Analysis of hydrogen plasma in MPCVD reactor

NASA Astrophysics Data System (ADS)

Shivkumar, Gayathri

The aim of this work is to build a numerical model that can predict the plasma properties of hydrogen plasmas inside a Seki Technotron Corp. AX5200S MPCVD system so that it may be used to understand and optimize the conditions for the growth of carbon nanostructures. A 2D model of the system is used in the finite element high frequency Maxwell solver and heat trasfer solver in COMSOL Multiphysics, where the solvers are coupled with user defined functions to analyze the plasma. A simplified chemistry model is formulated in order to determine the electron temperature in the plasma. This is used in the UDFs which calculate the electron number density as well as electron temperature. A Boltzmann equation solver for electrons in weakly ionized gases under uniform electric fields, called BOLSIG+, is used to obtain certain input parameters required for these UDFs. The system is modeled for several reactor geometries at pressures of 10 Torr and 30 Torr and powers ranging from 300 W to 700 W. The variation of plasma characteristics with changes in input conditions is studied and the electric field, electron number density, electron temperature and gas temperature are seen to increase with increasing power. Electric field, electron number density and electron temperature decrease and gas temperature increases with increasing pressure. The modeling results are compared with experimental measurements and a good agreement is found after calibrating the parameter gamma in Funer's model to match experimental electron number densities. The gas temperature is seen to have a weak dependence on power and a strong dependence on gas pressure. On an average, the gas temperature at a point 5 mm above the center of the puck increases from about 1000 K at a pressure of 10 Torr to about 1500 K at 30 Torr. The inclusion of the pillar produces an increase in the maximum electron number density of approximately 50%; it is higher under some conditions. It increases the maximum electron temperature by about 70% and at 500 W and 30 Torr, the maximum gas temperature is seen to increase by 50%. The effect of susceptor position is studied and it is seen that the only condition favorable to growth would be to raise it by less than 25 mm from the initial reference position or to maintain it at the same level.

A global view of F-region electron density and temperature at solar maximum

NASA Technical Reports Server (NTRS)

Brace, L. H.; Theis, R. F.; Hoegy, W. R.

1982-01-01

It is pointed out that the thermal structure of the ionosphere represents a quasi-static balance between a variety of heat sources and sinks which vary spatially and temporally on a wide range of time scales. The present investigation has the objective to present selected early results from the Dynamics Explorer-2 (DE-2) Langmuir probe instrument and to make an initial evaluation of how the thermal structure of the ionosphere at solar maximum differs from that observed at solar minimum. Bowen et al. (1964) and Brace and Reddy (1965) devised early empirical models of the F region electron temperature (Te), based on satellite Langmuir probe measurements at low levels of solar activity. The global structure of Te and the electron density (Ne) obtained in the current investigation is not very different from that reported by Brace and Reddy. The primary difference at solar maximum is that Ne is everywhere much higher, but Te differs only in detail.

Investigation of ionization-induced electron injection in a wakefield driven by laser inside a gas cell

DOE PAGES

Audet, T. L.; Hansson, M.; Lee, P.; ...

2016-02-16

Ionization-induced electron injection was investigated experimentally by focusing a driving laser pulse with a maximum normalized potential of 1.2 at different positions along the plasma density profile inside a gas cell, filled with a gas mixture composed of 99%H 2+1%N 2. Changing the laser focus position relative to the gas cell entrance controls the accelerated electron bunch properties, such as the spectrum width, maximum energy, and accelerated charge. Simulations performed using the 3D particle-in-cell code WARP with a realistic density profile give results that are in good agreement with the experimental ones. Lastly, we discuss the interest of this regimemore » for optimizing the bunch charge in a selected energy window.« less

Self-consistent many-electron theory of electron work functions and surface potential characteristics for selected metals

NASA Technical Reports Server (NTRS)

Smith, J. R.

1969-01-01

Electron work functions, surface potentials, and electron number density distributions and electric fields in the surface region of 26 metals were calculated from first principles within the free electron model. Calculation proceeded from an expression of the total energy as a functional of the electron number density, including exchange and correlation energies, as well as a first inhomogeneity term. The self-consistent solution was obtained via a variational procedure. Surface barriers were due principally to many-body effects; dipole barriers were small only for some alkali metals, becoming quite large for the transition metals. Surface energies were inadequately described by this model, which neglects atomistic effects. Reasonable results were obtained for electron work functions and surface potential characteristics, maximum electron densities varying by a factor of over 60.

On the Relative Importance of Convection and Temperature on the Behavior of the Ionosphere in North American during January 6-12, 1997

NASA Technical Reports Server (NTRS)

Richards, P. G.; Buonsanto, M. J.; Reinisch, B. W.; Holt, J.; Fennelly, J. A.; Scali, J. L.; Comfort, R. H.; Germany, G. A.; Spann, J.; Brittnacher, M.

1999-01-01

Measurements from a network of digisondes and an incoherent scatter radar In Eastern North American For January 6-12, 1997 have been compared with the Field Line Interhemispheric Plasma (FLIP) model which now includes the effects of electric field convective. With the exception of Bermuda, the model reproduces the daytime electron density very well most of the time. As is typical behavior for winter solar minimum on magnetically undisturbed nights, the measurements at Millstone Hill show high electron temperatures before midnight followed by a rapid decay, which is accompanied by a pronounced density enhancement in the early morning hours. The FLIP model reproduces the nighttime density enhancement well, provided the model is constrained to follow the topside electron temperature and the flux tube is full. Similar density enhancements are seen at Goose Bay, Wallops Island and Bermuda. However, the peak height variation and auroral images indicate the density enhancements at Goose Bay are most likely due to particle precipitation. Contrary to previously published work we find that the nighttime density variation at Millstone Hill is driven by the temperature behavior and not the other way around. Thus, in both the data and model, the overall nighttime density is lowered and the enhancement does not occur if the temperature remains high all night. Our calculations show that convections of plasma from higher magnetic latitudes does not cause the observed density maximum but it may enhance the density maximum if over-full flux tubes are convected over the station. On the other had, convection of flux tubes with high temperatures and depleted densities may prevent the density maximum from occurring. Despite the success in modeling the nighttime density enhancements, there remain two unresolved problems. First, the measured density decays much faster than the modeled density near sunset at Millstone Hill and Goose Bay though not at lower latitude stations. Second, we cannot fully explain the large temperatures before midnight nor the sudden decay near midnight.

Optimization of laser-plasma injector via beam loading effects using ionization-induced injection

NASA Astrophysics Data System (ADS)

Lee, P.; Maynard, G.; Audet, T. L.; Cros, B.; Lehe, R.; Vay, J.-L.

2018-05-01

Simulations of ionization-induced injection in a laser driven plasma wakefield show that high-quality electron injectors in the 50-200 MeV range can be achieved in a gas cell with a tailored density profile. Using the PIC code Warp with parameters close to existing experimental conditions, we show that the concentration of N2 in a hydrogen plasma with a tailored density profile is an efficient parameter to tune electron beam properties through the control of the interplay between beam loading effects and varying accelerating field in the density profile. For a given laser plasma configuration, with moderate normalized laser amplitude, a0=1.6 and maximum electron plasma density, ne 0=4 ×1018 cm-3 , the optimum concentration results in a robust configuration to generate electrons at 150 MeV with a rms energy spread of 4% and a spectral charge density of 1.8 pC /MeV .

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verheest, Frank, E-mail: frank.verheest@ugent.be; School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000; Hellberg, Manfred A., E-mail: hellberg@ukzn.ac.za

The propagation of arbitrary amplitude electron-acoustic solitons and double layers is investigated in a plasma containing cold positive ions, cool adiabatic and hot isothermal electrons, with the retention of full inertial effects for all species. For analytical tractability, the resulting Sagdeev pseudopotential is expressed in terms of the hot electron density, rather than the electrostatic potential. The existence domains for Mach numbers and hot electron densities clearly show that both rarefactive and compressive solitons can exist. Soliton limitations come from the cool electron sonic point, followed by the hot electron sonic point, until a range of rarefactive double layers occurs.more » Increasing the relative cool electron density further yields a switch to compressive double layers, which ends when the model assumptions break down. These qualitative results are but little influenced by variations in compositional parameters. A comparison with a Boltzmann distribution for the hot electrons shows that only the cool electron sonic point limit remains, giving higher maximum Mach numbers but similar densities, and a restricted range in relative hot electron density before the model assumptions are exceeded. The Boltzmann distribution can reproduce neither the double layer solutions nor the switch in rarefactive/compressive character or negative/positive polarity.« less

Influence of the electron density on the characteristics of terahertz waves generated under laser–cluster interaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frolov, A. A., E-mail: frolov@ihed.ras.ru

2016-12-15

A theory of generation of terahertz radiation under laser–cluster interaction, developed earlier for an overdense cluster plasma [A. A. Frolov, Plasma Phys. Rep. 42. 637 (2016)], is generalized for the case of arbitrary electron density. The spectral composition of radiation is shown to substantially depend on the density of free electrons in the cluster. For an underdense cluster plasma, there is a sharp peak in the terahertz spectrum at the frequency of the quadrupole mode of a plasma sphere. As the electron density increases to supercritical values, this spectral line vanishes and a broad maximum at the frequency comparable withmore » the reciprocal of the laser pulse duration appears in the spectrum. The dependence of the total energy of terahertz radiation on the density of free electrons is analyzed. The radiation yield is shown to increase significantly under resonance conditions, when the laser frequency is close to the eigenfrequency of the dipole or quadrupole mode of a plasma sphere.« less

Structural changes induced by lattice-electron interactions: SiO2 stishovite and FeTiO3 ilmenite.

PubMed

Yamanaka, Takamitsu

2005-09-01

The bright source and highly collimated beam of synchrotron radiation offers many advantages for single-crystal structure analysis under non-ambient conditions. The structure changes induced by the lattice-electron interaction under high pressure have been investigated using a diamond anvil pressure cell. The pressure dependence of electron density distributions around atoms is elucidated by a single-crystal diffraction study using deformation electron density analysis and the maximum entropy method. In order to understand the bonding electrons under pressure, diffraction intensity measurements of FeTiO3 ilmenite and gamma-SiO2 stishovite single crystals at high pressures were made using synchrotron radiation. Both diffraction studies describe the electron density distribution including bonding electrons and provide the effective charge of the cations. In both cases the valence electrons are more localized around the cations with increasing pressure. This is consistent with molecular orbital calculations, proving that the bonding electron density becomes smaller with pressure. The thermal displacement parameters of both samples are reduced with increasing pressure.

An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics.

PubMed

Valdivia, M P; Stutman, D; Stoeckl, C; Theobald, W; Mileham, C; Begishev, I A; Bromage, J; Regan, S P

2016-02-01

X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 10(23) cm(-3) in a low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. The 50 ± 15 μm spatial resolution achieved across the full field of view was found to be limited by the x-ray source-size, similar to conventional radiography.

Frictional Heating of Ions In The F2-region of The Ionosphere

NASA Astrophysics Data System (ADS)

Zhizhko, G. O.; Vlasov, V. G.

Auroral electron beams unstable on the Cherenkov resonance are stabilized by large- scale inhomogeneity of the plasma density during all their way from the acceleration region to the E-region of the ionosphere. The generation of plasma waves by beam is possible only in the region of small plasma density gradients, that always is the area of the F2-region maximum. Thus, collective dissipation of the electron beam energy occurs in the local region with the length about several tens of kilometers. This leads to the intensive heating of the electrons(up to temperatures about 10000 K) and will give origin to the ion upflows with velocity about 1 km/s and density about 109 cm-2 s-1. These flows can result in the ion frictional heating. At the same time ion temperatures reach the values about 5000 K. A numerical simulation of the ion frictional heating in the presence of collective elec- tron heating in the high-latitude F2-region of the ionosphere was performed. The sim- ulation has shown that the most critical parameter for the occurence of the ion fric- tional heating was the the steepness of the plasma density profile above the F2-region maximum.

Experimental investigation of electron guns for THz microwave vacuum amplifiers

NASA Astrophysics Data System (ADS)

Burtsev, A. A.; Grigor'ev, Yu. A.; Navrotsky, I. A.; Rogovin, V. I.; Sakhadzhi, G. V.; Shumikhin, K. V.

2016-05-01

Single-sheet and multiple beam electron emitters based on thermionic minicathodes for terahertz traveling-wave tubes have been studied. Data are presented for impregnated blade thermionic cathode with dimensions 0.1 × 0.7 mm and a maximum current density of 114 A/cm2 in a pulsed mode. A variant of the five-beam electron gun with 0.25-mm-diameter cylindrical minicathodes in cells of a control grid is proposed that provides a current density of 85.5 A/cm2 at a grid potential of 900-1000 V.

Novel plasma source for safe beryllium spectral line studies in the presence of beryllium dust

NASA Astrophysics Data System (ADS)

Stankov, B. D.; Vinić, M.; Gavrilović Božović, M. R.; Ivković, M.

2018-05-01

Plasma source for beryllium spectral line studies in the presence of beryllium dust particles was realised. The guideline during construction was to prevent exposure to formed dust, considering the toxicity of beryllium. Plasma source characterization through determination of optimal working conditions is described. The necessary conditions for Be spectral line appearance and optimal conditions for line shape measurements are found. It is proven experimentally that under these conditions dust appears coincidently with the second current maximum. The electron density measured after discharge current maximum is determined from the peak separation of the hydrogen Balmer beta spectral line, and the electron temperature is determined from the ratios of the relative intensities of Be spectral lines emitted from successive ionized stages of atoms. Maximum values of electron density and temperature are measured to be 9.3 × 1022 m-3 and 16 800 K, respectively. Construction details and testing of the BeO discharge tube in comparison with SiO2 and Al2O3 discharge tubes are also presented in this paper.

PIC simulations of post-pulse field reversal and secondary ionization in nanosecond argon discharges

NASA Astrophysics Data System (ADS)

Kim, H. Y.; Gołkowski, M.; Gołkowski, C.; Stoltz, P.; Cohen, M. B.; Walker, M.

2018-05-01

Post-pulse electric field reversal and secondary ionization are investigated with a full kinetic treatment in argon discharges between planar electrodes on nanosecond time scales. The secondary ionization, which occurs at the falling edge of the voltage pulse, is induced by charge separation in the bulk plasma region. This process is driven by a reverse in the electric field from the cathode sheath to the formerly driven anode. Under the influence of the reverse electric field, electrons in the bulk plasma and sheath regions are accelerated toward the cathode. The electron movement manifests itself as a strong electron current generating high electron energies with significant electron dissipated power. Accelerated electrons collide with Ar molecules and an increased ionization rate is achieved even though the driving voltage is no longer applied. With this secondary ionization, in a single pulse (SP), the maximum electron density achieved is 1.5 times higher and takes a shorter time to reach using 1 kV 2 ns pulse as compared to a 1 kV direct current voltage at 1 Torr. A bipolar dual pulse excitation can increase maximum density another 50%–70% above a SP excitation and in half the time of RF sinusoidal excitation of the same period. The first field reversal is most prominent but subsequent field reversals also occur and correspond to electron temperature increases. Targeted pulse designs can be used to condition plasma density as required for fast discharge applications.

Impact of impurities on zonal flow driven by trapped electron mode turbulence

NASA Astrophysics Data System (ADS)

Guo, Weixin; Wang, Lu; Zhuang, Ge

2017-12-01

The impact of impurities on the generation of zonal flow (ZF) driven by collisonless trapped electron mode turbulence in deuterium (D)-tritium (T) plasmas is investigated. An expression for ZF growth rate with impurities is derived by balancing the ZF potential shielded by polarization effects and the ZF modulated radial turbulent current. Then, it is shown that the maximum normalized ZF growth rate is reduced by the presence of fully ionized non-trace light impurities with relatively flat density profile, and slightly reduced by highly ionized trace tungsten, while the maximum normalized ZF growth rate can be enhanced by fully ionized non-trace light impurities with relatively steep density profile. In particular, the effects of high temperature helium from D-T reaction on ZF depend on the temperature ratio between electrons and high temperature helium. The possible relevance of our findings to recent experimental results and future burning plasmas is also discussed.

The determination of ionospheric electron content and distribution from satellite observations. Part 2. Results of the analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garriott, O K

1960-04-01

The results of observations of the radio transmissions from Sputnik III (1958 δ 2) in an 8-month period are presented. The measurements of integrated electron density are made in two ways, described in part 1. The measurements reveal the diurnal variation of the total ionospheric electron content; and the ratio of the total content to the content of the lower ionosphere below the height of maximum density in the F layer is obtained. An estimate of the average electron-density profile above the F-layer peak is made possible by the slow variation in the height of the satellite due to rotationmore » of the perigee position. The gross effects of large magnetic storms on the electron content and distribution are found.« less

The dependence of graphene Raman D-band on carrier density.

PubMed

Liu, Junku; Li, Qunqing; Zou, Yuan; Qian, Qingkai; Jin, Yuanhao; Li, Guanhong; Jiang, Kaili; Fan, Shoushan

2013-01-01

Raman spectroscopy has been an integral part of graphene research and can provide information about graphene structure, electronic characteristics, and electron-phonon interactions. In this study, the characteristics of the graphene Raman D-band, which vary with carrier density, are studied in detail, including the frequency, full width half-maximum, and intensity. We find the Raman D-band frequency increases for hole doping and decreases for electron doping. The Raman D-band intensity increases when the Fermi level approaches half of the excitation energy and is higher in the case of electron doping than that of hole doping. These variations can be explained by electron-phonon interaction theory and quantum interference between different Raman pathways in graphene. The intensity ratio of Raman D- and G-band, which is important for defects characterization in graphene, shows a strong dependence on carrier density.

Plasma studies of the permanent magnet electron cyclotron resonance ion source at Peking University.

PubMed

Ren, H T; Peng, S X; Xu, Y; Zhao, J; Lu, P N; Chen, J; Zhang, A L; Zhang, T; Guo, Z Y; Chen, J E

2014-02-01

At Peking University (PKU) we have developed several 2.45 GHz Permanent Magnet Electron Cyclotron Resonance ion sources for PKUNIFTY, SFRFQ, Coupled RFQ&SFRFQ, and Dielectric-Wall Accelerator (DWA) projects (respectively, 50 mA of D(+), 10 mA of O(+), 10 mA of He(+), and 50 mA of H(+)). In order to improve performance of these ion sources, it is necessary to better understand the principal factors that influence the plasma density and the atomic ion fraction. Theoretical analysis about microwave transmission and cut-off inside the discharge chamber were carried out to study the influence of the discharge chamber diameters. As a consequence, experimental studies on plasma density and ion fraction with different discharge chamber sizes have been carried out. Due to the difficulties in measuring plasma density inside the discharge chamber, the output beam current was measured to reflect the plasma density. Experimental results show that the plasma density increases to the maximum and then decreases significantly as the diameter changed from 64 mm to 30 mm, and the atomic ion fraction has the same tendency. The maximum beam intensity was obtained with the diameter of 35 mm, but the maximum atomic ion fraction with a diameter of 40 mm. The experimental results are basically accordant with the theoretical calculation. Details are presented in this paper.

Electron density increases due to Lightning activity as deduced from LWPC code and VLF signal perturbations.

NASA Astrophysics Data System (ADS)

Samir, Nait Amor; Bouderba, Yasmina

VLF signal perturbations in association with thunderstorm activity appear as changes in the signal amplitude and phase. Several papers reported on the characteristics of thus perturbations and their connection to the lightning strokes amplitude and polarity. In this contribution, we quantified the electrons density increases due to lightning activity by the use of the LWPC code and VLF signal perturbations parameters. The method is similar to what people did in studying the solar eruptions effect. the results showed that the reference height (h') decreased to lower altitudes (between 70 and 80 km). From the LWPC code results the maximum of the electron density was then deduced. Therefore, a numerical simulation of the atmospheric species times dependences was performed to study the recovery times of the electrons density at different heights. The results showed that the recovery time last for several minutes and explain the observation of long recovery Early signal perturbations.

Direct observation of in-plane anisotropy of the superconducting critical current density in Ba (Fe1-xCox) 2As2 crystals

NASA Astrophysics Data System (ADS)

Hecher, J.; Ishida, S.; Song, D.; Ogino, H.; Iyo, A.; Eisaki, H.; Nakajima, M.; Kagerbauer, D.; Eisterer, M.

2018-01-01

The phase diagram of iron-based superconductors exhibits structural transitions, electronic nematicity, and magnetic ordering, which are often accompanied by an electronic in-plane anisotropy and a sharp maximum of the superconducting critical current density (Jc) near the phase boundary of the tetragonal and the antiferromagnetic-orthorhombic phase. We utilized scanning Hall-probe microscopy to visualize the Jc of twinned and detwinned Ba (Fe1-xCox) 2As2 (x =5 %-8 % ) crystals to compare the electronic normal state properties with superconducting properties. We find that the electronic in-plane anisotropy continues into the superconducting state. The observed correlation between the electronic and the Jc anisotropy agrees qualitatively with basic models, however, the Jc anisotropy is larger than predicted from the resistivity data. Furthermore, our measurements show that the maximum of Jc at the phase boundary does not vanish when the crystals are detwinned. This shows that twin boundaries are not responsible for the large Jc, suggesting an exotic pinning mechanism.

Influence of heat and particle fluxes nonlocality on spatial distribution of plasma density in two-chamber inductively coupled plasma sources

NASA Astrophysics Data System (ADS)

Kudryavtsev, A. A.; Serditov, K. Yu.

2012-07-01

This study presents 2D simulations of the two-chamber inductively coupled plasma source where power is supplied in the small discharge chamber and extends by electron thermal conductivity mechanism to the big diffusion chamber. Depending on pressure, two main scenarios of plasma density and its spatial distribution behavior were identified. One case is characterized by the localization of plasma in the small driver chamber where power is deposed. Another case describes when the diffusion chamber becomes the main source of plasma with maximum of the electron density. The differences in spatial distribution are caused by local or non-local behavior of electron energy transport in the discharge volume due to different characteristic scale of heat transfer with electronic conductivity.

The plasmasphere electron content paradox

NASA Astrophysics Data System (ADS)

Krall, J.; Huba, J. D.

2016-09-01

Measurements show that plasmasphere refilling rates decrease with increasing solar activity, while paradoxically, the vertical integration of the plasmasphere electron density (pTEC) increases with increasing solar activity. Using the Naval Research Laboratory SAMI2 (Sami2 is Another Model of the Ionosphere) and SAMI3 (Sami3 is Also a Model of the Ionosphere) codes, we simulate plasmasphere refilling following a model storm, reproducing this observed phenomenon. In doing so, we find that the refilling rate and resulting pTEC values are sensitive to the oxygen profile in the thermosphere and exosphere: the supply of H+ in the topside ionosphere is limited by the local O+ density, through H+O+→H++O charge exchange. At solar minimum, the O+ supply simply increases with the O density in the exosphere. At solar maximum, we find that O-O+ collisions limit the O+ density in the topside ionosphere such that it decreases with increasing O density. The paradox occurs because the pTEC metric gives electrons in the topside ionosphere more weight than electrons in the plasmasphere.

Nano-Magnets and Additive Manufacturing for Electric Motors

NASA Technical Reports Server (NTRS)

Misra, Ajay K.

2014-01-01

High power density is required for application of electric motors in hybrid electric propulsion. Potential path to achieve high power density in electric motors include advanced materials, lightweight thermal management, lightweight structural concepts, high power density power electronics, and advanced manufacturing. This presentation will focus on two key technologies for achieving high power density, advanced magnets and additive manufacturing. The maximum energy product in current magnets is reaching their theoretical limits as a result of material and process improvements. Future improvements in the maximum energy product for magnets can be achieved through development of nanocomposite magnets combining the hard magnetic phase and soft magnetic phase at the nanoscale level. The presentation will provide an overview of the current state of development for nanocomposite magnets and the future path for doubling the maximum energy product. The other part of the presentation will focus on the role of additive manufacturing in fabrication of high power density electric motors. The presentation will highlight the potential opportunities for applying additive manufacturing to fabricate electric motors.

Electron beam emission from a diamond-amplifier cathode.

PubMed

Chang, Xiangyun; Wu, Qiong; Ben-Zvi, Ilan; Burrill, Andrew; Kewisch, Jorg; Rao, Triveni; Smedley, John; Wang, Erdong; Muller, Erik M; Busby, Richard; Dimitrov, Dimitre

2010-10-15

The diamond amplifier (DA) is a new device for generating high-current, high-brightness electron beams. Our transmission-mode tests show that, with single-crystal, high-purity diamonds, the peak current density is greater than 400  mA/mm², while its average density can be more than 100  mA/mm². The gain of the primary electrons easily exceeds 200, and is independent of their density within the practical range of DA applications. We observed the electron emission. The maximum emission gain measured was 40, and the bunch charge was 50  pC/0.5  mm². There was a 35% probability of the emission of an electron from the hydrogenated surface in our tests. We identified a mechanism of slow charging of the diamond due to thermal ionization of surface states that cancels the applied field within it. We also demonstrated that a hydrogenated diamond is extremely robust.

Electron fluence correction factors for various materials in clinical electron beams.

PubMed

Olivares, M; DeBlois, F; Podgorsak, E B; Seuntjens, J P

2001-08-01

Relative to solid water, electron fluence correction factors at the depth of dose maximum in bone, lung, aluminum, and copper for nominal electron beam energies of 9 MeV and 15 MeV of the Clinac 18 accelerator have been determined experimentally and by Monte Carlo calculation. Thermoluminescent dosimeters were used to measure depth doses in these materials. The measured relative dose at dmax in the various materials versus that of solid water, when irradiated with the same number of monitor units, has been used to calculate the ratio of electron fluence for the various materials to that of solid water. The beams of the Clinac 18 were fully characterized using the EGS4/BEAM system. EGSnrc with the relativistic spin option turned on was used to optimize the primary electron energy at the exit window, and to calculate depth doses in the five phantom materials using the optimized phase-space data. Normalizing all depth doses to the dose maximum in solid water stopping power ratio corrected, measured depth doses and calculated depth doses differ by less than +/- 1% at the depth of dose maximum and by less than 4% elsewhere. Monte Carlo calculated ratios of doses in each material to dose in LiF were used to convert the TLD measurements at the dose maximum into dose at the center of the TLD in the phantom material. Fluence perturbation correction factors for a LiF TLD at the depth of dose maximum deduced from these calculations amount to less than 1% for 0.15 mm thick TLDs in low Z materials and are between 1% and 3% for TLDs in Al and Cu phantoms. Electron fluence ratios of the studied materials relative to solid water vary between 0.83+/-0.01 and 1.55+/-0.02 for materials varying in density from 0.27 g/cm3 (lung) to 8.96 g/cm3 (Cu). The difference in electron fluence ratios derived from measurements and calculations ranges from -1.6% to +0.2% at 9 MeV and from -1.9% to +0.2% at 15 MeV and is not significant at the 1sigma level. Excluding the data for Cu, electron fluence correction factors for open electron beams are approximately proportional to the electron density of the phantom material and only weakly dependent on electron beam energy.

An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics

DOE PAGES

Valdivia, M. P.; Stutman, D.; Stoeckl, C.; ...

2016-02-10

X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 10 23 cm ₋3more » in a low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. We found the 50 ± 15 μm spatial resolution achieved across the full field of view was limited by the x-ray source-size, similar to conventional radiography.« less

An ISEE/Whistler model of equatorial electron density in the magnetosphere

NASA Technical Reports Server (NTRS)

Carpenter, D. L.; Anderson, R. R.

1992-01-01

Attention is given to an empirical model of equatorial electron density in the magnetosphere covering the L range 2.25-8. Although the model is primarily intended for application to the local time interval 00-15 MLT, a way to extend the model to the 15-24-MLT period is presented. The model describes, in piecewise fashion, the 'saturated' plasmasphere, the region of steep plasmapause gradients, and the plasma trough. Within the plasmasphere the model profile can be expressed as logne - Sigma-xi, where x1 = -0.3145L + 3.9043 is the principal or 'reference' term, and additional terms account for: a solar cycle variation with a peak at solar maximum; an annual variation with a December maximum; and a semiannual variation with equinoctial maxima.

Molecular surface mesh generation by filtering electron density map.

PubMed

Giard, Joachim; Macq, Benoît

2010-01-01

Bioinformatics applied to macromolecules are now widely spread and in continuous expansion. In this context, representing external molecular surface such as the Van der Waals Surface or the Solvent Excluded Surface can be useful for several applications. We propose a fast and parameterizable algorithm giving good visual quality meshes representing molecular surfaces. It is obtained by isosurfacing a filtered electron density map. The density map is the result of the maximum of Gaussian functions placed around atom centers. This map is filtered by an ideal low-pass filter applied on the Fourier Transform of the density map. Applying the marching cubes algorithm on the inverse transform provides a mesh representation of the molecular surface.

The middle and high latitude winter ionosphere at the Ariel 4 satellite altitude

NASA Technical Reports Server (NTRS)

Tulunay, Y. K.; Grebowsky, J. M.

1983-01-01

The electron (0+) density variations over the northern and southern winter high latitude ionosphere are comprehensively analyzed using the technique of Brinton et al. (1978). Two-hour Magnetic Local Time (MLT) arithmetic means of electron densities are studied in terms of invariant magnetic latitude and in terms of magnetic activity as classified by the three-hour planetary magnetic activity index. It is found that the southern hemisphere densities are significantly lower than those in the northern hemisphere. Further, the maximum electron densities observed in the northern hemisphere are located in a MLT range symmetrical about the 14-02 MLT meridian, whereas in the southern hemisphere the maxima are observed about the noon midnight magnetic meridian. A deep localized ionization hole on the nightside of the polar cap is not observed although the polar cavity is apparent.

X-ray Thomson scattering measurements of temperature and density from multi-shocked CH capsules

DOE PAGES

Fletcher, L. B.; Glenzer, S. H.; Kritcher, A.; ...

2013-05-24

Proof-of-principle measurements of the electron densities, temperatures, and ionization states of spherically compressed multi-shocked CH (polystyrene) capsules have been achieved using spectrally resolved x-ray Thomson scattering. A total energy of 13.5 kJ incident on target is used to compress a 70 μm thick CH shell above solid-mass density using three coalescing shocks. Separately, a laser-produced zinc He-α x-ray source at 9 keV delayed 200 ps-800 ps after maximum compression is used to probe the plasma in the non-collective scattering regime. The data show that x-ray Thomson scattering enables a complete description of the time-dependent hydrodynamic evolution of shock-compressed CH capsules,more » with a maximum measured density of ρ > 6 g cm –3. Additionally, the results demonstrate that accurate measurements of x-ray scattering from bound-free transitions in the CH plasma demonstrate strong evidence that continuum lowering is the primary ionization mechanism of carbon L-shell electrons.« less

Universal time dependence of nighttime F region densities at high latitudes

NASA Technical Reports Server (NTRS)

De La Beaujardiere, O.; Wickwar, V. B.; Caudal, G.; Holt, J. M.; Craven, J. D.; Frank, L. A.; Brace, L. H.

1985-01-01

Coincident auroral-zone experiments using three incoherent-scatter radars at widely spaced longitudes are reported. The observational results demonstrate that, during the night, the F layer electron density is strongly dependent on the longitude of the observing site. Ionization patches were observed in the nighttime F region from the Chatanika and EISCAT radars, while densities observed from the Millstone radar were substantially smaller. The electron density within these maxima is larger at EISCAT than at Chatanika. When observed in the midnight sector auroral zone, these densities had a peak density at a high altitude of 360-475 km. The density was maximum when EISCAT was in the midnight sector and minimum when Millstone was in the midnight sector. A minimum in insolation in the auroral zone occurs at the UT when Millstone is in the midnight sector.

Propagation of a laser-driven relativistic electron beam inside a solid dielectric.

PubMed

Sarkisov, G S; Ivanov, V V; Leblanc, P; Sentoku, Y; Yates, K; Wiewior, P; Chalyy, O; Astanovitskiy, A; Bychenkov, V Yu; Jobe, D; Spielman, R B

2012-09-01

Laser probe diagnostics: shadowgraphy, interferometry, and polarimetry were used for a comprehensive characterization of ionization wave dynamics inside a glass target induced by a laser-driven, relativistic electron beam. Experiments were done using the 50-TW Leopard laser at the University of Nevada, Reno. We show that for a laser flux of ∼2 × 10(18) W/cm2 a hemispherical ionization wave propagates at c/3 for 10 ps and has a smooth electron-density distribution. The maximum free-electron density inside the glass target is ∼2 × 10(19) cm-3, which corresponds to an ionization level of ∼0.1%. Magnetic fields and electric fields do not exceed ∼15 kG and ∼1 MV/cm, respectively. The electron temperature has a hot, ringlike structure with a maximum of ∼0.7 eV. The topology of the interference phase shift shows the signature of the "fountain effect", a narrow electron beam that fans out from the propagation axis and heads back to the target surface. Two-dimensional particle-in-cell (PIC) computer simulations demonstrate radial spreading of fast electrons by self-consistent electrostatic fields driven by laser. The very low ionization observed after the laser heating pulse suggests a fast recombination on the sub-ps time scale.

Splitting of a vertical multiwalled carbon nanotube carpet to a graphene nanoribbon carpet and its use in supercapacitors.

PubMed

Zhang, Chenguang; Peng, Zhiwei; Lin, Jian; Zhu, Yu; Ruan, Gedeng; Hwang, Chih-Chau; Lu, Wei; Hauge, Robert H; Tour, James M

2013-06-25

Potassium vapor was used to longitudinally split vertically aligned multiwalled carbon nanotubes carpets (VA-CNTs). The resulting structures have a carpet of partially split MWCNTs and graphene nanoribbons (GNRs). The split structures were characterized by scanning electron microscopy, transmission electron microscopy, atomic force microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy. When compared to the original VA-CNTs carpet, the split VA-CNTs carpet has enhanced electrochemical performance with better specific capacitance in a supercapacitor. Furthermore, the split VA-CNTs carpet has excellent cyclability as a supercapacitor electrode material. There is a measured maximum power density of 103 kW/kg at an energy density of 5.2 Wh/kg and a maximum energy density of 9.4 Wh/kg. The superior electrochemical performances of the split VA-CNTs can be attributed to the increased surface area for ion accessibility after splitting, and the lasting conductivity of the structure with their vertical conductive paths based on the preserved GNR alignment.

Redox Potentials of Colloidal n-Type ZnO Nanocrystals: Effects of Confinement, Electron Density, and Fermi-Level Pinning by Aldehyde Hydrogenation.

PubMed

Carroll, Gerard M; Schimpf, Alina M; Tsui, Emily Y; Gamelin, Daniel R

2015-09-02

Electronically doped colloidal semiconductor nanocrystals offer valuable opportunities to probe the new physical and chemical properties imparted by their excess charge carriers. Photodoping is a powerful approach to introducing and controlling free carrier densities within free-standing colloidal semiconductor nanocrystals. Photoreduced (n-type) colloidal ZnO nanocrystals possessing delocalized conduction-band (CB) electrons can be formed by photochemical oxidation of EtOH. Previous studies of this chemistry have demonstrated photochemical electron accumulation, in some cases reaching as many as >100 electrons per ZnO nanocrystal, but in every case examined to date this chemistry maximizes at a well-defined average electron density of ⟨Nmax⟩ ≈ (1.4 ± 0.4) × 10(20) cm(-3). The origins of this maximum have never been identified. Here, we use a solvated redox indicator for in situ determination of reduced ZnO nanocrystal redox potentials. The Fermi levels of various photodoped ZnO nanocrystals possessing on average just one excess CB electron show quantum-confinement effects, as expected, but are >600 meV lower than those of the same ZnO nanocrystals reduced chemically using Cp*2Co, reflecting important differences between their charge-compensating cations. Upon photochemical electron accumulation, the Fermi levels become independent of nanocrystal volume at ⟨N⟩ above ∼2 × 10(19) cm(-3), and maximize at ⟨Nmax⟩ ≈ (1.6 ± 0.3) × 10(20) cm(-3). This maximum is proposed to arise from Fermi-level pinning by the two-electron/two-proton hydrogenation of acetaldehyde, which reverses the EtOH photooxidation reaction.

Enhanced Laser-Driven Ion Acceleration by Superponderomotive Electrons Generated from Near-Critical-Density Plasma

NASA Astrophysics Data System (ADS)

Bin, J. H.; Yeung, M.; Gong, Z.; Wang, H. Y.; Kreuzer, C.; Zhou, M. L.; Streeter, M. J. V.; Foster, P. S.; Cousens, S.; Dromey, B.; Meyer-ter-Vehn, J.; Zepf, M.; Schreiber, J.

2018-02-01

We report on the experimental studies of laser driven ion acceleration from a double-layer target where a near-critical density target with a few-micron thickness is coated in front of a nanometer-thin diamondlike carbon foil. A significant enhancement of proton maximum energies from 12 to ˜30 MeV is observed when a relativistic laser pulse impinges on the double-layer target under linear polarization. We attributed the enhanced acceleration to superponderomotive electrons that were simultaneously measured in the experiments with energies far beyond the free-electron ponderomotive limit. Our interpretation is supported by two-dimensional simulation results.

Experimental investigations of electron density and ion energy distributions in dual-frequency capacitively coupled plasmas for Ar/CF{sub 4} and Ar/O{sub 2}/CF{sub 4} discharges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Jia; Liu, Yong-Xin; Gao, Fei

2014-01-07

The electron density and ion energy distribution (IED) are investigated in low-pressure dual-frequency capacitively coupled Ar/CF{sub 4} (90%/10%) and Ar/O{sub 2}/CF{sub 4} (80%/10%/10%) plasmas. The relations between controllable parameters, such as high-frequency (HF) power, low-frequency (LF) power and gas pressure, and plasma parameters, such as electron density and IEDs, are studied in detail by utilizing a floating hairpin probe and an energy resolved quadrupole mass spectrometer, respectively. In our experiment, the electron density is mainly determined by the HF power and slightly influenced by the LF power. With increasing gas pressure, the electron density first goes up rapidly to amore » maximum value and then decreases at various HF and LF powers. The HF power also plays a considerable role in affecting the IEDs under certain conditions and the ion energy independently controlled by the LF source is discussed here. For clarity, some numerical results obtained from a two-dimensional fluid model are presented.« less

A pulser-sustainer carbon monoxide electric-discharge supersonic laser

NASA Technical Reports Server (NTRS)

Monson, D. J.; Srinivasan, G.

1977-01-01

Operation of a CW CO electric-discharge supersonic laser with a pulser-sustainer discharge is described. High-power operation as well as independent control over electron energy and density are demonstrated. Maximum input power achieved to date is 100 kW. The maximum output power is 6 kW or 10% of the sustainer positive-column power. Much improved performance appears possible.

Axial Structure of High-Vacuum Planar Magnetron Discharge Space

NASA Astrophysics Data System (ADS)

Miura, Tsutomu

1999-09-01

The spatial structure of high-vacuum planar magnetron discharge is theoretically investigated taking into account the electron confinement. The boundary xes of the electron confinement region depends on BA with Ea/BA as the parameter (BA: the magnetic flux density at the anode, Ea: the average electric field strength). The location at which the frequency of ionization events takes the maximum is expressed as CnNxiep (CnN: a factor related to the electron density distribution, xiep: the distance of the location from the cathode at which the ionization is most efficient). With increasing Ea and BA at a fixed Ea/BA, the density of the confined energetic electrons increases. With increasing Ea, the region where ionization is efficient shifts to the cathode side to give a high efficiency of the magnet. The boundary xes as determined by the probe method agreed with the theoretical prediction.

Simulation of Non-Uniform Electron Beams in the Gyrotron Electron-Optical System

NASA Astrophysics Data System (ADS)

Louksha, O. I.; Trofimov, P. A.

2018-04-01

New calculated data on the effect of emission inhomogeneities on the quality of the electron beam, which is formed in an electron-optical system of a gyrotron, have been obtained. The calculations were based on emission current density distributions, which were measured for the different cathodes in the gyrotron of Peter the Great St. Petersburg Polytechnic University. A satisfactory agreement between the experimental and calculated data on the influence of emission nonuniformities on the velocity spread of electrons has been shown. The necessity of considering the real distribution of the emission current density over the cathode surface to determine the main parameters of the electron beam—the velocity and energy spreads of the electrons, spatial structure of the beam, and coefficient of reflection of electrons from the magnetic mirror—has been demonstrated. The maximum level of emission inhomogeneities, which are permissible for effective work of gyrotrons, has been discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

St Lishev, Stiliyan; Shivarova, Antonia P.

The study combines experiments on probe diagnostics with laser-photodetachment-technique and Faraday-cup measurements directed towards determination of the position of the extraction device and its influence on the discharge structure. The measurements have been carried out in the second chamber of an inductively-driven tandem plasma source performed as small scale arrangements, with a magnetic filter located just after the transition between the two chambers of the source. Results for the axial profiles of the plasma parameters display the correlation of the ratio n lowbar /n{sub e} of the densities of the negative hydrogen ions and of the electrons and of themore » concentration of the negative ions with the electron density and temperature: The maxima of the (n lowbar /n{sub e})-ratio and of the density of the negative ions obtained are located at the position of maximum of the electron density behind the filter, in the region of the low electron temperature. Results from probe diagnostics and laser photodetachment measurements at a given axial position for different positions of the Faraday cup show the changes in the spatial distribution of the electron density and temperature and the reduction of the (n lowbar /n{sub e})-ratio and of the density of the negative ions caused by the extraction device.« less

[Performance of Electricity Generation and Feasibility of Discontinuous Power Supply of MFC by Using Pretreated Excess Sludge as Fuel].

PubMed

Zhao, Yan-hui; Zhao, Yang-guo; Guo, Liang

2016-03-15

The feasibility of treating pretreated excess sludge and capacity of supplying continuous power of microbial fuel cells (MFCs) were investigated. Two-chamber microbial fuel cells were started up and operated by using thermal pretreated excess sludge as the substrate. Potential fluctuations were achieved by changing the cathode electron acceptor. During the changes of electron acceptor, the operational stability of MFCs was assessed. The results indicated that the MFCs started successfully with oxygen as the cathode electron acceptor and reached 0.24 V after 148 hours. When the cathode electron acceptor was replaced by potassium ferricyanide, MFCs could obtain the maximum output voltage and maximum power density of 0.66 V and 4.21 W · m⁻³, respectively. When the cathode electron acceptor was changed from oxygen to potassium ferricyanide or the MFCs were closed circuit, the output power of MFCs recovered rapidly. In addition, changes of electron acceptor showed no effect on the removal of COD and ammonia nitrogen. Their removal efficiencies approached to 70% and 80%, respectively. This study concluded that MFC could treat the pretreated excess sludge and produce electricity simultaneously with a high power density. The MFC could also achieve discontinuous electricity supply during operation.

Radio range measurements of coronal electron densities at 13 and 3.6 centimeter wavelengths during the 1988 solar conjunction of Voyager 2

NASA Technical Reports Server (NTRS)

Krisher, T. P.; Anderson, J. D.; Morabito, D. D.; Asmar, S. W.; Borutzki, S. E.; Delitsky, M. L.; Densmore, A. C.; Eshe, P. M.; Lewis, G. D.; Maurer, M. J.

1991-01-01

Radio range measurements of total solar plasma delay obtained during the solar conjunction of the Voyager 2 spacecraft in December 1988, which occurred near solar maximum activity in the 11 yr cycle are reported. The radio range measurements were generated by the Deep Space Network at two wavelengths on the downlink from the spacecraft: 3.6 and 13 cm. A direct measurement of the integrated electron density along the ray path between the earth stations and the spacecraft was obtained by differencing the range at the two wavelengths. Coronal electron density profiles have been derived during ingress and egress of the ray path, which approached the sun to within 5 solar radii. At 10 solar radii, the derived density profiles yield 34079 + or - 611/cu cm on ingress and 49688 + or - 983/cu cm on egress. These density levels are significantly higher than observed near previous solar maxima.

High-temperature electron-hole superfluidity with strong anisotropic gaps in double phosphorene monolayers

NASA Astrophysics Data System (ADS)

Saberi-Pouya, S.; Zarenia, M.; Perali, A.; Vazifehshenas, T.; Peeters, F. M.

2018-05-01

Excitonic superfluidity in double phosphorene monolayers is investigated using the BCS mean-field equations. Highly anisotropic superfluidity is predicted where we found that the maximum superfluid gap is in the Bose-Einstein condensate (BEC) regime along the armchair direction and in the BCS-BEC crossover regime along the zigzag direction. We estimate the highest Kosterlitz-Thouless transition temperature with maximum value up to ˜90 K with onset carrier densities as high as 4 ×1012cm-2 . This transition temperature is significantly larger than what is found in double electron-hole few-layers graphene. Our results can guide experimental research toward the realization of anisotropic condensate states in electron-hole phosphorene monolayers.

The TELEC - A plasma type of direct energy converter. [Thermo-Electronic Laser Energy Converter for electric power generation

NASA Technical Reports Server (NTRS)

Britt, E. J.

1978-01-01

The Thermo-Electronic Laser Energy Converter (TELEC) is a high-power density plasma device designed to convert a 10.6-micron CO2 laser beam into electric power. Electromagnetic radiation is absorbed in plasma electrons, creating a high-electron temperature. Energetic electrons diffuse from the plasma and strike two electrodes having different areas. The larger electrode collects more electrons and there is a net transport of current. An electromagnetic field is generated in the external circuit. A computer program has been designed to analyze TELEC performance allowing parametric variation for optimization. Values are presented for TELEC performance as a function of cesium pressure and for current density and efficiency as a function of output voltage. Efficiency is shown to increase with pressure, reaching a maximum over 45%.

An observational study of the nightside ionospheres of Mars and Venus with radio occultation methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, M.H.G.; Luhmann, J.G.; Kliore, A.J.

1990-10-01

An analysis of Mars and Venus nightside electron density profiles obtained with radio occultation methods shows how the nightside ionospheres of both planets vary with solar zenith angle. From previous studies it is known that the dayside peak electron densities at Mars and Venus show a basic similarity in that they both exhibit Chapman layer-like behavior. In contrast, the peak altitudes at mars behave like an ideal Chapman layer on the dayside, whereas the altitude of the peak at Venus is fairly constant up to the terminator. The effect of major dust storms can also be seen in the peakmore » altitudes at Mars. All Venus nightside electron density profiles show a distinct main peak for both solar minimum and maximum, whereas many profiles from the nightside of Mars do not show any peak at all. This suggests that the electron density in the Mars nightside ionosphere is frequently too low to be detected by radio occultation. On the Pioneer Venus orbiter, disappearing ionospheres were observed near solar maximum in the in-situ data when the solar wind dynamic pressure was exceptionally high. This condition occurs because the high solar wind dynamic pressure decreases the altitude of the ionopause near the terminator below {approximately}250 km, thus reducing the normal nightward transport of dayside ionospheric plasma. On the basis of the Venus observations, one might predict that if a positive correlation of nightside peak density with dynamic pressure was found, it could mean that transport from the dayside is the only significant source for the nightside ionosphere of Mars. The lack of a correlation would imply that the precipitation source at Mars is quite variable.« less

Role of turbulence regime on determining the local density gradient

DOE PAGES

Wang, X.; Mordijck, Saskia; Doyle, E. J.; ...

2017-11-16

In this study we show that the local density gradient in the plasma core depends on the calculated mode-frequency of the most unstable linear mode and reaches a maximum when this frequency is close to zero. Previous theoretical and experimental work on AUG has shown that the ratio of electron to ion temperature, and as such the frequency of the dominant linear gyrokinetic mode, affects the local density gradient close to ρ = 0.3 [1, 2]. On DIII-D we find that by adding Electron Cyclotron Heating (ECH), we modify the dominant unstable linear gyro kinetic mode from an Ion Temperaturemore » Gradient (ITG) mode to a Trapped Electron Mode (TEM), which means that the frequency of the dominant mode changes sign (from the ion to the electron direction). Local density peaking around mid-radius increases by 50% right around the cross-over between the ITG and TEM regimes. By comparing how the particle flux changes, through the derivative of the electron density, n e, with respect to time, ∂n e/∂t, we find that the particle flux also exhibits the same trend versus mode frequency. As a result, we find that the changes in local particle transport are inversely proportional to the changes in electron density, indicating that the changes are driven by a change in thermo-diffusive pinch.« less

Dynamic Characteristics of Positive Pulsed Dielectric Barrier Discharge for Ozone Generation in Air

NASA Astrophysics Data System (ADS)

Wei, Linsheng; Peng, Bangfa; Li, Ming; Zhang, Yafang; Hu, Zhaoji

2016-02-01

A comprehensive dynamic model consisting of 66 reactions and 24 species is developed to investigate the dynamic characteristics of ozone generation by positive pulsed dielectric barrier discharge (DBD) using parallel-plate reactor in air. The electron energy conservation equation is coupled to the electron continuity equation, the heavy species continuity equation, and Poisson's equation for a better description. The reliability of the model is experimentally confirmed. The model can be used to predict the temporal and spatial evolution of species, as well as streamer propagation. The simulation results show that electron density increases nearly exponentially in the direction to the anode at the electron avalanche. Streamer propagation velocity is about 5.26 × 104 m/s from anode to cathode in the simulated condition. The primary positive ion, negative ion, and excited species are O2+, O3- and O2(1Δg) in pulsed DBD in air, respectively. N2O has the largest density among nitrogen oxides. e and N2+ densities in the streamer head increase gradually to maximum values with the development of the streamer. Meanwhile, the O2+, O, O3, N2(A3Σ) and N2O densities reach maximum values in the vicinity of the anode. supported by National Natural Science Foundation of China (Nos. 51366012 and 11105067), Jiangxi Province Young Scientists (Jinggang Star) Cultivation Plan of China (No. 20133BCB23008), Natural Science Foundation of Jiangxi, China (No. 20151BAB206047) and Jiangxi Province Higher School Science and Technology Landing Plan of China (No. KJLD-14015)

Global multi-dimensional modeling of ionospheric electron density using GNSS measurements and IRI model

NASA Astrophysics Data System (ADS)

Alizadeh, M.; Schuh, H.; Schmidt, M. G.

2012-12-01

In the last decades Global Navigation Satellite System (GNSS) has turned into a promising tool for probing the ionosphere. The classical input data for developing Global Ionosphere Maps (GIM) is obtained from the dual-frequency GNSS observations. Simultaneous observations of GNSS code or carrier phase at each frequency is used to form a geometric-free linear combination which contains only the ionospheric refraction term and the differential inter-frequency hardware delays. To relate the ionospheric observable to the electron density, a model is used that represents an altitude-dependent distribution of the electron density. This study aims at developing a global multi-dimensional model of the electron density using simulated GNSS observations from about 150 International GNSS Service (IGS) ground stations. Due to the fact that IGS stations are in-homogenously distributed around the world and the accuracy and reliability of the developed models are considerably lower in the area not well covered with IGS ground stations, the International Reference Ionosphere (IRI) model has been used as a background model. The correction term is estimated by applying spherical harmonics expansion to the GNSS ionospheric observable. Within this study this observable is related to the electron density using different functions for the bottom-side and top-side ionosphere. The bottom-side ionosphere is represented by an alpha-Chapman function and the top-side ionosphere is represented using the newly proposed Vary-Chap function.aximum electron density, IRI background model (elec/m3), day 202 - 2010, 0 UT eight of maximum electron density, IRI background model (km), day 202 - 2010, 0 UT

Adsorption properties of the molecule resveratrol on CNT(8,0-10) nanotube: Geometry optimization, molecular structure, spectroscopic (NMR, UV/Vis, excited state), FMO, MEP and HOMO-LUMO investigations

NASA Astrophysics Data System (ADS)

Sheikhi, Masoome; Shahab, Siyamak; Khaleghian, Mehrnoosh; Hajikolaee, Fatemeh Haji; Balakhanava, Iryna; Alnajjar, Radwan

2018-05-01

In the present work the adsorption properties of the molecule Resveratrol (RSV) (trans-3,5,4‧-Trihydroxystilbene) on CNT(8,0-10) nanotube was investigated by Density Functional Theory (DFT) in the gaseous phase for the first time. The non-bonded interaction effects of compounds RSV and CNT(8,0-10) nanotube on the electronic properties, chemical shift tensors and natural charge were determined and discussed. The electronic spectra of the RSV and the complex CNT(8,0-10)/RSV in the gaseous phase were calculated by Time Dependent Density Functional Theory (TD-DFT) for investigation of the maximum wavelength value of the RSV before and after the non-bonded interaction with the CNT(8,0-10) nanotube and molecular orbitals involved in the formation of absorption spectrum of the complex RSV at maximum wavelength.

Laser ablation in an ambient gas: Modelling and experiment

NASA Astrophysics Data System (ADS)

Moscicki, Tomasz; Hoffman, Jacek; Szymanski, Zygmunt

2018-02-01

The laser ablation of graphite in ambient argon is studied both experimentally and theoretically in conditions corresponding to the initial conditions of carbon nanotube synthesis by the laser vaporization method. The results of the experiment show that the maximum plasma temperature of 24 000 K is reached 25 ns after the beginning of the laser pulse and decreases to about 4000-4500 K after 10 μs. The maximum electron density of 8 × 1025 m-3 is reached 15 ns from the beginning of the laser pulse. The hydrodynamic model applied shows comparable plasma temperatures and electron densities. The model also replicates well a shock wave and plume confinement—intrinsic features of supersonic flow of the ablated plume in an ambient gas. The results show that the theoretical model can be used to simulate nanosecond laser ablation in an ambient gas from the beginning of the process up to several microseconds.

Achieving High Current Density of Perovskite Solar Cells by Modulating the Dominated Facets of Room-Temperature DC Magnetron Sputtered TiO2 Electron Extraction Layer.

PubMed

Huang, Aibin; Lei, Lei; Zhu, Jingting; Yu, Yu; Liu, Yan; Yang, Songwang; Bao, Shanhu; Cao, Xun; Jin, Ping

2017-01-25

The short circuit current density of perovskite solar cell (PSC) was boosted by modulating the dominated plane facets of TiO 2 electron transport layer (ETL). Under optimized condition, TiO 2 with dominant {001} facets showed (i) low incident light loss, (ii) highly smooth surface and excellent wettability for precursor solution, (iii) efficient electron extraction, and (iv) high conductivity in perovskite photovoltaic application. A current density of 24.19 mA cm -2 was achieved as a value near the maximum limit. The power conversion efficiency was improved to 17.25%, which was the record value of PSCs with DC magnetron sputtered carrier transport layer. What is more, the room-temperature process had a great significance for the cost reduction and flexible application of PSCs.

Flexible all-solid-state supercapacitors based on polyaniline orderly nanotubes array.

PubMed

Li, Huihua; Song, Juan; Wang, Linlin; Feng, Xiaomiao; Liu, Ruiqing; Zeng, Wenjin; Huang, Zhendong; Ma, Yanwen; Wang, Lianhui

2017-01-07

Flexible all-solid-state supercapacitors are crucial to meet the growing needs for portable electronic devices such as foldable phones and wearable electronics. As promising candidates for pseudocapacitor electrode materials, polyaniline (PANI) orderly nanotube arrays are prepared via a simple template electrodeposition method. The structures of the final product were characterized using various characterization techniques, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The obtained PANI nanotube film could be directly used as a flexible all-solid-state supercapacitor electrode. Electrochemical results show that the areal capacitance of a PANI nanotube-based supercapacitor with the deposition cycle number of 100 can achieve a maximum areal capacitance of 237.5 mF cm -2 at a scan rate of 10 mV s -1 and maximum energy density of 24.31 mW h cm -2 at a power density of 2.74 mW cm -2 . In addition, the prepared supercapacitor exhibits excellent flexibility under different bending conditions. It retains 95.2% of its initial capacitance value after 2000 cycles at a current density of 1.0 mA cm -1 , which displays its superior cycling stability. Moreover, the prepared flexible all-solid-state supercapacitor can power a light-emitting-diode (LED), which meets the practical applications of micropower supplies.

Seasonal variations of nighttime D-region ionosphere in 2013 solar maximum observed from a low-latitude station

NASA Astrophysics Data System (ADS)

Tan, Le Minh; Thu, Nguyen Ngoc; Ha, Tran Quoc; Nguyen-Luong, Quang

2015-10-01

We present the observation of tweek atmospherics with harmonics m = 1-8 during the solar maximum year, 2013, at Tay Nguyen University, Vietnam (Geog. 12.65° N, 108.02° E). The analysis of 33,690 tweeks on ten international quiet days during 2 months each season, summer (May, August), winter (February, November), and equinox (March, September), shows that tweeks occur about 51 % during summer, 22 % during winter, and 27 % during equinox. The D-region ionosphere is more sharply bounded for harmonics m = 5-6 around an altitude of 85.5 km. The environment of the D-region is more inhomogeneous during winter and equinox seasons. The mean electron density varies from 28.4-225 cm -3, which corresponds to the harmonics m = 1-8 at the mean reflection height of 81.5-87.7 km. The results reveal that the lower reference height in our work as compared to other works is due to the higher level of solar activity. The equivalent electron density profile of the nighttime D-region ionosphere using tweek method during summer, equinox, and winter seasons shows lower values of electron density by 12-58 %, 3-67 %, and 24-76 % than those obtained using the International Reference Ionosphere (IRI-2012) model.

Excitation of a global plasma mode by an intense electron beam in a dc discharge

DOE PAGES

Sydorenko, D.; Kaganovich, I. D.; Ventzek, P. L. G.; ...

2018-01-01

The interaction of an intense electron beam with a finite-length, inhomogeneous plasma is investigated numerically. The plasma density profile is maximal in the middle and decays towards the plasma edges. Two regimes of the two-stream instability are observed. In one regime, the frequency of the instability is the plasma frequency at the density maximum and plasma waves are excited in the middle of the plasma. In the other regime, the frequency of the instability matches the local plasma frequency near the edges of the plasma and the intense plasma oscillations occur near plasma boundaries. The latter regime appears sporadically andmore » only for strong electron beam currents. This instability generates a copious amount of suprathermal electrons. Finally, the energy transfer to suprathermal electrons is the saturation mechanism of the instability.« less

Excitation of a global plasma mode by an intense electron beam in a dc discharge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sydorenko, D.; Kaganovich, I. D.; Ventzek, P. L. G.

The interaction of an intense electron beam with a finite-length, inhomogeneous plasma is investigated numerically. The plasma density profile is maximal in the middle and decays towards the plasma edges. Two regimes of the two-stream instability are observed. In one regime, the frequency of the instability is the plasma frequency at the density maximum and plasma waves are excited in the middle of the plasma. In the other regime, the frequency of the instability matches the local plasma frequency near the edges of the plasma and the intense plasma oscillations occur near plasma boundaries. The latter regime appears sporadically andmore » only for strong electron beam currents. This instability generates a copious amount of suprathermal electrons. Finally, the energy transfer to suprathermal electrons is the saturation mechanism of the instability.« less

Cadmium recovery by coupling double microbial fuel cells.

PubMed

Choi, Chansoo; Hu, Naixu; Lim, Bongsu

2014-10-01

Cr(VI)-MFC of the double microbial fuel cell (d-MFC) arrangement could successfully complement the insufficient voltage and power needed to recover cadmium metal from Cd(II)-MFC, which operated as a redox-flow battery. It was also possible to drain electrical energy from the d-MFC by an additional passage. The highest maximum utilization power density (22.5Wm(-2)) of Cr(VI)-MFC, with the cathode optimized with sulfate buffer, was 11.3times higher than the highest power density directly supplied to Cd(II)-MFC (2.0Wm(-2)). Cr(VI)-MFC could generate 3times higher power with the additional passage than without it; and the current density for the former was 4.2times higher than the latter at the same maximum power point (38.0Am(-2) vs. 9.0Am(-2)). This boosting phenomenon could be explained by the Le Chatelier's principle, which addresses the rate of electron-hole pair formation that can be accelerated by quickly removing electrons generated by microorganisms. Copyright © 2014 Elsevier Ltd. All rights reserved.

Electron heating enhancement by frequency-chirped laser pulses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yazdani, E.; Afarideh, H., E-mail: hafarideh@aut.ac.ir; Sadighi-Bonabi, R., E-mail: Sadighi@sharif.ir

2014-09-14

Propagation of a chirped laser pulse with a circular polarization through an uprising plasma density profile is studied by using 1D-3V particle-in-cell simulation. The laser penetration depth is increased in an overdense plasma compared to an unchirped pulse. The induced transparency due to the laser frequency chirp results in an enhanced heating of hot electrons as well as increased maximum longitudinal electrostatic field at the back side of the solid target, which is very essential in target normal sheath acceleration regime of proton acceleration. For an applied chirp parameter between 0.008 and 0.01, the maximum amount of the electrostatic fieldmore » is improved by a factor of 2. Furthermore, it is noticed that for a chirped laser pulse with a₀=5, because of increasing the plasma transparency length, the laser pulse can penetrate up to about n{sub e}≈6n{sub c}, where n{sub c} is plasma critical density. It shows 63% increase in the effective critical density compared to the relativistic induced transparency regime for an unchirped condition.« less

Millisecond radio spikes from the dwarf M flare star AD Leonis

NASA Technical Reports Server (NTRS)

Lang, K. R.; Willson, R. F.

1986-01-01

Arecibo radio observations of millisec bursts of radio signals at 1415 MHz from AD Leonis are reported. The observed burst had an ellipticity of 0.95, 50-100 percent circular polarization, and a flux density maximum of 30 mJy. The 50 sec burst featured five quasi-periodic oscillations with a mean periodicity of about 3.2 sec. A second, less intense burst that occurred 20 sec later was 100 percent circularly polarized. The area emitting the bursts covered an estimated 0.005 of the radius of AD Leonis and had an electron density of 6 billion/cu cm and a longitudinal magnetic field strength of 250 gauss, if the source was an electron-cyclotron maser. A coherent plasma source would require, for the first harmonic, an electron density of 20 billion/cu cm and a magnetic field much less than 500 gauss. A second harmonic of the plasma frequency would require an electron density of 6 billion/cu cm and a field strength much less than 250 gauss. The possibility that the source was periodic oscillations in coronal loops is discussed.

Pressure dependence of electron density distribution and d-p-π hybridization in titanate perovskite ferroelectrics

NASA Astrophysics Data System (ADS)

Yamanaka, Takamitsu; Nakamoto, Yuki; Ahart, Muhtar; Mao, Ho-kwang

2018-04-01

Electron density distributions of PbTi O3 , BaTi O3 , and SrTi O3 were determined by synchrotron x-ray powder diffraction up to 55 GPa at 300 K and ab initio quantum chemical molecular orbital (MO) calculations, together with a combination of maximum entropy method calculations. The intensity profiles of Bragg peaks reveal split atoms in both ferroelectric PbTi O3 and BaTi O3 , reflecting the two possible positions occupied by the Ti atom. The experimentally obtained atomic structure factor was used for the determination of the deformation in electron density and the d-p-π hybridization between dx z (and dy z) of Ti and px (and py) of O in the Ti-O bond. Ab initio MO calculations proved the change of the molecular orbital coupling and of Mulliken charges with a structure transformation. The Mulliken charge of Ti in the Ti O6 octahedron increased in the ionicity with increasing pressure in the cubic phase. The bonding nature is changed with a decrease in the hybridization of the Ti-O bond and the localization of the electron density with increasing pressure. The hybridization decreases with pressure and disappears in the cubic paraelectric phase, which has a much more localized electron density distribution.

Ionic liquid gating on atomic layer deposition passivated GaN: Ultra-high electron density induced high drain current and low contact resistance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, Hong; Du, Yuchen; Ye, Peide D., E-mail: yep@purdue.edu

2016-05-16

Herein, we report on achieving ultra-high electron density (exceeding 10{sup 14 }cm{sup −2}) in a GaN bulk material device by ionic liquid gating, through the application of atomic layer deposition (ALD) of Al{sub 2}O{sub 3} to passivate the GaN surface. Output characteristics demonstrate a maximum drain current of 1.47 A/mm, the highest reported among all bulk GaN field-effect transistors, with an on/off ratio of 10{sup 5} at room temperature. An ultra-high electron density exceeding 10{sup 14 }cm{sup −2} accumulated at the surface is confirmed via Hall-effect measurement and transfer length measurement. In addition to the ultra-high electron density, we also observe a reductionmore » of the contact resistance due to the narrowing of the Schottky barrier width on the contacts. Taking advantage of the ALD surface passivation and ionic liquid gating technique, this work provides a route to study the field-effect and carrier transport properties of conventional semiconductors in unprecedented ultra-high charge density regions.« less

Formation of the Electric Double Layer and its Effects on Moving Bodies in a Space Plasma Environment

NASA Technical Reports Server (NTRS)

Yang, Qianli; Wu, S. T.; Stone, N. H.; Li, Xiaoquing

1996-01-01

In this paper we solve the self-consistent Vlasov and Poisson equations by a numerical method to determine the local distribution function of the ion and the electron, within a thin layer near the moving body, respectively. Using these ion and electron distributions, the number density for the ions and electrons are determined, such that, the electric potential is obtained within this thin layer (i.e., measured by Debye length). Numerical results are presented for temporal evolution of the electron and ion density and its corresponding electric potential within the layer which shows the formation of electric double layer and its structures. From these numerical results, we are able to determine the maximum conditions of the electric potential, it may create satellite anomaly.

Rocket observation of electron density irregularities in the lower E region

NASA Astrophysics Data System (ADS)

Watanabe, Yuzo; Nakamura, Yoshiharu; Amemiya, Hiroshi

Results are presented on measurements of local ionospheric electron density irregularities, in the size range 3-300 km, observed by a Langmuir probe on board the S-310-16 sounding rocket launched on February 1, 1986 from Kagoshima Space Center (Japan). Results of a frequency analysis of data indicates that the spectral index of the irregularities is 0.9 to 1.8 and the irregularity amplitude is 1 to 15 percent. The amplitude reaches its maximum at the 88 km altitude. The mechanism involved in the generation of these irregularities is explained in the framework of the neutral turbulence theory.

Analysis of microscopic parameters of surface charging in polymer caused by defocused electron beam irradiation.

PubMed

Liu, Jing; Zhang, Hai-Bo

2014-12-01

The relationship between microscopic parameters and polymer charging caused by defocused electron beam irradiation is investigated using a dynamic scattering-transport model. The dynamic charging process of an irradiated polymer using a defocused 30 keV electron beam is conducted. In this study, the space charge distribution with a 30 keV non-penetrating e-beam is negative and supported by some existing experimental data. The internal potential is negative, but relatively high near the surface, and it decreases to a maximum negative value at z=6 μm and finally tend to 0 at the bottom of film. The leakage current and the surface potential behave similarly, and the secondary electron and leakage currents follow the charging equilibrium condition. The surface potential decreases with increasing beam current density, trap concentration, capture cross section, film thickness and electron-hole recombination rate, but with decreasing electron mobility and electron energy. The total charge density increases with increasing beam current density, trap concentration, capture cross section, film thickness and electron-hole recombination rate, but with decreasing electron mobility and electron energy. This study shows a comprehensive analysis of microscopic factors of surface charging characteristics in an electron-based surface microscopy and analysis. Copyright © 2014 Elsevier Ltd. All rights reserved.

Modeling and Numerical Simulation of Microwave Pulse Propagation in Air Breakdown Environment

NASA Technical Reports Server (NTRS)

Kuo, S. P.; Kim, J.

1991-01-01

Numerical simulation is used to investigate the extent of the electron density at a distant altitude location which can be generated by a high-power ground-transmitted microwave pulse. This is done by varying the power, width, shape, and carrier frequency of the pulse. The results show that once the breakdown threshold field is exceeded in the region below the desired altitude location, electron density starts to build up in that region through cascading breakdown. The generated plasma attenuates the pulse energy (tail erosion) and thus deteriorates the energy transmission to the destined altitude. The electron density saturates at a level limited by the pulse width and the tail erosion process. As the pulse continues to travel upward, though the breakdown threshold field of the background air decreases, the pulse energy (width) is reduced more severely by the tail erosion process. Thus, the electron density grows more quickly at the higher altitude, but saturates at a lower level. Consequently, the maximum electron density produced by a single pulse at 50 km altitude, for instance, is limited to a value below 10(exp 6) cm(exp -3). Three different approaches are examined to determine if the ionization at the destined location can be improved: a repetitive pulse approach, a focused pulse approach, and two intersecting beams. Only the intersecting beam approach is found to be practical for generating the desired density level.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fang, Dongfan, E-mail: fangdongfan1208@126.com; Sun, Qizhi; Zhao, Xiaoming

A 633 nm laser interferometer has been designed based on a novel concept, which, without the acousto-optic modulator or the demodulator circuit, adopts the fibers to connect all elements except photodetectors and oscilloscope in this system to make it more compact, portable, and efficient. The noteworthy feature is to mathematically compare the two divided interference signals, which have the same phase-shift caused by the electron density but possess the different initial phase and low angular frequencies. It is possible to read the plasma density directly on the oscilloscope by our original mathematic demodulation method without a camera. Based on themore » Abel inversion algorithm, the radial electron density profiles versus time can be obtained by using the multi-chord system. The designed measurable phase shift ranges from 0 to 2π rad corresponding to the maximum line integral of electron density less than 3.5 × 10{sup 17} cm{sup −2}, and the phase accuracy is about 0.017 rad corresponding to the line integral of electron density accuracy of 1 × 10{sup 15} cm{sup −2}. After the construction of eight-chord interferometer, it will provide the detailed time resolved information of the spatial distribution of the electron density in the field-reversed configuration (FRC) plasma target produced by the “Yingguang-1” programmed-discharge device, which is being constructed in the Key Laboratory of Pulsed Power, China Academy of Engineering Physics.« less

Regional model-based computerized ionospheric tomography using GPS measurements: IONOLAB-CIT

NASA Astrophysics Data System (ADS)

Tuna, Hakan; Arikan, Orhan; Arikan, Feza

2015-10-01

Three-dimensional imaging of the electron density distribution in the ionosphere is a crucial task for investigating the ionospheric effects. Dual-frequency Global Positioning System (GPS) satellite signals can be used to estimate the slant total electron content (STEC) along the propagation path between a GPS satellite and ground-based receiver station. However, the estimated GPS-STEC is very sparse and highly nonuniformly distributed for obtaining reliable 3-D electron density distributions derived from the measurements alone. Standard tomographic reconstruction techniques are not accurate or reliable enough to represent the full complexity of variable ionosphere. On the other hand, model-based electron density distributions are produced according to the general trends of ionosphere, and these distributions do not agree with measurements, especially for geomagnetically active hours. In this study, a regional 3-D electron density distribution reconstruction method, namely, IONOLAB-CIT, is proposed to assimilate GPS-STEC into physical ionospheric models. The proposed method is based on an iterative optimization framework that tracks the deviations from the ionospheric model in terms of F2 layer critical frequency and maximum ionization height resulting from the comparison of International Reference Ionosphere extended to Plasmasphere (IRI-Plas) model-generated STEC and GPS-STEC. The suggested tomography algorithm is applied successfully for the reconstruction of electron density profiles over Turkey, during quiet and disturbed hours of ionosphere using Turkish National Permanent GPS Network.

Plasma density limits for hole boring by intense laser pulses.

PubMed

Iwata, Natsumi; Kojima, Sadaoki; Sentoku, Yasuhiko; Hata, Masayasu; Mima, Kunioki

2018-02-12

High-power lasers in the relativistic intensity regime with multi-picosecond pulse durations are available in many laboratories around the world. Laser pulses at these intensities reach giga-bar level radiation pressures, which can push the plasma critical surface where laser light is reflected. This process is referred to as the laser hole boring (HB), which is critical for plasma heating, hence essential for laser-based applications. Here we derive the limit density for HB, which is the maximum plasma density the laser can reach, as a function of laser intensity. The time scale for when the laser pulse reaches the limit density is also derived. These theories are confirmed by a series of particle-in-cell simulations. After reaching the limit density, the plasma starts to blowout back toward the laser, and is accompanied by copious superthermal electrons; therefore, the electron energy can be determined by varying the laser pulse length.

