute energy and spectra of BEUV light emitted from Tb, Gd, and Mo plasmas were measured with a absolutely calibrated BEUV calorimeter and a transmission grating spectrometer. 1.0 x 1012 W/cm2 is the optimal laser intensity to produced efficient BEUV light source plasmas with Tb and Gd targets. Maximum CE is achieved at 0.8% that is two times higher than the published CEs obtained with planar targets.

  12. Reduction of line width and edge roughness by resist reflow process for extreme ultra-violet lithography

    NASA Astrophysics Data System (ADS)

    Cho, In Wook; Park, Joon-Min; Kim, Hyunsu; Hong, Joo-Yoo; Kim, Seong-Sue; Cho, Han-Ku; Oh, Hye-Keun

    2009-03-01

    Extreme ultra-violet lithography (EUVL) has been prepared for next generation lithography for several years. We could get sub-22 nm line and space (L/S) pattern using EUVL, but there are still some problems such as roughness, sensitivity, and resolution. According to 2007 ITRS roadmap, line edge roughness (LER) has to be below 1.9 nm to get a 22 nm node, but it is too difficult to control line width roughness (LWR) because line width is determined by not only the post exposure bake (PEB) time, temperature and acid diffusion length, but also the component and size of the resist. A new method is suggested to reduce the roughness. The surface roughness can be smoothed by applying the resist reflow process (RRP) for the developed resist. We made resist profile which has surface roughness by applying exposure, PEB and development process for line and space pattern. The surface roughness is calculated by changing parameters such as the protected ratio of resin. The PEB time is also varied. We compared difference between 1:1 L/S and 1:3 L/S pattern for 22 nm. Developed resist baked above the glass transition temperature will flow and the surface will be smoothed. As a result, LER and LWR will be much smaller after RRP. The result shows that the decreasing ratio of LER due to RRP is larger when initial LER is large. We believe that current ~ 5 nm LWR can be smoothed to ~ 1 nm by using RRP after develop.

  13. Extreme ultra-violet burst, particle heating, and whistler wave emission in fast magnetic reconnection induced by kink-driven Rayleigh-Taylor instability

    NASA Astrophysics Data System (ADS)

    Chai, Kil-Byoung; Zhai, Xiang; Bellan, Paul M.

    2016-03-01

    A spatially localized energetic extreme ultra-violet (EUV) burst is imaged at the presumed position of fast magnetic reconnection in a plasma jet produced by a coaxial helicity injection source; this EUV burst indicates strong localized electron heating. A circularly polarized high frequency magnetic field perturbation is simultaneously observed at some distance from the reconnection region indicating that the reconnection emits whistler waves and that Hall dynamics likely governs the reconnection. Spectroscopic measurement shows simultaneous fast ion heating. The electron heating is consistent with Ohmic dissipation, while the ion heating is consistent with ion trajectories becoming stochastic.

  14. Microgap ultra-violet detector

    DOEpatents

    Wuest, Craig R.; Bionta, Richard M.

    1994-01-01

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse.

  15. Microgap ultra-violet detector

    DOEpatents

    Wuest, C.R.; Bionta, R.M.

    1994-09-20

    A microgap ultra-violet detector of photons with wavelengths less than 400 run (4,000 Angstroms) which comprises an anode and a cathode separated by a gas-filled gap and having an electric field placed across the gap is disclosed. Either the anode or the cathode is semi-transparent to UV light. Upon a UV photon striking the cathode an electron is expelled and accelerated across the gap by the electric field causing interactions with other electrons to create an electron avalanche which contacts the anode. The electron avalanche is detected and converted to an output pulse. 2 figs.

  16. Ultra violet disinfection: A 3-year history

    SciTech Connect

    Tubesing, R.R.; Lindeke, D.R.

    1998-07-01

    The Stillwater Wastewater Treatment Facility is one of nine wastewater treatment facilities operated by the Metropolitan Council Environmental Services in the Minneapolis-St. Paul Metropolitan Area. The facility services the cities of Stillwater, Oak Park Heights, and Bayport. In 1993, an ultra violet disinfection facility began operation to provide the disinfection for the Facility. This presentation discusses the reasons for using ultra violet disinfection in lieu of chlorination/dechlorination facilities, the operating performance, and operating cost factors.

  17. Electronic states of thiophene/phenylene co-oligomers: Extreme-ultra violet excited photoelectron spectroscopy observations and density functional theory calculations

    SciTech Connect

    Kawaguchi, Yoshizo; Sasaki, Fumio; Mochizuki, Hiroyuki; Ishitsuka, Tomoaki; Tomie, Toshihisa; Ootsuka, Teruhisa; Watanabe, Shuji; Shimoi, Yukihiro; Yamao, Takeshi; Hotta, Shu

    2013-02-28

    We have investigated electronic states in the valence electron bands for the thin films of three thiophene/phenylene co-oligomer (TPCO) compounds, 2,5-bis(4-biphenylyl)thiophene (BP1T), 1,4-bis(5-phenylthiophen-2-yl)benzene (AC5), and 1,4-bis{l_brace}5-[4-(trifluoromethyl)phenyl]thiophen-2-yl{r_brace}benzene (AC5-CF{sub 3}), by using extreme-UV excited photoelectron spectroscopy (EUPS). By comparing both EUPS spectra and secondary electron spectra between AC5 and AC5-CF{sub 3}, we confirm that CF{sub 3} substitution to AC5 deepens valence states by 2 eV, and increases the ionization energy by 3 eV. From the cut-off positions of secondary electron spectra, the work functions of AC5, AC5-CF{sub 3}, and BP1T are evaluated to be 3.8 eV, 4.8 eV, and 4.0 eV, respectively. We calculate molecular orbital (MO) energy levels by the density functional theory and compare results of calculations with those of experiments. Densities of states obtained by broadening MO levels well explain the overall features of experimental EUPS spectra of three TPCOs.

  18. New Sub-nanometer Spectral Estimates of the 0-5 nm Solar Soft X-Ray Irradiance at Mars Using the Extreme UltraViolet Monitor (EUVM) Onboard MAVEN

    NASA Astrophysics Data System (ADS)

    Thiemann, E.; Eparvier, F. G.; Chamberlin, P. C.; Woods, T. N.; Peterson, W. K.; Mitchell, D. L.; Xu, S.; Liemohn, M. W.

    2015-12-01

    The Extreme UltraViolet Monitor (EUVM) onboard the Mars Atmosphere and Volatile EvolutioN (MAVEN) probe at Mars characterizes the solar extreme ultraviolet (EUV) and soft x-ray (SXR) input into the Martian atmosphere. EUVM measures solar irradiance at 0-7 nm, 17-22 nm and 121.6 nm at a nominal 1 second cadence. These bands were selected to capture variability originating at different heights in the solar atmosphere; and are used to drive the Flare Irradiance Solar Model at Mars (FISM-M) that is a model of the solar spectrum from 0.1-190 nm with 1 nm resolution and produced routinely as the EUVM Level 3 data product. The 0-5 nm range of the solar spectrum is of particular aeronomic interest because the primary species of the Mars upper atmosphere have Auger transitions in this range. When an Auger transition is excited by incident SXR radiation, secondary electrons are emitted with sufficient energy to further ionize the atmosphere. Because these transitions are highly structured, sub-nm resolution of the solar spectrum is needed in the 0-5 nm range to fully constrain the solar input and more accurately characterize the energetics of the upper atmosphere. At Earth, .1 nm resolution estimates of the solar 0-5 nm range are produced by the X-ray Photometer System (XPS) onboard the SOlar Radiation and Climate Experiment (SORCE) satellite by combining broad-band SXR measurements with solar flare temperature measurements to drive an atomic physics based forward model of solar coronal emissions. This spectrum has been validated with other models as well as with photo-electron and day glow measurements at Earth. Similar to XPS, the EUVM 0-7 nm and 17-22 nm bands can be used to produce an XPS-like model at Mars, but with reduced precision due to differences in the available bands. We present first results of this technique applied to a set of solar flares observed by MAVEN EUVM and Earth assets. In addition to comparing EUVM and Earth-asset derived 0-5 nm solar spectra to

  19. STEREO's Extreme UltraViolet Imager (EUVI)

    NASA Technical Reports Server (NTRS)

    2007-01-01

    At a pixel resolution of 2048x2048, the STEREO EUVI instrument provides views of the Sun in ultraviolet light that rivals the full-disk views of SOHO/EIT. This image is through the 171 Angstrom (ultraviolet) filter which is characteristic of iron ions (missing eight and nine electrons) at 1 million degrees. There is a short data gap in the latter half of the movie that creates a freeze and then jump in the data view. This is a movie of the Sun in 171 Angstrom ultraviolet light. The time frame is late January, 2007

  20. Can Ultra-violet Mie Lidar Be an Effective Instrument During High Pollution Episode?

    NASA Astrophysics Data System (ADS)

    Liu, Qiaojun; Wang, Zhangjun; Du, Libin; Cheng, Andrew Yuk Sun; Meng, Xiangqian; Chen, Chao; Li, Xianxin; Liu, Xingtao

    2016-06-01

    Vertical profiles of particulates were measured by a 355 nm Mie scattering lidar during a dust-storm event. A high energy pulse laser was employed as the light source to detect the extinction coefficient in the altitude up to 6 km in the day and 9 km at night. The extinction profiles showed layers of high aerosol concentrations in good agreement with ground-based pollution measurements, which indicated that such ultra-violet lidar is a very useful remote sensing instrument for monitoring extinction profiles during extreme high aerosol loading and low visibility atmospheric conditions when low energy lidar systems cannot obtain effective results.

  1. Tests and calibration on ultra violet imaging telescope (UVIT)

    NASA Astrophysics Data System (ADS)

    Kumar, Amit; Ghosh, S. K.; Kamath, P. U.; Postma, Joe; Kathiravan, S.; Mahesh, P. K.; Nagbhushana, S.; Navalgund, K. H.; Rajkumar, N.; Rao, M. N.; Sarma, K. S.; Sriram, S.; Stalin, C. S.; Tandon, S. N.

    2012-09-01

    Ultra Violet Imaging Telescope on ASTROSAT Satellite mission is a suite of Far Ultra Violet (FUV; 130 - 180 nm), Near Ultra Violet (NUV; 200 - 300 nm) and Visible band (VIS; 320-550nm) imagers. ASTROSAT is a first multi wavelength mission of INDIA. UVIT will image the selected regions of the sky simultaneously in three channels & observe young stars, galaxies, bright UV Sources. FOV in each of the 3 channels is ~ 28 arc-minute. Targeted angular resolution in the resulting UV images is better than 1.8 arc-second (better than 2.0 arc-second for the visible channel). Two identical co-aligned telescopes (T1, T2) of Ritchey-Chretien configuration (Primary mirror of ~375 mm diameter) collect the celestial radiation and feed to the detector system via a selectable filter on a filter wheel mechanism; gratings are available in the filter wheels of FUV and NUV channels for slit-less low resolution spectroscopy. The detector system for each of the 3 channels is generically identical. One telescope images in the FUV channel, and other images in NUV and VIS channels. One time open-able mechanical cover on each telescope also works as Sun-shield after deployment. We will present the optical tests and calibrations done on the two telescopes. Results on vibrations test and thermo-vacuum tests on the engineering model will also be presented.

  2. Vacuum ultra-violet and ultra-violet scintillation light detection by means of silicon photomultipliers at cryogenic temperature

    NASA Astrophysics Data System (ADS)

    Falcone, A.; Bertoni, R.; Boffelli, F.; Bonesini, M.; Cervi, T.; Menegolli, A.; Montanari, C.; Prata, M. C.; Rappoldi, A.; Raselli, G. L.; Rossella, M.; Simonetta, M.; Spanu, M.; Torti, M.; Zani, A.

    2015-07-01

    We tested the performance of two types of silicon photomultipliers, AdvanSiD ASD-NUV-SiPM3S-P and Hamamatsu 3×3 MM-50 UM VUV2, both at room (300 K) and at liquid nitrogen (77 K) temperature: breakdown voltage, quenching resistance, signal shape, gain and dark counts rate have been studied as function of temperature. The response of the devices to ultra-violet light is also studied.

  3. Frequency Up-Conversion to the Vacuum Ultra-Violet in Coherently Prepared Media

    NASA Astrophysics Data System (ADS)

    Marangos, J. P.; Kuçukkara, I.; Anscombe, M.

    In this contribution we discuss recent work that has demonstrated that electromagnetically induced transparency (EIT) can greatly increase the intensity of coherent vacuum ultra-violet (VUV) radiation (at wavelengths shorter than 130nm) generated in resonant four-wave mixing schemes. We will start by introducing the basic concept of EIT enhanced resonant four-wave mixing, comparing it briefly with other coherently enhanced non-linear frequency up-conversion schemes. Experiments proving this concept in atomic hydrogen in the mid-1990's will be summarised. Our own recent work on EIT enhanced four-wave mixing in Kr will be presented and recent results demonstrating high conversion efficiencies into the VUV, and the limits placed on this process at high density-length products, will be discussed.

  4. Polyamide as an efficient sorbent for simultaneous interface-free determination of three Sudan dyes in saffron and urine using high-performance liquid chromatography-ultra violet detection.

    PubMed

    Saeidi, Iman; Barfi, Behruz; Payrovi, Moazameh; Feizy, Javid; Sheibani, Hojat A; Miri, Mina; Ghollasi Moud, Farahnaz

    2015-01-01

    With polyamide (PA) as an efficient sorbent for solid phase extraction (SPE) of Sudan dyes II, III and Red 7B from saffron and urine, their determination by HPLC was performed. The optimum conditions for SPE were achieved using 7 mL methanol/water (1:9, v/v, pH 7) as the washing solvent and 3 mL tetrahydrofuran for elution. Good clean-up and high (above 90%) recoveries were observed for all the analytes. The optimized mobile phase composition for HPLC analysis of these compounds was methanol-water (70:30, v/v). The SPE parameters, such as the maximum loading capacity and breakthrough volume, were also determined for each analyte. The limits of detection (LODs), limits of quantification (LOQs), linear ranges and recoveries for the analytes were 4.6-6.6 microg/L, 13.0-19.8 microg/L, 13.0-5000 microg/L (r2>0.99) and 92.5%-113.4%, respectively. The precisions (RSDs) of the overall analytical procedure, estimated by five replicate measurements for Sudan II, III and Red 7B in saffron and urine samples were 2.3%, 1.8% and 3.6%, respectively. The developed method is simple and successful in the application to the determination of Sudan dyes in saffron and urine samples with HPLC coupled with UV detection.

  5. Investigation of ultra violet (UV) resistance for high strength fibers

    NASA Astrophysics Data System (ADS)

    Said, M. A.; Dingwall, Brenda; Gupta, A.; Seyam, A. M.; Mock, G.; Theyson, T.

    Ultra long duration balloons (ULDB), currently under development by the National Aeronautics and Space Administration (NASA), requires the use of high strength fibers in the selected super-pressure pumpkin design. The pumpkin shape balloon concept allows clear separation of the load transferring functions of the major structural elements of the pneumatic envelope, the tendons and the film. Essentially, the film provides the gas barrier and transfers only local pressure load to the tendons. The tendons, in the mean time, provide the global pressure containing strength. In that manner, the strength requirement for the film only depends on local parameters. The tendon is made of p-phenylene-2,6-benzobisoxazole (PBO) fibers, which is selected due to its high strength to weight ratio when compared to other high performance, commercially available, fibers. High strength fibers, however, are known to degrade upon exposure to light, particularly at short wavelengths. This paper reports the results of an investigation of the resistance of four commercial high strength fibers to ultra violet (UV) exposure. The results indicate that exposing high strength fibers in continuous yarn form to UV led to serious loss in strength of the fibers except for Spectra® fibers. The adverse changes in mechanical behavior occurred over short duration of exposure compared to the 100 day duration targeted for these missions. UV blocking finishes to improve the UV resistance of these fibers are being investigated. The application of these specially formulated coatings is expected to lead to significant improvement of the UV resistance of these high performance fibers. In this publication, we report on the mechanical behavior of the fibers pre- and post-exposure to UV, but without application of the blocking finishes.

  6. Global Ultra-Violet Ionosphere-Thermosphere Observatory (GUVITO)

    NASA Astrophysics Data System (ADS)

    Curtis, N.; Crowley, G.; Christensen, A. B.; Paxton, L. J.; Robichaud, J.; Barry, M. A.; Bust, G. S.

    2009-12-01

    UV spectrographic imagers such as SSUSI and GUVI provide measurements of the aurora, ionospheric electron density, ionospheric bubbles, and thermospheric temperature, composition, and density. These imagers have been a key element of the Air Force DMSP program, but to accommodate new satellite concepts and maintain flexibility in the choice of new space systems and launch options, lighter weight and more capable UV instruments are needed to replace the current series of SSUSI sensors. Here we describe a technological alternative to the currently flying SSUSI sensors. It is a spectrographic imaging capability known as the “Global Ultra-Violet Ionosphere-Thermosphere Observatory” (GUVITO) sensor and associated software. GUVITO improves upon current instruments by being smaller in size, weight and power but with improved functionality. The GUVITO sensor represents an upgrade of the SSUSI and GUVI sensors in terms of scan mirror functionality and reliability, sensor functionality, mass, and power requirements. In particular, this improved functionality is expected to lead to enhanced capability in observing ionospheric bubbles, which are thought to cause scintillation and serious technological challenges for communications, navigation and surveillance systems. Initial development and risk reduction activities are currently funded by AFRL through a SBIR Phase II contract. The enhanced reliability and performance of the GUVITO sensor system is achieved with flight heritage components, concepts, software, hardware and is guided by key personnel experienced with both the SSUSI and GUVI hardware, software and operations. GUVITO would meet DoD priority requirements in ionospheric density, scintillation, and satellite drag, meet NPOESS IORD-II requirements for space environment Environmental Data Records (EDRs), maintain current DMSP capability, ensure long-term continuity of space environmental monitoring and leverage new technology development for future operational

  7. White light emission from polystyrene under pulsed ultra violet laser irradiation

    PubMed Central

    Kim, Eunkyeom; Kyhm, Jihoon; Kim, Jung Hyuk; Lee, Gi Yong; Ko, Doo-Hyun; Han, Il Ki; Ko, Hyungduk

    2013-01-01

    This paper reports for the first time the luminescent property of polystyrene (PS), produced by pulsed ultra violet laser irradiation. We have discovered that, in air, ultra-violet (UV) irradiated PS nanospheres emit bright white light with the dominant peak at 510 nm, while in vacuum they emit in the near-blue region. From the comparison of PS nanospheres irradiated in vacuum and air, we suggest that the white luminescence is due to the formation of carbonyl groups on the surface of PS by photochemical oxidation. Our results potentially offer a new route and strategy for white light sources. PMID:24247038

  8. Effect of Ultra Violet Radiation on Surface Properties: Comparison of RTV 655 and Silica--Based Aerogels

    NASA Astrophysics Data System (ADS)

    Sinden-Redding, Mackenzie; Sabri, Firouzeh

    2009-11-01

    The broad spectrum of ultra violet (UV) radiation causes material property changes such as chalkiness, brittleness, color change, and ultimately complete mechanical failure. UV radiation is also known to modify the surface charge state of insulators. These effects are intensified for materials used in space exploration due to the lack of an atmosphere. In this work, we compare the radiation response and the material properties of RTV 655 (existing calibration targets material on Phoenix Mars Lander) and silica-based aerogels. The extreme light-weight and ability to color-code aerogels makes this material a candidate for the next generation of calibration targets. The radiation response of both materials will be studied using Kelvin Probe, UV-VIS spectrophotometry, and ESR techniques.

  9. Consequences of Ultra-Violet Irradiation on the Mechanical Properties of Spider Silk

    PubMed Central

    Lai, Wee Loong; Goh, Kheng Lim

    2015-01-01

    The outstanding combination of high tensile strength and extensibility of spider silk is believed to contribute to the material’s toughness. Thus, there is great interest in engineering silk for biomedical products such as suture or implants. Additionally, over the years, many studies have also sought to enhance the mechanical properties of spider silk for wider applicability, e.g., by irradiating the material using ultra-violet radiation. However, the limitations surrounding the use of ultra-violet radiation for enhancing the mechanical properties of spider silk are not well-understood. Here, we have analyzed the mechanical properties of spider silk at short ultra-violet irradiation duration. Specimens of spider silk were subjected to ultra-violet irradiation (254-nm wavelength, i.e. UVC) for 10, 20, and 30 min, respectively, followed by tensile test to rupture to determine the strength (maximum stress), extensibility (rupture strain), and toughness (strain energy density to rupture). Controls, i.e., specimens that did not received UVC, were also subjected to tensile test to rupture to determine the respective mechanical properties. One-way analysis of variance reveals that these properties decrease significantly (p < 0.05) with increasing irradiation duration. Among the three mechanical parameters, the strength of the spider silk degrades most rapidly; the extensibility of the spider silk degrades the slowest. Overall, these changes correspond to the observed surface modifications as well as the bond rupture between the peptide chains of the treated silk. Altogether, this simple but comprehensive study provides some key insights into the dependence of the mechanical properties on ultra-violet irradiation duration. PMID:26378587

  10. Consequences of Ultra-Violet Irradiation on the Mechanical Properties of Spider Silk.

    PubMed

    Lai, Wee Loong; Goh, Kheng Lim

    2015-01-01

    The outstanding combination of high tensile strength and extensibility of spider silk is believed to contribute to the material's toughness. Thus, there is great interest in engineering silk for biomedical products such as suture or implants. Additionally, over the years, many studies have also sought to enhance the mechanical properties of spider silk for wider applicability, e.g., by irradiating the material using ultra-violet radiation. However, the limitations surrounding the use of ultra-violet radiation for enhancing the mechanical properties of spider silk are not well-understood. Here, we have analyzed the mechanical properties of spider silk at short ultra-violet irradiation duration. Specimens of spider silk were subjected to ultra-violet irradiation (254-nm wavelength, i.e. UVC) for 10, 20, and 30 min, respectively, followed by tensile test to rupture to determine the strength (maximum stress), extensibility (rupture strain), and toughness (strain energy density to rupture). Controls, i.e., specimens that did not received UVC, were also subjected to tensile test to rupture to determine the respective mechanical properties. One-way analysis of variance reveals that these properties decrease significantly (p < 0.05) with increasing irradiation duration. Among the three mechanical parameters, the strength of the spider silk degrades most rapidly; the extensibility of the spider silk degrades the slowest. Overall, these changes correspond to the observed surface modifications as well as the bond rupture between the peptide chains of the treated silk. Altogether, this simple but comprehensive study provides some key insights into the dependence of the mechanical properties on ultra-violet irradiation duration. PMID:26378587

  11. Fabrication and characterization of p-ZnO:(P,N)/n-ZnO:Al homojunction ultra-violet (UV) light emitting diodes (Presentation Recording)

    NASA Astrophysics Data System (ADS)

    Rafiudeen, Amiruddin; Reddy, T. Srinivasa; Cheemadan, Shaheer; Kumar, M. C. Santhosh

    2015-10-01

    ZnO possess distinctive characteristics such as low cost, wide band gap (3.36 eV) and large exciton binding energy (60meV). As the band gap lies in ultra violet (UV) region, ZnO is considered as a novel material for the fabrication of ultra violet light emitting diodes (UV-LEDs). However, ZnO being intrinsic n-type semiconductor the key challenge lies in realization of stable and reproducible p-type ZnO. In the present research dual acceptor group-V elements such as P and N are simultaneously doped in ZnO films to obtain the p-type characteristics. The deposition is made by programmable spray pyrolysis technique upon glass substrates at 697K. The optimum doping concentration of P and N were found to be 0.75 at% which exhibits hole concentration of 4.48 x 10^18 cm-3 and resistivity value of 9.6 Ω.cm. The deposited p-ZnO were found to be stable for a period over six months. Highly conducting n-type ZnO films is made by doping aluminum (3 at%) which exhibits higher electron concentration of 1.52 x 10^19 cm-3 with lower electrical resistivity of 3.51 x 10-2 Ω.cm. The structural, morphological, optical and electrical properties of the deposited n-ZnO and p-ZnO thin films are investigated. An efficient p-n homojunction has been fabricated using the optimum p-ZnO:(P,N) and n-ZnO:Al layers. The current-voltage (I-V) characteristics show typical rectifying characteristics of p-n junction with a low turn on voltage. Electroluminescence (EL) studies reveals the fabricated p-n homojunction diodes exhibits strong emission features in ultra-violet (UV) region around 378 nm.

  12. Microstructure of nitride semiconductors for ultra-violet light emitters

    NASA Astrophysics Data System (ADS)

    Liu, Rong

    Group III-nitride semiconductors are important materials for the fabrication of light-emitting-diodes (LEDs) and laser diodes operating in the blue-ultraviolet region. While their unique physical properties have made it possible to fabricate high-efficiency blue devices, the ultraviolet (UV) counterparts face many challenges. High-performance, nitride-based UV-LEDs should revolutionize the general lighting technology. In the near future, fluorescent bulbs are expected to be replaced by long-life and compact-size UV-LEDs coated with phosphors. This dissertation addresses the challenges facing the development of such UV-emitting nitride semiconductor materials. Three critical issues need to be resolved in order to fabricate high-performance UV-LEDs based on aluminum gallium nitride (AlGaN) alloys: (a) the growth of crack-free AlGaN films, (b) the elimination of crystalline defects, and (c) control of doping. In order to address these issues, epitaxy on a new substrate, ZrB2, has been studied. This substrate is closely matched to AlGaN and permits minimization of residual strain due to lattice and thermal-expansion mismatch and thus avoids the formation of cracks. The growth of crack-free AlGaN using facet-controlled epitaxial lateral overgrowth has also been studied. Plastic relaxation mechanism of mismatch strain has been understood by detailed characterization of the microstructure. The defect density has been reduced by more than one order of magnitude using these approaches, with a significant improvement in the UV-LEDs' efficiency. Distinct dopant incorporation behavior has been observed in lateral overgrowth. The effects of silicon doping on the optical properties and microstructure of AlGaN/GaN quantum wells have also been investigated. These studies have resulted in significant improvement of UV-LEDs' performance. Finally, recommendations for further work are made.

  13. Luminescence spectroscopy from the vacuum ultra-violet to the visible for Er 3+ and Tm 3+ in complex fluoride crystals

    NASA Astrophysics Data System (ADS)

    Khaidukov, N. M.; Lam, S. K.; Lo, D.; Makhov, V. N.; Suetin, N. V.

    2002-05-01

    Spectra and decay kinetics of luminescence from several complex fluorides of alkali elements and yttrium or gadolinium doped with Er 3+ or Tm 3+ have been studied in the vacuum ultra-violet (VUV), ultra-violet (UV) and visible spectral ranges under excitation by the 157 nm radiation from a pulsed molecular F 2-laser. It has been found that yttrium crystals have intense VUV luminescence due to interconfiguration 5d-4f transitions in the rare earth ions. On the other hand, the 5d-4f luminescence from Er 3+ or Tm 3+ in gadolinium crystals is completely absent and the nonradiative decay as a result of cross-relaxation is the dominant decay channel from the 5d level of the doping rare earth ion in these crystals. This process leads to complete conversion of absorbed VUV radiation into the lower energy part of the spectrum. These gadolinium fluorides appear to be promising materials for VUV-excited phosphors with high-quantum efficiency.

  14. Oxidation preventative capping layer for deep-ultra-violet and soft x-ray multilayers

    DOEpatents

    Prisbrey, Shon T.

    2004-07-06

    The invention uses iridium and iridium compounds as a protective capping layer on multilayers having reflectivity in the deep ultra-violet to soft x-ray regime. The iridium compounds can be formed in one of two ways: by direct deposition of the iridium compound from a prepared target or by depositing a thin layer (e.g., 5-50 angstroms) of iridium directly onto an element. The deposition energy of the incoming iridium is sufficient to activate the formation of the desired iridium compound. The compounds of most interest are iridium silicide (IrSi.sub.x) and iridium molybdenide (IrMo.sub.x).

  15. Detection of biological warfare agents using ultra violet-laser induced fluorescence LIDAR.

    PubMed

    Joshi, Deepti; Kumar, Deepak; Maini, Anil K; Sharma, Ramesh C

    2013-08-01

    This review has been written to highlight the threat of biological warfare agents, their types and detection. Bacterial biological agent Bacillus anthracis (bacteria causing the disease anthrax) which is most likely to be employed in biological warfare is being discussed in detail. Standoff detection of biological warfare agents in aerosol form using Ultra violet-Laser Induced Fluorescence (UV-LIF) spectroscopy method has been studied. Range-resolved detection and identification of biological aerosols by both nano-second and non-linear femto-second LIDAR is also discussed. Calculated received fluorescence signal for a cloud of typical biological agent Bacillus globigii (Simulants of B. anthracis) at a location of ~5.0 km at different concentrations in presence of solar background radiation has been described. Overview of current research efforts in internationally available working UV-LIF LIDAR systems are also mentioned briefly. PMID:23719340

  16. Bias Selectable Dual Band AlGaN Ultra-violet Detectors

    NASA Technical Reports Server (NTRS)

    Yan, Feng; Miko, Laddawan; Franz, David; Guan, Bing; Stahle, Carl M.

    2007-01-01

    Bias selectable dual band AlGaN ultra-violet (UV) detectors, which can separate UV-A and UV-B using one detector in the same pixel by bias switching, have been designed, fabricated and characterized. A two-terminal n-p-n photo-transistor-like structure was used. When a forward bias is applied between the top electrode and the bottom electrode, the detectors can successfully detect W-A and reject UV-B. Under reverse bias, they can detect UV-B and reject UV-A. The proof of concept design shows that it is feasible to fabricate high performance dual-band UV detectors based on the current AlGaN material growth and fabrication technologies.

  17. Detection of biological warfare agents using ultra violet-laser induced fluorescence LIDAR.

    PubMed

    Joshi, Deepti; Kumar, Deepak; Maini, Anil K; Sharma, Ramesh C

    2013-08-01

    This review has been written to highlight the threat of biological warfare agents, their types and detection. Bacterial biological agent Bacillus anthracis (bacteria causing the disease anthrax) which is most likely to be employed in biological warfare is being discussed in detail. Standoff detection of biological warfare agents in aerosol form using Ultra violet-Laser Induced Fluorescence (UV-LIF) spectroscopy method has been studied. Range-resolved detection and identification of biological aerosols by both nano-second and non-linear femto-second LIDAR is also discussed. Calculated received fluorescence signal for a cloud of typical biological agent Bacillus globigii (Simulants of B. anthracis) at a location of ~5.0 km at different concentrations in presence of solar background radiation has been described. Overview of current research efforts in internationally available working UV-LIF LIDAR systems are also mentioned briefly.

  18. Detection of biological warfare agents using ultra violet-laser induced fluorescence LIDAR

    NASA Astrophysics Data System (ADS)

    Joshi, Deepti; Kumar, Deepak; Maini, Anil K.; Sharma, Ramesh C.

    This review has been written to highlight the threat of biological warfare agents, their types and detection. Bacterial biological agent Bacillus anthracis (bacteria causing the disease anthrax) which is most likely to be employed in biological warfare is being discussed in detail. Standoff detection of biological warfare agents in aerosol form using Ultra violet-Laser Induced Fluorescence (UV-LIF) spectroscopy method has been studied. Range-resolved detection and identification of biological aerosols by both nano-second and non-linear femto-second LIDAR is also discussed. Calculated received fluorescence signal for a cloud of typical biological agent Bacillus globigii (Simulants of B. anthracis) at a location of ˜5.0 km at different concentrations in presence of solar background radiation has been described. Overview of current research efforts in internationally available working UV-LIF LIDAR systems are also mentioned briefly.

  19. Effect of Montmorillonite Modification on Ultra Violet Radiation Cured Nanocomposite Filled with Glycidyl Methacrylate Modified Kenaf

    NASA Astrophysics Data System (ADS)

    Rozyanty, A. R.; Rozman, H. D.; Zhafer, S. F.; Musa, L.; Zuliahani, A.

    2016-06-01

    In this study nanocomposite cured by ultra violet radiation, were produced using modified montmorillonite (MMT) as reinforcing agent, chemically modified kenaf bast fiber as filler and unsaturated polyester as the matrix. Kenaf bast fiber was chemically modified with glycidyl methacrylate (GMA) whilst MMT were modified with cetyl trimethyl ammonium bromide (CTAB) and glycidyl methacrylate (GMA). Fixed 12 percent of GMA modified kenaf bast fiber with different percentage (i.e., 1, 3 and 5) of unmodified and modified MMT loading was used to produce the composite. The performed of GMA reaction with hydroxyl group of cellulose in kenaf bast fiber was evaluated using Fourier Transform infrared (FTIR) spectroscopy. GMA-MMT filled composite showed higher mechanical properties than MMT and CTAB-MMT filled composite. However, the increase of MMT, CTAB-MMT and GMA- MMT loading resulted in the reduction of mechanical properties. Scanning electron microscopy (SEM) analysis showed the evidence of compatibility enhancement between MMT and kenaf bast fiber with unsaturated polyester matrix.

  20. Buried graphene electrodes on GaN-based ultra-violet light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Kim, Byung-Jae; Lee, Chongmin; Mastro, Michael A.; Hite, Jennifer K.; Eddy, Charles R.; Ren, Fan; Pearton, Stephen J.; Kim, Jihyun

    2012-07-01

    We report that the oxidation of graphene-based highly transparent conductive layers to AlGaN/GaN/AlGaN ultra-violet (UV) light-emitting diodes (LEDs) was suppressed by the use of SiNX passivation layers. Although graphene is considered to be an ideal candidate as the transparent conductive layer to UV-LEDs, oxidation of these layers at high operating temperatures has been an issue. The oxidation is initiated at the un-saturated carbon atoms at the edges of the graphene and reduces the UV light intensity and degrades the current-voltage (I-V) characteristics. The oxidation also can occur at defects, including vacancies. However, GaN-based UV-LEDs deposited with SiNX by plasma-enhanced chemical vapor deposition showed minimal degradation of light output intensity and I-V characteristics because the graphene-based UV transparent conductive layers were shielded from the oxygen molecules. This is a simple and effective approach for maintaining the advantages of graphene conducting layers as electrodes on UV-LEDs.

  1. Ultra-violet and visible absorption characterization of explosives by differential reflectometry

    NASA Astrophysics Data System (ADS)

    Dubroca, Thierry; Moyant, Kyle; Hummel, Rolf E.

    2013-03-01

    This study presents some optical properties of TNT (2,4,6-trinitrotoluene), RDX, HMX and tetryl, specifically their absorption spectra as a function of concentration in various solvents in the ultraviolet and visible portion of the electromagnetic spectrum. We utilize a standoff explosives detection method, called differential reflectometry (DR). TNT was diluted in six different solvents (acetone, acetonitrile, ethanol, ethyl acetate, methanol, and toluene), which allowed for a direct comparison of absorption features over a wide range of concentrations. A line-shape analysis was adopted with great accuracy (R2 > 0.99) to model the absorption features of TNT in differential reflectivity spectra. We observed a blue shift in the pertinent absorption band with decreasing TNT concentration for all solvents. Moreover, using this technique, it was found that for all utilized solvents the concentration of TNT as well as of RDX, HMX, and tetryl, measured as a function of the transition wavelength of the ultra-violet absorption edge in differential reflectivity spectra shows three distinct regions. A model is presented to explain this behavior which is based on intermolecular hydrogen bonding of explosives molecules with themselves (or lack thereof) at different concentrations. Other intermolecular forces such as dipole-dipole interactions, London dispersion forces and π-stacking contribute to slight variations in the resulting spectra, which were determined to be rather insignificant in comparison to hydrogen bonding. The results are aimed towards a better understanding of the DR spectra of explosives energetic materials.

  2. Ultra-violet and visible absorption characterization of explosives by differential reflectometry.

    PubMed

    Dubroca, Thierry; Moyant, Kyle; Hummel, Rolf E

    2013-03-15

    This study presents some optical properties of TNT (2,4,6-trinitrotoluene), RDX, HMX and tetryl, specifically their absorption spectra as a function of concentration in various solvents in the ultraviolet and visible portion of the electromagnetic spectrum. We utilize a standoff explosives detection method, called differential reflectometry (DR). TNT was diluted in six different solvents (acetone, acetonitrile, ethanol, ethyl acetate, methanol, and toluene), which allowed for a direct comparison of absorption features over a wide range of concentrations. A line-shape analysis was adopted with great accuracy (R(2)>0.99) to model the absorption features of TNT in differential reflectivity spectra. We observed a blue shift in the pertinent absorption band with decreasing TNT concentration for all solvents. Moreover, using this technique, it was found that for all utilized solvents the concentration of TNT as well as of RDX, HMX, and tetryl, measured as a function of the transition wavelength of the ultra-violet absorption edge in differential reflectivity spectra shows three distinct regions. A model is presented to explain this behavior which is based on intermolecular hydrogen bonding of explosives molecules with themselves (or lack thereof) at different concentrations. Other intermolecular forces such as dipole-dipole interactions, London dispersion forces and π-stacking contribute to slight variations in the resulting spectra, which were determined to be rather insignificant in comparison to hydrogen bonding. The results are aimed towards a better understanding of the DR spectra of explosives energetic materials.

  3. Sub-50 nm metrology on extreme ultra violet chemically amplified resist--A systematic assessment.

    PubMed

    Maas, D J; Fliervoet, T; Herfst, R; van Veldhoven, E; Meessen, J; Vaenkatesan, V; Sadeghian, H

    2015-10-01

    With lithographic patterning dimensions decreasing well below 50 nm, it is of high importance to understand metrology at such small scales. This paper presents results obtained from dense arrays of contact holes (CHs) with various Critical Dimension (CD) between 15 and 50 nm, as patterned in a chemically amplified resist using an ASML EUV scanner and measured at ASML and TNO. To determine the differences between various (local) CD metrology techniques, we conducted an experiment using optical scatterometry, CD-Scanning Electron Microscopy (CD-SEM), Helium ion Microscopy (HIM), and Atomic Force Microscopy (AFM). CD-SEM requires advanced beam scan strategies to mitigate sample charging; the other tools did not need that. We discuss the observed main similarities and differences between the various techniques. To this end, we assessed the spatial frequency content in the raw images for SEM, HIM, and AFM. HIM and AFM resolve the highest spatial frequencies, which are attributed to the more localized probe-sample interaction for these techniques. Furthermore, the SEM, HIM, and AFM waveforms are analyzed in detail. All techniques show good mutual correlation, albeit the reported CD values systematically differ significantly. HIM systematically reports a 25% higher CD uniformity number than CD-SEM for the same arrays of CHs, probably because HIM has a higher resolution than the CD-SEM used in this assessment. A significant speed boost for HIM and AFM is required before these techniques are to serve the demanding industrial metrology applications like optical critical dimension and CD-SEM do nowadays. PMID:26520961

  4. Sub-50 nm metrology on extreme ultra violet chemically amplified resist—A systematic assessment

    NASA Astrophysics Data System (ADS)

    Maas, D. J.; Fliervoet, T.; Herfst, R.; van Veldhoven, E.; Meessen, J.; Vaenkatesan, V.; Sadeghian, H.

    2015-10-01

    With lithographic patterning dimensions decreasing well below 50 nm, it is of high importance to understand metrology at such small scales. This paper presents results obtained from dense arrays of contact holes (CHs) with various Critical Dimension (CD) between 15 and 50 nm, as patterned in a chemically amplified resist using an ASML EUV scanner and measured at ASML and TNO. To determine the differences between various (local) CD metrology techniques, we conducted an experiment using optical scatterometry, CD-Scanning Electron Microscopy (CD-SEM), Helium ion Microscopy (HIM), and Atomic Force Microscopy (AFM). CD-SEM requires advanced beam scan strategies to mitigate sample charging; the other tools did not need that. We discuss the observed main similarities and differences between the various techniques. To this end, we assessed the spatial frequency content in the raw images for SEM, HIM, and AFM. HIM and AFM resolve the highest spatial frequencies, which are attributed to the more localized probe-sample interaction for these techniques. Furthermore, the SEM, HIM, and AFM waveforms are analyzed in detail. All techniques show good mutual correlation, albeit the reported CD values systematically differ significantly. HIM systematically reports a 25% higher CD uniformity number than CD-SEM for the same arrays of CHs, probably because HIM has a higher resolution than the CD-SEM used in this assessment. A significant speed boost for HIM and AFM is required before these techniques are to serve the demanding industrial metrology applications like optical critical dimension and CD-SEM do nowadays.

  5. Sub-50 nm metrology on extreme ultra violet chemically amplified resist—A systematic assessment

    SciTech Connect

    Maas, D. J. Herfst, R.; Veldhoven, E. van; Fliervoet, T.; Meessen, J.; Vaenkatesan, V.; Sadeghian, H.

    2015-10-15

    With lithographic patterning dimensions decreasing well below 50 nm, it is of high importance to understand metrology at such small scales. This paper presents results obtained from dense arrays of contact holes (CHs) with various Critical Dimension (CD) between 15 and 50 nm, as patterned in a chemically amplified resist using an ASML EUV scanner and measured at ASML and TNO. To determine the differences between various (local) CD metrology techniques, we conducted an experiment using optical scatterometry, CD-Scanning Electron Microscopy (CD-SEM), Helium ion Microscopy (HIM), and Atomic Force Microscopy (AFM). CD-SEM requires advanced beam scan strategies to mitigate sample charging; the other tools did not need that. We discuss the observed main similarities and differences between the various techniques. To this end, we assessed the spatial frequency content in the raw images for SEM, HIM, and AFM. HIM and AFM resolve the highest spatial frequencies, which are attributed to the more localized probe-sample interaction for these techniques. Furthermore, the SEM, HIM, and AFM waveforms are analyzed in detail. All techniques show good mutual correlation, albeit the reported CD values systematically differ significantly. HIM systematically reports a 25% higher CD uniformity number than CD-SEM for the same arrays of CHs, probably because HIM has a higher resolution than the CD-SEM used in this assessment. A significant speed boost for HIM and AFM is required before these techniques are to serve the demanding industrial metrology applications like optical critical dimension and CD-SEM do nowadays.

  6. An Ultra-Violet Tolerant Wild-Type Strain of Melanin-Producing Bacillus thuringiensis

    PubMed Central

    Sansinenea, Estibaliz; Salazar, Francisco; Ramirez, Melanie; Ortiz, Aurelio

    2015-01-01

    Background: Bacillus thuringiensis is the most successful biological control agent used in agriculture, forestry and mosquito control. However, the insecticidal activity of the B. thuringiensis formulation is not very stable and rapidly loses its biological activity under field conditions, due to the ultraviolet radiation in sunlight. Melanin is known to absorb radiation therefore photo protection of B. thuringiensis based on melanin has been extensively studied. Objectives: The aim of this study was to find a wild type strain of naturally melanin-producing B. thuringiensis to avoid any mutation or manipulation that can affect the Cry protein content. Materials and Methods: Bacillus thuringiensis strains were isolated from soils of different States of Mexico and pigment extraction was followed by lowering the pH to 2 using 1N HCl. Pigment was characterized by some chemical tests based on its solubility, bleaching by H2O2 and flocculation with FeCl3, and using an Infrared (IR) spectrum. Ultraviolet (UV) irradiation experiment was performed to probe the melanin efficacy. Results: ELI52 strain of B. thuringiensis was confirmed to naturally produce melanin. The Cry protein analysis suggested that ELI52 is probably a B. thuringiensis subsp. israelensis strain with toxic activity against the Diptera order of insects. Ultra Violet protection efficacy of melanin was probed counting total viable colonies after UV radiation and comparing the results with the non-producing melanin strain L-DOPA (L-3, 4-dihydroxyphenylalanine) was also detected in the culture. ELI52 strain showed an antagonistic effect over some common bacteria from the environment. Conclusions: ELI52 wild-type strain of B. thuringiensis is a good bio-insecticide that produces melanin with UV-resistance that is probably toxic against the Diptera order of insects and can inhibit the growth of other environmental bacteria. PMID:26421136

  7. Two Types of Aurora on Mars as Observed by MAVEN's Imaging UltraViolet Spectrograph

    NASA Astrophysics Data System (ADS)

    Schneider, N. M.; Deighan, J.; Jain, S.; Stiepen, A.; Stewart, I. F.; Larson, D. E.; Mitchell, D. L.; Mazelle, C. X.; Lee, C.; Lillis, R. J.; Evans, J. S.; Brain, D. A.; Stevens, M. H.; McClintock, W. E.; Chaffin, M.; Crismani, M. M. J.; Holsclaw, G. M.; Lefèvre, F.; Lo, D.; Clarke, J. T.; Montmessin, F.; Jakosky, B. M.

    2015-12-01

    The Imaging UltraViolet Spectrograph (IUVS) on the MAVEN spacecraft has detected two distinct types of auroral emission on Mars. First, we report the discovery of a low altitude, diffuse aurora spanning much of Mars' northern hemisphere coincident with a solar energetic particle outburst. IUVS observed northerly latitudes during late December 2014, detecting auroral emission in virtually all nightside observations for ~5 days spanning virtually all geographic longitudes. The vertical profile showed emission down to ~70 km altitude (1 microbar), deeper than confirmed at any other planet. The onset and duration of emission coincide with the observed arrival of solar energetic particles up to 200 keV precipitating directly and deeply into the atmosphere. Preliminary modeling of the precipitation, energy deposition and spectral line emission yields good matches to the observations. These observations represent a new class of planetary auroras produced in the Martian middle atmosphere. Given minimal magnetic fields over most of the planet, Mars is likely to exhibit aurora more globally than Earth. Second, we confirm the existence of small patches of discrete aurora near crustal magnetic fields in Mars' southern hemisphere, as observed previously by SPICAM on Mars Express (Bertaux et al., Nature, 435, 790-794 (2005)). IUVS observed southern latitudes in July and August 2015, detecting discrete auroral emission in ~1% of suitable observations. Limb scans resolved both vertically and along-slit indicate this type of auroral emission was patchy on the scale of ~40 km, and located at higher altitudes ~140 km. The higher altitudes imply a lower energy of precipitating particles. The mix of spectral emissions also differed signficiantly from the discrete aurora, indicating different excitation and quenching processes. We will discuss the observed properties of the aurora and associated charged particle precipitation, as well as the broader implications of this high

  8. Two Types of Aurora on Mars as Observed by MAVEN's Imaging UltraViolet Spectrograph

    NASA Astrophysics Data System (ADS)

    Schneider, Nicholas M.; Deighan, J.; Jain, S. K.; Stiepen, A.; Larson, D.; Mitchell, D. L.; Lee, C. O.; Lillis, R.; Brain, D.; McClintock, W. E.; Chaffin, M. S.; Crismani, M.; Holsclaw, G. M.; Jakosky, B. M.; Mazelle, C.; Evans, J. S.; Stewart, A. I. F.; Stevens, M. H.; Clarke, J. T.; Montmessin, F.; Lefevre, F.; Lo, D.

    2015-11-01

    The Imaging UltraViolet Spectrograph (IUVS) on the MAVEN spacecraft has detected two distinct types of auroral emission on Mars. First, we report the discovery of a low altitude, diffuse aurora spanning much of Mars’ northern hemisphere coincident with a solar energetic particle outburst. IUVS observed northerly latitudes during late December 2014, detecting auroral emission in virtually all nightside observations for ~5 days spanning virtually all geographic longitudes. The vertical profile showed emission down to ~70 km altitude (1 microbar), deeper than confirmed at any other planet. The onset and duration of emission coincide with the observed arrival of solar energetic particles up to 200 keV precipitating directly and deeply into the atmosphere. Preliminary modeling of the precipitation, energy deposition and spectral line emission yields good matches to the observations. These observations represent a new class of planetary auroras produced in the Martian middle atmosphere. Given minimal magnetic fields over most of the planet, Mars is likely to exhibit aurora more globally than Earth.Second, we confirm the existence of small patches of discrete aurora near crustal magnetic fields in Mars' southern hemisphere, as observed previously by SPICAM on Mars Express (Bertaux et al., Nature, 435, 790-794 (2005)). IUVS observed southern latitudes in July and August 2015, detecting discrete auroral emission in ~1% of suitable observations. Limb scans resolved both vertically and along-slit indicate this type of auroral emission was patchy on the scale of ~40 km, and located at higher altitudes ~140 km. The higher altitudes imply a lower energy of precipitating particles. The mix of spectral emissions also differed signficiantly from the diffuse aurora, indicating different excitation and quenching processes.We will discuss the observed properties of the aurora and associated charged particle precipitation, as well as the broader implications of this high

  9. Urinary Concentrations of Benzophenone-Type Ultra Violet Light Filters and Semen Quality

    PubMed Central

    Buck Louis, Germaine M.; Chen, Zhen; Kim, Sungduk; Sapra, Katherine J.; Bae, Jisuk; Kannan, Kurunthachalam

    2015-01-01

    Objective To assess benzophenone-type ultra violet (UV) filter concentrations, chemicals used in sunscreen and personal care products, and semen endpoints. Design Cohort. Setting 16 counties in Michigan and Texas Participants 413 men provided semen and urine samples, 2005–2009. Five UV filters were quantified (ng/mL) in urine using liquid chromatography-triple-quadrupole mass spectrometry: BP-1 (2,4-dihydroxybenzophenone), BP-2 (2,2′,4,4′-tetrahydroxybenzophenone), BP-3 (2-hydroxy-4-methoxybenzophenone), BP-8 (2,2′-dihydroxy-4-methoxybenzophenone), and 4-OH-BP (4-hydroxybenzophenone). Using linear regression, beta coefficients (β) and 95% confidence intervals (CIs) for each chemical dichotomized at the 75th percentile and Box-Cox transformed semen endpoint were estimated, after adjusting for age, BMI, cotinine, season, and site. Interventions None. Main Outcome Measures 35 semen endpoints. Results BP-2 was associated with diminished sperm concentration (β=−0.74; 95% CI −1.41, −0.08), straight (β=−4.57; 95% CI −8.95, −0.18) and linear movement (β=−3.15; 95% CI −6.01, −0.30), more immature (β=0.38; 95% CI 0.15, 0.62) sperm, and a decreased percentage of other tail abnormalities (β=−0.16; 95% CI −0.31, −0.01). BP-8 was associated with decreased hypo-osmotic swelling (β=−2.57; 95% CI −4.86, −0.29) and higher acrosome area (β=1.14; 95% CI 0.01, 2.26). No associations were observed for BP-1, BP-3 or 4OH-BP. Conclusion The findings suggest that specific UV filters may be associated with some aspects of semen endpoints, but await future corroboration. PMID:26253817

  10. Parametric Evaluation of an Innovative Ultra-Violet PhotocatalyticOxidation (UVPCO) Air Cleaning Technology for Indoor Applications

    SciTech Connect

    Hodgson, Alfred T.; Sullivan, Douglas P.; Fisk, William J.

    2005-10-31

    An innovative Ultra-Violet Photocatalytic Oxidation (UVPCO) air cleaning technology employing a semitransparent catalyst coated on a semitransparent polymer substrate was evaluated to determine its effectiveness for treating mixtures of volatile organic compounds (VOCs) representative of indoor environments at low, indoor-relevant concentration levels. The experimental UVPCO contained four 30 by 30-cm honeycomb monoliths irradiated with nine UVA lamps arranged in three banks. A parametric evaluation of the effects of monolith thickness, air flow rate through the device, UV power, and reactant concentrations in inlet air was conducted for the purpose of suggesting design improvements. The UVPCO was challenged with three mixtures of VOCs. A synthetic office mixture contained 27 VOCs commonly measured in office buildings. A building product mixture was created by combining sources including painted wallboard, composite wood products, carpet systems, and vinyl flooring. The third mixture contained formaldehyde and acetaldehyde. Steady state concentrations were produced in a classroom laboratory or a 20-m{sup 3} chamber. Air was drawn through the UVPCO, and single-pass conversion efficiencies were measured from replicate samples collected upstream and downstream of the reactor. Thirteen experiments were conducted in total. In this UVPCO employing a semitransparent monolith design, an increase in monolith thickness is expected to result in general increases in both reaction efficiencies and absolute reaction rates for VOCs oxidized by photocatalysis. The thickness of individual monolith panels was varied between 1.2 and 5 cm (5 to 20 cm total thickness) in experiments with the office mixture. VOC reaction efficiencies and rates increased with monolith thickness. However, the analysis of the relationship was confounded by high reaction efficiencies in all configurations for a number of compounds. These reaction efficiencies approached or exceeded 90% for alcohols, glycol

  11. Fabrication of SnO2-Reduced Graphite Oxide Monolayer-Ordered Porous Film Gas Sensor with Tunable Sensitivity through Ultra-Violet Light Irradiation

    NASA Astrophysics Data System (ADS)

    Xu, Shipu; Sun, Fengqiang; Yang, Shumin; Pan, Zizhao; Long, Jinfeng; Gu, Fenglong

    2015-03-01

    A new graphene-based composite structure, monolayer-ordered macroporous film composed of a layer of orderly arranged macropores, was reported. As an example, SnO2-reduced graphite oxide monolayer-ordered macroporous film was fabricated on a ceramic tube substrate under the irradiation of ultra-violet light (UV), by taking the latex microsphere two-dimensional colloid crystal as a template. Graphite oxide sheets dispersed in SnSO4 aqueous solution exhibited excellent affinity with template microspheres and were in situ incorporated into the pore walls during UV-induced growth of SnO2. The growing and the as-formed SnO2, just like other photocatalytic semiconductor, could be excited to produce electrons and holes under UV irradiation. Electrons reduced GO and holes adsorbed corresponding negative ions, which changed the properties of the composite film. This film was directly used as gas-sensor and was able to display high sensitivity in detecting ethanol gas. More interestingly, on the basis of SnO2-induced photochemical behaviours, this sensor demonstrated tunable sensitivity when UV irradiation time was controlled during the fabrication process and post in water, respectively. This study provides efficient ways of conducting the in situ fabrication of a semiconductor-reduced graphite oxide film device with uniform surface structure and controllable properties.

  12. Fabrication of SnO₂-reduced graphite oxide monolayer-ordered porous film gas sensor with tunable sensitivity through ultra-violet light irradiation.

    PubMed

    Xu, Shipu; Sun, Fengqiang; Yang, Shumin; Pan, Zizhao; Long, Jinfeng; Gu, Fenglong

    2015-01-01

    A new graphene-based composite structure, monolayer-ordered macroporous film composed of a layer of orderly arranged macropores, was reported. As an example, SnO2-reduced graphite oxide monolayer-ordered macroporous film was fabricated on a ceramic tube substrate under the irradiation of ultra-violet light (UV), by taking the latex microsphere two-dimensional colloid crystal as a template. Graphite oxide sheets dispersed in SnSO4 aqueous solution exhibited excellent affinity with template microspheres and were in situ incorporated into the pore walls during UV-induced growth of SnO2. The growing and the as-formed SnO2, just like other photocatalytic semiconductor, could be excited to produce electrons and holes under UV irradiation. Electrons reduced GO and holes adsorbed corresponding negative ions, which changed the properties of the composite film. This film was directly used as gas-sensor and was able to display high sensitivity in detecting ethanol gas. More interestingly, on the basis of SnO2-induced photochemical behaviours, this sensor demonstrated tunable sensitivity when UV irradiation time was controlled during the fabrication process and post in water, respectively. This study provides efficient ways of conducting the in situ fabrication of a semiconductor-reduced graphite oxide film device with uniform surface structure and controllable properties. PMID:25758292

  13. Ultra-violet radiation is responsible for the differences in global epidemiology of chickenpox and the evolution of varicella-zoster virus as man migrated out of Africa

    PubMed Central

    2011-01-01

    Background Of the eight human herpes viruses, varicella-zoster virus, which causes chickenpox and zoster, has a unique epidemiology. Primary infection is much less common in children in the tropics compared with temperate areas. This results in increased adult susceptibility causing outbreaks, for example in health-care workers migrating from tropical to temperate countries. The recent demonstration that there are different genotypes of varicella-zoster virus and their geographic segregation into tropical and temperate areas suggests a distinct, yet previously unconsidered climatic factor may be responsible for both the clinical and molecular epidemiological features of this virus infection. Presentation of the hypothesis Unlike other human herpes viruses, varicella-zoster virus does not require intimate contact for infection to occur indicating that transmission may be interrupted by a geographically restricted climatic factor. The factor with the largest difference between tropical and temperate zones is ultra-violet radiation. This could reduce the infectiousness of chickenpox cases by inactivating virus in vesicles, before or after rupture. This would explain decreased transmissibility in the tropics and why the peak chickenpox incidence in temperate zones occurs during winter and spring, when ultra-violet radiation is at its lowest. The evolution of geographically restricted genotypes is also explained by ultra-violet radiation driving natural selection of different virus genotypes with varying degrees of resistance to inactivation, tropical genotypes being the most resistant. Consequently, temperate viruses should be more sensitive to its effects. This is supported by the observation that temperate genotypes are found in the tropics only in specific circumstances, namely where ultra-violet radiation has either been excluded or significantly reduced in intensity. Testing the Hypothesis The hypothesis is testable by exposing different virus genotypes to ultra-violet

  14. Non-Contact and Non-Destructive Characterization of Shallow Implanted Silicon PN Junctions using Ultra-Violet Raman Spectroscopy

    NASA Astrophysics Data System (ADS)

    Fukumoto, Masashi; Hasuike, Noriyuki; Harima, Hiroshi; Yoshimoto, Masahiro; Yoo, Woo Sik

    2011-01-01

    Ultra-shallow boron implanted (B+ 1 keV 1×1015 cm-2) n-type Si wafers were prepared and characterized by four point probe, SIMS and 363.8 nm excited ultra-violet (UV) Raman spectroscopy before and after rapid thermal annealing (RTA). The penetration depth of 363.8 nm laser radiation in a backscattering Raman configuration, is approximately 5 nm. As junction depth increases from high temperature RTA, sheet resistance decreases. Raman peaks shift in the lower wavenumber direction and its full-width-at-half-maximum (FWHM) broadens. There is clear correlation between junction depth and Raman spectra data. UV Raman spectroscopy can be used as a very powerful non-contact, non-destructive, in-line characterization and monitoring technique for ultra-shallow junctions (USJs).

  15. Driving Extreme Efficiency to Market

    NASA Astrophysics Data System (ADS)

    Garbesi, Karina

    2014-03-01

    The rapid development of extremely energy efficient appliances and equipment is essential to curtail catastrophic climate disruption. This will require the on-going development of products that apply all best-practices and that take advantage of the synergies of hybridization and building integration. Beyond that, it requires the development of new disruptive technologies and concepts. To facilitate these goals, in 2011 the Lawrence Berkeley National Laboratory and the U.S. Department of Energy launched the Max Tech and Beyond Design Competition for Ultra-Low-Energy-Use Appliances and Equipment. Now in its third year, the competition supports faculty-lead student design teams at U.S. universities to develop and test new technology prototypes. This talk describes what the competition and the Max Tech Program are doing to drive such rapid technology progress and to facilitate the entry to the market of successful Max Tech prototypes. The talk also initiates a discussion of physicists' unique role in driving that technology progress faster and farther. Emerging Technologies, Building Technologies Office, U.S. Department of Energy.

  16. Ultra-violet Sensing Characteristic and Field Emission Properties of Vertically Aligned Aluminum Doped Zinc Oxide Nanorod Arrays

    SciTech Connect

    Mamat, M. H.; Malek, M. F.; Musa, M. Z.; Khusaimi, Z.; Rusop, M.

    2011-05-25

    Ultra-violet (UV) sensing behavior and field emission characteristic have been investigated on vertically aligned aluminum (Al) doped zinc oxide (ZnO) nanorod arrays prepared using sol-gel immersion method. Uniform and high coverage density of ZnO nanorod arrays have been successfully deposited on seeded-catalyst coated substrates. The synthesized nanorods have diameter sizes between 50 nm to 150 nm. The XRD spectra show Al doped ZnO nanorod array has high crystallinity properties with the dominancy of crystal growth along (002) plane or c-axis. UV photoresponse measurement indicates that Al doped ZnO nanorod array sensitively detects UV light as shown by conductance increment after UV illumination exposure. The nanorod array shows good field emission properties with low turn on field and threshold field at 2.1 V/{mu}m and 5.6 V/{mu}m, respectively. The result suggested that Al doped ZnO nanorod arrays prepared by low-cost sol-gel immersion method show promising result towards fabrication of multi applications especially in UV photoconductive sensor and field emission displays.

  17. Vacuum ultra-violet damage and damage mitigation for plasma processing of highly porous organosilicate glass dielectrics

    NASA Astrophysics Data System (ADS)

    de Marneffe, J.-F.; Zhang, L.; Heyne, M.; Lukaszewicz, M.; Porter, S. B.; Vajda, F.; Rutigliani, V.; el Otell, Z.; Krishtab, M.; Goodyear, A.; Cooke, M.; Verdonck, P.; Baklanov, M. R.

    2015-10-01

    Porous organosilicate glass thin films, with k-value 2.0, were exposed to 147 nm vacuum ultra-violet (VUV) photons emitted in a Xenon capacitive coupled plasma discharge. Strong methyl bond depletion was observed, concomitant with a significant increase of the bulk dielectric constant. This indicates that, besides reactive radical diffusion, photons emitted during plasma processing do impede dielectric properties and therefore need to be tackled appropriately during patterning and integration. The detrimental effect of VUV irradiation can be partly suppressed by stuffing the low-k porous matrix with proper sacrificial polymers showing high VUV absorption together with good thermal and VUV stability. In addition, the choice of an appropriate hard-mask, showing high VUV absorption, can minimize VUV damage. Particular processing conditions allow to minimize the fluence of photons to the substrate and lead to negligible VUV damage. For patterned structures, in order to reduce VUV damage in the bulk and on feature sidewalls, the combination of both pore stuffing/material densification and absorbing hard-mask is recommended, and/or the use of low VUV-emitting plasma discharge.

  18. Vacuum ultra-violet damage and damage mitigation for plasma processing of highly porous organosilicate glass dielectrics

    SciTech Connect

    Marneffe, J.-F. de Lukaszewicz, M.; Porter, S. B.; Vajda, F.; Rutigliani, V.; Verdonck, P.; Baklanov, M. R.; Zhang, L.; Heyne, M.; El Otell, Z.; Krishtab, M.; Goodyear, A.; Cooke, M.

    2015-10-07

    Porous organosilicate glass thin films, with k-value 2.0, were exposed to 147 nm vacuum ultra-violet (VUV) photons emitted in a Xenon capacitive coupled plasma discharge. Strong methyl bond depletion was observed, concomitant with a significant increase of the bulk dielectric constant. This indicates that, besides reactive radical diffusion, photons emitted during plasma processing do impede dielectric properties and therefore need to be tackled appropriately during patterning and integration. The detrimental effect of VUV irradiation can be partly suppressed by stuffing the low-k porous matrix with proper sacrificial polymers showing high VUV absorption together with good thermal and VUV stability. In addition, the choice of an appropriate hard-mask, showing high VUV absorption, can minimize VUV damage. Particular processing conditions allow to minimize the fluence of photons to the substrate and lead to negligible VUV damage. For patterned structures, in order to reduce VUV damage in the bulk and on feature sidewalls, the combination of both pore stuffing/material densification and absorbing hard-mask is recommended, and/or the use of low VUV-emitting plasma discharge.

  19. The effects of welding parameters on ultra-violet light emissions, ozone and CrVI formation in MIG welding.

    PubMed

    Dennis, J H; Mortazavi, S B; French, M J; Hewitt, P J; Redding, C R

    1997-01-01

    This paper describes the relationships between ultra-violet emission, ozone generation and CrVI production in MIG welding which were measured as a function of shield gas flow rate, welding voltage, electrode stick-out and shield gas composition using an automatic welding rig that permitted MIG welding under reproducible conditions. The experimental results are interpreted in terms of the physico-chemical processes occurring in the micro- and macro-environments of the arc as part of research into process modification to reduce occupational exposure to ozone and CrVI production rates in MIG welding. We believe the techniques described here, and in particular the use of what we have termed u.v.-ozone measurements, will prove useful in further study of ozone generation and CrVI formation and may be applied in the investigation of engineering control of occupational exposure in MIG and other welding process such as Manual Metal Arc (MMA) and Tungsten Inert Gas (TIG). PMID:9072953

  20. The effects of welding parameters on ultra-violet light emissions, ozone and CrVI formation in MIG welding.

    PubMed

    Dennis, J H; Mortazavi, S B; French, M J; Hewitt, P J; Redding, C R

    1997-01-01

    This paper describes the relationships between ultra-violet emission, ozone generation and CrVI production in MIG welding which were measured as a function of shield gas flow rate, welding voltage, electrode stick-out and shield gas composition using an automatic welding rig that permitted MIG welding under reproducible conditions. The experimental results are interpreted in terms of the physico-chemical processes occurring in the micro- and macro-environments of the arc as part of research into process modification to reduce occupational exposure to ozone and CrVI production rates in MIG welding. We believe the techniques described here, and in particular the use of what we have termed u.v.-ozone measurements, will prove useful in further study of ozone generation and CrVI formation and may be applied in the investigation of engineering control of occupational exposure in MIG and other welding process such as Manual Metal Arc (MMA) and Tungsten Inert Gas (TIG).

  1. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOEpatents

    Wolfe, Jesse D.

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  2. Specific ultra-violet absorbance as an indicator measurement of merucry sources in an Adirondack River basin

    USGS Publications Warehouse

    Burns, Douglas A.; Aiken, George R.; Bradley, Paul M.; Journey, Celeste A.; Schelker, Jakob

    2013-01-01

    The Adirondack region of New York has been identified as a hot spot where high methylmercury concentrations are found in surface waters and biota, yet mercury (Hg) concentrations vary widely in this region. We collected stream and groundwater samples for Hg and organic carbon analyses across the upper Hudson River, a 493 km2 basin in the central Adirondacks to evaluate and model the sources of variation in filtered total Hg (FTHg) concentrations. Variability in FTHg concentrations during the growing seasons (May-Oct) of 2007-2009 in Fishing Brook, a 66-km2 sub-basin, was better explained by specific ultra-violet absorbance at 254 nm (SUVA254), a measure of organic carbon aromaticity, than by dissolved organic carbon (DOC) concentrations, a commonly used Hg indicator. SUVA254 was a stronger predictor of FTHg concentrations during the growing season than during the dormant season. Multiple linear regression models that included SUVA254 values and DOC concentrations could explain 75 % of the variation in FTHg concentrations on an annual basis and 84 % during the growing season. A multiple linear regression landscape modeling approach applied to 27 synoptic sites across the upper Hudson basin found that higher SUVA254 values are associated with gentler slopes, and greater riparian area, and lower SUVA254 values are associated with an increasing influence of open water. We hypothesize that the strong Hg?SUVA254 relation in this basin reflects distinct patterns of FTHg and SUVA254 that are characteristic of source areas that control the mobilization of Hg to surface waters, and that the seasonal influence of these source areas varies in this heterogeneous basin landscape.

  3. Evaluating sanitization of toothbrushes using ultra violet rays and 0.2% chlorhexidine solution: A comparative clinical study

    PubMed Central

    Tomar, Poonam; Hongal, Sudheer; Saxena, Vrinda; Jain, Manish; Rana, Kuldeep; Ganavadiya, Rahul

    2014-01-01

    Background: Toothbrushes may play a significant role in plaque control. Toothbrushes should be correctly stored, disinfected and changed at regular intervals. Objective: The purpose of this study was to evaluate the efficacy of 0.2% chlorhexidine (CHX) gluconate solution and ultra violet (UV) toothbrush-sanitizer for toothbrush disinfection. Materials and Methods: Fresh tooth brushes were distributed to fifteen study subjects, who were selected randomly and who met the study criteria. All the study participants were asked to brush their teeth with the tooth brush provided. No special instructions were given regarding the brushing techniques. Toothbrushes were collected after 7 days. All tooth brushes were randomly allocated to three groups. Tooth brushes were subjected to microbial analysis and total bacterial count was assessed. Tooth brushes allocated to Group I were soaked in 2% CHX mouthwash for 12 h, Group II were kept in UV-light toothbrush holder for 7 min, and Group III were soaked in normal saline for 12 h. All the toothbrushes were subjected for microbial analysis and mean bacterial count was determined. Results: There was a statistically significant difference between mean colony-forming unit count pre-sanitization and post-sanitization in all the groups, using 0.2% CHX gluconate, UV rays and normal saline (P < 0.007). However, the mean bacterial count reduced drastically after the treatment with UV rays (P = 0.001). Conclusions: CHX, UV rays and normal saline are effective in a reduction of bacterial count on toothbrushes. UV rays treatment was more effective, when compared to CHX and normal saline. PMID:25538466

  4. A preliminary estimate of the EUVE cumulative distribution of exposure time on the unit sphere. [Extreme Ultra-Violet Explorer

    NASA Technical Reports Server (NTRS)

    Tang, C. C. H.

