On the semiannual change in exospheric temperature.

NASA Technical Reports Server (NTRS)

Titheridge, J. E.

1972-01-01

Discussion of some uncertainties about the semiannual density variations of the neutral atmosphere at heights above 100 km ascribed by Jacchia (1965), on the basis of long observations of the decay of satellite orbits, to changes in exosphere temperature, but later, because of some difficulties, attributed by Jacchia (1971) to semiannual density variations that may not be produced primarily by changes in temperature. Temperature values derived from ionosphere electron content data recorded since 1965 at several sites in New Zealand using the Faraday rotation of geostationary satellite signals and from their comparison with ionosonde measurements are shown to suggest that the semiannual variations represent primarily changes in temperature and only secondarily in density.

Implantable, Ingestible Electronic Thermometer

NASA Technical Reports Server (NTRS)

Kleinberg, Leonard

1987-01-01

Small quartz-crystal-controlled oscillator swallowed or surgically implanted provides continuous monitoring of patient's internal temperature. Receiver placed near patient measures oscillator frequency, and temperature inferred from previously determined variation of frequency with temperature. Frequency of crystal-controlled oscillator varies with temperature. Circuit made very small and implanted or ingested to measure internal body temperature.

Temperature Dependent Electron Transport Properties of Gold Nanoparticles and Composites: Scanning Tunneling Spectroscopy Investigations.

PubMed

Patil, Sumati; Datar, Suwarna; Dharmadhikari, C V

2018-03-01

Scanning tunneling spectroscopy (STS) is used for investigating variations in electronic properties of gold nanoparticles (AuNPs) and its composite with urethane-methacrylate comb polymer (UMCP) as function of temperature. Films are prepared by drop casting AuNPs and UMCP in desired manner on silicon substrates. Samples are further analyzed for morphology under scanning electron microscopy (SEM) and atomic force microscopy (AFM). STS measurements performed in temperature range of 33 °C to 142 °C show systematic variation in current versus voltage (I-V) curves, exhibiting semiconducting to metallic transition/Schottky behavior for different samples, depending upon preparation method and as function of temperature. During current versus time (I-t) measurement for AuNPs, random telegraphic noise is observed at room temperature. Random switching of tunneling current between two discrete levels is observed for this sample. Power spectra derived from I-t show 1/f2 dependence. Statistical analysis of fluctuations shows exponential behavior with time width τ ≈ 7 ms. Local density of states (LDOS) plots derived from I-V curves of each sample show systematic shift in valance/conduction band edge towards/away from Fermi level, with respect to increase in temperature. Schottky emission is best fitted electron emission mechanism for all samples over certain range of bias voltage. Schottky plots are used to calculate barrier heights and temperature dependent measurements helped in measuring activation energies for electron transport in all samples.

The radial gradients and collisional properties of solar wind electrons

NASA Technical Reports Server (NTRS)

Gilvie, K. W.; Scudder, J. D.

1977-01-01

The plasma instrument on Mariner 10 carried out measurements of electron density and temperature in the interplanetary medium between heliocentric distances of 0.85 and 0.45 AU. Due to the stable coronal configuration and low solar activity during the period of observation, the radial variations of these quantities could be obtained. The power-law exponent of the core temperature was measured to be -0.3 + or - 0.04, and the halo temperature was found to be almost independent of heliocentric distance. The exponent of the power law for the density variation was 2.5 + or - 0.2 and the extrapolated value at 1 AU was consistent with measured values during the same period. Calculations of the core electron self-collision time, and the core-halo equipartition time were made as a function of radial distance. These measurements indicate a macroscale picture of a Coulomb-collisional core and a collisionless isothermal halo. Extrapolating back to the sun, core and halo temperatures become equal at a radial distance of approx. 2-15 radii.

The effect of dust charge variation, due to ion flow and electron depletion, on dust levitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Land, Victor; Douglass, Angela; Qiao Ke

2011-11-29

Using a fluid model, the plasma densities, electron temperature and ion Mach number in front of a powered electrode in different plasma discharges is computed. The dust charge is computed using OML theory for Maxwellian electrons and ions distributed according to a shifted-Maxwellian. By assuming force balance between gravity and the electrostatic force, the dust levitation height is obtained. The importance of the dust charge variation is investigated.

Temporal variations of electron density and temperature in Kr/Ne/H2 photoionized plasma induced by nanosecond pulses from extreme ultraviolet source

NASA Astrophysics Data System (ADS)

Saber, I.; Bartnik, A.; Wachulak, P.; Skrzeczanowski, W.; Jarocki, R.; Fiedorowicz, H.

2017-06-01

Spectral investigations of low-temperature photoionized plasmas created in a Kr/Ne/H2 gas mixture were performed. The low-temperature plasmas were generated by gas mixture irradiation using extreme ultraviolet pulses from a laser-plasma source. Emission spectra in the ultraviolet/visible range from the photoionized plasmas contained lines that mainly corresponded to neutral atoms and singly charged ions. Temporal variations in the plasma electron temperature and electron density were studied using different characteristic emission lines at various delay times. Results, based on Kr II lines, showed that the electron temperature decreased from 1.7 to 0.9 eV. The electron densities were estimated using different spectral lines at each delay time. In general, except for the Hβ line, in which the electron density decreased from 3.78 × 1016 cm-3 at 200 ns to 5.77 × 1015 cm-3 at 2000 ns, most of the electron density values measured from the different lines were of the order of 1015 cm-3 and decreased slightly while maintaining the same order when the delay time increased. The time dependences of the measured and simulated intensities of a spectral line of interest were also investigated. The validity of the partial or full local thermodynamic equilibrium (LTE) conditions in plasma was explained based on time-resolved electron density measurements. The partial LTE condition was satisfied for delay times in the 200 ns to 1500 ns range. The results are summarized, and the dominant basic atomic processes in the gas mixture photoionized plasma are discussed.

First principles electronic and thermal properties of some AlRE intermetallics

NASA Astrophysics Data System (ADS)

Srivastava, Vipul; Sanyal, Sankar P.; Rajagopalan, M.

2008-10-01

A study on structural and electronic properties of non-magnetic cubic B 2-type AlRE (RE=Sc, Y, La, Ce, Pr and Lu) intermetallics has been done theoretically. The self-consistent tight binding linear muffin tin orbital method is used to describe the electronic properties of these intermetallics at ambient and at high pressure. These compounds show metallic behavior under ambient conditions. The variation of density of states under compression indicates some possibility of structural phase transformation in AlLa, AlCe and AlPr. Thermal properties like Debye temperature and Grüneisen constant are calculated at T=0 K and at ambient pressure within the Debye-Grüneisen model and compared with the others’ theoretical results. Our results are in good agreement. We have also performed a pressure-induced variation of Debye temperature and have found a decrease in Debye temperature around 40 kbar in AlRE (RE=La, Ce, Pr) intermetallics.

Hydrogen partitioning and transport in titanium aluminides

NASA Technical Reports Server (NTRS)

Han, Kwang S.; Lee, Weon S.

1993-01-01

This report gives the final summary of the research work perfomed from March 1, 1990 to August 28, 1993. Brief descriptions of the research findings are given on the surface variation of Ti-14Al-21Nb as a function of temperature under ultrahigh vacuum conditions; titanium aluminides: surface composition effects as a function of temperature; Auger electron intensity variation in oxygen-charged silver; and segregation of sulfur on a titanium surface studied by Auger electron spectroscopy. Each description details one or more of the attached corresponding figures. Published journal documents are provided as appendices to give further detail.

SiGe Based Low Temperature Electronics for Lunar Surface Applications

NASA Technical Reports Server (NTRS)

Mojarradi, Mohammad M.; Kolawa, Elizabeth; Blalock, Benjamin; Cressler, John

2012-01-01

The temperature at the permanently shadowed regions of the moon's surface is approximately -240 C. Other areas of the lunar surface experience temperatures that vary between 120 C and -180 C during the day and night respectively. To protect against the large temperature variations of the moon surface, traditional electronics used in lunar robotics systems are placed inside a thermally controlled housing which is bulky, consumes power and adds complexity to the integration and test. SiGe Based electronics have the capability to operate over wide temperature range like that of the lunar surface. Deploying low temperature SiGe electronics in a lander platform can minimize the need for the central thermal protection system and enable the development of a new generation of landers and mobility platforms with highly efficient distributed architecture. For the past five years a team consisting of NASA, university and industry researchers has been examining the low temperature and wide temperature characteristic of SiGe based transistors for developing electronics for wide temperature needs of NASA environments such as the Moon, Titan, Mars and Europa. This presentation reports on the status of the development of wide temperature SiGe based electronics for the landers and lunar surface mobility systems.

A note on anomalous band-gap variations in semiconductors with temperature

NASA Astrophysics Data System (ADS)

Chakraborty, P. K.; Mondal, B. N.

2018-03-01

An attempt is made to theoretically study the band-gap variations (ΔEg) in semiconductors with temperature following the works, did by Fan and O'Donnell et al. based on thermodynamic functions. The semiconductor band-gap reflects the bonding energy. An increase in temperature changes the chemical bondings, and electrons are promoted from valence band to conduction band. In their analyses, they made several approximations with respect to temperature and other fitting parameters leading to real values of band-gap variations with linear temperature dependences. In the present communication, we have tried to re-analyse the works, specially did by Fan, and derived an analytical model for ΔEg(T). Because, it was based on the second-order perturbation technique of thermodynamic functions. Our analyses are made without any approximations with respect to temperatures and other fitting parameters mentioned in the text, leading to a complex functions followed by an oscillating nature of the variations of ΔEg. In support of the existence of the oscillating energy band-gap variations with temperature in a semiconductor, possible physical explanations are provided to justify the experimental observation for various materials.

Measurement of density and temperature in a hypersonic turbulent boundary layer using the electron beam fluorescence technique. Ph.D. Thesis. Final Report, 1 Oct. 1969 - 1 Sep. 1972

NASA Technical Reports Server (NTRS)

Mcronald, A. D.

1975-01-01

Mean density and temperature fluctuations were measured across the turbulent, cooled-wall boundary layer in a continuous hypersonic (Mach 9.4) wind tunnel in air, using the nitrogen fluorescence excited by a 50 kV electron beam. Data were taken at three values of the tunnel stagnation pressure, the corresponding free stream densities being equivalent to 1.2, 4.0, and 7.4 torr at room temperature, and the boundary layer thicknesses about 4.0, 4.5, and 6.0 inches. The mean temperature and density profiles were similar to those previously determined in the same facility by conventional probes (static and pitot pressure, total temperature). A static pressure variation of about 50% across the boundary layer was found, the shape of the variation changing somewhat for the three stagnation pressure levels. The quadrupole model for rotational temperature spectra gave closer agreement with the free stream isentropic level (approximately 44 K) than the dipole model.

Density functional and theoretical study of the temperature and pressure dependency of the plasmon energy of solids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Attarian Shandiz, M., E-mail: mohammad.attarianshandiz@mail.mcgill.ca; Gauvin, R.

The temperature and pressure dependency of the volume plasmon energy of solids was investigated by density functional theory calculations. The volume change of crystal is the major factor responsible for the variation of valence electron density and plasmon energy in the free electron model. Hence, to introduce the effect of temperature and pressure for the density functional theory calculations of plasmon energy, the temperature and pressure dependency of lattice parameter was used. Also, by combination of the free electron model and the equation of state based on the pseudo-spinodal approach, the temperature and pressure dependency of the plasmon energy wasmore » modeled. The suggested model is in good agreement with the results of density functional theory calculations and available experimental data for elements with the free electron behavior.« less

First-principles investigations into the thermodynamics of cation disorder and its impact on electronic structure and magnetic properties of spinel Co(Cr1-x Mn x )2O4.

PubMed

Das, Debashish; Ghosh, Subhradip

2017-02-08

Cation disorder over different crystallographic sites in spinel oxides is known to affect their properties. Recent experiments on Mn doped multiferroic [Formula: see text] indicate that a possible distribution of Mn atoms among tetrahedrally and octahedrally coordinated sites in the spinel lattice give rise to different variations in the structural parameters and saturation magnetisations in different concentration regimes of Mn atoms substituting the Cr. A composition dependent magnetic compensation behaviour points to the role conversions of the magnetic constituents. In this work, we have investigated the thermodynamics of cation disorder in [Formula: see text] system and its consequences on the structural, electronic and magnetic properties, using results from first-principles electronic structure calculations. We have computed the variations in the cation-disorder as a function of Mn concentration and the temperature and found that at the annealing temperature of the experiment many of the systems exhibit cation disorder. Our results support the interpretations of the experimental results regarding the qualitative variations in the sub-lattice occupancies and the associated magnetisation behaviour, with composition. We have analysed the variations in structural, magnetic and electronic properties of this system with variations in the compositions and the degree of cation disorder from the variations in their electronic structures and by using the ideas from crystal field theory. Our study provides a complete microscopic picture of the effects that are responsible for composition dependent behavioural differences of the properties of this system. This work lays down a general framework, based upon results from first-principles calculations, to understand and analyse the substitutional magnetic spinel oxides [Formula: see text] in presence of cation disorder.

Energy relaxation of intense laser pulse-produced plasmas

NASA Astrophysics Data System (ADS)

Shihab, M.; Abou-Koura, G. H.; El-Siragy, N. M.

2016-05-01

We describe a collisional radiative model (CRE) of homogeneously expanded nickel plasmas in vacuum. The CRE model is coupled with two separate electron and ion temperature magneto-hydrodynamic equations. On the output, the model provides the temporal variation of the electron temperature, ion temperature, and average charge state. We demonstrate the effect of three-body recombination ({∝}N_e T^{-9/2}_e) on plasma parameters, as it changes the time dependence of electron temperature from t^{-2} to t^{-1} and exhibits a pronounced effect leading to a freezing feature in the average charge state. In addition, the effect of the three-body recombination on the warm up of ions and delaying the equilibration is addressed.

Mid-Latitude Ionospheric Disturbances Due to Geomagnetic Storms at ISS Altitudes

NASA Technical Reports Server (NTRS)

Minow, Joseph I.; Willis, Emily M.; Neergaard Parker, Linda

2014-01-01

Spacecraft charging of the International Space Station (ISS) is dominated by interaction of the US high voltage solar arrays with the F2-region ionosphere plasma environment. ISS solar array charging is enhanced in a high electron density environment due to the increased thermal electron currents to the edges of the solar cells. High electron temperature environments suppress charging due to formation of barrier potentials on the charged solar cell cover glass that restrict the charging currents to the cell edge [Mandell et al., 2003]. Environments responsible for strong solar array charging are therefore characterized by high electron densities and low electron temperatures. In support of the ISS space environmental effects engineering community, we are working to understand a number of features of solar array charging and to determine how well future charging behavior can be predicted from in-situ plasma density and temperature measurements. One aspect of this work is a need to characterize the magnitude of electron density and temperature variations that occur at ISS orbital altitudes (approximately 400 km) over time scales of days, the latitudes over which significant variations occur, and the time periods over which the disturbances persist once they start. This presentation provides examples of mid-latitude electron density and temperature disturbances at altitudes relevant to ISS using data sets and tools developed for our ISS plasma environment study. "Mid-latitude" is defined as the extra-tropical region between approx. 30 degrees to approx. 60 degrees magnetic latitude sampled by ISS over its 51.6 degree inclination orbit. We focus on geomagnetic storm periods because storms are well known drivers for disturbances in the ionospheric plasma environment.

Scaling of confinement and profiles in the EXTRAP T2 reversed-field pinch

NASA Astrophysics Data System (ADS)

Welander, A.

1999-01-01

In the EXTRAP T2 reversed-field pinch the diagnostic techniques for the measurement of electron density and temperature include; Thomson scattering which gives values at three radial positions in the core (r/a = 0, 0.28, 0.56), Langmuir probes which give values at the edge (r/a > 0.9) and interferometry which gives a line-averaged density. The empirical scaling of electron density and temperature including profile information with global plasma parameters has been studied. The density profile is subject to large variations, with an average parabolic shape when the density is low and flatter shapes when the density is increased. The change in the profile shape can be attributed to a shift in the penetration length of neutrals from the vicinity of the wall. The temperature scales roughly as I/n1/2 where I is the plasma current and n is the density. The temperature profile is always quite flat with lower variations and there is a tendency for a flatter profile at higher temperatures.

Axial- and radial-resolved electron density and excitation temperature of aluminum plasma induced by nanosecond laser: Effect of the ambient gas composition and pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dawood, Mahmoud S.; Hamdan, Ahmad, E-mail: ahmad.ba.hamdan@gmail.com, E-mail: Joelle.margot@umontreal.ca; Margot, Joëlle, E-mail: ahmad.ba.hamdan@gmail.com, E-mail: Joelle.margot@umontreal.ca

2015-11-15

The spatial variation of the characteristics of an aluminum plasma induced by a pulsed nanosecond XeCl laser is studied in this paper. The electron density and the excitation temperature are deduced from time- and space- resolved Stark broadening of an ion line and from a Boltzmann diagram, respectively. The influence of the gas pressure (from vacuum up to atmospheric pressure) and compositions (argon, nitrogen and helium) on these characteristics is investigated. It is observed that the highest electron density occurs near the laser spot and decreases by moving away both from the target surface and from the plume center tomore » its edge. The electron density increases with the gas pressure, the highest values being occurred at atmospheric pressure when the ambient gas has the highest mass, i.e. in argon. The excitation temperature is determined from the Boltzmann plot of line intensities of iron impurities present in the aluminum target. The highest temperature is observed close to the laser spot location for argon at atmospheric pressure. It decreases by moving away from the target surface in the axial direction. However, no significant variation of temperature occurs along the radial direction. The differences observed between the axial and radial direction are mainly due to the different plasma kinetics in both directions.« less

Constructiveness and destructiveness of temperature in asymmetric quantum pseudo dot qubit system

NASA Astrophysics Data System (ADS)

Chen, Ying-Jie; Song, Hai-Tao; Xiao, Jing-Lin

2018-06-01

By using the variational method of the Pekar type, we theoretically study the temperature effects on the asymmetric quantum pseudo dot qubit with a pseudoharmonic potential under an electromagnetic field. The numerical results are analyzed and discussed in detail and show that the relationships of the ground and first excited state energies, the electron oscillation period and the electron probability density in the superposition state of the ground state and the first-excited state with the temperature, the chemical potential, the pseudoharmonic potential, the electric field strength, the cyclotron frequency, the electron phonon coupling constant, the transverse and longitudinal effective confinement length, respectively.

Dust Acoustic Solitary Waves in Dusty Plasma with Trapped Electrons Having Different Temperature Nonthermal Ions

NASA Astrophysics Data System (ADS)

Deka, Manoj Kr.

2016-12-01

In this report, a detailed investigation on the study of dust acoustics solitary waves solution with negatively dust charge fluctuation in dusty plasma corresponding to lower and higher temperature nonthermal ions with trapped electrons is presented. We consider temporal variation of dust charge as a source of dissipation term to derive the lower order modified Kadomtsev-Petviashvili equation by using the reductive perturbation technique. Solitary wave solution is obtained with the help of sech method in presence of trapped electrons and low (and high) temperature nonthermal ions. Both nonthermality of ions and trapped state of the electrons are found to have an imperative control on the nonlinear coefficient, dissipative coefficient as well as height of the wave potential.

The Effect of Temperature and Electric Field on a Quantum Pseudodot Qubit

NASA Astrophysics Data System (ADS)

Chen, Ying-Cong; Xiao, Jing-Lin

2018-02-01

The electron's probability density (EPD) and the oscillating period (OP) of an electron confined by a three-dimensional RbCl quantum pseudodot (QPD) are studied. Calculations are performed by employing variational method of Pekar type (VMPT) and the quantum statistics theory (QST).The influences of the temperature and electric field on the EPD and the OP of the RbCl QPD qubit have been derived in detail. According to the obtained results, it is observed that the EPD and the OP increase (decrease) with raising temperature at lower (higher) temperature region. They are decaying functions of the electric field.

MAVEN observations of electron temperatures in the dayside ionosphere at Mars

NASA Astrophysics Data System (ADS)

Sakai, S.; Cravens, T.; Andersson, L.; Fowler, C. M.; Thiemann, E.; Eparvier, F. G.; Bougher, S. W.; Rahmati, A.; Reedy, N. L.; Mitchell, D. L.; Mazelle, C. X.; Mahaffy, P. R.; Jakosky, B. M.

2016-12-01

The Mars Atmosphere and Volatile EvolutioN (MAVEN) have observed the ionospheric electron temperature at Mars since November 2014. The only in-situ measurements of plasma temperatures were provided by the two Viking landers in 1976 before the MAVEN mission. The ionospheric electron temperatures are particularly important for determining the neutral escape rate from the atmosphere of Mars. We have investigated the electron temperatures on the dayside ionosphere using the Langmuir Probe and Waves instrument onboard MAVEN. The temperatures are studied in two regions of (1) the crustal magnetic field and (2) the solar wind/induced (or draped) magnetic field. We also focused on how temperatures vary with solar zenith angle (SZA) and the solar extreme ultraviolet (EUV) irradiances. The electron temperatures did not vary much due to the SZA variation, but increased when the solar EUV irradiances are high. This means the ionospheric temperatures are sensitive to the solar activity. Furthermore, we investigated the correlation of electron temperatures against magnetic field configurations under the same EUV irradiances. The electron temperatures in the crustal region were lower than those in the draped region. One possible explanation is that the energy input from high altitude, which is related to the tail and solar wind electrons, might control the temperatures in the draped region. Vertical heat conductance in the draped region could also affect the electron temperatures (with a greater effect in the draped region), so that electrons cooled at low altitude tend to transport to high altitude. However, the electron heating is more local in the draped region, and the electrons would be heated efficiently. Therefore, the electron temperatures in the draped region were higher than those in the crustal region. It is implied that the rate of atmospheric escape, which is attributed to photochemical escape, depends on the topology of the magnetic fields.

Self-Correcting Electronically-Scanned Pressure Sensor

NASA Technical Reports Server (NTRS)

Gross, C.; Basta, T.

1982-01-01

High-data-rate sensor automatically corrects for temperature variations. Multichannel, self-correcting pressure sensor can be used in wind tunnels, aircraft, process controllers and automobiles. Offers data rates approaching 100,000 measurements per second with inaccuracies due to temperature shifts held below 0.25 percent (nominal) of full scale over a temperature span of 55 degrees C.

Enhanced specific heat jump in electron-doped CaMnO3: Spin ordering driven by charge separation

NASA Astrophysics Data System (ADS)

Moritomo, Y.; Machida, A.; Nishibori, E.; Takata, M.; Sakata, M.

2001-12-01

Temperature variation of the magnetic susceptibility χ, resistivity ρ, specific heat C, and lattice constants has been investigated in electron-doped CaMnO3. The parent CaMnO3 is an antiferromagnetic band insulator, and shows an insulator-metal crossover with electron doping, together with an enhanced ferromagnetic component. We have found an enhancement of the specific heat jump ΔC at the spin-ordering temperature Tspin and interpreted the enhancement in terms of the intrinsic charge separation.

Temperature and magnetic field effects on electron transport through DNA molecules in a two-dimensional four-channel system.

PubMed

Joe, Yong S; Lee, Sun H; Hedin, Eric R; Kim, Young D

2013-06-01

We utilize a two-dimensional four-channel DNA model, with a tight-binding (TB) Hamiltonian, and investigate the temperature and the magnetic field dependence of the transport behavior of a short DNA molecule. Random variation of the hopping integrals due to the thermal structural disorder, which partially destroy phase coherence of electrons and reduce quantum interference, leads to a reduction of the localization length and causes suppressed overall transmission. We also incorporate a variation of magnetic field flux density into the hopping integrals as a phase factor and observe Aharonov-Bohm (AB) oscillations in the transmission. It is shown that for non-zero magnetic flux, the transmission zero leaves the real-energy axis and moves up into the complex-energy plane. We also point out that the hydrogen bonds between the base pair with flux variations play a role to determine the periodicity of AB oscillations in the transmission.

Improving temperature monitoring in the vaccine cold chain at the periphery: an intervention study using a 30-day electronic refrigerator temperature logger (Fridge-tag).

PubMed

Kartoğlu, Umit; Nelaj, Erida; Maire, Denis

2010-05-28

This intervention study was conducted in Albania to establish the superiority of the Fridge-tag (30-day electronic refrigerator temperature logger) against thermometers. Intervention sites used Fridge-tag and a modified temperature control record sheet, while control sites continued with their routine operation with thermometers. All refrigerators in both groups were equipped with downloadable electronic data loggers to record temperatures for reference. Focus group sessions were conducted with involved staff to discuss temperature monitoring, Fridge-tag use and its user-friendliness. Significant discrepancies were observed between thermometer readings and the electronic data loggers in control sites, while all alarms from Fridge-tag were confirmed in the intervention group. Thermometers are not sufficient to monitor temperatures in refrigerators since they miss the great majority of low and high alarms. Fridge-tag has proven to be an effective tool in providing health workers with the information they need to take the necessary actions when there are refrigerator temperature variations. (c) 2010 Elsevier Ltd. All rights reserved.

Important Variation in Vibrational Properties of LiFePO4 and FePO4 Induced by Magnetism

PubMed Central

Seifitokaldani, Ali; Gheribi, Aïmen E.; Phan, Anh Thu; Chartrand, Patrice; Dollé, Mickaël

2016-01-01

A new thermodynamically self-consistent (TSC) method, based on the quasi-harmonic approximation (QHA), is used to obtain the Debye temperatures of LiFePO4 (LFP) and FePO4 (FP) from available experimental specific heat capacities for a wide temperature range. The calculated Debye temperatures show an interesting critical and peculiar behavior so that a steep increase in the Debye temperatures is observed by increasing the temperature. This critical behavior is fitted by the critical function and the adjusted critical temperatures are very close to the magnetic phase transition temperatures in LFP and FP. Hence, the critical behavior of the Debye temperatures is correlated with the magnetic phase transitions in these compounds. Our first-principle calculations support our conjecture that the change in electronic structures, i.e. electron density of state and electron localization function, and consequently the change in thermophysical properties due to the magnetic transition may be the reason for the observation of this peculiar behavior of the Debye temperatures. PMID:27604551

Important Variation in Vibrational Properties of LiFePO4 and FePO4 Induced by Magnetism

NASA Astrophysics Data System (ADS)

Seifitokaldani, Ali; Gheribi, Aïmen E.; Phan, Anh Thu; Chartrand, Patrice; Dollé, Mickaël

2016-09-01

A new thermodynamically self-consistent (TSC) method, based on the quasi-harmonic approximation (QHA), is used to obtain the Debye temperatures of LiFePO4 (LFP) and FePO4 (FP) from available experimental specific heat capacities for a wide temperature range. The calculated Debye temperatures show an interesting critical and peculiar behavior so that a steep increase in the Debye temperatures is observed by increasing the temperature. This critical behavior is fitted by the critical function and the adjusted critical temperatures are very close to the magnetic phase transition temperatures in LFP and FP. Hence, the critical behavior of the Debye temperatures is correlated with the magnetic phase transitions in these compounds. Our first-principle calculations support our conjecture that the change in electronic structures, i.e. electron density of state and electron localization function, and consequently the change in thermophysical properties due to the magnetic transition may be the reason for the observation of this peculiar behavior of the Debye temperatures.

Important Variation in Vibrational Properties of LiFePO4 and FePO4 Induced by Magnetism.

PubMed

Seifitokaldani, Ali; Gheribi, Aïmen E; Phan, Anh Thu; Chartrand, Patrice; Dollé, Mickaël

2016-09-08

A new thermodynamically self-consistent (TSC) method, based on the quasi-harmonic approximation (QHA), is used to obtain the Debye temperatures of LiFePO4 (LFP) and FePO4 (FP) from available experimental specific heat capacities for a wide temperature range. The calculated Debye temperatures show an interesting critical and peculiar behavior so that a steep increase in the Debye temperatures is observed by increasing the temperature. This critical behavior is fitted by the critical function and the adjusted critical temperatures are very close to the magnetic phase transition temperatures in LFP and FP. Hence, the critical behavior of the Debye temperatures is correlated with the magnetic phase transitions in these compounds. Our first-principle calculations support our conjecture that the change in electronic structures, i.e. electron density of state and electron localization function, and consequently the change in thermophysical properties due to the magnetic transition may be the reason for the observation of this peculiar behavior of the Debye temperatures.

Investigation of AlGaN/GaN HEMTs degradation with gate pulse stressing at cryogenic temperature

NASA Astrophysics Data System (ADS)

Wang, Ning; Wang, Hui; Lin, Xinpeng; Qi, Yongle; Duan, Tianli; Jiang, Lingli; Iervolino, Elina; Cheng, Kai; Yu, Hongyu

2017-09-01

Degradation on DC characteristics of AlGaN/GaN high electron mobility transistors (HEMTs) after applying pulsed gate stress at cryogenic temperatures is presented in this paper. The nitrogen vacancy near to the AlGaN/GaN interface leads to threshold voltage of stress-free sample shifting positively at low temperature. The anomalous behavior of threshold voltage variation (decrease first and then increase) under gate stressing as compared to stress-free sample is observed when lowing temperature. This can be correlated with the pre-existing electron traps in SiNX layer or at SiNX/AlGaN interface which can be de-activated and the captured electrons inject back to channel with lowering temperature, which counterbalances the influence of nitrogen vacancy on threshold voltage shift.

Electron temperatures and densities in the venus ionosphere: pioneer venus orbiter electron temperature probe results.

PubMed

Brace, L H; Theis, R F; Krehbiel, J P; Nagy, A F; Donahue, T M; McElroy, M B; Pedersen, A

1979-02-23

Altitude profiles of electron temperature and density in the ionosphere of Venus have been obtained by the Pioneer Venus orbiter electron temperatutre probe. Elevated temperatutres observed at times of low solar wind flux exhibit height profiles that are consistent with a model in which less than 5 percent of the solar wind energy is deposited at the ionopause and is conducted downward through an unmagnetized ionosphere to the region below 200 kilomneters where electron cooling to the neutral atmosphere proceeds rapidly. When solar wind fluxes are higher, the electron temperatures and densities are highly structured and the ionopause moves to lower altitudes. The ionopause height in the late afternoon sector observed thus far varies so widely from day to (day that any height variation with solar zenith angle is not apparent in the observations. In the neighborhood of the ionopause, measuremnents of plasma temperatures and densities and magnetic field strength indicate that an induced magnetic barrier plays an important role in the pressure transfer between the solar wind and the ionosphere. The bow, shock is marked by a distinct increase in electron current collected by the instrument, a featutre that provides a convenient identification of the bow shock location.

Electronic structures and abnormal phonon behaviors of cobalt-modified Na0.5Bi0.5TiO3-6%BaTiO3 single crystals

NASA Astrophysics Data System (ADS)

Huang, T.; Zhang, P.; Xu, L. P.; Chen, C.; Zhang, J. Z.; Hu, Z. G.; Luo, H. S.; Chu, J. H.

2016-10-01

Optical properties, electronic structures, and structural variations of x wt% cobalt (Co) doped Na0.5Bi0.5TiO3-6%BaTiO3 (x=0%, 0.5%, 0.8%) single crystals have been studied by temperature-dependent optical ellipsometry and Raman spectra from 250 to 650 K. Based on the temperature evolution of electronic transitions (Ecp1 and Ecp2) and the phonon modes involving Ti-O vibrations, two critical temperature points exhibit an increasing trend with Co dopants, which are related to structural variations for ferroelectric to anti-ferroelectric, and anti-ferroelectric to paraelectric transition, respectively. Additionally, distinguishing abnormal phonon behaviors can be observed from Raman spectra for the crystal of x=0.5% and 0.8%, which show reverse frequency shift of the modes involving Ti-O vibration. It can be ascribed to different relative concentration of Co2+ and Co3+ in the crystals, which has been confirmed by X-ray Photoelectron Spectroscopy data.

Winter nighttime ion temperatures and energetic electrons from OGO 6 plasma measurements

NASA Technical Reports Server (NTRS)

Sanatani, S.; Breig, E. L.

1981-01-01

In the reported investigation, ion temperature and suprathermal electron flux data were acquired with the retarding potential analyzer on board the OGO 6 satellite when it was in solar eclipse. Attention is given to measurements in the 400- to 800-km height interval between midnight and predawn in the northern winter nonpolar ionosphere. Statistical analysis of data recorded during a 1 month time span permits a decoupling of horizontal and altitude effects. A distinct longitudinal variation is observed for ion temperature above 500 km, with a significant relative enhancement over the western North Atlantic. Altitude distributions of ion temperature are compatible with Millstone Hill profiles within the common region of this enhancement. Large fluxes of energetic electrons are observed and extend to much lower geomagnetic latitudes in the same longitude sector.

Effect of Synthesis Parameter on Crystal Structures and Magnetic Properties of Magnesium Nickel Ferrite (Mg0.5Ni0.5Fe2O4) Nanoparticles

NASA Astrophysics Data System (ADS)

Maulia, R.; Putra, R. A.; Suharyadi, E.

2017-05-01

Mg0.5Ni0.5Fe2O4 nanoparticles have been successfully synthesized by using co-precipitation method and varying the synthesis parameter, i.e. synthesis temperature and NaOH concentration. X-ray Diffraction (XRD) pattern showed that nanoparticles have cubic spinel structures with an additional phase of γ-Fe2O3 and particle size varies within the range of 4.3 - 6.7 nm. This variation is due to the effect of various synthesis parameters. Transmission Electron Microscopy (TEM) image showed that the nanoparticles exhibited agglomeration. The observed diffraction ring from selected area electron diffraction showed that the sample was polycrystalline and confirmed the peak appearing in XRD. The coercivities showed an increasing trend with an increase in particle size from 44.7 Oe to 49.6 Oe for variation of NaOH concentration, and a decreasing trend with an increase in particle size from 46.8 to 45.1 Oe for variation of synthesis temperature. The maximum magnetization showed an increasing trend with an increase in the ferrite phase from 3.7 emu/g to 5.4 emu/g possessed in the sample with variations on NaOH concentration. The maximum magnetization for the sample with variations on synthesis temperature varied from 4.4 emu/g to 5.7 emu/g due to its crystal structures.

Phonon quarticity induced by changes in phonon-tracked hybridization during lattice expansion and its stabilization of rutile TiO 2

DOE PAGES

Lan, Tian; Li, Chen W.; Hellman, O.; ...

2015-08-11

Although the rutile structure of TiO 2 is stable at high temperatures, the conventional quasiharmonic approximation predicts that several acoustic phonons decrease anomalously to zero frequency with thermal expansion, incorrectly predicting a structural collapse at temperatures well below 1000 K. In this paper, inelastic neutron scattering was used to measure the temperature dependence of the phonon density of states (DOS) of rutile TiO 2 from 300 to 1373 K. Surprisingly, these anomalous acoustic phonons were found to increase in frequency with temperature. First-principles calculations showed that with lattice expansion, the potentials for the anomalous acoustic phonons transform from quadratic tomore » quartic, stabilizing the rutile phase at high temperatures. In these modes, the vibrational displacements of adjacent Ti and O atoms cause variations in hybridization of 3d electrons of Ti and 2p electrons of O atoms. Finally, with thermal expansion, the energy variation in this “phonon-tracked hybridization” flattens the bottom of the interatomic potential well between Ti and O atoms, and induces a quarticity in the phonon potential.« less

Study of thermal aging effects on the conduction and trapping of charges in XLPE cable insulations under electron beam irradiation

NASA Astrophysics Data System (ADS)

Boukezzi, L.; Rondot, S.; Jbara, O.; Boubakeur, A.

2018-08-01

The effect of thermal aging on the charging phenomena in cross-linked polyethylene (XLPE) has been studied under electron beam irradiation in scanning electron microscope (SEM). The dynamic variation of trapped charge represents the trapping process of XLPE under electron beam irradiation. We have found that the trapped charge variation can be approximated by a first order exponential function. The amount of trapped charge presents enhanced values at the beginning of aging at lower temperatures (80 °C and 100 °C). This suggests the diffusion of cross-linking by-products to the surface of sample that acts as traps for injected electrons. The oxidation which is a very important form of XLPE degradation has an effect at the advanced stage of the aging process. For higher temperatures (120 °C and 140 °C), the taken part process in the evolution of the trapped charge is the crystallinity increase at the beginning of aging leading to the trapped charge decreasing, and the polar groups generated by thermo-oxidation process at the end of aging leading to the trapped charge increase. Variations of leakage current according to the aging time have quite similar trends with the dielectric losses factor and consequently some correlations must be made between charging mechanisms and the electrical behaviour of XLPE under thermal aging.

Phonon transport in a curved aluminum thin film due to laser short pulse irradiation

NASA Astrophysics Data System (ADS)

Mansoor, Saad Bin; Yilbas, Bekir Sami

2018-05-01

Laser short-pulse heating of a curved aluminum thin film is investigated. The Boltzmann transport equation is incorporated to formulate the heating situation. A Gaussian laser intensity distribution is considered along the film arc and time exponentially decaying of pulse intensity is incorporated in the analysis. The governing equations of energy transport in the electron and lattice sub-systems are coupled through the electron-phonon coupling parameter. To quantify the phonon intensity distribution in the thin film, equivalent equilibrium temperature is introduced, which is associated with the average energy of all phonons around a local point when the phonon energies are redistributed adiabatically to an equilibrium state. It is found the numerical simulations that electron temperature follows similar trend to the spatial distribution of the laser pulse intensity at the film edge. Temporal variation of electron temperature does not follow the laser pulse intensity distribution. The rise of temperature in the electron sub-system is fast while it remains slow in the lattice sub-system.

First-principles investigations into the thermodynamics of cation disorder and its impact on electronic structure and magnetic properties of spinel Co(Cr1-x Mn x )2O4

NASA Astrophysics Data System (ADS)

Das, Debashish; Ghosh, Subhradip

2017-02-01

Cation disorder over different crystallographic sites in spinel oxides is known to affect their properties. Recent experiments on Mn doped multiferroic \\text{CoC}{{\\text{r}}2}{{\\text{O}}4} indicate that a possible distribution of Mn atoms among tetrahedrally and octahedrally coordinated sites in the spinel lattice give rise to different variations in the structural parameters and saturation magnetisations in different concentration regimes of Mn atoms substituting the Cr. A composition dependent magnetic compensation behaviour points to the role conversions of the magnetic constituents. In this work, we have investigated the thermodynamics of cation disorder in \\text{Co}{{≤ft(\\text{C}{{\\text{r}}1-x}\\text{M}{{\\text{n}}x}\\right)}2}{{\\text{O}}4} system and its consequences on the structural, electronic and magnetic properties, using results from first-principles electronic structure calculations. We have computed the variations in the cation-disorder as a function of Mn concentration and the temperature and found that at the annealing temperature of the experiment many of the systems exhibit cation disorder. Our results support the interpretations of the experimental results regarding the qualitative variations in the sub-lattice occupancies and the associated magnetisation behaviour, with composition. We have analysed the variations in structural, magnetic and electronic properties of this system with variations in the compositions and the degree of cation disorder from the variations in their electronic structures and by using the ideas from crystal field theory. Our study provides a complete microscopic picture of the effects that are responsible for composition dependent behavioural differences of the properties of this system. This work lays down a general framework, based upon results from first-principles calculations, to understand and analyse the substitutional magnetic spinel oxides A{{≤ft({{B}1-x}{{C}x}\\right)}2}{{\\text{O}}4} in presence of cation disorder.

Investigation of the temperature dependent field emission from individual ZnO nanowires for evidence of field-induced hot electrons emission.

PubMed

Chen, Yicong; Zhang, Zhipeng; Li, Zhi-Bing; She, Juncong; Deng, Shaozhi; Xu, Ning-Sheng; Chen, Jun

2018-06-27

ZnO nanowires as field emitters have important applications in flat panel display and X-ray source. Understanding the intrinsic field emission mechanism is crucial for further improving the performance of ZnO nanowire field emitters. In this article, the temperature dependent field emission from individual ZnO nanowires was investigated by an in-situ measurement in ultra-high vacuum. The divergent temperature-dependent Fowler-Nordheim plots is found in the low field region. A field-induced hot electrons emission model that takes into account penetration length is proposed to explain the results. The carrier density and temperature dependence of the field-induced hot electrons emission current are derived theoretically. The obtained results are consistent with the experimental results, which could be attributed to the variation of effective electron temperature. All of these are important for a better understanding on the field emission process of semiconductor nanostructures. © 2018 IOP Publishing Ltd.

Influence of oxygen-vacancy complex /A center/ on piezoresistance of n-type silicon.

NASA Technical Reports Server (NTRS)

Littlejohn, M. A.; Loggins, C. D., Jr.

1972-01-01

Changes in both magnitude and temperature dependence of the piezoresistance of electron-irradiated n-type silicon, induced by the latter's oxygen-vacancy complex (A center), are shown to be due to the fact that the presence of the A center causes the total conduction-band electron concentration to change with an applied stress. This change in electron concentration leads to an additional piezoresistance contribution that is expected to be important in certain many-valley semiconductors. This offers the possibility of tailoring the thermal variations of semiconductor mechanical sensors to more desirable values over limited temperature ranges.

Temperature and electrical memory of polymer fibers

NASA Astrophysics Data System (ADS)

Yuan, Jinkai; Zakri, Cécile; Grillard, Fabienne; Neri, Wilfrid; Poulin, Philippe

2014-05-01

We report in this work studies of the shape memory behavior of polymer fibers loaded with carbon nanotubes or graphene flakes. These materials exhibit enhanced shape memory properties with the generation of a giant stress upon shape recovery. In addition, they exhibit a surprising temperature memory with a peak of generated stress at a temperature nearly equal to the temperature of programming. This temperature memory is ascribed to the presence of dynamical heterogeneities and to the intrinsic broadness of the glass transition. We present recent experiments related to observables other than mechanical properties. In particular nanocomposite fibers exhibit variations of electrical conductivity with an accurate memory. Indeed, the rate of conductivity variations during temperature changes reaches a well defined maximum at a temperature equal to the temperature of programming. Such materials are promising for future actuators that couple dimensional changes with sensing electronic functionalities.

Altitude and intensity characteristics of parametric instability excited by an HF pump wave near the fifth electron harmonic

NASA Astrophysics Data System (ADS)

Jun, WU; Jian, WU; M, T. RIETVELD; I, HAGGSTROM; Haisheng, ZHAO; Zhengwen, XU

2017-12-01

An ionospheric heating experiment involving an O mode pump wave was carried out at European Incoherent Scatter Scientific Association site in Tromsø. The observation of the ultra high frequency radar illustrates the systematic variations of the enhanced ion line and plasma line in altitude and intensity as a function of the pump frequency. The analysis shows that those altitude variations are due to the thermal effect, and the intensity variations of the enhanced ion line are dependent on whether or not the enhanced ion acoustic wave satisfy the Bragg condition of radar. Moreover, a prediction that if the enhancement in electron temperature is suppressed, those systematic variations will be absent, is given.

Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, T.; Guo, S.; Xu, L. P.

2015-06-14

Optical properties and structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) single crystal have been studied by temperature-dependent optical ellipsometry and Raman spectroscopy from 4.2 to 300 K. The second derivative of the complex dielectric functions reveals two interband transitions (E{sub cp1} and E{sub cp2}) located at about 3.49 and 4.25 eV, respectively. Depending on the temperature evolution of electronic transitions, structural variations appear near 60, 150, and 240 K, respectively. These anomalies are also well illustrated from the low-frequency phonon modes involving vibrations of Bi. The low-temperature structural variations of NBT-7%BT crystal can be associated with instability of the crystalline latticemore » driven by off-centered Bi ions, followed by the variations of polarizability of the unit cells.« less

Reprint of : Hanbury-Brown Twiss noise correlation with time controlled quasi-particles in ballistic quantum conductors

NASA Astrophysics Data System (ADS)

Glattli, D. C.; Roulleau, P.

2016-08-01

We study the Hanbury Brown and Twiss correlation of electronic quasi-particles injected in a quantum conductor using current noise correlations and we experimentally address the effect of finite temperature. By controlling the relative time of injection of two streams of electrons it is possible to probe the fermionic antibunching, performing the electron analog of the optical Hong Ou Mandel (HOM) experiment. The electrons are injected using voltage pulses with either sine-wave or Lorentzian shape. In the latter case, we propose a set of orthogonal wavefunctions, describing periodic trains of multiply charged electron pulses, which give a simple interpretation to the HOM shot noise. The effect of temperature is then discussed and experimentally investigated. We observe a perfect electron anti-bunching for a large range of temperature, showing that, as recently predicted, thermal mixing of the states does not affect anti-bunching properties, a feature qualitatively different from dephasing. For single charge Lorentzian pulses, we provide experimental evidence of the prediction that the HOM shot noise variation versus the emission time delay is remarkably independent of the temperature.

Surface compositional variations of Mo-47Re alloy as a function of temperature

NASA Technical Reports Server (NTRS)

Hoekje, S. J.; Outlaw, R. A.; Sankaran, S. N.

1993-01-01

Molybdenum-rhenium alloys are candidate materials for the National Aero-Space Plane (NASP) as well as for other applications in generic hypersonics. These materials are expected to be subjected to high-temperature (above 1200 C) casual hydrogen (below 50 torr), which could potentially degrade the material strength. Since the uptake of hydrogen may be controlled by the contaminant surface barriers, a study of Mo-47Re was conducted to examine the variations in surface composition as a function of temperature from 25 C to 1000 C. Pure molybdenum and rhenium were also examined and the results compared with those for the alloy. The analytical techniques employed were Auger electron spectroscopy, electron energy loss spectroscopy, ion scattering spectroscopy, and x ray photoelectron spectroscopy. The native surface was rich in metallic oxides that disappeared at elevated temperatures. As the temperature increased, the carbon and oxygen disappeared by 800 C and the surface was subsequently populated by the segregation of silicon, presumably from the grain boundaries. The alloy readily chemisorbed oxygen, which disappeared with heating. The disappearance temperature progressively increased for successive dosings. When the alloy was exposed to 800 torr of hydrogen at 900 C for 1 hour, no hydrogen interaction was observed.

Non-monotonic behavior of electron temperature in argon inductively coupled plasma and its analysis via novel electron mean energy equation

NASA Astrophysics Data System (ADS)

Zhao, Shu-Xia

2018-03-01

In this work, the behavior of electron temperature against the power in argon inductively coupled plasma is investigated by a fluid model. The model properly reproduces the non-monotonic variation of temperature with power observed in experiments. By means of a novel electron mean energy equation proposed for the first time in this article, this electron temperature behavior is interpreted. In the overall considered power range, the skin effect of radio frequency electric field results in localized deposited power density, responsible for an increase of electron temperature with power by means of one parameter defined as power density divided by electron density. At low powers, the rate fraction of multistep and Penning ionizations of metastables that consume electron energy two times significantly increases with power, which dominates over the skin effect and consequently leads to the decrease of temperature with power. In the middle power regime, a transition region of temperature is given by the competition between the ionizing effect of metastables and the skin effect of electric field. The power location where the temperature alters its trend moves to the low power end as increasing the pressure due to the lack of metastables. The non-monotonic curve of temperature is asymmetric at the short chamber due to the weak role of skin effect in increasing the temperature and tends symmetric when axially prolonging the chamber. Still, the validity of the fluid model in this prediction is estimated and the role of neutral gas heating is guessed. This finding is helpful for people understanding the different trends of temperature with power in the literature.

A quasilinear kinetic model for solar wind electrons and protons instabilities

NASA Astrophysics Data System (ADS)

Sarfraz, M.; Yoon, P. H.

2017-12-01

In situ measurements confirm the anisotropic behavior in temperatures of solar wind species. These anisotropies associated with charge particles are observed to be relaxed. In collionless limit, kinetic instabilities play a significant role to reshape particles distribution. The linear analysis results are encapsulated in inverse relationship between anisotropy and plasma beta based observations fittings techniques, simulations methods, or solution of linearized Vlasov equation. Here amacroscopic quasilinear technique is adopted to confirm inverse relationship through solutions of set of self-consistent kinetic equations. Firstly, for a homogeneous and non-collisional medium, quasilinear kinetic model is employed to display asymptotic variations of core and halo electrons temperatures and saturations of wave energy densities for electromagnetic electron cyclotron (EMEC) instability sourced by, T⊥}>T{∥ . It is shown that, in (β ∥ , T⊥}/T{∥ ) phase space, the saturations stages of anisotropies associated with core and halo electrons lined up on their respective marginal stability curves. Secondly, for case of electrons firehose instability ignited by excessive parallel temperature i.e T⊥}>T{∥ , both electrons and protons are allowed to dynamically evolve in time. It is also observed that, the trajectories of protons and electrons at saturation stages in phase space of anisotropy and plasma beta correspond to proton cyclotron and firehose marginal stability curves, respectively. Next, the outstanding issue that most of observed proton data resides in nearly isotropic state in phase space is interpreted. Here, in quasilinear frame-work of inhomogeneous solar wind system, a set of self-consistent quasilinear equations is formulated to show a dynamical variations of temperatures with spatial distributions. On choice of different initial parameters, it is shown that, interplay of electron and proton instabilities provides an counter-balancing force to slow down the protons away from marginal stability states. As we are dealing both, protons and electrons for radially expanding solar wind plasma, our present approach may eventually be incorporated in global-kinetic models of the solar wind species.

Laser short-pulse heating of an aluminum thin film: Energy transfer in electron and lattice sub-systems

NASA Astrophysics Data System (ADS)

Bin Mansoor, Saad; Sami Yilbas, Bekir

2015-08-01

Laser short-pulse heating of an aluminum thin film is considered and energy transfer in the film is formulated using the Boltzmann equation. Since the heating duration is short and the film thickness is considerably small, thermal separation of electron and lattice sub-systems is incorporated in the analysis. The electron-phonon coupling is used to formulate thermal communication of both sub-systems during the heating period. Equivalent equilibrium temperature is introduced to account for the average energy of all phonons around a local point when they redistribute adiabatically to an equilibrium state. Temperature predictions of the Boltzmann equation are compared with those obtained from the two-equation model. It is found that temperature predictions from the Boltzmann equation differ slightly from the two-equation model results. Temporal variation of equivalent equilibrium temperature does not follow the laser pulse intensity in the electron sub-system. The time occurrence of the peak equivalent equilibrium temperature differs for electron and lattice sub-systems, which is attributed to phonon scattering in the irradiated field in the lattice sub-system. In this case, time shift is observed for occurrence of the peak temperature in the lattice sub-system.

Effect of temperature oscillation on thermal characteristics of an aluminum thin film

NASA Astrophysics Data System (ADS)

Ali, H.; Yilbas, B. S.

2014-12-01

Energy transport in aluminum thin film is examined due to temperature disturbance at the film edge. Thermal separation of electron and lattice systems is considered in the analysis, and temperature variation in each sub-system is formulated. The transient analysis of frequency-dependent and frequency-independent phonon radiative transport incorporating electron-phonon coupling is carried out in the thin film. The dispersion relations of aluminum are used in the frequency-dependent analysis. Temperature at one edge of the film is oscillated at various frequencies, and temporal response of phonon intensity distribution in the film is predicted numerically using the discrete ordinate method. To assess the phonon transport characteristics, equivalent equilibrium temperature is introduced. It is found that equivalent equilibrium temperature in the electron and lattice sub-systems oscillates due to temperature oscillation at the film edge. The amplitude of temperature oscillation reduces as the distance along the film thickness increases toward the low-temperature edge of the film. Equivalent equilibrium temperature attains lower values for the frequency-dependent solution of the phonon transport equation than that corresponding to frequency-independent solution.

Sensing sheet: the response of full-bridge strain sensors to thermal variations for detecting and characterizing cracks

NASA Astrophysics Data System (ADS)

Tung, S.-T.; Glisic, B.

2016-12-01

Sensing sheets based on large-area electronics consist of a dense array of unit strain sensors. This new technology has potential for becoming an effective and affordable monitoring tool that can identify, localize and quantify surface damage in structures. This research contributes to their development by investigating the response of full-bridge unit strain sensors to thermal variations. Overall, this investigation quantifies the effects of temperature on thin-film full-bridge strain sensors monitoring uncracked and cracked concrete. Additionally, an empirical formula is developed to estimate crack width given an observed strain change and a measured temperature change. This research led to the understanding of the behavior of full-bridge strain sensors installed on cracked concrete and exposed to temperature variations. It proves the concept of the sensing sheet and its suitability for application in environments with variable temperature.

Biophoton research in blood reveals its holistic properties.

PubMed

Voeikov, V L; Asfaramov, R; Bouravleva, E V; Novikov, C N; Vilenskaya, N D

2003-05-01

Monitoring of spontaneous and luminophore amplified photon emission (PE) from non-diluted human blood under resting conditions and artificially induced immune reaction revealed that blood is a continuous source of biophotons indicating that it persists in electronically excited state. This state is pumped through generation of electron excitation produced in reactive oxygen species (ROS) reactions. Excited state of blood and of neutrophil suspensions (primary sources of ROS in blood) is an oscillatory one suggesting of interaction between individual sources of electron excitation. Excited state of blood is extremely sensitive to the tiniest fluctuations of external photonic fields but resistant to temperature variations as reflected in hysteresis of PE in response to temperature variations. These data suggest that blood is a highly cooperative non-equilibrium and non-linear system, whose components unceasingly interact in time and space. At least in part this property is provided by the ability of blood to store energy of electron excitation that is produced in course of its own normal metabolism. From a practical point of view analysis of these qualities of blood may be a basement of new approach to diagnostic procedures.

Multi precursors analysis associated with the powerful Ecuador (MW = 7.8) earthquake of 16 April 2016 using Swarm satellites data in conjunction with other multi-platform satellite and ground data

NASA Astrophysics Data System (ADS)

Akhoondzadeh, Mehdi; De Santis, Angelo; Marchetti, Dedalo; Piscini, Alessandro; Cianchini, Gianfranco

2018-01-01

After DEMETER satellite mission (2004-2010), the launch of the Swarm satellites (Alpha (A), Bravo (B) and Charlie (C)) has created a new opportunity in the study of earthquake ionospheric precursors. Nowadays, there is no doubt that multi precursors analysis is a necessary phase to better understand the LAIC (Lithosphere Atmosphere Ionosphere Coupling) mechanism before large earthquakes. In this study, using absolute scalar magnetometer, vector field magnetometer and electric field instrument on board Swarm satellites, GPS (Global Positioning System) measurements, MODIS-Aqua satellite and ECMWF (European Centre for Medium-Range Weather Forecasts) data, the variations of the electron density and temperature, magnetic field, TEC (Total Electron Content), LST (Land Surface Temperature), AOD (Aerosol Optical Depth) and SKT (SKin Temperature) have been surveyed to find the potential seismic anomalies around the strong Ecuador (Mw = 7.8) earthquake of 16 April 2016. The four solar and geomagnetic indices: F10.7, Dst, Kp and ap were investigated to distinguish whether the preliminary detected anomalies might be associated with the solar-geomagnetic activities instead of the seismo-ionospheric anomalies. The Swarm satellites (A, B and C) data analysis indicate the anomalies in time series of electron density variations on 7, 11 and 12 days before the event; the unusual variations in time series of electron temperature on 8 days preceding the earthquake; the analysis of the magnetic field scalar and vectors data show the considerable anomalies 52, 48, 23, 16, 11, 9 and 7 days before the main shock. A striking anomaly is detected in TEC variations on 1 day before earthquake at 9:00 UTC. The analysis of MODIS-Aqua night-time images shows that LST increase unusually on 11 days prior to main shock. In addition, the AOD variations obtained from MODIS measurements reach the maximum value on 10 days before the earthquake. The SKT around epicentral region presents anomalous higher value about 40 days before the earthquake. It should be noted that the different lead times of the observed anomalies could be acknowledged based on a reasonable LAIC earthquake mechanism. Our results emphasize that the Swarm satellites measurements play an undeniable role in progress the studies of the ionospheric precursors.

Effect of cooler electrons on a compressive ion acoustic solitary wave in a warm ion plasma — Forbidden regions, double layers, and supersolitons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghosh, S. S., E-mail: sukti@iigs.iigm.res.in; Sekar Iyengar, A. N.

It is observed that the presence of a minority component of cooler electrons in a three component plasma plays a deterministic role in the evolution of solitary waves, double layers, or the newly discovered structures called supersolitons. The inclusion of the cooler component of electrons in a single electron plasma produces sharp increase in nonlinearity in spite of a decrease in the overall energy of the system. The effect maximizes at certain critical value of the number density of the cooler component (typically 15%–20%) giving rise to a hump in the amplitude variation profile. For larger amplitudes, the hump leadsmore » to a forbidden region in the ambient cooler electron concentration which dissociates the overall existence domain of solitary wave solutions in two distinct parameter regime. It is observed that an inclusion of the cooler component of electrons as low as < 1% affects the plasma system significantly resulting in compressive double layers. The solution is further affected by the cold to hot electron temperature ratio. In an adequately hotter bulk plasma (i.e., moderately low cold to hot electron temperature ratio), the parameter domain of compressive double layers is bounded by a sharp discontinuity in the corresponding amplitude variation profile which may lead to supersolitons.« less

Temperature dependence of attitude sensor coalignments on the Solar Maximum Mission (SMM)

NASA Technical Reports Server (NTRS)

Pitone, D. S.; Eudell, A. H.; Patt, F. S.

1990-01-01

The temperature correlation of the relative coalignment between the fine-pointing sun sensor and fixed-head star trackers measured on the Solar Maximum Mission (SMM) is analyzed. An overview of the SMM, including mission history and configuration, is given. Possible causes of the misalignment variation are discussed, with focus placed on spacecraft bending due to solar-radiation pressure, electronic or mechanical changes in the sensors, uncertainty in the attitude solutions, and mounting-plate expansion and contraction due to thermal effects. Yaw misalignment variation from the temperature profile is assessed, and suggestions for spacecraft operations are presented, involving methods to incorporate flight measurements of the temperature-versus-alignment function and its variance in operational procedures and the spacecraft structure temperatures in the attitude telemetry record.

Electron-impact vibrational relaxation in high-temperature nitrogen

NASA Technical Reports Server (NTRS)

Lee, Jong-Hun

1992-01-01

Vibrational relaxation process of N2 molecules by electron-impact is examined for the future planetary entry environments. Multiple-quantum transitions from excited states to higher/lower states are considered for the electronic ground state of the nitrogen molecule N2 (X 1Sigma-g(+)). Vibrational excitation and deexcitation rate coefficients obtained by computational quantum chemistry are incorporated into the 'diffusion model' to evaluate the time variations of vibrational number densities of each energy state and total vibrational energy. Results show a non-Boltzmann distribution of number densities at the earlier stage of relaxation, which in turn suppresses the equilibrium process but affects little the time variation of total vibrational energy. An approximate rate equation and a corresponding relaxation time from the excited states, compatible with the system of flow conservation equations, are derived. The relaxation time from the excited states indicates the weak dependency of the initial vibrational temperature. The empirical curve-fit formula for the improved e-V relaxation time is obtained.

Marcus Bell-Shaped Electron Transfer Kinetics Observed in an Arrhenius Plot.

PubMed

Waskasi, Morteza M; Kodis, Gerdenis; Moore, Ana L; Moore, Thomas A; Gust, Devens; Matyushov, Dmitry V

2016-07-27

The Marcus theory of electron transfer predicts a bell-shaped dependence of the reaction rate on the reaction free energy. The top of the "inverted parabola" corresponds to zero activation barrier when the electron-transfer reorganization energy and the reaction free energy add up to zero. Although this point has traditionally been reached by altering the chemical structures of donors and acceptors, the theory suggests that it can also be reached by varying other parameters of the system including temperature. We find here dramatic evidence of this phenomenon from experiments on a fullerene-porphyrin dyad. Following photoinduced electron transfer, the rate of charge recombination shows a bell-shaped dependence on the inverse temperature, first increasing with cooling and then decreasing at still lower temperatures. This non-Arrhenius rate law is a result of a strong, approximately hyperbolic temperature variation of the reorganization energy and the reaction free energy. Our results provide potentially the cleanest confirmation of the Marcus energy gap law so far since no modification of the chemical structure is involved.

Evidence of Momentum Conservation at a Nonepitaxial Metal/Semiconductor Interface Using Ballistic Electron Emission Microscopy

NASA Technical Reports Server (NTRS)

Bell, L. D.

1996-01-01

Ballistic-Electron-Emission Microscopy (BEEM) spectroscopy has been performed on Au/Si(111) structures as a function of Au thickness and temperature. At 77 K a direct signature of parallel momentum conservation at the Au/Si interface is observed in the BEEM spectra. The variation in spectral shape with both Au thickness and temperature places restrictions on allowable values of inelastic and elastic mean-free paths in the metal, and also requires the presence of multiple electron passes within the Au layer. An independent indication of multiple reflections is directly observed in the attenuation of BEEM current with Au thickness.

Finite-T correlations and free exchange-correlation energy of quasi-one-dimensional electron gas

NASA Astrophysics Data System (ADS)

Garg, Vinayak; Sharma, Akariti; Moudgil, R. K.

2018-02-01

We have studied the effect of temperature on static density-density correlations and plasmon excitation spectrum of quasi-one-dimensional electron gas (Q1DEG) using the random phase approximation (RPA). Numerical results for static structure factor, pair-correlation function, static density susceptibility, free exchange-correlation energy and plasmon dispersion are presented over a wide range of temperature and electron density. As an interesting result, we find that the short-range correlations exhibit a non-monotonic dependence on temperature T, initially growing stronger (i.e. the pair-correlation function at small inter-electron spacing assuming relatively smaller values) with increasing T and then weakening above a critical T. The cross-over temperature is found to increase with increasing coupling among electrons. Also, the q = 2kF peak in the static density susceptibility χ(q,ω = 0,T) at T = 0 K smears out with rising T. The free exchange-correlation energy and plasmon dispersion show a significant variation with T, and the trend is qualitatively the same as in higher dimensions.

The influence of the Ar/O2 ratio on the electron density and electron temperature in microwave discharges

NASA Astrophysics Data System (ADS)

Espinho, S.; Hofmann, S.; Palomares, J. M.; Nijdam, S.

2017-10-01

The aim of this work is to study the properties of Ar-O2 microwave driven surfatron plasmas as a function of the Ar/O2 ratio in the gas mixture. The key parameters are the plasma electron density and electron temperature, which are estimated with Thomson scattering (TS) for O2 contents up to 50% of the total gas flow. A sharp drop in the electron density from {10}20 {{{m}}}-3 to approximately {10}18 {{{m}}}-3 is estimated as the O2 content in the gas mixture is increased up to 15%. For percentages of O2 lower than 10%, the electron temperature is estimated to be about 2-3 times higher than in the case of a pure argon discharge in the same conditions ({T}{{e}}≈ 1 eV) and gradually decreases as the O2 percentage is raised to 50%. However, for O2 percentages above 30%, the scattering spectra become Raman dominated, resulting in large uncertainties in the estimated electron densities and temperatures. The influence of photo-detached electrons from negative ions caused by the typical TS laser fluences is also likely to contribute to the uncertainty in the measured electron densities for high O2 percentages. Moreover, the detection limit of the system is reached for percentages of O2 higher than 25%. Additionally, both the electron density and temperature of microwave discharges with large Ar/O2 ratios are more sensitive to gas pressure variations.

Thermal response of the F region ionosphere in artificial modification experiments by HF radio waves

NASA Technical Reports Server (NTRS)

Mantas, G. P.; Lahoz, C. H.; Carlson, H. C., Jr.

1981-01-01

The thermal response of the nighttime F region ionosphere to local heating by HF radio waves has been observed with the incoherent scatter radar at Arecibo, Puerto Rico. The observations consist of high-resolution space and time variation of the electron temperature as a high-power HF transmitter is switched on and off with a period 240 s. As soon as the HF transmitter is turned on, the electron temperature begins to rise rapidly in a narrow altitude region near 300 km, below the F2 layer peak. The electron temperature perturbation subsequently spreads over a broader altitude region. The observations are compared with the anticipated thermal response of the ionosphere based on numerical solutions of the coupled time-dependent heat conduction equations for the electron and composite ion gases and are found to be in good agreement over the entire altitude region covered by the observations.

Low dimensional CH3NH3PbBr3 cubes for persistent luminescence: Energy variation of electron excitation

NASA Astrophysics Data System (ADS)

Besral, N.; Paul, T.; Thakur, S.; Sarkar, S.; Sardar, K.; Chanda, K.; Das, A.; Chattopadhyay, K. K.

2018-04-01

The impact of varying electron beam voltage upon room temperature CL (cathodoluminescence) properties of crystalline organic-inorganic lead halide perovskite CH3NH3PbBr3 (Methylammonium lead tribromide) microcubes have been studied. CH3NH3PbBr3 microcubes were synthesized at room temperature by a very straight forward wet chemical route. After preliminary characterizations like XRD (X-ray diffraction), FESEM (Field emission scanning electron microscopy), UV-Vis spectroscopy, CL study at three different beam voltages i.e. 5 kV, 10 kV and 15 kV respectively was performed at room temperature. Prominent emission signals were obtained with emission peaks at 2.190 eV (FWHM 0.120 eV), 2.222 eV (FWHM 0.108 eV) and 2.242 eV (FWHM 0.095 eV) for electron beam voltages 5 kV, 10 kV and 15 kV respectively.

Structural and optical properties of electron beam evaporated yttria stabilized zirconia thin films

NASA Astrophysics Data System (ADS)

Kirubaharan, A. Kamalan; Kuppusami, P.; Singh, Akash; Dharini, T.; Ramachandran, D.; Mohandas, E.

2015-06-01

Yttria stabilized zirconia (10 mole % Y2O3) thin films were deposited on quartz substrates using electron beam physical vapor deposition at the substrate temperatures in the range 300 - 973 K. XRD analysis showed cubic crystalline phase of YSZ films with preferred orientation along (111). The surface roughness was found to increase with the increase of deposition temperatures. The optical band gap of ˜5.7 eV was calculated from transmittance curves. The variation in the optical properties is correlated with the changes in the microstructural features of the films prepared as a function of substrate temperature.

MAVEN Observations of Solar Wind-Driven Magnetosonic Waves Heating the Martian Dayside Ionosphere

NASA Astrophysics Data System (ADS)

Fowler, C. M.; Andersson, L.; Ergun, R. E.; Harada, Y.; Hara, T.; Collinson, G.; Peterson, W. K.; Espley, J.; Halekas, J.; Mcfadden, J.; Mitchell, D. L.; Mazelle, C.; Benna, M.; Jakosky, B. M.

2018-05-01

We present Mars Atmosphere and Volatile EvolutioN observations of large-amplitude magnetosonic waves propagating through the magnetosheath into the Martian ionosphere near the subsolar point on the dayside of the planet. The observed waves grow in amplitude as predicted for a wave propagating into a denser, charged medium, with wave amplitudes reaching 25 nT, equivalent to ˜40% of the background field strength. These waves drive significant density and temperature variations (˜20% to 100% in amplitude) in the suprathermal electrons and light ion species (H+) that correlate with compressional fronts of the magnetosonic waves. Density and temperature variations are also observed for the ionospheric electrons, and heavy ion species (O+ and O2+); however, these variations are not in phase with the magnetic field variations. Whistler waves are observed at compressional wave fronts and are thought to be produced by unstable, anistropic suprathermal electrons. The magnetosonic waves drive significant ion and electron heating down to just above the exobase region. Ion heating rates are estimated to be between 0.03 and 0.2 eVs-1 per ion, and heavier ions could thus gain escape energy if located in this heating region for ˜10-70 s. The measured ionospheric density profile indicates severe ionospheric erosion above the exobase region, and this is likely caused by substantial ion outflow that is driven by the observed heating. The effectiveness of these magnetosonic waves to energize the plasma close to the exobase could have important implications for the long-term climate evolution for unmagnetized bodies that are exposed to the solar wind.

Observations of electron vortex magnetic holes and related wave-particle interactions in the turbulent magnetosheath

NASA Astrophysics Data System (ADS)

Huang, S.; Sahraoui, F.; Yuan, Z.; He, J.; Zhao, J.; Du, J.; Le Contel, O.; Wang, X.; Deng, X.; Fu, H.; Zhou, M.; Shi, Q.; Breuillard, H.; Pang, Y.; Yu, X.; Wang, D.

2017-12-01

Magnetic hole is characterized by a magnetic depression, a density peak, a total electron temperature increase (with a parallel temperature decrease but a perpendicular temperature increase), and strong currents carried by the electrons. The current has a dip in the core region of the magnetic hole and a peak in the outer region of the magnetic hole. There is an enhancement in the perpendicular electron fluxes at 90° pitch angles inside the magnetic hole, implying that the electrons are trapped within it. The variations of the electron velocity components Vem and Ven suggest that an electron vortex is formed by trapping electrons inside the magnetic hole in the circular cross-section. These observations demonstrate the existence of a new type of coherent structures behaving as an electron vortex magnetic hole in turbulent space plasmas as predicted by recent kinetic simulations. We perform a statistically study using high time solution data from the MMS mission. The magnetic holes with short duration (i.e., < 0.5 s) have their cross section smaller than the ion gyro-radius. Superposed epoch analysis of all events reveals that an increase in the electron density and total temperature, significantly increase (resp. decrease) the electron perpendicular (resp. parallel) temperature, and an electron vortex inside the holes. Electron fluxes at 90° pitch angles with selective energies increase in the KSMHs, are trapped inside KSMHs and form the electron vortex due to their collective motion. All these features are consistent with the electron vortex magnetic holes obtained in 2D and 3D particle-in-cell simulations, indicating that the observed the magnetic holes seem to be best explained as electron vortex magnetic holes. It is furthermore shown that the magnetic holes are likely to heat and accelerate the electrons. We also investigate the coupling between whistler waves and electron vortex magnetic holes. These whistler waves can be locally generated inside electron vortex magnetic holes by electron temperature anisotropic instability.

Consequences of Part Temperature Variability in Electron Beam Melting of Ti-6Al-4V

NASA Astrophysics Data System (ADS)

Fisher, Brian A.; Mireles, Jorge; Ridwan, Shakerur; Wicker, Ryan B.; Beuth, Jack

2017-12-01

To facilitate adoption of Ti-6Al-4V (Ti64) parts produced via additive manufacturing (AM), the ability to ensure part quality is critical. Measuring temperatures is an important component of part quality monitoring in all direct metal AM processes. In this work, surface temperatures were monitored using a custom infrared camera system attached to an Arcam electron beam melting (EBM®) machine. These temperatures were analyzed to understand their possible effect on solidification microstructure based on solidification cooling rates extracted from finite element simulations. Complicated thermal histories were seen during part builds, and temperature changes occurring during typical Ti64 builds may be large enough to affect solidification microstructure. There is, however, enough time between fusion of individual layers for spatial temperature variations (i.e., hot spots) to dissipate. This means that an effective thermal control strategy for EBM® can be based on average measured surface temperatures, ignoring temperature variability.

Bias Stress and Temperature Impact on InGaZnO TFTs and Circuits

PubMed Central

Martins, Jorge; Bahubalindruni, Pydi; Rovisco, Ana; Kiazadeh, Asal; Martins, Rodrigo; Fortunato, Elvira; Barquinha, Pedro

2017-01-01

This paper focuses on the analysis of InGaZnO thin-film transistors (TFTs) and circuits under the influence of different temperatures and bias stress, shedding light into their robustness when used in real-world applications. For temperature-dependent measurements, a temperature range of 15 to 85 °C was considered. In case of bias stress, both gate and drain bias were applied for 60 min. Though isolated transistors show a variation of drain current as high as 56% and 172% during bias voltage and temperature stress, the employed circuits were able to counteract it. Inverters and two-TFT current mirrors following simple circuit topologies showed a gain variation below 8%, while the improved robustness of a cascode current mirror design is proven by showing a gain variation less than 5%. The demonstration that the proper selection of TFT materials and circuit topologies results in robust operation of oxide electronics under different stress conditions and over a reasonable range of temperatures proves that the technology is suitable for applications such as smart food packaging and wearables. PMID:28773037

Bias Stress and Temperature Impact on InGaZnO TFTs and Circuits.

PubMed

Martins, Jorge; Bahubalindruni, Pydi; Rovisco, Ana; Kiazadeh, Asal; Martins, Rodrigo; Fortunato, Elvira; Barquinha, Pedro

2017-06-21

This paper focuses on the analysis of InGaZnO thin-film transistors (TFTs) and circuits under the influence of different temperatures and bias stress, shedding light into their robustness when used in real-world applications. For temperature-dependent measurements, a temperature range of 15 to 85 °C was considered. In case of bias stress, both gate and drain bias were applied for 60 min. Though isolated transistors show a variation of drain current as high as 56% and 172% during bias voltage and temperature stress, the employed circuits were able to counteract it. Inverters and two-TFT current mirrors following simple circuit topologies showed a gain variation below 8%, while the improved robustness of a cascode current mirror design is proven by showing a gain variation less than 5%. The demonstration that the proper selection of TFT materials and circuit topologies results in robust operation of oxide electronics under different stress conditions and over a reasonable range of temperatures proves that the technology is suitable for applications such as smart food packaging and wearables.