Aerosols: The key to understanding Titan's lower ionosphere

NASA Astrophysics Data System (ADS)

Molina-Cuberos, G. J.; Cardnell, S.; García-Collado, A. J.; Witasse, O.; López-Moreno, J. J.

2018-04-01

The Permittivity Wave and Altimetry system on board the Huygens probe observed an ionospheric hidden layer at a much lower altitude than the main ionosphere during its descent through the atmosphere of Titan, the largest satellite of Saturn. Previous studies predicted a similar ionospheric layer. However, neither previous nor post-Huygens theoretical models have been able to reproduce the measurements of the electrical conductivity and charge densities reported by the Mutual Impedance (MI) and Relaxation Probe (RP) sensors. The measurements were made from an altitude of 140 km down to the ground and show a maximum of charge densities of ≈ 2 ×109 m-3 positive ions and ≈ 450 ×106 m-3 electrons at approximately 65 km. Such a large difference between positive and negative charge densities has not yet been understood. Here, by making use of electron and ion capture processes in to aerosols, we are able to model both electron and positive ion number densities and to reconcile experimental data and model results.

Observation of ultrahigh-energy electrons by resonance absorption of high-power microwaves in a pulsed plasma.

PubMed

Rajyaguru, C; Fuji, T; Ito, H; Yugami, N; Nishida, Y

2001-07-01

The interaction of high power microwave with collisionless unmagnetized plasma is studied. Investigation on the generation of superthermal electrons near the critical layer, by the resonance absorption phenomenon, is extended to very high microwave power levels (eta=E(2)(0)/4 pi n(e)kT(e) approximately 0.3). Here E0, n(e), and T(e) are the vacuum electric field, electron density, and electron temperature, respectively. Successive generation of electron bunches having maximum energy of about 2 keV, due to nonlinear wave breaking, is observed. The electron energy epsilon scales as a function of the incident microwave power P, according to epsilon proportional to P0.5 up to 250 kW. The two-dimensional spatial distribution of high energy electrons reveals that they are generated near the critical layer. However, the lower energy component is again produced in the subcritical density region indicating the possibility of other electron heating mechanisms.

Higher-order ionospheric error at Arecibo, Millstone, and Jicamarca

NASA Astrophysics Data System (ADS)

Matteo, N. A.; Morton, Y. T.

2010-12-01

The ionosphere is a dominant source of Global Positioning System receiver range measurement error. Although dual-frequency receivers can eliminate the first-order ionospheric error, most second- and third-order errors remain in the range measurements. Higher-order ionospheric error is a function of both electron density distribution and the magnetic field vector along the GPS signal propagation path. This paper expands previous efforts by combining incoherent scatter radar (ISR) electron density measurements, the International Reference Ionosphere model, exponential decay extensions of electron densities, the International Geomagnetic Reference Field, and total electron content maps to compute higher-order error at ISRs in Arecibo, Puerto Rico; Jicamarca, Peru; and Millstone Hill, Massachusetts. Diurnal patterns, dependency on signal direction, seasonal variation, and geomagnetic activity dependency are analyzed. Higher-order error is largest at Arecibo with code phase maxima circa 7 cm for low-elevation southern signals. The maximum variation of the error over all angles of arrival is circa 8 cm.

Application of maximum likelihood methods to laser Thomson scattering measurements of low density plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Washeleski, Robert L.; Meyer, Edmond J. IV; King, Lyon B.

2013-10-15

Laser Thomson scattering (LTS) is an established plasma diagnostic technique that has seen recent application to low density plasmas. It is difficult to perform LTS measurements when the scattered signal is weak as a result of low electron number density, poor optical access to the plasma, or both. Photon counting methods are often implemented in order to perform measurements in these low signal conditions. However, photon counting measurements performed with photo-multiplier tubes are time consuming and multi-photon arrivals are incorrectly recorded. In order to overcome these shortcomings a new data analysis method based on maximum likelihood estimation was developed. Themore » key feature of this new data processing method is the inclusion of non-arrival events in determining the scattered Thomson signal. Maximum likelihood estimation and its application to Thomson scattering at low signal levels is presented and application of the new processing method to LTS measurements performed in the plume of a 2-kW Hall-effect thruster is discussed.« less

Application of maximum likelihood methods to laser Thomson scattering measurements of low density plasmas.

PubMed

Washeleski, Robert L; Meyer, Edmond J; King, Lyon B

2013-10-01

Laser Thomson scattering (LTS) is an established plasma diagnostic technique that has seen recent application to low density plasmas. It is difficult to perform LTS measurements when the scattered signal is weak as a result of low electron number density, poor optical access to the plasma, or both. Photon counting methods are often implemented in order to perform measurements in these low signal conditions. However, photon counting measurements performed with photo-multiplier tubes are time consuming and multi-photon arrivals are incorrectly recorded. In order to overcome these shortcomings a new data analysis method based on maximum likelihood estimation was developed. The key feature of this new data processing method is the inclusion of non-arrival events in determining the scattered Thomson signal. Maximum likelihood estimation and its application to Thomson scattering at low signal levels is presented and application of the new processing method to LTS measurements performed in the plume of a 2-kW Hall-effect thruster is discussed.

Effect of ion beam on the characteristics of ion acoustic Gardner solitons and double layers in a multicomponent superthermal plasma

NASA Astrophysics Data System (ADS)

Kaur, Nimardeep; Singh, Kuldeep; Saini, N. S.

2017-09-01

The nonlinear propagation of ion acoustic solitary waves (IASWs) is investigated in an unmagnetized plasma composed of a positive warm ion fluid, two temperature electrons obeying kappa type distribution and penetrated by a positive ion beam. The reductive perturbation method is used to derive the nonlinear equations, namely, Korteweg-de Vries (KdV), modified KdV (mKdV), and Gardner equations. The characteristic features of both compressive and rarefactive nonlinear excitations from the solution of these equations are studied and compared in the context with the observation of the He+ beam in the polar cap region near solar maximum by the Dynamics Explorer 1 satellite. It is observed that the superthermality and density of cold electrons, number density, and temperature of the positive ion beam crucially modify the basic properties of compressive and rarefactive IASWs in the KdV and mKdV regimes. It is further analyzed that the amplitude and width of Gardner solitons are appreciably affected by different plasma parameters. The characteristics of double layers are also studied in detail below the critical density of cold electrons. The theoretical results may be useful for the observation of nonlinear excitations in laboratory and ion beam driven plasmas in the polar cap region near solar maximum and polar ionosphere as well in Saturn's magnetosphere, solar wind, pulsar magnetosphere, etc., where the population of two temperature superthermal electrons is present.

A molecular dynamics and ab initio analysis of the electronic structure of single-walled carbon nanotubes adhered to a substrate

NASA Astrophysics Data System (ADS)

Van Der Geest, A. G.; Lu, Z.; Lusk, M. T.; Dunn, M. L.

2011-04-01

Single-wall nanotubes can adhere to planar surfaces via van der Waals forces, and this causes the tubes to deform. We use classical molecular dynamics to estimate this deformation and density functional theory to quantify its impact on electronic band structure. For (n,0) tubes, adhesion causes the maximum bandgap to rise more rapidly with diameter, but the value of the maximum is not affected. The influence of adhesion forces on bandgap was found to correlate with that associated with lateral, uniaxial compression for moderate values of adhesion energy and compressive distortion.

Effect of enhanced x-ray flux on the ionosphere over Cyprus during solar flares

NASA Astrophysics Data System (ADS)

Mostafa, Md. Golam; Haralambous, Haris

2015-06-01

In this work we study the effect of solar flares on the ionosphere over Cyprus. Solar flares are impulsive solar activity events usually coupled with Coronal Mass Ejection (CME). The arrival and the subsequent impact of solar flares on geospace, following an eruption on the Sun's surface is almost immediate (around 9 min) whereas the impact of CMEs is rather delayed (2-3 days) as the former is based on X-ray radiation whereas the latter phenomenon is related with particles and magnetic fields travelling at lower speeds via the Solar Wind. The penetration of X-rays down to the Dregion following such an event enhances the electron density. This increase can be monitored by ionosondes, which measure the electron density up to the maximum electron density NmF2. The significance of this increase lies on the increase of signal absorption causing limited window of operating frequencies for HF communications. In this study the effect of enhanced X-ray flux on the ionosphere over Cyprus during solar flares has been investigated. To establish the correlation and extent of impact on different layers, data of X-ray intensity from Geostationary Operational Environmental Satellite (GOES) and ionospheric characteristics (D & F layer) over Nicosia station (35° N, 33° E) were examined for all solar flares during the period 2011-2014. The analysis revealed a positive and good correlation between frequency of minimum reflection, fmin and X-ray intensity for D layer demonstrating that X-rays play a dominant role in the ionization of lower ionosphere. Hence, X-ray flux can be used as a good proxy for studying the solar flare effects on lower ionosphere. The correlation coefficient between maximum electron density of F layer, NmF2 and X-ray intensity was found to be poor.

Investigation of the silicon ion density during molecular beam epitaxy growth

NASA Astrophysics Data System (ADS)

Eifler, G.; Kasper, E.; Ashurov, Kh.; Morozov, S.

2002-05-01

Ions impinging on a surface during molecular beam epitaxy influence the growth and the properties of the growing layer, for example, suppression of dopant segregation and the generation of crystal defects. The silicon electron gun in the molecular beam epitaxy (MBE) equipment is used as a source for silicon ions. To use the effect of ion bombardment the mechanism of generation and distribution of ions was investigated. A monitoring system was developed and attached at the substrate position in the MBE growth chamber to measure the ion and electron densities towards the substrate. A negative voltage was applied to the substrate to modify the ion energy and density. Furthermore the current caused by charge carriers impinging on the substrate was measured and compared with the results of the monitoring system. The electron and ion densities were measured by varying the emission current of the e-gun achieving silicon growth rates between 0.07 and 0.45 nm/s and by changing the voltage applied to the substrate between 0 to -1000 V. The dependencies of ion and electron densities were shown and discussed within the framework of a simple model. The charged carrier densities measured with the monitoring system enable to separate the ion part of the substrate current and show its correlation to the generation rate. Comparing the ion density on the whole substrate and in the center gives a hint to the ion beam focusing effect. The maximum ion and electron current densities obtained were 0.40 and 0.61 μA/cm2, respectively.

Laser-driven relativistic electron beam interaction with solid dielectric

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sarkisov, G. S.; Ivanov, V. V.; Leblanc, P.

2012-07-30

The multi-frames shadowgraphy, interferometry and polarimetry diagnostics with sub-ps time resolution were used for an investigation of ionization wave dynamics inside a glass target induced by laser-driven relativistic electron beam. Experiments were done using the 50 TW Leopard laser at the UNR. For a laser flux of {approx}2 Multiplication-Sign 10{sup 18}W/cm{sup 2} a hemispherical ionization wave propagates at c/3. The maximum of the electron density inside the glass target is {approx}2 Multiplication-Sign 10{sup 19}cm{sup -3}. Magnetic and electric fields are less than {approx}15 kG and {approx}1 MV/cm, respectively. The electron temperature has a maximum of {approx}0.5 eV. 2D interference phasemore » shift shows the 'fountain effect' of electron beam. The very low ionization inside glass target {approx}0.1% suggests a fast recombination at the sub-ps time scale. 2D PIC-simulations demonstrate radial spreading of fast electrons by self-consistent electrostatic fields.« less

Uncooled pulsed zinc oxide semiconductor laser

NASA Astrophysics Data System (ADS)

Bogdankevich, O. V.; Darznek, S. A.; Zverev, M. M.; Kostin, N. N.; Krasavina, E. M.

1985-02-01

An optimized ZnO laser which operates at ambient temperature without cooling is reported, along with extension of the design to form a multielement high-power laser. ZnO single crystal plane-parallel wafers 0.22 mm thick, covered with total and semi-transparent coatings, were exposed to a 200 keV electron beam with a 10 nsec pulse and a current density up to 1 kA/sq cm. No damage was observed in the crystals at saturation. A 7 percent maximum efficiency at a reflection coefficient (RC) of 0.4 was associated with a maximum output of 25 kW and a light power density of 3 MW/sq cm. Cementing a ZnO wafer to a sapphire substrate, applying the same type of coatings and working with a RC of 0.6 yielded a maximum power of 300 kW/sq cm.

A comprehensive evaluation of factors that influence the spin polarization of electrons emitted from bulk GaAs photocathodes

DOE PAGES

Liu, Wei; Poelker, Matt; Peng, Xincun; ...

2017-07-19

Here, the degree of polarization of photoemitted electrons extracted from bulk unstrained GaAs photocathodes is usually considerably less than the theoretical maximum value of 50%, as a result of depolarization mechanisms that originate within the photocathode material and at the vacuum surface interface. This paper provides a comprehensive review of depolarization mechanisms and presents a systematic experimental evaluation of polarization sensitivities to temperature, dopant density, quantum efficiency, and crystal orientation. The highest measured polarization was similar to 50%, consistent with the maximum theoretical value, obtained from a photocathode sample with relatively low dopant concentration and cooled to 77 K. Inmore » general, measurements indicate electron spin polarization can be enhanced at the expense of photoelectron yield (or quantum efficiency).« less

A comprehensive evaluation of factors that influence the spin polarization of electrons emitted from bulk GaAs photocathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Wei; Poelker, Matt; Peng, Xincun

Here, the degree of polarization of photoemitted electrons extracted from bulk unstrained GaAs photocathodes is usually considerably less than the theoretical maximum value of 50%, as a result of depolarization mechanisms that originate within the photocathode material and at the vacuum surface interface. This paper provides a comprehensive review of depolarization mechanisms and presents a systematic experimental evaluation of polarization sensitivities to temperature, dopant density, quantum efficiency, and crystal orientation. The highest measured polarization was similar to 50%, consistent with the maximum theoretical value, obtained from a photocathode sample with relatively low dopant concentration and cooled to 77 K. Inmore » general, measurements indicate electron spin polarization can be enhanced at the expense of photoelectron yield (or quantum efficiency).« less

Enhancement-mode GaAs metal-oxide-semiconductor high-electron-mobility transistors with atomic layer deposited Al2O3 as gate dielectric

NASA Astrophysics Data System (ADS)

Lin, H. C.; Yang, T.; Sharifi, H.; Kim, S. K.; Xuan, Y.; Shen, T.; Mohammadi, S.; Ye, P. D.

2007-11-01

Enhancement-mode GaAs metal-oxide-semiconductor high-electron-mobility transistors (MOS-HEMTs) with ex situ atomic-layer-deposited Al2O3 as gate dielectrics are studied. Maximum drain currents of 211 and 263mA/mm are obtained for 1μm gate-length Al2O3 MOS-HEMTs with 3 and 6nm thick gate oxide, respectively. C-V characteristic shows negligible hysteresis and frequency dispersion. The gate leakage current density of the MOS-HEMTs is 3-5 orders of magnitude lower than the conventional HEMTs under similar bias conditions. The drain current on-off ratio of MOS-HEMTs is ˜3×103 with a subthreshold swing of 90mV/decade. A maximum cutoff frequency (fT) of 27.3GHz and maximum oscillation frequency (fmax) of 39.9GHz and an effective channel mobility of 4250cm2/Vs are measured for the 1μm gate-length Al2O3 MOS-HEMT with 6nm gate oxide. Hooge's constant measured by low frequency noise spectral density characterization is 3.7×10-5 for the same device.

Electricity generation and wastewater treatment of oil refinery in microbial fuel cells using Pseudomonas putida.

PubMed

Majumder, Dip; Maity, Jyoti Prakash; Tseng, Min-Jen; Nimje, Vanita Roshan; Chen, Hau-Ren; Chen, Chien-Cheng; Chang, Young-Fo; Yang, Tsui-Chu; Chen, Chen-Yen

2014-09-22

Microbial fuel cells (MFCs) represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059), a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm) chemical oxygen demand (COD) could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm² in the third cycle with a maximum current density of 0.015 mA/cm² in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10⁻²% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation.

Regional peculiarities in the inter-annual distribution of the red 630.0 nm line nightglow intensities over Abastumani

NASA Astrophysics Data System (ADS)

Toriashvili, L.; Didebulidze, G. G.; Todua, M.

2017-12-01

Peculiarities of the inter-annual distribution of atomic oxygen red OI 630.0 nm line nightglow intensity observed from Abastumani Astrophysical Observatory (41.75 N; 42.82 E) are considered, using the long-term dataset. This distribution demonstrates semi-annual and annual-like variations which occur during solar minimum, as well as maximum phases. The maximum values of the red line intensities are in Summer, however in June it is lower than in May and July, which may be due to regional effects. This phenomenon is considered as a the possible result of regional dynamical processes influencing the behavior of the ionosphere F2 layer which cause changes of electrons/ions densities in the 630.0 nm line luminous region (maximum luminous layer is at about 230-280 km). Using the red line intensities and ionosphere F2 layer electron density data of the IRI-12 model, the changes of meridional thermospheric wind velocities are estimated for this mid-latitude region. These meridional and vertical wind field changes causes of variations of the red line intensities in June can be caused by tidal wind and accompanied by atmospheric gravity waves activities.

Electricity Generation and Wastewater Treatment of Oil Refinery in Microbial Fuel Cells Using Pseudomonas putida

PubMed Central

Majumder, Dip; Maity, Jyoti Prakash; Tseng, Min-Jen; Nimje, Vanita Roshan; Chen, Hau-Ren; Chen, Chien-Cheng; Chang, Young-Fo; Yang, Tsui-Chu; Chen, Chen-Yen

2014-01-01

Microbial fuel cells (MFCs) represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059), a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm) chemical oxygen demand (COD) could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm2 in the third cycle with a maximum current density of 0.015 mA/cm2 in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10−2% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation. PMID:25247576

Occultation Experiment: Results of the First Direct Measurement of Mars's Atmosphere and Ionosphere.

PubMed

Kliore, A; Cain, D L; Levy, G S; Eshleman, V R; Fjeldbo, G; Drake, F D

1965-09-10

Changes in the frequency, phase, and amplitude of the Mariner IV radio signal, caused by passage through the atmosphere and ionosphere of Mars, were observed immediately before and after occultation by the planet. Preliminary analysis of these effects has yielded estimates of the refractivity and density of the atmosphere near the surface, the scale height in the atmosphere, and the electron density profile of the Martian ionosphere. The atmospheric density, temperature, and scale height are lower than previously predicted, as are the maximum density, temperature, scale height, and altitude of the ionosphere.

Design of BAs-AlN monolayered honeycomb heterojunction structures: A first-principles study

NASA Astrophysics Data System (ADS)

Camacho-Mojica, Dulce C.; López-Urías, Florentino

2016-04-01

BAs and AlN are semiconductor materials with an indirect and direct gap respectively in the bulk phase. Recently, electronic calculations have demonstrated that a single-layer or few layers of BAs and AlN exhibit a graphite-like structure with interesting electronic properties. In this work, infinite sheets single-layer heterojunction structures based on alternated strips with honeycomb BAs and AlN layers are investigated using first-principles density functional theory calculations. Optimized geometries, density of states, band-gaps, formation energies, and wave functions are studied for different strip widths joined along zigzag and armchair edges. Results in optimized heterojunction geometries revealed that BAs narrow strips exhibit a corrugation effect due to a lattice mismatch. It was found that zigzag heterojunctions are more energetically favored than armchair heterojunctions. Furthermore, the formation energy presents a maximum at the point where the heterojunction becomes a planar structure. Electronic charge density results yielded a more ionic behavior in Alsbnd N bonds than the Bsbnd As bonds in accordance with monolayer results. It was observed that the conduction band minimum for both heterojunctions exhibit confined states located mainly at the entire AlN strips whereas the valence band maximum exhibits confined states located mainly at BAs strips. We expect that the present investigation will motivate more experimental and theoretical studies on new layered materials made of III-V semiconductors.

Electronic theoretical study of the influences of O adsorption on the electronic structure and optical properties of graphene

NASA Astrophysics Data System (ADS)

Shuang, Zhou; Guili, Liu; Dazhi, Fan

2017-02-01

The electronic structure and optical properties of adsorbing O atoms on graphene with different O coverage are researched using the density functional theory based upon the first-principle study to obtain further insight into properties of graphene. The adsorption energies, band structures, the density of states, light absorption coefficient and reflectivity of each system are calculated theoretically after optimizing structures of each system with different O coverage. Our calculations show that adsorption of O atoms on graphene increases the bond length of C-C which adjacent to the O atoms. When the O coverage is 9.4%, the adsorption energy (3.91 eV) is the maximum, which only increases about 1.6% higher than that of 3.1% O coverage. We find that adsorbed O atoms on pristine graphene opens up indirect gap of about 0.493-0.952 eV. Adsorbing O atoms make pristine graphene from metal into a semiconductor. When the O coverage is 9.4%, the band gap (0.952 eV) is the maximum. Comparing with pristine graphene, we find the density of states at Fermi level of O atoms adsorbing on graphene with different coverage are significantly increased. We also find that light absorption coefficient and reflectivity peaks are significantly reduced, and the larger the coverage, the smaller the absorption coefficient and reflectivity peaks are. And the blue shift phenomenon appears.

Air-Cooled Heat Exchanger for High-Temperature Power Electronics: Preprint

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waye, S. K.; Lustbader, J.; Musselman, M.

2015-05-06

This work demonstrates a direct air-cooled heat exchanger strategy for high-temperature power electronic devices with an application specific to automotive traction drive inverters. We present experimental heat dissipation and system pressure curves versus flow rate for baseline and optimized sub-module assemblies containing two ceramic resistance heaters that provide device heat fluxes. The maximum allowable junction temperature was set to 175 deg.C. Results were extrapolated to the inverter scale and combined with balance-of-inverter components to estimate inverter power density and specific power. The results exceeded the goal of 12 kW/L and 12 kW/kg for power density and specific power, respectively.

A study of density effects in plasmas using analytical approximations for the self-consistent potential

NASA Astrophysics Data System (ADS)

Poirier, M.

2015-06-01

Density effects in ionized matter require particular attention since they modify energies, wavefunctions and transition rates with respect to the isolated-ion situation. The approach chosen in this paper is based on the ion-sphere model involving a Thomas-Fermi-like description for free electrons, the bound electrons being described by a full quantum mechanical formalism. This permits to deal with plasmas out of thermal local equilibrium, assuming only a Maxwell distribution for free electrons. For H-like ions, such a theory provides simple and rather accurate analytical approximations for the potential created by free electrons. Emphasis is put on the plasma potential rather than on the electron density, since the energies and wavefunctions depend directly on this potential. Beyond the uniform electron gas model, temperature effects may be analyzed. In the case of H-like ions, this formalism provides analytical perturbative expressions for the energies, wavefunctions and transition rates. Explicit expressions are given in the case of maximum orbital quantum number, and compare satisfactorily with results from a direct integration of the radial Schrödinger equation. Some formulas for lower orbital quantum numbers are also proposed.

Harmonic analysis of the ionospheric electron densities retrieved from FORMOSAT-3/COSMIC radio occultation measurements

NASA Astrophysics Data System (ADS)

Masoumi, S.; Safari, A.; Sharifi, M.; Sam Khaniani, A.

2011-12-01

In order to investigate regular variations of the ionosphere, the least-squares harmonic estimation is applied to the time series of ionospheric electron densities in the region of Iran derived from about five years of Global Positioning System Radio Occultation (GPS RO) observations by FORMOSAT-3/COSMIC satellites. Although the obtained results are slightly different from the expected ones due to the low horizontal resolution of RO measurements, high vertical resolution of the observations enables us to detect not only the Total Electron Content (TEC) variations, but also periodic patterns of electron densities in different altitudes of the ionosphere. Dominant diurnal and annual signals, together with their Fourier series decompositions, and also periods close to 27 days are obtained, which is consistent with the previous analyses on TEC. In the equatorial anomaly band, the annual component is weaker than its Fourier decomposition periods. In particular, the semiannual period dominates the annual component, which is probably due to the effect of geomagnetic field. By the investigation of the frequencies at different local times, the semiannual signal is more significant than the annual one in the daytime, while the annual frequency is dominant at night. By the detection of the phases of the components, it is revealed that the annual signal has its maximum in summer at high altitudes, and in winter at lower altitudes. This suggests the effect of neutral compositions in the lower atmosphere. Further, the semiannual component peaks around equinox during the day, while its maximum mostly occurs in solstice at night. Since RO measurements can be used to derive TEC along the signal path between a GPS satellite and a receiver, study on the potentiality of using these observations for the prediction of electron densities and its application to the ionospheric correction of the single frequency receivers is suggested.

Kinetic Alfven turbulence: Electron and ion heating by particle-in-cell simulations

NASA Astrophysics Data System (ADS)

Gary, S. P.; Hughes, R. S.; Wang, J.; Parashar, T. N.

2017-12-01

Three-dimensional particle-in-cell simulations of the forward cascade of decaying kinetic Alfvén turbulence have been carried out as an initial-value problem on a collisionless, homogeneous, magnetized, electron-ion plasma model with betae = betai =0.50 and mi/me=100 where subscripts e and i represent electrons and ions respectively. Initial anisotropic narrowband spectra of relatively long wavelength modes with approximately gyrotropic distributions in kperp undergo a forward cascade to broadband spectra of magnetic fluctuations at shorter wavelengths. Maximum electron and ion heating rates are computed as functions of the initial fluctuating magnetic field energy density eo on the range 0.05 < eo < 0.50. In contrast to dissipation by whistler turbulence, the maximum ion heating rate due to kinetic Alfvén turbulence is substantially greater than the maximum electron heating rate. Furthermore, ion heating as well as electron heating due to kinetic Alfvén turbulence scale approximately with eo. Finally, electron heating leads to anisotropies of the type T||e> Tperpe where the parallel and perpendicular symbols refer to directions parallel and perpendicular, respectively, to the background magnetic field, whereas the heated ions remain relatively isotropic. This implies that, for the range of eo values considered, the Landau wave-particle resonance is a likely heating mechanism for the electrons and may also contribute to ion heating.

Shock equation of state of 6LiH to 1.1 TPa

NASA Astrophysics Data System (ADS)

Lazicki, A.; London, R. A.; Coppari, F.; Erskine, D.; Whitley, H. D.; Caspersen, K. J.; Fratanduono, D. E.; Morales, M. A.; Celliers, P. M.; Eggert, J. H.; Millot, M.; Swift, D. C.; Collins, G. W.; Kucheyev, S. O.; Castor, J. I.; Nilsen, J.

2017-10-01

Using laser-generated shock waves, we have measured pressure, density, and temperature of LiH on the principal Hugoniot between 260 and 1100 GPa (2.6-11 Mbar) and on a second-shock Hugoniot up to 1400 GPa to near fivefold compression, extending the maximum pressure reached in non-nuclear experiments by a factor of two. We observe the onset of metal-like reflectivity consistent with temperature-induced ionization of the Li 2s electron, and no sign of additional changes in ionization up to the maximum pressure. Our measurements are in good agreement with gas gun, Z-machine, and underground test data and are accurately described by quantum molecular dynamics simulations. The results confirm the validity of equation of state models built on an average-atom description of the electron-thermal contribution to the free energy and a density-dependent Grüneisen parameter to describe shock response of LiH over this pressure range.

Structural instability in polyacene: A projector quantum Monte Carlo study

NASA Astrophysics Data System (ADS)

Srinivasan, Bhargavi; Ramasesha, S.

1998-04-01

We have studied polyacene within the Hubbard model to explore the effect of electron correlations on the Peierls' instability in a system marginally away from one dimension. We employ the projector quantum Monte Carlo method to obtain ground-state estimates of the energy and various correlation functions. We find strong similarities between polyacene and polyacetylene which can be rationalized from the real-space valence-bond arguments of Mazumdar and Dixit. Electron correlations tend to enhance the Peierls' instability in polyacene. This enhancement appears to attain a maximum at U/t~3.0, and the maximum shifts to larger values when the alternation parameter is increased. The system shows no tendency to destroy the imposed bond-alternation pattern, as evidenced by the bond-bond correlations. The cis distortion is seen to be favored over the trans distortion. The spin-spin correlations show that undistorted polyacene is susceptible to a spin-density-wave distortion for large interaction strength. The charge-charge correlations indicate the absence of a charge-density-wave distortion for the parameters studied.

A miniaturized human-motion energy harvester using flux-guided magnet stacks

NASA Astrophysics Data System (ADS)

Halim, M. A.; Park, J. Y.

2016-11-01

We present a miniaturized electromagnetic energy harvester (EMEH) using two flux-guided magnet stacks to harvest energy from human-generated vibration such as handshaking. Each flux-guided magnet stack increases (40%) the magnetic flux density by guiding the flux lines through a soft magnetic material. The EMEH has been designed to up-convert the applied human-motion vibration to a high-frequency oscillation by mechanical impact of a spring-less structure. The high-frequency oscillator consists of the analyzed 2-magnet stack and a customized helical compression spring. A standard AAA battery sized prototype (3.9 cm3) can generate maximum 203 μW average power from human hand-shaking vibration. It has a maximum average power density of 52 μWcm-3 which is significantly higher than the current state-of-the-art devices. A 6-stage multiplier and rectifier circuit interfaces the harvester with a wearable electronic load (wrist watch) to demonstrate its capability of powering small- scale electronic systems from human-generated vibration.

Magnetospheric electron density long-term (>1 day) refilling rates inferred from passive radio emissions measured by IMAGE RPI during geomagnetically quiet times

NASA Astrophysics Data System (ADS)

Denton, R. E.; Wang, Y.; Webb, P. A.; Tengdin, P. M.; Goldstein, J.; Redfern, J. A.; Reinisch, B. W.

2012-03-01

Using measurements of the electron density ne found from passive radio wave observations by the IMAGE spacecraft RPI instrument on consecutive passes through the magnetosphere, we calculate the long-term (>1 day) refilling rate of equatorial electron density dne,eq/dt from L = 2 to 9. Our events did not exhibit saturation, probably because our data set did not include a deep solar minimum and because saturation is an unusual occurrence, especially outside of solar minimum. The median rate in cm-3/day can be modeled with log10(dne,eq/dt) = 2.22 - 0.006L - 0.0347L2, while the third quartile rate can be modeled with log10(dne,eq/dt) = 3.39 - 0.353L, and the mean rate can be modeled as log10(dne,eq/dt) = 2.74 - 0.269L. These statistical values are found from the ensemble of all observed rates at each L value, including negative rates (decreases in density due to azimuthal structure or radial motion or for other reasons), in order to characterize the typical behavior. The first quartile rates are usually negative for L < 4.7 and close to zero for larger L values. Our rates are roughly consistent with previous observations of ion refilling at geostationary orbit. Most previous studies of refilling found larger refilling rates, but many of these examined a single event which may have exhibited unusually rapid refilling. Comparing refilling rates at solar maximum to those at solar minimum, we found that the refilling rate is larger at solar maximum for small L < 4, about the same at solar maximum and solar minimum for L = 4.2 to 5.8, and is larger at solar minimum for large L > 5.8 such as at geostationary orbit (L ˜ 6.8) (at least to L of about 8). These results agree with previous results for ion refilling at geostationary orbit, may agree with previous results at lower L, and are consistent with some trends for ionospheric density.

Self-consistent fluid modeling and simulation on a pulsed microwave atmospheric-pressure argon plasma jet

NASA Astrophysics Data System (ADS)

Chen, Zhaoquan; Yin, Zhixiang; Chen, Minggong; Hong, Lingli; Xia, Guangqing; Hu, Yelin; Huang, Yourui; Liu, Minghai; Kudryavtsev, A. A.

2014-10-01

In present study, a pulsed lower-power microwave-driven atmospheric-pressure argon plasma jet has been introduced with the type of coaxial transmission line resonator. The plasma jet plume is with room air temperature, even can be directly touched by human body without any hot harm. In order to study ionization process of the proposed plasma jet, a self-consistent hybrid fluid model is constructed in which Maxwell's equations are solved numerically by finite-difference time-domain method and a fluid model is used to study the characteristics of argon plasma evolution. With a Guass type input power function, the spatio-temporal distributions of the electron density, the electron temperature, the electric field, and the absorbed power density have been simulated, respectively. The simulation results suggest that the peak values of the electron temperature and the electric field are synchronous with the input pulsed microwave power but the maximum quantities of the electron density and the absorbed power density are lagged to the microwave power excitation. In addition, the pulsed plasma jet excited by the local enhanced electric field of surface plasmon polaritons should be the discharge mechanism of the proposed plasma jet.

Heating of the solar middle chromosphere by large-scale electric currents

NASA Technical Reports Server (NTRS)

Goodman, M. L.

1995-01-01

A global resistive, two-dimensional, time-dependent magnetohydrodynamic (MHD) model is used to introduce and support the hypothesis that the quiet solar middle chromosphere is heated by resistive dissipation of large-scale electric currents which fill most of its volume. The scale height and maximum magnitude of the current density are 400 km and 31.3 m/sq m, respectively. The associated magnetic field is almost horizontal, has the same scale height as the current density, and has a maximum magnitude of 153 G. The current is carried by electrons flowing across magnetic field lines at 1 m/s. The resistivity is the electron contribution to the Pedersen resitivity for a weakly ionized, strongly magnetized, hydrogen gas. The model does not include a driving mechanism. Most of the physical quantities in the model decrease exponentially with time on a resistive timescale of 41.3 minutes. However, the initial values and spatial; dependence of these quantities are expected to be essentially the same as they would be if the correct driving mechanism were included in a more general model. The heating rate per unit mass is found to be 4.5 x 10(exp 9) ergs/g/s, independent of height and latitude. The electron density scale height is found to be 800 km. The model predicts that 90% of the thermal energy required to heat the middle chromosphere is deposited in the height range 300-760 km above the temperature minimum. It is shown to be consistent to assume that the radiation rate per unit volume is proportional to the magnetic energy density, and then it follows that the heating rate per unit volume is also proportional to the energy from the photosphere into the overlying chromosphere are briefly discussed as possible driving mechanisms for establishing and maintaining the current system. The case in which part of or all of the current is carried by protons and metal ions, and the contribution of electron-proton scattering to the current are also considered, with the conclusion that these effects do not change the qualitative prediction of the model, but probably change the quantitative predictions slightly, mainly by increasing the maximum magntiude of the current density and magnetic field to at most approximately 100 mA/m and approximately 484 G, respectively. The heating rate per unit mass, current density scale height, magnetic field scale height, temperatures, and pressures are unchanged or are only slightly changed by including these additional effects due to protons and ions.

Investigation of the Electron Density Variation During the 21 August 2017 Solar Eclipse

NASA Astrophysics Data System (ADS)

Reinisch, B. W.; Dandenault, P. B.; Galkin, I. A.; Hamel, R.; Richards, P. G.

2018-02-01

This paper presents a comparison of modeled and measured electron densities for the 21 August 2017 solar eclipse across the USA. The location of the instrument was (43.81°N, 247.32°E) where the maximum obscuration of 99.6% occurred at 17.53 hr UT on 21 August. The solar apparent time was 9.96 hr, and the duration of the eclipse was 2.7 hr. It was found that if it is assumed that there are no chromosphere emissions at totality, 30% coronal emission remaining at totality gave the best fit to the electron density variation at 150 km. The 30% coronal emission estimate has uncertainties associated with respect to uncertainties in the solar spectrum, the measured electron density, and the amount of chromosphere emissions remaining at totality. The agreement between the modeled and measured electron densities is excellent at 150 km with the assumed 30% coronal emission at totality. At other altitudes, the agreement is very good, but the altitude profile would be improved if the model peak electron density (NmF2) decayed more slowly to better match the data. The minimum NmF2 in the model occurs 10 min after totality when it decreases to 0.55 from its noneclipse value. The minimum of the NmF2 data occurs between 6 and 10 min after totality but is 15% larger. The total electron content decreases to 0.65 of its preeclipse value. These relative changes agree well with those predicted by others prior to the eclipse.

High-Throughput Screening of Sulfide Thermoelectric Materials Using Electron Transport Calculations with OpenMX and BoltzTraP

NASA Astrophysics Data System (ADS)

Miyata, Masanobu; Ozaki, Taisuke; Takeuchi, Tsunehiro; Nishino, Shunsuke; Inukai, Manabu; Koyano, Mikio

2018-06-01

The electron transport properties of 809 sulfides have been investigated using density functional theory (DFT) calculations in the relaxation time approximation, and a material design rule established for high-performance sulfide thermoelectric (TE) materials. Benchmark electron transport calculations were performed for Cu12Sb4S13 and Cu26V2Ge6S32, revealing that the ratio of the scattering probability of electrons and phonons ( κ lat τ el -1 ) was constant at about 2 × 1014 W K-1 m-1 s-1. The calculated thermopower S dependence of the theoretical dimensionless figure of merit ZT DFT of the 809 sulfides showed a maximum at 140 μV K-1 to 170 μV K-1. Under the assumption of constant κ lat τ el -1 of 2 × 1014 W K-1 m-1 s-1 and constant group velocity v of electrons, a slope of the density of states of 8.6 states eV-2 to 10 states eV-2 is suitable for high- ZT sulfide TE materials. The Lorenz number L dependence of ZT DFT for the 809 sulfides showed a maximum at L of approximately 2.45 × 10-8 V2 K-2. This result demonstrates that the potential of high- ZT sulfide materials is highest when the electron thermal conductivity κ el of the symmetric band is equal to that of the asymmetric band.

Clostridium beijerinckii mutant obtained atmospheric pressure glow discharge generates enhanced electricity in a microbial fuel cell.

PubMed

Liu, Jun; Guo, Ting; Wang, Dong; Ying, Hanjie

2015-01-01

A Clostridium beijerinckii mutant M13 was derived from C. beijerinckii NCIMB 8052 by atmospheric pressure glow discharge. C. beijerinckii M13 generated a maximum output power density of 79.2 mW m(-2) and a maximum output voltage of 230 mV in a microbial fuel cell containing 1 g glucose l(-1) as carbon source and 0.15 g methyl viologen l(-1) as an electron carrier.

Layer structure of the Venus daytime ionosphere from Venera-15,-16 radio occultation

NASA Astrophysics Data System (ADS)

Gavrik, Anatoly

Up to now more than five hundred radio occultation experiments had been carried out by different missions to research physical properties of the Venus ionosphere. The purpose of this report is to show new properties of the Venus daytime ionosphere reanalyzing Venera-15,-16 dual-frequency occultation data. The high coherence and stability of radio signals of Venera- 15,-16 at wave lengths 32 cm and 8 cm, along with the fact, that the refractive amplification at 32 cm in the ionosphere exceeds by factor 6 the refractive amplification at 13 cm used by others researches, have allowed to perform analysis of radiophysical parameters in the Venus ionosphere more accurate. Progress in the radiovision theory and up-to-date digital processing techniques have provided an opportunity to discover unknown layered structure of the Venus daytime ionosphere. We offer the new technique of the data analysis that allows us to separate influence of noise, ionosphere and atmosphere on the radio occultation results. We point out that significant gradient variations in the vertical distribution of the electron density are observed in the region of maximum electron density of the daytime ionosphere at altitudes of 150-175 km. That testifies layered structure of this part of the Venus ionosphere. The results of data analysis reveal the regular existence of the ionospheric layers in the bottom daytime ionosphere at altitudes from 80 up to 115 km. The bottom border of the ionosphere part can vary in the range of 80-100 km, and gradients of the electron density show strong variability. We detect the wave structure in the top atmosphere and in the bottom ionosphere at altitudes from 60 up to 115 km as well. It is difficult to obtain correct electron density in the region, where we have detected the new ionospheric layers. Relative errors of the electron density are greater than 100% at altitudes between 80 and 120 km. The bottom part of the ionosphere is more variable, than overlying area of the main maximum of the daytime ionosphere. It is difficult to explain such layered structures of the Venus daytime ionosphere by means of existing model of the photochemical equilibrium.

Variations of plasmaspheric field-aligned electron and ion densities (90-4000 km) during quiet to moderately active (Kp < 4) geomagnetic conditions

NASA Astrophysics Data System (ADS)

Sonwalkar, V. S.; Reddy, A.

2017-12-01

Variation in field-aligned electron and ion densities as a function of geomagnetic activity are important parameters in the physics of the thermosphere-ionosphere-magnetosphere coupling. Using whistler mode sounding from IMAGE, we report variations in field-aligned electron density and O+/H+ transition height (HT) during two periods (16-23 Aug 2005; 24 Sep-06 Oct 2005) when geomagnetic conditions were quiet (maximum Kp in the past 24 hours, Kpmax,24 ≤ 2) to moderately active (2 < Kpmax,24 <4). The measurements were obtained in the L=1.7 to 3.3 range (90- 4000 km, 13 or 15 MLT). Our results show that, under similar geomagnetic activity, at similar L-shells but with different geographic longitudes and MLTs, the O+/H+ transition height varied within ±12% of 1100 km at L 2 and within ±8% of 1350 km at L 3. The electron densities along flux tubes varied within 30% and 20%, respectively, below (including F2 peak) and above HT. With increasing L shell: (a) O+/H+ transition height increased; (b) electron density variations below HT including F2 peak showed no trend; (c) electron density above HT decreased. For flux tubes at similar longitudes, L-shells, and MLT's, relative to quiet time, during moderate geomagnetic activity: (1) O+/H+ transition height was roughly same; (2) electron density variations below HT showed no trend; (3) electron density above HT increased ( 10-40 %). The measured electron density is in agreement with in situ measurements from CHAMP (350 km) and DMSP (850 km) and past space borne (e. g., ISIS) measurements but the F2 peak density is a factor of 2 lower relative to that measured by ground ionosondes and that predicted by IRI-2012 empirical model. The measured transition height is consistent with OGO 4, Explorer 31, and C/NOFS measurements but is lower than that from IRI-2012. The observed variations in electron density at F2 peak are consistent with past work and are attributed to solar, geomagnetic, and meteorological causes [e. g. Risibeth and Mendillo, 2001; Forbes et al., 2000]. To the best of our knowledge, variations in field-aligned electron density above transition height at mid-latitudes during quiet to moderately active periods have not been reported in the past. Further investigation using physics based models (e. g., SAMI3) is required to explain the observed variations.

Electron density and plasma dynamics of a spherical theta pinch

NASA Astrophysics Data System (ADS)

Teske, C.; Liu, Y.; Blaes, S.; Jacoby, J.

2012-03-01

A spherical theta pinch for plasma stripper applications has been developed and investigated regarding the electron density and the plasma confinement during the pinching sequence. The setup consists of a 6 μH induction coil surrounding a 4000 ml spherical discharge vessel and a capacitor bank with interchangeable capacitors leading to an overall capacitance of 34 μF and 50 μF, respectively. A thyristor switch is used for driving the resonant circuit. Pulsed coil currents reached values of up to 26 kA with maximum induction of 500 mT. Typical gas pressures were 0.7 Pa up to 120 Pa with ArH2 (2.8% H2)-gas as a discharge medium. Stark broadening measurements of the Hβ emission line were carried out in order to evaluate the electron density of the discharge. In accordance with the density measurements, the transfer efficiency was estimated and a scaling law between electron density and discharge energy was established for the current setup. The densities reached values of up to 8 × 1022 m-3 for an energy of 1.6 kJ transferred into the plasma. Further, the pinching of the discharge plasma was documented and the different stages of the pinching process were analyzed. The experimental evidence suggests that concerning the recent setup of the spherical theta pinch, a linear scaling law between the transferred energy and the achievable plasma density can be applied for various applications like plasma strippers and pulsed ion sources.

Whistler turbulence heating of electrons and ions: Three-dimensional particle-in-cell simuations

DOE PAGES

Gary, S. Peter; Hughes, R. Scott; Wang, Joseph

2016-01-14

In this study, the decay of whistler turbulence in a collisionless, homogeneous, magnetized plasma is studied using three-dimensional particle-in-cell simulations. The simulations are initialized with a narrowband, relatively isotropic distribution of long wavelength whistler modes. A first ensemble of simulations at electron betamore » $${\\beta }_{{\\rm{e}}}$$ = 0.25 and ion-to-electron mass ratio $${m}_{{\\rm{i}}}$$/$${m}_{{\\rm{e}}}$$ = 400 is carried out on a domain cube of dimension $$L{\\omega }_{\\mathrm{pi}}$$/c = 5.12 where $${\\omega }_{\\mathrm{pi}}$$ is the ion plasma frequency. The simulations begin with a range of dimensionless fluctuating field energy densities, $${\\epsilon }_{{\\rm{o}}}$$, and follow the fluctuations as they cascade to broadband, anisotropic turbulence which dissipates at shorter wavelengths, heating both electrons and ions. The electron heating is stronger and preferentially parallel/antiparallel to the background magnetic field $${{\\boldsymbol{B}}}_{{\\rm{o}}};$$ the ion energy gain is weaker and is preferentially in directions perpendicular to $${{\\boldsymbol{B}}}_{{\\rm{o}}}$$. The important new results here are that, over 0.01 < $${\\epsilon }_{{\\rm{o}}}$$ < 0.25, the maximum rate of electron heating scales approximately as $${\\epsilon }_{{\\rm{o}}}$$, and the maximum rate of ion heating scales approximately as $${\\epsilon }_{{\\rm{o}}}^{1.5}$$. A second ensemble of simulations at $${\\epsilon }_{{\\rm{o}}}$$ = 0.10 and $${\\beta }_{{\\rm{e}}}$$ = 0.25 shows that, over 25 < $${m}_{{\\rm{i}}}$$/$${m}_{{\\rm{e}}}\\;$$< 1836, the ratio of the maximum ion heating rate to the maximum electron heating rate scales approximately as $${m}_{{\\rm{e}}}$$/$${m}_{{\\rm{i}}}$$.« less

Multipactor saturation in parallel-plate waveguides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sorolla, E.; Mattes, M.

2012-07-15

The saturation stage of a multipactor discharge is considered of interest, since it can guide towards a criterion to assess the multipactor onset. The electron cloud under multipactor regime within a parallel-plate waveguide is modeled by a thin continuous distribution of charge and the equations of motion are calculated taking into account the space charge effects. The saturation is identified by the interaction of the electron cloud with its image charge. The stability of the electron population growth is analyzed and two mechanisms of saturation to explain the steady-state multipactor for voltages near above the threshold onset are identified. Themore » impact energy in the collision against the metal plates decreases during the electron population growth due to the attraction of the electron sheet on the image through the initial plate. When this growth remains stable till the impact energy reaches the first cross-over point, the electron surface density tends to a constant value. When the stability is broken before reaching the first cross-over point the surface charge density oscillates chaotically bounded within a certain range. In this case, an expression to calculate the maximum electron surface charge density is found whose predictions agree with the simulations when the voltage is not too high.« less

Voltage and power relationships in lithium-containing solar cells.

NASA Technical Reports Server (NTRS)

Faith, T. J.

1972-01-01

Photovoltaic characteristics have been measured on a large number of crucible-grown lithium-containing solar cells irradiated by 1-MeV electrons to fluences ranging from 3 x 10 to the 13th power to 3 x 10 to the 15th power electrons per sq cm. These measurements have established empirical relationships between cell photovoltaic parameters and lithium donor density gradient. Short-circuit current and maximum power measured immediately after irradiation decrease logarithmically with lithium gradient. Open-circuit voltage increases logarithmically with lithium gradient both immediately after irradiation and after recovery, the degree of recovery being strongly gradient-dependent at high fluence. As a result, the maximum power and the power at 0.43 V after recovery from 3 x 10 to the 15th power electrons per sq cm increase with increasing lithium gradient.

Maxima of |Ψ|2: a connection between quantum mechanics and Lewis structures.

PubMed

Lüchow, Arne

2014-04-30

The maxima of squared electronic wave functions |Ψ|2 are analyzed for a number of small molecules. They are in principle observables and show considerable chemical insight from first principles. The maxima contain substantial information about the relative electron positions in a molecule, such as the pairing of opposite spin electrons and the Pauli repulsion which are lost in the electron density. Single bond and double bond as well as polar bond pairs and lone pairs are obtained from the maximum analysis. In many cases, we find a correspondence to the electron arrangements in molecules as assumed by Lewis in 1916. Copyright © 2014 Wiley Periodicals, Inc.

Cassini measurements of cold plasma in the ionosphere of Titan.

PubMed

Wahlund, J E; Boström, R; Gustafsson, G; Gurnett, D A; Kurth, W S; Pedersen, A; Averkamp, T F; Hospodarsky, G B; Persoon, A M; Canu, P; Neubauer, F M; Dougherty, M K; Eriksson, A I; Morooka, M W; Gill, R; André, M; Eliasson, L; Müller-Wodarg, I

2005-05-13

The Cassini Radio and Plasma Wave Science (RPWS) Langmuir probe (LP) sensor observed the cold plasma environment around Titan during the first two flybys. The data show that conditions in Saturn's magnetosphere affect the structure and dynamics deep in the ionosphere of Titan. The maximum measured ionospheric electron number density reached 3800 per cubic centimeter near closest approach, and a complex chemistry was indicated. The electron temperature profiles are consistent with electron heat conduction from the hotter Titan wake. The ionospheric escape flux was estimated to be 10(25) ions per second.

Gas pressure and electron density at the level of the active zone of hollow cathode arc discharges

NASA Technical Reports Server (NTRS)

Minoo, M. H.

1984-01-01

A model for the longitudinal variations of the partial pressures of electrons, ions, and neutral particles is proposed as a result of an experimental study of pressure variations at the level of the active zone as a function of the various discharge parameters of a hollow cathode arc. The cathode region where the temperature passes through its maximum is called active zone. The proposed model embodies the very important variations which the partial electron and neutral particles pressures undergo at the level of the active zone.

Oxygen Vacancies in ZnO Nanosheets Enhance CO2 Electrochemical Reduction to CO.

PubMed

Geng, Zhigang; Kong, Xiangdong; Chen, Weiwei; Su, Hongyang; Liu, Yan; Cai, Fan; Wang, Guoxiong; Zeng, Jie

2018-05-22

As electron transfer to CO 2 is generally considered to be the critical step during the activation of CO 2 , it is important to develop approaches to engineer the electronic properties of catalysts to improve their performance in CO 2 electrochemical reduction. Herein, we developed an efficient strategy to facilitate CO 2 activation by introducing oxygen vacancies into electrocatalysts with electronic-rich surface. ZnO nanosheets rich in oxygen vacancies exhibited a current density of -16.1 mA cm -2 with a Faradaic efficiency of 83 % for CO production. Based on density functional theory (DFT) calculations, the introduction of oxygen vacancies increased the charge density of ZnO around the valence band maximum, resulting in the enhanced activation of CO 2 . Mechanistic studies further revealed that the enhancement of CO production by introducing oxygen vacancies into ZnO nanosheets originated from the increased binding strength of CO 2 and the eased CO 2 activation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Anharmonic Thermal Oscillations of the Electron Momentum Distribution in Lithium Fluoride

NASA Astrophysics Data System (ADS)

Erba, A.; Maul, J.; Itou, M.; Dovesi, R.; Sakurai, Y.

2015-09-01

Anharmonic thermal effects on the electron momentum distribution of a lithium fluoride single crystal are experimentally measured through high-resolution Compton scattering and theoretically modeled with ab initio simulations, beyond the harmonic approximation to the lattice potential, explicitly accounting for thermal expansion. Directional Compton profiles are measured at two different temperatures, 10 and 300 K, with a high momentum space resolution (0.10 a.u. in full width at half maximum), using synchrotron radiation. The effect of temperature on measured directional Compton profiles is clearly revealed by oscillations extending almost up to |p |=4 a .u . , which perfectly match those predicted from quantum-mechanical simulations. The wave-function-based Hartree-Fock method and three classes of the Kohn-Sham density functional theory (local-density, generalized-gradient, and hybrid approximations) are adopted. The lattice thermal expansion, as described with the quasiharmonic approach, is found to entirely account for the effect of temperature on the electron momentum density within the experimental accuracy.

Effects of Ionization in a Laser Wakefield Accelerator

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGuffey, C.; Schumaker, W.; Matsuoka, T.

2010-11-04

Experimental results are presented from studies of the ionization injection process in laser wakefield acceleration using the Hercules laser with laser power up to 100 TW. Gas jet targets consisting of gas mixtures reduced the density threshold required for electron injection and increased the maximum beam charge. Gas mixture targets produced smooth beams even at densities which would produce severe beam breakup in pure He targets and the divergence was found to increase with gas mixture pressure.

Pressed boride cathodes

NASA Technical Reports Server (NTRS)

Wolski, W.

1985-01-01

Results of experimental studies of emission cathodes made from lanthanum, yttrium, and gadolinium hexaborides are presented. Maximum thermal emission was obtained from lanthanum hexaboride electrodes. The hexaboride cathodes operated stably under conditions of large current density power draw, at high voltages and poor vacuum. A microtron electron gun with a lanthanum hexaboride cathode is described.

On a new scenario for the saturation of the low-threshold two-plasmon parametric decay instability of an extraordinary wave in the inhomogeneous plasma of magnetic traps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gusakov, E. Z., E-mail: Evgeniy.Gusakov@mail.ioffe.ru; Popov, A. Yu., E-mail: a.popov@mail.ioffe.ru; Irzak, M. A., E-mail: irzak@mail.ioffe.ru

The most probable scenario for the saturation of the low-threshold two-plasmon parametric decay instability of an electron cyclotron extraordinary wave has been analyzed. Within this scenario two upperhybrid plasmons at frequencies close to half the pump wave frequency radially trapped in the vicinity of the local maximum of the plasma density profile are excited due to the excitation of primary instability. The primary instability saturation results from the decays of the daughter upper-hybrid waves into secondary upperhybrid waves that are also radially trapped in the vicinity of the local maximum of the plasma density profile and ion Bernstein waves.

Ionosphere variability during the 2009 SSW: Influence of the lunar semidiurnal tide and mechanisms producing electron density variability

NASA Astrophysics Data System (ADS)

Pedatella, N. M.; Liu, H.-L.; Sassi, F.; Lei, J.; Chau, J. L.; Zhang, X.

2014-05-01

To investigate ionosphere variability during the 2009 sudden stratosphere warming (SSW), we present simulation results that combine the Whole Atmosphere Community Climate Model Extended version and the thermosphere-ionosphere-mesosphere electrodynamics general circulation model (TIME-GCM). The simulations reveal notable enhancements in both the migrating semidiurnal solar (SW2) and lunar (M2) tides during the SSW. The SW2 and M2 amplitudes reach ˜50 m s-1 and ˜40 m s-1, respectively, in zonal wind at E region altitudes. The dramatic increase in the M2 at these altitudes influences the dynamo generation of electric fields, and the importance of the M2 on the ionosphere variability during the 2009 SSW is demonstrated by comparing simulations with and without the M2. TIME-GCM simulations that incorporate the M2 are found to be in good agreement with Jicamarca Incoherent Scatter Radar vertical plasma drifts and Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) observations of the maximum F region electron density. The agreement with observations is worse if the M2 is not included in the simulation, demonstrating that the lunar tide is an important contributor to the ionosphere variability during the 2009 SSW. We additionally investigate sources of the F region electron density variability during the SSW. The primary driver of the electron density variability is changes in electric fields. Changes in meridional neutral winds and thermosphere composition are found to also contribute to the electron density variability during the 2009 SSW. The electron density variability for the 2009 SSW is therefore not solely due to variability in electric fields as previously thought.

Deformation behavior and spall fracture of the Hadfield steel under shock-wave loading

NASA Astrophysics Data System (ADS)

Gnyusov, S. F.; Rotshtein, V. P.; Polevin, S. D.; Kitsanov, S. A.

2011-03-01

Comparative studies of regularities in plastic deformation and fracture of the Hadfield polycrystalline steel upon quasi-static tension, impact failure, and shock-wave loading with rear spall are performed. The SINUS-7 accelerator was used as a shock-wave generator. The electron beam parameters of the accelerator were the following: maximum electron energy was 1.35 MeV, pulse duration at half-maximum was 45 ns, maximum energy density on a target was 3.4·1010 W/cm2, shock-wave amplitude was ~20 GPa, and strain rate was ~106 s-1. It is established that the failure mechanism changes from ductile transgranular to mixed ductile-brittle intergranular one when going from quasi-static tensile and Charpy impact tests to shock-wave loading. It is demonstrated that a reason for the intergranular spallation is the strain localization near the grain boundaries containing a carbide interlayer.

Ionization equilibrium and radiative energy loss rates for C, N, and O ions in low-density plasmas

NASA Technical Reports Server (NTRS)

Jacobs, V. L.; Davis, J.; Rogerson, J. E.; Blaha, M.

1978-01-01

The results of calculations of the ionization equilibrium and radiative energy loss rates for C, N and O ions in low-density plasmas are presented for electron temperatures in the range 10,000-10,000,000 K. The ionization structure is determined by using the steady-state corona model, in which electron impact ionization from the ground states is balanced by direct radiative and dielectronic recombination. With an improved theory, detailed calculations are carried out for the dielectronic recombination rates in which account is taken of all radiative and autoionization processes involving a single-electron electric-dipole transition of the recombining ion. The radiative energy loss processes considered are electron-impact excitation of resonance line emission, direct radiative recombination, dielectronic recombination, and electron-ion bremsstrahlung. For all three elements, resonance line emission resulting from 2s-2p transitions produces a broad maximum in the energy loss rate near 100,000 K.

Helicon normal modes in Proto-MPEX

NASA Astrophysics Data System (ADS)

Piotrowicz, P. A.; Caneses, J. F.; Green, D. L.; Goulding, R. H.; Lau, C.; Caughman, J. B. O.; Rapp, J.; Ruzic, D. N.

2018-05-01

The Proto-MPEX helicon source has been operating in a high electron density ‘helicon-mode’. Establishing plasma densities and magnetic field strengths under the antenna that allow for the formation of normal modes of the fast-wave are believed to be responsible for the ‘helicon-mode’. A 2D finite-element full-wave model of the helicon antenna on Proto-MPEX is used to identify the fast-wave normal modes responsible for the steady-state electron density profile produced by the source. We also show through the simulation that in the regions of operation in which core power deposition is maximum the slow-wave does not deposit significant power besides directly under the antenna. In the case of a simulation where a normal mode is not excited significant edge power is deposited in the mirror region. ).

Helicon normal modes in Proto-MPEX

DOE Office of Scientific and Technical Information (OSTI.GOV)

Piotrowicz, Pawel A.; Caneses, Juan F.; Green, David L.

Here, the Proto-MPEX helicon source has been operating in a high electron density 'helicon-mode'. Establishing plasma densities and magnetic field strengths under the antenna that allow for the formation of normal modes of the fast-wave are believed to be responsible for the 'helicon-mode'. A 2D finite-element full-wave model of the helicon antenna on Proto-MPEX is used to identify the fast-wave normal modes responsible for the steady-state electron density profile produced by the source. We also show through the simulation that in the regions of operation in which core power deposition is maximum the slow-wave does not deposit significant power besidesmore » directly under the antenna. In the case of a simulation where a normal mode is not excited significant edge power is deposited in the mirror region.« less

Helicon normal modes in Proto-MPEX

DOE PAGES

Piotrowicz, Pawel A.; Caneses, Juan F.; Green, David L.; ...

2018-05-22

Here, the Proto-MPEX helicon source has been operating in a high electron density 'helicon-mode'. Establishing plasma densities and magnetic field strengths under the antenna that allow for the formation of normal modes of the fast-wave are believed to be responsible for the 'helicon-mode'. A 2D finite-element full-wave model of the helicon antenna on Proto-MPEX is used to identify the fast-wave normal modes responsible for the steady-state electron density profile produced by the source. We also show through the simulation that in the regions of operation in which core power deposition is maximum the slow-wave does not deposit significant power besidesmore » directly under the antenna. In the case of a simulation where a normal mode is not excited significant edge power is deposited in the mirror region.« less

Generalized Lenard-Balescu calculations of electron-ion temperature relaxation in beryllium plasma.

PubMed

Fu, Zhen-Guo; Wang, Zhigang; Li, Da-Fang; Kang, Wei; Zhang, Ping

2015-09-01

The problem of electron-ion temperature relaxation in beryllium plasma at various densities (0.185-18.5g/cm^{3}) and temperatures [(1.0-8)×10^{3} eV] is investigated by using the generalized Lenard-Balescu theory. We consider the correlation effects between electrons and ions via classical and quantum static local field corrections. The numerical results show that the electron-ion pair distribution function at the origin approaches the maximum when the electron-electron coupling parameter equals unity. The classical result of the Coulomb logarithm is in agreement with the quantum result in both the weak (Γ_{ee}<10^{-2}) and strong (Γ_{ee}>1) electron-electron coupling ranges, whereas it deviates from the quantum result at intermediate values of the coupling parameter (10^{-2}<Γ_{ee}<1). We find that with increasing density of Be, the Coulomb logarithm will decrease and the corresponding relaxation rate ν_{ie} will increase. In addition, a simple fitting law ν_{ie}/ν_{ie}^{(0)}=a(ρ_{Be}/ρ_{0})^{b} is determined, where ν_{ie}^{(0)} is the relaxation rate corresponding to the normal metal density of Be and ρ_{0}, a, and b are the fitting parameters related to the temperature and the degree of ionization 〈Z〉 of the system. Our results are expected to be useful for future inertial confinement fusion experiments involving Be plasma.

DFT calculations of graphene monolayer in presence of Fe dopant and vacancy

NASA Astrophysics Data System (ADS)

Ostovari, Fatemeh; Hasanpoori, Marziyeh; Abbasnejad, Mohaddeseh; Salehi, Mohammad Ali

2018-07-01

In the present work, the effects of Fe doping and vacancies on the electronic, magnetic and optical properties of graphene are studied by density functional theory based calculations. The conductive behavior is revealed for the various defected graphene by means of electronic density of states. However, defected structures show different magnetic and optical properties compared to those of pure one. The ferromagnetic phase is the most probable phase by substituting Fe atoms and vacancies at AA sublattice of graphene. The optical properties of impure graphene differ from pure graphene under illumination with parallel polarization of electric field, whereas for perpendicular polarization it remains unchanged. In presence of defect and under parallel polarization of light, the static dielectric constant rises strongly and the maximum peak of Im ε(ω) shows red shift relative to pure graphene. Moreover, the maximum absorption peak gets broaden in the visible to infrared region at the same condition and the magnitude and related energy of peaks shift to higher value in the EELS spectra. Furthermore, the results show that the maximum values of refractive index and reflectivity spectra increase rapidly and represent the red and blue shifts; respectively. Generally; substituting the C atom with Fe has more effect on magnetic and optical properties relative to the C vacancies.

PREDICTIONS OF ION PRODUCTION RATES AND ION NUMBER DENSITIES WITHIN THE DIAMAGNETIC CAVITY OF COMET 67P/CHURYUMOV-GERASIMENKO AT PERIHELION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vigren, E.; Galand, M., E-mail: e.vigren@imperial.ac.uk

2013-07-20

We present a one-dimensional ion chemistry model of the diamagnetic cavity of comet 67P/Churyumov-Gerasimenko, the target comet for the ESA Rosetta mission. We solve the continuity equations for ionospheric species and predict number densities of electrons and selected ions considering only gas-phase reactions. We apply the model to the subsolar direction and consider conditions expected to be encountered by Rosetta at perihelion (1.29 AU) in 2015 August. Our default simulation predicts a maximum electron number density of {approx}8 Multiplication-Sign 10{sup 4} cm{sup -3} near the surface of the comet, while the electron number densities for cometocentric distances r > 10more » km are approximately proportional to 1/r {sup 1.23} assuming that the electron temperature is equal to the neutral temperature. We show that even a small mixing ratio ({approx}0.3%-1%) of molecules having higher proton affinity than water is sufficient for the proton transfer from H{sub 3}O{sup +} to occur so readily that other ions than H{sub 3}O{sup +}, such as NH{sub 4} {sup +} or CH{sub 3}OH{sub 2} {sup +}, become dominant in terms of volume mixing ratio in part of, if not throughout, the diamagnetic cavity. Finally, we test how the predicted electron and ion densities are influenced by changes of model input parameters, including the neutral background, the impinging EUV solar spectrum, the solar zenith angle, the cross sections for photo- and electron-impact processes, the electron temperature profile, and the temperature dependence of ion-neutral reactions.« less

Reconstruction of the ionospheric electron density by geostatistical inversion

NASA Astrophysics Data System (ADS)

Minkwitz, David; van den Boogaart, Karl Gerald; Hoque, Mainul; Gerzen, Tatjana

2015-04-01

The ionosphere is the upper part of the atmosphere where sufficient free electrons exist to affect the propagation of radio waves. Typically, the ionosphere extends from about 50 - 1000 km and its morphology is mainly driven by solar radiation, particle precipitation and charge exchange. Due to the strong ionospheric impact on many applications dealing with trans-ionospheric signals such as Global Navigation Satellite Systems (GNSS) positioning, navigation and remote sensing, the demand for a highly accurate reconstruction of the electron density is ever increasing. Within the Helmholtz Alliance project "Remote Sensing and Earth System Dynamics" (EDA) the utilization of the upcoming radar mission TanDEM-L and its related products are prepared. The TanDEM-L mission will operate in L-band with a wavelength of approximately 24 cm and aims at an improved understanding of environmental processes and ecosystem change, e.g. earthquakes, volcanos, glaciers, soil moisture and carbon cycle. Since its lower frequency compared to the X-band (3 cm) and C-band (5 cm) radar missions, the influence of the ionosphere will increase and might lead to a significant degradation of the radar image quality if no correction is applied. Consequently, our interest is the reconstruction of the ionospheric electron density in order to mitigate the ionospheric delay. Following the ionosphere's behaviour we establish a non-stationary and anisotropic spatial covariance model of the electron density separated into a vertical and horizontal component. In order to estimate the model's parameters we chose a maximum likelihood approach. This approach incorporates GNSS total electron content measurements, representing integral measurements of the electron density between satellite to receiver ray paths, and the NeQuick model as a non-stationary trend. Based on a multivariate normal distribution the spatial covariance model parameters are optimized and afterwards the 3D electron density can be calculated by kriging for arbitrary points or grids of interest.

Magnetotransport studies of mobility limiting mechanisms in undoped Si/SiGe heterostructures

NASA Astrophysics Data System (ADS)

Mi, X.; Hazard, T. M.; Payette, C.; Wang, K.; Zajac, D. M.; Cady, J. V.; Petta, J. R.

2015-07-01

We perform detailed magnetotransport studies on two-dimensional electron gases (2DEGs) formed in undoped Si/SiGe heterostructures in order to identify the electron mobility limiting mechanisms. By analyzing data from 26 different heterostructures, we observe a strong correlation between the background oxygen concentration in the Si quantum well and the maximum mobility. The highest-quality wafer supports a 2DEG with mobility μ =160 000 cm 2/Vs at a density n =2.17 ×1011 /cm 2 and exhibits a metal-to-insulator transition at a critical density nc=0.46 ×1011 /cm 2. We extract a valley splitting Δv˜150 μ eV at a magnetic field B =1.8 T. These results provide evidence that undoped Si/SiGe heterostructures are suitable for the fabrication of few-electron quantum dots.

Resistivity of a simple metal from room temperature to 10 to the 6th K

NASA Astrophysics Data System (ADS)

Milchberg, H. M.; Freeman, R. R.; Davey, S. C.; More, R. M.

1988-11-01

The resistivity of nearly solid-density Al was measured as a function of temperature over 4 orders of magnitude above ambient by observing the self-reflection of an intense, less than 0.5 psec, 308-nm light pulse incident on a planar Al target. As an increasing function of electron temperature, the resistivity is observed initially to increase, reach a maximum which is relatively constant over an extended temperature range, and then decrease at the highest temperatures. The broad maximum is interpreted as resistivity saturation, a condition in which the mean free path of the conduction electrons reaches a minimum value as a function of temperature, regardless of the extent of any further disorder in the material.

Calculation of effective atomic number and electron density of essential biomolecules for electron, proton, alpha particle and multi-energetic photon interactions

NASA Astrophysics Data System (ADS)

Kurudirek, Murat; Onaran, Tayfur

2015-07-01

Effective atomic numbers (Zeff) and electron densities (Ne) of some essential biomolecules have been calculated for total electron interaction, total proton interaction and total alpha particle interaction using an interpolation method in the energy region 10 keV-1 GeV. Also, the spectrum weighted Zeff for multi-energetic photons has been calculated using Auto-Zeff program. Biomolecules consist of fatty acids, amino acids, carbohydrates and basic nucleotides of DNA and RNA. Variations of Zeff and Ne with kinetic energy of ionizing charged particles and effective photon energies of heterogeneous sources have been studied for the given materials. Significant variations in Zeff and Ne have been observed through the entire energy region for electron, proton and alpha particle interactions. Non-uniform variation has been observed for protons and alpha particles in low and intermediate energy regions, respectively. The maximum values of Zeff have found to be in higher energies for total electron interaction whereas maximum values have found to be in relatively low energies for total proton and total alpha particle interactions. When it comes to the multi-energetic photon sources, it has to be noted that the highest Zeff values were found at low energy region where photoelectric absorption is the pre-dominant interaction process. The lowest values of Zeff have been shown in biomolecules such as stearic acid, leucine, mannitol and thymine, which have highest H content in their groups. Variation in Ne seems to be more or less the same with the variation in Zeff for the given materials as expected.

Fully non-inductive plasma start-up with lower-hybrid waves using the outboard-launch and top-launch antennas on the TST-2 spherical tokamak

NASA Astrophysics Data System (ADS)

Tsujii, Naoto; Takase, Yuichi; Ejiri, Akira; Shinya, Takahiro; Yajima, Satoru; Yamazaki, Hibiki; Togashi, Hiro; Moeller, Charles P.; Roidl, Benedikt; Takahashi, Wataru; Toida, Kazuya; Yoshida, Yusuke

2017-10-01

Removal of the central solenoid is essential to realize an economical spherical tokamak fusion reactor, but non-inductive plasma start-up is a challenge. On the TST-2 spherical tokamak, non-inductive plasma start-up using lower-hybrid (LH) waves has been investigated. Using the capacitively-coupled combline (CCC) antenna installed at the outboard midplane, fully non-inductive plasma current ramp-up up to a quarter of that of the typical Ohmic discharges has been achieved. Although it was desirable to keep the density low during the plasma current ramp-up to avoid the LH density limit, it was recognized that there was a maximum current density that could be carried by a given electron density. Since the density needed to increase as the plasma current was ramped-up, the achievable plasma current was limited by the maximum operational toroidal field of TST-2. The top-launch CCC antenna was installed to access higher density with up-shift of the parallel index of refraction. Numerical analysis of LH current drive with the outboard-launch and top-launch antennas was performed and the results were qualitatively consistent with the experimental observations.

How the laser-induced ionization of transparent solids can be suppressed

NASA Astrophysics Data System (ADS)

Gruzdev, Vitaly

2013-12-01

A capability to suppress laser-induced ionization of dielectric crystals in controlled and predictable way can potentially result in substantial improvement of laser damage threshold of optical materials. The traditional models that employ the Keldysh formula do not predict any suppression of the ionization because of the oversimplified description of electronic energy bands underlying the Keldysh formula. To fix this gap, we performed numerical simulations of time evolution of conduction-band electron density for a realistic cosine model of electronic bands characteristic of wide-band-gap cubic crystals. The simulations include contributions from the photo-ionization (evaluated by the Keldysh formula and by the formula for the cosine band of volume-centered cubic crystals) and from the avalanche ionization (evaluated by the Drude model). Maximum conduction-band electron density is evaluated from a single rate equation as a function of peak intensity of femtosecond laser pulses for alkali halide crystals. Results obtained for high-intensity femtosecond laser pulses demonstrate that the ionization can be suppressed by proper choice of laser parameters. In case of the Keldysh formula, the peak electron density exhibits saturation followed by gradual increase. For the cosine band, the electron density increases with irradiance within the low-intensity multiphoton regime and switches to decrease with intensity approaching threshold of the strong singularity of the ionization rate characteristic of the cosine band. Those trends are explained with specific modifications of band structure by electric field of laser pulses.