    1984-01-01

    A preliminary study of an all-sky coverage of the EUVE mission is given. Algorithms are provided to compute the exposure of the celestial sphere under the spinning telescopes, taking into account that during part of the exposure time the telescopes are blocked by the earth. The algorithms are used to give an estimate of exposure time at different ecliptic latitudes as a function of the angle of field of view of the telescope. Sample coverage patterns are also given for a 6-month mission.

  5. [Effect of extremely low frequency electromagnetic radiation and ultra-violet radiation on aggregation of thymocytes and erythrocytes].

    PubMed

    Roshchupkin, D I; Kramarenko, G G; Anosov, A K

    1996-01-01

    Electromagnetic radiation of superhigh frequencies (46.12 and 46.19 GHz, 0.3-1 mV/cm2) at an incident dose of about 12 kJ/m2 enhances the ability of isolated rabbit thymocytes for aggregation interaction with homologous erythrocytes. In the case of 46.19 GHz frequency, the stimulatory effect disappears as radiation dose in increased. A radiation of 46.12 GHz stimulates thymocytes also at high radiation doses. Superhigh-frequency radiation enhances the sensitivity of thymocytes to the damaging effect of UV radiation.

  6. Evaluation of Ultra-Violet Photocatalytic Oxidation for Indoor AirApplications

    SciTech Connect

    Hodgson, A.T.; Sullivan, D.P.; Fisk, W.J.

    2006-02-01

    Acceptable indoor air quality in office buildings may be achieved with less energy by combining effective air cleaning systems for volatile organic compounds (VOCs) with particle filtration then by relying solely on ventilation. For such applications, ultraviolet photocatalytic oxidation (UVPCO) systems are being developed for VOC destruction. An experimental evaluation of a UVPCO system is reported. The evaluation was unique in that it employed complex mixtures of VOCs commonly found in office buildings at realistically low concentrations. VOC conversion efficiencies varied over a broad range, usually exceeded 20%, and were as high as {approx}80%. Conversion efficiency generally diminished with increased air flow rate. Significant amounts of formaldehyde and acetaldehyde were produced due to incomplete mineralization. The results indicate that formaldehyde and acetaldehyde production rates may need to be reduced before such UVPCO systems can be deployed safely in occupied buildings.

  7. Quantitative Detection of Combustion Species using Ultra-Violet Diode Lasers

    NASA Technical Reports Server (NTRS)

    Pilgrim, J. S.; Peterson, K. A.

    2001-01-01

    Southwest Sciences is developing a new microgravity combustion diagnostic based on UV diode lasers. The instrument will allow absolute concentration measurements of combustion species on a variety of microgravity combustion platforms including the Space Station. Our approach uses newly available room temperature UV diode lasers, thereby keeping the instrument compact, rugged and energy efficient. The feasibility of the technique was demonstrated by measurement of CH radicals in laboratory flames. Further progress in fabrication technology of UV diode lasers at shorter wavelengths and higher power will result in detection of transient species in the deeper UV. High sensitivity detection of combustion radicals is provided with wavelength modulation absorption spectroscopy.

  8. Thermal annealing effects on ultra-violet luminescence properties of Gd doped AlN

    SciTech Connect

    Kita, Takashi; Ishizu, Yuta; Tsuji, Kazuma; Harada, Yukihiro; Chigi, Yoshitaka; Nishimoto, Tetsuro; Tanaka, Hiroyuki; Kobayashi, Mikihiro; Ishihara, Tsuguo; Izumi, Hirokazu

    2015-04-28

    We studied energy transfer from AlN to doped Gd{sup 3+} ions as a function of the post-thermal annealing temperature. Gd-doped AlN thin films were deposited on fused-silica substrates using a reactive radio-frequency magnetron sputtering technique. The film is a c-axis oriented polycrystal. The intra-orbital electron transition in Gd{sup 3+} showed an atomically sharp luminescence at 3.9 eV (318 nm). The photoluminescence (PL) excitation spectrum exhibited a resonant peak, indicating efficient energy transfer from the host AlN crystal to Gd{sup 3+} ions. The PL intensity increases approximately ten times by thermal annealing. The PL decay lifetime becomes long with annealing, and mid-gap luminescence relating to the crystal defects in AlN was also found to be reduced by annealing. These results suggest that energy dissipation of excited carriers in AlN was suppressed by annealing, and the efficiency of energy transfer into Gd{sup 3+} was improved.

  9. Formation and Fragmentation of Radical Peptide Anions: Insights from Vacuum Ultra Violet Spectroscopy

    NASA Astrophysics Data System (ADS)

    Brunet, Claire; Antoine, Rodolphe; Dugourd, Philippe; Canon, Francis; Giuliani, Alexandre; Nahon, Laurent

    2012-02-01

    We have studied the photodissociation of gas-phase deprotonated caerulein anions by vacuum ultraviolet (VUV) photons in the 4.5 to 20 eV range, as provided by the DESIRS beamline at the synchrotron radiation facility SOLEIL (France). Caerulein is a sulphated peptide with three aromatic residues and nine amide bonds. Electron loss is found to be the major relaxation channel at every photon energy. However, an increase in the fragmentation efficiency (neutral losses and peptide backbone cleavages) as a function of the energy is also observed. The oxidized ions, generated by electron photodetachment were further isolated and activated by collision (CID) in a MS3 scheme. The branching ratios of the different fragments observed by CID as a function of the initial VUV photon energy are found to be independent of the initial photon energy. Thus, there is no memory effect of the initial excitation energy on the fragmentation channels of the oxidized species on the time scale of our tandem MS experiment. We also report photofragment yields as a function of photon energy for doubly deprotonated caerulein ions, for both closed-shell ([M-2H]2-) non-radical ions and open-shell ([M-3H]2-•) radical ions. These latter ions are generated by electron photodetachment from [M-3H]3- precursor ions. The detachment yield increases monotonically with the energy with the appearance of several absorption bands. Spectra for radical and non-radical ions are quite similar in terms of observed bands; however, the VUV fragmentation yield is enhanced by the presence of a radical in caerulein peptides.

  10. Evaluation of Ultra-Violet Photocatalytic Oxidation (UVPCO) forIndoor Air Applications: Conversion of Volatile Organic Compounds at LowPart-per-Billion Concentrations

    SciTech Connect

    Hodgson, Alfred T.; Sullivan, Douglas P.; Fisk, William J.

    2005-09-30

    Efficient removal of indoor generated airborne particles and volatile organic compounds (VOCs) in office buildings and other large buildings may allow for a reduction in outdoor air supply rates with concomitant energy savings while still maintaining acceptable indoor air quality in these buildings. Ultra-Violet Photocatalytic Oxidation (UVPCO) air cleaners have the potential to achieve the necessary reductions in indoor VOC concentrations at relatively low cost. In this study, laboratory experiments were conducted with a scaled, prototype UVPCO device designed for use in a duct system. The experimental UVPCO contained two 30 by 30-cm honeycomb monoliths coated with titanium dioxide and 3% by weight tungsten oxide. The monoliths were irradiated with 12 UVC lamps arranged in four banks. The UVPCO was challenged with four mixtures of VOCs typical of mixtures encountered in indoor air. A synthetic office mixture contained 27 VOCs commonly measured in office buildings. A cleaning product mixture contained three cleaning products with high market shares. A building product mixture was created by combining sources including painted wallboard, composite wood products, carpet systems, and vinyl flooring. A fourth mixture contained formaldehyde and acetaldehyde. Steady-state concentrations were produced in a classroom laboratory or a 20-m{sup 3} environmental chamber. Air was drawn through the UVPCO, and single pass conversion efficiencies were measured from replicate air samples collected upstream and downstream of the reactor section. Concentrations of the mixtures were manipulated, with concentrations of individual VOCs mostly maintained below 10 ppb. Device flow rates were varied between 165 and 580 m{sup 3}/h. Production of formaldehyde, acetaldehyde, acetone, formic acid, and acetic acid as reaction products was investigated. Conversion efficiency data were generated for 48 individual VOCs or groups of closely related compounds. Alcohols and glycol ethers were the

  11. Diffractive element in extreme-UV lithography condenser

    DOEpatents

    Sweatt, William C.; Ray-Chaudhurl, Avijit K.

    2000-01-01

    Condensers having a mirror with a diffraction grating in projection lithography using extreme ultra-violet significantly enhances critical dimension control. The diffraction grating has the effect of smoothing the illumination at the camera's entrance pupil with minimum light loss. Modeling suggests that critical dimension control for 100 nm features can be improved from 3 nm to less than about 0.5 nm.

  12. Diffractive element in extreme-UV lithography condenser

    DOEpatents

    Sweatt, William C.; Ray-Chaudhuri, Avijit

    2001-01-01

    Condensers having a mirror with a diffraction grating in projection lithography using extreme ultra-violet significantly enhances critical dimension control. The diffraction grating has the effect of smoothing the illumination at the camera's entrance pupil with minimum light loss. Modeling suggests that critical dimension control for 100 nm features can be improved from 3 nm to less than about 0.5 nm.

  13. Ultra-violet absorption induced modifications in bulk and nanoscale electrical transport properties of Al-doped ZnO thin films

    SciTech Connect

    Kumar, Mohit; Basu, Tanmoy; Som, Tapobrata

    2015-08-07

    Using conductive atomic force microscopy and Kelvin probe force microscopy, we study local electrical transport properties in aluminum-doped zinc oxide (ZnO:Al or AZO) thin films. Current mapping shows a spatial variation in conductivity which corroborates well with the local mapping of donor concentration (∼10{sup 20 }cm{sup −3}). In addition, a strong enhancement in the local current at grains is observed after exposing the film to ultra-violet (UV) light which is attributed to persistent photocurrent. Further, it is shown that UV absorption gives a smooth conduction in AZO film which in turn gives rise to an improvement in the bulk photoresponsivity of an n-AZO/p-Si heterojunction diode. This finding is in contrast to the belief that UV absorption in an AZO layer leads to an optical loss for the underneath absorbing layer of a heterojunction solar cell.

  14. Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements

    SciTech Connect

    Niemi, K.; O'Connell, D.; Gans, T.; Oliveira, N. de; Joyeux, D.; Nahon, L.; Booth, J. P.

    2013-07-15

    Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N{sub 2}/O{sub 2} (4:1) admixtures. A maximum in the O-atom concentration of (9.1 {+-} 0.7) Multiplication-Sign 10{sup 20} m{sup -3} was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 {+-} 0.4) Multiplication-Sign 10{sup 19} m{sup -3} at 0.1 vol. %.

  15. Comparison of vacuum ultra-violet emission of Ar/CF4 and Ar/CF3I capacitively coupled plasmas

    NASA Astrophysics Data System (ADS)

    Zotovich, A.; Proshina, O.; el Otell, Z.; Lopaev, D.; Rakhimova, T.; Rakhimov, A.; de Marneffe, J.-F.; Baklanov, M. R.

    2016-10-01

    Spectra in the vacuum-ultra violet range (VUV, 30 nm-200 nm) as well as in the ultra-violet(UV) and visible ranges (UV+vis, 200 nm-800 nm) were measured from Ar/CF3I and Ar/CF4 discharges. The discharges were generated in an industrial 300 mm capacitively coupled plasma source with 27 MHz radio-frequency power. It was seen that the measured spectra were strongly modified. This is mainly due to absorption, especially by CF3I, and Ar self-trapping along the line of sight, towards the detector and in the plasma itself. The estimated unabsorbed VUV spectra were revealed from the spectra of mixtures with low fluorocarbon gas content by means of normalization with unabsorbed I* emission, at 206 nm, and CF2\\ast band (1B1(0,v‧,0){{\\to}1} A1(0,{{\\text{v}}\\prime \\prime} ,0)) emission between 230 nm and 430 nm. Absolute fluences of UV CF2\\ast emission were derived using hybrid 1-dimensional (1D) particle-in-cell (PIC) Monte-Carlo (MC) model calculations. Absolute calibration of the VUV emission was performed using these calculated values from the model, which has never been done previously for real etch conditions in an industrial chamber. It was seen that the argon resonant lines play a significant role in the VUV spectra. These lines are dominant in the case of etching recipes close to the standard ones. The restored unabsorbed spectra confirm that replacement of conventional CF4 etchant gas with CF3I in low-k etching recipes leads to an increase in the overall VUV emission intensity. However, emission from Ar exhibited the most intense peaks. Damage to low-k SiCOH glasses by the estimated VUV was calculated for blanket samples with pristine k-value of 2.2. The calculations were then compared with Fourier transform infrared (FTIR) data for samples exposed to the similar experimental conditions in the same reactor. It was shown that Ar emission plays the most significant role in VUV-induced damage.

  16. Warm dark matter via ultra-violet freeze-in: reheating temperature and non-thermal distribution for fermionic Higgs portal dark matter

    NASA Astrophysics Data System (ADS)

    McDonald, John

    2016-08-01

    Warm dark matter (WDM) of order keV mass may be able to resolve the disagreement between structure formation in cold dark matter simulations and observations. The detailed properties of WDM will depend upon its energy distribution, in particular how it deviates from the thermal distribution usually assumed in WDM simulations. Here we focus on WDM production via the Ultra-Violet (UV) freeze-in mechanism, for the case of fermionic Higgs portal dark matter ψ produced via the portal interaction bar psiψH†H/Λ. We introduce a new method to simplify the computation of the non-thermal energy distribution of dark matter from freeze-in. We show that the non-thermal energy distribution from UV freeze-in is hotter than the corresponding thermal distribution and has the form of a Bose-Einstein distribution with a non-thermal normalization. The resulting range of dark matter fermion mass consistent with observations is 5–7 keV. The reheating temperature must satisfy TR gtrsim 120 GeV in order to account for the observed dark matter density when mψ ≈ 5 keV, where the lower bound on TR corresponds to the limit where the fermion mass is entirely due to electroweak symmetry breaking via the portal interaction. The corresponding bound on the interaction scale is Λ gtrsim 6.0 × 109 GeV.

  17. Electro-spraying and ultra-violet light curing of polydimethylsiloxane to fabricate thin films for low-voltage dielectric elastomer actuators

    NASA Astrophysics Data System (ADS)

    Weiss, Florian M.; Kovacs, Gabor; Töpper, Tino; Osmani, Bekim; Leung, Vanessa Y. F.; Müller, Bert

    2016-04-01

    Currently, dielectric elastomer actuators (DEA) are mainly based on micrometer-thin polymer films and require operating voltages of several hundred volts. In medical applications, however, voltages as low as a few tens of volts are required. To this end, we prepared nanometer-thin dielectric elastomer layers. It is demonstrated that alternating current, electro-spray deposition allows for the fabrication of homogenous, flat, nanometer-thin polydimethylsiloxane (PDMS) films. The growth of the PDMS with average number molecular weights ranging from 800 to 62,700 g/mol, at a constant flow rate of 267 nL/s, was in situ monitored by means of spectroscopic ellipsometry. The Cauchy layer model used for data interpretation may only be applied to flat PDMS layers. Thus, in the present study the droplet morphology was also determined by atomic force microscopy. Spectroscopic ellipsometry does allow for the qualitative determination of the thin film morphology. However, for high molecular weight polymers the precise measurement during deposition is challenging. Independent of the molecular weight, the roughness of the deposited PDMS films considerably smoothens during the ultra-violet radiation treatment. After curing, the electro-sprayed nanometer-thin PDMS films are homogeneous enough to qualify for the fabrication of low-voltage DEA.

  18. Potentiating antilymphoma efficacy of chemotherapy using a liposome for integration of CD20 targeting, ultra-violet irradiation polymerizing, and controlled drug delivery

    NASA Astrophysics Data System (ADS)

    Wu, Cong; Li, Huafei; Zhao, He; Zhang, Weiwei; Chen, Yan; Yue, Zhanyi; Lu, Qiong; Wan, Yuxiang; Tian, Xiaoyu; Deng, Anmei

    2014-08-01

    Unlike most malignancies, chemotherapy but not surgery plays the most important role in treating non-Hodgkin lymphoma (NHL). Currently, liposomes have been widely used to encapsulate chemotherapeutic drugs in treating solid tumors. However, higher in vivo stability owns a much more important position for excellent antitumor efficacy in treating hematological malignancies. In this study, we finely fabricated a rituximab Fab fragment-decorated liposome based on 1,2-bis(10,12-tricosadiynoyl)-sn-glycero-3-phosphocholine (DC8,9PC), which can form intermolecular cross-linking through the diacetylenic group by ultra-violet (UV) irradiation. Our experimental results demonstrated that after the UV irradiation, the liposomes exhibit better serum stability and slower drug release with a decreased mean diameter of approximately 285 nm. The cellular uptake of adriamycin (ADR) by this Fab-navigated liposome was about four times of free drugs. Cytotoxicity assays against CD20+ lymphoma cells showed that the half maximal (50%) inhibitory concentration (IC50) of ADR-loaded immunoliposome was only one fourth of free ADR at the same condition. In vivo studies were evaluated in lymphoma-bearing SCID mice. With the high serum stability, finely regulated structure, active targeting strategy via antigen-antibody reaction and passive targeting strategy via enhanced permeability and retention (EPR) effect, our liposome exhibits durable and potent antitumor activities both in the disseminated and localized human NHL xeno-transplant models.

  19. Warm dark matter via ultra-violet freeze-in: reheating temperature and non-thermal distribution for fermionic Higgs portal dark matter

    NASA Astrophysics Data System (ADS)

    McDonald, John

    2016-08-01

    Warm dark matter (WDM) of order keV mass may be able to resolve the disagreement between structure formation in cold dark matter simulations and observations. The detailed properties of WDM will depend upon its energy distribution, in particular how it deviates from the thermal distribution usually assumed in WDM simulations. Here we focus on WDM production via the Ultra-Violet (UV) freeze-in mechanism, for the case of fermionic Higgs portal dark matter ψ produced via the portal interaction bar psiψH†H/Λ. We introduce a new method to simplify the computation of the non-thermal energy distribution of dark matter from freeze-in. We show that the non-thermal energy distribution from UV freeze-in is hotter than the corresponding thermal distribution and has the form of a Bose-Einstein distribution with a non-thermal normalization. The resulting range of dark matter fermion mass consistent with observations is 5-7 keV. The reheating temperature must satisfy TR gtrsim 120 GeV in order to account for the observed dark matter density when mψ ≈ 5 keV, where the lower bound on TR corresponds to the limit where the fermion mass is entirely due to electroweak symmetry breaking via the portal interaction. The corresponding bound on the interaction scale is Λ gtrsim 6.0 × 109 GeV.

  20. Determination of toxic cyclic heptapeptides by liquid chromatography with detection using ultra-violet, protein phosphatase assay and tandem mass spectrometry.

    PubMed

    Ortea, Paloma Muñiz; Allis, Orla; Healy, Brendan M; Lehane, Mary; Ní Shuilleabháin, Aine; Furey, Ambrose; James, Kevin J

    2004-06-01

    Microcystins, toxic cyclic heptapeptides and nodularin-R, a toxic cyclic pentapeptide, were determined using liquid chromatography (LC) with detection using photo-diode array ultra-violet (PDA-UV) and protein phosphatase (PP) assay. Positive fractions were analysed for toxins using collision-induced dissociation (CID) and tandem MS/MS experiments which were carried out simultaneously using electrospray ion-trap instrumentation. Reversed-phase liquid chromatography (LC) using an acetonitrile/water gradient was used for the LC-MS(2) determination of six microcystins standards and nodularin. The molecular related ion species, [M+H](+)([M+2H](2+) in the case of MC-RR), were used as the precursor ions for MS(2) experiments. Optimum calibration and reproducibility data were obtained for MC-LR using LC-MS(2); 0.1-5.0 microg/ml, r2 = 0.992 (n = 3); % RSD < or =7.3 at 0.25 microg MC-LR/ml (n = 3). The detection limit (S/N = 3) was better than 0.1 ng. Water samples for microcystin analysis were first screened using protein phosphatase (PP) assays and positives were concentrated using C-18 solid-phase extraction. The developed method was applied to examine a lake in Ireland contaminated by Microcystis sp. and MC-LR and MC-LA were identified.

  1. Strongly Time-Variable Ultra-Violet Metal Line Emission from the Circum-Galactic Medium of High-Redshift Galaxies

    NASA Astrophysics Data System (ADS)

    Sravan, Niharika; Faucher-Giguère, Claude-André; van de Voort, Freeke; Kereš, Dušan; Muratov, Alexander L.; Hopkins, Philip F.; Feldmann, Robert; Quataert, Eliot; Murray, Norman

    2016-08-01

    We use cosmological simulations from the Feedback In Realistic Environments (FIRE) project, which implement a comprehensive set of stellar feedback processes, to study ultra-violet (UV) metal line emission from the circum-galactic medium of high-redshift (z = 2 - 4) galaxies. Our simulations cover the halo mass range Mh ˜ 2 × 1011 - 8.5 × 1012 M⊙ at z = 2, representative of Lyman break galaxies. Of the transitions we analyze, the low-ionization C III (977 Å) and Si III (1207 Å) emission lines are the most luminous, with C IV (1548 Å) and Si IV (1394 Å) also showing interesting spatially-extended structures. The more massive halos are on average more UV-luminous. The UV metal line emission from galactic halos in our simulations arises primarily from collisionally ionized gas and is strongly time variable, with peak-to-trough variations of up to ˜2 dex. The peaks of UV metal line luminosity correspond closely to massive and energetic mass outflow events, which follow bursts of star formation and inject sufficient energy into galactic halos to power the metal line emission. The strong time variability implies that even some relatively low-mass halos may be detectable. Conversely, flux-limited samples will be biased toward halos whose central galaxy has recently experienced a strong burst of star formation. Spatially-extended UV metal line emission around high-redshift galaxies should be detectable by current and upcoming integral field spectrographs such as the Multi Unit Spectroscopic Explorer (MUSE) on the Very Large Telescope and Keck Cosmic Web Imager (KCWI).

  2. Simultaneous Determination of Six Benzodiazepines in Spiked Soft Drinks by High Performance Liquid Chromatography with Ultra Violet Detection (HPLC-UV).

    PubMed

    Soltaninejad, Kambiz; Karimi, Mohammad; Nateghi, Alireza; Daraei, Bahram

    2016-01-01

    A high performance liquid chromatographic method with ultra violet detection for simultaneous analysis of six benzodiazepines (BZDs) (chlordiazepoxide, diazepam, clonazepam, midazolam , flurazpam, and lorazepam) has been developed for forensic screening of adulterated non-alcoholic drinks. Samples were analyzed after a simple procedure for preparation using pH adjustment and filtering. Isocratic elution on a C18 column (250mm × 4.6 mm, 5μm) in the temperature 45ºC with a mobile phase consisting of 15mM phosphate buffer: methanol (50:50 v/v) at a flow rate 1.4 mL/min has been done. The column eluent was monitored with a UV detector at 245 nm. This allowed a rapid detection and identification as well as quantization of the eluting peaks. Calibration curves for all drugs in the range of 0.5- 10 µg/ mL that all the linear regression and has more than 0.996. Recovery rates for the BZDs were in the range 93.7- 108.7%. The limits of detection were calculated between 0.01- 0.02 µg/ mL. Also, the limits of quantification were 0.03- 0.05 µg/mL. Within-day and between -day coefficient of variation for all BZDs at all concentrations in the range of 0.45 - 7.69 % was calculated. The procedure can provide a simple, sensitive and fast method for the screening of six BZDs in adulterated soft drinks in forensic analysis. PMID:27642316

  3. Simultaneous Determination of Six Benzodiazepines in Spiked Soft Drinks by High Performance Liquid Chromatography with Ultra Violet Detection (HPLC-UV).

    PubMed

    Soltaninejad, Kambiz; Karimi, Mohammad; Nateghi, Alireza; Daraei, Bahram

    2016-01-01

    A high performance liquid chromatographic method with ultra violet detection for simultaneous analysis of six benzodiazepines (BZDs) (chlordiazepoxide, diazepam, clonazepam, midazolam , flurazpam, and lorazepam) has been developed for forensic screening of adulterated non-alcoholic drinks. Samples were analyzed after a simple procedure for preparation using pH adjustment and filtering. Isocratic elution on a C18 column (250mm × 4.6 mm, 5μm) in the temperature 45ºC with a mobile phase consisting of 15mM phosphate buffer: methanol (50:50 v/v) at a flow rate 1.4 mL/min has been done. The column eluent was monitored with a UV detector at 245 nm. This allowed a rapid detection and identification as well as quantization of the eluting peaks. Calibration curves for all drugs in the range of 0.5- 10 µg/ mL that all the linear regression and has more than 0.996. Recovery rates for the BZDs were in the range 93.7- 108.7%. The limits of detection were calculated between 0.01- 0.02 µg/ mL. Also, the limits of quantification were 0.03- 0.05 µg/mL. Within-day and between -day coefficient of variation for all BZDs at all concentrations in the range of 0.45 - 7.69 % was calculated. The procedure can provide a simple, sensitive and fast method for the screening of six BZDs in adulterated soft drinks in forensic analysis.

  4. Simultaneous Determination of Six Benzodiazepines in Spiked Soft Drinks by High Performance Liquid Chromatography with Ultra Violet Detection (HPLC-UV)

    PubMed Central

    Soltaninejad, Kambiz; Karimi, Mohammad; Nateghi, Alireza; Daraei, Bahram

    2016-01-01

    A high performance liquid chromatographic method with ultra violet detection for simultaneous analysis of six benzodiazepines (BZDs) (chlordiazepoxide, diazepam, clonazepam, midazolam , flurazpam, and lorazepam) has been developed for forensic screening of adulterated non-alcoholic drinks. Samples were analyzed after a simple procedure for preparation using pH adjustment and filtering. Isocratic elution on a C18 column (250mm × 4.6 mm, 5μm) in the temperature 45ºC with a mobile phase consisting of 15mM phosphate buffer: methanol (50:50 v/v) at a flow rate 1.4 mL/min has been done. The column eluent was monitored with a UV detector at 245 nm. This allowed a rapid detection and identification as well as quantization of the eluting peaks. Calibration curves for all drugs in the range of 0.5- 10 µg/ mL that all the linear regression and has more than 0.996. Recovery rates for the BZDs were in the range 93.7- 108.7%. The limits of detection were calculated between 0.01- 0.02 µg/ mL. Also, the limits of quantification were 0.03- 0.05 µg/mL. Within-day and between -day coefficient of variation for all BZDs at all concentrations in the range of 0.45 - 7.69 % was calculated. The procedure can provide a simple, sensitive and fast method for the screening of six BZDs in adulterated soft drinks in forensic analysis. PMID:27642316

  5. Pigmentation in Drosophila melanogaster reaches its maximum in Ethiopia and correlates most strongly with ultra-violet radiation in sub-Saharan Africa

    PubMed Central

    2014-01-01

    Background Pigmentation has a long history of investigation in evolutionary biology. In Drosophila melanogaster, latitudinal and altitudinal clines have been found but their underlying causes remain unclear. Moreover, most studies were conducted on cosmopolitan populations which have a relatively low level of genetic structure and diversity compared to sub-Saharan African populations. We investigated: 1) the correlation between pigmentation traits within and between the thorax and the fourth abdominal segment, and 2) their associations with different geographical and ecological variables, using 710 lines belonging to 30 sub-Saharan and cosmopolitan populations. Results Pigmentation clines substantially differed between sub-Saharan and cosmopolitan populations. While positive correlations with latitude have previously been described in Europe, India and Australia, in agreement with Bogert's rule or the thermal melanism hypothesis, we found a significant negative correlation in Africa. This correlation persisted even after correction for altitude, which in its turn showed a positive correlation with pigmentation independently from latitude. More importantly, we found that thoracic pigmentation reaches its maximal values in this species in high-altitude populations of Ethiopia (1,600-3,100 m). Ethiopian flies have a diffuse wide thoracic trident making the mesonotum and the head almost black, a phenotype that is absent from all other sub-Saharan or cosmopolitan populations including high-altitude flies from Peru (~3,400 m). Ecological analyses indicated that the variable most predictive of pigmentation in Africa, especially for the thorax, was ultra-violet (UV) intensity, consistent with the so-called Gloger's rule invoking a role of melanin in UV protection. Conclusion Our data suggest that different environmental factors may shape clinal variation in tropical and temperate regions, and may lead to the evolution of different degrees of melanism in different high

  6. Impact of BaB2O4 growth method on frequency conversion to the deep ultra-violet

    NASA Astrophysics Data System (ADS)

    Deyra, L.; Maillard, A.; Maillard, R.; Sangla, D.; Salin, F.; Balembois, F.; Kokh, A. E.; Georges, P.

    2015-12-01

    In this article, we report how the growth method used for barium beta-borate β-BaB2O4 (BBO) impacts its high power second harmonic generation properties in the deep-UV. We compared a BBO crystal grown by flux (Top Seeded Solution Growth or TSSG) and a BBO crystal grown by the Czochralski (CZ) method. We first characterized their transparency properties, then we measured their single-pass second harmonic conversion efficiencies with both a low average power and a high average power nanosecond pulsed lasers. We show that both crystals have comparable linear absorption and conversion efficiencies at low power, whereas in a high power experiment, the CZ-grown BBO yields higher conversion efficiency than the TSSG grown BBO. With a 30 W, 150 kHz, 8 ns green laser, the use of a CZ BBO led at best to a 40% increase in available average output power at 257 nm.

  7. Molecular beam epitaxy-grown wurtzite MgS thin films for solar-blind ultra-violet detection

    SciTech Connect

    Lai, Y. H.; He, Q. L.; Cheung, W. Y.; Lok, S. K.; Wong, K. S.; Sou, I. K.; Ho, S. K.; Tam, K. W.

    2013-04-29

    Molecular beam epitaxy grown MgS on GaAs(111)B substrate was resulted in wurtzite phase, as demonstrated by detailed structural characterizations. Phenomenological arguments were used to account for why wurtzite phase is preferred over zincblende phase or its most stable rocksalt phase. Results of photoresponse and reflectance measurements performed on wurtzite MgS photodiodes suggest a direct bandgap at around 5.1 eV. Their response peaks at 245 nm with quantum efficiency of 9.9% and enjoys rejection of more than three orders at 320 nm and close to five orders at longer wavelengths, proving the photodiodes highly competitive in solar-blind ultraviolet detection.

  8. Molecular beam epitaxy-grown wurtzite MgS thin films for solar-blind ultra-violet detection

    NASA Astrophysics Data System (ADS)

    Lai, Y. H.; He, Q. L.; Cheung, W. Y.; Lok, S. K.; Wong, K. S.; Ho, S. K.; Tam, K. W.; Sou, I. K.

    2013-04-01

    Molecular beam epitaxy grown MgS on GaAs(111)B substrate was resulted in wurtzite phase, as demonstrated by detailed structural characterizations. Phenomenological arguments were used to account for why wurtzite phase is preferred over zincblende phase or its most stable rocksalt phase. Results of photoresponse and reflectance measurements performed on wurtzite MgS photodiodes suggest a direct bandgap at around 5.1 eV. Their response peaks at 245 nm with quantum efficiency of 9.9% and enjoys rejection of more than three orders at 320 nm and close to five orders at longer wavelengths, proving the photodiodes highly competitive in solar-blind ultraviolet detection.

  9. The role of graphene formed on silver nanowire transparent conductive electrode in ultra-violet light emitting diodes.

    PubMed

    Seo, Tae Hoon; Lee, Seula; Min, Kyung Hyun; Chandramohan, S; Park, Ah Hyun; Lee, Gun Hee; Park, Min; Suh, Eun-Kyung; Kim, Myung Jong

    2016-01-01

    This paper reports a highly reliable transparent conductive electrode (TCE) that integrates silver nanowires (AgNWs) and high-quality graphene as a protecting layer. Graphene with minimized defects and large graphene domains has been successfully obtained through a facile two-step growth approach. Ultraviolet light emitting diodes (UV-LEDs) were fabricated with AgNWs or hybrid electrodes where AgNWs were combined with two-step grown graphene (A-2GE) or conventional one-step grown graphene (A-1GE). The device performance and reliability of the UV-LEDs with three different electrodes were compared. The A-2GE offered high figure of merit owing to the excellent UV transmittance and reduced sheet resistance. As a consequence, the UV-LEDs made with A-2GE demonstrated reduced forward voltage, enhanced electroluminescence (EL) intensity, and alleviated efficiency droop. The effects of joule heating and UV light illumination on the electrode stability were also studied. The present findings prove superior performance of the A-2GE under high current injection and continuous operation of UV LED, compared to other electrodes. From our observation, the A-2GE would be a reliable TCE for high power UV-LEDs. PMID:27387274

  10. The role of graphene formed on silver nanowire transparent conductive electrode in ultra-violet light emitting diodes

    NASA Astrophysics Data System (ADS)

    Seo, Tae Hoon; Lee, Seula; Min, Kyung Hyun; Chandramohan, S.; Park, Ah Hyun; Lee, Gun Hee; Park, Min; Suh, Eun-Kyung; Kim, Myung Jong

    2016-07-01

    This paper reports a highly reliable transparent conductive electrode (TCE) that integrates silver nanowires (AgNWs) and high-quality graphene as a protecting layer. Graphene with minimized defects and large graphene domains has been successfully obtained through a facile two-step growth approach. Ultraviolet light emitting diodes (UV-LEDs) were fabricated with AgNWs or hybrid electrodes where AgNWs were combined with two-step grown graphene (A-2GE) or conventional one-step grown graphene (A-1GE). The device performance and reliability of the UV-LEDs with three different electrodes were compared. The A-2GE offered high figure of merit owing to the excellent UV transmittance and reduced sheet resistance. As a consequence, the UV-LEDs made with A-2GE demonstrated reduced forward voltage, enhanced electroluminescence (EL) intensity, and alleviated efficiency droop. The effects of joule heating and UV light illumination on the electrode stability were also studied. The present findings prove superior performance of the A-2GE under high current injection and continuous operation of UV LED, compared to other electrodes. From our observation, the A-2GE would be a reliable TCE for high power UV-LEDs.

  11. The role of graphene formed on silver nanowire transparent conductive electrode in ultra-violet light emitting diodes.

    PubMed

    Seo, Tae Hoon; Lee, Seula; Min, Kyung Hyun; Chandramohan, S; Park, Ah Hyun; Lee, Gun Hee; Park, Min; Suh, Eun-Kyung; Kim, Myung Jong

    2016-07-08

    This paper reports a highly reliable transparent conductive electrode (TCE) that integrates silver nanowires (AgNWs) and high-quality graphene as a protecting layer. Graphene with minimized defects and large graphene domains has been successfully obtained through a facile two-step growth approach. Ultraviolet light emitting diodes (UV-LEDs) were fabricated with AgNWs or hybrid electrodes where AgNWs were combined with two-step grown graphene (A-2GE) or conventional one-step grown graphene (A-1GE). The device performance and reliability of the UV-LEDs with three different electrodes were compared. The A-2GE offered high figure of merit owing to the excellent UV transmittance and reduced sheet resistance. As a consequence, the UV-LEDs made with A-2GE demonstrated reduced forward voltage, enhanced electroluminescence (EL) intensity, and alleviated efficiency droop. The effects of joule heating and UV light illumination on the electrode stability were also studied. The present findings prove superior performance of the A-2GE under high current injection and continuous operation of UV LED, compared to other electrodes. From our observation, the A-2GE would be a reliable TCE for high power UV-LEDs.

  12. The role of graphene formed on silver nanowire transparent conductive electrode in ultra-violet light emitting diodes

    PubMed Central

    Seo, Tae Hoon; Lee, Seula; Min, Kyung Hyun; Chandramohan, S.; Park, Ah Hyun; Lee, Gun Hee; Park, Min; Suh, Eun-Kyung; Kim, Myung Jong

    2016-01-01

    This paper reports a highly reliable transparent conductive electrode (TCE) that integrates silver nanowires (AgNWs) and high-quality graphene as a protecting layer. Graphene with minimized defects and large graphene domains has been successfully obtained through a facile two-step growth approach. Ultraviolet light emitting diodes (UV-LEDs) were fabricated with AgNWs or hybrid electrodes where AgNWs were combined with two-step grown graphene (A-2GE) or conventional one-step grown graphene (A-1GE). The device performance and reliability of the UV-LEDs with three different electrodes were compared. The A-2GE offered high figure of merit owing to the excellent UV transmittance and reduced sheet resistance. As a consequence, the UV-LEDs made with A-2GE demonstrated reduced forward voltage, enhanced electroluminescence (EL) intensity, and alleviated efficiency droop. The effects of joule heating and UV light illumination on the electrode stability were also studied. The present findings prove superior performance of the A-2GE under high current injection and continuous operation of UV LED, compared to other electrodes. From our observation, the A-2GE would be a reliable TCE for high power UV-LEDs. PMID:27387274

  13. The investigation of O and N2 densities from the OSO-7 extreme UV data

    NASA Technical Reports Server (NTRS)

    1975-01-01

    The results of solar radiation observations in the extreme ultra-violet spectrum from 200 A to 600 A made by the OSO-7 Satellite were studied. The results of the influence of attenuation by the atmosphere in the 250 to 500 km altitude range are presented. Using published molecular absorption cross-sections at 304 A and 256 A, the Jaccia atmospheric model is validated, and shows that a mean exospheric of 1050 K is appropriate for the sunset data.

  14. Depth-resolved ultra-violet spectroscopic photo current-voltage measurements for the analysis of AlGaN/GaN high electron mobility transistor epilayer deposited on Si

    SciTech Connect

    Ozden, Burcu; Yang, Chungman; Tong, Fei; Khanal, Min P.; Mirkhani, Vahid; Sk, Mobbassar Hassan; Ahyi, Ayayi Claude; Park, Minseo

    2014-10-27

    We have demonstrated that the depth-dependent defect distribution of the deep level traps in the AlGaN/GaN high electron mobility transistor (HEMT) epi-structures can be analyzed by using the depth-resolved ultra-violet (UV) spectroscopic photo current-voltage (IV) (DR-UV-SPIV). It is of great importance to analyze deep level defects in the AlGaN/GaN HEMT structure, since it is recognized that deep level defects are the main source for causing current collapse phenomena leading to reduced device reliability. The AlGaN/GaN HEMT epi-layers were grown on a 6 in. Si wafer by metal-organic chemical vapor deposition. The DR-UV-SPIV measurement was performed using a monochromatized UV light illumination from a Xe lamp. The key strength of the DR-UV-SPIV is its ability to provide information on the depth-dependent electrically active defect distribution along the epi-layer growth direction. The DR-UV-SPIV data showed variations in the depth-dependent defect distribution across the wafer. As a result, rapid feedback on the depth-dependent electrical homogeneity of the electrically active defect distribution in the AlGaN/GaN HEMT epi-structure grown on a Si wafer with minimal sample preparation can be elucidated from the DR-UV-SPIV in combination with our previously demonstrated spectroscopic photo-IV measurement with the sub-bandgap excitation.

  15. High reflectance dielectric distributed Bragg reflectors for near ultra-violet planar microcavities: SiO2/HfO2 versus SiO2/SiNx

    NASA Astrophysics Data System (ADS)

    Réveret, F.; Bignet, L.; Zhigang, W.; Lafosse, X.; Patriarche, G.; Disseix, P.; Médard, F.; Mihailovic, M.; Leymarie, J.; Zúñiga-Pérez, J.; Bouchoule, S.

    2016-09-01

    SiO2/SiNx and SiO2/HfO2 distributed Bragg reflectors for the ultra-violet (λ = 360 nm-380 nm) are compared through their structural and optical properties. The SiO2/HfO2 system exhibits a lower interface roughness, higher reflectance, larger stop band, and lower penetration depth than SiO2/SiNx. A cavity quality factor of 3700 at about 360 nm is measured on a passive SiO2/HfO2-based planar microcavity. Compared with values obtained in the literature for the near UV range, the latter is rather large. Micro-reflectance measurements have been performed on a series of passive microcavities with increasing cavity thickness to determine the residual absorption in the SiO2 and HfO2 layers. Absorption coefficients of 30 (k = 0.86 × 10-4) and 160 cm-1 (k = 4.59 × 10-4) near λ ˜ 360 nm have been extracted for SiO2 and HfO2, respectively. Transfer-matrix simulations taking into account the residual absorption show that microcavity quality factors up to 8000 can be expected at 360-380 nm with this material system. Such values are well-suited for the fabrication of UV-vertical cavity surface emitting lasers or microcavity polariton lasers operating at room temperature.

  16. Detailed gas and diesel vehicle emissions: PTR-MS measurements of real-time VOC profiles and comprehensive characterization of primary emissions for IVOC, SVOC, and LVOC by gas chromatography with vacuum ultra-violet ionization mass spectrometry

    NASA Astrophysics Data System (ADS)

    Drozd, G.; Frodin, B.; Zhao, Y.; Franklin, J. P.; Cross, E. S.; Saleh, R.; Saliba, G.; Lambe, A. T.; Sardar, S.; Maldonado, H.; Russell, L. M.; Kroll, J. H.; Robinson, A. L.; Goldstein, A. H.

    2015-12-01

    Over the past fifteen years US vehicle emissions standards have dramatically improved, with the goal of reducing urban air pollution. Recent studies demonstrate secondary organic aerosol (SOA) to be the dominant contributor to urban organic aerosol, but controversy remains regarding the contributions of different vehicle types to SOA. Increased potency for SOA formation from non methane hydrocarbons (NMHC) from newer vehicles that meet tighter emission standards has also been observed. Both speciation and temporal resolution of vehicular emissions are critical for predicting SOA formation. The relative importance of diesel and gasoline emissions to SOA formation depends critically on speciation. Experiments were conducted at the California Air Resources Board Haagen-Smit Laboratory to better understand SOA formation for low, ultra-low, super ultra-low and partial zero emission vehicles (LEV, ULEV, SULEV, PZEV). Exhaust was sampled on filters and adsorbent tubes to measure intermediate-, semi-, and low-volatility NMHC (IVOC, SVOC, LVOC). A proton-transfer-reaction mass spectrometer (PTR-MS) measured volatile organics (VOC) emissions with high time-resolution. Analysis of filters and adsorbent tubes using gas chromatography with vacuum-ultra-violet ionization mass spectrometry provided unprecedented characterization of emissions according to degree of branching, number of cyclic rings, aromaticity, and molecular weight. ULEV vehicles show the composition distributions of primary particulate emissions peak for compounds in the SVOC range. PZEV vehicle emissions peak in the IVOC range. Diesel vehicles have up to ten times higher emissions than gasoline vehicles; their distributions have significant IVOC levels and peak in the SVOC/LVOC range. Our measurements are used to predict potential SOA formation by vehicle standard class and the relative SOA formation for diesel and gasoline vehicles. PTR-MS measurement show VOC emissions after cold start occur almost entirely

  17. Laser produced plasma for efficient extreme ultraviolet light sources

    SciTech Connect

    Donnelly, Tony; Cummins, Thomas; O' Gorman, Colm; Li Bowen; Harte, Colm S.; O'Reilly, Fergal; Sokell, Emma; Dunne, Padraig; O'Sullivan, Gerry

    2012-05-25

    Extreme ultraviolet emission from laser produced plasma and their relevance to EUV source development is discussed. The current state of the field for Sn LPP sources operating at 13.5 nm is described and initial results are given for EUV emission from CO{sub 2} laser irradiation of a bulk Sn target. A maximum conversion efficiency of 1.7% has been measured and the influence of the CO{sub 2} laser temporal profile on the CE is discussed. A double pulse irradiation scheme is shown to increase CE up to a maximum value of 2.1% for an optimum prepulse - pulse delay of 150 ns. The emergence of a new EUVL source wavelength at 6.7 nm based on Gd and Tb LPPs has been outlined. An initial experiment investigating picosecond laser irradiation as a means to produce strong 6.7 nm emission from a Gd{sub 2}O{sub 3} target has been performed and verified.

  18. Luminescent properties of Eu{sup 2+}-doped BaGdF{sub 5} glass ceramics a potential blue phosphor for ultra-violet light-emitting diode

    SciTech Connect

    Zhang, Weihuan; Zhang, Yuepin Ouyang, Shaoye; Zhang, Zhixiong; Wang, Qian; Xia, Haiping

    2015-01-14

    Eu{sup 2+} doped transparent oxyfluoride glass ceramics containing BaGdF{sub 5} nanocrystals were successfully fabricated by melt-quenching technique under a reductive atmosphere. The structure of the glass and glass ceramics were investigated by differential scanning calorimetry, X-ray diffraction (XRD), and transmission electron microscopy (TEM). The luminescent properties were investigated by transmission, excitation, and emission spectra. The decay time of the Gd{sup 3+} ions at 312 nm excited with 275 nm were also investigated. The results of XRD and TEM indicated the existence of BaGdF5 nanocrystals in the transparent glass ceramics. The excitation spectra of Eu{sup 2+} doped glass ceramics showed an excellent overlap with the main emission region of an ultraviolet light-emitting diode (UV-LED). Compared with the as-made glass, the emission of glass ceramics is much stronger by a factor of increasing energy transfer efficiency from Gd{sup 3+} to Eu{sup 2+} ions, the energy transfer efficiency from Gd{sup 3+} to Eu{sup 2+} ions was discussed. In addition, the chromaticity coordinates of glass and glass ceramics specimens were also discussed, which indicated that the Eu{sup 2+} doped BaGdF{sub 5} glass ceramics may be used as a potential blue-emitting phosphor for UV-LED.

  19. A comparative evaluation of disinfection effect of exposures to ultra-violet light and direct current glow discharge on Candida Albicans colonies coated over elastomeric impression material: An in vitro study

    PubMed Central

    Anand, Vijay

    2013-01-01

    Aim: The aim of our study is to compare the efficacy of ultra-violet light (U-V light) and direct current glow discharge in disinfecting Candida Albicans coated elastomeric impression material. Materials and Methods: Two hundred and forty samples of addition silicone material in the form of circular discs measuring (diameter-30 mm, thickness-3 mm) were prepared. Samples were divided into four groups namely A, B, C, D, with each group containing 60 samples. All samples in each group were sub grouped as follows for exposure time 15, 30, 60, 90, 120 and 180 s respectively. Group A samples were exposed to U-V light with 8 watts. Group B samples were exposed to U-V light with 16 watts. Group C samples were exposed to U-V light with 24 watts. Group D samples were exposed to direct current glow discharge. After exposure, the impression material was swabbed on sabourauds dextrose agar (SDA) plates and incubated at 37°C for 48 h. The total number of colonies indicating the number of C. Albicans that survived the direct current glow discharge and U-V light treatment was then determined using a microscope. Results and Conclusion: Group A samples exhibited proportionate decrease in the number of colonies with each greater time of exposure. Group B samples exhibited proportionate decrease in the number of colonies with each greater time of exposure. Group C samples exhibited total absence of C. Albicans colonies at 90 s exposure. In Group D samples there was a proportionate decrease in number of C. Albicans colonies with exposure to direct current glow discharge for more seconds. Hence, this study reveals that exposure to U-V light drastically reduced the C. Albicans colonies compared with exposure to direct current glow discharge. It was observed that with greater wattage of U-V light tube in U-V light unit chamber, greater decrease in colony count was observed in lesser time of exposure. PMID:23946583

  20. Ultra-Violet Induced Insulator Flashover

    SciTech Connect

    Javedani, J B; Houck, T L; Kelly, B T; Lahowe, D A; Shirk, M D; Goerz, D A

    2008-05-21

    Insulators are critical components in high-energy, pulsed power systems. It is known that the vacuum surface of the insulator will flashover when illuminated by ultraviolet (UV) radiation depending on the insulator material, insulator cone angle, applied voltage and insulator shot-history. A testbed comprised of an excimer laser (KrF, 248 nm, {approx} 2 MW/cm{sup 2}, 30 ns FWHM,), a vacuum chamber (low 1.0E-6 torr), and dc high voltage power supply (<60 kV) was assembled for insulator testing to measure the UV dose during a flashover event. Five in-house developed and calibrated fast D-Dot probes (>12 GHz, bandwidth) were embedded in the anode electrode underneath the insulator to determine the time of flashover with respect to UV arrival. A commercial energy meter were used to measure the UV fluence for each pulse. Four insulator materials High Density Polyethylene, Rexolite{reg_sign} 1400, Macor{trademark} and Mycalex with side-angles of 0, {+-}30, and {+-}45 degrees, 1.0 cm thick samples, were tested with a maximum UV fluence of 75 mJ/cm{sup 2} and at varying electrode charge (10 kV to 60 kV). This information clarified/corrected earlier published studies. A new phenomenon was observed related to the UV power level on flashover that as the UV pulse intensity was increased, the UV fluence on the insulator prior to flashover was also increased. This effect would bias the data towards higher minimum flashover fluence.

  1. UltraViolet freeze-in

    NASA Astrophysics Data System (ADS)

    Elahi, Fatemeh; Kolda, Christopher; Unwin, James

    2015-03-01

    If dark matter is thermally decoupled from the visible sector, the observed relic density can potentially be obtained via freeze-in production of dark matter. Typically in such models it is assumed that the dark matter is connected to the thermal bath through feeble renormalisable interactions. Here, rather, we consider the case in which the hidden and visible sectors are coupled only via non-renormalisable operators. This is arguably a more generic realisation of the dark matter freeze-in scenario, as it does not require the introduction of diminutive renormalisable couplings. We examine general aspects of freeze-in via non-renormalisable operators in a number of toy models and present several motivated implementations in the context of Beyond the Standard Model (BSM) physics. Specifically, we study models related to the Peccei-Quinn mechanism and Z ' portals.

  2. Intermediate Band Solar Cell with Extreme Broadband Spectrum Quantum Efficiency

    NASA Astrophysics Data System (ADS)

    Datas, A.; López, E.; Ramiro, I.; Antolín, E.; Martí, A.; Luque, A.; Tamaki, R.; Shoji, Y.; Sogabe, T.; Okada, Y.

    2015-04-01

    We report, for the first time, about an intermediate band solar cell implemented with InAs/AlGaAs quantum dots whose photoresponse expands from 250 to ˜6000 nm . To our knowledge, this is the broadest quantum efficiency reported to date for a solar cell and demonstrates that the intermediate band solar cell is capable of producing photocurrent when illuminated with photons whose energy equals the energy of the lowest band gap. We show experimental evidences indicating that this result is in agreement with the theory of the intermediate band solar cell, according to which the generation recombination between the intermediate band and the valence band makes this photocurrent detectable.

  3. Intermediate band solar cell with extreme broadband spectrum quantum efficiency.

    PubMed

    Datas, A; López, E; Ramiro, I; Antolín, E; Martí, A; Luque, A; Tamaki, R; Shoji, Y; Sogabe, T; Okada, Y

    2015-04-17

    We report, for the first time, about an intermediate band solar cell implemented with InAs/AlGaAs quantum dots whose photoresponse expands from 250 to ∼6000  nm. To our knowledge, this is the broadest quantum efficiency reported to date for a solar cell and demonstrates that the intermediate band solar cell is capable of producing photocurrent when illuminated with photons whose energy equals the energy of the lowest band gap. We show experimental evidence indicating that this result is in agreement with the theory of the intermediate band solar cell, according to which the generation recombination between the intermediate band and the valence band makes this photocurrent detectable. PMID:25933339

  4. Extreme ultraviolet quantum detection efficiency of rubidium bromide opaque photocathodes

    NASA Technical Reports Server (NTRS)

    Siegmund, Oswald H. W.; Gaines, Geoffrey A.

    1990-01-01

    Measurements are presented of the quantum detection efficiency (QDE) of three samples of RbBr photocathode layers over the 44-150-A wavelength range. The QDE of RbBr-coated microchannel plate (MCP) was measured using a back-to-back Z-stack MCP configuration in a detector with a wedge and strip position-sensitive anode, of the type described by Siegmund et al. (1984). To assess the stability of RbBr layer, the RbBr photocathode was exposed to air at about 30 percent humidity for 20 hr. It was found that the QDE values for the aged cathode were within the QDE measurement errors of the original values. A simple QDE model was developed, and it was found that its predictions are in accord with the QDE measurements.

  5. Intermediate band solar cell with extreme broadband spectrum quantum efficiency.

    PubMed

    Datas, A; López, E; Ramiro, I; Antolín, E; Martí, A; Luque, A; Tamaki, R; Shoji, Y; Sogabe, T; Okada, Y

    2015-04-17

    We report, for the first time, about an intermediate band solar cell implemented with InAs/AlGaAs quantum dots whose photoresponse expands from 250 to ∼6000  nm. To our knowledge, this is the broadest quantum efficiency reported to date for a solar cell and demonstrates that the intermediate band solar cell is capable of producing photocurrent when illuminated with photons whose energy equals the energy of the lowest band gap. We show experimental evidence indicating that this result is in agreement with the theory of the intermediate band solar cell, according to which the generation recombination between the intermediate band and the valence band makes this photocurrent detectable.

  6. Design, fabrication, and characterization of high-efficiency extreme ultraviolet diffusers

    SciTech Connect

    Naulleau, Patrick P.; Liddle, J. Alexander; Salmassi, Farhad; Anderson, Erik H.; Gullikson, Eric M.

    2004-02-19

    As the development of extreme ultraviolet (EUV) lithography progresses, interest grows in the extension of traditional optical components to the EUV regime. The strong absorption of EUV by most materials and its extremely short wavelength, however, makes it very difficult to implement many components that are commonplace in the longer wavelength regimes. One such example is the diffuser often implemented with ordinary ground glass in the visible light regime. Here we demonstrate the fabrication of reflective EUV diffusers with high efficiency within a controllable bandwidth. Using these techniques we have fabricated diffusers with efficiencies exceeding 10% within a moderate angular single-sided bandwidth of approximately 0.06 radians.

  7. Computation of reflected images from extreme ultraviolet masks

    NASA Astrophysics Data System (ADS)

    Bollepalli, Srinivas B.; Cerrina, Franco

    1999-06-01

    With EUV lithography emerging as a promising technology for semiconductor device fabrication with critical dimensions extreme ultra violet mask. In particular, we show the effects caused due to diffraction, non-uniformities in the multilayer stack due to substrate defects, and partial spatial coherence. Several simulation examples are presented.

  8. Method for high-precision multi-layered thin film deposition for deep and extreme ultraviolet mirrors

    DOEpatents

    Ruffner, Judith Alison

    1999-01-01

    A method for coating (flat or non-flat) optical substrates with high-reflectivity multi-layer coatings for use at Deep Ultra-Violet ("DUV") and Extreme Ultra-Violet ("EUV") wavelengths. The method results in a product with minimum feature sizes of less than 0.10-.mu.m for the shortest wavelength (13.4-nm). The present invention employs a computer-based modeling and deposition method to enable lateral and vertical thickness control by scanning the position of the substrate with respect to the sputter target during deposition. The thickness profile of the sputter targets is modeled before deposition and then an appropriate scanning algorithm is implemented to produce any desired, radially-symmetric thickness profile. The present invention offers the ability to predict and achieve a wide range of thickness profiles on flat or figured substrates, i.e., account for 1/R.sup.2 factor in a model, and the ability to predict and accommodate changes in deposition rate as a result of plasma geometry, i.e., over figured substrates.

  9. Method for high-precision multi-layered thin film deposition for deep and extreme ultraviolet mirrors

    DOEpatents

    Ruffner, J.A.

    1999-06-15

    A method for coating (flat or non-flat) optical substrates with high-reflectivity multi-layer coatings for use at Deep Ultra-Violet (DUV) and Extreme Ultra-Violet (EUV) wavelengths. The method results in a product with minimum feature sizes of less than 0.10 [micro]m for the shortest wavelength (13.4 nm). The present invention employs a computer-based modeling and deposition method to enable lateral and vertical thickness control by scanning the position of the substrate with respect to the sputter target during deposition. The thickness profile of the sputter targets is modeled before deposition and then an appropriate scanning algorithm is implemented to produce any desired, radially-symmetric thickness profile. The present invention offers the ability to predict and achieve a wide range of thickness profiles on flat or figured substrates, i.e., account for 1/R[sup 2] factor in a model, and the ability to predict and accommodate changes in deposition rate as a result of plasma geometry, i.e., over figured substrates. 15 figs.

  10. Extremely efficient indium-tin-oxide-free green phosphorescent organic light-emitting diodes.

    PubMed

    Cai, Min; Ye, Zhuo; Xiao, Teng; Liu, Rui; Chen, Ying; Mayer, Robert W; Biswas, Rana; Ho, Kai-Ming; Shinar, Ruth; Shinar, Joseph

    2012-08-16

    This paper demonstrates extremely efficient (η(P,max) = 118 lm W(-1) ) ITO-free green phosphorescent OLEDs (PHOLEDs) with multilayered, highly conductive poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) films as the anode. The efficiency is obtained without any outcoupling-enhancing structures and is 44% higher than the 82 lm W(-1) of similar optimized ITO-anode PHOLEDs. Detailed simulations show that this improvement is due largely to the intrinsically enhanced outcoupling that results from a weak microcavity effect. PMID:22786793

  11. Isolation of an extremely acidophilic and highly efficient strain Acidithiobacillus sp. for chalcopyrite bioleaching.

    PubMed

    Feng, Shoushuai; Yang, Hailin; Xin, Yu; Zhang, Ling; Kang, Wenliang; Wang, Wu

    2012-11-01

    An extremely acidophilic sulfur-oxidizing bacterium was isolated from an industrial-scale bioheap of the Zijinshan copper mine and was named ZJJN. A tuft of flagella and a layer of thick capsule outside the cell envelope were clearly observed under transmission electron microscopy (TEM), which might be closely related to the extremely acid-proof capacity of ZJJN cells in the bioleaching system; 16S ribosomal RNA (rRNA) phylogeny showed that the isolated strain was highly homologous to the genera of Acidithiobacillus. The optimum temperature of ZJJN was determined at 30 °C and pH at 1.0. It was capable of growth at even pH 0. Strain ZJJN can utilize reduced sulfur as an energy source but not with organics or ferrous ion. Strain ZJJN was sensitive to all antibiotics with different concentrations; when it showed a certain resistance to different concentrations of Cu(2+). In the mixed strains of ZJJN and A. ferrooxidans system (initial pH 1.0), the copper-leaching efficiency was up to 60.1 %, which was far higher than other systems. Scanning electron microscopy (SEM) analysis showed that less jarosite precipitation was produced in the most efficient system. The extremely acidophilic strain ZJJN would be of great potential in the application of chalcopyrite bioleaching.

  12. Recovery Act - CAREER: Sustainable Silicon -- Energy-Efficient VLSI Interconnect for Extreme-Scale Computing

    SciTech Connect

    Chiang, Patrick

    2014-01-31

    The research goal of this CAREER proposal is to develop energy-efficient, VLSI interconnect circuits and systems that will facilitate future massively-parallel, high-performance computing. Extreme-scale computing will exhibit massive parallelism on multiple vertical levels, from thou­ sands of computational units on a single processor to thousands of processors in a single data center. Unfortunately, the energy required to communicate between these units at every level (on­ chip, off-chip, off-rack) will be the critical limitation to energy efficiency. Therefore, the PI's career goal is to become a leading researcher in the design of energy-efficient VLSI interconnect for future computing systems.

  13. Cluster beam targets for laser plasma extreme ultraviolet and soft x-ray sources

    DOEpatents

    Kublak, Glenn D.; Richardson, Martin C. (CREOL

    1996-01-01

    Method and apparatus for producing extreme ultra violet (EUV) and soft x-ray radiation from an ultra-low debris plasma source are disclosed. Targets are produced by the free jet expansion of various gases through a temperature controlled nozzle to form molecular clusters. These target clusters are subsequently irradiated with commercially available lasers of moderate intensity (10.sup.11 -10.sup.12 watts/cm.sup.2) to produce a plasma radiating in the region of 0.5 to 100 nanometers. By appropriate adjustment of the experimental conditions the laser focus can be moved 10-30 mm from the nozzle thereby eliminating debris produced by plasma erosion of the nozzle.

  14. Extending the path for efficient extreme ultraviolet sources for advanced nanolithography

    SciTech Connect

    Sizyuk, Tatyana; Hassanein, Ahmed

    2015-09-15

    Developing efficient light sources for extreme ultraviolet (EUV) lithography is one of the most important problems of high volume manufacturing (HVM) of the next generation computer chips. Critical components of this technology are continued to face challenges in the demanding performance for HVM. Current investigations of EUV and beyond EUV (BEUV) community are focused on the dual-pulse laser produced plasma (LPP) using droplets of mass-limited targets. Two main objectives as well as challenges in the optimization of these light sources are related to enhancement of the conversion efficiency (CE) of the source and increase components lifetime of the collector optical system. These require significant experimental and computer simulation efforts. These requirements call for fine detail analysis of various plasma physics processes involved in laser target interactions and their effects on source optimization. We continued to enhance our comprehensive HEIGHTS simulation package and upgrade our CMUXE laboratories to study and optimize the efficiency of LPP sources. Integrated modeling and experimental research were done to both benchmark simulation results and to make projections and realistic predictions of the development path for powerful EUVL devices for HVM requirements. We continued the detail analysis of dual-pulse laser systems using various laser wavelengths and delay times between the two pulses. We showed that the efficiency of EUV sources can be improved utilizing the higher harmonics of Nd:YAG laser for the prepulse and the first harmonics for the main pulse, while still having lower efficiency than the combination involving CO{sub 2} laser in the range of parameters studied in this case. The differences in optimization process as well as in the source characteristics for two combinations of laser wavelengths were analyzed based on details of atomic and hydrodynamics processes during the evolving plasma plumes.

  15. Optimizing laser produced plasmas for efficient extreme ultraviolet and soft X-ray light sources

    SciTech Connect

    Sizyuk, Tatyana; Hassanein, Ahmed

    2014-08-15

    Photon sources produced by laser beams with moderate laser intensities, up to 10{sup 14 }W/cm{sup 2}, are being developed for many industrial applications. The performance requirements for high volume manufacture devices necessitate extensive experimental research supported by theoretical plasma analysis and modeling predictions. We simulated laser produced plasma sources currently being developed for several applications such as extreme ultraviolet lithography using 13.5% ± 1% nm bandwidth, possibly beyond extreme ultraviolet lithography using 6.× nm wavelengths, and water-window microscopy utilizing 2.48 nm (La-α) and 2.88 nm (He-α) emission. We comprehensively modeled plasma evolution from solid/liquid tin, gadolinium, and nitrogen targets as three promising materials for the above described sources, respectively. Results of our analysis for plasma characteristics during the entire course of plasma evolution showed the dependence of source conversion efficiency (CE), i.e., laser energy to photons at the desired wavelength, on plasma electron density gradient. Our results showed that utilizing laser intensities which produce hotter plasma than the optimum emission temperatures allows increasing CE for all considered sources that, however, restricted by the reabsorption processes around the main emission region and this restriction is especially actual for the 6.× nm sources.

  16. Load control and the provision of the efficiency of steam boilers equipped with an extremal governor

    NASA Astrophysics Data System (ADS)

    Sabanin, V. P.; Kormilitsyn, V. I.; Kostyk, V. I.; Smirnov, N. I.; Koroteev, A. V.; Repin, A. I.

    2014-12-01

    This paper presents an analysis of main problems of controlling small- and medium-size steam boilers. Noted are deficiencies of current normative and technical documents, as well as those of the traditional concept of the process of fuel firing, the methods for and algorithms of boiler control. There is established an approach to creation of such control systems in which a boiler is treated, as to control and load channels, as a nonlinear linked controlled objects. To control load and efficiency of a boiler, an universal schematic diagram is suggested that allows for the possibility of implementation in modern controllers of both known methods and a new method using an extremal governor, which would provide minimum fuel consumption at given thermal load of a boiler.

  17. Fluorescence efficiency and visible re-emission spectrum of tetraphenyl butadiene films at extreme ultraviolet wavelengths

    NASA Astrophysics Data System (ADS)

    Gehman, V. M.; Seibert, S. R.; Rielage, K.; Hime, A.; Sun, Y.; Mei, D.-M.; Maassen, J.; Moore, D.

    2011-10-01

    A large number of current and future experiments in neutrino and dark matter detection use the scintillation light from noble elements as a mechanism for measuring energy deposition. The scintillation light from these elements is produced in the extreme ultraviolet (EUV) range, from 60 to 200 nm. Currently, the most practical technique for observing light at these wavelengths is to surround the scintillation volume with a thin film of tetraphenyl butadiene (TPB) to act as a fluor. The TPB film absorbs EUV photons and re-emits visible photons, detectable with a variety of commercial photosensors. Here we present a measurement of the re-emission spectrum of TPB films when illuminated with 128, 160, 175, and 250 nm light. We also measure the fluorescence efficiency as a function of incident wavelength from 120 to 250 nm.

  18. Sensitivity calibration of an imaging extreme ultraviolet spectrometer-detector system for determining the efficiency of broadband extreme ultraviolet sources

    SciTech Connect

    Fuchs, S.; Roedel, C.; Bierbach, J.; Paz, A. E.; Foerster, E.; Paulus, G. G.; Krebs, M.; Haedrich, S.; Limpert, J.; Kuschel, S.; Wuensche, M.; Hilbert, V.; Zastrau, U.

    2013-02-15

    We report on the absolute sensitivity calibration of an extreme ultraviolet (XUV) spectrometer system that is frequently employed to study emission from short-pulse laser experiments. The XUV spectrometer, consisting of a toroidal mirror and a transmission grating, was characterized at a synchrotron source in respect of the ratio of the detected to the incident photon flux at photon energies ranging from 15.5 eV to 99 eV. The absolute calibration allows the determination of the XUV photon number emitted by laser-based XUV sources, e.g., high-harmonic generation from plasma surfaces or in gaseous media. We have demonstrated high-harmonic generation in gases and plasma surfaces providing 2.3 {mu}W and {mu}J per harmonic using the respective generation mechanisms.

  19. Physiological characteristics of the extreme thermophile Caldicellulosiruptor saccharolyticus: an efficient hydrogen cell factory

    PubMed Central

    2010-01-01

    Global concerns about climate changes and their association with the use of fossil fuels have accelerated research on biological fuel production. Biological hydrogen production from hemicellulose-containing waste is considered one of the promising avenues. A major economical issue for such a process, however, is the low substrate conversion efficiency. Interestingly, the extreme thermophilic bacterium Caldicellulosiruptor saccharolyticus can produce hydrogen from carbohydrate-rich substrates at yields close to the theoretical maximum of the dark fermentation process (i.e., 4 mol H2/mol hexose). The organism is able to ferment an array of mono-, di- and polysaccharides, and is relatively tolerant to high partial hydrogen pressures, making it a promising candidate for exploitation in a biohydrogen process. The behaviour of this Gram-positive bacterium bears all hallmarks of being adapted to an environment sparse in free sugars, which is further reflected in its low volumetric hydrogen productivity and low osmotolerance. These two properties need to be improved by at least a factor of 10 and 5, respectively, for a cost-effective industrial process. In this review, the physiological characteristics of C. saccharolyticus are analyzed in view of the requirements for an efficient hydrogen cell factory. A special emphasis is put on the tight regulation of hydrogen production in C. saccharolyticus by both redox and energy metabolism. Suggestions for strategies to overcome the current challenges facing the potential use of the organism in hydrogen production are also discussed. PMID:21092203

  20. An efficient pipeline wavefront phase recovery for the CAFADIS camera for extremely large telescopes.

    PubMed

    Magdaleno, Eduardo; Rodríguez, Manuel; Rodríguez-Ramos, José Manuel

    2010-01-01

    In this paper we show a fast, specialized hardware implementation of the wavefront phase recovery algorithm using the CAFADIS camera. The CAFADIS camera is a new plenoptic sensor patented by the Universidad de La Laguna (Canary Islands, Spain): international patent PCT/ES2007/000046 (WIPO publication number WO/2007/082975). It can simultaneously measure the wavefront phase and the distance to the light source in a real-time process. The pipeline algorithm is implemented using Field Programmable Gate Arrays (FPGA). These devices present architecture capable of handling the sensor output stream using a massively parallel approach and they are efficient enough to resolve several Adaptive Optics (AO) problems in Extremely Large Telescopes (ELTs) in terms of processing time requirements. The FPGA implementation of the wavefront phase recovery algorithm using the CAFADIS camera is based on the very fast computation of two dimensional fast Fourier Transforms (FFTs). Thus we have carried out a comparison between our very novel FPGA 2D-FFTa and other implementations. PMID:22315523

  1. An Efficient Pipeline Wavefront Phase Recovery for the CAFADIS Camera for Extremely Large Telescopes

    PubMed Central

    Magdaleno, Eduardo; Rodríguez, Manuel; Rodríguez-Ramos, José Manuel

    2010-01-01

    In this paper we show a fast, specialized hardware implementation of the wavefront phase recovery algorithm using the CAFADIS camera. The CAFADIS camera is a new plenoptic sensor patented by the Universidad de La Laguna (Canary Islands, Spain): international patent PCT/ES2007/000046 (WIPO publication number WO/2007/082975). It can simultaneously measure the wavefront phase and the distance to the light source in a real-time process. The pipeline algorithm is implemented using Field Programmable Gate Arrays (FPGA). These devices present architecture capable of handling the sensor output stream using a massively parallel approach and they are efficient enough to resolve several Adaptive Optics (AO) problems in Extremely Large Telescopes (ELTs) in terms of processing time requirements. The FPGA implementation of the wavefront phase recovery algorithm using the CAFADIS camera is based on the very fast computation of two dimensional fast Fourier Transforms (FFTs). Thus we have carried out a comparison between our very novel FPGA 2D-FFTa and other implementations. PMID:22315523

  2. An efficient pipeline wavefront phase recovery for the CAFADIS camera for extremely large telescopes.

    PubMed

    Magdaleno, Eduardo; Rodríguez, Manuel; Rodríguez-Ramos, José Manuel

    2010-01-01

    In this paper we show a fast, specialized hardware implementation of the wavefront phase recovery algorithm using the CAFADIS camera. The CAFADIS camera is a new plenoptic sensor patented by the Universidad de La Laguna (Canary Islands, Spain): international patent PCT/ES2007/000046 (WIPO publication number WO/2007/082975). It can simultaneously measure the wavefront phase and the distance to the light source in a real-time process. The pipeline algorithm is implemented using Field Programmable Gate Arrays (FPGA). These devices present architecture capable of handling the sensor output stream using a massively parallel approach and they are efficient enough to resolve several Adaptive Optics (AO) problems in Extremely Large Telescopes (ELTs) in terms of processing time requirements. The FPGA implementation of the wavefront phase recovery algorithm using the CAFADIS camera is based on the very fast computation of two dimensional fast Fourier Transforms (FFTs). Thus we have carried out a comparison between our very novel FPGA 2D-FFTa and other implementations.