Thermal Electron Contributions to Current-Driven Instabilities: SCIFER Observations in the 1400-km Cleft Ion Fountain and Their Implications to Thermal Ion Energization

NASA Technical Reports Server (NTRS)

Adrian, Mark L.; Pollock, C. J.; Moore, T. E.; Kintner, P. M.; Arnoldy, R. L.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

SCIFER TECHS observations of the variations in the thermal electron distribution in the 1400-km altitude cleft are associated with periods of intense ion heating and field-aligned currents. Energization of the thermal ion plasma in the mid-altitude cleft occurs within density cavities accompanied by enhanced thermal electron temperatures, large field-aligned thermal electron plasma flows and broadband low-frequency electric fields. Variations in the thermal electron contribution to field-aligned current densities indicate small scale (approximately 100's m) filamentary structure embedded within the ion energization periods. TECHS observations of the field-aligned drift velocities and temperatures of the thermal electron distribution are presented to evaluate the critical velocity thresholds necessary for the generation of electrostatic ion cyclotron and ion acoustic instabilities. This analysis suggests that, during periods of thermal ion energization, sufficient drift exists in the thermal electron distribution to excite the electrostatic ion cyclotron instability. In addition, brief periods exist within the same interval where the drift of the thermal electron distribution is sufficient to marginally excite the ion acoustic instability. In addition, the presence an enhancement in Langmuir emission at the plasma frequency at the center of the ion energization region, accompanied by the emission's second-harmonic, and collocated with observations of high-frequency electric field solitary structures suggest the presence of electron beam driven decay of Langmuir waves to ion acoustic modes as an additional free energy source for ion energization.

Ab-initio study of thermodynamic properties of boron nanowire at atomic scale

NASA Astrophysics Data System (ADS)

Bhuyan, Prabal D.; Gupta, Sanjeev K.; Sonvane, Y.; Gajjar, P. N.

2018-04-01

In the present work, we have optimized ribbon like zigzag structure of boron (B) nanowire (NW) and investigated vibrational and thermodynamic properties using quasi-harmonic approximations (QHA). All positive phonon in the phonon dispersive curve have confirmed dynamical stability of ribbon B-NW. The thermodynamic properties, like Debye temperature, internal energy and specific heat, are calculated as a function of temperature. The variation of specific heat is proportional to T3 Debye law at lower temperature for B-NW, while it becomes constant above room temperature at 1200K; obeys Dulong-Petit's law. The high Debye temperature of 1120K is observed at ambient temperature, which can be attributed to high thermal conductivity. Our study shows that B-NW with high thermal conductivity could be the next generation electron connector for nanoscale electronic devices.

Quantum Shielding Effects on the Eikonal Collision Cross Section in Strongly Coupled Two-temperature Plasmas

NASA Astrophysics Data System (ADS)

Lee, Myoung-Jae; Jung, Young-Dae

2017-05-01

The influence of nonisothermal and quantum shielding on the electron-ion collision process is investigated in strongly coupled two-temperature plasmas. The eikonal method is employed to obtain the eikonal scattering phase shift and eikonal cross section as functions of the impact parameter, collision energy, electron temperature, ion temperature, Debye length, and de Broglie wavelength. The results show that the quantum effect suppresses the eikonal scattering phase shift for the electron-ion collision in two-temperature dense plasmas. It is also found that the differential eikonal cross section decreases for small impact parameters. However, it increases for large impact parameters with increasing de Broglie wavelength. It is also found that the maximum position of the differential eikonal cross section is receded from the collision center with an increase in the nonisothermal character of the plasma. In addition, it is found that the total eikonal cross sections in isothermal plasmas are always greater than those in two-temperature plasmas. The variations of the eikonal cross section due to the two-temperature and quantum shielding effects are also discussed.

Preliminary Analysis of Images from the Thermospheric Temperature Imager on Fast, Affordable, Science and Technology SATellite (FASTSAT)

NASA Astrophysics Data System (ADS)

Rodriguez, M.; Jones, S.; Mentzell, E.; Gill, N.

2011-12-01

The Thermospheric Temperature Imager (TTI) on Fast, Affordable, Science and Technology SATellite (FASTSAT) measures the upper atmospheric atomic oxygen emission at 135.6 nm and the molecular nitrogen LBH emission at 135.4 nm to determine the atmospheric O/N2 density ratio. Observations of variations in this thermosheric ratio correspond to electron density variations in the ionosphere. The TTI design makes use of a Fabry-Perot interferometer to measure Doppler widened atmospheric emissions to determine neutral atmospheric temperature from low Earth orbit. FASTSAT launched November 10, 2010 and TTI is currently observing geomagnetic signatures in the aurora and airglow. This work is supported by NASA.

Preliminary Analysis of Images from the Thermospheric Temperature Image on Fast, Affordable, Science and Technology Satellite (FASTSAT)

NASA Technical Reports Server (NTRS)

Rodriquez, Marcello; Jones, Sarah; Mentzell, Eric; Gill, Nathaniel

2011-01-01

The Thermospheric Temperature Imager (TTI) on Fast, Affordable, Science and Technology SATellite (FASTSAT) measures the upper atmospheric atomic oxygen emission at 135.6 nm and the molecular nitrogen LBH emission at 135.4 nm to determine the atmospheric O/N2 density ratio. Observations of variations in this thermospheric ratio correspond to electron density variations in the ionosphere. The TTI design makes use of a Fabry-Perot interferometer to measure Doppler widened atmospheric emissions to determine neutral atmospheric temperature from low Earth orbit. FASTSAT launched November 10, 2010 and TTI is currently observing geomagnetic signatures in the aurora and airglow. This work is supported by NASA.

Investigating local degradation and thermal stability of charged nickel-based cathode materials through real-time electron microscopy.

PubMed

Hwang, Sooyeon; Kim, Seung Min; Bak, Seong-Min; Cho, Byung-Won; Chung, Kyung Yoon; Lee, Jeong Yong; Chang, Wonyoung; Stach, Eric A

2014-09-10

In this work, we take advantage of in situ transmission electron microscopy (TEM) to investigate thermally induced decomposition of the surface of Li(x)Ni(0.8)Co(0.15)Al(0.05)O2 (NCA) cathode materials that have been subjected to different states of charge (SOC). While uncharged NCA is stable up to 400 °C, significant changes occur in charged NCA with increasing temperature. These include the development of surface porosity and changes in the oxygen K-edge electron energy loss spectra, with pre-edge peaks shifting to higher energy losses. These changes are closely related to O2 gas released from the structure, as well as to phase changes of NCA from the layered structure to the disordered spinel structure, and finally to the rock-salt structure. Although the temperatures where these changes initiate depend strongly on the state of charge, there also exist significant variations among particles with the same state of charge. Notably, when NCA is charged to x = 0.33 (the charge state that is the practical upper limit voltage in most applications), the surfaces of some particles undergo morphological and oxygen K-edge changes even at temperatures below 100 °C, a temperature that electronic devices containing lithium ion batteries (LIB) can possibly see during normal operation. Those particles that experience these changes are likely to be extremely unstable and may trigger thermal runaway at much lower temperatures than would be usually expected. These results demonstrate that in situ heating experiments are a unique tool not only to study the general thermal behavior of cathode materials but also to explore particle-to-particle variations, which are sometimes of critical importance in understanding the performance of the overall system.

Temperature aspect of degradation of electrochemical double-layer capacitors (EDLC)

NASA Astrophysics Data System (ADS)

Baek, Dong-Cheon; Kim, Hyun-Ho; Lee, Soon-Bok

2015-03-01

Electric double layer capacitors (EDLC) cells have a process variation and temperature dependency in capacitance so that balancing is required when they are connected in series, which includes electronic voltage management based on capacitance monitoring. This paper measured temperature aspect of capacitance periodically to monitor health and degradation behavior of EDLC stressed under high temperatures and zero below temperatures respectively, which enables estimation of the state of health (SOH) regardless of temperature. At high temperature, capacitance saturation and delayed expression of degradation was observed. After cyclic stress at zero below temperature, less effective degradation and time recovery phenomenon were occurred.

Ion temperature of low-latitude and mid-latitude topside ionosphere for high solar activity

NASA Astrophysics Data System (ADS)

Cai, Lei; Zhang, Donghe; Hao, Yongqiang; Xiao, Zuo

The International Reference Ionosphere (IRI) describes the day and night latitudinal variation of ion temperature at 430 km with two functions using AEROS satellite measurements. The ion temperature at this height as one of the boundary parameters is used to make the ion temperature profile represented by a Booker-function. Since the low-latitude and mid-latitude topside ionospheric ion temperature has been measured with the Ionopsheric Plasma and Elec-trodynamics Instrument (IPEI) onboard Rocsat-1 satellite at about 600 km during the high solar activity years from 2000 to 2002, a new boundary at 600 km can be set for the ion temperature modeling. The latitudinal variation of ion temperature could be approximated by Epstein family of functions for different local time sectors. Furthermore, the longitudinal and seasonal variations are also taken into account to decide the fitting parameters. Only the magnetic quiet time data (Kp <3) are used for the statistical study. The results are compared with IRI-2007 model. In addition, events when Kp >4 are also analyzed to feature the ion temperature characteristic during the magnetic disturbance time condition. Combined with the IPEI field-aligned ion flow velocities and the plasma temperatures measured by the Special Sensors-Ions, Electrons, and Scintillation (SSIES) thermal plasma analysis package on board the DMSP F13 and F15 satellites, several feasible ion heating and heat loss mechanisms are summarized to interpret the ion temperature crests and toughs for different local time sectors, seasonal and longitudinal variations.

Effects of discharge chamber length on the negative ion generation in volume-produced negative hydrogen ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chung, Kyoung-Jae; Jung, Bong-Ki; An, YoungHwa

2014-02-15

In a volume-produced negative hydrogen ion source, control of electron temperature is essential due to its close correlation with the generation of highly vibrationally excited hydrogen molecules in the heating region as well as the generation of negative hydrogen ions by dissociative attachment in the extraction region. In this study, geometric effects of the cylindrical discharge chamber on negative ion generation via electron temperature changes are investigated in two discharge chambers with different lengths of 7.5 cm and 11 cm. Measurements with a radio-frequency-compensated Langmuir probe show that the electron temperature in the heating region is significantly increased by reducingmore » the length of the discharge chamber due to the reduced effective plasma size. A particle balance model which is modified to consider the effects of discharge chamber configuration on the plasma parameters explains the variation of the electron temperature with the chamber geometry and gas pressure quite well. Accordingly, H{sup −} ion density measurement with laser photo-detachment in the short chamber shows a few times increase compared to the longer one at the same heating power depending on gas pressure. However, the increase drops significantly as operating gas pressure decreases, indicating increased electron temperatures in the extraction region degrade dissociative attachment significantly especially in the low pressure regime. It is concluded that the increase of electron temperature by adjusting the discharge chamber geometry is efficient to increase H{sup −} ion production as long as low electron temperatures are maintained in the extraction region in volume-produced negative hydrogen ion sources.« less

High-temperature fcc phase of Pr:  Negative thermal expansion and intermediate valence state

NASA Astrophysics Data System (ADS)

Kuznetsov, A. Yu.; Dmitriev, V. P.; Bandilet, O. I.; Weber, H.-P.

2003-08-01

A high-temperature angle-dispersive synchrotron radiation diffraction study has revealed the double hexagonal-close-packed-to-face-centered-cubic (dhcp-to-fcc) transformation in the Pr metal occurring martensitically between 575 and 1035 K. The high-temperature fcc phase shows a negative thermal expansion in the range 600 800 K, attributed to the 4f-electron delocalization. A phenomenological theory is developed, which explains consistently the observed effect in terms of the mean valence variation of the metal as a function of temperature; it also predicts the existence of an isostructural phase transition and of a critical end point of a gas-liquid type in compressed Pr. The analysis of published data on P-T variation of conductivity of Pr supports this prediction.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andreev, V. V., E-mail: vvandreev@mail.ru; Vasileska, I., E-mail: ivonavasileska@yahoo.com; Korneeva, M. A., E-mail: korneevama@mail.ru

A pulse-periodic 2.45-GHz electron-cyclotron resonance plasma source on the basis of a permanent- magnet mirror trap has been constructed and tested. Variations in the discharge parameters and the electron temperature of argon plasma have been investigated in the argon pressure range of 1 × 10{sup –4} to 4 × 10{sup –3} Torr at a net pulsed input microwave power of up to 600 W. The plasma electron temperature in the above ranges of gas pressures and input powers has been measured by a Langmuir probe and determined using optical emission spectroscopy (OES) from the intensity ratios of spectral lines. Themore » OES results agree qualitatively and quantitatively with the data obtained using the double probe.« less

Variability of dayside electron temperature at Venus

NASA Technical Reports Server (NTRS)

Mahajan, K. K.; Ghosh, S.; Paul, R.; Hoegy, W. R.

1994-01-01

Langmuir probe measurements on Pioneer Venus Orbiter show that electron temperature (Te) profiles exhibit two distinct regions. The lower, but more extended region is in the main ionosphere where Te increases slowly with altitude. The other, less extended region is in the ionopause, where Te rise sharply with altitude. If horizontal magnetic fields and flux ropes in the ionosphere inhibit vertical thermal conductivity sufficiently, then the observed Te profile could be explained with EUV as the major heat source (Cravens et al., 1980). The rise in Te in the ionopause region has generally been attributed to solar wind heating (Brace and Kliore, 1991). We suggest that this sharp rise in Te is due primarily to the steep fall in electron density, Ne. If the heating rate is essentially unchanged and heat conduction is not of primary importance, then a steep rise in Te will maintain a constant electron cooling rate for a steeply falling Ne. We have observed large orbit to orbit variations in Te in the ionopause region which are found to be inversely related to changes in Ne. Variations in solar wind dynamic pressure do not seem to have a direct effect on Te, rather the effect is indirect coming through the sharp decrease in Ne.

Methodological Variability Using Electronic Nose Technology For Headspace Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knobloch, Henri; Turner, Claire; Spooner, Andrew

Since the idea of electronic noses was published, numerous electronic nose (e-nose) developments and applications have been used in analyzing solid, liquid and gaseous samples in the food and automotive industry or for medical purposes. However, little is known about methodological pitfalls that might be associated with e-nose technology. Some of the methodological variation caused by changes in ambient temperature, using different filters and changes in mass flow rates are described. Reasons for a lack of stability and reproducibility are given, explaining why methodological variation influences sensor responses and why e-nose technology may not always be sufficiently robust for headspacemore » analysis. However, the potential of e-nose technology is also discussed.« less

Seasonal variation of meteor decay times observed at King Sejong Station (62.22°S, 58.78°W), Antarctica

NASA Astrophysics Data System (ADS)

Kim, Jeong-Han; Kim, Yong Ha; Lee, Chang-Sup; Jee, Geonhwa

2010-07-01

We analyzed meteor decay times measured by a VHF radar at King Sejong Station by classifying strong and weak meteors according to their estimated electron line densities. The height profiles of monthly averaged decay times show a peak whose altitude varies with season at altitudes of 80-85 km. The higher peak during summer is consistent with colder temperatures that cause faster chemical reactions of electron removal. By adopting temperature dependent empirical recombination rates from rocket experiments and meteor electron densities of 2×105-2×106 cm-3 in a decay time model, we are able to account for decreasing decay times below the peak for all seasons without invoking meteor electron removal by hypothetical icy particles.

A novel pressure variation study on electronic structure, mechanical stability and thermodynamic properties of potassium based fluoroperovskite

NASA Astrophysics Data System (ADS)

Erum, Nazia; Azhar Iqbal, Muhammad

2017-09-01

The effect of pressure variation on stability, structural parameters, elastic constants, mechanical, electronic and thermodynamic properties of cubic SrKF3 fluoroperovskite have been investigated by using the full-potential linearized augmented plane wave (FP-LAPW) method combined with Quasi-harmonic Debye model in which the phonon effects are considered. The calculated lattice parameters show a prominent decrease in lattice constant and bonds length with the increase in pressure. The application of pressure from 0 to 25 GPa reveals a predominant characteristic associated with widening of bandgap with GGA and GGA plus Tran-Blaha modified Becke-Johnson (TB-mBJ) potential. The influence of pressure on elastic constants and their related mechanical parameters have been discussed in detail. Apart of linear dependence of elastic coefficients, transition from brittle to ductile behavior is also observed at elevated pressure ranges. We have successfully computed variation of lattice constant, volume expansion, bulk modulus, Debye temperature and specific heat capacities at pressure and temperature in the range of 0-25 GPa and 0-600 K.

Temperature dependence of attitude sensor coalignments on the Solar Maximum Mission (SMM)

NASA Technical Reports Server (NTRS)

Pitone, D. S.; Eudell, A. H.; Patt, F. S.

1989-01-01

Results are presented on the temperature correlation of the relative coalignment between the fine pointing sun sensor (FPSS) and fixed head star trackers (FHSTs) on the Solar Maximum Mission (SMM). This correlation can be caused by spacecraft electronic and mechanical effects. Routine daily measurements reveal a time dependent sensor coalignment variation. The magnitude of the alignment variation is on the order of 120 arc seconds (arc sec), which greatly exceeds the prelaunch thermal structural analysis estimate of 15 acr sec. Differences between FPSS-only and FHST-only yaw solutions as a function of mission day are correlated with the relevant spacecraft temperature. If unaccounted for, the sensor misalignments due to thermal effects are a significant source of error in attitude determination accuracy. Prominent sources of temperature variation are identified and correlated with the temperature profile observed on the SMM. It was determined that even relatively small changes in spacecraft temperature can affect the coalignments between the attitude hardware on the SMM and the science instrument support plate and that frequent recalibration of sensor alignments is necessary to compensate for this effect. An alterntive to frequent recalibration is to model the variation of alignments as a function of temperature and use this to maintain accurate ground or onboard alignment estimates. These flight data analysis results may be important consierations for prelaunch analysis of future missions.

Direct evaluation of boson dynamics via finite-temperature time-dependent variation with multiple Davydov states.

PubMed

Fujihashi, Yuta; Wang, Lu; Zhao, Yang

2017-12-21

Recent advances in quantum optics allow for exploration of boson dynamics in dissipative many-body systems. However, the traditional descriptions of quantum dissipation using reduced density matrices are unable to capture explicit information of bath dynamics. In this work, efficient evaluation of boson dynamics is demonstrated by combining the multiple Davydov Ansatz with finite-temperature time-dependent variation, going beyond what state-of-the-art density matrix approaches are capable to offer for coupled electron-boson systems. To this end, applications are made to excitation energy transfer in photosynthetic systems, singlet fission in organic thin films, and circuit quantum electrodynamics in superconducting devices. Thanks to the multiple Davydov Ansatz, our analysis of boson dynamics leads to clear revelation of boson modes strongly coupled to electronic states, as well as in-depth description of polaron creation and destruction in the presence of thermal fluctuations.

High-temperature electronics applications in space exploration

NASA Astrophysics Data System (ADS)

Jurgens, R. F.

1982-05-01

One of the most exciting applications of high-temperature electronics is related to the exploration of the planet Venus. On this planet the atmospheric temperatures range from about 170 K at elevations of 100 km to a searing 730 K near the surface. Mechanisms for exploring the atmosphere might include balloons, airplanes, surface landers, and surface-launched probes. Balloons, for example, could fly in the region from 20 (320 C at 22 bars) to 60 km (-20 C at 0.2 bar). Suitable balloon fabrics presently exclude excursions to lower altitudes; however, adequate electronic systems could survive to 325 C. Small airplanes would require more sophisticated electronics for guidance and control. Long life surface landers would most likely be developed first, as these could be used to measure long-term variations in weather. Ranging transponders would be important for ephemeris development, measurement of spin state, and studies of general relativity. Surface temperatures of 460 C and pressures of 90 bars present a challenge to the developers of such instruments. Other space applications for high-temperature electronics include transponders for the surface of Mercury, near solar drag-free orbiters, and deep atmospheric penetrators for Jupiter and Saturn. Each of these has its own particular problems with respect to instrumentation adequate to meet the desired scientific goals. This paper is primarily concerned with defining possible mission applications, the required electronic systems, and the approaches that are currently being studied for their development.

High-temperature electronics applications in space exploration

NASA Technical Reports Server (NTRS)

Jurgens, R. F.

1982-01-01

One of the most exciting applications of high-temperature electronics is related to the exploration of the planet Venus. On this planet the atmospheric temperatures range from about 170 K at elevations of 100 km to a searing 730 K near the surface. Mechanisms for exploring the atmosphere might include balloons, airplanes, surface landers, and surface-launched probes. Balloons, for example, could fly in the region from 20 (320 C at 22 bars) to 60 km (-20 C at 0.2 bar). Suitable balloon fabrics presently exclude excursions to lower altitudes; however, adequate electronic systems could survive to 325 C. Small airplanes would require more sophisticated electronics for guidance and control. Long life surface landers would most likely be developed first, as these could be used to measure long-term variations in weather. Ranging transponders would be important for ephemeris development, measurement of spin state, and studies of general relativity. Surface temperatures of 460 C and pressures of 90 bars present a challenge to the developers of such instruments. Other space applications for high-temperature electronics include transponders for the surface of Mercury, near solar drag-free orbiters, and deep atmospheric penetrators for Jupiter and Saturn. Each of these has its own particular problems with respect to instrumentation adequate to meet the desired scientific goals. This paper is primarily concerned with defining possible mission applications, the required electronic systems, and the approaches that are currently being studied for their development.

Electron Plasmas Cooled by Cyclotron-Cavity Resonance

DOE PAGES

Povilus, A. P.; DeTal, N. D.; Evans, L. T.; ...

2016-10-21

We observe that high-Q electromagnetic cavity resonances increase the cyclotron cooling rate of pure electron plasmas held in a Penning-Malmberg trap when the electron cyclotron frequency, controlled by tuning the magnetic field, matches the frequency of standing wave modes in the cavity. For certain modes and trapping configurations, this can increase the cooling rate by factors of 10 or more. In this paper, we investigate the variation of the cooling rate and equilibrium plasma temperatures over a wide range of parameters, including the plasma density, plasma position, electron number, and magnetic field.

Facile preparation of porous carbon from coffee bean waste using low temperature solvothermal method

NASA Astrophysics Data System (ADS)

Baroroh, L. A. Al; Fitria, D.; Amal, M. I.; Wismogroho, A. S.; Widayatno, W. B.

2018-03-01

In this study, porous carbon made from coffee bean waste (CBW) was carbonized at 500 °C, 600 °C, and 700 °C to find effective temperature. It is verified from the IR spectrum that carbonization process at certain temperature can effectively break cellulose bonding and make aromatics functional group while preserving its carbon structure. The TG-DTA curve shows four stages of decomposition process and confirms most effective carbonization temperature. Activation process of as-carbonized CBW was carried out using solvothermal method in KOH and NH4OH steam environment at 200 °C with variation of 30%, 40%, and 50% solvothermal volume. Scanning electron micrographs reveals significant increase of porosity on the carbon surface and differences of structural pores between the variations. The results show the possible potential of utilizing low temperature-solvothermal method for nanoporous carbon material.

Variation of Derived Mesospheric Nitric Oxide in Relation to Wind and Temperature in Winter

NASA Technical Reports Server (NTRS)

Friedrich, M.; Torkar, K. M.

1984-01-01

As a good approximation, changes of the NO-density are solely responsible for changes of the non-auroral D-region. Under the assumption that other ion production processes are either known or negligible, one can derive (NO) from electron densities using a suitable effective electron loss rate. In the Winter Anomaly Campaign 1975/76 nineteen rocket payloads carried electron density measurements on fifteen days. On two of these days (NO) was measured in-situ by photometers. For these days one can establish the production not due to Lyman-alpha and NO. This rest production can then be applied to all (NO) derivations based on electron density measurements. In addition, in this campaign winds and temperatures were measured from the ground to approximately the base of the thermosphere. The derived field of NO densities between December 1975 and February 1976 from 70 to 100 km is compared to corresponding fields of winds (zonal and meridional), temperatures, pressure and Richardson numbers.

Effects of temperature on the ground state of a strongly-coupling magnetic polaron and mean phonon number in RbCl quantum pseudodot

NASA Astrophysics Data System (ADS)

Sun, Yong; Ding, Zhao-Hua; Xiao, Jing-Lin

2016-07-01

On the condition of strong electron-LO phonon coupling in a RbCl quantum pseudodot (QPD), the ground state energy and the mean number of phonons are calculated by using the Pekar variational method and quantum statistical theory. The variations of the ground state energy and the mean number with respect to the temperature and the cyclotron frequency of the magnetic field are studied in detail. We find that the absolute value of the ground state energy increases (decreases) with increasing temperature when the temperature is in the lower (higher) temperature region, and that the mean number increases with increasing temperature. The absolute value of the ground state energy is a decreasing function of the cyclotron frequency of the magnetic field whereas the mean number is an increasing function of it. We find two ways to tune the ground state energy and the mean number: controlling the temperature and controlling the cyclotron frequency of the magnetic field.

Nonlinear electron transport mobility in asymmetric wide quantum well structure

NASA Astrophysics Data System (ADS)

Nayak, Rasmita K.; Das, Sudhakar; Panda, Ajit K.; Sahu, Trinath

2018-05-01

The nonlinearity of multisubband electron mobility µ in a GaAs/AlxGa1-xAs wide quantum well structure is studied by varying the well width w and doping concentration Nd b (Nd t ) lying in the bottom (top) barrier. The electrons diffuse into the well and accumulate near the interfaces forming two sheets of coupled two dimensional electron gases equivalent to a double quantum well structure. We show that interchange of doping concentrations N db and N dt lead to the enhancement of µ as a function of w as long as N dt > N db , even though the surface electron density remains unaltered. Further, keeping Nd b unchanged, variation of Nd t leads to nonlinearity in µ near the resonance of subband states at Nd t = Nd b at which the subband energy levels exhibit anticrossing. The variation of µ becomes prominent by increasing the well width and resonant doping concentration. The nonlinearity in µ is mostly because of the change in the interface roughness scattering potential through intersubband effects due to the substantial changes in the distributions of the subband wave functions around resonance. Our results of nonmonotonic variation of µ can be utilized for low temperature coupled quantum well devices.

[Plasma temperature of white-eye hexagonal pattern in dielectric barrier discharge].

PubMed

Zhao, Yang; Dong, Li-fang; Fu, Hong-yan

2015-01-01

By using the water-electrode discharge experimental setup, the white-eye hexagonal pattern is firstly observed and investigated in the dielectric barrier discharge with the mixture of argon and air whose content can be varied whenever necessary, and the study shows that the white-eye cell is an interleaving of three different hexagonal sub-structures: the spot, the ring, and the halo. The white-eye hexagonal pattern has the excellent discharge stability and sustainability during the experiment. Pictures recorded by ordinary camera with long exposure time in the same argon content condition show that the spot, the ring, and the halo of the white-eye hexagonal pattern have different brightness, which may prove that their plasma states are different. And, it is worth noting that there are obvious differences not only on the brightness but also on the color of the white-eye cell in conditions of different argon content, which shows that its plasma state also changed with the variation of the argon content. The white-eye hexagonal pattern is observed at a lower applied voltage so that the temperature of the water electrodes almost keeps unchanged during the whole experiment, which is advantageous for the long term stable measurement. The plasma state will not be affected by the temperature of the electrodes during the continuous discharge. Based on the above phenomena, plasma temperatures of the spot, the ring, and the halo in white-eye hexagonal pattern including molecule vibrational temperature and variations of electron density at different argon content are investigated by means of optical emission spectroscopy (OES). The emission spectra of the N2 second positive band(C3Πu-->B3Πg)are measured, and the molecule vibrational temperature of the spot, the ring, and the halo of the white-eye hexagonal pattern are calculated by the emission intensities. Furthermore, emission spectra of Ar I (2P2-->1S5)is collected and the changes of its width with different argon content are used to estimate the variations of electron density of the spot, the ring, and the halo of the white-eye hexagonal pattern. In the same argon content condition, the molecule vibrational temperatures of halo, ring, and spot in the white-eye hexagonal pattern are in descending order, while the electron densities of halo, ring, and spot are in ascending order. With argon content increasing from 70% to 90%, both the molecule vibrational temperature and the electron density of the spot increase, while both of them of the halo decrease. And the molecule vibrational temperature of the ring keeps constant, while its electron density decreases. The experimental results indicate that the plasma state of the spot, the halo and the ring in a white-eye cell of the white-eye hexagonal pattern is different. These results are of great importance to the investigation of the multilayer structure of the patterns in dielectric barrier discharge and applications in industry.

Temperature anisotropy instabilities stimulated by the interplay of the core and halo electrons in space plasmas

NASA Astrophysics Data System (ADS)

Lazar, M.; Shaaban, S. M.; Fichtner, H.; Poedts, S.

2018-02-01

Two central components are revealed by electron velocity distributions measured in space plasmas, a thermal bi-Maxwellian core and a bi-Kappa suprathermal halo. A new kinetic approach is proposed to characterize the temperature anisotropy instabilities driven by the interplay of core and halo electrons. Suggested by the observations in the solar wind, direct correlations of these two populations are introduced as co-variations of the key parameters, e.g., densities, temperature anisotropies, and (parallel) plasma betas. The approach involving correlations enables the instability characterization in terms of either the core or halo parameters and a comparative analysis to depict mutual effects. In the present paper, the instability conditions are described for an extended range of plasma beta parameters, making the new dual approach relevant for a wide variety of space plasmas, including the solar wind and planetary magnetospheres.

The effect of safety factor profile on transport in steady-state, high-performance scenarios

DOE PAGES

Holcomb, C. T.; Ferron, J. R.; Luce, T. C.; ...

2012-03-09

In this study, an analysis of the dependence of transport on the safety factor profile in high-performance, steady-state scenario discharges is presented. This is based on experimental scans of q 95 and q min taken with fixed β N, toroidal field, double-null plasma shape, divertor pumping, and electron cyclotron current drive input. The temperature and thermal diffusivity profiles were found to vary considerably with the q-profile, and these variations were significantly different for electrons and ions. With fixed q 95, both temperature profiles increase and broaden as q min is increased and the magnetic shear becomes low or negative inmore » the inner half radius, but these temperature profile changes are stronger for the electrons. Power balance calculations show the peak in the ion thermal diffusivity (χ i) at ρ – 0.6 – 0.8 increases with q 95 or q min.« less

A New Global Empirical Model of the Electron Temperature with the Inclusion of the Solar Activity Variations for IRI

NASA Technical Reports Server (NTRS)

Truhlik, V.; Triskova, L.

2012-01-01

A data-base of electron temperature (T(sub e)) comprising of most of the available LEO satellite measurements in the altitude range from 350 to 2000 km has been used for the development of a new global empirical model of T(sub e) for the International Reference Ionosphere (IRI). For the first time this will include variations with solar activity. Variations at five fixed altitude ranges centered at 350, 550, 850, 1400, and 2000 km and three seasons (summer, winter, and equinox) were represented by a system of associated Legendre polynomials (up to the 8th order) in terms of magnetic local time and the earlier introduced in vdip latitude. The solar activity variations of T(sub e) are represented by a correction term of the T(sub e) global pattern and it has been derived from the empirical latitudinal profiles of T(sub e) for day and night (Truhlik et al., 2009a). Comparisons of the new T(sub e) model with data and with the IRI 2007 Te model show that the new model agrees well with the data generally within standard deviation limits and that the model performs better than the current IRI T(sub e) model.

D-Wave Electron-H, -He+, and -Li2+ Elastic Scattering and Photoabsorption in P States of Two-Electron Systems

NASA Technical Reports Server (NTRS)

Bhatia, A. K.

2014-01-01

In previous papers [A. K. Bhatia, Phys. Rev. A 85, 052708 (2012); 86, 032709 (2012); 87, 042705 (2013)] electron-H, -He+, and -Li2+ P-wave scattering phase shifts were calculated using the variational polarized orbital theory. This method is now extended to the singlet and triplet D-wave scattering in the elastic region. The long-range correlations are included in the Schrodinger equation by using the method of polarized orbitals variationally. Phase shifts are compared to those obtained by other methods. The present calculation provides results which are rigorous lower bonds to the exact phase shifts. Using the presently calculated D-wave and previously calculated S-wave continuum functions, photoionization of singlet and triplet P states of He and Li+ are also calculated, along with the radiative recombination rate coefficients at various electron temperatures.

Electromagnetic interaction of spacecraft with ambient environment

NASA Astrophysics Data System (ADS)

Ku, Hwar-Ching; Silver, David M.

1993-01-01

A model of the midcourse space experiment (MSX) spacecraft and its electromagnetic environment has been developed using the potential of large spacecraft in the Auroral region (POLAR) code. The geometric model has a resolution of 0.341 meters and uses six materials to simulate the electrical surface properties of MSX. The vehicle model includes features such as the major instruments, electronic boxes, radiators, a dewar and open bay, a booster attachment ring, and three different orientations of the solar panels. The electron and ion composition and temperature environment are modeled as a function of the solar activity. Additional parameters include the ram-wake orientation, the hot electron spectrum, day-night-twilight variations, latitudinal variations, and solar panel voltage biasing. Nominal low spacecraft charging cases are described. Calculation with a high peak energetic electron flux produces a ground potential of -180 volts and differential charging as high as 66 volts.

Unexpected and Unexplained Surface Temperature Variations on Mimas

NASA Astrophysics Data System (ADS)

Howett, C.; Spencer, J. R.; Pearl, J. C.; Hurford, T. A.; Segura, M.; Cassini Cirs Team

2010-12-01

Until recently it was thought one of the most interesting things about Mimas, Saturn’s innermost classical icy moon, was its resemblance to Star Wars’ Death Star. However, a bizarre pattern of daytime surface temperatures was observed on Mimas using data obtained by Cassini’s Composite Infrared Spectrometer (CIRS) in February 2010. The observations were taken during Cassini’s closest ever encounter with Mimas (<10,000 km) and cover the daytime anti-Saturn hemisphere centered on longitude ~145° W. Instead of surface temperatures smoothly increasing throughout the morning and early afternoon, then cooling in the evening, as expected, a sharp V-shaped boundary is observed separating cooler midday and afternoon temperatures (~77 K) on the leading side from warmer morning temperatures (~92 K) on the trailing side. The boundary’s apex is centered at equatorial latitudes near the anti-Saturn point and extends to low north and south latitudes on the trailing side. Subtle differences in the surface colors have been observed that are roughly spatially correlated with the observed extent of the temperature anomaly, with the cooler regions tending to be bluer (Schenk et al., Submitted). However, visible-wavelength albedo is similar in the two regions, so albedo variations are probably not directly responsible for the thermal anomaly. It is more likely that thermal inertia variations produce the anomaly, with thermal inertia being unusually high in the region with anomalously low daytime temperatures. Comparison of the February 2010 CIRS data to previous lower spatial resolution data taken at different local times tentatively confirm that the cooler regions do indeed display higher thermal inertias. Bombardment of the surface by high energy electrons from Saturn’s radiation belts has been proposed to explain the observed color variations (Schenk et al., Submitted). Electrons above ~1 MeV preferentially impact Mimas’ leading hemisphere at low latitudes where they could cause surface defects. For this process to also explain the observed temperature differences it would have to affect the surface’s thermal inertia to a depth comparable to the diurnal thermal skin-depth (~0.5 cm). However, whether the formation of the giant Herschel crater (which lies in the middle of the observed portion of the cold region) contributed to the observed temperature anomaly or if electron bombardment alone is able to explain the thermal anomaly is currently unknown. Future CIRS observations should be able to map the full spatial extent of the thermal anomaly and clarify whether it is centered on (and thus likely related to) Herschel, or is centered on the trailing hemisphere and thus likely to be related to the observed color anomaly.

Temperature-driven topological quantum phase transitions in a phase-change material Ge2Sb2Te5.

PubMed

Eremeev, S V; Rusinov, I P; Echenique, P M; Chulkov, E V

2016-12-13

The Ge 2 Sb 2 Te 5 is a phase-change material widely used in optical memory devices and is a leading candidate for next generation non-volatile random access memory devices which are key elements of various electronics and portable systems. Despite the compound is under intense investigation its electronic structure is currently not fully understood. The present work sheds new light on the electronic structure of the Ge 2 Sb 2 Te 5 crystalline phases. We demonstrate by predicting from first-principles calculations that stable crystal structures of Ge 2 Sb 2 Te 5 possess different topological quantum phases: a topological insulator phase is realized in low-temperature structure and Weyl semimetal phase is a characteristic of the high-temperature structure. Since the structural phase transitions are caused by the temperature the switching between different topologically non-trivial phases can be driven by variation of the temperature. The obtained results reveal the rich physics of the Ge 2 Sb 2 Te 5 compound and open previously unexplored possibility for spintronics applications of this material, substantially expanding its application potential.

Finite temperature static charge screening in quantum plasmas

NASA Astrophysics Data System (ADS)

Eliasson, B.; Akbari-Moghanjoughi, M.

2016-07-01

The shielding potential around a test charge is calculated, using the linearized quantum hydrodynamic formulation with the statistical pressure and Bohm potential derived from finite temperature kinetic theory, and the temperature effects on the force between ions is assessed. The derived screening potential covers the full range of electron degeneracy in the equation of state of the plasma electrons. An attractive force between shielded ions in an arbitrary degenerate plasma exists below a critical temperature and density. The effect of the temperature on the screening potential profile qualitatively describes the ion-ion bound interaction strength and length variations. This may be used to investigate physical properties of plasmas and in molecular-dynamics simulations of fermion plasma. It is further shown that the Bohm potential including the kinetic corrections has a profound effect on the Thomson scattering cross section in quantum plasmas with arbitrary degeneracy.

Relations among low ionosphere parameters and high frequency radio wave absorption

NASA Technical Reports Server (NTRS)

Cipriano, J. P.

1973-01-01

Charged particle conductivities measured in the very low ionosphere at White Sands Missile Range, New Mexico, and Wallops Island, Virginia, are compared with atmospheric parameters and high frequency radio wave absorption measurements. Charged particle densities are derived from the conductivity data. Between 33 and 58 km, positive conductivity correlated well with neutral atmospheric temperature, with temperature coefficients as large as 4.6%/deg K. Good correlations were also found between HF radio wave absorption and negative conductivity at altitudes as low as 53 km, indicating that the day-to-day absorption variations were principally due to variations in electron loss rate.

Large-scale variation of electron parameters from Quasi-Thermal Noise during WIND perigees in the Earth's magnetosphere

NASA Astrophysics Data System (ADS)

Issautier, Karine; Ongala-Edoumou, Samuel; Moncuquet, Michel

2016-04-01

The quasi-thermal noise (QTN) method consists in measuring the electrostatic fluctuations produced by the thermal motion of the ambient particles. This noise is detected with a sensitive wave receiver and measured at the terminal of a passive electric antenna, which is immersed in a stable plasma. The analysis of the so-called QTN provides in situ measurements, mainly the total electron density, with a good accuracy, and thermal temperature in a large number of space media. We create a preliminary electron database to analyse the anti-correlation between electron density and temperature deduced from WIND perigees in the Earth's plasmasphere. We analyse the radio power spectra measured by the Thermal Noise Receiver (TNR), using the 100-m long dipole antenna, onboard WIND spacecraft. We develop a systematic routine to determine the electron density, core and halo temperature and the magnitude of the magnetic field based on QTN in Bernstein modes. Indeed, the spectra are weakly banded between gyroharmonics below the upper hybrid frequency, from which we derive the local electron density. From the gyrofrequency determination, we obtain an independent measure of the magnetic field magnitude, which is in close agreement with the onboard magnetometer.

Modeling quantum yield, emittance, and surface roughness effects from metallic photocathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dimitrov, D. A.; Bell, G. I.; Smedley, J.

Here, detailed measurements of momentum distributions of emitted electrons have allowed the investigation of the thermal limit of the transverse emittance from metal photocathodes. Furthermore, recent developments in material design and growth have resulted in photocathodes that can deliver high quantum efficiency and are sufficiently robust to use in high electric field gradient photoinjectors and free electron lasers. The growth process usually produces photoemissive material layers with rough surface profiles that lead to transverse accelerating fields and possible work function variations, resulting in emittance growth. To better understand the effects of temperature, density of states, and surface roughness on themore » properties of emitted electrons, we have developed realistic three-dimensional models for photocathode materials with grated surface structures. They include general modeling of electron excitation due to photon absorption, charge transport, and emission from flat and rough metallic surfaces. The models also include image charge and field enhancement effects. We report results from simulations with flat and rough surfaces to investigate how electron scattering, controlled roughness, work function variation, and field enhancement affect emission properties. Comparison of simulation results with measurements of the quantum yield and transverse emittance from flat Sb emission surfaces shows the importance of including efficient modeling of photon absorption, temperature effects, and the material density of states to achieve agreement with the experimental data.« less

Modeling quantum yield, emittance, and surface roughness effects from metallic photocathodes

DOE PAGES

Dimitrov, D. A.; Bell, G. I.; Smedley, J.; ...

2017-10-26

Here, detailed measurements of momentum distributions of emitted electrons have allowed the investigation of the thermal limit of the transverse emittance from metal photocathodes. Furthermore, recent developments in material design and growth have resulted in photocathodes that can deliver high quantum efficiency and are sufficiently robust to use in high electric field gradient photoinjectors and free electron lasers. The growth process usually produces photoemissive material layers with rough surface profiles that lead to transverse accelerating fields and possible work function variations, resulting in emittance growth. To better understand the effects of temperature, density of states, and surface roughness on themore » properties of emitted electrons, we have developed realistic three-dimensional models for photocathode materials with grated surface structures. They include general modeling of electron excitation due to photon absorption, charge transport, and emission from flat and rough metallic surfaces. The models also include image charge and field enhancement effects. We report results from simulations with flat and rough surfaces to investigate how electron scattering, controlled roughness, work function variation, and field enhancement affect emission properties. Comparison of simulation results with measurements of the quantum yield and transverse emittance from flat Sb emission surfaces shows the importance of including efficient modeling of photon absorption, temperature effects, and the material density of states to achieve agreement with the experimental data.« less

Influences of temperature and impurity on excited state of bound polaron in the parabolic quantum dots

NASA Astrophysics Data System (ADS)

Xiao, Jing-Lin

2014-06-01

On the condition of strong electron-LO phonon coupling in parabolic quantum dot (QD), the first excited state energy, the excitation energy and the transition frequency between the first excited and the ground states of the bound polaron are calculated by using the linear combination operator and the unitary transformation methods. The variation of the above quantities with the temperature, the Coulombic impurity potential and the QD confinement strength are studied in detail. We find that (1) These physical quantities will increase with increasing temperature. (2) They are increasing functions of the confinement strength due to the existence of the Coulombic impurity potential between the electron and the hydrogen-like impurity. (3) We obtain three ways of tuning them via controlling the temperature, the Coulombic impurity potential and the confinement strength.

Analysis of hydrogen plasma in MPCVD reactor

NASA Astrophysics Data System (ADS)

Shivkumar, Gayathri

The aim of this work is to build a numerical model that can predict the plasma properties of hydrogen plasmas inside a Seki Technotron Corp. AX5200S MPCVD system so that it may be used to understand and optimize the conditions for the growth of carbon nanostructures. A 2D model of the system is used in the finite element high frequency Maxwell solver and heat trasfer solver in COMSOL Multiphysics, where the solvers are coupled with user defined functions to analyze the plasma. A simplified chemistry model is formulated in order to determine the electron temperature in the plasma. This is used in the UDFs which calculate the electron number density as well as electron temperature. A Boltzmann equation solver for electrons in weakly ionized gases under uniform electric fields, called BOLSIG+, is used to obtain certain input parameters required for these UDFs. The system is modeled for several reactor geometries at pressures of 10 Torr and 30 Torr and powers ranging from 300 W to 700 W. The variation of plasma characteristics with changes in input conditions is studied and the electric field, electron number density, electron temperature and gas temperature are seen to increase with increasing power. Electric field, electron number density and electron temperature decrease and gas temperature increases with increasing pressure. The modeling results are compared with experimental measurements and a good agreement is found after calibrating the parameter gamma in Funer's model to match experimental electron number densities. The gas temperature is seen to have a weak dependence on power and a strong dependence on gas pressure. On an average, the gas temperature at a point 5 mm above the center of the puck increases from about 1000 K at a pressure of 10 Torr to about 1500 K at 30 Torr. The inclusion of the pillar produces an increase in the maximum electron number density of approximately 50%; it is higher under some conditions. It increases the maximum electron temperature by about 70% and at 500 W and 30 Torr, the maximum gas temperature is seen to increase by 50%. The effect of susceptor position is studied and it is seen that the only condition favorable to growth would be to raise it by less than 25 mm from the initial reference position or to maintain it at the same level.

Possible modification of the cooling index of interstellar helium pickup ions by electron impact ionization in the inner heliosphere

NASA Astrophysics Data System (ADS)

Chen, Jun Hong; Bochsler, Peter; Möbius, Eberhard; Gloeckler, George

2014-09-01

Interstellar neutrals penetrating into the inner heliosphere are ionized by photoionization, charge exchange with solar wind ions, and electron impact ionization. These processes comprise the first step in the evolution of interstellar pickup ion (PUI) distributions. Typically, PUI distributions have been described in terms of velocity distribution functions that cool adiabatically under solar wind expansion, with a cooling index of 3/2. Recently, the cooling index has been determined experimentally in observations of He PUI distributions with Advanced Composition Explorer (ACE)/Solar Wind Ion Composition Spectrometer and found to vary substantially over the solar cycle. The experimental determination of the cooling index depends on the knowledge of the ionization rates and their spatial variation. Usually, ionization rates increase with 1/r2 as neutral particles approach the Sun, which is not exactly true for electron impact ionization, because the electron temperature increases with decreasing distance from the Sun due to the complexity of its distributions and different radial gradients in temperature. This different dependence on distance may become important in the study of the evolution of PUI distributions and is suspected as one of the potential reasons for the observed variation of the cooling index. Therefore, we investigate in this paper the impact of electron ionization on the variability of the cooling index. We find that the deviation of the electron ionization rate from the canonical 1/r2 behavior of other ionization processes plays only a minor role.

Electron-phonon heat exchange in quasi-two-dimensional nanolayers

NASA Astrophysics Data System (ADS)

Anghel, Dragos-Victor; Cojocaru, Sergiu

2017-12-01

We study the heat power P transferred between electrons and phonons in thin metallic films deposited on free-standing dielectric membranes. The temperature range is typically below 1 K, such that the wavelengths of the excited phonon modes in the system is large enough so that the picture of a quasi-two-dimensional phonon gas is applicable. Moreover, due to the quantization of the components of the electron wavevectors perpendicular to the metal film's surface, the electrons spectrum forms also quasi two-dimensional sub-bands, as in a quantum well (QW). We describe in detail the contribution to the electron-phonon energy exchange of different electron scattering channels, as well as of different types of phonon modes. We find that heat flux oscillates strongly with thickness of the film d while having a much smoother variation with temperature (Te for the electrons temperature and Tph for the phonons temperature), so that one obtains a ridge-like landscape in the two coordinates, (d, Te) or (d, Tph), with crests and valleys aligned roughly parallel to the temperature axis. For the valley regions we find P ∝ Te3.5 - Tph3.5. From valley to crest, P increases by more than one order of magnitude and on the crests P cannot be represented by a simple power law. The strong dependence of P on d is indicative of the formation of the QW state and can be useful in controlling the heat transfer between electrons and crystal lattice in nano-electronic devices. Nevertheless, due to the small value of the Fermi wavelength in metals, the surface imperfections of the metallic films can reduce the magnitude of the oscillations of P vs. d, so this effect might be easier to observe experimentally in doped semiconductors.

Theory of electron--photon scattering effects in metals. Progress report, December 1, 1976--November 30, 1977

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lawrence, W.E.

1977-01-01

The general areas in which the investigations were carried out are transport properties and quasiparticle lifetimes in normal metals and superconductors. The more specific research projects upon which progress is reported are (a) the calculation of order parameter relaxation times in aluminum, (b) transport coefficients of the noble metals (emphasizing deviations from Matthiessen's rule), (c) variational transport calculations for a superconductor, (d) some general results on quasiparticle relaxation time anisotropy in polyvalent metals, and (e) a clarification of the roles of electron-electron and electron-phonon scattering in somple metals at low temperatures.

Structural, magnetic, and magnetocaloric properties of bilayer manganite La1.38Sr1.62Mn2O7

NASA Astrophysics Data System (ADS)

Yang, Yu-E.; Xie, Yunfei; Xu, Lisha; Hu, Dazhi; Ma, Chunlan; Ling, Langsheng; Tong, Wei; Pi, Li; Zhang, Yuheng; Fan, Jiyu

2018-04-01

In this study, we investigated the structural, magnetic phase transition, and magnetocaloric properties of bilayer perovskite manganite La1.38Sr1.62Mn2O7 based on X-ray diffraction, electron paramagnetic resonance, and temperature-/magnetic field-dependent magnetization measurements. The structural characterization results showed the prepared sample had a tetragonal structure with the space group I4/mmm. The Curie temperature was determined as 114 K in the magnetization studies and a second-order paramagnetic-ferromagnetic transition was confirmed by the Arrott plot, which showed that the slopes were positive for all the curves. According to the variation in the electron paramagnetic resonance spectrum, we detected obvious electronic phase separation across a broad temperature range from 220 to 80 K in this magnetic material, thereby indicating that the paramagnetic and ferromagnetic phases coexist above as well as below the Curie temperature. Based on a plot of the isothermal magnetization versus the magnetic applied field, we deduced the maximum magnetic entropy change, which only reached 1.89 J/kg.K under an applied magnetic field of 7.0 T. These theoretical investigations indicated that in addition to the magnetoelastic couplings and electron interaction, electronic phase separation and anisotropic exchange interactions also affect the magnetic entropy changes in this bilayer manganite.

Thermo-mechanical behavior of power electronic packaging assemblies: From characterization to predictive simulation of lifetimes

NASA Astrophysics Data System (ADS)

Dalverny, O.; Alexis, J.

2018-02-01

This article deals with thermo-mechanical behavior of power electronic modules used in several transportation applications as railway, aeronautic or automotive systems. Due to a multi-layered structures, involving different materials with a large variation of coefficient of thermal expansion, temperature variations originated from active or passive cycling (respectively from die dissipation or environmental constraint) induces strain and stresses field variations, giving fatigue phenomenon of the system. The analysis of the behavior of these systems and their dimensioning require the implementation of complex modeling strategies by both the multi-physical and the multi-scale character of the power modules. In this paper we present some solutions for studying the thermomechanical behavior of brazed assemblies as well as taking into account the interfaces represented by the numerous metallizations involved in the process assembly.

A spectroscopic study using line ratios of lithiumlike ions in a laser-produced plasma

NASA Astrophysics Data System (ADS)

Moreno, J. C.; Goldsmith, S.; Griem, H. R.

1989-02-01

Spectra of highly ionized titanium and calcium in the extreme ultraviolet region were observed in laser-produced plasmas using the OMEGA 24 beam (351 nm) laser system at the University of Rochester. The plasmas were produced using glass microballoon targets coated with a layer of a medium Z element and a layer of parylene (CH). Time-integrated electron temperatures and densities were obtained by comparing measured line intensity ratios of lithiumlike charge states of Ti and Ca to numerical calculations from a collisional-radiative model. The variation of line intensity ratios with electron density and temperature using the collisional-radiative model is discussed.

Direct ab initio dynamics study of the reaction of C 2(A 3Π u) radical with C 2H 6

NASA Astrophysics Data System (ADS)

Li, Na; Huo, Rui-Ping; Zhang, Xiang; Huang, Xu-Ri; Li, Ji-Lai; Sun, Chia-Chung

2011-02-01

The reaction of C 2 (A 3Π u) with C 2H 6 has been investigated at the BMC-CCSD//BB1K/6-311+G(2d, 2p) level. The classical barrier height for H-abstraction reaction is calculated to be 3.32 kcal/mol and the electron transfer behavior is also analyzed in detail. The rate constants are calculated by TST, CVT, and CVT/SCT over a wide temperature range 50-3000 K. The results indicate: (1) variational effect is small and nonclassical reflection effect is important to the H abstraction in high temperature region; and (2) variational effect is negligible and tunneling effect cooperating with the nonclassical reflection effect makes the rate constant temperature independence in low-temperature range. The CVT/SCT rate constants are in excellent agreement with experimental values.

An influence of solar activity on latitudinal distribution of atmospheric ozone and temperature in 2-D radiative-photochemical model

NASA Technical Reports Server (NTRS)

Dyominov, I. G.

1989-01-01

On the basis of the 2-D radiative-photochemical model of the ozone layer at heights 0 to 60 km in the Northern Hemisphere there are revealed and analyzed in detail the characteristic features of the season-altitude-latitude variations of ozone and temperature due to changes of the solar flux during the 11 year cycle, electron and proton precipitations.

The effect of reaction temperature on the room temperature ferromagnetic property of sol-gel derived tin oxide nanocrystal

NASA Astrophysics Data System (ADS)

Sakthiraj, K.; Hema, M.; Balachandra Kumar, K.

2018-06-01

In the present study, nanocrystalline tin oxide materials were prepared using sol-gel method with different reaction temperatures (25 °C, 50 °C, 75 °C & 90 °C) and the relation between the room temperature ferromagnetic property of the sample with processing temperature has been analysed. The X-ray diffraction pattern and infrared absorption spectra of the as-prepared samples confirm the purity of the samples. Transmission electron microscopy images visualize the particle size variation with respect to reaction temperature. The photoluminescence spectra of the samples demonstrate that luminescence process in materials is originated due to the electron transition mediated by defect centres. The room temperature ferromagnetic property is observed in all the samples with different amount, which was confirmed using vibrating sample magnetometer measurements. The saturation magnetization value of the as-prepared samples is increased with increasing the reaction temperature. From the photoluminescence & magnetic measurements we accomplished that, more amount of surface defects like oxygen vacancy and tin interstitial are created due to the increase in reaction temperature and it controls the ferromagnetic property of the samples.

Magnetospheric Multiscale Observations of Electron Vortex Magnetic Hole in the Turbulent Magnetosheath Plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, S. Y.; Yuan, Z. G.; Wang, D. D.

We report on the observations of an electron vortex magnetic hole corresponding to a new type of coherent structure in the turbulent magnetosheath plasma using the Magnetospheric Multiscale mission data. The magnetic hole is characterized by a magnetic depression, a density peak, a total electron temperature increase (with a parallel temperature decrease but a perpendicular temperature increase), and strong currents carried by the electrons. The current has a dip in the core region and a peak in the outer region of the magnetic hole. The estimated size of the magnetic hole is about 0.23 ρ {sub i} (∼30 ρ {submore » e}) in the quasi-circular cross-section perpendicular to its axis, where ρ {sub i} and ρ {sub e} are respectively the proton and electron gyroradius. There are no clear enhancements seen in high-energy electron fluxes. However, there is an enhancement in the perpendicular electron fluxes at 90° pitch angle inside the magnetic hole, implying that the electrons are trapped within it. The variations of the electron velocity components V {sub em} and V {sub en} suggest that an electron vortex is formed by trapping electrons inside the magnetic hole in the cross-section in the M – N plane. These observations demonstrate the existence of a new type of coherent structures behaving as an electron vortex magnetic hole in turbulent space plasmas as predicted by recent kinetic simulations.« less

The coupling between the ionosphere and the protonosphere and its implications on the long term variations of ionospheric electron content

NASA Technical Reports Server (NTRS)

Waldman, H.

1971-01-01

The long-term variations in the daytime exchange flux are estimated with the use of model hydrogen concentrations based on the inverse relationship between the abundance of neutral hydrogen and the neutral temperature in the thermosphere. The results are found to be compatible with the observed long-term behavior of the ionospheric electron content at a midlatitude location, as revealed by Faraday observations using geostationary satellites. The basic processes occurring in the ionosphere are reviewed, with emphasis on the concepts of limiting velocity and limiting flux. An approach to the problem of numerical simulation of the ionosphere is also presented and discussed.

Temperature dependence of the Urbach optical absorption edge: A theory of multiple phonon absorption and emission sidebands

NASA Astrophysics Data System (ADS)

Grein, C. H.; John, Sajeev

1989-01-01

The optical absorption coefficient for subgap electronic transitions in crystalline and disordered semiconductors is calculated by first-principles means with use of a variational principle based on the Feynman path-integral representation of the transition amplitude. This incorporates the synergetic interplay of static disorder and the nonadiabatic quantum dynamics of the coupled electron-phonon system. Over photon-energy ranges of experimental interest, this method predicts accurate linear exponential Urbach behavior of the absorption coefficient. At finite temperatures the nonlinear electron-phonon interaction gives rise to multiple phonon emission and absorption sidebands which accompany the optically induced electronic transition. These sidebands dominate the absorption in the Urbach regime and account for the temperature dependence of the Urbach slope and energy gap. The physical picture which emerges is that the phonons absorbed from the heat bath are then reemitted into a dynamical polaronlike potential well which localizes the electron. At zero temperature we recover the usual polaron theory. At high temperatures the calculated tail is qualitatively similar to that of a static Gaussian random potential. This leads to a linear relationship between the Urbach slope and the downshift of the extrapolated continuum band edge as well as a temperature-independent Urbach focus. At very low temperatures, deviations from these rules are predicted arising from the true quantum dynamics of the lattice. Excellent agreement is found with experimental data on c-Si, a-Si:H, a-As2Se3, and a-As2S3. Results are compared with a simple physical argument based on the most-probable-potential-well method.

Polaron mobility obtained by a variational approach for lattice Fröhlich models

NASA Astrophysics Data System (ADS)

Kornjača, Milan; Vukmirović, Nenad

2018-04-01

Charge carrier mobility for a class of lattice models with long-range electron-phonon interaction was investigated. The approach for mobility calculation is based on a suitably chosen unitary transformation of the model Hamiltonian which transforms it into the form where the remaining interaction part can be treated as a perturbation. Relevant spectral functions were then obtained using Matsubara Green's functions technique and charge carrier mobility was evaluated using Kubo's linear response formula. Numerical results were presented for a wide range of electron-phonon interaction strengths and temperatures in the case of one-dimensional version of the model. The results indicate that the mobility decreases with increasing temperature for all electron-phonon interaction strengths in the investigated range, while longer interaction range leads to more mobile carriers.

Basic electronic properties of iron selenide under variation of structural parameters

NASA Astrophysics Data System (ADS)

Guterding, Daniel; Jeschke, Harald O.; Valentí, Roser

2017-09-01

Since the discovery of high-temperature superconductivity in the thin-film FeSe /SrTiO3 system, iron selenide and its derivates have been intensively scrutinized. Using ab initio density functional theory calculations we review the electronic structures that could be realized in iron selenide if the structural parameters could be tuned at liberty. We calculate the momentum dependence of the susceptibility and investigate the symmetry of electron pairing within the random phase approximation. Both the susceptibility and the symmetry of electron pairing depend on the structural parameters in a nontrivial way. These results are consistent with the known experimental behavior of binary iron chalcogenides and, at the same time, reveal two promising ways of tuning superconducting transition temperatures in these materials: on one hand by expanding the iron lattice of FeSe at constant iron-selenium distance and, on the other hand, by increasing the iron-selenium distance with unchanged iron lattice.

Electron energy distribution function, effective electron temperature, and dust charge in the temporal afterglow of a plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Denysenko, I. B.; Azarenkov, N. A.; Kersten, H.

2016-05-15

Analytical expressions describing the variation of electron energy distribution function (EEDF) in an afterglow of a plasma are obtained. Especially, the case when the electron energy loss is mainly due to momentum-transfer electron-neutral collisions is considered. The study is carried out for different EEDFs in the steady state, including Maxwellian and Druyvesteyn distributions. The analytical results are not only obtained for the case when the rate for momentum-transfer electron-neutral collisions is independent on electron energy but also for the case when the collisions are a power function of electron energy. Using analytical expressions for the EEDF, the effective electron temperaturemore » and charge of the dust particles, which are assumed to be present in plasma, are calculated for different afterglow durations. An analytical expression for the rate describing collection of electrons by dust particles for the case when the rate for momentum-transfer electron-neutral collisions is independent on electron energy is also derived. The EEDF profile and, as a result, the effective electron temperature and dust charge are sufficiently different in the cases when the rate for momentum-transfer electron-neutral collisions is independent on electron energy and when the rate is a power function of electron energy.« less

Temperature Variations and N+/O+ in the Orion Nebula II. The Collision Strengths

NASA Astrophysics Data System (ADS)

Rubin, R. H.; Dufour, R. J.; Martin, P. G.; Ferland, G. J.; Baldwin, J. A.; Ortiz, C. O.; Walter, D. K.

2001-03-01

We continue an investigation of electron temperature (T[e]), mean-square T[e] variation (t2), and the N+/O+ abundance ratio. Our previous analysis of HST spectra of the Orion Nebula used collision strengths for N+ by Stafford et al. (1994). Here we examine the consequences of changing just these collision strengths by using those of Lennon & Burke (1994). Rather than utilize the standard analytical, low electron density (N[e]) regime treatment for the analysis, we develop a numerical technique that is valid at any density. With Stafford et al. collision strengths, we find the average N[e] for the (N+, O+)-zone is 7500 cm-3, the average T[e] is 9160 K, t2 is 0.045, and N+/O+ is 0.14. Using Lennon & Burke values, the ``best" solution is found when these respective quantities are: 9000 cm-3, 9920 K, 0.00073, and 0.15. The value for t2 is dramatically lower than that found using Stafford et al. data.

Synthesis of highly-monodisperse spherical titania particles with diameters in the submicron range.

PubMed

Tanaka, Shunsuke; Nogami, Daisuke; Tsuda, Natsuki; Miyake, Yoshikazu

2009-06-15

Monodisperse titania spheres with particle diameters in the range 380-960 nm were successfully synthesized by hydrolysis and condensation of titanium tetraisopropoxide. The preparation was performed using ammonia or dodecylamine (DDA) as a catalyst in methanol/acetonitrile co-solvent at room temperature. The samples were characterized by powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, dynamic light scattering, and nitrogen sorption measurement. The use of DDA was effective for the synthesis of monodisperse titania spheres with low coefficient of variation. When the titania spherical particles with coefficient of variation less than 4% were obtained, the colloidal crystallization easily occurred simply by centrifugation. The monodispersity was maintained even after crystallization of the particles by high temperature annealing. The titania particles prepared using DDA had mesopores near the surface of the spheres, providing high pore accessibility to the sphere from the surface-air interface. The particle size uniformity and photocatalytic reactivity of the titania prepared using DDA were higher than those of the titania prepared using ammonia.

Spectral lines and characteristic of temporal variations in photoionized plasmas induced with laser-produced plasma extreme ultraviolet source

NASA Astrophysics Data System (ADS)

Saber, I.; Bartnik, A.; Wachulak, P.; Skrzeczanowski, W.; Jarocki, R.; Fiedorowicz, H.

2017-11-01

Spectral lines for Kr/Ne/H2 photoionized plasma in the ultraviolet and visible (UV/Vis) wavelength ranges have been created using a laser-produced plasma (LPP) EUV source. The source is based on a double-stream gas puff target irradiated with a commercial Nd:YAG laser. The laser pulses were focused onto a gas stream, injected into a vacuum chamber synchronously with the EUV pulses. Spectral lines from photoionization in neutral Kr/Ne/H2 and up to few charged states were observed. The intense emission lines were associated with the Kr transition lines. Experimental and theoretical investigations on intensity variations for some ionic lines are presented. A decrease in the intensity with the delay time between the laser pulse and the spectrum acquisition was revealed. Electron temperature and electron density in the photoionized plasma have been estimated from the characteristic emission lines. Temperature was obtained using Boltzmann plot method, assuming that the population density of atoms and ions are considered in a local thermodynamic equilibrium (LTE). Electron density was calculated from the Stark broadening profile. The temporal evaluation of the plasma and the way of optimizing the radiation intensity of LPP EUV sources is discussed.

Commissioning a p-type silicon diode for use in clinical electron beams.

PubMed

Eveling, J N; Morgan, A M; Pitchford, W G

1999-01-01

Commissioning measurements were carried out on a p-type silicon diode detector for use in patient monitoring in high energy electron beams. Characteristics specific to the diode were examined. The variation in diode sensitivity with dose per pulse was found to be less than 1% over a range 0.069-0.237 mGy/pulse. The diode exhibited a sensitivity variation with accumulated dose of 10% per kGy and a sensitivity variation with surface temperature of 0.26%/degree C. The dependence of the diode response on the direction of the incident electron beam was investigated. Results were found to exceed the manufacturer's specifications. Output factors measured with the diode agree to within 1.5% of those measured with an NACP-02 air ionization chamber. The detector showed a variation in response with energy of 0.8% over the energy range 4-15 MeV. Prior to introducing the diode into clinical use, an assessment of beam perturbation directly behind the diode was made. The maximum reduction in local dose directly behind the diode at a depth of 1.0 cm below the surface was approximately 13% at 4 and 15 MeV.

Long-term stability of the Io high-temperature plasma torus

NASA Technical Reports Server (NTRS)

Moos, H. W.; Skinner, T. E.; Durrance, S. T.; Feldman, P. D.; Festou, M. C.

1985-01-01

The short wavelength camera of the International Ultraviolet Explorer satellite was used to measure S II 1256, S III 1199, semiforbidden S III 1729, and semiforbidden S IV 1406 emission from the high-temperature region of the Io plasma torus. Observations over a period of five years (1979-1984) indicate that the Io plasma parameters have relatively small variations, particularly in the case of the mixing ratio for the dominant constituent S(++), and electron temperature. A simple three-dimensional model of the plasma torus was used to obtain the ion mixing ratios and the plasma density for each observation. The results are compared with Voyager 1 data for mixing ratio (ion density divided by electron density); ionization balance; and plasma density. The results of the comparison are discussed in detail.

High temperature dielectric studies of indium-substituted NiCuZn nanoferrites

NASA Astrophysics Data System (ADS)

Hashim, Mohd.; Raghasudha, M.; Shah, Jyoti; Shirsath, Sagar E.; Ravinder, D.; Kumar, Shalendra; Meena, Sher Singh; Bhatt, Pramod; Alimuddin; Kumar, Ravi; Kotnala, R. K.

2018-01-01

In this study, indium (In3+)-substituted NiCuZn nanostructured ceramic ferrites with a chemical composition of Ni0.5Cu0.25Zn0.25Fe2-xInxO4 (0.0 ≤ x ≤ 0.5) were prepared by chemical synthesis involving sol-gel chemistry. Single phased cubic spinel structure materials were prepared successfully according to X-ray diffraction and transmission electron microscopy analyses. The dielectric properties of the prepared ferrites were measured using an LCR HiTester at temperatures ranging from room temperature to 300 °C at different frequencies from 102 Hz to 5 × 106 Hz. The variations in the dielectric parameters ε‧ and (tanδ) with temperature demonstrated the frequency- and temperature-dependent characteristics due to electron hopping between the ions. The materials had low dielectric loss values in the high frequency range at all temperatures, which makes them suitable for high frequency microwave applications. A qualitative explanation is provided for the dependences of the dielectric constant and dielectric loss tangent on the frequency, temperature, and composition. Mӧssbauer spectroscopy was employed at room temperature to characterize the magnetic behavior.

Dislocation loop formation by swift heavy ion irradiation of metals.

PubMed

Khara, Galvin S; Murphy, Samuel T; Duffy, Dorothy M

2017-07-19

A coupled two-temperature, molecular dynamics methodology is used to simulate the structural evolution of bcc metals (Fe and W) and fcc metals (Cu and Ni) following irradiation by swift heavy ions. Electronic temperature dependent electronic specific heat capacities and electron-phonon coupling strengths are used to capture the full effects of the variation in the electronic density of states. Tungsten is found to be significantly more resistant to damage than iron, due both to the higher melting temperature and the higher thermal conductivity. Very interesting defect structures, quite different from defects formed in cascades, are found to be created by swift heavy ion irradiation in the bcc metals. Isolated vacancies form a halo around elongated interstitial dislocation loops that are oriented along the ion path. Such configurations are formed by rapid recrystallization of the molten cylindrical region that is created by the energetic ion. Vacancies are created at the recrystallization front, resulting in excess atoms at the core which form interstitial dislocation loops on completion of crystallization. These unique defect structures could, potentially, be used to create metal films with superior mechanical properties and interesting nanostructures.

Dislocation loop formation by swift heavy ion irradiation of metals

NASA Astrophysics Data System (ADS)

Khara, Galvin S.; Murphy, Samuel T.; Duffy, Dorothy M.

2017-07-01

A coupled two-temperature, molecular dynamics methodology is used to simulate the structural evolution of bcc metals (Fe and W) and fcc metals (Cu and Ni) following irradiation by swift heavy ions. Electronic temperature dependent electronic specific heat capacities and electron-phonon coupling strengths are used to capture the full effects of the variation in the electronic density of states. Tungsten is found to be significantly more resistant to damage than iron, due both to the higher melting temperature and the higher thermal conductivity. Very interesting defect structures, quite different from defects formed in cascades, are found to be created by swift heavy ion irradiation in the bcc metals. Isolated vacancies form a halo around elongated interstitial dislocation loops that are oriented along the ion path. Such configurations are formed by rapid recrystallization of the molten cylindrical region that is created by the energetic ion. Vacancies are created at the recrystallization front, resulting in excess atoms at the core which form interstitial dislocation loops on completion of crystallization. These unique defect structures could, potentially, be used to create metal films with superior mechanical properties and interesting nanostructures.

A novel analytical model for scattering limited electron transport in nano-dimensional InAlAs/InGaAs heterostructure for cryogenic applications

NASA Astrophysics Data System (ADS)

Sharma, Neetika; Verma, Neha; Jogi, Jyotika

2017-11-01

This paper models the scattering limited electron transport in a nano-dimensional In0.52Al0.48As/In0.53Ga0.47As/InP heterostructure. An analytical model for temperature dependent sheet carrier concentration and carrier mobility in a two dimensional electron gas, confined in a triangular potential well has been developed. The model accounts for all the major scattering process including ionized impurity scattering and lattice scattering. Quantum mechanical variational technique is employed for studying the intrasubband scattering mechanism in the two dimensional electron gas. Results of various scattering limited structural parameters such as energy band-gap and functional parameters such as sheet carrier concentration, scattering rate and mobility are presented. The model corroborates the dominance of ionized impurity scattering mechanism at low temperatures and that of lattice scattering at high temperatures, both in turn limiting the carrier mobility. Net mobility obtained taking various scattering mechanisms into account has been found in agreement with earlier reported results, thus validating the model.

Multiphonon contribution to the polaron formation in cuprates with strong electron correlations and strong electron-phonon interaction

NASA Astrophysics Data System (ADS)

Ovchinnikov, Sergey G.; Makarov, Ilya A.; Kozlov, Peter A.

2017-03-01

In this work dependences of the electron band structure and spectral function in the HTSC cuprates on magnitude of electron-phonon interaction (EPI) and temperature are investigated. We use three-band p-d model with diagonal and offdiagonal EPI with breathing and buckling phonon mode in the frameworks of polaronic version of the generalized tight binding (GTB) method. The polaronic quasiparticle excitation in the system with EPI within this approach is formed by a hybridization of the local multiphonon Franck-Condon excitations with lower and upper Hubbard bands. Increasing EPI leads to transfer of spectral weight to high-energy multiphonon excitations and broadening of the spectral function. Temperature effects are taken into account by occupation numbers of local excited polaronic states and variations in the magnitude of spin-spin correlation functions. Increasing the temperature results in band structure reconstruction, spectral weight redistribution, broadening of the spectral function peak at the top of the valence band and the decreasing of the peak intensity. The effect of EPI with two phonon modes on the polaron spectral function is discussed.

Studies of magnetostriction and spin polarized band structures of rare earth intermetallics

NASA Technical Reports Server (NTRS)

Wallace, W. E.

1979-01-01

Anisotropic magnetostriction measurements of R6Fe23, R = (Tb, Dy, Ho, and Er) were carried out from 77 K to room temperature. Magnetic fields up to 2.1 Tesla were applied. All the compounds exhibited large magnetostrictions at 77 K, the largest effect being obtained for Tb6Fe23. Saturation magnetostriction values for the compounds were also determined for 77 K and room temperature. Results of the temperature dependence of magnetostriction for Er6Fe23 are in good agreement with Callen and Callen's single ion theory. Therefore, the main sources of magnetostriction in this compound is the Er ion. The spin-up and spin-down electronic energy bands, the density of states and the magnetic moments of YCo5, SmCo5, and GdCo5 were calculated by the spin polarized augmented plane wave technique. The calculations obtained show the origin of the moment, provide good estimates of its magnitude and variation, and the reasons for those variations. They also show the important role of partial charge transfer and of d-d electronic coupling. Calculations for LaNi5 and GdNi5 systems are discussed.