Electron density and currents of AlN/GaN high electron mobility transistors with thin GaN/AlN buffer layer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bairamis, A.; Zervos, Ch.; Georgakilas, A., E-mail: alexandr@physics.uoc.gr

2014-09-15

AlN/GaN high electron mobility transistor (HEMT) structures with thin GaN/AlN buffer layer have been analyzed theoretically and experimentally, and the effects of the AlN barrier and GaN buffer layer thicknesses on two-dimensional electron gas (2DEG) density and transport properties have been evaluated. HEMT structures consisting of [300 nm GaN/ 200 nm AlN] buffer layer on sapphire were grown by plasma-assisted molecular beam epitaxy and exhibited a remarkable agreement with the theoretical calculations, suggesting a negligible influence of the crystalline defects that increase near the heteroepitaxial interface. The 2DEG density varied from 6.8 × 10{sup 12} to 2.1 × 10{sup 13} cm{sup −2} as themore » AlN barrier thickness increased from 2.2 to 4.5 nm, while a 4.5 nm AlN barrier would result to 3.1 × 10{sup 13} cm{sup −2} on a GaN buffer layer. The 3.0 nm AlN barrier structure exhibited the highest 2DEG mobility of 900 cm{sup 2}/Vs for a density of 1.3 × 10{sup 13} cm{sup −2}. The results were also confirmed by the performance of 1 μm gate-length transistors. The scaling of AlN barrier thickness from 1.5 nm to 4.5 nm could modify the drain-source saturation current, for zero gate-source voltage, from zero (normally off condition) to 0.63 A/mm. The maximum drain-source current was 1.1 A/mm for AlN barrier thickness of 3.0 nm and 3.7 nm, and the maximum extrinsic transconductance was 320 mS/mm for 3.0 nm AlN barrier.« less

Comparison of SAR and induced current densities in adults and children exposed to electromagnetic fields from electronic article surveillance devices

NASA Astrophysics Data System (ADS)

Martínez-Búrdalo, M.; Sanchis, A.; Martín, A.; Villar, R.

2010-02-01

Electronic article surveillance (EAS) devices are widely used in most stores as anti-theft systems. In this work, the compliance with international guidelines in the human exposure to these devices is analysed by using the finite-difference time-domain (FDTD) method. Two sets of high resolution numerical phantoms of different size (REMCOM/Hershey and Virtual Family), simulating adult and child bodies, are exposed to a 10 MHz pass-by panel-type EAS consisting of two overlapping current-carrying coils. Two different relative positions between the EAS and the body (frontal and lateral exposures), which imply the exposure of different parts of the body at different distances, have been considered. In all cases, induced current densities in tissues of the central nervous system and specific absorption rates (SARs) are calculated to be compared with the limits from the guidelines. Results show that induced current densities are lower in the case of adult models as compared with those of children in both lateral and frontal exposures. Maximum SAR values calculated in lateral exposure are significantly lower than those calculated in frontal exposure, where the EAS-body distance is shorter. Nevertheless, in all studied cases, with an EAS driving current of 4 A rms, maximum induced current and SAR values are below basic restrictions.

Comparison of SAR and induced current densities in adults and children exposed to electromagnetic fields from electronic article surveillance devices.

PubMed

Martínez-Búrdalo, M; Sanchis, A; Martín, A; Villar, R

2010-02-21

Electronic article surveillance (EAS) devices are widely used in most stores as anti-theft systems. In this work, the compliance with international guidelines in the human exposure to these devices is analysed by using the finite-difference time-domain (FDTD) method. Two sets of high resolution numerical phantoms of different size (REMCOM/Hershey and Virtual Family), simulating adult and child bodies, are exposed to a 10 MHz pass-by panel-type EAS consisting of two overlapping current-carrying coils. Two different relative positions between the EAS and the body (frontal and lateral exposures), which imply the exposure of different parts of the body at different distances, have been considered. In all cases, induced current densities in tissues of the central nervous system and specific absorption rates (SARs) are calculated to be compared with the limits from the guidelines. Results show that induced current densities are lower in the case of adult models as compared with those of children in both lateral and frontal exposures. Maximum SAR values calculated in lateral exposure are significantly lower than those calculated in frontal exposure, where the EAS-body distance is shorter. Nevertheless, in all studied cases, with an EAS driving current of 4 A rms, maximum induced current and SAR values are below basic restrictions.

Maltodextrin-powered enzymatic fuel cell through a non-natural enzymatic pathway

NASA Astrophysics Data System (ADS)

Zhu, Zhiguang; Wang, Yiran; Minteer, Shelley D.; Percival Zhang, Y.-H.

Enzymatic fuel cells (EFCs) use a variety of fuels to generate electricity through oxidoreductase enzymes, such as oxidases or dehydrogenases, as catalysts on electrodes. We have developed a novel synthetic enzymatic pathway containing two free enzymes (maltodextrin phosphorylase and phosphoglucomutase) and one immobilized glucose-6-phosphate dehydrogenase that can utilize an oligomeric substrate maltodextrin for producing electrons mediated via a diaphorase and vitamin K 3 electron shuttle system. Three different enzyme immobilization approaches were compared based on electrostatic force entrapment, chemical cross-linking, and cross-linking with the aid of carbon nanotubes. At 10 mM glucose-6-phosphate (G6P) as a substrate concentration, the maximum power density of 0.06 mW cm -2 and retaining 42% of power output after 11 days were obtained through the method of chemical cross-linking with carbon nanotubes, approximately 6-fold and 3.5-fold better than those of the electrostatic force-based method, respectively. When changed to maltodextrin (degree of polymerization = 19) as the substrate, the EFC achieved a maximum power density of 0.085 mW cm -2. With the advantages of stable, low cost, high energy density, non-inhibitor to enzymes, and environmental friendly, maltodextrin is suggested to be an ideal fuel to power enzymatic fuel cells.

Aluminum/vacuum multilayer configuration for spatial high-energy electron shielding via electron return effects induced by magnetic field.

PubMed

Chen, Tuo; Tang, Xiaobin; Chen, Feida; Ni, Minxuan; Huang, Hai; Zhang, Yun; Chen, Da

2017-06-26

Radiation shielding of high-energy electrons is critical for successful space missions. However, conventional passive shielding systems exhibit several limitations, such as heavy configuration, poor shielding ability, and strong secondary bremsstrahlung radiation. In this work, an aluminum/vacuum multilayer structure was proposed based on the electron return effects induced by magnetic field. The shielding property of several configurations was evaluated by using the Monte Carlo method. Results showed that multilayer systems presented improved shielding ability to electrons, and less secondary x-ray transmissions than those of conventional systems. Moreover, the influences of magnetic flux density and number of layers on the shielding property of multilayer systems were investigated using a female Chinese hybrid reference phantom based on cumulative dose. In the case of two aluminum layers, the cumulative dose in a phantom gradually decreased with increasing magnetic flux density. The maximum decline rate was found within 0.4-1 Tesla. With increasing layers of configuration, the cumulative dose decreased and the shielding ability improved. This research provides effective shielding measures for future space radiation protection in high-energy electron environments.

Understanding the Impact of Return-Current Losses on the X-Ray Emission from Solar Flares

NASA Technical Reports Server (NTRS)

Holman, Gordon D.

2012-01-01

I obtain and examine the implications of one-dimensional analytic solutions for return-current losses on an initially power-law distribution of energetic electrons with a sharp low-energy cutoff in flare plasma with classical (collisional) resistivity. These solutions show, for example, that return-current losses are not sensitive to plasma density, but are sensitive to plasma temperature and the low energy cutoff of the injected nonthermal electron distribution. A characteristic distance from the electron injection site, x(sub rc), is derived. At distances less than x(sub rc) the electron flux density is not reduced by return-current losses, but plasma heating can be substantial in this region, in the upper, coronal part of the flare loop. Before the electrons reach the collisional thick-target region of the flare loop, an injected power-law electron distribution with a low-energy cutoff maintains that structure, but with a flat energy distribution below the cutoff energy, which is now determined by the total potential drop experienced by the electrons. Modifications due to the presence of collisional losses are discussed. I compare these results with earlier analytical results and with more recent numerical simulations. Emslie's 1980 conjecture that there is a maximum integrated X-ray source brightness on the order of 10(exp -15) photons per square centimeter per second per square centimeter is examined. I find that this is not actually a maximum brightness and its value is parameter dependent, but it is nevertheless a valuable benchmark for identifying return-current losses in hard X-ray spectra. I discuss an observational approach to identifying return-current losses in flare data, including identification of a return-current "bump" in X-ray light curves at low photon energies.

Solar cyclic behavior of trapped energetic electrons in Earth's inner radiation belt

NASA Astrophysics Data System (ADS)

Abel, Bob; Thorne, Richard M.

1994-10-01

Magnetic electron spectrometer data from six satellites (OV3-3, OV1-14, OGO 5, S3-2, S3-3, and CRRES) have been used to study long-term (1966-1991) behavior of trapped energetic electrons in the inner radiation belt. Comparison of the observed energy spectra at L equal to or greater than 1.35 for different phases of the solar cycle reveals a clear trend toward enhanced fluxes during periods of solar maximum for energies below a few hundred keV; we suggest that this is caused by an increase in the rate of inward radial diffusion from a source at higher L. In contrast, for L less than 1.30, where atmospheric collisions become increasingly important, the electron flux is reduced during solar maximum; we attribute this to the expected increase in upper atmospheric densities. The electron flux above 1 MeV exhibits a systematic decay beyond 1979 to values well below the current NASA AE-8 model. This indicates that the natural background of high-energy electrons has previously been overestimated due to the long lasting presence of electrons produced by nuclear detonations in the upper atmosphere in the late 1950s and early 1960s.

Solar cyclic behavior of trapped energetic electrons in Earth's inner radiation belt

NASA Technical Reports Server (NTRS)

Abel, Bob; Thorne, Richard M.

1994-01-01

Magnetic electron spectrometer data from six satellites (OV3-3, OV1-14, OGO 5, S3-2, S3-3, and CRRES) have been used to study long-term (1966-1991) behavior of trapped energetic electrons in the inner radiation belt. Comparison of the observed energy spectra at L equal to or greater than 1.35 for different phases of the solar cycle reveals a clear trend toward enhanced fluxes during periods of solar maximum for energies below a few hundred keV; we suggest that this is caused by an increase in the rate of inward radial diffusion from a source at higher L. In contrast, for L less than 1.30, where atmospheric collisions become increasingly important, the electron flux is reduced during solar maximum; we attribute this to the expected increase in upper atmospheric densities. The electron flux above 1 MeV exhibits a systematic decay beyond 1979 to values well below the current NASA AE-8 model. This indicates that the natural background of high-energy electrons has previously been overestimated due to the long lasting presence of electrons produced by nuclear detonations in the upper atmosphere in the late 1950s and early 1960s.

Terawatt x-ray free-electron-laser optimization by transverse electron distribution shaping

DOE PAGES

Emma, C.; Wu, J.; Fang, K.; ...

2014-11-03

We study the dependence of the peak power of a 1.5 Å Terawatt (TW), tapered x-ray free-electron laser (FEL) on the transverse electron density distribution. Multidimensional optimization schemes for TW hard x-ray free-electron lasers are applied to the cases of transversely uniform and parabolic electron beam distributions and compared to a Gaussian distribution. The optimizations are performed for a 200 m undulator and a resonant wavelength of λ r = 1.5 Å using the fully three-dimensional FEL particle code GENESIS. The study shows that the flatter transverse electron distributions enhance optical guiding in the tapered section of the undulator andmore » increase the maximum radiation power from a maximum of 1.56 TW for a transversely Gaussian beam to 2.26 TW for the parabolic case and 2.63 TW for the uniform case. Spectral data also shows a 30%–70% reduction in energy deposited in the sidebands for the uniform and parabolic beams compared with a Gaussian. An analysis of the transverse coherence of the radiation shows the coherence area to be much larger than the beam spotsize for all three distributions, making coherent diffraction imaging experiments possible.« less

Graphene oxide electrocatalyst on MnO2 air cathode as an efficient electron pump for enhanced oxygen reduction in alkaline solution

NASA Astrophysics Data System (ADS)

Basirun, Wan Jeffrey; Sookhakian, Mehran; Baradaran, Saeid; Endut, Zulkarnain; Mahmoudian, Mohammad Reza; Ebadi, Mehdi; Yousefi, Ramin; Ghadimi, Hanieh; Ahmed, Sohail

2015-03-01

Graphene oxide (GO) was deposited on the surface of a MnO2 air cathode by thermal evaporation at 50°C from a GO colloidal suspension. Fourier transformed infrared spectroscopy and field emission scanning electron microscopy confirmed the presence of GO on the MnO2 air cathode (GO-MnO2). Voltammetry and chrono-amperometry showed increased currents for the oxygen reduction reaction (ORR) in 6 M KOH solution for GO-MnO2 compared to the MnO2 cathode. The GO-MnO2 was used as an air cathode in an alkaline tin-air cell and produced a maximum power density of 13 mW cm-2, in contrast to MnO2, which produced a maximum power density of 9.2 mW cm-2. The electrochemical impedance spectroscopy results suggest that the chemical step for the ORR is the rate determining step, as proposed earlier by different researchers. It is suggested that the presence of GO and electrochemically reduced graphene oxide (ERGO) on the MnO2 surface are responsible for the increased rate of this step, whereby GO and ERGO accelerate the process of electron donation to the MnO2 and to adsorbed oxygen atoms.

Exciton Absorption in Semiconductor Quantum Wells Driven by a Strong Intersubband Pump Field

NASA Technical Reports Server (NTRS)

Liu, Ansheng; Ning, Cun-Zheng

1999-01-01

Optical interband excitonic absorption of semiconductor quantum wells (QW's) driven by a coherent pump field is investigated based on semiconductor Bloch equations. The pump field has a photon energy close to the intersubband spacing between the first two conduction subbands in the QW's. An external weak optical field probes the interband transition. The excitonic effects and pump-induced population redistribution within the conduction subbands in the QW system are included. When the density of the electron-hole pairs in the QW structure is low, the pump field induces an Autler-Townes splitting of the exciton absorption spectrum. The split size and the peak positions of the absorption doublet depend not only on the pump frequency and intensity but also on the carrier density. As the density of the electron-hole pairs is increased, the split contrast (the ratio between the maximum and minimum values) is decreased because the exciton effect is suppressed at higher densities due to the many-body screening.

Electron holes in phase space: What they are and why they matter

NASA Astrophysics Data System (ADS)

Hutchinson, I. H.

2017-05-01

This is a tutorial and selective review explaining the fundamental concepts and some currently open questions concerning the plasma phenomenon of the electron hole. The widespread occurrence of electron holes in numerical simulations, space-craft observations, and laboratory experiments is illustrated. The elementary underlying theory is developed of a one-dimensional electron hole as a localized potential maximum, self-consistently sustained by a deficit of trapped electron phase-space density. The spatial extent of a hole is typically a few Debye lengths; what determines the minimum and maximum possible lengths is explained, addressing the key aspects of the as yet unsettled dispute between the integral and differential approaches to hole structure. In multiple dimensions, holes tend to form less readily; they generally require a magnetic field and distribution-function anisotropy. The mechanisms by which they break up are explained, noting that this transverse instability is not fully understood. Examples are given of plasma circumstances where holes play an important role, and of recent progress on understanding their holistic kinematics and self-acceleration.

Design, construction and performance evaluation of the target tissue thickness measurement system in intraoperative radiotherapy for breast cancer

NASA Astrophysics Data System (ADS)

Yazdani, Mohammad Reza; Setayeshi, Saeed; Arabalibeik, Hossein; Akbari, Mohammad Esmaeil

2017-05-01

Intraoperative electron radiation therapy (IOERT), which uses electron beams for irradiating the target directly during the surgery, has the advantage of delivering a homogeneous dose to a controlled layer of tissue. Since the dose falls off quickly below the target thickness, the underlying normal tissues are spared. In selecting the appropriate electron energy, the accuracy of the target tissue thickness measurement is critical. In contrast to other procedures applied in IOERT, the routine measurement method is considered to be completely traditional and approximate. In this work, a novel mechanism is proposed for measuring the target tissue thickness with an acceptable level of accuracy. An electronic system has been designed and manufactured with the capability of measuring the tissue thickness based on the recorded electron density under the target. The results indicated the possibility of thickness measurement with a maximum error of 2 mm for 91.35% of data. Aside from system limitation in estimating the thickness of 5 mm phantom, for 88.94% of data, maximum error is 1 mm.

Low-energy plasma focus device as an electron beam source.

PubMed

Khan, Muhammad Zubair; Ling, Yap Seong; Yaqoob, Ibrar; Kumar, Nitturi Naresh; Kuang, Lim Lian; San, Wong Chiow

2014-01-01

A low-energy plasma focus device was used as an electron beam source. A technique was developed to simultaneously measure the electron beam intensity and energy. The system was operated in Argon filling at an optimum pressure of 1.7 mbar. A Faraday cup was used together with an array of filtered PIN diodes. The beam-target X-rays were registered through X-ray spectrometry. Copper and lead line radiations were registered upon usage as targets. The maximum electron beam charge and density were estimated to be 0.31 μC and 13.5 × 10(16)/m(3), respectively. The average energy of the electron beam was 500 keV. The high flux of the electron beam can be potentially applicable in material sciences.

Light programmable organic transistor memory device based on hybrid dielectric

NASA Astrophysics Data System (ADS)

Ren, Xiaochen; Chan, Paddy K. L.

2013-09-01

We have fabricated the transistor memory devices based on SiO2 and polystyrene (PS) hybrid dielectric. The trap states densities with different semiconductors have been investigated and a maximum 160V memory window between programming and erasing is realized. For DNTT based transistor, the trapped electron density is limited by the number of mobile electrons in semiconductor. The charge transport mechanism is verified by light induced Vth shift effect. Furthermore, in order to meet the low operating power requirement of portable electronic devices, we fabricated the organic memory transistor based on AlOx/self-assembly monolayer (SAM)/PS hybrid dielectric, the effective capacitance of hybrid dielectric is 210 nF cm-2 and the transistor can reach saturation state at -3V gate bias. The memory window in transfer I-V curve is around 1V under +/-5V programming and erasing bias.

The equatorial airglow and the ionospheric geomagnetic anomaly

NASA Technical Reports Server (NTRS)

Chandra, S.; Reed, E. I.; Troy, B. E., Jr.; Blamont, J. E.

1972-01-01

OGO D observations of OI (6300A) emissions reveal a global pattern in the equatorial airglow undetected from the ground-based observations. The post sunset emission rate of OI is generally asymmetrical with respect to the geomagnetic equator and shows no apparent correlation with the ultraviolet airglow (OI 1304 and 1356A) and F region electron density measured simultaneously from the same spacecraft. Both the ultraviolet airglow and the ion density measured in the altitude region of 450 km follow similar latitudinal variations and exhibit properties of the equatorial ionospheric anomaly. The asymmetry in OI emission can be attributed to the asymmetry in the height of the F 2 maximum inferred from the height of the maximum emission. From correlative studies of the airglow and the ionospheric measurements, the mechanisms for the ultraviolet and the 6300A emission are discussed in terms of the processes involving radiative and dissociative recombinations. A relationship between molecular oxygen density and the integrated OI emission rate is derived and the feasibility of using this relationship for estimating O2 density is discussed.

Ionospheric variations during sudden stratospheric warming in the high- and mid-latitude regions

NASA Astrophysics Data System (ADS)

Yasyukevich, Anna; Voeykov, Sergey; Mylnikova, Anna

2017-04-01

The ionospheric dynamic in the high- and middle-latitude regions during the periods of sudden stratospheric warmings (SSW) was studied by using the international network of phase dual-frequency GPS/GLONASS receivers and the vertical sounding data. Twelve SSW events that occurred in the Northern Hemisphere 2006 through 2013 were considered. In order to identify the possible response of the ionosphere to SSW events, we carried out the analysis of the total electron (TEC) and the F2-layer maximum electron density (NmF2) deviations from the background level. We have also studied changes of the level of total electron content (TEC) wave-like variations characterized by a special index WTEC. The index reflects the intensity of medium- and large-scale traveling ionospheric disturbances. The dynamics of the high- and middle-latitude ionosphere at the points near the SSW areas was found to differ from the regular. For a large number of events, it is shown that, despite quiet geomagnetic conditions, a noticeable decrease in the NmF2 and TEC values (by 5-10% relative to the background level) is observed during the SSW evolution and maximum stages. On the contrary, for 10-20 days after the SSW maxima, NmF2 and TEC significantly exceed the monthly averaged values. Moreover, these electron density changes are observed for both strong and weak stratospheric warmings, and are recorded mainly during daytime. The observed SSW effects in the polar and mid-latitude ionosphere are assumed to be probably associated with the changes in the neutral composition at the thermospheric heights that affect the F2-layer electron density. The study is supported by the Russian Foundation for Basic Research under Grant No. 16-35-60018, as well as by the RF President Grant of Public Support for RF Leading Scientific Schools (NSh-6894.2016.5).

Equatorial heating and hemispheric decoupling effects on inner magnetospheric core plasma evolution

NASA Technical Reports Server (NTRS)

Lin, J.; Horwitz, J. L.; Wilson, G. R.; Brown, D. G.

1994-01-01

We have extended our previous semikinetic study of early stage plasmasphere refilling with perpendicular ion heating by removing the restriction that the northern and southern boundaries are identical and incorporating a generalized transport description for the electrons. This allows investigation of the effects of electron heating and a more realistic calculation of electric fields produced by ion and electron temperature anisotropies. The combination of perpendicular ion heating and parallel electron heating leads to an equatorial electrostatic potential peak, which tends to shield and decouple ion flows in the northern and southern hemispheres. Unequal ionospheric upflows in the northern and southern hemispheres lead to the development of distinctly asymmetric densities and other bulk parameters. At t = 5 hour after the initiation of refiling with different source densities (N(sub north) = 100 cu/cm, N(sub south) = 50 cu/cm), the maximum potential drops of the northern and southern hemispheres are 0.6 and 1.3 V, respectively. At this time the minimum ion densities are 11 and 7 cu/cm for the northern and southern hemispheres. DE 1 observations of asymmetric density profiles by Olsen may be consistent with these predictions. Termination of particle heating causes the reduction of equatorial potential and allows interhemispheric coupling. When the inflows from the ionospheres are reduced (as may occur after sunset), decreases in plasma density near the ionospheric regions are observed while the heated trapped ion population at the equator persists.

The upgrade of the Thomson scattering system for measurement on the C-2/C-2U devices.

PubMed

Zhai, K; Schindler, T; Kinley, J; Deng, B; Thompson, M C

2016-11-01

The C-2/C-2U Thomson scattering system has been substantially upgraded during the latter phase of C-2/C-2U program. A Rayleigh channel has been added to each of the three polychromators of the C-2/C-2U Thomson scattering system. Onsite spectral calibration has been applied to avoid the issue of different channel responses at different spots on the photomultiplier tube surface. With the added Rayleigh channel, the absolute intensity response of the system is calibrated with Rayleigh scattering in argon gas from 0.1 to 4 Torr, where the Rayleigh scattering signal is comparable to the Thomson scattering signal at electron densities from 1 × 10 13 to 4 × 10 14 cm -3 . A new signal processing algorithm, using a maximum likelihood method and including detailed analysis of different noise contributions within the system, has been developed to obtain electron temperature and density profiles. The system setup, spectral and intensity calibration procedure and its outcome, data analysis, and the results of electron temperature/density profile measurements will be presented.

MeV electron acceleration at 1kHz with <10 mJ laser pulses

NASA Astrophysics Data System (ADS)

Salehi, Fatholah; Goers, Andy; Hine, George; Feder, Linus; Kuk, Donghoon; Kim, Ki-Yong; Milchberg, Howard

2016-10-01

We demonstrate laser driven acceleration of electrons at 1 kHz repetition rate with pC charge above 1MeV per shot using < 10 mJ pulse energies focused on a near-critical density He or H2 gas jet. Using the H2 gas jet, electron acceleration to 0.5 MeV in 10 fC bunches was observed with laser pulse energy as low as 1.3mJ . Using a near-critical density gas jet sets the critical power required for relativistic self-focusing low enough for mJ scale laser pulses to self- focus and drive strong wakefields. Experiments and particle-in-cell simulations show that optimal drive pulse duration and chirp for maximum electron bunch charge and energy depends on the target gas species. High repetition rate, high charge, and short duration electron bunches driven by very modest pulse energies constitutes an ideal portable electron source for applications such as ultrafast electron diffraction experiments and high rep. rate γ-ray production. This work is supported by the US Department of Energy, the National Science Foundation, and the Air Force Office of Scientific Research.

Spatial Structure of Large-Scale Plasma Density Perturbations HF-Induced in the Ionospheric F 2 Region

NASA Astrophysics Data System (ADS)

Frolov, V. L.; Komrakov, G. P.; Glukhov, Ya. V.; Andreeva, E. S.; Kunitsyn, V. E.; Kurbatov, G. A.

2016-07-01

We consider the experimental results obtained by studying the large-scale structure of the HF-disturbed ionospheric region. The experiments were performed using the SURA heating facility. The disturbed ionospheric region was sounded by signals radiated by GPS navigation satellite beacons as well as by signals of low-orbit satellites (radio tomography). The results of the experiments show that large-scale plasma density perturbations induced at altitudes higher than the F2 layer maximum can contribute significantly to the measured variations of the total electron density and can, with a certain arrangement of the reception points, be measured by the GPS sounding method.

Balancing the Electron and Hole Transfer for Efficient Quantum Dot Light-Emitting Diodes by Employing a Versatile Organic Electron-Blocking Layer.

PubMed

Jin, Xiao; Chang, Chun; Zhao, Weifeng; Huang, Shujuan; Gu, Xiaobing; Zhang, Qin; Li, Feng; Zhang, Yubao; Li, Qinghua

2018-05-09

The electron-blocking layer (EBL) is important to balance the charge carrier transfer and achieve highly efficient quantum dot light-emitting diodes (QLEDs). Here, we report the utilization of a soluble tert-butyldimethylsilyl chloride-modified poly( p-phenylene benzobisoxazole) (TBS-PBO) as an EBL for simultaneous good charge carrier transfer balance while maintaining a high current density. We show that the versatile TBS-PBO blocks excess electron injection into the quantum dots (QDs), thus leading to better charge carrier transfer balance. It also restricts the undesired QD-to-EBL electron-transfer process, which preserves the superior emission capabilities of the emitter. As a consequence, the TBS-PBO device delivers an external quantum efficiency (EQE) maximum of 16.7% along with a remarkable current density as high as 139 mA/cm 2 with a brightness of 5484 cd/m 2 . The current density of our device is higher than those of insulator EBL-based devices because of the higher conductivity of the TBS-PBO versus insulator EBL, thus helping achieve high luminance values ranging from 1414 to 20 000 cd/cm 2 with current densities ranging from 44 to 648 mA/cm 2 and EQE > 14%. We believe that these unconventional features of the present TBS-PBO-based QLEDs will expand the wide use of TBS-PBO as buffer layers in other advanced QLED applications.

Suppressed carrier density for the patterned high mobility two-dimensional electron gas at γ-Al2O3/SrTiO3 heterointerfaces

NASA Astrophysics Data System (ADS)

Niu, Wei; Gan, Yulin; Zhang, Yu; Valbjørn Christensen, Dennis; von Soosten, Merlin; Wang, Xuefeng; Xu, Yongbing; Zhang, Rong; Pryds, Nini; Chen, Yunzhong

2017-07-01

The two-dimensional electron gas (2DEG) at the non-isostructural interface between spinel γ-Al2O3 and perovskite SrTiO3 is featured by a record electron mobility among complex oxide interfaces in addition to a high carrier density up to the order of 1015 cm-2. Herein, we report on the patterning of 2DEG at the γ-Al2O3/SrTiO3 interface grown at 650 °C by pulsed laser deposition using a hard mask of LaMnO3. The patterned 2DEG exhibits a critical thickness of 2 unit cells of γ-Al2O3 for the occurrence of interface conductivity, similar to the unpatterned sample. However, its maximum carrier density is found to be approximately 3 × 1013 cm-2, much lower than that of the unpatterned sample (˜1015 cm-2). Remarkably, a high electron mobility of approximately 3600 cm2 V-1 s-1 was obtained at low temperatures for the patterned 2DEG at a carrier density of ˜7 × 1012 cm-2, which exhibits clear Shubnikov-de Haas quantum oscillations. The patterned high-mobility 2DEG at the γ-Al2O3/SrTiO3 interface paves the way for the design and application of spinel/perovskite interfaces for high-mobility all-oxide electronic devices.

Design and Analysis of an Electromagnetic Thrust Bearing

NASA Technical Reports Server (NTRS)

Banerjee, Bibhuti; Rao, Dantam K.

1996-01-01

A double-acting electromagnetic thrust bearing is normally used to counter the axial loads in many rotating machines that employ magnetic bearings. It essentially consists of an actuator and drive electronics. Existing thrust bearing design programs are based on several assumptions. These assumptions, however, are often violated in practice. For example, no distinction is made between maximum external loads and maximum bearing forces, which are assumed to be identical. Furthermore, it is assumed that the maximum flux density in the air gap occurs at the nominal gap position of the thrust runner. The purpose of this paper is to present a clear theoretical basis for the design of the electromagnetic thrust bearing which obviates such assumptions.

A model for chorus associated electrostatic bursts

NASA Technical Reports Server (NTRS)

Grabbe, C. L.

1984-01-01

The linear theory of the generation of electrostatic bursts of noise by electrons trapped in chorus wave packets is developed for a finite temperature electron beam and a Maxwellian elecron and ion background. The growth rates determined qualitatively in good agreement with those obtained by previous authors from a more idealized model. Two connected instability mechanisms seem to be occurring: a beam plasma (electron-ion two-stream) instability commonly associated with intensification of the chorus power levels, and a transitional or borderline resistive medium instability commonly associated with chorus hooks. The physical reasons for the two mechanisms is discussed. In the second case electron beams are difficult to identify in the particle data. An expression is obtained for the maximum growth rate in terms of the ratios of the beam and electron thermal velocities to the beam velocity, and of the beam density to plasma density. It is anticipated that this may allow the observed peak in the electrostatic noise spectrum to be used as a diagnostic for the beam characteristics. Previously announced in STAR as N84-12832

Quasiparticle and hybrid density functional methods in defect studies: An application to the nitrogen vacancy in GaN

NASA Astrophysics Data System (ADS)

Lewis, D. K.; Matsubara, M.; Bellotti, E.; Sharifzadeh, S.

2017-12-01

Defects in semiconductors can play a vital role in the performance of electronic devices, with native defects often dominating the electronic properties of the semiconductor. Understanding the relationship between structural defects and electronic function will be central to the design of new high-performance materials. In particular, it is necessary to quantitatively understand the energy and lifetime of electronic states associated with the defect. Here, we apply first-principles density functional theory (DFT) and many-body perturbation theory within the GW approximation to understand the nature and energy of the defect states associated with a charged nitrogen vacancy on the electronic properties of gallium nitride (GaN), as a model of a well-studied and important wide gap semiconductor grown with defects. We systematically investigate the sources of error associated with the GW approximation and the role of the underlying atomic structure on the predicted defect state energies. Additionally, analysis of the computed electronic density of states (DOS) reveals that there is one occupied defect state 0.2 eV below the valence band maximum and three unoccupied defect states at energy of 0.2-0.4 eV above the conduction band minimum, suggesting that this defect in the +1 charge state will not behave as a carrier trap. Furthermore, we compare the character and energy of the defect state obtained from GW and DFT using the HSE approximate density functional and find excellent agreement. This systematic study provides a more complete understanding of how to obtain quantitative defect energy states in bulk semiconductors.

A miniature microbial fuel cell operating with an aerobic anode chamber

NASA Astrophysics Data System (ADS)

Ringeisen, Bradley R.; Ray, Ricky; Little, Brenda

A miniature microbial fuel cell (mini-MFC) is described that utilizes an aerobic culture of Shewanella oneidensis DSP10 as the active electrochemical species in the anode chamber. We find that the maximum aerobic mini-MFC power without the addition of exogenous mediators was 0.40 mW, a 33% decrease when compared with an anaerobic DSP10 culture (0.6 mW) operating in the mini-MFC. This decrease is most likely due to the presence of dissolved oxygen in the anode chamber that scavenges electrons to form water, thereby reducing the number of electrons donated to the anode. Aerobic power and current density at maximum power using the true surface area of the anode (611 cm 2) were calculated to be 6.5 mW m -2 and 13 mA m -2. The power density rises to 2.0 W m -2 and 330 W m -3 when calculated using the cross-sectional area and volume of the device (2 cm 2, 1.2 cm 3). The Coulombic efficiency was also reduced from 11 to 5% when using the aerobic versus anaerobic culture. Similar results were found when the external mediator anthraquinone-2,6-disulfonate (AQDS) was added to the aerobic culture, resulting in a maximum power of 0.54 mW, a 37% drop in power when compared to the anaerobic mediated system.

Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

NASA Astrophysics Data System (ADS)

Rauner, D.; Kurutz, U.; Fantz, U.

2015-04-01

As the negative hydrogen ion density nH- is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H- is measured directly, however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H- is produced in the plasma volume, laser photodetachment is applied as the standard method to measure nH-. The additional application of CRDS provides the possibility to directly obtain absolute values of nH-, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H- production and destruction processes. The modelled densities are adapted to the absolute measurements of nH- via CRDS, allowing to identify collisions of H- with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H- in the plasma volume at HOMER. Furthermore, the characteristic peak of nH- observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as ne determines the volume production rate via dissociative electron attachment to vibrationally excited hydrogen molecules.

Phenomenological theory of laser-plasma interaction in ``bubble'' regime

NASA Astrophysics Data System (ADS)

Kostyukov, I.; Pukhov, A.; Kiselev, S.

2004-11-01

The electron trapping in the "bubble" regime of laser-plasma interaction as proposed by Pukhov and Meyer-ter-Vehn [A. Pukhov and J. Meyer-ter-Vehn, Appl. Phys. B 74, 355 (2002)] is studied. In this regime the laser pulse generates a solitary plasma electron cavity: the bubble. It is free from the cold plasma electrons and runs with nearly light velocity. The present work discusses the form of the bubble and the spatial distribution of electromagnetic fields within the cavity. We extend the one-dimensional electron capture theory to the three-dimensional case. It is shown that the bubble can trap plasma electrons. The trapping condition is derived and the trapping cross section is estimated. Electron motion in the self-generated electron bunch is investigated. Estimates for the maximum of electron bunch energy and the bunch density are provided.

Low-Energy Plasma Focus Device as an Electron Beam Source

PubMed Central

Seong Ling, Yap; Naresh Kumar, Nitturi; Lian Kuang, Lim; Chiow San, Wong

2014-01-01

A low-energy plasma focus device was used as an electron beam source. A technique was developed to simultaneously measure the electron beam intensity and energy. The system was operated in Argon filling at an optimum pressure of 1.7 mbar. A Faraday cup was used together with an array of filtered PIN diodes. The beam-target X-rays were registered through X-ray spectrometry. Copper and lead line radiations were registered upon usage as targets. The maximum electron beam charge and density were estimated to be 0.31 μC and 13.5 × 1016/m3, respectively. The average energy of the electron beam was 500 keV. The high flux of the electron beam can be potentially applicable in material sciences. PMID:25544952

Effects of gas residence time of CH4/H2 on sp2 fraction of amorphous carbon films and dissociated methyl density during radical-injection plasma-enhanced chemical vapor deposition

NASA Astrophysics Data System (ADS)

Sugiura, Hirotsugu; Jia, Lingyun; Kondo, Hiroki; Ishikawa, Kenji; Tsutsumi, Takayoshi; Hayashi, Toshio; Takeda, Keigo; Sekine, Makoto; Hori, Masaru

2018-06-01

Quadruple mass spectrometric measurements of CH3 density during radical-injection plasma-enhanced chemical vapor deposition to consider the sp2 fraction of amorphous carbon (a-C) films were performed. The sp2 fraction of the a-C films reached a minimum of 46%, where the CH3 density was maximum for a residence time of 6 ms. The sp2 fraction of the a-C films was tailored with the gaseous phase CH3 density during the deposition. This knowledge is useful for understanding the formation mechanism of bonding structures in the a-C films, which enables the precise control of their electronic properties.

Cloth-Based Power Shirt for Wearable Energy Harvesting and Clothes Ornamentation.

PubMed

Li, Suling; Zhong, Qize; Zhong, Junwen; Cheng, Xiaofeng; Wang, Bo; Hu, Bin; Zhou, Jun

2015-07-15

Harvesting ambient mechanical energy from human body motion has attracted great research interest. In this work, a power shirt based on triboelectrification and the electrostatic induction effect between fluorinated ethylene propylene (FEP) and external objects is demonstrated. This power shirt can effectively convert the ambient mechanical energy into electric power, and the working mechanism is systematically discussed. A maximum short-circuit current density of ∼0.37 μA/cm2 and a maximum peak power density of ∼4.65 μW/cm2 were achieved. Simultaneously, 11 blue LEDs were lit by sliding the sleeve and power shirt, indicating the potential application of the power shirt in clothes ornamentation and risk warning. This study develops an efficient path for harvesting human body energy and promoting the development of wearable electronics and smart garments.

Preparation, electronic structure, and chemical bonding of lead-free (1 - x)(K0.5Bi0.5)TiO3- xBaTiO3 solid solution

NASA Astrophysics Data System (ADS)

Sasikumar, S.; Saravanan, R.; Saravanakumar, S.; Robert, M. Charles

2018-01-01

Polycrystalline lead-free (1 - x)(K0.5Bi0.5)TiO3- xBaTiO3, ((1 - x)KBT- xBT) ( x = 0.00, 0.08, 0.12) ceramics were synthesized via solid-state reaction method. The powder X-ray diffraction (PXRD) and structural refinement results confirm that a single-phase tetragonal structure with space group P4mm. Charge density distribution inside the unit cell of (1 - x)KBT- xBT was investigated by the maximum entropy method. Charge density analysis reveals the reduction in ionic nature along K/Bi-O bond and enhancement of covalent nature along Ti-O bond with the addition of BaTiO3. The charge density distribution studies done using maximum entropy method for (1 - x)KBT- xBT have not been done so far. The surface morphology study was done using scanning electron microscopy (SEM). Energy dispersive X-rays spectra (EDS) were used to investigate the elemental compositions present in the system. The dielectric constant and loss tangent were studied as a function of frequency. The dielectric constant and loss were decreased with increase of frequency. Room temperature dielectric constant ( ɛ) and loss (tan δ) were measured for x = 0.00 about 511 and 0.51, respectively, at a frequency of 10 kHz.

Communication: Improved ab initio molecular dynamics by minimally biasing with experimental data

NASA Astrophysics Data System (ADS)

White, Andrew D.; Knight, Chris; Hocky, Glen M.; Voth, Gregory A.

2017-01-01

Accounting for electrons and nuclei simultaneously is a powerful capability of ab initio molecular dynamics (AIMD). However, AIMD is often unable to accurately reproduce properties of systems such as water due to inaccuracies in the underlying electronic density functionals. This shortcoming is often addressed by added empirical corrections and/or increasing the simulation temperature. We present here a maximum-entropy approach to directly incorporate limited experimental data via a minimal bias. Biased AIMD simulations of water and an excess proton in water are shown to give significantly improved properties both for observables which were biased to match experimental data and for unbiased observables. This approach also yields new physical insight into inaccuracies in the underlying density functional theory as utilized in the unbiased AIMD.

Communication: Improved ab initio molecular dynamics by minimally biasing with experimental data.

PubMed

White, Andrew D; Knight, Chris; Hocky, Glen M; Voth, Gregory A

2017-01-28

Accounting for electrons and nuclei simultaneously is a powerful capability of ab initio molecular dynamics (AIMD). However, AIMD is often unable to accurately reproduce properties of systems such as water due to inaccuracies in the underlying electronic density functionals. This shortcoming is often addressed by added empirical corrections and/or increasing the simulation temperature. We present here a maximum-entropy approach to directly incorporate limited experimental data via a minimal bias. Biased AIMD simulations of water and an excess proton in water are shown to give significantly improved properties both for observables which were biased to match experimental data and for unbiased observables. This approach also yields new physical insight into inaccuracies in the underlying density functional theory as utilized in the unbiased AIMD.

On the possible use of radio occultation middle latitude electron density profiles to retrieve thermospheric parameters

NASA Astrophysics Data System (ADS)

Mikhailov, Andrei V.; Belehaki, Anna; Perrone, Loredanna; Zolesi, Bruno; Tsagouri, Ioanna

2014-04-01

This paper investigates possible use of middle latitude daytime COSMIC and CHAMP ionospheric radio occultation (IRO) electron density profiles (EDPs) to retrieve thermospheric parameters, based on the Mikhailov et al. (2012) method. The aim of this investigation is to assess the applicability of this type of observations for the routine implementation of the method. According to the results extracted from the analysis presented here, about half of COSMIC IRO EDP observed under solar minimum (2007-2008) conditions gave neutral gas density with an inaccuracy close to the declared absolute inaccuracy ±(10-15)% of CHAMP observations, with the results being better than the empirical models JB-2008 and MSISE-00 provide. For the other half of IRO EDP, either the solution provided by the method had to be rejected due to insufficient accuracy or no solution could be obtained. For these cases, the parameters foF2 and hmF2 extracted from the corresponding IRO profiles have been found to be inconsistent with the classic mid-latitude daytime F2-layer formalism that the method relies on, and they are incompatible with the general trend provided by the IRI model. For solar maximum conditions (2002) the method was tested with IRO EDP from CHAMP and it is indicated that its performance is quite stable in the sense that a solution could be obtained for all the cases analyzed here. However available CHAMP EDP are confined by ~ 400 km in altitude and this might be the reason for the 20% bias of the retrieved densities toward larger values in respect to the observed densities. IRO observations up to 600 km under solar maximum are required to confirm the exact performance of the method.

Negative hydrogen ions in a linear helicon plasma device

NASA Astrophysics Data System (ADS)

Corr, Cormac; Santoso, Jesse; Samuell, Cameron; Willett, Hannah; Manoharan, Rounak; O'Byrne, Sean

2015-09-01

Low-pressure negative ion sources are of crucial importance to the development of high-energy (>1 MeV) neutral beam injection systems for the ITER experimental tokamak device. Due to their high power coupling efficiency and high plasma densities, helicon devices may be able to reduce power requirements and potentially remove the need for caesium. In helicon sources, the RF power can be coupled efficiently into the plasma and it has been previously observed that the application of a small magnetic field can lead to a significant increase in the plasma density. In this work, we investigate negative ion dynamics in a high-power (20 kW) helicon plasma source. The negative ion fraction is measured by probe-based laser photodetachment, electron density and temperature are determined by a Langmuir probe and tuneable diode laser absorption spectroscopy is used to determine the density of the H(n = 2) excited atomic state and the gas temperature. The negative ion density and excited atomic hydrogen density display a maximum at a low applied magnetic field of 3 mT, while the electron temperature displays a minimum. The negative ion density can be increased by a factor of 8 with the application of the magnetic field. Spatial and temporal measurements will also be presented. The Australian Research Grants Council is acknowledged for funding.

Electron density extrapolation above F2 peak by the linear Vary-Chap model supporting new Global Navigation Satellite Systems-LEO occultation missions

NASA Astrophysics Data System (ADS)

Hernández-Pajares, Manuel; Garcia-Fernández, Miquel; Rius, Antonio; Notarpietro, Riccardo; von Engeln, Axel; Olivares-Pulido, Germán.; Aragón-Àngel, Àngela; García-Rigo, Alberto

2017-08-01

The new radio-occultation (RO) instrument on board the future EUMETSAT Polar System-Second Generation (EPS-SG) satellites, flying at a height of 820 km, is primarily focusing on neutral atmospheric profiling. It will also provide an opportunity for RO ionospheric sounding, but only below impact heights of 500 km, in order to guarantee a full data gathering of the neutral part. This will leave a gap of 320 km, which impedes the application of the direct inversion techniques to retrieve the electron density profile. To overcome this challenge, we have looked for new ways (accurate and simple) of extrapolating the electron density (also applicable to other low-Earth orbiting, LEO, missions like CHAMP): a new Vary-Chap Extrapolation Technique (VCET). VCET is based on the scale height behavior, linearly dependent on the altitude above hmF2. This allows extrapolating the electron density profile for impact heights above its peak height (this is the case for EPS-SG), up to the satellite orbital height. VCET has been assessed with more than 3700 complete electron density profiles obtained in four representative scenarios of the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) in the United States and the Formosa Satellite Mission 3 (FORMOSAT-3) in Taiwan, in solar maximum and minimum conditions, and geomagnetically disturbed conditions, by applying an updated Improved Abel Transform Inversion technique to dual-frequency GPS measurements. It is shown that VCET performs much better than other classical Chapman models, with 60% of occultations showing relative extrapolation errors below 20%, in contrast with conventional Chapman model extrapolation approaches with 10% or less of the profiles with relative error below 20%.

Generalized charge-screening in relativistic Thomas–Fermi model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akbari-Moghanjoughi, M.

In this paper, we study the charge shielding within the relativistic Thomas-Fermi model for a wide range of electron number-densities and the atomic-number of screened ions. A generalized energy-density relation is obtained using the force-balance equation and taking into account the Chandrasekhar's relativistic electron degeneracy pressure. By numerically solving a second-order nonlinear differential equation, the Thomas-Fermi screening length is investigated, and the results are compared for three distinct regimes of the solid-density, warm-dense-matter, and white-dwarfs (WDs). It is revealed that our nonlinear screening theory is compatible with the exponentially decaying Thomas-Fermi-type shielding predicted by the linear response theory. Moreover, themore » variation of relative Thomas-Fermi screening length shows that extremely dense quantum electron fluids are relatively poor charge shielders. Calculation of the total number of screening electrons around a nucleus shows that there is a position of maximum number of screening localized electrons around the screened nucleus, which moves closer to the point-like nucleus by increase in the plasma number density but is unaffected due to increase in the atomic-number value. It is discovered that the total number of screening electrons, (N{sub s}∝r{sub TF}{sup 3}/r{sub d}{sup 3} where r{sub TF} and r{sub d} are the Thomas-Fermi and interparticle distance, respectively) has a distinct limit for extremely dense plasmas such as WD-cores and neutron star crusts, which is unique for all given values of the atomic-number. This is equal to saying that in an ultrarelativistic degeneracy limit of electron-ion plasma, the screening length couples with the system dimensionality and the plasma becomes spherically self-similar. Current analysis can provide useful information on the effects of relativistic correction to the charge screening for a wide range of plasma density, such as the inertial-confined plasmas and compact stellar objects.« less

Effect of salt concentration and mediators in salt bridge microbial fuel cell for electricity generation from synthetic wastewater.

PubMed

Sevda, Surajbhan; Sreekrishnan, T R

2012-01-01

The aim of this study was to investigate the feasibility of using agar salt bridges for proton transport in Microbial Fuel Cells (MFC). It also tries to elucidate and effect of mediators on electricity production from wastewaters through experimentation using a simulated wastewater. In order to offset the very high cost of proton exchange membrane, salt bridges have been used in dual chamber MFCs. When the concentration of salt was varied in agar salt bridges from 1% to 10%, the volumetric power density changed from 1.71 to 84.99 mW/m(3) with a concomitant variation in power density from 0.32 to 16.02 mW/m(2). The maximum power density was observed at 5% salt concentration with 10% agar, which was accompanied by 88.41% COD reduction. In the case of methylene blue (0.01 mM) as the electron mediator, the voltage and current generation were 0.551 V and 0.47 mA, respectively. A maximum open circuit voltage of 0.718 V was seen at 0.08 mM methylene blue concentration, whereas maximum power densities of 17.59 mW/m(2) and 89.22 mW/m(3) were obtained. Different concentrations of neutral red were also tried out as mediators. A maximum open circuit voltage of 0.730 V was seen at 0.01 mM neutral red, corresponding to a power density of 12.02 mW/m(2) (volumetric power density of 60.97 mW/m(3)). Biofilm formation on the electrode surface was not observed in the presence of mediators, but was present in the absence of mediators. The results clearly demonstrated the feasibility to use agar salt bridge for proton transport and role of mediators in MFCs to generate electricity.

A study of optical scattering methods in laboratory plasma diagnosis

NASA Technical Reports Server (NTRS)

Phipps, C. R., Jr.

1972-01-01

Electron velocity distributions are deduced along axes parallel and perpendicular to the magnetic field in a pulsed, linear Penning discharge in hydrogen by means of a laser Thomson scattering experiment. Results obtained are numerical averages of many individual measurements made at specific space-time points in the plasma evolution. Because of the high resolution in k-space and the relatively low maximum electron density 2 x 10 to the 13th power/cu cm, special techniques were required to obtain measurable scattering signals. These techniques are discussed and experimental results are presented.

Non-perturbative aspects of particle acceleration in non-linear electrodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burton, David A.; Flood, Stephen P.; Wen, Haibao

2015-04-15

We undertake an investigation of particle acceleration in the context of non-linear electrodynamics. We deduce the maximum energy that an electron can gain in a non-linear density wave in a magnetised plasma, and we show that an electron can “surf” a sufficiently intense Born-Infeld electromagnetic plane wave and be strongly accelerated by the wave. The first result is valid for a large class of physically reasonable modifications of the linear Maxwell equations, whilst the second result exploits the special mathematical structure of Born-Infeld theory.

Gold biorecovery from e-waste: An improved strategy through spent medium leaching with pH modification.

PubMed

Natarajan, Gayathri; Ting, Yen-Peng

2015-10-01

Rapid technological advancement and relatively short life time of electronic goods have resulted in an alarming growth rate of electronic waste which often contains significant quantities of toxic and precious metals. Compared to conventional recovery methods, bioleaching is an environmentally friendly process for metal extraction. Gold was bioleached from electronic scrap materials (ESM) via gold-cyanide complexation using cyanide produced from pure and mixed cultures of cyanogenic bacteria Chromobacterium violaceum, Pseudomonas aeruginosa and Pseudomonas fluorescens. As ESM was toxic to the bacteria, a two-step bioleaching approach was adopted where the solid waste was added to the bacterial culture after it has reached maximum growth and cyanide production during early stationary phase. Pure culture of C. violaceum showed the highest cyanide production, yielding maximum gold recovery of 11.3% at 0.5% w/v pulp density of ESM in two-step bioleaching. At the same pulp density of ESM, spent medium bioleaching using bacterial cell-free metabolites achieved gold recovery of 18%. Recovery increased to 30% when the pH of the spent medium was increased to shift the equilibrium in favor of cyanide ions production. It is demonstrated for the first time that pH modification of spent medium further improved metal solubilization and yielded higher metal recovery (compared to two-step bioleaching). Copyright © 2015 Elsevier Ltd. All rights reserved.

Evaluation of AlGaN/GaN high electron mobility transistors grown on ZrTi buffer layers with sapphire substrates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ren, Fan; Pearton, Stephen J.; Ahn, Shihyun

Here, AlGaN/GaN high electron mobility transistors (HEMTs) have been grown on sapphire substrates, using ZrTi buffer layers to provide in-plane lattice-matching to hexagonal GaN. X-ray diffraction (XRD) as well as cross-section transmission electron microscopy (TEM) were used to assess the quality of the HEMT structure. The XRD 2θ scans showed full-width-at-half-maximum values of 0.16°, 0.07°, and 0.08° for ZrTi alloy, GaN buffer layer, and the entire HEMT structure, respectively. TEM studies of the GaN buffer layer and the AlN/ZrTi/AlN stack showed the importance of growing thin AlN buffer layers on the ZrTi layer prior to growth of the GaN buffermore » layer. The density of threading dislocations in the GaN channel layer of the HEMT structure was estimated to be in the 10 8 cm –2 range. The HEMT device exhibited a saturation drain current density of 820 mA/mm, and the channel of the fabricated HEMTs could be well modulated. A cutoff frequency (f T) of 8.9 GHz and a maximum frequency of oscillation (f max) of 17.3 GHz were achieved for HEMTs with gate dimensions of 1 × 200 μm.« less

Evaluation of AlGaN/GaN high electron mobility transistors grown on ZrTi buffer layers with sapphire substrates

DOE PAGES

Ren, Fan; Pearton, Stephen J.; Ahn, Shihyun; ...

2016-09-21

Here, AlGaN/GaN high electron mobility transistors (HEMTs) have been grown on sapphire substrates, using ZrTi buffer layers to provide in-plane lattice-matching to hexagonal GaN. X-ray diffraction (XRD) as well as cross-section transmission electron microscopy (TEM) were used to assess the quality of the HEMT structure. The XRD 2θ scans showed full-width-at-half-maximum values of 0.16°, 0.07°, and 0.08° for ZrTi alloy, GaN buffer layer, and the entire HEMT structure, respectively. TEM studies of the GaN buffer layer and the AlN/ZrTi/AlN stack showed the importance of growing thin AlN buffer layers on the ZrTi layer prior to growth of the GaN buffermore » layer. The density of threading dislocations in the GaN channel layer of the HEMT structure was estimated to be in the 10 8 cm –2 range. The HEMT device exhibited a saturation drain current density of 820 mA/mm, and the channel of the fabricated HEMTs could be well modulated. A cutoff frequency (f T) of 8.9 GHz and a maximum frequency of oscillation (f max) of 17.3 GHz were achieved for HEMTs with gate dimensions of 1 × 200 μm.« less

High power density from a miniature microbial fuel cell using Shewanella oneidensis DSP10.

PubMed

Ringeisen, Bradley R; Henderson, Emily; Wu, Peter K; Pietron, Jeremy; Ray, Ricky; Little, Brenda; Biffinger, Justin C; Jones-Meehan, Joanne M

2006-04-15

A miniature microbial fuel cell (mini-MFC) is described that demonstrates high output power per device cross-section (2.0 cm2) and volume (1.2 cm3). Shewanella oneidensis DSP10 in growth medium with lactate and buffered ferricyanide solutions were used as the anolyte and catholyte, respectively. Maximum power densities of 24 and 10 mW/m2 were measured using the true surface areas of reticulated vitreous carbon (RVC) and graphite felt (GF) electrodes without the addition of exogenous mediators in the anolyte. Current densities at maximum power were measured as 44 and 20 mA/m2 for RVC and GF, while short circuit current densities reached 32 mA/m2 for GF anodes and 100 mA/m2 for RVC. When the power density for GF was calculated using the cross sectional area of the device or the volume of the anode chamber, we found values (3 W/m2, 500 W/m3) similar to the maxima reported in the literature. The addition of electron mediators resulted in current and power increases of 30-100%. These power densities were surprisingly high considering a pure S. oneidensis culture was used. We found that the short diffusion lengths and high surface-area-to-chamber volume ratio utilized in the mini-MFC enhanced power density when compared to output from similar macroscopic MFCs.

Particle-in-cell study of the ion-to-electron sheath transition

DOE PAGES

Scheiner, Brett; Baalrud, Scott D.; Hopkins, Matthew M.; ...

2016-08-09

The form of a sheath near a small electrode, with bias changing from below to above the plasma potential, is studied using 2D particle-in-cell simulations. When the electrode is biased within T e/2 e below the plasma potential, the electron velocity distribution functions (EVDFs) exhibit a loss-cone type truncation due to fast electrons overcoming the small potential difference between the electrode and plasma. No sheath is present in this regime, and the plasma remains quasineutral up to the electrode. The EVDF truncation leads to a presheath-like density and flow velocity gradients. Once the bias exceeds the plasma potential, an electronmore » sheath is present. In this case, the truncation driven behavior persists, but is accompanied by a shift in the maximum value of the EVDF that is not present in the negative bias cases. In conclusion, the flow moment has significant contributions from both the flow shift of the EVDF maximum, and the loss-cone truncation.« less

High current density ion beam obtained by a transition to a highly focused state in extremely low-energy region.

PubMed

Hirano, Y; Kiyama, S; Fujiwara, Y; Koguchi, H; Sakakita, H

2015-11-01

A high current density (≈3 mA/cm(2)) hydrogen ion beam source operating in an extremely low-energy region (E(ib) ≈ 150-200 eV) has been realized by using a transition to a highly focused state, where the beam is extracted from the ion source chamber through three concave electrodes with nominal focal lengths of ≈350 mm. The transition occurs when the beam energy exceeds a threshold value between 145 and 170 eV. Low-level hysteresis is observed in the transition when E(ib) is being reduced. The radial profiles of the ion beam current density and the low temperature ion current density can be obtained separately using a Faraday cup with a grid in front. The measured profiles confirm that more than a half of the extracted beam ions reaches the target plate with a good focusing profile with a full width at half maximum of ≈3 cm. Estimation of the particle balances in beam ions, the slow ions, and the electrons indicates the possibility that the secondary electron emission from the target plate and electron impact ionization of hydrogen may play roles as particle sources in this extremely low-energy beam after the compensation of beam ion space charge.

Radio Frequency Transistors Using Aligned Semiconducting Carbon Nanotubes with Current-Gain Cutoff Frequency and Maximum Oscillation Frequency Simultaneously Greater than 70 GHz.

PubMed

Cao, Yu; Brady, Gerald J; Gui, Hui; Rutherglen, Chris; Arnold, Michael S; Zhou, Chongwu

2016-07-26

In this paper, we report record radio frequency (RF) performance of carbon nanotube transistors based on combined use of a self-aligned T-shape gate structure, and well-aligned, high-semiconducting-purity, high-density polyfluorene-sorted semiconducting carbon nanotubes, which were deposited using dose-controlled, floating evaporative self-assembly method. These transistors show outstanding direct current (DC) performance with on-current density of 350 μA/μm, transconductance as high as 310 μS/μm, and superior current saturation with normalized output resistance greater than 100 kΩ·μm. These transistors create a record as carbon nanotube RF transistors that demonstrate both the current-gain cutoff frequency (ft) and the maximum oscillation frequency (fmax) greater than 70 GHz. Furthermore, these transistors exhibit good linearity performance with 1 dB gain compression point (P1dB) of 14 dBm and input third-order intercept point (IIP3) of 22 dBm. Our study advances state-of-the-art of carbon nanotube RF electronics, which have the potential to be made flexible and may find broad applications for signal amplification, wireless communication, and wearable/flexible electronics.

Solar Wind 0.1-1 keV Electrons in the Corotating Interaction Regions

NASA Astrophysics Data System (ADS)

Wang, L.; Tao, J.; Li, G.; Wimmer-Schweingruber, R. F.; Jian, L. K.; He, J.; Tu, C.; Tian, H.; Bale, S. D.

2017-12-01

Here we present a statistical study of the 0.1-1 keV suprathermal electrons in the undisturbed and compressed slow/fast solar wind, for the 71 corotating interaction regions (CIRs) with good measurements from the WIND 3DP and MFI instruments from 1995 to 1997. For each of these CIRs, we separate the strahl and halo electrons based on their different behaviors in pitch angle distributions in the undisturbed and compressed solar wind. We fit both the strahl and halo energy spectra to a kappa function with an index κ index and effective temperature Teff, and calculate the pitch-angle width at half-maximum (PAHM) of the strahl population. We also integrate the electron measurements between 0.1 and 1.0 keV to obtain the number density n and average energy Eavg for the strahl and halo populations. We find that for both the strahl and halo populations within and around these CIRs, the fitted κ index strongly correlates with Teff, similar to the quiet-time solar wind (Tao et al., ApJ, 2016). The number density of both the strahl and halo shows a strong positive correlation with the electron core temperature. The strahl number density ns is correlated with the magnitude of interplanetary magnetic field, and the strahl PAHM width is anti-correlated with the solar wind speed. These results suggest that the origin of strahl electrons from the solar corona is likely related to the electron core temperature and magnetic field strength, while the production of halo electrons in the interplanetary medium could depend on the solar wind velocity.

Direct thrust measurement of a permanent magnet helicon double layer thruster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takahashi, K.; Lafleur, T.; Charles, C.

2011-04-04

Direct thrust measurements of a permanent magnet helicon double layer thruster have been made using a pendulum thrust balance and a high sensitivity laser displacement sensor. At the low pressures used (0.08 Pa) an ion beam is detected downstream of the thruster exit, and a maximum thrust force of about 3 mN is measured for argon with an rf input power of about 700 W. The measured thrust is proportional to the upstream plasma density and is in good agreement with the theoretical thrust based on the maximum upstream electron pressure.

Charge density wave behavior and order-disorder in the antiferromagnetic metallic series Eu (Ga1 -xAlx)4

NASA Astrophysics Data System (ADS)

Stavinoha, Macy; Cooley, Joya A.; Minasian, Stefan G.; McQueen, Tyrel M.; Kauzlarich, Susan M.; Huang, C.-L.; Morosan, E.

2018-05-01

The solid solution Eu (Ga1-xAlx) 4 was grown in single crystal form to reveal a rich variety of crystallographic, magnetic, and electronic properties that differ from the isostructural end compounds EuGa4 and EuAl4, despite the similar covalent radii and electronic configurations of Ga and Al. Here we report the onset of magnetic spin reorientation and metamagnetic transitions for x =0 -1 evidenced by magnetization and temperature-dependent specific heat measurements. TN changes nonmonotonously with x , and it reaches a maximum around 20 K for x =0.50 , where the a lattice parameter also shows an extreme (minimum) value. Anomalies in the temperature-dependent resistivity consistent with charge density wave behavior exist only for x =0.50 and 1. Density functional theory calculations show increased polarization between the Ga-Al covalent bonds in the x =0.50 structure compared to the end compounds, such that crystallographic order and chemical pressure are proposed as the causes of the charge density wave behavior.

Laser-induced plasmas in air studied using two-color interferometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Zefeng; Wu, Jian, E-mail: jxjawj@mail.xjtu.edu.cn; Li, Xingwen

2016-08-15

Temporally and spatially resolved density profiles of Cu atoms, electrons, and compressed air, from laser-induced copper plasmas in air, are measured using fast spectral imaging and two-color interferometry. From the intensified CCD images filtered by a narrow-band-pass filter centered at 515.32 nm, the Cu atoms expansion route is estimated and used to determine the position of the fracture surface between the Cu atoms and the air. Results indicate that the Cu atoms density at distances closer to the target (0–0.4 mm) is quite low, with the maximum density appearing at the edge of the plasma's core being ∼4.6 × 10{sup 24 }m{sup −3} at 304 ns.more » The free electrons are mainly located in the internal region of the plume, which is supposed to have a higher temperature. The density of the shock wave is (4–6) × 10{sup 25 }m{sup −3}, corresponding to air compression of a factor of 1.7–2.5.« less

Interaction between the lower hybrid wave and density fluctuations in the scrape-off layer

NASA Astrophysics Data System (ADS)

Peysson, Y.; Madi, M.; Decker, J.; Kabalan, K.

2015-12-01

In the present paper, the perturbation of the launched power spectrum of the Lower Hybrid wave at the separatrix by electron density fluctuations in the scrape-off layer is investigated. Considering a slab geometry with magnetic field lines parallel to the toroidal direction, the full wave equation is solved using Comsol Multiphysics® for a fully active multi-junction like LH antenna made of two modules. When electron density fluctuations are incorporated in the dielectric tensor over a thin perturbed layer in front of the grill, it is shown that the power spectrum may be strongly modified from the antenna mouth to the plasma separatrix as the wave propagates. The diffraction effect leads to the appearance of multiple satellite lobes with randomly varying positions, a feature consistent with the recently developed model that has been applied successfully to high density discharges on the Tokamak Tore Supra corresponding to the large spectral gap regime [Decker J. et al. Phys. Plasma 21 (2014) 092504]. The perturbation is found to be maximum for the Fourier components of the fluctuating spectrum in the vicinity of the launched LH wavelength.

Topside ionosphere of Mars: Variability, transient layers, and the role of crustal magnetic fields

NASA Astrophysics Data System (ADS)

Gopika, P. G.; Venkateswara Rao, N.

2018-04-01

The topside ionosphere of Mars is known to show variability and transient topside layers. In this study, we analyzed the electron density profiles measured by the radio occultation technique aboard the Mars Global Surveyor spacecraft to study the topside ionosphere of Mars. The electron density profiles that we used in the present study span between 1998 and 2005. All the measurements are done from the northern high latitudes, except 220 profiles which were measured in the southern hemisphere, where strong crustal magnetic fields are present. We binned the observations into six measurement periods: 1998, 1999-north, 1999-south, 2000-2001, 2002-2003, and 2004-2005. We found that the topside ionosphere in the southern high latitudes is more variable than that from the northern hemisphere. This feature is clearly seen with fluctuations of wavelengths less than 20 km. Some of the electron density profiles show a transient topside layer with a local maximum in electron density between 160 km and 210 km. The topside layer is more prone to occur in the southern hemispheric crustal magnetic field regions than in the other regions. In addition, the peak density of the topside layer is greater in regions of strong crustal magnetic fields than in other regions. The variability of the topside ionosphere and the peak density of the topside layer, however, do not show one-to-one correlation with the strength of the crustal magnetic fields and magnetic field inclination. The results of the present study are discussed in the light of current understanding on the topside ionosphere, transient topside layers, and the role of crustal magnetic fields on plasma motions.

Very low frequency waves stimulated by an electron accelerator in the auroral ionosphere

NASA Technical Reports Server (NTRS)

Holtet, J. A.; Pran, B. K.; Egeland, A.; Grandal, B.; Jacobsen, T. A.; Maehlum, B. N.; Troim, J.

1981-01-01

The sounding rocket, Polar 5, carrying a 10 keV electron accelerator in a mother-daughter configuration and other diagnostic instruments, was launched into a slightly disturbed ionosphere with weak auroral activity on February 1, 1976 from Northern Norway to study VLF wave phenomena. The rocket trajectory crossed two auroral regions: one, between 86 and 111 s flight time, and a secondary region between 230 and 330 s. The daughter, carrying the accelerator, was separated axially from the mother in a forward direction at an altitude of 90 km. The VLF experiment, carried by the mother payload, recorded both electromagnetic and electrostatic waves. The receiving antenna was an electric dipole, 0.3 m tip-to-tip, oriented 90 degrees to the rocket spin axis. The onboard particle detector recorded increased electron fluxes in the two auroral regions. A double peaked structure was observed in the fluxes of 4-5 and 12-27 keV electrons within the northern auroral form. The number density of thermal plasma varied during the flight, with maximum density within the main auroral region. To the north of this aurora a slow, steady decrease in the density was observed, with no enhancement in the region of the second aurora.

One-dimensional α-MoO3 nanorods for high energy density pseudocapacitor

NASA Astrophysics Data System (ADS)

Dutta, Shibsankar; Pal, Shreyasi; De, Sukanta

2018-04-01

Ultralong α-MoO3 nanorods having length of 500 nm to 1 µm and uniform width of around ˜50 nm have been synthesized by a simple one step hydrothermal route using a molybdenum organic salt precursor. An evaluation of the electrochemical properties of the nanorods was done by cyclic voltammetry (CV), and galvanometric charging- discharging (GCD) test. Because of the high active sites and rapid ion diffusion and electron transport of the electrodes using as prepared nanorods reveals energy density of 65 Wh/kg at a power density of 940 W/ kg and a maximum specific capacitance of 474 F/g. It also shows excellent cycling stability.

Ionospheric tomography by gradient-enhanced kriging with STEC measurements and ionosonde characteristics

NASA Astrophysics Data System (ADS)

Minkwitz, David; van den Boogaart, Karl Gerald; Gerzen, Tatjana; Hoque, Mainul; Hernández-Pajares, Manuel

2016-11-01

The estimation of the ionospheric electron density by kriging is based on the optimization of a parametric measurement covariance model. First, the extension of kriging with slant total electron content (STEC) measurements based on a spatial covariance to kriging with a spatial-temporal covariance model, assimilating STEC data of a sliding window, is presented. Secondly, a novel tomography approach by gradient-enhanced kriging (GEK) is developed. Beyond the ingestion of STEC measurements, GEK assimilates ionosonde characteristics, providing peak electron density measurements as well as gradient information. Both approaches deploy the 3-D electron density model NeQuick as a priori information and estimate the covariance parameter vector within a maximum likelihood estimation for the dedicated tomography time stamp. The methods are validated in the European region for two periods covering quiet and active ionospheric conditions. The kriging with spatial and spatial-temporal covariance model is analysed regarding its capability to reproduce STEC, differential STEC and foF2. Therefore, the estimates are compared to the NeQuick model results, the 2-D TEC maps of the International GNSS Service and the DLR's Ionospheric Monitoring and Prediction Center, and in the case of foF2 to two independent ionosonde stations. Moreover, simulated STEC and ionosonde measurements are used to investigate the electron density profiles estimated by the GEK in comparison to a kriging with STEC only. The results indicate a crucial improvement in the initial guess by the developed methods and point out the potential compensation for a bias in the peak height hmF2 by means of GEK.

Characteristics of the Dust-Plasma Interaction Near Enceladus' South Pole

NASA Technical Reports Server (NTRS)

Shafiq, Muhammad; Wahlund, J.-E.; Morooka, M. W; Kurth, W. S.; Farrell, W. M.

2010-01-01

We present RPWS Langmuir probe data from the third Enceladus flyby (E3) showing (he presence of dusty plasma near Enceladus' South Pole. There is a sharp rise in both the electron and ion number densities when the spacecraft traverses through Enceladus plume. The ion density near Enceladus is found to increase abruptly from about 10(exp 2) cm (exp -3) before the closest approach to 10(exp 5) cm (exp -3) just 30 s after the closest approach, an amount two orders of magnitude higher than the electron density. Assuming that the inconsistency between the electron and ion number densities is due to the presence of dust particles that are collecting the missing electron charges, we present dusty plasma characteristics down to sub-micron particle sizes. By assuming a differential dust number density for a range in dust sizes and by making use of Langmuir probe data, the dust densities for certain lower limits in dust size distribution were estimated. In order to achieve the dust densities of micrometer and larger sized grains comparable to the ones reported in the literature. we show that the power law size distribution must hold down to at least 0.03 micron such that the total differential number density is dominated by the smallest sub-micron sized grains. The total dust number density in Enceladus' plume is of the order of l0(exp 2) cm(exp -3) reducing to 1 cm(exp -3) in the E- ring. The dust density for micrometer and larger sized grains is estimated to be about 10(exp -4) cm(exp -3) in the plume while it is about 10(exp -6) - 10(exp -7) cm(exp -3) in the E-ring. Dust charge for micron sized grains is estimated to be about eight thousand electron charges reducing to below one hundred electron charges for 0.03 micron sized grains. The effective dusty plasma Debye length is estimated and compared with intergrain distance as well as the electron Debye length. The maximum dust charging time of 1.4 h is found for 0.03 11mmicron sized grains just 1 min before the closest approach. The charging time decreases substantially in the plume where it is only a fraction of a second for 1 micron sized grains, 1 s for 0.l micron sized grains and about 10 s for 0.03 micron sized grains.