  3. CHARACTERIZATION OF RELATIVE SENSITIVITY OF AMPHIBIANS TO ULTRA VIOLET RADIATION

    EPA Science Inventory

    Different studies have demonstrated that solar ultraviolet (UV) radiation can adversely affect survival and development of embryonic and larval amphibians. However, because of among-laboratory variations in exposure profiles (artificial vs. natural sunlight; natural sunlight at d...

  4. The ultra-violet question in maximally supersymmetric field theories

    NASA Astrophysics Data System (ADS)

    Bossard, G.; Howe, P. S.; Stelle, K. S.

    2009-04-01

    We discuss various approaches to the problem of determining which supersymmetric invariants are permitted as counterterms in maximally supersymmetric super Yang-Mills and supergravity theories in various dimensions. We review the superspace non-renormalisation theorems based on conventional, light-cone, harmonic and certain non-Lorentz covariant superspaces, and we write down explicitly the relevant invariants. While the first two types of superspace admit the possibility of one-half BPS counterterms, of the form F 4 and R 4 respectively, the last two do not. This suggests that UV divergences begin with one-quarter BPS counterterms, i.e. d 2 F 4 and d 4 R 4, and this is supported by an entirely different approach based on algebraic renormalisation. The algebraic formalism is discussed for non-renormalisable theories and it is shown how the allowable supersymmetric counterterms can be determined via cohomological methods. These results are in agreement with all the explicit computations that have been carried out to date. In particular, they suggest that maximal supergravity is likely to diverge at four loops in D = 5 and at five loops in D = 4, unless other infinity suppression mechanisms not involving supersymmetry or gauge invariance are at work.

  5. Fluorescent Organic Planar pn Heterojunction Light-Emitting Diodes with Simplified Structure, Extremely Low Driving Voltage, and High Efficiency.

    PubMed

    Chen, Dongcheng; Xie, Gaozhan; Cai, Xinyi; Liu, Ming; Cao, Yong; Su, Shi-Jian

    2016-01-13

    Fluorescent organic light-emitting diodes capable of radiative utilization of both singlet and triplet excitons are achieved via a simple double-layer planar pn hetero-junction configuration without a conventional emission layer, leading to high external quantum efficiency above 10% and extremely low driving voltages close to the theoretical minima.

  6. Systematic investigation of self-absorption and conversion efficiency of 6.7 nm extreme ultraviolet sources

    SciTech Connect

    Otsuka, Takamitsu; Higashiguchi, Takeshi; Yugami, Noboru; Yatagai, Toyohiko; Kilbane, Deirdre; Dunne, Padraig; O'Sullivan, Gerry; Jiang, Weihua; Endo, Akira

    2010-12-06

    We have investigated the dependence of the spectral behavior and conversion efficiencies of rare-earth plasma extreme ultraviolet sources with peak emission at 6.7 nm on laser wavelength and the initial target density. The maximum conversion efficiency was 1.3% at a laser intensity of 1.6x10{sup 12} W/cm{sup 2} at an operating wavelength of 1064 nm, when self-absorption was reduced by use of a low initial density target. Moreover, the lower-density results in a narrower spectrum and therefore improved spectral purity. It is shown to be important to use a low initial density target and/or to produce low electron density plasmas for efficient extreme ultraviolet sources when using high-Z targets.

  7. Studying Extreme Ultraviolet Wave Transients with a Digital Laboratory: Direct Comparison of Extreme Ultraviolet Wave Observations to Global Magnetohydrodynamic Simulations

    NASA Astrophysics Data System (ADS)

    Downs, Cooper; Roussev, Ilia I.; van der Holst, Bart; Lugaz, Noé; Sokolov, Igor V.; Gombosi, Tamas I.

    2011-02-01

    In this work, we describe our effort to explore the signatures of large-scale extreme ultraviolet (EUV) transients in the solar corona (EUV waves) using a three-dimensional thermodynamic magnetohydrodynamic model. We conduct multiple simulations of the 2008 March 25 EUV wave (~18:40 UT), observed both on and off of the solar disk by the STEREO-A and B spacecraft. By independently varying fundamental parameters thought to govern the physical mechanisms behind EUV waves in each model, such as the ambient magneto-sonic speed, eruption free energy, and eruption handedness, we are able to assess their respective contributions to the transient signature. A key feature of this work is the ability to synthesize the multi-filter response of the STEREO Extreme UltraViolet Imagers directly from model data, which gives a means for direct interpretation of EUV observations with full knowledge of the three-dimensional magnetic and thermodynamic structures in the simulations. We discuss the implications of our results with respect to some commonly held interpretations of EUV waves (e.g., fast-mode magnetosonic wave, plasma compression, reconnection front, etc.) and present a unified scenario which includes both a wave-like component moving at the fast magnetosonic speed and a coherent driven compression front related to the eruptive event itself.

  8. A hybrid fuzzy logic and extreme learning machine for improving efficiency of circulating water systems in power generation plant

    NASA Astrophysics Data System (ADS)

    Aziz, Nur Liyana Afiqah Abdul; Siah Yap, Keem; Afif Bunyamin, Muhammad

    2013-06-01

    This paper presents a new approach of the fault detection for improving efficiency of circulating water system (CWS) in a power generation plant using a hybrid Fuzzy Logic System (FLS) and Extreme Learning Machine (ELM) neural network. The FLS is a mathematical tool for calculating the uncertainties where precision and significance are applied in the real world. It is based on natural language which has the ability of "computing the word". The ELM is an extremely fast learning algorithm for neural network that can completed the training cycle in a very short time. By combining the FLS and ELM, new hybrid model, i.e., FLS-ELM is developed. The applicability of this proposed hybrid model is validated in fault detection in CWS which may help to improve overall efficiency of power generation plant, hence, consuming less natural recourses and producing less pollutions.

  9. High-efficiency collector design for extreme-ultraviolet and x-ray applications.

    PubMed

    Zocchi, Fabio E

    2006-12-10

    A design of a two-reflection mirror for nested grazing-incidence optics is proposed in which maximum overall reflectivity is achieved by making the two grazing-incidence angles equal for each ray. The design is proposed mainly for application to nonimaging collector optics for extreme-ultraviolet microlithography where the radiation emitted from a hot plasma source needs to be collected and focused on the illuminator optics. For completeness, the design of a double- reflection mirror with equal reflection angles is also briefly outlined for the case of an object at infinity for possible use in x-ray applications.

  10. High-efficiency collector design for extreme-ultraviolet and x-ray applications

    SciTech Connect

    Zocchi, Fabio E

    2006-12-10

    A design of a two-reflection mirror for nested grazing-incidence optics is proposed in which maximum overall reflectivity is achieved by making the two grazing-incidence angles equal for each ray. The design is proposed mainly for application to nonimaging collector optics for extreme-ultraviolet microlithography where the radiation emitted from a hot plasma source needs to be collected and focused on the illuminator optics. For completeness, the design of a double-reflection mirror with equal reflection angles is also briefly outlined for the case of an object at infinity for possible use in x-ray applications.

  11. High-efficiency collector design for extreme-ultraviolet and x-ray applications.

    PubMed

    Zocchi, Fabio E

    2006-12-10

    A design of a two-reflection mirror for nested grazing-incidence optics is proposed in which maximum overall reflectivity is achieved by making the two grazing-incidence angles equal for each ray. The design is proposed mainly for application to nonimaging collector optics for extreme-ultraviolet microlithography where the radiation emitted from a hot plasma source needs to be collected and focused on the illuminator optics. For completeness, the design of a double- reflection mirror with equal reflection angles is also briefly outlined for the case of an object at infinity for possible use in x-ray applications. PMID:17119587

  12. Extremely efficient exciton fission and fusion and its dominant contribution to the photoluminescence yield in rubrene single crystals

    NASA Astrophysics Data System (ADS)

    Biaggio, Ivan; Irkhin, Pavel

    2013-12-01

    Measurements of photoluminescence yield over a wide range of excitation power in rubrene single crystals reveal a transition between a low-yield region and a region with a yield more than an order of magnitude larger. This transition occurs at an excitation density of 3 × 1020 cm-3 absorbed photons per second. This power dependence is predicted in case of an extremely efficient conversion between singlet and triplet excitons through fission and fusion. Triplet fusion starts contributing to rubrene's photoluminescence already at intensities of a few mW/cm2 at room temperature, corresponding to triplet densities of ˜1016 cm-3.

  13. Extremely Efficient Multiple Electron-hole Pair Generation in Carbon Nanotube Photodiodes

    NASA Astrophysics Data System (ADS)

    Gabor, Nathaniel

    2010-03-01

    The efficient generation of multiple electron-hole (e-h) pairs from a single photon could improve the efficiency of photovoltaic solar cells beyond standard thermodynamic limits [1] and has been the focus of much recent work in semiconductor nanomaterials [2,3]. In single walled carbon nanotubes (SWNTs), the small Fermi velocity and low dielectric constant suggests that electron-electron interactions are very strong and that high-energy carriers should efficiently generate e-h pairs. Here, I will discuss observations of highly efficient generation of e-h pairs due to impact excitation in SWNT p-n junction photodiodes [4]. To investigate optoelectronic transport properties of individual SWNT photodiodes, we focus a laser beam over the device while monitoring the electronic characteristics. Optical excitation into the second electronic subband E22 ˜ 2 EGAP leads to striking photocurrent steps in the device I-VSD characteristics that occur at voltage intervals of the band gap energy EGAP/ e. Spatially and spectrally resolved photocurrent combined with temperature-dependent studies suggest that these steps result from efficient generation of multiple e-h pairs from a single hot E22 carrier. We conclude that in the SWNT photodiode, a single photon with energy greater than 2EGAP is converted into multiple e-h pairs, leading to enhanced photocurrent and increased photo-conversion efficiency. [1] W. Shockley, and H. J. Queisser, Journal of Applied Physics 32, 510 (1961). [2] R. D. Schaller, and V. I. Klimov, Physical Review Letters 92 (18), 186601 (2004). [3] R. J. Ellingson, et al, Nano Letters, 5 (5), 865-871 (2005). [4] Nathaniel M. Gabor, Zhaohui Zhong, Ken Bosnick, Jiwoong Park, and Paul McEuen, Science, 325, 1367 (2009).

  14. Numerical Research of Steam and Gas Plant Efficiency of Triple Cycle for Extreme North Regions

    NASA Astrophysics Data System (ADS)

    Galashov, Nikolay; Tsibulskii, Svjatoslav; Matveev, Aleksandr; Masjuk, Vladimir

    2016-02-01

    The present work shows that temperature decrease of heat rejection in a cycle is necessary for energy efficiency of steam turbine plants. Minimum temperature of heat rejection at steam turbine plant work on water steam is 15°C. Steam turbine plant of triple cycle where lower cycle of steam turbine plant is organic Rankine cycle on low-boiling substance with heat rejection in air condenser, which safely allows rejecting heat at condensation temperatures below 0°C, has been offered. Mathematical model of steam and gas plant of triple cycle, which allows conducting complex researches with change of working body appearance and parameters defining thermodynamic efficiency of cycles, has been developed. On the basis of the model a program of parameters and index cycles design of steam and gas plants has been developed in a package of electron tables Excel. Numerical studies of models showed that energy efficiency of steam turbine plants of triple cycle strongly depend on low-boiling substance type in a lower cycle. Energy efficiency of steam and gas plants net 60% higher can be received for steam and gas plants on the basis of gas turbine plant NK-36ST on pentane and its condensation temperature below 0°C. It was stated that energy efficiency of steam and gas plants net linearly depends on condensation temperature of low-boiling substance type and temperature of gases leaving reco very boiler. Energy efficiency increases by 1% at 10% decrease of condensation temperature of pentane, and it increases by 0.88% at 15°C temperature decrease of gases leaving recovery boiler.

  15. Silicon-Carbide Power MOSFET Performance in High Efficiency Boost Power Processing Unit for Extreme Environments

    NASA Technical Reports Server (NTRS)

    Ikpe, Stanley A.; Lauenstein, Jean-Marie; Carr, Gregory A.; Hunter, Don; Ludwig, Lawrence L.; Wood, William; Del Castillo, Linda Y.; Fitzpatrick, Fred; Chen, Yuan

    2016-01-01

    Silicon-Carbide device technology has generated much interest in recent years. With superior thermal performance, power ratings and potential switching frequencies over its Silicon counterpart, Silicon-Carbide offers a greater possibility for high powered switching applications in extreme environment. In particular, Silicon-Carbide Metal-Oxide- Semiconductor Field-Effect Transistors' (MOSFETs) maturing process technology has produced a plethora of commercially available power dense, low on-state resistance devices capable of switching at high frequencies. A novel hard-switched power processing unit (PPU) is implemented utilizing Silicon-Carbide power devices. Accelerated life data is captured and assessed in conjunction with a damage accumulation model of gate oxide and drain-source junction lifetime to evaluate potential system performance at high temperature environments.

  16. Cyanopyridine Based Bipolar Host Materials for Green Electrophosphorescence with Extremely Low Turn-On Voltages and High Power Efficiencies.

    PubMed

    Li, Wei; Li, Jiuyan; Liu, Di; Li, Deli; Wang, Fang

    2016-08-24

    Low driving voltage and high power efficiency are basic requirements when practical applications of organic light emitting diodes (OLEDs) in displays and lighting are considered. Two novel host materials m-PyCNmCP and 3-PyCNmCP incorporating cyanopyridine moiety as electron-transporting unit are developed for use in fac-tris(2-phenylpyridine)iridium(III) (Ir(ppy)3) based green phosphorescent OLEDs (PhOLEDs). Extremely low turn-on voltages of 2.01 and 2.27 V are realized, which are even lower than the theoretical limit of the emitted photon energy (hv)/electron charge (e) (2.37 V) of Ir(ppy)3. High power efficiency of 101.4 lm/W (corresponding to a maximum external quantum efficiency of 18.4%) and 119.3 lm/W (24.7%) are achieved for m-PyCNmCP and 3-PyCNmCP based green PhOLEDs. The excellent EL performance benefits from the ideal parameters of host materials by combining cyano and pyridine to enhance the n-type feature. The energetic favorable alignment of HOMO/LUMO levels of hosts with adjacent layers and the dopant for easy charge injections and direct charge trapping by dopant, their bipolar feature to balance charge transportations, sufficiently high triplet energy and small singlet/triplet energy difference (0.38 and 0.43 eV) combine to be responsible for the extremely low driving voltages and high power efficiencies of the green PhOLEDs. PMID:27479511

  17. Extremely Accessible Potassium Nitrate (KNO3) as the Highly Efficient Electrolyte Additive in Lithium Battery.

    PubMed

    Jia, Weishang; Fan, Cong; Wang, Liping; Wang, Qingji; Zhao, Mingjuan; Zhou, Aijun; Li, Jingze

    2016-06-22

    The systematic investigation of RNO3 salts (R = Li, Na, K, and Cs) as electrolyte additives was carried out for lithium-battery systems. For the first time, the abundant and extremely available KNO3 was proved to be an excellent alternative of LiNO3 for suppression of the lithium dendrites. The reason was ascribed to the possible synergetic effect of K(+) and NO3(-) ions: The positively charged K(+) ion could surround the lithium dendrites by electrostatic attraction and then delay their further growth, while simultaneously the oxidative NO3(-) ion could be reduced and subsequently profitable to the reinforcement of the solid-electrolyte interphase (SEI). By adding KNO3 into the practical Li-S battery, the discharging capacity was enhanced to average 687 mAh g(-1) from the case without KNO3 (528 mAh g(-1)) during 100 cycles, which was comparable to the one with the well-known LiNO3 additive (637 mAh g(-1)) under the same conditions. PMID:27237827

  18. Extremely Accessible Potassium Nitrate (KNO3) as the Highly Efficient Electrolyte Additive in Lithium Battery.

    PubMed

    Jia, Weishang; Fan, Cong; Wang, Liping; Wang, Qingji; Zhao, Mingjuan; Zhou, Aijun; Li, Jingze

    2016-06-22

    The systematic investigation of RNO3 salts (R = Li, Na, K, and Cs) as electrolyte additives was carried out for lithium-battery systems. For the first time, the abundant and extremely available KNO3 was proved to be an excellent alternative of LiNO3 for suppression of the lithium dendrites. The reason was ascribed to the possible synergetic effect of K(+) and NO3(-) ions: The positively charged K(+) ion could surround the lithium dendrites by electrostatic attraction and then delay their further growth, while simultaneously the oxidative NO3(-) ion could be reduced and subsequently profitable to the reinforcement of the solid-electrolyte interphase (SEI). By adding KNO3 into the practical Li-S battery, the discharging capacity was enhanced to average 687 mAh g(-1) from the case without KNO3 (528 mAh g(-1)) during 100 cycles, which was comparable to the one with the well-known LiNO3 additive (637 mAh g(-1)) under the same conditions.

  19. Extremely large extinction efficiency and field enhancement in terahertz resonant dipole nanoantennas.

    PubMed

    Razzari, Luca; Toma, Andrea; Shalaby, Mostafa; Clerici, Matteo; Zaccaria, Remo Proietti; Liberale, Carlo; Marras, Sergio; Al-Naib, Ibraheem A I; Das, Gobind; De Angelis, Francesco; Peccianti, Marco; Falqui, Andrea; Ozaki, Tsuneyuki; Morandotti, Roberto; Di Fabrizio, Enzo

    2011-12-19

    The distinctive ability of nanometallic structures to manipulate light at the nanoscale has recently promoted their use for a spectacular set of applications in a wide range of areas of research including artificial optical materials, nano-imaging, biosensing, and nonlinear optics. Here we transfer this concept to the terahertz spectral region, demonstrating a metal nanostructure in shape of a dipole nanoantenna, which can efficiently resonate at terahertz frequencies, showing an effective cross section >100 times larger than its geometrical area, and a field enhancement factor of ~280, confined on a lateral section of ~λ/1,000. These results lead to immediate applications in terahertz artificial materials exhibiting giant dichroism, suggest the use of dipole nanoantennas in nanostructure-based terahertz metamaterials, and pave the way for nanoantenna-enhanced terahertz few-molecule spectroscopy and localized terahertz nonlinear optics.

  20. Wavelength-Scale Structures as Extremely High Haze Films for Efficient Polymer Solar Cells.

    PubMed

    Ham, Juyoung; Dong, Wan Jae; Jung, Gwan Ho; Lee, Jong-Lam

    2016-03-01

    Wavelength-scale inverted pyramid structures with low reflectance and excellent haze have been designed for application to polymer solar cells (PSCs). The wavelength-scale structured haze films are fabricated on the back surface of glass without damages to organic active layer by using a soft lithographic technique with etched GaN molds. With a rigorous coupled-wave analysis of optical modeling, we find the shift of resonance peaks with the increase of pattern's diameter. Wavelength-scale structures could provide the number of resonances at the long wavelength spectrum (λ = 650-800 nm), yielding enhancement of power conversion efficiency (PCE) in the PSCs. Compared with a flat device (PCE = 7.12%, Jsc = 15.6 mA/cm(2)), improved PCE of 8.41% is achieved in a haze film, which is mainly due to the increased short circuit current density (Jsc) of 17.5 mA/cm(2). Hence, it opens up exciting opportunities for a variety of PSCs with wavelength-scale structures to further improve performance, simplify complicated process, and reduce costs.

  1. A highly efficient multi-core algorithm for clustering extremely large datasets

    PubMed Central

    2010-01-01

    Background In recent years, the demand for computational power in computational biology has increased due to rapidly growing data sets from microarray and other high-throughput technologies. This demand is likely to increase. Standard algorithms for analyzing data, such as cluster algorithms, need to be parallelized for fast processing. Unfortunately, most approaches for parallelizing algorithms largely rely on network communication protocols connecting and requiring multiple computers. One answer to this problem is to utilize the intrinsic capabilities in current multi-core hardware to distribute the tasks among the different cores of one computer. Results We introduce a multi-core parallelization of the k-means and k-modes cluster algorithms based on the design principles of transactional memory for clustering gene expression microarray type data and categorial SNP data. Our new shared memory parallel algorithms show to be highly efficient. We demonstrate their computational power and show their utility in cluster stability and sensitivity analysis employing repeated runs with slightly changed parameters. Computation speed of our Java based algorithm was increased by a factor of 10 for large data sets while preserving computational accuracy compared to single-core implementations and a recently published network based parallelization. Conclusions Most desktop computers and even notebooks provide at least dual-core processors. Our multi-core algorithms show that using modern algorithmic concepts, parallelization makes it possible to perform even such laborious tasks as cluster sensitivity and cluster number estimation on the laboratory computer. PMID:20370922

  2. TWARIT: an extremely rapid and efficient approach for phylogenetic classification of metagenomic sequences.

    PubMed

    Reddy, Rachamalla Maheedhar; Mohammed, Monzoorul Haque; Mande, Sharmila S

    2012-09-01

    Phylogenetic assignment of individual sequence reads to their respective taxa, referred to as 'taxonomic binning', constitutes a key step of metagenomic analysis. Existing binning methods have limitations either with respect to time or accuracy/specificity of binning. Given these limitations, development of a method that can bin vast amounts of metagenomic sequence data in a rapid, efficient and computationally inexpensive manner can profoundly influence metagenomic analysis in computational resource poor settings. We introduce TWARIT, a hybrid binning algorithm, that employs a combination of short-read alignment and composition-based signature sorting approaches to achieve rapid binning rates without compromising on binning accuracy and specificity. TWARIT is validated with simulated and real-world metagenomes and the results demonstrate significantly lower overall binning times compared to that of existing methods. Furthermore, the binning accuracy and specificity of TWARIT are observed to be comparable/superior to them. A web server implementing TWARIT algorithm is available at http://metagenomics.atc.tcs.com/Twarit/

  3. Wavelength-Scale Structures as Extremely High Haze Films for Efficient Polymer Solar Cells.

    PubMed

    Ham, Juyoung; Dong, Wan Jae; Jung, Gwan Ho; Lee, Jong-Lam

    2016-03-01

    Wavelength-scale inverted pyramid structures with low reflectance and excellent haze have been designed for application to polymer solar cells (PSCs). The wavelength-scale structured haze films are fabricated on the back surface of glass without damages to organic active layer by using a soft lithographic technique with etched GaN molds. With a rigorous coupled-wave analysis of optical modeling, we find the shift of resonance peaks with the increase of pattern's diameter. Wavelength-scale structures could provide the number of resonances at the long wavelength spectrum (λ = 650-800 nm), yielding enhancement of power conversion efficiency (PCE) in the PSCs. Compared with a flat device (PCE = 7.12%, Jsc = 15.6 mA/cm(2)), improved PCE of 8.41% is achieved in a haze film, which is mainly due to the increased short circuit current density (Jsc) of 17.5 mA/cm(2). Hence, it opens up exciting opportunities for a variety of PSCs with wavelength-scale structures to further improve performance, simplify complicated process, and reduce costs. PMID:26901630

  4. Measurement of zone plate efficiencies in the extreme ultraviolet and applications to radiation monitors for absolute spectral emission

    NASA Astrophysics Data System (ADS)

    Seely, John; Holland, Glenn; Bremer, James C.; Zukowski, Tim; Feser, Michael; Feng, Yan; Kjornrattanawanich, Benjawan; Goray, Leonid

    2006-08-01

    The diffraction efficiencies of a Fresnel zone plate (ZP), fabricated by Xradia Inc. using the electron-beam writing technique, were measured using polarized, monochromatic synchrotron radiation in the extreme ultraviolet wavelength range 3.4-22 nm. The ZP had 2 mm diameter, 3330 zones, 150 nm outer zone width, and a 1 mm central occulter. The ZP was supported by a 100 nm thick Si 3N 4 membrane. The diffraction patterns were recorded by CMOS imagers with phosphor coatings and with 5.2 μm or 48 μm pixels. The focused +n orders (n=1-4), the diverging -1 order, and the undiffracted 0 order were observed as functions of wavelength and off-axis tilt angle. Sub-pixel focusing of the +n orders was achieved. The measured efficiency in the +1 order was in the 5% to 30% range with the phase-shift enhanced efficiency occurring at 8.3 nm where the gold bars are partially transmitting. The +2 and higher order efficiencies were much lower than the +1 order efficiency. The efficiencies were constant when the zone plate was tilted by angles up to +/-1° from the incident radiation beam. This work indicates the feasibility and benefits of using zone plates to measure the absolute EUV spectral emissions from solar and laboratory sources: relatively high EUV efficiency in the focused +1 order, good out-of-band rejection resulting from the low higher-order efficiencies and the ZP focusing properties, insensitivity to (unfocused) visible light scattered by the ZP, flat response with off-axis angle, and insensitivity to the polarization of the radiation based on the ZP circular symmetry. EUV sensors with Fresnel zone plates potentially have many advantages over existing sensors intended to accurately measure absolute EUV emission levels, such as those implemented on the GOES N-P satellites that use transmission gratings which have off-axis sensitivity variations and poor out-of-band EUV and visible light rejection, and other solar and laboratory sensors using reflection gratings which

  5. Extremely efficient exciton fission and fusion and its dominant contribution to the photoluminescence yield in rubrene single crystals

    SciTech Connect

    Biaggio, Ivan; Irkhin, Pavel

    2013-12-23

    Measurements of photoluminescence yield over a wide range of excitation power in rubrene single crystals reveal a transition between a low-yield region and a region with a yield more than an order of magnitude larger. This transition occurs at an excitation density of 3 × 10{sup 20} cm{sup −3} absorbed photons per second. This power dependence is predicted in case of an extremely efficient conversion between singlet and triplet excitons through fission and fusion. Triplet fusion starts contributing to rubrene's photoluminescence already at intensities of a few mW/cm{sup 2} at room temperature, corresponding to triplet densities of ∼10{sup 16} cm{sup −3}.

  6. AN AUTOMATIC DETECTION METHOD FOR EXTREME-ULTRAVIOLET DIMMINGS ASSOCIATED WITH SMALL-SCALE ERUPTION

    SciTech Connect

    Alipour, N.; Safari, H.; Innes, D. E.

    2012-02-10

    Small-scale extreme-ultraviolet (EUV) dimming often surrounds sites of energy release in the quiet Sun. This paper describes a method for the automatic detection of these small-scale EUV dimmings using a feature-based classifier. The method is demonstrated using sequences of 171 Angstrom-Sign images taken by the STEREO/Extreme UltraViolet Imager (EUVI) on 2007 June 13 and by Solar Dynamics Observatory/Atmospheric Imaging Assembly on 2010 August 27. The feature identification relies on recognizing structure in sequences of space-time 171 Angstrom-Sign images using the Zernike moments of the images. The Zernike moments space-time slices with events and non-events are distinctive enough to be separated using a support vector machine (SVM) classifier. The SVM is trained using 150 events and 700 non-event space-time slices. We find a total of 1217 events in the EUVI images and 2064 events in the AIA images on the days studied. Most of the events are found between latitudes -35 Degree-Sign and +35 Degree-Sign . The sizes and expansion speeds of central dimming regions are extracted using a region grow algorithm. The histograms of the sizes in both EUVI and AIA follow a steep power law with slope of about -5. The AIA slope extends to smaller sizes before turning over. The mean velocity of 1325 dimming regions seen by AIA is found to be about 14 km s{sup -1}.

  7. Novel Nanophosphors for High Efficiency Fluorescent Lamps

    SciTech Connect

    Alok M. Srivastava

    2005-09-30

    This is the Yearly Report of the Novel Nanophosphors for High Efficiency Fluorescent Lamps, Department of Energy (DOE). The overall goal of this three-year program is to develop novel hybrid phosphors by coating commercially available lamp phosphors with highly stable wide band-gap nanocrystalline phosphors (NCP). The novel hybrid phosphors will increase the efficiency of the fluorescent lamps by up to 32%, enabling total energy savings of 0.26 quads, the reduction in the U.S. energy bill by $6.5 billion and the reduction of the annual carbon emission by 4.1 billion kilogram. The prime technical approach is the development of NCP quantum-splitting phosphor (QSP) and ultra-violet emitting phosphors with quantum efficiencies exceeding that of the conventional phosphors at 185 nm. Our chief achievement, during the current contract period, pertains to the successful synthesis and characterization of coated phosphors. We demonstrated several synthesis techniques for the coating of micron sized commercial phosphors with quantum-splitting and UV emitting nanophosphors. We have also continued our fundamental investigations into the physical processes that determine the quantum efficiency of the nanophosphors and this has further helped codify a set of rules for the host lattice that support efficient quantum splitting and UV emission at room temperature. In this report we summarize the technical work completed under the Program, summarize our findings about the performance limits of the various technologies we investigated, and outline promising paths for future work.

  8. Using a Clean Energy Version of Moore's Law to Plan for the Extreme Efficiency of the Future

    NASA Astrophysics Data System (ADS)

    van Buskirk, Robert

    2014-03-01

    In 1965, Gordon Moore predicted a decade of exponential growth in the transistor density growth (and hence computing power) for integrated circuits that--with some modification--has held to the present day. In this talk, we discuss to what extent clean energy technologies are subject to similar laws of long term exponential improvement and how these improvement rates may be accelerating due to recent developments. We review a range of long term energy efficiency and technology productivity improvement trends ranging from lighting, televisions, refrigerators, HVAC, batteries, motors, power electronics and solar PV. After reviewing historical and recent trends, we discuss several factors that may lead to an acceleration of improvement rates in the clean energy technology sector. Finally, we discuss the Baumol effect which predicts how differential trends in technology productivity may affect trends in relative prices in the economy. We conclude with a discussion of some of the implications that Baumol's theories may have for the development of extreme levels of energy efficiency in the coming decades.

  9. Efficiency droop enhancement in AlGaN deep ultraviolet light-emitting diodes by making whole barriers but the bottom Mg doped

    NASA Astrophysics Data System (ADS)

    Sun, Jie; Sun, Huiqing; Yi, Xinyan; Yang, Xian; Fan, Xuancong; Zhang, Cheng; Zhang, Zhuding; Guo, Zhiyou

    2016-09-01

    Ultra violet light-emitting diodes (UVLEDs) with different types of Mg-doped barriers have been studied. The energy band diagrams, internal quantum efficiency, total output power and radiative recombination rate are investigated by APSYS software. The simulation results show that the UVLED with only a p-doped top barrier get little enhancement comparing to the conventional one, on the contrary the structure with p-doping in all but the bottom barriers has a much better optical and electrical properties due to enhancement of the holes' injection and the electrons' confinement. The efficiency droop is significantly alleviated and the light output power is greatly enhanced. To avoid forming a PN junction by the bottom barrier and the n-AlGaN in the proposed structure, therefore, the bottom barrier isn't p-doped. Then structures with different hole densities in the Mg-doped barriers have been studied numerically and that confirmed the best.

  10. Efficient trans-cleavage by the Schistosoma mansoni SMα1 hammerhead ribozyme in the extreme thermophile Thermus thermophilus

    PubMed Central

    Vazquez-Tello, Alejandro; Castán, Pablo; Moreno, Renata; Smith, James M.; Berenguer, José; Cedergren, Robert

    2002-01-01

    The catalytic hammerhead structure has been found in association with repetitive DNA from several animals, including salamanders, crickets and schistosomes, and functions to process in cis the long multimer transcripts into monomer RNA in vivo. The cellular role of these repetitive elements and their transcripts is unknown. Moreover, none of these natural hammerheads have been shown to trans-cleave a host mRNA in vivo. We analyzed the cis- and trans-cleavage properties of the hammerhead ribozyme associated with the SMα DNA family from the human parasite Schistosoma mansoni. The efficiency of trans-cleavage of a target RNA in vitro was affected mainly by both the temperature-dependent chemical step and the ribozyme–product dissociation step. The optimal temperature for trans-cleavage was 70°C. This result was confirmed when both the SMα1 ribozyme and the target RNA were expressed in the extreme thermophile Thermus thermophilus. Moreover, SMα1 RNA showed a remarkable thermostability, equal or superior to that of the most stable RNAs in this species, suggesting that SMα1 RNA has been selected for stability. Computer analysis predicts that the monomer and multimer transcripts fold into highly compact secondary structures, which may explain their exceptional stability in vivo. PMID:11917021

  11. Nanostructure surface patterning of GaN thin films and application to AlGaN/AlN multiple quantum wells: A way towards light extraction efficiency enhancement of III-nitride based light emitting diodes

    SciTech Connect

    Guo, Wei Kirste, Ronny; Bryan, Zachary; Bryan, Isaac; Collazo, Ramón; Sitar, Zlatko; Gerhold, Michael

    2015-03-21

    Enhanced light extraction efficiency was demonstrated on nanostructure patterned GaN and AlGaN/AlN Multiple-Quantum-Well (MQW) structures using mass production techniques including natural lithography and interference lithography with feature size as small as 100 nm. Periodic nanostructures showed higher light extraction efficiency and modified emission profile compared to non-periodic structures based on integral reflection and angular-resolved transmission measurement. Light extraction mechanism of macroscopic and microscopic nanopatterning is discussed, and the advantage of using periodic nanostructure patterning is provided. An enhanced photoluminescence emission intensity was observed on nanostructure patterned AlGaN/AlN MQW compared to as-grown structure, demonstrating a large-scale and mass-producible pathway to higher light extraction efficiency in deep-ultra-violet light-emitting diodes.

  12. Study of the large-scale structure of the plasmasphere using extreme ultraviolet observations

    SciTech Connect

    Chakrabarti, S.

    1982-01-01

    Plasmaspheric ion distributions in the 500-30,000 km range have been indirectly measured by observing selected lines of solar Extreme Ultra Violet spectrum resonantly scattered by different ionic species. The observations were made with a broad-band photometer on the Apollo-Soyuz mission and an EUV spectrometer on board the STP78-1 satellite. A third experiment has been conducted recently from rocket-borne photometers. The data obtained from these experiments were compared against several theoretical models of ion distributions. The study shows that the ad-hoc models, which were sufficient to explain previous observations, were unable to explain the data obtained by the instruments which were more sensitive than the previous ones. A kinetic equilibrium model of ion distribution, which takes the effect of a non-homogeneous magnetic field into account, was found to explain the observations. The model uses a reference ionosphere and a thermal structure of the plasmasphere as the input parameters. The ion density at the reference ionosphere (500 km) used in this analysis was obtained from simultaneous measurements by a mass spectrometer on the Atmospheric Explorer satellite. Ion temperature at the reference altitude was obtained from near-simultaneous measurements by a retarding potential analyzer on the same satellite. This use of independent measurements to restrict the boundary values enhances the validity of the model.

  13. Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

    SciTech Connect

    Shahzad, M.; Culfa, O.; Rossall, A. K.; Tallents, G. J.; Wilson, L. A.; Guilbaud, O.; Kazamias, S.; Delmas, O.; Demailly, J.; Maitrallain, A.; Pittman, M.; Baynard, E.; Farjardo, M.

    2015-02-15

    We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 10{sup 16} Wcm{sup −2} is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe{sup 5+} and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

  14. The composition and structure of white dwarf atmospheres revealed by extreme ultraviolet spectroscopy

    NASA Technical Reports Server (NTRS)

    Barstow, Martin A.; Hubeny, Ivan; Lanz, Thierry; Holberg, Jay B.; Sion, Edward M.

    1995-01-01

    The ROentgen SATellite (ROSAT) and Extreme UltraViolet Explorer (EUVE) all-sky surveys have resulted in an important change in our understanding of the general composition of hydrogen-rich DA white dwarf atmospheres, with the photospheric opacity dominated by heavy elements rather than helium in the hottest stars (T > 40, 000 K). Most stars cooler than 40,000 K have more or less pure H atmospheres. However, one question, which has not been resolved, concerned the specific nature of the heavy elements and the role of helium in the hottest white dwarfs. One view of white dwarf evolution requires that H-rich DA stars form by gravitational settling of He from either DAO or He-rich central stars of planetary nebulae. In this case, the youngest (hottest) DA white dwarfs may still contain visible traces of He. Spectroscopic observations now available with EUVE provide a crucial test of these ideas. Analysis of data from the EUVE Guest Observer programme and EUVE public archive allows quantitative consideration of the sources of EUV opacity and places limits on the abundance of He which may be present.

  15. Avian thermoregulation in the heat: efficient evaporative cooling allows for extreme heat tolerance in four southern hemisphere columbids.

    PubMed

    McKechnie, Andrew E; Whitfield, Maxine C; Smit, Ben; Gerson, Alexander R; Smith, Eric Krabbe; Talbot, William A; McWhorter, Todd J; Wolf, Blair O

    2016-07-15

    Birds show phylogenetic variation in the relative importance of respiratory versus cutaneous evaporation, but the consequences for heat tolerance and evaporative cooling capacity remain unclear. We measured evaporative water loss (EWL), resting metabolic rate (RMR) and body temperature (Tb) in four arid-zone columbids from southern Africa [Namaqua dove (Oena capensis, ∼37 g), laughing dove (Spilopelia senegalensis, ∼89 g) and Cape turtle dove (Streptopelia capicola, ∼148 g)] and Australia [crested pigeon (Ocyphaps lophotes), ∼186 g] at air temperatures (Ta) of up to 62°C. There was no clear relationship between body mass and maximum Ta tolerated during acute heat exposure. Maximum Tb at very high Ta was 43.1±1.0, 43.7±0.8, 44.7±0.3 and 44.3±0.8°C in Namaqua doves, laughing doves, Cape turtle doves and crested pigeons, respectively. In all four species, RMR increased significantly at Ta above thermoneutrality, but the increases were relatively modest with RMR at Ta=56°C being 32, 60, 99 and 11% higher, respectively, than at Ta=35°C. At the highest Ta values reached, evaporative heat loss was equivalent to 466, 227, 230 and 275% of metabolic heat production. The maximum ratio of evaporative heat loss to metabolic production observed in Namaqua doves, 4.66, exceeds by a substantial margin previous values reported for birds. Our results support the notion that cutaneous evaporation provides a highly efficient mechanism of heat dissipation and an enhanced ability to tolerate extremely high Ta. PMID:27207640

  16. STEREOSCOPIC DETERMINATION OF HEIGHTS OF EXTREME ULTRAVIOLET BRIGHT POINTS USING DATA TAKEN BY SECCHI/EUVI ABOARD STEREO

    SciTech Connect

    Kwon, Ryun-Young; Chae, Jongchul; Zhang Jie

    2010-05-01

    We measure the heights of EUV bright points (BPs) above the solar surface by applying a stereoscopic method to the data taken by the Solar TErrestrial RElations Observatory/SECCHI/Extreme UltraViolet Imager (EUVI). We have developed a three-dimensional reconstruction method for point-like features such as BPs using the simple principle that the position of a point in the three-dimensional space is specified as the intersection of two lines of sight. From a set of data consisting of EUVI 171 A, 195 A, 284 A, and 304 A images taken on 11 days arbitrarily selected during a period of 14 months, we have identified and analyzed 210 individual BPs that were visible on all four passband images and smaller than 30 Mm. The BPs seen in the 304 A images have an average height of 4.4 Mm, and are often associated with the legs of coronal loops. In the 171 A, 195 A, and 284 A images the BPs appear loop-shaped, and have average heights of 5.1, 6.7, and 6.1 Mm, respectively. Moreover, there is a tendency that overlying loops are filled with hotter plasmas. The average heights of BPs in 171 A, 195 A, and 284 A passbands are roughly twice the corresponding average lengths. Our results support the notion that an EUV BP represents a system of small loops with temperature stratification like flaring loops, being consistent with the magnetic reconnection origin.

  17. Test report: Low cost access and efficient use of TDRSS

    NASA Technical Reports Server (NTRS)

    Horan, S.

    1996-01-01

    In order to develop new ways to increase the number of users taking advantage of NASA's Space Network for space-to-ground communications links, researchers at New Mexico State University (NMSU) developed a technique for using non-gimballed antennas for accessing a Tracking and Data Relay Satellite (TDRS) within the Space Network (SN). This concept would allow spin-stabilized satellites to access one of the TDRS spacecraft in the SN constellation as the user satellite sweeps past the TDRS position as the satellite approaches either its ascending or descending node if this node is relatively close to the TDRS subsatellite point. ne research team from NMSU developing this concept proposed to NASA the use of the Extreme Ultra Violet Explorer (EUVE) to test this concept on orbit. EUVE differs from the desired satellite configuration in that EUVE has a relatively high-gain parabolic antenna and, most importantly, EUVE has an inertially-stabilized attitude control system while the concept to be tested was for a spin-stabilized satellite. We believed that these limitations would not affect the basic proof-of-concept test we were trying to achieve. With the approval and coordination of NASA, a total of six satellite passes through the West TDRS were requested and the necessary equipment configured for data collection at the Second TDRS Ground Terminal (STGT), also known as Danzante, at the White Sands Complex.

  18. How extreme are extremes?

    NASA Astrophysics Data System (ADS)

    Cucchi, Marco; Petitta, Marcello; Calmanti, Sandro

    2016-04-01

    High temperatures have an impact on the energy balance of any living organism and on the operational capabilities of critical infrastructures. Heat-wave indicators have been mainly developed with the aim of capturing the potential impacts on specific sectors (agriculture, health, wildfires, transport, power generation and distribution). However, the ability to capture the occurrence of extreme temperature events is an essential property of a multi-hazard extreme climate indicator. Aim of this study is to develop a standardized heat-wave indicator, that can be combined with other indices in order to describe multiple hazards in a single indicator. The proposed approach can be used in order to have a quantified indicator of the strenght of a certain extreme. As a matter of fact, extremes are usually distributed in exponential or exponential-exponential functions and it is difficult to quickly asses how strong was an extreme events considering only its magnitude. The proposed approach simplify the quantitative and qualitative communication of extreme magnitude

  19. Extreme ultraviolet reflection efficiencies of diamond-turned aluminum, polished nickel, and evaporated gold surfaces. [for telescope mirrors

    NASA Technical Reports Server (NTRS)

    Malina, R. F.; Cash, W.

    1978-01-01

    Measured reflection efficiencies are presented for flat samples of diamond-turned aluminum, nickel, and evaporated gold surfaces fabricated by techniques suited for EUV telescopes. The aluminum samples were 6.2-cm-diameter disks of 6061-T6, the electroless nickel samples were formed by plating beryllium disks with 7.5-microns of Kanigen. Gold samples were produced by coating the aluminum and nickel samples with 5 strips of evaporated gold. Reflection efficiencies are given for grazing angles in the 5-75 degree range. The results indicate that for wavelengths over about 100 A, the gold-coated nickel samples yield highest efficiencies. For shorter wavelengths, the nickel samples yield better efficiencies. 500 A is found to be the optimal gold thickness.

  20. Exciplex-triplet energy transfer: A new method to achieve extremely efficient organic light-emitting diode with external quantum efficiency over 30% and drive voltage below 3 V

    NASA Astrophysics Data System (ADS)

    Seo, Satoshi; Shitagaki, Satoko; Ohsawa, Nobuharu; Inoue, Hideko; Suzuki, Kunihiko; Nowatari, Hiromi; Yamazaki, Shunpei

    2014-04-01

    A novel approach to enhance the power efficiency of an organic light-emitting diode (OLED) by employing energy transfer from an exciplex to a phosphorescent emitter is reported. It was found that excitation energy of an exciplex formed between an electron-transporting material with a π-deficient quinoxaline moiety and a hole-transporting material with aromatic amine structure can be effectively transferred to a phosphorescent iridium complex in an emission layer of a phosphorescent OLED. Moreover, such an exciplex formation increases quantum efficiency and reduces drive voltage. A highly efficient, low-voltage, and long-life OLED based on this energy transfer is also demonstrated. This OLED device exhibited extremely high external quantum efficiency of 31% even without any attempt to enhance light outcoupling and also achieved a low drive voltage of 2.8 V and a long lifetime of approximately 1,000,000 h at a luminance of 1,000 cd/m2.

  1. Theoretical investigation of the spectrum and conversion efficiency of short wavelength extreme-ultraviolet light sources based on terbium plasmas

    SciTech Connect

    Sasaki, Akira; Nishihara, Katsunobu; Sunahara, Atsushi; Furukawa, Hiroyuki; Nishikawa, Takeshi; Koike, Fumihiro

    2010-12-06

    The emission spectrum and conversion efficiency of laser-produced terbium plasmas are theoretically investigated on the basis of computational atomic data. The theoretically calculated spectrum reproduces the main peak of observed spectrum at {lambda}=6.5 nm, which originates from 4d-4f transitions of near palladiumlike ions (Tb{sup 19+}). A simple model of the isothermal expansion of terbium plasma suggests that efficient emission can be achieved by pumping the plasma with a laser pulse at an intensity of approximately one order of magnitude greater than that used with tin sources at {lambda}=13.5 nm.

  2. Development of n+-in-p planar pixel sensors for extremely high radiation environments, designed to retain high efficiency after irradiation

    NASA Astrophysics Data System (ADS)

    Unno, Y.; Kamada, S.; Yamamura, K.; Ikegami, Y.; Nakamura, K.; Takubo, Y.; Takashima, R.; Tojo, J.; Kono, T.; Hanagaki, K.; Yajima, K.; Yamauchi, Y.; Hirose, M.; Homma, Y.; Jinnouchi, O.; Kimura, K.; Motohashi, K.; Sato, S.; Sawai, H.; Todome, K.; Yamaguchi, D.; Hara, K.; Sato, Kz.; Sato, Kj.; Hagihara, M.; Iwabuchi, S.

    2016-09-01

    We have developed n+-in-p pixel sensors to obtain highly radiation tolerant sensors for extremely high radiation environments such as those found at the high-luminosity LHC. We have designed novel pixel structures to eliminate the sources of efficiency loss under the bias rails after irradiation by removing the bias rail out of the boundary region and routing the bias resistors inside the area of the pixel electrodes. After irradiation by protons with the fluence of approximately 3 ×1015neq /cm2, the pixel structure with the polysilicon bias resistor and the bias rails removed far away from the boundary shows an efficiency loss of < 0.5 % per pixel at the boundary region, which is as efficient as the pixel structure without a biasing structure. The pixel structure with the bias rails at the boundary and the widened p-stop's underneath the bias rail also exhibits an improved loss of approximately 1% per pixel at the boundary region. We have elucidated the physical mechanisms behind the efficiency loss under the bias rail with TCAD simulations. The efficiency loss is due to the interplay of the bias rail acting as a charge collecting electrode with the region of low electric field in the silicon near the surface at the boundary. The region acts as a "shield" for the electrode. After irradiation, the strong applied electric field nearly eliminates the region. The TCAD simulations have shown that wide p-stop and large Si-SiO2 interface charge (inversion layer, specifically) act to shield the weighting potential. The pixel sensor of the old design irradiated by γ-rays at 2.4 MGy is confirmed to exhibit only a slight efficiency loss at the boundary.

  3. Efficient hydrogen production from the lignocellulosic energy crop Miscanthus by the extreme thermophilic bacteria Caldicellulosiruptor saccharolyticus and Thermotoga neapolitana

    PubMed Central

    de Vrije, Truus; Bakker, Robert R; Budde, Miriam AW; Lai, Man H; Mars, Astrid E; Claassen, Pieternel AM

    2009-01-01

    Background The production of hydrogen from biomass by fermentation is one of the routes that can contribute to a future sustainable hydrogen economy. Lignocellulosic biomass is an attractive feedstock because of its abundance, low production costs and high polysaccharide content. Results Batch cultures of Caldicellulosiruptor saccharolyticus and Thermotoga neapolitana produced hydrogen, carbon dioxide and acetic acid as the main products from soluble saccharides in Miscanthus hydrolysate. The presence of fermentation inhibitors, such as furfural and 5-hydroxylmethyl furfural, in this lignocellulosic hydrolysate was avoided by the mild alkaline-pretreatment conditions at a low temperature of 75°C. Both microorganisms simultaneously and completely utilized all pentoses, hexoses and oligomeric saccharides up to a total concentration of 17 g l-1 in pH-controlled batch cultures. T. neapolitana showed a preference for glucose over xylose, which are the main sugars in the hydrolysate. Hydrogen yields of 2.9 to 3.4 mol H2 per mol of hexose, corresponding to 74 to 85% of the theoretical yield, were obtained in these batch fermentations. The yields were higher with cultures of C. saccharolyticus compared to T. neapolitana. In contrast, the rate of substrate consumption and hydrogen production was higher with T. neapolitana. At substrate concentrations exceeding 30 g l-1, sugar consumption was incomplete, and lower hydrogen yields of 2.0 to 2.4 mol per mol of consumed hexose were obtained. Conclusion Efficient hydrogen production in combination with simultaneous and complete utilization of all saccharides has been obtained during the growth of thermophilic bacteria on hydrolysate of the lignocellulosic feedstock Miscanthus. The use of thermophilic bacteria will therefore significantly contribute to the energy efficiency of a bioprocess for hydrogen production from biomass. PMID:19534765

  4. Soft X-ray and extreme utraviolet quantum detection efficiency of potassium chloride photocathode layers on microchannel plates

    NASA Technical Reports Server (NTRS)

    Siegmund, Oswald H. W.; Everman, Elaine; Hull, Jeff; Vallerga, John V.; Lampton, Michael

    1988-01-01

    The quantum detection efficiency (QDE) of KCl photocathodes in the 44-1460 A range was investigated. An opaque layer of KCl, about 15,000-A-thick, was evaporated and applied the surface of a microchannel plate (MCP), and the contribution of the photocathode material in the channels (and on the interchannel web) to the QDE was measured using a Z stack MCP detector. It is shown that KCl is a relatively stable photocathode material, with the QDE equal to 30-40 percent in the EUV. At wavelengths above 200 A, the QDE is slightly better than the QDE of CsI, as reported by Siegmund et al. (1986). While the shape of the QDE curve as a function of wavelength is similar to those reported for CsI and KBr, KCl was found to lack the high QDE peak found in the curves of CsI and KBr at about 100 A. A simple QDE model is described, the predictions of which were found to agree with the measurements on the KCl photocathode.

  5. Grain Yield and Water Use Efficiency in Extremely-Late Sown Winter Wheat Cultivars under Two Irrigation Regimes in the North China Plain

    PubMed Central

    Wang, Bin; Zhang, Yinghua; Hao, Baozhen; Xu, Xuexin; Zhao, Zhigan; Wang, Zhimin; Xue, Qingwu

    2016-01-01

    Wheat production is threatened by water shortages and groundwater over-draft in the North China Plain (NCP). In recent years, winter wheat has been increasingly sown extremely late in early to mid-November after harvesting cotton or pepper. To improve water use efficiency (WUE) and guide the extremely late sowing practices, a 3-year field experiment was conducted under two irrigation regimes (W1, one-irrigation, 75 mm at jointing; W2, two-irrigation, 75 mm at jointing and 75 mm at anthesis) in 3 cultivars differing in spike size (HS4399, small spike; JM22, medium spike; WM8, large spike). Wheat was sown in early to mid-November at a high seeding rate of 800–850 seeds m−2. Average yields of 7.42 t ha−1 and WUE of 1.84 kg m−3 were achieved with an average seasonal evapotranspiration (ET) of 404 mm. Compared with W2, wheat under W1 did not have yield penalty in 2 of 3 years, and had 7.9% lower seasonal ET and 7.5% higher WUE. The higher WUE and stable yield under W1 was associated with higher 1000-grain weight (TGW) and harvest index (HI). Among the 3 cultivars, JM22 had 5.9%–8.9% higher yield and 4.2%–9.3% higher WUE than WM8 and HS4399. The higher yield in JM22 was attributed mainly to higher HI and TGW due to increased post-anthesis biomass and deeper seasonal soil water extraction. In conclusion, one-irrigation with a medium-sized spike cultivar JM22 could be a useful strategy to maintain yield and high WUE in extremely late-sown winter wheat at a high seeding rate in the NCP. PMID:27100187

  6. Mutations of Photosystem II D1 Protein That Empower Efficient Phenotypes of Chlamydomonas reinhardtii under Extreme Environment in Space

    PubMed Central

    Lambreva, Maya D.; Antonacci, Amina; Pastorelli, Sandro; Bertalan, Ivo; Johanningmeier, Udo; Mattoo, Autar K.

    2013-01-01

    Space missions have enabled testing how microorganisms, animals and plants respond to extra-terrestrial, complex and hazardous environment in space. Photosynthetic organisms are thought to be relatively more prone to microgravity, weak magnetic field and cosmic radiation because oxygenic photosynthesis is intimately associated with capture and conversion of light energy into chemical energy, a process that has adapted to relatively less complex and contained environment on Earth. To study the direct effect of the space environment on the fundamental process of photosynthesis, we sent into low Earth orbit space engineered and mutated strains of the unicellular green alga, Chlamydomonas reinhardtii, which has been widely used as a model of photosynthetic organisms. The algal mutants contained specific amino acid substitutions in the functionally important regions of the pivotal Photosystem II (PSII) reaction centre D1 protein near the QB binding pocket and in the environment surrounding Tyr-161 (YZ) electron acceptor of the oxygen-evolving complex. Using real-time measurements of PSII photochemistry, here we show that during the space flight while the control strain and two D1 mutants (A250L and V160A) were inefficient in carrying out PSII activity, two other D1 mutants, I163N and A251C, performed efficient photosynthesis, and actively re-grew upon return to Earth. Mimicking the neutron irradiation component of cosmic rays on Earth yielded similar results. Experiments with I163N and A251C D1 mutants performed on ground showed that they are better able to modulate PSII excitation pressure and have higher capacity to reoxidize the QA− state of the primary electron acceptor. These results highlight the contribution of D1 conformation in relation to photosynthesis and oxygen production in space. PMID:23691201

  7. Mutations of photosystem II D1 protein that empower efficient phenotypes of Chlamydomonas reinhardtii under extreme environment in space.

    PubMed

    Giardi, Maria Teresa; Rea, Giuseppina; Lambreva, Maya D; Antonacci, Amina; Pastorelli, Sandro; Bertalan, Ivo; Johanningmeier, Udo; Mattoo, Autar K

    2013-01-01

    Space missions have enabled testing how microorganisms, animals and plants respond to extra-terrestrial, complex and hazardous environment in space. Photosynthetic organisms are thought to be relatively more prone to microgravity, weak magnetic field and cosmic radiation because oxygenic photosynthesis is intimately associated with capture and conversion of light energy into chemical energy, a process that has adapted to relatively less complex and contained environment on Earth. To study the direct effect of the space environment on the fundamental process of photosynthesis, we sent into low Earth orbit space engineered and mutated strains of the unicellular green alga, Chlamydomonas reinhardtii, which has been widely used as a model of photosynthetic organisms. The algal mutants contained specific amino acid substitutions in the functionally important regions of the pivotal Photosystem II (PSII) reaction centre D1 protein near the QB binding pocket and in the environment surrounding Tyr-161 (YZ) electron acceptor of the oxygen-evolving complex. Using real-time measurements of PSII photochemistry, here we show that during the space flight while the control strain and two D1 mutants (A250L and V160A) were inefficient in carrying out PSII activity, two other D1 mutants, I163N and A251C, performed efficient photosynthesis, and actively re-grew upon return to Earth. Mimicking the neutron irradiation component of cosmic rays on Earth yielded similar results. Experiments with I163N and A251C D1 mutants performed on ground showed that they are better able to modulate PSII excitation pressure and have higher capacity to reoxidize the QA (-) state of the primary electron acceptor. These results highlight the contribution of D1 conformation in relation to photosynthesis and oxygen production in space.

  8. Temporal characterization of a time-compensated monochromator for high-efficiency selection of extreme-ultraviolet pulses generated by high-order harmonics

    SciTech Connect

    Poletto, L.; Villoresi, P.; Benedetti, E.; Ferrari, F.; Stagira, S.; Sansone, G.; Nisoli, M.

    2008-07-15

    Ultrafast extreme-ultraviolet pulses are spectrally selected by a time-delay-compensated grating monochromator. The intrinsic very short duration of the pulses is obtained by exploiting the high-order harmonic generation process. The temporal characterization of the harmonic pulses is obtained using a cross-correlation method: pulses as short as 8 fs are measured at the output of the monochromator in the case of the 23rd harmonic. This value is in agreement with the expected duration of such pulses, indicating that the influence of the monochromator is negligible. The photon flux has been measured with a calibrated photodiode, pointing out the good efficiency of the monochromator, derived by the exploitation for the two gratings of the conical diffraction mounting.

  9. Far-infrared-light shadowgraphy for high extraction efficiency of extreme ultraviolet light from a CO2-laser-generated tin plasma

    NASA Astrophysics Data System (ADS)

    Matsukuma, Hiraku; Hosoda, Tatsuya; Suzuki, Yosuke; Yogo, Akifumi; Yanagida, Tatsuya; Kodama, Takeshi; Nishimura, Hiroaki

    2016-08-01

    The two-color, double-pulse method is an efficient scheme to generate extreme ultraviolet light for fabricating the next generation semiconductor microchips. In this method, a Nd:YAG laser pulse is used to expand a several-tens-of-micrometers-scale tin droplet, and a CO2 laser pulse is subsequently directed at the expanded tin vapor after an appropriate delay time. We propose the use of shadowgraphy with a CO2 laser probe-pulse scheme to optimize the CO2 main-drive laser. The distribution of absorption coefficients is derived from the experiment, and the results are converted to a practical absorption rate for the CO2 main-drive laser.

  10. The Ethnic Differences of the Damage of Hair and Integral Hair Lipid after Ultra Violet Radiation

    PubMed Central

    Ji, Jae Hong; Park, Tae-Sik; Lee, Hae-Jin; Kim, Yoon-Duk; Pi, Long-Quan; Jin, Xin-Hai

    2013-01-01

    Background Genetic factors account for the majority of differences in skin color and hair morphology across human populations. Although many studies have been conducted to examine differences in skin color across populations, few studies have examined differences in hair morphology. Objective To investigate changing of integral hair lipids after ultraviolet (UV) irradiation in three human ethnic groups. Methods We studied the UV irradiation induced hair damage in hairs of three human populations. UV irradiation had been performed with self-manufactured phototherapy system. Damaged hair samples were prepared at 12 and 48 hours after UVA (20 J/sec) and UVB (8 J/sec) irradiation. We evaluated the changes of hair lipid using scanning electron microscopy (SEM), transmission electron microscopy (TEM), lipid TEM and HP-TLC. After UV irradiation, hair surface damage was shown. Results African hair showed more severe damage on hair surface than others. The lipid compositions across human populations were similar, but Asian hair had more integral hair lipids than other groups as a whole. Especially, free fatty acid contents were higher than other lipids. After UV irradiation, lipid contents were decreased. These patterns were shown in all human populations. Asian hair has more integral hair lipid than European or African hair. After UV irradiation, European and African hair samples exhibited more damage because they have less integral hair lipids. However, Asian hair samples have less damage. Conclusion We conclude that integral hair lipid may protect the hair against the UV light. PMID:23467772

  11. The efficacy of surface modified nano titanium dioxide against photocatalytic activity from the ultra violet irradiation

    NASA Astrophysics Data System (ADS)

    Lee, Wilson A.

    We have used sonochemistry to synthesize a multi-component coating for TiO2 nanoparticles to minimize the harmful effects of reactive oxygen species (ROS) from nano rutile TiO2. We measured the FTIR spectra of the coated particles and found that the coating was very robust and none of the components were removed even after vigorous washing in deionized water. We used Thermal Gravimetric Analysis (TGA) to estimate the amount of polymer brushes attached to the TiO2 particle and further derived the thickness of the coating. The in vitro SPF result showed no difference between the coated TiO2 and uncoated TiO2. The ability of these particles to scavenge free radicals was also tested using dyes in which Red #28 was exposed to UVA, UVB, and UVC wavelength. We found that the dye solution containing the uncoated TiO2 particles rapidly became clear upon exposure to all UV wavelengths. In contrast, the samples containing the functionalized particles did not change color with Ultraviolet-visible spectroscopy even when irradiated with 5.4 muo/cm2 UVA and UVB for 27 hours. lambda DNA exposed to UVA, UVB, and UVC for as little as 0.5hr began to show chain scission when subjected to electrophoresis. DNA exposed to UVB and UVC, in the presence of TiO2 particles did not show any damage. We therefore conclude that the free radicals were responsible for the breakage, and the presence of free radical scavengers minimizes their effectiveness in destroying DNA.

  12. Transmittance measurements of ultra violet and visible wavelength interference filters flown aboard LDEF

    NASA Technical Reports Server (NTRS)

    Mooney, Thomas A.; Smajkiewicz, Ali

    1991-01-01

    A set of ten interference filters for the UV and VIS spectral region were flown on the surface of the Long Duration Exposure Facility (LDEF) Tray B-8 along with earth radiation budget (ERB) components from the Eppley Laboratory. Transmittance changes and other degradation observed after the return of the filters to Barr are reported. Substrates, coatings, and (where applicable) cement materials are identified. In general, all filters except those containing lead compounds survived well. Metal dielectric filters for the UV developed large numbers of pinholes which caused an increase in transmittance. Band shapes and spectral positioning, however, did not change.

  13. Using JWST Heritage to Enable a Future Large Ultra-Violet Optical Infrared Telescope

    NASA Technical Reports Server (NTRS)

    Feinberg, Lee

    2016-01-01

    To the extent it makes sense, leverage JWST knowledge, designs, architectures, GSE. Develop a scalable design reference mission (9.2 meter). Do just enough work to understand launch break points in aperture size. Demonstrate 10 pm stability is achievable on a design reference mission. Make design compatible with starshades. While segmented coronagraphs with high throughput and large bandpasses are important, make the system serviceable so you can evolve the instruments. Keep it room temperature to minimize the costs associated with cryo. Focus resources on the contrast problem. Start with the architecture and connect it to the technology needs.

  14. High-resolution ultra-violet observations of the interstellar diffuse clouds toward Mu Columbae

    NASA Technical Reports Server (NTRS)

    Sofia, Ulysses J.; Savage, Blair D.; Cardelli, Jason A.

    1993-01-01

    Data obtained from the Goddard High Resolution spectrograph (GHRS) are used to study differences in gas-phase abundances of ions occurring in the diffuse neutral clouds toward mu Col. The sight-line characteristics determined in previous studies are reviewed and results for the cloud velocities, absorption equivalent widths, ion column densities, and depletions are presented. It is found that interstellar features from four distinct absorption regions with low-ionization gas are apparent in the GHRS data at heliocentric velocities of 23, 41, 53, and 62 km/s. Absorption by Mg II, Si II, and possibly Al II also occurs over the heliocentric velocity range from -17 to 0 km/s. The presence of stronger Si III absorption over this velocity region indicates that the absorption arises from an ionized gas region.

  15. A Fourier transform spectrometer for visible and near ultra-violet measurements of atmospheric absorption

    NASA Technical Reports Server (NTRS)

    Parsons, C. L.; Gerlach, J. C.; Whitehurst, M.

    1982-01-01

    The development of a prototype, ground-based, Sun-pointed Michelson interferometric spectrometer is described. Its intended use is to measure the atmospheric amount of various gases which absorb in the near-infrared, visible, and near-ultraviolet portions of the electromagnetic spectrum. Preliminary spectra which contain the alpha, 0.8 micrometer, and rho sigma tau water vapor absorption bands in the near-infrared are presented to indicate the present capability of the system. Ultimately, the spectrometer can be used to explore the feasible applications of Fourier transform spectroscopy in the ultraviolet where grating spectrometers were used exclusively.

  16. White Light Coronagraph (WLC) and Ultra-Violet Coronal Spectrometer (UVCS)

    NASA Technical Reports Server (NTRS)

    Moore, R.

    1986-01-01

    The WLC and UVS together reveal the corona and the roots of the solar wind from 1.5 to 6 solar radii from sun center. The WLC measures the plasma density and spatial structure of the corona and coronal mass ejections at a plasma density and spatial structure of the corona and coronal mass ejections at a resolution of about 20 arcsec. The UVCS in combination with the WLC measures the temperature and radial outflow speed of the coronal plasma. These instruments will detect mass ejections from active regions and high speed solar wind streams from coronal holes a few days before the source regions rotate onto the face of the Sun, thus giving a week or more of advanced warning for disturbed geomagnetic conditions at Earth.

  17. White Light Coronograph (WLC) and Ultra-Violet Coronal Spectrometer (UVCS)

    NASA Technical Reports Server (NTRS)

    Moore, R. L.

    1985-01-01

    The white light coronagraph (WLC) and ultraviolet coronal spectrometer (UVCS) together reveal the corona and the roots of the solar wind from 1.5 to 6 solar radii from Sun center. The WLC measures the plasma density and spatial structure of the corona and coronal mass ejections at a resolution of about 20 arcseconds. The UVCS, in combination with the WLC, measures the temperature and radial outflow speed of the coronal plasma. These instruments will detect mass ejections from active regions and high speed solar wind streams from coronal holes a few days before the source regions rotate onto the face of the Sun, thus giving a week or more of advanced warning for disturbed geomagnetic conditions at Earth.

  18. Noise analysis of a CCD based ultra-violet spectrometry system

    NASA Astrophysics Data System (ADS)

    Davenport, J. J.; Hodgkinson, J.; Saffell, J. R.; Tatam, R. P.

    2012-04-01

    We present the results of a study into the noise behaviour of an Avaspec-3648 CCD UV spectrometer for use in a spectroscopic gas detection system. A comparison was made between a deuterium UV lamp and a range of newly developed UV LEDs. A number of noise phenomena were identified and quantified including source fluctuation noise, photo-response non-uniformity (PRNU), dark current noise, fixed pattern noise (FPN) and read noise. For spectral measurements the dominant noise phenomenon was PRNU, giving a noise equivalent absorption (NEA) of 8 x 10-3 AU. A set of noise limitation techniques is presented, which decreases the NEA to 2 x 10-3 AU.

  19. [Optical multi-channel detection and analysis on solar ultra-violet irradiance spectrum].

    PubMed

    Zhao, Xiao-yan; He, Jie; Zuo, Hao-yi; Liang, Hui-min; Yang, Jing-guo

    2007-05-01

    The present paper reports a new type of ultraviolet CCD optical multi-channel analyzer and its application to detecting solar ultraviolet irradiance spectrum. Spectral detecting range of 200-1 100 nm, spectral resolution of 0.1 nm and detecting sensitivity of 0.02 lx were reached in this instrument. The solar spectra of UVB and UVA were measured in real time in Chengdu area. The measurement results have good correlation with the detection using normal solar ultraviolet irradiance detector. Primary analysis on the detection results of solar spectra in UVB and UVA indicated that in the morning and in the afternoon the irradiance of solar ultraviolet is smaller than that at noon, and reverse correlation holds for the change of SZA (Solar Zenith Angle). In different wavelength interval of UVA and UVB, generally, the radiation flux of long wavelength is greater than that of short. Clouds and aerosols in the atmosphere have important influence on ultraviolet irradiance.