Three-dimensional simulation of microwave-induced helium plasma under atmospheric pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, G. L.; Hua, W., E-mail: huaw@scu.edu.cn; Guo, S. Y.

2016-07-15

A three-dimensional model is presented to investigate helium plasma generated by microwave under atmospheric pressure in this paper, which includes the physical processes of electromagnetic wave propagation, electron and heavy species transport, gas flow, and heat transfer. The model is based on the fluid approximation calculation and local thermodynamic equilibrium assumption. The simulation results demonstrate that the maxima of the electron density and gas temperature are 4.79 × 10{sup 17 }m{sup −3} and 1667 K, respectively, for the operating conditions with microwave power of 500 W, gas flow rate of 20 l/min, and initial gas temperature of 500 K. The electromagnetic field distribution in the plasma sourcemore » is obtained by solving Helmholtz equation. Electric field strength of 2.97 × 10{sup 4 }V/m is obtained. There is a broad variation on microwave power, gas flow rate, and initial gas temperature to obtain deeper information about the changes of the electron density and gas temperature.« less

Electronic and Interfacial Properties of PD/6H-SiC Schottky Diode Gas Sensors

NASA Technical Reports Server (NTRS)

Chen, Liang-Yu; Hunter, Gary W.; Neudeck, Philip G.; Bansal, Gaurav; Petit, Jeremy B.; Knight, Dak; Liu, Chung-Chiun; Wu, Qinghai

1996-01-01

Pd/SiC Schottky diodes detect hydrogen and hydrocarbons with high sensitivity. Variation of the diode temperature from 100 C to 200 C shows that the diode sensitivity to propylene is temperature dependent. Long-term heat treating at 425 C up to 140 hours is carried out to determine the effect of extended heat treating on the diode properties and gas sensitivity. The heat treating significantly affects the diode's capacitive characteristics, but the diode's current carrying characteristics are much more stable with a large response to hydrogen. Scanning Electron Microscopy and X-ray Spectrometry studies of the Pd surface after the heating show cluster formation and background regions with grain structure observed in both regions. The Pd and Si concentrations vary between grains. Auger Electron Spectroscopy depth profiles revealed that the heat treating promoted interdiffusion and reaction between the Pd and SiC dw broadened the interface region. This work shows that Pd/SiC Schottky diodes have significant potential as high temperature gas sensors, but stabilization of the structure is necessary to insure their repeatability in long-term, high temperature applications.

Structural, Electronic and Dynamical Properties of Curium Monopnictides: Density Functional Calculations

NASA Astrophysics Data System (ADS)

Roondhe, Basant; Upadhyay, Deepak; Som, Narayan; Pillai, Sharad B.; Shinde, Satyam; Jha, Prafulla K.

2017-03-01

The structural, electronic, dynamical and thermodynamical properties of CmX (X = N, P, As, Sb, and Bi) compounds are studied using first principles calculations within density functional theory. The Perdew-Burke-Ernzerhof spin polarized generalized gradient approximation and Perdew-Wang (PW) spin polarized local density approximation as the exchange correlational functionals are used in these calculations. There is a good agreement between the present and previously reported data. The calculated electronic density of states suggests that the curium monopnictides are metallic in nature, which is consistent with earlier studies. The significant values of magnetic moment suggest their magnetic nature. The phonon dispersion curves and phonon density of states are also calculated, which depict the dynamical stability of these compounds. There is a significant separation between the optical and acoustical phonon branches. The temperature dependence of the thermodynamical functions are also calculated and discussed. Internal energy and vibrational contribution to the Helmholtz free energy increases and decreases, respectively, with temperature. The entropy increases with temperature. The specific heat at constant volume and Debye temperature obey Debye theory. The temperature variation of the considered thermodynamical functions is in line with those of other crystalline solids.

Hydrogen-induced morphotropic phase transformation of single-crystalline vanadium dioxide nanobeams.

PubMed

Hong, Woong-Ki; Park, Jong Bae; Yoon, Jongwon; Kim, Bong-Joong; Sohn, Jung Inn; Lee, Young Boo; Bae, Tae-Sung; Chang, Sung-Jin; Huh, Yun Suk; Son, Byoungchul; Stach, Eric A; Lee, Takhee; Welland, Mark E

2013-04-10

We report a morphotropic phase transformation in vanadium dioxide (VO2) nanobeams annealed in a high-pressure hydrogen gas, which leads to the stabilization of metallic phases. Structural analyses show that the annealed VO2 nanobeams are hexagonal-close-packed structures with roughened surfaces at room temperature, unlike as-grown VO2 nanobeams with the monoclinic structure and with clean surfaces. Quantitative chemical examination reveals that the hydrogen significantly reduces oxygen in the nanobeams with characteristic nonlinear reduction kinetics which depend on the annealing time. Surprisingly, the work function and the electrical resistance of the reduced nanobeams follow a similar trend to the compositional variation due mainly to the oxygen-deficiency-related defects formed at the roughened surfaces. The electronic transport characteristics indicate that the reduced nanobeams are metallic over a large range of temperatures (room temperature to 383 K). Our results demonstrate the interplay between oxygen deficiency and structural/electronic phase transitions, with implications for engineering electronic properties in vanadium oxide systems.

Field-Induced-Gap Infrared Detectors

NASA Technical Reports Server (NTRS)

Elliott, C. Thomas

1990-01-01

Semimetals become semiconductors under applied magnetic fields. New detectors require less cooling equipment because they operate at temperatures higher than liquid-helium temperatures required by extrinsic-semiconductor detectors. Magnetic fields for detectors provided by electromagnets based on recently-discovered high-transition-temperature superconducting materials. Detector material has to be semiconductor, in which photon absorbed by exciting electron/hole pair across gap Eg of forbidden energies between valence and conduction energy bands. Magnetic- and compositional-tuning effects combined to obtain two-absorber detector having narrow passband. By variation of applied magnetic field, passband swept through spectrum of interest.

Temperature dependence of spin-orbit torques in W/CoFeB bilayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skowroński, Witold, E-mail: skowron@agh.edu.pl; Cecot, Monika; Kanak, Jarosław

We report on the temperature variation of spin-orbit torques in perpendicularly magnetized W/CoFeB bilayers. Harmonic Hall voltage measurements in perpendicularly magnetized CoFeB reveal increased longitudinal and transverse effective magnetic field components at low temperatures. The damping-like spin-orbit torque reaches an efficiency of 0.55 at 19 K. Scanning transmission electron microscopy and X-ray reflectivity measurements indicate that considerable interface mixing between W and CoFeB may be responsible for strong spin-orbit interactions.

Variations in Cathodoluminescent Intensity of Spacecraft Materials Exposed to Energetic Electron Bombardment

NASA Technical Reports Server (NTRS)

Dekany, Justin; Christensen, Justin; Dennison, J. R.; Jensen, Amberly Evans; Wilson, Gregory; Schneider, Todd; Bowers, Charles W.; Meloy, Robert

2015-01-01

Many contemporary spacecraft materials exhibit cathodoluminescence when exposed to electron flux from the space plasma environment. A quantitative, physics-based model has been developed to predict the intensity of the total glow as a function of incident electron current density and energy, temperature, and intrinsic material properties. We present a comparative study of the absolute spectral radiance for more than 20 types of dielectric and composite materials based on this model which spans more than three orders of magnitude. Variations in intensity are contrasted for different electron environments, different sizes of samples and sample sets, different testing and analysis methods, and data acquired at different test facilities. Together, these results allow us to estimate the accuracy and precision to which laboratory studies may be able to determine the response of spacecraft materials in the actual space environment. It also provides guidance as to the distribution of emissions that may be expected for sets of similar flight hardware under similar environmental conditions.

Variations in Cathodoluminescent Intensity of Spacecraft Materials Exposed to Energetic Electron Bombardment

NASA Technical Reports Server (NTRS)

Dekany, Justin; Christensen, Justin; Dennison, J. R.; Jensen, Amberly Evans; Wilson, Gregory; Schneider, Todd A.; Bowers, Charles W.; Meloy, Robert

2014-01-01

Many contemporary spacecraft materials exhibit cathodoluminescence when exposed to electron flux from the space plasma environment. A quantitative, physics-based model has been developed to predict the intensity of the glow as a function of incident electron current density and energy, temperature, and intrinsic material properties. We present a comparative study of the absolute spectral radiance for several types of dielectric and composite materials based on this model which spans three orders of magnitude. Variations in intensity are contrasted for different electron environments, different sizes of samples and sample sets, different testing and analysis methods, and data acquired at different test facilities. Together, these results allow us to estimate the accuracy and precision to which laboratory studies may be able to determine the response of spacecraft materials in the actual space environment. It also provides guidance as to the distribution of emissions that may be expected for sets of similar flight hardware under similar environmental conditions.

Analysis of coronal H I Lyman alpha measurements from a rocket flight on 1979 April 13

NASA Technical Reports Server (NTRS)

Withbroe, G. L.; Kohl, J. L.; Weiser, H.; Noci, G.; Munro, R. H.

1982-01-01

It is noted that measurements of the profiles of resonantly scattered hydrogen Lyman-alpha coronal radiation have been used in determining hydrogen kinetic temperatures from 1.5 to 4 solar radii from sun center in a quiet region of the corona. Proton temperatures derived using the line widths decrease with height from 2.6 x 10 to the 6th K at 1.5 solar radii to 1.2 x 10 to the 6th K at 4 solar radii. These measurements, together with temperatures for lower heights determined from earlier Skylab and eclipse data, suggest that there is a maximum in the quiet coronal proton temperature at about 1.5 solar radii. Comparison of measured Lyman-alpha intensities with those calculated using a representative model for the radial variation of the coronal electron density yields information on the magnitude of the electron temperature gradient and suggests that the solar wind flow was subsonic for distances less than 4 solar radii.

NASCAP modelling of environmental-charging-induced discharges in satellites

NASA Technical Reports Server (NTRS)

Stevens, N. J.; Roche, J. C.

1979-01-01

The charging and discharging characteristics of a typical geosynchronous satellite experiencing time-varying geomagnetic substorms, in sunlight, were studied utilizing the NASA Charging Analyzer Program (NASCAP). An electric field criteria of 150,000 volts/cm to initiate discharges and transfer of 67 percent of the stored charge was used based on ground test results. The substorm characteristics were arbitrarily chosen to evaluate effects of electron temperature and particle density (which is equivalent to current density). It was found that while there is a minimum electron temperature for discharges to occur, the rate of discharges is dependent on particle density and duration times of the encounter. Hence, it is important to define the temporal variations in the substorm environments.

Observations at mercury encounter by the plasma science experiment on mariner 10.

PubMed

Ogilvie, K W; Scudder, J D; Hartle, R E; Siscoe, G L; Bridge, H S; Lazarus, A J; Asbridge, J R; Bame, S J; Yeates, C M

1974-07-12

A fully developed bow shock and magnetosheath were observed near Mercury, providing unambiguous evidence for a strong interaction between Mercury and the solar wind. Inside the sheath there is a distinct region analogous to the magnetosphere or magnetotail of Earth, populated by electrons with lower density and higher temperature than the electrons observed in the solar wind or magnetosheath. At the time of encounter, conditions were such that a perpendicular shock was observed on the inbound leg and a parallel shock was observed on the outbound leg of the trajectory, and energetic plasma electron events were detected upstream from the outbound shock crossing. The interaction is most likely not atmospheric, but the data clearly indicate that the obstacle to solar wind flow is magnetic, either intrinsic or induced. The particle fluxes and energy spectra showed large variations while the spacecraft was inside the magnetosphere, and these variations could be either spatial or temporal.

Stopping power of ions in a magnetized two-temperature plasma.

PubMed

Nersisyan, H B; Walter, M; Zwicknagel, G

2000-06-01

Using the dielectric theory for a weakly coupled plasma, we investigate the stopping power of an ion in an anisotropic two-temperature electron plasma in the presence of a magnetic field. The analysis is based on the assumption that the energy variation of the ion is much less than its kinetic energy. A general expression for the stopping power is analyzed for weak and strong magnetic fields (i.e., for the electron cyclotron frequency less than and greater than the plasma frequency), and for low and high ion velocities. It is found that the usually velocity independent friction coefficient contains an anomalous term which diverges logarithmically as the projectile velocity approaches zero. The physical origin of this anomalous term is the coupling between the cyclotron motion of the electrons and the long-wavelength, low-frequency fluctuations produced by the projectile ion.

Emergence of superconductivity in heavy-electron materials

PubMed Central

Yang, Yi-feng; Pines, David

2014-01-01

Although the pairing glue for the attractive quasiparticle interaction responsible for unconventional superconductivity in heavy-electron materials has been identified as the spin fluctuations that arise from their proximity to a magnetic quantum critical point, there has been no model to describe their superconducting transition at temperature Tc that is comparable to that found by Bardeen, Cooper, and Schrieffer (BCS) for conventional superconductors, where phonons provide the pairing glue. Here we propose such a model: a phenomenological BCS-like expression for Tc in heavy-electron materials that is based on a simple model for the effective range and strength of the spin-fluctuation-induced quasiparticle interaction and reflects the unusual properties of the heavy-electron normal state from which superconductivity emerges. We show that it provides a quantitative understanding of the pressure-induced variation of Tc in the “hydrogen atoms” of unconventional superconductivity, CeCoIn5 and CeRhIn5, predicts scaling behavior and a dome-like structure for Tc in all heavy-electron quantum critical superconductors, provides unexpected connections between members of this family, and quantifies their variations in Tc with a single parameter. PMID:25489102

Investigation of a possible electronic phase separation in the magnetic semiconductors Ga1 -xMnxAs and Ga1 -xMnxP by means of fluctuation spectroscopy

NASA Astrophysics Data System (ADS)

Lonsky, Martin; Teschabai-Oglu, Jan; Pierz, Klaus; Sievers, Sibylle; Schumacher, Hans Werner; Yuan, Ye; Böttger, Roman; Zhou, Shengqiang; Müller, Jens

2018-02-01

We present systematic temperature-dependent resistance noise measurements on a series of ferromagnetic Ga1 -xMnxAs epitaxial thin films covering a large parameter space in terms of the Mn content x and other variations regarding sample fabrication. We infer that the electronic noise is dominated by switching processes related to impurities in the entire temperature range. While metallic compounds with x >2 % do not exhibit any significant change in the low-frequency resistance noise around the Curie temperature TC, we find indications for an electronic phase separation in films with x <2 % in the vicinity of TC, manifesting itself in a maximum in the noise power spectral density. These results are compared with noise measurements on an insulating Ga1 -xMnxP reference sample, for which the evidence for an electronic phase separation is even stronger and a possible percolation of bound magnetic polarons is discussed. Another aspect addressed in this work is the effect of ion-irradiation-induced disorder on the electronic properties of Ga1 -xMnxAs films and, in particular, whether any electronic inhomogeneities can be observed in this case. Finally, we put our findings into the context of the ongoing debate on the electronic structure and the development of spontaneous magnetization in these materials.

Effect of annealing and In content on the properties of electron beam evaporated ZnO films

NASA Astrophysics Data System (ADS)

Mohamed, S. H.; Ali, H. M.; Mohamed, H. A.; Salem, A. M.

2005-08-01

The effect of both annealing and In content on the properties of ZnO films prepared by electron beam evaporation were investigated. The evaporation was carried out at room temperature from bulk samples prepared by sintering technique. X-ray diffraction showed that the structure of ZnO-In{2}O{3} films depends on both the In content and annealing temperature. Amorphous, highly transparent and relatively low resistive films which can be suitable for the usage as transparent electrode of organic light-emitting diode were obtained upon annealing at 300 circC. Partially crystalline, highly transparent and highly resistive films which can be used in piezoelectric applications were obtained upon annealing at 500 circC. For each composition the refractive index has no monotonic variation upon increasing annealing temperature.

Study of structural, electronic and magneto transport properties of La0.7Ca0.2-xSrxAg0.1MnO3

NASA Astrophysics Data System (ADS)

Subhashini, P.; Munirathinum, B.; Krishnaiah, M.; Venkatesh, R.; Venkateswarlu, D.; Ganesan, V.

2016-10-01

Structural, electrical and magneto transport properties of Lanthanum based manganites La0.7Ca0.2-xSrxAg0.1MnO3 (x=0 & 0.1) synthesized by low temperature nitrate route is studied systematically. The X-ray Diffraction patterns confirm the presence of orthorhombic structure with Pnma space group. The temperature dependence of MR (-35%) from 233-272K for x=0 and an MR (-26%) from 281-309K for x=0.1composition with an overall variation of 1% is very much advantageous for device application. Interestingly, in low temperature regime, the MR value of -47% obtained in x=0.1 composition at 10T around 5K is 20% higher than the MR obtained at 10T around the metal insulator transition. Significant changes happening in the low temperature MR measurements is discussed in the light of electron-electron interactions and weak localization mechanisms while the additional broad hump responsible for flat MR is attributed to the intrinsic electronic in homogeneity driven phase competition created due to the presence of mono valent Ag ions. The complex localization mechanism associated with insulating regime is in accordance with Variable range hopping of small polarons.

Ultra Uniform Pb0.865La0.09(Zr0.65Ti0.35)O3 Thin Films with Tunable Optical Properties Fabricated via Pulsed Laser Deposition

PubMed Central

Jiang, Shenglin; Huang, Chi; Gu, Honggang; Liu, Shiyuan; Zhu, Shuai; Li, Ming-Yu; Yao, Lingmin; Wu, Yunyi; Zhang, Guangzu

2018-01-01

Ferroelectric thin films have been utilized in a wide range of electronic and optical applications, in which their morphologies and properties can be inherently tuned by a qualitative control during growth. In this work, we demonstrate the evolution of the Pb0.865La0.09(Zr0.65Ti0.35)O3 (PLZT) thin films on MgO (200) with high uniformity and optimized optical property via the controls of the deposition temperatures and oxygen pressures. The perovskite phase can only be obtained at the deposition temperature above 700 °C and oxygen pressure over 50 Pa due to the improved crystallinity. Meanwhile, the surface morphologies gradually become smooth and compact owing to spontaneously increased nucleation sites with the elevated temperatures, and the crystallization of PLZT thin films also sensitively respond to the oxygen vacancies with the variation of oxygen pressures. Correspondingly, the refractive indices gradually develop with variations of the deposition temperatures and oxygen pressures resulted from the various slight loss, and the extinction coefficient for each sample is similarly near to zero due to the relatively smooth morphology. The resulting PLZT thin films exhibit the ferroelectricity, and the dielectric constant sensitively varies as a function of electric filed, which can be potentially applied in the electronic and optical applications. PMID:29596398

Observations Of Planetary Nebula NGC 3242 Using STIS From HST19 GO 12600

NASA Astrophysics Data System (ADS)

Miller, Timothy R.; Dufour, Reginald J.; Henry, Richard B. C.; Kwitter, Karen B.; Shaw, Richard A.; Balick, Bruce; Corradi, Romano

2014-06-01

During HST Cycle 19, we obtained long-slit spectra using STIS of the planetary nebula NGC 3242 with higher spatial resolution than previously published. The full wavelength range is around 1100-10200Å, covering many nebular lines for determining numerous ionic abundances and electron densities and temperatures. In this work, we first analyze the low- and moderate-resolution UV emission lines of carbon, nitrogen and oxygen. In particular, the resolved lines of C_III] 1907 and C_III] 1909 have yielded a direct measurement of one of the dominant ionic species for carbon and a determination of the density occupied by doubly-ionized carbon and other similar ions. Next, the spatial emission profile of these lines reveals variations in the inferred density along the line of sight from about 2800-11500 cm-3, compared with a value ~3800 cm-3, when averaged over the entire slit. Similarly, the electron temperature is around 12000K for the entire slit and ranges from about 11400-14000K when the slit is divided into smaller sub-regions. Lastly, these sub-regions of the nebula have been modeled in detail with the photoionization code CLOUDY. This modeling will assess the density profile that produces the observed density variation, reproduce the temperature fluctuations, and constrain the central star temperature. We acknowledge the gracious support from HST and the University of Oklahoma.

Verification of Fowler-Nordheim electron tunneling mechanism in Ni/SiO2/n-4H SiC and n+ poly-Si/SiO2/n-4H SiC MOS devices by different models

NASA Astrophysics Data System (ADS)

Kodigala, Subba Ramaiah

2016-11-01

This article emphasizes verification of Fowler-Nordheim electron tunneling mechanism in the Ni/SiO2/n-4H SiC MOS devices by developing three different kinds of models. The standard semiconductor equations are categorically solved to obtain the change in Fermi energy level of semiconductor with effect of temperature and field that extend support to determine sustainable and accurate tunneling current through the oxide layer. The forward and reverse bias currents with variation of electric field are simulated with help of different models developed by us for MOS devices by applying adequate conditions. The latter is quite different from former in terms of tunneling mechanism in the MOS devices. The variation of barrier height with effect of quantum mechanical, temperature, and fields is considered as effective barrier height for the generation of current-field (J-F) curves under forward and reverse biases but quantum mechanical effect is void in the latter. In addition, the J-F curves are also simulated with variation of carrier concentration in the n-type 4H SiC semiconductor of MOS devices and the relation between them is established.

Solar wind thermal electrons in the ecliptic plane between 1 and 4 AU - Preliminary results from the Ulysses radio receiver

NASA Technical Reports Server (NTRS)

Hoang, S.; Meyer-Vernet, N.; Bougeret, J.-L.; Harvey, C. C.; Lacombe, C.; Mangeney, A.; Moncuquet, M.; Perche, C.; Steinberg, J.-L.; Macdowall, R. J.

1992-01-01

The radio receiver of the Unified Radio and Plasma experiment aboard the Ulysses spacecraft records spectra of the quasi-thermal plasma noise. The interpretation of these spectra allows the determination of the total electron density Ne and of the cold (core) electron temperature Tc in the solar wind. A single power law does not fit the variations of Ne which result from the contribution from different solar wind structures. The distribution of the values of Tc suggests that, on the average, the solar wind is nearly isothermal.

Development of reverse biased p-n junction electron emission

NASA Technical Reports Server (NTRS)

Fowler, P.; Muly, E. C.

1971-01-01

A cold cathode emitter of hot electrons for use as a source of electrons in vacuum gauges and mass spectrometers was developed using standard Norton electroluminescent silicon carbide p-n diodes operated under reverse bias conditions. Continued development including variations in the geometry of these emitters was carried out such that emitters with an emission efficiency (emitted current/junction current) as high as 3 x 10-0.00001 were obtained. Pulse measurements of the diode characteristics were made and showed that higher efficiency can be attained under pulse conditions probably due to the resulting lower temperatures resulting from such operation.

Investigation of Third Gyro-harmonic Heating at HAARP Using Stimulated Radio Emissions, the MUIR and SuperDARN Radars

NASA Astrophysics Data System (ADS)

Mahmoudian, Alireza; Bernhardt, Paul; Ruohoniemi, J. Michael; Isham, Brett; Watkins, Brenton; Scales, Wayne

2016-07-01

Use of high frequency (HF) heating experiments has been extended in recent years as a useful methodology for plasma physicists wishing to remotely study the properties and behavior of the ionosphere as well as nonlinear plasma processes. Our recent work using high latitude heating experiments has lead to several important discoveries that have enabled assessment of active geomagnetic conditions, determination of minor ion species and their densities, ion mass spectrometry, electron temperature measurements in the heating ionosphere, as well a deeper understanding of physical processes associated with electron acceleration and formation of field aligned irregularities. The data recorded during two campaigns at HAARP in 2011 and 2012 will be presented. Several diagnostic instruments have been used to detect HAARP heater-generated ionospheric irregularities and plasma waves. These diagnostics include an ionosonde, MUIR (Modular UHF Ionospheric Radar at 446 MHz), SuperDARN HF backscatter radar and ground-based SEE receivers. Variation of the wideband/ narrowband SEE features, SuperDARN echoes, and enhanced ion lines were studied with pump power variation, pump frequency stepping near 3fce as well as changing beam angle relative to the magnetic zenith. In particular, formation of field-aligned irregularities (FAIs) and upper hybrid (UH) waves through oscillating two-stream instability (OSTI) and resonance instability is studied. During heating, Narrowband SEE (NSEE) showed enhancements that correlated with the enhanced MUIR radar ion lines. IA MSBS (Magnetized Stimulated Brillouin Scatter) lines are much narrower than Wideband SEE (WSEE) lines and as a result electron temperature calculated using NSEE line offset has potential to be more accurate. This technique may therefore complement the electron temperature calculation using ISR spectra. Strength of IA MSBS lines correlate with EHIL in the MUIR spectrum during HF pump frequency variation near 3fce. Therefore, NSEE could be used for similar diagnostic information, particularly temperature assessment during heating. More detailed physics-based modeling of such SEE is expected to provide further diagnostic information/capabilities. This work has demonstrated the tremendous future potential of Narrowband SEE (NSEE) as a powerful untapped ionospheric diagnostic which could provide complementary measurements for locations that ISR facilities are not available or as a complementary measurement for the waves and irregularities that cannot be observed by ISR.

Temperature dependence of nonlinear optical properties in Li doped nano-carbon bowl material

NASA Astrophysics Data System (ADS)

Li, Wei-qi; Zhou, Xin; Chang, Ying; Quan Tian, Wei; Sun, Xiu-Dong

2013-04-01

The mechanism for change of nonlinear optical (NLO) properties with temperature is proposed for a nonlinear optical material, Li doped curved nano-carbon bowl. Four stable conformations of Li doped corannulene were located and their electronic properties were investigated in detail. The NLO response of those Li doped conformations varies with relative position of doping agent on the curved carbon surface of corannulene. Conversion among those Li doped conformations, which could be controlled by temperature, changes the NLO response of bulk material. Thus, conformation change of alkali metal doped carbon nano-material with temperature rationalizes the variation of NLO properties of those materials.

Thermal annealing and temperature dependences of memory effect in organic memory transistor

NASA Astrophysics Data System (ADS)

Ren, X. C.; Wang, S. M.; Leung, C. W.; Yan, F.; Chan, P. K. L.

2011-07-01

We investigate the annealing and thermal effects of organic non-volatile memory with floating silver nanoparticles by real-time transfer curve measurements. During annealing, the memory window shows shrinkage of 23% due to structural variation of the nanoparticles. However, by increasing the device operating temperature from 20 to 90 °C after annealing, the memory window demonstrates an enlargement up to 100%. The differences in the thermal responses are explained and confirmed by the co-existence of electron and hole traps. Our findings provide a better understanding of organic memory performances under various operating temperatures and validate their applications for temperature sensing or thermal memories.

Reversible control of doping in graphene-on-SiO2 by cooling under gate-voltage

NASA Astrophysics Data System (ADS)

Singh, Anil Kumar; Gupta, Anjan Kumar

2017-11-01

The electronic properties of graphene can be modulated by various doping techniques other than back-gate, but most such methods are not easily reversible and also lead to mobility reduction. Here, we report on the reversible control of doping in graphene by cooling under back-gate-voltage. The observed variation in hysteresis in our devices with the temperature and interface preparation method is attributed to the variation in the density of redox species, namely, H2O and O2, at the graphene/SiO2 interface, and their diffusion. With careful interface preparation, we have been able to make devices with negligible hysteresis at room temperature and by exploiting hysteresis at high temperatures, we get a wide, but reversible tunability of interface charge density and graphene doping, by cooling to room temperature under gate-voltage. Such reversible control of graphene doping by manipulating the interface defect charge density can help in making new data storage devices using graphene.

Microwave absorption studies on high-T sub c superconductors and related materials II; Electron spin resonance of DPPH coated on Y sub 1 Ba sub 2 Cu sub 3 O sub y as a probe of magnetic field variations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sugawara, K.; Baar, D.J.; Shiohara, Y.

1991-05-10

This paper reports on the ESR linewidth ({Delta}{ital H}{sub p{bar p}}) of DPPH coated on the surface of powder specimens of Y{sub 1}Ba{sub 2}Cu{sub 3}O{sub y} studied under various magnetic field and temperature conditions. {Delta}{ital H}{sub p{bar p}} increases substantially with decreasing temperature in the field cooled case, whereas almost no linewidth broadening was found in the zero field cooled case. {Delta}{ital H}{sub p{bar p}} was found to be sensitive to the applied magnetic field. This effect was very pronounced at temperatures lower than 40 K, but decreased strongly with increasing temperature. The broadening of the resonance lineshape has beenmore » attributed to spatial and temporal variations of the fluxon distribution in the powder particles.« less

Ro-vibrational averaging of the isotropic hyperfine coupling constant for the methyl radical

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adam, Ahmad Y.; Jensen, Per, E-mail: jensen@uni-wuppertal.de; Yachmenev, Andrey

2015-12-28

We present the first variational calculation of the isotropic hyperfine coupling constant of the carbon-13 atom in the CH{sub 3} radical for temperatures T = 0, 96, and 300 K. It is based on a newly calculated high level ab initio potential energy surface and hyperfine coupling constant surface of CH{sub 3} in the ground electronic state. The ro-vibrational energy levels, expectation values for the coupling constant, and its temperature dependence were calculated variationally by using the methods implemented in the computer program TROVE. Vibrational energies and vibrational and temperature effects for coupling constant are found to be in verymore » good agreement with the available experimental data. We found, in agreement with previous studies, that the vibrational effects constitute about 44% of the constant’s equilibrium value, originating mainly from the large amplitude out-of-plane bending motion and that the temperature effects play a minor role.« less

Absorption of a laser light pulse in a dense plasma.

NASA Technical Reports Server (NTRS)

Mehlman-Balloffet, G.

1973-01-01

An experimental study of the absorption of a laser light pulse in a transient, high-density, high-temperature plasma is presented. The plasma is generated around a metallic anode tip by a fast capacitive discharge occurring in vacuum. The amount of transmitted light is measured for plasmas made of different metallic ions in the regions of the discharge of high electronic density. Variation of the transmission during the laser pulse is also recorded. Plasma electrons are considered responsible for the very high absorption observed.

Effect of Variation of Silicon Nitride Passivation Layer on Electron Irradiated Aluminum Gallium Nitride/Gallium Nitride HEMT Structures

DTIC Science & Technology

2014-06-19

the AlGaN is unintentionally doped . Figure 2.3. AlGaN/GaN band diagram showing polarization charges. The band diagram in Figure 2.3 shows...intentionally doped as are MESFETS, and the channel gets its electrons from the unintentional doping . There is less Coulomb scattering in the...temperature measurements are often used to provide spatial PL maps of doping and trap densities. Laser excitation (quasi-monochromatic) is

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Y.; Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240; Li, W., E-mail: weilee@sjtu.edu.cn

Low temperature tempering is important in improving the mechanical properties of steels. In this study, the thermoelectric power method was employed to investigate carbon segregation during low temperature tempering ranging from 110 °C to 170 °C of a medium carbon alloyed steel, combined with micro-hardness, transmission electron microscopy and atom probe tomography. Evolution of carbon dissolution from martensite and segregation to grain boundaries/interfaces and dislocations were investigated for different tempering conditions. Carbon concentration variation was quantified from 0.33 wt.% in quenching sample to 0.15 wt.% after long time tempering. The kinetic of carbon diffusion during tempering process was discussed throughmore » Johnson-Mehl-Avrami equation. - Highlights: • The thermoelectric power (TEP) was employed to investigate the low temperature tempering of a medium carbon alloyed steel. • Evolution of carbon dissolution was investigated for different tempering conditions. • Carbon concentration variation was quantified from 0.33 wt.% in quenching sample to 0.15 wt.% after long time tempering.« less

Thermal Structure and Energy Influx to the Day-and Nightside Venus Ionosphere.

PubMed

Knudsen, W C; Spenner, K; Whitten, R C; Spreiter, J R; Miller, K L; Novak, V

1979-07-06

Pioneer Venus in situ measurements made with the retarding potential analyzer reveal strong variations in the nightside ionospheric plasma density from location to location in some orbits and from orbit to orbit. The ionopause is evident at night as a relatively abrupt decrease in the thermal plasma concentration from a few hundred to ten or fewer ions per cubic centimeter. The nightside ion and electron temperatures above an altitude of 250 kilometers, within the ionosphere and away from the terminator, are comparable in magnitude and have a value at the ionopause of approximately 8000 K. The electron temperature increases from a few tens of thousands of degrees Kelvin just outside the ionopause to several hundreds of thoussands of degrees Kelvin further into the shocked solar wind. The coldest ion temperatures measured at an altitude of about 145 kilometers are 140 to 150 K and are still evidently above the neutral temperature. Preliminary day-and nightside model ion and electron temperature height profiles are compared with measured profiles. To raise the model ion temperature to the measured ion temperature on both day-and nightsides, it was necessary to include an ion energy source of the order of 4 x 10(-3) erg per square centimeter per second, presumably Joule heating. The heat flux through the electron gas from the solar wind into the neutral atmosphere averaged over day and night may be as large as 0.05 erg per square centimeter per second. Integrated over the planet surface, this heat flux represents one-tenth of the solar wind energy expended in drag on the sunward ionopause hemisphere.

Peculiar Features of Microstructure Formation and Microhardness Variations During Torsional Straining of Tantalum Specimens in Bridgman Anvils

NASA Astrophysics Data System (ADS)

Ditenberg, I. A.; Tymentsev, A. N.; Korznikov, A. V.

2015-04-01

Using the method of transmission electron microscopy, peculiar features of evolution of microstructure and variations in microhardness of Та are investigated under torsional loading in the Bridgman anvil as a function of plastic deformation at room temperature. A quantitative examination of grain and defect's structure of the material under study and the values of local internal stresses is performed in different loading stages. The mechanisms of formation of submicrocrystalline and nanostructured states are analyzed and so is the microstructure variation as a function of the defect-structure characteristics, strain level, and spacing from the axis of torsion.

Hydrogen absorption and its effect on magnetic properties of Nd2Fe14B

NASA Astrophysics Data System (ADS)

Bezdushnyi, R.; Damianova, R.; Tereshina, I. S.; Pankratov, N. Yu.; Nikitin, S. A.

2018-05-01

Magnetic properties of hydrides of the intermetallic compound Nd2Fe14BHx are investigated in the temperature range covering the Curie temperatures (TC) of the compounds (up to 670 K). The temperature dependencies of magnetization are measured under continuous control of hydrogen content in the investigated samples. The dependencies of Curie and spin-reorientation transition (TSR) temperatures on the hydrogen concentration are studied in detail. The dependence of hydrogen concentration on pressure at a constant temperature (near TC) and on the temperature at various pressures are obtained. We attempted to estimate the contributions of the unit cell volume increase upon hydrogenation and the electronic structure change in the variation of TC of the hydrogenated Nd2Fe14 B .

Spatial nonuniformity of electron energy in a microwave atmospheric-pressure microplasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu Liguo; Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang, Sichuan 621900; Zhang Zhibo

The characteristics of the electron energy in a microwave atmospheric-pressure argon microplasma are investigated by a spatially resolved optical emission spectroscopy. By adding tiny amount of xenon (<1 ppm) as tracer gas into the argon discharge, it is found that the spatial distribution of the electrons with energy >8.3 eV is quite different from that of the electrons with energy >11.5 eV. Spatial distribution of the population ratio between 4p and 5p levels of Ar atom is also determined. Furthermore, with a collisional-radiative model, it is found that the spatial variation of this population ratio is mainly attributed to themore » spatial nonuniformity of the effective electron temperature.« less

Electronic structure and Landé g-factor of a quantum ring in the presence of spin-orbit coupling: Temperature and Zeeman effect

NASA Astrophysics Data System (ADS)

Zamani, A.; Setareh, F.; Azargoshasb, T.; Niknam, E.

2017-10-01

A wide variety of semiconductor nanostructures have been fabricated experimentally and both theoretical and experimental investigations of their features imply the great role they have in new generation technological devices. However, mathematical modeling provide a powerful means due to definitive goal of predicting the features and understanding of such structures behavior under different circumstances. Therefore, effective Hamiltonian for an electron in a quantum ring with axial symmetry in the presence of both Rashba and Dresselhaus spin-orbit interactions (SOI) is derived. Here we report our study of the electronic structure and electron g-factor in the presence of spin-orbit (SO) couplings under the influence of external magnetic field at finite temperature. This investigation shows that, when Rashba and Dresselhaus couplings are simultaneously present, the degeneracy is removed and energy levels split into two branches. Furthermore, with enhancing the applied magnetic field, separation of former degenerate levels increases and also avoided crossings (anti-crossing) in the energy spectra is detected. It is also discussed how the energy levels of the system can be adjusted with variation of temperature as well as the magnetic field and geometrical sizes.

TOPLA: A New Empirical Representation of the F-Region Topside and Plasmasphere for the International Reference Ionosphere

NASA Technical Reports Server (NTRS)

Bilitza, D.; Reinisch, B.; Gallagher, D.; Huang, X.; Truhlik, V.; Nsumei, P.

2007-01-01

The goal of this LWS tools effort is the development of a new data-based F-region TOpside and PLAsmasphere (TOPLA) model for the electron density (Ne) and temperature (Te) for inclusion in the International Reference Ionosphere (IRI) model using newly available satellite data and models for these regions. The IRI model is the de facto international standard for specification of ionospheric parameters and is currently being considered as an ISO Technical Specification for the ionosphere. Our effort is directed towards improving the topside part of the model and extending it into the plasmasphere. Specifically we are planning to overcome the following shortcomings of the current IRI topside model: (I) overestimation of densities above 700 km by a factor of 2 and more, (3) unrealistically steep density profiles at high latitudes during very high solar activities, (4) no solar cycle variations and no semi-annual variations for the electron temperature, (5) discontinuities or unphysical gradients when merging with plasmaspheric models. We will report on first accomplishments and on the current status of the project.

Phase fluctuations in a strongly disordered s-wave NbN superconductor close to the metal-insulator transition.

PubMed

Mondal, Mintu; Kamlapure, Anand; Chand, Madhavi; Saraswat, Garima; Kumar, Sanjeev; Jesudasan, John; Benfatto, L; Tripathi, Vikram; Raychaudhuri, Pratap

2011-01-28

We explore the role of phase fluctuations in a three-dimensional s-wave superconductor, NbN, as we approach the critical disorder for destruction of the superconducting state. Close to critical disorder, we observe a finite gap in the electronic spectrum which persists at temperatures well above T(c). The superfluid density is strongly suppressed at low temperatures and evolves towards a linear-T variation at higher temperatures. These observations provide strong evidence that phase fluctuations play a central role in the formation of a pseudogap state in a disordered s-wave superconductor.

Correlation of Coronal Plasma Properties and Solar Magnetic Field in a Decaying Active Region

NASA Technical Reports Server (NTRS)

Ko, Yuan-Kuen; Young, Peter R.; Muglach, Karin; Warren, Harry P.; Ugarte-Urra, Ignacio

2016-01-01

We present the analysis of a decaying active region observed by the EUV Imaging Spectrometer on Hinode during 2009 December 7-11. We investigated the temporal evolution of its structure exhibited by plasma at temperatures from 300,000 to 2.8 million degrees, and derived the electron density, differential emission measure, effective electron temperature, and elemental abundance ratios of Si/S and Fe/S (as a measure of the First Ionization Potential (FIP) Effect). We compared these coronal properties to the temporal evolution of the photospheric magnetic field strength obtained from the Solar and Heliospheric Observatory Michelson Doppler Imager magnetograms. We find that, while these coronal properties all decreased with time during this decay phase, the largest change was at plasma above 1.5 million degrees. The photospheric magnetic field strength also decreased with time but mainly for field strengths lower than about 70 Gauss. The effective electron temperature and the FIP bias seem to reach a basal state (at 1.5 x 10(exp 6) K and 1.5, respectively) into the quiet Sun when the mean photospheric magnetic field (excluding all areas <10 G) weakened to below 35 G, while the electron density continued to decrease with the weakening field. These physical properties are all positively correlated with each other and the correlation is the strongest in the high-temperature plasma. Such correlation properties should be considered in the quest for our understanding of how the corona is heated. The variations in the elemental abundance should especially be considered together with the electron temperature and density.

NBS (National Bureau of Standards): Materials measurements

NASA Technical Reports Server (NTRS)

Manning, J. R.

1985-01-01

NBS work for NASA in support of NASA's Microgravity Science and Applications Program under NASA Government Order H-27954B (Properties of Electronic Materials) covering the period April 1, 1984 to March 31, 1985 is described. The work has been carried out in three independent tasks: Task 1--Surface Tensions and Their Variations with Temperature and Impurities; Task 2--Convention during Unidirectional Solidification; Task 3--Measurement of High Temperature Thermodynamic Properties. The results for each task are given separately in the body of the report.

Kinetic model for the collisionless sheath of a collisional plasma

DOE PAGES

Tang, Xian-Zhu; Guo, Zehua

2016-08-04

Collisional plasmas typically have mean-free-path still much greater than the Debye length, so the sheath is mostly collisionless. Once the plasma density, temperature, and flow are specified at the sheath entrance, the profile variation of electron and ion density, temperature, flow speed, and conductive heat fluxes inside the sheath is set by collisionless dynamics, and can be predicted by an analytical kinetic model distribution. Finally, these predictions are contrasted in this paper with direct kinetic simulations, showing good agreement.

Effect of plastic deformation on the magnetic properties and dislocation luminescence of isotopically enriched silicon {sup 29}Si:B

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koplak, O. V.; Shteynman, E. A.; Tereschenko, A. N.

2015-09-15

A correlation between the temperature dependences of the D1-line intensity of dislocation luminescence and the magnetic moment of plastically deformed isotopically enriched crystals {sup 29}Si:B is found. It is established that the magnetic susceptibility of the deformed crystals obtained by integration of the spectra of electron spin resonance and the D1-line intensity undergo similar nonmonotonic variations with temperature varying in the range of 20–32 K.

Temperature dependence of 2DEG and excitonic optical transitions in AlGaN/GaN heterostructures on SiC

NASA Astrophysics Data System (ADS)

Litton, C. W.; Reynolds, D. C.; Hoelscher, J. E.; Collins, T. C.; Fitch, R.; Via, G. D.; Gillespie, J.; Crespo, A.; Jenkins, T. J.; Worley, R.; Saxler, A.

2005-05-01

Four (4) unique optical transitions are reported in both the emission and reflection spectra of high-quality AlGaN/GaN heterostructures. Study of the shifts of spectral peak energies and their intensity variations with temperature, reveal that these transitions arise from Free Exciton recombination and transitions between the A- and B-valence bands and the excited states of the 2-dimensional electron gas (2DEG) at the heterointerface.

Ultrasonic determination of recrystallization

NASA Technical Reports Server (NTRS)

Generazio, E. R.

1986-01-01

Ultrasonic attenuation was measured for cold worked Nickel 200 samples annealed at increasing temperatures. Localized dislocation density variations, crystalline order and colume percent of recrystallized phase were determined over the anneal temperature range using transmission electron microscopy, X-ray diffraction, and metallurgy. The exponent of the frequency dependence of the attenuation was found to be a key variable relating ultrasonic attenuation to the thermal kinetics of the recrystallization process. Identification of this key variable allows for the ultrasonic determination of onset, degree, and completion of recrystallization.

Dispersion characteristics of anisotropic unmagnetized ultra-relativistic transverse plasma wave with arbitrary electron degeneracy

NASA Astrophysics Data System (ADS)

Sarfraz, M.; Farooq, H.; Abbas, G.; Noureen, S.; Iqbal, Z.; Rasheed, A.

2018-03-01

Thermal momentum space anisotropy is ubiquitous in many astrophysical and laboratory plasma environments. Using Vlasov-Maxwell's model equations, a generalized polarization tensor for a collisionless ultra-relativistic unmagnetized electron plasma is derived. In particular, the tensor is obtained by considering anisotropy in the momentum space. The integral of moments of Fermi-Dirac distribution function in terms of Polylog functions is used for describing the border line plasma systems (T/e TF e ≈1 ) comprising arbitrary electron degeneracy, where Te and TF e, are thermal and Fermi temperatures, respectively. Furthermore, the effects of variation in thermal momentum space anisotropy on the electron equilibrium number density and the spectrum of electromagnetic waves are analyzed.

Nature and evolution of incommensurate charge order in manganites visualized with cryogenic scanning transmission electron microscopy

PubMed Central

Savitzky, Benjamin H.; Admasu, Alemayehu S.; Kim, Jaewook; Cheong, Sang-Wook; Hovden, Robert; Kourkoutis, Lena F.

2018-01-01

Incommensurate charge order in hole-doped oxides is intertwined with exotic phenomena such as colossal magnetoresistance, high-temperature superconductivity, and electronic nematicity. Here, we map, at atomic resolution, the nature of incommensurate charge–lattice order in a manganite using scanning transmission electron microscopy at room temperature and cryogenic temperature (∼93 K). In diffraction, the ordering wave vector changes upon cooling, a behavior typically associated with incommensurate order. However, using real space measurements, we discover that the ordered state forms lattice-locked regions over a few wavelengths interspersed with phase defects and changing periodicity. The cations undergo picometer-scale (∼6 pm to 11 pm) transverse displacements, suggesting that charge–lattice coupling is strong. We further unearth phase inhomogeneity in the periodic lattice displacements at room temperature, and emergent phase coherence at 93 K. Such local phase variations govern the long-range correlations of the charge-ordered state and locally change the periodicity of the modulations, resulting in wave vector shifts in reciprocal space. These atomically resolved observations underscore the importance of lattice coupling and phase inhomogeneity, and provide a microscopic explanation for putative “incommensurate” order in hole-doped oxides. PMID:29382750

Structural, transport and magnetotransport properties of Ru-doped La0.5Sr0.5Mn1-xRuxO3 (x = 0.0 & 0.05) manganite

NASA Astrophysics Data System (ADS)

Jethva, Sadaf; Katba, Savan; Udeshi, Malay; Kuberkar, D. G.

2017-09-01

We report the results of the structural, transport and magnetotransport studies on polycrystalline La0.5Sr0.5Mn1-xRuxO3 (x = 0.0 and 0.05) manganite investigated using XRD and resistivity (with and without field) measurements. Rietveld refinement of XRD patterns confirms the single phasic tetragonal structure for both the samples crystalizing in I4/mcm space group (No. 140). Low-temperature resistivity and MR measurements with H = 0 T & 5 T field show thermal hysteresis which has been attributed to the first order phase transition. The increase in resistivity and decrease in metal - insulator transition temperature (TMI) with Ru - doping concentration in La0.5Sr0.5MnO3 (LSMO) has been understood in the context of superexchange interaction between Mn and Ru ions. The observed upturn in resistivity at low temperature under field has been explained using combined effect of electron - electron (e - e) interaction, Kondo-like spin-dependent scattering and electron - phonon interaction while the variation in resistivity at high temperature (T > Tp) has been explained using adiabatic small polaron hopping model.

Anomalous width variations for ion acoustic rarefactive solitary waves in a warm ion plasma with two electron temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghosh, S.S.; Sekar Iyengar, A.N.

1997-09-01

Anomalous width{endash}amplitude variations were observed in large amplitude rarefactive solitary waves which show increasing width with increasing amplitude, contrasting the usual reciprocal relation between the square of the width and the amplitude, beyond a certain value of the plasma parameters [S. S. Ghosh, K. K. Ghosh, and A. N. Sekar Iyengar, Phys. Plasmas, {bold 3}, 3939 (1996)]. For the limiting maximum amplitude, the {open_quotes}increasing width{close_quotes} solitary wave tends to a double layer-like solution. The overall variation was found to depend crucially on the specific parameter space. From a detailed investigation of the above behavior, a plausible physical explanation has beenmore » presented for such increases in the width. It is found that the ions{close_quote} initial kinetic energies and the cold electron concentration within the perturbed region play a significant role in determining the observed width{endash}amplitude variation. This contradicts the investigation of Sayal, Yadav, and Sharma [Phys. Scr. {bold 47}, 576 (1993)]. {copyright} {ital 1997 American Institute of Physics.}« less

Role of the heat accumulation effect in the multipulse modes of the femtosecond laser microstructuring of silicon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guk, I. V., E-mail: corchand@gmail.com; Shandybina, G. D.; Yakovlev, E. B.

2016-05-15

The results of quantitative evaluation of the heat accumulation effect during the femtosecond laser microstructuring of the surface of silicon are presented for discussion. In the calculations, the numerical–analytical method is used, in which the dynamics of electronic processes and lattice heating are simulated by the numerical method, and the cooling stage is described on the basis of an analytical solution. The effect of multipulse irradiation on the surface temperature is studied: in the electronic subsystem, as the dependence of the absorbance on the excited carrier density and the dependence of the absorbance on the electron-gas temperature; in the latticemore » subsystem, as the variation in the absorbance from pulse to pulse. It was shown that, in the low-frequency pulse-repetition mode characteristic of the femtosecond microstructuring of silicon, the heat accumulation effect is controlled not by the residual surface temperature by the time of the next pulse arrival, which corresponds to conventional concepts, but by an increase in the maximum temperature from pulse to pulse, from which cooling begins. The accumulation of the residual temperature of the surface can affect the microstructuring process during irradiation near the evaporation threshold or with increasing pulse-repetition rate.« less

Survey of the plasma electron environment of Jupiter: A view from Voyager

NASA Technical Reports Server (NTRS)

Scudder, J. D.; Sittler, E. C., Jr.; Bridge, H. S.

1980-01-01

The plasma environment within Jupiter's bow shock is considered in terms of the in situ, calibrated electron plasma measurements made between 10 eV and 5.95 keV by the Voyager plasma science experiment (PLS). Measurements were analyzed and corrected for spacecraft potential variations; the data were reduced to nearly model independent macroscopic parameters of the local electron density and temperature. It is tentatively concluded that the radial temperature profile within the plasma sheet is caused by the intermixing of two different electron populations that probably have different temporal histories and spatial paths to their local observation. The cool plasma source of the plasma sheet and spikes is probably the Io plasma torus and arrives in the plasma sheet as a result of flux tube interchange motions or other generalized transport which can be accomplished without diverting the plasma from the centrifugal equator. The hot suprathermal populations in the plasma sheet have most recently come from the sparse, hot mid-latitude "bath" of electrons which were directly observed juxtaposed to the plasma sheet.

Methane chemistry involved in a low-pressure electron cyclotron wave resonant plasma discharge

NASA Astrophysics Data System (ADS)

Morrison, N. A.; William, C.; Milne, W. I.

2003-12-01

Radio frequency (rf) generated methane plasmas are commonly employed in the deposition of hydrogenated amorphous carbon (a-C:H) thin films. However, very little is known about the rf discharge chemistry and how it relates to the deposition process. Consequently, we have characterized a low-pressure methane plasma and compared the results with those obtained theoretically by considering the steady-state kinetics of the chemical processes present in a low-pressure plasma reactor, in order to elucidate the dominant reaction channels responsible for the generation of the active precursors required for film growth. Mass spectrometry measurements of the gas phase indicated little variation in the plasma chemistry with increasing electron temperature. This was later attributed to the partial saturation of the electron-impact dissociation and ionization rate constants at electron temperatures in excess of ˜4 eV. The ion densities in the plasma were also found to be strongly dependent upon the parent neutral concentration in the gas phase, indicating that direct electron-impact reactions exerted greater influence on the plasma chemistry than secondary ion-neutral reactions.

A variational theory of Hall effect of Anderson lattice model: Application to colossal magnetoresistance manganites (Re1-x Ax MnO3)

NASA Astrophysics Data System (ADS)

Panwar, Sunil; Kumar, Vijay; Singh, Ishwar

2017-10-01

An anomalous Hall constant RH has been observed in various rare earth manganites doped with alkaline earths namely Re1-xAxMnO3 (where Re = La, Pr, Nd etc., and A = Ca, Sr, Ba etc.) which exhibit colossal magnetoresistance (CMR), metal- insulator transition and many other poorly understood phenomena. We show that this phenomenon of anomalous Hall constant can be understood using two band (ℓ-b) Anderson lattice model Hamiltonian alongwith (ℓ-b) hybridization recently studied by us for manganites in the strong electron-lattice Jahn-Teller (JT) coupling regime an approach similar to the two - fluid models. We use a variational method in this work to study the temperature variation of Hall constant RH (T) in these compounds. We have already used this variational method to study the zero field electrical resistivity ρ (T) and magnetic susceptibility of doped CMR manganites. In the present study, we find that the Hall constant RH (T) reduces with increasing magnetic field parameters h&m and the metal-insulator transition temperature (Tρ) shifts towards higher temperature region. We have also observed the role of the model parameters e.g. local Coulomb repulsion U, Hund's rule coupling JH between eg spins and t2g spins, ferromagnetic nearest neighbor exchange coupling JF between t2g core spins and hybridization Vk between ℓ-polarons and d-electrons on Hall constant RH (T) of these materials at different magnetic fields. Here we find that RH (T) for a particular value of h and m shows a rapid initial increase, followed by a sharp peak at low temperature say 50 K in our case and a slow decrease at high temperatures, resembling with the key feature of many CMR compounds like La0.8Ba0.2 MnO3.The magnitude of RH (T) reduces and the anomaly (sharp peak) in RH becomes broader and shifts towards higher temperature region on increasing Vk or JH or doping x and even vanishes on further increasing these parameters. Our results of anomalous Hall constant (RH) have same qualitative behavior as the zero-field electrical resistivity. Moreover Hall Constant (RH) shows positive values indicating that the carriers in these manganites are holes.

Simultaneous mesosphere-thermosphere-ionosphere parameter measurements over Gadanki (13.5°N, 79.2°E): First results

NASA Astrophysics Data System (ADS)

Taori, A.; Dashora, N.; Raghunath, K.; Russell, J. M., III; Mlynczak, Martin G.

2011-07-01

We report first simultaneous airglow, lidar, and total electron content measurements in the mesosphere-thermosphere-ionosphere system behavior from Gadanki (13.5°N, 79.2°E). The observed variability in mesospheric temperatures and 630 nm thermospheric emission intensity shows large variations from one night to another with clear upward propagating waves at mesospheric altitudes. The deduced mesospheric temperatures compare well with Sounding of the Atmosphere Using Broadband Emission Radiometry (SABER)-derived temperatures, while the variability agrees well with lidar temperatures (on the night of simultaneous observations). The 630.0 nm thermospheric emission intensity and GPS-total electron content data exhibit occurrence of plasma depletions on the nights of 22-23 October and 22-23 May 2009, while no depletions are noted on the nearby nights of 23-24 October and 21-22 May 2009. These first simultaneous data reveal strong gravity-wave growth at upper mesospheric altitudes on the nights when plasma depletions were noted.

Robustness in spin polarization and thermoelectricity in newly tailored Mn2-based Heusler alloys

NASA Astrophysics Data System (ADS)

Yousuf, S.; Gupta, D. C.

2018-02-01

Investigation of electronic structure, magnetism, hybridization and thermoelectricity of Mn2-based Heusler alloys within the framework of DFT simulation technique have been carried out. Through the optimized ground state parameters viz., lattice constant, total energy and bulk's modulus, electronic properties, magnetic properties and thermoelectric response of new tailored materials is reported. Mechanically stable with ductile nature and 100% spin polarization could favor their use in future spintronic materials. Thermoelectric properties are investigated through the variation of carrier concentration and temperature. Power factor analysis show a way for the selection of the optimal carrier concentration responsible for increasing their thermoelectric response with temperature. The power factor of 857.51 (966.16) × 109µW K-2 m-1 s-1 at an optimal concentration of 1018 cm-3 and temperature of 800 K for Mn2YSn (Mn2ZnSn) respectively is obtained. The Seebeck coefficient portray them as p-type materials and show a linear increase with temperature and vice versa for the carrier concentrations.

Robustness in spin polarization and thermoelectricity in newly tailored Mn2-based Heusler alloys

NASA Astrophysics Data System (ADS)

Yousuf, S.; Gupta, D. C.

2018-07-01

Investigation of electronic structure, magnetism, hybridization and thermoelectricity of Mn2-based Heusler alloys within the framework of DFT simulation technique have been carried out. Through the optimized ground state parameters viz., lattice constant, total energy and bulk's modulus, electronic properties, magnetic properties and thermoelectric response of new tailored materials is reported. Mechanically stable with ductile nature and 100% spin polarization could favor their use in future spintronic materials. Thermoelectric properties are investigated through the variation of carrier concentration and temperature. Power factor analysis show a way for the selection of the optimal carrier concentration responsible for increasing their thermoelectric response with temperature. The power factor of 857.51 (966.16) × 109µW K-2 m-1 s-1 at an optimal concentration of 1018 cm-3 and temperature of 800 K for Mn2YSn (Mn2ZnSn) respectively is obtained. The Seebeck coefficient portray them as p-type materials and show a linear increase with temperature and vice versa for the carrier concentrations.

Reversal of spontaneous magnetization and spontaneous exchange bias for Sm1-xYxCrO3: The effect of Y doping

NASA Astrophysics Data System (ADS)

Zhang, Hongguang; Wang, Jianhua; Xie, Liang; Fu, Dexiang; Guo, Yanyan; Li, Yongtao

2017-11-01

We report the crystal and electronic structures and magnetic properties of non-magnetic Y3+ ion doped SmCrO3 crystals. Structural distortion and electronic structure variation are caused by cation disorder due to Y doping. Although the spin moment of Sm3+ is diluted by nonmagnetic Y ions, spin reorientation continues to exist, and the temperature-dependent magnetization reversal effect and the spontaneous exchange bias effect under zero field cooling are simultaneously induced below Neel temperature. Significantly, the method of doping promotes the achievement of temperature dependent tunable switching of magnetization and sign of a spontaneous exchange bias from positive to negative. Our work provides more tunable ways to the sign reversal of magnetization and exchange bias, which have potential application in designing magnetic random access memory devices, thermomagnetic switches and spin-valve devices.

X-ray Emission Line Anisotropy Effects on the Isoelectronic Temperature Measurement Method

NASA Astrophysics Data System (ADS)

Liedahl, Duane; Barrios, Maria; Brown, Greg; Foord, Mark; Gray, William; Hansen, Stephanie; Heeter, Robert; Jarrott, Leonard; Mauche, Christopher; Moody, John; Schneider, Marilyn; Widmann, Klaus

2016-10-01

Measurements of the ratio of analogous emission lines from isoelectronic ions of two elements form the basis of the isoelectronic method of inferring electron temperatures in laser-produced plasmas, with the expectation that atomic modeling errors cancel to first order. Helium-like ions are a common choice in many experiments. Obtaining sufficiently bright signals often requires sample sizes with non-trivial line optical depths. For lines with small destruction probabilities per scatter, such as the 1s2p-1s2 He-like resonance line, repeated scattering can cause a marked angular dependence in the escaping radiation. Isoelectronic lines from near-Z equimolar dopants have similar optical depths and similar angular variations, which leads to a near angular-invariance for their line ratios. Using Monte Carlo simulations, we show that possible ambiguities associated with anisotropy in deriving electron temperatures from X-ray line ratios are minimized by exploiting this isoelectronic invariance.

Measured Electron Spin Relaxation Rates in Frozen Solutions of Azurin, VITAMIN-B12R, and Nitrosyl Ferrous Myoglobin.

NASA Astrophysics Data System (ADS)

Muench, Philip James

Rates in frozen glycerin/water solutions at temperatures between 1.4 K and 20 K are reported for a copper-containing protein, azurin, and a cobalt-containing biomolecular complex, vitamin B_{rm 12r}, the paramagnetic product of the photolysis of coenzyme B_{12}. Results are interpreted in terms of a spectral dimensionality. Rates are also reported for nitrosyl ferrous myoglobin in frozen water solution, which exhibits a dominant one-phonon relaxation process up to 20 K and thus does not reveal spectral dimensionality. The anomalous variation of rate with temperature observed in several iron-containing proteins is not conspicuous here. In a model two-phonon mechanism of relaxation, temperature dependence is fixed by a spectral dimensionality, m, which specifies the variation of vibrational density of states with frequency rho(nu ) ~ nu ^{rm m-1} and is named in analogy with the Debye density of states in 1-, 2-, and 3-dimensional crystals. At sufficiently high temperatures, a non-resonant two-phonon process (Raman) should dominate the relaxation of a paramagnetic ion unless low-lying (under ^{~}70 cm^ {-1}) electronic states are present, as in many rare earths and in high spin ferric complexes, including many ferric proteins. The temperature dependence of the Raman rate for a Kramers ion (odd number of electrons) is T^{rm 3+2m} if temperature is sufficiently lower than Theta = hnu_{rm max} /k, the Debye temperature. The values of m from relaxation data on frozen solutions of a protein have sometimes been dependent upon solvent conditions. The maximum values of m for heme proteins, iron-sulfur proteins, and one copper -and-iron-containing protein, have ranged from about 1.3 to 1.8. Pulse saturation/recovery was used. The recoveries were not exponential, but rates were estimated from semilogarithmic displays of signals or from numerical fitting. The temperature dependence of the rates for azurin between 1.5 K and 22 K can be fit with a spectral dimensionality of 3 and a rather low Debye temperature near 69 K, in contrast to iron proteins. Relaxation of vitamin B_{ rm 12r} differed between samples, indicating varied photolysis or freezing. The Raman relaxation was well fit by a simple power law in temperature, but the values of m varied from 1.14 to 1.48 between samples.

Exploding Pusher Targets for Electron-Ion Coupling Measurements

NASA Astrophysics Data System (ADS)

Whitley, Heather D.; Pino, Jesse; Schneider, Marilyn; Shepherd, Ronnie; Benedict, Lorin; Bauer, Joseph; Graziani, Frank; Garbett, Warren

2015-11-01

Over the past several years, we have conducted theoretical investigations of electron-ion coupling and electronic transport in plasmas. In the regime of weakly coupled plasmas, we have identified models that we believe describe the physics well, but experimental data is still needed to validate the models. We are currently designing spectroscopic experiments to study electron-ion equilibration and/or electron heat transport using exploding pusher (XP) targets for experiments at the National Ignition Facility. Two platforms are being investigated: an indirect drive XP (IDXP) with a plastic ablator and a polar-direct drive XP (PDXP) with a glass ablator. The fill gas for both designs is D2. We propose to use a higher-Z dopant, such as Ar, as a spectroscopic tracer for time-resolved electron and ion temperature measurements. We perform 1D simulations using the ARES hydrodynamic code, in order to produce the time-resolved plasma conditions, which are then post-processed with CRETIN to assess the feasibility of a spectroscopic measurement. We examine target performance with respect to variations in gas fill pressure, ablator thickness, atom fraction of the Ar dopant, and drive energy, and assess the sensitivity of the predicted spectra to variations in the models for electron-ion equilibration and thermal conductivity. Prepared by LLNL under Contract DE-AC52-07NA27344. LLNL-ABS-675219.

Magnetic field-driven lateral photovoltaic effect in the Fe/SiO2/p-Si hybrid structure with the Schottky barrier

NASA Astrophysics Data System (ADS)

Volkov, N. V.; Rautskii, M. V.; Tarasov, A. S.; Yakovlev, I. A.; Bondarev, I. A.; Lukyanenko, A. V.; Varnakov, S. N.; Ovchinnikov, S. G.

2018-07-01

We demonstrate that the lateral photovoltaic effect in the Fe/SiO2/p-Si structure not only strongly depends on the optical radiation wavelength and temperature, but is also sensitive to external magnetic fields. The magnetic field lowers the absolute value of photovoltage regardless of the wavelength and temperature; however, the relative photovoltage variation significantly depends on these parameters. The lateral photovoltage is observed both on the Fe film and Si substrate sides and results from separation of photoinduced electrons and holes in a built-in electric field of the Schottky barrier with their subsequent diffusion to the structure in the lateral direction from the illuminated area. The observed features in the behavior of the lateral photovoltaic effect originate from the variation in the light absorption coefficient of the semiconductor and the related quantum efficiency upon light wavelength variation. In addition, an important role is played by the change in the characteristics of the Schottky barrier at the redistribution of optically generated carriers and temperature variation. The effect of the magnetic field is attributed to the Lorentz force, which bends trajectories of carriers drifting under the action of the Schottky barrier field and, consequently, suppresses the lateral photovoltaic effect.

On the Relative Importance of Convection and Temperature on the Behavior of the Ionosphere in North American during January 6-12, 1997

NASA Technical Reports Server (NTRS)

Richards, P. G.; Buonsanto, M. J.; Reinisch, B. W.; Holt, J.; Fennelly, J. A.; Scali, J. L.; Comfort, R. H.; Germany, G. A.; Spann, J.; Brittnacher, M.

1999-01-01

Measurements from a network of digisondes and an incoherent scatter radar In Eastern North American For January 6-12, 1997 have been compared with the Field Line Interhemispheric Plasma (FLIP) model which now includes the effects of electric field convective. With the exception of Bermuda, the model reproduces the daytime electron density very well most of the time. As is typical behavior for winter solar minimum on magnetically undisturbed nights, the measurements at Millstone Hill show high electron temperatures before midnight followed by a rapid decay, which is accompanied by a pronounced density enhancement in the early morning hours. The FLIP model reproduces the nighttime density enhancement well, provided the model is constrained to follow the topside electron temperature and the flux tube is full. Similar density enhancements are seen at Goose Bay, Wallops Island and Bermuda. However, the peak height variation and auroral images indicate the density enhancements at Goose Bay are most likely due to particle precipitation. Contrary to previously published work we find that the nighttime density variation at Millstone Hill is driven by the temperature behavior and not the other way around. Thus, in both the data and model, the overall nighttime density is lowered and the enhancement does not occur if the temperature remains high all night. Our calculations show that convections of plasma from higher magnetic latitudes does not cause the observed density maximum but it may enhance the density maximum if over-full flux tubes are convected over the station. On the other had, convection of flux tubes with high temperatures and depleted densities may prevent the density maximum from occurring. Despite the success in modeling the nighttime density enhancements, there remain two unresolved problems. First, the measured density decays much faster than the modeled density near sunset at Millstone Hill and Goose Bay though not at lower latitude stations. Second, we cannot fully explain the large temperatures before midnight nor the sudden decay near midnight.

Lunar Prospector observations of the electrostatic potential of the lunar surface and its response to incident currents

NASA Astrophysics Data System (ADS)

Halekas, J. S.; Delory, G. T.; Lin, R. P.; Stubbs, T. J.; Farrell, W. M.

2008-09-01

We present an analysis of Lunar Prospector Electron Reflectometer data from selected time periods using newly developed methods to correct for spacecraft potential and self-consistently utilizing the entire measured electron distribution to remotely sense the lunar surface electrostatic potential with respect to the ambient plasma. These new techniques enable the first quantitative measurements of lunar surface potentials from orbit. Knowledge of the spacecraft potential also allows accurate characterization of the downward-going electron fluxes that contribute to lunar surface charging, allowing us to determine how the lunar surface potential reacts to changing ambient plasma conditions. On the lunar night side, in shadow, we observe lunar surface potentials of ˜-100 V in the terrestrial magnetotail lobes and potentials of ˜-200 V to ˜-1 kV in the plasma sheet. In the lunar wake, we find potentials of ˜-200 V near the edges but smaller potentials in the central wake, where electron temperatures increase and secondary emission may reduce the magnitude of the negative surface potential. During solar energetic particle events, we see nightside lunar surface potentials as large as ˜-4 kV. On the other hand, on the lunar day side, in sunlight, we generally find potentials smaller than our measurement threshold of ˜20 V, except in the plasma sheet, where we still observe negative potentials of several hundred volts at times, even in sunlight. The presence of significant negative charging in sunlight at these times, given the measured incident electron currents, implies either photocurrents from lunar regolith in situ two orders of magnitude lower than those measured in the laboratory or nonmonotonic near-surface potential variation with altitude. The functional dependence of the lunar surface potential on electron temperature in shadow implies somewhat smaller secondary emission yields from lunar regolith in situ than previously measured in the laboratory. These new techniques open the door for future studies of the variation of lunar surface charging as a function of temporal and spatial variations in input currents and as a function of location and material characteristics of the surface as well as comparisons to the increasingly sophisticated theoretical predictions now available.

Low-temperature transport properties of TaxN thin films (0.72 <= x <= 0.83)

NASA Astrophysics Data System (ADS)

Očko, Miroslav; Žonja, Sanja; Nelson, G. L.; Freericks, J. K.; Yu, Lei; Newman, N.

2010-11-01

We report on low-temperature (4-320 K) transport properties of TaxN thin films deposited on an amorphous SiO2 substrate. In this work, TaxN thin films were restricted to a narrow range of x: 0.72 <= x <= 0.83 yet show considerable and nonmonotonic variation of their transport properties with Ta concentration. This behaviour is consistent with a local minimum in the density of electronic states at the Fermi level, as calculated for the rock salt intermetallic Ta4N5, and a rigid band model for describing the transport. The temperature dependence of the resistivity is best fit to the unusual form exp(-T/T0). Interestingly enough, the fit parameter T0 correlates well with the temperature of the maximum of the corresponding thermopower. Both of these characteristics, the fit and the correlation with the thermopower, are consistent with the Jonson-Mahan many-body formalism for charge and thermal transport when one has a nontrivial temperature dependence of the chemical potential. At the lowest temperatures measured, we have also found that the resistivity and thermopower show signatures of electron-electron interactions. We discuss also our results in the light of some theories usually used for describing transport of thin films and to other experimental investigations that have been performed on TaxN.

Study on the effect of hydrogen addition on the variation of plasma parameters of argon-oxygen magnetron glow discharge for synthesis of TiO{sub 2} films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saikia, Partha, E-mail: partha.008@gmail.com; Institute of Physics, Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago; Saikia, Bipul Kumar

2016-04-15

We report the effect of hydrogen addition on plasma parameters of argon-oxygen magnetron glow discharge plasma in the synthesis of H-doped TiO{sub 2} films. The parameters of the hydrogen-added Ar/O{sub 2} plasma influence the properties and the structural phases of the deposited TiO{sub 2} film. Therefore, the variation of plasma parameters such as electron temperature (T{sub e}), electron density (n{sub e}), ion density (n{sub i}), degree of ionization of Ar and degree of dissociation of H{sub 2} as a function of hydrogen content in the discharge is studied. Langmuir probe and Optical emission spectroscopy are used to characterize the plasma.more » On the basis of the different reactions in the gas phase of the magnetron discharge, the variation of plasma parameters and sputtering rate are explained. It is observed that the electron and heavy ion density decline with gradual addition of hydrogen in the discharge. Hydrogen addition significantly changes the degree of ionization of Ar which influences the structural phases of the TiO{sub 2} film.« less

Magnon-induced interband spin-flip scattering contribution to resistivity and magnetoresistance in a nanocrystalline itinerant-electron ferromagnet: Effect of crystallite size

NASA Astrophysics Data System (ADS)

Madduri, P. V. Prakash; Kaul, S. N.

2017-05-01

We report the results of an exhaustive study of `zero-field' electrical resistivity ρ (T ) and magnetoresistance (MR) (in magnetic fields up to 90 kOe) over the temperature range 1.8-300 K in nanocrystalline (nc-) Ni with average crystallite size d ranging from 10 nm to 40 nm. A quantitative comparison of our results with the predictions of the recent self-consistent calculations permits us to unambiguously identify the scattering mechanisms responsible for ρ (T ) and MR in different temperature ranges and accurately determine their relative magnitudes in nc-Ni samples of different d . Like in bulk 3 d transition metal ferromagnets, ρ varies with temperature as T2 at T ≲15 K. Contrary to the widely-held view that the T2 variation of ρ at low temperatures arises from the electron-magnon (e -m ) scattering, this contribution to ρ (T ) is shown to originate from the electron-electron (Baber) scattering. In the temperature range 15 K≤T ≤300 K, the phonon-induced non-spin-flip (NSF) intraband [i.e., s↑↓-s↑↓ , d↑↓-d↑↓ electron-phonon (e -p )] scattering and magnon-induced spin-flip (SF) interband (i.e., s↑↓-d↓↑e -m ) scattering contributions completely account for the intrinsic resistivity. The former contribution dominates over the latter at T >T whereas the reverse is true at temperatures 15 K ≤T T , ρe -m(T ,H =0 ) becomes comparable in magnitude to ρe -p(T ,H =0 ) for d ≥25 nm. By contrast, the MR in nc-Ni is entirely due to the s↑↓-d↓↑e -m scattering. The present work clearly brings out the importance of the thermal renormalization of magnon mass (caused mainly by the magnon-magnon interactions) over the temperature range 15 K≤T ≤300 K. Irrespective of the value of d (including the bulk, d =∞ ), phonon-induced s↑↓-s↑↓ , d↑↓-d↑↓ transitions are more frequent than the e -p s↑↓-d↑↓ transitions over the entire temperature range 1.8 K≤T ≤300 K. The saturation magnetization at 0 K, spin wave stiffness at 0 K, Debye temperature as well as the parameters that are a direct measure of the strength of e -p coupling, e -m coupling, and level of suppression of e -m scattering by external magnetic field, all exhibit power law variations with d . The power law behavior asserts that the average crystallite size is the dominant length scale so far as the magnetism, electrical transport, and magnetotransport in nc-Ni are concerned.