A Novel Electrophototrophic Bacterium Rhodopseudomonas palustris Strain RP2, Exhibits Hydrocarbonoclastic Potential in Anaerobic Environments

PubMed Central

Venkidusamy, Krishnaveni; Megharaj, Mallavarapu

2016-01-01

An electrophototrophic, hydrocarbonoclastic bacterium Rhodopseudomonas palustris stain RP2 was isolated from the anodic biofilms of hydrocarbon fed microbial electrochemical remediation systems (MERS). Salient properties of the strain RP2 were direct electrode respiration, dissimilatory metal oxide reduction, spore formation, anaerobic nitrate reduction, free living diazotrophy and the ability to degrade n-alkane components of petroleum hydrocarbons (PH) in anoxic, photic environments. In acetate fed microbial electrochemical cells, a maximum current density of 305 ± 10 mA/m2 (1000Ω) was generated (power density 131.65 ± 10 mW/m2) by strain RP2 with a coulombic efficiency of 46.7 ± 1.3%. Cyclic voltammetry studies showed that anaerobically grown cells of strain RP2 is electrochemically active and likely to transfer electrons extracellularly to solid electron acceptors through membrane bound compounds, however, aerobically grown cells lacked the electrochemical activity. The ability of strain RP2 to produce current (maximum current density 21 ± 3 mA/m2; power density 720 ± 7 μW/m2, 1000 Ω) using PH as a sole energy source was also examined using an initial concentration of 800 mg l-1 of diesel range hydrocarbons (C9-C36) with a concomitant removal of 47.4 ± 2.7% hydrocarbons in MERS. Here, we also report the first study that shows an initial evidence for the existence of a hydrocarbonoclastic behavior in the strain RP2 when grown in different electron accepting and illuminated conditions (anaerobic and MERS degradation). Such observations reveal the importance of photoorganotrophic growth in the utilization of hydrocarbons from contaminated environments. Identification of such novel petrochemical hydrocarbon degrading electricigens, not only expands the knowledge on the range of bacteria known for the hydrocarbon bioremediation but also shows a biotechnological potential that goes well beyond its applications to MERS. PMID:27462307

The topside ionospheric effective scale heights (HT) derived with ROCSAT-1 and ground-based Ionosonde observations at equatorial and mid-latitude stations

NASA Astrophysics Data System (ADS)

Ram Sudarsanam, Tulasi; Su, Shin-Yi; Liu, C. H.; Reinisch, Bodo

In this study, we propose the assimilation of topside in situ electron density data from ROCSAT-1 satellite along with the ionosonde measurements for accurate determination of topside iono-spheric effective scale heights (HT) using -Chapman function. The reconstructed topside elec-tron density profiles using these scale heights exhibit an excellent similitude with Jicamarca Incoherent Scatter Radar (ISR) profiles, and are much better representations than the existing methods of Reinisch-Huang method and/or the empirical IRI-2007 model. The main advan-tage with this method is that it allows the precise determination of the effective scale height (HT) and the topside electron density profiles at a dense network of ionosonde/digisonde sta-tions where no ISR facilities are available. The demonstration of the method is applied by investigating the diurnal, seasonal and solar activity variations of HT over the dip-equatorial station Jicamarca and the mid-latitude station Grahamstown. The diurnal variation of scale heights over Jicamarca consistently exhibits a morning time descent followed by a minimum around 0700-0800 LT and a pronounced maximum at noon during all the seasons of both high and moderate solar activity periods. Further, the scale heights exhibit a secondary maximum during the post-sunset hours of equinoctial and summer months, whereas the post-sunset peak is absent during the winter months. These typical features are further investigated using the topside ion properties obtained by ROCSAT-1 as well as SAMI2 model simulations. The re-sults consistently indicate that the diurnal variation of the effective scale height (HT) does not closely follow the plasma temperature variation and at equatorial latitudes is largely controlled by the vertical ExB drift.

Polyaniline modified graphene and carbon nanotube composite electrode for asymmetric supercapacitors of high energy density

NASA Astrophysics Data System (ADS)

Cheng, Qian; Tang, Jie; Shinya, Norio; Qin, Lu-Chang

2013-11-01

Graphene and single-walled carbon nanotube (CNT) composites are explored as the electrodes for supercapacitors by coating polyaniline (PANI) nano-cones onto the graphene/CNT composite to obtain graphene/CNT-PANI composite electrode. The graphene/CNT-PANI electrode is assembled with a graphene/CNT electrode into an asymmetric pseudocapacitor and a highest energy density of 188 Wh kg-1 and maximum power density of 200 kW kg-1 are achieved. The structure and morphology of the graphene/CNT composite and the PANI nano-cone coatings are characterized by both scanning electron microscopy and transmission electron microscopy. The excellent performance of the assembled supercapacitors is also discussed and it is attributed to (i) effective utilization of the large surface area of the three-dimensional network structure of graphene-based composite, (ii) the presence of CNT in the composite preventing graphene from re-stacking, and (ii) uniform and vertically aligned PANI coating on graphene offering increased electrical conductivity.

Estimation of optimum density and temperature for maximum efficiency of tin ions in Z discharge extreme ultraviolet sources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Masnavi, Majid; Nakajima, Mitsuo; Hotta, Eiki

Extreme ultraviolet (EUV) discharge-based lamps for EUV lithography need to generate extremely high power in the narrow spectrum band of 13.5{+-}0.135 nm. A simplified collisional-radiative model and radiative transfer solution for an isotropic medium were utilized to investigate the wavelength-integrated light outputs in tin (Sn) plasma. Detailed calculations using the Hebrew University-Lawrence Livermore atomic code were employed for determination of necessary atomic data of the Sn{sup 4+} to Sn{sup 13+} charge states. The result of model is compared with experimental spectra from a Sn-based discharge-produced plasma. The analysis reveals that considerably larger efficiency compared to the so-called efficiency of amore » black-body radiator is formed for the electron density {approx_equal}10{sup 18} cm{sup -3}. For higher electron density, the spectral efficiency of Sn plasma reduces due to the saturation of resonance transitions.« less

Maximum likelihood density modification by pattern recognition of structural motifs

DOEpatents

Terwilliger, Thomas C.

2004-04-13

An electron density for a crystallographic structure having protein regions and solvent regions is improved by maximizing the log likelihood of a set of structures factors {F.sub.h } using a local log-likelihood function: (x)+p(.rho.(x).vertline.SOLV)p.sub.SOLV (x)+p(.rho.(x).vertline.H)p.sub.H (x)], where p.sub.PROT (x) is the probability that x is in the protein region, p(.rho.(x).vertline.PROT) is the conditional probability for .rho.(x) given that x is in the protein region, and p.sub.SOLV (x) and p(.rho.(x).vertline.SOLV) are the corresponding quantities for the solvent region, p.sub.H (x) refers to the probability that there is a structural motif at a known location, with a known orientation, in the vicinity of the point x; and p(.rho.(x).vertline.H) is the probability distribution for electron density at this point given that the structural motif actually is present. One appropriate structural motif is a helical structure within the crystallographic structure.

Evolution of 3D electron density of the solar corona from the minimum to maximum of Solar Cycle 24

NASA Astrophysics Data System (ADS)

Wang, Tongjiang; Reginald, Nelson L.; Davila, Joseph M.; St Cyr, O. C.

2016-10-01

The variability of the solar white-light corona and its connection to the solar activity has been studied for more than a half century. It is widely accepted that the temporal variation of the total radiance of the K-corona follows the solar cycle pattern (e.g., correlated with sunspot number). However, the origin of this variation and its relationships with regard to coronal mass ejections and the solar wind are yet to be clearly understood. COR1-A and -B instruments onboard the STEREO spacecraft have continued to perform high-cadence (5 min) polarized brightness (pB) measurements from two different vantage points from the solar minimum to the solar maximum of Solar Cycle 24. With these pB observations we have reconstructed the 3D coronal density between 1.5-4.0 solar radii for 100 Carrington rotations (CRs) from 2007 to 2014 using the spherically symmetric inversion (SSI) method. We validate these 3D density reconstructions by other means such as tomography, MHD modeling, and pB inversion of LASCO/C2 data. We analyze the solar cycle variations of total coronal mass (or average density) over the global Sun and in two hemispheres, as well as the variations of the streamer area and mean density. We find the short-term oscillations of 8-9 CRs during the ascending and maximum phases through wavelet analysis. We explore the origin of these oscillations based on evolution of the photospheric magnetic flux and coronal structures.

Enhancement in current density and energy conversion efficiency of 3-dimensional MFC anodes using pre-enriched consortium and continuous supply of electron donors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borole, Abhijeet P; Hamilton, Choo Yieng; Vishnivetskaya, Tatiana A

2011-01-01

Using a pre-enriched microbial consortium as the inoculum and continuous supply of carbon source, improvement in performance of a three-dimensional, flow-through MFC anode utilizing ferricyanide cathode was investigated. The power density increased from 170 W/m3 (1800 mW/m2) to 580 W/m3 (6130 mW/m2), when the carbon loading increased from 2.5 g/l-day to 50 g/l-day. The coulombic efficiency (CE) decreased from 90% to 23% with increasing carbon loading. The CEs are among the highest reported for glucose and lactate as the substrate with the maximum current density reaching 15.1 A/m2. This suggests establishment of a very high performance exoelectrogenic microbial consortium atmore » the anode. A maximum energy conversion efficiency of 54% was observed at a loading of 2.5 g/l-day. Biological characterization of the consortium showed presence of Burkholderiales and Rhodocyclales as the dominant members. Imaging of the biofilms revealed thinner biofilms compared to the inoculum MFC, but a 1.9-fold higher power density.« less

Target electron collision effects on energy loss straggling of protons in an electron gas at any degeneracy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barriga-Carrasco, Manuel D.

2008-03-15

The purpose of the present paper is to describe the effects of target electron collisions on proton energy loss straggling in plasmas at any degeneracy. Targets are considered fully ionized so electronic energy loss is only due to the free electrons. The analysis is focused on targets with electronic density around solid values n{sub e}{approx_equal}10{sup 23} cm{sup -3} and with temperature around T{approx_equal}10 eV; these targets are in the limit of weakly coupled electron gases. These types of plasma targets have not been studied extensively, though they are very important for inertial confinement fusion. The energy loss straggling is obtainedmore » from an exact quantum-mechanical evaluation, which takes into account the degeneracy of the target plasma, and later it is compared with common classical and degenerate approximations. Then electron collisions in the exact quantum-mechanical straggling calculation are considered. Now the energy loss straggling is enhanced for energies smaller than the energy before the maximum, then decreases around this maximum, and finally tends to the same values with respect to noncollisional calculation. Differences with the same results but not taking into account these collisions are as far as 17% in the cases analyzed. As an example, proton range distributions have been calculated to show the importance of an accurate energy straggling calculation.« less

Modeling Solar Zenith Angle Effects on the Polar Wind

NASA Technical Reports Server (NTRS)

Glocer, A; Kitamura, N.; Toth, G; Gombosi, T.

2012-01-01

We use the Polar Wind Outflow Model (PWOM) to study the geomagnetically quiet conditions in the polar cap during solar maximum. The PWOM solves the gyrotropic transport equations for O+, H+, and He+ along several magnetic field lines in the polar region in order to reconstruct the full 3D solution. We directly compare our simulation results to the data based empirical model of Kitamura et al. (2011) of electron density which is based on 63 months of Akebono satellite observations. The modeled ion and electron temperatures are also compared with a statistical compilation of quiet time data obtained by the EISCAT Svalbard Radar (ESR) and Intercosmos Satellites. The data and model agree reasonably well, albeit with some differences. This study shows that photoelectrons play an important role in explaining the differences between sunlit and dark results of electron density, ion composition, as well as ion and electron temperatures of the quiet time polar wind solution. Moreover, these results provide an initial validation of the PWOM s ability to model the quiet time "background" solution.

Heater-induced altitude descent of the EISCAT UHF ion line enhancements: Observations and modelling

NASA Astrophysics Data System (ADS)

Ashrafi, M.; Kosch, M. J.; Honary, F.

2006-01-01

On 12 November 2001, artificial optical annuli were produced using the EISCAT high-frequency (HF) ionospheric heating facility. This unusual phenomenon was induced using O-mode transmissions at 5.423 MHz with 550 MW effective isotropic radiated power and the pump beam dipped 9° south of the zenith. The pump frequency corresponds to the fourth electron gyroharmonic frequency at 215 km altitude. The EISCAT UHF radar observed a persistent pump-induced enhancement in the ion line backscatter power near the HF reflection altitude. The optical and radar signatures of HF pumping started at ˜230 km and descended to ˜220 km within ˜60 s. This effect has been modelled using the solution to differential equations describing pump-induced electron temperature and density perturbations. The decrease in altitude of the ion line by ˜10 km and changes in electron density have been modelled. The results show that a maximum electron temperature enhancement of up to ˜5700 K can be achieved on average, which is not sufficient to explain the observed optical emissions.

Electronic structure and magnetic anisotropy of Sm2Fe17Nx

NASA Astrophysics Data System (ADS)

Akai, Hisazumi; Ogura, Masako

2014-03-01

Electronic structure and magnetic properties of Sm2Fe17Nx are studies on the basis of the first-principles electronic structure calculation in the framework of the density functional theory within the local density and coherent potential approximations. The magnetic anisotropy of the system as a function of nitrogen concentration x is discussed by taking account not only of the crystal field effects but also of the effects of the f-electron transfer from Sm to the neighboring sites. Also discussed is the magnetic transition temperature that is estimated by mapping the system into a Heisenberg model. The results show the crystalline magnetic anisotropy changes its direction from in-plane to uniaxial ones as x increases. It takes the maximum value near x ~ 2 . 8 and then decreases slightly towards x = 3 . The mechanism for these behaviors is discussed in the light of the results of detailed calculations on the bonding properties between Sm and its neighboring N. This work was partly supported by Elements Strategy Initiative Center for Magnetic Materials Project, the Ministry of Education, Culture, Sports, Science and Technology, Japan.

The upgrade of the Thomson scattering system for measurement on the C-2/C-2U devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhai, K.; Schindler, T.; Kinley, J.

The C-2/C-2U Thomson scattering system has been substantially upgraded during the latter phase of C-2/C-2U program. A Rayleigh channel has been added to each of the three polychromators of the C-2/C-2U Thomson scattering system. Onsite spectral calibration has been applied to avoid the issue of different channel responses at different spots on the photomultiplier tube surface. With the added Rayleigh channel, the absolute intensity response of the system is calibrated with Rayleigh scattering in argon gas from 0.1 to 4 Torr, where the Rayleigh scattering signal is comparable to the Thomson scattering signal at electron densities from 1 × 10{supmore » 13} to 4 × 10{sup 14} cm{sup −3}. A new signal processing algorithm, using a maximum likelihood method and including detailed analysis of different noise contributions within the system, has been developed to obtain electron temperature and density profiles. The system setup, spectral and intensity calibration procedure and its outcome, data analysis, and the results of electron temperature/density profile measurements will be presented.« less

Response of the mid-latitude D-region ionosphere to the total solar eclipse of 22 July 2009 studied using VLF signals in South Korean peninsula

NASA Astrophysics Data System (ADS)

Phanikumar, D. V.; Kwak, Y.-S.; Patra, A. K.; Maurya, A. K.; Singh, Rajesh; Park, S.-M.

2014-09-01

In this paper, we analyze VLF signals received at Busan to study the the D-region changes linked with the solar eclipse event of 22 July 2009 for very short (∼390 km) transmitter-receiver great circle path (TRGCP) during local noon time 00:36-03:13 UT (09:36-12:13 KST). The eclipse crossed south of Busan with a maximum obscuration of ∼84%. Observations clearly show a reduction of ∼6.2 dB in the VLF signal strength at the time of maximum solar obscuration (84% at 01:53 UT) as compared to those observed on the control days. Estimated values of change in Wait ionospheric parameters: reflection height (h‧) in km and inverse scale height parameter (β) in km-1 from Long Wave Propagation Capability (LWPC) model during the maximum eclipse phase as compared to unperturbed ionosphere are 7 km and 0.055 km-1, respectively. Moreover, the D-region electron density estimated from model computation shows 95% depletion in electron density at the height of ∼71 km. The reflection height is found to increase by ∼7 km in the D-region during the eclipse as compared to those on the control days, implying a depletion in the Lyman-α flux by a factor of ∼7. The present observations are discussed in the light of current understanding on the solar eclipse induced D-region dynamics.

Two symmetric n-type interfaces SrTiO{sub 3}/LaAlO{sub 3} in perovskite: Electronic properties from density functional theory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reshak, A. H., E-mail: maalidph@yahoo.co.uk, E-mail: mabujafar@najah.edu; Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, 01007 Kangar, Perlis; Abu-Jafar, M. S., E-mail: maalidph@yahoo.co.uk, E-mail: mabujafar@najah.edu

2016-06-28

The first principles study of the (001) two symmetric n-type interfaces between two insulating perovskites, the nonpolar SrTiO{sub 3} (STO), and the polar LaAlO{sub 3} (LAO) was performed. We have analyzed the formation of metallic interface states between the STO and LAO heterointerfaces by using the all-electron full-potential linearized augmented plane-wave approach based on the density functional theory, within the local density approximation, the Perdew-Burke-Ernzerhof generalized gradient approximation (PBE-GGA), and the Engel-Vosko GGA (EVGGA) formalism. It has been found that some bands cross the Fermi energy level (E{sub F}), forming a metallic nature of two symmetric n-type 6.5STO/1.5LAO interfaces withmore » density of states at E{sub F}, N(E{sub F}) of about 3.56 (state/eV/unit cell), and bare electronic specific heat coefficient (γ) of about 0.62 mJ/(mol cell K{sup 2}). The electronic band stature and the partial density of states in the vicinity of E{sub F} are mainly originated from Ti1,2,3,4-3dxy orbitals. These bands are responsible for the metallic behavior and the forming of the Fermi surface of the two symmetric n-type 6.5STO/1.5LAO interfaces. To obtain a clear map of the valence band electronic charge density distribution of the two symmetric n-type 6.5STO/1.5LAO interfaces, we have investigated the bond's nature and the interactions between the atoms. It reveals that the charge is attracted towards O atoms as it is clear that the O atoms are surrounded by uniform blue spheres which indicate the maximum charge accumulation.« less

A magnetospheric signature of some F layer positive storms

NASA Technical Reports Server (NTRS)

Miller, N. J.; Mayr, H. G.; Grebowsky, J. M.; Harris, I.; Tulunay, Y. K.

1981-01-01

Calculations of electron density distributions in the global thermosphere-ionosphere system perturbed by high-latitude thermospheric heating are presented which indicate a link between the heating and magnetospheric plasma disturbances near the equator. The calculations were made using a self-consistent model of the global sunlit thermosphere-ionosphere system describing the evolution of equatorial plasma disturbances. The heat input is found to cause electron density enhancements that propagate along magnetic field lines from the F2 maximum over mid-latitudes to the equator in the magnetosphere and which correspond to the positive phase of an F layer storm. The positive phase is shown to be generated by the induction of equatorward winds that raise the mid-latitude F layer through momentum transfer from neutral atoms to ionospheric ions, which ions pull electrons with them. Model results are used to identify plasma signatures of equatorward winds and an intensified magnetospheric electric field in Explorer 45 and Arial 4 measurements taken during the positive phase of an F layer storm.

Synchrotron radiation from a runaway electron distribution in tokamaks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stahl, A.; Fülöp, T.; Landreman, M.

2013-09-15

The synchrotron radiation emitted by runaway electrons in a fusion plasma provides information regarding the particle momenta and pitch-angles of the runaway electron population through the strong dependence of the synchrotron spectrum on these parameters. Information about the runaway density and its spatial distribution, as well as the time evolution of the above quantities, can also be deduced. In this paper, we present the synchrotron radiation spectra for typical avalanching runaway electron distributions. Spectra obtained for a distribution of electrons are compared with the emission of mono-energetic electrons with a prescribed pitch-angle. We also examine the effects of magnetic fieldmore » curvature and analyse the sensitivity of the resulting spectrum to perturbations to the runaway distribution. The implications for the deduced runaway electron parameters are discussed. We compare our calculations to experimental data from DIII-D and estimate the maximum observed runaway energy.« less

Study on transport properties of silicene monolayer under external field using NEGF method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Syaputra, Marhamni, E-mail: marhamni@students.itb.ac.id; Wella, Sasfan Arman; Wungu, Triati Dewi Kencana

2015-09-30

We investigate the current-voltage (I-V) characteristics of a pristine monolayer silicene using non-equilibrium Green function (NEGF) method combining with density functional theory (DFT). This method succeeded in showing the relationship of I and V on silicene corresponding to the electronic characteristics such as density of states. The external field perpendicular to the silicene monolayer affects in increasing of the current. Under 0.2 eV external field, the current reaches the maximum peak at Vb = 0.3 eV with the increase is about 60% from what it is in zero external field.

Modelling of the internal dynamics and density in a tens of joules plasma focus device

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marquez, Ariel; Gonzalez, Jose; Tarifeno-Saldivia, Ariel

2012-01-15

Using MHD theory, coupled differential equations were generated using a lumped parameter model to describe the internal behaviour of the pinch compression phase in plasma focus discharges. In order to provide these equations with appropriate initial conditions, the modelling of previous phases was included by describing the plasma sheath as planar shockwaves. The equations were solved numerically, and the results were contrasted against experimental measurements performed on the device PF-50J. The model is able to predict satisfactorily the timing and the radial electron density profile at the maximum compression.

Sporadic-E As Observed with Rockets

NASA Technical Reports Server (NTRS)

Seddon, J. Carl

1961-01-01

Data obtained with rockets flown over New Mexico, U.S.A. and Manitoba, Canada have always shown the sporadic-E layer to be a thin layer with a large electron density gradient. The vertical electron density profiles and the horizontal uniformity of the sporadic-E layer are discussed herein. These layers have a strong tendency to form at preferential altitudes separated by approximately 6 km, and a striking correlation exists with wind- shears and magnetic field variations. In two cases where comparisons with ionograms were possible, the minimum frequency of the F-region echoes was found approximately equal to the plasma frequency of the sporadic-E layer reduced by half the gyrofrequency. On the other hand, the maximum frequency of the sporadic-E echoes as noted on ionograms was sometimes as much as 1 to 2 Mc greater than the plasma frequency.

Improving energy conversion efficiency for triboelectric nanogenerator with capacitor structure by maximizing surface charge density.

PubMed

He, Xianming; Guo, Hengyu; Yue, Xule; Gao, Jun; Xi, Yi; Hu, Chenguo

2015-02-07

Nanogenerators with capacitor structures based on piezoelectricity, pyroelectricity, triboelectricity and electrostatic induction have been extensively investigated. Although the electron flow on electrodes is well understood, the maximum efficiency-dependent structure design is not clearly known. In this paper, a clear understanding of triboelectric generators with capacitor structures is presented by the investigation of polydimethylsiloxane-based composite film nanogenerators, indicating that the generator, in fact, acts as both an energy storage and output device. Maximum energy storage and output depend on the maximum charge density on the dielectric polymer surface, which is determined by the capacitance of the device. The effective thickness of polydimethylsiloxane can be greatly reduced by mixing a suitable amount of conductive nanoparticles into the polymer, through which the charge density on the polymer surface can be greatly increased. This finding can be applied to all the triboelectric nanogenerators with capacitor structures, and it provides an important guide to the structural design for nanogenerators. It is demonstrated that graphite particles with sizes of 20-40 nm and 3.0% mass mixed into the polydimethylsiloxane can reduce 34.68% of the effective thickness of the dielectric film and increase the surface charges by 111.27% on the dielectric film. The output power density of the triboelectric nanogenerator with the composite polydimethylsiloxane film is 3.7 W m(-2), which is 2.6 times as much as that of the pure polydimethylsiloxane film.

40 CFR 1042.140 - Maximum engine power, displacement, power density, and maximum in-use engine speed.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Maximum engine power, displacement... Maximum engine power, displacement, power density, and maximum in-use engine speed. This section describes how to determine the maximum engine power, displacement, and power density of an engine for the...

40 CFR 1042.140 - Maximum engine power, displacement, power density, and maximum in-use engine speed.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Maximum engine power, displacement... Maximum engine power, displacement, power density, and maximum in-use engine speed. This section describes how to determine the maximum engine power, displacement, and power density of an engine for the...

Room temperature microwave oscillations in GaN/AlN resonant tunneling diodes with peak current densities up to 220 kA/cm2

NASA Astrophysics Data System (ADS)

Encomendero, Jimy; Yan, Rusen; Verma, Amit; Islam, S. M.; Protasenko, Vladimir; Rouvimov, Sergei; Fay, Patrick; Jena, Debdeep; Xing, Huili Grace

2018-03-01

We report the generation of room temperature microwave oscillations from GaN/AlN resonant tunneling diodes, which exhibit record-high peak current densities. The tunneling heterostructure grown by molecular beam epitaxy on freestanding GaN substrates comprises a thin GaN quantum well embedded between two AlN tunneling barriers. The room temperature current-voltage characteristics exhibit a record-high maximum peak current density of ˜220 kA/cm2. When biased within the negative differential conductance region, microwave oscillations are measured with a fundamental frequency of ˜0.94 GHz, generating an output power of ˜3.0 μW. Both the fundamental frequency and the output power of the oscillator are limited by the external biasing circuit. Using a small-signal equivalent circuit model, the maximum intrinsic frequency of oscillation for these diodes is predicted to be ˜200 GHz. This work represents a significant step towards microwave power generation enabled by resonant tunneling transport, an ultra-fast process that goes beyond the limitations of current III-Nitride high electron mobility transistors.

LASCO Observations Of The K-Corona From Solar Minimum To Solar Maximum And Beyond

NASA Astrophysics Data System (ADS)

Andrews, Michael D.; Howard, Russell A.

2003-09-01

The LASCO C2 and C3 coronagraphs on SOHO have been recording a regular series of images of the corona since May 1996. This sequence of data covers the period of solar minimum, the increase to solar maximum, and the beginning of the decline toward the next solar minimum. The images have been analyzed to determine the brightness of the K-corona (solar photons Thomson scattered from free electrons). The total brightness of the K-corona is approximately constant from May 1996 through May 1997. The brightness is then seen to increase steadily until early in the year 2000. The structure of the K-corona changes dramatically with solar cycle. The shape as seen in C2 becomes almost circular at solar maximum while the C3 images continue to show equatorial streamers. The magnitude of the solar cycle variation decreases as the height increases. We present data animations (movies) to show the large-scale structure. We have inverted 28-day averages of the white light images to determine radial profiles of electron density. We present these electron profiles, show how they vary as a function of both latitude and time, and compare our observed profiles with other models and observations.

Sb2O3/Ag/Sb2O3 Multilayer Transparent Conducting Films For Ultraviolet Organic Light-emitting Diode

NASA Astrophysics Data System (ADS)

Song, Chunyan; Zhang, Nan; Lin, Jie; Guo, Xiaoyang; Liu, Xingyuan

2017-01-01

A novel UV transparent conducting films based on Sb2O3/Ag/Sb2O3 (SAS) structure, which were prepared by an electron-beam thermal evaporation at room temperature. This SAS exhibits excellent electrical, optical and stable properties. Especially for UV region, the SAS has high transmittance of 80% at 306 nm and 92% at 335 nm, meanwhile achieving low sheet resistance ( ≤ 10 Ω sq-1). The UV OLED based on the SAS show competitive device performance. The UV OLED obtains the peak of UV electroluminescence at 376 nm and shows a very high maximum EQE of 4.1% with the maximum output power density of 5.18 mW cm-2. These results indicate that the potential of SAS applications in deep UV transparent electrodes and large-scale flexible transparent electronics.

Sb2O3/Ag/Sb2O3 Multilayer Transparent Conducting Films For Ultraviolet Organic Light-emitting Diode.

PubMed

Song, Chunyan; Zhang, Nan; Lin, Jie; Guo, Xiaoyang; Liu, Xingyuan

2017-01-25

A novel UV transparent conducting films based on Sb 2 O 3 /Ag/Sb 2 O 3 (SAS) structure, which were prepared by an electron-beam thermal evaporation at room temperature. This SAS exhibits excellent electrical, optical and stable properties. Especially for UV region, the SAS has high transmittance of 80% at 306 nm and 92% at 335 nm, meanwhile achieving low sheet resistance ( ≤ 10 Ω sq -1 ). The UV OLED based on the SAS show competitive device performance. The UV OLED obtains the peak of UV electroluminescence at 376 nm and shows a very high maximum EQE of 4.1% with the maximum output power density of 5.18 mW cm -2 . These results indicate that the potential of SAS applications in deep UV transparent electrodes and large-scale flexible transparent electronics.

Sb2O3/Ag/Sb2O3 Multilayer Transparent Conducting Films For Ultraviolet Organic Light-emitting Diode

PubMed Central

Song, Chunyan; Zhang, Nan; Lin, Jie; Guo, Xiaoyang; Liu, Xingyuan

2017-01-01

A novel UV transparent conducting films based on Sb2O3/Ag/Sb2O3 (SAS) structure, which were prepared by an electron-beam thermal evaporation at room temperature. This SAS exhibits excellent electrical, optical and stable properties. Especially for UV region, the SAS has high transmittance of 80% at 306 nm and 92% at 335 nm, meanwhile achieving low sheet resistance ( ≤ 10 Ω sq−1). The UV OLED based on the SAS show competitive device performance. The UV OLED obtains the peak of UV electroluminescence at 376 nm and shows a very high maximum EQE of 4.1% with the maximum output power density of 5.18 mW cm−2. These results indicate that the potential of SAS applications in deep UV transparent electrodes and large-scale flexible transparent electronics. PMID:28120888

Simultaneous Solar Maximum Mission and Very Large Array (VLA) observations of solar active regions

NASA Technical Reports Server (NTRS)

Lang, K. R.

1985-01-01

Simultaneous observations of solar active regions with the Solar Maximum Mission (SMM) Satellite and the Very Large Array (VLA) have been obtained and analyzed. Combined results enhance the scientific return for beyond that expeted from using either SMM or VLA alone. A total of two weeks of simultaneous SMM/VLA data were obtained. The multiple wavelength VLA observations were used to determine the temperature and magnetic structure at different heights within coronal loops. These data are compared with simultaneous SMM observations. Several papers on the subject are in progress. They include VLA observations of compact, transient sources in the transition region; simultaneous SMM/VLA observations of the coronal loops in one active region and the evolution of another one; and sampling of the coronal plasma using thermal cyclotron lines (magnetic field - VLA) and soft X ray spectral lines (electron density and electron temperaure-SMM).

High Performance 0.1 μm GaAs Pseudomorphic High Electron Mobility Transistors with Si Pulse-Doped Cap Layer for 77 GHz Car Radar Applications

NASA Astrophysics Data System (ADS)

Kim, Sungwon; Noh, Hunhee; Jang, Kyoungchul; Lee, JaeHak; Seo, Kwangseok

2005-04-01

In this study, 0.1 μm double-recessed T-gate GaAs pseudomorphic high electron mobility transistors (PHEMT’s), in which an InGaAs layer and a Si pulse-doped layer in the cap structure are inserted, have been successfully fabricated. This cap structure improves ohmic contact. The ohmic contact resistance is as small as 0.07 Ωmm, consequently the source resistance is reduced by about 20% compared to that of a conventional cap structure. This device shows good DC and microwave performance such as an extrinsic transconductance of 620 mS/mm, a maximum saturated drain current of 780 mA/mm, a cut-off frequency fT of 140 GHz and a maximum oscillation frequency of 260 GHz. The reverse breakdown is 5.7 V at a gate current density of 1 mA/mm. The maximum available gain is about 7 dB at 77 GHz. It is well suited for car radar monolithic microwave integrated circuits (MMICs).

The modeling of gold recovery from tetrachloroaurate wastewater using a microbial fuel cell.

PubMed

Choi, Chansoo; Hu, Naixu

2013-04-01

In this study, tetrachloroaurate as an electron acceptor of a microbial fuel cell (MFC) has been studied to discover the parameters that affect the cost-effective recovery of gold. The modeling and equations for calculating the maximum actual efficiency and electrochemical impedance spectroscopic internal resistance of the MFC were also developed. The maximum power density (Pmax) of 6.58 W/m(2) with a fill factor of 0.717 was achieved for 60 mL volumes of 2000 ppm Au(III) catholyte and 12.2 mM acetate anolyte, respectively. The Pmax can also be predicted simply by measuring Rint by EIS. Additionally, the maximum actual MFC efficiency of about 57% was achieved, and the recovery efficiency of Au and the remaining concentration reached 99.89±0.00% and 0.22±0.00 ppm, respectively, for an Au(III) concentration of 200 ppm. The anodic concentration polarization quenching of the MFC strongly supports a mediator mechanism for the electron transfer from the microorganism to the anode. Copyright © 2013 Elsevier Ltd. All rights reserved.

Model analysis and electrical characterization of atmospheric pressure cold plasma jet in pin electrode configuration

NASA Astrophysics Data System (ADS)

Deepak, G. Divya; Joshi, N. K.; Prakash, Ram

2018-05-01

In this study, both model analysis and electrical characterization of a dielectric barrier discharge based argon plasma jet have been carried at atmospheric pressure in a pin electrode configuration. The plasma and fluid dynamics modules of COMSOL multi-physics code have been used for the modeling of the plasma jet. The plasma parameters, such as, electron density, electron temperature and electrical potential have been analyzed with respect to the electrical parameters, i.e., supply voltage and supply frequency with and without the flow of gas. In all the experiments, gas flow rate has been kept constant at 1 liter per minute. This electrode configuration is subjected to a range of supply frequencies (10-25 kHz) and supply voltages (3.5-6.5 kV). The power consumed by the device has been estimated at different applied combinations (supply voltage & frequency) for optimum power consumption at maximum jet length. The maximum power consumed by the device in this configuration for maximum jet length of ˜26 mm is just ˜1 W.

Comparison of measured and modelled negative hydrogen ion densities at the ECR-discharge HOMER

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rauner, D.; Kurutz, U.; Fantz, U.

2015-04-08

As the negative hydrogen ion density n{sub H{sup −}} is a key parameter for the investigation of negative ion sources, its diagnostic quantification is essential in source development and operation as well as for fundamental research. By utilizing the photodetachment process of negative ions, generally two different diagnostic methods can be applied: via laser photodetachment, the density of negative ions is measured locally, but only relatively to the electron density. To obtain absolute densities, the electron density has to be measured additionally, which induces further uncertainties. Via cavity ring-down spectroscopy (CRDS), the absolute density of H{sup −} is measured directly,more » however LOS-averaged over the plasma length. At the ECR-discharge HOMER, where H{sup −} is produced in the plasma volume, laser photodetachment is applied as the standard method to measure n{sub H{sup −}}. The additional application of CRDS provides the possibility to directly obtain absolute values of n{sub H{sup −}}, thereby successfully bench-marking the laser photodetachment system as both diagnostics are in good agreement. In the investigated pressure range from 0.3 to 3 Pa, the measured negative hydrogen ion density shows a maximum at 1 to 1.5 Pa and an approximately linear response to increasing input microwave powers from 200 up to 500 W. Additionally, the volume production of negative ions is 0-dimensionally modelled by balancing H{sup −} production and destruction processes. The modelled densities are adapted to the absolute measurements of n{sub H{sup −}} via CRDS, allowing to identify collisions of H{sup −} with hydrogen atoms (associative and non-associative detachment) to be the dominant loss process of H{sup −} in the plasma volume at HOMER. Furthermore, the characteristic peak of n{sub H{sup −}} observed at 1 to 1.5 Pa is identified to be caused by a comparable behaviour of the electron density with varying pressure, as n{sub e} determines the volume production rate via dissociative electron attachment to vibrationally excited hydrogen molecules.« less

Ultrafast electron radiography of magnetic fields in high-intensity laser-solid interactions.

PubMed

Schumaker, W; Nakanii, N; McGuffey, C; Zulick, C; Chyvkov, V; Dollar, F; Habara, H; Kalintchenko, G; Maksimchuk, A; Tanaka, K A; Thomas, A G R; Yanovsky, V; Krushelnick, K

2013-01-04

Using electron bunches generated by laser wakefield acceleration as a probe, the temporal evolution of magnetic fields generated by a 4 × 10(19) W/cm(2) ultrashort (30 fs) laser pulse focused on solid density targets is studied experimentally. Magnetic field strengths of order B(0) ~ 10(4) T are observed expanding at close to the speed of light from the interaction point of a high-contrast laser pulse with a 10-μm-thick aluminum foil to a maximum diameter of ~1 mm. The field dynamics are shown to agree with particle-in-cell simulations.

The Influence of the Surface Neutralization of Active Impurities on the Field-Electron Emission Properties of p-Type Silicon Crystals

NASA Astrophysics Data System (ADS)

Yafarov, R. K.

2017-12-01

Correlation dependences between variations of the structural-phase composition, morphology characteristics, and field-electron-emission (FEE) properties of surface-structured p-type silicon singlecrystalline (100)-oriented wafers have been studied during their stepwise high-dose carbon-ion-beam irradiation. It is established that the stepwise implantation of carbon decreases the FEE threshold and favors an increase in the maximum FEE-current density by more than two orders of magnitude. Physicochemical mechanisms involved in this modification of the properties of near-surface layers of silicon under carbon-ion implantation are considered.

Influence of damping on proton energy loss in plasmas of all degeneracies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barriga-Carrasco, Manuel D.

2007-07-15

The purpose of the present paper is to describe the effects of electron-electron collisions on the stopping power of plasmas of any degeneracy. Plasma targets are considered fully ionized so electronic stopping is only due to the free electrons. We focus our analysis on plasmas which electronic density is around solid values n{sub e}{approx_equal}10{sup 23} cm{sup -3} and which temperature is around T{approx_equal}10 eV; these plasmas are in the limit of weakly coupled plasmas. This type of plasma has not been studied extensively though it is very important for inertial confinement fusion. The electronic stopping is obtained from an exactmore » quantum mechanical evaluation, which takes into account the degeneracy of the target plasma, and later it is compared with common classical and degenerate approximations. Differences are around 30% in some cases which can produce bigger mistakes in further energy deposition and projectile range studies. Then we consider electron-electron collisions in the exact quantum mechanical electronic stopping calculation. Now the maximum stopping occurs at velocities smaller than for the calculations without considering collisions for all kinds of plasmas analyzed. The energy loss enhances for velocities smaller than the velocity at maximum while decreases for higher velocities. Latter effects are magnified with increasing collision frequency. Differences with the same results for the case of not taking into account collisions are around 20% in the analyzed cases.« less

Cathodic reduction of hexavalent chromium [Cr(VI)] coupled with electricity generation in microbial fuel cells.

PubMed

Wang, Gang; Huang, Liping; Zhang, Yifeng

2008-11-01

A novel approach to Cr(VI)-contaminated wastewater treatment was investigated using microbial fuel cell technologies in fed-batch mode. By using synthetic Cr(VI)-containing wastewater as catholyte and anaerobic microorganisms as anodic biocatalyst, Cr(VI) at 100 mg/l was completely removed during 150 h (initial pH 2). The maximum power density of 150 mW/m(2) (0.04 mA/cm(2)) and the maximum open circuit voltage of 0.91 V were generated with Cr(VI) at 200 mg/l as electron acceptor. This work verifies the possibility of simultaneous electricity production and cathodic Cr(VI) reduction.

Note: Characterization of the plasma parameters of a capillary discharge-produced plasma channel waveguide to guide an intense laser pulse

DOE Office of Scientific and Technical Information (OSTI.GOV)

Higashiguchi, Takeshi; Yugami, Noboru; CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kanagawa, Saitama 332-0012

2010-04-15

We demonstrated the production of an optical waveguide in a capillary discharge-produced plasma using a cylindrical capillary. Plasma parameters of its waveguide were characterized by use of both a Nomarski laser interferometer and a hydrogen plasma line spectrum. A space-averaged maximum temperature of 3.3 eV with electron densities of the order of 10{sup 17} cm{sup -3} was observed at a discharge time of 150 ns and a maximum discharge current of 400 A. An ultrashort, intense laser pulse was guided by use of this plasma channel.

Carbon fiber enhanced bioelectricity generation in soil microbial fuel cells.

PubMed

Li, Xiaojing; Wang, Xin; Zhao, Qian; Wan, Lili; Li, Yongtao; Zhou, Qixing

2016-11-15

The soil microbial fuel cell (MFC) is a promising biotechnology for the bioelectricity recovery as well as the remediation of organics contaminated soil. However, the electricity production and the remediation efficiency of soil MFC are seriously limited by the tremendous internal resistance of soil. Conductive carbon fiber was mixed with petroleum hydrocarbons contaminated soil and significantly enhanced the performance of soil MFC. The maximum current density, the maximum power density and the accumulated charge output of MFC mixed carbon fiber (MC) were 10, 22 and 16 times as high as those of closed circuit control due to the carbon fiber productively assisted the anode to collect the electron. The internal resistance of MC reduced by 58%, 83% of which owed to the charge transfer resistance, resulting in a high efficiency of electron transfer from soil to anode. The degradation rates of total petroleum hydrocarbons enhanced by 100% and 329% compared to closed and opened circuit controls without the carbon fiber respectively. The effective range of remediation and the bioelectricity recovery was extended from 6 to 20cm with the same area of air-cathode. The mixed carbon fiber apparently enhanced the bioelectricity generation and the remediation efficiency of soil MFC by means of promoting the electron transfer rate from soil to anode. The use of conductively functional materials (e.g. carbon fiber) is very meaningful for the remediation and bioelectricity recovery in the bioelectrochemical remediation. Copyright © 2016 Elsevier B.V. All rights reserved.

Impact of low-dose electron irradiation on $$n^{+}p$$ silicon strip sensors

DOE PAGES

Adam, W.

2015-08-28

The response of n +p silicon strip sensors to electrons from a 90Sr source was measured using a multi-channel read-out system with 25 ns sampling time. The measurements were performed over a period of several weeks, during which the operating conditions were varied. The sensors were fabricated by Hamamatsu Photonics on 200 μm thick float-zone and magnetic-Czochralski silicon. Their pitch was 80 μm, and both p-stop and p-spray isolation of the n + strips were studied. The electrons from the 90Sr source were collimated to a spot with a full-width-at-half-maximum of 2 mm at the sensor surface, and the dosemore » rate in the SiO 2 at the maximum was about 50 Gy(SiO 2)/d. After only a few hours of making measurements, significant changes in charge collection and charge sharing were observed. Annealing studies, with temperatures up to 80 °C and annealing times of 18 h showed that the changes can only be partially annealed. The observations can be qualitatively explained by the increase of the positive oxide-charge density due to the ionization of the SiO 2 by the radiation from the β source. TCAD simulations of the electric field in the sensor for different oxide-charge densities and different boundary conditions at the sensor surface support this explanation. As a result, the relevance of the measurements for the design of n +p strip sensors is discussed.« less

Spectral optimization for measuring electron density by the dual-energy computed tomography coupled with balanced filter method.

PubMed

Saito, Masatoshi

2009-08-01

Dual-energy computed tomography (DECT) has the potential for measuring electron density distribution in a human body to predict the range of particle beams for treatment planning in proton or heavy-ion radiotherapy. However, thus far, a practical dual-energy method that can be used to precisely determine electron density for treatment planning in particle radiotherapy has not been developed. In this article, another DECT technique involving a balanced filter method using a conventional x-ray tube is described. For the spectral optimization of DECT using balanced filters, the author calculates beam-hardening error and air kerma required to achieve a desired noise level in electron density and effective atomic number images of a cylindrical water phantom with 50 cm diameter. The calculation enables the selection of beam parameters such as tube voltage, balanced filter material, and its thickness. The optimized parameters were applied to cases with different phantom diameters ranging from 5 to 50 cm for the calculations. The author predicts that the optimal combination of tube voltages would be 80 and 140 kV with Tb/Hf and Bi/Mo filter pairs for the 50-cm-diameter water phantom. When a single phantom calibration at a diameter of 25 cm was employed to cover all phantom sizes, maximum absolute beam-hardening errors were 0.3% and 0.03% for electron density and effective atomic number, respectively, over a range of diameters of the water phantom. The beam-hardening errors were 1/10 or less as compared to those obtained by conventional DECT, although the dose was twice that of the conventional DECT case. From the viewpoint of beam hardening and the tube-loading efficiency, the present DECT using balanced filters would be significantly more effective in measuring the electron density than the conventional DECT. Nevertheless, further developments of low-exposure imaging technology should be necessary as well as x-ray tubes with higher outputs to apply DECT coupled with the balanced filter method for clinical use.

X-ray photoelectron spectrum and electronic properties of a noncentrosymmetric chalcopyrite compound HgGa(2)S(4): LDA, GGA, and EV-GGA.

PubMed

Reshak, Ali Hussain; Khenata, R; Kityk, I V; Plucinski, K J; Auluck, S

2009-04-30

An all electron full potential linearized augmented plane wave method has been applied for a theoretical study of the band structure, density of states, and electron charge density of a noncentrosymmetric chalcopyrite compound HgGa(2)S(4) using three different approximations for the exchange correlation potential. Our calculations show that the valence band maximum (VBM) and conduction band minimum (CBM) are located at Gamma resulting in a direct energy gap of about 2.0, 2.2, and 2.8 eV for local density approximation (LDA), generalized gradient approximation (GGA), and Engel-Vosko (EVGGA) compared to the experimental value of 2.84 eV. We notice that EVGGA shows excellent agreement with the experimental data. This agreement is attributed to the fact that the Engel-Vosko GGA formalism optimizes the corresponding potential for band structure calculations. We make a detailed comparison of the density of states deduced from the X-ray photoelectron spectra with our calculations. We find that there is a strong covalent bond between the Hg and S atoms and Ga and S atoms. The Hg-Hg, Ga-Ga, and S-S bonds are found to be weaker than the Hg-S and Ga-S bonds showing that a covalent bond exists between Hg and S atoms and Ga and S atoms.

Layered-MnO₂ Nanosheet Grown on Nitrogen-Doped Graphene Template as a Composite Cathode for Flexible Solid-State Asymmetric Supercapacitor.

PubMed

Liu, Yongchuan; Miao, Xiaofei; Fang, Jianhui; Zhang, Xiangxin; Chen, Sujing; Li, Wei; Feng, Wendou; Chen, Yuanqiang; Wang, Wei; Zhang, Yining

2016-03-02

Flexible solid-state supercapacitors provide a promising energy-storage alternative for the rapidly growing flexible and wearable electronic industry. Further improving device energy density and developing a cheap flexible current collector are two major challenges in pushing the technology forward. In this work, we synthesize a nitrogen-doped graphene/MnO2 nanosheet (NGMn) composite by a simple hydrothermal method. Nitrogen-doped graphene acts as a template to induce the growth of layered δ-MnO2 and improves the electronic conductivity of the composite. The NGMn composite exhibits a large specific capacitance of about 305 F g(-1) at a scan rate of 5 mV s(-1). We also create a cheap and highly conductive flexible current collector using Scotch tape. Flexible solid-state asymmetric supercapacitors are fabricated with NGMn cathode, activated carbon anode, and PVA-LiCl gel electrolyte. The device can achieve a high operation voltage of 1.8 V and exhibits a maximum energy density of 3.5 mWh cm(-3) at a power density of 0.019 W cm(-3). Moreover, it retains >90% of its initial capacitance after 1500 cycles. Because of its flexibility, high energy density, and good cycle life, NGMn-based flexible solid state asymmetric supercapacitors have great potential for application in next-generation portable and wearable electronics.

Optical characteristics and parameters of gas-discharge plasma in a mixture of mercury dibromide vapor with argon

NASA Astrophysics Data System (ADS)

Malinina, A. A.; Malinin, A. N.

2015-03-01

Results are presented from studies of the optical characteristics and parameters of the plasma of a dielectric barrier discharge in a mixture of mercury dibromide vapor with argon—the working medium of an exciplex gas-discharge emitter. It is established that the partial pressures of mercury dibromide vapor and argon at which the average and pulsed emission intensities in the blue—green spectral region (λmax = 502 nm) reach their maximum values are 0.6 and 114.4 kPa, respectively. The electron energy distribution function, the transport characteristics, the specific power spent on the processes involving electrons, the electron density and temperature, and the rate constants for the processes of elastic and inelastic electron scattering from the molecules and atoms of the working mixture are determined by numerical simulation, and their dependences on the reduced electric field strength are analyzed. The rate constant of the process leading to the formation of exciplex mercury monobromide molecules for a reduced electric field of E/ N = 20 Td, at which the maximum emission intensity in the blue—green spectral region was observed in this experiment, is found to be 8.1 × 10-15 m3/s.

Electron acceleration by laser produced wake field: Pulse shape effect

NASA Astrophysics Data System (ADS)

Malik, Hitendra K.; Kumar, Sandeep; Nishida, Yasushi

2007-12-01

Analytical expressions are obtained for the longitudinal field (wake field: Ex), density perturbations ( ne') and the potential ( ϕ) behind a laser pulse propagating in a plasma with the pulse duration of the electron plasma period. A feasibility study on the wake field is carried out with Gaussian-like (GL) pulse, rectangular-triangular (RT) pulse and rectangular-Gaussian (RG) pulse considering one-dimensional weakly nonlinear theory ( ne'/n0≪1), and the maximum energy gain acquired by an electron is calculated for all these three types of the laser pulse shapes. A comparative study infers that the RT pulse yields the best results: In its case maximum electron energy gain is 33.5 MeV for a 30 fs pulse duration whereas in case of GL (RG) pulse of the same duration the gain is 28.6 (28.8)MeV at the laser frequency of 1.6 PHz and the intensity of 3.0 × 10 18 W/m 2. The field of the wake and hence the energy gain get enhanced for the higher laser frequency, larger pulse duration and higher laser intensity for all types of the pulses.

On Spatial Structuring of the F2 Layer Studied by the Satellite Radio Sounding of the Ionosphere Disturbed by High-Power HF Radio Waves

NASA Astrophysics Data System (ADS)

Tereshchenko, E. D.; Turyansky, V. A.; Khudukon, B. Z.; Yurik, R. Yu.; Frolov, V. L.

2018-01-01

We present the results of studying the characteristics of the artificial plasma structures excited in the ionospheric F2 region modified by high-power HF radio waves. The experiments were carried out at the Sura heating facility using satellite radio sounding of the ionosphere. The plasma density profile was reconstructed with the highest possible spatial resolution for today, about 4 km. In a direction close to the magnetic zenith of the pump wave, the following phenomena were observed: the formation of a cavity with a 15% lower plasma density at the altitudes of the F2 layer and below; the formation of an area with plasma density increased by 12% at altitudes greater than 400 km. With a long-term quasiperiodic impact of the pump wave on the ionosphere, wavy large-scale electron-density perturbations (the meridional scale λx ≈ 130 km and the vertical scale λz ≈ 440 km) are also formed above the Sura facility. These perturbations can be due to the plasma density modulation by an artificial acoustic-gravity wave with a period of 10.6 m, which was formed by the heat source inside a large-scale cavity with low plasma density; there is generation of the electron density irregularities for the electrons with ΔNe/Ne ≈ 3% in the form of layers having the sizes 10-12 km along and about 24 km across the geomagnetic field, which are found both below and above the F2-layer maximum. The mechanisms of the formation of these plasma structures are discussed.

The electron content of the southern mid-latitude ionosphere, 1965-1971.

NASA Technical Reports Server (NTRS)

Titheridge, J. E.

1973-01-01

Continuous accurate records of the electron content of the ionosphere are obtained at Auckland (ionosphere point at 34 deg S geographic, 38 deg geomagnetic) and at Invercargill (42 deg S geographic, 47 deg geomagnetic). Mean hourly values scaled from these records are used to show the average diurnal, seasonal and solar cycle changes in the ionosphere from June 1965 to August 1971. The mean daytime electron content shows no seasonal anomaly at any stage of the solar cycle, at 34 deg S. There is some anomaly at 42 deg S, particularly near solar maximum. The anomaly becomes quite marked in terms of peak density because of a contraction of the ionosphere in winter. The mean amplitude of the day-to-day fluctuations in electron content shows no appreciable solar cycle change.

Dose in bone and tissue near bone-tissue interface from electron beam.

PubMed

Shiu, A S; Hogstrom, K R

1991-08-01

This work has quantitatively studied the variation of dose both within bone and in unit density tissue near bone-tissue interfaces. Dose upstream of a bone-tissue interface is increased because of an increase in the backscattered electrons from the bone. The magnitude of this effect was measured using a thin parallel-plate ionization chamber upstream of a polymethyl methacrylate (PMMA)-hard bone interface. The electron backscatter factor (EBF) increased rapidly with bone thickness until a full EBF was achieved. This occurred at approximately 3.5 mm at 2 MeV and 6 mm at 13.1 MeV. The full EBF at the interface ranged from approximately 1.018 at 13.1 MeV to 1.05 at 2 MeV. It was also observed that the EBF had a dependence on the energy spectrum at the interface. The penetration of the backscattered electrons in the upstream direction of PMMA was also measured. The dose penetration fell off rapidly in the upstream direction of the interface. Dose enhancement to unit density tissue in bone was measured for an electron beam by placing thermoluminescent dosimeters (TLDs) in a PMMA-bone-PMMA phantom. The maximum dose enhancement in bone was approximately 7% of the maximum dose in water. However, the pencil-beam algorithm of Hogstrom et al. predicted an increase of only 1%, primarily owing to the inverse-square correction. Film was also used to measure the dose enhancement in bone. The film plane was aligned either perpendicular or parallel to the central axis of the beam. The film data indicated that the maximum dose enhancement in bone was approximately 8% for the former film alignment (which was similarly predicted by the TLD measurements) and 13% for the latter film alignment. These results confirm that the X ray film is not suitable to be irritated "edge on" in an inhomogeneous phantom without making perturbation corrections resulting from the film acting as a long narrow inhomogeneous cavity within the bone. In addition, the results give the radiotherapist a basis for clinical judgment when electron beams are used to treat lesions behind bone or near bony structures. We feel these data enhance the ability to recognize the shortcomings of the current dose calculation algorithm used clinically.

Modeling of O+ ions in the plasmasphere

NASA Astrophysics Data System (ADS)

Guiter, S. M.; Moore, T. E.; Khazanov, G. V.

1995-11-01

Heavy ion (O+, O++, and N+) density enhancements in the outer plasmasphere have been observed using the retarding ion mass spectrometer instrument on the DE 1 satellite. These are seen at L shells from 2 to 5, with most occurrences in the L=3 to 4 region; the maximum L shell at which these enhancements occur varies inversely with Dst. It is also known that enhancements of O+ and O++ overlie ionospheric electron temperature peaks. It is thought that these enhancements are related to heating of plasmaspheric particles through interactions with ring current ions. This was investigated using a time-dependent one-stream hydrodynamic model for plasmaspheric flows, in which the model flux tube is connected to the ionosphere. The model simultaneously solves the coupled continuity, momentum, and energy equations of a two-ion (H+ and O+) quasi-neutral, currentless plasma. This model is fully interhemispheric and diffusive equilibrium is not assumed; it includes a corotating tilted dipole magnetic field and neutral winds. First, diurnally reproducible results were found assuming only photoelectron heating of thermal electrons. For this case the modeled equatorial O+ density was below 1 cm-3 throughout the day. The O+ results also show significant diurnal variability, with standing shocks developing when production stops and O+ flows downward under the influence of gravity. Numerical tests were done with different levels of electron heating in the plasmasphere; these show that the equatorial O+ density is highly dependent on the assumed electron heating rates. Over the range of integrated plasmaspheric electron heating (along the flux tube) from 8.7 to 280×109 eV/s, the equatorial O+ density goes like the heating raised to the power 2.3.

Amide group anchored glucose oxidase based anodic catalysts for high performance enzymatic biofuel cell

NASA Astrophysics Data System (ADS)

Chung, Yongjin; Ahn, Yeonjoo; Kim, Do-Heyoung; Kwon, Yongchai

2017-01-01

A new enzyme catalyst is formed by fabricating gold nano particle (GNP)-glucose oxidase (GOx) clusters that are then attached to polyethyleneimine (PEI) and carbon nanotube (CNT) with cross-linkable terephthalaldehyde (TPA) (TPA/[CNT/PEI/GOx-GNP]). Especially, amide bonds belonging to TPA play an anchor role for incorporating rigid bonding among GNP, GOx and CNT/PEI, while middle size GNP is well bonded with thiol group of GOx to form strong GNP-GOx cluster. Those bonds are identified by chemical and electrochemical characterizations like XPS and cyclic voltammogram. The anchording effect of amide bonds induces fast electron transfer and strong chemical bonding, resulting in enhancements in (i) catalytic activity, (ii) amount of immobilized GOx and (ii) performance of enzymatic biofuel cell (EBC) including the catalyst. Regarding the catalytic activity, the TPA/[CNT/PEI/GOx-GNP] produces high electron transfer rate constant (6 s-1), high glucose sensitivity (68 μA mM-1 cm-2), high maximum current density (113 μA cm-2), low charge transfer resistance (17.0 Ω cm2) and long-lasting durability while its chemical structure is characterized by XPS confirming large portion of amide bond. In EBC measurement, it has high maximum power density (0.94 mW cm-2) compatible with catalytic acitivity measurements.

Location of the valence band maximum in the band structure of anisotropic 1 T'-ReSe2

NASA Astrophysics Data System (ADS)

Eickholt, P.; Noky, J.; Schwier, E. F.; Shimada, K.; Miyamoto, K.; Okuda, T.; Datzer, C.; Drüppel, M.; Krüger, P.; Rohlfing, M.; Donath, M.

2018-04-01

Transition-metal dichalcogenides (TMDCs) are a focus of current research due to their fascinating optical and electronic properties with possible technical applications. ReSe2 is an interesting material of the TMDC family, with unique anisotropic properties originating from its distorted 1 T structure (1 T '). To develop a fundamental understanding of the optical and electric properties, we studied the underlying electronic structure with angle-resolved photoemission (ARPES) as well as band-structure calculations within the density functional theory (DFT)-local density approximation (LDA) and GdW approximations. We identified the Γ ¯M¯1 direction, which is perpendicular to the a axis, as a distinct direction in k space with the smallest bandwidth of the highest valence band. Using photon-energy-dependent ARPES, two valence band maxima are identified within experimental limits of about 50 meV: one at the high-symmetry point Z , and a second one at a non-high-symmetry point in the Brillouin zone. Thus, the position in k space of the global valence band maximum is undecided experimentally. Theoretically, an indirect band gap is predicted on a DFT-LDA level, while quasiparticle corrections lead to a direct band gap at the Z point.

Charge transfer and optical properties of trifluoromethyl substituted benzodithiophene (TFMBDT): A theoretical study

NASA Astrophysics Data System (ADS)

Sahoo, Smruti Ranjan; Sahu, Sridhar; Sharma, Sagar

2018-05-01

We present density functional study of the charge transport and optical properties of trifluoromethyl substituted benzodithiophene (TFMBDT) molecule. We found the hole reorganization energy, reduced by 0.354 eV compared to the electron reorganization energy, thus favoring the hole transport across the molecular barrier. We found the maximum tH and tL at the tilting angle 85°, to be 0.473 eV and 0.472 eV, respectively. Although, both tH and tL are found to equivalent, however, low λh can contribute to the larger hole mobility. In the TD-DFT calculation, the low energy electronic transition (H→L) was found to be accordance with the electronic HOMO-LUMO energy gap of the conjugated organic molecule. The calculated gas phase maximum absorption (λmax) of TFMBDT molecule was observed at 337.31 nm (3.67 eV) for B3LYP/6-311+G(d, p) level and 328.04 nm (3.77 eV) for PBE1PBE/6-311+G(d, p) level, which is mostly associated with HOMO→LUMO transition.

Normally-off p-GaN/AlGaN/GaN high electron mobility transistors using hydrogen plasma treatment

NASA Astrophysics Data System (ADS)

Hao, Ronghui; Fu, Kai; Yu, Guohao; Li, Weiyi; Yuan, Jie; Song, Liang; Zhang, Zhili; Sun, Shichuang; Li, Xiajun; Cai, Yong; Zhang, Xinping; Zhang, Baoshun

2016-10-01

In this letter, we report a method by introducing hydrogen plasma treatment to realize normally-off p-GaN/AlGaN/GaN HEMT devices. Instead of using etching technology, hydrogen plasma was adopted to compensate holes in the p-GaN above the two dimensional electron gas (2DEG) channel to release electrons in the 2DEG channel and form high-resistivity area to reduce leakage current and increase gate control capability. The fabricated p-GaN/AlGaN/GaN HEMT exhibits normally-off operation with a threshold voltage of 1.75 V, a subthreshold swing of 90 mV/dec, a maximum transconductance of 73.1 mS/mm, an ON/OFF ratio of 1 × 107, a breakdown voltage of 393 V, and a maximum drain current density of 188 mA/mm at a gate bias of 6 V. The comparison of the two processes of hydrogen plasma treatment and p-GaN etching has also been made in this work.

The Mesoscale Ionospheric Simulation Testbed (MIST) Regional Data Assimilation Model (Invited)

NASA Astrophysics Data System (ADS)

Comberiate, J.; Kelly, M. A.; Miller, E.; Paxton, L.

2013-12-01

The Mesoscale Ionospheric Simulation Testbed (MIST) provides a regional nowcast and forecast of electron density values and has sufficient resolution to include equatorial plasma bubbles. The SSUSI instrument on the DMSP F18 satellite has high-resolution nightly observations of plasma bubbles at 8 PM local time throughout the current solar maximum. MIST can assimilate SSUSI UV observations, GPS TEC measurements, and SCINDA S4 readings simultaneously into a single scintillation map over a region of interest. MIST also models ionospheric physics to provide a short-term UHF scintillation forecast based on assimilated data. We will present examples of electron density and scintillation maps from MIST. We will also discuss the potential to predict scintillation occurrence up to 6 hours in advance using observations of the equatorial arcs from SSUSI observations at 5:30 PM local time on the DMSP F17 satellite.

Midlatitude sporadic-E layers

NASA Technical Reports Server (NTRS)

Miller, K. L.; Smith, L. G.

1976-01-01

The partially transparent echo from midlatitude sporadic E layers was recorded by ionosondes between the blanketing frequency and the maximum frequency. The theory that the midlatitude sporadic E layers are not uniform in the horizontal plane but contain localized regions of high electron density was evaluated using data obtained by incoherent scatter radar and found to provide a satisfactory explanation. The main features of midlatitude sporadic E layers are consistent with the convergence of metallic ions as described by the wind shear theory applied to gravity waves and tides. The interference of gravity waves with other gravity waves and tides can be recognized in the altitudes of occurrence and the structure of the layers. Small scale horizontal irregularities are attributed in some cases to critical level effects and in others to fluid instabilities. The convergence of a meteor trail can, under some circumstances, account for localized enhancement of the electron density in the layer.

Studies on effective atomic numbers for photon energy absorption and electron density of some narcotic drugs in the energy range 1 keV-20 MeV

NASA Astrophysics Data System (ADS)

Gounhalli, Shivraj G.; Shantappa, Anil; Hanagodimath, S. M.

2013-04-01

Effective atomic numbers for photon energy absorption ZPEA,eff, photon interaction ZPI,eff and for electron density Nel, have been calculated by a direct method in the photon-energy region from 1 keV to 20 MeV for narcotic drugs, such as Heroin (H), Cocaine (CO), Caffeine (CA), Tetrahydrocannabinol (THC), Cannabinol (CBD), Tetrahydrocannabivarin (THCV). The ZPEA,eff, ZPI,eff and Nel values have been found to change with energy and composition of the narcotic drugs. The energy dependence ZPEA,eff, ZPI,eff and Nel is shown graphically. The maximum difference between the values of ZPEA,eff, and ZPI,eff occurs at 30 keV and the significant difference of 2 to 33% for the energy region 5-100 keV for all drugs. The reason for these differences is discussed.

Ag-Cu nanoalloyed film as a high-performance cathode electrocatalytic material for zinc-air battery

NASA Astrophysics Data System (ADS)

Lei, Yimin; Chen, Fuyi; Jin, Yachao; Liu, Zongwen

2015-04-01

A novel Ag50Cu50 film electrocatalyst for oxygen reduction reaction (ORR) was prepared by pulsed laser deposition (PLD) method. The electrocatalyst actually is Ag-Cu alloyed nanoparticles embedded in amorphous Cu film, based on transmission electron microscopy (TEM) characterization. The rotating disk electrode (RDE) measurements provide evidence that the ORR proceed via a four-electron pathway on the electrocatalysts in alkaline solution. And it is much more efficient than pure Ag catalyst. The catalytic layer has maximum power density of 67 mW cm-2 and an acceptable cell voltage at 0.863 V when current densities increased up to 100 mA cm-2 in the Ag50Cu50-based primary zinc-air battery. The resulting rechargeable zinc-air battery exhibits low charge-discharge voltage polarization of 1.1 V at 20 mAcm-2 and high durability over 100 cycles in natural air.

X-ray line ratios from helium-like ions - Updated theory and SMM flare observations

NASA Technical Reports Server (NTRS)

Wolfson, C. J.; Leibacher, J. W.; Doyle, J. G.; Phillips, K. J. H.

1983-01-01

The potential which the conduction of measurements of the three principal lines emitted from helium-like ions has for the determination of plasma electron density was initially pointed out by Gabriel and Jordan (1969). The diagnostic technique is based on the fact that the ratio, R, of the intensity of a forbidden line to the intensity of an intercombination line decreases as electron density increases due to collisional excitation of levels. In the present investigation a further refinement of this procedure is provided by specifically calculating the effects of cascades from levels with principal quantum numbers up to n=6. Two improved spectrometers recently placed in operation include the SOLEX instrument on the satellite P78-1 and the X-ray Polychromator (XRP) instrument on the NASA Solar Maximum Mission satellite. Measurements obtained with one of the spectrometers making up the XRP are presented, taking into account the emission from Ne IX ions.

X-ray line ratios from helium-like ions - Updated theory and SMM flare observations

NASA Astrophysics Data System (ADS)

Wolfson, C. J.; Leibacher, J. W.; Doyle, J. G.; Phillips, K. J. H.

1983-06-01

The potential which the conduction of measurements of the three principal lines emitted from helium-like ions has for the determination of plasma electron density was initially pointed out by Gabriel and Jordan (1969). The diagnostic technique is based on the fact that the ratio, R, of the intensity of a forbidden line to the intensity of an intercombination line decreases as electron density increases due to collisional excitation of levels. In the present investigation a further refinement of this procedure is provided by specifically calculating the effects of cascades from levels with principal quantum numbers up to n=6. Two improved spectrometers recently placed in operation include the SOLEX instrument on the satellite P78-1 and the X-ray Polychromator (XRP) instrument on the NASA Solar Maximum Mission satellite. Measurements obtained with one of the spectrometers making up the XRP are presented, taking into account the emission from Ne IX ions.

Topside Electron Density Representations for Middle and High Latitudes: A Topside Parameterization for E-CHAIM Based On the NeQuick

NASA Astrophysics Data System (ADS)

Themens, David R.; Jayachandran, P. T.; Bilitza, Dieter; Erickson, Philip J.; Häggström, Ingemar; Lyashenko, Mykhaylo V.; Reid, Benjamin; Varney, Roger H.; Pustovalova, Ljubov

2018-02-01

In this study, we present a topside model representation to be used by the Empirical Canadian High Arctic Ionospheric Model (E-CHAIM). In the process of this, we also present a comprehensive evaluation of the NeQuick's, and by extension the International Reference Ionosphere's, topside electron density model for middle and high latitudes in the Northern Hemisphere. Using data gathered from all available incoherent scatter radars, topside sounders, and Global Navigation Satellite System Radio Occultation satellites, we show that the current NeQuick parameterization suboptimally represents the shape of the topside electron density profile at these latitudes and performs poorly in the representation of seasonal and solar cycle variations of the topside scale thickness. Despite this, the simple, one variable, NeQuick model is a powerful tool for modeling the topside ionosphere. By refitting the parameters that define the maximum topside scale thickness and the rate of increase of the scale height within the NeQuick topside model function, r and g, respectively, and refitting the model's parameterization of the scale height at the F region peak, H0, we find considerable improvement in the NeQuick's ability to represent the topside shape and behavior. Building on these results, we present a new topside model extension of the E-CHAIM based on the revised NeQuick function. Overall, root-mean-square errors in topside electron density are improved over the traditional International Reference Ionosphere/NeQuick topside by 31% for a new NeQuick parameterization and by 36% for a newly proposed topside for E-CHAIM.

Characterization of twin boundaries in an Fe–17.5Mn–0.56C twinning induced plasticity steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patterson, Erin E., E-mail: erin.diedrich@yahoo.com; Field, David P., E-mail: dfield@wsu.edu; Zhang, Yudong, E-mail: yudong.zhang@univ-metz.fr

2013-11-15

A twinning-induced plasticity steel of composition Fe–17.5 wt.% Mn–0.56 wt.% C–1.39 wt.% Al–0.24 wt.% Si was analyzed for the purpose of characterizing the relationship between tensile strain and deformation twinning. Tensile samples achieved a maximum of 0.46 true strain at failure, and a maximum ultimate tensile strength of 1599 MPa. Electron backscatter diffraction (EBSD) analysis showed that the grain orientation rotated heavily to < 111 > parallel to the tensile axis above 0.3 true strain. Sigma 3 misorientations, as identified by EBSD orientation measurements, and using the image quality maps were used to quantify the number of twins present inmore » the scanned areas of the samples. The image quality method yielded a distinct positive correlation between the twin area density and deformation, but the orientation measurements were unreliable in quantifying twin density in these structures. Quantitative analysis of the twin fraction is limited from orientation information because of the poor spatial resolution of EBSD in relation to the twin thickness. The EBSD orientation maps created for a thin foil sample showed some improvement in the resolution of the twins, but not enough to be significant. Measurements of the twins in the transmission electron microscopy micrographs yielded an average thickness of 23 nm, which is near the resolution capabilities of EBSD on this material for the instrumentation used. Electron channeling contrast imaging performed on one bulk tensile specimen of 0.34 true strain, using a method of controlled diffraction, yielded several images of twinning, dislocation structures and strain fields. A twin thickness of 66 nm was measured by the same method used for the transmission electron microscopy measurement. It is apparent that the results obtain by electron channeling contrast imaging were better than those by EBSD but did not capture all information on the twin boundaries such as was observed by transmission electron microscopy. - Highlights: • Performed tensile tests to assess mechanical performance of TWIP alloy • Analyzed tensile specimens using EBSD, TEM, and ECCI • EBSD showed that most twinning occurred at or near the < 111 >//TA orientation. • EBSD, TEM and ECCI were used to measure average twin density. • Compared spatial resolution of EBSD, ECCI and TEM for the instrumentation used.« less

A Hydrodynamic Theory for Spatially Inhomogeneous Semiconductor Lasers. 2; Numerical Results

NASA Technical Reports Server (NTRS)

Li, Jianzhong; Ning, C. Z.; Biegel, Bryan A. (Technical Monitor)

2001-01-01

We present numerical results of the diffusion coefficients (DCs) in the coupled diffusion model derived in the preceding paper for a semiconductor quantum well. These include self and mutual DCs in the general two-component case, as well as density- and temperature-related DCs under the single-component approximation. The results are analyzed from the viewpoint of free Fermi gas theory with many-body effects incorporated. We discuss in detail the dependence of these DCs on densities and temperatures in order to identify different roles played by the free carrier contributions including carrier statistics and carrier-LO phonon scattering, and many-body corrections including bandgap renormalization and electron-hole (e-h) scattering. In the general two-component case, it is found that the self- and mutual- diffusion coefficients are determined mainly by the free carrier contributions, but with significant many-body corrections near the critical density. Carrier-LO phonon scattering is dominant at low density, but e-h scattering becomes important in determining their density dependence above the critical electron density. In the single-component case, it is found that many-body effects suppress the density coefficients but enhance the temperature coefficients. The modification is of the order of 10% and reaches a maximum of over 20% for the density coefficients. Overall, temperature elevation enhances the diffusive capability or DCs of carriers linearly, and such an enhancement grows with density. Finally, the complete dataset of various DCs as functions of carrier densities and temperatures provides necessary ingredients for future applications of the model to various spatially inhomogeneous optoelectronic devices.

Density-functional theory for internal magnetic fields

NASA Astrophysics Data System (ADS)

Tellgren, Erik I.

2018-01-01

A density-functional theory is developed based on the Maxwell-Schrödinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and the total magnetic field, which can equivalently be represented as a physical current density. Hence, the theory can be regarded as a physical current density-functional theory and an alternative to the paramagnetic current density-functional theory due to Vignale and Rasolt. The energy functional has strong enough convexity properties to allow a formulation that generalizes Lieb's convex analysis formulation of standard density-functional theory. Several variational principles as well as a Hohenberg-Kohn-like mapping between potentials and ground-state densities follow from the underlying convex structure. Moreover, the energy functional can be regarded as the result of a standard approximation technique (Moreau-Yosida regularization) applied to the conventional Schrödinger ground-state energy, which imposes limits on the maximum curvature of the energy (with respect to the magnetic field) and enables construction of a (Fréchet) differentiable universal density functional.

Growth of low disorder GaAs/AlGaAs heterostructures by molecular beam epitaxy for the study of correlated electron phases in two dimensions

NASA Astrophysics Data System (ADS)

Watson, John D.