  20. Electronic structure of germanium selenide investigated using ultra-violet photo-electron spectroscopy

    NASA Astrophysics Data System (ADS)

    Mishra, P.; Lohani, H.; Kundu, A. K.; Patel, R.; Solanki, G. K.; Menon, Krishnakumar S. R.; Sekhar, B. R.

    2015-07-01

    The valence band electronic structure of GeSe single crystals has been investigated using angle resolved photoemission spectroscopy (ARPES) and x-ray photoelectron spectroscopy. The experimentally observed bands from ARPES, match qualitatively with our LDA-based band structure calculations along the Γ-Z, Γ-Y and Γ-T symmetry directions. The valence band maximum occurs nearly midway along the Γ-Z direction, at a binding energy of -0.5 eV, substantiating the indirect band gap of GeSe. Non-dispersive features associated with surface states and indirect transitions have been observed. The difference in hybridization of Se and Ge 4p orbitals leads to the variation of dispersion along the three symmetry directions. The predominance of the Se 4pz orbitals, evidenced from theoretical calculations, may be the cause for highly dispersive bands along the Γ-T direction. Detailed electronic structure analysis reveals the significance of the cation-anion 4p orbitals hybridization in the valence band dispersion of IV-VI semiconductors. This is the first comprehensive report of the electronic structure of a GeSe single crystal using ARPES in conjugation with theoretical band structure analysis.

  1. Solar Spectral Irradiance, Solar Activity, and the Near-Ultra-Violet

    NASA Astrophysics Data System (ADS)

    Fontenla, J. M.; Stancil, P. C.; Landi, E.

    2015-08-01

    The previous calculations of the Solar Spectral Irradiance (SSI) by the Solar Radiation Physical Modeling, version 2 system, are updated in this work by including new molecular photodissociation cross-sections of important species, and many more levels and lines in its treatment of non-LTE radiative transfer. The current calculations including the new molecular photodissociation opacities produce a reduced over-ionizaton of heavy elements in the lower chromosphere and solve the problems with prior studies of the UV SSI in the wavelength range 160-400 nm and now reproduce the available observations with much greater accuracy. Calculations and observations of the near-UV at 0.1 nm resolution and higher are compared. The current set of physical models includes four quiet-Sun and five active-region components, from which radiance is computed for ten observing angles. These radiances are combined with images of the solar disk to obtain the SSI and Total Solar Irradiance and their variations. The computed SSI is compared with measurements from space at several nm resolution and agreement is found within the accuracy level of these measurements. An important result is that the near-UV SSI increase with solar activity is significant for the photodissociation of ozone in the terrestrial atmosphere because a number of highly variable upper chromospheric lines overlap the ozone Hartley band.

  2. Observing the Forest Canopy with a New Ultra-Violet Compact Airborne Lidar

    PubMed Central

    Cuesta, Juan; Chazette, Patrick; Allouis, Tristan; Flamant, Pierre H.; Durrieu, Sylvie; Sanak, Joseph; Genau, Pascal; Guyon, Dominique; Loustau, Denis; Flamant, Cyrille

    2010-01-01

    We have developed a new airborne UV lidar for the forest canopy and deployed it in the Landes forest (France). It is the first one that: (i) operates at 355 nm for emitting energetic pulses of 16 mJ at 20 Hz while fulfilling eye-safety regulations and (ii) is flown onboard an ultra-light airplane for enhanced flight flexibility. Laser footprints at ground level were 2.4 m wide for a flying altitude of 300 m. Three test areas of ∼500 × 500 m2 with Maritime pines of different ages were investigated. We used a threshold method adapted for this lidar to accurately extract from its waveforms detailed forest canopy vertical structure: canopy top, tree crown base and undergrowth heights. Good detection sensitivity enabled the observation of ground returns underneath the trees. Statistical and one-to-one comparisons with ground measurements by field foresters indicated a mean absolute accuracy of ∼1 m. Sensitivity tests on detection threshold showed the importance of signal to noise ratio and footprint size for a proper detection of the canopy vertical structure. This UV-lidar is intended for future innovative applications of simultaneous observation of forest canopy, laser-induced vegetation fluorescence and atmospheric aerosols. PMID:22163608

  3. Observing the forest canopy with a new ultra-violet compact airborne lidar.

    PubMed

    Cuesta, Juan; Chazette, Patrick; Allouis, Tristan; Flamant, Pierre H; Durrieu, Sylvie; Sanak, Joseph; Genau, Pascal; Guyon, Dominique; Loustau, Denis; Flamant, Cyrille

    2010-01-01

    We have developed a new airborne UV lidar for the forest canopy and deployed it in the Landes forest (France). It is the first one that: (i) operates at 355 nm for emitting energetic pulses of 16 mJ at 20 Hz while fulfilling eye-safety regulations and (ii) is flown onboard an ultra-light airplane for enhanced flight flexibility. Laser footprints at ground level were 2.4 m wide for a flying altitude of 300 m. Three test areas of ≈ 500 × 500 m(2) with Maritime pines of different ages were investigated. We used a threshold method adapted for this lidar to accurately extract from its waveforms detailed forest canopy vertical structure: canopy top, tree crown base and undergrowth heights. Good detection sensitivity enabled the observation of ground returns underneath the trees. Statistical and one-to-one comparisons with ground measurements by field foresters indicated a mean absolute accuracy of ≈ 1 m. Sensitivity tests on detection threshold showed the importance of signal to noise ratio and footprint size for a proper detection of the canopy vertical structure. This UV-lidar is intended for future innovative applications of simultaneous observation of forest canopy, laser-induced vegetation fluorescence and atmospheric aerosols.

  4. [Optical multi-channel detection and analysis on solar ultra-violet irradiance spectrum].

    PubMed

    Zhao, Xiao-yan; He, Jie; Zuo, Hao-yi; Liang, Hui-min; Yang, Jing-guo

    2007-05-01

    The present paper reports a new type of ultraviolet CCD optical multi-channel analyzer and its application to detecting solar ultraviolet irradiance spectrum. Spectral detecting range of 200-1 100 nm, spectral resolution of 0.1 nm and detecting sensitivity of 0.02 lx were reached in this instrument. The solar spectra of UVB and UVA were measured in real time in Chengdu area. The measurement results have good correlation with the detection using normal solar ultraviolet irradiance detector. Primary analysis on the detection results of solar spectra in UVB and UVA indicated that in the morning and in the afternoon the irradiance of solar ultraviolet is smaller than that at noon, and reverse correlation holds for the change of SZA (Solar Zenith Angle). In different wavelength interval of UVA and UVB, generally, the radiation flux of long wavelength is greater than that of short. Clouds and aerosols in the atmosphere have important influence on ultraviolet irradiance. PMID:17655086

  5. Physical-Mechanical Properties of Nitrodopes Affected by Ultra-Violet Radiation

    PubMed Central

    Cakić, Suzana; Raskovic, Ljiljana; Lačnjevac, Časlav; Rajkovic, Milos; Barać, Miroljub; Stojanovic, Miodrag

    2007-01-01

    The FTIR spectroscopy has been employed in this research work to monitor the process of nitrodope photodegradation, by measuring surfaces of bands typical of a nitro group. Nitric esters are subject to degradation, which is reflected on a quantitative ratio of the surfaces of the IR bands that originate from the nitric ester. The obtained results show that the length of the UV rays' activity on the samples over the time periods of 240, 480 and 960 minutes directly affects the spectrum appearance of the same sample before and after the irradiation. The longer the action time of the UV rays and the higher a mass percentage of nitrocellulose in the nitrodope is, the smaller the bands' surfaces become, i.e. the level of degradation is higher. In order to confirm the degradation of nitrodope, the degree of crosslinking has also been examined by determining the König hardness and also the mean viscosity molar mass has been defined repeatedly applying the capillary viscosimetry method.

  6. Measurements of ultra-violet titanium lines in laser-ablation plasma

    NASA Astrophysics Data System (ADS)

    Parigger, Christian G.; Woods, Alexander C.; Surmick, David M.; Swafford, Lauren D.; Witte, Michael J.

    2014-09-01

    We present Stark broadened atomic titanium lines recorded following laser-induced optical break during ablation of a 99.999% pure titanium sample. The UV lines reveal electron density on the order of 20 to 60 × 1023 m- 3, and the electron temperature is estimated to be on the order of 40,000 K some 200 ns after the ablation process. In our study of the modified semi-empirical approach, we conclude that our results favor the standard Gaunt factor without the requirement of introducing an additional effective Gaunt factor, that others appear to use.

  7. Simultaneous efficient removal of high-strength ammonia nitrogen and chemical oxygen demand from landfill leachate by using an extremely high ammonia nitrogen-resistant strain.

    PubMed

    Yu, Dahai; Yang, Jiyu; Fang, Xuexun; Ren, Hejun

    2015-01-01

    Bioaugmentation is a promising technology for pollutant elimination from stressed environments, and it would provide an efficient way to solve challenges in traditional biotreatment of wastewater with high strength of ammonia nitrogen (NH4(+)-N). A high NH4(+)-N-resistant bacteria strain, identified as Bacillus cereus (Jlu BC), was domesticated and isolated from the bacteria consortium in landfill leachate. Jlu BC could survive in 100 g/L NH4(+)-N environment, which indicated its extremely high NH4(+)-N tolerance than the stains found before. Jlu BC was employed in the bioaugmented system to remove high strength of NH4(+)-N from landfill leachate, and to increase the removal efficiency, response surface methodology (RSM) was used for optimizing bioaugmentation degradation conditions. At the optimum condition (initial pH 7.33, 4.14 days, initial chemical oxygen demand [COD] concentration [18,000 mg/L], 3.5 mL inoculated domesticated bacteria strain, 0.3 mg/mL phosphorus supplement, 30 °C, and 170 rpm), 94.74 ± 3.8% removal rate of NH4(+)-N was obtained, and the experiment data corresponded well with the predicted removal rate of the RSM models (95.50%). Furthermore, COD removal rate of 81.94 ± 1.4% was obtained simultaneously. The results presented are promising, and the screened strain would be of great practical importance in mature landfill leachate and other NH4(+)-N enrichment wastewater pollution control.

  8. On the maximum conversion efficiency into the 13.5-nm extreme ultraviolet emission under a steady-state laser ablation of tin microspheres

    NASA Astrophysics Data System (ADS)

    Basko, M. M.

    2016-08-01

    Theoretical investigation has been performed on the conversion efficiency (CE) into the 13.5-nm extreme ultraviolet (EUV) radiation in a scheme where spherical microspheres of tin (Sn) are simultaneously irradiated by two laser pulses with substantially different wavelengths. The low-intensity short-wavelength pulse is used to control the rate of mass ablation and the size of the EUV source, while the high-intensity long-wavelength pulse provides efficient generation of the EUV light at λ=13.5 nm. The problem of full optimization for maximizing the CE is formulated and solved numerically by performing two-dimensional radiation-hydrodynamics simulations with the RALEF-2D code under the conditions of steady-state laser illumination. It is shown that, within the implemented theoretical model, steady-state CE values approaching 9% are feasible; in a transient peak, the maximum instantaneous CE of 11.5% was calculated for the optimized laser-target configuration. The physical factors, bringing down the fully optimized steady-state CE to about one half of the absolute theoretical maximum of CE≈20 % for the uniform static Sn plasma, are analyzed in detail.

  9. Low-loss smile-insensitive external frequency-stabilization of high power diode lasers enabled by vertical designs with extremely low divergence angle and high efficiency

    NASA Astrophysics Data System (ADS)

    Crump, Paul; Knigge, Steffen; Maaßdorf, Andre; Bugge, Frank; Hengesbach, Stefan; Witte, Ulrich; Hoffmann, Hans-Dieter; Köhler, Bernd; Hubrich, Ralf; Kissel, Heiko; Biesenbach, Jens; Erbert, Götz; Traenkle, Guenther

    2013-02-01

    Broad area lasers with narrow spectra are required for many pumping applications and for wavelength beam combination. Although monolithically stabilized lasers show high performance, some applications can only be addressed with external frequency stabilization, for example when very narrow spectra are required. When conventional diode lasers with vertical far field angle, ΘV 95% ~ 45° (95% power) are stabilized using volume holographic gratings (VHGs), optical losses are introduced, limiting both efficiency and reliable output power, with the presence of any bar smile compounding the challenge. Diode lasers with designs optimized for extremely low vertical divergence (ELOD lasers) directly address these challenges. The vertical far field angle in conventional laser designs is limited by the waveguiding of the active region itself. In ELOD designs, quantum barriers are used that have low refractive index, enabling the influence of the active region to be suppressed, leading to narrow far field operation from thin vertical structures, for minimal electrical resistance and maximum power conversion efficiency. We review the design process, and show that 975 nm diode lasers with 90 μm stripes that use ELOD designs operate with ΘV 95% = 26° and reach 58% power conversion efficiency at a CW output power of 10 W. We demonstrate directly that VHG stabilized ELOD lasers have significantly lower loss and larger operation windows than conventional lasers in the collimated feedback regimes, even in the presence of significant (≥ 1 μm) bar smile. We also discuss the potential influence of ELOD designs on reliable output power and options for further performance improvement.

  10. Semi-rational engineering of a coral fluorescent protein into an efficient highlighter.

    PubMed

    Tsutsui, Hidekazu; Karasawa, Satoshi; Shimizu, Hideaki; Nukina, Nobuyuki; Miyawaki, Atsushi

    2005-03-01

    Kaede is a natural photoconvertible fluorescent protein found in the coral Trachyphyllia geoffroyi. It contains a tripeptide, His 62-Tyr 63-Gly 64, which acts as a green chromophore that is photoconvertible to red following (ultra-) violet irradiation. Here, we report the molecular cloning and crystal structure determination of a new fluorescent protein, KikG, from the coral Favia favus, and its in vitro evolution conferring green-to-red photoconvertibility. Substitution of the His 62-Tyr 63-Gly 64 sequence into the native protein provided only negligible photoconversion. On the basis of the crystal structure, semi-rational mutagenesis of the amino acids surrounding the chromophore was performed, leading to the generation of an efficient highlighter, KikGR. Within mammalian cells, KikGR is more efficiently photoconverted and is several-fold brighter in both the green and red states than Kaede. In addition, KikGR was successfully photoconverted using two-photon excitation microscopy at 760 nm, ensuring optical cell labelling with better spatial discrimination in thick and highly scattering tissues.

  11. Efficient, green laser based on a blue-diode pumped rare-earth-doped fluoride crystal in an extremely short resonator

    NASA Astrophysics Data System (ADS)

    Strotkamp, Michael; Schwarz, Thomas; Jungbluth, Bernd; Faidel, Heinrich; Leers, Michael

    2010-02-01

    The green cw laser presented in this work is realized by means of a Pr:YLF crystal emitting at 523 nm that is pumped by a blue GaN laser diode in an extremely short resonator. With a 500 mW-diode a laser has been achieved with M2 = 1, a slope of 40 % and an output power of 140mW with an absorbed pump power of 410 mW which results in an electrooptical efficiency of 6.5 %. Despite the reduced overlap with a 1 W-diode the output power rises to 290 mW with an absorbed pump power of 850 mW and the M2 increases only slightly. Based on these results a compact laser package has been accomplished using a monolithic micro optics for the beam shaping of the diode light and joining all components with a low-shrinkage adhesive on a common base plate. In a first test of the alignment strategy a laser with an output power of 92 mW has been achieved by means of the 500 mW pump power.

  12. Energy efficient--advanced oxidation process for treatment of cyanide containing automobile industry wastewater.

    PubMed

    Mudliar, R; Umare, S S; Ramteke, D S; Wate, S R

    2009-05-30

    Destruction of cyanide (CN) from an automobile industry wastewater by advance oxidation process (AOP) has been evaluated. The operating conditions (in an indigenously designed photoreactor) for three different treatment strategies have been optimized. The treatment strategies involved use of, ultra violet light (UV), hydrogen peroxide (H(2)O(2)) and ozone (O(3)) in various combinations. Treatment of automobile industry wastewater (250 mg/L CN) showed fastest CN destruction, which was significantly (P<0.05) faster than that observed with synthetic wastewater (with similar CN concentration). A combined application of H(2)O(2)/O(3) was found to be the best option for maximum CN destruction. This treatment allows CN to reach the regional/international limit (of 0.02 mg/L) for safe industrial wastewater discharges to the receiving water bodies. The specific energy consumption by the photoreactor following this treatment was comparable to that obtained by conventional treatments, which use photocatalyst. Since the present treatment does not use catalyst, it provides an excellent energy efficient and economical option for treatment and safe disposal of CN containing industrial wastewater.

  13. High efficiency generalized transduction in Escherichia coli O157:H7.

    PubMed

    Marinus, Martin G; Poteete, Anthony R

    2013-01-01

    Genetic manipulation in enterohemorrhagic E. coli O157:H7 is currently restricted to recombineering, a method that utilizes the recombination system of bacteriophage lambda, to introduce gene replacements and base changes inter alia into the genome. Bacteriophage 933W is a prophage in E. coli O157:H7 strain EDL933, which encodes the genes ( stx2AB) for the production of Shiga toxin which is the basis for the potentially fatal Hemolytic Uremic Syndrome in infected humans. We replaced the stx2AB genes with a kanamycin cassette using recombineering. After induction of the prophage by ultra-violet light, we found that bacteriophage lysates were capable of transducing to wildtype, point mutations in the lactose, arabinose and maltose genes. The lysates could also transduce tetracycline resistant cassettes. Bacteriophage 933W is also efficient at transducing markers in E. coli K-12. Co-transduction experiments indicated that the maximal amount of transferred DNA was likely the size of the bacteriophage genome, 61 kB. All tested transductants, in both E. coli K-12 and O157:H7, were kanamycin-sensitive indicating that the transducing particles contained host DNA.

  14. Investigation of the patterning efficiency in a new azo-dye copolymer under UV irradiation toward photonic applications

    NASA Astrophysics Data System (ADS)

    Rocha, Licinio; Fiorini, Céline; Matczyszyn, Katarzyna; Raimond, Paul; Nunzi, Jean-Michel

    2008-04-01

    Azo-polymers have been the subject of a growing interest since the first demonstration of reversible birefringence and dichroism effects induced optically at room temperature in such materials. It is well established that the mechanisms involved are related to a molecular reorientation following photo induced trans-cis-trans isomerization of the chromophores. The interest for such materials has been strengthened with the more recent demonstration that the photo-isomerization mechanisms can be employed to induce controlled topographic modifications. A simple example is the induction of a sinusoidal modulation of the film surface by the irradiation with an interference pattern between two laser beams. Such a simple step technique appears thus as a simple tool towards realisation of photonic devices. However, if the realisation of gratings with periods in the visible wavelength scale is widely investigated, a strong decrease of the patterning efficiency is observed in the case of periods below 400nm, limiting then the potential of the technique. In order to circumvent this problem we have developed a new azo-polymer presenting an absorption band shifted to the Ultra Violet (UV) region of the spectrum. The possibility to induce gratings with periods down to 200nm with UV irradiation is evidenced. Optical geometries of excitation have been implemented to optimise the modulation efficiencies. As a potential application of the material investigated, the realisation of a polymer micro laser based on a distributed feedback scheme is demonstrated.

  15. Comparison and characterization of efficient frequency doubling at 397.5 nm with PPKTP, LBO and BiBO crystals

    NASA Astrophysics Data System (ADS)

    Wen, Xin; Han, Yashuai; Wang, Junmin

    2016-04-01

    A continuous-wave Ti:sapphire laser at 795 nm is frequency doubled in a bow-tie type enhancement four-mirror ring cavity with LiB3O5 (LBO), BiB3O6 (BiBO), and periodically polled KTiOPO4 (PPKTP) crystals, respectively. The properties of 397.5 nm ultra-violet (UV) output power, beam quality, stability for these different nonlinear crystals are investigated and compared. For PPKTP crystal, the highest doubling efficiency of 58.1% is achieved from 191 mW of 795 nm mode-matched fundamental power to 111 mW of 397.5 nm UV output. For LBO crystal, with 1.34 W of mode-matched 795 nm power, 770 mW of 397.5 nm UV output is achieved, implying a doubling efficiency of 57.4%. For BiBO crystal, with 323 mW of mode-matched 795 nm power, 116 mW of 397.5 nm UV output is achieved, leading to a doubling efficiency of 35.9%. The generated UV radiation has potential applications in the fields of quantum physics.

  16. Novel Nanophosphors for High Efficiency Fluorescent Lamps

    SciTech Connect

    Alok Srivatava

    2007-03-31

    This is the Final Report of the Novel Nanophosphors for High Efficiency Fluorescent Lamps, Department of Energy (DOE). The overall goal of this three-year program is to develop novel hybrid phosphors by coating commercially available lamp phosphors with highly stable wide band-gap nanocrystalline phosphors (NCP). The prime technical approach is the development of NCP quantum-splitting phosphor (QSP) and ultra-violet (UV) emitting phosphors with quantum efficiencies exceeding that of the conventional phosphors at 185 nm. The novel hybrid phosphors will increase the efficiency of the fluorescent lamps by up to 32%, enabling total energy savings of 0.26 quads, the reduction in the U.S. energy bill by $6.5 billion and the reduction of the annual carbon emission by 4.1 billion kilogram. Our work started by investigating through modeling calculations the requirement for the particle size of the NCP. Our work to develop suitable nanocrystalline phosphors started with the known oxide quantum splitting and UV emitting phosphors. We demonstrated several synthesis techniques for the production of high quality nanocrystalline materials that crystallizes in the desired phase and with the desired particle size. In collaboration with our subcontractor we demonstrated the feasibility for the manufacture of NC phosphors. We also demonstrated novel techniques of coating the NCP on the surface of micron sized phosphors. Our chief achievement pertains to the successful testing of the coated hybrid phosphor systems in linear fluorescent lamps. In linear fluorescent lamp tests, we have demonstrated up to 7% increase in the efficacy of hybrid phosphors over the conventional (uncoated) phosphors. We have also demonstrated the improvement in the lumen maintenance of the coated phosphors. A hybrid phosphor system based on the commercial red emitting phosphor, Y{sub 2}O{sub 3}:Eu{sup 3+} did not show the anticipated improvement in lamp efficacy. We explored the reasons for this observation

  17. The energy-down-shift effect of Cd(0.5)Zn(0.5)S-ZnS core-shell quantum dots on power-conversion-efficiency enhancement in silicon solar cells.

    PubMed

    Baek, Seung-Wook; Shim, Jae-Hyoung; Park, Jea-Gun

    2014-09-14

    We found that Cd0.5Zn0.5S-ZnS core (4.2 nm in diameter)-shell (1.2 nm in thickness) quantum dots (QDs) demonstrated a typical energy-down-shift (2.76-4.96 → 2.81 eV), which absorb ultra-violet (UV) light (250-450 nm in wavelength) and emit blue visible light (∼442 nm in wavelength). They showed the quantum yield of ∼80% and their coating on the SiNX film textured p-type silicon solar-cells enhanced the external-quantum-efficiency (EQE) of ∼30% at 300-450 nm in wavelength, thereby enhancing the short-circuit-current-density (JSC) of ∼2.23 mA cm(-2) and the power-conversion-efficiency (PCE) of ∼1.08% (relatively ∼6.04% increase compared with the reference without QDs for p-type silicon solar-cells). In particular, the PCE peaked at a specific coating thickness of the Cd0.5Zn0.5S-ZnS core-shell QD layer; i.e., the 1.08% PCE enhancement at the 8.8 nm thick QD layer.

  18. Diffraction efficiency of 200-nm-period critical-angle transmission gratings in the soft x-ray and extreme ultraviolet wavelength bands

    SciTech Connect

    Heilmann, Ralf K.; Ahn, Minseung; Bruccoleri, Alex; Chang, Chih-Hao; Gullikson, Eric M.; Mukherjee, Pran; Schattenburg, Mark L.

    2011-04-01

    We report on measurements of the diffraction efficiency of 200-nm-period freestanding blazed transmission gratings for wavelengths in the 0.96 to 19.4 nm range. These critical-angle transmission (CAT) gratings achieve highly efficient blazing over a broad band via total external reflection off the sidewalls of smooth, tens of nanometer thin ultrahigh aspect-ratio silicon grating bars and thus combine the advantages of blazed x-ray reflection gratings with those of more conventional x-ray transmission gratings. Prototype gratings with maximum depths of 3.2 and 6 {mu}m were investigated at two different blaze angles. In these initial CAT gratings the grating bars are monolithically connected to a cross support mesh that only leaves less than half of the grating area unobstructed. Because of our initial fabrication approach, the support mesh bars feature a strongly trapezoidal cross section that leads to varying CAT grating depths and partial absorption of diffracted orders. While theory predicts broadband absolute diffraction efficiencies as high as 60% for ideal CAT gratings without a support mesh, experimental results show efficiencies in the range of {approx}50-100% of theoretical predictions when taking the effects of the support mesh into account. Future minimization of the support mesh therefore promises broadband CAT grating absolute diffraction efficiencies of 50% or higher.

  19. Stability and efficiency of dye-sensitized solar cells based on papaya-leaf dye

    NASA Astrophysics Data System (ADS)

    Suyitno, Suyitno; Saputra, Trisma Jaya; Supriyanto, Agus; Arifin, Zainal

    2015-09-01

    The present article reports on the enhancement of the performance and stability of natural dye-based dye-sensitized solar cells (DSSCs). Natural dyes extracted from papaya leaves (PL) were investigated as sensitizers in TiO2-based DSSCs and evaluated in comparison with N719 dye. The acidity of the papaya-leaf extract dyes was tuned by adding benzoic acid. The TiO2 film-coated fluorine-doped tin oxide glass substrates were prepared using the doctor-blade method, followed by sintering at 450 °C. The counter electrode was coated by chemically deposited catalytic platinum. The working electrodes were immersed in N719 dye and papaya dye solutions with concentrations of 8 g/100 mL. The absorbance spectra of the dyes were obtained by ultra-violet-visible spectroscopy. The energy levels of the dyes were measured by the method of cyclic voltammetry. In addition, Fourier transform infrared spectroscopy was used to determine the characteristic functionalities of the dye molecules. The DSSC based on the N719 dye displayed a highest efficiency of 0.87% whereas those based on papaya-leaf dye achieved 0.28% at pH 3.5. The observed improved efficiency of the latter was attributed to the increased current density value. Furthermore, the DSSCs based on papaya-leaf dye with pH 3.5-4 exhibited better stability than those based on N719 dye. However, further studies are required to improve the current density and stability of natural dye-based DSSCs, including the investigation of alternative dye extraction routes, such as isolating the pure chlorophyll from papaya leaves and stabilizing it.

  20. Stability and efficiency of dye-sensitized solar cells based on papaya-leaf dye.

    PubMed

    Suyitno, Suyitno; Saputra, Trisma Jaya; Supriyanto, Agus; Arifin, Zainal

    2015-09-01

    The present article reports on the enhancement of the performance and stability of natural dye-based dye-sensitized solar cells (DSSCs). Natural dyes extracted from papaya leaves (PL) were investigated as sensitizers in TiO2-based DSSCs and evaluated in comparison with N719 dye. The acidity of the papaya-leaf extract dyes was tuned by adding benzoic acid. The TiO2 film-coated fluorine-doped tin oxide glass substrates were prepared using the doctor-blade method, followed by sintering at 450 °C. The counter electrode was coated by chemically deposited catalytic platinum. The working electrodes were immersed in N719 dye and papaya dye solutions with concentrations of 8 g/100 mL. The absorbance spectra of the dyes were obtained by ultra-violet-visible spectroscopy. The energy levels of the dyes were measured by the method of cyclic voltammetry. In addition, Fourier transform infrared spectroscopy was used to determine the characteristic functionalities of the dye molecules. The DSSC based on the N719 dye displayed a highest efficiency of 0.87% whereas those based on papaya-leaf dye achieved 0.28% at pH 3.5. The observed improved efficiency of the latter was attributed to the increased current density value. Furthermore, the DSSCs based on papaya-leaf dye with pH 3.5-4 exhibited better stability than those based on N719 dye. However, further studies are required to improve the current density and stability of natural dye-based DSSCs, including the investigation of alternative dye extraction routes, such as isolating the pure chlorophyll from papaya leaves and stabilizing it. PMID:25875031

  1. Stability and efficiency of dye-sensitized solar cells based on papaya-leaf dye.

    PubMed

    Suyitno, Suyitno; Saputra, Trisma Jaya; Supriyanto, Agus; Arifin, Zainal

    2015-09-01

    The present article reports on the enhancement of the performance and stability of natural dye-based dye-sensitized solar cells (DSSCs). Natural dyes extracted from papaya leaves (PL) were investigated as sensitizers in TiO2-based DSSCs and evaluated in comparison with N719 dye. The acidity of the papaya-leaf extract dyes was tuned by adding benzoic acid. The TiO2 film-coated fluorine-doped tin oxide glass substrates were prepared using the doctor-blade method, followed by sintering at 450 °C. The counter electrode was coated by chemically deposited catalytic platinum. The working electrodes were immersed in N719 dye and papaya dye solutions with concentrations of 8 g/100 mL. The absorbance spectra of the dyes were obtained by ultra-violet-visible spectroscopy. The energy levels of the dyes were measured by the method of cyclic voltammetry. In addition, Fourier transform infrared spectroscopy was used to determine the characteristic functionalities of the dye molecules. The DSSC based on the N719 dye displayed a highest efficiency of 0.87% whereas those based on papaya-leaf dye achieved 0.28% at pH 3.5. The observed improved efficiency of the latter was attributed to the increased current density value. Furthermore, the DSSCs based on papaya-leaf dye with pH 3.5-4 exhibited better stability than those based on N719 dye. However, further studies are required to improve the current density and stability of natural dye-based DSSCs, including the investigation of alternative dye extraction routes, such as isolating the pure chlorophyll from papaya leaves and stabilizing it.

  2. On symmetric X-ray beam splitting with high efficiency by use of reflection gratings with rectangular profile in the extreme off-plane configuration.

    PubMed

    Jark, Werner; Eichert, Diane

    2015-08-24

    In order to be reflected or diffracted off a surface structure soft X-rays and hard X-rays need to impinge at grazing angles of incidence onto the surface. In case of a reflection grating of highly symmetric structure with rectangular groove profile these grooves can be oriented parallel to the beam trajectory. In such a symmetric situation the distribution of the diffracted intensity with respect to the plane of incidence is then expected to be symmetric. This is indeed observed with symmetrically oriented diffraction peaks. It can be predicted that for appropriate structure parameters the intensity can be contained mostly in two symmetrically oriented diffraction peaks. This will also be the case for hard X-rays. The diffraction efficiency will be particularly high, when the angle of grazing incidence is chosen in the total reflection regime below the critical angle of the grating coating. These predictions were experimentally verified in this work for hard X-rays with photon energies between 4 keV and 12.4 keV. In the experiment of the order of 30% of the incident intensity was diffracted into the two first orders. This is to be compared to reflectivities of the order of 50% measured at the same coating in an unruled area of the substrate. Consequently the relative structural diffraction efficiency for each first order was about 30%, while ideally it could have been 40%. The presented grating structure will thus be a rather efficient amplitude beam splitter for hard X-rays, e.g. in the coherent beam from a free electron laser. In addition such object could then be used as the first component in Michelson interferometers for the beam characterisation or for introducing a time delay between two coherent beams.

  3. CMCTS stabilized Fe3O4 particles with extremely low toxicity as highly efficient near-infrared photothermal agents for in vivo tumor ablation

    NASA Astrophysics Data System (ADS)

    Shen, Song; Kong, Fenfen; Guo, Xiaomeng; Wu, Lin; Shen, Haijun; Xie, Meng; Wang, Xinshi; Jin, Yi; Ge, Yanru

    2013-08-01

    With the potential uses of photothermal therapy (PTT) in cancer treatment with excellent efficacy, and the growing concerns about the nanotoxicity of hyperthermia agents such as carbon nanotubes and gold-based nanomaterials, the importance of searching for a biocompatible hyperthermia agent cannot be emphasized too much. In this work, a novel promising hyperthermia agent employing magnetic Fe3O4 particles with fairly low toxicity was proposed. This hyperthermia agent showed rapid heat generation under NIR irradiation. After modification with carboxymethyl chitosan (CMCTS), the obtained Fe3O4@CMCTS particles could disperse stably in PBS and serum without any aggregation. The modification of CMCTS could decrease the adsorption of bovine serum albumin (BSA) and improve the cellular uptake. In a comparative study with hollow gold nanospheres (HAuNS), Fe3O4@CMCTS particles exhibited a comparable photothermal effect and fairly low cytotoxicity. The in vivo magnetic resonance (MR) images of mice revealed that by attaching a magnet to the tumor, Fe3O4@CMCTS particles accumulated in the tumor after intravenous injection and showed a low distribution in the liver. After being exposed to a 808 nm laser for 5 min at a low power density of 1.5 W cm-2, the tumors on Fe3O4@CMCTS-injected mice reached a temperature of ~52 °C and were completely destroyed. Thus, a kind of multifunctional magnetic nanoparticle with extremely low toxicity and a simple structure for simultaneous MR imaging, targeted drug delivery and photothermal therapy can be easily fabricated.With the potential uses of photothermal therapy (PTT) in cancer treatment with excellent efficacy, and the growing concerns about the nanotoxicity of hyperthermia agents such as carbon nanotubes and gold-based nanomaterials, the importance of searching for a biocompatible hyperthermia agent cannot be emphasized too much. In this work, a novel promising hyperthermia agent employing magnetic Fe3O4 particles with fairly low

  4. Achieving Extreme Utilization of Excitons by an Efficient Sandwich-Type Emissive Layer Architecture for Reduced Efficiency Roll-Off and Improved Operational Stability in Organic Light-Emitting Diodes.

    PubMed

    Wu, Zhongbin; Sun, Ning; Zhu, Liping; Sun, Hengda; Wang, Jiaxiu; Yang, Dezhi; Qiao, Xianfeng; Chen, Jiangshan; Alshehri, Saad M; Ahamad, Tansir; Ma, Dongge

    2016-02-10

    It has been demonstrated that the efficiency roll-off is generally caused by the accumulation of excitons or charge carriers, which is intimately related to the emissive layer (EML) architecture in organic light-emitting diodes (OLEDs). In this article, an efficient sandwich-type EML structure with a mixed-host EML sandwiched between two single-host EMLs was designed to eliminate this accumulation, thus simultaneously achieving high efficiency, low efficiency roll-off and good operational stability in the resulting OLEDs. The devices show excellent electroluminescence performances, realizing a maximum external quantum efficiency (EQE) of 24.6% with a maximum power efficiency of 105.6 lm W(-1) and a maximum current efficiency of 93.5 cd A(-1). At the high brightness of 5,000 cd m(-2), they still remain as high as 23.3%, 71.1 lm W(-1), and 88.3 cd A(-1), respectively. And, the device lifetime is up to 2000 h at initial luminance of 1000 cd m(-2), which is significantly higher than that of compared devices with conventional EML structures. The improvement mechanism is systematically studied by the dependence of the exciton distribution in EML and the exciton quenching processes. It can be seen that the utilization of the efficient sandwich-type EML broadens the recombination zone width, thus greatly reducing the exciton quenching and increasing the probability of the exciton recombination. It is believed that the design concept provides a new avenue for us to achieve high-performance OLEDs.

  5. MAVEN Primary Mission Results from the Imaging UltraViolet Spectrograph: Aurora, Meteor Showers, Dayglow and Corona

    NASA Astrophysics Data System (ADS)

    Schneider, Nicholas

    2016-07-01

    The Imaging Ultraviolet Spectrograph (IUVS) is one of nine science instruments aboard the Mars Atmosphere and Volatile and EvolutioN (MAVEN) spacecraft. Its payload is dedicated to exploring the upper atmosphere of Mars and understanding the magnitude and drivers of Mars' atmospheric escape rate. The instrument is among the most powerful spectrographs sent to another planet, with several key capabilities: (1) separate Far-UV & Mid-UV channels for stray light control, (2) a high resolution echelle mode to resolve deuterium and hydrogen emission, (3) internal instrument pointing and scanning capabilities to allow complete mapping and nearly continuous operation, and (4) optimization for airglow studies. I will present an overview of selected IUVS results, including: • The impact of Comet Siding Spring's tail on Mars' atmosphere; • The discovery of diffuse aurora at Mars, and its contrast with previously detected discrete aurora near crustal fields; • Significant seasonal and short-timescale variability in thermospheric dayglow emissions; • Global ozone maps spanning six months of seasonal evolution; and • Mapping of the Mars H and O coronas, to measure the escape rates of H and O and their variability.

  6. Method and apparatus for generating coherent radiation in the ultra-violet region and above by use of distributed feedback

    NASA Technical Reports Server (NTRS)

    Saffren, M. M. (Inventor)

    1976-01-01

    Helium in the superfluid state emits copious amounts of radiation in the ultraviolet region when excited by an electron stream. Conventional laser action using mirrors is impossible in superfluid helium because there are no mirrors that will reflect VUV radiation. By utilizing the distributed feedback method, the superfluid helium can be made to lase. By setting up a standing wave in superfluid helium that has a wavelength equal to, or harmonically related to, half the wavelength of the photon radiation chosen to be emitted as laser radiation by the superfluid helium, the need for end mirrors to produce reflection of the laser radiation is eliminated and reflection occurs instead at the wavefronts of the standing wave. The photons leave the superfluid helium at right angles to the standing wave as coherent radiation having a very high intensity. The standing wave established in the superfluid helium may be an acoustical standing wave, a thermal standing wave (second sound), or an electric standing wave.

  7. Sub-mm Scale Fiber Guided Deep/Vacuum Ultra-Violet Optical Source for Trapped Mercury Ion Clocks

    NASA Technical Reports Server (NTRS)

    Yi, Lin; Burt, Eric A.; Huang, Shouhua; Tjoelker, Robert L.

    2013-01-01

    We demonstrate the functionality of a mercury capillary lamp with a diameter in the sub-mm range and deep ultraviolet (DUV)/ vacuum ultraviolet (VUV) radiation delivery via an optical fiber integrated with the capillary. DUV spectrum control is observed by varying the fabrication parameters such as buffer gas type and pressure, capillary diameter, electrical resonator design, and temperature. We also show spectroscopic data of the 199Hg+ hyper-fine transition at 40.5GHz when applying the above fiber optical design. We present efforts toward micro-plasma generation in hollow-core photonic crystal fiber with related optical design and theoretical estimations. This new approach towards a more practical DUV optical interface could benefit trapped ion clock developments for future ultra-stable frequency reference and time-keeping applications.

  8. Ultra-violet B (UVB)-induced skin cell death occurs through a cyclophilin D intrinsic signaling pathway

    SciTech Connect

    Ji, Chao; Yang, Bo; Yang, Zhi; Tu, Ying; Yang, Yan-li; He, Li; Bi, Zhi-Gang

    2012-09-07

    Highlights: Black-Right-Pointing-Pointer UVB radiated skin keratinocytes show cyclophilin D (Cyp-D) upregulation. Black-Right-Pointing-Pointer NAC inhibits UVB induced Cyp-D expression, while H{sub 2}O{sub 2} facilitates it. Black-Right-Pointing-Pointer Cyp-D-deficient cells are significantly less susceptible to UVB induced cell death. Black-Right-Pointing-Pointer Over-expression of Cyp-D causes spontaneous keratinocytes cell death. -- Abstract: UVB-induced skin cell damage involves the opening of mitochondrial permeability transition pore (mPTP), which leads to both apoptotic and necrotic cell death. Cyclophilin D (Cyp-D) translocation to the inner membrane of mitochondrion acts as a key component to open the mPTP. Our Western-Blot results in primary cultured human skin keratinocytes and in HaCaT cell line demonstrated that UVB radiation and hydrogen peroxide (H{sub 2}O{sub 2}) induced Cyp-D expression, which was inhibited by anti-oxidant N-acetyl cysteine (NAC). We created a stable Cyp-D deficiency skin keratinocytes by expressing Cyp-D-shRNA through lentiviral infection. Cyp-D-deficient cells were significantly less susceptible than their counterparts to UVB- or H{sub 2}O{sub 2}-induced cell death. Further, cyclosporine A (Cs-A), a Cyp-D inhibitor, inhibited UVB- or H{sub 2}O{sub 2}-induced keratinocytes cell death. Reversely, over-expression of Cyp-D in primary keratinocytes caused spontaneous keratinocytes cell death. These results suggest Cyp-D's critical role in UVB/oxidative stress-induced skin cell death.

  9. Double layers and other phenomena in low-pressure plasma columns generated by ultra-violet light

    SciTech Connect

    Valentini, H.-B.; Kaiser, D.

    2015-12-15

    Low-pressure steady-state plasmas are analysed by means of a two-fluid model in both plane and cylindrical geometries. The charged particles are generated by UV illumination. Both a Gaussian and a one-step profile of the ionization are taken into account. Numerical results reveal various types of solutions depending on the ionization profile and the collisionality. The first state arises if the ionization spreads from the centre over a great part of the plasma. It has an almost quasineutral plasma core and a positively charged boundary sheath. The curvature of the number density of the charge particles is negative, except the boundary sheath. The second state occurs if the ionization is mainly localized in the vicinity of the centre and the collisionality is below a threshold. A slightly positive plasma core is surrounded by a double layer there where the ionization falls off steeply. Between the double layer and the boundary sheath a broad zone can exist where the plasma is nearly quasi-neutral and the electric field is small. Within the double layer the ion drift speed attains the Bohm velocity in collisionless plasmas, it is smaller in collisional cases. In a broad domain, the curvature of the number density of the charged particles can be positive. This is a feature of the so-called contracted columns. The transition between both the states occurs abruptly under collisonless conditions and becomes smooth as the collisionality increases. The minimum of the space charge density can become positive in this case. Several layers are possible, as well. Using the Gaussian profile analytical criteria can be given for a few of the mentioned phenomena. Probably, ionization profiles prescribed by photons allow to understand the origin of the contracted column more completely than up to now.

  10. The Type IIP SN 2005ay: An Extensive Study From UltraViolet To Near-IR

    NASA Astrophysics Data System (ADS)

    Bufano, F. M.; Turatto, M.; Zampieri, L.; Gal-Yam, A.

    2006-08-01

    Several supernova types are thought to explode via the gravitational collapse of the core of massive stars at the end of their lifetimes. The great observational diversity has not been fully understood even if it clearly involves the progenitor masses and configurations at the time of explosion. These Supernovae, called Core Collapse Supernovae (CC SNe), are expected to dominate the counts of SNe observed at high redshifts and to be the only observable probe of the first generation stars (Pop III). Recently indicated as reliable distance indicators (Hamuy 02, Pastorello `03), CC SNe are objects of great interest but significantly less studied in comparison with the Termonuclear ones. With the aim to understand better the reasons of the heterogeneous behaviour , we have started an extensive study of the properties of SN II with different observational features (luminosity, velocity, etc..). Here we present the last results on our first observed target, SN2005ay, a Type IIP supernova observed in an extended way from the Ultraviolet wavelengths, provided by the GALEX , to the Optical and near-IR , obtained with IISP (Italian Intensive Supernova Program).

  11. The effect of heat- or ultra violet ozone-treatment of titanium on complement deposition from human blood plasma.

    PubMed

    Linderbäck, Paula; Harmankaya, Necati; Askendal, Agneta; Areva, Sami; Lausmaa, Jukka; Tengvall, Pentti

    2010-06-01

    Titanium (Ti) is a well known metallic biomaterial extensively used in dental, orthopaedic-, and occasionally also in blood contacting applications. It integrates well to bone and soft tissues, and is shown upon blood plasma contact to activate the intrinsic pathway of coagulation and bind complement factor 3b. The material properties depend largely on those of the nm-thick dense layer of TiO(2) that becomes rapidly formed upon contact with air and water. The spontaneously formed amorphous Ti-oxide has a pzc approximately 5-6 and its water solubility is at the order of 1-2 micromolar. It is often subjected to chemical- and heat treatments in order to increase the anatase- and rutile crystallinity, to modify the surface topography and to decrease the water solubility. In this work, we prepared sol-gel derived titanium and smooth PVD titanium surfaces, and analysed their oxide and protein deposition properties in human blood plasma before and after annealing at 100-500 degrees C or upon UVO-treatment for up to 96 hours. The blood plasma results show that complement deposition vanished irreversibly after heat treatment at 250-300 degrees C for 30 minutes or after UVO exposure for 24 hours or longer. XPS and infrared spectroscopy indicated change of surface water/hydroxyl binding upon the heat- and UVO treatments, and increased Ti oxidation. XRD analysis confirmed an increased crystallinity and both control (untreated) and annealed smooth titanium displayed low XRD-signals indicating some nanocrystallinity, with predominantly anatase phase. The current results show that the behaviour of titanium dioxide in blood contact can be controlled through relatively simple means, such as mild heating and illumination in UV-light, which both likely irreversibly change the stoichiometry and structure of the outmost layers of titanium dioxide and its OH/H(2)O binding characteristics.

  12. LADEE UVS (UltraViolet Visible Spectrometer) and the Search for Lunar Exospheric Dust: A Detailed Spectral Analysis

    NASA Astrophysics Data System (ADS)

    Wooden, D. H.; Cook, A.; Colaprete, A.; Shirley, M.; Vargo, K.; Elphic, R. C.; Hermalyn, B.; Stubbs, T. J.; Glenar, D. A.

    2014-12-01

    The Lunar Atmosphere and Dust Environment Explorer (LADEE) executed science observations in lunar orbit spanning 2013-Oct-16- 2014-04-18 UT. LADEE's Ultraviolet/Visible Spectrometer (UVS) studies the composition and temporal variations of the tenuous lunar exosphere and dust environment, utilizing two sets of optics: a limb-viewing telescope, and a solar-viewer. The limb-viewing telescope observes illuminated dust and emitting gas species while the Sun is just behind the lunar limb. The solar viewer, with its diffuser, allows UVS to also stare directly at the solar disk as it approaches the limb, sampling progressively lower exosphere altitudes. Solar viewer "Occultation" activities occur at the lunar sunrise limb, as the LADEE spacecraft passes into the lunar night side, facing the Sun (the spacecraft orbit is near-equatorial retrograde). A loss of transmission of sunlight occurs by the occultation of dust grains along the line-of-sight [1, 2]. So-called "Inertial Limb" activities have the limb-viewing telescope pointed at the lit exosphere just after the Sun has set. Inertial Limb activities follow a similar progression of diminishing sampling altitudes but hold the solar elongation angle constant so the zodiacal light contribution remains constant while seeking to observe the weak lunar horizon glow [2,3,4]. On the dark side of the moon, "Sodium Tail" activities pointed the limb-viewing telescope in the direction of the Moon's sodium tail (~anti-sunward), during different lunar phases. Of the UVS data sets, these show the largest excess of scattered blue light, indicative of the presence of small (~100 nm) dust grains in the tail. Correlations are sought between dust in the sodium tail and meteor streams [5] and magnetotail [3] crossings to investigate impact- versus electrostatic-lofting [6]. Once lofted, nanoparticles can become charged and picked up by the solar wind [7,8]. The LADEE UVS Occultation, Inertial Limb, and Sodium Tail spectral datasets provide evidence of a lunar dust exosphere. [1] Wooden et al. 2014, LPSC 45, 2123 [2] Wooden et al. (2014) & [3] Colaprete et al. 2014, at http://nesf2014.arc.nasa.gov [4] Glenar et al. 2011, PSS 59, 1695 [5] Stubbs et al. 2014 LPSC 45, 2705 [6] Stubbs et al. (2014), PSS 90, 10 [7] Farrell et al., 2012, Icarus 219, 498 [8] Mayer-Vernet et al., 2009, Solar Phys. 256, 463

  13. LADEE UVS (UltraViolet Visible Spectrometer) and the Search for Lunar Exospheric Dust: A Detailed Spectral Analysis

    NASA Technical Reports Server (NTRS)

    Wooden, Diane H.; Cook, Amanda; Colaprete, Anthony; Shirley, Mark; Vargo, Kara; Elphic, Richard C.; Hermalyn, Brendan; Stubbs, Timothy John; Glenar, David A.

    2014-01-01

    The Lunar Atmosphere and Dust Environment Explorer (LADEE) executed science observations in lunar orbit spanning 2013-Oct-16- 2014-04-18 UT. LADEE's Ultraviolet/Visible Spectrometer (UVS) studies the composition and temporal variations of the tenuous lunar exosphere and dust environment, utilizing two sets of optics: a limb-viewing telescope, and a solar-viewer. The limb-viewing telescope observes illuminated dust and emitting gas species while the Sun is just behind the lunar limb. The solar viewer, with its diffuser, allows UVS to also stare directly at the solar disk as it approaches the limb, sampling progressively lower exosphere altitudes. Solar viewer "Occultation" activities occur at the lunar sunrise limb, as the LADEE spacecraft passes into the lunar night side, facing the Sun (the spacecraft orbit is near-equatorial retrograde). A loss of transmission of sunlight occurs by the occultation of dust grains along the line-of-sight. So-called "Inertial Limb" activities have the limb-viewing telescope pointed at the lit exosphere just after the Sun has set. Inertial Limb activities follow a similar progression of diminishing sampling altitudes but hold the solar elongation angle constant so the zodiacal light contribution remains constant while seeking to observe the weak lunar horizon glow. On the dark side of the moon, "Sodium Tail" activities pointed the limb-viewing telescope in the direction of the Moon's sodium tail (similar to anti-sunward), during different lunar phases. Of the UVS data sets, these show the largest excess of scattered blue light, indicative of the presence of small (approximately 100 nm) dust grains in the tail. Correlations are sought between dust in the sodium tail and meteor streams and magnetotail crossings to investigate impact- versus electrostatic-lofting. Once lofted, nanoparticles can become charged and picked up by the solar wind. The LADEE UVS Occultation, Inertial Limb, and Sodium Tail spectral datasets provide evidence of a lunar dust exosphere.

  14. High detection efficiency micro-structured solid-state neutron detector with extremely low leakage current fabricated with continuous p-n junction

    NASA Astrophysics Data System (ADS)

    Huang, Kuan-Chih; Dahal, Rajendra; Lu, James J.-Q.; Danon, Yaron; Bhat, Ishwara B.

    2013-04-01

    We report the continuous p-n junction formation in honeycomb structured Si diode by in situ boron deposition and diffusion process using low pressure chemical vapor deposition for solid-state thermal neutron detection applications. Optimized diffusion temperature of 800 °C was obtained by current density-voltage characteristics for fabricated p+-n diodes. A very low leakage current density of ˜2 × 10-8 A/cm2 at -1 V was measured for enriched boron filled honeycomb structured neutron detector with a continuous p+-n junction. The neutron detection efficiency for a Maxwellian spectrum incident on the face of the detector was measured under zero bias voltage to be ˜26%. These results are very encouraging for fabrication of large area solid-state neutron detector that could be a viable alternative to 3He tube based technology.

  15. Achieving extremely concentrated aqueous dispersions of graphene flakes and catalytically efficient graphene-metal nanoparticle hybrids with flavin mononucleotide as a high-performance stabilizer.

    PubMed

    Ayán-Varela, M; Paredes, J I; Guardia, L; Villar-Rodil, S; Munuera, J M; Díaz-González, M; Fernández-Sánchez, C; Martínez-Alonso, A; Tascón, J M D

    2015-05-20

    The stable dispersion of graphene flakes in an aqueous medium is highly desirable for the development of materials based on this two-dimensional carbon structure, but current production protocols that make use of a number of surfactants typically suffer from limitations regarding graphene concentration or the amount of surfactant required to colloidally stabilize the sheets. Here, we demonstrate that an innocuous and readily available derivative of vitamin B2, namely the sodium salt of flavin mononucleotide (FMNS), is a highly efficient dispersant in the preparation of aqueous dispersions of defect-free, few-layer graphene flakes. Most notably, graphene concentrations in water as high as ∼50 mg mL(-1) using low amounts of FMNS (FMNS/graphene mass ratios of about 0.04) could be attained, which facilitated the formation of free-standing graphene films displaying high electrical conductivity (∼52000 S m(-1)) without the need of carrying out thermal annealing or other types of post-treatment. The excellent performance of FMNS as a graphene dispersant could be attributed to the combined effect of strong adsorption on the sheets through the isoalloxazine moiety of the molecule and efficient colloidal stabilization provided by its negatively charged phosphate group. The FMNS-stabilized graphene sheets could be decorated with nanoparticles of several noble metals (Ag, Pd, and Pt), and the resulting hybrids exhibited a high catalytic activity in the reduction of nitroarenes and electroreduction of oxygen. Overall, the present results should expedite the processing and implementation of graphene in, e.g., conductive inks, composites, and hybrid materials with practical utility in a wide range of applications. PMID:25915172

  16. Achieving extremely concentrated aqueous dispersions of graphene flakes and catalytically efficient graphene-metal nanoparticle hybrids with flavin mononucleotide as a high-performance stabilizer.

    PubMed

    Ayán-Varela, M; Paredes, J I; Guardia, L; Villar-Rodil, S; Munuera, J M; Díaz-González, M; Fernández-Sánchez, C; Martínez-Alonso, A; Tascón, J M D

    2015-05-20

    The stable dispersion of graphene flakes in an aqueous medium is highly desirable for the development of materials based on this two-dimensional carbon structure, but current production protocols that make use of a number of surfactants typically suffer from limitations regarding graphene concentration or the amount of surfactant required to colloidally stabilize the sheets. Here, we demonstrate that an innocuous and readily available derivative of vitamin B2, namely the sodium salt of flavin mononucleotide (FMNS), is a highly efficient dispersant in the preparation of aqueous dispersions of defect-free, few-layer graphene flakes. Most notably, graphene concentrations in water as high as ∼50 mg mL(-1) using low amounts of FMNS (FMNS/graphene mass ratios of about 0.04) could be attained, which facilitated the formation of free-standing graphene films displaying high electrical conductivity (∼52000 S m(-1)) without the need of carrying out thermal annealing or other types of post-treatment. The excellent performance of FMNS as a graphene dispersant could be attributed to the combined effect of strong adsorption on the sheets through the isoalloxazine moiety of the molecule and efficient colloidal stabilization provided by its negatively charged phosphate group. The FMNS-stabilized graphene sheets could be decorated with nanoparticles of several noble metals (Ag, Pd, and Pt), and the resulting hybrids exhibited a high catalytic activity in the reduction of nitroarenes and electroreduction of oxygen. Overall, the present results should expedite the processing and implementation of graphene in, e.g., conductive inks, composites, and hybrid materials with practical utility in a wide range of applications.

  17. Penetrating nontorso trauma: the extremities

    PubMed Central

    Ball, Chad G.

    2015-01-01

    Summary Similar to penetrating torso trauma, nontorso injuries have undergone a fascinating oscillation between invasive and noninvasive approaches. This article discusses an organized approach to the evaluation and initial treatment of penetrating extremity injuries based on regional anatomy and clinical examination. The approach is reliable, efficient and minimizes both delays in diagnosis and missed injuries. Outpatient follow-up is particularly important for patients with extremity injuries who are discharged home from the emergency department. PMID:26022152

  18. Protic acid immobilized on solid support as an extremely efficient recyclable catalyst system for a direct and atom economical esterification of carboxylic acids with alcohols.

    PubMed

    Chakraborti, Asit K; Singh, Bavneet; Chankeshwara, Sunay V; Patel, Alpesh R

    2009-08-21

    A convenient and clean procedure of esterification is reported by direct condensation of equimolar amounts of carboxylic acids with alcohols catalyzed by an easy to prepare catalyst system of perchloric acid immobilized on silica gel (HClO(4)-SiO(2)). The direct condensation of aryl, heteroaryl, styryl, aryl alkyl, alkyl, cycloalkyl, and long-chain aliphatic carboxylic acids with primary/secondary alkyl/cycloalkyl, allyl, propargyl, and long-chain aliphatic alcohols has been achieved to afford the corresponding esters in excellent yields. Chiral alcohol and N-t-Boc protected chiral amino acid also resulted in ester formation with the representative carboxylic acid or alcohol without competitive N-t-Boc deprotection and detrimental effect on the optical purity of the product demonstrating the mildness and chemoselectivity of the procedure. The esters of long-chain (>C(10)) acids and alcohols are obtained in high yields. The catalyst is recovered and recycled without significant loss of activity. The industrial application of the esterification process is demonstrated by the synthesis of prodrugs of ibuprofen and a few commercial flavoring agents. Other protic acids such as H(2)SO(4), HBr, TfOH, HBF(4), and TFA that were adsorbed on silica gel were less effective compared to HClO(4)-SiO(2) following the order HClO(4)-SiO(2) > H(2)SO(4)-SiO(2) > HBr-SiO(2) > TfOH-SiO(2) > HBF(4)-SiO(2) approximately TFA-SiO(2). When HClO(4) was immobilized on other solid supports the catalytic efficiency followed the order HClO(4)-SiO(2) > HClO(4)-K10 > HClO(4)-Al(2)O(3) (neutral) > HClO(4)-Al(2)O(3) (acidic) > HClO(4)-Al(2)O(3) (basic).

  19. Extreme Gas Kinematics in the z=2.2 Powerful Radio Galaxy MRC1138-262: Evidence for Efficient AGN Feedback in the Early Universe?

    SciTech Connect

    Nesvadba, N H; Lehnert, M D; Eisenhauer, F; Gilbert, A M; Tecza, M; Abuter, R

    2007-06-26

    To explain the properties of the most massive low-redshift galaxies and the shape of their mass function, recent models of galaxy evolution include strong AGN feedback to complement starburst-driven feedback in massive galaxies. Using the near-infrared integral-field spectrograph SPIFFI on the VLT, we searched for direct evidence for such a feedback in the optical emission line gas around the z = 2.16 powerful radio galaxy MRC1138-262, likely a massive galaxy in formation. The kpc-scale kinematics, with FWHMs and relative velocities {approx}< 2400 km s{sup -1} and nearly spherical spatial distribution, do not resemble large-scale gravitational motion or starburst-driven winds. Order-of-magnitude timescale and energy arguments favor the AGN as the only plausible candidate to accelerate the gas, with a total energy injection of {approx} few x 10{sup 60} ergs or more, necessary to power the outflow, and relatively efficient coupling between radio jet and ISM. Observed outflow properties are in gross agreement with the models, and suggest that AGN winds might have a similar, or perhaps larger, cosmological significance than starburst-driven winds, if MRC1138-262 is indeed archetypal. Moreover, the outflow has the potential to remove significant gas fractions ({approx}< 50%) from a > L* galaxy within a few 10 to 100 Myrs, fast enough to preserve the observed [{alpha}/Fe] overabundance in massive galaxies at low redshift. Using simple arguments, it appears that feedback like that observed in MRC1138-262 may have sufficient energy to inhibit material from infalling into the dark matter halo and thus regulate galaxy growth as required in some recent models of hierarchical structure formation.

  20. Method for detection of extremely low concentration

    DOEpatents

    Andresen, Brian D.; Miller, Fred S.

    2002-01-01

    An ultratrace detector system for hand-held gas chromatography having high sensitivity, for example, to emissions generated during production of weapons, biological compounds, drugs, etc. The detector system is insensitive to water, air, helium, argon, oxygen, and CO.sub.2. The detector system is basically composed of a hand-held capillary gas chromatography (GC), an insulated heated redox-chamber, a detection chamber, and a vapor trap. For example, the detector system may use gas phase redox reactions and spectral absorption of mercury vapor. The gas chromatograph initially separates compounds that percolate through a bed of heated mercuric oxide (HgO) in a silica--or other metal--aerogel material which acts as an insulator. Compounds easily oxidized by HgO liberate atomic mercury that subsequently pass through a detection chamber which includes a detector cell, such as quartz, that is illuminated with a 254 nm ultra-violet (UV) mercury discharge lamp which generates the exact mercury absorption bands that are used to detect the liberated mercury atoms. Atomic mercury strongly absorbs 254 nm energy is therefore a specific signal for reducing compounds eluting from the capillary GC, whereafter the atomic mercury is trapped for example, in a silicon-aerogel trap.

  1. Food web efficiency differs between humic and clear water lake communities in response to nutrients and light.

    PubMed

    Faithfull, C L; Mathisen, P; Wenzel, A; Bergström, A K; Vrede, T

    2015-03-01

    This study demonstrates that clear and humic freshwater pelagic communities respond differently to the same environmental stressors, i.e. nutrient and light availability. Thus, effects on humic communities cannot be generalized from existing knowledge about these environmental stressors on clear water communities. Small humic lakes are the most numerous type of lake in the boreal zone, but little is known about how these lakes will respond to increased inflows of nutrients and terrestrial dissolved organic C (t-DOC) due to climate change and increased human impacts. Therefore, we compared the effects of nutrient addition and light availability on pelagic humic and clear water lake communities in a mesocosm experiment. When nutrients were added, phytoplankton production (PPr) increased in both communities, but pelagic energy mobilization (PEM) and bacterial production (BP) only increased in the humic community. At low light conditions, the addition of nutrients led to increased PPr only in the humic community, suggesting that, in contrast to the clear water community, humic phytoplankton were already adapted to lower ambient light levels. Low light significantly reduced PPr and PEM in the clear water community, but without reducing total zooplankton production, which resulted in a doubling of food web efficiency (FWE = total zooplankton production/PEM). However, total zooplankton production was not correlated with PEM, PPr, BP, PPr:BP or C:nutrient stoichiometry for either community type. Therefore, other factors such as food chain length, food quality, ultra-violet radiation or duration of the experiment, must have determined total zooplankton production and ultimately FWE.

  2. Food web efficiency differs between humic and clear water lake communities in response to nutrients and light.

    PubMed

    Faithfull, C L; Mathisen, P; Wenzel, A; Bergström, A K; Vrede, T

    2015-03-01

    This study demonstrates that clear and humic freshwater pelagic communities respond differently to the same environmental stressors, i.e. nutrient and light availability. Thus, effects on humic communities cannot be generalized from existing knowledge about these environmental stressors on clear water communities. Small humic lakes are the most numerous type of lake in the boreal zone, but little is known about how these lakes will respond to increased inflows of nutrients and terrestrial dissolved organic C (t-DOC) due to climate change and increased human impacts. Therefore, we compared the effects of nutrient addition and light availability on pelagic humic and clear water lake communities in a mesocosm experiment. When nutrients were added, phytoplankton production (PPr) increased in both communities, but pelagic energy mobilization (PEM) and bacterial production (BP) only increased in the humic community. At low light conditions, the addition of nutrients led to increased PPr only in the humic community, suggesting that, in contrast to the clear water community, humic phytoplankton were already adapted to lower ambient light levels. Low light significantly reduced PPr and PEM in the clear water community, but without reducing total zooplankton production, which resulted in a doubling of food web efficiency (FWE = total zooplankton production/PEM). However, total zooplankton production was not correlated with PEM, PPr, BP, PPr:BP or C:nutrient stoichiometry for either community type. Therefore, other factors such as food chain length, food quality, ultra-violet radiation or duration of the experiment, must have determined total zooplankton production and ultimately FWE. PMID:25373827

  3. Tapioca starch: An efficient fuel in gel-combustion synthesis of photocatalytically and anti-microbially active ZnO nanoparticles

    SciTech Connect

    Ramasami, Alamelu K.; Raja Naika, H.; Nagabhushana, H.; Ramakrishnappa, T.; Balakrishna, Geetha R.; Nagaraju, G.

    2015-01-15

    Zinc oxide nanoparticles were synthesized by gel-combustion method using novel bio-fuel tapioca starch pearls, derived from the tubers of Manihotesculenta. The product is characterized using various techniques. The X-ray diffraction pattern correspond to a hexagonal zincite structure. Fourier transform infrared spectrum showed main absorption peaks at 394 and 508 cm{sup −} {sup 1} due to stretching vibration of Zn–O. Ultravoilet–visible spectrum of zinc oxide nanoparticles showed absorption maximum at 373 nm whereas the maximum of the bulk zinc oxide was 377 nm. The morphology of the product was studied using scanning electron microscopy and transmission electron microscopy. The scanning electron microscopic images showed that the products are agglomerated and porous in nature. The transmission electron microscopic images revealed spherical particles of 40–50 nm in diameter. The photocatalytic degradation of methylene blue was examined using zinc oxide nanoparticles and found more efficient in sunlight than ultra-violet light due to reduced band gap. The antibacterial properties of zinc oxide nanoparticles were investigated against four bacterial strains Klebsiella aerogenes, Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aereus, where Pseudomonas aeruginosa and Staphylococcus aereus exhibited significant antibacterial activity in agar well diffusion method when compared to positive control. - Highlights: • ZnO nanoparticles have been prepared from a new bio-fuel, tapioca starch by gel combustion method. • XRD pattern revealed hexagonal zincite crystal structure with crystallite size 33 nm. • ZnO nanoparticles exhibited a band gap of 2.70 eV. • The ZnO nanoparticles exhibited superior degradation in sunlight in comparison with UV light. • The product showed a good anti-bacterial activity against two bacterial strains.

  4. Extreme Scale Visual Analytics

    SciTech Connect

    Wong, Pak C.; Shen, Han-Wei; Pascucci, Valerio

    2012-05-08

    Extreme-scale visual analytics (VA) is about applying VA to extreme-scale data. The articles in this special issue examine advances related to extreme-scale VA problems, their analytical and computational challenges, and their real-world applications.

  5. 21st Birthday Drinking: Extremely Extreme

    ERIC Educational Resources Information Center

    Rutledge, Patricia C.; Park, Aesoon; Sher, Kenneth J.

    2008-01-01

    Despite public recognition of the hazards of 21st birthday drinking, there is little empirical information concerning its prevalence, severity, and risk factors. Data from a sample of 2,518 college students suggest that 21st birthday drinking poses an extreme danger: (a) 4 of every 5 participants (83%) reported drinking to celebrate, (b) birthday…

  6. How extreme is extreme hourly precipitation?

    NASA Astrophysics Data System (ADS)

    Papalexiou, Simon Michael; Dialynas, Yannis G.; Pappas, Christoforos

    2016-04-01

    The importance of accurate representation of precipitation at fine time scales (e.g., hourly), directly associated with flash flood events, is crucial in hydrological design and prediction. The upper part of a probability distribution, known as the distribution tail, determines the behavior of extreme events. In general, and loosely speaking, tails can be categorized in two families: the subexponential and the hyperexponential family, with the first generating more intense and more frequent extremes compared to the latter. In past studies, the focus has been mainly on daily precipitation, with the Gamma distribution being the most popular model. Here, we investigate the behaviour of tails of hourly precipitation by comparing the upper part of empirical distributions of thousands of records with three general types of tails corresponding to the Pareto, Lognormal, and Weibull distributions. Specifically, we use thousands of hourly rainfall records from all over the USA. The analysis indicates that heavier-tailed distributions describe better the observed hourly rainfall extremes in comparison to lighter tails. Traditional representations of the marginal distribution of hourly rainfall may significantly deviate from observed behaviours of extremes, with direct implications on hydroclimatic variables modelling and engineering design.

  7. Cardiovascular flow simulation at extreme scale

    NASA Astrophysics Data System (ADS)

    Zhou, Min; Sahni, Onkar; Kim, H. Jin; Figueroa, C. Alberto; Taylor, Charles A.; Shephard, Mark S.; Jansen, Kenneth E.

    2009-12-01

    As cardiovascular models grow more sophisticated in terms of the geometry considered, and more physiologically realistic boundary conditions are applied, and fluid flow is coupled to structural models, the computational complexity grows. Massively parallel adaptivity and flow solvers with extreme scalability enable cardiovascular simulations to reach an extreme scale while keeping the time-to-solution reasonable. In this paper, we discuss our efforts in this area and provide two demonstrations: one on an extremely large and complex geometry (including many of the major arteries below the neck) where the solution is efficiently captured with anisotropic adaptivity and another case (severe abdominal aorta aneurysm) where the transitional flow leads to extremely large meshes (O(109)) and scalability to extremely large core counts (O(105)) for both rigid and deforming wall simulations.

  8. Time-of-flight electron spectrometer for a broad range of kinetic energies

    SciTech Connect

    Kothe, Alexander; Metje, Jan; Wilke, Martin; Moguilevski, Alexandre; Engel, Nicholas; Al-Obaidi, Ruba; Richter, Clemens; Golnak, Ronny; Kiyan, Igor Yu.; Aziz, Emad F.