First iron and cobalt(II) hexabromoclathrochelates: structural, magnetic, redox, and electrocatalytic behavior.

PubMed

Dolganov, Alexander V; Belov, Alexander S; Novikov, Valentin V; Vologzhanina, Anna V; Romanenko, Galina V; Budnikova, Yulia G; Zelinskii, Genrikh E; Buzin, Michail I; Voloshin, Yan Z

2015-02-07

Template condensation of dibromoglyoxime with n-butylboronic acid on the corresponding metal ion as a matrix under vigorous reaction conditions afforded iron and cobalt(ii) hexabromoclathrochelates. The paramagnetic cobalt clathrochelate was found to be a low-spin complex at temperatures below 100 K, with a gradual increase in the effective magnetic moment at higher temperatures due to the temperature 1/2↔3/2 spin crossover and a gap caused by the structure phase transition. The multitemperature X-ray and DSC studies of this complex and its iron(ii)-containing analog also showed temperature structural transitions. The variation of an encapsulated metal ion's radius, electronic structure and spin state caused substantial differences in the geometry of its coordination polyhedron; these differences increase with the decrease in temperature due to Jahn-Teller distortion of the encapsulated cobalt(ii) ion with an electronic configuration d(7). As follows from CV and GC data, these cage iron and cobalt complexes undergo both oxidation and reduction quasireversibly, and showed an electrocatalytic activity for hydrogen production in different producing systems.

Elastic properties, thermal stability, and thermodynamic parameters of MoAlB

NASA Astrophysics Data System (ADS)

Kota, Sankalp; Agne, Matthias; Zapata-Solvas, Eugenio; Dezellus, Olivier; Lopez, Diego; Gardiola, Bruno; Radovic, Miladin; Barsoum, Michel W.

2017-04-01

MoAlB is the first and, so far, the only transition-metal boride that forms alumina when heated in air and is thus potentially useful for high-temperature applications. Herein, the thermal stability in argon and vacuum atmospheres and the thermodynamic parameters of bulk polycrystalline MoAlB were investigated experimentally. At temperatures above 1708 K, in vacuum and inert atmospheres, this compound incongruently melts into the binary MoB and liquid aluminum metal as confirmed by differential thermal analysis, quenching experiments, x-ray diffraction, and scanning electron microscopy. Making use of that information together with heat-capacity measurements in the 4-1000-K temperature range—successfully modeled as the sum of lattice, electronic, and dilation contributions—the standard enthalpy, entropy, and free energy of formation are computed and reported for the full temperature range. The standard enthalpy of formation of MoAlB at 298 K was found to be -132 ±3.2 kJ/mol. Lastly, the thermal conductivity values are computed and modeled using a variation of the Slack model in the 300-1600-K temperature range.

Magnetic field and pressure dependant resistivity behaviour of MnAs

NASA Astrophysics Data System (ADS)

Satya, A. T.; Amaladass, E. P.; Mani, Awadhesh

2018-04-01

The studies on the effect of magnetic field and external pressure on temperature dependant electrical resistivity behaviour of polycrystalline MnAs have been reported. At ambient pressure, ρ(T) shows a first order magnetic transition associated with change in sign of the temperature coefficient of resistivity from positive in the ferromagnetic (FM) phase to negative in the paramagnetic (PM) phase. The magneto resistance is negative and shows a peak at the FM transition temperature (T C ). The first order hysteresis width decreases with increase in magnetic field and the intersection of extrapolated linear variations of T C with field for the cooling and warming cycles enabled determination of the tricritical point. At high pressures, ρ(T) displays non monotonic variation exhibiting a low temperature minimum ({T}\\min L) and a high temperature maximum ({T}\\max H) accompanying broad thermal hysteresis above {T}\\min L. It is surmised that spin disorder scattering is responsible for the resistivity behaviour above {T}\\min L and the essential features of ρ(T) are qualitatively explained using Kasuya theoretical model. Below the {T}\\min L, ρ(T) follows linear logarithmic temperature dependence similar to the effect occurring due to Kondo type of scattering of conduction electrons with localised moments.

A Model of the Influence of Neutral Air Dynamics on the Seasonal Variation in the Low Ionosphere

NASA Technical Reports Server (NTRS)

Nestorov, G.; Velinov, P. J.; Pancheva, T.

1984-01-01

Recently it has become clear that the phenomena in the ionospheric D-region are determined to a great extent by dynamical processes in the strato-mesosphere D-region. In this respect much attention is paid to the study of the winter anomaly (WA) phenomenon on medium and short radiowaves, in which the meteorological character of the lower ionosphere is most prominent. Significant experimental data about the variations of the electron concentration, N, ion composition, temperature and dynamic regime during WA permit a better understanding of the character of the physical processes in the middle atmosphere. The influence of the neutral wind on the seasonal variation of the electron concentration N for the altitude interval 90 or = z or = 120 km, where the ratio upsilon sub in/omega sub i, of the ion-neutral collision frequency, upsilon sub in and the ion gyrofrequency, omega sub i decreases from 40 to 1 was evaluated. CIRA-72 is used as a model of the zonal wind.

Scale Height variations with solar cycle in the ionosphere of Mars

NASA Astrophysics Data System (ADS)

Sanchez-Cano, Beatriz; Lester, Mark; Witasse, Olivier; Milan, Stephen E.; Hall, Benjamin E. S.; Cartacci, Marco; Radicella, Sandro M.; Blelly, Pierre-Louis

2015-04-01

The Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS) on board the Mars Express spacecraft has been probing the topside of the ionosphere of Mars since June 2005, covering currently almost one solar cycle. A good knowledge of the behaviour of the ionospheric variability for a whole solar period is essential since the ionosphere is strongly dependent on solar activity. Using part of this dataset, covering the years 2005 - 2012, differences in the shape of the topside electron density profiles have been observed. These variations seem to be linked to changes in the ionospheric temperature due to the solar cycle variation. In particular, Mars' ionospheric response to the extreme solar minimum between end-2007 and end-2009 followed a similar pattern to the response observed in the Earth's ionosphere, despite the large differences related to internal origin of the magnetic field between both planets. Plasma parameters such as the scale height as a function of altitude, the main peak characteristics (altitude, density), the total electron content (TEC), the temperatures, and the ionospheric thermal pressures show variations related to the solar cycle. The main changes in the topside ionosphere are detected during the period of very low solar minimum, when ionospheric cooling occurs. The effect on the scale height is analysed in detail. In contrast, a clear increase of the scale height is observed during the high solar activity period due to enhanced ionospheric heating. The scale height variation during the solar cycle has been empirically modelled. The results have been compared with other datasets such as radio-occultation and retarding potential analyser data from old missions, especially in low solar activity periods (e.g. Mariner 4, Viking 1 and 2 landers), as well as with numerical modelling.

Model for energy transfer in the solar wind: Model results

NASA Technical Reports Server (NTRS)

Barnes, A. A., Jr.; Hartle, R. E.

1972-01-01

A description is given of the results of solar wind flow in which the heating is due to (1) propagation and dissipation of hydromagnetic waves generated near the base of the wind, and (2) thermal conduction. A series of models is generated for fixed values of density, electron and proton temperature, and magnetic field at the base by varying the wave intensity at the base of the model. This series of models predicts the observed correlation between flow speed and proton temperature for a large range of velocities. The wave heating takes place in a shell about the sun greater than or approximately equal to 10 R thick. We conclude that large-scale variations observed in the solar wind are probably due mainly to variation in the hydromagnetic wave flux near the sun.

Electron Stark Broadening Database for Atomic N, O, and C Lines

NASA Technical Reports Server (NTRS)

Liu, Yen; Yao, Winifred M.; Wray, Alan A.; Carbon, Duane F.

2012-01-01

A database for efficiently computing the electron Stark broadening line widths for atomic N, O, and C lines is constructed. The line width is expressed in terms of the electron number density and electronatom scattering cross sections based on the Baranger impact theory. The state-to-state cross sections are computed using the semiclassical approximation, in which the atom is treated quantum mechanically whereas the motion of the free electron follows a classical trajectory. These state-to-state cross sections are calculated based on newly compiled line lists. Each atomic line list consists of a careful merger of NIST, Vanderbilt, and TOPbase line datasets from wavelength 50 nm to 50 micrometers covering the VUV to IR spectral regions. There are over 10,000 lines in each atomic line list. The widths for each line are computed at 13 electron temperatures between 1,000 K 50,000 K. A linear least squares method using a four-term fractional power series is then employed to obtain an analytical fit for each line-width variation as a function of the electron temperature. The maximum L2 error of the analytic fits for all lines in our line lists is about 5%.

Demonstration of Confined Electron Gas and Steep-Slope Behavior in Delta-Doped GaAs-AlGaAs Core-Shell Nanowire Transistors.

PubMed

Morkötter, S; Jeon, N; Rudolph, D; Loitsch, B; Spirkoska, D; Hoffmann, E; Döblinger, M; Matich, S; Finley, J J; Lauhon, L J; Abstreiter, G; Koblmüller, G

2015-05-13

Strong surface and impurity scattering in III-V semiconductor-based nanowires (NW) degrade the performance of electronic devices, requiring refined concepts for controlling charge carrier conductivity. Here, we demonstrate remote Si delta (δ)-doping of radial GaAs-AlGaAs core-shell NWs that unambiguously exhibit a strongly confined electron gas with enhanced low-temperature field-effect mobilities up to 5 × 10(3) cm(2) V(-1) s(-1). The spatial separation between the high-mobility free electron gas at the NW core-shell interface and the Si dopants in the shell is directly verified by atom probe tomographic (APT) analysis, band-profile calculations, and transport characterization in advanced field-effect transistor (FET) geometries, demonstrating powerful control over the free electron gas density and conductivity. Multigated NW-FETs allow us to spatially resolve channel width- and crystal phase-dependent variations in electron gas density and mobility along single NW-FETs. Notably, dc output and transfer characteristics of these n-type depletion mode NW-FETs reveal excellent drain current saturation and record low subthreshold slopes of 70 mV/dec at on/off ratios >10(4)-10(5) at room temperature.

Suprathermal electron energy distribution within the dayside Venus ionosphere

NASA Technical Reports Server (NTRS)

Knudsen, W. C.; Miller, K. L.; Spenner, K.; Novak, V.; Michelson, P. F.; Whitten, R. C.

1980-01-01

The suprathermal electron energy distribution for the dayside ionosphere has been derived from data returned by the Pioneer-Venus orbiter retarding potential analyzer. The shape and magnitude of the spectrum are consistent with the assumption that solar EUV radiation is the only significant source. The magnitude of the spectrum and its variation with altitude suggest that significant vertical transport occurs, with the electrons being lost through the ionopause. In turn, significant vertical transport suggests that the effective vertical electron heat conductivity may be comparable to the field-free value. The heat input to the thermal electron gas from the measured suprathermal electron flux is too small by a factor of at least five to maintain the observed electron temperature profile if the electron thermal conductivity is assumed to be close to the field-free value. It is thus inferred that most of the heat is supplied by the solar wind.

The effects of incomplete annealing on the temperature dependence of sheet resistance and gage factor in aluminum and phosphorus implanted silicon on sapphire

NASA Technical Reports Server (NTRS)

Pisciotta, B. P.; Gross, C.

1976-01-01

Partial annealing of damage to the crystal lattice during ion implantation reduces the temperature coefficient of resistivity of ion-implanted silicon, while facilitating controlled doping. Reliance on this method for temperature compensation of the resistivity and strain-gage factor is discussed. Implantation conditions and annealing conditions are detailed. The gage factor and its temperature variation are not drastically affected by crystal damage for some crystal orientations. A model is proposed to account for the effects of electron damage on the temperature dependence of resistivity and on silicon piezoresistance. The results are applicable to the design of silicon-on-sapphire strain gages with high gage factors.

Superconducting cuprate heterostructures for hot electron bolometers

NASA Astrophysics Data System (ADS)

Wen, B.; Yakobov, R.; Vitkalov, S. A.; Sergeev, A.

2013-11-01

Transport properties of the resistive state of quasi-two dimensional superconducting heterostructures containing ultrathin La2-xSrxCuO4 layers synthesized using molecular beam epitaxy are studied. The electron transport exhibits strong deviation from Ohm's law, δV ˜γI3, with a coefficient γ(T) that correlates with the temperature variation of the resistivity dρ /dT. Close to the normal state, analysis of the nonlinear behavior in terms of electron heating yields an electron-phonon thermal conductance per unit area ge -ph≈1 W/K cm2 at T = 20 K, one-two orders of magnitude smaller than in typical superconductors. This makes superconducting LaSrCuO heterostructures to be attractive candidate for the next generation of hot electron bolometers with greatly improved sensitivity.

Evolution of two-dimensional plasma parameters in the plane of the wafer during the E- to H- and H- to E-mode transition in an inductively coupled plasma

NASA Astrophysics Data System (ADS)

Park, Il-Seo; Kim, Kyung-Hyun; Kim, Tae-Woo; Kim, Kwan-Youg; Moon, Ho-Jun; Chung, Chin-Wook

2018-05-01

The evolution of plasma parameters during the transition from E- to H- and from H- to E-mode is measured at the wafer level two-dimensionally at low and high pressures. The plasma parameters, such as electron density and electron temperature, are obtained through a floating harmonic sideband method. During the E- to H-mode transition, while the electron kinetics remains in the non-local regime at low pressure, the electron kinetics is changed from the non-local to the local regime at high pressure. The two-dimensional profiles of the electron density at two different pressures have similar convex shape despite different electron kinetics. However, in the case of the electron temperature, at high pressure, the profiles of the electron temperature are changed from flat to convex shape. These results can be understood by the diffusion of the plasma to the wafer-level probe. Moreover, between the transition of E to H and reverse H to E, hysteresis is observed even at the wafer level. The hysteresis is clearly shown at high pressure compared to low pressure. This can be explained by a variation of collisional energy loss including effects of electron energy distribution function (bi-Maxwellian, Maxwellian, Druyvesteyn distribution) on the rate constant and multistep ionization of excited state atoms. During the E- to H-mode transition, Maxwellization is caused by increased electron‑electron collisions, which reduces the collisional energy loss at high pressure (Druyvesteyn distribution) and increases it at low pressure (bi-Maxwellian distribution). Thus, the hysteresis is intensified at high pressure because the reduced collisional energy loss leads to higher ionization efficiency.

A thermodynamic model to predict electron mobility in superfluid helium.

PubMed

Aitken, Frédéric; Volino, Ferdinand; Mendoza-Luna, Luis Guillermo; Haeften, Klaus von; Eloranta, Jussi

2017-06-21

Electron mobility in superfluid helium is modeled between 0.1 and 2.2 K by a van der Waals-type thermodynamic equation of state, which relates the free volume of solvated electrons to temperature, density, and phase dependent internal pressure. The model is first calibrated against known electron mobility reference data along the saturated vapor pressure line and then validated to reproduce the existing mobility literature values as a function of pressure and temperature with at least 10% accuracy. Four different electron mobility regimes are identified: (1) Landau critical velocity limit (T ≈ 0), (2) mobility limited by thermal phonons (T < 0.6 K), (3) thermal phonon and discrete roton scattering ("roton gas") limited mobility (0.6 K < T < 1.2 K), and (4) the viscous liquid ("roton continuum") limit (T > 1.2 K) where the ion solvation structure directly determines the mobility. In the latter regime, the Stokes equation can be used to estimate the hydrodynamic radius of the solvated electron based on its mobility and fluid viscosity. To account for the non-continuum behavior appearing below 1.2 K, the temperature and density dependent Millikan-Cunningham factor is introduced. The hydrodynamic electron bubble radii predicted by the present model appear generally larger than the solvation cavity interface barycenter values obtained from density functional theory (DFT) calculations. Based on the classical Stokes law, this difference can arise from the variation of viscosity and flow characteristics around the electron. The calculated DFT liquid density profiles show distinct oscillations at the vacuum/liquid interface, which increase the interface rigidity.

Experimentally Determined Plasma Parameters in a 30 cm Ion Engine

NASA Technical Reports Server (NTRS)

Sengupta, Anita; Goebel, Dan; Fitzgerald, Dennis; Owens, Al; Tynan, George; Dorner, Russ

2004-01-01

Single planar Langmuir probes and fiber optic probes are used to concurrently measure the plasma properties and neutral density variation in a 30cm diameter ion engine discharge chamber, from the immediate vicinity of the keeper to the near grid plasma region. The fiber optic probe consists of a collimated optical fiber recessed into a double bore ceramic tube fitted with a stainless steel light-limiting window. The optical fiber probe is used to measure the emission intensity of excited neutral xenon for a small volume of plasma, at various radial and axial locations. The single Langmuir probes, are used to generate current-voltage characteristics at a total of 140 spatial locations inside the discharge chamber. Assuming a maxwellian distribution for the electron population, the Langmuir probe traces provide spatially resolved measurements of plasma potential, electron temperature, and plasma density. Data reduction for the NSTAR TH8 and TH15 throttle points indicates an electron temperature range of 1 to 7.9 eV and an electron density range of 4e10 to le13 cm(sup -3), throughout the discharge chamber, consistent with the results in the literature. Plasma potential estimates, computed from the first derivative of the probe characteristic, indicate potential from 0.5V to 11V above the discharge voltage along the thruster centerline. These values are believed to be excessively high due to the sampling of the primary electron population along the thruster centerline. Relative neutral density profiles are also obtained with a fiber optic probe sampling photon flux from the 823.1 nm excited to ground state transition. Plasma parameter measurements and neutral density profiles will be presented as a function of probe location and engine discharge conditions. A discussion of the measured electron energy distribution function will also be presented, with regards to variation from pure maxwellian. It has been found that there is a distinct primary population found along the thruster centerline, which causes estimates of electron temperature, electron density, and plasma potential, to err on the high side, due this energetic population. Computation of the energy distribution fimction of the plasma clearly indicates the presence of primaries, whose presence become less obvious with radial distance from the main discharge plume.

Spacecraft potential control on ISEE-1

NASA Technical Reports Server (NTRS)

Gonfalone, A.; Pedersen, A.; Fahleson, U. V.; Faelthammar, C. G.; Mozer, F. S.; Torbert, R. B.

1979-01-01

Active control of the potential of the ISEE-1 satellite by the use of electron guns is reviewed. The electron guns contain a special cathode capable of emitting an electron current selectable between 10 to the -8th power and 10 to the -3rd power at energies from approximately .6 to 41 eV. Results obtained during flight show that the satellite potential can be stabilized at a value more positive than the normally positive floating potential. The electron guns also reduce the spin modulation of the spacecraft potential which is due to the aspect dependent photoemission of the long booms. Plasma parameters like electron temperature and density can be deduced from the variation of the spacecraft potential as a function of the gun current. The effects of electron beam emission on other experiments are briefly mentioned.

The TELEC - A plasma type of direct energy converter. [Thermo-Electronic Laser Energy Converter for electric power generation

NASA Technical Reports Server (NTRS)

Britt, E. J.

1978-01-01

The Thermo-Electronic Laser Energy Converter (TELEC) is a high-power density plasma device designed to convert a 10.6-micron CO2 laser beam into electric power. Electromagnetic radiation is absorbed in plasma electrons, creating a high-electron temperature. Energetic electrons diffuse from the plasma and strike two electrodes having different areas. The larger electrode collects more electrons and there is a net transport of current. An electromagnetic field is generated in the external circuit. A computer program has been designed to analyze TELEC performance allowing parametric variation for optimization. Values are presented for TELEC performance as a function of cesium pressure and for current density and efficiency as a function of output voltage. Efficiency is shown to increase with pressure, reaching a maximum over 45%.

Solar cycle variations of the solar wind

NASA Technical Reports Server (NTRS)

Crooker, N. U.

1983-01-01

Throughout the course of the past one and a half solar cycles, solar wind parameters measured near the ecliptic plane at 1 AU varied in the following way: speed and proton temperature have maxima during the declining phase and minima at solar minimum and are approximately anti-correlated with number density and electron temperature, while magnetic field magnitude and relative abundance of helium roughly follow the sunspot cycle. These variations are described in terms of the solar cycle variations of coronal holes, streamers, and transients. The solar wind signatures of the three features are discussed in turn, with special emphasis on the signature of transients, which is still in the process of being defined. It is proposed that magnetic clouds be identified with helium abundance enhancements and that they form the head of a transient surrounded by streamer like plasma, with an optional shock front. It is stressed that relative values of a parameter through a solar cycle should be compared beginning with the declining phase, especially in the case of magnetic field magnitude.

Mesospheric temperature estimation from meteor decay times of weak and strong meteor trails

NASA Astrophysics Data System (ADS)

Kim, Jeong-Han; Kim, Yong Ha; Jee, Geonhwa; Lee, Changsup

2012-11-01

Neutral temperatures near the mesopause region were estimated from the decay times of the meteor echoes observed by a VHF meteor radar during a period covering 2007 to 2009 at King Sejong Station (62.22°S, 58.78°W), Antarctica. While some previous studies have used all meteor echoes to determine the slope from a height profile of log inverse decay times for temperature estimation, we have divided meteor echoes into weak and strong groups of underdense meteor trails, depending on the strength of estimated relative electron line densities within meteor trails. We found that the slopes from the strong group are inappropriate for temperature estimation because the decay times of strong meteors are considerably scattered, whereas the slopes from the weak group clearly define the variation of decay times with height. We thus utilize the slopes only from the weak group in the altitude region between 86 km and 96 km to estimate mesospheric temperatures. The meteor estimated temperatures show a typical seasonal variation near the mesopause region and the monthly mean temperatures are in good agreement with SABER temperatures within a mean difference of 4.8 K throughout the year. The meteor temperatures, representing typically the region around the altitude of 91 km, are lower on average by 2.1 K than simultaneously measured SATI OH(6-2) rotational temperatures during winter (March-October).

Fermi Surface Studies and Temperature Dependence of the Electron-Positron Momentum Density in the High Critical Temperature Superconducting Yttrium BARIUM(2) COPPER(3) OXYGEN(7-X) System by Two-Dimensional Acar

NASA Astrophysics Data System (ADS)

von Stetten, Eric Carl

The electron-positron momentum density has been measured by the two dimensional angular correlation of annihilation radiation (2D ACAR) technique for single crystal and polycrystalline (sintered powder) YBa_2 Cu_3O_{7-x} samples. For sintered superconducting and nonsuperconducting samples, the shape and temperature variation of the momentum density was investigated using the high sensitivity 2D ACAR technique. The possible existence of Fermi surfaces (FS's) in the YBa_2Cu _3O_{7-x} system was investigated in high precision 2D ACAR experiments on an oriented (twinned) single crystal superconducting YBa_2Cu _3O_{7-x} (x ~ 0.1) sample, at temperatures above and below the superconducting transition temperature (~85 K). These experiments were performed in the c-axis projection, in order to observe the theoretically predicted cylindrical FS's (if they exist) in a single experiment, without a full reconstruction of the three dimensional momentum density. Large differences were observed between the room temperature 2D ACAR spectra for superconducting and nonsuperconducting sintered powder samples, and smaller differences were observed between the spectra for similarly prepared superconducting samples. For sintered superconducting samples, complex sample dependent temperature variations of the momentum density were observed, in contrast to the small linear temperature variation observed for a sintered powder nonsuperconducting sample. These results are interpreted as manifestations of the theoretically predicted preferential sampling of the linear Cu-O chain region by the positron in the YBa _2Cu_3O _{7-x} system. High precision experiments on the single crystal superconducting sample revealed a nearly isotropic 2D ACAR spectrum, with only four small (~3% of the height at p_{x} = p _{y} = 0) peaks centered along the (110) symmetry lines. A small narrowing of the 2D ACAR spectrum was observed above T_{c}. The Brillouin-zone-reduced momentum density was formed using the "Lock-Crisp-West folding" technique, in order to identify possible FS signatures; several small features were observed that could possibly be due to FS's. A computer study of statistical noise propagation in 2D ACAR data, however, found that the possible FS signatures in the experimental data are similar in shape and magnitude to noise produced features.

Comparative study of magnetic ordering in bulk and nanoparticles of Sm0.65Ca0.35MnO3: Magnetization and electron magnetic resonance measurements

NASA Astrophysics Data System (ADS)

Goveas, Lora Rita; Anuradha, K. N.; Bhagyashree, K. S.; Bhat, S. V.

2015-05-01

To explore the effect of size reduction to nanoscale on the hole doped Sm0.65Ca0.35MnO3 compound, dc magnetic measurements and electron magnetic resonance (EMR) were done on bulk and nanoparticle samples in the temperature range 10 ≤ T ≤ 300 K. Magnetization measurement showed that the bulk sample undergoes a charge ordering transition at 240 K and shows a mixed magnetic phase at low temperature. However, the nanosample underwent a ferromagnetic transition at 75 K, and the charge ordered state was destabilized on size reduction down to nanoscale. The low-temperature ferromagnetic component is found to be enhanced in nanoparticles as compared to their bulk counterpart. Interestingly around room temperature, bulk particles show higher magnetization where as at low temperature nanoparticles show higher magnetization. Ferromagnetism in the bulk is due to super exchange where as ferromagnetism in nanoparticles is due to uncompensated spins of the surface layer. Temperature variation of EMR parameters correlates well with the results of magnetic measurements. The magnetic behaviour of the nanoparticles is understood in terms of the core shell scenario.

Study of Plasma Waves Observed onboard Rosetta in the 67P/ChuryumovGerasimenko Comet Environment Using High Time Resolution Density Data Inferred from RPC-MIP and RPC-LAP Cross-calibration

NASA Astrophysics Data System (ADS)

Breuillard, H.; Henri, P.; Vallières, X.; Eriksson, A. I.; Odelstad, E.; Johansson, F. L.; Richter, I.; Goetz, C.; Wattieaux, G.; Tsurutani, B.; Hajra, R.; Le Contel, O.

2017-12-01

During two years, the groundbreaking ESA/Rosetta mission was able to escort comet 67P where previous cometary missions were only limited to flybys. This enabled for the first time to make in-situ measurements of the evolution of a comet's plasma environment. The density and temperature measured by Rosetta are derived from RPC-Mutual Impedance Probe (MIP) and RPC-Langmuir Probe (LAP). On one hand, low time resolution electron density are calculated using the plasma frequency extracted from the MIP mutual impedance spectra. On the other hand, high time resolution density fluctuations are estimated from the spacecraft potential measured by LAP. In this study, using a simple spacecraft charging model, we perform a cross-calibration of MIP plasma density and LAP spacecraft potential variations to obtain high time resolution measurements of the electron density. These results are also used to constrain the electron temperature. Then we make use of these new dataset, together with RPC-MAG magnetic field measurements, to investigate for the first time the compressibility and the correlations between plasma and magnetic field variations, for both singing comet waves and steepened waves observed, respectively during low and high cometary outgassing activity, in the plasma environment of comet 67P.

Electronic origin of structural transition in 122 Fe based superconductors

NASA Astrophysics Data System (ADS)

Ghosh, Haranath; Sen, Smritijit; Ghosh, Abyay

2017-03-01

Direct quantitative correlations between the orbital order and orthorhombicity is achieved in a number of Fe-based superconductors of 122 family. The former (orbital order) is calculated from first principles simulations using experimentally determined doping and temperature dependent structural parameters while the latter (the orthorhombicity) is taken from already established experimental studies; when normalized, both the above quantities quantitatively corresponds to each other in terms of their doping as well as temperature variations. This proves that the structural transition in Fe-based materials is electronic in nature due to orbital ordering. An universal correlations among various structural parameters and electronic structure are also obtained. Most remarkable among them is the mapping of two Fe-Fe distances in the low temperature orthorhombic phase, with the band energies Edxz, Edyz of Fe at the high symmetry points of the Brillouin zone. The fractional co-ordinate zAs of As which essentially determines anion height is inversely (directly) proportional to Fe-As bond distances (with exceptions of K doped BaFe2As2) for hole (electron) doped materials as a function of doping. On the other hand, Fe-As bond-distance is found to be inversely (directly) proportional to the density of states at the Fermi level for hole (electron) doped systems. Implications of these results to current issues of Fe based superconductivity are discussed.

International Reference Ionosphere -2010

NASA Astrophysics Data System (ADS)

Bilitza, Dieter; Reinisch, Bodo

The International Reference Ionosphere 2010 includes several important improvements and ad-ditions. This presentation introduces these changes and discusses their benefits. The electron and ion density profiles for the bottomside ionosphere will be significantly improved by using more ionosonde data as well as photochemical considerations. As an additional lower iono-sphere parameter IRI-2010 will include the transition height from molecular to cluster ions. At the F2 peak Neural Net models for the peak density and the propagation factor M3000F2, which is related to the F2 peak height, are introduced as new options. At high latitudes the model will benefit from the introduction of auroral oval boundaries and their variation with magnetic activity. Regarding the electron temperature, IRI-2010 now models variations with solar activity. The homepage for the IRI project is at http://IRI.gsfc.nasa.gov/.

Inter-Disciplinary Validation of Pre Earthquake Signals. Case Study for Major Earthquakes in Asia (2004-2010) and for 2011 Tohoku Earthquake

NASA Technical Reports Server (NTRS)

Ouzounov, D.; Pulinets, S.; Hattori, K.; Liu, J.-Y.; Yang. T. Y.; Parrot, M.; Kafatos, M.; Taylor, P.

2012-01-01

We carried out multi-sensors observations in our investigation of phenomena preceding major earthquakes. Our approach is based on a systematic analysis of several physical and environmental parameters, which we found, associated with the earthquake processes: thermal infrared radiation, temperature and concentration of electrons in the ionosphere, radon/ion activities, and air temperature/humidity in the atmosphere. We used satellite and ground observations and interpreted them with the Lithosphere-Atmosphere- Ionosphere Coupling (LAIC) model, one of possible paradigms we study and support. We made two independent continues hind-cast investigations in Taiwan and Japan for total of 102 earthquakes (M>6) occurring from 2004-2011. We analyzed: (1) ionospheric electromagnetic radiation, plasma and energetic electron measurements from DEMETER (2) emitted long-wavelength radiation (OLR) from NOAA/AVHRR and NASA/EOS; (3) radon/ion variations (in situ data); and 4) GPS Total Electron Content (TEC) measurements collected from space and ground based observations. This joint analysis of ground and satellite data has shown that one to six (or more) days prior to the largest earthquakes there were anomalies in all of the analyzed physical observations. For the latest March 11 , 2011 Tohoku earthquake, our analysis shows again the same relationship between several independent observations characterizing the lithosphere /atmosphere coupling. On March 7th we found a rapid increase of emitted infrared radiation observed from satellite data and subsequently an anomaly developed near the epicenter. The GPS/TEC data indicated an increase and variation in electron density reaching a maximum value on March 8. Beginning from this day we confirmed an abnormal TEC variation over the epicenter in the lower ionosphere. These findings revealed the existence of atmospheric and ionospheric phenomena occurring prior to the 2011 Tohoku earthquake, which indicated new evidence of a distinct coupling between the lithosphere and atmosphere/ionosphere.

Application of Signal Analysis to the Climate

PubMed Central

2014-01-01

The primary ingredient of the Anthropogenic Global Warming hypothesis, namely, the assumption that additional atmospheric carbon dioxide substantially raises the global temperature, is studied. This is done by looking at the data of temperature and CO2, both in the time domain and in the phase domain of periodic data. Bicentenary measurements are analyzed and a relaxation model is introduced in the form of an electronic equivalent circuit. The effects of this relaxation manifest themselves in delays in the time domain and correlated phase shifts in the phase domain. For extremely long relaxation time constants, the delay is maximally one-quarter period, which for the yearly-periodic signal means 3 months. This is not in line with the analyzed data, the latter showing delays of 9 (−3) months. These results indicate a reverse function of cause and effect, with temperature being the cause for atmospheric CO2 changes, rather than their effect. These two hypotheses are discussed on basis of literature, where it was also reported that CO2 variations are lagging behind temperature variations. PMID:27350978

Study of electrostatic electron cyclotron parallel flow velocity shear instability in the magnetosphere of Saturn

NASA Astrophysics Data System (ADS)

Kandpal, Praveen; Pandey, R. S.

2018-05-01

In the present paper, the study of electrostatic electron cyclotron parallel flow velocity shear instability in presence of perpendicular inhomogeneous DC electric field has been carried out in the magnetosphere of Saturn. Dimensionless growth rate variation of electron cyclotron waves has been observed with respect to k⊥ ρe for various plasma parameters. Effect of velocity shear scale length (Ae), inhomogeneity (P/a), the ratio of ion to electron temperature (Ti/Te) and density gradient (ɛnρe) on the growth of electron cyclotron waves in the inner magnetosphere of Saturn has been studied and analyzed. The mathematical formulation and computation of dispersion relation and growth rate have been done by using the method of characteristic solution and kinetic approach. This theoretical analysis has been done taking the relevant data from the Cassini spacecraft in the inner magnetosphere of Saturn. We have considered ambient magnetic field data and other relevant data for this study at the radial distance of ˜4.82-5.00 Rs. In our study velocity shear and ion to electron temperature ratio have been observed to be the major sources of free energy for the electron cyclotron instability. The inhomogeneity of electric field caused a small noticeable impact on the growth rate of electrostatic electron cyclotron instability. Density gradient has been observed playing stabilizing effect on electron cyclotron instability.

All-fiber pyroelectric nanogenerator

NASA Astrophysics Data System (ADS)

Ghosh, Sujoy Kumar; Xie, Mengying; Bowen, Christopher Rhys; Mandal, Dipankar

2018-04-01

An all-fiber pyroelectric nanogenerator (PyNG) is fabricated where both the active pyroelectric component and the electrodes were composed of fiber. The pyroelectric component was made with randomly organized electrospun PVDF nano-fibers possessing ferroelectric β- and γ-phases. The PyNG possess higher level of sensitivity which can detect very low level of temperature fluctuation, as, low as, 2 K. In addition, the thermal energy harvesting ability of the PyNG under several temperature variations and cycling frequencies paves the way for next generation thermal sensor and self-powered flexible micro-electronics.

Ultrasonic attenuation measurements determine onset, degree, and completion of recrystallization

NASA Technical Reports Server (NTRS)

Generazio, E. R.

1988-01-01

Ultrasonic attenuation was measured for cold worked Nickel 200 samples annealed at increasing temperatures. Localized dislocation density variations, crystalline order and volume percent of recrystallized phase were determined over the anneal temperature range using transmission electron microscopy, X-ray diffraction, and metallurgy. The exponent of the frequency dependence of the attenuation was found to be a key variable relating ultrasonic attenuation to the thermal kinetics of the recrystallization process. Identification of this key variable allows for the ultrasonic determination of onset, degree, and completion of recrystallization.

Evaluating Microstructure Preservation using Scanning Electron Microscopy in an Extinct Bivalve, Lahillia larseni

NASA Astrophysics Data System (ADS)

Mohr, R. C.; Tobin, T. S.

2017-12-01

Ontogenetic stable isotope (δ18O) sampling of accretionary carbonate shells can provide sub-annual records of environmental conditions, such as seawater temperature, during the life of an organism. These records of seasonal temperature variations can refine our understanding of ancient climates and past climate change. However, because original isotopic signatures can be altered by diagenesis, it is necessary to examine potential specimens for evidence of diagenetic alteration. Abundant aragonitic Lahillia larseni bivalves from the latest Cretaceous and Early Paleogene on Seymour Island, Antarctica, provide excellent opportunities for sclerochronological investigations. Shells of L. larseni preserve clear annual growth bands, which make them ideal candidates for high-resolution δ18O sampling to produce sub-annual records of seawater temperature variation. While the good visual condition of these shells and the preservation of original aragonitic material suggests a high level of preservation suitable for isotopic analysis, subtle alteration of the original shell microstructures can still compromise the original isotopic signatures. Scanning electron microscopy (SEM) can be used to evaluate the preservation of these microstructures. This study compares methods for imaging L. larseni bivalve shells with SEM and seeks a consistent way to evaluate their various microstructures for evidence of diagenetic alteration. High-resolution ontogenetic isotopic sampling will also be conducted on several L. larseni shells, as roughly sinusoidal δ18O profiles are often an indication that the original isotopic signatures have been preserved.

Advanced electro-mechanical micro-shutters for thermal infrared night vision imaging and targeting systems

NASA Astrophysics Data System (ADS)

Durfee, David; Johnson, Walter; McLeod, Scott

2007-04-01

Un-cooled microbolometer sensors used in modern infrared night vision systems such as driver vehicle enhancement (DVE) or thermal weapons sights (TWS) require a mechanical shutter. Although much consideration is given to the performance requirements of the sensor, supporting electronic components and imaging optics, the shutter technology required to survive in combat is typically the last consideration in the system design. Electro-mechanical shutters used in military IR applications must be reliable in temperature extremes from a low temperature of -40°C to a high temperature of +70°C. They must be extremely light weight while having the ability to withstand the high vibration and shock forces associated with systems mounted in military combat vehicles, weapon telescopic sights, or downed unmanned aerial vehicles (UAV). Electro-mechanical shutters must have minimal power consumption and contain circuitry integrated into the shutter to manage battery power while simultaneously adapting to changes in electrical component operating parameters caused by extreme temperature variations. The technology required to produce a miniature electro-mechanical shutter capable of fitting into a rifle scope with these capabilities requires innovations in mechanical design, material science, and electronics. This paper describes a new, miniature electro-mechanical shutter technology with integrated power management electronics designed for extreme service infra-red night vision systems.

Nature and evolution of incommensurate charge order in manganites visualized with cryogenic scanning transmission electron microscopy.

PubMed

El Baggari, Ismail; Savitzky, Benjamin H; Admasu, Alemayehu S; Kim, Jaewook; Cheong, Sang-Wook; Hovden, Robert; Kourkoutis, Lena F

2018-02-13

Incommensurate charge order in hole-doped oxides is intertwined with exotic phenomena such as colossal magnetoresistance, high-temperature superconductivity, and electronic nematicity. Here, we map, at atomic resolution, the nature of incommensurate charge-lattice order in a manganite using scanning transmission electron microscopy at room temperature and cryogenic temperature ([Formula: see text]93 K). In diffraction, the ordering wave vector changes upon cooling, a behavior typically associated with incommensurate order. However, using real space measurements, we discover that the ordered state forms lattice-locked regions over a few wavelengths interspersed with phase defects and changing periodicity. The cations undergo picometer-scale ([Formula: see text]6 pm to 11 pm) transverse displacements, suggesting that charge-lattice coupling is strong. We further unearth phase inhomogeneity in the periodic lattice displacements at room temperature, and emergent phase coherence at 93 K. Such local phase variations govern the long-range correlations of the charge-ordered state and locally change the periodicity of the modulations, resulting in wave vector shifts in reciprocal space. These atomically resolved observations underscore the importance of lattice coupling and phase inhomogeneity, and provide a microscopic explanation for putative "incommensurate" order in hole-doped oxides. Copyright © 2018 the Author(s). Published by PNAS.

Phase diagram of electron systems near the superconductor-insulator transition.

PubMed

Pokrovsky, V L; Falco, G M; Nattermann, T

2010-12-31

The zero temperature phase diagram of Cooper pairs exposed to disorder and a magnetic field is determined theoretically from a variational approach. Four distinct phases are found: a Bose and a Fermi insulating, a metallic, and a superconducting phase, respectively. The results explain the giant negative magnetoresistance found experimentally in In-O, TiN, Be and high-T(c) materials.

Theoretical studies for the rates and kinetic isotope effects of the excited-state double proton transfer in the 1:1 7-azaindole:H2O complex using variational transition state theory including multidimensional tunneling.

PubMed

Duong, My Phu Thi; Kim, Yongho

2010-03-18

Variational transition state theory calculations including multidimensional tunneling (VTST/MT) for excited-state tautomerization in the 1:1 7-azaindole:H(2)O complex were performed. Electronic structures and energies for reactant, product, transition state, and potential energy curves along the reaction coordinate were computed at the CASSCF(10,9)/6-31G(d,p) level of theory. The potential energies were corrected by second-order multireference perturbation theory to take the dynamic electron correlation into consideration. The final potential energy curves along the reaction coordinate were generated at the MRPT2//CASSCF(10,9)/6-31G(d,p) level. Two protons in the excited-state tautomerization are transferred concertedly, albeit asynchronously. The position of the variational transition state is very different from the conventional transition state, and is highly dependent on isotopic substitution. Rate constants were calculated using VTST/MT, and were on the order of 10(-6) s(-1) at room temperature. The HH/DD kinetic isotope effects are consistent with experimental observations; consideration of both tunneling and variational effects was essential to predict the experimental values correctly.

Resolving Rapid Variation in Energy for Particle Transport

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haut, Terry Scot; Ahrens, Cory Douglas; Jonko, Alexandra

2016-08-23

Resolving the rapid variation in energy in neutron and thermal radiation transport is needed for the predictive simulation capability in high-energy density physics applications. Energy variation is difficult to resolve due to rapid variations in cross sections and opacities caused by quantized energy levels in the nuclei and electron clouds. In recent work, we have developed a new technique to simultaneously capture slow and rapid variations in the opacities and the solution using homogenization theory, which is similar to multiband (MB) and to the finite-element with discontiguous support (FEDS) method, but does not require closure information. We demonstrated the accuracymore » and efficiency of the method for a variety of problems. We are researching how to extend the method to problems with multiple materials and the same material but with different temperatures and densities. In this highlight, we briefly describe homogenization theory and some results.« less

Temporal Gain Correction for X-Ray Calorimeter Spectrometers

NASA Technical Reports Server (NTRS)

Porter, F. S.; Chiao, M. P.; Eckart, M. E.; Fujimoto, R.; Ishisaki, Y.; Kelley, R. L.; Kilbourne, C. A.; Leutenegger, M. A.; McCammon, D.; Mitsuda, K.

2016-01-01

Calorimetric X-ray detectors are very sensitive to their environment. The boundary conditions can have a profound effect on the gain including heat sink temperature, the local radiation temperature, bias, and the temperature of the readout electronics. Any variation in the boundary conditions can cause temporal variations in the gain of the detector and compromise both the energy scale and the resolving power of the spectrometer. Most production X-ray calorimeter spectrometers, both on the ground and in space, have some means of tracking the gain as a function of time, often using a calibration spectral line. For small gain changes, a linear stretch correction is often sufficient. However, the detectors are intrinsically non-linear and often the event analysis, i.e., shaping, optimal filters etc., add additional non-linearity. Thus for large gain variations or when the best possible precision is required, a linear stretch correction is not sufficient. Here, we discuss a new correction technique based on non-linear interpolation of the energy-scale functions. Using Astro-HSXS calibration data, we demonstrate that the correction can recover the X-ray energy to better than 1 part in 104 over the entire spectral band to above 12 keV even for large-scale gain variations. This method will be used to correct any temporal drift of the on-orbit per-pixel gain using on-board calibration sources for the SXS instrument on the Astro-H observatory.

Positive Voltage Hazard to EMU Crewman from Currents through Plasma

NASA Technical Reports Server (NTRS)

Koontz, Steven L.; Kramer, Leonard; Hamilton, Doug; Mikatarian, Ronald

2010-01-01

This paper describes the model of the EMU with a human body in the circuit that has been used by NASA to evaluate the low positive voltage hazard. The model utilizes the electron collection characterization from on orbit Langmuir probe data as representative of electron collection to a positive charged surface with a wide range of on orbit plasma temperature and density conditions. The data has been unified according to non-linear theoretical temperature and density variation of the electron saturated probe current collection theory and used as a model for the electron collection at EMU surfaces. Vulnerable paths through the EMU connecting through the crewman s body have been identified along with electrical impedance of the exposed body parts. The body impedance information is merged with the electron collection characteristics in circuit simulation software (SPICE). The assessment shows that currents can be on the order of 20 mA for a 15 V exposure and of order 4 mA at 3V. These currents formally violate NASA protocol for electric current exposures however the human factors associated with subjective consequences of noxious stimuli from low voltage exposure during the stressful conditions of EVA are an area of active inquiry.

Electron Profile Stiffness and Critical Gradient Length Studies in the Alcator C-Mod Tokamak

NASA Astrophysics Data System (ADS)

Houshmandyar, Saeid; Hatch, David R.; Liao, Kenneth T.; Zhao, Bingzhe; Phillips, Perry E.; Rowan, William L.; Cao, Norman; Ernst, Darin R.; Rice, John E.

2017-10-01

Electron temperature profile stiffness was investigated at Alcator C-Mod L-mode discharges. Electrons were heated by ion cyclotron range of frequencies (ICRF) through minority heating. The intent of the heating mechanism was to vary the heat flux and simultaneously, gradually change the local gradient. The electron temperature gradient scale length (LTe- 1 = | ∇Te |/Te) was accurately measured through a novel technique, using the high-resolution radiometer ECE diagnostic. The TRANSP power balance analysis (Q/QGB) and the measured scale length (a/LTe) result in critical scale length measurements at all major radius locations. These measurements suggest that the profiles are already at the critical values. Furthermore, the dependence of the stiffness on plasma rotation and magnetic shear will be discussed. In order to understand the underlying mechanism of turbulence for these discharges, simulations using the gyrokinetic code, GENE, were carried out. For linear runs at electron scales, it was found that the largest growth rates are very sensitive to a/LTe variation, which suggests the presence of ETG modes, while the sensitivity studies in the ion scales indicate ITG/TEM modes. Supported by USDoE awards DE-FG03-96ER54373 and DE-FC02-99ER54512.

Rare Earth Doped Yttrium Aluminum Garnet (YAG) Selective Emitters

NASA Technical Reports Server (NTRS)

Chubb, Donald L.; Pal, AnnaMarie T.; Patton, Martin O.; Jenkins, Phillip P.

1999-01-01

As a result of their electron structure, rare earth ions in crystals at high temperature emit radiation in several narrow bands rather than in a continuous blackbody manner. This study presents a spectral emittance model for films and cylinders of rare earth doped yttrium aluminum garnets. Good agreement between experimental and theoretical film spectral emittances was found for erbium and holmium aluminum garnets. Spectral emittances of films are sensitive to temperature differences across the film. For operating conditions of interest, the film emitter experiences a linear temperature variation whereas the cylinder emitter has a more advantageous uniform temperature. Emitter efficiency is also a sensitive function of temperature. For holminum aluminum garnet film the efficiency is 0.35 at 1446K but only 0.27 at 1270 K.

Using real-time electron microscopy to explore the effects of transition-metal composition on the local thermal stability in charged Li xNi yMn zCo 1-y-zO 2 cathode materials

DOE PAGES

Hwang, Sooyeon; Kim, Seung Min; Bak, Seong -Min; ...

2015-05-08

In this study, we use in-situ transmission electron microcopy (TEM) to investigate the thermal decomposition that occurs at the surface of charged Li xNi yMn zCo 1-y-zO 2 (NMC) cathode materials of different composition (with y, z=0.8, 0.1 and 0.6, 0.2 and 0.4, 0.3), after they have been charged to their practical upper limit voltage (4.3V). By heating these materials inside the TEM, we are able to directly characterize near surface changes in both their electronic structure (using electron energy loss spectroscopy) and crystal structure and morphology (using electron diffraction and bright-field imaging). The most Ni-rich material (y, z =more » 0.8, 0.1) is found to be thermally unstable at significantly lower temperatures than the other compositions – this is manifested by changes in both the electronic structure and the onset of phase transitions at temperatures as low as 100°C. Electron energy loss spectroscopy indicates that the thermally induced reduction of Ni ions drives these changes, and that this is exacerbated by the presence of an additional redox reaction that occurs at 4.2V in the y, z = 0.8, 0.1 material. Exploration of individual particles shows that there are substantial variations in the onset temperatures and overall extent of these changes. Of the compositions studied, the composition of y, z = 0.6, 0.2 has the optimal combination of high energy density and reasonable thermal stability. The observations herein demonstrate that real time electron microscopy provide direct insight into the changes that occur in cathode materials with temperature, allowing optimization of different alloy concentrations to maximize overall performance.« less

Dry, portable calorimeter for nondestructive measurement of the activity of nuclear fuel

DOEpatents

Beyer, Norman S.; Lewis, Robert N.; Perry, Ronald B.

1976-01-01

The activity of a quantity of heat-producing nuclear fuel is measured rapidly, accurately and nondestructively by a portable dry calorimeter comprising a preheater, an array of temperature-controlled structures comprising a thermally guarded temperature-controlled oven, and a calculation and control unit. The difference between the amounts of electric power required to maintain the oven temperature with and without nuclear fuel in the oven is measured to determine the power produced by radioactive disintegration and hence the activity of the fuel. A portion of the electronic control system is designed to terminate a continuing sequence of measurements when the standard deviation of the variations of the amount of electric power required to maintain oven temperature is within a predetermined value.

Temperature dependent DC characterization of InAlN/(AlN)/GaN HEMT for improved reliability

NASA Astrophysics Data System (ADS)

Takhar, K.; Gomes, U. P.; Ranjan, K.; Rathi, S.; Biswas, D.

2015-02-01

InxAl1-xN/AlN/GaN HEMT device performance is analysed at various temperatures with the help of physics based 2-D simulation using commercially available BLAZE and GIGA modules from SILVACO. Various material parameters viz. band-gap, low field mobility, density of states, velocity saturation, and substrate thermal conductivity are considered as critical parameters for predicting temperature effect in InxAl1-xN/AlN/GaN HEMT. Reduction in drain current and transconductance has been observed due to the decrease of 2-DEG mobility and effective electron velocity with the increase in temperature. Degradation in cut-off frequency follows the transconductance profile as variation in gate-source/gate-drain capacitances observed very small.

Temperature and hydrostatic pressure effects on single dopant states in hollow cylindrical core-shell quantum dot

NASA Astrophysics Data System (ADS)

El-Yadri, M.; Aghoutane, N.; El Aouami, A.; Feddi, E.; Dujardin, F.; Duque, C. A.

2018-05-01

This work reports on theoretical investigation of the temperature and hydrostatic pressure effects on the confined donor impurity in a AlGaAs-GaAs hollow cylindrical core-shell quantum dot. The charges are assumed to be completely confined to the interior of the shell with approximately rigid walls. Within the framework of the effective-mass approximation and by using a variational approach, we have computed the donor binding energies as a function of the shell size in order to study the behavior of the electron-impurity attraction for a very small thickness under the influence of both temperature and hydrostatic pressure. Our results show that the temperature and hydrostatic pressure have a significant influence on the impurity binding energy for large shell quantum dots. It will be shown that the binding energy is more pronounced with increasing pressure and decreasing temperature for any impurity position and quantum dot size. The photoionization cross section is also analyzed by considering only the in-plane incident radiation polarization. Its behavior is investigated as a function of photon energy for different values of pressure and temperature. The opposite effects caused by temperature and hydrostatic pressure reveal a big practical interest and offer an alternative way to tuning of correlated electron-impurity transitions in optoelectronic devices.

Local-structure change rendered by electronic localization-delocalization transition in cerium-based metallic glasses

NASA Astrophysics Data System (ADS)

Luo, Qiang; Schwarz, Björn; Swarbrick, Janine C.; Bednarčik, Jozef; Zhu, Yingcai; Tang, Meibo; Zheng, Lirong; Li, Ran; Shen, Jun; Eckert, Jürgen

2018-02-01

With increasing temperature, metallic glasses (MGs) undergo first glass transition without pronounced structural change and then crystallization with distinct variation in structure and properties. The present study shows a structural change of short-range order induced by an electron-delocalization transition, along with an unusual large-volume shrinkage in Ce-based MGs. An f -electron localization-delocalization transition with thermal hysteresis is observed from the temperature dependence of x-ray absorption spectroscopy and resonant inelastic x-ray scattering spectra, indicating an inheritance of the 4 f configuration of pure Ce. However, the delocalization transition becomes broadened due to the local structural heterogeneity and related fluctuation of 4 f levels in the Ce-based MGs. The amorphous structure regulated 4 f delocalization of Ce leads to bond shortening and abnormal structure change of the topological and chemical short-range orders. Due to the hierarchical bonding nature, the structure should change in a similar manner on different length scales (but not isostructurally like the Ce metal) in Ce-based MGs.

Nanotwinning and structural phase transition in CdS quantum dots

NASA Astrophysics Data System (ADS)

Kumar, Pragati; Saxena, Nupur; Chandra, Ramesh; Gupta, Vinay; Agarwal, Avinash; Kanjilal, Dinakar

2012-10-01

Nanotwin structures are observed in high-resolution transmission electron microscopy studies of cubic phase CdS quantum dots in powder form by chemical co-precipitation method. The deposition of thin films of nanocrystalline CdS is carried out on silicon, glass, and TEM grids keeping the substrates at room temperature (RT) and 200°C by pulsed laser ablation. These films are then subjected to thermal annealing at different temperatures. Glancing angle X-ray diffraction results confirm structural phase transitions after thermal annealing of films deposited at RT and 200°C. The variation of average particle size and ratio of intensities in Raman peaks I 2LO/ I 1LO with annealing temperature are studied. It is found that electron-phonon interaction is a function of temperature and particle size and is independent of the structure. Besides Raman modes LO, 2LO and 3LO of CdS at approximately 302, 603, and 903 cm-1 respectively, two extra Raman modes at approximately 390 and 690 cm-1 are studied for the first time. The green and orange emissions observed in photoluminescence are correlated with phase transition.

Nanotwinning and structural phase transition in CdS quantum dots.

PubMed

Kumar, Pragati; Saxena, Nupur; Chandra, Ramesh; Gupta, Vinay; Agarwal, Avinash; Kanjilal, Dinakar

2012-10-23

Nanotwin structures are observed in high-resolution transmission electron microscopy studies of cubic phase CdS quantum dots in powder form by chemical co-precipitation method. The deposition of thin films of nanocrystalline CdS is carried out on silicon, glass, and TEM grids keeping the substrates at room temperature (RT) and 200°C by pulsed laser ablation. These films are then subjected to thermal annealing at different temperatures. Glancing angle X-ray diffraction results confirm structural phase transitions after thermal annealing of films deposited at RT and 200°C. The variation of average particle size and ratio of intensities in Raman peaks I2LO/I1LO with annealing temperature are studied. It is found that electron-phonon interaction is a function of temperature and particle size and is independent of the structure. Besides Raman modes LO, 2LO and 3LO of CdS at approximately 302, 603, and 903 cm-1 respectively, two extra Raman modes at approximately 390 and 690 cm-1 are studied for the first time. The green and orange emissions observed in photoluminescence are correlated with phase transition.

Wireless monitoring of highways

NASA Astrophysics Data System (ADS)

Bennett, Richard; Hayes-Gill, Barrie; Crowe, John A.; Armitage, Robert; Rodgers, Dale; Hendroff, Adrian

1999-05-01

Electronic hardware has been developed to telemetrically transmit temperature and strain measurements from within a public highway in the UK. These measurements provide an important health check for monitoring fatigue damage in pavements. Previous attempts at measuring strain and temperature have required lengths of cable to be installed in the highway. The installation of these cables is both expensive and damaging to the pavement and provides potentially unreliable electrical connections. The new systems consist of a retrofitted instrumented asphalt core which is bonded into the pavement structure. The core contains all the electronics necessary to record two temperatures and two strains. An analogue front end provides signal conditioning which is digitized and passed to microcontroller for endcoding. From there the data is transmitted via a low power radio link to a receiver and data logger positioned by the side of the road. The system has an in-situ operating life of 6 months on AA alkaline batteries. Results are presented of power management and fault tolerant radio protocol techniques, long term temperature variations, dynamic strain measurements within the highway, and RF transmission capabilities through a layer of asphalt.

Changes in divertor conditions in response to changing core density with RMPs

DOE PAGES

Briesemeister, Alexis R.; Ahn, Joon -Wook; Canik, John M.; ...

2017-06-07

The effects of changes in core density on divertor electron temperature, density and heat flux when resonant magnetic perturbations (RMPs) are applied are presented, notably a reduction in RMP induced secondary radial peaks in the electron temperature profile at the target plate is observed when the core density is increased, which is consistent with modeling. RMPs is used here to indicated non-axisymmetric magnetic field perturbations, created using in-vessel control coils, which have components which has at least one but typically many resonances with the rotational transform of the plasma. RMPs are found to alter inter-ELM heat flux to the divertormore » by modifying the core plasma density. It is shown that applying RMPs reduces the core density and increases the inter-ELM heat flux to both the inner and outer targets. Using gas puffing to return the core density to the pre-RMP levels more than eliminates the increase in inter-ELM heat flux, but a broadening of the heat flux to the outer target remains. These measurements were made at a single toroidal location, but the peak in the heat flux profile was found near the outer strike point where simulations indicate little toroidal variation should exist and tangentially viewing diagnostics showed no evidence of strong asymmetries. In experiments where divertor Thomson scattering measurements were available it is shown that, local secondary peaks in the divertor electron temperature profile near the target plate are reduced as the core density is increased, while peaks in the divertor electron density profile near the target are increased. Furthermore, these trends observed in the divertor electron temperature and density are qualitatively reproduced by scanning the upstream density in EMC3-Eirene modeling. Measurements are presented showing that higher densities are needed to induce detachment of the outer strike point in a case where an increase in electron temperature, likely due to a change in MHD activity, is seen after RMPs are applied.« less

Changes in divertor conditions in response to changing core density with RMPs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Briesemeister, Alexis R.; Ahn, Joon -Wook; Canik, John M.

The effects of changes in core density on divertor electron temperature, density and heat flux when resonant magnetic perturbations (RMPs) are applied are presented, notably a reduction in RMP induced secondary radial peaks in the electron temperature profile at the target plate is observed when the core density is increased, which is consistent with modeling. RMPs is used here to indicated non-axisymmetric magnetic field perturbations, created using in-vessel control coils, which have components which has at least one but typically many resonances with the rotational transform of the plasma. RMPs are found to alter inter-ELM heat flux to the divertormore » by modifying the core plasma density. It is shown that applying RMPs reduces the core density and increases the inter-ELM heat flux to both the inner and outer targets. Using gas puffing to return the core density to the pre-RMP levels more than eliminates the increase in inter-ELM heat flux, but a broadening of the heat flux to the outer target remains. These measurements were made at a single toroidal location, but the peak in the heat flux profile was found near the outer strike point where simulations indicate little toroidal variation should exist and tangentially viewing diagnostics showed no evidence of strong asymmetries. In experiments where divertor Thomson scattering measurements were available it is shown that, local secondary peaks in the divertor electron temperature profile near the target plate are reduced as the core density is increased, while peaks in the divertor electron density profile near the target are increased. Furthermore, these trends observed in the divertor electron temperature and density are qualitatively reproduced by scanning the upstream density in EMC3-Eirene modeling. Measurements are presented showing that higher densities are needed to induce detachment of the outer strike point in a case where an increase in electron temperature, likely due to a change in MHD activity, is seen after RMPs are applied.« less

Structural, magnetic, optical, dielectric, electrical and modulus spectroscopic characteristics of ZnFe2O4 spinel ferrite nanoparticles synthesized via honey-mediated sol-gel combustion method

NASA Astrophysics Data System (ADS)

Yadav, Raghvendra Singh; Kuřitka, Ivo; Vilcakova, Jarmila; Urbánek, Pavel; Machovsky, Michal; Masař, Milan; Holek, Martin

2017-11-01

This paper reports a honey-mediated green synthesis of ZnFe2O4 spinel ferrite nanoparticles and the effect of further annealing on structural, magnetic, optical, dielectric and electrical properties. X-ray diffraction study confirmed the well formation of ZnFe2O4 spinel ferrite crystal structure. Raman and Fourier transform infrared spectroscopy confirmed the formation of spinel ferrite crystal structure. The scanning electron microscopy study revealed the formation of spherical morphology at lower annealing temperature with achieved particle size 30-60 nm, whereas, octahedral like morphology at higher annealing temperature with particle size 50-400 nm. Magnetization measurements were carried out using a vibrating sample magnetometer at room temperature. The estimated magnetic parameter such as saturation magnetization (Ms), remanence (Mr) and coercivity (Hc) showed variation in value with nano-crystallite size. The highest saturation magnetization (Ms) was 12.81 emu/g for as-synthesized ZnFe2O4 spinel ferrite nanoparticles, whereas, highest coercivity (Hc) was 25.77 Oe for ZnFe2O4 nanoparticles annealed at high temperature 1000 °C. UV-Visible reflectance spectroscopy showed the band gap variation from 1.90 eV to 2.14 eV with the increase of annealing temperature. The dielectric constant and dielectric loss were decreased with frequency showing the normal behavior of spinel ferrites. The variation in conductivity is explained in terms of the variation in microstructure and variation in the mobility of charge carriers associated with the cation redistribution induced by annealing or grain size. The modulus and impedance spectroscopy study revealed the influence of bulk grain and the grain boundary on the electrical resistance and capacitance of ZnFe2O4 nanoparticles. The results presented in this work are helpful for green synthesis of well-controlled size, morphology and physical properties of ZnFe2O4 nanoparticles.

Isotropic in-plane quenched disorder and dilution induce a robust nematic state in electron-doped pnictides

DOE PAGES

Liang, Shuhua; Bishop, Christopher B.; Moreo, Adriana; ...

2015-09-21

The phase diagram of electron-doped pnictides is studied varying the temperature, electronic density, and isotropic in-plane quenched disorder strength and dilution by means of computational techniques applied to a three-orbital (xz,yz,xy) spin-fermion model with lattice degrees of freedom. In experiments, chemical doping introduces disorder but in theoretical studies the relationship between electronic doping and the randomly located dopants, with their associated quenched disorder, is difficult to address. Moreover, in this publication, the use of computational techniques allows us to study independently the effects of electronic doping, regulated by a global chemical potential, and impurity disorder at randomly selected sites. Surprisingly,more » our Monte Carlo simulations reveal that the fast reduction with doping of the N eel T N and the structural T S transition temperatures, and the concomitant stabilization of a robust nematic state, is primarily controlled in our model by the magnetic dilution associated with the in-plane isotropic disorder introduced by Fe substitution. In the doping range studied, changes in the Fermi surface produced by electron doping affect only slightly both critical temperatures. Our results also suggest that the specific material-dependent phase diagrams experimentally observed could be explained as a consequence of the variation in disorder profiles introduced by the different dopants. Finally, our findings are also compatible with neutron scattering and scanning tunneling microscopy, unveiling a patchy network of locally magnetically ordered clusters with anisotropic shapes, even though the quenched disorder is locally isotropic. Our study reveals a remarkable and unexpected degree of complexity in pnictides: the fragile tendency to nematicity intrinsic of translational invariant electronic systems needs to be supplemented by quenched disorder and dilution to stabilize the robust nematic phase experimentally found in electron-doped 122 compounds.« less

Isotropic in-plane quenched disorder and dilution induce a robust nematic state in electron-doped pnictides

NASA Astrophysics Data System (ADS)

Liang, Shuhua; Bishop, Christopher B.; Moreo, Adriana; Dagotto, Elbio

2015-09-01

The phase diagram of electron-doped pnictides is studied varying the temperature, electronic density, and isotropic in-plane quenched disorder strength and dilution by means of computational techniques applied to a three-orbital (x z ,y z ,x y ) spin-fermion model with lattice degrees of freedom. In experiments, chemical doping introduces disorder but in theoretical studies the relationship between electronic doping and the randomly located dopants, with their associated quenched disorder, is difficult to address. In this publication, the use of computational techniques allows us to study independently the effects of electronic doping, regulated by a global chemical potential, and impurity disorder at randomly selected sites. Surprisingly, our Monte Carlo simulations reveal that the fast reduction with doping of the Néel TN and the structural TS transition temperatures, and the concomitant stabilization of a robust nematic state, is primarily controlled in our model by the magnetic dilution associated with the in-plane isotropic disorder introduced by Fe substitution. In the doping range studied, changes in the Fermi surface produced by electron doping affect only slightly both critical temperatures. Our results also suggest that the specific material-dependent phase diagrams experimentally observed could be explained as a consequence of the variation in disorder profiles introduced by the different dopants. Our findings are also compatible with neutron scattering and scanning tunneling microscopy, unveiling a patchy network of locally magnetically ordered clusters with anisotropic shapes, even though the quenched disorder is locally isotropic. This study reveals a remarkable and unexpected degree of complexity in pnictides: the fragile tendency to nematicity intrinsic of translational invariant electronic systems needs to be supplemented by quenched disorder and dilution to stabilize the robust nematic phase experimentally found in electron-doped 122 compounds.

Fatigue behavior of ULTIMETRTM alloy: Experiment and theoretical modeling

NASA Astrophysics Data System (ADS)

Jiang, Liang

ULTIMETRTM alloy is a commercial Co-26Cr-9Ni (weight percent) superalloy, which possesses excellent resistance to both wear and corrosion. In order to extend the structural applications of this alloy and improve the fundamental understanding of the fatigue damage mechanisms, stress- and strain-controlled fatigue tests were performed at various temperatures and in different environments. The stress- and strain-life data were developed for the structural design and engineering applications of this material. Fractographic studies characterized the crack-initiation and propagation behavior of the alloy. Microstructure evolution during fatigue was revealed by x-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Specifically, it was found that the metastable face-centered-cubic structure of this alloy in the as-received condition could be transformed into a hexagonal-close-packed structure either under the action of plastic deformation at room temperature, or due to the aging and cyclic deformation at intermediate temperatures. This interesting observation constructed a sound basis for the alloy development. The dominant mechanisms, which control the fatigue behavior of ULTIMET alloy, were characterized. High-speed, high-resolution infrared (IR) thermography, as a non-contact, full-field, and nondestructive technique, was used to characterize the damage during fatigue. The temperature variations during each fatigue cycle, which were due to the thermal-elastic-plastic effect, were observed and related to stress-strain analyses. The temperature evolution during fatigue manifested the cumulative fatigue damage process. A constitutive model was developed to predict thermal and mechanical responses of ULTIMET alloy subjected to cyclic deformation. The predicted cyclic stress-strain responses and temperature variations were found to be in good agreement with the experimental results. In addition, a fatigue life prediction model was developed based on the strain-energy consideration, and the measured temperature could be utilized as an index for fatigue-life prediction.

Grain boundary-dominated electrical conduction and anomalous optical-phonon behaviour near the Neel temperature in YFeO3 ceramics

NASA Astrophysics Data System (ADS)

Raut, Subhajit; Babu, P. D.; Sharma, R. K.; Pattanayak, Ranjit; Panigrahi, Simanchalo

2018-05-01

We investigated the anomalous behaviour in the dielectric properties, occurring nearly at room temperature and at elevated temperatures (near the Neel temperature TN) of the polycrystalline samples of YFeO3 (YFO) ceramics. On the prepared YFO ceramics, the magnetic measurements showed the Neel temperature of YFO to be 650 K, below which the compound exhibited the weak ferromagnetic behaviour. X-ray photoelectron spectroscopy (XPS) shows the presence of Fe ions (Fe2+ and Fe3+ states) and also revealed the formation of the oxygen vacancies. The frequency dependence of the complex dielectric constant within the frequency domain of 100 Hz-1 MHz shows the presence of grain dominated dielectric relaxation over the thermal window of 300-373 K. The activation energy Eact.ɛ=0.611 eV extracted from the imaginary permittivity spectrum indicates the involvement of oxygen vacancies in the relaxation process. Above 493 K, the ac conductivity, complex impedance, and modulus studies revealed appreciable conduction and relaxation processes occurring in YFO ceramics with respective activation energies Eac t . σ=1.362 eV and Eac t . Z=1.345 eV , which suggests that the oxygen vacancies are also involved for the anomalous behaviour of the dielectric constant at elevated temperatures. The temperature dependent Raman spectroscopic measurements within the thermal window of 298-698 K showed anomalous variations of the line widths and frequencies of several Raman active modes above 473 K up to the vicinity of TN pointing towards the presence of admixtures of the electron-phonon and spin-phonon coupling in the system. A further study on the thermal variation of the B2g(4) mode frequency with [M(T)/MS]2 shows the occurrence of strong spin-phonon (s-p) coupling, while the line shape shows the presence of the Fano asymmetry, suggesting spin dependent electron-phonon (e-p) coupling in the system below TN.

Nanometre-scale thermometry in a living cell

NASA Astrophysics Data System (ADS)

Kucsko, G.; Maurer, P. C.; Yao, N. Y.; Kubo, M.; Noh, H. J.; Lo, P. K.; Park, H.; Lukin, M. D.

2013-08-01

Sensitive probing of temperature variations on nanometre scales is an outstanding challenge in many areas of modern science and technology. In particular, a thermometer capable of subdegree temperature resolution over a large range of temperatures as well as integration within a living system could provide a powerful new tool in many areas of biological, physical and chemical research. Possibilities range from the temperature-induced control of gene expression and tumour metabolism to the cell-selective treatment of disease and the study of heat dissipation in integrated circuits. By combining local light-induced heat sources with sensitive nanoscale thermometry, it may also be possible to engineer biological processes at the subcellular level. Here we demonstrate a new approach to nanoscale thermometry that uses coherent manipulation of the electronic spin associated with nitrogen-vacancy colour centres in diamond. Our technique makes it possible to detect temperature variations as small as 1.8 mK (a sensitivity of 9 mK Hz-1/2) in an ultrapure bulk diamond sample. Using nitrogen-vacancy centres in diamond nanocrystals (nanodiamonds), we directly measure the local thermal environment on length scales as short as 200 nanometres. Finally, by introducing both nanodiamonds and gold nanoparticles into a single human embryonic fibroblast, we demonstrate temperature-gradient control and mapping at the subcellular level, enabling unique potential applications in life sciences.

An acoustic thermometer for air refractive index estimation in long distance interferometric measurements

NASA Astrophysics Data System (ADS)

Pisani, Marco; Astrua, Milena; Zucco, Massimo

2018-02-01

We present a method to measure the temperature along the path of an optical interferometer based on the propagation of acoustic waves. It exploits the high sensitivity of the speed of sound to air temperature. In particular, it takes advantage of a technique where the generation of acoustic waves is synchronous with the amplitude modulation of a laser source. A photodetector converts the laser light into an electronic signal used as a reference, while the incoming acoustic waves are focused on a microphone and generate the measuring signal. Under this condition, the phase difference between the two signals substantially depends on the temperature of the air volume interposed between the sources and the receivers. A comparison with traditional temperature sensors highlighted the limit of the latter in the case of fast temperature variations and the advantage of a measurement integrated along the optical path instead of a sampling measurement. The capability of the acoustic method to compensate for the interferometric distance measurements due to air temperature variations has been demonstrated to the level of 0.1 °C corresponding to 10-7 on the refractive index of air. We applied the method indoor for distances up to 27 m, outdoor at 78 m and finally tested the acoustic thermometer over a distance of 182 m.

Periodic Variations in Low-Latitudinal Ionosphere during Stratospheric Sudden Warming Event in 2016/2017 Winter

NASA Astrophysics Data System (ADS)

Liu, J.; Zhang, D.

2017-12-01

With datasets of electron density, neutral wind, ionosonde, neutral temperature, and geomagnetism, we studied the low-latitudinal ionosphere in East-Asia sector during Stratospheric Sudden Warming (SSW) Event in 2016/2017 winter, and some periodic variations in several parameters were revealed. A notable quasi-14.5-day (Q14.5D) period was detected in the strength and location of the northern equatorial ionospheric anomaly (EIA) crest shown with total electron content (TEC). As comparison, northern EIA crest in the American sector had similar characters. With data from Wuhan meteor radar and Yunnan MF radar, we found that, within altitude ranging from 80-100 km, wind field also showed above-mentioned periodic variation, which varied in different heights and stations. The Q14.5D period was also revealed in critical frequency (foF2) and peak altitude (hmF2) of F2 layer from two ionosonde stations in southern China. From electron density of Defense Meteorological Satellite Program (DMSP) and TEC of Metop-A, it was shown that this period component is also noticeable in the topside ionosphere above 800 km. However, this character is different in EEJ, of which the Morlet wavelet showed higher strength in quasi-7.5-day period compared to its Q14.5D component.

A wearable pressure sensor based on ultra-violet/ozone microstructured carbon nanotube/polydimethylsiloxane arrays for electronic skins.