The unparalleled quality of GaAs/AlGaAs heterostructures grown by molecular beam epitaxy has enabled a wide range of experiments probing interaction effects in two-dimensional electron and hole gases. This dissertation presents work aimed at further understanding the key material-related issues currently limiting the quality of these 2D systems, particularly in relation to the fractional quantum Hall effect in the 2nd Landau level and spin-based implementations of quantum computation. The manuscript begins with a theoretical introduction to the quantum Hall effect which outlines the experimental conditions necessary to study the physics of interest and motivates the use of the semiconductor growth and cryogenic measurement techniques outlined in chapters 2 and 3, respectively. In addition to a generic introduction to the molecular beam epitaxy growth technique, chapter 2 summarizes some of what was learned about the material purity issues currently limiting the low temperature electron mobility. Finally, a series of appendices are included which detail the experimental methods used over the course of the research. Chapter 4 presents an experiment examining transport in a low density two-dimensional hole system in which the hole density could be varied by means of an evaporated back gate. At low temperature, the mobility reached a maximum of 2.6 x 106 cm2/Vs at a density of 6.2 x 1010 cm-2 which is the highest reported mobility in a two-dimensional hole system to date. In addition, it was found that the mobility as a function of density did not follow a power law with a single exponent. Instead, it was found that the power law varied with density, indicating a cross-over between dominant scattering mechanisms at low density and high density. At low density the mobility was found to be limited by remote ionized impurity scattering, while at high density the dominant scattering mechanism was found to be background impurity scattering. Chapter 5 details an experiment examining transport in a series of two-dimensional hole gases in which the dopant setback distance and the Al mole fraction in the barriers of the quantum well were varied. The hole density was tuned in this way from 0.18 -- 1.9 x 1011 cm-2. Surprisingly, the mobility at T = 0.3 K was found to peak at 2.3 x 10 6 cm-2 at an intermediate density of 6.5 x 10 10 cm-2. Self-consistent Schrodinger/Poisson calculations were performed for each wafer to examine the scattering rates due to a variety of potentials at low temperature. The drop in mobility at high density could be accounted for with the inclusion of interface roughness scattering, but using the same interface roughness scattering parameters for similar two-dimensional electron gases produced inconsistent results. This leaves open the possibility of contributions from other scattering mechanisms in the hole samples at high density. Chapter 6 presents an in-depth study of in-situ backgated two-dimensional gases used for studying the fragile fractional quantum Hall states in the 2nd Landau level. It was found that leakage currents as small as 4 pA could cause noticeable heating of the electron gas if the lattice was not properly thermally anchored to the cryostat. However, it was also found that when the heterostructure design and device fabrication recipe were properly optimized, gate voltages as large as 4 V could be applied before the leakage turned on, allowing the density to be tuned from full depletion to over 4 x 1011 cm-2. As a result, heating effects at dilution refrigerator temperatures were negligible and the gap at nu = 5/2 could be tuned continuously with density to a maximum value of 625 mK, the largest reported to date. An unusual evolution of the reentrant integer quantum Hall states as a function of density is also reported. Such devices should prove useful for the study of electron correlations in nanostructures in the 2nd Landau level.

Efficient ionisation of calcium, strontium and barium by resonant laser pumping

NASA Technical Reports Server (NTRS)

Skinner, C. H.

1980-01-01

Efficient ionization has been observed when an atomic vapor of strontium, barium or calcium was illuminated with a long pulse tunable laser at the frequency of the atomic resonance line. The variation in the degree of ionization with neutral density and laser intensity has been measured using the 'hook' method. The maximum ionization observed was 94%. Excited state populations were measured yielding an excitation temperature (depending on exact experimental conditions) in the region of 0.4 eV. The decay of ion density after the laser pulse was monitored and the recombination coefficients determined. The results are interpreted in terms of an electron heating model.

GaN MOSFET with Boron Trichloride-Based Dry Recess Process

NASA Astrophysics Data System (ADS)

Jiang, Y.; Wang, Q. P.; Tamai, K.; Miyashita, T.; Motoyama, S.; Wang, D. J.; Ao, J. P.; Ohno, Y.

2013-06-01

The dry recessed-gate GaN metal-oxide-semiconductor field-effect transistors (MOSFETs) on AlGaN/GaN heterostructure using boron trichloride (BCl3) as etching gas were fabricated and characterized. Etching with different etching power was conducted. Devices with silicon tetrachloride (SiCl4) etching gas were also prepared for comparison. Field-effect mobility and interface state density were extracted from current-voltage (I-V) characteristics. GaN MOSFETs on AlGaN/GaN heterostructure with BCl3 based dry recess achieved a high maximum electron mobility of 141.5 cm2V-1s-1 and a low interface state density.

Application of a dummy eye shield for electron treatment planning

PubMed Central

Kang, Sei-Kwon; Park, Soah; Hwang, Taejin; Cheong, Kwang-Ho; Han, Taejin; Kim, Haeyoung; Lee, Me-Yeon; Kim, Kyoung Ju; Oh, Do Hoon; Bae, Hoonsik

2013-01-01

Metallic eye shields have been widely used for near-eye treatments to protect critical regions, but have never been incorporated into treatment plans because of the unwanted appearance of the metal artifacts on CT images. The purpose of this work was to test the use of an acrylic dummy eye shield as a substitute for a metallic eye shield during CT scans. An acrylic dummy shield of the same size as the tungsten eye shield was machined and CT scanned. The BEAMnrc and the DOSXYZnrc were used for the Monte Carlo (MC) simulation, with the appropriate material information and density for the aluminum cover, steel knob and tungsten body of the eye shield. The Pinnacle adopting the Hogstrom electron pencil-beam algorithm was used for the one-port 6-MeV beam plan after delineation and density override of the metallic parts. The results were confirmed with the metal oxide semiconductor field effect transistor (MOSFET) detectors and the Gafchromic EBT2 film measurements. For both the maximum eyelid dose over the shield and the maximum dose under the shield, the MC results agreed with the EBT2 measurements within 1.7%. For the Pinnacle plan, the maximum dose under the shield agreed with the MC within 0.3%; however, the eyelid dose differed by –19.3%. The adoption of the acrylic dummy eye shield was successful for the treatment plan. However, the Pinnacle pencil-beam algorithm was not sufficient to predict the eyelid dose on the tungsten shield, and more accurate algorithms like MC should be considered for a treatment plan. PMID:22915776

High time resolution measurements of rocket potential changes induced by electron beam emission

NASA Technical Reports Server (NTRS)

Raitt, W. J.; Myers, N. B.; Williamson, P. R.; Banks, P. M.; Kawashima, N.

1984-01-01

The transient charging and photon emission from the vacuum chamber testing of the Cooperative High Altitude Rocket Gun Experiment are studied. Graphs of the mother-daughter voltage versus time and high time resolution data related to the return current to the vehicle are examined. It is observed that for average sounding rocket densities of 10 to the -6th torr the slope of the voltage rise of the rocket begins to flatten 40 microsec after the onset of electron beam emission, and for higher gas pressure the rocket reaches a maximum voltage of 25 or 30 microsec after the onset of electron beam emission. The data reveal that the return current mechanism for the higher gas pressure is through the sheath.

Stability of Nonstationary Cooling of Pure Hydrogen Gas with Respect to the Number of Discrete Levels Taken into Account

NASA Astrophysics Data System (ADS)

Belova, O. M.; Bychkov, K. V.

2018-03-01

The effect of the number K of atomic hydrogen levels taken into account on the cooling of the gas behind a shock front is studied. The calculations are done for the conditions in the atmospheres of long-period Mira Ceti type variables. K ranges from 2 to 25. The electron temperature Te(t; K) and ionization state x(r,K) asymptotically approach limiting functions Te(t) and x(t) that are independent of K. After the maximum electron temperature is reached, a partial equilibrium phase sets in, during which the populations of the highly excited discrete levels with principal quantum numbers ≥ 8 obey the Saha equation for the instantaneous electron temperature and density.

19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact

PubMed Central

2015-01-01

We demonstrate an InP heterojunction solar cell employing an ultrathin layer (∼10 nm) of amorphous TiO2 deposited at 120 °C by atomic layer deposition as the transparent electron-selective contact. The TiO2 film selectively extracts minority electrons from the conduction band of p-type InP while blocking the majority holes due to the large valence band offset, enabling a high maximum open-circuit voltage of 785 mV. A hydrogen plasma treatment of the InP surface drastically improves the long-wavelength response of the device, resulting in a high short-circuit current density of 30.5 mA/cm2 and a high power conversion efficiency of 19.2%. PMID:25679010

19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO2 Contact.

PubMed

Yin, Xingtian; Battaglia, Corsin; Lin, Yongjing; Chen, Kevin; Hettick, Mark; Zheng, Maxwell; Chen, Cheng-Ying; Kiriya, Daisuke; Javey, Ali

2014-12-17

We demonstrate an InP heterojunction solar cell employing an ultrathin layer (∼10 nm) of amorphous TiO 2 deposited at 120 °C by atomic layer deposition as the transparent electron-selective contact. The TiO 2 film selectively extracts minority electrons from the conduction band of p-type InP while blocking the majority holes due to the large valence band offset, enabling a high maximum open-circuit voltage of 785 mV. A hydrogen plasma treatment of the InP surface drastically improves the long-wavelength response of the device, resulting in a high short-circuit current density of 30.5 mA/cm 2 and a high power conversion efficiency of 19.2%.

Ultrahigh density alignment of carbon nanotube arrays by dielectrophoresis.

PubMed

Shekhar, Shashank; Stokes, Paul; Khondaker, Saiful I

2011-03-22

We report ultrahigh density assembly of aligned single-walled carbon nanotube (SWNT) two-dimensional arrays via AC dielectrophoresis using high-quality surfactant-free and stable SWNT solutions. After optimization of frequency and trapping time, we can reproducibly control the linear density of the SWNT between prefabricated electrodes from 0.5 SWNT/μm to more than 30 SWNT/μm by tuning the concentration of the nanotubes in the solution. Our maximum density of 30 SWNT/μm is the highest for aligned arrays via any solution processing technique reported so far. Further increase of SWNT concentration results in a dense array with multiple layers. We discuss how the orientation and density of the nanotubes vary with concentrations and channel lengths. Electrical measurement data show that the densely packed aligned arrays have low sheet resistances. Selective removal of metallic SWNTs via controlled electrical breakdown produced field-effect transistors with high current on-off ratio. Ultrahigh density alignment reported here will have important implications in fabricating high-quality devices for digital and analog electronics.

Statistical results from 10 years of Cassini Langmuir probe plasma measurements

NASA Astrophysics Data System (ADS)

Holmberg, M.; Shebanits, O.; Wahlund, J. E.; Morooka, M.; Andre, N.

2016-12-01

We use a new analysis method to obtain 10 years of Cassini RPWS Langmuir probe (LP) measurements to study the structure and dynamics of the inner plasma disk of Saturn. The LP plasma density measurements show good agreement with electron densities derived from the RPWS electric field power spectra and confirms and/or improves a number of previous findings about the structure of the plasma disk. E.g., the Enceladus plume is detected as a localised density maximum at the orbit of Enceladus, but the peak density of the inner plasma disk, excluding Enceladus plume passages, is located closer to 4.7 Rs. No density peaks are recorded at the orbits of the moons Mimas, Tethys, Dione, and Rhea. We confirm the previously detected plasma density dayside/nightside asymmetry, which is likely due to a particle drift in the dusk to dawn direction. Presented is also the LP result on the seasonal dependence of the plasma disk within Enceladus' orbit.

On the maximum energy of non-thermal particles in the primary hotspot of Cygnus A

NASA Astrophysics Data System (ADS)

Araudo, Anabella T.; Bell, Anthony R.; Blundell, Katherine M.; Matthews, James H.

2018-01-01

We study particle acceleration and magnetic field amplification in the primary hotspot in the north-west jet of radiogalaxy Cygnus A. By using the observed flux density at 43 GHz in a well-resolved region of this hotspot, we determine the minimum value of the jet density and constrain the magnitude of the magnetic field. We find that a jet with density greater than 5 × 10-5 cm-3 and hotspot magnetic field in the range 50-400 μG are required to explain the synchrotron emission at 43 GHz. The upper-energy cut-off in the hotspot synchrotron spectrum is at a frequency ≲5 × 1014 Hz, indicating that the maximum energy of non-thermal electrons accelerated at the jet reverse shock is Ee, max ∼ 0.8 TeV in a magnetic field of 100 μG. Based on the condition that the magnetic-turbulence scalelength has to be larger than the plasma skin depth, and that the energy density in non-thermal particles cannot violate the limit imposed by the jet kinetic luminosity, we show that Ee, max cannot be constrained by synchrotron losses as traditionally assumed. In addition to that, and assuming that the shock is quasi-perpendicular, we show that non-resonant hybrid instabilities generated by the streaming of cosmic rays with energy Ee, max can grow fast enough to amplify the jet magnetic field up to 50-400 μG and accelerate particles up to the maximum energy Ee, max observed in the Cygnus A primary hotspot.

A membraneless biofuel cell powered by ethanol and alcoholic beverage.

PubMed

Deng, Liu; Shang, Li; Wen, Dan; Zhai, Junfeng; Dong, Shaojun

2010-09-15

In this study, we reported on the construction of a stable single-chamber ethanol/O(2) biofuel cell harvesting energy from the ethanol and alcoholic beverage. We prepared a composite film which consisted of partially sulfonated (3-mercaptopropyl)-trimethoxysilane sol-gel (PSSG) and chitosan (CHI). The combination of ion-exchange capacity sol-gel and biopolymer chitosan not only provided the attached sites for mediator MDB and AuNPs to facilitate the electron transfer along the substrate reaction, but also gave the suitable microenvironment to retain the enzyme activity in long term. The ethanol bioanode was constructed with the film coimmobilized dehydrogenase (ADH), Meldola's blue (MDB) and gold nanoparticles (AuNPs). The MDB/AuNPs/PSSG-CHI-ADH composite modified electrode showed prominent electrocatalytic activity towards the oxidation of ethanol. The oxygen biocathode consisted of laccase and AuNPs immobilized on the PSSG-CHI composite membrane. The AuNPs/PSSG-CHI-laccase modified electrode catalyzed four-electron reduction of O(2) to water, without any mediator. The assembled single-chamber biofuel cell exhibited good stability and power output towards ethanol. The open-circuit voltage of this biofuel cell was 860 mV. The maximum power density of the biofuel cell was 1.56 mWcm(-2) at 550 mV. Most interestingly, this biofuel cell showed the similar performance when the alcoholic beverage acted as the fuel. When this biofuel cell ran with wine as the fuel, the maximum power output density was 3.21 mAcm(-2) and the maximum power density was 1.78 mWcm(-2) at 680 mV of the cell voltage. Our system exhibited stable and high power output in the multi-component substrate condition. This cell has great potential for the development and practical application of bioethanol fuel cell. Copyright 2010 Elsevier B.V. All rights reserved.

Electronic structures and enhanced optical properties of blue phosphorene/transition metal dichalcogenides van der Waals heterostructures.

PubMed

Peng, Qiong; Wang, Zhenyu; Sa, Baisheng; Wu, Bo; Sun, Zhimei

2016-08-24

As a fast emerging topic, van der Waals (vdW) heterostructures have been proposed to modify two-dimensional layered materials with desired properties, thus greatly extending the applications of these materials. In this work, the stacking characteristics, electronic structures, band edge alignments, charge density distributions and optical properties of blue phosphorene/transition metal dichalcogenides (BlueP/TMDs) vdW heterostructures were systematically studied based on vdW corrected density functional theory. Interestingly, the valence band maximum and conduction band minimum are located in different parts of BlueP/MoSe2, BlueP/WS2 and BlueP/WSe2 heterostructures. The MoSe2, WS2 or WSe2 layer can be used as the electron donor and the BlueP layer can be used as the electron acceptor. We further found that the optical properties under visible-light irradiation of BlueP/TMDs vdW heterostructures are significantly improved. In particular, the predicted upper limit energy conversion efficiencies of BlueP/MoS2 and BlueP/MoSe2 heterostructures reach as large as 1.16% and 0.98%, respectively, suggesting their potential applications in efficient thin-film solar cells and optoelectronic devices.

Development of a large-area planar surface-wave plasma source with a cavity launcher driven by a 915 MHz UHF wave

NASA Astrophysics Data System (ADS)

Chang, Xijiang; Kunii, Kazuki; Liang, Rongqing; Nagatsu, Masaaki

2013-04-01

A large-area planar surface-wave plasma (SWP) source driven by a 915 MHz ultrahigh frequency (UHF) wave was developed. To avoid using large, thick dielectric plates as vacuum windows, we propose a cavity launcher consisting of a cylindrical cavity with several small quartz discs at the bottom. Three types of launchers with quartz discs located at different positions were tested to compare their plasma production efficiencies and spatial distributions of electron density. With the optimum launcher, large-area plasma discharges with a radial uniformity within ±10% were obtained in a radius of about 25-30 cm in Ar gas at 8 Pa for incident power in the range 0.5-2.5 kW. The maximum electron density and temperature were approximately (0.95-1.1) × 1011 cm-3 and 1.9-2.0 eV, respectively, as measured by a Langmuir probe located 24 cm below the bottom of the cavity launcher. Using an Ar/NH3 SWP with the optimum launcher, we demonstrated large-area amino-group surface modification of polyurethane sheets. Experimental results indicated that a uniform amino-group modification was achieved over a radius of approximately 40 cm, which is slightly larger than the radial uniformity of the electron density distribution.

Wet model of Saturn's ionosphere: Water from the rings

NASA Technical Reports Server (NTRS)

Connerney, J. E. P.; Waite, J. H.

1984-01-01

Current theoretical models of Saturn's ionosphere are difficult to reconcile with the ionospheric electron density profiles obtained from the Pioneer and Voyager radio occultation observations and the large diurnal variation of maximum ionospheric electron density deduced from studies of Saturn lightning discharges. A model of Saturn's ionosphere is proposed in which water plays a major role as a minor constituent present by virtue of downward diffusion from an external source. This model of the Saturn ionosphere is a classical 'F2' type layer resulting from the photodissociative production of H(+) from H2 and rapid chemical loss due to a series of charge exchange reactions with water. A planet-wide influx of about 4x10 to the 7th power molecules/sec/sq cm of water from the rings is consistent with the observed ionospheric electron densities and estimates of influx due to micrometeoride bombardment of the rings. An enhanced influx of water occurs at latitudes (-38 deg, +44 deg) magnetically connected to the inner edge of Saturn's B ring which results from an electromagnetic erosion process contributing substantially to the (local) upper atmosphere water content. Present day influx at these latitudes is possibly as large as 2x10 to the 9th power molecules/sec/sq cm.

Dielectric function and plasmons in graphene: A self-consistent-field calculation within a Markovian master equation formalism

DOE PAGES

Karimi, F.; Davoody, A. H.; Knezevic, I.

2016-05-12

We introduce a method for calculating the dielectric function of nanostructures with an arbitrary band dispersion and Bloch wave functions. The linear response of a dissipative electronic system to an external electromagnetic field is calculated by a self-consistent-field approach within a Markovian master equation formalism (SCF-MMEF) coupled with full-wave electromagnetic equations. The SCF-MMEF accurately accounts for several concurrent scattering mechanisms. The method captures interband electron-hole-pair generation, as well as the interband and intraband electron scattering with phonons and impurities. We employ the SCF-MMEF to calculate the dielectric function, complex conductivity, and loss function for supported graphene. From the loss-function maximum,more » we obtain plasmon dispersion and propagation length for different substrate types [nonpolar diamondlike carbon (DLC) and polar SiO 2 and hBN], impurity densities, carrier densities, and temperatures. Plasmons on the two polar substrates are suppressed below the highest surface phonon energy, while the spectrum is broad on the nonpolar DLC. Plasmon propagation lengths are comparable on polar and nonpolar substrates and are on the order of tens of nanometers, considerably shorter than previously reported. As a result, they improve with fewer impurities, at lower temperatures, and at higher carrier densities.« less

GNSS-ISR data fusion: General framework with application to the high-latitude ionosphere

NASA Astrophysics Data System (ADS)

Semeter, Joshua; Hirsch, Michael; Lind, Frank; Coster, Anthea; Erickson, Philip; Pankratius, Victor

2016-03-01

A mathematical framework is presented for the fusion of electron density measured by incoherent scatter radar (ISR) and total electron content (TEC) measured using global navigation satellite systems (GNSS). Both measurements are treated as projections of an unknown density field (for GNSS-TEC the projection is tomographic; for ISR the projection is a weighted average over a local spatial region) and discrete inverse theory is applied to obtain a higher fidelity representation of the field than could be obtained from either modality individually. The specific implementation explored herein uses the interpolated ISR density field as initial guess to the combined inverse problem, which is subsequently solved using maximum entropy regularization. Simulations involving a dense meridional network of GNSS receivers near the Poker Flat ISR demonstrate the potential of this approach to resolve sub-beam structure in ISR measurements. Several future directions are outlined, including (1) data fusion using lower level (lag product) ISR data, (2) consideration of the different temporal sampling rates, (3) application of physics-based regularization, (4) consideration of nonoptimal observing geometries, and (5) use of an ISR simulation framework for optimal experiment design.

Surface modified CF x cathode material for ultrafast discharge and high energy density

DOE PAGES

Dai, Yang; Zhu, Yimei; Cai, Sendan; ...

2014-11-10

Li/CF x primary possesses the highest energy density of 2180 W h kg⁻¹ among all primary lithium batteries. However, a key limitation for the utility of this type of battery is in its poor rate capability because the cathode material, CF x, is an intrinsically poor electronic conductor. Here, we report on our development of a controlled process of surface de-fluorination under mild hydrothermal conditions to modify the highly fluorinated CF x. The modified CF x, consisting of an in situ generated shell component of F-graphene layers, possesses good electronic conductivity and removes the transporting barrier for lithium ions, yieldingmore » a high-capacity performance and an excellent rate-capability. Indeed, a capacity of 500 mA h g⁻¹ and a maximum power density of 44 800 W kg⁻¹ can be realized at the ultrafast rate of 30 C (24 A g⁻¹), which is over one order of magnitude higher than that of the state-of-the-art primary lithium-ion batteries.« less

On the probability distribution function of the mass surface density of molecular clouds. I

NASA Astrophysics Data System (ADS)

Fischera, Jörg

2014-05-01

The probability distribution function (PDF) of the mass surface density is an essential characteristic of the structure of molecular clouds or the interstellar medium in general. Observations of the PDF of molecular clouds indicate a composition of a broad distribution around the maximum and a decreasing tail at high mass surface densities. The first component is attributed to the random distribution of gas which is modeled using a log-normal function while the second component is attributed to condensed structures modeled using a simple power-law. The aim of this paper is to provide an analytical model of the PDF of condensed structures which can be used by observers to extract information about the condensations. The condensed structures are considered to be either spheres or cylinders with a truncated radial density profile at cloud radius rcl. The assumed profile is of the form ρ(r) = ρc/ (1 + (r/r0)2)n/ 2 for arbitrary power n where ρc and r0 are the central density and the inner radius, respectively. An implicit function is obtained which either truncates (sphere) or has a pole (cylinder) at maximal mass surface density. The PDF of spherical condensations and the asymptotic PDF of cylinders in the limit of infinite overdensity ρc/ρ(rcl) flattens for steeper density profiles and has a power law asymptote at low and high mass surface densities and a well defined maximum. The power index of the asymptote Σ- γ of the logarithmic PDF (ΣP(Σ)) in the limit of high mass surface densities is given by γ = (n + 1)/(n - 1) - 1 (spheres) or by γ = n/ (n - 1) - 1 (cylinders in the limit of infinite overdensity). Appendices are available in electronic form at http://www.aanda.org

A study on the electron transport properties of ZnON semiconductors with respect to the relative anion content

PubMed Central

Park, Jozeph; Kim, Yang Soo; Ok, Kyung-Chul; Park, Yun Chang; Kim, Hyun You; Park, Jin-Seong; Kim, Hyun-Suk

2016-01-01

High-mobility zinc oxynitride (ZnON) semiconductors were grown by RF sputtering using a Zn metal target in a plasma mixture of Ar, N2, and O2 gas. The RF power and the O2 to N2 gas flow rates were systematically adjusted to prepare a set of ZnON films with different relative anion contents. The carrier density was found to be greatly affected by the anion composition, while the electron mobility is determined by a fairly complex mechanism. First-principles calculations indicate that excess vacant nitrogen sites (VN) in N-rich ZnON disrupt the local electron conduction paths, which may be restored by having oxygen anions inserted therein. The latter are anticipated to enhance the electron mobility, and the exact process parameters that induce such a phenomenon can only be found experimentally. Contour plots of the Hall mobility and carrier density with respect to the RF power and O2 to N2 gas flow rate ratio indicate the existence of an optimum region where maximum electron mobility is obtained. Using ZnON films grown under the optimum conditions, the fabrication of high-performance devices with field-effect mobility values exceeding 120 cm2/Vs is demonstrated based on simple reactive RF sputtering methods. PMID:27098656

Nonlinear propagation of ion-acoustic waves in electron-positron-ion plasma with trapped electrons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alinejad, H.; Sobhanian, S.; Mahmoodi, J.

2006-01-15

A theoretical investigation has been made for ion-acoustic waves in an unmagnetized electron-positron-ion plasma. A more realistic situation in which plasma consists of a negatively charged ion fluid, free positrons, and trapped as well as free electrons is considered. The properties of stationary structures are studied by the reductive perturbation method, which is valid for small but finite amplitude limit, and by pseudopotential approach, which is valid for large amplitude. With an appropriate modified form of the electron number density, two new equations for the ion dynamics have been found. When deviations from isothermality are finite, the modified Korteweg-deVries equationmore » has been found, and for the case that deviations from isothermality are small, calculations lead to a generalized Korteweg-deVries equation. It is shown from both weakly and highly nonlinear analysis that the presence of the positrons may allow solitary waves to exist. It is found that the effect of the positron density changes the maximum value of the amplitude and M (Mach number) for which solitary waves can exist. The present theory is applicable to analyze arbitrary amplitude ion-acoustic waves associated with positrons which may occur in space plasma.« less

Plasma density behavior with new graphite limiters in the Hefei Tokamak-7

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asif, M.; Gao, X.; Li, J.

A new set of actively cooled toroidal double-ring graphite limiters has been developed in the Hefei Tokamak-7 (HT-7) [X. Gao et al., Phys. Plasmas 7, 2933 (2000)] for long pulse operation. The extension of operational region and density behavior with graphite (C) limiters have been studied in this paper. Extended high-density region at the high plasma current low-q{sub a} was obtained. The density profile with the C limiter was studied to compare with the previous molybdenum (Mo) limiter. The critical density of multifaceted asymmetric radiation from the edge (MARFE) onset is observed in the region of Z{sub eff}{sup 1/2}f{sub GW}=0.9{approx}1.2,more » where f{sub GW}=n{sub e}/n{sub GW}. (Here n{sub e} is the maximum line average electron density and n{sub GW} is the Greenwald density.) Under the same injected power, the critical density of MARFE onset with the new C limiter is much higher than the previous Mo limiter.« less

Transition metal sulfides grown on graphene fibers for wearable asymmetric supercapacitors with high volumetric capacitance and high energy density

NASA Astrophysics Data System (ADS)

Cai, Weihua; Lai, Ting; Lai, Jianwei; Xie, Haoting; Ouyang, Liuzhang; Ye, Jianshan; Yu, Chengzhong

2016-06-01

Fiber shaped supercapacitors are promising candidates for wearable electronics because they are flexible and light-weight. However, a critical challenge of the widespread application of these energy storage devices is their low cell voltages and low energy densities, resulting in limited run-time of the electronics. Here, we demonstrate a 1.5 V high cell voltage and high volumetric energy density asymmetric fiber supercapacitor in aqueous electrolyte. The lightweight (0.24 g cm-3), highly conductive (39 S cm-1), and mechanically robust (221 MPa) graphene fibers were firstly fabricated and then coated by NiCo2S4 nanoparticles (GF/NiCo2S4) via the solvothermal deposition method. The GF/NiCo2S4 display high volumetric capacitance up to 388 F cm-3 at 2 mV s-1 in a three-electrode cell and 300 F cm-3 at 175.7 mA cm-3 (568 mF cm-2 at 0.5 mA cm-2) in a two-electrode cell. The electrochemical characterizations show 1000% higher capacitance of the GF/NiCo2S4 as compared to that of neat graphene fibers. The fabricated device achieves high energy density up to 12.3 mWh cm-3 with a maximum power density of 1600 mW cm-3, outperforming the thin-film lithium battery. Therefore, these supercapacitors are promising for the next generation flexible and wearable electronic devices.

Transition metal sulfides grown on graphene fibers for wearable asymmetric supercapacitors with high volumetric capacitance and high energy density

PubMed Central

Cai, Weihua; Lai, Ting; Lai, Jianwei; Xie, Haoting; Ouyang, Liuzhang; Ye, Jianshan; Yu, Chengzhong

2016-01-01

Fiber shaped supercapacitors are promising candidates for wearable electronics because they are flexible and light-weight. However, a critical challenge of the widespread application of these energy storage devices is their low cell voltages and low energy densities, resulting in limited run-time of the electronics. Here, we demonstrate a 1.5 V high cell voltage and high volumetric energy density asymmetric fiber supercapacitor in aqueous electrolyte. The lightweight (0.24 g cm−3), highly conductive (39 S cm−1), and mechanically robust (221 MPa) graphene fibers were firstly fabricated and then coated by NiCo2S4 nanoparticles (GF/NiCo2S4) via the solvothermal deposition method. The GF/NiCo2S4 display high volumetric capacitance up to 388 F cm−3 at 2 mV s−1 in a three-electrode cell and 300 F cm−3 at 175.7 mA cm−3 (568 mF cm−2 at 0.5 mA cm−2) in a two-electrode cell. The electrochemical characterizations show 1000% higher capacitance of the GF/NiCo2S4 as compared to that of neat graphene fibers. The fabricated device achieves high energy density up to 12.3 mWh cm−3 with a maximum power density of 1600 mW cm−3, outperforming the thin-film lithium battery. Therefore, these supercapacitors are promising for the next generation flexible and wearable electronic devices. PMID:27248510

A comprehensive device modelling of perovskite solar cell with inorganic copper iodide as hole transport material

NASA Astrophysics Data System (ADS)

Zulqarnain Haider, Syed; Anwar, Hafeez; Wang, Mingqing

2018-03-01

Hole transport material (HTM) plays an important role in the efficiency and stability of perovskite solar cells (PSCs). Spiro-MeOTAD, the commonly used HTM, is costly and can be easily degraded by heat and moisture, thus offering hindrance to commercialize PSCs. There is dire need to find an alternate inorganic and stable HTM to exploit PSCs with their maximum capability. In this paper, a comprehensive device simulation is used to study various possible parameters that can influence the performance of perovskite solar cell with CuI as HTM. These include the effect of doping density, defect density and thickness of absorber layer, along with the influence of diffusion length of carriers as well as electron affinity of electron transport layer (ETM) and HTM on the performance of PSCs. In addition, hole mobility and doping density of HTM is also investigated. CuI is a p-type inorganic material with low cost and relatively high stability. It is found that concentration of dopant in absorber layer and HTM, the electron affinity of HTM and ETM affect the performance of solar cell minutely, while cell performance improves greatly with the reduction of defect density. Upon optimization of parameters, power conversion efficiency for this device is found to be 21.32%. The result shows that lead-based PSC with CuI as HTM is an efficient system. Enhancing the stability and reduction of defect density are critical factors for future research. These factors can be improved by better fabrication process and proper encapsulation of solar cell.

Microscopic Description of the Ferroism in Lead-Free AlFeO3.

PubMed

Santos, Guilherme M; Catellani, Igor B; Santos, Ivair A; Guo, Ruyan; Bhalla, Amar S; Padilha, José Eduardo; Cótica, Luiz F

2018-04-23

The microscopic origin of the ferroic and multiferroic properties of AlFeO 3 have been carefully investigated. The maximum entropy method was applied to X-ray diffraction data and ab initio density functional theory calculations in order to obtain the electron density distributions and electric polarization. The study of chemical bonds shows that the bonds between Fe(3d) and O(2p) ions are anisotropic, leading to the configuration of shorter/longer and stronger/weaker bonds. This leads to electric polarization. Density of states calculations showed a magnetic polarization as a result of a weak ferromagnetic ordering. These results unambiguously show that AlFeO 3 is a multiferroic material and exhibits a magnetoelectric coupling at room temperature, as has already been shown by experiments.

MEANS FOR CONTROLLING A NUCLEAR REACTOR

DOEpatents

Wilson, V.C.; Overbeck, W.P.; Slotin, L.; Froman, D.K.

1957-12-17

This patent relates to nuclear reactors of the type using a solid neutron absorbing material as a means for controlling the reproduction ratio of the system and thereby the power output. Elongated rods of neutron absorbing material, such as boron steel for example, are adapted to be inserted and removed from the core of tae reactor by electronic motors and suitable drive means. The motors and drive means are controlled by means responsive to the neutron density, such as ionization chambers. The control system is designed to be responsive also to the rate of change in neutron density to automatically maintain the total power output at a substantially constant predetermined value. A safety rod means responsive to neutron density is also provided for keeping the power output below a predetermined maximum value at all times.

Ionospheric modification with a VLF transmitter

NASA Technical Reports Server (NTRS)

Inan, Umran S.; Rodriguez, Juan V.; Lev-Tov, S.; Oh, J.

1992-01-01

Detectable heating of the nightime D region by a 28.5 kHz signal is observed in 16 out of 144 cases with events occurring under conditions of moderate to low D region electron densities as represented by the unperturbed VLF signal levels. Three dimensional modeling of the effects of NAU heating on a probe VLF signal predicts values in general agreement with observations and suggests that maximum effects should occur under tenuous D region conditions.

Bonding nature and electron delocalization of An(COT)2, An = Th, Pa, U.

PubMed

Páez-Hernández, Dayán; Murillo-López, Juliana A; Arratia-Pérez, Ramiro

2011-08-18

A systematic study of a series of An(COT)(2) compounds, where An = Th, Pa, U, and COT represents cyclooctatetraene, has been performed using relativistic density functional theory. The ZORA Hamiltonian was applied for the inclusion of relativistic effects, taking into account all of the electrons for the optimization and explicitly including spin-orbit coupling effects. Time-dependent density functional theory (TDDFT) was used to calculate the excitation energies with the GGA SAOP functional, and the electronic transitions were analyzed using double group irreducible representations. The calculated excitation energies are in perfect correlation with the increment of the ring delocalization as it increases along the actinide series. These results are sufficient to ensure that, for these complexes, the increment in delocalization, as indicated by ELF bifurcation and NICS analysis, leads to a shift in the maximum wavelength of absorption in the visible region. Also, delocalization in the COT ring increases along the actinide series, so the systems become more aromatic because of a modulation induced by the actinides. © 2011 American Chemical Society

Electronic structure and thermoelectric properties of half-Heusler compounds with eight electron valence count—KScX (X = C and Ge)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ciftci, Yasemin O.; Mahanti, Subhendra D.

Electronic band structure and structural properties of two representative half-Heusler (HH) compounds with 8 electron valence count (VC), KScC and KScGe, have been studied using first principles methods within density functional theory and generalized gradient approximation. These systems differ from the well studied class of HH compounds like ZrNiSn and ZrCoSb which have VC = 18 because of the absence of d electrons of the transition metal atoms Ni and Co. Electronic transport properties such as Seebeck coefficient (S), electrical conductivity (σ), electronic thermal conductivity (κ{sub e}) (the latter two scaled by electronic relaxation time), and the power factor (S{sup 2}σ) havemore » been calculated using semi-classical Boltzmann transport theory within constant relaxation time approximation. Both the compounds are direct band gap semiconductors with band extrema at the X point. Their electronic structures show a mixture of heavy and light bands near the valance band maximum and highly anisotropic conduction and valence bands near the band extrema, desirable features of good thermoelectric. Optimal p- or n-type doping concentrations have been estimated based on thermopower and maximum power factors. The optimum room temperature values of S are ∼1.5 times larger than that of the best room temperature thermoelectric Bi{sub 2}Te{sub 3}. We also discuss the impact of the band structure on deviations from Weidemann-Franz law as one tunes the chemical potential across the band gap.« less

The effects of magnetospheric processes on relativistic electron dynamics in the Earth's outer radiation belt

DOE PAGES

Tang, C. L.; Wang, Y. X.; Ni, B.; ...

2017-08-11

Using the electron phase space density (PSD) data measured by Van Allen Probe A from January 2013 to April 2015, we investigate the effects of magnetospheric processes on relativistic electron dynamics in the Earth's outer radiation belt during 50 geomagnetic storms. A statistical study shows that the maximum electron PSDs for various μ (μ = 630, 1096, 2290, and 3311 MeV/G) at L*~4.0 after the storm peak have good correlations with storm intensity (cc~0.70). This suggests that the occurrence and magnitude of geomagnetic storms are necessary for relativistic electron enhancements at the inner edge of the outer radiation belt (L*more » = 4.0). For moderate or weak storm events (SYM–H min > ~–100 nT) with weak substorm activity (AE max < 800 nT) and strong storm events (SYM–H min ≤ ~–100 nT) with intense substorms (AE max ≥ 800 nT) during the recovery phase, the maximum electron PSDs for various μ at different L* values (L* = 4.0, 4.5, and 5.0) are well correlated with storm intensity (cc > 0.77). For storm events with intense substorms after the storm peak, relativistic electron enhancements at L* = 4.5 and 5.0 are observed. This shows that intense substorms during the storm recovery phase are crucial to relativistic electron enhancements in the heart of the outer radiation belt. In conclusion, our statistics study suggests that magnetospheric processes during geomagnetic storms have a significant effect on relativistic electron dynamics.« less

The effects of magnetospheric processes on relativistic electron dynamics in the Earth's outer radiation belt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tang, C. L.; Wang, Y. X.; Ni, B.

Using the electron phase space density (PSD) data measured by Van Allen Probe A from January 2013 to April 2015, we investigate the effects of magnetospheric processes on relativistic electron dynamics in the Earth's outer radiation belt during 50 geomagnetic storms. A statistical study shows that the maximum electron PSDs for various μ (μ = 630, 1096, 2290, and 3311 MeV/G) at L*~4.0 after the storm peak have good correlations with storm intensity (cc~0.70). This suggests that the occurrence and magnitude of geomagnetic storms are necessary for relativistic electron enhancements at the inner edge of the outer radiation belt (L*more » = 4.0). For moderate or weak storm events (SYM–H min > ~–100 nT) with weak substorm activity (AE max < 800 nT) and strong storm events (SYM–H min ≤ ~–100 nT) with intense substorms (AE max ≥ 800 nT) during the recovery phase, the maximum electron PSDs for various μ at different L* values (L* = 4.0, 4.5, and 5.0) are well correlated with storm intensity (cc > 0.77). For storm events with intense substorms after the storm peak, relativistic electron enhancements at L* = 4.5 and 5.0 are observed. This shows that intense substorms during the storm recovery phase are crucial to relativistic electron enhancements in the heart of the outer radiation belt. In conclusion, our statistics study suggests that magnetospheric processes during geomagnetic storms have a significant effect on relativistic electron dynamics.« less

Biological treatment of steroidal drug industrial effluent and electricity generation in the microbial fuel cells.

PubMed

Liu, Ru; Gao, Chongyang; Zhao, Yang-Guo; Wang, Aijie; Lu, Shanshan; Wang, Min; Maqbool, Farhana; Huang, Qing

2012-11-01

The single chamber microbial fuel cells (MFCs) were used to treat steroidal drug production wastewater (SPW) and generate electricity simultaneously. The results indicated that the maximum COD removal efficiency reached 82%, total nitrogen and sulfate removal rate approached 62.47% and 26.46%, respectively. The maximum power density and the Coulombic efficiency reached to 22.3Wm(-3) and 30%, respectively. The scanning electron microscope showed that the dominant microbial populations were remarkably different in morphology on the surface of SPW and acetate-fed anodes. PCR-denaturing gradient gel electrophoresis profiles revealed that the microbial community structure fed with different concentrations of SPW presented a gradual succession and unique bacterial sequences were detected on the SPW and acetate-fed anodes. This research demonstrates that MFCs fed with SPW achieved a high efficiency of power density and simultaneous nutrient removal, and the dominant microorganisms on the anode were related to the types and the concentrations of substrates. Copyright © 2012 Elsevier Ltd. All rights reserved.

Asymmetric supercapacitors with high energy density based on helical hierarchical porous NaxMnO2 and MoO2 † †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc03326h Click here for additional data file.

PubMed Central

Lu, Xue-Feng; Huang, Zhi-Xiang; Tong, Ye-Xiang

2016-01-01

Helical hierarchical porous NaxMnO2/CC and MoO2/CC, which are assembled from nanosheets and nanoparticles, respectively, are fabricated using a simple electrodeposition method. These unique helical porous structures enable electrodes to have a high capacitance and an outstanding cycling performance. Based on the helical NaxMnO2/CC as the positive electrodes and helical MoO2/CC as the negative electrodes, high performance NaxMnO2/CC//MoO2/CC asymmetric supercapacitors (ASCs) are successfully assembled, and they achieve a maximum volume C sp of 2.04 F cm–3 and a maximum energy density of 0.92 mW h cm–3 for the whole device and an excellent cycling stability with 97.22% C sp retention after 6000 cycles. PMID:28791103

A study of effective atomic numbers and electron densities of some vitamins for electron, H, He and C ion interactions

NASA Astrophysics Data System (ADS)

Büyükyıldız, M.

2017-09-01

The radiological properties of some vitamins such as Retinol, Beta-carotene, Riboflavin, Niacin, Niacinamide, Pantothenic acid, Pyridoxine, Pyridoxamine, Pyridoxal, Biotin, Folic acid, Ascorbic acid, Cholecalciferol, Alpha-tocopherol, Gamma-tocopherol, Phylloquinone have been investigated with respect to total electron interaction and some heavy charged particle interaction as means of effective atomic numbers (Z_{eff}) and electron densities (N_{eff}) for the first time. Calculations were performed for total electron interaction and heavy ions such as H, He and C ion interactions in the energy region 10keV-10MeV by using a logarithmic interpolation method. Variations in Z_{eff}'s and N_{eff}'s of given vitamins have been studied according to the energy of electron or heavy charged particles, and significant variations have been observed for all types of interaction in the given energy region. The maximum values of Z_{eff} have been found in the different energy regions for different interactions remarkably and variations in N_{eff} seem approximately to be the same with variation in Z_{eff} for the given vitamins as expected. Z_{eff} values of some vitamins were plotted together and compared with each other for electron, H, He and C interactions and the ratios of Z_{eff}/ < A > have been changed in the range of 0.25-0.36, 0.20-0.36, 0.22-0.35 and 0.20-0.35 for electron, H, He and C interactions, respectively.

Validation of COSMIC radio occultation electron density profiles by incoherent scatter radar data

NASA Astrophysics Data System (ADS)

Cherniak, Iurii; Zakharenkova, Irina

The COSMIC/FORMOSAT-3 is a joint US/Taiwan radio occultation mission consisting of six identical micro-satellites. Each microsatellite has a GPS Occultation Experiment payload to operate the ionospheric RO measurements. FS3/COSMIC data can make a positive impact on global ionosphere study providing essential information about height electron density distribu-tion. For correct using of the RO electron density profiles for geophysical analysis, modeling and other applications it is necessary to make validation of these data with electron density distributions obtained by another measurement techniques such as proven ground based facili-ties -ionosondes and IS radars. In fact as the ionosondes provide no direct information on the profile above the maximum electron density and the topside ionosonde profile is obtained by fitting a model to the peak electron density value, the COSMIC RO measurements can make an important contribution to the investigation of the topside part of the ionosphere. IS radars provide information about the whole electron density profile, so we can estimate the agreement of topside parts between two independent measurements. To validate the reliability of COS-MIC data we have used the ionospheric electron density profiles derived from IS radar located near Kharkiv, Ukraine (geographic coordinates: 49.6N, 36.3E, geomagnetic coordinates: 45.7N, 117.8E). The Kharkiv radar is a sole incoherent scatter facility on the middle latitudes of Eu-ropean region. The radar operates with 100-m zenith parabolic antenna at 158 MHz with peak transmitted power 2.0 MW. The Kharkiv IS radar is able to determine the heights-temporal distribution of ionosphere parameters in height range of 70-1500 km. At the ionosphere in-vestigation by incoherent scatter method there are directly measured the power spectrum (or autocorrelation function) of scattered signal. With using of rather complex procedure of the received signal processing it is possible to estimate the majority of the ionospheric parameters -density and kinetic temperature of electron and main ions, the plasma drift velocity and others. The comparison of RO reveals that usually COSMIC RO profiles are in a rather good agreement with ISR profiles both in the F2 layer peak electron density (NmF2) and the form of profiles. The coincidence of profiles is better in the cases when projection of the ray path of tangent points is closer to the ISR location. It is necessary to note that retrieved electron density profiles should not be interpreted as actual vertical profiles. The geographical location of the ray path tangent points at the top and at the bottom of a profile may differ by several hundred kilometers. So the spatial smearing of data takes place and RO technique represents an image of vertical and horizontal ionospheric structure. That is why the comparison with ground-based data has rather relative character. We derived quantitative parameters to char-acterize the differences of the compared profiles: the peak height difference, the relative peak density difference. Most of the compared profiles agree within error limits, depending on the accuracy of the occultation-and the radar-derived profiles. In general COSMIC RO profiles are in a good agreement with incoherent radar profiles both in the F2 layer peak electron density (NmF2) and the form of the profiles. The coincidence of COSMIC and incoherent radar pro-files is better in the cases when projection of the ray path tangent points is closer to the radar location. COSMIC measurements can be efficiently used to study the topside part of the iono-spheric electron density. To validate the reliability of the COSMIC ionospheric observations it must be done the big work on the analysis and statistical generalization of the huge data array (today the total number of ionospheric occultation is more than 2.300.000), but this technique is a very promising one to retrieve accurate profiles of the ionospheric electron density with ground-based measurements on a global scale. We acknowledge the Taiwan's National Space Organization (NSPO) and the University Corporation for Atmospheric Research (UCAR) for providing the COSMIC Data.

Optoelectronics of inverted type-I CdS/CdSe core/crown quantum ring

NASA Astrophysics Data System (ADS)

Bose, Sumanta; Fan, Weijun; Zhang, Dao Hua

2017-10-01

Inverted type-I heterostructure core/crown quantum rings (QRs) are quantum-efficient luminophores, whose spectral characteristics are highly tunable. Here, we study the optoelectronic properties of type-I core/crown CdS/CdSe QRs in the zincblende phase—over contrasting lateral size and crown width. For this, we inspect their strain profiles, transition energies, transition matrix elements, spatial charge densities, electronic bandstructures, band-mixing probabilities, optical gain spectra, maximum optical gains, and differential optical gains. Our framework uses an effective-mass envelope function theory based on the 8-band k ṡ p method employing the valence force field model for calculating the atomic strain distributions. The gain calculations are based on the density-matrix equation and take into consideration the excitonic effects with intraband scattering. Variations in the QR lateral size and relative widths of core and crown (ergo the composition) affect their energy levels, band-mixing probabilities, optical transition matrix elements, emission wavelengths/intensities, etc. The optical gain of QRs is also strongly dimension and composition dependent with further dependency on the injection carrier density causing the band-filling effect. They also affect the maximum and differential gain at varying dimensions and compositions.

Microbial fuel cell operation using monoazo and diazo dyes as terminal electron acceptor for simultaneous decolourisation and bioelectricity generation.

PubMed

Oon, Yoong-Sin; Ong, Soon-An; Ho, Li-Ngee; Wong, Yee-Shian; Oon, Yoong-Ling; Lehl, Harvinder Kaur; Thung, Wei-Eng; Nordin, Noradiba

2017-03-05

Monoazo and diazo dyes [New coccine (NC), Acid orange 7 (AO7), Reactive red 120 (RR120) and Reactive green 19 (RG19)] were employed as electron acceptors in the abiotic cathode of microbial fuel cell. The electrons and protons generated from microbial organic oxidation at the anode which were utilized for electrochemical azo dye reduction at the cathodic chamber was successfully demonstrated. When NC was employed as the electron acceptor, the chemical oxygen demand (COD) removal and dye decolourisation efficiencies obtained at the anodic and cathodic chamber were 73±3% and 95.1±1.1%, respectively. This study demonstrated that the decolourisation rates of monoazo dyes were ∼50% higher than diazo dyes. The maximum power density in relation to NC decolourisation was 20.64mW/m 2 , corresponding to current density of 120.24mA/m 2 . The decolourisation rate and power output of different azo dyes were in the order of NC>AO7>RR120>RG19. The findings revealed that the structure of dye influenced the decolourisation and power performance of MFC. Azo dye with electron-withdrawing group at para substituent to azo bond would draw electrons from azo bond; hence the azo dye became more electrophilic and more favourable for dye reduction. Copyright © 2016 Elsevier B.V. All rights reserved.

The effect of different π-bridge configuration on bi-anchored triphenylamine and phenyl modified triphenylamine based dyes for dye sensitized solar cell (DSSC) application: A theoretical approach.

PubMed

Pounraj, P; Mohankumar, V; Pandian, M Senthil; Ramasamy, P

2018-01-01

Twenty eight bi-anchored triphenylamine (TH-1 to TH-14) and phenyl modified triphenylamine (PH-TH-1 to PH-TH-14) based metal free organic dyes are designed for DSSC application. The electronic effect of different π-bridge configurations in donor-π-bridge-acceptor (D-π-A) 2 structure was theoretically simulated and verified using density functional theory (DFT) and time dependent density functional theory (TD-DFT). The triphenylamine and phenyl modified triphenylamine groups are used as donor and cyanoacrylic acid group is used as acceptor. Thiophene and cyanovinyl groups are used as π-bridge. The ground state molecular structure was optimized by density functional theory and the electronic absorption spectra were calculated by time dependent density functional theory. The light harvesting efficiency (LHE), dye regeneration energy (ΔG reg ) and electron injection energy (ΔG inject ) are determined by computational examination. It is observed that, when the number of π-bridge increases, the band gap of the dye decreases. Also the absorption maximum and molar extinction coefficient of the dyes are increased. Theoretical result shows that the thiophene-cyanovinyl and thiophene-thiophene-cyanovinyl-cyanovinyl configurations give broader and red shifted absorption spectrum compared to other configurations. Also the results of phenyl modified triphenylamine (PH-TH) dyes clearly show better absorption and dye regeneration energy compared to TH dyes. Copyright © 2017 Elsevier Inc. All rights reserved.

Spatial confinement effects on spectroscopic and morphological studies of nanosecond laser-ablated Zirconium

NASA Astrophysics Data System (ADS)

Hayat, Asma; Bashir, Shazia; Rafique, Muhammad Shahid; Ahmad, Riaz; Akram, Mahreen; Mahmood, Khaliq; Zaheer, Ali

2017-12-01

Spatial confinement effects on plasma parameters and surface morphology of laser ablated Zr (Zirconium) are studied by introducing a metallic blocker. Nd:YAG laser at various fluencies ranging from 8 J cm-2 to 32 J cm-2 was employed as an irradiation source. All measurements were performed in the presence of Ar under different pressures. Confinement effects offered by metallic blocker are investigated by placing the blocker at different distances of 6 mm, 8 mm and 10 mm from the target surface. It is revealed from LIBS analysis that both plasma parameters i.e. excitation temperature and electron number density increase with increasing laser fluence due to enhancement in energy deposition. It is also observed that spatial confinement offered by metallic blocker is responsible for the enhancement of both electron temperature and electron number density of Zr plasma. This is true for all laser fluences and pressures of Ar. Maximum values of electron temperature and electron number density without blocker are 12,600 K and 14 × 1017 cm-3 respectively whereas, these values are enhanced to 15,000 K and 21 × 1017 cm-3 in the presence of blocker. The physical mechanisms responsible for the enhancement of Zr plasma parameters are plasma compression, confinement and pronounced collisional excitations due to reflection of shock waves. Scanning Electron Microscope (SEM) analysis was performed to explore the surface morphology of laser ablated Zr. It reveals the formation of cones, cavities and ripples. These features become more distinct and well defined in the presence of blocker due to plasma confinement. The optimum combination of blocker distance, fluence and Ar pressure can identify the suitable conditions for defining the role of plasma parameters for surface structuring.

Possible link of sudden onset and short-time periodic pulsation of polar mesosphere summer echoes to ULF Pc5 geomagnetic pulsations and solar wind dynamic pressure enhancement

NASA Astrophysics Data System (ADS)

Lee, Y.; Kirkwood, S.; Kwak, Y. S.

2016-12-01

The EISCAT VHF incoherent scatter radar in Tromsö, Norway, makes occasional observations of electron densities and Polar Mesosphere Summer Echoes, in the summer polar D-region ionosphere. In one of those datasets, pulsating polar mesospheric summer echoes (PMSE) are observed, with periodicities in the ultra-low frequency (ULF) Pc5 band (1.6-6.7 mHz), following an abrupt increase of the radar reflectivity when a geomagnetic field excursion is started, in turn linked to dynamic pressure (Pdyn) enhancement in the solar wind. At the excursion of the magnetic field, at auroral altitudes of 90 km and above, electron density is abruptly enhanced, followed by a series of short-lived peaks, superimposed on an enhanced level. The short-lived peaks are likely a signature of transient Pc5 geomagnetic pulsations and associated energetic electron precipitation from pitch-angle scattering into the loss cone in the magnetosphere. At the same time, at altitudes around 80-90 km, a sharp increase of PMSE reflectivity occurs, 100 times greater than the increase of electron density, and is followed by pulsating PMSE reflectivity with periodicities in the Pc5 band, increasing and decreasing in magnitude during the course of the next hour. The increase of the pulsation magnitude may be attributed to an increase of high-energy electron precipitation flux ( >30 keV) penetrating to at least the height of maximum PMSE reflectivity. This study suggests that Pc5 pulsation bursts in both magnetic field and high energy electron precipitation could play a crucial role in producing PMSE fluctuations on minute-to-minute time scales.

Influence of grid resolution in fluid-model simulation of nanosecond dielectric barrier discharge plasma actuator

NASA Astrophysics Data System (ADS)

Hua, Weizhuo; Fukagata, Koji

2018-04-01

Two-dimensional numerical simulation of a surface dielectric barrier discharge (SDBD) plasma actuator, driven by a nanosecond voltage pulse, is conducted. A special focus is laid upon the influence of grid resolution on the computational result. It is found that the computational result is not very sensitive to the streamwise grid spacing, whereas the wall-normal grid spacing has a critical influence. In particular, the computed propagation velocity changes discontinuously around the wall-normal grid spacing about 2 μm due to a qualitative change of discharge structure. The present result suggests that a computational grid finer than that was used in most of previous studies is required to correctly capture the structure and dynamics of streamer: when a positive nanosecond voltage pulse is applied to the upper electrode, a streamer forms in the vicinity of upper electrode and propagates along the dielectric surface with a maximum propagation velocity of 2 × 108 cm/s, and a gap with low electron and ion density (i.e., plasma sheath) exists between the streamer and dielectric surface. Difference between the results obtained using the finer and the coarser grid is discussed in detail in terms of the electron transport at a position near the surface. When the finer grid is used, the low electron density near the surface is caused by the absence of ionization avalanche: in that region, the electrons generated by ionization is compensated by drift-diffusion flux. In contrast, when the coarser grid is used, underestimated drift-diffusion flux cannot compensate the electrons generated by ionization, and it leads to an incorrect increase of electron density.

Anomalous resistivity and superconductivity in the two-band Hubbard model with one narrow band (Review)

NASA Astrophysics Data System (ADS)

Kagan, M. Yu.; Valkov, V. V.

2011-01-01

We search for marginal Fermi-liquid behavior in the two-band Hubbard model with one narrow band. We consider the limit of low electron densities in the bands and strong intraband and interband Hubbard interactions. We analyze the influence of electron-polaron effects and other mechanisms for mass-enhancement (related to the momentum dependence of the self-energies) on the effective mass and scattering times of light and heavy components in the clean case (electron-electron scattering and no impurities). We find a tendency towards phase separation (towards negative partial compressibility of heavy particles) in the 3D case with a large mismatch between the densities of heavy and light bands in the strong coupling limit. We also find that for low temperatures and equal densities, the resistivity in a homogeneous state R(T )∝T2 behaves as a Fermi-liquid in both 3D and 2D. For temperatures greater than the effective bandwidth for heavy electrons T >Wh*, the coherence of the heavy component breaks down completely. The heavy particles move diffusively in the surrounding light particles. At the same time, light particles scatter on heavy particles as if on immobile (static) impurities. Under these conditions, the heavy component is marginal, while the light component is not. The resistivity approaches saturation for T >Wh* in the 3D case. In 2D the resistivity has a maximum and a localization tail owing to weak-localization corrections of the Altshuler-Aronov type. This behavior of resistivity in 3D could be relevant for some uranium-based heavy-fermion compounds such as UNi2Al3 and in 2D, for some other mixed-valence compounds, possibly including layered manganites. We also consider briefly the superconductive (SC) instability in this model. The leading instability tends to p-wave pairing and is governed by an enhanced Kohn-Luttinger mechanism for SC at low electron densities. The critical temperature corresponds to the pairing of heavy electrons via polarization of the light electrons in 2D.

Facilitated charge transport in ternary interconnected electrodes for flexible supercapacitors with excellent power characteristics

NASA Astrophysics Data System (ADS)

Chen, Wanjun; He, Yongmin; Li, Xiaodong; Zhou, Jinyuan; Zhang, Zhenxing; Zhao, Changhui; Gong, Chengshi; Li, Shuankui; Pan, Xiaojun; Xie, Erqing

2013-11-01

Flexible and high performance supercapacitors are very critical in modern society. In order to develop the flexible supercapacitors with high power density, free-standing and flexible three-dimensional graphene/carbon nanotubes/MnO2 (3DG/CNTs/MnO2) composite electrodes with interconnected ternary 3D structures were fabricated, and the fast electron and ion transport channels were effectively constructed in the rationally designed electrodes. Consequently, the obtained 3DG/CNTs/MnO2 composite electrodes exhibit superior specific capacitance and rate capability compared to 3DG/MnO2 electrodes. Furthermore, the 3DG/CNTs/MnO2 based asymmetric supercapacitor demonstrates the maximum energy and power densities of 33.71 W h kg-1 and up to 22 727.3 W kg-1, respectively. Moreover, the asymmetric supercapacitor exhibits excellent cycling stability with 95.3% of the specific capacitance maintained after 1000 cycle tests. Our proposed synthesis strategy to construct the novel ternary 3D structured electrodes can be efficiently applied to other high performance energy storage/conversion systems.Flexible and high performance supercapacitors are very critical in modern society. In order to develop the flexible supercapacitors with high power density, free-standing and flexible three-dimensional graphene/carbon nanotubes/MnO2 (3DG/CNTs/MnO2) composite electrodes with interconnected ternary 3D structures were fabricated, and the fast electron and ion transport channels were effectively constructed in the rationally designed electrodes. Consequently, the obtained 3DG/CNTs/MnO2 composite electrodes exhibit superior specific capacitance and rate capability compared to 3DG/MnO2 electrodes. Furthermore, the 3DG/CNTs/MnO2 based asymmetric supercapacitor demonstrates the maximum energy and power densities of 33.71 W h kg-1 and up to 22 727.3 W kg-1, respectively. Moreover, the asymmetric supercapacitor exhibits excellent cycling stability with 95.3% of the specific capacitance maintained after 1000 cycle tests. Our proposed synthesis strategy to construct the novel ternary 3D structured electrodes can be efficiently applied to other high performance energy storage/conversion systems. Electronic supplementary information (ESI) available: Additional experimental details; calculations of the specific capacitances, and energy and power densities; additional SEM and optical images; XPS results; additional electrochemical results. See DOI: 10.1039/c3nr03923d

Maximum stand density for ponderosa pine and red and white fir in northern California

Treesearch

William.W. Oliver; Fabian C.C. Uzoh

1997-01-01

Why are forest managers interested in quantifying maximum stand density? Nearly all conceivable management objectives dictate a stand density less than a biological maximum. Certainly, the notion that thinning dense stands increases growth on the remaining trees and reduces mortality is well-established in the literature. The interest in quantifying maximum stand...

Enhanced two dimensional electron gas transport characteristics in Al2O3/AlInN/GaN metal-oxide-semiconductor high-electron-mobility transistors on Si substrate

NASA Astrophysics Data System (ADS)

Freedsman, J. J.; Watanabe, A.; Urayama, Y.; Egawa, T.

2015-09-01

The authors report on Al2O3/Al0.85In0.15N/GaN Metal-Oxide-Semiconductor High-Electron-Mobility Transistor (MOS-HEMT) on Si fabricated by using atomic layer deposited Al2O3 as gate insulator and passivation layer. The MOS-HEMT with the gate length of 2 μm exhibits excellent direct-current (dc) characteristics with a drain current maximum of 1270 mA/mm at a gate bias of 3 V and an off-state breakdown voltage of 180 V for a gate-drain spacing of 4 μm. Also, the 1 μm-gate MOS-HEMT shows good radio-frequency (rf) response such as current gain and maximum oscillation cut-off frequencies of 10 and 34 GHz, respectively. The capacitance-voltage characteristics at 1 MHz revealed significant increase in two-dimensional electron gas (2DEG) density for the MOS-HEMT compared to conventional Schottky barrier HEMTs. Analyses using drain-source conductivity measurements showed improvements in 2DEG transport characteristics for the MOS-HEMT. The enhancements in dc and rf performances of the Al2O3/Al0.85In0.15N/GaN MOS-HEMT are attributed to the improvements in 2DEG characteristics.

Deuterium cluster model for low energy nuclear reactions (LENR)

NASA Astrophysics Data System (ADS)

Miley, George; Hora, Heinrich

2007-11-01

For studying the possible reactions of high density deuterons on the background of a degenerate electron gas, a summary of experimental observations resulted in the possibility of reactions in pm distance and more than ksec duration similar to the K-shell electron capture [1]. The essential reason was the screening of the deuterons by a factor of 14 based on the observations. Using the bosonic properties for a cluster formation of the deuterons and a model of compound nuclear reactions [2], the measured distribution of the resulting nuclei may be explained as known from the Maruhn-Greiner theory for fission. The local maximum of the distribution at the main minimum indicates the excited states of the compound nuclei during their intermediary state. This measured local maximum may be an independent proof for the deuteron clusters at LENR. [1] H. Hora, G.H. Miley et al. Physics Letters A175, 138 (1993) [2] H. Hora and G.H. Miley, APS March Meeting 2007, Program p. 116

Design and Performance Analysis of Depletion-Mode InSb Quantum-Well Field-Effect Transistor for Logic Applications

NASA Astrophysics Data System (ADS)

Islam, R.; Uddin, M. M.; Hossain, M. Mofazzal; Matin, M. A.

The design of a 1μm gate length depletion-mode InSb quantum-well field-effect transistor (QWFET) with a 10nm-thick Al2O3 gate dielectric has been optimized using a quantum corrected self-consistent Schrödinger-Poisson (QCSP) and two-dimensional drift-diffusion model. The model predicts a very high electron mobility of 4.42m2V-1s-1 at Vg=0V, a small pinch off gate voltage (Vp) of -0.25V, a maximum extrinsic transconductance (gm) of ˜4.85mS/μm and a drain current density of more than 3.34mA/μm. A short-circuit current-gain cut-off frequency (fT) of 374GHz and a maximum oscillation frequency (fmax) of 645GHz are predicted for the device. These characteristics make the device a potential candidate for low power, high-speed logic electronic device applications.

Wrapping Aligned Carbon Nanotube Composite Sheets around Vanadium Nitride Nanowire Arrays for Asymmetric Coaxial Fiber-Shaped Supercapacitors with Ultrahigh Energy Density.

PubMed

Zhang, Qichong; Wang, Xiaona; Pan, Zhenghui; Sun, Juan; Zhao, Jingxin; Zhang, Jun; Zhang, Cuixia; Tang, Lei; Luo, Jie; Song, Bin; Zhang, Zengxing; Lu, Weibang; Li, Qingwen; Zhang, Yuegang; Yao, Yagang

2017-04-12

The emergence of fiber-shaped supercapacitors (FSSs) has led to a revolution in portable and wearable electronic devices. However, obtaining high energy density FSSs for practical applications is still a key challenge. This article exhibits a facile and effective approach to directly grow well-aligned three-dimensional vanadium nitride (VN) nanowire arrays (NWAs) on carbon nanotube (CNT) fiber with an ultrahigh specific capacitance of 715 mF/cm 2 in a three-electrode system. Benefiting from their intriguing structural features, we successfully fabricated a prototype asymmetric coaxial FSS (ACFSS) with a maximum operating voltage of 1.8 V. From core to shell, this ACFSS consists of a CNT fiber core coated with VN@C NWAs as the negative electrode, Na 2 SO 4 poly(vinyl alcohol) (PVA) as the solid electrolyte, and MnO 2 /conducting polymer/CNT sheets as the positive electrode. The novel coaxial architecture not only fully enables utilization of the effective surface area and decreases the contact resistance between the two electrodes but also, more importantly, provides a short pathway for the ultrafast transport of axial electrons and ions. The electrochemical results show that the optimized ACFSS exhibits a remarkable specific capacitance of 213.5 mF/cm 2 and an exceptional energy density of 96.07 μWh/cm 2 , the highest areal capacitance and areal energy density yet reported in FSSs. Furthermore, the device possesses excellent flexibility in that its capacitance retention reaches 96.8% after bending 5000 times, which further allows it to be woven into flexible electronic clothes with conventional weaving techniques. Therefore, the asymmetric coaxial architectural design allows new opportunities to fabricate high-performance flexible FSSs for future portable and wearable electronic devices.

Comparing methods to estimate Reineke’s maximum size-density relationship species boundary line slope

Treesearch

Curtis L. VanderSchaaf; Harold E. Burkhart

2010-01-01

Maximum size-density relationships (MSDR) provide natural resource managers useful information about the relationship between tree density and average tree size. Obtaining a valid estimate of how maximum tree density changes as average tree size changes is necessary to accurately describe these relationships. This paper examines three methods to estimate the slope of...

Bio-energy generation in an affordable, single-chamber microbial fuel cell integrated with adsorption hybrid system: effects of temperature and comparison study.

PubMed

Tee, Pei-Fang; Abdullah, Mohammad Omar; Tan, Ivy A W; Amin, Mohamed A M; Nolasco-Hipolito, Cirilo; Bujang, Kopli

2018-04-01

A microbial fuel cell (MFC) integrated with adsorption system (MFC-AHS) is tested under various operating temperatures with palm oil mill effluent as the substrate. The optimum operating temperature for such system is found to be at ∼35°C with current, power density, internal resistance (R in ), Coulombic efficiency (CE) and maximum chemical oxygen demand (COD) removal of 2.51 ± 0.2 mA, 74 ± 6 mW m -3 , 25.4 Ω, 10.65 ± 0.5% and 93.57 ± 1.2%, respectively. Maximum current density increases linearly with temperature at a rate of 0.1772 mA m -2  °C -1 , whereas maximum power density was in a polynomial function. The temperature coefficient (Q 10 ) is found to be 1.20 between 15°C and 35°C. Present studies have demonstrated better CE performance when compared to other MFC-AHSs. Generally, MFC-AHS has demonstrated higher COD removals when compared to standalone MFC regardless of operating temperatures. ACFF: activated carbon fiber felt; APHA: American Public Health Association; CE: Coulombic efficiency; COD: chemical oxygen demand; ECG: electrocardiogram; GAC: granular activated carbon; GFB: graphite fiber brush; MFC: microbial fuel cell; MFC-AHS: microbial fuel cell integrated with adsorption hybrid system; MFC-GG: microbial fuel cell integrated with graphite granules; POME: palm oil mill effluent; PTFE: polytetrafluoroethylene; SEM: scanning electron microscope.

Reduction of gate leakage current on AlGaN/GaN high electron mobility transistors by electron-beam irradiation.

PubMed

Oh, S K; Song, C G; Jang, T; Kim, Kwang-Choong; Jo, Y J; Kwak, J S

2013-03-01

This study examined the effect of electron-beam (E-beam) irradiation on the AIGaN/GaN HEMTs for the reduction of gate leakage. After E-beam irradiation, the gate leakage current significantly decreased from 2.68 x 10(-8) A to 4.69 x 10(-9) A at a drain voltage of 10 V. The maximum drain current density of the AIGaN/GaN HEMTs with E-beam irradiation increased 14%, and the threshold voltage exhibited a negative shift, when compared to that of the AIGaN/GaN HEMTs before E-beam irradiation. These results strongly suggest that the reduction of gate leakage current resulted from neutralization nitrogen vacancies and removing of oxygen impurities.

Bremsstrahlung hard x-ray source driven by an electron beam from a self-modulated laser wakefield accelerator

NASA Astrophysics Data System (ADS)

Lemos, N.; Albert, F.; Shaw, J. L.; Papp, D.; Polanek, R.; King, P.; Milder, A. L.; Marsh, K. A.; Pak, A.; Pollock, B. B.; Hegelich, B. M.; Moody, J. D.; Park, J.; Tommasini, R.; Williams, G. J.; Chen, Hui; Joshi, C.

2018-05-01

An x-ray source generated by an electron beam produced using a Self-Modulated Laser Wakefield Accelerator (SM-LWFA) is explored for use in high energy density science facilities. By colliding the electron beam, with a maximum energy of 380 MeV, total charge of >10 nC and a divergence of 64 × 100 mrad, from a SM-LWFA driven by a 1 ps 120 J laser, into a high-Z foil, an x/gamma-ray source was generated. A broadband bremsstrahlung energy spectrum with temperatures ranging from 0.8 to 2 MeV was measured with an almost 2 orders of magnitude flux increase when compared with other schemes using LWFA. GEANT4 simulations were done to calculate the source size and divergence.

19.2% Efficient InP Heterojunction Solar Cell with Electron-Selective TiO 2 Contact

DOE PAGES

Yin, Xingtian; Battaglia, Corsin; Lin, Yongjing; ...

2014-09-25

We demonstrate an InP heterojunction solar cell employing an ultrathin layer (~10 nm) of amorphous TiO 2 deposited at 120°C by atomic layer deposition as the transparent electron-selective contact. The TiO 2 film selectively extracts minority electrons from the conduction band of p-type InP while blocking the majority holes due to the large valence band offset, enabling a high maximum open-circuit voltage of 785 mV. Lastly, a hydrogen plasma treatment of the InP surface drastically improves the long-wavelength response of the device, resulting in a high short-circuit current density of 30.5 mA/cm 2 and a high power conversion efficiency ofmore » 19.2%.« less

Strong interplay between structure and electronic properties in CuIn(S,Se){2}: a first-principles study.

PubMed

Vidal, Julien; Botti, Silvana; Olsson, Pär; Guillemoles, Jean-François; Reining, Lucia

2010-02-05

We present a first-principles study of the electronic properties of CuIn(S,Se){2} (CIS) using state-of-the-art self-consistent GW and hybrid functionals. The calculated band gap depends strongly on the anion displacement u, an internal structural parameter that measures lattice distortion. This contrasts with the observed stability of the band gap of CIS solar panels under operating conditions, where a relatively large dispersion of values for u occurs. We solve this apparent paradox considering the coupled effect on the band gap of copper vacancies and lattice distortions. The correct treatment of d electrons in these materials requires going beyond density functional theory, and GW self-consistency is critical to evaluate the quasiparticle gap and the valence band maximum.

Electron beam induced current in the high injection regime.