    2013-02-15

    A newly constructed time-of-flight electron spectrometer of the magnetic bottle type is characterized for electron detection in a broad range of kinetic energies. The instrument is designed to measure the energy spectra of electrons generated from liquids excited by strong laser fields and photons in the range of extreme ultra violet and soft X-rays. Argon inner shell electrons were recorded to calibrate the spectrometer and investigate its characteristics, such as energy resolution and collection efficiency. Its energy resolution {Delta}E/E of 1.6% allows resolving the Ar 2p spin orbit structure at kinetic energies higher than 100 eV. The collection efficiency is determined and compared to that of the spectrometer in its field-free configuration.

  9. Bivariate extreme value distributions

    NASA Technical Reports Server (NTRS)

    Elshamy, M.

    1992-01-01

    In certain engineering applications, such as those occurring in the analyses of ascent structural loads for the Space Transportation System (STS), some of the load variables have a lower bound of zero. Thus, the need for practical models of bivariate extreme value probability distribution functions with lower limits was identified. We discuss the Gumbel models and present practical forms of bivariate extreme probability distributions of Weibull and Frechet types with two parameters. Bivariate extreme value probability distribution functions can be expressed in terms of the marginal extremel distributions and a 'dependence' function subject to certain analytical conditions. Properties of such bivariate extreme distributions, sums and differences of paired extremals, as well as the corresponding forms of conditional distributions, are discussed. Practical estimation techniques are also given.

  10. Extreme Environments: Why NASA?

    NASA Astrophysics Data System (ADS)

    Meyer, M. A.

    2002-12-01

    Life on our planet is the only known example in the universe and so we are relegated to this planet for the study of life. However, life may be a natural consequence of planet formation, and so the study of the origin, evolution, distribution and future of life may be greatly informed by planetary exploration. Astrobiology has adopted several approaches to study life on Earth, for deducing our origins, for determining the likelihood of life elsewhere, and for enabling the search for evidence of past or present life. The first approach has been the Exobiology Program, centered around understanding the origins of life and which supports individual investigator research. Second has been the construction of consortia-type research in which researchers from different disciplines focus on a larger problem. This structure began with NASA Specialized Centers of Research and Training and has grown to include the Astrobiology Institute - a collection of competitively selected groups of researchers attacking problems in Astrobiology as individual teams and as a consolidated Institute. With the formation of an intellectual basis for exploring for life elsewhere, Astrobiology has initiated the competitive research and development program in instrument development (Astrobiology Science and Technology for Instrument Development [ASTID] Program) that would enable future mission instruments for the exploration of planetary bodies in the search for prebiotic chemistry, habitable environments (past or present), biomarkers, and possibly life itself. However, the act of exploring requires robust instrumentation, mobile robotic platforms, efficient operations, and a high level of autonomy. To this end, Astrobiology has started a new research activity that promotes scientifically-driven robotic exploration of extreme environments on Earth that are analogous to suspected habitable environments on other planetary bodies. The program is called Astrobiology Science and Technology for

  11. Extremal surface barriers

    NASA Astrophysics Data System (ADS)

    Engelhardt, Netta; Wall, Aron C.

    2014-03-01

    We present a generic condition for Lorentzian manifolds to have a barrier that limits the reach of boundary-anchored extremal surfaces of arbitrary dimension. We show that any surface with nonpositive extrinsic curvature is a barrier, in the sense that extremal surfaces cannot be continuously deformed past it. Furthermore, the outermost barrier surface has nonnegative extrinsic curvature. Under certain conditions, we show that the existence of trapped surfaces implies a barrier, and conversely. In the context of AdS/CFT, these barriers imply that it is impossible to reconstruct the entire bulk using extremal surfaces. We comment on the implications for the firewall controversy.

  12. Survival of extreme opinions

    NASA Astrophysics Data System (ADS)

    Hsu, Jiann-wien; Huang, Ding-wei

    2009-12-01

    We study the survival of extreme opinions in various processes of consensus formation. All the opinions are treated equally and subjected to the same rules of changing. We investigate three typical models to reach a consensus in each case: (A) personal influence, (B) influence from surroundings, and (C) influence to surroundings. Starting with uniformly distributed random opinions, our calculated results show that the extreme opinions can survive in both models (A) and (B), but not in model (C). We obtain a conclusion that both personal influence and passive adaptation to the environment are not sufficient enough to eradicate all the extreme opinions. Only the active persuasion to change the surroundings eliminates the extreme opinions completely.

  13. Extreme environments and exobiology.

    PubMed

    Friedmann, E I

    1993-01-01

    Ecological research on extreme environments can be applied to exobiological problems such as the question of life on Mars. If life forms (fossil or extant) are found on Mars, their study will help to solve fundamental questions about the nature of life on Earth. Extreme environments that are beyond the range of adaptability of their inhabitants are defined as "absolute extreme". Such environments can serve as terrestrial models for the last stages of life in the history of Mars, when the surface cooled down and atmosphere and water disappeared. The cryptoendolithic microbial community in porous rocks of the Ross Desert in Antarctica and the microbial mats at the bottom of frozen Antarctic lakes are such examples. The microbial communities of Siberian permafrost show that, in frozen but stable communities, long-term survival is possible. In the context of terraforming Mars, selected microorganisms isolated from absolute extreme environments are considered for use in creation of a biological carbon cycle.

  14. Extreme environments and exobiology

    NASA Technical Reports Server (NTRS)

    Friedmann, E. I.

    1993-01-01

    Ecological research on extreme environments can be applied to exobiological problems such as the question of life on Mars. If life forms (fossil or extant) are found on Mars, their study will help to solve fundamental questions about the nature of life on Earth. Extreme environments that are beyond the range of adaptability of their inhabitants are defined as "absolute extreme". Such environments can serve as terrestrial models for the last stages of life in the history of Mars, when the surface cooled down and atmosphere and water disappeared. The cryptoendolithic microbial community in porous rocks of the Ross Desert in Antarctica and the microbial mats at the bottom of frozen Antarctic lakes are such examples. The microbial communities of Siberian permafrost show that, in frozen but stable communities, long-term survival is possible. In the context of terraforming Mars, selected microorganisms isolated from absolute extreme environments are considered for use in creation of a biological carbon cycle.

  15. Recovery of EUVL substrates

    SciTech Connect

    Vernon, S.P.; Baker, S.L.

    1995-01-19

    Mo/Si multilayers, were removed from superpolished zerodur and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  16. Enhanced hole boring with two-color relativistic laser pulses in the fast ignition scheme

    NASA Astrophysics Data System (ADS)

    Yu, Changhai; Deng, Aihua; Tian, Ye; Li, Wentao; Wang, Wentao; Zhang, Zhijun; Qi, Rong; Wang, Cheng; Liu, Jiansheng

    2016-08-01

    A scheme of using two-color laser pulses for hole boring into overdense plasma as well as energy transfer into electron and ion beams has been studied using particle-in-cell simulations. Following an ultra-short ultra-intense hole-boring laser pulse with a short central wavelength in extreme ultra-violet range, the main infrared driving laser pulse can be guided in the hollow channel preformed by the former laser and propagate much deeper into an overdense plasma, as compared to the case using the infrared laser only. In addition to efficiently transferring the main driving laser energy into energetic electrons and ions generation deep inside the overdense plasma, the ion beam divergence can be greatly reduced. The results might be beneficial for the fast ignition concept of inertial confinement fusion.

  17. Electronics for Extreme Environments

    NASA Technical Reports Server (NTRS)

    Patel, J. U.; Cressler, J.; Li, Y.; Niu, G.

    2001-01-01

    Most of the NASA missions involve extreme environments comprising radiation and low or high temperatures. Current practice of providing friendly ambient operating environment to electronics costs considerable power and mass (for shielding). Immediate missions such as the Europa orbiter and lander and Mars landers require the electronics to perform reliably in extreme conditions during the most critical part of the mission. Some other missions planned in the future also involve substantial surface activity in terms of measurements, sample collection, penetration through ice and crust and the analysis of samples. Thus it is extremely critical to develop electronics that could reliably operate under extreme space environments. Silicon On Insulator (SOI) technology is an extremely attractive candidate for NASA's future low power and high speed electronic systems because it offers increased transconductance, decreased sub-threshold slope, reduced short channel effects, elimination of kink effect, enhanced low field mobility, and immunity from radiation induced latch-up. A common belief that semiconductor devices function better at low temperatures is generally true for bulk devices but it does not hold true for deep sub-micron SOI CMOS devices with microscopic device features of 0.25 micrometers and smaller. Various temperature sensitive device parameters and device characteristics have recently been reported in the literature. Behavior of state of the art technology devices under such conditions needs to be evaluated in order to determine possible modifications in the device design for better performance and survivability under extreme environments. Here, we present a unique approach of developing electronics for extreme environments to benefit future NASA missions as described above. This will also benefit other long transit/life time missions such as the solar sail and planetary outposts in which electronics is out open in the unshielded space at the ambient space

  18. Extreme Programming: Maestro Style

    NASA Technical Reports Server (NTRS)

    Norris, Jeffrey; Fox, Jason; Rabe, Kenneth; Shu, I-Hsiang; Powell, Mark

    2009-01-01

    "Extreme Programming: Maestro Style" is the name of a computer programming methodology that has evolved as a custom version of a methodology, called extreme programming that has been practiced in the software industry since the late 1990s. The name of this version reflects its origin in the work of the Maestro team at NASA's Jet Propulsion Laboratory that develops software for Mars exploration missions. Extreme programming is oriented toward agile development of software resting on values of simplicity, communication, testing, and aggressiveness. Extreme programming involves use of methods of rapidly building and disseminating institutional knowledge among members of a computer-programming team to give all the members a shared view that matches the view of the customers for whom the software system is to be developed. Extreme programming includes frequent planning by programmers in collaboration with customers, continually examining and rewriting code in striving for the simplest workable software designs, a system metaphor (basically, an abstraction of the system that provides easy-to-remember software-naming conventions and insight into the architecture of the system), programmers working in pairs, adherence to a set of coding standards, collaboration of customers and programmers, frequent verbal communication, frequent releases of software in small increments of development, repeated testing of the developmental software by both programmers and customers, and continuous interaction between the team and the customers. The environment in which the Maestro team works requires the team to quickly adapt to changing needs of its customers. In addition, the team cannot afford to accept unnecessary development risk. Extreme programming enables the Maestro team to remain agile and provide high-quality software and service to its customers. However, several factors in the Maestro environment have made it necessary to modify some of the conventional extreme

  19. Extremely high latitude auroras

    NASA Astrophysics Data System (ADS)

    Gussenhoven, M. S.

    1982-04-01

    It is pointed out that imaging devices on the polar orbiting ISIS and Defense Meteorological Satellite Program (DMSP) satellites have greatly increased the extent of polar cap and auroral zone coverage and have prompted several studies of polar cap arcs. A description is presented of a statistical study of the occurrence conditions for arcs recorded in DMSP images at extremely high latitudes, taking into account corrected geomagnetic latitudes equal to or greater than 80 deg. The 80 deg boundary is chosen to minimize the problems associated with defining a polar cap boundary. Attention is given to the data base and categorization of extremely high latitude auroras, the relationship to magnetic activity, and the relationship to solar wind conditions. It is found that one category of extremely high latitude auroras is distinctly different from the rest. This category includes the oval auroras which expand poleward in the midnight sector.

  20. Advanced Instrumentation for Extreme Environments

    SciTech Connect

    Melin, Alexander M; Kisner, Roger; Fugate, David L

    2013-01-01

    The Department of Energy (DOE) Office of Nuclear Energy (NE) is pursuing embedded instrumentation and controls (I&C) technology for next generation nuclear power generation applications. Embedded systems encompass a wide range of configurations and technologies; we define embedding in this instance as the integration of the sensors and the control system design into the component design using a systems engineering process. Embedded I&C systems are often an essential part of developing new capabilities, improving reliability, enhancing performance, and reducing operational costs. The new intrinsically safe, more efficient, and cost effective reactor technologies (Next Generation Nuclear Plant and Small Modular Reactors) require the development and application of new I&C technologies. These new designs raise extreme environmental challenges such as high temperatures (over 700 C) and material compatibility (e.g., molten salts). The desired reliability and functionality requires measurements in these extreme conditions including high radiation environments which were not previously monitored in real time. The DOE/NE Nuclear Energy Enabling Technologies (NEET) program currently has several projects investigating I&C technologies necessary to make these reactor designs realizable. The project described in this paper has the specific goal of investigating embedded I&C with the following objectives: 1.Explore and quantify the potential gains from embedded I&C improved reliability, increased performance, and reduced cost 2.Identify practical control, sensing, and measurement techniques for the extreme environments found in high-temperature reactors 3.Design and fabricate a functional prototype high-temperature cooling pump for molten salts represents target demonstration of improved performance, reliability, and widespread usage There are many engineering challenges in the design of a high-temperature liquid salt cooling pump. The pump and motor are in direct contact with

  1. Extremal entanglement witnesses

    NASA Astrophysics Data System (ADS)

    Hansen, Leif Ove; Hauge, Andreas; Myrheim, Jan; Sollid, Per Øyvind

    2015-02-01

    We present a study of extremal entanglement witnesses on a bipartite composite quantum system. We define the cone of witnesses as the dual of the set of separable density matrices, thus TrΩρ≥0 when Ω is a witness and ρ is a pure product state, ρ=ψψ† with ψ=ϕ⊗χ. The set of witnesses of unit trace is a compact convex set, uniquely defined by its extremal points. The expectation value f(ϕ,χ)=TrΩρ as a function of vectors ϕ and χ is a positive semidefinite biquadratic form. Every zero of f(ϕ,χ) imposes strong real-linear constraints on f and Ω. The real and symmetric Hessian matrix at the zero must be positive semidefinite. Its eigenvectors with zero eigenvalue, if such exist, we call Hessian zeros. A zero of f(ϕ,χ) is quadratic if it has no Hessian zeros, otherwise it is quartic. We call a witness quadratic if it has only quadratic zeros, and quartic if it has at least one quartic zero. A main result we prove is that a witness is extremal if and only if no other witness has the same, or a larger, set of zeros and Hessian zeros. A quadratic extremal witness has a minimum number of isolated zeros depending on dimensions. If a witness is not extremal, then the constraints defined by its zeros and Hessian zeros determine all directions in which we may search for witnesses having more zeros or Hessian zeros. A finite number of iterated searches in random directions, by numerical methods, leads to an extremal witness which is nearly always quadratic and has the minimum number of zeros. We discuss briefly some topics related to extremal witnesses, in particular the relation between the facial structures of the dual sets of witnesses and separable states. We discuss the relation between extremality and optimality of witnesses, and a conjecture of separability of the so-called structural physical approximation (SPA) of an optimal witness. Finally, we discuss how to treat the entanglement witnesses on a complex Hilbert space as a subset of the

  2. Adventure and Extreme Sports.

    PubMed

    Gomez, Andrew Thomas; Rao, Ashwin

    2016-03-01

    Adventure and extreme sports often involve unpredictable and inhospitable environments, high velocities, and stunts. These activities vary widely and include sports like BASE jumping, snowboarding, kayaking, and surfing. Increasing interest and participation in adventure and extreme sports warrants understanding by clinicians to facilitate prevention, identification, and treatment of injuries unique to each sport. This article covers alpine skiing and snowboarding, skateboarding, surfing, bungee jumping, BASE jumping, and whitewater sports with emphasis on epidemiology, demographics, general injury mechanisms, specific injuries, chronic injuries, fatality data, and prevention. Overall, most injuries are related to overuse, trauma, and environmental or microbial exposure.

  3. Extreme field science

    NASA Astrophysics Data System (ADS)

    Bulanov, S. V.; Esirkepov, T. Zh; Hayashi, Y.; Kando, M.; Kiriyama, H.; Koga, J. K.; Kondo, K.; Kotaki, H.; Pirozhkov, A. S.; Bulanov, S. S.; Zhidkov, A. G.; Rosanov, N. N.; Chen, P.; Neely, D.; Kato, Y.; Narozhny, N. B.; Korn, G.

    2011-12-01

    We discuss the progress in the development of extreme light sources that will open new horizons for studying a wide range of fundamental science and astrophysics problems. The regimes of dominant radiation reaction, which completely change the electromagnetic wave-matter interaction, will be revealed, resulting in a new extremely powerful source of ultrashort high-brightness gamma-ray pulses. The possibility of abundant electron-positron pair creation via multi-photon processes and the possibility of reaching the critical field of quantum electrodynamics, which would lead to vacuum polarization and breakdown, are attracting considerable attention.

  4. Climate Extremes and Society

    NASA Astrophysics Data System (ADS)

    Mote, Philip

    2009-10-01

    In October 2005, as the United States still was reeling from Hurricane Katrina in August and as the alphabet was too short to contain all of that year's named Atlantic tropical storms (Hurricane Wilma was forming near Jamaica), a timely workshop in Bermuda focused on climate extremes and society (see Eos, 87(3), 25, 17 January 2006). This edited volume, which corresponds roughly to the presentations given at that workshop, offers a fascinating look at the critically important intersection of acute climate stress and human vulnerabilities. A changing climate affects humans and other living things not through the variable that most robustly demonstrates the role of rising greenhouse gases—globally averaged temperature—but through local changes, especially changes in extremes. The first part of this book, “Defining and modeling the nature of weather and climate extremes,” focuses on natural science. The second part, “Impacts of weather and climate extremes,” focuses on societal impacts and responses, emphasizing an insurance industry perspective because a primary sponsor of the workshop was the Risk Prediction Initiative, whose aim is to “support scientific research on topics of interest to its sponsors” (p. 320).

  5. Hydrological extremes and security

    NASA Astrophysics Data System (ADS)

    Kundzewicz, Z. W.; Matczak, P.

    2015-04-01

    Economic losses caused by hydrological extremes - floods and droughts - have been on the rise. Hydrological extremes jeopardize human security and impact on societal livelihood and welfare. Security can be generally understood as freedom from threat and the ability of societies to maintain their independent identity and their functional integrity against forces of change. Several dimensions of security are reviewed in the context of hydrological extremes. The traditional interpretation of security, focused on the state military capabilities, has been replaced by a wider understanding, including economic, societal and environmental aspects that get increasing attention. Floods and droughts pose a burden and serious challenges to the state that is responsible for sustaining economic development, and societal and environmental security. The latter can be regarded as the maintenance of ecosystem services, on which a society depends. An important part of it is water security, which can be defined as the availability of an adequate quantity and quality of water for health, livelihoods, ecosystems and production, coupled with an acceptable level of water-related risks to people, environments and economies. Security concerns arise because, over large areas, hydrological extremes - floods and droughts - are becoming more frequent and more severe. In terms of dealing with water-related risks, climate change can increase uncertainties, which makes the state's task to deliver security more difficult and more expensive. However, changes in population size and development, and level of protection, drive exposure to hydrological hazards.

  6. Lower extremity orthoses.

    PubMed

    Bogucki, Artur

    2002-01-31

    This article presents the medical indications and contemporary technical capabilities in orthotic management of lower extremity. The classification included typical orthoses as well as devices that today constitute an integral part of modern therapeutic procedures are presented. Therapeutic success is conditioned by professional team-work of the physician, the therapist, the orthotic technician and the patient. PMID:17679908

  7. Lower extremity prostheses.

    PubMed

    Bogucki, A

    2001-01-01

    This article discusses the technical and medical difficulties involved in the proper fitting of prostheses on the lower extremity. The factors determining the success of a prosthesis include the quality of the stump, the skill of prosthesis socket fabrication, and the proper ordering of components, as well as rehabilitation supervised by experts and professional care for the amputee. PMID:17984917

  8. Extreme Low Aspect Ratio Stellarators

    NASA Astrophysics Data System (ADS)

    Moroz, Paul

    1997-11-01

    Recently proposed Spherical Stellarator (SS) concept [1] includes the devices with stellarator features and low aspect ratio, A <= 3.5, which is very unusual for stellarators (typical stellarators have A ≈ 7-10 or above). Strong bootstrap current and high-β equilibria are two distinguished elements of the SS concept leading to compact, steady-state, and efficient fusion reactor. Different coil configurations advantageous for the SS have been identified and analyzed [1-6]. In this report, we will present results on novel stellarator configurations which are unusual even for the SS approach. These are the extreme-low-aspect-ratio-stellarators (ELARS), with the aspect ratio A ≈ 1. We succeeded in finding ELARS configurations with extremely compact, modular, and simple design compatible with significant rotational transform (ι ≈ 0.1 - 0.15), large plasma volume, and good particle transport characteristics. [1] P.E. Moroz, Phys. Rev. Lett. 77, 651 (1996); [2] P.E. Moroz, Phys. Plasmas 3, 3055 (1996); [3] P.E. Moroz, D.B. Batchelor et al., Fusion Tech. 30, 1347 (1996); [4] P.E. Moroz, Stellarator News 48, 2 (1996); [5] P.E. Moroz, Plasma Phys. Reports 23, 502 (1997); [6] P.E. Moroz, Nucl. Fusion 37, No. 8 (1997). *Supported by DOE Grant No. DE-FG02-97ER54395.

  9. Simultaneous determination of substituted diphenylamine antioxidants and benzotriazole ultra violet stabilizers in blood plasma and fish homogenates by ultra high performance liquid chromatography-electrospray tandem mass spectrometry.

    PubMed

    Lu, Zhe; Peart, Thomas E; Cook, Cyril J; De Silva, Amila O

    2016-08-26

    Analytical methods were developed for the determination of eight substituted diphenylamines (SDPAs) and six benzotriazole UV stabilizers (BZT-UVs) in blood plasma and fish homogenate matrices. Liquid-liquid extraction by methyl tert-butyl ether and denaturation by KOH following silica gel packed column clean-up was employed for blood plasma preparation. For the fish homogenate samples, ultrasonic assisted solvent extraction combined with automated gel permeation chromatography and silica gel packed column clean-up was used. The target compounds were determined by optimized ultra performance liquid chromatography-tandem mass spectrometry in positive electrospray ionization mode. The method limits of quantification (MLOQs) of the 14 analytes ranged from 0.002 to 1.5ngg(-1) and 0.001 to 2.3ngg(-1) (wet weight, w.w.) for blood plasma and fish homogenate, respectively. The total recoveries of the target compounds varied from 61% to 100% (mean 77±9%). Eleven targets including monobutyl- (C4), dibutyl- (C4C4), monooctyl- (C8), monobutyl monooctyl- (C4C8), dioctyl-(C8C8), monononyl- (C9), dinonly-(C9C9) and 4,4'-bis(α,α-dimethylbenzyl)-(diAMS) DPAs, as well as 2-(2H-Benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol (UV234), 2,4-di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl) phenol (UV327) and 2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol (UV328) were identified in the environmental biota samples, with concentrations in the range of 

  10. Collective electronic excitations in the ultra violet regime in 2-D and 1-D carbon nanostructures achieved by the addition of foreign atoms

    PubMed Central

    Bangert, U.; Pierce, W.; Boothroyd, C.; Pan, C.-T.; Gwilliam, R.

    2016-01-01

    Plasmons in the visible/UV energy regime have attracted great attention, especially in nano-materials, with regards to applications in opto-electronics and light harvesting; tailored enhancement of such plasmons is of particular interest for prospects in nano-plasmonics. This work demonstrates that it is possible, by adequate doping, to create excitations in the visible/UV regime in nano-carbon materials, i.e., carbon nanotubes and graphene, with choice of suitable ad-atoms and dopants, which are introduced directly into the lattice by low energy ion implantation or added via deposition by evaporation. Investigations as to whether these excitations are of collective nature, i.e., have plasmonic character, are carried out via DFT calculations and experiment-based extraction of the dielectric function. They give evidence of collective excitation behaviour for a number of the introduced impurity species, including K, Ag, B, N, and Pd. It is furthermore demonstrated that such excitations can be concentrated at nano-features, e.g., along nano-holes in graphene through metal atoms adhering to the edges of these holes. PMID:27271352

  11. OH SENSOR BASED ON ULTRA-VIOLET, CONTINUOUS-WAVE ABSORPTION SPECTROSCOPY UTILIZING A FREQUENCY-QUADRUPLED, FIBER-AMPLIFIED EXTERNAL CAVITY DIODE LASER. (R828180)

    EPA Science Inventory

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  12. Proposal for Testing and Validation of Vacuum Ultra-Violet Atomic Laser-Induced Fluorescence as a Method to Analyze Carbon Grid Erosion in Ion Thrusters

    NASA Technical Reports Server (NTRS)

    Stevens, Richard

    2003-01-01

    Previous investigation under award NAG3-25 10 sought to determine the best method of LIF to determine the carbon density in a thruster plume. Initial reports from other groups were ambiguous as to the number of carbon clusters that might be present in the plume of a thruster. Carbon clusters would certainly affect the ability to LIF; if they were the dominant species, then perhaps the LIF method should target clusters. The results of quadrupole mass spectroscopy on sputtered carbon determined that minimal numbers of clusters were sputtered from graphite under impact from keV Krypton. There were some investigations in the keV range by other groups that hinted at clusters, but at the time the proposal was presented to NASA, there was no data from low-energy sputtering available. Thus, the proposal sought to develop a method to characterize the population only of atoms sputtered from a graphite target in a test cell. Most of the ground work had been established by the previous two years of investigation. The proposal covering 2003 sought to develop an anti-Stokes Raman shifting cell to generate VUW light and test this cell on two different laser systems, ArF and YAG- pumped dye. The second goal was to measure the lowest detectable amounts of carbon atoms by 156.1 nm and 165.7 nm LIF. If equipment was functioning properly, it was expected that these goals would be met easily during the timeframe of the proposal, and that is the reason only modest funding was requested. The PI was only funded at half- time by Glenn during the summer months. All other work time was paid for by Whitworth College. The college also funded a student, Charles Shawley, who worked on the project during the spring.

  13. Evaluation of particle size distributions produced during ultra-violet nanosecond laser ablation and their relative contributions to ion densities in the inductively coupled plasma

    NASA Astrophysics Data System (ADS)

    Moses, Lance M.; Farnsworth, Paul B.

    2015-11-01

    Relative contributions to ion densities in the inductively coupled plasma (ICP) of particles of various sizes produced by laser ablation (LA) were investigated. Particles generated by 266 nm, ns LA of BaF2, CaF2, and a scandium aluminum alloy, characterized using SEM, consisted of hard and soft agglomerates, spherical particles, and irregularly-shaped particles. Although soft agglomerates and spherical particles were common to aerosols generated by LA in all cases, hard agglomerates appeared to be unique to the scandium aluminum alloy, while irregularly-shaped exfoliated particles were unique to the calcium and barium fluoride windows. The spatial distributions of Ca, Ba, and Sc ions in the ICP were determined from laser-induced fluorescence images taken with filters of pore sizes from 1-8 μm added in-line to the transport tube upstream from the ICP. In all cases, a significant fraction of the ions formed in the ICP originated from micron-sized particles. Differences in the penetration depths of nanometer-sized agglomerates and micron-sized particles were about 2 mm for Ca and 1 mm for Ba. Differences in the penetration depths of nanometer and micron-sized agglomerates observed in the case of aluminum scandium were much less significant. This suggests that micron-sized hard-agglomerates and nanometer-sized soft-agglomerates experience very similar vaporization patterns. Additionally, there was evidence that flow patterns in the transport tube affect the trajectories of particles entering the plasma.

  14. Ultra-violet protection and water repellency of polyester fabrics treated by surface deposition of nickel under the effect of low temperature plasma

    NASA Astrophysics Data System (ADS)

    Kan, C. W.; Yuen, C. W. M.

    2007-12-01

    This paper is aimed at understanding the textile properties of nickel-deposited polyester fabric after treating with low temperature plasma treatment. Low temperature plasma treatment with oxygen gas was employed in this paper to activate a hydrophilic surface for the polyester fabrics and hence facilitate the nickel deposition through an electroless plating process. The textile properties of plasma-induced electroless nickel-plated polyester fabrics were evaluated by different standard testing methods in terms of both physical and chemical performances. The electroless nickel plating with plasma treatment improved significantly the performance of nickel-plated polyester fabrics as reflected by the scanning electron microscopy, tensile strength, ultraviolet protection as well as fabric weight. On the contrary, it also enhanced the fabric thickness and colour fastness to crocking. In addition, there was no influence on the performance of colour fastness to light and colourfastness to laundering. Moreover, the application of plasma treatment adversely affected slightly the performance of contact angle and wrinkle recovery property.

  15. Sprayed zinc oxide films: Ultra-violet light-induced reversible surface wettability and platinum-sensitization-assisted improved liquefied petroleum gas response.

    PubMed

    Nakate, Umesh T; Patil, Pramila; Bulakhe, R N; Lokhande, C D; Kale, Sangeeta N; Naushad, Mu; Mane, Rajaram S

    2016-10-15

    We report the rapid (superhydrophobic to superhydrophilic) transition property and improvement in the liquefied petroleum gas (LPG) sensing response of zinc oxide (ZnO) nanorods (NRs) on UV-irradiation and platinum (Pt) surface sensitization, respectively. The morphological evolution of ZnO NRs is evidenced from the field emission scanning electron microscope and atomic force microscope digital images and for the structural elucidation X-ray diffraction pattern is used. Elemental survey mapping is obtained from energy dispersive X-ray analysis spectrum. The optical properties have been studied by UV-Visible and photoluminescence spectroscopy measurements. The rapid (120sec) conversion of superhydrophobic (154°) ZnO NRs film to superhydrophilic (7°) is obtained under UV light illumination and the superhydrophobicity is regained by storing sample in dark. The mechanism for switching wettability behavior of ZnO NRs has thoroughly been discussed. In second phase, Pt-sensitized ZnO NRs film has demonstrated considerable gas sensitivity at 260ppm concentration of LPG. At 623K operating temperature, the maximum LPG response of 58% and the response time of 49sec for 1040ppm LPG concentration of Pt- sensitized ZnO NRs film are obtained. This higher LPG response of Pt-sensitized ZnO NRs film over pristine is primarily due to electronic effect and catalytic effect (spill-over effect) caused by an additional of Pt on ZnO NRs film surface. PMID:27421113

  16. An assessment of the long-term drift in SBUV total ozone data, based on comparison with the Dobson network. [Solar Backscatter UltraViolet experiment

    NASA Technical Reports Server (NTRS)

    Fleig, Albert J.; Bhartia, Pawan K.; Silberstein, David S.

    1986-01-01

    Six years of total ozone data derived from the Nimbus 7 Solar Backscatter Ultraviolet (SBUV) experiment are compared with results from 41 Dobson stations to determine year-to-year changes in addition to the monthly bias change for individual stations and for the network. The SBUV measurements are found to drift against the Dobson stations with a linear trend of .38 + or - .13 percent/yr. The cause of the drift could not be separated between residual uncorrected drift in the SBUV instrument, limited sensitivity of the SBUV to increases in tropospheric ozone, and the effect of local increases in pollution level on individual Dobson stations.

  17. Simultaneous determination of substituted diphenylamine antioxidants and benzotriazole ultra violet stabilizers in blood plasma and fish homogenates by ultra high performance liquid chromatography-electrospray tandem mass spectrometry.

    PubMed

    Lu, Zhe; Peart, Thomas E; Cook, Cyril J; De Silva, Amila O

    2016-08-26

    Analytical methods were developed for the determination of eight substituted diphenylamines (SDPAs) and six benzotriazole UV stabilizers (BZT-UVs) in blood plasma and fish homogenate matrices. Liquid-liquid extraction by methyl tert-butyl ether and denaturation by KOH following silica gel packed column clean-up was employed for blood plasma preparation. For the fish homogenate samples, ultrasonic assisted solvent extraction combined with automated gel permeation chromatography and silica gel packed column clean-up was used. The target compounds were determined by optimized ultra performance liquid chromatography-tandem mass spectrometry in positive electrospray ionization mode. The method limits of quantification (MLOQs) of the 14 analytes ranged from 0.002 to 1.5ngg(-1) and 0.001 to 2.3ngg(-1) (wet weight, w.w.) for blood plasma and fish homogenate, respectively. The total recoveries of the target compounds varied from 61% to 100% (mean 77±9%). Eleven targets including monobutyl- (C4), dibutyl- (C4C4), monooctyl- (C8), monobutyl monooctyl- (C4C8), dioctyl-(C8C8), monononyl- (C9), dinonly-(C9C9) and 4,4'-bis(α,α-dimethylbenzyl)-(diAMS) DPAs, as well as 2-(2H-Benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol (UV234), 2,4-di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl) phenol (UV327) and 2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol (UV328) were identified in the environmental biota samples, with concentrations in the range of 

  18. Climatology of Ultra Violet (UV) irradiance as measured through the Belgian ground-based monitoring network during the time period of 1995-2014

    NASA Astrophysics Data System (ADS)

    Pandey, Praveen; Gillotay, Didier; Depiesse, Cedric

    2016-04-01

    In this study we describe the network of ground-based ultraviolet (UV) radiation monitoring stations in Belgium. The evolution of the entire network, together with the details of measuring instruments is given. The observed cumulative irradiances -UVB, UVA and total solar irradiance (TSI)- over the course of measurement for three stations -a northern (Ostende), central (Uccle) and a southern (Redu)- are shown. The longest series of measurement shown in this study is at Uccle, Brussels, from 1995 till 2014. Thus, the variation of the UV index (UVI), together with the variation of irradiances during summer and winter months at Uccle are shown as a part of this climatological study. The trend of UVB irradiance over the above mentioned three stations is shown. This UVB trend is studied in conjunction with the long-term satellite-based total column ozone value over Belgium, which shows two distinct trends marked by a change point. The total column ozone trend following the change point is positive. It is also seen that the UVB trend is positive for the urban/sub-urban sites: Uccle and Redu. Whereas the UVB trend at Ostende, which is a coastal site, is not positive. A possible explanation of this relation between total column ozone and UVB trend could be associated with aerosols, which is shown in this paper by means of a radiative transfer model based study -as a part of a preliminary investigation. It is seen that the UVI is influenced by the type of aerosols.

  19. Collective electronic excitations in the ultra violet regime in 2-D and 1-D carbon nanostructures achieved by the addition of foreign atoms

    NASA Astrophysics Data System (ADS)

    Bangert, U.; Pierce, W.; Boothroyd, C.; Pan, C.-T.; Gwilliam, R.

    2016-06-01

    Plasmons in the visible/UV energy regime have attracted great attention, especially in nano-materials, with regards to applications in opto-electronics and light harvesting; tailored enhancement of such plasmons is of particular interest for prospects in nano-plasmonics. This work demonstrates that it is possible, by adequate doping, to create excitations in the visible/UV regime in nano-carbon materials, i.e., carbon nanotubes and graphene, with choice of suitable ad-atoms and dopants, which are introduced directly into the lattice by low energy ion implantation or added via deposition by evaporation. Investigations as to whether these excitations are of collective nature, i.e., have plasmonic character, are carried out via DFT calculations and experiment-based extraction of the dielectric function. They give evidence of collective excitation behaviour for a number of the introduced impurity species, including K, Ag, B, N, and Pd. It is furthermore demonstrated that such excitations can be concentrated at nano-features, e.g., along nano-holes in graphene through metal atoms adhering to the edges of these holes.

  20. Separation of water-soluble vitamins by reversed-phase high performance liquid chromatography with ultra-violet detection: application to polyvitaminated premixes.

    PubMed

    Heudi, Olivier; Kilinç, Tamara; Fontannaz, Patric

    2005-04-01

    Nine water-soluble vitamins: [thiamine (B1), ascorbic acid (C), nicotinamide (PP), pyridoxine (B6), calcium pantothenate (B5), folic acid (B9), cyanocobalamin (B12), riboflavin (B2) and biotin (B8)] were separated on a YMC-Pack Pro C18 column (250 mm x 4.6 mm, 5 microm particle size) in a single run with a gradient elution of mobile phase consisting of 0.025% trifluoroacetic acid pH 2.6 (solvent A) and acetonitrile (solvent B). The separation was achieved within 17 min with a flow rate of 0.8 ml min(-1) and the detection was performed at two wavelengths (210 and 275 nm). The calibration graphs plotted with six concentrations of each vitamin were linear with a regression coefficient R2 > 0.995. The method was applied for the quantification of vitamins B1, C, PP, B6, B5, B9 B2 and B8 in polyvitaminated premixes (premixes) used for the fortification of infant nutrition products. The sample preparation involves an aqueous extraction of vitamins and two different samples dilution were used prior the LC-analysis. The specificity of the method was demonstrated by the retention characteristics, UV spectra and by comparing the peak purity with the standard of each vitamin. The repeatability of the method was evaluated at different level of concentrations on 12 premixes and the coefficients of variation (CVr) were below 6.5%. The values of the intermediate precision (CV1) were below 9.6% (n = 6). The concentrations of vitamins found in premixes with our method were comparable to the declared values, since no bias was found between the two sets of results at 95% confidence. The simplicity of the procedure should make it highly desirable for quality control of premixes in the food industry. PMID:15861787

  1. THE EXTREME HOSTS OF EXTREME SUPERNOVAE

    SciTech Connect

    Neill, James D.; Quimby, Robert; Ofek, Eran; Wyder, Ted K.; Martin, D. Christopher; Barlow, Tom A.; Foster, Karl; Friedman, Peter G.; Morrissey, Patrick; Sullivan, Mark; Gal-Yam, Avishay; Howell, D. Andrew; Nugent, Peter; Seibert, Mark; Overzier, Roderik; Neff, Susan G.; Schiminovich, David; Bianchi, Luciana; Donas, Jose; Heckman, Timothy M.

    2011-01-20

    We use GALEX ultraviolet (UV) and optical integrated photometry of the hosts of 17 luminous supernovae (LSNe, having peak M{sub V} < -21) and compare them to a sample of 26, 000 galaxies from a cross-match between the SDSS DR4 spectral catalog and GALEX interim release 1.1. We place the LSN hosts on the galaxy NUV - r versus M{sub r} color-magnitude diagram (CMD) with the larger sample to illustrate how extreme they are. The LSN hosts appear to favor low-density regions of the galaxy CMD falling on the blue edge of the blue cloud toward the low-luminosity end. From the UV-optical photometry, we estimate the star formation history of the LSN hosts. The hosts have moderately low star formation rates (SFRs) and low stellar masses (M{sub *}) resulting in high specific star formation rates (sSFR). Compared with the larger sample, the LSN hosts occupy low-density regions of a diagram plotting sSFR versus M{sub *} in the area having higher sSFR and lower M{sub *}. This preference for low M{sub *}, high sSFR hosts implies that the LSNe are produced by an effect having to do with their local environment. The correlation of mass with metallicity suggests that perhaps wind-driven mass loss is the factor that prevents LSNe from arising in higher-mass, higher-metallicity hosts. The massive progenitors of the LSNe (>100 M{sub sun}), by appearing in low-SFR hosts, are potential tests for theories of the initial mass function that limit the maximum mass of a star based on the SFR.

  2. The extreme ultraviolet explorer mission

    NASA Astrophysics Data System (ADS)

    Bowyer, S.; Malina, R. F.

    The Extreme Ultraviolet Explorer (EUVE) mission, currently scheduled for launch in September 1991, is described. The primary purpose of the mission is to survey the celestial sphere for astronomical sources of extreme ultraviolet (EUV) radiation. The survey will be accomplished with the use of three EUV telescopes, each sensitive to a different segment of the EUV band. A fourth telescope will perform a high sensitivity search of a limited sample of the sky in the shortest wavelength bands. The all-sky survey will be carried out in the first six months of the mission and will be made in four bands, or colors, λλ70-180 Å, 170-250 Å, 400-600 Å, and 500-700 Å. The second phase of the mission, conducted entirely by Guest Observers selected by NASA, will be devoted to spectroscopic observations of EUV sources. The performance of the instrument components is described. The mirrors meet the requirements of the mission, with the best mirror having a full width half energy spread of 4'' and a surface finish of 20 Å. Prototype thin film bandpass filters have been flown on the Space Shuttle and their performance optimized. Prototype detectors have been developed which have 1680 × 1680 pixel imaging capability (RMS) and up to 80% quantum efficiency. A newly invented, high efficiency grazing incidence spectrometer using variable line-space gratings will provide spectral data with ~1 Å resolution. An end-to-end model of the mission, from a stellar source to the resulting scientific data, has been constructed. Hypothetical data from astronomical sources have been processed through this model and are shown.

  3. Extremal quantum cloning machines

    SciTech Connect

    Chiribella, G.; D'Ariano, G. M.; Perinotti, P.; Cerf, N.J.

    2005-10-15

    We investigate the problem of cloning a set of states that is invariant under the action of an irreducible group representation. We then characterize the cloners that are extremal in the convex set of group covariant cloning machines, among which one can restrict the search for optimal cloners. For a set of states that is invariant under the discrete Weyl-Heisenberg group, we show that all extremal cloners can be unitarily realized using the so-called double-Bell states, whence providing a general proof of the popular ansatz used in the literature for finding optimal cloners in a variety of settings. Our result can also be generalized to continuous-variable optimal cloning in infinite dimensions, where the covariance group is the customary Weyl-Heisenberg group of displacement000.

  4. Tibetans at extreme altitude.

    PubMed

    Wu, Tianyi; Li, Shupin; Ward, Michal P

    2005-01-01

    Between 1960 and 2003, 13 Chinese expeditions successfully reached the summit of Chomolungma (Mt Everest or Sagarmatha). Forty-five of the 80 summiteers were Tibetan highlanders. During these and other high-altitude expeditions in Tibet, a series of medical and physiological investigations were carried out on the Tibetan mountaineers. The results suggest that these individuals are better adapted to high altitude and that, at altitude, they have a greater physical capacity than Han (ethnic Chinese) lowland newcomers. They have higher maximal oxygen uptake, greater ventilation, more brisk hypoxic ventilatory responses, larger lung volumes, greater diffusing capacities, and a better quality of sleep. Tibetans also have a lower incidence of acute mountain sickness and less body weight loss. These differences appear to represent genetic adaptations and are obviously significant for humans at extreme altitude. This paper reviews what is known about the physiologic responses of Tibetans at extreme altitudes.

  5. Penetrating extremity trauma.

    PubMed

    Ivatury, Rao R; Anand, Rahul; Ordonez, Carlos

    2015-06-01

    Penetrating extremity trauma (PET) usually becomes less important when present along with multiple truncal injuries. The middle eastern wars documented the terrible mortality and morbidity resulting from PET. Even in civilian trauma, PET can lead to significant morbidity and mortality. There are now well-established principles in the evaluation and management of vascular, bony, soft tissue, and neurologic lesions that will lead to a reduction of the poor outcomes. This review will summarize some of these recent concepts.

  6. On extreme geomagnetic storms

    NASA Astrophysics Data System (ADS)

    Cid, Consuelo; Palacios, Judith; Saiz, Elena; Guerrero, Antonio; Cerrato, Yolanda

    2014-10-01

    Extreme geomagnetic storms are considered as one of the major natural hazards for technology-dependent society. Geomagnetic field disturbances can disrupt the operation of critical infrastructures relying on space-based assets, and can also result in terrestrial effects, such as the Quebec electrical disruption in 1989. Forecasting potential hazards is a matter of high priority, but considering large flares as the only criterion for early-warning systems has demonstrated to release a large amount of false alarms and misses. Moreover, the quantification of the severity of the geomagnetic disturbance at the terrestrial surface using indices as Dst cannot be considered as the best approach to give account of the damage in utilities. High temporal resolution local indices come out as a possible solution to this issue, as disturbances recorded at the terrestrial surface differ largely both in latitude and longitude. The recovery phase of extreme storms presents also some peculiar features which make it different from other less intense storms. This paper goes through all these issues related to extreme storms by analysing a few events, highlighting the March 1989 storm, related to the Quebec blackout, and the October 2003 event, when several transformers burnt out in South Africa.

  7. Tunable, rare earth-doped solid state lasers

    DOEpatents

    Emmett, John L.; Jacobs, Ralph R.; Krupke, William F.; Weber, Marvin J.

    1980-01-01

    Laser apparatus comprising combinations of an excimer pump laser and a rare earth-doped solid matrix, utilizing the 5d-4f radiative transition in a rare earth ion to produce visible and ultra-violet laser radiation with high overall efficiency in selected cases and relatively long radiative lifetimes.

  8. Metagenomics of extreme environments.

    PubMed

    Cowan, D A; Ramond, J-B; Makhalanyane, T P; De Maayer, P

    2015-06-01

    Whether they are exposed to extremes of heat or cold, or buried deep beneath the Earth's surface, microorganisms have an uncanny ability to survive under these conditions. This ability to survive has fascinated scientists for nearly a century, but the recent development of metagenomics and 'omics' tools has allowed us to make huge leaps in understanding the remarkable complexity and versatility of extremophile communities. Here, in the context of the recently developed metagenomic tools, we discuss recent research on the community composition, adaptive strategies and biological functions of extremophiles. PMID:26048196

  9. Upper extremity golf injuries.

    PubMed

    Cohn, Michael A; Lee, Steven K; Strauss, Eric J

    2013-01-01

    Golf is a global sport enjoyed by an estimated 60 million people around the world. Despite the common misconception that the risk of injury during the play of golf is minimal, golfers are subject to a myriad of potential pathologies. While the majority of injuries in golf are attributable to overuse, acute traumatic injuries can also occur. As the body's direct link to the golf club, the upper extremities are especially prone to injury. A thorough appreciation of the risk factors and patterns of injury will afford accurate diagnosis, treatment, and prevention of further injury.

  10. Mineralogy under extreme conditions

    SciTech Connect

    Shu, Jinfu

    2012-02-07

    We have performed measurements of minerals based on the synchrotron source for single crystal and powder X-ray diffraction, inelastic scattering, spectroscopy and radiography by using diamond anvil cells. We investigated the properties of iron (Fe), iron-magnesium oxides (Fe, Mg)O, silica(SiO{sub 2}), iron-magnesium silicates (Fe, Mg)SiO{sub 3} under simulated high pressure-high temperature extreme conditions of the Earth's crust, upper mantle, low mantle, core-mantle boundary, outer core, and inner core. The results provide a new window on the investigation of the mineral properties at Earth's conditions.

  11. Characterizing Extreme Ionospheric Storms

    NASA Astrophysics Data System (ADS)

    Sparks, L.; Komjathy, A.; Altshuler, E.

    2011-12-01

    Ionospheric storms consist of disturbances of the upper atmosphere that generate regions of enhanced electron density typically lasting several hours. Depending upon the storm magnitude, gradients in electron density can sometimes become large and highly localized. The existence of such localized, dense irregularities is a major source of positioning error for users of the Global Positioning System (GPS). Consequently, satellite-based augmentation systems have been implemented to improve the accuracy and to ensure the integrity of user position estimates derived from GPS measurements. Large-scale irregularities generally do not pose a serious threat to estimate integrity as they can be readily detected by such systems. Of greater concern, however, are highly localized irregularities that interfere with the propagation of a signal detected by a user measurement but are poorly sampled by the receivers in the system network. The most challenging conditions have been found to arise following disturbances of large magnitude that occur only rarely over the course of a solar cycle. These extremely disturbed conditions exhibit behavior distinct from moderately disturbed conditions and, hence, have been designated "extreme storms". In this paper we examine and compare the behavior of the extreme ionospheric storms of solar cycle 23 (or, more precisely, extreme storms occurring between January 1, 2000, and December 31, 2008), as represented in maps of vertical total electron content. To identify these storms, we present a robust means of quantifying the regional magnitude of an ionospheric storm. Ionospheric storms are observed frequently to occur in conjunction with magnetic storms, i.e., periods of geophysical activity as measured by magnetometers. While various geomagnetic indices, such as the disturbance storm time (Dst) and the planetary Kp index, have long been used to rank the magnitudes of distinct magnetic storms, no comparable, generally recognized index exists for

  12. Metagenomics of extreme environments.

    PubMed

    Cowan, D A; Ramond, J-B; Makhalanyane, T P; De Maayer, P

    2015-06-01

    Whether they are exposed to extremes of heat or cold, or buried deep beneath the Earth's surface, microorganisms have an uncanny ability to survive under these conditions. This ability to survive has fascinated scientists for nearly a century, but the recent development of metagenomics and 'omics' tools has allowed us to make huge leaps in understanding the remarkable complexity and versatility of extremophile communities. Here, in the context of the recently developed metagenomic tools, we discuss recent research on the community composition, adaptive strategies and biological functions of extremophiles.

  13. Acute extremity compartment syndrome.

    PubMed

    Tumbarello, C

    2000-01-01

    Acute Extremity Compartment Syndrome is a disorder, which can cause loss of limb if left untreated. Compartment syndrome develops when pressures within the fascial compartments become elevated, resulting in decreased perfusion to muscles and nerves. Left untreated, tissue death occurs. Rapid identification of clinical signs can decrease severity of symptoms. Diligent nursing assessment and monitoring of clinical signs, with communication to the physician, will facilitate rapid treatment by the physician. The primary treatment option is early identification and intervention through performance of a fasciotomy.

  14. Extremely Isolated Elliptical Galaxies

    NASA Astrophysics Data System (ADS)

    Fuse, Christopher R.; Marcum, P.; Fanelli, M.; Aars, C.

    2006-06-01

    Isolated galaxies provide a means of assessing the evolution of galactic systems. Extremely isolated galaxies define a zero-interaction baseline for comparative studies of galaxy evolution. We present results of a search for isolated elliptical galaxies (IEGs). We utilize the optical imaging data produced by the Sloan Digital Sky Survey (SDSS) to identify candidate galaxies from Release 1-4 of the SDSS. Candidate IEGs meet strict isolation criteria: Any IEG must be separated by at least 2.5 Mpc from any neighboring non-dwarf galaxy having a MV fainter than -16.5 mag. The candidate isolated systems have no non-dwarf neighbors within a distance such that we can insure that the IEGs have never interacted with another existing galaxy since formation.In order to increase the signal-to-noise ratio, we have used the SDSS images in the u,g,r filters to create combined sets of images for each IEG. The stacked images permit a more robust determination of the morphology of the candidate galaxies. Verification that these are spheroidal systems is achieved through a bulge/disk decomposition technique using standard surface photometry. Our preliminary sample of 51 isolated systems defines a complete volume-limited population of extremely isolated early-type galaxies within a distance of 72Mpc

  15. Solar extreme events

    NASA Astrophysics Data System (ADS)

    Hudson, Hugh S.

    2015-08-01

    Solar flares and CMEs have a broad range of magnitudes. This review discusses the possibility of “extreme events,” defined as those with magnitudes greater than have been seen in the existing historical record. For most quantitative measures, this direct information does not extend more than a century and a half into the recent past. The magnitude distributions (occurrence frequencies) of solar events (flares/CMEs) typically decrease with the parameter measured or inferred (peak flux, mass, energy etc. Flare radiation fluxes tend to follow a power law slightly flatter than S-2, where S represents a peak flux; solar particle events (SPEs) follow a still flatter power law up to a limiting magnitude, and then appear to roll over to a steeper distribution, which may take an exponential form or follow a broken power law. This inference comes from the terrestrial 14C record and from the depth dependence of various radioisotope proxies in the lunar regolith and in meteorites. Recently major new observational results have impacted our use of the relatively limited historical record in new ways: the detection of actual events in the 14C tree-ring records, and the systematic observations of flares and “superflares” by the Kepler spacecraft. I discuss how these new findings may affect our understanding of the distribution function expected for extreme solar events.

  16. Some characterizations of unique extremality

    NASA Astrophysics Data System (ADS)

    Yao, Guowu

    2008-07-01

    In this paper, it is shown that some necessary characteristic conditions for unique extremality obtained by Zhu and Chen are also sufficient and some sufficient ones by them actually imply that the uniquely extremal Beltrami differentials have a constant modulus. In addition, some local properties of uniquely extremal Beltrami differentials are given.

  17. Monster symmetry and extremal CFTs

    NASA Astrophysics Data System (ADS)

    Gaiotto, Davide

    2012-11-01

    We test some recent conjectures about extremal selfdual CFTs, which are the candidate holographic duals of pure gravity in AdS 3. We prove that no c = 48 extremal selfdual CFT or SCFT may possess Monster symmetry. Furthermore, we disprove a recent argument against the existence of extremal selfdual CFTs of large central charge.

  18. Extremophiles and extreme environments.

    PubMed

    Rampelotto, Pabulo Henrique

    2013-08-07

    Over the last decades, the study of extremophiles has providing ground breaking discoveries that challenge the paradigms of modern biology and make us rethink intriguing questions such as "what is life?", "what are the limits of life?", and "what are the fundamental features of life?". These findings and possibilities have made the study of life in extreme environments one of the most exciting areas of research in recent decades. However, despite the latest advances we are just in the beginning of exploring and characterizing the world of extremophiles. This special issue discusses several aspects of these fascinating organisms, exploring their habitats, biodiversity, ecology, evolution, genetics, biochemistry, and biotechnological applications in a collection of exciting reviews and original articles written by leading experts and research groups in the field. [...].

  19. Pulsars and Extreme Physics

    NASA Astrophysics Data System (ADS)

    Bell-Burnell, Jocelyn

    2004-10-01

    Pulsars were discovered 35 years ago. What do we know about them now, and what have they taught us about the extremes of physics? With an average density comparable to that of the nucleus, magnetic fields around 108 T and speeds close to c these objects have stretched our understanding of the behaviour of matter. They serve as extrememly accurate clocks with which to carry out precision experiments in relativity. Created in cataclysmic explosions, pulsars are a (stellar) form of life after death. After half a billion revolutions most pulsars finally die, but amazingly some are born again to yet another, even weirder, afterlife. Pulsar research continues lively, delivering exciting, startling and almost unbelievable results!

  20. Investigating NARCCAP Precipitation Extremes via Bivariate Extreme Value Theory (Invited)

    NASA Astrophysics Data System (ADS)

    Weller, G. B.; Cooley, D. S.; Sain, S. R.; Bukovsky, M. S.; Mearns, L. O.

    2013-12-01

    We introduce methodology from statistical extreme value theory to examine the ability of reanalysis-drive regional climate models to simulate past daily precipitation extremes. Going beyond a comparison of summary statistics such as 20-year return values, we study whether the most extreme precipitation events produced by climate model simulations exhibit correspondence to the most extreme events seen in observational records. The extent of this correspondence is formulated via the statistical concept of tail dependence. We examine several case studies of extreme precipitation events simulated by the six models of the North American Regional Climate Change Assessment Program (NARCCAP) driven by NCEP reanalysis. It is found that the NARCCAP models generally reproduce daily winter precipitation extremes along the Pacific coast quite well; in contrast, simulation of past daily summer precipitation extremes in a central US region is poor. Some differences in the strength of extremal correspondence are seen in the central region between models which employ spectral nudging and those which do not. We demonstrate how these techniques may be used to draw a link between extreme precipitation events and large-scale atmospheric drivers, as well as to downscale extreme precipitation simulated by a future run of a regional climate model. Specifically, we examine potential future changes in the nature of extreme precipitation along the Pacific coast produced by the pineapple express (PE) phenomenon. A link between extreme precipitation events and a "PE Index" derived from North Pacific sea-surface pressure fields is found. This link is used to study PE-influenced extreme precipitation produced by a future-scenario climate model run.

  1. Masks for extreme ultraviolet lithography

    SciTech Connect

    Cardinale, G; Goldsmith, J; Kearney, P A; Larson, C; Moore, C E; Prisbrey, S; Tong, W; Vernon, S P; Weber, F; Yan, P-Y

    1998-09-01

    In extreme ultraviolet lithography (EUVL), the technology specific requirements on the mask are a direct consequence of the utilization of radiation in the spectral region between 10 and 15 nm. At these wavelengths, all condensed materials are highly absorbing and efficient radiation transport mandates the use of all-reflective optical systems. Reflectivity is achieved with resonant, wavelength-matched multilayer (ML) coatings on all of the optical surfaces - including the mask. The EUV mask has a unique architecture - it consists of a substrate with a highly reflective ML coating (the mask blank) that is subsequently over-coated with a patterned absorber layer (the mask). Particulate contamination on the EUVL mask surface, errors in absorber definition and defects in the ML coating all have the potential to print in the lithographic process. While highly developed technologies exist for repair of the absorber layer, no viable strategy for the repair of ML coating defects has been identified. In this paper the state-of-the-art in ML deposition technology, optical inspection of EUVL mask blank defects and candidate absorber patterning approaches are reviewed.

  2. Women in extreme poverty.

    PubMed

    1994-01-01

    Population is estimated to increase from 5.5 billion in 1990 to 10 billion by 2050; the poverty level is expected to increase from 1 billion to 2-3 billion people. Women in development has been promoted throughout the UN and development system, but women in poverty who perform work in the informal sector are still uncounted, and solutions are elusive. The issue of extreme poverty can not be approached as just another natural disaster with immediate emergency relief. Many people live in precarious economic circumstances throughout their lives. Recent research reveals a greater understanding of the underlying causes and the need for inclusion of poor women in sustainable development. Sanitation, water, housing, health facilities need to be improved. Women must have access to education, opportunities for trading, and loans on reasonable terms. UNESCO makes available a book on survival strategies for poor women in the informal sector. The profile shows common problems of illiteracy, broken marriages, and full time involvement in provision of subsistence level existence. Existence is a fragile balance. Jeanne Vickers' "Women and the World" offers simple, low cost interventions for aiding extremely poor women. The 1992 Commission on the Status of Women was held in Vienna. Excerpts from several speeches are provided. The emphasis is on some global responses and an analysis of solutions. The recommendation is for attention to the gender dimension of poverty. Women's dual role contributes to greater disadvantages. Women are affected differently by macroeconomic factors, and that there is intergenerational transfer of poverty. Social services should be viewed as investments and directed to easing the burdens on time and energy. Public programs must be equipped to deal with poverty and to bring about social and economic change. Programs must be aware of the different distribution of resources within households. Women must be recognized as principal economic providers within

  3. Workshop on Extreme Physics

    NASA Astrophysics Data System (ADS)

    Mundell, Carole; Sullivan, Mark

    2012-04-01

    abstract-type="normal">SummaryNever before has there been such a wealth of versatile ground- and space-based facilities with which to detect variable emission across the electromagnetic spectrum and beyond, to non-EM signals such as neutrinos and gravitational waves, to probe the most extreme phenomena in the Universe. The variable sky is already providing a wealth of new and surprising observations of phenomena such as GRBs, SNe and AGN that are pushing current theories beyond the state of the art. Multi-messenger follow-up will soon become de rigeur, and upcoming radio and optical all-sky transient surveys will revolutionise the study of the transient Universe. In addition to the technical and data challenges presented by such surveys, a major new challenge will be the interpretation of the wealth of available data and the identification of the underlying physics of new classes of variable (and potentially exotic) objects. Theoretical predictions will be vital for interpreting these future transient discoveries. The goal of this workshop was to bring together theorists and observers in order to identify unexplored synergies across three main research areas of extreme physics: gamma-ray bursts, supernovæ and, more generically, relativistic jets. It aimed to discuss key outstanding questions in these rapidly moving fields, such as the composition and acceleration of GRB and AGN jets, GRB progenitors and central engines, the origin of the wide range of observed variability time-scales in GRB prompt and after-glow light curves and related cosmological applications, the physics of the newly-discovered ultra-luminous SN-like optical transients-as well as to speculate on what we might hope to discover with future technology. The workshop absorbed two 90-minute sessions, selecting 3 main science topics (Relativistic Jets, GRBs and SNe) which it organised as structured discussions driven by a series of short but provocative questions. The final session featured a panel

  4. Extreme ultraviolet lithography machine

    SciTech Connect

    Tichenor, D.A.; Kubiak, G.D.; Haney, S.J.; Sweeney, D.W.

    2000-02-29

    An extreme ultraviolet lithography (EUVL) machine or system is disclosed for producing integrated circuit (IC) components, such as transistors, formed on a substrate. The EUVL machine utilizes a laser plasma point source directed via an optical arrangement onto a mask or reticle which is reflected by a multiple mirror system onto the substrate or target. The EUVL machine operates in the 10--14 nm wavelength soft x-ray photon. Basically the EUV machine includes an evacuated source chamber, an evacuated main or project chamber interconnected by a transport tube arrangement, wherein a laser beam is directed into a plasma generator which produces an illumination beam which is directed by optics from the source chamber through the connecting tube, into the projection chamber, and onto the reticle or mask, from which a patterned beam is reflected by optics in a projection optics (PO) box mounted in the main or projection chamber onto the substrate. In one embodiment of a EUVL machine, nine optical components are utilized, with four of the optical components located in the PO box. The main or projection chamber includes vibration isolators for the PO box and a vibration isolator mounting for the substrate, with the main or projection chamber being mounted on a support structure and being isolated.

  5. Extreme ultraviolet lithography machine

    DOEpatents

    Tichenor, Daniel A.; Kubiak, Glenn D.; Haney, Steven J.; Sweeney, Donald W.

    2000-01-01

    An extreme ultraviolet lithography (EUVL) machine or system for producing integrated circuit (IC) components, such as transistors, formed on a substrate. The EUVL machine utilizes a laser plasma point source directed via an optical arrangement onto a mask or reticle which is reflected by a multiple mirror system onto the substrate or target. The EUVL machine operates in the 10-14 nm wavelength soft x-ray photon. Basically the EUV machine includes an evacuated source chamber, an evacuated main or project chamber interconnected by a transport tube arrangement, wherein a laser beam is directed into a plasma generator which produces an illumination beam which is directed by optics from the source chamber through the connecting tube, into the projection chamber, and onto the reticle or mask, from which a patterned beam is reflected by optics in a projection optics (PO) box mounted in the main or projection chamber onto the substrate. In one embodiment of a EUVL machine, nine optical components are utilized, with four of the optical components located in the PO box. The main or projection chamber includes vibration isolators for the PO box and a vibration isolator mounting for the substrate, with the main or projection chamber being mounted on a support structure and being isolated.

  6. Detectors in Extreme Conditions

    SciTech Connect

    Blaj, G.; Carini, G.; Carron, S.; Haller, G.; Hart, P.; Hasi, J.; Herrmann, S.; Kenney, C.; Segal, J.; Tomada, A.

    2015-08-06

    Free Electron Lasers opened a new window on imaging the motion of atoms and molecules. At SLAC, FEL experiments are performed at LCLS using 120Hz pulses with 1012 - 1013 photons in 10 femtoseconds (billions of times brighter than the most powerful synchrotrons). This extreme detection environment raises unique challenges, from obvious to surprising. Radiation damage is a constant threat due to accidental exposure to insufficiently attenuated beam, focused beam and formation of ice crystals reflecting the beam onto the detector. Often high power optical lasers are also used (e.g., 25TW), increasing the risk of damage or impeding data acquisition through electromagnetic pulses (EMP). The sample can contaminate the detector surface or even produce shrapnel damage. Some experiments require ultra high vacuum (UHV) with strict design, surface contamination and cooling requirements - also for detectors. The setup is often changed between or during experiments with short turnaround times, risking mechanical and ESD damage, requiring work planning, training of operators and sometimes continuous participation of the LCLS Detector Group in the experiments. The detectors used most often at LCLS are CSPAD cameras for hard x-rays and pnCCDs for soft x-rays.

  7. Understanding water extremes with caution

    NASA Astrophysics Data System (ADS)

    Stehlík, Milan; Stehlíková, Silvia; Torres, Sebastián

    2016-06-01

    We discuss a sensitive topic, how to scientifically estimate extremes in water quality managements. Such extremes are incorporating establishment of thresholds or levels of certain chemicals in the drinking water. In particular, we address the water fluoridation and quality of drinking water in Chile. Statistical approaches demonstrating the necessary background of water manager will be given in a survey exposition to establish link between statistics of extremes and practice.

  8. Upper Extremity Amputations and Prosthetics

    PubMed Central

    Ovadia, Steven A.; Askari, Morad

    2015-01-01

    Upper extremity amputations are most frequently indicated by severe traumatic injuries. The location of the injury will determine the level of amputation. Preservation of extremity length is often a goal. The amputation site will have important implications on the functional status of the patient and options for prosthetic reconstruction. Advances in amputation techniques and prosthetic reconstructions promote improved quality of life. In this article, the authors review the principles of upper extremity amputation, including techniques, amputation sites, and prosthetic reconstructions. PMID:25685104

  9. Predictability of Extreme Events in Social Media

    PubMed Central

    Miotto, José M.; Altmann, Eduardo G.

    2014-01-01

    It is part of our daily social-media experience that seemingly ordinary items (videos, news, publications, etc.) unexpectedly gain an enormous amount of attention. Here we investigate how unexpected these extreme events are. We propose a method that, given some information on the items, quantifies the predictability of events, i.e., the potential of identifying in advance the most successful items. Applying this method to different data, ranging from views in YouTube videos to posts in Usenet discussion groups, we invariantly find that the predictability increases for the most extreme events. This indicates that, despite the inherently stochastic collective dynamics of users, efficient prediction is possible for the most successful items. PMID:25369138

  10. Predictability of extreme events in social media.

    PubMed

    Miotto, José M; Altmann, Eduardo G

    2014-01-01

    It is part of our daily social-media experience that seemingly ordinary items (videos, news, publications, etc.) unexpectedly gain an enormous amount of attention. Here we investigate how unexpected these extreme events are. We propose a method that, given some information on the items, quantifies the predictability of events, i.e., the potential of identifying in advance the most successful items. Applying this method to different data, ranging from views in YouTube videos to posts in Usenet discussion groups, we invariantly find that the predictability increases for the most extreme events. This indicates that, despite the inherently stochastic collective dynamics of users, efficient prediction is possible for the most successful items. PMID:25369138

  11. Upper extremity quad splint: indications and technique.

    PubMed

    DeFroda, Steven F; Gil, Joseph A; Bokshan, Steven; Waryasz, Gregory

    2015-12-01

    Patients experiencing high-energy trauma evaluated at level I trauma centers often present with multiple injuries and varying levels of hemodynamic instability. The polytrauma patient requires immediate assessment and stabilization of their orthopedic injuries once the primary trauma survey is complete, and oftentimes, operative fixation of injuries is delayed while patients are resuscitated by general trauma services. The authors describe the application of the upper extremity "quad" splint which includes components of a sugar tong, intrinsic plus, thumb spica, and dorsal extension blocking splint and its indication for patients with multiple upper extremity fractures distal to the humerus. This splint is efficiently applied using minimal material while simultaneously allowing for the stabilizing aspects of 4 splints commonly applied in the emergency setting. PMID:26472510

  12. Ethyl Lithiodiazoacetate: Extremely Unstable Intermediate Handled Efficiently in Flow.

    PubMed

    Müller, Simon T R; Hokamp, Tobias; Ehrmann, Svenja; Hellier, Paul; Wirth, Thomas

    2016-08-16

    Ethyl diazoacetate (EDA) is one of the most prominent diazo reagents. It is frequently used in metal-carbene-type reactions. However, EDA can also be used as a nucleophile under base catalysis. Whilst the addition of EDA to aldehydes can be performed using organic bases, the addition of EDA to other carbonyl electrophiles requires the use of organometallics such as lithium diisopropylamide (LDA). The generated ethyl lithiodiazoacetate is highly reactive and decomposes rapidly, even at low temperatures. Herein, we report a continuous flow protocol that overcomes the problems associated with the instantaneous decomposition of ethyl lithiodiazoacetate. The addition of ethyl lithiodiazoacetate to ketones provides direct access to tertiary diazoalcohols in good yields.

  13. Gender, Education, Extremism and Security

    ERIC Educational Resources Information Center

    Davies, Lynn

    2008-01-01

    This paper examines the complex relationships between gender, education, extremism and security. After defining extremism and fundamentalism, it looks first at the relationship of gender to violence generally, before looking specifically at how this plays out in more extremist violence and terrorism. Religious fundamentalism is also shown to have…

  14. Denitrification by extremely halophilic bacteria

    NASA Technical Reports Server (NTRS)

    Hochstein, L. I.; Tomlinson, G. A.

    1985-01-01

    Extremely halophilic bacteria were isolated from widely separated sites by anaerobic enrichment in the presence of nitrate. The anaerobic growth of several of these isolates was accompanied by the production of nitrite, nitrous oxide, and dinitrogen. These results are a direct confirmation of the existence of extremely halophilic denitrifying bacteria, and suggest that such bacteria may be common inhabitants of hypersaline environments.

  15. Representing Extremes in Agricultural Models

    NASA Technical Reports Server (NTRS)

    Ruane, Alex

    2015-01-01

    AgMIP and related projects are conducting several activities to understand and improve crop model response to extreme events. This involves crop model studies as well as the generation of climate datasets and scenarios more capable of capturing extremes. Models are typically less responsive to extreme events than we observe, and miss several forms of extreme events. Models also can capture interactive effects between climate change and climate extremes. Additional work is needed to understand response of markets and economic systems to food shocks. AgMIP is planning a Coordinated Global and Regional Assessment of Climate Change Impacts on Agricultural Production and Food Security with an aim to inform the IPCC Sixth Assessment Report.