PubMed

Yu, Guohui; Hu, Jingdong; Tan, Jianping; Gao, Yang; Lu, Yongfeng; Xuan, Fuzhen

2018-03-16

Pressure sensors with high performance (e.g., a broad pressure sensing range, high sensitivities, rapid response/relaxation speeds, temperature-stable sensing), as well as a cost-effective and highly efficient fabrication method are highly desired for electronic skins. In this research, a high-performance pressure sensor based on microstructured carbon nanotube/polydimethylsiloxane arrays was fabricated using an ultra-violet/ozone (UV/O 3 ) microengineering technique. The UV/O 3 microengineering technique is controllable, cost-effective, and highly efficient since it is conducted at room temperature in an ambient environment. The pressure sensor offers a broad pressure sensing range (7 Pa-50 kPa), a sensitivity of ∼ -0.101 ± 0.005 kPa -1 (<1 kPa), a fast response/relaxation speed of ∼10 ms, a small dependence on temperature variation, and a good cycling stability (>5000 cycles), which is attributed to the UV/O 3 engineered microstructures that amplify and transfer external applied forces and rapidly store/release the energy during the PDMS deformation. The sensors developed show the capability to detect external forces and monitor human health conditions, promising for the potential applications in electronic skin.

A wearable pressure sensor based on ultra-violet/ozone microstructured carbon nanotube/polydimethylsiloxane arrays for electronic skins

NASA Astrophysics Data System (ADS)

Yu, Guohui; Hu, Jingdong; Tan, Jianping; Gao, Yang; Lu, Yongfeng; Xuan, Fuzhen

2018-03-01

Pressure sensors with high performance (e.g., a broad pressure sensing range, high sensitivities, rapid response/relaxation speeds, temperature-stable sensing), as well as a cost-effective and highly efficient fabrication method are highly desired for electronic skins. In this research, a high-performance pressure sensor based on microstructured carbon nanotube/polydimethylsiloxane arrays was fabricated using an ultra-violet/ozone (UV/O3) microengineering technique. The UV/O3 microengineering technique is controllable, cost-effective, and highly efficient since it is conducted at room temperature in an ambient environment. The pressure sensor offers a broad pressure sensing range (7 Pa-50 kPa), a sensitivity of ˜ -0.101 ± 0.005 kPa-1 (<1 kPa), a fast response/relaxation speed of ˜10 ms, a small dependence on temperature variation, and a good cycling stability (>5000 cycles), which is attributed to the UV/O3 engineered microstructures that amplify and transfer external applied forces and rapidly store/release the energy during the PDMS deformation. The sensors developed show the capability to detect external forces and monitor human health conditions, promising for the potential applications in electronic skin.

The role of metabolism in understanding the altitudinal segregation pattern of two potentially interacting lizards.

PubMed

Žagar, Anamarija; Simčič, Tatjana; Carretero, Miguel A; Vrezec, Al

2015-01-01

Sympatric species from the same ecological guild, that exhibit partial altitudinal segregation, can potentially interact in areas of syntopic occurrence. Besides general species' ecology, physiology can provide important answers about species interactions reflected in altitudinal patterns. Lizards Podarcis muralis and Iberolacerta horvathi exhibit partial altitudinal segregation, while they strongly resemble in overall morphology and ecology (diet, daily and seasonal activity pattern), but show certain degree of physiological dissimilarity. They have similar mean preferred body temperatures and patterns of seasonal and daily variations but differ in the magnitude of seasonal variation. Since an ectotherm metabolism is highly dependent on body temperature, thermoregulation is expected to directly affect their metabolism. We compared metabolic rates of adult males from an area of sympatry, measured under two temperature regimes (20°C and 28°C). Both species increased metabolic rates with temperature in a similar pattern. We also compared electron transport activity from tail tissues which provide values of species' potential metabolic activity (enzymatic capacity). Species clearly differed in potential metabolic activity; I. horvathi attained higher values than P. muralis. No difference was detected in how species exploited this potential (calculated from the ratio of electron transport activity and metabolic rates). However, we observed higher potential metabolic activity I. horvathi which together with the ability to thermoregulate more precisely could represent a higher competitive advantage over P. muralis in thermally more restrictive environments such as higher altitudes. Understanding of metabolism seems to provide valuable information for understanding recent distributional patterns as well as species interactions. Copyright © 2014 Elsevier Inc. All rights reserved.

1/f noise in titanium doped aluminum thin film deposited by electron beam evaporation method and its dependence on structural variation with temperature

NASA Astrophysics Data System (ADS)

Ananda, P.; Vedanayakam, S. Victor; Thyagarajan, K.; Nandakumar, N.

2018-05-01

A brief review of Titanium doped Aluminum film has many attractive properties such as thermal properties and 1/f noise is highlighted. The thin film devices of Titanium doped alluminium are specially used in aerospace technology, automotive, biomedical fields also in microelectronics. In this paper, we discus on 1/f noise and nonlinear effects in titanium doped alluminium thin films deposited on glass substrate using electron beam evaporation for different current densities on varying temperatures of the film. The plots are dawn for 1/f noise of the films at different temperatures ranging from 300°C to 450°C and the slopes are determined. The studies shows a higher order increment in FFT amplitude of low frequency 1/f noise in thin films at annealing temperature 400°C. In this technology used in aerospace has been the major field of application of titanium doped alluminium, being one of the major challenges of the development of new alloys with improved strength at high temperature, wide chord Titanium doped alluminium fan blades increases the efficiency while reducing 1/f noise. Structural properties of XRD is identified.

On the nature of S II emission from Jupiter's hot plasma torus

NASA Technical Reports Server (NTRS)

Brown, R. A.; Shemansky, D. E.

1982-01-01

An effective electron temperature T(e) of 80,000 K is indicated by the Voyager 1 encounter Jupiter hot torus emission rates in the 6731, 1256, 911 and reclassified 765 A transitions of S II. A set of 53 measurements of the S II red line doublet obtained at 5.9 Jupiter radii shows strong, irregular fluctuations in intensity, but no variation in the line ratio. At this distance from Jupiter, the torus is found to be longitudinally uniform in density; this is consonant with Voyager UVS findings, but contrary to magnetic anomaly model predictions. It is suggested that presently unidentified ion-ion and/or iron-atom reactions are responsible for the S II component irregular variations, in view of the fact that electron properties are regular and variable only over a small range in the hot torus at 5.9 Jupiter radii.

High concentration effects of neutral-potential-well interface traps on recombination dc current-voltage lineshape in metal-oxide-silicon transistors

NASA Astrophysics Data System (ADS)

Chen, Zuhui; Jie, Bin B.; Sah, Chih-Tang

2008-11-01

Steady-state Shockley-Read-Hall kinetics is employed to explore the high concentration effect of neutral-potential-well interface traps on the electron-hole recombination direct-current current-voltage (R-DCIV) properties in metal-oxide-silicon field-effect transistors. Extensive calculations include device parameter variations in neutral-trapping-potential-well electron interface-trap density NET (charge states 0 and -1), dopant impurity concentration PIM, oxide thickness Xox, forward source/drain junction bias VPN, and transistor temperature T. It shows significant distortion of the R-DCIV lineshape by the high concentrations of the interface traps. The result suggests that the lineshape distortion observed in past experiments, previously attributed to spatial variation in surface impurity concentration and energy distribution of interface traps in the silicon energy gap, can also arise from interface-trap concentration along surface channel region.

Silicon Germanium Quantum Well Thermoelectrics

NASA Astrophysics Data System (ADS)

Davidson, Anthony Lee, III

Today's growing energy demands require new technologies to provide high efficiency clean energy. Thermoelectrics that convert heat to electrical energy directly can provide a method for the automobile industry to recover waste heat to power vehicle electronics, hence improving fuel economy. If large enough efficiencies can be obtained then the internal combustion engine could even be replaced. Exhaust temperature for automotive application range from 400 to 800 K. In this temperature range the current state of the art materials are bulk Si1-xGex alloys. By alternating layers of Si and Si1-xGex alloy device performance may be enhanced through quantum well effects and variations in material thermal properties. In this study, superlattices designed for in-plane operation with varying period and crystallinity are examined to determine the effect on electrical and thermal properties. In-plane electrical resistivity of these materials was found to be below the bulk material at a similar doping at room temperature, confirming the role of quantum wells in electron transport. As period is reduced in the structures boundary scattering limits electron propagation leading to increased resistivity. The Seebeck coefficient measured at room temperature is higher than the bulk material, additionally lending proof to the effects of quantum wells. When examining cross-plane operation the low doping in the Si layers of the device produce high resistivity resulting from boundary scattering. Thermal conductivity was measured from 77 K up to 674 K and shows little variation due to periodicity and temperature, however an order of magnitude reduction over bulk Si1-xGex is shown in all samples. A model is developed that suggests a combination of phonon dispersion effects and strong boundary scattering. Further study of the phonon dispersion effects was achieved through the examination of the heat capacity by combining thermal diffusivity with thermal conductivity. All superlattices show a reduction in heat capacity when compared to Si, suggesting the importance of phonon dispersion effects due to the periodicity. The Debye model does not provide agreement with this result due to the inadequate treatment of optical phonons. Overall the results show that the design of the superlattice structures results in a thermoelectric that has improved efficiency at room temperature to the state of the art materials with the promise of increased efficiency at higher temperatures.

Remote sensor response study in the regime of the microwave radiation-induced magnetoresistance oscillations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ye, Tianyu; Mani, R. G.; Wegscheider, W.

2013-11-04

A concurrent remote sensing and magneto-transport study of the microwave excited two dimensional electron system (2DES) at liquid helium temperatures has been carried out using a carbon detector to remotely sense the microwave activity of the 2D electron system in the GaAs/AlGaAs heterostructure during conventional magneto-transport measurements. Various correlations are observed and reported between the oscillatory magnetotransport and the remotely sensed reflection. In addition, the oscillatory remotely sensed signal is shown to exhibit a power law type variation in its amplitude, similar to the radiation-induced magnetoresistance oscillations.

SnS thin films deposited by chemical bath deposition, dip coating and SILAR techniques

NASA Astrophysics Data System (ADS)

Chaki, Sunil H.; Chaudhary, Mahesh D.; Deshpande, M. P.

2016-05-01

The SnS thin films were synthesized by chemical bath deposition (CBD), dip coating and successive ionic layer adsorption and reaction (SILAR) techniques. In them, the CBD thin films were deposited at two temperatures: ambient and 70 °C. The energy dispersive analysis of X-rays (EDAX), X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and optical spectroscopy techniques were used to characterize the thin films. The electrical transport properties studies on the as-deposited thin films were done by measuring the I-V characteristics, DC electrical resistivity variation with temperature and the room temperature Hall effect. The obtained results are deliberated in this paper.

Determination of dosimetric and kinetic features of gamma irradiated solid calcium ascorbate dihydrate using ESR spectroscopy

NASA Astrophysics Data System (ADS)

Tuner, H.

2013-01-01

Effects of gamma radiation on solid calcium ascorbate dihydrate were studied using electron spin resonance (ESR) spectroscopy. Irradiated samples were found to present two specific ESR lines with shoulder at low and high magnetic field sides. Structural and kinetic features of the radicalic species responsible for experimental ESR spectrum were explored through the variations of the signal intensities with applied microwave power, variable temperature, high-temperature annealing and room temperature storage time studies. Dosimetric potential of the sample was also determined using spectrum area and measured signal intensity measurements. It was concluded that three radicals with different spectroscopic and kinetic features were produced upon gamma irradiation.

Safety devices for neonatal intensive care.

PubMed

Neuman, M R; Flammer, C M; O'Connor, E

1982-01-01

Three relatively simple devices for improving safety in neonatal intensive care are described. When umbilical artery catheters are used, an inexpensive pressure switch is utilized to detect abnormally low pressures associated with catheter withdrawal or excessive fluid leakage from the catheter system. A capacitive, intravenous-line air bubble detector, consisting of a section of the intravenous line as the dielectric of a capacitor, is used to alert the clinical staff when air bubbles pass between the capacitor plates. An electronic temperature controller maintains the temperature of neonatal breathing gases to avoid temperature variations which occur with presently used techniques. These are relatively simple and inexpensive devices which can be fabricated by most hospital clinical engineering services.

Disorder induced magnetism and electrical conduction in La doped Ca2FeMoO6 double perovskite

NASA Astrophysics Data System (ADS)

Poddar, Asok; Bhowmik, R. N.; Muthuselvam, I. Panneer

2010-11-01

We report the magnetism and electrical transport properties of La doped Ca2FeMoO6 double perovskite. Reduction in magnetic moment, nonmonotonic variation in magnetic ordering temperature (TC), increasing magnetic hardness, low temperature resistivity upturn, and loss of metallic conductivity are some of the major changes that we observed due to La doping induced disorder in double perovskite structure. The increase in magnetic disorder in La doped samples and its effect on TC is more consistent with the mean field theory. The modification in electronic band structure due to La doping is understood by establishing a correlation between the temperature dependence of electrical conductivity and thermoelectric power.

Propagation of resist heating mask error to wafer level

NASA Astrophysics Data System (ADS)

Babin, S. V.; Karklin, Linard

2006-10-01

As technology is approaching 45 nm and below the IC industry is experiencing a severe product yield hit due to rapidly shrinking process windows and unavoidable manufacturing process variations. Current EDA tools are unable by their nature to deliver optimized and process-centered designs that call for 'post design' localized layout optimization DFM tools. To evaluate the impact of different manufacturing process variations on final product it is important to trace and evaluate all errors through design to manufacturing flow. Photo mask is one of the critical parts of this flow, and special attention should be paid to photo mask manufacturing process and especially to mask tight CD control. Electron beam lithography (EBL) is a major technique which is used for fabrication of high-end photo masks. During the writing process, resist heating is one of the sources for mask CD variations. Electron energy is released in the mask body mainly as heat, leading to significant temperature fluctuations in local areas. The temperature fluctuations cause changes in resist sensitivity, which in turn leads to CD variations. These CD variations depend on mask writing speed, order of exposure, pattern density and its distribution. Recent measurements revealed up to 45 nm CD variation on the mask when using ZEP resist. The resist heating problem with CAR resists is significantly smaller compared to other types of resists. This is partially due to higher resist sensitivity and the lower exposure dose required. However, there is no data yet showing CD errors on the wafer induced by CAR resist heating on the mask. This effect can be amplified by high MEEF values and should be carefully evaluated at 45nm and below technology nodes where tight CD control is required. In this paper, we simulated CD variation on the mask due to resist heating; then a mask pattern with the heating error was transferred onto the wafer. So, a CD error on the wafer was evaluated subject to only one term of the mask error budget - the resist heating CD error. In simulation of exposure using a stepper, variable MEEF was considered.

Electron heating in the exhaust of magnetic reconnection with negligible guide field

NASA Astrophysics Data System (ADS)

Wang, Shan; Chen, Li-Jen; Bessho, Naoki; Kistler, Lynn M.; Shuster, Jason R.; Guo, Ruilong

2016-03-01

Electron heating in the magnetic reconnection exhaust is investigated with particle-in-cell simulations, space observations, and theoretical analysis. Spatial variations of the electron temperature (Te) and associated velocity distribution functions (VDFs) are examined and understood in terms of particle energization and randomization processes that vary with exhaust locations. Inside the electron diffusion region (EDR), the electron temperature parallel to the magnetic field (Te∥) exhibits a local minimum and the perpendicular temperature (Te⊥) shows a maximum at the current sheet midplane. In the intermediate exhaust downstream from the EDR and far from the magnetic field pileup region, Te⊥/Te∥ is close to unity and Te is approximately uniform, but the VDFs are structured: close to the midplane, VDFs are quasi-isotropic, whereas farther away from the midplane, VDFs exhibit field-aligned beams directed toward the midplane. In the far exhaust, Te generally increases toward the midplane and the pileup region, and the corresponding VDFs show counter-streaming beams. A distinct population with low v∥ and high v⊥ is prominent in the VDFs around the midplane. Test particle results show that the magnetic curvature near the midplane produces pitch angle scattering to generate quasi-isotropic distributions in the intermediate exhaust. In the far exhaust, electrons with initial high v∥ (v⊥) are accelerated mainly through curvature (gradient-B) drift opposite to the electric field, without significant pitch angle scattering. The VDF structures predicted by simulations are observed in magnetotail reconnection measurements, indicating that the energization mechanisms captured in the reported simulations are applicable to magnetotail reconnection with negligible guide field.

Advanced spectroscopic analysis of 0.8-1.0-MA Mo x pinches and the influence of plasma electron beams on L-shell spectra of Mo ions.

PubMed

Shlyaptseva, A S; Hansen, S B; Kantsyrev, V L; Fedin, D A; Ouart, N; Fournier, K B; Safronova, U I

2003-02-01

This paper presents a detailed investigation of the temporal, spatial, and spectroscopic properties of L-shell radiation from 0.8 to 1.0 MA Mo x pinches. Time-resolved measurements of x-ray radiation and both time-gated and time-integrated spectra and pinhole images are presented and analyzed. High-current x pinches are found to have complex spatial and temporal structures. A collisional-radiative kinetic model has been developed and used to interpret L-shell Mo spectra. The model includes the ground state of every ionization stage of Mo and detailed structure for the O-, F-, Ne-, Na-, and Mg-like ionization stages. Hot electron beams generated by current-carrying electrons in the x pinch are modeled by a non-Maxwellian electron distribution function and have significant influence on L-shell spectra. The results of 20 Mo x-pinch shots with wire diameters from 24 to 62 microm have been modeled. Overall, the modeled spectra fit the experimental spectra well and indicate for time-integrated spectra electron densities between 2 x 10(21) and 2 x 10(22) cm(-3), electron temperatures between 700 and 850 eV, and hot electron fractions between 3% and 7%. Time-gated spectra exhibit wide variations in temperature and density of plasma hot spots during the same discharge.

Impact of structure and morphology of nanostructured ceria coating on AISI 304 oxidation kinetics

NASA Astrophysics Data System (ADS)

Aadhavan, R.; Suresh Babu, K.

2017-07-01

Nanostructured ceria-based coatings are shown to be protective against high-temperature oxidation of AISI 304 due to the dynamics of oxidation state and associated defects. However, the processing parameters of deposition have a strong influence in determining the structural and morphological aspects of ceria. The present work focuses on the effect of variation in substrate temperature (50-300 °C) and deposition rate (0.1-50 Å/s) of ceria in electron beam physical vapour evaporation method and correlates the changes in structure and morphology to high-temperature oxidation protection. Unlike deposition rate, substrate temperature exhibited a profound influence on crystallite size (7-18 nm) and oxygen vacancy concentration. Upon isothermal oxidation at 1243 K for 24 h, bare AISI 304 exhibited a linear mass gain with a rate constant of 3.0 ± 0.03 × 10-3 kg2 m-4 s-1 while ceria coating lowered the kinetics by 3-4 orders. Though the thickness of the coating was kept constant at 2 μm, higher deposition rate offered one order lower protection due to the porous nature of the coating. Variation in the substrate temperature modulated the porosity as well as oxygen vacancy concentration and displayed the best protection for coatings deposited at moderate substrate temperature. The present work demonstrates the significance of selecting appropriate processing parameters to obtain the required morphology for efficient high-temperature oxidation protection.

Models of H II regions - Heavy element opacity, variation of temperature

NASA Technical Reports Server (NTRS)

Rubin, R. H.

1985-01-01

A detailed set of H II region models that use the same physics and self-consistent input have been computed and are used to examine where in parameter space the effects of heavy element opacity is important. The models are briefly described, and tabular data for the input parameters and resulting properties of the models are presented. It is found that the opacities of C, Ne, O, and to a lesser extent N play a vital role over a large region of parameter space, while S and Ar opacities are negligible. The variation of the average electron temperature T(e) of the models with metal abundance, density, and T(eff) is investigated. It is concluded that by far the most important determinator of T(e) is metal abundance; an almost 7000 K difference is expected over the factor of 10 change from up to down abundances.

Inter-Diffusion in the Presence of Free Convection

NASA Technical Reports Server (NTRS)

Gupta, Prabhat K.

1999-01-01

Because of their technological importance, establishment of the precise values of interdiffusion coefficients is important in multicomponent fluid systems. Such values are not available because diffusion is influenced by free convection due to compositionally induced density variations. In this project, earth based diffusion experiments are being performed in a viscous fluid system PbO-SiO2 at temperatures between 500-1000 C. This system is chosen because it shows a large variation in density with small changes in composition and is expected to show a large free convection effect. Infinite diffusion couples at different temperatures and times are being studied with different orientations with respect to gravity. Composition fields will be measured using an Electron Microprobe Analyzer and will be compared with the results of a complementary modeling study to extract the values of the true diffusion coefficient from the measured diffusion profiles.

Cosmic Rays Variation Before Changes in Sun-Earth Environment

NASA Astrophysics Data System (ADS)

Mukherjee, S.

2011-12-01

Influence of cosmic rays variations on the Sun-Earth Environment has been observed before the changes in the atmospheric temperature, outbreak of influenza, cyclone, earthquake and tsunami. It has been recorded by Sun Observatory Heleospheric Observatory (SOHO) satellite data. Before the earthquake and tsunami the planetary indices (Kp) and Electron flux (E-flux) shows sudden changes followed by the atmospheric perturbations including very high temperature rise to sudden fall resulting snowfall in high altitude and rainfall in tropical areas. The active fault zones shows sudden faulting after the sudden drop in cosmic ray intensity and rise in Kp and E-flux. Besides the geo-environment the extraterrestrial influence on outbreak of H1N1 influenza has also been recorded based on the Mexico Cosmic ray data and its correlation with SOHO records. Distant stars have the potential to influence the heliophysical parameters by showering cosmic rays.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smylie, M. P.; Willa, K.; Claus, H.

We present resistivity and magnetization measurements on proton-irradiated crystals demonstrating that the superconducting state in the doped topological insulator Nb xBi 2Se 3 (x = 0.25) is surprisingly robust against disorder-induced electron scattering. The superconducting transition temperature Tc decreases without indication of saturation with increasing defect concentration, and the corresponding scattering rates far surpass expectations based on conventional theory. The low-temperature variation of the London penetration depth Δλ(T) follows a power law [Δλ(T)~T 2] indicating the presence of symmetry-protected point nodes. Lastly, our results are consistent with the proposed robust nematic E u pairing state in this material.

Technique for temperature compensation of eddy-current proximity probes

NASA Technical Reports Server (NTRS)

Masters, Robert M.

1989-01-01

Eddy-current proximity probes are used in turbomachinery evaluation testing and operation to measure distances, primarily vibration, deflection, or displacment of shafts, bearings and seals. Measurements of steady-state conditions made with standard eddy-current proximity probes are susceptible to error caused by temperature variations during normal operation of the component under investigation. Errors resulting from temperature effects for the specific probes used in this study were approximately 1.016 x 10 to the -3 mm/deg C over the temperature range of -252 to 100 C. This report examines temperature caused changes on the eddy-current proximity probe measurement system, establishes their origin, and discusses what may be done to minimize their effect on the output signal. In addition, recommendations are made for the installation and operation of the electronic components associated with an eddy-current proximity probe. Several techniques are described that provide active on-line error compensation for over 95 percent of the temperature effects.

On limitations of laser-induced fluorescence diagnostics for xenon ion velocity distribution function measurements in Hall thrusters

NASA Astrophysics Data System (ADS)

Romadanov, I.; Raitses, Y.; Diallo, A.; Hara, K.; Kaganovich, I. D.; Smolyakov, A.

2018-03-01

Hall thruster operation is characterized by strong breathing oscillations of the discharge current, the plasma density, the temperature, and the electric field. Probe- and laser-induced fluorescence (LIF) diagnostics were used to measure temporal variations of plasma parameters and the xenon ion velocity distribution function (IVDF) in the near-field plasma plume in regimes with moderate (<18%) external modulations of applied DC discharge voltage at the frequency of the breathing mode. It was shown that the LIF signal collapses while the ion density at the same location is finite. The proposed explanation for this surprising result is based on a strong dependence of the excitation cross-section of metastables on the electron temperature. For large amplitudes of oscillations, the electron temperature at the minimum enters the region of very low cross-section (for the excitation of the xenon ions); thus, significantly reducing the production of metastable ions. Because the residence time of ions in the channel is generally shorter than the time scale of breathing oscillations, the density of the excited ions outside the thruster is low and they cannot be detected. In the range of temperature of oscillations, the ionization cross-section of xenon atoms remains sufficiently large to sustain the discharge. This finding suggests that the commonly used LIF diagnostic of xenon IVDF can be subject to large uncertainties in the regimes with significant oscillations of the electron temperature, or other plasma parameters.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liang, Shuhua; Bishop, Christopher B.; Moreo, Adriana

The phase diagram of electron-doped pnictides is studied varying the temperature, electronic density, and isotropic in-plane quenched disorder strength and dilution by means of computational techniques applied to a three-orbital (xz,yz,xy) spin-fermion model with lattice degrees of freedom. In experiments, chemical doping introduces disorder but in theoretical studies the relationship between electronic doping and the randomly located dopants, with their associated quenched disorder, is difficult to address. Moreover, in this publication, the use of computational techniques allows us to study independently the effects of electronic doping, regulated by a global chemical potential, and impurity disorder at randomly selected sites. Surprisingly,more » our Monte Carlo simulations reveal that the fast reduction with doping of the N eel T N and the structural T S transition temperatures, and the concomitant stabilization of a robust nematic state, is primarily controlled in our model by the magnetic dilution associated with the in-plane isotropic disorder introduced by Fe substitution. In the doping range studied, changes in the Fermi surface produced by electron doping affect only slightly both critical temperatures. Our results also suggest that the specific material-dependent phase diagrams experimentally observed could be explained as a consequence of the variation in disorder profiles introduced by the different dopants. Finally, our findings are also compatible with neutron scattering and scanning tunneling microscopy, unveiling a patchy network of locally magnetically ordered clusters with anisotropic shapes, even though the quenched disorder is locally isotropic. Our study reveals a remarkable and unexpected degree of complexity in pnictides: the fragile tendency to nematicity intrinsic of translational invariant electronic systems needs to be supplemented by quenched disorder and dilution to stabilize the robust nematic phase experimentally found in electron-doped 122 compounds.« less

Effect of polyvinyl alcohol (PVA) on Ag-Cu nanopaste performance

NASA Astrophysics Data System (ADS)

Noordin, Norasiah Mohammad; Razak, Khairunisak Abd; Cheong, Kuan Yew

2017-07-01

Electronic devices used for extreme high temperature continue to be in demand, for instance in aviation, aerospace and automotive industry. The reliability of these devices strongly depends on electronic packaging. Die attach materials is vital in electronic packaging as it provides an interface in between a die and a substrate, and its quality will determine the performance of the devices. Nanopaste is one of categories classified in the die attach systems. It is a mixture of nano sized metal particles and organic additives (binder, surfactant, solvent). In this study, Ag and Cu nanoparticles was mixed into an organic binder system, polyvinyl alcohol (PVA) serves as binder and ethylene glycol functions as surfactant while deionized water used to dissolve PVA. The mixture was inserted in vacuum oven at 70°C and then proceeds for sintering in horizontal tube furnace with various sintering temperature, a dwell time of 30 min and ramp rate of 5°C/min. The samples were then characterized using field emission scanning electron microscope (FE-SEM) to examine the morphology, X-ray diffraction (XRD) for phase identification, Four Point Probe to measure sheet resistance, and thermogravimetric and differential scanning calorimetry analysis (TGA/DSC) to study the thermal response with respect to temperature. These parameter were studied, the effect of PVA amount (0.10, 0.15, 0.20, 0.30, 0.40, 0.50 g) in Ag-Cu nanopaste formulation was visual inspected, the variation of drying time (20, 30, 40, 60, 80, 100, 120 min) in vacuum oven and sintering temperature (280, 300, 320, 340, 360, 380, 400°C) was recorded. The optimum condition for producing Ag-Cu nanopaste is by using 0.15 g of PVA in the Ag-Cu formulation, 30 min drying time and 340°C sintering temperature.

Characterization of chromium compensated GaAs as an X-ray sensor material for charge-integrating pixel array detectors

NASA Astrophysics Data System (ADS)

Becker, J.; Tate, M. W.; Shanks, K. S.; Philipp, H. T.; Weiss, J. T.; Purohit, P.; Chamberlain, D.; Gruner, S. M.

2018-01-01

We studied the properties of chromium compensated GaAs when coupled to charge integrating ASICs as a function of detector temperature, applied bias and X-ray tube energy. The material is a photoresistor and can be biased to collect either electrons or holes by the pixel circuitry. Both are studied here. Previous studies have shown substantial hole trapping. This trapping and other sensor properties give rise to several non-ideal effects which include an extended point spread function, variations in the effective pixel size, and rate dependent offset shifts. The magnitude of these effects varies with temperature and bias, mandating good temperature uniformity in the sensor and very good temperature stabilization, as well as a carefully selected bias voltage.

Electron flat-top distributions and cross-scale wave modulations observed in the current sheet of geomagnetic tail

NASA Astrophysics Data System (ADS)

Zhao, Duo; Fu, Suiyan; Parks, George K.; Sun, Weijie; Zong, Qiugang; Pan, Dongxiao; Wu, Tong

2017-08-01

We present new observations of electron distributions and the accompanying waves during the current sheet activities at ˜60 RE in the geomagnetic tail detected by the ARTEMIS (Acceleration, Reconnection, Turbulence, and Electrodynamics of the Moon's Interaction with the Sun) spacecraft. We find that electron flat-top distribution is a common feature near the neutral sheet of the tailward flowing plasmas, consistent with the electron distributions that are shaped in the reconnection region. Whistler mode waves are generated by the anisotropic electron temperature associated with the electron flat-top distributions. These whistler mode waves are modulated by low frequency ion scale waves that are possibly excited by the high-energy ions injected during the current sheet instability. The magnetic and electric fields of the ion scale waves are in phase with electron density variations, indicating that they are compressional ion cyclotron waves. Our observations present examples of the dynamical processes occurring during the current sheet activities far downstream of the geomagnetic tail.

Van Allen Probe Charging During the St. Patrick's Day Event

NASA Technical Reports Server (NTRS)

Parker, L. Neergaard; Minow, J. I.

2015-01-01

The geomagnetic storms on and around March 17, 2015 marked the largest storms seen in the declining phase of the solar cycle to date. We use the Helium Oxygen Proton Electron (HOPE) mass spectrometer on board the Van Allen Probe - A and B satellites to study in detail the charging effects seen on these spacecraft during this time. Ion particle flux data provides information on the magnitude of the charging events using the ion line charging signature due to low energy ions accelerated by the spacecraft potential. Electron flux observations are used to correlate the charging environment with variations in spacecraft potential through the event. We also investigate the density and temperature of ions and electrons during the time of the charging event.

Linear and nonlinear dust ion acoustic solitary waves in a quantum dusty electron-positron-ion plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Emadi, E.; Zahed, H.

2016-08-15

The behavior of linear and nonlinear dust ion acoustic (DIA) solitary waves in an unmagnetized quantum dusty plasma, including inertialess electrons and positrons, ions, and mobile negative dust grains, are studied. Reductive perturbation and Sagdeev pseudopotential methods are employed for small and large amplitude DIA solitary waves, respectively. A minimum value of the Mach number obtained for the existence of solitary waves using the analytical expression of the Sagdeev potential. It is observed that the variation on the values of the plasma parameters such as different values of Mach number M, ion to electron Fermi temperature ratio σ, and quantummore » diffraction parameter H can lead to the creation of compressive solitary waves.« less

Cassini UVIS Observations of the Io Plasma Torus. 3; Observations of Temporal and Azimuthal Variability

NASA Technical Reports Server (NTRS)

Steffl, A. J.; Delamere, P. A.; Bagenal, F.

2006-01-01

In this third paper in a series presenting observations by the Cassini Ultraviolet Imaging Spectrometer (UVIS) of the Io plasma torus, we show remarkable, though subtle, spatio-temporal variations in torus properties. The Io torus is found to exhibit significant, near sinusoidal variations in ion composition as a functions of azimuthal position. The azimuthal variation in composition is such that the mixing ratio of S II us strongly correlated with the mixing ratio of S III and the equatorial electron density and strongly anti-correlated with the mixing ratios of both S IV and O II and the equatorial electron temperature. Surprisingly, the azimuthal variation in ion composition is observed to have a period of 10.07 h -- 1.5% longer than the System III rotation period of Jupiter, yet 1.3% shorter than the System UV period defined by [Brown, M. E., 1995. J. Geophys. Res. 100, 21683-21696]. Although the amplitude of the azimuthal variation of S III and O II remained in the range of 2-5%, the amplitude of the S II and S IV compositional variation ranged between 5 and 25% during the UVIS observations. Furthermore, the amplitude of the azimuthal variations of S II and S IV appears to be modulated by its location in System III longitude, such that when the region of maximum S II mixing ration (minimum S IV mixing ratio) is aligned with a System III longitude of 200 deg +/-, the amplitude is a factor of 4 greater than when the variation is anti-aligned. This behavior can explain numerous, often apparently contradictory, observations of variations in the properties of the Io plasma torus with the System III and System IV coordinate systems.

Multiferroic properties of microwave sintered PbFe12-xO19-δ

NASA Astrophysics Data System (ADS)

Prathap, S.; Madhuri, W.

2017-05-01

The effect of iron deficiency on the structural, electrical, ferroelectric and magnetic properties of nano PbFe12-xO19-δ (where x=0.0, 0.25, 0.50, 0.75, 1.0) hexaferrites prepared by sol-gel auto combustion and processed by microwaves are investigated. X-ray analysis confirms single phase magneto-plumbite phase formation. The surface morphology is studied from Field Emission Scanning Electron Microscope. Further, optical properties are investigated using Fourier Transform Infrared spectra and UV-visible spectra. AC electrical conductivity is estimated as a function of temperature and frequency in the range of room temperature (RT) to 500 °C and 100 Hz to 5MHz. AC electrical conduction analysis shows that conduction is mainly due to small polaron hopping mechanism. The variation of polarization with applied electric field exhibits hysteresis loop confirming the ferroelectric nature. The initial permeability studies with varying temperature reveals that the Curie transition temperature for the present series is around 400 °C. Variation of initial permeability with frequency ranging from 100 to 5 MHz shows a constant value (except for x=0.0) opening avenues for high frequency applications.

Electronic Disorder in Organic Semiconducting Films Observed with Kelvin Probe Force Microscopy

NASA Astrophysics Data System (ADS)

Hoffman, Benjamin Carl

This work is a study into electronic disorder within organic semiconducting (OSC) films from a scan-probe perspective. Organic electronics are an exciting technology poised for use in next generation devices with unique applications such as transparent displays and ultrathin flexible solar cells. Understanding and mapping electronic disorder in OSC has a high degree of relevance towards recognizing the properties of charge trapping that hinders transport and diminishes device performance. Evidence of surface potential inhomogeneity is identified by using Kelvin probe force microscopy (KPFM) to measure the contact potential difference (CPD) between probe and sample. OSC films are grown via organic molecular beam deposition (OMBD) to create well-ordered crystals with precise control of nominal thickness. Further research methods involve the study of diffraction peaks from grazing-incidence wide-angle x-ray scattering (GIWAXS) for crystallographic analysis as well as use of a probe station for transfer characteristics of fabricated thin film transistors. Initial research into this subject involved thin films of the novel organic molecule 2,8- diflouro-5,11-bis(triethylsilylethynyl)-anthradithiophene (diF-TES-ADT) that were grown on silicon substrates with a native oxide layer and analyzed with GIWAXS and KPFM. The crystallography of the films is that of a uniform (001) orientation. Variations in surface potential in diF-TES-ADT crystallites are observed to be unique from variations in the substrate. Nevertheless, surface potential variations in thick films are influenced by chemical passivation of the substrate and so the source of CPD variations are assigned to be intrinsic defects. Chemical treatment and processing methods control the growth kinetics which are linked to charge traps locally distorting the surface potential in OSC films. To continue the research into identifying charge trapping in ultra-thin films, 1.5 monolayer thick films of alpha-sexithiophene (6T) were grown on silicon substrates with a thick oxide layer to compare the surface potential of the first monolayer with that of the bilayer. The temperature of the substrate during film growth was varied and found to influence the interlayer surface potential contrast. Higher temperature samples have a bilayer with CPD above that of the monolayer, while lower temperature samples have a bilayer with CPD below that of the monolayer. GIWAXS data collected shows that the lower temperature sample has no observed out-of-plane order which we identify as the source of interlayer trapping formed between the first and second monolayers of the 6T films. The final project into the specifics of disorder involves using ultrathin films of 6T in an operational transistor with grounded source-drain electrodes to study the influence of gate bias on surface potential. Using the mean and standard deviation of CPD for a series of gate biases, the trap density of states (DOS) is calculated directly while allowing for the quantification of spatial variations. CPD histograms from the series of images illustrate the screening of deep traps as the transistor is turned on. While in the 'off' regime the images are electrostatic, after transitioning to the 'on' state the images show instability after threshold voltage. This dynamic 'on' state offers a unique view of shallow trap states being filled and then thermally released.

Effect of immobilized biosorbents on the heavy metals (Cu2+) biosorption with variations of temperature and initial concentration of waste

NASA Astrophysics Data System (ADS)

Siwi, W. P.; Rinanti, A.; Silalahi, M. D. S.; Hadisoebroto, R.; Fachrul, M. F.

2018-01-01

The aims of research is to studying the efficiency of copper removal by combining immobilized microalgae with optimizations of temperature and initial Copper concentration. The research was conducted in batch culture with temperature variations of 25°C, 30°C, and 35°C, as well as initial Cu2+ concentrations (mg/l) of 3, 5, 10, 15 and 20 using monoculture of S. cerevisiae, Chlorella sp., and mixed culture of them both as immobilized biosorbents. The optimum adsorption of 83.4% obtained in temperature of 30°C with an initial waste concentration of 17.62 mg/l, initial biomass concentration of 200 mg, pH of 4, and 120 minutes detention time by the immobilized mixed culture biosorbent. The cell morphology examined using Scanning Electron Microscope (SEM) has proved that the biosorbent surface was damaged after being in contact with copper (waste), implying that heavy metals (molecules) attach to different functional cell surfaces and change the biosorbent surface. The adsorption process of this research follows Langmuir Isotherm with the R2 value close to 1. The immobilized mixed culture biosorbent is capable of optimally removing copper at temperature of 30°C and initial Cu2+ concentration of 17.62 mg/l.

Two worlds collide: Image analysis methods for quantifying structural variation in cluster molecular dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steenbergen, K. G., E-mail: kgsteen@gmail.com; Gaston, N.

2014-02-14

Inspired by methods of remote sensing image analysis, we analyze structural variation in cluster molecular dynamics (MD) simulations through a unique application of the principal component analysis (PCA) and Pearson Correlation Coefficient (PCC). The PCA analysis characterizes the geometric shape of the cluster structure at each time step, yielding a detailed and quantitative measure of structural stability and variation at finite temperature. Our PCC analysis captures bond structure variation in MD, which can be used to both supplement the PCA analysis as well as compare bond patterns between different cluster sizes. Relying only on atomic position data, without requirement formore » a priori structural input, PCA and PCC can be used to analyze both classical and ab initio MD simulations for any cluster composition or electronic configuration. Taken together, these statistical tools represent powerful new techniques for quantitative structural characterization and isomer identification in cluster MD.« less

Two worlds collide: image analysis methods for quantifying structural variation in cluster molecular dynamics.

PubMed

Steenbergen, K G; Gaston, N

2014-02-14

Inspired by methods of remote sensing image analysis, we analyze structural variation in cluster molecular dynamics (MD) simulations through a unique application of the principal component analysis (PCA) and Pearson Correlation Coefficient (PCC). The PCA analysis characterizes the geometric shape of the cluster structure at each time step, yielding a detailed and quantitative measure of structural stability and variation at finite temperature. Our PCC analysis captures bond structure variation in MD, which can be used to both supplement the PCA analysis as well as compare bond patterns between different cluster sizes. Relying only on atomic position data, without requirement for a priori structural input, PCA and PCC can be used to analyze both classical and ab initio MD simulations for any cluster composition or electronic configuration. Taken together, these statistical tools represent powerful new techniques for quantitative structural characterization and isomer identification in cluster MD.

Dielectric barrier structure with hollow electrodes and its recoil effect

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yu, Shuang; Chen, Qunzhi; Liu, Jiahui

2015-06-15

A dielectric barrier structure with hollow electrodes (HEDBS), in which gas flow oriented parallel to the electric field, was proposed. Results showed that with this structure, air can be effectively ignited, forming atmospheric low temperature plasma, and the proposed HEDBS could achieve much higher electron density (5 × 10{sup 15}/cm{sup 3}). It was also found that the flow condition, including outlet diameter and flow rate, played a key role in the evolution of electron density. Optical emission spectroscopy diagnostic results showed that the concentration of reactive species had the same variation trend as the electron density. The simulated distribution of discharge gasmore » flow indicated that the HEDBS had a strong recoil effect on discharge gas, and could efficiently promote generating electron density as well as reactive species.« less

Thermo-electronic solar power conversion with a parabolic concentrator

NASA Astrophysics Data System (ADS)

Olukunle, Olawole C.; De, Dilip K.

2016-02-01

We consider the energy dynamics of the power generation from the sun when the solar energy is concentrated on to the emitter of a thermo-electronic converter with the help of a parabolic mirror. We use the modified Richardson-Dushman equation. The emitter cross section is assumed to be exactly equal to the focused area at a height h from the base of the mirror to prevent loss of efficiency. We report the variation of output power with solar insolation, height h, reflectivity of the mirror, and anode temperature, initially assuming that there is no space charge effect. Our methodology allows us to predict the temperature at which the anode must be cooled in order to prevent loss of efficiency of power conversion. Novel ways of tackling the space charge problem have been discussed. The space charge effect is modeled through the introduction of a parameter f (0 < f < 1) in the thermos-electron emission equation. We find that the efficiency of the power conversion depends on solar insolation, height h, apart from radii R of the concentrator aperture and emitter, and the collector material properties. We have also considered solar thermos electronic power conversion by using single atom-layer graphene as an emitter.

Ion thruster performance model

NASA Technical Reports Server (NTRS)

Brophy, J. R.

1984-01-01

A model of ion thruster performance is developed for high flux density, cusped magnetic field thruster designs. This model is formulated in terms of the average energy required to produce an ion in the discharge chamber plasma and the fraction of these ions that are extracted to form the beam. The direct loss of high energy (primary) electrons from the plasma to the anode is shown to have a major effect on thruster performance. The model provides simple algebraic equations enabling one to calculate the beam ion energy cost, the average discharge chamber plasma ion energy cost, the primary electron density, the primary-to-Maxwellian electron density ratio and the Maxwellian electron temperature. Experiments indicate that the model correctly predicts the variation in plasma ion energy cost for changes in propellant gas (Ar, Kr and Xe), grid transparency to neutral atoms, beam extraction area, discharge voltage, and discharge chamber wall temperature. The model and experiments indicate that thruster performance may be described in terms of only four thruster configuration dependent parameters and two operating parameters. The model also suggests that improved performance should be exhibited by thruster designs which extract a large fraction of the ions produced in the discharge chamber, which have good primary electron and neutral atom containment and which operate at high propellant flow rates.

Electron transport properties of bis[2-(2-hydroxyphenyl)-pyridine]beryllium investigated by impedance spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Yanping; Chen, Jiangshan; Huang, Jinying

2014-06-14

The electron transport properties of bis[2-(2-hydroxyphenyl)-pyridine] beryllium (Bepp{sub 2}) are investigated by impedance spectroscopy over a frequency range of 10 Hz to 13 MHz. The Cole-Cole plots demonstrate that the Bepp{sub 2}-based device can be represented by a single parallel resistance R{sub p} and capacitance C{sub p} network with a series resistance R{sub s}. The current-voltage characteristics and the variation of R{sub p} with applied bias voltage indicate the electron conduction of space-charge-limited current with exponential trap distributions in Bepp{sub 2}. It can be seen that the electron mobility exhibits strong field-dependence in low electric field region and almost saturate in highmore » electric field region. It is experimentally found that Bepp{sub 2} shows dispersion transport and becomes weak as the electric field increases. The activation energy is determined to be 0.043 eV by temperature-dependent conductivity, which is consistent with the result obtained from the temperature-dependent current density characteristics. The electron mobility reaches the orders of 10{sup −6}–10{sup −5} cm{sup 2} V{sup −1} s{sup −1}, depending on the electric field.« less

Mechanical and magneto-opto-electronic investigation of transition metal based fluoro-perovskites: An ab-initio DFT study

NASA Astrophysics Data System (ADS)

Erum, Nazia; Azhar Iqbal, Muhammad

2017-09-01

Detailed ab-initio calculations are performed to investigate structural, elastic, mechanical, magneto-electronic and optical properties of the KXF3 (X = V, Fe, Co, Ni) fluoro-perovskites using Full Potential Linearized Augmented Plane Wave (FP-LAPW) method within the framework of density functional theory (DFT). The calculated structural parameters by DFT and analytical methods are found consistent with the experimental results. From the elastic and mechanical properties, it can be inferred that these compounds are elastically stable and anisotropic while KCoF3 is harder than rest of the compounds. Furthermore, thermal behavior of these compounds is analyzed by calculating Debye temperature (θD). The calculated spin dependent magneto-electronic properties in these compounds reveal that exchange splitting is dominated by N-3d orbital. The stable magnetic phase optimizations verify the experimental observations at low temperature. Type of chemical bonding is analyzed with the help of variations in electron density difference distribution that is induced due to changes of the second cation. The linear optical properties are also discussed in terms of optical spectra. The present methodology represents an influential approach to calculate the whole set of mechanical and magneto-opto-electronic parameters, which would support to understand various physical phenomena and empower device engineers for implementing these materials in spintronic applications.

Electronic and phononic modulation of MoS2 under biaxial strain

NASA Astrophysics Data System (ADS)

Moghadasi, A.; Roknabadi, M. R.; Ghorbani, S. R.; Modarresi, M.

2017-12-01

Dichalcogenides of transition metals are attractive material due to its unique properties. In this work, it has been investigated the electronic band structure, phonon spectrum and heat capacity of MoS2 under the applied tensile and compressive biaxial strain using the density functional theory. The Molybdenum disulfide under compressive (tensile) strain up to 6% (10%) has stable atomic structure without any negative frequency in the phonon dispersion curves. The tensile biaxial strain reduces the energy gap in the electronic band structure and the optical-acoustic gap in phonon dispersion curves. The tensile biaxial strain also increases the specific heat capacity. On the other hand, the compressive biaxial strain in this material increases phonon gap and reduces the heat capacity and the electronic band gap. The phonon softening/hardening is reported for tensile/compressive biaxial strain in MoS2. We report phonon hardening for out of plane ZA mode in the presence of both tensile and compressive strains. Results show that the linear variation of specific heat with strain (CV ∝ε) and square dependency of specific heat with the temperature (CV ∝T2) for low temperature regime. The results demonstrate that the applied biaxial strain tunes the electronic energy gap and modifies the phonon spectrum of MoS2.

Facile synthesis of Ni/NiO@GO nanocomposites and its enhanced dielectric constant

NASA Astrophysics Data System (ADS)

Sarkar, S.; Giri, N.; Mondal, A.; Ray, R.

2018-05-01

Ni/NiO embedded Graphene Oxide (GO): Ni/NiO@GO is synthesized by citric acid assisted Pechini-type method. Structural and morphological characterizations are performed by X-ray powdered diffraction (XRD), field emission scanning electron microscopy (FESEM) and tunneling electron microscopy (TEM). Defects in GO sheets are probed by RAMAN spectroscopy. The temperature variation of dielectric constant (ɛR) and dielectric loss (tan δ) are investigated in the temperature range 300 - 400 K. Decoration of GO with Ni/NiO nanoparticles enhances its ɛR by˜55 times. Moreover, its dielectric constant measured at 5 MHz is found to be˜430 times to that of Ni/NiO along with the reduction of dielectric loss by a factor˜0.5. The enhanced dielectric constant makes the composite Ni/NiO@GO a potential candidate for using in ecologically friendly energy storage devices.

Thermal Conductivity within Nanoparticle Powder Beds

NASA Astrophysics Data System (ADS)

Wilson, Mark; Chandross, Michael

Non-equilibrium molecular dynamics is utilized to compute thermal transport properties within nanoparticle powder beds. In the realm of additive manufacturing of metals, the electronic contribution to thermal conduction is critical. To this end, our simulations incorporate the two temperature model, coupling a continuum representation of the electronic thermal contribution and the atomic phonon system. The direct method is used for conductivity determination, wherein thermal gradients between two different temperature heat flux reservoirs are calculated. The approach is demonstrated on several example cases including 304L stainless steel. The results from size distribution variations of mono/poly-disperse systems are extrapolated to predict values at the micron length scale, along with bulk properties at infinite system sizes. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

Hexamethylenetetramine assisted hydrothermal synthesis of BiPO4 and its electrochemical properties for supercapacitors

NASA Astrophysics Data System (ADS)

Nithya, V. D.; Kalai Selvan, R.; Vasylechko, Leonid

2015-11-01

The well defined microstructures of BiPO4 were successfully synthesized by the facile hexamethylenetetramine (HMT) assisted hydrothermal method. The low temperature monoclinic BiPO4 structure with space group P21/n, were obtained from X-ray diffraction (XRD) for the pristine and HMT-assisted BiPO4 with 1, 3, 5 and 10 mmole concentration. A transformation from low temperature monazite-type phase to the high temperature SbPO4-type phase of BiPO4 was observed at the 10 mmole concentration. There was a variation in the morphology from polyhedron to octahedra-like and finally into cube shape upon an increase in concentration of HMT. The role of reaction time in the morphology of BiPO4 particles was investigated. The selected area electron diffraction (SAED) pattern elucidated the ordered dot pattern and the calculated d-spacing revealed the formation of BiPO4. An increased specific capacitance of HMT assisted materials (202 F/g) compared with pristine BiPO4 (89 F/g) at 5 mA/cm2 was observed upon morphological variation due to HMT addition.

Nanometer scale thermometry in a living cell

PubMed Central

Kucsko, G.; Maurer, P. C.; Yao, N. Y.; Kubo, M.; Noh, H. J.; Lo, P. K.; Park, H.; Lukin, M. D.

2014-01-01

Sensitive probing of temperature variations on nanometer scales represents an outstanding challenge in many areas of modern science and technology1. In particular, a thermometer capable of sub-degree temperature resolution over a large range of temperatures as well as integration within a living system could provide a powerful new tool for many areas of biological, physical and chemical research; possibilities range from the temperature-induced control of gene expression2–5 and tumor metabolism6 to the cell-selective treatment of disease7,8 and the study of heat dissipation in integrated circuits1. By combining local light-induced heat sources with sensitive nanoscale thermometry, it may also be possible to engineer biological processes at the sub-cellular level2–5. Here, we demonstrate a new approach to nanoscale thermometry that utilizes coherent manipulation of the electronic spin associated with nitrogen-vacancy (NV) color centers in diamond. We show the ability to detect temperature variations down to 1.8 mK (sensitivity of 9mK/Hz) in an ultra-pure bulk diamond sample. Using NV centers in diamond nanocrystals (nanodiamonds, NDs), we directly measure the local thermal environment at length scales down to 200 nm. Finally, by introducing both nanodiamonds and gold nanoparticles into a single human embryonic fibroblast, we demonstrate temperature-gradient control and mapping at the sub-cellular level, enabling unique potential applications in life sciences. PMID:23903748

Flight data analysis and further development of variable-conductance heat pipes. [for aircraft control

NASA Technical Reports Server (NTRS)

Enginer, J. E.; Luedke, E. E.; Wanous, D. J.

1976-01-01

Continuing efforts in large gains in heat-pipe performance are reported. It was found that gas-controlled variable-conductance heat pipes can perform reliably for long periods in space and effectively provide temperature stabilization for spacecraft electronics. A solution was formulated that allows the control gas to vent through arterial heat-pipe walls, thus eliminating the problem of arterial failure under load, due to trace impurities of noncondensable gas trapped in an arterial bubble during priming. This solution functions well in zero gravity. Another solution was found that allows priming at a much lower fluid charge. A heat pipe with high capacity, with close temperature control of the heat source and independent of large variations in sink temperature was fabricated.

Nanotwinning and structural phase transition in CdS quantum dots

PubMed Central

2012-01-01

Nanotwin structures are observed in high-resolution transmission electron microscopy studies of cubic phase CdS quantum dots in powder form by chemical co-precipitation method. The deposition of thin films of nanocrystalline CdS is carried out on silicon, glass, and TEM grids keeping the substrates at room temperature (RT) and 200°C by pulsed laser ablation. These films are then subjected to thermal annealing at different temperatures. Glancing angle X-ray diffraction results confirm structural phase transitions after thermal annealing of films deposited at RT and 200°C. The variation of average particle size and ratio of intensities in Raman peaks I2LO/I1LO with annealing temperature are studied. It is found that electron-phonon interaction is a function of temperature and particle size and is independent of the structure. Besides Raman modes LO, 2LO and 3LO of CdS at approximately 302, 603, and 903 cm−1 respectively, two extra Raman modes at approximately 390 and 690 cm−1 are studied for the first time. The green and orange emissions observed in photoluminescence are correlated with phase transition. PMID:23092351

Hot electron inelastic scattering and transmission across graphene surfaces

NASA Astrophysics Data System (ADS)

Kong, Byoung Don; Champlain, James G.; Boos, J. Brad

2017-06-01

Inelastic scattering and transmission of externally injected hot carriers across graphene layers are considered as a function of graphene carrier density, temperature, and surrounding dielectric media. A finite temperature dynamic dielectric function for graphene for an arbitrary momentum q and frequency ω is found under the random phase approximation and a generalized scattering lifetime formalism is used to calculate the scattering and transmission rates. Unusual trends in scattering are found, including declining rates as graphene carrier density increases and interband transition excitations, which highlights the difference with out-of-plane as compared to in-plane transport. The results also show strong temperature dependence with a drastic increase in scattering at room temperature. The calculated scattering rate at T = 300 K shows a wide variation from 0.2 to 10 fs-1 depending on graphene carrier density, incident carrier momentum, and surrounding dielectrics. The analysis suggests that a transmission rate greater than 0.9 for a carrier with kinetic energy over 1 eV is achievable by carefully controlling the graphene carrier density in conjunction with the use of high-κ dielectric materials. Potential applications to electronic and electro-optical devices are also discussed.

Mid-Latitude Ionospheric Disturbances Due to Geomagnetic Storms at ISS Altitudes

NASA Technical Reports Server (NTRS)

Minow, Joseph I.; Willis, Emily M.; Parker, Linda Neergaard

2014-01-01

Spacecraft charging of the International Space Station (ISS) is dominated by the interaction of the high voltage US solar arrays with the F2-region ionospheric plasma environment. We are working to fully understand the charging behavior of the ISS solar arrays and determine how well future charging behavior can be predicted from in-situ measurements of plasma density and temperature. One aspect of this work is a need to characterize the magnitude of electron density and temperature variations that may be encountered at ISS orbital altitudes (approximately 400 km), the latitudes over which they occur, and the time periods for which the disturbances persist. We will present preliminary results from a study of ionospheric disturbances in the "mid-latitude" region defined as the approximately 30 - 60 degree extra-equatorial magnetic latitudes sampled by ISS. The study is focused on geomagnetic storm periods because they are well known drivers for disturbances in the high-latitude and mid-latitude ionospheric plasma. Changes in the F2 peak electron density obtained from ground based ionosonde records are compared to in-situ electron density and temperature measurements from the CHAMP and ISS spacecraft at altitudes near, or above, the F2 peak. Results from a number of geomagnetic storms will be presented and their potential impact on ISS charging will be discussed.

Atomic-scale distortions and temperature-dependent large pseudogap in thin films of the parent iron-chalcogenide superconductor Fe1+y Te

NASA Astrophysics Data System (ADS)

Gerbi, Andrea; Buzio, Renato; Kawale, Shrikant; Bellingeri, Emilio; Martinelli, Alberto; Bernini, Cristina; Tresca, Cesare; Capone, Massimo; Profeta, Gianni; Ferdeghini, Carlo

2017-12-01

We investigate with scanning tunneling microscopy/spectroscopy (STM/STS) and density functional theory (DFT) calculations the surface structures and the electronic properties of Fe1+y Te thin films grown by pulsed laser deposition. Contrary to the regular arrangement of antiferromagnetic nanostripes previously reported on cleaved single-crystal samples, the surface of Fe1+y Te thin films displays a peculiar distribution of spatially inhomogeneous nanostripes. Both STM and DFT calculations show the bias-dependent nature of such features and support the interpretation of spin-polarized tunneling between the FeTe surface and an unintentionally magnetized tip. In addition, the spatial inhomogeneity is interpreted as a purely electronic effect related to changes in hybridization and Fe-Fe bond length driven by local variations in the concentration of excess interstitial Fe cations. Unexpectedly, the surface density of states measured by STS strongly evolves with temperature in close proximity to the antiferromagnetic-paramagnetic first-order transition, and reveals a large pseudogap of 180-250 meV at about 50-65 K. We believe that in this temperature range a phase transition takes place, and the system orders and locks into particular combinations of orbitals and spins because of the interplay between excess interstitial magnetic Fe and strongly correlated d-electrons.

Mechanistic analysis of temperature-dependent current conduction through thin tunnel oxide in n+-polySi/SiO2/n+-Si structures

NASA Astrophysics Data System (ADS)

Samanta, Piyas

2017-09-01

We present a detailed investigation on temperature-dependent current conduction through thin tunnel oxides grown on degenerately doped n-type silicon (n+-Si) under positive bias ( VG ) on heavily doped n-type polycrystalline silicon (n+-polySi) gate in metal-oxide-semiconductor devices. The leakage current measured between 298 and 573 K and at oxide fields ranging from 6 to 10 MV/cm is primarily attributed to Poole-Frenkel (PF) emission of trapped electrons from the neutral electron traps located in the silicon dioxide (SiO2) band gap in addition to Fowler-Nordheim (FN) tunneling of electrons from n+-Si acting as the drain node in FLOating gate Tunnel OXide Electrically Erasable Programmable Read-Only Memory devices. Process-induced neutral electron traps are located at 0.18 eV and 0.9 eV below the SiO2 conduction band. Throughout the temperature range studied here, PF emission current IPF dominates FN electron tunneling current IFN at oxide electric fields Eox between 6 and 10 MV/cm. A physics based new analytical formula has been developed for FN tunneling of electrons from the accumulation layer of degenerate semiconductors at a wide range of temperatures incorporating the image force barrier rounding effect. FN tunneling has been formulated in the framework of Wentzel-Kramers-Brilloiun taking into account the correction factor due to abrupt variation of the energy barrier at the cathode/oxide interface. The effect of interfacial and near-interfacial trapped-oxide charges on FN tunneling has also been investigated in detail at positive VG . The mechanism of leakage current conduction through SiO2 films plays a crucial role in simulation of time-dependent dielectric breakdown of the memory devices and to precisely predict the normal operating field or applied floating gate (FG) voltage for lifetime projection of the devices. In addition, we present theoretical results showing the effect of drain doping concentration on the FG leakage current.

Strong Ionospheric Electron Heating Associated With Pulsating Auroras - A Swarm Survey

NASA Astrophysics Data System (ADS)

Liang, J.; Yang, B.; Burchill, J. K.; Donovan, E.; Knudsen, D. J.

2016-12-01

A pulsating aurora is a repetitive modulation of auroral luminosity with periods typically of the order of 1-30 sec. It is often observed in the equatorward portion of the auroral oval. While it is generally recognized that the ultimate source of the pulsating auroral precipitation comes from energetic electrons of magnetospheric origin, investigating the ionospheric signature of the pulsating aurora may offer clues to the magnetosphere-ionosphere coupling aspect of the pulsating aurora and, under certain circumstance, to the generation mechanism of the pulsating aurora. In this study, we perform an extensive survey on the ionospheric signatures (electron temperature, plasma density and field-aligned current etc.) of pulsating auroras using Swarm satellite data. Via the survey we repeatedly identify a strong electron temperature enhancement associated with the pulsating aurora. On average, the electron temperature at Swarm satellite altitude ( 500 km) increases from 2100 K at subauroral altitudes to a peak of 2900 K upon entering the pulsating aurora patch. This indicates that the pulsating auroras may act as an important heating source of the nightside ionosphere/thermosphere. On the other hand, no well-defined trend of plasma density variation associated with pulsating auroras is identified in the survey. There often exist moderate upward field-aligned currents (up to a few mA/m2) within the pulsating auroral patch when the patch is "on" during the traversal of satellites [Gillies et al., 2015], and the electron temperature enhancement is found to be positively correlated with the magnitude of the field-aligned current. In a few events with high-resolution Swarm electric field instrument (EFI) data, we find that the on-time pulsating auroral patch is associated with structured electric field disturbances with peaks exceeding 10 mV/m. Based upon observations and ionospheric models, we consider and evaluate several possible mechanisms that may account for the strong electron heating associated with the pulsating aurora, including the Joule heating related to the field-aligned current and to the structured electric field, the backscattered secondary electrons led by the impact of pulsating auroral precipitation, and the vertical conductive heat transport.

Experiences with integral microelectronics on smart structures for space

NASA Astrophysics Data System (ADS)

Nye, Ted; Casteel, Scott; Navarro, Sergio A.; Kraml, Bob

1995-05-01

One feature of a smart structure implies that some computational and signal processing capability can be performed at a local level, perhaps integral to the controlled structure. This requires electronics with a minimal mechanical influence regarding structural stiffening, heat dissipation, weight, and electrical interface connectivity. The Advanced Controls Technology Experiment II (ACTEX II) space-flight experiments implemented such a local control electronics scheme by utilizing composite smart members with integral processing electronics. These microelectronics, tested to MIL-STD-883B levels, were fabricated with conventional thick film on ceramic multichip module techniques. Kovar housings and aluminum-kapton multilayer insulation was used to protect against harsh space radiation and thermal environments. Development and acceptance testing showed the electronics design was extremely robust, operating in vacuum and at temperature range with minimal gain variations occurring just above room temperatures. Four electronics modules, used for the flight hardware configuration, were connected by a RS-485 2 Mbit per second serial data bus. The data bus was controlled by Actel field programmable gate arrays arranged in a single master, four slave configuration. An Intel 80C196KD microprocessor was chosen as the digital compensator in each controller. It was used to apply a series of selectable biquad filters, implemented via Delta Transforms. Instability in any compensator was expected to appear as large amplitude oscillations in the deployed structure. Thus, over-vibration detection circuitry with automatic output isolation was incorporated into the design. This was not used however, since during experiment integration and test, intentionally induced compensator instabilities resulted in benign mechanical oscillation symptoms. Not too surprisingly, it was determined that instabilities were most detectable by large temperature increases in the electronics, typically noticeable within minutes of unstable operation.

Effect of heavy-ion and electron irradiation on properties of Fe-based superconductors

NASA Astrophysics Data System (ADS)

Konczykowski, Marcin

2013-03-01

The introduction of defects by particle irradiation is used to reveal the role of disorder in matter, which is unavoidable in all crystalline solids. In superconductors defects introduce flux pinning, controlling critical current, Jc; as well as pair-breaking scattering, limiting the critical temperature, Tc. To elucidate defect related properties of Fe-based superconductors (FBS) we precede in two types of irradiation: heavy ion (6GeV Pb) to create disorder in the form of amorphous tracks and low temperature electron irradiation (2.5MeV at 20K) to create point like defects. Substantial increase of irreversible magnetization and an upward shift of the irreversibility line are observed after heavy ion irradiation of all FBS investigated to date. In BaK 122 , signatures of a Bose-glass vortex state; angular dependence and variable-range hopping flux creep are revealed. Remarkably, heavy ion irradiation does not depress Tc, however, point-like disorder introduced by electron irradiation does substantially. In isovalently substituted Ba(FeAs1 - xPx) 2 and Ba(Fe1 - x Rux As) 2 crystals, Tc decreases linearly with dose. Suppression to 40 % of initial value of Tc was achieved in Ba(FeAs1 - xPx) 2 . An increase of normal state resistivity is observed and correlated to depression of Tc. Change of superconducting gap structure with disorder was determined from penetration depth measurements, λ (T) dependence, at various stages of irradiation. Linear in T variation of pristine samples, indicative of the presence of nodes in gap, turned at low irradiation dose to exponential T variation, indicative of a fully gaped state. T2 variation of λ is observed at higher doses. This behaviour is incompatible with symmetry-imposed nodes of d-wave pairing but consistent with S + / - , S + / + mechanisms. This is the first observation of the impurity-induced node lifting expected in anisotropic s-wave superconductors

Thermal degradation study of silicon carbide threads developed for advanced flexible thermal protection systems

NASA Technical Reports Server (NTRS)

Tran, Huy Kim; Sawko, Paul M.

1992-01-01

Silicon carbide (SiC) fiber is a material that may be used in advanced thermal protection systems (TPS) for future aerospace vehicles. SiC fiber's mechanical properties depend greatly on the presence or absence of sizing and its microstructure. In this research, silicon dioxide is found to be present on the surface of the fiber. Electron Spectroscopy for Chemical Analysis (ESCA) and Scanning Electron Microscopy (SEM) show that a thin oxide layer (SiO2) exists on the as-received fibers, and the oxide thickness increases when the fibers are exposed to high temperature. ESCA also reveals no evidence of Si-C bonding on the fiber surface on both as-received and heat treated fibers. The silicon oxide layer is thought to signal the decomposition of SiC bonds and may be partially responsible for the degradation in the breaking strength observed at temperatures above 400 C. The variation in electrical resistivity of the fibers with increasing temperature indicates a transition to a higher band gap material at 350 to 600 C. This is consistent with a decomposition of SiC involving silicon oxide formation.

Evaluation of thermal expansion coefficient of carbon fiber reinforced composites using electronic speckle interferometry.

PubMed

Dong, Chengzhi; Li, Kai; Jiang, Yuxi; Arola, Dwayne; Zhang, Dongsheng

2018-01-08

An optical system for measuring the coefficient of thermal expansion (CTE) of materials has been developed based on electronic speckle interferometry. In this system, the temperature can be varied from -60°C to 180°C with a Peltier device. A specific specimen geometry and an optical arrangement based on the Michelson interferometer are proposed to measure the deformation along two orthogonal axes due to temperature changes. The advantages of the system include its high sensitivity and stability over the whole range of measurement. The experimental setup and approach for estimating the CTE was validated using an Aluminum alloy. Following this validation, the system was applied for characterizing the CTE of carbon fiber reinforced composite (CFRP) laminates. For the unidirectional fiber reinforced composites, the CTE varied with fiber orientation and exhibits anisotropic behavior. By stacking the plies with specific angles and order, the CTE of a specific CFRP was constrained to a low level with minimum variation temperature. The optical system developed in this study can be applied to CTE measurement for engineering and natural materials with high accuracy.

Intraspecific variation in Pinus pinaster PSII photochemical efficiency in response to winter stress and freezing temperatures.

PubMed

Corcuera, Leyre; Gil-Pelegrin, Eustaquio; Notivol, Eduardo

2011-01-01

As part of a program to select maritime pine (Pinus pinaster Ait.) genotypes for resistance to low winter temperatures, we examined variation in photosystem II activity by chlorophyll fluorescence. Populations and families within populations from contrasting climates were tested during two consecutive winters through two progeny trials, one located at a continental and xeric site and one at a mesic site with Atlantic influence. We also obtained the LT₅₀, or the temperature that causes 50% damage, by controlled freezing and the subsequent analysis of chlorophyll fluorescence in needles and stems that were collected from populations at the continental trial site.P. pinaster showed sensitivity to winter stress at the continental site, during the colder winter. The combination of low temperatures, high solar irradiation and low precipitation caused sustained decreases in maximal photochemical efficiency (F(v)/F(m)), quantum yield of non-cyclic electron transport (Φ(PSII)) and photochemical quenching (qP). The variation in photochemical parameters was larger among families than among populations, and population differences appeared only under the harshest conditions at the continental site. As expected, the environmental effects (winter and site) on the photochemical parameters were much larger than the genotypic effects (population or family). LT₅₀ was closely related to the minimum winter temperatures of the population's range. The dark-adapted F(v)/F(m) ratio discriminated clearly between interior and coastal populations.In conclusion, variations in F(v)/F(m), Φ(PSII), qP and non-photochemical quenching (NPQ) in response to winter stress were primarily due to the differences between the winter conditions and the sites and secondarily due to the differences among families and their interactions with the environment. Populations from continental climates showed higher frost tolerance (LT₅₀) than coastal populations that typically experience mild winters. Therefore, LT₅₀, as estimated by F(v)/F(m), is a reliable indicator of frost tolerance among P. pinaster populations.

Intraspecific Variation in Pinus Pinaster PSII Photochemical Efficiency in Response to Winter Stress and Freezing Temperatures

PubMed Central

Corcuera, Leyre; Gil-Pelegrin, Eustaquio; Notivol, Eduardo

2011-01-01

As part of a program to select maritime pine (Pinus pinaster Ait.) genotypes for resistance to low winter temperatures, we examined variation in photosystem II activity by chlorophyll fluorescence. Populations and families within populations from contrasting climates were tested during two consecutive winters through two progeny trials, one located at a continental and xeric site and one at a mesic site with Atlantic influence. We also obtained the LT50, or the temperature that causes 50% damage, by controlled freezing and the subsequent analysis of chlorophyll fluorescence in needles and stems that were collected from populations at the continental trial site. P. pinaster showed sensitivity to winter stress at the continental site, during the colder winter. The combination of low temperatures, high solar irradiation and low precipitation caused sustained decreases in maximal photochemical efficiency (Fv/Fm), quantum yield of non-cyclic electron transport (ΦPSII) and photochemical quenching (qP). The variation in photochemical parameters was larger among families than among populations, and population differences appeared only under the harshest conditions at the continental site. As expected, the environmental effects (winter and site) on the photochemical parameters were much larger than the genotypic effects (population or family). LT50 was closely related to the minimum winter temperatures of the population's range. The dark-adapted Fv/Fm ratio discriminated clearly between interior and coastal populations. In conclusion, variations in Fv/Fm, ΦPSII, qP and non-photochemical quenching (NPQ) in response to winter stress were primarily due to the differences between the winter conditions and the sites and secondarily due to the differences among families and their interactions with the environment. Populations from continental climates showed higher frost tolerance (LT50) than coastal populations that typically experience mild winters. Therefore, LT50, as estimated by Fv/Fm, is a reliable indicator of frost tolerance among P. pinaster populations. PMID:22220195

Impact Factors Analysis of the Hot Side Temperature of Thermoelectric Module

NASA Astrophysics Data System (ADS)

Zhang, Xingyu; Tan, Gangfeng; Yang, Bo

2018-03-01

The thermoelectric generator (TEG) plays a crucial role in converting the waste energy of exhaust into electricity, which ensures energy saving and increased fuel utilization efficiency. In the urban driving cycle, frequent vehicle operation, like deceleration or acceleration, results in continuous variation of the exhaust temperature. In order to make the operating performance stable, and to weaken the adverse effects of the frequent variation of the exhaust temperature on the lifetime and work efficiency of the electronic components of TEG systems, the output voltage of the thermoelectric (TE) module should stay more stable. This article provides an improved method for the temperature stability of the TE material hot side based on sandwiching material. From the view of the TEG system's average output power and the hot side temperature stability of the TE material, the analyzing factors, including the fluctuation frequency of the exhaust temperature and the physical properties and thickness of the sandwiching material are evaluated, respectively, in the sine and new European driving cycle (NEDC) fluctuation condition of the exhaust temperature. The results show few effects of sandwiching material thickness with excellent thermal conductivity on the average output power. During the 150-170 s of the NEDC test condition, the minimum hot side temperatures with a BeO ceramic thickness of 2 mm and 6 mm are, respectively, 537.19 K and 685.70 K, which shows the obvious effect on the hot side temperature stability of the BeO ceramic thickness in the process of acceleration and deceleration of vehicle driving.

Impact Factors Analysis of the Hot Side Temperature of Thermoelectric Module

NASA Astrophysics Data System (ADS)

Zhang, Xingyu; Tan, Gangfeng; Yang, Bo

2017-12-01

The thermoelectric generator (TEG) plays a crucial role in converting the waste energy of exhaust into electricity, which ensures energy saving and increased fuel utilization efficiency. In the urban driving cycle, frequent vehicle operation, like deceleration or acceleration, results in continuous variation of the exhaust temperature. In order to make the operating performance stable, and to weaken the adverse effects of the frequent variation of the exhaust temperature on the lifetime and work efficiency of the electronic components of TEG systems, the output voltage of the thermoelectric (TE) module should stay more stable. This article provides an improved method for the temperature stability of the TE material hot side based on sandwiching material. From the view of the TEG system's average output power and the hot side temperature stability of the TE material, the analyzing factors, including the fluctuation frequency of the exhaust temperature and the physical properties and thickness of the sandwiching material are evaluated, respectively, in the sine and new European driving cycle (NEDC) fluctuation condition of the exhaust temperature. The results show few effects of sandwiching material thickness with excellent thermal conductivity on the average output power. During the 150-170 s of the NEDC test condition, the minimum hot side temperatures with a BeO ceramic thickness of 2 mm and 6 mm are, respectively, 537.19 K and 685.70 K, which shows the obvious effect on the hot side temperature stability of the BeO ceramic thickness in the process of acceleration and deceleration of vehicle driving.