PubMed

Haney, Paul M; Yoon, Heayoung P; Koirala, Prakash; Collins, Robert W; Zhitenev, Nikolai B

2015-07-24

Electron beam induced current (EBIC) is a powerful technique which measures the charge collection efficiency of photovoltaics with sub-micron spatial resolution. The exciting electron beam results in a high generation rate density of electron-hole pairs, which may drive the system into nonlinear regimes. An analytic model is presented which describes the EBIC response when the total electron-hole pair generation rate exceeds the rate at which carriers are extracted by the photovoltaic cell, and charge accumulation and screening occur. The model provides a simple estimate of the onset of the high injection regime in terms of the material resistivity and thickness, and provides a straightforward way to predict the EBIC lineshape in the high injection regime. The model is verified by comparing its predictions to numerical simulations in one- and two-dimensions. Features of the experimental data, such as the magnitude and position of maximum collection efficiency versus electron beam current, are consistent with the three-dimensional model.

Anomalous Behavior of Electronic Heat Capacity of Strongly Correlated Iron Monosilicide

NASA Astrophysics Data System (ADS)

Povzner, A. A.; Volkov, A. G.; Nogovitsyna, T. A.

2018-04-01

The paper deals with the electronic heat capacity of iron monosilicide FeSi subjected to semiconductor-metal thermal transition during which the formation of its spintronic properties is observed. The proposed model which considers pd-hybridization of strongly correlated d-electrons with non-correlated p-electrons, demonstrates a connection of their contribution to heat capacity in the insulator phase with paramagnon effects and fluctuations of occupation numbers for p- and d-states. In a slitless state, the temperature curve of heat capacity is characterized by a maximum appeared due to normalization of the electron density of states using fluctuating exchange fields. At higher temperatures, a linear growth in heat capacity occurs due to paramagnon effects. The correlation between the model parameters and the first-principles calculation provides the electron contribution to heat capacity, which is obtained from the experimental results on phonon heat capacity. Anharmonicity of phonons is connected merely with the thermal expansion of the crystal lattice.

Collisional, radiative and total electron interaction in compound semiconductor detectors and solid state nuclear track detectors: effective atomic number and electron density.

PubMed

Kurudirek, Murat; Kurudirek, Sinem V

2015-05-01

Effective atomic numbers, Zeff and electron densities, Ne are widely used for characterization of interaction processes in radiation related studies. A variety of detectors are employed to detect different types of radiations i.e. photons and charged particles. In the present work, some compound semiconductor detectors (CSCD) and solid state nuclear track detectors (SSNTD) were investigated with respect to the partial as well as total electron interactions. Zeff and Ne of the given detectors were calculated for collisional, radiative and total electron interactions in the kinetic energy region 10keV-1GeV. Maximum values of Zeff and Ne were observed at higher kinetic energies of electrons. Significant variations in Zeff and Ne up to ≈20-25% were noticed for the detectors, GaN, ZnO, Amber and CR-39 for total electron interaction. Moreover, the obtained Zeff and Ne for electrons were compared to those obtained for photons in the entire energy region. Significant variations in Zeff were also noted not only for photons (up to ≈40% for GaN) but also between photons and electrons (up to ≈60% for CR-39) especially at lower energies. Except for the lower energies, Zeff and Ne keep more or less constant values for the given materials. The energy regions where Zeff and Ne keep constant clearly show the availability of using these parameters for characterization of the materials with respect to the radiation interaction processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

Directed Block Copolymer Assembly versus Electron Beam Lithography for Bit-Patterned Media with Areal Density of 1 Terabit/inch(2) and Beyond.

PubMed

Yang, Xiaomin; Wan, Lei; Xiao, Shuaigang; Xu, Yuan; Weller, Dieter K

2009-07-28

The directed self-assembly of block copolymer (BCP) offers a new route to perfect nanolithographic patterning at sub-50 nm length scale with molecular scale precision. We have explored the feasibility of using the BCP approach versus the conventional electron beam (e-beam) lithography to create highly dense dot patterns for bit-patterned media (BPM) applications. Cylinder-forming poly(styrene-b-methyl methacrylate) (PS-b-PMMA) directly self-assembled on a chemically prepatterned substrate. The nearly perfect hexagonal arrays of perpendicularly oriented cylindrical pores at a density of approximately 1 Terabit per square inch (Tb/in.(2)) are achieved over an arbitrarily large area. Considerable gains in the BCP process are observed relative to the conventional e-beam lithography in terms of the dot size variation, the placement accuracy, the pattern uniformity, and the exposure latitude. The maximum dimensional latitude in the cylinder-forming BCP patterns and the maximum skew angle that the BCP can tolerate have been investigated for the first time. The dimensional latitude restricts the formation of more than one lattice configuration in certain ranges. More defects in BCP patterns are observed when using low molecular weight BCP materials or on non-hexagonal prepatterns due to the dimensional latitude restriction. Finally, the limitations and challenges in the BCP approach that are associated with BPM applications will be briefly discussed.

An investigation of the ionospheric F region near the EIA crest in India using OI 777.4 and 630.0 nm nightglow observations

NASA Astrophysics Data System (ADS)

Parihar, Navin; Radicella, Sandro Maria; Nava, Bruno; Migoya-Orue, Yenca Olivia; Tiwari, Prabhakar; Singh, Rajesh

2018-05-01

Simultaneous observations of OI 777.4 and OI 630.0 nm nightglow emissions were carried at a low-latitude station, Allahabad (25.5° N, 81.9° E; geomag. lat. ˜ 16.30° N), located near the crest of the Appleton anomaly in India during September-December 2009. This report attempts to study the F region of ionosphere using airglow-derived parameters. Using an empirical approach put forward by Makela et al. (2001), firstly, we propose a novel technique to calibrate OI 777.4 and 630.0 nm emission intensities using Constellation Observing System for Meteorology, Ionosphere, and Climate/Formosa Satellite Mission 3 (COSMIC/FORMOSAT-3) electron density profiles. Next, the electron density maximum (Nm) and its height (hmF2) of the F layer have been derived from the information of two calibrated intensities. Nocturnal variation of Nm showed the signatures of the retreat of the equatorial ionization anomaly (EIA) and the midnight temperature maximum (MTM) phenomenon that are usually observed in the equatorial and low-latitude ionosphere. Signatures of gravity waves with time periods in the range of 0.7-3.0 h were also seen in Nm and hmF2 variations. Sample Nm and hmF2 maps have also been generated to show the usefulness of this technique in studying ionospheric processes.

Nano-size defects in arsenic-implanted HgCdTe films: a HRTEM study

NASA Astrophysics Data System (ADS)

Bonchyk, O. Yu.; Savytskyy, H. V.; Swiatek, Z.; Morgiel, Y.; Izhnin, I. I.; Voitsekhovskii, A. V.; Korotaev, A. G.; Mynbaev, K. D.; Fitsych, O. I.; Varavin, V. S.; Dvoretsky, S. A.; Marin, D. V.; Yakushev, M. V.

2018-02-01

Radiation damage and its transformation under annealing were studied with bright-field and high-resolution transmission electron microscopy for arsenic-implanted HgCdTe films with graded-gap surface layers. In addition to typical highly defective layers in as-implanted material, a 50 nm-thick sub-surface layer with very low defect density was observed. The main defects in other layers after implantation were dislocation loops, yet after arsenic activation annealing, the dominating defects were single dislocations. Transport (from depth to surface), transformation and annihilation of radiation-induced defects were observed as a result of annealing, with the depth with the maximum defect density decreasing from 110 to 40 nm.

Characterization of atomic oxygen from an ECR plasma source

NASA Astrophysics Data System (ADS)

Naddaf, M.; Bhoraskar, V. N.; Mandale, A. B.; Sainkar, S. R.; Bhoraskar, S. V.

2002-11-01

A low-power microwave-assisted electron cyclotron resonance (ECR) plasma system is shown to be a powerful and effective source of atomic oxygen (AO) useful in material processing. A 2.45 GHz microwave source with maximum power of 600 W was launched into the cavity to generate the ECR plasma. A catalytic nickel probe was used to determine the density of AO. The density of AO is studied as a function of pressure and axial position of the probe in the plasma chamber. It was found to vary from ~1×1020 to ~10×1020 atom m-3 as the plasma pressure was varied from 0.8 to 10 mTorr. The effect of AO in oxidation of silver is investigated by gravimetric analysis. The stoichiometric properties of the oxide are studied using the x-ray photoelectron spectroscopy as well as energy dispersive x-ray analysis. The degradation of the silver surface due to sputtering effect was viewed by scanning electron spectroscopy. The sputtering yield of oxygen ions in the plasma is calculated using the TRIM code. The effects of plasma pressure and the distance from the ECR zone on the AO density were also investigated. The density of AO measured by oxidation of silver is in good agreement with results obtained from the catalytic nickel probe.

Electrostatic-probe measurements of plasma parameters for two reentry flight experiments at 25000 feet per second

NASA Technical Reports Server (NTRS)

Jones, W. L., Jr.; Cross, A. E.

1972-01-01

Unique plasma diagnostic measurements at high altitudes from two geometrically similar blunt body reentry spacecraft using electrostatic probe rakes are presented. The probes measured the positive ion density profiles (shape and magnitude) during the two flights. The probe measurements were made at eight discrete points (1 cm to 7 cm) from the vehicle surface in the aft flow field of the spacecraft over the altitude range of 85.3 to 53.3 km (280,000 to 175,000 ft) with measured densities of 10 to the 8th power to 10 to the 12th power electrons/cu cm, respectively. Maximum reentry velocity for each spacecraft was approximately 7620 meters/second (25,000 ft/sec). In the first flight experiment, water was periodically injected into a flow field which was contaminated by ablation products from the spacecraft nose region. The nonablative nose of the second spacecraft thereby minimized flow field contamination. Comparisons of the probe measured density profiles with theoretical calculations are presented with discussion as to the probable cause of significant disagreement. Also discussed are the correlation of probe measurements with vehicle angle of attack motions and the good high altitude agreement between electron densities inferred from the probe measurements, VHF antenna measurements, and microwave reflectometer diagnostic measurements.

Excitation of lower hybrid waves by a spiraling ion beam in a magnetized dusty plasma cylinder

NASA Astrophysics Data System (ADS)

Sharma, Suresh C.; Walia, Ritu

2008-09-01

A spiraling ion beam propagating through a magnetized dusty plasma cylinder drives electrostatic lower hybrid waves to instability via cyclotron interaction. Numerical calculations of the growth rate and unstable mode frequencies have been carried out for the Princeton Q-1 device using the experimental dusty plasma parameters [e.g., Barkan et al., Planet. Space Sci. 43, 905 (1995)]. It is found that as the density ratio δ(=nio/neo, where ni0 is the ion plasma density and ne0 is the electron density) of negatively charged dust grains to electrons increases, the unstable mode frequency of the lower hybrid waves increases. In addition, the growth rate of the instability also increases with the density ratio δ. In other words, the presence of negatively charged dust grains can further destabilize the lower hybrid wave instability. The growth rate has the largest value for the modes where Jl(pnro) is maximum [here pn=xn/r0, where pn is the perpendicular wave number in cm-1, r0 is the plasma radius, and xn are the zeros of the Bessel function J1(x )] i.e., whose eigenfunctions peak at the location of the beam. The growth rate scales as one third power of the beam current.

Runaway electron studies with hard x-ray and microwave diagnostics in the FT-2 lower hybrid current drive discharges

NASA Astrophysics Data System (ADS)

Shevelev, A. E.; Khilkevitch, E. M.; Lashkul, S. I.; Rozhdestvensky, V. V.; Pandya, S. P.; Plyusnin, V. V.; Altukhov, A. B.; Kouprienko, D. V.; Chugunov, I. N.; Doinikov, D. N.; Esipov, L. A.; Gin, D. B.; Iliasova, M. V.; Naidenov, V. O.; Polunovsky, I. A.; Sidorov, A. V.; Kiptily, V. G.

2018-01-01

Studies of the super-thermal and runaway electron behavior in ohmic and lower hybrid current drive FT-2 tokamak plasmas have been carried out using information obtained from measurements of hard x-ray spectra and non-thermal microwave radiation intensity at the frequency of 10 GHz and in the range of (53 ÷ 78) GHz. A gamma-ray spectrometer based on a scintillation detector with a LaBr3(Ce) crystal was used, which provides measurements at counting rates up to 107 s-1. Reconstruction of the energy distribution of RE interacting with the poloidal limiter of the tokamak chamber was made with application of the DeGaSum code. Super-thermal electrons accelerated up to 2 MeV by the LH waves at the high-frequency pumping of the plasma with low density ≤ft< {{n}e} \\right> ~ 2  ×  1013 cm-3 and then up to 7 MeV by vortex electric field have been found. Experimental analysis of the runaway electron beam generation and evolution of their energy distribution in the FT-2 plasmas is presented in the article and compared with the numerical calculation of the maximum energy gained by runaway electrons for given plasma parameters. In addition, possible mechanisms for limiting the maximum energy gained by the runaway electrons are also calculated and described for a FT-2 plasma discharge.

Microwave emissions from police radar.

PubMed

Fink, J M; Wagner, J P; Congleton, J J; Rock, J C

1999-01-01

This study evaluated police officers' exposures to microwaves emitted by traffic radar units. Exposure measurements were taken at approximated ocular and testicular levels of officers seated in patrol vehicles. Comparisons were made of the radar manufacturers' published maximum power density specifications and actual measured power densities taken at the antenna faces of those units. Four speed-enforcement agencies and one transportation research institute provided 54 radar units for evaluation; 17 different models, encompassing 4 frequency bands and 3 antenna configurations, were included. Four of the 986 measurements taken exceeded the 5 mW/cm2 limit accepted by the International Radiation Protection Association and the National Council on Radiation Protection and Measurement, though none exceeded the American Conference of Governmental Industrial Hygienists, American National Standards Institute, Institute of Electrical and Electronic Engineers, or Occupational Safety and Health Administration standard of 10 mW/cm2. The four high measurements were maximum power density readings taken directly in front of the radar. Of the 812 measurements taken at the officers' seated ocular and testicular positions, none exceeded 0.04 mW/cm2; the highest of these (0.034 mW/cm2) was less than 1% of the most conservative current safety standards. High exposures in the limited region directly in front of the radar aperture are easily avoided with proper training. Results of this study indicate that police officer exposure to microwave radiation is apparently minimal. However, because of uncertainty in the medical and scientific communities concerning nonionizing radiation, it is recommended that law enforcement agencies implement a policy of prudent avoidance, including purchasing units with the lowest published maximum power densities, purchasing dash/rear deck-mounted units with antennae mounted outside the patrol vehicle, and training police officers to use the "stand-by" mode when not actually using radar.

Characteristics of spacecraft charging in low Earth orbit

NASA Astrophysics Data System (ADS)

Anderson, Phillip C.

2012-07-01

It has been found that the DMSP spacecraft at 840 km can charge to very large negative voltages (up to -2000 V) when encountering intense precipitating electron events (auroral arcs). We present an 11-year study of over 1600 charging events, defined as when the spacecraft charged to levels exceeding 100 V negative during an auroral crossing. The occurrence frequency of events was highly correlated with the 11-year solar cycle with the largest number of events occurring during solar minimum. This was due to the requirement that the background thermal plasma density be low, at most 104 cm-3. During solar maximum, the plasma density is typically well above that level due to the solar EUV ionizing radiation, and although the occurrence frequency of auroral arcs is considerably greater than at solar minimum, the occurrence of high-level charging is minimal. As a result of this study, we produced a model spectrum for precipitating electrons that can be used as a specification for the low-altitude auroral charging environment. There are implications from this study on a number of LEO satellite programs, including the International Space Station, which does enter the auroral zone, particularly during geomagnetic activity when the auroral boundary can penetrate to very low latitudes. The plasma density in the ISS orbit is usually well above the minimum required density for charging. However, in the wake of the ISS, the plasma density can be 2 orders of magnitude or more lower than the background density and thus conditions are ripe for charging.

Using live algae at the anode of a microbial fuel cell to generate electricity.

PubMed

Xu, Chang; Poon, Karen; Choi, Martin M F; Wang, Ruihua

2015-10-01

Live green microalgae Chlorella pyrenoidosa was introduced in the anode of a microbial fuel cell (MFC) to act as an electron donor. By controlling the oxygen content, light intensity, and algal cell density at the anode, microalgae would generate electricity without requiring externally added substrates. Two models of algal microbial fuel cells (MFCs) were constructed with graphite/carbon electrodes and no mediator. Model 1 algal MFC has live microalgae grown at the anode and potassium ferricyanide at the cathode, while model 2 algal MFC had live microalgae in both the anode and cathode in different growth conditions. Results indicated that a higher current produced in model 1 algal MFC was obtained at low light intensity of 2500 lx and algal cell density of 5 × 10(6) cells/ml, in which high algal density would limit the electricity generation, probably by increasing oxygen level and mass transfer problem. The maximum power density per unit anode volume obtained in model 1 algal MFC was relatively high at 6030 mW/m(2), while the maximum power density at 30.15 mW/m(2) was comparable with that of previous reported bacteria-driven MFC with graphite/carbon electrodes. A much smaller power density at 2.5 mW/m(2) was observed in model 2 algal MFC. Increasing the algal cell permeability by 4-nitroaniline would increase the open circuit voltage, while the mitochondrial acting and proton leak promoting agents resveratrol and 2,4-dinitrophenol would increase the electric current production in algal MFC.

Changes in atmospheric composition inferred from ionospheric production rates

NASA Technical Reports Server (NTRS)

Titheridge, J. E.

1974-01-01

Changes in the total electron content of the ionosphere near sunrise are used to determine the integrated production rate in the ionosphere (Q) from 1965 to 1971 at latitudes of 34S, 20N, and 34N. The observed regular semiannual variation in Q through a range of 1:3:1 is interpreted as an increase in the ratio O/N2 (relative densities) near the equinoxes. It follows that there is a worldwide semiannual variation in atmospheric composition, with the above ratio maximum just after the equinoxes. There is a large seasonal variation in the Northern hemisphere with a maximum in mid-summer. This effect is absent in the Southern hemisphere. At all times except solar maximum in the Northern hemisphere there is a global asymmetry. The ratio O/N2 is about three times as large in the Northern hemisphere. The overall mechanism appears to be N2 absorption.

Electronic and thermoelectric analysis of phases in the In 2O 3(ZnO) k system

DOE PAGES

Hopper, E. Mitchell; Zhu, Qimin; Song, Jung-Hwan; ...

2011-01-01

The high-temperature electrical conductivity and thermopower of several compounds in the In 2O 3(ZnO) k system (k = 3, 5, 7, and 9) were measured, and the band structures of the k = 1, 2, and 3 structures were predicted based on first-principles calculations. These phases exhibit highly dispersed conduction bands consistent with transparent conducting oxide behavior. Jonker plots (Seebeck coefficient vs. natural logarithm of conductivity) were used to obtain the product of the density of states and mobility for these phases, which were related to the maximum achievable power factor (thermopower squared times conductivity) for each phase by Ioffemore » analysis (maximum power factor vs. Jonker plot intercept). With the exception of the k = 9 phase, all other phases were found to have maximum predicted power factors comparable to other thermoelectric oxides if suitably doped.« less

Optical characteristics and parameters of gas-discharge plasma in a mixture of mercury dibromide vapor with neon

NASA Astrophysics Data System (ADS)

Malinina, A. A.; Malinin, A. N.

2013-12-01

Results are presented from studies of the optical characteristics and parameters of plasma of a dielectric barrier discharge in a mixture of mercury dibromide vapor with neon—the working medium of a non-coaxial exciplex gas-discharge emitter. The electron energy distribution function, the transport characteristics, the specific power losses for electron processes, the electron density and temperature, and the rate constants for the processes of elastic and inelastic electron scattering by the working mixture components are determined as functions of the reduced electric field. The rate constant of the process leading to the formation of exciplex mercury monobromide molecules is found to be 1.6 × 10-14 m3/s for a reduced electric field of E/ N = 15 Td, at which the maximum emission intensity in the blue-green spectral region (λmax = 502 nm) was observed in this experiment.

DFT study of Al doped armchair SWCNTs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhiman, Shobhna, E-mail: s-dhiman@hotmail.com; Rani, Anita; Kumar, Ranjan

2016-05-23

Electronic properties of endohedrally doped armchair single-walled carbon nanotubes (SWCNTs) with a chain of six Al atoms have been studied using ab-initio density functional theory. We investigate the binding energy/atom, ionization potential, electron Affinity and Homo-Lumo gap of doped armchair SWNTs from (4,4) to (6,6) with two ends open. BE/dopant atom and ionization potential is maximum for (6, 6) doped armchair carbon nanotube; suggest that it is more stable than (4, 4) and (5, 5) doped tubes. HOMO - LUMO gap of Al doped arm chair carbon nanotubes decreases linearly with the increase in diameter of the tube. This showsmore » that confinement induce a strong effect on electronic properties of doped tubes. These combined systems can be used for future nano electronics. The ab–initio calculations were performed with SIESTA code using generalized gradient approximation (GGA).« less

Plasma diagnostics of low pressure high power impulse magnetron sputtering assisted by electron cyclotron wave resonance plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stranak, Vitezslav; University of South Bohemia, Institute of Physics and Biophysics, Branisovska 31, 370 05 Ceske Budejovice; Herrendorf, Ann-Pierra

2012-11-01

This paper reports on an investigation of the hybrid pulsed sputtering source based on the combination of electron cyclotron wave resonance (ECWR) inductively coupled plasma and high power impulse magnetron sputtering (HiPIMS) of a Ti target. The plasma source, operated in an Ar atmosphere at a very low pressure of 0.03 Pa, provides plasma where the major fraction of sputtered particles is ionized. It was found that ECWR assistance increases the electron temperature during the HiPIMS pulse. The discharge current and electron density can achieve their stable maximum 10 {mu}s after the onset of the HiPIMS pulse. Further, a highmore » concentration of double charged Ti{sup ++} with energies of up to 160 eV was detected. All of these facts were verified experimentally by time-resolved emission spectroscopy, retarding field analyzer measurement, Langmuir probe, and energy-resolved mass spectrometry.« less

Anomalous resistivity and the origin of heavy mass in the two-band Hubbard model with one narrow band

NASA Astrophysics Data System (ADS)

Kagan, M. Yu.; Val'kov, V. V.

2011-07-01

We search for marginal Fermi-liquid behavior [1] in the two-band Hubbard model with one narrow band. We consider the limit of low electron densities in the bands and strong intraband and interband Hubbard interactions. We analyze the influence of electron polaron effect [2] and other mechanisms of mass enhancement (related to momentum dependence of the self-energies) on the effective mass and scattering times of light and heavy components in the clean case (electron-electron scattering and no impurities). We find the tendency towards phase separation (towards negative partial compressibility of heavy particles) in the 3D case for a large mismatch between the densities of heavy and light bands in the strong-coupling limit. We also observe that for low temperatures and equal densities, the homogeneous state resistivity R( T) ˜ T 2 behaves in a Fermi-liquid fashion in both 3D and 2D cases. For temperatures higher than the effective bandwidth for heavy electrons T > W {*/ h }, the coherent behavior of the heavy component is totally destroyed. The heavy particles move diffusively in the surrounding of light particles. At the same time, the light particles scatter on the heavy ones as if on immobile (static) impurities. In this regime, the heavy component is marginal, while the light one is not. The resistivity saturates for T > W {*/ h } in the 3D case. In 2D, the resistivity has a maximum and a localization tail due to weak-localization corrections of the Altshuler-Aronov type [3]. Such behavior of resistivity could be relevant for some uranium-based heavy-fermion compounds like UNi2Al3 in 3D and for some other mixed-valence compounds possibly including layered manganites in 2D. We also briefly consider the superconductive (SC) instability in the model. The leading instability is towards the p-wave pairing and is governed by the enhanced Kohn-Luttinger [4] mechanism of SC at low electron density. The critical temperature corresponds to the pairing of heavy electrons via polarization of the light ones in 2D.

A comparative study of capacitively coupled HBr/He, HBr/Ar plasmas for etching applications: Numerical investigation by fluid model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gul, Banat, E-mail: banatgul@gmail.com; Research Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Antwerp; Aman-ur-Rehman, E-mail: amansadiq@gmail.com

Fluid model has been applied to perform a comparative study of hydrogen bromide (HBr)/He and HBr/Ar capacitively coupled plasma discharges that are being used for anisotropic etching process. This model has been used to identify the most dominant species in HBr based plasmas. Our simulation results show that the neutral species like H and Br, which are the key player in chemical etching, have bell shape distribution, while ions like HBr{sup +}, Br{sup +}, which play a dominant rule in the physical etching, have double humped distribution and show peaks near electrodes. It was found that the dilution of HBrmore » by Ar and/or He results in an increase in electron density and electron temperature, which results in more ionization and dissociation and hence higher densities of neutral and charged species can be achieved. The ratio of positive ion flux to the neutral flux increases with an increase in additive gas fraction. Compare to HBr/He plasma, the HBr/Ar plasma shows a maximum change in the ion density and flux and hence the etching rate can be considered in the ion-assisted and in the ion-flux etch regime in HBr/Ar discharge. The densities of electron and other dominant species in HBr/Ar plasma are higher than those of HBr/He plasma. The densities and fluxes of the active neutrals and positive ions for etching and subsequently chemical etching versus physical sputtering in HBr/Ar and HBr/He plasmas discharge can be controlled by tuning gas mixture ratio and the desire etching can be achieved.« less

High current density ion beam obtained by a transition to a highly focused state in extremely low-energy region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hirano, Y., E-mail: y.hirano@aist.go.jp, E-mail: hirano.yoichi@phys.cst.nihon-u.ac.jp; College of Science and Technologies, Nihon University, Chiyodaku, Tokyo 101-0897; Kiyama, S.

2015-11-15

A high current density (≈3 mA/cm{sup 2}) hydrogen ion beam source operating in an extremely low-energy region (E{sub ib} ≈ 150–200 eV) has been realized by using a transition to a highly focused state, where the beam is extracted from the ion source chamber through three concave electrodes with nominal focal lengths of ≈350 mm. The transition occurs when the beam energy exceeds a threshold value between 145 and 170 eV. Low-level hysteresis is observed in the transition when E{sub ib} is being reduced. The radial profiles of the ion beam current density and the low temperature ion current densitymore » can be obtained separately using a Faraday cup with a grid in front. The measured profiles confirm that more than a half of the extracted beam ions reaches the target plate with a good focusing profile with a full width at half maximum of ≈3 cm. Estimation of the particle balances in beam ions, the slow ions, and the electrons indicates the possibility that the secondary electron emission from the target plate and electron impact ionization of hydrogen may play roles as particle sources in this extremely low-energy beam after the compensation of beam ion space charge.« less

Isotope effects of trapped electron modes in the presence of impurities in tokamak plasmas

NASA Astrophysics Data System (ADS)

Shen, Yong; Dong, J. Q.; Sun, A. P.; Qu, H. P.; Lu, G. M.; He, Z. X.; He, H. D.; Wang, L. F.

2016-04-01

The trapped electron modes (TEMs) are numerically investigated in toroidal magnetized hydrogen, deuterium and tritium plasmas, taking into account the effects of impurity ions such as carbon, oxygen, helium, tungsten and others with positive and negative density gradients with the rigorous integral eigenmode equation. The effects of impurity ions on TEMs are investigated in detail. It is shown that impurity ions have substantially-destabilizing (stabilizing) effects on TEMs in isotope plasmas for {{L}ez}\\equiv {{L}ne}/{{L}nz}>0 (<0 ), opposite to the case of ion temperature gradient (ITG) driven modes. Detailed analyses of the isotope mass dependence for TEM turbulences in hydrogenic isotope plasmas with and without impurities are performed. The relations between the maximum growth rate of the TEMs with respect to the poloidal wave number and the ion mass number are given in the presence of the impurity ions. The results demonstrate that the maximum growth rates scale as {γ\\max}\\propto Mi-0.5 in pure hydrogenic plasmas. The scale depends on the sign of its density gradient and charge number when there is a second species of (impurity) ions. When impurity ions have density profiles peaking inwardly (i.e. {{L}ez}\\equiv {{L}ne}/{{L}nz}>0 ), the scaling also depends on ITG parameter {ηi} . The maximum growth rates scale as {γ\\max}\\propto M\\text{eff}-0.5 for the case without ITG ({ηi}=0 ) or the ITG parameter is positive ({ηi}>0 ) but the impurity ion charge number is low (Z≤slant 5.0 ). However, when {ηi}>0 and the impurity ion charge number is moderate (Z=6.0-8.0 ), the scaling law is found as {γ\\max}\\propto M\\text{eff}-1.0 . Here, Z is impurity ion charge number, and the effective mass number, {{M}\\text{eff}}=≤ft(1-{{f}z}\\right){{M}i}+{{f}z}{{M}z} , with {{M}i} and {{M}Z} being the mass numbers of the hydrogenic and impurity ions, respectively, and {{f}z}=Z{{n}0z}/{{n}0e} being the charge concentration of impurity ions. In addition, with regard to the case of {{L}ez}<0 , the maximum growth rate scaling is {γ\\max}\\propto Mi-0.5 . The possible relations of the results with experimental observations are discussed.

Determination of Charge-Carrier Mobility in Disordered Thin-Film Solar Cells as a Function of Current Density

NASA Astrophysics Data System (ADS)

Mäckel, Helmut; MacKenzie, Roderick C. I.

2018-03-01

Charge-carrier mobility is a fundamental material parameter, which plays an important role in determining solar-cell efficiency. The higher the mobility, the less time a charge carrier will spend in a device and the less likely it is that it will be lost to recombination. Despite the importance of this physical property, it is notoriously difficult to measure accurately in disordered thin-film solar cells under operating conditions. We, therefore, investigate a method previously proposed in the literature for the determination of mobility as a function of current density. The method is based on a simple analytical model that relates the mobility to carrier density and transport resistance. By revising the theoretical background of the method, we clearly demonstrate what type of mobility can be extracted (constant mobility or effective mobility of electrons and holes). We generalize the method to any combination of measurements that is able to determine the mean electron and hole carrier density, and the transport resistance at a given current density. We explore the robustness of the method by simulating typical organic solar-cell structures with a variety of physical properties, including unbalanced mobilities, unbalanced carrier densities, and for high or low carrier trapping rates. The simulations reveal that near VOC and JSC , the method fails due to the limitation of determining the transport resistance. However, away from these regions (and, importantly, around the maximum power point), the method can accurately determine charge-carrier mobility. In the presence of strong carrier trapping, the method overestimates the effective mobility due to an underestimation of the carrier density.

Influence of irradiation conditions on plasma evolution in laser-surface interaction

NASA Astrophysics Data System (ADS)

Hermann, J.; Boulmer-Leborgne, C.; Dubreuil, B.; Mihailescu, I. N.

1993-09-01

The plasma plume induced by pulsed CO2 laser irradiation of a Ti target at power densities up to 4×108 W cm-2 was studied by emission spectroscopy. Time- and space-resolved measurements were performed by varying laser intensity, laser temporal pulse shape, ambient gas pressure, and the nature of the ambient gas. Experimental results are discussed by comparison with usual models. We show that shock wave and plasma propagation depend critically on the ratio Ivap/Ii, Ivap being the intensity threshold for surface vaporization and Ii the plasma ignition threshold of the ambient gas. Spectroscopic diagnostics of the helium breakdown plasma show maximum values of electron temperature and electron density in the order of kTe˜10 eV and ne=1018 cm-3, respectively. The plasma cannot be described by local thermodynamic equilibrium modeling. Nevertheless, excited metal atoms appear to be in equilibrium with electrons, hence, they can be used like a probe to measure the electron temperature. In order to get information on the role of the plasma in the laser-surface interaction, Ti surfaces were investigated by microscopy after irradiation. Thus an enhanced momentum transfer from the plasma to the target due to the recoil pressure of the breakdown plasma could be evidenced.

Detection and modeling of the acoustic perturbation produced by the launch of the Space Shuttle using the Global Positioning System

NASA Astrophysics Data System (ADS)

Bowling, T. J.; Calais, E.; Dautermann, T.

2010-12-01

Rocket launches are known to produce infrasonic pressure waves that propagate into the ionosphere where coupling between electrons and neutral particles induces fluctuations in ionospheric electron density observable in GPS measurements. We have detected ionospheric perturbations following the launch of space shuttle Atlantis on 11 May 2009 using an array of continually operating GPS stations across the Southeastern coast of the United States and in the Caribbean. Detections are prominent to the south of the westward shuttle trajectory in the area of maximum coupling between the acoustic wave and Earth’s magnetic field, move at speeds consistent with the speed of sound, and show coherency between stations covering a large geographic range. We model the perturbation as an explosive source located at the point of closest approach between the shuttle path and each sub-ionospheric point. The neutral pressure wave is propagated using ray tracing, resultant changes in electron density are calculated at points of intersection between rays and satellite-to-reciever line-of-sight, and synthetic integrated electron content values are derived. Arrival times of the observed and synthesized waveforms match closely, with discrepancies related to errors in the apriori sound speed model used for ray tracing. Current work includes the estimation of source location and energy.

Method for local temperature measurement in a nanoreactor for in situ high-resolution electron microscopy.

PubMed

Vendelbo, S B; Kooyman, P J; Creemer, J F; Morana, B; Mele, L; Dona, P; Nelissen, B J; Helveg, S

2013-10-01

In situ high-resolution transmission electron microscopy (TEM) of solids under reactive gas conditions can be facilitated by microelectromechanical system devices called nanoreactors. These nanoreactors are windowed cells containing nanoliter volumes of gas at ambient pressures and elevated temperatures. However, due to the high spatial confinement of the reaction environment, traditional methods for measuring process parameters, such as the local temperature, are difficult to apply. To address this issue, we devise an electron energy loss spectroscopy (EELS) method that probes the local temperature of the reaction volume under inspection by the electron beam. The local gas density, as measured using quantitative EELS, is combined with the inherent relation between gas density and temperature, as described by the ideal gas law, to obtain the local temperature. Using this method we determined the temperature gradient in a nanoreactor in situ, while the average, global temperature was monitored by a traditional measurement of the electrical resistivity of the heater. The local gas temperatures had a maximum of 56 °C deviation from the global heater values under the applied conditions. The local temperatures, obtained with the proposed method, are in good agreement with predictions from an analytical model. Copyright © 2013 Elsevier B.V. All rights reserved.

Sodankylä ionospheric tomography dataset 2003-2014

NASA Astrophysics Data System (ADS)

Norberg, J.; Roininen, L.; Kero, A.; Raita, T.; Ulich, T.; Markkanen, M.; Juusola, L.; Kauristie, K.

2015-12-01

Sodankylä Geophysical Observatory has been operating a tomographic receiver network and collecting the produced data since 2003. The collected dataset consists of phase difference curves measured from Russian COSMOS dual-frequency (150/400 MHz) low-Earth-orbit satellite signals, and tomographic electron density reconstructions obtained from these measurements. In this study vertical total electron content (VTEC) values are integrated from the reconstructed electron densities to make a qualitative and quantitative analysis to validate the long-term performance of the tomographic system. During the observation period, 2003-2014, there were three-to-five operational stations at the Fenno-Scandinavian sector. Altogether the analysis consists of around 66 000 overflights, but to ensure the quality of the reconstructions, the examination is limited to cases with descending (north to south) overflights and maximum elevation over 60°. These constraints limit the number of overflights to around 10 000. Based on this dataset, one solar cycle of ionospheric vertical total electron content estimates is constructed. The measurements are compared against International Reference Ionosphere IRI-2012 model, F10.7 solar flux index and sunspot number data. Qualitatively the tomographic VTEC estimate corresponds to reference data very well, but the IRI-2012 model are on average 40 % higher of that of the tomographic results.

Geometrical, electronic, and magnetic properties of CunFe (n=1-12) clusters: A density functional study

NASA Astrophysics Data System (ADS)

Ling, Wang; Dong, Die; Shi-Jian, Wang; Zheng-Quan, Zhao

2015-01-01

The geometrical, electronic, and magnetic properties of small CunFe (n=1-12) clusters have been investigated by using density functional method B3LYP and LanL2DZ basis set. The structural search reveals that Fe atoms in low-energy CunFe isomers tend to occupy the position with the maximum coordination number. The ground state CunFe clusters possess planar structure for n=2-5 and three-dimensional (3D) structure for n=6-12. The electronic properties of CunFe clusters are analyzed through the averaged binding energy, the second-order energy difference and HOMO-LUMO energy gap. It is found that the magic numbers of stability are 1, 3, 7 and 9 for the ground state CunFe clusters. The energy gap of Fe-encapsulated cage clusters is smaller than that of other configurations. The Cu5Fe and Cu7Fe clusters have a very large energy gap (>2.4 eV). The vertical ionization potential (VIP), electron affinity (EA) and photoelectron spectra are also calculated and simulated theoretically for all the ground-state clusters. The magnetic moment analyses for the ground-state CunFe clusters show that Fe atom can enhance the magnetic moment of the host cluster and carries most of the total magnetic moment.

Dependence of electron beam instability growth rates on the beam-plasma system parameters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strangeway, R.J.

1982-02-01

Electron beam instabilites are studied by using a simple model for an electron beam streaming through a cold plasma, the beam being of finite width perpendicular to the ambient magnetic field. Through considerations of finite geometry and the coldness of the beam and background plasma, an instability similar to the two stream instability is assumed to be the means for wave growth in the system. Having found the maximum growth rate for one set of beam-plasma system parameters, this maximum growth rate is traced as these parameters are varied. The parameters that describe the system are the beam velocity (v/submore » b/), electron gyrofrequency to ambient electron plasma frequency ratio (..cap omega../sub e//..omega../sub p/e), the beam to background number density ratio (n/sub b//n/sub a/), and the beam width (a). When ..cap omega../sub e//..omega../sub p/e>1, a mode with ..cap omega../sub e/<..omega..<..omega../sub u/hr is found to be unstable, where ..cap omega.. is the wave frequency and ..omega../sub u/hr is the upper hybrid resonance frequency. For low values of n/sub b//n/sub a/ and ..cap omega../sub e/<..omega../sub p/e, this mode is still present with ..omega../sub p/e<..omega..<..omega../sub u/hr. If the beam density is large, n/sub b//n/sub a/approx. =1, the instability occures for frequencies just above the electron gyrofrequency. This mode may well be that observed in laboratory plasma before the system undergoes the beam-plasma discharge. There is another instability present, which occurs for ..omega..approx. =..omega../sub p/e. The growth rates for this mode, which are generally larger than those found for the ..omega..approx. =..omega..uhr mode, are only weakly dependent on ..cap omega../sub d//..omega../sub p/e. That this mode is not always observed in the laboratory implies that some factors not considered in the present theory suppress this mode, specifically, finite beam length.« less

Estimation of Reineke and Volume-Based Maximum Size-Density Lines For Shortleaf Pine

Treesearch

Thomas B. Lynch; Robert F. Wittwer; Douglas J. Stevenson

2004-01-01

Maximum size-density relationships for Reineke's stand density index as well as for a relationship based on average tree volume were fitted to data from more than a decade of annual remeasurements of plots in unthinned naturally occurring shor tleaf pine in southeaster n Oklahoma. Reineke's stand density index is based on a maximum line of the form log(N) = a...

A PIC-MCC code RFdinity1d for simulation of discharge initiation by ICRF antenna

NASA Astrophysics Data System (ADS)

Tripský, M.; Wauters, T.; Lyssoivan, A.; Bobkov, V.; Schneider, P. A.; Stepanov, I.; Douai, D.; Van Eester, D.; Noterdaeme, J.-M.; Van Schoor, M.; ASDEX Upgrade Team; EUROfusion MST1 Team

2017-12-01

Discharges produced and sustained by ion cyclotron range of frequency (ICRF) waves in absence of plasma current will be used on ITER for (ion cyclotron-) wall conditioning (ICWC, Te = 3{-}5 eV, ne < 1018 m-3 ). In this paper, we present the 1D particle-in-cell Monte Carlo collision (PIC-MCC) RFdinity1d for the study the breakdown phase of ICRF discharges, and its dependency on the RF discharge parameters (i) antenna input power P i , (ii) RF frequency f, (iii) shape of the electric field and (iv) the neutral gas pressure pH_2 . The code traces the motion of both electrons and ions in a narrow bundle of magnetic field lines close to the antenna straps. The charged particles are accelerated in the parallel direction with respect to the magnetic field B T by two electric fields: (i) the vacuum RF field of the ICRF antenna E_z^RF and (ii) the electrostatic field E_zP determined by the solution of Poisson’s equation. The electron density evolution in simulations follows exponential increase, {\\dot{n_e} ∼ ν_ion t } . The ionization rate varies with increasing electron density as different mechanisms become important. The charged particles are affected solely by the antenna RF field E_z^RF at low electron density ({ne < 1011} m-3 , {≤ft \\vert E_z^RF \\right \\vert \\gg ≤ft \\vert E_zP \\right \\vert } ). At higher densities, when the electrostatic field E_zP is comparable to the antenna RF field E_z^RF , the ionization frequency reaches the maximum. Plasma oscillations propagating toroidally away from the antenna are observed. The simulated energy distributions of ions and electrons at {ne ∼ 1015} m-3 correspond a power-law Kappa energy distribution. This energy distribution was also observed in NPA measurements at ASDEX Upgrade in ICWC experiments.

Comparative ionospheres: Terrestrial and giant planets

NASA Astrophysics Data System (ADS)

Mendillo, Michael; Trovato, Jeffrey; Moore, Luke; Müller-Wodarg, Ingo

2018-03-01

The study of planetary ionospheres within our solar system offers a variety of settings to probe mechanisms of photo-ionization, chemical loss, and plasma transport. Ionospheres are a minor component of upper atmospheres, and thus their mix of ions observed depends on the neutral gas composition of their parent atmospheres. The same solar irradiance (x-rays and extreme-ultra-violet vs. wavelength) impinges upon each of these atmospheres, with solar flux magnitudes changed only by the inverse square of distance from the Sun. If all planets had the same neutral atmosphere-with ionospheres governed by photochemical equilibrium (production = loss)-their peak electron densities would decrease as the inverse of distance from the Sun, and any changes in solar output would exhibit coherent effects throughout the solar system. Here we examine the outer planet with the most observations of its ionosphere (Saturn) and compare its patterns of electron density with those at Earth under the same-day solar conditions. We show that, while the average magnitudes of the major layers of molecular ions at Earth and Saturn are approximately in accord with distance effects, only minor correlations exist between solar effects and day-to-day electron densities. This is in marked contrast to the strong correlations found between the ionospheres of Earth and Mars. Moreover, the variability observed for Saturn's ionosphere (maximum electron density and total electron content) is much larger than found at Earth and Mars. With solar irradiance changes far too small to cause such effects, we use model results to explore the roles of other agents. We find that water sources from Enceladus at low latitudes, and 'ring rain' at middle latitudes, contribute substantially to variability via water ion chemistry. Thermospheric winds and electrodynamics generated at auroral latitudes are suggested causes of high latitude ionospheric variability, but remain inconclusive due to the lack of relevant observations.

Dense electron-positron plasmas and ultraintense γ rays from laser-irradiated solids.

PubMed

Ridgers, C P; Brady, C S; Duclous, R; Kirk, J G; Bennett, K; Arber, T D; Robinson, A P L; Bell, A R

2012-04-20

In simulations of a 10 PW laser striking a solid, we demonstrate the possibility of producing a pure electron-positron plasma by the same processes as those thought to operate in high-energy astrophysical environments. A maximum positron density of 10(26) m(-3) can be achieved, 7 orders of magnitude greater than achieved in previous experiments. Additionally, 35% of the laser energy is converted to a burst of γ rays of intensity 10(22) W cm(-2), potentially the most intense γ-ray source available in the laboratory. This absorption results in a strong feedback between both pair and γ-ray production and classical plasma physics in the new "QED-plasma" regime.

Simple-to-Complex Transformation in Liquid Rubidium.

PubMed

Gorelli, Federico A; De Panfilis, Simone; Bryk, Taras; Ulivi, Lorenzo; Garbarino, Gaston; Parisiades, Paraskevas; Santoro, Mario

2018-05-18

We investigated the atomic structure of liquid Rb along an isothermal path at 573 K, up to 23 GPa, by X-ray diffraction measurements. By raising the pressure, we observed a liquid-liquid transformation from a simple metallic liquid to a complex one. The transition occurs at 7.5 ± 1 GPa which is slightly above the first maximum of the T-P melting line. This transformation is traced back to the density-induced hybridization of highest electronic orbitals leading to the accumulation of valence electrons between Rb atoms and to the formation of interstitial atomic shells, a behavior that Rb shares with Cs and is likely to be common to all alkali metals.

Numerical simulation of laser ion acceleration at ultra high intensity

NASA Astrophysics Data System (ADS)

Tatomirescu, Dragos; Popescu, Alexandra; d'Humières, Emmanuel; Vizman, Daniel

2017-01-01

With the latest advances in attainable laser intensity, the need to obtain better quality ion and electron beams has been a major field of research. This paper studies the effects of different target density profiles on the spatial distribution of the accelerated particles, the maximum energies achieved, and the characteristics of the electromagnetic fields using the same laser pulse parameters. The study starts by describing a baseline for a flat target which presents a proton-rich microdot on its backside. The effects of introducing a target curvature and, further on, a cone laser focusing structure are compared with the flat target baseline results. The maximum energy obtained increases when using complex structures, and also a smaller divergence of the ion beam is observed.

Exploring the formation and electronic structure properties of the g-C3N4 nanoribbon with density functional theory

NASA Astrophysics Data System (ADS)

Wu, Hong-Zhang; Zhong, Qing-Hua; Bandaru, Sateesh; Liu, Jin; Lau, Woon Ming; Li, Li-Li; Wang, Zhenling

2018-04-01

The optical properties and condensation degree (structure) of polymeric g-C3N4 depend strongly on the process temperature. For polymeric g-C3N4, its structure and condensation degree depend on the structure of molecular strand(s). Here, the formation and electronic structure properties of the g-C3N4 nanoribbon are investigated by studying the polymerization and crystallinity of molecular strand(s) employing first-principle density functional theory. The calculations show that the width of the molecular strand has a significant effect on the electronic structure of polymerized and crystallized g-C3N4 nanoribbons, a conclusion which would be indirect evidence that the electronic structure depends on the structure of g-C3N4. The edge shape also has a distinct effect on the electronic structure of the crystallized g-C3N4 nanoribbon. Furthermore, the conductive band minimum and valence band maximum of the polymeric g-C3N4 nanoribbon show a strong localization, which is in good agreement with the quasi-monomer characters. In addition, molecular strands prefer to grow along the planar direction on graphene. These results provide new insight on the properties of the g-C3N4 nanoribbon and the relationship between the structure and properties of g-C3N4.

Exploring the formation and electronic structure properties of the g-C3N4 nanoribbon with density functional theory.

PubMed

Wu, Hong-Zhang; Zhong, Qing-Hua; Bandaru, Sateesh; Liu, Jin; Lau, Woon Ming; Li, Li-Li; Wang, Zhenling

2018-04-18

The optical properties and condensation degree (structure) of polymeric g-C 3 N 4 depend strongly on the process temperature. For polymeric g-C 3 N 4 , its structure and condensation degree depend on the structure of molecular strand(s). Here, the formation and electronic structure properties of the g-C 3 N 4 nanoribbon are investigated by studying the polymerization and crystallinity of molecular strand(s) employing first-principle density functional theory. The calculations show that the width of the molecular strand has a significant effect on the electronic structure of polymerized and crystallized g-C 3 N 4 nanoribbons, a conclusion which would be indirect evidence that the electronic structure depends on the structure of g-C 3 N 4 . The edge shape also has a distinct effect on the electronic structure of the crystallized g-C 3 N 4 nanoribbon. Furthermore, the conductive band minimum and valence band maximum of the polymeric g-C 3 N 4 nanoribbon show a strong localization, which is in good agreement with the quasi-monomer characters. In addition, molecular strands prefer to grow along the planar direction on graphene. These results provide new insight on the properties of the g-C 3 N 4 nanoribbon and the relationship between the structure and properties of g-C 3 N 4 .

Surface Modified Pinecone Shaped Hierarchical Structure Fluorinated Mesocarbon Microbeads for Ultrafast Discharge and Improved Electrochemical Performances

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, Yang; Fang, Yuan; Cai, Sendan

2016-12-01

Among all primary lithium batteries, Li/CF x primary battery possesses the highest energy density of 2180 Wh kg -1. However, a key limitation is its poor rate capability because the cathode material CF x is intrinsically a poor electronic conductor. Here, we developed a so-called “doing subtraction” method to modify the pinecone shaped fluorinated mesocarbon microbead (F-MCMB). The modified fluorinated mesocarbon microbead (MF-MCMB), manifests the advantage of open-framed structure, possesses good electronic conductivity and removes transport barrier for lithium ions. Thus, high capacity performance and excellent rate capability without compromising capacity can be obtained. A capacity of 343 mAhg -1more » and a maximum power density of 54600 W kg -1 are realized at an ultrafast rate of 40 C (28A g -1). Additionally, the MF-MCMB cathode does not show any voltage delay even at 5C during the discharge, which is a remarkable improvement over the state-of-the-art CF xmaterials.« less

IRI STORM validation over Europe

NASA Astrophysics Data System (ADS)

Haralambous, Haris; Vryonides, Photos; Demetrescu, Crişan; Dobrică, Venera; Maris, Georgeta; Ionescu, Diana

2014-05-01

The International Reference Ionosphere (IRI) model includes an empirical Storm-Time Ionospheric Correction Model (STORM) extension to account for storm-time changes of the F layer peak electron density (NmF2) during increased geomagnetic activity. This model extension is driven by past history values of the geomagnetic index ap (The magnetic index applied is the integral of ap over the previous 33 hours with a weighting function deduced from physically based modeling) and it adjusts the quiet-time F layer peak electron density (NmF2) to account for storm-time changes in the ionosphere. In this investigation manually scaled hourly values of NmF2 measured during the main and recovery phases of selected storms for the maximum solar activity period of the current solar cycle are compared with the predicted IRI-2012 NmF2 over European ionospheric stations using the STORM model option. Based on the comparison a subsequent performance evaluation of the STORM option during this period is quantified.

Shock-Compressed Hydrogen

NASA Astrophysics Data System (ADS)

Bickham, S. R.; Collins, L. A.; Kress, J. D.; Lenosky, T. J.

1999-06-01

To investigate recent gas-gun and laser experiments on hydrogen at elevated temperatures and high densities, we have performed quantum molecular dynamics simulations using a variety of sophisticated models, ranging from tight-binding(TB) to density functional(DF)(T.J. Lenosky, J.D. Kress, L.A. Collins, and I. Kwon Phys. Rev. B 55), R11907(1997) and references therein.. The TB models have been especially tailored to reproduce experimental findings, such as Diamond-Anvil Cell data, and ab initio calculations, such as H_2, H_3, and H4 potential energy surfaces. The DF calculations have employed the local-density approximation(LDA) as well as generalized gradient corrections(GGA) with large numbers of plane-waves ( ~10^5) that represent a very broad range of excited and continuum electronic states. Good agreement obtains among all these models. The simulations exhibit a rapidly rising electrical conductivity at low temperatures and high pressures in good agreement with the gas-gun results. This conduction property stems from a mobility of the electrons provided principally by the dissociated monomers. The Hugoniot for the conditions of the laser experiment, generated from the TB Equation-of-State, shows a maximum compression of around four instead of the observed six. We also report optical properties of the hydrogen media.

Statistical density modification using local pattern matching

DOEpatents

Terwilliger, Thomas C.

2007-01-23

A computer implemented method modifies an experimental electron density map. A set of selected known experimental and model electron density maps is provided and standard templates of electron density are created from the selected experimental and model electron density maps by clustering and averaging values of electron density in a spherical region about each point in a grid that defines each selected known experimental and model electron density maps. Histograms are also created from the selected experimental and model electron density maps that relate the value of electron density at the center of each of the spherical regions to a correlation coefficient of a density surrounding each corresponding grid point in each one of the standard templates. The standard templates and the histograms are applied to grid points on the experimental electron density map to form new estimates of electron density at each grid point in the experimental electron density map.

Low-pressure hydrogen discharge maintenance in a large-size plasma source with localized high radio-frequency power deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Todorov, D.; Shivarova, A., E-mail: ashiva@phys.uni-sofia.bg; Paunska, Ts.

2015-03-15

The development of the two-dimensional fluid-plasma model of a low-pressure hydrogen discharge, presented in the study, is regarding description of the plasma maintenance in a discharge vessel with the configuration of the SPIDER source. The SPIDER source, planned for the neutral-beam-injection plasma-heating system of ITER, is with localized high RF power deposition to its eight drivers (cylindrical-coil inductive discharges) and a large-area second chamber, common for all the drivers. The continuity equations for the charged particles (electrons and the three types of positive ions) and for the neutral species (atoms and molecules), their momentum equations, the energy balance equations formore » electrons, atoms and molecules and the Poisson equations are involved in the discharge description. In addition to the local processes in the plasma volume, the surface processes of particle reflection and conversion on the walls as well as for a heat exchange with the walls are included in the model. The analysis of the results stresses on the role of the fluxes (particle and energy fluxes) in the formation of the discharge structure. The conclusion is that the discharge behavior is completely obeyed to non-locality. The latter is displayed by: (i) maximum values of plasma parameters (charged particle densities and temperatures of the neutral species) outside the region of the RF power deposition, (ii) shifted maxima of the electron density and temperature, of the plasma potential and of the electron production, (iii) an electron flux, with a vortex structure, strongly exceeding the total ion flux which gives evidence of a discharge regime of non-ambipolarity and (iv) a spatial distribution of the densities of the neutral species resulting from their fluxes.« less

Improvement of GPS radio occultation retrieval error of E region electron density: COSMIC measurement and IRI model simulation

NASA Astrophysics Data System (ADS)

Wu, Kang-Hung; Su, Ching-Lun; Chu, Yen-Hsyang

2015-03-01

In this article, we use the International Reference Ionosphere (IRI) model to simulate temporal and spatial distributions of global E region electron densities retrieved by the FORMOSAT-3/COSMIC satellites by means of GPS radio occultation (RO) technique. Despite regional discrepancies in the magnitudes of the E region electron density, the IRI model simulations can, on the whole, describe the COSMIC measurements in quality and quantity. On the basis of global ionosonde network and the IRI model, the retrieval errors of the global COSMIC-measured E region peak electron density (NmE) from July 2006 to July 2011 are examined and simulated. The COSMIC measurement and the IRI model simulation both reveal that the magnitudes of the percentage error (PE) and root mean-square-error (RMSE) of the relative RO retrieval errors of the NmE values are dependent on local time (LT) and geomagnetic latitude, with minimum in the early morning and at high latitudes and maximum in the afternoon and at middle latitudes. In addition, the seasonal variation of PE and RMSE values seems to be latitude dependent. After removing the IRI model-simulated GPS RO retrieval errors from the original COSMIC measurements, the average values of the annual and monthly mean percentage errors of the RO retrieval errors of the COSMIC-measured E region electron density are, respectively, substantially reduced by a factor of about 2.95 and 3.35, and the corresponding root-mean-square errors show averaged decreases of 15.6% and 15.4%, respectively. It is found that, with this process, the largest reduction in the PE and RMSE of the COSMIC-measured NmE occurs at the equatorial anomaly latitudes 10°N-30°N in the afternoon from 14 to 18 LT, with a factor of 25 and 2, respectively. Statistics show that the residual errors that remained in the corrected COSMIC-measured NmE vary in a range of -20% to 38%, which are comparable to or larger than the percentage errors of the IRI-predicted NmE fluctuating in a range of -6.5% to 20%.

Photo-electrochemical communication between cyanobacteria (Leptolyngbia sp.) and osmium redox polymer modified electrodes.

PubMed

Hasan, Kamrul; Bekir Yildiz, Huseyin; Sperling, Eva; Conghaile, Peter Ó; Packer, Michael A; Leech, Dónal; Hägerhäll, Cecilia; Gorton, Lo

2014-12-07

Photosynthetic microbial fuel cells (PMFCs) are an emerging technology for renewable solar energy conversion. Major efforts have been made to explore the electrogenic activity of cyanobacteria, mostly using practically unsustainable reagents. Here we report on photocurrent generation (≈8.64 μA cm(-2)) from cyanobacteria immobilized on electrodes modified with an efficient electron mediator, an Os(2+/3+) redox polymer. Upon addition of ferricyanide to the electrolyte, cyanobacteria generate the maximum current density of ≈48.2 μA cm(-2).

New Materials Developments for Military High Power Electronics and Capacitors

DTIC Science & Technology

2009-04-27

parameters, permittivity and breakdown field strength, and can be given by equation 1. (1) Where U - energy density (J/ cm3), ε - relative material... permittivity εo - permittivity of free space (8.85418782 × 10-12 m-3 kg-1 s4 A2) Emax (V/µm) - maximum field strength before material breakdown... Permittivity can be described as the ability of the material to polar- ize in response to an electric field through separation of ions, twist- ing permanent

UV Emissions and the Electron Density in the Auroral and Low to Mid-Latitude Daytime Ionospheres.

DTIC Science & Technology

1982-11-01

Anderson, 1982). Their concern has been with the analysis of satellite observed limb profiles for features such as 01 1356 A and N2 LBH bands. We have...two in going from solar minimum to maximum conditions. An ad- vantage of there being little relative variation among intensities is that altitude...desirable for our problem of interest since it concerns remote sensing of the ionosphere. The questions ariser as to how long the wavelength of I

LASER APPLICATIONS AND OTHER TOPICS IN QUANTUM ELECTRONICS: Study of a volume discharge in inert-gas halides without preionisation

NASA Astrophysics Data System (ADS)

Erofeev, M. V.; Tarasenko, V. F.

2008-04-01

The energy characteristics of radiation of halides of inert gases excited by a volume discharge without additional preionisation are studied. The pressures of working mixtures and relations between the inert gas and halogen optimal for obtaining the maximum pulsed power and radiation efficiency are determined. The peak UV radiation power density achieved 5 kW cm-2 and the radiation efficiency was ≈5.5%. The pulse FWHM was 30—40 ns.

Experimental observation of charge-shift bond in fluorite CaF2.

PubMed

Stachowicz, Marcin; Malinska, Maura; Parafiniuk, Jan; Woźniak, Krzysztof

2017-08-01

On the basis of a multipole refinement of single-crystal X-ray diffraction data collected using an Ag source at 90 K to a resolution of 1.63 Å -1 , a quantitative experimental charge density distribution has been obtained for fluorite (CaF 2 ). The atoms-in-molecules integrated experimental charges for Ca 2+ and F - ions are +1.40 e and -0.70 e, respectively. The derived electron-density distribution, maximum electron-density paths, interaction lines and bond critical points along Ca 2+ ...F - and F - ...F - contacts revealed the character of these interactions. The Ca 2+ ...F - interaction is clearly a closed shell and ionic in character. However, the F - ...F - interaction has properties associated with the recently recognized type of interaction referred to as `charge-shift' bonding. This conclusion is supported by the topology of the electron localization function and analysis of the quantum theory of atoms in molecules and crystals topological parameters. The Ca 2+ ...F - bonded radii - measured as distances from the centre of the ion to the critical point - are 1.21 Å for the Ca 2+ cation and 1.15 Å for the F - anion. These values are in a good agreement with the corresponding Shannon ionic radii. The F - ...F - bond path and bond critical point is also found in the CaF 2 crystal structure. According to the quantum theory of atoms in molecules and crystals, this interaction is attractive in character. This is additionally supported by the topology of non-covalent interactions based on the reduced density gradient.

SPE-LEEM Studies on the Surface and Electronic Structure of 2-D Transition Metal Dichalcogenides

NASA Astrophysics Data System (ADS)

Yeh, Po-Chun; Jin, Wencan; Zaki, Nader; Zhang, Datong; Sadowski, Jerzy; Al-Mahboob, Abdullah; van de Zande, Arend; Chenet, Daniel; Dadap, Jerry; Herman, Irving; Sutter, Petter; Hone, James; Osgood, Richard

2014-03-01

In this work, we studied the surface and electronic structure of monolayer and few-layer exfoliated MoS2 and WSe2, as well as chemical-vapor-deposition (CVD) grown MoS2, using Spectroscopic Photoemission and Low Energy Electron Microscope (SPE-LEEM). LEEM measurements reveal that, unlike exfoliated MoS2, CVD-grown MoS2 exhibits grain-boundary alterations due to surface strain. However, LEEM and micro-probe low energy electron diffraction show that the quality of CVD-grown MoS2 is comparable to that of exfoliated MoS2. Micrometer-scale angle-resolved photoemission spectroscopy (ARPES) measurement on exfoliated MoS2 and WSe2 single-crystals provides direct evidence for the shifting of the valence band maximum from Γ to K, when the layer number is thinned down to one, as predicted by density functional theory. Our measurements of the k-space resolved electronic structure allow for further comparison with other theoretical predictions and with transport measurements. Session I and II

Electron affinities and ionization energies of Cu and Ag delafossite compounds: A hybrid functional study

NASA Astrophysics Data System (ADS)

Miao, Mao-Sheng; Yarbro, Sam; Barton, Phillip T.; Seshadri, Ram

2014-01-01

Using density functional theory with a hybrid functional, we calculate the ionization energies and electron affinities of a series of delafossite compounds (AMO2: A =Cu, Ag; M =B, Al, Ga, In, Sc). The alignments of the valence band maximum and the conduction band minimum, which directly relate to the ionization energies and electron affinities, were obtained by calculations of supercell slab models constructed in a nonpolar orientation. Our calculations reveal that the ionization energy decreases with an increasing atomic number of group-III elements, and thus suggest an improved p-type doping propensity for heavier compounds. For keeping both a low ionization energy and a band gap of sufficient size, CuScO2 is superior to the Cu-based group-III delafossites. By analyzing the electronic structures, we demonstrate that the compositional trend of the ionization energies and electron affinities is the result of a combined effect of d-band broadening due to Cu(Ag)-Cu(Ag) coupling and a repositioning of the d-band center.

Electronic and optical properties of graphene-like InAs: An ab initio study

NASA Astrophysics Data System (ADS)

Sohrabi, Leila; Boochani, Arash; Ali Sebt, S.; Mohammad Elahi, S.

2018-03-01

The present work initially investigates structural, optical, and electronic properties of graphene-like InAs by using the full potential linear augmented plane wave method in the framework of density functional theory and is then compared with the bulk Indium Arsenide in the wurtzite phase. The lattice parameters are optimized with GGA-PBE and LDA approximations for both 2D- and 3D-InAs. In order to study the electronic properties of graphene-like InAs and bulk InAs in the wurtzite phase, the band gap is calculated by GGA-PBG and GGA-EV approximations. Moreover, optical parameters of graphene-like InAs and bulk InAs such as the real and imaginary parts of dielectric function, electron energy loss function, refractivity, extinction and absorption coefficients, and optical conductivity are investigated. Plasmonic frequencies of 2D- and 3D-InAs are also calculated by using maximum electron energy loss function and the roots of the real part of the dielectric function.

Energetic electrons in the midlatitude nighttime E region

NASA Technical Reports Server (NTRS)

Smith, L. G.; Geller, M. A.; Voss, H. D.

1973-01-01

Nike Apache 14.439 was launched from Wallops Island at 0003 EST on 1 November 1972, a very disturbed night (K sub P = 8). A Geiger counter in the payload detected electrons ( keV) with a maximum flux of 1086 + or -261/sq cm/sec/ster. The height-averaged ionization rate in the upper E region is calculated from the measured electron density profile and has a value of 35 1/cu/cm/sec. The ionization rate can be reconciled with the observed flux of electrons ( 70 2 keV) if the spectrum ( keV) is of the form J ( E) = J sub O exp(-E/E sub O) with E sub O equal to 8.3 keV. The ionization rate on this and other nights is found to be strongly dependent on geomagnetic activity. It is suggested that energetic electrons are the principal source of ionization at midlatitudes in the upper E region near midnight, even under rather quiet geomagnetic conditions.

Electronic torsional sound in linear atomic chains: Chemical energy transport at 1000 km/s

NASA Astrophysics Data System (ADS)

Kurnosov, Arkady A.; Rubtsov, Igor V.; Maksymov, Andrii O.; Burin, Alexander L.

2016-07-01

We investigate entirely electronic torsional vibrational modes in linear cumulene chains. The carbon nuclei of a cumulene are positioned along the primary axis so that they can participate only in the transverse and longitudinal motions. However, the interatomic electronic clouds behave as a torsion spring with remarkable torsional stiffness. The collective dynamics of these clouds can be described in terms of electronic vibrational quanta, which we name torsitons. It is shown that the group velocity of the wavepacket of torsitons is much higher than the typical speed of sound, because of the small mass of participating electrons compared to the atomic mass. For the same reason, the maximum energy of the torsitons in cumulenes is as high as a few electronvolts, while the minimum possible energy is evaluated as a few hundred wavenumbers and this minimum is associated with asymmetry of zero point atomic vibrations. Theory predictions are consistent with the time-dependent density functional theory calculations. Molecular systems for experimental evaluation of the predictions are proposed.

Density and beta limits in the Madison Symmetric Torus Reversed-Field Pinch

NASA Astrophysics Data System (ADS)

Caspary, Kyle Jonathan

Operational limits and the underlying physics are explored on the Madison Symmetric Torus (MST) Reversed-Field Pinch (RFP) using deuterium pellet fueling. The injection of a fast pellet provides a large source of fuel in the plasma edge upon impact with the vessel wall, capable of triggering density limit terminations for the full range of plasma current, up to 600 kA. As the pellet size and plasma density increase, approaching the empirical Greenwald limit, plasma degradation is observed in the form of current decay, increased magnetic activity in the edge and core, increased radiation and plasma cooling. The complete termination of the plasma is consistent with the Greenwald limit; however, a slightly smaller maximum density is observed in discharges without toroidal field reversal. The plasma beta is the ratio of the plasma pressure to the confining magnetic pressure. Beta limits are known to constrain other magnetic confinement devices, but no beta limit has yet been established on the RFP. On MST, the highest beta values are obtained in improved confinement discharges with pellet fueling. By using pellet injection to scan the plasma density during PPCD, we also achieve a scan of Ohmic input power due to the increase in plasma resistivity. We observe a factor of 3 or more increase in Ohmic power as we increase the density from 1*1019 to 3*10 19 m-3. Despite this increased Ohmic power, the electron contribution to beta is constant, suggesting a confinement limited beta for the RFP. The electrons and ions are classically well coupled in these cold, dense pellet fueled plasmas, so the increase in total beta at higher density is primarily due to the increased ion contribution. The interaction of pellet fueling and NBI heating is explored. Modeling of MST's neutral heating beam suggests an optimal density for beam power deposition of 2-3*1019 m-3. Low current, NBI heated discharges show evidence of an increased electron beta in this density range. Additionally, the fast ion population can enhance ablation as well as cause pellet deflection. Other exploratory experiments with the pellet injection system explore additional injection scenarios and expand the injector capabilities.

TEM and STEM Studies on the Cross-sectional Morphologies of Dual-/Tri-layer Broadband SiO2 Antireflective Films

NASA Astrophysics Data System (ADS)

Wang, Shuangyue; Yan, Hongwei; Li, Dengji; Qiao, Liang; Han, Shaobo; Yuan, Xiaodong; Liu, Wei; Xiang, Xia; Zu, Xiaotao

2018-02-01

Dual-layer and tri-layer broadband antireflective (AR) films with excellent transmittance were successfully fabricated using base-/acid-catalyzed mixed sols and propylene oxide (PO) modified silica sols. The sols and films were characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), transmission electron microscope (TEM), and scanning transmission electron microscope (STEM). FTIR and TEM results suggest that the PO molecules were covalently bonded to the silica particles and the bridge structure existing in PO modified silica sol is responsible for the low density of the top layer. The density ratio between different layers was measured by cross-sectional STEM, and the results are 1.69:1 and 2.1:1.7:1 from bottom-layer to top-layer for dual-layer and tri-layer films, respectively. The dual-layer film demonstrates good stability with 99.8% at the central wavelength of 351 nm and nearly 99.5% at the central wavelength of 1053 nm in laser system, and for the tri-layer AR film, the maximum transmittance reached nearly 100% at both the central wavelengths of 527 and 1053 nm.

Ensemble Monte Carlo particle investigation of hot electron induced source-drain burnout characteristics of GaAs field-effect transistors

NASA Astrophysics Data System (ADS)

Moglestue, C.; Buot, F. A.; Anderson, W. T.

1995-08-01

The lattice heating rate has been calculated for GaAs field-effect transistors of different source-drain channel design by means of the ensemble Monte Carlo particle model. Transport of carriers in the substrate and the presence of free surface charges are also included in our simulation. The actual heat generation was obtained by accounting for the energy exchanged with the lattice of the semiconductor during phonon scattering. It was found that the maximum heating rate takes place below the surface near the drain end of the gate. The results correlate well with a previous hydrodynamic energy transport estimate of the electronic energy density, but shifted slightly more towards the drain. These results further emphasize the adverse effects of hot electrons on the Ohmic contacts.

Electronic and optical properties of antiferromagnetic iron doped NiO - A first principles study

NASA Astrophysics Data System (ADS)

Petersen, John E.; Twagirayezu, Fidele; Scolfaro, Luisa M.; Borges, Pablo D.; Geerts, Wilhelmus J.

2017-05-01

Antiferromagnetic NiO is a candidate for next generation high-speed and scaled RRAM devices. Here, electronic and optical properties of antiferromagnetic NiO: Fe 25% in the rock salt structure are studied and compared to intrinsic NiO. From density of states and complex dielectric function analysis, the first optical transition is found to be at lower frequency than intrinsic NiO due to an Fe impurity level being the valence band maximum. The resulting effects on refractive index, reflectivity, absorption, optical conductivity and loss function for Fe-doped NiO are compared to those of intrinsic NiO, and notable differences are analyzed. The electronic component of the static dielectric constant of NiO: Fe 25% is calculated to be about 2% less than that of intrinsic NiO.

First-principles equation of state and shock compression predictions of warm dense hydrocarbons

DOE PAGES

Zhang, Shuai; Driver, Kevin P.; Soubiran, Francois; ...

2017-07-10

We use path integral Monte Carlo and density functional molecular dynamics to construct a coherent set of equations of state (EOS) for a series of hydrocarbon materials with various C:H ratios (2:1, 1:1, 2:3, 1:2, and 1:4) over the range of 0.07–22.4gcm –3 and 6.7 × 10 3 – 1.29 × 10 8K. The shock Hugoniot curve derived for each material displays a single compression maximum corresponding to K-shell ionization. For C:H = 1:1, the compression maximum occurs at 4.7-fold of the initial density and we show radiation effects significantly increase the shock compression ratio above 2 Gbar, surpassing relativisticmore » effects. The single-peaked structure of the Hugoniot curves contrasts with previous work on higher-Z plasmas, which exhibit a two-peak structure corresponding to both K- and L-shell ionization. Analysis of the electronic density of states reveals that the change in Hugoniot structure is due to merging of the L-shell eigenstates in carbon, while they remain distinct for higher-Z elements. Lastly, we show that the isobaric-isothermal linear mixing rule for carbon and hydrogen EOS is a reasonable approximation with errors better than 1% for stellar-core conditions.« less

Quaternized poly(styrene ethylene butylene poly styrene)/multiwalled carbon nanotube composites for alkaline fuel cell applications.

PubMed

Vinodh, Rajangam; Sangeetha, Dharmalingam

2013-08-01

The present study is aimed at synthesizing a novel anion exchange composite membrane from quaternized polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene [QPSEBS] and functionalized multi walled carbon nanotubes (f-MWCNT) by solution casting method. The characteristic properties of the QPSEBS/f-MWCNT composite membranes were investigated using Fourier transform infrared (FTIR), UV-Visible spectroscopy, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffraction (XRD) studies and Raman spectroscopy. The water uptake, ion exchange capacity, ionic conductivity, methanol permeability and selectivity ratio of the membranes were also studied. The prepared composite membranes were tested in an in-house fabricated alkaline membrane fuel cell (AMFC) set up using Pt/C as the common anode catalyst and three different cathode catalysts namely Pt/C, Pd-Ni/C and Ag/C. Among all the three cathode catalysts, Pt/C for QPSEBS/5% f-MWCNT is found to show the maximum power density and open circuit voltage (OCV) of 187 mW cm(-2) and 0.73 V respectively. For direct methanol alkaline membrane fuel cells (DMAMFC), the OCV of QPSEBS/5% f-MWCNT is found to be 0.76 V and the maximum power density of 59.5 mW cm(-2) is achieved at a current density of 175 mA cm(-2).