  16. Extreme events in computational turbulence.

    PubMed

    Yeung, P K; Zhai, X M; Sreenivasan, Katepalli R

    2015-10-13

    We have performed direct numerical simulations of homogeneous and isotropic turbulence in a periodic box with 8,192(3) grid points. These are the largest simulations performed, to date, aimed at improving our understanding of turbulence small-scale structure. We present some basic statistical results and focus on "extreme" events (whose magnitudes are several tens of thousands the mean value). The structure of these extreme events is quite different from that of moderately large events (of the order of 10 times the mean value). In particular, intense vorticity occurs primarily in the form of tubes for moderately large events whereas it is much more "chunky" for extreme events (though probably overlaid on the traditional vortex tubes). We track the temporal evolution of extreme events and find that they are generally short-lived. Extreme magnitudes of energy dissipation rate and enstrophy occur simultaneously in space and remain nearly colocated during their evolution. PMID:26424452

  17. Extreme Mean and Its Applications

    NASA Technical Reports Server (NTRS)

    Swaroop, R.; Brownlow, J. D.

    1979-01-01

    Extreme value statistics obtained from normally distributed data are considered. An extreme mean is defined as the mean of p-th probability truncated normal distribution. An unbiased estimate of this extreme mean and its large sample distribution are derived. The distribution of this estimate even for very large samples is found to be nonnormal. Further, as the sample size increases, the variance of the unbiased estimate converges to the Cramer-Rao lower bound. The computer program used to obtain the density and distribution functions of the standardized unbiased estimate, and the confidence intervals of the extreme mean for any data are included for ready application. An example is included to demonstrate the usefulness of extreme mean application.

  18. Modeling extreme risks in ecology.

    PubMed

    Burgman, Mark; Franklin, James; Hayes, Keith R; Hosack, Geoffrey R; Peters, Gareth W; Sisson, Scott A

    2012-11-01

    Extreme risks in ecology are typified by circumstances in which data are sporadic or unavailable, understanding is poor, and decisions are urgently needed. Expert judgments are pervasive and disagreements among experts are commonplace. We outline approaches to evaluating extreme risks in ecology that rely on stochastic simulation, with a particular focus on methods to evaluate the likelihood of extinction and quasi-extinction of threatened species, and the likelihood of establishment and spread of invasive pests. We evaluate the importance of assumptions in these assessments and the potential of some new approaches to account for these uncertainties, including hierarchical estimation procedures and generalized extreme value distributions. We conclude by examining the treatment of consequences in extreme risk analysis in ecology and how expert judgment may better be harnessed to evaluate extreme risks.

  19. Magnetotactic Bacteria from Extreme Environments

    NASA Astrophysics Data System (ADS)

    Bazylinski, Dennis A.; Lefère, Christopher T.

    2013-03-01

    Magnetotactic bacteria (MTB) represent a diverse collection of motile prokaryotes that biomineralize intracellular, membrane-bounded, tens-of-nanometer-sized crystals of a magnetic mineral called magnetosomes. Magnetosome minerals consist of either magnetite (Fe3O4) or greigite (Fe3S4) and cause cells to align along the Earth's geomagnetic field lines as they swim, a trait called magnetotaxis. MTB are known to mainly inhabit the oxic-anoxic interface (OAI) in water columns or sediments of aquatic habitats and it is currently thought that magnetosomes function as a means of making chemotaxis more efficient in locating and maintaining an optimal position for growth and survival at the OAI. Known cultured and uncultured MTB are phylogenetically associated with the Alpha-, Gamma- and Deltaproteobacteria classes of the phylum Proteobacteria, the Nitrospirae phylum and the candidate division OP3, part of the Planctomycetes-Verrucomicrobia-Chlamydiae (PVC) bacterial superphylum. MTB are generally thought to be ubiquitous in aquatic environments as they are cosmopolitan in distribution and have been found in every continent although for years MTB were thought to be restricted to habitats with pH values near neutral and at ambient temperature. Recently, however, moderate thermophilic and alkaliphilic MTB have been described including: an uncultured, moderately thermophilic magnetotactic bacterium present in hot springs in northern Nevada with a probable upper growth limit of about 63 °C; and several strains of obligately alkaliphilic MTB isolated in pure culture from different aquatic habitats in California, including the hypersaline, extremely alkaline Mono Lake, with an optimal growth pH of >9.0.

  20. Magnetotactic Bacteria from Extreme Environments

    PubMed Central

    Bazylinski, Dennis A.; Lefèvre, Christopher T.

    2013-01-01

    Magnetotactic bacteria (MTB) represent a diverse collection of motile prokaryotes that biomineralize intracellular, membrane-bounded, tens-of-nanometer-sized crystals of a magnetic mineral called magnetosomes. Magnetosome minerals consist of either magnetite (Fe3O4) or greigite (Fe3S4) and cause cells to align along the Earth’s geomagnetic field lines as they swim, a trait called magnetotaxis. MTB are known to mainly inhabit the oxic–anoxic interface (OAI) in water columns or sediments of aquatic habitats and it is currently thought that magnetosomes function as a means of making chemotaxis more efficient in locating and maintaining an optimal position for growth and survival at the OAI. Known cultured and uncultured MTB are phylogenetically associated with the Alpha-, Gamma- and Deltaproteobacteria classes of the phylum Proteobacteria, the Nitrospirae phylum and the candidate division OP3, part of the Planctomycetes-Verrucomicrobia-Chlamydiae (PVC) bacterial superphylum. MTB are generally thought to be ubiquitous in aquatic environments as they are cosmopolitan in distribution and have been found in every continent although for years MTB were thought to be restricted to habitats with pH values near neutral and at ambient temperature. Recently, however, moderate thermophilic and alkaliphilic MTB have been described including: an uncultured, moderately thermophilic magnetotactic bacterium present in hot springs in northern Nevada with a probable upper growth limit of about 63 °C; and several strains of obligately alkaliphilic MTB isolated in pure culture from different aquatic habitats in California, including the hypersaline, extremely alkaline Mono Lake, with an optimal growth pH of >9.0. PMID:25369742

  1. Extreme Thrombocytosis and Cardiovascular Surgery

    PubMed Central

    Natelson, Ethan A.

    2012-01-01

    Extreme thrombocytosis is a major risk factor for excessive bleeding and for thrombosis, either of which can complicate cardiovascular surgical and interventional procedures. Extreme thrombocytosis can also cause an unusual syndrome, erythromelalgia, that results in a type of chronic microvascular occlusive arterial disease. We present the differential diagnosis of conditions that may lead to extreme thrombocytosis, 3 cases (each of which illustrates a different potential complication), and a review of the pertinent medical literature. Correcting excessive thrombocytosis is typically not difficult, whether electively or acutely, and effective therapy usually controls thrombosis and excessive hemorrhage postprocedurally. PMID:23304015

  2. Nonparametric Spatial Models for Extremes: Application to Extreme Temperature Data.

    PubMed

    Fuentes, Montserrat; Henry, John; Reich, Brian

    2013-03-01

    Estimating the probability of extreme temperature events is difficult because of limited records across time and the need to extrapolate the distributions of these events, as opposed to just the mean, to locations where observations are not available. Another related issue is the need to characterize the uncertainty in the estimated probability of extreme events at different locations. Although the tools for statistical modeling of univariate extremes are well-developed, extending these tools to model spatial extreme data is an active area of research. In this paper, in order to make inference about spatial extreme events, we introduce a new nonparametric model for extremes. We present a Dirichlet-based copula model that is a flexible alternative to parametric copula models such as the normal and t-copula. The proposed modelling approach is fitted using a Bayesian framework that allow us to take into account different sources of uncertainty in the data and models. We apply our methods to annual maximum temperature values in the east-south-central United States. PMID:24058280

  3. Terrestrial Applications of Extreme Environment Stirling Space Power Systems

    NASA Technical Reports Server (NTRS)

    Dyson, Rodger. W.

    2012-01-01

    NASA has been developing power systems capable of long-term operation in extreme environments such as the surface of Venus. This technology can use any external heat source to efficiently provide electrical power and cooling; and it is designed to be extremely efficient and reliable for extended space missions. Terrestrial applications include: use in electric hybrid vehicles; distributed home co-generation/cooling; and quiet recreational vehicle power generation. This technology can reduce environmental emissions, petroleum consumption, and noise while eliminating maintenance and environmental damage from automotive fluids such as oil lubricants and air conditioning coolant. This report will provide an overview of this new technology and its applications.

  4. Hall sensors for extreme temperatures.

    PubMed

    Jankowski, Jakub; El-Ahmar, Semir; Oszwaldowski, Maciej

    2011-01-01

    We report on the preparation of the first complete extreme temperature Hall sensor. This means that the extreme-temperature magnetic sensitive semiconductor structure is built-in an extreme-temperature package especially designed for that purpose. The working temperature range of the sensor extends from -270 °C to +300 °C. The extreme-temperature Hall-sensor active element is a heavily n-doped InSb layer epitaxially grown on GaAs. The magnetic sensitivity of the sensor is ca. 100 mV/T and its temperature coefficient is less than 0.04 %/K. This sensor may find applications in the car, aircraft, spacecraft, military and oil and gas industries.

  5. Muscles of the Lower Extremity

    MedlinePlus

    ... Home » Cancer Registration & Surveillance Modules » Anatomy & Physiology » Muscular System » Muscle Groups » Lower Extremity Cancer Registration & Surveillance Modules Anatomy & Physiology Intro to the Human Body Body Functions & Life Process Anatomical Terminology Review Quiz ...

  6. Extreme events in computational turbulence

    PubMed Central

    Yeung, P. K.; Zhai, X. M.; Sreenivasan, Katepalli R.

    2015-01-01

    We have performed direct numerical simulations of homogeneous and isotropic turbulence in a periodic box with 8,1923 grid points. These are the largest simulations performed, to date, aimed at improving our understanding of turbulence small-scale structure. We present some basic statistical results and focus on “extreme” events (whose magnitudes are several tens of thousands the mean value). The structure of these extreme events is quite different from that of moderately large events (of the order of 10 times the mean value). In particular, intense vorticity occurs primarily in the form of tubes for moderately large events whereas it is much more “chunky” for extreme events (though probably overlaid on the traditional vortex tubes). We track the temporal evolution of extreme events and find that they are generally short-lived. Extreme magnitudes of energy dissipation rate and enstrophy occur simultaneously in space and remain nearly colocated during their evolution. PMID:26424452

  7. Extremal surfaces and entanglement entropy

    NASA Astrophysics Data System (ADS)

    Pal, Shesansu Sekhar

    2014-05-01

    We have obtained the equation of the extremal hypersurface by considering the Jacobson-Myers functional and computed the entanglement entropy. In this context, we show that the higher derivative corrected extremal surfaces cannot penetrate the horizon. Also, we have studied the entanglement temperature and entanglement entropy for low excited states for such higher derivative theories when the entangling region is of the strip type.

  8. Linking Extreme Weather Events and Extreme ENSO States

    NASA Astrophysics Data System (ADS)

    Perlwitz, J.; Hoerling, M. P.; Xu, T.; Hoell, A.; Cheng, L.; Wolter, K.

    2015-12-01

    To what extent are the risks of extreme weather events over the contiguous US, such as heavy precipitation, heat and cold waves, conditioned by the state of tropical east Pacific SSTs? Further, do extreme magnitudes of El Niño and La Niña events exert a unique and particularly strong controlling effect on weather extremes? Here, we utilize both observations and multi-model large ensemble historical simulations to characterize the behavior of 5-day maximum precipitation distributions. We focus on relations between ENSO impacts on seasonal means and weather extremes, and explore the distinction between effects based on ENSO phase and intensity. For the cold season (November to April), overall ENSO impacts on mean precipitation are shown to be consistent with observations. This signal includes enhanced seasonal mean precipitation over the southern part of the U.S. and central Great Plains during El Niño, and enhanced seasonal mean precipitation over the Midwest during La Nina. We further demonstrate how these signals change under the influence of the most extreme ENSO events, conditions that are difficult to verify from observations owing to small sample sizes, but are modeled via large ensemble methods. The statistics of 5-day maximum precipitation, with a focus on 20-year return levels that characterizes rare but potentially damaging events, are examined. We demonstrate substantial differences in changes in the risk of extreme 5-day precipitation and the seasonal mean precipitation signal, especially in such regions as California, and the western Great Plains including the Front Range of the Rockies from Montana to New Mexico. The plausibility of such behavior is discussed via physical considerations and by examining the structural uncertainty in such outcomes across three different climate models.

  9. Are hourly precipitation extremes increasing faster than daily precipitation extremes?

    NASA Astrophysics Data System (ADS)

    Barbero, Renaud; Fowler, Hayley; Blenkinsop, Stephen; Lenderink, Geert

    2016-04-01

    Extreme precipitation events appear to be increasing with climate change in many regions of the world, including the United States. These extreme events have large societal impacts, as seen during the recent Texas-Oklahoma flooding in May 2015 which caused several billion in damages and left 47 deaths in its path. Better understanding of past changes in the characteristics of extreme rainfall events is thus critical for reliable projections of future changes. Although it has been documented in several studies that daily precipitation extremes are increasing across parts of the contiguous United States, very few studies have looked at hourly extremes. However, this is of primary importance as recent studies on the temperature scaling of extreme precipitation have shown that increases above the Clausius-Clapeyron (~ 7% °C‑1) are possible for hourly precipitation. In this study, we used hourly precipitation data (HPD) from the National Climatic Data Center and extracted more than 1,000 stations across the US with more than 40 years of data spanning the period 1950-2010. As hourly measurements are often associated with a range of issues, the data underwent multiple quality control processes to exclude erroneous data. While no significant changes were found in annual maximum precipitation using both hourly and daily resolution datasets, significant increasing trends in terms of frequency of episodes exceeding present-day 95th percentiles of wet hourly/daily precipitation were observed across a significant portion of the US. The fraction of stations with significant increasing trends falls outside the confidence interval range during all seasons but the summer. While less than 12% of stations exhibit significant trends at the daily scale in the wintertime, more than 45% of stations, mostly clustered in central and Northern United States, show significant increasing trends at the hourly scale. This suggests that short-duration storms have increased faster than daily

  10. Study of extreme nuclear shapes in extreme conditions

    SciTech Connect

    Banerjee, Sudhee Ranjan

    2014-08-14

    Studies of extreme nuclear shapes have always fascinated scientists and are being pursued quite strongly over the years. Nuclei present themselves with interesting shapes and structures at different conditions of spin, excitation and also with the number of neutrons and/or protons in them. Gamma decays from the Giant dipole Resonances in nuclei can probe directly their shapes at different extreme conditions by looking at their resonant line-shapes, e.g., Jacobi shapes and shape-transitions, super/hyper-deformation etc. Similar such studies, done for the first time, using the LAMBDA high energy gamma spectrometer developed at VECC, is discussed here.

  11. Are hourly precipitation extremes increasing faster than daily precipitation extremes?

    NASA Astrophysics Data System (ADS)

    Barbero, Renaud; Fowler, Hayley; Blenkinsop, Stephen; Lenderink, Geert

    2016-04-01

    Extreme precipitation events appear to be increasing with climate change in many regions of the world, including the United States. These extreme events have large societal impacts, as seen during the recent Texas-Oklahoma flooding in May 2015 which caused several billion in damages and left 47 deaths in its path. Better understanding of past changes in the characteristics of extreme rainfall events is thus critical for reliable projections of future changes. Although it has been documented in several studies that daily precipitation extremes are increasing across parts of the contiguous United States, very few studies have looked at hourly extremes. However, this is of primary importance as recent studies on the temperature scaling of extreme precipitation have shown that increases above the Clausius-Clapeyron (~ 7% °C-1) are possible for hourly precipitation. In this study, we used hourly precipitation data (HPD) from the National Climatic Data Center and extracted more than 1,000 stations across the US with more than 40 years of data spanning the period 1950-2010. As hourly measurements are often associated with a range of issues, the data underwent multiple quality control processes to exclude erroneous data. While no significant changes were found in annual maximum precipitation using both hourly and daily resolution datasets, significant increasing trends in terms of frequency of episodes exceeding present-day 95th percentiles of wet hourly/daily precipitation were observed across a significant portion of the US. The fraction of stations with significant increasing trends falls outside the confidence interval range during all seasons but the summer. While less than 12% of stations exhibit significant trends at the daily scale in the wintertime, more than 45% of stations, mostly clustered in central and Northern United States, show significant increasing trends at the hourly scale. This suggests that short-duration storms have increased faster than daily

  12. Transverse deformations of extreme horizons

    NASA Astrophysics Data System (ADS)

    Li, Carmen; Lucietti, James

    2016-04-01

    We consider the inverse problem of determining all extreme black hole solutions to the Einstein equations with a prescribed near-horizon geometry. We investigate this problem by considering infinitesimal deformations of the near-horizon geometry along transverse null geodesics. We show that, up to a gauge transformation, the linearised Einstein equations reduce to an elliptic PDE for the extrinsic curvature of a cross-section of the horizon. We deduce that for a given near-horizon geometry there exists a finite dimensional moduli space of infinitesimal transverse deformations. We then establish a uniqueness theorem for transverse deformations of the extreme Kerr horizon. In particular, we prove that the only smooth axisymmetric transverse deformation of the near-horizon geometry of extreme Kerr, such that cross-sections of the horizon are marginally trapped surfaces, corresponds to that of the extreme Kerr black hole. Furthermore, we determine all smooth and biaxisymmetric transverse deformations of the near-horizon geometry of the five-dimensional extreme Myers-Perry black hole with equal angular momenta. We find a three parameter family of solutions such that cross-sections of the horizon are marginally trapped, which is more general than the known black hole solutions. We discuss the possibility that they correspond to new five-dimensional vacuum black holes.

  13. [Extreme results in electrolyte determination].

    PubMed

    Vogt, W; Oesterle, B

    1992-01-01

    Besides statistical quality control, quality control based on patient specimens is an important tool for quality enhancement and thus for an increased diagnostic certainty in laboratory medicine. One of three possibilities of plausibility judgement is the control of extreme results, that is alert and absurd value check. The aim of our study was to look for extremely high or low findings of the most frequently examined clinical-chemical parameters, to scrutinize their validity according to clearly defined criteria and to find out the underlying actual clinical situations and diseases. In this publication only the results for the electrolytes are discussed. Retrospectively the most extreme values of all results for serum sodium, potassium and chloride concentrations of a 21-month interval were extracted in a large university hospital. The clinical situation was then evaluated by reading the medical reports of these patients. The validity of the findings was judged by previously defined criteria and rated as confirmed, questionable and not confirmed. In all cases the survival time was determined. The most extreme confirmed results were for sodium 191 and 100 mmol/l, for potassium 9.0 and 1.3 mmol/l and for chloride 138 and 65 mmol/l. All these findings were compatible with life, at least for several hours. Even if it is probably impossible to give generally valid extreme ranges. Nevertheless our results should certainly have practical importance in absurd and alert value check. PMID:1502820

  14. Extreme Space Weather on Exoplanets

    NASA Astrophysics Data System (ADS)

    Cohen, O.; Drake, J. J.; Kashyap, V. L.; Glocer, A.; Garraffo, C.; Gombosi, T. I.

    2013-12-01

    The current search for exoplanets is focused on detecting Earth-like rocky planets in the habitable zone around faint, M-dwarf stars, where the definition of the habitable zone is the bounded distances from the star at which liquid water can exist on the planetary surface. However, other factors may play a role in the habitability of the planet. In particular, planets that orbit their host star in a close-in orbit, reside in an extreme space environment, where both the stellar wind and transient Coronal Mass Ejections (CMEs) can erode the planetary atmosphere. We present a detailed, three-dimensional modeling study of the space plasma physics of close-in exoplanets. The study includes the effect of the extreme space conditions on the planetary atmosphere, magnetospheric and upper atmosphere dynamics, extreme space weather on close-in planets, and star-planet magnetic interaction.

  15. Extreme, expedition, and wilderness medicine.

    PubMed

    Imray, Christopher H E; Grocott, Michael P W; Wilson, Mark H; Hughes, Amy; Auerbach, Paul S

    2015-12-19

    Extreme, expedition, and wilderness medicine are modern and rapidly evolving specialties that address the spirit of adventure and exploration. The relevance of and interest in these specialties are changing rapidly to match the underlying activities, which include global exploration, adventure travel, and military deployments. Extreme, expedition, and wilderness medicine share themes of providing best available medical care in the outdoors, especially in austere or remote settings. Early clinical and logistics decision making can often have important effects on subsequent outcomes. There are lessons to be learned from out-of-hospital care, military medicine, humanitarian medicine, and disaster medicine that can inform in-hospital medicine, and vice-versa. The future of extreme, expedition, and wilderness medicine will be defined by both recipients and practitioners, and empirical observations will be transformed by evidence-based practice.

  16. Extreme hydrological events and security

    NASA Astrophysics Data System (ADS)

    Kundzewicz, Z. W.; Matczak, P.

    2015-06-01

    Economic losses caused by hydrological extremes - floods and droughts - have been on the rise, worldwide. Hydrological extremes jeopardize human security and cause serious threats to human life and welfare and societal livelihood. Floods and droughts can undermine societies' security, understood as freedom from threat and the ability of societies to maintain their independent identity and their functional integrity against forces of change. Several dimensions of security are reviewed in the context of hydrological extremes. Floods and droughts pose a burden and serious challenges to the state, responsible to sustain economic development, societal and environmental security - the maintenance of ecosystem services, on which a society depends. It is shown that reduction of risk of hydrological disasters improves human security.

  17. Extreme, expedition, and wilderness medicine.

    PubMed

    Imray, Christopher H E; Grocott, Michael P W; Wilson, Mark H; Hughes, Amy; Auerbach, Paul S

    2015-12-19

    Extreme, expedition, and wilderness medicine are modern and rapidly evolving specialties that address the spirit of adventure and exploration. The relevance of and interest in these specialties are changing rapidly to match the underlying activities, which include global exploration, adventure travel, and military deployments. Extreme, expedition, and wilderness medicine share themes of providing best available medical care in the outdoors, especially in austere or remote settings. Early clinical and logistics decision making can often have important effects on subsequent outcomes. There are lessons to be learned from out-of-hospital care, military medicine, humanitarian medicine, and disaster medicine that can inform in-hospital medicine, and vice-versa. The future of extreme, expedition, and wilderness medicine will be defined by both recipients and practitioners, and empirical observations will be transformed by evidence-based practice. PMID:26738718

  18. Functional metagenomics of extreme environments.

    PubMed

    Mirete, Salvador; Morgante, Verónica; González-Pastor, José Eduardo

    2016-04-01

    The bioprospecting of enzymes that operate under extreme conditions is of particular interest for many biotechnological and industrial processes. Nevertheless, there is a considerable limitation to retrieve novel enzymes as only a small fraction of microorganisms derived from extreme environments can be cultured under standard laboratory conditions. Functional metagenomics has the advantage of not requiring the cultivation of microorganisms or previous sequence information to known genes, thus representing a valuable approach for mining enzymes with new features. In this review, we summarize studies showing how functional metagenomics was employed to retrieve genes encoding for proteins involved not only in molecular adaptation and resistance to extreme environmental conditions but also in other enzymatic activities of biotechnological interest.

  19. Shear Fractures of Extreme Dynamics

    NASA Astrophysics Data System (ADS)

    Tarasov, Boris

    2016-10-01

    Natural and laboratory observations show that shear ruptures (faults) can propagate with extreme dynamics (up to intersonic rupture velocities) through intact materials and along pre-existing faults with frictional and coherent (bonded) interfaces. The rupture propagation is accompanied by significant fault strength weakening in the rupture head. Although essential for understanding earthquakes, rock mechanics, tribology and fractures, the question of what physical processes determine how that weakening occurs is still unresolved. The general approach today to explain the fault weakening is based upon the strong velocity-weakening friction law according to which the fault strength drops rapidly with slip velocity. Different mechanisms of strength weakening caused by slip velocity have been proposed including thermal effect, high-frequency compressional waves, expansion of pore fluid, macroscopic melting and gel formation. This paper proposes that shear ruptures of extreme dynamics propagating in intact materials and in pre-existing frictional and coherent interfaces are governed by the same recently identified mechanism which is associated with an intensive microcracking process in the rupture tip observed for all types of extreme ruptures. The microcracking process creates, in certain conditions, a special fan-like microstructure shear resistance of which is extremely low (up to an order of magnitude less than the frictional strength). The fan-structure representing the rupture head provides strong interface weakening and causes high slip and rupture velocities. In contrast with the velocity-weakening dependency, this mechanism provides the opposite weakening-velocity effect. The fan-mechanism differs remarkably from all reported earlier mechanisms, and it can provide such important features observed in extreme ruptures as: extreme slip and rupture velocities, high slip velocity without heating, off-fault tensile cracking, transition from crack-like to pulse

  20. Extreme value analysis in biometrics.

    PubMed

    Hüsler, Jürg

    2009-04-01

    We review some approaches of extreme value analysis in the context of biometrical applications. The classical extreme value analysis is based on iid random variables. Two different general methods are applied, which will be discussed together with biometrical examples. Different estimation, testing, goodness-of-fit procedures for applications are discussed. Furthermore, some non-classical situations are considered where the data are possibly dependent, where a non-stationary behavior is observed in the data or where the observations are not univariate. A few open problems are also stated.

  1. Extreme Conditions Modeling Workshop Report

    SciTech Connect

    Coe, R. G.; Neary, V. S.; Lawson, M. J.; Yu, Y.; Weber, J.

    2014-07-01

    Sandia National Laboratories (SNL) and the National Renewable Energy Laboratory (NREL) hosted the Wave Energy Converter (WEC) Extreme Conditions Modeling (ECM) Workshop in Albuquerque, NM on May 13th-14th, 2014. The objective of the workshop was to review the current state of knowledge on how to model WECs in extreme conditions (e.g. hurricanes and other large storms) and to suggest how U.S. Department of Energy (DOE) and national laboratory resources could be used to improve ECM methods for the benefit of the wave energy industry.

  2. Flexible Diaphragm Withstands Extreme Temperatures

    NASA Technical Reports Server (NTRS)

    Lerma, G.

    1986-01-01

    Diaphragm seal retains flexibility throughout temperature range of -200 to +600 degree F (-129 to +316 degree C). Diaphragm durable, simple, versatile, and relatively inexpensive to manufacture. Suitable for refrigeration seals, autoclaves, storage lockers, and other sealing applications subjected to extreme temperature differentials.

  3. How Cells Endure Extreme Conditions

    SciTech Connect

    2009-01-01

    One of natures most gripping feats of survival is now better understood. For the first time, Berkeley Lab scientists observed the chemical changes in individual cells that enable them to survive in conditions that should kill them. http://newscenter.lbl.gov/feature-stories/2009/07/07/cells-endure-extremes/

  4. Patterned Growth in Extreme Environments

    NASA Astrophysics Data System (ADS)

    Curnutt, J.; Gomez, E.; Schubert, K. E.

    2009-12-01

    In this paper, cellular automata are used to model patterned growth of organisms in extreme environments. A brief introduction to cellular automaton modeling is given to assist the reader. Patterned growth of soil surface cyanobacteria and biovermiculation microbial mats in sulfuric acid caves are modeled and simulations conducted. Simulations are compared with actual systems, and future directions are discussed.

  5. Tetrasulfide extreme pressure lubricant additives

    SciTech Connect

    Gast, L.E.; Kenney, H.E.; Schwab, A.W.

    1980-08-19

    A novel class of compounds has been prepared comprising the tetrasulfides of /sup 18/C hydrocarbons, /sup 18/C fatty acids, and /sup 18/C fatty and alkyl and triglyceride esters. These tetrasulfides are useful as extreme pressure lubricant additives and show potential as replacements for sulfurized sperm whale oil.

  6. Astrobiology: Life in Extreme Environments

    ERIC Educational Resources Information Center

    Kaur, Preeti

    2011-01-01

    Astrobiology is the study of the origin, evolution and distribution of life in the universe. It seeks to answer two important scientific questions: how did we get here and are we alone in the universe? Scientists begin by studying life on Earth and its limits. The discovery of extremophiles on Earth capable of surviving extremes encourages the…

  7. Applied extreme-value statistics

    SciTech Connect

    Kinnison, R.R.

    1983-05-01

    The statistical theory of extreme values is a well established part of theoretical statistics. Unfortunately, it is seldom part of applied statistics and is infrequently a part of statistical curricula except in advanced studies programs. This has resulted in the impression that it is difficult to understand and not of practical value. In recent environmental and pollution literature, several short articles have appeared with the purpose of documenting all that is necessary for the practical application of extreme value theory to field problems (for example, Roberts, 1979). These articles are so concise that only a statistician can recognise all the subtleties and assumptions necessary for the correct use of the material presented. The intent of this text is to expand upon several recent articles, and to provide the necessary statistical background so that the non-statistician scientist can recognize and extreme value problem when it occurs in his work, be confident in handling simple extreme value problems himself, and know when the problem is statistically beyond his capabilities and requires consultation.

  8. The Extreme Universe Space Observatory

    NASA Technical Reports Server (NTRS)

    Adams, Jim; Six, N. Frank (Technical Monitor)

    2002-01-01

    This talk will describe the Extreme Universe Space Observatory (EUSO) mission. EUSO is an ESA mission to explore the most powerful energy sources in the universe. The mission objectives of EUSO are to investigate EECRs, those with energies above 3x10(exp 19) eV, and very high-energy cosmic neutrinos. These objectives are directly related to extreme conditions in the physical world and possibly involve the early history of the big bang and the framework of GUTs. EUSO tackles the basic problem posed by the existence of these extreme-energy events. The solution could have a unique impact on fundamental physics, cosmology, and/or astrophysics. At these energies, magnetic deflection is thought to be so small that the EECR component would serve as the particle channel for astronomy. EUSO will make the first measurements of EAS from space by observing atmospheric fluorescence in the Earth's night sky. With measurements of the airshower track, EUSO will determine the energy and arrival direction of these extreme-energy events. EUSO will make high statistics observations of CRs beyond the predicted GZK cutoff energy and widen the channel for high-energy neutrino astronomy. The energy spectra, arrival directions, and shower profiles will be analyzed to distinguish the nature of these events and search for their sources. With EUSO data, we will have the possibility to discover a local EECR source, test Z-burst scenarios and other theories, and look for evidence of the breakdown of the relativity principle at extreme Lorentz factors.

  9. Extremal higher spin black holes

    NASA Astrophysics Data System (ADS)

    Bañados, Máximo; Castro, Alejandra; Faraggi, Alberto; Jottar, Juan I.

    2016-04-01

    The gauge sector of three-dimensional higher spin gravities can be formulated as a Chern-Simons theory. In this context, a higher spin black hole corresponds to a flat connection with suitable holonomy (smoothness) conditions which are consistent with the properties of a generalized thermal ensemble. Building on these ideas, we discuss a definition of black hole extremality which is appropriate to the topological character of 3 d higher spin theories. Our definition can be phrased in terms of the Jordan class of the holonomy around a non-contractible (angular) cycle, and we show that it is compatible with the zero-temperature limit of smooth black hole solutions. While this notion of extremality does not require supersymmetry, we exemplify its consequences in the context of sl(3|2) ⊕ sl(3|2) Chern-Simons theory and show that, as usual, not all extremal solutions preserve supersymmetries. Remarkably, we find in addition that the higher spin setup allows for non-extremal supersymmetric black hole solutions. Furthermore, we discuss our results from the perspective of the holographic duality between sl(3|2) ⊕ sl(3|2) Chern-Simons theory and two-dimensional CFTs with W (3|2) symmetry, the simplest higher spin extension of the N = 2 super-Virasoro algebra. In particular, we compute W (3|2) BPS bounds at the full quantum level, and relate their semiclassical limit to extremal black hole or conical defect solutions in the 3 d bulk. Along the way, we discuss the role of the spectral flow automorphism and provide a conjecture for the form of the semiclassical BPS bounds in general N = 2 two-dimensional CFTs with extended symmetry algebras.

  10. Earth's Thermosphere under extreme solar EUV radiation environment

    NASA Astrophysics Data System (ADS)

    Tian, F.; Solomon, S. C.; Qian, L.; Roble, R. G.; Liu, H.; Kasting, J. F.

    2007-12-01

    It has been suggested that the exobase temperature of early terrestrial planetary atmosphere could have reached over 10,000 K (Kulikov et al. 2006) due to the extreme (up to 100 times that of today) solar EUV energy flux from the young Sun during the early stage of planetary evolution. Such high exobase temperature should have caused the dominant species at the exobase to escape at significant rate. Extremely fast escape of major gases in planetary atmospheres will lead to deviation from hydrostatic equilibrium. A newly developed 1-D, multi-component, hydrodynamic model has been used to investigate the response of Earth's thermosphere/ionosphere to extreme solar EUV conditions (Tian et al. 2007). We found that Earth's thermosphere/ionosphere could experience the transition from a hydrostatic equilibrium regime into a hydrodynamic regime when exposed to solar EUV fluxes exceeding certain critical level. In this regime, adiabatic cooling related to the hydrodynamic flow must be taken into the energy consideration. Due to extreme solar EUV fluxes, atomic nitrogen may have been the dominant species in upper thermosphere instead of atomic oxygen. In this work, we couple the hydrodynamic thermosphere model with an expanded GLOW model (including the electron impact ionization and excitation of nitrogen atoms) to investigate the contributions of photoelectrons and secondary electrons to thermospheric energetics under extreme conditions. The combined model provides self- consistent heating efficiency estimates for the Earth's atmosphere under extreme conditions. Implications of the simulation results to other early planetary atmospheres and their evolutions will be discussed.

  11. Detecting Extreme Events in Gridded Climate Data

    SciTech Connect

    Ramachandra, Bharathkumar; Gadiraju, Krishna; Vatsavai, Raju; Kaiser, Dale Patrick; Karnowski, Thomas Paul

    2016-01-01

    Detecting and tracking extreme events in gridded climatological data is a challenging problem on several fronts: algorithms, scalability, and I/O. Successful detection of these events will give climate scientists an alternate view of the behavior of different climatological variables, leading to enhanced scientific understanding of the impacts of events such as heat and cold waves, and on a larger scale, the El Nin o Southern Oscillation. Recent advances in computing power and research in data sciences enabled us to look at this problem with a different perspective from what was previously possible. In this paper we present our computationally efficient algorithms for anomalous cluster detection on climate change big data. We provide results on detection and tracking of surface temperature and geopotential height anomalies, a trend analysis, and a study of relationships between the variables. We also identify the limitations of our approaches, future directions for research and alternate approaches.

  12. Extreme overbalance perforating improves well performance

    SciTech Connect

    Dees, J.M.; Handren, P.J.

    1994-01-01

    The application of extreme overbalance perforating, by Oryx Energy Co., is consistently outperforming the unpredictable, tubing-conveyed, underbalance perforating method which is generally accepted as the industry standard. Successful results reported from more than 60 Oryx Energy wells, applying this technology, support this claim. Oryx began this project in 1990 to address the less-than-predictable performance of underbalanced perforating. The goal was to improve the initial completion efficiency, translating it into higher profits resulting from earlier product sales. This article presents the concept, mechanics, procedures, potential applications and results of perforating using overpressured well bores. The procedure can also be used in wells with existing perforations if an overpressured surge is used. This article highlights some of the case histories that have used these techniques.

  13. On causality of extreme events

    PubMed Central

    2016-01-01

    Multiple metrics have been developed to detect causality relations between data describing the elements constituting complex systems, all of them considering their evolution through time. Here we propose a metric able to detect causality within static data sets, by analysing how extreme events in one element correspond to the appearance of extreme events in a second one. The metric is able to detect non-linear causalities; to analyse both cross-sectional and longitudinal data sets; and to discriminate between real causalities and correlations caused by confounding factors. We validate the metric through synthetic data, dynamical and chaotic systems, and data representing the human brain activity in a cognitive task. We further show how the proposed metric is able to outperform classical causality metrics, provided non-linear relationships are present and large enough data sets are available. PMID:27330866

  14. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, Glenn D.

    1999-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  15. The 2014 Silba Precipitation Extreme

    NASA Astrophysics Data System (ADS)

    Rasol, Dubravka; Ólafsson, Haraldur

    2015-04-01

    On 30 July 2014 a 24 h precipitation record of 218 mm was set at the island of Silba in the N-Adriatic Sea. The precipitation was of convective nature and significantly less precipitation was recorded only small distances away, at the coast of mainland Croatia. The event is reproduced numerically and discussed in terms of dynamics and predictability. On a large scale, the precipitation extreme was associated with a slow-moving upper tropospheric low that formed over the N-Atlantic several days earlier. At lower levels, there were humid mediterranean airmasses. On a smaller scale, there are indications that the extreme convection may have been triggered by an orographic disturbance.

  16. On causality of extreme events.

    PubMed

    Zanin, Massimiliano

    2016-01-01

    Multiple metrics have been developed to detect causality relations between data describing the elements constituting complex systems, all of them considering their evolution through time. Here we propose a metric able to detect causality within static data sets, by analysing how extreme events in one element correspond to the appearance of extreme events in a second one. The metric is able to detect non-linear causalities; to analyse both cross-sectional and longitudinal data sets; and to discriminate between real causalities and correlations caused by confounding factors. We validate the metric through synthetic data, dynamical and chaotic systems, and data representing the human brain activity in a cognitive task. We further show how the proposed metric is able to outperform classical causality metrics, provided non-linear relationships are present and large enough data sets are available.

  17. Method for extreme ultraviolet lithography

    DOEpatents

    Felter, T. E.; Kubiak, G. D.

    2000-01-01

    A method of producing a patterned array of features, in particular, gate apertures, in the size range 0.4-0.05 .mu.m using projection lithography and extreme ultraviolet (EUV) radiation. A high energy laser beam is used to vaporize a target material in order to produce a plasma which in turn, produces extreme ultraviolet radiation of a characteristic wavelength of about 13 nm for lithographic applications. The radiation is transmitted by a series of reflective mirrors to a mask which bears the pattern to be printed. The demagnified focused mask pattern is, in turn, transmitted by means of appropriate optics and in a single exposure, to a substrate coated with photoresists designed to be transparent to EUV radiation and also satisfy conventional processing methods.

  18. The Extreme Ultraviolet Explorer mission

    NASA Technical Reports Server (NTRS)

    Welsh, Barry Y.

    1991-01-01

    The Extreme Ultraviolet Explorer (EUVE) is a NASA astronomy mission which will operate in the 70-760A spectral band. The science payload consists of three grazing incidence scanning telescopes and an EUV spectrometer/deep survey instrument. An overview of the planned mission profile is given, and the instrumentation which comprises the science payload is discussed. The EUVE is scheduled for launch in late August 1991.

  19. Typologies of Extreme Longevity Myths

    PubMed Central

    Young, Robert D.; Desjardins, Bertrand; McLaughlin, Kirsten; Poulain, Michel; Perls, Thomas T.

    2010-01-01

    Purpose. Political, national, religious, and other motivations have led the media and even scientists to errantly accept extreme longevity claims prima facie. We describe various causes of false claims of extraordinary longevity. Design and Methods. American Social Security Death Index files for the period 1980–2009 were queried for individuals with birth and death dates yielding ages 110+ years of age. Frequency was compared to a list of age-validated supercentenarians maintained by the Gerontology Research Group who died during the same time period. Age claims of 110+ years and the age validation experiences of the authors facilitated a list of typologies of false age claims. Results. Invalid age claim rates increase with age from 65% at age 110-111 to 98% by age 115 to 100% for 120+ years. Eleven typologies of false claims were: Religious Authority Myth, Village Elder Myth, Fountain of Youth Myth (substance), Shangri-La Myth (geographic), Nationalist Pride, Spiritual Practice, Familial Longevity, Individual and/or Family Notoriety, Military Service, Administrative Entry Error, and Pension-Social Entitlement Fraud. Conclusions. Understanding various causes of false extreme age claims is important for placing current, past, and future extreme longevity claims in context and for providing a necessary level of skepticism. PMID:21461047

  20. Geoeffectiveness of Extreme Solar Winds

    NASA Astrophysics Data System (ADS)

    Alleyne, H.; Nanan, B.; Walker, S.; Reme, H.; Lucek, E.; Andre, M.; Cornilleau-Wehrlin, N.; Fazakerley, A.; Decreau, P.; McCrea, I.; Zhang, S.; van Eyken, A.

    2006-12-01

    The geoeffectiveness of the extreme solar winds that flowed pass the Earth on 24 October 2003, 07 November 2004 and 09 November 2004 are presented using Cluster (FGM, CIS, PEACE, STAFF and EFW) and ground- based (EISCAT radars at 69.6N, 19.2E and IMAGE magnetometer network at 68-79N)observations. The Cluster observations suggest that magnetic reconnection need not be the main process for solar wind entry into the magnetosphere during extreme solar winds. The ion velocity in the magnetosheath-cusp region remains strongly anti-sunward and poleward and ion density remains high irrespective of IMF Bz is negative or positive. The ion velocity components are also found to agree with the ExB velocities. The ground-based observations indicate that the extreme solar winds directly affect the high latitude ionosphere. The solar wind plasma is found to enter the ionosphere through an afternoon cusp that descends to low latitudes during negative IMF Bz period when a westward electrojet is also found to ascend to high latitudes.

  1. Societal Impacts of Climate Extremes

    NASA Astrophysics Data System (ADS)

    Cutter, S. L.

    2011-12-01

    Direct economic losses from weather and climate-sensitive perils in the US are on the rise averaging more than $10billion annually during the past 50 years, a very conservative estimate. Starting in the 1990s and continuing today, crop and property losses from climate extremes are escalating, especially those related to hurricanes/ tropical storms and floods. The pattern for hazard-related mortality is less clear. However, as the US lacks a comprehensive inventory or database of natural hazard losses, these figures are rough estimates. This paper examines the temporal and spatial pattern of losses from climate-sensitive hazards for the US over the past fifty years. It illustrates that how and what you measure matters in the loss calculus (dollars or deaths, insured versus uninsured losses, impacts, or costs, or extreme versus non extreme events). The paper also examines the geographic variability in losses and the differential burdens of climate hazard losses on people and places in the U.S. The paper concludes with two questions: How can the nation reduce losses from climate-sensitive hazards when we don't know how much and where such losses occur? Furthermore, how can policy makers and practitioners assess the effectiveness of any hazard or disaster risk reduction policy when we lack the fundamental baseline of losses against which to measure progress?

  2. Technology improves upper extremity rehabilitation.

    PubMed

    Kowalczewski, Jan; Prochazka, Arthur

    2011-01-01

    Stroke survivors with hemiparesis and spinal cord injury (SCI) survivors with tetraplegia find it difficult or impossible to perform many activities of daily life. There is growing evidence that intensive exercise therapy, especially when supplemented with functional electrical stimulation (FES), can improve upper extremity function, but delivering the treatment can be costly, particularly after recipients leave rehabilitation facilities. Recently, there has been a growing level of interest among researchers and healthcare policymakers to deliver upper extremity treatments to people in their homes using in-home teletherapy (IHT). The few studies that have been carried out so far have encountered a variety of logistical and technical problems, not least the difficulty of conducting properly controlled and blinded protocols that satisfy the requirements of high-level evidence-based research. In most cases, the equipment and communications technology were not designed for individuals with upper extremity disability. It is clear that exercise therapy combined with interventions such as FES, supervised over the Internet, will soon be adopted worldwide in one form or another. Therefore it is timely that researchers, clinicians, and healthcare planners interested in assessing IHT be aware of the pros and cons of the new technology and the factors involved in designing appropriate studies of it. It is crucial to understand the technical barriers, the role of telesupervisors, the motor improvements that participants can reasonably expect and the process of optimizing IHT-exercise therapy protocols to maximize the benefits of the emerging technology.

  3. Technology improves upper extremity rehabilitation.

    PubMed

    Kowalczewski, Jan; Prochazka, Arthur

    2011-01-01

    Stroke survivors with hemiparesis and spinal cord injury (SCI) survivors with tetraplegia find it difficult or impossible to perform many activities of daily life. There is growing evidence that intensive exercise therapy, especially when supplemented with functional electrical stimulation (FES), can improve upper extremity function, but delivering the treatment can be costly, particularly after recipients leave rehabilitation facilities. Recently, there has been a growing level of interest among researchers and healthcare policymakers to deliver upper extremity treatments to people in their homes using in-home teletherapy (IHT). The few studies that have been carried out so far have encountered a variety of logistical and technical problems, not least the difficulty of conducting properly controlled and blinded protocols that satisfy the requirements of high-level evidence-based research. In most cases, the equipment and communications technology were not designed for individuals with upper extremity disability. It is clear that exercise therapy combined with interventions such as FES, supervised over the Internet, will soon be adopted worldwide in one form or another. Therefore it is timely that researchers, clinicians, and healthcare planners interested in assessing IHT be aware of the pros and cons of the new technology and the factors involved in designing appropriate studies of it. It is crucial to understand the technical barriers, the role of telesupervisors, the motor improvements that participants can reasonably expect and the process of optimizing IHT-exercise therapy protocols to maximize the benefits of the emerging technology. PMID:21763524

  4. Photostabilizing Efficiency of PVC in the Presence of Schiff Bases as Photostabilizers.

    PubMed

    Yousif, Emad; Al-Amiery, Ahmed A; Kadihum, Abdulhadi; Kadhum, Abdul Amir H; Mohamad, Abu Bakar

    2015-11-04

    The photostabilization of polyvinyl chloride (PVC) films by Schiff bases was investigated. Polyvinyl chloride films containing 0.5 wt % Schiff bases were produced using the same casting method as that used for additive-free PVC films from tetrahydrofuran (THF) solvent. The photostabilization activities of these compounds were determined by monitoring the carbonyl, polyene and hydroxyl indices with irradiation time. The changes in viscosity average molecular weight of PVC with irradiation time were also monitored using THF as a solvent. The quantum yield of chain scission (Φcs) for the studied complexes in PVC was estimated to range between 4.72 and 8.99 × 10(-8). According to the experimental results, several mechanisms were suggested, depending on the structure of the additive. Ultra violet (UV) absorption, peroxide decomposition and radical scavenging were suggested as the photostabilizing mechanisms.

  5. Outcomes for extremely premature infants.

    PubMed

    Glass, Hannah C; Costarino, Andrew T; Stayer, Stephen A; Brett, Claire M; Cladis, Franklyn; Davis, Peter J

    2015-06-01

    Premature birth is a significant cause of infant and child morbidity and mortality. In the United States, the premature birth rate, which had steadily increased during the 1990s and early 2000s, has decreased annually for 7 years and is now approximately 11.39%. Human viability, defined as gestational age at which the chance of survival is 50%, is currently approximately 23 to 24 weeks in developed countries. Infant girls, on average, have better outcomes than infant boys. A relatively uncomplicated course in the intensive care nursery for an extremely premature infant results in a discharge date close to the prenatal estimated date of confinement. Despite technological advances and efforts of child health experts during the last generation, the extremely premature infant (less than 28 weeks gestation) and extremely low birth weight infant (<1000 g) remain at high risk for death and disability with 30% to 50% mortality and, in survivors, at least 20% to 50% risk of morbidity. The introduction of continuous positive airway pressure, mechanical ventilation, and exogenous surfactant increased survival and spurred the development of neonatal intensive care in the 1970s through the early 1990s. Routine administration of antenatal steroids during premature labor improved neonatal mortality and morbidity in the late 1990s. The recognition that chronic postnatal administration of steroids to infants should be avoided may have improved outcomes in the early 2000s. Evidence from recent trials attempting to define the appropriate target for oxygen saturation in preterm infants suggests arterial oxygen saturation between 91% and 95% (compared with 85%-89%) avoids excess mortality; however, final analyses of data from these trials have not been published, so definitive recommendations are still pending. The development of neonatal neurocritical intensive care units may improve neurocognitive outcomes in this high-risk group. Long-term follow-up to detect and address

  6. Extreme weather events and global crop production

    NASA Astrophysics Data System (ADS)

    Ray, D. K.; Gerber, J. S.; West, P. C.

    2014-12-01

    Extreme weather events can lead to significant loss in crop production and even trigger global price spikes. However it is still not clear where exactly and what types of extreme events have resulted in sharp declines in crop production. Neither is it clear how frequently such extreme events have resulted in extreme crop production losses. Using extreme event metrics with a newly developed high resolution and long time series of crop statistics database we identify the frequency and type of extreme event driven crop production losses globally at high resolutions. In this presentation we will present our results as global maps identifying the frequency and type of extreme weather events that resulted in extreme crop production losses and quantify the losses. Understanding how extreme events affects crop production is critical for managing risk in the global food system

  7. Moving in extreme environments: extreme loading; carriage versus distance.

    PubMed

    Lucas, Samuel J E; Helge, Jørn W; Schütz, Uwe H W; Goldman, Ralph F; Cotter, James D

    2016-01-01

    This review addresses human capacity for movement in the context of extreme loading and with it the combined effects of metabolic, biomechanical and gravitational stress on the human body. This topic encompasses extreme duration, as occurs in ultra-endurance competitions (e.g. adventure racing and transcontinental races) and expeditions (e.g. polar crossings), to the more gravitationally limited load carriage (e.g. in the military context). Juxtaposed to these circumstances is the extreme metabolic and mechanical unloading associated with space travel, prolonged bedrest and sedentary lifestyle, which may be at least as problematic, and are therefore included as a reference, e.g. when considering exposure, dangers and (mal)adaptations. As per the other reviews in this series, we describe the nature of the stress and the associated consequences; illustrate relevant regulations, including why and how they are set; present the pros and cons for self versus prescribed acute and chronic exposure; describe humans' (mal)adaptations; and finally suggest future directions for practice and research. In summary, we describe adaptation patterns that are often U or J shaped and that over time minimal or no load carriage decreases the global load carrying capacity and eventually leads to severe adverse effects and manifest disease under minimal absolute but high relative loads. We advocate that further understanding of load carrying capacity and the inherent mechanisms leading to adverse effects may advantageously be studied in this perspective. With improved access to insightful and portable technologies, there are some exciting possibilities to explore these questions in this context. PMID:27110357

  8. Moving in extreme environments: extreme loading; carriage versus distance.

    PubMed

    Lucas, Samuel J E; Helge, Jørn W; Schütz, Uwe H W; Goldman, Ralph F; Cotter, James D

    2016-01-01

    This review addresses human capacity for movement in the context of extreme loading and with it the combined effects of metabolic, biomechanical and gravitational stress on the human body. This topic encompasses extreme duration, as occurs in ultra-endurance competitions (e.g. adventure racing and transcontinental races) and expeditions (e.g. polar crossings), to the more gravitationally limited load carriage (e.g. in the military context). Juxtaposed to these circumstances is the extreme metabolic and mechanical unloading associated with space travel, prolonged bedrest and sedentary lifestyle, which may be at least as problematic, and are therefore included as a reference, e.g. when considering exposure, dangers and (mal)adaptations. As per the other reviews in this series, we describe the nature of the stress and the associated consequences; illustrate relevant regulations, including why and how they are set; present the pros and cons for self versus prescribed acute and chronic exposure; describe humans' (mal)adaptations; and finally suggest future directions for practice and research. In summary, we describe adaptation patterns that are often U or J shaped and that over time minimal or no load carriage decreases the global load carrying capacity and eventually leads to severe adverse effects and manifest disease under minimal absolute but high relative loads. We advocate that further understanding of load carrying capacity and the inherent mechanisms leading to adverse effects may advantageously be studied in this perspective. With improved access to insightful and portable technologies, there are some exciting possibilities to explore these questions in this context.

  9. Extremely Randomized Machine Learning Methods for Compound Activity Prediction.

    PubMed

    Czarnecki, Wojciech M; Podlewska, Sabina; Bojarski, Andrzej J

    2015-11-09

    Speed, a relatively low requirement for computational resources and high effectiveness of the evaluation of the bioactivity of compounds have caused a rapid growth of interest in the application of machine learning methods to virtual screening tasks. However, due to the growth of the amount of data also in cheminformatics and related fields, the aim of research has shifted not only towards the development of algorithms of high predictive power but also towards the simplification of previously existing methods to obtain results more quickly. In the study, we tested two approaches belonging to the group of so-called 'extremely randomized methods'-Extreme Entropy Machine and Extremely Randomized Trees-for their ability to properly identify compounds that have activity towards particular protein targets. These methods were compared with their 'non-extreme' competitors, i.e., Support Vector Machine and Random Forest. The extreme approaches were not only found out to improve the efficiency of the classification of bioactive compounds, but they were also proved to be less computationally complex, requiring fewer steps to perform an optimization procedure.

  10. Communication path for extreme environments

    NASA Technical Reports Server (NTRS)

    Jorgensen, Charles C. (Inventor); Betts, Bradley J. (Inventor)

    2010-01-01

    Methods and systems for using one or more radio frequency identification devices (RFIDs), or other suitable signal transmitters and/or receivers, to provide a sensor information communication path, to provide location and/or spatial orientation information for an emergency service worker (ESW), to provide an ESW escape route, to indicate a direction from an ESW to an ES appliance, to provide updated information on a region or structure that presents an extreme environment (fire, hazardous fluid leak, underwater, nuclear, etc.) in which an ESW works, and to provide accumulated thermal load or thermal breakdown information on one or more locations in the region.

  11. Outcomes for Extremely Premature Infants

    PubMed Central

    Glass, Hannah C.; Costarino, Andrew T.; Stayer, Stephen A.; Brett, Claire; Cladis, Franklyn; Davis, Peter J.

    2015-01-01

    Premature birth is a significant cause of infant and child morbidity and mortality. In the United States, the premature birth rate, which had steadily increased during the 1990s and early 2000s, has decreased annually for four years and is now approximately 11.5%. Human viability, defined as gestational age at which the chance of survival is 50%, is currently approximately 23–24 weeks in developed countries. Infant girls, on average, have better outcomes than infant boys. A relatively uncomplicated course in the intensive care nursery for an extremely premature infant results in a discharge date close to the prenatal EDC. Despite technological advances and efforts of child health experts during the last generation, the extremely premature infant (less than 28 weeks gestation) and extremely low birth weight infant (ELBW) (< 1000 grams) remain at high risk for death and disability with 30–50% mortality and, in survivors, at least 20–50% risk of morbidity. The introduction of CPAP, mechanical ventilation, and exogenous surfactant increased survival and spurred the development of neonatal intensive care in the 1970s through the early 1990s. Routine administration of antenatal steroids during premature labor improved neonatal mortality and morbidity in the late 1990s. The recognition that chronic postnatal administration of steroids to infants should be avoided may have improved outcomes in the early 2000s. Evidence from recent trials attempting to define the appropriate target for oxygen saturation in preterm infants suggests arterial oxygen saturation between 91–95% (compared to 85–89%) avoids excess mortality. However, final analyses of data from these trials have not been published, so definitive recommendations are still pending The development of neonatal neurocognitive care visits may improve neurocognitive outcomes in this high-risk group. Long-term follow up to detect and address developmental, learning, behavioral, and social problems is critical for

  12. Materials Response under extreme conditions

    SciTech Connect

    Remington, B A; Lorenz, K T; Pollaine, S; McNaney, J M

    2005-10-06

    Solid state experiments at extreme pressures, 10-100 GPa (0.1-1 Mbar) and strain rates (10{sup 6}-10{sup 8} s{sup -1}) are being developed on high-energy laser facilities. The goal is an experimental capability to test constitutive models for high-pressure, solid-state strength for a variety of materials. Relevant constitutive models are discussed, and our progress in developing a quasi-isentropic, ramped-pressure, shockless drive is given. Designs to test the constitutive models with experiments measuring perturbation growth due to the Rayleigh-Taylor instability in solid-state samples are presented.

  13. Gravity and Extreme Magnetism SMEX

    NASA Technical Reports Server (NTRS)

    2012-01-01

    The Gravity and Extreme Magnetism SMEX mission will be the first mission to catalogue the X-ray polarisation of many astrophysical objects including black-holes and pulsars. This first of its kind mission is enabled by the novel use of a time projection chamber as an X-ray polarimeter. The detector has been developed over the last 5 years, with the current effort charged toward a demonstration of it's technical readiness to be at level 6 prior to the preliminary design review. This talk will describe the design GEMS polarimeter and the results to date from the engineering test unit.

  14. Extreme Geomagnetic Storms - 1868 - 2010

    NASA Astrophysics Data System (ADS)

    Vennerstrom, S.; Lefevre, L.; Dumbović, M.; Crosby, N.; Malandraki, O.; Patsou, I.; Clette, F.; Veronig, A.; Vršnak, B.; Leer, K.; Moretto, T.

    2016-05-01

    We present the first large statistical study of extreme geomagnetic storms based on historical data from the time period 1868 - 2010. This article is the first of two companion papers. Here we describe how the storms were selected and focus on their near-Earth characteristics. The second article presents our investigation of the corresponding solar events and their characteristics. The storms were selected based on their intensity in the aa index, which constitutes the longest existing continuous series of geomagnetic activity. They are analyzed statistically in the context of more well-known geomagnetic indices, such as the Kp and Dcx/Dst index. This reveals that neither Kp nor Dcx/Dst provide a comprehensive geomagnetic measure of the extreme storms. We rank the storms by including long series of single magnetic observatory data. The top storms on the rank list are the New York Railroad storm occurring in May 1921 and the Quebec storm from March 1989. We identify key characteristics of the storms by combining several different available data sources, lists of storm sudden commencements (SSCs) signifying occurrence of interplanetary shocks, solar wind in-situ measurements, neutron monitor data, and associated identifications of Forbush decreases as well as satellite measurements of energetic proton fluxes in the near-Earth space environment. From this we find, among other results, that the extreme storms are very strongly correlated with the occurrence of interplanetary shocks (91 - 100 %), Forbush decreases (100 %), and energetic solar proton events (70 %). A quantitative comparison of these associations relative to less intense storms is also presented. Most notably, we find that most often the extreme storms are characterized by a complexity that is associated with multiple, often interacting, solar wind disturbances and that they frequently occur when the geomagnetic activity is already elevated. We also investigate the semiannual variation in storm occurrence

  15. Physical examination of upper extremity compressive neuropathies.

    PubMed

    Popinchalk, Samuel P; Schaffer, Alyssa A

    2012-10-01

    A thorough history and physical examination are vital to the assessment of upper extremity compressive neuropathies. This article summarizes relevant anatomy and physical examination findings associated with upper extremity compressive neuropathies.

  16. Will extreme climatic events facilitate biological invasions?

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Extreme climatic events, such as intense heat waves, hurricanes, floods and droughts, can dramatically affect ecological and evolutionary processes, and more extreme events are projected with ongoing climate change. However, the implications of these events for biological invasions, which themselves...

  17. Mitochondrial function at extreme high altitude.

    PubMed

    Murray, Andrew J; Horscroft, James A

    2016-03-01

    At high altitude, barometric pressure falls and with it inspired P(O2), potentially compromising O2 delivery to the tissues. With sufficient acclimatisation, the erythropoietic response increases red cell mass such that arterial O2 content (C(aO2)) is restored; however arterial P(O2)(P(aO2)) remains low, and the diffusion of O2 from capillary to mitochondrion is impaired. Mitochondrial respiration and aerobic capacity are thus limited, whilst reactive oxygen species (ROS) production increases. Restoration of P(aO2) with supplementary O2 does not fully restore aerobic capacity in acclimatised individuals, possibly indicating a peripheral impairment. With prolonged exposure to extreme high altitude (>5500 m), muscle mitochondrial volume density falls, with a particular loss of the subsarcolemmal population. It is not clear whether this represents acclimatisation or deterioration, but it does appear to be regulated, with levels of the mitochondrial biogenesis factor PGC-1α falling, and shows similarities to adapted Tibetan highlanders. Qualitative changes in mitochondrial function also occur, and do so at more moderate high altitudes with shorter periods of exposure. Electron transport chain complexes are downregulated, possibly mitigating the increase in ROS production. Fatty acid oxidation capacity is decreased and there may be improvements in biochemical coupling at the mitochondrial inner membrane that enhance O2 efficiency. Creatine kinase expression falls, possibly impairing high-energy phosphate transfer from the mitochondria to myofibrils. In climbers returning from the summit of Everest, cardiac energetic reserve (phosphocreatine/ATP) falls, but skeletal muscle energetics are well preserved, possibly supporting the notion that mitochondrial remodelling is a core feature of acclimatisation to extreme high altitude. PMID:26033622

  18. Dome cities for extreme environments

    NASA Technical Reports Server (NTRS)

    Leonard, Raymond S.; Schwartz, Milton

    1992-01-01

    Extreme environments whether they be the frigid nights of the polar regions, the burning sands of the desert, or the harsh environment of space pose interesting challenges to the architect, the engineer, and the constructor in their efforts to create habitats for mankind. In space, the goals are to provide radiation protection while also providing an aesthetic living environment for long duration missions. Because of the need to provide both radiation protection and options for expansion of base facilities, a unique structural system which separates the radiation protection systems from the pressure envelope of the habitats was created. The system uses cable networks in a tensioned structural system, which supports the lunar regolith used for shielding above the facilities. The system is modular, easily expandable, and simple to construct. Additional innovations include the use of rock melting perpetrators for piles and anchoring deadmen, and various sized craters to provide side shielding. The reflective properties of the fabric used in the membrane are utilized to provide diffuse illumination. The use of craters along with the suspended shielding allows the dome to be utilized in fashions similar to those proposed by various designers unaware of the Moon's hostile radiation environment. Additional topics addressed deal with construction techniques for large domes, i.e., on the order of 100's to 1000's of meters, thermal control, the integration of tertiary water treatment schemes with architectural design, human factors, and its implications for the design of habitats for long term use in extreme environments.

  19. Compact pulsed laser having improved heat conductance

    NASA Technical Reports Server (NTRS)

    Yang, L. C. (Inventor)

    1977-01-01

    A highly efficient, compact pulsed laser having high energy to weight and volume ratios is provided. The laser utilizes a cavity reflector that operates as a heat sink and is essentially characterized by having a high heat conductivity, by being a good electrical insulator and by being substantially immune to the deleterious effects of ultra-violet radiation. Manual portability is accomplished by eliminating entirely any need for a conventional circulating fluid cooling system.

  20. Extreme Event impacts on Seafloor Ecosystems

    NASA Astrophysics Data System (ADS)

    Canals, Miquel; Sanchez-Vidal, Anna; Calafat, Antoni; Pedrosa-Pàmies, Rut; Lastras, Galderic

    2013-04-01

    a major DSWC event, the latest to date. Data show that DSWC modifies the properties of intermediate and deep waters, carries massive amounts of organic carbon to the basin thus fuelling the deep ecosystem, transports huge quantities of coarse and fine sedimentary particles that abrade canyon floors and rise the load of suspended particles, and also exports pollutants from the coastal area to deeper compartment. Our findings demonstrate that both types of climate-driven extreme events (coastal storms and DSWC) are highly efficient in transporting organic carbon from shallow to deep, thus contributing to its sequestration, and have the potential to tremendously impact the deep-sea ecosystems.

  1. Biology of Extreme Radiation Resistance: The Way of Deinococcus radiodurans

    PubMed Central

    Krisko, Anita; Radman, Miroslav

    2013-01-01

    The bacterium Deinococcus radiodurans is a champion of extreme radiation resistance that is accounted for by a highly efficient protection against proteome, but not genome, damage. A well-protected functional proteome ensures cell recovery from extensive radiation damage to other cellular constituents by molecular repair and turnover processes, including an efficient repair of disintegrated DNA. Therefore, cell death correlates with radiation-induced protein damage, rather than DNA damage, in both robust and standard species. From the reviewed biology of resistance to radiation and other sources of oxidative damage, we conclude that the impact of protein damage on the maintenance of life has been largely underestimated in biology and medicine. PMID:23818498

  2. Strain induced piezoelectric effect in black phosphorus and MoS2 van der Waals heterostructure

    PubMed Central

    Huang, Le; Li, Yan; Wei, Zhongming; Li, Jingbo

    2015-01-01

    The structural, electronic, transport and optical properties of black phosphorus/MoS2 (BP/MoS2) van der Waals (vdw) heterostructure are investigated by using first principles calculations. The band gap of BP/MoS2 bilayer decreases with the applied normal compressive strain and a semiconductor-to-metal transition is observed when the applied strain is more than 0.85 Å. BP/MoS2 bilayer also exhibits modulation of its carrier effective mass and carrier concentration by the applied compressive strain, suggesting that mobility engineering and good piezoelectric effect can be realized in BP/MoS2 heterostructure. Because the type-II band alignment can facilitate the separation of photo-excited electrons and holes, and it can benefit from the great absorption coefficient in ultra-violet region, the BP/MoS2 shows great potential to be a very efficient ultra-violet photodetector. PMID:26553370

  3. Strain induced piezoelectric effect in black phosphorus and MoS2 van der Waals heterostructure.

    PubMed

    Huang, Le; Li, Yan; Wei, Zhongming; Li, Jingbo

    2015-01-01

    The structural, electronic, transport and optical properties of black phosphorus/MoS2 (BP/MoS2) van der Waals (vdw) heterostructure are investigated by using first principles calculations. The band gap of BP/MoS2 bilayer decreases with the applied normal compressive strain and a semiconductor-to-metal transition is observed when the applied strain is more than 0.85 Å. BP/MoS2 bilayer also exhibits modulation of its carrier effective mass and carrier concentration by the applied compressive strain, suggesting that mobility engineering and good piezoelectric effect can be realized in BP/MoS2 heterostructure. Because the type-II band alignment can facilitate the separation of photo-excited electrons and holes, and it can benefit from the great absorption coefficient in ultra-violet region, the BP/MoS2 shows great potential to be a very efficient ultra-violet photodetector. PMID:26553370

  4. [Travelers exposed to extreme temperatures].

    PubMed

    Savourey, G; Bittel, J

    1997-01-01

    Sudden introduction of the unadapted human into extreme environments can result in serious, sometimes fatal, reactions. Most complications are due either to failure of thermoregulatory system or consecutive to the physiological responses to those environmental conditions. In addition to a number of minor diseases, cold can cause two major accidents, i.e., hypothermia and frostbite which can be enhanced at altitude. Moreover, the main disease in altitude conditions is represented by the acute mountain sickness which can lead to acute pulmonary and cerebral edema. Heat can cause heatstroke, dehydration, syncope, and other minor disorders. Prevention of these manifestations during stays in inhospitable climatic conditions for which the body is not suited requires knowledge of the environment and its dangers. Implementation of suitable measures can greatly reduces the incidence of adverse effects. PMID:9612745

  5. Zipf law: an extreme perspective

    NASA Astrophysics Data System (ADS)

    Eliazar, Iddo

    2016-04-01

    Extreme value theory (EVT) asserts that the Fréchet law emerges universally from linearly scaled maxima of collections of independent and identically distributed random variables that are positive-valued. Observations of many real-world sizes, e.g. city-sizes, give rise to the Zipf law: if we rank the sizes decreasingly, and plot the log-sizes versus the log-ranks, then an affine line emerges. In this paper we present an EVT approach to the Zipf law. Specifically, we establish that whenever the Fréchet law emerges from the EVT setting, then the Zipf law follows. The EVT generation of the Zipf law, its universality, and its associated phase transition, are analyzed and described in detail.

  6. Extreme solar energetic particle events

    NASA Astrophysics Data System (ADS)

    Vainio, Rami; Afanasiev, Alexandr; Battarbee, Markus

    2016-04-01

    Properties of extreme solar energetic particle (SEP) events, here defined as those leading to ground level enhancements (GLEs) of cosmic rays, are reviewed. We review recent efforts on modeling SEP acceleration to relativistic energies and present simulation results on particle acceleration at shocks driven by fast coronal mass ejections (CMEs) in different types of coronal magnetic structures and turbulent downstream compression regions. Based on these modeling results, we discuss the possible role of solar and CME parameters in the lack of GLEs during the present sunspot cycle. This work has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 637324 (HESPERIA). The Academy of Finland is thanked for financial support.