Electron transport near the Mott transition in n-GaAs and n-GaN

NASA Astrophysics Data System (ADS)

Romanets, P. N.; Sachenko, A. V.

2016-01-01

In this paper, we study the temperature dependence of the conductivity and the Hall coefficient near the metal-insulator phase transition. A theoretical investigation is performed within the effective mass approximation. The variational method is used to calculate the eigenvalues and eigenfunctions of the impurity states. Unlike previous studies, we have included nonlinear corrections to the screened impurity potential, because the Thomas-Fermi approximation is incorrect for the insulator phase. It is also shown that near the phase transition the exchange interaction is essential. The obtained temperature dependencies explain several experimental measurements in gallium arsenide (GaAs) and gallium nitride (GaN).

Deposition of thin silicon layers on transferred large area graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lupina, Grzegorz, E-mail: lupina@ihp-microelectronics.com; Kitzmann, Julia; Lukosius, Mindaugas

2013-12-23

Physical vapor deposition of Si onto transferred graphene is investigated. At elevated temperatures, Si nucleates preferably on wrinkles and multilayer graphene islands. In some cases, however, Si can be quasi-selectively grown only on the monolayer graphene regions while the multilayer islands remain uncovered. Experimental insights and ab initio calculations show that variations in the removal efficiency of carbon residuals after the transfer process can be responsible for this behavior. Low-temperature Si seed layer results in improved wetting and enables homogeneous growth. This is an important step towards realization of electronic devices in which graphene is embedded between two Si layers.

EHW Approach to Temperature Compensation of Electronics

NASA Technical Reports Server (NTRS)

Stoica, Adrian

2004-01-01

Efforts are under way to apply the concept of evolvable hardware (EHW) to compensate for variations, with temperature, in the operational characteristics of electronic circuits. To maintain the required functionality of a given circuit at a temperature above or below the nominal operating temperature for which the circuit was originally designed, a new circuit would be evolved; moreover, to obtain the required functionality over a very wide temperature range, there would be evolved a number of circuits, each of which would satisfy the performance requirements over a small part of the total temperature range. The basic concepts and some specific implementations of EHW were described in a number of previous NASA Tech Briefs articles, namely, "Reconfigurable Arrays of Transistors for Evolvable Hardware" (NPO-20078), Vol. 25, No. 2 (February 2001), page 36; Evolutionary Automated Synthesis of Electronic Circuits (NPO- 20535), Vol. 26, No. 7 (July 2002), page 37; "Designing Reconfigurable Antennas Through Hardware Evolution" (NPO-20666), Vol. 26, No. 7 (July 2002), page 38; "Morphing in Evolutionary Synthesis of Electronic Circuits" (NPO-20837), Vol. 26, No. 8 (August 2002), page 31; "Mixtrinsic Evolutionary Synthesis of Electronic Circuits" (NPO-20773) Vol. 26, No. 8 (August 2002), page 32; and "Synthesis of Fuzzy-Logic Circuits in Evolvable Hardware" (NPO-21095) Vol. 26, No. 11 (November 2002), page 38. To recapitulate from the cited prior articles: EHW is characterized as evolutionary in a quasi-genetic sense. The essence of EHW is to construct and test a sequence of populations of circuits that function as incrementally better solutions of a given design problem through the selective, repetitive connection and/or disconnection of capacitors, transistors, amplifiers, inverters, and/or other circuit building blocks. The connection and disconnection can be effected by use of field-programmable transistor arrays (FPTAs). The evolution is guided by a search-andoptimization algorithm (in particular, a genetic algorithm) that operates in the space of possible circuits to find a circuit that exhibits an acceptably close approximation of the desired functionality. The evolved circuits can be tested by mathematical modeling (that is, computational simulation) only, tested in real hardware, or tested in combinations of computational simulation and real hardware.

Langmuir Probe Measurements in a Grid-Assisted Magnetron Sputtering System

NASA Astrophysics Data System (ADS)

Sagás, Julio César; Pessoa, Rodrigo Sávio; Maciel, Homero Santiago

2018-02-01

The grid-assisted magnetron sputtering is a variation of the magnetron sputtering commonly used for thin film deposition. In this work, Langmuir probe measurements were performed in such a system by using the grid under two basic and practical electrical conditions, i.e., floating and grounded. The results show that grounding the grid leads to an enhancement of the plasma confinement and to increases in both floating and plasma potential, as inferred from the probe characteristics. The grounded grid drains electrons from the plasma, acting as an auxiliary anode and reducing the plasma diffusion toward the chamber walls. For the same discharge current, the improved confinement results in a lower electron temperature when compared to floating condition, although the electron densities are comparable in both cases.

Solar Pumped Laser

DTIC Science & Technology

1976-09-01

1 dB into 50 ohm load, output VSWR less than 1.5. Phase variation relative to the optical pulse train less than +A.5 Rod Temperature...design of the PSQM laser. All phases of design, mechanical, electronic and optical , borrowed heavily from the EFM lamp pumped laser...opnical power input change for the germanium device is twice that for the silicon device, its random phase noise for a typical in- put of 1 mW optical

Onset temperature for Si nanostructure growth on Si substrate during high vacuum electron beam annealing.

PubMed

Fang, F; Markwitz, A

2009-05-01

Silicon nanostructures, called Si nanowhiskers, are successfully synthesized on Si(100) substrate by high vacuum electron beam annealing. The onset temperature and duration needed for the Si nanowhiskers to grow was investigated. It was found that the onset and growth morphology of Si nanowhiskers strongly depend on the annealing temperature and duration applied in the annealing cycle. The onset temperature for nanowhisker growth was determined as 680 degrees C using an annealing duration of 90 min and temperature ramps of +5 degrees C s(-1) for heating and -100 degrees C s(-1) for cooling. Decreasing the annealing time at peak temperature to 5 min required an increase in peak temperature to 800 degrees C to initiate the nanowhisker growth. At 900 degrees C the duration for annealing at peak temperature can be set to 0 s to grow silicon nanowhiskers. A correlation was found between the variation in annealing temperature and duration and the nanowhisker height and density. Annealing at 900 degrees C for 0 s, only 2-3 nanowhiskers (average height 2.4 nm) grow on a surface area of 5 x 5 microm, whereas more than 500 nanowhiskers with an important average height of 4.6 nm for field emission applications grow on the same surface area for a sample annealed at 970 degrees C for 0 s. Selected results are presented showing the possibility of controlling the density and height of Si nanowhisker growth for field emission applications by applying different annealing temperature and duration.

Electronic conductivity studies on oxyhalide glasses containing TMO

NASA Astrophysics Data System (ADS)

Vijayatha, D.; Viswanatha, R.; Sujatha, B.; Narayana Reddy, C.

2016-05-01

Microwave-assisted synthesis is cleaner, more economical and much faster than conventional methods. The development of new routes for the synthesis of solid materials is an integral part of material science and technology. The electronic conductivity studies on xPbCl2 - 60 PbO - (40-x) V2O5 (1 ≥ x ≤ 10) glass system has been carried out over a wide range of composition and temperature (300 K to 423 K). X-ray diffraction study confirms the amorphous nature of the samples. The Scanning electron microscopic studies reveal the formation of cluster like morphology in PbCl2 containing glasses. The d.c conductivity exhibits Arrhenius behaviour and increases with V2O5 concentration. Analysis of the results is interpreted in view Austin-Mott's small polaron model of electron transport. Activation energies calculated using regression analysis exhibit composition dependent trend and the variation is explained in view of the structure of lead-vanadate glass.

Energetics of bacterial photosynthesis.

PubMed

Lebard, David N; Matyushov, Dmitry V

2009-09-10

We report the results of extensive numerical simulations and theoretical calculations of electronic transitions in the reaction center of Rhodobacter sphaeroides photosynthetic bacterium. The energetics and kinetics of five electronic transitions related to the kinetic scheme of primary charge separation have been analyzed and compared to experimental observations. Nonergodic formulation of the reaction kinetics is required for the calculation of the rates due to a severe breakdown of the system ergodicity on the time scale of primary charge separation, with the consequent inapplicability of the standard canonical prescription to calculate the activation barrier. Common to all reactions studied is a significant excess of the charge-transfer reorganization energy from the width of the energy gap fluctuations over that from the Stokes shift of the transition. This property of the hydrated proteins, breaking the linear response of the thermal bath, allows the reaction center to significantly reduce the reaction free energy of near-activationless electron hops and thus raise the overall energetic efficiency of the biological charge-transfer chain. The increase of the rate of primary charge separation with cooling is explained in terms of the temperature variation of induction solvation, which dominates the average donor-acceptor energy gap for all electronic transitions in the reaction center. It is also suggested that the experimentally observed break in the Arrhenius slope of the primary recombination rate, occurring near the temperature of the dynamical transition in proteins, can be traced back to a significant drop of the solvent reorganization energy close to that temperature.

Non-equilibrium hydrogen ionization in 2D simulations of the solar atmosphere

NASA Astrophysics Data System (ADS)

Leenaarts, J.; Carlsson, M.; Hansteen, V.; Rutten, R. J.

2007-10-01

Context: The ionization of hydrogen in the solar chromosphere and transition region does not obey LTE or instantaneous statistical equilibrium because the timescale is long compared with important hydrodynamical timescales, especially of magneto-acoustic shocks. Since the pressure, temperature, and electron density depend sensitively on hydrogen ionization, numerical simulation of the solar atmosphere requires non-equilibrium treatment of all pertinent hydrogen transitions. The same holds for any diagnostic application employing hydrogen lines. Aims: To demonstrate the importance and to quantify the effects of non-equilibrium hydrogen ionization, both on the dynamical structure of the solar atmosphere and on hydrogen line formation, in particular Hα. Methods: We implement an algorithm to compute non-equilibrium hydrogen ionization and its coupling into the MHD equations within an existing radiation MHD code, and perform a two-dimensional simulation of the solar atmosphere from the convection zone to the corona. Results: Analysis of the simulation results and comparison to a companion simulation assuming LTE shows that: a) non-equilibrium computation delivers much smaller variations of the chromospheric hydrogen ionization than for LTE. The ionization is smaller within shocks but subsequently remains high in the cool intershock phases. As a result, the chromospheric temperature variations are much larger than for LTE because in non-equilibrium, hydrogen ionization is a less effective internal energy buffer. The actual shock temperatures are therefore higher and the intershock temperatures lower. b) The chromospheric populations of the hydrogen n = 2 level, which governs the opacity of Hα, are coupled to the ion populations. They are set by the high temperature in shocks and subsequently remain high in the cool intershock phases. c) The temperature structure and the hydrogen level populations differ much between the chromosphere above photospheric magnetic elements and above quiet internetwork. d) The hydrogen n = 2 population and column density are persistently high in dynamic fibrils, suggesting that these obtain their visibility from being optically thick in Hα also at low temperature. Movie and Appendix A are only available in electronic form at http://www.aanda.org

Bi2Te3 thin hexagonal nanoplatelets: Synthesis and its characterization studies

NASA Astrophysics Data System (ADS)

Vinoth, S.; Balaganapathi, T.; KaniAmuthan, B.; Arun, T.; Muthuselvam, I. Panneer; Chou, Fang-Cheng; Thilakan, P.

2017-08-01

Solvothermal synthesis and optimization of pure Bismuth telluride (Bi2Te3) hexagonal nanoplatelets was carried out from Bismuth Oxide (Bi2O3) and Tellurium dioxide (TeO2). XRD measurements revealed a sensitive change in crystallization behaviour in correlation with variation in Te/Bi stoichiometry identified through the exchange in intensities between (10 10 ̅) and (110) peaks. Further, Energy Dispersive X-ray (EDAX) analysis revealed the variation in Te/Bi ratio with respect to autoclave temperature. Field emission scanning electron Microscope (FESEM) and the high resolution transmission electron Microscope (HRTEM) studies show the complete growth of hexagonal nanoplatelets at 200 °C. Confocal Micro-Raman measurements revealed the occurrence of symmetry breaking in the synthesized hexagonal nanoplatelets. The electrical conductivity and the activation energy were recorded as 6.01×10-3 S/m and 0.042 eV respectively. Highest maximum absolute value of Seebeck coefficient of -355 μV/K was obtained for the hexagonal nanoplatelets.

Influence of graphene quantum dots on electrical properties of polymer composites

NASA Astrophysics Data System (ADS)

Arthisree, D.; Joshi, Girish M.

2017-07-01

We successfully prepared synthetic nanocomposite (SNC) by dispersing graphene quantum dots (GQD) in cellulose acetate (CA) polymer system. The dispersion and occupied network of GQD were foreseen by microscopic techniques. The variation of plane to crossed linked array network was observed by the polarizing optical microscopic (POM) technique. The scanning electron microscopy (SEM) revealed the leaves like impressions of GQD in host polymer system. The series network of GQD occupied in CA at higher resolution was confirmed by transmission electron microscopy (TEM). The two dimensional (2D) topographic images demonstrated an entangled polymer network to plane morphology. The variation in surface roughness was evaluated from the dimensional (3D) topography. The influence of temperature on AC conductivity with highest value (4  ×  10-5 S cm-1), contributes to the decrease in activation energy. The DC conductivity obeys the percolation criteria co-related to the GQD loading by weight fraction. Furthermore, this synthetic nanocomposite is feasible for the development of sensing and electrical applications.

Mg and 18O Variations in the Shell of the Chilean Gastropod Concholepas concholepas Reflect SST and Growth Rate variations

NASA Astrophysics Data System (ADS)

Guzman, N.; Lazareth, C. E.; Poitrasson, F.; Cuif, J.; Ortlieb, L.

2004-12-01

To validate the use of fossil mollusc shells as recorders of environmental conditions, a primary calibration study was carried out on modern shells of the Chilean gastropod Concholepas concholepas, the so-called southern hemisphere abalone which is particularly abundant in Holocene archaeological sites. Organisms were maintained in culture tanks and feed with live mytilids. The sea water temperature in the tank was recorded every half-an-hour by an automatic device. The experiment lasted several months. Periodical marking with calcein provided a precise chronological control of the shell growth. Thus, well-dated high resolution chemical profiles could be directly compared with temperatures during shell formation. Geochemical analyses of the calcite layers include Mg, Sr and 16O/18O composition. Trace elements were analysed using Laser Ablation ICP-MS and Electron Microprobe while stable isotopes were measured on a Secondary Ion Mass spectrometry (SIMS). The shell growth rate during two months of formation varied between 30 and 140 µm/day which allows us to reach a temporal resolution for chemical profiles between a few hours and three days. The growth rate variations do not seem to be related to temperature fluctuations. Only Mg content was analytically reproducible and showed significant variations across the shells. The Mg high-resolution profiles display a grossly sinusoidal shape. Shells from different sites along the coasts of Chile showed mean Mg contents of 300 ppm and 500 ppm for mean temperatures of 17 and 20° C, respectively. This suggests a gross correlation between Mg and temperature. However, high resolution Mg results do not show an exact fitting neither with temperature nor with growth rates. Other parameters, like shell ageing as suggested by an amplitude increase observed near the edge of one of the shells, or other complex biological factors, may influence Mg incorporation into the shell. \\delta 18O values of the calcite vary between -1,5 and 2,0 \\permil for a temperature range between 17 and 22° C. Growth rate variations seem to be an important factor affecting the oxygen isotopic ratio within shells. When growth rate variations are limited, \\delta 18O and temperature are well correlated. The study confirms that, like for all biogenic carbonates, elemental and isotopic composition of the calcite layer of this gastropod, should not be used in paleoenvironmental reconstructions without detailed calibration experiments, and must systematically include precise growth rate analyses. The growth rhythms, which vary under the double influence of environmental and biological factors, are of paramount importance in the relationship between environmental parameters and geochemical composition of the growth layers of the shells. Work supported by "CONCHAS" Project (PNEDC).

Structural variations and dielectric properties of (Bi1-xL ax ) 2Si O5 (0 ≤x ≤0.1 ): Polycrystallines synthesized by crystallization of Bi-Si-O and Bi-La-Si-O glasses

NASA Astrophysics Data System (ADS)

Taniguchi, Hiroki; Tatewaki, Shingo; Yasui, Shintaro; Fujii, Yasuhiro; Yamaura, Jun-ichi; Terasaki, Ichiro

2018-04-01

This paper focuses on effects of isovalent La substitution on the crystal structure and dielectric properties of ferroelectric B i2Si O5 . Polycrystalline samples of (Bi1-xL ax ) 2Si O5 are synthesized by crystallization of Bi-Si-O and Bi-La-Si-O glasses with a composition range of 0 ≤x ≤0.1 . The crystal structure changes from monoclinic to tetragonal with increasing La-substitution rate x at room temperature. This structural variation stems from the change in orientation of Si O4 tetrahedra that form one-dimensional chains when they are in the ordered configuration, thus suggesting that lone-pair electrons play an important role in sustaining one-dimensional chains of Si O4 tetrahedra. Synchronizing with the disordering of Si O4 chains, ferroelectric phase transition temperature of (Bi1-xL ax ) 2Si O5 sharply decreases as x increases, and ferroelectricity finally vanishes at around x =0.03 . The present results demonstrate that lone-pair electrons of Bi play an important role in the ferroelectricity of B i2Si O5 through propping the ordered structure of one-dimensional Si O4 chains with stereochemical activity. Furthermore, an additional phase transition has been first discovered in the low-temperature region of (Bi1-xL ax ) 2Si O5 with x ≤0.01 , where the ordered one-dimensional Si O4 chains remain.

Observation of a well-defined hybridization gap and in-gap states on the SmB6 (001) surface

NASA Astrophysics Data System (ADS)

Sun, Zhixiang; Maldonado, Ana; Paz, Wendel S.; Inosov, Dmytro S.; Schnyder, Andreas P.; Palacios, J. J.; Shitsevalova, Natalya Yu.; Filipov, Vladimir B.; Wahl, Peter

2018-06-01

The rise of topology in condensed-matter physics has generated strong interest in identifying novel quantum materials in which topological protection is driven by electronic correlations. Samarium hexaboride is a Kondo insulator for which it has been proposed that a band inversion between 5 d and 4 f bands gives rise to topologically protected surface states. However, unambiguous proof of the existence and topological nature of these surface states is still missing, and its low-energy electronic structure is still not fully established. Here we present a study of samarium hexaboride by ultralow-temperature scanning tunneling microscopy and spectroscopy. We obtain clear atomically resolved topographic images of the sample surface. Our tunneling spectra reveal signatures of a hybridization gap with a size of about 8 meV and with a reduction of the differential conductance inside the gap by almost half, and surprisingly, several strong resonances below the Fermi level. The spatial variations of the energy of the resonances point toward a microscopic variation of the electronic states by the different surface terminations. High-resolution tunneling spectra acquired at 100 mK reveal a splitting of the Kondo resonance, possibly due to the crystal electric field.

Diagnostics of microwave assisted electron cyclotron resonance plasma source for surface modification of nylon 6

NASA Astrophysics Data System (ADS)

More, Supriya E.; Das, Partha Sarathi; Bansode, Avinash; Dhamale, Gayatri; Ghorui, S.; Bhoraskar, S. V.; Sahasrabudhe, S. N.; Mathe, Vikas L.

2018-01-01

Looking at the increasing scope of plasma processing of materials surface, here we present the development and diagnostics of a microwave assisted Electron Cyclotron Resonance (ECR) plasma system suitable for surface modification of polymers. Prior to the surface-treatment, a detailed diagnostic mapping of the plasma parameters throughout the reactor chamber was carried out by using single and double Langmuir probe measurements in Ar plasma. Conventional analysis of I-V curves as well as the elucidation form of the Electron Energy Distribution Function (EEDF) has become the source of calibration of plasma parameters in the reaction chamber. The high energy tail in the EEDF of electron temperature is seen to extend beyond 60 eV, at much larger distances from the ECR zone. This proves the suitability of the rector for plasma processing, since the electron energy is much beyond the threshold energy of bond breaking in most of the polymers. Nylon 6 is used as a representative candidate for surface processing in the presence of Ar, H2 + N2, and O2 plasma, treated at different locations inside the plasma chamber. In a typical case, the work of adhesion is seen to almost get doubled when treated with oxygen plasma. Morphology of the plasma treated surface and its hydrophilicity are discussed in view of the variation in electron density and electron temperature at these locations. Nano-protrusions arising from plasma treatment are set to be responsible for the hydrophobicity. Chemical sputtering and physical sputtering are seen to influence the surface morphology on account of sufficient electron energies and increased plasma potential.

Investigating the Structural, Thermal, and Electronic Properties of the Zircon-Type ZrSiO4, ZrGeO4 and HfSiO4 Compounds

NASA Astrophysics Data System (ADS)

Chiker, Fafa; Boukabrine, Fatiha; Khachai, H.; Khenata, R.; Mathieu, C.; Bin Omran, S.; Syrotyuk, S. V.; Ahmed, W. K.; Murtaza, G.

2016-11-01

In the present study, the structural, thermal, and electronic properties of some important orthosilicate dielectrics, such as the ZrSiO4, ZrGeO4, and HfSiO4 compounds, have been investigated theoretically with the use of first-principle calculations. We attribute the application of the modified Becke-Johnson exchange potential, which is basically an improvement over the local density approximation and the Perdew-Burke-Ernzerhof exchange-correlation functional, for a better description of the band gaps of the compounds. This resulted in a good agreement with our estimated values in comparison with the reported experimental data, specifically for the ZrSiO4, and HfSiO4 compounds. Conversely, for the ZrGeO4 compound, the calculated electronic band structure shows a direct band gap at the Γ point with the value of 5.79 eV. Furthermore, our evaluated thermal properties that are calculated by using the quasi-harmonic Debye model indicated that the volume variation with temperature is higher in the ZrGeO4 compound as compared to both the ZrSiO4 and HfSiO4 compounds, which is ascribed to the difference between the electron shells of the Si and Ge atoms. Therefore, these results also indicate that while the entropy ( S) and enthalpy ( U) parameters increase monotonically, the free energy ( G), in contrast, decreases monotonically with increasing temperature, respectively. Moreover, the pressure and temperature dependencies of the Debye temperature Θ, thermal expansion coefficient, and heat capacities C V were also predicted in our study.

Population decay time and distribution of exciton states analyzed by rate equations based on theoretical phononic and electron-collisional rate coefficients

NASA Astrophysics Data System (ADS)

Oki, Kensuke; Ma, Bei; Ishitani, Yoshihiro

2017-11-01

Population distributions and transition fluxes of the A exciton in bulk GaN are theoretically analyzed using rate equations of states of the principal quantum number n up to 5 and the continuum. These rate equations consist of the terms of radiative, electron-collisional, and phononic processes. The dependence of the rate coefficients on temperature is revealed on the basis of the collisional-radiative model of hydrogen plasma for the electron-collisional processes and theoretical formulation using Fermi's "golden rule" for the phononic processes. The respective effects of the variations in electron, exciton, and lattice temperatures are exhibited. This analysis is a base of the discussion on nonthermal equilibrium states of carrier-exciton-phonon dynamics. It is found that the exciton dissociation is enhanced even below 150 K mainly by the increase in the lattice temperature. When the thermal-equilibrium temperature increases, the population fluxes between the states of n >1 and the continuum become more dominant. Below 20 K, the severe deviation from the Saha-Boltzmann distribution occurs owing to the interband excitation flux being higher than the excitation flux from the 1 S state. The population decay time of the 1 S state at 300 K is more than ten times longer than the recombination lifetime of excitons with kinetic energy but without the upper levels (n >1 and the continuum). This phenomenon is caused by a shift of population distribution to the upper levels. This phonon-exciton-radiation model gives insights into the limitations of conventional analyses such as the ABC model, the Arrhenius plot, the two-level model (n =1 and the continuum), and the neglect of the upper levels.

A Ring-‘Rain’ influence for Saturn’s Cloud Albedo and Temperatures? Evidence Pro or Con from Voyager, HST, and Cassini

NASA Astrophysics Data System (ADS)

West, Robert A.; Li, Liming

2015-11-01

J. E. P. Connerney [Geophys. Res. Lett, 13, 773-776, 1986] pointed out that ‘latitudinal variations in images of Saturn’s disk, upper atmospheric temperatures, and ionospheric electron densities are found in magnetic conjugacy with features in Saturn’s ring plane’, and proposed ‘that these latitudinal variations are the result of a variable influx of water, transported along magnetic field lines from sources in Saturn’s ring plane’. Observations of H3+ support a ring-ionosphere connection [O'Donoghue et al., Nature 496, 7444, 2013]. What about cloud albedo and temperature? Connerney attributed a hemispheric asymmetry in haze and temperature to an asymmetry in water flux and predicted that ‘the presently-observed north-south asymmetry (upper tropospheric temperatures, aerosols) will persist throughout the Saturn year’. We can now test these ideas with data from the Cassini mission, from the Hubble Space Telescope, and from ground-based observations. Analyses of ground-based images and especially Hubble data established that the hemispheric asymmetry of the aerosol population does change, and seasonal effects are dominant, although non-seasonal variations are also observed [Karkoschka and Tomasko, Icarus 179, 195-221, 2005]. Upper tropospheric temperatures also vary as expected in response to seasonal forcing [Fletcher et al., Icarus 208, 337-352, 2009]. Connerney also identified dark bands in Voyager Green-filter images on magnetic conjugacy with the E ring and edges of the A and B rings. In Cassini Green-filter images there is some correspondence between dark bands and ring features in magnetic conjugacy, but collectively the correlation is not strong. Cassini 727-nm methane band images do not suggest depletion of aerosols in the upper troposphere at ring edge magnetic conjugacy latitudes as proposed by Connerney. We conclude that ring rain does not have a significant influence on upper tropospheric aerosols and temperatures on Saturn. Part of this work was performed by the Jet Propulsion Lab, Calif. Institute of Technology.

Temperature dependence of regioselectivity in nucleophilic photosubstitution of 4-nitroanisole. The activation energy criterion for regioselectivity.

PubMed

Wubbels, Gene G; Danial, Hanan; Policarpio, Danielle

2010-11-19

Photosubstitution of the nitro group vs the methoxy group of triplet 4-nitroanisole by hydroxide ion in water leads to product yields of about 80% 4-methoxyphenol and 20% 4-nitrophenol. The ratio depends slightly on temperature from 3 to 73 °C. The slight temperature variation in the yield ratio is reproduced almost perfectly with a simple Arrhenius model for a mechanism involving bonding of hydroxide ion with the triplet state of 4-nitroanisole. The competing transition states have activation energies of 2.2 and 2.6 kcal/mol, respectively. Correct prediction of regioselectivity can be done for this case by quantum chemical calculation of the competing triplet transition-state energies, or those of the corresponding triplet σ-complexes. Other models for aromatic photosubstitution regioselectivity in mechanisms of the S(N)2Ar* type, such as those based on calculated electron densities, HOMO/LUMO coefficients, or energy gap sizes, are discussed and shown to be inferior to the relative activation energies model. The photoreaction in alcohol solvents, claimed by others to generate the same products as in water and to have an exceedingly large variation of the product ratio with temperature, may reflect chemical changes other than those reported.

Characterization of Full Set Material Constants and Their Temperature Dependence for Piezoelectric Materials Using Resonant Ultrasound Spectroscopy

PubMed Central

Tang, Liguo; Cao, Wenwu

2016-01-01

During the operation of high power electromechanical devices, a temperature rise is unavoidable due to mechanical and electrical losses, causing the degradation of device performance. In order to evaluate such degradations using computer simulations, full matrix material properties at elevated temperatures are needed as inputs. It is extremely difficult to measure such data for ferroelectric materials due to their strong anisotropic nature and property variation among samples of different geometries. Because the degree of depolarization is boundary condition dependent, data obtained by the IEEE (Institute of Electrical and Electronics Engineers) impedance resonance technique, which requires several samples with drastically different geometries, usually lack self-consistency. The resonant ultrasound spectroscopy (RUS) technique allows the full set material constants to be measured using only one sample, which can eliminate errors caused by sample to sample variation. A detailed RUS procedure is demonstrated here using a lead zirconate titanate (PZT-4) piezoceramic sample. In the example, the complete set of material constants was measured from room temperature to 120 °C. Measured free dielectric constants and  were compared with calculated ones based on the measured full set data, and piezoelectric constants d15 and d33 were also calculated using different formulas. Excellent agreement was found in the entire range of temperatures, which confirmed the self-consistency of the data set obtained by the RUS. PMID:27168336

Correlation of martensitic transformation temperatures of Ni- Mn-Ga/Al-X alloys to non-bonding electron concentration

NASA Astrophysics Data System (ADS)

Ramudu, M.; Satish Kumar, A.; Seshubai, V.; Rajasekharan, T.

2015-02-01

The martensitic transformation TM of the alloys of Ni-Mn-Ga and Ni-Mn-Al show a general trend of increase with electron per atom ratio (e/a) calculated from the total number of electrons outside the rare gas shell of the atoms. However prediction of TM fails among iron substituted Ni-Mn-Ga alloys and those with In doped for Ga, due to the absence of a useful trend. A scheme of computing modified electron concentration is presented considering only the non-bonding electrons per atom Ne/a of the compounds, based on Pauling's ideas on the electronic structure of metallic elements. Systematic variation of TM with Ne/a is reproduced for a large number of alloys of Ni-Mn-Ga and the anomaly observed for Fe containing alloys with e/a disappears. The non-bonding electron concentration is thus demonstrated to be effective in predicting TM of shape memory alloys of Ni-Mn-Ga-X system including the isoelectronic compounds of Ni-Mn-Ga-In.

Effects of growth temperature on the properties of InGaN channel heterostructures grown by pulsed metal organic chemical vapor deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yachao; Zhou, Xiaowei; Xu, Shengrui

Pulsed metal organic chemical vapor deposition (P-MOCVD) is introduced into the growth of high quality InGaN channel heterostructures. The effects of InGaN channel growth temperature on the structural and transport properties of the heterostructures are investigated in detail. High resolution x-ray diffraction (HRXRD) and Photoluminescence (PL) spectra indicate that the quality of InGaN channel strongly depends on the growth temperature. Meanwhile, the atomic force microscopy (AFM) results show that the interface morphology between the InGaN channel and the barrier layer also relies on the growth temperature. Since the variation of material properties of InGaN channel has a significant influence onmore » the electrical properties of InAlN/InGaN heterostructures, the optimal transport properties can be achieved by adjusting the growth temperature. A very high two dimension electron gas (2DEG) density of 1.92 × 10{sup 13} cm{sup −2} and Hall electron mobility of 1025 cm{sup 2}/(V⋅s) at room temperature are obtained at the optimal growth temperature around 740 °C. The excellent transport properties in our work indicate that the heterostructure with InGaN channel is a promising candidate for the microwave power devices, and the results in this paper will be instructive for further study of the InGaN channel heterostructures.« less

The structure of ion-acoustic waves in a low-frequency three-component electron-ion space plasma with two-electron populations

NASA Astrophysics Data System (ADS)

Govender, G.; Moolla, S.

2018-07-01

Low-frequency ion-acoustic waves are analysed on the ion time-scale, in a three-component electron-ion space plasma. The solitary waves propagate in the positive x direction relative to an ambient magnetic field ěc {B}_0 which forms static background for a configuration consisting of cool fluid ions and both warm and hot Boltzmann-distributed electrons with temperatures T_{ic}, T_{ew} and T_{eh}, respectively. We derive linear dispersion relation for the waves by introducing first-order density, pressure and velocity perturbations into the ion fluid equations. Additionally, the variation in the nonlinear structure of the waves are investigated by carrying out a full parametric analysis utilising our numerical code. Our results reveal that ion-acoustic waves exhibit well-defined nonlinear spikes at speeds of M≥ 2.25 and an electric field amplitude of E_0=0.85. It is also shown that low wave speeds (M≤ 2), higher densities of the hot electrons, antiparallel drifting of the cool fluid ions, and increased ion temperatures all lead to significant dispersive effects. The ion-acoustic plasma waves featured in this paper have forms that are consistent with those classified as the type-A and type-B broadband electrostatic noise (BEN) observed in the data obtained from earlier satellite missions.

Ion extraction from a plasma

NASA Technical Reports Server (NTRS)

Aston, G.; Wilbur, P. J.

1981-01-01

The physical processes governing ion extraction from a plasma have been examined experimentally. The screen hole plasma sheath (the transition region wherein significant ion acceleration and complete electron retardation occurs) has been defined by equipotential plots for a variety of ion accelerator system geometries and operating conditions. It was found that the screen hole plasma sheath extends over a large distance, and influences ion and electron trajectories at least 15 Debye lengths within the discharge chamber. The electron density variation within the screen hole plasma sheath satisfied a Maxwell-Boltzmann density distribution at an effective electron temperature dependent on the discharge plasma primary-to-Maxwellian electron density ratio. Plasma ion flow up to and through the sheath was predominantly one-dimensional, and the ions entered the sheath region with a modified Bohm velocity. Low values of the screen grid thickness to screen hole diameter ratio were found to give good ion focusing and high extracted ion currents because of the effect of screen webbing on ion focusing.

LLE Review Quarterly Report (October - December 2007). Volume 113

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zuegel, Jonathan D.

2007-12-01

This volume of the LLE Review, covering October–December 2007, features “High-Intensity Laser–Plasma Interactions in the Refluxing Limit,” by P. M. Nilson, W. Theobald, J. Myatt, C. Stoeckl, M. Storm, O. V. Gotchev, J. D. Zuegel, R. Betti, D. D. Meyerhofer, and T. C. Sangster. In this article (p. 1), the authors report on target experiments using the Multi-Terawatt (MTW) Laser Facility to study isochoric heating of solid-density targets by fast electrons produced from intense, short-pulse laser irradiation. Electron refluxing occurs due to target-sheath field effects and contains most of the fast electrons within the target volume. This efficiently heats themore » solid-density plasma through collisions. X-ray spectroscopic measurements of absolute K α (x-radiation) photon yields and variations of the K β/K α b emission ratio both indicate that laser energy couples to fast electrons with a conversion efficiency of approximately 20%. Bulk electron temperatures of at least 200 eV are inferred for the smallest mass targets.« less

Dispersion of thermooptic coefficients of soda-lime-silica glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ghosh, G.

1995-01-01

The thermooptic coefficients, i.e., the variation of refractive index with temperature (dn/dT), are analyzed in a physically meaningful model for two series of soda-lime-silica glasses. 25Na{sub 2}O{center_dot}xCaO{center_dot}(75 {minus} x)SiO{sub 2} and (25 {minus} x)Na{sub 2}O{center_dot}xCaO {center_dot} 75SiO{sub 2}. This model is based on three physical parameters--the thermal expansion coefficient and excitonic and isentropic optical bands that are in the vacuum ultraviolet region--instead of on consideration of the temperature coefficient of electronic polarizability, as suggested in 1960. This model is capable of predicting and analyzing the thermooptic coefficients throughout the transmission region of the optical glasses at any operating temperature.

Spectroscopic measurements of hydrogen ion temperature during divertor recombination

NASA Astrophysics Data System (ADS)

Stotler, D. P.; Skinner, C. H.; Karney, C. F. F.

1999-01-01

We explore the possibility of using the neutral Hα spectral line profile to measure the ion temperature, Ti, in a recombining plasma. Since the Hα emissions due to recombination are larger than those due to other mechanisms, interference from nonrecombining regions contributing to the chord integrated data is insignificant. A Doppler and Stark broadened Hα spectrum is simulated by the DEGAS 2 neutral transport code using assumed plasma conditions. The application of a simple fitting procedure to this spectrum yields an electron density, ne, and Ti consistent with the assumed plasma parameters if the spectrum is dominated by recombination from a region of modest ne variation. General measurements of the ion temperature by Hα spectroscopy appear feasible within the context of a model for the entire divertor plasma.

Distribution of bacterioplankton with active metabolism in waters of the St. Anna Trough, Kara Sea, in autumn 2011

NASA Astrophysics Data System (ADS)

Mosharova, I. V.; Mosharov, S. A.; Ilinskiy, V. V.

2017-01-01

The distribution of bacterioplankton with active electron transport chains, as well as bacteria with intact cell membranes, was investigated for the first time in the region of St. Anna Trough in the Kara Sea. The average number of bacteria with active electron transport chains in the waters of the St. Anna Trough was 15.55 × 103 cells mL-1 (the limits of variation were 1.06-92.17 × 103 cells mL-1). The average number of bacteria with intact membranes was 33.46 × 103 cells mL-1 (the limits of variation were 6.78 to 103.18 × 103 cells mL-1). Almost all bacterioplankton microorganisms in the studied area were potentially viable, and the average share of bacteria with intact membranes was 92.1% of the total number of bacterioplankton (TNB) (the limits of variation were 76.2 to 98.4%). The share of bacteria with active metabolisms was 38.2% of the TNB (the limits of variation were 5.6-93.4%). The shares of the bacteria with active metabolisms were maximum in areas with the most stable environmental conditions (on the shelf and in deep water), whereas on the slope, where the gradients of water temperature and salinity were maximum, these values were lower.

Seasonal variation of water quality in a lateral hyporheic zone with response to dam operations

NASA Astrophysics Data System (ADS)

Chen, X.; Chen, L.; Zhao, J.

2015-12-01

Aquatic environment of lateral hyporheic zone in a regulated river were investigated seasonally under fluctuated water levels induced by dam operations. Groundwater levels variations in preassembled wells and changes in electronic conductivity (EC), dissolved oxygen (DO) concentration, water temperature and pH in the hyporheic zone were examined as environmental performance indicators for the water quality. Groundwater tables in wells were highly related to the river water levels that showed a hysteresis pattern, and the lag time is associated with the distances from wells to the river bank. The distribution of DO and EC were strongly related to the water temperature, indicating that the cold water released from up-reservoir could determine the biochemistry process in the hyporheic zone. Results also showed that the hyporheic water was weakly alkaline in the study area but had a more or less uniform spatial distribution. Dam release-storage cycles were the dominant factor in changing lateral hyporheic flow and water quality.

Sensitivity factor of the axial-symmetric transmission gauge: Deviation and long-term variation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takahashi, N.; Tuzi, Y.; Arakawa, I.

2007-07-15

The deviation of the sensitivity factors for about 50 sensors of the axial-symmetric transmission gauge (ATG) was examined. The deviation has been compared with that for about 30 sensors of the B-A gauge and for about 30 sensors of the extractor gauge. Almost the same deviations are found for the above three types of gauges. The long-term variations of the sensitivity factors for two sensors of the ATG were also measured during four years. After the initial change with operating time, the sensitivity factor stabilized after long-term operation. The room temperature effect of the sensitivity factor plays an important rolemore » on the total pressure measurement by an ionization gauge, but the change of the sensitivity factor was larger than the room temperature effect. The reason for the change of the factor is estimated in connection with the annealing and the alignment of the filament and with the deviation of the place of electron emission on the filament.« less

Magnetic Nonuniformity and Thermal Hysteresis of Magnetism in a Manganite Thin Film [Depth profiling of magnetization and coupling of strain with magnetization in (La 0.4Pr 0.6) 0.67Ca 0.33MnO 3 films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Surendra; Fitzsimmons, M. R.; Lookman, T.

We measured the chemical and magnetic depth profiles of a single crystalline film grown on a NdGaO 3 substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first order ferromagnetic transition at low temperatures

Magnetic nonuniformity and thermal hysteresis of magnetism in a manganite thin film.

PubMed

Singh, Surendra; Fitzsimmons, M R; Lookman, T; Thompson, J D; Jeen, H; Biswas, A; Roldan, M A; Varela, M

2012-02-17

We measured the chemical and magnetic depth profiles of a single crystalline (La(1-x)Pr(x))(1-y)Ca(y)MnO(3-δ) (x=0.52±0.05, y=0.23±0.04, δ=0.14±0.10) film grown on a NdGaO(3) substrate using x-ray reflectometry, electron microscopy, electron energy-loss spectroscopy, and polarized neutron reflectometry. Our data indicate that the film exhibits coexistence of different magnetic phases as a function of depth. The magnetic depth profile is correlated with a variation of chemical composition with depth. The thermal hysteresis of ferromagnetic order in the film suggests a first-order ferromagnetic transition at low temperatures.

First-Principles Momentum-Dependent Local Ansatz Wavefunction and Momentum Distribution Function Bands of Iron

NASA Astrophysics Data System (ADS)

Kakehashi, Yoshiro; Chandra, Sumal

2016-04-01

We have developed a first-principles local ansatz wavefunction approach with momentum-dependent variational parameters on the basis of the tight-binding LDA+U Hamiltonian. The theory goes beyond the first-principles Gutzwiller approach and quantitatively describes correlated electron systems. Using the theory, we find that the momentum distribution function (MDF) bands of paramagnetic bcc Fe along high-symmetry lines show a large deviation from the Fermi-Dirac function for the d electrons with eg symmetry and yield the momentum-dependent mass enhancement factors. The calculated average mass enhancement m*/m = 1.65 is consistent with low-temperature specific heat data as well as recent angle-resolved photoemission spectroscopy (ARPES) data.

Characterization of Anodic Aluminum Oxide Membrane with Variation of Crystallizing Temperature for pH Sensor.

PubMed

Yeo, Jin-Ho; Lee, Sung-Gap; Jo, Ye-Won; Jung, Hye-Rin

2015-11-01

We fabricated electrolyte-dielectric-metal (EDM) device incorporating a high-k Al2O3 sensing membrane from a porous anodic aluminum oxide (AAO) using a two step anodizing process for pH sensors. In order to change the properties of the AAO template, the crystallizing temperature was varied from 400 degrees C to 700 degrees C over 2 hours. The structural properties were observed by field emission scanning electron microscopy (FE-SEM). The pH sensitivity increased with an increase in the crystallizing temperature from 400 degrees C to 600 degrees C. However at 700 degrees C, deformation occurred. The porous AAO sensor with a crystallizing temperature of 600 degrees C displayed the good sensitivity and long-term stability and the values were 55.7 mV/pH and 0.16 mV/h, respectively.

Ultrasonic and metallographic studies on AISI 4140 steel exposed to hydrogen at high pressure and temperature

NASA Astrophysics Data System (ADS)

Oruganti, Malavika

This thesis conducts an investigation to study the effects of hydrogen exposure at high temperature and pressure on the behavior of AISI 4140 steel. Piezoelectric ultrasonic technique was primarily used to evaluate surface longitudinal wave velocity and defect geometry variations, as related to time after exposure to hydrogen at high temperature and pressure. Critically refracted longitudinal wave technique was used for the former and pulse-echo technique for the latter. Optical microscopy and scanning electron microscopy were used to correlate the ultrasonic results with the microstructure of the steel and to provide better insight into the steel behavior. The results of the investigation indicate that frequency analysis of the defect echo, determined using the pulse-echo technique at regular intervals of time, appears to be a promising tool for monitoring defect growth induced by a high temperature and high pressure hydrogen-related attack.

The topside ionospheric effective scale heights (HT) derived with ROCSAT-1 and ground-based Ionosonde observations at equatorial and mid-latitude stations

NASA Astrophysics Data System (ADS)

Ram Sudarsanam, Tulasi; Su, Shin-Yi; Liu, C. H.; Reinisch, Bodo

In this study, we propose the assimilation of topside in situ electron density data from ROCSAT-1 satellite along with the ionosonde measurements for accurate determination of topside iono-spheric effective scale heights (HT) using -Chapman function. The reconstructed topside elec-tron density profiles using these scale heights exhibit an excellent similitude with Jicamarca Incoherent Scatter Radar (ISR) profiles, and are much better representations than the existing methods of Reinisch-Huang method and/or the empirical IRI-2007 model. The main advan-tage with this method is that it allows the precise determination of the effective scale height (HT) and the topside electron density profiles at a dense network of ionosonde/digisonde sta-tions where no ISR facilities are available. The demonstration of the method is applied by investigating the diurnal, seasonal and solar activity variations of HT over the dip-equatorial station Jicamarca and the mid-latitude station Grahamstown. The diurnal variation of scale heights over Jicamarca consistently exhibits a morning time descent followed by a minimum around 0700-0800 LT and a pronounced maximum at noon during all the seasons of both high and moderate solar activity periods. Further, the scale heights exhibit a secondary maximum during the post-sunset hours of equinoctial and summer months, whereas the post-sunset peak is absent during the winter months. These typical features are further investigated using the topside ion properties obtained by ROCSAT-1 as well as SAMI2 model simulations. The re-sults consistently indicate that the diurnal variation of the effective scale height (HT) does not closely follow the plasma temperature variation and at equatorial latitudes is largely controlled by the vertical ExB drift.

Influence Of Secondary Electrons Produced From Plasma Material Interaction In Presence Of Crossed Electric And Magnetic Fields

NASA Astrophysics Data System (ADS)

Sawlani, Kapil; Herzog, Joshua M.; Kwak, Joowon; Foster, John

2012-10-01

The electron energy distribution function (EEDF) plays a very important role in determining thruster efficiency as it determines various gas phase reaction rates. In Hall thrusters, secondary electron emission derived from the interaction of energetic electrons with ceramic channel surfaces influence the overall shape of the EEDF as well as determine the potential difference between the plasma and wall. The role of secondary electrons on the discharge operation of Hall thrusters is poorly understood. Experimentally, determining this effect is even more taxing as the secondary electron yield (SEY) varies drastically based on many parameters such as incident electron energies, flux and impact angle, and also on the surface properties such as temperature and roughness. The electron transport is also affected by the profile of the magnetic field, which is not uniform across the length of the accelerating channel. The goal of this work is to map out the variation of the EEDF and potential profile in response to the controlled introduction of secondary electrons. This data is expected to serve as a tool to validate and improve existing numerical models by providing boundary conditions and SEY for various situations that are encountered in Hall thrusters.

Current transient spectroscopy for trapping analysis on Au-free AlGaN/GaN Schottky barrier diode

NASA Astrophysics Data System (ADS)

Hu, J.; Stoffels, S.; Lenci, S.; Bakeroot, B.; Venegas, R.; Groeseneken, G.; Decoutere, S.

2015-02-01

This paper presents a combined technique of high voltage off-state stress and current transient measurements to investigate the trapping/de-trapping characteristics of Au-free AlGaN/GaN Schottky barrier diodes. The device features a symmetric three-terminal structure with a central anode contact surrounded by two separate cathodes. Under the diode off-state stress conditions, the two separate cathodes were electrically shorted. The de-trapping dynamics was studied by monitoring the recovery of the two-dimensional electron gas (2DEG) current at different temperatures by applying 0.5 V at cathode 2 while grounding cathode 1. During the recovery, the anode contact acts as a sensor of changes in diode leakage current. This leakage variation was found to be mainly due to the barrier height variation. With this method, the energy level and capture cross section of different traps in the AlGaN/GaN Schottky barrier diode can be extracted. Furthermore, the physical location of different trapping phenomena is indicated by studying the variation of the diode leakage current during the recovery. We have identified two distinct trapping mechanisms: (i) electron trapping at the AlGaN surface in the vicinity of the Schottky contact which results in the leakage reduction (barrier height ϕB increase) together with RON degradation; (ii) the electron trapping in the GaN channel layer which partially depletes the 2DEG. The physical origin of the two different traps is discussed in the text.

A wide-band fiber optic frequency distribution system employing thermally controlled phase compensation

NASA Technical Reports Server (NTRS)

Johnson, Dean; Calhoun, Malcolm; Sydnor, Richard; Lutes, George

1993-01-01

An active wide-band fiber optic frequency distribution system employing a thermally controlled phase compensator to stabilize phase variations induced by environmental temperature changes is described. The distribution system utilizes bidirectional dual wavelength transmission to provide optical feedback of induced phase variations of 100 MHz signals propagating along the distribution cable. The phase compensation considered differs from earlier narrow-band phase compensation designs in that it uses a thermally controlled fiber delay coil rather than a VCO or phase modulation to compensate for induced phase variations. Two advantages of the wide-band system over earlier designs are (1) that it provides phase compensation for all transmitted frequencies, and (2) the compensation is applied after the optical interface rather than electronically ahead of it as in earlier schemes. Experimental results on the first prototype shows that the thermal stabilizer reduces phase variations and Allan deviation by a factor of forty over an equivalent uncompensated fiber optic distribution system.

Analysis of Fracture Mechanism for Al-Mg/SiCp Composite Materials

NASA Astrophysics Data System (ADS)

Maleque, M. A.; Adebisi, A. A.; Izzati, N.

2017-03-01

The present study aims to examine the fracture mechnism of silicon carbide particle (SiCp) reinforced aluminium matrix composite (AMC) material with 1 wt% addition of magnesium is fabricated using the stir casting process. The aluminium composite (Al-Mg/SiCp) is investigated for fatigue life and impact strength considering reinforcement weight fraction and influence of temperature on fracture toughness. The fabricated composite was tested using fatigue testing machine and charpy impact tester. Fractographic observations were evaluated with the scanning electron microscopy (SEM) on the fracture surface. It was found that increasing the SiCp weight fraction increased the fatigue life of the composite. Moreover, the 20 wt% SiCp Al-Mg composite attained the highest number of cycle and fatigue life compared to other variations. The mechanism responsible for the phenomena includes load transfer from the Al matrix alloy phase to the high strength and stiffness of the incorporated SiCp. The temperature variation influenced the impact strength of the composite and improved fracture toughness is achieved at 150 °C. It can be concluded from this study that reinforcement weight fraction and temperature affects the fracture behavior of the composites.

Capacitive wearable tactile sensor based on smart textile substrate with carbon black /silicone rubber composite dielectric

NASA Astrophysics Data System (ADS)

Guo, Xiaohui; Huang, Ying; Cai, Xia; Liu, Caixia; Liu, Ping

2016-04-01

To achieve the wearable comfort of electronic skin (e-skin), a capacitive sensor printed on a flexible textile substrate with a carbon black (CB)/silicone rubber (SR) composite dielectric was demonstrated in this paper. Organo-silicone conductive silver adhesive serves as a flexible electrodes/shielding layer. The structure design, sensing mechanism and the influence of the conductive filler content and temperature variations on the sensor performance were investigated. The proposed device can effectively enhance the flexibility and comfort of wearing the device asthe sensing element has achieved a sensitivity of 0.02536%/KPa, a hysteresis error of 5.6%, and a dynamic response time of ~89 ms at the range of 0-700 KPa. The drift induced by temperature variations has been calibrated by presenting the temperature compensation model. The research on the time-space distribution of plantar pressure information and the experiment of the manipulator soft-grasping were implemented with the introduced device, and the experimental results indicate that the capacitive flexible textile tactile sensor has good stability and tactile perception capacity. This study provides a good candidate for wearable artificial skin.

Studies Of Oxidation And Thermal Reduction Of The Cu(100) Surface Using Positron Annihilation Induced Auger Electron Spectroscopy

NASA Astrophysics Data System (ADS)

Fazleev, N. G.; Nadesalingam, M. P.; Maddox, W.; Weiss, A. H.

2011-06-01

Positron annihilation induced Auger electron spectroscopy (PAES) measurements from the surface of an oxidized Cu(100) single crystal show a large increase in the intensity of the annihilation induced Cu M2,3VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300 °C. The PAES intensity then decreases monotonically as the annealing temperature is increased to ˜550 °C. Experimental positron annihilation probabilities with Cu 3p and O 1s core electrons are estimated from the measured intensities of the positron annihilation induced Cu M2,3VV and O KLL Auger transitions. PAES results are analyzed by performing calculations of positron surface states and annihilation probabilities of the surface-trapped positrons with relevant core electrons taking into account the charge redistribution at the surface and various surface structures associated with low and high oxygen coverages. The variations in atomic structure and chemical composition of the topmost layers of the oxidized Cu(100) surface are found to affect localization and spatial extent of the positron surface state wave function. The computed positron binding energy and annihilation characteristics reveal their sensitivity to charge transfer effects, atomic structure and chemical composition of the topmost layers of the oxidized Cu(100) surface. Theoretical positron annihilation probabilities with Cu 3p and O 1s core electrons computed for the oxidized Cu(100) surface are compared with experimental ones. The obtained results provide a demonstration of thermal reduction of the copper oxide surface after annealing at 300 °C followed by re-oxidation of the Cu(100) surface at higher annealing temperatures presumably due to diffusion of subsurface oxygen to the surface.

Studies Of Oxidation And Thermal Reduction Of The Cu(100) Surface Using Positron Annihilation Induced Auger Electron Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fazleev, N. G.; Department of Physics, Kazan State University, Kazan 420008; Nadesalingam, M. P.

2011-06-01

Positron annihilation induced Auger electron spectroscopy (PAES) measurements from the surface of an oxidized Cu(100) single crystal show a large increase in the intensity of the annihilation induced Cu M2,3VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300 deg. C. The PAES intensity then decreases monotonically as the annealing temperature is increased to {approx}550 deg. C. Experimental positron annihilation probabilities with Cu 3p and O 1s core electrons are estimated from the measured intensities of the positron annihilation induced Cu M{sub 2,3}VV and O KLL Auger transitions. PAESmore » results are analyzed by performing calculations of positron surface states and annihilation probabilities of the surface-trapped positrons with relevant core electrons taking into account the charge redistribution at the surface and various surface structures associated with low and high oxygen coverages. The variations in atomic structure and chemical composition of the topmost layers of the oxidized Cu(100) surface are found to affect localization and spatial extent of the positron surface state wave function. The computed positron binding energy and annihilation characteristics reveal their sensitivity to charge transfer effects, atomic structure and chemical composition of the topmost layers of the oxidized Cu(100) surface. Theoretical positron annihilation probabilities with Cu 3p and O 1s core electrons computed for the oxidized Cu(100) surface are compared with experimental ones. The obtained results provide a demonstration of thermal reduction of the copper oxide surface after annealing at 300 deg. C followed by re-oxidation of the Cu(100) surface at higher annealing temperatures presumably due to diffusion of subsurface oxygen to the surface.« less

Millimeter-wave imaging diagnostics systems on the EAST tokamak (invited)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Y. L.; Xie, J. L., E-mail: jlxie@ustc.edu.cn; Yu, C. X.

2016-11-15

Millimeter-wave imaging diagnostics, with large poloidal span and wide radial range, have been developed on the EAST tokamak for visualization of 2D electron temperature and density fluctuations. A 384 channel (24 poloidal × 16 radial) Electron Cyclotron Emission Imaging (ECEI) system in F-band (90-140 GHz) was installed on the EAST tokamak in 2012 to provide 2D electron temperature fluctuation images with high spatial and temporal resolution. A co-located Microwave Imaging Reflectometry (MIR) will be installed for imaging of density fluctuations by December 2016. This “4th generation” MIR system has eight independent frequency illumination beams in W-band (75-110 GHz) driven bymore » fast tuning synthesizers and active multipliers. Both of these advanced millimeter-wave imaging diagnostic systems have applied the latest techniques. A novel design philosophy “general optics structure” has been employed for the design of the ECEI and MIR receiver optics with large aperture. The extended radial and poloidal coverage of ECEI on EAST is made possible by innovations in the design of front-end optics. The front-end optical structures of the two imaging diagnostics, ECEI and MIR, have been integrated into a compact system, including the ECEI receiver and MIR transmitter and receiver. Two imaging systems share the same mid-plane port for simultaneous, co-located 2D fluctuation measurements of electron density and temperature. An intelligent remote-control is utilized in the MIR electronics systems to maintain focusing at the desired radial region even with density variations by remotely tuning the probe frequencies in about 200 μs. A similar intelligent technique has also been applied on the ECEI IF system, with remote configuration of the attenuations for each channel.« less

Millimeter-wave imaging diagnostics systems on the EAST tokamak (invited)

NASA Astrophysics Data System (ADS)

Zhu, Y. L.; Xie, J. L.; Yu, C. X.; Zhao, Z. L.; Gao, B. X.; Chen, D. X.; Liu, W. D.; Liao, W.; Qu, C. M.; Luo, C.; Hu, X.; Spear, A. G.; Luhmann, N. C.; Domier, C. W.; Chen, M.; Ren, X.; Tobias, B. J.

2016-11-01

Millimeter-wave imaging diagnostics, with large poloidal span and wide radial range, have been developed on the EAST tokamak for visualization of 2D electron temperature and density fluctuations. A 384 channel (24 poloidal × 16 radial) Electron Cyclotron Emission Imaging (ECEI) system in F-band (90-140 GHz) was installed on the EAST tokamak in 2012 to provide 2D electron temperature fluctuation images with high spatial and temporal resolution. A co-located Microwave Imaging Reflectometry (MIR) will be installed for imaging of density fluctuations by December 2016. This "4th generation" MIR system has eight independent frequency illumination beams in W-band (75-110 GHz) driven by fast tuning synthesizers and active multipliers. Both of these advanced millimeter-wave imaging diagnostic systems have applied the latest techniques. A novel design philosophy "general optics structure" has been employed for the design of the ECEI and MIR receiver optics with large aperture. The extended radial and poloidal coverage of ECEI on EAST is made possible by innovations in the design of front-end optics. The front-end optical structures of the two imaging diagnostics, ECEI and MIR, have been integrated into a compact system, including the ECEI receiver and MIR transmitter and receiver. Two imaging systems share the same mid-plane port for simultaneous, co-located 2D fluctuation measurements of electron density and temperature. An intelligent remote-control is utilized in the MIR electronics systems to maintain focusing at the desired radial region even with density variations by remotely tuning the probe frequencies in about 200 μs. A similar intelligent technique has also been applied on the ECEI IF system, with remote configuration of the attenuations for each channel.

Quasi-Two-Dimensional Magnetism in Co-Based Shandites

NASA Astrophysics Data System (ADS)

Kassem, Mohamed A.; Tabata, Yoshikazu; Waki, Takeshi; Nakamura, Hiroyuki

2016-06-01

We report quasi-two-dimensional (Q2D) itinerant electron magnetism in the layered Co-based shandites. Comprehensive magnetization measurements were performed using single crystals of Co3Sn2-xInxS2 (0 ≤ x ≤ 2) and Co3-yFeySn2S2 (0 ≤ y ≤ 0.5). The magnetic parameters of both systems; the Curie temperature TC, effective moment peff and spontaneous moment ps; exhibit almost identical variations against the In- and Fe-concentrations, indicating significance of the electron count on the magnetism in the Co-based shandite. The ferromagnetic-nonmagnetic quantum phase transition is found around xc ˜ 0.8. Analysis based on the extended Q2D spin fluctuation theory clearly reveals the highly Q2D itinerant electron character of the ferromagnetism in the Co-based shandites.

Effect of pressure variation on structural, elastic, mechanical, optoelectronic and thermodynamic properties of SrNaF3 fluoroperovskite

NASA Astrophysics Data System (ADS)

Erum, Nazia; Azhar Iqbal, Muhammad

2017-12-01

The effect of pressure variation on structural, electronic, elastic, mechanical, optical and thermodynamic characteristics of cubic SrNaF3 fluoroperovskite have been investigated by employing first-principles method within the framework of gradient approximation (GGA). For the total energy calculations, we have used the full-potential linearized augmented plane wave (FP-LAPW) method. Thermodynamic properties are computed in terms of quasi-harmonic Debye model. The pressure effects are determined in the range of 0-25 GPa, in which mechanical stability of SrNaF3 fluoroperovskite remains valid. A prominent decrease in lattice constant and bonds length is observed with the increase in pressure from 0 to 25 GPa. The effect of increase in pressure on band structure calculations with GGA and GGA plus Tran-Blaha modified Becke-Johnson (TB-mBJ) potential reveals a predominant characteristic associated with widening of bandgap. The influence of pressure on set of isotropic elastic parameters and their related properties are numerically estimated for SrNaF3 polycrystalline aggregate. Apart of linear dependence of elastic coefficients, transition from brittle to ductile behavior is observed as pressure is increased from 0 to 25 GPa. We have successfully obtained variation of lattice constant, volume expansion, bulk modulus, Debye temperature and specific heat capacities with pressure and temperature in the range of 0-25 GPa and 0-600 K. All the calculated optical properties such as the complex dielectric function ɛ(ω), optical conductivity σ(ω), energy loss function L(ω), absorption coefficient α(w), refractive index n(ω), reflectivity R(ω), and effective number of electrons n eff, via sum rules shift towards the higher energies under the application of pressure.

Kinetics of the hydrogen atom abstraction reactions from 1-butanol by hydroxyl radical: theory matches experiment and more.

PubMed

Seal, Prasenjit; Oyedepo, Gbenga; Truhlar, Donald G

2013-01-17

In the present work, we study the H atom abstraction reactions by hydroxyl radical at all five sites of 1-butanol. Multistructural variational transition state theory (MS-VTST) was employed to estimate the five thermal rate constants. MS-VTST utilizes a multifaceted dividing surface that accounts for the multiple conformational structures of the transition state, and we also include all the structures of the reactant molecule. The vibrational frequencies and minimum energy paths (MEPs) were computed using the M08-HX/MG3S electronic structure method. The required potential energy surfaces were obtained implicitly by direct dynamics employing interpolated variational transition state theory with mapping (IVTST-M) using a variational reaction path algorithm. The M08-HX/MG3S electronic model chemistry was then used to calculate multistructural torsional anharmonicity factors to complete the MS-VTST rate constant calculations. The results indicate that torsional anharmonicity is very important at higher temperatures, and neglecting it would lead to errors of 26 and 32 at 1000 and 1500 K, respectively. Our results for the sums of the site-specific rate constants agree very well with the experimental values of Hanson and co-workers at 896-1269 K and with the experimental results of Campbell et al. at 292 K, but slightly less well with the experiments of Wallington et al., Nelson et al., and Yujing and Mellouki at 253-372 K; nevertheless, the calculated rates are within a factor of 1.61 of all experimental values at all temperatures. This gives us confidence in the site-specific values, which are currently inaccessible to experiment.

The effect of combination of magnetic field and low temperature on doped quantum wells

NASA Astrophysics Data System (ADS)

de P. Abreu, E.; Serra, R. M.; Emmel, P. D.

2001-10-01

In this work, we study in the optical absorption of lightly doped and compensated GaAs-GaAlAs quantum wells in the presence of applied magnetic field at low temperatures. The maximum values of magnetic field and temperature are chosen to be 10 T and 5 K, respectively. The wave functions and energies of electrons bound to impurities are calculated variationally using hydrogen-like functions. The absorption coefficient is computed through the use of Fermi golden rule and the statistics of this system is made by a self-consistent calculation of the electrostatic potential generated by ionized impurities, while the convergence parameter is the electronic chemical potential. We focus our attention on 1s→2p ± transitions. The results show that the range of frequency absorbed by the system stays unaltered in 1s→2p - transition and changes for the 1s→2p + transition, presenting a shift to higher frequencies as the magnetic field increases. Another important result is the decrease of the absorption coefficient for the lowest part of the frequency range as the temperature decreases, turning the material almost transparent for those frequencies. This kind of information may be useful for further diagnosis of quantum well systems.

Study on the Mathematical Model of Dielectric Recovery Characteristics in High Voltage SF6 Circuit Breaker

NASA Astrophysics Data System (ADS)

Lin, Xin; Wang, Feiming; Xu, Jianyuan; Xia, Yalong; Liu, Weidong

2016-03-01

According to the stream theory, this paper proposes a mathematical model of the dielectric recovery characteristic based on the two-temperature ionization equilibrium equation. Taking the dynamic variation of charged particle's ionization and attachment into account, this model can be used in collaboration with the Coulomb collision model, which gives the relationship of the heavy particle temperature and electron temperature to calculate the electron density and temperature under different pressure and electric field conditions, so as to deliver the breakdown electric field strength under different pressure conditions. Meanwhile an experiment loop of the circuit breaker has been built to measure the breakdown voltage. It is shown that calculated results are in conformity with experiment results on the whole while results based on the stream criterion are larger than experiment results. This indicates that the mathematical model proposed here is more accurate for calculating the dielectric recovery characteristic, it is derived from the stream model with some improvement and refinement and has great significance for increasing the simulation accuracy of circuit breaker's interruption characteristic. supported by Science and Technology Project of State Grid Corporation of China (No. GY17201200063), National Natural Science Foundation of China (No. 51277123), Basic Research Project of Liaoning Key Laboratory of Education Department (LZ2015055)

Dust acoustic shock waves in magnetized dusty plasma

NASA Astrophysics Data System (ADS)

Yashika, GHAI; Nimardeep, KAUR; Kuldeep, SINGH; N, S. SAINI

2018-07-01

We have presented a theoretical study of the dust acoustic (DA) shock structures in a magnetized, electron depleted dusty plasma in the presence of two temperature superthermal ions. By deriving a Korteweg–de Vries–Burgers equation and studying its shock solution, we aim to highlight the effects of magnetic field and obliqueness on various properties of the DA shock structures in the presence of kappa-distributed two temperature ion population. The present model is motivated by the observations of Geotail spacecraft in the Earth's magnetotail and it is seen that the different physical parameters such as superthermality of the cold and hot ions, the cold to hot ion temperature ratio, the magnetic field strength, obliqueness and the dust kinematic viscosity greatly influence the dynamics of the shock structures so formed. The results suggest that the variation of superthermalities of the cold and hot ions have contrasting effects on both positive and negative polarity shock structures. Moreover, it is noted that the presence of the ambient magnetic field affects the dispersive properties of the medium and tends to make the shock structures less wide and more abrupt. The findings of present investigation may be useful in understanding the dynamics of shock waves in dusty plasma environments containing two temperature ions where the electrons are significantly depleted.

Natural variations in the geomagnetically trapped electron population

NASA Technical Reports Server (NTRS)

Vampola, A. L.

1972-01-01

Temporal variations in the trapped natural electron flux intensities and energy spectra are discussed and demonstrated using recent satellite data. These data are intended to acquaint the space systems engineer with the types of natural variations that may be encountered during a mission and to augment the models of the electron environment currently being used in space system design and orbit selection. An understanding of the temporal variations which may be encountered should prove helpful. Some of the variations demonstrated here which are not widely known include: (1) addition of very energetic electrons to the outer zone during moderate magnetic storms: (2) addition of energetic electrons to the inner zone during major magnetic storms; (3) inversions in the outer zone electron energy spectrum during the decay phase of a storm injection event and (4) occasional formation of multiple maxima in the flux vs altitude profile of moderately energetic electrons.

Infrared study of the absorption edge of {beta}-InN films grown on GaN/MgO structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Perez-Caro, M.; Rodriguez, A. G.; Vidal, M. A.

2010-07-15

Infrared optical studies were carried out in a group of cubic InN samples grown by gas source molecular beam epitaxy on MgO (001) substrates. Room temperature (RT) reflectance and low-temperature (LT) transmittance measurements were performed by using fast Fourier transform infrared spectrometry. Reflectance fittings allowed to establish that {beta}-InN films have large free-carrier concentrations present (>10{sup 19} cm{sup -3}), a result that is corroborated by Hall effect measurements. Each sample explored exhibited a different optical absorption edge. The Varshni parameters that describe adequately the optical absorption edge responses with temperature are obtained for the set of samples studied. The observedmore » temperatures changes, from LT to RT, are the lowest reported for III-V semiconductor binary compounds. The temperature coefficient of the conduction band depends on the strength of the electron-phonon interaction (e-ph-i), as well as on the thermal expansion. It has been predicted that cubic InN has one of the smallest e-ph-i of all III-V compounds, which is corroborated by these results. The variation in values of absorption edges is clearly consistent with the Burstein-Moss and band renormalization effects, produced by high free electron concentrations. It is shown that the conduction band in {beta}-InN, analogous to wurtzite InN, follows a nonparabolic behavior.« less

Infrared study of the absorption edge of β-InN films grown on GaN/MgO structures

NASA Astrophysics Data System (ADS)

Pérez-Caro, M.; Rodríguez, A. G.; Vidal, M. A.; Navarro-Contreras, H.

2010-07-01

Infrared optical studies were carried out in a group of cubic InN samples grown by gas source molecular beam epitaxy on MgO (001) substrates. Room temperature (RT) reflectance and low-temperature (LT) transmittance measurements were performed by using fast Fourier transform infrared spectrometry. Reflectance fittings allowed to establish that β-InN films have large free-carrier concentrations present (>1019 cm-3), a result that is corroborated by Hall effect measurements. Each sample explored exhibited a different optical absorption edge. The Varshni parameters that describe adequately the optical absorption edge responses with temperature are obtained for the set of samples studied. The observed temperatures changes, from LT to RT, are the lowest reported for III-V semiconductor binary compounds. The temperature coefficient of the conduction band depends on the strength of the electron-phonon interaction (e-ph-i), as well as on the thermal expansion. It has been predicted that cubic InN has one of the smallest e-ph-i of all III-V compounds, which is corroborated by these results. The variation in values of absorption edges is clearly consistent with the Burstein-Moss and band renormalization effects, produced by high free electron concentrations. It is shown that the conduction band in β-InN, analogous to wurtzite InN, follows a nonparabolic behavior.

Flammability test for sunglasses: developing a system

NASA Astrophysics Data System (ADS)

Magri, Renan; Ventura, Liliane

2014-02-01

Recent investigations show the need for certificating sunglasses to ensure the safety and health to population. The Brazilian Standard ABNT NBR 15111 regulates features to sunglasses, however, there is not a sunglasses certification office in Brazil, therefore, our lab has been developing several equipment for sunglasses testing. This work refers to one of them: the flammability test system for sunglasses in compliance with the NBR 15111. The standard provides requirements for the flammability test procedure which requires that the equipment must operate at a temperature of 650 °C +/- 20 °C the end of a steel rod of 300 mm length and 6 mm diameter should be heated and pressed over the surface of the lenses for five seconds; the flammability is checked by visual inspection. The furnace is made of ceramic. We used a power electronic circuit to control the power in the furnace using ON/OFF mode and for measuring the temperature, we used a K-type thermocouple. A stepper motor with pulley lifts the steel rod. The system reaches the working temperature in 15 minutes for a step input of 61 V in open loop system. The electronics control are under development in order to shorten the time necessary to reach the working temperature and maintain the temperature variation in the furnace within the limits imposed by the standard as next steps.

Labile and recalcitrant organic matter utilization by river biofilm under increasing water temperature.

PubMed

Ylla, Irene; Romaní, Anna M; Sabater, Sergi

2012-10-01

Microbial biofilms in rivers contribute to the decomposition of the available organic matter which typically shows changes in composition and bioavailability due to their origin, seasonality, and watershed characteristics. In the context of global warming, enhanced biofilm organic matter decomposition would be expected but this effect could be specific when either a labile or a recalcitrant organic matter source would be available. A laboratory experiment was performed to mimic the effect of the predicted increase in river water temperature (+4 °C above an ambient temperature) on the microbial biofilm under differential organic matter sources. The biofilm microbial community responded to higher water temperature by increasing bacterial cell number, respiratory activity (electron transport system) and microbial extracellular enzymes (extracellular enzyme activity). At higher temperature, the phenol oxidase enzyme explained a large fraction of respiratory activity variation suggesting an enhanced microbial use of degradation products from humic substances. The decomposition of hemicellulose (β-xylosidase activity) seemed to be also favored by warmer conditions. However, at ambient temperature, the enzymes highly responsible for respiration activity variation were β-glucosidase and leu-aminopeptidase, suggesting an enhanced microbial use of polysaccharides and peptides degradation products. The addition of labile dissolved organic carbon (DOC; dipeptide plus cellobiose) caused a further augmentation of heterotrophic biomass and respiratory activity. The changes in the fluorescence index and the ratio Abs(250)/total DOC indicated that higher temperature accelerated the rates of DOC degradation. The experiment showed that the more bioavailable organic matter was rapidly cycled irrespective of higher temperature while degradation of recalcitrant substances was enhanced by warming. Thus, pulses of carbon at higher water temperature might have consequences for DOC processing.

Alterations in gill structure in tropical reef fishes as a result of elevated temperatures

PubMed Central

Bowden, A.J.; Gardiner, N.M.; Couturier, C.S.; Stecyk, J.A.W.; Nilsson, G.E.; Munday, P.L.; Rummer, J.L.