First-principles equation of state and shock compression predictions of warm dense hydrocarbons

NASA Astrophysics Data System (ADS)

Zhang, Shuai; Driver, Kevin P.; Soubiran, François; Militzer, Burkhard

2017-07-01

We use path integral Monte Carlo and density functional molecular dynamics to construct a coherent set of equations of state (EOS) for a series of hydrocarbon materials with various C:H ratios (2:1, 1:1, 2:3, 1:2, and 1:4) over the range of 0.07 -22.4 g cm-3 and 6.7 ×103-1.29 ×108K . The shock Hugoniot curve derived for each material displays a single compression maximum corresponding to K -shell ionization. For C:H = 1:1, the compression maximum occurs at 4.7-fold of the initial density and we show radiation effects significantly increase the shock compression ratio above 2 Gbar, surpassing relativistic effects. The single-peaked structure of the Hugoniot curves contrasts with previous work on higher-Z plasmas, which exhibit a two-peak structure corresponding to both K - and L -shell ionization. Analysis of the electronic density of states reveals that the change in Hugoniot structure is due to merging of the L -shell eigenstates in carbon, while they remain distinct for higher-Z elements. Finally, we show that the isobaric-isothermal linear mixing rule for carbon and hydrogen EOS is a reasonable approximation with errors better than 1% for stellar-core conditions.

Arbitrarily shaped high-coherence electron bunches from cold atoms

NASA Astrophysics Data System (ADS)

McCulloch, A. J.; Sheludko, D. V.; Saliba, S. D.; Bell, S. C.; Junker, M.; Nugent, K. A.; Scholten, R. E.

2011-10-01

Ultrafast electron diffractive imaging of nanoscale objects such as biological molecules and defects in solid-state devices provides crucial information on structure and dynamic processes: for example, determination of the form and function of membrane proteins, vital for many key goals in modern biological science, including rational drug design. High brightness and high coherence are required to achieve the necessary spatial and temporal resolution, but have been limited by the thermal nature of conventional electron sources and by divergence due to repulsive interactions between the electrons, known as the Coulomb explosion. It has been shown that, if the electrons are shaped into ellipsoidal bunches with uniform density, the Coulomb explosion can be reversed using conventional optics, to deliver the maximum possible brightness at the target. Here we demonstrate arbitrary and real-time control of the shape of cold electron bunches extracted from laser-cooled atoms. The ability to dynamically shape the electron source itself and to observe this shape in the propagated electron bunch provides a remarkable experimental demonstration of the intrinsically high spatial coherence of a cold-atom electron source, and the potential for alleviation of electron-source brightness limitations due to Coulomb explosion.

Ion temperature profiles in front of a negative planar electrode studied by a one-dimensional two-fluid model

NASA Astrophysics Data System (ADS)

Gyergyek, T.; Kovačič, J.

2016-06-01

Plasma-wall transition is studied by a one-dimensional steady state two-fluid model. Continuity and momentum exchange equations are used for the electrons, while the continuity, momentum exchange, and energy transport equation are used for the ions. Electrons are assumed to be isothermal. The closure of ion equations is made by the assumption that the heat flux is zero. The model equations are solved for potential, ion and electron density, and velocity and ion temperature as independent variables. The model includes coulomb collisions between ions and electrons and charge exchange collisions between ions and neutral atoms of the same species and same mass. The neutral atoms are assumed to be essentially at rest. The model is solved for finite ratio ɛ = /λ D L between the Debye length and λD and ionization length L in the pre-sheath and in the sheath at the same time. Charge exchange collisions heat the ions in the sheath and the pre-sheath. Even a small increase of the frequency of charge exchange collisions causes a substantial increase of ion temperature. Coulomb collisions have negligible effect on ion temperature in the pre-sheath, while in the sheath they cause a small cooling of ions. The increase of ɛ causes the increase of ion temperature. From the ion density and temperature profiles, the polytropic function κ is calculated according to its definition given by Kuhn et al. [Phys. Plasmas 13, 013503 (2006)]. The obtained profiles of κ indicate that the ion flow is isothermal only in a relatively narrow region in the pre-sheath, while close to the sheath edge and in the sheath it is closer to adiabatic. The ion sound velocity is space dependent and exhibits a maximum. This maximum indicates the location of the sheath edge only in the limit ɛ → 0 .

Electricity Generation in Microbial Fuel Cell (MFC) by Bacterium Isolated from Rice Paddy Field Soil

NASA Astrophysics Data System (ADS)

Fakhirruddin, Fakhriah; Amid, Azura; Salim, Wan Wardatul Amani Wan; Suhaida Azmi, Azlin

2018-03-01

Microbial fuel cell (MFC) is an alternative approach in generating renewable energy by utilising bacteria that will oxidize organic or inorganic substrates, producing electrons yielded as electrical energy. Different species of exoelectrogenic bacteria capable of generating significant amount of electricity in MFC has been identified, using various organic compounds for fuel. Soil sample taken from rice paddy field is proven to contain exoelectrogenic bacteria, thus electricity generation using mixed culture originally found in the soil, and pure culture isolated from the soil is studied. This research will isolate the exoelectrogenic bacterial species in the rice paddy field soil responsible for energy generation. Growth of bacteria isolated from the MFC is observed by measuring the optical density (OD), cell density weight (CDW) and viable cell count. Mixed bacterial species found in paddy field soil generates maximum power of 77.62 μW and 0.70 mA of current. In addition, the research also shows that the pure bacterium in rice paddy field soil can produce maximum power and current at 51.32 μW and 0.28 mA respectively.

Facile and environmentally friendly synthesis of ultrathin nickel hydroxide nanosheets with excellent supercapacitor performances

NASA Astrophysics Data System (ADS)

Hu, Xiaowei; Liu, Sheng; Li, Chenghui; Huang, Jiahao; Luv, Jixing; Xu, Pan; Liu, Jian; You, Xiao-Zeng

2016-06-01

In this article, we report a facile and environmentally friendly glutamic acid-assisted hydrothermal strategy for the preparation of ultrathin two-dimensional (2D) β-Ni(OH)2 nanosheets with a thickness of about 2 nm, which exhibit a maximum specific capacitance of 2537.4 F g-1 at a current density of 1 A g-1, even at 10 A g-1, the specific capacitance is still maintained at 2290.0 F g-1 with 77.6% retention after 3000 cycles.In this article, we report a facile and environmentally friendly glutamic acid-assisted hydrothermal strategy for the preparation of ultrathin two-dimensional (2D) β-Ni(OH)2 nanosheets with a thickness of about 2 nm, which exhibit a maximum specific capacitance of 2537.4 F g-1 at a current density of 1 A g-1, even at 10 A g-1, the specific capacitance is still maintained at 2290.0 F g-1 with 77.6% retention after 3000 cycles. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr02912d

Hybrid microfluidic fuel cell based on Laccase/C and AuAg/C electrodes.

PubMed

López-González, B; Dector, A; Cuevas-Muñiz, F M; Arjona, N; Cruz-Madrid, C; Arana-Cuenca, A; Guerra-Balcázar, M; Arriaga, L G; Ledesma-García, J

2014-12-15

A hybrid glucose microfluidic fuel cell composed of an enzymatic cathode (Laccase/ABTS/C) and an inorganic anode (AuAg/C) was developed and tested. The enzymatic cathode was prepared by adsorption of 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and Laccase on Vulcan XC-72, which act as a redox mediator, enzymatic catalyst and support, respectively. The Laccase/ABTS/C composite was characterised by Fourier Transform Infrared (FTIR) Spectroscopy, streaming current measurements (Zeta potential) and cyclic voltammetry. The AuAg/C anode catalyst was characterised by Transmission electron microscopy (TEM) and cyclic voltammetry. The hybrid microfluidic fuel cell exhibited excellent performance with a maximum power density value (i.e., 0.45 mW cm(-2)) that is the highest reported to date. The cell also exhibited acceptable stability over the course of several days. In addition, a Mexican endemic Laccase was used as the biocathode electrode and evaluated in the hybrid microfluidic fuel cell generating 0.5 mW cm(-2) of maximum power density. Copyright © 2014 Elsevier B.V. All rights reserved.

Parametric dependence of ion temperature and relative density in the NASA Lewis SUMMA facility. [superconducting magnetic mirror

NASA Technical Reports Server (NTRS)

Snyder, A.; Lauver, M. R.; Patch, R. W.

1976-01-01

Further hot-ion plasma experiments were conducted in the SUMMA superconducting magnetic mirror facility. A steady-state ExB plasma was formed by applying a strong radially inward dc electric field between cylindrical anodes and hollow cathodes located near the magnetic mirror maxima. Extending the use of water cooling to the hollow cathodes, in addition to the anodes, resulted in higher maximum power input to the plasma. Steady-state hydrogen plasmas with ion kinetic temperatures as high as 830 eV were produced. Functional relations were obtained empirically among the plasma current, voltage, magnetic flux density, ion temperature, and relative ion density. The functional relations were deduced by use of a multiple correlation analysis. Data were obtained for midplane magnetic fields from 0.5 to 3.37 tesla and input power up to 45 kW. Also, initial absolute electron density measurements are reported from a 90 deg Thomson scattering laser system.

Effect of Si, Mg, and Mg Zn doping on structural properties of a GaN layer grown by metalorganic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Cho, H. K.; Lee, J. Y.; Kim, K. S.; Yang, G. M.

2001-12-01

We have studied the structural properties of undoped, Si-doped, Mg-doped, and Mg-Zn codoped GaN using high-resolution X-ray diffraction (HRXRD) and transmission electron microscopy. When compared with undoped GaN, the dislocation density at the surface of the GaN layer decreases with Si doping and increases with Mg doping. In addition, we observed a reduction of dislocation density by codoping with Zn atoms in the Mg-doped GaN layer. The full width at half maximum of HRXRD shows that Si doping and Mg-Zn codoping improve the structural quality of the GaN layer as compared with undoped and Mg-doped GaN, respectively.

An investigation of ionospheric upper transition height variations at low and equatorial latitudes deduced from combined COSMIC and C/NOFS measurements

NASA Astrophysics Data System (ADS)

Yang, Changjun; Zhao, Biqiang; Zhu, Jie; Yue, Xinan; Wan, Weixing

2017-10-01

In this study we propose the combination of topside in-situ ion density data from the Communication/Navigation Outage Forecast System (C/NOFS) along with the electron density profile measurement from Constellation Observing System for Meteorology, Ionosphere & Climate (COSMIC) satellites Radio Occultation (RO) for studying the spatial and temporal variations of the ionospheric upper transition height (hT) and the oxygen ion (O+) density scale height. The latitudinal, local time and seasonal distributions of upper transition height show more consistency between hT re-calculated by the profile of the O+ using an α-Chapman function with linearly variable scale height and that determined from direct in-situ ion composition measurements, than with constant scale height and only the COSMIC data. The discrepancy in the values of hT between the C/NOFS measurement and that derived by the combination of COSMIC and C/NOFS satellites observations with variable scale height turns larger as the solar activity decreases, which suggests that the photochemistry and the electrodynamics of the equatorial ionosphere during the extreme solar minimum period produce abnormal structures in the vertical plasma distribution. The diurnal variation of scale heights (Hm) exhibits a minimum after sunrise and a maximum around noon near the geomagnetic equator. Further, the values of Hm exhibit a maximum in the summer hemisphere during daytime, whereas in the winter hemisphere the maximum is during night. Those features of Hm consistently indicate the prominent role of the vertical electromagnetic (E × B) drift in the equatorial ionosphere.

An investigation of ionospheric upper transition height variations at low and equatorial latitudes deduced from combined COSMIC and C/NOFS measurements

NASA Astrophysics Data System (ADS)

Zhao, Biqiang

2017-04-01

In this study we propose the combination of topside in-situ ion density data from the Communication/Navigation Outage Forecast System (C/NOFS) along with the electron density profile measurement from Constellation Observing System for Meteorology, Ionosphere & Climate (COSMIC) satellites Radio Occultation (RO) for studying the spatial and temporal variations of the ionospheric upper transition height (hT) and the oxygen ion (O+) density scale height. The latitudinal, local time and seasonal distributions of upper transition height show more consistency between hT re-calculated by the profile of the O+ using an a-Chapman function with linearly variable scale height and that determined from direct in-situ ion composition measurements, than with constant scale height and only the COSMIC data. The discrepancy in the values of hT between the C/NOFS measurement and that derived by the combination of COSMIC and C/NOFS satellites observations with variable scale height turns larger as the solar activity decreases, which suggests that the photochemistry and the electrodynamics of the equatorial ionosphere during the extreme solar minimum period produce abnormal structures in the vertical plasma distribution. The diurnal variation of scale heights (Hm) exhibits a minimum after sunrise and a maximum around noon near the geomagnetic equator. Further, the values of Hm exhibit a maximum in the summer hemisphere during daytime, whereas in the winter hemisphere the maximum is during night. Those features of Hm consistently indicate the prominent role of the vertical electromagnetic (E×B) drift in the equatorial ionosphere.

431 kA/cm2 peak tunneling current density in GaN/AlN resonant tunneling diodes

NASA Astrophysics Data System (ADS)

Growden, Tyler A.; Zhang, Weidong; Brown, Elliott R.; Storm, David F.; Hansen, Katurah; Fakhimi, Parastou; Meyer, David J.; Berger, Paul R.

2018-01-01

We report on the design and fabrication of high current density GaN/AlN double barrier resonant tunneling diodes grown via plasma assisted molecular-beam epitaxy on bulk GaN substrates. A quantum-transport solver was used to model and optimize designs with high levels of doping and ultra-thin AlN barriers. The devices displayed repeatable room temperature negative differential resistance with peak-to-valley current ratios ranging from 1.20 to 1.60. A maximum peak tunneling current density (Jp) of 431 kA/cm2 was observed. Cross-gap near-UV (370-385 nm) electroluminescence (EL) was observed above +6 V when holes, generated from a polarization induced Zener tunneling effect, recombine with electrons in the emitter region. Analysis of temperature dependent measurements, thermal resistance, and the measured EL spectra revealed the presence of severe self-heating effects.

Reentrant Metal-Insulator Transitions in Silicon -

NASA Astrophysics Data System (ADS)

Campbell, John William M.

This thesis describes a study of reentrant metal -insulator transitions observed in the inversion layer of extremely high mobility Si-MOSFETs. Magneto-transport measurements were carried out in the temperature range 20mK-4.2 K in a ^3He/^4 He dilution refrigerator which was surrounded by a 15 Tesla superconducting magnet. Below a melting temperature (T_{M}~500 mK) and a critical electron density (n_{s }~9times10^{10} cm^{-2}), the Shubnikov -de Haas oscillations in the diagonal resistivity enormous maximum values at the half filled Landau levels while maintaining deep minima corresponding to the quantum Hall effect at filled Landau levels. At even lower electron densities the insulating regions began to spread and eventually a metal-insulator transition could be induced at zero magnetic field. The measurement of extremely large resistances in the milliKelvin temperature range required the use of very low currents (typically in the 10^ {-12} A range) and in certain measurements minimizing the noise was also a consideration. The improvements achieved in these areas through the use of shielding, optical decouplers and battery operated instruments are described. The transport signatures of the insulating state are considered in terms of two basic mechanisms: single particle localization with transport by variable range hopping and the formation of a collective state such as a pinned Wigner crystal or electron solid with transport through the motion of bound dislocation pairs. The experimental data is best described by the latter model. Thus the two dimensional electron system in these high mobility Si-MOSFETs provides the first and only experimental demonstration to date of the formation of an electron solid at zero and low magnetic fields in the quantum limit where the Coulomb interaction energy dominates over the zero point oscillation energy. The role of disorder in favouring either single particle localization or the formation of a Wigner crystal is explored by considering a variety of samples with a wide range of mobilities and by varying the ratio of the carrier density (controlled by the applied gate voltage) to the impurity density (fixed during sample growth). A phase diagram showing the boundaries between the two dimensional electron gas, the Wigner solid, and the single particle localization induced insulator is established in terms of carrier density and sample mobility.

Calculation of induced current densities for humans by magnetic fields from electronic article surveillance devices

NASA Astrophysics Data System (ADS)

Gandhi, Om P.; Kang, Gang

2001-11-01

This paper illustrates the use of the impedance method to calculate the electric fields and current densities induced in millimetre resolution anatomic models of the human body, namely an adult and 10- and 5-year-old children, for exposure to nonuniform magnetic fields typical of two assumed but representative electronic article surveillance (EAS) devices at 1 and 30 kHz, respectively. The devices assumed for the calculations are a solenoid type magnetic deactivator used at store checkouts and a pass-by panel-type EAS system consisting of two overlapping rectangular current-carrying coils used at entry and exit from a store. The impedance method code is modified to obtain induced current densities averaged over a cross section of 1 cm2 perpendicular to the direction of induced currents. This is done to compare the peak current densities with the limits or the basic restrictions given in the ICNIRP safety guidelines. Because of the stronger magnetic fields at lower heights for both the assumed devices, the peak 1 cm2 area-averaged current densities for the CNS tissues such as the brain and the spinal cord are increasingly larger for smaller models and are the highest for the model of the 5-year-old child. For both the EAS devices, the maximum 1 cm2 area-averaged current densities for the brain of the model of the adult are lower than the ICNIRP safety guideline, but may approach or exceed the ICNIRP basic restrictions for models of 10- and 5-year-old children if sufficiently strong magnetic fields are used.

Calculation of induced current densities for humans by magnetic fields from electronic article surveillance devices.

PubMed

Gandhi, O P; Kang, G

2001-11-01

This paper illustrates the use of the impedance method to calculate the electric fields and current densities induced in millimetre resolution anatomic models of the human body, namely an adult and 10- and 5-year-old children, for exposure to nonuniform magnetic fields typical of two assumed but representative electronic article surveillance (EAS) devices at 1 and 30 kHz, respectively. The devices assumed for the calculations are a solenoid type magnetic deactivator used at store checkouts and a pass-by panel-type EAS system consisting of two overlapping rectangular current-carrying coils used at entry and exit from a store. The impedance method code is modified to obtain induced current densities averaged over a cross section of 1 cm2 perpendicular to the direction of induced currents. This is done to compare the peak current densities with the limits or the basic restrictions given in the ICNIRP safety guidelines. Because of the stronger magnetic fields at lower heights for both the assumed devices, the peak 1 cm2 area-averaged current densities for the CNS tissues such as the brain and the spinal cord are increasingly larger for smaller models and are the highest for the model of the 5-year-old child. For both the EAS devices, the maximum 1 cm2 area-averaged current densities for the brain of the model of the adult are lower than the ICNIRP safety guideline, but may approach or exceed the ICNIRP basic restrictions for models of 10- and 5-year-old children if sufficiently strong magnetic fields are used.

Electron density modulation in a pulsed dual-frequency (2/13.56 MHz) dual-antenna inductively coupled plasma discharge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sirse, Nishant, E-mail: nishant.sirse@dcu.ie; Mishra, Anurag; Yeom, Geun Y.

The electron density, n{sub e}, modulation is measured experimentally using a resonance hairpin probe in a pulsed, dual-frequency (2/13.56 MHz), dual-antenna, inductively coupled plasma discharge produced in argon-C{sub 4}F{sub 8} (90–10) gas mixtures. The 2 MHz power is pulsed at a frequency of 1 kHz, whereas 13.56 MHz power is applied in continuous wave mode. The discharge is operated at a range of conditions covering 3–50 mTorr, 100–600 W 13.56 MHz power level, 300–600 W 2 MHz peak power level, and duty ratio of 10%–90%. The experimental results reveal that the quasisteady state n{sub e} is greatly affected by the 2 MHz power levels and slightly affected by 13.56 MHzmore » power levels. It is observed that the electron density increases by a factor of 2–2.5 on increasing 2 MHz power level from 300 to 600 W, whereas n{sub e} increases by only ∼20% for 13.56 MHz power levels of 100–600 W. The rise time and decay time constant of n{sub e} monotonically decrease with an increase in either 2 or 13.56 MHz power level. This effect is stronger at low values of 2 MHz power level. For all the operating conditions, it is observed that the n{sub e} overshoots at the beginning of the on-phase before relaxing to a quasisteady state value. The relative overshoot density (in percent) depends on 2 and 13.56 MHz power levels. On increasing gas pressure, the n{sub e} at first increases, reaching to a maximum value, and then decreases with a further increase in gas pressure. The decay time constant of n{sub e} increases monotonically with pressure, increasing rapidly up to 10 mTorr gas pressure and at a slower rate of rise to 50 mTorr. At a fixed 2/13.56 MHz power level and 10 mTorr gas pressure, the quasisteady state n{sub e} shows maximum for 30%–40% duty ratio and decreases with a further increase in duty ratio.« less

Direct growth of vanadium nitride nanosheets on carbon nanotube fibers as novel negative electrodes for high-energy-density wearable fiber-shaped asymmetric supercapacitors

NASA Astrophysics Data System (ADS)

Guo, Jiabin; Zhang, Qichong; Sun, Juan; Li, Chaowei; Zhao, Jingxin; Zhou, Zhenyu; He, Bing; Wang, Xiaona; Man, Ping; Li, Qiulong; Zhang, Jun; Xie, Liyan; Li, Mingxing; Yao, Yagang

2018-04-01

Significant efforts have been recently devoted to constructing high-performance fiber-shaped asymmetric supercapacitors. However, it is still a paramount challenge to develop high-energy-density fiber-shaped asymmetric supercapacitors for practical applications in portable and wearable electronics. This work reports a simple and efficient method to directly grow vanadium nitride nanosheets on carbon nanotube fibers as advanced negative electrodes with a high specific capacitance of 188 F/cm3 (564 mF/cm2). Taking advantage of their attractive structure, we successfully fabricated a fiber-shaped asymmetric supercapacitor device with a maximum operating voltage of 1.6 V by assembling the vanadium nitride/carbon nanotube fiber negative electrode with the Zinc-Nickel-Cobalt ternary oxides nanowire arrays positive electrode. Due to the excellent synergistic effects between positive and negative electrodes, a remarkable specific capacitance of 50 F/cm3 (150 mF/cm2) and an outstanding energy density of 17.78 mWh/cm3 (53.33 μWh/cm2) for our fiber-shaped asymmetric supercapacitor can be achieved. Furthermore, the as-assembled fiber-shaped asymmetric supercapacitor device has excellent mechanical flexibility in that 91% of the capacitance retained after bending 90° for 3000 times. Thus, this work exploits a pathway to construct high-energy-density fiber-shaped asymmetric supercapacitor for next-generation portable and wearable electronics.

Theoretical study of the design dye-sensitivity for usage in the solar cell device

NASA Astrophysics Data System (ADS)

Alrikabi, Alaa

There are many applications in the polymer chemistry, pharmaceutical, agricultural and industrial fields of the thiadiazole molecule and their derivatives. Allowance of the energy gap of the polymer conjugated is an object of great interesting debit for the possible removal of a doping in the preparation of highly conductivity polymers. Thiadiazoles derivatives are structural foundation of the polymer materials. In this present work, the electronic properties of graphene nanoflakes (GNFs)-phenanthrene-1,3,4-thiadiazoles oligomers are studied and discussed. Where thiadiazoles is expanded from one to 9 unit's molecules at the structure. The energy gap, HOMO, LUMO distribution, total energy, Fermi level energy, work function, maximum wavelength absorption, vertical absorption energies, and oscillator strengths are calculated for each molecule. All calculations are carry out by usage density function theory (DFT) and depended time density function theory (TD-DFT) with the B3LYP/6-31G model in the Gaussian 09W software packages. Results show that increasing the number of monomeric units lead to great enhance in the electronic properties, which caused it decreased the band gap from 3.17 eV in the system with one unit of thiadiazole just to 1.35 eV in the system with 9 units of thiadiazole. This case is raised the value of maximum absorption wavelengths to >500 nm to give the better performance in optoelectronic and solar cell, as these structures have prime absorption bands within the solar spectrum.

Single-molecular diodes based on opioid derivatives.

PubMed

Siqueira, M R S; Corrêa, S M; Gester, R M; Del Nero, J; Neto, A M J C

2015-12-01

We propose an efficient single-molecule rectifier based on a derivative of opioid. Electron transport properties are investigated within the non-equilibrium Green's function formalism combined with density functional theory. The analysis of the current-voltage characteristics indicates obvious diode-like behavior. While heroin presents rectification coefficient R>1, indicating preferential electronic current from electron-donating to electron-withdrawing, 3 and 6-acetylmorphine and morphine exhibit contrary behavior, R<1. Our calculations indicate that the simple inclusion of acetyl groups modulate a range of devices, which varies from simple rectifying to resonant-tunneling diodes. In particular, the rectification rations for heroin diodes show microampere electron current with a maximum of rectification (R=9.1) at very low bias voltage of ∼0.6 V and (R=14.3)∼1.8 V with resistance varying between 0.4 and 1.5 M Ω. Once most of the current single-molecule diodes usually rectifies in nanoampere, are not stable over 1.0 V and present electrical resistance around 10 M. Molecular devices based on opioid derivatives are promising in molecular electronics.

LPM effect and primary energy estimations

NASA Technical Reports Server (NTRS)

Bourdeau, M. F.; Capdevielle, J. N.

1985-01-01

The distortion of the electron cascade development under LPM effects is now admitted; it consists of an increase of depth of showers origin, of shower maximum T sum max, a decrease of the number of particles at maximum N sub max and results in a flattening and a widening of the cascade transition curve. Connected with the influence of multiple Coulomb scattering on basic electromagnetic processes (bremsstrahlung, pair production), this effect appears at high energy with a threshold dependent on the density of the medium (more than 10 TeV for lead, more than 10 sup 6 TeV in air). Consequently, the electromagnetic components of hadron induced showers in lead and EAS in air calculated for the same hadronic cascades in the different alternative, including or not the LPM effect are examined here.

Improving the particle beam characteristics resulting from laser ion acceleration at ultra high intensity through target manipulation - Numerical modeling

NASA Astrophysics Data System (ADS)

Tatomirescu, Dragos; d'Humieres, Emmanuel; Vizman, Daniel

2017-12-01

The necessity to produce superior quality ion and electron beams has been a hot research field due to the advances in laser science in the past decade. This work focuses on the parametric study of different target density profiles in order to determine their effect on the spatial distribution of the accelerated particle beam, the particle maximum energy, and the electromagnetic field characteristics. For the scope of this study, the laser pulse parameters were kept constant, while varying the target parameters. The study continues the work published in [1] and focuses on further studying the effects of target curvature coupled with a cone laser focusing structure. The results show increased particle beam focusing and a significant enhancement in particle maximum energy.

Indirectly pumped 3.7 THz InGaAs/InAlAs quantum-cascade lasers grown by metal-organic vapor-phase epitaxy.

PubMed

Fujita, Kazuue; Yamanishi, Masamichi; Furuta, Shinichi; Tanaka, Kazunori; Edamura, Tadataka; Kubis, Tillmann; Klimeck, Gerhard

2012-08-27

Device-performances of 3.7 THz indirect-pumping quantum-cascade lasers are demonstrated in an InGaAs/InAlAs material system grown by metal-organic vapor-phase epitaxy. The lasers show a low threshold-current-density of ~420 A/cm2 and a peak output power of ~8 mW at 7 K, no sign of parasitic currents with recourse to well-designed coupled-well injectors in the indirect pump scheme, and a maximum operating temperature of Tmax ~100 K. The observed roll-over of output intensities in current ranges below maximum currents and limitation of Tmax are discussed with a model for electron-gas heating in injectors. Possible ways toward elevation of Tmax are suggested.

In-situ synthesis of Co3O4/graphite nanocomposite for high-performance supercapacitor electrode applications

NASA Astrophysics Data System (ADS)

Gopalakrishnan, M.; Srikesh, G.; Mohan, A.; Arivazhagan, V.

2017-05-01

In this work, a low cost and pollution free in-situ synthesis of phase pure Co3O4 nanoparticles and Co3O4/graphite nanocomposite have been successfully developed via co-precipitation method followed by the thermal treatment process. The prepared samples were characterized by powder X-ray diffraction, scanning electron microscope, high resolution transmission electron microscope, Fourier Transform Infrared Spectroscopy and electrochemical measurements. Electrochemical measurements such as cyclic voltammetry, galvanostatic charge-discharge, electrochemical impedance spectroscopy were carried out in 6 M KOH aqueous electrolytic solution. The results show the excellent maximum specific capacitive behavior of 239.5 F g-1 for pure and 395.04 F g-1 for Co3O4/graphite nanocomposite at a current density of 0.5 A g-1. This composite exhibits a good cyclic stability, with a small loss of 2.68% of maximum capacitance over a consecutive 1000 cycles. The investigation indicates that the prepared electrode material could be a potential and promising candidate for electrochemical supercapacitors.

Solitary waves in dusty plasmas with weak relativistic effects in electrons and ions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kalita, B. C., E-mail: bckalita123@gmail.com; Choudhury, M., E-mail: choudhurymamani@gmail.com

2016-10-15

Two distinct classes of dust ion acoustic (DIA) solitary waves based on relativistic ions and electrons, dust charge Z{sub d} and ion-to-dust mass ratio Q’ = m{sub i}/m{sub d} are established in this model of multicomponent plasmas. At the increase of mass ratio Q’ due to increase of relativistic ion mass and accumulation of more negative dust charges into the plasma causing decrease of dust mass, relativistic DIA solitons of negative potentials are abundantly observed. Of course, relativistic compressive DIA solitons are also found to exist simultaneously. Further, the decrease of temperature inherent in the speed of light c causesmore » the nonlinear term to be more active that increases the amplitude of the rarefactive solitons and dampens the growth of compressive solitons for relatively low and high mass ratio Q’, respectively. The impact of higher initial streaming of the massive ions is observed to identify the point of maximum dust density N{sub d} to yield rarefactive relativistic solitons of maximum amplitude.« less

Dopant Distribution in Atomic Layer Deposited ZnO:Al Films Visualized by Transmission Electron Microscopy and Atom Probe Tomography.

PubMed

Wu, Yizhi; Giddings, A Devin; Verheijen, Marcel A; Macco, Bart; Prosa, Ty J; Larson, David J; Roozeboom, Fred; Kessels, Wilhelmus M M

2018-02-27

The maximum conductivity achievable in Al-doped ZnO thin films prepared by atomic layer deposition (ALD) is limited by the low doping efficiency of Al. To better understand the limiting factors for the doping efficiency, the three-dimensional distribution of Al atoms in the ZnO host material matrix has been examined on the atomic scale using a combination of high-resolution transmission electron microscopy (TEM) and atom probe tomography (APT). Although the Al distribution in ZnO films prepared by so-called "ALD supercycles" is often presented as atomically flat δ-doped layers, in reality a broadening of the Al-dopant layers is observed with a full-width-half-maximum of ∼2 nm. In addition, an enrichment of the Al at grain boundaries is observed. The low doping efficiency for local Al densities > ∼1 nm -3 can be ascribed to the Al solubility limit in ZnO and to the suppression of the ionization of Al dopants from adjacent Al donors.

Dopant Distribution in Atomic Layer Deposited ZnO:Al Films Visualized by Transmission Electron Microscopy and Atom Probe Tomography

PubMed Central

2018-01-01

The maximum conductivity achievable in Al-doped ZnO thin films prepared by atomic layer deposition (ALD) is limited by the low doping efficiency of Al. To better understand the limiting factors for the doping efficiency, the three-dimensional distribution of Al atoms in the ZnO host material matrix has been examined on the atomic scale using a combination of high-resolution transmission electron microscopy (TEM) and atom probe tomography (APT). Although the Al distribution in ZnO films prepared by so-called “ALD supercycles” is often presented as atomically flat δ-doped layers, in reality a broadening of the Al-dopant layers is observed with a full-width–half-maximum of ∼2 nm. In addition, an enrichment of the Al at grain boundaries is observed. The low doping efficiency for local Al densities > ∼1 nm–3 can be ascribed to the Al solubility limit in ZnO and to the suppression of the ionization of Al dopants from adjacent Al donors. PMID:29515290

An Electrothermal Plasma Source Developed for Simulation of Transient Heat Loads in Future Large Fusion Devices

NASA Astrophysics Data System (ADS)

Gebhart, Trey; Baylor, Larry; Winfrey, Leigh

2016-10-01

The realization of fusion energy requires materials that can withstand high heat and particle fluxes at the plasma material interface. In this work, an electrothermal (ET) plasma source has been designed as a possible transient heat flux source for a linear plasma material interaction device. An ET plasma source operates in the ablative arc regime, which is driven by a DC capacitive discharge. The current travels through the 4mm bore of a boron nitride liner and subsequently ablates and ionizes the liner material. This results in a high density plasma with a large unidirectional bulk flow out of the source exit. The pulse length for the ET source has been optimized using a pulse forming network to have a duration of 1ms at full-width half maximum. The peak currents and maximum source energies seen in this system are 2kA and 5kJ. The goal of this work is to show that the ET source produces electron densities and heat fluxes that are comparable to transient events in future large magnetic confinement fusion devices. Heat flux, plasma temperature, and plasma density were determined for each test shot using infrared imaging and optical spectroscopy techniques. This work will compare the ET source output (heat flux, temperature, and density) with and without an applied magnetic field. Research sponsored by the Laboratory Directed Research and Development Program of Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U. S. Department of Energy.

77 FR 4014 - Takes of Marine Mammals Incidental to Specified Activities; Physical Oceanographic Studies in the...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-26

... chambers for a total discharge volume of 210 in\\3\\) with a 1,200 m long hydrophone streamer. GI guns will... require the Navy to use species-specific mean maximum densities, rather than the mean average densities... use mean maximum densities, rather than mean average densities. Marine mammal population density...

Structural and electronic properties for atomic clusters

NASA Astrophysics Data System (ADS)

Sun, Yan

We have studied the structural and electronic properties for different groups of atomic clusters by doing a global search on the potential energy surface using the Taboo Search in Descriptors Space (TSDS) method and calculating the energies with Kohn-Sham Density Functional Theory (KS-DFT). Our goal was to find the structural and electronic principles for predicting the structure and stability of clusters. For Ben (n = 3--20), we have found that the evolution of geometric and electronic properties with size reflects a change in the nature of the bonding from van der Waals to metallic and then bulk-like. The cluster sizes with extra stability agree well with the predictions of the jellium model. In the 4d series of transition metal (TM) clusters, as the d-type bonding becomes more important, the preferred geometric structure changes from icosahedral (Y, Zr), to distorted compact structures (Nb, Mo), and FCC or simple cubic crystal fragments (Tc, Ru, Rh) due to the localized nature of the d-type orbital. Analysis of relative isomer energies and their electronic density of states suggest that these clusters tend to follow a maximum hardness principle (MHP). For A4B12 clusters (A is divalent, B is monovalent), we found unusually large (on average 1.95 eV) HOMO-LUMO gap values. This shows the extra stability at an electronic closed shell (20 electrons) predicted by the jellium model. The importance of symmetry, closed electronic and ionic shells in stability is shown by the relative stability of homotops of Mg4Ag12 which also provides support for the hypothesis that clusters that satisfy more than one stability criterion ("double magic") should be particularly stable.

Magnetron sputtering system for coatings deposition with activation of working gas mixture by low-energy high-current electron beam

NASA Astrophysics Data System (ADS)

Gavrilov, N. V.; Kamenetskikh, A. S.; Men'shakov, A. I.; Bureyev, O. A.

2015-11-01

For the purposes of efficient decomposition and ionization of the gaseous mixtures in a system for coatings deposition using reactive magnetron sputtering, a low-energy (100-200 eV) high-current electron beam is generated by a grid-stabilized plasma electron source. The electron source utilizes both continuous (up to 20 A) and pulse-periodic mode of discharge with a self-heated hollow cathode (10-100 A; 0.2 ms; 10-1000 Hz). The conditions for initiation and stable burning of the high-current pulse discharge are studied along with the stable generation of a low-energy electron beam within the gas pressure range of 0.01 - 1 Pa. It is shown that the use of the electron beam with controllable parameters results in reduction of the threshold values both for the pressure of gaseous mixture and for the fluxes of molecular gases. Using such a beam also provides a wide range (0.1-10) of the flux density ratios of ions and sputtered atoms over the coating surface, enables an increase in the maximum pulse density of ion current from plasma up to 0.1 A, ensures an excellent adhesion, optimizes the coating structure, and imparts improved properties to the superhard nanocomposite coatings of (Ti,Al)N/a-Si3N4 and TiC/-a-C:H. Mass-spectrometric measurements of the beam-generated plasma composition proved to demonstrate a twofold increase in the average concentration of N+ ions in the Ar-N2 plasma generated by the high-current (100 A) pulsed electron beam, as compared to the dc electron beam.

Spectral Characteristics of Laser-Induced Graphite Plasma in Ambient Air

NASA Astrophysics Data System (ADS)

Wang, Jinmei; Zheng, Peichao; Liu, Hongdi; Fang, Liang

2016-11-01

An experimental setup of laser-induced graphite plasma was built and the spectral characteristics and properties of graphite plasma were studied. From the temporal behavior of graphite plasma, the duration of CN partials (B2 Σ+ → X2 Σ+) emission was two times longer than that of atomic carbon, and all intensities reached the maximum during the early stage from 0.2 μs to 0.8 μs. The electron temperature decreased from 11807 K to 8755 K, the vibration temperature decreased from 8973 K to 6472 K, and the rotational temperature decreased from 7288 K to 4491 K with the delay time, respectively. The effect of the laser energy was also studied, and it was found that the thresholds and spectral characteristics of CN molecular and C atomic spectroscopy presented great differences. At lower laser energies, the electron excited temperature, the electron density, the vibrational temperature and rotational temperature of CN partials increased rapidly. At higher laser energies, the increasing of electron excited temperature and electron density slow down, and the vibrational temperature and rotational temperature even trend to saturation due to plasma shielding and dissociation of CN molecules. The relationship among the three kinds of temperatures was Telec>Tvib>Trot at the same time. The electron density of the graphite plasma was in the order of 1017 cm-3 and 1018 cm-3. supported by National Natural Science Foundation of China (No. 61205149), Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry, Science Research Funds of Chongqing Municipal Education Commission (KJ1500436), Scientific and Technological Talents Training Project of Chongqing (CSTC2013kjrc-qnrc40002), Key Project of Foundation and Advanced Technology Research Project of Chongqing (CSTC2015jcyjB0358), Visiting Scholarship of State Key Laboratory of Power Transmission Equipment & System Security and New Technology (2007DA10512714409)

Detection of Ionospheric Alfven Resonator Signatures Onboard C/NOFS: Implications for IRI Modeling

NASA Technical Reports Server (NTRS)

Simoes, F.; Klenzing, J.; Ivanov, S.; Pfaff, R.; Rowland, D.; Bilitza, D.

2011-01-01

The 2008-2009 long-lasting solar minimum activity has been the one of its kind since the dawn of space age, offering exceptional conditions for investigating space weather in the near-Earth environment. First ever detection of Ionospheric Alfven Resonator (IAR) signatures in orbit offers new means for investigating ionospheric electrodynamics, namely MHD (MagnetoHydroDynamics) wave propagation, aeronomy processes, ionospheric dynamics, and Sun-Earth connection mechanisms at a local scale. Local and global plasma density heterogeneities in the ionosphere and magnetosphere allow for formation of waveguides and resonators where magnetosonic and shear Alfven waves propagate. The ionospheric magnetosonic waveguide results from complete magnetosonic wave reflection about the ionospheric F-region peak, where the Alfven index of refraction presents a maximum. MHD waves can also be partially trapped in the vertical direction between the lower boundary of the ionosphere and the magnetosphere, a resonance mechanism known as IAR. In this work we present C/NOFS (Communications/Navigation Outage Forecasting System) Extremely Low Frequency (ELF) electric field measurements related to IAR signatures, discuss the resonance and wave propagation mechanisms in the ionosphere, and address the electromagnetic inverse problem from which electron/ion distributions can be derived. These peculiar IAR electric field measurements provide new, complementary methodologies for inferring ionospheric electron and ion density profiles, and also contribute for the investigation of ionosphere dynamics and space weather monitoring. Specifically, IAR spectral signatures measured by C/NOFS contribute for improving the International Reference Ionosphere (IRI) model, namely electron density and ion composition.

Engineering hierarchical ultrathin CuCo2O4 nanosheets array on Ni foam by rapid electrodeposition method toward high-performance binder-free supercapacitors

NASA Astrophysics Data System (ADS)

Abbasi, Laleh; Arvand, Majid

2018-07-01

In the present work, we engineer hierarchical ultrathin CuCo2O4 nanosheets arrays on Ni foam through a facile, controllable and low-cost electrodeposition method by controlling deposition time and adjusting precursor's type, as a binder-free electrode for high performance supercapacitors. The effects of deposition time and types of precursors on the morphology of the as-prepared electrodes were investigated by X-ray diffraction, energy dispersive X-ray analysis, field-emission scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. As a results, the CuCo2O4 electrode prepared by nitrate salts at the deposition time of 10 min, includes the most uniform and ultrathin nanosheet arrays and exhibits the highest capacitance performance, such as ultrahigh specific capacitance of 1330 F g-1 at 2 A g-1 with 70% capacitance retention (938 F g-1) at ultrahigh current density of 60 A g-1, excellent cycling stability of 93.6% capacitance retention after 5000CD cycles and the maximum energy density of 29.55 Wh kg-1 at the power density of 0.4 kW kg-1. These superior electrochemical performances have been attributed to its unique structures with direct connected ultrathin nanosheets on the surface of Ni foam and abundant pores provide large electroactive sites for electrochemical reactions, as well as facile electron, ion transport and high electrical conductivity.

Membraneless enzymatic ethanol/O2 fuel cell: Transitioning from an air-breathing Pt-based cathode to a bilirubin oxidase-based biocathode

NASA Astrophysics Data System (ADS)

Aquino Neto, Sidney; Milton, Ross D.; Hickey, David P.; De Andrade, Adalgisa R.; Minteer, Shelley D.

2016-08-01

The bioelectrooxidation of ethanol was investigated in a fully enzymatic membraneless ethanol/O2 biofuel cell assembly using hybrid bioanodes containing multi-walled carbon nanotube (MWCNT)-decorated gold metallic nanoparticles with either a pyrroloquinoline quinone (PQQ)-dependent alcohol dehydrogenase (ADH) enzyme or a nicotinamide adenine dinucleotide (NAD+)-dependent ADH enzyme. The biofuel cell anode was prepared with the PQQ-dependent enzyme and designed using either a direct electron transfer (DET) architecture or via a mediated electron transfer (MET) configuration through a redox polymer, 1,1‧-dimethylferrocene-modified linear polyethyleneimine (FcMe2-C3-LPEI). In the case of the bioanode containing the NAD+-dependent enzyme, only the mediated electron transfer mechanism was employed using an electropolymerized methylene green film to regenerate the NAD+ cofactor. Regardless of the enzyme being employed at the anode, a bilirubin oxidase-based biocathode prepared within a DET architecture afforded efficient electrocatalytic oxygen reduction in an ethanol/O2 biofuel cell. The power curves showed that DET-based bioanodes via the PQQ-dependent ADH still lack high current densities, whereas the MET architecture furnished maximum power density values as high as 226 ± 21 μW cm-2. Considering the complete membraneless enzymatic biofuel cell with the NAD+-dependent ADH-based bioanode, power densities as high as 111 ± 14 μW cm-2 were obtained. This shows the advantage of PQQ-dependent ADH for membraneless ethanol/O2 biofuel cell applications.

A theoretical study of structural, opto-electronic and nonlinear properties of arylboroxine derivatives

NASA Astrophysics Data System (ADS)

Islam, Nasarul; Pandith, Altaf Hussain

2018-01-01

Density functional theory at CAM-B3LYP/6-311G++ (2d, 2p) level was employed to study the Triphenylboroxine derivatives ( TB) containing electron donating and electron substituents, for their charge transfer and nonlinear optical properties. The results reveal that electron donating groups facilitate the rapid electron injection as compared to unsubstituted TB. It was observed that upon substitution with electron donating groups, the TB derivatives show an increased double bond character in the B3-C18 bond indicating an increase in the degree of conjugation. The Frontier molecular orbital studies indicate that highest occupied molecular orbitals of the neutral molecules delocalize primarily over the three phenyl rings and bridging oxygen atoms, whereas the lowest unoccupied molecular orbitals localize largely on the two phenyl rings and the boron atoms. Further, the TD-DFT studies indicate that the maximum absorption band results from the electron transitions from the initial states that are contributed by the HOMO and HOMO-1 to the final states that are mainly contributed by the LUMOs. In addition, we have observed that the introduction of electron donating group to the TB-7 leads to more active nonlinear performance.

Low energy electron beam processing of YBCO thin films

NASA Astrophysics Data System (ADS)

Chromik, Š.; Camerlingo, C.; Sojková, M.; Štrbík, V.; Talacko, M.; Malka, I.; Bar, I.; Bareli, G.; Jung, G.

2017-02-01

Effects of low energy 30 keV electron irradiation of superconducting YBa2Cu3O7-δ thin films have been investigated by means of transport and micro-Raman spectroscopy measurements. The critical temperature and the critical current of 200 nm thick films initially increase with increasing fluency of the electron irradiation, reach the maximum at fluency 3 - 4 × 1020 electrons/cm2, and then decrease with further fluency increase. In much thinner films (75 nm), the critical temperature increases while the critical current decreases after low energy electron irradiation with fluencies below 1020 electrons/cm2. The Raman investigations suggest that critical temperature increase in irradiated films is due to healing of broken Cusbnd O chains that results in increased carrier's concentration in superconducting CuO2 planes. Changes in the critical current are controlled by changes in the density of oxygen vacancies acting as effective pinning centers for flux vortices. The effects of low energy electron irradiation of YBCO turned out to result from a subtle balance of many processes involving oxygen removal, both by thermal activation and kick-off processes, and ordering of chains environment by incident electrons.

Electron acceleration in downward auroral field-aligned currents

NASA Astrophysics Data System (ADS)

Cran-McGreehin, Alexandra P.; Wright, Andrew N.

2005-10-01

The auroral downward field-aligned current is mainly carried by electrons accelerated up from the ionosphere into the magnetosphere along magnetic field lines. Current densities are typically of the order of a few μ Am-2, and the associated electrons are accelerated to energies of several hundred eV up to a few keV. This downward current has been modeled by Temerin and Carlson (1998) using an electron fluid. This paper extends that model by describing the electron populations via distribution functions and modeling all of the F region. We assume a given ion density profile, and invoke quasi-neutrality to solve for the potential along the field line. Several important locations and quantities emerge from this model: the ionospheric trapping point, below which the ionospheric population is trapped by an ambipolar electric field; the location of maximum E∥, of the order of a few mVm-1, which lies earthward of the B/n peak; the acceleration region, located around the B/n peak, which normally extends between altitudes of 500 and 3000 km; and the total potential increase along the field line, of the order of a few hundred V up to several kV. The B/n peak is found to be the central factor determining the altitude and magnitude of the accelerating potential required. Indeed, the total potential drop is found to depend solely on the equilibrium properties in the immediate vicinity of the B/n peak.

Low intensity, continuous wave photodoping of ZnO quantum dots - photon energy and particle size effects.

PubMed

Aguirre, Matías E; Municoy, S; Grela, M A; Colussi, A J

2017-02-08

The unique properties of semiconductor quantum dots (QDs) have found application in the conversion of solar to chemical energy. How the relative rates of the redox processes that control QD photon efficiencies depend on the particle radius (r) and photon energy (E λ ), however, is not fully understood. Here, we address these issues and report the quantum yields (Φs) of interfacial charge transfer and electron doping in ZnO QDs capped with ethylene glycol (EG) as a function of r and E λ in the presence and absence of methyl viologen (MV 2+ ) as an electron acceptor, respectively. We found that Φs for the oxidation of EG are independent of E λ and photon fluence (φ λ ), but markedly increase with r. The independence of Φs on φ λ ensures that QDs are never populated by more than one electron-hole pair, thereby excluding Auger-type terminations. We show that these findings are consistent with the operation of an interfacial redox process that involves thermalized carriers in the Marcus inverted region. In the absence of MV 2+ , QDs accumulate electrons up to limiting volumetric densities ρ e,∞ that depend sigmoidally on excess photon energy E* = E λ - E BG (r), where E BG (r) is the r-dependent bandgap energy. The maximum electron densities: ρ ev,∞ ∼ 4 × 10 20 cm -3 , are reached at E* > 0.5 eV, independent of the particle radius.

Unification of field theory and maximum entropy methods for learning probability densities

NASA Astrophysics Data System (ADS)

Kinney, Justin B.

2015-09-01

The need to estimate smooth probability distributions (a.k.a. probability densities) from finite sampled data is ubiquitous in science. Many approaches to this problem have been described, but none is yet regarded as providing a definitive solution. Maximum entropy estimation and Bayesian field theory are two such approaches. Both have origins in statistical physics, but the relationship between them has remained unclear. Here I unify these two methods by showing that every maximum entropy density estimate can be recovered in the infinite smoothness limit of an appropriate Bayesian field theory. I also show that Bayesian field theory estimation can be performed without imposing any boundary conditions on candidate densities, and that the infinite smoothness limit of these theories recovers the most common types of maximum entropy estimates. Bayesian field theory thus provides a natural test of the maximum entropy null hypothesis and, furthermore, returns an alternative (lower entropy) density estimate when the maximum entropy hypothesis is falsified. The computations necessary for this approach can be performed rapidly for one-dimensional data, and software for doing this is provided.

Unification of field theory and maximum entropy methods for learning probability densities.

PubMed

Kinney, Justin B

2015-09-01

The need to estimate smooth probability distributions (a.k.a. probability densities) from finite sampled data is ubiquitous in science. Many approaches to this problem have been described, but none is yet regarded as providing a definitive solution. Maximum entropy estimation and Bayesian field theory are two such approaches. Both have origins in statistical physics, but the relationship between them has remained unclear. Here I unify these two methods by showing that every maximum entropy density estimate can be recovered in the infinite smoothness limit of an appropriate Bayesian field theory. I also show that Bayesian field theory estimation can be performed without imposing any boundary conditions on candidate densities, and that the infinite smoothness limit of these theories recovers the most common types of maximum entropy estimates. Bayesian field theory thus provides a natural test of the maximum entropy null hypothesis and, furthermore, returns an alternative (lower entropy) density estimate when the maximum entropy hypothesis is falsified. The computations necessary for this approach can be performed rapidly for one-dimensional data, and software for doing this is provided.

Design and Performance of a Miniature Radar L-Band Transceiver

NASA Technical Reports Server (NTRS)

McWatters, D.; Price, D.; Edelstein, W.

2004-01-01

Radar electronics developed for past JPL space missions historically had been custom designed and as such, given budgetary, time, and risk constraints, had not been optimized for maximum flexibility or miniaturization. To help reduce cost and risk of future radar missions, a generic radar module was conceived. The module includes a 1.25-GHz (L-band) transceiver and incorporates miniature high-density packaging of integrated circuits in die/chip form. The technology challenges include overcoming the effect of miniaturization and high packaging density to achieve the performance, reliability, and environmental ruggedness required for space missions. The module was chosen to have representative (generic) functionality most likely required from an L-band radar. For very large aperture phased-array spaceborne radar missions, the large dimensions of the array suggest the benefit of distributing the radar electronics into the antenna array. For such applications, this technology is essential in order to bring down the cost, mass, and power of the radar electronics module replicated in each panel of the array. For smaller sized arrays, a single module can be combined with the central radar controller and still provide the bene.ts of configuration .exibility, low power, and low mass. We present the design approach for the radar electronics module and the test results for its radio frequency (RF) portion: a miniature, low-power, radiation-hard L-band transceiver.

On the surface trapping parameters of polytetrafluoroethylene block

NASA Astrophysics Data System (ADS)

Zhang, Guan-Jun; Yang, Kai; Zhao, Wen-Bin; Yan, Zhang

2006-12-01

Surface flashover phenomena under high electric field are closely related to the surface characteristics of a solid insulating material between energized electrodes. Based on measuring the surface potential decaying curve of polytetrafluoroethylene (PTFE) block charged by a needle-plane corona discharge, its surface trapping parameters are calculated with the isothermal current theory, and the correlative curve between the surface trap density and its energy level is obtained. The maximum density of electron traps and hole traps in the surface layer of PTFE presents a similar value of ∼2.7 × 1017 eV-1 m-3, and the energy level of its electron and hole traps is of about 0.85-1.0 eV and 0.80-0.90 eV, respectively. Via the X-ray photoelectron spectroscopy (XPS) technique, the F, C, K and O elements are detected on the surface of PTFE samples, and F shows a remarkable atom proportion of ∼73.3%, quite different from the intrinsic distribution corresponding to its chemical formula. The electron traps are attributed to quantities of F atoms existing on the surface of PTFE due to its molecular chain with C atoms surrounded by F atoms spirally. It is considered that the distortions of chemical and electronic structure on solid surface are responsible for the flashover phenomena occurring at a low applied voltage.

Dependence of L-mode confinement on the electron cyclotron power deposition profile in the TCV tokamak

NASA Astrophysics Data System (ADS)

Kirneva, N. A.; Razumova, K. A.; Pochelon, A.; Behn, R.; Coda, S.; Curchod, L.; Duval, B. P.; Goodman, T. P.; Labit, B.; Karpushov, A. N.; Rancic, M.; Sauter, O.; Silva, M.; TCV Team

2012-01-01

Scenarios with different electron cyclotron heating power profile distributions and widths were compared for the first time in experiments on the Tokamak à Configuration Variable (TCV). The heating profile was changed from shot to shot over a wide range from localized on-axis, with normalized minor radius half-width at half maximum σ1/2 ~ 0.1, up to a widely distributed heating power profile with σ1/2 ~ 0.4 and finally to a profile peaked far off-axis. The global confinement, MHD activity, density, temperature and electron pressure profile evolution were compared. In particular, the energy confinement properties of discharges with localized on-axis heating and distributed on-axis heating were very similar, with degradation close to that predicted by the ITER L-mode scaling; in the case of off-axis heating, on the other hand, the confinement degradation was even stronger.

Grating formation by a high power radio wave in near-equator ionosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Rohtash; Sharma, A. K.; Tripathi, V. K.

2011-11-15

The formation of a volume grating in the near-equator regions of ionosphere due to a high power radio wave is investigated. The radio wave, launched from a ground based transmitter, forms a standing wave pattern below the critical layer, heating the electrons in a space periodic manner. The thermal conduction along the magnetic lines of force inhibits the rise in electron temperature, limiting the efficacy of heating to within a latitude of few degrees around the equator. The space periodic electron partial pressure leads to ambipolar diffusion creating a space periodic density ripple with wave vector along the vertical. Suchmore » a volume grating is effective to cause strong reflection of radio waves at a frequency one order of magnitude higher than the maximum plasma frequency in the ionosphere. Linearly mode converted plasma wave could scatter even higher frequency radio waves.« less

Design, fabrication and characterization of a double layer solid oxide fuel cell (DLFC)

NASA Astrophysics Data System (ADS)

Wang, Guangjun; Wu, Xiangying; Cai, Yixiao; Ji, Yuan; Yaqub, Azra; Zhu, Bin

2016-11-01

A double layer solid oxide fuel cell (DLSOFC) without using the electrolyte (layer) has been designed by integrating advantages of positive electrode material of lithium ion battery(LiNi0.8Co0.15Al0.05O2) and oxygen-permeable membranes material (trace amount cobalt incorporated terbium doped ceria, TDC + Co) based on the semiconductor physics principle. Instead of using an electrolyte layer, the depletion layer between the anode and cathode served as an electronic insulator to block the electrons but to maintain the electrolyte function for ionic transport. Thus the device with two layers can realize the function of SOFC and at the same time avoids the electronic short circuiting problem. Such novel DLFC showed good performance at low temperatures, for instance, a maximum power density of 230 mWcm-2 was achieved at 500 °C. The working principle of the new device is presented.

The relative density of forests in the United States

Treesearch

Christopher W. Woodall; Charles H. Perry; Patrick D. Miles

2006-01-01

A relative stand density assessment technique, using the mean specific gravity of all trees in a stand to predict its maximum stand density index (SDI) and subsequently its relative stand density (current SDI divided by maximum SDI), was used to estimate the relative density of forests across the United States using a national-scale forest inventory. Live tree biomass...

Time-dependent spectroscopy of plasma plume under laser welding conditions

NASA Astrophysics Data System (ADS)

Hoffman, Jacek; Szymanski, Zygmunt

2004-07-01

Momentary emission spectra of iron and argon lines were measured in a plasma plume induced during welding with a continuous wave CO2 laser. Time-dependent spectra were registered using a fast gate, lens coupled microchannel plate image intensifier placed between a spectrograph and a 1254 silicon intensified target detector connected to an optical multichannel analyser. The results, together with the analysis of the colour images from a fast camera, show that in the case when argon is the shielding gas, two plasmas exist: the argon plasma and the iron plasma. It has been found that during strong bursts the plasma plume over the keyhole consists mainly of metal vapour, not being diluted by the shielding gas. No apparent mixing of the metal vapour and the shielding gas has been observed. The space-averaged electron densities determined from the Stark broadening of the 7503.87, 7514.65 Å Ar I lines amounts to (0.75-1.05) × 1023 m-3 depending on the distance from the surface. Assuming that argon is not mixed with the metal vapour and is in local thermodynamic equilibrium these electron densities correspond to the temperatures of 12-13 kK. At the peaks of strong vapour bursts the space-averaged electron densities determined from the Stark broadening of the 5383.37 Å Fe I line are (0.6-1) × 1023 m-3. Numerical simulations showed that the maximum densities in the plasma centre are considerably higher and amount to ~1.8 × 1023 m-3 and ~2.45 × 1023 m-3 in the case of the argon and metal plasma, respectively. Consequently the absorption of the laser beam in the plasma plume amounts to ~5% of the beam power in the case of argon and 10% in the case of metal plasma.

Different electronic and charge-transport properties of four organic semiconductors Tetraazaperopyrenes derivatives

NASA Astrophysics Data System (ADS)

Shi, Yarui; Wei, Huiling; Liu, Yufang

2015-03-01

Tetraazaperopyrenes (TAPPs) derivatives are high-performance n-type organic semiconductor material families with the remarkable long-term stabilities. The charge carrier mobilities in TAPPs derivatives crystals were calculated by the density functional theory (DFT) method combined with the Marcus-Hush electron-transfer theory. The existence of considerable C-H…F-C bonding defines the conformation of the molecular structure and contributes to its stability. We illustrated how it is possible to control the electronic and charge-transport parameters of TAPPs derivatives as a function of the positions, a type of the substituents. It is found that the core substitution of TAPPs has a drastic influence on the charge-transport mobilities. The maximum electron mobility value of the core-brominated 2,9-bis (perfluoroalkyl)-substituted TAPPs is 0.521 cm2 V-1 s-1, which appear in the orientation angle 95° and 275°. The results demonstrate that the TAPPs with bromine substituents in ortho positions exhibit the best charge-transfer efficiency among the four different TAPP derivatives.

Direct measurement of the thickness-dependent electronic band structure of MoS2 using angle-resolved photoemission spectroscopy.

PubMed

Jin, Wencan; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Sadowski, Jerzy T; Al-Mahboob, Abdullah; van der Zande, Arend M; Chenet, Daniel A; Dadap, Jerry I; Herman, Irving P; Sutter, Peter; Hone, James; Osgood, Richard M

2013-09-06

We report on the evolution of the thickness-dependent electronic band structure of the two-dimensional layered-dichalcogenide molybdenum disulfide (MoS2). Micrometer-scale angle-resolved photoemission spectroscopy of mechanically exfoliated and chemical-vapor-deposition-grown crystals provides direct evidence for the shifting of the valence band maximum from Γ to K, for the case of MoS2 having more than one layer, to the case of single-layer MoS2, as predicted by density functional theory. This evolution of the electronic structure from bulk to few-layer to monolayer MoS2 had earlier been predicted to arise from quantum confinement. Furthermore, one of the consequences of this progression in the electronic structure is the dramatic increase in the hole effective mass, in going from bulk to monolayer MoS2 at its Brillouin zone center, which is known as the cause for the decreased carrier mobility of the monolayer form compared to that of bulk MoS2.

Online, automatic, ionospheric maps: IRI-PLAS-MAP

NASA Astrophysics Data System (ADS)

Arikan, F.; Sezen, U.; Gulyaeva, T. L.; Cilibas, O.

2015-04-01

Global and regional behavior of the ionosphere is an important component of space weather. The peak height and critical frequency of ionospheric layer for the maximum ionization, namely, hmF2 and foF2, and the total number of electrons on a ray path, Total Electron Content (TEC), are the most investigated and monitored values of ionosphere in capturing and observing ionospheric variability. Typically ionospheric models such as International Reference Ionosphere (IRI) can provide electron density profile, critical parameters of ionospheric layers and Ionospheric electron content for a given location, date and time. Yet, IRI model is limited by only foF2 STORM option in reflecting the dynamics of ionospheric/plasmaspheric/geomagnetic storms. Global Ionospheric Maps (GIM) are provided by IGS analysis centers for global TEC distribution estimated from ground-based GPS stations that can capture the actual dynamics of ionosphere and plasmasphere, but this service is not available for other ionospheric observables. In this study, a unique and original space weather service is introduced as IRI-PLAS-MAP from http://www.ionolab.org

Strain engineering on electronic structure and carrier mobility in monolayer GeP3

NASA Astrophysics Data System (ADS)

Zeng, Bowen; Long, Mengqiu; Zhang, Xiaojiao; Dong, Yulan; Li, Mingjun; Yi, Yougen; Duan, Haiming

2018-06-01

Using density functional theory coupled with the Boltzmann transport equation with relaxation time approximation, we have studied the strain effect on the electronic structure and carrier mobility of two-dimensional monolayer GeP3. We find that the energies of valence band maximum and conduction band minimum are nearly linearly shifted with a biaxial strain in the range of  ‑4% to 6%, and the band structure experiences a remarkable transition from semiconductor to metal with the appropriate compression (‑5% strain). Under biaxial strain, the mobility of the electron and hole in monolayer GeP3 reduces and increases by more than one order of magnitude, respectively. It is suggested that it is possible to perform successive transitions from an n-type semiconductor (‑4% strain) to a good performance p-semiconductor (+6% strain) by applying strain in monolayer GeP3, which is potentially useful for flexible electronics and nanosized mechanical sensors.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Wentao; Liu, Jiansheng, E-mail: michaeljs-liu@siom.ac.cn; Wang, Wentao

An electron beam with the maximum energy extending up to 1.8 GeV, much higher than the dephasing limit, is experimentally obtained in the laser wakefield acceleration with the plasma density of 3.5 × 10{sup 18} cm{sup −3}. With particle in cell simulations and theoretical analysis, we find that the laser intensity evolution plays a major role in the enhancement of the electron energy gain. While the bubble length decreases due to the intensity-decay of the laser pulse, the phase of the electron beam in the wakefield can be locked, which contributes to the overcoming of the dephasing. Moreover, the laser intensity evolution is describedmore » for the phase-lock acceleration of electrons in the uniform plasma, confirmed with our own simulation. Since the decaying of the intensity is unavoidable in the long distance propagation due to the pump depletion, the energy gain of the high energy laser wakefield accelerator can be greatly enhanced if the current process is exploited.« less

Photovoltaic Properties of Selenized CuGa/In Films with Varied Compositions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muzzillo, Christopher P.; Mansfield, Lorelle M.; Ramanathan, Kannan

2016-11-21

Thin CuGa/In films with varied compositions were deposited by co-evaporation and then selenized in situ with evaporated selenium. The selenized Cu(In, Ga)Se2 absorbers were used to fabricate 390 solar cells. Cu/(Ga+In) and Ga/(Ga+In) (Cu/III and Ga/III) were independently varied, and photovoltaic performance was optimal at Cu/III of 77-92% for all Ga/III compositions studied (Ga/III ~ 30, 50, and 70%). The best absorbers at each Ga/III composition were characterized with time-resolved photoluminescence, scanning electron microscopy, and secondary ion mass spectrometry, and devices were studied with temperature-dependent current density-voltage, light and electrical biased quantum efficiency, and capacitance-voltage. The best cells with Ga/IIImore » ~ 30, 50, and 70% had efficiencies of 14.5, 14.4, and 12.2% and maximum power temperature coefficients of -0.496, -0.452, and -0.413%/degrees C, respectively. This resulted in the Ga/III ~ 50% champion having the highest efficiency at temperatures greater than 40 degrees C, making it the optimal composition for practical purposes. This optimum is understood as a result of the absorber's band gap grading- where minimum band gap dominates short-circuit current density, maximum space charge region band gap dominates open-circuit voltage, and average absorber band gap dominates maximum power temperature coefficient.« less

Study on Locally Confined Deposition of Si Nanocrystals in High-Aspect-Ratio Si Nano-Pillar Array for Nano-Electronic and Nano-Photonic Applications

DTIC Science & Technology

2010-02-23

reflection, thus increasing the quantum efficiency by one order of magnitude and improving the light extraction from the nano-roughened device surface by...respectively. At a biased current of 400 A, the highest external quantum efficiency is over 0.2% to obtain the maximum EL power of >1 W. In...processing techniques for improving the internal and external quantum efficiencies of Si MOSLEDs via detuning the size and density of high-aspect-ratio Si

Pressure induced change in the electronic state of Ta 4 Pd 3 Te 16

DOE PAGES

Jo, Na Hyun; Xiang, Li; Kaluarachchi, Udhara S.; ...

2017-04-24

Here, we present measurements of superconducting transition temperature, resistivity, magnetoresistivity, and temperature dependence of the upper critical field of Ta 4 Pd 3 Te 16 under pressures up to 16.4 kbar. All measured properties have an anomaly at ~ 2 $-$ 4 kbar pressure range; in particular there is a maximum in T c and upper critical field, H c2 ( 0 ), and minimum in low temperature, normal state resistivity. Qualitatively, the data can be explained considering the density of state at the Fermi level as a dominant parameter.

AlN/GaN heterostructures for normally-off transistors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhuravlev, K. S., E-mail: zhur@isp.nsc.ru; Malin, T. V.; Mansurov, V. G.

The structure of AlN/GaN heterostructures with an ultrathin AlN barrier is calculated for normally-off transistors. The molecular-beam epitaxy technology of in situ passivated SiN/AlN/GaN heterostructures with a two-dimensional electron gas is developed. Normally-off transistors with a maximum current density of ~1 A/mm, a saturation voltage of 1 V, a transconductance of 350 mS/mm, and a breakdown voltage of more than 60 V are demonstrated. Gate lag and drain lag effects are almost lacking in these transistors.

Ion composition during the formation of a midlatitude E sub S layer

NASA Technical Reports Server (NTRS)

Aikin, A. C.; Goldberg, R. A.; Azcarraga, A.

1973-01-01

The positive ion composition within a midlatitude sporadic E layer has been measured with the aid of a rocket-borne ion mass spectrometer launched from El Arenosillo, Spain on July 3, 1972 at 0743 LMT. Ionograms taken before and during the rocket flight showed a developing sporadic E layer near 114 km. Rocket data showed peaks in electron density and metallic ions at this same height. Both the maximum and total content of the metals are observed to be greater on the downleg than the upleg measurement.

Nonlinear effects during interaction of femtosecond doughnut-shaped laser pulses with glasses: overcoming intensity clamping

NASA Astrophysics Data System (ADS)

Bulgakova, Nadezhda M.; Zhukov, Vladimir P.; Fedoruk, Mikhail P.; Rubenchik, Alexander M.

2017-05-01

Interaction of femtosecond laser pulses with a bulk glass (fused silica as an example) has been studied numerically based on non-linear Maxwell's equations supplemented by the hydrodynamics-type equations for free electron plasma for the cases of Gaussian linearly-polarized and doughnut-shaped radially-polarized laser beams. For Gaussian pulses focused inside glass (800 nm wavelength, 45 fs duration, numerical aperture of 0.25), the free electron density in the laser-excited region remains subcritical while the locally absorbed energy density does not exceed 2000 J/cm3 in the range of pulse energies of 200 nJ - 2 μJ. For doughnut-shaped pulses, the initial high-intensity ring of light is shrinking upon focusing. Upon reaching a certain ionization level on its way, the light ring splits into two branches, one of which shrinks swiftly toward the beam axis well before the geometrical focus, leading to generation of supercritical free electron density. The second branch represents the laser light scattered by the electron plasma away from the beam axis. The final laserexcited volume represents a tube of 0.5-1 μm in radius and 10-15 μm long. The local maximum of absorbed energy can be more than 10 times higher compared to the case of Gaussian beams of the same energy. The corresponding pressure levels have been evaluated. It is anticipated that, in the case of doughnut-shaped pulses, the tube-like shape of the deposited energy should lead to implosion of material that can be used for improving the direct writing of high-refractive index optical structures inside glass or for achieving extreme thermodynamic states of matter.

Phonons and superconductivity in fcc and dhcp lanthanum

NASA Astrophysics Data System (ADS)

Baǧcı, S.; Tütüncü, H. M.; Duman, S.; Srivastava, G. P.

2010-04-01

We have investigated the structural and electronic properties of lanthanum in the face-centered-cubic (fcc) and double hexagonal-close-packed (dhcp) phases using a generalized gradient approximation of the density functional theory and the ab initio pseudopotential method. It is found that double hexagonal-close-packed is the more stable phase for lanthanum. Differences in the density of states at the Fermi level between these two phases are pointed out and discussed in detail. Using the calculated lattice constant and electronic band structure for both phases, a linear response approach based on the density functional theory has been applied to study phonon modes, polarization characteristics of phonon modes, and electron-phonon interaction. Our phonon results show a softening behavior of the transverse acoustic branch along the Γ-L direction and the Γ-M direction for face-centered-cubic and double hexagonal-close-packed phases, respectively. Thus, the transverse-phonon linewidth shows a maximum at the zone boundary M(L) for the double hexagonal-close-packed phase (face-centered-cubic phase), where the transverse-phonon branch exhibits a dip. The electron-phonon coupling parameter λ is found to be 0.97 (1.06) for the double hexagonal-close-packed phase (face-centered-cubic phase), and the superconducting critical temperature is estimated to be 4.87 (dhcp) and 5.88 K (fcc), in good agreement with experimental values of around 5.0 (dhcp) and 6.0 K (fcc). A few superconducting parameters for the double hexagonal-close-packed phase have been calculated and compared with available theoretical and experimental results. Furthermore, the calculated superconducting parameters for both phases are compared between each other in detail.

The influence of synaptic size on AMPA receptor activation: a Monte Carlo model.

PubMed

Montes, Jesus; Peña, Jose M; DeFelipe, Javier; Herreras, Oscar; Merchan-Perez, Angel

2015-01-01

Physiological and electron microscope studies have shown that synapses are functionally and morphologically heterogeneous and that variations in size of synaptic junctions are related to characteristics such as release probability and density of postsynaptic AMPA receptors. The present article focuses on how these morphological variations impact synaptic transmission. We based our study on Monte Carlo computational simulations of simplified model synapses whose morphological features have been extracted from hundreds of actual synaptic junctions reconstructed by three-dimensional electron microscopy. We have examined the effects that parameters such as synaptic size or density of AMPA receptors have on the number of receptors that open after release of a single synaptic vesicle. Our results indicate that the maximum number of receptors that will open after the release of a single synaptic vesicle may show a ten-fold variation in the whole population of synapses. When individual synapses are considered, there is also a stochastical variability that is maximal in small synapses with low numbers of receptors. The number of postsynaptic receptors and the size of the synaptic junction are the most influential parameters, while the packing density of receptors or the concentration of extrasynaptic transporters have little or no influence on the opening of AMPA receptors.

Adenine-functionalized Spongy Graphene for Green and High-Performance Supercapacitors

PubMed Central

El-Gendy, Dalia M.; Ghany, Nabil A. Abdel; El Sherbini, E. E. Foad; Allam, Nageh K.