  7. Extreme ultraviolet Talbot interference lithography.

    PubMed

    Li, Wei; Marconi, Mario C

    2015-10-01

    Periodic nanopatterns can be generated using lithography based on the Talbot effect or optical interference. However, these techniques have restrictions that limit their performance. High resolution Talbot lithography is limited by the very small depth of focus and the demanding requirements in the fabrication of the master mask. Interference lithography, with large DOF and high resolution, is limited to simple periodic patterns. This paper describes a hybrid extreme ultraviolet lithography approach that combines Talbot lithography and interference lithography to render an interference pattern with a lattice determined by a Talbot image. As a result, the method enables filling the arbitrary shaped cells produced by the Talbot image with interference patterns. Detailed modeling, system design and experimental results using a tabletop EUV laser are presented. PMID:26480070

  8. Causes of Extremely Fast CMEs

    NASA Technical Reports Server (NTRS)

    Feynman, Joan; Ruzmaikin, Alexander

    2006-01-01

    We study CMEs observed by LASCO to have plane of the sky velocities exceeding 1500 km/sec. We find that these extremely fast CMEs are typically associated with flares accompanied by erupting prominences. Our results are consistent with a single CME initiation process that consists of three stages. The initial stage is brought about by the emergence of new magnetic flux, which interacts with the pre-existing magnetic configuration and results in a slow rise of the magnetic structure. The second stage is a fast reconnection phase with flaring, filament eruption and a sudden increase of the rise velocity of the magnetic structure (CME). The third stage consists of propagation in the corona. We discuss the sources of these CMEs and the need for improved understanding of the first and third stages.

  9. Weather extremes could affect agriculture

    NASA Astrophysics Data System (ADS)

    Balcerak, Ernie

    2012-05-01

    As Earth's climate warms, agricultural producers will need to adapt. Changes, especially increases in extreme events, are already having an impact on food production, according to speakers at a 1 May session on agriculture and food security at the AGU Science Policy Conference. Christopher Field, director of the Department of Global Ecology at the Carnegie Institution for Science of Washington, D. C., pointed out the complex factors that come into play in understanding food security, including spatially varying controls and stresses, incomplete models, and the potential for threshold responses. Factors that are likely to cause problems include increasing population; increasing preference for meat, which needs more land and energy inputs to produce; climate change; and increasing use of agricultural lands for biomass energy.

  10. Granular gases under extreme driving

    NASA Astrophysics Data System (ADS)

    Kang, W.; Machta, J.; Ben-Naim, E.

    2010-08-01

    We study inelastic gases in two dimensions using event-driven molecular-dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high-energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

  11. Carbon tetrachloride under extreme conditions

    SciTech Connect

    Pravica, Michael Sneed, Daniel; Wang, Yonggang; Smith, Quinlan; Subrahmanyam, Garimella

    2014-05-21

    We report on three experiments on carbon tetrachloride subjected to extreme conditions. In the first experiment, Raman spectra of CCl{sub 4} were acquired up to 28 GPa. Evidence was observed for at least two new phases of CCl{sub 4} above 14 GPa (phase VI) and above 22 GPa (phase VII). Decompression of the sample showed no evidence of pressure-induced decomposition. In the second experiment, a synchrotron x-ray diffraction study was performed up to 30 GPa verifying phase V and potential phases above 14 (VI) and 22 GPa (VII), respectively. In the third study, we examined irradiated CCl{sub 4} using synchrotron infrared spectroscopy to reduce fluorescent contamination. Some sort of carbon allotrope appears as a byproduct suggesting the following reaction with hard x-rays: CCl{sub 4}+ hν → C + 2Cl{sub 2}.

  12. Gut Microbiota and Extreme Longevity.

    PubMed

    Biagi, Elena; Franceschi, Claudio; Rampelli, Simone; Severgnini, Marco; Ostan, Rita; Turroni, Silvia; Consolandi, Clarissa; Quercia, Sara; Scurti, Maria; Monti, Daniela; Capri, Miriam; Brigidi, Patrizia; Candela, Marco

    2016-06-01

    The study of the extreme limits of human lifespan may allow a better understanding of how human beings can escape, delay, or survive the most frequent age-related causes of morbidity, a peculiarity shown by long-living individuals. Longevity is a complex trait in which genetics, environment, and stochasticity concur to determine the chance to reach 100 or more years of age [1]. Because of its impact on human metabolism and immunology, the gut microbiome has been proposed as a possible determinant of healthy aging [2, 3]. Indeed, the preservation of host-microbes homeostasis can counteract inflammaging [4], intestinal permeability [5], and decline in bone and cognitive health [6, 7]. Aiming at deepening our knowledge on the relationship between the gut microbiota and a long-living host, we provide for the first time the phylogenetic microbiota analysis of semi-supercentenarians, i.e., 105-109 years old, in comparison to adults, elderly, and centenarians, thus reconstructing the longest available human microbiota trajectory along aging. We highlighted the presence of a core microbiota of highly occurring, symbiotic bacterial taxa (mostly belonging to the dominant Ruminococcaceae, Lachnospiraceae, and Bacteroidaceae families), with a cumulative abundance decreasing along with age. Aging is characterized by an increasing abundance of subdominant species, as well as a rearrangement in their co-occurrence network. These features are maintained in longevity and extreme longevity, but peculiarities emerged, especially in semi-supercentenarians, describing changes that, even accommodating opportunistic and allochthonous bacteria, might possibly support health maintenance during aging, such as an enrichment and/or higher prevalence of health-associated groups (e.g., Akkermansia, Bifidobacterium, and Christensenellaceae). PMID:27185560

  13. Undulator radiation driven by laser-wakefield accelerator electron beams

    NASA Astrophysics Data System (ADS)

    Wiggins, S. M.; Anania, M. P.; Welsh, G. H.; Brunetti, E.; Cipiccia, S.; Grant, P. A.; Reboredo, D.; Manahan, G.; Grant, D. W.; Jaroszynski, D. A.

    2015-05-01

    The Advanced Laser-Plasma High-Energy Accelerators towards X-rays (ALPHA-X) programme is developing laserplasma accelerators for the production of ultra-short electron bunches with subsequent generation of coherent, bright, short-wavelength radiation pulses. The new Scottish Centre for the Application of Plasma-based Accelerators (SCAPA) will develop a wide range of applications utilising such light sources. Electron bunches can be propagated through a magnetic undulator with the aim of generating fully coherent free-electron laser (FEL) radiation in the ultra-violet and Xrays spectral ranges. Demonstration experiments producing spontaneous undulator radiation have been conducted at visible and extreme ultra-violet wavelengths but it is an on-going challenge to generate and maintain electron bunches of sufficient quality in order to stimulate FEL behaviour. In the ALPHA-X beam line experiments, a Ti:sapphire femtosecond laser system with peak power 20 TW has been used to generate electron bunches of energy 80-150 MeV in a 2 mm gas jet laser-plasma wakefield accelerator and these bunches have been transported through a 100 period planar undulator. High peak brilliance, narrow band spontaneous radiation pulses in the vacuum ultra-violet wavelength range have been generated. Analysis is provided with respect to the magnetic quadrupole beam transport system and subsequent effect on beam emittance and duration. Requirements for coherent spontaneous emission and FEL operation are presented.

  14. Electronic Components for use in Extreme Temperature Aerospace Applications

    NASA Technical Reports Server (NTRS)

    Patterson, Richard L.; Hammoud, Ahmad; Elbuluk, Malik

    2008-01-01

    Electrical power management and control systems designed for use in planetary exploration missions and deep space probes require electronics that are capable of efficient and reliable operation under extreme temperature conditions. Space-based infra-red satellites, all-electric ships, jet engines, electromagnetic launchers, magnetic levitation transport systems, and power facilities are also typical examples where the electronics are expected to be exposed to harsh temperatures and to operate under severe thermal swings. Most commercial-off-the-shelf (COTS) devices are not designed to function under such extreme conditions and, therefore, new parts must be developed or the conventional devices need to be modified. For example, spacecraft operating in the cold environment of deep space carry a large number of radioisotope heating units in order to maintain the surrounding temperature of the on-board electronics at approximately 20 C. At the other end, built-in radiators and coolers render the operation of electronics possible under hot conditions. These thermal measures lead to design complexity, affect development costs, and increase size and weight. Electronics capable of operation at extreme temperatures, thus, will not only tolerate the hostile operational environment, but also make the overall system efficient, more reliable, and less expensive. The Extreme Temperature Electronics Program at the NASA Glenn Research Center focuses on research and development of electronics suitable for applications in the aerospace environment and deep space exploration missions. Research is being conducted on devices, including COTS parts, for potential use under extreme temperatures. These components include semiconductor switching devices, passive devices, DC/DC converters, operational amplifiers, and oscillators. An overview of the program will be presented along with some experimental findings.

  15. Sparse extreme learning machine for classification.

    PubMed

    Bai, Zuo; Huang, Guang-Bin; Wang, Danwei; Wang, Han; Westover, M Brandon

    2014-10-01

    Extreme learning machine (ELM) was initially proposed for single-hidden-layer feedforward neural networks (SLFNs). In the hidden layer (feature mapping), nodes are randomly generated independently of training data. Furthermore, a unified ELM was proposed, providing a single framework to simplify and unify different learning methods, such as SLFNs, least square support vector machines, proximal support vector machines, and so on. However, the solution of unified ELM is dense, and thus, usually plenty of storage space and testing time are required for large-scale applications. In this paper, a sparse ELM is proposed as an alternative solution for classification, reducing storage space and testing time. In addition, unified ELM obtains the solution by matrix inversion, whose computational complexity is between quadratic and cubic with respect to the training size. It still requires plenty of training time for large-scale problems, even though it is much faster than many other traditional methods. In this paper, an efficient training algorithm is specifically developed for sparse ELM. The quadratic programming problem involved in sparse ELM is divided into a series of smallest possible sub-problems, each of which are solved analytically. Compared with SVM, sparse ELM obtains better generalization performance with much faster training speed. Compared with unified ELM, sparse ELM achieves similar generalization performance for binary classification applications, and when dealing with large-scale binary classification problems, sparse ELM realizes even faster training speed than unified ELM. PMID:25222727

  16. Trends in extreme learning machines: a review.

    PubMed

    Huang, Gao; Huang, Guang-Bin; Song, Shiji; You, Keyou

    2015-01-01

    Extreme learning machine (ELM) has gained increasing interest from various research fields recently. In this review, we aim to report the current state of the theoretical research and practical advances on this subject. We first give an overview of ELM from the theoretical perspective, including the interpolation theory, universal approximation capability, and generalization ability. Then we focus on the various improvements made to ELM which further improve its stability, sparsity and accuracy under general or specific conditions. Apart from classification and regression, ELM has recently been extended for clustering, feature selection, representational learning and many other learning tasks. These newly emerging algorithms greatly expand the applications of ELM. From implementation aspect, hardware implementation and parallel computation techniques have substantially sped up the training of ELM, making it feasible for big data processing and real-time reasoning. Due to its remarkable efficiency, simplicity, and impressive generalization performance, ELM have been applied in a variety of domains, such as biomedical engineering, computer vision, system identification, and control and robotics. In this review, we try to provide a comprehensive view of these advances in ELM together with its future perspectives. PMID:25462632

  17. Remembrance of ecohydrologic extremes past

    NASA Astrophysics Data System (ADS)

    Band, L. E.; Hwang, T.

    2013-12-01

    Ecohydrological systems operate at time scales that span several orders of magnitude. Significant processes and feedbacks range from subdaily physiologic response to meteorological drivers, to soil forming and geomorphic processes ranging up through 10^3-10^4 years. While much attention in ecohydrology has focused on ecosystem optimization paradigms, these systems can show significant transience in structure and function, with apparent memory of hydroclimate extremes and regime shifts. While optimization feedbacks can be reconciled with system transience, a better understanding of the time scales and mechanisms of adjustment to increased hydroclimate variability and to specific events is required to understand and predict dynamics and vulnerability of ecosystems. Under certain circumstances of slowly varying hydroclimate, we hypothesize that ecosystems can remain adjusted to changing climate regimes, without displaying apparent system memory. Alternatively, rapid changes in hydroclimate and increased hydroclimate variability, amplified with well expressed non-linearity in the processes controlling feedbacks between water, carbon and nutrients, can move ecosystems far from adjusted states. The Coweeta Hydrological Laboratory is typical of humid, broadleaf forests in eastern North America, with a range of forest biomes from northern hardwoods at higher elevations, to oak-pine assemblages at lower elevations. The site provides almost 80 years of rainfall-runoff records for a set of watersheds under different management, along with multi-decadal forest plot structural information, soil moisture conditions and stream chemistry. An initial period of multi-decadal cooling, was followed by three decades of warming and increased hydroclimate variability. While mean temperature has risen over this time period, precipitation shows no long term trends in the mean, but has had a significant rise in variability with repeated extreme drought and wet periods. Over this latter

  18. Polyimide Resins Resist Extreme Temperatures

    NASA Technical Reports Server (NTRS)

    2009-01-01

    Spacecraft and aerospace engines share a common threat: high temperature. The temperatures experienced during atmospheric reentry can reach over 2,000 F, and the temperatures in rocket engines can reach well over 5,000 F. To combat the high temperatures in aerospace applications, Dr. Ruth Pater of Langley Research Center developed RP-46, a polyimide resin capable of withstanding the most brutal temperatures. The composite material can push the service temperature to the limits of organic materials. Designed as an environmentally friendly alternative to other high-temperature resins, the RP-46 polyimide resin system was awarded a 1992 "R&D 100" award, named a "2001 NASA Technology of the Year," and later, due to its success as a spinoff technology, "2004 NASA Commercial Invention of the Year." The technology s commercial success also led to its winning the Langley s "Paul F. Holloway Technology Transfer Award" as well as "Richard T. Whitcom Aerospace Technology Transfer Award" both for 2004. RP-46 is relatively inexpensive and it can be readily processed for use as an adhesive, composite, resin molding, coating, foam, or film. Its composite materials can be used in temperatures ranging from minus 150 F to 2,300 F. No other organic materials are known to be capable of such wide range and extreme high-temperature applications. In addition to answering the call for environmentally conscious high-temperature materials, RP-46 provides a slew of additional advantages: It is extremely lightweight (less than half the weight of aluminum), chemical and moisture resistant, strong, and flexible. Pater also developed a similar technology, RP-50, using many of the same methods she used with RP-46, and very similar in composition to RP-46 in terms of its thermal capacity and chemical construction, but it has different applications, as this material is a coating as opposed to a buildable composite. A NASA license for use of this material outside of the Space Agency as well as

  19. Extreme rainfall in West Africa: A regional modeling

    NASA Astrophysics Data System (ADS)

    Panthou, G.; Vischel, T.; Lebel, T.; Blanchet, J.; Quantin, G.; Ali, A.

    2012-08-01

    In a world of increasing exposure of populations to natural hazards, the mapping of extreme rainfall remains a key subject of study. Such maps are required for both flood risk management and civil engineering structure design, the challenge being to take into account the local information provided by point rainfall series as well as the necessity of some regional coherency. Two approaches based on the extreme value theory are compared here, with an application to extreme rainfall mapping in West Africa. The first approach is a local fit and interpolation (LFI) consisting of a spatial interpolation of the generalized extreme value (GEV) distribution parameters estimated independently at each station. The second approach is a spatial maximum likelihood estimation (SMLE); it directly estimates the GEV distribution over the entire region by a single maximum likelihood fit using jointly all measurements combined with spatial covariates. Five LFI and three SMLE methods are considered, using the information provided by 126 daily rainfall series covering the period 1950-1990. The methods are first evaluated in calibration. Then the predictive skills and the robustness are assessed through a cross validation and an independent network validation process. The SMLE approach, especially when using the mean annual rainfall as covariate, appears to perform better for most of the scores computed. Using the Niamey 104 year time series, it is also shown that the SMLE approach has the capacity to deal more efficiently with the effect of local outliers by using the spatial information provided by nearby stations.

  20. Extremely Large Cusp Diamagnetic Cavities

    NASA Astrophysics Data System (ADS)

    Chen, J.; Fritz, T. A.

    2002-05-01

    Extremely large diamagnetic cavities with a size of as large as 6 Re have been observed in the dayside high-altitude cusp regions. Some of the diamagnetic cavities were independent of the IMF directions, which is unexpected by the current MHD (or ISM) models, suggesting that the cusp diamagnetic cavities are different from the magnetospheric sash, which provides a challenge to the existing MHD (or ISM) models. Associated with these cavities are ions with energies from 40 keV up to 8 MeV. The charge state distribution of these cusp cavity ions was indicative of their seed populations being a mixture of the ionospheric and the solar wind particles. The intensities of the cusp cavity energetic ions were observed to increase by as large as four orders of the magnitudes. During high solar wind pressure period on April 21, 1999, the POLAR spacecraft observed lower ion flux in the dayside high-latitude magnetosheath than that in the neighbouring cusp cavities. These observations indicate that the dayside high-altitude cusp diamagnetic cavity is a key region for transferring the solar wind energy, mass, and momentum into the Earth's magnetosphere. These energetic particles in the cusp diamagnetic cavity together with the cusp's connectivity have significant global impacts on the geospace environment research and will be shedding light on the long-standing unsolved fundamental issue about the origins of the energetic particles in the ring current and in upstream ion events.

  1. Extremely large cusp diamagnetic cavities

    NASA Astrophysics Data System (ADS)

    Chen, J.; Fritz, T.; Siscoe, G.

    Extremely large diamagnetic cavities with a size of as large as 6 Re have been observed in the dayside high-altitude cusp regions. These diamagnetic cavities are always there day by day. Some of the diamagnetic cavities have been observed in the morningside during intervals when the IMF By component was positive (duskward), suggesting that the cusp diamagnetic cavities are different from the magnetospheric sash predicted by MHD simulations. Associated with these cavities are ions with energies from 40 keV up to 8 MeV. The charge state distribution of these cusp cavity ions was indicative of their seed populations being a mixture of the ionospheric and the solar wind particles. The intensities of the cusp cavity energetic ions were observed to increase by as large as four orders of the magnitudes. These observations indicate that the dayside high-altitude cusp diamagnetic cavity is a key region for transferring the solar wind energy, mass, and momentum into the Earth's magnetosphere. These energetic particles in the cusp diamagnetic cavity together with the cusp's connectivity to the entire magnetopause may have significant global impacts on the geospace environment. They will possibly be shedding light on the long-standing unsolved fundamental issue about the origins of the energetic particles in the ring current and in the regions upstream of the subsolar magnetopause where energetic ion events frequently are observed.

  2. The Diffuse Extreme Ultraviolet Background

    NASA Technical Reports Server (NTRS)

    Vallerga, John; Slavin, Jonathan

    1996-01-01

    Observations of the diffuse EUV background towards 138 different directions using the spectrometers aboard the Extreme Ultraviolet Explorer satellite (EUVE) have been combined into a spectrum from 150A to 730A and represent an effective exposure of 18 million seconds. There is no significant evidence of any non-local line flux in the resultant spectrum such as that from a hot coronal plasma. These results are inconsistent with the Wisconsin C and B broad-band surveys assuming the source is a logT = 5.8 - 6.1 hot plasma in ionization equilibrium with solar abundances, confirming the previous result of Jelinksy, Vallerga and Edelstein) (hereafter Paper 1) using an observation along the ecliptic with the same instrument. To make these results consistent with the previous broad-band surveys, the plasma responsible for the emission must either be depleted in Fe by a factor of approximately 6, be behind an absorbing slab of neutral H with a column of 2 x 10(exp 19)/sq cm, or not be in collisional ionization equilibrium (CIE). One such non-CIE model (Breitswerdt and Schmutzier) that explains the soft x-ray results is also inconsistent with this EUV data.

  3. Extreme Mechanics of Growing Matter

    NASA Astrophysics Data System (ADS)

    Kuhl, Ellen

    2013-03-01

    Growth is a distinguishing feature of all living things. Unlike standard materials, living matter can autonomously respond to alterations in its environment. As a result of a continuous ultrastructural turnover and renewal of cells and extracellular matrix, living matter can undergo extreme changes in composition, size, and shape within the order of months, weeks, or days. While hard matter typically adapts by increasing its density to grow strong, soft matter adapts by increasing its volume to grow large. Here we provide a state-of-the-art review of growing matter, and compare existing mathematical models for growth and remodeling of living systems. Applications are plentiful ranging from plant growth to tumor growth, from asthma in the lungs to restenosis in the vasculature, from plastic to reconstructive surgery, and from skeletal muscle adaptation to heart failure. Using these examples, we discuss current challenges and potential future directions. We hope to initiate critical discussions around the biophysical modeling of growing matter as a powerful tool to better understand biological systems in health and disease. This research has been supported by the NSF CAREER award CMMI 0952021.

  4. The Extreme Case of Magnetars

    NASA Technical Reports Server (NTRS)

    Kouveliotou, Chryssa

    2011-01-01

    Magnetars are magnetically powered rotating neutron stars with extreme magnetic fields (over 10(exp 14) Gauss). They were discovered in the X- and gamma-rays where they predominantly emit their radiation. Very few sources (roughly 18) have been found since their discovery in 1987. NASA's Fermi Gamma-ray Space Telescope was launched June 11, 2009; since then the Fermi Gamma-ray Burst Monitor (GBM) recorded emission from four magnetar sources. Two of these were brand new sources, SGR J0501+4516, discovered with Swift and extensively monitored with Swift and GBM, SGR J0418+5729, discovered with GBM and the Interplanetary Network (IPN). A third was SGR J1550-5418, a source originally classified as an Anomalous X-ray Pulsar (AXP 1E1547.0-5408), but exhibiting a very prolific outburst with over 400 events recorded in January 2009. In my talk I will give a short history of magnetars and describe how this, once relatively esoteric field, has emerged as a link between several astrophysical areas including Gamma-Ray Bursts. Finally, I will describe the exciting new results of Fermi in this field and the current status of our knowledge of the magnetar population properties and magnetic fields.

  5. Extreme events in Uttarakhand, India

    NASA Astrophysics Data System (ADS)

    Dimri, V. P.

    2013-12-01

    Uttarakhand in NW Himalaya, India is prone to various disasters, which include earthquakes, cloud bursts, landslides, floods etc. These disasters have a cascading effect. The cloud burst results in flooding of rivers and landslides. The earthquakes shake the ground causing landslides, which sometimes block the natural path of river making artificial dams. These artificial dams can cause river flooding. The situation becomes more devastating, if heavy rainfall occurs. Such disasters are increasing in recent times. There could be several reasons for the rise in frequency of these disasters because of global and local environment changes. The global changes such as rise of global temperatures due to increase in CO2 concentration in the atmosphere can be responsible for melting of Himalayan Glaciers and changes in precipitation/ rainfall patterns etc. Anthropogenic causes such as deforestation, establishment of new townships, new hydro-power projects, mining activities etc are also making the condition more vulnerable by changing the course of river channels. A case study of such extreme event is presented. The region is affected by changes of both global and local origin, tectonically as well as climatologically.

  6. Lightcurves of Extreme Debris Disks

    NASA Astrophysics Data System (ADS)

    Rieke, George; Meng, Huan; Su, Kate

    2012-12-01

    We have recently discovered that some planetary debris disks with extreme fractional luminosities are variable on the timescale of a few years. This behavior opens a new possibility to understand planet building. Two of the known variable disks are around solar-like stars in the age range of 30 to 100+ Myr, which is the expected era of the final stages of terrestrial planet building. Such variability can be attributed to violent collisions (up to ones on the scale of the Moon-forming event between the proto-Earth and another proto-planet). The collisional cascades that are the aftermaths of these events can produce large clouds of tiny dust grains, possibly even condensed from silica vapor. A Spitzer pilot program has obtained the lightcurve of such a debris disk and caught two minor outbursts. Here we propose to continue the lightcurve monitoring with higher sampling rates and to expand it to more disks. The proposed time domain observations are a new dimension of debris disk studies that can bring unique insight to their evolution, providing important constraints on the collisional and dynamical models of terrestrial planet formation.

  7. Gravity and Extreme Magnetism SMEX

    NASA Technical Reports Server (NTRS)

    Swank, Jean; Kallman, Timothy R.; Jahoda, Keith M.

    2008-01-01

    Gas accreting ont,o black holes and neutron stars form a dynamic system generating X-rays with spectroscopic signatures and varying on time scales determined by the system. The radiation from various parts of these systems is surely polarized and compact sources have been calculated to give rise to net polarization from the unresolved sum of the radiation from the systems. Polarization has been looked to for some time as also bearing the imprint of strong gravity and providing complementary information that could resolve ambiguities between the physical models that can give rise to frequencies, time delays, and spectra. In the cases of both stellar black holes and supermassive black holes the net polarizations predicted for probable disk and corona models are less than 10 needed. This sensitivity can be achieved, even for sources as faint as 1 milliCrab, in the Gravity and Extreme Magnetism SMEX (GEMS) mission that uses foil mirrors and Time Projection Chamber detectors. Similarities have been pointed out between the timing and the spectral characteristics of low mass X-ray binaries and stellar black hole sources. Polarization measurements for these sources could play a role in determining the configuration of the disk and the neutron star.

  8. Science of Extreme Light Infrastructure

    NASA Astrophysics Data System (ADS)

    Tajima, Toshiki; Barish, Barry C.; Barty, C. P.; Bulanov, Sergei; Chen, Pisin; Feldhaus, Josef; Hajdu, Janos; Keitel, Christoph H.; Kieffer, Jean-Claude; Ko, Do-Kyeong; Leemans, Wim; Normand, Didier; Palumbo, Luigi; Rzazewski, Kazimierz; Sergeev, Alexander; Sheng, Zheng-Ming; Takasaki, Fumihiko; Teshima, Masahiro

    2010-04-01

    The infrastructure of Extreme Light Infrastructure (ELI) provides an unprecedented opportunity for a broad range of frontier science. Its highest ever intensity of lasers, as well as high fluence, high power, and/or ultrafast optical characteristics carve out new territories of discovery, ranging from attosecond science to photonuclear science, laser acceleration and associated beams, and high field science (Four Pillars of ELI). Its applications span from medicine, biology, engineering, energy, chemistry, physics, and fundamental understanding of the Universe. The relativistic optics that intense lasers have begun exploring may be extended into a new regime of ultra-relativistic regime, where even protons fly relativistically in the optical fields. ELI provides the highest intensity to date such that photon fields begin to feel even the texture of vacuum. This is a singular appeal of ELI with its relatively modest infrastructure (compared to the contemporary largest scientific infrastructures), yet provides an exceptional avenue along which the 21st Century science and society need to answer the toughest questions. The intensity frontier simultaneously brings in the energy horizon (TeV and PeV) as well as temporal frontier (attoseconds and zeptoseconds). It also turns over optics of atoms and molecules into that of nuclei with the ability to produce monoenergetic collimated γ-ray photons. As such, the ELI concept acutely demands an effort to encompass and integrate its Four Pillars.

  9. Extreme Programming in a Research Environment

    NASA Technical Reports Server (NTRS)

    Wood, William A.; Kleb, William L.

    2002-01-01

    This article explores the applicability of Extreme Programming in a scientific research context. The cultural environment at a government research center differs from the customer-centric business view. The chief theoretical difficulty lies in defining the customer to developer relationship. Specifically, can Extreme Programming be utilized when the developer and customer are the same person? Eight of Extreme Programming's 12 practices are perceived to be incompatible with the existing research culture. Further, six of the nine 'environments that I know don't do well with XP' apply. A pilot project explores the use of Extreme Programming in scientific research. The applicability issues are addressed and it is concluded that Extreme Programming can function successfully in situations for which it appears to be ill-suited. A strong discipline for mentally separating the customer and developer roles is found to be key for applying Extreme Programming in a field that lacks a clear distinction between the customer and the developer.

  10. [Injury mechanisms in extreme violence settings].

    PubMed

    Arcaute-Velazquez, Fernando Federico; García-Núñez, Luis Manuel; Noyola-Vilallobos, Héctor Faustino; Espinoza-Mercado, Fernando; Rodríguez-Vega, Carlos Eynar

    2016-01-01

    Extreme violence events are consequence of current world-wide economic, political and social conditions. Injury patterns found among victims of extreme violence events are very complex, obeying several high-energy injury mechanisms. In this article, we present the basic concepts of trauma kinematics that regulate the clinical approach to victims of extreme violence events, in the hope that clinicians increase their theoretical armamentarium, and reflecting on obtaining better outcomes.

  11. Reporting Outcomes of Extremely Preterm Births.

    PubMed

    Rysavy, Matthew A; Marlow, Neil; Doyle, Lex W; Tyson, Jon E; Serenius, Frederik; Iams, Jay D; Stoll, Barbara J; Barrington, Keith J; Bell, Edward F

    2016-09-01

    Published reports of extremely preterm birth outcomes provide important information to families, clinicians, and others and are widely used to make clinical and policy decisions. Misreporting or misunderstanding of outcome reports may have significant consequences. This article presents 7 recommendations to improve reporting of extremely preterm birth outcomes in both the primary and secondary literature. The recommendations should facilitate clarity in communication about extremely preterm birth outcomes and increase the value of existing and future work in this area. PMID:27516525

  12. Real World: Analog Testing in Extreme Environments

    NASA Video Gallery

    See how NASA uses analog testing to simulate space exploration. Explore extreme environments like the Aquarius underwater laboratory in Key Largo, Florida. Find out how scientists use mathematical ...

  13. Controlling extreme events on complex networks

    NASA Astrophysics Data System (ADS)

    Chen, Yu-Zhong; Huang, Zi-Gang; Lai, Ying-Cheng

    2014-08-01

    Extreme events, a type of collective behavior in complex networked dynamical systems, often can have catastrophic consequences. To develop effective strategies to control extreme events is of fundamental importance and practical interest. Utilizing transportation dynamics on complex networks as a prototypical setting, we find that making the network ``mobile'' can effectively suppress extreme events. A striking, resonance-like phenomenon is uncovered, where an optimal degree of mobility exists for which the probability of extreme events is minimized. We derive an analytic theory to understand the mechanism of control at a detailed and quantitative level, and validate the theory numerically. Implications of our finding to current areas such as cybersecurity are discussed.

  14. Peripheral nerve blocks for distal extremity surgery.

    PubMed

    Offierski, Chris

    2013-10-01

    Peripheral nerve block is well suited for distal extremity surgery. Blocking the nerves at the distal extremity is easily done. It does not require ultrasound or stimulators to identify the nerve. Blocking nerves in the distal extremity is safe with low risk of toxicity. The effect of the nerve block is limited to the distribution of the nerve. The distal nerves in the lower extremity are sensory branches of the sciatic nerve. This provides a sensory block only. This has the advantage of allowing the patient to actively contract tendons in the foot and ambulate more quickly after surgery. PMID:24093651

  15. The limits for life under multiple extremes.

    PubMed

    Harrison, Jesse P; Gheeraert, Nicolas; Tsigelnitskiy, Dmitry; Cockell, Charles S

    2013-04-01

    Life on Earth is limited by physical and chemical extremes that define the 'habitable space' within which it operates. Aside from its requirement for liquid water, no definite limits have been established for life under any extreme. Here, we employ growth data published for 67 prokaryotic strains to explore the limitations for microbial life under combined extremes of temperature, pH, salt (NaCl) concentrations, and pressure. Our review reveals a fundamental lack of information on the tolerance of microorganisms to multiple extremes that impedes several areas of science, ranging from environmental and industrial microbiology to the search for extraterrestrial life. PMID:23453124

  16. Generalized extreme gust wind speeds distributions

    USGS Publications Warehouse

    Cheng, E.; Yeung, C.

    2002-01-01

    Since summer 1996, the US wind engineers are using the extreme gust (or 3-s gust) as the basic wind speed to quantify the destruction of extreme winds. In order to better understand these destructive wind forces, it is important to know the appropriate representations of these extreme gust wind speeds. Therefore, the purpose of this study is to determine the most suitable extreme value distributions for the annual extreme gust wind speeds recorded in large selected areas. To achieve this objective, we are using the generalized Pareto distribution as the diagnostic tool for determining the types of extreme gust wind speed distributions. The three-parameter generalized extreme value distribution function is, thus, reduced to either Type I Gumbel, Type II Frechet or Type III reverse Weibull distribution function for the annual extreme gust wind speeds recorded at a specific site.With the considerations of the quality and homogeneity of gust wind data collected at more than 750 weather stations throughout the United States, annual extreme gust wind speeds at selected 143 stations in the contiguous United States were used in the study. ?? 2002 Elsevier Science Ltd. All rights reserved.

  17. Visible light absorbance enhanced by nitrogen embedded in the surface layer of Mn-doped sodium niobate crystals, detected by ultra violet - visible spectroscopy, x-ray photoelectron spectroscopy, and electric conductivity tests

    NASA Astrophysics Data System (ADS)

    Molak, A.; Pilch, M.

    2016-05-01

    Sodium niobate crystals doped with manganese ions, Na(NbMn)O3, were annealed in a nitrogen N2 flow at 600, 670, and 930 K. It was verified that simultaneous doping with Mn ions and annealing in nitrogen enhanced the photocatalytic features of sodium niobate. The transmission in the ultraviolet-visible range was measured at room temperature. The absorbance edge is in the range from 3.4 to 2.3 eV. The optical band gap Egap = 1.2-1.3 eV was evaluated using the Tauc relation. Crystals annealed at 670 K and 930 K exhibited an additional shift of the absorption edge of ˜20-40 nm toward longer wavelengths. The optical energy gap narrowed as a result of the superimposed effect of Mn and N co-doping. The x-ray photoelectron spectroscopy test showed that N ions incorporated into the surface layer. The valence band consisted of O 2p states hybridized with Nb 4d, Mn 3d, and N 2s states. The disorder detected in the surroundings of Nb and O ions decreased due to annealing. The binding energy of oxygen ions situated within the surface layer was EB ≈ 531 eV. The other contributions were assigned to molecular contamination. The contribution centered at 535.5 eV vanished after annealing at 600 K and 670 K. The contribution centered at 534 eV vanished after annealing at 930 K. The N2 annealing partly removed carbonates from the surfaces of the samples. In the 480-950 K range, the electric conductivity activation energy, Ea = 0.7-1.2 eV, was comparable with the optical Egap. The electric permittivity showed dispersion in the 0.1-800 kHz range that corresponds to the occurrence of defects.

  18. Deep ultra violet and visible Raman spectroscopy studies of ion implanted 6H-SiC: Recrytallisation behaviour and thermal decomposition/thermal etching of the near surface region

    NASA Astrophysics Data System (ADS)

    Kuhudzai, R. J.; Malherbe, J. B.; van der Berg, N. G.; Hlatshwayo, T. T.; Odutemowo, O.; Prinsloo, L. C.; Buys, A. V.; Erasmus, R.; Wendler, E.

    2015-12-01

    The recystallisation behaviour and thermal decomposition of the near surface amorphised region of 6H-SiC have been investigated by Raman spectroscopy. 360 keV ions of iodine and silver were implanted at room temperature into wafers of 6H-SiC resulting in the amorphisation of the near surface region. Vacuum annealing of the samples was performed at 1200 °C for 5 h and then sequentially from 1200 to 1600 °C in steps of 100 °C for 30 h at each annealing temperature. Raman spectroscopy was performed using two laser wavelength excitation regimes, the 514 nm laser (visible region) and the 244 nm laser (deep ultraviolet region, DUV). Measurements in the visible region for samples annealed at 1200 °C for 5 h showed that the characteristic 6H-SiC peaks, namely, the Transverse Optical (TO) and Longitudinal Optical (LO) are similar to the virgin samples, albeit with lower intensity due to some retained defects upon recystallisation of the SiC surface region. The similarities between the virgin spectra and the annealed sample were due to the deep penetration of the 514 nm laser into 6H-SiC resulting in the signal from the bulk undamaged 6H-SiC contributing to the overall spectra. However, DUV laser excitation, which only probes the near surface region, shows that after annealing the peaks are broader and asymmetrical compared to the virgin samples. DUV Raman spectra of samples annealed at 1600 °C indicate that SiC has completely decomposed and the top surface layer is now covered by a carbon layer. However the deeper penetrating laser in the visible region showed that the extent of decomposition at 1600 °C was greater for the silver implanted samples than for the iodine implanted samples.

  19. Application of parallel gradient high performance liquid chromatography with ultra-violet, evaporative light scattering and electrospray mass spectrometric detection for the quantitative quality control of the compound file to support pharmaceutical discovery.

    PubMed

    Squibb, Anthony W; Taylor, Mark R; Parnas, Barry L; Williams, Gareth; Girdler, Richard; Waghorn, Peter; Wright, Adrian G; Pullen, Frank S

    2008-05-01

    The success of drug discovery assays, using plate-based technologies, relies heavily on the quality of the substrates being tested. Sample purity, identity and concentration must be assured for a screening hit to be validated. Most major pharmaceutical companies maintain large liquid screening files with often in excess of one million stock solutions, typically dissolved in DMSO. However, due to the inherent inaccuracies of high-throughput gravimetric analysis and automated dilution, stock solution concentrations can vary significantly from the assumed nominal value. Here, we present a rapid and effective method for measuring purity, identity and concentration of these stock solutions using four high-performance liquid chromatography (HPLC) columns with parallel ultraviolet spectrophotometry (UV), electrospray ionisation mass spectrometry (ESI-MS) and evaporative light scattering detection (ELSD) with a throughput of 1 min per sample.

  20. 3H-1,2-dithiole-3-thione protects retinal pigment epithelium cells against Ultra-violet radiation via activation of Akt-mTORC1-dependent Nrf2-HO-1 signaling

    PubMed Central

    Li, Ke-ran; Yang, Su-qing; Gong, Yi-qing; Yang, Hong; Li, Xiu-miao; Zhao, Yu-xia; Yao, Jin; Jiang, Qin; Cao, Cong

    2016-01-01

    Excessive UV radiation and reactive oxygen species (ROS) cause retinal pigment epithelium (RPE) cell injuries. Nrf2 regulates transcriptional activation of many anti-oxidant genes. Here, we tested the potential role of 3H-1,2-dithiole-3-thione (D3T) against UV or ROS damages in cultured RPE cells (both primary cells and ARPE-19 line). We showed that D3T significantly inhibited UV-/H2O2-induced RPE cell death and apoptosis. UV-stimulated ROS production was dramatically inhibited by D3T pretreatment. D3T induced Nrf2 phosphorylation in cultured RPE cells, causing Nrf2 disassociation with KEAP1 and its subsequent nuclear accumulation. This led to expression of antioxidant response elements (ARE)-dependent gene heme oxygenase-1 (HO-1). Nrf2-HO-1 activation was required for D3T-mediated cytoprotective effect. Nrf2 shRNA knockdown or S40T dominant negative mutation as well as the HO-1 inhibitor Zinc protoporphyrin (ZnPP) largely inhibited D3T’s RPE cytoprotective effects against UV radiation. Yet, exogenous overexpression Nrf2 enhanced D3T’s activity in RPE cells. Further studies showed that D3T activated Akt/mTORC1 in cultured RPE cells. Akt-mTORC1 inhibitors, or Akt1 knockdown by shRNA, not only inhibited D3T-induced Nrf2-HO-1 activation, but also abolished the RPE cytoprotective effects. In vivo, D3T intravitreal injection protected from light-induced retinal dysfunctions in mice. Thus, D3T protects RPE cells from UV-induced damages via activation of Akt-mTORC1-Nrf2-HO-1 signaling axis. PMID:27151674

  1. Ablation of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} glass with an ultra-violet nano-second laser

    SciTech Connect

    Knotek, P.; Navesnik, J.; Cernohorsky, T.; Kincl, M.; Vlcek, M.; Tichy, L.

    2015-04-15

    Highlights: • The interaction of (GeS{sub 2}){sub 0.3}(Sb{sub 2}S{sub 3}){sub 0.7} bulk glass and film with UV nanosecond laser. • Ablation process, topography of crater and structure of the material were studied. • Ablation threshold fluencies changed with the spot diameter and number of pulses. • The photo-thermal expansion of the material occurred for low laser fluency. • Laser direct writing process applicable for fabrication of passive optical elements. - Abstract: The results of an experimental study of the laser ablation of bulk and thin films of a GeSbS chalcogenide glass using UV nanosecond pulses are reported. The response of the samples to illumination conditions was studied through the use of atomic force spectroscopy, digital holographic microscopy, Raman scattering and scanning electron microscopy. The multi-pulse ablation thresholds were determined for both the bulk and thin film samples for varying number of pulses and illuminated spot diameter. The possible application of direct laser writing into the bulk and thin films of this material is presented.

  2. High-performance anion-exchange chromatography coupled with pulsed amperometric detection and capillary zone electrophoresis with indirect ultra violet detection as powerful tools to evaluate prebiotic properties of fructooligosaccharides and inulin.

    PubMed

    Corradini, C; Bianchi, F; Matteuzzi, D; Amoretti, A; Rossi, M; Zanoni, S

    2004-10-29

    Fructooligosaccharides (FOS) and inulin are food grade non-digestible carbohydrates that exert beneficial nutritional effect. This paper describes the suitability of high-performance anion-exchange chromatography coupled with pulsed amperometric detection (HPAEC-PAD) and capillary zone electrophoresis (CZE) to evaluate fermentation properties of FOS and inulin in pure Bifidobacterium cultures; and to study their effects on faecal cultures (microbial population and short-chain fatty acids). Prebiotic effectiveness of FOS and inulin of different degrees of polymerization was evaluated monitoring the changes in their molecular weight distribution during the in vitro growth of selected Bifidobacterium strains. The qualitative analysis of the residual soluble oligosaccharides or polysaccharides from Raftilose Synergy, Raftiline HP and Raftilose P95 was carried out by HPAEC-PAD, using a CarboPac PA 100 column and an appositely optimized gradient elution program. Under the optimized gradient elution conditions, glucose, fructose, sucrose were resolved from each other and from fructans with a DP ranging from 3 (1-kestose) to 60. The chromatographic profiles of the spent broths pointed out that almost every strain presented a different capability to ferment fructan chains of variable DP, indicating wide strain to strain differences. To explore the prebiotic effect of FOS and inulin, related to of short chain fatty acids (SCFAs) accumulation in faecal cultures due to fermentative metabolism of intestinal microflora, analysis of SCFAs, acetic and lactic acid was achieved by co-electroosmotic capillary electrophoresis, where the electrophoretic mobility of the anionic analytes and electroosmotic flow (EOF) were similarly directed. Moreover, the use of UV detection for the analyses of our organic anions required a running electrolyte which allowed indirect detection. The optimization of the capillary electrophoretic conditions was carried out by applying a chemometric study based on the use of the experimental design, the effects of three parameters, i.e. temperature, voltage and percentage of methanol added to the background electrolyte were investigated.

  3. Reversed Phase High-Performance Liquid Chromatographic Ultra-violet (Photo Diode Array) Quantification of Oleanolic Acid and its Isomer Ursolic Acid for Phytochemical Comparison and Pharmacological Evaluation of Four Leucas Species Used in Ayurveda

    PubMed Central

    Shukla, Pushpendra Kumar; Misra, Ankita; Srivastava, Sharad; Rawat, Ajay K. S.

    2016-01-01

    Content: Different Leucas species are well known as “Dronpushpi,” a well-known herb of Ayurveda, used in the treatment of various ailments. Objective: Evaluation of four industrially important Leucas species for their in vitro antidiabetic potential and radical scavenging effect along with high-performance liquid chromatographic quantification of the bioactive triterpenes. Materials and Methods: The quantification of triterpenes was carried out on C-18 column with acetonitrile and water (90:10) as the solvent system at a detection wavelength of 210 nm. In vitro antidiabetic activity was evaluated by α-amylase inhibition assay based on starch–iodine and 3,5 dinitrosalicylic acid (DNS) method. Antioxidant activity was calculated by five different models, namely total phenolic and total flavonoid content, free radical scavenging activity by 1-1-diphenyl-2-pic-rylhydrazyl (DPPH), ferric-reducing power assay, and the total antioxidant capacity. Results: Maximum concentration of oleanolic acid was found in Leucas cristata, followed by Leucas mollissima, Leucas Aspera, and Leucas biflora. Ursolic acid was highest in L. mollissima and then in L. biflora, L. cristata, and L. aspera, respectively. In in vitro antidiabetic activity, IC50 of L. aspera (1.56 ± 0.01 mg/ml) and L. mollissima (0.75 ± 0.005 mg/ml) were found to be highest in DNS and iodine starch assay. IC50 in DPPH assay ranges from 0.6 ± 0.011 to 1.68 ± 0.011 mg/ml. Antioxidant capacity follows the order; L. aspera > L. mollissima > L. biflora > L. cristata. Conclusion: Promising activities were observed in targeted species, thus L. mollissima, L. biflora, and L. cristata can be used alternatively as a substitute to L. aspera. SUMMARY Physicochemical parameters are within the limit as per the Ayurvedic Pharmacopoeia of IndiaMaximum concentration of oleanolic acid was found in Leucas cristata; however, ursolic acid was highest in Leucas mollissimaIn vitro antidiabetic activity of Leucas aspera and L. mollissima was found to be heighest as compared to other species. However, antioxidant capacity is almost similar in targeted species.Promising activities were observed in all the species, thus L. mollissima, Leucas biflora, and L. cristata can be used alternatively as a substitute to L. aspera. PMID:27279701

  4. Simulation and Estimation of Extreme Quantiles and Extreme Probabilities

    SciTech Connect

    Guyader, Arnaud; Hengartner, Nicolas; Matzner-Lober, Eric

    2011-10-15

    Let X be a random vector with distribution {mu} on Double-Struck-Capital-R {sup d} and {Phi} be a mapping from Double-Struck-Capital-R {sup d} to Double-Struck-Capital-R . That mapping acts as a black box, e.g., the result from some computer experiments for which no analytical expression is available. This paper presents an efficient algorithm to estimate a tail probability given a quantile or a quantile given a tail probability. The algorithm improves upon existing multilevel splitting methods and can be analyzed using Poisson process tools that lead to exact description of the distribution of the estimated probabilities and quantiles. The performance of the algorithm is demonstrated in a problem related to digital watermarking.

  5. War injuries of the extremities.

    PubMed

    Korzinek, K

    1993-05-01

    This paper describes experience acquired during the war against Croatia under improvised conditions at the Kutina War Hospital in the immediate vicinity of the first front lines. Over a period of almost 6 months a total of 701 soldiers and civilians, 546 of whom had been wounded by firearm missiles, were treated at the Kutina War Hospital, which has a capacity of 30-40 beds. As many as 87% of the injuries were due to mine, bomb or artillery shell shrapnel. The percentage of gunshot wounds was very low, mainly caused by sniper shots. Most patients (419, or 76.7%) were admitted with injuries to the extremities, including 893 severe soft tissue injuries and 182 fractures (32.3%). Soft tissue injuries were treated by routine procedures of war surgery, associated with ample use of Lavasept, an antiseptic solution (Fresenius, Stans, Switzerland), which has proved to be highly efficacious in preventing and decontaminating infection without disturbance of the wound healing process. Long bone fractures were fixed with the aid of external fixators of various designs, including the CMC external fixator of our own construction. External fixators have once again proved indispensable in the treatment of open fractures sustained in war settings. Amputations were performed in 10.4% of cases, including fingers and toes. Only 8 patients died during or immediately after surgery, corresponding to a very low mortality rate of 1.46%. The main prerequisites for successful treatment are a professional relationship to war surgery and its specific requirements, satisfactory technical equipment, and excellent organization of medical and non-medical services.

  6. Extreme-UV lithography system

    DOEpatents

    Replogle, William C.; Sweatt, William C.

    2001-01-01

    A photolithography system that employs a condenser that includes a series of aspheric mirrors on one side of a small, incoherent source of radiation producing a series of beams is provided. Each aspheric mirror images the quasi point source into a curved line segment. A relatively small arc of the ring image is needed by the camera; all of the beams are so manipulated that they all fall onto this same arc needed by the camera. Also, all of the beams are aimed through the camera's virtual entrance pupil. The condenser includes a correcting mirror for reshaping a beam segment which improves the overall system efficiency. The condenser efficiently fills the larger radius ringfield created by today's advanced camera designs. The system further includes (i) means for adjusting the intensity profile at the camera's entrance pupil or (ii) means for partially shielding the illumination imaging onto the mask or wafer. The adjusting means can, for example, change at least one of: (i) partial coherence of the photolithography system, (ii) mask image illumination uniformity on the wafer or (iii) centroid position of the illumination flux in the entrance pupil. A particularly preferred adjusting means includes at least one vignetting mask that covers at least a portion of the at least two substantially equal radial segments of the parent aspheric mirror.

  7. Investigation of Star Formation: Instrumentation and Methodology

    NASA Astrophysics Data System (ADS)

    Veach, Todd Justin

    A thorough exploration of star formation necessitates observation across the electromagnetic spectrum. In particular, observations in the submillimeter and ultra-violet allow one to observe very early stage star formation and to trace the evolution from molecular cloud collapse to stellar ignition. Submillimeter observations are essential for piercing the heart of heavily obscured stellar nurseries to observe star formation in its infancy. Ultra-violet observations allow one to observe stars just after they emerge from their surrounding environment, allowing higher energy radiation to escape. To make detailed observations of early stage star formation in both spectral regimes requires state-of-the-art detector technology and instrumentation. In this dissertation, I discuss the calibration and feasibility of detectors developed by Lawrence Berkeley National Laboratory and specially processed at the Jet Propulsion Laboratory to increase their quantum efficiency at far-ultraviolet wavelengths. A cursory treatment of the delta-doping process is presented, followed by a thorough discussion of calibration procedures developed at JPL and in the Laboratory for Astronomical and Space Instrumentation at ASU. Subsequent discussion turns to a novel design for a Modular Imager Cell forming one possible basis for construction of future large focal plane arrays. I then discuss the design, fabrication, and calibration of a sounding rocket imaging system developed using the MIC and these specially processed detectors. Finally, I discuss one scientific application of sub-mm observations. I used data from the Heinrich Hertz Sub-millimeter Telescope and the Sub-Millimeter Array (SMA) to observe sub-millimeter transitions and continuum emission towards AFGL 2591. I tested the use of vibrationally excited HCN emission to probe the protostellar accretion disk structure. I measured vibrationally excited HCN line ratios in order to elucidate the appropriate excitation mechanism. I find

  8. Role of extreme events in vegetation dynamics

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Extreme climatic events challenge the capacity of vegetation models, including Dynamic Global Vegetation Models, to predict changes in plant species dynamics at local and regional spatial scales and over time periods relevant to ecologists and managers. Extreme climatic events are defined as large,...

  9. Generalized IRT Models for Extreme Response Style

    ERIC Educational Resources Information Center

    Jin, Kuan-Yu; Wang, Wen-Chung

    2014-01-01

    Extreme response style (ERS) is a systematic tendency for a person to endorse extreme options (e.g., strongly disagree, strongly agree) on Likert-type or rating-scale items. In this study, we develop a new class of item response theory (IRT) models to account for ERS so that the target latent trait is free from the response style and the tendency…

  10. Complex Plasma Research Under Extreme Conditions

    SciTech Connect

    Ishihara, Osamu

    2008-09-07

    Complex plasma research under extreme conditions is described. The extreme conditions include low-dimensionality for self-organized structures of dust particles, dust magnetization in high magnetic field, criticality in phase transition, and cryogenic environment for Coulomb crystals and dust dynamics.

  11. Surface atmospheric extremes (Launch and transportation areas)

    NASA Technical Reports Server (NTRS)

    1972-01-01

    The effects of extreme values of surface and low altitude atmospheric parameters on space vehicle design, tests, and operations are discussed. Atmospheric extremes from the surface to 150 meters for geographic locations of interest to NASA are given. Thermal parameters (temperature and solar radiation), humidity, pressure, and atmospheric electricity (lighting and static) are presented. Weather charts and tables are included.

  12. The Nature and Characteristics of Youthful Extremism

    ERIC Educational Resources Information Center

    Zubok, Iu. A.; Chuprov, V. I.

    2010-01-01

    Extremism is an acute problem of the present day. Moods of extremism are manifested in all spheres of the life and activities of young people--in education, work, business, political life, and leisure activity. They can be found in both individual and group social self-determination and are influenced by the immediate social environment as well as…

  13. EPE The Extreme Physics Explorer

    NASA Technical Reports Server (NTRS)

    Garcia, Michael; Elvis, Martin; Bookbinder, Jay; Brenneman, Laura; Bulbul, Esra; Nulsen, Paul; Patnaude, Dan; Smith, Randall; Bandler, Simon; Okajima, Takashi; Ptak, Andy; Figueroa-Feliciano, Enectali; Chakrabarty, Deepto; Danner, Rolf; Daily, Dean; Fraser, George; Willingale, Richard; Miller, Jon; Turner, T. J.; Risalti, Guido; Galeazzi, Massimiliano

    2012-01-01

    The Extreme Physics Explorer (EPE) is a mission concept that will address fundamental and timely questions in astrophysics which are primary science objectives of IXO. The reach of EPE to the areas outlined in NASA RFI NNH11ZDA018L is shown as a table. The dark green indicates areas in which EPE can do the basic IXO science, and the light green areas where EPE can contribute but will not reach the full IXO capability. To address these science questions, EPE will trace orbits close to the event horizon of black holes, measure black hole spin in active galactic nuclei (AGN), use spectroscopy to characterize outflows and the environment of AGN, map bulk motions and turbulence in galaxy clusters, and observe the process of cosmic feedback where black holes inject energy on galactic and intergalactic scales. EPE gives up the high resolution imaging of IXO in return for lightweight, high TRL foil mirrors which will provide >20 times the effective area of ASTRO-H and similar spatial resolution, with a beam sufficient to study point sources and nearby galaxies and clusters. Advances in micro-calorimeters allow improved performance at high rates with twice the energy resolution of ASTRO-H. A lower TRL option would provide 200 times the area of ASTRO-H using a micro-channel plate optic (MCPO) and a deployable optical bench. Both options are in the middle range of RFI missions at between $600M and $1000M. The EPE foil optic has direct heritage to ASTRO-H, allowing robust cost estimates. The spacecraft is entirely off the shelf and introduces no difficult requirements. The mission could be started and launched in this decade to an L2 orbit, with a three-year lifetime and consumables for 5 years. While ASTRO-H will give us the first taste of high-resolution, non-dispersive X-ray spectroscopy, it will be limited to small numbers of objects in many categories. EPE will give us the first statistically significant samples in each of these categories.

  14. Batch efficiency

    NASA Astrophysics Data System (ADS)

    Schwickerath, Ulrich; Silva, Ricardo; Uria, Christian

    2010-04-01

    A frequent source of concern for resource providers is the efficient use of computing resources in their centers. This has a direct impact on requests for new resources. There are two different but strongly correlated aspects to be considered: while users are mostly interested in a good turn-around time for their jobs, resource providers are mostly interested in a high and efficient usage of their available resources. Both things, the box usage and the efficiency of individual user jobs, need to be closely monitored so that the sources of the inefficiencies can be identified. At CERN, the Lemon monitoring system is used for both purposes. Examples of such sources are poorly written user code, inefficient access to mass storage systems, and dedication of resources to specific user groups. As a first step for improvements CERN has launched a project to develop a scheduler add-on that allows careful overloading of worker nodes that run idle jobs.

  15. Extremely acidophilic sulfur-oxidizing bacteria applied in biotechnological processes for gas purification.

    PubMed

    Kraakman, Norbertus J R; Pol, Arjan; Smeulders, Marjan J; Jetten, Mike S M; Op Den Camp, Huub J M

    2012-01-01

    Extreme acidophilic (pH ~ 0.25) microorganisms have been studied and applied to treat volatile sulfur emissions like carbon disulfide. These microorganisms provide opportunities for biomass control and recycling of sulfuric acid using extremely low pH operating conditions as shown in 70 L bench-scale bioreactors. Applying the extreme acidophilic bacteria in full-scale bioreactors treating carbon disulfide in combination with hydrogen sulfide emissions from industrial processes like the viscose industry was shown to be effective with average total sulfur removal efficiency above 90%.

  16. Extreme Ultraviolet Imaging Telescope (EIT)

    NASA Technical Reports Server (NTRS)

    Lemen, J. R.; Freeland, S. L.

    1997-01-01

    Efforts concentrated on development and implementation of the SolarSoft (SSW) data analysis system. From an EIT analysis perspective, this system was designed to facilitate efficient reuse and conversion of software developed for Yohkoh/SXT and to take advantage of a large existing body of software developed by the SDAC, Yohkoh, and SOHO instrument teams. Another strong motivation for this system was to provide an EIT analysis environment which permits coordinated analysis of EIT data in conjunction with data from important supporting instruments, including Yohkoh/SXT and the other SOHO coronal instruments; CDS, SUMER, and LASCO. In addition, the SSW system will support coordinated EIT/TRACE analysis (by design) when TRACE data is available; TRACE launch is currently planned for March 1998. Working with Jeff Newmark, the Chianti software package (K.P. Dere et al) and UV /EUV data base was fully integrated into the SSW system to facilitate EIT temperature and emission analysis.

  17. Climate extremes and the carbon cycle (Invited)

    NASA Astrophysics Data System (ADS)

    Reichstein, M.; Bahn, M.; Ciais, P.; Mahecha, M. D.; Seneviratne, S. I.; Zscheischler, J.

    2013-12-01

    The terrestrial biosphere is a key component of the global carbon cycle and its carbon balance is strongly influenced by climate. Ongoing environmental changes are thought to increase global terrestrial carbon uptake. But evidence is mounting that rare climate extremes can lead to a decrease in ecosystem carbon stocks and therefore have the potential to negate the expected increase in terrestrial carbon uptake. Here we explore the mechanisms and impacts of climate extremes on the terrestrial carbon cycle, and propose a pathway to improve our understanding of present and future impacts of climate extremes on the terrestrial carbon budget. In addition to direct impact on the carbon fluxes of photosynthesis and respiration via extreme temperature and (or) drought, effects of extreme events may also lead to lagged responses, such as wildfires triggered by heat waves and droughts, or pest and pathogen outbreaks following wind-throw caused by heavy storms, reduced plant health due to drought stress or due to less frequent cold extremes in presently cold regions. One extreme event can potentially override accumulated previous carbon sinks, as shown by the Western European 2003 heat wave.. Extreme events have the potential to affect the terrestrial ecosystem carbon balance through a single factor, or as a combination of factors. Climate extremes can cause carbon losses from accumulated stocks, as well as long-lasting impacts on (e.g. lagged effects) on plant growth and mortality, extending beyond the duration of the extreme event itself. The sensitivity of terrestrial ecosystems and their carbon balance to climate change and extreme events varies according to the type of extreme, the climatic region, the land cover, and the land management. Extreme event impacts are very relevant in forests due to the importance of lagged and memory effects on tree growth and mortality, the longevity of tree species, the large forest carbon stocks and their vulnerability, as well as the

  18. The influence of altering push force effectiveness on upper extremity demand during wheelchair propulsion.

    PubMed

    Rankin, Jeffery W; Kwarciak, Andrew M; Mark Richter, W; Neptune, Richard R

    2010-10-19

    Manual wheelchair propulsion has been linked to a high incidence of overuse injury and pain in the upper extremity, which may be caused by the high load requirements and low mechanical efficiency of the task. Previous studies have suggested that poor mechanical efficiency may be due to a low effective handrim force (i.e. applied force that is not directed tangential to the handrim). As a result, studies attempting to reduce upper extremity demand have used various measures of force effectiveness (e.g., fraction effective force, FEF) as a guide for modifying propulsion technique, developing rehabilitation programs and configuring wheelchairs. However, the relationship between FEF and upper extremity demand is not well understood. The purpose of this study was to use forward dynamics simulations of wheelchair propulsion to determine the influence of FEF on upper extremity demand by quantifying individual muscle stress, work and handrim force contributions at different values of FEF. Simulations maximizing and minimizing FEF resulted in higher average muscle stresses (23% and 112%) and total muscle work (28% and 71%) compared to a nominal FEF simulation. The maximal FEF simulation also shifted muscle use from muscles crossing the elbow to those at the shoulder (e.g., rotator cuff muscles), placing greater demand on shoulder muscles during propulsion. The optimal FEF value appears to represent a balance between increasing push force effectiveness to increase mechanical efficiency and minimize upper extremity demand. Thus, care should be taken in using force effectiveness as a metric to reduce upper extremity demand.

  19. Extreme Learning Machine for Multilayer Perceptron.

    PubMed

    Tang, Jiexiong; Deng, Chenwei; Huang, Guang-Bin

    2016-04-01

    Extreme learning machine (ELM) is an emerging learning algorithm for the generalized single hidden layer feedforward neural networks, of which the hidden node parameters are randomly generated and the output weights are analytically computed. However, due to its shallow architecture, feature learning using ELM may not be effective for natural signals (e.g., images/videos), even with a large number of hidden nodes. To address this issue, in this paper, a new ELM-based hierarchical learning framework is proposed for multilayer perceptron. The proposed architecture is divided into two main components: 1) self-taught feature extraction followed by supervised feature classification and 2) they are bridged by random initialized hidden weights. The novelties of this paper are as follows: 1) unsupervised multilayer encoding is conducted for feature extraction, and an ELM-based sparse autoencoder is developed via l1 constraint. By doing so, it achieves more compact and meaningful feature representations than the original ELM; 2) by exploiting the advantages of ELM random feature mapping, the hierarchically encoded outputs are randomly projected before final decision making, which leads to a better generalization with faster learning speed; and 3) unlike the greedy layerwise training of deep learning (DL), the hidden layers of the proposed framework are trained in a forward manner. Once the previous layer is established, the weights of the current layer are fixed without fine-tuning. Therefore, it has much better learning efficiency than the DL. Extensive experiments on various widely used classification data sets show that the proposed algorithm achieves better and faster convergence than the existing state-of-the-art hierarchical learning methods. Furthermore, multiple applications in computer vision further confirm the generality and capability of the proposed learning scheme. PMID:25966483

  20. High resolution modelling of extreme precipitation events in urban areas

    NASA Astrophysics Data System (ADS)

    Siemerink, Martijn; Volp, Nicolette; Schuurmans, Wytze; Deckers, Dave

    2015-04-01

    The present day society needs to adjust to the effects of climate change. More extreme weather conditions are expected, which can lead to longer periods of drought, but also to more extreme precipitation events. Urban water systems are not designed for such extreme events. Most sewer systems are not able to drain the excessive storm water, causing urban flooding. This leads to high economic damage. In order to take appropriate measures against extreme urban storms, detailed knowledge about the behaviour of the urban water system above and below the streets is required. To investigate the behaviour of urban water systems during extreme precipitation events new assessment tools are necessary. These tools should provide a detailed and integral description of the flow in the full domain of overland runoff, sewer flow, surface water flow and groundwater flow. We developed a new assessment tool, called 3Di, which provides detailed insight in the urban water system. This tool is based on a new numerical methodology that can accurately deal with the interaction between overland runoff, sewer flow and surface water flow. A one-dimensional model for the sewer system and open channel flow is fully coupled to a two-dimensional depth-averaged model that simulates the overland flow. The tool uses a subgrid-based approach in order to take high resolution information of the sewer system and of the terrain into account [1, 2]. The combination of using the high resolution information and the subgrid based approach results in an accurate and efficient modelling tool. It is now possible to simulate entire urban water systems using extreme high resolution (0.5m x 0.5m) terrain data in combination with a detailed sewer and surface water network representation. The new tool has been tested in several Dutch cities, such as Rotterdam, Amsterdam and The Hague. We will present the results of an extreme precipitation event in the city of Schiedam (The Netherlands). This city deals with

  1. Analysis of the dependence of extreme rainfalls

    NASA Astrophysics Data System (ADS)

    Padoan, Simone; Ancey, Christophe; Parlange, Marc

    2010-05-01

    The aim of spatial analysis is to quantitatively describe the behavior of environmental phenomena such as precipitation levels, wind speed or daily temperatures. A number of generic approaches to spatial modeling have been developed[1], but these are not necessarily ideal for handling extremal aspects given their focus on mean process levels. The areal modelling of the extremes of a natural process observed at points in space is important in environmental statistics; for example, understanding extremal spatial rainfall is crucial in flood protection. In light of recent concerns over climate change, the use of robust mathematical and statistical methods for such analyses has grown in importance. Multivariate extreme value models and the class of maxstable processes [2] have a similar asymptotic motivation to the univariate Generalized Extreme Value (GEV) distribution , but providing a general approach to modeling extreme processes incorporating temporal or spatial dependence. Statistical methods for max-stable processes and data analyses of practical problems are discussed by [3] and [4]. This work illustrates methods to the statistical modelling of spatial extremes and gives examples of their use by means of a real extremal data analysis of Switzerland precipitation levels. [1] Cressie, N. A. C. (1993). Statistics for Spatial Data. Wiley, New York. [2] de Haan, L and Ferreria A. (2006). Extreme Value Theory An Introduction. Springer, USA. [3] Padoan, S. A., Ribatet, M and Sisson, S. A. (2009). Likelihood-Based Inference for Max-Stable Processes. Journal of the American Statistical Association, Theory & Methods. In press. [4] Davison, A. C. and Gholamrezaee, M. (2009), Geostatistics of extremes. Journal of the Royal Statistical Society, Series B. To appear.

  2. Efficiency Goals

    ERIC Educational Resources Information Center

    Graham, Donald

    2009-01-01

    The lighting of learning environments is an important focus in designing new schools and renovating older schools. Studies long have shown that appropriate lighting levels and daylighting improve learning; now, climbing energy budgets have spurred school administrators to seek more efficient use of lighting. Electricity rates are expected to rise…

  3. Comparison of line x-ray emission from solid and porous nano-layer coated targets irradiated by double laser pulses

    SciTech Connect

    Fazeli, R.; Mahdieh, M. H.

    2015-11-15

    Enhancement of line x-ray emission from both solid and porous iron targets induced by irradiation of single and double laser pulses is studied numerically. The line emission from laser produced plasma is calculated within the extreme ultra-violet lithography wavelength range of 13.5–13.7 nm. The effects of pre-pulse intensity and delay time between two pulses (pre-pulse and main pulse) are examined. The results show that using double pulses irradiation in the conditions of porous target can reduce the x-ray enhancement. According to the results, the use of both pre-pulse and porous target leads to efficient absorption of the laser energy. Calculations also show that such enhanced laser absorption can ionize atoms of the target material to very high degrees of ionization, leading to decrease of the density of appropriate ions that are responsible for line emission in the selected wavelength region. By increasing the target porosity, x-ray yield was more reduced.

  4. Comparison of line x-ray emission from solid and porous nano-layer coated targets irradiated by double laser pulses

    NASA Astrophysics Data System (ADS)

    Fazeli, R.; Mahdieh, M. H.

    2015-11-01

    Enhancement of line x-ray emission from both solid and porous iron targets induced by irradiation of single and double laser pulses is studied numerically. The line emission from laser produced plasma is calculated within the extreme ultra-violet lithography wavelength range of 13.5-13.7 nm. The effects of pre-pulse intensity and delay time between two pulses (pre-pulse and main pulse) are examined. The results show that using double pulses irradiation in the conditions of porous target can reduce the x-ray enhancement. According to the results, the use of both pre-pulse and porous target leads to efficient absorption of the laser energy. Calculations also show that such enhanced laser absorption can ionize atoms of the target material to very high degrees of ionization, leading to decrease of the density of appropriate ions that are responsible for line emission in the selected wavelength region. By increasing the target porosity, x-ray yield was more reduced.

  5. Overcoming pattern collapse on e-beam and EUV lithography

    NASA Astrophysics Data System (ADS)

    Jouve, A.; Simon, J.; Pikon, A.; Solak, H.; Vannuffel, C.; Tortai, J.-H.

    2006-03-01

    In this study we investigate the pattern collapse mechanism of dense patterns with resolution under 60nm printed in Extreme Ultra Violet (EUV-IL) and Electron Beam Lithographies (EBL). Pattern collapse occurs when physical properties of the material can't imbalanced the capillary force exerted on the pattern during the drying of the rinse liquid. In former simulation models, the height of the pattern at which collapse occurs (critical height, H c) was predicted using either elastic deformation properties, or plasticizing limit value of the resist. Experimental observations of unstuck patterns, lead us to develop 2 new models considering the adhesion properties of the resist film on the substrate. By comparing simulated to experimental results for varying pattern pitchs printed in 2 Chemically Amplified Resists (CARS), we show that pattern collapse behaviour of EUV-IL and EBL patterns is not only ruled by rigidity or strength of the resist but can be perfectly described with equation defining the unsticking of a non bending pattern. Finally by using surfactinated solution on sub-60nm dense patterns, great improvements in H c values and increase of process window latitude are shown. However, due to larger capillary force, this efficiency decreases with pattern pitch and appears limited on patterns width smaller than 40 nm.

  6. Interferometry in the Extreme Ultraviolet and X-Ray

    NASA Technical Reports Server (NTRS)

    Cash, W.; Shipley, A.; Osterman, S.; Joy, M. K.