2015-01-01

Tropical regions are expected to be some of the most affected by rising sea surface temperatures (SSTs) because seasonal temperature variations are minimal. As temperatures rise, less oxygen dissolves in water, but metabolic requirements of fish and thus, the demand for effective oxygen uptake, increases. Gill remodelling is an acclimation strategy well documented in freshwater cyprinids experiencing large seasonal variations in temperature and oxygen as well as an amphibious killifish upon air exposure. However, no study has investigated whether tropical reef fishes remodel their gills to allow for increased oxygen demands at elevated temperatures. We tested for gill remodelling in five coral reef species (Acanthochromis polyacanthus, Chromis atripectoralis, Pomacentrus moluccensis, Dascyllus melanurus and Cheilodipterus quinquelineatus) from populations in northern Papua New Guinea (2° 35.765′ S; 150° 46.193′ E). Fishes were acclimated for 12-14 days to 29 and 31 °C, encompassing their seasonal range (29-31 °C), and 33 and 34 °C to account for end-of-century predicted temperatures. We measured lamellar perimeter, cross-sectional area, base thickness, and length for five filaments on the 2nd gill arches and qualitatively assessed 3rd gill arches via scanning electron microscopy (SEM). All species exhibited significant differences in the quantitative measurements made on the lamellae, but no consistent trends with temperature were observed. SEM only revealed alterations in gill morphology in P. moluccensis. The overall lack of changes in gill morphology with increasing temperature suggests that these near-equatorial reef fishes may fail to maintain adequate O2 uptake under future climate scenarios unless other adaptive mechanisms are employed. PMID:24862962

Static and dynamic protein impact on electronic properties of light-harvesting complex LH2.

PubMed

Zerlauskiene, O; Trinkunas, G; Gall, A; Robert, B; Urboniene, V; Valkunas, L

2008-12-11

A comparative analysis of the temperature dependence of the absorption spectra of the LH2 complexes from different species of photosynthetic bacteria, i.e., Rhodobacter sphaeroides, Rhodoblastus acidophilus, and Phaeospirillum molischianum, was performed in the temperature range from 4 to 300 K. Qualitatively, the temperature dependence is similar for all of the species studied. The spectral bandwidths of both B800 and B850 bands increases with temperature while the band positions shift in opposite directions: the B800 band shifts slightly to the red while the B850 band to the blue. These results were analyzed using the modified Redfield theory based on the exciton model. The main conclusion drawn from the analysis was that the spectral density function (SDF) is the main factor underlying the strength of the temperature dependence of the bandwidths for the B800 and B850 electronic transitions, while the bandwidths themselves are defined by the corresponding inhomogeneous distribution function (IDF). Slight variation of the slope of the temperature dependence of the bandwidths between species can be attributed to the changes of the values of the reorganization energies and characteristic frequencies determining the SDF. To explain the shift of the B850 band position with temperature, which is unusual for the conventional exciton model, a temperature dependence of the IDF must be postulated. This dependence can be achieved within the framework of the modified (dichotomous) exciton model. The slope of the temperature dependence of the B850 bandwidth is then defined by the value of the reorganization energy and by the difference between the transition energies of the dichotomous states of the pigment molecules. The equilibration factor between these dichotomous states mainly determines the temperature dependence of the peak shift.

Thermal-to-visible transducer (TVT) for thermal-IR imaging

NASA Astrophysics Data System (ADS)

Flusberg, Allen; Swartz, Stephen; Huff, Michael; Gross, Steven

2008-04-01

We have been developing a novel thermal-to-visible transducer (TVT), an uncooled thermal-IR imager that is based on a Fabry-Perot Interferometer (FPI). The FPI-based IR imager can convert a thermal-IR image to a video electronic image. IR radiation that is emitted by an object in the scene is imaged onto an IR-absorbing material that is located within an FPI. Temperature variations generated by the spatial variations in the IR image intensity cause variations in optical thickness, modulating the reflectivity seen by a probe laser beam. The reflected probe is imaged onto a visible array, producing a visible image of the IR scene. This technology can provide low-cost IR cameras with excellent sensitivity, low power consumption, and the potential for self-registered fusion of thermal-IR and visible images. We will describe characteristics of requisite pixelated arrays that we have fabricated.

The ionosphere of Uranus - A myriad of possibilities

NASA Astrophysics Data System (ADS)

Chandler, M. O.; Waite, J. H.

1986-01-01

A one-dimensional model has been used to study the effects of exospheric temperature, methane and water influx, ionospheric outflow, and electron precipitation on the composition and structure of the ionosphere of Uranus. Peak ion concentrations range from 1000 to 1 million per cu cm with a wide variation in peak altitude, which depends strongly on the exospheric temperature. In all the cases considered, H(+) is the major ion in the topside ionosphere. At altitudes near or below the peak, H3(+) and CH5(+) can dominate, depending on the magnitude of CH4 and H2O influx. Atomic hydrogen column depths above the methane absorbing layer exceed 10 to the 17th per sq cm and can produce large (400 R) emissions of resonantly scattered Lyman-alpha. In the sunlit polar cap, electron precipitation with energy fluxes of 0.6 to 1.0 erg/sq cm s results in direct production of Lyman-alpha emissions that exceed 1 kR.

Real-time radon monitoring at Stromboli volcano: influence of environmental parameters on 222Rn degassing

NASA Astrophysics Data System (ADS)

Cigolini, C.; Ripepe, M.; Poggi, P.; Laiolo, M.

2008-12-01

Two real-time stations for radon monitoring are currently operative at Stromboli volcano. The 222Rn electronic dosimeters are interfaced with an electronic board connected to a radiomodem for wireless data transfer (through a directional antenna) to a receiving station at the volcano observatory (COA). Radon activity data and enviromental parameters (soil temperature and atmospheric pressure) are sampled every 15 minutes and are instantaneously elaborated and transferred via web so that they can be checked in remote. Collected time series show that there is an overall inverse correlation between radon emissions and seasonal temperature variations. Signal processing analysis show that radon emissions in sectors of diffuse degassing are modulated by tidal forces as well. In addition, radon activities recorded at the summit station, located along the summit fracture zone where the gas flux is concentrated, are positively correlated with changes in atmospheric pressure and confirm the occurrence of the 'atmospheric stack effect'. It is not excluded that this process may play an active role in modulating Stromboli explosivity.

Ribosome dynamics and tRNA movement by time-resolved electron cryomicroscopy.

PubMed

Fischer, Niels; Konevega, Andrey L; Wintermeyer, Wolfgang; Rodnina, Marina V; Stark, Holger

2010-07-15

The translocation step of protein synthesis entails large-scale rearrangements of the ribosome-transfer RNA (tRNA) complex. Here we have followed tRNA movement through the ribosome during translocation by time-resolved single-particle electron cryomicroscopy (cryo-EM). Unbiased computational sorting of cryo-EM images yielded 50 distinct three-dimensional reconstructions, showing the tRNAs in classical, hybrid and various novel intermediate states that provide trajectories and kinetic information about tRNA movement through the ribosome. The structures indicate how tRNA movement is coupled with global and local conformational changes of the ribosome, in particular of the head and body of the small ribosomal subunit, and show that dynamic interactions between tRNAs and ribosomal residues confine the path of the tRNAs through the ribosome. The temperature dependence of ribosome dynamics reveals a surprisingly flat energy landscape of conformational variations at physiological temperature. The ribosome functions as a Brownian machine that couples spontaneous conformational changes driven by thermal energy to directed movement.

On the Origins of the Intercorrelations Between Solar Wind Variables

NASA Astrophysics Data System (ADS)

Borovsky, Joseph E.

2018-01-01

It is well known that the time variations of the diverse solar wind variables at 1 AU (e.g., solar wind speed, density, proton temperature, electron temperature, magnetic field strength, specific entropy, heavy-ion charge-state densities, and electron strahl intensity) are highly intercorrelated with each other. In correlation studies of the driving of the Earth's magnetosphere-ionosphere-thermosphere system by the solar wind, these solar wind intercorrelations make determining cause and effect very difficult. In this report analyses of solar wind spacecraft measurements and compressible-fluid computer simulations are used to study the origins of the solar wind intercorrelations. Two causes are found: (1) synchronized changes in the values of the solar wind variables as the plasma types of the solar wind are switched by solar rotation and (2) dynamic interactions (compressions and rarefactions) in the solar wind between the Sun and the Earth. These findings provide an incremental increase in the understanding of how the Sun-Earth system operates.

The International Reference Ionosphere - Status 2013

NASA Astrophysics Data System (ADS)

Bilitza, Dieter

2015-04-01

This paper describes the latest version of the International Reference Ionosphere (IRI) model. IRI-2012 includes new models for the electron density and ion densities in the region below the F-peak, a storm-time model for the auroral E-region, an improved electron temperature model that includes variations with solar activity, and for the first time a description of auroral boundaries. In addition, the thermosphere model required for baseline neutral densities and temperatures was upgraded from MSIS-86 to the newer NRLMSIS-00 model and Corrected Geomagnetic coordinates (CGM) were included in IRI as an additional coordinate system for a better representation of auroral and polar latitudes. Ongoing IRI activities towards the inclusion of an improved model for the F2 peak height hmF2 are discussed as are efforts to develop a "Real-Time IRI". The paper is based on an IRI status report presented at the 2013 IRI Workshop in Olsztyn, Poland. The IRI homepage is at

Methanogenesis control by employing various environmental stress conditions in two-chambered microbial fuel cells.

PubMed

Chae, Kyu-Jung; Choi, Mi-Jin; Kim, Kyoung-Yeol; Ajayi, F F; Park, Woosin; Kim, Chang-Won; Kim, In S

2010-07-01

This study examines methanogen activity in microbial fuel cells when exposed to various environmental stresses, such as oxygen, low pH, low temperature, inhibitor (2-bromoethanesulfonate (BES)), and variations in external resistance. Controlling methanogenesis resulted in an increase in Coulombic efficiency (CE) because it was a major cause of electron loss. Methane was mainly produced from aceticlastic methanogenesis, rather than by syntrophic acetate oxidation, with Methanosarcinaceae being the primary contributor. Lowering the resistance from 600 to 50 Omega reduced the methanogenic electron loss by 24%; however, changing the temperature or pH level had little effect. A BES injection was the most potent strategy for the selective inhibition of methanogens without damaging exoelectrogens. The addition of 0.1-0.27 mM BES increased the CE from 35% to 70%. Oxygen stress successfully inhibited methanogens, while slightly suppressing the exoelectrogens, and is believed to be a practical option due to its low operating cost. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

Crystal Structure Variations of Sn Nanoparticles upon Heating

NASA Astrophysics Data System (ADS)

Mittal, Jagjiwan; Lin, Kwang-Lung

2018-04-01

Structural changes in Sn nanoparticles during heating below the melting point have been investigated using differential scanning calorimetry (DSC), x-ray diffraction (XRD) analysis, electron diffraction (ED), and high-resolution transmission electron microscopy (HRTEM). DSC revealed that the heat required to melt the nanoparticles (28.43 J/g) was about half compared with Sn metal (52.80 J/g), which was attributed to the large surface energy contribution for the nanoparticles. ED and XRD analyses of the Sn nanoparticles revealed increased intensity for crystal planes having large interplaner distances compared with regular crystal planes with increasing heat treatment temperature (HTT). HRTEM revealed an increase in interlayer spacing at the surface and near joints between nanoparticles with the HTT, leading to an amorphous structure of nanoparticles at the surface at 220°C. These results highlight the changes that occur in the morphology and crystal structure of Sn nanoparticles at the surface and in the interior with increase of the heat treatment temperature.

Robust odd-parity superconductivity in the doped topological insulator Nb x Bi 2 Se 3

DOE PAGES

Smylie, M. P.; Willa, K.; Claus, H.; ...

2017-09-15

We present resistivity and magnetization measurements on proton-irradiated crystals demonstrating that the superconducting state in the doped topological insulator Nb xBi 2Se 3 (x = 0.25) is surprisingly robust against disorder-induced electron scattering. The superconducting transition temperature Tc decreases without indication of saturation with increasing defect concentration, and the corresponding scattering rates far surpass expectations based on conventional theory. The low-temperature variation of the London penetration depth Δλ(T) follows a power law [Δλ(T)~T 2] indicating the presence of symmetry-protected point nodes. Lastly, our results are consistent with the proposed robust nematic E u pairing state in this material.

Effect of Different Cooling Regimes on the Mechanical Properties of Cementitious Composites Subjected to High Temperatures

PubMed Central

Yu, Jiangtao; Weng, Wenfang; Yu, Kequan

2014-01-01

The influence of different cooling regimes (quenching in water and cooling in air) on the residual mechanical properties of engineered cementitious composite (ECC) subjected to high temperature up to 800°C was discussed in this paper. The ECC specimens are exposed to 100, 200, 400, 600, and 800°C with the unheated specimens for reference. Different cooling regimens had a significant influence on the mechanical properties of postfire ECC specimens. The microstructural characterization was examined before and after exposure to fire deterioration by using scanning electron microscopy (SEM). Results from the microtest well explained the mechanical properties variation of postfire specimens. PMID:25161392

Robust odd-parity superconductivity in the doped topological insulator NbxBi2Se3

NASA Astrophysics Data System (ADS)

Smylie, M. P.; Willa, K.; Claus, H.; Snezhko, A.; Martin, I.; Kwok, W.-K.; Qiu, Y.; Hor, Y. S.; Bokari, E.; Niraula, P.; Kayani, A.; Mishra, V.; Welp, U.

2017-09-01

We present resistivity and magnetization measurements on proton-irradiated crystals demonstrating that the superconducting state in the doped topological insulator NbxBi2Se3 (x =0.25 ) is surprisingly robust against disorder-induced electron scattering. The superconducting transition temperature Tc decreases without indication of saturation with increasing defect concentration, and the corresponding scattering rates far surpass expectations based on conventional theory. The low-temperature variation of the London penetration depth Δ λ (T ) follows a power law [Δ λ (T ) ˜T2] indicating the presence of symmetry-protected point nodes. Our results are consistent with the proposed robust nematic Eu pairing state in this material.

Calculation of the Ionization Coefficient in the Townsend Discharge in the Mixture of Argon and Mercury Vapors with Temperature-Dependent Composition

NASA Astrophysics Data System (ADS)

Bondarenko, G. G.; Dubinina, M. S.; Fisher, M. R.; Kristya, V. I.

2018-04-01

For a hybrid model of the low-current discharge considering, along with direct ionization of the mixture components by electrons, the Penning ionization of mercury atoms by metastable argon atoms, the ionization coefficient in the argon-mercury mixture used in illuminating lamps is calculated. The analytical approximation formula describing the dependence of the ionization coefficient of the mixture on the reduced electric field strength and temperature is obtained for sufficiently wide ranges of their variations, and its accuracy is estimated. It is demonstrated that the discharge ignition voltage calculated using this formula is in agreement with the results of simulation and the available experimental data.

The Io plasma torus during the Cassini encounter with Jupiter: Temporal, radial and azimuthal variations

NASA Astrophysics Data System (ADS)

Steffl, Andrew Joseph

During the Cassini spacecraft's flyby of Jupiter (1 October 2000 to 31 March 2001), the Ultraviolet Imaging Spectrograph (UVIS) produced an extensive dataset consisting of several thousand spectrally-dispersed images of the lo plasma torus. The temporal, radial, and azimuthal variability of the to plasma torus during this period are examined. The total EUV power radiated from the torus is found to be ~1.7 x 10 12 W with variations of 25%. Several events were observed during which the torus brightened by 20% over a few hours. Significant changes in the composition of the torus plasma were observed between 1 October 2000 and 11 November 2000. The composition and electron temperature of the torus plasma as a function of radial distance were derived from a scale of the midnight sector of the torus. The radial profile during the Cassini epoch shows significant differences from the Voyager era. The Io torus is found to exhibit significant azimuthal variations in ion composition. This compositional variation is observed to have a period of 10.07 hours 1.5% longer than the System III rotation period of Jupiter. While exhibiting many similar characteristics, the periodicity in the UVIS data is 1.3% shorter than the "System IV" period. The amplitude of the azimuthal variation of S II and S IV varies between 5-25% during the observing period, while the amplitude of the variation of S III and O II remains in the range of 2-5%. The amplitude of the azimuthal compositional asymmetry appears to be modulated by its location in System III longitude. The observed temporal variability is reproduced by models of the torus chemistry that include a factor of 3 increase in the rate of oxygen and sulfur atoms supplied to the extended neutral clouds that are the source of the torus plasma coupled with a ~35% increase in the amount of riot electrons in the Io torus. The observed azimuthal variability of the Io torus is well matched by models incorporating a primary source of hot electrons that slips 12.2°/day relative to the System III coordinate system and a secondary source of hot electrons that remains fixed in System III.

Observations of electron gyroharmonic waves and the structure of the Io torus. [jupiter 1 spacecraft radio astronomy experiment

NASA Technical Reports Server (NTRS)

Birmingham, T. J.; Alexander, J. K.; Desch, M. D.; Hubbard, R. F.; Pedersen, B. M.

1980-01-01

Narrow-banded emissions were observed by the Planetary Radio Astronomy experiment on the Voyager 1 spacecraft as it traversed the Io plasma torus. These waves occur between harmonics of the electron gyrofrequency and are the Jovian analogue of electrostatic emissions observed and theoretically studied for the terrestrial magnetosphere. The observed frequencies always include the component near the upper hybrid resonant frequency, (fuhr) but the distribution of the other observed emissions varies in a systematic way with position in the torus. A refined model of the electron density variation, based on identification of the fuhr line, is included. Spectra of the observed waves are analyzed in terms of the linear instability of an electron distribution function consisting of isotropic cold electrons and hot losscone electrons. The positioning of the observed auxiliary harmonics with respect to fuhr is shown to be an indicator of the cold to hot temperature ratio. It is concluded that this ratio increases systematically by an overall factor of perhaps 4 or 5 between the inner and outer portions of the torus.

High performance printed oxide field-effect transistors processed using photonic curing.

PubMed

Garlapati, Suresh Kumar; Marques, Gabriel Cadilha; Gebauer, Julia Susanne; Dehm, Simone; Bruns, Michael; Winterer, Markus; Tahoori, Mehdi Baradaran; Aghassi-Hagmann, Jasmin; Hahn, Horst; Dasgupta, Subho

2018-06-08

Oxide semiconductors are highly promising candidates for the most awaited, next-generation electronics, namely, printed electronics. As a fabrication route for the solution-processed/printed oxide semiconductors, photonic curing is becoming increasingly popular, as compared to the conventional thermal curing method; the former offers numerous advantages over the latter, such as low process temperatures and short exposure time and thereby, high throughput compatibility. Here, using dissimilar photonic curing concepts (UV-visible light and UV-laser), we demonstrate facile fabrication of high performance In 2 O 3 field-effect transistors (FETs). Beside the processing related issues (temperature, time etc.), the other known limitation of oxide electronics is the lack of high performance p-type semiconductors, which can be bypassed using unipolar logics from high mobility n-type semiconductors alone. Interestingly, here we have found that our chosen distinct photonic curing methods can offer a large variation in threshold voltage, when they are fabricated from the same precursor ink. Consequently, both depletion and enhancement-mode devices have been achieved which can be used as the pull-up and pull-down transistors in unipolar inverters. The present device fabrication recipe demonstrates fast processing of low operation voltage, high performance FETs with large threshold voltage tunability.

Recent Progress in Electronic Skin

PubMed Central

Wang, Xiandi; Dong, Lin; Zhang, Hanlu; Yu, Ruomeng; Wang, Zhong Lin

2015-01-01

The skin is the largest organ of the human body and can sense pressure, temperature, and other complex environmental stimuli or conditions. The mimicry of human skin's sensory ability via electronics is a topic of innovative research that could find broad applications in robotics, artificial intelligence, and human–machine interfaces, all of which promote the development of electronic skin (e‐skin). To imitate tactile sensing via e‐skins, flexible and stretchable pressure sensor arrays are constructed based on different transduction mechanisms and structural designs. These arrays can map pressure with high resolution and rapid response beyond that of human perception. Multi‐modal force sensing, temperature, and humidity detection, as well as self‐healing abilities are also exploited for multi‐functional e‐skins. Other recent progress in this field includes the integration with high‐density flexible circuits for signal processing, the combination with wireless technology for convenient sensing and energy/data transfer, and the development of self‐powered e‐skins. Future opportunities lie in the fabrication of highly intelligent e‐skins that can sense and respond to variations in the external environment. The rapidly increasing innovations in this area will be important to the scientific community and to the future of human life. PMID:27980911

One-dimensional time-dependent fluid model of a very high density low-pressure inductively coupled plasma

NASA Astrophysics Data System (ADS)

Chaplin, Vernon H.; Bellan, Paul M.

2015-12-01

A time-dependent two-fluid model has been developed to understand axial variations in the plasma parameters in a very high density (peak ne≳ 5 ×1019 m-3 ) argon inductively coupled discharge in a long 1.1 cm radius tube. The model equations are written in 1D with radial losses to the tube walls accounted for by the inclusion of effective particle and energy sink terms. The ambipolar diffusion equation and electron energy equation are solved to find the electron density ne(z ,t ) and temperature Te(z ,t ) , and the populations of the neutral argon 4s metastable, 4s resonant, and 4p excited state manifolds are calculated to determine the stepwise ionization rate and calculate radiative energy losses. The model has been validated through comparisons with Langmuir probe ion saturation current measurements; close agreement between the simulated and measured axial plasma density profiles and the initial density rise rate at each location was obtained at pA r=30 -60 mTorr . We present detailed results from calculations at 60 mTorr, including the time-dependent electron temperature, excited state populations, and energy budget within and downstream of the radiofrequency antenna.

High performance printed oxide field-effect transistors processed using photonic curing

NASA Astrophysics Data System (ADS)

Garlapati, Suresh Kumar; Cadilha Marques, Gabriel; Gebauer, Julia Susanne; Dehm, Simone; Bruns, Michael; Winterer, Markus; Baradaran Tahoori, Mehdi; Aghassi-Hagmann, Jasmin; Hahn, Horst; Dasgupta, Subho

2018-06-01

Oxide semiconductors are highly promising candidates for the most awaited, next-generation electronics, namely, printed electronics. As a fabrication route for the solution-processed/printed oxide semiconductors, photonic curing is becoming increasingly popular, as compared to the conventional thermal curing method; the former offers numerous advantages over the latter, such as low process temperatures and short exposure time and thereby, high throughput compatibility. Here, using dissimilar photonic curing concepts (UV–visible light and UV-laser), we demonstrate facile fabrication of high performance In2O3 field-effect transistors (FETs). Beside the processing related issues (temperature, time etc.), the other known limitation of oxide electronics is the lack of high performance p-type semiconductors, which can be bypassed using unipolar logics from high mobility n-type semiconductors alone. Interestingly, here we have found that our chosen distinct photonic curing methods can offer a large variation in threshold voltage, when they are fabricated from the same precursor ink. Consequently, both depletion and enhancement-mode devices have been achieved which can be used as the pull-up and pull-down transistors in unipolar inverters. The present device fabrication recipe demonstrates fast processing of low operation voltage, high performance FETs with large threshold voltage tunability.

Gold-Based Nanostructures for Ultrafast Dynamic Nanothermometer

NASA Astrophysics Data System (ADS)

Sun, Hongtao

Nano-scale temperature measurements are of significance for fundamental understanding of functional applications and nanosystems, requiring ultimate miniaturization of thermometers with reduced size, maintained sensitivity, simplicity and accuracy of temperature reading. Particularly, grand challenges exist for scenarios of combustion or thermal shock where materials may be subjected to drastic temperature variations and extreme thermal flux, and dynamic thermal sensors with an ultrafast response (seconds to milliseconds) are yet to be developed. Targeting the developments of advanced nano-scale thermal sensors with a fast time response and rapid readout, this thesis reports innovative designs of high surface-to-volume ratio gold nanostructures including ultrathin gold island films on transparent quartz substrates and silica-gold core-shell (SiO2 Au) nanospheres as potential dynamic thermal sensors for accurate temperature determination. The sensing mechanism is based on strong temperature dependences of the thermally-dewetting-induced morphological self-reorganization and characteristic surface plasmon (SP) absorption of the gold nanostructures. The irreversible thermally-induced morphological and optical signatures behave as characteristic "fingerprints" for temperature recording, allowing the retrieval of thermal history ex-situ. The fundamental studies of thermal-induced dewetting process and its corresponding unique optical properties were extensively investigated by high resolution scanning electron microscopy (HR-SEM), atomic force microscopy (AFM), and UV-vis-NIR spectroscopy, which illustrate temperature and time dependent variations. As compared with current nanothermometer technologies such as metal-filled nanotubes, our thermo-sensor offers positively synergistic advantages of ultrafast time response, permanent recording and fast readout of thermal history, and ex-situ capability for effective temperature measurements. In addition, SiO2 Au nanospheres display simultaneously enhanced near bandgap edge (NBE) emissions and suppress defect level emission (DLE) of poly(vinyl alcohol) (PVA) zinc oxide nanoparticles (ZnO NPs), significantly improving the UV emission of the ZnO. Maximum emission enhancement by nearly 4 times was observed using SiO2 Au nanospheres with SP band at 554 nm. The enhanced UV emission is ascribed to the transfer of the energetic electrons excited by SP from gold nanoshells to the conduction band of ZnO. As a result of their superior tunability of surface plasmon resonance (SPR), the SiO2 Au core/shell nanospheres may be very useful in tuning the photoluminescence for a wide range of optoelectronic applications.

Universal doping evolution of the superconducting gap anisotropy in single crystals of electron-doped Ba(Fe1-x Rh x )2As2 from London penetration depth measurements.

PubMed

Kim, Hyunsoo; Tanatar, M A; Martin, C; Blomberg, E C; Ni, Ni; Bud'ko, S L; Canfield, P C; Prozorov, R

2018-06-06

Doping evolution of the superconducting gap anisotropy was studied in single crystals of 4d-electron doped Ba(Fe 1-x Rh x ) 2 As 2 using tunnel diode resonator measurements of the temperature variation of the London penetration depth [Formula: see text]. Single crystals with doping levels representative of an underdoped regime x  =  0.039 ([Formula: see text] K), close to optimal doping x  =  0.057 ([Formula: see text] K) and overdoped x  =  0.079 ([Formula: see text] K) and x  =  0.131([Formula: see text] K) were studied. Superconducting energy gap anisotropy was characterized by the exponent, n, by fitting the data to the power-law, [Formula: see text]. The exponent n varies non-monotonically with x, increasing to a maximum n  =  2.5 for x  =  0.079 and rapidly decreasing towards overdoped compositions to 1.6 for x  =  0.131. This behavior is qualitatively similar to the doping evolution of the superconducting gap anisotropy in other iron pnictides, including hole-doped (Ba,K)Fe 2 As 2 and 3d-electron-doped Ba(Fe,Co) 2 As 2 superconductors, finding a full gap near optimal doping and strong anisotropy toward the ends of the superconducting dome in the T-x phase diagram. The normalized superfluid density in an optimally Rh-doped sample is almost identical to the temperature-dependence in the optimally doped Ba(Fe,Co) 2 As 2 samples. Our study supports the universal superconducting gap variation with doping and [Formula: see text] pairing at least in iron based superconductors of the BaFe 2 As 2 family.

Universal doping evolution of the superconducting gap anisotropy in single crystals of electron-doped Ba(Fe 1–xRh x) 2As 2 from London penetration depth measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Hyunsoo; Tanatar, M. A.; Martin, C.

Doping evolution of the superconducting gap anisotropy was studied in single crystals of 4d-electron doped Ba(Fe 1–xRh x) 2As 2 using tunnel diode resonator measurements of the temperature variation of the London penetration depth Δλ( T). Single crystals with doping levels representative of an underdoped regime x = 0.039 ( T c = 15.5 K), close to optimal doping x = 0.057 ( T c = 24.4 K) and overdoped x = 0.079 ( T c = 21.5 K) and x = 0.131( T c = 4.9 K) were studied. Superconducting energy gap anisotropy was characterized by the exponent, n,more » by fitting the data to the power-law, Δλ = AT n. The exponent n varies non-monotonically with x, increasing to a maximum n = 2.5 for x = 0.079 and rapidly decreasing towards overdoped compositions to 1.6 for x = 0.131. This behavior is qualitatively similar to the doping evolution of the superconducting gap anisotropy in other iron pnictides, including hole-doped (Ba,K)Fe 2As 2 and 3d-electron-doped Ba(Fe,Co) 2As 2 superconductors, finding a full gap near optimal doping and strong anisotropy toward the ends of the superconducting dome in the T-x phase diagram. The normalized superfluid density in an optimally Rh-doped sample is almost identical to the temperature-dependence in the optimally doped Ba(Fe,Co) 2As 2 samples. In conclusion, our study supports the universal superconducting gap variation with doping and pairing at least in iron based superconductors of the BaFe 2As 2 family.« less

A Non-thermal Pulsed X-Ray Emission of AR Scorpii

NASA Astrophysics Data System (ADS)

Takata, J.; Hu, C.-P.; Lin, L. C. C.; Tam, P. H. T.; Pal, P. S.; Hui, C. Y.; Kong, A. K. H.; Cheng, K. S.

2018-02-01

We report the analysis result of UV/X-ray emission from AR Scorpii, which is an intermediate polar (IP) composed of a magnetic white dwarf and an M-type star, with the XMM-Newton data. The X-ray/UV emission clearly shows a large variation over the orbit, and their intensity maximum (or minimum) is located at the superior conjunction (or inferior conjunction) of the M star orbit. The hardness ratio of the X-ray emission shows a small variation over the orbital phase and shows no indication of the absorption by an accretion column. These properties are naturally explained by the emission from the M star surface rather than that from the accretion column on the white dwarf’s (WD) star, which is similar to usual IPs. Additionally, the observed X-ray emission also modulates with the WD’s spin with a pulse fraction of ∼14%. The peak position is aligned in the optical/UV/X-ray band. This supports the hypothesis that the electrons in AR Scorpii are accelerated to a relativistic speed and emit non-thermal photons via the synchrotron radiation. In the X-ray bands, evidence of the power-law spectrum is found in the pulsed component, although the observed emission is dominated by the optically thin thermal plasma emissions with several different temperatures. It is considered that the magnetic dissipation/reconnection process on the M star surface heats up the plasma to a temperature of several keV and also accelerates the electrons to the relativistic speed. The relativistic electrons are trapped in the WD’s closed magnetic field lines by the magnetic mirror effect. In this model, the observed pulsed component is explained by the emissions from the first magnetic mirror point.

Universal doping evolution of the superconducting gap anisotropy in single crystals of electron-doped Ba(Fe 1–xRh x) 2As 2 from London penetration depth measurements

DOE PAGES

Kim, Hyunsoo; Tanatar, M. A.; Martin, C.; ...

2018-05-08

Doping evolution of the superconducting gap anisotropy was studied in single crystals of 4d-electron doped Ba(Fe 1–xRh x) 2As 2 using tunnel diode resonator measurements of the temperature variation of the London penetration depth Δλ( T). Single crystals with doping levels representative of an underdoped regime x = 0.039 ( T c = 15.5 K), close to optimal doping x = 0.057 ( T c = 24.4 K) and overdoped x = 0.079 ( T c = 21.5 K) and x = 0.131( T c = 4.9 K) were studied. Superconducting energy gap anisotropy was characterized by the exponent, n,more » by fitting the data to the power-law, Δλ = AT n. The exponent n varies non-monotonically with x, increasing to a maximum n = 2.5 for x = 0.079 and rapidly decreasing towards overdoped compositions to 1.6 for x = 0.131. This behavior is qualitatively similar to the doping evolution of the superconducting gap anisotropy in other iron pnictides, including hole-doped (Ba,K)Fe 2As 2 and 3d-electron-doped Ba(Fe,Co) 2As 2 superconductors, finding a full gap near optimal doping and strong anisotropy toward the ends of the superconducting dome in the T-x phase diagram. The normalized superfluid density in an optimally Rh-doped sample is almost identical to the temperature-dependence in the optimally doped Ba(Fe,Co) 2As 2 samples. In conclusion, our study supports the universal superconducting gap variation with doping and pairing at least in iron based superconductors of the BaFe 2As 2 family.« less

Universal doping evolution of the superconducting gap anisotropy in single crystals of electron-doped Ba(Fe1‑x Rh x )2As2 from London penetration depth measurements

NASA Astrophysics Data System (ADS)

Kim, Hyunsoo; Tanatar, M. A.; Martin, C.; Blomberg, E. C.; Ni, Ni; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

2018-06-01

Doping evolution of the superconducting gap anisotropy was studied in single crystals of 4d-electron doped Ba(Fe1‑x Rh x )2As2 using tunnel diode resonator measurements of the temperature variation of the London penetration depth . Single crystals with doping levels representative of an underdoped regime x  =  0.039 ( K), close to optimal doping x  =  0.057 ( K) and overdoped x  =  0.079 ( K) and x  =  0.131( K) were studied. Superconducting energy gap anisotropy was characterized by the exponent, n, by fitting the data to the power-law, . The exponent n varies non-monotonically with x, increasing to a maximum n  =  2.5 for x  =  0.079 and rapidly decreasing towards overdoped compositions to 1.6 for x  =  0.131. This behavior is qualitatively similar to the doping evolution of the superconducting gap anisotropy in other iron pnictides, including hole-doped (Ba,K)Fe2As2 and 3d-electron-doped Ba(Fe,Co)2As2 superconductors, finding a full gap near optimal doping and strong anisotropy toward the ends of the superconducting dome in the T-x phase diagram. The normalized superfluid density in an optimally Rh-doped sample is almost identical to the temperature-dependence in the optimally doped Ba(Fe,Co)2As2 samples. Our study supports the universal superconducting gap variation with doping and pairing at least in iron based superconductors of the BaFe2As2 family.

Observational investigation of ionospheric turbulent spectral content in relation to geomagnetic field variations and local seismicity

NASA Astrophysics Data System (ADS)

Contadakis, M. E.; Arambelos, D.; Asteriadis, G.; Pikridas, Ch.; Spatalas, S.; Chatzinikos, M.

2006-04-01

Atmospheric and underground explosions as well as shallow earthquakes producing strong vertical ground displacement, are known to produce pressure waves that propagates at infrasonic speeds in the atmosphere. At ionospheric altitudes these waves are coupled to ionospheric gravity waves and induce variations in the ionospheric electron density. On the other hand local lithospheric density, ion inhalation, temperature or electromagnetic field variations, produced by the local tectonic activity during the earthquake preparation period, induces near surface atmospheric variations and affect the ionospheric density through the Lithospher-Atmosphere- Ionosphere Coupling. That is the lithospheric near surface tectonic activity results to local pre- co- and post seismic disturbances on the ionospheric Total Electron Content (TEC). Nevertheless these disturbances are mixed with disturbances induced to the ionospher by a number of agents such as tropospheric jets, magnetic storms and sub-storms, solar activity, ionosphere-magnetosphere coupling etc, and a major problem is to discriminate the influence of those agents from the influence of the local tectonic activity. In this paper we present the results of the wavelet analysis of TVEC variations over a network of 4 GPS stations, depicted from EUREF-EPN network, covering the whole area of Greece. Our results indicate that 1) Disturbances with period higher than 3 hours have a Universal origin i.e. earth-tides, Aurora or Equatorial anomaly. 2) Disturbances with periods equal or smaller than 3 hours are of local origin. 3) Strong Variations of geomagnetic field affect the disturbances of all periods. 4) Disturbances with period 3 hours present a good coherency in the measurements of more than one GPS stations. In concluding disturbances with period equal or less than 3 hours are suitable for de

Spatial variations of the local density of states modified by CDWs in 1 T- TaS2- xSex

NASA Astrophysics Data System (ADS)

Hasegawa, T.; Yamaguchi, W.; Kim, J.-J.; Wei, W.; Nantoh, M.; Ikuta, H.; Kitazawa, K.; Manivannan, A.; Fujishima, A.; Uchinokura, K.

1994-07-01

Spatial variations of the local density of states (LDOS) near the Fermi level have been observed on the layered dichalcogenides 1 T- TaS2- xSex ( x = 0, 0.2, 2) for the first time. The tunneling spectra on the cleaved surfaces were measured by atomic-site tunneling (AST) spectroscopy technique at room temperature. In 1T-TaS 2, the LDOS was substantially different among the three inequivalent Ta atomic sites induced by the CDW formation. However, the surface electronic structure became homogeneous, as the Se content was increased. By substituting Se for S, the minimum position of the LDOS was systematically shifted to a higher energy side above the Fermi level.

High-Temperature and High-Pressure Study of Electronic and Thermal Properties of PbTaO3 and SnAlO3 Metal Perovskites by Density Functional Theory Calculations

NASA Astrophysics Data System (ADS)

Khandy, Shakeel Ahmad; Islam, Ishtihadah; Ganai, Zahid Saleem; Gupta, Dinesh C.; Parrey, Khursheed Ahmad

2018-01-01

First principles calculations on the thermodynamic properties of PbTaO3 and SnAlO3 in a temperature range from 0 K to 800 K and pressure range from 0 GPa to 30 GPa have been carried out within the framework of density functional theory (DFT). The band structures of these oxides at different pressures display an increase in metallic character with a concomitant decrease in lattice constants, while the bulk modulus increases with increasing pressure. The thermal concert of these materials has been analyzed in terms of the temperature and pressure variation in Debye temperature, thermal expansion, entropy, and the Grüneisen parameter. Debye temperatures have been calculated from the elastic parameters as well as the quasi-harmonic Debye model, which are 339.07 GPa for PbTaO3 and 714.36 GPa for SnAlO3.

Conduction in Carbon Nanotubes Through Metastable Resonant States

NASA Astrophysics Data System (ADS)

Zhang, Zhengfan; Chandrasekhar, Venkat; Dikin, Dmitriy A.; Ruoff, Rodney S.

2004-03-01

We have made transport measurements on individual multi-walled carbon nanotubes [1]. The measurements show that the presence or movement of impurities or defects in the carbon nanotube can radically change its low temperature transport characteristics. The low temperature conductance can either decrease monotonically with decreasing temperature, or show a sudden increase at very low temperatures, sometimes in the same sample. This unusual behavior of the temperature dependence of the conductance is correlated with large variations in the differential conductance as a function of the dc voltage across the wire. The effect is well described as arising from quantum interference of conduction channels corresponding to direct transmission through the nanotube and resonant transmission through a discrete electron state, the so-called Fano resonance. We thank the group of R. P. H. Chang for providing us the nanotubes used in these experiments. Funding for this work was provided by a NASA/MSFC Phase II SBIR, Contract No. NAS8-02102, through a subcontract from Lytec, LLC. [1] Z. Zhang et al., cond-mat/0311360.

M-H characteristics and demagnetization resistance of samarium-cobalt permanent magnets to 300 C

NASA Technical Reports Server (NTRS)

Niedra, J. M.

1992-01-01

The influence of temperature on the M-H demagnetization characteristics of permanent magnets is important information for the full utilization of the capabilities of samarium-cobalt magnets at high temperatures in demagnetization-resistant permanent magnet devices. In high temperature space power converters, such as free-piston Stirling engine driven linear alternators, magnet demagnetization can occur as long-term consequence of thermal agitation of domains and of metallurgical change, and also as an immediate consequence of too large an applied field. Investigated here is the short-term demagnetization resistance to applied fields derived from basic M-H data. These quasistatic demagnetization data were obtained for commercial, high-intrinsic-coercivity, Sm2Co17-type magnets from 5 sources, in the temperature range 23 to 300 C. An electromagnet driven, electronic hysteresigraph was used to test the 1-cm cubic samples. The observed variation of the 2nd quadrant M-H characteristics was a typical rapid loss of M-coercivity and a relatively lesser loss of remanence with increasing temperature.

Low-Temperature Photochemically Activated Amorphous Indium-Gallium-Zinc Oxide for Highly Stable Room-Temperature Gas Sensors.

PubMed

Jaisutti, Rawat; Kim, Jaeyoung; Park, Sung Kyu; Kim, Yong-Hoon

2016-08-10

We report on highly stable amorphous indium-gallium-zinc oxide (IGZO) gas sensors for ultraviolet (UV)-activated room-temperature detection of volatile organic compounds (VOCs). The IGZO sensors fabricated by a low-temperature photochemical activation process and exhibiting two orders higher photocurrent compared to conventional zinc oxide sensors, allowed high gas sensitivity against various VOCs even at room temperature. From a systematic analysis, it was found that by increasing the UV intensity, the gas sensitivity, response time, and recovery behavior of an IGZO sensor were strongly enhanced. In particular, under an UV intensity of 30 mW cm(-2), the IGZO sensor exhibited gas sensitivity, response time and recovery time of 37%, 37 and 53 s, respectively, against 750 ppm concentration of acetone gas. Moreover, the IGZO gas sensor had an excellent long-term stability showing around 6% variation in gas sensitivity over 70 days. These results strongly support a conclusion that a low-temperature solution-processed amorphous IGZO film can serve as a good candidate for room-temperature VOCs sensors for emerging wearable electronics.

Fluorescence and room temperature activity of Y₂O₃:(Eu³⁺,Au³⁺)/palygorskite nanocomposite.

PubMed

He, Xi; Yang, Huaming

2015-01-28

The fluorescence and room temperature activity of a palygorskite supported Y2O3:(Eu(3+),Au(3+)) nanocomposite were investigated to design a fluorescence-indicated catalyst. The effects of Au(3+) doping on the structure and surface properties of the host material were systematically characterized. The fluorescence intensity of Y2O3:Eu(3+) was affected by Au(3+) doping, which was related to the crystallinity of Y2O3. Excess Au(3+) ions were segregated to the host surface and reduced to metallic Au. The local symmetry of Eu(3+) was reduced by Au(3+) doping, which benefited the energy transfer between Eu(3+) and Au(3+). Energy absorbed by Eu(3+) was transferred from Au(3+) to metallic Au, where electrons were produced. These electrons were absorbed by O2 to change into O2(-), which acted as the oxidant for ortho-dichlorobenzene (o-DCB). The variation of fluorescence intensity during the catalytic reaction was observed. The room temperature catalytic activity of the nanocomposite under UV irradiation was revealed. The as-synthesized nanocomposite might have potential applications in environmental fields.

Characterization and frequency-thermal response of electrical properties of Cu nanoferrite prepared by sol-gel method

NASA Astrophysics Data System (ADS)

Moghadasi, Fatemeh S.; Daadmehr, Vahid; Kashfi, Monire

2016-10-01

In this paper, we have synthesized copper ferrite nanocrystals using sol-gel method. X-ray diffraction (XRD) analysis confirms that the ferrite has cubic spinal structure and shows Jahn-Teller effect. Also, scan electron microscope (SEM) image demonstrates that grains are nano size order. We showed that the dielectric properties are compatible with the Maxwell-Wagner model and phenomenological Koop's theory. Loss tangent and conductivity of the ferrite have been measured to have small values of 2.4 and 2×10-7 S/m, respectively at room temperature and at 12 Hz. Conductivity has been investigated in terms of localized hopping mechanism and good obedience of Jonscher's law was observed. Variation of activation energy was studied and showed a transition temperature of 443 °K. The electrical modulus shows relaxation of interfacial polarization with relaxation time of 0.318 ms at 24 °C and 15.9 μs at 72 °C. In Impedance spectroscopy, we observed the effects of grain and grain boundary. By increasing temperature, capacity and conduction would increase which show easier polarization process and a semiconducting behavior. Also, relaxation times are shifted to smaller values to represent increasing the electrons mobility.

Variational theory of valence fluctuations: Ground states and quasiparticle excitations of the Anderson lattice model

NASA Astrophysics Data System (ADS)

Brandow, B. H.

1986-01-01

A variational study of ground states of the orbitally nondegenerate Anderson lattice model, using a wave function with one variational parameter per Bloch state k, has been extended to deal with essentially metallic systems having a nonintegral number of electrons per site. Quasiparticle excitations are obtained by direct appeal to Landau's original definition for interacting Fermi liquids, scrEqp(k,σ)=δEtotal/δn qp(k,σ). This approach provides a simple and explicit realization of the Luttinger picture of a periodic Fermi liquid. A close correspondence is maintained between the ``interacting'' (U=∞) system and the corresponding ``noninteracting'' (U=0) case, i.e., ordinary band theory; the result can be described as a renormalized band or renormalized hybridization theory. The occupation-number distribution for the conduction orbitals displays a finite discontinuity at the Fermi surface. If the d-f hybridization is nonzero throughout the Brillouin zone, the quasiparticle spectrum will always exhibit a gap, although this gap becomes exponentially small (i.e., of order TK) in the Kondo-lattice regime. In the ``ionic'' case with precisely two electrons per site, such a system may therefore exhibit an insulating (semiconducting) gap. The quasiparticle state density exhibits a prominent spike on each side of the spectral gap, just as in the elementary hybridization model (the U=0 case). For the metallic case, with a nonintegral number of electrons per site, the Fermi level falls within one of the two sharp density peaks. The effective mass at the Fermi surface tends to be very large; enhancements by a factor >~102 are quite feasible. The foregoing variational theory has also been refined by means of a trial wave function having two variational parameters per Bloch state k. The above qualitative features are all retained, with some quantitative differences, but there are also some qualitatively new features. The most interesting of these is the appearance, within the Kondo regime, of a significant quasiparticle contribution to the f spectral weight in the vicinity of ɛf. The present ``one-parameter'' and ``two-parameter'' versions can be viewed as lattice generalizations of the first two approximations of the (1/Nf)-expansion school, although our treatment of lattice aspects departs from strict 1/Nf methodology. The two versions have Wilson ratios ≡1 and ≠1, respectively, consistent with (1/Nf)-expansion studies of the single-impurity model, and a number of other features likewise show good correspondence with (1/Nf)-expansion results. Implications are presented for the finite-temperature behaviors of several properties, especially the specific heat and electrical resistivity. Comparison with experiment then leads to some inferences about the band structures of heavy-fermion materials. A new mechanism is presented for breakup of the coherent Fermi-liquid behavior, as temperature is increased. There are two main approximations: (a) Neglect of the ``site exclusion'' problem, i.e., within cluster-expansion terms we ignore the requirement that interacting sites must all be distinct. (b) Assumption of a low density of excited quasiparticles (those excited from the ``far'' side of the hybridization gap) limits the present treatment to very low temperatures, T<

A Measurable Difference: Bridge Versus Loop

NASA Technical Reports Server (NTRS)

1998-01-01

Trig-Tek, Inc.'s Model 251A ACL-8 Anderson Current Loop (ACL) Conditioner is an eight channel device designed to condition variable-resistant sensor signals from Strain Gage and RTD's (Resistance Temperature Device)s. It uses NASA's patented ACL technology instead of the classic wheatstone bridge. The electronic measurement circuit delivers accuracy far beyond previous methods and prevents errors caused by variation in the wires that connect sensors to data collection equipment. This is the first license to market a NASA Dryden Flight Research Center patent.

Experimental Evidence for Quantum Interference and Vibrationally Induced Decoherence in Single-Molecule Junctions

NASA Astrophysics Data System (ADS)

Ballmann, Stefan; Härtle, Rainer; Coto, Pedro B.; Elbing, Mark; Mayor, Marcel; Bryce, Martin R.; Thoss, Michael; Weber, Heiko B.

2012-08-01

We analyze quantum interference and decoherence effects in single-molecule junctions both experimentally and theoretically by means of the mechanically controlled break junction technique and density-functional theory. We consider the case where interference is provided by overlapping quasidegenerate states. Decoherence mechanisms arising from electronic-vibrational coupling strongly affect the electrical current flowing through a single-molecule contact and can be controlled by temperature variation. Our findings underline the universal relevance of vibrations for understanding charge transport through molecular junctions.

Experimental evidence for quantum interference and vibrationally induced decoherence in single-molecule junctions.

PubMed

Ballmann, Stefan; Härtle, Rainer; Coto, Pedro B; Elbing, Mark; Mayor, Marcel; Bryce, Martin R; Thoss, Michael; Weber, Heiko B

2012-08-03

We analyze quantum interference and decoherence effects in single-molecule junctions both experimentally and theoretically by means of the mechanically controlled break junction technique and density-functional theory. We consider the case where interference is provided by overlapping quasidegenerate states. Decoherence mechanisms arising from electronic-vibrational coupling strongly affect the electrical current flowing through a single-molecule contact and can be controlled by temperature variation. Our findings underline the universal relevance of vibrations for understanding charge transport through molecular junctions.

Effects of the major sudden stratospheric warming event of 2009 on the subionospheric very low frequency/low frequency radio signals

NASA Astrophysics Data System (ADS)

Pal, S.; Hobara, Y.; Chakrabarti, S. K.; Schnoor, P. W.

2017-07-01

This paper presents effects of the major sudden stratospheric warming (SSW) event of 2009 on the subionospheric very low frequency/low frequency (VLF/LF) radio signals propagating in the Earth-ionosphere waveguide. Signal amplitudes from four transmitters received by VLF/LF radio networks of Germany and Japan corresponding to the major SSW event are investigated for possible anomalies and atmospheric influence on the high- to middle-latitude ionosphere. Significant anomalous increase or decrease of nighttime and daytime amplitudes of VLF/LF signals by ˜3-5 dB during the SSW event have been found for all propagation paths associated with stratospheric temperature rise at 10 hPa level. Increase or decrease in VLF/LF amplitudes during daytime and nighttime is actually due to the modification of the lower ionospheric boundary conditions in terms of electron density and electron-neutral collision frequency profiles and associated modal interference effects between the different propagating waveguide modes during the SSW period. TIMED/SABER mission data are also used to investigate the upper mesospheric conditions over the VLF/LF propagation path during the same time period. We observe a decrease in neutral temperature and an increase in pressure at the height of 75-80 km around the peak time of the event. VLF/LF anomalies are correlated and in phase with the stratospheric temperature and mesospheric pressure variation, while minimum of mesospheric cooling shows a 2-3 day delay with maximum VLF/LF anomalies. Simulations of VLF/LF diurnal variation are performed using the well-known Long Wave Propagating Capability (LWPC) code within the Earth-ionosphere waveguide to explain the VLF/LF anomalies qualitatively.

Dependence of Coulomb Sum Rule on the Short Range Correlation by Using Av18 Potential

NASA Astrophysics Data System (ADS)

Modarres, M.; Moeini, H.; Moshfegh, H. R.

The Coulomb sum rule (CSR) and structure factor are calculated for inelastic electron scattering from nuclear matter at zero and finite temperature in the nonrelativistic limit. The effect of short-range correlation (SRC) is presented by using lowest order constrained variational (LOCV) method and the Argonne Av18 and Δ-Reid soft-core potentials. The effects of different potentials as well as temperature are investigated. It is found that the nonrelativistic version of Bjorken scaling approximately sets in at the momentum transfer of about 1.1 to 1.2 GeV/c and the increase of temperature makes it to decrease. While different potentials do not significantly change CSR, the SRC improves the Coulomb sum rule and we get reasonably close results to both experimental data and others theoretical predictions.

Effects of temperature variability on community structure in a natural microbial food web.

PubMed

Zander, Axel; Bersier, Louis-Félix; Gray, Sarah M

2017-01-01

Climate change research has demonstrated that changing temperatures will have an effect on community-level dynamics by altering species survival rates, shifting species distributions, and ultimately, creating mismatches in community interactions. However, most of this work has focused on increasing temperature, and still little is known about how the variation in temperature extremes will affect community dynamics. We used the model aquatic community held within the leaves of the carnivorous plant, Sarracenia purpurea, to test how food web dynamics will be affected by high temperature variation. We tested the community response of the first (bacterial density), second (protist diversity and composition), and third trophic level (predator mortality), and measured community respiration. We collected early and late successional stage inquiline communities from S. purpurea from two North American and two European sites with similar average July temperature. We then created a common garden experiment in which replicates of these communities underwent either high or normal daily temperature variation, with the average temperature equal among treatments. We found an impact of temperature variation on the first two, but not on the third trophic level. For bacteria in the high-variation treatment, density experienced an initial boost in growth but then decreased quickly through time. For protists in the high-variation treatment, alpha-diversity decreased faster than in the normal-variation treatment, beta-diversity increased only in the European sites, and protist community composition tended to diverge more in the late successional stage. The mortality of the predatory mosquito larvae was unaffected by temperature variation. Community respiration was lower in the high-variation treatment, indicating a lower ecosystem functioning. Our results highlight clear impacts of temperature variation. A more mechanistic understanding of the effects that temperature, and especially temperature variation, will have on community dynamics is still greatly needed. © 2016 John Wiley & Sons Ltd.

Collapse of ferromagnetism in itinerant-electron system: A magnetic, transport properties, and high pressure study of (Hf,Ta)Fe2 compounds

NASA Astrophysics Data System (ADS)

Diop, L. V. B.; Kastil, J.; Isnard, O.; Arnold, Z.; Kamarad, J.

2014-10-01

The magnetism and transport properties were studied for Laves (Hf,Ta)Fe2 itinerant-electron compounds, which exhibit a temperature-induced first-order transition from the ferromagnetic (FM) to the antiferromagnetic (AFM) state upon heating. At finite temperatures, the field-induced metamagnetic phase transition between the AFM and FM has considerable effects on the transport properties of these model metamagnetic compounds. A large negative magnetoresistance of about 14% is observed in accordance with the metamagnetic transition. The magnetic phase diagram is determined for the Laves Hf1-xTaxFe2 series and its Ta concentration dependence discussed. An unusual behavior is revealed in the paramagnetic state of intermediate compositions, it gives rise to the rapid increase and saturation of the local spin fluctuations of the 3d electrons. This new result is analysed in the frame of the theory of Moriya. For a chosen composition Hf0.825Ta0.175Fe2, exhibiting such remarkable features, a detailed investigation is carried out under hydrostatic pressure up to 1 GPa in order to investigate the volume effect on the magnetic properties. With increasing pressure, the magnetic transition temperature TFM-AFM from ferromagnetic to antiferromagnetic order decreases strongly non-linearly and disappears at a critical pressure of 0.75 GPa. In the pressure-induced AFM state, the field-induced first-order AFM-FM transition appears and the complex temperature dependence of the AFM-FM transition field is explained by the contribution from both the magnetic and elastic energies caused by the significant temperature variation of the amplitude of the local Fe magnetic moment. The application of an external pressure leads also to the progressive decrease of the Néel temperature TN. In addition, a large pressure effect on the spontaneous magnetization MS for pressures below 0.45 GPa, dln(Ms)/dP = -6.3 × 10-2 GPa-1 was discovered. The presented results are consistent with Moriya's theoretical predictions and can significantly help to better understand the underlying physics of itinerant electron magnetic systems nowadays widely investigated for both fundamental and applications purposes.

Characterization of a dielectric barrier discharge in contact with liquid and producing a plasma activated water

NASA Astrophysics Data System (ADS)

Neretti, G.; Taglioli, M.; Colonna, G.; Borghi, C. A.

2017-01-01

In this work a low-temperature plasma source for the generation of plasma activated water (PAW) is developed and characterized. The plasma reactor was operated by means of an atmospheric-pressure air dielectric barrier discharge (DBD). The plasma generated is in contact with the water surface and is able to chemically activate the liquid medium. Electrodes were supplied by both sinusoidal and nanosecond-pulsed voltage waveforms. Treatment times were varied from 2 to 12 min to increase the energy dose released to the water by the DBD plasma. The physics of the discharge was studied by means of electrical, spectroscopic and imaging diagnostics. The interaction between the plasma and the liquid was investigated as well. Temperature and composition of the treated water were detected. Images of the discharges showed a filamentary behaviour in the sinusoidal case and a more homogeneous behaviour in the nanosecond-pulsed one. The images and the electrical measurements allowed to evaluate an average electron number density of about 4  ×  1019 and 6  ×  1017 m-3 for the sinusoidal and nanosecond-pulsed discharges respectively. Electron temperatures in the range of 2.1÷2.6 eV were measured by using spectroscopic diagnostics. Rotational temperatures in the range of 318-475 K were estimated by fitting synthetic spectra with the measured ones. Water temperature and pH level did not change significantly after the exposure to the DBD plasma. The production of ozone and hydrogen peroxide within the water was enhanced by increasing the plasma treatment time and the energy dose. Numerical simulations of the nanosecond-pulsed discharge were performed by using a self-consistent coupling of state-to-state kinetics of the air mixture with the Boltzmann equation of free electron kinetics. Temporal evolution of the electron energy distribution function shows departure from the Maxwellian distribution especially during the afterglow phase of the discharge. When limited deviations from Maxwellian distribution were observed, calculated electron temperature is in good agreement with the one measured by means of spectroscopic diagnostics. Computed temporal evolution of the energy delivered to the discharge is comparable with the one obtained from electrical measurements. The electrical discharges supplied by both voltage waveforms produce plasma activated water with negligible thermal effects and pH variations.

Physics of the Merging Clusters Cygnus A, A3667, and A2065

NASA Astrophysics Data System (ADS)

Markevitch, Maxim; Sarazin, Craig L.; Vikhlinin, Alexey

1999-08-01

We present ASCA gas temperature maps of the nearby merging galaxy clusters Cygnus A, A3667, and A2065. Cygnus A appears to have a particularly simple merger geometry that allows an estimate of the subcluster collision velocity from the observed temperature variations. We estimate it to be ~2000 km s-1. Interestingly, this is similar to the free-fall velocity that the two Cygnus A subclusters should have achieved at the observed separation, suggesting that the merger has been effective in dissipating the kinetic energy of gas halos into thermal energy, without channeling its major fraction elsewhere (e.g., into turbulence). In A3667 we may be observing a spatial lag between the shock front seen in the X-ray image and the corresponding rise of the electron temperature. A lag of the order of hundreds of kiloparsecs is possible because of the combination of thermal conduction and a finite electron-ion equilibration time. Forthcoming better spatial resolution data will allow a direct measurement of these phenomena in the cluster gas using such lags. A2065 has gas density peaks coincident with two central galaxies. A merger with the collision velocity estimated from the temperature map should have swept away such peaks if the subcluster total mass distributions had flat cores in the centers. The fact that the peaks have survived (or quickly reemerged) suggests that the gravitational potential is also strongly peaked. Finally, the observed specific entropy variations in A3667 and Cygnus A indicate that energy injection from a single major merger may be of the order of the full thermal energy of the gas. We hope that these order-of-magnitude estimates will encourage further work on hydrodynamic simulations, as well as a more quantitative representation of the simulation results, in anticipation of the Chandra and XMM data.

Synthesis and characterization of (Bi{sub 0.5}Ba{sub 0.5}) (Fe{sub 0.5}Ti{sub 0.5}) O{sub 3} ceramic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parida, B.N., E-mail: bichitra_mama@rediffmail.com; Das, Piyush R., E-mail: prdas63@gmail.com; Padhee, R.

2015-01-15

Graphical abstract: Temperature variation of (a) dielectric constant (b) dielectric loss of the sample. - Highlights: • The high values of dielectric permittivity and low value of tangent loss. • It used for microwave applications. • The impedance and dielectric relaxation in the material is non exponential and non Debye-type. • Its ac conductivity obeys Jonscher universal power law. - Abstract: The polycrystalline sample of (Bi{sub 0.5}Ba{sub 0.5}) (Fe{sub 0.5}Ti{sub 0.5}) O{sub 3} (BF–BT) was prepared by a standard mixed oxide method. Analysis of room temperature XRD pattern and Raman/FTIR spectra of the compound does not exhibit any change inmore » its crystal structure of BaTiO{sub 3} on addition of BiFeO{sub 3} in equal ratio. The surface morphology of the gold-plated sintered pellet sample recorded by SEM (scanning electron microscope) exhibits a uniform distribution of grains with less porosity. Detailed studies of nature and quantity of variation of dielectric constant, tangent loss, and polarization with temperature and frequency indicate the existence of ferroelectric phase transition at high-temperature. There is a low-temperature anti-ferromagnetic phase transition below 375 °C in the material. Detailed studies of electrical properties (impedance, modulus, etc.) of the material confirmed a strong correlation between micro-structure and properties.« less

Effects of the temperature and pressure on the electronic and optical properties of an exciton in GaAs/Ga1-xAlxAs quantum ring

NASA Astrophysics Data System (ADS)

El-Bakkari, K.; Sali, A.; Iqraoun, E.; Rezzouk, A.; Es-Sbai, N.; Ouazzani Jamil, M.

2018-06-01

Using a variational approach, we have calculated the binding energies (E1s,2sb) and interband emission energy (Eph) of an exciton confined in GaAs / Ga1 - x Alx As quantum rings (QRs) structures under effects of the temperature and pressure, in the effective mass approximation. We have taken into consideration the difference in the effective masses of the charge carriers in two materials, well and barrier. The results that we have obtained show clearly that E1s,2sb and Eph are influenced by the structure geometries of QR (height H, radial thickness Δ R and potential barrier), the temperature and pressure. Indeed, with a smaller geometric parameter, E1s,2sb and Eph become higher due to the improvement in confinement of the charge carriers. We have also observed that for a given value of the temperature, the pressure leads to an increasing of the E1s,2sb and Eph , and the latter quantities are decreasing with temperature. In addition, these variations of the E1s,2sb and Eph under the external perturbations are more remarkable in small H for fixed Δ R , and for larger Δ R for a given value of the H, because for the choice of a finite height of the barrier in the z direction and an infinite confinement in ρ direction.

Lower Hybrid Wave Induced SOL Emissivity Variation at High Density on the Alcator C-Mod Tokamak

DOE Office of Scientific and Technical Information (OSTI.GOV)

Faust, I.; Terry, J. L.; Reinke, M. L.

Lower Hybrid Current Drive (LHCD) in the Alcator C-Mod tokamak provides current profile control for the generation of Advanced Tokamak (AT) plasmas. Non-thermal electron bremsstrahlung emission decreases dramatically at n-bar{sub e}>1{center_dot}10{sup 20}[m{sup -3}] for diverted discharges, indicating low current drive efficiency. It is suggested that Scrape-Off-Layer (SOL) collisional absorption of LH waves is the cause for the absence of non-thermal electrons at high density. VUV and visible spectroscopy in the SOL provide direct information on collision excitation processes. Deuterium Balmer-, Lyman- and He-I transition emission measurements were used for initial characterization of SOL electron-neutral collisional absorption. Data from Helium andmore » Deuterium LHCD discharges were characterized by an overall increase in the emissivity as well as an outward radial shift in the emissivity profile with increasing plasma density and applied LHCD power. High-temperature, high-field (T{sub e} = 5keV,B{sub t} = 8T) helium discharges at high density display increased non-thermal signatures as well as reduced SOL emissivity. Variations in emissivity due to LHCD were seen in SOL regions not magnetically connected to the LH Launcher, indicating global SOL effects due to LHCD.« less

Influence of interface layer on optical properties of sub-20 nm-thick TiO2 films

NASA Astrophysics Data System (ADS)

Shi, Yue-Jie; Zhang, Rong-Jun; Li, Da-Hai; Zhan, Yi-Qiang; Lu, Hong-Liang; Jiang, An-Quan; Chen, Xin; Liu, Juan; Zheng, Yu-Xiang; Wang, Song-You; Chen, Liang-Yao

2018-02-01

The sub-20 nm ultrathin titanium dioxide (TiO2) films with tunable thickness were deposited on Si substrates by atomic layer deposition (ALD). The structural and optical properties were acquired by transmission electron microscopy, atomic force microscopy and spectroscopic ellipsometry. Afterwards, a constructive and effective method of analyzing interfaces by applying two different optical models consisting of air/TiO2/Ti x Si y O2/Si and air/effective TiO2 layer/Si, respectively, was proposed to investigate the influence of interface layer (IL) on the analysis of optical constants and the determination of band gap of TiO2 ultrathin films. It was found that two factors including optical constants and changing components of the nonstoichiometric IL could contribute to the extent of the influence. Furthermore, the investigated TiO2 ultrathin films of 600 ALD cycles were selected and then annealed at the temperature range of 400-900 °C by rapid thermal annealing. Thicker IL and phase transition cause the variation of optical properties of TiO2 films after annealing and a shorter electron relaxation time reveals the strengthened electron-electron and electron-phonon interactions in the TiO2 ultrathin films at high temperature. The as-obtained results in this paper will play a role in other studies of high dielectric constants materials grown on Si substrates and in the applications of next generation metal-oxide-semiconductor devices.

Upper critical field reaches 90 tesla near the Mott transition in fulleride superconductors

DOE PAGES

Kasahara, Y.; Takeuchi, Y.; Zadik, R. H.; ...

2017-02-17

Controlled access to the border of the Mott insulating state by variation of control parameters offers exotic electronic states such as anomalous and possibly high-transition-temperature (T c) superconductivity. The alkali-doped fullerides show a transition from a Mott insulator to a superconductor for the first time in three-dimensional materials, but the impact of dimensionality and electron correlation on superconducting properties has remained unclear. Here we show that, near the Mott insulating phase, the upper critical field H c2 of the fulleride superconductors reaches values as high as ~90 T—the highest among cubic crystals. This is accompanied by a crossover from weak-more » to strong-coupling superconductivity and appears upon entering the metallic state with the dynamical Jahn–Teller effect as the Mott transition is approached. Lastly, these results suggest that the cooperative interplay between molecular electronic structure and strong electron correlations plays a key role in realizing robust superconductivity with high-T c and high-H c2.« less

Upper critical field reaches 90 tesla near the Mott transition in fulleride superconductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasahara, Y.; Takeuchi, Y.; Zadik, R. H.

Controlled access to the border of the Mott insulating state by variation of control parameters offers exotic electronic states such as anomalous and possibly high-transition-temperature (T c) superconductivity. The alkali-doped fullerides show a transition from a Mott insulator to a superconductor for the first time in three-dimensional materials, but the impact of dimensionality and electron correlation on superconducting properties has remained unclear. Here we show that, near the Mott insulating phase, the upper critical field H c2 of the fulleride superconductors reaches values as high as ~90 T—the highest among cubic crystals. This is accompanied by a crossover from weak-more » to strong-coupling superconductivity and appears upon entering the metallic state with the dynamical Jahn–Teller effect as the Mott transition is approached. Lastly, these results suggest that the cooperative interplay between molecular electronic structure and strong electron correlations plays a key role in realizing robust superconductivity with high-T c and high-H c2.« less

Nonlinear collisionless electron cyclotron interaction in the pre-ionisation stage

NASA Astrophysics Data System (ADS)

Farina, D.

2018-06-01

Electron cyclotron (EC) wave-particle interaction is theoretically investigated in the pre-ionisation phase, much before collisions and other mechanisms can play a role. In the very first phase of a plasma discharge with EC-assisted breakdown, the motion of an electron at room temperature in a static magnetic field under the action of a localised microwave beam is nonlinear, and transition to states of larger energy can occur via wave trapping. Within a Hamiltonian adiabatic formalism, the conditions at which the particles gain energy in single beam crossing are derived in a rigorous way, and the energy variation is characterized quantitatively as a function of the wave frequency, harmonic number, polarisation and EC power and beam width. Estimates of interest for applications to tokamak start-up are obtained for the first, second and third cyclotron harmonic. The investigation confirms that electrons can easily gain energies well above the ionisation energy in most conditions at the first two harmonics, while not at the third harmonic, as observed in experiments.

Unraveling the excitation mechanisms of highly oblique lower-band chorus waves

DOE PAGES

Li, Wen; Mourenas, D.; Artemyev, A. V.; ...

2016-08-17

Excitation mechanisms of highly oblique, quasi-electrostatic lower band chorus waves are investigated using Van Allen Probes observations near the equator of the Earth's magnetosphere. Linear growth rates are evaluated based on in situ, measured electron velocity distributions and plasma conditions and compared with simultaneously observed wave frequency spectra and wave normal angles. Accordingly, two distinct excitation mechanisms of highly oblique lower band chorus have been clearly identified for the first time. The first mechanism relies on cyclotron resonance with electrons possessing both a realistic temperature anisotropy at keV energies and a plateau at 100–500 eV in the parallel velocity distribution.more » The second mechanism corresponds to Landau resonance with a 100–500 eV beam. In both cases, a small low-energy beam-like component is necessary for suppressing an otherwise dominating Landau damping. In conclusion, our new findings suggest that small variations in the electron distribution could have important impacts on energetic electron dynamics.« less

Electronic conductivity studies on oxyhalide glasses containing TMO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vijayatha, D.; Department of Physics, Gurunanak Institute of Technology, Hyderabad -040; Viswanatha, R.

2016-05-06

Microwave-assisted synthesis is cleaner, more economical and much faster than conventional methods. The development of new routes for the synthesis of solid materials is an integral part of material science and technology. The electronic conductivity studies on xPbCl{sub 2} – 60 PbO – (40-x) V{sub 2}O{sub 5} (1 ≥ x ≤ 10) glass system has been carried out over a wide range of composition and temperature (300 K to 423 K). X-ray diffraction study confirms the amorphous nature of the samples. The Scanning electron microscopic studies reveal the formation of cluster like morphology in PbCl{sub 2} containing glasses. The d.c conductivity exhibitsmore » Arrhenius behaviour and increases with V{sub 2}O{sub 5} concentration. Analysis of the results is interpreted in view Austin-Mott’s small polaron model of electron transport. Activation energies calculated using regression analysis exhibit composition dependent trend and the variation is explained in view of the structure of lead-vanadate glass.« less

Microstructure characterization of 316L deformed at high strain rates using EBSD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yvell, K., E-mail: kyv@du.se

2016-12-15

Specimens from split Hopkinson pressure bar experiments, at strain rates between ~ 1000–9000 s{sup −1} at room temperature and 500 °C, have been studied using electron backscatter diffraction. No significant differences in the microstructures were observed at different strain rates, but were observed for different strains and temperatures. Size distribution for subgrains with boundary misorientations > 2° can be described as a bimodal lognormal area distribution. The distributions were found to change due to deformation. Part of the distribution describing the large subgrains decreased while the distribution for the small subgrains increased. This is in accordance with deformation being heterogeneousmore » and successively spreading into the undeformed part of individual grains. The variation of the average size for the small subgrain distribution varies with strain but not with strain rate in the tested interval. The mean free distance for dislocation slip, interpreted here as the average size of the distribution of small subgrains, displays a variation with plastic strain which is in accordance with the different stages in the stress-strain curves. The rate of deformation hardening in the linear hardening range is accurately calculated using the variation of the small subgrain size with strain. - Highlights: •Only changes in strain, not strain rate, gave differences in the microstructure. •A bimodal lognormal size distribution was found to describe the size distribution. •Variation of the subgrain fraction sizes agrees with models for heterogeneous slip. •Variation of subgrain size with strain describes part of the stress strain curve.« less

Propagation distance-resolved characteristics of filament-induced copper plasma

DOE PAGES

Ghebregziabher, Isaac; Hartig, Kyle C.; Jovanovic, Igor

2016-03-02

Copper plasma generated at different filament-copper interaction points was characterized by spectroscopic, acoustic, and imaging measurements. The longitudinal variation of the filament intensity was qualitatively determined by acoustic measurements in air. The maximum plasma temperature was measured at the location of peak filament intensity, corresponding to the maximum mean electron energy during plasma formation. The highest copper plasma density was measured past the location of the maximum electron density in the filament, where spectral broadening of the filament leads to enhanced ionization. Acoustic measurements in air and on solid target were correlated to reconstructed plasma properties. Lastly, optimal line emissionmore » is measured near the geometric focus of the lens used to produce the filament.« less

A Probabilistic Approach to Predict Thermal Fatigue Life for Ball Grid Array Solder Joints

NASA Astrophysics Data System (ADS)

Wei, Helin; Wang, Kuisheng

2011-11-01

Numerous studies of the reliability of solder joints have been performed. Most life prediction models are limited to a deterministic approach. However, manufacturing induces uncertainty in the geometry parameters of solder joints, and the environmental temperature varies widely due to end-user diversity, creating uncertainties in the reliability of solder joints. In this study, a methodology for accounting for variation in the lifetime prediction for lead-free solder joints of ball grid array packages (PBGA) is demonstrated. The key aspects of the solder joint parameters and the cyclic temperature range related to reliability are involved. Probabilistic solutions of the inelastic strain range and thermal fatigue life based on the Engelmaier model are developed to determine the probability of solder joint failure. The results indicate that the standard deviation increases significantly when more random variations are involved. Using the probabilistic method, the influence of each variable on the thermal fatigue life is quantified. This information can be used to optimize product design and process validation acceptance criteria. The probabilistic approach creates the opportunity to identify the root causes of failed samples from product fatigue tests and field returns. The method can be applied to better understand how variation affects parameters of interest in an electronic package design with area array interconnections.

Ion extraction from a plasma. Ph.D. Thesis. Progress Report, 1 Dec. 1979 - 1 Dec. 1980

NASA Technical Reports Server (NTRS)

Aston, G.

1980-01-01

An experimental investigation of the physical processes governing ion extraction from a plasma is presented. The screen hole plasma sheath of a multiaperture ion accelerator system is defined by equipotential plots for a variety of accelerator system geometries and operating conditions. A sheath thickness of at least fifteen Debye lengths is shown to be typical. The electron density variation within the sheath satisfies a Maxwell Boltzmann density distribution at an effective electron temperature dependent on the discharge plasma primary to Maxwellian electron density ratio. Plasma ion flow up to and through the sheath is predominately one dimensional and the ions enter the sheath with a modified Bohm velocity. Low values of the screen grid thickness to screen hole diameter ratio give good ion focusing and high extracted ion currents because of the effect of screen webbing on ion focusing.