2017-01-01

A simple method is demonstrated to prepare spongy adenine-functionalized graphene (SFG) as interconnected, porous 3-dimensional (3D) network crinkly sheets. Such 3D network structure provides better contact at the electrode/electrolyte interface and facilitates the charge transfer kinetics. The fabricated SFG was characterized by X-ray diffraction (XRD), FTIR, scanning electron microscopy (FESEM), Raman spectroscopy, thermogravimetric analysis (TGA), UV−vis absorption spectroscopy, and transmission electron microscopy (TEM). The synthesized materials have been evaluated as supercapacitor materials in 0.5 M H2SO4 using cyclic voltammetry (CV) at different potential scan rates, and galvanostatic charge/discharge tests at different current densities. The SFG electrodes showed a maximum specific capacitance of 333 F/g at scan rate of 1 mV/s and exhibited excellent cycling retention of 102% after 1000 cycles at 200 mV/s. The energy density was 64.42 Wh/kg with a power density of 599.8 W/kg at 1.0 A/g. Those figures of merit are much higher than those reported for graphene-based materials tested under similar conditions. The observed high performance can be related to the synergistic effects of the spongy structure and the adenine functionalization. PMID:28216668

Dynamics of Different Bacterial Communities Are Capable of Generating Sustainable Electricity from Microbial Fuel Cells with Organic Waste

PubMed Central

Yamamoto, Shuji; Suzuki, Kei; Araki, Yoko; Mochihara, Hiroki; Hosokawa, Tetsuya; Kubota, Hiroko; Chiba, Yusuke; Rubaba, Owen; Tashiro, Yosuke; Futamata, Hiroyuki

2014-01-01

The relationship between the bacterial communities in anolyte and anode biofilms and the electrochemical properties of microbial fuel cells (MFCs) was investigated when a complex organic waste-decomposing solution was continuously supplied to MFCs as an electron donor. The current density increased gradually and was maintained at approximately 100 to 150 mA m−2. Polarization curve analyses revealed that the maximum power density was 7.4 W m−3 with an internal resistance of 110 Ω. Bacterial community structures in the organic waste-decomposing solution and MFCs differed from each other. Clonal analyses targeting 16S rRNA genes indicated that bacterial communities in the biofilms on MFCs developed to specific communities dominated by novel Geobacter. Multidimensional scaling analyses based on DGGE profiles revealed that bacterial communities in the organic waste-decomposing solution fluctuated and had no dynamic equilibrium. Bacterial communities on the anolyte in MFCs had a dynamic equilibrium with fluctuations, while those of the biofilm converged to the Geobacter-dominated structure. These bacterial community dynamics of MFCs differed from those of control-MFCs under open circuit conditions. These results suggested that bacterial communities in the anolyte and biofilm have a gentle symbiotic system through electron flow, which resulted in the advance of current density from complex organic waste. PMID:24789988

Dynamics of different bacterial communities are capable of generating sustainable electricity from microbial fuel cells with organic waste.

PubMed

Yamamoto, Shuji; Suzuki, Kei; Araki, Yoko; Mochihara, Hiroki; Hosokawa, Tetsuya; Kubota, Hiroko; Chiba, Yusuke; Rubaba, Owen; Tashiro, Yosuke; Futamata, Hiroyuki

2014-01-01

The relationship between the bacterial communities in anolyte and anode biofilms and the electrochemical properties of microbial fuel cells (MFCs) was investigated when a complex organic waste-decomposing solution was continuously supplied to MFCs as an electron donor. The current density increased gradually and was maintained at approximately 100 to 150 mA m(-2). Polarization curve analyses revealed that the maximum power density was 7.4 W m(-3) with an internal resistance of 110 Ω. Bacterial community structures in the organic waste-decomposing solution and MFCs differed from each other. Clonal analyses targeting 16S rRNA genes indicated that bacterial communities in the biofilms on MFCs developed to specific communities dominated by novel Geobacter. Multidimensional scaling analyses based on DGGE profiles revealed that bacterial communities in the organic waste-decomposing solution fluctuated and had no dynamic equilibrium. Bacterial communities on the anolyte in MFCs had a dynamic equilibrium with fluctuations, while those of the biofilm converged to the Geobacter-dominated structure. These bacterial community dynamics of MFCs differed from those of control-MFCs under open circuit conditions. These results suggested that bacterial communities in the anolyte and biofilm have a gentle symbiotic system through electron flow, which resulted in the advance of current density from complex organic waste.

Citrate gel-combustion synthesis and sintering of nanocrystalline ThO2 powders

NASA Astrophysics Data System (ADS)

Sanjay Kumar, D.; Ananthasivan, K.; Amirthapandian, S.; Dasgupta, Arup; Jogeswara Rao, G.

2017-12-01

A systematic study of the influence of citric acid to nitrate mole (R) ratio (R = 0 to 0.50) on the citrate gel-combustion synthesis of nanocrystalline (nc) ThO2 in bulk quantities (30 g) by using citrate gel-combustion was carried out. The nc-ThO2 powders were characterized for their bulk density, size distribution of particles, specific surface area, carbon residue and X-ray crystallite size. All these powders were compacted at pressures varying from 60 to 353 MPa and sintered by using the "two-step sintering" method. Powders prepared from a mixture with an "R" value of 0.125 compacted at 243 MPa yielded a maximum sintered density of 98.8 ± 0.3% T.D. For nc-ThO2, this is the highest sintered density reported so far. The microstructural investigations on nc-ThO2 powders were carried out by using both scanning electron microscopy (SEM) and transmission electron microscopy (TEM). SEM images of the sintered thoria monoliths revealed faceted grains with well defined grain boundaries. Shrinkage anisotropy factor (α) revealed that the compacts prepared from the powders obtained from starting mixtures with R values of 0.125-0.50 had undergone uniform sintering (near isotropic shrinkage).

The Influence of Synaptic Size on AMPA Receptor Activation: A Monte Carlo Model

PubMed Central

Montes, Jesus; Peña, Jose M.; DeFelipe, Javier; Herreras, Oscar; Merchan-Perez, Angel

2015-01-01

Physiological and electron microscope studies have shown that synapses are functionally and morphologically heterogeneous and that variations in size of synaptic junctions are related to characteristics such as release probability and density of postsynaptic AMPA receptors. The present article focuses on how these morphological variations impact synaptic transmission. We based our study on Monte Carlo computational simulations of simplified model synapses whose morphological features have been extracted from hundreds of actual synaptic junctions reconstructed by three-dimensional electron microscopy. We have examined the effects that parameters such as synaptic size or density of AMPA receptors have on the number of receptors that open after release of a single synaptic vesicle. Our results indicate that the maximum number of receptors that will open after the release of a single synaptic vesicle may show a ten-fold variation in the whole population of synapses. When individual synapses are considered, there is also a stochastical variability that is maximal in small synapses with low numbers of receptors. The number of postsynaptic receptors and the size of the synaptic junction are the most influential parameters, while the packing density of receptors or the concentration of extrasynaptic transporters have little or no influence on the opening of AMPA receptors. PMID:26107874

Effect of starting powder characteristics on density, microstructure and low temperature oxidation behavior of a Si3N48w/o Y2O3 ceramic

NASA Technical Reports Server (NTRS)

Schuon, S.; Dutta, S.

1980-01-01

The densification and oxidation behavior of Si3N4 - 8w/oY2O3 prepared from three commercial starting powders were studied. Bars of SN 402, SN 502, and CP 85/15 were sintered for 3 to 4.5 hours at 1750 C. A second set was hot pressed for 2 hours at 1750 C. The microstructures were studied by transmission electron microscopy and scanning electron microscopy, densities were determined, and the phase compositions were determined by X-ray diffraction. Densification and microstructure were greatly influenced by the starting powder morphology and impurity content. Although SN 402 exhibited the maximum weight lose, the highest sintered and hot pressed densities were obtained with this powder. All powders had both equiaxed and elongated grains. Sintered bars were composed of beta silicon nitride and n-melelite. In contrast, hot pressed bars contained beta silicon nitride, H-phase, and J-phase, but no melelite. Yttria distribution in sintered bars was related to the presence of cation impurities such as Ca, Fe, and Mg. A limited oxidation study at 750 C in air showed no instability in these Si3N4 - 8 w/oY2O3 specimens, regardless of startin powder.

Study of plasma parameters in a pulsed plasma accelerator using triple Langmuir probe

NASA Astrophysics Data System (ADS)

Borthakur, S.; Talukdar, N.; Neog, N. K.; Borthakur, T. K.

2018-01-01

A Triple Langmuir Probe (TLP) has been used to study plasma parameters of a transient plasma produced in a newly developed Pulsed Plasma Accelerator system. In this experiment, a TLP with a capacitor based current mode biasing circuit was used that instantaneously gives voltage traces in an oscilloscope which are directly proportional to the plasma electron temperature and density. The electron temperature (Te) and plasma density (ne) of the plasma are measured with the help of this probe and found to be 24.13 eV and 3.34 × 1021/m3 at the maximum energy (-15 kV) of the system, respectively. An attempt was also made to analyse the time-dependent fluctuations in plasma parameters detected by the highly sensitive triple probe. In addition to this, the variation of these parameters under different discharge voltages was studied. The information obtained from these parameters is the initial diagnostics of a new device which is to be dedicated to study the impact of high heat flux plasma stream upon material surfaces inside an ITER like tokamak.

The ionosphere of Europa from Galileo radio occultations

NASA Technical Reports Server (NTRS)

Kliore, A. J.; Hinson, D. P.; Flasar, F. M.; Nagy, A. F.; Cravens, T. E.

1997-01-01

The Galileo spacecraft performed six radio occultation observations of Jupiter's Galilean satellite Europa during its tour of the jovian system. In five of the six instances, these occultations revealed the presence of a tenuous ionosphere on Europa, with an average maximum electron density of nearly 10(4) per cubic centimeter near the surface and a plasma scale height of about 240 +/- 40 kilometers from the surface to 300 kilometers and of 440 +/- 60 kilometers above 300 kilometers. Such an ionosphere could be produced by solar photoionization and jovian magnetospheric particle impact in an atmosphere having a surface density of about 10(8) electrons per cubic centimeter. If this atmosphere is composed primarily of O2, then the principal ion is O2+ and the neutral atmosphere temperature implied by the 240-kilometer scale height is about 600 kelvin. If it is composed of H2O, the principal ion is H3O+ and the neutral temperature is about 340 kelvin. In either case, these temperatures are much higher than those observed on Europa's surface, and an external heating source from the jovian magnetosphere is required.

Predicting the melting temperature of ice-Ih with only electronic structure information as input.

PubMed

Pinnick, Eric R; Erramilli, Shyamsunder; Wang, Feng

2012-07-07

The melting temperature of ice-Ih was calculated with only electronic structure information as input by creating a problem-specific force field. The force field, Water model by AFM for Ice and Liquid (WAIL), was developed with the adaptive force matching (AFM) method by fitting to post-Hartree-Fock quality forces obtained in quantum mechanics∕molecular mechanics calculations. WAIL predicts the ice-Ih melting temperature to be 270 K. The model also predicts the densities of ice and water, the temperature of maximum density of water, the heat of vaporizations, and the radial distribution functions for both ice and water in good agreement with experimental measurements. The non-dissociative WAIL model is very similar to a flexible version of the popular TIP4P potential and has comparable computational cost. By customizing to problem-specific configurations with the AFM approach, the resulting model is remarkably more accurate than any variants of TIP4P for simulating ice-Ih and water in the temperature range from 253 K and 293 K under ambient pressure.

High-Power Growth-Robust InGaAs/InAlAs Terahertz Quantum Cascade Lasers

PubMed Central

2017-01-01

We report on high-power terahertz quantum cascade lasers based on low effective electron mass InGaAs/InAlAs semiconductor heterostructures with excellent reproducibility. Growth-related asymmetries in the form of interface roughness and dopant migration play a crucial role in this material system. These bias polarity dependent phenomena are studied using a nominally symmetric active region resulting in a preferential electron transport in the growth direction. A structure based on a three-well optical phonon depletion scheme was optimized for this bias direction. Depending on the sheet doping density, the performance of this structure shows a trade-off between high maximum operating temperature and high output power. While the highest operating temperature of 155 K is observed for a moderate sheet doping density of 2 × 1010 cm–2, the highest peak output power of 151 mW is found for 7.3 × 1010 cm–2. Furthermore, by abutting a hyperhemispherical GaAs lens to a device with the highest doping level a record output power of 587 mW is achieved for double-metal waveguide structures. PMID:28470028

On the mid-latitude ionospheric storm association with intense geomagnetic storms

NASA Astrophysics Data System (ADS)

Okpala, Kingsley Chukwudi; Ogbonna, Chinasa Edith

2018-04-01

The bulk association between ionospheric storms and geomagnetic storms has been studied. Hemispheric features of seasonal variation of ionospheric storms in the mid-latitude were also investigated. 188 intense geomagnetic storms (Dst ≤ 100 nT) that occurred during solar cycles 22 and 23 were considered, of which 143 were observed to be identified with an ionospheric storm. Individual ionospheric storms were identified as maximum deviations of the F2 layer peak electron density from quiet time values. Only ionospheric storms that could clearly be associated with the peak of a geomagnetic storm were considered. Data from two mid-latitude ionosonde stations; one in the northern hemisphere (i.e. Moscow) and the other in the southern hemisphere (Grahamstown) were used to study ionospheric conditions at the time of the individual geomagnetic storms. Results show hemispheric and latitudinal differences in the intensity and nature of ionospheric storms association with different types of geomagnetic storms. These results are significant for our present understanding of the mechanisms which drive the changes in electron density during different types of ionospheric storms.

A Study of Ionospheric Storm Association with Intense Geomagnetic Storms

NASA Astrophysics Data System (ADS)

Okpala, K. C.

2017-12-01

The bulk association between ionospheric storms and geomagnetic storms have been studied. Hemispheric features of seasonal variation of ionospheric storms in the mid-latitude were also investigated. 188 intense geomagnetic storms (Dst ≤100nT) that occurred during solar cycle 22 and 23 were considered, of which 143 were observed to be identified with an ionospheric storm. Individual ionospheric storms were identified as maximum deviations of the F2 layer peak electron density from quiet time values. Only ionospheric storms that could clearly be associated with the peak of a geomagnetic storms were considered. Data from two mid-latitude ionosonde stations; one in the northern hemisphere (i.e Moscow) and the other in the southern hemisphere (Grahamstown) were used to study ionospheric condition at the time of the individual geomagnetic storms. Results show hemispheric and latitudinal differences in the intensity and nature of ionospheric storms association with different types of geomagnetic storms. These results are significant for our present understanding of the mechanisms which drive the changes in electron density during different types of ionospheric storms.

Interaction Between New Anti-cancer Drug Syndros and CNT(6,6-6) Nanotube for Medical Applications: Geometry Optimization, Molecular Structure, Spectroscopic (NMR, UV/Vis, Excited state), FMO, MEP and HOMO-LUMO Investigation

NASA Astrophysics Data System (ADS)

Sheikhi, Masoome; Shahab, Siyamak; Khaleghian, Mehrnoosh; Kumar, Rakesh

2018-03-01

In the present work, Density Functional Theory (DFT) was first time employed to investigate the interaction between new drug (6aR,10aR)-6,6,9-trimethyl-3-pentyl-6a,7,8,10a-tetrahydrobenzo[c]chromen-1-ol (Syndros) and the CNT(6,6-6) Nanotube in the gaseous phase. The interaction effects of compounds Syndros and CNT (6,6-6) nanotube on the electronic properties, chemical shift tensors and natural charge was also determined and discussed. The electronic spectra of the Syndros and the complex CNT(6,6-6)/Syndros in the gas phase were calculated by Time Dependent Density Functional Theory (TD-DFT) for the formation of adsorption effect on maximum wavelength of the Syndros. Nucleus-Independent Chemical Shifts (NICS) calculations have also been carried out for the compound Syndors and the complex CNT(6,6-6)/Syndros and the aromaticity of the compound Syndors before and after interaction with the CNT(6,6-6) Nanotube was investigated.

Increasing the applicability of density functional theory. V. X-ray absorption spectra with ionization potential corrected exchange and correlation potentials.

PubMed

Verma, Prakash; Bartlett, Rodney J

2016-07-21

Core excitation energies are computed with time-dependent density functional theory (TD-DFT) using the ionization energy corrected exchange and correlation potential QTP(0,0). QTP(0,0) provides C, N, and O K-edge spectra to about an electron volt. A mean absolute error (MAE) of 0.77 and a maximum error of 2.6 eV is observed for QTP(0,0) for many small molecules. TD-DFT based on QTP (0,0) is then used to describe the core-excitation spectra of the 22 amino acids. TD-DFT with conventional functionals greatly underestimates core excitation energies, largely due to the significant error in the Kohn-Sham occupied eigenvalues. To the contrary, the ionization energy corrected potential, QTP(0,0), provides excellent approximations (MAE of 0.53 eV) for core ionization energies as eigenvalues of the Kohn-Sham equations. As a consequence, core excitation energies are accurately described with QTP(0,0), as are the core ionization energies important in X-ray photoionization spectra or electron spectroscopy for chemical analysis.

High-Power Growth-Robust InGaAs/InAlAs Terahertz Quantum Cascade Lasers.

PubMed

Deutsch, Christoph; Kainz, Martin Alexander; Krall, Michael; Brandstetter, Martin; Bachmann, Dominic; Schönhuber, Sebastian; Detz, Hermann; Zederbauer, Tobias; MacFarland, Donald; Andrews, Aaron Maxwell; Schrenk, Werner; Beck, Mattias; Ohtani, Keita; Faist, Jérôme; Strasser, Gottfried; Unterrainer, Karl

2017-04-19

We report on high-power terahertz quantum cascade lasers based on low effective electron mass InGaAs/InAlAs semiconductor heterostructures with excellent reproducibility. Growth-related asymmetries in the form of interface roughness and dopant migration play a crucial role in this material system. These bias polarity dependent phenomena are studied using a nominally symmetric active region resulting in a preferential electron transport in the growth direction. A structure based on a three-well optical phonon depletion scheme was optimized for this bias direction. Depending on the sheet doping density, the performance of this structure shows a trade-off between high maximum operating temperature and high output power. While the highest operating temperature of 155 K is observed for a moderate sheet doping density of 2 × 10 10 cm -2 , the highest peak output power of 151 mW is found for 7.3 × 10 10 cm -2 . Furthermore, by abutting a hyperhemispherical GaAs lens to a device with the highest doping level a record output power of 587 mW is achieved for double-metal waveguide structures.

Effect of Traverse and Rotational Speeds on the Tensile Behavior of the Underwater Dissimilar Friction Stir Welded Aluminum Alloys

NASA Astrophysics Data System (ADS)

Bijanrostami, Kh.; Barenji, R. Vatankhah; Hashemipour, M.

2017-02-01

The tensile behavior of the underwater dissimilar friction stir welded AA6061 and AA7075 aluminum alloy joints was investigated for the first time. For this aim, the joints were welded at different conditions and tensile test was conducted for measuring the strength and elongation of them. In addition, the microstructure of the joints was characterized by means of optical and transmission electron microscopes. Scanning electron microscope was used for fractography of the joints. Furthermore, the process parameters and tensile properties of the joints were correlated and optimized. The results revealed that the maximum tensile strength of 237.3 MPa and elongation of 41.2% could be obtained at a rotational speed 1853 rpm and a traverse speed of 50 mm/min. In comparison with the optimum condition, higher heat inputs caused grain growth and reduction in dislocation density and hence led to lower strength. The higher elongations for the joints welded at higher heat inputs were due to lower dislocation density inside the grains, which was consistent with a more ductile fracture of them.

The ionosphere of Europa from Galileo radio occultations.

PubMed

Kliore, A J; Hinson, D P; Flasar, F M; Nagy, A F; Cravens, T E

1997-07-18

The Galileo spacecraft performed six radio occultation observations of Jupiter's Galilean satellite Europa during its tour of the jovian system. In five of the six instances, these occultations revealed the presence of a tenuous ionosphere on Europa, with an average maximum electron density of nearly 10(4) per cubic centimeter near the surface and a plasma scale height of about 240 +/- 40 kilometers from the surface to 300 kilometers and of 440 +/- 60 kilometers above 300 kilometers. Such an ionosphere could be produced by solar photoionization and jovian magnetospheric particle impact in an atmosphere having a surface density of about 10(8) electrons per cubic centimeter. If this atmosphere is composed primarily of O2, then the principal ion is O2+ and the neutral atmosphere temperature implied by the 240-kilometer scale height is about 600 kelvin. If it is composed of H2O, the principal ion is H3O+ and the neutral temperature is about 340 kelvin. In either case, these temperatures are much higher than those observed on Europa's surface, and an external heating source from the jovian magnetosphere is required.

Polydopamine as a new modification material to accelerate startup and promote anode performance in microbial fuel cells

NASA Astrophysics Data System (ADS)

Du, Qing; An, Jingkun; Li, Junhui; Zhou, Lean; Li, Nan; Wang, Xin

2017-03-01

The bacterial anode material is important to the performance of microbial fuel cells (MFCs) because its characteristics affect the biofilm formation and extracellular electron transfer. Here we find that a superhydrophilic semiconductor, polydopamine (PDA), is an effective modification material for the anode to accelerate startup and improve power density. When the activated carbon anode is added with 50% (wt.) PDA, the startup time is 14% shorter than the control (from 88 h to 76 h), with a 31% increase in maximum power density from 613 ± 9 to 803 ± 6 mW m-2, and the Columbic efficiency increases from 19% to 48%. These can be primarily attributed to the abundant functional groups (such as amino group, and catechol functions) introduced by PDA that improve hydrophilicity and extracellular electron transfer. PDA also increases proportions of Proteobacteria and Firmicutes families, indicating that PDA has a selective effect on anode microbial community. Our findings provide a new approach to accelerate anode biofilm formation and enhance MFC power output by modification of biocompatible PDA.

Development of Enterobacter aerogenes fuel cells: from in situ biohydrogen oxidization to direct electroactive biofilm.

PubMed

Zhuang, Li; Zhou, Shungui; Yuan, Yong; Liu, Tinglin; Wu, Zhifeng; Cheng, Jiong

2011-01-01

This study described an Enterobacter aerogenes-catalyzed microbial fuel cell (MFC) with a carbon-based anode that exhibited a maximum power density of 2.51 W/m(3) in the absence of artificial electron mediators. The MFC was started up rapidly, within hours, and the current generation in the early stage was demonstrated to result from in situ oxidation of biohydrogen produced by E. aerogenes during glucose fermentation. Over periodic replacement of substrate, both planktonic biomass in the culture liquid and hydrogen productivity decreased, while increased power density and coulombic efficiency and decreased internal resistance were unexpectedly observed. Using scanning electron microscopy and cyclic voltammetry, it was found that the enhanced MFC performance was associated with the development of electroactive biofilm on the anodic surface, proposed to involve an acclimation and selection process of E. aerogenes cells under electrochemical tension. The significant advantage of rapid start-up and the ability to develop an electroactive biofilm identifies E. aerogenes as a suitable biocatalyst for MFC applications. Copyright © 2010 Elsevier Ltd. All rights reserved.

Highly durable piezo-electric energy harvester by a super toughened and flexible nanocomposite: effect of laponite nano-clay in poly(vinylidene fluoride)

NASA Astrophysics Data System (ADS)

Rahman, Wahida; Ghosh, Sujoy Kumar; Ranjan Middya, Tapas; Mandal, Dipankar

2017-09-01

A highly durable piezoelectric energy harvester is introduced by integrating the toughness and flexibility of a non-electrically poled, laponite nano-clay mineral-induced γ-phase (up to 98%) in a poly(vinylidene-fluoride) (PVDF) matrix by a simple solvent evaporation technique. Owing to a superior electromechanical coupling effect, PVDF/laponite nanocomposites retain excellent biomechanical energy harvesting capabilities under external vibration (as high as 6 V output voltage and 70 nA output current under a compressive force of 300 N) and charge storage properties under an external high electric field (maximum 0.8~ \\text{J} \\text{c}{{\\text{m}}-3} of discharged energy density at a breakdown strength of 302 MV m-1). As a proof of concept, the fabricated nanogenerator (NG) possesses a high output power density (~6.3 mW m-2) that directly drives several consumer electronics without using any storage system or batteries. It paves the way for potential applicability in next generation electronics, particularly as a self-powered device and to configure sustainable internet of things (IoT) sensor networks.

Valency configuration of transition metal impurities in ZnO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petit, Leon; Schulthess, Thomas C; Svane, Axel

2006-01-01

We use the self-interaction corrected local spin-density approximation to investigate the ground state valency configuration of transition metal (TM=Mn, Co) impurities in n- and p-type ZnO. We find that in pure Zn{sub 1-x}TM{sub x}O, the localized TM{sup 2+} configuration is energetically favored over the itinerant d-electron configuration of the local spin density (LSD) picture. Our calculations indicate furthermore that the (+/0) donor level is situated in the ZnO gap. Consequently, for n-type conditions, with the Fermi energy {epsilon}F close to the conduction band minimum, TM remains in the 2+ charge state, while for p-type conditions, with {epsilon}F close to themore » valence band maximum, the 3+ charge state is energetically preferred. In the latter scenario, modeled here by co-doping with N, the additional delocalized d-electron charge transfers into the entire states at the top of the valence band, and hole carriers will only exist, if the N concentration exceeds the TM impurity concentration.« less

Inkjet-Printed Electrodes on A4 Paper Substrates for Low-Cost, Disposable, and Flexible Asymmetric Supercapacitors.

PubMed

Sundriyal, Poonam; Bhattacharya, Shantanu

2017-11-08

Printed electronics is widely gaining much attention for compact and high-performance energy-storage devices because of the advancement of flexible electronics. The development of a low-cost current collector, selection, and utilization of the proper material deposition tool and improvement of the device energy density are major challenges for the existing flexible supercapacitors. In this paper, we have reported an inkjet-printed solid-state asymmetric supercapacitor on commercial A4 paper using a low-cost desktop printer (EPSON L130). The physical properties of all inks have been carefully optimized so that the developed inks are within the printable range, i.e., Fromm number of 4 < Z < 14 for all inks. The paper substrate is made conducting (sheet resistance ∼ 1.6 Ω/sq) by printing 40 layers of conducting graphene oxide (GO) ink on its surface. The developed conducting patterns on paper are further printed with a GO-MnO 2 nanocomposite ink to make a positive electrode, and another such structure is printed with activated carbon ink to form a negative electrode. A combination of both of these electrodes is outlaid by fabricating an asymmetric supercapacitor. The assembled asymmetric supercapacitor with poly(vinyl alcohol) (PVA)-LiCl gel electrolyte shows a stable potential window of 0-2.0 V and exhibits outstanding flexibility, good cyclic stability, high rate capability, and high energy density. The fabricated paper-substrate-based flexible asymmetric supercapacitor also displays an excellent electrochemical performances, e.g., a maximum areal capacitance of 1.586 F/cm 2 (1023 F/g) at a current density of 4 mA/cm 2 , highest energy density of 22 mWh/cm 3 at a power density of 0.099 W/cm 3 , a capacity retention of 89.6% even after 9000 charge-discharge cycles, and a low charge-transfer resistance of 2.3 Ω. So, utilization of inkjet printing for the development of paper-based flexible electronics has a strong potential for embedding into the next generation low-cost, compact, and wearable energy-storage devices and other printed electronic applications.

Formation of high-β plasma and stable confinement of toroidal electron plasma in Ring Trap 1a)

NASA Astrophysics Data System (ADS)

Saitoh, H.; Yoshida, Z.; Morikawa, J.; Furukawa, M.; Yano, Y.; Kawai, Y.; Kobayashi, M.; Vogel, G.; Mikami, H.

2011-05-01

Formation of high-β electron cyclotron resonance heating plasma and stable confinement of pure electron plasma have been realized in the Ring Trap 1 device, a magnetospheric configuration generated by a levitated dipole field magnet. The effects of coil levitation resulted in drastic improvements of the confinement properties, and the maximum local β value has exceeded 70%. Hot electrons are major component of electron populations, and its particle confinement time is 0.5 s. Plasma has a peaked density profile in strong field region [H. Saitoh et al., 23rd IAEA Fusion Energy Conference EXC/9-4Rb (2010)]. In pure electron plasma experiment, inward particle diffusion is realized, and electrons are stably trapped for more than 300 s. When the plasma is in turbulent state during beam injection, plasma flow has a shear, which activates the diocotron (Kelvin-Helmholtz) instability. The canonical angular momentum of the particle is not conserved in this phase, realizing the radial diffusion of charged particles across closed magnetic surfaces. [Z. Yoshida et al., Phys Rev. Lett. 104, 235004 (2010); H. Saitoh et al., Phys. Plasmas 17, 112111 (2010).].

Multicomponent density functional theory embedding formulation.

PubMed

Culpitt, Tanner; Brorsen, Kurt R; Pak, Michael V; Hammes-Schiffer, Sharon

2016-07-28

Multicomponent density functional theory (DFT) methods have been developed to treat two types of particles, such as electrons and nuclei, quantum mechanically at the same level. In the nuclear-electronic orbital (NEO) approach, all electrons and select nuclei, typically key protons, are treated quantum mechanically. For multicomponent DFT methods developed within the NEO framework, electron-proton correlation functionals based on explicitly correlated wavefunctions have been designed and used in conjunction with well-established electronic exchange-correlation functionals. Herein a general theory for multicomponent embedded DFT is developed to enable the accurate treatment of larger systems. In the general theory, the total electronic density is separated into two subsystem densities, denoted as regular and special, and different electron-proton correlation functionals are used for these two electronic densities. In the specific implementation, the special electron density is defined in terms of spatially localized Kohn-Sham electronic orbitals, and electron-proton correlation is included only for the special electron density. The electron-proton correlation functional depends on only the special electron density and the proton density, whereas the electronic exchange-correlation functional depends on the total electronic density. This scheme includes the essential electron-proton correlation, which is a relatively local effect, as well as the electronic exchange-correlation for the entire system. This multicomponent DFT-in-DFT embedding theory is applied to the HCN and FHF(-) molecules in conjunction with two different electron-proton correlation functionals and three different electronic exchange-correlation functionals. The results illustrate that this approach provides qualitatively accurate nuclear densities in a computationally tractable manner. The general theory is also easily extended to other types of partitioning schemes for multicomponent systems.

Multicomponent density functional theory embedding formulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Culpitt, Tanner; Brorsen, Kurt R.; Pak, Michael V.

Multicomponent density functional theory (DFT) methods have been developed to treat two types of particles, such as electrons and nuclei, quantum mechanically at the same level. In the nuclear-electronic orbital (NEO) approach, all electrons and select nuclei, typically key protons, are treated quantum mechanically. For multicomponent DFT methods developed within the NEO framework, electron-proton correlation functionals based on explicitly correlated wavefunctions have been designed and used in conjunction with well-established electronic exchange-correlation functionals. Herein a general theory for multicomponent embedded DFT is developed to enable the accurate treatment of larger systems. In the general theory, the total electronic density ismore » separated into two subsystem densities, denoted as regular and special, and different electron-proton correlation functionals are used for these two electronic densities. In the specific implementation, the special electron density is defined in terms of spatially localized Kohn-Sham electronic orbitals, and electron-proton correlation is included only for the special electron density. The electron-proton correlation functional depends on only the special electron density and the proton density, whereas the electronic exchange-correlation functional depends on the total electronic density. This scheme includes the essential electron-proton correlation, which is a relatively local effect, as well as the electronic exchange-correlation for the entire system. This multicomponent DFT-in-DFT embedding theory is applied to the HCN and FHF{sup −} molecules in conjunction with two different electron-proton correlation functionals and three different electronic exchange-correlation functionals. The results illustrate that this approach provides qualitatively accurate nuclear densities in a computationally tractable manner. The general theory is also easily extended to other types of partitioning schemes for multicomponent systems.« less

Normal and abnormal evolution of argon metastable density in high-density plasmas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seo, B. H.; Kim, J. H., E-mail: jhkim86@kriss.re.kr; You, S. J., E-mail: sjyou@cnu.ac.kr

2015-05-15

A controversial problem on the evolution of Ar metastable density as a function of electron density (increasing trend versus decreasing trend) was resolved by discovering the anomalous evolution of the argon metastable density with increasing electron density (discharge power), including both trends of the metastable density [Daltrini et al., Appl. Phys. Lett. 92, 061504 (2008)]. Later, by virtue of an adequate physical explanation based on a simple global model, both evolutions of the metastable density were comprehensively understood as part of the abnormal evolution occurring at low- and high-density regimes, respectively, and thus the physics behind the metastable evolution hasmore » seemed to be clearly disclosed. In this study, however, a remarkable result for the metastable density behavior with increasing electron density was observed: even in the same electron density regime, there are both normal and abnormal evolutions of metastable-state density with electron density depending on the measurement position: The metastable density increases with increasing electron density at a position far from the inductively coupled plasma antenna but decreases at a position close to the antenna. The effect of electron temperature, which is spatially nonuniform in the plasma, on the electron population and depopulation processes of Argon metastable atoms with increasing electron density is a clue to understanding the results. The calculated results of the global model, including multistep ionization for the argon metastable state and measured electron temperature, are in a good agreement with the experimental results.« less

Layout and results from the initial operation of the high-resolution x-ray imaging crystal spectrometer on the Large Helical Device.

PubMed

Pablant, N A; Bitter, M; Delgado-Aparicio, L; Goto, M; Hill, K W; Lazerson, S; Morita, S; Roquemore, A L; Gates, D; Monticello, D; Nielson, H; Reiman, A; Reinke, M; Rice, J E; Yamada, H

2012-08-01

First results of ion and electron temperature profile measurements from the x-ray imaging crystal spectrometer (XICS) diagnostic on the Large Helical Device (LHD) are presented. This diagnostic system has been operational since the beginning of the 2011 LHD experimental campaign and is the first application of the XICS diagnostic technique to helical plasma geometry. The XICS diagnostic provides measurements of ion and electron temperature profiles in LHD with a spatial resolution of 2 cm and a maximum time resolution of 5 ms (typically 20 ms). Ion temperature profiles from the XICS diagnostic are possible under conditions where charge exchange recombination spectroscopy (CXRS) is not possible (high density) or is perturbative to the plasma (low density or radio frequency heated plasmas). Measurements are made by using a spherically bent crystal to provide a spectrally resolved 1D image of the plasma from line integrated emission of helium-like Ar(16 +). The final hardware design and configuration are detailed along with the calibration procedures. Line-integrated ion and electron temperature measurements are presented, and the measurement accuracy is discussed. Finally central temperature measurements from the XICS system are compared to measurements from the Thomson scattering and CXRS systems, showing excellent agreement.

Electricity generation by Pyrococcus furiosus in microbial fuel cells operated at 90°C.

PubMed

Sekar, Narendran; Wu, Chang-Hao; Adams, Michael W W; Ramasamy, Ramaraja P

2017-07-01

Hyperthermophiles are microorganisms that thrive in extremely hot environments with temperatures near and even above 100°C. They are the most deeply rooted microorganisms on phylogenetic trees suggesting they may have evolved to survive in the early hostile earth. The simple respiratory systems of some of these hyperthermophiles make them potential candidates to develop microbial fuel cells (MFC) that can generate power at temperatures approaching the boiling point. We explored extracellular electron transfer in the hyperthermophilic archaeon Pyrococcus furiosus (Pf) by studying its ability to generate electricity in a two-chamber MFC. Pf growing in defined medium functioned as an anolyte in a MFC operated at 90°C, generating a maximum current density of 2 A m -2 and a peak power density of 225 mW m -2 without the addition of any external redox mediator. Electron microscopy and electrochemical impedance spectroscopy of the anode with the attached Pf biofilm demonstrated bio-electrochemical behavior that led to electricity generation in the MFC via direct electron transfer. This proof of concept study reveals for the first time that a hyperthermophile such as Pf can generate electricity in MFC at extreme temperatures. Biotechnol. Bioeng. 2017;114: 1419-1427. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

Characterization of a novel strain phylogenetically related to Kocuria rhizophila and its chemical modification to improve performance of microbial fuel cells.

PubMed

Luo, Jianmei; Li, Ming; Zhou, Minghua; Hu, Youshuang

2015-07-15

It is certainly an important research area to discovery new exoelectrogens for microbial fuel cells (MFCs), and how to effectively manipulate its cell property to improve power performance is still a great challenge. In this study, a new electrochemically active bacterium phylogenetically related to Kocuria rhizophila was first isolated and found electrogenic in MFCs, which was identified through the combination methods of molecular biology, physiological, biochemical and morphological characteristics. The MFCs inoculated with this strain generated power from a wide variety of substrates, reached a maximum power density of 75mW/m(2) in the substrate of 1g/L glucose. And the electron transfer mechanism was confirmed to be dominantly direct biofilm mechanism. Chemical treatment with five reagents was verified to be a feasible strategy to improve the power density of MFCs, increasing approximately 1.75 fold at most after treated with lysozyme. This enhancement was contributed to the significant enhancement on cell permeability, cell membrane fluidity and Coenzyme Q10 (the electron carrier). Thus this work offered a novel Gram-positive electrogenic bacterium and proved chemical treatment was a feasible strategy to improve electron transfer for application in MFCs. Copyright © 2015 Elsevier B.V. All rights reserved.

Microwave synthesis of molybdenum doped LiFePO4/C and its electrochemical studies.

PubMed

Naik, Amol; P, Sajan C

2016-05-10

A Mo-doped LiFePO4 composite was prepared successfully from an iron carbonyl complex by adopting a facile and rapid microwave assisted solid state method. The evolution of gases from the iron precursor produces a highly porous product. The formation and substitution of Mo in LiFePO4 were confirmed by X-ray diffraction; surface analysis was carried out by scanning electron microscopy, field emission scanning electron microscopy, and transmission electron microscopy. The electrochemical properties of the substituted LiFePO4 were examined by cyclic voltammetry, electrochemical impedance spectroscopy and by recording charge-discharge cycles. It was observed that the as prepared composites consisted of a single phase orthorhombic olivine-type structure, where Mo(6+) was successfully introduced into the M2(Fe) sites. Incorporation of supervalent Mo(6+) introduced Li(+) ion vacancies in LiFePO4. The synthesized material facilitated lithium ion diffusion during charging/discharging due to the charge compensation effect and porosity. The battery performance studies showed that LiMo0.05Fe0.095PO4 exhibited a maximum capacity of 169.7 mA h g(-1) at 0.1 C current density, with admirable stability retention. Even at higher current densities, the retention of the specific capacity was exceptional.

Carrier concentration dependence of donor activation energy in n-type GaN epilayers grown on Si (1 1 1) by plasma-assisted MBE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Mahesh; Central Research Laboratory, Bharat Electronics, Bangalore 560 013; Bhat, Thirumaleshwara N.

Highlights: ► The n-type GaN layers were grown by plasma-assisted molecular beam epitaxy. ► The optical characteristics of a donor level in Si-doped GaN were studied. ► Activation energy of a Si-related donor was estimated from temperature dependent PL measurements. ► PL peak positions, FWHM of PL and activation energies are found to be proportional to the cube root of carrier density. ► The involvement of donor levels is supported by the temperature-dependent electron concentration measurements. -- Abstract: The n-type GaN layers were grown by plasma-assisted MBE and either intentionally doped with Si or unintentionally doped. The optical characteristics ofmore » a donor level in Si-doped, GaN were studied in terms of photoluminescence (PL) spectroscopy as a function of electron concentration. Temperature dependent PL measurements allowed us to estimate the activation energy of a Si-related donor from temperature-induced decay of PL intensity. PL peak positions, full width at half maximum of PL and activation energies are found to be proportional to the cube root of carrier density. The involvement of donor levels is supported by the temperature-dependent electron concentration measurements.« less

Density functional study of structural and electronic properties of Al{sub n}@C{sub 60}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhiman, Shobhna, E-mail: s-dhiman@hotmail.com; Kumar, Ranjan; Dharamvir, Keya

2014-04-24

Fullerene derivatives have been shown to make contributions in many types of applications. Ab initio investigation of structural and electronic properties of aluminum doped endohedral fullerene has been performed using numerical atomic orbital density functional theory. We have obtained ground state structures for Al{sub n}@C{sub 60} (n=1–10). Which shows that C{sub 60} molecule can accommodate maximum of nine aluminum atoms, for n > 9 the cage eventually break. Encapsulated large number of aluminum atoms leads to deformation of cage with diameter varies from 7.16Å to 7.95Å. Binding energy/Al atom is found to increase till n = 4 and after thatmore » it decreases with the number of Al atoms with a sudden increase for n=10 due to breakage of C{sub 60} cage and electronic affinity first increases till n=4 then it decreases up to n=9 with a sharp increase for n=10. Ionization potential also first increases and then decreases. Homo-Lumo gap decreases till n=3 with a sharp increase for n=4, after that it shows an oscillatory nature. The results obtained are consistent with available theoretical and experimental results. The ab-initio calculations were performed using SIESTA code with generalized gradient approximation (GGA)« less

Sodankylä ionospheric tomography data set 2003-2014

NASA Astrophysics Data System (ADS)

Norberg, Johannes; Roininen, Lassi; Kero, Antti; Raita, Tero; Ulich, Thomas; Markkanen, Markku; Juusola, Liisa; Kauristie, Kirsti

2016-07-01

Sodankylä Geophysical Observatory has been operating a receiver network for ionospheric tomography and collecting the produced data since 2003. The collected data set consists of phase difference curves measured from COSMOS navigation satellites from the Russian Parus network (Wood and Perry, 1980) and tomographic electron density reconstructions obtained from these measurements. In this study vertical total electron content (VTEC) values are integrated from the reconstructed electron densities to make a qualitative and quantitative analysis to validate the long-term performance of the tomographic system. During the observation period, 2003-2014, there were three to five operational stations at the Fennoscandia sector. Altogether the analysis consists of around 66 000 overflights, but to ensure the quality of the reconstructions, the examination is limited to cases with descending (north to south) overflights and maximum elevation over 60°. These constraints limit the number of overflights to around 10 000. Based on this data set, one solar cycle of ionospheric VTEC estimates is constructed. The measurements are compared against the International Reference Ionosphere (IRI)-2012 model, F10.7 solar flux index and sunspot number data. Qualitatively the tomographic VTEC estimate corresponds to reference data very well, but the IRI-2012 model results are on average 40 % higher than that of the tomographic results.

Using sewage sludge pyrolytic gas to modify titanium alloy to obtain high-performance anodes in bio-electrochemical systems

NASA Astrophysics Data System (ADS)

Gu, Yuan; Ying, Kang; Shen, Dongsheng; Huang, Lijie; Ying, Xianbin; Huang, Haoqian; Cheng, Kun; Chen, Jiazheng; Zhou, Yuyang; Chen, Ting; Feng, Huajun

2017-12-01

Titanium is under consideration as a potential stable bio-anode because of its high conductivity, suitable mechanical properties, and electrochemical inertness in the operating potential window of bio-electrochemical systems; however, its application is limited by its poor electron-transfer capacity with electroactive bacteria and weak ability to form biofilms on its hydrophobic surface. This study reports an effective and low-cost way to convert a hydrophobic titanium alloy surface into a hydrophilic surface that can be used as a bio-electrode with higher electron-transfer rates. Pyrolytic gas of sewage sludge is used to modify the titanium alloy. The current generation, anodic biofilm formation surface, and hydrophobicity are systematically investigated by comparing bare electrodes with three modified electrodes. Maximum current density (15.80 A/m2), achieved using a modified electrode, is 316-fold higher than that of the bare titanium alloy electrode (0.05 A/m2) and that achieved by titanium alloy electrodes modified by other methods (12.70 A/m2). The pyrolytic gas-modified titanium alloy electrode can be used as a high-performance and scalable bio-anode for bio-electrochemical systems because of its high electron-transfer rates, hydrophilic nature, and ability to achieve high current density.

Control of malodorous hydrogen sulfide compounds using microbial fuel cell.

PubMed

Eaktasang, Numfon; Min, Hyeong-Sik; Kang, Christina; Kim, Han S

2013-10-01

In this study, a microbial fuel cell (MFC) was used to control malodorous hydrogen sulfide compounds generated from domestic wastewaters. The electricity production demonstrated a distinct pattern of a two-step increase during 170 h of system run: the first maximum current density was 118.6 ± 7.2 mA m⁻² followed by a rebound of current density increase, reaching the second maximum of 176.8 ± 9.4 mA m⁻². The behaviors of the redox potential and the sulfate level in the anode compartment indicated that the microbial production of hydrogen sulfide compounds was suppressed in the first stage, and the hydrogen sulfide compounds generated from the system were removed effectively as a result of their electrochemical oxidation, which contributed to the additional electricity production in the second stage. This was also directly supported by sulfur deposits formed on the anode surface, which was confirmed by analyses on those solids using a scanning electron microscope equipped with energy dispersive X-ray spectroscopy as well as an elemental analyzer. To this end, the overall reduction efficiencies for HS⁻ and H₂S(g) were as high as 67.5 and 96.4 %, respectively. The correlations among current density, redox potential, and sulfate level supported the idea that the electricity signal generated in the MFC can be utilized as a potential indicator of malodor control for the domestic wastewater system.

Electronic torsional sound in linear atomic chains: Chemical energy transport at 1000 km/s

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kurnosov, Arkady A.; Rubtsov, Igor V.; Maksymov, Andrii O.

2016-07-21

We investigate entirely electronic torsional vibrational modes in linear cumulene chains. The carbon nuclei of a cumulene are positioned along the primary axis so that they can participate only in the transverse and longitudinal motions. However, the interatomic electronic clouds behave as a torsion spring with remarkable torsional stiffness. The collective dynamics of these clouds can be described in terms of electronic vibrational quanta, which we name torsitons. It is shown that the group velocity of the wavepacket of torsitons is much higher than the typical speed of sound, because of the small mass of participating electrons compared to themore » atomic mass. For the same reason, the maximum energy of the torsitons in cumulenes is as high as a few electronvolts, while the minimum possible energy is evaluated as a few hundred wavenumbers and this minimum is associated with asymmetry of zero point atomic vibrations. Theory predictions are consistent with the time-dependent density functional theory calculations. Molecular systems for experimental evaluation of the predictions are proposed.« less

Energetic particle signatures of satellites and rings in Neptune's magnetosphere

NASA Technical Reports Server (NTRS)

Selesnick, R. S.; Stone, E. C.

1992-01-01

The cosmic ray system on Voyager 2 found a trapped radiation environment in Neptune's inner magnetosphere which is controlled primarily by absorption at the rings and satellite surfaces. The intensity of electrons with kinetic energies approximately greater than 1 MeV shows particularly strong and narrow signatures associated with absorption by the satellite 1989N1 at an orbital radius of 4.75 Neptune radii. Closer to the planet are several signatures of the inner satellites and rings. Absorption limits the intensity of the inner radiation belt sufficiently for the maximum intensity to occur outside the orbit of 1989N1 at a magnetic L shell of about 7. Radial profiles of the electron phase space density show that electrons diffuse inward from a source in the outer magnetosphere. Many of the inward-diffusing electrons are absorbed upon reaching a satellite orbital radius, but the finite absorption efficiency allows some of the electrons to pass by unaffected. The locations of the satellite and ring signatures also provide constraints on the nondipolar components of the planetary magnetic field.

Electron and phonon transport in Co-doped FeV0.6Nb0.4Sb half-Heusler thermoelectric materials

NASA Astrophysics Data System (ADS)

Fu, Chenguang; Liu, Yintu; Xie, Hanhui; Liu, Xiaohua; Zhao, Xinbing; Jeffrey Snyder, G.; Xie, Jian; Zhu, Tiejun

2013-10-01

The electron and phonon transport characteristics of n-type Fe1-xCoxV0.6Nb0.4Sb half-Heusler thermoelectric compounds is analyzed. The acoustic phonon scattering is dominant in the carrier transport. The deformation potential of Edef = 14.1 eV and the density of state effective mass m* ≈ 2.0 me are derived under a single parabolic band assumption. The band gap is calculated to be ˜0.3 eV. Electron and phonon mean free paths are estimated based on the low and high temperature measurements. The electron mean free path is higher than the phonon one above room temperature, which is consistent with the experimental result that the electron mobility decreases more than the lattice thermal conductivity by grain refinement to enhance boundary scattering. A maximum ZT value of ˜0.33 is obtained at 650 K for x = 0.015, an increase by ˜60% compared with FeVSb. The optimal doping level is found to be ˜3.0 × 1020 cm-3 at 600 K.

Development and Validation of the Whole Atmosphere Community Climate Model With Thermosphere and Ionosphere Extension (WACCM-X 2.0)

NASA Astrophysics Data System (ADS)

Liu, Han-Li; Bardeen, Charles G.; Foster, Benjamin T.; Lauritzen, Peter; Liu, Jing; Lu, Gang; Marsh, Daniel R.; Maute, Astrid; McInerney, Joseph M.; Pedatella, Nicholas M.; Qian, Liying; Richmond, Arthur D.; Roble, Raymond G.; Solomon, Stanley C.; Vitt, Francis M.; Wang, Wenbin

2018-02-01

Key developments have been made to the NCAR Whole Atmosphere Community Climate Model with thermosphere and ionosphere extension (WACCM-X). Among them, the most important are the self-consistent solution of global electrodynamics, and transport of O+ in the F-region. Other ionosphere developments include time-dependent solution of electron/ion temperatures, metastable O+ chemistry, and high-cadence solar EUV capability. Additional developments of the thermospheric components are improvements to the momentum and energy equation solvers to account for variable mean molecular mass and specific heat, a new divergence damping scheme, and cooling by O(3P) fine structure. Simulations using this new version of WACCM-X (2.0) have been carried out for solar maximum and minimum conditions. Thermospheric composition, density, and temperatures are in general agreement with measurements and empirical models, including the equatorial mass density anomaly and the midnight density maximum. The amplitudes and seasonal variations of atmospheric tides in the mesosphere and lower thermosphere are in good agreement with observations. Although global mean thermospheric densities are comparable with observations of the annual variation, they lack a clear semiannual variation. In the ionosphere, the low-latitude E × B drifts agree well with observations in their magnitudes, local time dependence, seasonal, and solar activity variations. The prereversal enhancement in the equatorial region, which is associated with ionospheric irregularities, displays patterns of longitudinal and seasonal variation that are similar to observations. Ionospheric density from the model simulations reproduces the equatorial ionosphere anomaly structures and is in general agreement with observations. The model simulations also capture important ionospheric features during storms.

Fibroblast contractility and growth in plastic compressed collagen gel scaffolds with microstructures correlated with hydraulic permeability.

PubMed

Serpooshan, Vahid; Muja, Naser; Marelli, Benedetto; Nazhat, Showan N

2011-03-15

Scaffold microstructure is hypothesized to influence physical and mechanical properties of collagen gels, as well as cell function within the matrix. Plastic compression under increasing load was conducted to produce scaffolds with increasing collagen fibrillar densities ranging from 0.3 to above 4.1 wt % with corresponding hydraulic permeability (k) values that ranged from 1.05 to 0.03 μm², as determined using the Happel model. Scanning electron microscopy revealed that increasing the level of collagen gel compression yielded a concomitant reduction in pore size distribution and a slight increase in average fibril bundle diameter. Decreasing k delayed the onset of contraction and significantly reduced both the total extent and the maximum rate of contraction induced by NIH3T3 fibroblasts seeded at a density of either 6.0 x 10⁴ or 1.5 x 10⁵ cells mL⁻¹. At the higher cell density, however, the effect of k reduction on collagen gel contraction was overcome by an accelerated onset of contraction which led to an increase in both the total extent and the maximum rate of contraction. AlamarBlue™ measurements indicated that the metabolic activity of fibroblasts within collagen gels increased as k decreased. Moreover, increasing seeded cell density from 2.0 x 10⁴ to 1.5 x 10⁵ cells mL⁻¹ significantly increased NIH3T3 proliferation. In conclusion, fibroblast-matrix interactions can be optimized by defining the microstructural properties of collagen scaffolds through k adjustment which in turn, is dependent on the cell seeding density. Copyright © 2011 Wiley Periodicals, Inc.

Design, modeling, and diagnostics of microplasma generation at microwave frequency

NASA Astrophysics Data System (ADS)

Miura, Naoto

Plasmas are partially ionized gases that find wide utility in the processing of materials, especially in integrated circuit fabrication. Most industrial applications of plasma occur in near-vacuum where the electrons are hot (>10,000 K) but the gas remains near room temperature. Typical atmospheric plasmas, such as arcs, are hot and destructive to sensitive materials. Recently the emerging field of microplasmas has demonstrated that atmospheric ionization of cold gases is possible if the plasma is microscopic. This dissertation investigates the fundamental physical properties of two classes of microplasma, both driven by microwave electric fields. The extension of point-source microplasmas into a line-shaped plasma is also described. The line-shape plasma is important for atmospheric processing of materials using roll-coating. Microplasma generators driven near 1 GHz were designed using microstrip transmission lines and characterized using argon near atmospheric pressure. The electrical characteristics of the microplasma including the discharge voltage, current and resistance were estimated by comparing the experimental power reflection coefficient to that of an electromagnetic simulation. The gas temperature, argon metastable density and electron density were obtained by optical absorption and emission spectroscopy. The microscopic internal plasma structure was probed using spatially-resolved diode laser absorption spectroscopy of excited argon states. The spatially resolved diagnostics revealed that argon metastable atoms were depleted within the 200mum core of the microplasma where the electron density was maximum. Two microplasma generators, the split-ring resonator (SRR) and the transmission line (T-line) generator, were compared. The SRR ran efficiently with a high impedance plasma (>1000 O) and was stabilized by the self-limiting of absorbed power (<1W) as a lower impedance plasma caused an impedance mismatch. Gas temperatures were <1000 K and electron densities were ~1020 m-3, conditions which are favorable for treatment of delicate materials. The T-line generator ran most efficiently with an intense, low impedance plasma that matched the impedance of the T-line (35 O). With the T-line generator, the absorbed power could exceed 20W, which created an electron density of 1021 m-3, but the gas temperature exceeded 2000 K. Finally, line-shaped microplasmas based on resonant and non-resonant configurations were developed, tested, and analyzed.

Recombination-pumped XUV lasing in capillary discharges and dynamic z-pinches

NASA Astrophysics Data System (ADS)

Pöckl, M.; Hebenstreit, M.; Fertner, R.; Neger, T.; Aumayr, F.

1996-08-01

A fully time-dependent collisional - radiative model is employed to calculate relevant population densities in a recombining carbon/hydrogen z-pinch plasma. In particular, the dependence of the small signal gain G on the maximum electron temperature and cooling rate, as well as the influence of Lyman-0022-3727/29/8/005/img8 reabsorption, are studied. Although in conditions typical for dynamic z-pinches the maximum electron temperature and cooling rates would, in principle, be sufficiently high, gain on the Balmer-0022-3727/29/8/005/img8 transition is strongly reduced by Lyman-0022-3727/29/8/005/img8 reabsorption. In order to investigate vacuum spark capillary discharges, the system of rate equations is coupled with balance equations of the plasma energy and the total number of heavy particles. The resulting set of equations is solved self-consistently. Results are presented that show the systematic dependence of the small signal gain on electrical input power, wall material, and capillary geometry. High gain coefficients 0022-3727/29/8/005/img11 could be achieved by modelling high-voltage discharges with short ringing periods through capillaries containing boron or carbon. While the maximum achievable gain coefficient for lithium is rather poor 0022-3727/29/8/005/img12 the duration of population inversion would be long enough (a few tens of nanoseconds) to make multi-pass operation possible.

40 CFR Appendix B to Subpart II to... - Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density B Appendix B to Subpart II to Part 63 Protection of...—Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density EC01MY92.046 ...

40 CFR Appendix B to Subpart II to... - Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 11 2012-07-01 2012-07-01 false Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density B Appendix B to Subpart II to Part 63 Protection of...—Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density EC01MY92.046 ...

40 CFR Appendix B to Subpart II of... - Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 11 2014-07-01 2014-07-01 false Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density B Appendix B to Subpart II of Part 63 Protection of...—Maximum Allowable Thinning Rates as a Function of As Supplied VOC Content and Thinner Density EC01MY92.046 ...

47 CFR 25.212 - Narrowband analog transmissions and digital transmissions in the GSO Fixed Satellite Service.

Code of Federal Regulations, 2013 CFR

2013-10-01

... kHz if the maximum input power spectral density into the antenna does not exceed −8 dBW/4 kHz and the maximum transmitted satellite carrier EIRP density does not exceed 17 dBW/4 kHz. (2) In the 14.0... services, if the maximum input spectral power density into the antenna does not exceed −14 dBW/4 kHz, and...

Growth and Deposition of Inorganic Nutrient Elements in Developing Leaves of Zea mays L. 1

PubMed Central

Meiri, Avraham; Silk, Wendy Kuhn; Läuchli, André

1992-01-01

Spatial distributions of growth and of the concentration of some inorganic nutrient elements were analyzed in developing leaves of maize (Zea mays L.). Growth was analyzed by pinprick experiments with numerical analysis to characterize fields of velocity and relative elemental elongation rate. Inductively coupled plasma and atomic emission spectroscopy were used to measure nutrients extracted from segments of leaf tissue collected by position. Leaves 7 and 8, both elongating 3 millimeters per hour had maximum relative elemental growth rates of 0.06 to 0.08 millimeters per hour with maximum rates 20 to 50 millimeters from the node and cessation of growth by 90 millimeters from the node. Spatial distribution of dry weight density revealed that the rate of biomass deposition was maximum in the most rapidly expanding region and continued beyond the elongation zone. The nutrient elements K, Cl, Ca, Mg, and P showed different distribution patterns of ion density (on a dry weight basis). K and Cl had minimal density in the leaf tips; K density was maximum in the growing region, whereas Cl density was maximum at the region of growth cessation. Ca, Mg, and P had relatively high densities at the base of the elongation zone near the node and also in the tip regions. Near the node, P and Mg densities were higher in the young, growing leaves, whereas Ca density near the node was higher in older leaves that had completed elongation. Deposition rates of all nutrients were greatest in the region of maximum elongation rate. PMID:16669027

Geometric isomerism in pentacoordinate Cu2+ complexes: equilibrium, kinetic, and density functional theory studies reveal the existence of equilibrium between square pyramidal and trigonal bipyramidal forms for a tren-derived ligand.

PubMed

Algarra, Andrés G; Basallote, Manuel G; Castillo, Carmen E; Clares, M Paz; Ferrer, Armando; García-España, Enrique; Llinares, José M; Máñez, M Angeles; Soriano, Conxa

2009-02-02

A ligand (L1) (bis(aminoethyl)[2-(4-quinolylmethyl)aminoethyl]amine) containing a 4-quinolylmethyl group attached to one of the terminal amino groups of tris(2-aminoethyl)amine (tren) has been prepared, and its protonation constants and stability constants for the formation of Cu(2+) complexes have been determined. Kinetic studies on the formation of Cu(2+) complexes in slightly acidic solutions and on the acid-promoted complex decomposition strongly suggest that the Cu(2+)-L1 complex exists in solution as a mixture of two species, one of them showing a trigonal bipyramidal (tbp) coordination environment with an absorption maximum at 890 nm in the electronic spectrum, and the other one being square pyramidal (sp) with a maximum at 660 nm. In acidic solution only a species with tbp geometry is formed, whereas in neutral and basic solutions a mixture of species with tbp and sp geometries is formed. The results of density functional theory (DFT) calculations indicate that these results can be rationalized by invoking the existence of an equilibrium of hydrolysis of the Cu-N bond with the amino group supporting the quinoline ring so that CuL1(2+) would be actually a mixture of tbp [CuL1(H(2)O)](2+) and sp [CuL1(H(2)O)(2)](2+). As there are many Cu(2+)-polyamine complexes with electronic spectra that show two overlapping bands at wavelengths close to those observed for the Cu(2+)-L1 complex, the existence of this kind of equilibrium between species with two different geometries can be quite common in the chemistry of these compounds. A correlation found between the position of the absorption maximum and the tau parameter measuring the distortion from the idealized tbp and sp geometries can be used to estimate the actual geometry in solution of this kind of complex.

Real-time reconstruction of topside ionosphere scale height from coordinated GPS-TEC and ionosonde observations

NASA Astrophysics Data System (ADS)

Gulyaeva, Tamara; Poustovalova, Ljubov

The International Reference Ionosphere model extended to the plasmasphere, IRI-Plas, has been recently updated for assimilation of total electron content, TEC, derived from observations with Global Navigation Satellite System, GNSS. The ionosonde products of the F2 layer peak density (NmF2) and height (hmF2) ensure true electron density maximum at the F2 peak. The daily solar and magnetic indices used by IRI-Plas code are compiled in data files including the 3-hour ap and kp magnetic index from 1958 onward, 12-monthly smoothed sunspot number R12 and Global Electron Content GEC12, daily solar radio flux F10.7 and daily sunspot number Ri. The 3-h ap-index is available in Real Time, RT, mode from GFZ, Potsdam, Germany, daily update of F10.7 is provided by Space Weather Canada service, and daily estimated international sunspot number Ri is provided by Solar Influences Data Analysis Center, SIDC, Belgium. For IRI-Plas-RT operation in regime of the daily update and prediction of the F2 layer peak parameters, the proxy kp and ap forecast for 3 to 24 hours ahead based on data for preceding 12 hours is applied online at http://www.izmiran.ru/services/iweather/. The topside electron density profile of IRI-Plas code is expressed with complementary half-peak density anchor height above hmF2 which corresponds to transition O+/H+ height. The present investigation is focused on reconstruction of topside ionosphere scale height using vertical total electron content (TEC) data derived from the Global Positioning System GPS observations and the ionosonde derived F2 layer peak parameters from 25 observatories ingested into IRI-Plas model. GPS-TEC and ionosonde measurements at solar maximum (September, 2002, and October, 2003) for quiet, positively disturbed, and negatively disturbed days of the month are used to obtain the topside scale height, Htop, representing the range of altitudes from hmF2 to the height where NmF2 decay by e times occurs. Mapping of the F2 layer peak parameters and TEC allows interpolate these parameters at coordinated grid sites from independent GPS receivers and ionosondes data. Exponential scale height Htop exceeds scale height HT of the α-Chapman layer by 3 times - the latter refers to a narrow altitude range from hmF2 to the height of 1.2 times decay of NmF2. While typical quiet daytime value of the topside scale height is around 200 km, it can be enhanced by 2-3 times during the negative phase of the ionospheric storm as it is captured by IRI-Plas-RT model ingesting the F2 peak and TEC data. This study is supported by the joint grant of RFBR 13-02-91370-CT_a and TUBITAK 112E568.

NASA Astrophysics Data System (ADS)

Wang, Mao-Hua; Zhang, Bo; Zhou, Fu

2014-07-01

Silica was homogeneously coated on the surface of CaCu3Ti4O12 (CCTO) particles via the sol-gel method. The obtained powders were characterized by x-ray diffraction analysis, Fourier-transform infrared spectroscopy, transmission electron microscopy (TEM), energy-dispersive spectroscopy, scanning electron microscopy, and zeta potential analysis. The results demonstrate that there were silica layers on the surface of the CCTO particles. Physical and dielectric properties of silica-coated CCTO were also studied. TEM imaging showed that the thickness of the silica layer on the CCTO particles was about 20 nm to 35 nm. The specimen coated with 1.0 wt.% silica showed the maximum relative density of 96.7% with high dielectric constant (12.78 × 104) and low dielectric loss (0.005) at 20°C after sintering at 1000°C for 6 h.

Galvanic displacement assembly of ultrathin Co3O4 nanosheet arrays on nickel foam for a high-performance supercapacitor

NASA Astrophysics Data System (ADS)

You, Yuxiu; Zheng, Maojun; Ma, Liguo; Yuan, Xiaoliang; Zhang, Bin; Li, Qiang; Wang, Faze; Song, Jingnan; Jiang, Dongkai; Liu, Pengjie; Ma, Li; Shen, Wenzhong

2017-03-01

High-performance supercapacitors are very desirable for many portable electronic devices, electric vehicles and high-power electronic devices. Herein, a facile and binder-free synthesis method, galvanic displacement of the precursor followed by heat treatment, is used to fabricate ultrathin Co3O4 nanosheet arrays on nickel foam substrate. When used as a supercapacitor electrode the prepared Co3O4 on nickel foam exhibits a maximum specific capacitance of 1095 F g-1 at a current density of 1 A g-1 and good cycling stability of 71% retention after 2000 cycling tests. This excellent electrochemical performance can be ascribed to the high specific surface area of each Co3O4 nanosheet that comprises numerous nanoparticles.

Lithium salt doped conjugated polymers as electron transporting materials for highly efficient blue polymer light-emitting diodes

NASA Astrophysics Data System (ADS)

Huang, Fei; Shih, Ping-I.; Liu, Michelle S.; Shu, Ching-Fong; Jen, Alex K.-Y.

2008-12-01

Highly efficient blue polymer light-emitting diodes (PLEDs) are fabricated using a conjugated polymer, poly[9,9-bis(2-(2-(2-diethanol-amino-ethoxy) ethoxy) ethyl) fluorene-alt-4, 4'-phenylether] as an electron transporting layer (ETL). It was found that the performance of these blue-emitting devices could be greatly improved if the ETL was doped with LiF or Li2CO3 salts. A bis[(4,6-di-fluorophenyl)-pyridinato-N, C2] (picolinate) Ir(III) (FIrpic) complex based blue phosphorescent PLED exhibited a maximum luminance efficiency of 20.3 cd/A with a luminance of 1600 cd/m2 at the current density of 7.9 mA/cm2 and drive voltage of 8.0 V.

Wigner crystalline edges in ν<~1 quantum dots

NASA Astrophysics Data System (ADS)

Goldmann, Eyal; Renn, Scot R.

1999-12-01

We investigate the edge reconstruction phenomenon believed to occur in quantum dots in the quantum Hall regime when the filling fraction is ν<~1. Our approach involves the examination of large dots (<= 40 electrons) using a partial diagonalization technique in which the occupancies of the deep interior orbitals are frozen. To interpret the results of this calculation, we evaluate the overlap between the diagonalized ground state and a set of trial wave functions which we call projected necklace (PN) states. A PN state is simply the angular momentum projection of a maximum density droplet surrounded by a ring of localized electrons. Our calculations reveal that PN states have up to 99% overlap with the diagonalized ground states, and are lower in energy than the states identified in Chamon and Wen's study of the edge reconstruction.

Feasibility study of surface-modified carbon cloth electrodes using atmospheric pressure plasma jets for microbial fuel cells

NASA Astrophysics Data System (ADS)

Chang, Shih-Hang; Liou, Jyun-Sian; Liu, Jung-Liang; Chiu, Yi-Fan; Xu, Chang-Han; Chen, Bor-Yann; Chen, Jian-Zhang

2016-12-01

This study investigated the surface and electrochemical properties of carbon cloth electrodes surface-modified by using atmospheric pressure plasma jets (APPJs) for applications involving microbial fuel cells (MFCs). APPJ treatment made the carbon cloth highly hydrophilic and did not introduce any observable cracks or flaws. MFCs configured with APPJ-treated carbon cloth electrodes exhibited electrochemical performance (maximum power density of 7.56 mW m-2) superior to that of MFCs configured with untreated carbon cloth electrodes (maximum power density of 2.38 mW m-2). This boost in performance can be attributed to the formation of abundant carboxyl and ammonium functional groups on the surface of APPJ-treated carbon cloth, which promoted the formation of anodic biofilms and the adhesion of bacteria, while facilitating the transfer of electrons from the bacteria to the electrodes. APPJ surface modification is non-toxic and environmentally friendly (no exogenous chemicals are required), which is particularly beneficial as the introduction of toxins might otherwise inhibit bacterial growth and metabolism. The APPJ surface modification process is rapid, cost-effective, and applicable to substrates covering a large area, making it ideal for the fabrication of large-scale MFCs and bioelectrochemical bioenergy devices.

Design optimization of PVDF-based piezoelectric energy harvesters.

PubMed

Song, Jundong; Zhao, Guanxing; Li, Bo; Wang, Jin

2017-09-01

Energy harvesting is a promising technology that powers the electronic devices via scavenging the ambient energy. Piezoelectric energy harvesters have attracted considerable interest for their high conversion efficiency and easy fabrication in minimized sensors and transducers. To improve the output capability of energy harvesters, properties of piezoelectric materials is an influential factor, but the potential of the material is less likely to be fully exploited without an optimized configuration. In this paper, an optimization strategy for PVDF-based cantilever-type energy harvesters is proposed to achieve the highest output power density with the given frequency and acceleration of the vibration source. It is shown that the maximum power output density only depends on the maximum allowable stress of the beam and the working frequency of the device, and these two factors can be obtained by adjusting the geometry of piezoelectric layers. The strategy is validated by coupled finite-element-circuit simulation and a practical device. The fabricated device within a volume of 13.1 mm 3 shows an output power of 112.8 μW which is comparable to that of the best-performing piezoceramic-based energy harvesters within the similar volume reported so far.

The Structure of Titan's Ionosphere from 10 Years of Cassini Measurements: Solar Cycle and Saturn Local Time Dependence

NASA Astrophysics Data System (ADS)

Edberg, N. J. T.; Kurth, W. S.; Gurnett, D. A.; Andrews, D. J.; Vigren, E.; Shebanits, O.; Agren, K.; Wahlund, J. E.; Opgenoorth, H. J.; Holmberg, M.; Jackman, C. M.; Cravens, T.; Bertucci, C.; Dougherty, M. K.

2014-12-01

We present measurements from the Cassini Radio and Plasma Wave Science/Langmuir probe (RPWS/LP) instrument of the electron density in the ionosphere of Titan from the first ~100 flybys (2004-2014). After more than 10 years of measurements a good number of measurements exists from Titan's ionosphere. This allows for statistical studies of the structure of Titan's ionosphere. The electron density has been shown to vary significantly from one flyby to the next, as well as on longer time scales and here we discern some of the reasons for the observed ionospheric variability. Firstly, following the rise to the recent solar maximum we show how the ionospheric peak density, normalized to a common solar zenith angle, Nnorm clearly varies with the ~11-year solar cycle. Nnorm correlates well with the solar energy flux Fe and we find that Nnorm ∝ Fek, with k = 0.54 ± 0.18, which is close to the theoretical value of 0.5. Secondly, we present results that indicate that the ionospheric density in the topside ionosphere (altitude range 1200-2400 km) are generally significantly increased, roughly by a factor of 2, when Titan is located in the post-midnight sector of Saturn, i.e. at Saturn local times 00 - 03 h, compared to other local time sectors. We suggest that this increase could be caused by additional particle impact ionization from reconnection events in the Saturn tail.

Location-Control of Large Si Grains by Dual-Beam Excimer-Laser and Thick Oxide Portion

NASA Astrophysics Data System (ADS)

Ishihara, Ryoichi; Burtsev, Artyom; Alkemade, Paul F. A.

2000-07-01

An array of large Si grains was placed at a predetermined position by dual excimer-laser irradiation of a multi-layer structure of silicon (Si), silicon dioxide (SiO2) with an array of bumps and metal on a glass substrate. We have investigated the effects of irradiating energy density and the topology of the structure on the grain size and crystallographic structure by scanning electron microscopy (SEM) and electron back-scattering pattern (EBSP) analysis. In the low-energy-density regime, numerous small grains and petal shaped grains formed on top of the SiO2 bumps. The number of small grains on the bumps decreased with increasing irradiating energy density. At sufficiently high energy densities, one single Si grain as large as 3.5 μm was positioned at the center of the bumps. Although most of the area of the large Si grain has a single crystallographic orientation, twins and low-angle grain boundaries are often formed at the periphery of the grain. There was no preferred crystallographic orientation in the center of the location-controlled Si grain. Numerical analysis of the temperature profile showed that a temperature drop occurs at the center of the bump, during and immediately after laser irradiation. The diameter of the location-controlled Si grain increased with total thickness of the intermediate SiO2 layer, and took the maximum value of 6.2 μm.