    2000-01-01

    We report on demonstration of an x-ray interferometer that uses plane mirrors at grazing incidence to create interference fringes in the extreme ultraviolet and soft x-ray portions of the spectrum. X-ray interferometry has historically been implemented through narrow band, diffractive systems that split the wavefront. Our system, by using two separate optical channels to create interference from two areas of the wavefront, has broad band response and much higher efficiency. We discuss some applications of this technique to astronomy and microscopy including the possibility of eventually capturing a micro-arcsecond image of a black hole.

  7. A Triassic aquatic protorosaur with an extremely long neck.

    PubMed

    Li, Chun; Rieppel, Olivier; LaBarbera, Michael C

    2004-09-24

    By Middle Triassic time, a number of reptile lineages had diversified in shallow epicontinental seas and intraplatform basins along the margins of parts of Pangea, including the giraffe-necked protorosaurid reptile Tanystropheus from the Western Tethys (Europe and the Middle East), which grew to approximately 5 to 6 m long. Here we report another long-necked fossil, Dinocephalosaurus, from southwestern China, recently collected in Middle Triassic marine deposits approximately 230 million years old. This taxon represents unambiguous evidence for a fully aquatic protorosaur. Its extremely elongated neck is explained as an adaptation for aquatic life, perhaps for an increase in feeding efficiency.

  8. Changes in Concurrent Precipitation and Temperature Extremes

    DOE PAGESBeta

    Hao, Zengchao; AghaKouchak, Amir; Phillips, Thomas J.

    2013-08-01

    While numerous studies have addressed changes in climate extremes, analyses of concurrence of climate extremes are scarce, and climate change effects on joint extremes are rarely considered. This study assesses the occurrence of joint (concurrent) monthly continental precipitation and temperature extremes in Climate Research Unit (CRU) and University of Delaware (UD) observations, and in 13 Coupled Model Intercomparison Project Phase 5 (CMIP5) global climate simulations. Moreover, the joint occurrences of precipitation and temperature extremes simulated by CMIP5 climate models are compared with those derived from the CRU and UD observations for warm/wet, warm/dry, cold/wet, and cold/dry combinations of joint extremes.more » The number of occurrences of these four combinations during the second half of the 20th century (1951–2004) is assessed on a common global grid. CRU and UD observations show substantial increases in the occurrence of joint warm/dry and warm/wet combinations for the period 1978–2004 relative to 1951–1977. The results show that with respect to the sign of change in the concurrent extremes, the CMIP5 climate model simulations are in reasonable overall agreement with observations. The results reveal notable discrepancies between regional patterns and the magnitude of change in individual climate model simulations relative to the observations of precipitation and temperature.« less

  9. Extreme weather events and infectious disease outbreaks

    PubMed Central

    McMichael, Anthony J

    2015-01-01

    Human-driven climatic changes will fundamentally influence patterns of human health, including infectious disease clusters and epidemics following extreme weather events. Extreme weather events are projected to increase further with the advance of human-driven climate change. Both recent and historical experiences indicate that infectious disease outbreaks very often follow extreme weather events, as microbes, vectors and reservoir animal hosts exploit the disrupted social and environmental conditions of extreme weather events. This review article examines infectious disease risks associated with extreme weather events; it draws on recent experiences including Hurricane Katrina in 2005 and the 2010 Pakistan mega-floods, and historical examples from previous centuries of epidemics and ‘pestilence’ associated with extreme weather disasters and climatic changes. A fuller understanding of climatic change, the precursors and triggers of extreme weather events and health consequences is needed in order to anticipate and respond to the infectious disease risks associated with human-driven climate change. Post-event risks to human health can be constrained, nonetheless, by reducing background rates of persistent infection, preparatory action such as coordinated disease surveillance and vaccination coverage, and strengthened disaster response. In the face of changing climate and weather conditions, it is critically important to think in ecological terms about the determinants of health, disease and death in human populations. PMID:26168924

  10. Extreme weather events and infectious disease outbreaks.

    PubMed

    McMichael, Anthony J

    2015-01-01

    Human-driven climatic changes will fundamentally influence patterns of human health, including infectious disease clusters and epidemics following extreme weather events. Extreme weather events are projected to increase further with the advance of human-driven climate change. Both recent and historical experiences indicate that infectious disease outbreaks very often follow extreme weather events, as microbes, vectors and reservoir animal hosts exploit the disrupted social and environmental conditions of extreme weather events. This review article examines infectious disease risks associated with extreme weather events; it draws on recent experiences including Hurricane Katrina in 2005 and the 2010 Pakistan mega-floods, and historical examples from previous centuries of epidemics and 'pestilence' associated with extreme weather disasters and climatic changes. A fuller understanding of climatic change, the precursors and triggers of extreme weather events and health consequences is needed in order to anticipate and respond to the infectious disease risks associated with human-driven climate change. Post-event risks to human health can be constrained, nonetheless, by reducing background rates of persistent infection, preparatory action such as coordinated disease surveillance and vaccination coverage, and strengthened disaster response. In the face of changing climate and weather conditions, it is critically important to think in ecological terms about the determinants of health, disease and death in human populations. PMID:26168924

  11. Understanding hydrological extremes in the Anthropocene

    NASA Astrophysics Data System (ADS)

    Mård, Johanna; Di Baldassarre, Giuliano

    2016-04-01

    Hydrological extremes, from floods to droughts, pose one of the greatest challenges of the 21st century. Many of these challenges are associated with societal interactions with water, as people control or impact hydrological systems in a multitude of ways while they are also being affected and shaped by hydrological extremes, depending on their response to drought and flood events. However, the fact that the human and natural components of freshwater systems interact and co-evolve over time is often not taken into account. There is a need to study the two-way coupling between hydrology and society within a more comprehensive framework for hydrological extremes to anticipate future trajectories in a rapidly changing world. We present an interdisciplinary framework (and concepts) to identify internal controlling variables, processes and feedbacks, and the external system drivers and disturbances of the coupled human-water system with regard to hydrological extremes. To achieve this, the study (i) synthesizes existing research on coupled human-water system focusing on floods and droughts, (ii) analyzes hydrological extremes that have already occurred and their spatiotemporal patterns to investigate what patterns are observed in different regions of the world, and (iii) systematically describe the observed hydrological extremes, their causes and the interactions and feedbacks between hydrology and society. Advancing our understanding of mechanisms and feedbacks driving hydrological extremes is essential to better anticipate how the coupled human-water system will respond to future environmental change.

  12. Changes in Concurrent Precipitation and Temperature Extremes

    SciTech Connect

    Hao, Zengchao; AghaKouchak, Amir; Phillips, Thomas J.

    2013-08-01

    While numerous studies have addressed changes in climate extremes, analyses of concurrence of climate extremes are scarce, and climate change effects on joint extremes are rarely considered. This study assesses the occurrence of joint (concurrent) monthly continental precipitation and temperature extremes in Climate Research Unit (CRU) and University of Delaware (UD) observations, and in 13 Coupled Model Intercomparison Project Phase 5 (CMIP5) global climate simulations. Moreover, the joint occurrences of precipitation and temperature extremes simulated by CMIP5 climate models are compared with those derived from the CRU and UD observations for warm/wet, warm/dry, cold/wet, and cold/dry combinations of joint extremes. The number of occurrences of these four combinations during the second half of the 20th century (1951–2004) is assessed on a common global grid. CRU and UD observations show substantial increases in the occurrence of joint warm/dry and warm/wet combinations for the period 1978–2004 relative to 1951–1977. The results show that with respect to the sign of change in the concurrent extremes, the CMIP5 climate model simulations are in reasonable overall agreement with observations. The results reveal notable discrepancies between regional patterns and the magnitude of change in individual climate model simulations relative to the observations of precipitation and temperature.

  13. Extreme weather events and infectious disease outbreaks.

    PubMed

    McMichael, Anthony J

    2015-01-01

    Human-driven climatic changes will fundamentally influence patterns of human health, including infectious disease clusters and epidemics following extreme weather events. Extreme weather events are projected to increase further with the advance of human-driven climate change. Both recent and historical experiences indicate that infectious disease outbreaks very often follow extreme weather events, as microbes, vectors and reservoir animal hosts exploit the disrupted social and environmental conditions of extreme weather events. This review article examines infectious disease risks associated with extreme weather events; it draws on recent experiences including Hurricane Katrina in 2005 and the 2010 Pakistan mega-floods, and historical examples from previous centuries of epidemics and 'pestilence' associated with extreme weather disasters and climatic changes. A fuller understanding of climatic change, the precursors and triggers of extreme weather events and health consequences is needed in order to anticipate and respond to the infectious disease risks associated with human-driven climate change. Post-event risks to human health can be constrained, nonetheless, by reducing background rates of persistent infection, preparatory action such as coordinated disease surveillance and vaccination coverage, and strengthened disaster response. In the face of changing climate and weather conditions, it is critically important to think in ecological terms about the determinants of health, disease and death in human populations.

  14. 46 CFR 160.041-5 - Inspections and tests.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... and tests. (a) Accelerated weathering. The container without contents shall be exposed to ultra violet.... As an alternate to this test the container may be exposed to an ultra violet light for 100 hours...

  15. 16 CFR 305.3 - Description of covered products.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... transforms some of the ultra-violet energy generated by the mercury discharge into light, including only the... reprographic equipment; (vii) Lamps primarily designed to produce radiation in the ultra-violet region of...

  16. 46 CFR 160.041-5 - Inspections and tests.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... and tests. (a) Accelerated weathering. The container without contents shall be exposed to ultra violet.... As an alternate to this test the container may be exposed to an ultra violet light for 100 hours...

  17. 46 CFR 160.041-5 - Inspections and tests.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... and tests. (a) Accelerated weathering. The container without contents shall be exposed to ultra violet.... As an alternate to this test the container may be exposed to an ultra violet light for 100 hours...

  18. 46 CFR 160.041-5 - Inspections and tests.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... and tests. (a) Accelerated weathering. The container without contents shall be exposed to ultra violet.... As an alternate to this test the container may be exposed to an ultra violet light for 100 hours...

  19. 46 CFR 160.041-5 - Inspections and tests.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... and tests. (a) Accelerated weathering. The container without contents shall be exposed to ultra violet.... As an alternate to this test the container may be exposed to an ultra violet light for 100 hours...

  20. 16 CFR 305.3 - Description of covered products.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... transforms some of the ultra-violet energy generated by the mercury discharge into light, including only the... reprographic equipment; (vii) Lamps primarily designed to produce radiation in the ultra-violet region of...

  1. Fault Tolerant Magnetic Bearing Testing and Conical Magnetic Bearing Development for Extreme Temperature Environments

    NASA Technical Reports Server (NTRS)

    Keith, Theo G., Jr.; Clark, Daniel

    2004-01-01

    During the six month tenure of the grant, activities included continued research of hydrostatic bearings as a viable backup-bearing solution for a magnetically levitated shaft system in extreme temperature environments (1000 F), developmental upgrades of the fault-tolerant magnetic bearing rig at the NASA Glenn Research Center, and assisting in the development of a conical magnetic bearing for extreme temperature environments, particularly turbomachinery. It leveraged work from the ongoing Smart Efficient Components (SEC) and the Turbine-Based Combined Cycle (TBCC) program at NASA Glenn Research Center. The effort was useful in providing technology for more efficient and powerful gas turbine engines.

  2. Magnetic Reconnection in Extreme Astrophysical Environments

    NASA Astrophysics Data System (ADS)

    Uzdensky, Dmitri

    -positron pairs. The pairs make the reconnection layer optically thick, efficiently trapping gamma-ray photons and ensuring a local thermodynamic equilibrium between the radiation and the plasma. The plasma pressure inside the layer is then dominated by the radiation and pair pressure. At the same time, the timescale for radiation diffusion across the layer may still be much shorter than the global Alfven transit time along the layer, and hence the effects of radiative cooling on the thermodynamics of the layer need to be taken into account. In other words, the reconnection problem in this regime necessarily becomes a radiative transfer problem. In addition, the extremely high pair density, set by the local ther-modynamic equilibrium essentially independently of the upstream plasma density, can make the reconnection layer highly collisional, thereby justifying the use of resistive MHD (with Spitzer and Compton resistivities). The presence of all these processes calls for a substantial revision of our traditional physical picture of reconnection when applied to these environments. I will de-scribe how the corresponding new theory of reconnection of magnetar-strength magnetic fields ought to be constructed and will conclude by discussing its observational consequences and the prospects for future research.

  3. Astronomy and the Extreme Ultraviolet Explorer satellite.

    PubMed

    Bowyer, S

    1994-01-01

    The extreme ultraviolet wave band (100 to 912 angstroms) was thought until recently to be useless to astronomy, primarily because the opacity of the interstellar medium would prevent observations at these wavelengths. However, the interstellar medium has been found to be markedly inhomogeneous in both density and ionization state and the sun is fortunately located in a region of low extreme ultraviolet opacity. The Extreme Ultraviolet Explorer, launched in June 1992, has surveyed the sky in this wave band and has detected a wide variety of astronomical sources at considerable distances, including some extragalactic objects. Studies in the extreme ultraviolet band have already begun to increase our understanding of the contents of the universe.

  4. Controlling extreme events on complex networks.

    PubMed

    Chen, Yu-Zhong; Huang, Zi-Gang; Lai, Ying-Cheng

    2014-01-01

    Extreme events, a type of collective behavior in complex networked dynamical systems, often can have catastrophic consequences. To develop effective strategies to control extreme events is of fundamental importance and practical interest. Utilizing transportation dynamics on complex networks as a prototypical setting, we find that making the network "mobile" can effectively suppress extreme events. A striking, resonance-like phenomenon is uncovered, where an optimal degree of mobility exists for which the probability of extreme events is minimized. We derive an analytic theory to understand the mechanism of control at a detailed and quantitative level, and validate the theory numerically. Implications of our finding to current areas such as cybersecurity are discussed. PMID:25131344

  5. Controlling extreme events on complex networks

    PubMed Central

    Chen, Yu-Zhong; Huang, Zi-Gang; Lai, Ying-Cheng

    2014-01-01

    Extreme events, a type of collective behavior in complex networked dynamical systems, often can have catastrophic consequences. To develop effective strategies to control extreme events is of fundamental importance and practical interest. Utilizing transportation dynamics on complex networks as a prototypical setting, we find that making the network “mobile” can effectively suppress extreme events. A striking, resonance-like phenomenon is uncovered, where an optimal degree of mobility exists for which the probability of extreme events is minimized. We derive an analytic theory to understand the mechanism of control at a detailed and quantitative level, and validate the theory numerically. Implications of our finding to current areas such as cybersecurity are discussed. PMID:25131344

  6. NASA Measures Extreme Precipitation From Space

    NASA Video Gallery

    From Jan. 25 through Feb. 3, IMERG data estimated that the most extreme precipitation over the United States during this period was over 200mm (7.9 inches) in an area where stormy weather frequentl...

  7. Characteristics of Extreme Auroral Charging Events

    NASA Technical Reports Server (NTRS)

    Minow, Joseph I.; Willis, Emily; Parker, Linda Neergaard

    2014-01-01

    Today’s presentation describes preliminary results from a study of extreme auroral charging in low Earth orbit. Goal of study is to document characteristics of auroral charging events of importance to spacecraft design, operations, and anomaly investigations.

  8. Extreme space weather studies: Addressing societal needs

    NASA Astrophysics Data System (ADS)

    Ngwira, C. M.

    2014-12-01

    Extreme space weather events can adversely impact the operations of critical modern-day technological infrastructure such as high-voltage electric power transmission grids. Understanding of coupled magnetosphere-ionosphere dynamics under extreme solar wind driving conditions is still a major challenge mainly because of a lack of data during such time intervals. This presentation will highlight some of the past and on-going investigations on extreme space weather events, and how these investigations are used to address societal needs. Particularly, I will describe how first principles physics-based 3-D global MHD models are playing a major role in advancing our knowledge on extreme geomagnetically induced currents. These MHD models represent a very important component of attempts to understand the response of the magnetosphere-ionosphere system to varying solar wind conditions.

  9. Extremal dynamics and punctuated co-evolution

    NASA Astrophysics Data System (ADS)

    Sneppen, Kim

    1995-02-01

    Extremal dynamics opens up a new way for understanding the coherence that is observed in some large non-equilibrium systems. Extremal dynamics is characterized by quasistatic motion where only one part of the large system is active at a given instant: the part where a local variable assumes a global extremum value. Extremal dynamics may apply when the parts of the system nearly always are caught in metastable states. Examples from physics may include earthquakes, fluid invasion in porous media and possibly also dynamical roughening of interfaces. We discuss a simple model of extremal dynamics and its application to biological macroevolution. The model can be formulated as an ecology of adapting interacting species. The environment of any given species is affected by other species; hence it may change with time. For low mutation rate the model ecology expands at a self-organized critical state where periods of statis alternate with avalanches of evolutionary changes.

  10. Astronomy and the Extreme Ultraviolet Explorer satellite

    NASA Technical Reports Server (NTRS)

    Bowyer, S.

    1994-01-01

    The extreme ultraviolet wave band (100 to 912 angstroms) was thought until recently to be useless to astronomy, primarily because the opacity of the interstellar medium would prevent observations at these wavelengths. However, the interstellar medium has been found to be markedly inhomogeneous in both density and ionization state and the sun is fortunately located in a region of low extreme ultraviolet opacity. The Extreme Ultraviolet Explorer, launched in June 1992, has surveyed the sky in this wave band and has detected a wide variety of astronomical sources at considerable distances, including some extragalactic objects. Studies in the extreme ultraviolet band have already begun to increase our understanding of the contents of the universe.

  11. A Millennial Challenge: Extremism in Uncertain Times

    PubMed Central

    Fiske, Susan T.

    2014-01-01

    This comment highlights the relevance and importance of the uncertainty-extremism topic, both scientifically and societally, identifies common themes, locates this work in a wider scientific and social context, describes what we now know and what we still do not, acknowledges some limitations, foreshadowing future directions, and discusses some potential policy relevance. Common themes emerge around the importance of social justice as sound anti-extremism policy. PMID:24511155

  12. EXTREME VALUE THEORY WITH OPERATOR NORMING

    PubMed Central

    MEERSCHAERT, MARK M.; SCHEFFLER, HANS-PETER; STOEV, STILIAN A.

    2013-01-01

    A new approach to extreme value theory is presented for vector data with heavy tails. The tail index is allowed to vary with direction, where the directions are not necessarily along the coordinate axes. Basic asymptotic theory is developed, using operator regular variation and extremal integrals. A test is proposed to judge whether the tail index varies with direction in any given data set. PMID:24443640

  13. Test fields cannot destroy extremal black holes

    NASA Astrophysics Data System (ADS)

    Natário, José; Queimada, Leonel; Vicente, Rodrigo

    2016-09-01

    We prove that (possibly charged) test fields satisfying the null energy condition at the event horizon cannot overspin/overcharge extremal Kerr–Newman or Kerr–Newman–anti de Sitter black holes, that is, the weak cosmic censorship conjecture cannot be violated in the test field approximation. The argument relies on black hole thermodynamics (without assuming cosmic censorship), and does not depend on the precise nature of the fields. We also discuss generalizations of this result to other extremal black holes.

  14. Flexible diaphragm-extreme temperature usage

    NASA Technical Reports Server (NTRS)

    Lerma, Guillermo (Inventor)

    1991-01-01

    A diaphragm suitable for extreme temperature usage, such as encountered in critical aerospace applications, is fabricated by a unique method, and of a unique combination of materials. The materials include multilayered lay-ups of diaphragm materials sandwiched between layers of bleeder fabrics. After being formed in the desired shape on a mold, they are vacuum sealed and then cured under pressure, in a heated autoclave. A bond capable of withstanding extreme temperatures are produced.

  15. Updating upper extremity temporary prosthesis: thermoplastics.

    PubMed

    Fletchall, S; Tran, T; Ungaro, V; Hickerson, W

    1992-01-01

    Since 1989 amputees with upper-extremity burns have been fitted with a temporary prosthesis fabricated from low-temperature thermoplastic. Before 1989 conventional temporary prostheses were fabricated with plaster. The use of the thermoplastic material has produced a lightweight, cost-effective, modular system. No patients exhibited skin breakdown with the thermoplastic material. It appears that thermoplastics may be the next major breakthrough in terms of a design for a temporary upper-extremity prosthesis.

  16. A Millennial Challenge: Extremism in Uncertain Times.

    PubMed

    Fiske, Susan T

    2013-09-01

    This comment highlights the relevance and importance of the uncertainty-extremism topic, both scientifically and societally, identifies common themes, locates this work in a wider scientific and social context, describes what we now know and what we still do not, acknowledges some limitations, foreshadowing future directions, and discusses some potential policy relevance. Common themes emerge around the importance of social justice as sound anti-extremism policy. PMID:24511155

  17. Preconditioned iterations to calculate extreme eigenvalues

    SciTech Connect

    Brand, C.W.; Petrova, S.

    1994-12-31

    Common iterative algorithms to calculate a few extreme eigenvalues of a large, sparse matrix are Lanczos methods or power iterations. They converge at a rate proportional to the separation of the extreme eigenvalues from the rest of the spectrum. Appropriate preconditioning improves the separation of the eigenvalues. Davidson`s method and its generalizations exploit this fact. The authors examine a preconditioned iteration that resembles a truncated version of Davidson`s method with a different preconditioning strategy.

  18. Test fields cannot destroy extremal black holes

    NASA Astrophysics Data System (ADS)

    Natário, José; Queimada, Leonel; Vicente, Rodrigo

    2016-09-01

    We prove that (possibly charged) test fields satisfying the null energy condition at the event horizon cannot overspin/overcharge extremal Kerr-Newman or Kerr-Newman-anti de Sitter black holes, that is, the weak cosmic censorship conjecture cannot be violated in the test field approximation. The argument relies on black hole thermodynamics (without assuming cosmic censorship), and does not depend on the precise nature of the fields. We also discuss generalizations of this result to other extremal black holes.

  19. Prevention of Lower Extremity Injuries in Basketball

    PubMed Central

    Taylor, Jeffrey B.; Ford, Kevin R.; Nguyen, Anh-Dung; Terry, Lauren N.; Hegedus, Eric J.

    2015-01-01

    Context: Lower extremity injuries are common in basketball, yet it is unclear how prophylactic interventions affect lower extremity injury incidence rates. Objective: To analyze the effectiveness of current lower extremity injury prevention programs in basketball athletes, focusing on injury rates of (1) general lower extremity injuries, (2) ankle sprains, and (3) anterior cruciate ligament (ACL) tears. Data Sources: PubMed, MEDLINE, CINAHL, SPORTDiscus, and the Cochrane Register of Controlled Trials were searched in January 2015. Study Selection: Studies were included if they were randomized controlled or prospective cohort trials, contained a population of competitive basketball athletes, and reported lower extremity injury incidence rates specific to basketball players. In total, 426 individual studies were identified. Of these, 9 met the inclusion criteria. One other study was found during a hand search of the literature, resulting in 10 total studies included in this meta-analysis. Study Design: Systematic review and meta-analysis. Level of Evidence: Level 2. Data Extraction: Details of the intervention (eg, neuromuscular vs external support), size of control and intervention groups, and number of injuries in each group were extracted from each study. Injury data were classified into 3 groups based on the anatomic diagnosis reported (general lower extremity injury, ankle sprain, ACL rupture). Results: Meta-analyses were performed independently for each injury classification. Results indicate that prophylactic programs significantly reduced the incidence of general lower extremity injuries (odds ratio [OR], 0.69; 95% CI, 0.57-0.85; P < 0.001) and ankle sprains (OR, 0.45; 95% CI, 0.29-0.69; P < 0.001), yet not ACL ruptures (OR, 1.09; 95% CI, 0.36-3.29; P = 0.87) in basketball athletes. Conclusion: In basketball players, prophylactic programs may be effective in reducing the risk of general lower extremity injuries and ankle sprains, yet not ACL injuries. PMID

  20. Extreme Ultraviolet Explorer Bright Source List

    NASA Technical Reports Server (NTRS)

    Malina, Roger F.; Marshall, Herman L.; Antia, Behram; Christian, Carol A.; Dobson, Carl A.; Finley, David S.; Fruscione, Antonella; Girouard, Forrest R.; Hawkins, Isabel; Jelinsky, Patrick

    1994-01-01

    Initial results from the analysis of the Extreme Ultraviolet Explorer (EUVE) all-sky survey (58-740 A) and deep survey (67-364 A) are presented through the EUVE Bright Source List (BSL). The BSL contains 356 confirmed extreme ultraviolet (EUV) point sources with supporting information, including positions, observed EUV count rates, and the identification of possible optical counterparts. One-hundred twenty-six sources have been detected longward of 200 A.

  1. A spatial hybrid approach for downscaling of extreme precipitation fields

    NASA Astrophysics Data System (ADS)

    Bechler, Aurélien; Vrac, Mathieu; Bel, Liliane

    2015-05-01

    For a few decades, climate models are used to provide future scenarios of precipitation with increasingly higher spatial resolution. However, this resolution is not yet sufficient to describe efficiently what happens at local scale. Dynamical and statistical methods of downscaling have been developed and allow us to make the link between two levels of resolution and enable us to get values at a local scale based on large-scale information from global or regional climate models. Nevertheless, both the extreme behavior and the spatial structures are not well described by these downscaling methods. We propose a two-step methodology, called spatial hybrid downscaling (SHD), to solve this problem. The first step consists in applying a univariate (i.e., one-dimensional) statistical downscaling to link the high- and low-resolution variables at some given locations. Once this 1d-link is performed, a conditional simulation algorithm of max-stable processes adapted to the extremal t process enables us to get conditional distributions of extreme precipitation at any point of the region. An application is performed on precipitation data in the south of France where extreme (Cevenol) events have major impacts (e.g., floods). Different versions of the SHD approach are tested. Most of them show particularly good results regarding univariate and multivariate criteria and overcome classical downscaling techniques tested in comparison. Furthermore, these conclusions are robust to the choice of the 1d-link functions tested and to the choice of the conditioning points to drive the conditional local-scale simulations performed by the SHD approach.

  2. Evaluating environmental joint extremes for the offshore industry using the conditional extremes model

    NASA Astrophysics Data System (ADS)

    Ewans, Kevin; Jonathan, Philip

    2014-02-01

    Understanding extreme ocean environments and their interaction with fixed and floating structures is critical for the design of offshore and coastal facilities. The joint effect of various ocean variables on extreme responses of offshore structures is fundamental in determining the design loads. For example, it is known that mean values of wave periods tend to increase with increasing storm intensity, and a floating system responds in a complex way to both variables. Specification of joint extremes in design criteria has often been somewhat ad hoc, being based on fairly arbitrary combinations of extremes of variables estimated independently. Such approaches are even outlined in design guidelines. Mathematically more consistent estimates of the joint occurrence of extreme environmental variables fall into two camps in the offshore industry - response-based and response-independent. Both are outlined here, with emphasis on response-independent methods, particularly those based on the conditional extremes model recently introduced by (Heffernan and Tawn, 2004), which has a solid theoretical motivation. We illustrate an application of the conditional extremes model to joint estimation of extreme storm peak significant wave height and peak period at a northern North Sea location, incorporating storm direction as a model covariate. We also discuss joint estimation of extreme current profiles with depth off the North West Shelf of Australia. Methods such as the conditional extremes model provide valuable additions to the metocean engineer's toolkit.

  3. Predictability of extreme values in geophysical models

    NASA Astrophysics Data System (ADS)

    Sterk, Alef; Holland, Mark; Rabassa, Pau; Broer, Henk; Vitolo, Renato

    2014-05-01

    Classical extreme value theory studies the occurrence of unlikely large events. Extreme value theory was originally developed for time series of near-independent random variables, but in the last decade the theory has been extended to the setting of chaotic, deterministic dynamical systems. In the latter context one studies the distribution of large values in a time series generated by evaluating a scalar observable along evolutions of the system. We have studied the finite-time predictability of extreme values, such as convection, energy, and wind speeds, in three geophysical models. To that end we computed finite-time Lyapunov exponents (FTLEs) which measure the exponential growth rate of nearby trajectories over a finite time. In general, FTLEs strongly depend on the initial condition. We study whether initial conditions leading to extremes typically have a larger or smaller FTLE. Our study clearly suggests that general statements about the predictability of extreme values are not possible: the predictability of extreme values depends on (1) the observable, (2) the attractor of the system, and (3) the prediction lead time.

  4. Acclimatization and tolerance to extreme altitude

    NASA Technical Reports Server (NTRS)

    West, J. B.

    1993-01-01

    During the last ten years, two major experiments have elucidated the factors determining acclimatization and tolerance to extreme altitude (over 7000 m). These were the American Medical Research Expedition to Everest, and the low pressure chamber simulation, Operation Everest II. Extreme hyperventilation is one of the most important responses to extreme altitude. Its chief value is that it allows the climber to maintain an alveolar PO2 which keeps the arterial PO2 above dangerously low levels. Even so, there is evidence of residual impairment of central nervous system function after ascents to extreme altitude, and maximal oxygen consumption falls precipitously above 7000 m. The term 'acclimatization' is probably not appropriate for altitudes above 8000 m, because the body steadily deteriorates at these altitudes. Tolerance to extreme altitude is critically dependent on barometric pressure, and even seasonal changes in pressure probably affect climbing performance near the summit of Mt Everest. Supplementary oxygen always improves exercise tolerance at extreme altitudes, and rescue oxygen should be available on climbing expeditions to 8000 m peaks.

  5. Energetic Extremes in Aquatic Locomotion by Coral Reef Fishes

    PubMed Central

    Fulton, Christopher J.; Johansen, Jacob L.; Steffensen, John F.

    2013-01-01

    Underwater locomotion is challenging due to the high friction and resistance imposed on a body moving through water and energy lost in the wake during undulatory propulsion. While aquatic organisms have evolved streamlined shapes to overcome such resistance, underwater locomotion has long been considered a costly exercise. Recent evidence for a range of swimming vertebrates, however, has suggested that flapping paired appendages around a rigid body may be an extremely efficient means of aquatic locomotion. Using intermittent flow-through respirometry, we found exceptional energetic performance in the Bluelined wrasse Stethojulis bandanensis, which maintains tuna-like optimum cruising speeds (up to 1 metre s−1) while using 40% less energy than expected for their body size. Displaying an exceptional aerobic scope (22-fold above resting), streamlined rigid-body posture, and wing-like fins that generate lift-based thrust, S. bandanensis literally flies underwater to efficiently maintain high optimum swimming speeds. Extreme energetic performance may be key to the colonization of highly variable environments, such as the wave-swept habitats where S. bandanensis and other wing-finned species tend to occur. Challenging preconceived notions of how best to power aquatic locomotion, biomimicry of such lift-based fin movements could yield dramatic reductions in the power needed to propel underwater vehicles at high speed. PMID:23326566

  6. Evaluation of Advanced COTS Passive Devices for Extreme Temperature Operation

    NASA Technical Reports Server (NTRS)

    Patterson, Richard; Hammoud, Ahmad; Dones, Keishla R.

    2009-01-01

    Electronic sensors and circuits are often exposed to extreme temperatures in many of NASA deep space and planetary surface exploration missions. Electronics capable of operation in harsh environments would be beneficial as they simplify overall system design, relax thermal management constraints, and meet operational requirements. For example, cryogenic operation of electronic parts will improve reliability, increase energy density, and extend the operational lifetimes of space-based electronic systems. Similarly, electronic parts that are able to withstand and operate efficiently in high temperature environments will negate the need for thermal control elements and their associated structures, thereby reducing system size and weight, enhancing its reliability, improving its efficiency, and reducing cost. Passive devices play a critical role in the design of almost all electronic circuitry. To address the needs of systems for extreme temperature operation, some of the advanced and most recently introduced commercial-off-the-shelf (COTS) passive devices, which included resistors and capacitors, were examined for operation under a wide temperature regime. The types of resistors investigated included high temperature precision film, general purpose metal oxide, and wirewound.

  7. Climate extremes in the Pacific: improving seasonal prediction of tropical cyclones and extreme ocean temperatures to improve resilience

    NASA Astrophysics Data System (ADS)

    Kuleshov, Y.; Jones, D.; Spillman, C. M.

    2012-04-01

    Climate change and climate extremes have a major impact on Australia and Pacific Island countries. Of particular concern are tropical cyclones and extreme ocean temperatures, the first being the most destructive events for terrestrial systems, while the latter has the potential to devastate ocean ecosystems through coral bleaching. As a practical response to climate change, under the Pacific-Australia Climate Change Science and Adaptation Planning program (PACCSAP), we are developing enhanced web-based information tools for providing seasonal forecasts for climatic extremes in the Western Pacific. Tropical cyclones are the most destructive weather systems that impact on coastal areas. Interannual variability in the intensity and distribution of tropical cyclones is large, and presently greater than any trends that are ascribable to climate change. In the warming environment, predicting tropical cyclone occurrence based on historical relationships, with predictors such as sea surface temperatures (SSTs) now frequently lying outside of the range of past variability meaning that it is not possible to find historical analogues for the seasonal conditions often faced by Pacific countries. Elevated SSTs are the primary trigger for mass coral bleaching events, which can lead to widespread damage and mortality on reef systems. Degraded coral reefs present many problems, including long-term loss of tourism and potential loss or degradation of fisheries. The monitoring and prediction of thermal stress events enables the support of a range of adaptive and management activities that could improve reef resilience to extreme conditions. Using the climate model POAMA (Predictive Ocean-Atmosphere Model for Australia), we aim to improve accuracy of seasonal forecasts of tropical cyclone activity and extreme SSTs for the regions of Western Pacific. Improved knowledge of extreme climatic events, with the assistance of tailored forecast tools, will help enhance the resilience and

  8. Neurodevelopmental problems and extremes in BMI

    PubMed Central

    Tajnia, Armin; Lichtenstein, Paul; Lundström, Sebastian; Anckarsäter, Henrik; Nilsson, Thomas; Råstam, Maria

    2015-01-01

    Background. Over the last few decades, an increasing number of studies have suggested a connection between neurodevelopmental problems (NDPs) and body mass index (BMI). Attention deficit/hyperactivity disorder (ADHD) and autism spectrum disorders (ASD) both seem to carry an increased risk for developing extreme BMI. However, the results are inconsistent, and there have been only a few studies of the general population of children. Aims. We had three aims with the present study: (1) to define the prevalence of extreme (low or high) BMI in the group of children with ADHD and/or ASDs compared to the group of children without these NDPs; (2) to analyze whether extreme BMI is associated with the subdomains within the diagnostic categories of ADHD or ASD; and (3) to investigate the contribution of genetic and environmental factors to BMI in boys and girls at ages 9 and 12. Method. Parents of 9- or 12-year-old twins (n = 12,496) were interviewed using the Autism—Tics, ADHD and other Comorbidities (A-TAC) inventory as part of the Child and Adolescent Twin Study in Sweden (CATSS). Univariate and multivariate generalized estimated equation models were used to analyze associations between extremes in BMI and NDPs. Results. ADHD screen-positive cases followed BMI distributions similar to those of children without ADHD or ASD. Significant association was found between ADHD and BMI only among 12-year-old girls, where the inattention subdomain of ADHD was significantly associated with the high extreme BMI. ASD scores were associated with both the low and the high extremes of BMI. Compared to children without ADHD or ASD, the prevalence of ASD screen-positive cases was three times greater in the high extreme BMI group and double as much in the low extreme BMI group. Stereotyped and repetitive behaviors were significantly associated with high extreme BMIs. Conclusion. Children with ASD, with or without coexisting ADHD, are more prone to have low or high extreme BMIs than children

  9. The Pace of Perceivable Extreme Climate Change

    NASA Astrophysics Data System (ADS)

    Tan, X.; Gan, T. Y.

    2015-12-01

    When will the signal of obvious changes in extreme climate emerge over climate variability (Time of Emergence, ToE) is a key question for planning and implementing measures to mitigate the potential impact of climate change to natural and human systems that are generally adapted to potential changes from current variability. We estimated ToEs for the magnitude, duration and frequency of global extreme climate represented by 24 extreme climate indices (16 for temperature and 8 for precipitation) with different thresholds of the signal-to-noise (S/N) ratio based on projections of CMIP5 global climate models under RCP8.5 and RCP4.5 for the 21st century. The uncertainty of ToE is assessed by using 3 different methods to calculate S/N for each extreme index. Results show that ToEs of the projected extreme climate indices based on the RCP4.5 climate scenarios are generally projected to happen about 20 years later than that for the RCP8.5 climate scenarios. Under RCP8.5, the projected magnitude, duration and frequency of extreme temperature on Earth will all exceed 2 standard deviations by 2100, and the empirical 50th percentile of the global ToE for the frequency and magnitude of hot (cold) extreme are about 2040 and 2054 (2064 and 2054) for S/N > 2, respectively. The 50th percentile of global ToE for the intensity of extreme precipitation is about 2030 and 2058 for S/N >0.5 and S/N >1, respectively. We further evaluated the exposure of ecosystems and human societies to the pace of extreme climate change by determining the year of ToE for various extreme climate indices projected to occur over terrestrial biomes, marine realms and major urban areas with large populations. This was done by overlaying terrestrial, ecoregions and population maps with maps of ToE derived, to extract ToEs for these regions. Possible relationships between GDP per person and ToE are also investigated by relating the mean ToE for each country and its average value of GDP per person.

  10. Addressing Extremes within the WCRP - GEWEX Framework

    NASA Astrophysics Data System (ADS)

    van Oevelen, P. J.; Stewart, R.; Detemmerman, V.

    2008-12-01

    For large international coordination programs such as the Global Energy and Water Cycle Experiment (GEWEX) as part of the World Climate Research Programme (WCRP) it is difficult to strike a good balance between enabling as much international involvement as is possible and desirable and the achievability of the objectives. WCRP has decided that "Extremes Research" is one of several areas where it would like to see its efforts strengthened and scientific research pushed forward. The foci that are being selected should be phrased such that they are practical and achievable within a time span of 1 to 3 years. Preferably these foci build upon the expertise from cross WCRP activities and are not restricted to single core project activities. In this presentation an overview will be given of the various activities within GEWEX that are related to extremes and which ones would be most ideal to be addressed as WCRP foci from a GEWEX perspective. The rationale and context of extreme research will be presented as well links to other national and international programs. "Extremes Research" as a topic is attractive since it has a high societal relevance and impact. However, numerous definitions of extremes exist and they are being used in widely varying contexts making it not always clear of what exactly is being addressed. This presentation will give an outlook on what can be expected research wise in the near future based upon the outcomes of the Extremes Workshop organised last June in Vancouver in the context of the Coordinated Energy and water cycle Observations Project (CEOP) as part of GEWEX. In particular it will be shown how these activities, which will only address certain types of extremes, can be linked to adaptation and mitigation efforts taking place in other organisations and by national and international bodies.

  11. Eukaryotic diversity at pH extremes.

    PubMed

    Amaral-Zettler, Linda A

    2012-01-01

    Extremely acidic (pH < 3) and extremely alkaline (pH > 9) environments support a diversity of single-cell and to a lesser extent, multicellular eukaryotic life. This study compared alpha and beta diversity in eukaryotic communities from seven diverse aquatic environments with pH values ranging from 2 to 11 using massively-parallel pyrotag sequencing targeting the V9 hypervariable region of the 18S ribosomal RNA (rRNA) gene. A total of 946 operational taxonomic units (OTUs) were recovered at a 6% cut-off level (94% similarity) across the sampled environments. Hierarchical clustering of the samples segregated the communities into acidic and alkaline groups. Similarity percentage (SIMPER) analysis followed by indicator OTU analysis (IOA) and non-metric multidimensional scaling (NMDS) were used to determine which characteristic groups of eukaryotic taxa typify acidic or alkaline extremes and the extent to which pH explains eukaryotic community structure in these environments. Spain's Rio Tinto yielded the fewest observed OTUs while Nebraska Sandhills alkaline lakes yielded the most. Distinct OTUs, including metazoan OTUs, numerically dominated pH extreme sites. Indicator OTUs included the diatom Pinnularia and unidentified opisthokonts (Fungi and Filasterea) in the extremely acidic environments, and the ciliate Frontonia across the extremely alkaline sites. Inferred from NMDS, pH explained only a modest fraction of the variation across the datasets, indicating that other factors influence the underlying community structure in these environments. The findings from this study suggest that the ability for eukaryotes to adapt to pH extremes over a broad range of values may be rare, but further study of taxa that can broadly adapt across diverse acidic and alkaline environments, respectively present good models for understanding adaptation and should be targeted for future investigations.

  12. Eukaryotic diversity at pH extremes

    PubMed Central

    Amaral-Zettler, Linda A.

    2013-01-01

    Extremely acidic (pH < 3) and extremely alkaline (pH > 9) environments support a diversity of single-cell and to a lesser extent, multicellular eukaryotic life. This study compared alpha and beta diversity in eukaryotic communities from seven diverse aquatic environments with pH values ranging from 2 to 11 using massively-parallel pyrotag sequencing targeting the V9 hypervariable region of the 18S ribosomal RNA (rRNA) gene. A total of 946 operational taxonomic units (OTUs) were recovered at a 6% cut-off level (94% similarity) across the sampled environments. Hierarchical clustering of the samples segregated the communities into acidic and alkaline groups. Similarity percentage (SIMPER) analysis followed by indicator OTU analysis (IOA) and non-metric multidimensional scaling (NMDS) were used to determine which characteristic groups of eukaryotic taxa typify acidic or alkaline extremes and the extent to which pH explains eukaryotic community structure in these environments. Spain's Rio Tinto yielded the fewest observed OTUs while Nebraska Sandhills alkaline lakes yielded the most. Distinct OTUs, including metazoan OTUs, numerically dominated pH extreme sites. Indicator OTUs included the diatom Pinnularia and unidentified opisthokonts (Fungi and Filasterea) in the extremely acidic environments, and the ciliate Frontonia across the extremely alkaline sites. Inferred from NMDS, pH explained only a modest fraction of the variation across the datasets, indicating that other factors influence the underlying community structure in these environments. The findings from this study suggest that the ability for eukaryotes to adapt to pH extremes over a broad range of values may be rare, but further study of taxa that can broadly adapt across diverse acidic and alkaline environments, respectively present good models for understanding adaptation and should be targeted for future investigations. PMID:23335919

  13. Conditional simulations for fields of extreme precipitation

    NASA Astrophysics Data System (ADS)

    Bechler, Aurélien; Vrac, Mathieu; Bel, Liliane

    2014-05-01

    Many environmental models, such as hydrological models, require input data, e.g. precipitation values, correctly simulated and distributed, even at locations where no observation is available. This is particularly true for extreme events that may be of high importance for impact studies. The last decade has seen max-stable processes emerge as a powerful tool for the statistical modeling of spatial extremes. Recently, such processes have been used in climate context to perform simulations at ungauged sites based on empirical distributions of a spatial field conditioned by observed values in some locations. In this work conditional simulations of extremal t process are investigated, taking benefits of its spectral construction. The methodology of conditional simulations proposed by Dombry et al. [2013] for Brown-Resnick and Schlather models is adapted for the extremal t process with some improvements which enlarge the possible number of conditional points. A simulation study enables to highlight the role of the different parameters of the model and to emphasize the importance of the steps of the algorithm. In this work, we focus on the French Mediterranean basin, which is a key spot of occurrences of meteorological extremes such as heavy precipitation. Indeed, major extreme precipitation are regularly observed in this region near the 'cévenol" mountains. The modeling and the understanding of these extreme precipitation - the so-called 'cévenol events" - are of major importance for hydrological studies in this complex terrain since they often trigger major floods in this region. The application of our methodology on real data in this region shows that the model and the algorithm perform well provided the stationary assumptions are fulfilled.

  14. 49 CFR 178.509 - Standards for plastic drums and jerricans.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... substance contained or by ultra-violet radiation. Any permeation of the substance contained may not constitute a danger under normal conditions of transport. (2) If protection against ultra-violet radiation is... ultra-violet radiation is not limited. (3) Additives serving purposes other than protection...

  15. 49 CFR 178.509 - Standards for plastic drums and jerricans.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... substance contained or by ultra-violet radiation. Any permeation of the substance contained may not constitute a danger under normal conditions of transport. (2) If protection against ultra-violet radiation is... ultra-violet radiation is not limited. (3) Additives serving purposes other than protection...

  16. 49 CFR 178.509 - Standards for plastic drums and jerricans.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... substance contained or by ultra-violet radiation. Any permeation of the substance contained may not constitute a danger under normal conditions of transport. (2) If protection against ultra-violet radiation is... ultra-violet radiation is not limited. (3) Additives serving purposes other than protection...

  17. 49 CFR 178.517 - Standards for plastic boxes.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... substance contained or by ultra-violet radiation. (2) An expanded plastic box must consist of two parts made... plastic boxes, protection against ultra-violet radiation, if required, must be provided by the addition of... percent by mass; the content of inhibitors of ultra-violet radiation is not limited. (5) Additives...

  18. 49 CFR 178.517 - Standards for plastic boxes.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... substance contained or by ultra-violet radiation. (2) An expanded plastic box must consist of two parts made... plastic boxes, protection against ultra-violet radiation, if required, must be provided by the addition of... percent by mass; the content of inhibitors of ultra-violet radiation is not limited. (5) Additives...

  19. 49 CFR 178.517 - Standards for plastic boxes.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... substance contained or by ultra-violet radiation. (2) An expanded plastic box must consist of two parts made... plastic boxes, protection against ultra-violet radiation, if required, must be provided by the addition of... percent by mass; the content of inhibitors of ultra-violet radiation is not limited. (5) Additives...

  20. 49 CFR 178.517 - Standards for plastic boxes.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... substance contained or by ultra-violet radiation. (2) An expanded plastic box must consist of two parts made... plastic boxes, protection against ultra-violet radiation, if required, must be provided by the addition of... percent by mass; the content of inhibitors of ultra-violet radiation is not limited. (5) Additives...

  1. 49 CFR 178.517 - Standards for plastic boxes.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... substance contained or by ultra-violet radiation. (2) An expanded plastic box must consist of two parts made... plastic boxes, protection against ultra-violet radiation, if required, must be provided by the addition of... percent by mass; the content of inhibitors of ultra-violet radiation is not limited. (5) Additives...

  2. 77 FR 61600 - Certain New Chemicals; Receipt and Status Information

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-10

    ........... 08/30/2012 11/27/2012 CBI (G) Synergist for (G) Ultra violet ultra violet curable acrylated curable...-12-0345 08/23/2012 08/20/2012 (G) Ultra violet-curable urethane acrylate. P-12-0362 08/31/2012...

  3. 49 CFR 178.509 - Standards for plastic drums and jerricans.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... substance contained or by ultra-violet radiation. Any permeation of the substance contained may not constitute a danger under normal conditions of transport. (2) If protection against ultra-violet radiation is... ultra-violet radiation is not limited. (3) Additives serving purposes other than protection...

  4. Atmosphere and water loss from early Mars under extreme solar wind and extreme ultraviolet conditions.

    PubMed

    Terada, Naoki; Kulikov, Yuri N; Lammer, Helmut; Lichtenegger, Herbert I M; Tanaka, Takashi; Shinagawa, Hiroyuki; Zhang, Tielong

    2009-01-01

    The upper limits of the ion pickup and cold ion outflow loss rates from the early martian atmosphere shortly after the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) were investigated. We applied a comprehensive 3-D multi-species magnetohydrodynamic (MHD) model to an early martian CO(2)-rich atmosphere, which was assumed to have been exposed to a solar XUV [X-ray and extreme ultraviolet (EUV)] flux that was 100 times higher than today and a solar wind that was about 300 times denser. We also assumed the late onset of a planetary magnetic dynamo, so that Mars had no strong intrinsic magnetic field at that early period. We found that, due to such extreme solar wind-atmosphere interaction, a strong magnetic field of about approximately 4000 nT was induced in the entire dayside ionosphere, which could efficiently protect the upper atmosphere from sputtering loss. A planetary obstacle ( approximately ionopause) was formed at an altitude of about 1000 km above the surface due to the drag force and the mass loading by newly created ions in the highly extended upper atmosphere. We obtained an O(+) loss rate by the ion pickup process, which takes place above the ionopause, of about 1.5 x 10(28) ions/s during the first < or =150 million years, which is about 10(4) times greater than today and corresponds to a water loss equivalent to a global martian ocean with a depth of approximately 8 m. Consequently, even if the magnetic protection due to the expected early martian magnetic dynamo is neglected, ion pickup and sputtering were most likely not the dominant loss processes for the planet's initial atmosphere and water inventory. However, it appears that the cold ion outflow into the martian tail, due to the transfer of momentum from the solar wind to the ionospheric plasma, could have removed a global ocean with a depth of 10-70 m during the first < or =150 million years after the Sun arrived at the ZAMS.

  5. Atmosphere and water loss from early Mars under extreme solar wind and extreme ultraviolet conditions.

    PubMed

    Terada, Naoki; Kulikov, Yuri N; Lammer, Helmut; Lichtenegger, Herbert I M; Tanaka, Takashi; Shinagawa, Hiroyuki; Zhang, Tielong

    2009-01-01

    The upper limits of the ion pickup and cold ion outflow loss rates from the early martian atmosphere shortly after the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) were investigated. We applied a comprehensive 3-D multi-species magnetohydrodynamic (MHD) model to an early martian CO(2)-rich atmosphere, which was assumed to have been exposed to a solar XUV [X-ray and extreme ultraviolet (EUV)] flux that was 100 times higher than today and a solar wind that was about 300 times denser. We also assumed the late onset of a planetary magnetic dynamo, so that Mars had no strong intrinsic magnetic field at that early period. We found that, due to such extreme solar wind-atmosphere interaction, a strong magnetic field of about approximately 4000 nT was induced in the entire dayside ionosphere, which could efficiently protect the upper atmosphere from sputtering loss. A planetary obstacle ( approximately ionopause) was formed at an altitude of about 1000 km above the surface due to the drag force and the mass loading by newly created ions in the highly extended upper atmosphere. We obtained an O(+) loss rate by the ion pickup process, which takes place above the ionopause, of about 1.5 x 10(28) ions/s during the first < or =150 million years, which is about 10(4) times greater than today and corresponds to a water loss equivalent to a global martian ocean with a depth of approximately 8 m. Consequently, even if the magnetic protection due to the expected early martian magnetic dynamo is neglected, ion pickup and sputtering were most likely not the dominant loss processes for the planet's initial atmosphere and water inventory. However, it appears that the cold ion outflow into the martian tail, due to the transfer of momentum from the solar wind to the ionospheric plasma, could have removed a global ocean with a depth of 10-70 m during the first < or =150 million years after the Sun arrived at the ZAMS. PMID:19216683

  6. [Theoretical analysis and experimental measurement for secondary electron yield of microchannel plate in extreme ultraviolet region].

    PubMed

    Li, Min; Ni, Qi-liang; Dong, Ning-ning; Chen, Bo

    2010-08-01

    Photon counting detectors based on microchannel plate have widespread applications in astronomy. The present paper deeply studies secondary electron of microchannel plate in extreme ultraviolet. A theoretical model describing extreme ultraviolet-excited secondary electron yield is presented, and the factor affecting on the secondary electron yields of both electrode and lead glass which consist of microchannel plate is analyzed according to theoretical formula derived from the model. The result shows that the higher secondary electron yield is obtained under appropriate condition that the thickness of material is more than 20 nm and the grazing incidence angle is larger than the critical angle. Except for several wavelengths, the secondary electron yields of both electrode and lead glass decrease along with the increase in the wavelength And also the quantum efficiency of microchannel plate is measured using quantum efficiency test set-up with laser-produced plasmas source as an extreme ultraviolet radiation source, and the result of experiment agrees with theoretical analysis.

  7. High aspect ratio tungsten grating on ultrathin Si membranes for extreme UV lithography

    NASA Astrophysics Data System (ADS)

    Peng, Xinsheng; Ying, Yulong

    2016-09-01

    Extreme ultraviolet lithography is one of the modern lithography tools for high-volume manufacturing with 22 nm resolution and beyond. But critical challenges exist to the design and fabrication of large-scale and highly efficient diffraction transmission gratings, significantly reducing the feature sizes down to 22 nm and beyond. To achieve such a grating, the surface flatness, the line edge roughness, the transmission efficiency and aspect ratio should be improved significantly. Delachat et al (2015 Nanotechnology 26 108262) develop a full process to fabricate a tungsten diffraction grating on an ultrathin silicon membrane with higher aspect ratio up to 8.75 that met all the aforementioned requirements for extreme ultraviolet lithography. This process is fully compatible with standard industrial extreme ultraviolet lithography.

  8. High aspect ratio tungsten grating on ultrathin Si membranes for extreme UV lithography.

    PubMed

    Peng, Xinsheng; Ying, Yulong

    2016-09-01

    Extreme ultraviolet lithography is one of the modern lithography tools for high-volume manufacturing with 22 nm resolution and beyond. But critical challenges exist to the design and fabrication of large-scale and highly efficient diffraction transmission gratings, significantly reducing the feature sizes down to 22 nm and beyond. To achieve such a grating, the surface flatness, the line edge roughness, the transmission efficiency and aspect ratio should be improved significantly. Delachat et al (2015 Nanotechnology 26 108262) develop a full process to fabricate a tungsten diffraction grating on an ultrathin silicon membrane with higher aspect ratio up to 8.75 that met all the aforementioned requirements for extreme ultraviolet lithography. This process is fully compatible with standard industrial extreme ultraviolet lithography. PMID:27458188

  9. Multidecadal oscillations in rainfall and hydrological extremes

    NASA Astrophysics Data System (ADS)

    Willems, Patrick

    2013-04-01

    Many studies have anticipated a worldwide increase in the frequency and intensity of precipitation extremes and floods since the last decade(s). Natural variability by climate oscillations partly determines the observed evolution of precipitation extremes. Based on a technique for the identification and analysis of changes in extreme quantiles, it is shown that hydrological extremes have oscillatory behaviour at multidecadal time scales. Results are based on nearly independent extremes extracted from long-term historical time series of precipitation intensities and river flows. Study regions include Belgium - The Netherlands (Meuse basin), Ethiopia (Blue Nile basin) and Ecuador (Paute basin). For Belgium - The Netherlands, the past 100 years showed larger and more hydrological extremes around the 1910s, 1950-1960s, and more recently during the 1990-2000s. Interestingly, the oscillations for southwestern Europe are anti-correlated with these of northwestern Europe, thus with oscillation highs in the 1930-1940s and 1970s. The precipitation oscillation peaks are explained by persistence in atmospheric circulation patterns over the North Atlantic during periods of 10 to 15 years. References: Ntegeka V., Willems P. (2008), 'Trends and multidecadal oscillations in rainfall extremes, based on a more than 100 years time series of 10 minutes rainfall intensities at Uccle, Belgium', Water Resources Research, 44, W07402, doi:10.1029/2007WR006471 Mora, D., Willems, P. (2012), 'Decadal oscillations in rainfall and air temperature in the Paute River Basin - Southern Andes of Ecuador', Theoretical and Applied Climatology, 108(1), 267-282, doi:0.1007/s00704-011-0527-4 Taye, M.T., Willems, P. (2011). 'Influence of climate variability on representative QDF predictions of the upper Blue Nile Basin', Journal of Hydrology, 411, 355-365, doi:10.1016/j.jhydrol.2011.10.019 Taye, M.T., Willems, P. (2012). 'Temporal variability of hydro-climatic extremes in the Blue Nile basin', Water

  10. Extreme wind climate in the Czech Republic

    NASA Astrophysics Data System (ADS)

    Pop, L.; Hanslian, D.; Jiri, H.

    2011-12-01

    Extreme wind events belong to the most damaging weather-related hazards in Czech Republic. Therefore a complex survey is performed to exploit the wind data available over the period of industrial measurements in Czech Republic for extreme wind analysis. The object of the survey is to find the limitations of wind data available, to analyze the conditions for extreme wind events and to try to enhance the knowledge about the statistical behavior of extreme wind. The data quality showed itself as a major issue. The homogeneity of extreme wind data is broken in many cases as the extreme wind values are highly dependent on the measuring instrumentation and changes in neighborhood. It also may be difficult to distinguish between correct high wind data and erroneous values. The individual analysis and quality assessment of wind data used in extremal analysis is therefore essential. There are generally two basic groups of extreme wind events typical in the Czech Republic and generally over the mid-latitudes: The "convective" events (can be also called as "squalls") are primarily initiated by deep convection, whereas the primary cause for "non-convective" (synoptic) events is large-scale pressure gradient. The subject is, however, a bit more complex, as the pressure gradient inducing high wind in higher atmospheric levels or wind shear can be a significant factor in convective events; on the other hand, convection may increase wind speeds in otherwise "non-convective" synoptic-scale windstorms. In addition, there are some special phenomena that should be treated individually: the physical principle and climatological behavior (frequency, magnitude and area affected) of tornadoes make them very different from common convective straight winds; this is in lesser scale also the case of "foehn" or "bora" effects belonging to non-convective events. These effects, however, do not play major role over the Czech Republic. In Czech Republic, the overall impact of convective and non

  11. Detection and attribution of extreme weather disasters

    NASA Astrophysics Data System (ADS)

    Huggel, Christian; Stone, Dáithí; Hansen, Gerrit

    2014-05-01

    Single disasters related to extreme weather events have caused loss and damage on the order of up to tens of billions US dollars over the past years. Recent disasters fueled the debate about whether and to what extent these events are related to climate change. In international climate negotiations disaster loss and damage is now high on the agenda, and related policy mechanisms have been discussed or are being implemented. In view of funding allocation and effective risk reduction strategies detection and attribution to climate change of extreme weather events and disasters is a key issue. Different avenues have so far been taken to address detection and attribution in this context. Physical climate sciences have developed approaches, among others, where variables that are reasonably sampled over climatically relevant time periods and related to the meteorological characteristics of the extreme event are examined. Trends in these variables (e.g. air or sea surface temperatures) are compared between observations and climate simulations with and without anthropogenic forcing. Generally, progress has been made in recent years in attribution of changes in the chance of some single extreme weather events to anthropogenic climate change but there remain important challenges. A different line of research is primarily concerned with losses related to the extreme weather events over time, using disaster databases. A growing consensus is that the increase in asset values and in exposure are main drivers of the strong increase of economic losses over the past several decades, and only a limited number of studies have found trends consistent with expectations from climate change. Here we propose a better integration of existing lines of research in detection and attribution of extreme weather events and disasters by applying a risk framework. Risk is thereby defined as a function of the probability of occurrence of an extreme weather event, and the associated consequences

  12. Extreme wind turbine response during operation

    NASA Astrophysics Data System (ADS)

    Sørensen, John D.; Nielsen, Søren R. K.

    2007-07-01

    Estimation of extreme response values is very important for structural design of wind turbines. Due to the influence of control system and nonlinear structural behavior the extreme response is usually assessed based on simulation of turbulence time series. In this paper the problem of statistical load extrapolation is considered using techniques from structural reliability theory. Different simulation techniques to estimate extreme response characteristics are described and compared, including crude Monte Carlo simulation, Importance Sampling, and splitting methods such as the Russian Roulette and the Double and Clump algorithm. A statistically consistent technique is described for including statistical uncertainty and assessing the extreme 50-year response using simulated time series and conditioned on the model parameters. The peak over threshold method together with the Maximum Likelihood Method provides a tool to obtain consistent estimates incl. the statistical uncertainty. An illustrative example indicates that the statistical uncertainty is important compared to the coefficient of variation of the extreme response when the number of 10 minutes simulations at each mean wind speed is limited to 10.

  13. Statistical analysis of extreme auroral electrojet indices

    NASA Astrophysics Data System (ADS)

    Nakamura, Masao; Yoneda, Asato; Oda, Mitsunobu; Tsubouchi, Ken

    2015-09-01

    Extreme auroral electrojet activities can damage electrical power grids due to large induced currents in the Earth, degrade radio communications and navigation systems due to the ionospheric disturbances and cause polar-orbiting satellite anomalies due to the enhanced auroral electron precipitation. Statistical estimation of extreme auroral electrojet activities is an important factor in space weather research. For this estimation, we utilize extreme value theory (EVT), which focuses on the statistical behavior in the tail of a distribution. As a measure of auroral electrojet activities, auroral electrojet indices AL, AU, and AE, are used, which describe the maximum current strength of the westward and eastward auroral electrojets and the sum of the two oppositely directed in the auroral latitude ionosphere, respectively. We provide statistical evidence for finite upper limits to AL and AU and estimate the annual expected number and probable intensity of their extreme events. We detect two different types of extreme AE events; therefore, application of the appropriate EVT analysis to AE is difficult.

  14. How does public opinion become extreme?

    PubMed Central

    Ramos, Marlon; Shao, Jia; Reis, Saulo D. S.; Anteneodo, Celia; Andrade, José S.; Havlin, Shlomo; Makse, Hernán A.

    2015-01-01

    We investigate the emergence of extreme opinion trends in society by employing statistical physics modeling and analysis on polls that inquire about a wide range of issues such as religion, economics, politics, abortion, extramarital sex, books, movies, and electoral vote. The surveys lay out a clear indicator of the rise of extreme views. The precursor is a nonlinear relation between the fraction of individuals holding a certain extreme view and the fraction of individuals that includes also moderates, e.g., in politics, those who are “very conservative” versus “moderate to very conservative” ones. We propose an activation model of opinion dynamics with interaction rules based on the existence of individual “stubbornness” that mimics empirical observations. According to our modeling, the onset of nonlinearity can be associated to an abrupt bootstrap-percolation transition with cascades of extreme views through society. Therefore, it represents an early-warning signal to forecast the transition from moderate to extreme views. Moreover, by means of a phase diagram we can classify societies according to the percolative regime they belong to, in terms of critical fractions of extremists and people’s ties. PMID:25989484

  15. Extreme Metal Music and Anger Processing

    PubMed Central

    Sharman, Leah; Dingle, Genevieve A.

    2015-01-01

    The claim that listening to extreme music causes anger, and expressions of anger such as aggression and delinquency have yet to be substantiated using controlled experimental methods. In this study, 39 extreme music listeners aged 18–34 years were subjected to an anger induction, followed by random assignment to 10 min of listening to extreme music from their own playlist, or 10 min silence (control). Measures of emotion included heart rate and subjective ratings on the Positive and Negative Affect Scale (PANAS). Results showed that ratings of PANAS hostility, irritability, and stress increased during the anger induction, and decreased after the music or silence. Heart rate increased during the anger induction and was sustained (not increased) in the music condition, and decreased in the silence condition. PANAS active and inspired ratings increased during music listening, an effect that was not seen in controls. The findings indicate that extreme music did not make angry participants angrier; rather, it appeared to match their physiological arousal and result in an increase in positive emotions. Listening to extreme music may represent a healthy way of processing anger for these listeners. PMID:26052277

  16. How does public opinion become extreme?

    PubMed

    Ramos, Marlon; Shao, Jia; Reis, Saulo D S; Anteneodo, Celia; Andrade, José S; Havlin, Shlomo; Makse, Hernán A

    2015-01-01

    We investigate the emergence of extreme opinion trends in society by employing statistical physics modeling and analysis on polls that inquire about a wide range of issues such as religion, economics, politics, abortion, extramarital sex, books, movies, and electoral vote. The surveys lay out a clear indicator of the rise of extreme views. The precursor is a nonlinear relation between the fraction of individuals holding a certain extreme view and the fraction of individuals that includes also moderates, e.g., in politics, those who are "very conservative" versus "moderate to very conservative" ones. We propose an activation model of opinion dynamics with interaction rules based on the existence of individual "stubbornness" that mimics empirical observations. According to our modeling, the onset of nonlinearity can be associated to an abrupt bootstrap-percolation transition with cascades of extreme views through society. Therefore, it represents an early-warning signal to forecast the transition from moderate to extreme views. Moreover, by means of a phase diagram we can classify societies according to the percolative regime they belong to, in terms of critical fractions of extremists and people's ties. PMID:25989484

  17. How does public opinion become extreme?

    PubMed

    Ramos, Marlon; Shao, Jia; Reis, Saulo D S; Anteneodo, Celia; Andrade, José S; Havlin, Shlomo; Makse, Hernán A

    2015-05-19

    We investigate the emergence of extreme opinion trends in society by employing statistical physics modeling and analysis on polls that inquire about a wide range of issues such as religion, economics, politics, abortion, extramarital sex, books, movies, and electoral vote. The surveys lay out a clear indicator of the rise of extreme views. The precursor is a nonlinear relation between the fraction of individuals holding a certain extreme view and the fraction of individuals that includes also moderates, e.g., in politics, those who are "very conservative" versus "moderate to very conservative" ones. We propose an activation model of opinion dynamics with interaction rules based on the existence of individual "stubbornness" that mimics empirical observations. According to our modeling, the onset of nonlinearity can be associated to an abrupt bootstrap-percolation transition with cascades of extreme views through society. Therefore, it represents an early-warning signal to forecast the transition from moderate to extreme views. Moreover, by means of a phase diagram we can classify societies according to the percolative regime they belong to, in terms of critical fractions of extremists and people's ties.

  18. Biological Extreme Events: A Research Framework

    NASA Astrophysics Data System (ADS)

    Gutschick, Vincent P.; BassiriRad, Hormoz

    2010-03-01

    Efforts designed to understand and predict adaptation responses of organisms and populations to global climate change must make a clear distinction between responses to changes in average conditions (e.g., doubling of atmospheric carbon dioxide concentration accompanied by an average increase of 1°-3°C in global air temperature by the end of this century) and responses resulting from increased incidence of extreme events [Loehle and LeBlanc, 1996; Easterling et al., 2000; Garrett et al., 2006]. Such distinction is critical because, unlike changes in average conditions, extremes (e.g., megadroughts, fire, flooding, hurricanes, heat waves, and pest outbreaks) are typically short in duration but challenge organisms and populations considerably further beyond their ability to acclimate than those expected from average trends in climate changes. There is growing evidence that climatic extremes have been rising in frequency or magnitude during the last part of the twentieth century and will continue to increase during the remainder of this century [Easterling et al., 2000; Meehl et al., 2000; Parmesan and Yohe, 2003; Barnett et al., 2006]. More important, the frequency of extremes is likely to increase even if the climatic means do not change substantially [Intergovernmental Panel on Climate Change (IPCC), 2001, chapter 10]. Therefore, it makes sense to pay special attention to extremes as major agents of biological adaption (genetic change) when considering global climate change.

  19. Lower extremity muscle activation during baseball pitching.

    PubMed

    Campbell, Brian M; Stodden, David F; Nixon, Megan K

    2010-04-01

    The purpose of this study was to investigate muscle activation levels of select lower extremity muscles during the pitching motion. Bilateral surface electromyography data on 5 lower extremity muscles (biceps femoris, rectus femoris, gluteus maximus, vastus medialis, and gastrocnemius) were collected on 11 highly skilled baseball pitchers and compared with individual maximal voluntary isometric contraction (MVIC) data. The pitching motion was divided into 4 distinct phases: phase 1, initiation of pitching motion to maximum stride leg knee height; phase 2, maximum stride leg knee height to stride foot contact (SFC); phase 3, SFC to ball release; and phase 4, ball release to 0.5 seconds after ball release (follow-through). Results indicated that trail leg musculature elicited moderate to high activity levels during phases 2 and 3 (38-172% of MVIC). Muscle activity levels of the stride leg were moderate to high during phases 2-4 (23-170% of MVIC). These data indicate a high demand for lower extremity strength and endurance. Specifically, coaches should incorporate unilateral and bilateral lower extremity exercises for strength improvement or maintenance and to facilitate dynamic stabilization of the lower extremities during the pitching motion.

  20. Extreme value theory for singular measures.

    PubMed

    Lucarini, Valerio; Faranda, Davide; Turchetti, Giorgio; Vaienti, Sandro

    2012-06-01

    In this paper, we perform an analytical and numerical study of the extreme values of specific observables of dynamical systems possessing an invariant singular measure. Such observables are expressed as functions of the distance of the orbit of initial conditions with respect to a given point of the attractor. Using the block maxima approach, we show that the extremes are distributed according to the generalised extreme value distribution, where the parameters can be written as functions of the information dimension of the attractor. The numerical analysis is performed on a few low dimensional maps. For the Cantor ternary set and the Sierpinskij triangle, which can be constructed as iterated function systems, the inferred parameters show a very good agreement with the theoretical values. For strange attractors like those corresponding to the Lozi and Hènon maps, a slower convergence to the generalised extreme value distribution is observed. Nevertheless, the results are in good statistical agreement with the theoretical estimates. It is apparent that the analysis of extremes allows for capturing fundamental information of the geometrical structure of the attractor of the underlying dynamical system, the basic reason being that the chosen observables act as magnifying glass in the neighborhood of the point from which the distance is computed.