LETTER: Test of Te profile invariance by sensitivity studies

NASA Astrophysics Data System (ADS)

Becker, G.

1992-06-01

The response of the electron temperature profile shape to variations of the electron heating and density profiles is investigated in different confinement regimes. It is shown that the changes in rTe = -Te/(dTe/dr) exceed the measurement error if the shape of the electron heat diffusivity χe(r) is kept fixed. The observed constancy of rTe(r) in the outer half of the plasma is incompatible with such a fixed χe(r) shape, i.e., a Te profile constraining mechanism must be present. Local transport laws of the form χe varies as rTe-α with α gtrsim 4 and χe propto (dTe/dr)α with α >= 2 yield the experimental stiffness of the Te(r) shape but conflict with empirical χe scalings. These results support the model of a self-organizing and adjusting χe(r) causing Te profile invariance

Role of random magnetic anisotropy on the valence, magnetocaloric and resistivity properties in a hexagonal Sm2Ni0.87Si2.87 compound

NASA Astrophysics Data System (ADS)

Pakhira, Santanu; Kundu, Asish K.; Mazumdar, Chandan; Ranganathan, R.

2018-05-01

In this work, we report the effect of random magnetic anisotropy (RMA) on the valence, magnetocaloric and resistivity properties in a glassy intermetallic material Sm2Ni0.87Si2.87. On the basis of detailed studies on the valence band and core level electronic structure, we have established that both the Sm3+ and Sm2+ ions are present in the system, suggesting the compound to be of mixed valence in nature. The significant observation of positive magnetic entropy change in zero-field cooled measurement has been argued due to the presence of RMA that develops due to local electronic environmental variations between the rare-earth ions in the system. The quantum interference effect caused by the elastic electron–electron interaction is responsible for the resistivity upturn at low-temperature for this disordered metallic conductor.

Simulation of a large size inductively coupled plasma generator and comparison with experimental data

NASA Astrophysics Data System (ADS)

Lei, Fan; Li, Xiaoping; Liu, Yanming; Liu, Donglin; Yang, Min; Yu, Yuanyuan

2018-01-01

A two-dimensional axisymmetric inductively coupled plasma (ICP) model with its implementation in the COMSOL (Multi-physics simulation software) platform is described. Specifically, a large size ICP generator filled with argon is simulated in this study. Distributions of the number density and temperature of electrons are obtained for various input power and pressure settings and compared. In addition, the electron trajectory distribution is obtained in simulation. Finally, using experimental data, the results from simulations are compared to assess the veracity of the two-dimensional fluid model. The purpose of this comparison is to validate the veracity of the simulation model. An approximate agreement was found (variation tendency is the same). The main reasons for the numerical magnitude discrepancies are the assumption of a Maxwellian distribution and a Druyvesteyn distribution for the electron energy and the lack of cross sections of collision frequencies and reaction rates for argon plasma.

Effect on the properties of ITO thin films in Gamma environment

NASA Astrophysics Data System (ADS)

Sofi, A. H.; Shah, M. A.; Asokan, K.

2018-04-01

The present study reports the effect of gamma irradiation of varying doses (0-200 kGy) on the physical properties of the indium tin oxide (ITO) thin films. The films were fabricated by thermal evaporation method using indium-tin (InSn) ingots followed by an oxidation in atmosphere at a temperature of 550 °C. X-ray diffraction analysis confirmed the body-centered cubic (BCC) structure corresponds to the ITO thin films, high phase purity and a variation in crystallite size between 30-44 nm. While the optical studies revealed an increase in transmission as well as variation in optical band gap, the electrical studies confirmed n-type semiconductive behavior of the thin films, increase in mobility and a decrease in resistivity from 2.33×10-2 - 9.31×10-4 Ωcm with the increase in gamma dose from 0-200 kGy. The gamma irradiation caused totally electronic excitation and resulted in this modifications. The degenerate electron gas model was considered when attempting to understand the prevalent scattering mechanism in gamma irradiated ITO thin films.

On the evolution of antiferromagnetic nanodomains in NiO thin films: A LEEM study

NASA Astrophysics Data System (ADS)

Das, Jayanta; Menon, Krishnakumar S. R.

2018-03-01

Fractional order (1/2, 0) spots appear in the electron diffraction from NiO/Ag(0 0 1) films due to exchange scattering of low energy electrons by the antiferromagnetically ordered surface Ni moments. Utilizing these beams, imaging of the nanosized surface magnetic domains were carried out employing the high spatial resolution (∼ 10 nm) of the Low Energy Electron Microscopy (LEEM) in the dark-field (DF) mode. While selected through a contrast aperture, the four magnetic reflections produced by the p (2 × 2) antiferromagnetic sub-lattice lead to the visualization of the different magnetic twin domains. The intensity variations of different twin domains were measured as a function of electron beam energies via domain resolved LEEM I-V plots. The surface Néel temperatures (TN) of the films were measured using the temperature dependence of these half-order spot intensities. Detailed morphological studies of the size and shape of these nanodomains and their evolution as a function of the film thickness have been carried out with the help of pair-correlation function and fractal analysis. The size, shape and distribution of these magnetic domains are modified significantly by the strain relaxation mechanism beyond the critical film thickness. A method to estimate the relative domain sizes from a quantitative measure of the half-order spot intensities is manifested well below TN .

Compressive strain induced enhancement in thermoelectric-power-factor in monolayer MoS2 nanosheet

NASA Astrophysics Data System (ADS)

Dimple; Jena, Nityasagar; De Sarkar, Abir

2017-06-01

Strain and temperature induced tunability in the thermoelectric properties in monolayer MoS2 (ML-MoS2) has been demonstrated using density functional theory coupled to semi-classical Boltzmann transport theory. Compressive strain, in general and uniaxial compressive strain (along the zig-zag direction), in particular, is found to be most effective in enhancing the thermoelectric power factor, owing to the higher electronic mobility and its sensitivity to lattice compression along this direction. Variation in the Seebeck coefficient and electronic band gap with strain is found to follow the Goldsmid-Sharp relation. n-type doping is found to raise the relaxation time-scaled thermoelectric power factor higher than p-type doping and this divide widens with increasing temperature. The relaxation time-scaled thermoelectric power factor in optimally n-doped ML-MoS2 is found to undergo maximal enhancement under the application of 3% uniaxial compressive strain along the zig-zag direction, when both the (direct) electronic band gap and the Seebeck coefficient reach their maximum, while the electron mobility drops down drastically from 73.08 to 44.15 cm2 V-1 s-1. Such strain sensitive thermoelectric responses in ML-MoS2 could open doorways for a variety of applications in emerging areas in 2D-thermoelectrics, such as on-chip thermoelectric power generation and waste thermal energy harvesting.

A global plasma model for reactive deposition of compound films by modulated pulsed power magnetron sputtering discharges

NASA Astrophysics Data System (ADS)

Zheng, B. C.; Wu, Z. L.; Wu, B.; Li, Y. G.; Lei, M. K.

2017-05-01

A spatially averaged, time-dependent global plasma model has been developed to describe the reactive deposition of a TiAlSiN thin film by modulated pulsed power magnetron sputtering (MPPMS) discharges in Ar/N2 mixture gas, based on the particle balance and the energy balance in the ionization region, and considering the formation and erosion of the compound at the target surface. The modeling results show that, with increasing the N2 partial pressure from 0% to 40% at a constant working pressure of 0.3 Pa, the electron temperature during the strongly ionized period increases from 4 to 7 eV and the effective power transfer coefficient, which represents the power fraction that effectively heats the electrons and maintains the discharge, increases from about 4% to 7%; with increasing the working pressure from 0.1 to 0.7 Pa at a constant N2 partial pressure of 25%, the electron temperature decreases from 10 to 4 eV and the effective power transfer coefficient decreases from 8% to 5%. Using the modeled plasma parameters to evaluate the kinetic energy of arriving ions, the ion-to-neutral flux ratio of deposited species, and the substrate heating, the variations of process parameters that increase these values lead to an enhanced adatom mobility at the target surface and an increased input energy to the substrate, corresponding to the experimental observation of surface roughness reduction, the microstructure transition from the columnar structure to the dense featureless structure, and the enhancement of phase separation. At higher N2 partial pressure or lower working pressure, the modeling results demonstrate an increase in electron temperature, which shifts the discharge balance of Ti species from Ti+ to Ti2+ and results in a higher return fraction of Ti species, corresponding to the higher Al/Ti ratio of deposited films at these conditions. The modeling results are well correlated with the experimental observation of the composition variation and the microstructure transition of deposited TiAlSiN compound films, demonstrating the applicability of this approach in understanding the characteristics of reactive MPPMS discharges as well as the composition and microstructure of deposited compound films. The model for reactive MPPMS discharges has no special limitations and is applicable to high power impulse magnetron sputtering discharges as well.

Microwave Synthesized ZnO Nanorod Arrays for UV Sensors: A Seed Layer Annealing Temperature Study.

PubMed

Pimentel, Ana; Ferreira, Sofia Henriques; Nunes, Daniela; Calmeiro, Tomas; Martins, Rodrigo; Fortunato, Elvira

2016-04-20

The present work reports the influence of zinc oxide (ZnO) seed layer annealing temperature on structural, optical and electrical properties of ZnO nanorod arrays, synthesized by hydrothermal method assisted by microwave radiation, to be used as UV sensors. The ZnO seed layer was produced using the spin-coating method and several annealing temperatures, ranging from 100 to 500 °C, have been tested. X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and spectrophotometry measurements have been used to investigate the structure, morphology, and optical properties variations of the produced ZnO nanorod arrays regarding the seed layer annealing temperatures employed. After the growth of ZnO nanorod arrays, the whole structure was tested as UV sensors, showing an increase in the sensitivity with the increase of seed layer annealing temperature. The UV sensor response of ZnO nanorod arrays produced with the seed layer annealed temperature of 500 °C was 50 times superior to the ones produced with a seed layer annealed at 100 °C.

Microwave Synthesized ZnO Nanorod Arrays for UV Sensors: A Seed Layer Annealing Temperature Study

PubMed Central

Pimentel, Ana; Ferreira, Sofia Henriques; Nunes, Daniela; Calmeiro, Tomas; Martins, Rodrigo; Fortunato, Elvira

2016-01-01

The present work reports the influence of zinc oxide (ZnO) seed layer annealing temperature on structural, optical and electrical properties of ZnO nanorod arrays, synthesized by hydrothermal method assisted by microwave radiation, to be used as UV sensors. The ZnO seed layer was produced using the spin-coating method and several annealing temperatures, ranging from 100 to 500 °C, have been tested. X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and spectrophotometry measurements have been used to investigate the structure, morphology, and optical properties variations of the produced ZnO nanorod arrays regarding the seed layer annealing temperatures employed. After the growth of ZnO nanorod arrays, the whole structure was tested as UV sensors, showing an increase in the sensitivity with the increase of seed layer annealing temperature. The UV sensor response of ZnO nanorod arrays produced with the seed layer annealed temperature of 500 °C was 50 times superior to the ones produced with a seed layer annealed at 100 °C. PMID:28773423

500 C Electronic Packaging and Dielectric Materials for High Temperature Applications

NASA Technical Reports Server (NTRS)

Chen, Liang-yu; Neudeck, Philip G.; Spry, David J.; Beheim, Glenn M.; Hunter, Gary W.

2016-01-01

High-temperature environment operable sensors and electronics are required for exploring the inner solar planets and distributed control of next generation aeronautical engines. Various silicon carbide (SiC) high temperature sensors, actuators, and electronics have been demonstrated at and above 500C. A compatible packaging system is essential for long-term testing and application of high temperature electronics and sensors. High temperature passive components are also necessary for high temperature electronic systems. This talk will discuss ceramic packaging systems developed for high temperature electronics, and related testing results of SiC circuits at 500C and silicon-on-insulator (SOI) integrated circuits at temperatures beyond commercial limit facilitated by these high temperature packaging technologies. Dielectric materials for high temperature multilayers capacitors will also be discussed. High-temperature environment operable sensors and electronics are required for probing the inner solar planets and distributed control of next generation aeronautical engines. Various silicon carbide (SiC) high temperature sensors, actuators, and electronics have been demonstrated at and above 500C. A compatible packaging system is essential for long-term testing and eventual applications of high temperature electronics and sensors. High temperature passive components are also necessary for high temperature electronic systems. This talk will discuss ceramic packaging systems developed for high electronics and related testing results of SiC circuits at 500C and silicon-on-insulator (SOI) integrated circuits at temperatures beyond commercial limit facilitated by high temperature packaging technologies. Dielectric materials for high temperature multilayers capacitors will also be discussed.

Formation Mechanisms of the Spring-Autumn Asymmetry of the Midlatitudinal NmF2 under Daytime Quiet Geomagnetic Conditions at Low Solar Activity

NASA Astrophysics Data System (ADS)

Pavlov, A. V.; Pavlova, N. M.

2018-05-01

Formation mechanism of the spring-autumn asymmetry of the F2-layer peak electron number density of the midlatitudinal ionosphere, NmF2, under daytime quiet geomagnetic conditions at low solar activity are studied. We used the ionospheric parameters measured by the ionosonde and incoherent scatter radar at Millstone Hill on March 3, 2007, March 29, 2007, September 12, 2007, and September 18, 1984. The altitudinal profiles of the electron density and temperature were calculated for the studied conditions using a one-dimensional, nonstationary, ionosphere-plasmasphere theoretical model for middle geomagnetic latitudes. The study has shown that there are two main factors contributing to the formation of the observed spring-autumn asymmetry of NmF2: first, the spring-autumn variations of the plasma drift along the geomagnetic field due to the corresponding variations in the components of the neutral wind velocity, and, second, the difference between the composition of the neutral atmosphere under the spring and autumn conditions at the same values of the universal time and the ionospheric F2-layer peak altitude. The seasonal variations of the rate of O+(4S) ion production, which are associated with chemical reactions with the participation of the electronically excited ions of atomic oxygen, does not significantly affect the studied NmF2 asymmetry. The difference in the degree of influence of O+(4S) ion reactions with vibrationally excited N2 and O2 on NmF2 under spring and autumn conditions does not significantly change the spring-autumn asymmetry of NmF2.

Height Dependence of Plasma Properties of a Dark Lane and a Cool Loop in a Solar Limb Active Region Observed by Hinode/EIS

NASA Astrophysics Data System (ADS)

Lee, K.; Imada, S.; Moon, Y.; Lee, J.

2013-12-01

We investigate spectral properties of a cool loop and a dark lane over a limb active region on 2007 March 14 by the Hinode/EUV Imaging Spectrometer. The cool loop is clearly seen in the spectral lines formed at the transition region temperature. The dark lane is characterized by an elongated faint structure in coronal spectral lines and rooted on a bright point. We determine their electron densities, Doppler velocities, and non-thermal velocities with height over the limb. We derived electron densities using the density sensitive line pairs of Mg VII, Si X, Fe XII, Fe XIII and Fe XIV spectra. Under the hydrostatic equilibrium and isothermal assumption, we determine their temperatures from the density scale height. Comparing the scale height temperatures to the peak formation temperatures of the spectral lines, we note that the scale height temperature of the cool loop is consistent with a peak formation temperature of the Fe XII and the scale height temperatures of the dark lane from each spectral lines are much lower than their peak formation temperatures. The non-thermal velocity in the cool loop slightly decreases along the loop while that in the dark lane sharply falls off with height. The variation of non-thermal velocity with height in the cool loop and the dark lane is contrast to that in off-limb polar coronal holes which are considered as source of the solar wind. Such a decrease in the non-thermal velocity may be explained by wave damping near the solar surface or turbulence due to magnetic reconnection near the bright point.

Experimental Study of the Shock Waves Produced by Condenser Discharge in a Gas Tube (thesis); ETUDE EXPERIMENTALE DES ONDES DE CHOC PRODUITES PAR DECHARGES D'UN CONDENSATEUR DANS UN TUBE A GAZ (thesis)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Der Agobian, R.

1964-10-31

The shock waves Droduced by condenser discharge in a gas tube were investigated. The study was limited to wave velocities less than five times the speed of sound, propagated in gas at low pressure (several mm Hg). A method was designed and perfected for the detection of the shock waves that are insufficiently rapid to produce gas ionization. This method consisted of the creation of an autonomous plasma, before the arrival of the wave, which was then modified by the wave passage. two methods were used for the detection of phenomena accompanying the passage of the shock waves, an opticalmore » method and a radioelectric method. The qualitative study of the modifications produced on the wave passage showed the remarkable correlation existing between the results obtained by the two methods. The experimental results on the propagation laws for shock waves in a low-diameter tube agreed with theory. The variations of the coefficient oi recombination were determined as a iunction of the electron temperature, and the results were in good agreement with the Bates theory. It was shown that the electron gas of the plasma had the same increase of density as a neutral gas during the passage of a shock wave. The variations of the frequency of electron collisions on passage of the shock wave could be explained by considering the electron--ion collisions with respect to electron-- atom collisions. (J.S.R.)« less

Seasonal temperature variation influences climate suitability for dengue, chikungunya, and Zika transmission.

PubMed

Huber, John H; Childs, Marissa L; Caldwell, Jamie M; Mordecai, Erin A

2018-05-01

Dengue, chikungunya, and Zika virus epidemics transmitted by Aedes aegypti mosquitoes have recently (re)emerged and spread throughout the Americas, Southeast Asia, the Pacific Islands, and elsewhere. Understanding how environmental conditions affect epidemic dynamics is critical for predicting and responding to the geographic and seasonal spread of disease. Specifically, we lack a mechanistic understanding of how seasonal variation in temperature affects epidemic magnitude and duration. Here, we develop a dynamic disease transmission model for dengue virus and Aedes aegypti mosquitoes that integrates mechanistic, empirically parameterized, and independently validated mosquito and virus trait thermal responses under seasonally varying temperatures. We examine the influence of seasonal temperature mean, variation, and temperature at the start of the epidemic on disease dynamics. We find that at both constant and seasonally varying temperatures, warmer temperatures at the start of epidemics promote more rapid epidemics due to faster burnout of the susceptible population. By contrast, intermediate temperatures (24-25°C) at epidemic onset produced the largest epidemics in both constant and seasonally varying temperature regimes. When seasonal temperature variation was low, 25-35°C annual average temperatures produced the largest epidemics, but this range shifted to cooler temperatures as seasonal temperature variation increased (analogous to previous results for diurnal temperature variation). Tropical and sub-tropical cities such as Rio de Janeiro, Fortaleza, and Salvador, Brazil; Cali, Cartagena, and Barranquilla, Colombia; Delhi, India; Guangzhou, China; and Manila, Philippines have mean annual temperatures and seasonal temperature ranges that produced the largest epidemics. However, more temperate cities like Shanghai, China had high epidemic suitability because large seasonal variation offset moderate annual average temperatures. By accounting for seasonal variation in temperature, the model provides a baseline for mechanistically understanding environmental suitability for virus transmission by Aedes aegypti. Overlaying the impact of human activities and socioeconomic factors onto this mechanistic temperature-dependent framework is critical for understanding likelihood and magnitude of outbreaks.

Path integral Monte Carlo and the electron gas

NASA Astrophysics Data System (ADS)

Brown, Ethan W.

Path integral Monte Carlo is a proven method for accurately simulating quantum mechanical systems at finite-temperature. By stochastically sampling Feynman's path integral representation of the quantum many-body density matrix, path integral Monte Carlo includes non-perturbative effects like thermal fluctuations and particle correlations in a natural way. Over the past 30 years, path integral Monte Carlo has been successfully employed to study the low density electron gas, high-pressure hydrogen, and superfluid helium. For systems where the role of Fermi statistics is important, however, traditional path integral Monte Carlo simulations have an exponentially decreasing efficiency with decreased temperature and increased system size. In this thesis, we work towards improving this efficiency, both through approximate and exact methods, as specifically applied to the homogeneous electron gas. We begin with a brief overview of the current state of atomic simulations at finite-temperature before we delve into a pedagogical review of the path integral Monte Carlo method. We then spend some time discussing the one major issue preventing exact simulation of Fermi systems, the sign problem. Afterwards, we introduce a way to circumvent the sign problem in PIMC simulations through a fixed-node constraint. We then apply this method to the homogeneous electron gas at a large swatch of densities and temperatures in order to map out the warm-dense matter regime. The electron gas can be a representative model for a host of real systems, from simple medals to stellar interiors. However, its most common use is as input into density functional theory. To this end, we aim to build an accurate representation of the electron gas from the ground state to the classical limit and examine its use in finite-temperature density functional formulations. The latter half of this thesis focuses on possible routes beyond the fixed-node approximation. As a first step, we utilize the variational principle inherent in the path integral Monte Carlo method to optimize the nodal surface. By using a ansatz resembling a free particle density matrix, we make a unique connection between a nodal effective mass and the traditional effective mass of many-body quantum theory. We then propose and test several alternate nodal ansatzes and apply them to single atomic systems. Finally, we propose a method to tackle the sign problem head on, by leveraging the relatively simple structure of permutation space. Using this method, we find we can perform exact simulations this of the electron gas and 3He that were previously impossible.

Magnetic and structural properties of nanoparticles of nickel oxide

NASA Astrophysics Data System (ADS)

Shim, Hyunja (Jenny)

In this dissertation, magnetic properties of NiO nanoparticles (NP) prepared by the sol-gel method in the size range D = 5 nm to 20 nm, with and without oleic acid (OA) coating, are reported. Transmission electron microscopy (TEM) studies show the morphology of the smaller particles to be primarily rod-like, changing over to nearly spherical shapes for D >10 nm. Average sizes D of NP determined by x-ray diffraction (XRD) are compared with the results from TEM. From the analysis of the XRD line intensities, the particle size dependence of the Debye-Waller factors for Ni and O atoms are derived. It is found that the Debye-Waller factors of nickel and oxygen atoms in smaller particles are larger than those in bulk NiO. For the coated and uncoated NiO nanorods of 5 nm diameter, variations of the magnetization M with temperature T (5 K to 370 K) and temperature variations of the EMR (electron magnetic resonance) spectra were measured to determine the respective blocking temperatures TB(m) and TB(EMR). The following differences are noted: (1) TB(m) is reduced from 230 K (uncoated) to 85 K(coated) for H = 25 Oe; (2) Decrease of TB(m) with H is weaker and the ratio TB(EMR)/T B(m) is smaller for the uncoated particles. These differences are due to stronger interparticle interaction present in the uncoated particles. Temperature variation (5 K-300 K) of the AC magnetic susceptibilities (chi' and chi") at various frequencies f (0.1-10,000 Hz) are reported for the coated and uncoated 5 nm diameter nanorods of NiO. Using the peak in chi' as the blocking temperature TB, it is observed that TB increases with increasing f. The data for the two samples fit the Vogel-Fulcher law: f = f0exp[-Ea/k(TB-T0)] with f 0 = 9.2 x 1011 Hz, Ea/k = 1085 K and T0 = 162 K (0 K) for the uncoated (coated) particles. This shows that T0 provides a good measure of the effects of interparticle interactions on magnetic relaxation and that these interactions are essentially eliminated with the OA coating. For all the particles, measurements of M versus T (5 K-370 K) in the zero-field cooled (ZFC) and field-cooled (FC) modes are used to determine the average blocking temperature TP. For the OA coated particles, TP increases with increase in size D as expected for superparamagnetic particles. However for the uncoated NP, TP decreases initially with increase in size for D < 10 nm; but for D > 10 nm, TP follows the same trend as for the coated NP. These differences are interpreted in terms of significant interparticle interaction. The data of M vs. the applied field H for T > TP are fit to the modified Langevin function: M = M0 L (muPH/kBT) + chiaH, to determine the magnetic moment muP per particle as a function of size D. The variation of muP with size D is interpreted in terms of the fraction of spins on the surface layer of the particles which contribute to mu P. It is observed that this fraction varies as 1/D reaching nearly 100 % for the 5 nm particles. From the temperature dependence of M0 and extrapolating to M0 → 0, the Neel temperatures TN for various sizes are determined. TN for NiO nanoparticles is found to decreases rapidly with decrease in size for D < 10 nm.

Microstructure characterization and strengthening mechanisms of oxide dispersion strengthened (ODS) Fe-9%Cr and Fe-14%Cr extruded bars

NASA Astrophysics Data System (ADS)

Chauhan, A.; Bergner, F.; Etienne, A.; Aktaa, J.; de Carlan, Y.; Heintze, C.; Litvinov, D.; Hernandez-Mayoral, M.; Oñorbe, E.; Radiguet, B.; Ulbricht, A.

2017-11-01

The collaborative study is focused on the relationship between microstructure and yield stress for an ODS Fe-9%Cr-based transformable alloy and an ODS Fe-14%Cr-based ferritic alloy. The contributions to the total room temperature yield stress arising from various strengthening mechanisms are addressed on the basis of a comprehensive description of the microstructures uncovered by means of transmission electron microscopy (TEM), electron backscatter diffraction (EBSD), small-angle neutron scattering (SANS) and atom probe tomography (APT). While these methods provide a high degree of complementarity, a reasonable agreement was found in cases of overlap of information. The derived set of microstructure parameters along with reported strengthening equations was used to calculate the room temperature yield stress. The estimates were critically compared with the measured yield stress for an extended set of alloys including data reported for Fe-Cr model alloys and steels thus covering one order of magnitude or more in grain size, dislocation density, particle density and yield stress. The comparison shows that particle strengthening, dislocation forest strengthening, and Hall-Petch strengthening are the major contributions and that a mixed superposition rule reproduces the measured yield stress within experimental scatter for the whole extended set of alloys. The wide variation of microstructures additionally underpins the conclusions and goes beyond previous work, in which one or few ODS steels and narrow microstructure variations were typically covered.

The radiated electromagnetic field from collimated gamma rays and electron beams in air

NASA Astrophysics Data System (ADS)

Tumolillo, T. A.; Wondra, J. P.; Hobbs, W. E.; Smith, K.

1980-12-01

Nuclear weapons effects computer codes are used to study the electromagnetic field produced by gamma rays or by highly relativistic electron beams moving through the air. Consideration is given to large-area electron and gamma beams, small-area electron beams, variation of total beam current, variation of pressure in the beam channel, variation of the beam rise time, variation of beam radius, far-field radiated signals, and induced current on a system from a charged-particle beam. The work has application to system EMP coupling from nuclear weapons or charged-particle-beam weapons.

Impact of physical and chemical parameters on the hydroxyapatite nanopowder synthesized by chemical precipitation method

NASA Astrophysics Data System (ADS)

Thu Trang Pham, Thi; Phuong Nguyen, Thu; Pham, Thi Nam; Phuong Vu, Thi; Tran, Dai Lam; Thai, Hoang; Thanh Dinh, Thi Mai

2013-09-01

In this paper, the synthesis of hydroxyapatite (HAp) nanopowder was studied by chemical precipitation method at different values of reaction temperature, settling time, Ca/P ratio, calcination temperature, (NH4)2HPO4 addition rate, initial concentration of Ca(NO3)2 and (NH4)2HPO4. Analysis results of properties, morphology, structure of HAp powder from infrared (IR) spectra, x-ray diffraction (XRD), energy dispersive x-ray (EDX) spectra and scanning electron microscopy (SEM) indicated that the synthesized HAp powder had cylinder crystal shape with size less than 100 nm, single-phase structure. The variation of the synthesis conditions did not affect the morphology but affected the size of HAp crystals.

Preliminary Results on Thermal Shock Behavior of CuZnAl Shape Memory Alloy Using a Solar Concentrator as Heating Source

NASA Astrophysics Data System (ADS)

Tudora, C.; Abrudeanu, M.; Stanciu, S.; Anghel, D.; Plaiaşu, G. A.; Rizea, V.; Ştirbu, I.; Cimpoeşu, N.

2018-06-01

It is highly accepted that martensitic transformation can be induced by temperature variation and by stress solicitation. Using a solar concentrator, we manage to increase the material surface temperature (till 573 respectively 873 K) in very short periods of time in order to analyze the material behavior under thermal shocks. The heating/cooling process was registered and analyzed during the experiments. Material surface was analyzed before and after thermal shocks by microstructure point of view using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The experiments follow the material behavior during fast heating and propose the possibility of activating smart materials using the sun heat for aerospace applications.

Ionospheric electron heating associated with pulsating auroras: joint optical and PFISR observations

NASA Astrophysics Data System (ADS)

Liang, J.; Donovan, E.; Spanswick, E.; Reimer, A.; Hampton, D. L.; Varney, R. H.

2017-12-01

In a recent survey based upon Swarm satellite data, Liang et al. [2017] repeatedly identified a strong electron temperature (Te) enhancement associated with the pulsating aurora at Swarm altitudes ( 460 km). The observation of Te enhancement is not contingent upon whether the pulsating patch is "on" or "off" at the satellite traversal epoch. In this study, we use joint optical and Poker Flat Incoherent Scatter Radar (PFISR) observations to further investigate the 4D (space-time) variations of the Te enhancement in association with the pulsating aurora. In a long-lasting pulsating auroral event on 19 March 2015, we identify strong Te enhancements ( 600-1200 K) in the upper F-region ionosphere ( 300-600 km altitude) in conjunction to the passage of pulsating auroras over PFISR beams. The spatial-temporal variations of PFISR Te enhancement are found to generally conform to the variations of pulsating auroras. However, collocated meridian spectrograph observations suggest that the pulsating auroras of interest are composed of energetic electron precipitation with characteristic energy ≥10 keV, which is not supposed to be efficient in heating electrons in the upper F-region. On the other hand, only moderate (<27%) Ne enhancements are found in the upper F-region during the pulsating aurora and Te enhancement interval. There are also moderate Te enhancements ( 100 K) in the E-region accompanying the pulsating auroras, but no clue of Te enhancement is found in the lower F-region. Based upon the above observations and simulations using the model developed in Liang et al. [2017], we propose that thermal conduction from the topside ionosphere, led by magnetospheric heat fluxes, constitutes the most likely underlying mechanism for the upper F-region electron heating associated with pulsating auroras. Such magnetospheric heat fluxes may be pertinent to one long-hypothesized feature of pulsating auroras, namely the existence of an enhanced low-energy plasma population in magnetospheric magnetic flux tubes threading the pulsating auroral patch. Liang, J. B. Yang, E. Donovan, J. Burchill, and D. Knudsen (2017), Ionospheric electron heating associated with pulsating auroras: A Swarm survey and model simulation, JGRA53073, in press

Nanometric Integrated Temperature and Thermal Sensors in CMOS-SOI Technology.

PubMed

Malits, Maria; Nemirovsky, Yael

2017-07-29

This paper reviews and compares the thermal and noise characterization of CMOS (complementary metal-oxide-semiconductor) SOI (Silicon on insulator) transistors and lateral diodes used as temperature and thermal sensors. DC analysis of the measured sensors and the experimental results in a broad (300 K up to 550 K) temperature range are presented. It is shown that both sensors require small chip area, have low power consumption, and exhibit linearity and high sensitivity over the entire temperature range. However, the diode's sensitivity to temperature variations in CMOS-SOI technology is highly dependent on the diode's perimeter; hence, a careful calibration for each fabrication process is needed. In contrast, the short thermal time constant of the electrons in the transistor's channel enables measuring the instantaneous heating of the channel and to determine the local true temperature of the transistor. This allows accurate "on-line" temperature sensing while no additional calibration is needed. In addition, the noise measurements indicate that the diode's small area and perimeter causes a high 1/ f noise in all measured bias currents. This is a severe drawback for the sensor accuracy when using the sensor as a thermal sensor; hence, CMOS-SOI transistors are a better choice for temperature sensing.

Effect of Heat Treatment on Microstructure and Mechanical Properties of Laser Additively Manufactured AISI H13 Tool Steel

NASA Astrophysics Data System (ADS)

Chen, ChangJun; Yan, Kai; Qin, Lanlan; Zhang, Min; Wang, Xiaonan; Zou, Tao; Hu, Zengrong

2017-11-01

The effect of heat treatment on microstructure and mechanical properties (microhardness, wear resistance and impact toughness) of laser additively manufactured AISI H13 tool steel was systemically investigated. To understand the variation of microstructure and mechanical properties under different heat treatments, the as-deposited samples were treated at 350, 450, 550, 600 and 650 °C/2 h, respectively. Microstructure and phase transformation were investigated through optical microscopy, scanning electron microscope and transmission electron microscope. The mechanical properties were characterized by nanoindentation tests, Charpy tests and high-temperature wear tests. The microstructure of as-deposited samples consisted of martensite, ultrafine carbides and retained austenite. After the tempering treatment, the martensite was converted into tempered martensite and some fine alloy carbides which precipitated in the matrix. When treated at 550 °C, the greatest hardness and nanohardness were 600 HV0.3 and 6119.4 MPa due to many needle-like carbides precipitation. The value of hardness increased firstly and then decreased when increasing the temperature. When tempered temperatures exceeded 550 °C, the carbides became coarse, and martensitic matrix recrystallized at the temperature of 650 °C. The least impact energy was 6.0 J at a temperature of 550 °C. Samples tempered at 550 °C had larger wear volume loss than that of others. Wear resistances of all samples under atmospheric condition at 400 °C showed an oxidation mechanism.

Compositional redistribution in alloy films under high-voltage electron microscope irradiation

NASA Astrophysics Data System (ADS)

Lam, Nghi Q.; Leaf, O. K.; Minkoff, M.

1983-10-01

The problem of nonequilibrium segregation in alloy films under high-voltage electron microscope (HVEM) irradiation at elevated temperatures is re-examined in the present work, taking into account the damage-rate gradients caused by radial variation in the electron flux. Axial and radial compositional redistributions in model solid solutions, representative of concentrated Ni-Cu, Ni-Al and Ni-Si alloys, were calculated as a function of time, temperature, and film thickness, using a kinetic theory of segregation in binary alloys. The numerical results were achieved by means of a new software package (DISPL2) for solving convection-diffusion-kinetics problems with general orthogonal geometries. It was found that HVEM irradiation-induced segregation in thin films consists of two stages. Initially, due to the proximity of the film surfaces as sinks for point defects, the usual axial segregation (to surfaces) occurs at relatively short irradiation times, and rapidly attains quasi-steady state. Then, radial segregation becomes more and more competitive, gradually affecting the kinetics of axial segregation. At a given temperature, the buildup time to steady state is much longer in the present situation than in the simple case of one-dimensional segregation with uniform defect production. Changes in the alloy composition occur in a much larger zone than the irradiated volume. As a result, the average alloy composition within the irradiated region can differ greatly from that of the unirradiated alloy. The present calculations may be useful in the interpretation of the kinetics of certain HVEM irradiation-induced processes in alloys.

Microwave air plasmas in capillaries at low pressure II. Experimental investigation

NASA Astrophysics Data System (ADS)

Stancu, G. D.; Leroy, O.; Coche, P.; Gadonna, K.; Guerra, V.; Minea, T.; Alves, L. L.

2016-11-01

This work presents an experimental study of microwave (2.45 GHz excitation frequency) micro-plasmas, generated in dry air (N2 80%: O2 20%) within a small radius silica capillary (345 µm inner radius) at low pressure (300 Pa) and low powers (80-130 W). Experimental diagnostics are performed using optical emission spectroscopy calibrated in absolute intensity. Axial-resolved measurements (50 µm spatial resolution) of atomic transitions N(3p4S)  →  N(3s4P) O(3p5P)  →  O(3s5S) and molecular transitions N2(C,v‧)  →  N2(B,v″) \\text{N}2+ (B,v‧)  →  \\text{N}2+ (X,v″) allow us to obtain, as a function of the coupled power, the absolute densities of N(3p4S), O(3p5P), N2(C), N2(B) and \\text{N}2+ (B), as well as the gas (rotational) temperature (700-1000 K), the vibrational temperature of N2(C,v) (7000-10 000 K) and the excitation temperatures of N2(C) and N2(B) (11 000 K). The analysis of the H β line-width gives an upper limiting value of 1013 cm-3 for the electron density; its axial variation (4  ×  1011-6  ×  1012 cm-3) being estimated by solving the wave electrodynamics equations for the present geometry, plasma length and electron-neutral collision frequency. The experimental results were compared with the results from a 0D model, presented in companion paper I [1], which couples the system of rate balance equations for the dominant neutral and charged plasma species to the homogeneous two-term electron Boltzmann equation, taking the measured gas temperature and the estimated electron density as input parameters. Good qualitative agreement is found between the measurements and calculations of the local species densities for various powers and axial positions. The dissociation degree of oxygen is found above 10%. Moreover, both the measurements and calculations show evidence of the non-equilibrium behavior of low-temperature plasmas, with vibrational and excitation temperatures at least ten times higher than the gas temperature. These observations confirm that low-pressure microwave micro-plasmas exhibit high-reactivity, and the present study shows that these features are controlled by electron kinetics, as expected.

Nonexponential London Penetration Depth of FeAs-Based Superconducting RFeAsO[subscript 0.9]F[subscript 0.1] (R=La, Nd) Single Crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, C.; Tillman, M.E.; Kim, H.

2009-07-31

The superconducting penetration depth {lambda}(T) has been measured in RFeAsO{sub 0.9}F{sub 0.1} (R=La, Nd) single crystals (R-1111). In Nd-1111, we find an upturn in {lambda}(T) upon cooling and attribute it to the paramagnetism of the Nd ions, similar to the case of the electron-doped cuprate Nd-Ce-Cu-O. After the correction for paramagnetism, the London penetration depth variation is found to follow a power-law behavior, {Delta}{lambda}L(T) {proportional_to} T{sup 2} at low temperatures. The same T{sup 2} variation of {lambda}(T) was found in nonmagnetic La-1111 crystals. Analysis of the superfluid density and of penetration depth anisotropy over the full temperature range is consistentmore » with two-gap superconductivity. Based on this and on our previous work, we conclude that both the RFeAsO (1111) and BaFe{sub 2}As{sub 2} (122) families of pnictide superconductors exhibit unconventional two-gap superconductivity.« less

Temperature Dependence of the Spin-Hall Conductivity of a Two-Dimensional Impure Rashba Electron Gas in the Presence of Electron-Phonon and Electron-Electron Interactions

NASA Astrophysics Data System (ADS)

Yavari, H.; Mokhtari, M.; Bayervand, A.

2015-03-01

Based on Kubo's linear response formalism, temperature dependence of the spin-Hall conductivity of a two-dimensional impure (magnetic and nonmagnetic impurities) Rashba electron gas in the presence of electron-electron and electron-phonon interactions is analyzed theoretically. We will show that the temperature dependence of the spin-Hall conductivity is determined by the relaxation rates due to these interactions. At low temperature, the elastic lifetimes ( and are determined by magnetic and nonmagnetic impurity concentrations which are independent of the temperature, while the inelastic lifetimes ( and related to the electron-electron and electron-phonon interactions, decrease when the temperature increases. We will also show that since the spin-Hall conductivity is sensitive to temperature, we can distinguish the intrinsic and extrinsic contributions.

Low-valent low-coordinated manganese(I) ion dimer: a temperature dependent W-band EPR study.

PubMed

Sorace, Lorenzo; Golze, Christian; Gatteschi, Dante; Bencini, Alessandro; Roesky, Herbert W; Chai, Jianfang; Stückl, A Claudia

2006-01-09

W-Band EPR spectra of [[HC(CMeNAr)(2)]Mn](2) (Ar = 2,6-(i)Pr(2)C(6)H(3)) have been measured at different temperatures. The spectra show a behavior which is typical for an antiferromagnetically coupled dimer with excited states populating upon increasing temperature. By following the intensity variation of the different features of the spectra with temperature, we attributed different groups of resonances to the S = 1, 2, and 3 states of the dimer. Their corresponding spin Hamiltonian parameters were derived from simulations. The zero-field-splitting parameters measured in this way were D(S=1) = 1.57 cm(-1) and E(S=1) = 0.064 cm(-1), D(S=2) = 0.266 cm(-1) and E(S=2) = 0.0045 cm(-1), and D(S=3) = 0.075 cm(-1) and E(S=3) = 0. On the basis of the molecular structure of the system, we could estimate that zero-field splitting (ZFS) is the result of anisotropic exchange and single-ion anisotropic contributions of similar magnitude (|D| approximately 0.2 cm(-1)). These results allow a deeper insight into the electronic structure of the Mn(I) centers in low-coordination environments, further supporting the electronic structure of Mn(I) to be 4s(1)3d(5), as previously indicated by DFT calculations.

In situ soft XAS study on nickel-based layered cathode material at elevated temperatures: A novel approach to study thermal stability

DOE PAGES

Yoon, Won -Sub; Yang, Xiao -Qing; Haas, Otto; ...

2014-10-29

Tracking thermally induced reactions has always been challenging for electrode materials of electrochemical battery systems. Traditionally, a variety of calorimetric techniques and in situ XRD at elevated temperatures has been used to evaluate the thermal stability of electrode materials. These techniques are capable of providing variations in heat capacity, mass and average bulk composition of materials only. Herein, we report investigation of thermal characteristics of Li 0.33Ni 0.8Co 0.15Al 0.05O 2 by using in situ soft XAS measurements in combination with XRD. Fluorescence yield and partial electron yield measurements are used simultaneously to obtain element selective surface and bulk information.more » Fluorescence yield measurements reveal no energy change of the absorption peak and thus no valence state change in the bulk. However, electron yield measurements indicate that NiO-type rock salt structure is formed at the surface at temperatures above 200°C while no evidence for a surface reaction near Co sites in investigated temperature range is found. These results clearly show that in situ soft XAS can give a unique understanding of the role of each element in the structural transformation under thermal abuse offering a useful guidance in developing new battery system with improved safety performance.« less

Tensile Properties and Deflection Temperature of Polypropylene/Sumberejo Kenaf Fiber Composites with Fiber Content Variation

NASA Astrophysics Data System (ADS)

Ollivia, S. L.; Juwono, A. L.; Roseno, Seto

2017-05-01

The use of synthetic fibers as reinforcement in composites has disadvantage which are unsustainable and an adverse impact on the environment. An alternative reinforcement for composites is natural fiber. Polypropylene and Sumberejo kenaf fibers were used respectively as the matrix and reinforcement. The aim of this research was to obtain the optimum tensile properties and deflection temperature with the variation of kenaf fiber fractions. Polypropylene/kenaf fiber composites were fabricated by hot press method. The kenaf fiber was soaked in NaOH solution before being used as the reinforcement and polypropylene was extruded before being used as the matrix. The weight fractions were varied to produce composites and pristine polypropylene samples were also prepared for comparison. The optimum tensile strength, modulus and deflection temperature were found in the composites with the 40 wt% kenaf fiber fraction with an increase up to 80% and 170% compared to the pristine polypropylene with the values of (60.3 ± 4,3) MPa and (159.1 ± 1,8) °C respectively. The Scanning Electron Microscope observation results in the fracture surface of the composites with the 40 wt% fiber fraction showed a relatively good bonding interface between fibers and the matrix and the failure modes were fiber breakage and matrix failures.

Experimental study on structural, optoelectronic and room temperature sensing performance of Nickel doped ZnO based ethanol sensors

NASA Astrophysics Data System (ADS)

Sudha, M.; Radha, S.; Kirubaveni, S.; Kiruthika, R.; Govindaraj, R.; Santhosh, N.

2018-04-01

Nano crystalline undoped (1Z) Zinc Oxide (ZnO) and 5, 10 and 15 Wt. % (1ZN, 2ZN and 3ZN) of Nickel doped ZnO based sensors were fabricated using the hydrothermal approach on Fluorine doped Tin Oxide (FTO) glass substrates. X-ray diffraction (XRD) analysis proved the hexagonal Wurtzite structure of ZnO. Parametric variations in terms of dislocation density, bond length, lattice parameters and micro strain with respect to dopant concentration were analysed. The prominent variations in the crystallite size, optical band gap and Photoluminescence peak ratio of devices fabricated was observed. The Field Emission Scanning Electron Microscope (FESEM) images showed a change in diameter and density of the nanorods. The effect of the operating temperature, concentration of ethanol and the different doping levels of sensitivity, response and recovery time were investigated. It was inferred that 376% of sensitivity with a very quick response and recovery time of <5 s and 10 s respectively at 150 °C of 3ZN sensor has better performance compared to other three sensors. Also 3ZN sensor showed improved sensitivity of 114%, even at room temperature with response and recovery time of 35 s and 45 s respectively.

Ionospheric chemistry of NO(+)

NASA Technical Reports Server (NTRS)

Breig, E. L.; Hanson, W. B.; Hoffman, J. H.

1984-01-01

An investigation is described of the behavior of NO(+) in the daytime F region, with basic ion concentration measurements from the Atmosphere Explorer C satellite. The data set was acquired along select orbits at low latitudes and exhibits substantial variations in the NO(+) concentration, both along and between nearby orbits. An excellent consistency is demonstrated between these observations and current chemical equilibrium theory, in contrast to differences that have been reported for the related N2(+) ion. Large variations in the concurrently observed electron temperature permit a relevant comparison between different laboratory determinations of the dissociative recombination rate coefficient. Contributions to the NO(+) production from several secondary sources are also evaluated. Results strengthen the basis for the current theoretical ionospheric chemistry of NO(+) and establish important constraints on resolution of the difficulties with N2(+).

A Polymer Optical Fiber Temperature Sensor Based on Material Features.

PubMed

Leal-Junior, Arnaldo; Frizera-Netoc, Anselmo; Marques, Carlos; Pontes, Maria José

2018-01-19

This paper presents a polymer optical fiber (POF)-based temperature sensor. The operation principle of the sensor is the variation in the POF mechanical properties with the temperature variation. Such mechanical property variation leads to a variation in the POF output power when a constant stress is applied to the fiber due to the stress-optical effect. The fiber mechanical properties are characterized through a dynamic mechanical analysis, and the output power variation with different temperatures is measured. The stress is applied to the fiber by means of a 180° curvature, and supports are positioned on the fiber to inhibit the variation in its curvature with the temperature variation. Results show that the sensor proposed has a sensitivity of 1.04 × 10 -3 °C -1 , a linearity of 0.994, and a root mean squared error of 1.48 °C, which indicates a relative error of below 2%, which is lower than the ones obtained for intensity-variation-based temperature sensors. Furthermore, the sensor is able to operate at temperatures up to 110 °C, which is higher than the ones obtained for similar POF sensors in the literature.

Thermodynamic properties of rhodium at high temperature and pressure by using mean field potential approach

NASA Astrophysics Data System (ADS)

Kumar, Priyank; Bhatt, Nisarg K.; Vyas, Pulastya R.; Gohel, Vinod B.

2016-10-01

The thermophysical properties of rhodium are studied up to melting temperature by incorporating anharmonic effects due to lattice ions and thermally excited electrons. In order to account anharmonic effects due to lattice vibrations, we have employed mean field potential (MFP) approach and for thermally excited electrons Mermin functional. The local form of the pseudopotential with only one effective adjustable parameter rc is used to construct MFP and hence vibrational free energy due to ions - Fion. We have studied equation of state at 300 K and further, to access the applicability of present conjunction scheme, we have also estimated shock-Hugoniot and temperature along principle Hugoniot. We have carried out the study of temperature variation of several thermophysical properties like thermal expansion (βP), enthalpy (EH), specific heats at constant pressure and volume (CP and CV), specific heats due to lattice ions and thermally excited electrons ( and , isothermal and adiabatic bulk moduli (BT and Bs) and thermodynamic Gruneisen parameter (γth) in order to examine the inclusion of anharmonic effects in the present study. The computed results are compared with available experimental results measured by using different methods and previously obtained theoretical results using different theoretical philosophy. Our computed results are in good agreement with experimental findings and for some physical quantities better or comparable with other theoretical results. We conclude that local form of the pseudopotential used accounts s-p-d hybridization properly and found to be transferable at extreme environment without changing the values of the parameter. Thus, even the behavior of transition metals having complexity in electronic structure can be well understood with local pseudopotential without any modification in the potential at extreme environment. Looking to the success of present scheme (MFP + pseudopotential) we would like to extend it further for the study of liquid state properties as well as thermophysical properties of d and f block metals.

The ferromagnetic-spin glass transition in PdMn alloys: symmetry breaking of ferromagnetism and spin glass studied by a multicanonical method.

PubMed

Kato, Tomohiko; Saita, Takahiro

2011-03-16

The magnetism of Pd(1-x)Mn(x) is investigated theoretically. A localized spin model for Mn spins that interact with short-range antiferromagnetic interactions and long-range ferromagnetic interactions via itinerant d electrons is set up, with no adjustable parameters. A multicanonical Monte Carlo simulation, combined with a procedure of symmetry breaking, is employed to discriminate between the ferromagnetic and spin glass orders. The transition temperature and the low-temperature phase are determined from the temperature variation of the specific heat and the probability distributions of the ferromagnetic order parameter and the spin glass order parameter at different concentrations. The calculation results reveal that only the ferromagnetic phase exists at x < 0.02, that only the spin glass phase exists at x > 0.04, and that the two phases coexist at intermediate concentrations. This result agrees semi-quantitatively with experimental results.

Parametric study on the compressive strength geopolymer paving block

NASA Astrophysics Data System (ADS)

Aman; Awaluddin, A.; Ahmad, A.; Olivia, M.

2018-04-01

This paper reported about the investigated of sodium hidroxida concentration, effect of ratio liquid to solid (L/S), temperature and time on the compressive strength of geopolymer paving block using fly ash and fine aggregate as base material and combination of sodium hidroxida and sodium silicate as alkaline activator and the ratio of Na2SiO3/NaOH was 2 and fly ash to aggregate of 1: 3. The experiments were conducted with variation of the sodium hidroxida concentration of (10-16 M) liquid to solid (L/S) 0.1- 0.7 ratio, curing temperature 30-100 °C and curing time (7-28 day). The main evaluation techniques in this experimental were Compressive strength, X-ray diffraction (XRD),and Scaning Electron Microscope (SEM). The result showed that the compressive strength of Geopolymer Paving block has increased with an increasing of concentration, liquid to solid ratio, curing temperature and curing time.

Hardness of AISI type 410 martensitic steels after high temperature irradiation via nanoindentation

NASA Astrophysics Data System (ADS)

Waseem, Owais Ahmed; Jeong, Jong-Ryul; Park, Byong-Guk; Maeng, Cheol-Soo; Lee, Myoung-Goo; Ryu, Ho Jin

2017-11-01

The hardness of irradiated AISI type 410 martensitic steel, which is utilized in structural and magnetic components of nuclear power plants, is investigated in this study. Proton irradiation of AISI type 410 martensitic steel samples was carried out by exposing the samples to 3 MeV protons up to a 1.0 × 1017 p/cm2 fluence level at a representative nuclear reactor coolant temperature of 350 °C. The assessment of deleterious effects of irradiation on the micro-structure and mechanical behavior of the AISI type 410 martensitic steel samples via transmission electron microscopy-energy dispersive spectroscopy and cross-sectional nano-indentation showed no significant variation in the microscopic or mechanical characteristics. These results ensure the integrity of the structural and magnetic components of nuclear reactors made of AISI type 410 martensitic steel under high-temperature irradiation damage levels up to approximately 5.2 × 10-3 dpa.

Effect of substrate temperature in the synthesis of BN nanostructures

NASA Astrophysics Data System (ADS)

Sajjad, M.; Zhang, H. X.; Peng, X. Y.; Feng, P. X.

2011-06-01

Boron nitride (BN) nanostructures were grown on molybdenum discs at different substrate temperatures using the short-pulse laser plasma deposition technique. Large numbers of randomly oriented nanorods of fiber-like structures were obtained. The variation in the length and diameter of the nanorods as a function of the substrate temperature was systematically studied. The surface morphologies of the samples were studied using scanning electron microscopy. Energy dispersive x-ray spectroscopy confirmed that both the elements boron and nitrogen are dominant in the nanostructure. The x-ray diffraction (XRD) technique was used to analyse BN phases. The XRD peak that appeared at 26° showed the presence of hexagonal BN phase, whereas the peak at 44° was related to cubic BN content in the samples. Raman spectroscopic analysis showed vibrational modes of sp2- and sp3-type bonding in the sample. The Raman spectra agreed well with XRD results.

Far-infrared line observations of planetary nebulae. 1: The O 3 spectrum

NASA Technical Reports Server (NTRS)

Dinerstein, H. L.; Lester, D. F.; Werner, M. W.

1985-01-01

Observations of the far-infrared fine structure lines of O III have been obtained for six planetary nebulae. The infrared measurements are combined with optical O III line fluxes to probe physical conditions in the gas. From the observed line intensity ratios, a simultaneous solution was obtained for electron temperature and density, as well as means of evaluating the importance of inhomogeneities. Densities determined from the far-infrared O III lines agree well density diagnostics from other ions, indicating a fairly homogeneous density in the emitting gas. Temperatures are determined separately from the O III 4363/5007 A and 5007 A/52 micron intensity ratios and compared. Systematically higher values are derived from the former ratio, which is expected from a nebula which is not isothermal. Allowance for the presence of temperature variations within these nebulae raises their derived oxygen abundances, determinations to be reconciled with the solar value.

Thermal conductance characterization of a pressed copper rope strap between 0.13 K and 10 K

DOE PAGES

Dhuley, R. C.; Ruschman, M.; Link, J. T.; ...

2017-07-05

Mechanically pressing the ends of a copper braid in solid copper is an effective way of constructing solderless conductive straps for cryogenic applications. In this paper we present thermal conductance data of such a copper strap measured using the two-heater one-thermometer method. The measurements span a wide temperature range of 0.13–10 K applicable to a variety of cryogenic systems employing liquid helium, pulse tube coolers, adiabatic demagnetization refrigerators, and others. Above ≈1.5 K, the braid thermal conductivity dominates the strap conductance resulting in a near-linear dependence with temperature. The variation with temperature below ≈1.5 K is near-quadratic indicating dominance ofmore » the pressed contact conductance at the strap ends. In conclusion, electron-beam welding the braid to the strap ends is shown to be a promising solution for improving sub-Kelvin thermal conductance of the strap.« less

From Concept-to-Flight: An Active Active Fluid Loop Based Thermal Control System for Mars Science Laboratory Rover

NASA Technical Reports Server (NTRS)

Birur, Gajanana C.; Bhandari, Pradeep; Bame, David; Karlmann, Paul; Mastropietro, A. J.; Liu, Yuanming; Miller, Jennifer; Pauken, Michael; Lyra, Jacqueline

2012-01-01

The Mars Science Laboratory (MSL) rover, Curiosity, which was launched on November 26, 2011, incorporates a novel active thermal control system to keep the sensitive electronics and science instruments at safe operating and survival temperatures. While the diurnal temperature variations on the Mars surface range from -120 C to +30 C, the sensitive equipment are kept within -40 C to +50 C. The active thermal control system is based on a single-phase mechanically pumped fluid loop (MPFL) system which removes or recovers excess waste heat and manages it to maintain the sensitive equipment inside the rover at safe temperatures. This paper will describe the entire process of developing this active thermal control system for the MSL rover from concept to flight implementation. The development of the rover thermal control system during its architecture, design, fabrication, integration, testing, and launch is described.

Thermal conductance characterization of a pressed copper rope strap between 0.13 K and 10 K

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhuley, R. C.; Ruschman, M.; Link, J. T.

Mechanically pressing the ends of a copper braid in solid copper is an effective way of constructing solderless conductive straps for cryogenic applications. In this paper we present thermal conductance data of such a copper strap measured using the two-heater one-thermometer method. The measurements span a wide temperature range of 0.13–10 K applicable to a variety of cryogenic systems employing liquid helium, pulse tube coolers, adiabatic demagnetization refrigerators, and others. Above ≈1.5 K, the braid thermal conductivity dominates the strap conductance resulting in a near-linear dependence with temperature. The variation with temperature below ≈1.5 K is near-quadratic indicating dominance ofmore » the pressed contact conductance at the strap ends. In conclusion, electron-beam welding the braid to the strap ends is shown to be a promising solution for improving sub-Kelvin thermal conductance of the strap.« less

High temperature crystal field spectra of transition metal-bearing minerals - Relevance to remote-sensed spectra of planetary surfaces

NASA Technical Reports Server (NTRS)

Parkin, K. M.; Burns, R. G.

1980-01-01

It is pointed out that transition metal ions in silicate minerals, glasses, and crystalline and amorphous oxyhydroxides and salts contribute to the visible-near infrared spectral profiles of planetary surfaces. Investigations are conducted to obtain spectral information which might be helpful in the interpretation of the remote-sensed spectra of planetary surfaces. A description is presented of the results of high temperature crystal field spectral measurements of a variety of heated minerals containing Cr(3+), Fe(3+), Fe(++), and Mn(++) ions in different coordination symmetries, taking into account a correlation of the temperature-induced variations with those previously observed for octahedrally coordinated Fe(++)-bearing silicates. The employed experimental methods are also discussed, giving attention to the preparation of the samples, the determination of the absorption spectra, electron microprobe analyses, and the curve fitting procedure.

State-of-technology for joining TD-NiCr sheet

NASA Technical Reports Server (NTRS)

Holko, K. H.; Moore, T. J.; Gyorgak, C. A.

1972-01-01

At the current state-of-technology there are many joining processes that can be used to make sound welds in TD-NiCr sheet. Some of these that are described in this report are electron beam welding, gas-tungsten arc welding, diffusion welding, resistance spot welding, resistance seam welding, and brazing. The strengths of the welds made by the various processes show considerable variation, especially at elevated temperatures. Most of the fusion welding processes tend to give weak welds at elevated temperatures (with the exception of fusion-type resistance spotwelds). However, solid-state welds have been made with parent metal properties. The process used for a specific application will be dictated by the specific joint requirements. In highly stressed joints at elevated temperatures, one of the solid-state processes, such as DFW, RSW (solid-state or fusion), and RSEW, offer the most promise.

Cell chip temperature measurements in different operation regimes of HCPV modules

NASA Astrophysics Data System (ADS)

Rumyantsev, V. D.; Chekalin, A. V.; Davidyuk, N. Yu.; Malevskiy, D. A.; Pokrovskiy, P. V.; Sadchikov, N. A.; Pan'chak, A. N.

2013-09-01

A new method has been developed for accurate measurements of the solar cell temperature in maximum power point (MPP) operation regime in comparison with that in open circuit (OC) regime (TMPP and TOC). For this, an electronic circuit has been elaborated for fast variation of the cell load conditions and for voltage measurements, so that VOC values could serve as an indicator of TMPP at the first moment after the load disconnection. The method was verified in indoor investigations of the single-junction AlGaAs/GaAs cells under CW laser irradiation, where different modifications of the heat spreaders were involved. PV modules of the "SMALFOC" design (Small-size concentrators; Multijunction cells; "All-glass" structure; Lamination technology; Fresnel Optics for Concentration) with triple-junction InGaP/GaAs/Ge cells were examined outdoors to evaluate temperature regimes of their operation.

Annealing effect on the magnetic induced austenite transformation in polycrystalline freestanding Ni-Co-Mn-In films produced by co-sputtering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crouïgneau, G., E-mail: guillaume.crouigneau@neel.cnrs.fr; Univ. Grenoble Alpes, CRETA, F-38000 Grenoble; CNRS, Inst. NEEL, F-38000 Grenoble

2015-01-21

Ni-Co-Mn-In freestanding films, with a magneto-structural transformation at room temperature were successfully produced by co-sputtering and post-annealing methods leading to film composition mastering. For a post-annealing temperature of 700 °C, the phase transformation occurs slightly above room temperature, with a twisted martensitic microstructure phase observed at 300 K by Field Emission Scanning Electron Microscopy. Magnetization measurements on a polycrystalline film showed a phase transformation from a weakly magnetic martensite to a magnetic austenite phase. Moreover, an inverse magnetocaloric effect with an entropy variation of 4 J/kg K under 5 T was also measured. A simple magneto-actuation experiment based on the magnetic induced austenite transformation wasmore » also successfully completed. The possibility to insert such films in microsystems is clearly demonstrated in this work.« less

Effect of Temperature Variations on Molecular Weight Distributions - Batch, Chain Addition Polymerizations

DTIC Science & Technology

those that might be formed by temperature variations in real reactors. Under most conditions, temperature variations appear to have a much greater effect on MWD than residence time distributions and micromixing .

Evolution of Field-Aligned Electron and Ion Densities From Whistler Mode Radio Soundings During Quiet to Moderately Active Period and Comparisons With SAMI2 Simulations

NASA Astrophysics Data System (ADS)

Reddy, A.; Sonwalkar, V. S.; Huba, J. D.

2018-02-01

Knowledge of field-aligned electron and ion distributions is necessary for understanding the physical processes causing variations in field-aligned electron and ion densities. Using whistler mode sounding by Radio Plasma Imager/Imager for Magnetopause-to-Aurora Global Exploration (RPI/IMAGE), we determined the evolution of dayside electron and ion densities along L ˜ 2 and L ˜ 3 (90-4,000 km) during a 7 day (21-27 November 2005) geomagnetically quiet to moderately active period. Over this period the O+/H+ transition height was ˜880 ± 60 km and ˜1000 ± 100 km, respectively, at L ˜ 2 and L ˜ 3. The electron density varied in a complex manner; it was different at L ˜ 2 and L ˜ 3 and below and above the O+/H+ transition height. The measured electron and ion densities are consistent with those from Challenging Minisatellite Payload (CHAMP) and Defense Meteorological Satellite Program (DMSP) and other past measurements, but they deviated from bottomside sounding and International Reference Ionosphere (IRI) 2012 empirical model results. Using SAMI2 (Naval Research Laboratory (NRL) ionosphere model) with reasonably adjusted values of inputs (neutral densities, winds, electric fields, and photoelectron heating), we simulated the evolution of O+/H+ transition height and field-aligned electron and ion densities so that a fair agreement was obtained between the simulation results and observations. Simulation studies indicated that reduced neutral densities (H and/or O) with time limited O+-H charge exchange process. This reduction in neutral densities combined with changes in neutral winds and plasma temperature led to the observed variations in the electron and ion densities. The observation/simulation method presented here can be extended to investigate the role of neutral densities and composition, disturbed winds, and prompt penetration electric fields in the storm time ionosphere/plasmasphere dynamics.

Effect of freezing temperature in thermally induced phase separation method in hydroxyapatite/chitosan-based bone scaffold biomaterial

NASA Astrophysics Data System (ADS)

Albab, Muh Fadhil; Yuwono, Akhmad Herman; Sofyan, Nofrijon; Ramahdita, Ghiska

2017-02-01

In the current study, hydroxyapatite (HA)/chitosan-based bone scaffold has been fabricated using Thermally Induced Phase Separation (TIPS) method under freezing temperature variation of -20, -30, -40 and -80 °C. The samples with weight percent ratio of 70% HA and 30% chitosan were homogeneously mixed and subsequently dissolved in 2% acetic acid. The synthesized samples were further characterized using Fourier transform infrared (FTIR), compressive test and scanning electron microscope (SEM). The investigation results showed that low freezing temperature reduced the pore size and increased the compressive strength of the scaffold. In the freezing temperature of -20 °C, the pore size was 133.93 µm with the compressive strength of 5.9 KPa, while for -80 °C, the pore size declined to 60.55 µm with the compressive strength 29.8 KPa. Considering the obtained characteristics, HA/chitosan obtained in this work has potential to be applied as a bone scaffold.

Structural and magnetic analysis of La0.67Ca0.33MnO3 nanoparticles thermally treated: Acoustic detection of the magnetocaloric effect

NASA Astrophysics Data System (ADS)

Pena, C. F.; Soffner, M. E.; Mansanares, A. M.; Sampaio, J. A.; Gandra, F. C. G.; da Silva, E. C.; Vargas, H.

2017-10-01

Nanoparticles of La0.67Ca0.33MnO3 were synthesized via the sol-gel method, thermally treated and characterized using X-ray diffraction, magnetization, electron spin resonance and magnetoacoustic experiments. The formation of the desired perovskite structure was verified and the average size of the nanoparticles was also determined. An increase of the particle size by rising the treatment temperature was observed. The Curie temperature and the isothermal entropy variation of the samples were obtained from the magnetization data. The isothermal entropy change, produced under the application of an external magnetic field, which expresses the magnetocaloric effect, became significantly larger for the samples treated at higher temperatures. These results are in good agreement with those obtained by magnetoacoustics, based on the direct and contactless measurement of the temperature change, validating the ability of the technique to study the magnetocaloric effect in reduced mass and nanoparticles samples.

Effect of Temperature on Galling Behavior of SS 316, 316 L and 416 Under Self-Mated Condition

NASA Astrophysics Data System (ADS)

Harsha, A. P.; Limaye, P. K.; Tyagi, Rajnesh; Gupta, Ankit

2016-11-01

Galling behavior of three different stainless steels (SS 316, 316 L and 416) was evaluated at room temperature and 300 °C under a self-mated condition. An indigenously fabricated galling tester was used to evaluate the galling performance of mated materials as per ASTM G196-08 standard. The variation in frictional torque was recorded online during the test to assess the onset of galling. The galling50 (G50) stress value was used to compare the galling resistance of a combination of materials, and the results indicate a significant influence of temperature on the galling resistance of the materials tested. This has been attributed to the decrease in hardness and yield strength at elevated temperature which results in softening of the steel and limits its ability to resist severe deformation. Scanning electron micrographs of the galled surface reflected a severe plastic deformation in sliding direction, and a typical adhesive wear mechanism is prevalent during the galling process.

Recrystallization of fluconazole using the supercritical antisolvent (SAS) process.

PubMed

Park, Hee Jun; Kim, Min-Soo; Lee, Sibeum; Kim, Jeong-Soo; Woo, Jong-Soo; Park, Jeong-Sook; Hwang, Sung-Joo

2007-01-10

The supercritical antisolvent (SAS) process was used to modify solid state characteristics of fluconazole. Fluconazole was recrystallized at various temperatures (60-80 degrees C) and pressures (8-16MPa) using dichloromethane (DCM) as a solvent. Acetone and ethanol were also employed as solvents. The fluconazole polymorphs prepared by the SAS process were characterized by differential scanning calorimetry (DSC), thermogravimetry analysis (TGA), powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). Furthermore, the equilibrium solubility of the samples in aqueous solution was determined. Fluconazole anhydrate form I was obtained at low temperature (40 degrees C) and anhydrate form II was obtained at high temperature (80 degrees C). The variation of pressure during the SAS process may influence the preferred orientation. Anhydrate forms I and II were also obtained using various solvents. Therefore, it was shown that solid state characteristics of fluconazole, including the polymorphic form and preferred orientation, can be controlled by changing operating conditions of the SAS process such as temperature, pressure, and solvent.

Variation in the thermal parameters of Odontophrynus occidentalis in the Monte desert, Argentina: response to the environmental constraints.

PubMed

Sanabria, Eduardo Alfredo; Quiroga, Lorena Beatriz; Martino, Adolfo Ludovico

2012-03-01

We studied the variation of thermal parameters of Odontophrynus occidentalis between season (wet and dry) in the Monte desert (Argentina). We measured body temperatures, microhabitat temperatures, and operative temperatures; while in the laboratory, we measured the selected body temperatures. Our results show a change in the thermal parameters of O. occidentalis that is related to environmental constraints of their thermal niche. Environmental thermal constraints are present in both seasons (dry and wet), showing variations in thermal parameters studied. Apparently imposed environmental restrictions, the toads in nature always show body temperatures below the set point. Acclimatization is an advantage for toads because it allows them to bring more frequent body temperatures to the set point. The selected body temperature has seasonal intraindividual variability. These variations can be due to thermo-sensitivity of toads and life histories of individuals that limits their allocation and acquisition of resources. Possibly the range of variation found in selected body temperature is a consequence of the thermal environmental variation along the year. These variations of thermal parameters are commonly found in deserts and thermal bodies of nocturnal ectotherms. The plasticity of selected body temperature allows O. occidentales to have longer periods of activity for foraging and reproduction, while maintaining reasonable high performance at different temperatures. The plasticity in seasonal variation of the thermal parameters has been poorly studied, and is greatly advantageous to desert species during changes in both seasonal and daily temperature, as these environments are known for their high environmental variability. © 2012 WILEY PERIODICALS, INC.

Electron-phonon coupling in metallic carbon nanotubes: Dispersionless electron propagation despite dissipation

NASA Astrophysics Data System (ADS)

Rosati, Roberto; Dolcini, Fabrizio; Rossi, Fausto

2015-12-01

A recent study [Rosati, Dolcini, and Rossi, Appl. Phys. Lett. 106, 243101 (2015), 10.1063/1.4922739] has predicted that, while in semiconducting single-walled carbon nanotubes (SWNTs) an electronic wave packet experiences the typical spatial diffusion of conventional materials, in metallic SWNTs, its shape remains essentially unaltered up to micrometer distances at room temperature, even in the presence of the electron-phonon coupling. Here, by utilizing a Lindblad-based density-matrix approach enabling us to account for both dissipation and decoherence effects, we test such a prediction by analyzing various aspects that were so far unexplored. In particular, accounting for initial nonequilibrium excitations, characterized by an excess energy E0, and including both intra- and interband phonon scattering, we show that for realistically high values of E0 the electronic diffusion is extremely small and nearly independent of its energetic distribution, in spite of a significant energy-dissipation and decoherence dynamics. Furthermore, we demonstrate that the effect is robust with respect to the variation of the chemical potential. Our results thus suggest that metallic SWNTs are a promising platform to realize quantum channels for the nondispersive transmission of electronic wave packets.

One-dimensional time-dependent fluid model of a very high density low-pressure inductively coupled plasma

DOE PAGES

Chaplin, Vernon H.; Bellan, Paul M.

2015-12-28

A time-dependent two-fluid model has been developed to understand axial variations in the plasma parameters in a very high density (peak n e~ > 5x10 19 m –3) argon inductively coupled discharge in a long 1.1 cm radius tube. The model equations are written in 1D, with radial losses to the tube walls accounted for by the inclusion of effective particle and energy sink terms. The ambipolar diffusion equation and electron energy equation are solved to find the electron density n e(z,t) and temperature T e(z,t), and the populations of the neutral argon 4s metastable, 4s resonant, and 4p excitedmore » state manifolds are calculated in order to determine the stepwise ionization rate and calculate radiative energy losses. The model has been validated through comparisons with Langmuir probe ion saturation current measurements; close agreement between the simulated and measured axial plasma density profiles and the initial density rise rate at each location was obtained at p Ar = 30-60 mTorr. Lastly, we present detailed results from calculations at 60 mTorr, including the time-dependent electron temperature, excited state populations, and energy budget within and downstream of the radiofrequency (RF) antenna.« less

Measurement of electron density and electron temperature of a cascaded arc plasma using laser Thomson scattering compared to an optical emission spectroscopic approach

NASA Astrophysics Data System (ADS)

Yong, WANG; Cong, LI; Jielin, SHI; Xingwei, WU; Hongbin, DING

2017-11-01

As advanced linear plasma sources, cascaded arc plasma devices have been used to generate steady plasma with high electron density, high particle flux and low electron temperature. To measure electron density and electron temperature of the plasma device accurately, a laser Thomson scattering (LTS) system, which is generally recognized as the most precise plasma diagnostic method, has been established in our lab in Dalian University of Technology. The electron density has been measured successfully in the region of 4.5 × 1019 m-3 to 7.1 × 1020 m-3 and electron temperature in the region of 0.18 eV to 0.58 eV. For comparison, an optical emission spectroscopy (OES) system was established as well. The results showed that the electron excitation temperature (configuration temperature) measured by OES is significantly higher than the electron temperature (kinetic electron temperature) measured by LTS by up to 40% in the given discharge conditions. The results indicate that the cascaded arc plasma is recombining plasma and it is not in local thermodynamic equilibrium (LTE). This leads to significant error using OES when characterizing the electron temperature in a non-LTE plasma.

Low temperature electrical properties of some Pb-free solders

NASA Astrophysics Data System (ADS)

Kisiel, Ryszard; Pekala, Marek

2006-03-01

The electronic industry is engaged in developing Pb-free technologies for more than ten years. However till now not all properties of new solders are described. The aim of the paper is to present some electrical properties of new series of Pb-free solders (eutectic SnAg, near eutectic SnAgCu with and without Bi) in low temperature ranges 10 K to 273K. The following parameters were analyzed: electrical resistivity, temperature coefficient of resistance and thermoelectric power. The electrical resistivity at temperatures above 50 K is a monotonically rising function of temperature for Pb-free solders studied. The electrical resistivity of the Bi containing alloys is higher as compared to the remaining ones. The thermoelectric power values at room temperature are about -8 μV/K to -6 μV/K for Pb-free solders studied, being higher as compared to typical values -3 μVK of SnPb solder. The relatively low absolute values as well as the smooth and weak temperature variation of electrical resistivity in lead free solders enable the possible low temperature application. The moderate values of thermoelectric power around and above the room temperature show that when applying the solders studied the temperature should be kept as uniform as possible, in order to avoid spurious or noise voltages.